Multivariate Statistical Analysis: a tool for groundwater quality assessment in the hidrogeologic region of the Ring of Cenotes, Yucatan, Mexico.

NASA Astrophysics Data System (ADS)

Ye, M.; Pacheco Castro, R. B.; Pacheco Avila, J.; Cabrera Sansores, A.

2014-12-01

The karstic aquifer of Yucatan is a vulnerable and complex system. The first fifteen meters of this aquifer have been polluted, due to this the protection of this resource is important because is the only source of potable water of the entire State. Through the assessment of groundwater quality we can gain some knowledge about the main processes governing water chemistry as well as spatial patterns which are important to establish protection zones. In this work multivariate statistical techniques are used to assess the groundwater quality of the supply wells (30 to 40 meters deep) in the hidrogeologic region of the Ring of Cenotes, located in Yucatan, Mexico. Cluster analysis and principal component analysis are applied in groundwater chemistry data of the study area. Results of principal component analysis show that the main sources of variation in the data are due sea water intrusion and the interaction of the water with the carbonate rocks of the system and some pollution processes. The cluster analysis shows that the data can be divided in four clusters. The spatial distribution of the clusters seems to be random, but is consistent with sea water intrusion and pollution with nitrates. The overall results show that multivariate statistical analysis can be successfully applied in the groundwater quality assessment of this karstic aquifer.

A Spatial and Temporal Assessment of Non-Point Groundwater Pollution Sources, Tutuila Island, American Samoa

NASA Astrophysics Data System (ADS)

Shuler, C. K.; El-Kadi, A. I.; Dulaiova, H.; Glenn, C. R.; Fackrell, J.

2015-12-01

The quality of municipal groundwater supplies on Tutuila, the main island in American Samoa, is currently in question. A high vulnerability for contamination from surface activities has been recognized, and there exists a strong need to clearly identify anthropogenic sources of pollution and quantify their influence on the aquifer. This study examines spatial relationships and time series measurements of nutrients and other tracers to identify predominant pollution sources and determine the water quality impacts of the island's diverse land uses. Elevated groundwater nitrate concentrations are correlated with areas of human development, however, the mixture of residential and agricultural land use in this unique village based agrarian setting makes specific source identification difficult using traditional geospatial analysis. Spatial variation in anthropogenic impact was assessed by linking NO3- concentrations and δ15N(NO3) from an extensive groundwater survey to land-use types within well capture zones and groundwater flow-paths developed with MODFLOW, a numerical groundwater model. Land use types were obtained from high-resolution GIS data and compared to water quality results with multiple-regression analysis to quantify the impact that different land uses have on water quality. In addition, historical water quality data and new analyses of δD and δ18O in precipitation, groundwater, and mountain-front recharge waters were used to constrain the sources and mechanisms of contamination. Our analyses indicate that groundwater nutrient levels on Tutuila are controlled primarily by residential, not agricultural activity. Also a lack of temporal variation suggests that episodic pollution events are limited to individual water sources as opposed to the entire aquifer. These results are not only valuable for water quality management on Tutuila, but also provide insight into the sustainability of groundwater supplies on other islands with similar hydrogeology and land use history.

Environmental analysis of groundwater in Mecosta County, Michigan.

PubMed

Steinman, Alan D; Biddanda, Bopi; Chu, Xuefeng; Thompson, Kurt; Rediske, Rick

2007-11-01

Groundwater withdrawal has major economic, social, and environmental implications. In Michigan, recent legislative activity has begun to address the issue of groundwater sustainability. However, more hydrologic data are needed to help inform policy and legislation. A study was conducted in Mecosta County, Michigan to: (1) determine if a relationship could be established between land use/land cover and groundwater quality; and (2) develop a conceptual model for the shallow groundwater system of the study region. In general, groundwater quality was good, with below detection levels of E. coli, low total bacterial counts, and relatively low nutrient concentrations. No statistically significant associations were found between the bacterial numbers and either land use or the physical/chemical attributes measured, which may be because the scale of our spatial analysis was too coarse to detect patterns. Finer-scale, localized processes may have a greater influence on microorganism growth and abundance than coarser-scale, regional processes in this area. Our groundwater analysis suggested that shallow groundwater flow paths are generally consistent with regional surface water flow networks, and that shallow groundwater levels in most of the region have fluctuated within 1-2 m over the past 30 years, with no obvious increasing or decreasing trend.

Characterization of Surface Water and Groundwater Quality in the Lower Tano River Basin Using Statistical and Isotopic Approach.

NASA Astrophysics Data System (ADS)

Edjah, Adwoba; Stenni, Barbara; Cozzi, Giulio; Turetta, Clara; Dreossi, Giuliano; Tetteh Akiti, Thomas; Yidana, Sandow

2017-04-01

Adwoba Kua- Manza Edjaha, Barbara Stennib,c,Giuliano Dreossib, Giulio Cozzic, Clara Turetta c,T.T Akitid ,Sandow Yidanae a,eDepartment of Earth Science, University of Ghana Legon, Ghana West Africa bDepartment of Enviromental Sciences, Informatics and Statistics, Ca Foscari University of Venice, Italy cInstitute for the Dynamics of Environmental Processes, CNR, Venice, Italy dDepartment of Nuclear Application and Techniques, Graduate School of Nuclear and Allied Sciences University of Ghana Legon This research is part of a PhD research work "Hydrogeological Assessment of the Lower Tano river basin for sustainable economic usage, Ghana, West - Africa". In this study, the researcher investigated surface water and groundwater quality in the Lower Tano river basin. This assessment was based on some selected sampling sites associated with mining activities, and the development of oil and gas. Statistical approach was applied to characterize the quality of surface water and groundwater. Also, water stable isotopes, which is a natural tracer of the hydrological cycle was used to investigate the origin of groundwater recharge in the basin. The study revealed that Pb and Ni values of the surface water and groundwater samples exceeded the WHO standards for drinking water. In addition, water quality index (WQI), based on physicochemical parameters(EC, TDS, pH) and major ions(Ca2+, Na+, Mg2+, HCO3-,NO3-, CL-, SO42-, K+) exhibited good quality water for 60% of the sampled surface water and groundwater. Other statistical techniques, such as Heavy metal pollution index (HPI), degree of contamination (Cd), and heavy metal evaluation index (HEI), based on trace element parameters in the water samples, reveal that 90% of the surface water and groundwater samples belong to high level of pollution. Principal component analysis (PCA) also suggests that the water quality in the basin is likely affected by rock - water interaction and anthropogenic activities (sea water intrusion). This was confirm by further statistical analysis (cluster analysis and correlation matrix) of the water quality parameters. Spatial distribution of water quality parameters, trace elements and the results obtained from the statistical analysis was determined by geographical information system (GIS). In addition, the isotopic analysis of the sampled surface water and groundwater revealed that most of the surface water and groundwater were of meteoric origin with little or no isotopic variations. It is expected that outcomes of this research will form a baseline for making appropriate decision on water quality management by decision makers in the Lower Tano river Basin. Keywords: Water stable isotopes, Trace elements, Multivariate statistics, Evaluation indices, Lower Tano river basin.

Characterizing groundwater quality ranks for drinking purposes in Sylhet district, Bangladesh, using entropy method, spatial autocorrelation index, and geostatistics.

PubMed

Islam, Abu Reza Md Towfiqul; Ahmed, Nasir; Bodrud-Doza, Md; Chu, Ronghao

2017-12-01

Drinking water is susceptible to the poor quality of contaminated water affecting the health of humans. Thus, it is an essential study to investigate factors affecting groundwater quality and its suitability for drinking uses. In this paper, the entropy theory, multivariate statistics, spatial autocorrelation index, and geostatistics are applied to characterize groundwater quality and its spatial variability in the Sylhet district of Bangladesh. A total of 91samples have been collected from wells (e.g., shallow, intermediate, and deep tube wells at 15-300-m depth) from the study area. The results show that NO 3 - , then SO 4 2- , and As are the most contributed parameters influencing the groundwater quality according to the entropy theory. The principal component analysis (PCA) and correlation coefficient also confirm the results of the entropy theory. However, Na + has the highest spatial autocorrelation and the most entropy, thus affecting the groundwater quality. Based on the entropy-weighted water quality index (EWQI) and groundwater quality index (GWQI) classifications, it is observed that 60.45 and 53.86% of water samples are classified as having an excellent to good qualities, while the remaining samples vary from medium to extremely poor quality domains for drinking purposes. Furthermore, the EWQI classification provides the more reasonable results than GWQIs due to its simplicity, accuracy, and ignoring of artificial weight. A Gaussian semivariogram model has been chosen to the best fit model, and groundwater quality indices have a weak spatial dependence, suggesting that both geogenic and anthropogenic factors play a pivotal role in spatial heterogeneity of groundwater quality oscillations.

The National Water-Quality Assessment Program of the United States: Strategies for Monitoring Trends and Results from the First Two Decades of Study: 1991-2011

NASA Astrophysics Data System (ADS)

Lindsey, B.; McMahon, P.; Rupert, M.; Tesoriero, J.; Starn, J.; Anning, D.; Green, C.

2012-04-01

The U.S. Geological Survey National Water-Quality Assessment (NAWQA) Program was implemented in 1991 to provide long-term, consistent, and comparable information on the quality of surface and groundwater resources of the United States. Findings are used to support national, regional, state, and local information needs with respect to water quality. The three main goals of the program are to 1) assess the condition of the nation's streams, rivers, groundwater, and aquatic systems; 2) assess how conditions are changing over time; and 3) determine how natural features and human activities affect these conditions, and where those effects are most pronounced. As data collection progressed into the second decade, the emphasis of the interpretation of the data has shifted from primarily understanding status, to evaluation of trends. The program has conducted national and regional evaluations of change in the quality of water in streams, rivers, groundwater, and health of aquatic systems. Evaluating trends in environmental systems requires complex analytical and statistical methods, and a periodic re-evaluation of the monitoring methods used to collect these data. Examples given herein summarize the lessons learned from the evaluation of changes in water quality during the past two decades with an emphasis on the finding with respect to groundwater. The analysis of trends in groundwater is based on 56 well networks located in 22 principal aquifers of the United States. Analysis has focused on 3 approaches: 1) a statistical analysis of results of sampling over various time scales, 2) studies of factors affecting trends in groundwater quality, and 3) use of models to simulate groundwater trends and forecast future trends. Data collection for analysis of changes in groundwater-quality has focused on decadal resampling of wells. Understanding the trends in groundwater quality and the factors affecting those trends has been conducted using quarterly sampling, biennial sampling, and more recently continuous monitoring of selected parameters in a small number of wells. Models such as MODFLOW have been used for simulation and forecasting of future trends. Important outcomes from the groundwater-trends studies include issues involving statistics, sampling frequency, changes in laboratory analytical methods over time, the need for groundwater age-dating information, the value of understanding geochemical conditions and contaminant degradation, the need to understand groundwater-surface water interaction, and the value of modeling in understanding trends and forecasting potential future conditions. Statistically significant increases in chloride, dissolved solids, and nitrate concentrations were found in a large number of well networks over the first decadal sampling period. Statistically significant decreases of chloride, dissolved solids, and nitrate concentrations were found in a very small number of networks. Trends in surface-water are analyzed within 8 large major river basins within the United States with a focus on issues of regional importance. Examples of regional surface-water issues include an analysis of trends in dissolved solids in the Southeastern United States, trends in pesticides in the north-central United States, and trends in nitrate in the Mississippi River Basin. Evaluations of ecological indicators of water quality include temporal changes in stream habitat, and aquatic-invertebrate and fish assemblages.

Impact assessment of on-site sanitation system on groundwater quality in alluvial settings: A case study from Lucknow city in North India.

PubMed

Jangam, Chandrakant; Ramya Sanam, S; Chaturvedi, M K; Padmakar, C; Pujari, Paras R; Labhasetwar, Pawan K

2015-10-01

The present case study has been undertaken to investigate the impact of on-site sanitation on groundwater quality in alluvial settings in Lucknow City in India. The groundwater samples have been collected in the areas of Lucknow City where the on-site sanitation systems have been implemented. The groundwater samples have been analyzed for the major physicochemical parameters and fecal coliform. The results of analysis reveal that none of the groundwater samples exceeded the Bureau of Indian Standards (BIS) limits for all the parameters. Fecal coliform was not found in majority of the samples including those samples which were very close to the septic tank. The study area has a thick alluvium cover as a top layer which acts as a natural barrier for groundwater contamination from the on-site sanitation system. The t test has been performed to assess the seasonal effect on groundwater quality. The statistical t test implies that there is a significant effect of season on groundwater quality in the study area.

Factors controlling groundwater quality in the Yeonjegu District of Busan City, Korea, using the hydrogeochemical processes and fuzzy GIS.

PubMed

Venkatramanan, Senapathi; Chung, Sang Yong; Selvam, Sekar; Lee, Seung Yeop; Elzain, Hussam Eldin

2017-10-01

The hydrogeochemical processes and fuzzy GIS techniques were used to evaluate the groundwater quality in the Yeonjegu district of Busan Metropolitan City, Korea. The highest concentrations of major ions were mainly related to the local geology. The seawater intrusion into the river water and municipal contaminants were secondary contamination sources of groundwater in the study area. Factor analysis represented the contamination sources of the mineral dissolution of the host rocks and domestic influences. The Gibbs plot exhibited that the major ions were derived from the rock weathering condition. Piper's trilinear diagram showed that the groundwater quality was classified into five types of CaHCO 3 , NaHCO 3 , NaCl, CaCl 2 , and CaSO 4 types in that order. The ionic relationship and the saturation mineral index of the ions indicated that the evaporation, dissolution, and precipitation processes controlled the groundwater chemistry. The fuzzy GIS map showed that highly contaminated groundwater occurred in the northeastern and the central parts and that the groundwater of medium quality appeared in most parts of the study area. It suggested that the groundwater quality of the study area was influenced by local geology, seawater intrusion, and municipal contaminants. This research clearly demonstrated that the geochemical analyses and fuzzy GIS method were very useful to identify the contaminant sources and the location of good groundwater quality.

