Development of lightweight graphite/polyimide sandwich panels.

NASA Technical Reports Server (NTRS)

Poesch, J. G.

1972-01-01

Lightweight graphite/polyimide composite honeycomb core and sandwich panels were fabricated and tested. Honeycomb cores of 1/4-in. and 3/8-in. cell sizes of hexagonal configuration were produced from thin plus or minus 45 deg cross plied sheets of prepreg producing core weights between 1.8 and 3.6 lb/cu ft. Thin gauge prepreg using Hercules graphite tow and Monsanto Skybond 710 polyimide resin were manufactured to produce cured ply thicknesses of 0.001 to 0.002 in. Graphite core properties measured at temperatures from -150 to 600 F are reported. Core properties which are superior to available materials were obtained. Sandwich panels weighing less than 0.5 lb/sq ft were designed and fabricated which meet the support structure loads for the shuttle orbiter thermal protection system.

Development of graphite/polyimide honeycomb core materials

NASA Technical Reports Server (NTRS)

Stone, R. H.

1978-01-01

Honeycomb panel constructions consisting entirely of graphite/polyimide composites were developed and evaluated. Graphite/polyimide composites, were used in the honeycomb core webs and in pre-cured sandwich skins. Polyimide adhesives were also developed and evaluated for use in skin-core bonding. The purpose of this program was to develop light weight sandwich constructions for high temperature applications which could provide comparable shear strength and stiffness to metallic honeycomb constructions.

Fabrication and photoluminescence properties of graphite fiber/ZnO nanorod core-shell structures.

PubMed

Liu, Xianbin; Du, Hejun; Liu, Bo; Wang, Jianxiong; Sun, Xiao Wei; Sun, Handong

2011-08-01

Graphite fiber/ZnO nanorod core-shell structures were synthesized by thermal evaporation process. The core-shell hybrid architectures were comprised of ZnO nanorods grown on the surface of graphite fiber. In addition, Hollow ZnO hierarchical structure can be obtained by oxidizing the graphite fiber. Room temperature photoluminescence (PL) of the as-made graphite fiber/ZnO nanorod structures shows two UV peaks at around 3.274 eV and 3.181 eV. The temperature-dependent photoluminescence spectra demonstrate the two UV emissions are attributed to the intrinsic optical transitions and extrinsic defect-related emissions in ZnO. These hybrid structures may be used as the building block for fabrication of nanodevices.

Method and apparatus for producing a carbon based foam article having a desired thermal-conductivity gradient

DOEpatents

Klett, James W [Knoxville, TN; Cameron, Christopher Stan [Sanford, NC

2010-03-02

A carbon based foam article is made by heating the surface of a carbon foam block to a temperature above its graphitizing temperature, which is the temperature sufficient to graphitize the carbon foam. In one embodiment, the surface is heated with infrared pulses until heat is transferred from the surface into the core of the foam article such that the graphitizing temperature penetrates into the core to a desired depth below the surface. The graphitizing temperature is maintained for a time sufficient to substantially entirely graphitize the portion of the foam article from the surface to the desired depth below the surface. Thus, the foam article is an integral monolithic material that has a desired conductivity gradient with a relatively high thermal conductivity in the portion of the core that was graphitized and a relatively low thermal conductivity in the remaining portion of the foam article.

Systems and methods for dismantling a nuclear reactor

DOEpatents

Heim, Robert R; Adams, Scott Ryan; Cole, Matthew Denver; Kirby, William E; Linnebur, Paul Damon

2014-10-28

Systems and methods for dismantling a nuclear reactor are described. In one aspect the system includes a remotely controlled heavy manipulator ("manipulator") operatively coupled to a support structure, and a control station in a non-contaminated portion of a workspace. The support structure provides the manipulator with top down access into a bioshield of a nuclear reactor. At least one computing device in the control station provides remote control to perform operations including: (a) dismantling, using the manipulator, a graphite moderator, concrete walls, and a ceiling of the bioshield, the manipulator being provided with automated access to all internal portions of the bioshield; (b) loading, using the manipulator, contaminated graphite blocks from the graphite core and other components from the bioshield into one or more waste containers; and (c) dispersing, using the manipulator, dust suppression and contamination fixing spray to contaminated matter.

Controllable Synthesis of Ordered Mesoporous Mo2C@Graphitic Carbon Core-Shell Nanowire Arrays for Efficient Electrocatalytic Hydrogen Evolution.

PubMed

Zhu, Jiahui; Yao, Yan; Chen, Zhi; Zhang, Aijian; Zhou, Mengyuan; Guo, Jun; Wu, Winston Duo; Chen, Xiao Dong; Li, Yanguang; Wu, Zhangxiong

2018-06-06

Mo 2 C is a possible substitute to Pt-group metals for electrocatalytic hydrogen evolution reaction (HER). Both support-free and carbon-supported Mo 2 C nanomaterials with improved HER performance have been developed. Herein, distinct from prior research, novel ordered mesoporous core-shell nanowires with Mo 2 C cores and ultrathin graphitic carbon (GC) shells are rationally synthesized and demonstrated to be excellent for HER. The synthesis is fulfilled via a hard-templating approach combining in situ carburization and localized carbon deposition. Phosphomolybdic acid confined in the SBA-15 template is first converted to MoO 2 , which is then in situ carburized to Mo 2 C nanowires with abundant surface defects. Simultaneously, GC layer (the thickness is down to ∼1.0 nm in most areas) is controlled to be locally deposited on the Mo 2 C surface because of its strong affinity with carbon and catalytic effect on graphitization. Removal of the template results in the Mo 2 C@GC core-shell nanowire arrays with the structural properties well-characterized. They exhibit excellent performance for HER with a low overpotential of 125 mV at 10 mA cm -2 , a small Tafel slope of 66 mV dec -1 , and an excellent stability in acidic electrolytes. The influences of several factors, especially the spatial configuration and relative contents of the GC and Mo 2 C components, on HER performance are elucidated with control experiments. The excellent HER performance of the mesoporous Mo 2 C@GC core-shell nanowire arrays originates from the rough Mo 2 C nanowires with diverse active sites and short charge-transfer paths and the ultrathin GC shells with improved surface area, electronic conductivity, and stabilizing effect on Mo 2 C.

Status of Initial Assessment of Physical and Mechanical Properties of Graphite Grades for NGNP Appkications

DOE Office of Scientific and Technical Information (OSTI.GOV)

Strizak, Joe P; Burchell, Timothy D; Windes, Will

2011-12-01

Current candidate graphite grades for the core structures of NGNP include grades NBG-17, NBG-18, PCEA and IG-430. Both NBG-17 and NBG-18 are manufactured using pitch coke, and are vibrationally molded. These medium grain products are produced by SGL Carbon SAS (France). Tayo Tanso (Japan) produces IG-430 which is a petroleum coke, isostatically molded, nuclear grade graphite. And PCEA is a medium grain, extruded graphite produced by UCAR Carbon Co. (USA) from petroleum coke. An experimental program has been initiated to develop physical and mechanical properties data for these current candidate graphites. The results will be judged against the requirements formore » nuclear grade graphites set forth in ASTM standard D 7219-05 "Standard Specification for Isotropic and Near-isotropic Nuclear Graphites". Physical properties data including thermal conductivity and coefficient of thermal expansion, and mechanical properties data including tensile, compressive and flexural strengths will be obtained using the established test methods covered in D-7219 and ASTM C 781-02 "Standard Practice for Testing Graphite and Boronated Graphite Components for High-Temperature Gas-Cooled Nuclear Reactors". Various factors known to effect the properties of graphites will be investigated. These include specimen size, spatial location within a graphite billet, specimen orientation (ag and wg) within a billet, and billet-to-billet variations. The current status of the materials characterization program is reported herein. To date billets of the four graphite grades have been procured, and detailed cut up plans for obtaining the various specimens have been prepared. Particular attention has been given to the traceability of each specimen to its spatial location and orientation within a billet.« less

Ureilite smelting

NASA Technical Reports Server (NTRS)

Walker, David; Grove, Tim

1993-01-01

Ureilites containing homogeneous Fo76 olivine cores in intimate co-existence with graphite must have recrystallized at pressures of at least approximately 100 bars to suppress smelting of the fayalite component of the olivine to Fe metal. Smelting of olivine and pyroxene-saturated magmatic liquids produces orthopyroxene-without-olivine crystalline derivatives unlike those in ureilites. Thus the Mg# compositional variation within the ureilite suite, which is commonly attributed to partial smelting, cannot plausibly be produced by assemblages rich in liquid. In situ smelting of graphitic olivine + pigeonite crystal mushes can produce the correct crystal assemblage, but fails to provide a plausible account for the removal of metal from ureilites or for the correlation of Mg# with Delta O-17. Even if Mg# and Delta O-17 variations are established in the nebula, ureilite recrystallization with graphite must have occurred at pressures greater than the minima we have experimentally established, corresponding to parent objects not less than approximately 100 km in radius.

Ab Initio Theory of Dynamical Core-Hole Screening in Graphite from X-Ray Absorption Spectra

NASA Astrophysics Data System (ADS)

Wessely, O.; Katsnelson, M. I.; Eriksson, O.

2005-04-01

We have implemented the effect of dynamical core-hole screening, as given by Mahan, Nozières, and De Dominicis, in a first-principles based method and applied the theory to the x-ray absorption (XA) spectrum of graphite. It turns out that two of the conspicuous peaks of graphite are well described, both regarding the position, shape, and relative intensity, whereas one peak is absent in the theory. Only by incorporation of both excitonic and delocalized processes can a full account of the experimental spectrum be obtained theoretically, and we interpret the XA spectrum in graphite to be the result of a well screened and a poor screened process, much in the same way as is done for core level x-ray photoelectron spectroscopy.

A New Method to Measure Crack Extension in Nuclear Graphite Based on Digital Image Correlation

DOE PAGES

Lai, Shigang; Shi, Li; Fok, Alex; ...

2017-01-01

Graphite components, used as moderators, reflectors, and core-support structures in a High-Temperature Gas-Cooled Reactor, play an important role in the safety of the reactor. Specifically, they provide channels for the fuel elements, control rods, and coolant flow. Fracture is the main failure mode for graphite, and breaching of the above channels by crack extension will seriously threaten the safety of a reactor. In this paper, a new method based on digital image correlation (DIC) is introduced for measuring crack extension in brittle materials. Cross-correlation of the displacements measured by DIC with a step function was employed to identify the advancingmore » crack tip in a graphite beam specimen under three-point bending. The load-crack extension curve, which is required for analyzing the R-curve and tension softening behaviors, was obtained for this material. Furthermore, a sensitivity analysis of the threshold value employed for the cross-correlation parameter in the crack identification process was conducted. Finally, the results were verified using the finite element method.« less

A New Method to Measure Crack Extension in Nuclear Graphite Based on Digital Image Correlation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lai, Shigang; Shi, Li; Fok, Alex

Graphite components, used as moderators, reflectors, and core-support structures in a High-Temperature Gas-Cooled Reactor, play an important role in the safety of the reactor. Specifically, they provide channels for the fuel elements, control rods, and coolant flow. Fracture is the main failure mode for graphite, and breaching of the above channels by crack extension will seriously threaten the safety of a reactor. In this paper, a new method based on digital image correlation (DIC) is introduced for measuring crack extension in brittle materials. Cross-correlation of the displacements measured by DIC with a step function was employed to identify the advancingmore » crack tip in a graphite beam specimen under three-point bending. The load-crack extension curve, which is required for analyzing the R-curve and tension softening behaviors, was obtained for this material. Furthermore, a sensitivity analysis of the threshold value employed for the cross-correlation parameter in the crack identification process was conducted. Finally, the results were verified using the finite element method.« less

Develop, demonstrate, and verify large area composite structural bonding with polyimide adhesives. [adhesively bonding graphite-polyimide structures

NASA Technical Reports Server (NTRS)

Bhombal, B. D.; Wykes, D. H.; Hong, K. C.; Stenersen, A. A.

1982-01-01

The technology required to produce graphite-polyimide structural components with operational capability at 598 K (600 F) is considered. A series of polyimide adhesives was screened for mechanical and physical properties and processibility in fabricating large midplane bonded panels and honeycomb sandwich panels in an effort to fabricate a structural test component of the space shuttle aft body flap. From 41 formulations, LaRC-13, FM34B-18, and a modified LaRC-13 adhesive were selected for further evaluation. The LaRC-13 adhesive was rated as the best of the three adhesives in terms of availability, cost, processibility, properties, and ability to produce void fee large area (12" x 12") midplane bonds. Surface treatments and primers for the adhesives were evaluated and processes were developed for the fabrication of honeycomb sandwich panels of very good quality which was evidenced by rupture in the honeycomb core rather than in the facesheet bands on flatwise tensile strength testing. The fabrication of the adhesively bonded honeycomb sandwich cover panels, ribs, and leading edge covers of Celion graphite/LARC-160 polyimide laminates is described.

Chemical stabilization of graphite surfaces

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bistrika, Alexander A.; Lerner, Michael M.

Embodiments of a device, or a component of a device, including a stabilized graphite surface, methods of stabilizing graphite surfaces, and uses for the devices or components are disclosed. The device or component includes a surface comprising graphite, and a plurality of haloaryl ions and/or haloalkyl ions bound to at least a portion of the graphite. The ions may be perhaloaryl ions and/or perhaloalkyl ions. In certain embodiments, the ions are perfluorobenzenesulfonate anions. Embodiments of the device or component including stabilized graphite surfaces may maintain a steady-state oxidation or reduction surface current density after being exposed to continuous oxidation conditionsmore » for a period of at least 1-100 hours. The device or component is prepared by exposing a graphite-containing surface to an acidic aqueous solution of the ions under oxidizing conditions. The device or component can be exposed in situ to the solution.« less

7. Another picture of workers laying up the graphite core ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

7. Another picture of workers laying up the graphite core of the 105-B pile. This view is towards the rear of the pile. The gun barrels can be seen protruding into the pile. D-3047 - B Reactor, Richland, Benton County, WA

Liquid-phase pulsed laser ablation synthesis of graphitized carbon-encapsulated palladium core-shell nanospheres for catalytic reduction of nitrobenzene to aniline

NASA Astrophysics Data System (ADS)

Kim, Yu-jin; Ma, Rory; Reddy, D. Amaranatha; Kim, Tae Kyu

2015-12-01

Graphitized carbon-encapsulated palladium (Pd) core-shell nanospheres were produced via pulsed laser ablation of a solid Pd foil target submerged in acetonitrile. The microstructural features and optical properties of these nanospheres were characterized via high resolution transmission electron microscopy (HRTEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and UV-visible spectroscopy. Microstructural analysis indicated that the core-shell nanostructures consisted of single-crystalline cubic metallic Pd spheres that serve as the core material, over which graphitized carbon was anchored as a heterogeneous shell. The absorbance spectrum of the synthesized nanostructures exhibited a broad (absorption) band at ∼264 nm; this band corresponded to the typical inter-band transition of a metallic system and resulted possibly from the absorbance of the ionic Pd2+. The catalytic properties of the Pd and Pd@C core-shell nanostructures were investigated using the reduction of nitrobenzene to aniline by an excess amount of NaBH4 in an aqueous solution at room temperature, as a model reaction. Owing to the graphitized carbon-layered structure and the high specific surface area, the resulting Pd@C nanostructures exhibited higher conversion efficiencies than their bare Pd counterparts. In fact, the layered structure provided access to the surface of the Pd nanostructures for the hydrogenation reaction, owing to the synergistic effect between graphitized carbon and the nanostructures. Their unique structure and excellent catalytic performance render Pd@C core-shell nanostructures highly promising candidates for catalysis applications.

Fabrication of TREAT Fuel with Increased Graphite Loading

DOE Office of Scientific and Technical Information (OSTI.GOV)

Luther, Erik Paul; Leckie, Rafael M.; Dombrowski, David E.

2014-02-05

As part of the feasibility study exploring the replacement of the HEU fuel core of the TREAT reactor at Idaho National Laboratory with LEU fuel, this study demonstrates that it is possible to increase the graphite content of extruded fuel by reformulation. The extrusion process was use to fabricate the “upgrade” core1 for the TREAT reactor. The graphite content achieved is determined by calculation and has not been measured by any analytical method. In conjunction, a technique, Raman Spectroscopy, has been investigated for measuring the graphite content. This method shows some promise in differentiating between carbon and graphite; however, standardsmore » that would allow the technique to be calibrated to quantify the graphite concentration have yet to be fabricated. Continued research into Raman Spectroscopy is on going. As part of this study, cracking of graphite extrusions due to volatile evolution during heat treatment has been largely eliminated. Continued research to optimize this extrusion method is required.« less

The 737 graphite composite flight spoiler flight service evaluation

NASA Technical Reports Server (NTRS)

Stoecklin, R. L.

1976-01-01

The flight-service experience of 110 graphite-epoxy spoilers on 737 transport aircraft and related ground-based environmental exposure of graphite-epoxy material specimens is reported. Spoilers were installed on each of 27 aircraft representing seven major airlines operating throughout the world. Based on visual, ultrasonic, and destructive testing, there is no evidence of moisture migration into the honeycomb core and no core corrosion. Tests of removed spoilers and of ground-based exposure specimens after the second year of service indicate modest changes in composite strength.

The 737 graphite composite flight spoiler flight service evaluation

NASA Technical Reports Server (NTRS)

Hoffman, D. J.; Stoecklin, R. L.

1980-01-01

The flight service experience of 111 graphite-epoxy spoilers on 737 transport aircraft and related ground based enviromental exposure of graphite-epoxy material specimens is reported. Spoilers were installed on 28 aircraft representing seven major airlines operating throughout the world. Over 1,188,367 spoiler flight hours and 1,786,837 spoiler landings were accumulated by this fleet. Tests of removed spoilers and ground-based exposure specimens after the fifth year of service indicate modest changes in composite strength properties. Two incidents of trailing edge delamination with subsequent core corrosion were observed. Based on visual, ultrasonic, and destructive testing, there has been no evidence of moisture migration into the honeycomb core and no core corrosion.

HTGR fuels and core development program. Quarterly progress report for the period ending August 31, 1975

DOE Office of Scientific and Technical Information (OSTI.GOV)

None

1975-09-30

Studies of reactions between core materials and coolant impurities, basic fission product transport mechanisms, core graphite development and testing, the development and testing of recyclable fuel systems, and physics and fuel management studies are described. Materials studies include irradiation capsule tests of both fuel and graphite. Experimental procedures and results are discussed and, where appropriate, the data are presented in tables, graphs, and photographs. (auth)

Advanced manufacturing development of a composite empennage component for L-1011 aircraft. Phase 2: Design and analysis

NASA Technical Reports Server (NTRS)

Jackson, A. C.; Crocker, J. F.; Ekvall, J. C.; Eudaily, R. R.; Mosesian, B.; Vancleave, R. R.; Vanhamersveld, J.

1981-01-01

The composite fin design consists of two one-piece cocured covers, two one-piece cocured spars and eleven ribs. The lower ribs are truss ribs with graphite/epoxy caps and aluminum truss members. The upper three ribs are a sandwich design with graphite/epoxy face sheets and a syntactic epoxy core. The design achieves a 27% weight saving compared to the metal box. The fastener count has been reduced from over 40,000 to less than 7000. The structural integrity of the composite fin was verified by analysis and test. The static, fail-safe and flutter analyses were completed. An extensive test program has established the material behavior under a range of conditions and critical subcomponents were tested to verify the structural concepts.

Top shield temperatures, C and K Reactors

DOE Office of Scientific and Technical Information (OSTI.GOV)

Agar, J.D.

1964-12-28

A modification program is now in progress at the C and K Reactors consisting of an extensive renovation of the graphite channels in the vertical safety rod ststems. The present VSR channels are being enlarged by a graphite coring operation and channel sleeves will be installed in the larger channels. One problem associated with the coring operation is the danger of damaging top thermal shield cooling tubes located close to the VSR channels to such an extent that these tubes will have to be removed from service. If such a condition should exist at one or a number of locationsmore » in the top shield of the reactors after reactor startup, the question remains -- what would the resulting temperatures be of the various components of the top shields? This study was initiated to determine temperature distributions in the top shield complex at the C and K Reactors for various top thermal shield coolant system conditions. Since the top thermal shield cooling system at C Reactor is different than those at the K Reactors, the study was conducted separately for the two different systems.« less

Absolute x-ray dosimetry on a synchrotron medical beam line with a graphite calorimeter.

PubMed

Harty, P D; Lye, J E; Ramanathan, G; Butler, D J; Hall, C J; Stevenson, A W; Johnston, P N

2014-05-01

The absolute dose rate of the Imaging and Medical Beamline (IMBL) on the Australian Synchrotron was measured with a graphite calorimeter. The calorimetry results were compared to measurements from the existing free-air chamber, to provide a robust determination of the absolute dose in the synchrotron beam and provide confidence in the first implementation of a graphite calorimeter on a synchrotron medical beam line. The graphite calorimeter has a core which rises in temperature when irradiated by the beam. A collimated x-ray beam from the synchrotron with well-defined edges was used to partially irradiate the core. Two filtration sets were used, one corresponding to an average beam energy of about 80 keV, with dose rate about 50 Gy/s, and the second filtration set corresponding to average beam energy of 90 keV, with dose rate about 20 Gy/s. The temperature rise from this beam was measured by a calibrated thermistor embedded in the core which was then converted to absorbed dose to graphite by multiplying the rise in temperature by the specific heat capacity for graphite and the ratio of cross-sectional areas of the core and beam. Conversion of the measured absorbed dose to graphite to absorbed dose to water was achieved using Monte Carlo calculations with the EGSnrc code. The air kerma measurements from the free-air chamber were converted to absorbed dose to water using the AAPM TG-61 protocol. Absolute measurements of the IMBL dose rate were made using the graphite calorimeter and compared to measurements with the free-air chamber. The measurements were at three different depths in graphite and two different filtrations. The calorimetry measurements at depths in graphite show agreement within 1% with free-air chamber measurements, when converted to absorbed dose to water. The calorimetry at the surface and free-air chamber results show agreement of order 3% when converted to absorbed dose to water. The combined standard uncertainty is 3.9%. The good agreement of the graphite calorimeter and free-air chamber results indicates that both devices are performing as expected. Further investigations at higher dose rates than 50 Gy/s are planned. At higher dose rates, recombination effects for the free-air chamber are much higher and expected to lead to much larger uncertainties. Since the graphite calorimeter does not have problems associated with dose rate, it is an appropriate primary standard detector for the synchrotron IMBL x rays and is the more accurate dosimeter for the higher dose rates expected in radiotherapy applications.

Graphite grain-size spectrum and molecules from core-collapse supernovae

NASA Astrophysics Data System (ADS)

Clayton, Donald D.; Meyer, Bradley S.

2018-01-01

Our goal is to compute the abundances of carbon atomic complexes that emerge from the C + O cores of core-collapse supernovae. We utilize our chemical reaction network in which every atomic step of growth employs a quantum-mechanically guided reaction rate. This tool follows step-by-step the growth of linear carbon chain molecules from C atoms in the oxygen-rich C + O cores. We postulate that once linear chain molecules reach a sufficiently large size, they isomerize to ringed molecules, which serve as seeds for graphite grain growth. We demonstrate our technique for merging the molecular reaction network with a parallel program that can follow 1017 steps of C addition onto the rare seed species. Due to radioactivity within the C + O core, abundant ambient oxygen is unable to convert C to CO, except to a limited degree that actually facilitates carbon molecular ejecta. But oxygen severely minimizes the linear-carbon-chain abundances. Despite the tiny abundances of these linear-carbon-chain molecules, they can give rise to a small abundance of ringed-carbon molecules that serve as the nucleations on which graphite grain growth builds. We expand the C + O-core gas adiabatically from 6000 K for 109 s when reactions have essentially stopped. These adiabatic tracks emulate the actual expansions of the supernova cores. Using a standard model of 1056 atoms of C + O core ejecta having O/C = 3, we calculate standard ejection yields of graphite grains of all sizes produced, of the CO molecular abundance, of the abundances of linear-carbon molecules, and of Buckminsterfullerene. None of these except CO was expected from the C + O cores just a few years past.

They Came from the Deep in the Supernova: The Origin of TiC and Metal Subgrains in Presolar Graphite Grains

NASA Astrophysics Data System (ADS)

Lodders, Katharina

2006-08-01

A new formation scenario for TiC and Fe-Ni metal inclusions in presolar graphite grains of supernova origin is described. The mineralogy and chemistry require condensation of Fe-Ni titanides from Fe-, Ni-, and Ti-rich gaseous ejecta, subsequent carburization to make TiC and metal, and encapsulation into graphite. Titanides only condense if Si is depleted relative to heavier elements, which requires α-rich freeze-out and a deep mass cut for the supernova ejecta. This Si-poor core material must remain unmixed with other supernova zones until the titanides condense. This can be accomplished by transport of core ejecta in bipolar jets through the major expanding supernova zone ejecta. If the jets stall in regions dominated by C-rich ejecta such as the C-He zone, where graphite condenses, thermochemically favored in situ carburization of the titanides-either before or during encapsulation into condensing graphite-leads to a TiC-and-metal composite. This scenario agrees with theoretical models and observations of asymmetric core collapse in supernovae that are associated with bipolar jets loaded with iron-peak elements.

Design Study of a Modular Gas-Cooled, Closed-Brayton Cycle Reactor for Marine Use

DTIC Science & Technology

1989-06-01

materials in the core and surroundings. To investigate this design point in the marine variant I developed the program HEAT.BAS to perform a one-dimensional...helium as the working fluid. The core is a graphite moderated, epithermal spectrum reactor, using TRISO fuel particles in extruded graphite fuel elements...The fuel is highly enriched U2315 . The containment is shaped in an inverted ’T’ with two sections. The upper section contains the reactor core

Apparatus for controlling molten core debris

DOEpatents

Golden, Martin P. [Trafford, PA; Tilbrook, Roger W. [Monroeville, PA; Heylmun, Neal F. [Pittsburgh, PA

1977-07-19

Apparatus for containing, cooling, diluting, dispersing and maintaining subcritical the molten core debris assumed to melt through the bottom of a nuclear reactor pressure vessel in the unlikely event of a core meltdown. The apparatus is basically a sacrificial bed system which includes an inverted conical funnel, a core debris receptacle including a spherical dome, a spherically layered bed of primarily magnesia bricks, a cooling system of zig-zag piping in graphite blocks about and below the bed and a cylindrical liner surrounding the graphite blocks including a steel shell surrounded by firebrick. Tantalum absorber rods are used in the receptacle and bed.

High-temperature gas-cooled reactor technology development program. Annual progress report for period ending December 31, 1982

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kasten, P.R.; Rittenhouse, P.L.; Bartine, D.E.

1983-06-01

During 1982 the High-Temperature Gas-Cooled Reactor (HTGR) Technology Program at Oak Ridge National Laboratory (ORNL) continued to develop experimental data required for the design and licensing of cogeneration HTGRs. The program involves fuels and materials development (including metals, graphite, ceramic, and concrete materials), HTGR chemistry studies, structural component development and testing, reactor physics and shielding studies, performance testing of the reactor core support structure, and HTGR application and evaluation studies.

Development and demonstration of manufacturing processes for fabricating graphite/LARC-160 polyimide structural elements, part 4, paragraph B

NASA Technical Reports Server (NTRS)

1980-01-01

A quality assurance program was developed which included specifications for celion/LARC-160 polyimide materials and quality control of materials and processes. The effects of monomers and/or polymer variables and prepeg variables on the processibility of celion/LARC prepeg were included. Processes for fabricating laminates, honeycomb core panels, and chopped fiber moldings were developed. Specimens and conduct tests were fabricated to qualify the processes for fabrication of demonstration components.

Large-Scale Weibull Analysis of H-451 Nuclear- Grade Graphite Specimen Rupture Data

NASA Technical Reports Server (NTRS)

Nemeth, Noel N.; Walker, Andrew; Baker, Eric H.; Murthy, Pappu L.; Bratton, Robert L.

2012-01-01

A Weibull analysis was performed of the strength distribution and size effects for 2000 specimens of H-451 nuclear-grade graphite. The data, generated elsewhere, measured the tensile and four-point-flexure room-temperature rupture strength of specimens excised from a single extruded graphite log. Strength variation was compared with specimen location, size, and orientation relative to the parent body. In our study, data were progressively and extensively pooled into larger data sets to discriminate overall trends from local variations and to investigate the strength distribution. The CARES/Life and WeibPar codes were used to investigate issues regarding the size effect, Weibull parameter consistency, and nonlinear stress-strain response. Overall, the Weibull distribution described the behavior of the pooled data very well. However, the issue regarding the smaller-than-expected size effect remained. This exercise illustrated that a conservative approach using a two-parameter Weibull distribution is best for designing graphite components with low probability of failure for the in-core structures in the proposed Generation IV (Gen IV) high-temperature gas-cooled nuclear reactors. This exercise also demonstrated the continuing need to better understand the mechanisms driving stochastic strength response. Extensive appendixes are provided with this report to show all aspects of the rupture data and analytical results.

Apparatus for controlling molten core debris. [LMFBR

DOEpatents

Golden, M.P.; Tilbrook, R.W.; Heylmun, N.F.

1977-07-19

Disclosed is an apparatus for containing, cooling, diluting, dispersing and maintaining subcritical the molten core debris assumed to melt through the bottom of a nuclear reactor pressure vessel in the unlikely event of a core meltdown. The apparatus is basically a sacrificial bed system which includes an inverted conical funnel, a core debris receptacle including a spherical dome, a spherically layered bed of primarily magnesia bricks, a cooling system of zig-zag piping in graphite blocks about and below the bed and a cylindrical liner surrounding the graphite blocks including a steel shell surrounded by firebrick. Tantalum absorber rods are used in the receptacle and bed. 9 claims, 22 figures.

Eddy-Current Probes For Inspecting Graphite-Fiber Composites

NASA Technical Reports Server (NTRS)

Workman, Gary L.; Wang, Morgan

1992-01-01

Eddy-current probes with E-shaped and U-shaped magnetic cores developed to detect flaws in graphite-fiber/epoxy and other composites. Magnetic fields more concentrated, yielding better coupling with specimens.

The 737 graphite composite flight spoiler flight service evaluation

NASA Technical Reports Server (NTRS)

Stoecklin, R. L.

1975-01-01

The flight service experience of 108 graphite-epoxy spoilers on 737 transport aircraft, and related ground-based environmental exposure of graphite-epoxy material specimens were evaluated. Four spoilers were installed on each of 27 aircraft for a 5-year study. As of February 28, 1975, a total of 294,280 spoiler flight-hours and 460,686 spoiler landings were accumulated. Based on visual, ultrasonic, and destructive testing, no moisture migration into the honeycomb core and no core corrosion has occurred. Tests of removed spoilers and of ground-based exposure specimens after the first year of service indicate no significant changes in composite strength.

High-temperature, high-pressure bonding of nested tubular metallic components

DOEpatents

Quinby, T.C.

A tool is described for effecting high-temperature, high-compression bonding between the confronting faces of nested, tubular, metallic components. In a typical application, the tool is used to produce tubular target assemblies for irradiation in nuclear reactors or particle accelerators. The target assembly comprising a uranum foil and an aluninum-alloy substrate. The tool is composed of graphite. It comprises a tubular restraining member in which a mechanically expandable tubular core is mounted to form an annulus. The components to be bonded are mounted in nested relation in the annulus. The expandable core is formed of individually movable, axially elongated segments whose outer faces cooperatively define a cylindrical pressing surface and whose inner faces cooperatively define two opposed, inwardly tapered, axial bores. Tapered rams extend into the bores. The loaded tool is mounted in a conventional hot-press provided with evacuation means, heaters for maintaining its interior at bonding temperature, and hydraulic cylinders for maintaining a selected inwardly directed pressure on the tapered rams. With the hot-press evacuated and the loaded tool at the desired temperature, the cylinders are actuated to apply the selected pressure to the rams. The rams in turn expand the segmented core to maintain the nested components in compression against the restraining member. These conditions are maintained until the confronting faces of the nested components are joined in a continuous, uniform bond characterized by high thermal conductivity.

Synthesis of core-shell iron nanoparticles via a new (novel) approach

NASA Astrophysics Data System (ADS)

Chaudhary, Rakesh P.; Koymen, Ali R.

2014-03-01

Carbon-encapsulated iron (Fe) nanoparticles were synthesized by a newly developed method in toluene. Transmission Electron Microscopy (TEM) and High Resolution Transmission Electron Microscopy (HRTEM) of the as prepared sample reveal that core-shell nanostructures have been formed with Fe as core and graphitic carbon as shell. Fe nanoparticles with diameter 11nm to 102 nm are encapsulated by 6-8 nm thick graphitic carbon layers. There was no iron carbide formation observed between the Fe core and the graphitic shell. The Fe nanoparticles have body centered cubic (bcc) crystal structure. The magnetic hysteresis loop of the as synthesized powder at room temperature showed a saturation magnetization of 9 Am2 kg-1. After thermal treatment crystalline order of the samples improved and hence saturation magnetization increased to 24 Am2kg-1. We foresee that the carbon-encapsulated Fe nanoparticles are biologically friendly and could have potential applications in Magnetic Resonance Imaging (MRI) and Photothermal cancer therapy.

Method of producing exfoliated graphite composite compositions for fuel cell flow field plates

DOEpatents

Zhamu, Aruna; Shi, Jinjun; Guo, Jiusheng; Jang, Bor Z

2014-04-08

A method of producing an electrically conductive composite composition, which is particularly useful for fuel cell bipolar plate applications. The method comprises: (a) providing a supply of expandable graphite powder; (b) providing a supply of a non-expandable powder component comprising a binder or matrix material; (c) blending the expandable graphite with the non-expandable powder component to form a powder mixture wherein the non-expandable powder component is in the amount of between 3% and 60% by weight based on the total weight of the powder mixture; (d) exposing the powder mixture to a temperature sufficient for exfoliating the expandable graphite to obtain a compressible mixture comprising expanded graphite worms and the non-expandable component; (e) compressing the compressible mixture at a pressure within the range of from about 5 psi to about 50,000 psi in predetermined directions into predetermined forms of cohered graphite composite compact; and (f) treating the so-formed cohered graphite composite to activate the binder or matrix material thereby promoting adhesion within the compact to produce the desired composite composition. Preferably, the non-expandable powder component further comprises an isotropy-promoting agent such as non-expandable graphite particles. Further preferably, step (e) comprises compressing the mixture in at least two directions. The method leads to composite plates with exceptionally high thickness-direction electrical conductivity.

Sulfur-Doping Templated Synthesis of Nanoporous Graphitic Nanocages and Its Supported Catalysts for Efficient Methanol Oxidation.

PubMed

Sheng, Zhao Min; Hong, Cheng Yang; Dai, Xian You; Chang, Cheng Kang; Chen, Jian Bin; Liu, Yan

2015-04-01

We demonstrate a new sulfur (S)-doping templated approach to fabricate highly nanoporous graphitic nanocages (GNCs) by air-oxidizing the templates in the graphitic shells to create nanopores. Sulfur can be introduced, when Fe@C core-shell nanoparticles are prepared and then S-doped GNCs can be obtained by removing their ferrous cores. Due to removing S-template, both the specific surface area (from 540 to 850 m2 g(-1)) and the mesopore volume (from 0.44 to 0.9 cm3 g(-1)) of the graphitic nanocages have sharply risen. Its high specific surface area improves catalyst loading to provide more reaction electro-active sites while its high mesopore volume pro- motes molecule diffusion across the nanocages, making it an excellent material to support Pt/Ru catalysts for direct methanol fuel cells.

Development of lightweight graphite/polyimide sandwich panels, phases 3, 4 and 5

NASA Technical Reports Server (NTRS)

Merlette, J. B.

1972-01-01

Work performed in the last three phases of the program included: (1) face sheet processing; (2) honeycomb core manufacture; (3) face sheet-to-core bonding development; and (4) sandwich panel fabrication and testing. Resin cure studies were a major portion of this effort since processing problems traced to the polyimide matrix resin had to be resolved before quality core and face sheets could be fabricated. Honeycomb core fabrication and testing were conducted by Hexcel Corporation. A total of four graphite/polyimide resin composite cores were fabricated, tested, and reported. Two sandwich panels weighing .48 and .58 lb/sq ft, respectively were designed and fabricated which meet the support structure loads for the shuttle orbiter thermal protection system.

High temperature gas-cooled reactor (HTGR) graphite pebble fuel: Review of technologies for reprocessing

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mcwilliams, A. J.

2015-09-08

This report reviews literature on reprocessing high temperature gas-cooled reactor graphite fuel components. A basic review of the various fuel components used in the pebble bed type reactors is provided along with a survey of synthesis methods for the fabrication of the fuel components. Several disposal options are considered for the graphite pebble fuel elements including the storage of intact pebbles, volume reduction by separating the graphite from fuel kernels, and complete processing of the pebbles for waste storage. Existing methods for graphite removal are presented and generally consist of mechanical separation techniques such as crushing and grinding chemical techniquesmore » through the use of acid digestion and oxidation. Potential methods for reprocessing the graphite pebbles include improvements to existing methods and novel technologies that have not previously been investigated for nuclear graphite waste applications. The best overall method will be dependent on the desired final waste form and needs to factor in the technical efficiency, political concerns, cost, and implementation.« less

Study to investigate design, fabrication and test of low cost concepts for large hybrid composite helicopter fuselage, phase 2

NASA Technical Reports Server (NTRS)

Adams, K. M.; Lucas, J. J.

1977-01-01

The development of a frame/stringer/skin fabrication technique for composite airframe construction was studied as a low cost approach to the manufacturer of larger helicopter airframe components. A center cabin aluminum airframe section of the Sikorsky CH-53D, was selected for evaluation as a composite structure. The design, as developed, is composed of a woven KEVLAR R-49/epoxy skin and graphite/epoxy frames and stringers. The single cure concept is made possible by the utilization of pre-molded foam cores, over which the graphite/epoxy pre-impregnated frame and stringer reinforcements are positioned. Bolted composite channel sections were selected as the optimum joint construction. The applicability of the single cure concept to larger realistic curved airframe sections, and the durability of the composite structure in a realistic spectrum fatigue environment, was described.

GAS COOLED NUCLEAR REACTORS

DOEpatents

Long, E.; Rodwell, W.

1958-06-10

A gas-cooled nuclear reactor consisting of a graphite reacting core and reflector structure supported in a containing vessel is described. A gas sealing means is included for sealing between the walls of the graphite structure and containing vessel to prevent the gas coolant by-passing the reacting core. The reacting core is a multi-sided right prismatic structure having a pair of parallel slots around its periphery. The containing vessel is cylindrical and has a rib on its internal surface which supports two continuous ring shaped flexible web members with their radially innermost ends in sealing engagement within the radially outermost portion of the slots. The core structure is supported on ball bearings. This design permits thermal expansion of the core stracture and vessel while maintainirg a peripheral seal between the tvo elements.

Effect of Reacting Surface Density on the Overall Graphite Oxidation Rate

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chang H. Oh; Eung Kim; Jong Lim

2009-05-01

Graphite oxidation in an air-ingress accident is presently a very important issue for the reactor safety of the very high temperature gas cooled-reactor (VHTR), the concept of the next generation nuclear plant (NGNP) because of its potential problems such as mechanical degradation of the supporting graphite in the lower plenum of the VHTR might lead to core collapse if the countermeasure is taken carefully. The oxidation process of graphite has known to be affected by various factors, including temperature, pressure, oxygen concentration, types of graphite, graphite shape and size, flow distribution, etc. However, our recent study reveals that the internalmore » pore characteristics play very important roles in the overall graphite oxidation rate. One of the main issues regarding graphite oxidation is the potential core collapse problem that may occur following the degradation of graphite mechanical strength. In analyzing this phenomenon, it is very important to understand the relationship between the degree of oxidization and strength degradation. In addition, the change of oxidation rate by graphite oxidation degree characterization by burn-off (ratio of the oxidized graphite density to the original density) should be quantified because graphite strength degradation is followed by graphite density decrease, which highly affects oxidation rates and patterns. Because the density change is proportional to the internal pore surface area, they should be quantified in advance. In order to understand the above issues, the following experiments were performed: (1)Experiment on the fracture of the oxidized graphite and validation of the previous correlations, (2) Experiment on the change of oxidation rate using graphite density and data collection, (3) Measure the BET surface area of the graphite. The experiments were performed using H451 (Great Lakes Carbon Corporation) and IG-110 (Toyo Tanso Co., Ltd) graphite. The reason for the use of those graphite materials is because their chemical and mechanical characteristics are well identified by the previous investigations, and therefore it was convenient for us to access the published data, and to apply and validate our new methodologies. This paper presents preliminary results of compressive strength vs. burn-off and surface area density vs. burn-off, which can be used for the nuclear graphite selection for the NGNP.« less

Nanostructural evolution during emission of CsI-coated carbon fiber cathodes

NASA Astrophysics Data System (ADS)

Drummy, Lawrence F.; Apt, Scott; Shiffler, Don; Golby, Ken; LaCour, Matt; Maruyama, Benji; Vaia, Richard A.

2010-06-01

Carbon-based nanofiber and microfiber cathodes exhibit very low voltages for the onset of electron emission, and thus provide exciting opportunities for applications ranging from high power microwave sources to field emission displays. CsI coatings have been experimentally shown to lower the work function for emission from the fiber tips, although little is known about the microstructure of the fibers themselves in their as-received state, after coating with CsI, or after being subjected to high voltage cycling. Longitudinal cross sections of the original, unused CsI-coated fibers produced by focused ion beam lift-out revealed a nanostructured graphitic core surrounded by an amorphous carbon shell with submicron sized islands of crystalline CsI on the outer surface. Aberration-corrected high resolution electron microscopy (HREM) of the fiber core achieved 0.10 nm resolution, with the graphite (200) clearly visible in digital fast Fourier transformations of the 2-4 nm highly ordered graphitic domains. As the cathode fibers are cycled at high voltage, HREM demonstrates that the graphitic ordering of the core increases with the number of cycles, however the structure and thickness of the amorphous carbon layer remains unchanged. These results are consistent with micro-Raman measurements of the fiber disordered/graphitic (D/G) band ratios. After high voltage cycling, a uniform ˜100 nm film at the fiber tip was evident in both bright field transmission electron microscopy (TEM) and high angle annular dark field scanning TEM (STEM). Low-dose electron diffraction techniques confirmed the amorphous nature of this film, and STEM with elemental mapping via x-ray energy dispersive spectroscopy indicates this layer is composed of CsIO. The oxidative evolution of tip composition and morphology due to impurities in the chamber, along with increased graphitization of the fiber core, contributes to changes in emission behavior with cycling.

Monte Carlo Analysis of the Battery-Type High Temperature Gas Cooled Reactor

NASA Astrophysics Data System (ADS)

Grodzki, Marcin; Darnowski, Piotr; Niewiński, Grzegorz

2017-12-01

The paper presents a neutronic analysis of the battery-type 20 MWth high-temperature gas cooled reactor. The developed reactor model is based on the publicly available data being an `early design' variant of the U-battery. The investigated core is a battery type small modular reactor, graphite moderated, uranium fueled, prismatic, helium cooled high-temperature gas cooled reactor with graphite reflector. The two core alternative designs were investigated. The first has a central reflector and 30×4 prismatic fuel blocks and the second has no central reflector and 37×4 blocks. The SERPENT Monte Carlo reactor physics computer code, with ENDF and JEFF nuclear data libraries, was applied. Several nuclear design static criticality calculations were performed and compared with available reference results. The analysis covered the single assembly models and full core simulations for two geometry models: homogenous and heterogenous (explicit). A sensitivity analysis of the reflector graphite density was performed. An acceptable agreement between calculations and reference design was obtained. All calculations were performed for the fresh core state.

Pre-conceptual Development and characterization of an extruded graphite composite fuel for the TREAT Reactor

DOE Office of Scientific and Technical Information (OSTI.GOV)

Luther, Erik; Rooyen, Isabella van; Leckie, Rafael

2015-03-01

In an effort to explore fuel systems that are more robust under accident scenarios, the DOE-NE has identified the need to resume transient testing. The Transient Reactor Test (TREAT) facility has been identified as the preferred option for the resumption of transient testing of nuclear fuel in the United States. In parallel, NNSA’s Global Threat Reduction Initiative (GTRI) Convert program is exploring the needs to replace the existing highly enriched uranium (HEU) core with low enriched uranium (LEU) core. In order to construct a new LEU core, materials and fabrication processes similar to those used in the initial core fabricationmore » must be identified, developed and characterized. In this research, graphite matrix fuel blocks were extruded and materials properties of were measured. Initially the extrusion process followed the historic route; however, the project was expanded to explore methods to increase the graphite content of the fuel blocks and explore modern resins. Materials properties relevant to fuel performance including density, heat capacity and thermal diffusivity were measured. The relationship between process defects and materials properties will be discussed.« less

Development of a Continuum Damage Mechanics Material Model of a Graphite-Kevlar(Registered Trademark) Hybrid Fabric for Simulating the Impact Response of Energy Absorbing Kevlar(Registered Trademark) Hybrid Fabric for Simulating the Impact Response of Energy Absorbing

NASA Technical Reports Server (NTRS)

Jackson, Karen E.; Fasanella, Edwin L.; Littell, Justin D.

2017-01-01

This paper describes the development of input properties for a continuum damage mechanics based material model, Mat 58, within LS-DYNA(Registered Trademark) to simulate the response of a graphite-Kevlar(Registered Trademark) hybrid plain weave fabric. A limited set of material characterization tests were performed on the hybrid graphite-Kevlar(Registered Trademark) fabric. Simple finite element models were executed in LS-DYNA(Registered Trademark) to simulate the material characterization tests and to verify the Mat 58 material model. Once verified, the Mat 58 model was used in finite element models of two composite energy absorbers: a conical-shaped design, designated the "conusoid," fabricated of four layers of hybrid graphite-Kevlar(Registered Trademark) fabric; and, a sinusoidal-shaped foam sandwich design, designated the "sinusoid," fabricated of the same hybrid fabric face sheets with a foam core. Dynamic crush tests were performed on components of the two energy absorbers, which were designed to limit average vertical accelerations to 25- to 40-g, to minimize peak crush loads, and to generate relatively long crush stroke values under dynamic loading conditions. Finite element models of the two energy absorbers utilized the Mat 58 model that had been verified through material characterization testing. Excellent predictions of the dynamic crushing response were obtained.

High-temperature, high-pressure bonding of nested tubular metallic components

DOEpatents

Quinby, Thomas C.

1980-01-01

This invention is a tool for effecting high-temperature, high-compression bonding between the confronting faces of nested, tubular, metallic components. In a typical application, the tool is used to produce tubular target assemblies for irradiation in nuclear reactors or particle accelerators, the target assembly comprising a uranium foil and an aluminum-alloy substrate. The tool preferably is composed throughout of graphite. It comprises a tubular restraining member in which a mechanically expandable tubular core is mounted to form an annulus with the member. The components to be bonded are mounted in nested relation in the annulus. The expandable core is formed of individually movable, axially elongated segments whose outer faces cooperatively define a cylindrical pressing surface and whose inner faces cooperatively define two opposed, inwardly tapered, axial bores. Tapered rams extend respectively into the bores. The loaded tool is mounted in a conventional hot-press provided with evacuation means, heaters for maintaining its interior at bonding temperature, and hydraulic cylinders for maintaining a selected inwardly directed pressure on the tapered rams. With the hot-press evacuated and the loaded tool at the desired temperature, the cylinders are actuated to apply the selected pressure to the rams. The rams in turn expand the segmented core to maintain the nested components in compression against the restraining member. These conditions are maintained until the confronting faces of the nested components are joined in a continuous, uniform bond characterized by high thermal conductivity.

Design modification for the modular helium reactor for higher temperature operation and reliability studies for nuclear hydrogen production processes

NASA Astrophysics Data System (ADS)

Reza, S. M. Mohsin

Design options have been evaluated for the Modular Helium Reactor (MHR) for higher temperature operation. An alternative configuration for the MHR coolant inlet flow path is developed to reduce the peak vessel temperature (PVT). The coolant inlet path is shifted from the annular path between reactor core barrel and vessel wall through the permanent side reflector (PSR). The number and dimensions of coolant holes are varied to optimize the pressure drop, the inlet velocity, and the percentage of graphite removed from the PSR to create this inlet path. With the removal of ˜10% of the graphite from PSR the PVT is reduced from 541°C to 421°C. A new design for the graphite block core has been evaluated and optimized to reduce the inlet coolant temperature with the aim of further reduction of PVT. The dimensions and number of fuel rods and coolant holes, and the triangular pitch have been changed and optimized. Different packing fractions for the new core design have been used to conserve the number of fuel particles. Thermal properties for the fuel elements are calculated and incorporated into these analyses. The inlet temperature, mass flow and bypass flow are optimized to limit the peak fuel temperature (PFT) within an acceptable range. Using both of these modifications together, the PVT is reduced to ˜350°C while keeping the outlet temperature at 950°C and maintaining the PFT within acceptable limits. The vessel and fuel temperatures during low pressure conduction cooldown and high pressure conduction cooldown transients are found to be well below the design limits. The reliability and availability studies for coupled nuclear hydrogen production processes based on the sulfur iodine thermochemical process and high temperature electrolysis process have been accomplished. The fault tree models for both these processes are developed. Using information obtained on system configuration, component failure probability, component repair time and system operating modes and conditions, the system reliability and availability are assessed. Required redundancies are made to improve system reliability and to optimize the plant design for economic performance. The failure rates and outage factors of both processes are found to be well below the maximum acceptable range.

CMB-13 research on carbon and graphite

NASA Technical Reports Server (NTRS)

Smith, M. C.

1972-01-01

The research on graphite and carbon for this period is reported. Topics discussed include: effects of grinding on the Santa Marie graphites, properties and purities of coal-tar, resin-bonded graphite, carbonization of resin components, and glass-like carbon filler.

Effects of Boron and Graphite Uncertainty in Fuel for TREAT Simulations

DOE Office of Scientific and Technical Information (OSTI.GOV)

Vaughn, Kyle; Mausolff, Zander; Gonzalez, Esteban

Advanced modeling techniques and current computational capacity make full core TREAT simulations possible, with the goal of such simulations to understand the pre-test core and minimize the number of required calibrations. But, in order to simulate TREAT with a high degree of precision the reactor materials and geometry must also be modeled with a high degree of precision. This paper examines how uncertainty in the reported values of boron and graphite have an effect on simulations of TREAT.

Neutronics and Transient Calculations for the Conversion of the Transient Reactor Rest Facility (TREAT)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kontogeorgakos, Dimitrios C.; Connaway, Heather M.; Papadias, Dionissios D.

2015-01-01

The Transient Reactor Test Facility (TREAT) is a graphite-reflected, graphitemoderated, and air-cooled reactor fueled with 93.1% enriched UO2 particles dispersed in graphite, with a carbon-to-235U ratio of ~10000:1. TREAT was used to simulate accident conditions by subjecting fuel test samples placed at the center of the core to high energy transient pulses. The transient pulse production is based on the core’s selflimiting nature due to the negative reactivity feedback provided by the fuel graphite as the core temperature rises. The analysis of the conversion of TREAT to low enriched uranium (LEU) is currently underway. This paper presents the analytical methodsmore » used to calculate the transient performance of TREAT in terms of power pulse production and resulting peak core temperatures. The validation of the HEU neutronics TREAT model, the calculation of the temperature distribution and the temperature reactivity feedback as well as the number of fissions generated inside fuel test samples are discussed.« less

Advanced Na-NiCl2 Battery Using Nickel-Coated Graphite with Core-Shell Microarchitecture.

PubMed

Chang, Hee-Jung; Canfield, Nathan L; Jung, Keeyoung; Sprenkle, Vincent L; Li, Guosheng

2017-04-05

Stationary electric energy storage devices (rechargeable batteries) have gained increasing prominence due to great market needs, such as smoothing the fluctuation of renewable energy resources and supporting the reliability of the electric grid. With regard to raw materials availability, sodium-based batteries are better positioned than lithium batteries due to the abundant resource of sodium in Earth's crust. However, the sodium-nickel chloride (Na-NiCl 2 ) battery, one of the most attractive stationary battery technologies, is hindered from further market penetration by its high material cost (Ni cost) and fast material degradation at its high operating temperature. Here, we demonstrate the design of a core-shell microarchitecture, nickel-coated graphite, with a graphite core to maintain electrochemically active surface area and structural integrity of the electron percolation pathway while using 40% less Ni than conventional Na-NiCl 2 batteries. An initial energy density of 133 Wh/kg (at ∼C/4) and energy efficiency of 94% are achieved at an intermediate temperature of 190 °C.

Modelling deformation and fracture of Gilsocarbon graphite subject to service environments

NASA Astrophysics Data System (ADS)

Šavija, Branko; Smith, Gillian E.; Heard, Peter J.; Sarakinou, Eleni; Darnbrough, James E.; Hallam, Keith R.; Schlangen, Erik; Flewitt, Peter E. J.

2018-02-01

Commercial graphites are used for a wide range of applications. For example, Gilsocarbon graphite is used within the reactor core of advanced gas-cooled reactors (AGRs, UK) as a moderator. In service, the mechanical properties of the graphite are changed as a result of neutron irradiation induced defects and porosity arising from radiolytic oxidation. In this paper, we discuss measurements undertaken of mechanical properties at the micro-length-scale for virgin and irradiated graphite. These data provide the necessary inputs to an experimentally-informed model that predicts the deformation and fracture properties of Gilsocarbon graphite at the centimetre length-scale, which is commensurate with laboratory test specimen data. The model predictions provide an improved understanding of how the mechanical properties and fracture characteristics of this type of graphite change as a result of exposure to the reactor service environment.

SIMPLIFIED SODIUM GRAPHITE REACTOR SYSTEM

DOEpatents

Dickinson, R.W.

1963-03-01

This patent relates to a nuclear power reactor comprising a reactor vessel, shielding means positioned at the top of said vessel, means sealing said reactor vessel to said shielding means, said vessel containing a quantity of sodium, a core tank, unclad graphite moderator disposed in said tank, means including a plurality of process tubes traversing said tank for isolating said graphite from said sodium, fuel elements positioned in said process tubes, said core tank being supported in spaced relation to the walls and bottom of said reactor vessel and below the level of said sodium, neutron shielding means positioned adjacent said core tank between said core tank and the walls of said vessel, said neutron shielding means defining an annuiar volume adjacent the inside wall of said reactor vessel, inlet plenum means below said core tank for providing a passage between said annular volume and said process tubes, heat exchanger means removably supported from the first-named shielding means and positioned in said annular volume, and means for circulating said sodium over said neutron shielding means down through said heat exchanger, across said inlet plenum and upward through said process tubes, said last-named means including electromagnetic pumps located outside said vessel and supported on said vessel wall between said heat exchanger means and said inlet plenum means. (AEC)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gao, J.X.; Wei, B.Q.; Li, D.D.

The evolution of microstructure in bainite during graphitization annealing at 680 °C of Jominy-quenched bars of an Al-Si bearing medium carbon (0.4C wt%) steel has been studied and compared with that in martensite by using light, scanning and transmission electron microscopy. The results show that the graphitization process in bainite is different from that in martensite in many aspects such as the initial carbon state, the behavior of cementite, the nucleation-growth feature and kinetics of formation of graphite spheroids during graphitization annealing, and the shape, size and distribution of these graphite spheroids. The fact that the graphitization in bainite canmore » produce more homogeneous graphite spheroids with more spherical shape and finer size in a shorter annealing time without the help of preexisting coring particles implies that bainite should be a better starting structure than martensite for making graphitic steel. - Highlights: • This article presents a microstructural characterization of formation of graphite spheroids in bainite. • Nucleation and growth characteristics of graphite spheroids formed in bainite and martensite are compared. • Bainite should be a better starting structure for making graphitic steel as results show.« less

Porous mesocarbon microbeads with graphitic shells: constructing a high-rate, high-capacity cathode for hybrid supercapacitor

PubMed Central

Lei, Yu; Huang, Zheng-Hong; Yang, Ying; Shen, Wanci; Zheng, Yongping; Sun, Hongyu; Kang, Feiyu

2013-01-01

Li4Ti5O12/activated carbon hybrid supercapacitor can combine the advantages of both lithium-ion battery and supercapacitor, which may meet the requirements for developing high-performance hybrid electric vehicles. Here we proposed a novel “core-shell” porous graphitic carbon (PGC) to replace conventional activated carbon for achieving excellent cell performance. In this PGC structure made from mesocarbon microbead (MCMB), the inner core is composed of porous amorphous carbon, while the outer shell is graphitic carbon. The abundant porosity and the high surface area not only offer sufficient reaction sites to store electrical charge physically, but also can accelerate the liquid electrolyte to penetrate the electrode and the ions to reach the reacting sites. Meanwhile, the outer graphitic shells of the porous carbon microbeads contribute to a conductive network which will remarkably facilitate the electron transportation, and thus can be used to construct a high-rate, high-capacity cathode for hybrid supercapacitor, especially at high current densities. PMID:23963328

Compression of Composite Materials: A Review,

DTIC Science & Technology

1987-11-01

epoxy tension face, . and a plexiglass core under the specimen gage-section. A Kevlar /glass phenolic hybrid composite system was evaluated in the...epoxy [0116 specimens, S2/SP-250 7 glass/epoxy [0/±45/9012s specimens, Kevlar 285 weave/Cycom 4143 Aramid/epoxy specimens, unidirectional FP alumina...bundles tested erc- E-glass, T300 graphite, T700 graphite, P75 graphite, Kevlar 49, and FP alumina. " -1. They observed that bundle failure

Correlated NanoSIMS, TEM, and XANES Studies of Presolar Grains

NASA Astrophysics Data System (ADS)

Groopman, Evan Edward

The objective of this thesis is to describe the correlated study of individual presolar grains via Nano-scale Secondary Ion Mass Spectrometry (NanoSIMS), Transmission Electron Microscopy (TEM), and Scanning Transmission X-ray Microscopy (STXM) utilizing X-ray Absorption Near Edge Structure (XANES), with a focus on connecting these correlated laboratory studies to astrophysical phenomena. The correlated isotopic, chemical, and microstructural studies of individual presolar grains provide the most detailed description of their formation environments, and help to inform astrophysical models and observations of stellar objects. As a part of this thesis I have developed and improved upon laboratory techniques for micromanipulating presolar grains and embedding them in resin for ultramicrotomy after NanoSIMS analyses and prior to TEM characterization. The new methods have yielded a 100% success rate and allow for the specific correlation of microstructural and isotopic properties of individual grains. Knowing these properties allows for inferences to be made regarding the condensation sequences and the origins of the stellar material that condensed to form these grains. NanoSIMS studies of ultramicrotomed sections of presolar graphite grains have revealed complex isotopic heterogeneities that appear to be primary products of the grains' formation environments and not secondary processing during the grains' lifetimes. Correlated excesses in 15N and 18O were identified as being carried by TiC subgrains within presolar graphite grains from supernovae (SNe). These spatially-correlated isotopic anomalies pinpoint the origin of the material that formed these grains: the inner He/C zone. Complex microstructures and isotopic heterogeneities also provide evidence for mixing in globular SN ejecta, which is corroborated by models and telescopic observations. In addition to these significant isotopic discoveries, I have also observed the first reported nanocrystalline core surrounded by turbostratic graphite within a low-density SN graphite grain. Nanocrystalline cores consisting of randomly-oriented 2-4 nm sheets of graphene and surrounded by concentric shells of graphite have been observed in high-density presolar graphite grains from Asymptotic Giant Branch stars, whose grains are typically microstructurally distinct from SN graphite grains. These vastly different stellar environments briefly formed similar nanocrystalline structures before diverging in the structure of their mantling graphite to be typical of AGB and SN grains. While relatively few correlated NanoSIMS and TEM studies have been performed previously, which this research thesis aims to expand, my collaborators and I also endeavored to add a third correlated technique, STXM/XANES, which had previously not been applied to presolar grains. XANES allows for the investigation of molecular bonds, which we used to help infer physical and chemical properties of stellar ejecta. I investigated the C K-edge and Ti L-edge of molecular bonds in both presolar graphite grains and their TiC subgrains. The presolar graphite grains, while overwhelmingly composed of aromatic C molecules, host a wide variety of minor organic molecules. Considering the large isotopic anomalies in the grains, these minor components are not likely due to contamination. I also investigated the valence state of Ti in Ti-rich subgrains and plan to work towards illuminating the effect that V in solid solution has upon the TiC bonds.

The 737 graphite composite flight spoiler flight service evaluation

NASA Technical Reports Server (NTRS)

Coggeshall, R. L.

1982-01-01

A flight service report was prepared which covers the flight service experience of 111 graphite epoxy spoilers on 737 transport aircraft and related ground based environmental exposure of graphite epoxy material specimens. Spoilers were installed on 28 aircraft representing seven major airlines operating throughout the world. Tests of removed spoilers after the seventh year of service continue to indicate modest changes in composite strength properties. Two spoilers were tested, one with 6 and one with 7 years of service, and both had residual strengths that fall within the original static strength scatter band. Both these units had typical service included discrepancies when tested. Based on visual, ultrasonic, and destructive inspection there continues to be no evidence of moisture migration into the honeycomb core and no core corrosion in the deployed units.

Supernova graphite in the NanoSIMS: Carbon, oxygen and titanium isotopic compositions of a spherule and its TiC sub-components

NASA Astrophysics Data System (ADS)

Stadermann, F. J.; Croat, T. K.; Bernatowicz, T. J.; Amari, S.; Messenger, S.; Walker, R. M.; Zinner, E.

2005-01-01

Presolar graphite spherules from the Murchison low-density separate KE3 contain a large number of internal TiC crystals that range in size from 15 to 500 nm. We have studied one such graphite grain in great detail by successive analyses with SEM, ims3f SIMS, TEM and NanoSIMS. Isotopic measurements of the 'bulk' particle in the ims3f indicate a supernova origin for this graphite spherule. The NanoSIMS measurements of C, N, O and Ti isotopes were performed directly on TEM ultramicrotome sections of the spherule, allowing correlated studies of the isotopic and mineralogical properties of the graphite grain and its internal crystals. We found isotopic gradients in 12C/ 13C and 16O/ 18O from the core of the graphite spherule to its perimeter, with the most anomalous compositions being present in the center. These gradients may be the result of isotopic exchange with isotopically normal material, either in the laboratory or during the particle's history. No similar isotopic gradients were found in the 16O/ 17O and 14N/ 15N ratios, which are normal within analytical uncertainty throughout the graphite spherule. Due to an unusually high O signal, internal TiC crystals were easily located during NanoSIMS imaging measurements. It was thus possible to determine isotopic compositions of several internal TiC grains independent of the surrounding graphite matrix. These TiC crystals are significantly more anomalous in their O isotopes than the graphite, with 16O/ 18O ratios ranging from 14 to 250 (compared to a terrestrial value of 499). Even the most centrally located TiC grains show significant variations in their O isotopic compositions from crystal to crystal. Measurement of the Ti isotopes in three TiC grains found no variations among them and no large differences between the compositions of the different crystals and the 'bulk' graphite spherule. However, the same three TiC crystals vary by a factor of 3 in their 16O/ 18O ratios. It is not clear in what form the O is associated with the TiC grains and whether it is cogenetic or the result of surface reactions on the TiC grains before they accreted onto the growing graphite spherule. The presence of 44Ca from short-lived 44Ti (t 1/2 = 60y) in one of the TiC subgrains confirms the identification of this graphite spherule as a supernova condensate.

Design and evaluation of artificial cornea with core-skirt design using polyhydroxyethyl methacrylate and graphite.

PubMed

Sinha, Mukty; Gupte, Tanvi

2017-06-10

Artificial cornea is the effective treatment option for corneal blindness. One of the challenges with the artificial cornea is limited, or no tissue integration necessitates reimplantation due to necrosis or corneal melting. We propose here a new formulation approach for core-skirt incorporating graphite in the outer skirt region to improve cell adhesion. Hydroxyethyl methacrylate (HEMA) and ethylene glycol dimethacrylate were procured from Sigma-Aldrich. Polyhydroxyethyl methacrylate (PHEMA) was synthesized by free radical polymerization of HEMA. PHEMA hydrogel core with graphite incorporated skirt was developed with the help of mould and spacer. Pores were introduced into the skirt by salt leaching technique using sodium chloride as porogen. The porous skirt was improved for its aesthetic appeal of black colour and mechanical strength to sustain intraocular pressure by incorporating graphite. The material properties of the newly developed design were evaluated in terms of wetting behaviour, mechanical strength, water vapour permeability, degradation profile and cell adhesion. The polymerization of HEMA was confirmed by thin layer chromatography and FTIR. Water content of the polymeric film was optimized at 50% where maximum transparency with required refractive index of 1.4 was obtained. The concentration of salt vital for the essential porosity was also optimized using optical microscopy and scanning electron microscopy. Other properties, namely mechanical strength, water vapour transmission rate and degradation behaviour, showed that the developed design is suitable for ocular applications. Furthermore, cell adhesion study confirmed tissue adhesion in the skirt region but absent in the core. The core-skirt design may offer an efficient cornea replacement alternative with enhanced tissue integration in addition to desired mechanical behaviour with a clear and aesthetic vision.

Facile Synthesis of Pre-Doping Lithium-Ion Into Nitrogen-Doped Graphite Negative Electrode for Lithium-Ion Capacitor.

PubMed

Lee, Seul-Yi; Kim, Ji-Il; Rhee, Kyong Yop; Park, Soo-Jin

2015-09-01

Nitrogen-doped graphite, prepared via the thermal decomposition of melamine into a carbon matrix for use as the negative electrode in lithium-ion capacitors (LICs), was evaluated by electrochemical measurements. Furthermore, in order to study the performance of pre-doped lithium components as a function of nitrogen-doped material, the pre-doped lithium graphite was allowed to react with a lithium salt solution. The results showed that the nitrogen functional groups in the graphite largely influenced the pre-doped lithium components, thereby contributing to the discharge capacity and cycling performance. We confirmed that the large initial irreversible capacity could be significantly decreased by using pre-doped lithium components obtained through the nitrogen-doping method.

Production of an impermeable composite of irradiated graphite and glass by hot isostatic pressing as a long term leach resistant waste form

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fachinger, Johannes; Muller, Walter; Marsat, Eric

2013-07-01

Around 250,000 tons of irradiated graphite (i-graphite) exists worldwide and can be considered as a current waste or future waste stream. The largest national i-graphite inventory is located in UK (∼ 100,000 tons) with significant quantities also in Russia and France [5]. Most of the i-graphite remains in the cores of shutdown nuclear reactors including the MAGNOX type in UK and the UNGG in France. Whilst there are still operational power reactors with graphite cores, such as the Russian RBMKs and the AGRs in UK, all of them will reach their end of life during the next two decades. Themore » most common reference waste management option of i-graphite is a wet or dry retrieval of the graphite blocks from the reactor core and the grouting of these blocks in a container without further conditioning. This produces large waste package volumes because the encapsulation capacity of the grout is limited and large cavities in the graphite blocks could reduce the packing densities. Packing densities from 0.5 to 1 tons per cubic meter have been assumed for grouting solutions. Furthermore the grout is permeable. This could over time allow the penetration of aqueous phases into the waste block and a potential dissolution and release of radionuclides. As a result particularly highly soluble radionuclides may not be retained by the grout. Vitrification could present an alternative, however a similar waste package volume increase may be expected since the encapsulation capacity of glass is potentially similar to or worse than that of grout. FNAG has developed a process for the production of a graphite-glass composite material called Impermeable Graphite Matrix (IGM) [3]. This process is also applicable to irradiated graphite which allows the manufacturing of an impermeable material without volume increase. Crushed i-graphite is mixed with 20 vol.% of glass and then pressed under vacuum at an elevated temperature in an axial hot vacuum press (HVP). The obtained product has zero or negligible porosity and a water impermeable structure. Structural analysis shows that the glass in the composite has replaced the pores in the graphite structure. The typical pore volume of a graphite material is in the range of 20 vol.%. Therefore no volume increase will occur in comparison with the former graphite material. This IGM material will allow the encapsulation of graphite with package densities larger than 1.5 ton per cubic meter. Therefore a huge volume saving can be achieved by such an alternative encapsulation method. Disposal performance is also enhanced since little or no leaching of radionuclides is observed due to the impermeability of the material NNL and FNAG have proved that IGM can be produced by hot isostatic pressing (HIP) which has several advantages for radioactive materials over the HVP process. - The sealed HIP container avoids the release of any radionuclides. - The outside of the waste package is not contaminated. - The HIP process time is shorter than the HVP process time. The isostatic press avoids anisotropic density distributions. - Simple filling of the HIP container has advantages over the filling of an axial die. (authors)« less

Divertor scenario development for NSTX Upgrade

NASA Astrophysics Data System (ADS)

Soukhanovskii, V. A.; McLean, A. G.; Meier, E. T.; Rognlien, T. D.; Ryutov, D. D.; Bell, R. E.; Diallo, A.; Gerhardt, S. P.; Kaita, R.; Kolemen, E.; Leblanc, B. P.; Menard, J. E.; Podesta, M.; Scotti, F.

2012-10-01

In the NSTX-U tokamak, initial plans for divertor plasma-facing components (PFCs) include lithium and boron coated graphite, with a staged transition to molybdenum. Steady-state peak divertor heat fluxes are projected to reach 20-30 MW/m^2 in 2 MA, 12 MW NBI-heated discharges of up to 5 s duration, thus challenging PFC thermal limits. Based on the recent NSTX divertor experiments and modeling with edge transport code UEDGE, a favorable basis for divertor power handling in NSTX-U is developed. The snowflake divertor geometry and feedback-controlled divertor impurity seeding applied to the lower and upper divertors are presently envisioned. In the NSTX snowflake experiments with lithium-coated graphite PFCs, the peak divertor heat fluxes from Type I ELMs and between ELMs were significantly reduced due to geometry effects, increased volumetric losses and null-point convective redistribution between strike points. H-mode core confinement was maintained at H98(y,2)<=1 albeit the radiative detachment. Additional CD4 seeding demonstrated potential for a further increase of divertor radiation.

The 737 graphite composite flight spoiler flight service evaluation

NASA Technical Reports Server (NTRS)

Stoecklin, R. L.

1977-01-01

The flight service experience of 110 graphite epoxy spoilers on 737 transport aircraft was reviewed as well as ground based environmental exposure of graphite epoxy material specimens for the period from April 1976 through April 1977. Several spoilers were installed on each of 27 aircraft representing seven major airlines operating throughout the world. A flight service evaluation program of at least 5 years is under way. As of April 30, 1977, a total of 766,938 spoiler flight hours and 1,168,090 spoiler landings were accumulated by the fleet. Based on visual ultrasonic, and destructive testing, there was no evidence of moisture migration into the honeycomb core and no core corrosion. Tests of removed spoilers and of ground based exposure specimens after the third year of service continue to indicate modest changes in composite strength properties.

Development of fuel cell bipolar plates from graphite filled wet-lay thermoplastic composite materials

NASA Astrophysics Data System (ADS)

Huang, Jianhua; Baird, Donald G.; McGrath, James E.

A method with the potential to produce economical bipolar plates with high electrical conductivity and mechanical properties is described. Thermoplastic composite materials consisting of graphite particles, thermoplastic fibers and glass or carbon fibers are generated by means of a wet-lay (paper-making) process to yield highly formable sheets. The sheets are then stacked and compression molded to form bipolar plates with gas flow channels. Poly(phenylene sulfide) (PPS) based wet-lay composite plates have in-plane conductivity of 200-300 S cm -1, tensile strength of 57 MPa, flexural strength of 96 MPa and impact strength (unnotched) of 81 J m -1 (1.5 ft-lb in. -1). These values well exceed industrial as well as Department of Energy requirements or targets and have never been reached before for composite bipolar plates. The use of wet-lay sheets also makes it possible to choose different components including polymer, graphite particle and reinforcement for the core and outer layers of the plate, respectively, to optimize the properties and/or reduce the cost of the plate. The through-plane conductivity (around 20 S cm -1) and half-cell resistance of the bipolar plate indicate that the through-plane conductivity of the material needs some improvement.

One-Pot Exfoliation of Graphite and Synthesis of Nanographene/Dimesitylporphyrin Hybrids

PubMed Central

Bernal, M. Mar; Pérez, Emilio M.

2015-01-01

A simple one-pot process to exfoliate graphite and synthesize nanographene-dimesitylporphyrin hybrids has been developed. Despite the bulky mesityl groups, which are expected to hinder the efficient π–π stacking between the porphyrin core and graphene, the liquid-phase exfoliation of graphite is significantly favored by the presence of the porphyrins. Metallation of the porphyrin further enhances this effect. The resulting graphene/porphyrin hybrids were characterized by spectroscopy (UV-visible, fluorescence, and Raman) and microscopy (STEM, scanning transmission electron microscopy). PMID:25984598

Laser ablation of a silicon target in chloroform: formation of multilayer graphite nanostructures

NASA Astrophysics Data System (ADS)

Abderrafi, Kamal; García-Calzada, Raúl; Sanchez-Royo, Juan F.; Chirvony, Vladimir S.; Agouram, Saïd; Abargues, Rafael; Ibáñez, Rafael; Martínez-Pastor, Juan P.

2013-04-01

With the use of high-resolution transmission electron microscopy, selected area electron diffraction and x-ray photoelectron spectroscopy methods of analysis we show that the laser ablation of a Si target in chloroform (CHCl3) by nanosecond UV pulses (40 ns, 355 nm) results in the formation of about 50-80 nm core-shell nanoparticles with a polycrystalline core composed of small (5-10 nm) Si and SiC mono-crystallites, the core being coated by several layers of carbon with the structure of graphite (the shell). In addition, free carbon multilayer nanostructures (carbon nano-onions) are also found in the suspension. On the basis of a comparison with similar laser ablation experiments implemented in carbon tetrachloride (CCl4), where only bare (uncoated) Si nanoparticles are produced, we suggest that a chemical (solvent decomposition giving rise to highly reactive CH-containing radicals) rather than a physical (solvent atomization followed by carbon nanostructure formation) mechanism is responsible for the formation of graphitic shells. The silicon carbonization process found for the case of laser ablation in chloroform may be promising for silicon surface protection and functionalization.

Nondestructive evaluation of nuclear-grade graphite

NASA Astrophysics Data System (ADS)

Kunerth, D. C.; McJunkin, T. R.

2012-05-01

The material of choice for the core of the high-temperature gas-cooled reactors being developed by the U.S. Department of Energy's Next Generation Nuclear Plant Program is graphite. Graphite is a composite material whose properties are highly dependent on the base material and manufacturing methods. In addition to the material variations intrinsic to the manufacturing process, graphite will also undergo changes in material properties resulting from radiation damage and possible oxidation within the reactor. Idaho National Laboratory is presently evaluating the viability of conventional nondestructive evaluation techniques to characterize the material variations inherent to manufacturing and in-service degradation. Approaches of interest include x-ray radiography, eddy currents, and ultrasonics.

Gas-cooled reactor programs. High-temperature gas-cooled reactor technology development program. Annual progress report, December 31, 1983

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kasten, P.R.; Rittenhouse, P.L.; Bartine, D.E.

