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Sample records for global silicate weathering

  1. A framework for predicting global silicate weathering and CO2 drawdown rates over geologic time-scales

    PubMed Central

    Hilley, George E.; Porder, Stephen

    2008-01-01

    Global silicate weathering drives long-time-scale fluctuations in atmospheric CO2. While tectonics, climate, and rock-type influence silicate weathering, it is unclear how these factors combine to drive global rates. Here, we explore whether local erosion rates, GCM-derived dust fluxes, temperature, and water balance can capture global variation in silicate weathering. Our spatially explicit approach predicts 1.9–4.6 × 1013 mols of Si weathered globally per year, within a factor of 4–10 of estimates of global silicate fluxes derived from riverine measurements. Similarly, our watershed-based estimates are within a factor of 4–18 (mean of 5.3) of the silica fluxes measured in the world's ten largest rivers. Eighty percent of total global silicate weathering product traveling as dissolved load occurs within a narrow range (0.01–0.5 mm/year) of erosion rates. Assuming each mol of Mg or Ca reacts with 1 mol of CO2, 1.5–3.3 × 108 tons/year of CO2 is consumed by silicate weathering, consistent with previously published estimates. Approximately 50% of this drawdown occurs in the world's active mountain belts, emphasizing the importance of tectonic regulation of global climate over geologic timescales. PMID:18952842

  2. A framework for predicting global silicate weathering and CO2 drawdown rates over geologic time-scales.

    PubMed

    Hilley, George E; Porder, Stephen

    2008-11-04

    Global silicate weathering drives long-time-scale fluctuations in atmospheric CO(2). While tectonics, climate, and rock-type influence silicate weathering, it is unclear how these factors combine to drive global rates. Here, we explore whether local erosion rates, GCM-derived dust fluxes, temperature, and water balance can capture global variation in silicate weathering. Our spatially explicit approach predicts 1.9-4.6 x 10(13) mols of Si weathered globally per year, within a factor of 4-10 of estimates of global silicate fluxes derived from riverine measurements. Similarly, our watershed-based estimates are within a factor of 4-18 (mean of 5.3) of the silica fluxes measured in the world's ten largest rivers. Eighty percent of total global silicate weathering product traveling as dissolved load occurs within a narrow range (0.01-0.5 mm/year) of erosion rates. Assuming each mol of Mg or Ca reacts with 1 mol of CO(2), 1.5-3.3 x 10(8) tons/year of CO(2) is consumed by silicate weathering, consistent with previously published estimates. Approximately 50% of this drawdown occurs in the world's active mountain belts, emphasizing the importance of tectonic regulation of global climate over geologic timescales.

  3. Natural Weathering Rates of Silicate Minerals

    NASA Astrophysics Data System (ADS)

    White, A. F.

    2003-12-01

    Silicates constitute more than 90% of the rocks exposed at Earth's land surface (Garrels and Mackenzie, 1971). Most primary minerals comprising these rocks are thermodynamically unstable at surface pressure/temperature conditions and are therefore susceptible to chemical weathering. Such weathering has long been of interest in the natural sciences. Hartt (1853) correctly attributed chemical weathering to "the efficacy of water containing carbonic acid in promoting the decomposition of igneous rocks." Antecedent to the recent interest in the role of vegetation on chemical weathering, Belt (1874) observed that the most intense weathering of rocks in tropical Nicaragua was confined to forested regions. He attributed this effect to "the percolation through rocks of rain water charged with a little acid from decomposing vegetation." Chamberlin (1899) proposed that the enhanced rates of chemical weathering associated with major mountain building episodes in Earth's history resulted in a drawdown of atmospheric CO2 that led to periods of global cooling. Many of the major characteristics of chemical weathering had been described when Merrill (1906) published the groundbreaking volume Rocks, Rock Weathering, and Soils.The major advances since that time, particularly during the last several decades, have centered on understanding the fundamental chemical, hydrologic, and biologic processes that control weathering and in establishing quantitative weathering rates. This research has been driven by the importance of chemical weathering to a number environmentally and economically important issues. Undoubtedly, the most significant aspect of chemical weathering is the breakdown of rocks to form soils, a process that makes life possible on the surface of the Earth. The availability of many soil macronutrients such as magnesium, calcium, potassium, and PO4 is directly related to the rate at which primary minerals weather. Often such nutrient balances are upset by anthropogenic

  4. Orbital-scale changes in the global silicate weathering intensity: the Mesozoic bedded chert sequence in Japan as its potential measure

    NASA Astrophysics Data System (ADS)

    Ikeda, M.; Tada, R.; Olsen, P. E.

    2012-12-01

    Silicate weathering is one of the most important regulators of the Earth system dynamics through nutrient supply and consumption of atmospheric CO2. However, its changes in the geologic past using geologic records have been controversial due to the lack of appropriate method to quantitatively reconstruct the past global silicate weathering intensity. One way for its measurement would be an estimation of the pelagic biogenic silica burial rate, because the silicate weathering and pelagic biogenic silica burial are the major source and major sink of dissolved silica in the present ocean, respectively (e.g. Treguer et al., 1995). During the Mesozoic, the pelagic bedded chert is the potential major sink of the biogenic silica in the ocean. We therefore first estimate the biogenic silica burial rate for the Inuyama bedded chert in Japan based on the major elements chemical analysis of individual chert and shale beds on the continuous sequence with bed-by-bed resolution. The rhythmically alternation of chert and shale beds were reflected by the precession cycle (Ikeda et al., 2010). By using the chert-shale couplet as time scale, we reconstructed the variation in the biogenic silica burial rate for the Inuyama bedded chert from the Early Triassic to Early Jurassic. Together with paleogeographic distribution of bedded chert compiled from previous studies, the biogenic silica burial rate in the low latitude Panthalassa ocean in the form of bedded chert was several times higher than the biogenic silica burial rate in the modern global ocean (DeMaster, 2002). This result suggests that bedded chert was the major sink of the dissolved silica in the ocean at least during the early Mesozoic. Therefore, the variations in the biogenic silica burial rate for bedded chert should be proportional to the variations in the dissolved silica input to the ocean in time-scales longer than its residence time in the ocean (15 kyr; Treguer et al., 1995). The variation in 87Sr/86Sr isotopic

  5. Impact of atmospheric CO2 levels on continental silicate weathering

    NASA Astrophysics Data System (ADS)

    Beaulieu, E.; GoddéRis, Y.; Labat, D.; Roelandt, C.; Oliva, P.; Guerrero, B.

    2010-07-01

    Anthropogenic sources are widely accepted as the dominant cause for the increase in atmospheric CO2 concentrations since the beginning of the industrial revolution. Here we use the B-WITCH model to quantify the impact of increased CO2 concentrations on CO2 consumption by weathering of continental surfaces. B-WITCH couples a dynamic biogeochemistry model (LPJ) and a process-based numerical model of continental weathering (WITCH). It allows simultaneous calculations of the different components of continental weathering fluxes, terrestrial vegetation dynamics, and carbon and water fluxes. The CO2 consumption rates are estimated at four different atmospheric CO2 concentrations, from 280 up to 1120 ppmv, for 22 sites characterized by silicate lithologies (basalt, granite, or sandstones). The sensitivity to atmospheric CO2 variations is explored, while temperature and rainfall are held constant. First, we show that under 355 ppmv of atmospheric CO2, B-WITCH is able to reproduce the global pattern of weathering rates as a function of annual runoff, mean annual temperature, or latitude for silicate lithologies. When atmospheric CO2 increases, evapotranspiration generally decreases due to progressive stomatal closure, and the soil CO2 pressure increases due to enhanced biospheric productivity. As a result, vertical drainage and soil acidity increase, promoting CO2 consumption by mineral weathering. We calculate an increase of about 3% of the CO2 consumption through silicate weathering (mol ha-1 yr-1) for 100 ppmv rise in CO2. Importantly, the sensitivity of the weathering system to the CO2 rise is not uniform and heavily depends on the climatic, lithologic, pedologic, and biospheric settings.

  6. Geochemistry of large river suspended sediments: Silicate weathering or recycling tracer?

    SciTech Connect

    Gaillardet, J.; Dupre, B.; Allegre, C.J.

    1999-12-01

    This study focuses on the major and trace element composition of suspended sediments transported by the world's largest rivers. Its main purpose is to answer the following question: is the degree of weathering of modern river-borne particles consistent with the estimated river dissolved loads derived from silicate weathering? In agreement with the well known mobility of elements during weathering of continental rocks, the authors confirm that river sediments are systematically depleted in Na, K, Ba with respect to the Upper Continental Crust. For each of these mobile elements, a systematics of weathering indexes of river-borne solids is attempted. A global consistency is found between all these indexes. Important variations in weathering intensities exist. A clear dependence of weathering intensities with climate is observed for the rivers draining mostly lowlands. However, no global correlation exists between weathering intensities and climatic or relief parameters because the trend observed for lowlands is obscured by rivers draining orogenic zones. An inverse correlation between weathering intensities and suspended sediment concentrations is observed showing that the regions having the highest rates of physical denudation produce the least weathered sediments. Finally, chemical and physical weathering are compared through the use of a simple steady state model. The authors show that the weathering intensities of large river suspended sediments can only be reconciled with the (silicate-derived) dissolved load or rivers, by admitting that most of the continental rocks submitted to weathering in large river basins have already suffered previous weathering cycles. A simple graphical method is proposed for calculating the proportion of sedimentary recycling in large river basins. Finally, even if orogenic zones produce weakly weathered sediments, the authors emphasize the fact that silicate chemical weathering rates (and hence CO{sub 2} consumption rates by silicate

  7. Lithium Isotopes as Proxy of Continental Silicate Weathering

    NASA Astrophysics Data System (ADS)

    Liu, X. M.; Wanner, C.; Rudnick, R. L.; McDonough, W. F.

    2014-12-01

    Chemical weathering has an important influence on continental crust evolution, as weathering of basalt preferentially removes soluble elements, such as Mg and Ca, and can shift the crust towards more andesitic compositions, thus helping to solve the crustal composition paradox. The isotopic compositions of soluble elements (e.g., Li and Mg) provide a monitor of chemical weathering of the continents through time. Here we evaluate the factors influencing the abundance, [Li], and isotopic composition of riverine Li delivered to the oceans through analyses and modeling of [Li] and d7Li in streams and groundwaters draining a single continental lithology, the Columbia River Basalts (CRBs). The streams were sampled in different climate zones that lie on the dry and wet sides of the Cascades Mountains, and during two different seasons (summer and late winter) in order to evaluate climatic and seasonal influences on Li isotopes in rivers. Dissolved Li (δ7Li = +9.3 to +30.4) is systematically heavier than that of fresh or weathered CRBs, suspended loads (-5.9 to -0.3), and shallow groundwaters (+6.7 to +9.4). Continued isotopic fractionation between stream water and suspended and/or bed loads has a major influence on riverine δ7Li as indicated by the heavier Li in streams, compared to the shallow groundwaters that feed them. Seasonal δ7Li variation is observed only for streams west of the Cascades, where the difference in precipitation rate between the seasons is greatest. Reactive transport model simulations reveal that riverine δ7Li is strongly controlled by subsurface residence times and Li isotope fractionation occurring within rivers. The varying residence times for groundwaters feeding the western streams in summer (long residence times, higher δ7Li, greater weathering) and winter (short residence times, lower δ7Li, less weathering) explains the observed seasonal variations. A global, negative correlation between δ7Li and Li/Na for streams and rivers draining

  8. Silicate weathering and CO2 consumption within agricultural landscapes, the Ohio-Tennessee River Basin

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Myriad studies have shown the extent of human alteration to global biogeochemical cycles. Yet, there is only a limited understanding of the influence that humans have over silicate weathering fluxes; fluxes that have regulated atmospheric carbon dioxide concentrations and global climate over geologi...

  9. The geoengineering potential of artificially enhanced silicate weathering of olivine

    NASA Astrophysics Data System (ADS)

    Köhler, Peter; Hartmann, Jens; Wolf-Gladrow, Dieter A.

    2010-05-01

    Geoengineering is a proposed action to manipulate Earth's climate in order to counteract global warming from anthropogenic greenhouse gas emissions. We investigate in more detail the potential of a specific geoengineering technique, the carbon sequestration by artificially enhanced silicate weathering via the dissolution of olivine. This approach would not only operate against rising temperatures but would also oppose ocean acidification, because it influences the global climate via the carbon cycle. We here show the consequences of this technique for the chemistry of the surface ocean at rates necessary for geoengineering. We calculate that olivine dissolution has the potential to sequestrate up to one Pg C yr-1 directly, if olivine is distributed as fine powder over land areas of the humid tropics. The carbon sequestration potential is limited by the saturation concentration of silicic acid. In our calculations for the Amazon and Congo river catchments a maximum annual dissolution of 1.8 and 0.4 Pg of olivine seems possible, corresponding to the sequestration of 0.5 and 0.1 Pg C yr-1. Open water dissolution of fine grained olivine and an enhancement of the biological pump by the rising riverine input of silicic acid might increase our estimate of the carbon sequestration, but additional research is needed here. We finally calculate with a carbon cycle model the consequences of sequestration rates of 1 to 5 Pg C yr-1 for the 21st century by this technique. At maximum this technique would reduce global warming by 1 K and counteract ocean acidification by a rise in surface ocean pH by 0.1 in the year 2100.

  10. Geoengineering potential of artificially enhanced silicate weathering of olivine.

    PubMed

    Köhler, Peter; Hartmann, Jens; Wolf-Gladrow, Dieter A

    2010-11-23

    Geoengineering is a proposed action to manipulate Earth's climate in order to counteract global warming from anthropogenic greenhouse gas emissions. We investigate the potential of a specific geoengineering technique, carbon sequestration by artificially enhanced silicate weathering via the dissolution of olivine. This approach would not only operate against rising temperatures but would also oppose ocean acidification, because it influences the global climate via the carbon cycle. If important details of the marine chemistry are taken into consideration, a new mass ratio of CO(2) sequestration per olivine dissolution of about 1 is achieved, 20% smaller than previously assumed. We calculate that this approach has the potential to sequestrate up to 1 Pg of C per year directly, if olivine is distributed as fine powder over land areas of the humid tropics, but this rate is limited by the saturation concentration of silicic acid. In our calculations for the Amazon and Congo river catchments, a maximum annual dissolution of 1.8 and 0.4 Pg of olivine seems possible, corresponding to the sequestration of 0.5 and 0.1 Pg of C per year, but these upper limit sequestration rates come at the environmental cost of pH values in the rivers rising to 8.2. Open water dissolution of fine-grained olivine and an enhancement of the biological pump by the rising riverine input of silicic acid might increase our estimate of the carbon sequestration, but additional research is needed here. We finally calculate with a carbon cycle model the consequences of sequestration rates of 1-5 Pg of C per year for the 21st century by this technique.

  11. Geoengineering potential of artificially enhanced silicate weathering of olivine

    PubMed Central

    Köhler, Peter; Hartmann, Jens; Wolf-Gladrow, Dieter A.

    2010-01-01

    Geoengineering is a proposed action to manipulate Earth’s climate in order to counteract global warming from anthropogenic greenhouse gas emissions. We investigate the potential of a specific geoengineering technique, carbon sequestration by artificially enhanced silicate weathering via the dissolution of olivine. This approach would not only operate against rising temperatures but would also oppose ocean acidification, because it influences the global climate via the carbon cycle. If important details of the marine chemistry are taken into consideration, a new mass ratio of CO2 sequestration per olivine dissolution of about 1 is achieved, 20% smaller than previously assumed. We calculate that this approach has the potential to sequestrate up to 1 Pg of C per year directly, if olivine is distributed as fine powder over land areas of the humid tropics, but this rate is limited by the saturation concentration of silicic acid. In our calculations for the Amazon and Congo river catchments, a maximum annual dissolution of 1.8 and 0.4 Pg of olivine seems possible, corresponding to the sequestration of 0.5 and 0.1 Pg of C per year, but these upper limit sequestration rates come at the environmental cost of pH values in the rivers rising to 8.2. Open water dissolution of fine-grained olivine and an enhancement of the biological pump by the rising riverine input of silicic acid might increase our estimate of the carbon sequestration, but additional research is needed here. We finally calculate with a carbon cycle model the consequences of sequestration rates of 1–5 Pg of C per year for the 21st century by this technique. PMID:21059941

  12. Global weather research

    NASA Technical Reports Server (NTRS)

    1981-01-01

    Modeling, prediction, and analysis of global meteorological phenomena influencing the large scale behavior of the atmosphere are summarized. Prediction of global weather phenomena based on satellite data is discussed and models of global phenomena developed. The atmospheric general circulation model (AGCE) is reviewed, axisymmetric flow calculated, and axisymmetric states in cylindrical, spherical, three dimensional, and spin up numerical models for AGCE described. The role of latent heat release in baroclinic waves, latent heat and cyclonic systems, and a theoretical study of baroclinic flow related to the AGCE and the flow regime were studied with a simplified general circulation model. AGCE and the geophysical fluid flow cell (GFFC) instrumentation are discussed. Investigation of solar and planetary convection for GFFC is described. The utilization of satellite cloud observations to diagnose the energy state and transformations in extratropical cyclones is reviewed.

  13. Grasslands, silicate weathering and diatoms: Cause and effect

    SciTech Connect

    Johansson, A.K. . Dept. of Geological Sciences)

    1993-03-01

    Diatoms are silica-limited, photosynthetic, single-celled eukaryotes that today occupy a wide variety of habitats both in freshwater and marine environments. Ultimately the silica they use is derived from the weathering of silicates on land. Although marine diatoms first appear in the Jurassic, the fossil record shows a remarkable correlation between the Mid-Miocene appearance of widespread grasslands and the drastic increase in diatom-rich deposits in freshwater, as well as in marine environments throughout the world. Grasses actively weather silicates, accumulating soluble silica into their leaves. Decomposing grasses release this soluble silica into the soil from whence it is transported into lakes and oceans and made available to diatoms. Grasses also probably increased chemical weathering, and hence the release of soluble silica, in previously weakly vegetated semi-arid areas. Increased weathering of silicates also led to cooler climates as evidenced by the Mid-Miocene [delta][sup 18]O record. The author suggests that the Tertiary expansion of grasslands is responsible for the explosive increase in diversity and abundance of diatoms in the oceans and freshwaters of the Mid-Miocene.

  14. An Evaluation of Ethyl Silicate-Based Grouts for Weathered Silicate Stones

    NASA Astrophysics Data System (ADS)

    Dolph, Brittany Helen

    Culturally significant monuments made of weathered siliceous stone often display sub-surface condition issues such as cracks and voids. These issues require grouts that are ideally compatible with the composition and properties of the substrate. Based on the successful application of ethyl silicates as consolidants in recent literature, this study examines possible formulation pathways for the development of a grout incorporating ethyl silicate. Tetraethylorthosilicate (TEOS), dibutyltin dilaurate (DBTL) as a catalyst, silicone oil (PDMS), various grades of ground quartz, sepiolite, and hollow glass spheres were used in differing concentrations to create samples. These were visually and physically assessed on workability, separation, shrinkage, cracking, strength, and flexibility. Quantitative analysis was performed on selected formulations using UV-Vis-NIR reflectance spectroscopy in coordination with a weight loss experiment to investigate kinetics, dynamic mechanical analysis (DMA), and scanning electron microscopy (SEM). Successful formulations tended to include oligomeric TEOS, crushed quartz of mixed grades, sepiolite powder, and PDMS, and show promise for future investigations.

  15. Silicate weathering and CO2 consumption within agricultural landscapes, the Ohio-Tennessee River Basin, USA

    NASA Astrophysics Data System (ADS)

    Fortner, S. K.; Lyons, W. B.; Carey, A. E.; Shipitalo, M. J.; Welch, S. A.; Welch, K. A.

    2012-03-01

    Myriad studies have shown the extent of human alteration to global biogeochemical cycles. Yet, there is only a limited understanding of the influence that humans have over silicate weathering fluxes; fluxes that have regulated atmospheric carbon dioxide concentrations and global climate over geologic timescales. Natural landscapes have been reshaped into agricultural ones to meet food needs for growing world populations. These processes modify soil properties, alter hydrology, affect erosion, and consequently impact water-soil-rock interactions such as chemical weathering. Dissolved silica (DSi), Ca2+, Mg2+, NO3-, and total alkalinity were measured in water samples collected from five small (0.0065 to 0.383 km2) gauged watersheds at the North Appalachian Experimental Watershed (NAEW) near Coshocton, Ohio, USA. The sampled watersheds in this unglaciated region include: a forested site (70+ year stand), mixed agricultural use (corn, forest, pasture), an unimproved pasture, tilled corn, and a recently (<3 yr) converted no-till corn field. The first three watersheds had perennial streams, but the two corn watersheds only produced runoff during storms and snowmelt. For the perennial streams, total discharge was an important control of dissolved silicate transport. Median DSi yields (2210-3080 kg km-2 yr-1) were similar to the median of annual averages between 1979-2009 for the much larger Ohio-Tennessee River Basin (2560 kg km-2 yr-1). Corn watersheds, which only had surface runoff, had substantially lower DSi yields (<530 kg km-2 yr-1) than the perennial-flow watersheds. The lack of contributions from Si-enriched groundwater largely explained their much lower DSi yields with respect to sites having baseflow. A significant positive correlation between the molar ratio of (Ca2++Mg2+)/alkalinity to DSi in the tilled corn and the forested site suggested, however, that silicate minerals weathered as alkalinity was lost via enhanced nitrification resulting from fertilizer

  16. Negative CO2 emissions via enhanced silicate weathering in coastal environments.

    PubMed

    Meysman, Filip J R; Montserrat, Francesc

    2017-04-01

    Negative emission technologies (NETs) target the removal of carbon dioxide (CO2) from the atmosphere, and are being actively investigated as a strategy to limit global warming to within the 1.5-2°C targets of the 2015 UN climate agreement. Enhanced silicate weathering (ESW) proposes to exploit the natural process of mineral weathering for the removal of CO2 from the atmosphere. Here, we discuss the potential of applying ESW in coastal environments as a climate change mitigation option. By deliberately introducing fast-weathering silicate minerals onto coastal sediments, alkalinity is released into the overlying waters, thus creating a coastal CO2 sink. Compared with other NETs, coastal ESW has the advantage that it counteracts ocean acidification, does not interfere with terrestrial land use and can be directly integrated into existing coastal management programmes with existing (dredging) technology. Yet presently, the concept is still at an early stage, and so two major research challenges relate to the efficiency and environmental impact of ESW. Dedicated experiments are needed (i) to more precisely determine the weathering rate under in situ conditions within the seabed and (ii) to evaluate the ecosystem impacts-both positive and negative-from the released weathering products.

  17. The time scale of the silicate weathering negative feedback on atmospheric CO2

    NASA Astrophysics Data System (ADS)

    Colbourn, G.; Ridgwell, A.; Lenton, T. M.

    2015-05-01

    The ultimate fate of CO2 added to the ocean-atmosphere system is chemical reaction with silicate minerals and burial as marine carbonates. The time scale of this silicate weathering negative feedback on atmospheric pCO2 will determine the duration of perturbations to the carbon cycle, be they geological release events or the current anthropogenic perturbation. However, there has been little previous work on quantifying the time scale of the silicate weathering feedback, with the primary estimate of 300-400 kyr being traceable to an early box model study by Sundquist (1991). Here we employ a representation of terrestrial rock weathering in conjunction with the "GENIE" (Grid ENabled Integrated Earth system) model to elucidate the different time scales of atmospheric CO2 regulation while including the main climate feedbacks on CO2 uptake by the ocean. In this coupled model, the main dependencies of weathering—runoff, temperature, and biological productivity—were driven from an energy-moisture balance atmosphere model and parameterized plant productivity. Long-term projections (1 Myr) were conducted for idealized scenarios of 1000 and 5000 PgC fossil fuel emissions and their sensitivity to different model parameters was tested. By fitting model output to a series of exponentials we determined the e-folding time scale for atmospheric CO2 drawdown by silicate weathering to be ˜240 kyr (range 170-380 kyr), significantly less than existing quantifications. Although the time scales for reequilibration of global surface temperature and surface ocean pH are similar to that for CO2, a much greater proportion of the peak temperature anomaly persists on this longest time scale; ˜21% compared to ˜10% for CO2.

  18. Silicate weathering and CO2 consumption within agricultural landscapes, the Ohio-Tennessee River Basin, USA

    NASA Astrophysics Data System (ADS)

    Fortner, S. K.; Lyons, W. B.; Carey, A. E.; Shipitalo, M. J.; Welch, S. A.; Welch, K. A.

    2011-09-01

    Myriad studies have shown the extent of human alteration to global biogeochemical cycles. Yet, there is only a limited understanding of the influence that humans have over silicate weathering fluxes; fluxes that have regulated atmospheric carbon dioxide concentrations and global climate over geologic timescales. Natural landscapes have been reshaped into agricultural ones to meet food needs for growing world populations. These processes modify soil properties, alter hydrology, affect erosion, and consequently impact water-soil-rock interactions such as chemical weathering. Dissolved silica (DSi), Ca2+, Mg2+, NO3-, and total alkalinity were measured in water samples collected from five small (0.65 to 38.3 ha) gauged watersheds at the North Appalachian Experimental Watershed (NAEW) near Coshocton, Ohio, USA. The sampled watersheds in this unglaciated region include: a forested site (70+ yr stand), mixed agricultural use (corn, forest, pasture), an unimproved pasture, tilled corn, and a recently (<3 yr) converted no-till corn field. The first three watersheds had perennial streams, but the two corn watersheds only produced runoff during storms and snowmelt. For the perennial streams, total discharge was an important control of dissolved silicate transport. Median DSi yields (22.1-30.8 kg ha-1 a-1) were similar to the median of annual averages between 1979-2009 for the much larger Ohio-Tennessee River Basin (25.6 kg ha-1 a-1). Corn watersheds, which only had surface runoff, had substantially lower DSi yields (<5.3 kg ha-1 a-1) than the perennial-flow watersheds. The lack of contributions from Si-enriched groundwater largely explained their much lower DSi yields with respect to sites having baseflow. A significant positive correlation between the molar ratio of (Ca2+ + Mg2)/alkalinity to DSi in the tilled corn and the forested site suggested, however, that silicate minerals weathered as alkalinity was lost via enhanced nitrification resulting from fertilizer additions

  19. Lithium isotope history of Cenozoic seawater: changes in silicate weathering and reverse weathering.

    PubMed

    Misra, Sambuddha; Froelich, Philip N

    2012-02-17

    Weathering of uplifted continental rocks consumes carbon dioxide and transports cations to the oceans, thereby playing a critical role in controlling both seawater chemistry and climate. However, there are few archives of seawater chemical change that reveal shifts in global tectonic forces connecting Earth ocean-climate processes. We present a 68-million-year record of lithium isotopes in seawater (δ(7)Li(SW)) reconstructed from planktonic foraminifera. From the Paleocene (60 million years ago) to the present, δ(7)Li(SW) rose by 9 per mil (‰), requiring large changes in continental weathering and seafloor reverse weathering that are consistent with increased tectonic uplift, more rapid continental denudation, increasingly incongruent continental weathering (lower chemical weathering intensity), and more rapid CO(2) drawdown. A 5‰ drop in δ(7)Li(SW) across the Cretaceous-Paleogene boundary cannot be produced by an impactor or by Deccan trap volcanism, suggesting large-scale continental denudation.

  20. Enhanced silicate weathering of tropical shelf sediments exposed during glacial lowstands: A sink for atmospheric CO2

    NASA Astrophysics Data System (ADS)

    Wan, Shiming; Clift, Peter D.; Zhao, Debo; Hovius, Niels; Munhoven, Guy; France-Lanord, Christian; Wang, Yinxi; Xiong, Zhifang; Huang, Jie; Yu, Zhaojie; Zhang, Jin; Ma, Wentao; Zhang, Guoliang; Li, Anchun; Li, Tiegang

    2017-03-01

    Atmospheric CO2 and global climate are closely coupled. Since 800 ka CO2 concentrations have been up to 50% higher during interglacial compared to glacial periods. Because of its dependence on temperature, humidity, and erosion rates, chemical weathering of exposed silicate minerals was suggested to have dampened these cyclic variations of atmospheric composition. Cooler and drier conditions and lower non-glacial erosion rates suppressed in situ chemical weathering rates during glacial periods. However, using systematic variations in major element geochemistry, Sr-Nd isotopes and clay mineral records from Ocean Drilling Program Sites 1143 and 1144 in the South China Sea spanning the last 1.1 Ma, we show that sediment deposited during glacial periods was more weathered than sediment delivered during interglacials. We attribute this to subaerial exposure and weathering of unconsolidated shelf sediments during glacial sealevel lowstands. Our estimates suggest that enhanced silicate weathering of tropical shelf sediments exposed during glacial lowstands can account for ∼9% of the carbon dioxide removed from the atmosphere during the glacial and thus represent a significant part of the observed glacial-interglacial variation of ∼80 ppmv. As a result, if similar magnitudes can be identified in other tropical shelf-slope systems, the effects of increased sediment exposure and subsequent silicate weathering during lowstands could have potentially enhanced the drawdown of atmospheric CO2 during cold stages of the Quaternary. This in turn would have caused an intensification of glacial cycles.

  1. Assessing Silicate Weathering in Permafrost-Dominated Catchments Using Lithium Isotopes: The Lena River, Siberia

    NASA Astrophysics Data System (ADS)

    Murphy, M. J.; Pogge von Strandmann, P.; Porcelli, D.; Katchinoff, J. A.; Moreras Martí, A.; Hirst, C. A.; Andersson, P. S.; Maximov, T. C.

    2015-12-01

    Rising global temperatures have the potential to influence the Earth's climate feedback cycles due to permafrost thawing, altering the freshwater input and trace metal and carbon fluxes into the ocean and atmosphere. Riverine lithium isotope ratios (d7Li) are a tracer of silicate weathering processes, which are key in the removal of atmospheric CO2 over geological timescales. Despite this, little is known about the effects of permafrost thawing on d7Li variations. Strong seasonal changes in the thawed active layer thickness dictate surficial water flow paths, which may influence intra-annual riverine d7Li signatures. We present a study of the dissolved d7Li from the large permafrost-dominated watersheds of the Lena River (Siberia), which drain into the Arctic Ocean. This work comprises a temporal study during the May 2015 spring flood, from ice breakup through peak flooding, thus monitoring changes in water-rock and water-soil interaction, both processes that control weathering and hence Li isotopes. Before riverine ice started to break up, high [Li] are observed as the river signature is governed by winter base flow conditions. As the river ice breaks up, surface runoff flows over the impermeable permafrost, interacting with leaf litter, diluting the [Li]. We compare d7Li over the spring flood period with a greater spatial study conducted over two summer field seasons (2012/2013) of the main Lena River channel and its tributaries, which drain a variety of lithologies/topographies. During the summer, the thawed active layer promotes deeper water flow paths, greater water-rock interaction and enhanced secondary minerals formation which preferentially take up 6Li. Summer riverine d7Li typically fall between +14.5 ‰ to +28.5 ‰, with rivers draining the Central Siberian Plateau typically exhibiting high [Li], but similar δ7Li to rivers draining the Verkhoyansk Mountain Range. Overall, this study demonstrates how Li isotopes respond to weathering in a permafrost

  2. Introducing GFWED: The Global Fire Weather Database

    NASA Technical Reports Server (NTRS)

    Field, R. D.; Spessa, A. C.; Aziz, N. A.; Camia, A.; Cantin, A.; Carr, R.; de Groot, W. J.; Dowdy, A. J.; Flannigan, M. D.; Manomaiphiboon, K.; Pappenberger, F.; Tanpipat, V.; Wang, X.

    2015-01-01

    The Canadian Forest Fire Weather Index (FWI) System is the mostly widely used fire danger rating system in the world. We have developed a global database of daily FWI System calculations, beginning in 1980, called the Global Fire WEather Database (GFWED) gridded to a spatial resolution of 0.5 latitude by 2-3 longitude. Input weather data were obtained from the NASA Modern Era Retrospective-Analysis for Research and Applications (MERRA), and two different estimates of daily precipitation from rain gauges over land. FWI System Drought Code calculations from the gridded data sets were compared to calculations from individual weather station data for a representative set of 48 stations in North, Central and South America, Europe, Russia,Southeast Asia and Australia. Agreement between gridded calculations and the station-based calculations tended to be most different at low latitudes for strictly MERRA based calculations. Strong biases could be seen in either direction: MERRA DC over the Mato Grosso in Brazil reached unrealistically high values exceeding DCD1500 during the dry season but was too low over Southeast Asia during the dry season. These biases are consistent with those previously identified in MERRAs precipitation, and they reinforce the need to consider alternative sources of precipitation data. GFWED can be used for analyzing historical relationships between fire weather and fire activity at continental and global scales, in identifying large-scale atmosphereocean controls on fire weather, and calibration of FWI-based fire prediction models.

  3. Introducing the Global Fire Weather Database (GFWED)

    NASA Astrophysics Data System (ADS)

    Field, Robert

    2016-04-01

    The Canadian Fire Weather Index (FWI) System is the mostly widely used fire danger rating system in the world. We have developed a global database of daily FWI System calculations beginning in 1980 called the Global Fire WEather Database (GFWED) gridded to a spatial resolution of 0.5° latitude by 2/3° longitude. Input weather data were obtained from the NASA Modern Era Retrospective-Analysis for Research (MERRA), and two different estimates of daily precipitation from rain gauges over land. FWI System Drought Code calculations from the gridded datasets were compared to calculations from individual weather station data for a representative set of 48 stations in North, Central and South America, Europe, Russia, Southeast Asia and Australia. Agreement between gridded calculations and the station-based calculations tended to be most different at low latitudes for strictly MERRA-based calculations. Strong biases could be seen in either direction: MERRA DC over the Mato Grosso in Brazil reached unrealistically high values exceeding DC=1500 during the dry season but was too low over Southeast Asia during the dry season. These biases are consistent with those previously-identified in MERRA's precipitation and reinforce the need to consider alternative sources of precipitation data. GFWED can be used for analyzing historical relationships between fire weather and fire activity at continental and global scales, in identifying large-scale atmosphere-ocean controls on fire weather, and calibration of FWI-based fire prediction models. These applications will be discussed.

  4. 40K-40Ca systematics as a tracer of silicate weathering in the Himalayas

    NASA Astrophysics Data System (ADS)

    Davenport, J.; Caro, G.; France-Lanord, C.

    2015-12-01

    Increased weathering resulting from the uplift of the Himalayan Mountains has been cited as one cause (among others) of late Cenozoic cooling. Orogenic uplift generally results in the development of high relief and enhanced erosion, which in turn induces rapid chemical weathering and uptake of atmospheric CO2. Tracing these processes can be accomplished using techniques such as the budget of major element and/or Sr isotopes of the dissolved load. However, in the Himalaya, Sr isotopic compositions are extreme even in carbonate phases, making it difficult to produce realistic estimates of silicate and carbonate inputs to Himalayan rivers. In this study, we explore the potential of the 40K-40Ca system to quantify the relative contributions of silicate and carbonate weathering to river dissolved loads. To this end, we analysed a suite of 40 rivers draining the main litho-tectonic units of the Himalaya, sediments, bedrock, mineral separates and soil and gravel. Our results show that Himalayan carbonates exhibit no radiogenic 40Ca excess despite highly variable 87Sr/86Sr signatures (0.73-0.85). The silicate fraction of bedload sediments is variably radiogenic (+1 to +4), with ɛ40Ca correlating with the 87Sr/86Sr ratio. Analyses of plagioclase, biotite and muscovite separates from a HHC gneiss and greywacke show homogeneous ɛ40Ca despite highly variable K/Ca ratios, indicating recent metamorphic equilibration on a mineral scale. Thus, incongruent weathering of high K/Ca minerals should not represent a significant factor when considering the transfer of radiogenic calcium to the dissolved load. The ɛ40Ca signatures of dissolved river material are significantly influenced by silicate lithologies, and range from +0.1 in carbonate dominated catchments to >+2 ɛ-units in rivers draining predominantly silicate catchments. The silicate contributions estimated from our 40Ca results are in line with major element budgets when considering small catchments but largely exceeds

  5. Global economic impacts of severe Space Weather.

    NASA Astrophysics Data System (ADS)

    Schulte In Den Baeumen, Hagen; Cairns, Iver

    Coronal mass ejections (CMEs) strong enough to create electromagnetic effects at latitudes below the auroral oval are frequent events, and could have substantial impacts on electric power transmission and telecommunication grids. Modern society’s heavy reliance on these domestic and international networks increases our susceptibility to such a severe Space Weather event. Using a new high-resolution model of the global economy we simulate the economic impact of large CMEs for 3 different planetary orientations. We account for the economic impacts within the countries directly affected as well as the post-disaster economic shock in partner economies through international trade. For the CMEs modeled the total global economic impacts would range from US 380 billion to US 1 trillion. Of this total economic shock 50 % would be felt in countries outside the zone of direct impact, leading to a loss in global GDP of 0.1 - 1 %. A severe Space Weather event could lead to global economic damages of the same order as other weather disasters, climate change, and extreme financial crisis.

  6. Introducing the Global Fire WEather Database (GFWED)

    NASA Astrophysics Data System (ADS)

    Field, R. D.

    2015-12-01

    The Canadian Fire Weather Index (FWI) System is the mostly widely used fire danger rating system in the world. We have developed a global database of daily FWI System calculations beginning in 1980 called the Global Fire WEather Database (GFWED) gridded to a spatial resolution of 0.5° latitude by 2/3° longitude. Input weather data were obtained from the NASA Modern Era Retrospective-Analysis for Research (MERRA), and two different estimates of daily precipitation from rain gauges over land. FWI System Drought Code calculations from the gridded datasets were compared to calculations from individual weather station data for a representative set of 48 stations in North, Central and South America, Europe, Russia, Southeast Asia and Australia. Agreement between gridded calculations and the station-based calculations tended to be most different at low latitudes for strictly MERRA-based calculations. Strong biases could be seen in either direction: MERRA DC over the Mato Grosso in Brazil reached unrealistically high values exceeding DC=1500 during the dry season but was too low over Southeast Asia during the dry season. These biases are consistent with those previously-identified in MERRA's precipitation and reinforce the need to consider alternative sources of precipitation data. GFWED is being used by researchers around the world for analyzing historical relationships between fire weather and fire activity at large scales, in identifying large-scale atmosphere-ocean controls on fire weather, and calibration of FWI-based fire prediction models. These applications will be discussed. More information on GFWED can be found at http://data.giss.nasa.gov/impacts/gfwed/

  7. Climatic and landscape controls on water transit times and silicate mineral weathering in the critical zone

    NASA Astrophysics Data System (ADS)

    Zapata-Rios, Xavier; McIntosh, Jennifer; Rademacher, Laura; Troch, Peter A.; Brooks, Paul D.; Rasmussen, Craig; Chorover, Jon

    2015-08-01

    The critical zone (CZ) can be conceptualized as an open system reactor that is continually transforming energy and water fluxes into an internal structural organization and dissipative products. In this study, we test a controlling factor on water transit times (WTT) and mineral weathering called Effective Energy and Mass Transfer (EEMT). We hypothesize that EEMT, quantified based on local climatic variables, can effectively predict WTT within—and mineral weathering products from—the CZ. This study tests whether EEMT or static landscape characteristics are good predictors of WTT, aqueous phase solutes, and silicate weathering products. Our study site is located around Redondo Peak, a rhyolitic volcanic resurgent dome, in northern New Mexico. At Redondo Peak, springs drain slopes along an energy gradient created by differences in terrain aspect. This investigation uses major solute concentrations, the calculated mineral mass undergoing dissolution, and the age tracer tritium and relates them quantitatively to EEMT and landscape characteristics. We found significant correlations between EEMT, WTT, and mineral weathering products. Significant correlations were observed between dissolved weathering products (Na+ and DIC), 3H concentrations, and maximum EEMT. In contrast, landscape characteristics such as contributing area of spring, slope gradient, elevation, and flow path length were not as effective predictive variables of WTT, solute concentrations, and mineral weathering products. These results highlight the interrelationship between landscape, hydrological, and biogeochemical processes and suggest that basic climatic data embodied in EEMT can be used to scale hydrological and hydrochemical responses in other sites.

  8. Isolation and the interaction between a mineral-weathering Rhizobium tropici Q34 and silicate minerals.

    PubMed

    Wang, Rong Rong; Wang, Qi; He, Lin Yan; Qiu, Gang; Sheng, Xia Fang

    2015-05-01

    The purposes of this study were to isolate and evaluate the interaction between mineral-weathering bacteria and silicate minerals (feldspar and biotite). A mineral-weathering bacterium was isolated from weathered rocks and identified as Rhizobium tropici Q34 based on 16S rRNA gene sequence analysis. Si and K concentrations were increased by 1.3- to 4.0-fold and 1.1- to 1.7-fold in the live bacterium-inoculated cultures compared with the controls respectively. Significant increases in the productions of tartaric and succinic acids and extracellular polysaccharides by strain Q34 were observed in cultures with minerals. Furthermore, significantly more tartaric acid and polysaccharide productions by strain Q34 were obtained in the presence of feldspar, while better growth and more citric acid production of strain Q34 were observed in the presence of biotite. Mineral dissolution experiments showed that the organic acids and polysaccharides produced by strain Q34 were also capable of promoting the release of Si and K from the minerals. The results showed that the growth and metabolite production of strain Q34 were enhanced in the presence of the minerals and different mineral exerted distinct impacts on the growth and metabolite production. The bio-weathering process is probably a synergistic action of organic acids and extracellular polysaccharides produced by the bacterium.

  9. Long-term stability of global erosion rates and weathering during late-Cenozoic cooling.

    PubMed

    Willenbring, Jane K; von Blanckenburg, Friedhelm

    2010-05-13

    Over geologic timescales, CO(2) is emitted from the Earth's interior and is removed from the atmosphere by silicate rock weathering and organic carbon burial. This balance is thought to have stabilized greenhouse conditions within a range that ensured habitable conditions. Changes in this balance have been attributed to changes in topographic relief, where varying rates of continental rock weathering and erosion are superimposed on fluctuations in organic carbon burial. Geological strata provide an indirect yet imperfectly preserved record of this change through changing rates of sedimentation. Widespread observations of a recent (0-5-Myr) fourfold increase in global sedimentation rates require a global mechanism to explain them. Accelerated uplift and global cooling have been given as possible causes, but because of the links between rates of erosion and the correlated rate of weathering, an increase in the drawdown of CO(2) that is predicted to follow may be the cause of global climate change instead. However, globally, rates of uplift cannot increase everywhere in the way that apparent sedimentation rates do. Moreover, proxy records of past atmospheric CO(2) provide no evidence for this large reduction in recent CO(2) concentrations. Here we question whether this increase in global weathering and erosion actually occurred and whether the apparent increase in the sedimentation rate is due to observational biases in the sedimentary record. As evidence, we recast the ocean dissolved (10)Be/(9)Be isotope system as a weathering proxy spanning the past approximately 12 Myr (ref. 14). This proxy indicates stable weathering fluxes during the late-Cenozoic era. The sum of these observations shows neither clear evidence for increased erosion nor clear evidence for a pulse in weathered material to the ocean. We conclude that processes different from an increase in denudation caused Cenozoic global cooling, and that global cooling had no profound effect on spatially and

  10. 40K-40Ca systematics as a Tracer of Silicate Weathering: A Himalayan case study

    NASA Astrophysics Data System (ADS)

    Davenport, Jesse; Caro, Guillaume; France-Lanord, Christian

    2015-04-01

    This study investigates the use of the 40K-40Ca system as a tracer to better quantify the contributions of silicate and carbonate lithologies in the dissolved load of major Himalayan rivers. Previous work using Sr isotopes as a proxy for silicate weathering has been complicated by the redistribution of radiogenic 87Sr between silicate and carbonate lithologies, particularly in the Lesser Himalaya, where dolomites exhibit 87Sr/86Sr ratios as high as 0.85. The 40Ca signature of carbonates, on the other hand, appears to be remarkably resistant to metamorphism and dolomitization [1]. It was therefore anticipated that the 40K-40Ca system could circumvent issues associated with such secondary events, and yield more robust constraints on the relative contribution of silicate vs. carbonate lithologies in dissolved river loads. The main difficulty in applying the 40K-40Ca decay scheme as a tracer lies in the analytical precision required to measure small variations (~1 ɛ-unit) on the large 40Ca isotope (96.9%). This difficulty can now be overcome using the Finnigan Triton TIMS, which allows measurements of the 40Ca/44Ca ratio with external precision of 0.35 ɛ-unit in multidynamic mode. Using this method, we generated high-precision 40Ca data on carbonates/dolomites, bedload sediments, dissolved load, and clay samples originating from and representing the main litho-tectonic units of the Himalaya. Our results show that metamorphosed dolomites from the Lesser Himalaya (LH) exhibit no radiogenic 40Ca excess despite highly variable 87Sr/86Sr signatures (0.73-0.85). Thus, all Himalayan carbonates appear to be characterized by a homogeneous ɛ40Ca=0. In contrast, silicate material is radiogenic, with ɛ40Ca averaging +1 in the Tethyan Sedimentary Series (TSS), +1.6 in the High Himalaya crystalline (HHC) and +4 ɛ-units in the LH. Results obtained from a series of 35 Himalayan rivers (including the Brahmaputra, Ganga and its main tributaries) show that ɛ40Ca in the

  11. Microbial control of silicate weathering in organic-rich ground water

    USGS Publications Warehouse

    Hiebert, Franz K.; Bennett, Philip C.

    1992-01-01

    An in situ microcosm study of the influence of surface-adhering bacteria on silicate diagenesis in a shallow petroleum-contaminated aquifer showed that minerals were colonized by indigenous bacteria and chemically weathered at a rate faster than theoretically predicted. Feldspar and quartz fragments were placed in anoxic, organic-rich ground water, left for 14 months, recovered, and compared to unreacted controls with scanning electron microscopy. Ground-water geochemistry was characterized before and after the experiment. Localized mineral etching probably occurred in a reaction zone at the bacteria-mineral interface where high concentrations of organic acids, formed by bacteria during metabolism of hydrocarbon, selectively mobilized silica and aluminum from the mineral surface.

  12. Marine silicate weathering in the anoxic sediment of the Ulleung Basin: Evidence and consequences

    NASA Astrophysics Data System (ADS)

    Kim, Ji-Hoon; Torres, Marta E.; Haley, Brian A.; Ryu, Jong-Sik; Park, Myong-Ho; Hong, Wei-Li; Choi, Jiyoung

    2016-08-01

    Marine silicate weathering (MSiW) in anoxic sediments has been recently shown to be a significant sink for CO2 generated by methanogenesis. Independently, the roles of clay dehydration (illitization) in producing water and driving upward fluid advection have been well established in deep marine sediments, but to date the K+ source required for the reaction has not been established. Here we present chemical and strontium isotope properties of pore fluids from seven cores in the Ulleung Basin, which show radiogenic 87Sr/86Sr values (up to ˜0.71045), very high alkalinity values (maximum ˜130 mM), and enrichment in H4SiO4, Na+, K+, and Mg2+, consistent with MSiW. This reaction consumes CO2, generates alkalinity, and acts as a K+ source for illitization; water released from MSiW-supported illitization drives upward fluid flow. Our results highlight the importance of MSiW along continental margins and its underappreciated role in carbon cycling, silicate diagenesis, and hydrogeology of marine systems.

  13. BET surface area distributions in polar stream sediments: Implications for silicate weathering in a cold-arid environment

    USGS Publications Warehouse

    Marra, Kristen R.; Elwood Madden, Megan E; Soreghan, Gerilyn S.; Hall, Brenda L

    2014-01-01

    BET surface area values are critical for quantifying the amount of potentially reactive sediments available for chemical weathering and ultimately, prediction of silicate weathering fluxes. BET surface area values of fine-grained (<62.5 μm) sediment from the hyporheic zone of polar glacial streams in the McMurdo Dry Valleys, Antarctica (Wright and Taylor Valleys) exhibit a wide range (2.5–70.6 m2/g) of surface area values. Samples from one (Delta Stream, Taylor Valley) of the four sampled stream transects exhibit high values (up to 70.6 m2/g), which greatly exceed surface area values from three temperate proglacial streams (0.3–12.1 m2/g). Only Clark stream in Wright Valley exhibits a robust trend with distance, wherein surface area systematically decreases (and particle size increases) in the mud fraction downstream, interpreted to reflect rapid dissolution processes in the weathering environment. The remaining transects exhibit a range in variability in surface area distributions along the length of the channel, likely related to variations in eolian input to exposed channel beds, adjacent snow drifts, and to glacier surfaces, where dust is trapped and subsequently liberated during summer melting. Additionally, variations in stream discharge rate, which mobilizes sediment in pulses and influences water:rock ratios, the origin and nature of the underlying drift material, and the contribution of organic acids may play significant roles in the production and mobilization of high-surface area sediment. This study highlights the presence of sediments with high surface area in cold-based glacier systems, which influences models of chemical denudation rates and the impact of glacial systems on the global carbon cycle.

  14. Silicate versus carbonate weathering in Iceland: New insights from Ca isotopes

    NASA Astrophysics Data System (ADS)

    Jacobson, Andrew D.; Grace Andrews, M.; Lehn, Gregory O.; Holmden, Chris

    2015-04-01

    Several studies have measured riverine fluxes of Ca and carbonate alkalinity in Iceland with the aim of quantifying the role of basalt weathering in the long-term carbon cycle. A major assumption is that all of the Ca and alkalinity originates from the dissolution of Ca-bearing silicate minerals, such as plagioclase and clinopyroxene. However, hydrothermal calcite occurs throughout Iceland, and even trace levels are expected to impact river geochemistry owing to the mineral's high solubility and fast dissolution rate. To test this hypothesis, we used a new, high-precision Ca isotope MC-TIMS method (δ44/40Ca; 2σSD = ± 0.04 ‰) to trace sources of Ca in Icelandic rivers. We report elemental and Ca isotope data for rivers, high- and low-temperature groundwater, basalt, hydrothermal calcite (including Iceland Spar), and stilbite and heulandite, which are two types of zeolites commonly formed during low-grade metamorphism of basalt. In agreement with previous research, we find that rivers have higher δ44/40Ca values than basalt, with a maximum difference of ∼0.40‰. This difference may reflect isotope fractionation in the weathering zone, i.e., preferential uptake of 40Ca during clay mineral formation, adsorption, and other geochemical processes that cycle Ca. However, calcite δ44/40Ca values are also up to ∼0.40‰ higher than bedrock values, and on a diagram of δ44/40Ca versus Sr/Ca, nearly all waters plot within a plausible mixing domain bounded by the measured compositions of basalt and calcite, with glacial rivers plotting closer to calcite than non-glacial rivers. Calcite and heulandite form during hydrothermal alteration of basalt in the deep lava pile and often occur together in metabasalts now exposed at the surface. Because heulandite δ44/40Ca values are ∼1-2‰ lower than basalt, we suggest that 40Ca uptake by heudlandite explains the relatively high δ44/40Ca values of calcite and that calcite weathering in turn elevates riverine δ44/40Ca

  15. Electrochemical Acceleration of Carbonate and Silicate Weathering for CO2 Mitigation

    NASA Astrophysics Data System (ADS)

    Rau, G. H.; Carroll, S.

    2011-12-01

    Carbonate and many silicate minerals dissolve in strong acids, and such acids are commonly generated at the anode of a conventional saline water electrolysis cell. It was therefore reasoned that encasing such an anode with base minerals would lead to enhanced mineral dissolution and hence increased hydroxide (base) generation at the cathode, formed in course of splitting water, generating H2 and OH-. Subsequent exposue of the alkalized solution to CO2 (e.g., as in air) would lead to absorption of the CO2 and formation of stable dissolved or solid (bi)carbonates for carbon sequestration. Previously, it has been demonstrated that mineral carbonate encasement of a seawater electrolysis cell anode indeed generated basic solutions in excess of pH 9 that were subsequently neutralized via contact with air CO2, increasing the carbon content of the initial seawater by 30% (Rau, G.H. 2008. Environ Sci. Techol. 42, 8935-). To test such a weathering/CO2 capture scheme using silicate minerals, either powdered wollastonite or ultramafic rock standard (UM-4) was encased around the anode of an electrolysis cell composed of graphite electrodes and a 0.25M Na2SO4 electrolyte solution. After 0.5 to 1.5 hrs of electricity application (3.5Vdc, 5-10mA), the electrolyte pH rose to as much as 11.1 (initial and blank solution pH's <6.6). Subequent bubbling of these basic solutions with air lowered pH by at least 2 units and increased dissolve carbon content (primarily bicarbonate) by as much as 50X that of the blanks. While Ca2+ and Mg2+ concentrations were elevated, these were insufficient to balance the majority of the bicarbonate anions formed in solution. This suggests that in these experiments the silicate minerals acted as a neutralizer of the anolyte acid, H2SO4, forming mostly insoluble CaSO4 and MgSO4 at the anode. This then allowed NaOH normally produced at the cathode to accumulate in solution, in turn reacting with air CO2 to form NaHCO3. Longer electrolysis times and

  16. The contribution of weathering of the main Alpine rivers on the global carbon cycle

    NASA Astrophysics Data System (ADS)

    Donnini, Marco; Probst, Jean-Luc; Probst, Anne; Frondini, Francesco; Marchesini, Ivan; Guzzetti, Fausto

    2013-04-01

    classification of Meybeck (1986, 1987). Then for each basin we computed Rsil weighted average considering the surface and the mean precipitation for the surface area of each lithology. Lastly, we estimated the (Ca+Mg) originating from carbonate weathering as the remaining cations after silicate correction. Depending on time-scales of the phenomena (shorter than about 1 million year i.e., correlated to the short term carbon cycle, or longer than about 1 million years i.e., correlated to the long-term carbon cycle), we considered different equations for the quantification of the atmospheric CO2 consumed by weathering (Huh, 2010). The results show the net predominance of carbonate weathering on fixing atmospheric CO2 and that, considering the long-term carbon cycle, the amount of atmospheric CO2 uptake by weathering is about one order of magnitude lower than considering the short-term carbon cycle. Moreover, considering the short-term carbon cycle, the mean CO2 consumed by Alpine basins is of the same order of magnitude of the mean CO2 consumed by weathering by the 60 largest rivers of the world estimated by Gaillardet et al. (1999). References Amiotte-Suchet, P. "Cycle Du Carbone, Érosion Chimique Des Continents Et Transfert Vers Les Océans." Sci. Géol. Mém. Strasbourg 97 (1995): 156. Amiotte-Suchet, P., and J.-L. Probst. "Origins of dissolved inorganic carbon in the Garonne river waters: seasonal and interannual variations." Sci. Géologiques Bull. Strasbourg 49, no. 1-4 (1996): 101-126. Berner, E.K., and R.A. Berner. The Global Water Cycle. Geochemistry and Environment. Prentice Halle. Engelwood Cliffs, NJ, 1987. Drever, J.L. The Geochemistry of Natural Waters. Prentice Hall, 1982. Gaillardet, J., B. Dupré, P. Louvat, and C.J. Allègre. "Global Silicate Weathering and CO2 Consumption Rates Deduced from the Chemistry of Large Rivers." Chemical Geology 159 (1999): 3-30. Garrels, R.M., and F.T. Mackenzie. Evolution of Sedimentary Rocks. New York: W.W. Nortonand, 1971. Huh, Y

  17. Continental igneous rock composition: A major control of past global chemical weathering

    PubMed Central

    Bataille, Clément P.; Willis, Amy; Yang, Xiao; Liu, Xiao-Ming

    2017-01-01

    The composition of igneous rocks in the continental crust has changed throughout Earth’s history. However, the impact of these compositional variations on chemical weathering, and by extension on seawater and atmosphere evolution, is largely unknown. We use the strontium isotope ratio in seawater [(87Sr/86Sr)seawater] as a proxy for chemical weathering, and we test the sensitivity of (87Sr/86Sr)seawater variations to the strontium isotopic composition (87Sr/86Sr) in igneous rocks generated through time. We demonstrate that the 87Sr/86Sr ratio in igneous rocks is correlated to the epsilon hafnium (εHf) of their hosted zircon grains, and we use the detrital zircon record to reconstruct the evolution of the 87Sr/86Sr ratio in zircon-bearing igneous rocks. The reconstructed 87Sr/86Sr variations in igneous rocks are strongly correlated with the (87Sr/86Sr)seawater variations over the last 1000 million years, suggesting a direct control of the isotopic composition of silicic magmatism on (87Sr/86Sr)seawater variations. The correlation decreases during several time periods, likely reflecting changes in the chemical weathering rate associated with paleogeographic, climatic, or tectonic events. We argue that for most of the last 1000 million years, the (87Sr/86Sr)seawater variations are responding to changes in the isotopic composition of silicic magmatism rather than to changes in the global chemical weathering rate. We conclude that the (87Sr/86Sr)seawater variations are of limited utility to reconstruct changes in the global chemical weathering rate in deep times. PMID:28345044

  18. Continental igneous rock composition: A major control of past global chemical weathering.

    PubMed

    Bataille, Clément P; Willis, Amy; Yang, Xiao; Liu, Xiao-Ming

    2017-03-01

    The composition of igneous rocks in the continental crust has changed throughout Earth's history. However, the impact of these compositional variations on chemical weathering, and by extension on seawater and atmosphere evolution, is largely unknown. We use the strontium isotope ratio in seawater [((87)Sr/(86)Sr)seawater] as a proxy for chemical weathering, and we test the sensitivity of ((87)Sr/(86)Sr)seawater variations to the strontium isotopic composition ((87)Sr/(86)Sr) in igneous rocks generated through time. We demonstrate that the (87)Sr/(86)Sr ratio in igneous rocks is correlated to the epsilon hafnium (εHf) of their hosted zircon grains, and we use the detrital zircon record to reconstruct the evolution of the (87)Sr/(86)Sr ratio in zircon-bearing igneous rocks. The reconstructed (87)Sr/(86)Sr variations in igneous rocks are strongly correlated with the ((87)Sr/(86)Sr)seawater variations over the last 1000 million years, suggesting a direct control of the isotopic composition of silicic magmatism on ((87)Sr/(86)Sr)seawater variations. The correlation decreases during several time periods, likely reflecting changes in the chemical weathering rate associated with paleogeographic, climatic, or tectonic events. We argue that for most of the last 1000 million years, the ((87)Sr/(86)Sr)seawater variations are responding to changes in the isotopic composition of silicic magmatism rather than to changes in the global chemical weathering rate. We conclude that the ((87)Sr/(86)Sr)seawater variations are of limited utility to reconstruct changes in the global chemical weathering rate in deep times.

  19. Notes on a Vision for the Global Space Weather Enterprise

    NASA Astrophysics Data System (ADS)

    Head, James N.

    2015-07-01

    Space weather phenomena impacts human civilization on a global scale and hence calls for a global approach to research, monitoring, and operational forecasting. The Global Space Weather Enterprise (GSWE) could be arranged along lines well established in existing international frameworks related to space exploration or to the use of space to benefit humanity. The Enterprise need not establish a new organization, but could evolve from existing international organizations. A GSWE employing open architectural concepts could be arranged to promote participation by all interested States regardless of current differences in science and technical capacity. Such an Enterprise would engender capacity building and burden sharing opportunities.

  20. Silicate or Carbonate Weathering: Fingerprinting Sources of Dissolved Inorganic Carbon Using δ13C in a Tropical River, Southern India

    NASA Astrophysics Data System (ADS)

    Bhagat, H.; Ghosh, P.

    2015-12-01

    Rivers are an inherently vital resource for the development of any region and their importance is highlighted by the presence of many ancient human civilizations adjacent to river systems. δ13C - Si/HCO3 systematics has been applied to large south Indian rivers which drain the Deccan basaltic traps in order to quantify their relative contributions from silicate and carbonate weathering. This study investigates δ13C - Si/HCO3 systematics of the Cauvery River basin which flows through silicate lithology in the higher reaches and carbonate lithology with pedogenic and marine carbonates dominating the terrain in the lower reaches of the basin. The samples for the present study were collected at locations within the watershed during Pre-Monsoon and Monsoon Season 2014. The measurements of stable isotope ratios of δ13CDIC and were accomplished through a Thermo Scientific GasBench II interface connected to a MAT 253 IRMS. We captured a large spatial variation in δ13C and Si/HCO3 values during both seasons; Pre-Monsoon δ13C values ranges between -17.57‰ to -4.02‰ and during Monsoon it varies between -9.19‰ to +0.61‰. These results indicate a two end-member mixing component i.e. a silicate and a carbonate end member; governing the weathering interactions of the Cauvery River. Within the drainage basin, we identified silicate and carbonate dominating sources by using contributions of DIC and δ13C. Si/HCO3 values for Pre-Monsoon ranges between 0.028 - 0.67 and for Monsoon it varies between 0.073 - 0.80. Lighter δ13C composition was observed at sampling sites at higher altitude in contrast to sampling sites at flood plain which show relatively enriched δ13C which indicate mixing of soil derived CO2 with C4 plants. Result suggests dominance of carbonate weathering during the Monsoon Period, while silicate weathering is pronounced during Pre- Monsoon period.

  1. Global Weather's Problem Child--El Nino.

    ERIC Educational Resources Information Center

    Rasmusson, Eugene M.

    1984-01-01

    Discusses the nature and effects of the El Nino/Southern Oscillation phenomenon. Indicates that new understanding of the phenomenon from current data will provide a global view of climate that has never before been within reach. (JN)

  2. Economic value of global weather measurements

    SciTech Connect

    Canavan, G.; Butterworth, J.

    1999-02-19

    Global sensor networks could support increased activity in a number of economic sectors. Potential benefits and the predicted time scales required to realize them are estimated. Benefits are particular compelling for fundamental reasons for aviation, hotels and restaurants, natural disasters, construction, agriculture, and apparel. These benefits can be captured by simple logistic approximations.

  3. Global Navigation Satellite Systems and Space Weather: Building upon the International Space Weather Initiative

    NASA Astrophysics Data System (ADS)

    Gadimova, S. H.; Haubold, H. J.

    2014-01-01

    Globally there is growing interest in better unders tanding solar-terrestrial interactions, particularly patterns and trends in space weather. This is not only for scientific reasons, but also because the reliable operation of ground-based and space-based assets and infrastructures is increasingly dependent on their robustness against the detrimental effects of space weather. Consequently, in 2009, the United Nations Committee on the Peaceful Uses of Outer Space (COPUOS) proposed the International Space Weather Initiative (ISWI), as a follow-up activity to the International Heliophysical Year 2007 (IHY2007), to be implemented under a three-year workplan from 2010 to 2012 (UNGA Document, A/64/20). All achievements of international cooperation and coordination for ISWI, including instrumentation, data analysis, modelling, education, training and public outreach, are made a vailable through the ISWI Newsletter and the ISWI Website (http://www.iswi-secretariat.org/). Since the last solar maximum in 2000, societal dependence on global navigation satellite system (GNSS) has increased substantially. This situation has brought increasing attention to the subject of space weather and its effects on GNSS systems and users. Results concerning the impact of space weather on GNSS are made available at the Information Portal (www.unoosa.org) of the International Committee on Global Navigati on Satellite Systems (ICG). This paper briefly reviews the curre nt status of ISWI with regard to GNSS.

  4. Global Weather Prediction and High-End Computing at NASA

    NASA Technical Reports Server (NTRS)

    Lin, Shian-Jiann; Atlas, Robert; Yeh, Kao-San

    2003-01-01

    We demonstrate current capabilities of the NASA finite-volume General Circulation Model an high-resolution global weather prediction, and discuss its development path in the foreseeable future. This model can be regarded as a prototype of a future NASA Earth modeling system intended to unify development activities cutting across various disciplines within the NASA Earth Science Enterprise.

  5. Effect of carbonic anhydrase on silicate weathering and carbonate formation at present day CO2 concentrations compared to primordial values

    PubMed Central

    Xiao, Leilei; Lian, Bin; Hao, Jianchao; Liu, Congqiang; Wang, Shijie

    2015-01-01

    It is widely recognized that carbonic anhydrase (CA) participates in silicate weathering and carbonate formation. Nevertheless, it is still not known if the magnitude of the effect produced by CA on surface rock evolution changes or not. In this work, CA gene expression from Bacillus mucilaginosus and the effects of recombination protein on wollastonite dissolution and carbonate formation under different conditions are explored. Real-time fluorescent quantitative PCR was used to explore the correlation between CA gene expression and sufficiency or deficiency in calcium and CO2 concentration. The results show that the expression of CA genes is negatively correlated with both CO2 concentration and ease of obtaining soluble calcium. A pure form of the protein of interest (CA) is obtained by cloning, heterologous expression, and purification. The results from tests of the recombination protein on wollastonite dissolution and carbonate formation at different levels of CO2 concentration show that the magnitudes of the effects of CA and CO2 concentration are negatively correlated. These results suggest that the effects of microbial CA in relation to silicate weathering and carbonate formation may have increased importance at the modern atmospheric CO2 concentration compared to 3 billion years ago. PMID:25583135

  6. Effect of carbonic anhydrase on silicate weathering and carbonate formation at present day CO2 concentrations compared to primordial values

    NASA Astrophysics Data System (ADS)

    Xiao, Leilei; Lian, Bin; Hao, Jianchao; Liu, Congqiang; Wang, Shijie

    2015-01-01

    It is widely recognized that carbonic anhydrase (CA) participates in silicate weathering and carbonate formation. Nevertheless, it is still not known if the magnitude of the effect produced by CA on surface rock evolution changes or not. In this work, CA gene expression from Bacillus mucilaginosus and the effects of recombination protein on wollastonite dissolution and carbonate formation under different conditions are explored. Real-time fluorescent quantitative PCR was used to explore the correlation between CA gene expression and sufficiency or deficiency in calcium and CO2 concentration. The results show that the expression of CA genes is negatively correlated with both CO2 concentration and ease of obtaining soluble calcium. A pure form of the protein of interest (CA) is obtained by cloning, heterologous expression, and purification. The results from tests of the recombination protein on wollastonite dissolution and carbonate formation at different levels of CO2 concentration show that the magnitudes of the effects of CA and CO2 concentration are negatively correlated. These results suggest that the effects of microbial CA in relation to silicate weathering and carbonate formation may have increased importance at the modern atmospheric CO2 concentration compared to 3 billion years ago.

  7. Impact of derived global weather data on simulated crop yields.

    PubMed

    van Wart, Justin; Grassini, Patricio; Cassman, Kenneth G

    2013-12-01

    Crop simulation models can be used to estimate impact of current and future climates on crop yields and food security, but require long-term historical daily weather data to obtain robust simulations. In many regions where crops are grown, daily weather data are not available. Alternatively, gridded weather databases (GWD) with complete terrestrial coverage are available, typically derived from: (i) global circulation computer models; (ii) interpolated weather station data; or (iii) remotely sensed surface data from satellites. The present study's objective is to evaluate capacity of GWDs to simulate crop yield potential (Yp) or water-limited yield potential (Yw), which can serve as benchmarks to assess impact of climate change scenarios on crop productivity and land use change. Three GWDs (CRU, NCEP/DOE, and NASA POWER data) were evaluated for their ability to simulate Yp and Yw of rice in China, USA maize, and wheat in Germany. Simulations of Yp and Yw based on recorded daily data from well-maintained weather stations were taken as the control weather data (CWD). Agreement between simulations of Yp or Yw based on CWD and those based on GWD was poor with the latter having strong bias and large root mean square errors (RMSEs) that were 26-72% of absolute mean yield across locations and years. In contrast, simulated Yp or Yw using observed daily weather data from stations in the NOAA database combined with solar radiation from the NASA-POWER database were in much better agreement with Yp and Yw simulated with CWD (i.e. little bias and an RMSE of 12-19% of the absolute mean). We conclude that results from studies that rely on GWD to simulate agricultural productivity in current and future climates are highly uncertain. An alternative approach would impose a climate scenario on location-specific observed daily weather databases combined with an appropriate upscaling method.

  8. Evaluating the effects of terrestrial ecosystems, climate and carbon dioxide on weathering over geological time: a global-scale process-based approach.

    PubMed

    Taylor, Lyla L; Banwart, Steve A; Valdes, Paul J; Leake, Jonathan R; Beerling, David J

    2012-02-19

    Global weathering of calcium and magnesium silicate rocks provides the long-term sink for atmospheric carbon dioxide (CO(2)) on a timescale of millions of years by causing precipitation of calcium carbonates on the seafloor. Catchment-scale field studies consistently indicate that vegetation increases silicate rock weathering, but incorporating the effects of trees and fungal symbionts into geochemical carbon cycle models has relied upon simple empirical scaling functions. Here, we describe the development and application of a process-based approach to deriving quantitative estimates of weathering by plant roots, associated symbiotic mycorrhizal fungi and climate. Our approach accounts for the influence of terrestrial primary productivity via nutrient uptake on soil chemistry and mineral weathering, driven by simulations using a dynamic global vegetation model coupled to an ocean-atmosphere general circulation model of the Earth's climate. The strategy is successfully validated against observations of weathering in watersheds around the world, indicating that it may have some utility when extrapolated into the past. When applied to a suite of six global simulations from 215 to 50 Ma, we find significantly larger effects over the past 220 Myr relative to the present day. Vegetation and mycorrhizal fungi enhanced climate-driven weathering by a factor of up to 2. Overall, we demonstrate a more realistic process-based treatment of plant fungal-geosphere interactions at the global scale, which constitutes a first step towards developing 'next-generation' geochemical models.