Spatial variability analysis of combining the water quality and groundwater flow model to plan groundwater and surface water management in the Pingtung plain

NASA Astrophysics Data System (ADS)

Chen, Ching-Fang; Chen, Jui-Sheng; Jang, Cheng-Shin

2014-05-01

As a result of rapid economic growth in the Pingtung Plain, the use of groundwater resources has changed dramatically. The groundwater is quite rich in the Pingtung plain and the most important water sources. During the several decades, a substantial amount of groundwater has been pumped for the drinking, irrigation and aquaculture water supplies. However, because the sustainable use concept of groundwater resources is lack, excessive pumping of groundwater causes the occurrence of serious land subsidence and sea water intrusion. Thus, the management and conservation of groundwater resources in the Pingtung plain are considerably critical. This study aims to assess the conjunct use effect of groundwater and surface water in the Pingtung plain on recharge by reducing the amount of groundwater extraction. The groundwater quality variability and groundwater flow models are combined to spatially analyze potential zones of groundwater used for multi-purpose in the Pingtung Plain. First, multivariate indicator kriging (MVIK) is used to analyze spatial variability of groundwater quality based on drinking, aquaculture and irrigation water quality standards, and probabilistically delineate suitable zones in the study area. Then, the groundwater flow model, Processing MODFLOW (PMWIN), is adopted to simulate groundwater flow. The groundwater flow model must be conducted by the calibration and verification processes, and the regional groundwater recovery is discussed when specified water rights are replaced by surface water in the Pingtung plain. Finally, the most suitable zones of reducing groundwater use are determined for multi-purpose according to combining groundwater quality and quantity. The study results can establish a sound and low-impact management plan of groundwater resources utilization for the multi-purpose groundwater use, and prevent decreasing ground water tables, and the occurrence of land subsidence and sea water intrusion in the Pingtung plain.

Groundwater hydrogeochemical characteristics in rehabilitated coalmine spoils

NASA Astrophysics Data System (ADS)

Gomo, M.; Masemola, E.

2016-04-01

The investigation aims to identify and describe hydrogeochemical processes controlling the evolution of groundwater chemistry in rehabilitated coalmine spoils and their overall influence on groundwater quality at a study area located in the Karoo basin of South Africa. A good understanding of the processes that controls the evolution of the mine water quality is vital for the planning, application and management of post-mining remedial actions. The study utilises scatter plots, statistical analysis, PHREEQC hydrogeochemical modelling, stoichiometric reaction ratios analysis, and the expanded Durov diagram as complimentary tools to interpret the groundwater chemistry data collected from monitoring boreholes from 1995 to 2014. Measured pH ranging between 6-8 and arithmetic mean of 7.32 shows that the groundwater system is characterised by circumneutral hydrogeochemical conditions period. Comparison of measured groundwater ion concentrations to theoretical reaction stoichiometry identifies Dolomite-Acid Mine Drainage (AMD) neutralisation as the main hydrogeochemical process controlling the evolution of the groundwater chemistry. Hydrogeochemical modelling shows that, the groundwater has temporal variations of calcite and dolomite saturation indices characterised by alternating cycles of over-saturation and under-saturation that is driven by the release of sulphate, calcium and magnesium ions from the carbonate-AMD neutralization process. Arithmetic mean concentrations of sulphate, calcium and magnesium are in the order of 762 mg/L, 141 mg/L and 108 mg/L. Calcium and magnesium ions contribute to very hard groundwater quality conditions. Classification based on total dissolved solids (TDS), shows the circumneutral water is of poor to unacceptable quality for drinking purposes. Despite its ability to prevent AMD formation and leaching of metals, the dolomite-AMD neutralisation process can still lead to problems of elevated TDS and hardness which mines should be aware of when developing water quality management plans.

Coastal Water Quality Modeling in Tidal Lake: Revisited with Groundwater Intrusion

NASA Astrophysics Data System (ADS)

Kim, C.

2016-12-01

A new method for predicting the temporal and spatial variation of water quality, with accounting for a groundwater effect, has been proposed and applied to a water body partially connected to macro-tidal coastal waters in Korea. The method consists of direct measurement of environmental parameters, and it indirectly incorporates a nutrients budget analysis to estimate the submarine groundwater fluxes. Three-dimensional numerical modeling of water quality has been used with the directly collected data and the indirectly estimated groundwater fluxes. The applied area is Saemangeum tidal lake that is enclosed by 33km-long sea dyke with tidal openings at two water gates. Many investigations of groundwater impact reveal that 10 50% of nutrient loading in coastal waters comes from submarine groundwater, particularly in the macro-tidal flat, as in the west coast of Korea. Long-term monitoring of coastal water quality signals the possibility of groundwater influence on salinity reversal and on the excess mass outbalancing the normal budget in Saemangeum tidal lake. In the present study, we analyze the observed data to examine the influence of submarine groundwater, and then a box model is demonstrated for quantifying the influx and efflux. A three-dimensional numerical model has been applied to reproduce the process of groundwater dispersal and its effect on the water quality of Saemangeum tidal lake. The results show that groundwater influx during the summer monsoon then contributes significantly, 20% more than during dry season, to water quality in the tidal lake.

Ground-water quality in selected areas of Wisconsin

USGS Publications Warehouse

Hindall, S.M.

1979-01-01

Analysis of 2,071 ground-water samples from 970 wells throughout Wisconsin indicate large variations in ground-water quality. Ground water in Wisconsin is generally suitable for most uses, but in some areas concentrations of chemical constituents exceed recommended drinking-water standards. Iron, manganese, and nitrate commonly exceed recommended drinking-water standards and dissolved solids, sulfate, heavy metals, and phenolic materials may present local problems. (USGS)

Geospatial distribution modeling and determining suitability of groundwater quality for irrigation purpose using geospatial methods and water quality index (WQI) in Northern Ethiopia

NASA Astrophysics Data System (ADS)

Gidey, Amanuel

2018-06-01

Determining suitability and vulnerability of groundwater quality for irrigation use is a key alarm and first aid for careful management of groundwater resources to diminish the impacts on irrigation. This study was conducted to determine the overall suitability of groundwater quality for irrigation use and to generate their spatial distribution maps in Elala catchment, Northern Ethiopia. Thirty-nine groundwater samples were collected to analyze and map the water quality variables. Atomic absorption spectrophotometer, ultraviolet spectrophotometer, titration and calculation methods were used for laboratory groundwater quality analysis. Arc GIS, geospatial analysis tools, semivariogram model types and interpolation methods were used to generate geospatial distribution maps. Twelve and eight water quality variables were used to produce weighted overlay and irrigation water quality index models, respectively. Root-mean-square error, mean square error, absolute square error, mean error, root-mean-square standardized error, measured values versus predicted values were used for cross-validation. The overall weighted overlay model result showed that 146 km2 areas are highly suitable, 135 km2 moderately suitable and 60 km2 area unsuitable for irrigation use. The result of irrigation water quality index confirms 10.26% with no restriction, 23.08% with low restriction, 20.51% with moderate restriction, 15.38% with high restriction and 30.76% with the severe restriction for irrigation use. GIS and irrigation water quality index are better methods for irrigation water resources management to achieve a full yield irrigation production to improve food security and to sustain it for a long period, to avoid the possibility of increasing environmental problems for the future generation.

Hydrochemical and multivariate analysis of groundwater quality in the northwest of Sinai, Egypt.

PubMed

El-Shahat, M F; Sadek, M A; Salem, W M; Embaby, A A; Mohamed, F A

2017-08-01

The northwestern coast of Sinai is home to many economic activities and development programs, thus evaluation of the potentiality and vulnerability of water resources is important. The present work has been conducted on the groundwater resources of this area for describing the major features of groundwater quality and the principal factors that control salinity evolution. The major ionic content of 39 groundwater samples collected from the Quaternary aquifer shows high coefficients of variation reflecting asymmetry of aquifer recharge. The groundwater samples have been classified into four clusters (using hierarchical cluster analysis), these match the variety of total dissolvable solids, water types and ionic orders. The principal component analysis combined the ionic parameters of the studied groundwater samples into two principal components. The first represents about 56% of the whole sample variance reflecting a salinization due to evaporation, leaching, dissolution of marine salts and/or seawater intrusion. The second represents about 15.8% reflecting dilution with rain water and the El-Salam Canal. Most groundwater samples were not suitable for human consumption and about 41% are suitable for irrigation. However, all groundwater samples are suitable for cattle, about 69% and 15% are suitable for horses and poultry, respectively.

Quality-assurance and data management plan for groundwater activities by the U.S. Geological Survey in Kansas, 2014

USGS Publications Warehouse

Putnam, James E.; Hansen, Cristi V.

2014-01-01

As the Nation’s principle earth-science information agency, the U.S. Geological Survey (USGS) is depended on to collect data of the highest quality. This document is a quality-assurance plan for groundwater activities (GWQAP) of the Kansas Water Science Center. The purpose of this GWQAP is to establish a minimum set of guidelines and practices to be used by the Kansas Water Science Center to ensure quality in groundwater activities. Included within these practices are the assignment of responsibilities for implementing quality-assurance activities in the Kansas Water Science Center and establishment of review procedures needed to ensure the technical quality and reliability of the groundwater products. In addition, this GWQAP is intended to complement quality-assurance plans for surface-water and water-quality activities and similar plans for the Kansas Water Science Center and general project activities throughout the USGS. This document provides the framework for collecting, analyzing, and reporting groundwater data that are quality assured and quality controlled. This GWQAP presents policies directing the collection, processing, analysis, storage, review, and publication of groundwater data. In addition, policies related to organizational responsibilities, training, project planning, and safety are presented. These policies and practices pertain to all groundwater activities conducted by the Kansas Water Science Center, including data-collection programs, interpretive and research projects. This report also includes the data management plan that describes the progression of data management from data collection to archiving and publication.

A reconnaissance analysis of groundwater quality in the Eagle Ford shale region reveals two distinct bromide/chloride populations.

PubMed

Hildenbrand, Zacariah L; Carlton, Doug D; Meik, Jesse M; Taylor, Josh T; Fontenot, Brian E; Walton, Jayme L; Henderson, Drew; Thacker, Jonathan B; Korlie, Stephanie; Whyte, Colin J; Hudak, Paul F; Schug, Kevin A

2017-01-01

The extraction of oil and natural gas from unconventional shale formations has prompted a series of investigations to examine the quality of the groundwater in the overlying aquifers. Here we present a reconnaissance analysis of groundwater quality in the Eagle Ford region of southern Texas. These data reveal two distinct sample populations that are differentiable by bromide/chloride ratios. Elevated levels of fluoride, nitrate, sulfate, various metal ions, and the detection of exotic volatile organic compounds highlight a high bromide group of samples, which is geographically clustered, while encompassing multiple hydrogeological strata. Samples with bromide/chloride ratios representative of connate water displayed elevated levels of total organic carbon, while revealing the detection of alcohols and chlorinated compounds. These findings suggest that groundwater quality in the Western Gulf Basin is, for the most part, controlled by a series of natural processes; however, there is also evidence of episodic contamination events potentially attributed to unconventional oil and gas development or other anthropogenic activities. Collectively, this characterization of natural groundwater constituents and exogenous compounds will guide targeted remediation efforts and provides insight for agricultural entities, industrial operators, and rural communities that rely on groundwater in southern Texas. Copyright © 2016 Elsevier B.V. All rights reserved.

Impact of land-use on groundwater quality: GIS-based study from an alluvial aquifer in the western Ganges basin

NASA Astrophysics Data System (ADS)

Khan, Arina; Khan, Haris Hasan; Umar, Rashid

2017-12-01

In this study, groundwater quality of an alluvial aquifer in the western Ganges basin is assessed using a GIS-based groundwater quality index (GQI) concept that uses groundwater quality data from field survey and laboratory analysis. Groundwater samples were collected from 42 wells during pre-monsoon and post-monsoon periods of 2012 and analysed for pH, EC, TDS, Anions (Cl, SO4, NO3), and Cations (Ca, Mg, Na). To generate the index, several parameters were selected based on WHO recommendations. The spatially variable grids of each parameter were modified by normalizing with the WHO standards and finally integrated into a GQI grid. The mean GQI values for both the season suggest good groundwater quality. However, spatial variations exist and are represented by GQI map of both seasons. This spatial variability was compared with the existing land-use, prepared using high-resolution satellite imagery available in Google earth. The GQI grids were compared to the land-use map using an innovative GIS-based method. Results indicate that the spatial variability of groundwater quality in the region is not fully controlled by the land-use pattern. This probably reflects the diffuse nature of land-use classes, especially settlements and plantations.

Temporal variations of groundwater quality in the Western Jianghan Plain, China.

PubMed

Niu, Beibei; Wang, Huanhuan; Loáiciga, Hugo A; Hong, Song; Shao, Wei

2017-02-01

The Western Jianghan Plain (WJHP) lies in the middle reaches of the Yangtze River. It has been impacted by anthropogenic activities during the past decades. The long-term variations of the WJHP's regional aquifer's hydrochemistry and groundwater quality have not been previously assessed. Sixteen physiochemical parameters at 29 monitoring wells within the Western Jianghan Plain were monitored during 1992-2010 and analyzed with multiple approaches. The confined groundwater is predominantly of the HCO 3 -Ca-Mg type with Cl - , SO 4 2- , NH 4 -N, and NO 3 -N showing remarkable spatial variations. Correlation analysis was used to identify the origins and contamination sources of groundwater. The seasonal Mann-Kendall test revealed that pH, NO 3 -N, and Cl - concentrations at 27, 26 and 15 wells, respectively, exhibited significant increasing trends during 1992-2010. The increase of pH may be attributed to CO 2 degassing caused by extensive groundwater extraction. Regional average NO 3 -N concentrations of groundwater increased coincidently with the increased use of fertilizer, which suggests that nitrate pollution is caused by agricultural activities. Abnormally high values of Cl - and SO 4 2- at some wells were induced by industrial chemicals. In addition, the similarity of the temporal variations of the regional average of pH, NH 4 -N, and NO 3 -N concentrations in groundwater with those in the Yangtze River at the outlet of the Three Gorges Reservoir (TGR) suggests that the variations of these parameters in the WJHP is partly due to water storage by the TGR. This study presents an analysis of temporal variations of groundwater quality in the WJHP that reveals a relation between the creation of the TGR and downstream groundwater quality. This paper's findings provide clues for measures that could be taken to protect the groundwater quality of the WJHP's aquifer. Copyright © 2016. Published by Elsevier B.V.

Elucidating hydraulic fracturing impacts on groundwater quality using a regional geospatial statistical modeling approach.