1984-06-01

ORNL continues to make significant contributions to the national program. In the HTR fuels area, we are providing detailed statistical information on the fission product retention performance of irradiated fuel. Our studies are also providing basic data on the mechanical, physical, and chemical behavior of HTR materials, including metals, ceramics, graphite, and concrete. The ORNL has an important role in the development of improved HTR graphites and in the specification of criteria that need to be met by commercial products. We are also developing improved reactor physics design methods. Our work in component development and testing centers in the Componentmore » Flow Test Loop (CFTL), which is being used to evaluate the performance of the HTR core support structure. Other work includes experimental evaluation of the shielding effectiveness of the lower portions of an HTR core. This evaluation is being performed at the ORNL Tower Shielding Facility. Researchers at ORNL are developing welding techniques for attaching steam generator tubing to the tubesheets and are testing ceramic pads on which the core posts rest. They are also performing extensive testing of aggregate materials obtained from potential HTR site areas for possible use in prestressed concrete reactor vessels. During the past year we continued to serve as a peer reviewer of small modular reactor designs being developed by GA and GE with balance-of-plant layouts being developed by Bechtel Group, Inc. We have also evaluated the national need for developing HTRs with emphasis on the longer term applications of the HTRs to fossil conversion processes.« less

Effect of Damage on Strength and Durability

DTIC Science & Technology

2010-05-01

sheets and different core materials. The HRP core has a phenolic resin matrix, the NP core has nylon modified phenolic base resin matrix and TPC core...core are 25% to 65% higher than those of NP or TPC cores. The phenolic resin of the HRP makes core stiff and brittle, resulting in cracking on impact...characteristics of graphite laminates can be improved by inserting glass or Kevlar fibers to form a hybrid laminate system. However, since glass and

REFLECTOR FOR NEUTRONIC REACTORS

DOEpatents

Fraas, A.P.

1963-08-01

A reflector for nuclear reactors that comprises an assembly of closely packed graphite rods disposed with their major axes substantially perpendicular to the interface between the reactor core and the reflector is described. Each graphite rod is round in transverse cross section at (at least) its interface end and is provided, at that end, with a coaxial, inwardly tapering hole. (AEC)

Kinetics of Chronic Oxidation of NBG-17 Nuclear Graphite by Water Vapor

DOE Office of Scientific and Technical Information (OSTI.GOV)

Contescu, Cristian I; Burchell, Timothy D; Mee, Robert

2015-05-01

This report presents the results of kinetic measurements during accelerated oxidation tests of NBG-17 nuclear graphite by low concentration of water vapor and hydrogen in ultra-high purity helium. The objective is to determine the parameters in the Langmuir-Hinshelwood (L-H) equation describing the oxidation kinetics of nuclear graphite in the helium coolant of high temperature gas-cooled reactors (HTGR). Although the helium coolant chemistry is strictly controlled during normal operating conditions, trace amounts of moisture (predictably < 0.2 ppm) cannot be avoided. Prolonged exposure of graphite components to water vapor at high temperature will cause very slow (chronic) oxidation over the lifetimemore » of graphite components. This behavior must be understood and predicted for the design and safe operation of gas-cooled nuclear reactors. The results reported here show that, in general, oxidation by water of graphite NBG-17 obeys the L-H mechanism, previously documented for other graphite grades. However, the characteristic kinetic parameters that best describe oxidation rates measured for graphite NBG-17 are different than those reported previously for grades H-451 (General Atomics, 1978) and PCEA (ORNL, 2013). In some specific conditions, certain deviations from the generally accepted L-H model were observed for graphite NBG-17. This graphite is manufactured in Germany by SGL Carbon Group and is a possible candidate for the fuel elements and reflector blocks of HTGR.« less

HTR-PROTEUS PEBBLE BED EXPERIMENTAL PROGRAM CORE 4: RANDOM PACKING WITH A 1:1 MODERATOR-TO-FUEL PEBBLE RATIO

DOE Office of Scientific and Technical Information (OSTI.GOV)

John D. Bess; Leland M. Montierth

2013-03-01

In its deployment as a pebble bed reactor (PBR) critical facility from 1992 to 1996, the PROTEUS facility was designated as HTR-PROTEUS. This experimental program was performed as part of an International Atomic Energy Agency (IAEA) Coordinated Research Project (CRP) on the Validation of Safety Related Physics Calculations for Low Enriched HTGRs. Within this project, critical experiments were conducted for graphite moderated LEU systems to determine core reactivity, flux and power profiles, reaction-rate ratios, the worth of control rods, both in-core and reflector based, the worth of burnable poisons, kinetic parameters, and the effects of moisture ingress on these parameters.more » One benchmark experiment was evaluated in this report: Core 4. Core 4 represents the only configuration with random pebble packing in the HTR-PROTEUS series of experiments, and has a moderator-to-fuel pebble ratio of 1:1. Three random configurations were performed. The initial configuration, Core 4.1, was rejected because the method for pebble loading, separate delivery tubes for the moderator and fuel pebbles, may not have been completely random; this core loading was rejected by the experimenters. Cores 4.2 and 4.3 were loaded using a single delivery tube, eliminating the possibility for systematic ordering effects. The second and third cores differed slightly in the quantity of pebbles loaded (40 each of moderator and fuel pebbles), stacked height of the pebbles in the core cavity (0.02 m), withdrawn distance of the stainless steel control rods (20 mm), and withdrawn distance of the autorod (30 mm). The 34 coolant channels in the upper axial reflector and the 33 coolant channels in the lower axial reflector were open. Additionally, the axial graphite fillers used in all other HTR-PROTEUS configurations to create a 12-sided core cavity were not used in the randomly packed cores. Instead, graphite fillers were placed on the cavity floor, creating a funnel-like base, to discourage ordering effects during pebble loading. Core 4 was determined to be acceptable benchmark experiment.« less

HTR-proteus pebble bed experimental program core 4: random packing with a 1:1 moderator-to-fuel pebble ratio

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bess, John D.; Montierth, Leland M.; Sterbentz, James W.

2014-03-01

In its deployment as a pebble bed reactor (PBR) critical facility from 1992 to 1996, the PROTEUS facility was designated as HTR-PROTEUS. This experimental program was performed as part of an International Atomic Energy Agency (IAEA) Coordinated Research Project (CRP) on the Validation of Safety Related Physics Calculations for Low Enriched HTGRs. Within this project, critical experiments were conducted for graphite moderated LEU systems to determine core reactivity, flux and power profiles, reaction-rate ratios, the worth of control rods, both in-core and reflector based, the worth of burnable poisons, kinetic parameters, and the effects of moisture ingress on these parameters.more » One benchmark experiment was evaluated in this report: Core 4. Core 4 represents the only configuration with random pebble packing in the HTR-PROTEUS series of experiments, and has a moderator-to-fuel pebble ratio of 1:1. Three random configurations were performed. The initial configuration, Core 4.1, was rejected because the method for pebble loading, separate delivery tubes for the moderator and fuel pebbles, may not have been completely random; this core loading was rejected by the experimenters. Cores 4.2 and 4.3 were loaded using a single delivery tube, eliminating the possibility for systematic ordering effects. The second and third cores differed slightly in the quantity of pebbles loaded (40 each of moderator and fuel pebbles), stacked height of the pebbles in the core cavity (0.02 m), withdrawn distance of the stainless steel control rods (20 mm), and withdrawn distance of the autorod (30 mm). The 34 coolant channels in the upper axial reflector and the 33 coolant channels in the lower axial reflector were open. Additionally, the axial graphite fillers used in all other HTR-PROTEUS configurations to create a 12-sided core cavity were not used in the randomly packed cores. Instead, graphite fillers were placed on the cavity floor, creating a funnel-like base, to discourage ordering effects during pebble loading. Core 4 was determined to be acceptable benchmark experiment.« less

Casting of weldable graphite/magnesium metal matrix composites with built-in metallic inserts

NASA Technical Reports Server (NTRS)

Lee, Jonathan A.; Kashalikar, Uday; Majkowski, Patricia

1994-01-01

Technology innovations directed at the advanced development of a potentially low cost and weldable graphite/magnesium metal matrix composites (MMC) through near net shape pressure casting are described. These MMC components uniquely have built-in metallic inserts to provide an innovative approach for joining or connecting other MMC components through conventional joining techniques such as welding, brazing, mechanical fasteners, etc. Moreover, the metallic inserts trapped within the MMC components can be made to transfer the imposed load efficiently to the continuous graphite fiber reinforcement thus producing stronger, stiffer, and more reliable MMC components. The use of low pressure near net shape casting is economical compared to other MMC fabrication processes. These castable and potentially weldable MMC components can provide great payoffs in terms of high strength, high stiffness, low thermal expansion, lightweight, and easily joinable MMC components for several future NASA space structural, industrial, and commercial applications.

FUEL ASSAY REACTOR

DOEpatents

Spinrad, B.I.; Sandmeier, H.A.; Martens, F.H.

1962-12-25

A reactor having maximum sensitivity to perturbations is described comprising a core consisting of a horizontally disposed, rectangular, annular fuel zone containing enriched uranium dioxide dispersed in graphite, the concentration of uranium dioxide increasing from the outside to the inside of the fuel zone, an internal reflector of graphite containing an axial test opening disposed within the fuel zone, an external graphite reflector, means for changing the neutron spectrum in the test opening, and means for measuring perturbations in the neutron flux caused by the introduction of different fuel elements into the test opening. (AEC)

Ti-doped isotropic graphite: A promising armour material for plasma-facing components

NASA Astrophysics Data System (ADS)

García-Rosales, C.; López-Galilea, I.; Ordás, N.; Adelhelm, C.; Balden, M.; Pintsuk, G.; Grattarola, M.; Gualco, C.

2009-04-01

Finely dispersed Ti-doped isotropic graphites with 4 at.% Ti have been manufactured using synthetic mesophase pitch 'AR' as raw material. These new materials show a thermal conductivity at room temperature of ˜200 W/mK and flexural strength close to 100 MPa. Measurement of the total erosion yield by deuterium bombardment at ion energies and sample temperatures for which pure carbon shows maximum values, resulted in a reduction of at least a factor of 4, mainly due to dopant enrichment at the surface caused by preferential erosion of carbon. In addition, ITER relevant thermal shock loads were applied with an energetic electron beam at the JUDITH facility. The results demonstrated a significantly improved performance of Ti-doped graphite compared to pure graphite. Finally, Ti-doped graphite was successfully brazed to a CuCrZr block using a Mo interlayer. These results let assume that Ti-doped graphite can be a promising armour material for divertor plasma-facing components.

Radioisotopic heat source

DOEpatents

Sayell, E.H.

1973-10-23

A radioisotopic heat source is described which includes a core of heat productive, radioisotopic material, an impact resistant layer of graphite surrounding said core, and a shell of iridium metal intermediate the core and the impact layer. The source may also include a compliant mat of iridium between the core and the iridium shell, as well as an outer covering of iridium metal about the entire heat source. (Official Gazette)

Engineering Analysis Studies for Preliminary Design of Lightweight Cryogenic Hydrogen Tanks in UAV Applications

NASA Technical Reports Server (NTRS)

Sullivan, Roy M.; Palko, Joseph L.; Tornabene, Robert T.; Bednarcyk, Brett A.; Powers, Lynn M.; Mital, Subodh K.; Smith, Lizalyn M.; Wang, Xiao-Yen J.; Hunter, James E.

2006-01-01

A series of engineering analysis studies were conducted to investigate the potential application of nanoclay-enhanced graphite/epoxy composites and polymer cross-linked silica aerogels in cryogenic hydrogen storage tank designs. This assessment focused on the application of these materials in spherical tank designs for unmanned aeronautic vehicles with mission durations of 14 days. Two cryogenic hydrogen tank design concepts were considered: a vacuum-jacketed design and a sandwiched construction with an aerogel insulating core. Analyses included thermal and structural analyses of the tank designs as well as an analysis of hydrogen diffusion to specify the material permeability requirements. The analyses also provided material property targets for the continued development of cross-linked aerogels and nanoclay-enhanced graphite/epoxy composites for cryogenic storage tank applications. The results reveal that a sandwiched construction with an aerogel core is not a viable design solution for a 14-day mission. A vacuum-jacketed design approach was shown to be far superior to an aerogel. Aerogel insulation may be feasible for shorter duration missions. The results also reveal that the application of nanoclay-enhanced graphite/epoxy should be limited to the construction of outer tanks in a vacuum-jacketed design, since a graphite/epoxy inner tank does not provide a significant weight savings over aluminum and since the ability of nanoclay-enhanced graphite/epoxy to limit hydrogen permeation is still in question.

Flight service evaluation of an advanced composite empennage component on commercial transport aircraft

NASA Technical Reports Server (NTRS)

1976-01-01

The development and flight evaluation of an advanced composite empennage component is presented. The recommended concept for the covers is graphite-epoxy hats bonded to a graphite-epoxy skin. The hat flare-out has been eliminated, instead the hat is continuous into the joint. The recommended concept for the spars is graphite-epoxy caps and a hybrid of Kevlar-49 and graphite-epoxy in the spar web. The spar cap, spar web stiffeners for attaching the ribs, and intermediate stiffeners are planned to be fabricated as a unit. Access hole in the web will be reinforced with a donut type, zero degree graphite-epoxy wound reinforcement. The miniwich design concept in the upper three ribs originally proposed is changed to a graphite-epoxy stiffened solid laminate design concept. The recommended configuration for the lower seven ribs remains as graphite-epoxy caps with aluminum cruciform diagonals. The indicated weight saving for the current advanced composite vertical fin configuration is 20.2% including a 24 lb growth allowance. The project production cost saving is approximately 1% based on a cumulative average of 250 aircraft and including only material, production labor, and quality assurance costs.

Neutron irradiation damage of nuclear graphite studied by high-resolution transmission electron microscopy and Raman spectroscopy

NASA Astrophysics Data System (ADS)

Krishna, R.; Jones, A. N.; McDermott, L.; Marsden, B. J.

2015-12-01

Nuclear graphite components are produced from polycrystalline artificial graphite manufacture from a binder and filler coke with approximately 20% porosity. During the operational lifetime, nuclear graphite moderator components are subjected to fast neutron irradiation which contributes to the change of material and physical properties such as thermal expansion co-efficient, young's modulus and dimensional change. These changes are directly driven by irradiation-induced changes to the crystal structure as reflected through the bulk microstructure. It is therefore of critical importance that these irradiation changes and there implication on component property changes are fully understood. This work examines a range of irradiated graphite samples removed from the British Experimental Pile Zero (BEPO) reactor; a low temperature, low fluence, air-cooled Materials Test Reactor which operated in the UK. Raman spectroscopy and high-resolution transmission electron microscopy (HRTEM) have been employed to characterise the effect of increased irradiation fluence on graphite microstructure and understand low temperature irradiation damage processes. HRTEM confirms the structural damage of the crystal lattice caused by irradiation attributed to a high number of defects generation with the accumulation of dislocation interactions at nano-scale range. Irradiation-induced crystal defects, lattice parameters and crystallite size compared to virgin nuclear graphite are characterised using selected area diffraction (SAD) patterns in TEM and Raman Spectroscopy. The consolidated 'D'peak in the Raman spectra confirms the formation of in-plane point defects and reflected as disordered regions in the lattice. The reduced intensity and broadened peaks of 'G' and 'D' in the Raman and HRTEM results confirm the appearance of turbulence and disordering of the basal planes whilst maintaining their coherent layered graphite structure.

Graphitized hollow carbon spheres and yolk-structured carbon spheres fabricated by metal-catalyst-free chemical vapor deposition

DOE PAGES

Li, Xufan; Chi, Miaofang; Mahurin, Shannon Mark; ...

2016-01-18

Hard-sphere-templating method has been widely used to synthesize hollow carbon spheres (HCSs), in which the spheres were firstly coated with a carbon precursor, followed by carbonization and core removal. The obtained HCSs are generally amorphous or weakly graphitized (with the help of graphitization catalysts). In this work, we report on the fabrication of graphitized HCSs and yolk–shell Au@HCS nanostructures using a modified templating method, in which smooth, uniform graphene layers were grown on SiO 2 spheres or Au@SiO 2 nanoparticles via metal-catalyst-free chemical vapor deposition (CVD) of methane. Furthermore, our work not only provides a new method to fabricate high-quality,more » graphitized HCSs but also demonstrates a reliable approach to grow quality graphene on oxide surfaces using CVD without the presence of metal catalysts.« less

Flight service evaluation of composite helicopter components

NASA Technical Reports Server (NTRS)

Rich, M. J.; Lowry, D. W.

1983-01-01

This first interim report presents the technical background for including environmental effects in the design of helicopter composite structures, and test results after approximately two year field exposure of components and panels. Composite structural components were removed from Sikorsky S-76 helicopters commercially operated in the Gulf Coast region of Louisiana. Fatigue tests were conducted for a graphite/epoxy tail rotor spar and static test for a graphite/epoxy and Kevlar/epoxy stabilizer. Graphite/epoxy and Kevlar/epoxy panels are being exposed to the outdoor environment in Stratford, Connecticut and West Palm Beach, Florida. For this reporting period the two year panels were returned, moisture measurements taken, and strength tests conducted. Results are compared with initial type certificate strengths for components and with initial laboratory coupon tests for the exposed panels. Comparisons are also presented with predicted and measured moisture contents.

Flight service evaluation of composite helicopter components

NASA Technical Reports Server (NTRS)

Rich, M. J.; Lowry, D. W.

1982-01-01

This first interim report presents the technical background for including environmental effects in the design of helicopter composite structures, and test results after approximately two year field exposure of components and panels. Composite structural components were removed from Sikorsky S-76 helicopters commercially operated in the Gulf Coast region of Louisiana. Fatigue tests were conducted for a graphite/epoxy tail rotor spar and static test for a graphite/epoxy and Kevlar/epoxy stabilizer. Graphite/epoxy and Kevlar/epoxy panels are being exposed to the outdoor environment in Stratford, Connecticut and West Palm Beach, Florida. For this reporting period the two year panels were returned, moisture measurements taken, and strength tests conducted. Results are compared with initial type certificate strengths for components and with initial laboratory coupon tests for the exposed panels. Comparisons are also presented with predicted and measured moisture contents.

Ultrathin nitrogen-doped graphitized carbon shell encapsulating CoRu bimetallic nanoparticles for enhanced electrocatalytic hydrogen evolution.

PubMed

Xu, You; Li, Yinghao; Yin, Shuli; Yu, Hongjie; Xue, Hairong; Li, Xiaonian; Wang, Hongjing; Wang, Liang

2018-06-01

Design of highly active and cost-effective electrocatalysts is very important for the generation of hydrogen by electrochemical water-splitting. Herein, we report the fabrication of ultrathin nitrogen-doped graphitized carbon shell encapsulating CoRu bimetallic nanoparticles (CoRu@NCs) and demonstrate their promising feasibility for efficiently catalyzing the hydrogen evolution reaction (HER) over a wide pH range. The resultant CoRu@NC nanohybrids possess an alloy-carbon core-shell structure with encapsulated low-ruthenium-content CoRu bimetallic alloy nanoparticles (10-30 nm) as the core and ultrathin nitrogen-doped graphitized carbon layers (2-6 layers) as the shell. Remarkably, the optimized catalyst (CoRu@NC-2 sample) with a Ru content as low as 2.04 wt% shows superior catalytic activity and excellent durability for HER in acidic, neutral, and alkaline conditions. This work offers a new method for the design and synthesis of non-platium-based electrocatalysts for HER in all-pH.

Developments in Hollow Graphite Fiber Technology

NASA Technical Reports Server (NTRS)

Stallcup, Michael; Brantley, Lott W., Jr. (Technical Monitor)

2002-01-01

Hollow graphite fibers will be lighter than standard solid graphite fibers and, thus, will save weight in optical components. This program will optimize the processing and properties of hollow carbon fibers developed by MER and to scale-up the processing to produce sufficient fiber for fabricating a large ultra-lightweight mirror for delivery to NASA.

AIR COOLED NEUTRONIC REACTOR

DOEpatents

Fermi, E.; Szilard, L.

1958-05-27

A nuclear reactor of the air-cooled, graphite moderated type is described. The active core consists of a cubicle mass of graphite, approximately 25 feet in each dimension, having horizontal channels of square cross section extending between two of the opposite faces, a plurality of cylindrical uranium slugs disposed in end to end abutting relationship within said channels providing a space in the channels through which air may be circulated, and a cadmium control rod extending within a channel provided in the moderator. Suitable shielding is provlded around the core, as are also provided a fuel element loading and discharge means, and a means to circulate air through the coolant channels through the fuel charels to cool the reactor.

Graphitization in Carbon MEMS and Carbon NEMS

NASA Astrophysics Data System (ADS)

Sharma, Swati

Carbon MEMS (CMEMS) and Carbon NEMS (CNEMS) are an emerging class of miniaturized devices. Due to the numerous advantages such as scalable manufacturing processes, inexpensive and readily available precursor polymer materials, tunable surface properties and biocompatibility, carbon has become a preferred material for a wide variety of future sensing applications. Single suspended carbon nanowires (CNWs) integrated on CMEMS structures fabricated by electrospinning of SU8 photoresist on photolithographially patterned SU8 followed by pyrolysis are utilized for understanding the graphitization process in micro and nano carbon materials. These monolithic CNW-CMEMS structures enable the fabrication of very high aspect ratio CNWs of predefined length. The CNWs thus fabricated display core---shell structures having a graphitic shell with a glassy carbon core. The electrical conductivity of these CNWs is increased by about 100% compared to glassy carbon as a result of enhanced graphitization. We explore various tunable fabrication and pyrolysis parameters to improve graphitization in the resulting CNWs. We also suggest gas-sensing application of the thus fabricated single suspended CNW-CMEMS devices by using the CNW as a nano-hotplate for local chemical vapor deposition. In this thesis we also report on results from an optimization study of SU8 photoresist derived carbon electrodes. These electrodes were applied to the simultaneous detection of traces of Cd(II) and Pb(II) through anodic stripping voltammetry and detection limits as low as 0.7 and 0.8 microgL-1 were achieved. To further improve upon the electrochemical behavior of the carbon electrodes we elucidate a modified pyrolysis technique featuring an ultra-fast temperature ramp for obtaining bubbled porous carbon from lithographically patterned SU8. We conclude this dissertation by suggesting the possible future works on enhancing graphitization as well as on electrochemical applications

Synthesis of ultrathin nitrogen-doped graphitic carbon nanocages as advanced electrode materials for supercapacitor.

PubMed

Tan, Yueming; Xu, Chaofa; Chen, Guangxu; Liu, Zhaohui; Ma, Ming; Xie, Qingji; Zheng, Nanfeng; Yao, Shouzhuo

2013-03-01

Synthesis of nitrogen-doped carbons with large surface area, high conductivity, and suitable pore size distribution is highly desirable for high-performance supercapacitor applications. Here, we report a novel protocol for template synthesis of ultrathin nitrogen-doped graphitic carbon nanocages (CNCs) derived from polyaniline (PANI) and their excellent capacitive properties. The synthesis of CNCs involves one-pot hydrothermal synthesis of Mn3O4@PANI core-shell nanoparticles, carbonization to produce carbon coated MnO nanoparticles, and then removal of the MnO cores by acidic treatment. The CNCs prepared at an optimum carbonization temperature of 800 °C (CNCs-800) have regular frameworks, moderate graphitization, high specific surface area, good mesoporosity, and appropriate N doping. The CNCs-800 show high specific capacitance (248 F g(-1) at 1.0 A g(-1)), excellent rate capability (88% and 76% capacitance retention at 10 and 100 A g(-1), respectively), and outstanding cycling stability (~95% capacitance retention after 5000 cycles) in 6 M KOH aqueous solution. The CNCs-800 can also exhibit great pseudocapacitance in 0.5 M H2SO4 aqueous solution besides the large electrochemical double-layer capacitance. The excellent capacitance performance coupled with the facile synthesis of ultrathin nitrogen-doped graphitic CNCs indicates their great application potential in supercapacitors.

Lightweight orthotic appliances

NASA Technical Reports Server (NTRS)

Baucom, R. M.; St. Clair, T. L.

1976-01-01

Graphite-filament reinforced polymer materials are used in applications requiring high tensile strength and modulus. Superior properties of graphite composite materials permit fabrication of supports that are considerably lighter, thinner, and stiffer than conventional components.

DESIGN CHARACTERISTICS OF THE IDAHO NATIONAL LABORATORY HIGH-[TEMPERATURE GAS-COOLED TEST REACTOR

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sterbentz, James; Bayless, Paul; Strydom, Gerhard

A point design for a graphite-moderated, high-temperature, gas-cooled test reactor (HTG TR) has been developed by Idaho National Laboratory (INL) as part of a United States (U.S.) Department of Energy (DOE) initiative to explore and potentially expand the existing U.S. test reactor capabilities. This paper provides a summary of the design and its main attributes. The 200 MW HTG TR is a thermal-neutron spectrum reactor composed of hexagonal prismatic fuel and graphite reflector blocks. Twelve fuel columns (96 fuel blocks total and 6.34 m active core height) are arranged in two hexagonal rings to form a relatively compact, high-power density,more » annular core sandwiched between inner, outer, top, and bottom graphite reflectors. The HTG-TR is designed to operate at 7 MPa with a coolant inlet/outlet temperature of 325°C/650°C, and utilizes TRISO particle fuel from the DOE AGR Program with 425 ?m uranium oxycarbide (UCO) kernels and an enrichment of 15.5 wt% 235U. The primary mission of the HTG TR is material irradiation and therefore the core has been specifically designed and optimized to provide the highest possible thermal and fast neutron fluxes. The highest thermal neutron flux (3.90E+14 n/cm2s) occurs in the outer reflector, and the maximum fast flux levels (1.17E+14 n/cm2s) are produced in the central reflector column where most of the graphite has been removed. Due to high core temperatures under accident conditions, all the irradiation test facilities have been located in the inner and outer reflectors where fast flux levels decline. The core features a large number of irradiation positions with large test volumes and long test lengths, ideal for thermal neutron irradiation of large test articles. The total available test volume is more than 1100 liters. Up to four test loop facilities can be accommodated with pressure tube boundaries to isolate test articles and test fluids (e.g., liquid metal, liquid salt, light water) from the helium primary coolant system.« less

Dynamical core-hole screening in the x-ray absorption spectra of hydrogenated carbon nanotubes and graphene

NASA Astrophysics Data System (ADS)

Wessely, O.; Katsnelson, M. I.; Nilsson, A.; Nikitin, A.; Ogasawara, H.; Odelius, M.; Sanyal, B.; Eriksson, O.

2007-10-01

We have calculated the electronic structure and the x-ray absorption (XA) spectrum of a hydrogenated single graphite plane, in order to simulate recent experimental results on hydrogenated single wall carbon nanotubes (SWCNT) as well as hydrogenated graphene. We find that the presence of H induces a substantial component of sp3 bonding and as a result the π and π* components to the electronic structure vanish. We have calculated a theoretical x-ray absorption spectrum using a multiband version of the Mahan-Nozières-De Dominicis theory. By making a fitting of the XA signal of C atoms that have H attached to them and C atoms without H in the vicinity we obtain a good representation of the experimental data and we can draw the conclusion that in the experiments [A. Nikitin , Phys. Rev. Lett. 95, 225507 (2005)] some 35-50 % H have been absorbed in the SWCNT.

Status of Chronic Oxidation Studies of Graphite

DOE Office of Scientific and Technical Information (OSTI.GOV)

Contescu, Cristian I.; Mee, Robert W.

Graphite will undergo extremely slow, but continuous oxidation by traces of moisture that will be present, albeit at very low levels, in the helium coolant of HTGR. This chronic oxidation may cause degradation of mechanical strength and thermal properties of graphite components if a porous oxidation layer penetrates deep enough in the bulk of graphite components during the lifetime of the reactor. The current research on graphite chronic oxidation is motivated by the acute need to understand the behavior of each graphite grade during prolonged exposure to high temperature chemical attack by moisture. The goal is to provide the elementsmore » needed to develop predictive models for long-time oxidation behavior of graphite components in the cooling helium of HTGR. The tasks derived from this goal are: (1) Oxidation rate measurements in order to determine and validate a comprehensive kinetic model suitable for prediction of intrinsic oxidation rates as a function of temperature and oxidant gas composition; (2) Characterization of effective diffusivity of water vapor in the graphite pore system in order to account for the in-pore transport of moisture; and (3) Development and validation of a predictive model for the penetration depth of the oxidized layer, in order to assess the risk of oxidation caused damage of particular graphite grades after prolonged exposure to the environment of helium coolant in HTGR. The most important and most time consuming of these tasks is the measurement of oxidation rates in accelerated oxidation tests (but still under kinetic control) and the development of a reliable kinetic model. This report summarizes the status of chronic oxidation studies on graphite, and then focuses on model development activities, progress of kinetic measurements, validation of results, and improvement of the kinetic models. Analysis of current and past results obtained with three grades of showed that the classical Langmuir-Hinshelwood model cannot reproduce all data collected so far. Starting from here we propose a modification of the LH model to include temperature activation of graphite surface as a Boltzmann activation function. The enhanced Boltzmann-Langmuir-Hinshelwood model (BLH) was tested successfully on three grades of graphite. The model is a robust, comprehensive mathematical function that allows better fitting of experimental results spanning a wide range of temperature and partial pressures of water vapor and hydrogen. However, the model did not fit satisfactorily the data extracted from the old report on graphite H-451 oxidation by water.« less

Heterogeneous photo-Fenton processes using graphite carbon coating hollow CuFe2O4 spheres for the degradation of methylene blue

NASA Astrophysics Data System (ADS)

Guo, Xiaojun; Wang, Kebai; Li, Dai; Qin, Jiabin

2017-10-01

The novel graphite carbon coating hollow CuFe2O4 spheres were fabricated through solvothermal method and characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and Raman spectra, etc. The catalytic performance of the graphite carbon coating hollow CuFe2O4 spheres was evaluated in photo-Fenton-like degradation of methylene blue (MB) using H2O2 as a green oxidant under light irradiation (λ > 400 nm). The results demonstrated that the hollow CuFe2O4 spheres with graphite carbon coating exhibited superior catalytic activity. In the preparation process of catalyst, the addition of glucose was very important to its catalytic performance. Photoresponse analysis of the typical samples proved that CuFe2O4@graphite carbon core-shell hollow spheres possessed excellent photocurrent response and lower electrochemical impedance. In addition, a possible mechanism for photocatalytic degradation of MB had been presumed. Moreover, after five regeneration cycles, the graphite carbon coating hollow CuFe2O4 spheres still exhibited better properties.

A First Look at Graphite Grains from Orgueil: Morphology, Carbon, Nitrogen and Neon Isotopic Compositions of Individual, Chemically Separated Grains

NASA Technical Reports Server (NTRS)

Pravdivtseva, O.; Zinner, E.; Meshik, A. P.; Hohenberg, C. M.; Walker, R. W.

2004-01-01

Presolar graphite in Murchison has been extensively studied. It is characterized by a unique Ne isotopic composition, known as the Ne-E(L) component. According to studies by Huss and Lewis, the concentration of Ne-E(L) in Orgueil is about one order of magnitude higher than in Murchison, when normalized to the matrix. This could be due to a higher presolar graphite abundance in Orgueil, or due to a higher Ne-E concentrations per grain. The Ne isotopic compositions in individual presolar graphite grains from Murchison have been measured before. It was shown, that a third of the grains have detectable excesses in 22Ne, characteristic of the Ne-E(L) component. One grain in a hundred had a Ne-22 concentration two orders of magnitude higher than blank.

Making Mercury's Core with Light Elements

NASA Technical Reports Server (NTRS)

Vander Kaaden, Kathleen E.; McCubbin, Francis M.; Ross, D. Kent

2016-01-01

Recent results obtained from the MErcury Surface, Space ENvironment, GEochemistry, and Ranging spacecraft showed the surface of Mercury has low FeO abundances (less than 2 wt%) and high S abundances (approximately 4 wt%), suggesting the oxygen fugacity of Mercury's surface materials is somewhere between 3 to 7 log10 units below the IW buffer. The highly reducing nature of Mercury has resulted in a relatively thin mantle and a large core that has the potential to exhibit an exotic composition in comparison to the other terrestrial planets. This exotic composition may extend to include light elements (e.g., Si, C, S). Furthermore, has argued for a possible primary floatation crust on Mercury composed of graphite, which may require a core that is C-saturated. In order to investigate mercurian core compositions, we conducted piston cylinder experiments at 1 GPa, from 1300 C to 1700 C, using a range of starting compositions consisting of various Si-Fe metal mixtures (Si5Fe95, Si10Fe90, Si22Fe78, and Si35Fe65). All metals were loaded into graphite capsules used to ensure C-saturation during the duration of each experimental run. Our experiments show that Fe-Si metallic alloys exclude carbon relative to more Fe-rich metal. This exclusion of carbon commences within the range of 5 to 10 wt% Si. These results indicate that if Mercury has a Si-rich core (having more than approximately 5 wt% silicon), it would have saturated in carbon at low C abundances allowing for the possible formation of a graphite floatation crust as suggested by. These results have important implications for the thermal and magmatic evolution of Mercury.

6. Workers laying up the graphite core of the 105B ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

6. Workers laying up the graphite core of the 105-B file. In the lower-left can be seen a portion of the rear face of the pile, the top of its shielding wall, and the gun barrels protruding through it. The inside of the front face of the pile and its gun barrels can be seen toward the upper-right side. The angled top of the front shielding wall can be seen in the picture. All four walls were "stepped" in this manner where they joined with another wall or the ceiling to form a "labyrinth" joint, so that radiation would not have a straight route through any gaps in the joints. D-3045 - B Reactor, Richland, Benton County, WA

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ganesh, Panchapakesan; Kent, Paul R; Mochalin, Vadym N

We simulate the experimentally observed graphitization of nanodiamonds into multi-shell onion-like carbon nanostructures, also called carbon onions, at different temperatures, using reactive force fields. The simulations include long-range Coulomb and van der Waals interactions. Our results suggest that long-range interactions play a crucial role in the phase-stability and the graphitization process. Graphitization is both enthalpically and entropically driven and can hence be controlled with temperature. The outer layers of the nanodiamond have a lower kinetic barrier toward graphitization irrespective of the size of the nanodiamond and graphitize within a few-hundred picoseconds, with a large volume increase. The inner core ofmore » the nanodiamonds displays a large size-dependent kinetic barrier, and graphitizes much more slowly with abrupt jumps in the internal energy. It eventually graphitizes by releasing pressure and expands once the outer shells have graphitized. The degree of transformation at a particular temperature is thereby determined by a delicate balance between the thermal energy, long-range interactions, and the entropic/enthalpic free energy gained by graphitization. Upon full graphitization, a multi-shell carbon nanostructure appears, with a shell-shell spacing of about {approx}3.4 {angstrom} for all sizes. The shells are highly defective with predominantly five- and seven-membered rings to curve space. Larger nanodiamonds with a diameter of 4 nm can graphitize into spiral structures with a large ({approx}29-atom carbon ring) pore opening on the outermost shell. Such a large one-way channel is most attractive for a controlled insertion of molecules/ions such as Li ions, water, or ionic liquids, for increased electrochemical capacitor or battery electrode applications.« less

Organic nitrogen chemistry during low-grade metamorphism

USGS Publications Warehouse

Boudou, J.-P.; Schimmelmann, A.; Ader, M.; Mastalerz, Maria; Sebilo, M.; Gengembre, L.

2008-01-01

Most of the organic nitrogen (Norg) on Earth is disseminated in crustal sediments and rocks in the form of fossil nitrogen-containing organic matter. The chemical speciation of fossil Norg within the overall molecular structure of organic matter changes with time and heating during burial. Progressive thermal evolution of organic matter involves phases of enhanced elimination of Norg and ultimately produces graphite containing only traces of nitrogen. Long-term chemical and thermal instability makes the chemical speciation of Norg a valuable tracer to constrain the history of sub-surface metamorphism and to shed light on the subsurface biogeochemical nitrogen cycle and its participating organic and inorganic nitrogen pools. This study documents the evolutionary path of Norg speciation, transformation and elimination before and during metamorphism and advocates the use of X-ray photoelectron spectroscopy (XPS) to monitor changes in Norg speciation as a diagnostic tool for organic metamorphism. Our multidisciplinary evidence from XPS, stable isotopes, traditional quantitative coal analyses, and other analytical approaches shows that at the metamorphic onset Norg is dominantly present as pyrrolic and pyridinic nitrogen. The relative abundance of nitrogen substituting for carbon in condensed, partially aromatic systems (where N is covalently bonded to three C atoms) increases exponentially with increasing metamorphic grade, at the expense of pyridinic and pyrrolic nitrogen. At the same time, much Norg is eliminated without significant nitrogen isotope fractionation. The apparent absence of Rayleigh-type nitrogen isotopic fractionation suggests that direct thermal loss of nitrogen from an organic matrix does not serve as a major pathway for Norg elimination. Instead, we propose that hot H, O-containing fluids or some of their components gradually penetrate into the carbonaceous matrix and eliminate Norg along a progressing reaction front, without causing nitrogen isotope fractionation in the residual Norg in the unreacted core of the carbonaceous matrix. Before the reaction front can reach the core, an increasing part of core Norg chemically stabilizes in the form of nitrogen atoms substituting for carbon in condensed, partially aromatic systems forming graphite-like structural domains with delocalized ??-electron systems (nitrogen atoms substituting for "graphitic" carbon in natural metamorphic organic matter). Thus, this nitrogen species with a conservative isotopic composition is the dominant form of residual nitrogen at higher metamorphic grade. ?? 2007 Elsevier Ltd. All rights reserved.

Overview of SBIR Phase II Work on Hollow Graphite Fibers

NASA Technical Reports Server (NTRS)

Stallcup, Michael; Brantley, Lott W. (Technical Monitor)

2001-01-01

Ultra-Lightweight materials are enabling for producing space based optical components and support structures. Heretofore, innovative designs using existing materials has been the approach to produce lighter-weight optical systems. Graphite fiber reinforced composites, because of their light weight, have been a material of frequent choice to produce space based optical components. Hollow graphite fibers would be lighter than standard solid graphite fibers and, thus, would save weight in optical components. The Phase I SBIR program demonstrated it is possible to produce hollow carbon fibers that have strengths up to 4.2 GPa which are equivalent to commercial fibers, and composites made from the hollow fibers had substantially equivalent composite strengths as commercial fiber composites at a 46% weight savings. The Phase II SBIR program will optimize processing and properties of the hollow carbon fiber and scale-up processing to produce sufficient fiber for fabricating a large ultra-lightweight mirror for delivery to NASA. Information presented here includes an overview of the strength of some preliminary hollow fibers, photographs of those fibers, and a short discussion of future plans.

Development of lightweight graphite/polyimide honeycomb. Phase 1: Materials selection

NASA Technical Reports Server (NTRS)

Poesch, J. G.

1971-01-01

The materials selected for the production of extremely lightweight honeycomb sandwich panels are discussed. The resin selected for the first core and face sheet fabrication was Monsanto RS6234 polyimide. The fiber selected for core manufacture was Hercules HT-S, and for face sheets, Hercules HM-S; these selections are discussed.

Postbuckling behavior of graphite-epoxy panels

NASA Technical Reports Server (NTRS)

Starnes, J. H., Jr.; Dickson, J. N.; Rouse, M.

1984-01-01

Structurally efficient fuselage panels are often designed to allow buckling to occur at applied loads below ultimate. Interest in applying graphite-epoxy materials to fuselage primary structure led to several studies of the post-buckling behavior of graphite-epoxy structural components. Studies of the postbuckling behavior of flat and curved, unstiffened and stiffened graphite-epoxy panels loaded in compression and shear were summarized. The response and failure characteristics of specimens studied experimentally were described, and analytical and experimental results were compared. The specimens tested in the studies described were fabricated from commercially available 0.005-inch-thick unidirectional graphite-fiber tapes preimpregnated with 350 F cure thermosetting epoxy resins.

Radiation Characterization Summary: ACRR Polyethylene-Lead-Graphite (PLG) Bucket Located in the Central Cavity on the 32-Inch Pedestal at the Core Centerline (ACRR-PLG-CC-32-cl).

DOE Office of Scientific and Technical Information (OSTI.GOV)

Parma, Edward J.,; Vehar, David W.; Lippert, Lance L.

2015-06-01

This document presents the facility-recommended characterization of the neutron, prompt gamma-ray, and delayed gamma-ray radiation fields in the Annular Core Research Reactor (ACRR) for the polyethylene-lead-graphite (PLG) bucket in the central cavity on the 32-inch pedestal at the core centerline. The designation for this environment is ACRR-PLG-CC-32-cl. The neutron, prompt gamma-ray, and delayed gamma-ray energy spectra, uncertainties, and covariance matrices are presented as well as radial and axial neutron and gamma-ray fluence profiles within the experiment area of the bucket. Recommended constants are given to facilitate the conversion of various dosimetry readings into radiation metrics desired by experimenters. Representative pulsemore » operations are presented with conversion examples. Acknowledgements The authors wish to thank the Annular Core Research Reactor staff and the Radiation Metrology Laboratory staff for their support of this work. Also thanks to David Ames for his assistance in running MCNP on the Sandia parallel machines.« less

Development and demonstration of manufacturing processes for fabricating graphite/LARC 160 polyimide structural elements

NASA Technical Reports Server (NTRS)

Frost, R. K.; Jones, J. S.; Dynes, P. J.; Wykes, D. H.

1981-01-01

The development and demonstration of manufacturing technologies for the structural application of Celion graphite/LARC-160 polyimide composite material is discussed. Process development and fabrication of demonstration components are discussed. Process development included establishing quality assurance of the basic composite material and processing, nondestructive inspection of fabricated components, developing processes for specific structural forms, and qualification of processes through mechanical testing. Demonstration components were fabricated. The demonstration components consisted of flat laminates, skin/stringer panels, honeycomb panels, chopped fiber compression moldings, and a technology demonstrator segment (TDS) representative of the space shuttle aft body flap.

Thermal oxidation of nuclear graphite: A large scale waste treatment option.

PubMed

Theodosiou, Alex; Jones, Abbie N; Marsden, Barry J

2017-01-01

This study has investigated the laboratory scale thermal oxidation of nuclear graphite, as a proof-of-concept for the treatment and decommissioning of reactor cores on a larger industrial scale. If showed to be effective, this technology could have promising international significance with a considerable impact on the nuclear waste management problem currently facing many countries worldwide. The use of thermal treatment of such graphite waste is seen as advantageous since it will decouple the need for an operational Geological Disposal Facility (GDF). Particulate samples of Magnox Reactor Pile Grade-A (PGA) graphite, were oxidised in both air and 60% O2, over the temperature range 400-1200°C. Oxidation rates were found to increase with temperature, with a particular rise between 700-800°C, suggesting a change in oxidation mechanism. A second increase in oxidation rate was observed between 1000-1200°C and was found to correspond to a large increase in the CO/CO2 ratio, as confirmed through gas analysis. Increasing the oxidant flow rate gave a linear increase in oxidation rate, up to a certain point, and maximum rates of 23.3 and 69.6 mg / min for air and 60% O2 respectively were achieved at a flow of 250 ml / min and temperature of 1000°C. These promising results show that large-scale thermal treatment could be a potential option for the decommissioning of graphite cores, although the design of the plant would need careful consideration in order to achieve optimum efficiency and throughput.

Thermal oxidation of nuclear graphite: A large scale waste treatment option

PubMed Central

Jones, Abbie N.; Marsden, Barry J.

2017-01-01

This study has investigated the laboratory scale thermal oxidation of nuclear graphite, as a proof-of-concept for the treatment and decommissioning of reactor cores on a larger industrial scale. If showed to be effective, this technology could have promising international significance with a considerable impact on the nuclear waste management problem currently facing many countries worldwide. The use of thermal treatment of such graphite waste is seen as advantageous since it will decouple the need for an operational Geological Disposal Facility (GDF). Particulate samples of Magnox Reactor Pile Grade-A (PGA) graphite, were oxidised in both air and 60% O2, over the temperature range 400–1200°C. Oxidation rates were found to increase with temperature, with a particular rise between 700–800°C, suggesting a change in oxidation mechanism. A second increase in oxidation rate was observed between 1000–1200°C and was found to correspond to a large increase in the CO/CO2 ratio, as confirmed through gas analysis. Increasing the oxidant flow rate gave a linear increase in oxidation rate, up to a certain point, and maximum rates of 23.3 and 69.6 mg / min for air and 60% O2 respectively were achieved at a flow of 250 ml / min and temperature of 1000°C. These promising results show that large-scale thermal treatment could be a potential option for the decommissioning of graphite cores, although the design of the plant would need careful consideration in order to achieve optimum efficiency and throughput. PMID:28793326

An Overview of Reactor Concepts, a Survey of Reactor Designs.

DTIC Science & Technology

1985-02-01

may be very different. HTGRs may use highly enriched uranium, thereby yielding better fuel economy and a reduc- tion of the actual core size for a...specific power level. The HTGR core may have fuel and control rods placed in graphite arrays similar to PWR core con- figuration, or they may have fuel ...rods are pulled out. A Peach Bottom core design is another HTGR design. This design is featured by the fuel pin’s ability to purge itself of fission

Homogeneous Nanodiamonds Are Different in Reality

NASA Astrophysics Data System (ADS)

Wu, Chi-Chin; Gottfried, Jennifer; Pesce-Rodriguez, Rose; Advanced Energetic Materials Team

Commercial detonation nanodiamonds (ND) have been investigated for many applications. They consist of carbon nanoparticles with diamond cores surrounded by onion-like graphitic shells. Unfortunately, variations in the purity and carbon structure between commercial ND samples due to variations in synthesis and purification conditions is an ongoing issue, since these differences can affect the resulting application-dependent ND behavior. Via characterization with transmission electron microscopy, this work investigates the structural and chemical differences among nominally homologous commercial detonation ND sold by a single vendor under the same item number. Significant discrepancies in the carbon structure and crystallinity between different batches with similar sizes and shapes were identified. The ND containing more non-carbon entities as impurities and oxygen-containing surface functional groups were found to possess thicker graphitic shells surrounding an unstable diamond core which quickly transforms to graphite under electron beam irradiation. However, the structure of ND with higher purities and thin onion shells remain unchanged over extended exposure to electron beams. This study demonstrates the structural and chemical differences between nominally identical commercial detonation ND samples and reveals their influence on the decomposition behavior of the particles.

Design, fabrication and test of graphite/epoxy metering truss structure components, phase 3

NASA Technical Reports Server (NTRS)

1974-01-01

The design, materials, tooling, manufacturing processes, quality control, test procedures, and results associated with the fabrication and test of graphite/epoxy metering truss structure components exhibiting a near zero coefficient of thermal expansion are described. Analytical methods were utilized, with the aid of a computer program, to define the most efficient laminate configurations in terms of thermal behavior and structural requirements. This was followed by an extensive material characterization and selection program, conducted for several graphite/graphite/hybrid laminate systems to obtain experimental data in support of the analytical predictions. Mechanical property tests as well as the coefficient of thermal expansion tests were run on each laminate under study, the results of which were used as the selection criteria for the single most promising laminate. Further coefficient of thermal expansion measurement was successfully performed on three subcomponent tubes utilizing the selected laminate.

Fabrication of graphite/polyimide composite structures.

NASA Technical Reports Server (NTRS)

Varlas, M.

1972-01-01

Selection of graphite/polyimide composite as a prime candidate for high-temperature structural applications involving long-duration temperature environments of 400 to 600 F. A variety of complex graphite/polyimide components has been fabricated, using a match-metal die approach developed for making fiber-reinforced resin composites. Parts produced include sections of a missile adapter skin flange, skin frame section, and I-beam and hat-section stringers, as well as unidirectional (0 deg) and plus or minus 45 deg oriented graphite/polyimide tubes in one-, two-, and six-inch diameters.

Structural changes in a commercial lithium-ion battery during electrochemical cycling: An in situ neutron diffraction study

NASA Astrophysics Data System (ADS)

Sharma, Neeraj; Peterson, Vanessa K.; Elcombe, Margaret M.; Avdeev, Maxim; Studer, Andrew J.; Blagojevic, Ned; Yusoff, Rozila; Kamarulzaman, Norlida

The structural response to electrochemical cycling of the components within a commercial Li-ion battery (LiCoO 2 cathode, graphite anode) is shown through in situ neutron diffraction. Lithuim insertion and extraction is observed in both the cathode and anode. In particular, reversible Li incorporation into both layered and spinel-type LiCoO 2 phases that comprise the cathode is shown and each of these components features several phase transitions attributed to Li content and correlated with the state-of-charge of the battery. At the anode, a constant cell voltage correlates with a stable lithiated graphite phase. Transformation to de-lithiated graphite at the discharged state is characterised by a sharp decrease in both structural cell parameters and cell voltage. In the charged state, a two-phase region exists and is composed of the lithiated graphite phase and about 64% LiC 6. It is postulated that trapping Li in the solid|electrolyte interface layer results in minimal structural changes to the lithiated graphite anode across the constant cell voltage regions of the electrochemical cycle.

From spent graphite to amorphous sp2+sp3 carbon-coated sp2 graphite for high-performance lithium ion batteries

NASA Astrophysics Data System (ADS)

Ma, Zhen; Zhuang, Yuchan; Deng, Yaoming; Song, Xiaona; Zuo, Xiaoxi; Xiao, Xin; Nan, Junmin

2018-02-01

Today, with the massive application of lithium ion batteries (LIBs) in the portable devices and electric vehicles, to supply the active materials with high-performances and then to recycle their wastes are two core issues for the development of LIBs. In this paper, the spent graphite (SG) in LIBs is used as raw materials to fabricate two comparative high-capacity graphite anode materials. Based on a microsurgery-like physical reconstruction, the reconstructed graphite (RG) with a sp2+sp3 carbon surface is prepared through a microwave exfoliation and subsequent spray drying process. In contrast, the neural-network-like amorphous sp2+sp3 carbon-coated graphite (AC@G) is synthesized using a self-reconfigurable chemical reaction strategy. Compared with SG and commercial graphite (CG), both RG and AC@G have enhanced specific capacities, from 311.2 mAh g-1 and 360.7 mAh g-1 to 409.7 mAh g-1 and 420.0 mAh g-1, at 0.1C after 100 cycles. In addition, they exhibit comparable cycling stability, rate capability, and voltage plateau with CG. Because the synthesis of RG and AC@G represents two typical physical and chemical methods for the recycling of SG, these results on the sp2+sp3 carbon layer coating bulk graphite also reveal an approach for the preparation of high-performance graphite anode materials derived from SG.

Thermodynamic Simulation of Equilibrium Composition of Reaction Products at Dehydration of a Technological Channel in a Uranium-Graphite Reactor

NASA Astrophysics Data System (ADS)

Pavliuk, A. O.; Zagumennov, V. S.; Kotlyarevskiy, S. G.; Bespala, E. V.

2018-01-01

The problems of accumulation of nuclear fuel spills in the graphite stack in the course of operation of uranium-graphite nuclear reactors are considered. The results of thermodynamic analysis of the processes in the graphite stack at dehydration of a technological channel, fuel element shell unsealing and migration of fission products, and activation of stable nuclides in structural elements of the reactor and actinides inside the graphite moderator are given. The main chemical reactions and compounds that are produced in these modes in the reactor channel during its operation and that may be hazardous after its shutdown and decommissioning are presented. Thermodynamic simulation of the equilibrium composition is performed using the specialized code TERRA. The results of thermodynamic simulation of the equilibrium composition in different cases of technological channel dehydration in the course of the reactor operation show that, if the temperature inside the active core of the nuclear reactor increases to the melting temperature of the fuel element, oxides and carbides of nuclear fuel are produced. The mathematical model of the nonstationary heat transfer in a graphite stack of a uranium-graphite reactor in the case of the technological channel dehydration is presented. The results of calculated temperature evolution at the center of the fuel element, the replaceable graphite element, the air gap, and in the surface layer of the block graphite are given. The numerical results show that, in the case of dehydration of the technological channel in the uranium-graphite reactor with metallic uranium, the main reaction product is uranium dioxide UO2 in the condensed phase. Low probability of production of pyrophoric uranium compounds (UH3) in the graphite stack is proven, which allows one to disassemble the graphite stack without the risk of spontaneous graphite ignition in the course of decommissioning of the uranium-graphite nuclear reactor.

Cage-Type Highly Graphitic Porous Carbon-Co3O4 Polyhedron as the Cathode of Lithium-Oxygen Batteries.

PubMed

Tang, Jing; Wu, Shichao; Wang, Tao; Gong, Hao; Zhang, Huabin; Alshehri, Saad M; Ahamad, Tansir; Zhou, Haoshen; Yamauchi, Yusuke

2016-02-03

A novel cage-type highly graphitic porous carbon-Co3O4 (GPC-Co3O4) polyhedron was designed and successfully prepared for the first time by executing a two-step annealing of core-shell structured metal-organic frameworks (MOFs). The low graphitic carbon cores were selectively removed during the secondary annealing in air atmospheres, leaving the interior voids due to their lower thermal stability compared with the graphitic carbon shells. Inspired by the unique properties of the cage-type GPC-Co3O4 polyhedron, GPC-Co3O4 was assembled as an oxygen electrode for a rechargeable Li-O2 battery without the additional conductive agent. The efficient generation of Li2O2 during discharging and the reversible decomposition of Li2O2 during charging were clearly observed by XRD patterns and SEM images. The GPC-Co3O4 polyhedron integrates the beneficial properties, including high electronic conductivity, the rigid cage-type structure consisting of the mesoporous walls and interior void space, as well as the uniformly embedded catalytically active Co3O4 nanoparticles. As a result, the GPC-Co3O4 cathode displays a low charge overpotential of 0.58 V, a good rate capability, and a long cycle life in a Li-O2 battery.

A study of the relationship between microstructure and oxidation effects in nuclear graphite at very high temperatures

NASA Astrophysics Data System (ADS)

Lo, I.-Hsuan; Tzelepi, Athanasia; Patterson, Eann A.; Yeh, Tsung-Kuang

2018-04-01

Graphite is used in the cores of gas-cooled reactors as both the neutron moderator and a structural material, and traditional and novel graphite materials are being studied worldwide for applications in Generation IV reactors. In this study, the oxidation characteristics of petroleum-based IG-110 and pitch-based IG-430 graphite pellets in helium and air environments at temperatures ranging from 700 to 1600 °C were investigated. The oxidation rates and activation energies were determined based on mass loss measurements in a series of oxidation tests. The surface morphology was characterized by scanning electron microscopy. Although the thermal oxidation mechanism was previously considered to be the same for all temperatures higher than 1000 °C, the significant increases in oxidation rate observed at very high temperatures suggest that the oxidation behavior of the selected graphite materials at temperatures higher than 1200 °C is different. This work demonstrates that changes in surface morphology and in oxidation rate of the filler particles in the graphite materials are more prominent at temperatures above 1200 °C. Furthermore, possible intrinsic factors contributing to the oxidation of the two graphite materials at different temperature ranges are discussed taking account of the dominant role played by temperature.

Defect induced electronic states and magnetism in ball-milled graphite.

PubMed

Milev, Adriyan; Dissanayake, D M A S; Kannangara, G S K; Kumarasinghe, A R

2013-10-14

The electronic structure and magnetism of nanocrystalline graphite prepared by ball milling of graphite in an inert atmosphere have been investigated using valence band spectroscopy (VB), core level near-edge X-ray absorption fine structure (NEXAFS) spectroscopy and magnetic measurements as a function of the milling time. The NEXAFS spectroscopy of graphite milled for 30 hours shows simultaneous evolution of new states at ~284.0 eV and at ~290.5 eV superimposed upon the characteristic transitions at 285.4 eV and 291.6 eV, respectively. The modulation of the density of states is explained by evolution of discontinuities within the sheets and along the fracture lines in the milled graphite. The magnetic measurements in the temperature interval 2-300-2 K at constant magnetic field strength show a correlation between magnetic properties and evolution of the new electronic states. With the reduction of the crystallite sizes of the graphite fragments, the milled material progressively changes its magnetic properties from diamagnetic to paramagnetic with contributions from both Pauli and Curie paramagnetism due to the evolution of new states at ~284 and ~290.5 eV, respectively. These results indicate that the magnetic behaviour of ball-milled graphite can be manipulated by changing the milling conditions.

Nanofibers of fullerene C60 through interplay of ball-and-socket supermolecules.

PubMed

Hubble, Lee J; Raston, Colin L

2007-01-01

Mixing solutions of p-tBu-calix[5]arene and C(60) in toluene results in a 1:1 complex (C(60)) intersection(p-tBu-calix[5]arene), which precipitates as nanofibers. The principle structural unit is based on a host-guest ball-and-socket nanostructure of the two components, with an extended structure comprising zigzag/helical arrays of fullerenes (powder X-ray diffraction data coupled with molecular modeling). Under argon at temperatures above 309 degrees C, the fibers undergo selective volatilization of the calixarenes to afford C(60)-core nanostructures encapsulated in a graphitic material sheath, which exhibits a dramatic increase in surface area. Above 650 degrees C the material exhibits an ohmic conductance response, due to the encapsulation process.

Development of design data for graphite reinforced epoxy and polyimide composites

NASA Technical Reports Server (NTRS)

Scheck, W. G.

1974-01-01

Processing techniques and design data were characterized for a graphite/epoxy composite system that is useful from 75 K to 450 K, and a graphite/polyimide composite system that is useful from 75 K to 589 K. The Monsanto 710 polyimide resin was selected as the resin to be characterized and used with the graphite fiber reinforcement. Material was purchased using the prepreg specification for the design data generation for both the HT-S/710 and HM-S/710 graphite/polyimide composite system. Lamina and laminate properties were determined at 75 K, 297 K, and 589 K. The test results obtained on the skin-stringer components proved that graphite/polyimide composites can be reliably designed and analyzed much like graphite/epoxy composites. The design data generated in the program includes the standard static mechanical properties, biaxial strain data, creep, fatigue, aging, and thick laminate data.

Formation, characterization, and dynamics of onion-like carbon structures for electrical energy storage from nanodiamonds using reactive force fields

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ganesh, P.; Kent, P. R. C.; Mochalin, V.

We simulate the experimentally observed graphitization of nanodiamonds into multi-shell onion-like carbonnanostructures, also called carbon onions, at different temperatures, using reactive force fields. The simulations include long-range Coulomb and van der Waals interactions. Our results suggest that long-range interactions play a crucial role in the phase-stability and the graphitization process. Graphitization is both enthalpically and entropically driven and can hence be controlled with temperature. The outer layers of the nanodiamond have a lower kinetic barrier toward graphitization irrespective of the size of the nanodiamond and graphitize within a few-hundred picoseconds, with a large volume increase. The inner core of themore » nanodiamonds displays a large size-dependent kinetic barrier, and graphitizes much more slowly with abrupt jumps in the internal energy. It eventually graphitizes by releasing pressure and expands once the outer shells have graphitized. The degree of transformation at a particular temperature is thereby determined by a delicate balance between the thermal energy, long-range interactions, and the entropic/enthalpic free energy gained by graphitization. Upon full graphitization, a multi-shell carbonnanostructure appears, with a shell-shell spacing of about ~3.4 Å for all sizes. The shells are highly defective with predominantly five- and seven-membered rings to curve space. Larger nanodiamonds with a diameter of 4 nm can graphitize into spiral structures with a large (~29-atom carbon ring) pore opening on the outermost shell. Such a large one-way channel is most attractive for a controlled insertion of molecules/ions such as Li ions, water, or ionic liquids, for increased electrochemical capacitor or battery electrode applications.« less

Formation, characterization and dynamics of onion like carbon structures from nanodiamonds using reactive force-fields for electrical energy storage

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kent, Paul R

We simulate the experimentally observed graphitization of nanodiamonds into multi-shell onion-like carbon nanostructures, also called carbon onions, at different temperatures, using reactive force fields. The simulations include long-range Coulomb and van der Waals interactions. Our results suggest that long-range interactions play a crucial role in the phase-stability and the graphitization process. Graphitization is both enthalpically and entropically driven and can hence be controlled with temperature. The outer layers of the nanodiamond have a lower kinetic barrier toward graphitization irrespective of the size of the nanodiamond and graphitize within a few-hundred picoseconds, with a large volume increase. The inner core ofmore » the nanodiamonds displays a large size-dependent kinetic barrier, and graphitizes much more slowly with abrupt jumps in the internal energy. It eventually graphitizes by releasing pressure and expands once the outer shells have graphitized. The degree of transformation at a particular temperature is thereby determined by a delicate balance between the thermal energy, long-range interactions, and the entropic/enthalpic free energy gained by graphitization. Upon full graphitization, a multi-shell carbon nanostructure appears, with a shell-shell spacing of about {approx}3.4 {angstrom} for all sizes. The shells are highly defective with predominantly five- and seven-membered rings to curve space. Larger nanodiamonds with a diameter of 4 nm can graphitize into spiral structures with a large ({approx}29-atom carbon ring) pore opening on the outermost shell. Such a large one-way channel is most attractive for a controlled insertion of molecules/ions such as Li ions, water, or ionic liquids, for increased electrochemical capacitor or battery electrode applications.« less

Sheath-Core Graphite/Silk Fiber Made by Dry-Meyer-Rod-Coating for Wearable Strain Sensors.

PubMed

Zhang, Mingchao; Wang, Chunya; Wang, Qi; Jian, Muqiang; Zhang, Yingying

2016-08-17

Recent years have witnessed the explosive development of flexible strain sensors. Nanomaterials have been widely utilized to fabricate flexible strain sensors, because of their high flexibility and electrical conductivity. However, the fabrication processes for nanomaterials and the subsequent strain sensors are generally complicated and are manufactured at high cost. In this work, we developed a facile dry-Meyer-rod-coating process to fabricate sheath-core-structured single-fiber strain sensors using ultrafine graphite flakes as the sheath and silk fibers as the core by virtue of their flexibility, high production, and low cost. The fabricated strain sensor exhibits a high sensitivity with a gauge factor of 14.5 within wide workable strain range up to 15%, and outstanding stability (up to 3000 cycles). The single-fiber-based strain sensors could be attached to a human body to detect joint motions or easily integrated into the multidirectional strain sensor for monitoring multiaxial strain, showing great potential applications as wearable strain sensors.

Structural Performance of a Compressively Loaded Foam-Core Hat-Stiffened Textile Composite Panel

NASA Technical Reports Server (NTRS)

Ambur, Damodar R.; Dexter, Benson H.

1996-01-01

A structurally efficient hat-stiffened panel concept that utilizes a structural foam as a stiffener core material has been designed and developed for aircraft primary structural applications. This stiffener concept is fabricated from textile composite material forms with a resin transfer molding process. This foam-filled hat-stiffener concept is structurally more efficient than most other prismatically stiffened panel configurations in a load range that is typical for both fuselage and wing structures. The panel design is based on woven/stitched and braided graphite-fiber textile preforms, an epoxy resin system, and Rohacell foam core. The structural response of this panel design was evaluated for its buckling and postbuckling behavior with and without low-speed impact damage. The results from single-stiffener and multi-stiffener specimen tests suggest that this structural concept responds to loading as anticipated and has excellent damage tolerance characteristics compared to a similar panel design made from preimpregnated graphite-epoxy tape material.

Technology of civil usage of composites. [in commercial aircraft structures

NASA Technical Reports Server (NTRS)

Kemp, D. E.

1977-01-01

The paper deals with the use of advanced composites in structural components of commercial aircraft. The need for testing the response of a material system to service environment is discussed along with methods for evaluating design and manufacturing aspects of a built-up structure under environmental conditions and fail-safe (damage-tolerance) evaluation of structures. Crashworthiness aspects, the fire-hazard potential, and electrical damage of composite structures are considered. Practical operational experience with commercial aircraft is reviewed for boron/epoxy foreflaps, Kevlar/epoxy fillets and fairings, graphite/epoxy spoilers, graphite/polysulfone spoilers, graphite/epoxy floor posts, boron/aluminum aft pylon skin panels, graphite/epoxy engine nose cowl outer barrels, and graphite/epoxy upper aft rudder segments.

Development of seal ring carbon-graphite materials (tasks 5, 6, and 7)

NASA Technical Reports Server (NTRS)

Fechter, N. J.; Petrunich, P. S.

1972-01-01

Carbon-graphite seal ring bodies for operation at air temperatures to 1300 F(704 C) were manufactured from three select formulations. Mechanical and thermal properties, porosities, and oxidation rates were measured. The results have shown that: (1) Major property improvements anticipated from the screening studies were not realized because of processing problems associated with the scale-up in material size and probable deterioration of a phenolic resin binder; (2) the mechanical properties of a phenolic resin-bonded, carbon-graphite material can be improved by applying high pressure during carbonization; and (3) the textile form of graphite fiber used as the minor filler component in a carbon-graphite material can beneficially affect mechanical properties.

Irradiation Creep in Graphite

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ubic, Rick; Butt, Darryl; Windes, William

2014-03-13

An understanding of the underlying mechanisms of irradiation creep in graphite material is required to correctly interpret experimental data, explain micromechanical modeling results, and predict whole-core behavior. This project will focus on experimental microscopic data to demonstrate the mechanism of irradiation creep. High-resolution transmission electron microscopy should be able to image both the dislocations in graphite and the irradiation-induced interstitial clusters that pin those dislocations. The team will first prepare and characterize nanoscale samples of virgin nuclear graphite in a transmission electron microscope. Additional samples will be irradiated to varying degrees at the Advanced Test Reactor (ATR) facility and similarlymore » characterized. Researchers will record microstructures and crystal defects and suggest a mechanism for irradiation creep based on the results. In addition, the purchase of a tensile holder for a transmission electron microscope will allow, for the first time, in situ observation of creep behavior on the microstructure and crystallographic defects.« less

Exfoliation of graphite into graphene in polar solvents mediated by amphiphilic hexa-peri-hexabenzocoronene.

PubMed

Kabe, Ryota; Feng, Xinliang; Adachi, Chihaya; Müllen, Klaus

2014-11-01

A water-soluble surfactant consisting of hexa-peri-hexabenzocoronene (HBC) as hydrophobic aromatic core and hydrophilic carboxy substituents was synthesized. It exhibited a self-assembled nanofiber structure in the solid state. Profiting from the π interactions between the large aromatic core of HBC and graphene, the surfactant mediated the exfoliation of graphite into graphene in polar solvents, which was further stabilized by the bulky hydrophilic carboxylic groups. A graphene dispersion with a concentration as high as 1.1 mg L(-1) containing 2-6 multilayer nanosheets was obtained. The lateral size of the graphene sheets was in the range of 100-500 nm based on atomic force microscope (AFM) and transmission electron microscope (TEM) measurements. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Phase Structures and Magnetic Properties of Graphite Nanosheets and Ni-Graphite Nanocomposite Synthesized by Electrical Explosion of Wire in Liquid

NASA Astrophysics Data System (ADS)

Nguyen, Minh-Thuyet; Kim, Jin-Hyung; Lee, Jung-Goo; Kim, Jin-Chun

2018-03-01

The present work studied on phases and magnetic properties of graphite nanosheets and Ni-graphite nanocomposite synthesized using the electrical explosion of wire (EEW) in ethanol. X-ray diffraction and field emission scanning electron microscope were used to investigate the phases and the morphology of the nanopowders obtained. It was found that graphite nanosheets were absolutely fabricated by EEW with a thickness of 29 nm and 3 μm diameter. The as-synthesized Ni-graphite composite powders had a Ni-coating on the surfaces of graphite sheets. The hysteresis loop of the as-exploded, the hydrogen-treated composite nanopowders and the sintered samples were examined with a vibrating sample magnetometer at room temperature. The Ni-graphite composite exposed the magnetic behaviors which are attributed to Ni component. The magnetic properties of composite had the improvement from 10.2 emu/g for the as-exploded powders to 15.8 emu/g for heat-treated powders and 49.16 emu/g for sintered samples.

Quantifying microstructural dynamics and electrochemical activity of graphite and silicon-graphite lithium ion battery anodes

NASA Astrophysics Data System (ADS)

Pietsch, Patrick; Westhoff, Daniel; Feinauer, Julian; Eller, Jens; Marone, Federica; Stampanoni, Marco; Schmidt, Volker; Wood, Vanessa

2016-09-01

Despite numerous studies presenting advances in tomographic imaging and analysis of lithium ion batteries, graphite-based anodes have received little attention. Weak X-ray attenuation of graphite and, as a result, poor contrast between graphite and the other carbon-based components in an electrode pore space renders data analysis challenging. Here we demonstrate operando tomography of weakly attenuating electrodes during electrochemical (de)lithiation. We use propagation-based phase contrast tomography to facilitate the differentiation between weakly attenuating materials and apply digital volume correlation to capture the dynamics of the electrodes during operation. After validating that we can quantify the local electrochemical activity and microstructural changes throughout graphite electrodes, we apply our technique to graphite-silicon composite electrodes. We show that microstructural changes that occur during (de)lithiation of a pure graphite electrode are of the same order of magnitude as spatial inhomogeneities within it, while strain in composite electrodes is locally pronounced and introduces significant microstructural changes.

Auger Electrons as Probes for Composite Micro- and Nano- structured Materials: Application to Solid Electrolyte Interphases in Graphite and Silicon-Graphite Electrodes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kalaga, Kaushik; Shkrob, Ilya A.; Haasch, Richard T.

In this study, Auger electron spectroscopy (AES) combined with ion sputtering profilometry, Xray photoelectron spectroscopy (XPS), and scanning electron microscopy (SEM) have been used in a complementary fashion to examine chemical and microstructural changes in graphite (Gr) and silicon/graphite (Si/Gr) blends contained in the negative electrodes of lithium-ion cells. We demonstrate how AES can be used to characterize morphology of the solid-electrolyte interphase (SEI) deposits in such heterogeneous media, complementing well-established methods, such as XPS and SEM. In this way we demonstrate that the SEI does not consist of uniformly thick layers on the graphite and silicon; the thickness ofmore » the SEI layers in cycle-life aged electrodes follows an exponential distribution with a mean of ca. 13 nm for the graphite and ca. 20-25 nm for the silicon nanoparticles (with a crystalline core of 50-70 nm in diameter). Furthermore, a “sticky-sphere” model, in which Si nanoparticles are covered with a layer of polymer binder (that is replaced by the SEI during cycling) of variable thickness is introduced to account for the features observed.« less

Auger Electrons as Probes for Composite Micro- and Nano- structured Materials: Application to Solid Electrolyte Interphases in Graphite and Silicon-Graphite Electrodes

DOE PAGES

Kalaga, Kaushik; Shkrob, Ilya A.; Haasch, Richard T.; ...

2017-10-05

In this study, Auger electron spectroscopy (AES) combined with ion sputtering profilometry, Xray photoelectron spectroscopy (XPS), and scanning electron microscopy (SEM) have been used in a complementary fashion to examine chemical and microstructural changes in graphite (Gr) and silicon/graphite (Si/Gr) blends contained in the negative electrodes of lithium-ion cells. We demonstrate how AES can be used to characterize morphology of the solid-electrolyte interphase (SEI) deposits in such heterogeneous media, complementing well-established methods, such as XPS and SEM. In this way we demonstrate that the SEI does not consist of uniformly thick layers on the graphite and silicon; the thickness ofmore » the SEI layers in cycle-life aged electrodes follows an exponential distribution with a mean of ca. 13 nm for the graphite and ca. 20-25 nm for the silicon nanoparticles (with a crystalline core of 50-70 nm in diameter). Furthermore, a “sticky-sphere” model, in which Si nanoparticles are covered with a layer of polymer binder (that is replaced by the SEI during cycling) of variable thickness is introduced to account for the features observed.« less

A Study of the Oxidation Behaviour of Pile Grade A (PGA) Nuclear Graphite Using Thermogravimetric Analysis (TGA), Scanning Electron Microscopy (SEM) and X-Ray Tomography (XRT).

PubMed

Payne, Liam; Heard, Peter J; Scott, Thomas B

2015-01-01

Pile grade A (PGA) graphite was used as a material for moderating and reflecting neutrons in the UK's first generation Magnox nuclear power reactors. As all but one of these reactors are now shut down there is a need to understand the residual state of the material prior to decommissioning of the cores, in particular the location and concentration of key radio-contaminants such as 14C. The oxidation behaviour of unirradiated PGA graphite was studied, in the temperature range 600-1050°C, in air and nitrogen using thermogravimetric analysis, scanning electron microscopy and X-ray tomography to investigate the possibility of using thermal degradation techniques to examine 14C distribution within irradiated material. The thermal decomposition of PGA graphite was observed to follow the three oxidation regimes historically identified by previous workers with limited, uniform oxidation at temperatures below 600°C and substantial, external oxidation at higher temperatures. This work demonstrates that the different oxidation regimes of PGA graphite could be developed into a methodology to characterise the distribution and concentration of 14C in irradiated graphite by thermal treatment.

A Study of the Oxidation Behaviour of Pile Grade A (PGA) Nuclear Graphite Using Thermogravimetric Analysis (TGA), Scanning Electron Microscopy (SEM) and X-Ray Tomography (XRT)

PubMed Central

Payne, Liam; Heard, Peter J.; Scott, Thomas B.

2015-01-01

Pile grade A (PGA) graphite was used as a material for moderating and reflecting neutrons in the UK’s first generation Magnox nuclear power reactors. As all but one of these reactors are now shut down there is a need to understand the residual state of the material prior to decommissioning of the cores, in particular the location and concentration of key radio-contaminants such as 14C. The oxidation behaviour of unirradiated PGA graphite was studied, in the temperature range 600–1050°C, in air and nitrogen using thermogravimetric analysis, scanning electron microscopy and X-ray tomography to investigate the possibility of using thermal degradation techniques to examine 14C distribution within irradiated material. The thermal decomposition of PGA graphite was observed to follow the three oxidation regimes historically identified by previous workers with limited, uniform oxidation at temperatures below 600°C and substantial, external oxidation at higher temperatures. This work demonstrates that the different oxidation regimes of PGA graphite could be developed into a methodology to characterise the distribution and concentration of 14C in irradiated graphite by thermal treatment. PMID:26575374

Graphitic carbon nitride nanosheet@metal-organic framework core-shell nanoparticles for photo-chemo combination therapy

NASA Astrophysics Data System (ADS)

Chen, Rui; Zhang, Jinfeng; Wang, Yu; Chen, Xianfeng; Zapien, J. Antonio; Lee, Chun-Sing

2015-10-01

Recently, nanoscale metal-organic frameworks (NMOFs) have started to be developed as a promising platform for bioimaging and drug delivery. On the other hand, combination therapies using multiple approaches are demonstrated to achieve much enhanced efficacy. Herein, we report, for the first time, core-shell nanoparticles consisting of a photodynamic therapeutic (PDT) agent and a MOF shell while simultaneously carrying a chemotherapeutic drug for effective combination therapy. In this work, core-shell nanoparticles of zeolitic-imadazolate framework-8 (ZIF-8) as shell embedded with graphitic carbon nitride (g-C3N4) nanosheets as core are fabricated by growing ZIF-8 in the presence of g-C3N4 nanosheets. Doxorubicin hydrochloride (DOX) is then loaded into the ZIF-8 shell of the core-shell nanoparticles. The combination of the chemotherapeutic effects of DOX and the PDT effect of g-C3N4 nanosheets can lead to considerably enhanced efficacy. Furthermore, the red fluorescence of DOX and the blue fluorescence of g-C3N4 nanosheets provide the additional function of dual-color imaging for monitoring the drug release process.Recently, nanoscale metal-organic frameworks (NMOFs) have started to be developed as a promising platform for bioimaging and drug delivery. On the other hand, combination therapies using multiple approaches are demonstrated to achieve much enhanced efficacy. Herein, we report, for the first time, core-shell nanoparticles consisting of a photodynamic therapeutic (PDT) agent and a MOF shell while simultaneously carrying a chemotherapeutic drug for effective combination therapy. In this work, core-shell nanoparticles of zeolitic-imadazolate framework-8 (ZIF-8) as shell embedded with graphitic carbon nitride (g-C3N4) nanosheets as core are fabricated by growing ZIF-8 in the presence of g-C3N4 nanosheets. Doxorubicin hydrochloride (DOX) is then loaded into the ZIF-8 shell of the core-shell nanoparticles. The combination of the chemotherapeutic effects of DOX and the PDT effect of g-C3N4 nanosheets can lead to considerably enhanced efficacy. Furthermore, the red fluorescence of DOX and the blue fluorescence of g-C3N4 nanosheets provide the additional function of dual-color imaging for monitoring the drug release process. Electronic supplementary information (ESI) available. See DOI: 10.1039/c5nr04436g

A "Sticky" Mucin-Inspired DNA-Polysaccharide Binder for Silicon and Silicon-Graphite Blended Anodes in Lithium-Ion Batteries.