  9. Evaluating the effects of terrestrial ecosystems, climate and carbon dioxide on weathering over geological time: a global-scale process-based approach

    PubMed Central

    Taylor, Lyla L.; Banwart, Steve A.; Valdes, Paul J.; Leake, Jonathan R.; Beerling, David J.

    2012-01-01

    Global weathering of calcium and magnesium silicate rocks provides the long-term sink for atmospheric carbon dioxide (CO2) on a timescale of millions of years by causing precipitation of calcium carbonates on the seafloor. Catchment-scale field studies consistently indicate that vegetation increases silicate rock weathering, but incorporating the effects of trees and fungal symbionts into geochemical carbon cycle models has relied upon simple empirical scaling functions. Here, we describe the development and application of a process-based approach to deriving quantitative estimates of weathering by plant roots, associated symbiotic mycorrhizal fungi and climate. Our approach accounts for the influence of terrestrial primary productivity via nutrient uptake on soil chemistry and mineral weathering, driven by simulations using a dynamic global vegetation model coupled to an ocean–atmosphere general circulation model of the Earth's climate. The strategy is successfully validated against observations of weathering in watersheds around the world, indicating that it may have some utility when extrapolated into the past. When applied to a suite of six global simulations from 215 to 50 Ma, we find significantly larger effects over the past 220 Myr relative to the present day. Vegetation and mycorrhizal fungi enhanced climate-driven weathering by a factor of up to 2. Overall, we demonstrate a more realistic process-based treatment of plant fungal–geosphere interactions at the global scale, which constitutes a first step towards developing ‘next-generation’ geochemical models. PMID:22232768

  10. Evaluating sensitivity of silicate mineral dissolution rates to physical weathering using a soil evolution model (SoilGen2.25)

    NASA Astrophysics Data System (ADS)

    Opolot, E.; Finke, P. A.

    2015-08-01

    Silicate mineral dissolution rates depend on the interaction of a number of factors categorized either as intrinsic (e.g. mineral surface area, mineral composition) or extrinsic (e.g. climate, hydrology, biological factors, physical weathering). Estimating the integrated effect of these factors on the silicate mineral dissolution rates therefore necessitates the use of fully mechanistic soil evolution models. This study applies a mechanistic soil evolution model (SoilGen) to explore the sensitivity of silicate mineral dissolution rates to the integrated effect of other soil forming processes and factors. The SoilGen soil evolution model is a 1-D model developed to simulate the time-depth evolution of soil properties as a function of various soil forming processes (e.g. water, heat and solute transport, chemical and physical weathering, clay migration, nutrient cycling and bioturbation) driven by soil forming factors (i.e., climate, organisms, relief, parent material). Results from this study show that although soil solution chemistry (pH) plays a dominant role in determining the silicate mineral dissolution rates, all processes that directly or indirectly influence the soil solution composition equally play an important role in driving silicate mineral dissolution rates. Model results demonstrated a decrease of silicate mineral dissolution rates with time, an obvious effect of texture and an indirect but substantial effect of physical weathering on silicate mineral dissolution rates. Results further indicated that clay migration and plant nutrient recycling processes influence the pH and thus the silicate mineral dissolution rates. Our silicate mineral dissolution rates results fall between field and laboratory rates but were rather high and more close to the laboratory rates owing to the assumption of far from equilibrium reaction used in our dissolution rate mechanism. There is therefore need to include secondary mineral precipitation mechanism in our formulation

  11. Evaluating sensitivity of silicate mineral dissolution rates to physical weathering using a soil evolution model (SoilGen2.25)

    NASA Astrophysics Data System (ADS)

    Opolot, E.; Finke, P. A.

    2015-11-01

    Silicate mineral dissolution rates depend on the interaction of a number of factors categorized either as intrinsic (e.g. mineral surface area, mineral composition) or extrinsic (e.g. climate, hydrology, biological factors, physical weathering). Estimating the integrated effect of these factors on the silicate mineral dissolution rates therefore necessitates the use of fully mechanistic soil evolution models. This study applies a mechanistic soil evolution model (SoilGen) to explore the sensitivity of silicate mineral dissolution rates to the integrated effect of other soil-forming processes and factors. The SoilGen soil evolution model is a 1-D model developed to simulate the time-depth evolution of soil properties as a function of various soil-forming processes (e.g. water, heat and solute transport, chemical and physical weathering, clay migration, nutrient cycling, and bioturbation) driven by soil-forming factors (i.e., climate, organisms, relief, parent material). Results from this study show that although soil solution chemistry (pH) plays a dominant role in determining the silicate mineral dissolution rates, all processes that directly or indirectly influence the soil solution composition play an equally important role in driving silicate mineral dissolution rates. Model results demonstrated a decrease of silicate mineral dissolution rates with time, an obvious effect of texture and an indirect but substantial effect of physical weathering on silicate mineral dissolution rates. Results further indicated that clay migration and plant nutrient recycling processes influence the pH and thus the silicate mineral dissolution rates. Our silicate mineral dissolution rates results fall between field and laboratory rates but were rather high and more close to the laboratory rates possibly due to the assumption of far from equilibrium reaction used in our dissolution rate mechanism. There is therefore a need to include secondary mineral precipitation mechanism in our

  12. Atlas of the global distribution of atmospheric heating during the global weather experiment

    NASA Technical Reports Server (NTRS)

    Schaack, Todd K.; Johnson, Donald R.

    1991-01-01

    Global distributions of atmospheric heating for the annual cycle of the Global Weather Experiment are estimated from the European Centre for Medium-Range Weather Forecasts (ECMWF) Level 3b data set. Distributions of monthly, seasonally, and annually averaged heating are presented for isentropic and isobaric layers within the troposphere and for the troposphere as a whole. The distributions depict a large-scale structure of atmospheric heating that appears spatially and temporally consistent with known features of the global circulation and the seasonal evolution.

  13. Chemical weathering of silicate rocks as a function of elevation in the southern Swiss Alps

    NASA Astrophysics Data System (ADS)

    Drever, James I.; Zobrist, Jürg

    1992-08-01

    Surface water and soil samples were collected from a series of small catchments on granitic gneiss in the Canton of Ticino in southern Switzerland. Elevations of the sampling points ranged from 220 to 2400 m; vegetation varied correspondingly from deciduous forest through coniferous forest to alpine pasture and essentially unvegetated rock and talus. Annual precipitation averaged 1.9 to 2.4 m. The concentrations of the major cations and silica in surface waters decreased more or less exponentially with elevation. The cationic denudation rate decreased from about 500 meq/m 2 · y at the lower elevations to about 20 meq/m 2 · y at the highest. Alkalinity decreased from 250 to about -7 μeq/1. Although total concentrations decreased with elevation, there were no clear systematic trends in the ratios of the concentrations of the major cations and silica. This suggests that the nature of the secondary minerals formed during weathering in the area does not change with elevation, despite great changes in soil type and environmental conditions. The clay mineralogy of the soils is dominated by unweathered and slightly weathered bedrock minerals: mica and chlorite, hydrobiotite, and poorly characterized mixed-layer material. Small amounts of kaolinite and smectite were observed in a few samples, but there do not appear to be any systematic trends in clay mineralogy with elevation. Mass-balance arguments suggest that the major (in terms of solute generation) weathering product is either kaolinite or a mixture of A1(OH) 3 and 2:1 clays. The lack of dependence of weathering stoichiometry on elevation (a surrogate for several environmental variables) or solute concentrations perhaps reflects the importance of local relief, which did not vary systematically with elevation.

  14. Iron speciation and isotope fractionation during silicate weathering and soil formation in an alpine glacier forefield chronosequence

    NASA Astrophysics Data System (ADS)

    Kiczka, Mirjam; Wiederhold, Jan G.; Frommer, Jakob; Voegelin, Andreas; Kraemer, Stephan M.; Bourdon, Bernard; Kretzschmar, Ruben

    2011-10-01

    The chemical weathering of primary Fe-bearing minerals, such as biotite and chlorite, is a key step of soil formation and an important nutrient source for the establishment of plant and microbial life. The understanding of the relevant processes and the associated Fe isotope fractionation is therefore of major importance for the further development of stable Fe isotopes as a tracer of the biogeochemical Fe cycle in terrestrial environments. We investigated the Fe mineral transformations and associated Fe isotope fractionation in a soil chronosequence of the Swiss Alps covering 150 years of soil formation on granite. For this purpose, we combined for the first time stable Fe isotope analyses with synchrotron-based Fe-EXAFS spectroscopy, which allowed us to interpret changes in Fe isotopic composition of bulk soils, size fractions, and chemically separated Fe pools over time in terms of weathering processes. Bulk soils and rocks exhibited constant isotopic compositions along the chronosequence, whereas soil Fe pools in grain size fractions spanned a range of 0.4‰ in δ 56Fe. The clay fractions (<2 μm), in which newly formed Fe(III)-(hydr)oxides contributed up to 50% of the total Fe, were significantly enriched in light Fe isotopes, whereas the isotopic composition of silt and sand fractions, containing most of the soil Fe, remained in the range described by biotite/chlorite samples and bulk soils. Iron pools separated by a sequential extraction procedure covered a range of 0.8‰ in δ 56Fe. For all soils the lightest isotopic composition was observed in a 1 M NH 2OH-HCl-25% acetic acid extract, targeting poorly-crystalline Fe(III)-(hydr)oxides, compared with easily leachable Fe in primary phyllosilicates (0.5 M HCl extract) and Fe in residual silicates. The combination of the Fe isotope measurements with the speciation data obtained by Fe-EXAFS spectroscopy permitted to quantitatively relate the different isotope pools forming in the soils to the mineral

  15. Potential of global croplands and bioenergy crops for climate change mitigation through deployment for enhanced weathering.

    PubMed

    Kantola, Ilsa B; Masters, Michael D; Beerling, David J; Long, Stephen P; DeLucia, Evan H

    2017-04-01

    Conventional row crop agriculture for both food and fuel is a source of carbon dioxide (CO2) and nitrous oxide (N2O) to the atmosphere, and intensifying production on agricultural land increases the potential for soil C loss and soil acidification due to fertilizer use. Enhanced weathering (EW) in agricultural soils-applying crushed silicate rock as a soil amendment-is a method for combating global climate change while increasing nutrient availability to plants. EW uses land that is already producing food and fuel to sequester carbon (C), and reduces N2O loss through pH buffering. As biofuel use increases, EW in bioenergy crops offers the opportunity to sequester CO2 while reducing fossil fuel combustion. Uncertainties remain in the long-term effects and global implications of large-scale efforts to directly manipulate Earth's atmospheric CO2 composition, but EW in agricultural lands is an opportunity to employ these soils to sequester atmospheric C while benefitting crop production and the global climate.

  16. Influence of extreme weather disasters on global crop production.

    PubMed

    Lesk, Corey; Rowhani, Pedram; Ramankutty, Navin

    2016-01-07

    In recent years, several extreme weather disasters have partially or completely damaged regional crop production. While detailed regional accounts of the effects of extreme weather disasters exist, the global scale effects of droughts, floods and extreme temperature on crop production are yet to be quantified. Here we estimate for the first time, to our knowledge, national cereal production losses across the globe resulting from reported extreme weather disasters during 1964-2007. We show that droughts and extreme heat significantly reduced national cereal production by 9-10%, whereas our analysis could not identify an effect from floods and extreme cold in the national data. Analysing the underlying processes, we find that production losses due to droughts were associated with a reduction in both harvested area and yields, whereas extreme heat mainly decreased cereal yields. Furthermore, the results highlight ~7% greater production damage from more recent droughts and 8-11% more damage in developed countries than in developing ones. Our findings may help to guide agricultural priorities in international disaster risk reduction and adaptation efforts.

  17. Influence of extreme weather disasters on global crop production

    NASA Astrophysics Data System (ADS)

    Lesk, Corey; Rowhani, Pedram; Ramankutty, Navin

    2016-01-01

    In recent years, several extreme weather disasters have partially or completely damaged regional crop production. While detailed regional accounts of the effects of extreme weather disasters exist, the global scale effects of droughts, floods and extreme temperature on crop production are yet to be quantified. Here we estimate for the first time, to our knowledge, national cereal production losses across the globe resulting from reported extreme weather disasters during 1964-2007. We show that droughts and extreme heat significantly reduced national cereal production by 9-10%, whereas our analysis could not identify an effect from floods and extreme cold in the national data. Analysing the underlying processes, we find that production losses due to droughts were associated with a reduction in both harvested area and yields, whereas extreme heat mainly decreased cereal yields. Furthermore, the results highlight ~7% greater production damage from more recent droughts and 8-11% more damage in developed countries than in developing ones. Our findings may help to guide agricultural priorities in international disaster risk reduction and adaptation efforts.

  18. How severe Space Weather can disrupt global supply chains

    NASA Astrophysics Data System (ADS)

    Schulte in den Bäumen, H.; Moran, D.; Lenzen, M.; Cairns, I.; Steenge, A.

    2014-06-01

    Coronal mass ejections (CMEs) strong enough to create electromagnetic effects at latitudes below the auroral oval are frequent events that could soon have substantial impacts on electrical grids. Modern society's heavy reliance on these domestic and international networks increases our susceptibility to such a severe space weather event. Using a new high-resolution model of the global economy we simulate the economic impact of strong CMEs for 3 different planetary orientations. We account for the economic impacts within the countries directly affected as well as the post-disaster economic shock in partner economies linked by international trade. For a 1989 Quebec-like event the global economic impacts would range from USD 2.4 to 3.4 trillion over a year. Of this total economic shock about 50% would be felt in countries outside the zone of direct impact, leading to a loss in global GDP of 3.9 to 5.6%. The global economic damages are of the same order as wars, extreme financial crisis and estimated for future climate change.

  19. How severe space weather can disrupt global supply chains

    NASA Astrophysics Data System (ADS)

    Schulte in den Bäumen, H.; Moran, D.; Lenzen, M.; Cairns, I.; Steenge, A.

    2014-10-01

    Coronal mass ejections (CMEs) strong enough to create electromagnetic effects at latitudes below the auroral oval are frequent events that could soon have substantial impacts on electrical grids. Modern society's heavy reliance on these domestic and international networks increases our susceptibility to such a severe space-weather event. Using a new high-resolution model of the global economy, we simulate the economic impact of strong CMEs for three different planetary orientations. We account for the economic impacts within the countries directly affected, as well as the post-disaster economic shock in partner economies linked by international trade. For a 1989 Quebec-like event, the global economic impacts would range from USD 2.4 to 3.4 trillion over a year. Of this total economic shock, about 50% would be felt in countries outside the zone of direct impact, leading to a loss in global Gross Domestic Product (GDP) of 3.9 to 5.6%. The global economic damage is of the same order as wars, extreme financial crisis and estimated for future climate change.

  20. Shaken and Stirred: A Combined Reaction-Diffusion and Random Rate Model for the Temporal Evolution and Earthquake-induced Hydrodynamics of Silicate Mineral Weathering

    NASA Astrophysics Data System (ADS)

    Evaristo, J. A.; Willenbring, J.

    2013-12-01

    The time dependency of silicate mineral weathering has been explored in the literature in terms of processes and features that are intrinsic and extrinsic to the mineral [1]. However, although the advent of sophisticated reactive transport models has allowed for coupling increasingly complex reaction and transport processes [2,3], a simple and fundamental understanding of the temporal evolution of weathering is lacking. Here, we propose that a purely deterministic approach may not be sufficient given the inherent differences in reactivity over space and time. Therefore, we explore how a combined reaction-diffusion and random rate model - informed by a stochastic distribution of weathering rates K (T-1) - might be able to explain not only the temporal evolution but also the hydrodynamics of weathering during earthquakes; the latter being purportedly described by time-dependent property permeability (L2). Preliminary model results show that (1) an increase in dimensionless quantity βrp, where β is the diffusion length (L-1) and rp is the distance between pores (L), leads to a decrease in minimum reaction rate with time from the relation Kmin ∝ e-βrp/rp ; (2) at a given porosity, a time-dependent decrease in reactivity arises as permeability decreases due to decreasing pore size (and therefore increasing rp), which in turn may be related to the time-dependent feedback between dissolution and precipitation; (3) while permeability is lower in older soils, transient stresses as during earthquakes [4], may induce more efficient "declogging" of pores in these soils than in younger soils due to higher hydrodynamic viscous shear stress, thereby, resulting in a coseismic change in stream discharge Q; and (4) subsequent weathering beyond t~Kmin-1 exhibits a fall in rates, marking the cessation of logarithmic decay possibly due to dissolution-precipitation feedback. [1] White and Brantley (2003), Chem. Geol. 202, 479. [2] Lichtner P.C. (1996), Mineralogical Society of

  1. Chemical weathering rate laws and global geochemical cycles

    NASA Astrophysics Data System (ADS)

    Lasaga, Antonio C.; Soler, Josep M.; Ganor, Jiwchar; Burch, Timothy E.; Nagy, Kathryn L.

    1994-05-01

    In this paper, we discuss the recent kinetic work on water-rock interactions. Standard activity-activity diagrams are reinterpreted, using a mass transfer kinetic model and recent data on the relative rates of mineral reactions. The development of a fully integrated rate law is discussed, with special attention to the important effects of deviation from equilibrium on the rates of mineral-water reactions. The combined effects of temperature, pH, ionic strength, and saturation conditions on the overall dissolution and precipitation rates of minerals must be properly described before any seriously quantitative model of coupled fluid flow and chemical reaction can be undertaken. A rate law that integrates these effects is proposed. The functional dependence of the rate on ΔGr, the free energy change for the mineral reaction, is discussed, based on recent experimental work. An important result is the presence of a surface transition in the reaction mechanism leading to a very strong nonlinear dependence of the dissolution rates on ΔGr. The possible role of dislocation defects in this surface transition is discussed. The relation of global weathering rates and geochemical cycles to the recent experimental and theoretical water-rock kinetic work is explored. The temperature effect on the silica content of streams is reevaluated. The variation of silica concentration with runoff in the rivers of the world is quantified, using a coupled fluid flow and reaction model and the full rate law developed for a proto-granite system by the kinetic experiments. Implications of the water-rock kinetic data for the current geochemical cycles models are discussed with especial emphasis on the link between physical weathering and chemical weathering.

  2. Characteristics of precipitation regimes during the global weather experiment

    NASA Technical Reports Server (NTRS)

    Ahrens, Glen D.; Paegle, Julia N.

    1986-01-01

    Rainfall data were used in conjunction with heating rate values obtained from GLA/NASA to describe large scale heating changes and concurrent circulation fluctuations for weekly averages during the Special Observing Period I (January-March 1979) of the Global Weather Experiment. The GLA diabatic heating rates were obtained as residues of the thermodynamic energy equation during the four-dimensional data assimilation cycle (as described by Kalnay and Baker, 1984). In week one, the heating and rainfall rate profiles display a positive anomaly on the West Pacific in both fields. The anomaly appears to propagate eastward into the East Pacific and South America by the fifth week. By the week four, the negative anomaly over the Indian Ocean becomes positive. These heating patterns are reflected on positive divergent anomalies at 200 mb analyzed for the same periods. The stream-function anomalies display anticyclonic circulations over the heating anomalies.

  3. Transport properties of interfacial Si-rich layers formed on silicate minerals during weathering: Implications for environmental concerns

    NASA Astrophysics Data System (ADS)

    Daval, Damien; Rémusat, Laurent; Bernard, Sylvain; Wild, Bastien; Micha, Jean-Sébastien; Rieutord, François; Fernandez-Martinez, Alejandro

    2015-04-01

    The dissolution of silicate minerals is of primary importance for various processes ranging from chemical weathering to CO2 sequestration. Whether it determines the rates of soil formation, CO2 uptake and its impact on climate change, channeling caused by hydrothermal circulation in reservoirs of geothermal power plants, durability of radioactive waste confinement glasses or geological sequestration of CO2, the same strategy is commonly applied for determining the long term evolution of fluid-rock interactions. This strategy relies on a bottom-up approach, where the kinetic rate laws governing silicate mineral dissolution are determined from laboratory experiments. However, a long-standing problem regarding this approach stems from the observation that laboratory-derived dissolution rates overestimate their field counterparts by orders of magnitude, casting doubt on the accuracy and relevance of predictions based on reactive-transport simulations. Recently [1], it has been suggested that taking into account the formation of amorphous Si-rich surface layers (ASSL) as a consequence of mineral dissolution may contribute to decrease the large gap existing between laboratory and natural rates. Our ongoing study is aimed at deciphering the extent to which ASSL may represent a protective entity which affects the dissolution rate of the underlying minerals, both physically (passivation) and chemically (by promoting the formation of a local chemical medium which significantly differs from that of the bulk solution). Our strategy relies on the nm-scale measurement of the physicochemical properties (diffusivity, thickness and density) of ASSL formed on cleavages of a model mineral (wollastonite) and their evolution as a function of reaction progress. Our preliminary results indicate that the diffusivity of nm-thick ASSL formed on wollastonite surface is ~1,000,000 times smaller than that reported for an aqueous medium, as estimated from the monitoring of the progression of a

  4. Weather.

    ERIC Educational Resources Information Center

    Ruth, Amy, Ed.

    1996-01-01

    This theme issue of "The Goldfinch" focuses on weather in Iowa and weather lore. The bulletin contains historical articles, fiction, activities, and maps. The table of contents lists: (1) "Wild Rosie's Map"; (2) "History Mystery"; (3) "Iowa's Weather History"; (4) "Weather Wonders"; (6)…

  5. Global Cooperation in the Science of Space Weather

    NASA Technical Reports Server (NTRS)

    Gopalswamy, Nat

    2011-01-01

    The international space science community had recognized the importance of space weather more than a decade ago, which resulted in a number of international collaborative activities such as the Climate and Weather of the Sun Earth System (CAWSES) by SCOSTEP and the International Space Weather Initiative (ISWI). The ISWI program is a continuation of the successful International Heliophysical Year (IHY) program. These programs have brought scientists together to tackle the scientific issues behind space weather. In addition to the vast array of space instruments, ground based instruments have been deployed, which not only filled voids in data coverage, but also inducted young scientists from developing countries into the scientific community. This paper presents a summary of CAWSES and ISWI activities that promote space weather science via complementary approaches in international scientific collaborations. capacity building. and public outreach.

  6. Stable carbon isotopes in dissolved inorganic carbon: extraction and implications for quantifying the contributions from silicate and carbonate weathering in the Krishna River system during peak discharge.

    PubMed

    Laskar, Amzad H; Gandhi, Naveen; Thirumalai, Kaustubh; Yadava, Madhusudan G; Ramesh, Rengaswamy; Mahajan, Ramakant R; Kumar, Dharmendra

    2014-06-01

    We present a comparative study of two offline methods, a newly developed method and an existing one, for the measurement of the stable carbon isotopic composition (δ(13)C) of dissolved inorganic carbon (DIC; δ(13)CDIC) in natural waters. The measured δ(13)CDIC values of different water samples, prepared from laboratory Na2CO3, ground and oceanic waters, and a laboratory carbonate isotope standard, are found to be accurate and reproducible to within 0.5 ‰\\ (1σ). The extraction of CO2 from water samples by these methods does not require pre-treatment or sample poisoning and can be applied to a variety of natural waters to address carbon cycling in the hydrosphere. In addition, we present a simple method (based on a two-end-member mixing model) to estimate the silicate-weathering contribution to DIC in a river system by using the concentration of DIC and its δ(13)C. This approach is tested with data from the Krishna River system as a case study, thereby quantifying the contribution of silicate and carbonate weathering to DIC, particularly during peak discharge.

  7. Hydrologic regulation of chemical weathering and the geologic carbon cycle.

    PubMed

    Maher, K; Chamberlain, C P

    2014-03-28

    Earth's temperature is thought to be regulated by a negative feedback between atmospheric CO2 levels and chemical weathering of silicate rocks that operates over million-year time scales. To explain variations in the strength of the weathering feedback, we present a model for silicate weathering that regulates climatic and tectonic forcing through hydrologic processes and imposes a thermodynamic limit on weathering fluxes, based on the physical and chemical properties of river basins. Climate regulation by silicate weathering is thus strongest when global topography is elevated, similar to the situation today, and lowest when global topography is more subdued, allowing planetary temperatures to vary depending on the global distribution of topography and mountain belts, even in the absence of appreciable changes in CO2 degassing rates.

  8. Constraints on the Global-scale Chemical Weathering State of Mars From TES Results Based on Spectral Analysis of Chemically Weathered Basalts

    NASA Astrophysics Data System (ADS)

    Michalski, J. R.; Kraft, M. D.; Sharp, T. G.; Christensen, P. R.

    2005-12-01

    On Earth, subaerially exposed basaltic rocks (from arid-to-tropical regions) develop weathering rinds and rock coatings that affect spectroscopic measurements of their natural surfaces. Similarly, basaltic rocks and basaltic soil particles on Mars may have rinds and coatings that are spectroscopically observable. Thermal emission spectroscopy, because it provides information about the composition and structure of silicate and non-silicate minerals and mineraloids, provides a useful perspective on the mineralogy of weathered surfaces; reconciliation of the emission spectral features of weathered surfaces with observations from other datasets is critical to interpretations of thermal emission spectral features of Mars. In this study, we investigate the thermal emission (6-25 μm) and visible/near-infrared (VNIR) (0.4-2.5 μm) spectroscopic features of fresh and weathered surfaces of rock samples from the Columbia River Basalt Group (CRBG). VNIR spectra of weathered rock surfaces are brighter and redder than fresh rock surfaces, but contain no evidence for neoformation of clay minerals within subaerially exposed, weathered surfaces. In contrast, thermal emission spectroscopy suggests an enrichment of clay minerals in weathered surfaces. Also, thermal emission spectroscopy indicates the presence of glass-like materials in many weathered surfaces, which likely correspond to amorphous weathering products present within fractures, as coatings on minerals, or as coatings on the rocks themselves. These results have important implications for interpretation of TES and THEMIS data of Mars, including: 1) glasses and clays detected on Mars from thermal infrared spectra may correspond to poorly crystalline weathering products within chemically weathered rock surfaces, 2) chemically weathered surfaces of basalts may appear oxidized but clay-poor to VNIR datasets, and 3) the differential chemical breakdown of primary phases can affect interpretations of the remaining primary rock

  9. Atmospheric and oceanographic research review, 1978. [global weather, ocean/air interactions, and climate

    NASA Technical Reports Server (NTRS)

    1978-01-01

    Research activities related to global weather, ocean/air interactions, and climate are reported. The global weather research is aimed at improving the assimilation of satellite-derived data in weather forecast models, developing analysis/forecast models that can more fully utilize satellite data, and developing new measures of forecast skill to properly assess the impact of satellite data on weather forecasting. The oceanographic research goal is to understand and model the processes that determine the general circulation of the oceans, focusing on those processes that affect sea surface temperature and oceanic heat storage, which are the oceanographic variables with the greatest influence on climate. The climate research objective is to support the development and effective utilization of space-acquired data systems in climate forecast models and to conduct sensitivity studies to determine the affect of lower boundary conditions on climate and predictability studies to determine which global climate features can be modeled either deterministically or statistically.

  10. Stormy Weather: 101 Solutions to Global Climate Change.

    ERIC Educational Resources Information Center

    Dauncey, Guy

    This document presents 101 solutions to global climate change. These solutions are actions that are well suited to every level of society. This book creates awareness about global climate change. The history of Earth and the greenhouse effect are discussed, and explanations and solutions to global climate change are provided including traveling…

  11. Characterizing englacial and subglacial weathering processes in a silicate-carbonate system at Robertson Glacier, Canada: Combining field measurements and remote sensing

    NASA Astrophysics Data System (ADS)

    Rutledge, A. M.; Christensen, P. R.

    2012-12-01

    Geologic weathering processes in cold environments, especially processes acting on subglacial and englacial sediments and rocks, are not well characterized due to the difficulty of accessing these environments. However, subglacial and englacial weathering of geologic materials contributes to the solute flux in meltwater and provides a potential source of energy to chemotrophic microbes, and is thus an important component to understand. In this study, we characterize the weathering products present in a glaciated silicate-carbonate system using infrared spectroscopy, x-ray diffraction, and geochemical analyses. We use Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) data to determine whether glacial weathering products can be detected from remotely detected infrared spectra. The major goals of the project are to quantify weathering inputs to the glacial energy budget, and to link in situ sampling with remote sensing capabilities. Robertson Glacier, Alberta, Canada (115°20'W, 50°44'N) provides an excellent field site for this technique as it is accessible, and its retreating stage allows sampling of fresh subglacial and englacial sediments. This site is also of great significance to microbiology studies due to the recent detection of methanogens in the local subglacial till. Samples of glacially altered rock and sediments were collected on a downstream transect of the glacier in September 2011. Infrared laboratory spectroscopy and x-ray diffraction were used to determine the composition and abundance of minerals present. Infrared imagery of the region was collected at the time of sampling with the ASTER satellite instrument. Geochemical data were also collected at each location, and ice and water samples were analyzed for major and minor elements. pH values decreased in the downstream direction, and Ca+2 and SO4-2 in solution increased downstream. This is initially consistent with earlier studies of similar systems; however, the majority of

  12. AFGWC (Air Force Global Weather Central) Cloud Forecast Models

    DTIC Science & Technology

    1987-04-01

    Weather Center, Offutt AFB, NE 68113. This document contains export- controlled technical data. USAF ETAC/DOL ltr, 9 Feb 1995 UNCLASSIFIED ::Am:tiiiiii...wmmmmm •..-111111111111 ?TWWT’ . " iwimni WC FILE COP* Lf> 5 I o < AFGWC CLOUD FORECAST MODELS EDITED BY MAJOR TIMOTHY D, CRUM SCm ’-■ It...5LAYBR model makes extra-tropical forecasts for periods up to 48 hours. Forecasts of layer and total cloud, cloud type, layer temperatures , and

  13. Water - The key to global change. [of weather and climate

    NASA Technical Reports Server (NTRS)

    Soffen, Gerald A.

    1988-01-01

    The role of water in processes of global change is discussed. The importance of water in global warming, the loss of biological diversity, the activity of the El Nino southern oscillation, and the melting of polar ice are examined. Plans for a mission to measure tropical rainfall using a two frequency radar, a visible/IR radiometer and a passive microwave radiometer are noted. The way in which global change is affected by changes in patterns of available water is considered.

  14. 4DVAR for Global Atmospheric Numerical Weather Prediction

    DTIC Science & Technology

    2016-06-07

    generation global atmospheric 4D variational (4DVAR) data assimilation system, NAVDAS-AR2. OBJECTIVES The objective of this project is to construct...and transition a 4DVAR global atmospheric data assimilation system for NOGAPS to the Fleet Numerical Meteorology and Oceanography Center (FNMOC...This system, NAVDAS-AR, represents the first operational, weak constraint, 4DVAR atmospheric data assimilation system in the world. In this context

  15. Seafloor weathering controls on atmospheric CO{sub 2} and global climate

    SciTech Connect

    Brady, P.V.; Gislason, S.R.

    1997-03-01

    Alteration of surficial marine basalts at low temperatures (<40{degrees}C) is a potentially important sink for atmospheric CO{sub 2} over geologic time. Petrologic analyses, thermodynamic calculations, and experimental weathering results point to extensive Ca leaching and consumption of marine CO{sub 2} during alteration. Basalt weathering in seawater-like solutions is sensitive to temperature. The activation energy for initial basalt weathering in seawater is 41-65 U kJ mol{sup -1}. If seafloor weathering temperatures are set by deep ocean fluids under high fluid to rock ratios the feedback between weathering and atmospheric CO{sub 2} is indirect, but sizeable. If the bulk of seafloor weathering occurs in the presence of low-temperature hydrothermal fluids, the weathering feedback depends on the linkage between spreading rates and heat flow. In either case, the primary linkage between seafloor weathering and the global carbon cycle appears to be thermal as opposed to chemical. 81 refs., 4 figs., 2 tabs.

  16. Global markets and the differential effects of climate and weather on conflict

    NASA Astrophysics Data System (ADS)

    Meng, K. C.; Hsiang, S. M.; Cane, M. A.

    2011-12-01

    Both climate and weather have been attributed historically as possible drivers for violence. Previous empirical studies have either focused on isolating local idiosyncratic weather variation or have conflated weather with spatially coherent climatic changes. This paper provides the first study of the differential impacts of climate and weather variation by employing methods developed in earlier work linking the El Nino Southern Oscillation (ENSO) with the onset of civil conflicts. By separating the effects of climate from local weather, we are able to test possible mechanisms by which atmospheric changes can cause violence. It is generally difficult to separate the effect of year-to-year climate variations from other global events that might drive conflict. We avoid this problem by examining the set of tropical countries that are strongly teleconnected to ENSO. For this region, the ENSO cycle parallels the common year-to-year pattern of violence. Using ENSO, we isolate the influence of climatic changes from other global determinants of violence and compare it with the effect of local weather variations. We find that while climate affects the onset of civil conflicts in teleconnected countries, local weather has no significant effect. Productivity overall as well as across major sectors is more affected by local weather than by climatic variation. This is particularly evident in the agricultural sector where total value and cereal yield decline much greater from a 1°C increase in local temperature than a 1°C increase in ENSO. However, when examining the effect on food prices, we find that ENSO is associated with a large and statistically significant increase in cereal prices but no effect from hotter local temperatures. Altogether, this evidence points toward the ability of global and regional commodity markets to insure against the effects of local weather variation and their limitations in containing losses from aggregate shocks such as El Nino events. We posit

  17. Modeling extreme "Carrington-type" space weather events using three-dimensional global MHD simulations

    NASA Astrophysics Data System (ADS)

    Ngwira, Chigomezyo M.; Pulkkinen, Antti; Kuznetsova, Maria M.; Glocer, Alex

    2014-06-01

    There is a growing concern over possible severe societal consequences related to adverse space weather impacts on man-made technological infrastructure. In the last two decades, significant progress has been made toward the first-principles modeling of space weather events, and three-dimensional (3-D) global magnetohydrodynamics (MHD) models have been at the forefront of this transition, thereby playing a critical role in advancing our understanding of space weather. However, the modeling of extreme space weather events is still a major challenge even for the modern global MHD models. In this study, we introduce a specially adapted University of Michigan 3-D global MHD model for simulating extreme space weather events with a Dst footprint comparable to the Carrington superstorm of September 1859 based on the estimate by Tsurutani et. al. (2003). Results are presented for a simulation run with "very extreme" constructed/idealized solar wind boundary conditions driving the magnetosphere. In particular, we describe the reaction of the magnetosphere-ionosphere system and the associated induced geoelectric field on the ground to such extreme driving conditions. The model setup is further tested using input data for an observed space weather event of Halloween storm October 2003 to verify the MHD model consistence and to draw additional guidance for future work. This extreme space weather MHD model setup is designed specifically for practical application to the modeling of extreme geomagnetically induced electric fields, which can drive large currents in ground-based conductor systems such as power transmission grids. Therefore, our ultimate goal is to explore the level of geoelectric fields that can be induced from an assumed storm of the reported magnitude, i.e., Dst˜=-1600 nT.

  18. Global Muon Detector Network Used for Space Weather Applications

    NASA Astrophysics Data System (ADS)

    Rockenbach, M.; Dal Lago, A.; Schuch, N. J.; Munakata, K.; Kuwabara, T.; Oliveira, A. G.; Echer, E.; Braga, C. R.; Mendonça, R. R. S.; Kato, C.; Kozai, M.; Tokumaru, M.; Bieber, J. W.; Evenson, P.; Duldig, M. L.; Humble, J. E.; Al Jassar, H. K.; Sharma, M. M.; Sabbah, I.

    2014-08-01

    In this work, we summarize the development and current status of the Global Muon Detector Network (GMDN). The GMDN started in 1992 with only two muon detectors. It has consisted of four detectors since the Kuwait-city muon hodoscope detector was installed in March 2006. The present network has a total of 60 directional channels with an improved coverage of the sunward Interplanetary Magnetic Field (IMF) orientation, making it possible to continuously monitor cosmic ray precursors of geomagnetic storms. The data analysis methods developed also permit precise calculation of the three dimensional cosmic ray anisotropy on an hourly basis free from the atmospheric temperature effect and analysis of the cosmic ray precursors free from the diurnal anisotropy of the cosmic ray intensity.

  19. The Power of Many: Nanosatellites For Cost Effective Global Weather Data

    NASA Astrophysics Data System (ADS)

    Greenberg, A.; Platzer, P.

    2015-12-01

    While weather processing technology through modeling and simulations has continued to advance, the amount of raw data available for analysis has dwindled. Most raw weather data is collected from satellites that are past their intended decommission date, and the likelihood of a catastrophic failure and diminishing reliability increases with each passing day. A United States government report released this year recognized the potential risk that this creates, citing a few alternatives to our aging satellite technology to at least maintain the level of raw weather data we currently have available. This report also highlighted nanosatellites as one of the most promising solutions, due in no small part to their standard form factor, translating into increased launch capabilities and better resiliency with fewer points of failure, rapidly advancing technology and low capital expenditure. Taking advantage of rapid advancements in sensor technology, these nanosatellites are replaced every two years or less and de-orbit quickly. Each new generation carries an improved payload and offers more network-wide resiliency. A constellation of just ten GPS-RO enabled nanosatellites taking measurements from every point on Earth, coupled with a globally distributed network of ground stations, can provide five times more radio occultation data than the combined efforts of current weather satellites. By the end of this year, Spire Global, Inc. will launch the world's first network of commercial weather satellites using GPS-RO for raw data collection.

  20. The space weather of the global ionosphere S4 scintillation

    NASA Astrophysics Data System (ADS)

    Liu, Jann-Yenq; Chen, Shih-Ping; Yeh, Wen-Hao

    2016-04-01

    In this paper, a method is introduced which converts S4 index observations by radio occultation of FORMOSAT-3/COSMIC (F3/C) to the scintillation on the ground. To carry out the conversion, three dimensional (3D) structures of S4max, the maximum value on each profile probed by F3/C, are constructed, which allows us to understand GPS scintillation variations at various local times, seasons, and solar activity conditions, as well as the geographical distribution from the space-based point of view. By applying the method to data of the 3D structure, maps of the worst case scenario on the ground as functions of geomagnetic local time and geographic coordinates are constructed and reported here. The converted S4max for the first time estimates the global distribution of ionospheric scintillations in the GPS L1 band C/A code signal on the ground. The results show that the worst-case scintillations appear within the low latitude region of ±30°N, peaking around ±20°N magnetic latitude; they begin at 1900 MLT, reach their maximum at 2100 MLT, and vanish by about 0200-0300 MLT. The most pronounced low-latitude scintillation occurs over the South American and African sectors. Finally, based on the above the above data, an empirical model is constructed. For a given time, location, and solar activity, the model forecasts the ionospheric S4 scintillation in the L1 band signal on the ground.

  1. Quantifying the VNIR Effects of Nanophase Iron Generated through the Space Weathering of Silicates: Reconciling Modeled Data with Laboratory Observations

    NASA Astrophysics Data System (ADS)

    Legett, C., IV; Glotch, T. D.; Lucey, P. G.

    2015-12-01

    Space weathering is a diverse set of processes that occur on the surfaces of airless bodies due to exposure to the space environment. One of the effects of space weathering is the generation of nanophase iron particles in glassy rims on mineral grains due to sputtering of iron-bearing minerals. These particles have a size-dependent effect on visible and near infrared (VNIR) reflectance spectra with smaller diameter particles (< 50 nm) causing both reddening and darkening of the spectra with respect to unweathered material (Britt-Pieters particle behavior), while larger particles (> 300 nm) darken without reddening. Between these two sizes, a gradual shift between these two behaviors occurs. In this work, we present results from the Multiple Sphere T-Matrix (MSTM) scattering model in combination with Hapke theory to explore the particle size and iron content parameter spaces with respect to VNIR (700-1700 nm) spectral slope. Previous work has shown that the MSTM-Hapke hybrid model offers improvements over Mie-Hapke models. Virtual particles are constructed out of an arbitrary number of spheres, and each sphere is assigned a refractive index and extinction coefficient for each wavelength of interest. The model then directly solves Maxwell's Equations at every wave-particle interface to predict the scattering, extinction and absorption efficiencies. These are then put into a simplified Hapke bidirectional reflectance model that yields a predicted reflectance. Preliminary results show an area of maximum slopes for iron particle diameters < 80 nm and iron concentrations of ~1-10wt% in an amorphous silica matrix. Further model runs are planned to better refine the extent of this region. Companion laboratory work using mixtures of powdered aerogel and nanophase iron particles provides a point of comparison to modeling efforts. The effects on reflectance and emissivity values due to particle size in a nearly ideal scatterer (aerogel) are also observed with comparisons to

  2. Rare Earth Element Behavior During Incongruent Weathering and Varying Discharge Conditions in Silicate Dominated River Systems: The Australian Victorian Alps

    NASA Astrophysics Data System (ADS)

    Hagedorn, K. B.; Cartwright, I.

    2008-12-01

    The distribution of rare earth elements (REE) and trace elements was measured by ICP-MS on fresh, slightly weathered and weathered granite and surface water samples from a network of 11 pristine rivers draining the Australian Victorian Alps during (i) high and (ii) low discharge conditions. River water REE concentrations are largely derived from atmospheric precipitation (rain, snow), as indicated by similar Chondrite normalized REE patterns (higher LREE over HREE; negative Ce anomalies, positive Eu anomalies) and similar total REE concentrations during both dry and wet seasons. Calculations based on the covariance between REE and Cl concentrations and oxygen and hydrogen isotopes indicate precipitation input coupled with subsequent evaporation may account for 30% o 100% of dissolved REE in stream waters. The dissolved contribution to the granitic substratum to stream water comes mainly from the transformation of plagioclase to smectite, kaolinite and gibbsite and minor apatite dissolution. However, since most REE of the regional granite are present in accessory minerals (titanite, zircon, etc.) they do not significantly contribute to the river REE pool. REE concentrations drop sharply downstream as a result of dilution and chemical attenuation. A trend of downstream enrichment of the heavier REE is due to selective partitioning of the lighter REE (as both free REE or REECO3 complexes) to hydrous oxides of suspended Al which, in turn, is controlled by a downstream increase of pH to values > 6.1 (for free REE) and > 7.3 (for REECO3 complexes). Although most circumneutral waters were supersaturated with REE phosphate compounds, precipitation of LnPO4 is not believed to have been a dominant process because the predicted phosphate fractionation pattern is inconsistent with the observed trends. Negative saturation indices of hydrous ferric oxides also militate against surface complexation onto goethite. Instead, REE attenuation most likely resulted from adsorption onto

  3. Stable runoff and weathering fluxes into the oceans over Quaternary climate cycles

    NASA Astrophysics Data System (ADS)

    von Blanckenburg, Friedhelm; Bouchez, Julien; Ibarra, Daniel E.; Maher, Kate

    2015-07-01

    Throughout the Quaternary period, the Earth’s surface has been subject to large changes in temperature and precipitation associated with fluctuations between glacial and interglacial states that have affected biogeochemical cycling. However, the effect of these climate oscillations on weathering is debated, with climate modelling efforts using empirical relationships between measures of climate and weathering suggesting minimal changes in global weathering rates between these two climate states. The ratio of the cosmogenic isotope 10Be, which is produced in the atmosphere and deposited to the oceans and the land surface, to 9Be, which is introduced to the oceans by the riverine silicate weathering flux, can be used to track relative weathering fluxes. Here we apply this proxy to marine sediment beryllium records spanning the past two million years, and find no detectable shifts in inputs from global silicate weathering into the oceans. Using climate model simulations of the Last Glacial Maximum along with a model for silicate weathering, we find that there was large regional variability in runoff between glacial and interglacial periods, but that this regional variability was insufficient to shift global weathering fluxes. We suggest that this stability in weathering explains the observation that the removal of CO2 from the atmosphere by silicate weathering has been in approximate balance with CO2 degassing over the past 600,000 years.

  4. Analyzing Personal Happiness from Global Survey and Weather Data: A Geospatial Approach.

    PubMed

    Peng, Yi-Fan; Tang, Jia-Hong; Fu, Yang-chih; Fan, I-chun; Hor, Maw-Kae; Chan, Ta-Chien

    2016-01-01

    Past studies have shown that personal subjective happiness is associated with various macro- and micro-level background factors, including environmental conditions, such as weather and the economic situation, and personal health behaviors, such as smoking and exercise. We contribute to this literature of happiness studies by using a geospatial approach to examine both macro and micro links to personal happiness. Our geospatial approach incorporates two major global datasets: representative national survey data from the International Social Survey Program (ISSP) and corresponding world weather data from the National Oceanic and Atmospheric Administration (NOAA). After processing and filtering 55,081 records of ISSP 2011 survey data from 32 countries, we extracted 5,420 records from China and 25,441 records from 28 other countries. Sensitivity analyses of different intervals for average weather variables showed that macro-level conditions, including temperature, wind speed, elevation, and GDP, are positively correlated with happiness. To distinguish the effects of weather conditions on happiness in different seasons, we also adopted climate zone and seasonal variables. The micro-level analysis indicated that better health status and eating more vegetables or fruits are highly associated with happiness. Never engaging in physical activity appears to make people less happy. The findings suggest that weather conditions, economic situations, and personal health behaviors are all correlated with levels of happiness.

  5. Analyzing Personal Happiness from Global Survey and Weather Data: A Geospatial Approach

    PubMed Central

    Peng, Yi-Fan; Tang, Jia-Hong; Fu, Yang-chih; Fan, I-chun; Hor, Maw-Kae; Chan, Ta-Chien

    2016-01-01

    Past studies have shown that personal subjective happiness is associated with various macro- and micro-level background factors, including environmental conditions, such as weather and the economic situation, and personal health behaviors, such as smoking and exercise. We contribute to this literature of happiness studies by using a geospatial approach to examine both macro and micro links to personal happiness. Our geospatial approach incorporates two major global datasets: representative national survey data from the International Social Survey Program (ISSP) and corresponding world weather data from the National Oceanic and Atmospheric Administration (NOAA). After processing and filtering 55,081 records of ISSP 2011 survey data from 32 countries, we extracted 5,420 records from China and 25,441 records from 28 other countries. Sensitivity analyses of different intervals for average weather variables showed that macro-level conditions, including temperature, wind speed, elevation, and GDP, are positively correlated with happiness. To distinguish the effects of weather conditions on happiness in different seasons, we also adopted climate zone and seasonal variables. The micro-level analysis indicated that better health status and eating more vegetables or fruits are highly associated with happiness. Never engaging in physical activity appears to make people less happy. The findings suggest that weather conditions, economic situations, and personal health behaviors are all correlated with levels of happiness. PMID:27078263

  6. Recent results from the GISS model of the global atmosphere. [circulation simulation for weather forecasting

    NASA Technical Reports Server (NTRS)

    Somerville, R. C. J.

    1975-01-01

    Large numerical atmospheric circulation models are in increasingly widespread use both for operational weather forecasting and for meteorological research. The results presented here are from a model developed at the Goddard Institute for Space Studies (GISS) and described in detail by Somerville et al. (1974). This model is representative of a class of models, recently surveyed by the Global Atmospheric Research Program (1974), designed to simulate the time-dependent, three-dimensional, large-scale dynamics of the earth's atmosphere.

  7. Error growth patterns in systems with spatial chaos: from coupled map lattices to global weather models.

    PubMed

    Primo, C; Szendro, I G; Rodríguez, M A; Gutiérrez, J M

    2007-03-09

    Error growth in spatiotemporal chaotic systems is investigated by analyzing the interplay between temporal and spatial dynamics. The spatial correlation and localization of relative fluctuations grow and decay indicating two different regimes, before and after saturation by nonlinear effects. This general behavior is shown to hold both in simple coupled map lattices and in global weather models. This explains the increasing or decreasing trends previously observed in the exponential growth rate of these spatiotemporal systems.

  8. Chemical and Biological Catalytic Enhancement of Weathering of Silicate Minerals and industrial wastes as a Novel Carbon Capture and Storage Technology

    NASA Astrophysics Data System (ADS)

    Park, A. H. A.

    2014-12-01

    Increasing concentration of CO2 in the atmosphere is attributed to rising consumption of fossil fuels around the world. The development of solutions to reduce CO2 emissions to the atmosphere is one of the most urgent needs of today's society. One of the most stable and long-term solutions for storing CO2 is via carbon mineralization, where minerals containing metal oxides of Ca or Mg are reacted with CO2 to produce thermodynamically stable Ca- and Mg-carbonates that are insoluble in water. Carbon mineralization can be carried out in-situ or ex-situ. In the case of in-situ mineralization, the degree of carbonation is thought to be limited by both mineral dissolution and carbonate precipitation reaction kinetics, and must be well understood to predict the ultimate fate of CO2 within geological reservoirs. While the kinetics of in-situ mineral trapping via carbonation is naturally slow, it can be enhanced at high temperature and high partial pressure of CO2. The addition of weak organic acids produced from food waste has also been shown to enhance mineral weathering kinetics. In the case of the ex-situ carbon mineralization, the role of these ligand-bearing organic acids can be further amplified for silicate mineral dissolution. Unfortunately, high mineral dissolution rates often lead to the formation of a silica-rich passivation layer on the surface of silicate minerals. Thus, the use of novel solvent mixture that allows chemically catalyzed removal of this passivation layer during enhanced Mg-leaching surface reaction has been proposed and demonstrated. Furthermore, an engineered biological catalyst, carbonic anhydrase, has been developed and evaluated to accelerate the hydration of CO2, which is another potentially rate-limiting step of the carbonation reaction. The development of these novel catalytic reaction schemes has significantly improved the overall efficiency and sustainability of in-situ and ex-situ mineral carbonation technologies and allowed direct

  9. Transport of Aerosols: Regional and Global Implications for Climate, Weather, and Air Quality

    NASA Technical Reports Server (NTRS)

    Chin, Mian; Diehl, Thomas; Yu, Hongbin; Bian, Huisheng; Remer, Lorraine; Kahn, Ralph

    2008-01-01

    Long-range transport of atmospheric aerosols can have a significant impact on global climate, regional weather, and local air quality. In this study, we use a global model GOCART together with satellite data and ground-based measurements to assess the emission and transport of pollution, dust, biomass burning, and volcanic aerosols and their implications. In particular, we will show the impact of emissions and long-range transport of aerosols from major pollution and dust source regions to (1) the surface air quality, (2) the atmospheric heating rates, and (3) surface radiation change near the source and downwind regions.

  10. Hydroecological Connections: Hyporheic Zone Weathering of Silicate Minerals Controls Diatom Biodiversity in Microbial Mats in Glacial Meltwater Streams of the McMurdo Dry Valleys, Antarctica

    NASA Astrophysics Data System (ADS)

    McKnight, D. M.; Dyson, I.; Esposito, R. M.; Gooseff, M. N.; Lyons, W. B.; Welch, K. A.

    2015-12-01

    The McMurdo Dry Valleys of Antarctica is comprised of alpine and terminal glaciers, large expanses of patterned ground, and ice-covered lakes in the valley floors, which are linked by glacial meltwater streams that flow during the austral summer. As part of the McMurdo Dry Valleys Long-Term Ecological research project, we have observed stream ecosystem response to a sustained 18 year cool period with low flows, which has been recently interrupted by three "flood events" during sunny, warm summers. Many of these streams contain thriving microbial mats comprised of cyanobacteria and endemic diatoms, the most diverse group of eukaryotic organisms in the valleys. Of the 45 diatom taxa, some common taxa are heavily silicified, Hantzschia amphioxys f. muelleri, while others are only lightly silicified. By comparing diatom communities in streams which flow every summer with those in streams that only flow during flood events, we found that hydrologic flow regime acts as a strong environmental filter on diatom community composition. Following the first flood event in 2001/02, mat biomass was two-fold lower due to scouring and recovered over several years, with lesser declines following the subsequent floods. In the longer streams, the diatom community composition remained stable through the flood events, whereas in two of the shorter streams, Green and Bowles Creeks, the diatom community shifted after the first flood event to a greater abundance of lightly silicified taxa. Water quality monitoring and reactive transport modeling have shown that rapid weathering of silicate minerals in the hyporheic zone accounts for the downstream increases in Si concentration which are observed in the longer streams. One mechanism driving this greater abundance of lightly silicified diatoms in shorter streams could be the greater dilution of the Si supply from hyporheic weathering in shorter streams under high flows. Given that the stream diatom community is well preserved in the 40

  11. The analysis sensitivity to tropical winds from the Global Weather Experiment

    NASA Technical Reports Server (NTRS)

    Paegle, J.; Paegle, J. N.; Baker, W. E.

    1986-01-01

    The global scale divergent and rotational flow components of the Global Weather Experiment (GWE) are diagnosed from three different analyses of the data. The rotational flow shows closer agreement between the analyses than does the divergent flow. Although the major outflow and inflow centers are similarly placed in all analyses, the global kinetic energy of the divergent wind varies by about a factor of 2 between different analyses while the global kinetic energy of the rotational wind varies by only about 10 percent between the analyses. A series of real data assimilation experiments has been performed with the GLA general circulation model using different amounts of tropical wind data during the First Special Observing Period of the Global Weather Experiment. In exeriment 1, all available tropical wind data were used; in the second experiment, tropical wind data were suppressed; while, in the third and fourth experiments, only tropical wind data with westerly and easterly components, respectively, were assimilated. The rotational wind appears to be more sensitive to the presence or absence of tropical wind data than the divergent wind. It appears that the model, given only extratropical observations, generates excessively strong upper tropospheric westerlies. These biases are sufficiently pronounced to amplify the globally integrated rotational flow kinetic energy by about 10 percent and the global divergent flow kinetic energy by about a factor of 2. Including only easterly wind data in the tropics is more effective in controlling the model error than including only westerly wind data. This conclusion is especially noteworthy because approximately twice as many upper tropospheric westerly winds were available in these cases as easterly winds.

  12. Continental-pelagic carbonate partitioning and the global carbonate-silicate cycle

    NASA Technical Reports Server (NTRS)

    Caldeira, K.; Rampino, M. R. (Principal Investigator)

    1991-01-01

    A carbonate-silicate geochemical cycle model is developed and used to explore dynamic and climatic consequences of constraints on shallow-water carbonate burial and possible carbon loss to the mantle associated with sea-floor subduction. The model partitions carbonate deposition between shallow-water and deep-water environments and includes carbon fluxes between the mantle and lithosphere. When total lithospheric carbonate mass is constant, there are two stable steady states, one in which the carbonate burial flux is mostly continental and another in which it is mostly pelagic. The continental steady state is characterized by a low metamorphic CO2 flux to the atmosphere and predominantly shallow-water carbonate burial. The pelagic steady state is characterized by a high metamorphic CO2 flux and predominantly deep-water carbonate burial. For reasonable parameter values, when total lithospheric carbonate mass is allowed to vary, the model oscillates between predominantly continental and predominantly pelagic modes. Model results suggest that carbonate deposition patterns established during the Cenozoic may be pushing the Earth system from the continental to the pelagic mode on a time scale of 10(8) yr, with a possible consequent order-of-magnitude increase in the metamorphic CO2 flux to the atmosphere.

  13. Global Weather States and Their Properties from Passive and Active Satellite Cloud Retrievals

    NASA Technical Reports Server (NTRS)

    Tselioudis, George; Rossow, William; Zhang, Yuanchong; Konsta, Dimitra

    2013-01-01

    In this study, the authors apply a clustering algorithm to International Satellite Cloud Climatology Project (ISCCP) cloud optical thickness-cloud top pressure histograms in order to derive weather states (WSs) for the global domain. The cloud property distribution within each WS is examined and the geographical variability of each WS is mapped. Once the global WSs are derived, a combination of CloudSat and Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observations (CALIPSO) vertical cloud structure retrievals is used to derive the vertical distribution of the cloud field within each WS. Finally, the dynamic environment and the radiative signature of the WSs are derived and their variability is examined. The cluster analysis produces a comprehensive description of global atmospheric conditions through the derivation of 11 WSs, each representing a distinct cloud structure characterized by the horizontal distribution of cloud optical depth and cloud top pressure. Matching those distinct WSs with cloud vertical profiles derived from CloudSat and CALIPSO retrievals shows that the ISCCP WSs exhibit unique distributions of vertical layering that correspond well to the horizontal structure of cloud properties. Matching the derived WSs with vertical velocity measurements shows a normal progression in dynamic regime when moving from the most convective to the least convective WS. Time trend analysis of the WSs shows a sharp increase of the fair-weather WS in the 1990s and a flattening of that increase in the 2000s. The fact that the fair-weather WS is the one with the lowest cloud radiative cooling capability implies that this behavior has contributed excess radiative warming to the global radiative budget during the 1990s.

  14. GFDL's unified regional-global weather-climate modeling system with variable resolution capability for severe weather predictions and regional climate simulations

    NASA Astrophysics Data System (ADS)

    Lin, S. J.

    2015-12-01

    The NOAA/Geophysical Fluid Dynamics Laboratory has been developing a unified regional-global modeling system with variable resolution capabilities that can be used for severe weather predictions (e.g., tornado outbreak events and cat-5 hurricanes) and ultra-high-resolution (1-km) regional climate simulations within a consistent global modeling framework. The fundation of this flexible regional-global modeling system is the non-hydrostatic extension of the vertically Lagrangian dynamical core (Lin 2004, Monthly Weather Review) known in the community as FV3 (finite-volume on the cubed-sphere). Because of its flexability and computational efficiency, the FV3 is one of the final candidates of NOAA's Next Generation Global Prediction System (NGGPS). We have built into the modeling system a stretched (single) grid capability, a two-way (regional-global) multiple nested grid capability, and the combination of the stretched and two-way nests, so as to make convection-resolving regional climate simulation within a consistent global modeling system feasible using today's High Performance Computing System. One of our main scientific goals is to enable simulations of high impact weather phenomena (such as tornadoes, thunderstorms, category-5 hurricanes) within an IPCC-class climate modeling system previously regarded as impossible. In this presentation I will demonstrate that it is computationally feasible to simulate not only super-cell thunderstorms, but also the subsequent genesis of tornadoes using a global model that was originally designed for century long climate simulations. As a unified weather-climate modeling system, we evaluated the performance of the model with horizontal resolution ranging from 1 km to as low as 200 km. In particular, for downscaling studies, we have developed various tests to ensure that the large-scale circulation within the global varaible resolution system is well simulated while at the same time the small-scale can be accurately captured

  15. Temperature dependence of basalt weathering

    NASA Astrophysics Data System (ADS)

    Li, Gaojun; Hartmann, Jens; Derry, Louis A.; West, A. Joshua; You, Chen-Feng; Long, Xiaoyong; Zhan, Tao; Li, Laifeng; Li, Gen; Qiu, Wenhong; Li, Tao; Liu, Lianwen; Chen, Yang; Ji, Junfeng; Zhao, Liang; Chen, Jun

    2016-06-01

    The homeostatic balance of Earth's long-term carbon cycle and the equable state of Earth's climate are maintained by negative feedbacks between the levels of atmospheric CO2 and the chemical weathering rate of silicate rocks. Though clearly demonstrated by well-controlled laboratory dissolution experiments, the temperature dependence of silicate weathering rates, hypothesized to play a central role in these weathering feedbacks, has been difficult to quantify clearly in natural settings at landscape scale. By compiling data from basaltic catchments worldwide and considering only inactive volcanic fields (IVFs), here we show that the rate of CO2 consumption associated with the weathering of basaltic rocks is strongly correlated with mean annual temperature (MAT) as predicted by chemical kinetics. Relations between temperature and CO2 consumption rate for active volcanic fields (AVFs) are complicated by other factors such as eruption age, hydrothermal activity, and hydrological complexities. On the basis of this updated data compilation we are not able to distinguish whether or not there is a significant runoff control on basalt weathering rates. Nonetheless, the simple temperature control as observed in this global dataset implies that basalt weathering could be an effective mechanism for Earth to modulate long-term carbon cycle perturbations.

  16. Association of global weather changes with acute coronary syndromes: gaining insights from clinical trials data

    NASA Astrophysics Data System (ADS)

    Bakal, Jeffrey A.; Ezekowitz, Justin A.; Westerhout, Cynthia M.; Boersma, Eric; Armstrong, Paul W.

    2013-05-01

    The aim of this study was to develop a method for the identification of global weather parameters and patient characteristics associated with a type of heart attack in which there is a sudden partial blockage of a coronary artery. This type of heart attack does not demonstrate an elevation of the ST segment on an electrocardiogram and is defined as a non-ST elevation acute coronary syndrome (NSTE-ACS). Data from the Global Summary of the Day database was linked with the enrollment and baseline data for a phase III international clinical trial in NSTE-ACS in four 48-h time periods covering the week prior to the clinical event that prompted enrollment in the study. Meteorological events were determined by standardizing the weather data from enrollment dates against an empirical distribution from the month prior. These meteorological events were then linked to the patients' geographic region, demographics and comorbidities to identify potential susceptible populations. After standardization, changes in temperature and humidity demonstrated an association with the enrollment event. Additionally there appeared to be an association with gender, region and a history of stroke. This methodology may provide a useful global insight into assessing the biometeorologic component of diseases from international data.

  17. Global Positioning System Energetic Particle Data: The Next Space Weather Data Revolution

    NASA Technical Reports Server (NTRS)

    Knipp, Delores J.; Giles, Barbara L.

    2016-01-01

    The Global Positioning System (GPS) has revolutionized the process of getting from point A to point Band so much more. A large fraction of the worlds population relies on GPS (and its counterparts from other nations) for precision timing, location, and navigation. Most GPS users are unaware that the spacecraft providing the signals they rely on are operating in a very harsh space environment the radiation belts where energetic particles trapped in Earths magnetic field dash about at nearly the speed of light. These subatomic particles relentlessly pummel GPS satellites. So by design, every GPS satellite and its sensors are radiation hardened. Each spacecraft carries particle detectors that provide health and status data to system operators. Although these data reveal much about the state of the space radiation environment, heretofore they have been available only to system operators and supporting scientists. Research scientists have long sought a policy shift to allow more general access. With the release of the National Space Weather Strategy and Action Plan organized by the White House Office of Science Technology Policy (OSTP) a sample of these data have been made available to space weather researchers. Los Alamos National Laboratory (LANL) and the National Center for Environmental Information released a months worth of GPS energetic particle data from an interval of heightened space weather activity in early 2014 with the hope of stimulating integration of these data sets into the research arena. Even before the public data release GPS support scientists from LANL showed the extraordinary promise of these data.

  18. Long Range Weather Prediction III: Miniaturized Distributed Sensors for Global Atmospheric Measurements

    DOE R&D Accomplishments Database

    Teller, E.; Leith, C.; Canavan, G.; Wood, L.

    2001-11-13

    We continue consideration of ways-and-means for creating, in an evolutionary, ever-more-powerful manner, a continually-updated data-base of salient atmospheric properties sufficient for finite differenced integration-based, high-fidelity weather prediction over intervals of 2-3 weeks, leveraging the 10{sup 14} FLOPS digital computing systems now coming into existence. A constellation comprised of 10{sup 6}-10{sup 9} small atmospheric sampling systems--high-tech superpressure balloons carrying early 21st century semiconductor devices, drifting with the local winds over the meteorological spectrum of pressure-altitudes--that assays all portions of the troposphere and lower stratosphere remains the central feature of the proposed system. We suggest that these devices should be active-signaling, rather than passive-transponding, as we had previously proposed only for the ground- and aquatic-situated sensors of this system. Instead of periodic interrogation of the intra-atmospheric transponder population by a constellation of sophisticated small satellites in low Earth orbit, we now propose to retrieve information from the instrumented balloon constellation by existing satellite telephony systems, acting as cellular tower-nodes in a global cellular telephony system whose ''user-set'' is the atmospheric-sampling and surface-level monitoring constellations. We thereby leverage the huge investment in cellular (satellite) telephony and GPS technologies, with large technical and economic gains. This proposal minimizes sponsor forward commitment along its entire programmatic trajectory, and moreover may return data of weather-predictive value soon after field activities commence. We emphasize its high near-term value for making better mesoscale, relatively short-term weather predictions with computing-intensive means, and its great long-term utility in enhancing the meteorological basis for global change predictive studies. We again note that adverse impacts of weather

  19. Long Range Weather Prediction III: Miniaturized Distributed Sensors for Global Atmospheric Measurements

    SciTech Connect

    Teller, E; Leith, C; Canavan, G; Wood, L

    2001-11-13

    We continue consideration of ways-and-means for creating, in an evolutionary, ever-more-powerful manner, a continually-updated data-base of salient atmospheric properties sufficient for finite differenced integration-based, high-fidelity weather prediction over intervals of 2-3 weeks, leveraging the 10{sup 14} FLOPS digital computing systems now coming into existence. A constellation comprised of 10{sup 6}-10{sup 9} small atmospheric sampling systems--high-tech superpressure balloons carrying early 21st century semiconductor devices, drifting with the local winds over the meteorological spectrum of pressure-altitudes--that assays all portions of the troposphere and lower stratosphere remains the central feature of the proposed system. We suggest that these devices should be active-signaling, rather than passive-transponding, as we had previously proposed only for the ground- and aquatic-situated sensors of this system. Instead of periodic interrogation of the intra-atmospheric transponder population by a constellation of sophisticated small satellites in low Earth orbit, we now propose to retrieve information from the instrumented balloon constellation by existing satellite telephony systems, acting as cellular tower-nodes in a global cellular telephony system whose ''user-set'' is the atmospheric-sampling and surface-level monitoring constellations. We thereby leverage the huge investment in cellular (satellite) telephony and GPS technologies, with large technical and economic gains. This proposal minimizes sponsor forward commitment along its entire programmatic trajectory, and moreover may return data of weather-predictive value soon after field activities commence. We emphasize its high near-term value for making better mesoscale, relatively short-term weather predictions with computing-intensive means, and its great long-term utility in enhancing the meteorological basis for global change predictive studies. We again note that adverse impacts of weather

  20. Global silicate mineralogy of the Moon from the Diviner lunar radiometer.

    PubMed

    Greenhagen, Benjamin T; Lucey, Paul G; Wyatt, Michael B; Glotch, Timothy D; Allen, Carlton C; Arnold, Jessica A; Bandfield, Joshua L; Bowles, Neil E; Donaldson Hanna, Kerri L; Hayne, Paul O; Song, Eugenie; Thomas, Ian R; Paige, David A

    2010-09-17

    We obtained direct global measurements of the lunar surface using multispectral thermal emission mapping with the Lunar Reconnaissance Orbiter Diviner Lunar Radiometer Experiment. Most lunar terrains have spectral signatures that are consistent with known lunar anorthosite and basalt compositions. However, the data have also revealed the presence of highly evolved, silica-rich lunar soils in kilometer-scale and larger exposures, expanded the compositional range of the anorthosites that dominate the lunar crust, and shown that pristine lunar mantle is not exposed at the lunar surface at the kilometer scale. Together, these observations provide compelling evidence that the Moon is a complex body that has experienced a diverse set of igneous processes.

  1. Re-Assessing The Weathering Signature Of Continental Waters: Constraints from Mg and Li isostope ratios

    NASA Astrophysics Data System (ADS)

    Tipper, E.

    2015-12-01

    Chemical weathering mediates Earth's carbon cycle and hence global climate over geological time-scales. Ca and Mg from silicate minerals are released to the solute phase during dissolution with carbonic acid and subsequenty buried as marine carbonate. This mechanism has provided the climatic feedback that has maintained Earth's climate equable over geological history. Quantitative models of contemporary silicate weathering processes coupled to estimates of modern day carbon fluxes associated with silicate weathering are thus fundamental to understanding the feedbacks between the carbon cycle, climate and chemical weathering. Estimating the Ca and Mg released from silicate weathering is not straightforward because their fluxes are dominated by carbonate weathering. Instead, contemporary silicate weathering fluxes are typically quantified based on Na and K fluxes in river waters because these elements are considered to be derived from silicate weathering. Silicate Ca fluxes are based on the product of the Na flux and an average Ca/Na ratio of silicate rocks. This relies on the assumption that Na and K are predominantly released by silicate mineral dissolution. However, it has been proposed that Na-Ca exchange reactions with clay on mineral surfaces could account for 80% of the Na in rivers waters. At present, none of the methods to estimate silicate weathering fluxes and associated CO2 consumption account for cation-exchange reactions largely because physical and chemical weathering were assumed to be steady state processes implying that cation exchange has no net influence on weathering fluxes. In tandem, there are numerous reports of stable isotope fractionation of the elements Mg and Li that are inferred to be induced by clay minerals. At present it is not clear whether this fractionation is associated with mineral surfaces (exchange) or structural incorporation into the clays. Here we will report Mg and Li isotope analyses on dissolved, exchangeable and

  2. The acid and alkalinity budgets of weathering in the Andes-Amazon system: Insights into the erosional control of global biogeochemical cycles

    NASA Astrophysics Data System (ADS)

    Torres, Mark A.; West, A. Joshua; Clark, Kathryn E.; Paris, Guillaume; Bouchez, Julien; Ponton, Camilo; Feakins, Sarah J.; Galy, Valier; Adkins, Jess F.