PubMed

Burton, Taylour G; Rifai, Hanadi S; Hildenbrand, Zacariah L; Carlton, Doug D; Fontenot, Brian E; Schug, Kevin A

2016-03-01

Hydraulic fracturing operations have been viewed as the cause of certain environmental issues including groundwater contamination. The potential for hydraulic fracturing to induce contaminant pathways in groundwater is not well understood since gas wells are completed while isolating the water table and the gas-bearing reservoirs lay thousands of feet below the water table. Recent studies have attributed ground water contamination to poor well construction and leaks in the wellbore annulus due to ruptured wellbore casings. In this paper, a geospatial model of the Barnett Shale region was created using ArcGIS. The model was used for spatial analysis of groundwater quality data in order to determine if regional variations in groundwater quality, as indicated by various groundwater constituent concentrations, may be associated with the presence of hydraulically fractured gas wells in the region. The Barnett Shale reservoir pressure, completions data, and fracture treatment data were evaluated as predictors of groundwater quality change. Results indicated that elevated concentrations of certain groundwater constituents are likely related to natural gas production in the study area and that beryllium, in this formation, could be used as an indicator variable for evaluating fracturing impacts on regional groundwater quality. Results also indicated that gas well density and formation pressures correlate to change in regional water quality whereas proximity to gas wells, by itself, does not. The results also provided indirect evidence supporting the possibility that micro annular fissures serve as a pathway transporting fluids and chemicals from the fractured wellbore to the overlying groundwater aquifers. Copyright © 2015 Elsevier B.V. All rights reserved.

Use of the landfill water pollution index (LWPI) for groundwater quality assessment near the landfill sites.

PubMed

Talalaj, Izabela A; Biedka, Pawel

2016-12-01

The purpose of the paper is to assess the groundwater quality near the landfill sites using landfill water pollution index (LWPI). In order to investigate the scale of groundwater contamination, three landfills (E, H and S) in different stages of their operation were taken into analysis. Samples of groundwater in the vicinity of studied landfills were collected four times each year in the period from 2004 to 2014. A total of over 300 groundwater samples were analysed for pH, EC, PAH, TOC, Cr, Hg, Zn, Pb, Cd, Cu, as required by the UE legal acts for landfill monitoring system. The calculated values of the LWPI allowed the quantification of the overall water quality near the landfill sites. The obtained results indicated that the most negative impact on groundwater quality is observed near the old Landfill H. Improper location of piezometer at the Landfill S favoured infiltration of run-off from road pavement into the soil-water environment. Deep deposition of the groundwater level at Landfill S area reduced the landfill impact on the water quality. Conducted analyses revealed that the LWPI can be used for evaluation of water pollution near a landfill, for assessment of the variability of water pollution with time and for comparison of water quality from different piezometers, landfills or time periods. The applied WQI (Water Quality Index) can also be an important information tool for landfill policy makers and the public about the groundwater pollution threat from landfill.

Spatio-temporal variation of stream-aquifer interaction: Effect of a weir construction in Korea

NASA Astrophysics Data System (ADS)

Lee, Hyeonju; Koo, Min-Ho; Kim, Kisu; Kim, Yongcheol

2015-04-01

The Four Major Rivers Restoration Project was conducted to secure sufficient water resources, introduce comprehensive flood control measures, and improve water quality while restore the river ecosystem in Korea. The dredging of river bed and the installation of 16 weirs were done in Han, Geum, Yeongsan, and Nakdong rivers from late 2010 to early 2012 as a part of the project. Groundwater data obtained from 213 groundwater monitoring wells near the four major rivers were used to analyze the impacts of weir construction on the nearby groundwater flow system. The groundwater level and chemical characteristics were analyzed to investigate how the groundwater flow system and water quality changed after the weir construction. The results showed that groundwater level rose immediately following the rise of stream stage after the weir construction. Also, the hydrologic condition of the stream in some upland of the weirs was changed from a gaining to a losing stream. Consequently, the direction of groundwater flow was changed from perpendicular to parallel to the stream, and it swapped the groundwater in the downstream of the weir for the water recharged from the stream. Considering the results, some groundwater quality is expected to be changed and become similar to that of the stream, although the change has been not observed yet. Therefore, both further monitoring of the groundwater quality and hydrogeochemical analysis are required for quantitatively evaluating the effect of the weir.

Hydrochemical and environmental isotope analysis of groundwater and surface water in a dry mountain region in Northern Chile.

PubMed

Zang, Carina; Dame, Juliane; Nüsser, Marcus

2018-05-08

This case study examines the geological imprint and land use practices on water quality in the arid Huasco Valley against the backdrop of ongoing water conflicts surrounding competing demands for agriculture and mining. The study is based on a detailed analysis of spatial and temporal variations of monthly surface and bi-monthly groundwater quality samples measured during the Chilean summer of 2015/16. Additional information on source regions and river-groundwater interactions were collected using stable water isotopes. Regarding the geological impact on water quality, high concentrations of Ca 2+ , SO 4 2- and HCO 3 - indicate a strong influence of magmatic rocks, which constitute this high mountain basin, on the hydrochemistry. Piper and Gibbs-diagrams revealed that all samples show a homogenous distribution dominated by rock-water interactions. Measured NO 3 - concentrations in surface water are generally low. However, groundwater aquifers exhibit higher concentrations. Mn is the only heavy metal with elevated concentrations in surface water, which are possibly related to mining activities. The results illustrate that both surface and groundwater can be classified as suitable for irrigation. In addition, groundwater has been found to be suitable as drinking water. High similarities in isotopic signatures indicate a strong connection between surface and groundwater. Isotopic analyses suggest a strong influence of evaporation. This combined approach of hydrogeochemical and isotopic analysis proved to be a helpful tool in characterizing the catchment and can serve as a basis for future sustainable water management.

Assessment of the impact of landfill on groundwater quality: a case study of the Pirana site in western India.

PubMed

Singh, Umesh Kumar; Kumar, Manish; Chauhan, Rita; Jha, Pawan Kumar; Ramanathan, Al; Subramanian, V

2008-06-01

In present study focus has been given on estimating quality and toxicity of waste with respect to heavy metals and its impact on groundwater quality, using statistical and empirical relationships between different hydrochemical data, so that easy monitoring may be possible which in turn help the sustainable management of landfill site and municipal solid waste. Samples of solid waste, leachate and groundwater were analyzed to evaluate the impact of leachates on groundwater through the comparison of their hydrochemical nature. Results suggest the existence of an empirical relationship between some specific indicator parameters like heavy metals of all three above mentioned sample type. Further, K/Mg ratio also indicates three groundwater samples heavily impacted from leachate contamination. A good number of samples are also showing higher values for NO(3)(-) and Pb than that of World Health Organization (WHO) drinking water regulation. Predominance of Fe and Zn in both groundwater and solid waste samples may be due to metal plating industries in the area. Factor analysis is used as a tool to explain observed relation between numerous variables in term of simpler relation, which may help to deduce the strength of relation. Positive loading of most of the factors for heavy metal clearly shows landfill impact on ground water quality especially along the hydraulic gradient. Cluster analysis, further substantiates the impact of landfill. Two major groups of samples obtained from cluster analysis suggest that one group comprises samples that are severely under the influence of landfill and contaminated leachates along the groundwater flow direction while other assorted with samples without having such influence.

Groundwater-Quality Data in the Madera-Chowchilla Study Unit, 2008: Results from the California GAMA Program

USGS Publications Warehouse

Shelton, Jennifer L.; Fram, Miranda S.; Belitz, Kenneth

2009-01-01

Groundwater quality in the approximately 860-square-mile Madera-Chowchilla study unit (MADCHOW) was investigated in April and May 2008 as part of the Priority Basin Project of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The GAMA Priority Basin Project was developed in response to the Groundwater Quality Monitoring Act of 2001 and is being conducted by the U.S. Geological Survey (USGS) in cooperation with the California State Water Resources Control Board (SWRCB). The study was designed to provide a spatially unbiased assessment of the quality of raw groundwater used for public water supplies within MADCHOW, and to facilitate statistically consistent comparisons of groundwater quality throughout California. Samples were collected from 35 wells in Madera, Merced, and Fresno Counties. Thirty of the wells were selected using a spatially distributed, randomized grid-based method to provide statistical representation of the study area (grid wells), and five more were selected to provide additional sampling density to aid in understanding processes affecting groundwater quality (flow-path wells). Detection summaries in the text and tables are given for grid wells only, to avoid over-representation of the water quality in areas adjacent to flow-path wells. Groundwater samples were analyzed for a large number of synthetic organic constituents (volatile organic compounds [VOCs], low-level 1,2-dibromo-3-chloropropane [DBCP] and 1,2-dibromoethane [EDB], pesticides and pesticide degradates, polar pesticides and metabolites, and pharmaceutical compounds), constituents of special interest (N-nitrosodimethylamine [NDMA], perchlorate, and low-level 1,2,3-trichloropropane [1,2,3-TCP]), naturally occurring inorganic constituents (nutrients, major and minor ions, and trace elements), and radioactive constituents (uranium isotopes, and gross alpha and gross beta particle activities). Naturally occurring isotopes and geochemical tracers (stable isotopes of hydrogen, oxygen, and carbon, and activities of tritium and carbon-14), and dissolved noble gases also were measured to help identify the sources and ages of the sampled groundwater. In total, approximately 300 constituents and field water-quality indicators were investigated. Three types of quality-control samples (blanks, replicates, and samples for matrix spikes) each were collected at approximately 11 percent of the wells sampled for each analysis, and the results obtained from these samples were used to evaluate the quality of the data for the groundwater samples. Field blanks rarely contained detectable concentrations of any constituent, suggesting that data for the groundwater samples were not compromised by possible contamination during sample collection, handling or analysis. Differences between replicate samples were within acceptable ranges. Matrix spike recoveries were within acceptable ranges for most compounds. This study did not attempt to evaluate the quality of water delivered to consumers; after withdrawal from the ground, raw groundwater typically is treated, disinfected, or blended with other waters to maintain water quality. Regulatory thresholds apply to water that is served to the consumer, not to raw groundwater. However, to provide some context for the results, concentrations of constituents measured in the raw groundwater were compared with regulatory and non-regulatory health-based thresholds established by the U.S. Environmental Protection Agency (USEPA) and the California Department of Public Health (CDPH), and with aesthetic and technical thresholds established by CDPH. Comparisons between data collected for this study and drinking-water thresholds are for illustrative purposes only, and are not indicative of compliance or non-compliance with regulatory thresholds. The concentrations of most constituents detected in groundwater samples from MADCHOW wells were below drinking-water thresholds. Organic compounds (VOCs and pesticides

Understanding Land Use Impacts on Groundwater Quality Using Chemical Analysis

NASA Astrophysics Data System (ADS)

Nitka, A.; Masarik, K.; Masterpole, D.; Johnson, B.; Piette, S.

2017-12-01

Chippewa County, in western Wisconsin, has a unique historical set of groundwater quality data. The county conducted extensive groundwater sampling of private wells in 1985 (715 wells) and 2007 (800 wells). In 2016, they collaborated with UW-Extension and UW-Stevens Point to evaluate the current status of groundwater quality in Chippewa County by sampling of as many of the previously studied wells as possible. Nitrate was a primary focus of this groundwater quality inventory. Of the 744 samples collected, 60 were further analyzed for chemical indicators of agricultural and septic waste, two major sources of nitrate contamination. Wells for nitrate source analysis were selected from the 2016 participants based upon certain criteria. Only wells with a Wisconsin Unique Well Number were considered to ensure well construction information was available. Next, an Inverse Distance Weighting tool in ESRI ArcMap was used to assign values categorizing septic density. Two-thirds of the wells were selected in higher density areas and one-third in lower density areas. Equally prioritized was an even distribution of nitrate - N concentrations, with 28 of the wells having nitrate - N concentrations higher than the drinking water standard of 10 mg/L and 32 wells with concentrations between 2 and 10 mg/L. All wells with WUWN and nitrate - N concentrations greater than 20 mg/L were selected. The results of the nitrate source analyses will aid in determining temporal changes and spatial relationships of groundwater quality to soils, geology and land use in Chippewa County.

Applicability of ELISA-based Determination of Pesticides for Groundwater Quality Monitoring

NASA Astrophysics Data System (ADS)

Tsuchihara, Takeo; Yoshimoto, Shuhei; Ishida, Satoshi; Imaizumi, Masayuki

The principals and procedures of ELISA (Enzyme-linked Immunosorbent Assay)-based determination of pesticides (Fenitrothion) in environmental samples were reviewed, and the applicability of the ELISA method for groundwater quality monitoring were validated through the experimental tracer tests in soil columns and the field test in Okinoerabu Island. The test results showed that the ELISA method could be useful not only for screening but also for quantitative analysis of pesticides. In the experimental tracer tests in soil columns, the retardation of pesticides leaching compared with conservative tracers were observed. In the field test, the contamination of the pesticide was detected in groundwater samples in Okinoerabu Island, even though the targeted pesticide was considered to be applied to the upland field 4 months ago. In order to investigate the transport and fate of pesticides in groundwater taking into account retardation from the field to groundwater table and the residue in groundwater, continuous observations of pesticides in groundwater are in a strong need, and the ELISA method is applicable to the long-term quality groundwater monitoring.

Extended principle component analysis - a useful tool to understand processes governing water quality at catchment scales

NASA Astrophysics Data System (ADS)

Selle, B.; Schwientek, M.

2012-04-01

Water quality of ground and surface waters in catchments is typically driven by many complex and interacting processes. While small scale processes are often studied in great detail, their relevance and interplay at catchment scales remain often poorly understood. For many catchments, extensive monitoring data on water quality have been collected for different purposes. These heterogeneous data sets contain valuable information on catchment scale processes but are rarely analysed using integrated methods. Principle component analysis (PCA) has previously been applied to this kind of data sets. However, a detailed analysis of scores, which are an important result of a PCA, is often missing. Mathematically, PCA expresses measured variables on water quality, e.g. nitrate concentrations, as linear combination of independent, not directly observable key processes. These computed key processes are represented by principle components. Their scores are interpretable as process intensities which vary in space and time. Subsequently, scores can be correlated with other key variables and catchment characteristics, such as water travel times and land use that were not considered in PCA. This detailed analysis of scores represents an extension of the commonly applied PCA which could considerably improve the understanding of processes governing water quality at catchment scales. In this study, we investigated the 170 km2 Ammer catchment in SW Germany which is characterised by an above average proportion of agricultural (71%) and urban (17%) areas. The Ammer River is mainly fed by karstic springs. For PCA, we separately analysed concentrations from (a) surface waters of the Ammer River and its tributaries, (b) spring waters from the main aquifers and (c) deep groundwater from production wells. This analysis was extended by a detailed analysis of scores. We analysed measured concentrations on major ions and selected organic micropollutants. Additionally, redox-sensitive variables and environmental tracers indicating groundwater age were analysed for deep groundwater from production wells. For deep groundwater, we found that microbial turnover was stronger influenced by local availability of energy sources than by travel times of groundwater to the wells. Groundwater quality primarily reflected the input of pollutants determined by landuse, e.g. agrochemicals. We concluded that for water quality in the Ammer catchment, conservative mixing of waters with different origin is more important than reactive transport processes along the flow path.

Groundwater quality from a part of Prakasam District, Andhra Pradesh, India

NASA Astrophysics Data System (ADS)

Subba Rao, N.