PubMed

Kim, Sunjin; Jeong, You Kyeong; Wang, Younseon; Lee, Haeshin; Choi, Jang Wook

2018-05-14

New binder concepts have lately demonstrated improvements in the cycle life of high-capacity silicon anodes. Those binder designs adopt adhesive functional groups to enhance affinity with silicon particles and 3D network conformation to secure electrode integrity. However, homogeneous distribution of silicon particles in the presence of a substantial volumetric content of carbonaceous components (i.e., conductive agent, graphite, etc.) is still difficult to achieve while the binder maintains its desired 3D network. Inspired by mucin, the amphiphilic macromolecular lubricant, secreted on the hydrophobic surface of gastrointestine to interface aqueous serous fluid, here, a renatured DNA-alginate amphiphilic binder for silicon and silicon-graphite blended electrodes is reported. Mimicking mucin's structure comprised of a hydrophobic protein backbone and hydrophilic oligosaccharide branches, the renatured DNA-alginate binder offers amphiphilicity from both components, along with a 3D fractal network structure. The DNA-alginate binder facilitates homogeneous distribution of electrode components in the electrode as well as its enhanced adhesion onto a current collector, leading to improved cyclability in both silicon and silicon-graphite blended electrodes. © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Suspended-Bed Reactor preliminary design, /sup 233/U--/sup 232/Th cycle. Final report (revised)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Karam, R.A.; Alapour, A.; Lee, C.C.

1977-11-01

The preliminary design Suspended-Bed Reactor is described. Coated particles about 2 mm in diameter are used as the fuel. The coatings consist of three layers: (1) low density pyrolytic graphite, 70 ..mu.. thick, (2) silicon carbide pressure vessel, 30 ..mu.. thick, and (3) ZrC layer, 50 ..mu.. thick, to protect the pressure vessel from moisture and oxygen. The fuel kernel can be either uranium-thorium dicarbide or metal. The coated particles are suspended by helium gas (coolant) in a cluster of pressurized tubes. The upward flow of helium fluidizes the coated particles. As the flow rate increases, the bed of particlesmore » is lifted upward to the core section. The particles are restrained at the upper end of the core by a suitable screen. The overall particle density in the core is just enough for criticality condition. Should the helium flow cease, the bed in the core section will collapse, and the particles will flow downward into the section where the increased physical spacings among the tubes brings about a safe shutdown. By immersing this section of the tubes in a large graphite block to serve as a heat sink, dissipation of decay heat becomes manageable. This eliminates the need for emergency core cooling systems.« less

Effective gaseous diffusion coefficients of select ultra-fine, super-fine and medium grain nuclear graphite

DOE PAGES

Kane, Joshua J.; Matthews, Austin C.; Orme, Christopher J.; ...

2018-05-05

Understanding “Where?” and “How much?” oxidation has occurred in a nuclear graphite component is critical to predicting any deleterious effects to physical, mechanical, and thermal properties. A key factor in answering these questions is characterizing the effective mass transport rates of gas species in nuclear graphites. Effective gas diffusion coefficients were determined for twenty-six graphite specimens spanning six modern grades of nuclear graphite. A correlation was established for the majority of grades examined allowing a reasonable estimate of the effective diffusion coefficient to be determined purely from an estimate of total porosity. The importance of Knudsen diffusion to the measuredmore » diffusion coefficients is also shown for modern grades. Furthermore, Knudsen diffusion has not historically been considered to contribute to measured diffusion coefficients of nuclear graphite.« less

Effective gaseous diffusion coefficients of select ultra-fine, super-fine and medium grain nuclear graphite

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kane, Joshua J.; Matthews, Austin C.; Orme, Christopher J.

Understanding “Where?” and “How much?” oxidation has occurred in a nuclear graphite component is critical to predicting any deleterious effects to physical, mechanical, and thermal properties. A key factor in answering these questions is characterizing the effective mass transport rates of gas species in nuclear graphites. Effective gas diffusion coefficients were determined for twenty-six graphite specimens spanning six modern grades of nuclear graphite. A correlation was established for the majority of grades examined allowing a reasonable estimate of the effective diffusion coefficient to be determined purely from an estimate of total porosity. The importance of Knudsen diffusion to the measuredmore » diffusion coefficients is also shown for modern grades. Furthermore, Knudsen diffusion has not historically been considered to contribute to measured diffusion coefficients of nuclear graphite.« less

Automated eddy current analysis of materials

NASA Technical Reports Server (NTRS)

Workman, Gary L.

1991-01-01

The use of eddy current techniques for characterizing flaws in graphite-based filament-wound cylindrical structures is described. A major emphasis was also placed upon incorporating artificial intelligence techniques into the signal analysis portion of the inspection process. Developing an eddy current scanning system using a commercial robot for inspecting graphite structures (and others) was a goal in the overall concept and is essential for the final implementation for the expert systems interpretation. Manual scans, as performed in the preliminary work here, do not provide sufficiently reproducible eddy current signatures to be easily built into a real time expert system. The expert systems approach to eddy current signal analysis requires that a suitable knowledge base exist in which correct decisions as to the nature of a flaw can be performed. A robotic workcell using eddy current transducers for the inspection of carbon filament materials with improved sensitivity was developed. Improved coupling efficiencies achieved with the E-probes and horseshoe probes are exceptional for graphite fibers. The eddy current supervisory system and expert system was partially developed on a MacIvory system. Continued utilization of finite element models for predetermining eddy current signals was shown to be useful in this work, both for understanding how electromagnetic fields interact with graphite fibers, and also for use in determining how to develop the knowledge base. Sufficient data was taken to indicate that the E-probe and the horseshoe probe can be useful eddy current transducers for inspecting graphite fiber components. The lacking component at this time is a large enough probe to have sensitivity in both the far and near field of a thick graphite epoxy component.

Development, manufacturing, and test of graphite-epoxy composite spoilers for flight service on 737 transport aircraft

NASA Technical Reports Server (NTRS)

Stoecklin, R. L.

1976-01-01

A total of 114 spoiler units were fabricated in a production shop environment, utilizing three graphite epoxy material systems. Production planning paper was generated for each spoiler unit to completely document each production step of each spoiler unit. The graphite epoxy skins were laid up on production tooling using both mechanical and hand layup techniques. Inspection techniques utilized MRB type assessment in the abscence of quality requirements. Each completed spoiler was subjected to ultrasonic inspection utilizing a multicolor recording system that documented each inspection result. In addition, one static test spoiler was sectioned after the test to examine the adhesive filleting to the honeycomb core. Visual examination of the cured adhesives showed excellent results.

Pebble Bed Reactors Design Optimization Methods and their Application to the Pebble Bed Fluoride Salt Cooled High Temperature Reactor (PB-FHR)

NASA Astrophysics Data System (ADS)

Cisneros, Anselmo Tomas, Jr.

The Fluoride salt cooled High temperature Reactor (FHR) is a class of advanced nuclear reactors that combine the robust coated particle fuel form from high temperature gas cooled reactors, direct reactor auxillary cooling system (DRACS) passive decay removal of liquid metal fast reactors, and the transparent, high volumetric heat capacitance liquid fluoride salt working fluids---flibe (33%7Li2F-67%BeF)---from molten salt reactors. This combination of fuel and coolant enables FHRs to operate in a high-temperature low-pressure design space that has beneficial safety and economic implications. In 2012, UC Berkeley was charged with developing a pre-conceptual design of a commercial prototype FHR---the Pebble Bed- Fluoride Salt Cooled High Temperature Reactor (PB-FHR)---as part of the Nuclear Energy University Programs' (NEUP) integrated research project. The Mark 1 design of the PB-FHR (Mk1 PB-FHR) is 236 MWt flibe cooled pebble bed nuclear heat source that drives an open-air Brayton combine-cycle power conversion system. The PB-FHR's pebble bed consists of a 19.8% enriched uranium fuel core surrounded by an inert graphite pebble reflector that shields the outer solid graphite reflector, core barrel and reactor vessel. The fuel reaches an average burnup of 178000 MWt-d/MT. The Mk1 PB-FHR exhibits strong negative temperature reactivity feedback from the fuel, graphite moderator and the flibe coolant but a small positive temperature reactivity feedback of the inner reflector and from the outer graphite pebble reflector. A novel neutronics and depletion methodology---the multiple burnup state methodology was developed for an accurate and efficient search for the equilibrium composition of an arbitrary continuously refueled pebble bed reactor core. The Burnup Equilibrium Analysis Utility (BEAU) computer program was developed to implement this methodology. BEAU was successfully benchmarked against published results generated with existing equilibrium depletion codes VSOP and PEBBED for a high temperature gas cooled pebble bed reactor. Three parametric studies were performed for exploring the design space of the PB-FHR---to select a fuel design for the PB-FHR] to select a core configuration; and to optimize the PB-FHR design. These parametric studies investigated trends in the dependence of important reactor performance parameters such as burnup, temperature reactivity feedback, radiation damage, etc on the reactor design variables and attempted to understand the underlying reactor physics responsible for these trends. A pebble fuel parametric study determined that pebble fuel should be designed with a carbon to heavy metal ratio (C/HM) less than 400 to maintain negative coolant temperature reactivity coefficients. Seed and thorium blanket-, seed and inert pebble reflector- and seed only core configurations were investigated for annular FHR PBRs---the C/HM of the blanket pebbles and discharge burnup of the thorium blanket pebbles were additional design variable for core configurations with thorium blankets. Either a thorium blanket or graphite pebble reflector is required to shield the outer graphite reflector enough to extend its service lifetime to 60 EFPY. The fuel fabrication costs and long cycle lengths of the thorium blanket fuel limit the potential economic advantages of using a thorium blanket. Therefore, the seed and pebble reflector core configuration was adopted as the baseline core configuration. Multi-objective optimization with respect to economics was performed for the PB-FHR accounting for safety and other physical design constraints derived from the high-level safety regulatory criteria. These physical constraints were applied along in a design tool, Nuclear Application Value Estimator, that evaluated a simplified cash flow economics model based on estimates of reactor performance parameters calculated using correlations based on the results of parametric design studies for a specific PB-FHR design and a set of economic assumptions about the electricity market to evaluate the economic implications of design decisions. The optimal PB-FHR design---Mark 1 PB-FHR---is described along with a detailed summary of its performance characteristics including: the burnup, the burnup evolution, temperature reactivity coefficients, the power distribution, radiation damage distributions, control element worths, decay heat curves and tritium production rates. The Mk1 PB-FHR satisfies the PB-FHR safety criteria. The fuel, moderator (pebble core, pebble shell, graphite matrix, TRISO layers) and coolant have global negative temperature reactivity coefficients and the fuel temperatures are well within their limits.

Co@Co3 O4 @PPD Core@bishell Nanoparticle-Based Composite as an Efficient Electrocatalyst for Oxygen Reduction Reaction.

PubMed

Wang, Zhijuan; Li, Bing; Ge, Xiaoming; Goh, F W Thomas; Zhang, Xiao; Du, Guojun; Wuu, Delvin; Liu, Zhaolin; Andy Hor, T S; Zhang, Hua; Zong, Yun

2016-05-01

Durable electrocatalysts with high catalytic activity toward oxygen reduction reaction (ORR) are crucial to high-performance primary zinc-air batteries (ZnABs) and direct methanol fuel cells (DMFCs). An efficient composite electrocatalyst, Co@Co3 O4 core@shell nanoparticles (NPs) embedded in pyrolyzed polydopamine (PPD) is reported, i.e., in Co@Co3 O4 @PPD core@bishell structure, obtained via a three-step sequential process involving hydrothermal synthesis, high temperature calcination under nitrogen atmosphere, and gentle heating in air. With Co@Co3 O4 NPs encapsulated by ultrathin highly graphitized N-doped carbon, the catalyst exhibits excellent stability in aqueous alkaline solution over extended period and good tolerance to methanol crossover effect. The integration of N-doped graphitic carbon outer shell and ultrathin nanocrystalline Co3 O4 inner shell enable high ORR activity of the core@bishell NPs, as evidenced by ZnABs using catalyst of Co@Co3 O4 @PPD in air-cathode which delivers a stable voltage profile over 40 h at a discharge current density of as high as 20 mA cm(-2) . © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Experimental high temperature carbon isotope fractionation involving graphite

NASA Astrophysics Data System (ADS)

Kueter, N.; Schmidt, M. W.; Lilley, M. D.; Bernasconi, S. M.

2016-12-01

Graphite/carbonate carbon isotope fractionation was mainly investigated at 400- 800°C and is based on empirical calibrations, theoretical calculations and few experiments [1,2]. Own work on COH-fluid/graphite isotope fractionation shows that in experiments up to 1000oC a fluid phase is always enriched in 13C compared to coexisting graphitic carbon. The eventual kinetic isotope effect in these experiments is best displayed by the graphitic carbon being at least 3 ‰ lighter than methane. Only few experiments done in the graphite/carbonate pair dealt with higher temperatures reaching 1400°C, indicating a fractionation of up to 2 ‰ at temperatures of the Earth's mantle [2-4]. To better understand carbon isotope fractionation in crustal systems and still overcome kinetic effects, we study the graphite/carbonatite pair with piston cylinder experiments in the Na2CO3-CaCO3-CaO-COH system. Tartaric acid (C4H6O6) supplies reduced carbon, time series are performed at 10 kbar, 1300-1800°C. Initial experiments at 1300°C produce well-ordered, micron-sized graphite flakes growing attached to the capsule walls while the Na-Ca-carbonatite-melt quenches to dendritic textures. No gaseous phase was observed. Conditions well above the liquidus of the Na2CO3-CaCO3-binary lead to dissolution of the H2O from tartaric acid decomposition in the melt, any CO2-component is bound by the excess CaO to CaCO3melt while in the relatively oxidizing capsule environment any CH4-component reacts with CO2 to carbon and H2O. The graphite and the carbonatite quench are measured for their δ13C composition using a GasBench II (carbonate-dissolution in phosphoric acid) and TC/EA (residual graphite combusted in oxygen atmosphere) system coupled to a Thermo Fischer IRMS. Our results expand from the graphite-carbonate system to graphite-fluid system when adding available fluid-carbonate fractionation factors, but are also directly applicable to diamond synthesis as graphite is often found as a precursor phase in diamond-growth experiments in carbonatite systems and natural diamonds. [1] Chacko et al. (2001) Rev Min Geochem; Deines & Eggler (2009) GCA; [3] Scheele & Hoefs (1992) CMP; [4] Chacko et al. (1991) GCA

Develop and demonstrate manufacturing processes for fabricating graphite filament reinforced polymide (Gr/PI) composite structural elements

NASA Technical Reports Server (NTRS)

Chase, V. A.; Harrison, E. S.

1985-01-01

A study was conducted to assess the merits of using graphite/polyimide, NR-150B2 resin, for structural applications on advanced space launch vehicles. The program was divided into two phases: (1) Fabrication Process Development; and (2) Demonstration Components. The first phase of the program involved the selection of a graphite fiber, quality assurance of the NR-150B2 polyimide resin, and the quality assurance of the graphite/polyimide prepreg. In the second phase of the program, a limited number of components were fabricated before the NR-150B2 resin system was removed from the market by the supplier, Du Pont. The advancement of the NR-150B2 polyimide resin binder was found to vary significantly based on previous time and temperature history during the prepregging operation. Strength retention at 316C (600F) was found to be 50% that of room temperature strength. However, the composite would retain its initial strength after 200 hours exposure at 316C (600F). Basic chemistry studies are required for determining NR-150B2 resin binder quality assurance parameters. Graphite fibers are available that can withstand high temperature cure and postcure cycles.

Space structures concepts and materials

NASA Technical Reports Server (NTRS)

Nowitzky, A. M.; Supan, E. C.

1988-01-01

An extension is preseted of the evaluation of graphite/aluminum metal matrix composites (MMC) for space structures application. A tubular DWG graphite/aluminum truss assembly was fabricated having the structural integrity and thermal stability needed for space application. DWG is a proprietary thin ply continuous graphite reinforced aluminum composite. The truss end fittings were constructed using the discontinuous ceramic particulate reinforced MMC DWAl 20 (trademark). Thermal stability was incorporated in the truss by utilizing high stiffness, negative coefficient of thermal expansion (CTE) P100 graphite fibers in a 6061 aluminum matrix, crossplied to provide minimized CTE in the assembled truss. Tube CTE was designed to be slightly negative to offset the effects of the end fitting and sleeve, CTE values of which are approx. 1/2 that of aluminum. In the design of the truss configuration, the CTE contribution of each component was evaluated to establish the component dimension and layup configuration required to provide a net zero CTE in the subassemblies which would then translate to a zero CTE for the entire truss bay produced.

Converting a carbon preform object to a silicon carbide object

NASA Technical Reports Server (NTRS)

Levin, Harry (Inventor)

1990-01-01

A process for converting in depth a carbon or graphite preform object to a silicon carbide object, silicon carbide/silicon object, silicon carbide/carbon-core object, or a silicon carbide/silicon/carbon-core object, by contacting it with silicon liquid and vapor over various lengths of contact time in a reaction chamber. In the process, a stream comprised of a silicon-containing precursor material in gaseous phase below the decomposition temperature of said gas and a coreactant, carrier or diluent gas such as hydrogen is passed through a hole within a high emissivity, thin, insulating septum into the reaction chamber above the melting point of silicon. The thin septum has one face below the decomposition temperature of the gas and an opposite face exposed to the reaction chamber. Thus, the precursor gas is decomposed directly to silicon in the reaction chamber. Any stream of decomposition gas and any unreacted precursor gas from the reaction chamber is removed. A carbon or graphite preform object placed in the reaction chamber is contacted with the silicon. The carbon or graphite preform object is recovered from the reactor chamber after it has been converted to a desired silicon carbide, silicon and carbon composition.

ELM elimination with lithium aerosol injection in upper-single null discharges using the tungsten divertor in EAST

NASA Astrophysics Data System (ADS)

Sun, Z.; Maingi, R.; Hu, J.; Lunsford, R.; Diallo, A.; Tritz, K.; Osborne, T.; Canik, J.; Zuo, G.; Wang, L.; Xu, G.; Gong, X.; EAST Team Team

2017-10-01

A reproducible, fully non-inductive H-mode regime devoid of large ELMs has been achieved by continuous Li injection in EAST into the upper `ITER-like' tungsten divertor, extending previous results on the graphite divertor. These discharges did not suffer from density or impurity accumulation, and maintained constant core radiated power. The new results extend the energy confinement multiplier H98(y,2) 1.2, as compared to H98(y,2) 0.75 previously on the graphite divertor. The observed ELM elimination is correlated with a decrease in particle recycling, as expected from the strong Li coating before the experiment, and real-time Li aerosol injection. In addition, core W concentration was reduced during the Li injection. ELM elimination is likely related to the reduced recycling and density /temperature profile changes. A low-n electromagnetic coherent mode (MCM) at 40kHz became stronger in amplitude and also more coherent. The MCM shows strong magnetic fluctuations as measured by fast Mirnov coils, but weak density fluctuations. As compared to the graphite divertor, Li injection into the tungsten divertor eliminated ELMs at twice the previous auxiliary heating power, and reduced pedestal collisionality.

Quantum confinement-induced tunable exciton states in graphene oxide.

PubMed

Lee, Dongwook; Seo, Jiwon; Zhu, Xi; Lee, Jiyoul; Shin, Hyeon-Jin; Cole, Jacqueline M; Shin, Taeho; Lee, Jaichan; Lee, Hangil; Su, Haibin

2013-01-01

Graphene oxide has recently been considered to be a potential replacement for cadmium-based quantum dots due to its expected high fluorescence. Although previously reported, the origin of the luminescence in graphene oxide is still controversial. Here, we report the presence of core/valence excitons in graphene-based materials, a basic ingredient for optical devices, induced by quantum confinement. Electron confinement in the unreacted graphitic regions of graphene oxide was probed by high resolution X-ray absorption near edge structure spectroscopy and first-principles calculations. Using experiments and simulations, we were able to tune the core/valence exciton energy by manipulating the size of graphitic regions through the degree of oxidation. The binding energy of an exciton in highly oxidized graphene oxide is similar to that in organic electroluminescent materials. These results open the possibility of graphene oxide-based optoelectronic device technology.

Fe{sub 2}O{sub 3} nanowires on HOPG as precursor of new carbon-based anode for high-capacity lithium ion batteries

DOE Office of Scientific and Technical Information (OSTI.GOV)

Angelucci, Marco; Frau, Eleonora; Betti, Maria Grazia

Iron Oxides nanostructures are very promising systems for new generation of anode material for Lithium-Ion batteries because of their high capacity associated to their surface area. A core-level photoemission study of Fe{sub 2}O{sub 3} nanowires deposited on highly-oriented pyrolitic graphite (HOPG) under Li exposure is presented. The Fe-2p, Fe-3p, and Li-1s core-level lineshape evolution upon Li exposure in ultra-high-vacuum conditions clearly brings to light the Fe ion reduction from fully trivalent to prevalently divalent at saturation. Furthermore, the graphite substrate allows allocation of a large amount of Li ions surrounding the iron-oxide nanowires, opening a new scenario towards the usemore » of graphene for improving the ionic charge exchange.« less

Electrocatalytic N-Doped Graphitic Nanofiber - Metal/Metal Oxide Nanoparticle Composites.

PubMed

Tang, Hongjie; Chen, Wei; Wang, Jiangyan; Dugger, Thomas; Cruz, Luz; Kisailus, David

2018-03-01

Carbon-based nanocomposites have shown promising results in replacing commercial Pt/C as high-performance, low cost, nonprecious metal-based oxygen reduction reaction (ORR) catalysts. Developing unique nanostructures of active components (e.g., metal oxides) and carbon materials is essential for their application in next generation electrode materials for fuel cells and metal-air batteries. Herein, a general approach for the production of 1D porous nitrogen-doped graphitic carbon fibers embedded with active ORR components, (M/MO x , i.e., metal or metal oxide nanoparticles) using a facile two-step electrospinning and annealing process is reported. Metal nanoparticles/nanoclusters nucleate within the polymer nanofibers and subsequently catalyze graphitization of the surrounding polymer matrix and following oxidation, create an interconnected graphite-metal oxide framework with large pore channels, considerable active sites, and high specific surface area. The metal/metal oxide@N-doped graphitic carbon fibers, especially Co 3 O 4 , exhibit comparable ORR catalytic activity but superior stability and methanol tolerance versus Pt in alkaline solutions, which can be ascribed to the synergistic chemical coupling effects between Co 3 O 4 and robust 1D porous structures composed of interconnected N-doped graphitic nanocarbon rings. This finding provides a novel insight into the design of functional electrocatalysts using electrospun carbon nanomaterials for their application in energy storage and conversion fields. © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Dynamical Core-Hole Screening in the X-Ray Absorption Spectra of Hydrogenated Carbon Nanotubes And Graphene

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wessely, O.; /Uppsala U. /Imperial Coll., London; Katsnelson, M.I.

2009-04-30

We have calculated the electronic structure and the x-ray absorption (XA) spectrum of a hydrogenated single graphite plane, in order to simulate recent experimental results on hydrogenated single wall carbon nanotubes (SWCNT) as well as hydrogenated graphene. We find that the presence of H induces a substantial component of sp{sup 3} bonding and as a result the {pi} and {pi}* components to the electronic structure vanish. We have calculated a theoretical x-ray absorption spectrum using a multiband version of the Mahan-Nozieres-De Dominicis theory. By making a fitting of the XA signal of C atoms that have H attached to themmore » and C atoms without H in the vicinity we obtain a good representation of the experimental data and we can draw the conclusion that in the experiments [A. Nikitin et al., Phys. Rev. Lett. 95, 225507 (2005)] some 35-50 % H have been absorbed in the SWCNT.« less

Understanding the reaction of nuclear graphite with molecular oxygen: Kinetics, transport, and structural evolution

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kane, Joshua J.; Contescu, Cristian I.; Smith, Rebecca E.

A thorough understanding of oxidation is important when considering the health and integrity of graphite components in graphite reactors. For the next generation of graphite reactors, HTGRs specifically, an unlikely air ingress has been deemed significant enough to have made its way into the licensing applications of many international licensing bodies. While a substantial body of literature exists on nuclear graphite oxidation in the presence of molecular oxygen and significant efforts have been made to characterize oxidation kinetics of various grades, the value of existing information is somewhat limited. Often, multiple competing processes, including reaction kinetics, mass transfer, and microstructuralmore » evolution, are lumped together into a single rate expression that limits the ability to translate this information to different conditions. This article reviews the reaction of graphite with molecular oxygen in terms of the reaction kinetics, gas transport, and microstructural evolution of graphite. It also presents the foundations of a model for the graphite-molecular oxygen reaction system that is kinetically independent of graphite grade, and is capable of describing both the bulk and local oxidation rates under a wide range of conditions applicable to air-ingress.« less

Understanding the reaction of nuclear graphite with molecular oxygen: Kinetics, transport, and structural evolution

DOE PAGES

Kane, Joshua J.; Contescu, Cristian I.; Smith, Rebecca E.; ...

2017-06-08

A thorough understanding of oxidation is important when considering the health and integrity of graphite components in graphite reactors. For the next generation of graphite reactors, HTGRs specifically, an unlikely air ingress has been deemed significant enough to have made its way into the licensing applications of many international licensing bodies. While a substantial body of literature exists on nuclear graphite oxidation in the presence of molecular oxygen and significant efforts have been made to characterize oxidation kinetics of various grades, the value of existing information is somewhat limited. Often, multiple competing processes, including reaction kinetics, mass transfer, and microstructuralmore » evolution, are lumped together into a single rate expression that limits the ability to translate this information to different conditions. This article reviews the reaction of graphite with molecular oxygen in terms of the reaction kinetics, gas transport, and microstructural evolution of graphite. It also presents the foundations of a model for the graphite-molecular oxygen reaction system that is kinetically independent of graphite grade, and is capable of describing both the bulk and local oxidation rates under a wide range of conditions applicable to air-ingress.« less

Evaluation of co-cokes from bituminous coal with vacuum resid or decant oil, and evaluation of anthracites, as precursors to graphite

NASA Astrophysics Data System (ADS)

Nyathi, Mhlwazi S.

2011-12-01

Graphite is utilized as a neutron moderator and structural component in some nuclear reactor designs. During the reactor operaction the structure of graphite is damaged by collision with fast neutrons. Graphite's resistance to this damage determines its lifetime in the reactor. On neutron irradiation, isotropic or near-isotropic graphite experiences less structural damage than anisotropic graphite. The degree of anisotropy in a graphite artifact is dependent on the structure of its precursor coke. Currently, there exist concerns over a short supply of traditional precursor coke, primarily due to a steadily increasing price of petroleum. The main goal of this study was to study the anisotropic and isotropic properties of graphitized co-cokes and anthracites as a way of investigating the possibility of synthesizing isotropic or near-isotropic graphite from co-cokes and anthracites. Demonstrating the ability to form isotropic or near-isotropic graphite would mean that co-cokes and anthracites have a potential use as filler material in the synthesis of nuclear graphite. The approach used to control the co-coke structure was to vary the reaction conditions. Co-cokes were produced by coking 4:1 blends of vacuum resid/coal and decant oil/coal at temperatures of 465 and 500 °C for reaction times of 12 and 18 hours under autogenous pressure. Co-cokes obtained were calcined at 1420 °C and graphitized at 3000 °C for 24 hours. Optical microscopy, X-ray diffraction, temperature-programmed oxidation and Raman spectroscopy were used to characterize the products. It was found that higher reaction temperature (500 °C) or shorter reaction time (12 hours) leads to an increase in co-coke structural disorder and an increase in the amount of mosaic carbon at the expense of textural components that are necessary for the formation of anisotropic structure, namely, domains and flow domains. Characterization of graphitized co-cokes showed that the quality, as expressed by the degree of graphitization and crystallite dimensions, of the final product is dependent on the nature of the precursor co-coke. The methodology for studying anthracites was to select two anthracites on basis of rank, PSOC1515 being semi-anthracite and DECS21 anthracite. The selected anthracites were graphitized, in both native and demineralized states, under the same conditions as co-cokes. Products obtained from DECS21 showed higher degrees of graphitization and larger crystallite dimensions than products obtained from PSOC1515. Demineralization of anthracites served to increase the degree of graphitization, indicating that the minerals contained in these anthracites have no graphitization-enhancing ability. A larger crystallite length for products obtained from native versions, compared to demineralized versions, was attributed to a formation and decomposition of a silicon carbide during graphitization of native versions. In order to examine the anisotropic and isotropic properties, nuclear-grade graphite samples obtained from Oak Ridge National Laboratory (ORNL) and commercial graphite purchased from Fluka were characterized under similar conditions as graphitized co-cokes and anthracites. These samples served as representatives of "two extremes", with ORNL samples being the isotropic end and commercial graphite being the anisotropic end. Through evaluating relationships between structural parameters, it was observed that graphitized co-cokes are situated, structurally, somewhere between the "two extremes", whereas graphitized anthracites are closer to the anisotropic end. Basically, co-cokes have a better potential than anthracites to transform to isotropic or near-isotropic graphite upon graphitization. By co-coking vacuum resid/coal instead of decant oil/coal or using 500 °C instead of 465 °C, a shift away from commercial graphite towards ORNL samples was attained. Graphitizing a semi-anthracite or demineralizing anthracites before graphitization also caused a shift towards ORNL samples.

Tomographic location of potential melt-bearing phenocrysts in lunar glass spherules

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ebel, D.S.; Fogel, R.A.; Rivers, M.L.

2005-02-04

Apollo 17 orange glass spherules contain olivine phenocrysts with melt inclusions from depth. Tomography (<2micron/pxl) of >200 spherules located 1 phenocryst. We will try to find melt inclusions and obtain original magma volatiles and compositions. In 1971, Apollo 17 astronauts collected a 10 cm soil sample (74220) comprised almost entirely of orange glass spherules. Below this, a double drive-tube core sampled a 68 cm thick horizon comprised of orange glass and black beads (crystallized equivalents of orange glass). Primitive lunar glass spherules (e.g.-A17 orange glasses) are thought to represent ejecta from lunar mare fire fountains. The fire-fountains were apparently drivenmore » by a combination of C-O gas exsolution from orange glass melt and the oxidation of graphite. Upon eruption, magmas lost their volatiles (e.g., S, CO, CO{sub 2}) to space. Evidence for volatile escape remains as volatile-rich coatings on the exteriors of many spherules. Moreover, it showed that Type I and II Fe-Ni-rich metal particles found within orange glass olivine phenocrysts, or free-floating in the glass itself, are powerful evidence for the volatile driving force for lunar fire fountains. More direct evidence for the volatile mechanism has yet to be uncovered. Issues remaining include: the exact composition of magmatic volatiles; the hypothesized existence of graphite in the magma; the oxygen fugacity of the magma and of the lunar interior. In 1996 reported a single {approx}450 micron, equant olivine phenocryst, containing four glassy melt inclusions (or inclusion cores), the largest {approx}30micron in size, in a thin section of the 74001/2 drill core. The melt is assumed to sample the parent magma of the lunar basalts at depth, evidenced by the S content of the inclusion (600 ppm) which is 400 ppm greater than that of the orange glass host. Such melts potentially contain a full complement of the volatile components of the parent magma, which can be analyzed by infrared spectroscopy. Although the A17 orange glass magma is thought to derive from {approx} 400 km depth, the calculations imply a 4 km depth of graphite oxidation (and melt saturation in C-O volatiles) during ascent. We have imaged several hundred similar orange glass spherules, from sample 74220,764, using synchrotron x-ray computer-aided microtomography (XRCMT). Our goals: (1) locate similar phenocrysts containing melt inclusions; (2) analyze phenocrysts to understand the evolution of the magma; (3) analyze melt and fluid inclusions using EPMA and FTIR to obtain direct evidence of magmatic volatiles and pristine bulk compositions.« less

CMB-13 research on carbon and graphite

NASA Technical Reports Server (NTRS)

Smith, M. C.

1972-01-01

The effects of grinding on Santa Maria coke are considered, as well as the production of resin-bonded graphite from the coke. Kynol fibers, properties and purities of coal tar pitches, carbonization of resin components, synthesis of gamma BL (4-furfuryl 2-pentenoic acid gamma lactone), and a glass-like carbon powder for use as a filler are also discussed. The hydrogen contents of commercial cokes and graphites are tabulated, and a quantimet image-analyzing computer and its operation are described.

Pyrolytic graphite collector development program

NASA Technical Reports Server (NTRS)

Wilkins, W. J.

1982-01-01

Pyrolytic graphite promises to have significant advantages as a material for multistage depressed collector electrodes. Among these advantages are lighter weight, improved mechanical stiffness under shock and vibration, reduced secondary electron back-streaming for higher efficiency, and reduced outgassing at higher operating temperatures. The essential properties of pyrolytic graphite and the necessary design criteria are discussed. This includes the study of suitable electrode geometries and methods of attachment to other metal and ceramic collector components consistent with typical electrical, thermal, and mechanical requirements.

Low cost damage tolerant composite fabrication

NASA Technical Reports Server (NTRS)

Palmer, R. J.; Freeman, W. T.

1988-01-01

The resin transfer molding (RTM) process applied to composite aircraft parts offers the potential for using low cost resin systems with dry graphite fabrics that can be significantly less expensive than prepreg tape fabricated components. Stitched graphite fabric composites have demonstrated compression after impact failure performance that equals or exceeds that of thermoplastic or tough thermoset matrix composites. This paper reviews methods developed to fabricate complex shape composite parts using stitched graphite fabrics to increase damage tolerance with RTM processes to reduce fabrication cost.

Method for depositing a uniform layer of particulate material on the surface of an article having interconnected porosity

DOEpatents

Wrenn, Jr., George E.; Lewis, Jr., John

1984-01-01

The invention is a method for depositing liquid-suspended particles on an immersed porous article characterized by interconnected porosity. In one form of the invention, coating is conducted in a vessel containing an organic liquid supporting a colloidal dispersion of graphite sized to lodge in surface pores of the article. The liquid comprises a first volatile component (e.g., acetone) and a second less-volatile component (e.g., toluene) containing a dissolved organic graphite-bonding agent. The liquid also contains an organic agent (e.g., cellulose gum) for maintaining the particles in suspension. A porous carbon article to be coated is immersed in the liquid so that it is permeated therewith. While the liquid is stirred to maintain a uniform blend, the vessel headspace is evacuated to effect flashing-off of the first component from the interior of the article. This causes particle-laden liquid exterior of the article to flow inwardly through its surface pores, lodging particles in these pores and forming a continuous graphite coating. The coated article is retrieved and heated to resin-bond the graphite. The method can be used to form a smooth, adherent, continuous coating of various materials on various porous articles. The method is rapid and reproducible.

Method for depositing a uniform layer of particulate material on the surface of an article having interconnected porosity

DOEpatents

Wrenn, G.E. Jr.; Lewis, J. Jr.

1982-09-29

The invention is a method for depositing liquid-suspended particles on an immersed porous article characterized by interconnected porosity. In one form of the invention, coating is conducted in a vessel containing an organic liquid supporting a colloidal dispersion of graphite sized to lodge in surface pores of the article. The liquid comprises a first volatile component (e.g., acetone) and a second less-volatile component (e.g., toluene) containing a dissolved organic graphite-bonding agent. The liquid also contains an organic agent (e.g., cellulose gum) for maintaining the particles in suspension. A porous carbon article to be coated is immersed in the liquid so that it is permeated therewith. While the liquid is stirred to maintain a uniform blend, the vessel headspace is evacuated to effect flashing-off of the first component from the interior of the article. This causes particle-laden liquid exterior of the article to flow inwardly through its surface pores, lodging particles in these pores and forming a continuous graphite coating. The coated article is retrieved and heated to resin-bond the graphite. The method can be used to form a smooth, adherent, continuous coating of various materials on various porous articles. The method is rapid and reproducible.

Adhesive properties and adhesive joints strength of graphite/epoxy composites

NASA Astrophysics Data System (ADS)

Rudawska, Anna; Stančeková, Dana; Cubonova, Nadezda; Vitenko, Tetiana; Müller, Miroslav; Valášek, Petr

2017-05-01

The article presents the results of experimental research of the adhesive joints strength of graphite/epoxy composites and the results of the surface free energy of the composite surfaces. Two types of graphite/epoxy composites with different thickness were tested which are used to aircraft structure. The single-lap adhesive joints of epoxy composites were considered. Adhesive properties were described by surface free energy. Owens-Wendt method was used to determine surface free energy. The epoxy two-component adhesive was used to preparing the adhesive joints. Zwick/Roell 100 strength device were used to determination the shear strength of adhesive joints of epoxy composites. The strength test results showed that the highest value was obtained for adhesive joints of graphite-epoxy composite of smaller material thickness (0.48 mm). Statistical analysis of the results obtained, the study showed statistically significant differences between the values of the strength of the confidence level of 0.95. The statistical analysis of the results also showed that there are no statistical significant differences in average values of surface free energy (0.95 confidence level). It was noted that in each of the results the dispersion component of surface free energy was much greater than polar component of surface free energy.

Binary gaseous mixture and single component adsorption of methane and argon on exfoliated graphite

NASA Astrophysics Data System (ADS)

Russell, Brice Adam

Exfoliated graphite was used as a substrate for adsorption of argon and methane. Adsorption experiments were conducted for both equal parts mixtures of argon and methane and for each gas species independently. The purpose of this was to compare mixture adsorption to single component adsorption and to investigate theoretical predictions concerning the kinetics of adsorption made by Burde and Calbi.6 In particular, time to reach pressure equilibrium of a single dose at a constant temperature for the equal parts mixture was compared to time of adsorption for each species by itself. It was shown that mixture adsorption is a much more complex and time consuming process than single component adsorption and requires a much longer amount of time to reach equilibrium. Information about the composition evolution of the mixture during the times when pressure was going toward equilibrium was obtained using a quadrupole mass spectrometer. Evidence for initial higher rate of adsorption for the weaker binding energy species (argon) was found as well as overall composition change which clearly indicated a higher coverage of methane on the graphite sample by the time equilibration was reached. Effective specific surface area of graphite for both argon and methane was also determined using the Point-B method.2

Examination of Surface Deposits on Oldbury Reactor Core Graphite to Determine the Concentration and Distribution of 14C.

PubMed

Payne, Liam; Heard, Peter J; Scott, Thomas B

2016-01-01

Pile Grade A graphite was used as a moderator and reflector material in the first generation of UK Magnox nuclear power reactors. As all of these reactors are now shut down there is a need to examine the concentration and distribution of long lived radioisotopes, such as 14C, to aid in understanding their behaviour in a geological disposal facility. A selection of irradiated graphite samples from Oldbury reactor one were examined where it was observed that Raman spectroscopy can distinguish between underlying graphite and a surface deposit found on exposed channel wall surfaces. The concentration of 14C in this deposit was examined by sequentially oxidising the graphite samples in air at low temperatures (450°C and 600°C) to remove the deposit and then the underlying graphite. The gases produced were captured in a series of bubbler solutions that were analysed using liquid scintillation counting. It was observed that the surface deposit was relatively enriched with 14C, with samples originating lower in the reactor exhibiting a higher concentration of 14C. Oxidation at 600°C showed that the remaining graphite material consisted of two fractions of 14C, a surface associated fraction and a graphite lattice associated fraction. The results presented correlate well with previous studies on irradiated graphite that suggest there are up to three fractions of 14C; a readily releasable fraction (corresponding to that removed by oxidation at 450°C in this study), a slowly releasable fraction (removed early at 600°C in this study), and an unreleasable fraction (removed later at 600°C in this study).

Examination of Surface Deposits on Oldbury Reactor Core Graphite to Determine the Concentration and Distribution of 14C

PubMed Central

Payne, Liam; Heard, Peter J.; Scott, Thomas B.

2016-01-01

Pile Grade A graphite was used as a moderator and reflector material in the first generation of UK Magnox nuclear power reactors. As all of these reactors are now shut down there is a need to examine the concentration and distribution of long lived radioisotopes, such as 14C, to aid in understanding their behaviour in a geological disposal facility. A selection of irradiated graphite samples from Oldbury reactor one were examined where it was observed that Raman spectroscopy can distinguish between underlying graphite and a surface deposit found on exposed channel wall surfaces. The concentration of 14C in this deposit was examined by sequentially oxidising the graphite samples in air at low temperatures (450°C and 600°C) to remove the deposit and then the underlying graphite. The gases produced were captured in a series of bubbler solutions that were analysed using liquid scintillation counting. It was observed that the surface deposit was relatively enriched with 14C, with samples originating lower in the reactor exhibiting a higher concentration of 14C. Oxidation at 600°C showed that the remaining graphite material consisted of two fractions of 14C, a surface associated fraction and a graphite lattice associated fraction. The results presented correlate well with previous studies on irradiated graphite that suggest there are up to three fractions of 14C; a readily releasable fraction (corresponding to that removed by oxidation at 450°C in this study), a slowly releasable fraction (removed early at 600°C in this study), and an unreleasable fraction (removed later at 600°C in this study). PMID:27706228

EXPERIMENTAL LIQUID METAL FUEL REACTOR

DOEpatents

Happell, J.J.; Thomas, G.R.; Denise, R.P.; Bunts, J.L. Jr.

1962-01-23

A liquid metal fuel nuclear fission reactor is designed in which the fissionable material is dissolved or suspended in a liquid metal moderator and coolant. The liquid suspension flows into a chamber in which a critical amount of fissionable material is obtained. The fluid leaves the chamber and the heat of fission is extracted for power or other utilization. The improvement is in the support arrangement for a segrnented graphite core to permit dif ferential thermal expansion, effective sealing between main and blanket liquid metal flows, and avoidance of excessive stress development in the graphite segments. (AEC)

Fabrication and characterization of tapered graphite/epoxy box beams

NASA Astrophysics Data System (ADS)

Yen, S.-C.; Gopal, P.; Dharani, L. R.

1993-04-01

Graphite/epoxy (T300/934) prepreg is used to fabricate tapered box beams with a taper angle of 2 deg between the top and bottom walls. The prepreg is cured on a segmented steel core using a hot-press. A screw arrangement is used to apply curing pressure in the horizontal direction, while the platens of the hot-press apply pressure in the vertical direction. The inplane bending stiffness of the beam is determined by 3-point bend test and is found to be in agreement with theory.

Neutronics Analyses of the Minimum Original HEU TREAT Core

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kontogeorgakos, D.; Connaway, H.; Yesilyurt, G.

2014-04-01

This work was performed to support the feasibility study on the potential conversion of the Transient Reactor Test Facility (TREAT) at Idaho National Laboratory from the use of high-enriched uranium (HEU) fuel to the use of low-enriched uranium (LEU) fuel. The analyses were performed by the GTRI Reactor Conversion staff at the Argonne National Laboratory (ANL). The objective of this study was to validate the MCNP model of the TREAT reactor with the well-documented measurements which were taken during the start-up and early operation of TREAT. Furthermore, the effect of carbon graphitization was also addressed. The graphitization level was assumedmore » to be 100% (ANL/GTRI/TM-13/4). For this purpose, a set of experiments was chosen to validate the TREAT MCNP model, involving the approach to criticality procedure, in-core neutron flux measurements with foils, and isothermal temperature coefficient and temperature distribution measurements. The results of this study extended the knowledge base for the TREAT MCNP calculations and established the credibility of the MCNP model to be used in the core conversion feasibility analysis.« less

The structural behavior of a graphite-polymide honeycomb sandwich panel with quasi-isotropic face sheets and an orthotropic core

NASA Technical Reports Server (NTRS)

Hyer, M. W.; Hagaman, J. A.

1979-01-01

The results of a series of tests of graphite-polyimide honeycomb sandwich panels are presented. The panels were 1.22 m long, 0.508 m wide, and approximately 13.3 m thick. The face sheets were a T-300/PMR-15 fabric in a quasi-isotropic layup and were 0.279 mm thick. The core was Hexcel HRH 327-3/16 - 4.0 glass reinforced polyimide honeycomb, 12.7 mm thick. Three panels were used in the test: one was cut into smaller pieces for testing as beam, compression, and shear specimens; a second panel was used for plate bending tests; the third panel was used for in-plane stability tests. Presented are the experimental results of four point bending tests, short block compression tests, core transverse shear modulus, three point bending tests, vibration tests, plate bending tests, and panel stability tests. The results of the first three tests are used to predict the results of some of the other tests. The predictions and experimental results are compared, and the agreement is quite good.

Feasibility Study of Graphite Epoxy Antenna for a Microwave Limb Sounder Radiometer (MLSR)

NASA Technical Reports Server (NTRS)

1979-01-01

Results are presented of a feasibility study to design graphite epoxy antenna reflectors for a jet propulsion laboratory microwave limb sounder instrument (MLSR). Two general configurations of the offset elliptic parabolic reflectors are presented that will meet the requirements on geometry and reflector accuracy. The designs consist of sandwich construction for the primary reflectors, secondary reflector support structure and cross-tie members between reflector pairs. Graphite epoxy materials of 3 and 6 plies are used in the facesheets of the sandwich. An aluminum honeycomb is used for the core. A built-in adjustment system is proposed to reduce surface distortions during assembly. The manufacturing and environmental effects are expected to result in surface distortions less than .0015 inch and pointing errors less than .002 degree.

Overview of physics goals for OP1.2a on Wendelstein 7-X

NASA Astrophysics Data System (ADS)

Pedersen, Thomas Sunn; W7-X Team

2017-10-01

Wendelstein 7-X achieved, and in many cases exceeded, the pre-defined goals for its first operation phase, OP1.1. Results include core values of Te = 8 keV, Ti = 2 keV and ne>3*1019 m-3 and confinement times of 100-150 ms. The next operation phase, OP1.2a, scheduled to start in fall 2017, features a much more elaborate set of plasma-facing components. 10 inertially cooled graphite test divertor units (TDU) have been installed, as have graphite tiles on all the heat shields and baffles. Upgrades have also been made to heating systems, diagnostics, and particle fueling systems. This will allow for significantly increased pulse lengths, heating power and plasma performance, in particular, higher plasma density, and higher ion temperatures, thereby enabling a much more detailed investigation of the W7-X optimization and significantly higher triple products than achieved in OP1.1. The robustness of the TDU allows for an aggressive exploration of divertor operation scenarios in this phase. The main goals and plans, and, if available, first results of OP1.2a will be presented. This work has been carried out within the framework of the EUROfusion Consortium and has received funding from the Euratom research and training programme 2014-2018 under Grant agreement No 633053.

Fluid-deposited graphitic inclusions in quartz: Comparison between KTB (German Continental Deep-Drilling) core samples and artificially reequilibrated natural inclusions

USGS Publications Warehouse

Pasteris, J.D.; Chou, I.-Ming

1998-01-01

We used Raman microsampling spectroscopy (RMS) to determine the degree of crystallinity of minute (2-15 ??m) graphite inclusions in quartz in two sets of samples: experimentally reequilibrated fluid inclusions in a natural quartz grain and biotite-bearing paragneisses from the KTB deep drillhole in SE Germany. Our sequential reequilibration experiments at 725??C on initially pure CO2 inclusions in a quartz wafer and the J. Krautheim (1993) experiments at 900-1100??C on organic compounds heated in gold or platinum capsules suggest that, at a given temperature, (1) fluid-deposited graphite will have a lower crystallinity than metamorphosed organic matter and (2) that the crystallinity of fluid-deposited graphite is affected by the composition of the fluid from which it was deposited. We determined that the precipitation of more-crystalline graphite is favored by lower fH2 (higher fO2), and that the crystallinity of graphite is established by the conditions (including gas fugacities) that pertain as the fluid first reaches graphite saturation. Graphite inclusions within quartz grains in the KTB rocks show a wide range in crystallinity index, reflecting three episodes of carbon entrapment under different metamorphic conditions. Isolated graphite inclusions have the spectral properties of totally ordered, completely crystalline graphite. Such crystallinity suggests that the graphite was incorporated from the surrounding metasedimentary rocks, which underwent metamorphism at upper amphibolite-facies conditions. Much of the fluid-deposited graphite in fluid inclusions, however, shows some spectral disorder. The properties of that graphite resemble those of experimental precipitates at temperatures in excess of 700??C and at elevated pressures, suggesting that the inclusions represent precipitates from C-O-H fluids trapped under conditions near those of peak metamorphism at the KTB site. In contrast, graphite that is intimately associated with chlorite and other (presumably low-temperature) silicates in inclusions is highly disordered and spectrally resembles kerogens. This graphite probably was deposited during later greenschist-facies retrograde metamorphism at about 400-500??C. The degree of crystallinity of fluid-deposited graphite is shown to be a much more complex function of temperature than is the crystallinity of metamorphic graphite. To some extent, experiments can provide temperature-calibration of the crystallinity index. However, the difference in time scales between experimental runs and geologic processes makes it difficult to infer specific temperatures for naturally precipitated graphite. Copyright ?? 1998 Elsevier Science Ltd.

Constraints on Ureilite Petrogenesis and Carbon-Metal-Silicate Equilibria on the UPB

NASA Astrophysics Data System (ADS)

Goodrich, C. A.; Holloway, J. R.

1992-07-01

The most important constraints on models of ureilite petrogenesis are 1) Ureilites have lost a basaltic complement (they are ultramafic, extremely depleted in plagiophile elements, enriched in HREE, and have negative Eu anomalies and superchondritic Ca/Al ratios). 2) Ureilites experienced long equilibration times at high T (indicated by coarse grain size, extreme homogeneity of core crystals, correlations between olivine and pyroxene compositions, and metamorphic-like textures), followed by rapid cooling (indicated by structural features of pyroxene and narrow reduction rims on olivine). 3) Ureilites are probably residues (based on mass balance) but partly crystallized from melts. 4) Ureilites are derived from a minimum of six reservoirs that were distinct in oxygen isotopic composition and did not equilibrate with one another (this is consistent with the observation that olivine and pyroxene cores do not show correlations of mg with MnO, Cr2O3, Sm/Eu or Lu/Eu). 5) There is a correlation between oxygen isotopic composition and mg ratio in ureilites. Similar correlations are observed for Allende chondrules and group means of H3-L3-LL3 chondrites (Fig. 1), and are argued to result from nebular processes [1]. 6) If graphite-metal-silicate-CO/CO2 equilibrium was established during melting, then mg ratios of ureilites were determined by depth because CCO redox reactions are strongly pressure-dependent. Cohenite-bearing metallic spherule inclusions in the silicates and euhedral shapes of large graphite crystals in low-shock ureilites have been taken as evidence of equilibrium. Olivine reduction rims, highly variable interstitial metal compositions, and a lack of correlation between mg and metal content argue against equilibrium. 7) Ureilites either lost a low melting-T metal fraction or gained a refractory-rich metal component. (they have high abundances of siderophile elements but show fractionation between [Os, Ir, W, Re] and [Ni, Ga, Ge, Au]). 8) Primordial noble gases were retained in some carbon phases. 9) Ureilites formed at ~4.55 Ga but both Sm-Nd and Rb-Sr isotopic systematics have been subsequently disturbed. Constraints 1-4 are best met if ureilites are partial melt residues produced by ~25% equilibrium partial melting on an oxygen-isotopically heterogeneous parent body in >=6 distinct melting zones. If there was no global magma ocean, km-sized melting zones would not equilibrate oxygen with one another in 10 m.y. Constraints 5 and 6 appear difficult to reconcile. If the UPB inherited a nebular oxygen isotope-mg correlation how could this correlation have survived partial melting? If the melting zones all experienced approximately the same degree of melting (Mn/Mg, Cr/Mg, and HRE provide evidence for this), and silicate equilibria determined mg, then the original correlation may simply have shifted to higher mg, consistent with the position of the ureilite trend relative to the Allende trends (Fig. 1). However, if mg was depth-dependent then it is unlikely that any oxygen isotope-mg correlation would remain. Also, noble gases in carbon would be lost (violating constraint 8) during carbon redox reactions. All constraints would be better met if graphite-metal-silicate-CO/CO2 equilibrium was not established during partial melting. If graphite was primary but a CO/CO2 fluid phase was not present then there would have been no pressure/depth dependence of fO(sub)2. As long as the pressure was sufficiently high (~100-200 bars) to stabilize the most ferroan ureilite (Fo 76) then the more magnesian ureilites would have been stable in the presence of graphite and metal. On the other hand, constraints 7, 8, and 9 could be neatly met if most of the carbon was not primary but a carbon-metal-noble gas assemblage was added as a late component to the ultramafic rocks. The cohenite-bearing metallic spherules are rare and tiny (10-50 micrometers) compared to interstitial metal (mm-sized irregular grains). They appear to have been droplets of immiscible, hypereutectic Fe(Ni)-C liquids that were trapped by crystallizing silicates. In contrast, the interstitial metal and graphite show no evidence of having been a liquid Fe-C alloy and their confinement to grain boundaries and reduction rims is consistent with late addition. Goodrich and Berkley (2) argued that the spherules were carbon-saturated at 1200-1225 degrees C and therefore that the silicate liquid must have contained graphite. However, in the Fe-C system the stable graphite liquidus is much steeper than the metastable cohenite liquidus, and although these alloys were cohenite-saturated, they were not graphite-saturated. Hence, the silicate magma probably did not contain graphite and carbon was not the dominant control on fO(sub)2. Thus, it may be possible to reconcile the main constraints on ureilite petrogenesis without high pressures. [1] R.N. Clayton & T.K. Mayeda (1988] GCA 52, 1313. [2] C.A. Goodrich & J.L. Berkely (1986) GCA 50, 681.

Fabrication and magnetic properties of Ni nanospheres encapsulated in a fullerene-like carbon.

PubMed

Pol, S V; Pol, V G; Frydman, A; Churilov, G N; Gedanken, A

2005-05-19

A very simple, efficient, and economical synthetic technique, which produces fascinating fullerene-like Ni-C (graphitic) core-shell nanostructures at a relatively low temperature, is reported. The thermal dissociation of Ni acetylacetonate is carried out in a closed vessel cell (Swagelok) that was heated at 700 degrees C for 3 h. The encapsulation of ferromagnetic Ni nanospheres into the onion structured graphitic layers is obtained in a one-stage, single precursor reaction, without a catalyst, that possesses interesting magnetic properties. The magnetoresistance (MR) property of Ni nanospheres encapsulated in a fullerene-like carbon was measured, which shows large negative MR, of the order of 10%. The proposed mechanism for the formation of the Ni-C core-shell system is based on the segregation and the surface flux formed in the Ni and carbon particles during the reaction under autogenic pressure at elevated temperature.

Quantum confinement-induced tunable exciton states in graphene oxide

PubMed Central

Lee, Dongwook; Seo, Jiwon; Zhu, Xi; Lee, Jiyoul; Shin, Hyeon-Jin; Cole, Jacqueline M.; Shin, Taeho; Lee, Jaichan; Lee, Hangil; Su, Haibin

2013-01-01

Graphene oxide has recently been considered to be a potential replacement for cadmium-based quantum dots due to its expected high fluorescence. Although previously reported, the origin of the luminescence in graphene oxide is still controversial. Here, we report the presence of core/valence excitons in graphene-based materials, a basic ingredient for optical devices, induced by quantum confinement. Electron confinement in the unreacted graphitic regions of graphene oxide was probed by high resolution X-ray absorption near edge structure spectroscopy and first-principles calculations. Using experiments and simulations, we were able to tune the core/valence exciton energy by manipulating the size of graphitic regions through the degree of oxidation. The binding energy of an exciton in highly oxidized graphene oxide is similar to that in organic electroluminescent materials. These results open the possibility of graphene oxide-based optoelectronic device technology. PMID:23872608

Baking and helium glow discharge cleaning of SST-1 Tokamak with graphite plasma facing components

NASA Astrophysics Data System (ADS)

Semwal, P.; Khan, Z.; Raval, D. C.; Dhanani, K. R.; George, S.; Paravastu, Y.; Prakash, A.; Thankey, P.; Ramesh, G.; Khan, M. S.; Saikia, P.; Pradhan, S.

2017-04-01

Graphite plasma facing components (PFCs) were installed inside the SST-1 vacuum vessel. Prior to installation, all the graphite tiles were baked at 1000 °C in a vacuum furnace operated below 1.0 × 10-5 mbar. However due to the porous structure of graphite, they absorb a significant amount of water vapour from air during the installation process. Rapid desorption of this water vapour requires high temperature bake-out of the PFCs at ≥ 250 °C. In SST-1 the PFCs were baked at 250 °C using hot nitrogen gas facility to remove the absorbed water vapour. Also device with large graphite surface area has the disadvantage that a large quantity of hydrogen gets trapped inside it during plasma discharges which makes density control difficult. Helium glow discharge cleaning (He-GDC) effectively removes this stored hydrogen as well as other impurities like oxygen and hydrocarbon within few nano-meters from the surface by particle induced desorption. Before plasma operation in SST-1 tokamak, both baking of PFCs and He-GDC were carried out so that these impurities were removed effectively. The mean desorption yield of hydrogen was found to be 0.24. In this paper the results of baking and He-GDC experiments of SST-1 will be presented in detail.

Development of a portable graphite calorimeter for radiation dosimetry.

PubMed

Sakama, Makoto; Kanai, Tatsuaki; Fukumura, Akifumi

2008-01-01

We developed and performance-tested a portable graphite calorimeter designed to measure the absolute dosimetry of various beams including heavy-ion beams, based on a flexible and convenient means of measurement. This measurement system is fully remote-controlled by the GPIB system. This system uses a digital PID (Proportional, Integral, Derivative) control method based on the LabVIEW software. It was possible to attain stable conditions in a shorter time by this system. The standard deviation of the measurements using the calorimeter was 0.79% at a dose rate of 0.8 Gy/min in 17 calorimeter runs for a (60)Co photon beam. The overall uncertainties for the absorbed dose to graphite and water of the (60)Co photon beam using the developed calorimeter were 0.89% and 1.35%, respectively. Estimations of the correction factors due to vacuum gaps, impurities in the core, the dose gradient and the radiation profile were included in the uncertainties. The absorbed doses to graphite and water irradiated by the (60)Co photon beam were compared with dosimetry measurements obtained using three ionization chambers. The absorbed doses to graphite and water estimated by the two dosimetry methods agreed within 0.1% and 0.3%, respectively.

All about the Pencil

ERIC Educational Resources Information Center

Stevens, Sue

2006-01-01

This article presents the history of pencils. Graphite, which is the main component that makes pencils write, was first discovered to be useful in marking the sheep of local farmers in Borrowdale, England in 1954. This graphite left a much darker mark than lead, which made it ideal for use by writers and artists. Around, 1795, Nicolas-Jacques…

Graphitic biocarbon from metal-catalyzed hydrothermal carbonization of lignin

DOE PAGES

Demir, Muslum; Kahveci, Zafer; Aksoy, Burak; ...

2015-10-09

Lignin is a high-volume byproduct from the pulp and paper industry and is currently burned to generate electricity and process heat. Moreover, the industry has been searching for high value-added uses of lignin to improve the process economics. In addition, battery manufacturers are seeking nonfossil sources of graphitic carbon for environmental sustainability. In our work, lignin (which is a cross-linked polymer of phenols, a component of biomass) is converted into graphitic porous carbon using a two-step conversion. Lignin is first carbonized in water at 300 °C and 1500 psi to produce biochar, which is then graphitized using a metal nitratemore » catalyst at 900–1100 °C in an inert gas at 15 psi. Graphitization effectiveness of three different catalysts—iron, cobalt, and manganese nitrates—is examined. The product is analyzed for morphology, thermal stability, surface properties, and electrical conductivity. Both temperature and catalyst type influenced the degree of graphitization. A good quality graphitic carbon was obtained using catalysis by Mn(NO 3) 2 at 900 °C and Co(NO 3) 2 at 1100 °C.« less

Property-based design: optimization and characterization of polyvinyl alcohol (PVA) hydrogel and PVA-matrix composite for artificial cornea.

PubMed

Jiang, Hong; Zuo, Yi; Zhang, Li; Li, Jidong; Zhang, Aiming; Li, Yubao; Yang, Xiaochao

2014-03-01

Each approach for artificial cornea design is toward the same goal: to develop a material that best mimics the important properties of natural cornea. Accordingly, the selection and optimization of corneal substitute should be based on their physicochemical properties. In this study, three types of polyvinyl alcohol (PVA) hydrogels with different polymerization degree (PVA1799, PVA2499 and PVA2699) were prepared by freeze-thawing techniques. After characterization in terms of transparency, water content, water contact angle, mechanical property, root-mean-square roughness and protein adsorption behavior, the optimized PVA2499 hydrogel with similar properties of natural cornea was selected as a matrix material for artificial cornea. Based on this, a biomimetic artificial cornea was fabricated with core-and-skirt structure: a transparent PVA hydrogel core, surrounding by a ringed PVA-matrix composite skirt that composed of graphite, Fe-doped nano hydroxyapatite (n-Fe-HA) and PVA hydrogel. Different ratio of graphite/n-Fe-HA can tune the skirt color from dark brown to light brown, which well simulates the iris color of Oriental eyes. Moreover, morphologic and mechanical examination showed that an integrated core-and-skirt artificial cornea was formed from an interpenetrating polymer network, no phase separation appeared on the interface between the core and the skirt.

Century-scale high-resolution black carbon records in sediment cores from the South Yellow Sea, China

NASA Astrophysics Data System (ADS)

Xu, Xiaoming; Hong, Yuehui; Zhou, Qianzhi; Liu, Jinzhong; Yuan, Lirong; Wang, Jianghai

2018-01-01

Black carbon (BC) has received increasing attention in the last 20 years because it is not only an absorbent of toxic pollutants but also a greenhouse substance, preserving fire-history records, and more importantly, acting as an indicator of biogeochemical cycles and global changes. By adopting an improved chemothermal oxidation method (WXY), this study reconstructed the century-scale high-resolution records of BC deposition from two fine-grained sediment cores collected from the Yellow Sea Cold Water Mass in the South Yellow Sea. The BC records were divided into five stages, which exhibited specific sequences with three BC peaks at approximately 1891, 1921, and 2007 AD, representing times at which the first heavy storms appeared just after the termination of long-term droughts. The significant correlation between the times of the BC peaks in the cores and heavy storms in the area of the Huanghe (Yellow) River demonstrated that BC peaks could result from markedly strengthened sedimentation due to surface runoff, which augmented the atmospheric deposition. Stable carbon isotope analysis indicated that the evident increase in carbon isotope ratios of BC in Stage 5 might have resulted from the input of weathered rock-derived graphitic carbon cardinally induced by the annual anthropogenic modulation of water-borne sediment in the Huanghe River since 2005 AD. Numerical calculations demonstrated that the input fraction of graphitic carbon was 22.97% for Stage 5, whereas no graphitic carbon entered during Stages 1 and 3. The obtained data provide new and important understanding of the source-sink history of BC in the Yellow Sea.

X-ray photoelectron spectroscopic and morphologic studies of Ru nanoparticles deposited onto highly oriented pyrolytic graphite

NASA Astrophysics Data System (ADS)

Bavand, R.; Yelon, A.; Sacher, E.

2015-11-01

Ruthenium nanoparticles (Ru NPs) function as effective catalysts in specific reactions, such as methanation and Fischer-Tropsch syntheses. It is our purpose to physicochemically characterize their surfaces, at which catalysis occurs, by surface-sensitive X-ray photoelectron spectroscopy (XPS), using the symmetric peak component anaylsis technique developed in our laboratory to reveal previously hidden components. Ru NPs were deposited by evaporation (0.25-1.5 nm nominal deposition range) onto highly oriented pyrolytic graphite (HOPG). In addition to their surfaces being characterized by XPS, an indication of morphology was obtained from transmission electron microscopy (TEM). Our use of symmetric peak component XPS analysis has revealed detailed information on a previously unidentified surface oxide initially formed, as well as on the valence electronic structure and its variation with NP size, information that is of potential importance in the use of these NPs in catalysis. Each of the several Ru core XPS spectra characterized (3d, 3p and 3s) was found to be composed of three symmetric components. Together with two metal oxide O1s components, these give evidence of a rather complex, previously unidentified oxide that is initially formed. The Ru valence band (4d and 5s) spectra clearly demonstrate a loss of metallicity, a simultaneous increase of the Kubo gap, and an abrupt transfer in valence electron density from the 4d to the 5s orbitals (known as electron spill-over), as the NP size decreases below 0.5 nm. TEM photomicrographs, as a function of deposition rate, show that, at a rate that gives insufficient time for the NP condensation energy to dissipate, the initially well-separated NPs are capable of diffusing laterally and aggregating. This indicates weak NP bonding to the HOPG substrate. Carbide is formed, at both high and low deposition rates, at Ru deposition thicknesses greater than 0.25 nm, its formation explained by Ru NPs reacting with residual hydrocarbon vapor, under the influence of the heat of condensation released on Ru deposition, and not by Ru reacting with the HOPG substrate.

Recompressed exfoliated graphite articles

DOEpatents

Zhamu, Aruna; Shi, Jinjun; Guo, Jiusheng; Jang, Bor Z

2013-08-06

This invention provides an electrically conductive, less anisotropic, recompressed exfoliated graphite article comprising a mixture of (a) expanded or exfoliated graphite flakes; and (b) particles of non-expandable graphite or carbon, wherein the non-expandable graphite or carbon particles are in the amount of between about 3% and about 70% by weight based on the total weight of the particles and the expanded graphite flakes combined; wherein the mixture is compressed to form the article having an apparent bulk density of from about 0.1 g/cm.sup.3 to about 2.0 g/cm.sup.3. The article exhibits a thickness-direction conductivity typically greater than 50 S/cm, more typically greater than 100 S/cm, and most typically greater than 200 S/cm. The article, when used in a thin foil or sheet form, can be a useful component in a sheet molding compound plate used as a fuel cell separator or flow field plate. The article may also be used as a current collector for a battery, supercapacitor, or any other electrochemical cell.

Ultrafast plasmon-enhanced hot electron process in model heterojunctions: Ag/TiO2 and Ag/graphite

NASA Astrophysics Data System (ADS)

Petek, Hrvoje

We study the plasmonically enhanced nonlinear photoemission from Ag nanocluster-decorated graphite and TiO2(110) surfaces by time-resolved two-photon photoemission spectroscopy (TR-2PP). Evaporating Ag atoms on graphite and TiO2 surfaces forms pancake-like Ag clusters with 5 nm diameter and 1-1.5 nm height through self-limiting growth mode. The Ag nanoparticles enhance the two-photon photoemission (2PP) signal by approximately two-orders of magnitude as compared with the bare surfaces for p-polarized excitation. In the case of s-polarization there is essentially no enhancement for graphite, and only about an order-of-magnitude enhancement for TiO2. Wavelength dependent measurements of the enhancement reveal that for Ag/graphite there is a single plasmonic resonance due to the ⊥-plasmon mode at 3.6 eV. By contrast, for Ag/TiO2 there are ⊥ and ||-plasmon modes with resonant energies of 3.8 and 3.1 eV, respectively. Apparently the dielectric properties of the substrate have strong influence on the type and frequency of Ag plasmonic modes that can exist on the surfaces. 2PP spectra of the Ag/graphite and Ag/TiO2 surfaces reveal two distinct components that are common to both. The high energy component consists of a coherent 2PP process from an occupied interface state, which only exists in the presence of Ag. We identify this state, as an interface state formed by charge donation from the Ag-5s band to the unoccupied states of the substrates. The low energy component consists of a hot electron signal that is created by plasmon dephasing. TR-2PP measurements are performed on the plasmon-induced electron dynamics to assess their relevance for plasmonically enhanced femtochemistry. This research was supported by NSF Grant CHE-1414466.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Carroll, Mark C.

High-purity graphite is the core structural material of choice in the Very High Temperature Reactor (VHTR) design, a graphite-moderated, helium-cooled configuration capable of producing thermal energy for power generation as well as process heat for industrial applications that require temperatures higher than the outlet temperatures of present nuclear reactors. The Baseline Graphite Characterization Program is establishing accurate as-manufactured mechanical and physical property distributions in nuclear-grade graphites by providing comprehensive data that captures the level of variation in measured values. In addition to providing a thorough comparison between these values in different graphite grades, the program is also carefully tracking individualmore » specimen source, position, and orientation information in order to provide comparisons both in specific properties and in the associated variability between different lots, different billets, and different positions from within a single billet. This report is a preliminary comparison between each of the grades of graphite that are considered “candidate” grades from four major international graphite producers. These particular grades (NBG-18, NBG-17, PCEA, IG-110, and 2114) are the major focus of the evaluations presently underway on irradiated graphite properties through the series of Advanced Graphite Creep (AGC) experiments. NBG-18, a medium-grain pitch coke graphite from SGL from which billets are formed via vibration molding, was the favored structural material in the pebble-bed configuration. NBG-17 graphite from SGL is essentially NBG-18 with the grain size reduced by a factor of two. PCEA, petroleum coke graphite from GrafTech with a similar grain size to NBG-17, is formed via an extrusion process and was initially considered the favored grade for the prismatic layout. IG-110 and 2114, from Toyo Tanso and Mersen (formerly Carbone Lorraine), respectively, are fine-grain grades produced via an isomolding process. An analysis of the comparison between each of these grades will include not only the differences in fundamental and statistically-significant individual strength levels, but also the differences in the overall variability in properties within each of the grades that will ultimately provide the basis for predicting in-service performance. The comparative performance of the different types of nuclear-grade graphites will naturally continue to evolve as thousands more specimens are fully characterized with regard to strength, physical properties, and thermal performance from the numerous grades of graphite being evaluated.« less

Development of Advanced High Strength Cast Alloys for Heavy Duty Engines

DOE Office of Scientific and Technical Information (OSTI.GOV)

Barlow, James

Gray iron has been the primary alloy for heavy duty diesel engine core castings for decades. During recent decades the limitations of gray iron have been reached in some applications, leading to the use of compacted graphite iron in engine blocks and heads. Caterpillar has had compacted graphite designs in continuous production since the late 1980’s. Due to the drive for higher power density, decreased emissions and increased fuel economy, cylinder pressures and temperatures continue to increase. Currently no viable replacement for today’s compacted graphite irons exist at an acceptable cost level. This project explored methods to develop the nextmore » generation of heavy duty diesel engine materials as well as demonstrated some results on new alloy designs although cost targets will likely not be met.« less

NEUTRONIC REACTOR

DOEpatents

Wigner, E.P.

1957-09-17

A reactor of the type having coolant liquid circulated through clad fuel elements geometrically arranged in a solid moderator, such as graphite, is described. The core is enclosed in a pressure vessel and suitable shielding, wherein means is provided for circulating vapor through the core to superheat the same. This is accomplished by drawing off the liquid which has been heated in the core due to the fission of the fuel, passing it to a nozzle within a chamber where it flashes into a vapor, and then passing the vapor through separate tubes extending through the moderator to pick up more heat developed in the core due to the fission of the fuel, thereby producing superheated vapor.

Preparation and magnetic properties of phthalocyanine-based carbon materials containing transition metals

NASA Astrophysics Data System (ADS)

Honda, Z.; Sato, S.; Hagiwara, M.; Kida, T.; Sakai, M.; Fukuda, T.; Kamata, N.

2016-07-01

A simple method for the preparation of bulk quantities of magnetic carbon materials, which contain uniformly dispersed transition metals (M = Fe, Co, Ni, and Cu) as the magnetic components, is presented. By using highly chlorinated metal phthalocyanine as the building block and potassium as the coupling reagent, phthalocyanine-based carbon materials (PBCMs) containing transition metals were obtained. Our experiments demonstrate the structure of these PBCMs consists of transition metals embedded in graphitic carbon that includes a square planar MN4 magnetic core and the Fe and Co-PBCM possess spontaneous magnetization at room temperature. In addition, carbon-coated transition metal particles were obtained by the Wurtz-type reaction with excess amount of potassium coupling agent. The large transition metal surface area and magnetization of these M-PBCMs are useful for spintronic and catalytic applications.

Preliminary Structural Sizing and Alternative Material Trade Study of CEV Crew Module

NASA Technical Reports Server (NTRS)

Bednarcyk, Brett A.; Arnold, Steve M.; Collier, Craig S.; Yarrington, Phillip W.

2007-01-01

This paper presents the results of a preliminary structural sizing and alternate material trade study for NASA s Crew Exploration Vehicle (CEV) Crew Module (CM). This critical CEV component will house the astronauts during ascent, docking with the International Space Station, reentry, and landing. The alternate material design study considers three materials beyond the standard metallic (aluminum alloy) design that resulted from an earlier NASA Smart Buyer Team analysis. These materials are graphite/epoxy composite laminates, discontinuously reinforced SiC/Al (DRA) composites, and a novel integrated panel material/concept known as WebCore. Using the HyperSizer (Collier Research and Development Corporation) structural sizing software and NASTRAN finite element analysis code, a comparison is made among these materials for the three composite CM concepts considered by the 2006 NASA Engineering and Safety Center Composite Crew Module project.

Fixed Eigenvector Analysis of Thermographic NDE Data

NASA Technical Reports Server (NTRS)

Cramer, K. Elliott; Winfree, William P.

2011-01-01

Principal Component Analysis (PCA) has been shown effective for reducing thermographic NDE data. This paper will discuss an alternative method of analysis that has been developed where a predetermined set of eigenvectors is used to process the thermal data from both reinforced carbon-carbon (RCC) and graphiteepoxy honeycomb materials. These eigenvectors can be generated either from an analytic model of the thermal response of the material system under examination, or from a large set of experimental data. This paper provides the details of the analytic model, an overview of the PCA process, as well as a quantitative signal-to-noise comparison of the results of performing both conventional PCA and fixed eigenvector analysis on thermographic data from two specimens, one Reinforced Carbon-Carbon with flat bottom holes and the second a sandwich construction with graphite-epoxy face sheets and aluminum honeycomb core.

The nuclear battery

NASA Astrophysics Data System (ADS)

Kozier, K. S.; Rosinger, H. E.