    2016-09-01

    The correlation between chemical weathering fluxes and denudation rates suggests that tectonic activity can force variations in atmospheric pCO2 by modulating weathering fluxes. However, the effect of weathering on pCO2 is not solely determined by the total mass flux. Instead, the effect of weathering on pCO2 also depends upon the balance between 1) alkalinity generation by carbonate and silicate mineral dissolution and 2) sulfuric acid generation by the oxidation of sulfide minerals. In this study, we explore how the balance between acid and alkalinity generation varies with tectonic uplift to better understand the links between tectonics and the long-term carbon cycle. To trace weathering reactions across the transition from the Peruvian Andes to the Amazonian foreland basin, we measured a suite of elemental concentrations (Na, K, Ca, Mg, Sr, Si, Li, SO4, and Cl) and isotopic ratios (87Sr/86Sr and δ34S) on both dissolved and solid phase samples. Using an inverse model, we quantitatively link systematic changes in solute geochemistry with elevation to downstream declines in sulfuric acid weathering as well as the proportion of cations sourced from silicates. With a new carbonate-system framework, we show that weathering in the Andes Mountains is a CO2 source whereas foreland weathering is a CO2 sink. These results are consistent with the theoretical expectation that the ratio of sulfide oxidation to silicate weathering increases with increasing erosion. Altogether, our results suggest that the effect of tectonically-enhanced weathering on atmospheric pCO2 is strongly modulated by sulfide mineral oxidation.

  3. Stable runoff and weathering fluxes into the oceans over Quaternary climate cycles

    NASA Astrophysics Data System (ADS)

    von Blanckenburg, Friedhelm; Bouchez, Julien; Ibarra Daniel, E.; Kate, Maher

    2016-04-01

    Throughout the Quaternary, erosion and biogeochemical cycles at the Earth surface responded to large oscillations in temperature and precipitation. Such changes are recorded in sedimentary archives and radiogenic isotope mass balances. In contrast, climate models combined with empirical relationships between measures of climate and weatheringindicate minimal change in global weathering rates. Here we resolve the extent to which the supply of dissolved elements to oceans was altered by glacial-interglacial oscillations with a new weathering proxy. We estimate relative weathering fluxes from the ratio of cosmogenic beryllium-10, produced in the atmosphere, to the stable isotope beryllium-9, introduced into the oceans by the riverine silicate weathering flux [1]. Using sedimentary Be records,we show over multiple glacial-interglacial cycles, and over the last 2 Myr, shifts in global silicate weathering inputs are not detectable [2]. Combining climate model simulations of the Last Glacial Maximum with a new model for silicate weathering, we show how large regional variability in runoff between glacial and interglacial periods was insufficient to shift global weathering fluxes. The observed and modeled stability explains why removal of atmospheric CO2 by silicate weathering has been balanced to within 2% of net CO2 degassing over the last 600 kyr. Because over >104 yr time scales weathering and erosion are also coupled, our study provides additional evidence that global erosion rates did not shift along any long-term trend over the Quaternary [3]. [1] von Blanckenburg, F. and Bouchez, J. (2014). "River fluxes to the sea from the oceans 10Be/9Be ratio." Earth and Planetary Science Letters 387: 34-43. [2] von Blanckenburg, F., Bouchez. J. Ibarra, D.E., Maher, K. (2015). "Stable runoff and weathering fluxes into the oceans over Quaternary climate cycles." Nature Geosciences 10.1038/ngeo2452. [3] Willenbring, J. K. and von Blanckenburg, F. (2010). "Long-term stability of

  4. Impacts of increasing the aerosol complexity in the Met Office global numerical weather prediction model

    NASA Astrophysics Data System (ADS)

    Mulcahy, J. P.; Walters, D. N.; Bellouin, N.; Milton, S. F.

    2014-05-01

    The inclusion of the direct and indirect radiative effects of aerosols in high-resolution global numerical weather prediction (NWP) models is being increasingly recognised as important for the improved accuracy of short-range weather forecasts. In this study the impacts of increasing the aerosol complexity in the global NWP configuration of the Met Office Unified Model (MetUM) are investigated. A hierarchy of aerosol representations are evaluated including three-dimensional monthly mean speciated aerosol climatologies, fully prognostic aerosols modelled using the CLASSIC aerosol scheme and finally, initialised aerosols using assimilated aerosol fields from the GEMS project. The prognostic aerosol schemes are better able to predict the temporal and spatial variation of atmospheric aerosol optical depth, which is particularly important in cases of large sporadic aerosol events such as large dust storms or forest fires. Including the direct effect of aerosols improves model biases in outgoing long-wave radiation over West Africa due to a better representation of dust. However, uncertainties in dust optical properties propagate to its direct effect and the subsequent model response. Inclusion of the indirect aerosol effects improves surface radiation biases at the North Slope of Alaska ARM site due to lower cloud amounts in high-latitude clean-air regions. This leads to improved temperature and height forecasts in this region. Impacts on the global mean model precipitation and large-scale circulation fields were found to be generally small in the short-range forecasts. However, the indirect aerosol effect leads to a strengthening of the low-level monsoon flow over the Arabian Sea and Bay of Bengal and an increase in precipitation over Southeast Asia. Regional impacts on the African Easterly Jet (AEJ) are also presented with the large dust loading in the aerosol climatology enhancing of the heat low over West Africa and weakening the AEJ. This study highlights the

  5. HESFIRE: a global fire model to explore the role of anthropogenic and weather drivers

    SciTech Connect

    Le Page, Yannick LB; Morton, Douglas; Bond-Lamberty, Benjamin; Pereira, Jose M.; Hurtt, George C.

    2015-02-13

    Vegetation fires are a major driver of ecosystem dynamics and greenhouse gas emissions. Anticipating potential changes in fire activity and their impacts relies first on a realistic model of fire activity (e.g., fire incidence and interannual variability) and second on a model accounting for fire impacts (e.g., mortality and emissions). In this paper, we focus on our understanding of fire activity and describe a new fire model, HESFIRE (Human–Earth System FIRE), which integrates the influence of weather, vegetation characteristics, and human activities on fires in a stand-alone framework. It was developed with a particular emphasis on allowing fires to spread over consecutive days given their major contribution to burned areas in many ecosystems. A subset of the model parameters was calibrated through an optimization procedure using observation data to enhance our knowledge of regional drivers of fire activity and improve the performance of the model on a global scale. Modeled fire activity showed reasonable agreement with observations of burned area, fire seasonality, and interannual variability in many regions, including for spatial and temporal domains not included in the optimization procedure. Significant discrepancies are investigated, most notably regarding fires in boreal regions and in xeric ecosystems and also fire size distribution. The sensitivity of fire activity to model parameters is analyzed to explore the dominance of specific drivers across regions and ecosystems. The characteristics of HESFIRE and the outcome of its evaluation provide insights into the influence of anthropogenic activities and weather, and their interactions, on fire activity.

  6. Increasing Diversity in Global Climate Change, Space Weather and Space Technology Research and Education

    NASA Astrophysics Data System (ADS)

    Johnson, L. P.; Austin, S. A.; Howard, A. M.; Boxe, C.; Jiang, M.; Tulsee, T.; Chow, Y. W.; Zavala-Gutierrez, R.; Barley, R.; Filin, B.; Brathwaite, K.

    2015-12-01

    This presentation describes projects at Medgar Evers College of the City University of New York that contribute to the preparation of a diverse workforce in the areas of ocean modeling, planetary atmospheres, space weather and space technology. Specific projects incorporating both undergraduate and high school students include Assessing Parameterizations of Energy Input to Internal Ocean Mixing, Reaction Rate Uncertainty on Mars Atmospheric Ozone, Remote Sensing of Solar Active Regions and Intelligent Software for Nano-satellites. These projects are accompanied by a newly developed Computational Earth and Space Science course to provide additional background on methodologies and tools for scientific data analysis. This program is supported by NSF award AGS-1359293 REU Site: CUNY/GISS Center for Global Climate Research and the NASA New York State Space Grant Consortium.

  7. Proceedings of the First National Workshop on the Global Weather Experiment: Current Achievements and Future Directions, volume 2, part 2

    NASA Technical Reports Server (NTRS)

    1985-01-01

    An assessment of the status of research using Global Weather Experiment (GWE) data and of the progress in meeting the objectives of the GWE, i.e., better knowledge and understanding of the atmosphere in order to provide more useful weather prediction services. Volume Two consists of a compilation of the papers presented during the workshop. These cover studies that addressed GWE research objectives and utilized GWE information. The titles in Part 2 of this volume include General Circulation Planetary Waves, Interhemispheric, Cross-Equatorial Exchange, Global Aspects of Monsoons, Midlatitude-Tropical Interactions During Monsoons, Stratosphere, Southern Hemisphere, Parameterization, Design of Observations, Oceanography, Future Possibilities, Research Gaps, with an Appendix.

  8. FORMOSAT-7/COSMIC-2 GNSS radio occultation constellation mission for global weather monitoring

    NASA Astrophysics Data System (ADS)

    Cook, K.; Fong, Chen-Joe; Wenkel, M. J.; Wilczynski, P.; Yen, N.; Chang, G. S.

    The United States and Taiwan, through an Agreement signed in May 2010, have begun to jointly develop a satellite program to deliver next-generation global navigation satellite system (GNSS) radio occultation (RO) data to users around the world. This Program, known as FORMOSAT-7/COSMIC-2, is the follow-on to the FORMOSAT-3/COSMIC mission, which was a joint US-Taiwan 6-satellite constellation demonstration mission launched in April 2006. The COSMIC mission was the world's first operational GPS radio occultation (GPS-RO) mission for global weather forecast; climate monitoring; atmospheric, ionospheric, and geodetic research. The GPS-RO data from COSMIC has been extremely valuable to the climate, meteorology, and space weather communities, including real-time forecasting users as well as U.S. and international research communities. FORMOSAT-3/COSMIC reached the end of its design life in 2011. The constellation satellites have exhibited some unrecoverable anomalies and consequently the critical real-time satellite observing capability is degrading and may go offline with uncertainty in the coming few years. The National Oceanic and Atmospheric Administration (NOAA) and Taiwan's National Space Organization (NSPO) have recognized the potential GPS-RO data gap due to the degrading COSMIC/FORMOSAT-3 constellation and agreed to implement the follow-on COSMIC-2/FORMOSAT-7 mission in 2010. Both experienced programmatic difficulties in the past two years in the course of implementing the COSMIC-2/FORMOSAT-7 Program; however, significant progress over the past six months has occurred. This paper will provide an overview of the COSMIC2/FORMOSAT-7 Program including the Program goals and objectives. It will also discuss the status of the Program including current satellite and constellation configuration, activities to determine the optimal and minimal ground system architecture to meet data latency requirements, and other discussions on the mission and scientific payload technol

  9. Hydrologic Regulation of Global Geochemical Cycles

    NASA Astrophysics Data System (ADS)

    Maher, K.

    2015-12-01

    Earth's temperature is thought to be regulated by a negative feedback between atmospheric CO2 levels and chemical weathering of silicate rocks. However, direct evidence for the operation of this feedback over million-year timescales is difficult to obtain. For example, weathering fluxes over the last 20 million years of the Cenozoic Era, calculated using marine isotopic proxies (i.e. 87Sr/86Sr, δ7Li, and 187Os/188Os), appear inconsistent with past atmospheric CO2 levels and carbon mass balance. Similarly, observations from modern catchments suggest that chemical weathering fluxes are strongly correlated with erosion rates and only weakly correlated with temperature. As an alternative approach to evaluating the operation of a negative feedback, we use the major surface reservoirs of carbon to determine the imbalance in the geologic carbon cycle and the required silicate weathering flux over the Cenozoic. A miniscule (0.5-1%) increase in silicate weathering is necessary to explain the long-term decline in CO2 levels over the Cenozoic, providing evidence for a strong negative feedback between silicate weathering and climate. Rather than an appreciable increase in the silicate weathering flux, the long-term decrease in CO2levels may be due to an increase in the strength of the silicate weathering feedback. To explain the observed variations in the strength of the weathering feedback during the Cenozoic, we present a model for silicate weathering where hydrologic processes regulate climatic and tectonic forcings due to the presence of a thermodynamic limit to weathering fluxes. Climate regulation by silicate weathering is thus strongest when global topography is elevated, similar to today, and lowest when global topography is more subdued, allowing planetary temperatures to vary depending on the global distribution of topography and mountain belts. These results also motivate several key outstanding challenges in earth surface processes, including the need to

  10. Proceedings of the First National Workshop on the Global Weather Experiment: Current Achievements and Future Directions, volume 1

    NASA Technical Reports Server (NTRS)

    1985-01-01

    A summary of the proceedings in which the most important findings stemming from the Global Weather Experiment (GWE) are highlighted, additional key results and recommendations are comered, and the presentations and discussion are summarized. Detailed achievements, unresolved problems, and recommendations are included.

  11. HESFIRE: a global fire model to explore the role of anthropogenic and weather drivers

    DOE PAGES

    Le Page, Yannick LB; Morton, Douglas; Bond-Lamberty, Benjamin; ...

    2015-02-13

    Vegetation fires are a major driver of ecosystem dynamics and greenhouse gas emissions. Anticipating potential changes in fire activity and their impacts relies first on a realistic model of fire activity (e.g., fire incidence and interannual variability) and second on a model accounting for fire impacts (e.g., mortality and emissions). In this paper, we focus on our understanding of fire activity and describe a new fire model, HESFIRE (Human–Earth System FIRE), which integrates the influence of weather, vegetation characteristics, and human activities on fires in a stand-alone framework. It was developed with a particular emphasis on allowing fires to spreadmore » over consecutive days given their major contribution to burned areas in many ecosystems. A subset of the model parameters was calibrated through an optimization procedure using observation data to enhance our knowledge of regional drivers of fire activity and improve the performance of the model on a global scale. Modeled fire activity showed reasonable agreement with observations of burned area, fire seasonality, and interannual variability in many regions, including for spatial and temporal domains not included in the optimization procedure. Significant discrepancies are investigated, most notably regarding fires in boreal regions and in xeric ecosystems and also fire size distribution. The sensitivity of fire activity to model parameters is analyzed to explore the dominance of specific drivers across regions and ecosystems. The characteristics of HESFIRE and the outcome of its evaluation provide insights into the influence of anthropogenic activities and weather, and their interactions, on fire activity.« less

  12. Carbon dioxide efficiency of terrestrial enhanced weathering.

    PubMed

    Moosdorf, Nils; Renforth, Phil; Hartmann, Jens

    2014-05-06

    Terrestrial enhanced weathering, the spreading of ultramafic silicate rock flour to enhance natural weathering rates, has been suggested as part of a strategy to reduce global atmospheric CO2 levels. We budget potential CO2 sequestration against associated CO2 emissions to assess the net CO2 removal of terrestrial enhanced weathering. We combine global spatial data sets of potential source rocks, transport networks, and application areas with associated CO2 emissions in optimistic and pessimistic scenarios. The results show that the choice of source rocks and material comminution technique dominate the CO2 efficiency of enhanced weathering. CO2 emissions from transport amount to on average 0.5-3% of potentially sequestered CO2. The emissions of material mining and application are negligible. After accounting for all emissions, 0.5-1.0 t CO2 can be sequestered on average per tonne of rock, translating into a unit cost from 1.6 to 9.9 GJ per tonne CO2 sequestered by enhanced weathering. However, to control or reduce atmospheric CO2 concentrations substantially with enhanced weathering would require very large amounts of rock. Before enhanced weathering could be applied on large scales, more research is needed to assess weathering rates, potential side effects, social acceptability, and mechanisms of governance.

  13. Impact of nitrogenous fertilizers on carbonate dissolution in small agricultural catchments: Implications for weathering CO 2 uptake at regional and global scales

    NASA Astrophysics Data System (ADS)

    Perrin, Anne-Sophie; Probst, Anne; Probst, Jean-Luc

    2008-07-01

    catchments. Using these values, the deficit of CO 2 uptake can be estimated as up to 0.22-0.53 and 12-29 Tg yr -1 CO 2 on a country scale (France) and a global scale, respectively. These losses represent up to 5.7-13.4% and only 1.6-3.8% of the total CO 2 flux naturally consumed by carbonate dissolution, for France and on a global scale, respectively. Nevertheless, this loss of alkalinity relative to the Ca + Mg content relates to carbonate weathering by protons from N-fertilizers nitrification, which is a net source of CO 2 for the atmosphere. This anthropogenic CO 2 source is not negligible since it could reach 6-15% of CO 2 uptake by natural silicate weathering and could consequently partly counterbalance this natural CO 2 sink. 1 Tg of carbon = 10 12 g of C = 0.083 10 12 mol of C.

  14. Atmospheric test models and numerical experiments for the simulation of the global distribution of weather data transponders

    SciTech Connect

    Grossman, A; Molenkamp, C R

    1999-08-25

    A proposal has been made to establish a high density global network of atmospheric micro transponders to record time, temperature, and wind data with time resolution of {le} 1 minute, temperature accuracy of {+-} 1 K, spatial resolution no poorer than {approx}3km horizontally and {approx}0.1km vertically, and 2-D speed accuracy of {le} 1m/s. This data will be used in conjunction with advanced numerical weather prediction models to provide increases in the reliability of long range weather forecasts. Major advances in data collection technology will be required to provide the proposed high-resolution data collection network. Systems studies must be undertaken to determine insertion requirements, spacing, and evolution of the transponder ensemble, which will be used to collect the data. Numerical models which provide realistic global weather pattern simulations must be utilized in order to perform these studies. A global circulation model with a 3{sup o} horizontal resolution has been used for initial simulations of the generation and evolution of transponder distributions. These studies indicate that reasonable global coverage of transponders can be achieved by a launch scenario consisting of the sequential launch of transponders at specified heights from a globally distributed set of launch sites.

  15. Seafloor Weathering As a Long-Term Climate Regulation Mechanism

    NASA Astrophysics Data System (ADS)

    Farahat, N. X.; Abbot, D. S.; Archer, D. E.

    2014-12-01

    The global carbon cycle determines the distribution of carbon between the atmosphere, ocean, and solid earth. Carbon from the mantle enters the Earth's surficial environment as CO2 by volcanic outgassing, and carbon is buried in the oceanic crust as carbonate rocks during silicate rock weathering. The subduction of carbonate-rich oceanic plates returns carbon to the mantle, closing the cycle. Subtle adjustments in continental silicate weathering, widely held to consume atmospheric CO2 at a rate controlled by climate, are believed to have maintained habitable conditions throughout Earth's history. This long term climate regulation mechanism is known as a climate-weathering feedback. Seafloor weathering, low-temperature basalt alteration and carbonate precipitation in the permeable upper oceanic crust, has been proposed as a climate-weathering feedback as well, but the link to climate is presently poorly understood. Such a climate regulation mechanism would be particularly important on waterworld planets where continental silicate weathering cannot regulate climate. It has so far not been possible to determine whether changes in seafloor weathering could contribute to climate regulation on Earth or in a waterworld scenario because the necessary modeling framework has not yet been developed. However, advances in porous media flow modeling and reactive transport modeling, as well as the availability of inexpensive computational power, allow the seafloor weathering problem to be looked at in greater detail. We have developed a spatially resolved two-dimmensional (2D) numerical model of seafloor weathering in the permeable upper oceanic crust. This model simulates 2D off-axis hydrothermal flow coupled to geochemical alteration of seafloor basalt by modeling reactive transport of chemical species in seawater-derived hydrothermal fluids. The focus of this research is to use the model to determine the effect of geological and climatic factors on seafloor weathering, which

  16. Weather Avoidance Guidelines for NASA Global Hawk High-Altitude UAS

    NASA Technical Reports Server (NTRS)

    Cecil, Daniel J.; Zipser, Edward J.; Velden, Chris; Monette, Sarah; Heymsfield, Gerry; Braun, Scott; Newman, Paul; Black, Pete; Black, Michael; Dunion, Jason

    2014-01-01

    NASA operates two Global Hawk unmanned aircraft systems for Earth Science research projects. In particular, they are used in the Hurricane and Severe Storm Sentinel (HS3) project during 2012, 2013, and 2014 to take measurements from the environment around tropical cyclones, and from directly above tropical cyclones. There is concern that strict adherence to the weather avoidance rules used in 2012 may sacrifice the ability to observe important science targets. We have proposed modifications to these weather avoidance rules that we believe will improve the ability to observe science targets without compromising aircraft safety. The previous guidelines, used in 2012, specified: Do not approach thunderstorms within 25 nm during flight at FL500 or below. When flying above FL500: Do not approach reported lightning within 25NM in areas where cloud tops are reported at FL500 or higher. Aircraft should maintain at least 10000 ft vertical separation from reported lightning if cloud tops are below FL500. No over-flight of cumulus tops higher than FL500. No flight into forecast or reported icing conditions. No flight into forecast or reported moderate or severe turbulence Based on past experience with high-altitude flights over tropical cyclones, we have recommended changing this guidance to: Do not approach thunderstorms within 25 nm during flight at FL500 or below. Aircraft should maintain at least 5000 ft vertical separation from significant convective cloud tops except: a) When cloud tops above FL500: In the event of reported significant lightning activity or indicators of significant overshooting tops, do not approach within 10-25 nm, depending on pilot discretion and advice from Mission Scientist. b) When cloud tops are below FL500, maintain 10000 ft separation from reported significant lightning or indicators of significant overshooting tops. No flight into forecasted or reported icing conditions. No flight into forecasted or reported moderate or severe turbulence The

  17. Fundamental statistical relationships between monthly and daily meteorological variables: Temporal downscaling of weather based on a global observational dataset

    NASA Astrophysics Data System (ADS)

    Sommer, Philipp; Kaplan, Jed

    2016-04-01

    Accurate modelling of large-scale vegetation dynamics, hydrology, and other environmental processes requires meteorological forcing on daily timescales. While meteorological data with high temporal resolution is becoming increasingly available, simulations for the future or distant past are limited by lack of data and poor performance of climate models, e.g., in simulating daily precipitation. To overcome these limitations, we may temporally downscale monthly summary data to a daily time step using a weather generator. Parameterization of such statistical models has traditionally been based on a limited number of observations. Recent developments in the archiving, distribution, and analysis of "big data" datasets provide new opportunities for the parameterization of a temporal downscaling model that is applicable over a wide range of climates. Here we parameterize a WGEN-type weather generator using more than 50 million individual daily meteorological observations, from over 10'000 stations covering all continents, based on the Global Historical Climatology Network (GHCN) and Synoptic Cloud Reports (EECRA) databases. Using the resulting "universal" parameterization and driven by monthly summaries, we downscale mean temperature (minimum and maximum), cloud cover, and total precipitation, to daily estimates. We apply a hybrid gamma-generalized Pareto distribution to calculate daily precipitation amounts, which overcomes much of the inability of earlier weather generators to simulate high amounts of daily precipitation. Our globally parameterized weather generator has numerous applications, including vegetation and crop modelling for paleoenvironmental studies.

  18. Application of dynamical systems theory to global weather phenomena revealed by satellite imagery

    NASA Technical Reports Server (NTRS)

    Saltzman, Barry; Ebisuzaki, Wesley; Maasch, Kirk A.; Oglesby, Robert; Pandolfo, Lionel; Tang, Chung-Muh

    1989-01-01

    Theoretical studies of low frequency and seasonal weather variability; dynamical properties of observational and general circulation model (GCM)-generated records; effects of the hydrologic cycle and latent heat release on extratropical weather; and Earth-system science studies are summarized.

  19. Atmospheric Test Models and Numerical Experiments for the Simulation of the Global Distributions of Weather Data Transponders III. Horizontal Distributions

    SciTech Connect

    Molenkamp, C.R.; Grossman, A.

    1999-12-20

    A network of small balloon-borne transponders which gather very high resolution wind and temperature data for use by modern numerical weather predication models has been proposed to improve the reliability of long-range weather forecasts. The global distribution of an array of such transponders is simulated using LLNL's atmospheric parcel transport model (GRANTOUR) with winds supplied by two different general circulation models. An initial study used winds from CCM3 with a horizontal resolution of about 3 degrees in latitude and longitude, and a second study used winds from NOGAPS with a 0.75 degree horizontal resolution. Results from both simulations show that reasonable global coverage can be attained by releasing balloons from an appropriate set of launch sites.

  20. Constraining the role of early land plants in Palaeozoic weathering and global cooling.

    PubMed

    Quirk, Joe; Leake, Jonathan R; Johnson, David A; Taylor, Lyla L; Saccone, Loredana; Beerling, David J

    2015-08-22

    How the colonization of terrestrial environments by early land plants over 400 Ma influenced rock weathering, the biogeochemical cycling of carbon and phosphorus, and climate in the Palaeozoic is uncertain. Here we show experimentally that mineral weathering by liverworts—an extant lineage of early land plants—partnering arbuscular mycorrhizal (AM) fungi, like those in 410 Ma-old early land plant fossils, amplified calcium weathering from basalt grains threefold to sevenfold, relative to plant-free controls. Phosphate weathering by mycorrhizal liverworts was amplified 9-13-fold over plant-free controls, compared with fivefold to sevenfold amplification by liverworts lacking fungal symbionts. Etching and trenching of phyllosilicate minerals increased with AM fungal network size and atmospheric CO2 concentration. Integration of grain-scale weathering rates over the depths of liverwort rhizoids and mycelia (0.1 m), or tree roots and mycelia (0.75 m), indicate early land plants with shallow anchorage systems were probably at least 10-fold less effective at enhancing the total weathering flux than later-evolving trees. This work challenges the suggestion that early land plants significantly enhanced total weathering and land-to-ocean fluxes of calcium and phosphorus, which have been proposed as a trigger for transient dramatic atmospheric CO2 sequestration and glaciations in the Ordovician.

  1. Constraining the role of early land plants in Palaeozoic weathering and global cooling

    PubMed Central

    Quirk, Joe; Leake, Jonathan R.; Johnson, David A.; Taylor, Lyla L.; Saccone, Loredana; Beerling, David J.

    2015-01-01

    How the colonization of terrestrial environments by early land plants over 400 Ma influenced rock weathering, the biogeochemical cycling of carbon and phosphorus, and climate in the Palaeozoic is uncertain. Here we show experimentally that mineral weathering by liverworts—an extant lineage of early land plants—partnering arbuscular mycorrhizal (AM) fungi, like those in 410 Ma-old early land plant fossils, amplified calcium weathering from basalt grains threefold to sevenfold, relative to plant-free controls. Phosphate weathering by mycorrhizal liverworts was amplified 9–13-fold over plant-free controls, compared with fivefold to sevenfold amplification by liverworts lacking fungal symbionts. Etching and trenching of phyllosilicate minerals increased with AM fungal network size and atmospheric CO2 concentration. Integration of grain-scale weathering rates over the depths of liverwort rhizoids and mycelia (0.1 m), or tree roots and mycelia (0.75 m), indicate early land plants with shallow anchorage systems were probably at least 10-fold less effective at enhancing the total weathering flux than later-evolving trees. This work challenges the suggestion that early land plants significantly enhanced total weathering and land-to-ocean fluxes of calcium and phosphorus, which have been proposed as a trigger for transient dramatic atmospheric CO2 sequestration and glaciations in the Ordovician. PMID:26246550

  2. From short-range barotropic modelling to extended-range global weather prediction: a 40-year perspective

    NASA Astrophysics Data System (ADS)

    Bengtsson, Lennart

    1999-01-01

    At the end of the 20th century, we can look back on a spectacular development of numerical weather prediction, which has, practically uninterrupted, been going on since the middle of the century. High-resolution predictions for more than a week ahead for any part of the globe are now routinely produced and anyone with an Internet connection can access many of these forecasts for anywhere in the world. Extended predictions for several seasons ahead are also being done — the latest El Niño event in 1997/1998 is an example of such a successful prediction.The great achievement is due to a number of factors including the progress in computational technology and the establishment of global observing systems, combined with a systematic research program with an overall strategy towards building comprehensive prediction systems for climate and weather. In this article, I will discuss the different evolutionary steps in this development and the way new scientific ideas have contributed to efficiently explore the computing power and in using observations from new types of observing systems. Weather prediction is not an exact science due to unavoidable errors in initial data and in the models. To quantify the reliability of a forecast is therefore essential and probably more so the longer the forecasts are. Ensemble prediction is thus a new and important concept in weather and climate prediction,which I believe will become a routine aspect of weather prediction in the future. The limit between weather and climate prediction is becoming more and more diffuse and in the final part of this article I will outline the way I think development may proceed in the future.

  3. From short-range barotropic modelling to extended-range global weather prediction: a 40-year perspective

    NASA Astrophysics Data System (ADS)

    Bengtsson, Lennart

    1999-02-01

    At the end of the 20th century, we can look back on a spectacular development of numerical weather prediction, which has, practically uninterrupted, been going on since the middle of the century. High-resolution predictions for more than a week ahead for any part of the globe are now routinely produced and anyone with an Internet connection can access many of these forecasts for anywhere in the world. Extended predictions for several seasons ahead are also being done — the latest El Niño event in 1997/1998 is an example of such a successful prediction. The great achievement is due to a number of factors including the progress in computational technology and the establishment of global observing systems, combined with a systematic research program with an overall strategy towards building comprehensive prediction systems for climate and weather. In this article, I will discuss the different evolutionary steps in this development and the way new scientific ideas have contributed to efficiently explore the computing power and in using observations from new types of observing systems. Weather prediction is not an exact science due to unavoidable errors in initial data and in the models. To quantify the reliability of a forecast is therefore essential and probably more so the longer the forecasts are. Ensemble prediction is thus a new and important concept in weather and climate prediction, which I believe will become a routine aspect of weather prediction in the future. The limit between weather and climate prediction is becoming more and more diffuse and in the final part of this article I will outline the way I think development may proceed in the future.

  4. Negligible glacial-interglacial variation in continental chemical weathering rates.

    PubMed

    Foster, Gavin L; Vance, Derek

    2006-12-14

    Chemical weathering of the continents is central to the regulation of atmospheric carbon dioxide concentrations, and hence global climate. On million-year timescales silicate weathering leads to the draw-down of carbon dioxide, and on millennial timescales chemical weathering affects the calcium carbonate saturation state of the oceans and hence their uptake of carbon dioxide. However, variations in chemical weathering rates over glacial-interglacial cycles remain uncertain. During glacial periods, cold and dry conditions reduce the rate of chemical weathering, but intense physical weathering and the exposure of carbonates on continental shelves due to low sea levels may increase this rate. Here we present high-resolution records of the lead isotope composition of ferromanganese crusts from the North Atlantic Ocean that cover the past 550,000 years. Combining these records with a simple quantitative model of changes in the lead isotope composition of the deep North Atlantic Ocean in response to chemical weathering, we find that chemical weathering rates were two to three times lower in the glaciated interior of the North Atlantic Region during glacial periods than during the intervening interglacial periods. This decrease roughly balances the increase in chemical weathering caused by the exposure of continental shelves, indicating that chemical weathering rates remained relatively constant on glacial-interglacial timescales. On timescales of more than a million years, however, we suggest that enhanced weathering of silicate glacial sediments during interglacial periods results in a net draw-down of atmospheric carbon dioxide, creating a positive feedback on global climate that, once initiated, promotes cooling and further glaciation.

  5. Severe Space Weather Events: Global Geospace Responses to Powerful Solar Wind Drivers (Invited)

    NASA Astrophysics Data System (ADS)

    Baker, D.

    2009-12-01

    Recent international space science programs have made a concerted effort to study activity on the Sun, the propagation of energy bursts from the Sun to near-Earth space, energy coupling into the magnetosphere, and its redistribution and deposition in the upper and middle atmosphere. Extreme solar, geomagnetic and solar wind conditions can be observed by a large international array of satellites and ground-based sensors. We discuss the types of space weather-related problems that have been identified in recent times and consider examples of space weather-induced spacecraft (and ground-based) anomalies and failures that affect both civilian and military systems. Special attention will be given to delineating the specific kinds of geospace responses that occur for different transient solar wind drivers. In this context, we discuss near-term plans to consolidate and integrate understanding as an important component of the community effort to propose technical and operational solutions to space weather problems. I will focus on new scientific advancement that is needed for successful space weather programs and will describe actions that can help assure a good future integrated space weather program.

  6. Vertical structure of the wind field during the Special Observing Period I of the Global Weather Experiment

    NASA Technical Reports Server (NTRS)

    Paegle, J. N.; Paegle, J.; Zhen, Z.; Sampson, G.

    1986-01-01

    The vertical structure of the global atmosphere is analyzed for selected periods of the Special Observing Period I (SOP-I) for the Global Weather Experiment (GWE). The analysis consists of projection of the stream-function and velocity potential at 200 and 850 mb on spherical harmonics and of the wind and height fields on the normal modes of a linearized form of the primitive equations for a basic state at rest. The kinematic vertical structure is discussed in terms of correlation coefficients of the 200 mb and 850 mb winds and analysis of the internal and external normal modes of the primitive equations. The reliability of the results is checked by applying the same analysis methods to data sets obtained from three different institutions: Geophysical Fluid Dynamics Laboratory (GFDL), European Center for Medium Range Weather Forecasting (ECMWF), and Goddard Laboratory for the Atmospheres (GLA). It is found that, on a global basis, vertically reversing circulations are as important as the equivalent barotropic structures. For the verticaly reversing components, the gravity and mixed Rossby-gravity modes have contributions of the same order of magnitude as those of the Rossby modes in tropical latitudes.

  7. Research Review: Walter Orr Roberts on the Atmosphere, Global Pollution and Weather Modification

    ERIC Educational Resources Information Center

    Jacobsen, Sally

    1973-01-01

    Global Atmospheric Research Program is envisaged to study various aspects of the environment for the whole globe. Describes programs undertaken and the international problems involved in implementing results of such research on a global level. (PS)

  8. Flat world versus real world : where is weathering the most important ?

    NASA Astrophysics Data System (ADS)

    Godderis, Yves; Maffre, Pierre; Ladant, Jean-Baptiste; Donnadieu, Yannick

    2016-04-01

    Mountain ranges are a key driver of the Earth climates. Acting on a large range of timescales, they modulate the atmospheric and oceanic circulations but also plays a crucial role in regulating the geological carbon cycle through their impacts on erosion and continental weathering. Since the 90's, there is an ongoing debate about the role of the mountain uplift on the long term global cooling of the Earth climate. Mountain ranges are thought to enhance silicate weathering and the associated CO2 consumption. But this has been repeatedly questioned in the recent years. Here we present a new method for modeling the spatial distribution of both physical erosion and coupled chemical weathering. The IPSL ocean-atmosphere model calculates the continental climate, which is used to force the erosion/weathering model. We first compare the global silicate weathering for two geographical configurations: the present-day world with mountain ranges, and a world where all mountains have been removed. Depending on the chosen formalism for silicate weathering and on the climate changes linked to the removal of mountains, it can be higher in the flat world than in the real world, or up to 5 times weaker. In the second part of the talk, we will explore the role of the Hercynian mountain range on the onset and demise of the late Paleozoic ice age, within the context of the Pangea assembly.

  9. Space Weather Activities at SERC for IHY: (1) Local Education, (2) Global Outreach and (3) Data Base Service (P61)

    NASA Astrophysics Data System (ADS)

    Yumoto, K.; Magdas/Cpmn Group

    2006-11-01

    arnoldyuki@serc.kyushu-u.ac.jp The Space Environment Research Center (SERC), Kyushu University (KU), conducts everyday space weather “now casting”. There are two main goals in this effort: (1) to train and educate KU students about the complexities of the Sun-Earth system so that they can become space weather forecasters in the future, (2) to globally disseminate space weather information from SERC as a service to the scientific community and the general public. In order to understand the complexities of the Sun-Earth system, KU students analyze the data of four regions: (1) solar surface, (2) solar wind, (3) geospace, and (4) the Earth’s surface. Using real-time public data from SOHO Real Time Movies, Solar Monitor, NASA/GSFC/SDAC, and SEC‘s Anonymous FTP Server, they check each day the Sun Spot Number, locations of active regions and coronal holes, and identify solar flare events: GOES X-Ray Flux, CME: SOHO/ LASCO- C2, 3, and Proton Event: GOES Proton Flux. By analyzing ACE Real Time Data, KU students examine the solar wind (Speed, Density, Temperature) and Interplanetary Magnetic Field (IMF: Bt, Bz, Phi), and identify events of sector boundary, CIR, CME, and Shock/Discontinuity. To understand magnetic circumstances in geospace and on the Earth’s Surface, KU students analyze storms and substorms using Dst index (Kyoto Univ.), Kp index (NOAA), and Magnetic Pulsation Index (Pc 3, 4, and 5: SERC). Every morning KU students create a space weather report and then discuss it with the staff at SERC for local training and education. The report and its details are disseminated on the SERC Home Page (http://www.serc.kyushu-u.ac.jp) to provide "global outreach" for space weather information. MAGDAS (Magnetic Data Acquisition System) data are obtained from the Circum-pan Pacific Magnetometer Network (CPMN) locations during the IHY period (2007-2008). MAGDAS magnetometers are installed at 50 stations along the 210o magnetic meridian and the magnetic dip equator

  10. Toward Seamless Weather-Climate Prediction with a Global Cloud Resolving Model

    DTIC Science & Technology

    2012-09-30

    and the El Nino -Southern Oscillation (ENSO). Organized moist convections in the tropical atmosphere have their origins at space scale of less than...OMB control number. 1. REPORT DATE 2012 2. REPORT TYPE N/A 3. DATES COVERED - 4 . TITLE AND SUBTITLE Toward Seamless Weather-Climate...performance in reproducing the atmospheric internal modes such as MJO and teleconnection patterns associated with El Nino . This experiment may be

  11. Chemical weathering and CO₂ consumption in the Lower Mekong River.

    PubMed

    Li, Siyue; Lu, X X; Bush, Richard T

    2014-02-15

    Data on river water quality from 42 monitoring stations in the Lower Mekong Basin obtained during the period 1972-1996 was used to relate solute fluxes with controlling factors such as chemical weathering processes. The total dissolved solid (TDS) concentration of the Lower Mekong varied from 53 mg/L to 198 mg/L, and the median (114 mg/L) was compared to the world spatial median value (127 mg/L). Total cationic exchange capacity (Tz(+)) ranged from 729 to 2,607 μmolc/L, and the mean (1,572 μmolc/L) was 1.4 times higher than the world discharge-weighted average. Calcium and bicarbonate dominated the annual ionic composition, accounting for ~70% of the solute load that equalled 41.2×10(9)kg/y. TDS and major elements varied seasonally and in a predictable way with river runoff. The chemical weathering rate of 37.7t/(km(2)y), with respective carbonate and silicate weathering rates of 27.5t/(km(2) y) (13.8mm/ky) and 10.2t/(km(2) y) (3.8mm/ky), was 1.5 times higher than the global average. The CO2 consumption rate was estimated at 191×10(3)molCO2/(km(2)y) for silicate weathering, and 286×10(3)molCO2/(km(2)y) by carbonate weathering. In total, the Mekong basin consumed 228×10(9)molCO2/y and 152×10(9)molCO2/y by the combined weathering of carbonate and silicate, constituting 1.85% of the global CO2 consumption by carbonate weathering and 1.75% by silicates. This is marginally higher than its contribution to global water discharge ~1.3% and much higher than (more than three-fold) its contribution to world land surface area. Remarkable CO2 consumed by chemical weathering (380×10(9)mol/y) was similar in magnitude to dissolved inorganic carbon as HCO3(-) (370×10(9)mol/y) exported by the Mekong to the South China Sea. In this landscape, atmospheric CO2 consumption by rock chemical weathering represents an important carbon sink with runoff and physical erosion controlling chemical erosion.

  12. Developing a Global, Short-Term Fire Weather Forecasting Tool Using NWP Input Meteorology and Satellite Fire Data

    NASA Astrophysics Data System (ADS)

    Peterson, D. A.; Hyer, E. J.; Wang, J.

    2011-12-01

    In order to meet the emerging need for better estimates of biomass burning emissions in air quality and climate models, a statistical model is developed to characterize the effect of a given set of meteorological conditions on the following day's fire activity, including ignition and spread potential. Preliminary tests are conducted within several spatial domains of the North American boreal forest by investigating a wide range of meteorological information, including operational fire weather forecasting indices, such as the Canadian Forest Fire Danger Rating System (CFFDRS). However, rather than using local noon surface station data, the six components of the CFFDRS are modified to use inputs from the North America Regional Reanalysis (NARR) and the Navy's Operational Global Atmospheric Prediction System Model (NOGAPS). The Initial Spread Index (ISI) and the Fire Weather Index (FWI) are shown to be the most relevant components of the CFFDRS for short-term changes in fire activity. However, both components are found to be highly sensitive to variations in relative humidity and wind speed input data. Several variables related to fire ignition from dry lighting, such as instability and the synoptic pattern, are also incorporated. Cases of fire ignition, growth, decay, and extinction are stratified using satellite fire observations from the Geostationary Operational Environmental Satellites (GOES) and the MODerate Resolution Imaging Spectroradiometer (MODIS) and compared to the available suite of meteorological information. These comparisons reveal that combinations of meteorological variables, such as the FWI, ISI, and additional indices developed for this study, produce the greatest separability between major fire growth and decay cases, which are defined by the observed change in fire counts and fire radiative power. This information is used to derive statistical relationships affecting the short-term changes in fire activity and subsequently applied to other

  13. Sensing Hazards with Operational Unmanned Technology: NOAA's Application of the Global Hawk Aircraft for High Impact Weather Forecasting

    NASA Astrophysics Data System (ADS)

    Coffey, J. J.; Wick, G. A.; Hood, R. E.; Dunion, J. P.; Black, M. L.; Kenul, P.

    2015-12-01

    The NOAA Unmanned Aircraft Systems (UAS) program has begun the project Sensing Hazards with Operational Unmanned Technology (SHOUT) to evaluate the potential of high altitude, long endurance unmanned aircraft like the Global Hawk to improve forecasts of high-impact weather events and mitigate any degradations in the forecasts that might occur if there were a gap in satellite coverage. The first phase of the project is occurring this August and September using the NASA Global Hawk to study the impact of targeted observations of hurricanes and tropical cyclones. This follows several successful research missions conducted by both NASA and NOAA. Instruments on the aircraft for SHOUT include the Airborne Vertical Atmospheric Profiling System (AVAPS or dropsondes), the High Altitude MMIC Sounding Radiometer (HAMSR, a microwave sounder), the High-Altitude Imaging Wind and Rain Airborne Profiler (HIWRAP, a scanning Doppler precipitation radar), and the Lightning Instrument Package (LIP). The observations are being utilized for real-time forecasting, ingestion into operational weather models, and in post mission impact studies. Data impact is being evaluated through a combination of Observing System Experiments (OSEs) and Observing System Simulation Experiments (OSSEs). This presentation describes observations collected during this year's campaign, utilization of the data at the National Hurricane Center, and the results of preliminary data impact assessments of the data from SHOUT and previous experiments.

  14. World weather program

    NASA Technical Reports Server (NTRS)

    1980-01-01

    A brief description of the Global Weather Experiment is presented. The world weather watch program plan is described and includes a global observing system, a global data processing system, a global telecommunication system, and a voluntary cooperation program. A summary of Federal Agency plans and programs to meet the challenges of international meteorology for the two year period, FY 1980-1981, is presented.

  15. Understanding silicate hydration from quantitative analyses of hydrating tricalcium silicates

    NASA Astrophysics Data System (ADS)

    Pustovgar, Elizaveta; Sangodkar, Rahul P.; Andreev, Andrey S.; Palacios, Marta; Chmelka, Bradley F.; Flatt, Robert J.; D'Espinose de Lacaillerie, Jean-Baptiste

    2016-03-01

    Silicate hydration is prevalent in natural and technological processes, such as, mineral weathering, glass alteration, zeolite syntheses and cement hydration. Tricalcium silicate (Ca3SiO5), the main constituent of Portland cement, is amongst the most reactive silicates in water. Despite its widespread industrial use, the reaction of Ca3SiO5 with water to form calcium-silicate-hydrates (C-S-H) still hosts many open questions. Here, we show that solid-state nuclear magnetic resonance measurements of 29Si-enriched triclinic Ca3SiO5 enable the quantitative monitoring of the hydration process in terms of transient local molecular composition, extent of silicate hydration and polymerization. This provides insights on the relative influence of surface hydroxylation and hydrate precipitation on the hydration rate. When the rate drops, the amount of hydroxylated Ca3SiO5 decreases, thus demonstrating the partial passivation of the surface during the deceleration stage. Moreover, the relative quantities of monomers, dimers, pentamers and octamers in the C-S-H structure are measured.

  16. Understanding silicate hydration from quantitative analyses of hydrating tricalcium silicates

    PubMed Central

    Pustovgar, Elizaveta; Sangodkar, Rahul P.; Andreev, Andrey S.; Palacios, Marta; Chmelka, Bradley F.; Flatt, Robert J.; d'Espinose de Lacaillerie, Jean-Baptiste

    2016-01-01

    Silicate hydration is prevalent in natural and technological processes, such as, mineral weathering, glass alteration, zeolite syntheses and cement hydration. Tricalcium silicate (Ca3SiO5), the main constituent of Portland cement, is amongst the most reactive silicates in water. Despite its widespread industrial use, the reaction of Ca3SiO5 with water to form calcium-silicate-hydrates (C-S-H) still hosts many open questions. Here, we show that solid-state nuclear magnetic resonance measurements of 29Si-enriched triclinic Ca3SiO5 enable the quantitative monitoring of the hydration process in terms of transient local molecular composition, extent of silicate hydration and polymerization. This provides insights on the relative influence of surface hydroxylation and hydrate precipitation on the hydration rate. When the rate drops, the amount of hydroxylated Ca3SiO5 decreases, thus demonstrating the partial passivation of the surface during the deceleration stage. Moreover, the relative quantities of monomers, dimers, pentamers and octamers in the C-S-H structure are measured. PMID:27009966

  17. Toward Seamless Weather-Climate Prediction with a Global Cloud Resolving Model

    DTIC Science & Technology

    2016-01-14

    Organized moist convections in the tropical atmosphere have their origins at space scale of less than 10 km, and they play a key role in the initiation...such a global high resolution model that has a proper dynamic core and physics packages and is capable of representing realistically convection and...OBJECTIVE We aim to develop a new global model framework with the goal of reducing the uncertainty in moist convective processes. The Geophysical

  18. Chemical weathering and long-term CO2 consumption in the Ayeyarwady and Mekong river basins in the Himalayas

    NASA Astrophysics Data System (ADS)

    Manaka, Takuya; Otani, Souya; Inamura, Akihiko; Suzuki, Atsushi; Aung, Thura; Roachanakanan, Raywadee; Ishiwa, Takeshige; Kawahata, Hodaka

    2015-06-01

    The role of terrestrial river systems in the global carbon cycle on a long timescale has been a subject of interest, especially in the context of past climate changes such as the global cooling in the Cenozoic. The discharges of water and carbon into the ocean from the Himalayan watersheds are among the highest in the world. However, there are few reliable geochemical data from the Ayeyarwady River. This study focused on reevaluating chemical weathering in the Himalayan watersheds based on samples taken from the Ayeyarwady, Mekong, and Chao Phraya Rivers and on chemical analysis of the composition of dissolved substances in these rivers. Comparisons of water quality showed that, unlike in previous studies, the total alkalinity budgets of the Ayeyarwady are dominated by carbonate rather than silicate weathering. Long-term CO2 consumption by silicate weathering in the Ayeyarwady is estimated to be only 63-145 × 109 mol yr-1, which is only 10% of the previous estimate. Our results also suggest that the total Himalayan watersheds account for only about 10% of the total global CO2 consumption by silicate weathering. Although we need further studies, chemical weathering and associated CO2 uptake in the Himalayas likely played a lesser role in long-term global cooling in the past than previously appreciated.

  19. Investigating the Climate System: WEATHER. Global Awareness Tour. Problem-Based Classroom Modules

    ERIC Educational Resources Information Center

    Passow, Michael J.

    2003-01-01

    With support from National Aeronautics and Space Administration's (NASA's) Goddard Space Flight Center, Institute for Global Environmental Strategies (IGES) has developed educational materials that incorporate information and data from the Tropical Rainfall Measuring Mission (TRMM), a joint satellite mission between the United States and Japan.…

  20. Effects of climate on chemical weathering in watersheds

    USGS Publications Warehouse

    White, A.F.; Blum, A.E.

    1995-01-01

    Climatic effects on chemical weathering are evaluated by correlating variations in solute concentrations and fluxes with temperature, precipitation, runoff, and evapotranspiration (ET) for a worldwide distribution of sixty-eight watersheds underlain by granitoid rock types. Stream solute concentrations are strongly correlated with proportional ET loss, and evaporative concentration makes stream solute concentrations an inapprorpiate surrogate for chemical weathering. Chemical fluxes are unaffected by ET, and SiO2 and Na weathering fluxes exhibit systematic increases with precipitation, runoff, and temperature. However, warm and wet watersheds produce anomalously rapid weathering rates. A proposed model that provides an improved prediction of weathering rates over climatic extremes is the product of linear precipitation and Arrhenius temperature functions. The resulting apparent activation energies based on SiO2 and Na fluxes are 59.4 and 62.5 kJ.mol-1, respectively. The coupling between temperature and precipitation emphasizes the importance of tropical regions in global silicate weathering fluxes, and suggests it is not representative to use continental averages for temperature and precipitation in the weathering rate functions of global carbon cycling and climatic change models. Fluxes of K, Ca, and Mg exhibit no climatic correlation, implying that other processes, such as ion exchange, nutrient cycling, and variations in lithology, obscure any climatic signal. -from Authors

  1. Including latent and sensible heat fluxes from sea spray in global weather and climate models

    NASA Astrophysics Data System (ADS)

    Copsey, Dan

    2016-04-01

    Most standard weather and climate models calculate interfacial latent (evaporation) and sensible heat fluxes over the ocean based on parameterisations of atmospheric turbulence, using the wave state only in the calculation of surface roughness length. They ignore latent and sensible heat fluxes generated by sea spray, which is an acceptable assumption at low wind speeds. However at high wind speeds (> 15 m/s) a significant amount of sea spray is generated from the sea surface which, while airborne, cools to an equilibrium temperature, absorbs heat and releases moisture before re-impacting the sea surface. This could impact, for example, the total heat loss from the Southern Ocean (which is anomalously warm in Met Office coupled models) or the accuracy of tropical cyclone forecasts. A modified version of the Fairall sea spray parameterisation scheme has been tested in the Met Office Unified Model including the JULES surface exchange model in both climate and NWP mode. The fast part of the scheme models the temperature change of the droplets to an equilibrium temperature and the slow part of the scheme models the evaporation and heat absorption while the droplets remain airborne. Including this scheme in the model cools and moistens the near surface layers of the atmosphere during high wind events, including tropical cyclones. Sea spray goes on to increase the convection intensity and precipitation near the high wind events in the model.

  2. Proterozoic oxygen rise linked to shifting balance between seafloor and terrestrial weathering

    PubMed Central

    Mills, Benjamin; Lenton, Timothy M.; Watson, Andrew J.

    2014-01-01

    A shift toward higher atmospheric oxygen concentration during the late Proterozoic has been inferred from multiple indirect proxies and is seen by many as a prerequisite for the emergence of complex animal life. However, the mechanisms controlling the level of oxygen throughout the Proterozoic and its eventual rise remain uncertain. Here we use a simple biogeochemical model to show that the balance between long-term carbon removal fluxes via terrestrial silicate weathering and ocean crust alteration plays a key role in determining atmospheric oxygen concentration. This balance may be shifted by changes in terrestrial weatherability or in the generation rate of oceanic crust. As a result, the terrestrial chemical weathering flux may be permanently altered—contrasting with the conventional view that the global silicate weathering flux must adjust to equal the volcanic CO2 degassing flux. Changes in chemical weathering flux in turn alter the long-term supply of phosphorus to the ocean, and therefore the flux of organic carbon burial, which is the long-term source of atmospheric oxygen. Hence we propose that increasing solar luminosity and a decrease in seafloor spreading rate over 1,500–500 Ma drove a gradual shift from seafloor weathering to terrestrial weathering, and a corresponding steady rise in atmospheric oxygen. Furthermore, increased terrestrial weatherability during the late Neoproterozoic may explain low temperature, increases in ocean phosphate, ocean sulfate, and atmospheric oxygen concentration at this time. PMID:24927553

  3. Proterozoic oxygen rise linked to shifting balance between seafloor and terrestrial weathering.

    PubMed

    Mills, Benjamin; Lenton, Timothy M; Watson, Andrew J

    2014-06-24

    A shift toward higher atmospheric oxygen concentration during the late Proterozoic has been inferred from multiple indirect proxies and is seen by many as a prerequisite for the emergence of complex animal life. However, the mechanisms controlling the level of oxygen throughout the Proterozoic and its eventual rise remain uncertain. Here we use a simple biogeochemical model to show that the balance between long-term carbon removal fluxes via terrestrial silicate weathering and ocean crust alteration plays a key role in determining atmospheric oxygen concentration. This balance may be shifted by changes in terrestrial weatherability or in the generation rate of oceanic crust. As a result, the terrestrial chemical weathering flux may be permanently altered--contrasting with the conventional view that the global silicate weathering flux must adjust to equal the volcanic CO2 degassing flux. Changes in chemical weathering flux in turn alter the long-term supply of phosphorus to the ocean, and therefore the flux of organic carbon burial, which is the long-term source of atmospheric oxygen. Hence we propose that increasing solar luminosity and a decrease in seafloor spreading rate over 1,500-500 Ma drove a gradual shift from seafloor weathering to terrestrial weathering, and a corresponding steady rise in atmospheric oxygen. Furthermore, increased terrestrial weatherability during the late Neoproterozoic may explain low temperature, increases in ocean phosphate, ocean sulfate, and atmospheric oxygen concentration at this time.

  4. Frequencies and Characteristics of Global Oceanic Precipitation from Shipboard Present-Weather Reports

    NASA Technical Reports Server (NTRS)

    Petty, Grant W.

    1995-01-01

    Ship reports of present weather obtained from the Comprehensive Ocean-Atmosphere Data Set are analyzed for the period 1958-91 in order to elucidate regional and seasonal variations in the climatological frequency, phase, intensity, and character of oceanic precipitation. Specific findings of note include the following: 1) The frequency of thunderstorm reports, relative to all precipitation reports, is a strong function of location, with thunderstorm activity being favored within 1000-3000 km of major tropical and subtropical land masses, while being quite rare at other locations, even within the intertropical convergence zone. 2) The latitudinal frequency of precipitation over the southern oceans increases steadily toward the Antarctic continent and shows relatively little seasonal variation. The frequency of convective activity, however, shows considerable seasonal variability, with sharp winter maxima occurring near 38 deg. latitude in both hemispheres. 3) Drizzle is the preferred form of precipitation in a number of regions, most of which coincide with known regions of persistent marine stratus and stratocumulus in the subtropical highs. Less well documented is the high relative frequency of drizzle in the vicinity of the equatorial sea surface temperature front in the eastern Pacific. 4) Regional differences in the temporal scale of precipitation events (e.g., transient showers versus steady precipitation) are clearly depicted by way of the ratio of the frequency of precipitation at the observation time to the frequency of all precipitation reports, including precipitation during the previous hour. The results of this study suggest that many current satellite rainfall estimation techniques may substantially underestimate the fractional coverage or frequency of precipitation poleward of 50 deg. latitude and in the subtropical dry zones. They also draw attention to the need to carefully account for regional differences in the physical and spatial properties of

  5. Direct measurement of the combined effects of lichen, rainfall, and temperature onsilicate weathering

    USGS Publications Warehouse

    Brady, P.V.; Dorn, R.I.; Brazel, A.J.; Clark, J.; Moore, R.B.; Glidewell, T.

    1999-01-01

    A key uncertainty in models of the global carbonate-silicate cycle and long-term climate is the way that silicates weather under different climatologic conditions, and in the presence or absence of organic activity. Digital imaging of basalts in Hawaii resolves the coupling between temperature, rainfall, and weathering in the presence and absence of lichens. Activation energies for abiotic dissolution of plagioclase (23.1 ?? 2.5 kcal/mol) and olivine (21.3 ?? 2.7 kcal/mol) are similar to those measured in the laboratory, and are roughly double those measured from samples taken underneath lichen. Abiotic weathering rates appear to be proportional to rainfall. Dissolution of plagioclase and olivine underneath lichen is far more sensitive to rainfall.

  6. Large igneous provinces and organic carbon burial: Controls on global temperature and continental weathering during the Early Cretaceous

    NASA Astrophysics Data System (ADS)

    Bodin, Stéphane; Meissner, Philipp; Janssen, Nico M. M.; Steuber, Thomas; Mutterlose, Jörg

    2015-10-01

    There is an abundance of evidence for short intervals of cold climatic conditions during the Early Cretaceous. However, the lack of a high-resolution, long-term Early Cretaceous paleotemperature record hampers a full-scale synthesis of these putative "cold snap" episodes, as well as a more holistic approach to Early Cretaceous climate changes. We present an extended compilation of belemnite-based oxygen, carbon and strontium isotope records covering the Berriasian-middle Albian from the Vocontian Basin (SE France). This dataset clearly demonstrates three intervals of cold climatic conditions during the Early Cretaceous (late Valanginian-earliest Hauterivian, late early Aptian, latest Aptian-earliest Albian). Each of these intervals is associated with rapid and high amplitude sea-level fluctuations, supporting the hypothesis of transient growth of polar ice caps during the Early Cretaceous. As evidenced by positive carbon isotope excursions, each cold episode is associated with enhanced burial of organic matter on a global scale. Moreover, there is a relatively good match between the timing and size of large igneous province eruptions and the amplitude of Early Cretaceous warming episodes. Altogether, these observations confirm the instrumental role of atmospheric CO2 variations in driving Early Cretaceous climate change. From a long-term perspective, the coupling of global paleotemperature and seawater strontium isotopic ratio during the Early Cretaceous is best explained by temperature-controlled changes of continental crust weathering rates.

  7. Compilation of 3D global conductivity model of the Earth for space weather applications

    NASA Astrophysics Data System (ADS)

    Alekseev, Dmitry; Kuvshinov, Alexey; Palshin, Nikolay

    2015-07-01

    We have compiled a global three-dimensional (3D) conductivity model of the Earth with an ultimate goal to be used for realistic simulation of geomagnetically induced currents (GIC), posing a potential threat to man-made electric systems. Bearing in mind the intrinsic frequency range of the most intense disturbances (magnetospheric substorms) with typical periods ranging from a few minutes to a few hours, the compiled 3D model represents the structure in depth range of 0-100 km, including seawater, sediments, earth crust, and partly the lithosphere/asthenosphere. More explicitly, the model consists of a series of spherical layers, whose vertical and lateral boundaries are established based on available data. To compile a model, global maps of bathymetry, sediment thickness, and upper and lower crust thicknesses as well as lithosphere thickness are utilized. All maps are re-interpolated on a common grid of 0.25×0.25 degree lateral spacing. Once the geometry of different structures is specified, each element of the structure is assigned either a certain conductivity value or conductivity versus depth distribution, according to available laboratory data and conversion laws. A numerical formalism developed for compilation of the model, allows for its further refinement by incorporation of regional 3D conductivity distributions inferred from the real electromagnetic data. So far we included into our model four regional conductivity models, available from recent publications, namely, surface conductance model of Russia, and 3D conductivity models of Fennoscandia, Australia, and northwest of the United States.

  8. Weather Avoidance Guidelines for NASA Global Hawk High-Altitude Unmanned Aircraft Systems (UAS)

    NASA Technical Reports Server (NTRS)

    Cecil, Daniel J.; Zipser, Edward J.; Velden, Chris S.; Monette, Sarah A.; Heymsfield, Gerald M.; Braun, Scott A.; Newman, Paul A.; Black, Peter G.; Black, Michael L.; Dunion, Jason P.

    2014-01-01

    The current Global Hawk flight rules would probably not have been effective in the single event of greatest concern (the Emily encounter). The cloud top had not reached 50,000 ft until minutes before the encounter. The TOT and lightning data would not have been available until near the overflight time since this was a rapidly growing cell. This case would have required a last-minute diversion when lightning became frequent. Avoiding such a cell probably requires continual monitoring of the forward camera and storm scope, whether or not cloud tops have been exceeding specific limits. However, the current overflight rules as strictly interpreted would have prohibited significant fractions of the successful Global Hawk overpasses of Karl and Matthew that proved not to be hazardous. Many other high altitude aircraft (ER-2 and Global Hawk) flights in NASA tropical cyclone field programs have successfully overflown deep convective clouds without incident.The convective cell that caused serious concern about the safety of the ER-2 in Emily was especially strong for a tropical cyclone environment, probably as strong or stronger than any that was overflown by the ER-2 in 20 previous flights over tropical cyclones. Specifically, what made that cell a safety concern was the magnitude of the vertical velocity of the updraft, at least 20 m/s (4000 ft/minute) at the time the ER-2 overflew it. Such a strong updraft can generate strong gravity waves at and above the tropopause, posing a potential danger to aircraft far above the maximum altitude of the updraft itself or its associated cloud top. Indeed, the ER-2 was probably at least 9000 ft above that cloud top. Cloud-top height, by itself, is not an especially good indicator of the intensity of convection and the likelihood of turbulence. Nor is overflying high cloud tops (i.e. > 50,000 ft) of particular concern unless there is other evidence of very strong convective updrafts beneath those tops in the path of the aircraft

  9. Nonlinear dynamics and instability of aqueous dissolution of silicate glasses and minerals.

    PubMed

    Wang, Yifeng; Jove-Colon, Carlos F; Kuhlman, Kristopher L

    2016-07-22

    Aqueous dissolution of silicate glasses and minerals plays a critical role in global biogeochemical cycles and climate evolution. The reactivity of these materials is also important to numerous engineering applications including nuclear waste disposal. The dissolution process has long been considered to be controlled by a leached surface layer in which cations in the silicate framework are gradually leached out and replaced by protons from the solution. This view has recently been challenged by observations of extremely sharp corrosion fronts and oscillatory zonings in altered rims of the materials, suggesting that corrosion of these materials may proceed directly through congruent dissolution followed by secondary mineral precipitation. Here we show that complex silicate material dissolution behaviors can emerge from a simple positive feedback between dissolution-induced cation release and cation-enhanced dissolution kinetics. This self-accelerating mechanism enables a systematic prediction of the occurrence of sharp dissolution fronts (vs. leached surface layers), oscillatory dissolution behaviors and multiple stages of glass dissolution (in particular the alteration resumption at a late stage of a corrosion process). Our work provides a new perspective for predicting long-term silicate weathering rates in actual geochemical systems and developing durable silicate materials for various engineering applications.

  10. Nonlinear dynamics and instability of aqueous dissolution of silicate glasses and minerals

    PubMed Central

    Wang, Yifeng; Jove-Colon, Carlos F.; Kuhlman, Kristopher L.

    2016-01-01

    Aqueous dissolution of silicate glasses and minerals plays a critical role in global biogeochemical cycles and climate evolution. The reactivity of these materials is also important to numerous engineering applications including nuclear waste disposal. The dissolution process has long been considered to be controlled by a leached surface layer in which cations in the silicate framework are gradually leached out and replaced by protons from the solution. This view has recently been challenged by observations of extremely sharp corrosion fronts and oscillatory zonings in altered rims of the materials, suggesting that corrosion of these materials may proceed directly through congruent dissolution followed by secondary mineral precipitation. Here we show that complex silicate material dissolution behaviors can emerge from a simple positive feedback between dissolution-induced cation release and cation-enhanced dissolution kinetics. This self-accelerating mechanism enables a systematic prediction of the occurrence of sharp dissolution fronts (vs. leached surface layers), oscillatory dissolution behaviors and multiple stages of glass dissolution (in particular the alteration resumption at a late stage of a corrosion process). Our work provides a new perspective for predicting long-term silicate weathering rates in actual geochemical systems and developing durable silicate materials for various engineering applications. PMID:27443508

  11. Nonlinear dynamics and instability of aqueous dissolution of silicate glasses and minerals

    DOE PAGES

    Wang, Yifeng; Jove-Colon, Carlos F.; Kuhlman, Kristopher L.

    2016-07-22

    Aqueous dissolution of silicate glasses and minerals plays a critical role in global biogeochemical cycles and climate evolution. The reactivity of these materials is also important to numerous engineering applications including nuclear waste disposal. The dissolution process has long been considered to be controlled by a leached surface layer in which cations in the silicate framework are gradually leached out and replaced by protons from the solution. This view has recently been challenged by observations of extremely sharp corrosion fronts and oscillatory zonings in altered rims of the materials, suggesting that corrosion of these materials may proceed directly through congruentmore » dissolution followed by secondary mineral precipitation. Here we show that complex silicate material dissolution behaviors can emerge from a simple positive feedback between dissolution-induced cation release and cation-enhanced dissolution kinetics. This self-accelerating mechanism enables a systematic prediction of the occurrence of sharp dissolution fronts (vs. leached surface layers), oscillatory dissolution behaviors and multiple stages of glass dissolution (in particular the alteration resumption at a late stage of a corrosion process). In conclusion, our work provides a new perspective for predicting long-term silicate weathering rates in actual geochemical systems and developing durable silicate materials for various engineering applications.« less

  12. Nonlinear dynamics and instability of aqueous dissolution of silicate glasses and minerals

    SciTech Connect

    Wang, Yifeng; Jove-Colon, Carlos F.; Kuhlman, Kristopher L.

    2016-07-22

    Aqueous dissolution of silicate glasses and minerals plays a critical role in global biogeochemical cycles and climate evolution. The reactivity of these materials is also important to numerous engineering applications including nuclear waste disposal. The dissolution process has long been considered to be controlled by a leached surface layer in which cations in the silicate framework are gradually leached out and replaced by protons from the solution. This view has recently been challenged by observations of extremely sharp corrosion fronts and oscillatory zonings in altered rims of the materials, suggesting that corrosion of these materials may proceed directly through congruent dissolution followed by secondary mineral precipitation. Here we show that complex silicate material dissolution behaviors can emerge from a simple positive feedback between dissolution-induced cation release and cation-enhanced dissolution kinetics. This self-accelerating mechanism enables a systematic prediction of the occurrence of sharp dissolution fronts (vs. leached surface layers), oscillatory dissolution behaviors and multiple stages of glass dissolution (in particular the alteration resumption at a late stage of a corrosion process). In conclusion, our work provides a new perspective for predicting long-term silicate weathering rates in actual geochemical systems and developing durable silicate materials for various engineering applications.

  13. Nonlinear dynamics and instability of aqueous dissolution of silicate glasses and minerals

    NASA Astrophysics Data System (ADS)

    Wang, Yifeng; Jove-Colon, Carlos F.; Kuhlman, Kristopher L.

    2016-07-01

    Aqueous dissolution of silicate glasses and minerals plays a critical role in global biogeochemical cycles and climate evolution. The reactivity of these materials is also important to numerous engineering applications including nuclear waste disposal. The dissolution process has long been considered to be controlled by a leached surface layer in which cations in the silicate framework are gradually leached out and replaced by protons from the solution. This view has recently been challenged by observations of extremely sharp corrosion fronts and oscillatory zonings in altered rims of the materials, suggesting that corrosion of these materials may proceed directly through congruent dissolution followed by secondary mineral precipitation. Here we show that complex silicate material dissolution behaviors can emerge from a simple positive feedback between dissolution-induced cation release and cation-enhanced dissolution kinetics. This self-accelerating mechanism enables a systematic prediction of the occurrence of sharp dissolution fronts (vs. leached surface layers), oscillatory dissolution behaviors and multiple stages of glass dissolution (in particular the alteration resumption at a late stage of a corrosion process). Our work provides a new perspective for predicting long-term silicate weathering rates in actual geochemical systems and developing durable silicate materials for various engineering applications.

  14. Atmospheric CO2 Removal by Enhancing Weathering

    NASA Astrophysics Data System (ADS)

    Koster van Groos, A. F.; Schuiling, R. D.

    2014-12-01

    The increase of the CO2 content in the atmosphere by the release of anthropogenic CO2 may be addressed by the enhancement of weathering at the surface of the earth. The average emission of mantle-derived CO2 through volcanism is ~0.3 Gt/year (109 ton/year). Considering the ~3.000 Gt of CO2 present in the atmosphere, the residence time of CO2 in the earth's atmosphere is ~10,000 years. Because the vast proportion of carbon in biomass is recycled through the atmosphere, CO2 is continuously removed by a series of weathering reactions of silicate minerals and stored in calcium and magnesium carbonates. The addition of anthropogenic CO2 from fossil fuel and cement production, which currently exceeds 35 Gt/year and dwarfs the natural production 100-fold, cannot be compensated by current rates of weathering, and atmospheric CO2 levels are rising rapidly. To address this increase in CO2 levels, weathering rates would have to be accelerated on a commensurate scale. Olivine ((Mg,Fe)2SiO4) is the most reactive silicate mineral in the weathering process. This mineral is the major constituent in relatively common ultramafic rocks such as dunites (olivine content > 90%). To consume the current total annual anthropogenic release of CO2, using a simplified weathering reaction (Mg2SiO4 + 4CO2 + 4H2O --> 2 Mg2+ + 4HCO3- + H4SiO4) would require ~30 Gt/year or ~8-9 km3/year of dunite. This is a large volume; it is about double the total amount of ore and gravel currently mined (~ 17 Gt/year). To mine and crush these rocks to <100 μm costs ~ 8/ton. The transport and distribution over the earth's surface involves additional costs, that may reach 2-5/ton. Thus, the cost of remediation for the release of anthropogenic CO2 is 300-400 billion/year. This compares to a 2014 global GDP of ~80 trillion. Because weathering reactions require the presence of water and proceed more rapidly at higher temperatures, the preferred environments to enhance weathering are the wet tropics. From a socio

  15. Major ion chemistry in the headwaters of the Yamuna river system:. Chemical weathering, its temperature dependence and CO 2 consumption in the Himalaya

    NASA Astrophysics Data System (ADS)

    Dalai, T. K.; Krishnaswami, S.; Sarin, M. M.