2018-03-01

Quality of groundwater is assessed from a part of Prakasam district, Andhra Pradesh, India. Groundwater samples collected from thirty locations from the study area were analysed for pH, electrical conductivity (EC), total dissolved solids (TDS), calcium (Ca2+), magnesium (Mg2+), sodium (Na+), potassium (K+), bicarbonate ( {HCO}3^{ - } ), chloride (Cl-), sulphate ( {SO}4^{2 - } ), nitrate ( {NO}3^{ - } ) and fluoride (F-). The results of the chemical analysis indicate that the groundwater is alkaline in nature and are mainly characterized by Na+- {HCO}3^{ - } and Na+-Cl- facies. Groundwater chemistry reflects the dominance of rock weathering and is subsequently modified by human activities, which are supported by genetic geochemical evolution and hydrogeochemical relations. Further, the chemical parameters (pH, TDS, Ca2+, Mg2+, Na+, {HCO}3^{ - } , Cl-, {SO}4^{2 - } , {NO}3^{ - } and F-) were compared with the drinking water quality standards. The sodium adsorption ratio, percent sodium, permeability index, residual sodium carbonate, magnesium ratio and Kelly's ratio were computed and USSL, Wilcox and Doneen's diagrams were also used for evaluation of groundwater quality for irrigation. For industrial purpose, the pH, TDS, {HCO}3^{ - } , Cl- and {SO}4^{2 - } were used to assess the impact of incrustation and corrosion activities on metal surfaces. As a whole, it is observed that the groundwater quality is not suitable for drinking, irrigation and industrial purposes due to one or more chemical parameters exceeding their standard limits. Therefore, groundwater management measures were suggested to improve the water quality.

Twenty years of global groundwater research: A Science Citation Index Expanded-based bibliometric survey (1993-2012)

NASA Astrophysics Data System (ADS)

Niu, Beibei; Loáiciga, Hugo A.; Wang, Zhen; Zhan, F. Benjamin; Hong, Song

2014-11-01

A bibliometric analysis was conducted to evaluate groundwater research from different perspectives in the period 1993-2012 based on the Science Citation Index-Expanded (SCIE) database. The bibliometric analysis summarizes output, categorical, geographical, and institutional patterns, as well as research hotspots in global groundwater studies. Groundwater research experienced notable growth in the past two decades. ;Environmental sciences;, ;water resources; and ;multidisciplinary geosciences; were the three major subject categories. The Journal of Hydrology published the largest number of groundwater-related publications in the surveyed period. Major author clusters and research regions are located in the United States, Western Europe, Eastern and Southern Asia, and Eastern Australia. The United States was a leading contributor to global groundwater research with the largest number of independent and collaborative papers, its dominance affirmed by housing 12 of the top 20 most active institutions reporting groundwater-related research. The US Geological Survey, the Chinese Academy of Sciences, and the USDA Agricultural Research Service were the three institutions with the largest number of groundwater-related publications. A keywords analysis revealed that groundwater quality and contamination, effective research technologies, and treatment technologies for water-quality improvement were the main research areas in the study period. Several keywords such as ;arsenic;, ;climate change;, ;fluoride;, ;groundwater management;, ;hydrogeochemistry;, ;uncertainty;, ;numerical modeling;, ;seawater intrusion;, ;adsorption;, ;remote sensing;, ;land use;, ;USA;(as study site), and ;water supply; received dramatically increased attention during the study period, possibly signaling future research trends.

Index of surface-water records, part 12, Pacific slope basins in Washington and upper Columbia River basin, to September 30, 1948

USGS Publications Warehouse

,

1949-01-01

The groundwater resources of Wood County, Wisconsin, are described. Groundwater is pumped only from wells drilled in Precambrian rock in the northern two-thirds of the county. The generally low permeability of this rock limits the availability of groundwater in this area. Saturated deposits of sand and gravel yield more than 500 gal/min to wells in the southern part of the county. Background groundwater quality and indicators of groundwater-quality problems, such as elevated concentrations of nitrate, chloride, hardness, and iron, are compared by aquifer for the entire county. An elevated concentration of iron is the major water quality problem in the county. Results of water quality analysis from observation wells drilled next to abandoned landfills throughout the county indicate that groundwater in the immediate vicinity of these landfills has been affected by leachate. The report includes maps of the thickness and saturated thickness of unconsolidated deposits, a water-table map, and tables of aquifer-production and well-production data from about 1,500 drillers ' well-construction reports. (USGS)

Groundwater quality from private domestic water-supply wells in the vicinity of petroleum production in southwestern Indiana

USGS Publications Warehouse

Risch, Martin R.; Silcox, Cheryl A.

2016-06-02

The U.S. Geological Survey provided technical support to the Agency for Toxic Substances and Disease Registry for site selection and sample collection and analysis in a 2012 investigation of groundwater quality from 29 private domestic water-supply wells in the vicinity of petroleum production in southwestern Indiana. Petroleum hydrocarbons, oil and grease, aromatic volatile organic compounds, methane concentrations greater than 8,800 micrograms per liter, chloride concentrations greater than 250 milligrams per liter, and gross alpha radioactivity greater than 15 picocuries per liter were reported in the analysis of groundwater samples from 11 wells.

Quality-assurance plan for groundwater activities, U.S. Geological Survey, Washington Water Science Center

USGS Publications Warehouse

Kozar, Mark D.; Kahle, Sue C.

2013-01-01

This report documents the standard procedures, policies, and field methods used by the U.S. Geological Survey’s (USGS) Washington Water Science Center staff for activities related to the collection, processing, analysis, storage, and publication of groundwater data. This groundwater quality-assurance plan changes through time to accommodate new methods and requirements developed by the Washington Water Science Center and the USGS Office of Groundwater. The plan is based largely on requirements and guidelines provided by the USGS Office of Groundwater, or the USGS Water Mission Area. Regular updates to this plan represent an integral part of the quality-assurance process. Because numerous policy memoranda have been issued by the Office of Groundwater since the previous groundwater quality assurance plan was written, this report is a substantial revision of the previous report, supplants it, and contains significant additional policies not covered in the previous report. This updated plan includes information related to the organization and responsibilities of USGS Washington Water Science Center staff, training, safety, project proposal development, project review procedures, data collection activities, data processing activities, report review procedures, and archiving of field data and interpretative information pertaining to groundwater flow models, borehole aquifer tests, and aquifer tests. Important updates from the previous groundwater quality assurance plan include: (1) procedures for documenting and archiving of groundwater flow models; (2) revisions to procedures and policies for the creation of sites in the Groundwater Site Inventory database; (3) adoption of new water-level forms to be used within the USGS Washington Water Science Center; (4) procedures for future creation of borehole geophysics, surface geophysics, and aquifer-test archives; and (5) use of the USGS Multi Optional Network Key Entry System software for entry of routine water-level data collected as part of long-term water-level monitoring networks.

Application of multivariate statistical analysis and hydrochemical and isotopic investigations for evaluation of groundwater quality and its suitability for drinking and agriculture purposes: case of Oum Ali-Thelepte aquifer, central Tunisia.

PubMed

Hassen, Imen; Hamzaoui-Azaza, Fadoua; Bouhlila, Rachida

2016-03-01

Groundwater plays a dominant role in arid regions; it is among the most available water resources in Tunisia. Located in northwestern Tunisia, Oum Ali-Thelepte is a deep Miocene sedimentary aquifer, where groundwater is the most important source of water supply. The aim of the study is to investigate the hydrochemical processes leading to mineralization and to assess water quality with respect to agriculture and drinking for a better management of groundwater resources. To achieve such objectives, water analysis was carried out on 16 groundwater samples collected during January-February 2014. Stable isotopes and 26 hydrochemical parameters were examined. The interpretation of these analytical data showed that the concentrations of major and trace elements were within the permissible level for human use. The distribution of mineral processes in this aquifer was identified using conventional classification techniques, suggesting that the water facies gradually changes from Ca-HCO3 to Mg-SO4 type and are controlled by water-rock interaction. These results were endorsed using multivariate statistical methods such as principal component analysis and cluster analysis. The sustainability of groundwater for drinking and irrigation was assessed based on the water quality index (WQI) and on Wilcox and Richards's diagrams. This aquifer has been classified as "excellent water" serving good irrigation in the area. As for the stable isotope, the measurements showed that groundwater samples lay between global meteoric water line (GMWL) and LMWL; hence, this arrangement signifies that the recharge of the Oum Ali-Thelepte aquifer is ensured by rainwater infiltration through mountains in the border of the aquifer without evaporation effects.

Groundwater quality characterization around Jawaharnagar open dumpsite, Telangana State

NASA Astrophysics Data System (ADS)

Unnisa, Syeda Azeem; Zainab Bi, Shaik

2017-11-01

In the present work groundwater samples were collected from ten different data points in and around Jawaharnagar municipal dumpsite, Telangana State Hyderabad city from May 2015 to May 2016 on monthly basis for groundwater quality characterization. Pearson's correlation coefficient ( r) value was determined using correlation matrix to identify the highly correlated and interrelated water quality standards issued by Bureau of Indian Standard (IS-10500:2012). It is found that most of the groundwater samples are above acceptable limits and are not potable. The chemical analysis results revealed that pH range from 7.2 to 7.8, TA 222 to 427 mg/l, TDS 512 to 854 mg/l, TH 420 to 584 mg/l, Calcium 115 to 140 mg/l, Magnesium 55 to 115 mg/l, Chlorides 202 to 290 mg/l, Sulphates 170 to 250 mg/l, Nitrates 6.5 to 11.3 mg/l, and Fluoride 0.9 to 1.7 mg/l. All samples showed higher range of physicochemical parameters except nitrate content which was lower than permissible limit. Highly positive correlation was observed between pH-TH ( r = 0.5063), TA-Cl- ( r = 0.5896), TDS-SO4 - ( r = 0.5125), Mg2+-NO3 - ( r = 0.5543) and Cl--F- ( r = 0.7786). The groundwater samples in and around Jawaharnagar municipal dumpsite implies that groundwater samples were contaminated by municipal leachate migration from open dumpsite. The results revealed that the systematic calculations of correlation coefficient between water parameters and regression analysis provide qualitative and rapid monitoring of groundwater quality.

Spatial and temporal variation of groundwater quality and its suitability for irrigation and drinking purpose using GIS and WQI in an urban fringe

NASA Astrophysics Data System (ADS)

Dhanasekarapandian, M.; Chandran, S.; Devi, D. Saranya; Kumar, V.

2016-12-01

This study is aimed at evaluating the groundwater quality within the urban reach of Gridhumal river sub-basin. 29 groundwater samples were collected with different categorization during post-monsoon (POM) and summer (SUM) seasons respectively. Various physical and chemical parameters viz., pH, Electrical Conductivity (EC), Total Dissolved Solids (TDS), Total Hardness (TH), Total Alkalinity, cations such as, Ca2+, Mg2+, Na+, anions such as NO3-, SO42-, F-, Cl- were analyzed and were compared with the standard guidelines recommended by WHO, ICMR, BIS. GIS techniques were used to find out the distribution of groundwater quality on land use pattern. Results indicated that the EC, TDS, TH, Na+, Cl-, NO3- level in groundwater samples was above critical limits, and it was found to be very high in wastewater irrigated areas in the urban reach of Gridhumal river sub-basin. Geochemical analysis of groundwater samples shows the predominance of Na-Cl and NaHCO3 types. The geochemical data was interpreted using WQI for drinking water quality and were found not suitable for drinking purposes. With Wilcox diagram, only 30% and 21% groundwater samples show suitability for irrigation for post monsoon and summer season. The US Salinity Laboratory Staff plot depicted that all the post monsoon groundwater sources are C3-S3, C4-S4 type and C4-S4 for the summer season. 17% samples show C3-S1 type for both the season. From the HC analysis in the groundwater samples have been classified into two groups, one is ionic and another metals group. PCA results revealed the existence of seven significant principal components indicating how processes like rock-water interaction and anthropogenic activities influence groundwater quality. Seven factors which together explain 83.33% and 77.85% of the total variance in the post monsoon and summer season respectively. In comparing heavy metal contents present in water samples with BIS/WHO standards, Pb, Cr and Cd concentrations were found to be present above the maximum permissible limits and were found in the following order Cd < Pb < Fe < Cr < Mn < Zn. By results, it is concluded that groundwater is not suitable for irrigation and drinking purposes due to long term use of wastewater, anthropogenic activities, over-extraction of groundwater and changes in land use pattern.

Analysis of Groundwater Reserved in Dusun Ngantru Sekaran Village East Java

NASA Astrophysics Data System (ADS)

Pandjaitan, N. H.; Waspodo, R. S. B.; Karunia, T. U.; Mustikasari, N.

2018-05-01

Limited capacity of fresh water in some areas in Indonesia made some regions had drought problem or lack of surface water. One of the solutions was increasing ground water used. This research aimed to identify aquifer and the pattern of ground water flow and also to determine potential of groundwater reserved in Dusun Ngantru. The result would be use to find the right location to be used as groundwater wells. The method used in this research was geoelectric method. This method was used to determine the condition of aquifer and rocks under the soil and to define hydrogeological condition of Dusun Ngantru.The analysis results can be used as a reference of where and what kind of groundwater runs underneath, in order to be optimally utilized. The results of hydrogeological studies and the distribution of aquifer showed that there were unconfined and semi aquifers. The direction of the groundwater flow in the study site varied greatly as the lithologic arrangement varied just as much. In the study locations there were Ledok formation, Mundu formation, and Lidah formation. Groundwater potential ware predicted of 55.33 m3/day or 0.64 lt/s. Based on water quality standard in Indonesia, the water quality of wells were classified as first class quality.

Geospatial Modelling for Micro Zonation of Groundwater Regime in Western Assam, India

NASA Astrophysics Data System (ADS)

Singh, R. P.

2016-12-01

Water, most precious natural resource on earth, is vital to sustain the natural system and human civilisation on the earth. The Assam state located in north-eastern part of India has a relatively good source of ground water due to their geographic and physiographic location but there is problem deterioration of groundwater quality causing major health problem in the area. In this study, I tried a integrated study of remote sensing and GIS and chemical analysis of groundwater samples to throw a light over groundwater regime and provides information for decision makers to make sustainable water resource management. The geospatial modelling performed by integrating hydrogeomorphic features. Geomorphology, lineament, Drainage, Landuse/landcover layer were generated through visual interpretation on satellite image (LISS III) based on tone, texture, shape, size, and arrangement of the features. Slope layer was prepared by using SRTM DEM data set .The LULC of the area were categories in to 6 classes of Agricultural field, Forest area ,River, Settlement , Tree-clad area and Wetlands. The geospatial modelling performed through weightage and rank method in GIS, depending on the influence of the features on ground water regime. To Assess the ground water quality of the area 45 groundwater samples have been collected from the field and chemical analysis performed through the standard method in the laboratory. The overall assessment of the ground water quality of the area analyse through Water Quality Index and found that about 70% samples are not potable for drinking purposes due to higher concentration Arsenic, Fluoride and Iron. It appears that, source of all these pollutants geologically and geomorphologically derived. Interpolated layer of Water Quality Index and geospatial modelled Groundwater potential layer provides a holistic view of groundwater scenario and provide direction for better planning and groundwater resource management. Study will be discussed in details during the conference.