The evolution and present status of an Atomic Energy of Canada Limited program to develop a small, solid-state, passively cooled reactor power supply known as the Nuclear Battery is reviewed. Key technical features of the Nuclear Battery reactor core include a heat-pipe primary heat transport system, graphite neutron moderator, low-enriched uranium TRISO coated-particle fuel and the use of burnable poisons for long-term reactivity control. An external secondary heat transport system extracts useful heat energy, which may be converted into electricity in an organic Rankine cycle engine or used to produce high-pressure steam. The present reference design is capable of producing about 2400 kW(t) (about 600 kW(e) net) for 15 full-power years. Technical and safety features are described along with recent progress in component hardware development programs and market assessment work.

Corrosion of graphite composites in phosphoric acid fuel cells

NASA Technical Reports Server (NTRS)

Christner, L. G.; Dhar, H. P.; Farooque, M.; Kush, A. K.

1986-01-01

Polymers, polymer-graphite composites and different carbon materials are being considered for many of the fuel cell stack components. Exposure to concentrated phosphoric acid in the fuel cell environment and to high anodic potential results in corrosion. Relative corrosion rates of these materials, failure modes, plausible mechanisms of corrosion and methods for improvement of these materials are investigated.

Analysis and measurements of low frequency lightning component penetration through aerospace vehicle metal and graphite skins

NASA Technical Reports Server (NTRS)

Robb, J. D.; Chen, T.

1980-01-01

An analysis of the shielding properties of mixed metal and graphite composite structures has illustrated some important aspects of electromagnetic field penetration into the interior. These include: (1) that graphite access doors on metallic structures will attenuate lightning magnetic fields very little; conversely, metal doors on a graphite structure will also attenuate fields from lightning strike currents very little, i.e., homogeneity of the shield is a critical factor in shielding and (2) that continuous conductors between two points inside a graphite skin such as an air data probe metallic tubing connection to an air data computer can allow large current penetrations into a vehicle interior. The true weight savings resulting from the use of composite materials can only be evaluated after the resulting electromagnetic problems such as current penetrations have been solved, and this generally requires weight addition in the form of cable shields, conductor bonding or external metallization.

On the Application of Lithium Additives in the Electrolytic Production of Primary Aluminum

NASA Astrophysics Data System (ADS)

Saitov, A. V.; Bazhin, V. Yu.; Povarov, V. G.

2017-12-01

The behavior of carbon-graphite subjected to treatment in the lithium carbonate Li2CO3 melt without cryolite and alkali-metal fluorides is studied to reliably estimate the influence of lithium on the surface layers of a carbon-containing cathode lining. The chemical composition and the structure of the carbon-graphite material after its interaction with lithium in the Li2CO3 melt have been studied. The high-temperature interaction of the system components in the melt is found to be accompanied by fracture of the operating surface of the carbon-graphite material, while the carbon-graphite surface does not failed upon interacting with lithium vapors. Based on the obtained data, a model for the formation of lithium ions during the reduction of lithium and its interaction with a carbon-graphite sample during the electrolysis of lithium carbonate is proposed.

Online Parameterization of Lumped Thermal Dynamics in Cylindrical Lithium Ion Batteries for Core Temperature Estimation and Health Monitoring

DTIC Science & Technology

2012-01-01

Experiments have been conducted to validate the de- signed parameterization scheme. A 2.3Ah A123TM 26650 LiFePO4 /graphite battery is cycled with a BitrodeTM...management strategy. The type of battery used in the experiment ( LiFePO4 26650) is different from the one in Fig. 3. Schematics of the Flow Chamber [23...of a cylindrical lifepo4 /graphite lithium-ion battery,” Journal of Power Sources, vol. 195, pp. 2961–2968, 2010. [9] C. W. Park and A. K. Jaura

Ultraviolet interstellar linear polarization. I - Applicability of current dust grain models

NASA Technical Reports Server (NTRS)

Wolff, Michael J.; Clayton, Geoffrey C.; Meade, Marilyn R.

1993-01-01

UV spectropolarimetric observations yielding data on the wavelength-dependence of interstellar polarization along eight lines of sight facilitate the evaluation of dust grain models previously used to fit the extinction and polarization in the visible and IR. These models pertain to bare silicate/graphite grains, silicate cores with organic refractory mantles, silicate cores with amorphous carbon mantles, and composite grains. The eight lines-of-sight show three different interstellar polarization dependences.

A new oxidation based technique for artifact free TEM specimen preparation of nuclear graphite

NASA Astrophysics Data System (ADS)

Johns, Steve; Shin, Wontak; Kane, Joshua J.; Windes, William E.; Ubic, Rick; Karthik, Chinnathambi

2018-07-01

Graphite is a key component in designs of current and future nuclear reactors whose in-service lifetimes are dependent upon the mechanical performance of the graphite. Irradiation damage from fast neutrons creates lattice defects which have a dynamic effect on the microstructure and mechanical properties of graphite. Transmission electron microscopy (TEM) can offer real-time monitoring of the dynamic atomic-level response of graphite subjected to irradiation; however, conventional TEM specimen-preparation techniques, such as argon ion milling itself, damage the graphite specimen and introduce lattice defects. It is impossible to distinguish these defects from the ones created by electron or neutron irradiation. To ensure that TEM specimens are artifact-free, a new oxidation-based technique has been developed. Bulk nuclear grades of graphite (IG-110 and NBG-18) and highly oriented pyrolytic graphite (HOPG) were initially mechanically thinned to ∼60 μm. Discs 3 mm in diameter were then oxidized at temperatures between 575 °C and 625 °C in oxidizing gasses using a new jet-polisher-like set-up in order to achieve optimal oxidation conditions to create self-supporting electron-transparent TEM specimens. The quality of these oxidized specimens were established using optical and electron microscopy. Samples oxidized at 575 °C exhibited large areas of electron transparency and the corresponding lattice imaging showed no apparent damage to the graphite lattice.

A new oxidation based technique for artifact free TEM specimen preparation of nuclear graphite

DOE Office of Scientific and Technical Information (OSTI.GOV)

Johns, Steve; Shin, Wontak; Kane, Joshua J.

Graphite is a key component in designs of current and future nuclear reactors whose in-service lifetimes are dependent upon the mechanical performance of the graphite. Irradiation damage from fast neutrons creates lattice defects which have a dynamic effect on the microstructure and mechanical properties of graphite. Transmission electron microscopy (TEM) can offer real-time monitoring of the dynamic atomic-level response of graphite subjected to irradiation; however, conventional TEM specimen-preparation techniques, such as argon ion milling itself, damage the graphite specimen and introduce lattice defects. It is impossible to distinguish these defects from the ones created by electron or neutron irradiation. Thus,tomore » ensure that TEM specimens are artifact-free, a new oxidation-based technique has been developed. Bulk nuclear grades of graphite (IG-110 and NBG-18) and highly oriented pyrolytic graphite (HOPG) were initially mechanically thinned to ~60μm. Discs 3mm in diameter were then oxidized at temperatures between 575°C and 625°C in oxidizing gasses using a new jet-polisher-like set-up in order to achieve optimal oxidation conditions to create self-supporting electron-transparent TEM specimens. The quality of these oxidized specimens were established using optical and electron microscopy. Samples oxidized at 575°C exhibited large areas of electron transparency and the corresponding lattice imaging showed no apparent damage to the graphite lattice.« less

A new oxidation based technique for artifact free TEM specimen preparation of nuclear graphite

DOE PAGES

Johns, Steve; Shin, Wontak; Kane, Joshua J.; ...

2018-04-03

Graphite is a key component in designs of current and future nuclear reactors whose in-service lifetimes are dependent upon the mechanical performance of the graphite. Irradiation damage from fast neutrons creates lattice defects which have a dynamic effect on the microstructure and mechanical properties of graphite. Transmission electron microscopy (TEM) can offer real-time monitoring of the dynamic atomic-level response of graphite subjected to irradiation; however, conventional TEM specimen-preparation techniques, such as argon ion milling itself, damage the graphite specimen and introduce lattice defects. It is impossible to distinguish these defects from the ones created by electron or neutron irradiation. Thus,tomore » ensure that TEM specimens are artifact-free, a new oxidation-based technique has been developed. Bulk nuclear grades of graphite (IG-110 and NBG-18) and highly oriented pyrolytic graphite (HOPG) were initially mechanically thinned to ~60μm. Discs 3mm in diameter were then oxidized at temperatures between 575°C and 625°C in oxidizing gasses using a new jet-polisher-like set-up in order to achieve optimal oxidation conditions to create self-supporting electron-transparent TEM specimens. The quality of these oxidized specimens were established using optical and electron microscopy. Samples oxidized at 575°C exhibited large areas of electron transparency and the corresponding lattice imaging showed no apparent damage to the graphite lattice.« less

In-depth understanding of core-shell nanoarchitecture evolution of g-C3N4@C, N co-doped anatase/rutile: Efficient charge separation and enhanced visible-light photocatalytic performance

NASA Astrophysics Data System (ADS)

Mohamed, Mohamad Azuwa; Jaafar, Juhana; M. Zain, M. F.; Minggu, Lorna Jeffery; Kassim, Mohammad B.; Rosmi, Mohamad Saufi; Alias, Nur Hashimah; Mohamad Nor, Nor Azureen; W. Salleh, W. N.; Othman, Mohd Hafiz Dzarfan

2018-04-01

Herein, we demonstrated the simultaneous formation of multi-component heterojunction consisting graphitic carbon nitride (g-C3N4) and C, N co-doped anatase/rutile mixed phase by using facile sol-gel assisted heat treatment. The evolution of core-shell nanostructures heterojunction formation was elucidated by varying the temperature of heat treatment from 300 °C to 600 °C. Homogeneous heterojunction formation between g-C3N4 and anatase/rutile mixed phase was observed in gT400 with C and N doping into TiO2 lattice by O substitution. The core-shell nanoarchitectures between g-C3N4 as shell, and anatase/rutile mixed phase as core with C and N atoms are doped at the interstitial positions of TiO2 lattice was observed in gT500. The result indicated that core-shell nanoarchitectures photocatalyst (gT500) prepared at 500 ◦C exhibited the highest photocatalytic activity in the degradation of methyl orange under visible light irradiation. Meanwhile, the possible mechanisms of charge generation, migration, action species and reaction that probably occur at the gT500 sample were also proposed. The photodegradation results of gT500 correlated completely with the results of the PEC and photoluminescence analysis, which directly evidenced improved charge separation and migration as the crucial parameters governing photocatalysis. It is worthy to note that, the simultaneous formation of multicomponent heterojunction with core-shell structure provided an enormous impact in designing highly active photocatalyst with superior interfacial charge transfer.

Study Methods to Standardize Thermography NDE

NASA Technical Reports Server (NTRS)

Walker, James L.; Workman, Gary L.

1998-01-01

The purpose of this work is to develop thermographic inspection methods and standards for use in evaluating structural composites and aerospace hardware. Qualification techniques and calibration methods are investigated to standardize the thermographic method for use in the field. Along with the inspections of test standards structural hardware, support hardware is designed and fabricated to aid in the thermographic process. Also, a standard operating procedure is developed for performing inspections with the Bales Thermal Image Processor (TIP). Inspections are performed on a broad range of structural composites. These materials include various graphite/epoxies, graphite/cyanide-ester, graphite/silicon-carbide, graphite phenolic and Keviar/epoxy. Also metal honeycomb (titanium and aluminum faceplates over an aluminum honeycomb core) structures are investigated. Various structural shapes are investigated and the thickness of the structures vary from as few as 3 plies to as many as 80 plies. Special emphasis is placed on characterizing defects in attachment holes and bondlines, in addition to those resulting from impact damage and the inclusion of foreign matter. Image processing through statistical analysis and digital filtering is investigated to enhance the quality and quantify the NDE thermal images when necessary.

Study Methods to Standardize Thermography NDE

NASA Technical Reports Server (NTRS)

Walker, James L.; Workman, Gary L.

1998-01-01

The purpose of this work is to develop thermographic inspection methods and standards for use in evaluating structural composites and aerospace hardware. Qualification techniques and calibration methods are investigated to standardize the thermographic method for use in the field. Along with the inspections of test standards structural hardware, support hardware is designed and fabricated to aid in the thermographic process. Also, a standard operating procedure is developed for performing inspections with the Bales Thermal Image Processor (TIP). Inspections are performed on a broad range of structural composites. These materials include graphite/epoxies, graphite/cyanide-ester, graphite/silicon-carbide, graphite phenolic and Kevlar/epoxy. Also metal honeycomb (titanium and aluminum faceplates over an aluminum honeycomb core) structures are investigated. Various structural shapes are investigated and the thickness of the structures vary from as few as 3 plies to as many as 80 plies. Special emphasis is placed on characterizing defects in attachment holes and bondlines, in addition to those resulting from impact damage and the inclusion of foreign matter. Image processing through statistical analysis and digital filtering is investigated to enhance the quality and quantify the NDE thermal images when necessary.

Modeling Optical and Radiative Properties of Clouds Constrained with CARDEX Observations

NASA Astrophysics Data System (ADS)

Mishra, S. K.; Praveen, P. S.; Ramanathan, V.

2013-12-01

Carbonaceous aerosols (CA) have important effects on climate by directly absorbing solar radiation and indirectly changing cloud properties. These particles tend to be a complex mixture of graphitic carbon and organic compounds. The graphitic component, called as elemental carbon (EC), is characterized by significant absorption of solar radiation. Recent studies showed that organic carbon (OC) aerosols absorb strongly near UV region, and this faction is known as Brown Carbon (BrC). The indirect effect of CA can occur in two ways, first by changing the thermal structure of the atmosphere which further affects dynamical processes governing cloud life cycle; secondly, by acting as cloud condensation nuclei (CCN) that can change cloud radiative properties. In this work, cloud optical properties have been numerically estimated by accounting for CAEDEX (Cloud Aerosol Radiative Forcing Dynamics Experiment) observed cloud parameters and the physico-chemical and optical properties of aerosols. The aerosol inclusions in the cloud drop have been considered as core shell structure with core as EC and shell comprising of ammonium sulfate, ammonium nitrate, sea salt and organic carbon (organic acids, OA and brown carbon, BrC). The EC/OC ratio of the inclusion particles have been constrained based on observations. Moderate and heavy pollution events have been decided based on the aerosol number and BC concentration. Cloud drop's co-albedo at 550nm was found nearly identical for pure EC sphere inclusions and core-shell inclusions with all non-absorbing organics in the shell. However, co-albedo was found to increase for the drop having all BrC in the shell. The co-albedo of a cloud drop was found to be the maximum for all aerosol present as interstitial compare to 50% and 0% inclusions existing as interstitial aerosols. The co-albedo was found to be ~ 9.87e-4 for the drop with 100% inclusions existing as interstitial aerosols externally mixed with micron size mineral dust with 2% hematite content. The cloud spectral optical properties and the radiative properties for the aforesaid cases during CARDEX observations will be discussed in detail.

INVESTIGATION OF TITANIUM BONDED GRAPHITE FOAM COMPOSITES FOR MICRO ELECTRONIC MECHANICAL SYSTEMS (MEMS) APPLICATIONS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Menchhofer, Paul A.

PiMEMS Inc. (Santa Barbara, CA) in collaboration with ORNL investigated the use of Titanium Bonded Graphite Foam Composites (TBGC) for thermal mitigation in Micro Electronic Mechanical Systems (MEMS) applications. Also considered were potentially new additive manufacturing routes to producing novel high surface area micro features and diverse shaped heat transfer components for numerous lightweight MEMs applications.

Gelcasting polymeric precursors for producing net-shaped graphites

DOEpatents

Klett, James W.; Janney, Mark A.

2002-01-01

The present invention discloses a method for molding complex and intricately shaped high density monolithic carbon, carbon-carbon, graphite, and thermoplastic composites using gelcasting technology. The method comprising a polymeric carbon precursor, a solvent, a dispersant, an anti-foaming agent, a monomer system, and an initiator system. The components are combined to form a suspension which is poured into a mold and heat-treated to form a thermoplastic part. The thermoplastic part can then be further densified and heat-treated to produce a high density carbon or graphite composite. The present invention also discloses the products derived from this method.

B{sub 4}C-SiC reaction-sintered coatings on graphite plasma facing components

DOE Office of Scientific and Technical Information (OSTI.GOV)

Valentine, P.G.; Trester, P.W.; Winter, J.

1994-05-01

Boron carbide plus silicon carbide (B{sub 4}C-SiC) reaction-sintered coatings for use on graphite plasma-facing components were developed. Such coatings are of interest in TEXTOR tokamak limiter-plasma interactions as a means of reducing carbon erosion, of providing a preferred release of boron for oxygen gettering, and of investigating silicon`s effect on radiative edge phenomena. Specimens evaluated had (a) either Ringsdorfwerke EK 98 graphite or Le Carbon Lorraine felt-type AEROLOR A05 CFC substrates; (b) multiphase coatings, comprised of B{sub 4}C, Sic, and graphite; (c) nominal coating compositions of 69 wt.-% B{sub 4}C + 31 wt.-% SiC; and (d) nominal coating thicknesses betweenmore » 250 and 775 {mu}m. Coated coupons were evaluated by high heat flux experiments in the JUDITH (electron beam) test facility at KFA. Simulated disruptions, with energy densities up to 10 MJm{sup {minus}2}, and normal operation simulations, with power densities up to 12 MWm{sup {minus}2}, were conducted. The coatings remained adherent; at the highest levels tested, minor changes occurred, including localized remelting, modification of the crystallographic phases, occasional microcracking, and erosion.« less

Transmission electron microscopy of unstained hybrid Au nanoparticles capped with PPAA (plasma-poly-allylamine): structure and electron irradiation effects.

PubMed

Gontard, Lionel C; Fernández, Asunción; Dunin-Borkowski, Rafal E; Kasama, Takeshi; Lozano-Pérez, Sergio; Lucas, Stéphane

2014-12-01

Hybrid (organic shell-inorganic core) nanoparticles have important applications in nanomedicine. Although the inorganic components of hybrid nanoparticles can be characterized readily using conventional transmission electron microscopy (TEM) techniques, the structural and chemical arrangement of the organic molecular components remains largely unknown. Here, we apply TEM to the physico-chemical characterization of Au nanoparticles that are coated with plasma-polymerized-allylamine, an organic compound with the formula C3H5NH2. We discuss the use of energy-filtered TEM in the low-energy-loss range as a contrast enhancement mechanism for imaging the organic shells of such particles. We also study electron-beam-induced crystallization and amorphization of the shells and the formation of graphitic-like layers that contain both C and N. The resistance of the samples to irradiation by high-energy electrons, which is relevant for optical tuning and for understanding the degree to which such hybrid nanostructures are stable in the presence of biomedical radiation, is also discussed. Copyright © 2014 Elsevier Ltd. All rights reserved.

Effect of reactor radiation on the thermal conductivity of TREAT fuel

NASA Astrophysics Data System (ADS)

Mo, Kun; Miao, Yinbin; Kontogeorgakos, Dimitrios C.; Connaway, Heather M.; Wright, Arthur E.; Yacout, Abdellatif M.

2017-04-01

The Transient Reactor Test Facility (TREAT) at the Idaho National Laboratory is resuming operations after more than 20 years in latency in order to produce high-neutron-flux transients for investigating transient-induced behavior of reactor fuels and their interactions with other materials and structures. A parallel program is ongoing to develop a replacement core in which the fuel, historically containing highly-enriched uranium (HEU), is replaced by low-enriched uranium (LEU). Both the HEU and prospective LEU fuels are in the form of UO2 particles dispersed in a graphite matrix, but the LEU fuel will contain a much higher volume of UO2 particles, which may create a larger area of interphase boundaries between the particles and the graphite. This may lead to a higher volume fraction of graphite exposed to the fission fragments escaping from the UO2 particles, and thus may induce a higher volume of fission-fragment damage on the fuel graphite. In this work, we analyzed the reactor-radiation induced thermal conductivity degradation of graphite-based dispersion fuel. A semi-empirical method to model the relative thermal conductivity with reactor radiation was proposed and validated based on the available experimental data. Prediction of thermal conductivity degradation of LEU TREAT fuel during a long-term operation was performed, with a focus on the effect of UO2 particle size on fission-fragment damage. The proposed method can be further adjusted to evaluate the degradation of other properties of graphite-based dispersion fuel.

GRAFEC: A New Spanish Program to Investigate Waste Management Options for Radioactive Graphite - 12399

DOE Office of Scientific and Technical Information (OSTI.GOV)

Marquez, Eva; Pina, Gabriel; Rodriguez, Marina

Spain has to manage about 3700 tons of irradiated graphite from the reactor Vandellos I as radioactive waste. 2700 tons are the stack of the reactor and are still in the reactor core waiting for retrieval. The rest of the quantities, 1000 tons, are the graphite sleeves which have been already retrieved from the reactor. During operation the graphite sleeves were stored in a silo and during the dismantling stage a retrieval process was carried out separating the wires from the graphite, which were crushed and introduced into 220 cubic containers of 6 m{sup 3} each and placed in interimmore » storage. The graphite is an intermediate level radioactive waste but it contains long lived radionuclides like {sup 14}C which disqualifies disposal at the low level waste repository of El Cabril. Therefore, a new project has been started in order to investigate two new options for the management of this waste type. The first one is based on a selective decontamination of {sup 14}C by thermal methods. This method is based on results obtained at the Research Centre Juelich (FZJ) in the Frame of the EC programs 'Raphael' and 'Carbowaste'. The process developed at FZJ is based on a preferential oxidation of {sup 14}C in comparison to the bulk {sup 12}C. Explanations for this effect are the inhomogeneous distribution and a weaker bounding of {sup 14}C which is not incorporated in the graphite lattice. However these investigations have only been performed with graphite from the high temperature reactor Arbeitsgemeinschaft Versuchsreaktor Juelich AVR which has been operated in a non-oxidising condition or research reactor graphite operated at room temperature. The reactor Vandellos I has been operated with CO{sub 2} as coolant and significant amounts of graphite have been already oxidised. The aim of the project is to validate whether a {sup 14}C decontamination can also been achieved with graphite from Vandellos I. A second possibility under investigation is the encapsulation of the graphite in a long term stable glass matrix. The principal applicability has been already proved by FNAG. Crushed graphite mixed with a suitable glass powder has been pressed at elevated temperature under vacuum. The vacuum is required to avoid gas enclosures in the obtained product. The obtained products, named IGM for 'Impermeable Graphite Matrix', have densities above 99% of theoretical density. The amount of glass has been chosen with respect to the pore volume of the former graphite parts. The method allows the production of encapsulated graphite without increasing the disposal volume. This paper will give a short overview of characterisation results of different irradiated graphite materials obtained at CIEMAT and in the Carbowaste project as well as the proposed methods and the actual status of the program including first results about leaching of non-radioactive IGM samples and hopefully first tendencies concerning the C-14 separation from graphite of Vandellos I by thermal treatment. Both processes, the thermal treatment as well as the IGM, have the potential to solve problems related to the management of irradiated graphite in Spain. However the methods have only been tested with different types of i-graphite and virgin graphite, respectively. Only investigations with real i-graphite from Spain will reveal whether the described methods are applicable to graphite from Vandellos I. However all partners are convinced that one of these new methods or a combination of them will lead to a feasible option to manage i-graphite in Spain on an industrial scale. (authors)« less

Dissolution Mediated Boron and Carbon Storage during Exhumation of HP Metapelites: Examples from New Hampshire Tourmaline-Graphite Intergrowths

NASA Astrophysics Data System (ADS)

Galvez, M.; Rumble, D.; Cody, G. D.; Sverjensky, D. A.

2013-12-01

The dynamic of light elements (e.g. C,B) in subduction zones is a complex process ultimately governed by variables such as P, T, fH2 and pH. Interface phenomena at scales from the outcrop to intergranular surfaces play key chemical and mechanical roles on this dynamic (e.g. Galvez et al. 2013). We report here a petrological study of hydrated borosilicate tourmaline intergrown with graphite formed at the contact between igneous intrusives and high grade micaschists in New Hampshire graphite deposits (Rumble and Hoering, 1986). Our study includes Raman scattering, SEM, microprobe analysis and thermodynamic modeling, focusing on the Franklin Pierce and Walpole outcrops. Both localities experienced HP-HT metamorphism during the Acadian orogeny as well as complex metasomatic process during exhumation. The tourmaline-graphite intergrowths are structurally localized at and around contacts between an aplite sill and micaschists - biotite-muscovite-garnet-sillimanite-plagioclase-quartz-ilmenite - (Franklin Pierce), or along shear zones (Walpole) in veins. Tourmalines are dravitic in composition (i.e. Na, Mg rich with minor vacancy and Li content 0.2/0.1 a.p.f.u) and contain multiple primary tubular mixed fluid-solid inclusions containing graphite, quartz and gaseous CO2 and CH4. Sharp optical and compositional radial zonations are observed from core to rim in sections along and perpendicular to the c-axis. Blue-green cores are enriched in Mg and Ca (1.5/0.1 a.p.f.u respectively) whereas rims are enriched in Fe, Na and Ti (0.9/0.6/0.1 a.p.f.u respectively). Alternative interpretations in terms of sector zoning or compositional variability of the mineralizing fluid will be discussed. The carbonaceous material (CM) occurs primarily as flakes directly replacing biotite present in wall rocks. The structural ordering of CM, of unambiguous abiotic origin, reveals a material possessing the 3 dimensional structure of hexagonal graphite. Our results are critically compared to measurements done on other metasomatic or biogenic graphite displaying high structural ordering. Other textural habit of graphite are radiating crystals of graphite preferentially growing along crystalline planes of wall rock minerals (e.g. plagioclases) and at the interface between grain edge. We test whether a C and B(OH)3° (×As, Cu) rich acidic vapor unmixing from a salt-rich aqueous fluid exsolved from crystallizing igneous bodies can account for some geochemical and textural greisen-type metasomatic features of these outcrops. Other mechanical and geochemical processes participating in the process will be discussed. This work is direct evidence that respeciation and/or fluid-rock interaction at varying P,T,fH2,pH conditions of fluids during exhumation, as well as interaction between magmatic bodies and metasedimentary units play a key role in the cycling of light elements during exhumation. Rumble, D., III, and Hoering, T.C., 1986, Carbon isotope geochemistry of graphite vein deposits from New Hampshire, U.S.A: Geochimica et Cosmochimica Acta, v. 50, p. 1239-1247. Galvez ME, Beyssac O, Martinez I, Benzerara K, Chaduteau C, Malvoisin B, Malavieille J (2013) Graphite formation by carbonate reduction during subduction. Nature Geoscience 6 (6):473-477

Nitrogen–doped graphitized carbon shell encapsulated NiFe nanoparticles: A highly durable oxygen evolution catalyst

DOE PAGES

Du, Lei; Luo, Langli; Feng, Zhenxing; ...

2017-07-05

Oxygen evolution reaction (OER) plays a crucial role in various energy conversion devices such as water electrolyzers and metal–air batteries. Precious metal catalysts such as Ir, Ru and their oxides are usually used for enhancing reaction kinetics but are limited by their scarcity. The challenges associated with alternative non–precious metal catalysts such as transition metal oxides and (oxy)hydroxides are their low electronic conductivity and durability. The carbon encapsulating transition metal nanoparticles are expected to address these challenges. However, the relationship between precursor compositions and catalyst properties, and the intrinsic functions of each component has been rarely studied. In this paper,more » we report a highly durable (no degradation after 20,000 cycles) and highly active (360 mV overpotential at 10 mA cm –2 GEO) OER catalyst derived from bimetallic metal–organic frameworks (MOFs) precursors. This catalyst consists of NiFe nanoparticles encapsulated by nitrogen–doped graphitized carbon shells. The electron–donation/deviation from Fe and tuned lattice and electronic structures of metal cores by Ni are revealed to be primary contributors to the enhanced OER activity, whereas N concentration contributes negligibly. Finally, we further demonstrated that the structure and morphology of encapsulating carbon shells, which are the key factors influencing the durability, are facilely controlled by the chemical state of precursors.« less

Nitrogen–doped graphitized carbon shell encapsulated NiFe nanoparticles: A highly durable oxygen evolution catalyst

DOE Office of Scientific and Technical Information (OSTI.GOV)

Du, Lei; Luo, Langli; Feng, Zhenxing

Oxygen evolution reaction (OER) plays a crucial role in various energy conversion devices such as water electrolyzers and metal–air batteries. Precious metal catalysts such as Ir, Ru and their oxides are usually used for enhancing reaction kinetics but are limited by their scarcity. The challenges associated with alternative non–precious metal catalysts such as transition metal oxides and (oxy)hydroxides are their low electronic conductivity and durability. The carbon encapsulating transition metal nanoparticles are expected to address these challenges. However, the relationship between precursor compositions and catalyst properties, and the intrinsic functions of each component has been rarely studied. In this paper,more » we report a highly durable (no degradation after 20,000 cycles) and highly active (360 mV overpotential at 10 mA cm –2 GEO) OER catalyst derived from bimetallic metal–organic frameworks (MOFs) precursors. This catalyst consists of NiFe nanoparticles encapsulated by nitrogen–doped graphitized carbon shells. The electron–donation/deviation from Fe and tuned lattice and electronic structures of metal cores by Ni are revealed to be primary contributors to the enhanced OER activity, whereas N concentration contributes negligibly. Finally, we further demonstrated that the structure and morphology of encapsulating carbon shells, which are the key factors influencing the durability, are facilely controlled by the chemical state of precursors.« less

MEANS FOR COOLING REACTORS

DOEpatents

Wheeler, J.A.

1957-11-01

A design of a reactor is presented in which the fuel elements may be immersed in a liquid coolant when desired without the necessity of removing them from the reactor structure. The fuel elements, containing the fissionable material are in plate form and are disposed within spaced slots in a moderator material, such as graphite to form the core. Adjacent the core is a tank containing the liquid coolant. The fuel elements are mounted in spaced relationship on a rotatable shaft which is located between the core and the tank so that by rotation of the shaft the fuel elements may be either inserted in the slots in the core to sustain a chain reaction or immersed in the coolant.

Improvement of Ion/Ioff for h-BN encapsulated bilayer graphene by graphite local back gate electrode

NASA Astrophysics Data System (ADS)

Uwanno, Teerayut; Taniguchi, Takashi; Watanabe, Kenji; Nagashio, Kosuke

The critical issue for bilayer graphene (BLG) devices is low Ion/Ioff even at the band gap of 0.3eV. Band gap in BLG can be formed by creating potential difference between the two layers of BLG. This can be done by applying external electric field perpendicularly to BLG to induce different carrier densities in the two layers. Due to such origin, the spatial uniformity of band gap in the channel is quite sensitive to charge inhomogeneity in BLG. In order to apply electric field of 3V/nm to open the maximum band gap of 0.3eV, high- k gate stack has been utilized so far. However, oxide dielectrics usually have large charge inhomogeneity causing in-plane potential fluctuation in BLG channel. Due to surface flatness and small charge inhomogeneity, h-BN has been used as dielectrics to achieve high quality graphene devices, however, Ion/Iofffor BLG/ h-BN heterostuctures has not been reported yet. In this study, we used graphite as local back gate electrode to BLG encapsulated with h-BN. This resulted in much higher Ion/Ioff, indicating the importance of screening of charge inhomogeneity from SiO2 substrate surface by local graphite back gate electrode. This research was partly supported by JSPS Core-to-Core Program, A. Advanced Research Networks.

A Low O/Si Ratio on the Surface of Mercury: Evidence for Silicon Smelting?

NASA Astrophysics Data System (ADS)

McCubbin, Francis M.; Vander Kaaden, Kathleen E.; Peplowski, Patrick N.; Bell, Aaron S.; Nittler, Larry R.; Boyce, Jeremy W.; Evans, Larry G.; Keller, Lindsay P.; Elardo, Stephen M.; McCoy, Timothy J.

2017-10-01

Data from the Gamma-Ray Spectrometer (GRS) that flew on the MErcury Surface, Space ENvironment, GEochemistry, and Ranging spacecraft indicate that the O/Si weight ratio of Mercury's surface is 1.2 ± 0.1. This value is lower than any other celestial surface that has been measured by GRS and suggests that 12-20% of the surface materials on Mercury are composed of Si-rich, Si-Fe alloys. The origin of the metal is best explained by a combination of space weathering and graphite-induced smelting. The smelting process would have been facilitated by interaction of graphite with boninitic and komatiitic parental liquids. Graphite entrained at depth would have reacted with FeO components dissolved in silicate melt, resulting in the production of up to 0.4-0.9 wt % CO from the reduction of FeO to Fe0—CO production that could have facilitated explosive volcanic processes on Mercury. Once the graphite-entrained magmas erupted, the tenuous atmosphere on Mercury prevented the buildup of CO over the lavas. The partial pressure of CO would have been sufficiently low to facilitate reaction between graphite and SiO2 components in silicate melts to produce CO and metallic Si. Although exotic, Si-rich metal as a primary smelting product is hypothesized on Mercury for three primary reasons: (1) low FeO abundances of parental magmas, (2) elevated abundances of graphite in the crust and regolith, and (3) the presence of only a tenuous atmosphere at the surface of the planet within the 3.5-4.1 Ga timespan over which the planet was resurfaced through volcanic processes.

Is Water at the Graphite Interface Vapor-like or Ice-like?

PubMed

Qiu, Yuqing; Lupi, Laura; Molinero, Valeria

2018-04-05

Graphitic surfaces are the main component of soot, a major constituent of atmospheric aerosols. Experiments indicate that soots of different origins display a wide range of abilities to heterogeneously nucleate ice. The ability of pure graphite to nucleate ice in experiments, however, seems to be almost negligible. Nevertheless, molecular simulations with the monatomic water model mW with water-carbon interactions parameterized to reproduce the experimental contact angle of water on graphite predict that pure graphite nucleates ice. According to classical nucleation theory, the ability of a surface to nucleate ice is controlled by the binding free energy between ice immersed in liquid water and the surface. To establish whether the discrepancy in freezing efficiencies of graphite in mW simulations and experiments arises from the coarse resolution of the model or can be fixed by reparameterization, it is important to elucidate the contributions of the water-graphite, water-ice, and ice-water interfaces to the free energy, enthalpy, and entropy of binding for both water and the model. Here we use thermodynamic analysis and free energy calculations to determine these interfacial properties. We demonstrate that liquid water at the graphite interface is not ice-like or vapor-like: it has similar free energy, entropy, and enthalpy as water in the bulk. The thermodynamics of the water-graphite interface is well reproduced by the mW model. We find that the entropy of binding between graphite and ice is positive and dominated, in both experiments and simulations, by the favorable entropy of reducing the ice-water interface. Our analysis indicates that the discrepancy in freezing efficiencies of graphite in experiments and the simulations with mW arises from the inability of the model to simultaneously reproduce the contact angle of liquid water on graphite and the free energy of the ice-graphite interface. This transferability issue is intrinsic to the resolution of the model, and arises from its lack of rotational degrees of freedom.

The effects of temperatures on the pebble flow in a pebble bed high temperature reactor

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sen, R. S.; Cogliati, J. J.; Gougar, H. D.

2012-07-01

The core of a pebble bed high temperature reactor (PBHTR) moves during operation, a feature which leads to better fuel economy (online refueling with no burnable poisons) and lower fuel stress. The pebbles are loaded at the top and trickle to the bottom of the core after which the burnup of each is measured. The pebbles that are not fully burned are recirculated through the core until the target burnup is achieved. The flow pattern of the pebbles through the core is of importance for core simulations because it couples the burnup distribution to the core temperature and power profiles,more » especially in cores with two or more radial burnup 'zones '. The pebble velocity profile is a strong function of the core geometry and the friction between the pebbles and the surrounding structures (other pebbles or graphite reflector blocks). The friction coefficient for graphite in a helium environment is inversely related to the temperature. The Thorium High Temperature Reactor (THTR) operated in Germany between 1983 and 1989. It featured a two-zone core, an inner core (IC) and outer core (OC), with different fuel mixtures loaded in each zone. The rate at which the IC was refueled relative to the OC in THTR was designed to be 0.56. During its operation, however, this ratio was measured to be 0.76, suggesting the pebbles in the inner core traveled faster than expected. It has been postulated that the positive feedback effect between inner core temperature, burnup, and pebble flow was underestimated in THTR. Because of the power shape, the center of the core in a typical cylindrical PBHTR operates at a higher temperature than the region next to the side reflector. The friction between pebbles in the IC is lower than that in the OC, perhaps causing a higher relative flow rate and lower average burnup, which in turn yield a higher local power density. Furthermore, the pebbles in the center region have higher velocities than the pebbles next to the side reflector due to the interaction between the pebbles and the immobile graphite reflector as well as the geometry of the discharge conus near the bottom of the core. In this paper, the coupling between the temperature profile and the pebble flow dynamics was analyzed by using PEBBED/THERMIX and PEBBLES codes by modeling the HTR-10 reactor in China. Two extreme and opposing velocity profiles are used as a starting point for the iterations. The PEBBED/THERMIX code is used to calculate the burnup, power and temperature profiles with one of the velocity profiles as input. The resulting temperature profile is then passed to PEBBLES code to calculate the updated pebble velocity profile taking the new temperature profile into account. If the aforementioned hypothesis is correct, the strong temperature effect upon the friction coefficients would cause the two cases to converge to different final velocity and temperature profiles. The results of this analysis indicates that a single zone pebble bed core is self-stabilizing in terms of the pebble velocity profile and the effect of the temperature profile on the pebble flow is insignificant. (authors)« less

Heat and mass transfer rates during flow of dissociated hydrogen gas over graphite surface

NASA Technical Reports Server (NTRS)

Nema, V. K.; Sharma, O. P.

1986-01-01

To improve upon the performance of chemical rockets, the nuclear reactor has been applied to a rocket propulsion system using hydrogen gas as working fluid and a graphite-composite forming a part of the structure. Under the boundary layer approximation, theoretical predictions of skin friction coefficient, surface heat transfer rate and surface regression rate have been made for laminar/turbulent dissociated hydrogen gas flowing over a flat graphite surface. The external stream is assumed to be frozen. The analysis is restricted to Mach numbers low enough to deal with the situation of only surface-reaction between hydrogen and graphite. Empirical correlations of displacement thickness, local skin friction coefficient, local Nusselt number and local non-dimensional heat transfer rate have been obtained. The magnitude of the surface regression rate is found low enough to ensure the use of graphite as a linear or a component of the system over an extended period without loss of performance.

High temperature resin matrix composites for aerospace structures

NASA Technical Reports Server (NTRS)

Davis, J. G., Jr.

1980-01-01

Accomplishments and the outlook for graphite-polyimide composite structures are briefly outlined. Laminates, skin-stiffened and honeycomb sandwich panels, chopped fiber moldings, and structural components were fabricated with Celion/LARC-160 and Celion/PMR-15 composite materials. Interlaminar shear and flexure strength data obtained on as-fabricated specimens and specimens that were exposed for 125 hours at 589 K indicate that epoxy sized and polyimide sized Celion graphite fibers exhibit essentially the same behavior in a PMR-15 matrix composite. Analyses and tests of graphite-polyimide compression and shear panels indicate that utilization in moderately loaded applications offers the potential for achieving a 30 to 50 percent reduction in structural mass compared to conventional aluminum panels. Data on effects of moisture, temperature, thermal cycling, and shuttle fluids on mechanical properties indicate that both LARC-160 and PMR-15 are suitable matrix materials for a graphite-polyimide aft body flap. No technical road blocks to building a graphite-polyimide composite aft body flap are identified.

Evidence for Reduced, Carbon-rich Regions in the Solar Nebula from an Unusual Cometary Dust Particle

NASA Astrophysics Data System (ADS)

De Gregorio, Bradley T.; Stroud, Rhonda M.; Nittler, Larry R.; Kilcoyne, A. L. David

2017-10-01

Geochemical indicators in meteorites imply that most formed under relatively oxidizing conditions. However, some planetary materials, such as the enstatite chondrites, aubrite achondrites, and Mercury, were produced in reduced nebular environments. Because of large-scale radial nebular mixing, comets and other Kuiper Belt objects likely contain some primitive material related to these reduced planetary bodies. Here, we describe an unusual assemblage in a dust particle from comet 81P/Wild 2 captured in silica aerogel by the NASA Stardust spacecraft. The bulk of this ˜20 μm particle is comprised of an aggregate of nanoparticulate Cr-rich magnetite, containing opaque sub-domains composed of poorly graphitized carbon (PGC). The PGC forms conformal shells around tiny 5-15 nm core grains of Fe carbide. The C, N, and O isotopic compositions of these components are identical within errors to terrestrial standards, indicating a formation inside the solar system. Magnetite compositions are consistent with oxidation of reduced metal, similar to that seen in enstatite chondrites. Similarly, the core-shell structure of the carbide + PGC inclusions suggests a formation via FTT reactions on the surface of metal or carbide grains in warm, reduced regions of the solar nebula. Together, the nanoscale assemblage in the cometary particle is most consistent with the alteration of primary solids condensed from a C-rich, reduced nebular gas. The nanoparticulate components in the cometary particle provide the first direct evidence from comets of reduced, carbon-rich regions that were present in the solar nebula.

Processing, Microstructure, and Mechanical Properties of Interpenetrating Biomorphic Graphite/Copper Composites

NASA Astrophysics Data System (ADS)

Childers, Amanda Esther Sall

Composite properties can surpass those of the individual phases, allowing for the development of advanced, high-performance materials. Bio-inspired and naturally-derived materials have garnered attention as composite constituents due to their inherently efficient and complex structures. Wood-derived ceramics, produced by converting a wood precursor into a ceramic scaffold, can exhibit a wide range of microstructures depending on the wood species, including porosity, pore size and distribution, and connectivity. The focus of this work was to investigate the processing, microstructure, and properties of graphite/copper composites produced using wood-derived graphite scaffolds. Graphite/copper composites combine low specific gravity, high thermal conductivity, and tailorable thermal expansion properties, and due to the non-wetting behavior of copper to graphite, offer a unique system in which mechanically bonded interfaces in composites can be studied. Graphite scaffolds were produced from red oak, beech, and pine precursors using a catalytic pyrolyzation method, resulting in varying types of pore networks. Two infiltration methods were investigated to overcome challenges associated with non-wetting systems: copper electrodeposition and pressure-assisted melt infiltration. The phase distributions, constituent properties, interfacial characteristics, mechanical behavior, and load partitioning of these biomorphic graphite/copper composites were investigated, and were correlated to the wood species. The multi-domain feature sizes in the graphite scaffolds resulted in composites with copper relegated not only to the large, connected channels produced from the transport features in the wood, but also within the smaller, lower aspect ratio fibrous regions of the scaffold. Both features contributed to the mechanical behavior of the composites to varying degrees depending on the wood species. A multi-component predictive model also was developed and used to guide the additive-assisted electroplating of the graphitized scaffold, and helped illuminate the roles of plating additives in macro-sized channels. The model can be adapted for many material systems, sample geometries, and plating conditions to investigate the use of metal electrodeposition as a means of scaffold infiltration. Additionally, X-ray diffraction tomography was used to resolve position-dependent strain in a composite. The results of this nascent capability were discussed with respect to a two-component system under increasing uniaxial load, and compared to the results of conventional volume-averaged measurements.

The WSTIAC Quarterly. Volume 9, Number 3

DTIC Science & Technology

2010-01-25

program .[8] THE THORIUM FUEL CYCLE AND LFTR POWER PLANT The thorium fuel cycle is based on a series of neutron absorp- tion and beta decay processes...the fig- ure is a graphite matrix moderated MSR reactor with fuel salt mixture (ThF4-U233F4) being circulated by a pump through the core and to a...the core as purified salt. As one of the unique safety features, a melt-plug at the reactor bottom would permit the reactor fluid fuel to be drained

Carbon Solubility in Silicon-Iron-Bearing Metals during Core Formation on Mercury

NASA Technical Reports Server (NTRS)

Vander Kaaden, Kathleen E.; McCubbin, Francis M.; Ross, D. Kent; Rapp, Jennifer F.; Danielson, Lisa R.; Keller, Lindsay P.; Righter, Kevin

2016-01-01

Recent results obtained from the MErcury Surface, Space ENvironment, GEochemistry, and Ranging (MESSENGER) spacecraft showed the surface of Mercury has high S abundances (approximately 4 wt%) and low Iron(II) Oxide abundances (less than 2 wt%). Based on these extreme values, the oxygen fugacity of Mercury's surface materials was estimated to be approximately 3 to 7 log(sub 10) units below the IW buffer (Delta IW-3 to Delta IW-7). This highly reducing nature of the planet has resulted in a large core and relatively thin mantle, extending to only approximately 420 km depth (corresponding to a core-mantle boundary pressure of approximately 4-7 GPa) within the planet. Furthermore, MESSENGER results have suggested the presence of carbon on the surface of the planet. Previous experimental results from have also suggested the possibility of a primary floatation crust on Mercury composed of graphite, produced after a global magma ocean event. With these exotic conditions of this compositional end-member planet, it begs the question, what is the core composition of Mercury? Although no definitive conclusion has been reached, previous studies have made advances towards answering this question. Riner et al. and Chen et al. looked at iron sulfide systems and implemented various crystallization and layered core scenarios to try and determine the composition and structure of Mercury's core. Malavergne et al. examined core crystallization scenarios in the presence of sulfur and silicon. Hauck et al. used the most recent geophysical constraints from the MESSENGER spacecraft to model the internal structure of Mercury, including the core, in a iron-sulfur-silicon system. More recently, Chabot et al. conducted a series of metal-silicate partitioning experiments in a iron-sulfur-silicon system. These results showed the core of Mercury has the potential to contain more than 15 wt% silicon. However, with the newest results from MESSENGER's low altitude campaign, carbon is another potential light element that could be incorporated into Mercury's core. The goal of this study is to determine the carbon concentration at graphite saturation in various silicon-iron bearing metals relevant to possible mercurian core compositions. Future experiments will include the addition of sulfur into these metals.

The Investigation and Development of Low Cost Hardware Components for Proton-Exchange Membrane Fuel Cells - Final Report

DOE Office of Scientific and Technical Information (OSTI.GOV)

George A. Marchetti

1999-12-15

Proton exchange membrane (PEM) fuel cell components, which would have a low-cost structure in mass production, were fabricated and tested. A fuel cell electrode structure, comprising a thin layer of graphite (50 microns) and a front-loaded platinum catalyst layer (600 angstroms), was shown to produce significant power densities. In addition, a PEM bipolar plate, comprising flexible graphite, carbon cloth flow-fields and an integrated polymer gasket, was fabricated. Power densities of a two-cell unit using this inexpensive bipolar plate architecture were shown to be comparable to state-of-the-art bipolar plates.

Eddy current inspection of graphite fiber components

NASA Technical Reports Server (NTRS)

Workman, G. L.; Bryson, C. C.

1990-01-01

The recognition of defects in materials properties still presents a number of problems for nondestructive testing in aerospace systems. This project attempts to utilize current capabilities in eddy current instrumentation, artificial intelligence, and robotics in order to provide insight into defining geometrical aspects of flaws in composite materials which are capable of being evaluated using eddy current inspection techniques. The unique capabilities of E-probes and horseshoe probes for inspecting probes for inspecting graphite fiber materials were evaluated and appear to hold great promise once the technology development matures. The initial results are described of modeling eddy current interactions with certain flaws in graphite fiber samples.

Graphite/epoxy composite adapters for the Space Shuttle/Centaur vehicle

NASA Technical Reports Server (NTRS)

Kasper, Harold J.; Ring, Darryl S.

1990-01-01

The decision to launch various NASA satellite and Air Force spacecraft from the Space Shuttle created the need for a high-energy upper stage capable of being deployed from the cargo bay. Two redesigned versions of the Centaur vehicle which employed a graphite/epoxy composite material for the forward and aft adapters were selected. Since this was the first time a graphite/epoxy material was used for Centaur major structural components, the development of the adapters was a major effort. An overview of the composite adapter designs, subcomponent design evaluation test results, and composite adapter test results from a full-scale vehicle structural test is presented.

Nature of very small grains - PAH molecules or silicates?. [Polycyclic Aromatic Hydrocarbon in interstellar dust

NASA Technical Reports Server (NTRS)

Desert, F. X.; Leger, A.; Puget, J. L.; Boulanger, F.; Sellgren, K.

1986-01-01

The predictions of the model of Puget et al. (1985) for the emission from Very Small Grains (VSGs) including both graphitic and silicate components are compared with published 8-13-micron observations of astronomical sources. The VSGs are found to be mainly graphitic and an upper limit is placed on the relative mass of silicates based on lack of the 9.7-micron silicate emission feature on M 82 and NGC 2023. This dissymetry in the composition of VSGs supports the suggestion that they are formed in grain-grain collisions where the behaviors of graphite and silicate grains are expected to be quite different.

Compacted graphite iron: Cast iron makes a comeback

NASA Astrophysics Data System (ADS)

Dawson, S.

1994-08-01

Although compacted graphite iron has been known for more than four decades, the absence of a reliable mass-production technique has resulted in relatively little effort to exploit its operational benefits. However, a proven on-line process control technology developed by SinterCast allows for series production of complex components in high-quality CGI. The improved mechanical properties of compacted graphite iron relative to conventional gray iron allow for substantial weight reduction in gasoline and diesel engines or substantial increases in horsepower, or an optimal combination of both. Concurrent with these primary benefits, CGI also provides significant emissions and fuel efficiency benefits allowing automakers to meet legislated performance standards. The operational and environmental benefits of compacted graphite iron together with its low cost and recyclability reinforce cast iron as a prime engineering material for the future.

Chamber-core structures for fairing acoustic mitigation

NASA Astrophysics Data System (ADS)

Ardelean, Emil; Williams, Andrew; Korshin, Nicholas; Henderson, Kyle; Lane, Steven; Richard, Robert

2005-05-01

Extreme noise and vibration levels at lift-off and during ascent can damage sensitive payload components. Recently, the Air Force Research Laboratory, Space Vehicles Directorate has investigated a composite structure fabrication approach, called chamber-core, for building payload fairings. Chamber-core offers a strong, lightweight structure with inherent noise attenuation characteristics. It uses one-inch square axial tubes that are sandwiched between inner and outer face-sheets to form a cylindrical fairing structure. These hollow tubes can be used as acoustic dampers to attenuate the amplitude response of low frequency acoustic resonances within the fairing"s volume. A cylindrical, graphite-epoxy chamber-core structure was built to study noise transmission characteristics and to quantify the achievable performance improvement. The cylinder was tested in a semi-reverberant acoustics laboratory using bandlimited random noise at sound pressure levels up to 110 dB. The performance was measured using external and internal microphones. The noise reduction was computed as the ratio of the spatially averaged external response to the spatially averaged interior response. The noise reduction provided by the chamber-core cylinder was measured over three bandwidths, 20 Hz to 500 Hz, 20 Hz to 2000 Hz, and 20 Hz to 5000 Hz. For the bare cylinder with no acoustic resonators, the structure provided approximately 13 dB of attenuation over the 20 Hz to 500 Hz bandwidth. With the axial tubes acting as acoustic resonators at various frequencies over the bandwidth, the noise reduction provided by the cylinder increased to 18.2 dB, an overall increase of 4.8 dB over the bandwidth. Narrow-band reductions greater than 10 dB were observed at specific low frequency acoustic resonances. This was accomplished with virtually no added mass to the composite cylinder.

Advanced Materials and Fabrication Techniques for the Orion Attitude Control Motor

NASA Technical Reports Server (NTRS)

Gorti, Sridhar; Holmes, Richard; O'Dell, John; McKechnie, Timothy; Shchetkovskiy, Anatoliy

2013-01-01

Rhenium, with its high melting temperature, excellent elevated temperature properties, and lack of a ductile-to-brittle transition temperature (DBTT), is ideally suited for the hot gas components of the ACM (Attitude Control Motor), and other high-temperature applications. However, the high cost of rhenium makes fabricating these components using conventional fabrication techniques prohibitive. Therefore, near-net-shape forming techniques were investigated for producing cost-effective rhenium and rhenium alloy components for the ACM and other propulsion applications. During this investigation, electrochemical forming (EL-Form ) techniques were evaluated for producing the hot gas components. The investigation focused on demonstrating that EL-Form processing techniques could be used to produce the ACM flow distributor. Once the EL-Form processing techniques were established, a representative rhenium flow distributor was fabricated, and samples were harvested for material properties testing at both room and elevated temperatures. As a lower cost and lighter weight alternative to an all-rhenium component, rhenium- coated graphite and carbon-carbon were also evaluated. The rhenium-coated components were thermal-cycle tested to verify that they could withstand the expected thermal loads during service. High-temperature electroforming is based on electrochemical deposition of compact layers of metals onto a mandrel of the desired shape. Mandrels used for electro-deposition of near-net shaped parts are generally fabricated from high-density graphite. The graphite mandrel is easily machined and does not react with the molten electrolyte. For near-net shape components, the inner surface of the electroformed part replicates the polished graphite mandrel. During processing, the mandrel itself becomes the cathode, and scrap or refined refractory metal is the anode. Refractory metal atoms from the anode material are ionized in the molten electrolytic solution, and are deposited onto the cathodic mandrel by electrochemical reduction. Rotation of the mandrel ensures uniform distribution of refractory material. The EL-Form process allows for manufacturing in an inert atmosphere with deposition rates from 0.0004 to 0.002 in./h (10.2 to 50.8 m/h). Thicknesses typically range from microns to greater than 0.5 in. (13 mm). The refractory component produced is fabricated, dependably, to within one micron of the desired tolerances with no shrinkage or distortion as in other refractory metal manufacture techniques. The electroforming process has been used to produce solid, nonporous deposits of rhenium, iridium, niobium, tungsten, and their alloys.

Comparative study on neutron data in integral experiments of MYRRHA mockup critical cores in the VENUS-F reactor

NASA Astrophysics Data System (ADS)

Krása, Antonín; Kochetkov, Anatoly; Baeten, Peter; Vittiglio, Guido; Wagemans, Jan; Bécares, Vicente

2017-09-01

VENUS-F is a fast, zero-power reactor with 30% wt. metallic uranium fuel and solid lead as coolant simulator. It serves as a mockup of the MYRRHA reactor core. This paper describes integral experiments performed in two critical VENUS-F core configurations (with and without graphite reflector). Discrepancies between experiments and Monte Carlo calculations (MCNP5) of keff, fission rate spatial distribution and reactivity effects (lead void and fuel Doppler) depending on a nuclear data library used (JENDL-4.0, ENDF-B-VII.1, JEFF-3.1.2, 3.2, 3.3T2) are presented.

Ultrafast core-loss spectroscopy in four-dimensional electron microscopy

PubMed Central

van der Veen, Renske M.; Penfold, Thomas J.; Zewail, Ahmed H.

2015-01-01

We demonstrate ultrafast core-electron energy-loss spectroscopy in four-dimensional electron microscopy as an element-specific probe of nanoscale dynamics. We apply it to the study of photoexcited graphite with femtosecond and nanosecond resolutions. The transient core-loss spectra, in combination with ab initio molecular dynamics simulations, reveal the elongation of the carbon-carbon bonds, even though the overall behavior is a contraction of the crystal lattice. A prompt energy-gap shrinkage is observed on the picosecond time scale, which is caused by local bond length elongation and the direct renormalization of band energies due to temperature-dependent electron–phonon interactions. PMID:26798793

Effect of reactor radiation on the thermal conductivity of TREAT fuel

DOE PAGES

Mo, Kun; Miao, Yinbin; Kontogeorgakos, Dimitrios C.; ...

2017-02-04

The Transient Reactor Test Facility (TREAT) at the Idaho National Laboratory is resuming operations after more than 20 years in latency in order to produce high-neutron-flux transients for investigating transient-induced behavior of reactor fuels and their interactions with other materials and structures. A parallel program is ongoing to develop a replacement core in which the fuel, historically containing highly-enriched uranium (HEU), is replaced by low-enriched uranium (LEU). Both the HEU and prospective LEU fuels are in the form of UO 2 particles dispersed in a graphite matrix, but the LEU fuel will contain a much higher volume of UO 2more » particles, which may create a larger area of interphase boundaries between the particles and the graphite. This may lead to a higher volume fraction of graphite exposed to the fission fragments escaping from the UO 2 particles, and thus may induce a higher volume of fission-fragment damage on the fuel graphite. In this work, we analyzed the reactor-radiation induced thermal conductivity degradation of graphite-based dispersion fuel. A semi-empirical method to model the relative thermal conductivity with reactor radiation was proposed and validated based on the available experimental data. Prediction of thermal conductivity degradation of LEU TREAT fuel during a long-term operation was performed, with a focus on the effect of UO 2 particle size on fission-fragment damage. Lastly, the proposed method can be further adjusted to evaluate the degradation of other properties of graphite-based dispersion fuel.« less

Effect of reactor radiation on the thermal conductivity of TREAT fuel

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mo, Kun; Miao, Yinbin; Kontogeorgakos, Dimitrios C.

The Transient Reactor Test Facility (TREAT) at the Idaho National Laboratory is resuming operations after more than 20 years in latency in order to produce high-neutron-flux transients for investigating transient-induced behavior of reactor fuels and their interactions with other materials and structures. A parallel program is ongoing to develop a replacement core in which the fuel, historically containing highly-enriched uranium (HEU), is replaced by low-enriched uranium (LEU). Both the HEU and prospective LEU fuels are in the form of UO 2 particles dispersed in a graphite matrix, but the LEU fuel will contain a much higher volume of UO 2more » particles, which may create a larger area of interphase boundaries between the particles and the graphite. This may lead to a higher volume fraction of graphite exposed to the fission fragments escaping from the UO 2 particles, and thus may induce a higher volume of fission-fragment damage on the fuel graphite. In this work, we analyzed the reactor-radiation induced thermal conductivity degradation of graphite-based dispersion fuel. A semi-empirical method to model the relative thermal conductivity with reactor radiation was proposed and validated based on the available experimental data. Prediction of thermal conductivity degradation of LEU TREAT fuel during a long-term operation was performed, with a focus on the effect of UO 2 particle size on fission-fragment damage. Lastly, the proposed method can be further adjusted to evaluate the degradation of other properties of graphite-based dispersion fuel.« less

Thermal neutron flux measurement using self-powered neutron detector (SPND) at out-core locations of TRIGA PUSPATI Reactor (RTP)

NASA Astrophysics Data System (ADS)

Ali, Nur Syazwani Mohd; Hamzah, Khaidzir; Mohamad Idris, Faridah; Hairie Rabir, Mohamad

2018-01-01

The thermal neutron flux measurement has been conducted at the out-core location using self-powered neutron detectors (SPNDs). This work represents the first attempt to study SPNDs as neutron flux sensor for developing the fault detection system (FDS) focusing on neutron flux parameters. The study was conducted to test the reliability of the SPND’s signal by measuring the neutron flux through the interaction between neutrons and emitter materials of the SPNDs. Three SPNDs were used to measure the flux at four different radial locations which located at the fission chamber cylinder, 10cm above graphite reflector, between graphite reflector and tank liner and fuel rack. The measurements were conducted at 750 kW reactor power. The outputs from SPNDs were collected through data acquisition system and were corrected to obtain the actual neutron flux due to delayed responses from SPNDs. The measurements showed that thermal neutron flux between fission chamber location near to the tank liner and fuel rack were between 5.18 × 1011 nv to 8.45 × 109 nv. The average thermal neutron flux showed a good agreement with those from previous studies that has been made using simulation at the same core configuration at the nearest irradiation facilities with detector locations.

NASA Tech Briefs, June 2011

NASA Technical Reports Server (NTRS)

2011-01-01

Topics covered include: Wind and Temperature Spectrometry of the Upper Atmosphere in Low-Earth Orbit; Health Monitor for Multitasking, Safety-Critical, Real-Time Software; Stereo Imaging Miniature Endoscope; Early Oscillation Detection Technique for Hybrid DC/DC Converters; Parallel Wavefront Analysis for a 4D Interferometer; Schottky Heterodyne Receivers With Full Waveguide Bandwidth; Carbon Nanofiber-Based, High-Frequency, High-Q, Miniaturized Mechanical Resonators; Ultracapacitor-Based Uninterrupted Power Supply System; Coaxial Cables for Martian Extreme Temperature Environments; Using Spare Logic Resources To Create Dynamic Test Points; Autonomous Coordination of Science Observations Using Multiple Spacecraft; Autonomous Phase Retrieval Calibration; EOS MLS Level 1B Data Processing Software, Version 3; Cassini Tour Atlas Automated Generation; Software Development Standard Processes (SDSP); Graphite Composite Panel Polishing Fixture; Material Gradients in Oxygen System Components Improve Safety; Ridge Waveguide Structures in Magnesium-Doped Lithium Niobate; Modifying Matrix Materials to Increase Wetting and Adhesion; Lightweight Magnetic Cooler With a Reversible Circulator; The Invasive Species Forecasting System; Method for Cleanly and Precisely Breaking Off a Rock Core Using a Radial Compressive Force; Praying Mantis Bending Core Breakoff and Retention Mechanism; Scoring Dawg Core Breakoff and Retention Mechanism; Rolling-Tooth Core Breakoff and Retention Mechanism; Vibration Isolation and Stabilization System for Spacecraft Exercise Treadmill Devices; Microgravity-Enhanced Stem Cell Selection; Diagnosis and Treatment of Neurological Disorders by Millimeter-Wave Stimulation; Passive Vaporizing Heat Sink; Remote Sensing and Quantization of Analog Sensors; Phase Retrieval for Radio Telescope and Antenna Control; Helium-Cooled Black Shroud for Subscale Cryogenic Testing; Receive Mode Analysis and Design of Microstrip Reflectarrays; and Chance-Constrained Guidance With Non-Convex Constraints.

Thermal-mechanical behavior of high precision composite mirrors

NASA Technical Reports Server (NTRS)

Kuo, C. P.; Lou, M. C.; Rapp, D.

1993-01-01

Composite mirror panels were designed, constructed, analyzed, and tested in the framework of a NASA precision segmented reflector task. The deformations of the reflector surface during the exposure to space enviroments were predicted using a finite element model. The composite mirror panels have graphite-epoxy or graphite-cyanate facesheets, separated by an aluminum or a composite honeycomb core. It is pointed out that in order to carry out detailed modeling of composite mirrors with high accuracy, it is necessary to have temperature dependent properties of the materials involved and the type and magnitude of manufacturing errors and material nonuniformities. The structural modeling and analysis efforts addressed the impact of key design and materials parameters on the performance of mirrors.

Impact-damaged graphite-thermoplastic trapezoidal-corrugation sandwich and semi-sandwich panels

NASA Technical Reports Server (NTRS)

Jegley, D.

1993-01-01

The results of a study of the effects of impact damage on compression-loaded trapezoidal-corrugation sandwich and semi-sandwich graphite-thermoplastic panels are presented. Sandwich panels with two identical face sheets and a trapezoidal corrugated core between them, and semi-sandwich panels with a corrugation attached to a single skin are considered in this study. Panels were designed, fabricated and tested. The panels were made using the manufacturing process of thermoforming, a less-commonly used technique for fabricating composite parts. Experimental results for unimpacted control panels and panels subjected to impact damage prior to loading are presented. Little work can be found in the literature about these configurations of thermoformed panels.

Molecular dynamics investigations of liquid-vapor interaction and adsorption of formaldehyde, oxocarbons, and water in graphitic slit pores.

PubMed

Huang, Pei-Hsing; Hung, Shang-Chao; Huang, Ming-Yueh

2014-08-07

Formaldehyde exposure has been associated with several human cancers, including leukemia and nasopharyngeal carcinoma, motivating the present investigation on the microscopic adsorption behaviors of formaldehyde in multi-component-mixture-filled micropores. Molecular dynamics (MD) simulation was used to investigate the liquid-vapor interaction and adsorption of formaldehyde, oxocarbons, and water in graphitic slit pores. The effects of the slit width, system temperature, concentration, and the constituent ratio of the mixture on the diffusion and adsorption properties are studied. As a result of interactions between the components, the z-directional self-diffusivity (D(z)) in the mixture substantially decreased by about one order of magnitude as compared with that of pure (single-constituent) adsorbates. When the concentration exceeds a certain threshold, the D(z) values dramatically decrease due to over-saturation inducing barriers to diffusion. The binding energy between the adsorbate and graphite at the first adsorption monolayer is calculated to be 3.99, 2.01, 3.49, and 2.67 kcal mol(-1) for CO2, CO, CH2O, and H2O, respectively. These values agree well with those calculated using the density functional theory coupled cluster method and experimental results. A low solubility of CO2 in water and water preferring to react with CH2O, forming hydrated methanediol clusters, are observed. Because the cohesion in a hydrated methanediol cluster is much higher than the adhesion between clusters and the graphitic surface, the hydrated methanediol clusters were hydrophobic, exhibiting a large contact angle on graphite.

Visible and infrared optical properties of stacked cone graphite microtubes.

PubMed

Bruce, Charles W; Alyones, Sharhabeel

2012-06-01

The absorptive and scattering optical properties of heat-treated, vapor-grown, graphite microtubes consisting of nanotubes in a "stacked cone" configuration were investigated through the visible and infrared wavelengths using photoacoustic and other spectrometric techniques. However, computations of these properties involved uncertainties that were not easily resolved; the appropriate dielectric coefficients were presumed to be a combination of the published values for the distinct orientations of graphite, but the correct proportions are not evident and none of the reasonable choices produced satisfactory agreement (within the measurement limits of error). Since both of the primary components of the extinction were measured, the appropriate computational codes were employed in reverse to compute the dielectric coefficients for the graphite microtubes. Differences, primarily for the imaginary index, are most distinct for visible and near infrared wavelengths; in this wavelength region, the imaginary index falls progressively to less than half that for the computed mixture.

An investigation on the effects of phase change material on material components used for high temperature thermal energy storage system

NASA Astrophysics Data System (ADS)

Kim, Taeil; Singh, Dileep; Zhao, Weihuan; Yua, Wenhua; France, David M.

2016-05-01

The latent heat thermal energy storage (LHTES) systems for concentrated solar power (CSP) plants with advanced power cycle require high temperature phase change materials (PCMs), Graphite foams with high thermal conductivity to enhance the poor thermal conductivity of PCMs. Brazing of the graphite foams to the structural metals of the LHTES system could be a method to assemble the system and a method to protect the structural metals from the molten salts. In the present study, the LHTES prototype capsules using MgCl2-graphite foam composites were assembled by brazing and welding, and tested to investigate the corrosion attack of the PCM salt on the BNi-4 braze. The microstructural analysis showed that the BNi-4 braze alloy can be used not only for the joining of structure alloy to graphite foams but also for the protecting of structure alloy from the corrosion by PCM.

Thermal Pyrolytic Graphite Enhanced Components

NASA Technical Reports Server (NTRS)

Hardesty, Robert E. (Inventor)

2015-01-01

A thermally conductive composite material, a thermal transfer device made of the material, and a method for making the material are disclosed. Apertures or depressions are formed in aluminum or aluminum alloy. Plugs are formed of thermal pyrolytic graphite. An amount of silicon sufficient for liquid interface diffusion bonding is applied, for example by vapor deposition or use of aluminum silicon alloy foil. The plugs are inserted in the apertures or depressions. Bonding energy is applied, for example by applying pressure and heat using a hot isostatic press. The thermal pyrolytic graphite, aluminum or aluminum alloy and silicon form a eutectic alloy. As a result, the plugs are bonded into the apertures or depressions. The composite material can be machined to produce finished devices such as the thermal transfer device. Thermally conductive planes of the thermal pyrolytic graphite plugs may be aligned in parallel to present a thermal conduction path.

The vulnerability of commercial aircraft avionics to carbon fibers

NASA Technical Reports Server (NTRS)

Meyers, J. A.; Salmirs, S.

1980-01-01

Avionics components commonly used in commercial aircraft were tested for vulnerability to failure when operated in an environment with a high density of graphite fibers. The components were subjected to a series of exposures to graphite fibers of different lengths. Lengths used for the tests were (in order) 1 mm, 3 mm, and 10 mm. The test procedure included subjecting the equipment to characteristic noise and shock environments. Most of the equipment was invulnerable or did not fail until extremely high average exposures were reached. The single exception was an air traffic control transponder produced in the early 1960's. It had the largest case open area through which fibers could enter and it had no coated boards.

Anomalous Complex Electrical Conductivity of a Graphitic Black Schist From the Himalayas of Central Nepal

NASA Astrophysics Data System (ADS)

Börner, Jana H.; Girault, Frédéric; Bhattarai, Mukunda; Adhikari, Lok Bijaya; Deldicque, Damien; Perrier, Frédéric; Spitzer, Klaus

2018-05-01

We analyzed in the laboratory the frequency-dependent, complex-valued, electrical conductivity of a graphitic black schist and an augen gneiss, both collected in the Main Central Thrust shear zone in the Himalayas of central Nepal, which was heavily affected by the deadly Mw7.8 Gorkha earthquake in 2015. We focused on anisotropy and salinity dependence of both cores and crushed material as well as the impact of CO2 on conductivity. This black schist possesses an extraordinarily high polarizability and a highly frequency-dependent conductivity. Its anisotropy is very pronounced. The investigations can relate the main polarization feature to disseminated, aligned plates of graphite. By contrast, the augen gneiss shows low polarizability and a moderately anisotropic conductivity dominated by the pore-filling brine. We further demonstrate that neglecting the complex and frequency-dependent nature of conductivity can lead to serious misinterpretation of magnetotelluric data during inversion if highly polarizable rocks are present.

Ultrathin nitrogen-doped graphitized carbon shell encapsulating CoRu bimetallic nanoparticles for enhanced electrocatalytic hydrogen evolution

NASA Astrophysics Data System (ADS)

Xu, You; Li, Yinghao; Yin, Shuli; Yu, Hongjie; Xue, Hairong; Li, Xiaonian; Wang, Hongjing; Wang, Liang

2018-06-01

Design of highly active and cost-effective electrocatalysts is very important for the generation of hydrogen by electrochemical water-splitting. Herein, we report the fabrication of ultrathin nitrogen-doped graphitized carbon shell encapsulating CoRu bimetallic nanoparticles (CoRu@NCs) and demonstrate their promising feasibility for efficiently catalyzing the hydrogen evolution reaction (HER) over a wide pH range. The resultant CoRu@NC nanohybrids possess an alloy–carbon core–shell structure with encapsulated low-ruthenium-content CoRu bimetallic alloy nanoparticles (10–30 nm) as the core and ultrathin nitrogen-doped graphitized carbon layers (2–6 layers) as the shell. Remarkably, the optimized catalyst (CoRu@NC-2 sample) with a Ru content as low as 2.04 wt% shows superior catalytic activity and excellent durability for HER in acidic, neutral, and alkaline conditions. This work offers a new method for the design and synthesis of non-platium-based electrocatalysts for HER in all-pH.

Environmentally-friendly oxygen-free roasting/wet magnetic separation technology for in situ recycling cobalt, lithium carbonate and graphite from spent LiCoO2/graphite lithium batteries.

PubMed

Li, Jia; Wang, Guangxu; Xu, Zhenming

2016-01-25

The definite aim of the present paper is to present some novel methods that use oxygen-free roasting and wet magnetic separation to in situ recycle of cobalt, Lithium Carbonate and Graphite from mixed electrode materials. The in situ recycling means to change waste into resources by its own components, which is an idea of "waste+waste→resources." After mechanical scraping the mixed electrode materials enrich powders of LiCoO2 and graphite. The possible reaction between LiCoO2 and graphite was obtained by thermodynamic analysis. The feasibility of the reaction at high temperature was studied with the simultaneous thermogravimetry analysis under standard atmospheric pressure. Then the oxygen-free roasting/wet magnetic separation method was used to transfer the low added value mixed electrode materials to high added value products. The results indicated that, through the serious technologies of oxygen-free roasting and wet magnetic separation, mixture materials consist with LiCoO2 and graphite powders are transferred to the individual products of cobalt, Lithium Carbonate and Graphite. Because there is not any chemical solution added in the process, the cost of treating secondary pollution can be saved. This study provides a theoretical basis for industrial-scale recycling resources from spent LIBs. Copyright © 2015 Elsevier B.V. All rights reserved.

Data Report on Post-Irradiation Dimensional Change of AGC-1 Samples

DOE Office of Scientific and Technical Information (OSTI.GOV)

William Windes

This report summarizes the initial dimensional changes for loaded and unloaded AGC-1 samples. The dimensional change for all samples is presented as a function of dose. The data is further presented by graphite type and applied load levels to illustrate the differences between graphite forming processes and stress levels within the graphite components. While the three different loads placed on the samples have been verified [ ref: Larry Hull’s report] verification of the AGC-1 sample temperatures and dose levels are expected in the summer of 2012. Only estimated dose and temperature values for the samples are presented in this reportmore » to allow a partial analysis of the results.« less

Dielectric properties of novel polyurethane-PZT-graphite foam composites

NASA Astrophysics Data System (ADS)

Tolvanen, Jarkko; Hannu, Jari; Nelo, Mikko; Juuti, Jari; Jantunen, Heli

2016-09-01

Flexible foam composite materials offer multiple benefits to future electronic applications as the rapid development of the electronics industry requires smaller, more efficient, and lighter materials to further develop foldable and wearable applications. The aims of this work were to examine the electrical properties of three- and four-phase novel foam composites in different conditions, find the optimal mixture for four-phase foam composites, and study the combined effects of lead zirconate titanate (PZT) and graphite fillers. The flexible and highly compressible foams were prepared in a room-temperature mixing process using polyurethane, PZT, and graphite components as well as their combinations, in which air acted as one phase. In three-phase foams the amount of PZT varied between 20 and 80 wt% and the amount of graphite, between 1 and 15 wt%. The four-phase foams were formed by adding 40 wt% of PZT while the amount of graphite ranged between 1 and 15 wt%. The presented results and materials could be utilized to develop new flexible and soft sensor applications by means of material technology.

Magnetic carbon nanostructures: microwave energy-assisted pyrolysis vs. conventional pyrolysis.

PubMed

Zhu, Jiahua; Pallavkar, Sameer; Chen, Minjiao; Yerra, Narendranath; Luo, Zhiping; Colorado, Henry A; Lin, Hongfei; Haldolaarachchige, Neel; Khasanov, Airat; Ho, Thomas C; Young, David P; Wei, Suying; Guo, Zhanhu

2013-01-11

Magnetic carbon nanostructures from microwave assisted- and conventional-pyrolysis processes are compared. Unlike graphitized carbon shells from conventional heating, different carbon shell morphologies including nanotubes, nanoflakes and amorphous carbon were observed. Crystalline iron and cementite were observed in the magnetic core, different from a single cementite phase from the conventional process.

Organic geochemistry of core samples from an ultradeep hot well (300°C, 7 km)

USGS Publications Warehouse

Price, Leigh C.

1982-01-01

Concepts prevelant among petroleum organic geochemists concerning the thermal fate of hydrocarbons, with subsequent graphite formation, and greenschist metamorphism, are in sharp contradiction to these data. Conventional concepts of the distribution of heavy hydrocarbons with increasing temperature and depth apparently require further review and revision.

Analysis of granular flow in a pebble-bed nuclear reactor.

PubMed

Rycroft, Chris H; Grest, Gary S; Landry, James W; Bazant, Martin Z

2006-08-01

Pebble-bed nuclear reactor technology, which is currently being revived around the world, raises fundamental questions about dense granular flow in silos. A typical reactor core is composed of graphite fuel pebbles, which drain very slowly in a continuous refueling process. Pebble flow is poorly understood and not easily accessible to experiments, and yet it has a major impact on reactor physics. To address this problem, we perform full-scale, discrete-element simulations in realistic geometries, with up to 440,000 frictional, viscoelastic 6-cm-diam spheres draining in a cylindrical vessel of diameter 3.5m and height 10 m with bottom funnels angled at 30 degrees or 60 degrees. We also simulate a bidisperse core with a dynamic central column of smaller graphite moderator pebbles and show that little mixing occurs down to a 1:2 diameter ratio. We analyze the mean velocity, diffusion and mixing, local ordering and porosity (from Voronoi volumes), the residence-time distribution, and the effects of wall friction and discuss implications for reactor design and the basic physics of granular flow.