    2002-10-01

    The Yamuna river and its tributaries in the Himalaya constitute the Yamuna River System (YRS). The YRS basin has a drainage area and discharge comparable in magnitude to those of the Bhagirathi and the Alaknanda rivers, which merge to form the Ganga at the foothills of the Himalaya. A detailed geochemical study of the YRS was carried out to determine: (i) the relative significance of silicate, carbonate and evaporite weathering in contributing to its major ion composition; (ii) CO 2 consumption via silicate weathering; and (iii) the factors regulating chemical weathering of silicates in the basin. The results show that the YRS waters are mildly alkaline, with a wide range of TDS, ˜32 to ˜620 mg l-1. In these waters, the abundances of Ca, Mg and alkalinity, which account for most of TDS, are derived mainly from carbonates. Many of the tributaries in the lower reaches of the Yamuna basin are supersaturated with calcite. In addition to carbonic acid, sulphuric acid generated by oxidation of pyrites also seems to be supplying protons for chemical weathering. Silicate weathering in YRS basin contributes, on average, ˜25% (molar basis) of total cations on a basin wide scale. Silicate weathering, however, does not seem to be intense in the basin as evident from low Si/(Na*+K) in the waters, ˜1.2 and low values of chemical index of alteration (CIA) in bed sediments, ˜60. CO 2 drawdown resulting from silicate weathering in the YRS basin in the Himalaya during monsoon ranges between (4 to 7) × 10 5 moles km -2 y -1. This is higher than that estimated for the Ganga at Rishikesh for the same season. The CO 2 consumption rates in the Yamuna and the Ganga basins in the Himalaya are higher than the global average value, suggesting enhanced CO 2 drawdown in the southern slopes of the Himalaya. The impact of this enhanced drawdown on the global CO 2 budget may not be pronounced, as the drainage area of the YRS and the Ganga in the Himalaya is small. The CO 2 drawdown by

  16. Differential weathering of basaltic and granitic catchments from concentration-discharge relationships

    NASA Astrophysics Data System (ADS)

    Ibarra, Daniel E.; Caves, Jeremy K.; Moon, Seulgi; Thomas, Dana L.; Hartmann, Jens; Chamberlain, C. Page; Maher, Kate

    2016-10-01

    A negative feedback between silicate weathering rates and climate is hypothesized to play a central role in moderating atmospheric CO2 concentrations on geologic timescales. However, uncertainty regarding the processes that regulate the operation of the negative feedback limits our ability to interpret past variations in the ocean-atmosphere carbon cycle. In particular, the mechanisms that determine the flux of weathered material for a given climatic state are still poorly understood. Here, we quantify the processes that determine catchment-scale solute fluxes for two lithologic end-members-basalt and granite-by applying a recently developed solute production model that links weathering fluxes to both discharge and the reactivity of the weathering material. We evaluate the model against long-term monitoring of concentration-discharge relationships from basaltic and granitic catchments to determine the parameters associated with solute production in each catchment. Higher weathering rates in basaltic catchments relative to granitic catchments are driven by differing responses to increases in runoff, with basaltic catchments showing less dilution with increasing runoff. In addition, results from the solute production model suggest that thermodynamic constraints on weathering reactions could explain higher concentrations in basaltic catchments at lower runoff compared to granitic catchments. To understand how the response to changing discharge controls weathering fluxes under different climatic states, we define basalt/granite weatherability as the ratio of the basalt catchment flux to the granite catchment flux. This weatherability is runoff-dependent and increases with increasing runoff. For HCO3- and SiO2(aq) fluxes, for modern global runoff, the derived mean basalt/granite weatherability is 2.2 (1.3-3.7, 2σ) and 1.7 (1.6-2.1, 2σ), respectively. Although we cannot determine the array of individual processes resulting in differences among catchments, the relative

  17. CropWatch agroclimatic indicators (CWAIs) for weather impact assessment on global agriculture.

    PubMed

    Gommes, René; Wu, Bingfang; Zhang, Ning; Feng, Xueliang; Zeng, Hongwei; Li, Zhongyuan; Chen, Bo

    2017-02-01

    CropWatch agroclimatic indicators (CWAIs) are a monitoring tool developed by the CropWatch global crop monitoring system in the Chinese Academy of Sciences (CAS; www.cropwatch.com.cn , Wu et al Int J Digital Earth 7(2):113-137, 2014, Wu et al Remote Sens 7:3907-3933, 2015). Contrary to most other environmental and agroclimatic indicators, they are "agronomic value-added", i.e. they are spatial values averaged over agricultural areas only and they include a weighting that enhances the contribution of the areas with the largest production potential. CWAIs can be computed for any time interval (starting from dekads) and yield one synthetic value per variable over a specific area and time interval, for instance a national annual value. Therefore, they are very compatible with socio-economic and other variables that are usually reported at regular time intervals over administrative units, such as national environmental or agricultural statistics. Two of the CWAIs are satellite-based (RAIN and Photosynthetically Active radiation, PAR) while the third is ground based (TEMP, air temperature); capitals are used when specifically referring to CWAIs rather than the climate variables in general. The paper first provides an overview of some common agroclimatic indicators, describing their procedural, systemic and normative features in subsequent sections, following the terminology of Binder et al Environ Impact Assess Rev 30:71-81 (2010). The discussion focuses on the systemic and normative aspects: the CWAIs are assessed in terms of their coherent description of the agroclimatic crop environment, at different spatial scales (systemic). The final section shows that the CWAIs retain key statistical properties of the underlying climate variables and that they can be compared to a reference value and used as monitoring and early warning variables (normative).

  18. CropWatch agroclimatic indicators (CWAIs) for weather impact assessment on global agriculture

    NASA Astrophysics Data System (ADS)

    Gommes, René; Wu, Bingfang; Zhang, Ning; Feng, Xueliang; Zeng, Hongwei; Li, Zhongyuan; Chen, Bo

    2016-07-01

    CropWatch agroclimatic indicators (CWAIs) are a monitoring tool developed by the CropWatch global crop monitoring system in the Chinese Academy of Sciences (CAS; www.cropwatch.com.cn, Wu et al Int J Digital Earth 7(2):113-137, 2014, Wu et al Remote Sens 7:3907-3933, 2015). Contrary to most other environmental and agroclimatic indicators, they are "agronomic value-added", i.e. they are spatial values averaged over agricultural areas only and they include a weighting that enhances the contribution of the areas with the largest production potential. CWAIs can be computed for any time interval (starting from dekads) and yield one synthetic value per variable over a specific area and time interval, for instance a national annual value. Therefore, they are very compatible with socio-economic and other variables that are usually reported at regular time intervals over administrative units, such as national environmental or agricultural statistics. Two of the CWAIs are satellite-based (RAIN and Photosynthetically Active radiation, PAR) while the third is ground based (TEMP, air temperature); capitals are used when specifically referring to CWAIs rather than the climate variables in general. The paper first provides an overview of some common agroclimatic indicators, describing their procedural, systemic and normative features in subsequent sections, following the terminology of Binder et al Environ Impact Assess Rev 30:71-81 (2010). The discussion focuses on the systemic and normative aspects: the CWAIs are assessed in terms of their coherent description of the agroclimatic crop environment, at different spatial scales (systemic). The final section shows that the CWAIs retain key statistical properties of the underlying climate variables and that they can be compared to a reference value and used as monitoring and early warning variables (normative).

  19. CropWatch agroclimatic indicators (CWAIs) for weather impact assessment on global agriculture

    NASA Astrophysics Data System (ADS)

    Gommes, René; Wu, Bingfang; Zhang, Ning; Feng, Xueliang; Zeng, Hongwei; Li, Zhongyuan; Chen, Bo

    2017-02-01

    CropWatch agroclimatic indicators (CWAIs) are a monitoring tool developed by the CropWatch global crop monitoring system in the Chinese Academy of Sciences (CAS; http://www.cropwatch.com.cn, Wu et al Int J Digital Earth 7(2):113-137, 2014, Wu et al Remote Sens 7:3907-3933, 2015). Contrary to most other environmental and agroclimatic indicators, they are "agronomic value-added", i.e. they are spatial values averaged over agricultural areas only and they include a weighting that enhances the contribution of the areas with the largest production potential. CWAIs can be computed for any time interval (starting from dekads) and yield one synthetic value per variable over a specific area and time interval, for instance a national annual value. Therefore, they are very compatible with socio-economic and other variables that are usually reported at regular time intervals over administrative units, such as national environmental or agricultural statistics. Two of the CWAIs are satellite-based (RAIN and Photosynthetically Active radiation, PAR) while the third is ground based (TEMP, air temperature); capitals are used when specifically referring to CWAIs rather than the climate variables in general. The paper first provides an overview of some common agroclimatic indicators, describing their procedural, systemic and normative features in subsequent sections, following the terminology of Binder et al Environ Impact Assess Rev 30:71-81 (2010). The discussion focuses on the systemic and normative aspects: the CWAIs are assessed in terms of their coherent description of the agroclimatic crop environment, at different spatial scales (systemic). The final section shows that the CWAIs retain key statistical properties of the underlying climate variables and that they can be compared to a reference value and used as monitoring and early warning variables (normative).

  20. Steady- and non-steady-state carbonate-silicate controls on atmospheric CO2

    USGS Publications Warehouse

    Sundquist, E.T.

    1991-01-01

    Two contrasting hypotheses have recently been proposed for the past long-term relation between atmospheric CO2 and the carbonate-silicate geochemical cycle. One approach (Berner, 1990) suggests that CO2 levels have varied in a manner that has maintained chemical weathering and carbonate sedimentation at a steady state with respect to tectonically controlled decarbonation reactions. A second approach (Raymo et al., 1988), applied specificlly to the late Cenozoic, suggests a decrease in CO2 caused by an uplift-induced increase in chemical weathering, without regard to the rate of decarbonation. According to the steady-state (first) hypothesis, increased weathering and carbonate sedimentation are generally associated with increasing atmospheric CO2, whereas the uplift (second) hypothesis implies decreasing CO2 under the same conditions. An ocean-atmosphere-sediment model has been used to assess the response of atmospheric CO2 and carbonate sedimentation to global perturbations in chemical weathering and decarbonation reactions. Although this assessment is theoretical and cannot yet be related to the geologic record, the model simulations compare steady-state and non-steady-state carbonate-silicate cycle response. The e-fold response time of the 'CO2-weathering' feedback mechanism is between 300 and 400 ka. The response of carbonate sedimentation is much more rapid. These response times provide a measure of the strength of steady-state assumptions, and imply that certain systematic relations are sustained throughout steady-state and non-steady-state scenarios for the carbonate-silicate cycle. The simulations suggest that feedbacks can maintain the system near a steady state, but that non-steady-state effects may contribute to long-term trends. The steady-state and uplift hypotheses are not necessarily incompatible over time scales of a few million years. ?? 1991.

  1. Water geochemistry of the Qiantangjiang River, East China: Chemical weathering and CO2 consumption in a basin affected by severe acid deposition

    NASA Astrophysics Data System (ADS)

    Liu, Wenjing; Shi, Chao; Xu, Zhifang; Zhao, Tong; Jiang, Hao; Liang, Chongshan; Zhang, Xuan; Zhou, Li; Yu, Chong

    2016-09-01

    The chemical composition of the Qiantangjiang River, the largest river in Zhejiang province in eastern China, was measured to understand the chemical weathering of rocks and the associated CO2 consumption and anthropogenic influences within a silicate-dominated river basin. The average total dissolved solids (TDS, 113 mg l-1) and total cation concentration (TZ+, 1357 μeq l-1) of the river waters are comparable with those of global major rivers. Ca2+ and HCO3- followed by Na2+ and SO42-, dominate the ionic composition of the river water. There are four major reservoirs (carbonates, silicates, atmospheric and anthropogenic inputs) contributing to the total dissolved load of the investigated rivers. The dissolved loads of the rivers are dominated by both carbonate and silicate weathering, which together account for about 76.3% of the total cationic load origin. The cationic chemical weathering rates of silicate and carbonate for the Qiantangjiang basin are estimated to be approximately 4.9 ton km-2 a-1 and 13.9 ton km-2 a-1, respectively. The calculated CO2 consumption rates with the assumption that all the protons involved in the weathering reaction are provided by carbonic acid are 369 × 103 mol km-2 a-1 and 273 × 103 mol km-2 a-1 by carbonate and silicate weathering, respectively. As one of the most severe impacted area by acid rain in China, H2SO4 from acid precipitation is also an important proton donor in weathering reactions. When H2SO4 is considered, the CO2 consumption rates for the river basin are estimated at 286 × 103 mol km-2 a-1 for carbonate weathering and 211 × 103 mol km-2 a-1 for silicate weathering, respectively. The results highlight that the drawdown effect of CO2 consumption by carbonate and silicate weathering can be largely overestimated if the role of sulfuric acid is ignored, especially in the area heavily impacted by acid deposition like Qiantangjiang basin. The actual CO2 consumption rates (after sulfuric acid weathering effect

  2. The Global Positioning System constellation as a space weather monitor. Comparison of electron measurements with Van Allen Probes data

    DOE PAGES

    Morley, Steven K.; Sullivan, John P.; Henderson, Michael G.; ...

    2016-02-06

    Energetic electron observations in Earth's radiation belts are typically sparse, and multipoint studies often rely on serendipitous conjunctions. This paper establishes the scientific utility of the Combined X-ray Dosimeter (CXD), currently flown on 19 satellites in the Global Positioning System (GPS) constellation, by cross-calibrating energetic electron measurements against data from the Van Allen Probes. By breaking our cross calibration into two parts—one that removes any spectral assumptions from the CXD flux calculation and one that compares the energy spectra—we first validate the modeled instrument response functions, then the calculated electron fluxes. Unlike previous forward modeling of energetic electron spectra, wemore » use a combination of four distributions that together capture a wide range of observed spectral shapes. Moreover, our two-step approach allowed us to identify, and correct for, small systematic offsets between block IIR and IIF satellites. Using the Magnetic Electron Ion Spectrometer and Relativistic Electron-Proton Telescope on Van Allen Probes as a “gold standard,” here we demonstrate that the CXD instruments are well understood. A robust statistical analysis shows that CXD and Van Allen Probes fluxes are similar and the measured fluxes from CXD are typically within a factor of 2 of Van Allen Probes at energies inline image4 MeV. Our team present data from 17 CXD-equipped GPS satellites covering the 2015 “St. Patrick's Day” geomagnetic storm to illustrate the scientific applications of such a high data density satellite constellation and therefore demonstrate that the GPS constellation is positioned to enable new insights in inner magnetospheric physics and space weather forecasting.« less

  3. The Global Positioning System constellation as a space weather monitor. Comparison of electron measurements with Van Allen Probes data

    SciTech Connect

    Morley, Steven K.; Sullivan, John P.; Henderson, Michael G.; Blake, J. Bernard; Baker, Daniel N.

    2016-02-06

    Energetic electron observations in Earth's radiation belts are typically sparse, and multipoint studies often rely on serendipitous conjunctions. This paper establishes the scientific utility of the Combined X-ray Dosimeter (CXD), currently flown on 19 satellites in the Global Positioning System (GPS) constellation, by cross-calibrating energetic electron measurements against data from the Van Allen Probes. By breaking our cross calibration into two parts—one that removes any spectral assumptions from the CXD flux calculation and one that compares the energy spectra—we first validate the modeled instrument response functions, then the calculated electron fluxes. Unlike previous forward modeling of energetic electron spectra, we use a combination of four distributions that together capture a wide range of observed spectral shapes. Moreover, our two-step approach allowed us to identify, and correct for, small systematic offsets between block IIR and IIF satellites. Using the Magnetic Electron Ion Spectrometer and Relativistic Electron-Proton Telescope on Van Allen Probes as a “gold standard,” here we demonstrate that the CXD instruments are well understood. A robust statistical analysis shows that CXD and Van Allen Probes fluxes are similar and the measured fluxes from CXD are typically within a factor of 2 of Van Allen Probes at energies inline image4 MeV. Our team present data from 17 CXD-equipped GPS satellites covering the 2015 “St. Patrick's Day” geomagnetic storm to illustrate the scientific applications of such a high data density satellite constellation and therefore demonstrate that the GPS constellation is positioned to enable new insights in inner magnetospheric physics and space weather forecasting.

  4. RECONSTRUCTING CORONAL MASS EJECTIONS WITH COORDINATED IMAGING AND IN SITU OBSERVATIONS: GLOBAL STRUCTURE, KINEMATICS, AND IMPLICATIONS FOR SPACE WEATHER FORECASTING

    SciTech Connect

    Liu Ying; Luhmann, Janet G.; Lin, Robert P.; Bale, Stuart D.; Thernisien, Arnaud; Vourlidas, Angelos; Davies, Jackie A.

    2010-10-20

    We reconstruct the global structure and kinematics of coronal mass ejections (CMEs) using coordinated imaging and in situ observations from multiple vantage points. A forward modeling technique, which assumes a rope-like morphology for CMEs, is used to determine the global structure (including orientation and propagation direction) from coronagraph observations. We reconstruct the corresponding structure from in situ measurements at 1 AU with the Grad-Shafranov method, which gives the flux-rope orientation, cross section, and a rough knowledge of the propagation direction. CME kinematics (propagation direction and radial distance) during the transit from the Sun to 1 AU are studied with a geometric triangulation technique, which provides an unambiguous association between solar observations and in situ signatures; a track fitting approach is invoked when data are available from only one spacecraft. We show how the results obtained from imaging and in situ data can be compared by applying these methods to the 2007 November 14-16 and 2008 December 12 CMEs. This merged imaging and in situ study shows important consequences and implications for CME research as well as space weather forecasting: (1) CME propagation directions can be determined to a relatively good precision as shown by the consistency between different methods; (2) the geometric triangulation technique shows a promising capability to link solar observations with corresponding in situ signatures at 1 AU and to predict CME arrival at the Earth; (3) the flux rope within CMEs, which has the most hazardous southward magnetic field, cannot be imaged at large distances due to expansion; (4) the flux-rope orientation derived from in situ measurements at 1 AU may have a large deviation from that determined by coronagraph image modeling; and (5) we find, for the first time, that CMEs undergo a westward migration with respect to the Sun-Earth line at their acceleration phase, which we suggest is a universal

  5. Ecosystem Greenhouse Gas Fluxes Respond Directly to Weather Not Climate: A Case Study on the Relationship of Global Atmospheric Circulation, Foehn Frequency, and Winter Weather to Northern Alps Regional Grassland Phenology and Carbon Cycling

    NASA Astrophysics Data System (ADS)

    Desai, A. R.; Wohlfahrt, G.; Zeeman, M. J.; Katata, G.; Mauder, M.; Schmid, H. P. E.

    2014-12-01

    The impact of climate change on regional ecosystem structure and biogeochemical cycling has two important aspects that require better elaboration to improve projections of these effects. The first is that ecosystems don't respond directly to climate, but indirectly via frequency and occurrence of weather systems, which are driven by climatic shifts in global circulation and radiative processes. The second is that many responses of ecosystems to these weather patterns and extremes are lagged in time. Here, we examine these aspects for northern Alpine grasslands. Long-term eddy covariance flux tower and phenology observations in Austria and Germany and biophysical models reveal a strong influence of winter air temperature, snowfall, and snowmelt frequency on winter grass mortality and spring grassland carbon uptake. Further, the mode of climate variability that drives winter air temperature and snow depth patterns is primarily the frequency of strong regional southerly Foehn flow that promotes warm, dry conditions in winter. Finally, we demonstrate that much of the interannual variance in Foehn frequency and southerly flow is driven by statistics and climatic trends of 500 hPa pressure patterns in Greenland, part of the Arctic Oscillation. However, a few years, including the unusually warm and dry winter of 2013-2014 appear to have secondary, possibly local thermotopographic circulation factors that promoted its weather conditions regionally, which also included primarily cool and wet conditions in northern Europe and the southern Alps. These findings demonstrate that the regional response of ecosystems to climate change is modulated by how large-scale circulation patterns influence local meteorology and topographic flows both during and outside the growing season and provides a framework for future assessment and climate model improvements of linkages of climate change, weather patterns, and ecosystem responses.

  6. Increased chemical weathering during the deglacial to mid-Holocene summer monsoon intensification.

    PubMed

    Miriyala, Pavan; Sukumaran, N P; Nath, B Nagender; Ramamurty, P B; Sijinkumar, A V; Vijayagopal, B; Ramaswamy, V; Sebastian, Tyson

    2017-03-17

    Chemical weathering and the ensuing atmospheric carbon dioxide consumption has long been considered to work on geological time periods until recently when some modelling and natural records have shown that the weathering-related CO2 consumption can change at century to glacial-interglacial time scale. Last glacial to interglacial transition period is a best test case to understand the interplay between Pco2-temperature-chemical weathering when a pulse of rapid chemical weathering was initiated. Here we show, from a high resolution 54 ka record from the Andaman Sea in the northern Indian Ocean, that the chemical weathering responds to deglacial to mid-Holocene summer monsoon intensification in the Myanmar watersheds. The multi-proxy data (Al/K, CIA, Rb/Sr, (87)Sr/(86)Sr for degree of weathering and (143)Nd/(144)Nd for provenance) reveal an increase in silicate weathering with initiation of interglacial warm climate at ~17.7 ka followed by a major change at 15.5 ka. Inferred changes in chemical weathering have varied in tandem with the regional monsoonal proxies (δ(18)Osw-salinity changes of Northern Indian Ocean, effective Asian moisture content and δ(18)O records of Chinese caves) and are synchronous with changes in summer insolation at 30°N and δ(18)O of GISP2 implying that chemical weathering was not a later amplifier but worked in tandem with global climate change.

  7. Increased chemical weathering during the deglacial to mid-Holocene summer monsoon intensification

    NASA Astrophysics Data System (ADS)

    Miriyala, Pavan; Sukumaran, N. P.; Nath, B. Nagender; Ramamurty, P. B.; Sijinkumar, A. V.; Vijayagopal, B.; Ramaswamy, V.; Sebastian, Tyson

    2017-03-01

    Chemical weathering and the ensuing atmospheric carbon dioxide consumption has long been considered to work on geological time periods until recently when some modelling and natural records have shown that the weathering-related CO2 consumption can change at century to glacial-interglacial time scale. Last glacial to interglacial transition period is a best test case to understand the interplay between Pco2-temperature-chemical weathering when a pulse of rapid chemical weathering was initiated. Here we show, from a high resolution 54 ka record from the Andaman Sea in the northern Indian Ocean, that the chemical weathering responds to deglacial to mid-Holocene summer monsoon intensification in the Myanmar watersheds. The multi-proxy data (Al/K, CIA, Rb/Sr, 87Sr/86Sr for degree of weathering and 143Nd/144Nd for provenance) reveal an increase in silicate weathering with initiation of interglacial warm climate at ~17.7 ka followed by a major change at 15.5 ka. Inferred changes in chemical weathering have varied in tandem with the regional monsoonal proxies (δ18Osw-salinity changes of Northern Indian Ocean, effective Asian moisture content and δ18O records of Chinese caves) and are synchronous with changes in summer insolation at 30°N and δ18O of GISP2 implying that chemical weathering was not a later amplifier but worked in tandem with global climate change.

  8. Increased chemical weathering during the deglacial to mid-Holocene summer monsoon intensification

    PubMed Central

    Miriyala, Pavan; Sukumaran, N. P.; Nath, B. Nagender; Ramamurty, P. B.; Sijinkumar, A. V.; Vijayagopal, B.; Ramaswamy, V.; Sebastian, Tyson

    2017-01-01

    Chemical weathering and the ensuing atmospheric carbon dioxide consumption has long been considered to work on geological time periods until recently when some modelling and natural records have shown that the weathering-related CO2 consumption can change at century to glacial-interglacial time scale. Last glacial to interglacial transition period is a best test case to understand the interplay between Pco2-temperature-chemical weathering when a pulse of rapid chemical weathering was initiated. Here we show, from a high resolution 54 ka record from the Andaman Sea in the northern Indian Ocean, that the chemical weathering responds to deglacial to mid-Holocene summer monsoon intensification in the Myanmar watersheds. The multi-proxy data (Al/K, CIA, Rb/Sr, 87Sr/86Sr for degree of weathering and 143Nd/144Nd for provenance) reveal an increase in silicate weathering with initiation of interglacial warm climate at ~17.7 ka followed by a major change at 15.5 ka. Inferred changes in chemical weathering have varied in tandem with the regional monsoonal proxies (δ18Osw-salinity changes of Northern Indian Ocean, effective Asian moisture content and δ18O records of Chinese caves) and are synchronous with changes in summer insolation at 30°N and δ18O of GISP2 implying that chemical weathering was not a later amplifier but worked in tandem with global climate change. PMID:28303943

  9. The role of forest trees and their mycorrhizal fungi in carbonate rock weathering and its significance for global carbon cycling.

    PubMed

    Thorley, Rachel M S; Taylor, Lyla L; Banwart, Steve A; Leake, Jonathan R; Beerling, David J

    2015-09-01

    On million-year timescales, carbonate rock weathering exerts no net effect on atmospheric CO2 concentration. However, on timescales of decades-to-centuries, it can contribute to sequestration of anthropogenic CO2 and increase land-ocean alkalinity flux, counteracting ocean acidification. Historical evidence indicates this flux is sensitive to land use change, and recent experimental evidence suggests that trees and their associated soil microbial communities are major drivers of continental mineral weathering. Here, we review key physical and chemical mechanisms by which the symbiotic mycorrhizal fungi of forest tree roots potentially enhance carbonate rock weathering. Evidence from our ongoing field study at the UK's national pinetum confirms increased weathering of carbonate rocks by a wide range of gymnosperm and angiosperm tree species that form arbuscular (AM) or ectomycorrhizal (EM) fungal partnerships. We demonstrate that calcite-containing rock grains under EM tree species weather significantly faster than those under AM trees, an effect linked to greater soil acidification by EM trees. Weathering and corresponding alkalinity export are likely to increase with rising atmospheric CO2 and associated climate change. Our analyses suggest that strategic planting of fast-growing EM angiosperm taxa on calcite- and dolomite-rich terrain might accelerate the transient sink for atmospheric CO2 and slow rates of ocean acidification.

  10. Continental weathering following a Cryogenian glaciation: Evidence from calcium and magnesium isotopes

    NASA Astrophysics Data System (ADS)

    Kasemann, Simone A.; Pogge von Strandmann, Philip A. E.; Prave, Anthony R.; Fallick, Anthony E.; Elliott, Tim; Hoffmann, Karl-Heinz

    2014-06-01

    A marked ocean acidification event and elevated atmospheric carbon dioxide concentrations following the extreme environmental conditions of the younger Cryogenian glaciation have been inferred from boron isotope measurements. Calcium and magnesium isotope analyses offer additional insights into the processes occurring during this time. Data from Neoproterozoic sections in Namibia indicate that following the end of glaciation the continental weathering flux transitioned from being of mixed carbonate and silicate character to a silicate-dominated one. Combined with the effects of primary dolomite formation in the cap dolostones, this caused the ocean to depart from a state of acidification and return to higher pH after climatic amelioration. Differences in the magnitude of stratigraphic isotopic changes across the continental margin of the southern Congo craton shelf point to local influences modifying and amplifying the global signal, which need to be considered in order to avoid overestimation of the worldwide chemical weathering flux.

  11. Continental flood basalt weathering as a trigger for Neoproterozoic Snowball Earth

    NASA Astrophysics Data System (ADS)

    Cox, Grant M.; Halverson, Galen P.; Stevenson, Ross K.; Vokaty, Michelle; Poirier, André; Kunzmann, Marcus; Li, Zheng-Xiang; Denyszyn, Steven W.; Strauss, Justin V.; Macdonald, Francis A.

    2016-07-01

    Atmospheric CO2 levels and global climate are regulated on geological timescales by the silicate weathering feedback. However, this thermostat has failed multiple times in Earth's history, most spectacularly during the Cryogenian (c. 720-635 Ma) Snowball Earth episodes. The unique middle Neoproterozoic paleogeography of a rifting, low-latitude, supercontinent likely favored a globally cool climate due to the influence of the silicate weathering feedback and planetary albedo. Under these primed conditions, the emplacement and weathering of extensive continental flood basalt provinces may have provided the final trigger for runaway global glaciation. Weathering of continental flood basalts may have also contributed to the characteristically high carbon isotope ratios (δ13 C) of Neoproterozoic seawater due to their elevated P contents. In order to test these hypotheses, we have compiled new and previously published Neoproterozoic Nd isotope data from mudstones in northern Rodinia (North America, Australia, Svalbard, and South China) and Sr isotope data from carbonate rocks. The Nd isotope data are used to model the mafic detrital input into sedimentary basins in northern Rodinia. The results reveal a dominant contribution from continental flood basalt weathering during the ca. 130 m.y. preceding the onset of Cryogenian glaciation, followed by a precipitous decline afterwards. These data are mirrored by the Sr isotope record, which reflects the importance of chemical weathering of continental flood basalts on solute fluxes to the early-middle Neoproterozoic ocean, including a pulse of unradiogenic Sr input into the oceans just prior to the onset of Cyrogenian glaciation. Hence, our new data support the hypotheses that elevated rates of flood basalt weathering contributed to both the high average δ13 C of seawater in the Neoproterozoic and to the initiation of the first (Sturtian) Snowball Earth.

  12. Mineral stimulation of subsurface microorganisms: release of limiting nutrients from silicates

    USGS Publications Warehouse

    Roger, Jennifer Roberts; Bennett, Philip C.

    2004-01-01

    Microorganisms play an important role in the weathering of silicate minerals in many subsurface environments, but an unanswered question is whether the mineral plays an important role in the microbial ecology. Silicate minerals often contain nutrients necessary for microbial growth, but whether the microbial community benefits from their release during weathering is unclear. In this study, we used field and laboratory approaches to investigate microbial interactions with minerals and glasses containing beneficial nutrients and metals. Field experiments from a petroleum-contaminated aquifer, where silicate weathering is substantially accelerated in the contaminated zone, revealed that phosphorus (P) and iron (Fe)-bearing silicate glasses were preferentially colonized and weathered, while glasses without these elements were typically barren of colonizing microorganisms, corroborating previous studies using feldspars. In laboratory studies, we investigated microbial weathering of silicates and the release of nutrients using a model ligand-promoted pathway. A metal-chelating organic ligand 3,4 dihydroxybenzoic acid (3,4 DHBA) was used as a source of chelated ferric iron, and a carbon source, to investigate mineral weathering rate and microbial metabolism.In the investigated aquifer, we hypothesize that microbes produce organic ligands to chelate metals, particularly Fe, for metabolic processes and also form stable complexes with Al and occasionally with Si. Further, the concentration of these ligands is apparently sufficient near an attached microorganism to destroy the silicate framework while releasing the nutrient of interest. In microcosms containing silicates and glasses with trace phosphate mineral inclusions, microbial biomass increased, indicating that the microbial community can use silicate-bound phosphate inclusions. The addition of a native microbial consortium to microcosms containing silicates or glasses with iron oxide inclusions correlated to

  13. Enhanced weathering strategies for stabilizing climate and averting ocean acidification

    NASA Astrophysics Data System (ADS)

    Taylor, Lyla L.; Quirk, Joe; Thorley, Rachel M. S.; Kharecha, Pushker A.; Hansen, James; Ridgwell, Andy; Lomas, Mark R.; Banwart, Steve A.; Beerling, David J.

    2016-04-01

    Chemical breakdown of rocks, weathering, is an important but very slow part of the carbon cycle that ultimately leads to CO2 being locked up in carbonates on the ocean floor. Artificial acceleration of this carbon sink via distribution of pulverized silicate rocks across terrestrial landscapes may help offset anthropogenic CO2 emissions. We show that idealized enhanced weathering scenarios over less than a third of tropical land could cause significant drawdown of atmospheric CO2 and ameliorate ocean acidification by 2100. Global carbon cycle modelling driven by ensemble Representative Concentration Pathway (RCP) projections of twenty-first-century climate change (RCP8.5, business-as-usual; RCP4.5, medium-level mitigation) indicates that enhanced weathering could lower atmospheric CO2 by 30-300 ppm by 2100, depending mainly on silicate rock application rate (1 kg or 5 kg m-2 yr-1) and composition. At the higher application rate, end-of-century ocean acidification is reversed under RCP4.5 and reduced by about two-thirds under RCP8.5. Additionally, surface ocean aragonite saturation state, a key control on coral calcification rates, is maintained above 3.5 throughout the low latitudes, thereby helping maintain the viability of tropical coral reef ecosystems. However, we highlight major issues of cost, social acceptability, and potential unanticipated consequences that will limit utilization and emphasize the need for urgent efforts to phase down fossil fuel emissions.

  14. Enhanced Weathering Strategies for Stabilizing Climate and Averting Ocean Acidification

    NASA Technical Reports Server (NTRS)

    Taylor, Lyla L.; Quirk, Joe; Thorley, Rachel M. S.; Kharecha, Pushker A.; Hansen, James; Ridgwell, Andy; Lomas, Mark R.; Banwart, Steve A.; Beerling, David J.

    2015-01-01

    Chemical breakdown of rocks, weathering, is an important but very slow part of the carbon cycle that ultimately leads to CO2 being locked up in carbonates on the ocean floor. Artificial acceleration of this carbon sink via distribution of pulverized silicate rocks across terrestrial landscapes may help offset anthropogenic CO2 emissions. We show that idealized enhanced weathering scenarios over less than a third of tropical land could cause significant drawdown of atmospheric CO2 and ameliorate ocean acidification by 2100. Global carbon cycle modelling driven by ensemble Representative Concentration Pathway (RCP) projections of twenty-first-century climate change (RCP8.5, business-as-usual; RCP4.5, medium-level mitigation) indicates that enhanced weathering could lower atmospheric CO2 by 30-300 ppm by 2100, depending mainly on silicate rock application rate (1 kg or 5 kg m(exp -2) yr (exp -1)) and composition. At the higher application rate, end-of-century ocean acidification is reversed under RCP4.5 and reduced by about two-thirds under RCP8.5. Additionally, surface ocean aragonite saturation state, a key control on coral calcification rates, is maintained above 3.5 throughout the low latitudes, thereby helping maintain the viability of tropical coral reef ecosystems. However, we highlight major issues of cost, social acceptability, and potential unanticipated consequences that will limit utilization and emphasize the need for urgent efforts to phase down fossil fuel emissions.

  15. The carbonate-silicate cycle and CO2/climate feedbacks on tidally locked terrestrial planets.

    PubMed

    Edson, Adam R; Kasting, James F; Pollard, David; Lee, Sukyoung; Bannon, Peter R

    2012-06-01

    Atmospheric gaseous constituents play an important role in determining the surface temperatures and habitability of a planet. Using a global climate model and a parameterization of the carbonate-silicate cycle, we explored the effect of the location of the substellar point on the atmospheric CO(2) concentration and temperatures of a tidally locked terrestrial planet, using the present Earth continental distribution as an example. We found that the substellar point's location relative to the continents is an important factor in determining weathering and the equilibrium atmospheric CO(2) level. Placing the substellar point over the Atlantic Ocean results in an atmospheric CO(2) concentration of 7 ppmv and a global mean surface air temperature of 247 K, making ∼30% of the planet's surface habitable, whereas placing it over the Pacific Ocean results in a CO(2) concentration of 60,311 ppmv and a global temperature of 282 K, making ∼55% of the surface habitable.

  16. Enhanced oxidative weathering in glaciated mountain catchments: A stabilising feedback on atmospheric carbon dioxide?

    NASA Astrophysics Data System (ADS)

    Horan, K.; Hilton, R. G.; Burton, K. W.; Selby, D. S.; Ottley, C. J.

    2015-12-01

    Mountain belts act as sources of carbon dioxide (CO2) to the atmosphere if physical erosion and exhumation expose rock-derived organic carbon ('petrogenic' organic carbon, OCpetro) to chemical weathering. Estimates suggest 15x1021g of carbon is stored in rocks globally as OCpetro, ~25,000 times the amount of carbon in the pre-industrial atmosphere. Alongside volcanic and metamorphic degassing, OCpetro weathering is thought to be the main source of CO2 to the atmosphere over geological timescales. Erosion in mountain river catchments has been shown to enhance oxidative weathering and CO2 release. However, we still lack studies which quantify this process. In addition, it is not clear how glaciation may impact OCpetro oxidation. In analogy with silicate weathering, large amounts of fine sediment in glacial catchments may enhance oxidative weathering. Here we quantify oxidative weathering in nine catchments draining OCpetro bearing rocks in the western Southern Alps, New Zealand. Using rhenium (Re) as a tracer of oxidative weathering, we develop techniques to precisely measure Re concentration at sub-ppt levels in river waters. Using [Re]water/[Re]rock as a weathering tracer, we estimate that the weathering efficiency in glacial catchments is >4 times that of non-glacial catchments. Combining this with the OCpetro content of rocks and dissolved Re flux, we estimate the CO2 release by OCpetro oxidation. The analysis suggests that non-glacial catchments in the western Southern Alps release similar amounts of CO2 as catchments in Taiwan where erosion rates are comparable. In this mountain belt, the CO2 release does not negate CO2 drawdown by silicate weathering and by riverine transfer of organic matter. Based on our results, we propose that mountain glaciation may greatly enhance OCpetro oxidation rates. Depending on the global fluxes involved, this provides a feedback to damp low atmospheric CO2 levels and global cooling. During glacial periods (low CO2, low global

  17. Weather Watch

    ERIC Educational Resources Information Center

    Bratt, Herschell Marvin

    1973-01-01

    Suggests a number of ways in which Federal Aviation Agency weather report printouts can be used in teaching the weather section of meteorology. These weather sequence reports can be obtained free of charge at most major airports. (JR)

  18. Insolation data manual: long-term monthly averages of solar radiation, temperature, degree-days and global anti K/sub T/ for 248 national weather service stations

    SciTech Connect

    Knapp, C L; Stoffel, T L; Whitaker, S D

    1980-10-01

    Monthly averaged data is presented which describes the availability of solar radiation at 248 National Weather Service stations. Monthly and annual average daily insolation and temperature values have been computed from a base of 24 to 25 years of data. Average daily maximum, minimum, and monthly temperatures are provided for most locations in both Celsius and Fahrenheit. Heating and cooling degree-days were computed relative to a base of 18.3/sup 0/C (65/sup 0/F). For each station, global anti K/sub T/ (cloudiness index) were calculated on a monthly and annual basis. (MHR)

  19. Weather assessment and forecasting

    NASA Technical Reports Server (NTRS)

    1977-01-01

    Data management program activities centered around the analyses of selected far-term Office of Applications (OA) objectives, with the intent of determining if significant data-related problems would be encountered and if so what alternative solutions would be possible. Three far-term (1985 and beyond) OA objectives selected for analyses as having potential significant data problems were large-scale weather forecasting, local weather and severe storms forecasting, and global marine weather forecasting. An overview of general weather forecasting activities and their implications upon the ground based data system is provided. Selected topics were specifically oriented to the use of satellites.

  20. Reconnaissance of Field Sites for the Study of Chemical Weathering on the Guayana Shield, South America

    SciTech Connect

    Steefell, C I

    2003-02-01

    Despite the fact that chemical weathering of silicate rocks plays an important role in the draw-down of CO{sub 2} over geologic time scales (Berner and Berner, 1996), the overall controls on the rate of chemical weathering are still not completely understood. Lacking a mechanistic understanding of these controls, it remains difficult to evaluate a hypothesis such as that presented by Raymo and Ruddiman (1992), who suggested that enhanced weathering and CO{sub 2} draw-down resulting from the uplift of the Himalayas contributed to global cooling during the Cenozoic. At an even more fundamental level, the three to four order of magnitude discrepancy between laboratory and field weathering rates is still unresolved (White et al., 1996). There is as yet no comprehensive, mechanistic model for silicate chemical weathering that considers the coupled effects of precipitation, vadose zone flow, and chemical reactions. The absence of robust process models for silicate weathering and the failure to resolve some of these important questions may in fact be related-the controls on the overall rates of weathering cannot be understood without considering the weathering environment as one in which multiple, time-dependent chemical and physical processes are coupled (Malmstrom, 2000). Once chemical weathering is understood at a mechanistic process level, the important controls on chemical weathering (physical erosion, temperature, precipitation) can be folded into larger scale models tracking the global carbon cycle. Our goal in this study was to carry out the preliminary work needed to establish a field research site for chemical weathering om the Cuayana Shield in South America. The Guayana Shield is a Precambrian province greater than 1.5 billion years old covering portions of Venezuela, Guyana (the country), Surinam, French Guiana, and Brazil (Figure 1). More important than the age of the rocks themselves, however, is the age of the erosion surface developed on the Shield, with

  1. COST Action ES1206 : Advanced Global Navigation Satellite Systems Tropospheric Products for Monitoring Severe Weather Events and Climate (GNSS4SWEC)

    NASA Astrophysics Data System (ADS)

    Jones, Jonathan; Guerova, Guergana; Dousa, Jan; de Haan, Siebren; Bock, Olivier; Dick, Galina; Pottiaux, Eric; Pacione, Rosa

    2014-05-01

    Global Navigation Satellite Systems (GNSS) have revolutionised positioning, navigation, and timing, becoming a common part of our everyday life. Aside from these well-known civilian and commercial applications, GNSS is now an established atmospheric observing system which can accurately sense water vapour, the most abundant greenhouse gas, accounting for 60-70% of atmospheric warming. Severe weather forecasting is challenging, in part due to the high temporal and spatial variation of atmospheric water vapour. Water vapour is under-sampled in the current meteorological and climate observing systems, obtaining and exploiting more high-quality humidity observations is essential to weather forecasting and climate monitoring. The new COST Action, ES1206, will address new and improved capabilities from con-current developments in both the GNSS and meteorological communities. For the first time, the synergy of the three GNSS systems (GPS, GLONASS and Galileo) will be used to develop new, advanced tropospheric products, exploiting the full potential of multi-GNSS water vapour estimates on a wide range of temporal and spatial scales, from real-time monitoring and forecasting of severe weather, to climate research. In addition the Action will promote the use of meteorological data in GNSS positioning, navigation, and timing services. The Action will stimulate knowledge transfer and data sharing throughout Europe.

  2. Space weathering on airless bodies

    NASA Astrophysics Data System (ADS)

    Pieters, Carle M.; Noble, Sarah K.

    2016-10-01

    Space weathering refers to alteration that occurs in the space environment with time. Lunar samples, and to some extent meteorites, have provided a benchmark for understanding the processes and products of space weathering. Lunar soils are derived principally from local materials but have accumulated a range of optically active opaque particles (OAOpq) that include nanophase metallic iron on/in rims formed on individual grains (imparting a red slope to visible and near-infrared reflectance) and larger iron particles (which darken across all wavelengths) such as are often found within the interior of recycled grains. Space weathering of other anhydrous silicate bodies, such as Mercury and some asteroids, produces different forms and relative abundance of OAOpq particles depending on the particular environment. If the development of OAOpq particles is minimized (such as at Vesta), contamination by exogenic material and regolith mixing become the dominant space weathering processes. Volatile-rich bodies and those composed of abundant hydrous minerals (dwarf planet Ceres, many dark asteroids, and outer solar system satellites) are affected by space weathering processes differently than the silicate bodies of the inner solar system. However, the space weathering products of these bodies are currently poorly understood and the physics and chemistry of space weathering processes in different environments are areas of active research.

  3. Weathering Processes Across Extreme Erosional Gradients: Do Landslides Matter?

    NASA Astrophysics Data System (ADS)

    Emberson, R.; Hovius, N.; Galy, A.; Marc, O.

    2015-12-01

    A process-based understanding of weathering in actively eroding mountain belts is vital to understand how linkages between erosion and weathering affect global biogeochemical cycles on a range of timescales. Here we present surface water chemistry data from Southern Taiwan that demonstrates the impact of variable erosive processes on weathering budgets on a large range of scales, from tens of metres to large catchments (>50km2). Southern Taiwan is an excellent example of a number of gradients in erosive processes, with relief and median slope increasing from the southernmost small hills to mountainous threshold-hillslopes with up to 2.5km of relief approximately 100km to the north. Furthermore, Typhoon Morakot (2009) triggered extremely extensive landsliding in some catchments within this zone, allowing distinctions to be drawn between average topographic characteristics of catchments and the erosive processes (i.e. mass wasting) at work therein. Landslides play an important role in localising weathering in deposits with high internal surface area and slow throughflow of fluids, creating sites of rapid weathering which can be a first order control on catchment solute budgets in watersheds where landslides deposits and scars exceed 2% of drained area. Variation in the detailed chemistry of landslide seepages - particularly the carbonate/silicate weathering balance - indicates that this process has a different impact on inorganic weathering-driven carbon cycling than slower erosive processes; a strong positive correlation between landslide-affected area and Ca2+:Si ratios on catchment scale suggests rapid erosion is not strongly coupled to CO2 drawdown. Rapid oxidation of sulphides - ubiquitous in many rapidly eroding mountain belts - within highly fragmented landslide deposits, and associated sulphuric-acid driven weathering, further complicates the effect landsliding has on the carbon cycle.

  4. Application of global weather and climate model output to the design and operation of wind-energy systems

    SciTech Connect

    Curry, Judith

    2015-05-21

    This project addressed the challenge of providing weather and climate information to support the operation, management and planning for wind-energy systems. The need for forecast information is extending to longer projection windows with increasing penetration of wind power into the grid and also with diminishing reserve margins to meet peak loads during significant weather events. Maintenance planning and natural gas trading is being influenced increasingly by anticipation of wind generation on timescales of weeks to months. Future scenarios on decadal time scales are needed to support assessment of wind farm siting, government planning, long-term wind purchase agreements and the regulatory environment. The challenge of making wind forecasts on these longer time scales is associated with a wide range of uncertainties in general circulation and regional climate models that make them unsuitable for direct use in the design and planning of wind-energy systems. To address this challenge, CFAN has developed a hybrid statistical/dynamical forecasting scheme for delivering probabilistic forecasts on time scales from one day to seven months using what is arguably the best forecasting system in the world (European Centre for Medium Range Weather Forecasting, ECMWF). The project also provided a framework to assess future wind power through developing scenarios of interannual to decadal climate variability and change. The Phase II research has successfully developed an operational wind power forecasting system for the U.S., which is being extended to Europe and possibly Asia.

  5. Understanding space weather to shield society: A global road map for 2015-2025 commissioned by COSPAR and ILWS

    NASA Astrophysics Data System (ADS)

    Schrijver, Carolus J.; Kauristie, Kirsti; Aylward, Alan D.; Denardini, Clezio M.; Gibson, Sarah E.; Glover, Alexi; Gopalswamy, Nat; Grande, Manuel; Hapgood, Mike; Heynderickx, Daniel; Jakowski, Norbert; Kalegaev, Vladimir V.; Lapenta, Giovanni; Linker, Jon A.; Liu, Siqing; Mandrini, Cristina H.; Mann, Ian R.; Nagatsuma, Tsutomu; Nandy, Dibyendu; Obara, Takahiro; Paul O'Brien, T.; Onsager, Terrance; Opgenoorth, Hermann J.; Terkildsen, Michael; Valladares, Cesar E.; Vilmer, Nicole

    2015-06-01

    There is a growing appreciation that the environmental conditions that we call space weather impact the technological infrastructure that powers the coupled economies around the world. With that comes the need to better shield society against space weather by improving forecasts, environmental specifications, and infrastructure design. We recognize that much progress has been made and continues to be made with a powerful suite of research observatories on the ground and in space, forming the basis of a Sun-Earth system observatory. But the domain of space weather is vast - extending from deep within the Sun to far outside the planetary orbits - and the physics complex - including couplings between various types of physical processes that link scales and domains from the microscopic to large parts of the solar system. Consequently, advanced understanding of space weather requires a coordinated international approach to effectively provide awareness of the processes within the Sun-Earth system through observation-driven models. This roadmap prioritizes the scientific focus areas and research infrastructure that are needed to significantly advance our understanding of space weather of all intensities and of its implications for society. Advancement of the existing system observatory through the addition of small to moderate state-of-the-art capabilities designed to fill observational gaps will enable significant advances. Such a strategy requires urgent action: key instrumentation needs to be sustained, and action needs to be taken before core capabilities are lost in the aging ensemble. We recommend advances through priority focus (1) on observation-based modeling throughout the Sun-Earth system, (2) on forecasts more than 12 h ahead of the magnetic structure of incoming coronal mass ejections, (3) on understanding the geospace response to variable solar-wind stresses that lead to intense geomagnetically-induced currents and ionospheric and radiation storms, and (4

  6. Updated global soil map for the Weather Research and Forecasting model and soil moisture initialization for the Noah land surface model

    NASA Astrophysics Data System (ADS)

    DY, C. Y.; Fung, J. C. H.

    2016-08-01

    A meteorological model requires accurate initial conditions and boundary conditions to obtain realistic numerical weather predictions. The land surface controls the surface heat and moisture exchanges, which can be determined by the physical properties of the soil and soil state variables, subsequently exerting an effect on the boundary layer meteorology. The initial and boundary conditions of soil moisture are currently obtained via National Centers for Environmental Prediction FNL (Final) Operational Global Analysis data, which are collected operationally in 1° by 1° resolutions every 6 h. Another input to the model is the soil map generated by the Food and Agriculture Organization of the United Nations - United Nations Educational, Scientific and Cultural Organization (FAO-UNESCO) soil database, which combines several soil surveys from around the world. Both soil moisture from the FNL analysis data and the default soil map lack accuracy and feature coarse resolutions, particularly for certain areas of China. In this study, we update the global soil map with data from Beijing Normal University in 1 km by 1 km grids and propose an alternative method of soil moisture initialization. Simulations of the Weather Research and Forecasting model show that spinning-up the soil moisture improves near-surface temperature and relative humidity prediction using different types of soil moisture initialization. Explanations of that improvement and improvement of the planetary boundary layer height in performing process analysis are provided.

  7. Soil Organic Carbon Loss: An Overlooked Factor in the Carbon Sequestration Potential of Enhanced Mineral Weathering

    NASA Astrophysics Data System (ADS)

    Dietzen, Christiana; Harrison, Robert

    2016-04-01

    Weathering of silicate minerals regulates the global carbon cycle on geologic timescales. Several authors have proposed that applying finely ground silicate minerals to soils, where organic acids would enhance the rate of weathering, could increase carbon uptake and mitigate anthropogenic CO2 emissions. Silicate minerals such as olivine could replace lime, which is commonly used to remediate soil acidification, thereby sequestering CO2 while achieving the same increase in soil pH. However, the effect of adding this material on soil organic matter, the largest terrestrial pool of carbon, has yet to be considered. Microbial biomass and respiration have been observed to increase with decreasing acidity, but it is unclear how long the effect lasts. If the addition of silicate minerals promotes the loss of soil organic carbon through decomposition, it could significantly reduce the efficiency of this process or even create a net carbon source. However, it is possible that this initial flush of microbial activity may be compensated for by additional organic matter inputs to soil pools due to increases in plant productivity under less acidic conditions. This study aimed to examine the effects of olivine amendments on soil CO2 flux. A liming treatment representative of typical agricultural practices was also included for comparison. Samples from two highly acidic soils were split into groups amended with olivine or lime and a control group. These samples were incubated at 22°C and constant soil moisture in jars with airtight septa lids. Gas samples were extracted periodically over the course of 2 months and change in headspace CO2 concentration was determined. The effects of enhanced mineral weathering on soil organic matter have yet to be addressed by those promoting this method of carbon sequestration. This project provides the first data on the potential effects of enhanced mineral weathering in the soil environment on soil organic carbon pools.

  8. Severe Weather

    ERIC Educational Resources Information Center

    Forde, Evan B.

    2004-01-01

    Educating the public about safety issues related to severe weather is part of the National Oceanic and Atmospheric Administration's (NOAA) mission. This month's insert, Severe Weather, has been created by NOAA to help educate the public about hazardous weather conditions. The four types of severe weather highlighted in this poster are hurricanes,…

  9. Severe Weather

    ERIC Educational Resources Information Center

    Forde, Evan B.

    2004-01-01

    Educating the public about safety issues related to severe weather is part of the National Oceanic and Atmospheric Administration's (NOAA) mission. This article deals with a poster entitled, "Severe Weather," that has been created by NOAA to help educate the public about hazardous weather conditions. The four types of severe weather highlighted in…

  10. Approach to Integrate Global-Sun Models of Magnetic Flux Emergence and Transport for Space Weather Studies

    NASA Technical Reports Server (NTRS)

    Mansour, Nagi N.; Wray, Alan A.; Mehrotra, Piyush; Henney, Carl; Arge, Nick; Godinez, H.; Manchester, Ward; Koller, J.; Kosovichev, A.; Scherrer, P.; Zhao, J.; Stein, R.; Duvall, T.; Fan, Y.

    2013-01-01

    The Sun lies at the center of space weather and is the source of its variability. The primary input to coronal and solar wind models is the activity of the magnetic field in the solar photosphere. Recent advancements in solar observations and numerical simulations provide a basis for developing physics-based models for the dynamics of the magnetic field from the deep convection zone of the Sun to the corona with the goal of providing robust near real-time boundary conditions at the base of space weather forecast models. The goal is to develop new strategic capabilities that enable characterization and prediction of the magnetic field structure and flow dynamics of the Sun by assimilating data from helioseismology and magnetic field observations into physics-based realistic magnetohydrodynamics (MHD) simulations. The integration of first-principle modeling of solar magnetism and flow dynamics with real-time observational data via advanced data assimilation methods is a new, transformative step in space weather research and prediction. This approach will substantially enhance an existing model of magnetic flux distribution and transport developed by the Air Force Research Lab. The development plan is to use the Space Weather Modeling Framework (SWMF) to develop Coupled Models for Emerging flux Simulations (CMES) that couples three existing models: (1) an MHD formulation with the anelastic approximation to simulate the deep convection zone (FSAM code), (2) an MHD formulation with full compressible Navier-Stokes equations and a detailed description of radiative transfer and thermodynamics to simulate near-surface convection and the photosphere (Stagger code), and (3) an MHD formulation with full, compressible Navier-Stokes equations and an approximate description of radiative transfer and heating to simulate the corona (Module in BATS-R-US). CMES will enable simulations of the emergence of magnetic structures from the deep convection zone to the corona. Finally, a plan

  11. Enhanced weathering strategies for cooling the planet and saving coral reefs

    NASA Astrophysics Data System (ADS)

    Beerling, D. J.; Taylor, L.; Quirk, J.; Thorley, R.; Kharecha, P. A.; Hansen, J. E.; Ridgwell, A. J.; Lomas, M.; Banwart, S. A.

    2014-12-01

    Acceleration of the chemical weathering sink for atmospheric CO2 via distribution of pulverized silicate rocks across terrestrial landscapes has been proposed as a macro-engineering Carbon Dioxide Removal (CDR) scheme, but its effectiveness and response to ongoing global change is poorly understood. We employ a detailed spatially resolved weathering model driven by two ensemble Representative Concentration Pathway (RCP) projections of 21st Century climate (RCP8.5 and RCP4.5) to assess enhanced weathering and examine feedbacks on atmospheric CO2 and ocean carbonate biogeochemistry. Atmospheric CO2 reduction of ~100-260 ppm by year 2100, the range depending mainly on rock composition, is obtained by spreading 5 kg m-2 yr-1 over 20 Mkm2 tropical weathering 'hotspots'. Ocean acidification is neutralized in RCP4.5 and ameliorated in RCP8.5 due to enhanced land-ocean export of weathered alkalinity products and reduced CO2 forcings, and the aragonite saturation state of surface oceans is raised to >3.5, thus avoiding likely extinction of coral reef ecosystems. We suggest that accelerated weathering has substantial potential to help limit global warming and benefits to marine life not obtained from other CDR approaches, but major issues of cost, social acceptability, and potential unanticipated consequences should encourage urgent efforts to phase down fossil fuel emissions.

  12. Weather & Weather Maps. Teacher's Manual.

    ERIC Educational Resources Information Center

    Metro, Peter M.; Green, Rachel E.

    This guide is intended to provide an opportunity for students to work with weather symbols used for reporting weather. Also included are exercises in location of United States cities by latitude and longitude, measurement of distances in miles and kilometers, and prediction of weather associated with various types of weather fronts. (RE)

  13. The impact of tropical wind data on the analysis and forcasts of the GLA GCM for the global weather experiment

    NASA Technical Reports Server (NTRS)

    Paegle, Jan; Baker, W. E.

    1985-01-01

    It is well-known that divergent wind estimates are much more dependent upon the analysis system than are estimates of the rotational wind. This conclusion is supported in recent analyses of FGGE SOP1 data produced by the Goddard Laboratory for Atmospheres (GLA), the Geophysical Fluid Dynamics Laboratory (GFDL) and the European Center for Medium Range Weather Forecasting (ECMWF). These analyses differ in the forecast models that are used for the four-dimensional assimilation, in the data rejection criteria, and, to a certain extent, in the data density. Because the final divergent wind is a product of both model constraints and observation, it is relevant to inquire how much of each goes into the final product. We presently investigate this question through a systematic analysis of tropical data that are sampled at different densities by the GLA GCM.

  14. Rolling stones; fast weathering of olivine in shallow seas for cost-effective CO2 capture and mitigation of global warming and ocean acidification

    NASA Astrophysics Data System (ADS)

    Schuiling, R. D.; de Boer, P. L.

    2011-12-01

    Human CO2 emissions may drive the Earth into a next greenhouse state. They can be mitigated by accelerating weathering of natural rock under the uptake of CO2. We disprove the paradigm that olivine weathering in nature would be a slow process, and show that it is not needed to mill olivine to very fine, 10 μm-size grains in order to arrive at a complete dissolution within 1-2 year. In high-energy shallow marine environments olivine grains and reaction products on the grain surfaces, that otherwise would greatly retard the reaction, are abraded so that the chemical reaction is much accelerated. When kept in motion even large olivine grains rubbing and bumping against each other quickly produce fine clay- and silt-sized olivine particles that show a fast chemical reaction. Spreading of olivine in the world's 2% most energetic shelf seas can compensate a year's global CO2 emissions and counteract ocean acidification against a price well below that of carbon credits.

  15. Chemical weathering and the role of sulfuric and nitric acids in carbonate weathering: Isotopes (13C, 15N, 34S, and 18O) and chemical constraints

    NASA Astrophysics Data System (ADS)

    Li, Cai; Ji, Hongbing

    2016-05-01

    Multiple isotopes (13C-DIC, 34S and 18O-SO42-, 15N and 18O-NO3-) and water chemistry were used to evaluate weathering rates and associated CO2 consumption by carbonic acid and strong acids (H2SO4 and HNO3) in a typical karst watershed (Wujiang River, Southwest China). The dual sulfate isotopes indicate that sulfate is mainly derived from sulfide oxidation in coal stratum and sulfide-containing minerals, and dual nitrate isotopes indicate that nitrate is mainly derived from soil N and nitrification. The correlation between isotopic compositions and water chemistry suggests that sulfuric and nitric acids, in addition to carbonic acid, are involved in carbonate weathering. The silicate and carbonate weathering rates are 7.2 t km-2 yr-1 and 76 t km-2 yr-1, respectively. In comparison with carbonate weathering rates (43 t km-2 yr-1) by carbonic acid alone, the subsequent increase in rates indicates significant enhancement of weathering when combined with sulfuric and nitric acids. Therefore, the role of sulfuric and nitric acids in the rock weathering should be considered in the global carbon cycle.

  16. Sensitivity of the boreal forest-mire ecotone CO2, CH4, and N2O global warming potential to rainy and dry weather

    NASA Astrophysics Data System (ADS)

    Ťupek, Boris; Minkkinen, Kari; Vesala, Timo; Nikinmaa, Eero

    2015-04-01

    In a mosaic of well drained forests and poorly drained mires of boreal landscape the weather events such as drought and rainy control greenhouse gas dynamics and ecosystem global warming potential (GWP). In forest-mire ecotone especially in ecosystems where CO2 sink is nearly balanced with CO2 source, it's fairly unknown whether the net warming effect of emissions of gases with strong radiative forcing (CH4 and N2O) could offset the net cooling effect of CO2 sequestration. We compared the net ecosystem CO2 exchange (NEE) estimated from the carbon sequestrations of forest stands and forest floor CO2 fluxes against CH4 and N2O fluxes of nine forest/mire site types along the soil moisture gradient in Finland. The ground water of nine sites changed between 10 m in upland forests and 0.1 m in mires, and weather during three years ranged between exceptionally wet and dry for the local climate. The NEE of upland forests was typically a sink of CO2, regardless the weather. Though, xeric pine forest was estimated to be a source of CO2 during wet and intermediate year and became a weak sink only in dry year. The NEE of forest-mire transitions ranged between a sink in dry year, while increased stand carbon sequestration could offset the reduced forest floor CO2 emission, and a source in wet year. The NEE of two sparsely forested mires strongly differed. The lawn type mire was balanced around zero and the hummock type mire was relatively strong NEE sink, regardless the weather. Generally, nearly zero N2O emission could not offset the cooling effect of net CH4 sink and net CO2 sink of upland forest and forest-mire transitions. However in sparsely forested mires, with N2O emission also nearly zero, the CH4 emission during wet and intermediate year played important role in turning the net cooling effect of NEE into a net warming. When evaluating GWP of boreal landscapes, undisturbed forest-mire transitions should be regarded as net cooling ecosystems instead of hotspots of net

  17. The influence of tropical wind data on the analysis and forecasts of the GLAS GCM for the Global Weather Experiment

    NASA Technical Reports Server (NTRS)

    Paegle, J.; Baker, W. E.

    1985-01-01

    Several densities of tropical divergent wind data were included in a fourth-order GCM to examine the effects on the accuracy of the model predictions. The experiments covered assimilation of all available tropical wind data, no tropical wind data between 20 deg N and 20 deg S, only westerly tropical wind data and only easterly tropical wind data. The predictions were all made for the 200 mb upper troposphere. Elimination of tropical data produced excessively strong upper tropospheric westerlies which in turn amplified the globally integrated rotational flow kinetic energy by around 10 percent and doubled the global divergent flow kinetic energy. Retaining only easterly wind data, ameliorated most of the error. Inclusion of all the tropical wind data however, did not lead to overall positive effects, as the data were linked to tropical wave energetics and ageostrophic winds which were already assimilated in the model.

  18. Development and Implementation of an Isentropic Potential Vorticity Algorithm for use at Air Force Global Weather Center

    DTIC Science & Technology

    1997-03-01

    conditions. vertical profiles of the global mean values are shown on the right (after Peixoto and Oort , 1992) ................ 33 vi Figure Description Page...scale vertical motions critical to cloud and precipitation forecasts, and an alternative method of locating the tropopause in cross-sectional analysis...Depiction and visualization of moisture advection have direct application to forecasting regions of likely cloud , contrail, and precipitation

  19. The role of nitrification in silicate hydrolysis in soils near Santa Cruz, CA

    NASA Astrophysics Data System (ADS)

    Kyker-Snowman, E.; White, A.; Lawrence, C. R.; Schulz, M. S.

    2013-12-01

    In some ecosystems, nitrification (microbial conversion of ammonium to nitrate) may supplant carbonic acid as a source of acidity and drive silicate weathering. Recent studies have explored the impact that ammonium fertilizer addition to soils has on weathering of various mineral types (Pacheco et al. 2013) and demonstrated directly that ammonium addition to soils can increase carbonate weathering (Gandois et al. 2011). Some evidence points to a role for nitrification in silicate weathering at a series of coastal grassland terraces near Santa Cruz, CA. Weathering rates in these soils have been estimated using the byproducts of silicate hydrolysis (Cl--adjusted Na+ and other cations). If carbonic acid from dissolved CO2 is the source of acidity in silicate hydrolysis, bicarbonate should balance the cations produced during weathering. However, in the Santa Cruz soils nitrate is the dominant anion balancing cation concentrations. High concentrations of CO2 (>1%) at depths greater than 1m may provide additional support for nitrification-based silicate hydrolysis at Santa Cruz. We evaluate the role of nitrification in silicate weathering for soils from the Santa Cruz Marine Terrace Chronosequence using a column ammonium-addition experiment and a basic weathering model. The column experiment uses ammonium inputs in excess of natural inputs and measures weathering products in eluted fluids over time. The model incorporates more realistic estimates of ammonium input and explores whether the observed concentrations of cations, nitrate and CO2 seen at Santa Cruz can be explained by nitrification-driven acidity or if other inputs need to be considered. Gandois, L, Perrin, A-S, and Probst, A. 2011. Impact of nitrogenous fertiliser-induced proton release on cultivated soils with contrasting carbonate contents: A column experiment. Geochimica et Cosmochimica Acta 75 pp. 1185-1198. Pacheco, F, Landim, P, and Szocs, T. 2013. Anthropogenic impacts on mineral weathering: A

  20. Jerks as Guiding Influences on the Global Environment: Effects on the Solid Earth, Its Angular Momentum and Lithospheric Plate Motions, the Atmosphere, Weather, and Climate

    NASA Astrophysics Data System (ADS)

    Quinn, J. M.; Leybourne, B. A.

    2010-12-01

    Jerks are thought to be the result of torques applied at the core-mantle boundary (CMB) caused by either of two possible processes, working together or separately: 1) Electromagnetic Induction and 2) Mechanical Slippage. In the first case, it is thought that electromagnetic energy slowly builds-up at the CMB, reaches some critical level, and is then suddenly released, causing a geomagneticly induced torque at the CMB due to the differential electrical conductivity between the lower mantle and the surface of the outer core. The second case is driven by stress and strain increases that buildup mechanical potential energy, which is released when a critical level is reached, thereby generating a torque at the CMB. Generally, a trigger is required to start the Jerk process in motion. In the electromagnetic case, it is suggested that energy from the Sun may supply the requisite energy buildup that is subsequently released by a magnetic storm trigger, for instance. In the case of mechanical slippage, bari-center motion among the Earth, Moon, and Sun, as well as tidal forces and mass redistributions through Earth's wobbles combine to provide the accumulated stress/strain buildup and subsequent trigger. The resulting fluid flow changes at the CMB result in geomagnetic field changes and Joule heating throughout the solid Earth, its oceans, and atmosphere. It is shown that the Global Temperature Anomaly (GTA), which is measured at Earth's surface, correlates with changes in the geomagnetic non-dipole moment, and thus with core fluid motions. This links Global Warming and weather with core processes, important examples being the 1930's Dust Bowl Era and the 1947 Impulse. The CMB torque also affects Earth's angular momentum. But it appears that magnetic storms can as well. As a consequence, the Jet Stream, atmospheric circulation patterns, and the Global Oscillation System (i.e., El-Nino/Southern-Oscillation, North Atlantic Oscillation, the Pacific Decade Oscillation, etc.) are

  1. Mitigation of Atmospheric Delay in SAR Absolute Ranging Using Global Numerical Weather Prediction Data: Corner Reflector Experiments at 3 Different Test Sites

    NASA Astrophysics Data System (ADS)

    Cong, Xiaoying; Balss, Ulrich; Eineder, Michael

    2015-04-01

    The atmospheric delay due to vertical stratification, the so-called stratified atmospheric delay, has a great impact on both interferometric and absolute range measurements. In our current researches [1][2][3], centimeter-range accuracy has been proven based on Corner Reflector (CR) based measurements by applying atmospheric delay correction using the Zenith Path Delay (ZPD) corrections derived from nearby Global Positioning System (GPS) stations. For a global usage, an effective method has been introduced to estimate the stratified delay based on global 4-dimensional Numerical Weather Prediction (NWP) products: the direct integration method [4][5]. Two products, ERA-Interim and operational data, provided by European Centre for Medium-Range Weather Forecast (ECMWF) are used to integrate the stratified delay. In order to access the integration accuracy, a validation approach is investigated based on ZPD derived from six permanent GPS stations located in different meteorological conditions. Range accuracy at centimeter level is demonstrated using both ECMWF products. Further experiments have been carried out in order to determine the best interpolation method by analyzing the temporal and spatial correlation of atmospheric delay using both ECMWF and GPS ZPD. Finally, the integrated atmospheric delays in slant direction (Slant Path Delay, SPD) have been applied instead of the GPS ZPD for CR experiments at three different test sites with more than 200 TerraSAR-X High Resolution SpotLight (HRSL) images. The delay accuracy is around 1-3 cm depending on the location of test site due to the local water vapor variation and the acquisition time/date. [1] Eineder M., Minet C., Steigenberger P., et al. Imaging geodesy - Toward centimeter-level ranging accuracy with TerraSAR-X. Geoscience and Remote Sensing, IEEE Transactions on, 2011, 49(2): 661-671. [2] Balss U., Gisinger C., Cong X. Y., et al. Precise Measurements on the Absolute Localization Accuracy of TerraSAR-X on the

  2. The integration of remote sensing data into global weather prediction, wave forecasting, and ocean circulation computer based systems

    NASA Technical Reports Server (NTRS)

    Pierson, W. J., Jr.

    1970-01-01

    Data from infrared imaging systems and satellite infrared spectrometer (SIRS) for determining sea surface temperature and the atmospheric structure in cloudless areas over the oceans are discussed. Although some interpretations differ, it is clear that simultaneous measurements of radar sea return and passive microwave temperature will provide estimates of the wind speed, and perhaps wind direction, over the oceans, especially in cloudless areas, for a wide range of wind speeds. The problem of integrating the data that would be obtained by a spacecraft, especially one with a combination radar-radiometer, into global analysis procedures for meteorological, wave, and oceanographic predictions is described.