Assessment of groundwater quality: a fusion of geochemical and geophysical information via Bayesian neural networks.

PubMed

Maiti, Saumen; Erram, V C; Gupta, Gautam; Tiwari, Ram Krishna; Kulkarni, U D; Sangpal, R R

2013-04-01

Deplorable quality of groundwater arising from saltwater intrusion, natural leaching and anthropogenic activities is one of the major concerns for the society. Assessment of groundwater quality is, therefore, a primary objective of scientific research. Here, we propose an artificial neural network-based method set in a Bayesian neural network (BNN) framework and employ it to assess groundwater quality. The approach is based on analyzing 36 water samples and inverting up to 85 Schlumberger vertical electrical sounding data. We constructed a priori model by suitably parameterizing geochemical and geophysical data collected from the western part of India. The posterior model (post-inversion) was estimated using the BNN learning procedure and global hybrid Monte Carlo/Markov Chain Monte Carlo optimization scheme. By suitable parameterization of geochemical and geophysical parameters, we simulated 1,500 training samples, out of which 50 % samples were used for training and remaining 50 % were used for validation and testing. We show that the trained model is able to classify validation and test samples with 85 % and 80 % accuracy respectively. Based on cross-correlation analysis and Gibb's diagram of geochemical attributes, the groundwater qualities of the study area were classified into following three categories: "Very good", "Good", and "Unsuitable". The BNN model-based results suggest that groundwater quality falls mostly in the range of "Good" to "Very good" except for some places near the Arabian Sea. The new modeling results powered by uncertainty and statistical analyses would provide useful constrain, which could be utilized in monitoring and assessment of the groundwater quality.

Human virus and microbial indicator occurrence in public-supply groundwater systems: meta-analysis of 12 international studies

USDA-ARS?s Scientific Manuscript database

Groundwater quality is often evaluated using microbial indicators. This study examines data from 12 international groundwater studies (conducted 1992–2013). Sites were chosen from 718 public drinking-water systems with a range of hydrogeological conditions. Focus was on testing the value of indicato...

Classification management plan of groundwater quality in Taiwan

NASA Astrophysics Data System (ADS)

Chen, Chun Ming; Chen, Yu Ying; Pan, Shih Cheng; Li, Hui Jun; Hsiao, Fang Ke

2017-04-01

Taiwan Environmental Protection Administration has been monitoring regional water quality for 14 years. Since the beginning of 2002 till now, there are 453 regional groundwater monitoring wells in ten groundwater subregions in Taiwan, and the monitoring of groundwater quality has been carried out for a long time. Currently, water quality monitoring project has reached 50 items, while the number of water quality monitoring data has reached more than 20,000. In order to use the monitoring data efficiently, this study constructed the localized groundwater quality indicators of Taiwan. This indicator takes into account the different users' point of view, incorporating the Taiwan groundwater pollution monitoring standards (Category II), irrigation water quality standard and drinking water source water quality standard. 50 items of water quality monitoring projects were simplified and classified. The groundwater quality parameters were divided into five items, such as potability for drinking water, salting, external influence, health influences and toxicity hazard. The weight of the five items of groundwater was calculated comprehensively, and the groundwater quality of each monitoring well was evaluated with three grades of good, ordinary, and poor. According to the monitoring results of the groundwater monitoring wells in October to December of 2016, about 70% of groundwater quality in Taiwan is in good to ordinary grades. The areas with poor groundwater quality were mostly distributed in coastal, agriculture and part of the urban areas. The conductivity or ammonia nitrogen concentration was higher in those regions, showing that groundwater may be salinized or affected by external influences. Groundwater quality indicators can clearly show the current comprehensive situation of the groundwater environment in Taiwan and can be used as a tool for groundwater quality classification management. The indicators can coordinate with the Taiwan land planning policy in the future, and will be able to effectively grasp the changes of the national sub-regional environmental resources, which can serve as one of the important references in national land zoning according to environmental resources. Keywords: Groundwater Quality Indicators, Groundwater Quality Classification management

Assessment of groundwater quality using geographical information system (GIS), at north-east Cairo, Egypt.

PubMed

El-Shahat, M F; Sadek, M A; Mostafa, W M; Hagagg, K H

2016-04-01

The present investigation has been conducted to delineate the hydrogeochemical and environmental factors that control the water quality of the groundwater resources in the north-east of Cairo. A complementary approach based on hydrogeochemistry and a geographical information system (GIS) based protectability index has been employed for conducting this work. The results from the chemical analysis revealed that the groundwater of the Quaternary aquifer is less saline than that of the Miocene aquifer and the main factors that control the groundwater salinity in the studied area are primarily related to the genesis of the original recharging water modified after by leaching, dissolution, cation exchange, and fertilizer leachate. The computed groundwater quality index (WQI) falls into two categories: fair for almost all the Miocene groundwater samples, while the Quaternary groundwater samples are all have a good quality. The retarded flow and non-replenishment of the Miocene aquifer compared to the renewable active recharge of the Quaternary aquifer can explain this variation of WQI. The index and overlay approach exemplified by the DUPIT index has been used to investigate the protectability of the study aquifers against diffuse pollutants. Three categories (highly protectable less vulnerable, moderately protectable moderately vulnerable and less protectable highly vulnerable) have been determined and areally mapped.

Geographical Information System based assessment of spatiotemporal characteristics of groundwater quality of upland sub-watersheds of Meenachil River, parts of Western Ghats, Kottayam District, Kerala, India

NASA Astrophysics Data System (ADS)

Vijith, H.; Satheesh, R.

2007-09-01

Hydrogeochemistry of groundwater in upland sub-watersheds of Meenachil river, parts of Western Ghats, Kottayam, Kerala, India was used to assess the quality of groundwater for determining its suitability for drinking and agricultural purposes. The study area is dominated by rocks of Archaean age, and Charnonckite is dominated over other rocks. Rubber plantation dominated over other types of the vegetation in the area. Though the study area receives heavy rainfall, it frequently faces water scarcity as well as water quality problems. Hence, a Geographical Information System (GIS) based assessment of spatiotemporal behaviour of groundwater quality has been carried out in the region. Twenty-eight water samples were collected from different wells and analysed for major chemical constituents both in monsoon and post-monsoon seasons to determine the quality variation. Physical and chemical parameters of groundwater such as pH, dissolved oxygen (DO), total hardness (TH), chloride (Cl), nitrate (NO3) and phosphate (PO4) were determined. A surface map was prepared in the ArcGIS 8.3 (spatial analyst module) to assess the quality in terms of spatial variation, and it showed that the high and low regions of water quality varied spatially during the study period. The influence of lithology over the quality of groundwater is negligible in this region because majority of the area comes under single lithology, i.e. charnockite, and it was found that the extensive use of fertilizers and pesticides in the rubber, tea and other agricultural practices influenced the groundwater quality of the region. According to the overall assessment of the basin, all the parameters analysed are below the desirable limits of WHO and Indian standards for drinking water. Hence, considering the pH, the groundwater in the study area is not suitable for drinking but can be used for irrigation, industrial and domestic purposes. The spatial analysis of groundwater quality patterns of the study area shows seasonal fluctuations and these spatial patterns of physical and chemical constituents are useful in deciding water use strategies for various purposes.

Groundwater quality, age, and susceptibility and vulnerability to nitrate contamination with linkages to land use and groundwater flow, Upper Black Squirrel Creek Basin, Colorado, 2013

USGS Publications Warehouse

Wellman, Tristan P.; Rupert, Michael G.

2016-03-03

The results of this investigation offer the foundational information needed for developing best management practices to mitigate nitrate contamination, basic concepts on water quality to aid public education, and information to guide regulatory measures if policy makers determine this is warranted. Science-based decision making will require continued monitoring and analysis of water quality in the future.

Assessing the Groundwater Quality at a Saudi Arabian Agricultural Site and the Occurrence of Opportunistic Pathogens on Irrigated Food Produce.

PubMed

Alsalah, Dhafer; Al-Jassim, Nada; Timraz, Kenda; Hong, Pei-Ying

2015-10-05

This study examines the groundwater quality in wells situated near agricultural fields in Saudi Arabia. Fruits (e.g., tomato and green pepper) irrigated with groundwater were also assessed for the occurrence of opportunistic pathogens to determine if food safety was compromised by the groundwater. The amount of total nitrogen in most of the groundwater samples exceeded the 15 mg/L permissible limit for agricultural irrigation. Fecal coliforms in densities > 12 MPN/100 mL were detected in three of the groundwater wells that were in close proximity to a chicken farm. These findings, coupled with qPCR-based fecal source tracking, show that groundwater in wells D and E, which were nearest to the chicken farm, had compromised quality. Anthropogenic contamination resulted in a shift in the predominant bacterial phyla within the groundwater microbial communities. For example, there was an elevated presence of Proteobacteria and Cyanobacteria in wells D and E but a lower overall microbial richness in the groundwater perturbed by anthropogenic contamination. In the remaining wells, the genus Acinetobacter was detected at high relative abundance ranging from 1.5% to 48% of the total groundwater microbial community. However, culture-based analysis did not recover any antibiotic-resistant bacteria or opportunistic pathogens from these groundwater samples. In contrast, opportunistic pathogenic Enterococcus faecalis and Pseudomonas aeruginosa were isolated from the fruits irrigated with the groundwater from wells B and F. Although the groundwater was compromised, quantitative microbial risk assessment suggests that the annual risk incurred from accidental consumption of E. faecalis on these fruits was within the acceptable limit of 10(-4). However, the annual risk arising from P. aeruginosa was 9.55 × 10(-4), slightly above the acceptable limit. Our findings highlight that the groundwater quality at this agricultural site in western Saudi Arabia is not pristine and that better agricultural management practices are needed alongside groundwater treatment strategies to improve food safety.

Assessing the Groundwater Quality at a Saudi Arabian Agricultural Site and the Occurrence of Opportunistic Pathogens on Irrigated Food Produce

PubMed Central

Alsalah, Dhafer; Al-Jassim, Nada; Timraz, Kenda; Hong, Pei-Ying

2015-01-01

This study examines the groundwater quality in wells situated near agricultural fields in Saudi Arabia. Fruits (e.g., tomato and green pepper) irrigated with groundwater were also assessed for the occurrence of opportunistic pathogens to determine if food safety was compromised by the groundwater. The amount of total nitrogen in most of the groundwater samples exceeded the 15 mg/L permissible limit for agricultural irrigation. Fecal coliforms in densities > 12 MPN/100 mL were detected in three of the groundwater wells that were in close proximity to a chicken farm. These findings, coupled with qPCR-based fecal source tracking, show that groundwater in wells D and E, which were nearest to the chicken farm, had compromised quality. Anthropogenic contamination resulted in a shift in the predominant bacterial phyla within the groundwater microbial communities. For example, there was an elevated presence of Proteobacteria and Cyanobacteria in wells D and E but a lower overall microbial richness in the groundwater perturbed by anthropogenic contamination. In the remaining wells, the genus Acinetobacter was detected at high relative abundance ranging from 1.5% to 48% of the total groundwater microbial community. However, culture-based analysis did not recover any antibiotic-resistant bacteria or opportunistic pathogens from these groundwater samples. In contrast, opportunistic pathogenic Enterococcus faecalis and Pseudomonas aeruginosa were isolated from the fruits irrigated with the groundwater from wells B and F. Although the groundwater was compromised, quantitative microbial risk assessment suggests that the annual risk incurred from accidental consumption of E. faecalis on these fruits was within the acceptable limit of 10−4. However, the annual risk arising from P. aeruginosa was 9.55 × 10−4, slightly above the acceptable limit. Our findings highlight that the groundwater quality at this agricultural site in western Saudi Arabia is not pristine and that better agricultural management practices are needed alongside groundwater treatment strategies to improve food safety. PMID:26445052

Annual summary of ground-water conditions in Arizona, spring 1984 to spring 1985

USGS Publications Warehouse

,

1986-01-01

In arid and semiarid regions such as Arizona, the availability of adequate water supplies has a significant influence on the type and extent of economic development. About two-thirds of the water used in the State is groundwater. The nature and extent of the groundwater reservoirs must be known for proper management of this valuable resource. The U.S. Geological Survey, in cooperation with the State of Arizona, has conducted a program of groundwater studies in Arizona since 1939. The primary purposes of these studies are to define the amount, location, and quality of the groundwater resources of Arizona and to monitor the effects of large-scale development of the groundwater supplies. The program includes the collection, compilation, and analysis of the geologic and hydrologic data necessary to evaluate the groundwater resources of the State. The basic hydrologic data are in computer storage and are available to the public. Since 1974, a major thrust of the program has been to inventory the groundwater conditions in the 68 groundwater areas of the State. Several selected groundwater areas are studied each year; water levels are measured annually in a statewide observation well network, many groundwater samples are collected and analyzed annually, and groundwater pumpage is computed for most of the areas. As of July 1985, reports had been published for 56 of the 68 groundwater areas. Data collected in the groundwater areas include information on selected wells, water level measurements, and water samples for chemical analysis. The data for each of the selected groundwater areas are analyzed, and the results are published in map form. Typically, the maps show depth to water; change in water levels; altitude of the water level; and quality of water data, such as specific conductance, dissolved solids, and fluoride. (Lantz-PTT)

The spatial and seasonal variability of the groundwater chemistry and quality in the exploited aquifer in the Daxing District, Beijing, China.