Decoding structural complexity in conical carbon nanofibers.

PubMed

Zhu, Yi-An; Wang, Zi-Jun; Cheng, Hong-Ye; Yang, Qin-Min; Sui, Zhi-Jun; Zhou, Xing-Gui; Chen, De

2017-06-07

Conical carbon nanofibers (CNFs) exist primarily as graphitic ribbons that fold into a cylindrical structure with the formation of a hollow core. Structural analysis aided by molecular modeling proves useful for obtaining a full picture of how the size of the central channel varies from fiber to fiber. From a geometrical perspective, conical CNFs possibly have cone tips that are nearly closed. On the other hand, their fiber wall thickness can be reduced to a minimum possible value that is determined solely by the apex angle, regardless of the outer diameter. A formula has been developed to express the number of carbon atoms present in conical CNFs in terms of measurable structural parameters. It appears that the energetically preferred fiber wall thickness increases not only with the apex angle, but also with the number of atoms in the constituent graphitic cones. The origin of the empirical observation that conical CNFs with small apex angles tend to have a large hollow core lies in the fact that in graphene sheets that are more highly curved the curvature-induced strain energy rises more rapidly as the fiber wall thickens.

Briefing Book. Volume 1: The Evolution of the Nuclear Non-Proliferation Regime (Fourth Edition).

DTIC Science & Technology

1998-01-01

usually termed) nuclear reactors. The first of these is that they contain a core or mass of fissile material (the fuel ) which may weigh tens of tons... HTGR is cooled with helium gas and moderated with graphite. Highly enriched uranium is used as fuel (93 per cent U-235), though this may be mixed with...to convert U-238 in a blanket around the core into Pu-239 at a rate faster than its own consumption of fissile material. They thus produce more fuel

Porous and Cellular Materials for Structural Applications; Symposium Held in San Francisco, California on April 13-15, 1998

DTIC Science & Technology

1998-04-01

Industrial Scale 179 M. Schmidt and F. Schwertfeger Structural Graphitic Carbon Foams 185 Kristen M. Kearns, David P. Anderson, and Heather J...Nanostructured Powders and Their Industrial Application, Q. Beaucage, J.E. Mark, Q. Burns, H. Duen-Wu, 1998, ISBN: 1-55899-426-2 Volume 521—Porous and Cellular...has faces which are 0.03" thick and the core is 0.4" thick. Bonding between the core and face is achieved using a standard industrial epoxy adhesive

Development of autoclave moldable addition-type polyimides

NASA Technical Reports Server (NTRS)

Vaughan, R. W.; Jones, R. J.; Orell, M. K.; Zakrzewski, G. A.

1976-01-01

Chemistry and processing modifications of the poly(Diels Alder) polyimide (PDA) resin were performed to obtain structural composites suitable for 589 K (600 F) service. This work demonstrated that the PDA resin formulation is suitable for service at 589 K (600 F) for up to 125 hours when used in combination with Hercules HTS graphite fiber. Sandwich panels were autoclave molded using PDA/HTS skins and polyimide/glass honeycomb core. Excellent adhesion between honeycomb core and the facing skins was demonstrated. Fabrication ease was demonstrated by autoclave molding three-quarter scale YF-12 wing panels.

Advanced solar panel designs

NASA Technical Reports Server (NTRS)

Ralph, E. L.; Linder, E.

1995-01-01

This paper describes solar cell panel designs that utilize new hgih efficiency solar cells along with lightweight rigid panel technology. The resulting designs push the W/kg and W/sq m parameters to new high levels. These new designs are well suited to meet the demand for higher performance small satellites. This paper reports on progress made on two SBIR Phase 1 contracts. One panel design involved the use of large area (5.5 cm x 6.5 cm) GaAs/Ge solar cells of 19% efficiency combined with a lightweight rigid graphite fiber epoxy isogrid substrate configuration. A coupon (38 cm x 38 cm) was fabricated and tested which demonstrated an array specific power level of 60 W/kg with a potential of reaching 80 W/kg. The second panel design involved the use of newly developed high efficiency (22%) dual junction GaInP2/GaAs/Ge solar cells combined with an advanced lightweight rigid substrate using aluminum honeycomb core with high strength graphite fiber mesh facesheets. A coupon (38 cm x 38 cm) was fabricated and tested which demonstrated an array specific power of 105 W/kg and 230 W/sq m. This paper will address the construction details of the panels and an a analysis of the component weights. A strawman array design suitable for a typical small-sat mission is described for each of the two panel design technologies being studied. Benefits in respect to weight reduction, area reduction, and system cost reduction are analyzed and compared to conventional arrays.

Impact of speciation on the electron charge transfer properties of nanodiamond drug carriers

NASA Astrophysics Data System (ADS)

Sun, Baichuan; Barnard, Amanda S.

2016-07-01

Unpassivated diamond nanoparticles (bucky-diamonds) exhibit a unique surface reconstruction involving graphitization of certain crystal facets, giving rise to hybrid core-shell particles containing both aromatic and aliphatic carbon. Considerable effort is directed toward eliminating the aromatic shell, but persistent graphitization of subsequent subsurface-layers makes perdurable purification a challenge. In this study we use some simple statistical methods, in combination with electronic structure simulations, to predict the impact of different fractions of aromatic and aliphatic carbon on the charge transfer properties of the ensembles of bucky-diamonds. By predicting quality factors for a variety of cases, we find that perfect purification is not necessary to preserve selectivity, and there is a clear motivation for purifying samples to improve the sensitivity of charge transfer reactions. This may prove useful in designing drug delivery systems where the release of (selected) drugs needs to be sensitive to specific conditions at the point of delivery.Unpassivated diamond nanoparticles (bucky-diamonds) exhibit a unique surface reconstruction involving graphitization of certain crystal facets, giving rise to hybrid core-shell particles containing both aromatic and aliphatic carbon. Considerable effort is directed toward eliminating the aromatic shell, but persistent graphitization of subsequent subsurface-layers makes perdurable purification a challenge. In this study we use some simple statistical methods, in combination with electronic structure simulations, to predict the impact of different fractions of aromatic and aliphatic carbon on the charge transfer properties of the ensembles of bucky-diamonds. By predicting quality factors for a variety of cases, we find that perfect purification is not necessary to preserve selectivity, and there is a clear motivation for purifying samples to improve the sensitivity of charge transfer reactions. This may prove useful in designing drug delivery systems where the release of (selected) drugs needs to be sensitive to specific conditions at the point of delivery. Electronic supplementary information (ESI) available. See DOI: 10.1039/c6nr03068h

Nanocarbon: Defect Architectures and Properties

NASA Astrophysics Data System (ADS)

Vuong, Amanda

The allotropes of carbon make its solid phases amongst the most diverse of any element. It can occur naturally as graphite and diamond, which have very different properties that make them suitable for a wide range of technological and commercial purposes. Recent developments in synthetic carbon include Highly Oriented Pyrolytic Graphite (HOPG) and nano-carbons, such as fullerenes, nanotubes and graphene. The main industrial application of bulk graphite is as an electrode material in steel production, but in purified nuclear graphite form, it is also used as a moderator in Advanced Gas-cooled Reactors across the United Kingdom. Both graphene and graphite are damaged over time when subjected to bombardment by electrons, neutrons or ions, and these have a wide range of effects on their physical and electrical properties, depending on the radiation flux and temperature. This research focuses on intrinsic defects in graphene and dimensional change in nuclear graphite. The method used here is computational chemistry, which complements physical experiments. Techniques used comprise of density functional theory (DFT) and molecular dynamics (MD), which are discussed in chapter 2 and chapter 3, respectively. The succeeding chapters describe the results of simulations performed to model defects in graphene and graphite. Chapter 4 presents the results of ab initio DFT calculations performed to investigate vacancy complexes that are formed in AA stacked bilayer graphene. In AB stacking, carbon atoms surrounding the lattice vacancies can form interlayer structures with sp2 bonding that are lower in energy compared to in-plane reconstructions. From the investigation of AA stacking, sp2 interlayer bonding of adjacent multivacancy defects in registry creates a type of stable sp2 bonded wormhole between the layers. Also, a new class of mezzanine structure characterised by sp3 interlayer bonding, resembling a prismatic vacancy loop has also been identified. The mezzanine, which is a V6 hexavacancy variant, where six sp3 carbon atoms sit midway between two carbon layers and bond to both, is substantially more stable than any other vacancy aggregate in AA stacked layers. Chapter 5 presents the results of ab initio DFT calculations performed to investigate the wormhole and mezzanine defect that were identified in chapter 4 and the ramp defect discovered by Trevethan et al.. DFT calculations were performed on these defects in twisted bilayer graphene. From the investigation of vacancy complexes in twisted bilayer graphene, it is found that vacancy complexes are unstable in the twisted region and are more favourable in formation energy when the stacking arrangement is close to AA or AB stacking. It has also been discovered that the ramp defect is more stable in the twisted bilayer graphene compared to the mezzanine defect. Chapter 6 presents the results of ab initio DFT calculations performed to investigate a form of extending defect, prismatic edge dislocation. Suarez-Martinez et al.'s research suggest the armchair core is disconnected from any other layer, whilst the zigzag core is connected. In the investigation here, the curvature of the mezzanine defect allows it to swing between the armchair, zigzag and Klein in the AA stacking. For the AB stacking configuration, the armchair and zigzag core are connected from any other layer. Chapter 7 present results of MD simulations using the adaptive intermolecular reactive empirical bond order (AIREBO) potential to investigate the dimensional change of graphite due to the formation of vacancies present in a single crystal. It has been identified that there is an expansion along the c-axis, whilst a contraction along the a- and b- axes due to the coalescence of vacancy forming in-plane and between the layers. The results here are in good agreement with experimental studies of low temperature irradiation. The final chapter gives conclusions to this work.

Mars Mission Analysis Trades Based on Legacy and Future Nuclear Propulsion Options

NASA Astrophysics Data System (ADS)

Joyner, Russell; Lentati, Andrea; Cichon, Jaclyn

2007-01-01

The purpose of this paper is to discuss the results of mission-based system trades when using a nuclear thermal propulsion (NTP) system for Solar System exploration. The results are based on comparing reactor designs that use a ceramic-metallic (CERMET), graphite matrix, graphite composite matrix, or carbide matrix fuel element designs. The composite graphite matrix and CERMET designs have been examined for providing power as well as propulsion. Approaches to the design of the NTP to be discussed will include an examination of graphite, composite, carbide, and CERMET core designs and the attributes of each in regards to performance and power generation capability. The focus is on NTP approaches based on tested fuel materials within a prismatic fuel form per the Argonne National Laboratory testing and the ROVER/NERVA program. NTP concepts have been examined for several years at Pratt & Whitney Rocketdyne for use as the primary propulsion for human missions beyond earth. Recently, an approach was taken to examine the design trades between specific NTP concepts; NERVA-based (UC)C-Graphite, (UC,ZrC)C-Composite, (U,Zr)C-Solid Carbide and UO2-W CERMET. Using Pratt & Whitney Rocketdyne's multidisciplinary design analysis capability, a detailed mission and vehicle model has been used to examine how several of these NTP designs impact a human Mars mission. Trends for the propulsion system mass as a function of power level (i.e. thrust size) for the graphite-carbide and CERMET designs were established and correlated against data created over the past forty years. These were used for the mission trade study. The resulting mission trades presented in this paper used a comprehensive modeling approach that captures the mission, vehicle subsystems, and NTP sizing.

a Dosimetry Assessment for the Core Restraint of AN Advanced Gas Cooled Reactor

NASA Astrophysics Data System (ADS)

Thornton, D. A.; Allen, D. A.; Tyrrell, R. J.; Meese, T. C.; Huggon, A. P.; Whiley, G. S.; Mossop, J. R.

2009-08-01

This paper describes calculations of neutron damage rates within the core restraint structures of Advanced Gas Cooled Reactors (AGRs). Using advanced features of the Monte Carlo radiation transport code MCBEND, and neutron source data from core follow calculations performed with the reactor physics code PANTHER, a detailed model of the reactor cores of two of British Energy's AGR power plants has been developed for this purpose. Because there are no relevant neutron fluence measurements directly supporting this assessment, results of benchmark comparisons and successful validation of MCBEND for Magnox reactors have been used to estimate systematic and random uncertainties on the predictions. In particular, it has been necessary to address the known under-prediction of lower energy fast neutron responses associated with the penetration of large thicknesses of graphite.

Synthesis of monolithic graphene – graphite integrated electronics

PubMed Central

Park, Jang-Ung; Nam, SungWoo; Lee, Mi-Sun; Lieber, Charles M.

2013-01-01

Encoding electronic functionality into nanoscale elements during chemical synthesis has been extensively explored over the past decade as the key to developing integrated nanosystems1 with functions defined by synthesis2-6. Graphene7-12 has been recently explored as a two-dimensional nanoscale material, and has demonstrated simple device functions based on conventional top-down fabrication13-20. However, the synthetic approach to encoding electronic functionality and thus enabling an entire integrated graphene electronics in a chemical synthesis had not previously been demonstrated. Here we report an unconventional approach for the synthesis of monolithically-integrated electronic devices based on graphene and graphite. Spatial patterning of heterogeneous catalyst metals permits the selective growth of graphene and graphite, with controlled number of graphene layers. Graphene transistor arrays with graphitic electrodes and interconnects were formed from synthesis. These functional, all-carbon structures were transferrable onto a variety of substrates. The integrated transistor arrays were used to demonstrate real-time, multiplexed chemical sensing, and more significantly, multiple carbon layers of the graphene-graphite device components were vertically assembled to form a three-dimensional flexible structure which served as a top-gate transistor array. These results represent a substantial progress towards encoding electronic functionality via chemical synthesis and suggest future promise for one-step integration of graphene-graphite based electronics. PMID:22101813

Synthesis of monolithic graphene-graphite integrated electronics.

PubMed

Park, Jang-Ung; Nam, SungWoo; Lee, Mi-Sun; Lieber, Charles M

2011-11-20

Encoding electronic functionality into nanoscale elements during chemical synthesis has been extensively explored over the past decade as the key to developing integrated nanosystems with functions defined by synthesis. Graphene has been recently explored as a two-dimensional nanoscale material, and has demonstrated simple device functions based on conventional top-down fabrication. However, the synthetic approach to encoding electronic functionality and thus enabling an entire integrated graphene electronics in a chemical synthesis had not previously been demonstrated. Here we report an unconventional approach for the synthesis of monolithically integrated electronic devices based on graphene and graphite. Spatial patterning of heterogeneous metal catalysts permits the selective growth of graphene and graphite, with a controlled number of graphene layers. Graphene transistor arrays with graphitic electrodes and interconnects were formed from the synthesis. These functional, all-carbon structures were transferable onto a variety of substrates. The integrated transistor arrays were used to demonstrate real-time, multiplexed chemical sensing and more significantly, multiple carbon layers of the graphene-graphite device components were vertically assembled to form a three-dimensional flexible structure which served as a top-gate transistor array. These results represent substantial progress towards encoding electronic functionality through chemical synthesis and suggest the future promise of one-step integration of graphene-graphite based electronics.

Beyond the classical kinetic model for chronic graphite oxidation by moisture in high temperature gas-cooled reactors

DOE PAGES

Contescu, Cristian I.; Mee, Robert W.; Lee, Yoonjo; ...

2017-11-03

Four grades of nuclear graphite with various microstructures were subjected to accelerated oxidation tests in helium with traces of moisture and hydrogen in order to evaluate the effects of chronic oxidation on graphite components in high temperature gas cooled reactors. Kinetic analysis showed that the Langmuir-Hinshelwood (LH) model cannot consistently reproduce all results. In particular, at high temperatures and water partial pressures oxidation was always faster than the LH model predicts, with stronger deviations for superfine grain graphite than for medium grain grades. It was also found empirically that the apparent reaction order for water has a sigmoid-type variation withmore » temperature which follows the integral Boltzmann distribution function. This suggests that the apparent activation with temperature of graphite reactive sites that causes deviations from the LH model is rooted in specific structural and electronic properties of surface sites on graphite. A semi-global kinetic model was proposed, whereby the classical LH model was modified with a temperature-dependent reaction order for water. The new Boltzmann-enhanced model (BLH) was shown to consistently predict experimental oxidation rates over large ranges of temperature (800-1100 oC) and partial pressures of water (3-1200 Pa) and hydrogen (0-300 Pa), not only for the four grades of graphite but also for the historic grade H-451. The BLH model offers as more reliable input for modeling the chemical environment effects during the life-time operation of new grades of graphite in advanced nuclear reactors operating at high and very high temperatures.« less

Beyond the classical kinetic model for chronic graphite oxidation by moisture in high temperature gas-cooled reactors

DOE Office of Scientific and Technical Information (OSTI.GOV)

Contescu, Cristian I.; Mee, Robert W.; Lee, Yoonjo

Four grades of nuclear graphite with various microstructures were subjected to accelerated oxidation tests in helium with traces of moisture and hydrogen in order to evaluate the effects of chronic oxidation on graphite components in high temperature gas cooled reactors. Kinetic analysis showed that the Langmuir-Hinshelwood (LH) model cannot consistently reproduce all results. In particular, at high temperatures and water partial pressures oxidation was always faster than the LH model predicts, with stronger deviations for superfine grain graphite than for medium grain grades. It was also found empirically that the apparent reaction order for water has a sigmoid-type variation withmore » temperature which follows the integral Boltzmann distribution function. This suggests that the apparent activation with temperature of graphite reactive sites that causes deviations from the LH model is rooted in specific structural and electronic properties of surface sites on graphite. A semi-global kinetic model was proposed, whereby the classical LH model was modified with a temperature-dependent reaction order for water. The new Boltzmann-enhanced model (BLH) was shown to consistently predict experimental oxidation rates over large ranges of temperature (800-1100 oC) and partial pressures of water (3-1200 Pa) and hydrogen (0-300 Pa), not only for the four grades of graphite but also for the historic grade H-451. The BLH model offers as more reliable input for modeling the chemical environment effects during the life-time operation of new grades of graphite in advanced nuclear reactors operating at high and very high temperatures.« less

Modeling of irradiated graphite (14)C transfer through engineered barriers of a generic geological repository in crystalline rocks.

PubMed

Poskas, Povilas; Grigaliuniene, Dalia; Narkuniene, Asta; Kilda, Raimondas; Justinavicius, Darius

2016-11-01

There are two RBMK-1500 type graphite moderated reactors at the Ignalina nuclear power plant in Lithuania, and they are under decommissioning now. The graphite cannot be disposed of in a near surface repository, because of large amounts of (14)C. Therefore, disposal of the graphite in a geological repository is a reasonable solution. This study presents evaluation of the (14)C transfer by the groundwater pathway into the geosphere from the irradiated graphite in a generic geological repository in crystalline rocks and demonstration of the role of the different components of the engineered barrier system by performing local sensitivity analysis. The speciation of the released (14)C into organic and inorganic compounds as well as the most recent information on (14)C source term was taken into account. Two alternatives were considered in the analysis: disposal of graphite in containers with encapsulant and without it. It was evaluated that the maximal fractional flux of inorganic (14)C into the geosphere can vary from 10(-11)y(-1) (for non-encapsulated graphite) to 10(-12)y(-1) (for encapsulated graphite) while of organic (14)C it was about 10(-3)y(-1) of its inventory. Such difference demonstrates that investigations on the (14)C inventory and chemical form in which it is released are especially important. The parameter with the highest influence on the maximal flux into the geosphere for inorganic (14)C transfer was the sorption coefficient in the backfill and for organic (14)C transfer - the backfill hydraulic conductivity. Copyright © 2016 Elsevier B.V. All rights reserved.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Häusler, I., E-mail: ines.haeusler@bam.de; Dörfel, I., E-mail: Ilona.doerfel@bam.de; Peplinski, B., E-mail: Burkhard.peplinski@bam.de

A model system was used to simulate the properties of tribofilms which form during automotive braking. The model system was prepared by ball milling of a blend of 70 vol.% iron oxides, 15 vol.% molybdenum disulfide and 15 vol.% graphite. The resulting mixture was characterized by X-ray powder diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and various transmission electron microscopic (TEM) methods, including energy dispersive X-ray spectroscopy (EDXS), high resolution investigations (HRTEM) with corresponding simulation of the HRTEM images, diffraction methods such as scanning nano-beam electron diffraction (SNBED) and selected area electron diffraction (SAED). It could be shown that the ballmore » milling caused a reduction of the grain size of the initial components to the nanometer range. Sometimes even amorphization or partial break-down of the crystal structure was observed for MoS{sub 2} and graphite. Moreover, chemical reactions lead to a formation of surface coverings of the nanoparticles by amorphous material, molybdenum oxides, and iron sulfates as derived from XPS. - Highlights: • Ball milling of iron oxides, MoS{sub 2}, and graphite to simulate a tribofilm • Increasing coefficient of friction after ball milling of the model blend • Drastically change of the diffraction pattern of the powder mixture • TEM & XPS showed the components of the milled mixture and the process during milling. • MoS{sub 2} and graphite suffered a loss in translation symmetry or became amorphous.« less

Structural Analysis of Pyrolytic Graphite Optics for the HiPEP Ion Thruster

NASA Technical Reports Server (NTRS)

Meckel, Nicole; Polaha, Jonathan; Juhlin, Nils

2006-01-01

The long lifetime requirements of interplanetary exploration missions is driving the need to develop long-life components for the electric propulsion thrusters that are being targeted for these missions. One of the primary life-limiting components of ion thrusters are the optics, which are continuously eroded during the operation of the thruster. Pyrolytic graphite optics are being considered for the High Power Electric Propulsion (HiPEP) ion thruster because of their very high resistance to erosion. This paper describes the structural analysis of the HiPEP pyrolytic graphite. A description of the development of the grid model, as well as the development of the effective properties and stress concentrations in the apertured area of the grids is included. An evaluation of the use of curved grids shows that the increased stiffness (compared to flat grids) prevents intergrid impact during launch, however, the residual stresses introduced by curving the grids pushes the resulting peak stresses beyond the critical stress. As a result, flat grids are recommended as the design solution. Thermally induced grid displacements during normal thruster operation are also presented.

Honeycomb Core Permeability Under Mechanical Loads

NASA Technical Reports Server (NTRS)

Glass, David E.; Raman, V. V.; Venkat, Venki S.; Sankaran, Sankara N.

1997-01-01

A method for characterizing the air permeability of sandwich core materials as a function of applied shear stress was developed. The core material for the test specimens was either Hexcel HRP-3/16-8.0 and or DuPont Korex-1/8-4.5 and was nominally one-half inch thick and six inches square. The facesheets where made of Hercules' AS4/8552 graphite/epoxy (Gr/Ep) composites and were nominally 0.059-in. thick. Cytec's Metalbond 1515-3M epoxy film adhesive was used for co-curing the facesheets to the core. The permeability of the specimens during both static (tension) and dynamic (reversed and non-reversed) shear loads were measured. The permeability was measured as the rate of air flow through the core from a circular 1-in2 area of the core exposed to an air pressure of 10.0 psig. In both the static and dynamic testing, the Korex core experienced sudden increases in core permeability corresponding to a core catastrophic failure, while the URP core experienced a gradual increase in the permeability prior to core failure. The Korex core failed at lower loads than the HRP core both in the transverse and ribbon directions.

Initial Neutronics Analyses for HEU to LEU Fuel Conversion of the Transient Reactor Test Facility (TREAT) at the Idaho National Laboratory

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kontogeorgakos, D.; Derstine, K.; Wright, A.

2013-06-01

The purpose of the TREAT reactor is to generate large transient neutron pulses in test samples without over-heating the core to simulate fuel assembly accident conditions. The power transients in the present HEU core are inherently self-limiting such that the core prevents itself from overheating even in the event of a reactivity insertion accident. The objective of this study was to support the assessment of the feasibility of the TREAT core conversion based on the present reactor performance metrics and the technical specifications of the HEU core. The LEU fuel assembly studied had the same overall design, materials (UO 2more » particles finely dispersed in graphite) and impurities content as the HEU fuel assembly. The Monte Carlo N–Particle code (MCNP) and the point kinetics code TREKIN were used in the analyses.« less

Multidisciplinary Simulation of Graphite-Composite and Cermet Fuel Elements for NTP Point of Departure Designs

NASA Technical Reports Server (NTRS)

Stewart, Mark E.; Schnitzler, Bruce G.

2015-01-01

This paper compares the expected performance of two Nuclear Thermal Propulsion fuel types. High fidelity, fluid/thermal/structural + neutronic simulations help predict the performance of graphite-composite and cermet fuel types from point of departure engine designs from the Nuclear Thermal Propulsion project. Materials and nuclear reactivity issues are reviewed for each fuel type. Thermal/structural simulations predict thermal stresses in the fuel and thermal expansion mis-match stresses in the coatings. Fluid/thermal/structural/neutronic simulations provide predictions for full fuel elements. Although NTP engines will utilize many existing chemical engine components and technologies, nuclear fuel elements are a less developed engine component and introduce design uncertainty. Consequently, these fuel element simulations provide important insights into NTP engine performance.

Investigating the Co-Adsorption Behavior of Nucleic-Acid Base (Thymine and Cytosine) and Melamine at Liquid/Solid Interface

NASA Astrophysics Data System (ADS)

Zhao, Huiling; Li, Yinli; Chen, Dong; Liu, Bo

2016-12-01

The co-adsorption behavior of nucleic-acid base (thymine; cytosine) and melamine was investigated by scanning tunneling microscopy (STM) technique at liquid/solid (1-octanol/graphite) interface. STM characterization results indicate that phase separation happened after dropping the mixed solution of thymine-melamine onto highly oriented pyrolytic graphite (HOPG) surface, while the hetero-component cluster-like structure was observed when cytosine-melamine binary assembly system is used. From the viewpoints of non-covalent interactions calculated by using density functional theory (DFT) method, the formation mechanisms of these assembled structures were explored in detail. This work will supply a methodology to design the supramolecular assembled structures and the hetero-component materials composed by biological and chemical compound.

Design and Optimization of Composite Gyroscope Momentum Wheel Rings

NASA Technical Reports Server (NTRS)

Bednarcyk, Brett A.; Arnold, Steven M.

2007-01-01

Stress analysis and preliminary design/optimization procedures are presented for gyroscope momentum wheel rings composed of metallic, metal matrix composite, and polymer matrix composite materials. The design of these components involves simultaneously minimizing both true part volume and mass, while maximizing angular momentum. The stress analysis results are combined with an anisotropic failure criterion to formulate a new sizing procedure that provides considerable insight into the design of gyroscope momentum wheel ring components. Results compare the performance of two optimized metallic designs, an optimized SiC/Ti composite design, and an optimized graphite/epoxy composite design. The graphite/epoxy design appears to be far superior to the competitors considered unless a much greater premium is placed on volume efficiency compared to mass efficiency.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Aaron, Adam M.; Cunningham, Richard Burns; Fugate, David L.

Effective high-temperature thermal energy exchange and delivery at temperatures over 600°C has the potential of significant impact by reducing both the capital and operating cost of energy conversion and transport systems. It is one of the key technologies necessary for efficient hydrogen production and could potentially enhance efficiencies of high-temperature solar systems. Today, there are no standard commercially available high-performance heat transfer fluids above 600°C. High pressures associated with water and gaseous coolants (such as helium) at elevated temperatures impose limiting design conditions for the materials in most energy systems. Liquid salts offer high-temperature capabilities at low vapor pressures, goodmore » heat transport properties, and reasonable costs and are therefore leading candidate fluids for next-generation energy production. Liquid-fluoride-salt-cooled, graphite-moderated reactors, referred to as Fluoride Salt Reactors (FHRs), are specifically designed to exploit the excellent heat transfer properties of liquid fluoride salts while maximizing their thermal efficiency and minimizing cost. The FHR s outstanding heat transfer properties, combined with its fully passive safety, make this reactor the most technologically desirable nuclear power reactor class for next-generation energy production. Multiple FHR designs are presently being considered. These range from the Pebble Bed Advanced High Temperature Reactor (PB-AHTR) [1] design originally developed by UC-Berkeley to the Small Advanced High-Temperature Reactor (SmAHTR) and the large scale FHR both being developed at ORNL [2]. The value of high-temperature, molten-salt-cooled reactors is also recognized internationally, and Czechoslovakia, France, India, and China all have salt-cooled reactor development under way. The liquid salt experiment presently being developed uses the PB-AHTR as its focus. One core design of the PB-AHTR features multiple 20 cm diameter, 3.2 m long fuel channels with 3 cm diameter graphite-based fuel pebbles slowly circulating up through the core. Molten salt coolant (FLiBe) at 700°C flows concurrently (at significantly higher velocity) with the pebbles and is used to remove heat generated in the reactor core (approximately 1280 W/pebble), and supply it to a power conversion system. Refueling equipment continuously sorts spent fuel pebbles and replaces spent or damaged pebbles with fresh fuel. By combining greater or fewer numbers of pebble channel assemblies, multiple reactor designs with varying power levels can be offered. The PB-AHTR design is discussed in detail in Reference [1] and is shown schematically in Fig. 1. Fig. 1. PB-AHTR concept (drawing taken from Peterson et al., Design and Development of the Modular PB-AHTR Proceedings of ICApp 08). Pebble behavior within the core is a key issue in proving the viability of this concept. This includes understanding the behavior of the pebbles thermally, hydraulically, and mechanically (quantifying pebble wear characteristics, flow channel wear, etc). The experiment being developed is an initial step in characterizing the pebble behavior under realistic PB-AHTR operating conditions. It focuses on thermal and hydraulic behavior of a static pebble bed using a convective salt loop to provide prototypic fluid conditions to the bed, and a unique inductive heating technique to provide prototypic heating in the pebbles. The facility design is sufficiently versatile to allow a variety of other experimentation to be performed in the future. The facility can accommodate testing of scaled reactor components or sub-components such as flow diodes, salt-to-salt heat exchangers, and improved pump designs as well as testing of refueling equipment, high temperature instrumentation, and other reactor core designs.« less

Examining the Possibility of Carbon as a Light Element in the Core of Mercury

NASA Technical Reports Server (NTRS)

Vander Kaaden, Kathleen; McCubbin, Francis M.; Turner, Amber; Ross, D. Kent

2017-01-01

Results from the MErcury Surface, Space ENvironment, GEochemistry and Ranging (MESSENGER) spacecraft have shown elevated abundances of C on the surface of Mercury. Peplowski et al. used GRS data from MESSENGER to show an average northern hemisphere abundance of C on the planet of 0 to 4.1 wt% C at the three-sigma detection limit. Confirmation of C on the planet prompts many questions regarding the role of C during the differentiation and evolution of Mercury. The elevated abundances of both S and C on Mercury's surface, coupled with the low abundances of iron, suggest that the oxygen fugacity of the planet is several log10 units below the Iron-Wustite buffer. These observations spark questions about the bulk composition of Mercury's core. This experimental study seeks to understand the impact of C as a light element on potential mercurian core compositions. In order to address this question, experiments were conducted at 1 GPa and a variety of temperatures (700 - 1500 C) on metal compositions ranging from Si5Fe95 to Si22Fe78, possibly representative of the mercurian core. All starting metals were completely enclosed in a graphite capsule to ensure C saturation at a given set of run conditions. All elements, including C, were analyzed using electron probe microanalysis. Precautions were taken to ensure accurate measurements of C with this technique including using the LDE2 crystal, the cold finger on the microprobe to minimize contamination and increase the vacuum, and an instrument with no oil based pumps. Based on the superliquidus experimental results in the present study, as Fe-rich cores become more Si-rich, the C content of that core composition will decrease. Furthermore, although C concentration at graphite saturation (CCGS) varies from a liquid to a solid, temperature does not seem to play a substantial role in CCGS, at least at 1 GPa.

Production of Metal-Free Composites Composed of Graphite Oxide and Oxidized Carbon Nitride Nanodots and Their Enhanced Photocatalytic Performances.

PubMed

Kim, Seung Yeon; Oh, Junghoon; Park, Sunghee; Shim, Yeonjun; Park, Sungjin

2016-04-04

A novel metal-free composite (GN) composed of two types of carbon-based nanomaterials, graphite oxide (GO) and 2D oxidized carbon nitride (OCN) nanodots was produced. Chemical and morphological characterizations reveal that GN contains a main component of GO with well-dispersed 2D OCN nanodots. GN shows enhanced photocatalytic performance for degrading an organic pollutant, Rhodamine B, under visible light. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Analytical techniques and instrumentation, a compilation

NASA Technical Reports Server (NTRS)

1974-01-01

Procedures for conducting materials tests and structural analyses of aerospace components are presented as a part of the NASA technology utilization program. Some of the subjects discussed are as follows: (1) failures in cryogenic tank insulation, (2) friction characteristics of graphite and graphite-metal combinations, (3) evaluation of polymeric products in thermal-vacuum environment, (4) erosion of metals by multiple impacts with water, (5) mass loading effects on vibrated ring and shell structures, (6) nonlinear damping in structures, and (7) method for estimating reliability of randomly excited structures.

The viscoelastic behavior of the principal compliance matrix of a unidirectional graphite/epoxy composite

NASA Technical Reports Server (NTRS)

Morris, D. H.; Yeow, Y. T.

1979-01-01

The time-temperature response of the principal compliances of a unidirectional graphite/epoxy composite was determined. It is shown that two components of the compliance matrix are time and temperature independent and that the compliance matrix is symmetric for the viscoelastic composite. The time-temperature superposition principle is used to determine shift factors which are independent of fiber orientation, for fiber angles that vary from 10 D to 90 D with respect to the load direction.

Extraterrestrial diamond inclusions reveal a Mars-sized planet

NASA Astrophysics Data System (ADS)

Nabiei, F.; Badro, J.; Dennenwaldt, T.; Oveisi, E.; Cantoni, M.; Hébert, C.; El Goresy, A.; Barrat, J. A.; Gillet, P.

2017-12-01

Ureilites are achondritic meteorites, distinct by their high carbon content. Carbon dominantly exists as graphite and diamond forming veins between olivine and pyroxene grains in the matrix. The presence of diamonds is, often, attributed to the shock-induced transformation from graphite. However, a recent study (Miyahara et al. 2016) on Almahata Sitta MS-170 mainly based on the large size of diamonds suggested their growth in the static high pressure conditions of planetary interior. We prepared five thin sections by the focused ion beam (FIB) from the diamonds in Almahatta Sitta MS-170 for transmission electron microscopy (TEM) analysis. Abundance of dislocations, stacking faults and {111} twinnings indicate significant deformation. Moreover, large numbers of inclusions are found in diamonds. Electron energy-loss spectroscopy (EELS) showed that when a twinning is intersected with an inclusion, it transforms to graphite. This together with other morphological and crystallographical characteristics of the graphite and diamond phases point to the shock-induced transformation of diamond to graphite. Energy dispersive X-ray (EDX) spectroscopy and electron diffraction were used to chemically and structurally characterize the diamond inclusions. Most of the inclusions are Fe-Ni-S-P type up to 60 nm in diameter, each consisting of three phases: kamacite (Fe, Ni), troilite (FeS) and Schreibersite ((Fe,Ni)3P). The inclusions always have euhedral shape indicating the existence of a parent phase that later broke down. Chemical analysis of complete inclusions (identified with electron tomography) agrees with the stoichiometric (Fe0.93,Ni0.07)3(S0.88,P0.12) phase that only forms above 21 GPa (Gu et al. 2016). The ureilite parent body (UPB) needs to be at least about Mars-sized to generate such a pressure at its core-mantle boundary. This is in the same size range estimated for the planetary embryos forming early in the Solar System. Moreover, although the UPB did not go through an extensive magma ocean period, it was partially differentiated through segregation of S-rich core (Warren et al. 2006). The existence of Mg-free chromite (Cr2FeO4) inclusions in diamond and the vein-like arrangement of Fe-S inclusions suggest that the diamonds are formed from Fe-S-C melt at the pressures exceeding 21 GPa inside the UPB.

Research on graphite reinforced glass matrix composites

NASA Technical Reports Server (NTRS)

Prewo, K. M.; Thompson, E. R.

1980-01-01

High levels of mechanical performance in tension, flexure, fatigue, and creep loading situations of graphite fiber reinforced glass matrix composites are discussed. At test temperatures of up to 813 K it was found that the major limiting factor was the oxidative instability of the reinforcing graphite fibers. Particular points to note include the following: (1) a wide variety of graphite fibers were found to be comparable with the glass matrix composite fabrication process; (2) choice of fiber, to a large extent, controlled resultant composite performance; (3) composite fatigue performance was found to be excellent at both 300 K and 703 K; (4) composite creep and stress rupture at temperatures of up to 813 K was limited by the oxidative stability of the fiber; (5) exceptionally low values of composite thermal expansion coefficient were attributable to the dimensional stability of both matrix and fiber; and (6) component fabricability was demonstrated through the hot pressing of hot sections and brazing using glass and metal joining phases.

Bimetallic Metal-Organic Frameworks for Controlled Catalytic Graphitization of Nanoporous Carbons

PubMed Central

Tang, Jing; Salunkhe, Rahul R.; Zhang, Huabin; Malgras, Victor; Ahamad, Tansir; Alshehri, Saad M.; Kobayashi, Naoya; Tominaka, Satoshi; Ide, Yusuke; Kim, Jung Ho; Yamauchi, Yusuke

2016-01-01

Single metal-organic frameworks (MOFs), constructed from the coordination between one-fold metal ions and organic linkers, show limited functionalities when used as precursors for nanoporous carbon materials. Herein, we propose to merge the advantages of zinc and cobalt metals ions into one single MOF crystal (i.e., bimetallic MOFs). The organic linkers that coordinate with cobalt ions tend to yield graphitic carbons after carbonization, unlike those bridging with zinc ions, due to the controlled catalytic graphitization by the cobalt nanoparticles. In this work, we demonstrate a feasible method to achieve nanoporous carbon materials with tailored properties, including specific surface area, pore size distribution, degree of graphitization, and content of heteroatoms. The bimetallic-MOF-derived nanoporous carbon are systematically characterized, highlighting the importance of precisely controlling the properties of the carbon materials. This can be done by finely tuning the components in the bimetallic MOF precursors, and thus designing optimal carbon materials for specific applications. PMID:27471193

ENGINEERING AND CONSTRUCTING THE HALLAM NUCLEAR POWER FACILITY REACTOR STRUCTURE

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mahlmeister, J E; Haberer, W V; Casey, D F

1960-12-15

The Hallam Nuclear Power Facility reactor structure, including the cavity liner, is described, and the design philosophy and special design requirements which were developed during the preliminary and final engineering phases of the project are explained. The structure was designed for 600 deg F inlet and 1000 deg F outlet operating sodium temperatures and fabricated of austenitic and ferritic stainless steels. Support for the reactor core components and adequate containment for biological safeguards were readily provided even though quite conservative design philosophy was used. The calculated operating characteristics, including heat generation, temperature distributions and stress levels for full-power operation, aremore » summarized. Ship fabrication and field installation experiences are also briefly related. Results of this project have established that the sodium graphite reactor permits practical and economical fabrication and field erection procedures; considerably higher operating design temperatures are believed possible without radical design changes. Also, larger reactor structures can be similarly constructed for higher capacity (300 to 1000 Mwe) nuclear power plants. (auth)« less

Lightweight, Rack-Mountable Composite Cold Plate/Shelves

NASA Technical Reports Server (NTRS)

Hurlbert, Kathryn M.; Ruemmele, Warren; Nguyen, Hai D.; Andish, Kambiz; McCalley, Sean

2004-01-01

Rack-mountable composite-material structural components that would serve as both shelves and cold plates for removing heat from electronic or other equipment mounted on the shelves have been proposed as lightweight alternatives to all-metal cold plate/shelves now in use. A proposed cold plate/shelf would include a highly thermally conductive face sheet containing oriented graphite fibers bonded to an aluminum honeycomb core, plus an extruded stainless-steel substructure containing optimized flow passages for a cooling fluid, and an inlet and outlet that could be connected to standard manifold sections. To maximize heat-transfer efficiency, the extruded stainless-steel substructure would be connected directly to the face sheet. On the basis of a tentative design, the proposed composite cold plate/shelf would weigh about 38 percent less than does an all-aluminum cold plate in use or planned for use in some spacecraft and possibly aircraft. Although weight is a primary consideration, the tentative design offers the additional benefit of reduction of thickness to half that of the all-aluminum version.

The Role of Carbon in Core Formation Under Highly Reducing Conditions With Implications for the Planet Mercury

NASA Technical Reports Server (NTRS)

Vander Kaaden, Kathleen E..; McCubbin, Francis M.; Ross, D. Kent; Draper, David S.

2017-01-01

Results from the MErcury Surface, Space ENvironment, GEochemistry and Ranging (MESSENGER) spacecraft have shown elevated abundances of carbon on the surface of Mercury. Furthermore, the X-Ray Spectrometer on board MESSENGER measured elevated abundances of sulfur and low abundances of iron, suggesting the planet's oxygen fugacity (fO2) is several log10 units below the Iron-Wüstite (IW) buffer. Similar to the role of other volatiles (e.g. sulfur) on highly reducing planetary bodies, carbon is expected to behave differently than it would under higher fO2. As discussed by Nittler et al. and Hauck et al., under such highly reducing conditions, the majority of the iron partitions into the core. On Mercury, this resulted in a relatively large core and a thin mantle. Using a composition similar to the largest volcanic field on the planet (the northern volcanic plains), Vander Kaaden and McCubbin conducted sink-float experiments to determine the density of melts and minerals on Mercury. They showed that graphite would be the only buoyant mineral in a mercurian magma ocean. Therefore, Vander Kaaden and McCubbin proposed a possible primary flotation crust on the planet composed of graphite. Concurrently, Peplowski et al. used GRS data from MESSENGER to show an average northern hemisphere abundance of C on the planet of 1.4 +/- 0.9 wt%. However, as this result was only at the one-sigma detection limit, possible carbon abundances at the three-sigma detection limit for Mercury range from 0 to 4.1 wt% carbon. Additionally, Murchie et al. investigated the possible darkening agent on Mercury and concluded that coarse-grained graphite could darken high reflectance plains to the low reflectance material. To further test the possibility of elevated abundances of carbon in Mercury's crust, Peplowski et al. used the low-altitude MESSENGER data to show that carbon is the only material consistent with both the visible to near-infrared spectra and the neutron measurements of low reflectance material on Mercury, confirming that C is the primary darkening agent on Mercury. Confirmation of carbon on the planet prompts many questions regarding the role of carbon during the differentiation and evolution of Mercury. Given the elevated abundances of both S and C on Mercury's surface, it begs the question, what is the core composition of the planet? This study seeks to understand the impact of C as a light element on potential core compositions on Mercury.

Stoichiometry effect on the irradiation response in the microstructure of zirconium carbides

DOE Office of Scientific and Technical Information (OSTI.GOV)

Young Yang; Wei-Yang Lo; Clayton Dickerson

2014-11-01

Zone-refined ultra high pure ZrC with five C/Zr ratios ranging from 0.84 to 1.17 was irradiated using a 2 MeV proton beam at 1125 C. The stoichiometry effect on the irradiation response of ZrC microstructure was examined using transmission electron microscopy following the irradiation. The irradiated microstructures generally feature a high density of perfect dislocation loops particularly at away from the graphite precipitates, and the C/Zr ratio shows a notable effect on the size and density of dislocation loops. The dislocation loops are identified as interstitial type perfect loops, and it was indirectly proved that the dislocation loop core likelymore » consists of carbon atoms. Graphite precipitates that form with excess carbon in the super-stoichiometric ZrC are detrimental, and the dramatic increases in the size of and density of dislocation loops in the vicinity of graphite precipitates in ZrC phase were observed. Irradiationinduced faceted voids were only observed in ZrC0.95, which is attributed to the pre-existing dislocation lines as biased sinks for vacancies.« less

Evolution of the secondary electron emission during the graphitization of thin C films

NASA Astrophysics Data System (ADS)

Larciprete, Rosanna; Grosso, Davide Remo; Di Trolio, Antonio; Cimino, Roberto

2015-02-01

The relation between the atomic hybridization and the secondary electron emission yield (SEY) in carbon materials has been investigated during the thermal graphitization of thin amorphous carbon layers deposited by magnetron sputtering on Cu substrates. C1s core level, valence band and Raman spectroscopy were used to follow the sp3→sp2 structural reorganization while the SEY curves as a function of the kinetic energy of the incident electron beam were measured in parallel. We found that an amorphous C layer with a thickness of a few tens of nanometers is capable to modify the secondary emission properties of the clean copper surface, reducing the maximum yield from 1.4 to 1.2. A further SEY decrease observed with the progressive conversion of sp3 hybrids into six-fold aromatic domains was related to the electronic structure close to the Fermi level of the C-films. We found that a moderate structural quality of the C layer is sufficient to notably decrease the SEY as aromatic clusters of limited size approach the secondary emission properties of graphite.

Multi-Scale Modeling of a Graphite-Epoxy-Nanotube System

NASA Technical Reports Server (NTRS)

Frankland, S. J. V.; Riddick, J. C.; Gates, T. S.

2005-01-01

A multi-scale method is utilized to determine some of the constitutive properties of a three component graphite-epoxy-nanotube system. This system is of interest because carbon nanotubes have been proposed as stiffening and toughening agents in the interlaminar regions of carbon fiber/epoxy laminates. The multi-scale method uses molecular dynamics simulation and equivalent-continuum modeling to compute three of the elastic constants of the graphite-epoxy-nanotube system: C11, C22, and C33. The 1-direction is along the nanotube axis, and the graphene sheets lie in the 1-2 plane. It was found that the C11 is only 4% larger than the C22. The nanotube therefore does have a small, but positive effect on the constitutive properties in the interlaminar region.

Diffusivity and solubility of hydrogen in the carbon fibre composite SEP N11

DOE Office of Scientific and Technical Information (OSTI.GOV)

Alberici, S.; Perujo, A.; Camposilvan, J.

1995-10-01

In this paper we present the hydrogen diffusivity and solubility in the carbon fibre composite (CFC) SEP N11 with tri-directional fibres structure that is a possible candidate as armour material for plasma facing components (PFC). The technique used for these measurements is a gas evolution method and the measurements were carried out in the temperature range 900 - 1200 K with a loading hydrogen pressure of 100 kPa. The results obtained showed that the Sieverts` constant K{sub s} is of the same order of magnitude as those previously obtained for several graphites, while the diffusivity is about five to sixmore » orders of magnitude higher as compared to graphites. Furthermore, CFC presents an endothermic behaviour in contrast to graphites. 10 refs., 3 figs.« less

Baseline Concept Description of a Small Modular High Temperature Reactor

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hans Gougar

2014-05-01

The objective of this report is to provide a description of generic small modular high temperature reactors (herein denoted as an smHTR), summarize their distinguishing attributes, and lay out the research and development (R&D) required for commercialization. The generic concepts rely heavily on the modular high temperature gas-cooled reactor designs developed in the 1980s which were never built but for which pre-licensing or certification activities were conducted. The concept matured more recently under the Next Generation Nuclear Plant (NGNP) project, specifically in the areas of fuel and material qualification, methods development, and licensing. As all vendor-specific designs proposed under NGNPmore » were all both ‘small’ or medium-sized and ‘modular’ by International Atomic Energy Agency (IAEA) and Department of Energy (DOE) standards, the technical attributes, challenges, and R&D needs identified, addressed, and documented under NGNP are valid and appropriate in the context of Small Modular Reactor (SMR) applications. Although the term High Temperature Reactor (HTR) is commonly used to denote graphite-moderated, thermal spectrum reactors with coolant temperatures in excess of 650oC at the core outlet, in this report the historical term High Temperature Gas-Cooled Reactor (HTGR) will be used to distinguish the gas-cooled technology described herein from its liquid salt-cooled cousin. Moreover, in this report it is to be understood that the outlet temperature of the helium in an HTGR has an upper limit of 950 degrees C which corresponds to the temperature to which certain alloys are currently being qualified under DOE’s ARC program. Although similar to the HTGR in just about every respect, the Very High Temperature Reactor (VHTR) may have an outlet temperature in excess of 950 degrees C and is therefore farther from commercialization because of the challenges posed to materials exposed to these temperatures. The VHTR is the focus of R&D under the Generation IV program and its specific R&D needs will be included in this report when appropriate for comparison. The distinguishing features of the HTGR are the refractory (TRISO) coated particle fuel, the low-power density, graphite-moderated core, and the high outlet temperature of the inert helium coolant. The low power density and fuel form effectively eliminate the possibility of core melt, even upon a complete loss of coolant pressure and flow. The graphite, which constitutes the bulk of the core volume and mass, provides a large thermal buffer that absorbs fission heat such that thermal transients occur over a timespan of hours or even days. As chemically-inert helium is already a gas, there is no coolant temperature or void feedback on the neutronics and no phase change or corrosion product that could degrade heat transfer. Furthermore, the particle coatings and interstitial graphite retain fission products such that the source terms at the plant boundary remain well below actionable levels under all anticipated nominal and off-normal operating conditions. These attributes enable the reactor to supply process heat to a collocated industrial plant with negligible risk of contamination and minimal dynamic coupling of the facilities (Figure 1). The exceptional retentive properties of coated particle fuel in a graphite matrix were first demonstrated in the DRAGON reactor, a European research facility that began operation in 1964.« less

Baseline Concept Description of a Small Modular High Temperature Reactor

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gougar, Hans D.

2014-10-01

The objective of this report is to provide a description of generic small modular high temperature reactors (herein denoted as an smHTR), summarize their distinguishing attributes, and lay out the research and development (R&D) required for commercialization. The generic concepts rely heavily on the modular high temperature gas-cooled reactor designs developed in the 1980s which were never built but for which pre-licensing or certification activities were conducted. The concept matured more recently under the Next Generation Nuclear Plant (NGNP) project, specifically in the areas of fuel and material qualification, methods development, and licensing. As all vendor-specific designs proposed under NGNPmore » were all both ‘small’ or medium-sized and ‘modular’ by International Atomic Energy Agency (IAEA) and Department of Energy (DOE) standards, the technical attributes, challenges, and R&D needs identified, addressed, and documented under NGNP are valid and appropriate in the context of Small Modular Reactor (SMR) applications. Although the term High Temperature Reactor (HTR) is commonly used to denote graphite-moderated, thermal spectrum reactors with coolant temperatures in excess of 650oC at the core outlet, in this report the historical term High Temperature Gas-Cooled Reactor (HTGR) will be used to distinguish the gas-cooled technology described herein from its liquid salt-cooled cousin. Moreover, in this report it is to be understood that the outlet temperature of the helium in an HTGR has an upper limit of 950 degrees C which corresponds to the temperature to which certain alloys are currently being qualified under DOE’s ARC program. Although similar to the HTGR in just about every respect, the Very High Temperature Reactor (VHTR) may have an outlet temperature in excess of 950 degrees C and is therefore farther from commercialization because of the challenges posed to materials exposed to these temperatures. The VHTR is the focus of R&D under the Generation IV program and its specific R&D needs will be included in this report when appropriate for comparison. The distinguishing features of the HTGR are the refractory (TRISO) coated particle fuel, the low-power density, graphite-moderated core, and the high outlet temperature of the inert helium coolant. The low power density and fuel form effectively eliminate the possibility of core melt, even upon a complete loss of coolant pressure and flow. The graphite, which constitutes the bulk of the core volume and mass, provides a large thermal buffer that absorbs fission heat such that thermal transients occur over a timespan of hours or even days. As chemically-inert helium is already a gas, there is no coolant temperature or void feedback on the neutronics and no phase change or corrosion product that could degrade heat transfer. Furthermore, the particle coatings and interstitial graphite retain fission products such that the source terms at the plant boundary remain well below actionable levels under all anticipated nominal and off-normal operating conditions. These attributes enable the reactor to supply process heat to a collocated industrial plant with negligible risk of contamination and minimal dynamic coupling of the facilities (Figure 1). The exceptional retentive properties of coated particle fuel in a graphite matrix were first demonstrated in the DRAGON reactor, a European research facility that began operation in 1964.« less

Encapsulation of α-Fe2O3 nanoparticles in graphitic carbon microspheres as high-performance anode materials for lithium-ion batteries

NASA Astrophysics Data System (ADS)

Zhang, Hongwei; Sun, Xiaoran; Huang, Xiaodan; Zhou, Liang

2015-02-01

A novel ``spray drying-carbonization-oxidation'' strategy has been developed for the fabrication of α-Fe2O3-graphitic carbon (α-Fe2O3@GC) composite microspheres, in which α-Fe2O3 nanoparticles with sizes of 30-50 nm are well-encapsulated by onion-like graphitic carbon shells with a thickness of 5-10 nm. In the constructed composite, the α-Fe2O3 nanoparticles act as the primary active material, providing a high capacity. Meanwhile, the graphitic carbon shells serve as the secondary active component, structural stabilizer, interfacial stabilizer, and electron-highway. As a result, the synthesized α-Fe2O3@GC nanocomposite exhibits a superior lithium-ion battery performance with a high reversible capacity (898 mA h g-1 at 400 mA g-1), outstanding rate capability, and excellent cycling stability. Our product, in terms of the facile and scalable preparation process and excellent electrochemical performance, demonstrates its great potential as a high-performance anode material for lithium-ion batteries.A novel ``spray drying-carbonization-oxidation'' strategy has been developed for the fabrication of α-Fe2O3-graphitic carbon (α-Fe2O3@GC) composite microspheres, in which α-Fe2O3 nanoparticles with sizes of 30-50 nm are well-encapsulated by onion-like graphitic carbon shells with a thickness of 5-10 nm. In the constructed composite, the α-Fe2O3 nanoparticles act as the primary active material, providing a high capacity. Meanwhile, the graphitic carbon shells serve as the secondary active component, structural stabilizer, interfacial stabilizer, and electron-highway. As a result, the synthesized α-Fe2O3@GC nanocomposite exhibits a superior lithium-ion battery performance with a high reversible capacity (898 mA h g-1 at 400 mA g-1), outstanding rate capability, and excellent cycling stability. Our product, in terms of the facile and scalable preparation process and excellent electrochemical performance, demonstrates its great potential as a high-performance anode material for lithium-ion batteries. Electronic supplementary information (ESI) available: XRD pattern, XPS spectrum, CV curves, TEM and SEM images, and table. See DOI: 10.1039/c4nr06771a

Light weight fire resistant graphite composites

NASA Technical Reports Server (NTRS)

Kourtides, D. A.; Parker, J. A.; Hsu, M. T. S.

1986-01-01

Composite structures with a honeycomb core and characterized by lightweight and excellent fire resistance are provided. These sandwich structures employ facesheets made up of bismaleimide-vinyl styrylpyridine copolymers with fiber reinforcement such as carbon fiber reinforcement. In preferred embodiments the facesheets are over layered with a decorative film. The properties of these composites make them attractive materials of construction aircraft and spacecraft.

Nuclear design analysis of square-lattice honeycomb space nuclear rocket engine

NASA Astrophysics Data System (ADS)

Widargo, Reza; Anghaie, Samim

1999-01-01

The square-lattice honeycomb reactor is designed based on a cylindrical core that is determined to have critical diameter and length of 0.50 m and 0.50 c, respectively. A 0.10-cm thick radial graphite reflector, in addition to a 0.20-m thick axial graphite reflector are used to reduce neutron leakage from the reactor. The core is fueled with solid solution of 93% enriched (U, Zr, Nb)C, which is one of several ternary uranium carbides that are considered for this concept. The fuel is to be fabricated as 2 mm grooved (U, Zr, Nb)C wafers. The fuel wafers are used to form square-lattice honeycomb fuel assemblies, 0.10 m in length with 30% cross-sectional flow area. Five fuel assemblies are stacked up axially to form the reactor core. Based on the 30% void fraction, the width of the square flow channel is about 1.3 mm. The hydrogen propellant is passed through these flow channels and removes the heat from the reactor core. To perform nuclear design analysis, a series of neutron transport and diffusion codes are used. The preliminary results are obtained using a simple four-group cross-section model. To optimize the nuclear design, the fuel densities are varied for each assembly. Tantalum, hafnium and tungsten are considered and used as a replacement for niobium in fuel material to provide water submersion sub-criticality for the reactor. Axial and radial neutron flux and power density distributions are calculated for the core. Results of the neutronic analysis indicate that the core has a relatively fast spectrum. From the results of the thermal hydraulic analyses, eight axial temperature zones are chosen for the calculation of group average cross-sections. An iterative process is conducted to couple the neutronic calculations with the thermal hydraulics calculations. Results of the nuclear design analysis indicate that a compact core can be designed based on ternary uranium carbide square-lattice honeycomb fuel. This design provides a relatively high thrust to weight ratio.

Experimental investigation of graphite/polyimide sandwich panels in edgewise compression

NASA Technical Reports Server (NTRS)

Camarda, C. J.

1980-01-01

The local and general buckling behavior of graphite/polyimide sandwich panels simply supported along all four edges and loaded in uniaxial edgewise compression was investigated. Material properties of adhesive and facings were determined from flatwise tension and sandwich beam flexure tests. Tensile and compressive material properties of the facings were determined at 116, R.T., and 589 K (-250, R.T., and 600 F) using the sandwich beam flexure test method. Results indicate that Gr/PI is a usable structural material for short term use at temperatures as high as 589 K (600 F). Buckling specimens were 30.5 X 33.0 cm (12 x 13 in.), had quasi-isotropic symmetric facings and a glass/polyimide honeycomb core. Core thicknesses varied and three panels of each thickness were tested in edgewise compression at room temperature to investigate failure modes and corresponding buckling formulas. Specimens 0.635 cm (0.25 in.) thick failed by overall buckling at loads close to the analytically predicted buckling load; all other panels failed by face wrinkling. Results of the winkling tests indicate that several buckling formulas were unconservative and therefore not suitable for design purposes; recommended wrinkling equations are presented.

Investigation on the Core Bypass Flow in a Very High Temperature Reactor

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hassan, Yassin

2013-10-22

Uncertainties associated with the core bypass flow are some of the key issues that directly influence the coolant mass flow distribution and magnitude, and thus the operational core temperature profiles, in the very high-temperature reactor (VHTR). Designers will attempt to configure the core geometry so the core cooling flow rate magnitude and distribution conform to the design values. The objective of this project is to study the bypass flow both experimentally and computationally. Researchers will develop experimental data using state-of-the-art particle image velocimetry in a small test facility. The team will attempt to obtain full field temperature distribution using racksmore » of thermocouples. The experimental data are intended to benchmark computational fluid dynamics (CFD) codes by providing detailed information. These experimental data are urgently needed for validation of the CFD codes. The following are the project tasks: • Construct a small-scale bench-top experiment to resemble the bypass flow between the graphite blocks, varying parameters to address their impact on bypass flow. Wall roughness of the graphite block walls, spacing between the blocks, and temperature of the blocks are some of the parameters to be tested. • Perform CFD to evaluate pre- and post-test calculations and turbulence models, including sensitivity studies to achieve high accuracy. • Develop the state-of-the art large eddy simulation (LES) using appropriate subgrid modeling. • Develop models to be used in systems thermal hydraulics codes to account and estimate the bypass flows. These computer programs include, among others, RELAP3D, MELCOR, GAMMA, and GAS-NET. Actual core bypass flow rate may vary considerably from the design value. Although the uncertainty of the bypass flow rate is not known, some sources have stated that the bypass flow rates in the Fort St. Vrain reactor were between 8 and 25 percent of the total reactor mass flow rate. If bypass flow rates are on the high side, the quantity of cooling flow through the core may be considerably less than the nominal design value, causing some regions of the core to operate at temperatures in excess of the design values. These effects are postulated to lead to localized hot regions in the core that must be considered when evaluating the VHTR operational and accident scenarios.« less

New constant-temperature operating mode for graphite calorimeter at LNE-LNHB.

PubMed

Daures, J; Ostrowsky, A

2005-09-07

The realization of the unit of absorbed dose at LNE-LNHB is based on calorimetry with the present GR8 graphite calorimeter. For this reason the calorimetric technique must be maintained, developed and improved in the laboratory. The usual quasi-adiabatic operating mode at LNHB is based on the thermal feedback between the core (sensitive element) and the jacket (adjacent body). When a core-jacket temperature difference is detected, a commercially available analogue PID (Proportional, Integral, Derivative) controller sends to the jacket an amount of electrical power to reduce this difference. Nevertheless, the core and jacket temperatures increase with irradiations and electrical calibrations whereas the surrounding is maintained at a fixed temperature to shield against the room temperature variations. At radiotherapy dose rates, fewer than ten measurements, or electrical calibrations, per day can be performed. This paper describes the new constant-temperature operating mode which has been implemented recently to improve flexibility in use and, to some extent, accuracy. The core and the jacket temperatures are maintained at fixed temperatures. A steady state is achieved without irradiation. Then, under irradiation, the electrical power needed to maintain the assigned temperature in the core is reduced by the amount of heat generated by ionizing radiation. The difference between these electrical powers, without and with irradiation, gives the mean absorbed dose rate to the core. The quality of this electrical power substitution measurement is strongly dependent upon the quality of the core and jacket thermal control. The core temperature is maintained at the set value using a digital PID regulator developed at the laboratory with LabView software on PC for this purpose. This regulator is versatile and particularly well suited for calorimetry purposes. Measurements in a cobalt-60 beam have shown no significant difference (<0.09%) between the two operating modes, with an equivalent reproducibility (1sigma < 0.06%). These results corroborate the negligible difference of heat transfer between steady and irradiation periods when working in quasi-adiabatic mode with thermal feedback between the core and the jacket. The new constant-temperature mode allows numerous and fully automated measurements. The electrical calibration is an integral part of the measurement; no extra runs are needed. It also allows faster thermal equilibrium before starting runs. Moreover the quality of vacuum within the gaps between the bodies is less important.

Fabrication and Testing of Carbon Fiber, Graphite-Epoxy Panels for Submillimeter Telescope Use

NASA Astrophysics Data System (ADS)

Rieger, H.; Helwig, G.; Parks, R. E.; Ulich, B. L.

1983-12-01

An experimental carbon-fiber, graphite-epoxy, aluminum Flexcore sandwich panel roughly 1-m square was made by Dornier System, Friedrichshafen, West Germany. The panel was a pre-prototype of the panels to be used in the dish of the 10-m diameter Sub-Millimeter Telescope, a joint project of the Max-Planck-Institute fur Radioastronomie, Bonn, West Germany, and Steward Observatory, the University of Arizona in Tucson. This paper outlines the fabrication process for the panel and indicates the surface accuracy of the panel replication process. To predict the behavior of the panel under various environmental loads, the panel was modeled structurally using anisotropic elements for the core material. Results of this analysis along with experimental verification of these predictions are also given.

Neutron Reference Benchmark Field Specifications: ACRR Polyethylene-Lead-Graphite (PLG) Bucket Environment (ACRR-PLG-CC-32-CL).

DOE Office of Scientific and Technical Information (OSTI.GOV)

Vega, Richard Manuel; Parm, Edward J.; Griffin, Patrick J.

2015-07-01

This report was put together to support the International Atomic Energy Agency (IAEA) REAL- 2016 activity to validate the dosimetry community’s ability to use a consistent set of activation data and to derive consistent spectral characterizations. The report captures details of integral measurements taken in the Annular Core Research Reactor (ACRR) central cavity with the Polyethylene-Lead-Graphite (PLG) bucket, reference neutron benchmark field. The field is described and an “a priori” calculated neutron spectrum is reported, based on MCNP6 calculations, and a subject matter expert (SME) based covariance matrix is given for this “a priori” spectrum. The results of 37 integralmore » dosimetry measurements in the neutron field are reported.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Loyalka, Sudarshan

High and Very High Temperatures Gas Reactors (HTGRs/VHTRs) have five barriers to fission product (FP) release: the TRISO fuel coating, the fuel elements, the core graphite, the primary coolant system, and the reactor building. This project focused on measurements and computations of FP diffusion in graphite, FP adsorption on graphite and FP interactions with dust particles of arbitrary shape. Diffusion Coefficients of Cs and Iodine in two nuclear graphite were obtained by the release method and use of Inductively Coupled Plasma-Mass Spectroscopy (ICP-MS) and Instrumented Neutron Activation Analysis (INAA). A new mathematical model for fission gas release from nuclear fuelmore » was also developed. Several techniques were explored to measure adsorption isotherms, notably a Knudsen Effusion Mass Spectrometer (KEMS) and Instrumented Neutron Activation Analysis (INAA). Some of these measurements are still in progress. The results will be reported in a supplemental report later. Studies of FP interactions with dust and shape factors for both chain-like particles and agglomerates over a wide size range were obtained through solutions of the diffusion and transport equations. The Green's Function Method for diffusion and Monte Carlo technique for transport were used, and it was found that the shape factors are sensitive to the particle arrangements, and that diffusion and transport of FPs can be hindered. Several journal articles relating to the above work have been published, and more are in submission and preparation.« less

PhybalSIT — Fatigue Assessment and Life Time Calculation of the Ductile Cast Iron EN-GJS-600 at Ambient and Elevated Temperatures

NASA Astrophysics Data System (ADS)

Jost, Benjamin; Klein, Marcus; Eifler, Dietmar

This paper focuses on the ductile cast iron EN-GJS-600 which is often used for components of combustion engines. Under service conditions, those components are mechanically loaded at different temperatures. Therefore, this investigation targets at the fatigue behavior of EN-GJS-600 at ambient and elevated temperatures. Light and scanning electron microscopic investigations were done to characterize the sphericity of the graphite as well as the ferrite, pearlite and graphite fraction. At elevated temperatures, the consideration of dynamic strain ageing effects is of major importance. In total strain increase, temperature increase and constant total strain amplitude tests, the plastic strain amplitude, the stress amplitude, the change in temperature and the change in electrical resistance were measured. The measured values depend on plastic deformation processes in the bulk of the specimens and at the interfaces between matrix and graphite. The fatigue behavior of EN-GJS-600 is dominated by cyclic hardening processes. The physically based fatigue life calculation "PHYBALSIT" (SIT = strain increase test) was developed for total strain controlled fatigue tests. Only one temperature increase test is necessary to determine the temperature interval of pronounced dynamic strain ageing effects.

Carbon Solubility in Metallic Iron and Melting Relations in the Fe-C System at High Pressure and Temperature

NASA Astrophysics Data System (ADS)

Wang, Y.; Fei, Y.

2006-05-01

Carbon has been proposed to be one of the light elements in the Earth's core. Knowledge of phase relations in the Fe-C system at high pressure and temperature is needed to understand the carbon content in the core and its effect on the physical properties and the temperature of the core. Experimental data in this system at high pressure and temperature are limited. In this study we report new experimental data on melting relations up to 25 GPa. The experiments were performed using piston-cylinder and multi-anvil devices at the Geophysical Laboratory. Mixtures of fine power of pure iron and graphite with different carbon content were prepared as starting materials. The starting materials were loaded into MgO capsules and then compressed to the desired pressures, using various high-pressure cell assemblies that have been calibrated at high pressure. High temperatures were achieved using either graphite heater (<6 GPa) or rhenium heater at higher pressures and measured with a tungsten-rhenium thermocouple. Melting relations were determined with a JEOL JXA-8900 electron microprobe, based on quench textures and chemical composition of the quenched phases. Powder X- ray diffraction technique was also used to identify phases and determine unit cell parameters. A positive slope between the solubility of carbon in metallic iron and pressure was found at elevated temperatures. The eutectic temperature increases with increasing pressure. The liquidus temperature determined in this study is significantly lower than the calculated value in previous study. Our study presents directly experimental measurements of the melting relations in the Fe-C system at high pressure and temperature, which provides better constraints on composition and temperature of the Earth's core.

HTR-PROTEUS pebble bed experimental program cores 9 & 10: columnar hexagonal point-on-point packing with a 1:1 moderator-to-fuel pebble ratio

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bess, John D.

2014-03-01

PROTEUS is a zero-power research reactor based on a cylindrical graphite annulus with a central cylindrical cavity. The graphite annulus remains basically the same for all experimental programs, but the contents of the central cavity are changed according to the type of reactor being investigated. Through most of its service history, PROTEUS has represented light-water reactors, but from 1992 to 1996 PROTEUS was configured as a pebble-bed reactor (PBR) critical facility and designated as HTR-PROTEUS. The nomenclature was used to indicate that this series consisted of High Temperature Reactor experiments performed in the PROTEUS assembly. During this period, seventeen criticalmore » configurations were assembled and various reactor physics experiments were conducted. These experiments included measurements of criticality, differential and integral control rod and safety rod worths, kinetics, reaction rates, water ingress effects, and small sample reactivity effects (Ref. 3). HTR-PROTEUS was constructed, and the experimental program was conducted, for the purpose of providing experimental benchmark data for assessment of reactor physics computer codes. Considerable effort was devoted to benchmark calculations as a part of the HTR-PROTEUS program. References 1 and 2 provide detailed data for use in constructing models for codes to be assessed. Reference 3 is a comprehensive summary of the HTR-PROTEUS experiments and the associated benchmark program. This document draws freely from these references. Only Cores 9 and 10 are evaluated in this benchmark report due to similarities in their construction. The other core configurations of the HTR-PROTEUS program are evaluated in their respective reports as outlined in Section 1.0. Cores 9 and 10 were evaluated and determined to be acceptable benchmark experiments.« less

HTR-PROTEUS PEBBLE BED EXPERIMENTAL PROGRAM CORES 5, 6, 7, & 8: COLUMNAR HEXAGONAL POINT-ON-POINT PACKING WITH A 1:2 MODERATOR-TO-FUEL PEBBLE RATIO

DOE Office of Scientific and Technical Information (OSTI.GOV)

John D. Bess

2013-03-01

PROTEUS is a zero-power research reactor based on a cylindrical graphite annulus with a central cylindrical cavity. The graphite annulus remains basically the same for all experimental programs, but the contents of the central cavity are changed according to the type of reactor being investigated. Through most of its service history, PROTEUS has represented light-water reactors, but from 1992 to 1996 PROTEUS was configured as a pebble-bed reactor (PBR) critical facility and designated as HTR-PROTEUS. The nomenclature was used to indicate that this series consisted of High Temperature Reactor experiments performed in the PROTEUS assembly. During this period, seventeen criticalmore » configurations were assembled and various reactor physics experiments were conducted. These experiments included measurements of criticality, differential and integral control rod and safety rod worths, kinetics, reaction rates, water ingress effects, and small sample reactivity effects (Ref. 3). HTR-PROTEUS was constructed, and the experimental program was conducted, for the purpose of providing experimental benchmark data for assessment of reactor physics computer codes. Considerable effort was devoted to benchmark calculations as a part of the HTR-PROTEUS program. References 1 and 2 provide detailed data for use in constructing models for codes to be assessed. Reference 3 is a comprehensive summary of the HTR-PROTEUS experiments and the associated benchmark program. This document draws freely from these references. Only Cores 9 and 10 are evaluated in this benchmark report due to similarities in their construction. The other core configurations of the HTR-PROTEUS program are evaluated in their respective reports as outlined in Section 1.0. Cores 9 and 10 were evaluated and determined to be acceptable benchmark experiments.« less

HTR-PROTEUS PEBBLE BED EXPERIMENTAL PROGRAM CORES 9 & 10: COLUMNAR HEXAGONAL POINT-ON-POINT PACKING WITH A 1:1 MODERATOR-TO-FUEL PEBBLE RATIO

DOE Office of Scientific and Technical Information (OSTI.GOV)

John D. Bess

2013-03-01

PROTEUS is a zero-power research reactor based on a cylindrical graphite annulus with a central cylindrical cavity. The graphite annulus remains basically the same for all experimental programs, but the contents of the central cavity are changed according to the type of reactor being investigated. Through most of its service history, PROTEUS has represented light-water reactors, but from 1992 to 1996 PROTEUS was configured as a pebble-bed reactor (PBR) critical facility and designated as HTR-PROTEUS. The nomenclature was used to indicate that this series consisted of High Temperature Reactor experiments performed in the PROTEUS assembly. During this period, seventeen criticalmore » configurations were assembled and various reactor physics experiments were conducted. These experiments included measurements of criticality, differential and integral control rod and safety rod worths, kinetics, reaction rates, water ingress effects, and small sample reactivity effects (Ref. 3). HTR-PROTEUS was constructed, and the experimental program was conducted, for the purpose of providing experimental benchmark data for assessment of reactor physics computer codes. Considerable effort was devoted to benchmark calculations as a part of the HTR-PROTEUS program. References 1 and 2 provide detailed data for use in constructing models for codes to be assessed. Reference 3 is a comprehensive summary of the HTR-PROTEUS experiments and the associated benchmark program. This document draws freely from these references. Only Cores 9 and 10 are evaluated in this benchmark report due to similarities in their construction. The other core configurations of the HTR-PROTEUS program are evaluated in their respective reports as outlined in Section 1.0. Cores 9 and 10 were evaluated and determined to be acceptable benchmark experiments.« less

Reproducibility of structural strength and stiffness for graphite-epoxy aircraft spoilers

NASA Technical Reports Server (NTRS)

Howell, W. E.; Reese, C. D.

1978-01-01

Structural strength reproducibility of graphite epoxy composite spoilers for the Boeing 737 aircraft was evaluated by statically loading fifteen spoilers to failure at conditions simulating aerodynamic loads. Spoiler strength and stiffness data were statistically modeled using a two parameter Weibull distribution function. Shape parameter values calculated for the composite spoiler strength and stiffness were within the range of corresponding shape parameter values calculated for material property data of composite laminates. This agreement showed that reproducibility of full scale component structural properties was within the reproducibility range of data from material property tests.

Development and demonstration of manufacturing processes for fabricating graphite/Larc-160 polyimide structural elements, part 4, paragraph B

NASA Technical Reports Server (NTRS)

1981-01-01

Progress in the development of processes for production of Celion/LARC-160 graphite-polyimide materials, quality control, and the fabrication of Space Shuttle composite structure components is reported. Liquid chromatographic analyses of three repeatibility batches were performed and are compared to previous Hexcel standard production and to variables study LARC-160 intermediate resins. Development of processes for chopped fiber molding are described and flexural strength, elastic modulus, and other physical and mechanical properties of the molding are presented.

Microscopic insight into the bilateral formation of carbon spirals from a symmetric iron core

PubMed Central

Shiozawa, Hidetsugu; Bachmatiuk, Alicja; Stangl, Andreas; Cox, David C.; Silva, S. Ravi P.; Rümmeli, Mark H.; Pichler, Thomas

2013-01-01

Mirrored carbon-spirals have been produced from pressured ferrocene via the bilateral extrusion of the spiral pairs from an iron core. A parametric plot of the surface geometry displays the fractal growth of the conical helix made with the logarithmic spiral. Electron microscopy studies show the core is a crystalline cementite which grows and transforms its shape from spherical to biconical as it extrudes two spiralling carbon arms. In a cross section along the arms we observe graphitic flakes arranged in a herringbone structure, normal to which defects propagate. Local-wave-pattern analysis reveals nanoscale defect patterns of two-fold symmetry around the core. The data suggest that the bilateral growth originates from a globular cementite crystal with molten surfaces and the nano-defects shape emerging hexagonal carbon into a fractal structure. Understanding and knowledge obtained provide a basis for the controlled production of advanced carbon materials with designed geometries. PMID:23670649

A review on management of spent lithium ion batteries and strategy for resource recycling of all components from them.