  3. Climate change mitigation: potential benefits and pitfalls of enhanced rock weathering in tropical agriculture.

    PubMed

    Edwards, David P; Lim, Felix; James, Rachael H; Pearce, Christopher R; Scholes, Julie; Freckleton, Robert P; Beerling, David J

    2017-04-01

    Restricting future global temperature increase to 2°C or less requires the adoption of negative emissions technologies for carbon capture and storage. We review the potential for deployment of enhanced weathering (EW), via the application of crushed reactive silicate rocks (such as basalt), on over 680 million hectares of tropical agricultural and tree plantations to offset fossil fuel CO2 emissions. Warm tropical climates and productive crops will substantially enhance weathering rates, with potential co-benefits including decreased soil acidification and increased phosphorus supply promoting higher crop yields sparing forest for conservation, and reduced cultural eutrophication. Potential pitfalls include the impacts of mining operations on deforestation, producing the energy to crush and transport silicates and the erosion of silicates into rivers and coral reefs that increases inorganic turbidity, sedimentation and pH, with unknown impacts for biodiversity. We identify nine priority research areas for untapping the potential of EW in the tropics, including effectiveness of tropical agriculture at EW for major crops in relation to particle sizes and soil types, impacts on human health, and effects on farmland, adjacent forest and stream-water biodiversity.

  4. Cockpit weather information system

    NASA Technical Reports Server (NTRS)

    Tu, Jeffrey Chen-Yu (Inventor)

    2000-01-01

    Weather information, periodically collected from throughout a global region, is periodically assimilated and compiled at a central source and sent via a high speed data link to a satellite communication service, such as COMSAT. That communication service converts the compiled weather information to GSDB format, and transmits the GSDB encoded information to an orbiting broadcast satellite, INMARSAT, transmitting the information at a data rate of no less than 10.5 kilobits per second. The INMARSAT satellite receives that data over its P-channel and rebroadcasts the GDSB encoded weather information, in the microwave L-band, throughout the global region at a rate of no less than 10.5 KB/S. The transmission is received aboard an aircraft by means of an onboard SATCOM receiver and the output is furnished to a weather information processor. A touch sensitive liquid crystal panel display allows the pilot to select the weather function by touching a predefined icon overlain on the display's surface and in response a color graphic display of the weather is displayed for the pilot.

  5. A global non-hydrostatic weather forecast model in KIAPS using the spectral element on a cubed sphere

    NASA Astrophysics Data System (ADS)

    Choi, Suk-Jin; Lee, Eun-Hee; Hong, Song-You

    2016-04-01

    This presentation covers an introduction to the current state of a non-hydrostatic global atmospheric model to be named the KIAPS integrated model (KIM). Efforts to resolve an excessive dissipation in small scales in KIM will be discussed. Also, simulated results for several idealized benchmark tests and full-physics forecasts will be shown. The dynamical core of the model is using the Euler equation set in a flux form based on the terrain following mass-based vertical coordinate, which is discretized by horizontal spectral element method (SEM) and the vertical finite difference method (FDM) for the spatial discretization and a time-split third-order Runge-Kutta (RK3) for the time discretization. Owing to the virtue of SEM and the explicit time integrator, KIM can achieve easily a high level of scalability. The physics package coupled with the dynamical core is a standard physics package from existing models such as the GRIMs, WRF, and GFS.

  6. Has Anthropogenic Global Warming in the Arctic Contributed to Colder Winter Weather in the Northern Hemisphere Mid-latitudes?

    NASA Astrophysics Data System (ADS)

    Cohen, J. L.; Furtado, J. C.; Barlow, M. A.; Cherry, J. E.; Alexeev, V. A.

    2012-12-01

    The global climate models predict that temperatures will warm the greatest in winter due to a positive feedback of increased greenhouse gases and a diminished and darker cryosphere. Furthermore, current consensus on global climate change predicts warming trends over the NH continents during boreal winter. However, recent trends in Northern Hemisphere (NH) seasonal surface temperatures diverge from these projections. For the last two decades or so, NH landmasses have experienced significant warming trends for all seasons except winter, when large-scale cooling trends exist instead. We propose a mechanism linking Arctic warming and winter continental cooling. Evidence suggests that summer and autumn Arctic warming trends are concurrent with increases in high-latitude moisture and an increase in autumnal Eurasian snow cover, which dynamically induces large-scale wintertime cooling. Understanding this counterintuitive response to radiative warming of the climate system has the potential to improve climate predictions at seasonal and longer timescales.a) JAS area-averaged (poleward of 60°N) surface temperature anomalies (°C) from NASA MERRA. b) September area-averaged (poleward of 65°N) Arctic Ocean sea ice coverage (fractional area). c) September - October vertically integrated (700-1000 hPa) and area-averaged (poleward of 60°N) specific humidity (kg m-2). d) October mean snow cover areal extent (106 km2) over the Eurasian continent from observations (black) and ensemble-mean from the historical runs of the CMIP5 model output (brown line). e) The DJF average AO index (standardized). Same-coloured dashed lines in a) - e) represent the linear trend in each index. Trends with double asterisk (**) indicate trends are significant at the p < 0.01 level.

  7. Calcium silicate insulation structure

    DOEpatents

    Kollie, Thomas G.; Lauf, Robert J.

    1995-01-01

    An insulative structure including a powder-filled evacuated casing utilizes a quantity of finely divided synthetic calcium silicate having a relatively high surface area. The resultant structure-provides superior thermal insulating characteristics over a broad temperature range and is particularly well-suited as a panel for a refrigerator or freezer or the insulative barrier for a cooler or a insulated bottle.

  8. Space Weather Services of Korea

    NASA Astrophysics Data System (ADS)

    Yoon, KiChang; Kim, Jae-Hun; Kim, Young Yun; Kwon, Yongki; Wi, Gwan-sik

    2016-07-01

    The Korean Space Weather Center (KSWC) of the National Radio Research Agency (RRA) is a government agency which is the official source of space weather information for Korean Government and the primary action agency of emergency measure to severe space weather condition. KSWC's main role is providing alerts, watches, and forecasts in order to minimize the space weather impacts on both of public and commercial sectors of satellites, aviation, communications, navigations, power grids, and etc. KSWC is also in charge of monitoring the space weather condition and conducting research and development for its main role of space weather operation in Korea. In this study, we will present KSWC's recent efforts on development of application-oriented space weather research products and services on user needs, and introduce new international collaborative projects, such as IPS-Driven Enlil model, DREAM model estimating electron in satellite orbit, global network of DSCOVR and STEREO satellites tracking, and ARMAS (Automated Radiation Measurement for Aviation Safety).

  9. Space Weather Services of Korea

    NASA Astrophysics Data System (ADS)

    Yoon, K.; Hong, S.; Park, S.; Kim, Y. Y.; Wi, G.

    2015-12-01

    The Korean Space Weather Center (KSWC) of the National Radio Research Agency (RRA) is a government agency which is the official source of space weather information for Korean Government and the primary action agency of emergency measure to severe space weather condition. KSWC's main role is providing alerts, watches, and forecasts in order to minimize the space weather impacts on both of public and commercial sectors of satellites, aviation, communications, navigations, power grids, and etc. KSWC is also in charge of monitoring the space weather condition and conducting research and development for its main role of space weather operation in Korea. In this study, we will present KSWC's recent efforts on development of application-oriented space weather research products and services on user needs, and introduce new international collaborative projects, such as IPS-Driven Enlil model, global network of DSCOVR and STEREO satellites tracking, and ARMAS (Automated Radiation Measurement for Aviation Safety).

  10. Do disease cycles follow changes in weather? Researchers ponder global warming`s effect on the carriers of human illness

    SciTech Connect

    Brown, K.S.

    1996-07-01

    Two years ago, Mother Nature one-upped an Institute of Medicine (IOM) committee big time. In 1991, the committee had wracked its collective brains to come up with a plausible epidemic scenario for a report on disease emergence. The team finally settled on a potential southern US outbreak of yellow fever, a well-known African viral disease carried by mosquitoes. The idea was realistic, if not particularly imaginative. Yellow fever is an old problem. Shortly after the report on microbe-induced epidemics was released, Mother Nature displayed tremendous creativity. In the spring of 1993, a mysterious virus began killing young people in the Southwest. The culprit turned out to be a previously unrecognized strain of hantavirus, which causes a deadly respiratory disease. Emerging from its natural host, the common deer mouse, the hantavirus strain affected at least 131 people. Half died. Today, emerging viruses have shocked the public and sent scientists searching for causes of epidemics and factors that determine how serious disease outbreaks might be be. One factor gaining attention climate. To learn how global warming might affect mosquitoes, mice and other microbe carriers, biologists are studying diseases within an environmental context. This article discusses the work in this area and some of the results, speculations, and future areas of interest.

  11. MSATT Workshop on Chemical Weathering on Mars

    NASA Technical Reports Server (NTRS)

    Burns, Roger (Editor); Banin, Amos (Editor)

    1992-01-01

    The topics covered with respect to chemical weathering on Mars include the following: Mars soil, mineralogy, spectroscopic analysis, clays, silicates, oxidation, iron oxides, water, chemical reactions, geochemistry, minerals, Mars atmosphere, atmospheric chemistry, salts, planetary evolution, volcanology, Mars volcanoes, regolith, surface reactions, Mars soil analogs, carbonates, meteorites, and reactivity.

  12. Chemical weathering in a tropical watershed, Luquillo Mountains, Puerto Rico: I. Long-term versus short-term weathering fluxes

    USGS Publications Warehouse

    White, A.F.; Blum, A.E.; Schulz, M.S.; Vivit, D.V.; Stonestrom, D.A.; Larsen, M.; Murphy, S.F.; Eberl, D.

    1998-01-01

    The pristine Rio Icacos watershed in the Luquillo Mountains in eastern Puerto Rico has the fastest documented weathering rate of silicate rocks on the Earth's surface. A regolith propagation rate of 58 m Ma-1 calculated from iso-volumetric saprolite formation from quartz diorite, is comparable to the estimated denudation rate (25-50 Ma-1) but is an order of magnitude faster than the global average weathering rate (6 Ma-1). Weathering occurs in two distinct environments; plagioclase and hornblende react at the saprock interface and biotite and quartz weather in the overlying thick saprolitic regolith. These environments produce distinctly different water chemistries, with K, Mg, and Si increasing linearly with depth in saprolite porewaters and with stream waters dominated by Ca, Na, and Si. Such differences are atypical of less intense weathering in temperate watersheds. Porewater chemistry in the shallow regolith is controlled by closed-system recycling of inorganic nutrients such as K. Long-term elemental fluxes through the regolith (e.g., Si = 1.7 ?? 10-8 moles m-2 s-1) are calculated from mass losses based on changes in porosity and chemistry between the regolith and bedrock and from the age of the regolith surface (200 Ma). Mass losses attributed to solute fluxes are determined using a step-wise infiltration model which calculates mineral inputs to the shallow and deep saprolite porewaters and to stream water. Pressure heads decrease with depth in the shallow regolith (-2.03 m H2O m-1), indicating that both increasing capillary tension and graviometric potential control porewater infiltration. Interpolation of experimental hydraulic conductivities produces an infiltration rate of 1 m yr-1 at average field moisture saturation which is comparable with LiBr tracer tests and with base discharge from the watershed. Short term weathering fluxes calculated from solute chemistries and infiltration rates (e.g., Si = 1.4 ?? 10-8 moles m-2 s-1) are compared to watershed

  13. Weather Instruments.

    ERIC Educational Resources Information Center

    Brantley, L. Reed, Sr.; Demanche, Edna L.; Klemm, E. Barbara; Kyselka, Will; Phillips, Edwin A.; Pottenger, Francis M.; Yamamoto, Karen N.; Young, Donald B.

    This booklet presents some activities to measure various weather phenomena. Directions for constructing a weather station are included. Instruments including rain gauges, thermometers, wind vanes, wind speed devices, humidity devices, barometers, atmospheric observations, a dustfall jar, sticky-tape can, detection of gases in the air, and pH of…

  14. Wacky Weather

    ERIC Educational Resources Information Center

    Sabarre, Amy; Gulino, Jacqueline

    2013-01-01

    What do a leaf blower, water hose, fan, and ice cubes have in common? Ask the students who participated in an integrative science, technology, engineering, and mathematics (I-STEM) education unit, "Wacky Weather," and they will tell say "fun and severe weather"--words one might not have expected! The purpose of the unit…

  15. Mass-balance modeling of mineral weathering rates and CO2 consumption in the forested, metabasaltic Hauver Branch watershed, Catoctin Mountain, Maryland, USA

    USGS Publications Warehouse

    Rice, Karen; Price, Jason R.; Szymanski, David W.

    2013-01-01

    Mineral weathering rates and a forest macronutrient uptake stoichiometry were determined for the forested, metabasaltic Hauver Branch watershed in north-central Maryland, USA. Previous studies of Hauver Branch have had an insufficient number of analytes to permit determination of rates of all the minerals involved in chemical weathering, including biomass. More equations in the mass-balance matrix were added using existing mineralogic information. The stoichiometry of a deciduous biomass term was determined using multi-year weekly to biweekly stream-water chemistry for a nearby watershed, which drains relatively unreactive quartzite bedrock.At Hauver Branch, calcite hosts ~38 mol% of the calcium ion (Ca2+) contained in weathering minerals, but its weathering provides ~90% of the stream water Ca2+. This occurs in a landscape with a regolith residence time of more than several Ka (kiloannum). Previous studies indicate that such old regolith does not typically contain dissolving calcite that affects stream Ca2+/Na+ ratios. The relatively high calcite dissolution rate likely reflects dissolution of calcite in fractures of the deep critical zone.Of the carbon dioxide (CO2) consumed by mineral weathering, calcite is responsible for approximately 27%, with the silicate weathering consumption rate far exceeding that of the global average. The chemical weathering of mafic terrains in decaying orogens thus may be capable of influencing global geochemical cycles, and therefore, climate, on geological timescales. Based on carbon-balance calculations, atmospheric-derived sulfuric acid is responsible for approximately 22% of the mineral weathering occurring in the watershed. Our results suggest that rising air temperatures, driven by global warming and resulting in higher precipitation, will cause the rate of chemical weathering in the Hauver Branch watershed to increase until a threshold temperature is reached. Beyond the threshold temperature, increased recharge would

  16. Enhanced Weathering Strategies for Stabilizing Climate and Averting Ocean Acidification - Supplementary Information

    NASA Technical Reports Server (NTRS)

    Taylor, Lyla L.; Quirk, Joe; Thorley, Rachel M. S.; Kharecha, Pushker A.; Hansen, James; Ridgwell, Andy; Lomas, Mark R.; Banwart, Steve A.; Beerling, David J.

    2015-01-01

    Chemical breakdown of rocks, weathering, is an important but very slow part of the carbon cycle that ultimately leads to CO2 being locked up in carbonates on the ocean floor. Artificial acceleration of this carbon sink via distribution of pulverized silicate rocks across terrestrial landscapes may help offset anthropogenic CO2 emissions. We show that idealized enhanced weathering scenarios over less than a third of tropical land could cause significant drawdown of atmospheric CO2 and ameliorate ocean acidification by 2100. Global carbon cycle modelling driven by ensemble Representative Concentration Pathway (RCP) projections of twenty-first-century climate change (RCP8.5, business-as-usual; RCP4.5, medium-level mitigation) indicates that enhanced weathering could lower atmospheric CO2 by 30-300 ppm by 2100, depending mainly on silicate rock application rate (1 kg or 5 kg m(exp. -2) yr (exp -1)) and composition. At the higher application rate, end-of-century ocean acidification is reversed under RCP4.5 and reduced by about two-thirds under RCP8.5. Additionally, surface ocean aragonite saturation state, a key control on coral calcification rates, is maintained above 3.5 throughout the low latitudes, thereby helping maintain the viability of tropical coral reef ecosystems. However, we highlight major issues of cost, social acceptability, and potential unanticipated consequences that will limit utilization and emphasize the need for urgent efforts to phase down fossil fuel emissions.

  17. Silicates in Alien Asteroids

    NASA Technical Reports Server (NTRS)

    2009-01-01

    This plot of data from NASA's Spitzer Space Telescopes shows that asteroid dust around a dead 'white dwarf' star contains silicates a common mineral on Earth. The data were taken primarily by Spitzer's infrared spectrograph, an instrument that breaks light apart into its basic constituents. The yellow dots show averaged data from the spectrograph, while the orange triangles show older data from Spitzer's infrared array camera. The white dwarf is called GD 40.

  18. Thermochemistry of Silicates

    NASA Technical Reports Server (NTRS)

    Costa, Gustavo; Jacobson, Nathan

    2015-01-01

    The thermodynamic properties of vapor and condensed phases of silicates are crucial in many fields of science. These quantities address fundamental questions on the formation, stability, transformation, and physical properties of silicate minerals and silicate coating compositions. Here the thermodynamic activities of silica and other species in solid solution have been measured by the analysis of the corresponding high temperature vapors using Knudsen Effusion Mass Spectrometry (KEMS). In first set of experiments KEMS has been used to examine the volatility sequence of species (Fe, SiO, Mg, O2 and O) present in the vapor phase during heating of fosterite-rich olivine (Fo93Fa7) up to 2400 C and to measure the Fe, SiO and Mg activities in its solid solution. The data of fosterite-rich olivine are essential for thermochemical equilibrium models to predict the atmospheric and surface composition of hot, rocky exoplanets (Lava Planets). In the second set of experiments the measured thermodynamic activities of the silica in Y2O3-SiO2 and Yb2O3-SiO2 systems are used to assess their reactivity and degradation recession as environmental barrier coatings (EBCs) in combustion environments (e.g. non-moveable parts of gas turbine engine).

  19. Some topics on geochemistry of weathering: a review.

    PubMed

    Formoso, Milton L L

    2006-12-01

    Weathering is a complex process comprising physical disaggregation, chemical and biological decomposition of rocks and minerals transforming complex structure minerals in simpler ones. Hydrolysis of silicates is perhaps the most important process but associated certainly to biological weathering. It is discussed the role ofwaters: activities/concentrations of chemical species, pH, Eh, importance of complexes. Weathering is not only a destructive process. It can concentrate chemical species and form mineral deposits (kaolin, bauxite, Fe, Mn, P, Nb, Au). Weathering studies are important in pedology, engineering geology, hydrogeology, paleoclimatology and ecology. The use of stonemeal is based upon the study of rock weathering.

  20. Weatherizing America

    SciTech Connect

    Stewart, Zachary; Bergeron, T.J.; Barth, Dale; Qualis, Xavier; Sewall, Travis; Fransen, Richard; Gill, Tony

    2009-01-01

    As Recovery Act money arrives to expand home weatherization programs across the country, Zachary Stewart of Phoenix, Ariz., and others have found an exciting opportunity not only to start working again, but also to find a calling.

  1. Weatherizing America

    ScienceCinema

    Stewart, Zachary; Bergeron, T.J.; Barth, Dale; Qualis, Xavier; Sewall, Travis; Fransen, Richard; Gill, Tony

    2016-07-12

    As Recovery Act money arrives to expand home weatherization programs across the country, Zachary Stewart of Phoenix, Ariz., and others have found an exciting opportunity not only to start working again, but also to find a calling.

  2. Chemical weathering and associated carbon-dioxide consumption in a tropical river basin (Swarna River), Southwestern India

    NASA Astrophysics Data System (ADS)

    Muguli, T.; Gurumurthy, G. P.; Balakrishna, K.; Audry, S.; Riotte, J.; Braun, J.; Chadaga, M.; Shankar HN, U.

    2013-12-01

    Chemical weathering in river basins forms the key process to study the global climate change on a long term scale due to its association with the carbon sequestration. Water samples from a west flowing tropical river (Swarna River) of Southern India were collected for a period of two years to study the chemical weathering process and to quantify the weathering and associated carbon-dioxide consumption rates in the river basin. In addition, the major ion chemistry of Swarna River is studied for the first time on a spatial and temporal (monthly) scale to decipher the factors (lithology, precipitation/ discharge, temperature, slope and physical weathering) controlling the chemical weathering process. Swarna River originates in Western Ghats at an altitude of 1100 m above mean sea level and flows westwards draining Peninsular Gneiss and Dharwar Schist to join the Arabian Sea near Udupi. The river basin receives annual rainfall of 4500 mm and experiences warm climate with average temperature of 30°C. Major ion composition and radiogenic strontium isotopic composition measured in the Swarna river water reflects the influence of silicate rocks in the basin. The river water chemistry is found to be least affected by anthropogenic impact; however, the effect of evaporation is observed on few samples during the peak dry season. The atmospheric inputs and carbonate contributions to the river water are corrected to estimate the silicate weathering rate (SWR) and the associated carbon-dioxide consumption rate (CCR) using local rainwater and bed rock composition respectively. The SWR and CCR in the Swarna river basin are estimated to be 46 tons/km2/yr and 4.4 x 10^5 mol/km2/yr respectively. This estimation is observed to be relatively higher than the recently reported SWR and CCR in the adjacent larger Nethravati river basin (Gurumurthy et al., 2012). The increased rate could be attributed to the relatively higher precipitation in the Swarna river basin than the lithological

  3. 21 CFR 573.260 - Calcium silicate.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 21 Food and Drugs 6 2013-04-01 2013-04-01 false Calcium silicate. 573.260 Section 573.260 Food and... Listing § 573.260 Calcium silicate. Calcium silicate, including synthetic calcium silicate, may be safely used as an anticaking agent in animal feed, provided that the amount of calcium silicate does...

  4. 21 CFR 573.260 - Calcium silicate.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 21 Food and Drugs 6 2014-04-01 2014-04-01 false Calcium silicate. 573.260 Section 573.260 Food and... Listing § 573.260 Calcium silicate. Calcium silicate, including synthetic calcium silicate, may be safely used as an anticaking agent in animal feed, provided that the amount of calcium silicate does...

  5. 21 CFR 573.260 - Calcium silicate.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 21 Food and Drugs 6 2012-04-01 2012-04-01 false Calcium silicate. 573.260 Section 573.260 Food and... Listing § 573.260 Calcium silicate. Calcium silicate, including synthetic calcium silicate, may be safely used as an anticaking agent in animal feed, provided that the amount of calcium silicate does...

  6. 21 CFR 573.260 - Calcium silicate.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 21 Food and Drugs 6 2010-04-01 2010-04-01 false Calcium silicate. 573.260 Section 573.260 Food and... Listing § 573.260 Calcium silicate. Calcium silicate, including synthetic calcium silicate, may be safely used as an anticaking agent in animal feed, provided that the amount of calcium silicate does...

  7. 21 CFR 573.260 - Calcium silicate.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 21 Food and Drugs 6 2011-04-01 2011-04-01 false Calcium silicate. 573.260 Section 573.260 Food and... Listing § 573.260 Calcium silicate. Calcium silicate, including synthetic calcium silicate, may be safely used as an anticaking agent in animal feed, provided that the amount of calcium silicate does...

  8. The effect of rock composition on cyanobacterial weathering of crystalline basalt and rhyolite.

    PubMed

    Olsson-Francis, K; Simpson, A E; Wolff-Boenisch, D; Cockell, C S

    2012-09-01

    The weathering of volcanic rocks contributes significantly to the global silicate weathering budget, effecting carbon dioxide drawdown and long-term climate control. The rate of chemical weathering is influenced by the composition of the rock. Rock-dwelling micro-organisms are known to play a role in changing the rate of weathering reactions; however, the influence of rock composition on bio-weathering is unknown. Cyanobacteria are known to be a ubiquitous surface taxon in volcanic rocks. In this study, we used a selection of fast and slow growing cyanobacterial species to compare microbial-mediated weathering of bulk crystalline rocks of basaltic and rhyolitic composition, under batch conditions. Cyanobacterial growth caused an increase in the pH of the medium and an acceleration of rock dissolution compared to the abiotic controls. For example, Anabaena cylindrica increased the linear release rate (R(i)(l)) of Ca, Mg, Si and K from the basalt by more than fivefold (5.21-12.48) and increased the pH of the medium by 1.9 units. Although A. cylindrica enhanced rhyolite weathering, the increase in R(i)(l) was less than threefold (2.04-2.97) and the pH increase was only 0.83 units. The R(i)(l) values obtained with A. cylindrica were at least ninefold greater with the basalt than the rhyolite, whereas in the abiotic controls, the difference was less than fivefold. Factors accounting for the slower rate of rhyolite weathering and lower biomass achieved are likely to include the higher content of quartz, which has a low rate of weathering and lower concentrations of bio-essential elements, such as, Ca, Fe and Mg, which are known to be important in controlling cyanobacterial growth. We show that at conditions where weathering is favoured, biota can enhance the difference between low and high Si-rock weathering. Our data show that cyanobacteria can play a significant role in enhancing rock weathering and likely have done since they evolved on the early Earth.

  9. The Weather Radar Toolkit, National Oceanic and Atmospheric Administration (NOAA) National Climatic Data Center's support of interoperability and the Global Earth Observation System of Systems (GEOSS)

    NASA Astrophysics Data System (ADS)

    Ansari, S.; Del Greco, S.

    2006-12-01

    In February 2005, 61 countries around the World agreed on a 10 year plan to work towards building open systems for sharing geospatial data and services across different platforms worldwide. This system is known as the Global Earth Observation System of Systems (GEOSS). The objective of GEOSS focuses on easy access to environmental data and interoperability across different systems allowing participating countries to measure the "pulse" of the planet in an effort to advance society. In support of GEOSS goals, NOAA's National Climatic Data Center (NCDC) has developed radar visualization and data exporter tools in an open systems environment. The NCDC Weather Radar Toolkit (WRT) loads Weather Surveillance Radar 1988 Doppler (WSR-88D) volume scan (S-band) data, known as Level-II, and derived products, known as Level-III, into an Open Geospatial Consortium (OGC) compliant environment. The application is written entirely in Java and will run on any Java- supported platform including Windows, Macintosh and Linux/Unix. The application is launched via Java Web Start and runs on the client machine while accessing these data locally or remotely from the NCDC archive, NOAA FTP server or any URL or THREDDS Data Server. The WRT allows the data to be manipulated to create custom mosaics, composites and precipitation estimates. The WRT Viewer provides tools for custom data overlays, Web Map Service backgrounds, animations and basic filtering. The export of images and movies is provided in multiple formats. The WRT Data Exporter allows for data export in both vector polygon (Shapefile, Well-Known Text) and raster (GeoTIFF, ESRI Grid, VTK, NetCDF, GrADS) formats. By decoding the various Radar formats into the NetCDF Common Data Model, the exported NetCDF data becomes interoperable with existing software packages including THREDDS Data Server and the Integrated Data Viewer (IDV). The NCDC recently partnered with NOAA's National Severe Storms Lab (NSSL) to decode Sigmet C-band Doppler

  10. Smooth Sailing for Weather Forecasting

    NASA Technical Reports Server (NTRS)

    2002-01-01

    Through a cooperative venture with NASA's Stennis Space Center, WorldWinds, Inc., developed a unique weather and wave vector map using space-based radar satellite information and traditional weather observations. Called WorldWinds, the product provides accurate, near real-time, high-resolution weather forecasts. It was developed for commercial and scientific users. In addition to weather forecasting, the product's applications include maritime and terrestrial transportation, aviation operations, precision farming, offshore oil and gas operations, and coastal hazard response support. Target commercial markets include the operational maritime and aviation communities, oil and gas providers, and recreational yachting interests. Science applications include global long-term prediction and climate change, land-cover and land-use change, and natural hazard issues. Commercial airlines have expressed interest in the product, as it can provide forecasts over remote areas. WorldWinds, Inc., is currently providing its product to commercial weather outlets.

  11. 21 CFR 182.2906 - Tricalcium silicate.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... Tricalcium silicate. (a) Product. Tricalcium silicate. (b) Tolerance. 2 percent. (c) Limitations, restrictions, or explanation. This substance is generally recognized as safe when used in table salt...

  12. 21 CFR 582.2906 - Tricalcium silicate.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... Tricalcium silicate. (a) Product. Tricalcium silicate. (b) Tolerance. 2 percent. (c) Limitations, restrictions, or explanation. This substance is generally recognized as safe when used in table salt...

  13. 21 CFR 182.2906 - Tricalcium silicate.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... Tricalcium silicate. (a) Product. Tricalcium silicate. (b) Tolerance. 2 percent. (c) Limitations, restrictions, or explanation. This substance is generally recognized as safe when used in table salt...

  14. 21 CFR 582.2906 - Tricalcium silicate.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... Tricalcium silicate. (a) Product. Tricalcium silicate. (b) Tolerance. 2 percent. (c) Limitations, restrictions, or explanation. This substance is generally recognized as safe when used in table salt...

  15. 21 CFR 582.2906 - Tricalcium silicate.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... Tricalcium silicate. (a) Product. Tricalcium silicate. (b) Tolerance. 2 percent. (c) Limitations, restrictions, or explanation. This substance is generally recognized as safe when used in table salt...

  16. 21 CFR 182.2906 - Tricalcium silicate.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... Tricalcium silicate. (a) Product. Tricalcium silicate. (b) Tolerance. 2 percent. (c) Limitations, restrictions, or explanation. This substance is generally recognized as safe when used in table salt...

  17. 21 CFR 582.2906 - Tricalcium silicate.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... Tricalcium silicate. (a) Product. Tricalcium silicate. (b) Tolerance. 2 percent. (c) Limitations, restrictions, or explanation. This substance is generally recognized as safe when used in table salt...

  18. 21 CFR 182.2906 - Tricalcium silicate.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... Tricalcium silicate. (a) Product. Tricalcium silicate. (b) Tolerance. 2 percent. (c) Limitations, restrictions, or explanation. This substance is generally recognized as safe when used in table salt...

  19. 21 CFR 582.2906 - Tricalcium silicate.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... Tricalcium silicate. (a) Product. Tricalcium silicate. (b) Tolerance. 2 percent. (c) Limitations, restrictions, or explanation. This substance is generally recognized as safe when used in table salt...

  20. Weathering of sulfides on Mars

    NASA Technical Reports Server (NTRS)

    Burns, Roger G.; Fisher, Duncan S.

    1987-01-01

    Pyrrhotite-pentlandite assemblages in mafic and ultramafic igneous rocks may have contributed significantly to the chemical weathering reactions that produce degradation products in the Martian regolith. By analogy and terrestrial processes, a model is proposed whereby supergene alteration of these primary Fe-Ni sulfides on Mars has generated secondary sulfides (e.g., pyrite) below the water table and produced acidic groundwater containing high concentrations of dissolved Fe, Ni, and sulfate ions. The low pH solutions also initiated weathering reactions of igneous feldspars and ferromagnesian silicates to form clay silicate and ferric oxyhydroxide phases. Near-surface oxidation and hydrolysis of ferric sulfato-and hydroxo-complex ions and sols formed gossan above the water table consisting of poorly crystalline hydrated ferric sulfates (e.g., jarosite), oxides (ferrihydrite, goethite), and silica (opal). Underlying groundwater, now permafrost contains hydroxo sulfato complexes of Fe, Al, Mg, Ni, which may be stabilized in frozen acidic solutions beneath the surface of Mars. Sublimation of permafrost may replenish colloidal ferric oxides, sulfates, and phyllosilicates during dust storms on Mars.

  1. Lithium isotope behaviour during weathering in the Ganges Alluvial Plain

    NASA Astrophysics Data System (ADS)

    Pogge von Strandmann, Philip A. E.; Frings, Patrick J.; Murphy, Melissa J.

    2017-02-01

    The Ganges river system is responsible for the transportation of a large flux of dissolved materials derived from Himalayan weathering to the oceans. Silicate weathering-driven cooling resulting from uplift of the Himalayas has been proposed to be a key player in Cenozoic climate variation. This study has analysed Li isotope (δ7Li) ratios from over 50 Ganges river waters and sediments, in order to trace silicate weathering processes. Sediments have δ7Li of ∼0‰, identical to bulk continental crust, however suspended sediment depth profiles do not display variations associated with grain size that have been observed in other large river systems. Dissolved δ7Li are low (∼11‰) in the Ganges headwaters, but reach a constant value of 21 ± 1.6‰ within a relatively short distance downstream, which is then maintained for almost 2000 km to the Ganges mouth. Given that Li isotopes are controlled by the ratio of primary mineral dissolution to secondary mineral formation, this suggests that the Ganges floodplain is at steady-state in terms of these processes for most of its length. Low δ7Li in the mountainous regions suggest silicate weathering is therefore at its most congruent where uplift and fresh silicate exposure rates are high. However, there is no correlation between δ7Li and the silicate weathering rate in these rivers, suggesting that Li isotopes cannot be used as a weathering-rate tracer, although they do inform on weathering congruency and intensity. The close-to-constant δ7Li values for the final 2000 km of Ganges flow also suggest that once the size of the alluvial plain reached more than ∼500 km (the flow distance after which riverine δ7Li stops varying), the Ganges exerted little influence on the changing Cenozoic seawater δ7Li, because riverine δ7Li attained a near steady-state composition.

  2. Seafloor weathering buffering climate: numerical experiments

    NASA Astrophysics Data System (ADS)

    Farahat, N. X.; Archer, D. E.; Abbot, D. S.

    2013-12-01

    Continental silicate weathering is widely held to consume atmospheric CO2 at a rate controlled in part by temperature, resulting in a climate-weathering feedback [Walker et al., 1981]. It has been suggested that weathering of oceanic crust of warm mid-ocean ridge flanks also has a CO2 uptake rate that is controlled by climate [Sleep and Zahnle, 2001; Brady and Gislason, 1997]. Although this effect might not be significant on present-day Earth [Caldeira, 1995], seafloor weathering may be more pronounced during snowball states [Le Hir et al., 2008], during the Archean when seafloor spreading rates were faster [Sleep and Zahnle, 2001], and on waterworld planets [Abbot et al., 2012]. Previous studies of seafloor weathering have made significant contributions using qualitative, generally one-box, models, and the logical next step is to extend this work using a spatially resolved model. For example, experiments demonstrate that seafloor weathering reactions are temperature dependent, but it is not clear whether the deep ocean temperature affects the temperature at which the reactions occur, or if instead this temperature is set only by geothermal processes. Our goal is to develop a 2-D numerical model that can simulate hydrothermal circulation and resulting alteration of oceanic basalts, and can therefore address such questions. A model of diffusive and convective heat transfer in fluid-saturated porous media simulates hydrothermal circulation through porous oceanic basalt. Unsteady natural convection is solved for using a Darcy model of porous media flow that has been extensively benchmarked. Background hydrothermal circulation is coupled to mineral reaction kinetics of basaltic alteration and hydrothermal mineral precipitation. In order to quantify seafloor weathering as a climate-weathering feedback process, this model focuses on hydrothermal reactions that influence carbon uptake as well as ocean alkalinity: silicate rock dissolution, calcium and magnesium leaching

  3. The surface of Mercury: space weathering effects

    NASA Astrophysics Data System (ADS)

    Baratta, G.; Kanuchova, Z.; Palumbo, M. E.; Sangiorgio, I.; Strazzulla, G.

    2011-10-01

    We present some results of an ongoing experimental research aimed at simulating the effects of ion bombardment (space weathering) in solid objects of the Solar System. In particular we have investigated the color changes induced by the ion bombardment in the UV-Vis-IR In this contribution we focus on materials (silicates) and spectral range (200-300 nanometers) particularly relevant to the study of the Mercury's surface.

  4. Chemical weathering in the Three Rivers region of Eastern Tibet

    NASA Astrophysics Data System (ADS)

    Noh, Hyonjeong; Huh, Youngsook; Qin, Jianhua; Ellis, Andre

    2009-04-01

    Three large rivers - the Chang Jiang (Yangtze), Mekong (Lancang Jiang) and Salween (Nu Jiang) - originate in eastern Tibet and run in close parallel over 300 km near the eastern Himalayan syntaxis. Seventy-four river water samples were collected mostly during the summer season from 1999 to 2004. Their major element compositions vary widely, with total dissolved solids (TDS) ranging from 31 to 3037 mg/l, reflecting the complex geologic makeup of the vast drainage basins. The major ion distribution of the main channel samples primarily reflects the weathering of carbonates. Evaporite dissolution prevails in the headwater samples of the Chang Jiang in the Tibetan Plateau interior, as evidenced by the high TDS (928 and 3037 mg/l) and the Na-Cl dominant major element composition. Local tributary samples of the Mekong and Salween, draining the Lincang Batholith and the Tengchong Volcano, show distinctive silicate weathering signatures. We used five reservoirs - rain, halite, sulfate, carbonate, and silicate - in a forward model to calculate the contribution from silicate weathering to the total dissolved load and to estimate the consumption rate of atmospheric CO 2 by silicate weathering. Carbonate weathering accounts for about 50% of the total cationic charge (TZ +) in the samples of the Mekong and the Salween exiting the Tibetan Plateau. In the "exit" sample of the Chang Jiang, 45% of TZ + is from halite dissolution inherited from the extreme headwater tributaries in the interior of the plateau, and carbonates contribute only 26% to the TZ +. The net rate of CO 2 consumption by silicate weathering is (103-121) × 10 3 mol km -2 year -1, lower than the rivers draining the Himalayan front. GIS-based analyses indicate that runoff and relief can explain 52% of the spread in the rate of atmospheric CO 2 drawdown by silicate weathering, but other climatic (temperature, precipitation, potential evapotranspiration) and geomorphic (elevation, slope) factors also show

  5. Does mineral surface area affect chemical weathering rates?

    NASA Astrophysics Data System (ADS)

    Salome Eiriksdottir, Eydis; Reynir Gislason, Sigurdur; Oelkers, Eric H.

    2010-05-01

    concentration of soluble elements (Na, Ca, Ba, V) decrease with decreasing particle size in samples collected from various catchments. References. Eiriksdottir E.S., Louvat P., Gislason S.R., Óskarsson N., Hardardóttir J., 2008. Temporal variation of chemical and mechanical weathering in NE Iceland: Evaluation of a steady-state model of erosion. EPSL 272, 78-88 Gaillardet, J., Dupré, B., Allegre, C.J., Négrel, P., 1999b. Geochemistry of large river suspended sediments: silicate weathering or recycling tracer? Geochim. Cosmochim. Acta 63, 4037-4051. Gislason, S.R., Oelkers, E.H., Snorrason, Á., 2006. Role of river-suspended material in the global carbon cycle. Geology 34, 49-52. Milliman, J.D., Syvitski, J.P.M., 1992. Geomorphic/tectonic control of sediment discharge to the ocean: the importance of small mountainous rivers. J. Geol. 100, 525-544. Tómasson, H., 1990. Suspended material in Icelandic rivers. In: Guttormur, S. (Ed.), Vatnid og Landid. Orkustofnun, Reykjavik, pp. 169-174.

  6. GLOBAL CHANGE RESEARCH NEWS #33: PUBLICATION OF RESEARCH AGENDA FROM UNITED STATES - CANADA SYMPOSIUM ON NORTH AMERICAN CLIMATE CHANGE AND WEATHER EXTREMES

    EPA Science Inventory

    A three-day workshop on climate variability and change and extreme weather events in North America was held in October 1999 in Atlanta, Georgia. The workshop was a bi-national effort conducted under the auspices of a United States - Canada agreement fostering cooperation on activ...

  7. Activities in Teaching Weather

    ERIC Educational Resources Information Center

    Tonn, Martin

    1977-01-01

    Presented is a unit composed of activities for teaching weather. Topics include cloud types and formation, simple weather instruments, and the weather station. Illustrations include a weather chart and instruments. A bibliography is given. (MA)

  8. IODP Expedition 354: A Bengal fan record of Himalayan erosion, weathering and organic carbon burial during the Neogene.

    NASA Astrophysics Data System (ADS)

    France-Lanord, C.; Spiess, V.; Klaus, A.; Galy, A.; Galy, V.

    2015-12-01

    The development of the Himalayan orogen induced a major change in continental distribution, topography and climate that impacted the global biogeochemical cycles. The development of the highest mountain range coupled to the intense monsoonal precipitation regime generated an intense erosional flux that enhanced both organic carbon burial and silicate weathering. The largest part of the sediment flux was exported to the Bengal Fan, accumulating a long-term archive of this erosion. These sediments record the nature of eroded formations in the Himalaya and allow the documentation of weathering as well as organic carbon fluxes. In February-March 2015, IODP Expedition 354 drilled an E-W transect in the middle fan at 8°N to investigate interactions between the growth of the Himalaya, the development of the Indian monsoon, and processes affecting the carbon cycle. This expedition obtained a comprehensive record of turbiditic deposition since the Late Oligocene. Shipboard results reveal that the chemical and mineralogical compositions of turbiditic sediments cored across the transect are relatively stable throughout the Neogene. They reveal a weak regime of chemical weathering with no significant variation through time. This differs from the distal fan record (Leg 116) where from ~7 to 1 Ma, weathered and smectite rich sediments dominated. This difference implies that the distal fan record is not related to a direct evolution of the erosion regime but rather is controlled by a change in sediment transport within the fan. Shipboard estimates of organic carbon loading and behavior resemble observations made in the modern Ganga-Brahmaputra river sediments, suggesting efficient terrestrial organic carbon burial in the Bengal Fan [1]. Preliminary observations support the idea that Himalayan erosion has consumed atmospheric CO2 through the burial of organic carbon, more than by silicate weathering. [1] http://dx.doi.org/10.1038/nature06273

  9. Deducing Weathering Processes Using Silicon Isotopes in the Ganges Alluvial Plain, India

    NASA Astrophysics Data System (ADS)

    Frings, P.; De La Rocha, C. L.; Fontorbe, G.; Chakrapani, G.; Clymans, W.; Conley, D. J.

    2014-12-01

    The Ganges Alluvial Plain ('GAP') is the sedimentary infill of the foreland basin created during Himalayan orogeny. Freshly eroded material from the Himalaya and southern cratonic tributaries is deposited into a system with long water-sediment interaction times, creating potential for further generation of river weathering fluxes. To quantify weathering processes in the GAP, 51 sites including all major tributaries were sampled in a September 2013 campaign and analysed for major and minor ions, Ge/Si ratios and δ30Si, δ13C and δ18O. Net dissolved Si (DSi) and major cation yields are 2 to 5 times lower in the GAP than the Himalaya, and at a whole basin scale approximate the global average, indicating that the plain apparently moderates the efficiency of Himalayan weathering rates. Mainstem δ30Si spans 0.81 to 1.93‰ (see figure) and gives the impression of a system buffered to moderate DSi and δ30Si. Ge/Si ratios (µmol/mol) are higher than expected in the Himalaya (>3), reflecting input of Ge-enriched water from hot springs, and decline to ~1.4 in the GAP. For the Himalayan sourced rivers, δ30Si increases with distance from the Himalayan front, and can not be explained entirely by conservative mixing with higher δ30Si peninsular and GAP streams. To a first degree, the δ30Si data suggest incorporation of Si into secondary minerals as the key fractionating process, and that this occurs both in situ during initial weathering and progressively in the GAP. Partitioning of solutes between sources is complicated in the GAP. Consistent with previous work, carbonate weathering dominates the ion fluxes, but with substantial contributions from saline/alkaline soil salts, the chlorination of wastewater and highly variable rainfall chemistry. Due to these contributions, precisely inferring the input from silicate weathering is difficult. We introduce a novel method to infer silicate-weathering rates that exploits the fractionation of Si during clay formation to account

  10. Analysis of a Sheet Silicate.

    ERIC Educational Resources Information Center

    Adams, J. M.; Evans, S.

    1980-01-01

    Describes a student project in analytical chemistry using sheet silicates. Provides specific information regarding the use of phlogopite in an experiment to analyze samples for silicon, aluminum, magnesium, iron, potassium, and fluoride. (CS)

  11. 21 CFR 172.410 - Calcium silicate.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 21 Food and Drugs 3 2010-04-01 2009-04-01 true Calcium silicate. 172.410 Section 172.410 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) FOOD FOR HUMAN... Agents § 172.410 Calcium silicate. Calcium silicate, including synthetic calcium silicate, may be...

  12. 21 CFR 172.410 - Calcium silicate.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 21 Food and Drugs 3 2012-04-01 2012-04-01 false Calcium silicate. 172.410 Section 172.410 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) FOOD FOR HUMAN... Agents § 172.410 Calcium silicate. Calcium silicate, including synthetic calcium silicate, may be...

  13. 21 CFR 172.410 - Calcium silicate.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 21 Food and Drugs 3 2014-04-01 2014-04-01 false Calcium silicate. 172.410 Section 172.410 Food and... PERMITTED FOR DIRECT ADDITION TO FOOD FOR HUMAN CONSUMPTION Anticaking Agents § 172.410 Calcium silicate. Calcium silicate, including synthetic calcium silicate, may be safely used in food in accordance with...

  14. 21 CFR 172.410 - Calcium silicate.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 21 Food and Drugs 3 2013-04-01 2013-04-01 false Calcium silicate. 172.410 Section 172.410 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) FOOD FOR HUMAN... Agents § 172.410 Calcium silicate. Calcium silicate, including synthetic calcium silicate, may be...

  15. 21 CFR 172.410 - Calcium silicate.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 21 Food and Drugs 3 2011-04-01 2011-04-01 false Calcium silicate. 172.410 Section 172.410 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) FOOD FOR HUMAN... Agents § 172.410 Calcium silicate. Calcium silicate, including synthetic calcium silicate, may be...

  16. Can enhanced weathering remove carbon dioxide from the atmosphere to prevent climate change? (Invited)

    NASA Astrophysics Data System (ADS)

    Renforth, P.; Pogge von Strandmann, P.; Henderson, G. M.

    2013-12-01

    On long timescales, silicate weathering provides the ultimate sink for CO2 released by volcanic degassing and, because the rate of such weathering is temperature dependant, this sink is thought to respond to climate change to provide a strong negative feedback stabilising Earth's climate. An increase of global weathering rates is expected in response to anthropogenic warming and this increased weathering will ultimately (on the timescale of hundreds of thousands of years) serve to remove additional CO2 and return the climate system to lower temperatures. Some have proposed that accelerating this natural process by adding ground minerals to the land surface may help to prevent climate change. However, a major challenge in assessing such a proposal is the lack of experimental kinetic data for minerals added to the environment. Here we will present results from an experiment in which a forsterite rich olivine (Mg2SiO4) was added to the top of a soil column extracted from an agricultural field. A solution was passed through the columns over a period of 5 months and the drainage waters were collected and analysed. The greater flux of Mg measured eluting from the treated soil can be used to constrain the weathering rate of the olivine. A weathering rate can be determined by normalising the rate of magnesium flux to the surface area of olivine in the soil. By combining this information with a simple shrinking core model, we can estimate that an average particle size less than 1 μm would be required in order for the olivine to completely dissolve in a year. Therefore, the energy requirements for enhanced weathering are large >2 GJ(electrical) per net tonne of CO2 sequestered, but it is at least comparable to direct air capture technologies. These preliminary results suggest limited carbon capture potential for enhanced weathering in temperate agricultural soils. However, some environments may be better suited (e.g. humid tropical agricultural soils) and additional

  17. Fate of silicate minerals in a peat bog

    USGS Publications Warehouse

    Bennett, Philip C.; Siegel, Donald I.; Hillier, Barbara M.; Glaser, Paul H.

    1991-01-01

    An investigation of silicate weathering in a Minnesota mire indicates that quartz and aluminosilicates rapidly dissolve in anoxic, organic-rich, neutral- pH environments. Vertical profiles of pH, dissolved silicon, and major cations were obtained at a raised bog and a spring fen and compared. Profiles of readily extractable silicon, diatom abundance, ash mineralogy, and silicate surface texture were determined from peat cores collected at each site.In the bog, normally a recharge mound, dissolved silicon increases with depth as pH increases, exceeding the background silicon concentration by a factor of two. Silicate grain surfaces, including quartz, are chemically etched at this location, despite being in contact with pore water at neutral pH with dissolved silicon well above the equilibrium solubility of quartz. The increasing silica concentrations at circum-neutral pH are consistent with a system where silicate solubility is influenced by silica-organic-acid complexes. Silica-organic-acid complexes therefore may be the cause of the almost complete absence of diatoms in decomposed peat and contribute to the formation of silica-depleted underclays commonly found beneath coal.

  18. Tin in silicate melts

    NASA Astrophysics Data System (ADS)

    Paparoni, Guido

    An experimental technique that uses Re metal capsules as containers for tin-bearing systems has been developed and successfully used in the study of the compositional dependence of SnO2 solubility in silicate melts. These experiments have been performed in the absence of an aqueous fluid phase and oxygen fugacity (fO2) has been established by the addition of tin-metal to SnO2. This approach solves three long-standing problems in the study of SnO 2 solubility in silicate melts: (1) Alloying of noble-metal crucibles and corrosion of ceramic crucibles is avoided; (2) fO 2 is established by direct contact of a metal-oxide oxygen buffer; (3) Gaseous SnO is not lost to the furnace atmosphere. The Re-capsule technique, combined with evacuated silica-tube experiments, has been applied to the study of the system SnO-SiO2 at pressures of 1 atm and 10 kbar. SnO2 solubilities of up to 95 wt% SnO are reported. The system SnO-SiO2 is found to be a pseudo-binary of the ternary system Sn°-SnO2-SiO2. A revised phase diagram for the system SnO-SiO2 at a pressure ≈1 atm is provided, and a new phase diagram for the system SnOSiO2 at a pressure = 10 kbar has been constructed. These results are used to suggest the topology of the ternary system Sn°-SnO2SiO2. The Re-capsule technique has also been applied to the study of the subaluminous haplogranite system (SiO2NaAlSi3O8-KAlSi 3O8) at T = 1100°C, P = 10 kbar and fO 2 at Sn°-SnO2. Solubilities span the range of 41 to 80 wt% SnO. In the haplogranite system, the solubility of SnO2 increases with the proportion of normative SiO2, and SnO is found to expand the stability field of SiO2. In the feldspar join, Na-based melts dissolve a larger proportion of SnO than K-based melts. This effect is lost as SiO2 is progressively added to the feldspar join. Small amounts of F (1 wt%) are found to increase the solubility of SnO 2 by an equivalent 15 wt% normative quartz as shown with the Spor Mountain rhyolite. A comparison of SnO2 solubilities

  19. Thermochemistry of Silicate Speciation in Aqueous Sodium Silicate Solutions: Ionization and Polymerization of Small Silicate Ion

    DTIC Science & Technology

    1993-07-12

    reasonable success, but a number of simplifications were used. For instance, the polymerization equilibrium constants were assumed to be independent of...Another weakness lies in the functionality assumed for the ionization equilibrium constants . As will be discussed below, experimental data that the free...characterize silicate species in fairly complex alkaline silicate solutions and thereby to estimate a large number of equilibrium constants [27,28

  20. Modulation of Cenozoic climate by weathering of large igneous provinces on continents drifting through equatorial humid belt

    NASA Astrophysics Data System (ADS)

    Muttoni, G.; Kent, D. V.

    2011-12-01

    The small reservoir of CO2 in the atmosphere (pCO2) that modulates climate through the greenhouse effect is a delicate balance between large fluxes of sources and sinks. The major long-term source of CO2 is global degassing from sea-floor spreading, subduction, hotspot activity, and metamorphism; the ultimate sink is through weathering of continental silicates. Most carbon cycle models are driven by changes in the source flux, in particular, variable rates of ocean floor production (and concomitant subduction) but the area/age versus age distribution of the modern ocean is compatible with a steady rate since 180 Ma (Rowley, 2002 GSA Bulletin). We previously suggested (2008 PNAS) that evidence of high pCO2 and warm climates in the Cretaceous-early Cenozoic could be explained by the subduction of Tethyan ocean crust loaded with equatorial carbonate-rich pelagic (more readily subductable) sediments since the onset of India's northward flight at ~120 Ma up until the CO2-producing decarbonation factory slowed down with collision of India and Asia at the Early Eocene Climate Optimum at 50 Ma. At about this time, the India continent and the highly weatherable Deccan Traps drifted into the equatorial humid belt where uptake of CO2 by efficient silicate weathering would further lower the level of pCO2. Continued weathering uptake was influenced by the southerly extrusion of SE Asia in response to the Indian indentor starting at ~40 Ma (Molnar & Tapponnier, 1975 Science) as well as the emplacement of the Ethiopian traps near the Equator at 30 Ma. The ongoing impingement of India into Asia and resultant southerly tectonic extrusion of SE Asia (Replumaz & Tapponnier, 2003 JGR) makes it the dominant new area in the equatorial humid belt. Moreover, SE Asia presently accounts for 25% of CO2 consumption of all basaltic provinces, which account for ~1/3 of the total consumption by continental silicate weathering (Dessert et al., 2003 Chemical Geology) that is within the range of

  1. Seafloor Weathering Dependence on Temperature and Dissolved Inorganic Carbon

    NASA Astrophysics Data System (ADS)

    Abbot, D. S.; Farahat, N. X.; Archer, D. E.

    2015-12-01

    Most thinking on Earth's carbon cycle implicates silicate weathering as the dominant control of atmospheric CO2 concentration over long timescales. Recent analyses of alteration of basalt at the seafloor, however, suggest that seafloor weathering (low-temperature (<60C) chemical alteration of the upper oceanic crust due to hydrothermal seawater circulation) increases dramatically in warm, high CO2 periods of Earth's history. This raises the possibility that seafloor weathering could complement silicate weathering in maintaining Earth's long term climate stability. Moreover, seafloor weathering would be the only type of weathering available on an exoplanet entirely covered by water, so understanding how it might work is essential for understanding the habitable zones of such waterworlds. We have built a 2D numerical model of the flow of seawater through porous basalt coupled to chemical alteration reactions that can calculate alkalinity fluxes and carbonate deposition (seafloor weathering). I will present simulations in which we vary the seawater temperature and dissolved inorganic carbon concentration, which are boundary conditions to our model, over large ranges. These results will provide a constraint on the ability of seafloor weathering to act as an effective climate buffer on Earth and other planets. I can't give you a preview of the results yet because at the time of writing this abstract we haven't completed the simulations!

  2. Cenozoic carbon cycle imbalances and a variable weathering feedback

    NASA Astrophysics Data System (ADS)

    Caves, Jeremy K.; Jost, Adam B.; Lau, Kimberly V.; Maher, Kate

    2016-09-01

    The long-term stability of Earth's climate and the recovery of the ocean-atmosphere system after carbon cycle perturbations are often attributed to a stabilizing negative feedback between silicate weathering and climate. However, evidence for the operation of this feedback over million-year timescales and in response to tectonic and long-term climatic change remains scarce. For example, the past 50 million years of the Cenozoic Era are characterized by long-term cooling and declining atmospheric CO2 (pCO2). During this interval, constant or decreasing carbon fluxes from the solid Earth to the atmosphere suggest that stable or decreasing weathering fluxes are needed to balance the carbon cycle. In contrast, marine isotopic proxies of weathering (i.e., 87Sr/86Sr, δ7 Li , and 187Os/188Os) are interpreted to reflect increasing weathering fluxes. Here, we evaluate the existence of a negative feedback by reconstructing the imbalance in the carbon cycle during the Cenozoic using the surface inventories of carbon and alkalinity. Only a sustained 0.25-0.5% increase in silicate weathering is necessary to explain the long-term decline in pCO2 over the Cenozoic. We propose that the long-term decrease in pCO2 is due to an increase in the strength of the silicate weathering feedback (i.e., the constant of proportionality between the silicate weathering flux and climate), rather than an increase in the weathering flux. This increase in the feedback strength, which mirrors the marine isotope proxies, occurs as transient, <1 million year increases in the weathering flux, which remove CO2. As runoff and temperature decline in response, the integrated weathering flux over >1 million year timescales remains invariant to match the long-term inputs of carbon. Over the Cenozoic, this results in stable long-term weathering fluxes even as pCO2 decreases. We attribute increasing feedback strength to a change in the type and reactivity of rock in the weathering zone, which collectively has

  3. Comparative pathology of silicate pneumoconiosis.

    PubMed Central

    Brambilla, C.; Abraham, J.; Brambilla, E.; Benirschke, K.; Bloor, C.

    1979-01-01

    A simple pneumoconiosis with lamellar birefringent crystals was observed in animals dying in the San Diego Zoo. We studied 100 autopsies from 11 mammalian and eight avian species. In mammals, mild pulmonary lesions comprised crystal-laden macrophages in alveoli and lymphatics. Interstitial fibrosis was present in 20% of cases. There were no nodules. In birds, dust retention produced large granulomas around tertiary bronchi without fibrosis. Mineralogic analysis using scanning and transmission electron microscopy showed most of the crystals to be silicates. Ninety percent were complex silicates, with aluminum-potassium silicates comprising 70% of the analyzed particles. Electron and x-ray diffraction showed the silicates to be muscovite mica and its hydrothermal degradation product, ie, illite clay. This mica was also present on filtration membranes of atmospheric air samples obtained from the San Diego Zoo. The amount of dust retention was related to the animal's age, anatomic or ecologic variances, and length of stay in the San Diego Zoo. Its semidesert atmosphere is rich in silicates, which are inhaled and deposited in the lungs. Similar mica-induced lesions are found in humans living in this region or the Southwest of the USA. This simple pneumoconiosis is likely to be widespread in human populations living in desert or semidesert climates. Images Figure 9 Figure 10 Figure 7 Figure 8 Figure 5 Figure 6 Figure 1 Figure 2 Figure 3 Figure 4 PMID:223447

  4. Chemical and Physical Weathering in a Hot-arid, Tectonically Active Alluvial System (Anza-Borrego Desert, CA)

    NASA Astrophysics Data System (ADS)

    Joo, Y. J.; Elwood Madden, M.; Soreghan, G. S.

    2014-12-01

    Climate and tectonics are primary controls on bedrock erosion, and sediment production, transport, and deposition. Additionally, silicate weathering in tectonically active regions is known to play a significant role in global climate owing to the high rates of physical erosion and exposure of unweathered bedrock to chemical weathering, which removes CO2 from the atmosphere. Therefore, the feedback between weathering and climate is key to understanding climate change through Earth history. This study investigates chemical and physical weathering of alluvial sediments in the Anza-Borrego Desert, California, located in the southern part of the San Andreas Fault System. This setting provides an ideal opportunity to study weathering in a hot and arid climate with mean annual temperatures of ~23 °C and mean annual precipitation of ~160 mm in the basin. Samples were collected along a proximal-to-distal transect of an alluvial-fan system sourced exclusively from Cretaceous tonalite of the Peninsular Range. The single bedrock lithology enables exploration of the effects of other variables — climate, transport distance, drainage area, and tectonics— on the physical and chemical properties of the sediments. Although minimal overall (CIA = 56-61), the degree of chemical weathering increases down transect, dominated by plagioclase dissolution. BET surface area of the mud (<63µm) fraction decreases distally, which is consistent with coarsening grain-size. Chemical alteration and BET surface area both increase in a distal region, within the active Elsinore Fault zone. Extensive fracturing here, together with a more-humid Pleistocene climate likely facilitated in-situ bedrock weathering; specifically, dissolution of primary minerals (e.g. plagioclase), preceding the arid alluvial erosion, transport, and deposition in the Holocene. This study further seeks to disentangle the complex record of the climate and tectonic signals imprinted in these sediments.

  5. Using WITCH to determine the factors that govern shale weathering and solute fluxes in the Critical Zone

    NASA Astrophysics Data System (ADS)

    Sullivan, P. L.; Godderis, Y.; Shi, Y.; Gu, X.; Schott, J.; Duffy, C.; Brantley, S. L.

    2015-12-01

    Quantifying the effects of climate and biota on silicate and carbonate mineral weathering rates is crucial for predicting regolith formation and global weathering fluxes. Recent efforts demonstrate that geochemical, vegetation and climate models can be linked to understand the controls on solute fluxes in the critical zone. These efforts also elucidate field weathering rates and mineralogical evolution. To investigate the controls on shale weathering and solute flux, we developed a baseline shale weathering and solute flux model utilizing field observations from the Susquehanna Shale Hills Critical Zone Observatory (SSHCZO). Our modeling approach linked the physically-based land surface hydrologic model, Flux-PIHM (Penn State Integrated Hydrologic Model), to the numerical chemical weathering model WITCH. We are progressively testing the importance of mineral reactive surface area, aspect, clay thermodynamic constants, and vegetation cycling (uptake and decomposition) on soil water solute fluxes. Under baseline conditions, WITCH simulated the range in soil water Mg2+ concentrations observed on the sun-facing hillslope but slightly underestimated the concentrations observed on the shaded slope. The baseline WITCH modeling suggests Mg2+ solute concentrations are primarily controlled by clay weathering but that Ca2+, K+, Na+ and Si are driven by other critical zone processes. The inclusion of aspect resulted in lower recharge rates on the sun-facing side because ET was higher on that side. This in turn also resulted in lower soil water solute concentrations on the shaded hillslope. Cooler temperatures on that side also reduced the simulated chlorite and illite dissolution rates. When a vegetation cycling module was incorporated in WITCH, the simulation reproduced the range in Ca2+, K+, and Si concentrations in soil waters as observed in the field for both hillslopes. Modeling results suggest the inclusion of aspect and vegetation cycling are key in simulating soils

  6. Leaching and reconstruction at the surfaces of dissolving chain-silicate minerals

    NASA Astrophysics Data System (ADS)

    Casey, William H.; Westrich, Henry R.; Banfield, Jillian F.; Ferruzzi, Giulio; Arnold, Geroge W.

    1993-11-01

    THE pathways by which silicate minerals transform to solutes, clays and amorphous solids are relevant to a wide range of natural, industrial and even medical concerns. For example, weathered layers on silicate may have a high sorptive capacity, affecting nutrient and contamination retention in soils; less obviously, such layers on inhaled silicate grains might affect their interaction with lung tissue. Here we report the observation, in dissolution experiments on a range of chain-silicate minerals, of the formation of a near-surface amorphous region enriched in silicon and hydrogen, and depleted in other metals. Raman spectroscopy and ion-beam elemental analysis show that portions of the polymeric silicate anion in this region spontaneously reconstruct to form a network that contains four-member silicate rings and areas of incipient crystallization. If hydrolysable metals interact with the silicate anion during this reconstruction, clays and amorphous products may form directly. This process complements traditional dissolution-precipitation pathways of mineral diagenesis1, as the silicon does not have to be present in solution before being incorporated into a growing secondary phase.

  7. The rise and fall of continental arcs: Interplays between magmatism, uplift, weathering, and climate

    NASA Astrophysics Data System (ADS)

    Lee, Cin-Ty A.; Thurner, Sally; Paterson, Scott; Cao, Wenrong

    2015-09-01

    high and continued to erode and weather well after (>50 My) the end of magmatism. Thus, in the aftermath of a global continental arc flare-up, both the total volcanic inputs of CO2 decline and the average weatherability of continents increases, the latter due to the increased proportion of widespread remnant topography available for weathering and erosion. This combination leads to a decrease in the long-term baseline of carbon in the ocean/atmosphere system, leading to cooling. Mid-Cenozoic cooling is often attributed solely to increased weathering rates associated with India-Eurasian collision and the Himalayan orogeny. However, the total area of now-extinct Cretaceous-Paleogene continental arcs is 1.3-2 times larger than that of the Himalayan range front and the Tibetan plateau combined, suggesting that weathering of these remnant volcanic arcs may also play a role in drawing down CO2 through silicate weathering and subsequent carbonate burial. In summary, if global continental arc flare-ups lead to greenhouse conditions, long-lived icehouse conditions should follow in the aftermath due to decreased CO2 inputs and an increase in regional weathering efficiency of remnant arc topography.

  8. Final report on the safety assessment of aluminum silicate, calcium silicate, magnesium aluminum silicate, magnesium silicate, magnesium trisilicate, sodium magnesium silicate, zirconium silicate, attapulgite, bentonite, Fuller's earth, hectorite, kaolin, lithium magnesium silicate, lithium magnesium sodium silicate, montmorillonite, pyrophyllite, and zeolite.

    PubMed

    Elmore, Amy R

    2003-01-01

    This report reviews the safety of Aluminum, Calcium, Lithium Magnesium, Lithium Magnesium Sodium, Magnesium Aluminum, Magnesium, Sodium Magnesium, and Zirconium Silicates, Magnesium Trisilicate, Attapulgite, Bentonite, Fuller's Earth, Hectorite, Kaolin, Montmorillonite, Pyrophyllite, and Zeolite as used in cosmetic formulations. The common aspect of all these claylike ingredients is that they contain silicon, oxygen, and one or more metals. Many silicates occur naturally and are mined; yet others are produced synthetically. Typical cosmetic uses of silicates include abrasive, opacifying agent, viscosity-increasing agent, anticaking agent, emulsion stabilizer, binder, and suspending agent. Clay silicates (silicates containing water in their structure) primarily function as adsorbents, opacifiers, and viscosity-increasing agents. Pyrophyllite is also used as a colorant. The International Agency for Research on Cancer has ruled Attapulgite fibers >5 microm as possibly carcinogenic to humans, but fibers <5 microm were not classified as to their carcinogenicity to humans. Likewise, Clinoptilolite, Phillipsite, Mordenite, Nonfibrous Japanese Zeolite, and synthetic Zeolites were not classified as to their carcinogenicity to humans. These ingredients are not significantly toxic in oral acute or short-term oral or parenteral toxicity studies in animals. Inhalation toxicity, however, is readily demonstrated in animals. Particle size, fibrogenicity, concentration, and mineral composition had the greatest effect on toxicity. Larger particle size and longer and wider fibers cause more adverse effects. Magnesium Aluminum Silicate was a weak primary skin irritant in rabbits and had no cumulative skin irritation in guinea pigs. No gross effects were reported in any of these studies. Sodium Magnesium Silicate had no primary skin irritation in rabbits and had no cumulative skin irritation in guinea pigs. Hectorite was nonirritating to the skin of rabbits in a Draize primary skin

  9. Photochemical weathering and contemporary volatile loss on Mars

    NASA Technical Reports Server (NTRS)

    Huguenin, R. L.

    1987-01-01

    In an earlier series of papers by the author it was proposed that photochemical weathering of Fe(2+) in magnetite and in mafic silicates may be occurring in the contemporary surface environment with a resultant loss of O2 from the atmosphere. Morris and Lauer challenged the photochemical weathering model, proposing that oxidation by radiant heating rather than UV photoelectron emission induced oxidation may have dominated in the authors experiments. Subsequent laboratory studies of photochemical weathering of magnetite described here support the authors original proposal that UV illunimation can indeed drive the oxidation of magnetite under contemporary Martian surface conditions. The negative results of the Morris and Lauer study can now be explained.

  10. Forecasting the Weather.

    ERIC Educational Resources Information Center

    Bollinger, Richard

    1984-01-01

    Presents a computer program which predicts the weather based on student input of such weather data as wind direction and barometric pressure. Also provides procedures for several hands-on, weather-related activities. (JN)

  11. Weather in the News.

    ERIC Educational Resources Information Center

    Markle, Sandra

    1989-01-01

    A discussion of TV weather forecasting introduces this article which features several hands-on science activities involving observing, researching, and experimenting with the weather. A reproducible worksheet on the reliability of weather forecasts is included. (IAH)

  12. A Quantitative Geochemical, Mineralogical and Physical Study of Some Selected Rock Weathering Profiles from Brazil

    DTIC Science & Technology

    1977-08-17

    weather to gibbsite (plus or minus iron oxides) in well-drained, and smectite in poorly-drained, environments. Kaolinite found in the vicinity of quartz...rock and completely weathered saprolite. Quartz-rich rock types exhibit wide, gradational weathered zones and usually form kaolinite or halloysite in...free rocks is either formed by re-silication of gibbsite , or is of secondary origin (transported). Texture of the rock (aphanitic vs. phaneric) has

  13. Battery components employing a silicate binder

    DOEpatents

    Delnick, Frank M.; Reinhardt, Frederick W.; Odinek, Judy G.

    2011-05-24

    A battery component structure employing inorganic-silicate binders. In some embodiments, casting or coating of components may be performed using aqueous slurries of silicates and electrode materials or separator materials.

  14. Circumstellar Crystalline Silicates: Evolved Stars

    NASA Astrophysics Data System (ADS)

    Tartar, Josh; Speck, A. K.

    2008-05-01

    One of the most exciting developments in astronomy in the last 15 years was the discovery of crystalline silicate stardust by the Short Wavelength Spectrometer (SWS) on board of ISO; discovery of the crystalline grains was indeed one of the biggest surprises of the ISO mission. Initially discovered around AGB stars (evolved stars in the range of 0.8 > M/M¤>8) at far-infrared (IR) wavelengths, crystalline silicates have since been seen in many astrophysical environments including young stellar objects (T Tauri and Herbig Ae/Be), comets and Ultra Luminous Infrared Galaxies. Low and intermediate mass stars (LIMS) comprise 95% of the contributors to the ISM, so study of the formation of crystalline silicates is critical to our understanding of the ISM, which is thought to be primarily amorphous (one would expect an almost exact match between the composition of AGB dust shells and the dust in the ISM). Whether the crystalline dust is merely undetectable or amorphized remains a mystery. The FORCAST instrument on SOFIA as well as the PACS instrument on Herschel will provide exciting observing opportunities for the further study of crystalline silicates.

