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Sample records for gps wo mochiita

  1. Environmental applications of GPS

    SciTech Connect

    Vigil, S.A.; Zueck, D.

    1999-07-01

    The use of the Global Positioning System (GPS) has revolutionized air travel, ocean navigation, land navigation, and the collection of environmental data. Although a basic civilian GPS receiver can be purchased for as little as $100, the receiver is only the tip of a 12 billion dollar iceberg. This paper will discuss the history and basic operation of the Global Positioning System, a satellite-based precision positioning and timing service developed and operated by the Department of Defense. It will also describe the accuracy limitations of the civil GPS service and how accuracy can be enhanced by the use of differential GPS (DGPS), using either the free National Differential GPS system, or commercial differential monitor stations. Finally, the paper will discuss the future accuracy upgrades of civil GPS as a result of recent federal policy decisions.

  2. GPS Measurement Of Attitude

    NASA Technical Reports Server (NTRS)

    Dinardo, S. J.; Hushbeck, E. L.; Meehan, T. K.; Munson, T. N.; Purcell, G. H.; Srinivasan, J. M.; Young, L. E.; Yunck, T. P.

    1992-01-01

    Signals transmitted by satellites of Global Positioning System (GPS) measure orientation of baseline on ship, aircraft, or other vehicle with accuracy. Two GPS antennas and receivers placed at well separated points on platform. Receivers measure positions of ends of baseline as functions of time. Output processor computes vector difference between two positions and determines orientation of baseline. Combined with conventional GPS data, orientation data allows more precise navigation and mapping and enhances calculations related to performance and control of vehicle.

  3. USNO GPS program

    NASA Technical Reports Server (NTRS)

    Putkovich, K.

    1981-01-01

    Initial test results indicated that the Global Positioning System/Time Transfer Unit (GPS/TTU) performed well within the + or - 100 nanosecond range required by the original system specification. Subsequent testing involved the verification of GPS time at the master control site via portable clocks and the acquisition and tracking of as many passes of the space vehicles currently in operation as possible. A description and discussion of the testing, system modifications, test results obtained, and an evaluation of both GPS and the GPS/TTU are presented.

  4. Crop Dusting Using GPS

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Global Positioning System (GPS) receivers and GPS-based swath guidance systems are used on agricultural aircraft for remote sensing, airplane guidance, and to support variable-rate aerial application of crop inputs such as insecticides, cotton growth regulators, and defoliants. Agricultural aircraf...

  5. Aircraft landing using GPS

    NASA Astrophysics Data System (ADS)

    Lawrence, David Gary

    The advent of the Global Positioning System (GPS) is revolutionizing the field of navigation. Commercial aviation has been particularly influenced by this worldwide navigation system. From ground vehicle guidance to aircraft landing applications, GPS has the potential to impact many areas of aviation. GPS is already being used for non-precision approach guidance; current research focuses on its application to more critical regimes of flight. To this end, the following contributions were made: (1) Development of algorithms and a flexible software architecture capable of providing real-time position solutions accurate to the centimeter level with high integrity. This architecture was used to demonstrate 110 automatic landings of a Boeing 737. (2) Assessment of the navigation performance provided by two GPS-based landing systems developed at Stanford, the Integrity Beacon Landing System, and the Wide Area Augmentation System. (3) Preliminary evaluation of proposed enhancements to traditional techniques for GPS positioning, specifically, dual antenna positioning and pseudolite augmentation. (4) Introduction of a new concept for positioning using airport pseudolites. The results of this research are promising, showing that GPS-based systems can potentially meet even the stringent requirements of a Category III (zero visibility) landing system. Although technical and logistical hurdles still exist, it is likely that GPS will soon provide aircraft guidance in all phases of flight, including automatic landing, roll-out, and taxi.

  6. GPS Activities at SLAC

    SciTech Connect

    Behrend, Dirk

    2002-11-19

    The Alignment Engineering Group of the Stanford Linear Accelerator Center (SLAC) started to use RTK (real-time kinematic) GPS equipment in order to perform structure mapping and GIS-related tasks on the SLAC campus. In a first step a continuously observing GPS station (SLAC M40) was set up. This station serves as master control station for all differential GPS activities on site and its coordinates have been determined in the well-defined global geodetic datum ITRF2000 at a given reference epoch. Some trials have been performed to test the RTK method. The tests have proven RTK to be very fast and efficient.

  7. GPS system simulation methodology

    NASA Technical Reports Server (NTRS)

    Ewing, Thomas F.

    1993-01-01

    The following topics are presented: background; Global Positioning System (GPS) methodology overview; the graphical user interface (GUI); current models; application to space nuclear power/propulsion; and interfacing requirements. The discussion is presented in vugraph form.

  8. GPS Metric Tracking Unit

    NASA Technical Reports Server (NTRS)

    2008-01-01

    As Global Positioning Satellite (GPS) applications become more prevalent for land- and air-based vehicles, GPS applications for space vehicles will also increase. The Applied Technology Directorate of Kennedy Space Center (KSC) has developed a lightweight, low-cost GPS Metric Tracking Unit (GMTU), the first of two steps in developing a lightweight, low-cost Space-Based Tracking and Command Subsystem (STACS) designed to meet Range Safety's link margin and latency requirements for vehicle command and telemetry data. The goals of STACS are to improve Range Safety operations and expand tracking capabilities for space vehicles. STACS will track the vehicle, receive commands, and send telemetry data through the space-based asset, which will dramatically reduce dependence on ground-based assets. The other step was the Low-Cost Tracking and Data Relay Satellite System (TDRSS) Transceiver (LCT2), developed by the Wallops Flight Facility (WFF), which allows the vehicle to communicate with a geosynchronous relay satellite. Although the GMTU and LCT2 were independently implemented and tested, the design collaboration of KSC and WFF engineers allowed GMTU and LCT2 to be integrated into one enclosure, leading to the final STACS. In operation, GMTU needs only a radio frequency (RF) input from a GPS antenna and outputs position and velocity data to the vehicle through a serial or pulse code modulation (PCM) interface. GMTU includes one commercial GPS receiver board and a custom board, the Command and Telemetry Processor (CTP) developed by KSC. The CTP design is based on a field-programmable gate array (FPGA) with embedded processors to support GPS functions.

  9. Bacteriophage WO in Wolbachia infecting terrestrial isopods.

    PubMed

    Braquart-Varnier, Christine; Grève, Pierre; Félix, Christine; Martin, Gilbert

    2005-11-18

    Wolbachia are maternally inherited intracellular alpha-proteobacteria that infect a wide range of arthropods. They are associated with a number of different reproductive phenotypes in arthropods and nematodes. In isopod crustacean, Wolbachia are responsible for feminization of genetic males in many species, and for cytoplasmic incompatibility in two species. In this paper, we report the first detection of phage WO from Wolbachia infecting terrestrial isopods. All Wolbachia strains tested in this study were infected with phage WO. Based on the orf7 phage sequence, we identified three different phage sequences in four Wolbachia strains. The phage of Wolbachia infecting Armadillidium vulgare seems to be not active, unlike other phages WO previously described in arthropods. PMID:16198306

  10. Bacteriophage WO in Wolbachia infecting terrestrial isopods.

    PubMed

    Braquart-Varnier, Christine; Grève, Pierre; Félix, Christine; Martin, Gilbert

    2005-11-18

    Wolbachia are maternally inherited intracellular alpha-proteobacteria that infect a wide range of arthropods. They are associated with a number of different reproductive phenotypes in arthropods and nematodes. In isopod crustacean, Wolbachia are responsible for feminization of genetic males in many species, and for cytoplasmic incompatibility in two species. In this paper, we report the first detection of phage WO from Wolbachia infecting terrestrial isopods. All Wolbachia strains tested in this study were infected with phage WO. Based on the orf7 phage sequence, we identified three different phage sequences in four Wolbachia strains. The phage of Wolbachia infecting Armadillidium vulgare seems to be not active, unlike other phages WO previously described in arthropods.

  11. Networked differential GPS system

    NASA Technical Reports Server (NTRS)

    Mueller, K. Tysen (Inventor); Loomis, Peter V. W. (Inventor); Kalafus, Rudolph M. (Inventor); Sheynblat, Leonid (Inventor)

    1994-01-01

    An embodiment of the present invention relates to a worldwide network of differential GPS reference stations (NDGPS) that continually track the entire GPS satellite constellation and provide interpolations of reference station corrections tailored for particular user locations between the reference stations Each reference station takes real-time ionospheric measurements with codeless cross-correlating dual-frequency carrier GPS receivers and computes real-time orbit ephemerides independently. An absolute pseudorange correction (PRC) is defined for each satellite as a function of a particular user's location. A map of the function is constructed, with iso-PRC contours. The network measures the PRCs at a few points, so-called reference stations and constructs an iso-PRC map for each satellite. Corrections are interpolated for each user's site on a subscription basis. The data bandwidths are kept to a minimum by transmitting information that cannot be obtained directly by the user and by updating information by classes and according to how quickly each class of data goes stale given the realities of the GPS system. Sub-decimeter-level kinematic accuracy over a given area is accomplished by establishing a mini-fiducial network.

  12. Time-resolved spectroscopy in ZnWO4 and ZnWO4 : Fe

    NASA Astrophysics Data System (ADS)

    Grigorjeva, L.; Pankratov, V.; Millers, D.; Chernov, S.; Nagirnyi, V.; Kotlov, A.; Watterich, A.

    2003-01-01

    Time-resolved luminescence and absorption of ZnWO4 and ZnWO4:Fe have been studied. The fast decaying luminescence at similar to 1.7 eV is attributed to either Fe2+ or a Fe3+ related center. The two observed stages in luminescence decay kinetics under ionising radiation are suggested to be due to two types of self-trapped excitons.

  13. The GPS Space Service Volume

    NASA Technical Reports Server (NTRS)

    Bauer, F. H.; Moreau, M. C.; Dahle-Melsaether, M. E.; Petrofski, W. P.; Stanton, B. J.; Thomason, S.; Harris, G. A.; Sena, R. P.; Temple, L. Parker, III

    2006-01-01

    Prior to the advent of artificial satellites, the concept of navigating in space and the desire to understand and validate the laws of planetary and satellite motion dates back centuries. At the initiation of orbital flight in 1957, space navigation was dominated by inertial and groundbased tracking methods, underpinned by the laws of planetary motion. It was early in the 1980s that GPS was first explored as a system useful for refining the position, velocity, and timing (PVT) of other spacecraft equipped with GPS receivers. As a result, an entirely new GPS utility was developed beyond its original purpose of providing PVT services for land, maritime, and air applications. Spacecraft both above and below the GPS constellation now receive the GPS signals, including the signals that spill over the limb of the Earth. The use of radionavigation satellite services for space navigation in High Earth Orbits is in fact a capability unique to GPS. Support to GPS space applications is being studied and planned as an important improvement to GPS. This paper discusses the formalization of PVT services in space as part of an overall GPS improvement effort. It describes the GPS Space Service Volume (SSV) and compares it to the Terrestrial Service Volume (TSV). It also discusses SSV coverage with the current GPS constellation, coverage characteristics as a function of altitude, expected power levels, and coverage figures of merit.

  14. GPS lessons learned

    NASA Technical Reports Server (NTRS)

    Heflin, Michael B.

    2003-01-01

    Global geodesy has improved dramatically over the past decade starting with the GPS for IERS and Geodynamics demonstration campaign in 1991 (GIG 91). At the time it took over a week of CPU time to process a network solution based on 21 global receivers and orbit overlaps were in the 40 cm range. Today it is possible to process a network solution based on 80 global receivers in less then one day of CPU time and orbit overlaps are in the 4 cm range. Special methods are under development for efficient processing of increasingly large regional networks which may contain hundreds or thousands of GPS receivers. Along the way there have been many lessons learned about GPS satellites, receivers, monuments, antennas, radomes, analysis, reference frames, error sources, and interpretation. A wide range of scientific disciplines have been impacted including studies of plate motion, post-glacial rebound, seasonal loading, deformation in plate boundary zones, coseismic displacements due to major earthquakes, postseiemic relaxation, and interseismic strain accumulation related to assessment of seismic hazards. Lessons learned will be presented in the context of new dense networks such as the Plate Boundary Observation (PBO).

  15. Augmented reality using GPS

    NASA Astrophysics Data System (ADS)

    Kim, Juwan; Kim, Haedong; Jang, Byungtae; Kim, Jungsik; Kim, Donghyun

    1998-04-01

    This paper describes a prototype system to be developing using GPS (Global Positioning System) as a tracker in order to combine real images with virtual geographical images in real time. To cover long distances, this system is built using a monitor-based configuration and divided into two parts. One is the real scene acquisition system that includes a vehicle, a wireless CCD camera, a GPS attitude determination device and a wireless data communication device. The other is the processing and visualization system that includes a wireless data communication device, a PC with a video overlay card and a 3D graphics accelerator. The pilot area of the current system is the part of SERI (Systems Engineering Research Institute) which is the institute we are working for now. And virtual objects are generated with 3D modeling data of the main building, the new building to be planned, and so on in SERI. The wireless CCD camera attached to a vehicle acquires the real scenes. And GPS attitude determination device produces a wireless CCD camera's position and orientation data. And then this information is transmitted to the processing and visualization part by air. In the processing and visualization system, virtual images are rendered using the received information and combined with the real scenes. Applications are an enhanced bird's-eye view and disaster rescue work such as earthquake.

  16. Detection and phylogenetic analysis of bacteriophage WO in spiders (Araneae).

    PubMed

    Yan, Qian; Qiao, Huping; Gao, Jin; Yun, Yueli; Liu, Fengxiang; Peng, Yu

    2015-11-01

    Phage WO is a bacteriophage found in Wolbachia. Herein, we represent the first phylogenetic study of WOs that infect spiders (Araneae). Seven species of spiders (Araneus alternidens, Nephila clavata, Hylyphantes graminicola, Prosoponoides sinensis, Pholcus crypticolens, Coleosoma octomaculatum, and Nurscia albofasciata) from six families were infected by Wolbachia and WO, followed by comprehensive sequence analysis. Interestingly, WO could be only detected Wolbachia-infected spiders. The relative infection rates of those seven species of spiders were 75, 100, 88.9, 100, 62.5, 72.7, and 100 %, respectively. Our results indicated that both Wolbachia and WO were found in three different body parts of N. clavata, and WO could be passed to the next generation of H. graminicola by vertical transmission. There were three different sequences for WO infected in A. alternidens and two different WO sequences from C. octomaculatum. Only one sequence of WO was found for the other five species of spiders. The discovered sequence of WO ranged from 239 to 311 bp. Phylogenetic tree was generated using maximum likelihood (ML) based on the orf7 gene sequences. According to the phylogenetic tree, WOs in N. clavata and H. graminicola were clustered in the same group. WOs from A. alternidens (WAlt1) and C. octomaculatum (WOct2) were closely related to another clade, whereas WO in P. sinensis was classified as a sole cluster.

  17. Reactivity of Hydrogen and Methanol on (001) Surfaces of WO3, ReO3, WO3/ReO3 and ReO3/WO3

    SciTech Connect

    Ling, Sanliang; Mei, Donghai; Gutowski, Maciej S.

    2011-05-16

    Bulk tungsten trioxide (WO3) and rhenium trioxide (ReO3) share very similar structures but display different electronic properties. WO3 is a wide bandgap semiconductor while ReO3 is an electronic conductor. With the advanced molecular beam epitaxy techniques, it is possible to make heterostructures comprised of layers of WO3 and ReO3. These heterostructures might display reactivity different than pure WO3 and ReO3. The interactions of two probe molecules (hydrogen and methanol) with the (001) surfaces of WO3, ReO3, and two heterostructures ReO3/WO3 and WO3/ReO3 were investigated at the density functional theory level. Atomic hydrogen prefers to adsorb at the terminal O1C sites forming a surface hydroxyl on four surfaces. Dissociative adsorption of a hydrogen molecule at the O1C site leads to formation of a water molecule adsorbed at the surface M5C site. This is thermodynamically the most stable state. A thermodynamically less stable dissociative state involves two surface hydroxyl groups O1CH and O2CH. The interaction of molecular hydrogen and methanol with pure ReO3 is stronger than with pure WO3 and the strength of the interaction substantially changes on the WO3/ReO3 and ReO3/WO3 heterostructures. The reaction barriers for decomposition and recombination reactions are sensitive to the nature of heterostructure. The calculated adsorption energy of methanol on WO3(001) of -65.6 kJ/mol is consistent with the previous experimental estimation of -67 kJ/mol. This material is based upon work supported as part of the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the US Department of Energy, Office of Science, Office of Basic Energy Sciences.

  18. Synthesis of dumbbell-like Bi2WO6@CaWO4 composite photocatalyst and application in water treatment

    NASA Astrophysics Data System (ADS)

    Zhang, Zhijie; Wang, Wenzhong; Jiang, Dong; Xu, Jiayue

    2014-02-01

    Dumbbell-like Bi2WO6@CaWO4 composite photocatalyst was successfully synthesized via hydrothermal method in one step, in which the Bi2WO6 nanoplates assembled on the surface of the CaWO4 microspheres. The growth mechanism of such a special micro-nano structure was investigated. This structure holds the advantages of both a microstructure and a nanostructure, which can not only ensure the sufficient contact between the Bi2WO6 photocatalyst and the organic molecules, but also favor the sediment of the catalyst particles. Photocatalytic degradation of rhodamine B (RhB), demonstrated that the Bi2WO6@CaWO4 composite reserved the high photo-activity of Bi2WO6. Besides RhB, the Bi2WO6@CaWO4 composite could also degrade other model pollutants such as methyl orange (MO) and phenol effectively. Moreover, the composite photocatalyst could settle naturally in 15 min, which is beneficial for its separation and recycling.

  19. Sensing Human Activity: GPS Tracking

    PubMed Central

    van der Spek, Stefan; van Schaick, Jeroen; de Bois, Peter; de Haan, Remco

    2009-01-01

    The enhancement of GPS technology enables the use of GPS devices not only as navigation and orientation tools, but also as instruments used to capture travelled routes: as sensors that measure activity on a city scale or the regional scale. TU Delft developed a process and database architecture for collecting data on pedestrian movement in three European city centres, Norwich, Rouen and Koblenz, and in another experiment for collecting activity data of 13 families in Almere (The Netherlands) for one week. The question posed in this paper is: what is the value of GPS as ‘sensor technology’ measuring activities of people? The conclusion is that GPS offers a widely useable instrument to collect invaluable spatial-temporal data on different scales and in different settings adding new layers of knowledge to urban studies, but the use of GPS-technology and deployment of GPS-devices still offers significant challenges for future research. PMID:22574061

  20. Shuttle Global Positioning System (GPS) design study

    NASA Technical Reports Server (NTRS)

    Nilsen, P. W.

    1979-01-01

    The effects of oscillator noise on Shuttle Global Positioning System (GPS) receiver performance, GPS navigation system self-test, GPS ground transmitter design to augment shuttle navigation, the effect of ionospheric delay modelling on GPS receiver design, and GPS receiver tracking of Shuttle transient maneuvers were investigated.

  1. A GPS coverage model

    NASA Technical Reports Server (NTRS)

    Skidmore, Trent A.

    1994-01-01

    The results of several case studies using the Global Positioning System coverage model developed at Ohio University are summarized. Presented are results pertaining to outage area, outage dynamics, and availability. Input parameters to the model include the satellite orbit data, service area of interest, geometry requirements, and horizon and antenna mask angles. It is shown for precision-landing Category 1 requirements that the planned GPS 21 Primary Satellite Constellation produces significant outage area and unavailability. It is also shown that a decrease in the user equivalent range error dramatically decreases outage area and improves the service availability.

  2. GPS Sounding Rocket Developments

    NASA Technical Reports Server (NTRS)

    Bull, Barton

    1999-01-01

    Sounding rockets are suborbital launch vehicles capable of carrying scientific payloads several hundred miles in altitude. These missions return a variety of scientific data including; chemical makeup and physical processes taking place in the atmosphere, natural radiation surrounding the Earth, data on the Sun, stars, galaxies and many other phenomena. In addition, sounding rockets provide a reasonably economical means of conducting engineering tests for instruments and devices used on satellites and other spacecraft prior to their use in more expensive activities. This paper addresses the NASA Wallops Island history of GPS Sounding Rocket experience since 1994 and the development of highly accurate and useful system.

  3. Position, Navigation, and Timing: GPS Scientific Applications

    NASA Technical Reports Server (NTRS)

    Neilan, Ruth E.

    2008-01-01

    This slide presentation reviews the development and deployment of the Global Positioning System (GPS). This presentation also includes measuring space and time, GPS as a tool for science, development of high precision JPL GPS receivers, and technology and applications developments.

  4. GPS Moving Vehicle Experiment

    NASA Technical Reports Server (NTRS)

    Oaks, O. J.; Reid, Wilson; Wright, James; Duffey, Christopher; Williams, Charles; Warren, Hugh; Zeh, Tom; Buisson, James

    1996-01-01

    The Naval Research Laboratory (NRL) in the development of timing systems for remote locations, had a technical requirement for a Y code (SA/AS) Global Positioning System (GPS) precise time transfer receiver (TTR) which could be used both in a stationary mode or mobile mode. A contract was awarded to the Stanford Telecommunication Corporation (STEL) to build such a device. The Eastern Range (ER) als had a requirement for such a receiver and entered into the contract with NRL for the procurement of additional receivers. The Moving Vehicle Experiment (MVE) described in this paper is the first in situ test of the STEL Model 5401C Time Transfer System in both stationary and mobile operations. The primary objective of the MVE was to test the timing accuracy of the newly developed GPS TTR aboard a moving vessel. To accomplish this objective, a joint experiment was performed with personnel from NRL and the er at the Atlantic Undersea Test and Evaluation Center (AUTEC) test range at Andros Island. Results and discussion of the test are presented in this paper.

  5. GPS Sounding Rocket Developments

    NASA Technical Reports Server (NTRS)

    Bull, Barton

    1999-01-01

    Sounding rockets are suborbital launch vehicles capable of carrying scientific payloads several hundred miles in altitude. These missions return a variety of scientific data including; chemical makeup and physical processes taking place In the atmosphere, natural radiation surrounding the Earth, data on the Sun, stars, galaxies and many other phenomena. In addition, sounding rockets provide a reasonably economical means of conducting engineering tests for instruments and devices used on satellites and other spacecraft prior to their use in more expensive activities. The NASA Sounding Rocket Program is managed by personnel from Goddard Space Flight Center Wallops Flight Facility (GSFC/WFF) in Virginia. Typically around thirty of these rockets are launched each year, either from established ranges at Wallops Island, Virginia, Poker Flat Research Range, Alaska; White Sands Missile Range, New Mexico or from Canada, Norway and Sweden. Many times launches are conducted from temporary launch ranges in remote parts of the world requi6ng considerable expense to transport and operate tracking radars. An inverse differential GPS system has been developed for Sounding Rocket. This paper addresses the NASA Wallops Island history of GPS Sounding Rocket experience since 1994 and the development of a high accurate and useful system.

  6. In situ synthesis of CdS/CdWO4/WO3 heterojunction films with enhanced photoelectrochemical properties

    NASA Astrophysics Data System (ADS)

    Zhan, Faqi; Li, Jie; Li, Wenzhang; Yang, Yahui; Liu, Wenhua; Li, Yaomin

    2016-09-01

    CdS/CdWO4/WO3 heterojunction films on fluorine-doped tin oxide (FTO) substrates are for the first time prepared as an efficient photoanode for photoelectrochemical (PEC) hydrogen generation by an in situ conversion process. The samples are characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), ultraviolet visible spectrometry (UV-vis) and X-ray photoelectron spectroscopy (XPS). The CdS hollow spheres (∼80 nm) sensitized WO3 plate film with a CdWO4 buffer-layer exhibits increased visible light absorption and a significantly improved photoelectrochemical performance. The photocurrent density at 0 V (vs. Ag/AgCl) of the CdS/CdWO4/WO3 anode is ∼3 times higher than that of the CdWO4/WO3 anode, and ∼9 times higher than that of pure WO3 under illumination. The highest incident-photon-to-current-efficiency (IPCE) value increased from 16% to 63% when the ternary heterojunction was formed. This study demonstrates that the synthesis of ternary composite photocatalysts by the in situ conversion process may be a promising approach to achieve high photoelectric conversion efficiency.

  7. Determining GPS average performance metrics

    NASA Technical Reports Server (NTRS)

    Moore, G. V.

    1995-01-01

    Analytic and semi-analytic methods are used to show that users of the GPS constellation can expect performance variations based on their location. Specifically, performance is shown to be a function of both altitude and latitude. These results stem from the fact that the GPS constellation is itself non-uniform. For example, GPS satellites are over four times as likely to be directly over Tierra del Fuego than over Hawaii or Singapore. Inevitable performance variations due to user location occur for ground, sea, air and space GPS users. These performance variations can be studied in an average relative sense. A semi-analytic tool which symmetrically allocates GPS satellite latitude belt dwell times among longitude points is used to compute average performance metrics. These metrics include average number of GPS vehicles visible, relative average accuracies in the radial, intrack and crosstrack (or radial, north/south, east/west) directions, and relative average PDOP or GDOP. The tool can be quickly changed to incorporate various user antenna obscuration models and various GPS constellation designs. Among other applications, tool results can be used in studies to: predict locations and geometries of best/worst case performance, design GPS constellations, determine optimal user antenna location and understand performance trends among various users.

  8. Optimal Preprocessing Of GPS Data

    NASA Technical Reports Server (NTRS)

    Wu, Sien-Chong; Melbourne, William G.

    1994-01-01

    Improved technique for preprocessing data from Global Positioning System (GPS) receiver reduces processing time and number of data to be stored. Technique optimal in sense it maintains strength of data. Also sometimes increases ability to resolve ambiguities in numbers of cycles of received GPS carrier signals.

  9. Performance: GPs in the spotlight.

    PubMed

    Clews, Graham

    2009-08-13

    PCTs are having to review the level of service they are getting from GP practices. The balanced scorecard tool attempts to combine quality and efficiency indicators. GPs' concerns include publication of the scorecard data without agreement by the GPs. PMID:19810224

  10. GPS Position Time Series @ JPL

    NASA Technical Reports Server (NTRS)

    Owen, Susan; Moore, Angelyn; Kedar, Sharon; Liu, Zhen; Webb, Frank; Heflin, Mike; Desai, Shailen

    2013-01-01

    Different flavors of GPS time series analysis at JPL - Use same GPS Precise Point Positioning Analysis raw time series - Variations in time series analysis/post-processing driven by different users. center dot JPL Global Time Series/Velocities - researchers studying reference frame, combining with VLBI/SLR/DORIS center dot JPL/SOPAC Combined Time Series/Velocities - crustal deformation for tectonic, volcanic, ground water studies center dot ARIA Time Series/Coseismic Data Products - Hazard monitoring and response focused center dot ARIA data system designed to integrate GPS and InSAR - GPS tropospheric delay used for correcting InSAR - Caltech's GIANT time series analysis uses GPS to correct orbital errors in InSAR - Zhen Liu's talking tomorrow on InSAR Time Series analysis

  11. Nd:SrWO 4 and Nd:BaWO 4 Raman lasers

    NASA Astrophysics Data System (ADS)

    Šulc, J.; Jelínková, H.; Basiev, T. T.; Doroschenko, M. E.; Ivleva, L. I.; Osiko, V. V.; Zverev, P. G.

    2007-09-01

    Properties of the laser operation and simultaneously stimulated Raman scattering in the SRS-active neodymium doped SrWO4 and BaWO4 crystals coherently end-pumped at wavelength 752 nm by pulsed free-running alexandrite laser radiation were investigated. The Nd3+ ion emission at wavelength λNd ˜ 1.06 μm was corresponding to 4F3/2 → 4I11/2 transition. To reach the SRS-self-conversion threshold inside Raman crystal the Nd3+ lasers were operating in a Q-switching regime. For Q-switching LiF:F2- crystal as a saturable absorber was used. Raman self-conversion at wavelength ˜1.17 μm was successfully reached with both tungstate crystals. The shortest generated pulse (1.3 ns FWHM) and highest peak power (615 kW) was obtained with Nd:BaWO4 Raman laser Q-switched by LiF:F2- crystal with initial transmission T0 = 60%. Up to 0.8 mJ was registered at the first Stokes wavelength 1169 nm. Using Q-switched Nd:SrWO4 laser higher energy in Raman emission was obtained (1.23 mJ) but generated pulse was longer (2.9 ns FWHM) resulting in lower peak power (430 kW).

  12. 75 FR 8928 - Announcement of IS-GPS-200, IS-GPS-705, IS-GPS-800 Interface Control Working Group (ICWG...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-02-26

    ... Department of the Air Force Announcement of IS-GPS-200, IS-GPS-705, IS-GPS-800Interface Control Working Group... an Interface Control Working Group (ICWG) teleconference meeting for document/s IS-GPS-200E (NAVSTAR GPS Space Segment/Navigation User Interfaces), IS-GPS-705A (NAVSTAR GPS Space Segment/User Segment...

  13. NASA's Global Differential GPS System

    NASA Astrophysics Data System (ADS)

    Bar-Sever, Y.; Muellerschoen, R.

    2003-04-01

    The NASA Global Differential GPS (GDGPS) system provides an unparalleled combination of real time positioning accuracy and availability. Developed and operated by the Jet Propulsion Laboratory (JPL) for NASA’s terrestrial, airborne, and spaceborne applications, the GDGPS system processes real time GPS data from a global network of more than 40 dual frequency GPS ground sites. It is the only network providing global, multiply-redundant, real time coverage of all GPS satellites, all the time. The system has demonstrated real time positioning accuracy of 10 cm horizontally, and 20 cm vertically for users anywhere in the world, on the ground and in the air. Real time orbit determination of low Earth satellites carrying precise GPS receivers was demonstrated to achieve accuracy of 10 30 cm 3D RMS (depending primarily on altitude). A track record of 99.99% availability extends from January 2000 to the present. We will describe the unique Internet-based architecture of the system, and the concept of reliability through redundancy, and discuss the capability of system to enhance many science and civil applications, as well as the potential of the system for GPS integrity monitoring and for GPS enhancements.

  14. Nd:SrWO4 Raman laser

    NASA Astrophysics Data System (ADS)

    Jelinkova, Helena; Sulc, Jan; Doroschenko, Maxim E.; Skornyakov, Vadim V.; Kravtsov, Sergey B.; Basiev, Tasoltan T.; Zverev, Peter G.

    2004-09-01

    Properties of the laser operation and simultaneously stimulated Raman scattering in the new SRS-active neodymium doped SrWO4 crystal coherently end-pumped by alexandrite 752 nm laser radiation were investigated. The maximum generated energy 90 mJ from the free-running Nd3+:SrWO4 laser at 1057 nm wavelength was obtained with the output coupler reflectivity 52%. The slope efficiency reached s = 0.52, the beam characteristic parameters M2 and divergence q were 2.5 +/- 0.1, and 1.5 +/- 0.1 mrad, respectively. Maximal output energy of 1.46 mJ for the fundamental wavelength was obtained for Q-switched Nd3+:SrWO4 oscillator with a double Fabry-Perrot as the output coupler (R = 48%), and with the 5% initial transmission of LiF:F2- saturable absorber. Up to 0.74 mJ energy was registered at the first Stokes frequency. The pulse duration was 5 ns and 2.4 ns for the fundamental and Stokes radiation, respectively. The energy of 1.25 mJ at 1170 nm was obtained for closed Raman resonator with special mirrors. For the case of mode-locking, two dye saturable absorbers (ML51 dye in dichlorethan and 3955 dye in ethanol) were used and SRS radiation in the form of pulse train was observed. The influence of the various Raman laser output couplers reflectivity as well as the initial transmissions of passive absorbers were investigated with the goal of the output energy maximization at the Stokes wavelength. In the output, the total measured energy was 1.8 mJ (for ML51 dye) and 2.4 mJ (for 3955 dye). The SRS output at 1170 nm was approximately 20% of total energy.

  15. Precise GPS orbits for geodesy

    NASA Astrophysics Data System (ADS)

    Colombo, Oscar L.

    1994-05-01

    The Global Positioning System (GPS) has become, in recent years, the main space-based system for surveying and navigation in many military, commercial, cadastral, mapping, and scientific applications. Better receivers, interferometric techniques (DGPS), and advances in post-processing methods have made possible to position fixed or moving receivers with sub-decimeter accuracies in a global reference frame. Improved methods for obtaining the orbits of the GPS satellites have played a major role in these achievements; this paper gives a personal view of the main developments in GPS orbit determination.

  16. Precise GPS orbits for geodesy

    NASA Technical Reports Server (NTRS)

    Colombo, Oscar L.

    1994-01-01

    The Global Positioning System (GPS) has become, in recent years, the main space-based system for surveying and navigation in many military, commercial, cadastral, mapping, and scientific applications. Better receivers, interferometric techniques (DGPS), and advances in post-processing methods have made possible to position fixed or moving receivers with sub-decimeter accuracies in a global reference frame. Improved methods for obtaining the orbits of the GPS satellites have played a major role in these achievements; this paper gives a personal view of the main developments in GPS orbit determination.

  17. Synergism of SLR and GPS

    NASA Technical Reports Server (NTRS)

    Schutz, Bob E.

    1994-01-01

    The launch of GPS-35 (RPN 5) with a laser retroreflector has provided an opportunity to compare SLR-determined orbits of a GPS satellite with those determined by GPS receivers operated with the transmitted radio signals on the L(sub 1) and L(sub 2) frequencies. Operational considerations of the SLR and hardware design have influenced the amount and quality of SLR data collected on this satellite. As of February 1, 1994, all of the collected SLR data have been collected from northern hemisphere stations. Adequate southern hemisphere coverage is required to fully compare the results obtained from L(sub 1)/L(sub 2) and from SLR.

  18. Analysis of Spaceborne GPS Systems

    NASA Technical Reports Server (NTRS)

    Cosmo, Mario L.; Davis, James L.; Elosegui, Pedro; Hill, Michael; ScireScapuzzo, Francesca

    1998-01-01

    A reasonable amount of literature can be found on the general topic of GPS receiving antennas, but very little has been published on spaceborne GPS receiving antennas. This very new topic seems to be so far more of interest for the industrial world than for the academic community. For satellite applications, microstrip antennas are usually preferred over other types of antennas mainly because of their non-electrical characteristics, such as small size, relatively lightweight, shape, possibility of integration with microwave integrated circuits, and relatively low costs. Careful design of patch antennas could meet all the requirements (electrical and non-electrical) of GPS receiving antenna to be mounted on a tethered satellite.

  19. Microwave-assisted synthesis of Zn-WO3 and ZnWO4 for pseudocapacitor applications

    NASA Astrophysics Data System (ADS)

    Kumar, R. Dhilip; Andou, Y.; Karuppuchamy, S.

    2016-05-01

    Nanosized Zn-WO3 and ZnWO4 materials have been prepared by microwave irradiation method. The physico-chemical characterization of the prepared nanomaterials was carried out by X-ray diffraction (XRD) and high resolution-scanning electron microscopy (HR-SEM) techniques. The size and shape of the ZnWO4 material can be controlled by changing the temperature. The XRD analysis revealed the formation of monoclinic phase of the calcined nanopowder. The HR-SEM images showed the sphere and plate shape particles. The electrochemical behavior of the ZnWO4 modified electrodes was investigated using electrochemical impedance spectroscopy (EIS), cyclic voltammetry (CV) and galvanostatic charge-discharge (GCD) techniques. The synthesized material shows the pseudocapacitance. The specific capacitance of 35.70 F/g was achieved for the Zn-WO3 nanopowder.

  20. Synthesis of S-doped WO3 nanowires with enhanced photocatalytic performance towards dye degradation

    NASA Astrophysics Data System (ADS)

    Han, Fugui; Li, Heping; Fu, Li; Yang, Jun; Liu, Zhong

    2016-05-01

    In this letter, S-doped WO3 nanowires (S-WO3) were prepared using a hydrothermal method followed by a low-temperature solid-state annealing treatment. The synthesized S-WO3 was characterized by SEM, EDX, XRD, XPS, Raman spectroscopy, UV-vis DRS and photocurrent responses. The results indicated that S could enhance the light harvesting capacity of WO3 nanowires. The photocatalytic performance of the S-WO3 was investigated by photodegradation of methyl orange (MO) under visible light irradiation. Results demonstrated that the photocatalytic activity of the S-WO3 nanowires is much higher than that of pure WO3 nanowires.

  1. Scintillation-Hardened GPS Receiver

    NASA Technical Reports Server (NTRS)

    Stephens, Donald R.

    2015-01-01

    CommLargo, Inc., has developed a scintillation-hardened Global Positioning System (GPS) receiver that improves reliability for low-orbit missions and complies with NASA's Space Telecommunications Radio System (STRS) architecture standards. A software-defined radio (SDR) implementation allows a single hardware element to function as either a conventional radio or as a GPS receiver, providing backup and redundancy for platforms such as the International Space Station (ISS) and high-value remote sensing platforms. The innovation's flexible SDR implementation reduces cost, weight, and power requirements. Scintillation hardening improves mission reliability and variability. In Phase I, CommLargo refactored an open-source GPS software package with Kalman filter-based tracking loops to improve performance during scintillation and also demonstrated improved navigation during a geomagnetic storm. In Phase II, the company generated a new field-programmable gate array (FPGA)-based GPS waveform to demonstrate on NASA's Space Communication and Navigation (SCaN) test bed.

  2. Ephemeris errors of GPS satellites

    NASA Technical Reports Server (NTRS)

    Colombo, O. L.

    1986-01-01

    Numerical models are developed to examine the potential effects of solar radiation, the terrestrial gravitational field, and the estimated initial state of the Global Positioning System (GPS) satellites, along with the capability of current models to account for the effects on the ephemeris of the GPS constellation. Of particular interest is the accuracy of the satellite position predictions for applications in geodesy. The main characteristics of the GPS orbits are reviewed and linear combinations of possible errors for 3 day ephemerides are examined. It is shown that the effects of the forces on the GPS orbits will be dynamic, yet can be expressed simply enough to maintain positioning accuracy to 1 percent. The calculations can also take into consideration solar wind pressure on the solar panels.

  3. Synthesis, Characterization, and Gas Sensing Applications of WO3 Nanobricks

    NASA Astrophysics Data System (ADS)

    Xiao, Jingkun; Song, Chengwen; Dong, Wei; Li, Chen; Yin, Yanyan; Zhang, Xiaoni; Song, Mingyan

    2015-08-01

    WO3 nanobricks are fabricated by a simple hydrothermal method. Morphology and structure of the WO3 nanobricks are characterized by scanning electron microscopy and x-ray diffraction. Gas sensing properties of the as-prepared WO3 sensor are systematically investigated by a static gas sensing system. The results show that the WO3 nanobricks with defect corners demonstrate good crystallinity, and the mean edge length and wall thickness are 1-1.5 and 400 nm, respectively. The WO3 sensor achieves its maximum sensitivity to 100 ppm ethanol at the optimal operating temperature of 300 °C. Ultra-fast response time (2-3 s) and fast recovery time (4-11 s) of the WO3 sensor toward 100 ppm ethanol are also observed at this optimal operating temperature. Moreover, the WO3 sensor exhibits high selectivity to other gases such as methanol, benzene, hexane, and dichloromethane, indicating its excellent potential application as a gas sensor for ethanol detection.

  4. WO3 nanopaticles and PEDOT:PSS/WO3 composite thin films studied for photocatalytic and electrochromic applications

    NASA Astrophysics Data System (ADS)

    Ivanov Boyadjiev, Stefan; Manduca, Bruno; Szűcs, Júlia; Miklós Szilágyi, Imre

    2016-03-01

    WO3 is a widely studied material for electrochromic and photocatalytic applications. In the present study, WO3 nanoparticles with a controlled structure (monoclinic or hexagonal) were obtained by controlled thermal decomposition of hexagonal ammonium tungsten bronze in air at 500 °C and 600 °C, respectively. The formation, morphology, structure and composition of the as-prepared nanoparticles were studied by powder X-ray diffraction (XRD), transmission electron microscopy (TEM), and scanning electron microscopy combined with energy-dispersive X-ray spectroscopy (SEM-EDX). The photocatalytic activity of the monoclinic and hexagonal WO3 nanoparticles was studied by decomposing methyl orange in aqueous solution under UV light irradiation. In order to study the electrochromic properties of the WO3 nanoparticles, as well to introduce them for self-cleaning photocatalytic surface applications, thin films were prepared from the WO3 particles together with a conductive polymer. For this, PEDOT:PSS was used, which gives excellent opportunities for obtaining transparent and conductive thin films, suitable for both electrochromic and photocatalytic applications. By spin-coating, transparent PEDOT:PSS/WO3 composite thin films were prepared, on which cyclic voltammetry measurements were performed, and the coloring and bleaching states were studied. Our initial results for the PEDOT:PSS/WO3 composite thin films are promising, suggesting that such composites, after further development, might be successfully used in electrochromic devices and photocatalysis.

  5. Athermal directions and their dispersion in KGd(WO4)2 and KLu(WO4)2 crystals

    NASA Astrophysics Data System (ADS)

    Filippov, V. V.

    2015-12-01

    An analysis of the existence of athermal properties for optically biaxial crystals KGd(WO4)2 and KLu(WO4)2 is performed and compared with that of KY(WO4)2 for monolithic and laser cavity configurations. Short-wavelength limits for athermal behavior in the principal planes of optical indicatrix are found. In KGd(WO4)2 they lie near or in the absorption band. In KLu(WO4)2, one of the two isonomal waves and both isonomal waves in the Np-Nm principal plane of KGd(WO4)2 for the laser cavity configuration have also long-wavelength limits. It is shown that for some wavelengths (one or two in the visible spectrum) and light wave polarization, the optical indicatrix axes can be athermal. In KLuW, for the monolithic configuration, the Np axis is athermal at three wavelengths, two of which lie in the IR region (0.843 and 1.975 μm). All-space athermal directions are determined for KLu(WO4)2 at 2 μm. For the monolithic configuration, they form a cone with its axis parallel to the Np axis and oval cross-section.

  6. Wakeshield WSF-02 GPS Experiment

    NASA Technical Reports Server (NTRS)

    Schutz, B. E.; Abusali, P. A. M.; Schroeder, Christine; Tapley, Byron; Exner, Michael; Mccloskey, rick; Carpenter, Russell; Cooke, Michael; Mcdonald, samantha; Combs, Nick; Duncan, Courtney; Dunn, Charles; Meehan, Tom

    1995-01-01

    Shuttle mission STS-69 was launched on September 7, 1995, 10:09 CDT, carrying the Wake Shield Facility (WSF-02). The WSF-02 spacecraft included a set of payloads provided by the Texas Space Grant Consortium, known as TexasSat. One of the TexasSat payloads was a GPS TurboRogue receiver loaned by the University Corporation for Atmospheric Research. On September 11, the WSF-02 was unberthed from the Endeavour payload bay using the remote manipulator system. The GPS receiver was powered on prior to release and the WSF-02 remained in free-flight for three days before being retrieved on September 14. All WSF-02 GPS data, which includes dual frequency pseudorange and carrier phase, were stored in an on-board recorder for post-flight analysis, but "snap- shots" of data were transmitted for 2-3 minutes at intervals of several hours, when permitted by the telemetry band- widdl The GPS experiment goals were: (1) an evaluation of precision orbit determination in a low altitude environment (400 km) where perturbations due to atmospheric drag and the Earth's gravity field are more pronounced than for higher altitude satellites with high precision orbit requirements, such as TOPEX/POSEIDON; (2) an assessment of relative positioning using the WSF GPS receiver and the Endeavour Collins receiver; and (3) determination of atmospheric temperature profiles using GPS signals passing through the atmosphere. Analysis of snap-shot telemetry data indicate that 24 hours of continuous data were stored on board, which includes high rate (50 Hz) data for atmosphere temperature profiles. Examination of the limited number of real-time navigation solutions show that at least 7 GPS satellites were tracked simultaneously and the on-board clock corrections were at the microsec level, as expected. Furthermore, a dynamical consistency test provided a further validation of the on-board navigation solutions. Complete analysis will be conducted in post-flight using the data recorded on-board.

  7. GPS/INS Sensor Fusion Using GPS Wind up Model

    NASA Technical Reports Server (NTRS)

    Williamson, Walton R. (Inventor)

    2013-01-01

    A method of stabilizing an inertial navigation system (INS), includes the steps of: receiving data from an inertial navigation system; and receiving a finite number of carrier phase observables using at least one GPS receiver from a plurality of GPS satellites; calculating a phase wind up correction; correcting at least one of the finite number of carrier phase observables using the phase wind up correction; and calculating a corrected IMU attitude or velocity or position using the corrected at least one of the finite number of carrier phase observables; and performing a step selected from the steps consisting of recording, reporting, or providing the corrected IMU attitude or velocity or position to another process that uses the corrected IMU attitude or velocity or position. A GPS stabilized inertial navigation system apparatus is also described.

  8. Precision GPS ephemerides and baselines

    NASA Technical Reports Server (NTRS)

    1992-01-01

    The required knowledge of the Global Positioning System (GPS) satellite position accuracy can vary depending on a particular application. Application to relative positioning of receiver locations on the ground to infer Earth's tectonic plate motion requires the most accurate knowledge of the GPS satellite orbits. Research directed towards improving and evaluating the accuracy of GPS satellite orbits was conducted at the University of Texas Center for Space Research (CSR). Understanding and modeling the forces acting on the satellites was a major focus of the research. Other aspects of orbit determination, such as the reference frame, time system, measurement modeling, and parameterization, were also investigated. Gravitational forces were modeled by truncated versions of extant gravity fields such as, Goddard Earth Model (GEM-L2), GEM-T1, TEG-2, and third body perturbations due to the Sun and Moon. Nongravitational forces considered were the solar radiation pressure, and perturbations due to thermal venting and thermal imbalance. At the GPS satellite orbit accuracy level required for crustal dynamic applications, models for the nongravitational perturbation play a critical role, since the gravitational forces are well understood and are modeled adequately for GPS satellite orbits.

  9. NH3 sensing characteristics of nano-WO3 thin films deposited on porous silicon.

    PubMed

    Sun, Fengyun; Hu, Ming; Sun, Peng; Zhang, Jie; Liu, Bo

    2010-11-01

    The NH3 sensing characteristics of nano-tungsten trioxide (WO3) thin films deposited on porous silicon (PS) were investigated in the present study. Porous silicon layer was first prepared by electrochemical etching in an HF-based solution on a p(+)-type silicon substrate. Then, WO3 nano-films were deposited on the porous silicon layer by DC magnetron sputtering. Pt electrodes were deposited on the top surface of the WO3 films to obtain the WO3/PS gas sensor. The WO3 films deposited on PS were characterized by SEM, XRD and XPS. The NH3 sensing characteristics for WO3/PS gas sensor were tested at room temperature and 50 degrees C. The results showed that the NH3 sensing characteristics of WO3/PS were superior to WO3/Al2O3 at room temperature. The sensing mechanism of the nano-WO3 thin films based on PS was also discussed. PMID:21138022

  10. GPS test range mission planning

    NASA Astrophysics Data System (ADS)

    Roberts, Iris P.; Hancock, Thomas P.

    The principal features of the Test Range User Mission Planner (TRUMP), a PC-resident tool designed to aid in deploying and utilizing GPS-based test range assets, are reviewed. TRUMP features time history plots of time-space-position information (TSPI); performance based on a dynamic GPS/inertial system simulation; time history plots of TSPI data link connectivity; digital terrain elevation data maps with user-defined cultural features; and two-dimensional coverage plots of ground-based test range assets. Some functions to be added during the next development phase are discussed.

  11. A simulation of GPS and differential GPS sensors

    NASA Technical Reports Server (NTRS)

    Rankin, James M.

    1993-01-01

    The Global Positioning System (GPS) is a revolutionary advance in navigation. Users can determine latitude, longitude, and altitude by receiving range information from at least four satellites. The statistical accuracy of the user's position is directly proportional to the statistical accuracy of the range measurement. Range errors are caused by clock errors, ephemeris errors, atmospheric delays, multipath errors, and receiver noise. Selective Availability, which the military uses to intentionally degrade accuracy for non-authorized users, is a major error source. The proportionality constant relating position errors to range errors is the Dilution of Precision (DOP) which is a function of the satellite geometry. Receivers separated by relatively short distances have the same satellite and atmospheric errors. Differential GPS (DGPS) removes these errors by transmitting pseudorange corrections from a fixed receiver to a mobile receiver. The corrected pseudorange at the moving receiver is now corrupted only by errors from the receiver clock, multipath, and measurement noise. This paper describes a software package that models position errors for various GPS and DGPS systems. The error model is used in the Real-Time Simulator and Cockpit Technology workstation simulations at NASA-LaRC. The GPS/DGPS sensor can simulate enroute navigation, instrument approaches, or on-airport navigation.

  12. Synthesis and photoelectrochemical properties of CdWO4 and CdS/CdWO4 nanostructures

    NASA Astrophysics Data System (ADS)

    Xu, Weina; Zheng, Chunhua; Hua, Hao; Yang, Qi; Chen, Lin; Xi, Yi; Hu, Chenguo

    2015-02-01

    A facile composite-salt-mediated strategy is employed for the first time to synthesize CdWO4 nanowire and nanoflower arrays on cadmium foil substrates. The photoelectrochemical (PEC) properties are measured on the electrodes made of the CdWO4 nanowire and nanoflower arrays under the simulated sunlight illumination. Both electrodes display high sensitive response and photocurrent stability. The photocurrent density of the nanowire arrays electrode reach 0.35 mA/cm2, which is about 3 times as much as that of the nanoflower array electrode. To improve the visible light photocurrent response, CdS nanoparticles are deposited on the CdWO4 nanowire arrays to form a CdS/CdWO4 heterojunction. Remarkably enhanced photoresponse is observed on the CdS/CdWO4 heterostructure and the photocurrent intensity is about twice as much as that of the electrode made of the pure CdWO4 nanowire arrays. The photoelectric mechanism is also discussed by the crystal structure and morphology characterization, optical band gap and carrier mobility analysis. This work presents a new design of a photoelectrochemical device for possible applications in photoelectrolysis of water and solar cells or highly sensitive light detection.

  13. Photocatalytic properties of h-WO3 nanoparticles obtained by annealing and h-WO3 nanorods prepared by hydrothermal method

    NASA Astrophysics Data System (ADS)

    Boyadjiev, Stefan I.; Nagy-Kovács, Teodóra; Lukács, István; Szilágyi, Imre M.

    2016-03-01

    In the present study, two different methods for preparing hexagonal WO3 (h-WO3) photocatalysts were used - controlled thermal decomposition and hydrothermal synthesis. WO3 nanoparticles with hexagonal structure were obtained by annealing (NH4)xWO3-y at 500 °C in air. WO3 nanorods were prepared by a hydrothermal method using sodium tungstate Na2WO4, HCl, (COOH)2 and NaSO4 precursors at 200 °C. The formation, morphology, structure and composition of the as-prepared nanoparticles and nanorods were studied by powder X-ray diffraction (XRD), transmission electron microscopy (TEM), and scanning electron microscopy combined with energy-dispersive X-ray spectroscopy (SEM-EDX). The photocatalytic activity of the h-WO3 nanoparticles and nanorods was studied by decomposing methyl orange in aqueous solution under UV light irradiation.

  14. Detection of VHF lightning from GPS orbit

    SciTech Connect

    Suszcynsky, D. M.

    2003-01-01

    Satellite-based VHF' lightning detection is characterized at GPS orbit by using a VHF receiver system recently launched on the GPS SVN 54 satellite. Collected lightning triggers consist of Narrow Bipolar Events (80%) and strong negative return strokes (20%). The results are used to evaluate the performance of a future GPS-satellite-based VHF global lightning monitor.

  15. Ground Truth Accuracy Tests of GPS Seismology

    NASA Astrophysics Data System (ADS)

    Elosegui, P.; Oberlander, D. J.; Davis, J. L.; Baena, R.; Ekstrom, G.

    2005-12-01

    As the precision of GPS determinations of site position continues to improve the detection of smaller and faster geophysical signals becomes possible. However, lack of independent measurements of these signals often precludes an assessment of the accuracy of such GPS position determinations. This may be particularly true for high-rate GPS applications. We have built an apparatus to assess the accuracy of GPS position determinations for high-rate applications, in particular the application known as "GPS seismology." The apparatus consists of a bidirectional, single-axis positioning table coupled to a digitally controlled stepping motor. The motor, in turn, is connected to a Field Programmable Gate Array (FPGA) chip that synchronously sequences through real historical earthquake profiles stored in Erasable Programmable Read Only Memory's (EPROM). A GPS antenna attached to this positioning table undergoes the simulated seismic motions of the Earth's surface while collecting high-rate GPS data. Analysis of the time-dependent position estimates can then be compared to the "ground truth," and the resultant GPS error spectrum can be measured. We have made extensive measurements with this system while inducing simulated seismic motions either in the horizontal plane or the vertical axis. A second stationary GPS antenna at a distance of several meters was simultaneously collecting high-rate (5 Hz) GPS data. We will present the calibration of this system, describe the GPS observations and data analysis, and assess the accuracy of GPS for high-rate geophysical applications and natural hazards mitigation.

  16. Shuttle Global Positioning (GPS) System design study

    NASA Technical Reports Server (NTRS)

    Nilsen, P.; Huth, G. K.

    1980-01-01

    Investigations of certain aspects and problems of the shuttle global positioning system GPS, are presented. Included are: test philosophy and test outline; development of a phase slope specification for the shuttle GPS antenna; an investigation of the shuttle jamming vulnerability; and an expression for the GPS signal to noise density ratio for the thermal protection system.

  17. Error modeling for GPS geodetic applications

    NASA Technical Reports Server (NTRS)

    Rim, Hyung Jin; Schutz, Bob E.; Tapley, Byron D.

    1993-01-01

    An extensive investigation was conducted to provide realistic error models for Global Positioning System (GPS) related numerical simulation. This study considers most of the important error sources for measurement and dynamic models which are currently being used for GPS geodetic applications. These error models were evaluated by comparing with real GPS data.

  18. Integrated navigation of aerial robot for GPS and GPS-denied environment

    NASA Astrophysics Data System (ADS)

    Suzuki, Satoshi; Min, Hongkyu; Wada, Tetsuya; Nonami, Kenzo

    2016-09-01

    In this study, novel robust navigation system for aerial robot in GPS and GPS- denied environments is proposed. Generally, the aerial robot uses position and velocity information from Global Positioning System (GPS) for guidance and control. However, GPS could not be used in several environments, for example, GPS has huge error near buildings and trees, indoor, and so on. In such GPS-denied environment, Laser Detection and Ranging (LIDER) sensor based navigation system have generally been used. However, LIDER sensor also has an weakness, and it could not be used in the open outdoor environment where GPS could be used. Therefore, it is desired to develop the integrated navigation system which is seamlessly applied to GPS and GPS-denied environments. In this paper, the integrated navigation system for aerial robot using GPS and LIDER is developed. The navigation system is designed based on Extended Kalman Filter, and the effectiveness of the developed system is verified by numerical simulation and experiment.

  19. Recent Activities in Spaceborne GPS

    NASA Technical Reports Server (NTRS)

    Yunck, T. P.

    1995-01-01

    After years of patient advocacy and paper studies by a diverse corps of enthusiasts, spaceborne GPS has at last become a presence in the world of flight projects. Owing to rapidly declining hardware costs, and the high value of autonomous onboard positioning, timing, and attitude determination, basic navigation receivers are coming to be seen as almost indispensable to future low earth orbiters.

  20. Recent GPS Results at SLAC

    SciTech Connect

    Behrend, Dirk; Imfeld, Hans L.; /SLAC

    2005-08-17

    The Alignment Engineering Group (AEG) makes use of GPS technology for fulfilling part of its above ground surveying tasks at SLAC since early 2002. A base station (SLAC M40) has been set up at a central location of the SLAC campus serving both as master station for real-time kinematic (RTK) operations and as datum point for local GPS campaigns. The Leica RS500 system is running continuously and the GPS data are collected both externally (logging PC) and internally (receiver flashcard). The external logging is facilitated by a serial to Ethernet converter and an Ethernet connection at the station. Internal logging (ring buffer) is done for data security purposes. The weatherproof boxes for the instrumentation are excellent shelters against rain and wind, but do heat up considerably in sun light. Whereas the GPS receiver showed no problems, the Pacific Crest PDL 35 radio shut down several times due to overheating disrupting the RTK operations. In order to prevent heat-induced shutdowns, a protection against direct sun exposure (shading) and a constant air circulation system (ventilation) were installed. As no further shutdowns have occurred so far, it appears that the two measures successfully mended the heat problem.

  1. Ekofisk automatic GPS subsidence measurements

    SciTech Connect

    Mes, M.J.; Landau, H.; Luttenberger, C.

    1996-10-01

    A fully automatic GPS satellite-based procedure for the reliable measurement of subsidence of several platforms in almost real time is described. Measurements are made continuously on platforms in the North Sea Ekofisk Field area. The procedure also yields rate measurements, which are also essential for confirming platform safety, planning of remedial work, and verification of subsidence models. GPS measurements are more attractive than seabed pressure-gauge-based platform subsidence measurements-they are much cheaper to install and maintain and not subject to gauge drift. GPS measurements were coupled to oceanographic quantities such as the platform deck clearance, which leads to less complex offshore survey procedures. Ekofisk is an oil and gas field in the southern portion of the Norwegian North Sea. Late in 1984, it was noticed that the Ekofisk platform decks were closer to the sea surface than when the platforms were installed-subsidence was the only logical explanation. After the subsidence phenomenon was recognized, an accurate measurement method was needed to measure progression of subsidence and the associated subsidence rate. One available system for which no further development was needed, was the NAVSTAR GPS-measurements started in March 1985.

  2. Animal Tracking ARGOS vs GPS

    NASA Astrophysics Data System (ADS)

    Robinson, P. W.; Costa, D.; Arnould, J.; Weise, M.; Kuhn, C.; Simmons, S. E.; Villegas, S.; Tremblay, Y.

    2006-12-01

    ARGOS satellite tracking technology has enabled a tremendous increase in our understanding of the movement patterns of a diverse array of marine vertebrates from Sharks to marine mammals. Our current understanding has moved from simple descriptions of large scale migratory patterns to much more sophisticated comparisons of animal movements and behavior relative to oceanic features. Further, animals are increasingly used to carry sensors that can acquire water column temperature and salinity profiles. However, a major limitation of this work is the spatial precision of ARGOS locations. ARGOS provides 7 location qualities that range from 3,2,1,0,A,B,Z and correspond to locations with a precision of 150m to tens of kilometers. Until recently, GPS technology could not be effectively used with marine mammals because they did not spend sufficient time at the surface to allow complete acquisition of satellite information. The recent development of Fastloc technology has allowed the development of GPS tags that can be deployed on marine mammals. Here we compare the location quality and frequency derived from standard ARGOS PTTs to Fastloc GPS locations acquired from 11 northern elephant seals, 5 California and 5 Galapagos sea lions and 1 Cape and 3 Australian fur seals. Our results indicate that GPS technology will greatly enhance our ability to understand the movement patterns of marine vertebrates and the in-situ oceanographic data they collect.

  3. Optimal Preprocessing Of GPS Data

    NASA Technical Reports Server (NTRS)

    Wu, Sien-Chong; Melbourne, William G.

    1994-01-01

    Improved technique for preprocessing data from Global Positioning System receiver reduces processing time and number of data to be stored. Optimal in sense that it maintains strength of data. Also increases ability to resolve ambiguities in numbers of cycles of received GPS carrier signals.

  4. The application of NAVSTAR Differential GPS to civil helicopter operations

    NASA Technical Reports Server (NTRS)

    Beser, J.; Parkinson, B. W.

    1981-01-01

    Principles concerning the operation of the NAVSTAR Global Positioning Systems (GPS) are discussed. Selective availability issues concerning NAVSTAR GPS and differential GPS concepts are analyzed. Civil support and market potential for differential GPS are outlined. It is concluded that differential GPS provides a variation on the baseline GPS system, and gives an assured, uninterrupted level of accuracy for the civilian community.

  5. Large single crystal growth of MnWO4-type materials from high-temperature solutions

    NASA Astrophysics Data System (ADS)

    Gattermann, U.; Röska, B.; Paulmann, C.; Park, S.-H.

    2016-11-01

    A simple high-temperature growth apparatus was constructed to obtain large crystals of chemically gradient (In, Na)-doped MnWO4solid-solutions. This paper presents the crystal growth and characterisation of both MnWO4and epitaxially grown (In, Na): MnWO4crystals on MnWO4. These large monolithic crystals were made in two steps: A MnWO4 crystal was grown in the crystallographic main direction [001] applying the Czochralski method, followed by the top seeded growth of (In, Na): MnWO4 solid-solutions with an oriented seed crystal of MnWO4. Such a monolithic crystal will serve to fundamental investigation of coupling properties at boundaries between various multiferroic MnWO4-typesolid-solutions.

  6. Altimetry Using GPS-Reflection/Occultation Interferometry

    NASA Technical Reports Server (NTRS)

    Cardellach, Estel; DeLaTorre, Manuel; Hajj, George A.; Ao, Chi

    2008-01-01

    A Global Positioning System (GPS)- reflection/occultation interferometry was examined as a means of altimetry of water and ice surfaces in polar regions. In GPS-reflection/occultation interferometry, a GPS receiver aboard a satellite in a low orbit around the Earth is used to determine the temporally varying carrier- phase delay between (1) one component of a signal from a GPS transmitter propagating directly through the atmosphere just as the GPS transmitter falls below the horizon and (2) another component of the same signal, propagating along a slightly different path, reflected at glancing incidence upon the water or ice surface.

  7. Spaceborne GPS: Current Status and Future Visions

    NASA Technical Reports Server (NTRS)

    Bauer, Frank H.; Hartman, Kate; Lightsey, E. Glenn

    1998-01-01

    The Global Positioning System (GPS), developed by the Department of Defense is quickly revolutionizing the architecture of future spacecraft and spacecraft systems. Significant savings in spacecraft life cycle cost, in power, and in mass can be realized by exploiting GPS technology in spaceborne vehicles. These savings are realized because GPS is a systems sensor--it combines the ability to sense space vehicle trajectory, attitude, time, and relative ranging between vehicles into one package. As a result, a reduced spacecraft sensor complement can be employed and significant reductions in space vehicle operations cost can be realized through enhanced on-board autonomy. This paper provides an overview of the current status of spaceborne GPS, a description of spaceborne GPS receivers available now and in the near future, a description of the 1997-2000 GPS flight experiments, and the spaceborne GPS team's vision for the future.

  8. Integrated Global Positioning Systems (GPS) Laboratory

    NASA Technical Reports Server (NTRS)

    Brown, Dewayne Randolph

    2002-01-01

    The purpose of this research is to develop a user-friendly Integrated GPS lab manual. This manual will help range engineers at NASA to integrate the use of GPS Simulators, GPS receivers, computers, MATLAB software, FUGAWI software and SATELLITE TOOL KIT software. The lab manual will be used in an effort to help NASA engineers predict GPS Coverage of planned operations and analyze GPS coverage of operation post mission. The Integrated GPS Laboratory was used to do GPS Coverage for two extensive case studies. The first scenario was an airplane trajectory in which an aircraft flew from Cape Canaveral to Los Angeles, California. In the second scenario, a rocket trajectory was done whereas a rocket was launched from Cape Canaveral to one thousand kilometers due east in the Atlantic Ocean.

  9. Spaceborne GPS Current Status and Future Visions

    NASA Technical Reports Server (NTRS)

    Bauer, Frank H.; Hartman, Kate; Lightsey, E. Glenn

    1998-01-01

    The Global Positioning System (GPS), developed by the Department of Defense, is quickly revolutionizing the architecture of future spacecraft and spacecraft systems. Significant savings in spacecraft life cycle cost, in power, and in mass can be realized by exploiting Global Positioning System (GPS) technology in spaceborne vehicles. These savings are realized because GPS is a systems sensor-it combines the ability to sense space vehicle trajectory, attitude, time, and relative ranging between vehicles into one package. As a result, a reduced spacecraft sensor complement can be employed on spacecraft and significant reductions in space vehicle operations cost can be realized through enhanced on- board autonomy. This paper provides an overview of the current status of spaceborne GPS, a description of spaceborne GPS receivers available now and in the near future, a description of the 1997-1999 GPS flight experiments and the spaceborne GPS team's vision for the future.

  10. International GPS Service for Geodynamics

    NASA Technical Reports Server (NTRS)

    Zumberge, J. F. (Editor); Urban, M. P. (Editor); Liu, R. (Editor); Neilan, R. E. (Editor)

    1996-01-01

    This 1995 annual report of the IGS International GPS (Global Positioning System) Service for Geodynamics - describes the second operational year of the service. It provides the many IGS contributing agencies and the rapidly growing user community with essential information on current organizational and technical matters promoting the IGS standards and products (including organizational framework, data processing strategies, and statistics showing the remarkable expansion of the GPS monitoring network, the improvement of IGS performance, and product quality). It also introduces important practical concepts for network densification by integration of regional stations and the combination of station coordinate solutions. There are groups of articles describing general aspects of the IGS, the Associate Analysis Centers (AACs), Data Centers, and IGS stations.

  11. Pre-Flight Testing of Spaceborne GPS Receivers Using a GPS Constellation Simulator

    NASA Technical Reports Server (NTRS)

    Kizhner, Semion; Davis, Edward; Alonso, Roberto

    1999-01-01

    The NASA Goddard Space Flight Center (GSFC) Global Positioning System (GPS) applications test facility has been established within the GSFC Guidance Navigation and Control Center. The GPS test facility is currently housing the Global Simulation Systems Inc. (GSSI) STR2760 GPS satellite 40-channel attitude simulator and a STR4760 12-channel navigation simulator. The facility also contains a few other resources such as an atomic time standard test bed, a rooftop antenna platform and a radome. It provides a new capability for high dynamics GPS simulations of space flight that is unique within the aerospace community. The GPS facility provides a critical element for the development and testing of GPS based technologies i.e. position, attitude and precise time determination used on-board a spacecraft, suborbital rocket or balloon. The GPS simulator system is configured in a transportable rack and is available for GPS component development as well as for component, spacecraft subsystem and system level testing at spacecraft integration and test sites. The GPS facility has been operational since early 1996 and has been utilized by space flight projects carrying GPS experiments, such as the OrbView-2 and the Argentine SAC-A spacecrafts. The SAC-A pre-flight test data obtained by using the STR2760 simulator and the comparison with preliminary analysis of the GPS data from SAC-A telemetry are summarized. This paper describes pre-flight tests and simulations used to support a unique spaceborne GPS experiment. The GPS experiment mission objectives and the test program are described, as well as the GPS test facility configuration needed to verify experiment feasibility. Some operational and critical issues inherent in GPS receiver pre-flight tests and simulations using this GPS simulator, and test methodology are described. Simulation and flight data are presented. A complete program of pre-flight testing of spaceborne GPS receivers using a GPS constellation simulator is

  12. Pre-Flight Testing of Spaceborne GPS Receivers using a GPS Constellation Simulator

    NASA Technical Reports Server (NTRS)

    Kizhner, Semion; Davis, Edward; Alonso, R.

    1999-01-01

    The NASA Goddard Space Flight Center (GSFC) Global Positioning System (GPS) applications test facility has been established within the GSFC Guidance Navigation and Control Center. The GPS test facility is currently housing the Global Simulation Systems Inc. (GSSI) STR2760 GPS satellite 40-channel attitude simulator and a STR4760 12-channel navigation simulator. The facility also contains a few other resources such as an atomic time standard test bed, a rooftop antenna platform and a radome. It provides a new capability for high dynamics GPS simulations of space flight that is unique within the aerospace community. The GPS facility provides a critical element for the development and testing of GPS based technologies i.e. position, attitude and precise time determination used on-board a spacecraft, suborbital rocket balloon. The GPS simulation system is configured in a transportable rack and is available for GPS component development as well as for component, spacecraft subsystem and system level testing at spacecraft integration and tests sites. The GPS facility has been operational since early 1996 and has utilized by space flight projects carrying GPS experiments, such as the OrbView-2 and the Argentine SAC-A spacecrafts. The SAC-A pre-flight test data obtained by using the STR2760 simulator and the comparison with preliminary analysis of the GPS data from SAC-A telemetry are summarized. This paper describes pre-flight tests and simulations used to support a unique spaceborne GPS experiment. The GPS experiment mission objectives and the test program are described, as well as the GPS test facility configuration needed to verify experiment feasibility. Some operational and critical issues inherent in GPS receiver pre-flight tests and simulations using this GPS simulation, and test methodology are described. Simulation and flight data are presented. A complete program of pre-flight testing of spaceborne GPS receivers using a GPS constellation simulator is detailed.