PubMed

Zhang, Wenxuan; Xu, Chengjian; He, Wenzhi; Li, Guangming; Huang, Juwen

2018-02-01

The wide use of lithium ion batteries (LIBs) has brought great numbers of discarded LIBs, which has become a common problem facing the world. In view of the deleterious effects of spent LIBs on the environment and the contained valuable materials that can be reused, much effort in many countries has been made to manage waste LIBs, and many technologies have been developed to recycle waste LIBs and eliminate environmental risks. As a review article, this paper introduces the situation of waste LIB management in some developed countries and in China, and reviews separation technologies of electrode components and refining technologies of LiCoO 2 and graphite. Based on the analysis of these recycling technologies and the structure and components characteristics of the whole LIB, this paper presents a recycling strategy for all components from obsolete LIBs, including discharge, dismantling, and classification, separation of electrode components and refining of LiCoO 2 /graphite. This paper is intended to provide a valuable reference for the management, scientific research, and industrial implementation on spent LIBs recycling, to recycle all valuable components and reduce the environmental pollution, so as to realize the win-win situation of economic and environmental benefits.

Dual-Layer Oxidation-Protective Plasma-Sprayed SiC-ZrB2/Al2O3-Carbon Nanotube Coating on Graphite

NASA Astrophysics Data System (ADS)

Ariharan, S.; Sengupta, Pradyut; Nisar, Ambreen; Agnihotri, Ankur; Balaji, N.; Aruna, S. T.; Balani, Kantesh

2017-02-01

Graphite is used in high-temperature gas-cooled reactors because of its outstanding irradiation performance and corrosion resistance. To restrict its high-temperature (>873 K) oxidation, atmospheric-plasma-sprayed SiC-ZrB2-Al2O3-carbon nanotube (CNT) dual-layer coating was deposited on graphite substrate in this work. The effect of each layer was isolated by processing each component of the coating via spark plasma sintering followed by isothermal kinetic studies. Based on isothermal analysis and the presence of high residual thermal stress in the oxide scale, degradation appeared to be more severe in composites reinforced with CNTs. To avoid the complexity of analysis of composites, the high-temperature activation energy for oxidation was calculated for the single-phase materials only, yielding values of 11.8, 20.5, 43.5, and 4.5 kJ/mol for graphite, SiC, ZrB2, and CNT, respectively, with increased thermal stability for ZrB2 and SiC. These results were then used to evaluate the oxidation rate for the composites analytically. This study has broad implications for wider use of dual-layer (SiC-ZrB2/Al2O3) coatings for protecting graphite crucibles even at temperatures above 1073 K.

Construction of hierarchically porous graphitized carbon-supported NiFe layered double hydroxides with a core-shell structure as an enhanced electrocatalyst for the oxygen evolution reaction.

PubMed

Ni, Yuanman; Yao, Lihua; Wang, Yin; Liu, Bing; Cao, Minhua; Hu, Changwen

2017-08-17

The oxygen evolution reaction (OER) is a vital half-reaction in water splitting and metal-air batteries. Developing earth-abundant, highly efficient and durable OER catalysts has faced huge challenges until now, because OER is a strict kinetic sluggish process. Herein, we report the construction of hierarchically porous graphitized carbon (HPGC) supported NiFe layered double hydroxides (LDHs) with a core-shell structure (denoted as HPGC@NiFe) by a facile strategy. The HPGC was first obtained by pyrolysing phenolic resin nanospheres with FeCl 3 and ZnCl 2 as the catalyst and the activator, respectively. Then the NiFe LDH arrays were directly grown on the HPGC by a one-step hydrothermal method. The as-synthesized HPGC@NiFe reveals excellent OER properties with a low onset potential, a lower overpotential of 265 mV (corresponding to the current density at 10 mA cm -2 ) and a small Tafel slope (56 mV per decade). And its catalytic activity is even superior to that of the start-of-the-art noble-metal catalyst IrO 2 /C. Notably, the HPGC@NiFe electrode shows admirable stability measured by performing 2000 cycle CVs and long-term electrolysis for 50 h. The prominent performance can be attributed to the synergistic effect between the NiFe-LDHs and the hierarchically porous graphitized carbon, in which the former can increase the exposure of the active sites, while the latter can increase the charge transfer efficiency. Our research implies the possibility for the development of low-cost layered double hydroxides as a promising candidate in electrochemical energy storage and conversion equipment.

Multi-Physics Simulation of TREAT Kinetics using MAMMOTH

DOE Office of Scientific and Technical Information (OSTI.GOV)

DeHart, Mark; Gleicher, Frederick; Ortensi, Javier

With the advent of next generation reactor systems and new fuel designs, the U.S. Department of Energy (DOE) has identified the need for the resumption of transient testing of nuclear fuels. DOE has decided that the Transient Reactor Test Facility (TREAT) at Idaho National Laboratory (INL) is best suited for future testing. TREAT is a thermal neutron spectrum nuclear test facility that is designed to test nuclear fuels in transient scenarios. These specific fuels transient tests range from simple temperature transients to full fuel melt accidents. The current TREAT core is driven by highly enriched uranium (HEU) dispersed in amore » graphite matrix (1:10000 U-235/C atom ratio). At the center of the core, fuel is removed allowing for the insertion of an experimental test vehicle. TREAT’s design provides experimental flexibility and inherent safety during neutron pulsing. This safety stems from the graphite in the driver fuel having a strong negative temperature coefficient of reactivity resulting from a thermal Maxwellian shift with increased leakage, as well as graphite acting as a temperature sink. Air cooling is available, but is generally used post-transient for heat removal. DOE and INL have expressed a desire to develop a simulation capability that will accurately model the experiments before they are irradiated at the facility, with an emphasis on effective and safe operation while minimizing experimental time and cost. At INL, the Multi-physics Object Oriented Simulation Environment (MOOSE) has been selected as the model development framework for this work. This paper describes the results of preliminary simulations of a TREAT fuel element under transient conditions using the MOOSE-based MAMMOTH reactor physics tool.« less

Chemical and constitutional influences in the self-assembly of functional supramolecular hydrogen-bonded nanoscopic fibres.

PubMed

Puigmartí-Luis, Josep; Minoia, Andrea; Pérez Del Pino, Angel; Ujaque, Gregori; Rovira, Concepció; Lledós, Agustí; Lazzaroni, Roberto; Amabilino, David B

2006-12-13

A new series of secondary amides bearing long alkyl chains with pi-electron-donor cores has been synthesized and characterised, and their self-assembly upon casting at surfaces has been studied. The different supramolecular assemblies of the materials have been visualized by using atomic force microscopy (AFM) and transmission electron microscopy (TEM). It is possible to obtain well-defined fibres of these aromatic core molecules as a result of the hydrogen bonds between the amide groups. Indeed, by altering the alkyl-chain lengths, constitutions, concentrations and solvent, it is possible to form different rodlike aggregates on graphite. Aggregate sizes with a lower limit of 6-8 nm width have been reached for different amide derivatives, while others show larger aggregates with rodlike morphologies which are several micrometers in length. For one compound that forms nanofibres, doping was performed by using a chemical oxidant, and the resulting layer on graphite was shown to exhibit metallic-like spectroscopy curves when probed with current-sensing AFM. This technique also revealed current maps of the surface of the molecular material. Fibre formation not only takes place on the graphite surface: nanometre scale rods have been imaged by using TEM on a grid after evaporation of solutions of the compounds in chloroform. Molecular modelling proves the importance of the hydrogen bonds in the generation of the fibres, and indicates that the constitution of the molecules is vital for the formation of the desired columnar stacks, results that are consistent with the images obtained by microscopic techniques. The results show the power of noncovalent bonds in self-assembly processes that can lead to electrically conducting nanoscale supramolecular wires.

High-resolution transmission electron microscopy studies of graphite materials prepared by high-temperature treatment of unburned carbon concentrates from combustion fly ashes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Miguel Cabielles; Jean-Nol Rouzaud; Ana B. Garcia

2009-01-15

High-resolution transmission electron microscopy (HRTEM) has been used in this work to study the microstructural (structure and microtexture) changes occurring during the high-temperature treatment of the unburned carbon concentrates from coal combustion fly ashes. Emphasis was placed on two aspects: (i) the development of graphitic carbon structures and (ii) the disordered carbon forms remaining in the graphitized samples. In addition, by coupling HRTEM with energy-dispersive spectroscopy, the transformations with the temperature of the inorganic matter (mainly iron- and silicon-based phases) of the unburned carbon concentrates were evidenced. The HRTEM results were compared to the averaged structural order of the materialsmore » as evaluated by X-ray diffraction (XRD) and Raman spectroscopy. As indicated by XRD and Raman parameters, more-ordered materials were obtained from the unburned carbon concentrates with higher mineral/inorganic matter, thus inferring the catalytic effect of some of their components. However, the average character of the information provided by these instrumental techniques seems to be inconclusive in discriminating between carbon structures with different degrees of order (stricto sensu graphite, graphitic, turbostratic, etc.) in a given graphitized unburned carbon. Unlike XRD and Raman, HRTEM is a useful tool for imaging directly the profile of the polyaromatic layers (graphene planes), thus allowing the sample heterogeneity to be looked at, specifically the presence of disordered carbon phases. 49 refs., 9 figs., 3 tabs.« less

Damage Tolerance of Sandwich Plates with Debonded Face Sheets

NASA Technical Reports Server (NTRS)

Avery, John L., III; Sankar, Bhavani V.

1998-01-01

Axial compression tests were performed on debonded sandwich composites made of graphite/epoxy face-sheets and aramid fiber honeycomb core. The sandwich beams were manufactured using a vacuum baccrin2 process. The face-sheet and the sandwich beam were co-cured. Delamination between one of the face sheets and the core was introduced by using a Teflon layer during the curing process. Axial compression tests were performed to determine the ultimate load carrying capacity of the debonded beams. Flatwise tension tests and Double Cantilever Beam tests were performed to determine. respectively, the strength and fracture toughness of the face-sheet/core interface. From the test results semi-empirical formulas were derived for the fracture toughness and ultimate compressive load carrying capacity in terms of the core density. core thickness. face-sheet thickness and debond length. Four different failure modes and their relation to the structural properties were identified. Linear buckling analysis was found to be inadequate in predicting the compressive load carrying capacity of the debonded sandwich composites.

Graphite Fiber Textile Preform/Copper Matrix Composites

NASA Technical Reports Server (NTRS)

Filatovs, G. J.; Lee, Bruce; Bass, Lowell

1996-01-01

Graphite fiber reinforced/copper matrix composites are candidate materials for critical heat transmitting and rejection components because of their high thermal conduction. The use of textile (braid) preforms allows near-net shapes which confers additional advantages, both for enhanced thermal conduction and increased robustness of the preform against infiltration and handling damage. Issues addressed in the past year center on the determination of the braid structure following infiltration, and the braidability vs. the conductivity of the fibers. Highly conductive fibers eventuate from increased graphitization, which increases the elastic modulus, but lowers the braidability; a balance between these factors must be achieved. Good quality braided preform bars have been fabricated and infiltrated, and their thermal expansion characterized; their analytic modeling is underway. The braided preform of an integral finned tube has been fabricated and is being prepared for infiltration.

Swift heavy ion-induced radiation damage in isotropic graphite studied by micro-indentation and in-situ electrical resistivity

NASA Astrophysics Data System (ADS)

Hubert, Christian; Voss, Kay Obbe; Bender, Markus; Kupka, Katharina; Romanenko, Anton; Severin, Daniel; Trautmann, Christina; Tomut, Marilena

2015-12-01

Due to its excellent thermo-physical properties and radiation hardness, isotropic graphite is presently the most promising material candidate for new high-power ion accelerators which will provide highest beam intensities and energies. Under these extreme conditions, specific accelerator components including production targets and beam protection modules are facing the risk of degradation due to radiation damage. Ion-beam induced damage effects were tested by irradiating polycrystalline, isotropic graphite samples at the UNILAC (GSI, Darmstadt) with 4.8 MeV per nucleon 132Xe, 150Sm, 197Au, and 238U ions applying fluences between 1 × 1011 and 1 × 1014 ions/cm2. The overall damage accumulation and its dependence on energy loss of the ions were studied by in situ 4-point resistivity measurements. With increasing fluence, the electric resistivity increases due to disordering of the graphitic structure. Irradiated samples were also analyzed off-line by means of micro-indentation in order to characterize mesoscale effects such as beam-induced hardening and stress fields within the specimen. With increasing fluence and energy loss, hardening becomes more pronounced.

Structural characterization of cup-stacked-type nanofibers with an entirely hollow core

NASA Astrophysics Data System (ADS)

Endo, M.; Kim, Y. A.; Hayashi, T.; Fukai, Y.; Oshida, K.; Terrones, M.; Yanagisawa, T.; Higaki, S.; Dresselhaus, M. S.

2002-02-01

Straight long carbon nanofibers with a large hollow core obtained by a floating reactant method show a stacking morphology of truncated conical graphene layers, which in turn exhibit a large portion of open edges on the outer surface and also in the inner channels. Through a judicious choice of oxidation conditions, nanofibers with increased active edge sites are obtained without disrupting the fiber's morphology. A graphitization process induces a morphological change from a tubular type to a reversing saw-toothed type and the formation of loops along the inner channel of the nanofibers, accompanied by a decrease in interlayer spacing.

Experimental and computational correlation of fracture parameters KIc, JIc, and GIc for unimodular and bimodular graphite components

NASA Astrophysics Data System (ADS)

Bhushan, Awani; Panda, S. K.

2018-05-01

The influence of bimodularity (different stress ∼ strain behaviour in tension and compression) on fracture behaviour of graphite specimens has been studied with fracture toughness (KIc), critical J-integral (JIc) and critical strain energy release rate (GIc) as the characterizing parameter. Bimodularity index (ratio of tensile Young's modulus to compression Young's modulus) of graphite specimens has been obtained from the normalized test data of tensile and compression experimentation. Single edge notch bend (SENB) testing of pre-cracked specimens from the same lot have been carried out as per ASTM standard D7779-11 to determine the peak load and critical fracture parameters KIc, GIc and JIc using digital image correlation technology of crack opening displacements. Weibull weakest link theory has been used to evaluate the mean peak load, Weibull modulus and goodness of fit employing two parameter least square method (LIN2), biased (MLE2-B) and unbiased (MLE2-U) maximum likelihood estimator. The stress dependent elasticity problem of three-dimensional crack progression behaviour for the bimodular graphite components has been solved as an iterative finite element procedure. The crack characterizing parameters critical stress intensity factor and critical strain energy release rate have been estimated with the help of Weibull distribution plot between peak loads versus cumulative probability of failure. Experimental and Computational fracture parameters have been compared qualitatively to describe the significance of bimodularity. The bimodular influence on fracture behaviour of SENB graphite has been reflected on the experimental evaluation of GIc values only, which has been found to be different from the calculated JIc values. Numerical evaluation of bimodular 3D J-integral value is found to be close to the GIc value whereas the unimodular 3D J-value is nearer to the JIc value. The significant difference between the unimodular JIc and bimodular GIc indicates that GIc should be considered as the standard fracture parameter for bimodular brittle specimens.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Paul Demkowicz; Lance Cole; Scott Ploger

The AGR-1 irradiation experiment ended on November 6, 2009, after 620 effective full power days in the Advanced Test Reactor, achieving a peak burnup of 19.6% FIMA. The test train was shipped to the Materials and Fuels Complex in March 2010 for post-irradiation examination. The first PIE activities included non-destructive examination of the test train, followed by disassembly of the test train and individual capsules and detailed inspection of the capsule contents, including the fuel compacts and the graphite fuel holders. Dimensional measurements of the compacts, graphite holders, and steel capsules shells were performed using a custom vision measurement systemmore » (for outer diameters and lengths) and conventional bore gauges (for inner diameters). Gamma spectrometry of the intact test train gave a preliminary look at the condition of the interior components. No evidence of damage to compacts or graphite components was evident from the isotopic and gross gamma scans. Neutron radiography of the intact Capsule 2 showed a high degree of detail of interior components and confirmed the observation that there was no major damage to the capsule. Disassembly of the capsules was initiated using procedures qualified during out-of-cell mockup testing. Difficulties were encountered during capsule disassembly due to irradiation-induced changes in some of the capsule components’ properties, including embrittled niobium and molybdenum parts that were susceptible to fracture and swelling of the graphite fuel holders that affected their removal from the capsule shells. This required various improvised modifications to the disassembly procedure to avoid damage to the fuel compacts. Ultimately the capsule disassembly was successful and only one compact from Capsule 4 (out of 72 total in the test train) sustained damage during the disassembly process, along with the associated graphite holder. The compacts were generally in very good condition upon removal. Only relatively minor damage or markings were visible using high resolution photographic inspection. Compact dimensional measurements indicated diametrical shrinkage of 0.9 to 1. 4%, and length shrinkage of 0.2 to 1.1%. The shrinkage was somewhat dependent on compact location within each capsule and within the test train. Compacts exhibited a maximum diametrical shrinkage at a fast neutron fluence of approximately 3×1021 n/cm2. A multivariate statistical analysis indicates that fast neutron fluence as well as compact position in the test train influence compact shrinkage.« less

Frequency Response of an Aircraft Wing with Discrete Source Damage Using Equivalent Plate Analysis

NASA Technical Reports Server (NTRS)

Krishnamurthy, T.; Eldred, Lloyd B.

2007-01-01

An equivalent plate procedure is developed to provide a computationally efficient means of matching the stiffness and frequencies of flight vehicle wing structures for prescribed loading conditions. Several new approaches are proposed and studied to match the stiffness and first five natural frequencies of the two reference models with and without damage. One approach divides the candidate reference plate into multiple zones in which stiffness and mass can be varied using a variety of materials including aluminum, graphite-epoxy, and foam-core graphite-epoxy sandwiches. Another approach places point masses along the edge of the stiffness-matched plate to tune the natural frequencies. Both approaches are successful at matching the stiffness and natural frequencies of the reference plates and provide useful insight into determination of crucial features in equivalent plate models of aircraft wing structures.

Silicate Inclusions in IAB Irons: Correlations Between Metal Composition and Inclusion Properties, and Inferences for Their Origin

NASA Astrophysics Data System (ADS)

Benedix, G. K.; McCoy, T. J.; Keil, K.

1995-09-01

IAB irons are the largest group of iron meteorites, exhibit a large range of siderophile element concentrations in their metal, and commonly contain silicate inclusions with roughly chondritic composition. They are closely related to IIICD irons [1,2] and their inclusions resemble winonaites [3]. It has been suggested that IAB's and IIICD's formed in individual impact melt pools [4,2] on a common parent body. However, it has also been suggested that fractional crystallization [5,6] of a S-saturated core could produce the observed siderophile element trends. Metal composition is correlated with silicate inclusion mineralogy in IIICD's [1], indicating reactions between solid silicates and the metallic magma in a core. These trends observed in IIICD's differ from those in IAB's, suggesting different parent bodies. A bi-modal grouping, based primarily on mineralogy and mineral abundances, was suggested for IAB inclusions [7]. However, recent recoveries of several new silicate-bearing IAB's, along with the emergence of new ideas on their origins, prompted a comprehensive study to document more fully the range of inclusions within IAB irons, to examine possible correlations between the compositions of the metallic host and the silicate inclusions, and to elucidate the origin of IAB irons. We are studying troilite-graphite-silicate inclusions in 24 IAB irons with Ni concentrations ranging from 6.6-25.0%. These include Odessa and Copiapo types [7], newly recovered meteorites (e.g., Lueders [8]) and meteorites with extreme Ni contents (e.g., Jenny's Creek, 6.8%; San Cristobal, 25.0% [9]). The inclusions exhibit a range of textures from recrystallized to partial melts (e.g., Caddo County [10]). Rigorous classification [7] is hampered by heterogeneities between group meteorites, between different samples of distinct meteorites, and within individual inclusions. While intergroup heterogeneities make comparisons between the suite of IAB's somewhat difficult, some general trends do exist. Inclusion mineralogy progresses from graphite-troilite nodules in low Ni IAB's, to silicate-dominated inclusions in high Ni IAB's. With increasing Ni abundance in the metal, systematic variations are found in several properties. Two groups are delineated on a Ni vs Fa content plot and both are positively correlated with Ni content. Graphite abundance noticeably decreases with increasing Ni content [7]. Graphite location also varies with Ni: graphite is primarily found interstitial to the silicates in low Ni IAB's, but is located at metal-silicate boundaries in those with higher Ni abundances. With increasing Ni, daubreelite disappears. Inclusion shape also varies [7]: more angular inclusions are associated with low Ni, while more rounded inclusions exist at high Ni contents. These systematic changes suggest interaction between the silicate inclusions and an evolving metallic magma. Troilite and graphite abundances may be related to early nucleation on silicates, hence their depletion in high Ni (later crystallizing) irons. The presence of abundant graphite creates reducing conditions which would result in the formation of daubreelite. Conditions become more oxidizing with loss of graphite, evidenced by lack of daubreelite and more FeO-rich silicates in high Ni irons. Although an overall trend exists, the story is complicated by heterogeneities. Significant variations are found between paired samples (e.g., Toluca and Tacubaya), as well as within individual inclusions (daubreelite and chromite in same inclusion). Local oxidation conditions may be controlled by graphite abundance. Heterogeneities within specific meteorites need documentation. Most of the inclusions exhibit similar textural (metamorphic) features, but a few show evidence of partial melting and melt migration, further complicating the parent body history. While a variety of processes (oxidation-reduction, metamorphism, partial melting) affected the inclusions during formation, systematic changes observed here indicate that the silicates were interacting with a single evolving metallic magma. We suggest that the requirement for a common system is more compatible with core formation [5,6] than with impact-melt pools [2,4]. References: [1] McCoy T. J. et al. (1993) Meteoritics, 28, 552-560. [2] Choi B.-G. et al. (1995) GCA, 59, 593-612. [3] Benedix G. K. et al. (1995) LPS XXVI, 99-100. [4] Wasson J. T. et al. (1980) Z. Naturforsch., 35a, 781-795. [5] Kracher A. (1982) GRL, 9, 412-415. [6] Kracher A. (1985) Proc. LPSC 15th, in JGR, 90, C689-C698. [7] Bunch T. E. et al. (1970) Contrib. Mineral. Petrol., 25, 297-340. [8] McCoy et al. (1995) Meteoritics, in preparation. [9] Scott E. R. D. and Bild R. W. (1974) GCA, 38, 1379-1391. [10] Takeda H. et al. (1993) Meteoritics, 28, 447.

Sodium-22 In Supernovae

NASA Astrophysics Data System (ADS)

Amari, Sachiko

2008-05-01

There are several isotopically distinct noble gas components in meteorites. Of them, Ne-E(L), heavily enriched in 22Ne, is carried by graphite with a range of density (1.6 - 2.2 g/cm3). Bulk (=aggregates) noble gas analysis of graphite separates from the Murchison meteorite indicate that a dominant source of 22Ne is 22Na (T1/2 = 2.6 a) with varying proportions of 22Ne via 14N(α,γ)18F(e+ν)18O(α,γ)22Ne with density. Low-density graphite grains, from their isotopic signatures, are believed to have formed in supernovae. Examinations of both bulk and single-grain analyses of low-density graphite grains (Amari et al., 1995; Nichols et al., 1994) indicate that all 22Ne in low-density graphite grains is from the decay of 22Na that was produced in the O/Ne zone in supernovae. One may argue why implanted 20,22Ne was not observed in the grains, considering the fact that the mass fraction of 20Ne is 5 orders of magnitude larger than that of 22Na. Croat et al. (2003) observed TiC subgrains inside low-density graphite grains have amorphous rims with the thickness of 3 to 15 nm, indicating atom bombardment from the surrounding gas. Assuming the gas is He, they estimated the velocity is 50 km/s or less. If the relative velocities between the Ne and the graphite grains are in that range, the penetration depth into the graphite grains is 2nm. Such shallow surface layers would be sputtered once the grains hit the reverse shock and keep traveling into the hot H-rich region (Nozawa et al, 2007). It remains to be seen whether or not 22Na in higher-density graphite is from supernovae or novae, or both. Amari, S. et al. 1995, Geochim. Cosmochim. Acta, 59, 1411 Croat, T.K. et al. 2003, Geochim. Cosmochim. Acta, 67, 4705 Nichols R.H. et al. 1994, Meteoritics, 29, 510 Nozawa, T. et al. 2007 ApJ, 666, 955

Determination of total tin in silicate rocks by graphite furnace atomic absorption spectrometry

USGS Publications Warehouse

Elsheimer, H.N.; Fries, T.L.

1990-01-01

A method is described for the determination of total tin in silicate rocks utilizing a graphite furnace atomic absorption spectrometer with a stabilized-temperature platform furnace and Zeeman-effect background correction. The sample is decomposed by lithium metaborate fusion (3 + 1) in graphite crucibles with the melt being dissolved in 7.5% hydrochloric acid. Tin extractions (4 + 1 or 8 + 1) are executed on portions of the acid solutions using a 4% solution of tricotylphosphine oxide in methyl isobutyl ketone (MIBK). Ascorbic acid is added as a reducing agent prior to extraction. A solution of diammonium hydrogenphosphate and magnesium nitrate is used as a matrix modifier in the graphite furnace determination. The limit of detection is > 10 pg, equivalent to > 1 ??g l-1 of tin in the MIBK solution or 0.2-0.3 ??g g-61 in the rock. The concentration range is linear between 2.5 and 500 ??g l-1 tin in solution. The precision, measured as relative standard deviation, is < 20% at the 2.5 ??g l-1 level and < 7% at the 10-30 ??g l-1 level of tin. Excellent agreement with recommended literature values was found when the method was applied to the international silicate rock standards BCR-1, PCC-1, GSP-1, AGV-1, STM-1, JGb-1 and Mica-Fe. Application was made to the determination of tin in geological core samples with total tin concentrations of the order of 1 ??g g-1 or less.

Tracing Life in the Earliest Terrestrial Rock Record

NASA Astrophysics Data System (ADS)

Lepland, A.; van Zuilen, M.; Arrhenius, G.

2001-12-01

The principal method for studying the earliest traces of life in the metamorphosed, oldest (> 3.5 Ga) terrestrial rocks involves determination of isotopic composition of carbon, mainly prevailing as graphite. It is generally believed that this measure can distinguish biogenic graphite from abiogenic varieties. However, the interpretation of life from carbon isotope ratios has to be assessed within the context of specific geologic circumstances requiring (i) reliable protolith interpretation (ii) control of secondary, metasomatic processes, and (iii) understanding of different graphite producing mechanisms and related carbon isotopic systematics. We have carried out a systematic study of abundance, isotopic composition and petrographic associations of graphite in rocks from the ca. 3.8 Ga Isua Supracrustal Belt (ISB) in southern West Greenland. Our study indicates that most of the graphite in ISB occurs in carbonate-rich metasomatic rocks (metacarbonates) while sedimentary units, including banded iron formations (BIFs) and metacherts, have exceedingly low graphite concentrations. Regardless of isotopic composition of graphite in metacarbonate rocks, their secondary origin disqualifies them from providing evidence for traces of life stemming from 3.8 Ga. Recognition of the secondary origin of Isua metacarbonates thus calls for reevaluation of biologic interpretations by Schidlowski et al. (1979) and Mojzsis et al. (1996) that suggested the occurrence of 3.8 Ga biogenic graphite in these rocks. The origin of minute quantities of reduced carbon, released from sedimentary BIFs and metacherts at combustion steps > 700 C remains to be clarified. Its isotopic composition (d13C from -18 to -25%) may hint at a biogenic origin. However, such isotopically light carbon was also found in Proterozoic mafic dykes cross-cutting the metasedimentary units in the ISB. The occurrence of isotopically light, reduced carbon in biologically irrelevant dykes may indicate secondary graphite crystallization from CO2 or CH4- containing fluids that in turn may derive from bioorganic sources. If this were the case, trace amounts of isotopically light secondary graphite can also be expected in metasediments, complicating the usage of light graphite as primary biomarker. The possibility of recent organic contamination, particularly important in low graphite samples, needs also to be considered; it appears as a ubiquitous component released at combustion in the 400 to 500 deg range. - A potential use of the apatite-graphite association as a biomarker has been proposed in the study by Mojzsis et al. (1996). Close inspection of several hundred apatite crystals from Isua BIFs and metacherts did, however, not show an association between these two minerals, moreover graphite is practically absent in these metasediments. In contrast, apatite crystals in the non-sedimentary metacarbonate rocks were found commonly to have invaginations, coatings and inclusions of abundant graphite. Considering that such graphite inclusions in apatite are restricted to the secondary metasomatic carbonate rocks in the ISB this association can not be considered as a primary biomarker in the Isua Supracrustal Belt References: Mojzsis,S.J, .Arrhenius,G., McKeegan, K.D.,.Harrison, T.M.,.Nutman, A.P & C.R.L.Friend.,1996. Nature 384: 55 Schidlowski, M., Appel, P.W.U., Eichmann, R. & Junge, C.E., 1979. Geochim. Cosmochim. Acta 43: 189-190.

Graphite fiber textile preform/copper matrix composites

NASA Technical Reports Server (NTRS)

Filatovs, G. J.

1993-01-01

This project has the objective of exploring the use of graphite fiber textile preform/copper matrix composites in spacecraft heat transmitting and radiating components. The preforms are to be fabricated by braiding of tows and when infiltrated with copper will result in a 3-D reinforced, near net shape composite with improved specific properties such as lower density and higher stiffness. It is anticipated that the use of textile technology will result in a more robust preform and consequently better final composite; it is hard to anticipate what performance tradeoffs will result, and these will be explored through testing and characterization.

Percolation transition in carbon composite on the basis of fullerenes and exfoliated graphite

NASA Astrophysics Data System (ADS)

Berezkin, V. I.; Popov, V. V.

2018-01-01

The electrical conductivity of a carbon composite on the basis of C60 fullerenes and exfoliated graphite is investigated in the range of relative contents of components from 0 to 100%. The samples are obtained by the thermal treatment of the initial dispersed mixtures in vacuum in the diffusion-adsorption process and their further cold pressing. The resistivity of the samples gradually increases with an increase in the fraction of fullerenes, and a sharp transition from the conductive state to the dielectric one is observed after achieving certain concentrations of C60. The interpretation of the results within the percolation theory makes it possible to evaluate the percolation threshold (expressed as a relative content of graphite) as equal to 4.45 wt % and the critical conductivity index as equal to 1.85 (which is typical for three-dimensional twocomponent disordered media including those having pores).

Rice husk-originating silicon-graphite composites for advanced lithium ion battery anodes.

PubMed

Kim, Hye Jin; Choi, Jin Hyeok; Choi, Jang Wook

2017-01-01

Rice husk is produced in a massive amount worldwide as a byproduct of rice cultivation. Rice husk contains approximately 20 wt% of mesoporous SiO 2 . We produce mesoporous silicon (Si) by reducing the rice husk-originating SiO 2 using a magnesio-milling process. Taking advantage of meso-porosity and large available quantity, we apply rice husk-originating Si to lithium ion battery anodes in a composite form with commercial graphite. By varying the mass ratio between these two components, trade-off relation between specific capacity and cycle life was observed. A controllable pre-lithiation scheme was adopted to increase the initial Coulombic efficiency and energy density. The series of electrochemical results suggest that rice husk-originating Si-graphite composites are promising candidates for high capacity lithium ion battery anodes, with the prominent advantages in battery performance and scalability.

A model of the thermal-spike mechanism in graphite/epoxy laminates

NASA Technical Reports Server (NTRS)

Adamson, M. J.

1982-01-01

The influence of a thermal spike on a moisture-saturated graphite/epoxy composite was studied in detail. A single thermal spike from 25 C to 132 C was found to produce damage as evidenced by a significant increase in the level of moisture saturation in the composite. Approximately half of this increase remained after a vacuum anneal at 150 C for 7 days, suggesting the presence of an irreversible damage component. Subsequent thermal spikes created less and less additional moisture absorption, with the cumulative effect being a maximum or limiting moisture capacity of the composite. These observations are explained in terms of a model previously developed to explain the reverse thermal effect of moisture absorption in epoxy and epoxy matrix composites. This model, based on the inverse temperature dependence of free volume, contributes an improved understanding of thermal-spike effects in graphite/epoxy composites.

Impact response of graphite-epoxy flat laminates using projectiles that simulate aircraft engine encounters

NASA Technical Reports Server (NTRS)

Preston, J. L., Jr.; Cook, T. S.

1975-01-01

An investigation of the response of a graphite-epoxy material to foreign object impact was made by impacting spherical projectiles of gelatin, ice, and steel normally on flat panels. The observed damage was classified as transverse (stress wave delamination and cracking), penetrative, or structural (gross failure): the minimum, or threshold, velocity to cause each class of damage was established as a function of projectile characteristics. Steel projectiles had the lowest transverse damage threshold, followed by gelatin and ice. Making use of the threshold velocities and assuming that the normal component of velocity produces the damage in nonnormal impacts, a set of impact angles and velocities was established for each projectile material which would result in damage to composite fan blades. Analysis of the operating parameters of a typical turbine fan blade shows that small steel projectiles are most likely to cause delamination and penetration damage to unprotected graphite-epoxy composite fan blades.

Direct manufacturing of ultrathin graphite on three-dimensional nanoscale features

PubMed Central

Pacios, Mercè; Hosseini, Peiman; Fan, Ye; He, Zhengyu; Krause, Oliver; Hutchison, John; Warner, Jamie H.; Bhaskaran, Harish

2016-01-01

There have been many successful attempts to grow high-quality large-area graphene on flat substrates. Doing so at the nanoscale has thus far been plagued by significant scalability problems, particularly because of the need for delicate transfer processes onto predefined features, which are necessarily low-yield processes and which can introduce undesirable residues. Herein we describe a highly scalable, clean and effective, in-situ method that uses thin film deposition techniques to directly grow on a continuous basis ultrathin graphite (uG) on uneven nanoscale surfaces. We then demonstrate that this is possible on a model system of atomic force probe tips of various radii. Further, we characterize the growth characteristics of this technique as well as the film’s superior conduction and lower adhesion at these scales. This sets the stage for such a process to allow the use of highly functional graphite in high-aspect-ratio nanoscale components. PMID:26939862

Improved Blackbody Temperature Sensors for a Vacuum Furnace

NASA Technical Reports Server (NTRS)

Farmer, Jeff; Coppens, Chris; O'Dell, J. Scott; McKechnie, Timothy N.; Schofield, Elizabeth

2009-01-01

Some improvements have been made in the design and fabrication of blackbody sensors (BBSs) used to measure the temperature of a heater core in a vacuum furnace. Each BBS consists of a ring of thermally conductive, high-melting-temperature material with two tantalum-sheathed thermocouples attached at diametrically opposite points. The name "blackbody sensor" reflects the basic principle of operation. Heat is transferred between the ring and the furnace heater core primarily by blackbody radiation, heat is conducted through the ring to the thermocouples, and the temperature of the ring (and, hence, the temperature of the heater core) is measured by use of the thermocouples. Two main requirements have guided the development of these BBSs: (1) The rings should have as high an emissivity as possible in order to maximize the heat-transfer rate and thereby maximize temperature-monitoring performance and (2) the thermocouples must be joined to the rings in such a way as to ensure long-term, reliable intimate thermal contact. The problem of fabricating a BBS to satisfy these requirements is complicated by an application-specific prohibition against overheating and thereby damaging nearby instrumentation leads through the use of conventional furnace brazing or any other technique that involves heating the entire BBS and its surroundings. The problem is further complicated by another application-specific prohibition against damaging the thin tantalum thermocouple sheaths through the use of conventional welding to join the thermocouples to the ring. The first BBS rings were made of graphite. The tantalum-sheathed thermocouples were attached to the graphite rings by use of high-temperature graphite cements. The ring/thermocouple bonds thus formed were found to be weak and unreliable, and so graphite rings and graphite cements were abandoned. Now, each BBS ring is made from one of two materials: either tantalum or a molybdenum/titanium/zirconium alloy. The tantalum-sheathed thermocouples are bonded to the ring by laser brazing. The primary advantage of laser brazing over furnace brazing is that in laser brazing, it is possible to form a brazed connection locally, without heating nearby parts to the flow temperature of the brazing material. Hence, it is possible to comply with the prohibition against overheating nearby instrumentation leads. Also, in laser brazing, unlike in furnace brazing, it is possible to exert control over the thermal energy to such a high degree that it becomes possible to braze the thermocouples to the ring without burning through the thin tantalum sheaths on the thermocouples. The brazing material used in the laser brazing process is a titanium-boron paste. This brazing material can withstand use at temperatures up to about 1,400 C. In thermal-cycling tests performed thus far, no debonding between the rings and thermocouples has been observed. Emissivity coatings about 0.001 in. (.0.025 mm) thick applied to the interior surfaces of the rings have been found to improve the performance of the BBS sensors by raising the apparent emissivities of the rings. In thermal-cycling tests, the coatings were found to adhere well to the rings.

GUM Analysis for TIMS Isotopic Ratios in BEP0 Graphite Qualification Samples, Round 2

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gerlach, David C.; Heasler, Patrick G.; Reid, Bruce D.

In May 2007, one set of three samples from NBL were addressed to Steve Petersen for TIMS analysis, and included BEP0 samples numbered 27008, 30986, and 50846. All cores were trimmed by tooling, and lightly cleaned by CO2 pellet blasting. Small discs were cut from the second set of samples for SIMS analysis, with the remainder of each used for TIMS preparation.

Comparison of tokamak behaviour with tungsten and low-Z plasma facing materials

NASA Astrophysics Data System (ADS)

Philipps, V.; Neu, R.; Rapp, J.; Samm, U.; Tokar, M.; Tanabe, T.; Rubel, M.

2000-12-01

Graphite wall materials are used in present day fusion devices in order to optimize plasma core performance and to enable access to a large operational space. A large physics database exists for operation with these plasma facing materials, which also indicate their use in future devices with extended burn times. The radiation from carbon impurities in the edge and divertor regions strongly helps to reduce the peak power loads on the strike areas, but carbon radiation also supports the formation of MARFE instabilities which can hinder access to high densities. The main concerns with graphite are associated with its strong chemical affinity to hydrogen, which leads to chemical erosion and to the formation of hydrogen-rich carbon layers. These layers can store a significant fraction of the total tritium fuel, which might prevent the use of these materials in future tritium devices. High-Z plasma facing materials are much more advantageous in this sense, but these advantages compete with the strong poisoning of the plasma if they enter the plasma core. New promising experiences have been obtained with high-Z wall materials in several devices, about which a survey is given in this paper and which also addresses open questions for future research and development work.

Heat Source Characterization In A TREAT Fuel Particle Using Coupled Neutronics Binary Collision Monte-Carlo Calculations

DOE Office of Scientific and Technical Information (OSTI.GOV)

Schunert, Sebastian; Schwen, Daniel; Ghassemi, Pedram

This work presents a multi-physics, multi-scale approach to modeling the Transient Test Reactor (TREAT) currently prepared for restart at the Idaho National Laboratory. TREAT fuel is made up of microscopic fuel grains (r ˜ 20µm) dispersed in a graphite matrix. The novelty of this work is in coupling a binary collision Monte-Carlo (BCMC) model to the Finite Element based code Moose for solving a microsopic heat-conduction problem whose driving source is provided by the BCMC model tracking fission fragment energy deposition. This microscopic model is driven by a transient, engineering scale neutronics model coupled to an adiabatic heating model. Themore » macroscopic model provides local power densities and neutron energy spectra to the microscpic model. Currently, no feedback from the microscopic to the macroscopic model is considered. TREAT transient 15 is used to exemplify the capabilities of the multi-physics, multi-scale model, and it is found that the average fuel grain temperature differs from the average graphite temperature by 80 K despite the low-power transient. The large temperature difference has strong implications on the Doppler feedback a potential LEU TREAT core would see, and it underpins the need for multi-physics, multi-scale modeling of a TREAT LEU core.« less

One-by-one imprinting in two eccentric layers of hollow core-shells: Sequential electroanalysis of anti-HIV drugs.

PubMed

Singh, Kislay; Jaiswal, Swadha; Singh, Richa; Fatma, Sana; Prasad, Bhim Bali

2018-07-15

Double layered one-by-one imprinted hollow core-shells@ pencil graphite electrode was fabricated for sequential sensing of anti-HIV drugs. For this, two eccentric layers were developed on the surface of vinylated silica nanospheres to obtain double layered one-by-one imprinted solid core-shells. This yielded hollow core-shells on treatment with hydrofluoric acid. The modified hollow core-shells (single layered dual imprinted) evolved competitive diffusion of probe/analyte molecules. However, the corresponding double layered one-by-one imprinted hollow core-shells (outer layer imprinted with Zidovudine, and inner layer with Lamivudine) were found relatively better owing to their bilateral diffusions into molecular cavities, without any competition. The entire work is based on differential pulse anodic stripping voltammetry at double layered one-by-one imprinted hollow core-shells. This resulted in indirect detection of electro inactive targets with limits of detection as low as 0.91 and 0.12 (aqueous sample), 0.94 and 0.13 (blood serum), and 0.99 and 0.20 ng mL -1 (pharmaceutics) for lamivudine and zidovudine, respectively in anti-HIV drug combination. Copyright © 2018 Elsevier B.V. All rights reserved.

Lithium loss in the solid electrolyte interphase: Lithium quantification of aged lithium ion battery graphite electrodes by means of laser ablation inductively coupled plasma mass spectrometry and inductively coupled plasma optical emission spectroscopy

NASA Astrophysics Data System (ADS)

Schwieters, Timo; Evertz, Marco; Mense, Maximilian; Winter, Martin; Nowak, Sascha

2017-07-01

In this work we present a new method using LA-ICP-MS to quantitatively determine the lithium content in aged graphite electrodes of a lithium ion battery (LIB) by performing total depth profiling. Matrix matched solid external standards are prepared using a solid doping approach to avoid elemental fractionation effects during the measurement. The results are compared and matched to the established ICP-OES technique for bulk quantification after performing a microwave assisted acid digestion. The method is applied to aged graphite electrodes in order to determine the lithium immobilization (= "Li loss") in the solid electrolyte interphase after the first cycle of formation. For this, different samples including a reference sample are created to obtain varying thicknesses of the SEI covering the electrode particles. By applying defined charging voltages, an initial lithiation process is performed to obtain specific graphite intercalation compounds (GICs, with target stoichiometries of LiC30, LiC18, LiC12 and LiC6). Afterwards, the graphite electrode is completely discharged to obtain samples without mobile, thus active lithium in its lattice. Taking the amount of lithium into account which originates from the residues of the LiPF6 (dissolved in the carbon components containing electrolyte), it is possible to subtract the amount of lithium in the SEI.

COMPOSITION AND METHOD FOR COATING A CERAMIC BODY

DOEpatents

Blanchard, M.K.

1958-11-01

A method is presented for protecting a beryllium carbide-graphite body. The method consists in providing a ceramic coating which must contain at least one basic oxide component, such as CaO, at least one amphoteric oxide component, such as Al/sub 2/O/sub 3/, and at least one acidic oxide component, such as SiO/ sub 2/. Various specific formulations for this ceramic coating are given and the coating is applied by conventional ceramic techniques.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bess, John D.; Sterbentz, James W.; Snoj, Luka

PROTEUS is a zero-power research reactor based on a cylindrical graphite annulus with a central cylindrical cavity. The graphite annulus remains basically the same for all experimental programs, but the contents of the central cavity are changed according to the type of reactor being investigated. Through most of its service history, PROTEUS has represented light-water reactors, but from 1992 to 1996 PROTEUS was configured as a pebble-bed reactor (PBR) critical facility and designated as HTR-PROTEUS. The nomenclature was used to indicate that this series consisted of High Temperature Reactor experiments performed in the PROTEUS assembly. During this period, seventeen criticalmore » configurations were assembled and various reactor physics experiments were conducted. These experiments included measurements of criticality, differential and integral control rod and safety rod worths, kinetics, reaction rates, water ingress effects, and small sample reactivity effects (Ref. 3). HTR-PROTEUS was constructed, and the experimental program was conducted, for the purpose of providing experimental benchmark data for assessment of reactor physics computer codes. Considerable effort was devoted to benchmark calculations as a part of the HTR-PROTEUS program. References 1 and 2 provide detailed data for use in constructing models for codes to be assessed. Reference 3 is a comprehensive summary of the HTR-PROTEUS experiments and the associated benchmark program. This document draws freely from these references. Only Cores 9 and 10 are evaluated in this benchmark report due to similarities in their construction. The other core configurations of the HTR-PROTEUS program are evaluated in their respective reports as outlined in Section 1.0. Cores 9 and 10 were evaluated and determined to be acceptable benchmark experiments.« less

Creation of Triple Hierarchical Micro-Meso-Macroporous N-doped Carbon Shells with Hollow Cores Toward the Electrocatalytic Oxygen Reduction Reaction

NASA Astrophysics Data System (ADS)

Xing, Ruohao; Zhou, Tingsheng; Zhou, Yao; Ma, Ruguang; Liu, Qian; Luo, Jun; Wang, Jiacheng

2018-03-01

A series of triple hierarchical micro-meso-macroporous N-doped carbon shells with hollow cores have been successfully prepared via etching N-doped hollow carbon spheres with CO2 at high temperatures. The surface areas, total pore volumes and micropore percentages of the CO2-activated samples evidently increase with increasing activation temperature from 800 to 950 °C, while the N contents show a contrary trend from 7.6 to 3.8 at%. The pyridinic and graphitic nitrogen groups are dominant among various N-containing groups in the samples. The 950 °C-activated sample (CANHCS-950) has the largest surface area (2072 m2 g-1), pore volume (1.96 cm3 g-1), hierarchical micro-mesopore distributions (1.2, 2.6 and 6.2 nm), hollow macropore cores ( 91 nm) and highest relative content of pyridinic and graphitic N groups. This triple micro-meso-macropore system could synergistically enhance the activity because macropores could store up the reactant, mesopores could reduce the transport resistance of the reactants to the active sites, and micropores could be in favor of the accumulation of ions. Therefore, the CANHCS-950 with optimized structure shows the optimal and comparable oxygen reduction reaction (ORR) activity but superior methanol tolerance and long-term durability to commercial Pt/C with a 4e--dominant transfer pathway in alkaline media. These excellent properties in combination with good stability and recyclability make CANHCSs among the most promising metal-free ORR electrocatalysts reported so far in practical applications. [Figure not available: see fulltext.

Structure, Frictional Melting and Fault Weakening during the 2008 Mw 7.9 Wenchuan Earthquake Slip: Observation from the WFSD Drilling Core Samples

NASA Astrophysics Data System (ADS)

Li, H.; Wang, H.; Li, C.; Zhang, J.; Sun, Z.; Si, J.; Liu, D.; Chevalier, M. L.; Han, L.; Yun, K.; Zheng, Y.

2015-12-01

The 2008 Mw7.9 Wenchuan earthquake produced two co-seismic surface ruptures along Yingxiu-Beichuan fault (~270 km) and the Guanxian-Anxian fault (~80 km) simultaneously in the Longmen Shan thrust belt. Besides, two surface rupture zones were tracked in the southern segment of the Yingxiu-Beichuan rupture zone, one along the Yingxiu fault, the other along the Shenxigou-Longchi fault, which both converged into one rupture zone at the Bajiaomiao village, Hongkou town, where one distinct fault plane with two striation orientations was exposed. The Wenchuan earthquake Fault Scientific Drilling project (WFSD) was carried out right after the earthquake to investigate its faulting mechanisms and rupture process. Six boreholes were drilled along the rupture zones with depths ranging from 600 to 2400 m. WFSD-1 and WFSD-2 are located at the Bajiaomiao area, the southern segment of the Yingxiu-Beichuan rupture zone, while WFSD-4 and WFSD-4S are in the Nanba town area, in the northern part of the rupture zone. Detailed research showed that ~1 mm thick Principal Slip Zone (PSZ) of the Wenchuan earthquake is located at ~589 m-depth in the WFSD-1 cores. Graphite present in the PSZ indicates a low fault strength. Long-term temperature monitoring shows an extremely low fault friction coefficient during the earthquake. Recently, another possible PSZ was found in WFSD-1 cores at ~732 m-depth, with a ~2 mm thick melt layer in the fault gouge, where feldspar was melted but quartz was not, indicating that the frictional melting temperature was 1230°C < T < 1720°C. These two PSZs at depth may correspond to the two co-seismic surface rupture zones. Besides, the Wenchuan earthquake PSZ was also recognized in the WFSD-4S cores, at ~1084 m-depth. About 200-400 μm thick melt layer (fault vein, mainly feldspar), as well as melt injection veins, were observed in the slip zone, where oblique distinct striations were visible on the slip surface. Therefore, there are two PSZs in the shallow crust at the southern segment along the Yingxiu-Beichuan fault, and another one along the northern segment. Melt and graphite in the PSZs indicate that the frictional melting and thermal pressurization are the main fault mechanisms during the Wenchuan earthquake. The melt and graphite can be considered as markers of large earthquakes.

CARBON-RICH PRESOLAR GRAINS FROM MASSIVE STARS: SUBSOLAR {sup 12}C/{sup 13}C AND {sup 14}N/{sup 15}N RATIOS AND THE MYSTERY OF {sup 15}N

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pignatari, M.; Zinner, E.; Hoppe, P.

2015-08-01

Carbon-rich grains with isotopic anomalies compared to the Sun are found in primitive meteorites. They were made by stars, and carry the original stellar nucleosynthesis signature. Silicon carbide grains of Type X and C and low-density (LD) graphites condensed in the ejecta of core-collapse supernovae. We present a new set of models for the explosive He shell and compare them with the grains showing {sup 12}C/{sup 13}C and {sup 14}N/{sup 15}N ratios lower than solar. In the stellar progenitor H was ingested into the He shell and not fully destroyed before the explosion. Different explosion energies and H concentrations aremore » considered. If the supernova shock hits the He-shell region with some H still present, the models can reproduce the C and N isotopic signatures in C-rich grains. Hot-CNO cycle isotopic signatures are obtained, including a large production of {sup 13}C and {sup 15}N. The short-lived radionuclides {sup 22}Na and {sup 26}Al are increased by orders of magnitude. The production of radiogenic {sup 22}Ne from the decay of {sup 22}Na in the He shell might solve the puzzle of the Ne-E(L) component in LD graphite grains. This scenario is attractive for the SiC grains of type AB with {sup 14}N/{sup 15}N ratios lower than solar, and provides an alternative solution for SiC grains originally classified as nova grains. Finally, this process may contribute to the production of {sup 14}N and {sup 15}N in the Galaxy, helping to produce the {sup 14}N/{sup 15}N ratio in the solar system.« less

Carbon-rich presolar grains from massive stars. Subsolar 12 C/ 13 C and 14 N/ 15 N ratios and the mystery of 15 N

DOE PAGES

Pignatari, M.; Zinner, E.; Hoppe, P.; ...

2015-07-30

We compared carbon-rich grains with isotopic anomalies to the Sun are found in primitive meteorites. They were made by stars, and carry the original stellar nucleosynthesis signature. Silicon carbide grains of Type X and C and low-density (LD) graphites condensed in the ejecta of core-collapse supernovae. Furthermore, we present a new set of models for the explosive He shell and compare them with the grains showing 12C/ 13C and 14N/ 15N ratios lower than solar. In the stellar progenitor H was ingested into the He shell and not fully destroyed before the explosion. All of the explosion energies and Hmore » concentrations are considered. If the supernova shock hits the He-shell region with some H still present, the models can reproduce the C and N isotopic signatures in C-rich grains. Hot-CNO cycle isotopic signatures are obtained, including a large production of 13C and 15N. The short-lived radionuclides 22Na and 26Al are increased by orders of magnitude. The production of radiogenic 22Ne from the decay of 22Na in the He shell might solve the puzzle of the Ne-E(L) component in LD graphite grains. This scenario is attractive for the SiC grains of type AB with 14N/ 15N ratios lower than solar, and provides an alternative solution for SiC grains originally classified as nova grains. Finally, this process may contribute to the production of 14N and 15N in the Galaxy, helping to produce the 14N/ 15N ratio in the solar system.« less

Low-velocity impact tests on fibrous composite sandwich structures

NASA Technical Reports Server (NTRS)

Sharma, A. V.

1981-01-01

The effect of low-velocity projectile impact on the load-carrying ability of the composite sandwich structural components is investigated experimentally, the impact simulating the damage caused by runway debris and the accidental dropping of hand tools during servicing on secondary aircraft structures made with composites. The sandwich-type beam specimens were fabricated with graphite/epoxy face sheets, aluminum honeycomb core, and a steel (back) plate. A four-point beam-loading apparatus was used, and the ultimate strength, ultimate strain, and residual strength of the composites were determined. A faired curve is presented indicating the lower bound of the failure threshold for each of the laminate configurations tested in compression and tension as a function of the projectile impact energy. It is shown that strength degradation due to impact is dependent on the laminate configuration and the fiber/matrix combination. The laminates having more angle plies near the impact surface and unidirectional plies elsewhere seem to show extensive interply and intraply fiber delaminations at failure relative to the laminates with a cross-ply on the impact surface.

Analyzing the impact of reactive transport on the repository performance of TRISO fuel

NASA Astrophysics Data System (ADS)

Schmidt, Gregory

One of the largest determiners of the amount of electricity generated by current nuclear reactors is the efficiency of the thermodynamic cycle used for power generation. Current light water reactors (LWR) have an efficiency of 35% or less for the conversion of heat energy generated by the reactor to electrical energy. If this efficiency could be improved, more power could be generated from equivalent volumes of nuclear fuel. One method of improving this efficiency is to use a coolant flow that operates at a much higher temperature for electricity production. A reactor design that is currently proposed to take advantage of this efficiency is a graphite-moderated, helium-cooled reactor known as a High Temperature Gas Reactor (HTGR). There are significant differences between current LWR's and the proposed HTGR's but most especially in the composition of the nuclear fuel. For LWR's, the fuel elements consist of pellets of uranium dioxide or plutonium dioxide that are placed in long tubes made of zirconium metal alloys. For HTGR's, the fuel, known as TRISO (TRIstructural-ISOtropic) fuel, consists of an inner sphere of fissile material, a layer of dense pyrolytic carbon (PyC), a ceramic layer of silicon carbide (SiC) and a final dense outer layer of PyC. These TRISO particles are then compacted with graphite into fuel rods that are then placed in channels in graphite blocks. The blocks are then arranged in an annular fashion to form a reactor core. However, this new fuel form has unanswered questions on the environmental post-burn-up behavior. The key question for current once-through fuel operations is how these large irradiated graphite blocks with spent fuel inside will behave in a repository environment. Data in the literature to answer this question is lacking, but nevertheless this is an important question that must be answered before wide-spread adoption of HTGR's could be considered. This research has focused on answering the question of how the large quantity of graphite surrounding the spent HTGR fuel will impact the release of aqueous uranium from the TRISO fuel. In order to answer this question, the sorption and partitioning behavior of uranium to graphite under a variety of conditions was investigated. Key systematic variables that were analyzed include solution pH, dissolved carbonate concentration, uranium metal concentration and ionic strength. The kinetics and desorption characteristics of uranium/graphite partitioning were studied as well. The graphite used in these experiments was also characterized by a variety of techniques and conclusions are drawn about the relevant surface chemistry of graphite. This data was then used to generate a model for the reactive transport of uranium in a graphite matrix. This model was implemented with the software code CXTFIT and validated through the use of column studies mirroring the predicted system.

BRAZING ALLOYS

DOEpatents

Donnelly, R.G.; Gilliland, R.G.; Slaughter, G.M.

1962-02-20

A brazing alloy is described which, in the molten state, is characterized by excellent wettability and flowability and is capable of forming a corrosion-resistant brazed joint. At least one component of said joint is graphite and the other component is a corrosion-resistant refractory metal. The brazing alloy consists essentially of 40 to 90 wt % of gold, 5 to 35 wt% of nickel, and 1 to 45 wt% of tantalum. (AEC)

NEUTRONIC REACTOR

DOEpatents

Wigner, E.P.

1958-04-22

A nuclear reactor for isotope production is described. This reactor is designed to provide a maximum thermal neutron flux in a region adjacent to the periphery of the reactor rather than in the center of the reactor. The core of the reactor is generally centrally located with respect tn a surrounding first reflector, constructed of beryllium. The beryllium reflector is surrounded by a second reflector, constructed of graphite, which, in tune, is surrounded by a conventional thermal shield. Water is circulated through the core and the reflector and functions both as a moderator and a coolant. In order to produce a greatsr maximum thermal neutron flux adjacent to the periphery of the reactor rather than in the core, the reactor is designed so tbat the ratio of neutron scattering cross section to neutron absorption cross section averaged over all of the materials in the reflector is approximately twice the ratio of neutron scattering cross section to neutron absorption cross section averaged over all of the material of the core of the reactor.

Conductivity tensor for anisotropic plasma in gyrokinetic theory

DOE PAGES

Porazik, Peter; Johnson, Jay R.

2017-05-18

Comprehensive non-invasive spectroscopic techniques and electrical measurements of the carbon arc revealed two distinguishable plasma synthesis regions in the radial direction normal to the arc axis. These regions, which are defined as the arc core and the arc periphery, are shown to have very different compositions of carbon species with different densities and temperatures. The colder arc periphery is dominated by carbon diatomic molecules (C-2), which are in the minority in the composition of the hot arc core. These differences are due to a highly non-uniform distribution of the arc current, which is mainly conducted through the arc core populatedmore » with carbon atoms and ions. Therefore, the ablation of the graphite anode is governed by the arc core, while the formation of carbon molecules occurs in the colder arc periphery. This result is consistent with previous predictions that the plasma environment in the arc periphery is suitable for synthesis of carbon nanotubes.« less

Conductivity tensor for anisotropic plasma in gyrokinetic theory

DOE Office of Scientific and Technical Information (OSTI.GOV)

Porazik, Peter; Johnson, Jay R.

Comprehensive non-invasive spectroscopic techniques and electrical measurements of the carbon arc revealed two distinguishable plasma synthesis regions in the radial direction normal to the arc axis. These regions, which are defined as the arc core and the arc periphery, are shown to have very different compositions of carbon species with different densities and temperatures. The colder arc periphery is dominated by carbon diatomic molecules (C-2), which are in the minority in the composition of the hot arc core. These differences are due to a highly non-uniform distribution of the arc current, which is mainly conducted through the arc core populatedmore » with carbon atoms and ions. Therefore, the ablation of the graphite anode is governed by the arc core, while the formation of carbon molecules occurs in the colder arc periphery. This result is consistent with previous predictions that the plasma environment in the arc periphery is suitable for synthesis of carbon nanotubes.« less

Merging of Kirkendall Growth and Ostwald Ripening: CuO@MnO2 Core-shell Architectures for Asymmetric Supercapacitors

PubMed Central

Huang, Ming; Zhang, Yuxin; Li, Fei; Wang, Zhongchang; Alamusi; Hu, Ning; Wen, Zhiyu; Liu, Qing

2014-01-01

Fabricating hierarchical core-shell nanostructures is currently the subject of intensive research in the electrochemical field owing to the hopes it raises for making efficient electrodes for high-performance supercapacitors. Here, we develop a simple and cost-effective approach to prepare CuO@MnO2 core-shell nanostructures without any surfactants and report their applications as electrodes for supercapacitors. An asymmetric supercapacitor with CuO@MnO2 core-shell nanostructure as the positive electrode and activated microwave exfoliated graphite oxide (MEGO) as the negative electrode yields an energy density of 22.1 Wh kg−1 and a maximum power density of 85.6 kW kg−1; the device shows a long-term cycling stability which retains 101.5% of its initial capacitance even after 10000 cycles. Such a facile strategy to fabricate the hierarchical CuO@MnO2 core-shell nanostructure with significantly improved functionalities opens up a novel avenue to design electrode materials on demand for high-performance supercapacitor applications. PMID:24682149

C-O-H-N fluids circulations and graphite precipitation in reactivated Hudsonian shear zones during basement uplift of the Wollaston-Mudjatik Transition Zone: Example of the Cigar Lake U deposit

NASA Astrophysics Data System (ADS)

Martz, Pierre; Cathelineau, Michel; Mercadier, Julien; Boiron, Marie-Christine; Jaguin, Justine; Tarantola, Alexandre; Demacon, Mickael; Gerbeaud, Olivier; Quirt, David; Doney, Amber; Ledru, Patrick

2017-12-01

Graphitic shear zones are spatially associated with unconformity-related uranium deposits that are located around the unconformity between the strata of the Paleo- to Mesoproterozoic Athabasca Basin (Saskatchewan, Canada) and its underlying Archean to Paleoproterozoic basement. The present study focuses on basement-hosted ductile-brittle graphitic shear zones near the Cigar Lake U deposit, one of the largest unconformity-related U deposits. The goal of the study is to decipher the pre-Athabasca Basin fluid migration history recorded within such structures and its potential role on the formation of such exceptional deposit. Dominantly C-O-H(-N) metamorphic fluids have been trapped in Fluid Inclusion Planes (FIPs) in magmatic quartz within ductile-brittle graphitic shear zones active during retrograde metamorphism associated with the formation of the Wollaston-Mudjatik Transition Zone (WMTZ) between ca. 1805 and 1720 Ma. Such fluids show a compositional evolution along the retrograde path, from a dense and pure CO2 fluid during the earliest stages, through a lower density CO2 ± CH4-N2 (± H2O) fluid and, finally, to a very low density CH4-N2 fluid. Statistical study of the orientation, distribution, proportion, and chemical characterization of the FIPs shows that: i) CO2 (δ13CCO2 around - 9‰ PDB) from decarbonation reactions and/or partial water-metamorphic graphite equilibrium initially migrated regionally and pervasively under lithostatic conditions at about 500 to 800 °C and 150 to 300 MPa. Such P-T conditions attest to a high geothermal gradient of around 60 to 90 °C/km, probably related to rapid exhumation of the basement or a large-scale heat source. ii) Later brittle reactivation of the shear zone at around 450 °C and 25-50 MPa favored circulation of CO2-CH4-N2(± H2O) fluids in equilibrium with metamorphic graphite (δ13CCO2 around - 14‰) under hydrostatic conditions and only within the shear zones. Cooling of these fluids and the water uptake linked to fluid-basement rock reactions led to the precipitation at around 450 °C of poorly-crystallized hydrothermal graphite. This graphite presents isotopic (δ13C - 30 to - 26‰ PDB) and morphological differences from the high-T metamorphic graphite (> 600 °C, - 29 to - 20‰ δ13C) derived from metamorphism of C-rich sedimentary material. The brittle structural reactivation and the related fluid migration and graphite precipitation were specifically focused within the shear zones and related damage zones. The brittle reactivation produced major changes in the petro-physical, mineralogical, and chemical characteristics of the structures and their damage zones. It especially increased the fracture paleoporosity and rock weakness toward the fault cores. These major late metamorphic modifications of the graphitic shear zones were likely key parameters favoring the enhanced reactivity of these basement zones under tectonic stress following deposition of the Athabasca Basin, and so controlled basinal brine movement at the basin/basement interface related to the formation of the unconformity-related uranium deposits. This relationship consequently readily explains the specific spatial relationships between unconformity-related U deposits and the ductile-brittle graphitic shear zones.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Luther, Erik Paul; Leckie, Rafael M.; Dombrowski, David E.

This supplemental report describes fuel fabrication efforts conducted for the Idaho National Laboratory Trade Study for the TREAT Conversion project that is exploring the replacement of the HEU (Highly Enriched Uranium) fuel core of the TREAT reactor with LEU (Low Enriched Uranium) fuel. Previous reports have documented fabrication of fuel by the “upgrade” process developed at Los Alamos National Laboratory. These experiments supplement an earlier report that describes efforts to increase the graphite content of extruded fuel and minimize cracking.

TUNGSTEN BASE ALLOYS

DOEpatents

Schell, D.H.; Sheinberg, H.

1959-12-15

A high-density quaternary tungsten-base alloy having high mechanical strength and good machinability composed of about 2 wt.% Ni, 3 wt.% Cu, 5 wt.% Pb, and 90wt.% W is described. This alloy can be formed by the powder metallurgy technique of hot pressing in a graphite die without causing a reaction between charge and the die and without formation of a carbide case on the final compact, thereby enabling re-use of the graphite die. The alloy is formable at hot- pressing temperatures of from about 1200 to about 1350 deg C. In addition, there is little component shrinkage, thereby eliminating the necessity of subsequent extensive surface machining.

IMPREGNATION OF GRAPHITE SPECIMENS USING THE FURFURYL ALCOHOL IMPREGNATION PROCESS. Project DRAGON

DOE Office of Scientific and Technical Information (OSTI.GOV)

Martina, R.A.; Vohler, O.J.

1964-11-15

This report gives the results of the furfuryl alcohol impregnation treatment of graphite fuel rods and end plugs done by Sigri Kohlefabrikate GmbH, Meitingen, from May 1962 till April 1964. By impregnating the components two and three times, resp. the permeability was decreased, starting from a coefficient of about 5 x 10{sup -2}cm{sup 2}sec{sup -1}, to a value of 10{sup -6} - 10{sup -7}cm{sup 2}sec{sup -1}. The rejects as occured with the first batches were finally diminished to a negligible amount by studying the single steps of treatment. (auth)

Carbothermal transformation of a graphitic carbon nanofiber/silica aerogel composite to a SiC/silica nanocomposite.

PubMed

Lu, Weijie; Steigerwalt, Eve S; Moore, Joshua T; Sullivan, Lisa M; Collins, W Eugene; Lukehart, C M

2004-09-01

Carbon nanofiber/silica aerogel composites are prepared by sol-gel processing of surface-enhanced herringbone graphitic carbon nanofibers (GCNF) and Si(OMe)4, followed by supercritical CO2 drying. Heating the resulting GCNF/silica aerogel composites to 1650 degrees C under a partial pressure of Ar gas initiates carbothermal reaction between the silica aerogel matrix and the carbon nanofiber component to form SiC/silica nanocomposites. The SiC phase is present as nearly spherical nanoparticles, having an average diameter of ca. 8 nm. Formation of SiC is confirmed by powder XRD and by Raman spectroscopy.

Uncovering the local inelastic interactions during manufacture of ductile cast iron: How the substructure of the graphite particles can induce residual stress concentrations in the matrix

NASA Astrophysics Data System (ADS)

Andriollo, Tito; Hellström, Kristina; Sonne, Mads Rostgaard; Thorborg, Jesper; Tiedje, Niels; Hattel, Jesper

2018-02-01

Recent X-ray diffraction (XRD) measurements have revealed that plastic deformation and a residual elastic strain field can be present around the graphite particles in ductile cast iron after manufacturing, probably due to some local mismatch in thermal contraction. However, as only one component of the elastic strain tensor could be obtained from the XRD data, the shape and magnitude of the associated residual stress field have remained unknown. To compensate for this and to provide theoretical insight into this unexplored topic, a combined experimental-numerical approach is presented in this paper. First, a material equivalent to the ductile cast iron matrix is manufactured and subjected to dilatometric and high-temperature tensile tests. Subsequently, a two-scale hierarchical top-down model is devised, calibrated on the basis of the collected data and used to simulate the interaction between the graphite particles and the matrix during manufacturing of the industrial part considered in the XRD study. The model indicates that, besides the viscoplastic deformation of the matrix, the effect of the inelastic deformation of the graphite has to be considered to explain the magnitude of the XRD strain. Moreover, the model shows that the large elastic strain perturbations recorded with XRD close to the graphite-matrix interface are not artifacts due to e.g. sharp gradients in chemical composition, but correspond to residual stress concentrations induced by the conical sectors forming the internal structure of the graphite particles. In contrast to common belief, these results thus suggest that ductile cast iron parts cannot be considered, in general, as stress-free at the microstructural scale.

Electrospun core-shell fibers for robust silicon nanoparticle-based lithium ion battery anodes.

PubMed

Hwang, Tae Hoon; Lee, Yong Min; Kong, Byung-Seon; Seo, Jin-Seok; Choi, Jang Wook

2012-02-08

Because of its unprecedented theoretical capacity near 4000 mAh/g, which is approximately 10-fold larger compared to those of the current commercial graphite anodes, silicon has been the most promising anode for lithium ion batteries, particularly targeting large-scale energy storage applications including electrical vehicles and utility grids. Nevertheless, Si suffers from its short cycle life as well as the limitation for scalable electrode fabrication. Herein, we develop an electrospinning process to produce core-shell fiber electrodes using a dual nozzle in a scalable manner. In the core-shell fibers, commercially available nanoparticles in the core are wrapped by the carbon shell. The unique core-shell structure resolves various issues of Si anode operations, such as pulverization, vulnerable contacts between Si and carbon conductors, and an unstable sold-electrolyte interphase, thereby exhibiting outstanding cell performance: a gravimetric capacity as high as 1384 mAh/g, a 5 min discharging rate capability while retaining 721 mAh/g, and cycle life of 300 cycles with almost no capacity loss. The electrospun core-shell one-dimensional fibers suggest a new design principle for robust and scalable lithium battery electrodes suffering from volume expansion. © 2011 American Chemical Society

A carbon-rich region in Miller Range 091004 and implications for ureilite petrogenesis

NASA Astrophysics Data System (ADS)

Day, James M. D.; Corder, Christopher A.; Cartigny, Pierre; Steele, Andrew M.; Assayag, Nelly; Rumble, Douglas; Taylor, Lawrence A.

2017-02-01

Ureilite meteorites are partially melted asteroidal-peridotite residues, or more rarely, cumulates that can contain greater than three weight percent carbon. Here we describe an exceptional C-rich lithology, composed of 34 modal % large (up to 0.8 mm long) crystalline graphite grains, in the Antarctic ureilite meteorite Miller Range (MIL) 091004. This C-rich lithology is embedded within a silicate region composed dominantly of granular olivine with lesser quantities of low-Ca pyroxene, and minor FeNi metal, high-Ca pyroxene, spinel, schreibersite and troilite. Petrological evidence indicates that the graphite was added after formation of the silicate region and melt depletion. Associated with graphite is localized reduction of host olivine (Fo88-89) to nearly pure forsterite (Fo99), which is associated with FeNi metal grains containing up to 11 wt.% Si. The main silicate region is typical of ureilite composition, with highly siderophile element (HSE) abundances ∼0.3 × chondrite, 187Os/188Os of 0.1260-0.1262 and Δ17O of -0.81 ± 0.16‰. Mineral trace-element analyses reveal that the rare earth elements (REE) and the HSE are controlled by pyroxene and FeNi metal phases in the meteorite, respectively. Modeling of bulk-rock REE and HSE abundances indicates that the main silicate region experienced ∼6% silicate and >50% sulfide melt extraction, which is at the lower end of partial melt removal estimated for ureilites. Miller Range 091004 demonstrates heterogeneous distribution of carbon at centimeter scales and a limited range in Mg/(Mg + Fe) compositions of silicate grain cores, despite significant quantities of carbon. These observations demonstrate that silicate rim reduction was a rapid disequilibrium process, and came after silicate and sulfide melt removal in MIL 091004. The petrography and mineral chemistry of MIL 091004 is permissive of the graphite representing late-stage C-rich melt that pervaded silicates, or carbon that acted as a lubricant during anatexis and impact disruption in the parent body. Positive correlation of Pt/Os ratios with olivine core compositions, but a wide range of oxygen isotope compositions, indicates that ureilites formed from a compositionally heterogeneous parent body that experienced variable sulfide and metal melt-loss that is most pronounced in relatively oxidized ureilites with Δ17O between -1.5 and ∼0‰.

Fuselage Structure Response to Boundary Layer, Tonal Sound, and Jet Noise

NASA Technical Reports Server (NTRS)

Maestrello, L.

2004-01-01

Experiments have been conducted to study the response of curved aluminum and graphite-epoxy fuselage structures to flow and sound loads from turbulent boundary layer, tonal sound, and jet noise. Both structures were the same size. The aluminum structure was reinforced with tear stoppers, while the graphite-epoxy structure was not. The graphite-epoxy structure weighed half as much as the aluminum structure. Spatiotemporal intermittence and chaotic behavior of the structural response was observed, as jet noise and tonal sound interacted with the turbulent boundary layer. The fundamental tone distributed energy to other components via wave interaction with the turbulent boundary layer. The added broadband sound from the jet, with or without a shock, influenced the responses over a wider range of frequencies. Instantaneous spatial correlation indicates small localized spatiotemporal regions of convected waves, while uncorrelated patterns dominate the larger portion of the space. By modifying the geometry of the tear stoppers between panels and frame, the transmitted and reflected waves of the aluminum panels were significantly reduced. The response level of the graphite-epoxy structure was higher, but the noise transmitted was nearly equal to that of the aluminum structure. The fundamental shock mode is between 80 deg and 150 deg and the first harmonic is between 20 deg and 80 deg for the underexpanded supersonic jet impinging on the turbulent boundary layer influencing the structural response. The response of the graphite-epoxy structure due to the fundamental mode of the shock impingement was stabilized by an externally fixed oscillator.

Co-production of Nitrogen-15 and Oxygen-18 in Explosive Helium Burning and Implications for Supernova Graphite Grains

NASA Astrophysics Data System (ADS)

Bojazi, Michael

My Masters research involves simulations of a supernova whereby a shock wave of constant Mach number is sent through a 15-solar-mass star evolved to the point of core-collapse. The resulting nucleosynthesis is examined with the intent of explaining the overproduction, relative to solar values, of nitrogen-15 and oxygen-18 abundances in supernova presolar graphite grains, as experimentally determined by Groopman et al. via a NanoSIMS analysis. We find such overabundances to be present in the helium-rich zone. Oxygen-18 is leftover from presupernova helium burning while nitrogen-15 is produced by explosive helium burning. Interestingly, anomalous excesses in molybdenum-95 and molybdenum-97 abundances in SiC X grains, discovered by Pellin et al. using the CHARISMA instrument, probably arise from explosive helium burning as well. These results signal the importance of the helium-rich zone for supernova presolar grain growth. We suggest that matter deep from the supernova, which is rich in iron-peak elements, gets injected into the helium-rich zone. Small TiC grains form in this material. These subgrains then traverse the helium-rich zone and serve as seeds for the growth of the graphite or SiC X grains.

Epitaxial Growth of Aligned and Continuous Carbon Nanofibers from Carbon Nanotubes.