PubMed

Zhai, Yuanzheng; Lei, Yan; Zhou, Jun; Li, Muzi; Wang, Jinsheng; Teng, Yanguo

2015-02-01

The aquifer in the Beijing Plain is intensively used as a primary source to meet the growing needs of the various sectors (drinking, agricultural, and industrial purposes). The analysis of groundwater chemical characteristics provides much important information useful in water resources management. To characterize the groundwater chemistry, reveal its spatial and seasonal variability, and determine its quality suitability for domestic and agricultural uses, a total of 200 groundwater samples were collected in June and October 2012 from 100 exploited wells in Daxing District, Beijing, China. All of the indices (39 items) listed in the Quality Standard for Groundwater of China (QSGC) as well as eight additional common parameters were tested and analyzed for all samples, based on which research target was achieved. The seasonal effect on the groundwater chemistry and quality was very slight, whereas the spatial changes were very obvious. The aquifer is mainly dominated by HCO3-Ca·Mg-type water. Of the 39 quality indices listed in QSGC, 28 indices of all of the samples for the 2 months can be classified into the excellent level, whereas the remaining 11 indices can be classified into different levels with the total hardness, NO3, NO2, and Fe being the worst, mainly distributed in the residential and industrial land. According to the general quality index, the groundwater can be classified from good to a relatively poor level, mainly from southeast to northwest. Furthermore, the relatively poor-level area in the northwest expands to the southeast more than in the past years, to which people should pay attention because this reverse spatial distribution relative to the natural law indicates an obvious, anthropogenic impact on the groundwater. In addition, the groundwater in this area is generally very suitable for irrigation year-round. Nevertheless, we recommend performing agricultural water-saving measures for the sustainable development of water and urbanization, groundwater recovery, and ecological safety.

Assessment of groundwater quality for drinking and irrigation purposes using hydrochemical studies in Malwa region, southwestern part of Punjab, India

NASA Astrophysics Data System (ADS)

Kaur, Tajinder; Bhardwaj, Renu; Arora, Saroj

2017-10-01

Deterioration of groundwater quality due to anthropogenic activities is increasing at an alarming rate in most parts of the Punjab, but limited work has been carried out on groundwater quality and monitoring. This paper highlights the groundwater quality and compares its suitability for drinking and irrigation purpose in Malwa region, a southwestern part of Punjab. The Malwa region makes up the most cultivated area of Punjab with high consumption of pesticides and fertilizers. Twenty-four water samples representing groundwater sources were collected and analyzed for almost all major cations, anions and other physicochemical parameters. Analytical results of physicochemical analysis showed majority of the samples above the permissible limits of the Indian standards. The groundwater of the study area was very hard and the relative abundance of major cations and anions was Na+ > Ca2+ > Mg2+ > K+ and HCO3 - > SO4 2- > Cl-. Fluoride content was higher than permissible limit in 75 % of the samples. The mean concentration of arsenic in groundwater was 9.37 and 11.01µg/L during summer and winter season, respectively. The parameters like sodium adsorption ratio and sodium percentage (Na%) revealed good quality of groundwater for irrigation purposes, whereas magnesium ratio and corrosivity ratio values showed that water is not suitable for agriculture and domestic use. The dominant hydrochemical facies of groundwater was Ca-Mg-HCO3 and Ca-Mg-SO4-Cl. Chloro alkaline indices 1 and 2 indicated that reverse ion exchange is dominant in the region. The samples fall in rock dominance and evaporation dominance fields as indicated by Gibbs diagram. The saturation index shows that all the water samples were supersaturated with respect to carbonate minerals. This work thus concludes that groundwater in the study area is chemically unsuitable for domestic and agricultural uses. It is recommended to carry out a continuous water quality monitoring program and development of effective management practices for utilization of water resources.

Early warning risk assessment for drinking water production: decoding subtle evidence

NASA Astrophysics Data System (ADS)

Merz, Christoph; Lischeid, Gunnar; Böttcher, Steven

2016-04-01

Due to increasing demands for high quality water for drinking water supply all over the world there is acute need for methods to detect possible threats to groundwater resources early. Especially drinking water production in complex geologic settings has a particularly high risk for unexpected degradation of the groundwater quality due to the unknown interplay between anthropogenically induced hydraulic changes and geochemical processes. This study investigates the possible benefit of the Principal Component Analysis (PCA) for groundwater and drinking water management using common sets of physicochemical monitoring data. The approach was used to identify the prevailing processes driving groundwater quality shifts and related threats, which might be masked in anthropogenically impacted aquifer systems. The approach was applied to a data set from a waterworks located in the state of Brandenburg, NE Germany, which has been operating since nearly four decades. The region faces confronting and increasing demands due to rising peri-urban settlements. The PCA subdivided the data set according to different strengths of effects induced by differing geochemical processes at different sites in the capture zone of the waterworks and varying in time. Thus a spatial assessment of these processes could be performed as well as a temporal assessment of long-term groundwater quality shifts in the extracted water. The analysis revealed that over the period of 16 years of water withdrawal the geochemistry of the extracted groundwater had become increasingly more dissimilar compared to the characteristics found at the majority of observation wells. This component could be identified as highly mineralized CaSO4 dominated water from unexamined deeper zones of the aquifer system. Due to the complex geochemical and hydraulic interactions in the system, this process was masked and was not evident in the data set without validation by the applied statistical analysis. The findings give a clear indication of a potential threat to the groundwater resources in this region with danger for drinking water contamination in a medium-term period.

Groundwater quality and its suitability for drinking and irrigational use in the Southern Tiruchirappalli district, Tamil Nadu, India

NASA Astrophysics Data System (ADS)

Selvakumar, S.; Ramkumar, K.; Chandrasekar, N.; Magesh, N. S.; Kaliraj, S.

2017-03-01

A total of 20 groundwater samples were collected from both dug and bore wells of southern Tiruchirappalli district and analyzed for various hydrogeochemical parameters. The analyzed physicochemical parameters such as pH, electrical conductivity, total dissolved solids, calcium, magnesium, sodium, potassium, bicarbonate, carbonate, sulfate, chloride, nitrate, and fluoride are used to characterize the groundwater quality and its suitability for drinking and irrigational uses. The results of the chemical analysis indicates that the groundwater in the study area is slightly alkaline and mainly contains Na+, Ca2+, and Mg2+ cations as well as HCO3 2-, Cl-, SO4 2-and NO3 - anions. The total dissolved solids mainly depend on the concentration of major ions such as Ca, Mg, Na, K, HCO3, Cl, and SO4. Based on TDS, 55 % of the samples are suitable for drinking and rest of the samples are unsuitable for drinking. The total hardness indicates that majority of the groundwater samples are found within the permissible limit of WHO. The dominant hydrochemical facies for groundwater are Ca-Mg-Cl, Ca-HCO3, and Ca-Cl type. The USSL graphical geochemical representation of groundwater quality suggests that majority of the water samples belongs to high medium salinity with low alkali hazards. The Gibb's plot indicates that the groundwater chemistry of the study area is mainly controlled by evaporation and rock-water interaction. Spearman's correlation and factor analysis were used to distinguish the statistical relation between different ions and contamination source in the study area.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Elvado Environmental LLC

This report contains the groundwater and surface water monitoring data that were obtained during calendar year (CY) 2008 at the U.S. Department of Energy (DOE) Y-12 National Security Complex (hereafter referenced as Y-12) on the DOE Oak Ridge Reservation (ORR) in Oak Ridge, Tennessee. The CY 2008 monitoring data were obtained from wells, springs, and surface water sampling locations in three hydrogeologic regimes at Y-12 (Figure A.1). The Bear Creek Hydrogeologic Regime (Bear Creek Regime) encompasses a section of Bear Creek Valley (BCV) between the west end of Y-12 and the west end of the Bear Creek Watershed (directions aremore » in reference to the Y-12 grid system). The Upper East Fork Poplar Creek Hydrogeologic Regime (East Fork Regime) encompasses the Y-12 industrial facilities and support structures in BCV. The Chestnut Ridge Hydrogeologic Regime (Chestnut Ridge Regime) encompasses a section of Chestnut Ridge directly south of Y-12. Section 2 of this report provides background information pertinent to groundwater and surface water quality monitoring in each hydrogeologic regime, including the topography and bedrock geology, surface water drainage, groundwater system, and extent of groundwater contamination. The CY 2008 groundwater and surface water monitoring data in this report were obtained from sampling and analysis activities implemented under the Y-12 Groundwater Protection Program (GWPP) managed by Babcock & Wilcox Technical Services Y-12, LLC (B&W Y-12) and from sampling and analysis activities implemented under several monitoring programs managed by Bechtel Jacobs Company LLC (BJC). Cooperative implementation of the monitoring programs directed by the Y-12 GWPP and BJC (i.e., coordinating sample collection and sharing data) ensures that the CY 2008 monitoring results fulfill requirements of all the applicable monitoring drivers with no duplication of sampling and analysis efforts. Section 3 of this report contains a summary of information regarding the groundwater and surface water sampling and analysis activities implemented under the Y-12 GWPP including sampling locations and frequency; quality assurance (QA)/quality control (QC) sampling; sample collection and handling; field measurements and laboratory analytes; data management and data quality objective (DQO) evaluation; and groundwater elevation monitoring. However, this report does not include equivalent QA/QC or DQO evaluation information regarding the groundwater and surface water sampling and analysis activities associated with the monitoring programs implemented by BJC. Such details are deferred to the respective programmatic plans and reports issued by BJC (see Section 3.0).« less

Hydrogeochemical and isotopic investigation and water quality assessment of groundwater in the Sisseb El Alem Nadhour Saouaf aquifer (SANS), northeastern Tunisia

NASA Astrophysics Data System (ADS)

Hamdi, Mohamed; Zagrarni, Mohamed Faouzi; Jerbi, Hamza; Tarhouni, Jamila

2018-05-01

In the Sisseb El Alem Nadhour Saouaf basin (SANS), as in all other arid regions, surface water is scarce and groundwater is the greatest most important source of water for all uses. This study aims to identify the processes governing groundwater mineralization in order to assess the suitability of the groundwater for drinking and agriculture purposes. This research used a geodatabase which includes information on hydrogeology, geochemistry, land cover, and geology. We identified the most important factors involved in the deterioration of water quality, including anhydrite and gypsum dissolution, silicate weathering, downward leakage between aquifers, evaporation, groundwater over-exploitation, and the overuse of fertilizers. Furthermore, the two following important factors were identified: the intrusion of Sebkhat El Kelbia and the vertical flow from the deep aquifer. Results were used to develop a conceptual geochemical model, wherein three geochemical regions were differentiated. Statistical techniques, such as Principal Component Analysis (PCA) and Hierarchical Cluster Analysis (HCA) were used to confirm the water affinities and the presence of three different geochemical regions. The water quality index (WQI), Wilcox and Richards's diagrams were performed to assess the suitability of groundwater to drinking and irrigation purposes. These indexes confirm the fact that the groundwater of this aquifer is not suitable for irrigation, neither for drinking. Furthermore, 18O and deuterium isotope data indicate the importance of evaporation in the basin, and the recharge with modern rainfall.

Complex interactions among climate change, sanitation, and groundwater quality: A case study from Ramotswa, Botswana

NASA Astrophysics Data System (ADS)

McGill, B. M.; Altchenko, Y.; Kenabatho, P. K.; Sylvester, S. R.; Villholth, K. G.

2017-12-01

With population growth, rapid urbanization, and climate change, groundwater is becoming an increasingly important source of drinking water around the world, including southern Africa. This is an investigation into the coupled human and natural system linking climate change, droughts, sanitation, and groundwater quality in Ramotswa, a town in the semi-arid southeastern Botswana. During the recent drought from 2013-2016, water shortages from reservoirs that supply the larger city of Gaborone resulted in curtailed water supply to Ramotswa, forcing people with flush toilets to use pit latrines. Pit latrines have been suspected as the cause of elevated nitrate in the Ramotswa groundwater, which also contributes to the town's drinking water supply. The groundwater pollution paradoxically makes Ramotswa dependent on Gaborone's water, supplied in large part by surface reservoirs, which are vulnerable to drought. Analysis of long-term rainfall records indicates that droughts like the one in 2013-2016 are increasing in likelihood due to climate change. Because of the drought, many more people used pit latrines than under normal conditions. Analysis of the groundwater for nitrate and using caffeine as an indicator, human waste leaching from pit latrines is implicated as the major culprit for the nitrate pollution. The results indicate a critical indirect linkage between climate change, sanitation, groundwater quality and water security in this area of rapid urbanization and population growth. Recommendations are offered for how Ramotswa's water security could be made less vulnerable to climate change.

Natural and anthropogenic factors affecting the shallow groundwater quality in a typical irrigation area with reclaimed water, North China Plain.

PubMed

Gu, Xiaomin; Xiao, Yong; Yin, Shiyang; Pan, Xingyao; Niu, Yong; Shao, Jingli; Cui, Yali; Zhang, Qiulan; Hao, Qichen

2017-09-22

In this study, the hydrochemical characteristics of shallow groundwater were analyzed to get insight into the factors affecting groundwater quality in a typical agricultural dominated area of the North China Plain. Forty-four shallow groundwater samples were collected for chemical analysis. The water type changes from Ca·Na-HCO 3 type in grass land to Ca·Na-Cl (+NO 3 ) type and Na (Ca)-Cl (+NO 3 +SO 4 ) type in construction and facility agricultural land, indicating the influence of human activities. The factor analysis and geostatistical analysis revealed that the two major factors contributing to the groundwater hydrochemical compositions were the water-rock interaction and contamination from sewage discharge and agricultural fertilizers. The major ions (F, HCO 3 ) and trace element (As) in the shallow groundwater represented the natural origin, while the nitrate and sulfate concentrations were related to the application of fertilizer and sewage discharge in the facility agricultural area, which was mainly affected by the human activities. The values of pH, total dissolved solids, electric conductivity, and conventional component (K, Ca, Na, Mg, Cl) in shallow groundwater increased from grass land and cultivated land, to construction land and to facility agriculture which were originated from the combination sources of natural processes (e.g., water-rock interaction) and human activities (e.g., domestic effluents). The study indicated that both natural processes and human activities had influences on the groundwater hydrochemical compositions in shallow groundwater, while anthropogenic processes had more contribution, especially in the reclaimed water irrigation area.