  13. GPS Multipath in Urban Environments

    NASA Astrophysics Data System (ADS)

    Bilich, A.; Sella, G.

    2008-12-01

    Multipath, where a GNSS signal arrives by more than one path, is considered one of the last unmodeled errors remaining in GNSS. Multipath is of great concern because the additional path length traveled by the incoming signal biases the satellite-receiver range and therefore determination of position. Siting a GNSS station in an urban area, in the immediate vicinity of large reflecting objects such as rooftops, buildings, asphalt and concrete parking lots, grassy fields, and chainlink fences, is both a multipath nightmare and a necessary evil. We note that continuously-operating GNSS stations are becoming increasingly common in urban areas, which makes sense as these stations are often installed in support of civil infrastructure (e.g. departments of transportation, strong motion monitoring of buildings in earthquake-prone areas, surveying networks). Urban stations are well represented in geodetic networks such as the CORS (United States) and GeoNet (Japan) networks, with more stations likely to be installed in the coming years. What sources and types of urban multipath are the most detrimental to geodetic GPS positioning? Which reflecting objects are assumed to be a major source of multipath error, but the GPS data show otherwise? Are certain reflecting environments worse for specific applications, i.e. kinematic vs. static positioning? If forced to install a GNSS station in a highly reflective environment, is it possible to rank objects for their multipath severity? To answer these questions, we provide multipath examples taken from continuously- operating GNSS stations sited in urban environments. We concentrate on some of the most common obstacles and reflecting objects for urban sites - rooftops, parking lots, and fences. We analyze the multipath signature of these objects as manifested in the GPS phase, pseudorange, and signal-to-noise ratio (SNR) observables, and also examine multipath impacts on the precision and accuracy of GPS-derived positions.

  14. Precision GPS ephemerides and baselines

    NASA Technical Reports Server (NTRS)

    1991-01-01

    Based on the research, the area of precise ephemerides for GPS satellites, the following observations can be made pertaining to the status and future work needed regarding orbit accuracy. There are several aspects which need to be addressed in discussing determination of precise orbits, such as force models, kinematic models, measurement models, data reduction/estimation methods, etc. Although each one of these aspects was studied at CSR in research efforts, only points pertaining to the force modeling aspect are addressed.

  15. Ionospheric Scintillation Effects on GPS

    NASA Astrophysics Data System (ADS)

    Steenburgh, R. A.; Smithtro, C.; Groves, K.

    2007-12-01

    . Ionospheric scintillation of Global Positioning System (GPS) signals threatens navigation and military operations by degrading performance or making GPS unavailable. Scintillation is particularly active, although not limited to, a belt encircling the earth within 20 degrees of the geomagnetic equator. As GPS applications and users increases, so does the potential for detrimental impacts from scintillation. We examined amplitude scintillation data spanning seven years from Ascension Island, U.K.; Ancon, Peru; and Antofagasta, Chile in the Atlantic/Americas longitudinal sector at as well as data from Parepare, Indonesia; Marak Parak, Malaysia; Pontianak, Indonesia; Guam; and Diego Garcia, U.K.; in the Pacific longitudinal sector. From these data, we calculate percent probability of occurrence of scintillation at various intensities described by the S4 index. Additionally, we determine Dilution of Precision at one minute resolution. We examine diurnal, seasonal and solar cycle characteristics and make spatial comparisons. In general, activity was greatest during the equinoxes and solar maximum, although scintillation at Antofagasta, Chile was higher during 1998 rather than at solar maximum.

  16. Applications of GPS technologies to field sports.

    PubMed

    Aughey, Robert J

    2011-09-01

    Global positioning system (GPS) technology was made possible after the invention of the atomic clock. The first suggestion that GPS could be used to assess the physical activity of humans followed some 40 y later. There was a rapid uptake of GPS technology, with the literature concentrating on validation studies and the measurement of steady-state movement. The first attempts were made to validate GPS for field sport applications in 2006. While GPS has been validated for applications for team sports, some doubts continue to exist on the appropriateness of GPS for measuring short high-velocity movements. Thus, GPS has been applied extensively in Australian football, cricket, hockey, rugby union and league, and soccer. There is extensive information on the activity profile of athletes from field sports in the literature stemming from GPS, and this includes total distance covered by players and distance in velocity bands. Global positioning systems have also been applied to detect fatigue in matches, identify periods of most intense play, different activity profiles by position, competition level, and sport. More recent research has integrated GPS data with the physical capacity or fitness test score of athletes, game-specific tasks, or tactical or strategic information. The future of GPS analysis will involve further miniaturization of devices, longer battery life, and integration of other inertial sensor data to more effectively quantify the effort of athletes.

  17. Pulsed laser deposition of CdWO4 thin films

    NASA Astrophysics Data System (ADS)

    Kodu, M.; Avarmaa, T.; Jaaniso, R.; Leemets, K.; Mändar, H.; Nagirnyi, V.

    2016-10-01

    Thin CdWO4 films were produced on various substrates by pulsed laser deposition. A method of producing transparent films of high structural and optical quality on MgO substrate was developed. It is based on deposition of an amorphous film from a non-stoichiometric CdWO4-CdO target and a consequent crystallization of the film in oxygen atmosphere at 750 °C. The quality of the films produced was verified by x-ray diffraction, electron probe microanalysis, scanning electron microscopy, Raman and optical spectroscopy.

  18. Photocatalytic water treatment over WO 3 under visible light irradiation combined with ozonation

    NASA Astrophysics Data System (ADS)

    Nishimoto, Shunsuke; Mano, Takayuki; Kameshima, Yoshikazu; Miyake, Michihiro

    2010-11-01

    Photocatalytic water treatment over bare WO 3 under visible light irradiation combined with ozonation (O 3/vis/WO 3) was investigated using an aqueous phenol solution as model wastewater. The O 3/vis/WO 3 treatment exhibited a much higher total organic carbon removal than ozonation alone. Bare WO 3 was found to function as an active visible-light-responsive photocatalyst for decomposition of organic compounds in the presence of ozone, which readily reacts with photoexcited electrons in the conduction band of WO 3.

  19. The WO3/WS2 nanostructures: Preparation, characterization and optical absorption properties

    NASA Astrophysics Data System (ADS)

    Cao, Shixiu; Zhao, Cong; Han, Tao; Peng, Lingling

    2016-07-01

    The WO3/WS2 nanostructures were successfully prepared using a two-step hydrothermal/gas phase method. The physical properties of the nanostructures were characterized using XRD, SEM, TEM, UV-visible spectroscopy. The WO3/WS2 nanostructures obtained were coexistence of WO3 and WS2 in the same particle. The WO3/WS2 nanostructures contained a wide and intensive absorption in the UV-visible light region of 245-750 nm, which showed that the WO3/WS2 nanostructures may have a potential application as an UV-visible photocatalyst.

  20. Reactive Sputter Deposition of WO3/Ag/WO3 Film for Indium Tin Oxide (ITO)-Free Electrochromic Devices.

    PubMed

    Yin, Yi; Lan, Changyong; Guo, Huayang; Li, Chun

    2016-02-17

    Functioning both as electrochromic (EC) and transparent-conductive (TC) coatings, WO3/Ag/WO3 (WAW) trilayer film shows promising potential application for ITO-free electrochromic devices. Reports on thermal-evaporated WAW films revealed that these bifunctional WAW films have distinct EC characteristics; however, their poor adhesive property leads to rapid degradation of coloring-bleaching cycling. Here, we show that WAW film with improved EC durability can be prepared by reactive sputtering using metal targets. We find that, by introducing an ultrathin tungsten (W) sacrificial layer before the deposition of external WO3, the oxidation of silver, which leads to film insulation and apparent optical haze, can be effectively avoided. We also find that the luminous transmittance and sheet resistance were sensitive to the thicknesses of tungsten and silver layers. The optimized structure for TC coating was obtained to be WO3 (45 nm)/Ag (10 nm)/W (2 nm)/WO3 (45 nm) with a sheet resistance of 16.3 Ω/□ and a luminous transmittance of 73.7%. Such film exhibits compelling EC performance with decent luminous transmittance modulation ΔTlum of 29.5%, fast switching time (6.6 s for coloring and 15.9 s for bleaching time), and long-term cycling stability (2000 cycles) with an applied potential of ±1.2 V. Thicker external WO3 layer (45/10/2/100 nm) leads to larger modulation with maximum ΔTlum of 46.4%, but at the cost of significantly increasing the sheet resistance. The strategy of introducing ultrathin metal sacrificial layer to avoid silver oxidation could be extended to fabricating other oxide-Ag-oxide transparent electrodes via low-cost reactive sputtering. PMID:26726834

  1. Multiple Horizontal Transfers of Bacteriophage WO and Host Wolbachia in Fig Wasps in a Closed Community.

    PubMed

    Wang, Ningxin; Jia, Sisi; Xu, Heng; Liu, Yong; Huang, Dawei

    2016-01-01

    Wolbachia-bacteriophage WO is a good model system for studying interactions between bacteria and viruses. Previous surveys of insect hosts have been conducted via sampling from open or semi-open communities; however, no studies have reported the infection patterns of phage WO of insects living in a closed community. Figs and fig wasps form a peculiar closed community in which the Ficus tree provides a compact syconium habitat for a variety of fig wasp. Therefore, in this study, we performed a thorough survey of Wolbachia and bacteriophage WO infection patterns in a total of 1406 individuals from 23 fig wasps species living on three different fig tree species. The infection rates of Wolbachia and phage WO were 82.6% (19/23) and 39.1% (9/23), respectively. Additionally, phage WO from fig wasps showed strong insect host specificity based on orf7 sequences from fig wasps and 21 other insect species. Probably due to the physical barrier of fig syconium, most phage WO from fig wasps form a specific clade. Phylogenetic analysis showed the absence of congruence between WO and host Wolbachia, WO and insect host, as well as Wolbachia and fig wasps, suggesting that both Wolbachia and phage WO exchanged frequently and independently within the closed syconium. Thus, the infection pattern of bacteriophage WO from fig wasps appeared quite different from that in other insects living outside, although the effect and the transfer routes of phage WO are unclear, which need to be investigated in the future.

  2. Multiple Horizontal Transfers of Bacteriophage WO and Host Wolbachia in Fig Wasps in a Closed Community

    PubMed Central

    Wang, Ningxin; Jia, Sisi; Xu, Heng; Liu, Yong; Huang, Dawei

    2016-01-01

    Wolbachia-bacteriophage WO is a good model system for studying interactions between bacteria and viruses. Previous surveys of insect hosts have been conducted via sampling from open or semi-open communities; however, no studies have reported the infection patterns of phage WO of insects living in a closed community. Figs and fig wasps form a peculiar closed community in which the Ficus tree provides a compact syconium habitat for a variety of fig wasp. Therefore, in this study, we performed a thorough survey of Wolbachia and bacteriophage WO infection patterns in a total of 1406 individuals from 23 fig wasps species living on three different fig tree species. The infection rates of Wolbachia and phage WO were 82.6% (19/23) and 39.1% (9/23), respectively. Additionally, phage WO from fig wasps showed strong insect host specificity based on orf7 sequences from fig wasps and 21 other insect species. Probably due to the physical barrier of fig syconium, most phage WO from fig wasps form a specific clade. Phylogenetic analysis showed the absence of congruence between WO and host Wolbachia, WO and insect host, as well as Wolbachia and fig wasps, suggesting that both Wolbachia and phage WO exchanged frequently and independently within the closed syconium. Thus, the infection pattern of bacteriophage WO from fig wasps appeared quite different from that in other insects living outside, although the effect and the transfer routes of phage WO are unclear, which need to be investigated in the future. PMID:26913026

  3. Tripartite associations among bacteriophage WO, Wolbachia, and host affected by temperature and age in Tetranychus urticae.

    PubMed

    Lu, Ming-Hong; Zhang, Kai-Jun; Hong, Xiao-Yue

    2012-11-01

    A phage density model of cytoplasmic incompatibility (CI), which means lytic phages reduce bacterial density associated with CI, significantly enhances our understanding of the tripartite associations among bacteriophage WO, Wolbachia and host. However, WO may alternate between lytic and lysogenic life cycles or change phage production under certain conditions including temperature, host age and host species background. Here, extreme temperatures can induce an alteration in the life cycle of WO and change the tripartite associations among WO, Wolbachia and CI. Based on the accumulation of the WO load, WO can transform into the lytic life cycle with increasing age. These findings confirmed that the environment plays an important role in the associations among WO, Wolbachia and host. PMID:22669278

  4. Tripartite associations among bacteriophage WO, Wolbachia, and host affected by temperature and age in Tetranychus urticae.

    PubMed

    Lu, Ming-Hong; Zhang, Kai-Jun; Hong, Xiao-Yue

    2012-11-01

    A phage density model of cytoplasmic incompatibility (CI), which means lytic phages reduce bacterial density associated with CI, significantly enhances our understanding of the tripartite associations among bacteriophage WO, Wolbachia and host. However, WO may alternate between lytic and lysogenic life cycles or change phage production under certain conditions including temperature, host age and host species background. Here, extreme temperatures can induce an alteration in the life cycle of WO and change the tripartite associations among WO, Wolbachia and CI. Based on the accumulation of the WO load, WO can transform into the lytic life cycle with increasing age. These findings confirmed that the environment plays an important role in the associations among WO, Wolbachia and host.

  5. Tungsten Trioxide (WO3) Nanoparticles as a New Anode Material for Sodium-Ion Batteries.

    PubMed

    Santhosha, A L; Das, Shyamal K; Bhattacharyya, Aninda J

    2016-04-01

    Tungsten trioxide (WO3) is investigated for the first time as an anode material for sodium-ion batteries. Pristine WO3 displays a discharge potential plateau at 1 V and exhibits a 1st discharge cycle sodium storage capacity of 640 mAh g-1. Electronic wiring of WO3 with graphene oxide (GO, 1% by weight) led to a significant increase in the storage capacity and cyclability of WO3. As a result, the discharge capacity of 1% GO-WO3 is enhanced to 927 mAh g-1 in the 1st discharge cycle. The electrochemical intercalation of Na in to WO3 and (1%) GO-WO3 as obtained from galvanostatic charge/discharge cycling is also supported by cyclic voltammetry. PMID:27451776

  6. Micro/nano-structured CaWO4/Bi2WO6 composite: synthesis, characterization and photocatalytic properties for degradation of organic contaminants.

    PubMed

    Guo, Yadan; Zhang, Gaoke; Gan, Huihui; Zhang, Yalei

    2012-11-01

    The micro/nano-structured CaWO(4)/Bi(2)WO(6) composite was successfully synthesized by a one-step hydrothermal route without using any templates or surfactants. The as-prepared samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), UV-vis diffuse reflectance spectroscopy (UV-vis DRS), Fourier transform infrared (FT-IR) spectroscopy, thermogravimetry-differential scanning calorimetry (TG-DSC) and Brunauer-Emmet-Teller (BET) theory. The results indicated that the composite has a two-phase composition: CaWO(4) and Bi(2)WO(6). The photocatalytic activities of the CaWO(4)/Bi(2)WO(6) composite were evaluated for the degradation of Rhodamine B (RhB) dye and 4-nitrophenol (4-NP) in aqueous solution under visible-light irradiation (>420 nm), which were 4.5 times and 2.5 times higher than that of the pure Bi(2)WO(6), respectively. On the basis of the calculated energy band positions, the mechanism of enhanced photocatalytic activity for the micro/nano-structured CaWO(4)/Bi(2)WO(6) composite can be attributed to the effective separation of electron-hole pairs.

  7. Miniaturized GPS/MEMS IMU integrated board

    NASA Technical Reports Server (NTRS)

    Lin, Ching-Fang (Inventor)

    2012-01-01

    This invention documents the efforts on the research and development of a miniaturized GPS/MEMS IMU integrated navigation system. A miniaturized GPS/MEMS IMU integrated navigation system is presented; Laser Dynamic Range Imager (LDRI) based alignment algorithm for space applications is discussed. Two navigation cameras are also included to measure the range and range rate which can be integrated into the GPS/MEMS IMU system to enhance the navigation solution.

  8. The GPS Laser Retroreflector Array Project

    NASA Technical Reports Server (NTRS)

    Merkowitz, Stephen M.

    2012-01-01

    Systematic co-location in space through the precision orbit determination of GPS satellites via satellite laser ranging will contribute significantly towards improving the accuracy and stability of the international terrestrial reference frame. NASA recently formed the GPS Laser Retroreflector Array Project to develop and deliver retroreflectors for integration on the next generation of GPS satellites. These retroreflectors will be an important contributor to achieving a global accuracy of 1.0 mm and 0.1 mm/year stability in the international terrestrial reference frame. We report here the current status of the GPS Laser Retroreflector Array Project.

  9. GPS data exploration for seismologists and geodesists

    NASA Astrophysics Data System (ADS)

    Webb, F.; Bock, Y.; Kedar, S.; Dong, D.; Jamason, P.; Chang, R.; Prawirodirdjo, L.; MacLeod, I.; Wadsworth, G.

    2007-12-01

    Over the past decade, GPS and seismic networks spanning the western US plate boundaries have produced vast amounts of data that need to be made accessible to both the geodesy and seismology communities. Unlike seismic data, raw geodetic data requires significant processing before geophysical interpretations can be made. This requires the generation of data-products (time series, velocities and strain maps) and dissemination strategies to bridge these differences and assure efficient use of data across traditionally separate communities. "GPS DATA PRODUCTS FOR SOLID EARTH SCIENCE" (GDPSES) is a multi-year NASA funded project, designed to produce and deliver high quality GPS time series, velocities, and strain fields, derived from multiple GPS networks along the western US plate boundary, and to make these products easily accessible to geophysicists. Our GPS product dissemination is through modern web-based IT methodology. Product browsing is facilitated through a web tool known as GPS Explorer and continuous streams of GPS time series are provided using web services to the seismic archive, where it can be accessed by seismologists using traditional seismic data viewing and manipulation tools. GPS-Explorer enables users to efficiently browse several layers of data products from raw data through time series, velocities and strain by providing the user with a web interface, which seamlessly interacts with a continuously updated database of these data products through the use of web-services. The current archive contains GDPSES data products beginning in 1995, and includes observations from GPS stations in EarthScope's Plate Boundary Observatory (PBO), as well as from real-time real-time CGPS stations. The generic, standards-based approach used in this project enables GDPSES to seamlessly expand indefinitely to include other space-time-dependent data products from additional GPS networks. The prototype GPS-Explorer provides users with a personalized working environment

  10. Determination of GPS orbits to submeter accuracy

    NASA Technical Reports Server (NTRS)

    Bertiger, W. I.; Lichten, S. M.; Katsigris, E. C.

    1988-01-01

    Orbits for satellites of the Global Positioning System (GPS) were determined with submeter accuracy. Tests used to assess orbital accuracy include orbit comparisons from independent data sets, orbit prediction, ground baseline determination, and formal errors. One satellite tracked 8 hours each day shows rms error below 1 m even when predicted more than 3 days outside of a 1-week data arc. Differential tracking of the GPS satellites in high Earth orbit provides a powerful relative positioning capability, even when a relatively small continental U.S. fiducial tracking network is used with less than one-third of the full GPS constellation. To demonstrate this capability, baselines of up to 2000 km in North America were also determined with the GPS orbits. The 2000 km baselines show rms daily repeatability of 0.3 to 2 parts in 10 to the 8th power and agree with very long base interferometry (VLBI) solutions at the level of 1.5 parts in 10 to the 8th power. This GPS demonstration provides an opportunity to test different techniques for high-accuracy orbit determination for high Earth orbiters. The best GPS orbit strategies included data arcs of at least 1 week, process noise models for tropospheric fluctuations, estimation of GPS solar pressure coefficients, and combine processing of GPS carrier phase and pseudorange data. For data arc of 2 weeks, constrained process noise models for GPS dynamic parameters significantly improved the situation.

  11. Requirements for Navstar GPS and construction of the German GPS information and observation system GIBS

    NASA Astrophysics Data System (ADS)

    Lechner, Wolfgang

    The commission 'Application of Orientation and Navigation in Land Traffic' set up the working group called GIBS (Civil German GPS Information and Observation System for Use in Earth Science and Navigation). The work performed by GIBS to elucidate the requirements for Navstar GPS and a GPS information service are discussed.

  12. The Te-ni-wo-ha: An Etymological Study.

    ERIC Educational Resources Information Center

    Jolly, Yukiko S.

    1972-01-01

    The designation of the Japanese word class "joshi" (in English known as particles, post-positional case markers, or relationals) by the term te-ni-wo-ha can be traced to the early superimposition of the Chinese writing system on Japanese speech. Because of the structural differences between the two languages and the existence of elements in…

  13. Chip Advancer For GPS Receiver

    NASA Technical Reports Server (NTRS)

    Meehan, Thomas K.; Srinivasan, Jeffrey M.; Thomas, J. Brooks

    1989-01-01

    Instrument errors made negligible. For each integration interval, both delay and rate of change of delay initialized to small fraction of chip - for example, to order of 10 to the negative 7th power - thereby making feedback control and extraction of delay highly accurate and flexible. With appropriate selection of sampling rate relative to chip rate, commensurability errors reduced to extremely small levels. In Global Positioning System (GPS) receiver, pseudorandom code sequence generated by simple digital logic incorporating effects of time, delay, and rate of change of delay. Flexibility in starting time and sum interval very useful in aligning correlation interval with beginnings and endings of data bits.

  14. Tungsten-based nanomaterials (WO3 & Bi2WO6): Modifications related to charge carrier transfer mechanisms and photocatalytic applications

    NASA Astrophysics Data System (ADS)

    Girish Kumar, S.; Koteswara Rao, K. S. R.

    2015-11-01

    Heterogeneous photocatalysis is an ideal green energy technology for the purification of wastewater. Although titania dominates as the reference photocatalyst, its wide band gap is a bottleneck for extended utility. Thus, search for non-TiO2 based nanomaterials has become an active area of research in recent years. In this regard, visible light absorbing polycrystalline WO3 (2.4-2.8 eV) and Bi2WO6 (2.8 eV) with versatile structure-electronic properties has gained considerable interest to promote the photocatalytic reactions. These materials are also explored in selective functional group transformation in organic reactions, because of low reduction and oxidation potential of WO3 CB and Bi2WO6 VB, respectively. In this focused review, various strategies such as foreign ion doping, noble metal deposition and heterostructuring with other semiconductors designed for efficient photocatalysis is discussed. These modifications not only extend the optical response to longer wavelengths, but also prolong the life-time of the charge carriers and strengthen the photocatalyst stability. The changes in the surface-bulk properties and the charge carrier transfer dynamics associated with each modification correlating to the high activity are emphasized. The presence of oxidizing agents, surface modification with Cu2+ ions and synthesis of exposed facets to promote the degradation rate is highlighted. In depth study on these nanomaterials is likely to sustain interest in wastewater remediation and envisaged to signify in various green energy applications.

  15. WO{sub 3} nanoplates, hierarchical flower-like assemblies and their photocatalytic properties

    SciTech Connect

    Huang, Jianhua Xiao, Liang; Yang, Xiaolong

    2013-08-01

    Graphical abstract: WO{sub 3} nanoplates, hierarchical flower-like assemblies and their visible light-driven photocatalytic properties for degradation of rhodamine B. - Highlights: • Preparation of monoclinic WO{sub 3} by a hydrothermal reaction of PbWO{sub 4} in the presence of HNO{sub 3}. • Single-crystalline WO{sub 3} nanoplates were formed when 4 M HNO{sub 3} solution was used. • WO{sub 3} flowers were assembled by nanoplates when 15 M HNO{sub 3} solution was used. • The products showed excellent visible light-driven photodegradation of rhodamine B. - Abstract: Monoclinic WO{sub 3} was prepared by a hydrothermal reaction of PbWO{sub 4} in the presence of HNO{sub 3}. WO{sub 3} rectangular nanoplates with a side length of 50–150 nm and a thickness of about 25 nm were obtained at 4 M HNO{sub 3} solution. And the single crystal nature was confirmed by the selected area electron diffraction. Whereas WO{sub 3} hierarchical flower-like assemblies with 3–5 μm in diameter were self-organized by nanoplates in the presence of 15 M HNO{sub 3} solution. Compared with commercial WO{sub 3} particles, our products showed an enhancement of photocatalytic properties for the degradation of rhodamine B under visible light irradiation.

  16. Synthesis of surface sulfated BiWO with enhanced photocatalytic performance.

    PubMed

    Ju, Yongming; Hong, Jianming; Zhang, Xiuyu; Xu, Zhencheng; Wei, Dongyang; Sang, Yanhong; Fang, Xiaohang; Fang, Jiande; Wang, Zhenxing

    2012-01-01

    Sulfated BiWO (SBiWO) was synthesized by an impregnation method to enhance the visible-light-driven photoactivities of BiWO (BiWO). The characterization results verified that sulfate anion mainly anchored on the catalyst surface greatly extended the visible-light-responsive range without destroying the crystal lattice. Moreover, the SBiWO-based photoactivities were evaluated with the removal of Malachite Green (MG) under UV-Vis irradiation emitted from two microwave-powered electrodeless discharge lamps (MPEDL2) and under visible light (lamda > 420 nm). The results demonstrated that the kinetic constant was increased 2.25 times, varying from 0.1478 (BiWO) to 0.3328 min(-1) (SBiWO-1). Similar results were also obtained for the visible light-driven reaction. Furthermore, radical scavengers such as t-butanol restricted the visible-light induced degradation of MG over BiWO and SBiWO-1. This indicated that the sulfating process increased the generation of reactive oxygen species, which was further verified by molecular probe with salicylic acid. Thus, more blue-shifting at lam = 618 nm was observed over SBiWO. On the basis of the above results, the photocatalytic mechanism over the sulfated catalyst was also discussed. PMID:23534216

  17. Ideas for Future GPS Timing Improvements

    NASA Technical Reports Server (NTRS)

    Hutsell, Steven T.

    1996-01-01

    Having recently met stringent criteria for full operational capability (FOC) certification, the Global Positioning System (GPS) now has higher customer expectations than ever before. In order to maintain customer satisfaction, and the meet the even high customer demands of the future, the GPS Master Control Station (MCS) must play a critical role in the process of carefully refining the performance and integrity of the GPS constellation, particularly in the area of timing. This paper will present an operational perspective on several ideas for improving timing in GPS. These ideas include the desire for improving MCS - US Naval Observatory (USNO) data connectivity, an improved GPS-Coordinated Universal Time (UTC) prediction algorithm, a more robust Kalman Filter, and more features in the GPS reference time algorithm (the GPS composite clock), including frequency step resolution, a more explicit use of the basic time scale equation, and dynamic clock weighting. Current MCS software meets the exceptional challenge of managing an extremely complex constellation of 24 navigation satellites. The GPS community will, however, always seek to improve upon this performance and integrity.

  18. Vulnerability/survivability of the GPS system

    NASA Astrophysics Data System (ADS)

    Burgess, Alan

    This paper considers some of the features that contribute to the military survivability of GPS in times of crisis. It discusses each segment in turn and addresses the potential threats and the counter measures applicable thus enabling GPS to provide a continuing service. The design aspects primarily protect military applications, but the benefits apply equally to the civil community.

  19. Spaceborne GPS remote sensing for atmospheric research

    NASA Astrophysics Data System (ADS)

    Feng, Dasheng; Herman, Benjamin M.; Exner, M. L.; Schreiner, B.; Anthes, Richard A.; Ware, Randolph H.

    1995-11-01

    The global positioning system (GPS) is based on a constellation of 24 transmitter satellites orbiting the earth at approximately 21,000 km altitude. The original goal of the GPS was to provide global and all-weather precision positioning and navigation for the military. Since this original concept was developed, several civilian applications have been conceived that are making use of these satellites. GPS/MET is one such application. GPS/MET is sponsored by NSF, FAA, NOAA, and NASA. The goal of GPS/MET is to demonstrate the feasibility of recovering atmospheric temperature profiles from occulting radio signals from one of the 24 GPS transmitters. On April 3, 1995, a small radio receiver was launched into a 750 km low- earth orbit and 70 degree inclination. As this receiver orbits, occultations occur when the radio link between any one of the 24 GPS transmitters and the low-earth orbiting (LEO) receiver progressively descends or ascends through the earth's atmosphere. With the current constellation of GPS transmitters, approximately 500 such occultations occur in each 24-hour period per LEO receiver. Several hundred occultations have been analyzed to date, where some type of confirmational data has been available (i.e., radiosonde, satellite, numerical analysis gridded data). In this paper, we present a brief outline of the method followed by a few typical temperature soundings that have been obtained.

  20. Space Shuttle Navigation in the GPS Era

    NASA Technical Reports Server (NTRS)

    Goodman, John L.

    2001-01-01

    The Space Shuttle navigation architecture was originally designed in the 1970s. A variety of on-board and ground based navigation sensors and computers are used during the ascent, orbit coast, rendezvous, (including proximity operations and docking) and entry flight phases. With the advent of GPS navigation and tightly coupled GPS/INS Units employing strapdown sensors, opportunities to improve and streamline the Shuttle navigation process are being pursued. These improvements can potentially result in increased safety, reliability, and cost savings in maintenance through the replacement of older technologies and elimination of ground support systems (such as Tactical Air Control and Navigation (TACAN), Microwave Landing System (MLS) and ground radar). Selection and missionization of "off the shelf" GPS and GPS/INS units pose a unique challenge since the units in question were not originally designed for the Space Shuttle application. Various options for integrating GPS and GPS/INS units with the existing orbiter avionics system were considered in light of budget constraints, software quality concerns, and schedule limitations. An overview of Shuttle navigation methodology from 1981 to the present is given, along with how GPS and GPS/INS technology will change, or not change, the way Space Shuttle navigation is performed in the 21 5 century.

  1. Wave Measurements Using GPS Velocity Signals

    PubMed Central

    Doong, Dong-Jiing; Lee, Beng-Chun; Kao, Chia Chuen

    2011-01-01

    This study presents the idea of using GPS-output velocity signals to obtain wave measurement data. The application of the transformation from a velocity spectrum to a displacement spectrum in conjunction with the directional wave spectral theory are the core concepts in this study. Laboratory experiments were conducted to verify the accuracy of the inversed displacement of the surface of the sea. A GPS device was installed on a moored accelerometer buoy to verify the GPS-derived wave parameters. It was determined that loss or drifting of the GPS signal, as well as energy spikes occurring in the low frequency band led to erroneous measurements. Through the application of moving average skill and a process of frequency cut-off to the GPS output velocity, correlations between GPS-derived, and accelerometer buoy-measured significant wave heights and periods were both improved to 0.95. The GPS-derived one-dimensional and directional wave spectra were in agreement with the measurements. Despite the direction verification showing a 10° bias, this exercise still provided useful information with sufficient accuracy for a number of specific purposes. The results presented in this study indicate that using GPS output velocity is a reasonable alternative for the measurement of ocean waves. PMID:22346618

  2. Errors in long distance kinematic GPS

    NASA Technical Reports Server (NTRS)

    Colombo, Oscar L.

    1991-01-01

    An attempt is made to quantify the contribution of tropospheric refraction, GPS ephemerides errors, and unresolved ambiguities to the overall error in the use of differential GPS to estimate aircraft position over very long distances. The extent to which such errors can be filtered out when estimating a trajectory, and how efficiently this may be done, are addressed.

  3. Monitoring beach changes using GPS surveying techniques

    USGS Publications Warehouse

    Morton, Robert; Leach, Mark P.; Paine, Jeffrey G.; Cardoza, Michael A.

    1993-01-01

    The adaptation of Global Positioning System (GPS) surveying techniques to beach monitoring activities is a promising response to this challenge. An experiment that employed both GPS and conventional beach surveying was conducted, and a new beach monitoring method employing kinematic GPS surveys was devised. This new method involves the collection of precise shore-parallel and shore-normal GPS positions from a moving vehicle so that an accurate two-dimensional beach surface can be generated. Results show that the GPS measurements agree with conventional shore-normal surveys at the 1 cm level, and repeated GPS measurements employing the moving vehicle demonstrate a precision of better than 1 cm. In addition, the nearly continuous sampling and increased resolution provided by the GPS surveying technique reveals alongshore changes in beach morphology that are undetected by conventional shore-normal profiles. The application of GPS surveying techniques combined with the refinement of appropriate methods for data collection and analysis provides a better understanding of beach changes, sediment transport, and storm impacts.

  4. Ready To Navigate: Classroom GPS Applications.

    ERIC Educational Resources Information Center

    Lucking, Robert A.; Christmann, Edwin P.

    2002-01-01

    Discusses the potential contribution of GPS and related Geographic Information Systems (GIS) technology to education. Provides resources for teachers to plan a lesson on exploring with the help of a GPS device in order to increase students' awareness of their surroundings and broaden understanding of their place in the world. (KHR)

  5. External Review of GPS LifePlan

    ERIC Educational Resources Information Center

    Arendale, David R.

    2008-01-01

    The GPS LifePlan is an interactive resource that helps students succeed in reaching their career, education and personal goals. GPS stands for "GOALS + PLANS = SUCCESS". http://gpslifeplan.org This holistic academic and student development program provides a structure for students to define their goals and helps them establish plans to…

  6. An assisted GPS support for GPS simulators for embedded mobile positioning

    NASA Astrophysics Data System (ADS)

    Kashyap, Pradeep; Samant, Abhay; Sagiraju, Phani K.; Akopian, David

    2009-02-01

    During recent years, location technologies have emerged as a research area with many possible applications in wireless communications, surveillance, military equipment, etc. Location Based Services (LBS) such as safety applications have become very popular. For example, US Federal Communication Commission Enhanced 911 (E911) Mandate seeks to provide emergency services personnel with location information that will enable them to dispatch assistance to wireless 911 callers much more quickly. Assisted GPS (A-GPS) is an extension of the conventional Global Positioning System (GPS) which increases start-up sensitivity by as much as 25dB relative to conventional GPS and reduces start times to less than six seconds. In A-GPS assistance data is delivered to the receiver through communication links. This paper addresses the generation of the assistance for GPS simulators for testing A-GPS receivers. The proposed approach is to use IP-based links and location support standards for assistance delivery avoiding network-specific signaling mechanisms so that GPS receiver developers can use this information for testing A-GPS capabilities using basic GPS simulators. The approach is implemented for the GPS simulator developed by the National InstrumentsTM.

  7. GPS-based navigation for space applications

    NASA Astrophysics Data System (ADS)

    Champetier, C.; Duhamel, T.; Frezet, M.

    1995-03-01

    We present in this paper a survey of the applications of the GPS (global positioning system) system for spacecraft navigation. The use of the GPS techniques for space missions is a striking example of dual-use of military technology; it can bring vast improvements in performances and, in some cases, for a reduced cost. We only deal in this paper with the functional aspects and performances of GPS uses without addressing the issues of hardware implementation where current developments are leading to an increased miniaturization of the GPS receiver hardware. We start this paper with a general overview of the GPS system and its various uses for space missions. We then focus on four areas where MATRA MARCONI Space has conducted detailed analyses of performances: autonomous navigation for geostationary spacecraft, relative navigation for space rendezvous, differential navigation for landing vehicles, absolute navigation for launchers and reentry vehicles.

  8. Positional Accuracy of Gps Satellite Almanac

    NASA Astrophysics Data System (ADS)

    Ma, Lihua; Zhou, Shangli

    2014-12-01

    How to accelerate signal acquisition and shorten starting time are key problems in the Global Positioning System (GPS). GPS satellite almanac plays an important role in signal reception period. Almanac accuracy directly affects the speed of GPS signal acquisition, the start time of the receiver, and even the system performance to some extent. Combined with precise ephemeris products released by the International GNSS Service (IGS), the authors analyse GPS satellite almanac from the first day to the third day in the 1805th GPS week (from August 11 to 13, 2014 in the Gregorian calendar). The results show that mean of position errors in three-dimensional coordinate system varies from about 1 kilometer to 3 kilometers, which can satisfy the needs of common users.

  9. Preparation of Pt supported on WO 3-C with enhanced catalytic activity by microwave-pyrolysis method

    NASA Astrophysics Data System (ADS)

    Ye, Jilei; Liu, Jianguo; Zou, Zhigang; Gu, Jun; Yu, Tao

    The WO 3-C hybrid materials are prepared by intermittently microwave-pyrolysis using ammonium tungstate as the precursor, and then Pt nano-particles are deposited by microwave-assited polyol process on WO 3-C. The TEM images show the dispersion of ∼10 nm WO 3 particles size supported on carbon and ∼3 nm Pt metal crystallites supported on WO 3-C. XRD results illustrate that WO 3 presented as monoclinic phase and the content of WO 3 in WO 3/C and Pt/WO 3-C catalysts is further characterized by EDAX. Furthermore, XPS characterizations indicate that the interaction between Pt and WO 3 is dramatically enhanced after heat treatment at 200 °C. The activities of Pt/WO 3-C for the electrochemical oxidation of methanol are compared with Pt/C in acid solution by cyclic voltammetry, CO-stripping and chronoaperometry. Pt/WO 3-C catalyst calcined at 200 °C exhibits the highest activity per electrochemical active surface area for methanol oxidation and is 60 mV more negative for CO electro-oxidation than that of Pt/C and Pt/WO 3-C without heat treatment. The great enhancement of electrochemical performance may be due to the improvement of the synergistic effect between Pt and WO 3 in Pt/WO 3-C catalyst after heat treatment.

  10. Spectroscopic properties of KGd(WO 4) 2 and KGd(WO 4) 2:Ho 3+ single crystals studied by Brillouin and Raman scattering methods

    NASA Astrophysics Data System (ADS)

    Kasprowicz, D.; Runka, T.; Szybowicz, M.; Drozdowski, M.; Majchrowski, A.; Michalski, E.; Żmija, J.

    2006-07-01

    KGd(WO 4) 2 single crystals, pure and doped with holmium ions Ho 3+ at 0.5 and 1% concentrations were investigated by Brillouin and Raman scattering methods. Polarized Raman spectra of KGd(WO 4) 2 and KGd(WO 4) 2:Ho 3+ single crystals have been measured at room temperature. The assignment of the Raman-active A g and B g modes have been performed. Brillouin spectra were collected for the acoustic phonons propagating in [100], [001], [101], [-101], [110], [-110], [011] and [0-11] directions in KGd(WO 4) 2 and KGd(WO 4) 2:Ho 3+ single crystals at room temperature. Obtained results have been discussed in terms of the influence of the doping concentration on the lattice dynamics and crystal structure.

  11. Interplanetary GPS using pulsar signals

    NASA Astrophysics Data System (ADS)

    Becker, W.; Bernhardt, M. G.; Jessner, A.

    2015-11-01

    An external reference system suitable for deep space navigation can be defined by fast spinning and strongly magnetized neutron stars, called pulsars. Their beamed periodic signals have timing stabilities comparable to atomic clocks and provide characteristic temporal signatures that can be used as natural navigation beacons, quite similar to the use of GPS satellites for navigation on Earth. By comparing pulse arrival times measured on-board a spacecraft with predicted pulse arrivals at a reference location, the spacecraft position can be determined autonomously and with high accuracy everywhere in the solar system and beyond. The unique properties of pulsars make clear already today that such a navigation system will have its application in future astronautics. In this paper we describe the basic principle of spacecraft navigation using pulsars and report on the current development status of this novel technology.

  12. Tailoring surface states in WO3 photoanodes for efficient photoelectrochemical water splitting

    NASA Astrophysics Data System (ADS)

    Singh, Trilok; Müller, Ralf; Singh, Jai; Mathur, Sanjay

    2015-08-01

    The dynamics of photo-induced charge carriers are significantly influenced by the surface states of WO3 thin films, which were synthesized by reactive sputtering of tungsten substrates in oxygen plasma. Tailoring the surface properties by (i) hydrogen plasma treatment and (ii) anchoring plasmonic nanoparticles (Au and Ag) altered the light harvesting and charge separation/transport processes of WO3 photoanodes. Upon hydrogen plasma-treatment and coating of noble metal clusters, WO3 films showed enhanced visible light absorption and consequently higher photocurrent density (1.4 mA cm-2) compared to pristine WO3 (0.2 mA cm-2). Enhancement in hydrogen treated WO3 sample was found to be due to the reduction of W(VI) into W(V) centers, which produced substoichiometric WO3-x phases, whereas noble metal particles contributed towards both resonant and non-resonant scattering of incident light thereby increasing photon-to-current conversion efficiency.

  13. In situ etching WO{sub 3} nanoplates: Hydrothermal synthesis, photoluminescence and gas sensor properties

    SciTech Connect

    Su, Xintai; Li, Yani; Jian, Jikang; Wang, Jide

    2010-12-15

    A novel hydrothermal process using p-nitrobenzoic acid as structure-directing agent has been employed to synthesize plate-shaped WO{sub 3} nanostructures containing holes. The p-nitrobenzoic acid plays a critical role in the synthesis of such novel WO{sub 3} nanoplates. The morphology, structure and optical property of the WO{sub 3} nanoplates have been characterized by transmission electron microcopy (TEM), scanning electron microcopy (SEM), X-ray diffraction (XRD) and photoluminescence (PL). The lateral size of the nanoplates is 500-1000 nm, and the thickness is about 80 nm. The formation mechanism of WO{sub 3} nanoplates is discussed briefly. The gas sensitivity of WO{sub 3} nanoplates was studied to ethanol and acetone at different operation temperatures and concentrations. Furthermore, the WO{sub 3} nanoplate-based gas sensor exhibits high sensitivity for ethanol and acetone as well as quick response and recovery time at low temperature.

  14. Enhanced photoelectrochemical and photocatalytic activity of WO3-surface modified TiO2 thin film.

    PubMed

    Qamar, Mohammad; Drmosh, Qasem; Ahmed, Muhammad I; Qamaruddin, Muhammad; Yamani, Zain H

    2015-01-01

    Development of nanostructured photocatalysts for harnessing solar energy in energy-efficient and environmentally benign way remains an important area of research. Pure and WO3-surface modified thin films of TiO2 were prepared by magnetron sputtering on indium tin oxide glass, and photoelectrochemical and photocatalytic activities of these films were studied. TiO2 particles were <50 nm, while deposited WO3 particles were <20 nm in size. An enhancement in the photocurrent was observed when the TiO2 surface was modified WO3 nanoparticles. Effect of potential, WO3 amount, and radiations of different wavelengths on the photoelectrochemical activity of TiO2 electrodes was investigated. Photocatalytic activity of TiO2 and WO3-modified TiO2 for the decolorization of methyl orange was tested. Graphical abstractWO3-surface modified TiO2 film showing better photocatalytic and photoelectrocatalytic activity. PMID:25852351

  15. Room temperature NO2-sensing properties of WO3 nanoparticles/porous silicon

    NASA Astrophysics Data System (ADS)

    Yan, Wenjun; Hu, Ming; Zeng, Peng; Ma, Shuangyun; Li, Mingda

    2014-02-01

    WO3 nanoparticles were synthesized by sol-gel method with tungsten hexachloride (WCl6) as precursor and deposited onto porous silicon and alumina substrates by dip-coating. The morphology and crystal structure of samples were investigated by means of field emission scanning electron microscope and X-ray diffractometer. It is the experimental results demonstrated by gas sensing tests that WO3 nanoparticles combining with the substrate of porous silicon presented an improved NO2-sensing property at room temperature. Compared to WO3 deposited on alumina working above 100 °C, the WO3 nanoparticles/porous silicon exhibited higher properties upon exposure to sub-ppm concentrations of NO2 gas at room temperature. Additionally, the NO2-sensing performance of WO3 nanoparticles/porous silicon was enhanced markedly, in comparison to pure porous silicon. The mechanism of WO3/porous silicon composite structure on the NO2 sensing was explained in detail.

  16. Enhancement of the photocatalytic activity and electrochemical property of graphene-SrWO4 nanocomposite

    NASA Astrophysics Data System (ADS)

    Liu, Xiaoyan; Nie, Yu; Yang, Hongxun; Sun, Shengnan; Chen, Yingying; Yang, Tongyi; Lin, Shengling

    2016-05-01

    SrWO4 is a promising candidate as not only photocatalyst for the removal of organic pollutants from water, but also electrode material for energy storage devices. However, the drawbacks of its poor adsorptive performance, low electrical conductivity, and high recombination rate of photogenerated electron-hole pair impede its practical applications. In this work, we have developed a new graphene/SrWO4 nanocomposite synthesized via a facile chemical precipitation method. Characterizations show that SrWO4 nanoparticles with 80 nm or so deposited on the surface of graphene nanosheets. Graphene nanosheets in the graphene-SrWO4 hybrid could increase adsorptive property, improve the electrical conductivity of hybrid, and reduce the recombination of electron-hole pairs. As a kind of photocatalyst or electrode material for supercapacitor, the binary graphene-SrWO4 hybrid presents enhanced photocatalytic activity and electrochemical property compared to pure SrWO4.

  17. Poly(methacrylic acid)-mediated morphosynthesis of PbWO4 micro-crystals

    NASA Astrophysics Data System (ADS)

    Yu, J. G.; Zhao, X. F.; Liu, S. W.; Li, M.; Mann, S.; Ng, D. H. L.

    2007-04-01

    PbWO4 crystals with various morphologies were fabricated via a facile poly(methacrylic acid)-mediated hydrothermal route. Novel microsized PbWO4 single crystals with a needle-like shape as well as other morphologies, such as a fishbone, dendrite, sphere, spindle, ellipsoid, rod, and dumbbell with two dandelion-like heads, could be produced. The presence of PMAA, [Pb2+]/[WO4 2-] molar ratio (R), and aging temperature played key roles in the formation of the PbWO4 needle-like structures. Between temperatures of 60 to 150 °C, the length and photoluminescence intensities of the PbWO4 micro needles significantly increased with aging temperature, while the diameter did not change remarkably. Time-dependent experiments revealed that the formation of PbWO4 microneedles involved an unusual growth process, involving nucleation, oriented assembly and controlled mesoscale restructuring of nanoparticle building blocks.

  18. Photocatalytic Removal of Microcystin-LR by Advanced WO3-Based Nanoparticles under Simulated Solar Light

    PubMed Central

    Zhao, Chao; Li, Dawei; Feng, Chuanping; Zhang, Zhenya; Sugiura, Norio; Yang, Yingnan

    2015-01-01

    A series of advanced WO3-based photocatalysts including CuO/WO3, Pd/WO3, and Pt/WO3 were synthesized for the photocatalytic removal of microcystin-LR (MC-LR) under simulated solar light. In the present study, Pt/WO3 exhibited the best performance for the photocatalytic degradation of MC-LR. The MC-LR degradation can be described by pseudo-first-order kinetic model. Chloride ion (Cl−) with proper concentration could enhance the MC-LR degradation. The presence of metal cations (Cu2+ and Fe3+) improved the photocatalytic degradation of MC-LR. This study suggests that Pt/WO3 photocatalytic oxidation under solar light is a promising option for the purification of water containing MC-LR. PMID:25884038

  19. Preparation and characterization of WO3 nanoparticles, WO3/TiO2 core/shell nanocomposites and PEDOT:PSS/WO3 composite thin films for photocatalytic and electrochromic applications

    NASA Astrophysics Data System (ADS)

    Boyadjiev, Stefan I.; Santos, Gustavo dos Lopes; Szżcs, Júlia; Szilágyi, Imre M.

    2016-03-01

    In this study, monoclinic WO3 nanoparticles were obtained by thermal decomposition of (NH4)xWO3 in air at 600 °C. On them by atomic layer deposition (ALD) TiO2 films were deposited, and thus core/shell WO3/TiO2 nanocomposites were prepared. We prepared composites of WO3 nanoparticles with conductive polymer as PEDOT:PSS, and deposited thin films of them on glass and ITO substrates by spin coating. The formation, morphology, composition and structure of the as-prepared pure and composite nanoparticles, as well thin films, were studied by TEM, SEM-EDX and XRD. The photocatalytic activity of both the WO3 and core/shell WO3/TiO2 nanoparticles was studied by decomposing methyl orange in aqueous solution under UV light irradiation. Cyclic voltammetry measurements were performed on the composite PEDOT:PSS/WO3 thin films, and the coloring and bleaching states were studied.

  20. GPS Radio Occultation as Part of the Global Observing System for Atmosphere

    NASA Technical Reports Server (NTRS)

    Mannucci, Anthony J.; Ao, C. O.; Iijima, B. A.; Wilson, B. D.; Yunck, T. P.; Kursinski, E. R.

    2008-01-01

    Topics include: The Measurement (Physical retrievals based on time standards), GPS Retrieval Products, Retrievals and Radiances: CLARREO Mission, GPS RO and AIRS, GPS RO and Microwave, GPS RO and Radiosondes, GPS/GNSS Science, and Conclusions.

  1. Evaluating the Effect of Global Positioning System (GPS) Satellite Clock Error via GPS Simulation

    NASA Astrophysics Data System (ADS)

    Sathyamoorthy, Dinesh; Shafii, Shalini; Amin, Zainal Fitry M.; Jusoh, Asmariah; Zainun Ali, Siti

    2016-06-01

    This study is aimed at evaluating the effect of Global Positioning System (GPS) satellite clock error using GPS simulation. Two conditions of tests are used; Case 1: All the GPS satellites have clock errors within the normal range of 0 to 7 ns, corresponding to pseudorange error range of 0 to 2.1 m; Case 2: One GPS satellite suffers from critical failure, resulting in clock error in the pseudorange of up to 1 km. It is found that increase of GPS satellite clock error causes increase of average positional error due to increase of pseudorange error in the GPS satellite signals, which results in increasing error in the coordinates computed by the GPS receiver. Varying average positional error patterns are observed for the each of the readings. This is due to the GPS satellite constellation being dynamic, causing varying GPS satellite geometry over location and time, resulting in GPS accuracy being location / time dependent. For Case 1, in general, the highest average positional error values are observed for readings with the highest PDOP values, while the lowest average positional error values are observed for readings with the lowest PDOP values. For Case 2, no correlation is observed between the average positional error values and PDOP, indicating that the error generated is random.

  2. GPS radio interferometry of travelling ionospheric disturbances

    NASA Astrophysics Data System (ADS)

    Afraimovich, E. L.; Palamartchouk, K. S.; Perevalova, N. P.

    1998-01-01

    This paper presents some results investigating the new possibilities of radio interferometry of Travelling Ionospheric Disturbances (TIDs) that are based on exploiting standard measurements of transionospheric radio signal characteristics and coordinate-time measurements using dual-frequency multichannel receivers of the Global Positioning System (GPS). A Statistical Angle-of-arrival and Doppler Method for GPS radio interferometry (SADM-GPS) is proposed for determining the characteristics of the TIDs dynamics by measuring variations of GPS phase derivatives with respect to time and spatial coordinates. These data are used to calculate corresponding values of the velocity vector, in view of a correction for satellite motions based on the current information available regarding the angular coordinates of the satellites. Subsequently, velocity and direction distributions are constructed and analyzed to verify the hypothesis of whether there is a predominant displacement. If it exists, then the pattern can be considered to be travelling, and the mean travel velocity can be determined from the velocity distribution. Through a computer simulation it was shown that multi-satellite GPS radio interferometry in conjunction with the SADM-GPS algorithm allows the detection and measurement of the velocity vector of TIDs in virtually the entire azimuthal range of possible TID propagation directions. The use of the proposed method is exemplified by an investigation of TIDs during the solar eclipse of 9 March 1997, using the GPS-radio interferometer GPSINT at Irkutsk.

  3. PiVoT GPS Receiver

    NASA Technical Reports Server (NTRS)

    Wennersten, Miriam Dvorak; Banes, Anthony Vince; Boegner, Gregory J.; Dougherty, Lamar; Edwards, Bernard L.; Roman, Joseph; Bauer, Frank H. (Technical Monitor)

    2001-01-01

    NASA Goddard Space Flight Center has built an open architecture, 24 channel space flight GPS receiver. The CompactPCI PiVoT GPS receiver card is based on the Mitel/GEC Plessey Builder-2 board. PiVoT uses two Plessey 2021 correlators to allow tracking of up to 24 separate GPS SV's on unique channels. Its four front ends can support four independent antennas, making it a useful card for hosting GPS attitude determination algorithms. It has been built using space quality, radiation tolerant parts. The PiVoT card will track a weaker signal than the original Builder 2 board. It also hosts an improved clock oscillator. The PiVoT software is based on the original Plessey Builder 2 software ported to the Linux operating system. The software is POSIX complaint and can easily be converted to other POSIX operating systems. The software is open source to anyone with a licensing agreement with Plessey. Additional tasks can be added to the software to support GPS science experiments or attitude determination algorithms. The next generation PiVoT receiver will be a single radiation hardened CompactPCI card containing the microprocessor and the GPS receiver optimized for use above the GPS constellation. PiVoT was flown successfully on a balloon in July, 2001, for its first non-simulated flight.

  4. Briefing highlights space weather risks to GPS

    NASA Astrophysics Data System (ADS)

    Tretkoff, Ernie

    2011-07-01

    Solar storms, which are expected to increase as the Sun nears the most active phase of the solar cycle, can disrupt a variety of technologies on which society relies. Speakers at a 22 June briefing on Capitol Hill in Washington, D. C., focused on how space weather can affect the Global Positioning System (GPS), which is used in a wide range of industries, including commercial air travel, agriculture, national security, and emergency response. Rocky Stone, chief technical pilot for United Airlines, noted that GPS allows more aircraft to be in airspace, saves fuel, and helps aircraft move safely on runways. “Improvements in space weather forecasting need to be pursued,” he said. Precision GPS has also “changed the whole nature of farming,” said Ron Hatch, Director of Navigation Systems, NavCom Technology/John Deere. GPS makes it possible for tractors to be driven in the most efficient paths and for fertilizer and water to be applied precisely to the areas that most need them. Space weather-induced degradation of GPS signals can cause significant loss to farms that rely on GPS. Elizabeth Zimmerman, Deputy Associate Administrator for the Office of Response and Recovery at the Federal Emergency Management Agency (FEMA), described how FEMA relies on GPS for disaster recovery. The agency is developing an operations plan for dealing with space weather, she said.

  5. NASA's GPS tracking system for Aristoteles

    NASA Astrophysics Data System (ADS)

    Davis, E. S.; Hajj, G.; Kursinski, E. R.; Kyriacou, C.; Meehan, T. K.; Melbourne, William G.; Neilan, R. E.; Young, L. E.; Yunck, Thomas P.

    1991-12-01

    NASA 's Global Positioning System (GPS) tracking system for Artistoteles receivers and a GPS flight receiver aboard Aristoteles is described. It will include a global network of GPS ground receivers and a GPS flight receiver aboard Aristoteles. The flight receiver will operate autonomously; it will provide real time navigation solutions for Aristoteles and tracking data needed by ESOC for operational control of the satellite. The GPS flight and ground receivers will currently and continuously track all visible GPS satellites. These observations will yield high accuracy differential positions and velocities of Aristoteles in a terrestrial frame defined by the locations of the globally distributed ground work. The precise orbits and tracking data will be made available to science investigators as part of the geophysical data record. The characteristics of the GPS receivers, both flight and ground based, that NASA will be using to support Aristoteles are described. The operational aspects of the overall tracking system, including the data functions and the resulting data products are summarized. The expected performance of the tracking system is compared to Aristoteles requirements and the need to control key error sources such as multipath is identified.

  6. Seasonal Effects on GPS PPP Accuracy

    NASA Astrophysics Data System (ADS)

    Saracoglu, Aziz; Ugur Sanli, D.

    2016-04-01

    GPS Precise Point Positioning (PPP) is now routinely used in many geophysical applications. Static positioning and 24 h data are requested for high precision results however real life situations do not always let us collect 24 h data. Thus repeated GPS surveys of 8-10 h observation sessions are still used by some research groups. Positioning solutions from shorter data spans are subject to various systematic influences, and the positioning quality as well as the estimated velocity is degraded. Researchers pay attention to the accuracy of GPS positions and of the estimated velocities derived from short observation sessions. Recently some research groups turned their attention to the study of seasonal effects (i.e. meteorological seasons) on GPS solutions. Up to now usually regional studies have been reported. In this study, we adopt a global approach and study the various seasonal effects (including the effect of the annual signal) on GPS solutions produced from short observation sessions. We use the PPP module of the NASA/JPL's GIPSY/OASIS II software and globally distributed GPS stations' data of the International GNSS Service. Accuracy studies previously performed with 10-30 consecutive days of continuous data. Here, data from each month of a year, incorporating two years in succession, is used in the analysis. Our major conclusion is that a reformulation for the GPS positioning accuracy is necessary when taking into account the seasonal effects, and typical one term accuracy formulation is expanded to a two-term one.

  7. Think GPS offers high security? Think again.

    SciTech Connect

    Johnston, R. G.; Warner, J. S.

    2004-01-01

    The Global Positioning System (GPS) is being increasingly used for a variety of important applications. These include public safety services (police, fire, rescue, and ambulance), marine and aircraft navigation, vehicle theft monitoring, cargo tracking, and critical time synchronization for utility, telecommunications, banking, and computer industries. Civilian GPS signals-the only ones available to business and to most of the federal government-are high-tech, but not high-security. They were never meant for critical or security applications. Unlike the military GPS signals, civilian GPS satellite signals are unencrypted and unauthenticated. This makes it easy for even relatively unsophisticated adversaries to jam or counterfeit them. Counterfeiting ('spoofing') of civilian GPS signals is particularly troublesome because it is totally surreptitious, and (as we have demonstrated) surprisingly simple. The U.S. Department of Transportation (DOT) has warned of vulnerabilities and looming problems associated with over-reliance and over-confidence in civilian GPS. Few GPS users appear to be paying attention.

  8. Snake River Plain FORGE Well Data for WO-2

    DOE Data Explorer

    Robert Podgorney

    1991-07-29

    Well data for the WO-2 well located in eastern Snake River Plain, Idaho. This data collection includes lithology reports, borehole logs, temperature at depth data, neutron density and gamma data, and rock strength parameters for the WO-2 well. This collection of data has been assembled as part of the site characterization data used to develop the conceptual geologic model for the Snake River Plain site in Idaho, as part of phase 1 of the Frontier Observatory for Research in Geothermal Energy (FORGE) initiative. They were assembled by the Snake River Geothermal Consortium (SRGC), a team of collaborators that includes members from national laboratories, universities, industry, and federal agencies, lead by the Idaho National Laboratory (INL).

  9. Synthesis and ionic liquid gating of hexagonal WO{sub 3} thin films

    SciTech Connect

    Wu, Phillip M. E-mail: beasley@stanford.edu; Munakata, Ko; Hammond, R. H.; Geballe, T. H.; Beasley, M. R. E-mail: beasley@stanford.edu; Ishii, Satoshi; Tanabe, Kenji; Tokiwa, Kazuyasu

    2015-01-26

    Via thin film deposition techniques, the meta-stable in bulk crystal hexagonal phase of tungsten oxide (hex-WO{sub 3}) is stabilized as a thin film. The hex-WO{sub 3} structure is potentially promising for numerous applications and is related to the structure for superconducting compounds found in WO{sub 3}. Utilizing ionic liquid gating, carriers were electrostatically induced in the films and an insulator-to-metal transition is observed. These results show that ionic liquid gating is a viable technique to alter the electrical transport properties of WO{sub 3}.

  10. Spontaneous and stimulated Raman scattering in ZnWO{sub 4} crystals

    SciTech Connect

    Basiev, Tasoltan T; Karasik, Aleksandr Ya; Sobol, A A; Chunaev, D S; Shukshin, V E

    2011-04-30

    Spontaneous and stimulated Raman scattering (SRS) are studied in ZnWO{sub 4} crystals with a wolframite structure. The polarised Raman scattering spectra corresponding to all the six independent Raman tensor components are measured. The frequencies of the complete set of vibrational modes are identified. The threshold pump energies for SRS in ZnWO{sub 4} and KGd(WO{sub 4}){sub 2} crystals are measured upon excitation by picosecond 1047-nm pulses of a Nd:YLF laser. The SRS gains for ZnWO{sub 4} crystals are determined based on the measured thresholds and spectroscopic parameters of the crystals. (nonlinear optics phenomena)

  11. Disciplined rubidium oscillator with GPS selective availability

    NASA Technical Reports Server (NTRS)

    Dewey, Wayne P.

    1993-01-01

    A U.S. Department of Defense decision for continuous implementation of GPS Selective Availability (S/A) has made it necessary to modify Rubidium oscillator disciplining methods. One such method for reducing the effects of S/A on the oscillator disciplining process was developed which achieves results approaching pre-S/A GPS. The Satellite Hopping algorithm used in minimizing the effects of S/A on the oscillator disciplining process is described, and the results of using this process to those obtained prior to the implementation of S/A are compared. Test results are from a TrueTime Rubidium based Model GPS-DC timing receiver.

  12. WO3 nanotubes prepared by a coaxial electrospinning method.

    PubMed

    Cao, Xingxing; Zhang, Xuebin; Hu, Jixiang; Wang, Yang; Liu, Jia; Wu, Haijun; Feng, Yi

    2014-08-01

    In this paper, WO3 nanotubes were prepared by a coaxial electrospinning method. Firstly, core-shell structured composite fibers were fabricated via coaxial electrospinning under the optimal electro-spinning parameters to get the best composite fibers with uniform diameters and smooth surface, which pure PVA being the core solution and PVA/AMT/alcohol being the shell one, respectively. Secondly, the composite fibers were calcined in air at 600 °C for 4 h to wipe out the pure PVA, leading to the formation of nanotubes. After sintering, the obtained WO3 nanotubes were characterized by Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), Field emission scanning electron microscopy (FESEM) and high-resolution transmission electron microscopy (HRTEM). The XRD show that the resultant materials consist of pure tungsten trioxide (WO3) with good crystallinity, while FESEM and HRTEM images indicate that the materials are nanotubes with rough surface and consist of nanoparticles. The inner diameter and the wall thickness of nanotubes were calculated to be around 100 and 50 nm, respectively. PMID:25936119

  13. Eukaryotic association module in phage WO genomes from Wolbachia

    PubMed Central

    Bordenstein, Sarah R.; Bordenstein, Seth R.

    2016-01-01

    Viruses are trifurcated into eukaryotic, archaeal and bacterial categories. This domain-specific ecology underscores why eukaryotic viruses typically co-opt eukaryotic genes and bacteriophages commonly harbour bacterial genes. However, the presence of bacteriophages in obligate intracellular bacteria of eukaryotes may promote DNA transfers between eukaryotes and bacteriophages. Here we report a metagenomic analysis of purified bacteriophage WO particles of Wolbachia and uncover a eukaryotic association module in the complete WO genome. It harbours predicted domains, such as the black widow latrotoxin C-terminal domain, that are uninterrupted in bacteriophage genomes, enriched with eukaryotic protease cleavage sites and combined with additional domains to forge one of the largest bacteriophage genes to date (14,256 bp). To the best of our knowledge, these eukaryotic-like domains have never before been reported in packaged bacteriophages and their phylogeny, distribution and sequence diversity imply lateral transfers between bacteriophage/prophage and animal genomes. Finally, the WO genome sequences and identification of attachment sites will potentially advance genetic manipulation of Wolbachia. PMID:27727237

  14. Size analysis of nanoparticles extracted from W/O emulsions.

    PubMed

    Nagelreiter, C; Kotisch, H; Heuser, T; Valenta, C

    2015-07-01

    Nanosized particles are frequently used in many different applications, especially TiO2 nanoparticles as physical filters in sunscreens to protect the skin from UV radiation. However, concerns have arisen about possible health issues caused by nanoparticles and therefore, the assessment of the occurrence of nanoparticles is important in pharmaceutical and cosmetic formulations. In a previous work of our group, a method was presented to extract nanoparticles from O/W emulsions. But to respond to the needs of dry and sensitive skin, sunscreens of the water-in-oil emulsion type are available. In these, assessment of present nanoparticles is also an important issue, so the present study offers a method for extracting nanoparticles from W/O emulsions. Both methods emanate from the same starting point, which minimizes both effort and cost before the beginning of the assessment. By addition of NaOH pellets and centrifugation, particles were extracted from W/O emulsions and measured for their size and surface area by laser diffraction. With the simple equation Q=A/S a distinction between nanoparticles and microparticles was achieved in W/O emulsions, even in commercially available samples. The present method is quick and easy to implement, which makes it cost-effective. PMID:25907509

  15. WO3 nanotubes prepared by a coaxial electrospinning method.

    PubMed

    Cao, Xingxing; Zhang, Xuebin; Hu, Jixiang; Wang, Yang; Liu, Jia; Wu, Haijun; Feng, Yi

    2014-08-01

    In this paper, WO3 nanotubes were prepared by a coaxial electrospinning method. Firstly, core-shell structured composite fibers were fabricated via coaxial electrospinning under the optimal electro-spinning parameters to get the best composite fibers with uniform diameters and smooth surface, which pure PVA being the core solution and PVA/AMT/alcohol being the shell one, respectively. Secondly, the composite fibers were calcined in air at 600 °C for 4 h to wipe out the pure PVA, leading to the formation of nanotubes. After sintering, the obtained WO3 nanotubes were characterized by Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), Field emission scanning electron microscopy (FESEM) and high-resolution transmission electron microscopy (HRTEM). The XRD show that the resultant materials consist of pure tungsten trioxide (WO3) with good crystallinity, while FESEM and HRTEM images indicate that the materials are nanotubes with rough surface and consist of nanoparticles. The inner diameter and the wall thickness of nanotubes were calculated to be around 100 and 50 nm, respectively.

  16. Size analysis of nanoparticles extracted from W/O emulsions.

    PubMed

    Nagelreiter, C; Kotisch, H; Heuser, T; Valenta, C

    2015-07-01

    Nanosized particles are frequently used in many different applications, especially TiO2 nanoparticles as physical filters in sunscreens to protect the skin from UV radiation. However, concerns have arisen about possible health issues caused by nanoparticles and therefore, the assessment of the occurrence of nanoparticles is important in pharmaceutical and cosmetic formulations. In a previous work of our group, a method was presented to extract nanoparticles from O/W emulsions. But to respond to the needs of dry and sensitive skin, sunscreens of the water-in-oil emulsion type are available. In these, assessment of present nanoparticles is also an important issue, so the present study offers a method for extracting nanoparticles from W/O emulsions. Both methods emanate from the same starting point, which minimizes both effort and cost before the beginning of the assessment. By addition of NaOH pellets and centrifugation, particles were extracted from W/O emulsions and measured for their size and surface area by laser diffraction. With the simple equation Q=A/S a distinction between nanoparticles and microparticles was achieved in W/O emulsions, even in commercially available samples. The present method is quick and easy to implement, which makes it cost-effective.

  17. Improvement of radiopurity level of enriched 116CdWO4 and ZnWO4 crystal scintillators by recrystallization

    NASA Astrophysics Data System (ADS)

    Barabash, A. S.; Belli, P.; Bernabei, R.; Borovlev, Yu. A.; Cappella, F.; Caracciolo, V.; Cerulli, R.; Danevich, F. A.; Incicchitti, A.; Kobychev, V. V.; Konovalov, S. I.; Laubenstein, M.; Mokina, V. M.; Polischuk, O. G.; Safonova, O. E.; Shlegel, V. N.; Tretyak, V. I.; Tupitsyna, I. A.; Umatov, V. I.; Zhdankov, V. N.

    2016-10-01

    As low as possible radioactive contamination of a detector plays a crucial role to improve sensitivity of a double beta decay experiment. The radioactive contamination of a sample of 116CdWO4 crystal scintillator by thorium was reduced by a factor ≈10, down to the level 0.01 mBq/kg (228Th), by exploiting the recrystallization procedure. The total alpha activity of uranium and thorium daughters was reduced by a factor ≈3, down to 1.6 mBq/kg. No change in the specific activity (the total α activity and 228Th) was observed in a sample of ZnWO4 crystal produced by recrystallization after removing ≈0.4 mm surface layer of the crystal.