PubMed

Lin, Xiaoyang; Zhao, Wei; Zhou, Wenbin; Liu, Peng; Luo, Shu; Wei, Haoming; Yang, Guangzhi; Yang, Junhe; Cui, Jie; Yu, Richeng; Zhang, Lina; Wang, Jiaping; Li, Qunqing; Zhou, Weiya; Zhao, Weisheng; Fan, Shoushan; Jiang, Kaili

2017-02-28

Exploiting the superior properties of nanomaterials at macroscopic scale is a key issue of nanoscience. Different from the integration strategy, "additive synthesis" of macroscopic structures from nanomaterial templates may be a promising choice. In this paper, we report the epitaxial growth of aligned, continuous, and catalyst-free carbon nanofiber thin films from carbon nanotube films. The fabrication process includes thickening of continuous carbon nanotube films by gas-phase pyrolytic carbon deposition and further graphitization of the carbon layer by high-temperature treatment. As-fabricated nanofibers in the film have an "annual ring" cross-section, with a carbon nanotube core and a graphitic periphery, indicating the templated growth mechanism. The absence of a distinct interface between the carbon nanotube template and the graphitic periphery further implies the epitaxial growth mechanism of the fiber. The mechanically robust thin film with tunable fiber diameters from tens of nanometers to several micrometers possesses low density, high electrical conductivity, and high thermal conductivity. Further extension of this fabrication method to enhance carbon nanotube yarns is also demonstrated, resulting in yarns with ∼4-fold increased tensile strength and ∼10-fold increased Young's modulus. The aligned and continuous features of the films together with their outstanding physical and chemical properties would certainly promote the large-scale applications of carbon nanofibers.

Real-time monitoring of subsurface microbial metabolism with graphite electrodes

DOE PAGES

Wardman, Colin; Nevin, Kelly P.; Lovley, Derek R.

2014-11-21

Monitoring in situ microbial activity in anoxic submerged soils and aquatic sediments can be labor intensive and technically difficult, especially in dynamic environments in which a record of changes in microbial activity over time is desired. Microbial fuel cell concepts have previously been adapted to detect changes in the availability of relatively high concentrations of organic compounds in waste water but, in most soils and sediments, rates of microbial activity are not linked to the concentrations of labile substrates, but rather to the turnover rates of the substrate pools with steady state concentrations in the nM-μ M range. In ordermore » to determine whether levels of current produced at a graphite anode would correspond to the rates of microbial metabolism in anoxic sediments, small graphite anodes were inserted in sediment cores and connected to graphite brush cathodes in the overlying water. Currents produced were compared with the rates of [2- 14C]-acetate metabolism. There was a direct correlation between current production and the rate that [2- 14C]-acetate was metabolized to 14CO 2 and 14CH 4 in sediments in which Fe(III) reduction, sulfate reduction, or methane production was the predominant terminal electron-accepting process. At comparable acetate turnover rates, currents were higher in the sediments in which sulfate-reduction or Fe(III) reduction predominated than in methanogenic sediments. This was attributed to reduced products (Fe(II), sulfide) produced at distance from the anode contributing to current production in addition to the current that was produced from microbial oxidation of organic substrates with electron transfer to the anode surface in all three sediment types. In conclusion, the results demonstrate that inexpensive graphite electrodes may provide a simple strategy for real-time monitoring of microbial activity in a diversity of anoxic soils and sediments.« less

A graphite calorimeter for absolute measurements of absorbed dose to water: application in medium-energy x-ray filtered beams.

PubMed

Pinto, M; Pimpinella, M; Quini, M; D'Arienzo, M; Astefanoaei, I; Loreti, S; Guerra, A S

2016-02-21

The Italian National Institute of Ionizing Radiation Metrology (ENEA-INMRI) has designed and built a graphite calorimeter that, in a water phantom, has allowed the determination of the absorbed dose to water in medium-energy x-rays with generating voltages from 180 to 250 kV. The new standard is a miniaturized three-bodies calorimeter, with a disc-shaped core of 21 mm diameter and 2 mm thickness weighing 1.134 g, sealed in a PMMA waterproof envelope with air-evacuated gaps. The measured absorbed dose to graphite is converted into absorbed dose to water by means of an energy-dependent conversion factor obtained from Monte Carlo simulations. Heat-transfer correction factors were determined by FEM calculations. At a source-to-detector distance of 100 cm, a depth in water of 2 g cm(-2), and at a dose rate of about 0.15 Gy min(-1), results of calorimetric measurements of absorbed dose to water, D(w), were compared to experimental determinations, D wK, obtained via an ionization chamber calibrated in terms of air kerma, according to established dosimetry protocols. The combined standard uncertainty of D(w) and D(wK) were estimated as 1.9% and 1.7%, respectively. The two absorbed dose to water determinations were in agreement within 1%, well below the stated measurement uncertainties. Advancements are in progress to extend the measurement capability of the new in-water-phantom graphite calorimeter to other filtered medium-energy x-ray qualities and to reduce the D(w) uncertainty to around 1%. The new calorimeter represents the first implementation of in-water-phantom graphite calorimetry in the kilovoltage range and, allowing independent determinations of D(w), it will contribute to establish a robust system of absorbed dose to water primary standards for medium-energy x-ray beams.

The Place for Thermoplastic Composites in Structural Components

DTIC Science & Technology

1987-12-01

The molten tube is then squashed flat and consolidated into ribbon form by continuous opposed-belt laminating. Existing graphite-epoxy pultrusion...the solid form it must have a molecular weight that exceeds the critical entanglement value. Thus thermoplastic materials of commercial worth almost

Development of CVD-W coatings on CuCrZr and graphite substrates with a PVD intermediate layer

NASA Astrophysics Data System (ADS)

Song, Jiupeng; Lian, Youyun; Lv, Yanwei; Liu, Junyong; Yu, Yang; Liu, Xiang; Yan, Binyou; Chen, Zhigang; Zhuang, Zhigang; Zhao, Ximeng; Qi, Yang

2014-12-01

In order to apply tungsten (W) coatings by chemical vapor deposition (CVD) for repairing or updating the plasma facing components (PFCs) of the first wall and divertor in existing or future tokomaks, where CuCrZr or graphite is the substrate material, an intermediate layer by physical vapor deposition (PVD) has been used to accommodate the interface stress due to the mismatch of thermal expansion or act as a diffusion barrier between the CVD-W coating and the substrate. The prepared CuCrZr/PVD-Cu/CVD-W sample with active cooling has passed thermal fatigue tests by electron beam with an absorbed power of 2.2 MW/m2, 50 s on/50 s off, for 100 cycles. Another graphite/PVD-Si/CVD-W sample without active cooling underwent thermal fatigue testing with an absorbed power density of 4.62 MW/m2, 5 s on/25 s off, for 200 cycles, and no catastrophic failure was found.

Systems integration and demonstration of advanced reusable structure for ALS

NASA Technical Reports Server (NTRS)

Gibbins, Martin N.

1991-01-01

The objective was to investigate the potential of advanced material to achieve life cycle cost (LCC) benefits for reusable structure on the advanced launch system. Three structural elements were investigated - all components of an Advanced Launch System reusable propulsion/avionics module. Leading aeroshell configurations included sandwich structure using titanium, graphite/polyimide (Gr/PI), or high-temperature aluminum (HTA) face sheets. Thrust structure truss concepts used titanium, graphite/epoxy, or silicon carbide/aluminum struts. Leading aft bulkhead concepts employed graphite epoxy and aluminum. The technical effort focused on the aeroshell because the greatest benefits were expected there. Thermal analyses show the structural temperature profiles during operation. Finite element analyses show stresses during splash-down. Weight statements and manufacturing cost estimates were prepared for calculation of LCC for each design. The Gr/PI aeroshell showed the lowest potential LCC, but the HTA aeroshell was judged to be lower risk. A technology development plan was prepared to validate the applicable structural technology.

Enhancement of gaps in thin graphitic films for heterostructure formation

NASA Astrophysics Data System (ADS)

Hague, J. P.

2014-04-01

There are a large number of atomically thin graphitic films with a structure similar to that of graphene. These films have a spread of band gaps relating to their ionicity and, also, to the substrate on which they are grown. Such films could have a range of applications in digital electronics, where graphene is difficult to use. I use the dynamical cluster approximation to show how electron-phonon coupling between film and substrate can enhance these gaps in a way that depends on the range and strength of the coupling. It is found that one of the driving factors in this effect is a charge density wave instability for electrons on a honeycomb lattice that can open a gap in monolayer graphene. The enhancement at intermediate coupling is sufficiently large that spatially varying substrates and superstrates could be used to create heterostructures in thin graphitic films with position-dependent electron-phonon coupling and gaps, leading to advanced electronic components.

Design of a tokamak fusion reactor first wall armor against neutral beam impingement

DOE Office of Scientific and Technical Information (OSTI.GOV)

Myers, R.A.

1977-12-01

The maximum temperatures and thermal stresses are calculated for various first wall design proposals, using both analytical solutions and the TRUMP and SAP IV Computer Codes. Beam parameters, such as pulse time, cycle time, and beam power, are varied. It is found that uncooled plates should be adequate for near-term devices, while cooled protection will be necessary for fusion power reactors. Graphite and tungsten are selected for analysis because of their desirable characteristics. Graphite allows for higher heat fluxes compared to tungsten for similar pulse times. Anticipated erosion (due to surface effects) and plasma impurity fraction are estimated. Neutron irradiationmore » damage is also discussed. Neutron irradiation damage (rather than erosion, fatigue, or creep) is estimated to be the lifetime-limiting factor on the lifetime of the component in fusion power reactors. It is found that the use of tungsten in fusion power reactors, when directly exposed to the plasma, will cause serious plasma impurity problems; graphite should not present such an impurity problem.« less

Preliminary burn and impact tests of hybrid polymeric composites. [preventing graphite fiber release

NASA Technical Reports Server (NTRS)

Tompkins, S. S.; Brewer, W. D.

1978-01-01

Free graphite fibers released into the environment from resin matrix composite components, as a result of fire and/or explosion, pose a potential hazard to electrical equipment. An approach to prevent the fibers from becoming airborne is to use hybrid composite materials which retain the fibers at the burn site. Test results are presented for three hybrid composites that were exposed to a simulation of an aircraft fire and explosion. The hybrid systems consisted of 16 plies of graphite-epoxy with two plies of Kevlar-, S-glass-, or boron-epoxy on each face. Two different test environments were used. In one environment, specimens were heated by convection only, and then impacted by a falling mass. In the other environment, specimens were heated by convection and by radiation, but were not impacted. The convective heat flux was about 100-120 kW/m in both environments and the radiative flux was about 110 kW/sq m.

Electrolyte volume effects on electrochemical performance and solid electrolyte interphase in Si-graphite/NMC lithium-ion pouch cells

DOE PAGES

An, Seong Jin; Li, Jianlin; Daniel, Claus; ...

2017-05-15

This study aims to explore the correlations between electrolyte volume, electrochemical performance, and properties of the solid electrolyte interphase in pouch cells with Si-graphite composite anodes. The electrolyte is 1.2 M LiPF 6 in ethylene carbonate:ethylmethyl carbonate with 10 wt.% fluoroethylene carbonate. Single layer pouch cells (100 mAh) were constructed with 15 wt.% Si-graphite/LiNi 0.5Mn 0.3CO 0.2O 2 electrodes. It is found that a minimum electrolyte volume factor of 3.1 times the total pore volume of cell components (cathode, anode, and separator) is needed for better cycling stability. Less electrolyte causes increases in ohmic and charge transfer resistances. Lithium dendritesmore » are observed when the electrolyte volume factor is low. The resistances from the anodes become significant as the cells are discharged. As a result, solid electrolyte interphase thickness grows as the electrolyte volume factor increases and is non-uniform after cycling.« less

Laser induced periodic surface structures formation by nanosecond laser irradiation of poly (ethylene terephthalate) reinforced with Expanded Graphite

NASA Astrophysics Data System (ADS)

Rodríguez-Beltrán, René I.; Hernandez, Margarita; Paszkiewicz, Sandra; Szymczyk, Anna; Rosłaniec, Zbigniew; Ezquerra, Tiberio A.; Castillejo, Marta; Moreno, Pablo; Rebollar, Esther

2018-04-01

We report on the formation of Laser Induced Periodic Surface Structures in poly (ethylene terephthalate) and poly (ethylene terephthalate)/Expanded Graphite films by laser irradiation with nanosecond pulses at 266 nm. The characterization studies show that the quality of the ripples depends strongly on the irradiation time and fluence and the optimal conditions for obtaining LIPSS are affected by the amount of the expanded graphite present in the film due to the differences in crystallinity, thermal conductivity and thermal diffusivity of the nanocomposites. Physicochemical modifications in the materials were inspected by Raman spectroscopy, the colloidal probe technique and contact angle measurements using different liquids. Results show that there is an increase of the hydrophilicity of the surfaces after laser irradiation together with an increase of the surface free energy and in particular of its polar component. Additionally, the adhesion force estimated by the colloidal probe technique increases after laser nanostructuring.

The reduction mechanism of a natural chromite at 1416 °C

NASA Astrophysics Data System (ADS)

Soykan, O.; Eric, R. H.; King, R. P.

1991-02-01

The behavior of a natural chromite from the Bushveld Complex, Transvaal, South Africa, during reduction at 1416 °C by graphite was studied by means of thermogravimetric analysis, X-ray diffraction (XRD) analysis, energy-dispersive X-ray analysis (EDAX), and metallographic analysis. Experimental runs were allowed to proceed up to 120 minutes, resulting in 99 pct reduction. The specific objective of this study was to delineate the reduction mechanism of chromite by graphite. Zoning was observed in partially reduced chromites with degrees of reduction of up to about 70 pct. The inner cores were rich in iron, while the outer cores were depleted of iron. Energy-dispersive X-ray analysis revealed that Fe2+ and Cr3+ ions had diffused outward, whereas Cr2+, Al3+, and Mg2+ ions had diffused inward. The following mechanism of reduction, which is based on the assumption that the composition of the spinel phase remains stoichiometric with increasing degree of reduction, is proposed, (a) Initially, Fe3+ and Fe2+ ions at the surface of the chromite particle are reduced to the metallic state. This is followed immediately by the reduction of Cr3+ ions to the divalent state, (b) Cr2+ ions diffusing toward the center of the particle reduce the Fe3+ ions in the spinel under the surface of the particle to Fe2+ at the interface between the inner and outer cores. Fe2+ ions diffuse toward the surface, where they are reduced to metallic iron, (c) After the iron has been completely reduced, Cr3+ and any Cr2+ that is present are reduced to the metallic state, leaving an iron- and chromium-free spinel, MgAl2O4.

Structural and chemical degradation mechanisms of pure YSZ and its components ZrO2 and Y2O3 in carbon-rich fuel gases.

PubMed

Köck, Eva-Maria; Kogler, Michaela; Götsch, Thomas; Klötzer, Bernhard; Penner, Simon

2016-05-25

Structural and chemical degradation mechanisms of metal-free yttria stabilized zirconia (YSZ-8, 8 mol% Y2O3 in ZrO2) in comparison to its pure oxidic components ZrO2 and Y2O3 have been studied in carbon-rich fuel gases with respect to coking/graphitization and (oxy)carbide formation. By combining operando electrochemical impedance spectroscopy (EIS), operando Fourier-transform infrared (FT-IR) spectroscopy and X-ray photoelectron spectroscopy (XPS), the removal and suppression of CH4- and CO-induced carbon deposits and of those generated in more realistic fuel gas mixtures (syngas, mixtures of CH4 or CO with CO2 and H2O) was examined under SOFC-relevant conditions up to 1273 K and ambient pressures. Surface-near carbidization is a major problem already on the "isolated" (i.e. Nickel-free) cermet components, leading to irreversible changes of the conduction properties. Graphitic carbon deposition takes place already on the "isolated" oxides under sufficiently fuel-rich conditions, most pronounced in the pure gases CH4 and CO, but also significantly in fuel gas mixtures containing H2O and CO2. For YSZ, a comparative quantification of the total amount of deposited carbon in all gases and mixtures is provided and thus yields favorable and detrimental experimental approaches to suppress the carbon formation. In addition, the effectivity and reversibility of removal of the coke/graphite layers was comparably studied in the pure oxidants O2, CO2 and H2O and their effective contribution upon addition to the pure fuel gases CO and CH4 verified.

Multilayer core-shell structured composite paper electrode consisting of copper, cuprous oxide and graphite assembled on cellulose fibers for asymmetric supercapacitors

NASA Astrophysics Data System (ADS)

Wan, Caichao; Jiao, Yue; Li, Jian

2017-09-01

An easily-operated and inexpensive strategy (pencil-drawing-electrodeposition-electro-oxidation) is proposed to synthesize a novel class of multilayer core-shell structured composite paper electrode, which consists of copper, cuprous oxide and graphite assembled on cellulose fibers. This interesting electrode structure plays a pivotal role in providing more active sites for electrochemical reactions, facilitating ion and electron transport and shorting their diffusion pathways. This electrode demonstrates excellent electrochemical properties with a high specific capacitance of 601 F g-1 at 2 A g-1 and retains 83% of this capacitance when operated at an ultrahigh current density of 100 A g-1. In addition, a high energy density of 13.4 W h kg-1 at the power density of 0.40 kW kg-1 and a favorable cycling stability (95.3%, 8000 cycles) were achieved for this electrode. When this electrode was assembled into an asymmetric supercapacitor with carbon paper as negative electrode, the device displays remarkable electrochemical performances with a large areal capacitances (122 mF cm-2 at 1 mA cm-2), high areal energy density (10.8 μW h cm-2 at 402.5 μW cm-2) and outstanding cycling stability (91.5%, 5000 cycles). These results unveil the potential of this composite electrode as a high-performance electrode material for supercapacitors.

Benchmark Evaluation of Start-Up and Zero-Power Measurements at the High-Temperature Engineering Test Reactor

DOE PAGES

Bess, John D.; Fujimoto, Nozomu

2014-10-09

Benchmark models were developed to evaluate six cold-critical and two warm-critical, zero-power measurements of the HTTR. Additional measurements of a fully-loaded subcritical configuration, core excess reactivity, shutdown margins, six isothermal temperature coefficients, and axial reaction-rate distributions were also evaluated as acceptable benchmark experiments. Insufficient information is publicly available to develop finely-detailed models of the HTTR as much of the design information is still proprietary. However, the uncertainties in the benchmark models are judged to be of sufficient magnitude to encompass any biases and bias uncertainties incurred through the simplification process used to develop the benchmark models. Dominant uncertainties in themore » experimental keff for all core configurations come from uncertainties in the impurity content of the various graphite blocks that comprise the HTTR. Monte Carlo calculations of keff are between approximately 0.9 % and 2.7 % greater than the benchmark values. Reevaluation of the HTTR models as additional information becomes available could improve the quality of this benchmark and possibly reduce the computational biases. High-quality characterization of graphite impurities would significantly improve the quality of the HTTR benchmark assessment. Simulation of the other reactor physics measurements are in good agreement with the benchmark experiment values. The complete benchmark evaluation details are available in the 2014 edition of the International Handbook of Evaluated Reactor Physics Benchmark Experiments.« less

A solid reactor core thermal model for nuclear thermal rockets

NASA Astrophysics Data System (ADS)

Rider, William J.; Cappiello, Michael W.; Liles, Dennis R.

1991-01-01

A Helium/Hydrogen Cooled Reactor Analysis (HERA) computer code has been developed. HERA has the ability to model arbitrary geometries in three dimensions, which allows the user to easily analyze reactor cores constructed of prismatic graphite elements. The code accounts for heat generation in the fuel, control rods, and other structures; conduction and radiation across gaps; convection to the coolant; and a variety of boundary conditions. The numerical solution scheme has been optimized for vector computers, making long transient analyses economical. Time integration is either explicit or implicit, which allows the use of the model to accurately calculate both short- or long-term transients with an efficient use of computer time. Both the basic spatial and temporal integration schemes have been benchmarked against analytical solutions.

Evaporation of sessile droplets affected by graphite nanoparticles and binary base fluids.

PubMed

Zhong, Xin; Duan, Fei

2014-11-26

The effects of ethanol component and nanoparticle concentration on evaporation dynamics of graphite-water nanofluid droplets have been studied experimentally. The results show that the formed deposition patterns vary greatly with an increase in ethanol concentration from 0 to 50 vol %. Nanoparticles have been observed to be carried to the droplet surface and form a large piece of aggregate. The volume evaporation rate on average increases as the ethanol concentration increases from 0 to 50 vol % in the binary mixture nanofluid droplets. The evaporation rate at the initial stage is more rapid than that at the late stage to dry, revealing a deviation from a linear fitting line, standing for a constant evaporation rate. The deviation is more intense with a higher ethanol concentration. The ethanol-induced smaller liquid-vapor surface tension leads to higher wettability of the nanofluid droplets. The graphite nanoparticles in ethanol-water droplets reinforce the pinning effect in the drying process, and the droplets with more ethanol demonstrate the depinning behavior only at the late stage. The addition of graphite nanoparticles in water enhances a droplet baseline spreading at the beginning of evaporation, a pinning effect during evaporation, and the evaporation rate. However, with a relatively high nanoparticle concentration, the enhancement is attenuated.

Formation of Reversible Solid Electrolyte Interface on Graphite Surface from Concentrated Electrolytes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lu, Dongping; Tao, Jinhui; Yan, Pengfei

2017-02-10

Interfacial phenomena have always been key determinants for the performance of energy storage technologies. The solid electrolyte interfacial (SEI) layer, pervasive on the surfaces of battery electrodes for numerous chemical couples, directly affects the ion transport, charge transfer and lifespan of the entire energy system. Almost all SEI layers, however, are unstable resulting in the continuous consumption of the electrolyte. Typically, this leads to the accumulation of degradation products on/restructuring of the electrode surface and thus increased cell impedance, which largely limits the long-term operation of the electrochemical reactions. Herein, a completely new SEI formation mechanism has been discovered, inmore » which the electrolyte components reversibly self-assemble into a protective surface coating on a graphite electrode upon changing the potential. In contrast to the established wisdom regarding the necessity of employing the solvent ethylene carbonate (EC) to form a protective SEI layer on graphite, a wide range of EC-free electrolytes are demonstrated for the reversible intercalation/deintercalation of Li+ cations within a graphite lattice, thereby providing tremendous flexibility in electrolyte tailoring for battery couples. This novel finding is broadly applicable and provides guidance for how to control interfacial reactions through the relationship between ion aggregation and solvent decomposition at polarized interfaces.« less

Producibility aspects of advanced composites for an L-1011 Aileron

NASA Technical Reports Server (NTRS)

Van Hamersveld, J.; Fogg, L. D.

1976-01-01

The design of advanced composite aileron suitable for long-term service on transport aircraft includes Kevlar 49 fabric skins on honeycomb sandwich covers, hybrid graphite/Kevlar 49 ribs and spars, and graphite/epoxy fittings. Weight and cost savings of 28 and 20 percent, respectively, are predicted by comparison with the production metallic aileron. The structural integrity of the design has been substantiated by analysis and static tests of subcomponents. The producibility considerations played a key role in the selection of design concepts with potential for low-cost production. Simplicity in fabrication is a major factor in achieving low cost using advanced tooling and manufacturing methods such as net molding to size, draping, forming broadgoods, and cocuring components. A broadgoods dispensing machine capable of handling unidirectional and bidirectional prepreg materials in widths ranging from 12 to 42 inches is used for rapid layup of component kits and covers. Existing large autoclaves, platen presses, and shop facilities are fully exploited.

Quality control of FWC during assembly and commissioning in SST-1 Tokamak

NASA Astrophysics Data System (ADS)

Patel, Hitesh; Santra, Prosenjit; Parekh, Tejas; Biswas, Prabal; Jayswal, Snehal; Chauhan, Pradeep; Paravastu, Yuvakiran; George, Siju; Semwal, Pratibha; Thankey, Prashant; Ramesh, Gattu; Prakash, Arun; Dhanani, Kalpesh; Raval, D. C.; Khan, Ziauddin; Pradhan, Subrata

2017-04-01

First Wall Components (FWC) of SST-1 tokamak, which are in the immediate vicinity of plasma, comprises of limiters, divertors, baffles, passive stabilizers designed to operate long duration (∼1000 s) discharges of elongated plasma. All FWC consist of copper alloy heat sink modules with SS cooling tubes brazed onto it, graphite tiles acting as armour material facing the plasma, and are mounted to the vacuum vessels with suitable Inconel support structures at inter-connected ring & port locations. The FWC are very recently assembled and commissioned successfully inside the vacuum vessel of SST-1 undergoing a rigorous quality control and checks at every stage of the assembly process. This paper will present the quality control aspects and checks of FWC from commencement of assembly procedure, namely material test reports, leak testing of high temperature baked components, assembled dimensional tolerances, leak testing of all welded joints, graphite tile tightening torques, electrical continuity and electrical isolation of passive stabilizers from vacuum vessel, baking and cooling hydraulic connections inside vacuum vessel.

Preparation and Characterization of Graphene Oxide Paper

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dikin,D.; Stankovich, S.; Zimney, E.

2007-01-01

Free-standing paper-like or foil-like materials are an integral part of our technological society. Their uses include protective layers, chemical filters, components of electrical batteries or supercapacitors, adhesive layers, electronic or optoelectronic components, and molecular storage. Inorganic 'paper-like' materials based on nanoscale components such as exfoliated vermiculite or mica platelets have been intensively studied and commercialized as protective coatings, high-temperature binders, dielectric barriers and gas-impermeable membranes. Carbon-based flexible graphite foils composed of stacked platelets of expanded graphite have long been used in packing and gasketing applications because of their chemical resistivity against most media, superior sealability over a wide temperature range,more » and impermeability to fluids. The discovery of carbon nanotubes brought about bucky paper, which displays excellent mechanical and electrical properties that make it potentially suitable for fuel cell and structural composite applications. Here we report the preparation and characterization of graphene oxide paper, a free-standing carbon-based membrane material made by flow-directed assembly of individual graphene oxide sheets. This new material outperforms many other paper-like materials in stiffness and strength. Its combination of macroscopic flexibility and stiffness is a result of a unique interlocking-tile arrangement of the nanoscale graphene oxide sheets.« less

Preparation and characterization of graphene oxide paper.

PubMed

Dikin, Dmitriy A; Stankovich, Sasha; Zimney, Eric J; Piner, Richard D; Dommett, Geoffrey H B; Evmenenko, Guennadi; Nguyen, SonBinh T; Ruoff, Rodney S

2007-07-26

Free-standing paper-like or foil-like materials are an integral part of our technological society. Their uses include protective layers, chemical filters, components of electrical batteries or supercapacitors, adhesive layers, electronic or optoelectronic components, and molecular storage. Inorganic 'paper-like' materials based on nanoscale components such as exfoliated vermiculite or mica platelets have been intensively studied and commercialized as protective coatings, high-temperature binders, dielectric barriers and gas-impermeable membranes. Carbon-based flexible graphite foils composed of stacked platelets of expanded graphite have long been used in packing and gasketing applications because of their chemical resistivity against most media, superior sealability over a wide temperature range, and impermeability to fluids. The discovery of carbon nanotubes brought about bucky paper, which displays excellent mechanical and electrical properties that make it potentially suitable for fuel cell and structural composite applications. Here we report the preparation and characterization of graphene oxide paper, a free-standing carbon-based membrane material made by flow-directed assembly of individual graphene oxide sheets. This new material outperforms many other paper-like materials in stiffness and strength. Its combination of macroscopic flexibility and stiffness is a result of a unique interlocking-tile arrangement of the nanoscale graphene oxide sheets.

BRAZING ALLOYS

DOEpatents

Donnelly, R.G.; Gilliland, R.G.; Slaughter, G.M.

1963-02-26

A brazing alloy which, in the molten state, is characterized by excellent wettability and flowability, said alloy being capable of forming a corrosion resistant brazed joint wherein at least one component of said joint is graphite and the other component is a corrosion resistant refractory metal, said alloy consisting essentially of 20 to 50 per cent by weight of gold, 20 to 50 per cent by weight of nickel, and 15 to 45 per cent by weight of molybdenum. (AEC)

Non-precious metal catalysts prepared from precursor comprising cyanamide

DOEpatents

Chung, Hoon Taek; Zelenay, Piotr

2015-10-27

Catalyst comprising graphitic carbon and methods of making thereof; said graphitic carbon comprising a metal species, a nitrogen-containing species and a sulfur containing species. A catalyst for oxygen reduction reaction for an alkaline fuel cell was prepared by heating a mixture of cyanamide, carbon black, and a salt selected from an iron sulfate salt and an iron acetate salt at a temperature of from about 700.degree. C. to about 1100.degree. C. under an inert atmosphere. Afterward, the mixture was treated with sulfuric acid at elevated temperature to remove acid soluble components, and the resultant mixture was heated again under an inert atmosphere at the same temperature as the first heat treatment step.

Self repairing composites for drone air vehicles

NASA Astrophysics Data System (ADS)

Dry, Carolyn

2015-04-01

The objective of this effort was to demonstrate the feasibility of impact-initiated delivery of repair chemicals through hollow fiber architectures embedded within graphite fiber reinforced polymer matrix composites, representative of advanced drone aircraft component material systems. Self-repairing structures through coupon and elements were demonstrated, and evaluated.

Facile synthesis of hierarchical Co3O4@MnO2 core-shell arrays on Ni foam for asymmetric supercapacitors

NASA Astrophysics Data System (ADS)

Huang, Ming; Zhang, Yuxin; Li, Fei; Zhang, Lili; Wen, Zhiyu; Liu, Qing

2014-04-01

Hierarchical Co3O4@MnO2 core-shell arrays on Ni foam have been fabricated by a facile hydrothermal approach and further investigated as the electrode for high-performance supercapacitors. Owing to the high conductivity of the well-defined mesoporous Co3O4 nanowire arrays in combination with the large surface area provided by the ultrathin MnO2 nanosheets, the unique designed Co3O4@MnO2 core-shell arrays on Ni foam have exhibited a high specific capacitance (560 F g-1 at a current density of 0.2 A g-1), good rate capability, and excellent cycling stability (95% capacitance retention after 5000 cycles). An asymmetric supercapacitor with Co3O4@MnO2 core-shell nanostructure as the positive electrode and activated microwave exfoliated graphite oxide activated graphene (MEGO) as the negative electrode yielded an energy density of 17.7 Wh kg-1 and a maximum power density of 158 kW kg-1. The rational design of the unique core-shell array architectures demonstrated in this work provides a new and facile approach to fabricate high-performance electrode for supercapacitors.

A Protection And Detection Surface (PADS) for damage tolerance

NASA Technical Reports Server (NTRS)

Shuart, M. J.; Prasad, C. B.; Biggers, S. B.

1990-01-01

A protection and detection surface (PADS) concept was studied for application to composite primary aircraft structures. A Kevlar-epoxy woven face sheet with a Rohacell foam core was found to be the most effective PADS configuration among the configurations evaluated. The weight of the PADS configuration was estimated to be approximately 17 percent of the structural weight. The PADS configuration was bonded to graphite-epoxy base laminates, and up to a 70 percent improvement in compression-after-impact failure strains was observed.

A Protection And Detection Surface (PADS) for damage tolerance

NASA Technical Reports Server (NTRS)

Shuart, Mark J.; Prasad, Chunchu B.; Biggers, Sherrill B.

1990-01-01

A protection and detection surface (PADS) concept was studied for application to composite primary aircraft structures. A Kevlar-epoxy woven face sheet with a Rohacell foam core was found to be the most effective PADS configuration among the configurations evaluated. The weight of the PADS configuration was estimated to be approximately 17 pct of the structural weight. The PADS configuration was bonded to graphite-epoxy base laminates, and up to a 70 pct improvement in compression-after-impact failure strains was observed.

A 10-MJ compact homopolar generator

NASA Astrophysics Data System (ADS)

McKee, B. D.; McNab, I. R.

1986-11-01

The design and initial testing of a lightweight (5 kJ/kg) iron-cored homopolar generator is described. The machine employs an external power supply to motor up to operating speed (12,500 rpm) at which point 10 MJ of energy is stored in the steel rotor. Copper-graphite brushes in the stator, actuated by pneumatic actuators, make contact with the rotor surface and permit the inertial energy to be transferred to a load circuit at current levels up to 1.5 MA and voltages up to 60 V.

Effect of Tooling Material on the Internal Surface Quality of Ti6Al4V Parts Fabricated by Hot Isostatic Pressing

NASA Astrophysics Data System (ADS)

Cai, Chao; Song, Bo; Wei, Qingsong; Yan, Wu; Xue, Pengju; Shi, Yusheng

2017-01-01

For the net-shape hot isostatic pressing (HIP) process, control of the internal surface roughness of as-HIPped parts remains a challenge for practical engineering. To reveal the evolution mechanism of the internal surface of the parts during the HIP process, the effect of different tooling materials (H13, T8, Cr12 steel, and graphite) as internal cores on the interfacial diffusion and surface roughness was systematically studied.

Dry-air-stable lithium silicide-lithium oxide core-shell nanoparticles as high-capacity prelithiation reagents.

PubMed

Zhao, Jie; Lu, Zhenda; Liu, Nian; Lee, Hyun-Wook; McDowell, Matthew T; Cui, Yi

2014-10-03

Rapid progress has been made in realizing battery electrode materials with high capacity and long-term cyclability in the past decade. However, low first-cycle Coulombic efficiency as a result of the formation of a solid electrolyte interphase and Li trapping at the anodes, remains unresolved. Here we report LixSi-Li2O core-shell nanoparticles as an excellent prelithiation reagent with high specific capacity to compensate the first-cycle capacity loss. These nanoparticles are produced via a one-step thermal alloying process. LixSi-Li2O core-shell nanoparticles are processible in a slurry and exhibit high capacity under dry-air conditions with the protection of a Li2O passivation shell, indicating that these nanoparticles are potentially compatible with industrial battery fabrication processes. Both Si and graphite anodes are successfully prelithiated with these nanoparticles to achieve high first-cycle Coulombic efficiencies of 94% to >100%. The LixSi-Li2O core-shell nanoparticles enable the practical implementation of high-performance electrode materials in lithium-ion batteries.

Modelling the graphite fracture mechanisms

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jacquemoud, C.; Marie, S.; Nedelec, M.

2012-07-01

In order to define a design criterion for graphite components, it is important to identify the physical phenomena responsible for the graphite fracture, to include them in a more effective modelling. In a first step, a large panel of experiments have been realised in order to build up an important database; results of tensile tests, 3 and 4 point bending tests on smooth and notched specimens have been analysed and have demonstrated an important geometry related effects on the behavior up to fracture. Then, first simulations with an elastic or an elastoplastic bilinear constitutive law have not made it possiblemore » to simulate the experimental fracture stress variations with the specimen geometry, the fracture mechanisms of the graphite being at the microstructural scale. That is the reason why a specific F.E. model of the graphite structure has been developed in which every graphite grain has been meshed independently, the crack initiation along the basal plane of the particles as well as the crack propagation and coalescence have been modelled too. This specific model has been used to test two different approaches for fracture initiation: a critical stress criterion and two criteria of fracture mechanic type. They are all based on crystallographic considerations as a global critical stress criterion gave unsatisfactory results. The criteria of fracture mechanic type being extremely unstable and unable to represent the graphite global behaviour up to the final collapse, the critical stress criterion has been preferred to predict the results of the large range of available experiments, on both smooth and notched specimens. In so doing, the experimental observations have been correctly simulated: the geometry related effects on the experimental fracture stress dispersion, the specimen volume effects on the macroscopic fracture stress and the crack propagation at a constant stress intensity factor. In addition, the parameters of the criterion have been related to experimental observations: the local crack initiation stress of 8 MPa corresponds to the non-linearity apparition on the global behavior observed experimentally and the the maximal critical stress defined for the particle of 30 MPa is equivalent to the fracture stress of notched specimens. This innovative combination of crack modelling and a local crystallographic critical stress criterion made it possible to understand that cleavage initiation and propagation in the graphite microstructure was driven by a mean critical stress criterion. (authors)« less

VERY LARGE INTERSTELLAR GRAINS AS EVIDENCED BY THE MID-INFRARED EXTINCTION

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wang, Shu; Jiang, B. W.; Li, Aigen, E-mail: shuwang@mail.bnu.edu.cn, E-mail: bjiang@bnu.edu.cn, E-mail: wanshu@missouri.edu, E-mail: lia@missouri.edu

The sizes of interstellar grains are widely distributed, ranging from a few angstroms to a few micrometers. The ultraviolet (UV) and optical extinction constrains the dust in the size range of a couple hundredths of micrometers to several submicrometers. The near and mid infrared (IR) emission constrains the nanometer-sized grains and angstrom-sized very large molecules. However, the quantity and size distribution of micrometer-sized grains remain unknown because they are gray in the UV/optical extinction and they are too cold and emit too little in the IR to be detected by IRAS, Spitzer, or Herschel. In this work, we employ themore » ∼3–8 μm mid-IR extinction, which is flat in both diffuse and dense regions to constrain the quantity, size, and composition of the μm-sized grain component. We find that, together with nano- and submicron-sized silicate and graphite (as well as polycyclic aromatic hydrocarbons), μm-sized graphite grains with C/H ≈ 137 ppm and a mean size of ∼1.2 μm closely fit the observed interstellar extinction of the Galactic diffuse interstellar medium from the far-UV to the mid-IR, as well as the near-IR to millimeter thermal emission obtained by COBE/DIRBE, COBE/FIRAS, and Planck up to λ ≲ 1000 μm. The μm-sized graphite component accounts for ∼14.6% of the total dust mass and ∼2.5% of the total IR emission.« less

Fission Product Inventory and Burnup Evaluation of the AGR-2 Irradiation by Gamma Spectrometry

DOE Office of Scientific and Technical Information (OSTI.GOV)

Harp, Jason Michael; Stempien, John Dennis; Demkowicz, Paul Andrew

Gamma spectrometry has been used to evaluate the burnup and fission product inventory of different components from the US Advanced Gas Reactor Fuel Development and Qualification Program's second TRISO-coated particle fuel irradiation test (AGR-2). TRISO fuel in this irradiation included both uranium carbide / uranium oxide (UCO) kernels and uranium oxide (UO 2) kernels. Four of the 6 capsules contained fuel from the US Advanced Gas Reactor program, and only those capsules will be discussed in this work. The inventories of gamma-emitting fission products from the fuel compacts, graphite compact holders, graphite spacers and test capsule shell were evaluated. Thesemore » data were used to measure the fractional release of fission products such as Cs-137, Cs-134, Eu-154, Ce-144, and Ag-110m from the compacts. The fraction of Ag-110m retained in the compacts ranged from 1.8% to full retention. Additionally, the activities of the radioactive cesium isotopes (Cs-134 and Cs-137) have been used to evaluate the burnup of all US TRISO fuel compacts in the irradiation. The experimental burnup evaluations compare favorably with burnups predicted from physics simulations. Predicted burnups for UCO compacts range from 7.26 to 13.15 % fission per initial metal atom (FIMA) and 9.01 to 10.69 % FIMA for UO 2 compacts. Measured burnup ranged from 7.3 to 13.1 % FIMA for UCO compacts and 8.5 to 10.6 % FIMA for UO 2 compacts. Results from gamma emission computed tomography performed on compacts and graphite holders that reveal the distribution of different fission products in a component will also be discussed. Gamma tomography of graphite holders was also used to locate the position of TRISO fuel particles suspected of having silicon carbide layer failures that lead to in-pile cesium release.« less

Fission Product Inventory and Burnup Evaluation of the AGR-2 Irradiation by Gamma Spectrometry

DOE Office of Scientific and Technical Information (OSTI.GOV)

Harp, Jason M.; Demkowicz, Paul A.; Stempien, John D.

Gamma spectrometry has been used to evaluate the burnup and fission product inventory of different components from the US Advanced Gas Reactor Fuel Development and Qualification Program's second TRISO-coated particle fuel irradiation test (AGR-2). TRISO fuel in this irradiation included both uranium carbide / uranium oxide (UCO) kernels and uranium oxide (UO2) kernels. Four of the 6 capsules contained fuel from the US Advanced Gas Reactor program, and only those capsules will be discussed in this work. The inventories of gamma-emitting fission products from the fuel compacts, graphite compact holders, graphite spacers and test capsule shell were evaluated. These datamore » were used to measure the fractional release of fission products such as Cs-137, Cs-134, Eu-154, Ce-144, and Ag-110m from the compacts. The fraction of Ag-110m retained in the compacts ranged from 1.8% to full retention. Additionally, the activities of the radioactive cesium isotopes (Cs-134 and Cs-137) have been used to evaluate the burnup of all US TRISO fuel compacts in the irradiation. The experimental burnup evaluations compare favorably with burnups predicted from physics simulations. Predicted burnups for UCO compacts range from 7.26 to 13.15 % fission per initial metal atom (FIMA) and 9.01 to 10.69 % FIMA for UO2 compacts. Measured burnup ranged from 7.3 to 13.1 % FIMA for UCO compacts and 8.5 to 10.6 % FIMA for UO2 compacts. Results from gamma emission computed tomography performed on compacts and graphite holders that reveal the distribution of different fission products in a component will also be discussed. Gamma tomography of graphite holders was also used to locate the position of TRISO fuel particles suspected of having silicon carbide layer failures that lead to in-pile cesium release.« less

Unusually conductive carbon-inherently conducting polymer (ICP) composites: Synthesis and characterization

NASA Astrophysics Data System (ADS)

Bourdo, Shawn Edward

Two groups of materials that have recently come to the forefront of research initiatives are carbon allotropes, especially nanotubes, and conducting polymers-more specifically inherently conducting polymers. The terms conducting polymers and inherently conducting polymers sometimes are used interchangeably without fully acknowledging a major difference in these terms. Conducting polymers (CPs) and inherently conducting polymers (ICPs) are both polymeric materials that conduct electricity, but the difference lies in how each of these materials conducts electricity. For CPs of the past, an electrically conductive filler such as metal particles, carbon black, or graphite would be blended into a polymer (insulator) allowing for the CP to carry an electric current. An ICP conducts electricity due to the intrinsic nature of its chemical structure. The two materials at the center of this research are graphite and polyaniline. For the first time, a composite between carbon allotropes (graphite) and an inherently conducting polymer (PANI) has exhibited an electrical conductivity greater than either of the two components. Both components have a plethora of potential applications and therefore the further investigation could lead to use of these composites in any number of technologies. Touted applications that use either conductive carbons or ICPs exist in a wide range of fields, including electromagnetic interference (EMI) shielding, radar evasion, low power rechargeable batteries, electrostatic dissipation (ESD) for anti-static textiles, electronic devices, light emitting diodes (LEDs), corrosion prevention, gas sensors, super capacitors, photovoltaic cells, and resistive heating. The main motivation for this research has been to investigate the connection between an observed increase in conductivity and structure of composites. Two main findings have resulted from the research as related to the observed increase in conductivity. The first was the structural evidence from Raman spectroscopy, X-ray diffraction, and thermal analysis suggesting a more crystalline graphite matrix due to intimate interactions with PANI that resulted in a charge transfer. Confirmation of charge transfer was observed through magnetic susceptibility, electron paramagnetic resonance, and temperature dependent electrical conductivity studies.

Carbon-Coated Core-Shell Fe-Cu Nanoparticles as Highly Active and Durable Electrocatalysts for a Zn-Air Battery.

PubMed

Nam, Gyutae; Park, Joohyuk; Choi, Min; Oh, Pilgun; Park, Suhyeon; Kim, Min Gyu; Park, Noejung; Cho, Jaephil; Lee, Jang-Soo

2015-06-23

Understanding the interaction between a catalyst and oxygen has been a key step in designing better electrocatalysts for the oxygen reduction reaction (ORR) as well as applying them in metal-air batteries and fuel cells. Alloying has been studied to finely tune the catalysts' electronic structures to afford proper binding affinities for oxygen. Herein, we synthesized a noble-metal-free and nanosized transition metal CuFe alloy encapsulated with a graphitic carbon shell as a highly efficient and durable electrocatalyst for the ORR in alkaline solution. Theoretical models and experimental results demonstrated that the CuFe alloy has a more moderate binding strength for oxygen molecules as well as the final product, OH(-), thus facilitating the oxygen reduction process. Furthermore, the nitrogen-doped graphitic carbon-coated layer, formed catalytically under the influence of iron, affords enhanced charge transfer during the oxygen reduction process and superior durability. These benefits were successfully confirmed by realizing the catalyst application in a mechanically rechargeable Zn-air battery.

In situ targeted MRI detection of Helicobacter pylori with stable magnetic graphitic nanocapsules

PubMed Central

Li, Yunjie; Hu, Xiaoxiao; Ding, Ding; Zou, Yuxiu; Xu, Yiting; Wang, Xuewei; Zhang, Yin; Chen, Long; Chen, Zhuo; Tan, Weihong

2017-01-01

Helicobacter pylori infection is implicated in the aetiology of many diseases. Despite numerous studies, a painless, fast and direct method for the in situ detection of H. pylori remains a challenge, mainly due to the strong acidic/enzymatic environment of the gastric mucosa. Herein, we report the use of stable magnetic graphitic nanocapsules (MGNs), for in situ targeted magnetic resonance imaging (MRI) detection of H. pylori. Several layers of graphene as the shell effectively protect the magnetic core from corrosion while retaining the superior contrast effect for MRI in the gastric environment. Boronic-polyethylene glycol molecules were synthesized and modified on the MGN surface for targeted MRI detection. In a mouse model of H. pylori-induced infection, H. pylori was specifically detected through both T2-weighted MR imaging and Raman gastric mucosa imaging using functionalized MGNs. These results indicated that enhancement of MRI using MGNs may be a promising diagnostic and bioimaging platform for very harsh conditions. PMID:28643777

Potential for on-orbit manufacture of large space structures using the pultrusion process

NASA Technical Reports Server (NTRS)

Wilson, Maywood L.; Macconochie, Ian O.; Johnson, Gary S.

1987-01-01

On-orbit manufacture of lightweight, high-strength, advanced-composite structures using the pultrusion process is proposed. This process is adaptable to a zero-gravity environment by using preimpregnated graphite-fiber reinforcement systems. The reinforcement material is preimpregnated with a high-performance thermoplastic resin at a ground station, is coiled on spools for compact storage, and is transported into Earth orbit. A pultrusion machine is installed in the Shuttle cargo bay from which very long lengths of the desired structure is fabricated on-orbit. Potential structural profiles include rods, angles, channels, hat sections, tubes, honeycomb-cored panels, and T, H, and I beams. A potential pultrudable thermoplastic/graphite composite material is presented as a model for determining the effect on Earth-to-orbit package density of an on-orbit manufacture, the package density is increased by 132 percent, and payload volume requirement is decreased by 56.3 percent. The fabrication method has the potential for on-orbit manufacture of structural members for space platforms, large space antennas, and long tethers.

Advanced Solar Panel Designs

NASA Technical Reports Server (NTRS)

Ralph, E. L.; Linder, E. B.

1995-01-01

Solar panel designs that utilize new high-efficiency solar cells and lightweight rigid panel technologies are described. The resulting designs increase the specific power (W/kg) achievable in the near-term and are well suited to meet the demands of higher performance small satellites (smallsats). Advanced solar panel designs have been developed and demonstrated on two NASA SBIR contracts at Applied Solar. The first used 19% efficient, large area (5.5 cm x 6.5 cm) GaAs/Ge solar cells with a lightweight rigid graphite epoxy isogrid substrate configuration. A 1,445 sq cm coupon was fabricated and tested to demonstrate 60 W/kg with a high potential of achieving 80 W/kg. The second panel design used new 22% efficiency, dual-junction GaInP2/GaAs/Ge solar cells combined with a lightweight aluminum core/graphite fiber mesh facesheet substrate. A 1,445 sq cm coupon was fabricated and tested to demonstrate 105 W/kg with the potential of achieving 115 W/kg.

In situ targeted MRI detection of Helicobacter pylori with stable magnetic graphitic nanocapsules

NASA Astrophysics Data System (ADS)

Li, Yunjie; Hu, Xiaoxiao; Ding, Ding; Zou, Yuxiu; Xu, Yiting; Wang, Xuewei; Zhang, Yin; Chen, Long; Chen, Zhuo; Tan, Weihong

2017-06-01

Helicobacter pylori infection is implicated in the aetiology of many diseases. Despite numerous studies, a painless, fast and direct method for the in situ detection of H. pylori remains a challenge, mainly due to the strong acidic/enzymatic environment of the gastric mucosa. Herein, we report the use of stable magnetic graphitic nanocapsules (MGNs), for in situ targeted magnetic resonance imaging (MRI) detection of H. pylori. Several layers of graphene as the shell effectively protect the magnetic core from corrosion while retaining the superior contrast effect for MRI in the gastric environment. Boronic-polyethylene glycol molecules were synthesized and modified on the MGN surface for targeted MRI detection. In a mouse model of H. pylori-induced infection, H. pylori was specifically detected through both T2-weighted MR imaging and Raman gastric mucosa imaging using functionalized MGNs. These results indicated that enhancement of MRI using MGNs may be a promising diagnostic and bioimaging platform for very harsh conditions.

AGR-2 and AGR-3/4 Release-to-Birth Ratio Data Analysis

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pham, Binh T.; Einerson, Jeffrey J.; Scates, Dawn M.

A series of Advanced Gas Reactor (AGR) irradiation tests is being conducted in the Advanced Test Reactor (ATR) at Idaho National Laboratory (INL) in support of development and qualification of tristructural isotropic (TRISO) low enriched fuel used in the High Temperature Gas-cooled Reactor (HTGR). Each AGR test consists of multiple independently controlled and monitored capsules containing fuel compacts placed in a graphite cylinder shrouded by a steel shell. These capsules are instrumented with thermocouples embedded in the graphite enabling temperature control. AGR configuration and irradiation conditions are based on prismatic HTGR technology that is distinguished primarily through use of heliummore » coolant, a low-power-density ceramic core capable of withstanding very high temperatures, and TRISO coated particle fuel. Thus, these tests provide valuable irradiation performance data to support fuel process development, qualify fuel for normal operating conditions, and support development and validation of fuel performance and fission product transport models and codes.« less

Thermal-hydraulic analysis of N Reactor graphite and shield cooling system performance

DOE Office of Scientific and Technical Information (OSTI.GOV)

Low, J.O.; Schmitt, B.E.

1988-02-01

A series of bounding (worst-case) calculations were performed using a detailed hydrodynamic RELAP5 model of the N Reactor graphite and shield cooling system (GSCS). These calculations were specifically aimed to answer issues raised by the Westinghouse Independent Safety Review (WISR) committee. These questions address the operability of the GSCS during a worst-case degraded-core accident that requires the GDCS to mitigate the consequences of the accident. An accident scenario previously developed was designed as the hydrogen-mitigation design-basis accident (HMDBA). Previous HMDBA heat transfer analysis,, using the TRUMP-BD code, was used to define the thermal boundary conditions that the GSDS may bemore » exposed to. These TRUMP/HMDBA analysis results were used to define the bounding operating conditions of the GSCS during the course of an HMDBA transient. Nominal and degraded GSCS scenarios were investigated using RELAP5 within or at the bounds of the HMDBA transient. 10 refs., 42 figs., 10 tabs.« less

Conformationally pre-organized and pH-responsive flat dendrons: synthesis and self-assembly at the liquid-solid interface.

PubMed

El Malah, Tamer; Ciesielski, Artur; Piot, Luc; Troyanov, Sergey I; Mueller, Uwe; Weidner, Steffen; Samorì, Paolo; Hecht, Stefan

2012-01-21

Efficient Cu-catalyzed 1,3-dipolar cycloaddition reactions have been used to prepare two series of three regioisomers of G-1 and G-2 poly(triazole-pyridine) dendrons. The G-1 and G-2 dendrons consist of branched yet conformationally pre-organized 2,6-bis(phenyl/pyridyl-1,2,3-triazol-4-yl)pyridine (BPTP) monomeric and trimeric cores, respectively, carrying one focal and either two or four peripheral alkyl side chains. In the solid state, the conformation and supramolecular organization were studied by means of a single crystal X-ray structure analysis of one derivative. At the liquid-solid interface, the self-assembly behavior was investigated by scanning tunneling microscopy (STM) on graphite surfaces. Based on the observed supramolecular organization, it appears that the subtle balance between conformational preferences inherent in the dendritic backbone on the one side and the adsorption and packing of the alkyl side chains on the graphite substrate on the other side dictate the overall structure formation in 2D.

Chemistry of anthracene-acetylene oligomers XXV: on-surface chirality of a self-assembled molecular network of a fan-blade-shaped anthracene-acetylene macrocycle with a long alkyl chain.

PubMed

Tsuya, Takuya; Iritani, Kohei; Tahara, Kazukuni; Tobe, Yoshito; Iwanaga, Tetsuo; Toyota, Shinji

2015-03-27

An anthracene cyclic dimer with two different linkers and a dodecyl group was synthesized by means of coupling reactions. The calculated structure had a planar macrocyclic π core and a linear alkyl chain. Scanning tunneling microscopy observations at the 1-phenyloctane/graphite interface revealed that the molecules formed a self-assembled monolayer that consisted of linear striped bright and dark bands. In each domain, the molecular network consisted of either Re or Si molecules that differed in the two-dimensional chirality about the macrocyclic faces, which led to a unique conglomerate-type self-assembly. The molecular packing mode and the conformation of the alkyl chains are discussed in terms of the intermolecular interactions and the interactions between the molecules and the graphite surface with the aid of MM3 simulations of a model system. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

IMPROVEMENTS IN THE THERMAL NEUTRON CALIBRATION UNIT, TNF2, AT LNMRI/IRD.

PubMed

Astuto, A; Fernandes, S S; Patrão, K C S; Fonseca, E S; Pereira, W W; Lopes, R T

2018-02-21

The standard thermal neutron flux unit, TNF2, in the Brazilian National Ionizing Radiation Metrology Laboratory was rebuilt. Fluence is still achieved by moderating of four 241Am-Be sources with 0.6 TBq each. The facility was again simulated and redesigned with graphite core and paraffin added graphite blocks surrounding it. Simulations using the MCNPX code on different geometric arrangements of moderator materials and neutron sources were performed. The resulting neutron fluence quality in terms of intensity, spectrum and cadmium ratio was evaluated. After this step, the system was assembled based on the results obtained from the simulations and measurements were performed with equipment existing in LNMRI/IRD and by simulated equipment. This work focuses on the characterization of a central chamber point and external points around the TNF2 in terms of neutron spectrum, fluence and ambient dose equivalent, H*(10). This system was validated with spectra measurements, fluence and H*(10) to ensure traceability.

Evaluation of a metal fuselage panel selectively reinforced with filamentary composites for space shuttle application

NASA Technical Reports Server (NTRS)

Wennhold, W. F.

1974-01-01

The use of high strength and modulus of advanced filamentary composites to reduce the structural weight of aerospace vehicles was investigated. Application of the technology to space shuttle components was the primary consideration. The mechanical properties for the boron/epoxy, graphite/epoxy, and polyimide data are presented. Structural testing of two compression panel components was conducted in a simulated space shuttle thermal environment. Results of the tests are analyzed.

Coated metal sintering carriers for fuel cell electrodes

DOEpatents

Donelson, Richard; Bryson, E. S.

1998-01-01

A carrier for conveying components of a fuel cell to be sintered through a sintering furnace. The carrier comprises a metal sheet coated with a water-based carbon paint, the water-based carbon paint comprising water, powdered graphite, an organic binder, a wetting agent, a dispersing agent and a defoaming agent.

Wall Conditioning Characterization in NSTX-U

NASA Astrophysics Data System (ADS)

Caron, D.; Soukhanovskii, V.; Scotti, F.; Weller, M.

2016-10-01

Impurities in tokamak plasmas can lead to disruptive instabilities due to radiative energy loss which impede access to high-confinements mode. One source of impurities in NSTX-U are water molecules trapped in graphite plasma facing components (PFCs), which make up the walls and divertors. Hydrogen and oxygen impurities are released into the plasma due to plasma surface interactions. Extreme ultraviolet (EUV) and visible spectrometers are used in conjunction with a residual gas analyzer (RGA) to characterize the source and amount of released impurities. A high resolution visible spectrometer measured H/D Balmer- α intensity ratio on the inner wall, the upper and lower divertors, and provided a hydrogen time history for shot-to-shot trends. The RGA provided partial pressure trends of masses 2 (H2) , 16 (O2) , and 18 (H2O). Trends of O VIII and C VI spectral line intensities from the core plasma were obtained from the EUV spectrometer. The trends are correlated with wall conditioning, namely helium glow discharge cleaning and boronization. Using these trends, impurity content monitoring and recommendations for wall conditioning can be implemented. Work supported by DOE under Contracts DE-AC52-07NA27344 and DE-AC02-09CH11466.

Recent advances in metal oxide-based electrode architecture design for electrochemical energy storage.

PubMed

Jiang, Jian; Li, Yuanyuan; Liu, Jinping; Huang, Xintang; Yuan, Changzhou; Lou, Xiong Wen David

2012-10-02

Metal oxide nanostructures are promising electrode materials for lithium-ion batteries and supercapacitors because of their high specific capacity/capacitance, typically 2-3 times higher than that of the carbon/graphite-based materials. However, their cycling stability and rate performance still can not meet the requirements of practical applications. It is therefore urgent to improve their overall device performance, which depends on not only the development of advanced electrode materials but also in a large part "how to design superior electrode architectures". In the article, we will review recent advances in strategies for advanced metal oxide-based hybrid nanostructure design, with the focus on the binder-free film/array electrodes. These binder-free electrodes, with the integration of unique merits of each component, can provide larger electrochemically active surface area, faster electron transport and superior ion diffusion, thus leading to substantially improved cycling and rate performance. Several recently emerged concepts of using ordered nanostructure arrays, synergetic core-shell structures, nanostructured current collectors, and flexible paper/textile electrodes will be highlighted, pointing out advantages and challenges where appropriate. Some future electrode design trends and directions are also discussed. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Visible-light-enhanced interactions of hydrogen sulfide with composites of zinc (oxy)hydroxide with graphite oxide and graphene.

PubMed

Seredych, Mykola; Mabayoje, Oluwaniyi; Bandosz, Teresa J

2012-01-17

Composites of zinc(oxy)hydroxide-graphite oxide and of zinc(oxy)hydroxide-graphene were used as adsorbents of hydrogen sulfide under ambient conditions. The initial and exhausted samples were characterized by XRD, FTIR, potentiometric titration, EDX, thermal analysis, and nitrogen adsorption. An increase in the amount of H(2)S adsorbed/oxidized on their surfaces in comparison with that of pure Zn(OH)(2) is linked to the structure of the composite, the relative number of terminal hydroxyls, and the kind of graphene-based phase used. Although terminal groups are activated by a photochemical process, the graphite oxide component owing to the chemical bonds with the zinc(oxy)hydroxide phase and conductive properties helps in electron transfer, leading to more efficient oxygen activation via the formation of superoxide ions. Elemental sulfur, zinc sulfide, sulfite, and sulfate are formed on the surface. The formation of sulfur compounds on the surface of zinc(oxy)hydroxide during the course of the breakthrough experiments and thus Zn(OH)(2)-ZnS heterojunctions can also contribute to the increased surface activity of our materials. The results show the superiority of graphite oxide in the formation of composites owing to its active surface chemistry and the possibility of interface bond formation, leading to an increase in the number of electron-transfer reactions. © 2011 American Chemical Society

Enhancing the oxidation resistance of graphite by applying an SiC coat with crack healing at an elevated temperature

NASA Astrophysics Data System (ADS)

Park, Jae-Won; Kim, Eung-Seon; Kim, Jae-Un; Kim, Yootaek; Windes, William E.

2016-08-01

The potential of reducing the oxidation of the supporting graphite components during normal and/or accident conditions in the Very High Temperature Reactor (VHTR) design has been studied. In this work efforts have been made to slow the oxidation process of the graphite with a thin SiC coating (∼ 10 μm). Upon heating at ≥ 1173 K in air, the spallations and cracks were formed in the dense columnar structured SiC coating layer grown on the graphite with a functionally gradient electron beam physical vapor deposition (EB-PVD. In accordance with the formations of these defects, the sample was vigorously oxidized, leaving only the SiC coating layer. Then, efforts were made to heal the surface defects using additional EB-PVD with ion beam bombardment and chemical vapor deposition (CVD). The EB-PVD did not effectively heal the cracks. But, the CVD was more appropriate for crack healing, likely due to its excellent crack line filling capability with a high density and high aspect ratio. It took ∼ 34 min for the 20% weight loss of the CVD crack healed sample in the oxidation test with annealing at 1173 K, while it took ∼ 8 min for the EB-PVD coated sample, which means it took ∼4 times longer at 1173 K for the same weight reduction in this experimental set-up.

Solid sampling determination of magnesium in lithium niobate crystals by graphite furnace atomic absorption spectrometry

NASA Astrophysics Data System (ADS)

Dravecz, Gabriella; Laczai, Nikoletta; Hajdara, Ivett; Bencs, László

2016-12-01

The vaporization/atomization processes of Mg in high-resolution continuum source graphite furnace atomic absorption spectrometry (HR-CS-GFAAS) were investigated by evaporating solid (powder) samples of lithium niobate (LiNbO3) optical single crystals doped with various amounts of Mg in a transversally heated graphite atomizer (THGA). Optimal analytical conditions were attained by using the Mg I 215.4353 nm secondary spectral line. An optimal pyrolysis temperature of 1500 °C was found for Mg, while the compromise atomization temperature in THGAs (2400 °C) was applied for analyte vaporization. The calibration was performed against solid (powered) lithium niobate crystal standards. The standards were prepared with exactly known Mg content via solid state fusion of the oxide components of the matrix and analyte. The correlation coefficient (R value) of the linear calibration was not worse than 0.9992. The calibration curves were linear in the dopant concentration range of interest (0.74-7.25 mg/g Mg), when dosing 3-10 mg of the powder samples into the graphite sample insertion boats. The Mg content of the studied 19 samples was in the range of 1.69-4.13 mg/g. The precision of the method was better than 6.3%. The accuracy of the results was verified by means of flame atomic absorption spectrometry with solution sample introduction after digestion of several crystal samples.

Evaluation of flawed composite structural components under static and cyclic loading. [fatigue life of graphite-epoxy composite materials

NASA Technical Reports Server (NTRS)

Porter, T. R.

1979-01-01

The effects of initial defects on the fatigue and fracture response of graphite-epoxy composite laminates are presented. The structural laminates investigated were a typical angle ply laminate, a polar/hoop wound pressure vessel laminate, and a typical engine fan blade laminate. Defects investigated were full and half penetration circular holes, full and half penetration slits, and countersink holes. The effects of the defect size and type on the static fracture strength, fatigue performance, and residual static strength are shown as well as the results of loadings on damage propagation in composite laminates. The data obtained were used to define proof test levels as a qualification procedure in composite structure subjected to cyclic loading.

Hindered Glymes for Graphite-Compatible Electrolytes.

PubMed

Shanmukaraj, Devaraj; Grugeon, Sylvie; Laruelle, Stephane; Armand, Michel

2015-08-24

Organic carbonate mixtures are used almost exclusively as lithium battery electrolyte solvents. The linear compounds (dimethyl carbonate, diethyl carbonate, ethyl methyl carbonate) act mainly as thinner for the more viscous and high-melting ethylene carbonate but are the least stable component and have low flash points; these are serious handicaps for lifetime and safety. Polyethers (glymes) are useful co-solvents, but all formerly known representatives solvate Li(+) strongly enough to co-intercalate in the graphite negative electrode and exfoliate it. We have put forward a new electrolyte composition comprising a polyether to which a bulky tert-butyl group is attached ("hindered glyme"), thus completely preventing co-intercalation while maintaining good conductivity. This alkyl-carbonate-free electrolyte shows remarkable cycle efficiency of the graphite electrode, not only at room temperature, but also at 50 and 70 °C in the presence of lithium bis(fluorosulfonimide). The two-ethylene-bridge hindered glyme has a high boiling point and a flash point of 80 °C, a considerable advantage for safety. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Study to investigate design, fabrication and test of low cost concepts for large hybrid composite helicopter fuselage, phase 1

NASA Technical Reports Server (NTRS)

Adams, K. M.; Lucas, J. J.

1975-01-01

The development of a frame/stringer/skin fabrication technique for composite airframe construction was studied as a low cost approach to the manufacture of large helicopter airframe components. A center cabin aluminum airframe section of the Sikorsky CH-53D helicopter was selected for evaluation as a composite structure. The design, as developed, is composed of a woven KEVLAR-49/epoxy skin and graphite/epoxy frames and stringers. To support the selection of this specific design concept a materials study was conducted to develop and select a cure compatible graphite and KEVLAR-49/epoxy resin system, and a foam system capable of maintaining shape and integrity under the processing conditions established. The materials selected were, Narmco 5209/Thornel T-300 graphite, Narmco 5209/KEVLAR-49 woven fabric, and Stathane 8747 polyurethane foam. Eight specimens were fabricated, representative of the frame, stringer, and splice joint attachments. Evaluation of the results of analysis and test indicate that design predictions are good to excellent except for some conservatism of the complex frame splice.

Complex structure of the carbon arc discharge for synthesis of nanotubes

DOE PAGES

Vekselman, V.; Feurer, M.; Huang, T.; ...

2017-06-06

Comprehensive non-invasive spectroscopic techniques and electrical measurements of the carbon arc revealed two distinguishable plasma synthesis regions in the radial direction normal to the arc axis. These regions, which are defined as the arc core and the arc periphery, are shown to have very different compositions of carbon species with different densities and temperatures. The colder arc periphery is dominated by carbon diatomic molecules (C 2), which are in the minority in the composition of the hot arc core. These differences are due to a highly non-uniform distribution of the arc current, which is mainly conducted through the arc coremore » populated with carbon atoms and ions. Therefore, the ablation of the graphite anode is governed by the arc core, while the formation of carbon molecules occurs in the colder arc periphery. Furthermore, this result is consistent with previous predictions that the plasma environment in the arc periphery is suitable for synthesis of carbon nanotubes.« less

The Chornobyl accident revisited, part II: The state of the nuclear fuel located within the Chornobyl Sarcophagus

DOE Office of Scientific and Technical Information (OSTI.GOV)

Borovol, A.A.; Sich, A.R.

1995-10-01

Approximately 135 tonnes of the 190.3-tonne initial core fuel load ({approx}71%) at Chornobyl Unit 4 melted and flowed into the lower regions of the reactor building to form various kinds of the now-solidified lava-like fuel-containing materials (LFCMs) or corium. The results of radiochemical analyses reveal that only 5% of the LFCM inventory of Ru-106 remains, whereas, surprisingly, 35% of the LFCM inventory of Cs-137 remains. Moreover, the results of these analyses support the fact that little if any of the 5020 tonnes of various materials (dropped from helicopters during the active phase of the accident in an attempt to smothermore » the burning graphite) ever made it into the core shaft, where the bulk of the core was located. The results appear to support earlier Western source-term estimates that significantly more volatile radionuclides may have been released as a result of the accident.« less

The Chornobyl accident revisited, Part II: The state of the nuclear fuel located within the Chornobyl sarcophagus

DOE Office of Scientific and Technical Information (OSTI.GOV)

Borovoi, A.A.; Sich, A.R.

1995-01-01

Approximately 135 tonnes of the 190.3-tonne initial core fuel load ({approx}71%) at Chernobyl Unit 4 melted and flowed into the lower regions of the reactor building to form various kinds of the now-solidified lava-like fuel-containing materials (LFCMs) or corium. The results of radiochemical analyses reveal that only 5% of the LFCM inventory of Ru-106 remains. whereas, surprisingly, 35% of the LFCM inventory of Cs-137 remains. Moreover, the results of these analyses support the fact that little if any of the 5020 tonnes of various materials (dropped from helicopters during the active phase of the accident in an attempt to smothermore » the burning graphite) ever made it into the core shaft, where the bulk of the core was located. The results appear to support earlier Western source-term estimates that significantly more volatile radionuclides may have been released as a result of the accident. 37 refs., 13 figs., 7 tabs.« less

Synthesis of carbon core–shell pore structures and their performance as supercapacitors

DOE PAGES

Ariyanto, Teguh; Dyatkin, Boris; Zhang, Gui-Rong; ...

2015-07-15

High-power supercapacitors require excellent electrolyte mobility within the pore network and high electrical conductivity for maximum capacitance and efficiency. Achieving high power typically requires sacrificing energy densities, as the latter demands a high specific surface area and narrow porosity that impedes ion transport. Here, we present a novel solution for this optimization problem: a nanostructured core–shell carbonaceous material that exhibits a microporous carbon core surrounded by a mesoporous, graphitic shell. The tunable synthesis parameters yielded a structure that features either a sharp or a gradual transition between the core and shell sections. Electrochemical supercapacitor testing using organic electrolyte revealed thatmore » these novel core–shell materials outperform carbons with homogeneous pore structures. The hybrid core–shell materials showed a combination of good capacitance retention, typical for the carbon present in the shell and high specific capacitance, typical for the core material. These materials achieved power densities in excess of 40 kW kg -1 at energy densities reaching 27 Wh kg -1.« less

Complex structure of the carbon arc discharge for synthesis of nanotubes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Vekselman, V.; Feurer, M.; Huang, T.

Comprehensive non-invasive spectroscopic techniques and electrical measurements of the carbon arc revealed two distinguishable plasma synthesis regions in the radial direction normal to the arc axis. These regions, which are defined as the arc core and the arc periphery, are shown to have very different compositions of carbon species with different densities and temperatures. The colder arc periphery is dominated by carbon diatomic molecules (C 2), which are in the minority in the composition of the hot arc core. These differences are due to a highly non-uniform distribution of the arc current, which is mainly conducted through the arc coremore » populated with carbon atoms and ions. Therefore, the ablation of the graphite anode is governed by the arc core, while the formation of carbon molecules occurs in the colder arc periphery. Furthermore, this result is consistent with previous predictions that the plasma environment in the arc periphery is suitable for synthesis of carbon nanotubes.« less

Combustion-derived substances in deep basins of Puget Sound: historical inputs from fossil fuel and biomass combustion.

PubMed

Kuo, Li-Jung; Louchouarn, Patrick; Herbert, Bruce E; Brandenberger, Jill M; Wade, Terry L; Crecelius, Eric

2011-04-01

Reconstructions of 250 years historical inputs of two distinct types of black carbon (soot/graphitic black carbon (GBC) and char-BC) were conducted on sediment cores from two basins of the Puget Sound, WA. Signatures of polycyclic aromatic hydrocarbons (PAHs) were also used to support the historical reconstructions of BC to this system. Down-core maxima in GBC and combustion-derived PAHs occurred in the 1940s in the cores from the Puget Sound Main Basin, whereas in Hood Canal such peak was observed in the 1970s, showing basin-specific differences in inputs of combustion byproducts. This system showed relatively higher inputs from softwood combustion than the northeastern U.S. The historical variations in char-BC concentrations were consistent with shifts in climate indices, suggesting an influence of climate oscillations on wildfire events. Environmental loading of combustion byproducts thus appears as a complex function of urbanization, fuel usage, combustion technology, environmental policies, and climate conditions. Copyright © 2010 Elsevier Ltd. All rights reserved.

Plasma-wall interaction data needs critical to a Burning Core Experiment (BCX)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1985-11-01

The Division of Development and Technology has sponsored a four day US-Japan workshop ''Plasma-Wall Interaction Data Needs Critical to a Burning Core Experiment (BCX)'', held at Sandia National Laboratories, Livermore, California on June 24 to 27, 1985. The workshop, which brought together fifty scientists and engineers from the United States, Japan, Germany, and Canada, considered the plasma-material interaction and high heat flux (PMI/HHF) issues for the next generation of magnetic fusion energy devices, the Burning Core Experiment (BCX). Materials options were ranked, and a strategy for future PMI/HHF research was formulated. The foundation for international collaboration and coordination of thismore » research was also established. This volume contains the last three of the five technical sessions. The first of the three is on plasma materials interaction issues, the second is on research facilities and the third is from smaller working group meetings on graphite, beryllium, advanced materials and future collaborations.« less

Residual-strength tests of L-1011 vertical fin components after 10 and 20 years of simulated flight service

NASA Technical Reports Server (NTRS)

Lopez, O. F.

1984-01-01

Part of the NASA/ACEE Program was to determine the effect of long-term durability testing on the residual strength of graphite-epoxy cover panel and spar components of the Lockheed L-1011 aircraft vertical stabilizer. The results of these residual strength tests are presented herein. The structural behavior and failure mode of both cover panel and spar components were addressed, and the test results obtained were compared with the static test results generated by Lockheed. The effect of damage on one of the spar specimens was described.

Advanced technology for extended endurance alkaline fuel cells

NASA Technical Reports Server (NTRS)

Sheibley, D. W.; Martin, R. A.

1987-01-01

Advanced components have been developed for alkaline fuel cells with a view to the satisfaction of NASA Space Station design requirements for extended endurance. The components include a platinum-on-carbon catalyst anode, a potassium titanate-bonded electrolyte matrix, a lightweight graphite electrolyte reservoir plate, a gold-plated nickel-perforated foil electrode substrate, a polyphenylene sulfide cell edge frame material, and a nonmagnesium cooler concept. When incorporated into the alkaline fuel cell unit, these components are expected to yield regenerative operation in a low earth orbit Space Station with a design life greater than 5 years.

Mode I Toughness Measurements of Core/Facesheet Bonds in Honeycomb Sandwich Structures

NASA Technical Reports Server (NTRS)

Nettles, Alan T.; Ratcliffe, James G.

2006-01-01

Composite sandwich structures will be used in many future applications in aerospace, marine and offshore industries due to the fact that the strength and stiffness to mass ratios surpass any other structural type. Sandwich structure also offers advantages over traditional stiffened panels such as ease of manufacturing and repair. During the last three decades, sandwich structure has been used extensively for secondary structure in aircraft (fuselage floors, rudders and radome structure). Sandwich structure is also used as primary structure in rotorcraft, the most common example being the trailing edge of rotor blades. As with other types of composite construction, sandwich structure exhibits several types of failure mode such as facesheet wrinkling, core crushing and sandwich buckling. Facesheet/core debonding has also been observed in the marine and aerospace industry. During this failure mode, peel stresses applied to an existing facesheet/core debond or an interface low in toughness, results in the facesheet being peeled from the core material, possibly leading to a significant loss in structural integrity of the sandwich panel. In an incident during a test on a liquid hydrogen fuel tank of the X-33 prototype vehicle, the outer graphite/epoxy facesheet and honeycomb core became debonded from the inner facesheet along significant areas, leading to failure of the tank. As a consequence of the accident; significant efforts were made to characterize the toughness of the facesheet/core bond. Currently, the only standardized method available for assessing the quality of the facesheet/core interface is the climbing drum peel test (ASTM D1781). During this test a sandwich beam is removed from a panel and the lip of one of the facesheets is attached to a drum, as shown in Fig. 1. The drum is then rotated along the sandwich beam, causing the facesheet to peel from the core. This method has two major drawbacks. First, it is not possible to obtain quantitative fracture data from the test and so the results can only be used in a qualitative manner. Second, only sandwich structure with thin facesheets can be tested (to facilitate wrapping of the facesheet around the climbing drum). In recognition of the need for a more quantitative facesheet/core fracture test, several workers have devised experimental techniques for characterizing the toughness of the facesheet/core interface. In all of these cases, the tests are designed to yield a mode I-dominated fracture toughness of the facesheet/core interface in a manner similar to that used to determine mode I fracture toughness of composite laminates. In the current work, a modified double cantilever beam is used to measure the mode I-dominated fracture toughness of the interface in a sandwich consisting of glass/phenolic honeycomb core reinforced with graphite epoxy facesheets. Two specimen configurations were tested as shown in Fig 2. The first configuration consisted of reinforcing the facesheets with aluminum blocks (Fig. 2a). In the second configuration unreinforced specimens were tested (Fig. 2b). Climbing drum peel tests were also conducted to compare the fracture behavior observed between this test and the modified double cantilever beam. This paper outlines the test procedures and data reduction strategies used to compute fracture toughness values from the tests. The effect of specimen reinforcement on fracture toughness of the facesheet/core interface is discussed.