Calendar Year 2011 Groundwater Monitoring Report, U.S. Department of Energy Y-12 National Security Complex, Oak Ridge, Tennessee

DOE Office of Scientific and Technical Information (OSTI.GOV)

Elvado Environmental LLC,

2012-12-01

This report contains the groundwater and surface water monitoring data that were obtained during calendar year (CY) 2011 at the U.S. Department of Energy (DOE) Y-12 National Security Complex (Y-12) on the DOE Oak Ridge Reservation (ORR) in Oak Ridge, Tennessee. The CY 2011 monitoring data were obtained from wells, springs, and surface water sampling locations in three hydrogeologic regimes at Y-12. The Bear Creek Hydrogeologic Regime (Bear Creek Regime) encompasses a section of Bear Creek Valley (BCV) between the west end of Y-12 and the west end of the Bear Creek Watershed (directions are in reference to the Y-12more » grid system). The Upper East Fork Poplar Creek Hydrogeologic Regime (East Fork Regime) encompasses the Y-12 industrial facilities and support structures in BCV. The Chestnut Ridge Hydrogeologic Regime (Chestnut Ridge Regime) encompasses a section of Chestnut Ridge directly south of Y-12. This report provides background information pertinent to groundwater and surface water quality monitoring in each hydrogeologic regime, including the topography and bedrock geology, surface water drainage, groundwater system, and known extent of groundwater contamination. The CY 2011 groundwater and surface water monitoring data in this report were obtained from sampling and analysis activities implemented under the Y-12 Groundwater Protection Program (GWPP) managed by Babcock & Wilcox Technical Services Y-12, LLC (B&W Y-12) and from sampling and analysis activities implemented under several monitoring programs managed by the DOE Environmental Management (EM) contractor responsible for environmental cleanup on the ORR. In August 2011, URS | CH2M Oak Ridge LLC (UCOR) replaced Bechtel Jacobs Company LLC (BJC) as the DOE EM contractor. For this report, BJC/UCOR will be referenced as the managing contractor for CY 2011. Cooperative implementation of the monitoring programs directed by the Y-12 GWPP and BJC/UCOR (i.e., coordinating sample collection and sharing data) ensures that the CY 2011 monitoring results fulfill requirements of all the applicable monitoring drivers with no duplication of sampling and analysis efforts. This report contains a summary of information regarding the groundwater and surface water sampling and analysis activities implemented under the Y-12 GWPP including sampling locations and frequency; quality assurance (QA)/quality control (QC) sampling; sample collection and handling; field measurements and laboratory analytes; data management and data quality objective (DQO) evaluation; and groundwater elevation monitoring. However, this report does not include equivalent QA/QC or DQO evaluation information regarding the groundwater and surface water sampling and analysis activities associated with the monitoring programs implemented by BJC/UCOR. Such details are deferred to the respective programmatic plans and reports issued by BJC. Collectively, the groundwater and surface water monitoring data obtained during CY 2011 by the Y-12 GWPP and BJC/UCOR address DOE Order 436.1 and DOE Order 458.1 requirements for monitoring groundwater and surface water quality in areas (1) which are, or could be, affected by operations at Y-12 (surveillance monitoring) and (2) where contaminants from Y-12 are most likely to migrate beyond the boundaries of the ORR (exit pathway/perimeter monitoring). This report presents a summary evaluation of the monitoring data with regard to the respective objectives of surveillance monitoring and exit pathway/perimeter monitoring, based on the analytical results for the principal groundwater contaminants at Y-12: nitrate, uranium, volatile organic compounds (VOCs), gross alpha activity, and gross beta activity. This report summarizes the most pertinent findings regarding the principal contaminants, along with recommendations proposed for ongoing groundwater and surface water quality monitoring performed under the Y-12 GWPP.« less

Calendar Year 2007 Groundwater Monitoring Report, U.S. Department of Energy Y-12 National Security Complex, Oak Ridge, Tennessee

DOE Office of Scientific and Technical Information (OSTI.GOV)

Elvado Environmental LLC

2008-12-01

This report contains the groundwater and surface water monitoring data that were obtained during calendar year (CY) 2007 at the U.S. Department of Energy (DOE) Y-12 National Security Complex (hereafter referenced as Y-12) on the DOE Oak Ridge Reservation (ORR) in Oak Ridge, Tennessee. The CY 2007 monitoring data were obtained from wells, springs, and surface water sampling locations in three hydrogeologic regimes at Y-12 (Figure A.1). The Bear Creek Hydrogeologic Regime (Bear Creek Regime) encompasses a section of Bear Creek Valley (BCV) between the west end of Y-12 and the west end of the Bear Creek Watershed (directions aremore » in reference to the Y-12 grid system). The Upper East Fork Poplar Creek Hydrogeologic Regime (East Fork Regime) encompasses the Y-12 industrial facilities and support structures in BCV. The Chestnut Ridge Hydrogeologic Regime (Chestnut Ridge Regime) encompasses a section of Chestnut Ridge directly south of Y-12. Section 2 of this report provides background information pertinent to groundwater and surface water quality monitoring in each hydrogeologic regime, including the topography and bedrock geology, surface water drainage, groundwater system, and extent of groundwater contamination. The CY 2007 groundwater and surface water monitoring data in this report were obtained from sampling and analysis activities implemented under the Y-12 Groundwater Protection Program (GWPP) managed by BWXT Y-12, L.L.C. (BWXT), and from sampling and analysis activities implemented under several monitoring programs managed by Bechtel Jacobs Company LLC (BJC). In December 2007, the BWXT corporate name was changed to Babcock & Wilcox Technical Services Y-12, LLC (B&W Y-12), which is applied to personnel and organizations throughout CY 2007 for this report. Cooperative implementation of the monitoring programs directed by the Y-12 GWPP and BJC (i.e., coordinating sample collection and sharing data) ensures that the CY 2007 monitoring results fulfill requirements of all the applicable monitoring drivers with no duplication of sampling and analysis efforts. Section 3 of this report contains a summary of information regarding the groundwater and surface water sampling and analysis activities implemented under the Y-12 GWPP including sampling locations and frequency; quality assurance (QA)/quality control (QC) sampling; sample collection and handling; field measurements and laboratory analytes; data management and data quality objective (DQO) evaluation; and groundwater elevation monitoring. However, this report does not include equivalent information regarding the groundwater and surface water sampling and analysis activities associated with the monitoring programs implemented by BJC. Such details are deferred to the respective programmatic plans and reports issued by BJC (see Section 3.0). Collectively, the groundwater and surface water monitoring data obtained during CY 2007 by the Y-12 GWPP and BJC address DOE Order 450.1 (Environmental Protection Program) requirements for monitoring groundwater and surface water quality in areas: (1) which are, or could be, affected by operations at Y-12 (surveillance monitoring); and (2) where contaminants from Y-12 are most likely to migrate beyond the boundaries of the ORR (exit pathway/perimeter monitoring). Section 4 of this report presents a summary evaluation of the monitoring data with regard to the respective objectives of surveillance monitoring and exit pathway/perimeter monitoring, based on the analytical results for the principal groundwater and surface water contaminants at Y-12: nitrate, uranium, volatile organic compounds (VOCs), gross alpha activity, and gross beta activity. Section 5 of this report summarizes the most pertinent findings regarding the principal contaminants, along with recommendations proposed for ongoing groundwater and surface water quality monitoring performed under the Y-12 GWPP.« less

Progress, opportunities, and key fields for groundwater quality research under the impacts of human activities in China with a special focus on western China.

PubMed

Li, Peiyue; Tian, Rui; Xue, Chenyang; Wu, Jianhua

2017-05-01

Groundwater quality research is extremely important for supporting the safety of the water supply and human health in arid and semi-arid areas of China. This review article was constructed to report the latest research progress of groundwater quality in western China where groundwater quality is undergoing fast deterioration because of fast economic development and extensive anthropogenic activities. The opportunities brought by increasing public awareness of groundwater quality protection were also highlighted and discussed. To guide and promote further development of groundwater quality research in China, especially in western China, ten key groundwater quality research fields were proposed. The review shows that the intensification of human activities and the associated impacts on groundwater quality in China, especially in western China, has made groundwater quality research increasingly important, and has caught the attention of local, national, and international agencies and scholars. China has achieved some progress in groundwater quality research in terms of national and regional laws, regulations, and financial supports. The future of groundwater quality research in China, especially in western China, is promising reflected by the opportunities highlighted. The key research fields proposed in this article may also inform groundwater quality protection and management at the national and international level.

An update of hydrologic conditions and distribution of selected constituents in water, eastern Snake River Plain aquifer and perched groundwater zones, Idaho National Laboratory, Idaho, emphasis 2012-15

USGS Publications Warehouse

Bartholomay, Roy C.; Maimer, Neil V.; Rattray, Gordon W.; Fisher, Jason C.

2017-04-10

Since 1952, wastewater discharged to in ltration ponds (also called percolation ponds) and disposal wells at the Idaho National Laboratory (INL) has affected water quality in the eastern Snake River Plain (ESRP) aquifer and perched groundwater zones underlying the INL. The U.S. Geological Survey (USGS), in cooperation with the U.S. Department of Energy, maintains groundwater-monitoring networks at the INL to determine hydrologic trends and to delineate the movement of radiochemical and chemical wastes in the aquifer and in perched groundwater zones. This report presents an analysis of water-level and water-quality data collected from the ESRP aquifer, multilevel monitoring system (MLMS) wells in the ESRP aquifer, and perched groundwater wells in the USGS groundwater monitoring networks during 2012-15.

Y-12 Groundwater Protection Program Groundwater and Surface Water Sampling and Analysis Plan for Calendar Year 2004

DOE Office of Scientific and Technical Information (OSTI.GOV)

Elvado Environmental LLC for the Environmental Compliance Department ES&H Division, Y-12 National Security Complex Oak Ridge, Tennessee

2003-09-30

This plan provides a description of the groundwater and surface water quality monitoring activities planned for calendar year (CY) 2004 at the U.S. Department of Energy (DOE) Y-12 National Security Complex that will be managed by the Y-12 Groundwater Protection Program (GWPP). Groundwater and surface water monitoring performed by the GWPP during CY 2004 will be in accordance with the following requirements of DOE Order 5400.1: (1) to maintain surveillance of existing and potential groundwater contamination sources; (2) to provide for the early detection of groundwater contamination and determine the quality of groundwater and surface water where contaminants are mostmore » likely to migrate beyond the Oak Ridge Reservation property line; (3) to identify and characterize long-term trends in groundwater quality at Y-12; and (4) to provide data to support decisions concerning the management and protection of groundwater resources. Groundwater and surface water monitoring during CY 2004 will be performed primarily in three hydrogeologic regimes at Y-12: the Bear Creek Hydrogeologic Regime (Bear Creek Regime), the Upper East Fork Poplar Creek Hydrogeologic Regime (East Fork Regime), and the Chestnut Ridge Hydrogeologic Regime (Chestnut Ridge Regime). The Bear Creek and East Fork regimes are located in Bear Creek Valley, and the Chestnut Ridge Regime is located south of Y-12 (Figure A.1). Additional surface water monitoring will be performed north of Pine Ridge, along the boundary of the Oak Ridge Reservation (Figure A.1). Modifications to the CY 2004 monitoring program may be necessary during implementation. Changes in programmatic requirements may alter the analytes specified for selected monitoring wells, or wells could be added or removed from the planned monitoring network. All modifications to the monitoring program will be approved by the Y-12 GWPP manager and documented as addenda to this sampling and analysis plan.« less

Y-12 Groundwater Protection Program Groundwater and Surface Water Sampling and Analysis Plan for Calendar Year 2005

DOE Office of Scientific and Technical Information (OSTI.GOV)

None

2004-09-30

This plan provides a description of the groundwater and surface water quality monitoring activities planned for calendar year (CY) 2005 at the U.S. Department of Energy (DOE) Y-12 National Security Complex (Y-12) that will be managed by the Y-12 Groundwater Protection Program (GWPP). Groundwater and surface water monitoring performed by the GWPP during CY 2005 will be in accordance with DOE Order 540.1 requirements and the following goals: (1) to maintain surveillance of existing and potential groundwater contamination sources; (2) to provide for the early detection of groundwater contamination and determine the quality of groundwater and surface water where contaminantsmore » are most likely to migrate beyond the Oak Ridge Reservation property line; (3) to identify and characterize long-term trends in groundwater quality at Y-12; and (4) to provide data to support decisions concerning the management and protection of groundwater resources. Groundwater and surface water monitoring during CY 2005 will be performed primarily in three hydrogeologic regimes at Y-12: the Bear Creek Hydrogeologic Regime (Bear Creek Regime), the Upper East Fork Poplar Creek Hydrogeologic Regime (East Fork Regime), and the Chestnut Ridge Hydrogeologic Regime (Chestnut Ridge Regime). The Bear Creek and East Fork regimes are located in Bear Creek Valley, and the Chestnut Ridge Regime is located south of Y-12 (Figure A.1). Additional surface water monitoring will be performed north of Pine Ridge, along the boundary of the Oak Ridge Reservation (Figure A.1). Modifications to the CY 2005 monitoring program may be necessary during implementation. Changes in programmatic requirements may alter the analytes specified for selected monitoring wells or may add or remove wells from the planned monitoring network. All modifications to the monitoring program will be approved by the Y-12 GWPP manager and documented as addenda to this sampling and analysis plan.« less

Intensive rice agriculture deteriorates the quality of shallow groundwater in a typical agricultural catchment in subtropical central China.

PubMed

Wang, Yi; Li, Yuyuan; Li, Yong; Liu, Feng; Liu, Xinliang; Gong, Dianlin; Ma, Qiumei; Li, Wei; Wu, Jinshui

2015-09-01

High nitrogen (N) concentrations in rural domestic water supplies have been attributed to excessive agricultural N leaching into shallow groundwater systems; therefore, it is important to determine the impact of agriculture (e.g., rice production) on groundwater quality. To understand the impact of agricultural land use on the N concentrations in the shallow groundwater in subtropical central China, a large observation program was established to observe ammonium-N (NH4-N), nitrate-N (NO3-N), and total N (TN) concentrations in 161 groundwater observation wells from April 2010 to November 2012. The results indicated that the median values of NH4-N, NO3-N, and TN concentrations in the groundwater were 0.15, 0.39, and 1.38 mg N L(-1), respectively. A total of 36.3 % of the water samples were categorized as NH4-N pollution, and only a small portion of the samples were categorized as NO3-N pollution, based on the Chinese Environmental Quality Standards for Groundwater of GB/T 14848-93 (General Administration of Quality Supervision of China, 1993). These results indicated of moderate groundwater NH4-N pollution, which was mainly attributed to intensive rice agriculture with great N fertilizer application rates in the catchment. In addition, tea and vegetable fields showed higher groundwater NO3-N and TN concentrations than other agricultural land use types. The factorial correspondence analysis (FCA) suggested that the flooded agricultural land use types (e.g., single-rice and double-rice) had potential to impose NH4-N pollution, particularly in the soil exhausting season during from July to October. And, the great N fertilizer application rates could lead to a worse NO3-N and TN pollution in shallow groundwater. Hence, to protect groundwater quality and minimize NH4-N pollution, managing optimal fertilizer application and applying appropriate agricultural land use types should be implemented in the region.