  18. Evaluation of WO2013125543, WO2013146963 and EP2634185: the first Tyk2 inhibitors from Takeda and Sareum.

    PubMed

    Norman, Peter

    2014-03-01

    Three patent applications, from two different companies, claim structurally novel Tyk2 inhibitors and their uses for the treatment of autoimmune diseases. In EP-2634185 Sareum claims 5-anilino-2-(2-halophenyl)-oxazole-4-carboxamide derivatives which are shown to be nanomolar potency Tyk2 inhibitors with 10 - 100-fold selectivity over JAK1, JAK2 and JAK3. Takeda's WO-2013125543 and WO-2013146963 claim two distinct structural classes of Tyk2 inhibitors. The first application claims inhibitors based on an unusual 1,5-dihydro-4H-pyrazolo[4,3-c]pyridine-4-one scaffold and the second claims 1-(2-arylaminopyrimidin-4-yl)-pyrrolidin-2-one derivatives. One example of the latter was shown to be orally active in an IL-23-induced inflammation model. PMID:24386992

  19. Navstar Global Positioning System (GPS) clock program: Present and future

    NASA Technical Reports Server (NTRS)

    Tennant, D. M.

    1981-01-01

    Global Positioning System (GPS) program status are discussed and plans for ensuring the long term continuation of the program are presented. Performance of GPS clocks is presented in terms of on orbit data as portrayed by GPS master control station kalman filter processing. The GPS Clock reliability program is reviewed in depth and future plans fo the overall clock program are published.

  20. Shuttle Global Positioning System (GPS) system design study

    NASA Technical Reports Server (NTRS)

    Nilsen, P. W.

    1979-01-01

    The various integration problems in the Shuttle GPS system were investigated. The analysis of the Shuttle GPS link was studied. A preamplifier was designed since the Shuttle GPS antennas must be located remotely from the receiver. Several GPS receiver architecture trade-offs were discussed. The Shuttle RF harmonics and intermode that fall within the GPS receiver bandwidth were analyzed. The GPS PN code acquisition was examined. Since the receiver clock strongly affects both GPS carrier and code acquisition performance, a clock model was developed.

  1. Temperature and acidity effects on WO{sub 3} nanostructures and gas-sensing properties of WO{sub 3} nanoplates

    SciTech Connect

    Zhang, Huili; Liu, Zhifang; Yang, Jiaqin; Guo, Wei; Zhu, Lianjie; Zheng, Wenjun

    2014-09-15

    Graphical abstract: Generally, large acid quantity and high temperature are beneficial to the formation of anhydrous WO3, but the acidity effect on the crystal phase is weaker than that of temperature. Large acid quantity is found helpful to the oriented growth of tungsten oxides, forming a nanoplate-like product. - Highlights: • Large acid quantity is propitious to the oriented growth of a WO{sub 3} nanoplate. • Effect of acid quantity on crystal phases of products is weaker than that of temperature. • One step hydrothermal synthesis of WO{sub 3} is facile and can be easily scaled up. • A WO{sub 3} nanoplate shows a fast response and distinct sensing selectivity to acetone gas. - Abstract: WO{sub 3} nanostructures were successfully synthesized by a facile hydrothermal method using Na{sub 2}WO{sub 4}·2H{sub 2}O and HNO{sub 3} as raw materials. They are characterized by X-ray diffraction (XRD), scanning electron microscope (SEM) and transmission electron microscope (TEM). The specific surface area was obtained from N{sub 2} adsorption–desorption isotherm. The effects of the amount of HNO{sub 3}, hydrothermal temperature and reaction time on the crystal phases and morphologies of the WO{sub 3} nanostructures were investigated in detail, and the reaction mechanism was discussed. Large amount of acid is found for the first time to be helpful to the oriented growth of tungsten oxides, forming nanoplate-like products, while hydrothermal temperature has more influence on the crystal phase of the product. Gas-sensing properties of the series of as-prepared WO{sub 3} nanoplates were tested by means of acetone, ethanol, formaldehyde and ammonia. One of the WO{sub 3} nanoplates with high specific surface area and high crystallinity displays high sensitivity, fast response and distinct sensing selectivity to acetone gas.

  2. Tightly-coupled GPS/UWB Integration

    NASA Astrophysics Data System (ADS)

    Macgougan, Glenn; O'Keefe, Kyle; Klukas, Richard

    Ultra-wideband (UWB) ranging radios, an emerging technology that offers precise, short distance range measurements are investigated as a method to augment carrier-phase GPS positioning. A commercially available UWB ranging system is used in a tightly-coupled GPS and UWB real-time kinematic (RTK) system. The performance of the tightly-coupled system is evaluated in static and kinematic testing. This work demonstrates that UWB errors can be successfully estimated in a real-time filter. The results of static testing show that the integrated solution provides better accuracy, better ability to resolve integer ambiguities and enhanced fixed ambiguity solution availability compared with GPS alone. In kinematic testing in a degraded GPS environment, sub-decimetre accuracy was maintained.

  3. Permanent GPS Geodetic Array in Southern California

    NASA Technical Reports Server (NTRS)

    Green, Cecil H.; Green, Ida M.

    1998-01-01

    The southern California Permanent GPS Geodetic Array (PGGA) was established in the spring of 1990 to evaluate continuous Global Positioning System (GPS) measurements as a new too] for monitoring crustal deformation. Southern California is an ideal location because of the relatively high rate of tectonic deformation, the high probability of intense seismicity, the long history of conventional and space geodetic measurements, and the availability of a well developed infrastructure to support continuous operations. Within several months of the start of regular operations, the PGGA recorded far-field coseismic displacements induced by the June 28, 1992 (M(sub w)=7.3), Landers earthquake, the largest magnitude earthquake in California in the past 40 years and the first one to be recorded by a continuous GPS array. Only nineteen months later, on 17 January 1994, the PGGA recorded coseismic displacements for the strongest earthquake to strike the Los Angeles basin in two decades, the (M(sub e)=6.7) Northridge earthquake. At the time of the Landers earthquake, only seven continuous GPS sites were operating in southern California; by the beginning of 1994, three more sites had been added to the array. However, only a pair of sites were situated in the Los Angeles basin. The destruction caused by the Northridge earthquake spurred a fourfold increase in the number of continuous GPS sites in southern California within 2 years of this event. The PGGA is now the regional component of the Southern California Integrated GPS Network (SCIGN), a major ongoing densification of continuous GPS sites, with a concentration in the Los Angeles metropolitan region. Continuous GPS provides temporally dense measurements of surface displacements induced by crustal deformation processes including interseismic, coseismic, postseismic, and aseismic deformation and the potential for detecting anomalous events such as preseismic deformation and interseismic strain variations. Although strain meters

  4. Reprocessing of GPS observations: influence of calibration models of antenna/radome combinations on permanent GPS station coordinates

    NASA Astrophysics Data System (ADS)

    Ishchenko, Marina

    2012-05-01

    Observations of the GPS satellites at permanent stations located in Ukraine and in the Eastern Europe were reprocessed at the GPS Analysis Center of the Main Astronomical Observatory with Bernese GPS Software ver. 5.0. The effect of influence of relative and absolute phase center variations of antenna/radome combinations to determination coordinates of permanent GPS stations are considered.

  5. Scintillation Effects on Space Shuttle GPS Data

    NASA Technical Reports Server (NTRS)

    Goodman, John L.; Kramer, Leonard

    2001-01-01

    Irregularities in ionospheric electron density result in variation in amplitude and phase of Global Positioning System (GPS) signals, or scintillation. GPS receivers tracking scintillated signals may lose carrier phase or frequency lock in the case of phase sc intillation. Amplitude scintillation can cause "enhancement" or "fading" of GPS signals and result in loss of lock. Scintillation can occur over the equatorial and polar regions and is a function of location, time of day, season, and solar and geomagnetic activity. Mid latitude regions are affected only very rarely, resulting from highly disturbed auroral events. In the spring of 1998, due to increasing concern about scintillation of GPS signals during the upcoming solar maximum, the Space Shuttle Program began to assess the impact of scintillation on Collins Miniaturized Airborne GPS Receiver (MAGR) units that are to replace Tactical Air Control and Navigation (TACAN) units on the Space Shuttle orbiters. The Shuttle Program must determine if scintillation effects pose a threat to safety of flight and mission success or require procedural and flight rule changes. Flight controllers in Mission Control must understand scintillation effects on GPS to properly diagnose "off nominal" GPS receiver performance. GPS data from recent Space Shuttle missions indicate that the signals tracked by the Shuttle MAGR manifest scintillation. Scintillation is observed as anomalous noise in velocity measurements lasting for up to 20 minutes on Shuttle orbit passes and are not accounted for in the error budget of the MAGR accuracy parameters. These events are typically coincident with latitude and local time occurrence of previously identified equatorial spread F within about 20 degrees of the magnetic equator. The geographic and seasonal history of these events from ground-based observations and a simple theoretical model, which have potential for predicting events for operational purposes, are reviewed.

  6. Annealing dynamics of WO{sub 3} by in situ XRD

    SciTech Connect

    Righettoni, Marco; Pratsinis, Sotiris E.

    2014-11-15

    Highlights: • Flame-made WO{sub 3} nanoparticles with closely controlled crystal and grain size. • Dynamic phase transition of annealing of pure and Si-doped WO{sub 3} by in situ XRD. • Irreversible evolution of WO{sub 3} crystallinity by heating/cooling during its annealing. • Si-doping alters the WO{sub 3} crystallinity dynamics and stabilizes nanosized WO{sub 3}. • Flame-made nano-WO{sub 3} can sense NO at the ppb level. - Abstract: Tungsten trioxide is a semiconductor with distinct applications in gas sensors, catalysis, batteries and pigments. As such the transition between its different crystal structures during its annealing are of interest, especially for sensor applications. Here, WO{sub 3} nanoparticles with closely controlled crystal and grain size (9–15 nm) and phase composition are made by flame spray pyrolysis and the formation of different WO{sub 3} phases during annealing is investigated. Most notably, the dynamic phase transition and crystal size evolution of WO{sub 3} during heating and cooling is monitored by in situ X-ray diffraction revealing how metastable WO{sub 3} phases can be captured stably. The effect of Si-doping is studied since it is used in practise to control crystal growth and phase transition during metal oxide synthesis and processing. Finally the influence of annealing on the WO{sub 3} sensing performance of NO, a lung inflammation tracer in the human breath, is explored at the ppb-level.

  7. Front end for GPS receivers

    NASA Technical Reports Server (NTRS)

    Thomas, Jr., Jess Brooks (Inventor)

    1999-01-01

    The front end in GPS receivers has the functions of amplifying, down-converting, filtering and sampling the received signals. In the preferred embodiment, only two operations, A/D conversion and a sum, bring the signal from RF to filtered quadrature baseband samples. After amplification and filtering at RF, the L1 and L2 signals are each sampled at RF at a high selected subharmonic rate. The subharmonic sample rates are approximately 900 MHz for L1 and 982 MHz for L2. With the selected subharmonic sampling, the A/D conversion effectively down-converts the signal from RF to quadrature components at baseband. The resulting sample streams for L1 and L2 are each reduced to a lower rate with a digital filter, which becomes a straight sum in the simplest embodiment. The frequency subsystem can be very simple, only requiring the generation of a single reference frequency (e.g. 20.46 MHz minus a small offset) and the simple multiplication of this reference up to the subharmonic sample rates for L1 and L2. The small offset in the reference frequency serves the dual purpose of providing an advantageous offset in the down-converted carrier frequency and in the final baseband sample rate.

  8. Permanent GPS and crustal deformation in Greenland

    NASA Astrophysics Data System (ADS)

    Khan, S. A.

    2003-12-01

    The National Survey and Cadastre - Denmark (KMS) is responsible for the geodetic definition of the reference network in Greenland. Permanent GPS plays an important role in the monitoring and maintenance of the geodetic network. Furthermore, KMS supports the international GPS infrastructure and research by supporting IGS. In October 1998 KMS has established a permanent GPS station THU2 at Thule Airbase. Besides THU2 the old permanent station THU1 is also running. The Thule stations are important because they are two of the few northernmost stations in the IGS network. THU2 has been operating since March 1999, and it is now a high quality and high performance station contributing to the IGS Low-Earth Orbiters (LEO) network. Besides the GPS stations in Thule, KMS is also running a permanent GPS station SCOB in Scoresbysund, which was established in August 1997, and in October 2001 a permanent station QAQ1 was established in Qaqortoq. This station is registered at IGS. Furthermore, University of Colorado operates the IGS station Kellyville near Kangerlussuaq and a station in Kulusuk. Using the BERNESE software, we have calculated daily baseline solutions between the GPS sites. The time series of the 3D crustal movements are analyzed due to post glacial rebound, plate tectonic and seasonal deformations (e.g. atmosphere loading). In addition, we have used the GIPSY OASIS II software to obtain similar time series. The results are compared with modeled estimates of the glacial rebound.

  9. Factors predicting trust between GPs and OPs

    PubMed Central

    Nauta, A.P.; von Grumbkow, J.

    2001-01-01

    Abstract Purpose To study possible differences in trust between general practitioners (GPs) and occupational physicians (OPs) and the explanatory factors for trust. Insight into the factors predicting trust can improve programmes for stimulating the co-operation of GPs and OPs. Theory On the basis of theories of trust and of social identity theory we expected, (1) in both professions a higher level of knowledge-based trust than of identification-based trust, (2) a relationship between higher levels of identification-based trust and higher frequency of contact, (3) OPs to have a higher level of identification-based trust than GPs. We hypothesised (4) that OPs perceiving an equal status have higher levels of trust and (5) GPs perceiving a higher status have lower levels of trust. Methods A mail survey sent to 2297 doctors (1728 GPs and 569 OPs) of which we used 547 questionnaires. Results Hypotheses 1 and 2 were supported. Hypothesis 3 was not supported. Hypotheses 4 and 5 were supported for knowledge-based trust. On the basis of these findings it is possible that co-operation between the two groups is still in its early stages. Conclusions Programmes to improve the co-operation of GPs and OPs should focus on equalising status and stimulating contacts to build (identification-based) trust. PMID:16896412

  10. GPS as an orbit determination subsystems

    NASA Technical Reports Server (NTRS)

    Fennessey, Richard; Roberts, Pat; Knight, Robin; Vanvolkinburg, Bart

    1995-01-01

    This paper evaluates the use of Global Positioning System (GPS) receivers as a primary source of tracking data for low-Earth orbit satellites. GPS data is an alternative to using range, azimuth, elevation, and range-rate (RAER) data from the Air Force Satellite Control Network antennas, the Space Ground Link System (SGLS). This evaluation is applicable to missions such as Skipper, a joint U.S. and Russian atmosphere research mission, that will rely on a GPS receiver as a primary tracking data source. The Detachment 2, Space and Missile Systems Center's Test Support Complex (TSC) conducted the evaluation based on receiver data from the Space Test Experiment Platform Mission O (STEP-O) and Advanced Photovoltaic and Electronics Experiments (APEX) satellites. The TSC performed orbit reconstruction and prediction on the STEP-0 and APEX vehicles using GPS receiver navigation solution data, SGLS RAER data, and SGLS anglesonly (azimuth and elevation) data. For the STEP-O case, the navigation solution based orbits proved to be more accurate than SGLS RAER based orbits. For the APEX case, navigation solution based orbits proved to be less accurate than SGLS RAER based orbits for orbit prediction, and results for orbit reconstruction were inconclusive due to the lack of a precise truth orbit. After evaluating several different GPS data processing methods, the TSC concluded that using GPS navigation solution data is a viable alternative to using SGLS RAER data.

  11. Combined GPS/GLONASS precise point positioning with fixed GPS ambiguities.

    PubMed

    Pan, Lin; Cai, Changsheng; Santerre, Rock; Zhu, Jianjun

    2014-09-18

    Precise point positioning (PPP) technology is mostly implemented with an ambiguity-float solution. Its performance may be further improved by performing ambiguity-fixed resolution. Currently, the PPP integer ambiguity resolutions (IARs) are mainly based on GPS-only measurements. The integration of GPS and GLONASS can speed up the convergence and increase the accuracy of float ambiguity estimates, which contributes to enhancing the success rate and reliability of fixing ambiguities. This paper presents an approach of combined GPS/GLONASS PPP with fixed GPS ambiguities (GGPPP-FGA) in which GPS ambiguities are fixed into integers, while all GLONASS ambiguities are kept as float values. An improved minimum constellation method (MCM) is proposed to enhance the efficiency of GPS ambiguity fixing. Datasets from 20 globally distributed stations on two consecutive days are employed to investigate the performance of the GGPPP-FGA, including the positioning accuracy, convergence time and the time to first fix (TTFF). All datasets are processed for a time span of three hours in three scenarios, i.e., the GPS ambiguity-float solution, the GPS ambiguity-fixed resolution and the GGPPP-FGA resolution. The results indicate that the performance of the GPS ambiguity-fixed resolutions is significantly better than that of the GPS ambiguity-float solutions. In addition, the GGPPP-FGA improves the positioning accuracy by 38%, 25% and 44% and reduces the convergence time by 36%, 36% and 29% in the east, north and up coordinate components over the GPS-only ambiguity-fixed resolutions, respectively. Moreover, the TTFF is reduced by 27% after adding GLONASS observations. Wilcoxon rank sum tests and chi-square two-sample tests are made to examine the significance of the improvement on the positioning accuracy, convergence time and TTFF.

  12. Combined GPS/GLONASS Precise Point Positioning with Fixed GPS Ambiguities

    PubMed Central

    Pan, Lin; Cai, Changsheng; Santerre, Rock; Zhu, Jianjun

    2014-01-01

    Precise point positioning (PPP) technology is mostly implemented with an ambiguity-float solution. Its performance may be further improved by performing ambiguity-fixed resolution. Currently, the PPP integer ambiguity resolutions (IARs) are mainly based on GPS-only measurements. The integration of GPS and GLONASS can speed up the convergence and increase the accuracy of float ambiguity estimates, which contributes to enhancing the success rate and reliability of fixing ambiguities. This paper presents an approach of combined GPS/GLONASS PPP with fixed GPS ambiguities (GGPPP-FGA) in which GPS ambiguities are fixed into integers, while all GLONASS ambiguities are kept as float values. An improved minimum constellation method (MCM) is proposed to enhance the efficiency of GPS ambiguity fixing. Datasets from 20 globally distributed stations on two consecutive days are employed to investigate the performance of the GGPPP-FGA, including the positioning accuracy, convergence time and the time to first fix (TTFF). All datasets are processed for a time span of three hours in three scenarios, i.e., the GPS ambiguity-float solution, the GPS ambiguity-fixed resolution and the GGPPP-FGA resolution. The results indicate that the performance of the GPS ambiguity-fixed resolutions is significantly better than that of the GPS ambiguity-float solutions. In addition, the GGPPP-FGA improves the positioning accuracy by 38%, 25% and 44% and reduces the convergence time by 36%, 36% and 29% in the east, north and up coordinate components over the GPS-only ambiguity-fixed resolutions, respectively. Moreover, the TTFF is reduced by 27% after adding GLONASS observations. Wilcoxon rank sum tests and chi-square two-sample tests are made to examine the significance of the improvement on the positioning accuracy, convergence time and TTFF. PMID:25237901

  13. Effect of crystallization water on the structural and electrical properties of CuWO{sub 4} under high pressure

    SciTech Connect

    Wang, Li; Yan, Jiejuan; Liu, Cailong; Liu, Xizhe; Han, Yonghao E-mail: cc060109@qq.com; Gao, Chunxiao E-mail: cc060109@qq.com; Ke, Feng; Wang, Qinglin; Li, Yanchun; Ma, Yanzhang

    2015-11-16

    The effect of crystallization water on the structural and electrical properties of CuWO{sub 4} under high pressure has been investigated by in situ X-ray diffraction and alternating current impedance spectra measurements. The crystallization water was found to be a key role in modulating the structural stability of CuWO{sub 4} at high pressures. The anhydrous CuWO{sub 4} undergoes two pressure-induced structural transitions at 8.8 and 18.5 GPa, respectively, while CuWO{sub 4}·2H{sub 2}O keeps its original structure up to 40.5 GPa. Besides, the crystallization water makes the electrical transport behavior of anhydrous CuWO{sub 4} and CuWO{sub 4}·2H{sub 2}O quite different. The charge carrier transportation is always isotropic in CuWO{sub 4}·2H{sub 2}O, but anisotropic in the triclinic and the third phase of anhydrous CuWO{sub 4}. The grain resistance of CuWO{sub 4}·2H{sub 2}O is always larger than that of anhydrous CuWO{sub 4} in the entire pressure range. By analyzing the relaxation response, we found that the large number of hydrogen bonds can soften the grain characteristic frequency of CuWO{sub 4}·2H{sub 2}O over CuWO{sub 4} by one order of magnitude.

  14. Correlation between surface chemistry, density, and band gap in nanocrystalline WO3 thin films.

    PubMed

    Vemuri, R S; Engelhard, M H; Ramana, C V

    2012-03-01

    Nanocrystalline WO(3) thin films were produced by sputter-deposition by varying the ratio of argon to oxygen in the reactive gas mixture during deposition. The surface chemistry, physical characteristics, and optical properties of nanocrystalline WO(3) films were evaluated using X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), atomic force microscopy (AFM), X-ray reflectivity (XRR), and spectrophotometric measurements. The effect of ultramicrostructure was significant on the optical properties of WO(3) films. The XPS analyses indicate the formation of stoichiometric WO(3) with tungsten existing in fully oxidized valence state (W(6+)). However, WO(3) films grown at high oxygen concentration (>60%) in the sputtering gas mixture were over stoichiometric with excess oxygen. XRR simulations based on isotropic WO(3) film-SiO(2) interface-Si substrate modeling indicate that the density of WO(3) films is sensitive to the oxygen content in the sputtering gas. The spectral transmission of the films increased with increasing oxygen. The band gap of these films increases from 2.78 to 3.25 eV with increasing oxygen. A direct correlation between the film density and band gap in nanocrystalline WO(3) films is established on the basis of the observed results. PMID:22332637

  15. Lithium-titanate-nanotube-supported WO3 for enhancing transmittance contrast in electrochromics.

    PubMed

    Dong, Yunbing; Xiong, Chunrong; Zhang, Yilu; Xing, Shuai; Jiang, Hong

    2016-03-11

    Lithium titanate nanotubes (Li-TNTs) have been successfully synthesized. The inner and outer diameters of the nanotubes are 5 nm and 8 nm with an interlayer spacing of 0.83 nm. The nanotubes were in accordance with the Li1.81H0.19Ti2O5 · xH2O phase. The chemical component was Li0.9H1.1Ti2O5 · H2O as determined by ICP-AES. The Li-TNT-supported WO3 nanoparticle (WO3/Li-TNTs) thin film was prepared onto ITO glass via spin-coating and then fabricated with an electrochromic device. The Li ion diffusion coefficient in the WO3/Li-TNT film was 6.1 × 10(-10) cm(2) s(-1), which is eight times higher than that for the pure WO3 film. The transmittance contrast of the pure WO3-based ECD was 53.3% at 600 nm. However, this increased to 74.1% for the WO3/Li-TNT-based ECD. Meanwhile, the color-switching times of the WO3/Li-TNT-based ECD were apparently shorter than the ones for the WO3-based ECD. PMID:26866352

  16. Influence of peculiarities of electronic excitation relaxation on luminescent properties of MgWO4

    NASA Astrophysics Data System (ADS)

    Krutyak, N. R.; Spassky, D. A.; Tupitsyna, I. A.; Dubovik, A. M.

    2016-07-01

    Luminescent properties of magnesium tungstate monocrystals grown by two different methods are studied. Only the exciton luminescence of these crystals themselves is observed. Temperature dependence of the low-energy range in the luminescence excitation spectra is described by the Urbach rule. Slope coefficient σ0 = 0.74 obtained from this dependence implies autolocalization of the excitons in MgWO4. The processes of electronic excitations relaxation are considered depending on the structure of valence band in MgWO4 and in other wolframites, ZnWO4 and CdWO4. In contrast to ZnWO4 and CdWO4, the d-states of the cation do not participate in formation of the MgWO4 valence band. Using the excitation spectra measured in the range of the fundamental absorption (4-20 eV), it is shown that this difference manifests itself in relaxation of electronic excitations and may be the cause of the relatively low light yield of MgWO4.

  17. The morphology-dependent photocatalysis for rhodamine B degradation over Bi2WO6 hierarchical nanostructure.

    PubMed

    Tian, Yue; Fang, Ming; Xu, Wei; Li, Nian; Chen, Yongzhou; Zhang, Lide

    2011-09-01

    In this paper, the nanostructured Bi2WO6 with different hierarchical morphologies was synthesized via a warmly hydrothermal route. The structure and morphology of the as-prepared Bi2WO6 products were characterized by X-ray diffraction (XRD), field emission scanning electron microscope (FE-SEM), UV-vis absorption spectroscopy (UV-Vis) and N2-sorption analysis. The photocatalytic efficiency of Bi2WO6 was investigated by photodegradation of rhodamine B (RhB) under visible-light irradiation. The present work demonstrated that Bi2WO6 with four different hierarchical structures was effective visible-light-driven photocatalytic functional material for environmental purification. Moreover, the nest-like Bi2WO6 exhibited superior photocatalytic effects on rhodamine B degradation compared with other three Bi2WO6 morphologies. The excellent catalytic effect of the nest-like Bi2WO6 was attributed to its unique structural property and large surface area. The relationship between morphology and photocatalytic performance was discussed in detail. The photocatalytic mechanism for the degradation of RhB was also investigated, which revealed the important role of morphology in improving the photocatalyitc activities of Bi2WO6.

  18. Sunlight highly photoactive Bi2WO6-TiO2 heterostructures for rhodamine B degradation.

    PubMed

    Colón, G; Murcia López, S; Hidalgo, M C; Navío, J A

    2010-07-14

    Highly efficient Bi(2)WO(6)-TiO(2) heterostructures are synthesized by means of a hydrothermal method; they have high photoactivity for the degradation of rhodamine B under sunlike irradiation. An interesting synergetic effect between TiO(2) and Bi(2)WO(6) leads to an improved charge carrier separation mechanism, causing the excellent photocatalytic performance.

  19. Enhanced visible light photocatalytic activity of Bi2WO6 via modification with polypyrrole

    NASA Astrophysics Data System (ADS)

    Duan, Fang; Zhang, Qianhong; Shi, Dongjian; Chen, Mingqing

    2013-03-01

    Enhanced visible light photocatalytic activity of Bi2WO6 photocatalyst modified with different amounts of polypyrrole (PPy) was synthesized by 'in situ' deposition oxidative polymerization of pyrrole. The as-prepared PPy/Bi2WO6 composites were characterized by X-ray powder diffraction (XRD), field emission scanning electron microscopy (FE-SEM), Fourier transform infrared (FT-IR) spectra, X-ray photoelectron spectroscopy (XPS) and UV-vis diffuse absorption spectra. The photocatalytic activities of the PPy/Bi2WO6 samples were determined by photocatalytic degradation of rhodamine-B (RhB) and methylene blue (MB) in aqueous solution under visible light irradiation. The results indicated that the existence of PPy did not affect the crystal structure and the morphology of Bi2WO6 photocatalyst, but showed great influences on the photocatalytic activity of Bi2WO6. Besides, an optimal content of PPy on the surface of Bi2WO6 photocatalyst with the highest photocatalytic ability was discovered, and the obtained PPy/Bi2WO6 photocatalysts showed high stability and did not photocorrode during the photocatalytic process. The possible mechanism of enhanced photocatalytic activities of PPy/Bi2WO6 samples was also discussed in this work.

  20. 3D graphene network@WO3 nanowire composites: a multifunctional colorimetric and electrochemical biosensing platform.

    PubMed

    Ma, Ye; Zhao, Minggang; Cai, Bin; Wang, Wei; Ye, Zhizhen; Huang, Jingyun

    2014-10-01

    A three dimensional graphene network (3DGN)@WO3 nanowire (NW) sensor is proposed which can perform colorimetric and electrochemical sensing techniques to detect H2O2, ascorbic acid and dopamine. The 3DGN provides three functions: anchoring, separating, conducting, while the WO3 NWs maximize surface area and catalyse reactions.

  1. Correlation between surface chemistry, density and band gap in nanocrystalline WO3 thin films

    SciTech Connect

    Vemuri, Venkata Rama Ses; Engelhard, Mark H.; Ramana, C.V.

    2012-03-01

    Nanocrystalline WO3 thin films were produced by sputter-deposition by varying the ratio of argon to oxygen in the reactive gas mixture during deposition. The surface chemistry, physical characteristics, and optical properties of nanocrystalline WO3 films were evaluated using X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), atomic force microscopy (AFM), X-ray reflectivity (XRR), and spectrophotometric measurements. The effect of ultra-microstructure was significant on the optical properties of WO3 films. The XPS analyses indicate the formation of stoichiometric WO3 with tungsten existing in fully oxidized valence state (W6+). However, WO3 films grown at high oxygen concentration (>60%) in the sputtering gas mixture were over stoichiometric with excess oxygen. XRR simulations, which are based on isotropic WO3 film - SiO2 interface - Si substrate model, indicate that the density of WO3 films is sensitive to the oxygen content in the sputtering gas. The spectral transmission of the films increased with the increasing oxygen. The band gap of these films increases from 2.78 eV to 3.25 eV with increasing oxygen. A direct correlation between the film-density and band gap in nanocrystalline WO3 films is established based on the observed results.

  2. Optical properties of WO{sub 3} thin films using surface plasmon resonance technique

    SciTech Connect

    Paliwal, Ayushi; Sharma, Anjali; Gupta, Vinay E-mail: vgupta@physics.du.ac.in; Tomar, Monika

    2014-01-28

    Indigenously assembled surface plasmon resonance (SPR) technique has been exploited to study the thickness dependent dielectric properties of WO{sub 3} thin films. WO{sub 3} thin films (80 nm to 200 nm) have been deposited onto gold (Au) coated glass prism by sputtering technique. The structural, optical properties and surface morphology of the deposited WO{sub 3} thin films were studied using X-ray diffraction, UV-visible spectrophotometer, Raman spectroscopy, and Scanning electron microscopy (SEM). XRD analysis shows that all the deposited WO{sub 3} thin films are exhibiting preferred (020) orientation and Raman data indicates that the films possess single phase monoclinic structure. SEM images reveal the variation in grain size with increase in thickness. The SPR reflectance curves of the WO{sub 3}/Au/prism structure were utilized to estimate the dielectric properties of WO{sub 3} thin films at optical frequency (λ = 633 nm). As the thickness of WO{sub 3} thin film increases from 80 nm to 200 nm, the dielectric constant is seen to be decreasing from 5.76 to 3.42, while the dielectric loss reduces from 0.098 to 0.01. The estimated value of refractive index of WO{sub 3} film is in agreement to that obtained from UV-visible spectroscopy studies. The strong dispersion in refractive index is observed with wavelength of incident laser light.

  3. Effect of Bisphenol A on invasion ability of human trophoblastic cell line BeWo

    PubMed Central

    Wang, Zi-Yi; Lu, Jing; Zhang, Yuan-Zhen; Zhang, Ming; Liu, Teng; Qu, Xin-Lan

    2015-01-01

    Bisphenol A (BPA) is a kind of environmental endocrine disruptors (EEDs) that interfere embryo implantation. Trophoblast invasion plays a crucial role during embryo implantation. In this study, the effects of BPA on invasion ability of human trophoblastic cell line BeWo and its possible mechanism were investigated. BeWo cells were exposed to BPA and co-cultured with human endometrial cells to mimic embryo implantation in transwell model. The proliferation and invasion capability of BeWo cells were detected. The expression of E-cadherin, DNMT1, MMP-2, MMP-9, TIMP-1 and TIMP-2 were also analyzed. The results showed that the invasion capability of BeWo was reduced after daily exposure to BPA. BPA had biphasic effect on E-cadherin expression level in BeWo cells and expression level of DNMT1 was decreased when treated with BPA. Moreover, BPA treatment also changed the balance of MMPs/TIMPs in BeWo cells by down-regulating MMP-2, MMP-9 and up-regulating TIMP-1, TIMP-2 with increasing BPA concentration. Taken together, these results showed that BPA treatment could reduce the invasion ability of BeWo cells and alter the expression level of E-cadherin, DNMT1, TIMP-1, TIMP-2, MMP-2, and MMP-9. Our study would help us to understand the possible mechanism of BPA effect on invasion ability of human trophoblastic cell line BeWo. PMID:26823751

  4. Lithium-titanate-nanotube-supported WO3 for enhancing transmittance contrast in electrochromics

    NASA Astrophysics Data System (ADS)

    Dong, Yunbing; Xiong, Chunrong; Zhang, Yilu; Xing, Shuai; Jiang, Hong

    2016-03-01

    Lithium titanate nanotubes (Li-TNTs) have been successfully synthesized. The inner and outer diameters of the nanotubes are 5 nm and 8 nm with an interlayer spacing of 0.83 nm. The nanotubes were in accordance with the Li1.81H0.19Ti2O5 · xH2O phase. The chemical component was Li0.9H1.1Ti2O5 · H2O as determined by ICP-AES. The Li-TNT-supported WO3 nanoparticle (WO3/Li-TNTs) thin film was prepared onto ITO glass via spin-coating and then fabricated with an electrochromic device. The Li ion diffusion coefficient in the WO3/Li-TNT film was 6.1 × 10-10 cm2 s-1, which is eight times higher than that for the pure WO3 film. The transmittance contrast of the pure WO3-based ECD was 53.3% at 600 nm. However, this increased to 74.1% for the WO3/Li-TNT-based ECD. Meanwhile, the color-switching times of the WO3/Li-TNT-based ECD were apparently shorter than the ones for the WO3-based ECD.

  5. Strain Accommodation By Facile WO6 Octahedral Distortion and Tilting During WO3 Heteroepitaxy on SrTiO3(001)

    SciTech Connect

    Du, Yingge; Gu, Meng; Varga, Tamas; Wang, Chong M.; Bowden, Mark E.; Chambers, Scott A.

    2014-08-27

    In this paper, we show that compared to other BO6 octahedra in ABO3 structured perovskite oxides, the WO6 octahedra in tungsten trioxide (WO3) can withstand a much larger degree of distortion and tilting to accommodate interfacial strain, which in turn strongly impact the nucleation, structure, and defect formation during the epitaxial growth of WO3 on SrTiO3(001). A meta-stable tetragonal phase can be stabilized by epitaxy and a thickness dependent phase transition (tetragonal to monoclinic) is observed. In contrast to misfit dislocations to accommodate the interfacial stain, the facial WO6 octahedral distortion and tilting give rise to three types of planar defects that affect more than 15 monolayers from the interface. These atomically resolved, unusual interfacial defects may significantly alter the electronic, electrochromic, and mechanical properties of the epitaxial films.

  6. US Coast Guard GPS Information Center (GPSIC) and its function within the Civil GPS Service (CGS)

    NASA Technical Reports Server (NTRS)

    1993-01-01

    In 1987, the U.S. Department of Defense (DOD) formally requested that the U.S. Department of Transportation (DOT) take responsibility for providing an office that would respond to nonmilitary user needs for GPS information, data, and assistance. DOT accepted this responsibility and in February 1989, named the Coast Guard as their lead agency for the project. Since that time, the U.S. Coast Guard has worked with the U.S. Space Command to develop requirements and implement a plan for providing the requested interface with the civil GPS community. The Civil GPS Service (CGS) consists of four main elements: GPS Information Center (GPSIC) - provides GPS status information to civilian users of the system: Civil GPS Service Interface Committee (CGSIC) - established to identify civil GPS user technical information needs in support of the CGS program; Differential GPS (DGPS) - Coast Guard Research and Development Project; and PPS Program Office (PPSPO) - (Under development) will administer the program allowing qualified civil users to have access to the PPS signal. Details about the services these organizations provide are described.

  7. The International GPS Service (IGS) as a Continuous Reference System for Precise GPS Positioning

    NASA Technical Reports Server (NTRS)

    Neilan, Ruth; Heflin, Michael; Watkins, Michael; Zumberge, James

    1996-01-01

    The International GPS Service for Geodynamics (IGS) is an organization which operates under the auspices of the International Association of Geodesy (IAG) and has been operational since January 1994. The primary objective of the IGS is to provide precise GPS data and data products to support geodetic and geophysical research activities.

  8. Photoelectrochemical behavior of hierarchically structured Si/WO3 core-shell tandem photoanodes.

    PubMed

    Coridan, Robert H; Arpin, Kevin A; Brunschwig, Bruce S; Braun, Paul V; Lewis, Nathan S

    2014-05-14

    WO3 thin films have been deposited in a hierarchically structured core-shell morphology, with the cores consisting of an array of Si microwires and the shells consisting of a controlled morphology WO3 layer. Porosity was introduced into the WO3 outer shell by using a self-assembled microsphere colloidal crystal as a mask during the deposition of the WO3 shell. Compared to conformal, unstructured WO3 shells on Si microwires, the hierarchically structured core-shell photoanodes exhibited enhanced near-visible spectral response behavior, due to increased light absorption and reduced distances over which photogenerated carriers were collected. The use of structured substrates also improved the growth rate of microsphere-based colloidal crystals and suggests strategies for the use of colloidal materials in large-scale applications.

  9. Ethanol sensing of SnO2-WO3 core/shell nanowires

    NASA Astrophysics Data System (ADS)

    Park, Sunghoon; Kim, Soohyun; Sun, Gun-Joo; Choi, Seung-Bok; Lee, Sangmin; Lee, Chongmu

    2015-09-01

    SnO2-WO3 core/shell nanowires were synthesized by the thermal evaporation of Sn powders in an oxidizing ambient followed by the thermal evaporation of WO3 powders. Their C2H5OH gas sensing properties were then examined. The C2H5OH gas sensing properties were improved remarkably by formation of the SnO2-WO3 heterostructures. The SnO2-WO3 core/shell nanowire sensors showed a much stronger and faster response to C2H5OH gas than the pristine SnO2-nanowire sensors. The enhanced sensing performance of the SnO2-WO3 core/shell nanowires towards C2H5OH gas can be accounted for by the potential barrier-controlled carrier-transport mechanism combined with the surface-depletion mechanism. [Figure not available: see fulltext.

  10. GPS Space Service Volume: Ensuring Consistent Utility Across GPS Design Builds for Space Users

    NASA Technical Reports Server (NTRS)

    Bauer, Frank H.; Parker, Joel Jefferson Konkl; Valdez, Jennifer Ellen

    2015-01-01

    GPS availability and signal strength originally specified for users on or near surface of Earth with transmitted power levels specified at edge-of-Earth, 14.3 degrees. Prior to the SSV specification, on-orbit performance of GPS varied from block build to block build (IIA, IIRM, IIF) due to antenna gain and beam width variances. Unstable on-orbit performance results in significant risk to space users. Side-lobe signals, although not specified, were expected to significantly boost GPS signal availability for users above the constellation. During GPS III Phase A, NASA noted significant discrepancies in power levels specified in GPS III specification documents, and measured on-orbit performance. To stabilize the signal for high altitude space users, NASA DoD team in 2003-2005 led the creation of new Space Service Volume (SSV) definition and specifications.

  11. MWCNT/WO{sub 3} nanocomposite photoanode for visible light induced water splitting

    SciTech Connect

    Yousefzadeh, Samira; Reyhani, Ali; Naseri, Naimeh; Moshfegh, Alireza Z.

    2013-08-15

    The Multi-walled carbon nanotube (MWCNT)/WO{sub 3} nanocomposite thin films with different MWCNT’s weight percentages were prepared by sol–gel method as visible light induced photoanode in water splitting reaction. Weight percentage of MWCNT in the all nanocomposite thin films was confirmed by TGA/DSC analysis. According to XPS analysis, oxygenated groups at the surface of the MWCNT and stoichiometric formation of WO{sub 3} thin films were determined, while the crystalline structure of the nanocomposite samples was studied by XRD indicating (0 0 2) peak of MWCNT in the monoclinic phase of WO{sub 3}. The influence of different weight percentage (wt%) of MWCNT on WO{sub 3} photoactivity showed that the electron conductivity, charge transfer and electron life time had improved as compared with the pure WO{sub 3}. Based on linear sweep voltammetry and chronoamperometry measurements, the (1 wt%) MWCNT/WO{sub 3} nanocomposite thin films photoanode has a maximum photocurrent density of ∼4.5 A/m{sup 2} and electron life time of about 57 s. - Graphical abstract: Photocurrent density versus time at constant potential (0.7 V) for the WO{sub 3} films containing different MWCNT weight percentages annealed at 400 °C under 1000 Wm{sup −2} visible photo-illumination. Display Omitted - Highlights: • MWCNT/ WO{sub 3} nanocomposite thin films were synthesized using sol–gel derived method. • TGA/DSC confirmed the weight percentage of MWCNT in the all nanocomposite thin films. • XPS analysis revealed that WO{sub 3} was attached on the oxygenated group of MWCNT surface. • The Highest Photoelectrochemical activity is achieved for (1 wt%)MWCNT/WO{sub 3} thin film.

  12. Very long-period GPS waveforms. What can GPS bring to Earth seismic velocity models?

    NASA Astrophysics Data System (ADS)

    Kelevitz, K.; Houlie, N.; Nissen-Meyer, T.; Boschi, L.; Giardini, D.; Rothacher, M.

    2014-12-01

    It is now admitted that high rate GPS observations can provide reliable surface displacement waveforms. For long-period (T > 5s) transients, it was shown that GPS and seismometer (STS-1) displacements are in agreement at least for vertical component [Houlié et al., 2011]. We propose here to supplement existing long-period seismic networks with high rate (>= 1Hz) GPS data in order to improve the resolution of global seismic velocity models. We aim at extending the use of GPS measurements beyond the range of STS-1 in the low frequency end (T>1000s). We present the results of the processing of 1Hz GPS records of the Hokkaido, Sumatra and Tohoku earthquakes (25th of September, 2003, Mw = 8.3; 26th of December, 2004, Mw = 8.9; 11th of March, 2011, Mw = 9.1, respectively). 3D waveforms phase time-series have been used to recover the ground motion histories at the GPS sites. Through the better resolution of inversion of the GPS phase observations, we determine displacement waveforms of periods ranging from 30 seconds to 1300 seconds for a selection of sites. We compare inverted GPS waveforms with STS-1 waveforms, superconducting gravity waveforms and synthetic waveforms computed using 3D global wave propagation with SPECFEM. We find that the GPS waveforms are in agreement with the SPECFEM synthetic data and are able to fill the period-gap between the broadband seismometer STS-1 data and the normal mode period range detected by the superconducting gravimeters. References: Houlié, N., G. Occhipinti, T. Blanchard, N. Shapiro, P. Lognonne, and M. Murakami (2011), New approach to detect seismic surface waves in 1Hz-sampled GPS time series, Scientific reports, 1, 44.

  13. Epitaxial growth of high quality WO3 thin films

    DOE PAGES

    Leng, X.; Pereiro, J.; Strle, J.; Bollinger, A. T.; Bozovic, I.

    2015-09-09

    We have grown epitaxial WO3 films on various single-crystal substrates using radio-frequency (RF) magnetron sputtering. While pronounced surface roughness is observed in films grown on LaSrAlO4 substrates, films grown on YAlO3 substrates show atomically flat surfaces, as demonstrated by atomic force microscopy (AFM) and X-ray diffraction (XRD) measurements. The crystalline structure has been confirmed to be monoclinic by symmetric and skew-symmetric XRD. Furthermore, the dependence of the growth modes and the surface morphology on the lattice mismatch is discussed.

  14. Epitaxial growth of high quality WO3 thin films

    NASA Astrophysics Data System (ADS)

    Leng, X.; Pereiro, J.; Strle, J.; Bollinger, A. T.; Božović, I.

    2015-09-01

    We have grown epitaxial WO3 films on various single-crystal substrates using radio frequency magnetron sputtering. While pronounced surface roughness is observed in films grown on LaSrAlO4 substrates, films grown on Y AlO3 substrates show atomically flat surfaces, as demonstrated by atomic force microscopy and X-ray diffraction (XRD) measurements. The crystalline structure has been confirmed to be monoclinic by symmetric and skew-symmetric XRD. The dependence of the growth modes and the surface morphology on the lattice mismatch are discussed.

  15. Uav Onboard GPS in Positioning Determination

    NASA Astrophysics Data System (ADS)

    Tahar, K. N.; Kamarudin, S. S.

    2016-06-01

    The establishment of ground control points is a critical issue in mapping field, especially for large scale mapping. The fast and rapid technique for ground control point's establishment is very important for small budget projects. UAV onboard GPS has the ability to determine the point positioning. The objective of this research is to assess the accuracy of unmanned aerial vehicle onboard global positioning system in positioning determination. Therefore, this research used UAV onboard GPS as an alternative to determine the point positioning at the selected area. UAV is one of the powerful tools for data acquisition and it is used in many applications all over the world. This research concentrates on the error contributed from the UAV onboard GPS during observation. There are several points that have been used to study the pattern of positioning error. All errors were analyzed in world geodetic system 84- coordinate system, which is the basic coordinate system used by the global positioning system. Based on this research, the result of UAV onboard GPS positioning could be used in ground control point establishment with the specific error. In conclusion, accurate GCP establishment could be achieved using UAV onboard GPS by applying a specific correction based on this research.

  16. Physical applications of GPS geodesy: a review.

    PubMed

    Bock, Yehuda; Melgar, Diego

    2016-10-01

    Geodesy, the oldest science, has become an important discipline in the geosciences, in large part by enhancing Global Positioning System (GPS) capabilities over the last 35 years well beyond the satellite constellation's original design. The ability of GPS geodesy to estimate 3D positions with millimeter-level precision with respect to a global terrestrial reference frame has contributed to significant advances in geophysics, seismology, atmospheric science, hydrology, and natural hazard science. Monitoring the changes in the positions or trajectories of GPS instruments on the Earth's land and water surfaces, in the atmosphere, or in space, is important for both theory and applications, from an improved understanding of tectonic and magmatic processes to developing systems for mitigating the impact of natural hazards on society and the environment. Besides accurate positioning, all disturbances in the propagation of the transmitted GPS radio signals from satellite to receiver are mined for information, from troposphere and ionosphere delays for weather, climate, and natural hazard applications, to disturbances in the signals due to multipath reflections from the solid ground, water, and ice for environmental applications. We review the relevant concepts of geodetic theory, data analysis, and physical modeling for a myriad of processes at multiple spatial and temporal scales, and discuss the extensive global infrastructure that has been built to support GPS geodesy consisting of thousands of continuously operating stations. We also discuss the integration of heterogeneous and complementary data sets from geodesy, seismology, and geology, focusing on crustal deformation applications and early warning systems for natural hazards. PMID:27552205

  17. Physical applications of GPS geodesy: a review.

    PubMed

    Bock, Yehuda; Melgar, Diego

    2016-10-01

    Geodesy, the oldest science, has become an important discipline in the geosciences, in large part by enhancing Global Positioning System (GPS) capabilities over the last 35 years well beyond the satellite constellation's original design. The ability of GPS geodesy to estimate 3D positions with millimeter-level precision with respect to a global terrestrial reference frame has contributed to significant advances in geophysics, seismology, atmospheric science, hydrology, and natural hazard science. Monitoring the changes in the positions or trajectories of GPS instruments on the Earth's land and water surfaces, in the atmosphere, or in space, is important for both theory and applications, from an improved understanding of tectonic and magmatic processes to developing systems for mitigating the impact of natural hazards on society and the environment. Besides accurate positioning, all disturbances in the propagation of the transmitted GPS radio signals from satellite to receiver are mined for information, from troposphere and ionosphere delays for weather, climate, and natural hazard applications, to disturbances in the signals due to multipath reflections from the solid ground, water, and ice for environmental applications. We review the relevant concepts of geodetic theory, data analysis, and physical modeling for a myriad of processes at multiple spatial and temporal scales, and discuss the extensive global infrastructure that has been built to support GPS geodesy consisting of thousands of continuously operating stations. We also discuss the integration of heterogeneous and complementary data sets from geodesy, seismology, and geology, focusing on crustal deformation applications and early warning systems for natural hazards.

  18. GPS Remote Sensing Measurements Using Aerosonde UAV

    NASA Technical Reports Server (NTRS)

    Grant, Michael S.; Katzberg, Stephen J.; Lawrence, R. W.

    2005-01-01

    In February 2004, a NASA-Langley GPS Remote Sensor (GPSRS) unit was flown on an Aerosonde unmanned aerial vehicle (UAV) from the Wallops Flight Facility (WFF) in Virginia. Using direct and surface-reflected 1.575 GHz coarse acquisition (C/A) coded GPS signals, remote sensing measurements were obtained over land and portions of open water. The strength of the surface-reflected GPS signal is proportional to the amount of moisture in the surface, and is also influenced by surface roughness. Amplitude and other characteristics of the reflected signal allow an estimate of wind speed over open water. In this paper we provide a synopsis of the instrument accommodation requirements, installation procedures, and preliminary results from what is likely the first-ever flight of a GPS remote sensing instrument on a UAV. The correct operation of the GPSRS unit on this flight indicates that Aerosonde-like UAV's can serve as platforms for future GPS remote sensing science missions.

  19. GPS/INS Enhancement for Land Navigation using Neural Network

    NASA Astrophysics Data System (ADS)

    Kaygisiz, Burak H.; Erkmen, Ismet; Erkmen, Aydan M.

    2004-05-01

    We propose in this paper a method to enhance the performance of a coupled global positioning/inertial navigation system (GPS/INS) for land navigation applications during GPS signal loss. Our method is based on the use of an artificial neural network (ANN) to intelligently aid the GPS/INS coupled navigation system in the absence of GPS signals. The proposed enhanced GPS/INS is tested in the dynamic environment of a land vehicle navigating around a closed path on the METU campus and we provide the results. Our GPS/INS+ANN system performance is thus demonstrated with a land trial.

  20. Ag loaded WO3 nanoplates for efficient photocatalytic degradation of sulfanilamide and their bactericidal effect under visible light irradiation.

    PubMed

    Zhu, Wenyu; Liu, Jincheng; Yu, Shuyan; Zhou, Yan; Yan, Xiaoli

    2016-11-15

    Sulfonamides (SAs) are extensively used antibiotics and their residues in the water bodies propose potential threat to the public. In this study, degradation efficiency of sulfanilamide (SAM), which is the precursor of SAs, using WO3 nanoplates and their Ag heterogeneous as photocatalysts was investigated. WO3 nanoplates with uniform size were synthesized by a facile one step hydrothermal method. Different amount of Ag nanoparticles (Ag NPs) were loaded onto WO3 nanoplates using a photo-reduction method to generate WO3/Ag composites. The physio-chemical properties of synthesized nanomaterials were systematically characterized. Photodegradation of SAM by WO3 and WO3/Ag composites was conducted under visible light irradiation. The results show that WO3/Ag composites performed much better than pure WO3 where the highest removal rate was 96.2% in 5h. Ag as excellent antibacterial agent also endows certain antibacterial efficiency to WO3, and 100% removal efficiency against Escherichia Coli and Bacillus subtilis could be achieved in 2h under visible light irradiation for all three WO3/Ag composites synthesized. The improved performance in terms of SAM degradation and antibacterial activity of WO3/Ag can be attributed to the improved electron-hole pair separation rate where Ag NPs act as effective electron trapper during the photocatalytic process. PMID:27450332

  1. Enhancement of visible-light photocatalytic activity of silver and mesoporous carbon co-modified Bi2WO6

    NASA Astrophysics Data System (ADS)

    Zhao, Qian; Gong, Ming; Liu, Wangping; Mao, Yulin; Le, Shukun; Ju, Shang; Long, Fei; Liu, Xiufang; Liu, Kai; Jiang, Tingshun

    2015-03-01

    Ordered mesoporous carbon CMK-3 was prepared by hard template method using SBA-15 as template, sucrose as carbon source. Flower/sphere-like Bi2WO6 and CMK-3/Bi2WO6 photocatalysts were synthesized by hydrothermal method, and then Ag/Bi2WO6 and Ag/Bi2WO6/CMK-3 composite photocatalysts were prepared via a photoreduction process. The samples were characterized by XRD, UV-vis, TEM (HR-TEM), SEM, N2 physical adsorption and PL and their photocatalytic activities were evaluated by the photocatalytic degradation of methylene blue (MB) under visible light irradiation. The results show that both incorporating of CMK-3 and Ag loading greatly improved the photocatalytic activity of Bi2WO6, and the content of CMK-3 and silver have an impact on the photocatalytic activity of Bi2WO6. The photocatalytic activity of Ag/Bi2WO6/CMK-3 photocatalyst is superior to the activities of CMK-3/Bi2WO6 and Ag/Bi2WO6 under comparable conditions, and Ag/Bi2WO6/CMK-3 photocatalyst has high stability and is easy to be recycled. Also, the mechanism for the enhancement of the photocatalytic activity of CMK-3 and Ag co-modified Bi2WO6 was also investigated.

  2. International GPS Service 2001 - 2002 Technical Reports

    NASA Technical Reports Server (NTRS)

    Gowey, Ken (Editor); Neilan, Ruth (Editor); Moore, Angelyn (Editor)

    2004-01-01

    Applications of the Global Positioning System (GPS) to Earth Science are numerous. The International GPS Service (IGS), a federation of government agencies and universities, plays an increasingly critical role in support of GPS-related research and engineering activities. Contributions from the IGS Governing Board and Central Bureau, analysis and data centers, station operators, and others constitute the 2001 / 2002 Technical Reports. Hard copies of each volume can be obtained by contacting the IGS Central Bureau at the Jet Propulsion Laboratory. This report is published in black and white. To view graphs or plots that use color to represent data trends or information, please refer to the online PDF version at http://igscb.jpl.nasa.gov/overview/pubs.html.

  3. US Coast Guard differential GPS network

    SciTech Connect

    Alsip, D.H.; Butler, J.M.; Radice, J.T.

    1993-03-01

    In order to aid navigation and to prevent disasters such as oil spills, collisions, and wrecks of vessels and aircraft, the US Coast Guard is charged with establishing, maintaining, and operating electronic aids to navigation. In a technological advance developed and operated by the Department of Defense, the global positioning system (GPS) provides all-weather global coverage, 24 hours/day at unprecedented accuracies. GPS provides standard positioning service (SPS) and precise positioning service (PPS). By applying differential techniques to GPS, navigational accuracies of better than 10 meters can be achieved. For the first time, an all-weather system is possible to meet all the marine navigator's needs including harbor and harbor approach navigation. This should revolutionize navigation safety and efficiency, surveying operations, search and rescue operations, and underwater mine disposal efficiency and safety.

  4. Airborne gravimetry, altimetry, and GPS navigation errors

    NASA Technical Reports Server (NTRS)

    Colombo, Oscar L.

    1992-01-01

    Proper interpretation of airborne gravimetry and altimetry requires good knowledge of aircraft trajectory. Recent advances in precise navigation with differential GPS have made it possible to measure gravity from the air with accuracies of a few milligals, and to obtain altimeter profiles of terrain or sea surface correct to one decimeter. These developments are opening otherwise inaccessible regions to detailed geophysical mapping. Navigation with GPS presents some problems that grow worse with increasing distance from a fixed receiver: the effect of errors in tropospheric refraction correction, GPS ephemerides, and the coordinates of the fixed receivers. Ionospheric refraction and orbit error complicate ambiguity resolution. Optimal navigation should treat all error sources as unknowns, together with the instantaneous vehicle position. To do so, fast and reliable numerical techniques are needed: efficient and stable Kalman filter-smoother algorithms, together with data compression and, sometimes, the use of simplified dynamics.

  5. GPS common-view time transfer

    NASA Technical Reports Server (NTRS)

    Lewandowski, W.

    1994-01-01

    The introduction of the GPS common-view method at the beginning of the 1980's led to an immediate and dramatic improvement of international time comparisons. Since then, further progress brought the precision and accuracy of GPS common-view intercontinental time transfer from tens of nanoseconds to a few nanoseconds, even with SA activated. This achievement was made possible by the use of the following: ultra-precise ground antenna coordinates, post-processed precise ephemerides, double-frequency measurements of ionosphere, and appropriate international coordination and standardization. This paper reviews developments and applications of the GPS common-view method during the last decade and comments on possible future improvements whose objective is to attain sub-nanosecond uncertainty.

  6. The GPS Topex/Poseidon precise orbit determination experiment - Implications for design of GPS global networks

    NASA Technical Reports Server (NTRS)

    Lindqwister, Ulf J.; Lichten, Stephen M.; Davis, Edgar S.; Theiss, Harold L.

    1993-01-01

    Topex/Poseidon, a cooperative satellite mission between United States and France, aims to determine global ocean circulation patterns and to study their influence on world climate through precise measurements of sea surface height above the geoid with an on-board altimeter. To achieve the mission science aims, a goal of 13-cm orbit altitude accuracy was set. Topex/Poseidon includes a Global Positioning System (GPS) precise orbit determination (POD) system that has now demonstrated altitude accuracy better than 5 cm. The GPS POD system includes an on-board GPS receiver and a 6-station GPS global tracking network. This paper reviews early GPS results and discusses multi-mission capabilities available from a future enhanced global GPS network, which would provide ground-based geodetic and atmospheric calibrations needed for NASA deep space missions while also supplying tracking data for future low Earth orbiters. Benefits of the enhanced global GPS network include lower operations costs for deep space tracking and many scientific and societal benefits from the low Earth orbiter missions, including improved understanding of ocean circulation, ocean-weather interactions, the El Nino effect, the Earth thermal balance, and weather forecasting.

  7. An updated GPS velocity field for Canada

    NASA Astrophysics Data System (ADS)

    Craymer, M. R.; Henton, J. A.; Piraszewski, M.; Lapelle, E.

    2011-12-01

    In an effort to improve previous continental-scale GPS velocity fields for North America and Canada in particular, we have reprocessed data from nearly all continuous GPS sites in Canada, the northern portions of the US including Alaska, Greenland as well as a set of global sites used to define the reference frame. In addition, repeated high accuracy campaign surveys of the Canadian Base Network were included. Previous velocity fields were derived from coordinate time series of somewhat inhomogeneous GPS results due to: (1) the use of relative antenna calibrations that did not include satellite antennas or account for the presence of antenna radomes, (2) the use of different reference frames, (3) the use of IGS precise orbits based on these calibrations and reference frames, and (4) the use of different (evolving) versions of GPS processing software and procedures. This reprocessing effort of all previous data since 2000 is based on more consistent and accurate absolute antenna calibrations of both station and satellite antennas, the ITRF2005 reference frame and the latest versions of the Bernese GPS Software and IGS processing procedures with their so-called "repro1" reprocessed orbits. Also, more than four additional years of continuous data and a new CBN survey campaign have been included in this velocity field estimation. Furthermore, we have processed all the continuous data with NRCan's Precise Point Positioning (PPP) software using the same IGS repro1 orbits, precise clocks and absolute antenna calibrations together with the Vienna Mapping Function (VMF1) for the tropospheric model. The PPP software has proven to be highly efficient for processing such large networks and the additional solutions have provided much needed redundancy for some regions. The new time series and velocity results from both the Bernese and PPP solutions are compared with each other and with our previous solution. Comparisons are also made with solutions from other GPS analysis

  8. Single-Receiver GPS Phase Bias Resolution

    NASA Technical Reports Server (NTRS)

    Bertiger, William I.; Haines, Bruce J.; Weiss, Jan P.; Harvey, Nathaniel E.

    2010-01-01

    Existing software has been modified to yield the benefits of integer fixed double-differenced GPS-phased ambiguities when processing data from a single GPS receiver with no access to any other GPS receiver data. When the double-differenced combination of phase biases can be fixed reliably, a significant improvement in solution accuracy is obtained. This innovation uses a large global set of GPS receivers (40 to 80 receivers) to solve for the GPS satellite orbits and clocks (along with any other parameters). In this process, integer ambiguities are fixed and information on the ambiguity constraints is saved. For each GPS transmitter/receiver pair, the process saves the arc start and stop times, the wide-lane average value for the arc, the standard deviation of the wide lane, and the dual-frequency phase bias after bias fixing for the arc. The second step of the process uses the orbit and clock information, the bias information from the global solution, and only data from the single receiver to resolve double-differenced phase combinations. It is called "resolved" instead of "fixed" because constraints are introduced into the problem with a finite data weight to better account for possible errors. A receiver in orbit has much shorter continuous passes of data than a receiver fixed to the Earth. The method has parameters to account for this. In particular, differences in drifting wide-lane values must be handled differently. The first step of the process is automated, using two JPL software sets, Longarc and Gipsy-Oasis. The resulting orbit/clock and bias information files are posted on anonymous ftp for use by any licensed Gipsy-Oasis user. The second step is implemented in the Gipsy-Oasis executable, gd2p.pl, which automates the entire process, including fetching the information from anonymous ftp

  9. A GPS Receiver for Lunar Missions

    NASA Technical Reports Server (NTRS)

    Bamford, William A.; Heckler, Gregory W.; Holt, Greg N.; Moreau, Michael C.

    2008-01-01

    Beginning with the launch of the Lunar Reconnaissance Orbiter (LRO) in October of 2008, NASA will once again begin its quest to land humans on the Moon. This effort will require the development of new spacecraft which will safely transport people from the Earth to the Moon and back again, as well as robotic probes tagged with science, re-supply, and communication duties. In addition to the next-generation spacecraft currently under construction, including the Orion capsule, NASA is also investigating and developing cutting edge navigation sensors which will allow for autonomous state estimation in low Earth orbit (LEO) and cislunar space. Such instruments could provide an extra layer of redundancy in avionics systems and reduce the reliance on support and on the Deep Space Network (DSN). One such sensor is the weak-signal Global Positioning System (GPS) receiver "Navigator" being developed at NASA's Goddard Space Flight Center (GSFC). At the heart of the Navigator is a Field Programmable Gate Array (FPGA) based acquisition engine. This engine allows for the rapid acquisition/reacquisition of strong GPS signals, enabling the receiver to quickly recover from outages due to blocked satellites or atmospheric entry. Additionally, the acquisition algorithm provides significantly lower sensitivities than a conventional space-based GPS receiver, permitting it to acquire satellites well above the GPS constellation. This paper assesses the performance of the Navigator receiver based upon three of the major flight regimes of a manned lunar mission: Earth ascent, cislunar navigation, and entry. Representative trajectories for each of these segments were provided by NASA. The Navigator receiver was connected to a Spirent GPS signal generator, to allow for the collection of real-time, hardware-in-the-loop results for each phase of the flight. For each of the flight segments, the Navigator was tested on its ability to acquire and track GPS satellites under the dynamical

  10. Improving the orbits of eclipsing GPS satellites

    NASA Astrophysics Data System (ADS)

    Rodriguez Solano, Carlos Javier; Hugentobler, Urs; Steigenberger, Peter; Allende Alba, Gerardo

    2013-04-01

    The orbits of GPS satellites show a lower performance during Sun-Earth eclipse seasons than during periods outside these seasons. In particular the orbits of GPS II and IIA satellites are worse during eclipses, while GPS IIR satellite orbits are almost unaffected. The cause of this problem is the non-nominal yaw attitude of the satellites during eclipses, i.e., the yaw maneuvers performed at noon, shadow and post-shadow. If the yaw maneuvers are not properly taken into account, two effects appear: 1) the phase measurements are degraded since the modelled position of the satellite's navigation antenna differs from the true position, and 2) the non-conservative forces like solar radiation pressure and Earth radiation pressure are mismodelled due to the wrong orientation of the satellite's surfaces in space. In this study, we introduce the yaw maneuver information available from models in the computation of solar radiation pressure and Earth radiation pressure acting on a box-wing like satellite. Also the computation of the satellite's navigation antenna position takes into account the yaw maneuver models. The improvement of GPS satellite orbits during eclipse seasons is quantified in terms of orbit predictions after 6 hours and after 4 days for all GPS satellites during 2007 and 2008. Already the use of the currently available yaw maneuver models, with nominal hardware yaw rates, shows an important improvement when combined with our box-wing model. In addition, we have estimated the real hardware yaw rates from PPP residuals and use this information for orbit prediction, obtaining an additional improvement in the orbits of GPS II and IIA satellites during eclipse seasons.

  11. Electrochromic Characterization of Electrodeposited WO3 Thin Films

    NASA Astrophysics Data System (ADS)

    Vijayalakshmi, R.; Jayachandran, M.; Sanjeeviraja, C.

    2002-12-01

    The electrochromic properties of certain transition metal oxides have been studied for several years resulting in commercial films are deposited as thin layers (0.1 to 0.4 microns) onto a transparent conductive automotive mirror and sun-glass products. The largest potential application of electrochromics is in window to regulate heat and light flow. Fabrication cost is one of the greatest barriers for large area development of the smart windows. Tungsten trioxide (WO3) can be colored deeply in with an optical irradiation of appropriate energy (photochromism) or with an applied electric field (electrochromism). These processes have received considerable attention because of their potential application in electrochromic windows, display devices, sensors, and so on. For these purposes, tungsten trioxide films prepared by various physical methods such as molecular beam epitaxy, CVD, etc have been reported. These methods are generally expensive and it is difficult to form large area films. However electrodeposition method is probably most economical method for making the films in addition to its relative ease in forming in large area films. In this paper, tungsten trioxide (WO3) films are prepared through the electrodeposition route and these films are used to study the electrochromic behavior in the various electrolytes by changing the concentrations. When coloration, the film attains deep blue color and in reduced state it becomes colorless. After the ion intercalation, the optical properties are also studied in the UV-Vis-NIR region.

  12. Pickering w/o emulsions: drug release and topical delivery.

    PubMed

    Frelichowska, Justyna; Bolzinger, Marie-Alexandrine; Valour, Jean-Pierre; Mouaziz, Hanna; Pelletier, Jocelyne; Chevalier, Yves

    2009-02-23

    The skin absorption from Pickering emulsions as a new dosage form was investigated for the first time. Pickering emulsions are stabilized by adsorbed solid particles instead of emulsifier molecules. They are promising dosage forms that significantly differ from classical emulsions within several features. The skin permeation of a hydrophilic model penetrant (caffeine) was investigated from a w/o Pickering emulsion and compared to a w/o classical emulsion stabilized with an emulsifier. Both emulsions had the same composition and physicochemical properties in order to focus on the effect of the interfacial layer on the drug release and skin absorption processes. The highest permeation rates were obtained from the Pickering emulsion with a pseudo-steady state flux of 25 microg cm(-2)h(-1), threefold higher than from a classical emulsion (9.7 microg cm(-2)h(-1)). After 24h exposure, caffeine was mostly in the receptor fluid and in the dermis; cumulated amounts of caffeine were higher for the Pickering emulsion. Several physicochemical phenomena were investigated for clearing up the mechanisms of enhanced permeation from the Pickering emulsion. Among them, higher adhesion of Pickering emulsion droplets to skin surface was disclosed. The transport of caffeine adsorbed on silica particles was also considered relevant since skin stripping showed that aggregates of silica particles entered deeply the stratum corneum.

  13. A Bridge Deflection Monitoring with GPS

    NASA Astrophysics Data System (ADS)

    Figurski, M.; Gałuszkiewicz, M.; Wrona, M.

    2007-01-01

    This paper introduces results of investigation carried on by The Applied Geomatics Section in Military University of Technology. Research includes possibilities of monitoring dynamic behavior of a bridge using high rate GPS data. Whole event was executed with collaboration of The Road and Bridge Management and The Warsaw Geodesy Company. Interdisciplinary approach with this project allows authors to get reliable information about investigating constructions and their respond for true traffic loading detected by GPS receivers. Way of compute data and used software (TRACK) are also shown in this paper.

  14. Investigation on Tidal Components in GPS Coordinates

    NASA Astrophysics Data System (ADS)

    Araszkiewicz, Andrzej; Bogusz, Janusz; Figurski, Mariusz

    2009-01-01

    This paper presents analyses on the GPS coordinates from sub-diurnal solutions of EPN data provided by Warsaw Military University of Technology. The aim of this research is to investigate the way the tidal models used in Bernese software (solid Earth and ocean tides as well) fit to the individual conditions of EPN stations. The 1-hour solution technique of GPS data processing was utilized to obtain coordinates of above 70 EPN stations. Additionally several Polish permanent sites with clearly seen oscillations were examined. This processing technique allowed us to recognize diurnal and sub-diurnal residual oscillations which could be next utilized for validation of the tidal models.