International Classification of Functioning, Disability and Health Core Sets for cerebral palsy, autism spectrum disorder, and attention-deficit-hyperactivity disorder.

PubMed

Schiariti, Verónica; Mahdi, Soheil; Bölte, Sven

2018-05-30

Capturing functional information is crucial in childhood disability. The International Classification of Functioning, Disability and Health (ICF) Core Sets promote assessments of functional abilities and disabilities in clinical practice regarding circumscribed diagnoses. However, the specificity of ICF Core Sets for childhood-onset disabilities has been doubted. This study aimed to identify content commonalities and differences among the ICF Core Sets for cerebral palsy (CP), and the newly developed Core Sets for autism spectrum disorder (ASD) and attention-deficit-hyperactivity disorder (ADHD). The categories within each Core Set were aggregated at the ICF component and chapter levels. Content comparison was conducted using descriptive analyses. The activities and participation component of the ICF was the most covered across all Core Sets. Main differences included representation of ICF components and coverage of ICF chapters within each component. CP included all ICF components, while ADHD and ASD predominantly focused on activities and participation. Environmental factors were highly represented in the ADHD Core Sets (40.5%) compared to the ASD (28%) and CP (27%) Core Sets. International Classification of Functioning, Disability and Health Core Sets for CP, ASD, and ADHD capture both common but also unique functional information, showing the importance of creating condition-specific, ICF-based tools to build functional profiles of individuals with childhood-onset disabilities. The International Classification of Functioning, Disability and Health (ICF) Core Sets for cerebral palsy (CP), autism spectrum disorder (ASD), and attention-deficit-hyperactivity disorder (ADHD) include unique functional information. The ICF-based tools for CP, ASD, and ADHD differ in terms of representation and coverage of ICF components and ICF chapters. Representation of environmental factors uniquely influences functioning and disability across ICF Core Sets for CP, ASD and ADHD. © 2018 Mac Keith Press.

Development and test of advanced composite components. Center Directors discretionary fund program

NASA Technical Reports Server (NTRS)

Faile, G.; Hollis, R.; Ledbetter, F.; Maldonado, J.; Sledd, J.; Stuckey, J.; Waggoner, G.; Engler, E.

1985-01-01

This report describes the design, analysis, fabrication, and test of a complex bathtub fitting. Graphite fibers in an epoxy matrix were utilized in manufacturing of 11 components representing four different design and layup concepts. Design allowables were developed for use in the final stress analysis. Strain gage measurements were taken throughout the static load test and correlation of test and analysis data were performed, yielding good understanding of the material behavior and instrumentation requirements for future applications.

Advanced rotary engine components utilizing fiber reinforced Mg castings

NASA Technical Reports Server (NTRS)

Goddard, D.; Whitman, W.; Pumphrey, R.; Lee, C.-M.

1986-01-01

Under a two-phase program sponsored by NASA, the technology for producing advanced rotary engine components utilizing graphite fiber-reinforced magnesium alloy casting is being developed. In Phase I, the successful casting of a simulated intermediate housing was demonstrated. In Phase II, the goal is to produce an operating rotor housing. The effort involves generation of a material property data base, optimization of parameters, and development of wear- and corrosion-resistant cast surfaces and surface coatings. Results to date are described.

Assembly & Metrology of First Wall Components of SST-1

NASA Astrophysics Data System (ADS)

Parekh, Tejas; Santra, Prosenjit; Biswas, Prabal; Patel, Hiteshkumar; Paravastu, Yuvakiran; Jaiswal, Snehal; Chauhan, Pradeep; Babu, Gattu Ramesh; A, Arun Prakash; Bhavsar, Dhaval; Raval, Dilip C.; Khan, Ziauddin; Pradhan, Subrata

2017-04-01

First Wall Components (FWC) of SST-1 tokamak, which are in the immediate vicinity of plasma comprises of limiters, divertors, baffles, passive stabilizers are designed to operate long duration (1000 s) discharges of elongated plasma. All FWC consists of a copper alloy heat sink modules with SS cooling tubes brazed onto it, graphite tiles acting as armour material facing the plasma, and are mounted to the vacuum vessels with suitable Inconel support structures at ring & port locations. The FWC are very recently assembled and commissioned successfully inside the vacuum vessel of SST-1 undergoing a meticulous planning of assembly sequence, quality checks at every stage of the assembly process. This paper will present the metrology aspects & procedure of each FWC, both outside the vacuum vessel, and inside the vessel, assembly tolerances, tools, equipment and jig/fixtures, used at each stage of assembly, starting from location of support bases on vessel rings, fixing of copper modules on support structures, around 3800 graphite tile mounting on 136 copper modules with proper tightening torques, till final toroidal and poloidal geometry of the in-vessel components are obtained within acceptable limits, also ensuring electrical continuity of passive stabilizers to form a closed saddle loop, electrical isolation of passive stabilizers from vacuum vessel.

Impact Testing and Simulation of Composite Airframe Structures

NASA Technical Reports Server (NTRS)

Jackson, Karen E.; Littell, Justin D.; Horta, Lucas G.; Annett, Martin S.; Fasanella, Edwin L.; Seal, Michael D., II

2014-01-01

Dynamic tests were performed at NASA Langley Research Center on composite airframe structural components of increasing complexity to evaluate their energy absorption behavior when subjected to impact loading. A second objective was to assess the capabilities of predicting the dynamic response of composite airframe structures, including damage initiation and progression, using a state-of-the-art nonlinear, explicit transient dynamic finite element code, LS-DYNA. The test specimens were extracted from a previously tested composite prototype fuselage section developed and manufactured by Sikorsky Aircraft Corporation under the US Army's Survivable Affordable Repairable Airframe Program (SARAP). Laminate characterization testing was conducted in tension and compression. In addition, dynamic impact tests were performed on several components, including I-beams, T-sections, and cruciform sections. Finally, tests were conducted on two full-scale components including a subfloor section and a framed fuselage section. These tests included a modal vibration and longitudinal impact test of the subfloor section and a quasi-static, modal vibration, and vertical drop test of the framed fuselage section. Most of the test articles were manufactured of graphite unidirectional tape composite with a thermoplastic resin system. However, the framed fuselage section was constructed primarily of a plain weave graphite fabric material with a thermoset resin system. Test data were collected from instrumentation such as accelerometers and strain gages and from full-field photogrammetry.

Nurses' fidelity to theory-based core components when implementing Family Health Conversations - a qualitative inquiry.

PubMed

Östlund, Ulrika; Bäckström, Britt; Lindh, Viveca; Sundin, Karin; Saveman, Britt-Inger

2015-09-01

A family systems nursing intervention, Family Health Conversation, has been developed in Sweden by adapting the Calgary Family Assessment and Intervention Models and the Illness Beliefs Model. The intervention has several theoretical assumptions, and one way translate the theory into practice is to identify core components. This may produce higher levels of fidelity to the intervention. Besides information about how to implement an intervention in accordance to how it was developed, evaluating whether it was actually implemented as intended is important. Accordingly, we describe the nurses' fidelity to the identified core components of Family Health Conversation. Six nurses, working in alternating pairs, conducted Family Health Conversations with seven families in which a family member younger than 65 had suffered a stroke. The intervention contained a series of three-1-hour conversations held at 2-3 week intervals. The nurses followed a conversation structure based on 12 core components identified from theoretical assumptions. The transcripts of the 21 conversations were analysed using manifest qualitative content analysis with a deductive approach. The 'core components' seemed to be useful even if nurses' fidelity varied among the core components. Some components were followed relatively well, but others were not. This indicates that the process for achieving fidelity to the intervention can be improved, and that it is necessary for nurses to continually learn theory and to practise family systems nursing. We suggest this can be accomplished through reflections, role play and training on the core components. Furthermore, as in this study, joint reflections on how the core components have been implemented can lead to deeper understanding and knowledge of how Family Health Conversation can be delivered as intended. © 2014 Nordic College of Caring Science.

Formative Processes of a Sliding Zone in Pelitic Schist - Implications of Microscopic Analyses on High-quality Drilled Cores

NASA Astrophysics Data System (ADS)

Yamasaki, S.; Chigira, M.

2009-04-01

Pelitic schist has been known to be easily deformed by gravitational force to form characteristic topographic and geologic features, but little is known about how they develop. This is mainly due to the fact that deformed politic schist is so fragile that it could not be obtained from subsurface without disturbance. We analyzed high-quality undisturbed cores obtained by using a sophisticated drilling technique from two typical pelitic schist landslide sites in Japan. We made analyses on physical, chemical, mineralogical properties and observations from mesoscopic to microscopic rock textures of these cores and found that a special layering of rock-forming minerals determines the locations of shearing by gravity and that there is specific water-rock interaction processes in pelitic schist. Pelitic schist consists of thinly alternating beds of black layers and quartz-rich layers, and a black layer has numerous microscopic layers containing abundant pyrite and graphite grains (pyrite-graphite layers). Many of the black layers were observed to have microfractures connected to open cracks, suggesting that relatively thick, continuous black layers are easily sheared to form an incipient sliding layer. Thus unevenly distributed pyrite-graphite layers likely to determine the potential location of microscopic slip in a rock mass. Shear displacement along black layers occurs unevenly, depending upon the microscopic heterogeneity in mineral composition as well as undulating shape of the layers. Open micro-cracks nearly perpendicular to the schistosity were commonly observed in quartz-rich layers in contact with black layers, suggesting that the shearing occurred with heterogeneous displacements along the black layer and that it occurred under the low confining pressure. This is in the incipient stage of a fracture zone. When shearing occurs along two thick neighboring black layers, the rock in between would be fractured, rotated and pulverized. In some cases, quartz-rich layers were fractured in a brittle manner and their fragments were rearranged to form micro-folds. Rocks are thus pulverized with multiple shear surfaces. Incipient fracture zones and their surroundings have many voids because they are made under low confining pressures near the ground surface, so oxidizing surface water easily percolates through them. Oxidizing water reacts with pyrite which is contained in pelitic schist, producing sulfuric acid through. The rocks therefore become deteriorated by the water-rock interaction and would be easily deformed. Such a combination of the physical processes of deformation and fracturing and the chemical process of weathering develop a sliding zone.

Experimentally determined sulfur isotope fractionation between metal and silicate and implications for planetary differentiation

NASA Astrophysics Data System (ADS)

Labidi, J.; Shahar, A.; Le Losq, C.; Hillgren, V. J.; Mysen, B. O.; Farquhar, J.

2016-02-01

The Earth's mantle displays a subchondritic 34S/32S ratio. Sulfur is a moderately siderophile element (i.e. iron-loving), and its partitioning into the Earth's core may have left such a distinctive isotope composition on the terrestrial mantle. In order to constrain the sulfur isotope fractionation occurring during core-mantle differentiation, high-pressure and temperature experiments were conducted with synthetic mixtures of metal and silicate melts. With the purpose to identify the mechanism(s) responsible for the S isotope fractionations, we performed our experiments in different capsules - namely, graphite and boron nitride capsules - and thus at different fO2, with varying major element chemistry of the silicate and metal fractions. The S isotope fractionations Δ34Smetal-silicate of equilibrated metal alloys versus silicate melts is +0.2 ± 0.1‰ in a boron-free and aluminum-poor system quenched at 1-1.5 GPa and 1650 °C. The isotope fractionation increases linearly with increasing boron and aluminum content, up to +1.4 ± 0.2‰, and is observed to be independent of the silicon abundance as well as of the fO2 over ∼3.5 log units of variations explored here. The isotope fractionations are also independent of the graphite or nitride saturation of the metal. Only the melt structural changes associated with aluminum and boron concentration in silicate melts have been observed to affect the strength of sulfur bonding. These results establish that the structure of silicate melts has a direct influence on the S2- average bonding strengths. These results can be interpreted in the context of planetary differentiation. Indeed, the structural environments of silicate evolve strongly with pressure. For example, the aluminum, iron or silicon coordination numbers increase under the effect of pressure. Consequently, based on our observations, the sulfur-bonding environment is likely to be affected. In this scheme, we tentatively hypothesize that S isotope fractionations between the silicate mantle and metallic core of terrestrial planetary bodies would depend on the average pressure at which their core-mantle differentiation occurred.

Core Intervention Components: Identifying and Operationalizing What Makes Programs Work. ASPE Research Brief

ERIC Educational Resources Information Center

Blase, Karen; Fixsen, Dean

2013-01-01

This brief is part of a series that explores key implementation considerations. It focuses on the importance of identifying, operationalizing, and implementing the "core components" of evidence-based and evidence-informed interventions that likely are critical to producing positive outcomes. The brief offers a definition of "core components",…

Coated metal sintering carriers for fuel cell electrodes

DOEpatents

Donelson, R.; Bryson, E.S.

1998-11-10

A carrier is described for conveying components of a fuel cell to be sintered through a sintering furnace. The carrier comprises a metal sheet coated with a water-based carbon paint, the water-based carbon paint comprising water, powdered graphite, an organic binder, a wetting agent, a dispersing agent and a defoaming agent.

Some observations on the fracture of austempered ductile iron

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fan, Z.K.; Smallman, R.E.

1994-07-15

There is extensive work on the fracture of steel with ferrite or/and austenite structure, but little on crack propagation in austempered ductile iron (ADI) whose microstructure also comprises austenite and ferrite (in the form of bainitic ferrite) but with graphite nodules in the matrix. Because of its good combination of wear resistance and toughness, and its low density and low cost (compared with forge steel), ADI has been widely used for various kinds of engineering components, such as gears, crankshafts, vehicle components, sprockets, cutting and digging tools etc. The matrix of ADI can withstand a certain amount of deformation beforemore » fracture during tensile or impact testing; for example, the elongation of ADI (grade 1050/700/7 to ASTM Standard) can reach 7--10% during tensile testing. However, the graphite nodules in the matrix cannot deform and hence are barriers to matrix deformation and give rise to crack initiation. In addition, carbides may precipitate in the bainitic ferrite laths or at the ferrite/austenite interfaces and these may also influence the fracture of ADI and produce characteristic features.« less

Vacuum Plasma Spray Forming of Tungsten Lorentz Force Accelerator Components

NASA Technical Reports Server (NTRS)

Zimmerman, Frank R.

2004-01-01

The Vacuum Plasma Spray (VPS) Laboratory at NASA's Marshall Space Flight Center, working with the Jet Propulsion Laboratory, has developed and demonstrated a fabrication technique using the VPS process to form anode and cathode sections for a Lorentz force accelerator made from tungsten. Lorentz force accelerators are an attractive form of electric propulsion that provides continuous, high-efficiency propulsion at useful power levels for such applications as orbit transfers or deep space missions. The VPS process is used to deposit refractory metals such as tungsten onto a graphite mandrel of the desired shape. Because tungsten is reactive at high temperatures, it is thermally sprayed in an inert environment where the plasma gun melts and deposits the molten metal powder onto a mandrel. A three-axis robot inside the chamber controls the motion of the plasma spray torch. A graphite mandrel acts as a male mold, forming the required contour and dimensions for the inside surface of the anode or cathode of the accelerator. This paper describes the processing techniques, design considerations, and process development associated with the VPS forming of Lorentz force accelerator components.

NASA's Earth Science Data Systems

NASA Technical Reports Server (NTRS)

Ramapriyan, H. K.

2015-01-01

NASA's Earth Science Data Systems (ESDS) Program has evolved over the last two decades, and currently has several core and community components. Core components provide the basic operational capabilities to process, archive, manage and distribute data from NASA missions. Community components provide a path for peer-reviewed research in Earth Science Informatics to feed into the evolution of the core components. The Earth Observing System Data and Information System (EOSDIS) is a core component consisting of twelve Distributed Active Archive Centers (DAACs) and eight Science Investigator-led Processing Systems spread across the U.S. The presentation covers how the ESDS Program continues to evolve and benefits from as well as contributes to advances in Earth Science Informatics.

Advanced divertor configurations with large flux expansion

NASA Astrophysics Data System (ADS)

Soukhanovskii, V. A.; Bell, R. E.; Diallo, A.; Gerhardt, S.; Kaye, S.; Kolemen, E.; LeBlanc, B. P.; McLean, A.; Menard, J. E.; Paul, S. F.; Podesta, M.; Raman, R.; Ryutov, D. D.; Scotti, F.; Kaita, R.; Maingi, R.; Mueller, D. M.; Roquemore, A. L.; Reimerdes, H.; Canal, G. P.; Labit, B.; Vijvers, W.; Coda, S.; Duval, B. P.; Morgan, T.; Zielinski, J.; De Temmerman, G.; Tal, B.

2013-07-01

Experimental studies of the novel snowflake divertor concept (D. Ryutov, Phys. Plasmas 14 (2007) 064502) performed in the NSTX and TCV tokamaks are reviewed in this paper. The snowflake divertor enables power sharing between divertor strike points, as well as the divertor plasma-wetted area, effective connection length and divertor volumetric power loss to increase beyond those in the standard divertor, potentially reducing heat flux and plasma temperature at the target. It also enables higher magnetic shear inside the separatrix, potentially affecting pedestal MHD stability. Experimental results from NSTX and TCV confirm the predicted properties of the snowflake divertor. In the NSTX, a large spherical tokamak with a compact divertor and lithium-coated graphite plasma-facing components (PFCs), the snowflake divertor operation led to reduced core and pedestal impurity concentration, as well as re-appearance of Type I ELMs that were suppressed in standard divertor H-mode discharges. In the divertor, an otherwise inaccessible partial detachment of the outer strike point with an up to 50% increase in divertor radiation and a peak divertor heat flux reduction from 3-7 MW/m2 to 0.5-1 MW/m2 was achieved. Impulsive heat fluxes due to Type-I ELMs were significantly dissipated in the high magnetic flux expansion region. In the TCV, a medium-size tokamak with graphite PFCs, several advantageous snowflake divertor features (cf. the standard divertor) have been demonstrated: an unchanged L-H power threshold, enhanced stability of the peeling-ballooning modes in the pedestal region (and generally an extended second stability region), as well as an H-mode pedestal regime with reduced (×2-3) Type I ELM frequency and slightly increased (20-30%) normalized ELM energy, resulting in a favorable average energy loss comparison to the standard divertor. In the divertor, ELM power partitioning between snowflake divertor strike points was demonstrated. The NSTX and TCV experiments are providing support for the snowflake divertor as a viable solution for the outstanding tokamak plasma-material interface issues.

Constraining the Dust Opacity Law in Three Small and Isolated Molecular Clouds

DOE Office of Scientific and Technical Information (OSTI.GOV)

Webb, K. A.; Thanjavur, K.; Di Francesco, J.

Density profiles of isolated cores derived from thermal dust continuum emission rely on models of dust properties, such as mass opacity, that are poorly constrained. With complementary measures from near-infrared extinction maps, we can assess the reliability of commonly used dust models. In this work, we compare Herschel -derived maps of the optical depth with equivalent maps derived from CFHT WIRCAM near-infrared observations for three isolated cores: CB 68, L 429, and L 1552. We assess the dust opacities provided from four models: OH1a, OH5a, Orm1, and Orm4. Although the consistency of the models differs between the three sources, themore » results suggest that the optical properties of dust in the envelopes of the cores are best described by either silicate and bare graphite grains (e.g., Orm1) or carbonaceous grains with some coagulation and either thin or no ice mantles (e.g., OH5a). None of the models, however, individually produced the most consistent optical depth maps for every source. The results suggest that either the dust in the cores is not well-described by any one dust property model, the application of the dust models cannot be extended beyond the very center of the cores, or more complex SED fitting functions are necessary.« less

Mass Conservation in Modeling Moisture Diffusion in Multi-Layer Carbon Composite Structures

NASA Technical Reports Server (NTRS)

Nurge, Mark A.; Youngquist, Robert C.; Starr, Stanley O.

2009-01-01

Moisture diffusion in multi-layer carbon composite structures is difficult to model using finite difference methods due to the discontinuity in concentrations between adjacent layers of differing materials. Applying a mass conserving approach at these boundaries proved to be effective at accurately predicting moisture uptake for a sample exposed to a fixed temperature and relative humidity. Details of the model developed are presented and compared with actual moisture uptake data gathered over 130 days from a graphite epoxy composite sandwich coupon with a Rohacell foam core.

Isotope heat source simulator for testing of space power systems

NASA Technical Reports Server (NTRS)

Prok, G. M.; Smith, R. B.

1973-01-01

A reliable isotope heat source simulator was designed for use in a Brayton power system. This simulator is composed of an electrically heated tungsten wire which is wound around a boron nitride core and enclosed in a graphite jacket. Simulator testing was performed at the expected operating temperature of the Brayton power system. Endurance testing for 5012 hours was followed by cycling the simulator temperature. The integrity of this simulator was maintained throughout testing. Alumina beads served as a diffusion barrier to prevent interaction between the tungsten heater and boron nitride core. The simulator was designed to maintain a surface temperature of 1311 to 1366 K (1900 to 2000 F) with a power input of approximately 400 watts. The design concept and the materials used in the simulator make possible man different geometries. This flexibility increases its potential use.

Surface Anchoring of Nematic Phase on Carbon Nanotubes: Nanostructure of Ultra-High Temperature Materials

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ogale, Amod A

2012-04-27

Nuclear energy is a dependable and economical source of electricity. Because fuel supply sources are available domestically, nuclear energy can be a strong domestic industry that can reduce dependence on foreign energy sources. Commercial nuclear power plants have extensive security measures to protect the facility from intruders [1]. However, additional research efforts are needed to increase the inherent process safety of nuclear energy plants to protect the public in the event of a reactor malfunction. The next generation nuclear plant (NGNP) is envisioned to utilize a very high temperature reactor (VHTR) design with an operating temperature of 650-1000°C [2]. Onemore » of the most important safety design requirements for this reactor is that it must be inherently safe, i.e., the reactor must shut down safely in the event that the coolant flow is interrupted [2]. This next-generation Gen IV reactor must operate in an inherently safe mode where the off-normal temperatures may reach 1500°C due to coolant-flow interruption. Metallic alloys used currently in reactor internals will melt at such temperatures. Structural materials that will not melt at such ultra-high temperatures are carbon/graphtic fibers and carbon-matrix composites. Graphite does not have a measurable melting point; it is known to sublime starting about 3300°C. However, neutron radiation-damage effects on carbon fibers are poorly understood. Therefore, the goal of this project is to obtain a fundamental understanding of the role of nanotexture on the properties of resulting carbon fibers and their neutron-damage characteristics. Although polygranular graphite has been used in nuclear environment for almost fifty years, it is not suitable for structural applications because it do not possess adequate strength, stiffness, or toughness that is required of structural components such as reaction control-rods, upper plenum shroud, and lower core-support plate [2,3]. For structural purposes, composites consisting of strong carbon fibers embedded in a carbon matrix are needed. Such carbon/carbon (C/C) composites have been used in aerospace industry to produce missile nose cones, space shuttle leading edge, and aircraft brake-pads. However, radiation-tolerance of such materials is not adequately known because only limited radiation studies have been performed on C/C composites, which suggest that pitch-based carbon fibers have better dimensional stability than that of polyacrylonitrile (PAN) based fibers [4]. The thermodynamically-stable state of graphitic crystalline packing of carbon atoms derived from mesophase pitch leads to a greater stability during neutron irradiation [5]. The specific objectives of this project were: (i) to generating novel carbonaceous nanostructures, (ii) measure extent of graphitic crystallinity and the extent of anisotropy, and (iii) collaborate with the Carbon Materials group at Oak Ridge National Lab to have neutron irradiation studies and post-irradiation examinations conducted on the carbon fibers produced in this research project.« less

Evaluation of Neutron Radiography Reactor LEU-Core Start-Up Measurements

DOE PAGES

Bess, John D.; Maddock, Thomas L.; Smolinski, Andrew T.; ...

2014-11-04

Benchmark models were developed to evaluate the cold-critical start-up measurements performed during the fresh core reload of the Neutron Radiography (NRAD) reactor with Low Enriched Uranium (LEU) fuel. Experiments include criticality, control-rod worth measurements, shutdown margin, and excess reactivity for four core loadings with 56, 60, 62, and 64 fuel elements. The worth of four graphite reflector block assemblies and an empty dry tube used for experiment irradiations were also measured and evaluated for the 60-fuel-element core configuration. Dominant uncertainties in the experimental k eff come from uncertainties in the manganese content and impurities in the stainless steel fuel claddingmore » as well as the 236U and erbium poison content in the fuel matrix. Calculations with MCNP5 and ENDF/B-VII.0 neutron nuclear data are approximately 1.4% (9σ) greater than the benchmark model eigenvalues, which is commonly seen in Monte Carlo simulations of other TRIGA reactors. Simulations of the worth measurements are within the 2σ uncertainty for most of the benchmark experiment worth values. The complete benchmark evaluation details are available in the 2014 edition of the International Handbook of Evaluated Reactor Physics Benchmark Experiments.« less

Evaluation of Neutron Radiography Reactor LEU-Core Start-Up Measurements

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bess, John D.; Maddock, Thomas L.; Smolinski, Andrew T.

Benchmark models were developed to evaluate the cold-critical start-up measurements performed during the fresh core reload of the Neutron Radiography (NRAD) reactor with Low Enriched Uranium (LEU) fuel. Experiments include criticality, control-rod worth measurements, shutdown margin, and excess reactivity for four core loadings with 56, 60, 62, and 64 fuel elements. The worth of four graphite reflector block assemblies and an empty dry tube used for experiment irradiations were also measured and evaluated for the 60-fuel-element core configuration. Dominant uncertainties in the experimental k eff come from uncertainties in the manganese content and impurities in the stainless steel fuel claddingmore » as well as the 236U and erbium poison content in the fuel matrix. Calculations with MCNP5 and ENDF/B-VII.0 neutron nuclear data are approximately 1.4% (9σ) greater than the benchmark model eigenvalues, which is commonly seen in Monte Carlo simulations of other TRIGA reactors. Simulations of the worth measurements are within the 2σ uncertainty for most of the benchmark experiment worth values. The complete benchmark evaluation details are available in the 2014 edition of the International Handbook of Evaluated Reactor Physics Benchmark Experiments.« less

Microscale Variations in the 13C Content of the Murchison Meteorite

NASA Astrophysics Data System (ADS)

Romanek, C.; Gibson, E.; Socki, R.; Burkett, P. J.

1993-07-01

Heretofore unresolved micrometer-scale carbon isotopic zonation in the Murchison meteorite (CM3) is documented using a laser microprobe mass spectrometer. High-resolution isotopic gradients and heterogeneities between high- and low-temperature textural components help to constrain the processes that have shaped the physiochemical character of this carbonaceous chondrite. Previous bulk samples of Murchison yield an average delta ^13C value of - 5.7 +/- 4.3 per mil [1] while individual components such as micrometer-sized mineral separates (e.g., C(sub)graphite , C(sub)diamond, and SiC), acid- soluble extracts (e.g., CaCO3 and polar hydrocarbons), and insoluble residues (e.g., polycyclic aromatic hydrocarbons) are isotopically diverse (delta ^13C of -1000 to 29,000 per mil). While these studies shed light on the origin and occurrence of C-bearing phases, they fail to constrain intrinsic spatial isotopic heterogeneities. The power of the laser microprobe lies in the fact that in situ chemical and isotopic compositions are measured simultaneously for volatiles extracted from extremely small sample volumes (i.e., 0.025 mm^3 for 5 wt% C). Nd-YAG laser irradiation (1.06 micrometers) is directed onto texturally defined targets (>=50 micrometers wide) from which solid material is volatilized. Condensible gaseous phases are collected in a variable-temperature cold trap while the more volatile species (CH4 and CO) are quantified using an ion trap mass spectrometer. All gases are then converted to CO2 in a CuO furnace (containing Pt) held at 600 degrees C and analyzed for carbon and oxygen isotope ratios. The concentration and isotopic composition of condensed species are determined by stepped sublimation of unstable components and conversion to CO2. Preliminary isotopic analyses of the total volatile C content (i.e., bulk microanalysis) from distinct textural components at least 0.05 mm^3 in volume are described below. The most ^13C-depleted components within Murchison reside within the cores of chondrules and/or aggregates. Three typical cores were analyzed, with an average bulk composition of -21.0 +/- 0.5 per mil (n = 7). The bulk ^13C content of C-bearing phases increases monotonically outward in all directions within 100 to 200 micrometers of each core (i.e., within dust mantles) to a constant matrix value of -12.5 +/- 0.5 per mil (n = 40). The most isotopically enriched textural component found in Murchison is a regolith breccia clast without chondrules that has an average bulk delta ^13C value of -10 +/-0.5 per mil (n = 5). The clast was originally detectable only under cathodoluminescence, but with the aid of the laser microprobe it is now characterized by an unusually low volatile content and enriched ^13C composition. In general, the most isotopically enriched components also produce the lowest yield of gas (normalized to sampling volume). This trend of isotopic enrichment from chondrule to matrix has been documented previously for oxygen isotopes in carbonaceous chondrites [2]. Carbon isotopic gradients and heterogeneities within Murchison reflect fundamental changes in the chemical speciation and/or isotopic content of the main C-bearing components (i.e., acid-soluble and insoluble hydrocarbon fractions) within the meteorite. Perhaps core interiors and dust mantles are responding to environmental changes reflected in the speciation of C-bearing species distributed within the solar nebula or the parent body. Inverse correlations between hydrocarbon atomic mass number and ^13C abundance in the acid-soluble [3] and insoluble residues [4] of Murchison have been documented. Alternatively, micrometer-scale isotopic gradients may reflect fundamental changes in the isotopic composition of individual C-bearing species through time. Enrichments may represent kinetically controlled processes related to hydrocarbon formation. In contrast, assuming an equilibrium fractionation mechanism, isotopic enrichments may record a temperature-dependent component to hydrocarbon delta ^13C values. These opposing alternatives will be discussed in light of the isotopic composition of individual C-bearing components volatilized from tightly constrained sample volumes within Murchison. References: [1] Kerridge J. F. (1985) GCA, 49, 1707-1714. [2] Clayton R. N. and Mayeda T. K. (1984) EPSL, 67, 151-161. [3] Yuen G. et al. (1984) Nature, 307, 254. [4] Gilmour I. et al. (1991) Meteoritics, 26, 337-338.

Strain and dynamic measurements using fiber optic sensors embedded into graphite/epoxy tubes

NASA Technical Reports Server (NTRS)

Dehart, D. W.; Doederlein, T.; Koury, J.; Rogowski, R. S.; Heyman, J. S.; Holben, M. S., Jr.

1989-01-01

Graphite/epoxy tubes were fabricated with embedded optical fibers to evaluate the feasibility of monitoring strains with a fiber optic technique. Resistance strain gauges were attached to the tubes to measure strain at four locations along the tube for comparison with the fiber optic sensors. Both static and dynamic strain measurements were made with excellent agreement between the embedded fiber optic strain sensor and the strain gauges. Strain measurements of 10(exp -7) can be detected with the optical phase locked loop (OPLL) system using optical fiber. Because of their light weight, compatibility with composites, immunity to electromagnetic interference, and based on the static and dynamic results obtained, fiber optic sensors embedded in composites may be useful as the sensing component of smart structures.

Three-dimensional direct laser written graphitic electrical contacts to randomly distributed components

NASA Astrophysics Data System (ADS)

Dorin, Bryce; Parkinson, Patrick; Scully, Patricia

2018-04-01

The development of cost-effective electrical packaging for randomly distributed micro/nano-scale devices is a widely recognized challenge for fabrication technologies. Three-dimensional direct laser writing (DLW) has been proposed as a solution to this challenge, and has enabled the creation of rapid and low resistance graphitic wires within commercial polyimide substrates. In this work, we utilize the DLW technique to electrically contact three fully encapsulated and randomly positioned light-emitting diodes (LEDs) in a one-step process. The resolution of the contacts is in the order of 20 μ m, with an average circuit resistance of 29 ± 18 kΩ per LED contacted. The speed and simplicity of this technique is promising to meet the needs of future microelectronics and device packaging.

Compositional Variation of Tourmaline from the Paleoproterozoic Bhukia Gold Prospect of Aravalli Supergroup, Western India: Implications for the Provenance and Gold Metallogeny

NASA Astrophysics Data System (ADS)

Mukherjee, R.; Venkatesh, A. S.; Fareeduddin, F.

2016-12-01

Bhukia is a unique gold prospect in terms of its host lithologies such as albitite and carbonates with respect to greenstone hosted Archean gold deposits from India. Tourmaline occurs along with apatite, magnetite, graphite, chalcopyrite and gold-sulfide association in Bhukia gold prospect preserve geochemical record of changing physico-chemical conditions during its growth. Tourmalinization is one of the distinct hydrothermal alterations present in the study area. Chemical composition of two varieties of tourmalines presents as significant amounts within albitite and carbonate rocks from Bhukia gold prospect. EPMA analysis of two varieties of tourmalines viz. 1) rounded to sub-rounded, euhedral, green colored tourmalines and 2) elongated, zoned, brown colored tourmalines unlocks their chemical compositions as well as variations from core to rim. In some albitite litho-units, tourmaline occurs as major constituents (>15%), present as layers, termed as tourmalinites. Al-Fe-Mg and Na/ (Na+Ca) vs Fe/ (Fe+Mg) suggests that tourmalines from the Bhukia gold prospect are Mg-rich dravite to Fe-rich schrol in composition. Tourmalines present within the albitite rocks show variations in iron and sodium content from core to rim whereas similarity exist from core to rim in case of carbonate rocks. Presence of albite confirms the role of Na-rich fluids during the formation of tourmalines. Tourmalines present in Bhukia gold prospect is mainly influenced by boron influx and the source may be boron bearing hydrothermal fluid or boron bearing minerals. Dewatering of original un-metamorphosed rock during progressive metamorphism may remove boron from the metasedimentary rocks. Due to the mobile nature of boron, it dispersed and mixed with hydrothermal fluids and alumina that is required for the formation of the tourmaline might have been leached from metasedimentary rocks present in Bhukia gold prospect. Presence of hydrothermal alterations such as tourmalinization and albitization along with Au-Cu-graphite-magnetite association suggest this deposit to be an IOCG (Iron oxide copper gold) type.

Boundary pressure of inter-connection of Fe-Ni-S melt in olivine based on in-situ X-ray tomography: Implication to core formation in asteroids

NASA Astrophysics Data System (ADS)

Terasaki, H.; Urakawa, S.; Uesugi, K.; Nakatsuka, A.; Funakoshi, K.; Ohtani, E.

2011-12-01

Interconnectivity of Fe-alloy melt in crystalline silicates is important property for the core formation mechanism in planetary interior. In previous studies, the interconnectivity of Fe-alloy melt has been studied based on textural observation of recovered samples from high pressure and temperature. However, there is no observation under high pressure and temperature. We have developed 80-ton uni-axial press for X-ray computed micro-tomography (X-CT) and performed X-CT measurement under high pressure (Urakawa et al. 2010). Here we report X-CT measurement of Fe-Ni-S melt in crystalline olivine and interconnectivity of the melt up to 3.5 GPa and 1273 K. X-CT measurements were carried out at BL20B2 beamline, SPring-8 synchrotron facility. The sample was powder mixture of Fe-Ni-S and olivine, which was enclosed in graphite capsule. Heating was performed using a cylindrical graphite furnace. Pressure was generated using opposed toroidal-shape WC anvil. The uni-axial press was set on the rotational stage and X-ray radiography image of the sample was collected using CCD camera from 0°to 180°with 0.3° step. 3-D image of the sample was obtained by reconstructing the 2-D radiography image. The 3-D CT image shows that the size of the Fe-Ni-S melt increased significantly compared to that before melting below 2.5 GPa, suggesting that the melt was interconnected in olivine crystals. On the other hand, 3-D texture of the sample at 3.5 GPa did not show difference from that before melting. Therefore, the boundary of inter-connection of Fe-Ni-S melt is likely to locate between 2.5 and 3.5 GPa. This result is important application for the core formation mechanism especially in small bodies, such as differentiated asteroids.

HTR-PROTEUS Pebble Bed Experimental Program Cores 1, 1A, 2, and 3: Hexagonal Close Packing with a 1:2 Moderator-to-Fuel Pebble Ratio

DOE Office of Scientific and Technical Information (OSTI.GOV)

John D. Bess; Barbara H. Dolphin; James W. Sterbentz

2013-03-01

In its deployment as a pebble bed reactor (PBR) critical facility from 1992 to 1996, the PROTEUS facility was designated as HTR-PROTEUS. This experimental program was performed as part of an International Atomic Energy Agency (IAEA) Coordinated Research Project (CRP) on the Validation of Safety Related Physics Calculations for Low Enriched HTGRs. Within this project, critical experiments were conducted for graphite moderated LEU systems to determine core reactivity, flux and power profiles, reaction-rate ratios, the worth of control rods, both in-core and reflector based, the worth of burnable poisons, kinetic parameters, and the effects of moisture ingress on these parameters.more » Four benchmark experiments were evaluated in this report: Cores 1, 1A, 2, and 3. These core configurations represent the hexagonal close packing (HCP) configurations of the HTR-PROTEUS experiment with a moderator-to-fuel pebble ratio of 1:2. Core 1 represents the only configuration utilizing ZEBRA control rods. Cores 1A, 2, and 3 use withdrawable, hollow, stainless steel control rods. Cores 1 and 1A are similar except for the use of different control rods; Core 1A also has one less layer of pebbles (21 layers instead of 22). Core 2 retains the first 16 layers of pebbles from Cores 1 and 1A and has 16 layers of moderator pebbles stacked above the fueled layers. Core 3 retains the first 17 layers of pebbles but has polyethylene rods inserted between pebbles to simulate water ingress. The additional partial pebble layer (layer 18) for Core 3 was not included as it was used for core operations and not the reported critical configuration. Cores 1, 1A, 2, and 3 were determined to be acceptable benchmark experiments.« less

HTR-PROTEUS Pebble Bed Experimental Program Cores 1, 1A, 2, and 3: Hexagonal Close Packing with a 1:2 Moderator-to-Fuel Pebble Ratio

DOE Office of Scientific and Technical Information (OSTI.GOV)

John D. Bess; Barbara H. Dolphin; James W. Sterbentz

2012-03-01

In its deployment as a pebble bed reactor (PBR) critical facility from 1992 to 1996, the PROTEUS facility was designated as HTR-PROTEUS. This experimental program was performed as part of an International Atomic Energy Agency (IAEA) Coordinated Research Project (CRP) on the Validation of Safety Related Physics Calculations for Low Enriched HTGRs. Within this project, critical experiments were conducted for graphite moderated LEU systems to determine core reactivity, flux and power profiles, reaction-rate ratios, the worth of control rods, both in-core and reflector based, the worth of burnable poisons, kinetic parameters, and the effects of moisture ingress on these parameters.more » Four benchmark experiments were evaluated in this report: Cores 1, 1A, 2, and 3. These core configurations represent the hexagonal close packing (HCP) configurations of the HTR-PROTEUS experiment with a moderator-to-fuel pebble ratio of 1:2. Core 1 represents the only configuration utilizing ZEBRA control rods. Cores 1A, 2, and 3 use withdrawable, hollow, stainless steel control rods. Cores 1 and 1A are similar except for the use of different control rods; Core 1A also has one less layer of pebbles (21 layers instead of 22). Core 2 retains the first 16 layers of pebbles from Cores 1 and 1A and has 16 layers of moderator pebbles stacked above the fueled layers. Core 3 retains the first 17 layers of pebbles but has polyethylene rods inserted between pebbles to simulate water ingress. The additional partial pebble layer (layer 18) for Core 3 was not included as it was used for core operations and not the reported critical configuration. Cores 1, 1A, 2, and 3 were determined to be acceptable benchmark experiments.« less

In situ observation of quasimelting of diamond and reversible graphite-diamond phase transformations.

PubMed

Huang, J Y

2007-08-01

Because of technique difficulties in achieving the extreme high-pressure and high-temperature (HPHT) simultaneously, direct observation of the structures of carbon at extreme HPHT conditions has not been possible. Banhart and Ajayan discovered remarkably that carbon onions can act as nanoscopic pressure cells to generate high pressures. By heating carbon onions to approximately 700 degrees C and under electron beam irradiation, the graphite-to-diamond transformation was observed in situ by transmission electron microscopy (TEM). However, the highest achievable temperature in a TEM heating holder is less than 1000 degrees C. Here we report that, by using carbon nanotubes as heaters and carbon onions as high-pressure cells, temperatures higher than 2000 degrees C and pressures higher than 40 GPa were achieved simultaneously in carbon onions. At such HPHT conditions and facilitated by electron beam irradiation, the diamond formed in the carbon onion cores frequently changed its shape, size, orientation, and internal structure and moved like a fluid, implying that it was in a quasimelting state. The fluctuation between the solid phase of diamond and the fluid/amorphous phase of diamond-like carbon, and the changes of the shape, size, and orientation of the solid diamond, were attributed to the dynamic crystallization of diamond crystal from the quasimolten state and the dynamic graphite-diamond phase transformations. Our discovery offers unprecedented opportunities to studying the nanostructures of carbon at extreme conditions in situ and at an atomic scale.

Upshot of natural graphite inclusion on the performance of porous conducting carbon fiber paper in a polymer electrolyte membrane fuel cell

NASA Astrophysics Data System (ADS)

Kaushal, Shweta; Negi, Praveen; Sahu, A. K.; Dhakate, S. R.

2017-09-01

Porous conducting carbon fiber paper (PCCFP) is one of the vital component of the gas diffusion layer (GDL) in a fuel cell. This PCCFP serves as the most suitable substrate for the GDL due to its electrical conductivity, mechanical properties, and porosity. In this approach, carbon fiber composite papers were developed by incorporating different fractions of natural graphite (NG) in the matrix phase, i.e. Phenolic resin, and using the combined process of paper making and carbon-carbon composite formation technique. These prepared samples were then heat treated at 1800 °C in an inert atmosphere. The effect of natural graphite incorporation was ascertained by characterizing porous carbon paper by various techniques i.e. X-ray diffraction, Raman spectroscopy, Scanning electron microscopy, electrical and mechanical properties, and I-V performance in a unit fuel cell assembly. The inclusion of NG certainly enhance the properties of the carbon matrix as well as improving the conductive path of carbon fibers. In this study addition of 1 wt.% of natural graphite demonstrated a significant improvement in the electrical conductivity and performance of PCCFP and resulted in the improvement of power density from 361-563 mW cm-2. This paper reports that the uniform dispersion of NG was able to generate a maximum number of macrosize pores in the carbon paper that strengthened the flexural modulus from 4 to 12 GPa without compromising the porosity required for the GDL.

X-33 LH2 Tank Failure Investigation Findings

NASA Technical Reports Server (NTRS)

Niedermeyer, Mindy; Clinton, R. G., Jr. (Technical Monitor)

2000-01-01

This presentation focuses on the tank history, test objectives, failure description, investigation and conclusions. The test objectives include verify structural integrity at 105% expected flight load limit varying the following parameters: cryogenic temperature; internal pressure; and mechanical loading. The Failure description includes structural component of the aft body, quad-lobe design, and sandwich - honeycomb graphite epoxy construction.

Method for producing dustless graphite spheres from waste graphite fines

DOEpatents

Pappano, Peter J [Oak Ridge, TN; Rogers, Michael R [Clinton, TN

2012-05-08

A method for producing graphite spheres from graphite fines by charging a quantity of spherical media into a rotatable cylindrical overcoater, charging a quantity of graphite fines into the overcoater thereby forming a first mixture of spherical media and graphite fines, rotating the overcoater at a speed such that the first mixture climbs the wall of the overcoater before rolling back down to the bottom thereby forming a second mixture of spherical media, graphite fines, and graphite spheres, removing the second mixture from the overcoater, sieving the second mixture to separate graphite spheres, charging the first mixture back into the overcoater, charging an additional quantity of graphite fines into the overcoater, adjusting processing parameters like overcoater dimensions, graphite fines charge, overcoater rotation speed, overcoater angle of rotation, and overcoater time of rotation, before repeating the steps until graphite fines are converted to graphite spheres.

Core losses of a permanent magnet synchronous motor with an amorphous stator core under inverter and sinusoidal excitations

NASA Astrophysics Data System (ADS)

Yao, Atsushi; Sugimoto, Takaya; Odawara, Shunya; Fujisaki, Keisuke

2018-05-01

We report core loss properties of permanent magnet synchronous motors (PMSM) with amorphous magnetic materials (AMM) core under inverter and sinusoidal excitations. To discuss the core loss properties of AMM core, a comparison with non-oriented (NO) core is also performed. In addition, based on both experiments and numerical simulations, we estimate higher (time and space) harmonic components of the core losses under inverter and sinusoidal excitations. The core losses of PMSM are reduced by about 59% using AMM stator core instead of NO core under sinusoidal excitation. We show that the average decrease obtained by using AMM instead of NO in the stator core is about 94% in time harmonic components.

10 CFR 55.41 - Written examination: Operators.

Code of Federal Regulations, 2011 CFR

2011-01-01

... coefficients, and poison effects. (2) General design features of the core, including core structure, fuel elements, control rods, core instrumentation, and coolant flow. (3) Mechanical components and design... changes, and operating limitations and reasons for these operating characteristics. (6) Design, components...

10 CFR 55.41 - Written examination: Operators.

Code of Federal Regulations, 2010 CFR

2010-01-01

... coefficients, and poison effects. (2) General design features of the core, including core structure, fuel elements, control rods, core instrumentation, and coolant flow. (3) Mechanical components and design... changes, and operating limitations and reasons for these operating characteristics. (6) Design, components...

10 CFR 55.41 - Written examination: Operators.

Code of Federal Regulations, 2012 CFR

2012-01-01

... coefficients, and poison effects. (2) General design features of the core, including core structure, fuel elements, control rods, core instrumentation, and coolant flow. (3) Mechanical components and design... changes, and operating limitations and reasons for these operating characteristics. (6) Design, components...

Are TiC Grains a Carrier of the 21 Micron Emission Band Observed around Post-Asymptotic Giant Branch Objects?

NASA Astrophysics Data System (ADS)

Chigai, Takeshi; Yamamoto, Tetsuo; Kaito, Chihiro; Kimura, Yuki

2003-04-01

The carrier of the 21 μm band observed in post-asymptotic giant branch (post-AGB) stars is examined. We analyze the infrared spectra of the TiC clusters measured by von Helden et al. in 2000 and determine the absorption efficiency Q in the 21 μm band. Using Q, we estimate the Ti/Si abundance ratios needed to realize the flux ratios of the 21 and 11 μm emission observed in the infrared spectra of the post-AGB stars exhibiting both 21 and 11 μm emission. In view of the nature of the TiC condensation by which TiC grains are quickly mantled by graphite, we calculate the emission spectra of the graphite-coated TiC grains and other possible types of core-mantle grains and compare with the observed spectra. Both the abundance and condensation considerations strongly suggest that TiC is an implausible carrier of the observed infrared 21 μm feature around carbon-rich post-AGB stars.

Carbon Isotopic Heterogeneity of Graphite in the San Juan Mass of the Campo Del Cielo IAB Iron Meteorite

NASA Technical Reports Server (NTRS)

Maruoka, T.; Kurat, G.; Zinner, E.; Varela, M. E.; Ametrano, S. J.

2003-01-01

The origin of IAB iron meteorites is still a matter of debate. It is generally believed that iron meteorites originated from molten cores in small planetesimals because the fractionation trend of trace elements (e.g., Ir, Ge, Ga, etc. vs. Ni) for most iron meteorites can be more or less explained by fractional crystallization from metal melts. However, this process cannot produce trace element characteristics of the IAB (and other) iron meteorites. To explain these trace element abundance patterns, several models have been proposed. Although most of these models require a high temperature, clear evidence has recently been obtained for a sub-solidus formation of IAB iron meteorites from noble gas analyses. Moreover, heterogeneous distributions of some trace elements in metal and other phases also suggest a low temperature origin of at least some IAB iron meteorites. Here we use the carbon isotopic compositions of graphite to constrain the origin of IAB iron meteorites. Our data confirm a possible low temperature origin of IAB iron meteorites.

Hydrogen-Treated Rutile TiO2 Shell in Graphite-Core Structure as a Negative Electrode for High-Performance Vanadium Redox Flow Batteries.

PubMed

Vázquez-Galván, Javier; Flox, Cristina; Fàbrega, Cristian; Ventosa, Edgar; Parra, Andres; Andreu, Teresa; Morante, Joan Ramón

2017-05-09

Hydrogen-treated TiO 2 as an electrocatalyst has shown to boost the capacity of high-performance all-vanadium redox flow batteries (VRFBs) as a simple and eco-friendly strategy. The graphite felt-based GF@TiO 2 :H electrode is able to inhibit the hydrogen evolution reaction (HER), which is a critical barrier for operating at high rate for long-term cycling in VRFBs. Significant improvements in charge/discharge and electron-transfer processes for the V 3+ /V 2+ reaction on the surface of reduced TiO 2 were achieved as a consequence of the formation of oxygen functional groups and oxygen vacancies in the lattice structure. Key performance indicators of VRFB have been improved, such as high capability rates and electrolyte-utilization ratios (82 % at 200 mA cm -2 ). Additionally, high coulombic efficiencies (ca. 100 % up to the 96th cycle, afterwards >97 %) were obtained, demonstrating the feasibility of achieving long-term stability. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Experimental investigation of graphite/polyimide sandwich panels in edgewise compression. M.S. Thesis

NASA Technical Reports Server (NTRS)

Camarda, C. J.

1980-01-01

The local and general buckling of graphite/polyimide sandwich panels simply supported along all four edges and loaded in uniaxial edgewise compression is investigated. Material properties of sandwich panel constituents (adhesive and facings) were determined from flatwise tension and sandwich beam flexure tests. An adhesive bond study resulted in the selection of a suitable cure cycle for FM 34 polyimide film adhesive and, a bonding technique using a liquid cell edge version of that adhesive resulted in considerable mass savings. Tensile and compressive material properties of the facings, quasiisotropic, symmetric, laminates (0, +45,90,-45)s of Celion/PMR-15, were determined at 116, R.T., and 589 K (-250, R.T., and 600 F) usng the sandwich beam flexure test method. Results indicate the Gr/PI is a usable structural material for short term use at temperatures as high as 589 K (600 F). Buckling specimens were 1006.5 sq cm. 156 sq in., had quasiisotropic symmetric facings (0, + or - 45,90)s and a glass/polyimide honeycomb core (HRH-327-3/8-4).

Lunar and Planetary Science XXXV: Effects of Impacts: Shock and Awe

NASA Technical Reports Server (NTRS)

Kyte, F. T.; Koeberl, C.

2004-01-01

This document discusses the following topics: Zircon as a Shock Indicator in Impactites of Drill Core Yaxcopoil-1, Chicxulub Impact Structure, Mexico; Experimental Investigation of Shock Effects in a Metapelitic Granulite; Experimental Reproduction of Shock Veins in Single-Crystal Minerals; Post-Shock Crystal-Plastic Processes in Quartz from Crystalline Target Rocks of the Charlevoix Impact Structure; Shock Reequilibration of Fluid Inclusions; How Does Tektite Glass Lose Its Water?; Assessing the Role of Anhydrite in the KT Mass Extinction: Hints from Shock-loading Experiments; A Mineralogical and Geochemical Study of the Nonmarine Permian/Triassic Boundary in the Southern Karoo Basin, South Africa; Extraterrestrial Chromium in the Permian-Triassic Boundary at Graphite Peak, Antarctica; Magnetic Fe,Si,Al-rich Impact Spherules from the P-T Boundary Layer at Graphite Peak, Antarctica; A Newly Recognized Late Archean Impact Spherule Layer in the Reivilo Formation, Griqualand West Basin, South Africa; Initial Cr-Isotopic and Iridium Measurements of Concentrates from Late Eocene Cpx-Spherule Deposits; An Ordinary Chondrite Impactor Composition for the Bosumtwi Impact Structure, Ghana, West Africa: Discussion of Siderophile Element Contents and Os and Cr Isotope Data.

Nitrogen–doped graphitized carbon shell encapsulated NiFe nanoparticles: A highly durable oxygen evolution catalyst

DOE Office of Scientific and Technical Information (OSTI.GOV)

Du, Lei; Luo, Langli; Feng, Zhenxing

Oxygen evolution reaction (OER) plays a crucial role in various energy conversion devices such as water electrolyzers and metal–air batteries. Precious metal catalysts such as Ir, Ru and their oxides are usually used for enhancing reaction kinetics but are limited by their scarce resource. The challenges associated with alternative non–precious metal catalysts such as transition metal oxides and (oxy)hydroxides etc. are their low electronic conductivity and durability. Herein, we report a highly active (360 mV overpotential at 10 mA cm–2GEO) and durable (no degradation after 20000 cycles) OER catalyst derived from bimetallic metal–organic frameworks (MOFs) precursors. This catalyst consists ofmore » NiFe nanoparticles encapsulated by nitrogen–doped graphitized carbon shells. The electron-donation/deviation from Fe and tuned electronic structure of metal cores by Ni are revealed to be primary contributors to the enhanced OER activity, whereas N concentration contributes negligibly. We further demonstrated that the structure and morphology of encapsulating carbon shells, which are the key factors influencing the durability, are facilely controlled by the chemical state of precursors.« less

Castellated tiles as the beam-facing components for the diagnostic calorimeter of the negative ion source SPIDER

DOE Office of Scientific and Technical Information (OSTI.GOV)

Peruzzo, S., E-mail: simone.peruzzo@igi.cnr.it; Cervaro, V.; Dalla Palma, M.

2016-02-15

This paper presents the results of numerical simulations and experimental tests carried out to assess the feasibility and suitability of graphite castellated tiles as beam-facing component in the diagnostic calorimeter of the negative ion source SPIDER (Source for Production of Ions of Deuterium Extracted from Radio frequency plasma). The results indicate that this concept could be a reliable, although less performing, alternative for the present design based on carbon fiber composite tiles, as it provides thermal measurements on the required spatial scale.

Castellated tiles as the beam-facing components for the diagnostic calorimeter of the negative ion source SPIDER

NASA Astrophysics Data System (ADS)

Peruzzo, S.; Cervaro, V.; Dalla Palma, M.; Delogu, R.; De Muri, M.; Fasolo, D.; Franchin, L.; Pasqualotto, R.; Pimazzoni, A.; Rizzolo, A.; Tollin, M.; Zampieri, L.; Serianni, G.

2016-02-01

This paper presents the results of numerical simulations and experimental tests carried out to assess the feasibility and suitability of graphite castellated tiles as beam-facing component in the diagnostic calorimeter of the negative ion source SPIDER (Source for Production of Ions of Deuterium Extracted from Radio frequency plasma). The results indicate that this concept could be a reliable, although less performing, alternative for the present design based on carbon fiber composite tiles, as it provides thermal measurements on the required spatial scale.

Finite Element Simulation of Solid Rocket Booster Separation Motors During Motor Firing

NASA Technical Reports Server (NTRS)

Yu. Weiping; Crane, Debora J.

2007-01-01

One of the toughest challenges facing Solid Rocket Booster (SRB) engineers is to ensure that any design changes made to the Shuttle-Derived Booster Separation Motors (BSM) for future space exploration vehicles is able to withstand the increasingly hostile motor firing environment without cracking its critical component - the graphite throat. This paper presents a critical analysis methodology and techniques for assessing effects of BSM design changes with great accuracy and precision. For current Space Shuttle operation, the motor firing occurs at SRB separation - approximately 125 seconds after Shuttle launch at an altitude of about 28 miles. The motor operation event lasts about two seconds, however, the surface temperature of the graphite throat increases approximately 3400 F in less than one second with a corresponding increase in surface pressure of approximately 2200 pounds per square inch (psi) in less than one-tenth of a second. To capture this process fully and accurately, a two-phase sequentially coupled thermal-mechanical finite element approach was developed. This method allows the time- and location-dependent pressure fields to interact with the spatial-temporal thermal fields throughout the operation. The material properties of graphite throat are orthotropic and temperature-dependent. The analysis involves preload and multiple body contacts.

Lithium dendrite and solid electrolyte interphase investigation using OsO4

NASA Astrophysics Data System (ADS)

Zier, Martin; Scheiba, Frieder; Oswald, Steffen; Thomas, Jürgen; Goers, Dietrich; Scherer, Torsten; Klose, Markus; Ehrenberg, Helmut; Eckert, Jürgen

2014-11-01

Osmium tetroxide (OsO4) staining, commonly used to enhance scattering contrast in electron microscopy of biologic tissue and polymer blends, has been adopted for studies of graphite anodes in lithium-ion batteries. OsO4 shows a coordinated reaction with components of the solid electrolyte interphase (SEI) and lithium dendrites, thereby increasing material contrast for scanning electron microscopy investigations. Utilizing the high affinity of lithium metal to react with osmium tetroxide it was possible to localize even small lithium deposits on graphite electrodes. In spite of their reaction with the OsO4 fume, the lithium dendrite morphology remains almost untouched by the staining procedure, offering information on the dendrite growth process. Correlating the quantity of osmium detected with the amount of residual ("dead") lithium of a discharged electrode, it was possible to obtain a practical measure for lithium plating and stripping efficiencies. EDX mappings allowed for a localization of electrochemically stripped lithium dendrites by their residual stained SEI shells. Cross sections, prepared by focused ion beam (FIB) of cycled graphite electrodes treated with OsO4, revealed important information about deposition and distribution of metallic lithium and the electrolyte reduction layer across the electrode.

Brazed graphite/refractory metal composites for first-wall protection elements

NASA Astrophysics Data System (ADS)

Šmid, I.; Croessmann, C. D.; Salmonson, J. C.; Whitley, J. B.; Kny, E.; Reheis, N.; Kneringer, G.; Nickel, H.

1991-03-01

The peak surface heat flux deposition on divertor elements of near term fusion devices is expected to exceed 10 MW/m 2. The needed reliability of brazed plasma interactive components, particularly under abnormal operating conditions with peak surface temperatures well beyond 1000°C, makes refractory metallic substrates and brazes with a high melting point very attractive. TZM, a high temperature alloy of molybdenum, and isotropic graphite, materials very closely matched in their thermal expansion, were brazed with four high-temperature brazes. The brazes used were Zr, 90Ni/10Ti, 90Cu/10Ti and 70Ag/27Cu/3Ti (nominal composition prior to brazing, wt%). The resulting composite tiles of 50 × 50 mm2 with a TZM thickness of 5 mm and a graphite thickness of 10 mm have been tested in high heat flux simulation for their thermal fatigue properties. Up to 600 loading cycles were carried out with an average heat flux of 10 MW/m 2 for 0.5 s pulses. The maximum surface temperature was 1100°C. In support of the experiment, the thermal response and temperature gradients of the samples were investigated using a finite element model.

Initial Assessment of X-Ray Computer Tomography image analysis for material defect microstructure

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kane, Joshua James; Windes, William Enoch

2016-06-01

The original development work leading to this report was focused on the non destructive three-dimensional (3-D) characterization of nuclear graphite as a means to better understand the nature of the inherent pore structure. The pore structure of graphite and its evolution under various environmental factors such as irradiation, mechanical stress, and oxidation plays an important role in their observed properties and characteristics. If we are to transition from an empirical understanding of graphite behavior to a truly predictive mechanistic understanding the pore structure must be well characterized and understood. As the pore structure within nuclear graphite is highly interconnected andmore » truly 3-D in nature, 3-D characterization techniques are critical. While 3-D characterization has been an excellent tool for graphite pore characterization, it is applicable to a broad number of materials systems over many length scales. Given the wide range of applications and the highly quantitative nature of the tool, it is quite surprising to discover how few materials researchers understand and how valuable of a tool 3-D image processing and analysis can be. Ultimately, this report is intended to encourage broader use of 3 D image processing and analysis in materials science and engineering applications, more specifically nuclear-related materials applications, by providing interested readers with enough familiarity to explore its vast potential in identifying microstructure changes. To encourage this broader use, the report is divided into two main sections. Section 2 provides an overview of some of the key principals and concepts needed to extract a wide variety of quantitative metrics from a 3-D representation of a material microstructure. The discussion includes a brief overview of segmentation methods, connective components, morphological operations, distance transforms, and skeletonization. Section 3 focuses on the application of concepts from Section 2 to relevant materials at Idaho National Laboratory. In this section, image analysis examples featuring nuclear graphite will be discussed in detail. Additionally, example analyses from Transient Reactor Test Facility low-enriched uranium conversion, Advanced Gas Reactor like compacts, and tristructural isotopic particles are shown to give a broader perspective of the applicability to relevant materials of interest.« less

Nickel-Graphite Composite Compliant Interface and/or Hot Shoe Material

NASA Technical Reports Server (NTRS)

Firdosy, Samad A.; Chun-Yip Li, Billy; Ravi, Vilupanur A.; Fleurial, Jean-Pierre; Caillat, Thierry; Anjunyan, Harut

2013-01-01

Next-generation high-temperature thermoelectric-power-generating devices will employ segmented architectures and will have to reliably withstand thermally induced mechanical stresses produced during component fabrication, device assembly, and operation. Thermoelectric materials have typically poor mechanical strength, exhibit brittle behavior, and possess a wide range of coefficient of thermal expansion (CTE) values. As a result, the direct bonding at elevated temperatures of these materials to each other to produce segmented leg components is difficult, and often results in localized microcracking at interfaces and mec hanical failure due to the stresses that arise from the CTE mismatch between the various materials. Even in the absence of full mechanical failure, degraded interfaces can lead to increased electrical and thermal resistances, which adversely impact conversion efficiency and power output. The proposed solution is the insertion of a mechanically compliant layer, with high electrical and thermal conductivity, between the low- and high-temperature segments to relieve thermomechanical stresses during device fabrication and operation. This composite material can be used as a stress-relieving layer between the thermoelectric segments and/or between a thermoelectric segment and a hot- or cold-side interconnect material. The material also can be used as a compliant hot shoe. Nickel-coated graphite powders were hot-pressed to form a nickel-graphite composite material. A freestanding thermoelectric segmented leg was fabricated by brazing the compliant pad layer between the high-temperature p- Zintl and low-temperature p-SKD TE segments using Cu-Ag braze foils. The segmented leg stack was heated in vacuum under a compressive load to achieve bonding. The novelty of the innovation is the use of composite material that re duces the thermomechanical stresses en - countered in the construction of high-efficiency, high-temperature therm - o-electric devices. The compliant pad enables the bonding of dissimilar thermoelectric materials while maintaining the desired electrical and thermal properties essential for efficient device operation. The modulus, CTE, electrical, and thermal conductances of the composite can be controlled by varying the ratio of nickel to graphite.

FennoFlakes: a project for identifying flake graphite ores in the Fennoscandian shield and utilizing graphite in different applications

NASA Astrophysics Data System (ADS)

Palosaari, Jenny; Eklund, O.; Raunio, S.; Lindfors, T.; Latonen, R.-M.; Peltonen, J.; Smått, J.-H.; Kauppila, J.; Lund, S.; Sjöberg-Eerola, P.; Blomqvist, R.; Marmo, J.

2016-04-01

Natural graphite is a strategic mineral, since the European Commission stated (Report on critical raw materials for the EU (2014)) that graphite is one of the 20 most critical materials for the European Union. The EU consumed 13% of all flake graphite in the world but produced only 3%, which stresses the demand of the material. Flake graphite, which is a flaky version of graphite, forms under high metamorphic conditions. Flake graphite is important in different applications like batteries, carbon brushes, heat sinks etc. Graphene (a single layer of graphite) can be produced from graphite and is commonly used in many nanotechnological applications, e.g. in electronics and sensors. The steps to obtain pure graphene from graphite ore include fragmentation, flotation and exfoliation, which can be cumbersome and resulting in damaging the graphene layers. We have started a project named FennoFlakes, which is a co-operation between geologists and chemists to fill the whole value chain from graphite to graphene: 1. Exploration of graphite ores (geological and geophysical methods). 2. Petrological and geochemical analyses on the ores. 3. Development of fragmentation methods for graphite ores. 4. Chemical exfoliation of the enriched flake graphite to separate flake graphite into single and multilayer graphene. 5. Test the quality of the produced material in several high-end applications with totally environmental friendly and disposable material combinations. Preliminary results show that flake graphite in high metamorphic areas has better qualities compared to synthetic graphite produced in laboratories.

Measuring Moisture Levels in Graphite Epoxy Composite Sandwich Structures

NASA Technical Reports Server (NTRS)

Nurge, Mark; Youngquist, Robert; Starr, Stanley

2011-01-01

Graphite epoxy composite (GEC) materials are used in the construction of rocket fairings, nose cones, interstage adapters, and heat shields due to their high strength and light weight. However, they absorb moisture depending on the environmental conditions they are exposed to prior to launch. Too much moisture absorption can become a problem when temperature and pressure changes experienced during launch cause the water to vaporize. The rapid state change of the water can result in structural failure of the material. In addition, heat and moisture combine to weaken GEC structures. Diffusion models that predict the total accumulated moisture content based on the environmental conditions are one accepted method of determining if the material strength has been reduced to an unacceptable level. However, there currently doesn t exist any field measurement technique to estimate the actual moisture content of a composite structure. A multi-layer diffusion model was constructed with Mathematica to predict moisture absorption and desorption from the GEC sandwich structure. This model is used in conjunction with relative humidity/temperature sensors both on the inside and outside of the material to determine the moisture levels in the structure. Because the core materials have much higher diffusivity than the face sheets, a single relative humidity measurement will accurately reflect the moisture levels in the core. When combined with an external relative humidity measurement, the model can be used to determine the moisture levels in the face sheets. Since diffusion is temperaturedependent, the temperature measurements are used to determine the diffusivity of the face sheets for the model computations.

Toroidal-Core Microinductors Biased by Permanent Magnets

NASA Technical Reports Server (NTRS)

Lieneweg, Udo; Blaes, Brent

2003-01-01

The designs of microscopic toroidal-core inductors in integrated circuits of DC-to-DC voltage converters would be modified, according to a proposal, by filling the gaps in the cores with permanent magnets that would apply bias fluxes (see figure). The magnitudes and polarities of the bias fluxes would be tailored to counteract the DC fluxes generated by the DC components of the currents in the inductor windings, such that it would be possible to either reduce the sizes of the cores or increase the AC components of the currents in the cores without incurring adverse effects. Reducing the sizes of the cores could save significant amounts of space on integrated circuits because relative to other integrated-circuit components, microinductors occupy large areas - of the order of a square millimeter each. An important consideration in the design of such an inductor is preventing magnetic saturation of the core at current levels up to the maximum anticipated operating current. The requirement to prevent saturation, as well as other requirements and constraints upon the design of the core are expressed by several equations based on the traditional magnetic-circuit approximation. The equations involve the core and gap dimensions and the magnetic-property parameters of the core and magnet materials. The equations show that, other things remaining equal, as the maximum current is increased, one must increase the size of the core to prevent the flux density from rising to the saturation level. By using a permanent bias flux to oppose the flux generated by the DC component of the current, one would reduce the net DC component of flux in the core, making it possible to reduce the core size needed to prevent the total flux density (sum of DC and AC components) from rising to the saturation level. Alternatively, one could take advantage of the reduction of the net DC component of flux by increasing the allowable AC component of flux and the corresponding AC component of current. In either case, permanent-magnet material and the slant (if any) and thickness of the gap must be chosen according to the equations to obtain the required bias flux. In modifying the design of the inductor, one must ensure that the inductance is not altered. The simplest way to preserve the original value of inductance would be to leave the gap dimensions unchanged and fill the gap with a permanent- magnet material that, fortuitously, would produce just the required bias flux. A more generally applicable alternative would be to partly fill either the original gap or a slightly enlarged gap with a suitable permanent-magnet material (thereby leaving a small residual gap) so that the reluctance of the resulting magnetic circuit would yield the desired inductance.

A Delphi study to identify the core components of nurse to nurse handoff.

PubMed

O'Rourke, Jennifer; Abraham, Joanna; Riesenberg, Lee Ann; Matson, Jeff; Lopez, Karen Dunn

2018-03-08

The aim of this study was to identify the core components of nurse-nurse handoffs. Patient handoffs involve a process of passing information, responsibility and control from one caregiver to the next during care transitions. Around the globe, ineffective handoffs have serious consequences resulting in wrong treatments, delays in diagnosis, longer stays, medication errors, patient falls and patient deaths. To date, the core components of nurse-nurse handoff have not been identified. This lack of identification is a significant gap in moving towards a standardized approach for nurse-nurse handoff. Mixed methods design using the Delphi technique. From May 2016 - October 2016, using a series of iterative steps, a panel of handoff experts gave feedback on the nurse-nurse handoff core components and the content in each component to be passed from one nurse to the next during a typical unit-based shift handoff. Consensus was defined as 80% agreement or higher. After three rounds of participant review, 17 handoff experts with backgrounds in clinical nursing practice, academia and handoff research came to consensus on the core components of handoff: patient summary, action plan and nurse-nurse synthesis. This is the first study to identify the core components of nurse-nurse handoff. Subsequent testing of the core components will involve evaluating the handoff approach in a simulated and then actual patient care environment. Our long-term goal is to improve patient safety outcomes by validating an evidence-based handoff framework and handoff curriculum for pre-licensure nursing programmes that strengthen the quality of their handoff communication as they enter clinical practice. © 2018 John Wiley & Sons Ltd.

Voronoi-Tessellated Graphite Produced by Low-Temperature Catalytic Graphitization from Renewable Resources.

PubMed

Zhao, Leyi; Zhao, Xiuyun; Burke, Luke T; Bennett, J Craig; Dunlap, Richard A; Obrovac, Mark N

2017-09-11

A highly crystalline graphite powder was prepared from the low temperature (800-1000 °C) graphitization of renewable hard carbon precursors using a magnesium catalyst. The resulting graphite particles are composed of Voronoi-tessellated regions comprising irregular sheets; each Voronoi-tessellated region having a small "seed" particle located near their centroid on the surface. This suggests nucleated outward growth of graphitic carbon, which has not been previously observed. Each seed particle consists of a spheroidal graphite shell on the inside of which hexagonal graphite platelets are perpendicularly affixed. This results in a unique high surface area graphite with a high degree of graphitization that is made with renewable feedstocks at temperatures far below that conventionally used for artificial graphites. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Haugen, Carl C.; Forget, Benoit; Smith, Kord S.

Most high performance computing systems being deployed currently and envisioned for the future are based on making use of heavy parallelism across many computational nodes and many concurrent cores. These types of heavily parallel systems often have relatively little memory per core but large amounts of computing capability. This places a significant constraint on how data storage is handled in many Monte Carlo codes. This is made even more significant in fully coupled multiphysics simulations, which requires simulations of many physical phenomena be carried out concurrently on individual processing nodes, which further reduces the amount of memory available for storagemore » of Monte Carlo data. As such, there has been a move towards on-the-fly nuclear data generation to reduce memory requirements associated with interpolation between pre-generated large nuclear data tables for a selection of system temperatures. Methods have been previously developed and implemented in MIT’s OpenMC Monte Carlo code for both the resolved resonance regime and the unresolved resonance regime, but are currently absent for the thermal energy regime. While there are many components involved in generating a thermal neutron scattering cross section on-the-fly, this work will focus on a proposed method for determining the energy and direction of a neutron after a thermal incoherent inelastic scattering event. This work proposes a rejection sampling based method using the thermal scattering kernel to determine the correct outgoing energy and angle. The goal of this project is to be able to treat the full S (a, ß) kernel for graphite, to assist in high fidelity simulations of the TREAT reactor at Idaho National Laboratory. The method is, however, sufficiently general to be applicable in other thermal scattering materials, and can be initially validated with the continuous analytic free gas model.« less

Influence of Metal-Coated Graphite Powders on Microstructure and Properties of the Bronze-Matrix/Graphite Composites

NASA Astrophysics Data System (ADS)

Zhao, Jian-hua; Li, Pu; Tang, Qi; Zhang, Yan-qing; He, Jian-sheng; He, Ke

2017-02-01

In this study, the bronze-matrix/x-graphite (x = 0, 1, 3 and 5%) composites were fabricated by powder metallurgy route by using Cu-coated graphite, Ni-coated graphite and pure graphite, respectively. The microstructure, mechanical properties and corrosive behaviors of bronze/Cu-coated-graphite (BCG), bronze/Ni-coated-graphite (BNG) and bronze/pure-graphite (BPG) were characterized and investigated. Results show that the Cu-coated and Ni-coated graphite could definitely increase the bonding quality between the bronze matrix and graphite. In general, with the increase in graphite content in bronze-matrix/graphite composites, the friction coefficients, ultimate density and wear rates of BPG, BCG and BNG composites all went down. However, the Vickers microhardness of the BNG composite would increase as the graphite content increased, which was contrary to the BPG and BCG composites. When the graphite content was 3%, the friction coefficient of BNG composite was more stable than that of BCG and BPG composites, indicating that BNG composite had a better tribological performance than the others. Under all the values of applied loads (10, 20, 40 and 60N), the BCG and BNG composites exhibited a lower wear rate than BPG composite. What is more, the existence of nickel in graphite powders could effectively improve the corrosion resistance of the BNG composite.

CHEMICAL AND PHYSICAL CHARACTERIZATION OF COLLAPSING LOW-MASS PRESTELLAR DENSE CORES

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hincelin, U.; Commerçon, B.; Wakelam, V.

The first hydrostatic core, also called the first Larson core, is one of the first steps in low-mass star formation as predicted by theory. With recent and future high-performance telescopes, the details of these first phases are becoming accessible, and observations may confirm theory and even present new challenges for theoreticians. In this context, from a theoretical point of view, we study the chemical and physical evolution of the collapse of prestellar cores until the formation of the first Larson core, in order to better characterize this early phase in the star formation process. We couple a state-of-the-art hydrodynamical modelmore » with full gas-grain chemistry, using different assumptions for the magnetic field strength and orientation. We extract the different components of each collapsing core (i.e., the central core, the outflow, the disk, the pseudodisk, and the envelope) to highlight their specific physical and chemical characteristics. Each component often presents a specific physical history, as well as a specific chemical evolution. From some species, the components can clearly be differentiated. The different core models can also be chemically differentiated. Our simulation suggests that some chemical species act as tracers of the different components of a collapsing prestellar dense core, and as tracers of the magnetic field characteristics of the core. From this result, we pinpoint promising key chemical species to be observed.« less

Producing graphite with desired properties

NASA Technical Reports Server (NTRS)

Dickinson, J. M.; Imprescia, R. J.; Reiswig, R. D.; Smith, M. C.

1971-01-01

Isotropic or anisotropic graphite is synthesized with precise control of particle size, distribution, and shape. The isotropic graphites are nearly perfectly isotropic, with thermal expansion coefficients two or three times those of ordinary graphites. The anisotropic graphites approach the anisotropy of pyrolytic graphite.

Brazing graphite to graphite

DOEpatents

Peterson, George R.

1976-01-01

Graphite is joined to graphite by employing both fine molybdenum powder as the brazing material and an annealing step that together produce a virtually metal-free joint exhibiting properties similar to those found in the parent graphite. Molybdenum powder is placed between the faying surfaces of two graphite parts and melted to form molybdenum carbide. The joint area is thereafter subjected to an annealing operation which diffuses the carbide away from the joint and into the graphite parts. Graphite dissolved by the dispersed molybdenum carbide precipitates into the joint area, replacing the molybdenum carbide to provide a joint of virtually graphite.