  15. Amended Silicated for Mercury Control

    SciTech Connect

    James Butz; Thomas Broderick; Craig Turchi

    2006-12-31

    Amended Silicates{trademark}, a powdered, noncarbon mercury-control sorbent, was tested at Duke Energy's Miami Fort Station, Unit 6 during the first quarter of 2006. Unit 6 is a 175-MW boiler with a cold-side electrostatic precipitator (ESP). The plant burns run-of-the-river eastern bituminous coal with typical ash contents ranging from 8-15% and sulfur contents from 1.6-2.6% on an as-received basis. The performance of the Amended Silicates sorbent was compared with that for powdered activated carbon (PAC). The trial began with a period of baseline monitoring during which no sorbent was injected. Sampling during this and subsequent periods indicated mercury capture by the native fly ash was less than 10%. After the baseline period, Amended Silicates sorbent was injected at several different ratios, followed by a 30-day trial at a fixed injection ratio of 5-6 lb/MMACF. After this period, PAC was injected to provide a comparison. Approximately 40% mercury control was achieved for both the Amended Silicates sorbent and PAC at injection ratios of 5-6 lbs/MMACF. Higher injection ratios did not achieve significantly increased removal. Similar removal efficiencies have been reported for PAC injection trials at other plants with cold-side ESPs, most notably for plants using medium to high sulfur coal. Sorbent injection did not detrimentally impact plant operations and testing confirmed that the use of Amended Silicates sorbent does not degrade fly ash quality (unlike PAC). The cost for mercury control using either PAC or Amended Silicates sorbent was estimated to be equivalent if fly ash sales are not a consideration. However, if the plant did sell fly ash, the effective cost for mercury control could more than double if those sales were no longer possible, due to lost by-product sales and additional cost for waste disposal. Accordingly, the use of Amended Silicates sorbent could reduce the overall cost of mercury control by 50% or more versus PAC for locations where fly

  16. Geochemical investigation of weathering processes in a forested headwater catchment: Mass-balance weathering fluxes

    USGS Publications Warehouse

    Jones, B.F.; Herman, J.S.

    2008-01-01

    Geochemical research on natural weathering has often been directed towards explanations of the chemical composition of surface water and ground water resulting from subsurface water-rock interactions. These interactions are often defined as the incongruent dissolution of primary silicates, such as feldspar, producing secondary weathering products, such as clay minerals and oxyhydroxides, and solute fluxes (Meunier and Velde, 1979). The chemical composition of the clay-mineral product is often ignored. However, in earlier investigations, the saprolitic weathering profile at the South Fork Brokenback Run (SFBR) watershed, Shenandoah National Park, Virginia, was characterized extensively in terms of its mineralogical and chemical composition (Piccoli, 1987; Pochatila et al., 2006; Jones et al., 2007) and its basic hydrology. O'Brien et al. (1997) attempted to determine the contribution of primary mineral weathering to observed stream chemistry at SFBR. Mass-balance model results, however, could provide only a rough estimate of the weathering reactions because idealized mineral compositions were utilized in the calculations. Making use of detailed information on the mineral occurrence in the regolith, the objective of the present study was to evaluate the effects of compositional variation on mineral-solute mass-balance modelling and to generate plausible quantitative weathering reactions that support both the chemical evolution of the surface water and ground water in the catchment, as well as the mineralogical evolution of the weathering profile. ?? 2008 The Mineralogical Society.

  17. 21 CFR 582.2227 - Calcium silicate.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 21 Food and Drugs 6 2013-04-01 2013-04-01 false Calcium silicate. 582.2227 Section 582.2227 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) ANIMAL... Calcium silicate. (a) Product. Calcium silicate. (b) Tolerance. 2 percent and 5 percent. (c)...

  18. 21 CFR 182.2227 - Calcium silicate.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 21 Food and Drugs 3 2013-04-01 2013-04-01 false Calcium silicate. 182.2227 Section 182.2227 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) FOOD FOR... Calcium silicate. (a) Product. Calcium silicate. (b) Tolerance. 2 percent and 5 percent. (c)...

  19. 21 CFR 182.2227 - Calcium silicate.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 21 Food and Drugs 3 2012-04-01 2012-04-01 false Calcium silicate. 182.2227 Section 182.2227 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) FOOD FOR... Calcium silicate. (a) Product. Calcium silicate. (b) Tolerance. 2 percent and 5 percent. (c)...

  20. 21 CFR 182.2227 - Calcium silicate.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 21 Food and Drugs 3 2011-04-01 2011-04-01 false Calcium silicate. 182.2227 Section 182.2227 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) FOOD FOR... Calcium silicate. (a) Product. Calcium silicate. (b) Tolerance. 2 percent and 5 percent. (c)...

  1. 21 CFR 182.2227 - Calcium silicate.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 21 Food and Drugs 3 2010-04-01 2009-04-01 true Calcium silicate. 182.2227 Section 182.2227 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) FOOD FOR... Calcium silicate. (a) Product. Calcium silicate. (b) Tolerance. 2 percent and 5 percent. (c)...

  2. 21 CFR 582.2227 - Calcium silicate.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 21 Food and Drugs 6 2012-04-01 2012-04-01 false Calcium silicate. 582.2227 Section 582.2227 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) ANIMAL... Calcium silicate. (a) Product. Calcium silicate. (b) Tolerance. 2 percent and 5 percent. (c)...

  3. 21 CFR 582.2227 - Calcium silicate.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 21 Food and Drugs 6 2014-04-01 2014-04-01 false Calcium silicate. 582.2227 Section 582.2227 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) ANIMAL... Calcium silicate. (a) Product. Calcium silicate. (b) Tolerance. 2 percent and 5 percent. (c)...

  4. 21 CFR 582.2227 - Calcium silicate.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 21 Food and Drugs 6 2010-04-01 2010-04-01 false Calcium silicate. 582.2227 Section 582.2227 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) ANIMAL... Calcium silicate. (a) Product. Calcium silicate. (b) Tolerance. 2 percent and 5 percent. (c)...

  5. 21 CFR 582.2227 - Calcium silicate.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 21 Food and Drugs 6 2011-04-01 2011-04-01 false Calcium silicate. 582.2227 Section 582.2227 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) ANIMAL... Calcium silicate. (a) Product. Calcium silicate. (b) Tolerance. 2 percent and 5 percent. (c)...

  6. 21 CFR 182.2437 - Magnesium silicate.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 21 Food and Drugs 3 2013-04-01 2013-04-01 false Magnesium silicate. 182.2437 Section 182.2437 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) FOOD FOR... Magnesium silicate. (a) Product. Magnesium silicate. (b) Tolerance. 2 percent. (c) Limitations,...

  7. 21 CFR 182.2437 - Magnesium silicate.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 21 Food and Drugs 3 2010-04-01 2009-04-01 true Magnesium silicate. 182.2437 Section 182.2437 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) FOOD FOR... Magnesium silicate. (a) Product. Magnesium silicate. (b) Tolerance. 2 percent. (c) Limitations,...

  8. 21 CFR 582.2437 - Magnesium silicate.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 21 Food and Drugs 6 2012-04-01 2012-04-01 false Magnesium silicate. 582.2437 Section 582.2437 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) ANIMAL... Magnesium silicate. (a) Product. Magnesium silicate. (b) Tolerance. 2 percent. (c) Limitations,...

  9. 21 CFR 582.2437 - Magnesium silicate.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 21 Food and Drugs 6 2014-04-01 2014-04-01 false Magnesium silicate. 582.2437 Section 582.2437 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) ANIMAL... Magnesium silicate. (a) Product. Magnesium silicate. (b) Tolerance. 2 percent. (c) Limitations,...

  10. 21 CFR 582.2437 - Magnesium silicate.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 21 Food and Drugs 6 2011-04-01 2011-04-01 false Magnesium silicate. 582.2437 Section 582.2437 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) ANIMAL... Magnesium silicate. (a) Product. Magnesium silicate. (b) Tolerance. 2 percent. (c) Limitations,...

  11. 21 CFR 182.2437 - Magnesium silicate.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 21 Food and Drugs 3 2011-04-01 2011-04-01 false Magnesium silicate. 182.2437 Section 182.2437 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) FOOD FOR... Magnesium silicate. (a) Product. Magnesium silicate. (b) Tolerance. 2 percent. (c) Limitations,...

  12. 21 CFR 182.2437 - Magnesium silicate.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 21 Food and Drugs 3 2012-04-01 2012-04-01 false Magnesium silicate. 182.2437 Section 182.2437 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) FOOD FOR... Magnesium silicate. (a) Product. Magnesium silicate. (b) Tolerance. 2 percent. (c) Limitations,...

  13. 21 CFR 582.2437 - Magnesium silicate.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 21 Food and Drugs 6 2010-04-01 2010-04-01 false Magnesium silicate. 582.2437 Section 582.2437 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) ANIMAL... Magnesium silicate. (a) Product. Magnesium silicate. (b) Tolerance. 2 percent. (c) Limitations,...

  14. 21 CFR 582.2437 - Magnesium silicate.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 21 Food and Drugs 6 2013-04-01 2013-04-01 false Magnesium silicate. 582.2437 Section 582.2437 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) ANIMAL... Magnesium silicate. (a) Product. Magnesium silicate. (b) Tolerance. 2 percent. (c) Limitations,...

  15. A Century of Monitoring Weather and Crops: The Weekly Weather and Crop Bulletin.

    NASA Astrophysics Data System (ADS)

    Heddinghaus, Thomas R.; Le Comte, Douglas M.

    1992-02-01

    Publication of a national weekly weather summary called the Weekly Weather Chronicle began in 1872. This summary was the precursor of today's Weekly Weather and Crop Bulletin (WWCB), a publication that reports global weather and climate conditions relevant to agricultural interests, as well as current national activities and assessments of crop and livestock conditions. The WWCB is produced by the Joint Agricultural Weather Facility (JAWF), a world agricultural weather information center located in the U.S. Department of Agriculture (USDA) headquarters in Washington, D.C., and jointly staffed by units of the National Oceanic and Atmospheric Administration's Climats. Analysis Center and USDA's World Agricultural Outlook Board and National Agricultural Statistics Service. Besides featuring charts and tables (e.g., temperature and precipitation maps and crop progress and condition tables), the WWCB contains summaries and special stories highlighting significant weather events affecting agriculture, such as droughts, torrential rains, floods, unusual warmth, heat waves, severe freezes, heavy snowfall, blizzards, damaging storms, and hurricanes.

  16. Dehydroxylated clay silicates on Mars: Riddles about the Martian regolith solved with ferrian saponites

    NASA Technical Reports Server (NTRS)

    Burns, Roger G.

    1992-01-01

    Clay silicates, resulting from the chemical weathering of volcanic glasses and basaltic rocks of Mars, are generally believed to be major constituents of the martian regolith and atmospheric dust. Because little attention has been given to the role, if any, of Mg-bearing clay silicates on the martian surface, the crystal chemistry, stability, and reactivity of Mg-Fe smectites are examined. Partially dehydroxylated ferrian saponites are suggested to be major constituents of the surface of Mars, regulating several properties of the regolith.

  17. Lithological influences on contemporary and long-term regolith weathering at the Luquillo Critical Zone Observatory

    USGS Publications Warehouse

    Buss, Heather L.; Lara, Maria Chapela; Moore, Oliver; Kurtz, Andrew C.; Schulz, Marjorie S.; White, Arthur F.

    2017-01-01

    Lithologic differences give rise to the differential weatherability of the Earth’s surface and globally variable silicate weathering fluxes, which provide an important negative feedback on climate over geologic timescales. To isolate the influence of lithology on weathering rates and mechanisms, we compare two nearby catchments in the Luquillo Critical Zone Observatory in Puerto Rico, which have similar climate history, relief and vegetation, but differ in bedrock lithology. Regolith and pore water samples with depth were collected from two ridgetops and at three sites along a slope transect in the volcaniclastic Bisley catchment and compared to existing data from the granitic Río Icacos catchment. The depth variations of solid-state and pore water chemistry and quantitative mineralogy were used to calculate mass transfer (tau) and weathering solute profiles, which in turn were used to determine weathering mechanisms and to estimate weathering rates.Regolith formed on both lithologies is highly leached of most labile elements, although Mg and K are less depleted in the granitic than in the volcaniclastic profiles, reflecting residual biotite in the granitic regolith not present in the volcaniclastics. Profiles of both lithologies that terminate at bedrock corestones are less weathered at depth, near the rock-regolith interfaces. Mg fluxes in the volcaniclastics derive primarily from dissolution of chlorite near the rock-regolith interface and from dissolution of illite and secondary phases in the upper regolith, whereas in the granitic profile, Mg and K fluxes derive from biotite dissolution. Long-term mineral dissolution rates and weathering fluxes were determined by integrating mass losses over the thickness of solid-state weathering fronts, and are therefore averages over the timescale of regolith development. Resulting long-term dissolution rates for minerals in the volcaniclastic regolith include chlorite: 8.9 × 10−14 mol m−2 s−1, illite: 2.1

  18. Lithological influences on contemporary and long-term regolith weathering at the Luquillo Critical Zone Observatory

    NASA Astrophysics Data System (ADS)

    Buss, Heather L.; Chapela Lara, María; Moore, Oliver W.; Kurtz, Andrew C.; Schulz, Marjorie S.; White, Art F.

    2017-01-01

    Lithologic differences give rise to the differential weatherability of the Earth's surface and globally variable silicate weathering fluxes, which provide an important negative feedback on climate over geologic timescales. To isolate the influence of lithology on weathering rates and mechanisms, we compare two nearby catchments in the Luquillo Critical Zone Observatory in Puerto Rico, which have similar climate history, relief and vegetation, but differ in bedrock lithology. Regolith and pore water samples with depth were collected from two ridgetops and at three sites along a slope transect in the volcaniclastic Bisley catchment and compared to existing data from the granitic Río Icacos catchment. The depth variations of solid-state and pore water chemistry and quantitative mineralogy were used to calculate mass transfer (tau) and weathering solute profiles, which in turn were used to determine weathering mechanisms and to estimate weathering rates. Regolith formed on both lithologies is highly leached of most labile elements, although Mg and K are less depleted in the granitic than in the volcaniclastic profiles, reflecting residual biotite in the granitic regolith not present in the volcaniclastics. Profiles of both lithologies that terminate at bedrock corestones are less weathered at depth, near the rock-regolith interfaces. Mg fluxes in the volcaniclastics derive primarily from dissolution of chlorite near the rock-regolith interface and from dissolution of illite and secondary phases in the upper regolith, whereas in the granitic profile, Mg and K fluxes derive from biotite dissolution. Long-term mineral dissolution rates and weathering fluxes were determined by integrating mass losses over the thickness of solid-state weathering fronts, and are therefore averages over the timescale of regolith development. Resulting long-term dissolution rates for minerals in the volcaniclastic regolith include chlorite: 8.9 × 10-14 mol m-2 s-1, illite: 2.1 × 10-14 mol m

  19. Iron-magnesium silicate bioweathering on Earth (and Mars?).

    PubMed

    Fisk, M R; Popa, R; Mason, O U; Storrie-Lombardi, M C; Vicenzi, E P

    2006-02-01

    We examined the common, iron-magnesium silicate minerals olivine and pyroxene in basalt and in mantle rocks to determine if they exhibit textures similar to bioweathering textures found in glass. Our results show that weathering in olivine may occur as long, narrow tunnels (1-3 microm in diameter and up to 100 microm long) and as larger irregular galleries, both of which have distinctive characteristics consistent with biological activity. These weathering textures are associated with clay mineral by-products and nucleic acids. We also examined olivine and pyroxene in martian meteorites, some of which experienced preterrestrial aqueous alteration. Some olivines and pyroxenes in the martian meteorite Nakhla were found to contain tunnels that are similar in size and shape to tunnels in terrestrial iron-magnesium silicates that contain nucleic acids. Though the tunnels found in Nakhla are similar to the biosignatures found in terrestrial minerals, their presence cannot be used to prove that the martian alteration features had a biogenic origin. The abundance and wide distribution of olivine and pyroxene on Earth and in the Solar System make bioweathering features in these minerals potentially important new biosignatures that may play a significant role in evaluating whether life ever existed on Mars.

  20. Teaching Weather Concepts.

    ERIC Educational Resources Information Center

    Sebastian, Glenn R.

    Ten exercises based on the weather map provided in the national newspaper "U.S.A. Today" are used to teach intermediate grade students about weather. An overview describes the history of "U.S.A. Today," the format of the newspaper's weather map, and the map's suitability for teaching weather concepts. Specific exercises, which are briefly…

  1. Fun with Weather

    ERIC Educational Resources Information Center

    Yildirim, Rana

    2007-01-01

    This three-part weather-themed lesson for young learners connects weather, clothing, and feelings vocabulary. The target structures covered are: asking about the weather; comparing weather; using the modal auxiliary, should; and the question word, when. The lessons utilize all four skills and include such activities as going outside, singing,…

  2. Weather in Your Life.

    ERIC Educational Resources Information Center

    Kannegieter, Sandy; Wirkler, Linda

    Facts and activities related to weather and meteorology are presented in this unit. Separate sections cover the following topics: (1) the water cycle; (2) clouds; (3) the Beaufort Scale for rating the speed and force of wind; (4) the barometer; (5) weather prediction; (6) fall weather in Iowa (sleet, frost, and fog); (7) winter weather in Iowa…

  3. Development and initial application of the global-through-urban weather research and forecasting model with chemistry (GU-WRF/Chem)

    NASA Astrophysics Data System (ADS)

    Zhang, Yang; Karamchandani, Prakash; Glotfelty, Timothy; Streets, David G.; Grell, Georg; Nenes, Athanasios; Yu, Fangqun; Bennartz, Ralf

    2012-10-01

    A unified model framework with online-coupled meteorology and chemistry and consistent model treatments across spatial scales is required to realistically simulate chemistry-aerosol-cloud-radiation-precipitation-climate interactions. In this work, a global-through-urban WRF/Chem model (i.e., GU-WRF/Chem) has been developed to provide such a unified model framework to simulate these important interactions across a wide range of spatial scales while reducing uncertainties from the use of offline-coupled model systems with inconsistent model treatments. Evaluation against available observations shows that GU-WRF/Chem is capable of reproducing observations with comparable or superior fidelity than existing mesoscale models. The net effect of atmospheric aerosols is to decrease shortwave and longwave radiation, NO2photolysis rate, near-surface temperature, wind speed at 10-m, planetary boundary layer height, and precipitation as well as to increase relative humidity at 2-m, aerosol optical depths, column cloud condensation nuclei, cloud optical thickness, and cloud droplet number concentrations at all scales. As expected, such feedbacks also change the abundance and lifetimes of chemical species through changing radiation, atmospheric stability, and the rates of many meteorologically-dependent chemical and microphysical processes. The use of higher resolutions in progressively nested domains from the global to local scale notably improves the model performance of some model predictions (especially for chemical predictions) and also captures spatial variability of aerosol feedbacks that cannot be simulated at a coarser grid resolution. Simulated aerosol, radiation, and cloud properties exhibit small-to-high sensitivity to various nucleation and aerosol activation parameterizations. Representing one of the few unified global-through-urban models, GU-WRF/Chem can be applied to simulate air quality and its interactions with meteorology and climate and to quantify the impact

  4. Cometary Silicates: Interstellar and Nebular Materials

    NASA Technical Reports Server (NTRS)

    Wooden, Diane H.

    2002-01-01

    Evidence for interstellar material in comets is deduced from IR spectra, insitu measurements of Halley, and chondritic porous interplanetary dust particles (CP IDPs). IR spectra of comets reveal the spectrally active minerals: amorphous carbon, amorphous silicates, and (in some comets) crystalline silicates. Evidence suggests amorphous silicates are of interstellar origin while crystalline silicates are of nebular origin. 10 microns spectra of comets and submicron amorphous silicate spherules in CP IDPs have shapes similar to lines-of-sight through the ISM. Thermal emission models of cometary IR spectra require Fe-bearing amorphous silicates. Fe-bearing amorphous silicates may be Fe-bearing crystalline silicates formed in AGB outflows that are amorphized through He+ ion bombardment in supernova shocks in the ISM. Crystalline silicates in comets, as revealed by IR spectra, and their apparent absence in the ISM, argues for their nebular origin. The high temperatures (less than l000 K) at which crystals form or are annealed occur in the inner nebula or in nebular shocks in the 5-10 AU region. Oxygen isotope studies of CP IDPs show by mass only 1 % of the silicate crystals are of AGB origin. Together this suggests crystalline silicates in comets are probably primitive grains from the early solar nebula.

  5. Potential for Increased Assimilation of Snpp Data Via Direct Readout to Hourly-Updated Global/Regional Numerical Weather Prediction Models for Situational Awareness

    NASA Astrophysics Data System (ADS)

    Benjamin, S.; Lin, H.; Weygandt, S.; Hu, M.; Alexander, C.

    2014-12-01

    Smaller data latency through direct readout will be crucial for hourly updated regional operational models run currently (e.g., NOAA Rapid Refresh (RAP) and 3-km HRRR) and also for future global hourly updated models. Most polar orbiter radiance data are not currently meeting data cut-off availability requirements (~30 minutes) for the current NOAA RAP model. Modest improvement in overall RAP forecast skill is available with full polar-orbiter data availability if data latency was smaller (Lin et al. 2015 a,b) To some extent, this is addressed through "partial cycling" catch-up cycles in RAP, but partial cycling requires parallel NWP cycles and use of more computer resources. Better satellite data coverage (enhanced with reduced data latency) improves forecast skill not only through direct use of more data over more geographic areas but also through improved bias correction leading to more effective use of observations and less data rejection. Increased use of hourly updated models (RAP and HRRR) is clearly occurring for improved decision making. RARS (Regional ATOVS Retransmission Services) is a precursor to full direct readout availability. Initial development toward a global rapid refresh capability now underway and smaller satellite data latency will be critical for successful demonstration of 3h and 1h global updating.

  6. Surface characterization of silicate bioceramics.

    PubMed

    Cerruti, Marta

    2012-03-28

    The success of an implanted prosthetic material is determined by the early events occurring at the interface between the material and the body. These events depend on many surface properties, with the main ones including the surface's composition, porosity, roughness, topography, charge, functional groups and exposed area. This review will portray how our understanding of the surface reactivity of silicate bioceramics has emerged and evolved in the past four decades, owing to the adoption of many complementary surface characterization tools. The review is organized in sections dedicated to a specific surface property, each describing how the property influences the body's response to the material, and the tools that have been adopted to analyse it. The final section introduces the techniques that have yet to be applied extensively to silicate bioceramics, and the information that they could provide.

  7. The mid-Cretaceous super plume, carbon dioxide, and global warming.

    PubMed

    Caldeira, K; Rampino, M R

    1991-06-01

    Carbon-dioxide releases associated with a mid-Cretaceous super plume and the emplacement of the Ontong-Java Plateau have been suggested as a principal cause of the mid-Cretaceous global warming. We developed a carbonate-silicate cycle model to quantify the possible climatic effects of these CO2 releases, utilizing four different formulations for the rate of silicate-rock weathering as a function of atmospheric CO2. We find that CO2 emissions resulting from super-plume tectonics could have produced atmospheric CO2 levels from 3.7 to 14.7 times the modern pre-industrial value of 285 ppm. Based on the temperature sensitivity to CO2 increases used in the weathering-rate formulations, this would cause a global warming of from 2.8 to 7.7 degrees C over today's global mean temperature. Altered continental positions and higher sea level may have been contributed about 4.8 degrees C to mid-Cretaceous warming. Thus, the combined effects of paleogeographic changes and super-plume related CO2 emissions could be in the range of 7.6 to 12.5 degrees C, within the 6 to 14 degrees C range previously estimated for mid-Cretaceous warming. CO2 releases from oceanic plateaus alone are unlikely to have been directly responsible for more than 20% of the mid-Cretaceous increase in atmospheric CO2.

  8. The mid-Cretaceous super plume, carbon dioxide, and global warming

    SciTech Connect

    Caldeira, K. ); Rampino, M.R. NASA Goddard Inst. for Space Studies, New York, NY )

    1991-06-01

    Carbon-dioxide releases associated with a mid-Cretaceous super plume and the emplacement of the Ontong-Java Plateau have been suggested as a principal cause of the mid-Cretaceous global warming. The authors developed a carbonate-silicate cycle model to quantify the possible climatic effects of these CO{sub 2} releases, utilizing four different formulations for the rate of silicate-rock weathering as a function of atmospheric CO{sub 2}. They find that CO{sub 2} emissions resulting from super-plume tectonics could have produced atmospheric CO{sub 2} levels from 3.7 to 14.7 times the modern pre-industrial value of 285 ppm. Based on the temperature sensitivity to CO{sub 2} increases used in the weathering-rate formulations, this would cause a global warming of from 2.8 to 7.7C over today's global mean temperature. Altered continental positions and higher sea level may have been contributed about 4.8C to mid-Cretaceous warming. Thus, the combined effects of paleogeographic changes and super-plume related CO{sub 2} emissions could be in the range of 7.6 to 12.5C, within the 6 to 14C range previously estimated for mid-Cretaceous warming. CO{sub 2} releases from oceanic plateaus alone are unlikely to have been directly responsible for more than 20% of the mid-Cretaceous increase in atmospheric CO{sub 2}.

  9. A new ice core proxy of continental weathering and its feedback with atmospheric CO2

    NASA Astrophysics Data System (ADS)

    Schmitt, J.; Seth, B.; Köhler, P.; Willenbring, J. K.; Fischer, H.

    2012-04-01

    The analysis of CO2 and its stable carbon isotopes from ice cores revealed large changes of atmospheric CO2 which are closely related to a reorganisation of the global ocean circulation, marine processes and minor contributions in the terrestrial carbon storage. These components dominate the large CO2 amplitudes during glacial/interglacial terminations. Yet, on longer orbital time scales, CO2 is also modulated by the alkalinity of the ocean system. The net alkalinity influx to the ocean is driven by silicate weathering, which draws down atmospheric CO2 and provides alkalinity in the form of bicarbonate ions. Conversely, alkalinity is lost during coral reef growth and when CaCO3 is buried in marine sediments. On orbital time scales, these fluxes are assumed to be almost balanced as atmospheric CO2 and its climatic effects feed back on the weathering rates providing a negative feedback loop. Besides these basic concepts, little is known about the magnitude of weathering rate fluctuations on orbital time scales. To date, proxies from marine sediments and Fe-Mn crusts that faithfully record the ocean composition over glacial interglacial cycles do not quantify the total weathering fluxes to the ocean but only indicate that the style of weathering or the source area of sediment has changed. Due to large spatial heterogeneity, individual field site measurements do not elucidate global fluxes of weathering products to the ocean and how those might affect atmospheric CO2 concentrations. Here, we use a novel approach using the pptv-level trace gas CF4, which can be analysed in air trapped in ice cores. CF4 is a trace impurity in granites and other plutonic rocks, and during weathering this gas escapes into the atmosphere. In preindustrial times, weathering of granitic rocks was the only natural source of CF4. Because CF4 is inert to destruction processes in the tropo- and stratospheres, its only sink is destruction by UV radiation in the mesosphere. This chemical inertness

  10. Modifying Silicates for Better Dispersion in Nanocomposites

    NASA Technical Reports Server (NTRS)

    Campbell, Sandi

    2005-01-01

    An improved chemical modification has been developed to enhance the dispersion of layered silicate particles in the formulation of a polymer/silicate nanocomposite material. The modification involves, among other things, the co-exchange of an alkyl ammonium ion and a monoprotonated diamine with interlayer cations of the silicate. The net overall effects of the improved chemical modification are to improve processability of the nanocomposite and maximize the benefits of dispersing the silicate particles into the polymer. Some background discussion is necessary to give meaning to a description of this development. Polymer/silicate nanocomposites are also denoted polymer/clay composites because the silicate particles in them are typically derived from clay particles. Particles of clay comprise layers of silicate platelets separated by gaps called "galleries." The platelet thickness is 1 nm. The length varies from 30 nm to 1 m, depending on the silicate. In order to fully realize the benefits of polymer/silicate nanocomposites, it is necessary to ensure that the platelets become dispersed in the polymer matrices. Proper dispersion can impart physical and chemical properties that make nanocomposites attractive for a variety of applications. In order to achieve nanometer-level dispersion of a layered silicate into a polymer matrix, it is typically necessary to modify the interlayer silicate surfaces by attaching organic functional groups. This modification can be achieved easily by ion exchange between the interlayer metal cations found naturally in the silicate and protonated organic cations - typically protonated amines. Long-chain alkyl ammonium ions are commonly chosen as the ion-exchange materials because they effectively lower the surface energies of the silicates and ease the incorporation of organic monomers or polymers into the silicate galleries. This completes the background discussion. In the present improved modification of the interlayer silicate surfaces

  11. World weather program: Plan for fiscal year 1972

    NASA Technical Reports Server (NTRS)

    1971-01-01

    The World Weather Program which is composed of the World Weather Watch, the Global Atmospheric Research Program, and the Systems Design and Technological Development Program is presented. The U.S. effort for improving the national weather services through advances in science, technology and expanded international cooperation during FY 72 are described. The activities of the global Atmospheric Research Program for last year are highlighted and fiscal summary of U.S. programs is included.

  12. The rate and causes of lunar space weathering: Insights from Lunar Reconnaissance Orbiter Wide Angle Camera ultraviolet observations

    NASA Astrophysics Data System (ADS)

    Denevi, B. W.; Robinson, M. S.; Sato, H.; Hapke, B. W.; McEwen, A. S.; Hawke, B. R.

    2011-12-01

    Lunar Reconnaissance Orbiter Wide Angle Camera global ultraviolet and visible imaging provides a unique opportunity to examine the rate and causes of space weathering on the Moon. Silicates typically have a strong decrease in reflectance toward UV wavelengths (<~450 nm) due to strong bands at 250 nm and in the far UV. Metallic iron is relatively spectrally neutral, and laboratory spectra suggest that its addition to mature soils in the form of submicroscopic iron (also known as nanophase iron) flattens silicate spectra, significantly reducing spectral slope in the ultraviolet. Reflectance at ultraviolet wavelengths may be especially sensitive to the surface coatings that form due to exposure to space weathering because scattering from the surfaces of grains contributes a larger fraction to the reflectance spectrum at short wavelengths. We find that the UV slope (as measured by the 320/415 nm ratio) is a more sensitive measure of maturity than indexes based on visible and near-infrared wavelengths. Only the youngest features (less than ~100 Ma) retain a UV slope that is distinct from mature soils of the same composition. No craters >20 km have UV slopes that approach those observed in laboratory spectra of fresh lunar materials (powdered lunar rocks). While the 320/415 nm ratio increases by ~18% from powdered rocks to mature soils in laboratory samples, Giordano Bruno, the freshest large crater, only shows a 3% difference between fresh and mature materials. At the resolution of our UV data (400 m/pixel), we observe some small (<5 km) craters that show a ~14% difference in 320/415 nm ratio from their mature surroundings. UV observations show that Reiner Gamma has had significantly lower levels of space weathering than any of the Copernican craters we examined, and was the only region we found with a UV slope that approached laboratory values for fresh powdered rock samples. This is consistent with the hypothesis that its high albedo is due to magnetic shielding from

  13. High-latitude filtering in a global grid-point model using model normal modes. [Fourier filters for synoptic weather forecasting

    NASA Technical Reports Server (NTRS)

    Takacs, L. L.; Kalnay, E.; Navon, I. M.

    1985-01-01

    A normal modes expansion technique is applied to perform high latitude filtering in the GLAS fourth order global shallow water model with orography. The maximum permissible time step in the solution code is controlled by the frequency of the fastest propagating mode, which can be a gravity wave. Numerical methods are defined for filtering the data to identify the number of gravity modes to be included in the computations in order to obtain the appropriate zonal wavenumbers. The performances of the model with and without the filter, and with a time tendency and a prognostic field filter are tested with simulations of the Northern Hemisphere winter. The normal modes expansion technique is shown to leave the Rossby modes intact and permit 3-5 day predictions, a range not possible with the other high-latitude filters.

  14. Pilot weather advisor

    NASA Technical Reports Server (NTRS)

    Kilgore, W. A.; Seth, S.; Crabill, N. L.; Shipley, S. T.; Graffman, I.; Oneill, J.

    1992-01-01

    The results of the work performed by ViGYAN, Inc., to demonstrate the Pilot Weather Advisor cockpit weather data system using a broadcast satellite communication system are presented. The Pilot Weather Advisor demonstrated that the technical problems involved with transmitting significant amount of weather data to an aircraft in-flight or on-the-ground via satellite are solvable with today's technology. The Pilot Weather Advisor appears to be a viable solution for providing accurate and timely weather information for general aviation aircraft.

  15. Effect of elevated CO2 and temperature on abiotic and biologically-driven basalt weathering and C sequestration

    NASA Astrophysics Data System (ADS)

    Dontsova, K.; Juarez, S.; Le Galliard, J. F.; Chollet, S.; Cros, A.; Llavata, M.; Massol, F.; Barré, P.; Gelabert, A.; Daval, D.; Corvisier, J.; Troch, P. A. A.; Barron-Gafford, G.; Van Haren, J. L. M.; Ferrière, R.

    2015-12-01

    Weathering of primary silicates is one of the mechanisms involved in carbon removal from the atmosphere, affecting the carbon cycle at geologic timescales with basalt significantly contributing to the global weathering CO2 flux. Mineral weathering can be enhanced by microbiota and plants. Increase in both temperature and amount of CO2 in the atmosphere can directly increase weathering and can also affect weathering through impact on biological systems. This would result in possible negative feedback on climate change. The goal of this research was to quantify direct and indirect effects of temperature and elevated CO2 on basalt weathering and carbon sequestration. In order to achieve this goal we performed controlled-environment mesocosm experiments at Ecotron Ile-de-France. Granular basalt collected in Flagstaff, AZ was exposed to rainfall at equilibrium with two different CO2 concentrations in the air, ambient (400 ppm) and elevated (800 ppm); and kept at two climate regimes, with ambient and elevated (+ 4° C) temperature. Four biological treatments were superimposed on this design: a plant-free control; N-fixing grass (alfalfa, Medicago sativa), N-fixing tree (Velvet mesquite, Prosopis velutina); and grass that does not form symbiotic relationships with N fixers (Green Sprangletop, Leptochloa dubia). All used basalt had native microbial community. Mesocosms were equipped with solution and gas samplers. To monitor biogenic and lithogenic weathering product concentrations, soil solution samples were collected under vacuum after each rainfall event and analyzed to determine pH, electrical conductivity, major and trace elements concentrations, anions concentrations, and aqueous phase organic matter chemistry. Soil gases were monitored for CO2 using porous Teflon gas samplers connected to the Vaisala probes. Plant biomass was collected at the end of the experiment to determine dry weight, as well as removal of N and lithogenic elements by the plants. Solid samples

  16. Effect of elevated CO2 and temperature on abiotic and biologically-driven basalt weathering and C sequestration

    NASA Astrophysics Data System (ADS)

    Juarez, Sabrina; Dontsova, Katerina; Le Galliard, Jean-François; Chollet, Simon; Llavata, Mathieu; Massol, Florent; Cros, Alexis; Barré, Pierre; Gelabert, Alexandre; Daval, Damien; Corvisier, Jérôme; Troch, Peter; Barron-Gafford, Greg; Van Haren, Joost; Ferrière, Régis

    2016-04-01

    Weathering of primary silicates is one of the mechanisms involved in carbon removal from the atmosphere, affecting the carbon cycle at geologic timescales with basalt significantly contributing to the global weathering CO2 flux. Mineral weathering can be enhanced by microbiota and plants. Increase in both temperature and amount of CO2 in the atmosphere can directly increase weathering and can also affect weathering through impact on biological systems. This would result in possible negative feedback on climate change. The goal of this research was to quantify direct and indirect effects of temperature and elevated CO2 on basalt weathering and carbon sequestration. In order to achieve this goal we performed controlled-environment mesocosm experiments at Ecotron Ile-de-France (France). Granular basalt collected in Flagstaff (AZ, USA) was exposed to rainfall at equilibrium with two different CO2 concentrations in the air, ambient (400 ppm) and elevated (800 ppm); and kept at two climate regimes, with ambient and elevated (+ 4° C) temperature. Four biological treatments were superimposed on this design: a plant-free control; N-fixing grass (Alfalfa, Medicago sativa), N-fixing tree (Velvet mesquite, Prosopis velutina); and grass that does not form symbiotic relationships with N fixers (Green Sprangletop, Leptochloa dubia). All used basalt had native microbial community. Mesocosms were equipped with solution and gas samplers. To monitor biogenic and lithogenic weathering product concentrations, soil solution samples were collected under vacuum after each rainfall event and analyzed to determine pH, electrical conductivity, major and trace elements concentrations, anions concentrations, and aqueous phase organic matter chemistry. Soil gases were monitored for CO2 using porous Teflon gas samplers connected to the Vaisala probes. Plant biomass was collected at the end of the experiment to determine dry weight, as well as removal of N and lithogenic elements by the plants

  17. Adsorption kinetics of silicic acid on akaganeite.

    PubMed

    Naren, Gaowa; Ohashi, Hironori; Okaue, Yoshihiro; Yokoyama, Takushi

    2013-06-01

    As part of a series of studies on the interaction between ferric ions and silicic acid in the hydrosphere, the adsorption of silicic acid on akaganeite was investigated kinetically at various pH values. The adsorption of silicic acid increased with increasing pH over an initial pH range of 4-11.5. In the kinetic experiment, the Cl(-) was released from akaganeite much faster than silicic acid was adsorbed. From this result, we concluded that chloride ions bound on the surface of akaganeite are released and Fe-OH or Fe-O(-) sites are formed, which then acts as an adsorption site for silicic acid. The uptake mechanism of silicic acid by akaganeite is significantly different from that by schwertmannite, despite the presence of the same tunnel structure.

  18. The Joint Agricultural Weather Facility's Operational Assessment Program.

    NASA Astrophysics Data System (ADS)

    Motha, Raymond P.; Heddinghaus, Thomas R.

    1986-09-01

    The Joint Agricultural Weather Facility (JAWF), a cooperative effort between the Climate Analysis Center, NMC/NWS/NOAA (National Meteorological Center/National Weather Service/National Oceanic and Atmospheric Administration) and the World Agricultural Outlook Board, U.S. Department of Agriculture (USDA), focuses on weather anomalies and their effects on the crop-yield potential in major international crop areas. The basic mission is to provide an objective procedure for translating the flow of global weather information into timely and accurate assessments of growing-season conditions which ultimately impact on global agricultural production and trade. Daily monitoring of satellite weather images and meteorological data provides the framework for agricultural weather analysis. Daily. weekly, and seasonal summaries are processed and merged with historical weather and crop data for evaluation of the crop-yield potential. Information is disseminated at routine briefings, in written summaries, and through informal discussions.

  19. Cumulate Fragments in Silicic Ignimbrites

    NASA Astrophysics Data System (ADS)

    Bachmann, O.; Ellis, B. S.; Wolff, J.

    2014-12-01

    Increasingly, studies are concluding that silicic ignimbrites are the result of the amalgamation of multiple discrete magma batches. Yet the existence of discrete batches presents a conundrum for magma generation and storage; if silicic magma batches are not generated nearly in situ in the upper crust, they must traverse, and reside within, a thermally hostile environment with large temperature gradients, resulting in low survivability in their shallow magmatic hearths. The Snake River Plain (Idaho, USA) is a type example of this 'multi-batch' assembly with ignimbrites containing multiple populations of pyroxene crystals, glass shards, and crystal aggregates. The ubiquitous crystal aggregates hint at a mechanism to facilitate the existence of multiple, relatively small batches of rhyolite in the upper crust. These aggregates contain the same plagioclase, pyroxene, and oxide mineral compositions as single phenocrysts of the same minerals in their host rocks, but they have significantly less silicic bulk compositions and lack quartz and sanidine, which occur as single phenocrysts in the deposits. This implies significant crystallization followed by melt extraction from mushy reservoir margins. The extracted melt then continues to evolve (crystallizing sanidine and quartz) while the melt-depleted margins provide an increasingly rigid and refractory network segregating the crystal-poor batches of magma. The hot, refractory, margins insulate the crystal-poor lenses, allowing (1) extended residence in the upper crust, and (2) preservation of chemical heterogeneities among batches. In contrast, systems that produce cumulates richer in low-temperature phases (quartz, K-feldspars, and/or biotite) favour remelting upon recharge, leading to less segregation of eruptible melt pockets and the formation of gradationally zoned ignimbrites. The occurrence of similar crystal aggregates from a variety of magmatic lineages suggests the generality of this process.

  20. Silicate stabilization studies in propylene glycol

    SciTech Connect

    Schwartz, S.A.

    1999-08-01

    In most North American and many European coolant formulations, the corrosion inhibition of heat-rejecting aluminum surfaces is provided by alkali metal silicates. But, their tendency towards polymerization, leading to gelation and/or precipitation, can reduce the effectiveness of a coolant. This paper presents the results of experiments which illustrate formulation-dependent behavior of inorganic silicate in propylene glycol compositions. Specific examples of the effects of glycol matrix, stabilizer type, and hard water on silicate stabilization are provided.

  1. Winter Weather Checklists

    MedlinePlus

    ... About CDC.gov . Natural Disasters and Severe Weather Earthquakes Being Prepared Emergency Supplies Home Hazards Indoor Safety ... Matters What's New Preparation & Planning Disasters & Severe Weather Earthquakes Extreme Heat Floods Hurricanes Landslides Tornadoes Tsunamis Volcanoes ...

  2. Winter Weather: Frostbite

    MedlinePlus

    ... About CDC.gov . Natural Disasters and Severe Weather Earthquakes Being Prepared Emergency Supplies Home Hazards Indoor Safety ... Matters What's New Preparation & Planning Disasters & Severe Weather Earthquakes Extreme Heat Floods Hurricanes Landslides Tornadoes Tsunamis Volcanoes ...

  3. Winter Weather: Outdoor Safety

    MedlinePlus

    ... About CDC.gov . Natural Disasters and Severe Weather Earthquakes Being Prepared Emergency Supplies Home Hazards Indoor Safety ... Matters What's New Preparation & Planning Disasters & Severe Weather Earthquakes Extreme Heat Floods Hurricanes Landslides Tornadoes Tsunamis Volcanoes ...

  4. Winter Weather Emergencies

    MedlinePlus

    Severe winter weather can lead to health and safety challenges. You may have to cope with Cold related health problems, including ... there are no guarantees of safety during winter weather emergencies, you can take actions to protect yourself. ...

  5. The quiet revolution of numerical weather prediction

    NASA Astrophysics Data System (ADS)

    Bauer, Peter; Thorpe, Alan; Brunet, Gilbert

    2015-09-01

    Advances in numerical weather prediction represent a quiet revolution because they have resulted from a steady accumulation of scientific knowledge and technological advances over many years that, with only a few exceptions, have not been associated with the aura of fundamental physics breakthroughs. Nonetheless, the impact of numerical weather prediction is among the greatest of any area of physical science. As a computational problem, global weather prediction is comparable to the simulation of the human brain and of the evolution of the early Universe, and it is performed every day at major operational centres across the world.

  6. Tailoring polymer properties with layered silicates

    NASA Astrophysics Data System (ADS)

    Xu, Liang

    Polymer layered silicate nanocomposites have found widespread applications in areas such as plastics, oil and gas production, biomedical, automotive and information storage, but their successful commercialization critically depends on consistent control over issues such as complete dispersion of layered silicate into the host polymer and optimal interaction between the layered silicates and the polymers. Polypropylene is a commercially important polymer but usually forms intercalated structures with organically modified layered silicate upon mixing, even it is pre-treated with compatibilizing agent such as maleic anhydride. In this work, layered silicate is well dispersed in ammonium modified polypropylene but does not provide sufficient reinforcement to the host polymer due to poor interactions. On the other hand, interactions between maleic anhydride modified polypropylene and layered silicate are fine tuned by using a small amount of maleic anhydride and mechanical strength of the resultant nanocomposites are significantly enhanced. In particular, the melt rheological properties of layered silicate nanocomposites with maleic anhydride functionalized polypropylene are contrasted to those based on ammonium-terminated polypropylene. While the maleic anhydride treated polypropylene based nanocomposites exhibit solid-like linear dynamic behavior, consistent with the formation of a long-lived percolated nanoparticle network, the single-end ammonium functionalized polypropylene based nanocomposites demonstrated liquid-like behavior at comparable montmorillonite concentrations. The differences in the linear viscoelasticity are attributed to the presence of bridging interaction in maleic anhydride functionalized nanocomposites, which facilitates formation of a long-lived silicate network mediated by physisorbed polymer chains. Further, the transient shear stress of the maleic anhydride functionalized nanocomposites in start-up of steady shear is a function of the shear

  7. Basaltic injections into floored silicic magma chambers

    NASA Astrophysics Data System (ADS)

    Wiebe, R. A.

    Recent studies have provided compelling evidence that many large accumulations of silicic volcanic rocks erupted from long-lasting, floored chambers of silicic magma that were repeatedly injected by basaltic magma. These basaltic infusions are commonly thought to play an important role in the evolution of the silicic systems: they have been proposed as a cause for explosive silicic eruptions [Sparks and Sigurdsson, 1977], compositional variation in ash-flow sheets [Smith, 1979], mafic magmatic inclusions in silicic volcanic rocks [Bacon, 1986], and mixing of mafic and silicic magmas [Anderson, 1976; Eichelberger, 1978]. If, as seems likely, floored silicic magma chambers have frequently been invaded by basalt, then plutonic bodies should provide records of these events. Although plutonic evidence for mixing and commingling of mafic and silicic magmas has been recognized for many years, it has been established only recently that some intrusive complex originated through multiple basaltic injections into floored chambers of silicic magma [e.g., Wiebe, 1974; Michael, 1991; Chapman and Rhodes, 1992].

  8. Physical and chemical weathering. [of Martian surface and rocks

    NASA Technical Reports Server (NTRS)

    Gooding, James L.; Arvidson, Raymond E.; Zolotov, Mikhail IU.

    1992-01-01

    Physical and chemical weathering processes that might be important on Mars are reviewed, and the limited observations, including relevant Viking results and laboratory simulations, are summarized. Physical weathering may have included rock splitting through growth of ice, salt or secondary silicate crystals in voids. Chemical weathering probably involved reactions of minerals with water, oxygen, and carbon dioxide, although predicted products vary sensitively with the abundance and physical form postulated for the water. On the basis of kinetics data for hydration of rock glass on earth, the fate of weathering-rind formation on glass-bearing Martian volcanic rocks is tentatively estimated to have been on the order of 0.1 to 4.5 cm/Gyr; lower rates would be expected for crystalline rocks.

  9. American Weather Stories.

    ERIC Educational Resources Information Center

    Hughes, Patrick

    Weather has shaped United States' culture, national character and folklore; at times it has changed the course of history. The seven accounts compiled in this publication highlight some of the nation's weather experiences from the hurricanes that threatened Christopher Columbus to the peculiar run of bad weather that has plagued American…

  10. Aviation weather services

    NASA Technical Reports Server (NTRS)

    Sprinkle, C. H.

    1983-01-01

    The primary responsibilities of the National Weather Service (NWS) are to: provide warnings of severe weather and flooding for the protection of life and property; provide public forecasts for land and adjacent ocean areas for planning and operation; and provide weather support for: production of food and fiber; management of water resources; production, distribution and use of energy; and efficient and safe air operations.

  11. Weather Fundamentals: Meteorology. [Videotape].

    ERIC Educational Resources Information Center

    1998

    The videos in this educational series, for grades 4-7, help students understand the science behind weather phenomena through dramatic live-action footage, vivid animated graphics, detailed weather maps, and hands-on experiments. This episode (23 minutes) looks at how meteorologists gather and interpret current weather data collected from sources…

  12. Cold-Weather Sports

    MedlinePlus

    ... Surgery? A Week of Healthy Breakfasts Shyness Cold-Weather Sports KidsHealth > For Teens > Cold-Weather Sports Print A A A What's in this ... Equipment Ahh, winter! Shorter days. Frigid temperatures. Foul weather. What better time to be outdoors? Winter sports ...

  13. Hot Weather Tips

    MedlinePlus

    ... FCA - A A + A You are here Home HOT Weather Tips Printer-friendly version We all suffer in hot weather. However, for elderly and disabled people and ... stress and following these tips for dealing with hot weather. Wear cool clothing: See that the person ...

  14. Increased precipitation and weathering across the Paleocene-Eocene Thermal Maximum in central China

    NASA Astrophysics Data System (ADS)

    Chen, Zuoling; Ding, Zhongli; Yang, Shiling; Zhang, Chunxia; Wang, Xu

    2016-06-01

    Global warming during the Paleocene-Eocene Thermal Maximum (PETM) ˜55.5 million years ago (Ma) was associated with a massive release of carbon to the ocean-atmosphere system, as evidenced by a prominent negative carbon isotope excursion (CIE) and widespread dissolution of marine carbonates. The paleohydrologic response to the PETM warming has been studied worldwide; however, relevant records of environmental perturbation in Asia are lacking so far. Here we extend the record of this event in central China, a subtropical paleosetting, through geochemical and mineralogical analyses of lacustrine sediments. Geochemical indicators of authigenic carbonates—including molar Mg/Ca and Sr/Ca ratios—suggest an overall increased precipitation across the PETM, compatible with the disappearance of authigenic dolomite and the appearance of kaolinite in the strata. The relatively humid conditions persisted long after the carbon-cycle perturbation had stopped, implying that the transient hyper-greenhouse warming might have forced the regional climate system into a new climate state that was not easily reversed. Additionally, a gradual increase in chemical index of alteration (CIA) and the appearance of kaolinite are associated with the PETM, indicating an intensified silicate weathering and pedogenesis in the watershed in response to warmer and more humid climate. Our results corroborate the theory that an accelerated continental chemical weathering served as a negative feedback to sequester carbon and lower the atmospheric greenhouse-gas levels during the PETM.

  15. Space Weathering on Icy Satellites in the Outer Solar System

    NASA Technical Reports Server (NTRS)

    Clark, R. N.; Perlman, Z.; Pearson, N.; Cruikshank, D. P.

    2014-01-01

    Space weathering produces well-known optical effects in silicate minerals in the inner Solar System, for example, on the Moon. Space weathering from solar wind and UV (ultraviolet radiation) is expected to be significantly weaker in the outer Solar System simply because intensities are low. However, cosmic rays and micrometeoroid bombardment would be similar to first order. That, combined with the much higher volatility of icy surfaces means there is the potential for space weathering on icy outer Solar System surfaces to show optical effects. The Cassini spacecraft orbiting Saturn is providing evidence for space weathering on icy bodies. The Cassini Visible and Infrared Mapping Spectrometer (VIMS) instrument has spatially mapped satellite surfaces and the rings from 0.35-5 microns and the Ultraviolet Imaging Spectrograph (UVIS) instrument from 0.1 to 0.2 microns. These data have sampled a complex mixing space between H2O ice and non-ice components and they show some common spectral properties. Similarly, spectra of the icy Galilean satellites and satellites in the Uranian system have some commonality in spectral properties with those in the Saturn system. The UV absorber is spectrally similar on many surfaces. VIMS has identified CO2, H2 and trace organics in varying abundances on Saturn's satellites. We postulate that through the spatial relationships of some of these compounds that they are created and destroyed through space weathering effects. For example, the trapped H2 and CO2 observed by VIMS in regions with high concentrations of dark material may in part be space weathering products from the destruction of H2O and organic molecules. The dark material, particularly on Iapetus which has the highest concentration in the Saturn system, is well matched by space-weathered silicates in the .4 to 2.6 micron range, and the spectral shapes closely match those of the most mature lunar soils, another indicator of space weathered material.

  16. The mid-Cretaceous super plume, carbon dioxide, and global warming

    NASA Technical Reports Server (NTRS)

    Caldeira, Ken; Rampino, Michael R.

    1991-01-01

    Carbon-dioxide releases associated with a mid-Cretaceous super plume and the emplacement of the Ontong-Java Plateau have been suggested as a principal cause of the mid-Cretaceous global warming. A carbonate-silicate cycle model is developed to quantify the possible climatic effects of these CO2 releases, utilizing four different formulations for the rate of silicate-rock weathering as a function of atmospheric CO2. CO2 emissions resulting from super-plume tectonics could have produced atmospheric CO2 levels from 3.7 to 14.7 times the modern preindustrial value of 285 ppm. Based on the temperature sensitivity to CO2 increases used in the weathering-rate formulations, this would cause a global warming of from 2.8 to 7.7 C over today's glogal mean temperature. Altered continental positions and higher sea level may have been contributed about 4.8 C to mid-Cretaceous warming. Thus, the combined effects of paleogeographic changes and super-plume related CO2 emissions could be in the range of 7.6 to 12.5 C, within the 6 to 14 C range previously estimated for mid-Cretaceous warming. CO2 releases from oceanic plateaus alone are unlikely to have been directly responsible for more than 20 percent of the mid-Cretaceous increase in atmospheric CO2.

  17. A preliminary study of the impact of the ERS 1 C band scatterometer wind data on the European Centre for Medium-Range Weather Forecasts global data assimilation system

    NASA Technical Reports Server (NTRS)

    Hoffman, Ross N.

    1993-01-01

    A preliminary assessment of the impact of the ERS 1 scatterometer wind data on the current European Centre for Medium-Range Weather Forecasts analysis and forecast system has been carried out. Although the scatterometer data results in changes to the analyses and forecasts, there is no consistent improvement or degradation. Our results are based on comparing analyses and forecasts from assimilation cycles. The two sets of analyses are very similar except for the low level wind fields over the ocean. Impacts on the analyzed wind fields are greater over the southern ocean, where other data are scarce. For the most part the mass field increments are too small to balance the wind increments. The effect of the nonlinear normal mode initialization on the analysis differences is quite small, but we observe that the differences tend to wash out in the subsequent 6-hour forecast. In the Northern Hemisphere, analysis differences are very small, except directly at the scatterometer locations. Forecast comparisons reveal large differences in the Southern Hemisphere after 72 hours. Notable differences in the Northern Hemisphere do not appear until late in the forecast. Overall, however, the Southern Hemisphere impacts are neutral. The experiments described are preliminary in several respects. We expect these data to ultimately prove useful for global data assimilation.

  18. Hydrochemical and Isotopic Constraints on the Temporal and Spatial Variability of Chemical Weathering and CO2 Fluxes: An Example From the Australian Victorian Alps

    NASA Astrophysics Data System (ADS)

    Hagedorn, B.; Cartwright, I.

    2007-12-01

    Water from a network of 11 pristine rivers draining the Australian Victorian Alps was collected at different locations during (i) high discharge (June 2006) and (ii) low discharge (February 2007) conditions and was analyzed for dissolved major ions, δ2H and δ18O, and δ34S of dissolved sulphate. River water chemistry implies that solutes are largely derived from precipitation and chemical weathering of silicate lithologies. Cl/Br ratios as low as 30 molar suggest that rivers have not dissolved halite, however, higher salinity (≥100 mmol/L) winter samples have intermediate Cl/Br ratios (600 to 2000 molar) that are attributed to minor halite dissolution at the onset of the rainy season. Subsequent mixing of river water homogenizes ratios and evaporation is the dominant process that increases downstream salinities. Oxygen and Hydrogen isotopes also indicate that mixing and evaporation have occurred. Despite the lack of carbonate outcrops in the study area and uniform negative calcite saturation indices, the dissolution of hydrothermal calcite may account for up to 67% of the total dissolved cations, generating up to 92% of all dissolved Ca and Mg. The sulphur isotope data (16 to 20°CDT) indicates that the dissolved SO4 is derived predominantly from atmospheric deposition and minor gypsum weathering and not from bacterial reduction of FeS. This militates against sulphuric acid weathering in Victorian rivers. Si/(Na* + K*) ratios suggest that silicate weathering is dominated by the transformation of plagioclase (An40) to smectite and, to a lesser extend, the production of kaolinite. In total, chemical weathering consumes 17.6 x 106 (summer) to 71.59 x 106(winter) mol/km2/yr CO2, with the highest values in rivers draining the basement outcrops rather than sedimentary rocks. This range is at the upper end of the global scale and shows that the predominance of fresh silicate lithologies exerts the main control on higher CO2 fluxes; temperature and runoff, in turn, are

  19. Weatherization and Intergovernmental Program - Weatherization Assistance Program

    SciTech Connect

    2010-06-01

    The U.S. Department of Energy’s (DOE) Weatherization Assistance Program reduces energy costs for low-income households by increasing the energy efficiency of their homes, while ensuring their health and safety.

  20. Distinct Mineral Weathering Behaviors of the Novel Mineral-Weathering Strains Rhizobium yantingense H66 and Rhizobium etli CFN42

    PubMed Central

    Chen, Wei; Luo, Long; He, Lin-Yan; Wang, Qi

    2016-01-01

    ABSTRACT Bacteria play important roles in mineral weathering, soil formation, and element cycling. However, little is known about the interaction between silicate minerals and rhizobia. In this study, Rhizobium yantingense H66 (a novel mineral-weathering rhizobium) and Rhizobium etli CFN42 were compared with respect to potash feldspar weathering, mineral surface adsorption, and metabolic activity during the mineral weathering process. Strain H66 showed significantly higher Si, Al, and K mobilization from the mineral and higher ratios of cell numbers on the mineral surface to total cell numbers than strain CFN42. Although the two strains produced gluconic acid, strain H66 also produced acetic, malic, and succinic acids during mineral weathering in low- and high-glucose media. Notably, higher Si, Al, and K releases, higher ratios of cell numbers on the mineral surface to total cell numbers, and a higher production of organic acids by strain H66 were observed in the low-glucose medium than in the high-glucose medium. Scanning electron microscope analyses of the mineral surfaces and redundancy analysis showed stronger positive correlations between the mineral surface cell adsorption and mineral weathering, indicated by the dissolved Al and K concentrations. The results showed that the two rhizobia behaved differently with respect to mineral weathering. The results suggested that Rhizobium yantingense H66 promoted potash feldspar weathering through increased adsorption of cells to the mineral surface and through differences in glucose metabolism at low and high nutrient concentrations, especially at low nutrient concentrations. IMPORTANCE This study reported the potash feldspar weathering, the cell adsorption capacity of the mineral surfaces, and the metabolic differences between the novel mineral-weathering Rhizobium yantingense H66 and Rhizobium etli CFN42 under different nutritional conditions. The results showed that Rhizobium yantingense H66 had a greater ability

  1. Multi-proxy Reconstruction of Seawater Chemistry Across K-Pg Boundary: Tracking Weathering Feedbacks in Response to Extreme Carbon Cycle Perturbation

    NASA Astrophysics Data System (ADS)

    Misra, S.; Elderfield, H.

    2014-12-01

    On geologic time scales concentrations of atmospheric CO2, a greenhouse gas and critical mediator of Earth's surface temperature and climate, is thought to be controlled by a balance between CO2 input from mantle degassing through volcanism and metamorphism and consumption via temperature-sensitive chemical weathering of tectonically uplifted continental rocks. This interplay between global climate and tectonic uplift also controls the delivery of cations to the oceans. Hence, past changes in seawater chemistry provide a powerful archive of the interplay and feedback between climate and tectonics. Mass Extinction Events, like that at K-Pg boundary, are characterized by rapid, global Carbon Cycle Perturbations either from increased mantle degassing or by incineration of the continents due to extra-terrestrial impact. It is hypothesized that enhanced chemical weathering of continental silicate rocks consumes this excess CO2 and restores steady-state. Lithium, B, and Mg are conservative ions in seawater that are isotopically homogeneous with a residence time much longer than the oceanic mixing time. As a result, δ7LiSW, δ11BSW, and δ26MgSW, recorded by marine calcites reflect a global picture and secular variations in isotopic composition of these elements within periods shorter than their residence time must thus reflect imbalances between the sources and sinks of these elements to and from the ocean. Cenozoic δ7LiSW shows an abrupt 5‰ drop across the K-Pg boundary, simultaneous with the seawater Ir and Os isotope spikes. This rapid decrease in δ7LiSW is due to a large instantaneous delivery of isotopically light Li to the oceans and cannot be produced by an impactor nor by Deccan trap volcanism, suggesting large-scale continental denudation. We will create high-resolution δ7LiSW, δ11BSW, and δ26MgSW records across K-Pg boundary using planktonic and benthic foraminifera from multiple ODP/DSDP sites to quantify the amount of C excursion and the response of

  2. High Pressure Response of Siliceous Materials

    DTIC Science & Technology

    2013-02-01

    quartz, Starphire soda lime silicate glass, hydrated Starphire, BOROFLOAT borosilicate glass, an iron-containing soda lime silicate glass, opal (a hydrated... Opal (hydrated amorphous silica). .............................................................................. 10 2.7. ROBAX glass ceramic...spectrum as a function of stress for BOROFLOAT borosilicate glass. .......... 29 4.8. Raman spectrum as a function of stress for opal (hydrated

  3. High Pressure Response of Siliceous Materials

    DTIC Science & Technology

    2013-02-01

    iron-containing soda lime silicate glass, opal (a hydrated silicate glass), ROBAX glass ceramic, and others were single crystal (α-quartz) and...10 2.6. Opal (hydrated amorphous silica...Raman spectrum as a function of stress for opal (hydrated silica) glass. ................... 29 4.9. Raman spectrum as a function of stress for

  4. 21 CFR 182.2227 - Calcium silicate.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 21 Food and Drugs 3 2014-04-01 2014-04-01 false Calcium silicate. 182.2227 Section 182.2227 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) SUBSTANCES GENERALLY RECOGNIZED AS SAFE Anticaking Agents § 182.2227 Calcium silicate. (a) Product. Calcium...

  5. 21 CFR 182.2437 - Magnesium silicate.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 21 Food and Drugs 3 2014-04-01 2014-04-01 false Magnesium silicate. 182.2437 Section 182.2437 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) SUBSTANCES GENERALLY RECOGNIZED AS SAFE Anticaking Agents § 182.2437 Magnesium silicate. (a) Product....

  6. The importance of terrestrial weathering for climate system modelling on extended timescales: a study with the UVic ESCM

    NASA Astrophysics Data System (ADS)

    Brault, Marc-Olivier; Matthews, Damon; Mysak, Lawrence

    2016-04-01

    The chemical erosion of carbonate and silicate rocks is a key process in the global carbon cycle and, through its coupling with calcium carbonate deposition in the ocean, is the primary sink of carbon on geologic timescales. The dynamic interdependence of terrestrial weathering rates with atmospheric temperature and carbon dioxide concentrations is crucial to the regulation of Earth's climate over multi-millennial timescales. However any attempts to develop a modeling context for terrestrial weathering as part of a dynamic climate system are limited, mostly because of the difficulty in adapting the multi-millennial timescales of the implied negative feedback mechanism with those of the atmosphere and ocean. Much of the earlier work on this topic is therefore based on box-model approaches, abandoning spatial variability for the sake of computational efficiency and the possibility to investigate the impact of weathering on climate change over time frames much longer than those allowed by traditional climate system models. As a result we still have but a rudimentary understanding of the chemical weathering feedback mechanism and its effects on ocean biogeochemistry and atmospheric CO2. Here, we introduce a spatially-explicit, rock weathering model into the University of Victoria Earth System Climate Model (UVic ESCM). We use a land map which takes into account a number of different rock lithologies, changes in sea level, as well as an empirical model of the temperature and NPP dependency of weathering rates for the different rock types. We apply this new model to the last deglacial period (c. 21000BP to 13000BP) as well as a future climate change scenario (c. 1800AD to 6000AD+), comparing the results of our 2-D version of the weathering feedback mechanism to simulations using only the box-model parameterizations of Meissner et al. [2012]. These simulations reveal the importance of two-dimensional factors (i.e., changes in sea level and rock type distribution) in the

  7. The effect of temperature on experimental and natural chemical weathering rates of granitoid rocks

    USGS Publications Warehouse

    White, A.F.; Blum, A.E.; Bullen, T.D.; Vivit, D.V.; Schulz, M.; Fitzpatrick, J.

    1999-01-01

    The effects of climatic temperature variations (5-35??C) on chemical weathering are investigated both experimentally using flow-through columns containing fresh and weathered granitoid rocks and for natural granitoid weathering in watersheds based on annual solute discharge. Although experimental Na and Si effluent concentrations are significantly higher in the fresh relative to the weathered granitoids, the proportional increases in concentration with increasing temperature are similar. Si and Na exhibit comparable average apparent activation energies (E(a)) of 56 and 61 kJ/mol, respectively, which are similar to those reported for experimental feldspar dissolution measured over larger temperature ranges. A coupled temperature-precipitation model, using an expanded database for solute discharge fluxes from a global distribution of 86 granitoid watersheds, produces an apparent activation energy for Si (51 kJ/mol), which is also comparable to those derived from the experimental study. This correlation reinforces evidence that temperature does significantly impact natural silicate weathering rates. Effluent K concentrations in the column study are elevated with respect to other cations compared to watershed discharge due to the rapid oxidation/dissolution of biotite. K concentrations are less sensitive to temperature, resulting in a lower average E(a) value (27 kJ/mol) indicative of K loss from lower energy interlayer sites in biotite. At lower temperatures, initial cation release from biotite is significantly faster than cation release from plagioclase. This agrees with reported higher K/Na ratios in cold glacial watersheds relative to warmer temperate environments. Increased release of less radiogenic Sr from plagioclase relative to biotite at increasing temperature produces corresponding decreases in 87Sr/86Sr ratios in the column effluents. A simple mixing calculation using effluent K/Na ratios, Sr concentrations and 87Sr/86Sr ratios for biotite and plagioclase

  8. Mesoporous Silicate Materials in Sensing

    PubMed Central

    Melde, Brian J.; Johnson, Brandy J.; Charles, Paul T.

    2008-01-01

    Mesoporous silicas, especially those exhibiting ordered pore systems and uniform pore diameters, have shown great potential for sensing applications in recent years. Morphological control grants them versatility in the method of deployment whether as bulk powders, monoliths, thin films, or embedded in coatings. High surface areas and pore sizes greater than 2 nm make them effective as adsorbent coatings for humidity sensors. The pore networks also provide the potential for immobilization of enzymes within the materials. Functionalization of materials by silane grafting or through co-condensation of silicate precursors can be used to provide mesoporous materials with a variety of fluorescent probes as well as surface properties that aid in selective detection of specific analytes. This review will illustrate how mesoporous silicas have been applied to sensing changes in relative humidity, changes in pH, metal cations, toxic industrial compounds, volatile organic compounds, small molecules and ions, nitroenergetic compounds, and biologically relevant molecules. PMID:27873810

  9. Space Weathering of Rocks

    NASA Technical Reports Server (NTRS)

    Noble, Sarah

    2011-01-01

    Space weathering discussions have generally centered around soils but exposed rocks will also incur the effects of weathering. On the Moon, rocks make up only a very small percentage of the exposed surface and areas where rocks are exposed, like central peaks, are often among the least space weathered regions we find in remote sensing data. However, our studies of weathered Ap 17 rocks 76015 and 76237 show that significant amounts of weathering products can build up on rock surfaces. Because rocks have much longer surface lifetimes than an individual soil grain, and thus record a longer history of exposure, we can study these products to gain a deeper perspective on the weathering process and better assess the relative impo!1ance of various weathering components on the Moon. In contrast to the lunar case, on small asteroids, like Itokowa, rocks make up a large fraction of the exposed surface. Results from the Hayabusa spacecraft at Itokowa suggest that while the low gravity does not allow for the development of a mature regolith, weathering patinas can and do develop on rock surfaces, in fact, the rocky surfaces were seen to be darker and appear spectrally more weathered than regions with finer materials. To explore how weathering of asteroidal rocks may differ from lunar, a set of ordinary chondrite meteorites (H, L, and LL) which have been subjected to artificial space weathering by nanopulse laser were examined by TEM. NpFe(sup 0) bearing glasses were ubiquitous in both the naturally-weathered lunar and the artificially-weathered meteorite samples.

  10. Identifying the crystal graveyards remaining after large silicic eruptions

    NASA Astrophysics Data System (ADS)

    Gelman, Sarah E.; Deering, Chad D.; Bachmann, Olivier; Huber, Christian; Gutiérrez, Francisco J.

    2014-10-01

    The formation of crystal-poor high-silica rhyolite via extraction of interstitial melt from an upper crustal mush predicts the complementary formation of large amounts of (typically unerupted) silicic cumulates. However, identification of these cumulates remains controversial. One hindrance to our ability to identify them is a lack of clear predictions for complementary chemical signatures between extracted melts and their residues. To address this discrepancy, we present a generalized geochemical model tracking the evolution of trace elements in a magma reservoir concurrently experiencing crystallization and extraction of interstitial melt. Our method uses a numerical solution rather than analytical, thereby allowing for various dependencies between crystallinity, partition coefficients for variably compatible and/or incompatible elements, and melt extraction efficiency. Results reveal unambiguous fractionation signatures for the extracted melts, while those signatures are muted for their cumulate counterparts. Our model is first applied to a well-constrained example (Searchlight pluton, USA), and provides a good fit to geochemical data. We then extrapolate our results to understanding the relationship between volcanic and plutonic silicic suites on a global scale. Utilizing the NAVDAT database to identify crystal accumulation or depletion signatures for each suite, we suggest that many large granitoids are indeed silicic cumulates, although their crystal accumulation signature is expected to be subtle.

  11. Weathering: methods and techniques to measure

    NASA Astrophysics Data System (ADS)

    Lopez-Arce, P.; Zornoza-Indart, A.; Alvarez de Buergo, M.; Fort, R.