  15. Dual RF Astrodynamic GPS Orbital Navigator Satellite

    NASA Technical Reports Server (NTRS)

    Kanipe, David B.; Provence, Robert Steve; Straube, Timothy M.; Reed, Helen; Bishop, Robert; Lightsey, Glenn

    2009-01-01

    Dual RF Astrodynamic GPS Orbital Navigator Satellite (DRAGONSat) will demonstrate autonomous rendezvous and docking (ARD) in low Earth orbit (LEO) and gather flight data with a global positioning system (GPS) receiver strictly designed for space applications. ARD is the capability of two independent spacecraft to rendezvous in orbit and dock without crew intervention. DRAGONSat consists of two picosatellites (one built by the University of Texas and one built by Texas A and M University) and the Space Shuttle Payload Launcher (SSPL); this project will ultimately demonstrate ARD in LEO.

  16. GPS for large-scale aerotriangulation

    NASA Astrophysics Data System (ADS)

    Rogowksi, Jerzy B.

    The application of GPS (Global Positioning System) measurements to photogrammetry is presented. The technology of establishment of a GPS network for aerotriangulation as a base for mapping at scales from 1:1000 has been worked out at the Institute of Geodesy and Geodetical Astronomy of the Warsaw University of Technology. This method consists of the design, measurement, and adjustment of this special network. The results of several pilot projects confirm the possibility of improving the aerotriangulation accuracy. A few-centimeter accuracy has been achieved.

  17. PTTI applications at the limits of GPS

    NASA Technical Reports Server (NTRS)

    Douglas, Rob J.; Popelar, J.

    1995-01-01

    Canadian plans for precise time and time interval services are examined in the light of GPS capabilities developed for geodesy. We present our experience in establishing and operating a geodetic type GPS station in a time laboratory setting, and show sub-nanosecond residuals for time transfer between geodetic sites. We present our approach to establishing realistic standard uncertainties for short-term frequency calibration services over time intervals of hours, and for longer-term frequency dissemination at better than the 10(exp -15) level of accuracy.

  18. Tungsten oxide (WO{sub 3}) thin films for application in advanced energy systems

    SciTech Connect

    Gullapalli, S. K.; Vemuri, R. S.; Manciu, F. S.; Enriquez, J. L.; Ramana, C. V.

    2010-07-15

    Inherent processes in coal gasification plants produce hazardous hydrogen sulfide (H{sub 2}S), which must be continuously and efficiently detected and removed before the fuel is used for power generation. An attempt has been made in this work to fabricate tungsten oxide (WO{sub 3}) thin films by radio-frequency reactive magnetron-sputter deposition. The impetus being the use of WO{sub 3} films for H{sub 2}S sensors in coal gasification plants. The effect of growth temperature, which is varied in the range of 30-500 deg. C, on the growth and microstructure of WO{sub 3} thin films is investigated. Characterizations made using scanning electron microscopy (SEM) and x-ray diffraction (XRD) indicate that the effect of temperature is significant on the microstructure of WO{sub 3} films. XRD and SEM results indicate that the WO{sub 3} films grown at room temperature are amorphous, whereas films grown at higher temperatures are nanocrystalline. The average grain-size increases with increasing temperature. WO{sub 3} films exhibit smooth morphology at growth temperatures {<=}300 deg. C while relatively rough at >300 deg. C. The analyses indicate that the nanocrystalline WO{sub 3} films grown at 100-300 deg. C could be the potential candidates for H{sub 2}S sensor development for application in coal gasification systems.

  19. Structural and gasochromic properties of WO3 films prepared by reactive sputtering deposition

    NASA Astrophysics Data System (ADS)

    Yamamoto, S.; Hakoda, T.; Miyashita, A.; Yoshikawa, M.

    2015-02-01

    The effects of deposition temperature and film thickness on the structural and gasochromic properties of tungsten trioxide (WO3) films used for the optical detection of diluted cyclohexane gas have been investigated. The WO3 films were prepared on SiO2 substrates by magnetron sputtering, with the deposition temperature ranging from 300 to 550 °C in an Ar and O2 gas mixture. The films were characterized by scanning electron microscopy (SEM), x-ray diffraction (XRD), and Rutherford backscattering spectroscopy (RBS). The gasochromic properties of the WO3 films, coated with a catalytic Pt layer, were examined by exposing them to up to 5% cyclohexane in N2 gas. It was found that (001)-oriented monoclinic WO3 films, with a columnar structure, grew at deposition temperatures between 400 and 450 °C. Furthermore, (010)-oriented WO3 films were preferably formed at deposition temperatures higher than 500 °C. The gasochromic characterization of the Pt/WO3 films revealed that (001)-oriented WO3 films, with cauliflower-like surface morphology, were appropriate for the optical detection of cyclohexane gas.

  20. A research on SLAM aided INS/GPS navigation system

    NASA Astrophysics Data System (ADS)

    Cao, Menglong; Cui, Pingyuan

    2007-11-01

    Simultaneous Localization and Mapping (SLAM) aided INS/GPS navigation system is a landmark based terrain aided autonomous integrated system that has the capability for online map building and simultaneously utilizing the generated map to bind the errors in the Inertial Navigation System (INS) when GPS is not available. If GPS information is available, the SLAM integrated system builds a landmark-based map using an INS/GPS solution. If GPS is not available, the previously newly generated map is used to constrain the INS errors. The SLAM augmented INS/GPS system shows two capabilities of landmark tracking and mapping using GPS information and more importantly, aiding the INS under GPS denied situation. The validity of the proposed method is demonstrated by computer simulation.

  1. WO3 nanorolls self-assembled as thin films by hydrothermal synthesis

    NASA Astrophysics Data System (ADS)

    Vankova, S.; Zanarini, S.; Amici, J.; Cámara, F.; Arletti, R.; Bodoardo, S.; Penazzi, N.

    2015-04-01

    We report a novel type of WO3 nanostructure, i.e. nanorolls obtained as a self-assembled thin film on a transparent conductive substrate. The mild conditions of preparation, avoiding the use of HCl, result in an eco-friendly hydrothermal method with reduced crystallization time. FESEM and HR-TEM show that WO3 nanocrystals are made of rolled nanoflakes with a telescope-like appearance at their tip. For their nano-porosity, electrochemical accessibility, good adhesion to substrates and the envisaged presence of nanocavities between the WO3 layers, these materials hold tremendous promise in nano-electronics, electrochromic devices, water photo-splitting cells, Li-ion batteries and nano-templated filters for UV radiation.We report a novel type of WO3 nanostructure, i.e. nanorolls obtained as a self-assembled thin film on a transparent conductive substrate. The mild conditions of preparation, avoiding the use of HCl, result in an eco-friendly hydrothermal method with reduced crystallization time. FESEM and HR-TEM show that WO3 nanocrystals are made of rolled nanoflakes with a telescope-like appearance at their tip. For their nano-porosity, electrochemical accessibility, good adhesion to substrates and the envisaged presence of nanocavities between the WO3 layers, these materials hold tremendous promise in nano-electronics, electrochromic devices, water photo-splitting cells, Li-ion batteries and nano-templated filters for UV radiation. Electronic supplementary information (ESI) available: Characterization techniques; additional FESEM micrographs; typical XRD pattern of WO3 nanoroll thin film; typical Nyquist plots at ambient temperature; indicative diameter and length of WO3 NR by varying the PVA chain length; effect of 2000 cycles of electrochemical switching on the STB, STC and ΔT% coloration efficiency of the WO3 NR. See DOI: 10.1039/c4nr07290a

  2. Fabrication and photocatalysis of mesoporous ZnWO{sub 4} with PAMAM as a template

    SciTech Connect

    Lin Shen Chen Jiebo; Weng Xiulan; Yang Liuyi; Chen Xinqin

    2009-05-06

    Mesoporous ZnWO{sub 4} was prepared with the template of PAMAM. The as-formed samples were characterized by X-ray diffraction (XRD), nitrogen absorption, scanning electron microscopy (SEM), transmission electron microscopy (TEM), and UV-vis diffuse reflectance spectroscopy (DRS). It is found that the size of pore is in the range of 5-22 nm and that the porosity of ZnWO{sub 4} is composed of aggregated ZnWO{sub 4} nanoparticles. The photocatalytic activities towards degradation of rhodamine B (RhB) and malachite green (MG) under UV light has been investigated. The formation mechanism of mesoporous structures is proposed.

  3. CTAB-assisted ultrasonic synthesis, characterization and photocatalytic properties of WO{sub 3}

    SciTech Connect

    Sánchez-Martínez, D. Gomez-Solis, C.; Torres-Martinez, Leticia M.

    2015-01-15

    Highlights: • WO{sub 3} 2D nanostructures were synthesized by ultrasound method assisted with CTAB. • WO{sub 3} morphology was mainly of rectangular nanoplates with a thickness of ∼50 nm. • The highest surface area value of WO{sub 3} was obtained to lowest concentration of CTAB. • WO{sub 3} activity was attributed to morphology, surface area and the addition of CTAB. • WO{sub 3} nanoplates were able to causing almost complete mineralization of rhB and IC. - Abstract: WO{sub 3} 2D nanostructures have been prepared by ultrasound synthesis method assisted with CTAB using different molar ratios. The formation of monoclinic crystal structure of WO{sub 3} was confirmed by X-ray powder diffraction (XRD). The characterization of the WO{sub 3} samples was complemented by analysis of scanning electron microscopy (SEM), which revealed morphology mainly of rectangular nanoplates with a thickness of around 50 nm and length of 100–500 nm. Infrared spectroscopy (FT-IR) was used to confirm the elimination of the CTAB in the synthesized samples. The specific surface area was determinate by the BET method and by means of diffuse reflectance spectroscopy (DRS) it was determinate the band-gap energy (E{sub g}) of the WO{sub 3} samples. The photocatalytic activity of the WO{sub 3} oxide was evaluated in the degradation reactions of rhodamine B (rhB) and indigo carmine (IC) under Xenon lamp irradiation. The highest photocatalytic activity was observed in the samples containing low concentration of CTAB with morphology of rectangular nanoplates and with higher surface area value than commercial WO{sub 3}. Photodegradation of rhB and IC were followed by means of UV–vis absorption spectra. The mineralization degree of organic dyes by WO{sub 3} photocatalyst was determined by total organic carbon analysis (TOC) reaching percentages of mineralization of 92% for rhB and 50% for IC after 96 h of lamp irradiation.

  4. Ionic liquid- and surfactant-controlled crystallization of WO3 films.

    PubMed

    Kaper, Helena; Djerdj, Igor; Gross, Silvia; Amenitsch, Heinz; Antonietti, Markus; Smarsly, Bernd M

    2015-07-21

    WO3 films were obtained via evaporation-induced self-assembly (EISA) using ionic surfactants such as long-chain ionic liquids 1-hexadecyl-3-methyl imidazolium chloride and bromide (C16mimCl and C16mimBr, respectively) and cetyltrimethylammonium chloride and bromide (CTAC and CTAB, respectively) as additives. Owing to the presence of the ionic surfactants, WO3 films crystallize in a preferred orientation along the a-axis on different substrates, as evidenced by X-ray diffraction. WO3 films with this orientation show improved electrochromic properties when compared to films with a lower degree of crystallographic orientation, prepared in an analogue fashion. PMID:26102203

  5. Future Technologies for Earth Science with Spaceborne GPS

    NASA Technical Reports Server (NTRS)

    Yunck, T. P.; Meehan, T. K.; Srinivasan, J. M.; Young, L. E.

    1995-01-01

    Spaceborne Global Positioning System (GPS) receivers will one day make important contributions to atmospheric, ionospheric, and solid Earth science. A number of GPS microsatellite missions are already in preparation in several countries. These missions require GPS flight receivers with capabilities well beyond the needs of most space missions. Receiver and microsatellite future technology is discussed.

  6. 78 FR 63459 - GPS Satellite Simulator Control Working Group Meeting

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-10-24

    ... From the Federal Register Online via the Government Publishing Office DEPARTMENT OF DEFENSE Air Force GPS Satellite Simulator Control Working Group Meeting AGENCY: Department of the Air Force. ACTION..., that the GPS Directorate will host a GPS Satellite Simulator Control Working Group (SSCWG) meeting on...

  7. 78 FR 67132 - GPS Satellite Simulator Control Working Group Meeting

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-11-08

    ... From the Federal Register Online via the Government Publishing Office DEPARTMENT OF DEFENSE Department of the Air Force GPS Satellite Simulator Control Working Group Meeting AGENCY: Space and Missile..., that the GPS Directorate will host a GPS Satellite Simulator Control Working Group (SSCWG) meeting on...

  8. 77 FR 70421 - GPS Satellite Simulator Control Working Group Meeting

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-11-26

    ... From the Federal Register Online via the Government Publishing Office DEPARTMENT OF DEFENSE Department of the Air Force GPS Satellite Simulator Control Working Group Meeting AGENCY: Space and Missile..., that the GPS Directorate will host a GPS Satellite Simulator Control Working Group (SSCWG) meeting...

  9. The Evolution of Global Positioning System (GPS) Technology.

    ERIC Educational Resources Information Center

    Kumar, Sameer; Moore, Kevin B.

    2002-01-01

    Describes technological advances in the Global Positioning System (GPS), which is also known as the NAVSTAR GPS satellite constellation program developed in 1937, and changes in the nature of our world by GPS in the areas of agriculture, health, military, transportation, environment, wildlife biology, surveying and mapping, space applications, and…

  10. GPSIM: A Personal Computer-Based GPS Simulator System

    NASA Astrophysics Data System (ADS)

    Ibrahim, D.

    Global Positioning Systems (GPS) are now in use in many applications, ranging from GIS to route guidance, automatic vehicle location (AVL), air, land, and marine navigation, and many other transportation and geographical based applications. In many applications, the GPS receiver is connected to some form of intelligent electronic system which receives the positional data from the GPS unit and then performs the required operation. When developing and testing GPS-based systems, one of the problems is that it is usually necessary to create GPS-compatible geographical data to simulate a GPS operation in real time. This paper provides the details of a Personal Computer (PC)-based GPS simulator system called GPSIM. The system receives user way-points and routes from Windows-based screen forms and then simulates a GPS operation in real time by generating most of the commonly used GPS sentences. The user-specified waypoints are divided into a number of small segments, each segment specifying a small distance in the direction of the original waypoint. The GPS sentence corresponding to the geographical coordinates of each segment is then sent out of the PC serial port. The system described is an invaluable testing tool for GPS-based system developers and also for people training to learn to use GPS-based products.

  11. Processing GPS Occultation Data To Characterize Atmosphere

    NASA Technical Reports Server (NTRS)

    Hajj, George; Kursinski, Emil; Leroy, Stephen; Lijima, Byron; de la Torre Juarez, Manuel; Romans, Larry; Ao, Chi

    2005-01-01

    GOAS [Global Positioning System (GPS) Occultation Analysis System] is a computer program that accepts signal-occultation data from GPS receivers aboard low-Earth-orbiting satellites and processes the data to characterize the terrestrial atmosphere and, in somewhat less comprehensive fashion, the ionosphere. GOAS is very robust and can be run in an unattended semi-operational processing mode. It features sophisticated retrieval algorithms that utilize the amplitudes and phases of the GPS signals. It incorporates a module that, using an assumed atmospheric refractivity profile, simulates the effects of the retrieval processing system, including the GPS receiver. GOAS utilizes the GIPSY software for precise determination of orbits as needed for calibration. The GOAS output for the Earth s troposphere and mid-to-lower stratosphere consists of high-resolution (<1 km) profiles of density, temperature, pressure, atmospheric refractivity, bending angles of signals, and water-vapor content versus altitude from the Earth s surface to an altitude of 30 km. The GOAS output for the ionosphere consists of electron-density profiles from an altitude of about 50 km to the altitude of a satellite, plus parameters related to the rapidly varying structure of the electron density, particularly in the E layer of the ionosphere.

  12. Discovering Hidden Treasures with GPS Technology

    ERIC Educational Resources Information Center

    Nagel, Paul; Palmer, Roger

    2014-01-01

    "I found it!" Addison proudly proclaimed, as she used an iPhone and Global Positioning System (GPS) software to find the hidden geocache along the riverbank. Others in Lisa Bostick's fourth grade class were jealous, but there would be other geocaches to find. With the excitement of movies like "Pirates of the Caribbean"…

  13. Global geodesy using GPS without fiducial sites

    NASA Technical Reports Server (NTRS)

    Heflin, Michael; Bertiger, Willy; Blewitt, Geoff; Freedman, Adam; Hurst, Ken; Lichten, Steve; Lindqwister, Ulf; Vigue, Yvonne; Webb, Frank; Yunck, Tom

    1992-01-01

    Baseline lengths and geocentric radii have been determined from GPS data without the use of fiducial sites. Data from the first GPS experiment for the IERS and Geodynamics (GIG '91) have been analyzed with a no-fiducial strategy. A baseline length daily repeatability of 2 mm + 4 parts per billion was obtained for baselines in the Northern Hemisphere. Comparison of baseline lengths from GPS and the global VLBI solution GLB659 (Caprette et al. 1990) show rms agreement of 2.1 parts per billion. The geocentric radius mean daily repeatability for all sites was 15 cm. Comparison of geocentric radii from GPS and SV5 (Murray et al. 1990) show rms agreement of 3.8 cm. Given n globally distributed stations, the n(n - 1)/2 baseline lengths and n geocentric radii uniquely define a rigid closed polyhedron with a well-defined center of mass. Geodetic information can be obtained by examining the structure of the polyhedron and its change with time.

  14. Accuracy assessment of GPS satellite orbits

    NASA Technical Reports Server (NTRS)

    Schutz, B. E.; Tapley, B. D.; Abusali, P. A. M.; Ho, C. S.

    1991-01-01

    GPS orbit accuracy is examined using several evaluation procedures. The existence is shown of unmodeled effects which correlate with the eclipsing of the sun. The ability to obtain geodetic results that show an accuracy of 1-2 parts in 10 to the 8th or better has not diminished.

  15. The Southern California Dense GPS Geodetic Array

    NASA Technical Reports Server (NTRS)

    Webb, F.

    1994-01-01

    The Southern California Earthquake Center is coordinating a effort by scientists at the Jet Propulsion Laboratory, the U.S. Geological Survey, and various academic institutions to establish a dense 250 station, continuously recording GPS geodetic array in southern California for measuring crustal deformation associated with slip on the numerous faults that underlie the major metropolitan areas of southern california.

  16. The MARCOR GPS mobile data system

    NASA Technical Reports Server (NTRS)

    Rothblatt, Martin

    1991-01-01

    Market research revealed several key demands for an Automatic Vehicle Location (AVL) Global Positioning System (GPS) radio. The demands were for minimization of urban building blockage, easy programmability to minimize mobile data transmission costs, high accuracy for street map level coordination, interface capability with non-digital Specialized Mobile Radios (SMR), and a selling price close to that of alternatives such as Signposts and Loran-C. A team of experts was assembled to surmount these challenges and deliver a GPS radio for $500 to $1000, which operates at high accuracy in an urban environment and is plug-compatible with nearly all vehicle radios. Among the engineering and production breakthroughs described here are a unique Simultrac (Trademark) approach to satellite tracking, enabling up to eight GPS satellites to be used for position determination with a 2-channel receiver, and a receiver-in-a-microphone design. A powerful Application Specific Integrated Circuit (ASIC) allowed GPS to be brought within easy reach of millions of AVL users such as bus, taxi, and delivery vehicle fleets.

  17. GPS LifePlan--Leading Campus Change

    ERIC Educational Resources Information Center

    Litecky, Larry; Bruner, Mike; Hageman, Kristin

    2009-01-01

    The Goals + Plans = Success (GPS) LifePlan is a new and innovative approach to assist and support students in answering critical questions that give direction to their pursuit of success. The program has brought impressive cultural changes to Century College. It benefited new students by establishing a framework for critical decision making that…

  18. Iranian Permanent GPS Network for Geodynamics (IPGN)

    NASA Astrophysics Data System (ADS)

    Tavakoli, F.; Nankali, H. R.; Sedighi, M.; Djamour, Y.; Mosavi, Z.

    2009-04-01

    Iran is one of the most tectonically active zone in Alpine-Himalayan seismic belt where has been shaken by largely destroying historical and instrumental earthquakes. Iran is located in the convergence zone between Arabia and Eurasia with a velocity of 22 mm/yr nearly to the North. The shortening between Arabian and Eurasian plates in Iran is mainly distributed on Zagros and Alborz belts. Despite the historical and scientific awareness of seismic hazard in Iran, unfortunately this country lacked a Continuous GPS network to study geodynamic and tectonic movements. Such geodetic measurement can play an important role to understand the tectonic deformation then to evaluate the seismic hazard on Iran. Since early 2005 National Cartographic Center of Iran (NCC) is establishing a continuous GPS network named Iranian Permanent GPS Network for Geodynamics (IPGN). Taking into account the number of provided GPS receivers, (108) we made a priority based on two factors of seismicity and population. At the first, in order to study general tectonic behavior in Iran 41 stations, globally distributed in whole of Iran, were been considered. Three other areas in the priority list were: Centeral Alborz, North-West of Iran and North-East of Iran. The rest of receivers, i.e. ~60, were considered for these areas as local networks. These four networks are daily processed and give us a continuous monitoring of any surface deformation. In this paper we try to present the results obtained from the network

  19. Signal quality monitoring for GPS augmentation systems

    NASA Astrophysics Data System (ADS)

    Mitelman, Alexander Michael

    Civilian applications of the Global Positioning System have grown rapidly over the past decade. One of the most significant examples is guidance for aviation. In conjunction with specially designed equipment on the ground, GPS can provide precision approach and landing capability for aircraft. As with other safety-critical aviation applications, GPS-based landing systems must meet stringent accuracy, safety, and availability requirements set by the Federal Aviation Administration. Currently, compliance with FAA requirements is ensured by a host of monitors including the Signal Quality Monitor, a module specifically tasked with continuously observing raw GPS signals for interference and distortion. This dissertation focuses on several theoretical and practical aspects of SQM design. The discussion begins with in-depth analysis of the seminal event in SQM, a significant anomaly on GPS space vehicle 19 initially observed in 1993. At the time, a tenfold increase in vertical position error was reported when this satellite was in view. Little consensus was initially reached about the exact origin, nature, or magnitude of the distortion; this section considers these effects in detail. The analysis is then extended to compute a rigorous upper bound for differential error. Starting with the architecture of a basic landing system, a theoretical worst-case is derived that maximizes user error while defying detection by the ground station. A simplified distortion model, adopted by the International Civil Aviation Organization in response to the worst-case analysis, is also described. The discussion then describes the design and construction of an arbitrary GPS generator. Essential features include architecture, shielding, independent signal and noise levels, and fast switching between two input channels. Two example applications are presented to illustrate the instrument's utility. A theoretical analysis of the ICAO model is validated by measuring the spectra of generated

  20. GPS Ocean Reflection Experiment on Spartan 251

    NASA Technical Reports Server (NTRS)

    Garrison, James L; Russo, Angela; Mickler, Dave; Armatys, Michael; Ferebee, Melvin J.

    1999-01-01

    It has recently been demonstrated that the GPS signal which has reflected from the ocean surface contains useful geophysical data from which the sea surface wind speed and other parameters can be extracted. This can be used for remote sensing, similar to present day use of radar altimeters or scatterometers, but with significantly smaller instrumentation because of the utilization of the existing GPS broadcast signal for illumination. Several campaigns of aircraft experimentation have been completed demonstrating this technique and reflected GPS data has been reliably collected from 25 km altitude on a balloon. However, there has not yet been a demonstration that the reflected GPS signal can be detected from orbit with sufficient signal to noise ratio (SNR) to make useful remote sensing measurements. A technology demonstration experiment was planned for a Space Shuttle flight in the late 2000 using the Spartan 251 recoverable carrier. This experiment would also have been the first flight validation of the PiVoT GPS receiver developed in house at the Goddard Space Flight Center. The "open-architecture" design of this receiver would allow the software modifications to be made which control code-correlator spacing to map out the shape of the reflected signal waveform, which is the most basic data product generated by this instrumentation. A moderate gain left-hand circularly polarized antenna, constructed from an array of off-the-shelf hemispherical antennas was to be used to give approximately 3 to 6 dB of additional gain. Preliminary SNR predictions have been done indicating that this antenna would offer sufficient gain to record waveform measurements. A system level description of the experiment instrumentation, including the receiver, antenna and data storage and retrieval will be given. The visibility of GPS reflections over the mission duration of several hours will be studied, including the effects of the limited beamwidth of the antenna. Spartan 251 has now

  1. Growth and crystallographic characterization of molecular beam epitaxial WO3 and MoO3/WO3 thin films on sapphire substrates

    NASA Astrophysics Data System (ADS)

    Yano, Mitsuaki; Koike, Kazuto; Matsuo, Masayuki; Murayama, Takayuki; Harada, Yoshiyuki; Inaba, Katsuhiko

    2016-09-01

    Molecular beam epitaxy of tungsten trioxide (WO3) on (01 1 bar 2)-oriented (r-plane) sapphire substrates and molybdenum trioxide (MoO3) on the WO3 was studied by focusing on their crystallogrhaphic properties. Although polycrystalline monoclinic (γ-phase) WO3 films were grown at 500 °C and they became single-crystalline (0 0 1)-oriented γ-phase at 700 °C, the latter films were oxygen-deficient from stoichiometry and contained dense and deep thermal etchpits. By using a two-step growth method where only the initial 15 nm was grown at 700 °C and the rest part was grown at 500 °C, (0 0 1)-oriented γ-phase single-crystalline WO3 films with stoichiometric composition and smooth surface were obtained. On top of the 15-nm-thick WO3 initiation layer, (1 1 0)-oriented orthorhombic (α-phase) MoO3 films with smooth surface were obtained.

  2. Electrochemical lithium insertion in the solid solution Bi{sub 2}WO{sub 6}-Sb{sub 2}WO{sub 6} with Aurivillius framework

    SciTech Connect

    Martinez-de la Cruz, A. Longoria Rodriguez, F.E.

    2007-10-02

    Following the structural evolution of the Aurivillius crystalline framework in the solid solution Bi{sub 2}WO{sub 6}-Sb{sub 2}WO{sub 6} we have carried out an electrochemical lithium insertion study in this system. A slight loss of the specific capacity of the electrochemical cell was observed as amount of Sb was increased. In general, the different compositions within solid solution Bi{sub 2-x}Sb{sub x}WO{sub 6} (0.25 {<=} x {<=} 0.75) exhibited a similar behaviour featured mainly by two semiconstant potential regions located at 1.7 and 0.8 V versus Li{sup +}/Li{sup o}. The oxide Sb{sub 2}WO{sub 6} with Autivillius structure but without Bi was tested as cathode too. The maximum amount of lithium inserted, 13.5 lithium atoms per formula, is the same amount inserted in its homologous bismuth oxide Bi{sub 2}WO{sub 6}.

  3. GPS, GNSS, and Ionospheric Density Gradients

    NASA Astrophysics Data System (ADS)

    Kintner, P. M.; O'Hanlon, B.; Humphreys, T. E.

    2009-12-01

    Ionospheric density and density gradients affect GNSS signals in two ways. They can introduce ranging errors or irregularities that form on the density gradients producing scintillation. Here we focus on the issue of ranging errors. There are two approaches to mitigating ranging errors produced by ionospheric density gradients which can be 20-30 m during major magnetic storms. The first approach is to use a reference receiver(s) to determine the ionospheric contribution to ranging errors. The ranging error is then transmitted to the user for correction within the mobile receiver. This approach is frequently referred to as differential GPS and, when multiple reference receivers are used, the system is referred to as an augmentation system. This approach is vulnerable to ionospheric gradients depending on the reference receiver spacing(s) and latency in applying the correction within the mobile receiver. The second approach is to transmit navigation signals at two frequencies and then use the relative delay between the two signals to both estimate the ranging error and calculate the correct range. Currently the dual frequency technique is used by US military receivers with an encryption key and some civilian receivers which must be stationary and average over times long compared to those required for navigation. However, the technology of space based radio navigation is changing. GPS will soon be a system with three frequencies and multiple codes. Furthermore Europe, Russia, and China are developing independent systems to complement and compete with GPS while India and Japan are developing local systems to enhance GPS performance in their regions. In this talk we address two questions. How do density gradients affect augmentation systems including the social consequences and will the new GPS/GNSS systems with multiple civilian frequencies be able to remove ionospheric errors. The answers are not at all clear.

  4. Terrestrial Reference Frame from GPS and SLR

    NASA Astrophysics Data System (ADS)

    Weiss, Jan; Bertiger, Willy; Desai, Shailen; Haines, Bruce; Sibois, Aurore

    2015-04-01

    We present strategies for realizing the terrestrial reference frame (TRF) using tracking data from terrestrial GPS receivers alone and in tandem with the GRACE and LAGEOS satellites. We generate solutions without apriori ties to the International Terrestrial Reference Frame (ITRF). Our approach relies on processing multi-day orbit arcs to take advantage of the satellite dynamics, GPS receiver and transmitter calibrations derived from low-Earth orbiter (LEO) data, and estimation strategies tuned for realizing a stable and accurate TRF. We furthermore take advantage of the geometric diversity provided by GPS tracking from GRACE, and explore the impacts of including ground-based satellite laser range (SLR) measurements to LAGEOS-1 and -2 with local ties relating the two geodetic techniques. We process data from 2003-2014 and compute Helmert transformations relative to ITRF/IGb08. With GPS alone we achieve a 3D origin offset and rate of <7 mm and <1 mm/yr, and reduce the offset to <4 mm when GRACE is included in the global solutions. Scale bias and rate are 3.1 ppb and 0.01 ppb/yr in either solution. Including SLR tracking from 11 ground stations to the LAGEOS satellites from 2012-2014 yields a reduction in scale bias of 0.5-1.0 ppb depending on the weight assigned to the SLR measurements. However, scatter is increased due to the relatively sparse SLR tracking network. We conclude with approaches for improving the TRF realized from GPS and SLR combined at the measurement level.

  5. Physical applications of GPS geodesy: a review

    NASA Astrophysics Data System (ADS)

    Bock, Yehuda; Melgar, Diego

    2016-10-01

    Geodesy, the oldest science, has become an important discipline in the geosciences, in large part by enhancing Global Positioning System (GPS) capabilities over the last 35 years well beyond the satellite constellation’s original design. The ability of GPS geodesy to estimate 3D positions with millimeter-level precision with respect to a global terrestrial reference frame has contributed to significant advances in geophysics, seismology, atmospheric science, hydrology, and natural hazard science. Monitoring the changes in the positions or trajectories of GPS instruments on the Earth’s land and water surfaces, in the atmosphere, or in space, is important for both theory and applications, from an improved understanding of tectonic and magmatic processes to developing systems for mitigating the impact of natural hazards on society and the environment. Besides accurate positioning, all disturbances in the propagation of the transmitted GPS radio signals from satellite to receiver are mined for information, from troposphere and ionosphere delays for weather, climate, and natural hazard applications, to disturbances in the signals due to multipath reflections from the solid ground, water, and ice for environmental applications. We review the relevant concepts of geodetic theory, data analysis, and physical modeling for a myriad of processes at multiple spatial and temporal scales, and discuss the extensive global infrastructure that has been built to support GPS geodesy consisting of thousands of continuously operating stations. We also discuss the integration of heterogeneous and complementary data sets from geodesy, seismology, and geology, focusing on crustal deformation applications and early warning systems for natural hazards.

  6. US Coast Guard GPS Information Center (GPSIC) and its function within the Civil GPS Service (CGS)

    NASA Technical Reports Server (NTRS)

    Barndt, Luann

    1992-01-01

    The Global Positioning System Information Center (GPSIC) was created to provide civil users of the Global Positioning System with timely system status and other GPS satellite information. The GPSIC began providing basic services on a test and evaluation basis in March 1990. Since then we have improved these services, formalized the information gathering processes, and expanded GPSIC operations to meet GPS user needs. The GPSIC serves as a central point of contact for civil users to make their interests and needs known to the system operator, the Department of Defense (DOD) under the management of the U.S. Air Force. The GPSIC provides GPS information to civil users through Operational Advisory Broadcasts (OAB) containing GPS performance data. The OABs are disseminated through numerous sources including 24 hour access to a voice telephone recording and a computer bulletin board system (BBS). The GPSIC staff also responds to individual user inquiries, comments, or concerns about civil access to and use of the GPS during normal working hours. This paper provides an overview of the Civil GPS Service as well as the details of the type of information and services that are available through the GPSIC and how they can be obtained. It will also address the future expansion of GPSIC responsibilities.

  7. Mixing frequency induces [WO4]2- generating blue luminescence

    NASA Astrophysics Data System (ADS)

    Xia, Zhongchao; Yang, Fugui

    2014-02-01

    In the process of investigating end-pumped continuous intra-cavity Raman laser, a strong blue luminescence at wavelength 473 nm (nanometer) in pure [XO4]2- (X = W, Y, …) has been observed. This luminescence is strange and inconsistent with the traditional single up-conversion luminescence theory, scintillation theory. Basing on the optics theory and scintillation crystal theory, we suggest a "mixing frequency inducing blue emission" mechanism to explain the phenomenon. The mixing wavelength 473.4 nm with the four wavelengths of 808, 890, 912, and 1.064 nm stimulates and induces the blue emission of the [WO4]2-. The mechanism is in good harmony with the experiment.

  8. Characterization of Nanoporous WO3 Films Grown via Ballistic Deposition

    SciTech Connect

    Smid, Bretislav; Li, Zhenjun; Dohnalkova, Alice; Arey, Bruce W.; Smith, R. Scott; Matolin, Vladimir; Kay, Bruce D.; Dohnalek, Zdenek

    2012-05-17

    We report on the preparation and characterization of high surface area, supported nanoporous tungsten oxide films prepared under different conditions on polished polycrystalline Ta and Pt(111) substrates via direct sublimation of monodispersed gas phase of cyclic (WO3)3 clusters. Scanning Electron Microscopy and Transmission Electron Microscopy were used to investigate the film morphology on a nanometer scale. The films consist of arrays of separated filaments that are amorphous. The chemical composition and the thermal stability of the films were investigated by means of X-ray Photoelectron Spectroscopy. The surface area and the distribution of binding sites on the films are measured as functions of growth temperature, deposition angle, and annealing conditions using temperature programmed desorption of Kr. Films deposited at 20 K and at an incident angle of 65{sup o} from substrate normal display the greatest specific surface area of {approx}560 m2/g.

  9. Development of a Miniature Multifunctional GPS Receiver for Space Applications

    NASA Astrophysics Data System (ADS)

    Miyano, Tomoyuki; Ishijima, Yoshiyuki; Kumagai, Susumu

    This paper presents the development of a miniature multifunctional GPS receiver at NASDA. The design and implementation method for a spaceborne GPS receiver has been investigated, and a breadboard model of a parallel signal search system incorporating matched filtering, an essential technique for next-generation GPS receivers, has been manufactured. The time to acquisition (TTA) of a GPS signal was measured on the breadboard model using a GPS simulator. The test results of the trial product show that TTA is within 60 msec, and time to first fix (TTFF) of the navigation calculation in a low-altitude orbit is within 5.3 min in the worst-case scenario.

  10. Evaluation of a Mobile Phone for Aircraft GPS Interference

    NASA Technical Reports Server (NTRS)

    Nguyen, Truong X.

    2004-01-01

    Measurements of spurious emissions from a mobile phone are conducted in a reverberation chamber for the Global Positioning System (GPS) radio frequency band. This phone model was previously determined to have caused interference to several aircraft GPS receivers. Interference path loss (IPL) factors are applied to the emission data, and the outcome compared against GPS receiver susceptibility. The resulting negative safety margins indicate there are risks to aircraft GPS systems. The maximum emission level from the phone is also shown to be comparable with some laptop computer's emissions, implying that laptop computers can provide similar risks to aircraft GPS receivers.

  11. Measuring Postglacial Rebound with GPS and Absolute Gravity

    NASA Technical Reports Server (NTRS)

    Larson, Kristine M.; vanDam, Tonie

    2000-01-01

    We compare vertical rates of deformation derived from continuous Global Positioning System (GPS) observations and episodic measurements of absolute gravity. We concentrate on four sites in a region of North America experiencing postglacial rebound. The rates of uplift from gravity and GPS agree within one standard deviation for all sites. The GPS vertical deformation rates are significantly more precise than the gravity rates, primarily because of the denser temporal spacing provided by continuous GPS tracking. We conclude that continuous GPS observations are more cost efficient and provide more precise estimates of vertical deformation rates than campaign style gravity observations where systematic errors are difficult to quantify.

  12. Application of GPS tracking techniques to orbit determination for TDRS

    NASA Technical Reports Server (NTRS)

    Haines, B. J.; Lichten, S. M.; Malla, R. P.; Wu, S. C.

    1993-01-01

    In this paper, we evaluate two fundamentally different approaches to TDRS orbit determination utilizing Global Positioning System (GPS) technology and GPS-related techniques. In the first, a GPS flight receiver is deployed on the TDRSS spacecraft. The TDRS ephemerides are determined using direct ranging to the GPS spacecraft, and no ground network is required. In the second approach, the TDRSS spacecraft broadcast a suitable beacon signal, permitting the simultaneous tracking of GPS and TDRSS satellites from a small ground network. Both strategies can be designed to meet future operational requirements for TDRS-2 orbit determination.

  13. Electrochemical properties of magnetron sputtered WO{sub 3} thin films

    SciTech Connect

    Madhavi, V.; Kondaiah, P.; Hussain, O. M.; Uthanna, S.

    2013-02-05

    Thin films of tungsten oxide (WO{sub 3}) were deposited on ITO substrates by using RF magnetron sputtering at oxygen and argon atmospheres of 6 Multiplication-Sign 10{sup -2}Pa and 4 Pa respectively. The chemical composition and surface morphology of the WO{sub 3} thin films have been studied by X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM) respectively. The results indicate that the deposited WO{sub 3} thin films are nearly stoichiometric. The electrochemical performances of the WO{sub 3} thin films have been evaluated by galvonostatic charging/discharging method. The discharge capacity was 15{mu}Ah/cm{sup 2}{mu}m at the initial cycle and faded rapidly in the first few cycles and stabilized at a lesser stage.

  14. Eliminating degradation and uncovering ion-trapping dynamics in electrochromic WO3 thin films

    NASA Astrophysics Data System (ADS)

    Wen, Rui-Tao; Granqvist, Claes G.; Niklasson, Gunnar A.

    2015-10-01

    There is keen interest in the use of amorphous WO3 thin films as cathodic electrodes in transmittance-modulating electrochromic devices. However, these films suffer from ion-trapping-induced degradation of optical modulation and reversibility on extended Li+-ion exchange. Here, we demonstrate that ion-trapping-induced degradation, which is commonly believed to be irreversible, can be successfully eliminated by constant-current-driven de-trapping; that is, WO3 films can be rejuvenated and regain their initial highly reversible electrochromic performance. Pronounced ion trapping occurs when x exceeds ~0.65 in LixWO3 during ion insertion. We find two main kinds of Li+-ion-trapping site (intermediate and deep) in WO3, where the intermediate ones are most prevalent. Li+ ions can be completely removed from intermediate traps but are irreversibly bound in deep traps. Our results provide a general framework for developing and designing superior electrochromic materials and devices.

  15. Enhanced electrochemical performance of monoclinic WO3 thin film with redox additive aqueous electrolyte.

    PubMed

    Shinde, Pragati A; Lokhande, Vaibhav C; Chodankar, Nilesh R; Ji, Taeksoo; Kim, Jin Hyeok; Lokhande, Chandrakant D

    2016-12-01

    To achieve the highest electrochemical performance for supercapacitor, it is very essential to find out a suitable pair of an active electrode material and an electrolyte. In the present work, a simple approach is employed to enhance the supercapacitor performance of WO3 thin film. The WO3 thin film is prepared by a simple and cost effective chemical bath deposition method and its electrochemical performance is tested in conventional (H2SO4) and redox additive [H2SO4+hydroquinone (HQ)] electrolytes. Two-fold increment in electrochemical performance for WO3 thin film is observed in redox additive aqueous electrolyte compared to conventional electrolyte. WO3 thin film showed maximum specific capacitance of 725Fg(-1), energy density of 25.18Whkg(-1) at current density of 7mAcm(-2) with better cycling stability in redox electrolyte. This strategy provides the versatile way for designing the high performance energy storage devices.

  16. Investigations On Stoichiometry And Melting Behavior Of NaY(WO{sub 4}){sub 2}

    SciTech Connect

    Salunke, R. G.; Gosavi, S. W.; Singh, S. G.; Singh, A. K.; Desai, D. G.; Chauhan, A. K.; Gadkari, S. C.

    2010-12-01

    Differential thermal analysis (DTA) and X-ray diffraction (XRD) studies were carried out to understand the melting behavior of the NaY(WO{sub 4}){sub 2}, an important functional material used for the laser production. It has been observed that the stoichiometric NaY(WO{sub 4}){sub 2} composition forms a solution with another phase of the Na{sub 2}WO{sub 4}-Y{sub 2}(WO{sub 4}){sub 3} pseudo-binary system. This is found to be detrimental for the growth of single crystals of the material. Therefore, molar fraction in the starting charge was suitably altered to successfully restrict the formation of the undesired phase in the melt. A composition is suggested for the favorable crystal growth of this material.

  17. Fabrication of luminescent SrWO{sub 4} thin films by a novel electrochemical method

    SciTech Connect

    Chen Lianping Gao Yuanhong

    2007-10-02

    Highly crystallized SrWO{sub 4} thin films with single scheelite structure were prepared within 60 min by a cell electrochemical method. X-ray diffraction analysis shows that SrWO{sub 4} thin films have a tetragonal structure. Scanning electron microscopy examinations reveal that SrWO{sub 4} grains grow well in tetragonal tapers and grains like flowers or bunches, which can usually form by using the electrolysis electrochemical method, have disappeared under cell electrochemical conditions. X-ray photoelectron spectra and energy dispersive X-ray microanalysis examinations demonstrate that the composition of the film is consistent with its stoichiometry. These SrWO{sub 4} films show a single blue emission peak (located at 460 nm) using an excitation wave of 230 nm. The speed of cell electrochemical method can be controlled by changing temperature. The optimum treatment temperature is about 50-60 deg. C.

  18. Structure and photocatalytic performance of layered HNbWO6 nanosheet aggregation

    NASA Astrophysics Data System (ADS)

    Hu, Li-Fang; Li, Rui; He, Jie; Da, Liang-guo; Lv, Wei; Hu, Jin-song

    2015-01-01

    Layered HNbWO6 nanosheet aggregation (e-HNbWO6) has been assembled by HNbWO6 nanosheet via an exfoliation-restaking route. The as-prepared samples are characterized by means of powder x-ray diffraction, scanning electron microscope, high-resolution transmission electron microscopy, laser Raman spectroscopy, ultraviolet-vis diffuse reflectance spectroscopy, and N2 adsorption-desorption isotherms. The photocatalytic performances of the as-prepared samples are evaluated by degradation of methylene blue (MB). The results revealed that e-HNbWO6 has a specific surface area of about 156.5 m2 g-1, and exhibits a relatively excellent photocatalytic performance for degradation of MB under UV light.

  19. Enhanced electrochemical performance of monoclinic WO3 thin film with redox additive aqueous electrolyte.

    PubMed

    Shinde, Pragati A; Lokhande, Vaibhav C; Chodankar, Nilesh R; Ji, Taeksoo; Kim, Jin Hyeok; Lokhande, Chandrakant D

    2016-12-01

    To achieve the highest electrochemical performance for supercapacitor, it is very essential to find out a suitable pair of an active electrode material and an electrolyte. In the present work, a simple approach is employed to enhance the supercapacitor performance of WO3 thin film. The WO3 thin film is prepared by a simple and cost effective chemical bath deposition method and its electrochemical performance is tested in conventional (H2SO4) and redox additive [H2SO4+hydroquinone (HQ)] electrolytes. Two-fold increment in electrochemical performance for WO3 thin film is observed in redox additive aqueous electrolyte compared to conventional electrolyte. WO3 thin film showed maximum specific capacitance of 725Fg(-1), energy density of 25.18Whkg(-1) at current density of 7mAcm(-2) with better cycling stability in redox electrolyte. This strategy provides the versatile way for designing the high performance energy storage devices. PMID:27565957

  20. Synthesis of Bi2WO6 Microspheres with Visible-Light Photocatalytic Properties

    NASA Astrophysics Data System (ADS)

    Wan, Gengping; Wang, Guizhen

    2013-12-01

    Bi2WO6 microspheres constructed from nanosheets have been synthesized by a controllable solvothermal route in a large scale. The structure characterizations of the microspheres were investigated in detail by means of X-ray diffraction (XRD), scanning electron microscopy (SEM) and high-resolution transmission electron microscopy (HRTEM). On the basis of XRD analysis and SEM observation of the products at different reaction time periods, a growth mechanism of Bi2WO6 microspheres was proposed. UV-Visible diffuse reflectance (DR) spectrum of the prepared Bi2WO6 microspheres demonstrates that they have absorption in the visible light region. The photocatalytic activity of Bi2WO6 microspheres toward Rhodamine-B (RhB) degradation was investigated and the as-prepared products exhibited good photocatalytic activity in degradation of RhB under 300 W Xe lamp light irradiation.

  1. Hydrothermal synthesis of Bi2WO6 hierarchical flowers with their photonic and photocatalytic properties

    NASA Astrophysics Data System (ADS)

    Dumrongrojthanath, Phattharanit; Thongtem, Titipun; Phuruangrat, Anukorn; Thongtem, Somchai

    2013-02-01

    Bi2WO6 hierarchical multi-layered flower-like assemblies were synthesized by a hydrothermal method at 180 °C for 24 h. XRD patterns were specified as pure orthorhombic well-crystallized Bi2WO6 phase. Their FTIR spectra show main absorption bands at 400-1000 cm-1, assigned as the stretching modes of the Bi-O and W-O, and W-O-W bridging stretching modes. SEM analysis shows that the product was 3D hierarchical flower-like assemblies, constructed by orderly arranged 2D layers of nanoplates. The UV-visible absorption shows an absorbance in the ultraviolet region with 3.4 eV band gap. Photocatalytic activity of Bi2WO6 hierarchical flowers was determined from the degradation of rhodamine-B by Xe light at 88% for 360 min irradiation.

  2. Strong aggregation adsorption of methylene blue from water using amorphous WO3 nanosheets

    NASA Astrophysics Data System (ADS)

    Luo, Jian Yi; Cao, Zhi; Chen, Feng; Li, Li; Lin, Yu Rong; Liang, Bao Wen; Zeng, Qing Guang; Zhang, Mei; He, Xin; Li, Chen

    2013-12-01

    In this paper, authors demonstrate the high performance of the amorphous WO3 nanosheets in the removal of methylene blue (MB) from water. The saturated MB adsorbed amount by using WO3 nanosheets as an adsorbent can reach to 600 mg/g, exceeding the ones of the normal activated carbon powders. Results indicate that the aggregation of adsorbed MB molecules occurs in the porous micro-structures of the amorphous WO3 nanosheets, and a precipitation phenomenon begins to happen when the initial MB concentration reach to 20 mg/L or greater, attributed to the density increase of WO3 nanosheets after their porous micro-structures are adsorbed with enough MB molecules.

  3. SUPERCRITICAL SOLVOTHERMAL SYNTHESIS AND NEAR-INFRARED ABSORBING PROPERTIES OF CsxWO3

    NASA Astrophysics Data System (ADS)

    Guo, Chongshen; Yin, Shu; Huang, Yunfang; Dong, Qiang; Li, Huihui; Sato, Tsugio

    2012-06-01

    CsxWO3 nanoparticles in the range of 20-50 nm have been successfully synthesized by the supercritical solvothermal approach, where after dissolving WCl6 and CsOH in a mixed solution of water, ethanol and oleic acid, the solution was heated at 300°C. The products were characterized by X-ray diffraction, TEM, HR-TEM, EDS, laser particle size analysis and thermographic measurements. CsxWO3 nanoparticles showed the high transparency in the visible region, excellent shielding performance of the near-infrared light and limited reflectance of light in the range of 200-2700 nm, indicating the strong absorption of NIR light on the nanosized CsxWO3. CsxWO3 nanoparticles also exhibited quick conversion of photo-energy to local heat.

  4. [Doctor's degree thesis of Tomasz Adolf Wołkowiński "Carditidis rheumaticae historia"].

    PubMed

    Stembrowicz, W

    2001-01-01

    In 1817 on the University of Vilnius Faculty of Medicine, T. A. Wołkowiński, a student of the eminent clinician Józef Frank, defended his doctor's degree thesis about a direct relation between rheumatic disease and cardiomegaly. It was probably the first paper in Poland describing with details the rheumatic heart disease. Unfortunately we don't know much about T. A. Wołkowiński's life.

  5. Temperature Dependence of the Luminescence Decay Time of a PbWO4 Scintillator

    NASA Astrophysics Data System (ADS)

    Shi, Chao-shu; Deng, Jie; Han, Zheng-fu; Xie, Zhi-jian; Liao, Jing-ying; G, Zimmerer; J, Beker; M, Kamada; M, Runne; A, Schröder

    1998-06-01

    Experimental results are given for the temperature dependence of the decay time of the emission at 430 nm from PbWO4 crystal under vacuum-ultraviolet (82 nm) photon excitation in the temperature range of 80-300 K. The structures in the curve are interpreted for the first time by studying the thermoluminescence of PbWO4, which originates from the traps in the crystal.

  6. UV-VUV synchrotron radiation spectroscopy of NiWO4

    NASA Astrophysics Data System (ADS)

    Kuzmin, A.; Pankratov, V.; Kalinko, A.; Kotlov, A.; Shirmane, L.; Popov, A. I.

    2016-07-01

    Photoluminescence and excitation spectra of microcrystalline and nanocrystalline nickel tungstate (NiWO4) were measured using UV-VUV synchrotron radiation source. The origin of the bands is interpreted using comparative analysis with isostructural ZnWO4 tungstate and based on the results of recent first-principles band structure calculations. The influence of the local atomic structure relaxation and of Ni2+ intra-ion d-d transitions on the photoluminescence band intensity are discussed.

  7. Four-wave-mixing generation of SRS components in BaWO{sub 4} and SrWO{sub 4} crystals under picosecond excitation

    SciTech Connect

    Basiev, Tasoltan T; Doroshenko, Maxim E; Ivleva, Lyudmila I; Smetanin, Sergei N; Jelinek, M; Kubecek, V; Jelinkova, H

    2013-07-31

    Four-wave-mixing stimulated Raman scattering (SRS) generation of Stokes and anti-Stokes components in BaWO{sub 4} and SrWO{sub 4} crystals excited by a 1064-nm pulsed laser with a pulse duration of 18 ps has been investigated. It is shown that, due to the four-wave mixings of SRS components in short ({approx}1 cm) crystals, the generation thresholds of the second and third Stokes components are much lower than the values determined by the cascade SRS mechanism. If the crystal length is increased by a factor of more than four, the mechanism of multiwave SRS becomes similar to the cascade mechanism (without four-wave mixings). Rotation of BaWO{sub 4} crystal makes it possible to control the competition of the processes of four-wave-mixing SRS generation of anti-Stokes and second Stokes components. (nonlinear optical phenomena)

  8. Controllable synthesis of hierarchical nanostructures of CaWO{sub 4} and SrWO{sub 4} via a facile low-temperature route

    SciTech Connect

    Chen, Z.; Gong, Q.; Zhu, J.; Yuan, Y.P.; Qian, L.W.; Qian, X.F.

    2009-01-08

    CaWO{sub 4} and SrWO{sub 4} nanostructures have been synthesized via a simple microemulsion-mediated route. With careful control of the fundamental experimental parameters including the concentration of reactants, the reaction time and the temperature, the products with different morphologies of dumbbell, coral, rod and dendrite have been obtained, respectively. The possible formation mechanism of these unique morphologies has been proposed based on surfactant self-assembly under different experimental conditions. The as-synthesized CaWO{sub 4} samples with various morphologies exhibit different photoluminescence properties. X-ray powder diffraction, transmission electron microscopy, field-emission scanning electron microscopy, and luminescence spectroscopy were used to characterize these products.

  9. The First Experiment with VLBI-GPS Hybrid System

    NASA Technical Reports Server (NTRS)

    Kwak, Younghee; Kondo, Tetsuro; Gotoh, Tadahiro; Amagai, Jun; Takiguchi, Hiroshi; Sekido, Mamoru; Ichikawa, Ryuichi; Sasao, Tetsuo; Cho, Jungho; Kim, Tuhwan

    2010-01-01

    In this paper, we introduce our GPS-VLBI hybrid system and show the results of the first experiment which is now under way. In this hybrid system, GPS signals are captured by a normal GPS antenna, down-converted to IF signals, and then sampled by the VLBI sampler VSSP32 developed by NICT. The sampled GPS data are recorded and correlated in the same way as VLBI observation data. The correlator outputs are the group delay and the delay rate. Since the whole system uses the same frequency standard, many sources of systematic errors are common between the VLBI system and the GPS system. In this hybrid system, the GPS antenna can be regarded as an additional VLBI antenna having multiple beams towards GPS satellites. Therefore, we expect that this approach will provide enough data to improve zenith delay estimates and geodetic results.

  10. Monitoring of D-layer using GPS

    NASA Astrophysics Data System (ADS)

    Golubkov, Maxim; Bessarab, Fedor; Karpov, Ivan; Golubkov, Gennady; Manzheliy, Mikhail; Borchevkina, Olga; Kuverova, Veronika; Malyshev, Nikolay; Ozerov, Georgy

    2016-07-01

    Changes in D layer of ionosphere during the periods of high solar activity lead to non-equilibrium two-temperature plasma parameter variations. Accordingly, the population of orbital degenerate states of Rydberg complexes changes in a fraction of a microsecond. In turn, this affects the operation of any of the systems based on the use of GPS radio signals passing through this layer. It is well known that GPS signals undergo the greatest distortion in the altitude range of 60-110 km. Therefore, the analysis of changes in signal intensity can be useful for plasma diagnosis in these altitudes. In particular, it is useful to determine the vertical temperature profiles and electron density. For this purpose, one can use the satellite radio occultation method. This method is widely used in recent years to solve problems of the electron concentration profile recovery in the F-region of the ionosphere, and also for climate problem solutions. This method allows to define the altitude profiles of the GPS signal propagation delays and to obtain from the inverse problem solution qualitatively high-altitude profiles of the quantities using relative measurements. To ensure the authenticity of the found distributions of electron density and temperature in the D region of the ionosphere, the results should be complemented by measurements of the own atmospheric radiation power at frequencies of 1.4 and 5.0 GHz. This ensures control of the reliability of the results obtained using the "Rydberg" code. Monitoring of the state changes in the D layer by repeatedly following at regular intervals GPS satellite measurements are also of great interest and can provide valuable information on the macroscopic dynamics of D layer containing Rydberg complexes and free electrons. For example, one can monitor changes in the thickness of the emitting layer in time. Such changes lead to an additional contribution to the formation of satellite GPS system errors. It should also be noted that the

  11. Reloading Continuous GPS in Northwest Mexico

    NASA Astrophysics Data System (ADS)

    Gonzalez-Garcia, J. J.; Suarez-Vidal, F.; Gonzalez-Ortega, J. A.

    2007-05-01

    For more than 10 years we try to follow the steps of the Southern California Integrated GPS Network (SCIGN) and the Plate Boundary Observatory (PBO) in USA, this gives us the opportunity to be in position to contribute to develop a modern GPS Network in Mexico. During 1998 and 2001, three stations were deployed in Northwest Mexico in concert with the development of SCIGN: SPMX in north central Baja California state at the National Astronomical Observatory, UNAM in the Sierra San Pedro Martir; CORX in Isla Coronados Sur, offshore San Diego, Ca./Tijuana, Mexico and GUAX in Guadalupe island 150 miles offshore Baja California peninsula, which provide a unique site on the Pacific plate in the Northamerica/Pacific boundary zone in Las Californias. The former IGS station in CICESE, Ensenada, CICE installed in 1995, was replaced by CIC1 in 1999. In 2004 and 2005 with partial support from SCIGN and UNAVCO to University of Arizona a volunteer team from UNAVCO, Caltech, U.S. Geological Survey, Universidad de la Sierra at Moctezuma Sonora and CICESE built two new shallow-braced GPS sites in northwest Mexico. The first site USMX is located at east-central Sonora and the second YESX is located high in the Sierra Madre Occidental at Yecora near the southern border of Sonora and Chihuahua. All data is openly available at SOPAC and/or UNAVCO. The existing information has been valuable to resolve the "total" plate motion between the Pacific plate (GUAX) and the Northamerica plate (USMX and YESX) in the north- central Gulf of California. Since the last year we have the capability of GPS data processing using GAMIT/GLOBK, and after gain some practice with survey mode data processing we can convert us in a GPS processing center in Mexico. Currently only 2 sites are operational: CIC1 and USMX. With new energy we are ready to contribute to the establishment of a modern GPS network in Mexico for science, hazard monitoring and infrastructure.

  12. Modulating memristive performance of hexagonal WO3 nanowire by water-oxidized hydrogen ion implantation.

    PubMed

    Zhou, Yong; Peng, Yuehua; Yin, Yanling; Zhou, Fang; Liu, Chang; Ling, Jing; Lei, Le; Zhou, Weichang; Tang, Dongsheng

    2016-01-01

    In a two-terminal Au/hexagonal WO3 nanowire/Au device, ions drifting or carriers self-trapping under external electrical field will modulate the Schottky barriers between the nanowire and electrodes, and then result in memristive effect. When there are water molecules adsorbed on the surface of WO3 nanowire, hydrogen ions will generate near the positively-charged electrode and transport in the condensed water film, which will enhance the memristive performance characterized by analogic resistive switching remarkably. When the bias voltage is swept repeatedly under high relative humidity level, hydrogen ions will accumulate on the surface and then implant into the lattice of the WO3 nanowire, which leads to a transition from semiconducting WO3 nanowire to metallic HxWO3 nanowire. This insulator-metal transition can be realized more easily after enough electron-hole pairs being excited by laser illumination. The concentration of hydrogen ions in HxWO3 nanowire will decrease when the device is exposed to oxygen atmosphere or the bias voltage is swept in atmosphere with low relative humidity. By modulating the concentration of hydrogen ions, conductive hydrogen tungsten bronze filament might form or rupture near electrodes when the polarity of applied voltage changes, which will endow the device with memristive performance characterized by digital resistive switching. PMID:27600368

  13. Modulating memristive performance of hexagonal WO3 nanowire by water-oxidized hydrogen ion implantation

    PubMed Central

    Zhou, Yong; Peng, Yuehua; Yin, Yanling; Zhou, Fang; Liu, Chang; Ling, Jing; Lei, Le; Zhou, Weichang; Tang, Dongsheng

    2016-01-01

    In a two-terminal Au/hexagonal WO3 nanowire/Au device, ions drifting or carriers self-trapping under external electrical field will modulate the Schottky barriers between the nanowire and electrodes, and then result in memristive effect. When there are water molecules adsorbed on the surface of WO3 nanowire, hydrogen ions will generate near the positively-charged electrode and transport in the condensed water film, which will enhance the memristive performance characterized by analogic resistive switching remarkably. When the bias voltage is swept repeatedly under high relative humidity level, hydrogen ions will accumulate on the surface and then implant into the lattice of the WO3 nanowire, which leads to a transition from semiconducting WO3 nanowire to metallic HxWO3 nanowire. This insulator-metal transition can be realized more easily after enough electron-hole pairs being excited by laser illumination. The concentration of hydrogen ions in HxWO3 nanowire will decrease when the device is exposed to oxygen atmosphere or the bias voltage is swept in atmosphere with low relative humidity. By modulating the concentration of hydrogen ions, conductive hydrogen tungsten bronze filament might form or rupture near electrodes when the polarity of applied voltage changes, which will endow the device with memristive performance characterized by digital resistive switching. PMID:27600368

  14. Synthesis of bismuth tungstate (Bi2WO6) nanoflakes and their field emission investigation

    NASA Astrophysics Data System (ADS)

    Kolhe, P. S.; Bankar, P. K.; Gavhane, D. S.; Sonawane, K. M.; Maiti, N.; More, M. A.

    2016-05-01

    The nanoflakes of Bismuth Tungstate (Bi2WO6) were successfully synthesized by a one-step facile hydrothermal route without using any templates or surfactants and field emission investigations of the Bi2WO6 nanoflakes emitter are reported. Structural and morphological analysis of as-synthesized Bi2WO6 nanoflakes has been carried out using X-ray diffraction (XRD) and scanning electron microscope (SEM). Moreover, the field emission characteristics of the Bi2WO6 nanoflakes are found to be superior to the other semiconductor emitters. The synthesized Bi2WO6 nanoflakes emitter delivers current density of ~222.35 μA/cm2 at an applied electric field of ~7.2 V/μm. The emission current stability investigated at pre-set value of ~2 μA is observed to be fairly good. These observed results demonstrate potential candidate of the Bi2WO6 cathode as an electron source for practical applications in vacuum microelectronic device.

  15. Memristive properties of hexagonal WO3 nanowires induced by oxygen vacancy migration.

    PubMed

    He, Xiongwu; Yin, Yanling; Guo, Jie; Yuan, Huajun; Peng, Yuehua; Zhou, Yong; Zhao, Ding; Hai, Kuo; Zhou, Weichang; Tang, Dongsheng

    2013-01-01

    Tungsten trioxide (WO3) is always oxygen-deficient or non-stoichiometric under atmospheric conditions. Positively charged oxygen vacancies prefer to drift as well as electrons when the electric field is strong enough, which will alter the distribution of oxygen vacancies and then endow WO3 with memristive properties. In Au/WO3 nanowire/Au sandwich structures with two ohmic contacts, the axial distribution of oxygen vacancies and then the electrical transport properties can be more easily modulated by bias voltage. The threshold electric field for oxygen vacancy drifting in single-crystal hexagonal WO3 nanowire is about 106 V/m, one order of magnitude less than that in its granular film. At elevated temperatures, the oxygen vacancy drifts and then the memristive effect can be enhanced remarkably. When the two metallic contacts are asymmetric, the WO3 nanowire devices even demonstrate good rectifying characteristic at elevated temperatures. Based on the drift of oxygen vacancies, nanoelectronic devices such as memristor, rectifier, and two-terminal resistive random access memory can be fabricated on individual WO3 nanowires. PMID:23347429

  16. Modulating memristive performance of hexagonal WO3 nanowire by water-oxidized hydrogen ion implantation.

    PubMed

    Zhou, Yong; Peng, Yuehua; Yin, Yanling; Zhou, Fang; Liu, Chang; Ling, Jing; Lei, Le; Zhou, Weichang; Tang, Dongsheng

    2016-01-01

    In a two-terminal Au/hexagonal WO3 nanowire/Au device, ions drifting or carriers self-trapping under external electrical field will modulate the Schottky barriers between the nanowire and electrodes, and then result in memristive effect. When there are water molecules adsorbed on the surface of WO3 nanowire, hydrogen ions will generate near the positively-charged electrode and transport in the condensed water film, which will enhance the memristive performance characterized by analogic resistive switching remarkably. When the bias voltage is swept repeatedly under high relative humidity level, hydrogen ions will accumulate on the surface and then implant into the lattice of the WO3 nanowire, which leads to a transition from semiconducting WO3 nanowire to metallic HxWO3 nanowire. This insulator-metal transition can be realized more easily after enough electron-hole pairs being excited by laser illumination. The concentration of hydrogen ions in HxWO3 nanowire will decrease when the device is exposed to oxygen atmosphere or the bias voltage is swept in atmosphere with low relative humidity. By modulating the concentration of hydrogen ions, conductive hydrogen tungsten bronze filament might form or rupture near electrodes when the polarity of applied voltage changes, which will endow the device with memristive performance characterized by digital resistive switching.

  17. WO3/TiO2 nanotube photoanodes for solar water splitting with simultaneous wastewater treatment.

    SciTech Connect

    Reyes, Karla Rosa; Robinson, David B.

    2013-05-01

    Nanostructured WO3/TiO2 nanotubes with properties that enhance solar photoconversion reactions were developed, characterized and tested. The TiO2 nanotubes were prepared by anodization of Ti foil, and WO3 was electrodeposited on top of the nanotubes. SEM images show that these materials have the same ordered structure as TiO2 nanotubes, with an external nanostructured WO3 layer. Diffuse reflectance spectra showed an increase in the visible absorption relative to bare TiO2 nanotubes, and in the UV absorption relative to bare WO3 films. Incident simulated solar photon-to-current efficiency increased from 30% (for bare WO3) to 50% (for WO3/TiO2 composites). With the addition of diverse organic pollutants, the photocurrent densities exhibited more than a 5-fold increase. Chemical oxygen demand measurements showed the simultaneous photodegradation of organic pollutants. The results of this work indicate that the unique structure and composition of these composite materials enhance the charge carrier transport and optical properties compared with the parent materials.

  18. Phonon properties of nanosized MnWO{sub 4} with different size and morphology

    SciTech Connect

    Maczka, MirosLaw; Ptak, Maciej; Kurnatowska, Michalina; Kepinski, Leszek; Tomaszewski, PaweL; Hanuza, Jerzy

    2011-09-15

    Highly hierarchical barlike and flowerlike MnWO{sub 4} microcrystals have been synthesized for the first time by a hydrothermal method, where ethanolamine (EA) and cetyltrimethylamonnium bromide (CTAB) play important roles in directing growth and self-assembly of these structures. The possible formation process has been proposed. In addition, platelike nanosized MnWO{sub 4} was also synthesized by annealing of a precursor obtained by coprecipitation method. The obtained samples were characterized by XRD, SEM, TEM, Raman and IR methods. Raman spectra showed relatively weak dependence on particle size and morphology of the particles. In contrast to this behavior, IR-active bands showed pronounced shifts and changes in relative intensities on particle size and the morphology. Origin of this behavior is discussed. - Graphical Abstract: SEM images of MnWO{sub 4} particles prepared by hydrothermal process at 150 deg. C (left panel) and 200 deg. C (right panel). Highlights: > Hydrothermal synthesis with ethanolamine enables growth of hierarchical nanosized MnWO{sub 4} particles. > Annealing of a precursor obtained by coprecipitation method enables growth of platelike MnWO{sub 4} nanoparticles. > Raman and IR spectra of MnWO{sub 4} nanoparticles depend on both size and morphology of the nanoparticles. > We discuss origin of this behavior.

  19. Investigation of x-ray photoelectron spectroscopic (XPS), cyclic voltammetric analyses of WO3 films and their electrochromic response in FTO/WO3/electrolyte/FTO cells

    NASA Astrophysics Data System (ADS)

    Sivakumar, R.; Gopalakrishnan, R.; Jayachandran, M.; Sanjeeviraja, C.

    2006-06-01

    Electrochromic thin films of tungsten oxide (WO3) were prepared on transparent conducting oxide substrates, i.e., fluorine doped tin oxide coated (FTO or SnO2:F) glass and microscopic glass substrates by the electron beam evaporation technique using pure WO3 (99.99%) pellets at various substrate temperatures (i.e., Tsub = room temperature (RT, 30 °C), 100 °C and 200 °C). The films were prepared under vacuum of the order of 1 × 10-5 mbar. The room temperature prepared films were further post-heat-treated (Tanne) at 200 and 300 °C for about 1 h in the vacuum environment. The prepared films are in monoclinic phase. The chemical composition has been characterized by using the XPS technique. The W 4f and O 1s core levels of WO3 films have been studied on the samples. The obtained core level binding energies revealed the WO3 films contained six-valent tungsten (W6+). The electrochemical nature of the films was studied by a three-electrode electrochemical cell in the configuration of FTO/WO3/H2SO4/Pt, SCE, using the cyclic voltammetry (CV) technique. Electrochromic devices (ECDs) of the general type FTO/WO3/electrolyte/FTO were studied. The films produced at higher substrate temperature show smaller modulation of the visible spectrum, compared with the films produced at lower temperatures. The significant chemical bonding nature associated with the coloring/bleaching process which follows the H+ ion incorporation in the film is studied by FTIR analysis. The W-O-W framework peak was observed at 563 cm-1 and confirms the stability of the films in the electrochemical analysis. The results obtained from cyclic voltammetry technique and ECD cell characterization are used to emphasize the suitability for some applications of the solar control systems.

  20. Preparation, characterization and photocatalytic behavior of WO3-fullerene/TiO2 catalysts under visible light

    PubMed Central

    2011-01-01

    WO3-treated fullerene/TiO2 composites (WO3-fullerene/TiO2) were prepared using a sol-gel method. The composite obtained was characterized by BET surface area measurements, X-ray diffraction, scanning electron microscopy, energy dispersive X-ray analysis, transmission electron microscopy, and UV-vis analysis. A methyl orange (MO) solution under visible light irradiation was used to determine the photocatalytic activity. Excellent photocatalytic degradation of a MO solution was observed using the WO3-fullerene, fullerene-TiO2, and WO3-fullerene/TiO2 composites under visible light. An increase in photocatalytic activity was observed, and WO3-fullerene/TiO2 has the best photocatalytic activity; it may attribute to the increase of the photo-absorption effect by the fullerene and the cooperative effect of the WO3. PMID:21774800

  1. Comparative studies of monoclinic and orthorhombic WO3 films used for hydrogen sensor fabrication on SiC crystal

    NASA Astrophysics Data System (ADS)

    Zuev, V. V.; Grigoriev, S. N.; Romanov, R. I.; Fominski, V. Y.; Volosova, M. A.; Demin, M. V.

    2016-09-01

    Amorphous WOx films were prepared on the SiC crystal by using two different methods, namely, reactive pulsed laser deposition (RPLD) and reactive deposition by ion sputtering (RDIS). After deposition, the WOx films were annealed in an air. The RISD film possessed a m-WO3 structure and consisted of closely packed microcrystals. Localized swelling of the films and micro-hills growth did not destroy dense crystal packing. RPLD film had layered β-WO3 structure with relatively smooth surface. Smoothness of the films were destroyed by localized swelling and the micro-openings formation was observed. Comparative study of m-WO3/SiC, Pt/m-WO3/SiC, and P-WO3/SiC samples shows that structural characteristics of the WO3 films strongly influence on the voltage/current response as well as on the rate of current growth during H2 detection at elevated temperatures.

  2. Integrated GPS/INS for aerospace application

    NASA Astrophysics Data System (ADS)

    Faruqi, Farhan A.; Turner, Kenneth J.; Pickering, Michael B.

    1995-06-01

    The Integrated Global Positioning System (GPS)/Inertial Navigation System (INS) is a cost effective way of providing an accurate and reliable navigation system for civil and military aviation. These systems also provide low cost solutions to mid-course navigation and guidance of medium and long range weapon systems. In this paper an error model is developed which can be used for GPS/INS filter mechanization. It is known that the model has a linear and a non-linear part. The latter consist of a quadratic function of system states and may be approximated by a noise term thereby allowing the use of the well known Kalman Filter (KF) design technique. KF algorithm suitable for this application is also developed, and computer simulation results for a typical aerospace application are given.

  3. Improved thermal force modeling for GPS satellites

    NASA Technical Reports Server (NTRS)

    Vigue, Y.; Schutz, R. E.; Abusali, P. A. M.

    1993-01-01

    Geophysical applications of the Global Positioning System (GPS) require the capability to estimate and propagate satellite orbits with high precision. An accurate model of all the forces acting on a satellite is an essential part of achieving high orbit accuracy. Methods of analyzing the perturbation due to thermal radiation and determining its effects on the long-term orbital behavior of GPS satellites are presented. The thermal imbalance force, a nongravitational orbit perturbation previously considered negligible, is the focus of this article. The earth's shadowing of a satellite in orbit causes periodic changes in the satellite's thermal environment. Simulations show that neglecting thermal imbalance in the satellite force model gives orbit error larger than ten meters over several days for eclipsing satellites. This orbit mismodeling can limit accuracy in orbit determination and in estimation of baselines used for geophysical applications.

  4. High dynamic GPS receiver validation demonstration

    NASA Technical Reports Server (NTRS)

    Hurd, W. J.; Statman, J. I.; Vilnrotter, V. A.

    1985-01-01

    The Validation Demonstration establishes that the high dynamic Global Positioning System (GPS) receiver concept developed at JPL meets the dynamic tracking requirements for range instrumentation of missiles and drones. It was demonstrated that the receiver can track the pseudorange and pseudorange rate of vehicles with acceleration in excess of 100 g and jerk in excess of 100 g/s, dynamics ten times more severe than specified for conventional High Dynamic GPS receivers. These results and analytic extensions to a complete system configuration establish that all range instrumentation requirements can be met. The receiver can be implemented in the 100 cu in volume required by all missiles and drones, and is ideally suited for transdigitizer or translator applications.

  5. Estimation of nutation using the GPS

    NASA Astrophysics Data System (ADS)

    Weber, R.

    GPS data has proven to be a valuable source for the determination of accurate ERP series. This series are of high quality mainly due to the uninterrupted coverage with observation data and the more or less regular distribution of the active IGS tracking sites. In February 1994 CODE, one of the seven analysis centers of the IGS, started to derive nutation rates in addition to the routinely estimated polar motion and UT1-UTC rates. In 1999, a set of nutation amplitude corrections for 34 periods with respect to the IERS96 model as well as to the IAU1980 model was presented in (Rothacher et al., 1999) based on 3.5 years of data. It has been demonstrated that GPS is especially sensitive to periods up to about 20 days. This presentation deals with preliminary results of the most recent update of the published amplitude corrections by taking into account 6 years of observation data.

  6. Regional Deformation Studies with GRACE and GPS

    NASA Technical Reports Server (NTRS)

    Davis, J. L.; Elosequi, P.; Tamisiea, M.; Mitrovica, J. X.

    2005-01-01

    GRACE data indicate large seasonal variations in gravity that have been shown to be to be related to climate-driven fluxes of surface water. Seasonal redistribution of surface mass deforms the Earth, and our previous study using GRACE data demonstrate that annual radial deformations of +/-13 mm in the region of Amazon River Basin were observed by both GRACE and ten GPS sites in the region. For the GRACE determinations, we estimate in a least-squares solution for each Stokes coefficient parameters that represent the amplitudes of the annual variation. We then filter these parameters based on a statistical test that uses the scatter of the postfit residuals. We demonstrate by comparison to the GPS amplitudes that this method is more accurate, for this region, than Gaussian smoothing. Our model for the temporal behavior of the gravity coefficients includes a rate term, and although the time series are noisy, the glacial isostatic adjustment signal over Hudson s Bay can be observed. .

  7. Digital Signal Processor For GPS Receivers

    NASA Technical Reports Server (NTRS)

    Thomas, J. B.; Meehan, T. K.; Srinivasan, J. M.

    1989-01-01

    Three innovative components combined to produce all-digital signal processor with superior characteristics: outstanding accuracy, high-dynamics tracking, versatile integration times, lower loss-of-lock signal strengths, and infrequent cycle slips. Three components are digital chip advancer, digital carrier downconverter and code correlator, and digital tracking processor. All-digital signal processor intended for use in receivers of Global Positioning System (GPS) for geodesy, geodynamics, high-dynamics tracking, and ionospheric calibration.

  8. Counterrotator And Correlator For GPS Receivers

    NASA Technical Reports Server (NTRS)

    Thomas, J. Brooks; Srinivasan, Jeffrey M.; Meehan, Thomas K.

    1989-01-01

    Accurate, all-digital, high-speed processor comprising correlator and down-converter developed for receivers in Global Positioning System (GPS). Processor reduces roundoff and commensurability errors to extremely small values. Use of digital chip and phase advancers provides outstanding control and accuracy in phase and feedback. Great flexibility imparted by provision for arbitrary starting time and integration length. Minimum-bit design requires minimum number of logical elements, thereby reducing size, power, and cost.

  9. Measuring Orientation Of The Earth With GPS

    NASA Technical Reports Server (NTRS)

    Freedman, Adam P.

    1992-01-01

    Report discusses feasibility of using Global Positioning System (GPS) to resolve short-term fluctuations (days or hours) in locations of points on crust of Earth to within centimeters or millimeters. With full constellation of satellites and ground receiving stations, system provides rapid (within 12 hours) determinations of variations in orientation. Measurements used to enhance precision of spacecraft navigation and in geophysical and meteorological studies of daily exchanges of angular momentum among fluid core, crust and mantle, oceans, and atmosphere.

  10. Comparison of LASSO and GPS time transfers

    NASA Technical Reports Server (NTRS)

    Lewandowski, W.; Petit, G.; Baumont, F.; Fridelance, P.; Gaignebet, J.; Grudler, P.; Veillet, C.; Wiant, J.; Klepczynski, W. J.

    1994-01-01

    The LASSO is a technique which should allow the comparison of remote atomic clocks with sub-nanosecond precision and accuracy. The first successful time transfer using LASSO has been carried out between the Observatoire de la Cote d'Azur in France and the McDonald Observatory in Texas, United States. This paper presents a preliminary comparison of LASSO time transfer with GPS common-view time transfer.

  11. Continuous GPS Carrier-Phase Time Transfer

    NASA Astrophysics Data System (ADS)

    Yao, Jian

    Time transfer (TT) is the process of transmitting a timing signal from one place to another place. It has applications to the formation and realization of Coordinated Universal Time (UTC), telecommunications, electrical power grids, and even stock exchanges. TT is the actual bottleneck of the UTC formation and realization since the technology of atomic clocks is almost always ahead of that of TT. GPS carrier-phase time transfer (GPSCPTT), as a mainstream TT technique accepted by most national timing laboratories, has suffered from the day-boundary-discontinuity (day-BD) problem for many years. This makes us difficult to observe a remote Cesium fountain clock behavior even after a few days. We find that day-BD comes from the GPS code noise. The day-BD can be lowered by ˜40% if more satellite-clock information is provided and if a few GPS receivers at the same station are averaged. To completely eliminate day-BD, the RINEX-Shift (RS) and revised RS (RRS) algorithms have been designed. The RS/RRS result matches the two-way satellite time/frequency transfer (TWSTFT) result much better than the conventional GPSCPTT result. With the RS/RRS algorithm, we are able to observe a remote Cesium fountain after half a day. We also study the BD due to GPS data anomalies (anomaly-BD). A simple curve-fitting strategy can eliminate the anomaly-BD. Thus, we achieve continuous GPSCPTT after eliminating both day-BD and anomaly-BD.

  12. Global Geodesy Using GPS Without Fiducial Sites

    NASA Technical Reports Server (NTRS)

    Heflin, Michael B.; Blewitt, Geoffrey

    1994-01-01

    Global Positioning System, GPS, used to make global geodetic measurements without use of fiducial site coordinates. Baseline lengths and geocentric radii for each site determined without having to fix any site coordinates. Given n globally distributed sites, n baseline lengths and n geocentric radii form polyhedron with each site at vertex and with geocenter at intersection of all radii. Geodetic information derived from structure of polyhedron and its change with time. Approach applied to any global geodetic technique.

  13. Kinematic GPS Profiles to monitor surface deformation

    NASA Astrophysics Data System (ADS)

    Charara, R.; Vigny, C.; Briole, P.

    2008-12-01

    GPS kinematic measurement consists in placing a GPS rover receiver that registers its position on a moving vehicule with a high frequency. The frequency of the data acquisition is chosen according to the number of points and the precision needed to characterize the rover trajectory. The position of the rover receiver can be determined with respect to another GPS reference station with a precision of a few centimeters. Consequently different kinematic profiles on trajectories can be realized in different contexts (volcano slopes, active faults,...). We first studied the correlation between different profiles on the same trajectory in the absense of any particular event. Then different individual profiles are interpolated and a single profiles is generated which we refer to as "tube". We also studied and analyzed the impact of different parameters such as the baseline length, the atmospheric errors and the number of individual profiles on the precision of the obtained tube. We present results of experimentations that were performed in Chili, Reunion Island and Greece and we show how the results can be influenced by the baselines lengths and topographies. In case of event (Earthquakes, volcanoes eruptions, landslides,...) this technique can be used to assess the amplitude of ground deformation. We estimate the thresholds (in term of amplitude and spatial extension) of detectable signals.

  14. Ionospheric scintillation effects on single frequency GPS

    NASA Astrophysics Data System (ADS)

    Steenburgh, R. A.; Smithtro, C. G.; Groves, K. M.

    2008-04-01

    Ionospheric scintillation of Global Positioning System (GPS) signals threatens navigation and military operations by degrading performance or making GPS unavailable. Scintillation is particularly active within, although not limited to, a belt encircling the Earth within 20 degrees of the geomagnetic equator. As GPS applications and users increase, so does the potential for degraded precision and availability from scintillation. We examined amplitude scintillation data spanning 7 years from Ascension Island, U.K.; Ancon, Peru; and Antofagasta, Chile in the Atlantic/American longitudinal sector as well as data from Parepare, Indonesia; Marak Parak, Malaysia; Pontianak, Indonesia; Guam; and Diego Garcia, U.K. in the Pacific longitudinal sector. From these data, we calculate percent probability of occurrence of scintillation at various intensities described by the S4 index. Additionally, we determine Dilution of Precision at 1 min resolution. We examine diurnal, seasonal, and solar cycle characteristics and make spatial comparisons. In general, activity was greatest during the equinoxes and solar maximum, although scintillation at Antofagasta, Chile was higher during 1998 rather than at solar maximum.

  15. Time and position accuracy using codeless GPS

    NASA Technical Reports Server (NTRS)

    Dunn, C. E.; Jefferson, D. C.; Lichten, S. M.; Thomas, J. B.; Vigue, Y.; Young, L. E.

    1994-01-01

    The Global Positioning System has allowed scientists and engineers to make measurements having accuracy far beyond the original 15 meter goal of the system. Using global networks of P-Code capable receivers and extensive post-processing, geodesists have achieved baseline precision of a few parts per billion, and clock offsets have been measured at the nanosecond level over intercontinental distances. A cloud hangs over this picture, however. The Department of Defense plans to encrypt the P-Code (called Anti-Spoofing, or AS) in the fall of 1993. After this event, geodetic and time measurements will have to be made using codeless GPS receivers. However, there appears to be a silver lining to the cloud. In response to the anticipated encryption of the P-Code, the geodetic and GPS receiver community has developed some remarkably effective means of coping with AS without classified information. We will discuss various codeless techniques currently available and the data noise resulting from each. We will review some geodetic results obtained using only codeless data, and discuss the implications for time measurements. Finally, we will present the status of GPS research at JPL in relation to codeless clock measurements.

  16. Cleaning HI Spectra Contaminated by GPS RFI

    NASA Astrophysics Data System (ADS)

    Sylvia, Kamin; Hallenbeck, Gregory L.; Undergraduate ALFALFA Team

    2016-01-01

    The NUDET systems aboard GPS satellites utilize radio waves to communicate information regarding surface nuclear events. The system tests appear in spectra as RFI (radio frequency interference) at 1381MHz, which contaminates observations of extragalactic HI (atomic hydrogen) signals at 50-150 Mpc. Test durations last roughly 20-120 seconds and can occur upwards of 30 times during a single night of observing. The disruption essentially renders the corresponding HI spectra useless.We present a method that automatically removes RFI in HI spectra caused by these tests. By capitalizing on the GPS system's short test durations and predictable frequency appearance we are able to devise a method of identifying times containing compromised data records. By reevaluating the remaining data, we are able to recover clean spectra while sacrificing little in terms of sensitivity to extragalactic signals. This method has been tested on 500+ spectra taken by the Undergraduate ALFALFA Team (UAT), in which it successfully identified and removed all sources of GPS RFI. It will also be used to eliminate RFI in the upcoming Arecibo Pisces-Perseus Supercluster Survey (APPSS).This work has been supported by NSF grant AST-1211005.

  17. Effect of fluorine, nitrogen, and carbon impurities on the electronic and magnetic properties of WO{sub 3}

    SciTech Connect

    Shein, I. R.; Ivanovskii, A. L.

    2013-06-15

    Within electron density functional theory with the use of the Vienna ab-initio simulation package (VASP), the effect of the sp substitutional impurities of fluorine (n-type dopant), nitrogen, and carbon (p-type dopants) on the electronic and magnetic properties of tungsten trioxide WO{sub 3} is studied. It is established that these impurities induce the transformation of tungsten trioxide (nonmagnetic semiconductor) into nonmagnetic metal (WO{sub 3}:F), magnetic semimetal (WO{sub 3}:N), or magnetic metal (WO{sub 3}:C) states.

  18. Inductive effect of poly(vinyl pyrrolidone) on morphology and photocatalytic performance of Bi2WO6

    NASA Astrophysics Data System (ADS)

    Zhang, Qiang; Chen, Jinxing; Xie, Yunyun; Wang, Mozhen; Ge, Xuewu

    2016-04-01

    Bi2WO6 has great potential applications in the field of photocatalyst due to its excellent visible-light photocatalytic performance. This work studied the detailed morphological evolution of Bi2WO6 particles synthesized in a simple hydrothermal system induced by the stabilizer poly(vinyl pyrrolidone) (PVP). The XRD and HRTEM results show PVP would not change the crystal structure of Bi2WO6, but the distribution of PVP on the initially formed Bi2WO6 nanosheets will induce the crystal growth, resulting in a distinct morphology evolution of Bi2WO6 with the increase of the concentration of PVP. At the same time, with the increase of the molecular weight of PVP, the morphology of Bi2WO6 varied from simple sheet-like (S-BWO) to some complicated morphology, such as flower-like (F-BWO), red blood cell-like (B-BWO), and square-pillar-like (SP-BWO). The photocatalytic performances of Bi2WO6 with various morphologies on the decomposition of RhB under visible light irradiation reveal that S-BWO has the best photocatalytic performance, while SP-BWO has the worst. This work not only gives the explanation of the inductive effect of PVP molecular chains on the morphological formation of Bi2WO6 particles, but also provides the controllable way to the preparation of Bi2WO6 with various morphologies taking advantage of the stabilizer PVP.

  19. Using GPS to Detect Imminent Tsunamis

    NASA Technical Reports Server (NTRS)

    Song, Y. Tony

    2009-01-01

    A promising method of detecting imminent tsunamis and estimating their destructive potential involves the use of Global Positioning System (GPS) data in addition to seismic data. Application of the method is expected to increase the reliability of global tsunami-warning systems, making it possible to save lives while reducing the incidence of false alarms. Tsunamis kill people every year. The 2004 Indian Ocean tsunami killed about 230,000 people. The magnitude of an earthquake is not always a reliable indication of the destructive potential of a tsunami. The 2004 Indian Ocean quake generated a huge tsunami, while the 2005 Nias (Indonesia) quake did not, even though both were initially estimated to be of the similar magnitude. Between 2005 and 2007, five false tsunami alarms were issued worldwide. Such alarms result in negative societal and economic effects. GPS stations can detect ground motions of earthquakes in real time, as frequently as every few seconds. In the present method, the epicenter of an earthquake is located by use of data from seismometers, then data from coastal GPS stations near the epicenter are used to infer sea-floor displacements that precede a tsunami. The displacement data are used in conjunction with local topographical data and an advanced theory to quantify the destructive potential of a tsunami on a new tsunami scale, based on the GPS-derived tsunami energy, much like the Richter Scale used for earthquakes. An important element of the derivation of the advanced theory was recognition that horizontal sea-floor motions contribute much more to generation of tsunamis than previously believed. The method produces a reliable estimate of the destructive potential of a tsunami within minutes typically, well before the tsunami reaches coastal areas. The viability of the method was demonstrated in computational tests in which the method yielded accurate representations of three historical tsunamis for which well-documented ground

  20. Synthesis and photoactivity enhancement of Ba doped Bi{sub 2}WO{sub 6} photocatalyst

    SciTech Connect

    Li, Wen Ting; Huang, Wan Zhen; Zhou, Huan; Yin, Hao Yong; Zheng, Yi Fan; Song, Xu Chun

    2015-04-15

    Highlights: • The Ba-doped Bi{sub 2}WO{sub 6} photocatalyst have been synthesized by a hydrothermal route. • The photocatalytic activity of Bi{sub 2}WO{sub 6} was greatly enhanced by Ba-doping. • The effect of Ba on the catalytic activity of Bi{sub 2}WO{sub 6} was studied and discussed. - Abstract: In this study, Bi{sub 2}WO{sub 6} doped with different barium contents were successfully prepared by a simple hydrothermal route at 180 °C for 12 h. The as-synthesized samples were characterized in detailed by X-ray powder diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), UV–vis diffusere flectance spectroscopy (UV–vis DRS) and Brunauer–Emmet–Teller (BET) theory. Their photocatalytic activities were evaluated by photodegradation of Rhodamine B (RhB) under simulated solar light. As a result, the photocatalytic properties were enhanced after Ba doping and the Ba-doped Bi{sub 2}WO{sub 6} with R{sub Ba} = 0.15 showed the highest photocatalytic activities of 96.3% RhB was decomposed in 50 min. Close investigation revealed that the proper Ba doped into Bi{sub 2}WO{sub 6} could not only increases its BET surface area, decrease its crystalline size, but also act as electron traps and facilitate the separation of photogenerated electron–hole pairs. The mechanism of enhanced photocatalytic activities of Ba-doped Bi{sub 2}WO{sub 6} were further investigated.

  1. WO-Type Wolf-Rayet Stars: the Last Hurrah of the Most Massive Stars?

    NASA Astrophysics Data System (ADS)

    Massey, Philip

    2014-10-01

    WO-type Wolf-Rayet (WR) stars are considered the final evolutionary stage of the highest mass stars, immediate precursors to Type Ic (He-poor) core-collapse supernovae. These WO stars are rare, and until recently only 6 were known. Our knowledge about their physical properties is mostly based on a single object, Sand 2 in the LMC. It was the only non-binary WO star both bright and unreddened enough that its FUV and NUV spectra could be obtained by FUSE and HST/FOS. A non-LTE analysis showed that Sand 2 is very hot and its (C+O)/He abundance ratio is higher than that found in WC-type WRs, suggesting it is indeed highly evolved. However, the O VI resonance doublet in the FUV required a considerably cooler temperature (120,000 K) model than did the optical O VI lines (170,000 K). Further, the enhanced chemical abundances did not match the predictions of stellar evolutionary models. Another non-LTE study found a 3x higher (C+O)/He abundance ratio and a cooler temperature. We have recently discovered two other bright, single, and lightly reddened WOs in the LMC, allowing us to take a fresh look at these important objects. Our newly found WOs span a range in excitation type, from WO1 (the highest) to WO4 (the lowest). Sand 2 is intermediate (WO3). We propose to use COS to obtain FUV and NUV data of all three stars for as comprehensive a study as is currently possible. These UV data will be combined with our optical Magellan spectra for a detailed analysis with CMFGEN with the latest atomic data. Knowing the degree of chemical evolution of these WO stars is crucial to determining their evolutionary status, and thus in understanding the final stages of the most massive stars.

  2. The performance analysis of a real-time integrated INS/GPS vehicle navigation system with abnormal GPS measurement elimination.

    PubMed

    Chiang, Kai-Wei; Duong, Thanh Trung; Liao, Jhen-Kai

    2013-08-15

    The integration of an Inertial Navigation System (INS) and the Global Positioning System (GPS) is common in mobile mapping and navigation applications to seamlessly determine the position, velocity, and orientation of the mobile platform. In most INS/GPS integrated architectures, the GPS is considered to be an accurate reference with which to correct for the systematic errors of the inertial sensors, which are composed of biases, scale factors and drift. However, the GPS receiver may produce abnormal pseudo-range errors mainly caused by ionospheric delay, tropospheric delay and the multipath effect. These errors degrade the overall position accuracy of an integrated system that uses conventional INS/GPS integration strategies such as loosely coupled (LC) and tightly coupled (TC) schemes. Conventional tightly coupled INS/GPS integration schemes apply the Klobuchar model and the Hopfield model to reduce pseudo-range delays caused by ionospheric delay and tropospheric delay, respectively, but do not address the multipath problem. However, the multipath effect (from reflected GPS signals) affects the position error far more significantly in a consumer-grade GPS receiver than in an expensive, geodetic-grade GPS receiver. To avoid this problem, a new integrated INS/GPS architecture is proposed. The proposed method is described and applied in a real-time integrated system with two integration strategies, namely, loosely coupled and tightly coupled schemes, respectively. To verify the effectiveness of the proposed method, field tests with various scenarios are conducted and the results are compared with a reliable reference system.

  3. The Performance Analysis of a Real-Time Integrated INS/GPS Vehicle Navigation System with Abnormal GPS Measurement Elimination

    PubMed Central

    Chiang, Kai-Wei; Duong, Thanh Trung; Liao, Jhen-Kai

    2013-01-01

    The integration of an Inertial Navigation System (INS) and the Global Positioning System (GPS) is common in mobile mapping and navigation applications to seamlessly determine the position, velocity, and orientation of the mobile platform. In most INS/GPS integrated architectures, the GPS is considered to be an accurate reference with which to correct for the systematic errors of the inertial sensors, which are composed of biases, scale factors and drift. However, the GPS receiver may produce abnormal pseudo-range errors mainly caused by ionospheric delay, tropospheric delay and the multipath effect. These errors degrade the overall position accuracy of an integrated system that uses conventional INS/GPS integration strategies such as loosely coupled (LC) and tightly coupled (TC) schemes. Conventional tightly coupled INS/GPS integration schemes apply the Klobuchar model and the Hopfield model to reduce pseudo-range delays caused by ionospheric delay and tropospheric delay, respectively, but do not address the multipath problem. However, the multipath effect (from reflected GPS signals) affects the position error far more significantly in a consumer-grade GPS receiver than in an expensive, geodetic-grade GPS receiver. To avoid this problem, a new integrated INS/GPS architecture is proposed. The proposed method is described and applied in a real-time integrated system with two integration strategies, namely, loosely coupled and tightly coupled schemes, respectively. To verify the effectiveness of the proposed method, field tests with various scenarios are conducted and the results are compared with a reliable reference system. PMID:23955434

  4. GPS Modeling and Analysis. Summary of Research: GPS Satellite Axial Ratio Predictions

    NASA Technical Reports Server (NTRS)

    Axelrad, Penina; Reeh, Lisa

    2002-01-01

    This report outlines the algorithms developed at the Colorado Center for Astrodynamics Research to model yaw and predict the axial ratio as measured from a ground station. The algorithms are implemented in a collection of Matlab functions and scripts that read certain user input, such as ground station coordinates, the UTC time, and the desired GPS (Global Positioning System) satellites, and compute the above-mentioned parameters. The position information for the GPS satellites is obtained from Yuma almanac files corresponding to the prescribed date. The results are displayed graphically through time histories and azimuth-elevation plots.

  5. Specification of a NAVSTAR Global Positioning System (GPS) receiver for a differential GPS ground system

    NASA Technical Reports Server (NTRS)

    Mccall, D. L.; Turner, R. N.

    1984-01-01

    One step towards the successful completion of a functional ground unit for the Differential Global Positioning System (DGPS) will be in choosing a currently available GPS receiver that will accurately measure the propagation times of the satellite signals and have the capability to be electrically interfaced with and controlled by a Digital Equipment Corporation (DEC) PDP-11/34A computer. The minimum requirements and characteristics of a NAVSTAR Global Positioning System (GPS) receiver are described. The specific technical specifications addressed include data accuracies and resolutions, receiver interface/external control, enclosure dimensions and mounting requirements, receiver operation, and environmental specifications.

  6. A New Ionosphere Monitoring Technology Based on GPS

    NASA Astrophysics Data System (ADS)

    Brunini, Claudio; Meza, Amalia; Azpilicueta, Francisco; van Zele, María Andrea; Gende, Mauricio; Díaz, Alejandro

    2004-04-01

    Although global positioning system (GPS) was originally planned as a satellite-based radio-navigation system for military purposes, civilian users have significantly increased their access to the system for both, commercial and scientific applications. Almost 400 permanent GPS tracking stations have been stablished around the globe with the main purpose of supporting scientific research. In addition, several GPS receivers on board of low Earth orbit satellites fitted with special antennas that focus on Earth’s horizon, are tracking the radio signals broadcasted by the high-orbiting GPS satellites, as they rise and set on Earth horizon. The data of these ground and space-born GPS receivers, readily accessible through Internet in a ‘virtual observatory’ managed by the International GPS Service, are extensively used for many researches and might possibly ignite a revolution in Earth remote sensing.

  7. Precise estimation of tropospheric path delays with GPS techniques

    NASA Technical Reports Server (NTRS)

    Lichten, S. M.

    1990-01-01

    Tropospheric path delays are a major source of error in deep space tracking. However, the tropospheric-induced delay at tracking sites can be calibrated using measurements of Global Positioning System (GPS) satellites. A series of experiments has demonstrated the high sensitivity of GPS to tropospheric delays. A variety of tests and comparisons indicates that current accuracy of the GPS zenith tropospheric delay estimates is better than 1-cm root-mean-square over many hours, sampled continuously at intervals of six minutes. These results are consistent with expectations from covariance analyses. The covariance analyses also indicate that by the mid-1990s, when the GPS constellation is complete and the Deep Space Network is equipped with advanced GPS receivers, zenith tropospheric delay accuracy with GPS will improve further to 0.5 cm or better.

  8. Application of GPS attitude determination to gravity gradient stabilized spacecraft

    NASA Technical Reports Server (NTRS)

    Lightsey, E. G.; Cohen, Clark E.; Parkinson, Bradford W.

    1993-01-01

    Recent advances in the Global Positioning System (GPS) technology have initiated a new era in aerospace navigation and control. GPS receivers have become increasingly compact and affordable, and new developments have made attitude determination using subcentimeter positioning among two or more antennas feasible for real-time applications. GPS-based attitude control systems will become highly portable packages which provide time, navigation, and attitude information of sufficient accuracy for many aerospace needs. A typical spacecraft application of GPS attitude determination is a gravity gradient stabilized satellite in low Earth orbit that employs a GPS receiver and four body mounted patch antennas. The coupled, linearized equations of motion enable complete position and attitude information to be extracted from only two antennas. A discussion of the various error sources for spaceborne GPS attitude measurement systems is included. Attitude determination of better than 0.3 degrees is possible for 1 meter antenna separation. Suggestions are provided to improve the accuracy of the attitude solution.

  9. Precise Orbit Determination of GPS Satellites Using Phase Observables

    NASA Astrophysics Data System (ADS)

    Jee, Myung-Kook; Choi, Kyu-Hong; Park, Pil-Ho

    1997-12-01

    The accuracy of user position by GPS is heavily dependent upon the accuracy of satellite position which is usually transmitted to GPS users in radio signals. The real-time satellite position information directly obtained from broadcast ephimerides has the accuracy of 3 x 10 meters which is very unsatisfactory to measure 100km baseline to the accuracy of less than a few mili-meters. There are globally at present seven orbit analysis centers capable of generating precise GPS ephimerides and their orbit quality is of the order of about 10cm. Therefore, precise orbit model and phase processing technique were reviewed and consequently precise GPS ephimerides were produced after processing the phase observables of 28 global GPS stations for 1 day. Initial 6 orbit parameters and 2 solar radiation coefficients were estimated using batch least square algorithm and the final results were compared with the orbit of IGS, the International GPS Service for Geodynamics.

  10. Structural, vibrational and luminescence properties of the (1−x)CaWO{sub 4}−xCdWO{sub 4} system

    SciTech Connect

    Taoufyq, A.; Guinneton, F.; Valmalette, J-C.; Arab, M.; Benlhachemi, A.; Bakiz, B.; Villain, S.; and others

    2014-11-15

    In the present work, we investigate the structural, microstructural, vibrational and luminescence properties of the system (1−x)CaWO{sub 4}−xCdWO{sub 4} with x ranging between 0 and 1. Polycrystalline samples were elaborated using a coprecipitation technique followed by thermal treatment at 1000 °C. The samples were then characterized using X-ray diffraction, scanning electron microscopy, Raman spectroscopy and luminescence analyses. X-ray diffraction profile analyses using Rietveld method showed that two kinds of solid solutions Ca{sub 1−x}Cd{sub x}WO{sub 4} having scheelite and wolframite structures, with respectively tetragonal and monoclinic crystal cells, were observed, with a biphasic system for compositions x=0.6 and 0.7. The scanning electron microscopy experiments showed a complex evolution of morphologies and crystallite sizes as x increased. The vibration modes of Raman spectra were characteristic of composition-dependent disordered solid solutions with decreasing wavenumbers as x increased. Luminescence experiments were performed under UV-laser light irradiation. The energies of emission bands increased linearly with cadmium composition x. The integrated intensity of luminescence reached a maximum value for the substituted wolframite phase with composition x=0.8. - Graphical abstract: Luminescence on UV excitation (364.5 nm) of (1−x)CaWO{sub 4−x}CdWO{sub 4} system, elaborated from coprecipitation technique at 1000 °C, with 0WO{sub 4} polycrystalline phases with 0≤x≤0.5. (b) Maximum of luminescence intensity for the composition x=0.8. - Highlights: • Solid solutions Ca{sub 1−x}Cd{sub x}WO{sub 4} are elaborated from coprecipitation technique. • The structures of two types of solid solutions are refined using Rietveld method. • A maximum of luminescence is obtained for an intermediate composition x=0.8.

  11. Harnessing and storing visible light using a heterojunction of WO3 and CdS for sunlight-free catalysis.

    PubMed

    Kim, Seonghun; Park, Yiseul; Kim, Wooyul; Park, Hyunwoong

    2016-08-01

    CdS and WO3 (CdS/WO3) bilayer film electrodes are fabricated to harness solar visible light (λ > 420 nm) and store photogenerated electrons for possible use during periods of unavailable sunlight. The overall film thickness is approximately 50-60 μm, while the CdS underlayer is slightly thinner than WO3 owing to a packing effect. The energetics of CdS and WO3 determined by optical and electrochemical analyses enables cascaded electron transfer from CdS to WO3. The open circuit potential (EOCP) of CdS/WO3 under visible light (approximately -0.35 V vs. SCE) is nearly maintained even in the absence of light, with a marginal decrease (∼0.15 V) in ∼20 h of darkness. Neither CdS nor WO3 alone exhibits such behavior. The electron lifetimes (τ) of CdS and WO3 are each less than 100 s, whereas coupling of the two increases τ to ∼2500 s at the EOCP. In the absence of dissolved O2, τ further increases, suggesting that O2 is the primary electron acceptor. In spite of oxic conditions, CdS/WO3 is capable of continuously reducing Cr(6+) to Cr(3+) and Ag(+) to Ag(0) after removal of visible light. The number of utilized (i.e., stored) electrons in the reductions of Cr(6+) and Ag(+) are estimated to be ∼1.08 × 10(17) and ∼0.87 × 10(17), respectively. The primary role of CdS is to be a visible-light absorber in the 420-565 nm wavelength range, transferring the photogenerated electrons to WO3. The electrons stored in WO3 are gradually released to electron acceptors with suitable redox potentials. PMID:27411566

  12. Method and apparatus for relative navigation using reflected GPS signals

    NASA Technical Reports Server (NTRS)

    Cohen, Ian R. (Inventor); Boegner, Jr., Gregory J. (Inventor)

    2010-01-01

    A method and system to passively navigate an orbiting moving body towards an orbiting target using reflected GPS signals. A pair of antennas is employed to receive both direct signals from a plurality of GPS satellites and a second antenna to receive GPS signals reflected off an orbiting target. The direct and reflected signals are processed and compared to determine the relative distance and position of the orbiting moving body relative to the orbiting target.

  13. GPS Antenna Characterization Experiment (ACE): Receiver Design and Initial Results

    NASA Technical Reports Server (NTRS)

    Martzen, Phillip; Highsmith, Dolan E.; Valdez, Jennifer E.; Parker, Joel J. K.; Moreau, Michael C.

    2015-01-01

    The GPS Antenna Characterization Experiment (ACE) is a research collaboration between Aerospace and NASA Goddard to characterize the gain patterns of the GPS L1 transmit antennas. High altitude GPS observations are collected at a ground station through a transponder-based or "bent-pipe" architecture where the GPS L1 RF spectrum is received at a platform in geosynchronous orbit and relayed to the ground for processing. The focus of this paper is the unique receiver algorithm design and implementation. The high-sensitivity GPS C/A-code receiver uses high fidelity code and carrier estimates and externally supplied GPS message bit data in a batch algorithm with settings for a 0 dB-Hz threshold. The resulting carrier-to-noise measurements are used in a GPS L1 transmit antenna pattern reconstruction. This paper shows initial transmit gain patterns averaged over each block of GPS satellites, including comparisons to available pre-flight gain measurements from the GPS vehicle contractors. These results provide never-before-seen assessments of the full, in-flight transmit gain patterns.

  14. Persons with Dementia and Their Caregivers Using GPS.

    PubMed

    Øderud, Tone; Landmark, Bjørg; Eriksen, Sissel; Fossberg, Anne Berit; Aketun, Sigrid; Omland, May; Hem, Karl-Gerhard; Østensen, Elisabeth; Ausen, Dag

    2015-01-01

    The aim of the study is to generate knowledge on the use of Global Positioning Systems (GPS) to support autonomy and independence for persons with dementia. By studying a larger cohort of persons with dementia (n=208) and their caregivers, this study provides essential knowledge for planning and implementing GPS technology as a part of public health care services. Commercially available GPS technology was provided to the cohort of 208 persons with dementia from nineteen different Norwegian municipalities. The participants used GPS when performing outdoor activities as part of their daily life during a period of time between 2012 and 2014. Their family caregivers were instructed on how to use the GPS technology for locating the participants. The study documents that using GPS for locating persons with dementia provide increased safety for the person with dementia, their family caregivers and their professional caregivers. Furthermore the results confirm that by using GPS, persons with dementia may maintain their autonomy, enjoy their freedom and continue their outdoor activities despite the progression of the disease. Preconditions for successful implementation are that health professionals are trained to assess the participant's needs, that ethical dilemmas are considered, that caregivers have adequate knowledge about using the technology and that procedures and routines for administrating the GPS and locating persons with dementia are established. Early intervention and close collaboration between persons with dementia, family caregivers and professional caregivers are important for successful implementation of GPS in public health care.

  15. Obtaining single path phase delays from GPS double differences

    SciTech Connect

    Alber, C.; Ware, R.; Rocken, C.; Braun, J.

    2000-07-01

    We describe a method for obtaining singlepath phase delays from GPS double differences. The resulting “zero differences” (ZDs) can be used for remote sensing of atmospheric water vapor. The method is demonstrated by simulating and observing atmospheric delay gradients, and by comparing ZDs with pointed radiometer observations of integrated water vapor along GPS ray paths. In-situ GPS antenna phase center and multipath effects are mapped in ZD residuals for a specific site and network. We conclude that ZDs derived from GPS network data show promise for real time sensing of water vapor for use in meteorological modeling and forecasting.

  16. Landslide monitoring using multi-antenna GPS deformation monitoring system

    NASA Astrophysics Data System (ADS)

    Yeh, T.; Hu, Y.; Ding, X.; Chen, C.

    2007-12-01

    GPS has already widely applied in civil engineering, fault detecting and landslide monitoring in the last decade, because of its convenience and high precision. However, GPS receiver is very expensive. If we want to monitor the landslide twenty-four hours a day, we need to buy a lot of GPS receivers. In order to spend less cost, multi- antenna GPS deformation monitoring system was employed to monitor the landslide of the freeway at Guansi section in Taiwan. Moreover, the data from 3D laser scanner, rain gauge, inclinometer and water table meter were utilized to analysis the movement of this landslide to make sure the safety of the drivers.

  17. Continued study of NAVSTAR/GPS for general aviation

    NASA Technical Reports Server (NTRS)

    Alberts, R. D.; Ruedger, W. H.

    1979-01-01

    A conceptual approach for examining the full potential of Global Positioning Systems (GPS) for the general aviation community is presented. Aspects of an experimental program to demonstrate these concepts are discussed. The report concludes with the observation that the true potential of GPS can only be exploited by utilization in concert with a data link. The capability afforded by the combination of position location and reporting stimulates the concept of GPS providing the auxiliary functions of collision avoidance, and approach and landing guidance. A series of general recommendations for future NASA and civil community efforts in order to continue to support GPS for general aviation are included.

  18. Analysis of Adverse Events in Identifying GPS Human Factors Issues

    NASA Technical Reports Server (NTRS)

    Adams, Catherine A.; Hwoschinsky, Peter V.; Adams, Richard J.

    2004-01-01

    The purpose of this study was to analyze GPS related adverse events such as accidents and incidents (A/I), Aviation Safety Reporting System (ASRS) reports and Pilots Deviations (PDs) to create a framework for developing a human factors risk awareness program. Although the occurrence of directly related GPS accidents is small the frequency of PDs and ASRS reports indicated there is a growing problem with situational awareness in terminal airspace related to different types of GPs operational issues. This paper addresses the findings of the preliminary research and a brief discussion of some of the literature on related GPS and automation issues.

  19. Kalman Filtering USNO's GPS Observations for Improved Time Transfer Predictions

    NASA Technical Reports Server (NTRS)

    Hutsell, Steven T.

    1996-01-01

    The Global Positioning System (GPS) Master Control Station (MCS) performs the Coordinated Universal Time (UTC) time transfer mission by uploading and broadcasting predictions of the GPS-UTC offset in subframe 4 of the GS navigation message. These predictions are based on only two successive daily data points obtained from the US Naval Observatory (USNO). USNO produces these daily smoothed data points by performing a least-squares fit on roughly 38 hours worth of data from roughly 160 successive 13-minute tracks of GPS satellites. Though sufficient for helping to maintain a time transfer error specification of 28 ns (1 Sigma), the MCS's prediction algorithm does not make the best use of the available data from from USNO, and produces data that can degrade quickly over extended prediction spans. This paper investigates how, by applying Kalman filtering to the same available tracking data, the MCS could improve its estimate of GPS-UTC, and in particular, the GPS-UTC A(sub 1) term. By refining the A(sub 1) (frequency) estimate for GPS-UTC predictions, error in GPS time transfer could drop significantly. Additional, the risk of future spikes in GPS's time transfer error could similarly be minimized, by employing robust Kalman filtering for GPS-UTC predictions.

  20. GENESIS: GPS Environmental and Earth Science Information System

    NASA Technical Reports Server (NTRS)

    Hajj, George

    1999-01-01

    This presentation reviews the GPS ENvironmental and Earth Science Information System (GENESIS). The objectives of GENESIS are outlined (1) Data Archiving, searching and distribution for science data products derived from Space borne TurboRogue Space Receivers for GPS science and other ground based GPS receivers, (2) Data browsing using integrated visualization tools, (3) Interactive web/java-based data search and retrieval, (4) Data subscription service, (5) Data migration from existing GPS archived data, (6) On-line help and documentation, and (7) participation in the WP-ESIP federation. The presentation reviews the products and services of Genesis, and the technology behind the system.

  1. Autonomous navigation system based on GPS and magnetometer data

    NASA Technical Reports Server (NTRS)

    Julie, Thienel K. (Inventor); Richard, Harman R. (Inventor); Bar-Itzhack, Itzhack Y. (Inventor)

    2004-01-01

    This invention is drawn to an autonomous navigation system using Global Positioning System (GPS) and magnetometers for low Earth orbit satellites. As a magnetometer is reliable and always provides information on spacecraft attitude, rate, and orbit, the magnetometer-GPS configuration solves GPS initialization problem, decreasing the convergence time for navigation estimate and improving the overall accuracy. Eventually the magnetometer-GPS configuration enables the system to avoid costly and inherently less reliable gyro for rate estimation. Being autonomous, this invention would provide for black-box spacecraft navigation, producing attitude, orbit, and rate estimates without any ground input with high accuracy and reliability.

  2. Top seeded solution growth of KHo(WO 4) 2 single crystals

    NASA Astrophysics Data System (ADS)

    Majchrowski, A.; Borowiec, M. T.; Michalski, E.

    2004-03-01

    Monoclinic KHo(WO 4) 2 single crystals have been grown by means of the Top Seeded Solution Growth method from K 2W 2O 7 self-flux containing up to 30 mol% of the crystallized compound. KHo(WO 4) 2 seed was selected from small crystals obtained by spontaneous crystallization and used to grow the first bulky KHo(WO 4) 2 crystal, from which seeds perpendicular to { 1¯ 1 1} and {1 1 0} planes, used in subsequent experiments, were cut out. Crystals grown on these seeds are designated in this paper as 1 1 1 and 1 1 0 crystals, respectively. Properly chosen thermal conditions allowed growth of crystals with one dominating crystallographic plane forming the bottom of the 1 1 1 crystals. Under conditions of very low temperature gradients, growing crystals developed bottoms consisting of several crystallographic planes, while a slightly steeper temperature gradient led to cracking of the growing crystals due to high anisotropy of thermal expansion coefficients, which is characteristic of all double tungstates. It was found that 1 1 1 KHo(WO 4) 2 single crystals were much bulkier than 1 1 0 ones, which had a rectangular cross-section elongated in the c direction. The bottom of 1 1 1 KHo(WO 4) 2 crystals was built of one ( 1¯ 1 1) plane, while in 1 1 0 crystals additional planes appeared that could not be eliminated by increasing the temperature gradient because such an increase led to cracking of crystals. As-grown 1 1 1 and 1 1 0 KHo(WO 4) 2 single crystals were of good quality, free from such defects as bubbles, cracks, and inclusions. The morphology of KHo(WO 4) 2 single crystals was investigated. Miller's indices of crystallographic faces ( h k l ) and edge indices [ u v w ] were found. Positions of the crystallographic axes a, b, and c in relation to growth faces and edges were found as well. The refractive indices and optical axes have been determined. The investigations of absorption spectra of KHo(WO 4) 2 single crystals were performed in a wide spectral range (4000

  3. A Bi2 WO6 -based hybrid photocatalyst with broad spectrum photocatalytic properties under UV, visible, and near-infrared irradiation.

    PubMed

    Tian, Jian; Sang, Yuanhua; Yu, Guangwei; Jiang, Huaidong; Mu, Xiaoning; Liu, Hong

    2013-09-25

    Near-infrared active photocatalytic properties of Bi2 WO6 nanosheets owing to the oxygen vacancies of the Bi2 WO6 nanosheets are reported. The broad spectrum photocatalyst, Bi2 WO6 -TiO2 nanobelt heterostructures, are obtained by assembling Bi2 WO6 nanocrystals on TiO2 nanobelts. The active light band of the novel hybrid photocatalyst with high photocatalytic activity covers full-spectrum solar light including the UV, visible, and near-infrared ranges.

  4. A study of Ti-doped WO3 thin films using comparative theoretical and experimental approach

    NASA Astrophysics Data System (ADS)

    Paez, Aurelio

    Metal oxides like Tungsten Oxide (WO3) are well documented and characterized in the literature, with uses in darkening windows and mirrors, flat computer displays, solar panel cooling, and sensors (of interest in this study). Ti doping of WO3 is less documented and the focus of this study. Sample thin films of pure WO3 and varyingly Ti doped WO3 were prepared using Radio Frequency magnetron sputtering (RF) (13.56 MHz) to grow thin films on a silicon substrate. This study aims to compare multiple Ti doping percentages in WO3 theoretically and then compare with experimental data taken from thin films of various Ti doping levels grown at temperatures ranging from room temperature to 400 0°C. Characterization of the materials was to be conducted using Fourier Transform Infrared Spectroscopy, Raman Spectroscopy, X-ray diffraction, and other theoretical and simulated approaches. Theoretical calculations optimized Ti doping at somewhere between 6.25% and 12%. Experimental data indicates that under the given growing conditions optimal Ti doping is 5%. The percentage of Ti may be able to be increased and the material retain desired characteristics with an increased growth temperature above 400 0°C as annealing samples post-growth has no positive impact on the thin film structure.

  5. Oxygen partial pressure effects on the magnetron sputtered WO3 films

    NASA Astrophysics Data System (ADS)

    Merhan Muğlu, G.; Gür, E.

    2016-04-01

    Electrochromism is changing color of a substance in response to the applied an external electric field and the phenomenon is reversible. WO3 is very attractive material due to its electrochromic properties as well as it is also attractive for many different applications such as gas sensors, phosphorous screen, textile, glass industry. In this study, it is aimed to provide optimization of the optical and structural characteristics of WO3 by changing the growth parameters mainly the oxygen partial pressure. The partial pressure of oxygen was changed with increments of 0.7 mTorr. For the analysis, X-ray Diffraction (XRD), absorption, Raman spectroscopy measurements were used. When O2 gas increased, peaks belong to the WO3 was observed in XRD patterns at the 2 theta angles of 23.0, 11.0, 23.5 and 28.5 angles corresponding to the (002), (020) and (220) planes, respectively. This shows that there is a significant effect of increasing O2 partial pressure in the formation of WO3 films. The bandgap energy of the WO3 thin films are found to be around 3.0 eV. Raman measurements showed vibrational modes of W-O-W stretching and bending modes which shows small shifts depending on the partial pressures of the O2. Obtained results indicated that better crystal structure is obtained with higher O2 gas partial pressure.

  6. Synthesis and characterization of WO{sub 3} spherical nanoparticles and nanorods

    SciTech Connect

    Adhikari, Sangeeta; Sarkar, Debasish Maiti, Himadri Sekhar

    2014-01-01

    Graphical abstract: Two different morphology WO{sub 3} nanoparticles are synthesized by a simple and new wet chemical route through control over pH, temperature and structure directing agents. Reaction mechanism has been proposed for the formation of different morphologies. Nanorod WO{sub 3} has better crystallinity with less specific surface area compared to the spherical nanoparticles. Comparable band gaps are obtained for both the nanoparticles. - Highlights: • Spherical WO{sub 3} nanoparticle and nanorod synthesis mechanisms proposed. • Thermal analysis and spectroscopy confirms the intermediate reactions. • Both of the morphology has pure and monoclinic phase with identical band gap energy. - Abstract: Simple and new wet chemical routes are adopted for the synthesis of tungsten trioxide (WO{sub 3}) nanopowders having two different morphologies such as spherical and rod-like. Acid catalyzed exothermic reaction and a structure directing reagent have been used to control the formation of spherical and rod shaped nanoparticles, respectively. Thermal analysis and FTIR spectral data have been used to confirm the formation of the intermediate and the ultimate reaction products. X-ray and Raman spectroscopic data indicate the monoclinic structure of both forms of the particles. Rod shaped WO{sub 3} particles exhibit better crystallinity and low specific surface area compared to those exhibited by spherical particles. Band gaps are found to be nearly identical irrespective of the morphology.

  7. Structural, electrical and optical properties of TiO 2 doped WO 3 thin films

    NASA Astrophysics Data System (ADS)

    Patil, P. S.; Mujawar, S. H.; Inamdar, A. I.; Shinde, P. S.; Deshmukh, H. P.; Sadale, S. B.

    2005-12-01

    TiO 2 doped WO 3 thin films were deposited onto glass substrates and fluorine doped tin oxide (FTO) coated conducting glass substrates, maintained at 500 °C by pyrolytic decomposition of adequate precursor solution. Equimolar ammonium tungstate ((NH 4) 2WO 4) and titanyl acetyl acetonate (TiAcAc) solutions were mixed together at pH 9 in volume proportions and used as a precursor solution for the deposition of TiO 2 doped WO 3 thin films. Doping concentrations were varied between 4 and 38%. The effect of TiO 2 doping concentration on structural, electrical and optical properties of TiO 2 doped WO 3 thin films were studied. Values of room temperature electrical resistivity, thermoelectric power and band gap energy ( Eg) were estimated. The films with 38% TiO 2 doping in WO 3 exhibited lowest resistivity, n-type electrical conductivity and improved electrochromic performance among all the samples. The values of thermoelectric power (TEP) were in the range of 23-56 μV/K and the direct band gap energy varied between 2.72 and 2.86 eV.

  8. Wolbachia and bacteriophage WO-B density of Wolbachia A-infected Aedes albopictus mosquito.

    PubMed

    Ahantarig, A; Trinachartvanit, W; Chauvatcharin, N; Kittayapong, P; Baimai, V

    2008-01-01

    Wolbachia are maternally inherited symbiotic bacteria capable of inducing an extensive range of reproductive abnormalities in their hosts, including cytoplasmic incompatibility (CI). Its density (concentration) is likely to influence the penetrance of CI in incompatible crosses. The variations of Wolbachia density could also be linked with phage WO density. We determined the relative density (relative concentration) of prophage WO orf7 and Wolbachia (phage-to-bacteria ratio) during early developmental and adult stages of singly infected Aedes albopictus mosquito (Wolbachia A-infected) by using real-time quantitative PCR. Phage WO and Wolbachia did not develop at the same rate. Relative Wolbachia density (bacteria-to-host ratio) was high later in development (adult stages) whilst relative prophage WO density (phage-to-bacteria ratio) was low in the adult stages. Furthermore, 12-d-old adults of singly infected female mosquito had the highest Wolbachia density. In contrast, the larval stage 4 (L4) contained the highest prophage WO-B orf7 density. The association of hosts-Wolbachia-phage among diverse species is different. Thus, if phage and Wolbachia are involved in CI mechanism, the information of this association should be acquired for each specific type of organism for future use of population replacement or gene drive system.

  9. Visible-light-induced degradation of rhodamine B by nanosized Bi2WO6.

    PubMed

    Fu, Hongbo; Pan, Chengshi; Yao, Wenqing; Zhu, Yongfa

    2005-12-01

    Visible-light-induced photodegradation of rhodamine B over nanosized Bi2WO6 has been observed. Bi2WO6 exhibited a high photoactivity to photodegrade rhodamine B in the central pH solution under visible irradiation (lambda > 420 nm). After five recycles for the photodegradation of rhodamine B, the catalyst did not exhibit any significant loss of activity, confirming the photocatalyst is essentially stable. The total organic carbon measurement displayed that a high degree of mineralization was achieved in the present photochemical system. The results of density functional theory calculation illuminated that the visible-light absorption band in the Bi2WO6 catalyst is attributed to the band transition from the hybrid orbitals of Bi6s and O2p to the W5d orbitals. The Bi2WO6-assisted photocatalytic degradation of rhodamine occurs via two competitive processes: a photocatalytic process and a photosensitized process. The transformation of rhodamine is mainly via the photocatalytic process. Kinetic studies by using electron spin resonance and the radical scavenger technologies suggest that *OH is not the dominant photooxidant. Direct hole transfers and O2*- could take part in Bi2WO6 photocatalysis. This study provided a possible treatment approach for organic pollutants by using visible light in aqueous ecosystems.

  10. Facile Fabrication of Sandwich Structured WO3 Nanoplate Arrays for Efficient Photoelectrochemical Water Splitting.

    PubMed

    Feng, Xiaoyang; Chen, Yubin; Qin, Zhixiao; Wang, Menglong; Guo, Liejin

    2016-07-20

    Herein, sandwich structured tungsten trioxide (WO3) nanoplate arrays were first synthesized for photoelectrochemical (PEC) water splitting via a facile hydrothermal method followed by an annealing treatment. It was demonstrated that the annealing temperature played an important role in determining the morphology and crystal phase of the WO3 film. Only when the hydrothermally prepared precursor was annealed at 500 °C could the sandwich structured WO3 nanoplates be achieved, probably due to the crystalline phase transition and increased thermal stress during the annealing process. The sandwich structured WO3 photoanode exhibited a photocurrent density of 1.88 mA cm(-2) and an incident photon-to-current conversion efficiency (IPCE) as high as 65% at 400 nm in neutral Na2SO4 solution under AM 1.5G illumination. To our knowledge, this value is one of the best PEC performances for WO3 photoanodes. Meanwhile, simultaneous hydrogen and oxygen evolution was demonstrated for the PEC water splitting. It was concluded that the high PEC performance should be attributed to the large electrochemically active surface area and active monoclinic phase. The present study can provide guidance to develop highly efficient nanostructured photoelectrodes with the favorable morphology.

  11. Nanobrick-like WO3 thin films: Hydrothermal synthesis and electrochromic application

    NASA Astrophysics Data System (ADS)

    Kondalkar, V. V.; Kharade, R. R.; Mali, S. S.; Mane, R. M.; Patil, P. B.; Patil, P. S.; Choudhury, S.; Bhosale, P. N.

    2014-09-01

    Nanobrick-like WO3 thin films have been synthesized via facile hydrothermal route. Nanostructured WO3 thin films were characterized using X-ray diffraction (XRD), UV-Vis-NIR spectrophotometer, scanning electron microscopy (SEM), atomic force microscopy (AFM) to investigate the intentional properties such as phase structure, optical properties and surface morphology. Moreover electrochromic (EC) performance of WO3 thin film was investigated in 0.5 M LiClO4/PC by means of cyclic voltammetry (CV), chronocoulometry (CC) and chronoamperometry (CA). The value of diffusion coefficient (D) was determined from anodic peak current and was found to be 1.51 × 10-9 cm2/s. The response time of 6.9 s for bleaching (tb) and 9.7 s for coloration (tc) was observed with excellent reversibility 76%. The coloration efficiency for nanobricks WO3 is 39.24 cm2/C. CIE 1931 L∗ab values for colored and bleached films were estimated at 2° observer using D-65 illumination. The electrochromic studies show highly reversible and the stable nature of WO3 thin film which provides a versatile and promising application towards the fabrication of smart windows.

  12. Design of a highly photocatalytically active ZnO/CuWO4 nanocomposite.

    PubMed

    Mavrič, T; Valant, M; Forster, M; Cowan, A J; Lavrenčič, U; Emin, S

    2016-12-01

    Here we report the synthesis, photocatalytic activity and mechanistic study of a novel charge separation heterostructure (HTS). A ZnO/CuWO4 HTS material is reported for the first time. The nanocomposite (NC) consist of CuWO4 nanoparticles (ca. 200-400nm) decorated with ZnO nanorods (ca. 30nm, 100nm length) and is shown to be a highly active photocatalyst for the decomposition of model contaminants including methyl orange (MO) and terephthalic acid (TPA). The ZnO/CuWO4 interface is shown to be key in controlling the enhanced activity of the composite material. Transient absorption (TA) spectroscopy studies demonstrate that photoinduced charge transfer across the ZnO/CuWO4 interface increases electron-hole lifetimes by 3 orders of magnitude, from <20μs in ZnO to 30ms in the ZnO/CuWO4 NC sample. Our findings show that through interface design efficient HTS materials can be prepared for a wide range of photocatalytic applications. PMID:27552417

  13. Plate Boundary Observatory GPS Data Analysis

    NASA Astrophysics Data System (ADS)

    Herring, T. A.; King, R.; McClusky, S.; Murray, M.; Santillan, M.; Melbourne, T.; Anderson, G.

    2005-12-01

    The Plate Boundary Observatory GPS data analysis centers (ACs) at the Berkeley Seismological Laboratory (BSL) and Central Washington University (CWU), and the analysis center coordinator (ACC) at the Massachusetts Institute of Technology began establishing the GPS processing centers on April 1, 2005. The PBO GPS data analyses will be operational on October 1, 2005, with the regular delivery of daily SINEX solution files with full covariance and time series files designed for ease of analysis and plotting. The initial results for the PBO analyses will start with data from January 1, 2004 and contain position time series for 209 PBO Nucleus stations, 17 IGS reference frame stations, 9 CORS stations (to bridge Alaska to the continental United States), and all PBO stations as they come on line. The first PBO site was ready on January 11, 2004. The PBO ACs routinely generate rapid orbit analyses (1-day latency), primarily to check data quality, and initial final orbit analyses with 6-13 day latency. The timing of the generation of these products is based on the availability of the International GNSS Service rapid and final orbit products. Currently, between 280 and 300 stations are included in these rapid analyses and typically 310-315 stations are in the final analyses. The initial testing of the analysis procedures shows median north and east daily root-mean-square (rms) scatters of 1.0-1.3 mm for horizontal positions for a network encompassing North America and Central Pacific. The median height rms scatter is 5 mm. This talk will show results and products being generated by the PBO ACs and ACC, and compare the results between the GIPSY (CWU) and GAMIT (BSL) processing.

  14. Global and regional kinematics with GPS

    NASA Technical Reports Server (NTRS)

    King, Robert W.

    1994-01-01

    The inherent precision of the doubly differenced phase measurement and the low cost of instrumentation made GPS the space geodetic technique of choice for regional surveys as soon as the constellation reached acceptable geometry in the area of interest: 1985 in western North America, the early 1990's in most of the world. Instrument and site-related errors for horizontal positioning are usually less than 3 mm, so that the dominant source of error is uncertainty in the reference frame defined by the satellites orbits and the tracking stations used to determine them. Prior to about 1992, when the tracking network for most experiments was globally sparse, the number of fiducial sites or the level at which they could be tied to an SLR or VLBI reference frame usually, set the accuracy limit. Recently, with a global network of over 30 stations, the limit is set more often by deficiencies in models for non-gravitational forces acting on the satellites. For regional networks in the northern hemisphere, reference frame errors are currently about 3 parts per billion (ppb) in horizontal position, allowing centimeter-level accuracies over intercontinental distances and less than 1 mm for a 100 km baseline. The accuracy of GPS measurements for monitoring height variations is generally 2-3 times worse than for horizontal motions. As for VLBI, the primary source of error is unmodeled fluctuations in atmospheric water vapor, but both reference frame uncertainties and some instrument errors are more serious for vertical than horizontal measurements. Under good conditions, daily repeatabilities at the level of 10 mm rms were achieved. This paper will summarize the current accuracy of GPS measurements and their implication for the use of SLR to study regional kinematics.

  15. Permanent GPS Geodetic Array in Southern California (PGGA) and GPS observations in Indonesia

    NASA Technical Reports Server (NTRS)

    Bock, Yehuds

    1994-01-01

    The Permanent GPS Geodetic Array (PGGA) is a network of permanent monitoring GPS stations in southern California devoted to the continuous measurement of crustal deformation in near real-time. The PGGA plays a unique role in studies of the kinematics of crustal deformation and the earthquake cycle in southern California because it is also providing temporally dense geodetic measurements of crustal motion over periods of minutes to variations in regional crustal strain. As it expands and matures the PGGA will play an increasingly important role in the study of active tectonics of southern California by bridging the frequency range between seismology, observatory geodesy, paleoseismology, and geology. In Indonesia GPS data is used for measurement of a large scale crustal deformation, extending from north China to the Indonesian archipelago. Indonesia offers a tremendous laboratory to study some of the processes that build continents, and mountains are active there. We began GPS observations in August 1989 on mainland Sumatra and the Mentawai Islands to study the phenomena of oblique plate convergence. We have analyzed the Indonesian data in conjunction with data collected on Christmas and Cocos Islands and at Darwin, Australia, and with the triangulation data in Sumatra.

  16. Multipath calibration in GPS pseudorange measurements

    NASA Technical Reports Server (NTRS)

    Kee, Changdon (Inventor); Parkinson, Bradford W. (Inventor)

    1998-01-01

    Novel techniques are disclosed for eliminating multipath errors, including mean bias errors, in pseudorange measurements made by conventional global positioning system receivers. By correlating the multipath signals of different satellites at their cross-over points in the sky, multipath mean bias errors are effectively eliminated. By then taking advantage of the geometrical dependence of multipath, a linear combination of spherical harmonics are fit to the satellite multipath data to create a hemispherical model of the multipath. This calibration model can then be used to compensate for multipath in subsequent measurements and thereby obtain GPS positioning to centimeter accuracy.

  17. First results from the Fennoscandian GPS networks

    NASA Technical Reports Server (NTRS)

    Johansson, J. M.; Jaldehag, R. T. K.

    1993-01-01

    Temporal correlations were measured of data obtained by the Swedish Permanent GPS Network for Positioning (SWEPOS). The model for correlations, r(Delta t) = exp(-(absolute value of (Delta t))/tau), can be used to predict precision of averaged values for different values of tau. Results indicate that tau is approximately equal to 1 day (r less than 1% after 5 days). The results show that the network can be used in geophysical applications such as the DOSE investigation on postglacial rebound.

  18. GPS survey of the western Tien Shan

    NASA Technical Reports Server (NTRS)

    Molnar, Peter H.

    1994-01-01

    This report summarizes the background, field work, data collection and analysis, and future plans associated with a collaborative GPS experiment in the Tien Shan of the former Soviet Union. This project involves the amalgamation of two, separately funded projects, which were proposed separately by PIs Hamburger and Reilinger (NSF number EAR-9115159 and NASA number NAG5-1941) and Molnar and Hager (NSF number EAR9117889 and NASA number NAG5-1947). In addition, the work is being conducted under the auspices of the US-USSR Agreement on Cooperation in the Field of Environmental Protection, with support from the United States Geological Survey.

  19. Topo-Iberia GPS network: installation complete

    NASA Astrophysics Data System (ADS)

    Khazaradze, G.

    2009-04-01

    As part of the project, titled "Geociencias en Iberia: Estudios integrados de topografía y evolución 4D: Topo-Iberia", we have established a network of 26 continuous GPS stations, covering the Spanish part of the Iberian Peninsula (22 stations) and Morocco (4 stations). A major objective behind the establishment of this array is to monitor millimeter level deformation of the crust due to the collision of African and Eurasian (including Iberian) tectonic plates. More specific goals of the project include the identification of the areas and/or specific seismic faults which exhibit higher deformation rates, which could imply an increased seismic hazard in these specific areas. The network has been designed as two X-shaped transects crossing the peninsula from NE to SW and NW to SE, with relatively coarse distribution of the stations, superimposed with denser coverage in the seismically active areas of the Betics, Pyrenees and Cantabrian chains. The majority of the built monuments consist of 1.5-1.8 m tall concrete pillars of 40 cm in diameter anchored to the bedrock using iron rebars. One station in Huesca was built according the UNAVCO's short drilled braced monument (SDBM) specifications. All the monuments were equipped with the SCIGN leveling mounts to ensure the precise antenna alignment and re-alignment in case of the antenna replacement, as well as, tamper resistance of the monument mark. In places were the snow accumulation was possible the antennas were covered with plastic radomes. The instrumentation used is Trimble NetRS dual-frequency receivers with choke-ring antennas. The communication is mainly via cellular telephone system. As of December 2008, the network installation has been competed and all the stations are fully operational. Here we report the milestones of the installation of the network and, as well as, present the first preliminary results of the analysis of the data. Besides the newly established Topo-Iberia CGPS stations, we have included

  20. Strain Accumulation in Montenegro Using GPS Measurements

    NASA Astrophysics Data System (ADS)

    Glavatovic, B.; Vucic, L.; D'Agostino, N.; D'Anastasio, E.; Selvaggi, G.

    2011-12-01

    In this work we present the preliminary results of the analysis of GPS measurements collected from continuous stations belonging to networks deployed for both sceintific and societal purposes. The area is particularly interesting in relationship with the large Mw 7.1 earthquake that affected the Montenegro coastal areas in 1979 and the large uncertainties associated with recurrence times of large events and the present-day rate of strain accumulation. The dataset from the MEPOS (Montenegro), MONTEPOS (Montenegro), AGROS (Serbia) and MAKPOS (Macedonia) networks, combined with data from the RING (http://ring.gm.ingv.it) and other continuous GPS networks in the Mediterranean, Eurasian and African regions, has been analyzed using the GIPSY-OASIS II software package and the precise point positioning method [Zumberge et al., 1997]. Carrier phase ambiguities have been successfully resolved across the entire network using an algorithm based on a fixed-point theorem that closely approximates a full-network resolution [Blewitt, 2008]. Satellite orbit and clock parameters, and daily coordinate transformation parameters into ITRF2005 were provided by the Jet Propulsion Laboratory (JPL). ITRF2005 positions were transformed into an Eurasia fixed reference frame by performing daily transformations into a frame that is defined by minimizing the horizontal velocities of 30 stations across the stable part of the Eurasian continent (away from areas affected by glacial isostatic adjustments). Common mode errors for this continental scale frame are further reduced by including an additional 60 stations as far away as Iceland, Eastern Eurasia, and Africa in a daily spatial (7 parameters) filter [D'Anastasio et al., 2008]. We estimate velocities from the continuous GPS time-series using the CATS software package [Williams, 2003] while accounting for annual and semi-annual constituents, simultaneously estimating rate uncertainties given the assumption that the error model is dominated by

  1. Facile hydrothermal synthesis of TiO2-Bi2WO6 hollow superstructures with excellent photocatalysis and recycle properties.