    2012-04-01

    Surface recession takes place when weathered material is removed from the rocks. In order to know how fast does weathering and erosion occur, a review of several methods, analyses and destructive and non-destructive techniques to measure weathering of rocks caused by physico-chemical changes that occur in bedrocks due to salt crystallization, freezing-thaw, thermal shock, influence of water, wind, temperature or any type of environmental agent leading to weathering processes and development of soils, in-situ in the field or through experimental works in the laboratory are addressed. From micro-scale to macro-scale, from the surface down to more in depth, several case studies on in-situ monitoring of quantification of decay on soils and rocks from natural landscapes (mountains, cliffs, caves, etc) or from urban environment (foundations or facades of buildings, retaining walls, etc) or laboratory experimental works, such as artificial accelerated ageing tests (a.a.e.e.) or durability tests -in which one or more than one weathering agents are selected to assess the material behaviour in time and in a cyclic way- performed on specimens of these materials are summarised. Discoloration, structural alteration, precipitation of weathering products (mass transfer), and surface recession (mass loss) are all products of weathering processes. Destructive (SEM-EDX, optical microscopy, mercury intrusion porosimetry, drilling resistance measurement, flexural and compression strength) and Non-destructive (spectrophotocolorimetry, 3D optical surface roughness, Schmidt hammer rebound tester, ultrasound velocity propagation, Nuclear Magnetic Resonance NMR, X ray computed micro-tomography or CT-scan, geo-radar differential global positioning systems) techniques and characterization analyses (e.g. water absorption, permeability, open porosity or porosity accessible to water) to assess their morphological, physico-chemical, mechanical and hydric weathering; consolidation products or

  12. NASA Connect: 'Plane Weather'

    NASA Technical Reports Server (NTRS)

    1999-01-01

    Excerpt from the NASA Connect show 'Plane Weather' This clip explains what high and low pressure weather systems are, and how these affect weather patterns. Weather affects our daily lives. The elements of weather: rain, wind, fog, ice and snow affect the operation and flight of an airplane. In this program, NASA and FAA researchers will introduce students to math, science, and weather; demonstrate how these elements influence flight; and show how NASA and FAA research is used to limit the effects of these elements on flight. Students will examine: the tools, techniques, and technologies used by engineers and scientists to detect these and other climatological factors affecting aircraft in flight. The lesson and classroom experiment will involve students in the scientific process and emphasizing problem solving, measurement, and reasoning skills.

  13. Tales of future weather

    NASA Astrophysics Data System (ADS)

    Hazeleger, W.; van den Hurk, B. J. J. M.; Min, E.; van Oldenborgh, G. J.; Petersen, A. C.; Stainforth, D. A.; Vasileiadou, E.; Smith, L. A.

    2015-02-01

    Society is vulnerable to extreme weather events and, by extension, to human impacts on future events. As climate changes weather patterns will change. The search is on for more effective methodologies to aid decision-makers both in mitigation to avoid climate change and in adaptation to changes. The traditional approach uses ensembles of climate model simulations, statistical bias correction, downscaling to the spatial and temporal scales relevant to decision-makers, and then translation into quantities of interest. The veracity of this approach cannot be tested, and it faces in-principle challenges. Alternatively, numerical weather prediction models in a hypothetical climate setting can provide tailored narratives for high-resolution simulations of high-impact weather in a future climate. This 'tales of future weather' approach will aid in the interpretation of lower-resolution simulations. Arguably, it potentially provides complementary, more realistic and more physically consistent pictures of what future weather might look like.

  14. High potential for weathering and climate effects of non-vascular vegetation in the Late Ordovician.

    PubMed

    Porada, P; Lenton, T M; Pohl, A; Weber, B; Mander, L; Donnadieu, Y; Beer, C; Pöschl, U; Kleidon, A

    2016-07-07

    It has been hypothesized that predecessors of today's bryophytes significantly increased global chemical weathering in the Late Ordovician, thus reducing atmospheric CO2 concentration and contributing to climate cooling and an interval of glaciations. Studies that try to quantify the enhancement of weathering by non-vascular vegetation, however, are usually limited to small areas and low numbers of species, which hampers extrapolating to the global scale and to past climatic conditions. Here we present a spatially explicit modelling approach to simulate global weathering by non-vascular vegetation in the Late Ordovician. We estimate a potential global weathering flux of 2.8 (km(3) rock) yr(-1), defined here as volume of primary minerals affected by chemical transformation. This is around three times larger than today's global chemical weathering flux. Moreover, we find that simulated weathering is highly sensitive to atmospheric CO2 concentration. This implies a strong negative feedback between weathering by non-vascular vegetation and Ordovician climate.

  15. High potential for weathering and climate effects of non-vascular vegetation in the Late Ordovician

    NASA Astrophysics Data System (ADS)

    Porada, P.; Lenton, T. M.; Pohl, A.; Weber, B.; Mander, L.; Donnadieu, Y.; Beer, C.; Pöschl, U.; Kleidon, A.

    2016-07-01

    It has been hypothesized that predecessors of today's bryophytes significantly increased global chemical weathering in the Late Ordovician, thus reducing atmospheric CO2 concentration and contributing to climate cooling and an interval of glaciations. Studies that try to quantify the enhancement of weathering by non-vascular vegetation, however, are usually limited to small areas and low numbers of species, which hampers extrapolating to the global scale and to past climatic conditions. Here we present a spatially explicit modelling approach to simulate global weathering by non-vascular vegetation in the Late Ordovician. We estimate a potential global weathering flux of 2.8 (km3 rock) yr-1, defined here as volume of primary minerals affected by chemical transformation. This is around three times larger than today's global chemical weathering flux. Moreover, we find that simulated weathering is highly sensitive to atmospheric CO2 concentration. This implies a strong negative feedback between weathering by non-vascular vegetation and Ordovician climate.

  16. Weather and climate

    NASA Technical Reports Server (NTRS)

    1975-01-01

    Recommendations for using space observations of weather and climate to aid in solving earth based problems are given. Special attention was given to: (1) extending useful forecasting capability of space systems, (2) reducing social, economic, and human losses caused by weather, (3) development of space system capability to manage and control air pollutant concentrations, and (4) establish mechanisms for the national examination of deliberate and inadvertent means for modifying weather and climate.

  17. Modulation of Late Cretaceous and Cenozoic climate by variable drawdown of atmospheric pCO2 from weathering of basaltic provinces on continents drifting through the equatorial humid belt

    NASA Astrophysics Data System (ADS)

    Kent, D. V.; Muttoni, G.

    2012-09-01

    The small reservoir of carbon dioxide in the atmosphere (pCO2) that modulates climate through the greenhouse effect reflects a delicate balance between large fluxes of sources and sinks. The major long-term source of CO2 is global outgassing from sea-floor spreading, subduction, hotspot activity, and metamorphism; the ultimate sink is through weathering of continental silicates and deposition of carbonates. Most carbon cycle models are driven by changes in the source flux scaled to variable rates of ocean floor production. However, ocean floor production may not be distinguishable from being steady since 180 Ma. We evaluate potential changes in sources and sinks of CO2 for the past 120 Ma in a paleogeographic context. Our new calculations show that although decarbonation of pelagic sediments in Tethyan subduction likely contributed to generally high pCO2 levels from the Late Cretaceous until the Early Eocene, shutdown of Tethyan subduction with collision of India and Asia at the Early Eocene Climate Optimum at around 50 Ma was inadequate to account for the large and prolonged decrease in pCO2 that eventually allowed the growth of significant Antarctic ice sheets by around 34 Ma. Instead, variation in area of continental basaltic provinces in the equatorial humid belt (5° S-5° N) seems to be the dominant control on how much CO2 is retained in the atmosphere via the silicate weathering feedback. The arrival of the highly weatherable Deccan Traps in the equatorial humid belt at around 50 Ma was decisive in initiating the long-term slide to lower atmospheric pCO2, which was pushed further down by the emplacement of the 30 Ma Ethiopian Traps near the equator and the southerly tectonic extrusion of SE Asia, an arc terrane that presently is estimated to account for 1/4 of CO2 consumption from all basaltic provinces that account for ~1/3 of the total CO2 consumption by continental silicate weathering (Dessert et al., 2003). A negative climate-feedback mechanism that

  18. Cockpit weather information needs

    NASA Technical Reports Server (NTRS)

    Scanlon, Charles H.

    1992-01-01

    The primary objective is to develop an advanced pilot weather interface for the flight deck and to measure its utilization and effectiveness in pilot reroute decision processes, weather situation awareness, and weather monitoring. Identical graphical weather displays for the dispatcher, air traffic control (ATC), and pilot crew should also enhance the dialogue capabilities for reroute decisions. By utilizing a broadcast data link for surface observations, forecasts, radar summaries, lightning strikes, and weather alerts, onboard weather computing facilities construct graphical displays, historical weather displays, color textual displays, and other tools to assist the pilot crew. Since the weather data is continually being received and stored by the airborne system, the pilot crew has instantaneous access to the latest information. This information is color coded to distinguish degrees of category for surface observations, ceiling and visibilities, and ground radar summaries. Automatic weather monitoring and pilot crew alerting is accomplished by the airborne computing facilities. When a new weather information is received, the displays are instantaneously changed to reflect the new information. Also, when a new surface or special observation for the intended destination is received, the pilot crew is informed so that information can be studied at the pilot's discretion. The pilot crew is also immediately alerted when a severe weather notice, AIRMET or SIGMET, is received. The cockpit weather display shares a multicolor eight inch cathode ray tube and overlaid touch panel with a pilot crew data link interface. Touch sensitive buttons and areas are used for pilot selection of graphical and data link displays. Time critical ATC messages are presented in a small window that overlays other displays so that immediate pilot alerting and action can be taken. Predeparture and reroute clearances are displayed on the graphical weather system so pilot review of weather along

  19. Pilot Weather Advisor System

    NASA Technical Reports Server (NTRS)

    Lindamood, Glenn; Martzaklis, Konstantinos Gus; Hoffler, Keith; Hill, Damon; Mehrotra, Sudhir C.; White, E. Richard; Fisher, Bruce D.; Crabill, Norman L.; Tucholski, Allen D.

    2006-01-01

    The Pilot Weather Advisor (PWA) system is an automated satellite radio-broadcasting system that provides nearly real-time weather data to pilots of aircraft in flight anywhere in the continental United States. The system was designed to enhance safety in two distinct ways: First, the automated receipt of information would relieve the pilot of the time-consuming and distracting task of obtaining weather information via voice communication with ground stations. Second, the presentation of the information would be centered around a map format, thereby making the spatial and temporal relationships in the surrounding weather situation much easier to understand

  20. The Weather and Climate Toolkit

    NASA Astrophysics Data System (ADS)

    Ansari, S.; Del Greco, S.; Hankins, B.

    2010-12-01

    The Weather and Climate Toolkit (WCT) is free, platform independent software distributed from NOAA’s National Climatic Data Center (NCDC). The WCT allows the visualization and data export of weather and climate data, including Radar, Satellite and Model data. By leveraging the NetCDF for Java library and Common Data Model, the WCT is extremely scalable and capable of supporting many new datasets in the future. Gridded NetCDF files (regular and irregularly spaced, using Climate-Forecast (CF) conventions) are supported, along with many other formats including GRIB. The WCT provides tools for custom data overlays, Web Map Service (WMS) background maps, animations and basic filtering. The export of images and movies is provided in multiple formats. The WCT Data Export Wizard allows for data export in both vector polygon/point (Shapefile, Well-Known Text) and raster (GeoTIFF, ESRI Grid, VTK, Gridded NetCDF) formats. These data export features promote the interoperability of weather and climate information with various scientific communities and common software packages such as ArcGIS, Google Earth, MatLAB, GrADS and R. The WCT also supports an embedded, integrated Google Earth instance. The Google Earth Browser Plugin allows seamless visualization of data on a native 3-D Google Earth instance linked to the standard 2-D map. Level-II NEXRAD data for Hurricane Katrina GPCP (Global Precipitation Product), visualized in 2-D and internal Google Earth view.

  1. Weather and emotional state

    NASA Astrophysics Data System (ADS)

    Spasova, Z.

    2010-09-01

    Introduction Given the proven effects of weather on the human organism, an attempt to examine its effects on a psychic and emotional level has been made. Emotions affect the bio-tonus, working ability and concentration, hence their significance in various domains of economic life, such as health care, education, transportation, tourism, etc. Data and methods The research has been made in Sofia City within a period of 8 months, using 5 psychological methods (Eysenck Personality Questionnaire (EPQ), State-Trait Anxiety Inventory (STAI), Test for Self-assessment of the emotional state (developed by Wessman and Ricks), Test for evaluation of moods and Test "Self-confidence - Activity - Mood" (developed by the specialists from the Military Academy in Saint Petersburg). The Fiodorov-Chubukov's complex-climatic method was used to characterize meteorological conditions because of the purpose to include in the analysis a maximal number of meteorological elements. 16 weather types are defined in dependence of the meteorological elements values according to this method. Abrupt weather changes from one day to another, defined by the same method, were considered as well. Results and discussions The results obtained by t-test show that the different categories of weather lead to changes in the emotional status, which indicates a character either positive or negative for the organism. The abrupt weather changes, according to expectations, have negative effect on human emotions but only when a transition to the cloudy weather or weather type, classified as "unfavourable" has been realized. The relationship between weather and human emotions is rather complicated since it depends on individual characteristics of people. One of these individual psychological characteristics, marked by the dimension "neuroticism", has a strong effect on emotional reactions in different weather conditions. Emotionally stable individuals are more "protected" to the weather influence on their emotions

  2. Laser processing of siliceous materials

    NASA Astrophysics Data System (ADS)

    Panzner, Michael; Lenk, Andreas; Wiedemann, Guenter R.; Hauptmann, Jan; Weiss, Hans J.; Ruemenapp, Thomas; Morgenthal, Lothar; Beyer, Eckhard

    2000-08-01

    Laser processing of siliceous materials becomes increasingly important. Analogous to the laser processing of conventional materials there are applications in the fields of cleaning, surface processing, cutting, etc. The present paper concerns the state of the art and new applications: (1) Laser cleaning of natural stone surfaces. The good disability allows restoration work to be carried out conveniently, as for example the complete removal of crusts or the removal to such degree that moisture is not trapped beneath. (2) Non-slip finish of polished natural stone surfaces: The excellent focusing of laser beams on spots as small as 100 micrometer and below can be exploited to produce macroscopically invisible structures on the surfaces of different materials. This permits microscopically small craters and lentil shaped depressions to be generated on the stone surface. Therefore it is possible to provide a non-slip finish to polished natural stone surfaces without noticeably impairing the gloss. (3) Concrete cutting: In Europe, and particularly in Germany, there is a growing demand for redevelopment of concrete apartment buildings, involving the removal of non-bearing walls and the cutting of openings. The temporal relocation of residents due to the noise and moisture from the use of diamond tools could be avoided by applying a laser cutting technology. With a 3 kW-Nd-YAG-laser, 70 mm concrete can be cut with rates up to 25 mm/min.

  3. Organically modified silicate aerogels, ``Aeromosils``

    SciTech Connect

    Kramer, S.J.; Mackenzie, J.D.; Rubio-Alonso, F.

    1996-12-31

    Aerogels derived from sol-gel oxides such as silica have become quite scientifically popular because of their extremely low densities, high surface areas, and their interesting optical, dielectric, thermal and acoustic properties. However, their commercial applicability has thus far been rather limited, due in great part to their brittleness and hydrophilicity. In prior work by the research group, modifying silicate gel structures with flexible, organic containing polymers such as polydimethylsiloxane imparted significant compliance (even rubbery behavior) and hydrophobicity. These materials have been referred to as Ormosils. This study expounds on the current effort to extend these desirable properties to aerogels, and in-so-doing, creating novel ``Aeromosils``. Reactive incorporation of hydroxy-terminal polydimethylsiloxane (PDMS) into silica sol-gels was made using both acid and two-step acid/base catalyzed processes. Aerogels were derived by employing the supercritical CO{sub 2} technique. Analyses of microstructure were made using nitrogen adsorption (BET surface area and pore size distribution), and some mechanical strengths were derived from tensile strength testing. Interesting Aeromosil properties obtained include optical transparency, surface areas of up to 1,200 m{sup 2}/g, rubberiness, and better strength than corresponding silica aerogels with elongations at break exceeding 5% in some cases.

  4. Weathering Database Technology

    ERIC Educational Resources Information Center

    Snyder, Robert

    2005-01-01

    Collecting weather data is a traditional part of a meteorology unit at the middle level. However, making connections between the data and weather conditions can be a challenge. One way to make these connections clearer is to enter the data into a database. This allows students to quickly compare different fields of data and recognize which…

  5. Designing a Weather Station

    ERIC Educational Resources Information Center

    Roman, Harry T.

    2012-01-01

    The collection and analysis of weather data is crucial to the location of alternate energy systems like solar and wind. This article presents a design challenge that gives students a chance to design a weather station to collect data in advance of a large wind turbine installation. Data analysis is a crucial part of any science or engineering…

  6. KSC Weather and Research

    NASA Technical Reports Server (NTRS)

    Maier, Launa; Huddleston, Lisa; Smith, Kristin

    2016-01-01

    This briefing outlines the history of Kennedy Space Center (KSC) Weather organization, past research sponsored or performed, current organization, responsibilities, and activities, the evolution of weather support, future technologies, and an update on the status of the buoys located offshore of Cape Canaveral Air Force Station and KSC.

  7. Weather Fundamentals: Clouds. [Videotape].

    ERIC Educational Resources Information Center

    1998

    The videos in this educational series, for grades 4-7, help students understand the science behind weather phenomena through dramatic live-action footage, vivid animated graphics, detailed weather maps, and hands-on experiments. This episode (23 minutes) discusses how clouds form, the different types of clouds, and the important role they play in…

  8. Home Weatherization Visit

    ScienceCinema

    Chu, Steven

    2016-07-12

    Secretary Steven Chu visits a home that is in the process of being weatherized in Columbus, OH, along with Ohio Governor Ted Strickland and Columbus Mayor Michael Coleman. They discuss the benefits of weatherization and how funding from the recovery act is having a direct impact in communities across America.

  9. On Observing the Weather

    ERIC Educational Resources Information Center

    Crane, Peter

    2004-01-01

    Rain, sun, snow, sleet, wind... the weather affects everyone in some way every day, and observing weather is a terrific activity to attune children to the natural world. It is also a great way for children to practice skills in gathering and recording information and to learn how to use simple tools in a standardized fashion. What better way to…

  10. Weather Cardboard Carpentry

    ERIC Educational Resources Information Center

    DeBruin, Jerome E.

    1977-01-01

    Included are instructions and diagrams for building weather instruments (wind vane, Celsius temperature scale, and anemometer) from simple tools and Tri-Wall, a triple-thick corrugated cardboard. Ordering sources for Tri-Wall are listed. Additional weather instruments that can be constructed are suggested. (CS)

  11. Tracking Weather Satellites.

    ERIC Educational Resources Information Center

    Martin, Helen E.

    1996-01-01

    Describes the use of weather satellites in providing an exciting, cohesive framework for students learning Earth and space science and in providing a hands-on approach to technology in the classroom. Discusses the history of weather satellites and classroom satellite tracking. (JRH)

  12. Weatherizing a Structure.

    ERIC Educational Resources Information Center

    Metz, Ron

    This instructional unit is one of 10 developed by students on various energy-related areas that deals specifically with weatherizing a structure. Its objective is for the student to be able to analyze factors related to specific structures that indicate need for weatherizing activities and to determine steps to correct defects in structures that…

  13. Teacher's Weather Sourcebook.

    ERIC Educational Resources Information Center

    Konvicka, Tom

    This book is a teaching resource for the study of weather-related phenomena. A "weather unit" is often incorporated into school study because of its importance to our daily lives and because of its potential to cut across disciplinary content. This book consists of two parts. Part I covers the major topics of atmospheric science such as the modern…

  14. Mild and Wild Weather.

    ERIC Educational Resources Information Center

    NatureScope, 1985

    1985-01-01

    Presents background information and six activities that focus on clouds, precipitation, and stormy weather. Each activity includes an objective, recommended age level(s), subject area(s), and instructional strategies. Also provided are two ready-to-copy pages (a coloring page on lightning and a list of weather riddles to solve). (JN)

  15. Weather Fundamentals: Wind. [Videotape].

    ERIC Educational Resources Information Center

    1998

    The videos in this educational series, for grades 4-7, help students understand the science behind weather phenomena through dramatic live-action footage, vivid animated graphics, detailed weather maps, and hands-on experiments. This episode (23 minutes) describes the roles of the sun, temperature, and air pressure in creating the incredible power…

  16. The Home Weather Station.

    ERIC Educational Resources Information Center

    Steinke, Steven D.

    1991-01-01

    Described is how an amateur weather observer measures and records temperature and precipitation at a well-equipped, backyard weather station. Directions for building an instrument shelter and a description of the instruments needed for measuring temperature and precipitation are included. (KR)

  17. Fabulous Weather Day

    ERIC Educational Resources Information Center

    Marshall, Candice; Mogil, H. Michael

    2007-01-01

    Each year, first graders at Kensington Parkwood Elementary School in Kensington, Maryland, look forward to Fabulous Weather Day. Students learn how meteorologists collect data about the weather, how they study wind, temperature, precipitation, basic types/characteristics of clouds, and how they forecast. The project helps the students grow in…

  18. Improved alkali-metal/silicate binders

    NASA Technical Reports Server (NTRS)

    Schutt, J.

    1978-01-01

    Family of inorganic binders utilizes potassium or sodium oxide/silicate dispersion and employs high mole ratio of silicon dioxide to alkali-metal binder. Binders are stable, inexpensive, extremely water resistant, and easy to apply.

  19. A Weathering Index for CK and R Chondrites

    NASA Technical Reports Server (NTRS)

    Rubin, Alan E.; Huber, Heinz

    2006-01-01

    We present a new weathering index (wi) for the metallic-Fe-Ni-poor chondrite groups (CK and R) based mainly on transmitted light observations of the modal abundance of crystalline material that is stained brown in thin sections: wi-0, <5 vol%; wi-1, 5-25 vol%; wi-2,25-50 vol%; wi-3,50- 75 vol%; wi-4, 75-95 vol%; wi-5, >95 vol%, wi-6, significant replacement of mafic silicates by phyllosilicates. Brown staining reflects mobilization of oxidized iron derived mainly from terrestrial weathering of Ni-bearing sulfide. With increasing degrees of terrestrial weathering of CK and R chondrites, the sulfide modal abundance decreases, and S, Se, and Ni become increasingly depleted. In addition, bulk Cl increases in Antarctic CK chondrites, probably due to contamination from airborne sea mist.

  20. Chemical weathering inferred from riverine water chemistry in the lower Xijiang basin, South China.

    PubMed

    Sun, Huiguo; Han, Jingtai; Li, Dong; Zhang, Shurong; Lu, Xixi

    2010-09-15

    Seasonal sampling was conducted on 13 sites involving the lower stem of the Xijiang river and its three tributaries to determine the spatial patterns of the riverine water chemistry and to quantify the chemical weathering rates of carbonate and silicate of the bedrock. Results indicate that the major ions in the Xijiang river system are dominated by Ca(2+) and HCO(3)(-) with a higher concentration of total dissolved solids, characteristic of the drainages developed on typical carbonate regions. Obvious spatial variations of major ion concentrations are found at various spatial scales, which are dominantly controlled by the lithology particularly carbonate distribution in the region. The four selected rivers show similar seasonal variations in major ions, with lower concentrations during the rainy season. Runoff is the first important factor for controlling the weathering rate in the basin, although increasing temperature and duration of water-rock interaction could make positive contributions to the enhancement of chemical weathering. The chemical weathering rates range from 52.6 to 73.7 t/km(2)/yr within the lower Xijiang basin and carbonate weathering is over one order of magnitude higher than that of silicates. CO(2) consumption rate by rock weathering is 2.0 x 10(11) mol/yr, of which more than 60% is contributed by carbonate weathering. The flux of CO(2) released to the atmosphere-ocean system by sulfuric acid-induced carbonate weathering is 1.1 x 10(5) mol/km(2)/yr, comparable with the CO(2) flux consumed by silicate weathering.

  1. NASA Connect: 'Plane Weather'

    NASA Technical Reports Server (NTRS)

    1999-01-01

    Excerpt from the NASA Connect show 'Plane Weather' This clip explains what high and low pressure weather systems are, and how they form. Weather affects our daily lives. The elements of weather: rain, wind, fog, ice and snow affect the operation and flight of an airplane. In this program, NASA and FAA researchers will introduce students to math, science, and weather; demonstrate how these elements influence flight; and show how NASA and FAA research is used to limit the effects of these elements on flight. Students will examine: the tools, techniques, and technologies used by engineers and scientists to detect these and other climatological factors affecting aircraft in flight. The lesson and classroom experiment will involve students in the scientific process and emphasizing problem solving, measurement, and reasoning skills.

  2. Influence of Silicate Melt Composition on Metal/Silicate Partitioning of W, Ge, Ga and Ni

    NASA Technical Reports Server (NTRS)

    Singletary, S. J.; Domanik, K.; Drake, M. J.

    2005-01-01

    The depletion of the siderophile elements in the Earth's upper mantle relative to the chondritic meteorites is a geochemical imprint of core segregation. Therefore, metal/silicate partition coefficients (Dm/s) for siderophile elements are essential to investigations of core formation when used in conjunction with the pattern of elemental abundances in the Earth's mantle. The partitioning of siderophile elements is controlled by temperature, pressure, oxygen fugacity, and by the compositions of the metal and silicate phases. Several recent studies have shown the importance of silicate melt composition on the partitioning of siderophile elements between silicate and metallic liquids. It has been demonstrated that many elements display increased solubility in less polymerized (mafic) melts. However, the importance of silicate melt composition was believed to be minor compared to the influence of oxygen fugacity until studies showed that melt composition is an important factor at high pressures and temperatures. It was found that melt composition is also important for partitioning of high valency siderophile elements. Atmospheric experiments were conducted, varying only silicate melt composition, to assess the importance of silicate melt composition for the partitioning of W, Co and Ga and found that the valence of the dissolving species plays an important role in determining the effect of composition on solubility. In this study, we extend the data set to higher pressures and investigate the role of silicate melt composition on the partitioning of the siderophile elements W, Ge, Ga and Ni between metallic and silicate liquid.

  3. Peralkaline silicic volcanic rocks in northwestern nevada.

    PubMed

    Noble, D C; Chipman, D W; Giles, D L

    1968-06-21

    Late Tertiary silicic ashflow tuffs and lavas peralkaline in chemical character (atomic Na + K greater than Al), mainly comendites, occur over wide areas in northwestern Nevada and appear to be widespread in southeastern Oregon. Such peralkaline rocks-which are not uncommon in the western United States-and other chemically unusual silicic rocks are found near the margins rather than toward the center of the Great Basin.

  4. Weather in Mountainous Terrain (Overcoming Scientific Barriers to Weather Support)

    DTIC Science & Technology

    2011-02-15

    Weather in Mountainous Terrain (Overcoming Scientific Barriers to Weather Support) Fiesta Resort & Conference Center Tempe, AZ February 1...Meteorology Overcoming Scientific Barriers to Weather Support Fiesta Resort & Conference Center Tempe, AZ February 1 & 2, 2010 Hosted by University

  5. Biological and Organic Chemical Decomposition of Silicates. Chapter 7.2

    NASA Technical Reports Server (NTRS)

    Sliverman, M. P.

    1979-01-01

    The weathering of silicate rocks and minerals, an important concern of geologists and geochemists for many years, traditionally has been approached from strictly physical and chemical points of view. Biological effects were either unrecognized, ignored, or were mentioned in passing to account for such phenomena as the accumulation of organic matter in sediments or the generation of reducing environments. A major exception occurred in soil science where agricultural scientists, studying the factors important in the development of soils and their ability to nourish and sustain various crops, laid the foundation for much of what is known of the biological breakdown of silicate rocks and minerals. The advent of the space age accelerated the realization that many environmental problems and geochemical processes on Earth can only be understood in terms of ecosystems. This in turn, spurred renewed interest and activity among modem biologists, geologists and soil scientists attempting to unravel the intimate relations between biology and the weathering of silicate rocks and minerals of the earth's surface.

  6. Biological and Organic Chemical Decomposition of Silicates. Chapter 7.2

    NASA Technical Reports Server (NTRS)

    Silverman, M. P.

    1979-01-01

    The weathering of silicate rocks and minerals, an important concern of geologists and geochemists for many years, traditionally has been approached from strictly physical and chemical points of view. Biological effects were either unrecognized, ignored, or were mentioned in passing to account for such phenomena as the accumulation of organic matter in sediments or the generation of reducing environments. A major exception occurred in soil science where agricultural scientists, studying the factors important in the development of soils and their ability to nourish and sustain various crops, laid the foundation for much of what is known of the biological breakdown of silicate rocks and minerals. The advent of the space age accelerated the realization that many environmental problems and geo- chemical processes on Earth can only be understood in terms of ecosystems. This in turn, spurred renewed interest and activity among modem biologists, geologists and soil scientists attempting to unravel the intimate relations between biology and the weathering of silicate rocks and minerals of the earth surface.

  7. Major ion chemistry of the Ganga-Brahmaputra river system: Weathering processes and fluxes to the Bay of Bengal

    SciTech Connect

    Sarin, M.M.; Krishnaswami, S.; Dilli, K.; Somayajulu, B.L.K. ); Moore, W.S. )

    1989-05-01

    The Ganga-Brahmaputra, one of the worlds's largest river systems, is first in terms of sediment transport and fourth in terms of water discharge. A detailed and systematic study of the major ion chemistry of these rivers and their tributaries, as well as the clay mineral composition of the bed sediments has been conducted. The chemistry of the highland rivers are all dominated by carbonate weathering; (Ca + Mg) and HCO{sub 3} account for about 80% of the cations and anions. In the lowland rivers, HCO{sub 3} excess over (Ca + Mg) and a relatively high contribution of (Na + K) to the total cations indicate that silicate weathering and/or contributions from alkaline/saline soils and ground waters could be important sources of major ions to these waters. The chemistry of the Ganga and the Yamuna in the lower reaches is by and large dictated by the chemistry of their tributaries and their mixing proportions. The highland rivers weather acidic rocks, whereas the others flow initially through basic effusives. The Ganga-Brahmaputra river system transports about 130 million tons of dissolved salts to the Bay of Bengal, which is nearly 3% of the global river flux to the oceans. The chemical denudation rates for the Ganga and the Brahmaputra basins are about 72 and 105 tons{center dot}km{sup {minus}2}{center dot}yr{sup {minus}1}, respectively, which are factors of 2 to 3 higher than the global average. The high denudation rate, particularly in the Brahmaputra, is attributable to high relief and heavy rainfall.

  8. Thermodynamics and Kinetics of Silicate Vaporization

    NASA Technical Reports Server (NTRS)

    Jacobson, Nathan S.; Costa, Gustavo C. C.

    2015-01-01

    Silicates are a common class of materials that are often exposed to high temperatures. The behavior of these materials needs to be understood for applications as high temperature coatings in material science as well as the constituents of lava for geological considerations. The vaporization behavior of these materials is an important aspect of their high temperature behavior and it also provides fundamental thermodynamic data. The application of Knudsen effusion mass spectrometry (KEMS) to silicates is discussed. There are several special considerations for silicates. The first is selection of an appropriate cell material, which is either nearly inert or has well-understood interactions with the silicate. The second consideration is proper measurement of the low vapor pressures. This can be circumvented by using a reducing agent to boost the vapor pressure without changing the solid composition or by working at very high temperatures. The third consideration deals with kinetic barriers to vaporization. The measurement of these barriers, as encompassed in a vaporization coefficient, is discussed. Current measured data of rare earth silicates for high temperature coating applications are discussed. In addition, data on magnesium-iron-silicates (olivine) are presented and discussed.

  9. Mars surface weathering products and spectral analogs: Palagonites and synthetic iron minerals

    NASA Technical Reports Server (NTRS)

    Golden, D. C.; Ming, D. W.; Morris, R. V.; Lauer, H. V., Jr.

    1992-01-01

    There are several hypotheses regarding the formation of Martian surface fines. These surface fines are thought to be products of weathering processes occurring on Mars. Four major weathering environments of igneous rocks on Mars have been proposed; (1) impact induced hydrothermal alterations; (2) subpermafrost igneous intrusion; (3) solid-gas surface reactions; and (4) subaerial igneous intrusion over permafrost. Although one or more of these processes may be important on the Martian surface, one factor in common for all these processes is the reaction of solid or molten basalt with water (solid, liquid, or gas). These proposed processes, with the exception of solid-gas surface reactions, are transient processes. The most likely product of transient hydrothermal processes are layer silicates, zeolites, hydrous iron oxides and palagonites. The long-term instability of hydrous clay minerals under present Martian conditions has been predicted; however, the persistence of such minerals due to slow kinetics of dehydration, or entrapment in permafrost, where the activity of water is high, can not be excluded. Anhydrous oxides of iron (e.g., hematite and maghemite) are thought to be stable under present Martian surface conditions. Oxidative weathering of sulfide minerals associated with Martian basalts has been proposed. Weathering of sulfide minerals leads to a potentially acidic permafrost and the formation of Fe(3) oxides and sulfates. Weathering of basalts under acidic conditions may lead to the formation of kaolinite through metastable halloysite and metahalloysite. Kaolinite, if present, is thought to be a thermodynamically stable phase at the Martian surface. Fine materials on Mars are important in that they influence the surface spectral properties; these fines are globally distributed on Mars by the dust storms and this fraction will have the highest surface area which should act as a sink for most of the absorbed volatiles near the surface of Mars. Therefore

  10. Interpreting the 10 micron Astronomical Silicate Feature

    NASA Astrophysics Data System (ADS)

    Bowey, Janet E.

    1998-11-01

    10micron spectra of silicate dust in the diffuse medium towards Cyg OB2 no. 12 and towards field and embedded objects in the Taurus Molecular Cloud (TMC) were obtained with CGS3 at the United Kingdom Infrared Telescope (UKIRT). Cold molecular-cloud silicates are sampled in quiescent lines of sight towards the field stars Taurus-Elias 16 and Elias 13, whilst observations of the embedded young stellar objects HL Tau, Taurus-Elias 7 (Haro6-10) and Elias 18 also include emission from heated dust. To obtain the foreground silicate absorption profiles, featureless continua are estimated using smoothed astronomical and laboratory silicate emissivities. TMC field stars and Cyg OB2 no. 12 are modelled as photospheres reddened by foreground continuum and silicate extinction. Dust emission in the non-photospheric continua of HL Tau and Elias 7 (Haro6-10) is distinguished from foreground silicate absorption using a 10micron disk model, based on the IR-submm model of T Tauri stars by Adams, Lada & Shu (1988), with terms added to represent the foreground continuum and silicate extinction. The absorption profiles of HL Tau and Elias 7 are similar to that of the field star Elias 16. Fitted temperature indices of 0.43 (HL Tau) and 0.33 (Elias 7) agree with Boss' (1996) theoretical models of the 200-300K region, but are lower than those of IR-submm disks (0.5-0.61; Mannings & Emerson 1994); the modelled 10micron emission of HL Tau is optically thin, that of Elias 7 is optically thick. A preliminary arcsecond-resolution determination of the 10micron emissivity near θ1 Ori D in the Trapezium region of Orion and a range of emission temperatures (225-310K) are derived from observations by T. L. Hayward; this Ney-Allen emissivity is 0.6micron narrower than the Trapezium emissivity obtained by Forrest et al. (1975) with a large aperture. Published interstellar grain models, elemental abundances and laboratory studies of Solar System silicates (IDPs, GEMS and meteorites), the 10micron

  11. HRTEM/AEM study of trace metal behavior, sheet silicate reactions, and fluid/solid mass balances in porphyry copper hydrothermal systems

    SciTech Connect

    Veblen, D.R.; Ilton, E.S.

    1989-04-01

    Transmission electron microscopy has been used to investigate copper (Cu) incorporation into silicates and alteration reactions in porphyry copper deposits. High Cu in biotites results from submicroscopic inclusions of native Cu. The incorporation of Cu in low-temperature alteration lamellae suggests that Cu enrichment occurs during weathering, rather than during the hydrothermal event. Drill core from Cyprus Casa Grande, Arizona, shows systematic variation of Cu in sheet silicates as a function of depth in the weathering column. The aims of the present project are to apply the powerful techniques of transmission electron microscopy (TEM), high-resolution TEM (HRTEM), and analytical electron microscopy (AEM) to understanding the geochemical processes in porphyry copper systems at the near-atomic scale. Our primary goals are to characterize the structural state of anomalously high Cu in silicates, determine the timing and conditions of Cu enrichment in silicates such as biotite, and use these data to suggest how base metals are released and subsequently immobilized under hydrothermal or weathering conditions; and to determine the submicroscopic, atomic-level reaction mechanisms responsible for silicate alteration in porphyry-copper hydrothermal systems, which will allow us to determine reaction stoichiometries and hence mass balances between minerals and hydrothermal fluid. 19 refs., 7 figs., 3 tabs.

  12. Perceptions of enhanced weathering as a biological negative emissions option.

    PubMed

    Pidgeon, Nick F; Spence, Elspeth

    2017-04-01

    This paper addresses the social acceptability of enhanced weathering, a technology that would involve spreading silicate particles over terrestrial surfaces in order to boost the biological processes that currently sequester CO2 as part of the earth's natural carbon cycle. We present the first exploration of British attitudes towards enhanced weathering, using an online survey (n = 935) of a representative quota sample of the public. Baseline awareness of weathering was extremely low. Many respondents remained undecided or neutral about risks, although more people support than oppose weathering. Factors predicting support for weathering and its research included feelings about the technology and trust in scientists. Over half of the sample agrees that scientists should be able to conduct research into effectiveness and risks, but with conditions also placed upon how research is conducted, including the need for scientific independence, small-scale trials, strict monitoring, risk minimization and transparency of results. Public engagement is needed to explore in more detail why particular individuals feel either positive or negative about weathering, and why they believe particular conditions should be applied to research, as part of wider responsible research and innovation processes for biological and other types of negative emissions technologies.

  13. Detection of solar wind-produced water in irradiated rims on silicate minerals.

    PubMed

    Bradley, John P; Ishii, Hope A; Gillis-Davis, Jeffrey J; Ciston, James; Nielsen, Michael H; Bechtel, Hans A; Martin, Michael C

    2014-02-04

    The solar wind (SW), composed of predominantly ∼1-keV H(+) ions, produces amorphous rims up to ∼150 nm thick on the surfaces of minerals exposed in space. Silicates with amorphous rims are observed on interplanetary dust particles and on lunar and asteroid soil regolith grains. Implanted H(+) may react with oxygen in the minerals to form trace amounts of hydroxyl (-OH) and/or water (H2O). Previous studies have detected hydroxyl in lunar soils, but its chemical state, physical location in the soils, and source(s) are debated. If -OH or H2O is generated in rims on silicate grains, there are important implications for the origins of water in the solar system and other astrophysical environments. By exploiting the high spatial resolution of transmission electron microscopy and valence electron energy-loss spectroscopy, we detect water sealed in vesicles within amorphous rims produced by SW irradiation of silicate mineral grains on the exterior surfaces of interplanetary dust particles. Our findings establish that water is a byproduct of SW space weathering. We conclude, on the basis of the pervasiveness of the SW and silicate materials, that the production of radiolytic SW water on airless bodies is a ubiquitous process throughout the solar system.

  14. Detection of solar wind-produced water in irradiated rims on silicate minerals

    PubMed Central

    Bradley, John P.; Ishii, Hope A.; Gillis-Davis, Jeffrey J.; Ciston, James; Nielsen, Michael H.; Bechtel, Hans A.; Martin, Michael C.

    2014-01-01

    The solar wind (SW), composed of predominantly ∼1-keV H+ ions, produces amorphous rims up to ∼150 nm thick on the surfaces of minerals exposed in space. Silicates with amorphous rims are observed on interplanetary dust particles and on lunar and asteroid soil regolith grains. Implanted H+ may react with oxygen in the minerals to form trace amounts of hydroxyl (−OH) and/or water (H2O). Previous studies have detected hydroxyl in lunar soils, but its chemical state, physical location in the soils, and source(s) are debated. If −OH or H2O is generated in rims on silicate grains, there are important implications for the origins of water in the solar system and other astrophysical environments. By exploiting the high spatial resolution of transmission electron microscopy and valence electron energy-loss spectroscopy, we detect water sealed in vesicles within amorphous rims produced by SW irradiation of silicate mineral grains on the exterior surfaces of interplanetary dust particles. Our findings establish that water is a byproduct of SW space weathering. We conclude, on the basis of the pervasiveness of the SW and silicate materials, that the production of radiolytic SW water on airless bodies is a ubiquitous process throughout the solar system. PMID:24449869

  15. Modulation of Late Cretaceous and Cenozoic climate by variable drawdown of atmospheric pCO2 from weathering of basaltic provinces on continents drifting through the equatorial humid belt

    NASA Astrophysics Data System (ADS)

    Kent, D. V.; Muttoni, G.

    2013-03-01

    The small reservoir of carbon dioxide in the atmosphere (pCO2) that modulates climate through the greenhouse effect reflects a delicate balance between large fluxes of sources and sinks. The major long-term source of CO2 is global outgassing from sea-floor spreading, subduction, hotspot activity, and metamorphism; the ultimate sink is through weathering of continental silicates and deposition of carbonates. Most carbon cycle models are driven by changes in the source flux scaled to variable rates of ocean floor production, but ocean floor production may not be distinguishable from being steady since 180 Ma. We evaluate potential changes in sources and sinks of CO2 for the past 120 Ma in a paleogeographic context. Our new calculations show that decarbonation of pelagic sediments by Tethyan subduction contributed only modestly to generally high pCO2 levels from the Late Cretaceous until the early Eocene, and thus shutdown of this CO2 source with the collision of India and Asia at the early Eocene climate optimum at around 50 Ma was inadequate to account for the large and prolonged decrease in pCO2 that eventually allowed the growth of significant Antarctic ice sheets by around 34 Ma. Instead, variation in area of continental basalt terranes in the equatorial humid belt (5° S-5° N) seems to be a dominant factor controlling how much CO2 is retained in the atmosphere via the silicate weathering feedback. The arrival of the highly weatherable Deccan Traps in the equatorial humid belt at around 50 Ma was decisive in initiating the long-term slide to lower atmospheric pCO2, which was pushed further down by the emplacement of the 30 Ma Ethiopian Traps near the equator and the southerly tectonic extrusion of SE Asia, an arc terrane that presently is estimated to account for 1/4 of CO2 consumption from all basaltic provinces that account for ~1/3 of the total CO2 consumption by continental silicate weathering (Dessert et al., 2003). A negative climate-feedback mechanism

  16. Environmental Education Tips: Weather Activities.

    ERIC Educational Resources Information Center

    Brainard, Audrey H.

    1989-01-01

    Provides weather activities including questions, on weather, heating the earth's surface, air, tools of the meteorologist, clouds, humidity, wind, and evaporation. Shows an example of a weather chart activity. (RT)

  17. Weather--An Integrated Unit

    ERIC Educational Resources Information Center

    McConnell, Vivian

    1976-01-01

    Outlined is a two week unit on weather offered as independent study for sixth- and seventh-year students in Vancouver, Canada, schools. Included is a section on weather lore and a chart of weather symbols. (SL)

  18. Cloud information for FIRE from surface weather reports

    NASA Technical Reports Server (NTRS)

    Hahn, Carole J.; Warren, Stephen G.; London, Julius

    1990-01-01

    Surface weather observations of clouds were analyzed to obtain a global cloud climatology (Warren et al, 1986; 1988). The form of the synoptic weather code limits the types of cloud information which are available from these reports. Comparison of surface weather reports with instrumental observations during the FIRE field experiments can help to clarify the operational definitions which were made in the climatology because of the nature of the synoptic code. The long-term climatology from surface weather observations is also useful background for planning the location and timing of intensive field experiments.

  19. NASA's Sentinels Monitoring Weather and Climate: Past, Present, and Future

    NASA Technical Reports Server (NTRS)

    Shepherd, J. Marshall; Herring, David; Gutro, Rob; Huffman, George; Halverson, Jeff

    2002-01-01

    Weatherwise is probably the most popular newstand magazine focusing on the subject of weather. It is published six times per year and includes features on weather, climate, and technology. This article (to appear in the January/February Issue) provides a comprehensive review of NASA s past, present, and future contributions in satellite remote sensing for weather and climate processes. The article spans the historical strides of the TIROS program through the scientific and technological innovation of Earth Observer-3 and Global Precipitation Measurement (GPM). It is one of the most thorough reviews of NASA s weather and climate satellite efforts to appear in the popular literature.

  20. Abrupt response of chemical weathering to Late Quaternary hydroclimate changes in northeast Africa.

    PubMed

    Bastian, Luc; Revel, Marie; Bayon, Germain; Dufour, Aurélie; Vigier, Nathalie

    2017-03-14

    Chemical weathering of silicate rocks on continents acts as a major sink for atmospheric carbon dioxide and has played an important role in the evolution of the Earth's climate. However, the magnitude and the nature of the links between weathering and climate are still under debate. In particular, the timescale over which chemical weathering may respond to climate change is yet to be constrained at the continental scale. Here we reconstruct the relationships between rainfall and chemical weathering in northeast Africa for the last 32,000 years. Using lithium isotopes and other geochemical proxies in the clay-size fraction of a marine sediment core from the Eastern Mediterranean Sea, we show that chemical weathering in the Nile Basin fluctuated in parallel with the monsoon-related climatic evolution of northeast Africa. We also evidence strongly reduced mineral alteration during centennial-scale regional drought episodes. Our findings indicate that silicate weathering may respond as quickly as physical erosion to abrupt hydroclimate reorganization on continents. Consequently, we anticipate that the forthcoming hydrological disturbances predicted for northeast Africa may have a major impact on chemical weathering patterns and soil resources in this region.

  1. Abrupt response of chemical weathering to Late Quaternary hydroclimate changes in northeast Africa

    PubMed Central

    Bastian, Luc; Revel, Marie; Bayon, Germain; Dufour, Aurélie; Vigier, Nathalie

    2017-01-01

    Chemical weathering of silicate rocks on continents acts as a major sink for atmospheric carbon dioxide and has played an important role in the evolution of the Earth’s climate. However, the magnitude and the nature of the links between weathering and climate are still under debate. In particular, the timescale over which chemical weathering may respond to climate change is yet to be constrained at the continental scale. Here we reconstruct the relationships between rainfall and chemical weathering in northeast Africa for the last 32,000 years. Using lithium isotopes and other geochemical proxies in the clay-size fraction of a marine sediment core from the Eastern Mediterranean Sea, we show that chemical weathering in the Nile Basin fluctuated in parallel with the monsoon-related climatic evolution of northeast Africa. We also evidence strongly reduced mineral alteration during centennial-scale regional drought episodes. Our findings indicate that silicate weathering may respond as quickly as physical erosion to abrupt hydroclimate reorganization on continents. Consequently, we anticipate that the forthcoming hydrological disturbances predicted for northeast Africa may have a major impact on chemical weathering patterns and soil resources in this region. PMID:28290474

  2. Abrupt response of chemical weathering to Late Quaternary hydroclimate changes in northeast Africa

    NASA Astrophysics Data System (ADS)

    Bastian, Luc; Revel, Marie; Bayon, Germain; Dufour, Aurélie; Vigier, Nathalie

    2017-03-01

    Chemical weathering of silicate rocks on continents acts as a major sink for atmospheric carbon dioxide and has played an important role in the evolution of the Earth’s climate. However, the magnitude and the nature of the links between weathering and climate are still under debate. In particular, the timescale over which chemical weathering may respond to climate change is yet to be constrained at the continental scale. Here we reconstruct the relationships between rainfall and chemical weathering in northeast Africa for the last 32,000 years. Using lithium isotopes and other geochemical proxies in the clay-size fraction of a marine sediment core from the Eastern Mediterranean Sea, we show that chemical weathering in the Nile Basin fluctuated in parallel with the monsoon-related climatic evolution of northeast Africa. We also evidence strongly reduced mineral alteration during centennial-scale regional drought episodes. Our findings indicate that silicate weathering may respond as quickly as physical erosion to abrupt hydroclimate reorganization on continents. Consequently, we anticipate that the forthcoming hydrological disturbances predicted for northeast Africa may have a major impact on chemical weathering patterns and soil resources in this region.

  3. Cosmogenic nuclide evidence for low weathering and denudation in the wet, tropical highlands of Sri Lanka

    NASA Astrophysics Data System (ADS)

    von Blanckenburg, Friedhelm; Hewawasam, Tilak; Kubik, Peter W.

    2004-09-01

    Some of the lowest weathering and erosion rates in any mountain range in the world have been measured using cosmogenic nuclides in the steep, humid, tropical highlands of Sri Lanka. The total preanthropogenic denudation rates were measured in creek sediments and soil samples from unperturbed rain forest sites, bedrock from mountain crests, and bedrock from inselbergs. Denudation rates are in the range of 5-30 t km-2 yr-1 (2-11 mm ky-1). These rates average denudation over the last 50-250 ky. Weathering exports in rivers draining the mountainous Central Highlands show that silicate weathering rates are also low, varying from 5 to 20 t km-2 yr-1 today (2-7 mm ky-1), but they represent a significant fraction of the total denudation. All these observations run contrary to the conventional geomorphologic and geochemical wisdom that would predict rapid erosion for highlands of high relief, temperatures, and precipitation. We speculate that the high relief in Sri Lanka represents the remnant of a geomorphic block that was uplifted during rifting at 130 Ma or even earlier and that was reduced to the interior of the island by rapid receding of escarpments after continental breakup. It is possible that throughout this history, hillslopes, where not exposing bare bedrock, were protected by thick weathered profiles. Such clay-rich layers would inhibit silicate weathering by shielding bedrock from weathering agents. In the absence of landscape rejuvenation, physical erosion rates are low, and fresh mineral surfaces are not being supplied. The observation that wet, steep, tropical highlands can have low rates of rock weathering and erosion has some potentially profound implications for the long-term controls of atmospheric CO2 budgets: High temperature and precipitation, which are much invoked though controversial agents for silicate dissolution and CO2 drawdown, become ineffective in promoting weathering in areas that are not tectonically active.

  4. Barium in the Yamuna River System in the Himalaya: Sources, fluxes, and its behavior during weathering and transport

    NASA Astrophysics Data System (ADS)

    Dalai, Tarun K.; Krishnaswami, S.; Sarin, M. M.

    2002-12-01

    Systematic measurements of Ba in waters and bed sediments of the Yamuna and many of its tributaries in the Himalaya (Yamuna River System) have been carried out. Dissolved Ba in the Yamuna River System (YRS) ranges from 17 to 871 nM. Streams near the source region draining predominantly granites/gneisses have lower abundance of Ba, <100 nM compared with those in the lower reaches. These data, coupled with those available for major ion composition of these rivers and their sediments, have been used to determine the contributions of silicates and carbonates, the two major lithologies in the drainage basin, to dissolved Ba in YRS. In YRS, dissolved Ba shows significant covariations with Na*, Si, Ca, and Mg. Using Na* as an index, it is estimated that silicates are an important source of Ba to many of the rivers; in a few streams in the lower reaches, however, they account for only <20% of measured Ba. Carbonate weathering, which dominates the major ion composition of YRS rivers, contributes on average ˜30% of dissolved Ba. Together, silicates and carbonates roughly balance measured Ba in many of the rivers, whereas in a few streams, Ba contributions from additional sources are needed to balance the budget. Prospective sources include organic matter/phosphorites. Plot of 1/Ba versus 87Sr/86Sr shows a two-component mixing trend, one with low Ba-high 87Sr/86Sr (silicates) and the other with high Ba-low 87Sr/86Sr (carbonates, phosphorites). Ba also shows significant positive correlation with dissolved Re and SO4. A likely explanation for the Ba-Re-SO4 association is that they are supplied from organic matter/phosphorites/carbonates assemblages through H2SO4 weathering. In YRS bed sediments, Ba shows significant correlation with K and Al. Ba/Na and Ba/Sr in these sediments are higher than those in granites of the Higher Himalaya. These observations can be explained in terms of (1) differential release of these elements during weathering, Ba being less mobile because of its

  5. Weathering, Soil Production, and Erosion Across Climatic and Tectonic Gradients

    NASA Astrophysics Data System (ADS)

    Norton, K. P.; Larsen, I. J.

    2014-12-01

    Weathering is one of the fundamental processes that sustain life on our planet. Physical weathering breaks down rock for soil production and chemical weathering is thought to operate as the ultimate long-term negative feedback on atmospheric CO2 concentrations. There remains, however, uncertainty as to the relationship between chemical and physical weathering at very fast rates. If chemical weathering becomes kinetically limited at rapid erosion rates, as has been shown in a number of locations around the globe, then the fastest erosion rates will be associated with reduced chemical weathering. This has led to a debate as to whether tectonically active mountain ranges or rolling plains are the main source of CO2 drawdown through silicate weathering. At the heart of this debate is the dearth of chemical weathering data at fast erosion rates. New cosmogenic nuclide-derived denudation rates from the West Coast of the New Zealand Southern Alps are among the fastest in the world and are linearly correlated with chemical weathering rates. The associated soil production rates reach an order of magnitude faster than previous estimates and far exceed the suggested maximum soil production rate. This suggests that very fast weathering and soil production is possible in such active landscapes and extreme climates. We investigate the controls on these rapid rates with a climate-driven soil production model. At the most basic level, soil production requires chemical weathering of primary minerals to secondary minerals. We apply soil production models with both exponential and hump-shaped dependencies on soil thickness. Mean annual temperature and precipitation are incorporated in the form of a modified Arrhenius equation that controls the maximum soil production rate. When applied to the Southern Alps, the model predicts very rapid soil production that matches the magnitude of the cosmogenic nuclide-derived rates. High annual precipitation in the Southern Alps supports rapid

  6. Diversity history of Cenozoic marine siliceous plankton

    NASA Astrophysics Data System (ADS)

    Lazarus, David; Renaudie, Johan

    2014-05-01

    Marine planktonic diatoms and polycystine radiolarians, both with shells of opaline silica, make up a large part of the deep-sea sediment fossil record. Diatom export of organic material to the deep ocean and sediments strongly affects the global carbon cycle; while both groups compete for, and are regulated by the availability of, dissolved silica derived from global weathering. Diatoms and radiolarians also both have a relatively (compared to foraminifera or coccolithophores) complex biogeography, with diverse, endemic polar and tropical assemblages. Changes in past diatom and radiolarian diversity can be used to understand how the ocean's biologic pump has evolved, how co-evolution between groups occurs, and how nutrient availability controls evolutionary change. Lazarus et al. (2014) recently showed that diatom diversity increased by a factor of ca 3.5X over the Cenozoic, with a temporary peak in the latest Eocene, a late Oligocene-early Miocene low interval, very strong diversification in the late Miocene-early Pliocene, and minor decline in the late Pliocene-Recent. Only Phanerozoic scale radiolarian diversity estimates have been available until now, and these are strongly biased by sample size. We employed similar data (NSB database) and methods (1 my bins, 'sqs' subsampling, outlier removal using Pacman trims) as Lazarus et al. (2014) to calculate, for the first time, a detailed estimate of radiolarian diversity history, and origination and extinction rates over the last 50 my, the period for which sufficient NSB data is available. Radiolarian diversity increases almost monotonically by a factor of 5, with relatively rapid increases in the mid Eocene (high relative origination) and early Miocene (due to low extinction rates), and a moderate decline in the Plio-Pleistocene due to high extinction rates. Combined high rates of both extinction and origination, with little diversity change, are seen at the Eocene-Oligocene boundary. Most of these events can be

  7. Weathering in a Cup.

    ERIC Educational Resources Information Center

    Stadum, Carol J.

    1991-01-01

    Two easy student activities that demonstrate physical weathering by expansion are described. The first demonstrates ice wedging and the second root wedging. A list of the needed materials, procedure, and observations are included. (KR)

  8. National Weather Service

    MedlinePlus

    ... SAFETY Floods Tsunami Beach Hazards Wildfire Cold Tornadoes Air Quality Fog Heat Hurricanes Lightning Safe Boating Rip Currents ... ACTIVE ALERTS FORECAST MAPS RADAR RIVERS, LAKES, RAINFALL AIR QUALITY SATELLITE PAST WEATHER " ); }); American Samoa Guam Puerto Rico/ ...

  9. Weather Information Processing

    NASA Technical Reports Server (NTRS)

    1991-01-01

    Science Communications International (SCI), formerly General Science Corporation, has developed several commercial products based upon experience acquired as a NASA Contractor. Among them are METPRO, a meteorological data acquisition and processing system, which has been widely used, RISKPRO, an environmental assessment system, and MAPPRO, a geographic information system. METPRO software is used to collect weather data from satellites, ground-based observation systems and radio weather broadcasts to generate weather maps, enabling potential disaster areas to receive advance warning. GSC's initial work for NASA Goddard Space Flight Center resulted in METPAK, a weather satellite data analysis system. METPAK led to the commercial METPRO system. The company also provides data to other government agencies, U.S. embassies and foreign countries.

  10. Weathering of Martian Evaporites

    NASA Technical Reports Server (NTRS)

    Wentworth, S. J.; Velbel, M. A.; Thomas-Keprta, K. L.; Longazo, T. G.; McKay, D. S.

    2001-01-01

    Evaporites in martian meteorites contain weathering or alteration features that may provide clues about the martian near-surface environment over time. Additional information is contained in the original extended abstract.

  11. Pain complaint and the weather: weather sensitivity and symptom complaints in chronic pain patients.

    PubMed

    Shutty, M S; Cundiff, G; DeGood, D E

    1992-05-01

    Chronic pain patients frequently report that weather conditions affect their pain; however, no standardized measures of weather sensitivity have been developed. We describe the development and use of the Weather and Pain Questionnaire (WPQ) which assess patient sensitivity to meteorologic variables defined by the National Weather Service (e.g., temperature, precipitation). Seventy chronic pain patients (59% females) with an average age of 43 years completed the WPQ. The instrument was revised using factor analysis to produce a Weather Sensitivity Index (WSI) (48% of variance) with high internal consistency (0.93) and test-retest reliability (r = 0.89). Reporting patterns suggested that patients could reliably identify which meteorologic variables influenced their pain but could not reliably determine which physical symptoms were consistently affected. The most frequently reported meteorologic variables which affect pain complaint were temperature (87%) and humidity (77%). The most frequently reported physical complaints associated with the weather were joint and muscle aches (82% and 79%, respectively). Patients labeled as being 'weather sensitive', defined by greater than median scores on the WPQ, reported significantly greater pain intensity, greater chronicity of pain problems, and more difficulties sleeping than patients with low scores on the WPQ. No differences in gender, education level, disability status, or global psychological distress were found. Results are discussed with respect to physiological and psychological mediating variables.

  12. Air Weather Service Master Station Catalog USAFETAC Climatic Database Users Handbook No. 6

    DTIC Science & Technology

    1993-03-01

    Federal Aviation Administration (FAA) G = Air Force Global Weather Central (AFGWC) K = Carswell Automated Weather Network (Det 7, AFGWC) 0...AFGWC) J = Jepsen (JEPS) K = Carswell Automated Weather Network (Det 7, AFGWC) M = Located by meteorological analysis B-6 N = Hydrology office...Airfield ACC - Area control center AERO - Aerodrome AHP - U.S. Army Heliport AUX - Auxiliary AFS - Airways Facilities Sector AMOS - Automated

  13. Phosphorus Equilibria Among Mafic Silicate Phases

    NASA Technical Reports Server (NTRS)

    Berlin, Jana; Xirouchakis, Dimitris

    2002-01-01

    Phosphorus incorporation in major rock-forming silicate minerals has the following implications: (1) Reactions between phosphorus-hosting major silicates and accessory phosphates, which are also major trace element carriers, may control the stability of the latter and thus may affect the amount of phosphorus and other trace elements released to the coexisting melt or fluid phase. (2) Less of a phosphate mineral is needed to account for the bulk phosphorus of planetaty mantles. (3) During partial melting of mantle mineral assemblages or equilibrium fractional crystallization of basaltic magmas, and in the absence or prior to saturation with a phosphate mineral, silicate melts may become enriched in phosphorus, especially in the geochemically important low melt fraction regime, Although the small differences in the ionic radii of IVp5+, IVSi4+, and IV Al3+ makes phosphoms incorporation into crystalline silicates perhaps unsurprising, isostructural silicate and phosphate crystalline solids do not readily form solutions, e.g., (Fe, Mg)2SiO4 vs. LiMgPO4, SiO)2 VS. AlPO4. Nonetheless, there are reports of, poorly characterized silico-phosphate phases in angrites , 2-4 wt% P2O5 in olivine and pyroxene grains in pallasites and reduced terestrial basalts which are little understood but potentially useful, and up to 17 wt% P2O5 in olivine from ancient slags. However, such enrichments are rare and only underscore the likelihood of phosphoms incorporation in silicate minerals. The mechanisms that allow phosphorus to enter major rock-forming silicate minerals (e.g., Oliv, Px, Gt) remain little understood and the relevant data base is limited. Nonetheless, old and new high-pressure (5-10 GPa) experimental data suggest that P2O5 wt% decreases from silica-poor to silica-rich compositions or from orthosilicate to chain silicate structures (garnet > olivine > orthopyroxene) which implies that phosphorus incorporation in silicates is perhaps more structure-than site-specific. The

  14. Weather Radar Studies.

    DTIC Science & Technology

    1985-03-31

    National Center for Atmospheric Research JAWS program and the National Severe Storms Laboratory are being analyzed to develop low-altitude wind shear...public through low-altitude wind shear aviation weather products the National Technical Information Service, NEXR I turbulence., Springfield, VA 22161. 19...were analyzed preliminarily to determine wind shear characteristics in the Memphis area. Doppler weather radar data from the National Center for

  15. Genetically optimizing weather predictions

    NASA Astrophysics Data System (ADS)

    Potter, S. B.; Staats, Kai; Romero-Colmenero, Encarni

    2016-07-01

    humidity, air pressure, wind speed and wind direction) into a database. Built upon this database, we have developed a remarkably simple approach to derive a functional weather predictor. The aim is provide up to the minute local weather predictions in order to e.g. prepare dome environment conditions ready for night time operations or plan, prioritize and update weather dependent observing queues. In order to predict the weather for the next 24 hours, we take the current live weather readings and search the entire archive for similar conditions. Predictions are made against an averaged, subsequent 24 hours of the closest matches for the current readings. We use an Evolutionary Algorithm to optimize our formula through weighted parameters. The accuracy of the predictor is routinely tested and tuned against the full, updated archive to account for seasonal trends and total, climate shifts. The live (updated every 5 minutes) SALT weather predictor can be viewed here: http://www.saao.ac.za/ sbp/suthweather_predict.html

  16. GEOSS interoperability for Weather, Ocean and Water

    NASA Astrophysics Data System (ADS)

    Richardson, David; Nyenhuis, Michael; Zsoter, Ervin; Pappenberger, Florian

    2013-04-01

    "Understanding the Earth system — its weather, climate, oceans, atmosphere, water, land, geodynamics, natural resources, ecosystems, and natural and human-induced hazards — is crucial to enhancing human health, safety and welfare, alleviating human suffering including poverty, protecting the global environment, reducing disaster losses, and achieving sustainable development. Observations of the Earth system constitute critical input for advancing this understanding." With this in mind, the Group on Earth Observations (GEO) started implementing the Global Earth Observation System of Systems (GEOSS). GEOWOW, short for "GEOSS interoperability for Weather, Ocean and Water", is supporting this objective. GEOWOW's main challenge is to improve Earth observation data discovery, accessibility and exploitability, and to evolve GEOSS in terms of interoperability, standardization and functionality. One of the main goals behind the GEOWOW project is to demonstrate the value of the TIGGE archive in interdisciplinary applications, providing a vast amount of useful and easily accessible information to the users through the GEO Common Infrastructure (GCI). GEOWOW aims at developing funcionalities that will allow easy discovery, access and use of TIGGE archive data and of in-situ observations, e.g. from the Global Runoff Data Centre (GRDC), to support applications such as river discharge forecasting.TIGGE (THORPEX Interactive Grand Global Ensemble) is a key component of THORPEX: a World Weather Research Programme to accelerate the improvements in the accuracy of 1-day to 2 week high-impact weather forecasts for the benefit of humanity. The TIGGE archive consists of ensemble weather forecast data from ten global NWP centres, starting from October 2006, which has been made available for scientific research. The TIGGE archive has been used to analyse hydro-meteorological forecasts of flooding in Europe as well as in China. In general the analysis has been favourable in terms of

  17. NAVSTAR Global Positioning System Overview

    DTIC Science & Technology

    1984-04-10

    Global Positioning System ( GPS ) is an all-weather, space-based navigation system under development by the Department of Defense (DoD...Happing Agency Los Angeles, California 90009 ABSTRACT The Navstar Global Positioning System ( GPS ) is an all-weather, space-based navigation system ...TITLE llnclud* Security Clauiti.ati-n) NAVSTAR Global Positioning System Overview N/A PROJECT NO. N/A TASK NO. N/A WORK UNIT NO.

  18. Initial effects of vegetation on Hawaiian basalt weathering rates

    SciTech Connect

    Cochran, M.F.; Berner, R.A. )

    1992-01-01

    Weathering of Ca and Mg silicates on land and ensuing precipitation and burial of Ca and Mg carbonates in marine sediments is the principal sink for carbon dioxide from the atmosphere/ocean system on geologic time scales. Model calculations of ancient atmospheric CO[sub 2] partial pressure depend strongly on the authors assumptions about the enhancement of silicate weathering rates first by primitive terrestrial biota, then by the appearance and evolution of the vascular plants. Aa and pahoehoe basalts were collected from Mauna Loa and Kilauea volcanoes on the island of Hawaii. Flows ranged in age (one year to several thousand years) and in ambient climate. Where possible, each flow was sampled beneath a suite of current plant covers: none, lichens, and higher plants. Rocks were embedded in epoxy to preserve the plant-rock interface, then sectioned and subjected to electron probe microanalysis. During initial weathering, vascular plants appeared to promote congruent dissolution of minerals (particularly olivine and Ca-rich plagioclase) and glass near the surfaces of underlying basalts. In the neighborhood of roots, primary cracks widened with time into networks of open channels. This effect was observed prior to the formation of measurable leached zones in exterior grains and prior to the appearance of secondary minerals. As a result, initial mass loss from young, plant-covered basalts appeared to be up to one or more orders of magnitude greater than from bare-rock controls. Despite earlier reports of substantial enhancement of Hawaiian basalt weathering rates by the lichen Stereocaulon vulcani, weathering observed beneath this lichen was comparable to that of unvegetated rocks.

  19. The weathering of micrometeorites from the Transantarctic Mountains

    NASA Astrophysics Data System (ADS)

    van Ginneken, Matthias; Genge, Matthew J.; Folco, Luigi; Harvey, Ralph P.

    2016-04-01

    Micrometeorites are cosmic dust particles recovered from the Earth's surface that dominate the influx of extraterrestrial material accreting to our planet. This paper provides the first in-depth study of the weathering of micrometeorites within the Antarctic environment that will allow primary and secondary features to be distinguished. It is based on the analysis of 366 particles from Larkman Nunatak and 25 from the Transantarctic Mountain collection. Several important morphological categories of weathering effects were identified: (1) irregular and faceted cavities, (2) surface etch pits, (3) infilled cavities, (4) replaced silicate phases, and (5) hydrated and replaced metal. These features indicate that congruent dissolution of silicate phases, in particular olivine, is important in generating new pore space within particles. Comparison of the preservation of glass and olivine also indicates preferential dissolution of olivine by acidic solutions during low temperature aqueous alteration. Precipitation of new hydrous phases within cavities, in particular ferrihydrite and jarosite, results in pseudomorph textures within heavily altered particles. Glass, in contrast, is altered to palagonite gels and shows a sequential replacement indicative of varying water to rock ratios. Metal is variably replaced by Fe-oxyhydroxides and results in decreases in Ni/Fe ratio. In contrast, sulphides within metal are largely preserved. Magnetite, an essential component of micrometeorites formed during atmospheric entry, is least altered by interaction with the terrestrial environment. The extent of weathering in the studied micrometeorites is sensitive to differences in their primary mineralogy and varies significantly with particle type. Despite these differences, we propose a weathering scale for micrometeorites based on both their degree of terrestrial alteration and the level of encrustation by secondary phases. The compositions and textures of weathering products, however

  20. Molybdenum Valence in Basaltic Silicate Melts

    NASA Technical Reports Server (NTRS)

    Danielson, L. R.; Righter, K.; Newville, M.; Sutton, S.; Pando, K.

    2010-01-01

    The moderately siderophile element molybdenum has been used as an indicator in planetary differentiation processes, and is particularly relevant to core formation [for example, 1-6]. However, models that apply experimental data to an equilibrium differentiation scenario infer the oxidation state of molybdenum from solubility data or from multivariable coefficients from metal-silicate partitioning data [1,3,7]. Partitioning behavior of molybdenum, a multivalent element with a transition near the J02 of interest for core formation (IW-2) will be sensitive to changes in JO2 of the system and silicate melt structure. In a silicate melt, Mo can occur in either 4+ or 6+ valence state, and Mo6+ can be either octahedrally or tetrahedrally coordinated. Here we present first XANES measurements of Mo valence in basaltic run products at a range of P, T, and JO2 and further quantify the valence transition of Mo.

  1. Titan: Callisto With Weather?

    NASA Astrophysics Data System (ADS)

    Moore, J. M.; Pappalardo, R. T.