    PubMed

    Hou, Ya-Fei; Liu, Shu-Juan; Zhang, Jing-huai; Cheng, Xiao; Wang, You

    2014-01-21

    One-dimensional mesoporous TiO2-Bi2WO6 hollow superstructures are prepared using a hydrothermal method and their photocatalysis and recycle properties are investigated. Experimental results indicate that anatase TiO2 nanoparticles are coupled with hierarchical Bi2WO6 hollow tubes on their surfaces. The TiO2-Bi2WO6 structure has a mesoporous wall and the pores in the wall are on average 21 nm. The hierarchical TiO2-Bi2WO6 heterostructures exhibit the highest photocatalytic activity in comparison with P25, pure Bi2WO6 hollow tube and mechanical mixture of Bi2WO6 tube and TiO2 nanoparticle in the degradation of rhodamine B (RhB) under simulated sunlight irradiation. The as-prepared TiO2-Bi2WO6 heterostructures can be easily recycled through sedimentation and they retains their high photocatalytic activity during the cycling use in the simulated sunlight-driving photodegradation process of RhB. The prepared mesoporous TiO2-Bi2WO6 with hollow superstructure is therefore a promising candidate material for water decontamination use.

  2. Enhancement of photoelectric response of bacteriorhodopsin by multilayered WO3 x H2O nanocrystals/PVA membrane.

    PubMed

    Li, Rui; Hu, Fengping; Bao, Qiaoliang; Bao, Shujuan; Qiao, Yan; Yu, Shucong; Guo, Jun; Li, Chang Ming

    2010-02-01

    For the first time, a multilayered WO(3) x H(2)O/PVA membrane on bacteriorhodopsin (bR) is constructed to significantly enhance the photoelectric response of bR by the spillover effect of WO(3) x H(2)O nanocrystals, providing great potential in its important applications in bioelectronics and proton exchange membrane fuel cells.

  3. Flexible electrochromics: magnetron sputtered tungsten oxide (WO3-x) thin films on Lexan (optically transparent polycarbonate) substrates

    NASA Astrophysics Data System (ADS)

    Uday Kumar, K.; Murali, Dhanya S.; Subrahmanyam, A.

    2015-06-01

    Tungsten oxide (WO3-x) based electrochromics on flexible substrates is a topic of recent interest. The present communication reports the electrochromic properties of WO3-x thin films grown on lexan, an optically transparent polycarbonate thermoplastic substrate. The WO3-x films are prepared at room temperature (300 K) by the reactive DC magnetron sputtering technique. The physical properties of metal oxide thin films are known to be controlled by the oxygen stoichiometry of the film. In the present work, the WO3-x thin films are prepared by varying the oxygen flow rates. All the WO3-x thin films are amorphous in nature. The electrochromic performance of the WO3-x thin films is evaluated by cyclic voltammetry measurements on tin doped indium oxide (ITO) coated lexan and glass substrates. The optical band gap of WO3-x thin films grown on lexan substrates (at any given oxygen flow rate) is significantly higher than those grown on glass substrates. The coloration efficiency of WO3-x thin films (at an oxygen flow rate of 10 sccm) on lexan substrates is: 143.9 cm2 C-1 which is higher compared to that grown on glass: 90.4 cm2 C-1.

  4. ZnO nanoplates surfaced-decorated by WO3 nanorods for NH3 gas sensing application

    NASA Astrophysics Data System (ADS)

    Dien Nguyen, Dac; Do, Duc Tho; Hien Vu, Xuan; Vuong Dang, Duc; Chien Nguyen, Duc

    2016-03-01

    Zinc oxide (ZnO) nanoplates and tungsten trioxide (WO3) nanorods were synthesized by hydrothermal treatment from zinc nitrate/potassium hydroxide and sodium tungstate/hydrochloric acid, respectively. The structure, morphology and compositions of the as-prepared WO3/ZnO nano-composites were characterized by x-ray diffraction, field emission scanning electron microscopy and energy dispersive spectroscopy. The obtained ZnO nanoplates have regular shape, single-crystal wurtzite structure with the thickness of 40 nm and 200 versus 400 nm in lateral dimensions. The WO3 nanorods possess the average diameter of 20 nm and the length of approximately 120 nm which were distributed on the surfaces of ZnO nanoplates. The WO3/ZnO nano-composites were prepared by grinding WO3 nanorods powder with ZnO nanoplates powder in various weight ratios (1:2, 1:1 and 2:1). The NH3 gas sensing properties of WO3/ZnO nano-composites were examined through the electrical resistance measurement. The gas sensing performance of the WO3/ZnO composite with weight ratio of 1:1 was better compared with that of other samples. For this sample, the maximum response to 300 ppm NH3 was 24 at the operating temperature of 250 °C. In addition, the gas sensing mechanism of the WO3/ZnO composites was discussed.

  5. Synthesis, characterization and electrochemical studies of nanostructured CaWO{sub 4} as platinum support for oxygen reduction reaction

    SciTech Connect

    Farsi, Hossein; Barzgari, Zahra

    2014-11-15

    Highlights: • Nanostructured CaWO{sub 4} was fabricated by co-precipitation method. • Platinum was electrodeposited onto the surface prepared nanostructured CaWO{sub 4}. • Pt/CaWO{sub 4}-graphite demonstrate good oxygen reduction reaction activity. - Abstract: In the present work, we employed nanostructured calcium tungstate as a supporting material for platinum, a well-known electrocatalyst for oxygen reduction. The co-precipitation method has been utilized to synthesize nanostructured calcium tungstate from aqueous solution. The structure and morphology of the obtained CaWO{sub 4} were characterized by X-ray diffraction (XRD) and transmission electron microscopy (TEM). Preparation of the Pt/CaWO{sub 4}-graphite catalyst was carried out by electrodeposition of Pt onto the surface of CaWO{sub 4}/graphite electrode. The physical properties of the catalyst were determined by scanning electron microscopy analysis and energy dispersive X-ray (SEM/EDX). The electrochemical activity of the Pt/CaWO{sub 4}-graphite for the oxygen reduction reaction (ORR) was investigated in acid solution by cyclic voltammetry measurements, linear sweep voltammetry, and electrochemical impedance spectroscopy. The results revealed that the Pt/CaWO{sub 4}-graphite has higher electrocatalytic activity for oxygen reduction in comparison with Pt/graphite catalyst.

  6. ZnWO{sub 4}–Cu system with enhanced photocatalytic activity by photo-Fenton-like synergistic reaction

    SciTech Connect

    Song, Jimei; Wang, Hong; Hu, Gang; Zhao, Shaojuan; Hu, Haiqin; Jin, Baokang

    2012-11-15

    Highlights: ► A novel coupled system of ZnWO{sub 4}–Cu exhibited much higher catalytic activity than pure ZnWO{sub 4} with H{sub 2}O{sub 2} under UV-light irradiation. ► The enhanced catalytic activity of ZnWO{sub 4}–Cu system was due to the synergistic effect of photocatalysis and Fenton-like process. ► The possible mechanism of the synergistic effect was proposed. -- Abstract: A novel coupled system of ZnWO{sub 4}–Cu, combining two different advanced oxidation processes of photocatalysis and Fenton-like for the degradation of organic dyes, was successfully synthesized. The as-synthesized samples were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS). The nanosized ZnWO{sub 4}–Cu samples exhibited much higher catalytic activity than pure ZnWO{sub 4}. In the presence of the ZC-0.2, the MB solution was completely degraded (the degradation ratio reached 97.79%); while for the ZC-0, the degradation ratio was only 72.29%. The effects of the amount of Cu on the photocatalytic performance of ZnWO{sub 4}–Cu were investigated in detail. The result showed that the synergistic effect between Cu and ZnWO{sub 4} played a key role. The possible mechanism of the synergistic system was proposed.

  7. H.sub.2O doped WO.sub.3, ultra-fast, high-sensitivity hydrogen sensors

    SciTech Connect

    Liu, Ping; Tracy, C. Edwin; Pitts, J. Roland; Lee, Se-Hee

    2011-03-22

    An ultra-fast response, high sensitivity structure for optical detection of low concentrations of hydrogen gas, comprising: a substrate; a water-doped WO.sub.3 layer coated on the substrate; and a palladium layer coated on the water-doped WO.sub.3 layer.

  8. The band structure of WO3 and non-rigid-band behaviour in Na0.67WO3 derived from soft x-ray spectroscopy and density functional theory.

    PubMed

    Chen, B; Laverock, J; Piper, L F J; Preston, A R H; Cho, S W; DeMasi, A; Smith, K E; Scanlon, D O; Watson, G W; Egdell, R G; Glans, P-A; Guo, J-H

    2013-04-24

    The electronic structure of single-crystal WO3 and Na0.67WO3 (a sodium-tungsten bronze) has been measured using soft x-ray absorption and resonant soft x-ray emission oxygen K-edge spectroscopies. The spectral features show clear differences in energy and intensity between WO3 and Na0.67WO3. The x-ray emission spectrum of metallic Na0.67WO3 terminates in a distinct Fermi edge. The rigid-band model fails to explain the electronic structure of Na0.67WO3 in terms of a simple addition of electrons to the conduction band of WO3. Instead, Na bonding and Na 3s-O 2p hybridization need to be considered for the sodium-tungsten bronze, along with occupation of the bottom of the conduction band. Furthermore, the anisotropy in the band structure of monoclinic γ-WO3 revealed by the experimental spectra with orbital-resolved geometry is explained via density functional theory calculations. For γ-WO3 itself, good agreement is found between the experimental O K-edge spectra and the theoretical partial density of states of O 2p orbitals. Indirect and direct bandgaps of insulating WO3 are determined from extrapolating separations between spectral leading edges and accounting for the core-hole energy shift in the absorption process. The O 2p non-bonding states show upward band dispersion as a function of incident photon energy for both compounds, which is explained using the calculated band structure and experimental geometry.

  9. Novel Bi(2)WO(6)-TiO(2) heterostructures for Rhodamine B degradation under sunlike irradiation.

    PubMed

    Murcia López, S; Hidalgo, M C; Navío, J A; Colón, G

    2011-01-30

    Highly efficient Bi(2)WO(6)-TiO(2) heterostructure is synthesized by means of a hydrothermal method having highly photoactivity for the degradation of Rhodamine B under sunlike irradiation. From the structural characterization it has been demonstrated that TiO(2) is incorporated on the Aurivillius structure. Interesting synergetic effect between TiO(2) and Bi(2)WO(6) leads to an improved charge carrier separation mechanism, causing the excellent photocatalytic performance under sunlike irradiation. The photocatalytic performance of Bi(2)WO(6) and Bi(2)WO(6)-TiO(2) was compared under different irradiation conditions and using increasing Rhodamine B concentration up to 25 ppm. After the photocatalytic analysis of both systems, the mineralization efficiency of the heterostructure appears significantly higher with respect to Bi(2)WO(6).

  10. Degradation of dimethylformamide on the surface of the nanosized WO3 films studied by infrared spectroscopy

    NASA Astrophysics Data System (ADS)

    Gavrilyuk, A. I.

    2016-07-01

    Here I report on the degradation of dimethylformamide on the surface of the nanosized WO3 films under the action of light. Dimethylformamide, a substance that has a series of interesting properties, was adsorbed on the surface of the WO3 films and its adsorption mechanism and transformations under the action of light have been investigated with the help of the IR spectroscopy. The spirit of the research is that both DMF modifications have been used i.e., conventional and that with the substitution of hydrogen atoms by deuterium. Formation of two weak bonds (donor-acceptor bond and hydrogen bond) provides a great catalytic effect for photo-initiated proton-coupled electron transfer from the adsorbed molecules to the WO3 film surface. The mechanism of the detachment of hydrogen atoms and subsequent transformation of the adsorbed molecules has been investigated and discussed.

  11. Effect of Pt nanoparticles on the optical gas sensing properties of WO3 thin films.

    PubMed

    Qadri, Muhammad U; Diaz, Alex Fabian Diaz; Cittadini, Michaela; Martucci, Alessandro; Pujol, Maria Cinta; Ferré-Borrull, Josep; Llobet, Eduard; Aguiló, Magdalena; Díaz, Francesc

    2014-01-01

    Thin films of tungsten trioxide were deposited on quartz substrates by RF magnetron sputtering. Different annealing temperatures in the range from 423 to 973 K were used under ambient atmosphere. The influence of the annealing temperature on the structure and optical properties of the resulting WO3 thin films were studied. The surface morphology of the films is composed of grains with an average size near 70 nm for the films annealed between 773 and 973 K. Some of the WO3 thin films were also coated with Pt nanoparticles of about 45 nm in size. Spectrometric measurements of transmittance were carried out for both types of WO3 samples in the wavelength range from 200-900 nm, to determine the effect of the exposure to two different gases namely H2 and CO. Films showed fast response and recovery times, in the range of few seconds. The addition of Pt nanoparticles enables reducing the operation temperature to room temperature.

  12. Low-Temperature H2S Detection with Hierarchical Cr-Doped WO3 Microspheres.

    PubMed

    Wang, Yanrong; Liu, Bin; Xiao, Songhua; Wang, Xinghui; Sun, Leimeng; Li, Han; Xie, Wuyuan; Li, Qiuhong; Zhang, Qing; Wang, Taihong

    2016-04-20

    Hierarchical Cr-doped WO3 microspheres have been successfully synthesized for efficient sensing of H2S gas at low temperatures. The hierarchical structures provide an effective gas diffusion path via well-aligned micro-, meso-, and macroporous architectures, resulting in significant enhancement in sensing response to H2S. The temperature and gas concentration dependence on the sensing properties elucidate that Cr dopants remarkably improve the response and lower the sensor' operating temperature down to 80 °C. Under 0.1 vol % H2S, the response of Cr-doped WO3 sensor is 6 times larger than pristine WO3 sensor at 80 °C. We suggest the increasing number of oxygen vacancies created by Cr dopants to be the underlying reason for enhancement of charge carrier density and accelerated reactions with H2S.

  13. Effect of Pt nanoparticles on the optical gas sensing properties of WO3 thin films.

    PubMed

    Qadri, Muhammad U; Diaz, Alex Fabian Diaz; Cittadini, Michaela; Martucci, Alessandro; Pujol, Maria Cinta; Ferré-Borrull, Josep; Llobet, Eduard; Aguiló, Magdalena; Díaz, Francesc

    2014-01-01

    Thin films of tungsten trioxide were deposited on quartz substrates by RF magnetron sputtering. Different annealing temperatures in the range from 423 to 973 K were used under ambient atmosphere. The influence of the annealing temperature on the structure and optical properties of the resulting WO3 thin films were studied. The surface morphology of the films is composed of grains with an average size near 70 nm for the films annealed between 773 and 973 K. Some of the WO3 thin films were also coated with Pt nanoparticles of about 45 nm in size. Spectrometric measurements of transmittance were carried out for both types of WO3 samples in the wavelength range from 200-900 nm, to determine the effect of the exposure to two different gases namely H2 and CO. Films showed fast response and recovery times, in the range of few seconds. The addition of Pt nanoparticles enables reducing the operation temperature to room temperature. PMID:24977386

  14. Effect of Pt Nanoparticles on the Optical Gas Sensing Properties of WO3 Thin Films

    PubMed Central

    Qadri, Muhammad U.; Diaz Diaz, Alex Fabian; Cittadini, Michaela; Martucci, Alessandro; Pujol, Maria Cinta; Ferré-Borrull, Josep; Llobet, Eduard; Aguiló, Magdalena; Díaz, Francesc

    2014-01-01

    Thin films of tungsten trioxide were deposited on quartz substrates by RF magnetron sputtering. Different annealing temperatures in the range from 423 to 973 K were used under ambient atmosphere. The influence of the annealing temperature on the structure and optical properties of the resulting WO3 thin films were studied. The surface morphology of the films is composed of grains with an average size near 70 nm for the films annealed between 773 and 973 K. Some of the WO3 thin films were also coated with Pt nanoparticles of about 45 nm in size. Spectrometric measurements of transmittance were carried out for both types of WO3 samples in the wavelength range from 200–900 nm, to determine the effect of the exposure to two different gases namely H2 and CO. Films showed fast response and recovery times, in the range of few seconds. The addition of Pt nanoparticles enables reducing the operation temperature to room temperature. PMID:24977386

  15. Dual Oxygen and Tungsten Vacancies on a WO3 Photoanode for Enhanced Water Oxidation.

    PubMed

    Ma, Ming; Zhang, Kan; Li, Ping; Jung, Myung Sun; Jeong, Myung Jin; Park, Jong Hyeok

    2016-09-19

    Alleviating charge recombination at the electrode/electrolyte interface by introducing an overlayer is considered an efficient approach to improve photoelectrochemical (PEC) water oxidation. A WO3 overlayer with dual oxygen and tungsten vacancies was prepared by using a solution-based reducing agent, LEDA (lithium dissolved in ethylenediamine), which improved the PEC performance of the mesoporous WO3 photoanode dramatically. In comparison to the pristine samples, the interconnected WO3 nanoparticles surrounded by a 2-2.5 nm thick overlayer exhibited a photocurrent density approximately 2.4 times higher and a marked cathodic shift of the onset potential, which is mainly attributed to the facilitative effect on interface charge transfer and the improved conductivity by enhanced charge carrier density. This simple and effective strategy may provide a new path to improve the PEC performance of other photoanodes. PMID:27533279

  16. Electrochromic properties of spray deposited TiO 2-doped WO 3 thin films

    NASA Astrophysics Data System (ADS)

    Patil, P. S.; Mujawar, S. H.; Inamdar, A. I.; Sadale, S. B.

    2005-08-01

    TiO 2-doped WO 3 thin films were deposited onto fluorine-doped tin oxide coated conducting glass substrates using spray pyrolysis technique at 525 °C. The volume percentage of TiO 2 dopant was varied from 13% to 38%. The thin film samples were transparent, uniform and strongly adherent to the substrates. Electrochromical properties of TiO 2-doped WO 3 thin films were studied with the help of cyclic voltammetry (CV), chronoamperometry (CA) and chronocoulometry (CC) techniques. It has been found that TiO 2 doping in WO 3 enhances its electrochromic performance. Colouration efficiency becomes almost double and samples exhibit increasingly high reversibility with TiO 2 doping concentrations, in the studied range.

  17. Understanding the synergistic effect of WO3-BiVO4 heterostructures by impedance spectroscopy.

    PubMed

    Shi, Xinjian; Herraiz-Cardona, Isaac; Bertoluzzi, Luca; Lopez-Varo, Pilar; Bisquert, Juan; Park, Jong Hyeok; Gimenez, Sixto

    2016-04-01

    WO3-BiVO4 n-n heterostructures have demonstrated remarkable performance in photoelectrochemical water splitting due to the synergistic effect between the individual components. Although the enhanced functional capabilities of this system have been widely reported, in-depth mechanistic studies explaining the carrier dynamics of this heterostructure are limited. The main goal is to provide rational design strategies for further optimization as well as to extend these strategies to different candidate systems for solar fuel production. In the present study, we perform systematic optoelectronic and photoelectrochemical characterization to understand the carrier dynamics of the system and develop a simple physical model to highlight the importance of the selective contacts to minimize bulk recombination in this heterostructure. Our results collectively indicate that while BiVO4 is responsible for the enhanced optical properties, WO3 controls the transport properties of the heterostructured WO3-BiVO4 system, leading to reduced bulk recombination. PMID:26975634

  18. Reduction of WO 3 to nano-WC by thermo-chemical reaction route

    NASA Astrophysics Data System (ADS)

    Kumar, Akshay; Singh, K.; Pandey, O. P.

    2009-02-01

    Thermo-chemical reaction route has been used to synthesize WC-nanoparticles from WO 3. Two different carbon sources are used to study the effect of these sources on synthesis. The as-prepared samples are characterized by using X-ray diffraction (XRD), differential thermal analyzer (DTA), thermo-gravimetric analysis (TGA) and transmission electron microscope (TEM). The results indicate that reduction of WO 3 to WC takes place by the adsorption of carbon at the surface of WO 3 forming porous structure at the defect sites through which carbon diffuses. As the concentration of adsorbed carbon increases the growth of carbon nanotube starts from this site which ultimately gets converted to carbon nano-fibers of higher chemical activity.

  19. Time-resolved luminescence spectroscopy of structurally disordered K3WO3F3 crystals

    NASA Astrophysics Data System (ADS)

    Omelkov, S. I.; Spassky, D. A.; Pustovarov, V. A.; Kozlov, A. V.; Isaenko, L. I.

    2016-08-01

    Three emission centers of exciton-like origin, with distinct relaxation time, emission and excitation spectra were revealed in K3WO3F3 and described taking into account its structural disordering. Low-temperature monoclinic phase of K3WO3F3 features few anion sites with mixed oxygen/fluorine occupancy per [WO3F3] octahedron. Therefore, different kinds of distorted octahedra form, providing different luminescence centers. The time-resolved luminescence spectroscopy technique was applied to distinguish these centers. The simultaneous thermal quenching of them above ∼200 K was qualitatively explained involving dynamic structural disorder of the compound. The energy transfer mechanism between centers was found and tentatively described by the diffusion of excitons. Apart from intrinsic luminescence, the PL of defect-related centers was discovered and the role of shallow charge carrier traps in the low-temperature persistent luminescence was revealed.

  20. Understanding the synergistic effect of WO3-BiVO4 heterostructures by impedance spectroscopy.

    PubMed

    Shi, Xinjian; Herraiz-Cardona, Isaac; Bertoluzzi, Luca; Lopez-Varo, Pilar; Bisquert, Juan; Park, Jong Hyeok; Gimenez, Sixto

    2016-04-01

    WO3-BiVO4 n-n heterostructures have demonstrated remarkable performance in photoelectrochemical water splitting due to the synergistic effect between the individual components. Although the enhanced functional capabilities of this system have been widely reported, in-depth mechanistic studies explaining the carrier dynamics of this heterostructure are limited. The main goal is to provide rational design strategies for further optimization as well as to extend these strategies to different candidate systems for solar fuel production. In the present study, we perform systematic optoelectronic and photoelectrochemical characterization to understand the carrier dynamics of the system and develop a simple physical model to highlight the importance of the selective contacts to minimize bulk recombination in this heterostructure. Our results collectively indicate that while BiVO4 is responsible for the enhanced optical properties, WO3 controls the transport properties of the heterostructured WO3-BiVO4 system, leading to reduced bulk recombination.

  1. The Effect of WO 3 on the Photocatalytic Activity of TiO 2

    NASA Astrophysics Data System (ADS)

    Do, Y. R.; Lee, W.; Dwight, K.; Wold, A.

    1994-01-01

    Samples of WO 3/TiO 2 mixed oxide powders were prepared by two methods: (1) the incipient wetness impregnation of an aqueous ammonia solution of H 2WO 4 onto TiO 2 (P25), followed by heat treatment and (2) the ultrasonic nebulization and flame hydrolysis of a mixed isopropanol solution of tungsten(V) pentaethoxide and titanium(IV) tetraisopropoxide. The photocatalytic activities of TiO 2-based catalysts were evaluated by the degradation of 1,4-dichlorobenzene (DCB). The addition of WO 3 to TiO 2 greatly increased its photocatalytic behavior. This may be related to an increase in the transfer of electrons from the TiO 2 to the outer system, via the formation of an intermediate W(V) species.

  2. Metal-insulator transition in Na{sub x}WO{sub 3}: Photoemission spectromicroscopy study

    SciTech Connect

    Paul, Sanhita Ghosh, Anirudha Raj, Satyabrata

    2014-04-24

    We have investigated the validity of percolation model, which is quite often invoked to explain the metal-insulator transition in sodium tungsten bronzes, Na{sub x}WO{sub 3} by photoelectron spectromicroscopy. The spatially resolved direct spectromicroscopic probing on both the insulating and metallic phases of high quality single crystals of Na{sub x}WO{sub 3} reveals the absence of any microscopic inhomogeneities embedded in the system within the experimental limit. Neither any metallic domains in the insulating host nor any insulating domains in the metallic host have been found to support the validity of percolation model to explain the metal-insulator transition in Na{sub x}WO{sub 3}.

  3. Nitrogen-incorporation induced changes in the microstructure of nanocrystalline WO3 thin films

    SciTech Connect

    Vemuri, Venkata Rama Sesha R.; Noor-A-Alam, M.; Gullapalli, Satya K.; Engelhard, Mark H.; Ramana, C.V.

    2011-12-30

    Nitrogen doped tungsten oxide (WO3) films were grown by reactive magnetron sputter-deposition by varying the nitrogen content in the reactive gas mixture keeping the deposition temperature fixed at 400 C. The crystal structure, surface morphology, chemical composition, and electrical resistivity of nitrogen doped WO3 films were evaluated using X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM) and electrical conductivity measurements. The results indicate that the nitrogen-doping induced changes in the microstructure and electrical properties of WO3 films are significant. XRD measurements coupled with SEM analysis indicates that the increasing nitrogen content decreases the grain size and crystal quality. The nitrogen concentration increases from 0 at.% to 1.35 at.% with increasing nitrogen flow rate from 0 to 20 sccm. The corresponding dc electrical conductivity of the films had shown a decreasing trend with increasing nitrogen content.

  4. 76 FR 72442 - Certain Automotive GPS Navigation Systems, Components Thereof, and Products Containing Same...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-11-23

    ... COMMISSION Certain Automotive GPS Navigation Systems, Components Thereof, and Products Containing Same... automotive GPS navigation systems, components thereof, and products containing same by reason of infringement... after importation of certain automotive GPS navigation systems, components thereof, and...

  5. Improved modeling of GPS selective availability

    NASA Technical Reports Server (NTRS)

    Braasch, Michael S.; Fink, Annmarie; Duffus, Keith

    1994-01-01

    Selective Availability (SA) represents the dominant error source for stand-alone users of the Global Positioning System (GPS). Even for DGPS, SA mandates the update rate required for a desired level of accuracy in realtime applications. As was witnessed in the recent literature, the ability to model this error source is crucial to the proper evaluation of GPS-based systems. A variety of SA models were proposed to date; however, each has its own shortcomings. Most of these models were based on limited data sets or data which were corrupted by additional error sources. A comprehensive treatment of the problem is presented. The phenomenon of SA is discussed and a technique is presented whereby both clock and orbit components of SA are identifiable. Extensive SA data sets collected from Block 2 satellites are presented. System Identification theory then is used to derive a robust model of SA from the data. This theory also allows for the statistical analysis of SA. The stationarity of SA over time and across different satellites is analyzed and its impact on the modeling problem is discussed.

  6. Civil helicopter flight operations using differential GPS

    NASA Technical Reports Server (NTRS)

    Edwards, F. G.; Loomis, P. V. W.

    1985-01-01

    The results of NASA flight trials of a dual-receiver differential global positioning system (DGPS) for civilian helicopter navigation applications, are presented. The three principal components of the DGPS system are described, including the GPS ground-reference system, a range tracking system, and an on-board sequential GPS receiver. The ground-based receiver in the DGPS operates at a known fixed location and receives C/A code signals from NAVSTAR satellites. System bias errors in the ground receiver are subtracted from the airborne solution for the navigational fix. Calculations of the differential bias error are carried out using an on-board PDP-11/34 M research computer. The ground-reference differential corrections for satellites are given in a table. It is shown that the differential correction signal of the DGPS contains only a small (0.1 rad/sec) high-frequency component which can be attributed to system error. A schematic diagram of the DGPS postflight data processing routine is provided.

  7. TAGGING, TRACKING AND LOCATING WITHOUT GPS

    SciTech Connect

    Cordaro, J.; Coleman, T.; Shull, D.

    2012-07-08

    The Savannah River National Laboratory (SRNL) was requested to lead a Law Enforcement Working Group that was formed to collaborate on common operational needs. All agencies represented on the working group ranked their need to tag, track, and locate a witting or unwitting target as their highest priority. Specifically, they were looking for technologies more robust than Global Positioning Satellite (GPS), could communicate back to the owner, and worked where normal cell phone communications did not work or were unreliable. SRNL brought together multiple technologies in a demonstration that was held in in various Alaska venues, including metropolitan, wilderness, and at-sea that met the working group's requirements. Using prototypical technologies from Boeing, On Ramp, and Fortress, SRNL was able to demonstrate the ability to track personnel and material in all scenarios including indoors, in heavily wooden areas, canyons, and in parking garages. In all cases GPS signals were too weak to measure. Bi-directional communication was achieved in areas that Wi-Fi, cell towers, or traditional radios would not perform. The results of the exercise will be presented. These technologies are considered ideal for tracking high value material such has nuclear material with a platform that allows seamless tracking anywhere in the world, indoors or outdoors.

  8. Gravity wave detection by GPS radio occultations

    NASA Astrophysics Data System (ADS)

    Schmidt, Torsten; Arras, Christina; De la Torre, Alejandro; Alexander, Peter; Llamedo, Pablo

    2016-07-01

    Gravity waves (GWs) play an important role for the general atmospheric circulation due to the related transport of energy and momentum between different regions of the atmosphere. The momentum mostly generated in the troposphere is transported to upper atmospheric levels where GWs break or dissipate and transfer their momentum to the background wind (GW drag). The deposit of GW momentum can occur in the complete altitude range from the upper troposphere-stratosphere, the mesosphere, and even in the thermosphere. A global observation of GW parameters (e.g. potential energy and vertical flux of absolute horizontal momentum) is only possible with satellite data. The radio occultation (RO) technique uses GPS signals received aboard low Earth orbiting satellites for atmospheric limb sounding. Atmospheric temperature profiles in the troposphere/stratosphere and ionospheric electron densities are derived with high vertical resolution. The GPS RO technique is sensitive to GWs with small ratios of vertical to horizontal wavelengths. In this presentation we give an overview about the derivation of GW parameters from RO temperature profiles, review some results of GW detection with RO data, and discuss the limitations of the RO technique. The focus of the presented results is (1) global GW activity in the upper troposphere and lower stratosphere for different seasons, (2) influence of the topography on GW activity from the troposphere to the ionosphere in the Andean region of South America, and (3) the variation of ionospheric sporadic E layers.

  9. Mapping carbon monoxide using GPS tracked sensors.

    PubMed

    Milton, Richard; Steed, Anthony

    2007-01-01

    In this paper we discuss a pilot study where we have mapped urban air pollution using mobile carbon monoxide (CO) sensors. Our objective is to use inexpensive Global Positioning System (GPS) receivers to track the sensors and explore CO variations at a fine geographic scale. The critical issue in data processing is the treatment of the imprecise logs from the GPS. By using knowledge about the route and the geometry of the buildings, we are able to increase the position accuracy significantly, while at the same time showing that certain events, such as CO profiles while crossing roads, can be detected with a high degree of accuracy. Comparisons between data from our own mobile sensors and a fixed sensor site show good agreement in the vicinity of the fixed sensor, while at the same time identifying significant CO peaks within 100 m of this location. Using the mobile sensors to collect data along two of the main roads in the area, we are able to show CO variations along an urban canyon for parallel and perpendicular wind directions. Finally, a number of significant sources of CO were discovered during the course of the study, which suggest possible locations for fixed sensor sites in the future. We conclude by discussing the results in the context of the push towards large sensor networks and mobile communications. The potential for ad hoc mobile sensor networks may be very large.

  10. Estimating Drivers’ Stress from GPS Traces

    PubMed Central

    Vhaduri, Sudip; Ali, Amin; Sharmin, Moushumi; Hovsepian, Karen; Kumar, Santosh

    2015-01-01

    Driving is known to be a daily stressor. Measurement of driver’s stress in real-time can enable better stress management by increasing self-awareness. Recent advances in sensing technology has made it feasible to continuously assess driver’s stress in real-time, but it requires equipping the driver with these sensors and/or instrumenting the car. In this paper, we present “GStress”, a model to estimate driver’s stress using only smartphone GPS traces. The GStress model is developed and evaluated from data collected in a mobile health user study where 10 participants wore physiological sensors for 7 days ( for an average of 10.45 hours/day) in their natural environment. Each participant engaged in 10 or more driving episodes, resulting in a total of 37 hours of driving data. We find that major driving events such as stops, turns, and braking increase stress of the driver. We quantify their impact on stress and thus construct our GStress model by training a Generalized Linear Mixed Model (GLMM) on our data. We evaluate the applicability of GStress in predicting stress from GPS traces, and obtain a correlation of 0.72. By obviating any burden on the driver or the car, we believe, GStress can make driver’s stress assessment ubiquitous. PMID:25866847

  11. The GPS Burst Detector W-Sensor

    SciTech Connect

    McCrady, D.D.; Phipps, P.

    1994-08-01

    The NAVSTAR satellites have two missions: navigation and nuclear detonation detection. The main objective of this paper is to describe one of the key elements of the Nuclear Detonation Detection System (NDS), the Burst Detector W-Sensor (BDW) that was developed for the Air Force Space and Missle Systems Center, its mission on GPS Block IIR, and how it utilizes GPS timing signals to precisely locate nuclear detonations (NUDET). The paper will also cover the interface to the Burst Detector Processor (BDP) which links the BDW to the ground station where the BDW is controlled and where data from multiple satellites are processed to determine the location of the NUDET. The Block IIR BDW is the culmination of a development program that has produced a state-of-the-art, space qualified digital receiver/processor that dissipates only 30 Watts, weighs 57 pounds, and has a 12in. {times} l4.2in. {times} 7.16in. footprint. The paper will highlight several of the key multilayer printed circuit cards without which the required power, weight, size, and radiation requirements could not have been met. In addition, key functions of the system software will be covered. The paper will be concluded with a discussion of the high speed digital signal processing and algorithm used to determine the time-of-arrival (TOA) of the electromagnetic pulse (EMP) from the NUDET.

  12. GPS application to mapping, charting and geodesy

    NASA Technical Reports Server (NTRS)

    Senus, W. J.; Hill, R. W.

    1981-01-01

    GPSPAC, a receiver being developed for space applications by the Defense Mapping Agency and NASA, will use signals from GPS constellations to generate real-time values of host vehicle position and velocity. The GPSPAC has an L-band antenna and preamp capable of receiving the 1575 MHz and 1227 MHz spread spectrum signals; its stable oscillator at 5.115 MHz provides the basic frequency reference, resulting in a long term drift of less than one part in 10 to the -10th day. The GPSPAC performs many functions on board the spacecraft which were previously relegated to large-scale ground-based computer/receiver systems. A positional accuracy of better than 8 can be achieved for those periods when four or more NAVSTAR satellites are visible to the host satellite. The GPS geodetic receiver development, which will provide prototype receivers for utilization in terrestrial surveying operations, has the potential to significantly enhance the accuracy of point geodetic surveys over the current user hardware capability.

  13. GPS-Aided Tsunami Early Detection System

    NASA Astrophysics Data System (ADS)

    Song, Y. T.; Bar-Sever, Y. E.; Liu, Z.; Khachikyan, R.

    2015-12-01

    Most tsunami fatalities occur in near-field communities of earthquakes at offshore faults. Tsunami early warning is key for reducing the number of fatalities. Unfortunately, an earthquake's magnitude often does not gauge the resulting tsunami power. Here we show that real-time GPS stations along coastlines are able to detect seafloor motions due to big earthquakes, and that the detected seafloor displacements are able to determine tsunami energy and scales instantaneously for early warnings. Our method focuses on estimating tsunami energy directly from seafloor motions because a tsunami's potential or scale, no matter how it is defined, has to be proportional to the tsunami energy. Since seafloor motions are the only source of a tsunami, their estimation directly relates to the mechanism that generates tsunamis; therefore, it is a proper way of identifying earthquakes that are capable of triggering tsunamis, while being able to discriminate those particular earthquakes from false alarms. Examples of detecting the tsunami energy scales for the 2004 Sumatra M9.1 earthquake, the 2005 Nias M8.7 earthquake, the 2010 M8.8 Chilean earthquake, and the 2011 M9.0 Tohoku-Oki earthquake will be presented. The development of the Indo-Pacific GPS-Aided Tsunami Early Detection (GATED) system will be reported.

  14. Luminescence spectroscopy of K3WO3F3 oxyfluoride crystals

    NASA Astrophysics Data System (ADS)

    Kozlov, A. V.; Pustovarov, V. A.

    2016-09-01

    Spectra of photoluminescence (PL) in region of 1.5-5.5 eV, PL excitation spectra (3-22 eV), PL decay kinetics, the temperature dependence of the PL were measured for single crystals and ceramics K3WO3F3 as well as irradiate ceramics K3WO3F3. Synchrotron radiation was used for low temperature PL experiments with time resolution. Single crystals are transparent in microwave, visible and near UV range, inter-band transition energy is Eg = 4.3 eV. The intrinsic luminescence of tungstates is usually ascribed to the radiative relaxation of exciton-like excitations localized on WO6 octahedra or WO4 tetrahedra. In K3WO3F3 the wide band luminescence in the region of 2.5 eV with the Stokes shift of 1.5 eV with the microsecond decay kinetics is connected with luminescence of triplet self-trapped excitons (STE). This luminescence is formed by electronic transitions in [WO3F3] octahedron. Different distortion of KWOF crystal lattice is manifested in the change of the Stokes shift of STE luminescence band. The 3.2 eV emission band in low-temperature PL spectrum with decay times of 1.8 ns and 11 ns corresponds to singlet STE luminescence. A new 2.9 eV emission band is discovered in low-temperature PL spectrum in the samples irradiated by fast electrons (E = 10 MeV, D = 160 kGy). This emission band is excited not intracenter mechanism, and through the creation of excitons bound on the defects. It is suggested that it is F-like centers of anionic sublattice induced by the mechanism of elastic collision.

  15. Fabrication and photoelectrochemical properties of porous ZnWO{sub 4} film

    SciTech Connect

    Zhao Xu; Yao Wenqing; Wu Yan; Zhang Shicheng; Yang Haipeng; Zhu Yongfa . E-mail: zhuyf@mail.tsinghua.edu.cn

    2006-08-15

    Porous ZnWO{sub 4} films have been fabricated on Indium-tin oxide (ITO) glass and its photoelectrochemical properties and high photocatalytic activities towards degradation of rhodamine B (RhB) has been investigated. Using amorphous heteronuclear complex as precursor and with the addition of polyethylene glycol (PEG, molecular weight=400), the porous ZnWO{sub 4} films have been achieved at the temperature of 500 deg. C via dip-coating method. It is composed of approximately 70 nm-sized particles and exhibits substantial porosity. The textures and porosity of ZnWO{sub 4} films are dependent on preparation factors, such as the ratio of precursor/PEG and the annealing conditions. The formation mechanism of porous ZnWO{sub 4} films was proposed. The porous ZnWO{sub 4} films exhibited high photocatalytic activities towards degrading RhB. The top of valence band and the bottom of the conduction band was estimated to be -0.56 and 3.45 eV (vs. saturated calomel electrode (SCE)), respectively. -- Graphical abstract: Current vs. potential curves for ZnWO{sub 4} film treated at various temperatures: ((a) photo 500 deg. C; (b) photo 550 deg. C; (c) photo TiO{sub 2}; (d) dark 500 deg. C; (e) dark 550 deg. C; (f) dark TiO{sub 2}) in (B) in 0.5 M Na{sub 2}SO{sub 4} solution pH 6.0, scan rate=10 mV s{sup -1}.

  16. Photoluminescence in the Ca{sub x}Sr{sub 1-x}WO{sub 4} system at room temperature

    SciTech Connect

    Porto, S.L.; Longo, E.; Simoes, L.G.P.; Lima, S.J.G.; Ferreira, J.M.; Soledade, L.E.B.; Espinoza, J.W.M.; Cassia-Santos, M.R.; Maurera, M.A.M.A.; Paskocimas, C.A.; Santos, I.M.G. Souza, A.G.

    2008-08-15

    In this work, a study was undertaken about the structural and photoluminescent properties, at room temperature, of powder samples from the Ca{sub x}Sr{sub 1-x}WO{sub 4} (x=0-1.0) system, synthesized by a soft chemical method and heat treated between 400 and 700 deg. C. The material was characterized using Infrared, UV-vis and Raman spectroscopy and XRD. The most intense PL emission was obtained for the sample calcined at 600 deg. C, which is neither highly disordered (400-500 deg. C), nor completely ordered (700 deg. C). Corroborating the role of disorder in the PL phenomenon, the most intense PL response was not observed for pure CaWO{sub 4} or SrWO{sub 4}, but for Ca{sub 0.6}Sr{sub 0.4}WO{sub 4}. The PL emission spectra could be separated into two Gaussian curves. The lower wavelength peak is placed around 530 nm, and the higher wavelength peak at about 690 nm. Similar results were reported in the literature for both CaWO{sub 4} and SrWO{sub 4}. - Graphical abstract: The structural and room temperature photoluminescence of Ca{sub x}Sr{sub 1-x}WO4 synthesized by a soft chemical method was studied. The most intense PL emission was obtained for the sample calcined at 600 deg. C, that is neither highly disordered (400-500 deg. C), nor completely ordered (700 deg. C). Corroborating the role of disorder in the PL phenomenon, the most intense PL response was not observed for pure CaWO{sub 4} or SrWO{sub 4}, but for Ca{sub 0.6}Sr{sub 0.4}WO{sub 4}.

  17. One-dimensional WO{sub 3} and its hydrate: One-step synthesis, structural and spectroscopic characterization

    SciTech Connect

    Iwu, Kingsley O.; Galeckas, Augustinas; Rauwel, Protima; Kuznetsov, Andrej Y.; Norby, Truls

    2012-01-15

    We report on a one-step hydrothermal growth of one-dimensional (1D) WO{sub 3} nanostructures, using urea as 1D growth-directing agent and a precursor free of metals other than tungsten. By decreasing the pH of the starting solution, the size of the nanostructures was reduced significantly, this development being accompanied by the realization of phase pure hexagonal WO{sub 3} nanorods (elimination of monoclinic impurity phase) and a red shift in optical absorption edge. Surface analyses indicated the presence of reduced tungsten species in the WO{sub 3} nanostructures, which increased two-fold in a hydrated WO{sub 3} phase obtained with further decrease in pH. We suggest that oxygen vacancies are responsible for this defect state in WO{sub 3}, while protons are responsible or contribute significantly to the same in the hydrated phase. - Graphical abstract: The figure illustrates the role of pH in morphological and absorption edge evolution of WO{sub 3} (hydrate) as well as the variation in the concentration of defect electrons between anhydrous and hydrated WO{sub 3}. Highlights: Black-Right-Pointing-Pointer WO{sub 3} nanorods prepared in a one step procedure. Black-Right-Pointing-Pointer HCl (aq) enables phase pure WO{sub 3} nanorods. Black-Right-Pointing-Pointer HCl (aq) induces significant reduction in dimension of and red shift in absorption edge of nanorods. Black-Right-Pointing-Pointer W{sup 5+} detected in hydrothermal WO{sub 3} phase, the concentration of which increases in the hydrated phase. Black-Right-Pointing-Pointer W{sup 5+} from the two phases due to different positive defects.

  18. An Interdisciplinary Approach at Studying the Earth-Sun System with GPS/GNSS and GPS-like Signals

    NASA Technical Reports Server (NTRS)

    Zuffada, Cinzia; Hajj, George; Mannucci, Anthony J.; Chao, Yi; Ao, Chi; Zumberge, James

    2005-01-01

    The value of Global Positioning Satellites (GPS) measurements to atmospheric science, space physics, and ocean science, is now emerging or showing a potential to play a major role in the evolving programs of NASA, NSF and NOAA. The objective of this communication is to identify and articulate the key scientific questions that are optimally, or perhaps uniquely, addressed by GPS or GPS-like observations, and discuss their relevance to existing or planned national Earth-science research programs. The GPS-based ocean reflection experiments performed to date have demonstrated the precision and spatial resolution suitable to altimetric applications that require higher spatial resolution and more frequent repeat than the current radar altimeter satellites. GPS radio occultation is promising as a climate monitoring tool because of its benchmark properties: its raw observable is based on extremely accurate timing measurements. GPS-derived temperature profiles can provide meaningful climate trend information over decadal time scales without the need for overlapping missions or mission-to-mission calibrations. By acquiring data as GPS satellites occult behind the Earth's limb, GPS also provides high vertical resolution information on the vertical structure of electron density with global coverage. New experimental techniques will create more comprehensive TEC maps by using signals reflected from the oceans and received in orbit. This communication will discuss a potential future GNSS Earth Observing System project which would deploy a constellation of satellites using GPS and GPS-like measurements, to obtain a) topography measurements based on GPS reflections with an accuracy and horizontal resolution suitable for eddy monitoring, and h) climate-records quality atmospheric temperature profiles. The constellation would also provide for measurements of ionospheric elec tron density. This is a good example of an interdisciplinary mission concept, with broad science objectives

  19. Processing In A GPS Receiver To Reduce Multipath Errors

    NASA Technical Reports Server (NTRS)

    Meehan, Thomas K.

    1994-01-01

    Four techniques of ancillary real-time digital processing of signals in Global Positioning System, GPS, receiver introduced reducing effects of multipath propagation of signals on position estimates produced by receiver. Multipath range errors halved. Applied in addition to other signal-processing techniques and to other techniques designing as receiving antenna to make it insensitive to reflections of GPS signals from nearby objects.

  20. Advancing Technology: GPS and GIS Outreach Training for Agricultural Producers

    ERIC Educational Resources Information Center

    Flynn, Allison; Arnold, Shannon

    2010-01-01

    The use of the Global Positioning System (GPS) and Global Information Systems (GIS) has made significant impacts on agricultural production practices. However, constant changes in the technologies require continuing educational updates. The outreach program described here introduces the operation, use, and applications of GPS receivers and GIS…

  1. Backyard Botany: Using GPS Technology in the Science Classroom

    ERIC Educational Resources Information Center

    March, Kathryn A.

    2012-01-01

    Global Positioning System (GPS) technology can be used to connect students to the natural world and improve their skills in observation, identification, and classification. Using GPS devices in the classroom increases student interest in science, encourages team-building skills, and improves biology content knowledge. Additionally, it helps…

  2. A simple method to improve autonomous GPS positioning for tractors.

    PubMed

    Gomez-Gil, Jaime; Alonso-Garcia, Sergio; Gómez-Gil, Francisco Javier; Stombaugh, Tim

    2011-01-01

    Error is always present in the GPS guidance of a tractor along a desired trajectory. One way to reduce GPS guidance error is by improving the tractor positioning. The most commonly used ways to do this are either by employing more precise GPS receivers and differential corrections or by employing GPS together with some other local positioning systems such as electronic compasses or Inertial Navigation Systems (INS). However, both are complex and expensive solutions. In contrast, this article presents a simple and low cost method to improve tractor positioning when only a GPS receiver is used as the positioning sensor. The method is based on placing the GPS receiver ahead of the tractor, and on applying kinematic laws of tractor movement, or a geometric approximation, to obtain the midpoint position and orientation of the tractor rear axle more precisely. This precision improvement is produced by the fusion of the GPS data with tractor kinematic control laws. Our results reveal that the proposed method effectively reduces the guidance GPS error along a straight trajectory.

  3. Coordinate Time and Proper Time in the GPS

    ERIC Educational Resources Information Center

    Matolcsi, T.; Matolcsi, M.

    2008-01-01

    The global positioning system (GPS) provides an excellent educational example of how the theory of general relativity is put into practice and becomes part of our everyday life. This paper gives a short and instructive derivation of an important formula used in the GPS, and is aimed at graduate students and general physicists. The authors…

  4. Two laboratory methods for the calibration of GPS speed meters

    NASA Astrophysics Data System (ADS)

    Bai, Yin; Sun, Qiao; Du, Lei; Yu, Mei; Bai, Jie

    2015-01-01

    The set-ups of two calibration systems are presented to investigate calibration methods of GPS speed meters. The GPS speed meter calibrated is a special type of high accuracy speed meter for vehicles which uses Doppler demodulation of GPS signals to calculate the measured speed of a moving target. Three experiments are performed: including simulated calibration, field-test signal replay calibration, and in-field test comparison with an optical speed meter. The experiments are conducted at specific speeds in the range of 40-180 km h-1 with the same GPS speed meter as the device under calibration. The evaluation of measurement results validates both methods for calibrating GPS speed meters. The relative deviations between the measurement results of the GPS-based high accuracy speed meter and those of the optical speed meter are analyzed, and the equivalent uncertainty of the comparison is evaluated. The comparison results justify the utilization of GPS speed meters as reference equipment if no fewer than seven satellites are available. This study contributes to the widespread use of GPS-based high accuracy speed meters as legal reference equipment in traffic speed metrology.

  5. Space shuttle navigation analysis. Volume 1: GPS aided navigation

    NASA Technical Reports Server (NTRS)

    Matchett, G. A.; Vogel, M. A.; Macdonald, T. J.

    1980-01-01

    Analytical studies related to space shuttle navigation are presented. Studies related to the addition of NAVSTAR Global Positioning System user equipment to the shuttle avionics suite are presented. The GPS studies center about navigation accuracy covariance analyses for both developmental and operational phases of GPS, as well as for various orbiter mission phases.

  6. A Simple Method to Improve Autonomous GPS Positioning for Tractors

    PubMed Central

    Gomez-Gil, Jaime; Alonso-Garcia, Sergio; Gómez-Gil, Francisco Javier; Stombaugh, Tim

    2011-01-01

    Error is always present in the GPS guidance of a tractor along a desired trajectory. One way to reduce GPS guidance error is by improving the tractor positioning. The most commonly used ways to do this are either by employing more precise GPS receivers and differential corrections or by employing GPS together with some other local positioning systems such as electronic compasses or Inertial Navigation Systems (INS). However, both are complex and expensive solutions. In contrast, this article presents a simple and low cost method to improve tractor positioning when only a GPS receiver is used as the positioning sensor. The method is based on placing the GPS receiver ahead of the tractor, and on applying kinematic laws of tractor movement, or a geometric approximation, to obtain the midpoint position and orientation of the tractor rear axle more precisely. This precision improvement is produced by the fusion of the GPS data with tractor kinematic control laws. Our results reveal that the proposed method effectively reduces the guidance GPS error along a straight trajectory. PMID:22163917

  7. Where in the World?: GPS Projects for the Technology Class

    ERIC Educational Resources Information Center

    Guccione, Sam

    2005-01-01

    Global positioning system (GPS) has many uses. They include navigation, location finding, vehicle tracking, surveying, autonomous control of highway construction equipment, scientific activities, asset location and entertainment. The GPS is a constellation of 24 satellites located in a 10,000-mile radius orbit in a way that allows for at least six…

  8. Mapping where We Live and Play with GPS Technology

    ERIC Educational Resources Information Center

    Gentry, Deborah J.

    2006-01-01

    As a result of technological advances such as the Global Positioning System (GPS) and the Geographic Information System (GIS), mapping practices and applications have become far more sophisticated. This article suggests family and consumer sciences students and professionals consider using GPS technology to map their communities as a strategy to…

  9. Ab-initio structure determination of β-La 2WO 6

    NASA Astrophysics Data System (ADS)

    Chambrier, M.-H.; Kodjikian, S.; Ibberson, R. M.; Goutenoire, F.

    2009-02-01

    The structure of the low-temperature form of β-La 2WO 6 has been determined from laboratory X-ray, neutron time-of-flight and electron diffraction data. This tungstate crystallizes in the non-centrosymmetric orthorhombic space group (no. 19) P2 12 12 1, with Z=8, a=7.5196(1) Å, b=10.3476(1) Å, c=12.7944(2) Å, and a measured density 7.37(1) g cm -3. The structure consists of tungsten [WO 6] octahedra and tetrahedral [OLa 4]. Tungsten polyhedra are connected such that [W 2O 11] 10- units are formed.

  10. Hydrothermal synthesis of NiWO4 crystals for high performance non-enzymatic glucose biosensors

    PubMed Central

    Mani, Sivakumar; Vediyappan, Veeramani; Chen, Shen-Ming; Madhu, Rajesh; Pitchaimani, Veerakumar; Chang, Jia-Yaw; Liu, Shang-Bin

    2016-01-01

    A facile hydrothermal route for the synthesis of ordered NiWO4 nanocrystals, which show promising applications as high performance non-enzymatic glucose sensor is reported. The NiWO4-modified electrodes showed excellent sensitivity (269.6 μA mM−1 cm−2) and low detection limit (0.18 μM) for detection of glucose with desirable selectivity, stability, and tolerance to interference, rendering their prospective applications as cost-effective, enzyme-free glucose sensors. PMID:27087561

  11. Hydrothermal synthesis of NiWO4 crystals for high performance non-enzymatic glucose biosensors

    NASA Astrophysics Data System (ADS)

    Mani, Sivakumar; Vediyappan, Veeramani; Chen, Shen-Ming; Madhu, Rajesh; Pitchaimani, Veerakumar; Chang, Jia-Yaw; Liu, Shang-Bin

    2016-04-01

    A facile hydrothermal route for the synthesis of ordered NiWO4 nanocrystals, which show promising applications as high performance non-enzymatic glucose sensor is reported. The NiWO4-modified electrodes showed excellent sensitivity (269.6 μA mM‑1 cm‑2) and low detection limit (0.18 μM) for detection of glucose with desirable selectivity, stability, and tolerance to interference, rendering their prospective applications as cost-effective, enzyme-free glucose sensors.

  12. Phase transitions in coprecipitated NiO-WO/sub 3/ system in calcination, reduction, and sulfiding

    SciTech Connect

    Agievskii, D.A.; Pavlova, L.I.; Landau, M.V.; Kvashonkin, V.I.; Chukin, G.D.

    1986-04-01

    X-ray diffraction and electron microscopy have been used in an investigation of the shaping of phase composition and structure of a coprecipitated NiO-WO/sub 3/ system in calcination, reduction, and sulfiding. It has been shown that calcination, when it leads to the formation of crystalline NiWO/sub 4/, lowers the efficiency of reduction and sulfiding to a considerable degree. A step-temperature sulfiding operation, in comparison with isothermal sulfiding, gives a less ordered structure of the WS/sub 2/, with loose packing of the particles into agglomerates.

  13. Iron-related luminescence centers in ZnWO4 : Fe

    NASA Astrophysics Data System (ADS)

    Nagirnyi, V.; Chernov, S.; Grigorjeva, L.; Jonsson, L.; Kirm, M.; Kotlov, A.; Lushchik, A.; Millers, D.; Nefedov, V. A.; Pankratov, V.; Zadneprovski, B. I.

    A systematic spectroscopic study of single ZnWO4 :Fe crystals with different iron concentrations has been performed under excitation by ultraviolet light, by synchrotron radiation or under photostimulation by near-infrared light. The luminescence of Fe3+-related centres has been studied. It is shown that iron centres of different types efficiently promote the formation of crystal defects at low temperatures. Electrons and holes can be trapped near Fe2+ or Fe3+ ions, which is further revealed in phosphorescence, thermostimulated or photostimulated luminescence. At room temperature the main effect of iron impurity is to reduce the light yield of a ZnWO4 scintillator.

  14. Preparation and photoelectrocatalytic activity of a nano-structured WO{sub 3} platelet film

    SciTech Connect

    Yagi, Masayuki Maruyama, Syou; Sone, Koji; Nagai, Keiji; Norimatsu, Takayoshi

    2008-01-15

    A tungsten trioxide (WO{sub 3}) film was prepared by calcination from a precursor paste including suspended ammonium tungstate and polyethylene glycol (PEG). The ammonium tungstate suspension was yielded by an acid-base reaction of tungstic acid and an ammonium solution followed by deposition with ethanol addition. Thermogravimetric (TG) analysis showed that the TG profile of PEG is significantly influenced by deposited ammonium tungstate, suggesting that PEG is interacting strongly with deposited ammonium tungstate in the suspension paste. X-ray diffraction (XRD) data indicated that the WO{sub 3} film is crystallized by sintering over 400 deg. C. The scanning electron microscopic (SEM) measurement showed that the film is composed of the nano-structured WO{sub 3} platelets. The semiconductor properties of the film were examined by Mott-Schottky analysis to give flat band potential E{sub FB}=0.30 V vs. saturated calomel reference electrode (SCE) and donor carrier density N{sub D}=2.5x10{sup 22} cm{sup -3}, latter of which is higher than previous WO{sub 3} films by two orders of magnitude. The higher N{sub D} was explained by the large interfacial heterojunction area caused by the nano-platelet structure, which apparently increases capacitance per a unit electrode area. The WO{sub 3} film sintered at 550 deg. C produced 3.7 mA cm{sup -2} of a photoanodic current at 1.2 V vs. SCE under illumination with a 500 W xenon lamp due to catalytic water oxidation. This photocurrent was 4.5-12.8 times higher than those for the other control WO{sub 3} films prepared by similar but different procedures. The high catalytic activity could be explained by the nano-platelet structure. The photocurrent was generated on illumination of UV and visible light below 470 nm, and the maximum incident photon-to-current conversion efficiency (IPCE) was 47% at 320 nm at 1.2 V. Technically important procedures for preparation of nano-structured platelets were discussed. - Graphical abstract: A

  15. Distinctions in the Raman Spectroscopy Features of WO3 Materials with Increasing Temperature

    NASA Astrophysics Data System (ADS)

    Garcia-Sanchez, Raul F.; Misra, Prabhakar

    2014-06-01

    Metal oxides are widely used in gas sensor applications due to their low cost, easy production and selectivity. Tungsten Oxide (WO3) is one of the most used metal oxides in the detection of Nitrogen gases (NOx). The purpose of this research is to determine if the Raman features of a metal oxide gas sensor can serve as tools to make estimates regarding the sensor capabilities related to the target gases. This research will be used for gas sensing of oxidizing/reducing toxic gases (i.e. H2S, NOx, SO2, etc.) and finding the effect that temperature, gas concentration, type of gas, exposure time and other variables have on the Raman spectra of metal oxides. In this experiment, the temperature was increased from 30-160 °C and the Raman data was taken using a 780 nm infrared laser. In two of the samples, WO3 on Silicon substrate and WO3 nanopowder, we found vibrational modes at 807, 716 and 271 cm-1, which are indicators of a monoclinic WO3 structure. The WO3 nanowires samples exhibit the O-W-O bond stretching feature is present and asymmetric stretching of the W-O bonds occurs, resulting in a 750 cm-1 band. The intensity of Raman features such as 750 cm-1 for nanowires and 492 and 670 cm-1 for WO3 on Silicon substrate begins to decay as temperature increases. Additionally, the vibrational modes related to O-H and W-OH become more pronounced as temperature increases due to those bonds reacting more strongly to the temperature change than the normal W-O bonds related to the original lattice structure. Finally, all samples have low-frequency phonon mode markers associated with temperature change, and in most cases these change as temperature increases. The understanding of the thermal effects will help develop theoretical models for the identification of specific metal oxide-gas relationships and provide a supplemental way of observing gas adsorption in addition to current conductivity measurements.

  16. Preparation and Characterization of Monodispersed WO3 Nanoclusters on TiO2(110)

    SciTech Connect

    Kim, Jooho; Bondarchuk, Olexsandr; Kay, Bruce D.; White, J. M.; Dohnalek, Zdenek

    2007-02-15

    A procedure is described for preparing a novel model early transition metal oxide system for catalysis studies?direct sublimation of tungsten trioxide on TiO2(110). Isolated monodispersed cyclic trimers, i.e., (WO3)3, can be formed on TiO2(110) that are thermally stable up to at least 750 K. Although not readily generalizable to monodispersed (WO3)x clusters other than cyclic trimers, this protocol provides an ideal nanocluster platform for carrying out model system catalysis studies over a wide temperature range.

  17. Surface morphology-controlled fabrication of Na2WO4 films with high structural stability

    NASA Astrophysics Data System (ADS)

    Yang, Dachi; Hernandez, Jose A.; Katiyar, Ram S.; Fonseca, Luis F.

    2016-06-01

    Films with designed surface morphologies are of great importance for high-performance devices and other applications such as gas sensors and catalysts. Na2WO4 films with various surface morphologies have been fabricated via physical evaporation inside the chamber created by approaching mouth to mouth two alumina boats containing precursors and by covering alumina boat with aluminum foil, respectively. The temperature-dependence Raman investigation reveals red shifting of the Raman peaks with increasing temperature in all cases. The observed Raman shifts are relatively small confirming high stability of the Na2WO4 films within the investigated temperature range.

  18. Hydrothermal synthesis of uniform WO{sub 3} submicrospheres using thiourea as an assistant agent

    SciTech Connect

    Su, X.T.; Xiao, F.; Lin, J.L.; Jian, J.K.; Li, Y.N.; Sun, Q.J.; Wang, J.D.

    2010-08-15

    Nearly monodisperse tungsten trioxide submicrospheres have been synthesized with tungsten acid and HCl as the starting materials and thiourea as a structure-directing agent through a facile hydrothermal method. The obtained products were characterized by X-ray diffraction, transmission electron microscopy, scanning electron microscopy and energy dispersive X-ray, respectively. The results show that the WO{sub 3} submicrospheres are monodisperse with a diameter of about 800-1000 nm. The morphology of the products gradually evolutes from rods to spheres with increase of the reaction time. The formation mechanism of the WO{sub 3} submicrospheres is primarily discussed.

  19. Alcohol Dehydration on Monooxo W=O and Dioxo O=W=O Species

    SciTech Connect

    Li, Zhenjun; Smid, Bretislav; Kim, Yu Kwon; Matolin, Vladimir; Kay, Bruce D.; Rousseau, Roger J.; Dohnalek, Zdenek

    2012-08-16

    The dehydration of 1-propanol on nanoporous WO3 films prepared via ballistic deposition at ~20 K has been investigated using temperature programmed desorption, infrared reflection absorption spectroscopy and density functional theory. The as deposited films are extremely efficient in 1-propanol dehydration to propene. This activity is correlated with the presence of dioxo O=W=O groups while monooxo W=O species are shown to be inactive. Annealing of the film induces densification that results in the loss of catalytic activity due to annihilation O=W=O species.

  20. Exposure of WO3 Photoanodes to Ultraviolet Light Enhances Photoelectrochemical Water Oxidation.

    PubMed

    Li, Tengfei; He, Jingfu; Peña, Bruno; Berlinguette, Curtis P

    2016-09-28

    Exposure of WO3 photoanodes to sustained irradiation by ultraviolet (UV) light induces a morphology change that enhances the photoelectrochemical (PEC) activity towards the oxygen evolution reaction (OER). A 30% enhancement in photocurrent density at 1.23 V vs RHE was measured despite a nominal change in onset potential. A structural and electrochemical analysis of the films before and after exposure to UV irradiation indicates that a higher film porosity and correspondingly higher specific surface area is responsible for the enhancement in PEC activity. The effect of prolonged UV irradiation on the WO3 films is fundamentally different to that which was previously observed for BiVO4 films.

  1. Exposure of WO3 Photoanodes to Ultraviolet Light Enhances Photoelectrochemical Water Oxidation.

    PubMed

    Li, Tengfei; He, Jingfu; Peña, Bruno; Berlinguette, Curtis P

    2016-09-28

    Exposure of WO3 photoanodes to sustained irradiation by ultraviolet (UV) light induces a morphology change that enhances the photoelectrochemical (PEC) activity towards the oxygen evolution reaction (OER). A 30% enhancement in photocurrent density at 1.23 V vs RHE was measured despite a nominal change in onset potential. A structural and electrochemical analysis of the films before and after exposure to UV irradiation indicates that a higher film porosity and correspondingly higher specific surface area is responsible for the enhancement in PEC activity. The effect of prolonged UV irradiation on the WO3 films is fundamentally different to that which was previously observed for BiVO4 films. PMID:27644107

  2. Towards GPS Surface Reflection Remote Sensing of Sea Ice Conditions

    NASA Technical Reports Server (NTRS)

    Komjathy, A.; Maslanik, J. A.; Zavorotny, V. U.; Axelrad, P.; Katzberg, S. J.

    2000-01-01

    This paper describes the research to extend the application of Global Positioning System (GPS) signal reflections, received by airborne instruments, to cryospheric remote sensing. The characteristics of the GPS signals and equipment afford the possibility of new measurements not possible with existing radar and passive microwave systems. In particular, the GPS receiving systems are small and light-weight, and as such are particularly well suited to be deployed on small aircraft or satellite platforms with minimal impact. Our preliminary models and experimental results indicate that reflected GPS signals have potential to provide information on the presence and condition of sea and fresh-water ice as well as the freeze/thaw state of frozen ground. In this paper we show results from aircraft experiments over the ice pack near Barrow, Alaska suggesting correlation between forward scattered GPS returns and RADARSAT backscattered signals.

  3. Automatic GPS satellite based subsidence measurements for Ekofisk

    SciTech Connect

    Mes, M.J.; Luttenberger, C.; Landau, H.; Gustavsen, K.

    1995-12-01

    A fully automatic procedure for the measurement of subsidence of many platforms in almost real time is presented. Such a method is important for developments which may be subject to subsidence and where reliable subsidence and rate measurements are needed for safety, planning of remedial work and verification of subsidence models. Automatic GPS satellite based subsidence measurements are made continuously on platforms in the North Sea Ekofisk Field area. A description of the system is given. The derivation of those parameters which give optimal measurement accuracy is described, the results of these derivations are provided. GPS satellite based measurements are equivalent to pressure gauge based platform subsidence measurements, but they are much cheaper to install and maintain. In addition, GPS based measurements are not subject to drift of any gauges. GPS measurements were coupled to oceanographic quantities such as the platform deck clearance. These quantities now follow from GPS based measurements.

  4. Terrain-Moisture Classification Using GPS Surface-Reflected Signals

    NASA Technical Reports Server (NTRS)

    Grant, Michael S.; Acton, Scott T.; Katzberg, Stephen J.

    2006-01-01

    In this study we present a novel method of land surface classification using surface-reflected GPS signals in combination with digital imagery. Two GPS-derived classification features are merged with visible image data to create terrain-moisture (TM) classes, defined here as visibly identifiable terrain or landcover classes containing a surface/soil moisture component. As compared to using surface imagery alone, classification accuracy is significantly improved for a number of visible classes when adding the GPS-based signal features. Since the strength of the reflected GPS signal is proportional to the amount of moisture in the surface, use of these GPS features provides information about the surface that is not obtainable using visible wavelengths alone. Application areas include hydrology, precision agriculture, and wetlands mapping.

  5. Operational Use of GPS Navigation for Space Shuttle Entry

    NASA Technical Reports Server (NTRS)

    Goodman, John L.; Propst, Carolyn A.

    2008-01-01

    The STS-118 flight of the Space Shuttle Endeavour was the first shuttle mission flown with three Global Positioning System (GPS) receivers in place of the three legacy Tactical Air Navigation (TACAN) units. This marked the conclusion of a 15 year effort involving procurement, missionization, integration, and flight testing of a GPS receiver and a parallel effort to formulate and implement shuttle computer software changes to support GPS. The use of GPS data from a single receiver in parallel with TACAN during entry was successfully demonstrated by the orbiters Discovery and Atlantis during four shuttle missions in 2006 and 2007. This provided the confidence needed before flying the first all GPS, no TACAN flight with Endeavour. A significant number of lessons were learned concerning the integration of a software intensive navigation unit into a legacy avionics system. These lessons have been taken into consideration during vehicle design by other flight programs, including the vehicle that will replace the Space Shuttle, Orion.

  6. How and Why to Do VLBI on GPS

    NASA Technical Reports Server (NTRS)

    Dickey, J. M.

    2010-01-01

    In order to establish the position of the center of mass of the Earth in the International Celestial Reference Frame, observations of the Global Positioning Satellite (GPS) constellation using the IVS network are important. With a good frame-tie between the coordinates of the IVS telescopes and nearby GPS receivers, plus a common local oscillator reference signal, it should be possible to observe and record simultaneously signals from the astrometric calibration sources and the GPS satellites. The standard IVS solution would give the atmospheric delay and clock offsets to use in analysis of the GPS data. Correlation of the GPS signals would then give accurate orbital parameters of the satellites in the ICRF reference frame, i.e., relative to the positions of the astrometric sources. This is particularly needed to determine motion of the center of mass of the earth along the rotation axis.

  7. Autonomous Navigation Improvements for High-Earth Orbiters Using GPS

    NASA Technical Reports Server (NTRS)

    Long, Anne; Kelbel, David; Lee, Taesul; Garrison, James; Carpenter, J. Russell; Bauer, F. (Technical Monitor)

    2000-01-01

    The Goddard Space Flight Center is currently developing autonomous navigation systems for satellites in high-Earth orbits where acquisition of the GPS signals is severely limited This paper discusses autonomous navigation improvements for high-Earth orbiters and assesses projected navigation performance for these satellites using Global Positioning System (GPS) Standard Positioning Service (SPS) measurements. Navigation performance is evaluated as a function of signal acquisition threshold, measurement errors, and dynamic modeling errors using realistic GPS signal strength and user antenna models. These analyses indicate that an autonomous navigation position accuracy of better than 30 meters root-mean-square (RMS) can be achieved for high-Earth orbiting satellites using a GPS receiver with a very stable oscillator. This accuracy improves to better than 15 meters RMS if the GPS receiver's signal acquisition threshold can be reduced by 5 dB-Hertz to track weaker signals.

  8. GPS Climatology: Long-term PWV Records from a Dense GPS Array (Invited)

    NASA Astrophysics Data System (ADS)

    Heki, K.; Yoshida, K.

    2009-12-01

    More than ten years has passed since people recognized meteorological value of atmospheric delays observed by Global Positioning System (GPS) together with station coordinates. Precipitable water vapor (PWV) data are obtained from ~1000 receivers of GPS Earth Observation Network (GEONET) in Japan in near real time. After years of basic studies of GPS meteorology, Japan Meteorological Agency has recently started to incorporate GPS-PWV routinely into its atmospheric model for numerical weather prediction. Here we expand the concept and study longer term behaviors of the atmospheric water vapor, i.e. GPS climatology. We use zenith total delays (ZTD) at GPS stations over the last 12 years. We also use surface meteorological data from ~200 observatories to isolate delays due to water vapor (zenith wet delay, ZWD) by removing those by dry air (hydrostatic delay). ZWD is proportional to PWV, and we explore climatological signals in PWV, e.g. interannual changes due to El Nino/Southern Oscillation (ENSO), longer-term changes such as North Atlantic Oscillation (NAO), Pacific Decadal Oscillation (PDO), and secular increase due to global warming. Average temperature over Japan in this period shows relatively rapid increase in late 1990’s and 2000’s and moderate decrease in the first half of 2000’s. PWV showed similar long-term signals to the surface temperature changes as well as strong seasonal signatures. These changes negatively correlate with indices of PDO, an inter-decadal climate oscillation in the northern Pacific Ocean bringing colder climates in its western part during positive phases. Unlike surface temperature, PWV did not show significant net increase during the studied period. NAO is considered to be a part of Arctic Oscillation (AO), and strongly influence winter climate in northern Japan. Negative temperature anomalies prevailed there in the 2000-2001 winter, when the NAO index was negative, but such anomalies were not evident in PWV. In addition to such

  9. GPS Monitor Station Upgrade Program at the Naval Research Laboratory

    NASA Technical Reports Server (NTRS)

    Galysh, Ivan J.; Craig, Dwin M.

    1996-01-01

    One of the measurements made by the Global Positioning System (GPS) monitor stations is to measure the continuous pseudo-range of all the passing GPS satellites. The pseudo-range contains GPS and monitor station clock errors as well as GPS satellite navigation errors. Currently the time at the GPS monitor station is obtained from the GPS constellation and has an inherent inaccuracy as a result. Improved timing accuracy at the GPS monitoring stations will improve GPS performance. The US Naval Research Laboratory (NRL) is developing hardware and software for the GPS monitor station upgrade program to improve the monitor station clock accuracy. This upgrade will allow a method independent of the GPS satellite constellation of measuring and correcting monitor station time to US Naval Observatory (USNO) time. THe hardware consists of a high performance atomic cesium frequency standard (CFS) and a computer which is used to ensemble the CFS with the two CFS's currently located at the monitor station by use of a dual-mixer system. The dual-mixer system achieves phase measurements between the high-performance CFS and the existing monitor station CFS's to within 400 femtoseconds. Time transfer between USNO and a given monitor station is achieved via a two way satellite time transfer modem. The computer at the monitor station disciplines the CFS based on a comparison of one pulse per second sent from the master site at USNO. The monitor station computer is also used to perform housekeeping functions, as well as recording the health status of all three CFS's. This information is sent to the USNO through the time transfer modem. Laboratory time synchronization results in the sub nanosecond range have been observed and the ability to maintain the monitor station CFS frequency to within 3.0 x 10 (sup minus 14) of the master site at USNO.

  10. Synthesis and characterization of novel WO{sub 3} loaded Ag–ZnO and its photocatalytic activity

    SciTech Connect

    Subash, B.; Krishnakumar, B.; Pandiyan, V.; Swaminathan, M.; Shanthi, M.

    2013-01-15

    Graphical abstract: Display Omitted Highlights: ► A novel WO{sub 3} loaded Ag–ZnO was prepared by a simple solvothermal method. ► ‘Ag’ traps the electron from both ZnO and WO{sub 3} reducing electro–hole recombination. ► WO{sub 3}–Ag–ZnO is more efficient than Ag–ZnO, WO{sub 3}–ZnO, Ag–WO{sub 3} and undoped catalysts. ► WO{sub 3}–Ag–ZnO material will be much useful for the treatment of dye effluents. -- Abstract: A novel WO{sub 3} loaded Ag–ZnO photocatalyst was successfully synthesized by a simple solvothermal method and characterized by X-ray diffraction (XRD), field emission scanning electron microscope (FE-SEM) images, energy dispersive spectrum (EDS), diffuse reflectance spectra (DRS), photoluminescence spectra (PL), cyclic voltammetry (CV) and Brunauer–Emmett–Teller (BET) surface area measurements. The photocatalytic activity of WO{sub 3}–Ag–ZnO was investigated for the degradation of RR 120 and RO 4 dyes in aqueous solution using UV-A light. WO{sub 3}–Ag–ZnO is found to be more efficient than Ag–ZnO, WO{sub 3}–ZnO, Ag–WO{sub 3}, commercial ZnO, prepared ZnO, TiO{sub 2}-P25 and TiO{sub 2} (Merck) at neutral pH for the mineralization of dyes. First time we have reported that novel WO{sub 3} loaded Ag–ZnO has been found to be very efficient for two azo dyes removal when compared to commercially available catalyst (Degussa P25, ZnO (Merck) and TiO{sub 2} (Merck)). The mineralization of dyes has been confirmed by chemical oxygen demand (COD) measurements. A mechanism of degradation has been proposed for the higher efficiency of WO{sub 3}–Ag–ZnO.

  11. Electronic polarizability and interaction parameter of gadolinium tungsten borate glasses with high WO{sub 3} content

    SciTech Connect

    Taki, Yukina; Shinozaki, Kenji; Honma, Tsuyoshi; Dimitrov, Vesselin; Komatsu, Takayuki

    2014-12-15

    Glasses with the compositions of 25Gd{sub 2}O{sub 3}–xWO{sub 3}–(75−x)B{sub 2}O{sub 3} with x=25–65 were prepared by using a conventional melt quenching method, and their electronic polarizabilities, optical basicities Λ(n{sub o}), and interaction parameters A(n{sub o}) were estimated from density and refractive index measurements in order to clarify the feature of electronic polarizability and bonding states in the glasses with high WO{sub 3} contents. The optical basicity of the glasses increases monotonously with the substitution of WO{sub 3} for B{sub 2}O{sub 3}, and contrary the interaction parameter decreases monotonously with increasing WO{sub 3} content. A good linear correlation was observed between Λ(n{sub o}) and A(n{sub o}) and between the glass transition temperature and A(n{sub o}). It was proposed that Gd{sub 2}O{sub 3} oxide belongs to the category of basic oxide with a value of A(n{sub o})=0.044 Å{sup −3} as similar to WO{sub 3}. The relationship between the glass formation and electronic polarizability in the glasses was discussed, and it was proposed that the glasses with high WO{sub 3} and Gd{sub 2}O{sub 3} contents would be a floppy network system consisting of mainly basic oxides. - Graphical abstract: This figure shows the correlation between the optical basicity and interaction parameter in borate-based glasses. The data obtained in the present study for Gd{sub 2}O{sub 3}–WO{sub 3}–B{sub 2}O{sub 3} glasses are locating in the correlation line for other borate glasses. These results shown in Fig. 8 clearly demonstrate that Gd{sub 2}O{sub 3}–WO{sub 3}–B{sub 2}O{sub 3} glasses having a wide range of optical basicity and interaction parameter are regarded as glasses consisting of acidic and basic oxides. - Highlights: • Gd{sub 2}O{sub 3}–WO{sub 3}–B{sub 2}O{sub 3} glasses with high WO{sub 3} contents were prepared. • Electronic polarizability and interaction parameter were estimated. • Optical basicity increases

  12. Rip current monitoring using GPS buoy system

    NASA Astrophysics Data System (ADS)

    Song, DongSeob; Kim, InHo; Kang, DongSoo

    2014-05-01

    The occurrence of rip current in the Haeundae beach, which is one of the most famous beaches in South Korea, has been threatening beach-goers security in summer season annually. Many coastal scientists have been investigating rip currents by using field observations and measurements, laboratory measurements and wave tank experiments, and computer and numerical modeling. Rip current velocity is intermittent and may rapidly increase within minutes due to larger incoming wave groups or nearshore circulation instabilities. It is important to understand that changes in rip current velocity occur in response to changes in incoming wave height and period as well as changes in water level. GPS buoys have been used to acquire sea level change data, atmospheric parameters and other oceanic variables in sea for the purposes of vertical datum determination, tide correction, radar altimeter calibration, ocean environment and marine pollution monitoring. Therefore, we adopted GPS buoy system for an experiment which is to investigate rip current velocity; it is sporadic and may quickly upsurge within minutes due to larger arriving wave groups or nearshore flow uncertainties. In this study, for high accurate positioning of buy equipment, a Satellite Based Argumentation System DGPS data logger was deployed to investigate within floating object, and it can be acquired three-dimensional coordinate or geodetic position of buoy with continuous NMEA-0183 protocol during 24 hours. The wave height measured by in-situ hydrometer in a cross-shore array clearly increased before and after occurrence of rip current, and wave period also was lengthened around an event. These results show that wave height and period correlate reasonably well with long-shore current interaction in the Haeundae beach. Additionally, current meter data and GPS buoy data showed that rip current velocities, about 0.2 m/s, may become dangerously strong under specific conditions. Acknowledgement This research was

  13. Precise Point Positioning Based on BDS and GPS Observations

    NASA Astrophysics Data System (ADS)

    Gao, ZhouZheng; Zhang, Hongping; Shen, Wenbin

    2014-05-01

    BeiDou Navigation Satellite System (BDS) has obtained the ability applying initial navigation and precise point services for the Asian-Pacific regions at the end of 2012 with the constellation of 5 Geostationary Earth Orbit (GEO), 5 Inclined Geosynchronous Orbit (IGSO) and 4 Medium Earth Orbit (MEO). Till 2020, it will consist with 5 GEO, 3 IGSO and 27 MEO, and apply global navigation service similar to GPS and GLONASS. As we known, GPS precise point positioning (PPP) is a powerful tool for crustal deformation monitoring, GPS meteorology, orbit determination of low earth orbit satellites, high accuracy kinematic positioning et al. However, it accuracy and convergence time are influenced by the quality of pseudo-range observations and the observing geometry between user and Global navigation satellites system (GNSS) satellites. Usually, it takes more than 30 minutes even hours to obtain centimeter level position accuracy for PPP while using GPS dual-frequency observations only. In recent years, many researches have been done to solve this problem. One of the approaches is smooth pseudo-range by carrier-phase observations to improve pseudo-range accuracy. By which can improve PPP initial position accuracy and shorten PPP convergence time. Another sachems is to change position dilution of precision (PDOP) with multi-GNSS observations. Now, BDS has the ability to service whole Asian-Pacific regions, which make it possible to use GPS and BDS for precise positioning. In addition, according to researches on GNSS PDOP distribution, BDS can improve PDOP obviously. Therefore, it necessary to do some researches on PPP performance using both GPS observations and BDS observations, especially in Asian-Pacific regions currently. In this paper, we focus on the influences of BDS to GPS PPP mainly in three terms including BDS PPP accuracy, PDOP improvement and convergence time of PPP based on GPS and BDS observations. Here, the GPS and BDS two-constellation data are collected from

  14. GPS Software Packages Deliver Positioning Solutions

    NASA Technical Reports Server (NTRS)

    2010-01-01

    "To determine a spacecraft s position, the Jet Propulsion Laboratory (JPL) developed an innovative software program called the GPS (global positioning system)-Inferred Positioning System and Orbit Analysis Simulation Software, abbreviated as GIPSY-OASIS, and also developed Real-Time GIPSY (RTG) for certain time-critical applications. First featured in Spinoff 1999, JPL has released hundreds of licenses for GIPSY and RTG, including to Longmont, Colorado-based DigitalGlobe. Using the technology, DigitalGlobe produces satellite imagery with highly precise latitude and longitude coordinates and then supplies it for uses within defense and intelligence, civil agencies, mapping and analysis, environmental monitoring, oil and gas exploration, infrastructure management, Internet portals, and navigation technology."

  15. GPS satellites: Radiation pressure, attitude and resonance

    NASA Astrophysics Data System (ADS)

    Hugentobler, U.; Ineichen, D.; Beutler, G.

    2003-04-01

    At the altitude of the CPS satellites the most important non-gravitational perturbation is caused by the solar radiation pressure acting on the satellite body and its solar panels. The development of high-fidelity radiation pressure models may be motivated by the following observation: The GPS satellites are orbiting in a 2:1-commensurability with the Earth's rotation which causes resonance. The expected sensitivity to specific coefficients of the geopotential is, however, significantly reduced by strong correlations of these parameters with radiation pressure parameters. Sophisticated radiation pressure models rely on a precise knowledge of the satellite's attitude which does not only affects the location of the antenna phase center or the phase windup of the signal carrier but, through radiation pressure, also the orbital dynamics. PRN 23, whose attitudinal behaviour was modified early in 2002 is an interesting case. Due to this change an impressive improvement in the orbit quality could be achieved.

  16. A rubidium clock for GPS. [breadboard model

    NASA Technical Reports Server (NTRS)

    Riley, W. J.

    1982-01-01

    The design objectives and approach; the more important design features; the signal parameters and error budget; and early test results in the development of a second-source rubidium frequency standard for use in the GPS navigation satellites are discussed. Tests of a breadboard version of the RFS show that the measured time-domain stability is within the goal specification. The results are uncorrected for the conribution of the reference and are probably limited by the reference stability in the medium term region. The Rb reference is bbetter in the medium term region, but the Cs reference is etter at 10,000 seconds and longer, probably because of the barometric sensitivity of the rubidium reference unit.

  17. GPS on-orbit battery performance

    NASA Astrophysics Data System (ADS)

    Kasten, J. L.

    1982-03-01

    Three batteries designed for the GPS system were evaluated. The batteries were wired together, and during the eclipse period were discharged through parallel diodes into a boost converter which then boosted the battery voltage up to the totally regulated bus voltage. Each battery, with a system life of approximately five years, had its own charger. During testing the battery was maintained or used on trickle charge. Data are presented for the battery capacity during the reconditioning. Raw data for each eclipse period and calculations for the average discharge voltage for each battery are given. Thermal cycling for one of the batteries and reconditioning cycles and regimes for all of the batteries are discussed. A reconditioning discharge curve is also given. The problem of temperature cycling in one of the batteries was resolved by redesigning the battery radiator system.

  18. CASA Uno GPS orbit and baseline experiments

    NASA Technical Reports Server (NTRS)

    Schutz, B. E.; Ho, C. S.; Abusali, P. A. M.; Tapley, B. D.

    1990-01-01

    CASA Uno data from sites distributed in longitude from Australia to Europe have been used to determine orbits of the GPS satellites. The characteristics of the orbits determined from double difference phase have been evaluated through comparisons of two-week solutions with one-week solutions and by comparisons of predicted and estimated orbits. Evidence of unmodeled effects is demonstrated, particularly associated with the orbit planes that experience solar eclipse. The orbit accuracy has been assessed through the repeatability of unconstrained estimated baseline vectors ranging from 245 km to 5400 km. Both the baseline repeatability and the comparison with independent space geodetic methods give results at the level of 1-2 parts in 100,000,000. In addition, the Mojave/Owens Valley (245 km) and Kokee Park/Ft. Davis (5409 km) estimates agree with VLBI and SLR to better than 1 part in 100,000,000.

  19. Some applications of GPS timing information

    NASA Technical Reports Server (NTRS)

    Zhang, Yinbai

    1994-01-01

    GPS Satellites transmit two independent signals. One is C/A code (course acquisition signal) which could be utilized by all civilian users. This service is called a Standard Positioning Service (SPS). Another is P code (precise signal) that could be only accessed by those authorized users. The service is called a precise positioning service (PPS). SPS C/A code users can navigate with accuracy of approximately 100 m and timing accuracy of about 250-300 ns (1 sigma). Such timing accuracy is not enough for precision time and frequency value transfer. For this reason we must do some research work to improve the SPS C/A code accuracy which SPS users can get. This paper presents our recent progress on timing information analysis, its data processing and its timing and frequency measurement applications.

  20. GPS Imaging of Sierra Nevada Uplift

    NASA Astrophysics Data System (ADS)

    Hammond, W. C.; Blewitt, G.; Kreemer, C.

    2015-12-01

    Recent improvements in the scope and precision of GPS networks across California and Nevada have allowed for uplift of the Sierra Nevada to be observed directly. Much of the signal, in the range of 1 to 2 mm/yr, has been attributed to lithospheric scale rebound following massive groundwater withdrawal in the San Joaquin Valley in southern California, exacerbated by drought since 2011. However, natural tectonic deformation associated with long term uplift of the range may also contribute to the observed signal. We have developed new algorithms that enhance the signal of Sierra Nevada uplift and improve our ability to interpret and separate natural tectonic signals from anthropogenic contributions. We apply our new Median Interannual Difference Adjusted for Skewness (MIDAS) algorithm to the vertical times series and a inverse distance-weighted median spatial filtering and Delaunay-based interpolation to despeckle the rate map. The resulting spatially continuous vertical rate field is insensitive to outliers and steps in the GPS time series, and omits isolated features attributable to unstable stations or unrepresentative rates. The resulting vertical rate field for California and Nevada exhibits regionally coherent signals from the earthquake cycle including interseismic strain accumulation in Cascadia, postseismic relaxation of the mantle from recent large earthquakes in central Nevada and southern California, groundwater loading changes, and tectonic uplift of the Sierra Nevada and Coast Ranges. Uplift of the Sierra Nevada extends from the Garlock Fault in the south to an indefinite boundary in the north near the latitude of Mt. Lassen to the eastern Sierra Nevada range front in Owen's Valley. The rates transition to near zero in the southern Walker Lane. The eastern boundary of uplift coincides with the highest strain rates in the western Great Basin, suggesting higher normal fault slip rates and a component of tectonic uplift of the Sierra Nevada.

  1. Comparison of GPS receiver DCB estimation methods using a GPS network

    NASA Astrophysics Data System (ADS)

    Choi, Byung-Kyu; Park, Jong-Uk; Min Roh, Kyoung; Lee, Sang-Jeong

    2013-07-01

    Two approaches for receiver differential code biases (DCB) estimation using the GPS data obtained from the Korean GPS network (KGN) in South Korea are suggested: the relative and single (absolute) methods. The relative method uses a GPS network, while the single method determines DCBs from a single station only. Their performance was assessed by comparing the receiver DCB values obtained from the relative method with those estimated by the single method. The daily averaged receiver DCBs obtained from the two different approaches showed good agreement for 7 days. The root mean square (RMS) value of those differences is 0.83 nanoseconds (ns). The standard deviation of the receiver DCBs estimated by the relative method was smaller than that of the single method. From these results, it is clear that the relative method can obtain more stable receiver DCBs compared with the single method over a short-term period. Additionally, the comparison between the receiver DCBs obtained by the Korea Astronomy and Space Science Institute (KASI) and those of the IGS Global Ionosphere Maps (GIM) showed a good agreement at 0.3 ns. As the accuracy of DCB values significantly affects the accuracy of ionospheric total electron content (TEC), more studies are needed to ensure the reliability and stability of the estimated receiver DCBs.

  2. GPS Velocity and Strain Rate Fields in Southwest Anatolia from Repeated GPS Measurements.

    PubMed

    Erdoğan, Saffet; Sahin, Muhammed; Tiryakioğlu, Ibrahim; Gülal, Engin; Telli, Ali Kazım

    2009-01-01

    Southwestern Turkey is a tectonically active area. To determine kinematics and strain distribution in this region, a GPS network of sixteen stations was established. We have used GPS velocity field data for southwest Anatolia from continuous measurements covering the period 2003 to 2006 to estimate current crustal deformation of this tectonically active region. GPS data were processed using GAMIT/GLOBK software and velocity and strain rate fields were estimated in the study area. The measurements showed velocities of 15-30 mm/yr toward the southwest and strain values up to 0.28-8.23×10(-8). Results showed that extension has been determined in the Burdur-Isparta region. In this study, all of strain data reveal an extensional neotectonic regime through the northeast edge of the Isparta Angle despite the previously reported compressional neotectonic regime. Meanwhile, results showed some small differences relatively with the 2006 model of Reilinger et al. As a result, active tectonic movements, in agreement with earthquake fault plane solutions showed important activity. PMID:22573998

  3. GPS Velocity and Strain Rate Fields in Southwest Anatolia from Repeated GPS Measurements

    PubMed Central

    Erdoğan, Saffet; Şahin, Muhammed; Tiryakioğlu, İbrahim; Gülal, Engin; Telli, Ali Kazım

    2009-01-01

    Southwestern Turkey is a tectonically active area. To determine kinematics and strain distribution in this region, a GPS network of sixteen stations was established. We have used GPS velocity field data for southwest Anatolia from continuous measurements covering the period 2003 to 2006 to estimate current crustal deformation of this tectonically active region. GPS data were processed using GAMIT/GLOBK software and velocity and strain rate fields were estimated in the study area. The measurements showed velocities of 15–30 mm/yr toward the southwest and strain values up to 0.28–8.23×10−8. Results showed that extension has been determined in the Burdur-Isparta region. In this study, all of strain data reveal an extensional neotectonic regime through the northeast edge of the Isparta Angle despite the previously reported compressional neotectonic regime. Meanwhile, results showed some small differences relatively with the 2006 model of Reilinger et al. As a result, active tectonic movements, in agreement with earthquake fault plane solutions showed important activity. PMID:22573998

  4. Extremely sensitive and selective NO probe based on villi-like WO3 nanostructures for application to exhaled breath analyzers.

    PubMed

    Moon, Hi Gyu; Choi, You Rim; Shim, Young-Seok; Choi, Kwon-Il; Lee, Jong-Heun; Kim, Jin-Sang; Yoon, Seok-Jin; Park, Hyung-Ho; Kang, Chong-Yun; Jang, Ho Won

    2013-11-13

    Self-assembled WO3 thin film nanostructures with 1-dimensional villi-like nanofingers (VLNF) have been synthesized on the SiO2/Si substrate with Pt interdigitated electrodes using glancing angle deposition (GAD). Room-temperature deposition of WO3 by GAD resulted in anisotropic nanostructures with large aspect ratio and porosity having a relative surface area, which is about 32 times larger than that of a plain WO3 film. A WO3 VLNF sensor shows extremely high response to nitric oxide (NO) at 200 °C in 80% of relative humidity atmosphere, while responses of the sensor to ethanol, acetone, ammonia, and carbon monoxide are negligible. Such high sensitivity and selectivity to NO are attributed to the highly efficient modualtion of potential barriers at narrow necks between individual WO3 VLNF and the intrinsically high sensitivity of WO3 to NO. The theoretical detection limit of the sensor for NO is expected to be as low as 88 parts per trillion (ppt). Since NO is an approved biomarker of chronic airway inflammation in asthma, unprecedentedly high response and selectivity, and ppt-level detection limit to NO under highly humid environment demonstrate the great potential of the WO3 VLNF for use in high performance breath analyzers.

  5. Monodisperse spindle-like FeWO{sub 4} nanoparticles: Controlled hydrothermal synthesis and enhanced optical properties

    SciTech Connect

    Guo, Jinxue; Zhou, Xiaoyu; Lu, Yibin; Zhang, Xiao; Kuang, Shaoping; Hou, Wanguo

    2012-12-15

    Monodisperse FeWO{sub 4} nanoparticles with specific spindle-like morphology have been synthesized in the presence of citric acid through hydrothermal process. In the synthesis route, citric acid played four roles such as the reducing agent, chelating regents, structure-directing agent and stabilizing agents. In addition, the morphology of FeWO{sub 4} was dramatically tuned by the pH value of the precursor medium. The optical properties of FeWO{sub 4} were investigated with UV-Vis spectra and photoluminescence spectroscopy. The photocatalytic experiments demonstrated that the decomposition efficiency of the monodisperse spindle-like FeWO{sub 4} nanoparticles is 74% after 30 min of UV irradiation, which displayed remarkable enhanced photodegradation activity compared with ordinary FeWO{sub 4} sample (57%) and normal TiO{sub 2} photocatalysts P-25 (56%). - Monodisperse spindle-like FeWO{sub 4} nanoparticles with enhanced photocatalytic activities. Highlights: Black-Right-Pointing-Pointer Monodisperse spindle-like FeWO{sub 4} were synthesized with hydrothermal method. Black-Right-Pointing-Pointer Citric acid plays key roles in the hydrothermal synthesis. Black-Right-Pointing-Pointer Their morphology can be tuned with pH value of the precursor medium. Black-Right-Pointing-Pointer They show enhanced photocatalytic activities with irradiation of UV light.

  6. Improved WO3 photocatalytic efficiency using ZrO2 and Ru for the degradation of carbofuran and ampicillin.

    PubMed

    Gar Alalm, Mohamed; Ookawara, Shinichi; Fukushi, Daisuke; Sato, Akira; Tawfik, Ahmed

    2016-01-25

    The photocatalytic degradation of carbofuran (pesticide) and ampicillin (pharmaceutical) using synthesized WO3/ZrO2 nanoparticles under simulated solar light was investigated. Transmission electron microscopy (TEM), X-ray diffraction (XRD), and Raman spectra analyses were used to characterize the prepared catalysts. The optimum ratio of WO3 to ZrO2 was determined to be 1:1 for the degradation of both contaminants. The degradation of carbofuran and ampicillin by WO3/ZrO2 after 240 min of irradiation was 100% and 96%, respectively. Ruthenium (Ru) was employed as an additive to WO3/ZrO2 to enhance the photocatalytic degradation rate. Ru/WO3/ZrO2 exhibited faster degradation rates than WO3/ZrO2. Furthermore, 100% and 97% degradation of carbofuran and ampicillin, respectively, was achieved using Ru/WO3/ZrO2 after 180 min of irradiation. The durability of the catalyst was investigated by reusing the same suspended catalyst, which achieved 92% of its initial efficiency. The photocatalytic degradation of ampicillin and carbofuran followed pseudo-first order kinetics according to the Langmuir-Hinshelwood model.

  7. Experimental and theoretical investigation of a mesoporous K(x)WO3 material having superior mechanical strength.

    PubMed

    Dey, Sonal; Anderson, Sean T; Mayanovic, Robert A; Sakidja, Ridwan; Landskron, Kai; Kokoszka, Berenika; Mandal, Manik; Wang, Zhongwu

    2016-02-01

    Mesoporous materials with tailored properties hold great promise for energy harvesting and industrial applications. We have synthesized a novel tungsten bronze mesoporous material (K(x)WO3; x ∼ 0.07) having inverse FDU-12 type pore symmetry and a crystalline framework. In situ small angle X-ray scattering (SAXS) measurements of the mesoporous K(0.07)WO3 show persistence of a highly ordered meso-scale pore structure to high pressure conditions (∼18.5 GPa) and a material with remarkable mechanical strength despite having ∼35% porosity. Pressure dependent in situ SAXS measurements reveal a bulk modulus κ = 44 ± 4 GPa for the mesoporous K(x)WO3 which is comparable to the corresponding value for the bulk monoclinic WO3 (γ-WO3). Evidence from middle angle (MAXS) and wide angle X-ray scattering (WAXS), high-resolution transmission electron microscopy (HR-TEM) and Raman spectroscopy shows that the presence of potassium leads to the formation of a K-bearing orthorhombic tungsten bronze (OTB) phase within a monoclinic WO3 host structure. Our ab initio molecular dynamics calculations show that the formation of the OTB phase provides superior strength to the mesoporous K(0.07)WO3. PMID:26781181

  8. Electrochromism and photocatalysis in dendrite structured Ti:WO3 thin films grown by sputtering

    NASA Astrophysics Data System (ADS)

    Karuppasamy, A.

    2015-12-01

    Titanium doped tungsten oxide (Ti:WO3) thin films with dendrite surface structures were grown by co-sputtering titanium and tungsten in Ar + O2 atmosphere. Ti:WO3 thin films were deposited at oxygen flow rates corresponding to pressures in the range 1.0 × 10-3-5.0 × 10-3 mbar. Argon flow rate and sputtering power densities for titanium (2 W/cm2) and tungsten (3 W/cm2) were kept constant. Ti:WO3 films deposited at an oxygen pressure of 5 × 10-3 mbar are found to be better electrochromic and photocatalytic. They have high optical modulation (80% at λ = 550 nm), coloration efficiency (60 cm2/C at λ = 550 nm), electron/ion storage and removal capacity (Qc: -22.01 mC/cm2, Qa: 17.72 mC/cm2), reversibility (80%) and methylene blue decomposition rate (-1.38 μmol/l d). The combined effects of titanium doping, dendrite surface structures and porosity leads to significant enhancement in the electrochromic and photocatalytic properties of Ti:WO3 films.

  9. Ultrasmall Biocompatible WO3- x Nanodots for Multi-Modality Imaging and Combined Therapy of Cancers.

    PubMed

    Wen, Ling; Chen, Ling; Zheng, Shimin; Zeng, Jianfeng; Duan, Guangxin; Wang, Yong; Wang, Guanglin; Chai, Zhifang; Li, Zhen; Gao, Mingyuan

    2016-07-01

    Ultrasmall biocompatible WO3 - x nanodots with an outstanding X-ray radiation sensitization effect are prepared, and demonstrated to be applicable for multi-modality tumor imaging through computed tomography and photoacoustic imaging (PAI), and effective cancer treatment combining both photothermal therapy and radiation therapy.

  10. Effects of Nickel Doping on the Multiferroic and Magnetic Phases of MnWO 4

    DOE PAGES

    Poudel, N.; Lorenz, B.; Lv, B.; Wang, Y. Q.; Ye, F.; Wang, Jinchen; Fernandez-baca, J. A.; Chu, C. W.

    2015-12-15

    There are various orders in multiferroic materials with a frustrated spiral spin modulation inducing a ferroelectric state are extremely sensitive to small perturbations such as magnetic and electric fields, external pressure, or chemical substitutions. A classical multiferroic, the mineral Hubnerite with chemical formula MnWO4, shows three different magnetic phases at low temperature. The intermediate phase between 7.5K < T < 12.7K is multiferroic and ferroelectricity is induced by an inversion symmetry breaking spiral Mn-spin order and strong spin-lattice interactions. Furthermore, the substitution of Ni2+ (spin 1) for Mn2+ (spin 5/2) in MnWO4 and its effects on the magnetic and multiferroicmore » phases are studied. The ferroelectric phase is stabilized for low Ni content (up to 10%). Upon further Ni doping, the polarization in the ferroelectric phase is quickly suppressed while a collinear and commensurate magnetic phase, characteristic of the magnetic structure in NiWO4, appears first at higher temperature, gradually extends to lower temperature, and becomes the ground state above 30% doping. Between 10% and 30%, the multiferroic phase coexists with the collinear commensurate phase. In this concentration region, the spin spiral plane is close to the a-b plane which explains the drop of the ferroelectric polarization. Finally, the phase diagram of Mn1-xNixWO4 is derived by a combination of magnetic susceptibility, specific heat, electric polarization, and neutron scattering measurements.« less

  11. Electrochemical Performance of Morphologically Different Bi2WO6 Nanostructures Synthesized via a Hydrothermal Route

    NASA Astrophysics Data System (ADS)

    Wang, Fei; Yang, Hua; Zhang, Haimin; Su, Junyan; Wang, Xiangxian

    2016-08-01

    Morphologically different Bi2WO6 nanostructures have been synthesized via a hydrothermal route, where the morphology was tailored by varying the pH value of the precursor solution. The samples prepared at pH 1, 7, and 11 consisted of flower-like hierarchical structures with average diameter of 7 μm, irregular flake-like structures with average thickness of 90 nm, and uniform spherical structures with average size of 85 nm, respectively. The electrochemical performance of the as-prepared Bi2WO6 samples was investigated by cyclic voltammetry, galvanostatic charge-discharge measurements, and electrochemical impedance spectroscopy. In 1 M KOH electrolyte at current density of 0.5 mA cm-2, the specific capacitance of the Bi2WO6 with flower-like hierarchical, flake-like, and spherical structure was measured to be 255 F g-1, 214 F g-1, and 412 F g-1, respectively. After 850 charge-discharge cycles at current density of 3 mA cm-2, the capacitance of the three samples remained at 87%, 78%, and 95% of the initial value, respectively. Among the three types of Bi2WO6 morphology, the spherical structure delivered the best electrochemical performance.

  12. Hierarchical nanostructured WO3-SnO2 for selective sensing of volatile organic compounds.

    PubMed

    Nayak, Arpan Kumar; Ghosh, Ruma; Santra, Sumita; Guha, Prasanta Kumar; Pradhan, Debabrata

    2015-08-01

    It remains a challenge to find a suitable gas sensing material that shows a high response and shows selectivity towards various gases simultaneously. Here, we report a mixed metal oxide WO3-SnO2 nanostructured material synthesized in situ by a simple, single-step, one-pot hydrothermal method at 200 °C in 12 h, and demonstrate its superior sensing behavior towards volatile organic compounds (VOCs) such as ammonia, ethanol and acetone. SnO2 nanoparticles with controlled size and density were uniformly grown on WO3 nanoplates by varying the tin precursor. The density of the SnO2 nanoparticles on the WO3 nanoplates plays a crucial role in the VOC selectivity. The responses of the present mixed metal oxides are found to be much higher than the previously reported results based on single/mixed oxides and noble metal-doped oxides. In addition, the VOC selectivity is found to be highly temperature-dependent, with optimum performance obtained at 200 °C, 300 °C and 350 °C for ammonia, ethanol and acetone, respectively. The present results on the cost-effective noble metal-free WO3-SnO2 sensor could find potential application in human breath analysis by non-invasive detection. PMID:26134476

  13. Au nanoparticle-functionalised WO3 nanoneedles and their application in high sensitivity gas sensor devices.

    PubMed

    Vallejos, Stella; Stoycheva, Toni; Umek, Polona; Navio, Cristina; Snyders, Rony; Bittencourt, Carla; Llobet, Eduard; Blackman, Christopher; Moniz, Savio; Correig, Xavier

    2011-01-01

    A new method of synthesising nanoparticle-functionalised nanostructured materials via Aerosol Assisted Chemical Vapour Deposition (AACVD) has been developed. Co-deposition of Au nanoparticles with WO(3) nanoneedles has been used to deposit a sensing layer directly onto gas sensor substrates providing devices with a six-fold increase in response to low concentrations of a test analyte (ethanol). PMID:21103469

  14. Enhanced photocatalytic activity in anodized WO3-loaded TiO2 nanotubes

    NASA Astrophysics Data System (ADS)

    Nazari, M.; Golestani-Fard, F.; Bayati, R.; Eftekhari-Yekta, B.

    2015-04-01

    In this work, TiO2 and WO3-grafted TiO2 nanotubes were grown via anodizing of titanium substrates in tungstate containing electrolytes. The samples were characterized in detail by XRD, XPS, SEM, EDX, and UV-Vis spectrophotometry techniques. Besides, photocatalytic characteristics were evaluated through measuring the degradation rate of 4-chlorophenol to establish a correlation between structure and photochemical properties. We were able to control morphology and growth mode of nanotubes from a tubular to a worm-like structure by changing the electrolyte composition. The samples possessed an anatase-rutile matrix where the anatase/rutile ratio was found to increase with the concentration of tungstate in the electrolyte. We attributed this observation to change in electrical conductivity of the electrolyte and the heat generated on the substrates. It was unambiguously revealed that a composite of WO3 and TiO2 forms and, in parallel, tungsten is doped into the crystalline lattice of TiO2. The maximum photocatalytic reaction rate constant for TiO2 and WO3-TiO2 samples was determined to be 0.0131 and 0.0174 min-1 respectively. The grafting TiO2 nanotubes with WO3 enhances the photocatalytic activity mainly due to the hindrance of charge carrier recombination and the formation of a more acidic surface. We established a correlation between structure, stoichiometry, and photocatalytic characteristics of nanotubes.

  15. Flame Synthesized Single Crystal Nanocolumn-Structured WO3 Thin Films for Photoelectrochemical Water Splitting.

    PubMed

    Ding, Jin-Rui; Kim, Kyo-Seon

    2016-02-01

    Tungsten oxide thin films have been found as an active visible light driven photoanode material for photoelectrochemical water splitting due to its good stability in aqueous solution and energetically favorable valence band position for water oxidation. Morphology control, which determines the performance of WO3 photoanode, is one of most focuses of recent research interests. In this work, we successfully prepared monoclinic WO3 thin films on ITO glass at low range of substrate temperature with a fabrication rate around 100 nm per minute by using aerosol flame deposition process. Single crystal nanocolumns with both triangular pyramid-like and triangular prism-like structure were obtained at certain process conditions. Photoelectrochemical properties of photoelectrodes assembled with both structured WO3 thin films were investigated. The prism-like nanocolumn-structured thin film generated the current density of 1.58 mAcm(-2) at potential of 1.0 V versus Ag/AgCl in 0.5 M H2SO4 solution under illumination of AM 1.5 simulated solar light (100 mVcm(-2)). It presented superior photoelectrochemical performance to pyramid-like nanocolumn-structured WO3 thin film. PMID:27433624

  16. Composite WO3/TiO2 nanostructures for high electrochromic activity

    DOE PAGES

    Reyes-Gil, Karla R.; Stephens, Zachary D.; Stavila, Vitalie; Robinson, David B.

    2015-01-06

    A composite material consisting of TiO2 nanotubes (NT) with WO3 electrodeposited on its surface has been fabricated, detached from its Ti substrate, and attached to a fluorine-doped tin oxide (FTO) film on glass for application to electrochromic (EC) reactions. Several adhesion layers were tested, finding that a paste of TiO2 made from commercially available TiO2 nanoparticles creates an interface for the TiO2 NT film to attach to the FTO glass, which is conductive and does not cause solution-phase ions in an electrolyte to bind irreversibly with the material. The effect of NT length and WO3 concentration on the EC performancemore » were studied. As a result, the composite WO3/TiO2 nanostructures showed higher ion storage capacity, better stability, enhanced EC contrast, and longer memory time compared with the pure WO3 and TiO2 materials« less

  17. Crystal structure and magnetic properties of potassium erbium double tungstate KEr(WO4)2

    NASA Astrophysics Data System (ADS)

    Borowiec, M. T.; Dyakonov, V. P.; Wozniak, K.; Dobrzycki, L.; Berkowski, M.; Zubov, E. E.; Michalski, E.; Szewczyk, A.; Gutowska, M. U.; Zayarnyuk, T.; Szymczak, H.

    2007-02-01

    Results of structural, magnetic and specific heat investigations of the potassium erbium double tungstate, KEr(WO4)2, are presented. Potassium erbium double-tungstate KEr(WO4)2 single crystals have been grown by the top-seeded solution growth method (TSSG) and modified Czochralski techniques. It crystallizes in the monoclinic crystal structure (C 2/c space group). The unit cell contains four formula units and is described by parameters a = 10.615(2) Å, b = 10.316(2) Å, c = 7.534(2) Å, β = 130.73(3)°. From the x-ray diffraction measurements the fractional atomic coordinates, displacement parameters and interatomic distances have been determined. The specific heat C(T) of the KEr(WO4)2 crystal has been measured over a temperature range of 0.6-300 K. The susceptibility has been studied at T = 0.25-4.0 K. The magnetic phase transition was observed at a temperature of 0.48 K. The magnetization has been measured in the temperature region from 4.2 to 60 K and in magnetic field up to 1.6 T. A strong anisotropy of magnetic properties was found. The temperature and field dependences of susceptibility and magnetization data were used for both elucidation of character of the magnetic ordering and calculation of the exchange and dipole-dipole interaction energies as well as for determination of the possible magnetic structure of KEr(WO4)2.

  18. Bi 2O 3-WO 3 compounds for photocatalytic applications by solid state and viscous processing

    NASA Astrophysics Data System (ADS)

    Finlayson, A. P.; Ward, E.; Tsaneva, V. N.; Glowacki, B. A.

    Water-splitting photoelectrochemical cells utilising photocatalysts have the potential to become a significant hydrogen source for fuel cells. Historically, the photocatalytic properties of TiO 2 and other compounds have been carefully investigated, but they suffer from poor energy conversion efficiencies for solar radiation. Inspired by the low bandgaps and high electrical conductivities of WO 3 and Bi 2O 3, this study investigates the suitability of compounds within this binary system as efficient photocatalysts. The structure and optical absorption spectra of these compounds have been determined via X-ray diffraction and UV-vis spectroscopy over the range of 300-900 nm. The semiconductor bandgaps of Bi 2O 3, WO 3 and Bi 2WO 6 were found to be 0.2 eV, in agreement with previously reported results. Two sample preparation techniques have been considered—solid-state processing and viscous processing techniques. A custom-built, computerised micro-coextrusion system has been used to prepare intermediate compounds from the WO 3-Bi 2O 3 binary oxide system and the design and optimisation of this technique are discussed.

  19. Robust Real-Time Wide-Area Differential GPS Navigation

    NASA Technical Reports Server (NTRS)

    Yunck, Thomas P. (Inventor); Bertiger, William I. (Inventor); Lichten, Stephen M. (Inventor); Mannucci, Anthony J. (Inventor); Muellerschoen, Ronald J. (Inventor); Wu, Sien-Chong (Inventor)

    1998-01-01

    The present invention provides a method and a device for providing superior differential GPS positioning data. The system includes a group of GPS receiving ground stations covering a wide area of the Earth's surface. Unlike other differential GPS systems wherein the known position of each ground station is used to geometrically compute an ephemeris for each GPS satellite. the present system utilizes real-time computation of satellite orbits based on GPS data received from fixed ground stations through a Kalman-type filter/smoother whose output adjusts a real-time orbital model. ne orbital model produces and outputs orbital corrections allowing satellite ephemerides to be known with considerable greater accuracy than from die GPS system broadcasts. The modeled orbits are propagated ahead in time and differenced with actual pseudorange data to compute clock offsets at rapid intervals to compensate for SA clock dither. The orbital and dock calculations are based on dual frequency GPS data which allow computation of estimated signal delay at each ionospheric point. These delay data are used in real-time to construct and update an ionospheric shell map of total electron content which is output as part of the orbital correction data. thereby allowing single frequency users to estimate ionospheric delay with an accuracy approaching that of dual frequency users.

  20. The infrared properties of the GPS and CSS radio sources

    NASA Astrophysics Data System (ADS)

    O'Dea, C. P.

    2016-02-01

    I review the results of three Spitzer studies of GHz-Peaked Spectrum (GPS) and Compact Steep Spectrum (CSS) radio galaxies. The luminosity of the IR continuum and the high ionization lines confirm that some GPS/CSS can have central engines which are similar to those of the extended powerful radio sources. This is consistent with the hypothesis that some GPS/CSS can evolve to become the large-scale sources. Warm H_2 is common in the GPS/CSS sources consistent with feedback via jet-ISM interaction. The GPS/CSS seem to have higher star formation rates than typical (2JY + 3CRR) radio sources. This should be confirmed with a larger sample. If compact sources interact with dense, clumpy star forming clouds and if the interaction with the dense medium sufficiently enhances the radio power, these star forming galaxies with enhanced radio emission will be selected for the current bright samples of GPS and CSS sources. This will increase the number of GPS and CSS sources which are observed to be forming stars. If radio sources have longer lives and/or star formation is more common in large radio galaxies, the need for a new population of star forming compact sources with enhanced radio emission is reduced.

  1. Application of neural networks to South African GPS TEC modelling

    NASA Astrophysics Data System (ADS)

    Habarulema, John Bosco; McKinnell, Lee-Anne; Cilliers, Pierre J.; Opperman, Ben D. L.

    2009-06-01

    The propagation of radio signals in the Earth's atmosphere is dominantly affected by the ionosphere due to its dispersive nature. Global Positioning System (GPS) data provides relevant information that leads to the derivation of total electron content (TEC) which can be considered as the ionosphere's measure of ionisation. This paper presents part of a feasibility study for the development of a Neural Network (NN) based model for the prediction of South African GPS derived TEC. The South African GPS receiver network is operated and maintained by the Chief Directorate Surveys and Mapping (CDSM) in Cape Town, South Africa. Vertical total electron content (VTEC) was calculated for four GPS receiver stations using the Adjusted Spherical Harmonic (ASHA) model. Factors that influence TEC were then identified and used to derive input parameters for the NN. The well established factors used are seasonal variation, diurnal variation, solar activity and magnetic activity. Comparison of diurnal predicted TEC values from both the NN model and the International Reference Ionosphere (IRI-2001) with GPS TEC revealed that the IRI provides more accurate predictions than the NN model during the spring equinoxes. However, on average the NN model predicts GPS TEC more accurately than the IRI model over the GPS locations considered within South Africa.

  2. Accuracy of High-Rate GPS for Seismology

    NASA Technical Reports Server (NTRS)

    Elosegui, P.; Davis, J. L.; Oberlander, D.; Baena, R.; Ekstrom, G.

    2006-01-01

    We built a device for translating a GPS antenna on a positioning table to simulate the ground motions caused by an earthquake. The earthquake simulator is accurate to better than 0.1 mm in position, and provides the "ground truth" displacements for assessing the technique of high-rate GPS. We found that the root-mean-square error of the 1-Hz GPS position estimates over the 15-min duration of the simulated seismic event was 2.5 mm, with approximately 96% of the observations in error by less than 5 mm, and is independent of GPS antenna motion. The error spectrum of the GPS estimates is approximately flicker noise, with a 50% decorrelation time for the position error of approx.1.6 s. We that, for the particular event simulated, the spectrum of dependent error in the GPS measurements. surface deformations exceeds the GPS error spectrum within a finite band. More studies are required to determine whether a generally optimal bandwidth exists for a target group of seismic events.

  3. Applications of Clocks to Space Navigation & "Planetary GPS"

    NASA Technical Reports Server (NTRS)

    Lichten, Stephen M.

    2004-01-01

    The ability to fly atomic clocks on GPS satellites has profoundly defined the capabilities and limitations of GPS in near-Earth applications. It is likely that future infrastructure for Lunar and Mars applications will be constrained by financial factors. The development of a low cost, small, high performance space clock -- or ultrahigh performance space clocks -- could revolutionize and drive the entire approach to GPS-like systems at the Moon (or Mars), and possibly even change the future of GPS at Earth. Many system trade studies are required. The performance of future GPS-like tracking systems at the Moon or Mars will depend critically on clock performance, availability of inertial sensors, and constellation coverage. Example: present-day GPS carry 10(exp -13) clocks and require several updates per day. With 10(exp -15) clocks, a constellation at Mars could operate autonomously with updates just once per month. Use of GPS tracking at the Moon should be evaluated in a technical study.

  4. Emerging Applications of Measurements From GPS and Related Signals

    NASA Astrophysics Data System (ADS)

    Zuffada, Cinzia; Zumberge, Jim; Chao, Yi; Kintner, Paul; Leroy, Stephen; Anderson, Jim

    2005-04-01

    Over the past two decades, the value of Global Positioning System (GPS) measurements to solid Earth science, atmospheric science, ocean science, space physics, and other areas has been firmly established in some cases, such as global and regional surface deformation. In other cases, the value of GPS measurements is now emerging or showing a potential. Some researchers believe the time now has come to assess, from a multi-program and multi-discipline perspective, the benefits of a continuing investment in GPS technology development, and to determine its role in the vision and priorities of national research organizations. In conjunction with the 2004 AGU Fall Meeting special focus session on ``Emerging science applications of measurements from GPS/GNSS and GPS-like signals: Recent results and future possibilities,'' a workshop was held on the prior evening, 16 December. Chaired by Jim Anderson of Harvard University, the workshop objective stated in the invitation to participants was ``...to identify and articulate the key scientific questions that are optimally, or perhaps uniquely, addressed by GPS (or more generally, the Global Navigation Satellite System, GNSS, to include other constellations such as Galileo) or GPS-like observations, and determine their relevance to existing or planned national Earth-science research programs.''

  5. NO{sub 2} gas sensing of flame-made Pt-loaded WO{sub 3} thick films

    SciTech Connect

    Samerjai, Thanittha; Tamaekong, Nittaya; Liewhiran, Chaikarn; Wisitsoraat, Anurat; Phanichphant, Sukon

    2014-06-01

    Unloaded WO{sub 3} and 0.25–1.0 wt% Pt-loaded WO{sub 3} nanoparticles for NO{sub 2} gas detection were synthesized by flame spray pyrolysis (FSP) and characterized via X-ray diffraction (XRD), scanning electron microscopy (SEM) and high resolution transmission electron microscopy (HRTEM). The BET surface area (SSA{sub BET}) of the nanoparticles was measured by nitrogen adsorption. The NO{sub 2} sensing properties of the sensors based on unloaded and Pt-loaded WO{sub 3} nanoparticles were investigated. The results showed that the gas sensing properties of the Pt-loaded WO{sub 3} sensors were excellent to those of the unloaded one. Especially, 0.25 wt% Pt-loaded WO{sub 3} sensor showed highest response to NO{sub 2} than the others at low operating temperature of 150 °C. - Graphical abstract: The response of 0.25 wt% Pt-loaded WO3 sensor was 637 towards NO{sub 2} concentration of 10 ppm at 150 °C. - Highlights: • Unloaded and Pt-loaded WO{sub 3} nanoparticles for NO{sub 2} gas detection were synthesized by flame spray pyrolysis (FSP). • Gas sensing properties of the Pt-loaded WO{sub 3} sensors were excellent to those of the unloaded one. • 0.25 wt% Pt-loaded WO{sub 3} sensor showed highest response to NO{sub 2} at low operating temperature of 150 °C.

  6. A graphene-coupled Bi2WO6 nanocomposite with enhanced photocatalytic performance: a first-principles study.

    PubMed

    Ren, Fengzhu; Zhang, Jihua; Wang, Yuanxu; Yao, Wenzhi

    2016-05-18

    An experimentally synthesized graphene/Bi2WO6 composite showed an enhancement of the visible-light photocatalytic activity, while the underlying mechanism is not known. Here, first-principles calculations based on density functional theory were performed to explore the various properties of the graphene/Bi2WO6(010) composite aiming at gaining insights into the mechanism of its photocatalytic activity. The stability, electronic properties, charge transfer, and visible-light response were investigated in detail on the Bi2WO6(010) surface coupled with graphene. An analysis of charge distribution and Bader charge shows that there is a strong covalent bonding between graphene and the Bi2WO6(010) surface. The covalent interaction induces a small bandgap in graphene. The interband transition of graphene and the surface states of the Bi2WO6(010) surface would cause the absorption spectrum of graphene/Bi2WO6(010) to cover the entire visible-light region and even the infrared-light region. The photogenerated electrons flow to graphene from the conduction band of Bi2WO6 under the built-in electric field and band edge potential well. Thus, graphene serves as a photogenerated electron collector and transporter which significantly reduces the probability of electron-hole recombination and increases catalytic reaction sites not only on the surface of graphene but on also the surface of Bi2WO6. The decrease of charge recombination is possibly responsible for the enhancement of the visible-light photocatalytic activity of the graphene/Bi2WO6(010) nanocomposite. PMID:27156737

  7. Recent genome reduction of Wolbachia in Drosophila recens targets phage WO and narrows candidates for reproductive parasitism

    PubMed Central

    Metcalf, Jason A.; Jo, Minhee; Bordenstein, Sarah R.; Jaenike, John

    2014-01-01

    Wolbachia are maternally transmitted endosymbionts that often alter their arthropod hosts’ biology to favor the success of infected females, and they may also serve as a speciation microbe driving reproductive isolation. Two of these host manipulations include killing males outright and reducing offspring survival when infected males mate with uninfected females, a phenomenon known as cytoplasmic incompatibility. Little is known about the mechanisms behind these phenotypes, but interestingly either effect can be caused by the same Wolbachia strain when infecting different hosts. For instance, wRec causes cytoplasmic incompatibility in its native host Drosophila recens and male killing in D. subquinaria. The discovery of prophage WO elements in most arthropod Wolbachia has generated the hypothesis that WO may encode genes involved in these reproductive manipulations. However, PCR screens for the WO minor capsid gene indicated that wRec lacks phage WO. Thus, wRec seemed to provide an example where phage WO is not needed for Wolbachia-induced reproductive manipulation. To enable investigation of the mechanism of phenotype switching in different host backgrounds, and to examine the unexpected absence of phage WO, we sequenced the genome of wRec. Analyses reveal that wRec diverged from wMel approximately 350,000 years ago, mainly by genome reduction in the phage regions. While it lost the minor capsid gene used in standard PCR screens for phage WO, it retained two regions encompassing 33 genes, several of which have previously been associated with reproductive parasitism. Thus, WO gene involvement in reproductive manipulation cannot be excluded and reliance on single gene PCR should not be used to rule out the presence of phage WO in Wolbachia. Additionally, the genome sequence for wRec will enable transcriptomic and proteomic studies that may help elucidate the Wolbachia mechanisms of altered reproductive manipulations associated with host switching, perhaps among

  8. Assessing the role of GPs in Nordic health care systems.

    PubMed

    Quaye, Randolph K

    2016-05-01

    Purpose This paper examines the changing role of general practitioners (GPs) in Nordic countries of Sweden, Norway and Denmark. It aims to explore the "gate keeping" role of GPs in the face of current changes in the health care delivery systems in these countries. Design/methodology/approach Data were collected from existing literature, interviews with GPs, hospital specialists and representatives of Danish regions and Norwegian Medical Association. Findings The paper contends that in all these changes, the position of the GPs in the medical division of labor has been strengthened, and patients now have increased and broadened access to choice. Research limitations/implications Health care cost and high cancer mortality rates have forced Nordic countries of Sweden, Norway and Denmark to rethink their health care systems. Several attempts have been made to reduce health care cost through market reform and by strenghtening the position of GPs. The evidence suggests that in Norway and Denmark, right incentives are in place to achieve this goal. Sweden is not far behind. The paper has limitations of a small sample size and an exclusive focus on GPs. Practical implications Anecdotal evidence suggests that physicians are becoming extremely unhappy. Understanding the changing status of primary care physicians will yield valuable information for assessing the effectiveness of Nordic health care delivery systems. Social implications This study has wider implications of how GPs see their role as potential gatekeepers in the Nordic health care systems. The role of GPs is changing as a result of recent health care reforms. Originality/value This paper contends that in Norway and Denmark, right incentives are in place to strengthen the position of GPs.

  9. Using GRACE as an Orbiting Fiducial Laboratory for GPS

    NASA Astrophysics Data System (ADS)

    Haines, B. J.; Bar-Sever, Y. E.; Bertiger, W.; Byun, S.; Desai, S. D.; Hajj, G.

    2006-12-01

    Uncertainties in the phase-center variations (PCV) of the GPS transmitter antennas are among the limiting sources of error in GPS-based global geodesy. We have used data from the BlackJack GPS receivers onboard the twin GRACE satellites to develop new estimates of GPS satellite antenna PCV. The estimates are expressed as tracking observable (distance) corrections mapped in two dimensions (nadir angle and azimuth). We have developed maps for both ionosphere-free carrier phase (LC) and pseudorange (PC). The GRACE tandem mission offers a number of substantial advantages for developing GPS PCV maps. The scale (mean height) of our GRACE orbit solutions is well determined at the cm level from dynamical constraints, and there is no troposphere signal to confound interpretation of the measurements. The multipath environment is also very favorable. We discuss our strategy for determining the GPS satellite PCV estimates from these data, and describe evaluations of the estimates using independent GPS data from both the TOPEX/POSEIDON (T/P; 1992--2005) and Jason-1 (2001 - ) missions. A heretofore unexplained 5--6 cm offset in the solved-for position of the T/P receiver antenna is reduced to less than 1 cm by applying the GRACE-based GPS PCV maps. The corresponding offset for Jason-1 is similarly decreased. Equally important, a spurious long-term (4-yr) drift in the daily estimated Jason-1 offsets is significantly reduced. These results hint at the potential benefits of these new GPS antenna PCV maps for wide-ranging geodetic applications wherein scale and long-term stability are important.

  10. Why GPS makes distances bigger than they are

    PubMed Central

    Ranacher, Peter; Brunauer, Richard; Trutschnig, Wolfgang; Van der Spek, Stefan; Reich, Siegfried

    2016-01-01

    ABSTRACT Global navigation satellite systems such as the Global Positioning System (GPS) is one of the most important sensors for movement analysis. GPS is widely used to record the trajectories of vehicles, animals and human beings. However, all GPS movement data are affected by both measurement and interpolation errors. In this article we show that measurement error causes a systematic bias in distances recorded with a GPS; the distance between two points recorded with a GPS is – on average – bigger than the true distance between these points. This systematic ‘overestimation of distance’ becomes relevant if the influence of interpolation error can be neglected, which in practice is the case for movement sampled at high frequencies. We provide a mathematical explanation of this phenomenon and illustrate that it functionally depends on the autocorrelation of GPS measurement error (C). We argue that C can be interpreted as a quality measure for movement data recorded with a GPS. If there is a strong autocorrelation between any two consecutive position estimates, they have very similar error. This error cancels out when average speed, distance or direction is calculated along the trajectory. Based on our theoretical findings we introduce a novel approach to determine C in real-world GPS movement data sampled at high frequencies. We apply our approach to pedestrian trajectories and car trajectories. We found that the measurement error in the data was strongly spatially and temporally autocorrelated and give a quality estimate of the data. Most importantly, our findings are not limited to GPS alone. The systematic bias and its implications are bound to occur in any movement data collected with absolute positioning if interpolation error can be neglected. PMID:27019610

  11. Observation on long afterglow of Tb{sup 3+} in CaWO{sub 4}

    SciTech Connect

    Wu, Haoyi; Hu, Yihua; Kang, Fengwen; Chen, Li; Wang, Xiaojuan; Ju, Guifang; Mu, Zhongfei

    2011-12-15

    Graphical abstract: The afterglow of Tb{sup 3+} is observed in CaWO{sub 4} matrix. The main emission of the afterglow is ascribed to the {sup 5}D{sub 4} {yields} {sup 7}F{sub 5} and {sup 5}D{sub 4} {yields} {sup 7}F{sub 6}. Emission due to {sup 5}D{sub 3} {yields} {sup 7}F{sub 4} and {sup 5}D{sub 3} {yields} {sup 7}F{sub 5} is weak. The cross-relaxation dominate the afterglow emission and it enhances the transition from {sup 5}D{sub 4} whereas from {sup 5}D{sub 3}. Highlights: Black-Right-Pointing-Pointer A green long afterglow is observed from Tb{sup 3+} in CaWO{sub 4} matrix. Black-Right-Pointing-Pointer Two traps which may have a strong influence on the afterglow properties are revealed by TL. Black-Right-Pointing-Pointer A mechanism model based on energy transfer from WO{sub 4}{sup 2-} group to Tb{sup 3+} followed by cross-relaxation is proposed. -- Abstract: The Tb{sup 3+} doped CaWO{sub 4} phosphors are synthesized via high temperature solid state reaction. The X-ray diffraction shows that small amount of Tb{sup 3+} does not have a significant influence on the structure of CaWO{sub 4}. A broad absorption band of the WO{sub 4}{sup 2-} group is observed from photoluminescence and the energy transfer from WO{sub 4}{sup 2-} group to Tb{sup 3+} ions induces the f-f transition. The cross-relaxation between two adjacent Tb{sup 3+} ions weakens {sup 5}D{sub 3}-{sup 7}F{sub j} transitions and enhances the {sup 5}D{sub 4}-{sup 7}F{sub j} transitions, leading to a green long afterglow of the phosphors. The thermoluminescence curves centered around 75 Degree-Sign C reveal the trap depth for afterglow generation is about 0.74-0.77 eV. The optimum Tb{sup 3+} concentration for afterglow properties is about 1%. A deep hole trap is induced when Tb{sup 3+} concentration exceeds 1% and it suppresses the thermoluminescence and the decay properties.

  12. The assemblage WO2 + H2O as a steady-state hydrogen source in moderately reduced hydrothermal experiments

    USGS Publications Warehouse

    Cygan, G.L.; I-Ming, Chou

    1990-01-01

    The values of fH2 for the assemblage WO2 + WO2.72 + H2O (designated as WO) have been measured in sealed Au capsules under an external pressure of 2 kbar CH4 and between 650 and 800??C using Ag-AgBr-HBr sensors of fH2. The fH2 values obtained can be represented by the equation log(fWOH2)2kbar,T(??0.06) = (-1924.9 ??(T,K) + 4.06 and are found to be slightly greater than those associated with the previously calibrated C-CH4 buffer. -from Authors

  13. Autonomous Relative Navigation for Formation-Flying Satellites Using GPS

    NASA Technical Reports Server (NTRS)

    Gramling, Cheryl; Carpenter, J. Russell; Long, Anne; Kelbel, David; Lee, Taesul

    2000-01-01

    The Goddard Space Flight Center is currently developing advanced spacecraft systems to provide autonomous navigation and control of formation flyers. This paper discusses autonomous relative navigation performance for a formation of four eccentric, medium-altitude Earth-orbiting satellites using Global Positioning System (GPS) Standard Positioning Service (SPS) and "GPS-like " intersatellite measurements. The performance of several candidate relative navigation approaches is evaluated. These analyses indicate that an autonomous relative navigation position accuracy of 1meter root-mean-square can be achieved by differencing high-accuracy filtered solutions if only measurements from common GPS space vehicles are used in the independently estimated solutions.

  14. GPS-based certification for the microwave landing system

    NASA Technical Reports Server (NTRS)

    Thornton, C. L.; Young, L. E.; Wu, S. C.; Thomas, J. B.

    1984-01-01

    An MLS (microwave landing system) certification system based on the Global Positioning System (GPS) is described. To determine the position history of the flight inspection aircraft during runway approach, signals from the GPS satellites, together with on-board radar altimetry, are used. It is shown that the aircraft position relative to a fixed point on the runway at threshold can be determined to about 30 cm vertically and 1 m horizontally. A requirement of the system is that the GPS receivers be placed on each flight inspection aircraft and at selected ground sites. The effects of different error sources on the determination of aircraft instantaneous position and its dynamics are analyzed.

  15. High-Precision Motorcycle Trajectory Measurements Using GPS

    NASA Astrophysics Data System (ADS)

    Koyama, Yuichiro; Tanaka, Toshiyuki

    A method for measuring motorcycle trajectory using GPS is needed for simulating motorcycle dynamics. In GPS measurements of a motorcycle, both the declination of the motorcycle and obstacles near the course can cause problems. Therefore, we propose a new algorithm for GPS measurement of motorcycle trajectory. We interpolate the missing observation data within a few seconds using polynomial curves, and use a Kalman filter to smoothen position calculations. This results in obtaining trajectory with high accuracy and with sufficient continuity. The precision is equal to that of fixed point positioning, given a sufficient number of available satellites.

  16. Forward and Inverse Modeling of GPS Multipath for Snow Monitoring

    NASA Astrophysics Data System (ADS)

    Nievinski, Felipe Geremia

    Snowpacks provide reservoirs of freshwater, storing solid precipitation and delaying runoff to be released later in the spring and summer when it is most needed. The goal of this dissertation is to develop the technique of GPS multipath reflectometry (GPS-MR) for ground-based measurement of snow depth. The phenomenon of multipath in GPS constitutes the reception of reflected signals in conjunction with the direct signal from a satellite. As these coherent direct and reflected signals go in and out of phase, signal-to-noise ratio (SNR) exhibits peaks and troughs that can be related to land surface characteristics. In contrast to other GPS reflectometry modes, in GPS-MR the poorly separated composite signal is collected utilizing a single antenna and correlated against a single replica. SNR observations derived from the newer L2-frequency civilian GPS signal (L2C) are used, as recorded by commercial off-the-shelf receivers and geodetic-quality antennas in existing GPS sites. I developed a forward/inverse approach for modeling GPS multipath present in SNR observations. The model here is unique in that it capitalizes on known information about the antenna response and the physics of surface scattering to aid in retrieving the unknown snow conditions in the antenna surroundings. This physically-based forward model is utilized to simulate the surface and antenna coupling. The statistically-rigorous inverse model is considered in two parts. Part I (theory) explains how the snow characteristics are parameterized; the observation/parameter sensitivity; inversion errors; and parameter uncertainty, which serves to indicate the sensing footprint where the reflection originates. Part II (practice) applies the multipath model to SNR observations and validates the resulting GPS retrievals against independent in situ measurements during a 1-3 year period in three different environments---grasslands, alpine, and forested. The assessment yields a correlation of 0.98 and an RMS error

  17. Calibration and integrity verification techniques applied to GPS simulators

    NASA Astrophysics Data System (ADS)

    Stulken, D. A.

    Automated calibration and signal verification techniques which are used in GPS simulators to ensure a high level of fidelity of the test stimulus employed in evaluating the performance of GPS receivers have been developed. The present techniques involve satellite signal power levels, jammer signal power levels, time of arrival of satellite signals, and the coordinated timing of simulated satellite signals with respect to the simulation of the host vehicle interface signals. From initial simulation and evaluation system design efforts, a new family of GPS RF signal generators were developed, the multiple channel signal generator and the single channel signal generator.

  18. Accurate aircraft wind measurements using the global positioning system (GPS)

    SciTech Connect

    Dobosy, R.J.; Crawford, T.L., McMillen, R.T., Dumas, E.J.

    1996-11-01

    High accuracy measurements of the spatial distribution of wind speed are required in the study of turbulent exchange between the atmosphere and the earth. The use of a differential global positioning system (GPS) to determine the sensor velocity vector component of wind speed is discussed in this paper. The results of noise and rocking testing are summarized, and fluxes obtained from the GPS-based methods are compared to those measured from systems on towers and airplanes. The GPS-based methods provided usable measurements that compared well with tower and aircraft data at a significantly lower cost. 21 refs., 1 fig., 2 tabs.

  19. 77 FR 23668 - GPS Satellite Simulator Working Group Notice of Meeting

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-04-20

    ... Department of the Air Force GPS Satellite Simulator Working Group Notice of Meeting AGENCY: The United States... Global Positioning Systems (GPS) Directorate will be hosting an open GPS Satellite Simulator Working... form a functioning GPS Satellite Simulator Working Group with industry and government...

  20. Satellite Constellations for Atmospheric Sounding with GPS: A Revolution in Atmospheric and Ionospheric Research

    NASA Technical Reports Server (NTRS)

    Yunck, T. P.; McCleese, D. J.; Melbourne, W. G.; Thornton, C. L.

    1995-01-01

    Spaceborne Global Positioning System (GPS) atmospheric science is blossoming. Proposed missions require high performance GPS flight receivers with capabilities beyond most space needs. With GPS technology maturing, and lower cost spaceborne receivers, GPS usage is expanding rapidly for space flight projects. Several of these are discussed, such as atmospheric occultation, ionospheric imaging, etc.