    2008-12-01

    Instead of being endogenically active, Titan's interior may be cold and dead. Those landforms on Titan that are unambiguously identifiable can all be explained by exogenic processes (aeolian, fluvial, impact cratering, and mass wasting). At the scale of available imaging data, the surface is dominated by vast dune ergs and by fluvial erosion, transportation, and deposition. The sparse distribution of recognizable impact craters (themselves exogenic) is consistent with the presence of aeolian and fluvial activity sufficient to cover and or erode smaller craters, leaving only large ones. Previous suggestions of endogenically produced landforms have been, without exception, inconclusively identified. Features suggested to be cryovolcanic flows may be debris flows and other mass movements, facilitated by hydrocarbon-fluidized unconsolidated materials. Ganesa Macula has been suggested as a putative cryovolcanic dome, but it may simply be an impact structure that contains radar-dark dune or mass-wasted materials. Mountains, which are heavily modified by fluvial and mass wasting processes, could have formed as the scarps of large impact features and/or by slow contraction due to global cooling and freezing of an internal ammonia-water ocean, rather than by endogenically powered orogeny. A cold and inactive interior is consistent with an internal ammonia-water ocean, which has a peritectic temperature of 173K, easily obtained in Titan by radioactive decay alone in the absence of tidal heating. Titan's orbital eccentricity should have damped if its interior is warm and dissipative; instead, its high eccentricity can be ancient if the interior is assumed to be cold and non-dissipative. Indeed, it has been suggested that Titan may be non-hydrostatic, consistent with a thick ice shell and a cold and rigid interior. We suggest that the satellite most akin to Titan may be Callisto. Like Callisto, which may have formed relatively slowly in the outer circumjovian accretion disk

  2. DOPPLER WEATHER SYSTEM

    SciTech Connect

    Berlin, Gary J.

    2002-08-05

    The SRS Doppler Weather System consists of a Doppler Server, A Master Server (also known as the Weather Server), several Doppler Slave Servers, and client-side software program called the Doppler Radar Client. This system is used to display near rel-time images taken from the SRS Weather Center's Doppler Radar computer. The Doppler Server is software that resides on the SRS Doppler Computer. It gathers raw data, 24-bit color weather images via screen scraping ever five minutes as requested by the Master Server. The Doppler Server then reduces the 24-bit color images to 8-bit color using a fixed color table for analysis and compression. This preserves the fidelity of the image color and arranges the colors in specific order for display. At the time of color reduction, the white color used for the city names on the background images are remapped to a different index (color) of white that the white on the weather scale. The Weather Server places a time stamp on the image, then compresses the image and passes it to all Doppler Slave servers. Each of the Doppler Slave servers mainitain a circular buffer of the eight most current images representing the last 40 minutes of weather data. As a new image is added, the oldest drops off. The Doppler Radar Client is an optional install program for any site-wide workstation. When a Client session is started, the Client requests Doppler Slave server assignment from the Master Server. Upon its initial request to the Slave Server, the Client obtains all eight current images and maintains its own circular buffer, updating its images every five minutes as the Doppler Slave is updated. Three background reference images are stored as part of the Client. The Client brings up the appropriate background image, decompresses the doppler data, and displays the doppler data on the background image.

  3. Hydrothermal synthesis of ytterbium silicate nanoparticles.

    PubMed

    Chen, Hongfei; Gao, Yanfeng; Liu, Yun; Luo, Hongjie

    2010-02-15

    A simple, low-cost hydrothermal method was developed to synthesize 20-nm-diameter single-crystalline ytterbium silicate (Yb(2)Si(2)O(7) and Yb(2)SiO(5)) nanoparticles at 200 degrees C. This is nearly 1000 degrees C lower than that for the typical sol-gel route to ytterbium silicate powders. Obtained powders showed very low thermal conductivity, a suitable thermal expansion coefficient, and excellent thermal/structural stability, suggesting a potential application to environmental and thermal barrier coatings. Special focus was placed on assessing the hydrothermal reaction mechanism for particle formation.

  4. Mafic silicates in the Orgueil carbonaceous meteorite

    NASA Technical Reports Server (NTRS)

    Kerridge, J. F.; Macdougall, J. D.

    1976-01-01

    Iron-bearing olivines and pyroxenes occurring in Orgueil may represent a separate population distinct from the magnesian varieties previously reported. Compositions of these iron-bearing silicates are inconsistent with an origin by direct equilibrium condensation in the nebula. Such an origin is more plausible for the magnesian silicates, but lacks conclusive evidence. An extra-solar system origin for either mafic population is possible, though similarly lacking in evidence. About 15% of the olivines, randomly distributed with respect to iron content, retain particle track evidence of a precompaction irradiation.

  5. Reaction of silicate minerals to form tetramethoxysilane.

    PubMed

    Lewis, Larry N; Schattenmann, Florian J; Jordan, Tracey M; Carnahan, James C; Flanagan, William P; Wroczynski, Ronald J; Lemmon, John P; Anostario, Joseph M; Othon, Michelle A

    2002-05-06

    Several silicon dioxide sources were used as reagents in the base-mediated reaction with dimethyl carbonate (DMC) to make tetramethoxysilane (Q'). Several commercially available diatomaceous earth materials were investigated. High throughput screening was employed to explore over 200 silicate rocks and minerals as alternative silicon dioxide sources for formation of Q' from DMC and base. Amorphous silicon dioxide materials are effective reagents for the Q' forming reaction. Effective silicon dioxide sources in addition to the diatomaceous earth materials include opal and various synthetic silicates (Li, Co, and Ca).

  6. Air Weather Service Master Station Catalog: USAFETAC Climatic Database Users Handbook No. 6

    DTIC Science & Technology

    1993-03-01

    Federal Aviation Administration (FAA) G = Air Force Global Weather Central (AFGWC) K = Carswell Automated Weather Network (Det 7, AFGWC) 0...Carswell Automated Weather Network (Det 7, AFGWC) M = Located by meteorological analysis B-6 P" 0 0 S 5 0 0 • 0 •, 0 N = Hydrology office...Airways Facilities Sector AMOS - Automated Meteorological Observing System ANG - Air National Guard weather facility AUT - Automated reporting

  7. Rates of oxidative weathering on the surface of Mars

    NASA Technical Reports Server (NTRS)

    Burns, Roger G.

    1992-01-01

    Implicit in the mnemonic 'MSATT' (Mars surface and atmosphere through time) is that rates of surface processes on Mars through time should be investigated, including studies of the kinetics and mechanism of oxidative weathering reactions occurring in the Martian regolith. Such measurements are described. Two major elements analyzed in the Viking Lander XRF experiment that are most vulnerable to atmospheric oxidation are iron and sulfur. Originally, they occurred as Fe(2+)-bearing silicate and sulfide minerals in basaltic rocks on the surface of Mars. However, chemical weathering reactions through time have produced ferric- and sulfate-bearing assemblages now visible in the Martian regolith. Such observations raise several question about: (1) when the oxidative weathering reactions took place on Mars; (2) whether or not the oxidized regolith is a fossilized remnant of past weathering processes; (3) deducting chemical interactions of the ancient Martian atmosphere with its surface from surviving phases; (4) possible weathering reactions still occurring in the frozen regolith; and (5) the kinetics and mechanism of past and present-day oxidative reactions on Mars. These questions may be addressed experimentally by studying reaction rates of dissolution and oxidation of basaltic minerals, and by identifying reaction products forming on the mineral surfaces. Results for the oxidation of pyrrhotite and dissolved ferrous iron are reported.

  8. Iron isotopic fractionation during continental weathering

    SciTech Connect

    Fantle, Matthew S.; DePaolo, Donald J.

    2003-10-01

    The biological activity on continents and the oxygen content of the atmosphere determine the chemical pathways through which Fe is processed at the Earth's surface. Experiments have shown that the relevant chemical pathways fractionate Fe isotopes. Measurements of soils, streams, and deep-sea clay indicate that the {sup 56}Fe/{sup 54}Fe ratio ({delta}{sup 56}Fe relative to igneous rocks) varies from +1{per_thousand} for weathering residues like soils and clays, to -3{per_thousand} for dissolved Fe in streams. These measurements confirm that weathering processes produce substantial fractionation of Fe isotopes in the modern oxidizing Earth surface environment. The results imply that biologically-mediated processes, which preferentially mobilize light Fe isotopes, are critical to Fe chemistry in weathering environments, and that the {delta}{sup 56}Fe of marine dissolved Fe should be variable and negative. Diagenetic reduction of Fe in marine sediments may also be a significant component of the global Fe isotope cycle. Iron isotopes provide a tracer for the influence of biological activity and oxygen in weathering processes through Earth history. Iron isotopic fractionation during weathering may have been smaller or absent in an oxygen-poor environment such as that of the early Precambrian Earth.

  9. Martian Weathering Environments of the Amazonian Indicated by Correlated Morphologic and Spectral Observation in Acidalia Planitia

    NASA Astrophysics Data System (ADS)

    Kraft, M. D.; Rogers, D.; Fergason, R. L.; Michalski, J. R.; Sharp, T. G.

    2009-12-01

    While much attention has been given to chemical alteration and the state of water on early Mars, it remains important to understand aqueous processes throughout Martian history, including the recent geologic past. It has been suggested that the Amazonian was marked primarily by anhydrous, oxidative weathering because Amazonian surfaces, such as the northern plains, lack hydration features in near-infrared spectra [1]. But high-silica materials (Surface Type 2, ST2) discovered by the Thermal Emission Spectrometer [2] that occur in the northern plains attest to aqueous alteration of silicate minerals. The questions are when did this occur and by what process? ST2 correlates spatially with outflow sediments and high-silica materials may have formed in large amounts of water related to outflow flooding events of the late Hesperian [3,4]. ST2 also may correspond to global ice-rich mantles, indicating formation in icy environments related to geologically recent climate fluctuations [3]. Can these very different mechanisms and environments be discerned? In a global study of TES spectra, Rogers et al. (2007) [5] found significant spectral differences between ST2 surfaces in northern and southern Acidalia Planitia that occur near 40-50° N. Several geomorphic transitions occur across latitudes, and many of these are directly or potentially related to Amazonian periglacial activity and occur in the 40-50° N range. This potential link between composition and periglacial morphology needs further exploration. We examined this relationship from 40-50° N in Acidalia Planitia, using Thermal Emission Imaging System (THEMIS) multispectral data to measure the local spectral properties of the surface. We identified a boundary between two surface spectral types that match closely the spectra of north and south Acidalia derived by Rogers et al. [2007]. This boundary is diffuse, occurring between 47-48° N in our study region in western Acidalia, and correlates with observed

  10. New weather index

    NASA Astrophysics Data System (ADS)

    Scientists at the National Oceanic and Atmospheric Administration (NOAA) and the University of Delaware have refined the wind-chill factor, a common measurement of weather discomfort, into a new misery register called the weather stress index. In addition to the mix of temperature and wind speed data used to calculate wind chill, the recipe for the index adds two new ingredients—humidity and a dash of benchmark statistics—to estimate human reaction to weather conditions. NOAA says that the weather stress index estimates human reaction to weather conditions and that the reaction depends on variations from the ‘normal’ conditions in the locality involved.Discomfort criteria for New Orleans, La., and Bismarck, N.D., for example, differ drastically. According to NOAA, when it's the middle of winter and it's -10°C with a relative humidity of 80% and 24 km/h winds, persons in New Orleans would be highly stressed while those in Bismarck wouldn't bat an eye.

  11. Weather from the Stratosphere?

    NASA Technical Reports Server (NTRS)

    Baldwin, Mark P.; Thompson, David W. J.; Shuckburgh, Emily F.; Norton, Warwick A.; Gillett, Nathan P.

    2006-01-01

    Is the stratosphere, the atmospheric layer between about 10 and 50 km, important for predicting changes in weather and climate? The traditional view is that the stratosphere is a passive recipient of energy and waves from weather systems in the underlying troposphere, but recent evidence suggests otherwise. At a workshop in Whistler, British Columbia (1), scientists met to discuss how the stratosphere responds to forcing from below, initiating feedback processes that in turn alter weather patterns in the troposphere. The lowest layer of the atmosphere, the troposphere, is highly dynamic and rich in water vapor, clouds, and weather. The stratosphere above it is less dense and less turbulent (see the figure). Variability in the stratosphere is dominated by hemispheric-scale changes in airflow on time scales of a week to several months. Occasionally, however, stratospheric air flow changes dramatically within just a day or two, with large-scale jumps in temperature of 20 K or more. The troposphere influences the stratosphere mainly through atmospheric waves that propagate upward. Recent evidence shows that the stratosphere organizes this chaotic wave forcing from below to create long-lived changes in the stratospheric circulation. These stratospheric changes can feed back to affect weather and climate in the troposphere.

  12. Space Weather Needs of an Evolving Customer Base (Invited)

    NASA Astrophysics Data System (ADS)

    Rutledge, B.; Viereck, R. A.; Onsager, T. G.

    2013-12-01

    Great progress has been made in raising the global awareness of space weather and the associated impacts on Earth and our technological systems. However, significant gaps still exist in providing comprehensive and easily understood space weather information, products, and services to the diverse and growing customer base. As technologies, such as Global Navigation Satellite Systems (GNSS), have become more ingrained in applications and fields of work that previously did not rely on systems sensitive to space weather, the customer base has grown substantially. Furthermore, the causes and effects of space weather can be difficult to interpret without a detailed understanding of the scientific underpinnings. In response to this change, space weather service providers must address this evolution by both improving services and by representing space weather information and impacts in ways that are meaningful to each facet of this diverse customer base. The NOAA Space Weather Prediction Center (SWPC) must work with users, spanning precision agriculture, emergency management, power grid operators and beyond, to both identify unmet space weather service requirements and to ensure information and decision support services are provided in meaningful and more easily understood forms.

  13. Micro Weather Stations for Mars

    NASA Technical Reports Server (NTRS)

    Crisp, David; Kaiser, William J.; VanZandt, Thomas R.; Hoenk, Michael E.; Tillman, James E.

    1995-01-01

    A global network of weather stations will be needed to characterize the near-surface environment on Mars. Here, we review the scientific and measurement objectives of this network. We also show how these objectives can be met within the cost-constrained Mars Surveyor Program by augmenting the Mars Pathfinder-derived landers with large numbers of very small (less than 5 liter), low-mass (less than 5 kg), low-power, low-cost Mini-meteorological stations. Each station would include instruments for measuring atmospheric. pressures, temperatures, wind velocities, humidity, and airborne dust abundance. They would also include a data handling, telemetry, power, atmospheric entry, and deployment systems in a rugged package capable of direct entry and a high-impact landing. In this paper, we describe these systems and summarize the data-taking strategies and data volumes needed to achieve the surface meteorology objectives for Mars.

  14. Utilization of Live Localized Weather Information for Sustainable Agriculture

    NASA Astrophysics Data System (ADS)

    Anderson, J.; Usher, J.

    2010-09-01

    Authors: Jim Anderson VP, Global Network and Business Development WeatherBug® Professional Jeremy Usher Managing Director, Europe WeatherBug® Professional Localized, real-time weather information is vital for day-to-day agronomic management of all crops. The challenge for agriculture is twofold in that local and timely weather data is not often available for producers and farmers, and it is not integrated into decision-support tools they require. Many of the traditional sources of weather information are not sufficient for agricultural applications because of the long distances between weather stations, meaning the data is not always applicable for on-farm decision making processes. The second constraint with traditional weather information is the timeliness of the data. Most delivery systems are designed on a one-hour time step, whereas many decisions in agriculture are based on minute-by-minute weather conditions. This is especially true for decisions surrounding chemical and fertilizer application and frost events. This presentation will outline how the creation of an agricultural mesonet (weather network) can enable producers and farmers with live, local weather information from weather stations installed in farm/field locations. The live weather information collected from each weather station is integrated into a web-enabled decision support tool, supporting numerous on-farm agronomic activities such as pest management, or dealing with heavy rainfall and frost events. Agronomic models can be used to assess the potential of disease pressure, enhance the farmer's abilities to time pesticide applications, or assess conditions contributing to yield and quality fluctuations. Farmers and industry stakeholders may also view quality-assured historical weather variables at any location. This serves as a record-management tool for viewing previously uncharted agronomic weather events in graph or table form. This set of weather tools is unique and provides a

  15. The space-weather enterprise: past, present, and future

    NASA Astrophysics Data System (ADS)

    Siscoe, G.

    2000-09-01

    Space-weather impacts society in diverse ways. Societies' responses have been correspondingly diverse. Taken together these responses constitute a space weather ``enterprise'', which has developed over time and continues to develop. Technological systems that space-weather affects have grown from isolated telegraph systems in the 1840s to ocean and continent-spanning cable communications systems, from a generator electrifying a few city blocks in the 1880s to continent-spanning networks of high-tension lines, from wireless telegraphy in the 1890s to globe-spanning communication by radio and satellites. To have a name for the global totality of technological systems that are vulnerable to space weather, I suggest calling it the cyberelectrosphere. When the cyberelectrosphere was young, scientists who study space weather, engineers who design systems that space weather affects, and operators of such systems - the personnel behind the space-weather enterprise - were relatively isolated. The space-weather enterprise was correspondingly incoherent. Now that the cyberelectrosphere has become pervasive and indispensable to most segments of society, the space weather enterprise has become systematic and coherent. At present it has achieved considerable momentum, but it has barely begun to realize the level of effectiveness to which it can aspire, as evidenced by achievements of a corresponding but more mature enterprise in meteorology, a field which provides useful lessons. The space-weather enterprise will enter a new phase after it matures roughly to where the tropospheric weather enterprise is now. Then it will become indispensable for humankind's further global networking through technology and for humankind's further utilization of and expansion into space.

  16. Weather Satellite Enterprise Information Chain

    NASA Astrophysics Data System (ADS)

    Jamilkowski, M. L.; Grant, K. D.; Miller, S. W.; Cochran, S.

    2015-12-01

    NOAA & NASA are acquiring the next-generation civilian operational weather satellite: Joint Polar Satellite System (JPSS). Contributing the afternoon orbit & ground system (GS) to replace current NOAA POES Satellites, its sensors will collect meteorological, oceanographic & climatological data. The JPSS Common Ground System (CGS), consisting of C3 and IDP segments, is developed by Raytheon. It now flies the Suomi National Polar-orbiting Partnership (S-NPP) satellite, transferring data between ground facilities, processing them into environmental products for NOAA weather centers, and expanding to support JPSS-1 in 2017. As a multi-mission system, CGS provides combinations of C3, data processing, and product delivery for numerous NASA, NOAA, DoD and international missions.The CGS provides a wide range of support to a number of missions: Command and control and mission management for the S-NPP mission today, expanding this support to the JPSS-1 satellite mission in 2017 Data acquisition for S-NPP, the JAXA's Global Change Observation Mission - Water (GCOM-W1), POES, and the Defense Meteorological Satellite Program (DMSP) and Coriolis/WindSat for the DoD Data routing over a global fiber network for S-NPP, JPSS-1, GCOM-W1, POES, DMSP, Coriolis/WindSat, NASA EOS missions, MetOp for EUMETSAT and the National Science Foundation Environmental data processing and distribution for S-NPP, GCOM-W1 and JPSS-1 The CGS plays a key role in facilitating the movement and value-added enhancement of data all the way from satellite-based sensor data to delivery to the consumers who generate forecasts and produce watches and warnings. This presentation will discuss the information flow from sensors, through data routing and processing, and finally to product delivery. It will highlight how advances in architecture developed through lessons learned from S-NPP and implemented for JPSS-1 will increase data availability and reduce latency for end user applications.

  17. Spaceborne weather radar

    NASA Technical Reports Server (NTRS)

    Meneghini, Robert; Kozu, Toshiaki

    1990-01-01

    The present work on the development status of spaceborne weather radar systems and services discusses radar instrument complementarities, the current forms of equations for the characterization of such aspects of weather radar performance as surface and mirror-image returns, polarimetry, and Doppler considerations, and such essential factors in spaceborne weather radar design as frequency selection, scanning modes, and the application of SAR to rain detection. Attention is then given to radar signal absorption by the various atmospheric gases, rain drop size distribution and wind velocity determinations, and the characteristics of clouds, as well as the range of available estimation methods for backscattering, single- and dual-wavelength attenuation, and polarimetric and climatological characteristics.

  18. Planetary Space Weather

    NASA Astrophysics Data System (ADS)

    Grande, M.

    2012-04-01

    Invited Talk - Space weather at other planets While discussion of space weather effects has so far largely been confined to the near-Earth environment, there are significant present and future applications to the locations beyond, and to other planets. Most obviously, perhaps, are the radiation hazards experienced by astronauts on the way to, and on the surface of, the Moon and Mars. Indeed, the environment experienced by planetary spacecraft in transit and at their destinations is of course critical to their design and successful operation. The case of forthcoming missions to Jupiter and Europa is an exreme example. Moreover, such craft can provide information which in turn increases our understanding of geospace. Indeed, space weather may be a significant factor in the habitability of other solar system and extrasolar planets, and the ability of life to travel between them.

  19. Climate-change effects on soils: Accelerated weathering, soil carbon and elemental cycling

    SciTech Connect

    Qafoku, Nikolla

    2015-04-01

    Climate change [i.e., high atmospheric carbon dioxide (CO2) concentrations (≥400 ppm); increasing air temperatures (2-4°C or greater); significant and/or abrupt changes in daily, seasonal, and inter-annual temperature; changes in the wet/dry cycles; intensive rainfall and/or heavy storms; extended periods of drought; extreme frost; heat waves and increased fire frequency] is and will significantly affect soil properties and fertility, water resources, food quantity and quality, and environmental quality. Biotic processes that consume atmospheric CO2, and create organic carbon (C) that is either reprocessed to CO2 or stored in soils are the subject of active current investigations, with great concern over the influence of climate change. In addition, abiotic C cycling and its influence on the inorganic C pool in soils is a fundamental global process in which acidic atmospheric CO2 participates in the weathering of carbonate and silicate minerals, ultimately delivering bicarbonate and Ca2+ or other cations that precipitate in the form of carbonates in soils or are transported to the rivers, lakes, and oceans. Soil responses to climate change will be complex, and there are many uncertainties and unresolved issues. The objective of the review is to initiate and further stimulate a discussion about some important and challenging aspects of climate-change effects on soils, such as accelerated weathering of soil minerals and resulting C and elemental fluxes in and out of soils, soil/geo-engineering methods used to increase C sequestration in soils, soil organic matter (SOM) protection, transformation and mineralization, and SOM temperature sensitivity. This review reports recent discoveries, identifies key research needs, and highlights opportunities offered by the climate-change effects on soils.

  20. Microfabrics in Siliceous Hotsprings: Yellowstone National Park, Wyoming

    NASA Technical Reports Server (NTRS)

    Guidry, S. A.; Chafetz, H. S.; Westall, F.

    2001-01-01

    Microfabrics shed light on the mechanisms governing siliceous sinter precipitation, the profound effects of microorganisms, as well as a conventional facies model for siliceous hotsprings. Additional information is contained in the original extended abstract.

  1. Global chemical erosion over the last 250 my: Variations due to changes in paleogeography, paleoclimate, and paleogeology

    SciTech Connect

    Gibbs, M.T.; Bluth, G.J.S.; Fawcett, P.J.; Kump, L.R.

    1999-07-01

    The authors utilize predictions of runoff from two series of GENESIS (version 1.02) climate model experiments to calculate chemical erosion rates for 12 time slices that span the Mesozoic and Cenozoic. A set of control experiments where geography is altered according to published paleogeographic reconstructions and atmospheric pCO{sub 2} is held fixed at the present-day value was designed to elucidate climate sensitivity to geography alone. A second series of experiments, where the (elevated) atmospheric CO{sub 2} level for each time slice was adapted from Berner (1991), was executed to determine the additional climate sensitivity to this parameter. By holding other climate forcing factors (for example, vegetation) constant throughout the sequence of experiments the authors evaluate the effects of systematic/coherent paleogeographic changes on runoff and temperature, and thus on global rates of chemical weathering. By using empirical relationships between runoff and bicarbonate fluxes for different rock types and maps of paleogeology they calculate global bicarbonate fluxes, taking into account spatial variations in lithology and hydrology. They find that spatial variations in lithology account for little variation in the total or silicate chemical erosion rates. Calculations suggest a weaker-than-expected CO{sub 2}-climate weathering feedback. The reasonable atmospheric pCO{sub 2} variations specified for the climate-model simulations do not lead to climatic effects that support large changes in the chemical erosion rate, compared to those generated by changing paleogeography. In general, however, they find that silicate weathering rates are similar to outgassing rates of volcanic and methamorphic CO{sub 2}.

  2. Dopant penetration studies through Hf silicate

    NASA Astrophysics Data System (ADS)

    Quevedo-Lopez, M. A.; Visokay, M. R.; Chambers, J. J.; Bevan, M. J.; LiFatou, A.; Colombo, L.; Kim, M. J.; Gnade, B. E.; Wallace, R. M.

    2005-02-01

    We present a study of the penetration of B, P, and As through Hf silicate (HfSixOy) and the effect of N incorporation in Hf silicate (HfSixOyNz) on dopant penetration from doped polycrystalline silicon capping layers. The extent of penetration through Hf silicate was found to be dependent upon the thermal annealing budget for each dopant investigated as follows: B(T⩾950°C/60s), P(T⩾1000°C/20s), and As (T⩾1050°C/60s). We propose that the enhanced diffusion observed for these dopants in HfSixOy, compared with that of SiO2 films, is related to grain boundary formation resulting from HfSixOy film crystallization. We also find that, as in the case of SiO2, N incorporation inhibits dopant (B, P, and As) diffusion through the Hf silicate and thus penetration into the underlying Si substrate. Only B penetration is clearly observed through HfSiON films for anneals at 1050 °C for durations of 10 s or longer. The calculated B diffusivity through the HfSixOyNz layer is D0=5.2×10-15cm2/s.

  3. Chemically bonded phospho-silicate ceramics

    DOEpatents

    Wagh, Arun S.; Jeong, Seung Y.; Lohan, Dirk; Elizabeth, Anne

    2003-01-01

    A chemically bonded phospho-silicate ceramic formed by chemically reacting a monovalent alkali metal phosphate (or ammonium hydrogen phosphate) and a sparsely soluble oxide, with a sparsely soluble silicate in an aqueous solution. The monovalent alkali metal phosphate (or ammonium hydrogen phosphate) and sparsely soluble oxide are both in powder form and combined in a stochiometric molar ratio range of (0.5-1.5):1 to form a binder powder. Similarly, the sparsely soluble silicate is also in powder form and mixed with the binder powder to form a mixture. Water is added to the mixture to form a slurry. The water comprises 50% by weight of the powder mixture in said slurry. The slurry is allowed to harden. The resulting chemically bonded phospho-silicate ceramic exhibits high flexural strength, high compression strength, low porosity and permeability to water, has a definable and bio-compatible chemical composition, and is readily and easily colored to almost any desired shade or hue.

  4. Dynamic Fatigue of a Titanium Silicate Glass

    NASA Technical Reports Server (NTRS)

    Tucker, Dennis S.; Nettles, Alan T.; Cagle, Holly A.; Smith, W. Scott (Technical Monitor)

    2002-01-01

    A dynamic fatigue study was performed on a Titanium Silicate Glass in order to assess its susceptibility to delayed failure. Fracture mechanics techniques were used to analyze the results for the purpose of making lifetime predictions for optical elements made from this material. The material has reasonably good resistance (N=23 to stress corrosion in ambient conditions).

  5. Lithium Manganese Silicate Positive Electrode Material

    NASA Astrophysics Data System (ADS)

    Yang, Qiong

    As the fast development of the electronic portable devices and drastic fading of fossil energy sources. The need for portable secondary energy sources is increasingly urgent. As a result, lithium ion batteries are being investigated intensely to meet the performance requirements. Among various electrode materials, the most expensive and capacity limiting component is the positive materials. Based on this, researches have been mostly focused on the development of novel cathode materials with high capacity and energy density and the lithium transition metal orthosilicates have been identified as possible high performance cathodes. Here in, we report the synthesis of a kind of lithium transition metal orthosilicates electrode lithium manganese silicate. Lithium manganese silicate has the advantage of high theoretical capacity, low cost raw material and safety. In this thesis, lithium manganese silicate are prepared using different silicon sources. The structure of silicon sources preferred are examined. Nonionic block copolymers surfactant, P123, is tried as carbon source and mophology directing agent. Lithium manganese silicate's performances are improved by adding P123.

  6. Space Weather Workshop

    NASA Technical Reports Server (NTRS)

    Gallagher, D. L.

    2004-01-01

    This workshop will focus on what space weather is about and its impact on society. An overall picture will be "painted" describing the Sun's influence through the solar wind on the near-Earth space environment, including the aurora, killer electrons at geosynchronous orbit, million ampere electric currents through the ionosphere and along magnetic field lines, and the generation of giga-Watts of natural radio waves. Reference material in the form of Internet sites will be provided so that teachers can discuss space weather in the classroom and enable students to learn more about this topic.

  7. Neutralization of atmospheric acidity by chemical weathering in an alpine drainage basin in the North Cascade mountains

    SciTech Connect

    Drever, J.I.; Hurcomb, D.R.

    1986-03-01

    The most important weathering reaction that neutralizes incoming atmospheric acidity in the South Cascade Lake basin is weathering of calcite, which occurs in trace amounts in veins, on joint surfaces, and as a subglacial surficial deposit. Although the basin is underlain by igneous and high-grade metamorphic rocks, weathering of plagioclase is quantitatively negligible; the principal silicate weathering reaction is alteration of biotite to vermiculite. These conclusions are based on mass-balance calculations involving runoff compositions and on mineralogical observations. For predictive modeling of the effects of increased acid deposition, it is essential to identify the relevant weathering reactions. Feldspar weathering is commonly not an important source of solutes in alpine basins underlain by granitic rocks. 30 references, 2 figures, 1 table.

  8. 2011 Space Weather Workshop to Be Held in April

    NASA Astrophysics Data System (ADS)

    Peltzer, Thomas

    2011-04-01

    The annual Space Weather Workshop will be held in Boulder, Colo., 26-29 April 2011. The workshop will bring customers, forecasters, commercial service providers, researchers, and government agencies together in a lively dialogue about space weather. The workshop will include 4 days of plenary sessions on a variety of topics, with poster sessions focusing on the Sun, interplanetary space, the magnetosphere, and the ionosphere. The conference will address the remarkably diverse impacts of space weather on today's technology. Highlights on this year's agenda will include presentations on space weather impacts on the Global Positioning System (GPS), the Solar Terrestrial Relations Observatory's (STEREO) mission milestone of a 360° view of the Sun, the latest from NASA's Solar Dynamics Observatory (SDO), and space weather impacts on emergency response by the Federal Emergency Management Agency (FEMA). Additionally, the vulnerabilities of satellites and the power grid to space weather will be addressed. Additional highlights will include the Commercial Space Weather Interest Group's (CSWIG) roundtable session and a presentation from the Office of the Federal Coordinator for Meteorology (OFCM). The CSWIG roundtable session on the growth of the space weather enterprise will feature distinguished panelists. As always, lively interaction between the audience and the panel is anticipated. The OFCM will present the National Space Weather Program's new strategic plan.

  9. Thermoset polymer-layered silicic acid nanocomposites

    NASA Astrophysics Data System (ADS)

    Wang, Zhen

    Nanocomposites are formed when phase mixing occurs on a nanometer length scale. Due to the improved phase morphology and interfacial properties, nanocomposites exhibit mechanical properties superior to conventional composites. Toyota researchers first demonstrated that organoclay could be exfoliated in a nylon-6 matrix to greatly improve the thermal and mechanical properties of the polymer, which has resulted in a practical application in the automobile industry. A great deal of research has been conducted on organic-inorganic hybrid composites in which smectite clays are used as reinforcement agents. However, little work has been devoted to derivatives of other layered inorganic solids. In the present work, the first examples of organic polymer-layered silicic acid nanocomposites have been prepared by formation of a cured epoxy polymer network in the presence of organo cation exchange forms of magadiite. The exfoliation of silicate nanolayers in the epoxy matrix was achieved by in-situ intragallery polymerization during the thermosetting process. In general, the tensile properties, solvent resistance, barrier properties and chemical stability of the polymer matrix are greatly improved by the embedded silicate nanolayers when the matrix is flexible (sub-ambient Tg). The improvement of properties are dependent on the silicate loading, the degree of nanolayer separation and interfacial properties. Interestingly, the exfoliation also affects the polymer elasticity in a favorable way. The mechanism leading to nanocomposite formation is proposed. One exfoliated epoxy-magadiite nanocomposite/composition possessed unique transparent optical properties. The exfoliation chemistry was successfully extended to the other members of the layered silicic acid family. A new approach also was developed to prepare thermoset epoxy polymer-layered silicate nanocomposites in which curing agents can be directly intercalated into the intragallery without the need for alkylammonium ions

  10. Sr isotopic characteristics in two small watersheds draining typical silicate and carbonate rocks: implication for the studies on seawater Sr isotopic evolution

    NASA Astrophysics Data System (ADS)

    Wu, W. H.; Zheng, H. B.; Yang, J. D.

    2013-06-01

    We systematically investigated Sr isotopic characteristics of small silicate watershed - the tributary Xishui River of the Yangtze River, and small carbonate watershed - the tributary Guijiang River of the Pearl River. The results show that the Xishui River has relatively high Sr concentrations (0.468-1.70 μmol L-1 in summer and 1.30-3.17 μmol L-1 in winter, respectively) and low 87Sr/86Sr ratios (0.708686-0.709148 in summer and 0.708515-0.709305 in winter), which is similar to the characteristics of carbonate weathering. The Guijiang River has low Sr concentrations (0.124-1.098 μmol L-1) and high 87Sr/86Sr ratios (0.710558-0.724605), being characterized by silicate weathering. In the Xishui River catchment, chemical weathering rates in summer are far higher than those in winter, indicating significant influence of climate regime. However, slight differences of 87Sr/86Sr ratios between summer and winter show that influence of climate on Sr isotope is uncertainty owing to very similar Sr isotope values in silicate and carbonate bedrocks. As 87Sr/86Sr ratios in the Xishui River are lower than those in seawater, they will decrease 87Sr/86Sr ratio of seawater after transported into oceans. Previous studies also showed that some basaltic watersheds with extremely high chemical weathering rates reduced the seawater Sr isotope ratios. In other words, river catchments with high silicate weathering rates do not certainly transport highly radiogenic Sr into oceans. Therefore, it may be questionable that using the variations of seawater 87Sr/86Sr ratio to indicate the continental silicate weathering intensity. In the Guijiang River catchment, 87Sr/86Sr ratios of carbonate rocks and other sources (rainwater, domestic and industrial waste water, and agricultural fertilizer) are lower than 0.71. In comparison, some non-carbonate components, such as, sand rocks, mud rocks, shales, have relatively high Sr isotopic compositions. Moreover, granites accounted for only 5% of the

  11. The significance of mid-latitude rivers for weathering rates and chemical fluxes: Evidence from northern Xinjiang rivers

    NASA Astrophysics Data System (ADS)

    Zhu, Bingqi; Yu, Jingjie; Qin, Xiaoguang; Rioual, Patrick; Liu, Ziting; Zhang, YiChi; Jiang, Fengqing; Mu, Yan; Li, Hongwei; Ren, Xiaozong; Xiong, Heigang

    2013-04-01

    SummaryRivers draining the sedimentary platform of northern Xinjiang (the center of Asian continent) are characterized by low discharge under a temperate and arid climate. The influence of rock mineralogy, climate, relief and human activity on natural water composition and export as a result of weathering is a major scientific concern both at the local and the global scale. While comprehensive work on the controlling mechanism of chemical weathering has been less carried out in the sedimentary platform of northern Xinjiang. Thus, the effects of climate and rock weathering on the inorganic hydrogeochemical processes are not well quantified at this climatic extreme. To remedy this lack a comprehensive survey has been carried out of the geochemistry of the large, pristine rivers in northern Xinjiang, the Erlqis, Yili, Wulungu, Jingou and numerous lesser streams which has not experienced the pervasive effects of glaciation and subsequent anthropogenic impacts. The scale of the terrain sampled, in terms of area, is comparable to that of the Huanghe and includes a diverse range of geologic and climatic environments. In this paper the chemical fluxes from the stable sedimentary basin of the northern Xinjiang platform will be presented and compared to published results from analogous terrains in the monsoon basins of China and world. Overall, the fluvial geochemistry of northern Xinjiang in westerly climate is similar to that of the Chinese rivers (Huanghe and Yangtze) in the East-Asian monsoon Climate, both in property-property relationships and concentration magnitudes. The range in the chemical signatures of the various tributaries is large; this reflects that lithology exerts the dominant influence in determining the weathering yield from the sedimentary terrains rather than the weathering environment. The effect of different rock weathering ranges from rivers dominated by aluminosilicate weathering, mainly of granites, sandstones and shales, to those bearing the

  12. Grain Growth and Silicates in Dense Clouds

    NASA Technical Reports Server (NTRS)

    Pendeleton, Yvonne J.; Chiar, J. E.; Ennico, K.; Boogert, A.; Greene, T.; Knez, C.; Lada, C.; Roellig, T.; Tielens, A.; Werner, M.; Whittet, D.

    2006-01-01

    Interstellar silicates are likely to be a part of all grains responsible for visual extinction (Av) in the diffuse interstellar medium (ISM) and dense clouds. A correlation between Av and the depth of the 9.7 micron silicate feature (measured as optical depth, tau(9.7)) is expected if the dust species are well 'mixed. In the di&se ISM, such a correlation is observed for lines of sight in the solar neighborhood. A previous study of the silicate absorption feature in the Taurus dark cloud showed a tendency for the correlation to break down at high Av (Whittet et al. 1988, MNRAS, 233,321), but the scatter was large. We have acquired Spitzer Infrared Spectrograph data of several lines of sight in the IC 5 146, Barnard 68, Chameleon I and Serpens dense clouds. Our data set spans an Av range between 2 and 35 magnitudes. All lines of sight show the 9.7 micron silicate feature. The Serpens data appear to follow the diffuse ISM correlation line whereas the data for the other clouds show a non-linear correlation between the depth of the silicate feature relative to Av, much like the trend observed in the Taurus data. In fact, it appears that for visual extinctions greater than about 10 mag, tau(9.7) begins to level off. This decrease in the growth of the depth of the 9.7 micron feature with increasing Av could indicate the effects of grain growth in dense clouds. In this poster, we explore the possibility that grain growth causes an increase in opacity (Av) without causing a corresponding increase in tau(9.7).

  13. Silicate Dust in Active Galactic Nuclei

    NASA Astrophysics Data System (ADS)

    Xie, Yanxia; Li, Aigen; Hao, Lei

    2017-01-01

    The unification theory of active galactic nuclei (AGNs) hypothesizes that all AGNs are surrounded by an anisotropic dust torus and are essentially the same objects but viewed from different angles. However, little is known about the dust that plays a central role in the unification theory. There are suggestions that the AGN dust extinction law appreciably differs from that of the Galaxy. Also, the silicate emission features observed in type 1 AGNs appear anomalous (i.e., their peak wavelengths and widths differ considerably from that of the Galaxy). In this work, we explore the dust properties of 147 AGNs of various types at redshifts z≲ 0.5, with special attention paid to 93 AGNs that exhibit the 9.7 and 18 μm silicate emission features. We model their silicate emission spectra obtained with the Infrared Spectrograph aboard the Spitzer Space Telescope. We find that 60/93 of the observed spectra can be well explained with “astronomical silicate,” while the remaining sources favor amorphous olivine or pyroxene. Most notably, all sources require the dust to be micron-sized (with a typical size of ∼1.5 ± 0.1 μm), much larger than submicron-sized Galactic interstellar grains, implying a flat or “gray” extinction law for AGNs. We also find that, while the 9.7 μm emission feature arises predominantly from warm silicate dust of temperature T ∼ 270 K, the ∼5–8 μm continuum emission is mostly from carbon dust of T ∼ 640 K. Finally, the correlations between the dust properties (e.g., mass, temperature) and the AGN properties (e.g., luminosity, black hole mass) have also been investigated.

  14. High chloride content calcium silicate glasses.

    PubMed

    Chen, Xiaojing; Karpukhina, Natalia; Brauer, Delia S; Hill, Robert G

    2017-03-08

    Chloride is known to volatilize from silicate glass melts and until now, only a limited number of studies on oxychloride silicate glasses have been reported. In this paper we have synthesized silicate glasses that retain large amounts of CaCl2. The CaCl2 has been added to the calcium metasilicate composition (CaO·SiO2). Glasses were produced via a melt quench route and an average of 70% of the chloride was retained after melting. Up to 31.6 mol% CaCl2 has been successfully incorporated into these silicate glasses without the occurrence of crystallization. (29)Si MAS-NMR spectra showed the silicon being present mainly as a Q(2) silicate species. This suggests that chloride formed Cl-Ca(n) species, rather than Si-Cl bonds. Upon increasing the CaCl2 content, the Tg reduced markedly from 782 °C to 370 °C. Glass density and glass crystallization temperature decreased linearly with an increase in the CaCl2 content. However, both linear regressions revealed a breakpoint at a CaCl2 content just below 20 mol%. This might be attributed to a significant change in the structure and is also correlated with the nature of the crystallizing phases formed upon heat treatment. The glasses with less than 19.2 mol% CaCl2 crystallized to wollastonite, whilst the compositions with CaCl2 content equal to or greater than 19.2 mol% are thought to crystallize to CaCl2. In practice, the crystallization of CaCl2 could not occur until the crystallization temperature fell below the melting point of CaCl2. The implications of the results along with the high chloride retention are discussed.

  15. 77 FR 21676 - Silicic Acid, Sodium Salt etc.; Tolerance Exemption

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-04-11

    ... AGENCY 40 CFR Part 180 Silicic Acid, Sodium Salt etc.; Tolerance Exemption AGENCY: Environmental... requirement of a tolerance for residues of Silicic acid, sodium salt, reaction products with... residues of Silicic acid, sodium salt, reaction products with chlorotrimethylsilane and iso-propyl...

  16. 21 CFR 582.2122 - Aluminum calcium silicate.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 21 Food and Drugs 6 2014-04-01 2014-04-01 false Aluminum calcium silicate. 582.2122 Section 582.2122 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED....2122 Aluminum calcium silicate. (a) Product. Aluminum calcium silicate. (b) Tolerance. 2 percent....

  17. 21 CFR 182.2122 - Aluminum calcium silicate.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 21 Food and Drugs 3 2014-04-01 2014-04-01 false Aluminum calcium silicate. 182.2122 Section 182...) SUBSTANCES GENERALLY RECOGNIZED AS SAFE Anticaking Agents § 182.2122 Aluminum calcium silicate. (a) Product. Aluminum calcium silicate. (b) Tolerance. 2 percent. (c) Limitations, restrictions, or explanation....

  18. 21 CFR 582.2122 - Aluminum calcium silicate.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 21 Food and Drugs 6 2011-04-01 2011-04-01 false Aluminum calcium silicate. 582.2122 Section 582.2122 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED....2122 Aluminum calcium silicate. (a) Product. Aluminum calcium silicate. (b) Tolerance. 2 percent....

  19. 21 CFR 582.2122 - Aluminum calcium silicate.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 21 Food and Drugs 6 2013-04-01 2013-04-01 false Aluminum calcium silicate. 582.2122 Section 582.2122 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED....2122 Aluminum calcium silicate. (a) Product. Aluminum calcium silicate. (b) Tolerance. 2 percent....

  20. 21 CFR 182.2122 - Aluminum calcium silicate.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 21 Food and Drugs 3 2013-04-01 2013-04-01 false Aluminum calcium silicate. 182.2122 Section 182.2122 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED....2122 Aluminum calcium silicate. (a) Product. Aluminum calcium silicate. (b) Tolerance. 2 percent....

  1. 21 CFR 582.2122 - Aluminum calcium silicate.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 21 Food and Drugs 6 2010-04-01 2010-04-01 false Aluminum calcium silicate. 582.2122 Section 582.2122 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED....2122 Aluminum calcium silicate. (a) Product. Aluminum calcium silicate. (b) Tolerance. 2 percent....

  2. 21 CFR 182.2122 - Aluminum calcium silicate.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 21 Food and Drugs 3 2010-04-01 2009-04-01 true Aluminum calcium silicate. 182.2122 Section 182.2122 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED....2122 Aluminum calcium silicate. (a) Product. Aluminum calcium silicate. (b) Tolerance. 2 percent....

  3. 21 CFR 582.2122 - Aluminum calcium silicate.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 21 Food and Drugs 6 2012-04-01 2012-04-01 false Aluminum calcium silicate. 582.2122 Section 582.2122 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED....2122 Aluminum calcium silicate. (a) Product. Aluminum calcium silicate. (b) Tolerance. 2 percent....

  4. 21 CFR 182.2122 - Aluminum calcium silicate.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 21 Food and Drugs 3 2011-04-01 2011-04-01 false Aluminum calcium silicate. 182.2122 Section 182.2122 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED....2122 Aluminum calcium silicate. (a) Product. Aluminum calcium silicate. (b) Tolerance. 2 percent....

  5. 21 CFR 182.2122 - Aluminum calcium silicate.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 21 Food and Drugs 3 2012-04-01 2012-04-01 false Aluminum calcium silicate. 182.2122 Section 182.2122 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED....2122 Aluminum calcium silicate. (a) Product. Aluminum calcium silicate. (b) Tolerance. 2 percent....

  6. 40 CFR 721.9513 - Modified magnesium silicate polymer (generic).

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 31 2011-07-01 2011-07-01 false Modified magnesium silicate polymer... Specific Chemical Substances § 721.9513 Modified magnesium silicate polymer (generic). (a) Chemical... as modified magnesium silicate polymer (PMN P-98-604) is subject to reporting under this section...

  7. 40 CFR 721.9513 - Modified magnesium silicate polymer (generic).

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 31 2014-07-01 2014-07-01 false Modified magnesium silicate polymer... Specific Chemical Substances § 721.9513 Modified magnesium silicate polymer (generic). (a) Chemical... as modified magnesium silicate polymer (PMN P-98-604) is subject to reporting under this section...

  8. 40 CFR 721.9513 - Modified magnesium silicate polymer (generic).

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 32 2013-07-01 2013-07-01 false Modified magnesium silicate polymer... Specific Chemical Substances § 721.9513 Modified magnesium silicate polymer (generic). (a) Chemical... as modified magnesium silicate polymer (PMN P-98-604) is subject to reporting under this section...

  9. 40 CFR 721.9513 - Modified magnesium silicate polymer (generic).

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 30 2010-07-01 2010-07-01 false Modified magnesium silicate polymer... Specific Chemical Substances § 721.9513 Modified magnesium silicate polymer (generic). (a) Chemical... as modified magnesium silicate polymer (PMN P-98-604) is subject to reporting under this section...

  10. 40 CFR 721.9513 - Modified magnesium silicate polymer (generic).

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 32 2012-07-01 2012-07-01 false Modified magnesium silicate polymer... Specific Chemical Substances § 721.9513 Modified magnesium silicate polymer (generic). (a) Chemical... as modified magnesium silicate polymer (PMN P-98-604) is subject to reporting under this section...

  11. 40 CFR 721.10495 - Metal silicate (generic).

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 32 2013-07-01 2013-07-01 false Metal silicate (generic). 721.10495... Substances § 721.10495 Metal silicate (generic). (a) Chemical substance and significant new uses subject to reporting. (1) The chemical substance identified generically as metal silicate (PMN P-05-634) is subject...

  12. 40 CFR 721.10495 - Metal silicate (generic).

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 31 2014-07-01 2014-07-01 false Metal silicate (generic). 721.10495... Substances § 721.10495 Metal silicate (generic). (a) Chemical substance and significant new uses subject to reporting. (1) The chemical substance identified generically as metal silicate (PMN P-05-634) is subject...

  13. Weathering the Double Whammy.

    ERIC Educational Resources Information Center

    Wellman, Jane V.

    2002-01-01

    Discusses how governing boards can help their institutions weather the "double-whammy" of doing more with less: identify the institution's short-term and long-term challenges; refocus the institution's mission, planning, and programming; assess and integrate the institution's tuition, aid, and outreach strategies; redouble the…

  14. Weather Specialist (AFSC 25120).

    ERIC Educational Resources Information Center

    Air Univ., Gunter AFS, Ala. Extension Course Inst.

    This correspondence course is designed for self-study to help military personnel to attain the rating of weather specialist. The course is organized in three volumes. The first volume, containing seven chapters, covers background knowledge, meteorology, and climatology. In the second volume, which also contains seven chapters, surface…

  15. Microbial Weathering of Olivine

    NASA Technical Reports Server (NTRS)

    McKay, D. S.; Longazo, T. G.; Wentworth, S. J.; Southam, G.

    2002-01-01

    Controlled microbial weathering of olivine experiments displays a unique style of nanoetching caused by biofilm attachment to mineral surfaces. We are investigating whether the morphology of biotic nanoetching can be used as a biosignature. Additional information is contained in the original extended abstract.

  16. Weather and Flight Testing

    NASA Technical Reports Server (NTRS)

    Wiley, Scott

    2007-01-01

    This viewgraph document reviews some of the weather hazards involved with flight testing. Some of the hazards reviewed are: turbulence, icing, thunderstorms and winds and windshear. Maps, pictures, satellite pictures of the meteorological phenomena and graphs are included. Also included are pictures of damaged aircraft.

  17. Worldwide Marine Weather Broadcasts.

    ERIC Educational Resources Information Center

    Department of the Navy, Washington, DC.

    This publication is a source of marine weather broadcast information in all areas of the world where such service is provided. This publication was designed for the use of U.S. naval and merchant ships. Sections 1 through 4 contain details of radio telegraph, radio telephone, radio facsimile, and radio teleprinter transmissions, respectively. The…

  18. Weather at LANL

    SciTech Connect

    Bruggeman, David Alan

    2016-04-19

    This report gives general information about how to become a meteorologist and what kinds of jobs exist in that field. Then it goes into detail about why weather is monitored at LANL, how it is done, and where the data can be accessed online.

  19. Weather, Climate, and You.

    ERIC Educational Resources Information Center

    Blai, Boris, Jr.

    Information from the American Institute of Medical Climatologists on human responses to weather and climatic conditions, including clouds, winds, humidity, barometric pressure, heat, cold, and other variables that may exert a pervasive impact on health, behavior, disposition, and the level of efficiency with which individuals function is reviewed.…

  20. Dress for the Weather

    ERIC Educational Resources Information Center

    Glen, Nicole J.; Smetana, Lara K.

    2010-01-01

    "If someone were traveling to our area for the first time during this time of year, what would you tell them to bring to wear? Why?" This question was used to engage students in a guided-inquiry unit about how climate differs from weather. In this lesson, students explored local and national data sets to give "travelers" advice…

  1. Shipboard Weather Observation.

    ERIC Educational Resources Information Center

    Palmaccio, Richard J.

    1983-01-01

    Details of how observers on a moving ship can furnish an accurate report of wind velocity are provided. A method employing vector addition and some trigonometry is covered. Wind velocity is initially indicated through an anemometer and a wind vane. Ships are urged to radio weather data. (MP)

  2. Rainy Weather Science.

    ERIC Educational Resources Information Center

    Reynolds, Karen

    1996-01-01

    Presents ideas on the use of rainy weather for activities in the earth, life, and physical sciences. Topics include formation and collision of raindrops, amount and distribution of rain, shedding of water by plants, mapping puddles and potholes, rainbow formation, stalking storms online, lightning, and comparing particles in the air before and…

  3. Weather in Motion.

    ERIC Educational Resources Information Center

    National Aeronautics and Space Administration, Washington, DC.

    The ATS-111 weather satellite, launched on November 18, 1967, in a synchronous earth orbit 22,000 miles above the equator, is described in this folder. The description is divided into these topics: the satellite, the camera, the display, the picture information, and the beneficial use of the satellite. Photographs from the satellite are included.…

  4. Satellite Weather Watch.

    ERIC Educational Resources Information Center

    Summers, R. Joe

    1982-01-01

    Describes an inexpensive (about $1,500) direct-readout ground station for use in secondary school science/mathematics programs. Includes suggested activities including, among others, developing map overlays, operating station equipment, interpreting satellite data, developing weather forecasts, and using microcomputers for data storage, orbit…

  5. Calibration of Smartphone-Based Weather Measurements Using Pairwise Gossip.

    PubMed

    Zamora, Jane Louie Fresco; Kashihara, Shigeru; Yamaguchi, Suguru

    2015-01-01

    Accurate and reliable daily global weather reports are necessary for weather forecasting and climate analysis. However, the availability of these reports continues to decline due to the lack of economic support and policies in maintaining ground weather measurement systems from where these reports are obtained. Thus, to mitigate data scarcity, it is required to utilize weather information from existing sensors and built-in smartphone sensors. However, as smartphone usage often varies according to human activity, it is difficult to obtain accurate measurement data. In this paper, we present a heuristic-based pairwise gossip algorithm that will calibrate smartphone-based pressure sensors with respect to fixed weather stations as our referential ground truth. Based on actual measurements, we have verified that smartphone-based readings are unstable when observed during movement. Using our calibration algorithm on actual smartphone-based pressure readings, the updated values were significantly closer to the ground truth values.

  6. Space Weather Workshop 2010 to Be Held in April

    NASA Astrophysics Data System (ADS)

    Peltzer, Thomas

    2010-03-01

    The annual Space Weather Workshop will be held in Boulder, Colo., 27-30 April 2010. The workshop will bring customers, forecasters, commercial service providers, researchers, and government agencies together in a lively dialogue about space weather. The workshop will include 4 days of plenary sessions on a variety of topics, with poster sessions focusing on the Sun, interplanetary space, the magnetosphere, and the ionosphere. The conference will address the remarkably diverse impacts of space weather on today's technology. Highlights on this year's agenda include ionospheric storms and their impacts on the Global Navigation Satellite System (GNSS), an update on NASA's recently launched Solar Dynamics Observatory (SDO), and new space weather-related activities in the Federal Emergency Management Agency (FEMA). Also this year, the Commercial Space Weather Interest Group will feature a presentation by former NOAA administrator, Vice Admiral Conrad Lautenbacher, U.S. Navy (Ret.).

  7. Calibration of Smartphone-Based Weather Measurements Using Pairwise Gossip

    PubMed Central

    Zamora, Jane Louie Fresco; Kashihara, Shigeru; Yamaguchi, Suguru

    2015-01-01

    Accurate and reliable daily global weather reports are necessary for weather forecasting and climate analysis. However, the availability of these reports continues to decline due to the lack of economic support and policies in maintaining ground weather measurement systems from where these reports are obtained. Thus, to mitigate data scarcity, it is required to utilize weather information from existing sensors and built-in smartphone sensors. However, as smartphone usage often varies according to human activity, it is difficult to obtain accurate measurement data. In this paper, we present a heuristic-based pairwise gossip algorithm that will calibrate smartphone-based pressure sensors with respect to fixed weather stations as our referential ground truth. Based on actual measurements, we have verified that smartphone-based readings are unstable when observed during movement. Using our calibration algorithm on actual smartphone-based pressure readings, the updated values were significantly closer to the ground truth values. PMID:26421312

  8. NAVSTAR Global Positioning System.

    DTIC Science & Technology

    1988-04-01

    number) The NAVSTAR Global Positioning System ( GPS ) is an all-weather, Jam-resistant, continuous-operations space-based, passive radio navigation and...with an understanding of the capabilities and limitations of the NAVSTAR Global Positioning System ( GPS ). II. Problem: To fight the next battle...navigation equipment and was not able to navigate on instruments or across a distant 9000-foot mountain. Had a NAVSTAR Global Positioning System ( GPS

  9. Weatherization Works: An interim report of the National Weatherization Evaluation

    SciTech Connect

    Brown, M.A.; Berry, L.G.; Kinney, L.F.

    1993-11-01

    The National Weatherization Evaluation is the first comprehensive evaluation of the Weatherization Assistance Program since 1984. The evaluation was designed to accomplish the following goals: Estimate energy savings and cost effectiveness; Assess nonenergy impacts; Describe the weatherization network; Characterize the eligible population and resources; and Identify factors influencing outcomes and opportunities for the future. As a national program, weatherization incorporates considerable diversity due to regional differences. Therefore, evaluation results are presented both in aggregate and for three climate regions: cold, moderate and hot.

  10. Present weathering rates in a humid tropical watershed: Nsimi, South Cameroon

    NASA Astrophysics Data System (ADS)

    Braun, Jean-Jacques; Ngoupayou, Jules Remy Ndam; Viers, Jérôme; Dupre, Bernard; Bedimo Bedimo, Jean-Pierre; Boeglin, Jean-Loup; Robain, Henri; Nyeck, Brunot; Freydier, Rémi; Nkamdjou, Luc Sigha; Rouiller, James; Muller, Jean-Pierre

    2005-01-01

    The study of biogeochemical and hydrological cycles in small experimental watersheds on silicate rocks, common for the Temperate Zone, has not yet been widely applied to the tropics, especially humid areas. This paper presents an updated database for a six-year period for the small experimental watershed of the Mengong brook in the humid tropics (Nsimi, South Cameroon). This watershed is developed on Precambrian granitoids (North Congo shield) and consists of two convexo-concave lateritic hills surrounding a large flat swamp covered by hydromorphic soils rich in upward organic matter. Mineralogical and geochemical investigations were carried out in the protolith, the saprolite, the hillside lateritic soils, and the swamp hydromorphic soils. Biomass chemical analyses were done for the representative species of the swamp vegetation. The groundwater was analysed from the parent rock/saprolite weathering front to the upper fringe in the hillside and swamp system. The chemistry of the wet atmospheric and throughfall deposits and the Mengong waters was monitored. In the Nsimi watershed the carbon transfer occurs primarily in an organic form and essentially as colloids produced by the slow biodegradation of the swamp organic matter. These organic colloids contribute significantly to the mobilization and transfer of Fe, Al, Zr, Ti, and Th in the uppermost first meter of the swamp regolith. When the organic colloid content is low (i.e., in the hillside groundwater), Th and Zr concentrations are extremely low (<3 pmol/L, ICP-MS detection limits). Strongly insoluble secondary thorianite (ThO 2) and primary zircon (ZrSiO 4) crystals control their mobilization, respectively. This finding thus justifies the potential use of both these elements as inert elements for isoelement mass balance calculations pertaining to the hillside regolith. Chloride can not be used as a conservative tracer of hydrological processes and chemical weathering in this watershed. Biogenic recycling

  11. A Sensitive Search for Exozodi Across the Ten-Micron Silicate Feature

    NASA Astrophysics Data System (ADS)

    Metchev, Stanimir

    2011-08-01

    I propose to test the feasibility of a differential photometric technique to identify faint dusty circumstellar debris disks with excess ten-micron silicate emission. A small number of perhaps the brightest such disks have been discovered by Spitzer and in archival IRAS data. These point to the potential existence of numerous other analogs of the solar system zodiacal dust belt. Silicate emission at ~10 micron is a distinctive feature of the excess signature of exozodiacal belts. The proposed technique employs differential narrow-band 8-11 micron photometry across the silicate feature, repeatedly sampling its 10-11 micron peak and its <9 micron low-flux wing. As aptly suggested by the TAC in the previous review of this proposal, the photometric precision of the approach was modeled by convolving the expected signal with the atmospheric transmission and instrument response profiles. The simulations are very encouraging, and have shown that the originally requested weather conditions were too restrictive. Eightieth percentile sky transparency at Mauna Kea (50%- ile at Cerro Pachon) is sufficient for the method to perform as well as exozodi searches with Spitzer around G stars within 25pc.

  12. Realtime Space Weather Forecasts Via Android Phone App

    NASA Astrophysics Data System (ADS)

    Crowley, G.; Haacke, B.; Reynolds, A.

    2010-12-01

    For the past several years, ASTRA has run a first-principles global 3-D fully coupled thermosphere-ionosphere model in real-time for space weather applications. The model is the Thermosphere-Ionosphere Mesosphere Electrodynamics General Circulation Model (TIMEGCM). ASTRA also runs the Assimilative Mapping of Ionospheric Electrodynamics (AMIE) in real-time. Using AMIE to drive the high latitude inputs to the TIMEGCM produces high fidelity simulations of the global thermosphere and ionosphere. These simulations can be viewed on the Android Phone App developed by ASTRA. The SpaceWeather app for the Android operating system is free and can be downloaded from the Google Marketplace. We present the current status of realtime thermosphere-ionosphere space-weather forcasting and discuss the way forward. We explore some of the issues in maintaining real-time simulations with assimilative data feeds in a quasi-operational setting. We also discuss some of the challenges of presenting large amounts of data on a smartphone. The ASTRA SpaceWeather app includes the broadest and most unique range of space weather data yet to be found on a single smartphone app. This is a one-stop-shop for space weather and the only app where you can get access to ASTRA’s real-time predictions of the global thermosphere and ionosphere, high latitude convection and geomagnetic activity. Because of the phone's GPS capability, users can obtain location specific vertical profiles of electron density, temperature, and time-histories of various parameters from the models. The SpaceWeather app has over 9000 downloads, 30 reviews, and a following of active users. It is clear that real-time space weather on smartphones is here to stay, and must be included in planning for any transition to operational space-weather use.

  13. Space Weather affects on Air Transportation

    NASA Astrophysics Data System (ADS)

    Jones, J. B. L.; Bentley, R. D.; Dyer, C.; Shaw, A.

    In Europe, legislation requires the airline industry to monitor the occupational exposure of aircrew to cosmic radiation. However, there are other significant impacts of space weather phenomena on the technological systems used for day-to-day operations which need to be considered by the airlines. These were highlighted by the disruption caused to the industry by the period of significant solar activity in late October and early November 2003. Next generation aircraft will utilize increasingly complex avionics as well as expanding the performance envelopes. These and future generation platforms will require the development of a new air-space management infrastructure with improved position accuracy (for route navigation and landing in bad weather) and reduced separation minima in order to cope with the expected growth in air travel. Similarly, greater reliance will be placed upon satellites for command, control, communication and information (C3I) of the operation. However, to maximize effectiveness of this globally interoperable C3I and ensure seamless fusion of all components for a safe operation will require a greater understanding of the space weather affects, their risks with increasing technology, and the inclusion of space weather information into the operation. This paper will review space weather effects on air transport and the increasing risks for future operations cause by them. We will examine how well the effects can be predicted, some of the tools that can be used and the practicalities of using such predictions in an operational scenario. Initial results from the SOARS ESA Space Weather Pilot Project will also be discussed,

  14. Characterizing Amorphous Silicates in Extraterrestrial Materials

    NASA Astrophysics Data System (ADS)

    Fu, X.; Wang, A.; Krawczynski, M. J.

    2015-12-01

    Amorphous silicates are common in extraterrestrial materials. They are seen in the matrix of carbonaceous chondrites as well as in planetary materials. Tagish Lake is one of the most primitive carbonaceous meteorites in which TEM and XRD analyses found evidence for poorly crystalline phyllosilicate-like species; Raman spectra revealed amorphous silicates with variable degree of polymerization and low crystallinity. On Mars, CheMin discovered amorphous phases in all analyzed samples, and poorly crystalline smectite in mudstone samples. These discoveries pose questions on the crystallinity of phyllosilicates found by remote sensing on Mars, which is directly relevant to aqueous alteration during geologic history of Mars. Our goal is to use spectroscopy to better characterize amorphous silicates. We use three approaches: (1) using silicate glasses synthesized with controlled chemistry to study the effects of silicate polymerization and (2) using phyllosilicates synthesized with controlled hydrothermal treatment to study the effect of crystallinity on vibrational spectroscopy, finally (3) to use the developed correlations in above two steps to study amorphous phases in meteorites, and those found in future missions to Mars. In the 1st step, silicate glasses were synthesized from pure oxides in a range of NBO/T ratios (from 0 to 4). Depending on the targeted NBO/T and composition of mixed oxides, temperatures for each experiment fell in a range from 1260 to 1520 °C, run for ~ 4 hrs. The melt was quenched in liquid N2 or water. Homogeneity of glass was checked under optical microscopy. Raman spectra were taken over 100 spots on small chips free of bubbles and crystals. We have observed that accompanying an increase of NBO/T, there is a strengthening and a position shift of the Raman peak near 1000 cm-1 (Si-Onon-bridging stretching mode), and the weakening of broad Raman peaks near 500 cm-1 (ring breathing mode) and 700cm-1 (Si-Obridging-Si mode). We are building the

  15. Amorphous Silicates in Primitive Meteoritic Materials: Acfer 094 and IDPs

    NASA Technical Reports Server (NTRS)

    Keller, L. P.; Nakamura-Messenger, K.; Messenger, S.; Walker, Robert M.

    2009-01-01

    The abundance of presolar grains is one measure of the primitive nature of meteoritic materials. Presolar silicates are abundant in meteorites whose matrices are dominated by amorphous silicates such as the unique carbonaceous chondrite Acfer 094. Presolar silicates are even more abundant in chondritic-porous interplanetary dust particles (CP-IDPs). Amorphous silicates in the form of GEMS (glass with embedded metal and sulfides) grains are a major component of CP IDPs. We are studying amorphous silicates in Acfer 094 matrix in order to determine whether they are related to the GEMS grains in CPIDPs

  16. Nanometre-scale evidence for interfacial dissolution-reprecipitation control of silicate glass corrosion

    NASA Astrophysics Data System (ADS)

    Hellmann, Roland; Cotte, Stéphane; Cadel, Emmanuel; Malladi, Sairam; Karlsson, Lisa S.; Lozano-Perez, Sergio; Cabié, Martiane; Seyeux, Antoine

    2015-03-01

    Silicate glasses are durable solids, and yet they are chemically unstable in contact with aqueous fluids—this has important implications for numerous industrial applications related to the corrosion resistance of glasses, or the biogeochemical weathering of volcanic glasses in seawater. The aqueous dissolution of synthetic and natural glasses results in the formation of a hydrated, cation-depleted near-surface alteration zone and, depending on alteration conditions, secondary crystalline phases on the surface. The long-standing accepted model of glass corrosion is based on diffusion-coupled hydration and selective cation release, producing a surface-altered zone. However, using a combination of advanced atomic-resolution analytical techniques, our data for the first time reveal that the structural and chemical interface between the pristine glass and altered zone is always extremely sharp, with gradients in the nanometre to sub-nanometre range. These findings support a new corrosion mechanism, interfacial dissolution-reprecipitation. Moreover, they also highlight the importance of using analytical methods with very high spatial and mass resolution for deciphering the nanometre-scale processes controlling corrosion. Our findings provide evidence that interfacial dissolution-reprecipitation may be a universal reaction mechanism that controls both silicate glass corrosion and mineral weathering.

  17. Nanometre-scale evidence for interfacial dissolution-reprecipitation control of silicate glass corrosion.

    PubMed

    Hellmann, Roland; Cotte, Stéphane; Cadel, Emmanuel; Malladi, Sairam; Karlsson, Lisa S; Lozano-Perez, Sergio; Cabié, Martiane; Seyeux, Antoine

    2015-03-01

    Silicate glasses are durable solids, and yet they are chemically unstable in contact with aqueous fluids-this has important implications for numerous industrial applications related to the corrosion resistance of glasses, or the biogeochemical weathering of volcanic glasses in seawater. The aqueous dissolution of synthetic and natural glasses results in the formation of a hydrated, cation-depleted near-surface alteration zone and, depending on alteration conditions, secondary crystalline phases on the surface. The long-standing accepted model of glass corrosion is based on diffusion-coupled hydration and selective cation release, producing a surface-altered zone. However, using a combination of advanced atomic-resolution analytical techniques, our data for the first time reveal that the structural and chemical interface between the pristine glass and altered zone is always extremely sharp, with gradients in the nanometre to sub-nanometre range. These findings support a new corrosion mechanism, interfacial dissolution-reprecipitation. Moreover, they also highlight the importance of using analytical methods with very high spatial and mass resolution for deciphering the nanometre-scale processes controlling corrosion. Our findings provide evidence that interfacial dissolution-reprecipitation may be a universal reaction mechanism that controls both silicate glass corrosion and mineral weathering.

  18. Bringing Weather into Your Classroom.

    ERIC Educational Resources Information Center

    Mogil, H. Michael

    1979-01-01

    Discusses meteorological resources available to classroom teachers. Describes in detail the National Oceanic and Atmospheric Administration (NOAA) Weather Radio and the A.M. Weather Show on Public Broadcasting Service (PBS). Includes addresses where teachers can get more information. (MA)

  19. Geography and Weather: Mountain Meterology.

    ERIC Educational Resources Information Center

    Mogil, H. Michael; Collins, H. Thomas

    1990-01-01

    Provided are 26 ideas to help children explore the effects of mountains on the weather. Weather conditions in Nepal and Colorado are considered separately. Nine additional sources of information are listed. (CW)

  20. Weathering the Storm: Nurses' Stories about Hurricane Sandy.

    PubMed

    Baumann, Steven L

    2014-07-01

    Proposed is a hermeneutic humanbecoming study on the reflections of 16 nurses' stories about Hurricane Sandy. The phenomenon of interest is weathering the storm. The research question is "what are the emerging meanings of the living experience of weathering the storm?" The perspective to be used is the humanbecoming school of thought. The participants were nurses who were living and working in New York City (NYC) during and after Hurricane Sandy. The emergent meanings are to enhance knowledge and understanding of the experience of weathering the storm for global health nursing.