  1. Deformation of Central Anatolia: GPS implications

    NASA Astrophysics Data System (ADS)

    Aktuğ, Bahadır; Parmaksız, Erdem; Kurt, Mustafa; Lenk, Onur; Kılıçoğlu, Ali; Gürdal, M. Ali; Özdemir, Soner

    2013-07-01

    Central Anatolia plays a key role to connect the theories about the subduction of African Plate along Hellenic and Cyprian Arcs and the collision of Arabia indenter along Bitlis-Zagros Thrust Zone. Taking place between the North Anatolian and East Anatolian mega shear zones, the neotectonics of seismically less active Central Anatolia is often regarded as tectonic escape or extrusion tectonics. Although, available GPS studies dating back to early 1990s reported coherent rotation, they were mostly focused on the seismically more active and more populated Western Anatolia and lack sufficient spatial resolution in quantifying second-order structures such as Tuz Gölü Fault Zone, Central Anatolia Fault Zone which comprises Ecemiş Fault and Erciyes Fault, Ezinepazarı Fault and their related basins and associated processes. Besides, the new dense GPS velocity field of Central Anatolia exhibits systematic local patterns of internal deformation which is inconsistent with either coherent rotation or translation. The velocity gradients computed along the rotation profiles of Central Anatolia show nearly westward and smooth increments which cannot be explained through a simple rotation/transport of Central Anatolia Basin. Moreover, estimating and removing an Euler rigid-body rotation rate which is computed from the sites lying in the middle part of Central Anatolia absorbs the velocity discrepancies between the Eastern and Western part of Central Anatolia down to a few millimetres and leaves out systematic residuals. Upon completion of Turkish National Fundamental GPS Network (TNFGN) in 1999, early revision surveys were carried out in Marmara region because of the 1999 Marmara earthquakes. Additional observations were carried out in Central Anatolia, resulting in a velocity field of unprecedented spatial density with average inter-station distance of 30-50 km.We computed the horizontal velocity field with respect to a not-net rotation frame, to Eurasia, and to a computed

  2. Preparation of ultra-thin and high-quality WO3 compact layers and comparision of WO3 and TiO2 compact layer thickness in planar perovskite solar cells

    NASA Astrophysics Data System (ADS)

    Zhang, Jincheng; Shi, Chengwu; Chen, Junjun; Wang, Yanqing; Li, Mingqian

    2016-06-01

    In this paper, the ultra-thin and high-quality WO3 compact layers were successfully prepared by spin-coating-pyrolysis method using the tungsten isopropoxide solution in isopropanol. The influence of WO3 and TiO2 compact layer thickness on the photovoltaic performance of planar perovskite solar cells was systematically compared, and the interface charge transfer and recombination in planar perovskite solar cells with TiO2 compact layer was analyzed by electrochemical impedance spectroscopy. The results revealed that the optimum thickness of WO3 and TiO2 compact layer was 15 nm and 60 nm. The planar perovskite solar cell with 15 nm WO3 compact layer gave a 9.69% average and 10.14% maximum photoelectric conversion efficiency, whereas the planar perovskite solar cell with 60 nm TiO2 compact layer achieved a 11.79% average and 12.64% maximum photoelectric conversion efficiency.

  3. Synthesis and characterization of F-doped Cs0.33WO3-xFx particles with improved near infrared shielding ability

    NASA Astrophysics Data System (ADS)

    Liu, Jingxiao; Luo, Jiayu; Shi, Fei; Liu, Suhua; Fan, Chuanyan; Xu, Qiang; Shao, Guolin

    2015-01-01

    F-doped Cs0.33WO3-xFx particles were successfully synthesized by the hydrothermal method with hydrofluoric acid as fluorine source, and a new kind of heat insulating films were prepared from dispersion of Cs0.33WO3-xFx nanoparticles in polyvinyl alcohol (PVA) aqueous solution. The effects of F doping on the crystal structure and morphology of Cs0.33WO3-xFx particles as well as the near-infrared (NIR) shielding ability and heat insulation properties of Cs0.33WO3-xFx films were investigated. The results indicated that HF acid addition could promote the formation of rod-like Cs0.33WO3-xFx particles during hydrothermal synthesis and increase the yield of Cs0.33WO3-xFx powders. Moreover, the as-prepared films from dispersion solution of Cs0.33WO3-xFx particles exhibited higher near-infrared (NIR) shielding ability and heat insulating properties than that of the undoped Cs0.33WO3 film. Particularly, the as-prepared Cs0.33WO3-xFx sample with F/W (molar ratio)=0.45 showed best NIR shielding ability and transparent heat insulating performance. The formation mechanism of nanorod-like particles and the effects of F doping on the properties of Cs0.33WO3-xFx products were discussed.

  4. Dehydration, Dehydrogenation, and Condensation of Alcohols on Supported Oxide Catalysts Based on Cyclic (WO3)3 and (MoO3)3 Clusters

    SciTech Connect

    Rousseau, Roger J.; Dixon, David A.; Kay, Bruce D.; Dohnalek, Zdenek

    2014-01-01

    Supported early transition metal oxides have important applications in numerous catalytic reactions. In this article we review preparation and activity of well-defined model WO3 and MoO3 catalysts prepared via deposition of cyclic gas-phase (WO3)3 and (MoO3)3 clusters generated by sublimation of WO3 and MoO3 powders. Conversion of small aliphatic alcohols to alkenes, aldehydes/ketons, and ethers is employed to probe the structure-activity relationships on model WO3 and MoO3 catalysts ranging from unsupported (WO3)3 and (MoO3)3 clusters embedded in alcohol matrices, to (WO3)3 clusters supported on surfaces of other oxides, and epitaxial and nanoporous WO3 films. Detailed theoretical calculations reveal the underlying reaction mechanisms and provide insight into the origin of the differences in the WO3 and MoO3 reactivity. For the range of interrogated (WO3)3 they further shed light into the role structure and binding of (WO3)3 clusters with the support play in determining their catalytic activity.

  5. Civil Application of Differential GPS Using a Single Channel Sequential Receiver

    NASA Technical Reports Server (NTRS)

    1981-01-01

    The Global Positioning System (GPS) and its potential for area navigation, landing, and takeoff under minimum ceilings and advanced air traffic control operation is discussed. The following topics are reported: status of the GPS system; GPS signal availability for the civil community; alternative differential GPS concepts; predicted performance enhancement achievable with differential GPS and the operational improvements which will result; and a development program to test and evaluate differential GPS concepts, performance and operational procedures applicable to helicopters. Potential benefits which will be derived from helicopter use of GPS in the differential mode are identified.

  6. Forskolin-induced differentiation of BeWo cells stimulates increased tumor growth in the chorioallantoic membrane (CAM) of the turkey (Meleagris gallopavo) egg.

    PubMed

    Schneider, Ralf; Borges, Marcus; Kadyrov, Mamed

    2011-05-01

    Invasiveness of BeWo cells has been assessed in a variety of assay systems including matrigel and mouse. At the same time BeWo cells are mostly used as model system for trophoblast fusion. Here we aimed to test the properties of BeWo cells in a combined approach. We forced BeWo cells to differentiate by culturing the cells in the presence of forskolin and then used these cells for invasion assays on the chorioallantoic membrane (CAM) of the turkey. The chorioallantoic membranes of turkey eggs were incubated with medium containing forskolin, BeWo cells cultured in medium alone, BeWo cells cultured in forskolin and washed, and BeWo cells cultured in forskolin and used directly for application. Suspensions were applied onto ten CAM per condition. For local tumor formation eggs were checked for tumor development every 24h macroscopically for up to 12 days and immunohistochemistry for cytokeratin 18 and Ki-67 were used for further analysis. Forskolin alone did not have any deleterious effect on the CAM. When the CAM was incubated with BeWo cells cultured in medium 40% of the eggs developed a macroscopically visible tumor. BeWo cells stimulated with forskolin and washed induced tumor growth in 50% of the eggs, while forskolin stimulated BeWo cells applied directly onto the CAM induced tumor growth in 70% of the eggs. Forced differentiation of BeWo cells by forskolin may lead to syncytial fusion in a plastic culture dish. Under the conditions used here, i.e. in direct contact to a living tissue, forskolin-induced differentiation of BeWo cells leads to an increase in tumor formation in the CAM. Thus BeWo cells may use signaling pathways to decide for both differentiation pathways similar to primary trophoblast depending on the environment.

  7. Codeless GPS Applications to Multi-Path: CGAMP

    NASA Technical Reports Server (NTRS)

    Macdoran, P. F.; Miller, R. B.; Jenkins, D.; Lemmon, J.; Gold, K.; Schreiner, W.; Snyder, G.

    1990-01-01

    Cordless Global Positioning System (GPS) Applications to Multi-Path (CGAMP) is meeting the challenge of exploiting the L-band signals from the Global Positioning System (GPS) satellites for the measurement of the impulse response of radio transmission channels over space-Earth paths. This approach was originally suggested by E. K. Smith and has been pursued by J. Lemmon, without an affordable implementation being identifiable. In addition to the high cost of a suitable P code correlating GPS receiver, there is also the major impediment of the often announced Department of Defense policy of selective availability/anti-spoof (SA/AS) that clouds reliable access to the wideband (20 MHz) P channel of the GPS signals without cryptographic access. A technique proposed by MacDoran utilizes codeless methods for exploiting the P channel signals implemented by the use of a pair of antennas and cross correlation signal detection.

  8. A New Indoor Positioning System Architecture Using GPS Signals.

    PubMed

    Xu, Rui; Chen, Wu; Xu, Ying; Ji, Shengyue

    2015-04-29

    The pseudolite system is a good alternative for indoor positioning systems due to its large coverage area and accurate positioning solution. However, for common Global Positioning System (GPS) receivers, the pseudolite system requires some modifications of the user terminals. To solve the problem, this paper proposes a new pseudolite-based indoor positioning system architecture. The main idea is to receive real-world GPS signals, repeat each satellite signal and transmit those using indoor transmitting antennas. The transmitted GPS-like signal can be processed (signal acquisition and tracking, navigation data decoding) by the general receiver and thus no hardware-level modification on the receiver is required. In addition, all Tx can be synchronized with each other since one single clock is used in Rx/Tx. The proposed system is simulated using a software GPS receiver. The simulation results show the indoor positioning system is able to provide high accurate horizontal positioning in both static and dynamic situations.

  9. Accuracy Assessment of Digital Elevation Models Using GPS

    NASA Astrophysics Data System (ADS)

    Farah, Ashraf; Talaat, Ashraf; Farrag, Farrag A.

    2008-01-01

    A Digital Elevation Model (DEM) is a digital representation of ground surface topography or terrain with different accuracies for different application fields. DEM have been applied to a wide range of civil engineering and military planning tasks. DEM is obtained using a number of techniques such as photogrammetry, digitizing, laser scanning, radar interferometry, classical survey and GPS techniques. This paper presents an assessment study of DEM using GPS (Stop&Go) and kinematic techniques comparing with classical survey. The results show that a DEM generated from (Stop&Go) GPS technique has the highest accuracy with a RMS error of 9.70 cm. The RMS error of DEM derived by kinematic GPS is 12.00 cm.

  10. Short-Period Information in GPS Time Series

    NASA Astrophysics Data System (ADS)

    Bogusz, Janusz; Figurski, Mariusz

    2010-01-01

    This paper presents results of the Polish Active Geodetic Network (ASG-EUPOS) processing. The analyses on the GPS coordinates from sub-diurnal solutions of ASG-EUPOS and EPN data provided by Warsaw Military University of Technology were performed. The aim of this research is to find out how the tidal models used in Bernese software (solid Earth and ocean tides as well) fit to the individual conditions of GPS stations. The 1-hour solution technique of GPS data processing was utilized to obtain coordinates of above 130 Polish and foreign stations. This processing technique allowed us to recognize residual diurnal and sub-diurnal oscillations which could be next utilized for validation of the tidal models used in GPS software.

  11. DARPA looks beyond GPS for positioning, navigating, and timing

    SciTech Connect

    Kramer, David

    2014-10-01

    Cold-atom interferometry, microelectromechanical systems, signals of opportunity, and atomic clocks are some of the technologies the defense agency is pursuing to provide precise navigation when GPS is unavailable.

  12. Strategies for sub-decimeter satellite tracking with GPS

    NASA Technical Reports Server (NTRS)

    Yunck, Thomas P.; Wu, Sien-Chong; Wu, Jiun-Tsong

    1986-01-01

    Decimeter tracking of low earth orbiters can be achieved with a variety of differential GPS techniques. A precisely known global network of GPS ground receivers and a receiver aboard the user satellite are needed, and all techniques must simultaneously estimate the user and GPS satellite orbits. Three basic strategies include a purely geometric, a fully dynamic, and a hybrid strategy, the last of which combines dynamic GPS solutions with a geometric user solution. Two powerful extensions of the hybrid strategy show the most promise. The first uses a quasi-optimal synthesis of dynamics and geometry in the user solution, while the second uses a novel gravity adjustment method to exploit data from repeat ground tracks in a computationally efficient way. The best of these techniques promise to deliver sub-decimeter accuracy down to the lowest possible orbits.

  13. Deployment of Autonomous GPS Stations in Marie Byrd Land, Antartica

    NASA Technical Reports Server (NTRS)

    Donnellan, A.; Luyendyk, B.; Smith, M.; Dace, G.

    1999-01-01

    During the 1998-1999 Antarctic field season, we installed three autonomous GPS stations in Marie Byrd Land, West Antarctica to measure glacio-isostatic rebound and rates of spreading across the West Antartic Rift System.

  14. A New Indoor Positioning System Architecture Using GPS Signals

    PubMed Central

    Xu, Rui; Chen, Wu; Xu, Ying; Ji, Shengyue

    2015-01-01

    The pseudolite system is a good alternative for indoor positioning systems due to its large coverage area and accurate positioning solution. However, for common Global Positioning System (GPS) receivers, the pseudolite system requires some modifications of the user terminals. To solve the problem, this paper proposes a new pseudolite-based indoor positioning system architecture. The main idea is to receive real-world GPS signals, repeat each satellite signal and transmit those using indoor transmitting antennas. The transmitted GPS-like signal can be processed (signal acquisition and tracking, navigation data decoding) by the general receiver and thus no hardware-level modification on the receiver is required. In addition, all Tx can be synchronized with each other since one single clock is used in Rx/Tx. The proposed system is simulated using a software GPS receiver. The simulation results show the indoor positioning system is able to provide high accurate horizontal positioning in both static and dynamic situations. PMID:25938199

  15. Using cluster analysis to organize and explore regional GPS velocities

    USGS Publications Warehouse

    Simpson, Robert W.; Thatcher, Wayne; Savage, James C.

    2012-01-01

    Cluster analysis offers a simple visual exploratory tool for the initial investigation of regional Global Positioning System (GPS) velocity observations, which are providing increasingly precise mappings of actively deforming continental lithosphere. The deformation fields from dense regional GPS networks can often be concisely described in terms of relatively coherent blocks bounded by active faults, although the choice of blocks, their number and size, can be subjective and is often guided by the distribution of known faults. To illustrate our method, we apply cluster analysis to GPS velocities from the San Francisco Bay Region, California, to search for spatially coherent patterns of deformation, including evidence of block-like behavior. The clustering process identifies four robust groupings of velocities that we identify with four crustal blocks. Although the analysis uses no prior geologic information other than the GPS velocities, the cluster/block boundaries track three major faults, both locked and creeping.

  16. INEGI's Network of GPS permanent stations in Mexico

    NASA Astrophysics Data System (ADS)

    Gonzalez Franco, G. A.

    2013-05-01

    The Active National Geodetic Network administered by INEGI (Instituto Nacional de Estadística y Geografía) is a set of 24 GPS permanent stations in Mexico that was established in 1993 for a national rural cadastral project, its has been mainly used for geodetic surveys through Mexico including international borders, and has been progressing to contribute to national, regional and international reference frames through the delivering of GPS data or coordinate solutions from INEGI Processing Center to SIRGAS and NAREF. Recently GAMIT/GLOBK Processing of permanent stations in Mexico was realized from 2007-2011 to determine station's velocity. Related to natural hazards, a subset of INEGI network contributes to the project Real Time Integrated Atmosferic Water Wapor and TEC from GPS. The GPS network planned evolution consider changing to a GNSS network, adding stations to IGS, maintain the services of the present, and contribute to multidisciplinary geodetic studies through data publicly available.

  17. Analysis of GPS Data Collected on the Greenland Ice Sheet

    NASA Technical Reports Server (NTRS)

    Larson, K.; Plumb, J.; Zwally, J.; Abdalati, W.; Koblinsky, Chester J. (Technical Monitor)

    2001-01-01

    For several years, GPS observations have been made year round at the Swiss Camp, Greenland. The GPS data are recorded for 12 hours every 10-15 days; data are stored in memory and downloaded during the annual field season. Traditional GPS analysis techniques, where the receiver is assumed not to move within a 24 hour period, is not appropriate at the Swiss Camp, where horizontal velocities are on the order of 30 cm/day. Comparison of analysis strategies for these GPS data indicate that a random walk parameterization, with a constraint of 1-2 x 10(exp -7) km/sqrt(sec) minimizes noise due to satellite outages without corrupting the estimated ice velocity. Low elevation angle observations should be included in the analysis in order to increase the number of satellites viewed at each data epoch. Carrier phase ambiguity resolution is important for improving the accuracy of receiver coordinates.

  18. GPS-based satellite tracking system for precise positioning

    NASA Technical Reports Server (NTRS)

    Yunck, T. P.; Melbourne, W. G.; Thornton, C. L.

    1985-01-01

    NASA is developing a Global Positioning System (GPS) based measurement system to provide precise determination of earth satellite orbits, geodetic baselines, ionospheric electron content, and clock offsets between worldwide tracking sites. The system will employ variations on the differential GPS observing technique and will use a network of nine fixed ground terminals. Satellite applications will require either a GPS flight receiver or an on-board GPS beacon. Operation of the system for all but satellite tracking will begin by 1988. The first major satellite application will be a demonstration of decimeter accuracy in determining the altitude of TOPEX in the early 1990's. By then the system is expected to yield long-baseline accuracies of a few centimeters and instantaneous time synchronization to 1 ns.

  19. A Mobile GPS Application: Mosque Tracking with Prayer Time Synchronization

    NASA Astrophysics Data System (ADS)

    Hashim, Rathiah; Ikhmatiar, Mohammad Sibghotulloh; Surip, Miswan; Karmin, Masiri; Herawan, Tutut

    Global Positioning System (GPS) is a popular technology applied in many areas and embedded in many devices, facilitating end-users to navigate effectively to user's intended destination via the best calculated route. The ability of GPS to track precisely according to coordinates of specific locations can be utilized to assist a Muslim traveler visiting or passing an unfamiliar place to find the nearest mosque in order to perform his prayer. However, not many techniques have been proposed for Mosque tracking. This paper presents the development of GPS technology in tracking the nearest mosque using mobile application software embedded with the prayer time's synchronization system on a mobile application. The prototype GPS system developed has been successfully incorporated with a map and several mosque locations.

  20. Using Transponders on the Moon to Increase Accuracy of GPS

    NASA Technical Reports Server (NTRS)

    Penanen, Konstantin; Chui, Talso

    2008-01-01

    It has been proposed to place laser or radio transponders at suitably chosen locations on the Moon to increase the accuracy achievable using the Global Positioning System (GPS) or other satellite-based positioning system. The accuracy of GPS position measurements depends on the accuracy of determination of the ephemerides of the GPS satellites. These ephemerides are determined by means of ranging to and from Earth-based stations and consistency checks among the satellites. Unfortunately, ranging to and from Earth is subject to errors caused by atmospheric effects, notably including unpredictable variations in refraction. The proposal is based on exploitation of the fact that ranging between a GPS satellite and another object outside the atmosphere is not subject to error-inducing atmospheric effects. The Moon is such an object and is a convenient place for a ranging station. The ephemeris of the Moon is well known and, unlike a GPS satellite, the Moon is massive enough that its orbit is not measurably affected by the solar wind and solar radiation. According to the proposal, each GPS satellite would repeatedly send a short laser or radio pulse toward the Moon and the transponder(s) would respond by sending back a pulse and delay information. The GPS satellite could then compute its distance from the known position(s) of the transponder(s) on the Moon. Because the same hemisphere of the Moon faces the Earth continuously, any transponders placed there would remain continuously or nearly continuously accessible to GPS satellites, and so only a relatively small number of transponders would be needed to provide continuous coverage. Assuming that the transponders would depend on solar power, it would be desirable to use at least two transponders, placed at diametrically opposite points on the edges of the Moon disk as seen from Earth, so that all or most of the time, at least one of them would be in sunlight.

  1. GPS and Glonass Combined Static Precise Point Positioning (ppp)

    NASA Astrophysics Data System (ADS)

    Pandey, D.; Dwivedi, R.; Dikshit, O.; Singh, A. K.

    2016-06-01

    With the rapid development of multi-constellation Global Navigation Satellite Systems (GNSSs), satellite navigation is undergoing drastic changes. Presently, more than 70 satellites are already available and nearly 120 more satellites will be available in the coming years after the achievement of complete constellation for all four systems- GPS, GLONASS, Galileo and BeiDou. The significant improvement in terms of satellite visibility, spatial geometry, dilution of precision and accuracy demands the utilization of combining multi-GNSS for Precise Point Positioning (PPP), especially in constrained environments. Currently, PPP is performed based on the processing of only GPS observations. Static and kinematic PPP solutions based on the processing of only GPS observations is limited by the satellite visibility, which is often insufficient for the mountainous and open pit mines areas. One of the easiest options available to enhance the positioning reliability is to integrate GPS and GLONASS observations. This research investigates the efficacy of combining GPS and GLONASS observations for achieving static PPP solution and its sensitivity to different processing methodology. Two static PPP solutions, namely standalone GPS and combined GPS-GLONASS solutions are compared. The datasets are processed using the open source GNSS processing environment gLAB 2.2.7 as well as magicGNSS software package. The results reveal that the addition of GLONASS observations improves the static positioning accuracy in comparison with the standalone GPS point positioning. Further, results show that there is an improvement in the three dimensional positioning accuracy. It is also shown that the addition of GLONASS constellation improves the total number of visible satellites by more than 60% which leads to the improvement of satellite geometry represented by Position Dilution of Precision (PDOP) by more than 30%.

  2. The GPS based precision orbit determination experiment on TOPEX

    NASA Technical Reports Server (NTRS)

    Melbourne, William G.; Davis, Edgar S.; Yunck, Thomas P.

    1988-01-01

    The objectives of the GPS-based precision orbit determination (POD) experiment on TOPEX are discussed. Problems facing this experiment include the careful design of all network receivers to control uncalibrated systematic group-delay biases and delay variations between channels, and the careful design of both the GPS-antenna-TOPEX satellite interface and the ground antennas to mimimize multipath. Questions of reference frames, geoid recovery, and the application of innovative orbit determination strategies must also be addressed.

  3. Software Defined GPS Receiver for International Space Station

    NASA Technical Reports Server (NTRS)

    Duncan, Courtney B.; Robison, David E.; Koelewyn, Cynthia Lee

    2011-01-01

    JPL is providing a software defined radio (SDR) that will fly on the International Space Station (ISS) as part of the CoNNeCT project under NASA's SCaN program. The SDR consists of several modules including a Baseband Processor Module (BPM) and a GPS Module (GPSM). The BPM executes applications (waveforms) consisting of software components for the embedded SPARC processor and logic for two Virtex II Field Programmable Gate Arrays (FPGAs) that operate on data received from the GPSM. GPS waveforms on the SDR are enabled by an L-Band antenna, low noise amplifier (LNA), and the GPSM that performs quadrature downconversion at L1, L2, and L5. The GPS waveform for the JPL SDR will acquire and track L1 C/A, L2C, and L5 GPS signals from a CoNNeCT platform on ISS, providing the best GPS-based positioning of ISS achieved to date, the first use of multiple frequency GPS on ISS, and potentially the first L5 signal tracking from space. The system will also enable various radiometric investigations on ISS such as local multipath or ISS dynamic behavior characterization. In following the software-defined model, this work will create a highly portable GPS software and firmware package that can be adapted to another platform with the necessary processor and FPGA capability. This paper also describes ISS applications for the JPL CoNNeCT SDR GPS waveform, possibilities for future global navigation satellite system (GNSS) tracking development, and the applicability of the waveform components to other space navigation applications.

  4. Multi-Cone Model for Estimating GPS Ionospheric Delays

    NASA Technical Reports Server (NTRS)

    Sparks, Lawrence; Komjathy, Attila; Mannucci, Anthony

    2009-01-01

    The multi-cone model is a computational model for estimating ionospheric delays of Global Positioning System (GPS) signals. It is a direct descendant of the conical-domain model. A primary motivation for the development of this model is the need to find alternatives for modeling slant delays at low latitudes, where ionospheric behavior poses an acute challenge for GPS signal-delay estimates based upon the thin-shell model of the ionosphere.

  5. Advancing the Chemistry of CuWO4 for Photoelectrochemical Water Oxidation.

    PubMed

    Lhermitte, Charles R; Bartlett, Bart M

    2016-06-21

    Photoelectrochemical (PEC) cells are an ongoing area of exploration that provide a means of converting solar energy into a storable chemical form (molecular bonds). In particular, using PEC cells to drive the water splitting reaction to obtain H2 could provide a clean and sustainable route to convert solar energy into chemical fuels. Since the discovery of catalytic water splitting on TiO2 photoelectrodes by Fujishima and Honda, significant efforts have been directed toward developing high efficiency metal oxides to use as photocatalysts for this reaction. Improving the efficiency of PEC cells requires developing chemically stable, and highly catalytic anodes for the oxygen-evolution reaction (OER). This water oxidation half reaction requires four protons and four electrons coupling in two bond making steps to form O2, which limits the rate. Our group has accelerated efforts in CuWO4 as a candidate for PEC OER chemistry. Its small band gap of 2.3 eV allows for using visible light to drive OER, and the reaction proceeds with a high degree of chemoselectivity, even in the presence of more kinetically accessible anions such as chloride, which is common to seawater. Furthermore, CuWO4 is a chemically robust material when subjected to the highly oxidizing conditions of PEC OER. The next steps for accelerating research using this (and other), ternary phase oxides, is to move beyond reporting the basic PEC measurements to understanding fundamental chemical reaction mechanisms operative during OER on semiconductor surfaces. In this Account, we outline the process for PEC OER on CuWO4 thin films with emphasis on the chemistry of this reaction, the reaction rate and selectivity (determined by controlled-potential coulometry and oxygen-detection experiments). We discuss key challenges with CuWO4 such as slow kinetics and the presence of an OER-mediating mid-gap state, probed by electrochemical impedance spectroscopy. We propose that this mid-gap state imparts the observed

  6. Advancing the Chemistry of CuWO4 for Photoelectrochemical Water Oxidation.

    PubMed

    Lhermitte, Charles R; Bartlett, Bart M

    2016-06-21

    Photoelectrochemical (PEC) cells are an ongoing area of exploration that provide a means of converting solar energy into a storable chemical form (molecular bonds). In particular, using PEC cells to drive the water splitting reaction to obtain H2 could provide a clean and sustainable route to convert solar energy into chemical fuels. Since the discovery of catalytic water splitting on TiO2 photoelectrodes by Fujishima and Honda, significant efforts have been directed toward developing high efficiency metal oxides to use as photocatalysts for this reaction. Improving the efficiency of PEC cells requires developing chemically stable, and highly catalytic anodes for the oxygen-evolution reaction (OER). This water oxidation half reaction requires four protons and four electrons coupling in two bond making steps to form O2, which limits the rate. Our group has accelerated efforts in CuWO4 as a candidate for PEC OER chemistry. Its small band gap of 2.3 eV allows for using visible light to drive OER, and the reaction proceeds with a high degree of chemoselectivity, even in the presence of more kinetically accessible anions such as chloride, which is common to seawater. Furthermore, CuWO4 is a chemically robust material when subjected to the highly oxidizing conditions of PEC OER. The next steps for accelerating research using this (and other), ternary phase oxides, is to move beyond reporting the basic PEC measurements to understanding fundamental chemical reaction mechanisms operative during OER on semiconductor surfaces. In this Account, we outline the process for PEC OER on CuWO4 thin films with emphasis on the chemistry of this reaction, the reaction rate and selectivity (determined by controlled-potential coulometry and oxygen-detection experiments). We discuss key challenges with CuWO4 such as slow kinetics and the presence of an OER-mediating mid-gap state, probed by electrochemical impedance spectroscopy. We propose that this mid-gap state imparts the observed

  7. Microwave selective heating for size effect of water droplet in W/O emulsion with sorbitan fatty acid monostearate surfactant

    NASA Astrophysics Data System (ADS)

    Sumi, Takuya; Horikoshi, Satoshi

    2015-09-01

    A stable water/oil (W/O) emulsion was prepared by adjustment with sorbitan fatty acid monoester surfactants. The prepared W/O emulsion was stable for 60 min in the atmosphere; however, the formation of non-uniform water droplets in the height of the emulsion in the quartz tube reactor were observed by the backscattering measurements with an infrared laser at 850 nm. The increase of temperature under microwave irradiation was influenced sensitively by the position of those water droplets. Those results were caused from the size and concentration of water droplets in the W/O emulsion. On the other hand, selective heating of the water droplets caused heating of the entire W/O emulsion, although the temperature difference between the water droplets and the oil phase was 20 °C.

  8. Facile fabrication of corrosion-resistant superhydrophobic and superoleophilic surfaces with MnWO(4):Dy(3+) microbouquets.

    PubMed

    Li, Taohai; Li, Quanguo; Yan, Jing; Li, Feng

    2014-04-21

    Superhydrophobic and superoleophilic MnWO4:Dy(3+) microbouquets were successfully fabricated via a facile hydrothermal process. The surface morphologies and chemical composition were investigated by scanning electron microscopy (SEM) and X-ray powder diffraction (XRD). The wettability of the as-synthesized MnWO4:Dy(3+) microbouquet film was studied by measuring the water contact angle (CA). A static CA for water of 165° and a very low sliding angle (SA) were observed, which were closely related to both the MnWO4:Dy(3+) microbouquet structure and chemical modification. Furthermore, the as-prepared MnWO4:Dy(3+) surface showed superhydrophobicity for some corrosive liquids such as aqueous basic and salt solutions.

  9. THE DISCOVERY OF A RARE WO-TYPE WOLF-RAYET STAR IN THE LARGE MAGELLANIC CLOUD

    SciTech Connect

    Neugent, Kathryn F.; Massey, Philip; Morrell, Nidia E-mail: phil.massey@lowell.edu

    2012-12-01

    While observing OB stars within the most crowded regions of the Large Magellanic Cloud, we happened upon a new Wolf-Rayet (WR) star in Lucke-Hodge 41, the rich OB association that contains S Doradus and numerous other massive stars. At first glance the spectrum resembled that of a WC4 star, but closer examination showed strong O VI {lambda}{lambda}3811, 34 lines, leading us to classify it as a WO4. This is only the second known WO in the LMC, and the first known WO4 (the other being a WO3). This rarity is to be expected due to these stars' short lifespans as they represent the most advanced evolutionary stage in a massive star's lifetime before exploding as supernovae. This discovery shows that while the majority of WRs within the LMC have been discovered, there may be a few WRs left to be found.

  10. Density-Functional Theory Study of the Effects of Atomic Impurity on the Band Edges of Monoclinic WO3

    SciTech Connect

    Huda, M. N.; Yan, Y.; Moon, C. Y.; Wei, S. H.; Al-Jassim, M. M.

    2008-01-01

    The effects of impurities in room-temperature monoclinic WO3 were studied by using the local density approximation to density-functional theory. Our main focus is on nitrogen impurity in WO{sub 3}, where both substitutional and interstitial cases were considered. We have also considered transition-metal atom impurities and some codoping approaches in WO{sub 3}. We find that, in general, band gap reduction was a common result due to the formation of impurity bands in the band gap. Also, the changes of band-edge positions, valence-band maxima and conduction-band minima, were found to depend on the electronic properties of the foreign atom and their concentration. Our results therefore provide guidance for making WO3 a suitable candidate for photoelectrodes for hydrogen generation by water splitting.

  11. Structure of Zr 2(WO 4)(PO 4) 2 from Powder X-Ray Data: Cation Ordering with No Superstructure

    NASA Astrophysics Data System (ADS)

    Evans, J. S. O.; Mary, T. A.; Sleight, A. W.

    1995-11-01

    Department of Chemistry and Center for Advanced Materials Research, Oregon State University, Corvallis, Oregon The ab initio structure determination of Zr2(WO4)(PO4)2 from room temperature powder X-ray diffraction data is reported. This compound crystallizes in the orthorhombic space group Pnca with a = 9.35451(9), b = 12.31831(9), and c = 9.16711(8) Å. The structure is based on ZrO6 octahedra sharing corners with WO4 and PO4 tetrahedra. Although Zr2(WO4)(PO4)2 is isostructural with Fe2(MoO4)3 and its WO4 and PO4 tetrahedra are well ordered, no superstructure or change in space group is required to account for this ordering.

  12. Bi{sub 2}WO{sub 6} photocatalytic films fabricated by layer-by-layer technique from Bi{sub 2}WO{sub 6} nanoplates and its spectral selectivity

    SciTech Connect

    Zhang Shicheng Shen Jiandong; Fu Hongbo; Dong Weiyang; Zheng Zhijian; Shi Liyi

    2007-04-15

    Bi{sub 2}WO{sub 6} multilayer films have been fabricated successfully by a layer-by-layer (LbL) technique from Bi{sub 2}WO{sub 6} nanoplates, which show higher visible-light photoactivity ({lambda}>420 nm) than that of Bi{sub 2}WO{sub 6} nanoplate powders and P25 TiO{sub 2} films. The films were characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), and UV-visible absorption spectroscopy. Photocatalytic activities of the films were evaluated by the rhodamine B (RhB) decomposition under UV and visible-light irradiation. Thickness and photoactivity of the film can be modified easily by changing the deposition cycles. Bi{sub 2}WO{sub 6} films have the spectral selectivity of the photocatalytic degradation of RhB. Under the wavelength greater than 300 nm, the RhB molecules tend to be transformed to rhodamine over Bi{sub 2}WO{sub 6} films selectively. However, in the case of shorter wavelength ({lambda}=254 nm) light irradiation, the RhB molecules can be photodegraded completely. - Graphical abstract: Bi{sub 2}WO{sub 6} multilayer film fabricated by layer-by-layer technique.

  13. Study on luminescent properties of Eu3+ doped Gd2WO6, Gd2W2O9 and Gd2(WO4)3 nanophosphors prepared by co-precipitation.

    PubMed

    Meng, Qingyu; Hua, Ruinian; Chen, Baojiu; Tian, Yue; Lu, Shuchen; Sun, Linan

    2011-01-01

    Eu3+ doped Gd2WO6, Gd2W2O9 and Gd2(WO4)3 nanophosphors with different concentrations have been prepared by co-precipitation. XRD (X-ray diffraction) and SEM (scanning electron microscopy) were used to investigate the structure and morphology. The emission spectra, excitation spectra and fluorescence decay curves were measured, and partial J-O parameters and quantum efficiencies of Eu3+ 5D0 energy level were calculated. Furthermore, concentration quenching curves of Eu3+ in different hosts were drawn. The photoluminescent properties of Eu3+ doped Gd2WO6, Gd2W2O9 and Gd2(WO4)3 nanophosphors have been studied. The results indicate that Eu3+ 5D0-7F2 red luminescence can be effectively excited by 395 nm and 465 nm in Gd2WO6 and Gd2W2O9 hosts, similar to the familiar Gd2(WO4)3:Eu. Especially Gd2W2O9:Eu has strong red emission and high quenching concentration, so it has potential applications for trichromatic white LED as red fluorescent materials. PMID:21446424

  14. GPS scintillations over Vietnam on April 2006

    NASA Astrophysics Data System (ADS)

    Alfonsi, Lucilla; Spogli, Luca; Tong, Jenna R.; de Franceschi, Giorgiana; Romano, Vincenzo; Bourdillon, Alain; Le Huy, Minh; Mitchell, Cathryn N.

    2010-05-01

    In Vietnam, at Hue (16.4°N, 107.6°E) and Hoc Mon (10.9°N, 106.6°E), are located two GPS receivers specially modified for recording, at a sampling rate of 50 Hz, the phase and the amplitude of the L1 signal and the Total Electron Content (TEC) from L1 and L2. In April 2006 both the receivers have observed post-sunset scintillation inhibition when moderate magnetic storms occurred. These measurements together with a 3D plus time imaging of the ionosphere produced by the Multi-Instrument Data Analysis System (MIDAS) have revealed interesting features that will be described in the present paper. In particular, the results confirm the role of the ring current on the generation of the equatorial F layer irregularities of scale size from less than a hundred meters to a few kilometers, highlighting also its important role in inhibiting scintillation during the storm. The characterization of the different conditions of the Interplanetary Magnetic Field (IMF) will be illustrated, as well, to attempt a description of the scintillation effects over a region scarcely investigated in the open literature.

  15. GPS high dynamic receiver tracking demonstration results

    NASA Technical Reports Server (NTRS)

    Hurd, W. J.; Statman, J. I.; Vilnrotter, V. A.

    1985-01-01

    Demonstration results are presented for a high dynamic GPS receiver. The receiver tested is a breadboard unit capable of tracking one simulated satellite signal in pseudorange and range rate. The receiver makes approximate maximum likelihood estimates of pseudorange and range rate each 20 ms, and tracks these observables using a third order filter with a time constant of 0.14 s. Carrier phase is not tracked, which eliminates the typical failure mode of loss of carrier lock associated with PLLs at high dynamics. The receiver tracks with pseudorange lag errors of under 0.06 m when subjected to simulated 50 g turns with 40 g/s peak jerk. Pseudorange errors due to receiver noise alone are approximately 0.6 m rms at a carrier power to noise spectral density ratio of 34 dB-Hz. The tracking threshold SNR is approximately 28 dB-Hz, which provides 12 dB margin relative to the 40 dB-Hz that occurs with minimum specified satellite signal strength, 3.5 dB system noise figure, and 0 dBi antenna gain.

  16. GPS survey of the western Tien Shan

    NASA Technical Reports Server (NTRS)

    Hager, Bradford H.; Molnar, Peter H.; Hamburger, Michael W.; Reilinger, Robert E.

    1995-01-01

    There were two major developments in 1994 in our collaborative GPS experiment in the Tien Shan of the Former Soviet Union (FSU). Both were motivated by our expectation that we will ultimately obtain better science at lower cost if we involve our colleagues in the FSU more deeply in (1) the collection and (2) the analysis of data. As an experimental test of the concept of having our local collaborators carry out the field work semi-autonomously, we sent 6 MIT receivers to the Tien Shan for a period of 3 months. To enable our collaborators to have the capability for data analysis, we provided computers for two data analysis centers and organized a two-week training session. This report emphasizes the rationale for deeper involvement of FSU scientists, describes the training sessions, discusses the data collection, and presents the results. We also discuss future plans. More detailed discussion of background, general scientific objectives, discussions with collaborators, and results for the campaigns in 1992 and 1993 have been given in previous reports.

  17. Characteristics of GPS sources in the Planck survey

    NASA Astrophysics Data System (ADS)

    Volvach, A. E.; Kardashev, N. S.; Larionov, M. G.; Volvach, L. N.

    2016-09-01

    Two series of 22.2 and 36.8-GHz observations of 43 GHz-Peaked Spectrum (GPS) radio sources from the Planck survey have been carried out using the 22-m radio telescope of the Crimean Astrophysical Observatory in 2014-2015, with the aim of studying the variability of these sources. The interval between the two series of observations was about nine months. These data were analyzed together with the Planck data at frequencies from 20 to 143 GHz. The fraction of quasars among GPS sources grows to 90% at millimeter wavelengths, compared to 1.4% at decimeter wavelengths. The growth in the variability indices of Planck GPS sources is not as sharp as that observed at decimeter and centimeter wavelengths, and remains at a level of about 30% at millimeter wavelengths. This supports the view that GPS sources are not strongly variable, compared to other types of Active Galactic Nuclei (AGNs). A mean spectrumfor the GPS radio sources has been obtained, which is shallower at low frequencies and steeper at high frequencies atmillimeter wavelengths than at decimeter and centimeterwavelengths. These properties of the GPS spectra at millimeter wavelengths testify to the compactness of these sources and the dense, inhomogeneous nature of the medium in which they are located. This also indirectly suggests that these objects are young and that their active states have short lifetimes.

  18. Understanding why GPs see pharmaceutical representatives: a qualitative interview study.

    PubMed Central

    Prosser, Helen; Walley, Tom

    2003-01-01

    BACKGROUND: Doctors are aware of the commercial bias in pharmaceutical representative information; nevertheless, such information is known to change doctors' prescribing, and augment irrational prescribing and prescribing costs. AIM: To explore GPs, reasons for receiving visits from pharmaceutical representatives. DESIGN OF STUDY: Qualitative study with semi-structured interviews. SETTING: One hundred and seven general practitioners (GPs) in practices from two health authorities in the North West of England. RESULTS: The main outcome measures of the study were: reasons for receiving/not receiving representative visits; advantages/disadvantages in receiving visits; and quality of representative-supplied information. Most GPs routinely see pharmaceutical representatives, because they bring new drug information speedily; they are convenient and accessible; and can be consulted with a saving of time and effort. Many GPs asserted they had the skills to critically appraise the evidence. Furthermore, the credibility and social characteristics of the representative were instrumental in shaping GPs' perceptions of representatives as legitimate information providers. GPs also received visits from representatives for reasons other than information acquisition. These reasons are congruent with personal selling techniques used in marketing communications. CONCLUSIONS: The study draws attention to the social and cultural contexts of GP-representative encounters and the way in which the acquisition of pharmacological information within the mercantile context of representative visits is legitimated. This highlights the need for doctors to critically appraise information supplied by representatives in relation to other information sources. PMID:12879831

  19. Application of GPS for transportation related engineering surveys

    NASA Astrophysics Data System (ADS)

    Merrell, Roger L.

    1986-09-01

    The Texas State Department of Highways and Public Transportation (SDHPT) has been using GPS for over two years to establish primary geodetic reference points for engineering projects and mapping control. In accordance with a Five Year GPS Implementation Plant developed in 1982, four GPS, unmanned, automatic Regional Reference Point (RRP) stations will be installed by September 1, 1986. Five additional stations are planned as justified. Each RRP will consist of a dual frequency GPS receiver that will ultimately track the satellites continuously. Operation of the receiver, telecommunications and other station keeping chores will be handled by a microcomputer. The RRP station network will be controlled through another centrally located microcomputer which is also interfaced with a larger mainframe system. Each RRP is designed to service an area bounded by a 200 KM radius and will act as the “other” receiver for roving field units operating in a GPS differential measurement mode. In order to meet the installation schedule, early decisions are being made concerning satellite tracking rates, operational scenarios, and telecommunications to facilitate development of the basic hardware and software systems. A period of continual enhancement to hardware, software and RRP operational procedures is expected as GPS technology expands.

  20. GPS Estimates of Integrated Precipitable Water Aid Weather Forecasters

    NASA Technical Reports Server (NTRS)

    Moore, Angelyn W.; Gutman, Seth I.; Holub, Kirk; Bock, Yehuda; Danielson, David; Laber, Jayme; Small, Ivory

    2013-01-01

    Global Positioning System (GPS) meteorology provides enhanced density, low-latency (30-min resolution), integrated precipitable water (IPW) estimates to NOAA NWS (National Oceanic and Atmospheric Adminis tration Nat ional Weather Service) Weather Forecast Offices (WFOs) to provide improved model and satellite data verification capability and more accurate forecasts of extreme weather such as flooding. An early activity of this project was to increase the number of stations contributing to the NOAA Earth System Research Laboratory (ESRL) GPS meteorology observing network in Southern California by about 27 stations. Following this, the Los Angeles/Oxnard and San Diego WFOs began using the enhanced GPS-based IPW measurements provided by ESRL in the 2012 and 2013 monsoon seasons. Forecasters found GPS IPW to be an effective tool in evaluating model performance, and in monitoring monsoon development between weather model runs for improved flood forecasting. GPS stations are multi-purpose, and routine processing for position solutions also yields estimates of tropospheric zenith delays, which can be converted into mm-accuracy PWV (precipitable water vapor) using in situ pressure and temperature measurements, the basis for GPS meteorology. NOAA ESRL has implemented this concept with a nationwide distribution of more than 300 "GPSMet" stations providing IPW estimates at sub-hourly resolution currently used in operational weather models in the U.S.

  1. System and method for generating attitude determinations using GPS

    NASA Technical Reports Server (NTRS)

    Cohen, Clark E. (Inventor)

    1996-01-01

    A GPS attitude receiver for determining the attitude of a moving vehicle in conjunction with a first, a second, a third, and a fourth antenna mounted to the moving vehicle. Each of the antennas receives a plurality of GPS signals that each include a carrier component. For each of the carrier components of the received GPS signals there is an integer ambiguity associated with the first and fourth antennas, an integer ambiguity associated with second and fourth antennas, and an integer ambiguity associated with the third and fourth antennas. The GPS attitude receiver measures phase values for the carrier components of the GPS signals received from each of the antennas at a plurality of measurement epochs during an initialization period and at a measurement epoch after the initialization period. In response to the phase values measured at the measurement epochs during the initialization period, the GPS attitude receiver computes integer ambiguity resolution values representing resolution of the integer ambiguities. Then, in response to the computed integer ambiguity resolution values and the phase value measured at the measurement epoch after the initialization period, it computes values defining the attitude of the moving vehicle at the measurement epoch after the initialization period.

  2. Permanent GPS Station Sulp: Problems and Preliminary Results

    NASA Astrophysics Data System (ADS)

    Abrikosov, O.; Zablotskyj, F.; Savchuk, S.

    The permanent GPS station SULP is operating starting from September 2001. GPS observations are carrying out by means of the receiver Trimble 4700 and the antenna Zephyr mounted at the fundamental monument of the Astronomical Observatory of the National University "Lviv Polytechnic". Starting from October 2001, daily and hourly observation files are hosted by OLG Data Center. Analysis of these data is performing by WUT and GOP Analysis Centers. Station SULP was included into episodic GPS campaigns GEODUC (1995) and CEGRN (1994 - 1999, 2001). There- fore, besides the traditional task of providing the permanent high-precision GPS ob- servations for supporting the European networks EUREF and CEGRN, it is planned to use SULP station for the following problems. (1) Investigation of recent movements of the Earth's surface in Carpathian area, particularly in the frames of CERGOP project. (2) Studying of local peculiarities of the atmosphere and constructing of correspond- ing mathematical models. (3) Providing of coordinate data for geodetic activities in the Western Ukraine. GPS data analysis for the mentioned problems is performing by means of GAMIT software. The permanent stations, which surround the Carpathian mountain area, are included into the analysis together with 4 active Ukrainian perma- nent GPS stations. First results show the possibility of the geodetic monitoring based on the permanent station SULP.

  3. The collection of GPS signal scattered off a wind-driven ocean with a down-looking GPS receiver: polarization properties versus wind speed and direction

    NASA Technical Reports Server (NTRS)

    Zuffada, C.; Fung, A.; Okolicany, M.; Huang, E.; Parker, J.

    2001-01-01

    A GPS transmitter-receiver pair form a bistatic radar for ocean remote sensing when the receiving platform carries a downlooking antenna capable of collecting the GPS signal scattered off the ocean surface.

  4. Synthesis of WO{sub 3} nanoparticles by citric acid-assisted precipitation and evaluation of their photocatalytic properties

    SciTech Connect

    Sánchez-Martínez, D.; Martínez-de la Cruz, A.; López-Cuéllar, E.

    2013-02-15

    Graphical abstract: Display Omitted Highlights: ► WO{sub 3} nanoparticles were synthesized by a simple citric acid-assisted precipitation. ► WO{sub 3} photocatalyst was able to the partial mineralization of rhB, IC and MO. ► WO{sub 3} can be considered as a photocatalyst active under visible light irradiation. -- Abstract: WO{sub 3} nanoparticles were synthesized by citric acid-assisted precipitation method using a 1:1.5 molar ratio of ammonium paratungstate hydrate (H{sub 42}N{sub 10}O{sub 42}W{sub 12}·xH{sub 2}O):citric acid (C{sub 6}H{sub 8}O{sub 7}). The formation of monoclinic crystal structure of WO{sub 3} at different temperatures was confirmed by X-ray powder diffraction (XRD). The characterization of the samples synthesized was complemented by transmission electron microscopy (TEM), Brunauer–Emmitt–Teller surface area (BET) and diffuse reflectance spectroscopy (DRS). According to the thermal treatment followed during the synthesis of WO{sub 3}, the morphology of the nanoparticles formed was characterized by rectangular and ovoid shapes. The photocatalytic activity of WO{sub 3} obtained under different experimental conditions was evaluated in the degradation of rhodamine B (rhB), indigo carmine (IC), methyl orange (MO), and Congo red (CR) in aqueous solution under UV and UV–vis radiation. The highest photocatalytic activity was observed in the sample obtained by thermal treatment at 700 °C. In general, the sequence of degradation of the organic dyes was: indigo carmine (IC) > rhodamine B (rhB) > methyl orange (MO) > Congo red (CR). The mineralization degree of organic dyes by WO{sub 3} photocatalysts was determined by total organic carbon analysis (TOC) reaching percentages of mineralization of 82% (rhB), 85% (IC), 28% (MO), and 7% (CR) for 96 h of lamp irradiation.

  5. Studies on RF sputtered (WO3)1-x (V2O5)x thin films for smart window applications

    NASA Astrophysics Data System (ADS)

    Meenakshi, M.; Sivakumar, R.; Perumal, P.; Sanjeeviraja, C.

    2016-05-01

    V2O5 doped WO3 targets for RF sputtering thin film deposition were prepared for various compositions. Thin films of (WO3)1-x (V2O5)x were deposited on to glass substrates using these targets. Structural characteristics of the prepared targets and thin films were studied using X-ray diffraction. Laser Raman studies were carried out on the thin films to confirm the compound formation.

  6. Magma flux at Okmok Volcano, Alaska, from a joint inversion of continuous GPS, campaign GPS, and interferometric synthetic aperture radar

    NASA Astrophysics Data System (ADS)

    Biggs, Juliet; Lu, Zhong; Fournier, Tom; Freymueller, Jeffrey T.

    2010-12-01

    Volcano deformation is usually measured using satellite geodetic techniques including interferometric synthetic aperture radar (InSAR), campaign GPS, and continuous GPS. Differences in the spatial and temporal sampling of each system mean that most appropriate inversion scheme to determine the source parameters from each data set is different. Most studies either compare results from independent inversions or subsample the data sets to the lowest common factor. It is unclear whether differences in the solution reflect differences in source behavior, differences in measurement bias, or differences in inversion technique. Here we develop a single inversion procedure that captures the benefits of each system, especially the daily sampling of continuous GPS and the high spatial resolution of InSAR. Okmok Volcano, Alaska, is an ideal target for such a test because a long series (<15 years) of InSAR and continuous GPS measurement exists and the source is almost continuously active and in a stable location.

  7. GPS Array as a Sensor of Lithosphere, Troposphere and Ionosphere

    NASA Astrophysics Data System (ADS)

    Heki, K.

    2011-12-01

    The Japanese dense array of GPS receivers (GEONET) started operation in 1993, and is currently composed of ~1200 stations. GPS (or GNSS in general) receivers can be compared to a Swiss army knife: it could be used not only for positioning (a knife) but also for various purposes, e.g. remote sensing of tropospheric water vapor or ionospheric electrons (screw driver, tin opener etc). Dense GPS arrays have been found extremely useful for variety of geophysical studies. In this lecture, I briefly review their historical achievements, recent highlights, and future perspectives. In Japan, first generation GPS stations were implemented in 1993 (the Kanto-Tokai region) and 1994 (nationwide) by GSI, Japan. Shortly after the launch, they successfully caught coseismic crustal movement of several major earthquakes, the 1994 October Shikotan (Mw8.3), the 1994 December Sanriku (Mw7.6), and the 1995 January Kobe (Mw7.0) earthquakes. These earthquakes accelerated the densification of the GPS network, achieving 1000 in the number of stations within the following 2-3 years. In addition to coseismic jumps, important discoveries continued in 1990s, e.g. large-scale afterslip of interplate thrust earthquakes and slow slip events (SSE). Later it was shown that tilt- and strainmeter can better observe short-term SSEs, and InSAR can draw more detailed maps of coseismic crustal movements. Now GPS array is recognized as a good tool to measure crustal movement with high temporal resolution and stability and with moderate sensitivity and spatial resolution. GPS data are also useful to study hydrosphere. Seasonal crustal movements in Japan mainly reflect changes in hydrological loads. Multipath signatures in GPS data also provide useful information on the environment around the antenna, e.g. soil moisture, snow depth and vegetation. I will compare the snow depth record over a winter inferred by analyzing GPS multipath signatures, and observed by a conventional apparatus. GPS can also measure

  8. Preparation of hexagonal WO{sub 3} from hexagonal ammonium tungsten bronze for sensing NH{sub 3}

    SciTech Connect

    Szilagyi, Imre Miklos Wang Lisheng; Gouma, Pelagia-Irene; Balazsi, Csaba; Madarasz, Janos; Pokol, Gyoergy

    2009-03-05

    Hexagonal tungsten oxide (h-WO{sub 3}) was prepared by annealing hexagonal ammonium tungsten bronze, (NH{sub 4}){sub 0.07}(NH{sub 3}){sub 0.04}(H{sub 2}O){sub 0.09}WO{sub 2.95}. The structure, composition and morphology of h-WO{sub 3} were studied by XRD, XPS, Raman, {sup 1}H MAS (magic angle spinning) NMR, scanning electron microscopy (SEM), and BET-N{sub 2} specific surface area measurement, while its thermal stability was investigated by in situ XRD. The h-WO{sub 3} sample was built up by 50-100 nm particles, had an average specific surface area of 8.3 m{sup 2}/g and was thermally stable up to 450 deg. C. Gas sensing tests showed that h-WO{sub 3} was sensitive to various levels (10-50 ppm) of NH{sub 3}, with the shortest response and recovery times (1.3 and 3.8 min, respectively) to 50 ppm NH{sub 3}. To this NH{sub 3} concentration, the sensor had significantly higher sensitivity than h-WO{sub 3} samples prepared by wet chemical methods.

  9. A facile synthesis of ZnWO{sub 4} nanoparticles by microwave assisted technique and its application in photocatalysis

    SciTech Connect

    Garadkar, K.M.; Ghule, L.A.; Sapnar, K.B.; Dhole, S.D.

    2013-03-15

    Highlights: ► Nanocrystalline ZnWO{sub 4} particles were successfully prepared by a microwave method. ► Spherical morphology with a 10 nm size. ► The band is 3.4 eV. ► The photodegradation of RhB was 95% within 25 min. - Abstract: A simple microwave assisted technique has been successfully developed to synthesize ZnWO{sub 4} nanoparticles. The X-ray diffraction results indicated that the synthesized nanoparticles exhibited only wolframite structure. Structural, morphological and optical properties of ZnWO{sub 4} nanoparticles have been analyzed by XRD, SEM, TEM EDAX, UV–vis and FT-IR spectral measurements. The transmission electron microscopy (TEM) image revealed that particle size of ZnWO{sub 4} nanoparticles was found to be 10 nm, the band-gap of ZnWO{sub 4} nanoparticles was found to be 3.4 eV. The photocatalytic activities for aqueous Rhodamine B and Methylene Blue samples were investigated and observed that ZnWO{sub 4} nanoparticles exhibited highly enhanced photocatalytic activity towards RhB than MB.

  10. Immobilization of WO{sub 3} or MoO{sub 3} on macroscopic silica fiber via CNFs template

    SciTech Connect

    Wu, Qiang Zhao, Li; Han, Ruobing

    2013-08-01

    Graphical abstract: Uniform immobilization of tungsten trioxide (WO{sub 3}) or molybdenum trioxide (MoO{sub 3}) on silica fiber was successfully achieved by using carbon nanofibers (CNFs) as template. FE-SEM coupled with XRD analysis confirmed the template effect and the existence of WO{sub 3} or MoO{sub 3} immobilized on silica fiber. It is expected that such materials with direct macroscopic shapes would hold promise as highly functionalized materials for potential practical applications, especially in photocatalysis. - Highlights: • WO{sub 3} or MoO{sub 3} with macroscopic shapes were successfully obtained. • WO{sub 3} and MoO{sub 3} immobilization depended on CNFs templates. • FE-SEM and XRD confirmed the structure and phase composition. - Abstract: Uniform immobilization of tungsten trioxide (WO{sub 3}) or molybdenum trioxide (MoO{sub 3}) on silica fiber was successfully achieved by using carbon nanofibers (CNFs) as template. Field emission scanning electron microscopy (FE-SEM), coupled with X-ray diffraction (XRD) analysis confirmed the template effect and the existence of WO{sub 3} or MoO{sub 3} immobilized on silica fiber. It is expected that such materials with direct macroscopic shapes would hold promise as highly functionalized materials for potential practical applications, especially in photocatalysis.

  11. Impact of Swarm GPS receiver updates on POD performance

    NASA Astrophysics Data System (ADS)

    van den IJssel, Jose; Forte, Biagio; Montenbruck, Oliver

    2016-05-01

    The Swarm satellites are equipped with state-of-the-art Global Positioning System (GPS) receivers, which are used for the precise geolocation of the magnetic and electric field instruments, as well as for the determination of the Earth's gravity field, the total electron content and low-frequency thermospheric neutral densities. The onboard GPS receivers deliver high-quality data with an almost continuous data rate. However, the receivers show a slightly degraded performance when flying over the geomagnetic poles and the geomagnetic equator, due to ionospheric scintillation. Furthermore, with only eight channels available for dual-frequency tracking, the amount of collected GPS tracking data is relatively low compared with various other missions. Therefore, several modifications have been implemented to the Swarm GPS receivers. To optimise the amount of collected GPS data, the GPS antenna elevation mask has slowly been reduced from 10° to 2°. To improve the robustness against ionospheric scintillation, the bandwidths of the GPS receiver tracking loops have been widened. Because these modifications were first implemented on Swarm-C, their impact can be assessed by a comparison with the close flying Swarm-A satellite. This shows that both modifications have a positive impact on the GPS receiver performance. The reduced elevation mask increases the amount of GPS tracking data by more than 3 %, while the updated tracking loops lead to around 1.3 % more observations and a significant reduction in tracking losses due to severe equatorial scintillation. The additional observations at low elevation angles increase the average noise of the carrier phase observations, but nonetheless slightly improve the resulting reduced-dynamic and kinematic orbit accuracy as shown by independent satellite laser ranging (SLR) validation. The more robust tracking loops significantly reduce the large carrier phase observation errors at the geomagnetic poles and along the geomagnetic

  12. Radiotracking large wilderness mammals: Integration of GPS and Argos technology

    USGS Publications Warehouse

    Schwartz, Charles C.; Arthur, Steve M.

    1999-01-01

    We tested 30 prototype global positioning system (GPS) radiocollars on brown bears (Ursus arctos) over a 3-year period on the Kenai Peninsula, Alaska. Collars were of 2 design types: GPS with an Argos (Argos Data collection and Location System) satellite uplink (n=19) and GPS unites where the data were stored on board (n=10) for retrieval at a later date. All units also contained a conventional VHF (very high frequency) transmitter and weighed 1.7 kg. GPS-Argos united obtained 10-82% of expected GPS fixes, and fix rate declined significantly (P<0.05) with time after deployment. Argos uplink success (proportion of successful transmissions of stored data) was linearly related to GPS fix rate (r=0.91, P<0.001). Store-on-board units obtained significantly more successful fixes when compared with the GPS-Argos units (t=-4.009, P<0.001). Fix success rate for deployed store-on-board collars ranged from 13-96%; because of the increased number of attempted fixes per day, these collars obtained fixes on 97% of days deployed. Accuracy of the GPS units was less than predicted by the NAVSTAR GPS technology using the course acquisition code. Reduced accuracy was likely a result of the proportion of 2-dimensional versus 3-dimensional fixes obtained, although we could not determine this statistic from recorded data. Increased overstory closure was the only variable measured that partially explained the reduced likelihood of a successful fix. Stem density, stem diameter, and overstory height measured within 3 m of the collar did not affect fix success. GPS fix success rates for collars attached to bears varied more and were lower than fix rates for stationary collars placed in various vegetation types, suggesting that the bear, terrain, and movement all influence both fix and uplink success rate. Application of this new technology to grizzly and brown bear research and comparisons to studies with moose (Alces alces) are discussed.

  13. GPS World, Innovation: Autonomous Navigation at High Earth Orbits

    NASA Technical Reports Server (NTRS)

    Bamford, William; Winternitz, Luke; Hay, Curtis

    2005-01-01

    Calculating a spacecraft's precise location at high orbital altitudes-22,000 miles (35,800 km) and beyond-is an important and challenging problem. New and exciting opportunities become possible if satellites are able to autonomously determine their own orbits. First, the repetitive task of periodically collecting range measurements from terrestrial antennas to high altitude spacecraft becomes less important-this lessens competition for control facilities and saves money by reducing operational costs. Also, autonomous navigation at high orbital altitudes introduces the possibility of autonomous station keeping. For example, if a geostationary satellite begins to drift outside of its designated slot it can make orbit adjustments without requiring commands from the ground. Finally, precise onboard orbit determination opens the door to satellites flying in formation-an emerging concept for many scientific space applications. The realization of these benefits is not a trivial task. While the navigation signals broadcast by GPS satellites are well suited for orbit and attitude determination at lower altitudes, acquiring and using these signals at geostationary (GEO) and highly elliptical orbits is much more difficult. The light blue trace describes the GPS orbit at approximately 12,550 miles (20,200 km) altitude. GPS satellites were designed to provide navigation signals to terrestrial users-consequently the antenna array points directly toward the earth. GEO and HE0 orbits, however, are well above the operational GPS constellation, making signal reception at these altitudes more challenging. The nominal beamwidth of a Block II/IIA GPS satellite antenna array is approximately 42.6 degrees. At GEO and HE0 altitudes, most of these primary beam transmissions are blocked by the Earth, leaving only a narrow region of nominal signal visibility near opposing limbs of the earth. This region is highlighted in gray. If GPS receivers at GEO and HE0 orbits were designed to use these

  14. Optimization of GPS Interferometric Reflectometry for Remote Sensing

    NASA Astrophysics Data System (ADS)

    Chen, Qiang

    GPS Interferometric Reflectometry (GPS-IR), a passive microwave remote sensing technique utilizing GPS signal as a source of opportunity, characterizes the Earth's surface through a bistatic radar configuration. The key idea of GPS-IR is utilizing a ground-based antenna to coherently receive the direct, or line-of-sight (LOS), signal and the Earth's surface reflected signal simultaneously. The direct and reflected signals create an interference pattern of the Signal-to-Noise Ratio (SNR), which contains the information about the Earth's surface environment. GPS-IR has proven its utility in a variety of environmental remote sensing applications, including the measurements of near-surface soil moisture, coastal sea level, snow depth and snow water equivalent, and vegetation biophysical parameters. A major approach of the GPS-IR technique is using the SNR data provided by the global network of the geodetic GPS stations deployed for tectonic and surveying applications. The geodetic GPS networks provide wide spatial coverage and have no additional cost for this capability expansion. However, the geodetic GPS instruments have intrinsic limitations: the geodetic-quality GPS antennas are designed to suppress the reflected signals, which is counter to the requirement of GPS-IR. As a result, it is desirable to refine and optimize the instrument and realize the full potential of the GPS-IR technique. This dissertation first analyzes the signal characteristics of four available polarizations of the GPS signal, and then discusses how these characteristics are related to and can be used for remote sensing applications of GPS-IR. Two types of antennas, a half-wavelength dipole antenna and a patch antenna, are proposed and fabricated to utilize the desired polarizations. Four field experiments are conducted to assess the feasibility of the design criteria and the performance of the proposed antennas. Three experiments are focused on snow depth measurement. The Table Mountain

  15. A hierarchically porous anatase TiO2 coated-WO3 2D IO bilayer film and its photochromic properties.

    PubMed

    Li, Hua; Wu, Huazhong; Xiao, Jiajia; Su, Yanli; Robichaud, Jacques; Brüning, Ralf; Djaoued, Yahia

    2016-01-18

    A hierarchically porous anatase TiO2 coated-WO3 2D inverse opal (IO) bilayer film was fabricated on ITO glass using a layer by layer route with a hierarchically porous TiO2 top layer and an ordered super-macroporous WO3 2D IO bottom layer. This novel TiO2 coated-WO3 2D IO bilayer film was evaluated for photochromic applications. PMID:26576930

  16. A hierarchically porous anatase TiO2 coated-WO3 2D IO bilayer film and its photochromic properties.

    PubMed

    Li, Hua; Wu, Huazhong; Xiao, Jiajia; Su, Yanli; Robichaud, Jacques; Brüning, Ralf; Djaoued, Yahia

    2016-01-18

    A hierarchically porous anatase TiO2 coated-WO3 2D inverse opal (IO) bilayer film was fabricated on ITO glass using a layer by layer route with a hierarchically porous TiO2 top layer and an ordered super-macroporous WO3 2D IO bottom layer. This novel TiO2 coated-WO3 2D IO bilayer film was evaluated for photochromic applications.

  17. Sub-nanosecond Yb:KLu(WO4)2 microchip laser.

    PubMed

    Loiko, P; Serres, J M; Mateos, X; Yumashev, K; Yasukevich, A; Petrov, V; Griebner, U; Aguiló, M; Díaz, F

    2016-06-01

    A diode-pumped Yb:KLu(WO4)2 microchip laser passively Q-switched by a Cr4+:YAG saturable absorber generated a maximum average output power of 590 mW at 1031 nm with a slope efficiency of 55%. The pulse characteristics were 690 ps/47.6 μJ at a pulse repetition frequency of 12.4 kHz. The output beam had an excellent circular profile with M2<1.05. Yb:KLu(WO4)2 is very promising for ultrathin sub-ns microchip lasers. PMID:27244429

  18. Phase modification and surface plasmon resonance of Au/WO3 system

    NASA Astrophysics Data System (ADS)

    Bose, R. Jolly; Kavitha, V. S.; Sudarsanakumar, C.; Pillai, V. P. Mahadevan

    2016-08-01

    We report the action of gold as catalyst for the modification of phase from triclinic WO3 to monoclinic W18O49 and nucleation centre for the formation of W18O49 phase, in gold incorporated tungsten oxide films prepared by RF magnetron sputtering technique. A new band is observed near 925 cm-1 in the Raman spectra of gold incorporated tungsten oxide films which is not observed in the pure tungsten oxide film. The intensity of this band enhances with gold content. A localized surface plasmon resonance (LSPR) band is observed near the wavelength 604 nm in gold incorporated tungsten oxide films. The integrated intensities of LSPR band and Raman band (∼925 cm-1) can be used for sensing the quantity of gold in the Au/WO3 matrix.

  19. Electric field control of ferroelectric domain structures in MnWO4.

    PubMed

    Yu, H W; Li, X; Liu, M F; Lin, L; Yan, Z B; Zhou, X H; Liu, J M

    2014-07-30

    Competing interactions make the magnetic structure of MnWO4 highly frustrated, and only the AF2 phase of the three magnetically ordered phases (AF1, AF2, AF3) is ferroelectric. The high frustration may thus allow a possibility to tune the magnetic structure by means of an electric field via magnetoelectric coupling. By using the pyroelectric current method, we measure the remnant ferroelectric polarization in MnWO4 upon application of a poling electric field via two different roadmaps. It is demonstrated that an electric field as low as 10 kV cm(-1) is sufficient to enhance the stability of a ferroelectric AF2 phase at the expense of a non-ferroelectric AF1 phase. This work suggests that electric field induced electrostatic energy, although small due to weak magnetically induced electric polarization, may effectively tune ferroelectric domain structures, and thus the magnetic structure of highly frustrated multiferroic materials.

  20. G0W0 band structure of CdWO4.

    PubMed

    Laasner, Raul

    2014-03-26

    The full quasiparticle band structure of CdWO4 is calculated within the single-shot GW (G0W0) approximation using maximally localized Wannier functions, which allows one to assess the validity of the commonly used scissor operator. Calculations are performed using the Godby-Needs plasmon pole model and the accurate contour deformation technique. It is shown that while the two methods yield identical band gap energies, the low-lying states are given inaccurately by the plasmon pole model. We report a band gap energy of 4.94 eV, including spin-orbit interaction at the DFT-LDA (density functional theory-local density approximation) level. Quasiparticle renormalization in CdWO4 is shown to be correlated with localization distance. Electron and hole effective masses are calculated at the DFT and G0W0 levels. PMID:24599225