Effects of seasonal change and seawater intrusion on water quality for drinking and irrigation purposes, in coastal aquifers of Dar es Salaam, Tanzania

NASA Astrophysics Data System (ADS)

Sappa, Giuseppe; Ergul, Sibel; Ferranti, Flavia; Sweya, Lukuba Ngalya; Luciani, Giulia

2015-05-01

Groundwater is the major source to meet domestic, industrial and agricultural needs in the city of Dar es Salaam, Tanzania. However, population growth, increasing urbanization, industrialization and tourism, and climatic changes have caused an intensive exploitation of groundwater resources leading the aquifers become more vulnerable to seawater intrusion. The aim of this study is to examine the variations of groundwater chemistry (as resulting from natural and anthropogenic inputs) depending on seasonal changes, in order to evaluate water quality for drinking and irrigation purposes. Physical and chemical data come from the analysis of groundwater samples, collected from 72 wells, used for the evaluation of water quality parameters, during a year of monitoring. Pattern diagrams, geochemical modeling techniques and Principal Component Analysis (PCA) have been used to identify the main factors influencing groundwater composition. Based on the hydrochemistry, the groundwater was classified into three types: (a) Na-Cl, (b) Ca-Cl, (c) mixed Ca-Na-HCO3-Cl (d) mixed Ca-Mg-Cl-SO4. The geochemical modeling results show that groundwater chemistry is mainly influenced by evaporation process, as it is suggested by the increase of Na and Cl ions concentrations. According to irrigation water quality assessment diagrams of USDA, most water samples from dry and rainy seasons, distributed in category C2-S1, C3-S1, C3-S2, C4-S2 highlighting medium to very high salinity hazard and low to medium sodium content class. PCA evidenced the role of seawater intrusion, evaporation process and anthropogenic pollution (i.e. high NO3 levels due to agricultural activities), as the major factors that influenced the water chemistry, and hence the water quality. Based on Pearson correlation matrix, the presence of high correlations (>0.8) among Na, Cl, Mg and SO4, in association with EC, were interpreted as the seawater intrusion effects. In this area groundwater quality is generally low, and often exceeds permissible limits of standard guideline values of WHO and FAO, referred to EC and chloride values. The high salinity and the groundwater level depletion create serious problems for current use of water supplies as well as future exploitation.

Water quality data for selected wells in the Coastal Plain of New Jersey, 1996-98

USGS Publications Warehouse

Hibbs, Kathleen L.; Stackelberg, Paul E.; Kauffman, Leon J.; Ayers, Mark A.

2001-01-01

Water-quality data were collected during 1996-98 for 217 wells in New Jersey and 3 wells in New York as part of the U. S. Geological Survey's National Water Quality Assessment Program. Samples were collected for five ground-water surveys that were designed to assess water quality in major aquifer systems, with an emphasis on recently recharged (shallow) ground water associated with present and recent human activities. This report (1) summarizes the hydrogeologic framework in the areas of data collection; (2) describes the objectives and procedures for designing each ground-water survey; (3) summarizes the procedures and protocols for data collec-tion, analysis, and quality control; and (4) lists the concentrations of inorganic constituents, volatile organic compounds, pesticides, nutrients, and trace elements present in the ground-water samples.

An early warning system for groundwater pollution based on the assessment of groundwater pollution risks.

NASA Astrophysics Data System (ADS)

Zhang, Weihong.; Zhao, Yongsheng; Hong, Mei; Guo, Xiaodong

2009-04-01

Groundwater pollution usually is complex and concealed, remediation of which is difficult, high cost, time-consuming, and ineffective. An early warning system for groundwater pollution is needed that detects groundwater quality problems and gets the information necessary to make sound decisions before massive groundwater quality degradation occurs. Groundwater pollution early warning were performed by considering comprehensively the current groundwater quality, groundwater quality varying trend and groundwater pollution risk . The map of the basic quality of the groundwater was obtained by fuzzy comprehensive evaluation or BP neural network evaluation. Based on multi-annual groundwater monitoring datasets, Water quality state in sometime of the future was forecasted using time-sequenced analyzing methods. Water quality varying trend was analyzed by Spearman's rank correlative coefficient.The relative risk map of groundwater pollution was estimated through a procedure that identifies, cell by cell,the values of three factors, that is inherent vulnerability, load risk of pollution source and contamination hazard. DRASTIC method was used to assess inherent vulnerability of aquifer. Load risk of pollution source was analyzed based on the potential of contamination and pollution degree. Assessment index of load risk of pollution source which involves the variety of pollution source, quantity of contaminants, releasing potential of pollutants, and distance were determined. The load risks of all sources considered by GIS overlay technology. Early warning model of groundwater pollution combined with ComGIS technology organically, the regional groundwater pollution early-warning information system was developed, and applied it into Qiqiha'er groundwater early warning. It can be used to evaluate current water quality, to forecast water quality changing trend, and to analyze space-time influencing range of groundwater quality by natural process and human activities. Keywords: groundwater pollution, early warning, aquifer vulnerability, pollution load, pollution risk, ComGIS

Modeling Effects of Groundwater Basin Closure, and Reversal of Closure, on Groundwater Quality

NASA Astrophysics Data System (ADS)

Pauloo, R.; Guo, Z.; Fogg, G. E.

2017-12-01

Population growth, the expansion of agriculture, and climate uncertainties have accelerated groundwater pumping and overdraft in aquifers worldwide. In many agricultural basins, a water budget may be stable or not in overdraft, yet disconnected ground and surface water bodies can contribute to the formation of a "closed" basin, where water principally exits the basin as evapotranspiration. Although decreasing water quality associated with increases in Total Dissolved Solids (TDS) have been documented in aquifers across the United States in the past half century, connections between water quality declines and significant changes in hydrologic budgets leading to closed basin formation remain poorly understood. Preliminary results from an analysis with a regional-scale mixing model of the Tulare Lake Basin in California indicate that groundwater salinization resulting from open to closed basin conversion can operate on a decades-to-century long time scale. The only way to reverse groundwater salinization caused by basin closure is to refill the basin and change the hydrologic budget sufficiently for natural groundwater discharge to resume. 3D flow and transport modeling, including the effects of heterogeneity based on a hydrostratigraphic facies model, is used to explore rates and time scales of groundwater salinization and its reversal under different water and land management scenarios. The modeling is also used to ascertain the extent to which local and regional heterogeneity need to be included in order to appropriately upscale the advection-dispersion equation in a basin scale groundwater quality management model. Results imply that persistent managed aquifer recharge may slow groundwater salinization, and complete reversal may be possible at sufficiently high water tables.

Quality and age of shallow groundwater in the Bakken Formation production area, Williston Basin, Montana and North Dakota

USGS Publications Warehouse

McMahon, Peter B.; Caldwell, Rodney R.; Galloway, Joel M.; Valder, Joshua F.; Hunt, Andrew G.

2015-01-01

The quality and age of shallow groundwater in the Bakken Formation production area were characterized using data from 30 randomly distributed domestic wells screened in the upper Fort Union Formation. Comparison of inorganic and organic chemical concentrations to health based drinking-water standards, correlation analysis of concentrations with oil and gas well locations, and isotopic data give no indication that energy-development activities affected groundwater quality. It is important, however, to consider these results in the context of groundwater age. Most samples were recharged before the early 1950s and had 14C ages ranging from 30,000 years. Thus, domestic wells may not be as well suited for detecting contamination associated with recent surface spills as shallower wells screened near the water table. Old groundwater could be contaminated directly by recent subsurface leaks from imperfectly cemented oil and gas wells, but horizontal groundwater velocities calculated from 14C ages imply that the contaminants would still be less than 0.5 km from their source. For the wells sampled in this study, the median distance to the nearest oil and gas well was 4.6 km. Because of the slow velocities, a long-term commitment to groundwater monitoring in the upper Fort Union Formation is needed to assess the effects of energy development on groundwater quality. In conjunction with that effort, monitoring could be done closer to energy-development activities to increase the likelihood of early detection of groundwater contamination if it did occur.

Determination of trigger levels for groundwater quality in landfills located in historically human-impacted areas.

PubMed

Stefania, Gennaro A; Zanotti, Chiara; Bonomi, Tullia; Fumagalli, Letizia; Rotiroti, Marco

2018-05-01

Landfills are one of the most recurrent sources of groundwater contamination worldwide. In order to limit their impacts on groundwater resources, current environmental regulations impose the adoption of proper measures for the protection of groundwater quality. For instance, in the EU member countries, the calculation of trigger levels for identifying significant adverse environmental effects on groundwater generated by landfills is required by the Landfill Directive 99/31/EC. Although the derivation of trigger levels could be relatively easy when groundwater quality data prior to the construction of a landfill are available, it becomes challenging when these data are missing and landfills are located in areas that are already impacted by historical contamination. This work presents a methodology for calculating trigger levels for groundwater quality in landfills located in areas where historical contaminations have deteriorated groundwater quality prior to their construction. This method is based on multivariate statistical analysis and involves 4 steps: (a) implementation of the conceptual model, (b) landfill monitoring data collection, (c) hydrochemical data clustering and (d) calculation of the trigger levels. The proposed methodology was applied on a case study in northern Italy, where a currently used lined landfill is located downstream of an old unlined landfill and others old unmapped waste deposits. The developed conceptual model stated that groundwater quality deterioration observed downstream of the lined landfill is due to a degrading leachate plume fed by the upgradient unlined landfill. The methodology led to the determination of two trigger levels for COD and NH 4 -N, the former for a zone representing the background hydrochemistry (28 and 9 mg/L for COD and NH 4 -N, respectively), the latter for the zone impacted by the degrading leachate plume from the upgradient unlined landfill (89 and 83 mg/L for COD and NH 4 -N, respectively). Copyright © 2018 Elsevier Ltd. All rights reserved.

Groundwater quality data from the National Water-Quality Assessment Project, May 2012 through December 2013

USGS Publications Warehouse

Arnold, Terri L.; Desimone, Leslie A.; Bexfield, Laura M.; Lindsey, Bruce D.; Barlow, Jeannie R.; Kulongoski, Justin T.; Musgrove, MaryLynn; Kingsbury, James A.; Belitz, Kenneth

2016-06-20

Groundwater-quality data were collected from 748 wells as part of the National Water-Quality Assessment Project of the U.S. Geological Survey National Water-Quality Program from May 2012 through December 2013. The data were collected from four types of well networks: principal aquifer study networks, which assess the quality of groundwater used for public water supply; land-use study networks, which assess land-use effects on shallow groundwater quality; major aquifer study networks, which assess the quality of groundwater used for domestic supply; and enhanced trends networks, which evaluate the time scales during which groundwater quality changes. Groundwater samples were analyzed for a large number of water-quality indicators and constituents, including major ions, nutrients, trace elements, volatile organic compounds, pesticides, and radionuclides. These groundwater quality data are tabulated in this report. Quality-control samples also were collected; data from blank and replicate quality-control samples are included in this report.

California GAMA Special Study: Analysis of Carbamazepine, Oxcarbazepine and Metabolites as Wastewater Tracers in Water Resource Studies

DOE Office of Scientific and Technical Information (OSTI.GOV)

Owens, J. E.; Vu, A. K.; Esser, B. K.

2010-08-20

The Groundwater Ambient Monitoring and Assessment (GAMA) Program is a comprehensive groundwater quality monitoring program managed by the California State Water Resources Control Board (SWRCB). The GAMA Special Studies project provides analyses and interpretation of constituents of concern that allow assessment of current groundwater conditions. In addition, the Special Studies project develops analyses that will enhance the monitoring and assessment effort by focusing on specific constituents of concern and water quality parameters, such as disinfection byproducts (DBP), wastewater indicators, and redox conditions, as it relates to irrigation and groundwater management. This study developed a robust analytical method for the quantitationmore » of CBZ, OXC, CBZ-E, CBZ-DiOH, and CBZ-10-OH in wastewater treatement plant (WWTP) effluent and in groundwater in the parts per trillion range.« less

Quality modeling of drinking groundwater using GIS in rural communities, northwest of Iran

PubMed Central

2014-01-01

Given the importance of groundwater resources in water supply, this work aimed to study quality of drinking groundwater in rural areas in Tabriz county, northwest of Iran. Thirty two groundwater samples from different areas were collected and analyzed in terms of general parameters along with 20 heavy metals (e.g. As, Hg and …). The data of the analyses were applied as an attribute database for preparing thematic maps and showing water quality parameters. Multivariate statistical techniques, including principal component analysis (PCA) and hierarchical cluster analysis (CA) were used to compare and evaluate water quality. The findings showed that hydrochemical faces of the groundwater were of calcium-bicarbonate type. EC values were from 110 to 1750 μs/cm, in which concentration of salts was high in the east and a zone in north of the studied area. Hardness was from 52 to 476 mg/l and CaCO3 with average value of 185.88 ± 106.56 mg/L indicated hard water. Dominant cations and anions were Ca2+ > Na+ > Mg2+ > K+ and HCO3− > Cl− > SO42− > NO32, respectively. In the western areas, arsenic contamination was observed as high as 69 μg/L. Moreover, mercury was above the standard level in one of the villages. Eskandar and Olakandi villages had the lowest quality of drinking water. In terms of CA, sampling sites were classified into four clusters of similar water quality and PCA demonstrated that 3 components could cover 84.3% of the parameters. For investigating arsenic anomaly, conducting a comprehensive study in the western part of studied area is strongly recommended. PMID:25093080

Chemical characteristics of groundwater and assessment of groundwater quality in Varaha River Basin, Visakhapatnam District, Andhra Pradesh, India.

PubMed

Rao, N Subba; Rao, P Surya; Reddy, G Venktram; Nagamani, M; Vidyasagar, G; Satyanarayana, N L V V

2012-08-01

Study on chemical characteristics of groundwater and impacts of groundwater quality on human health, plant growth, and industrial sector is essential to control and improve the water quality in every part of the country. The area of the Varaha River Basin is chosen for the present study, where the Precambrian Eastern Ghats underlain the Recent sediments. Groundwater quality is of mostly brackish and very hard, caused by the sources of geogenic, anthropogenic, and marine origin. The resulting groundwater is characterized by Na(+) > Mg(2+) > Ca(2+) : [Formula: see text] > Cl(-) > [Formula: see text], Na(+) > Mg(2+) > Ca(2+) : [Formula: see text] > Cl(-) > [Formula: see text] > [Formula: see text], Na(+) > Mg(2+) > Ca(2+) : [Formula: see text] > Cl(-), and Na(+) > Mg(2+) > Ca(2+) : Cl(-) > [Formula: see text] > [Formula: see text] facies, following the topographical and water flow-path conditions. The genetic geochemical evolution of groundwater ([Formula: see text] and Cl(-)-[Formula: see text] types under major group of [Formula: see text]) and the hydrogeochemical signatures (Na(+)/Cl(-), >1 and [Formula: see text]/Cl(-), <1) indicate that the groundwater is of originally fresh quality, but is subsequently modified to brackish by the influences of anthropogenic and marine sources, which also supported by the statistical analysis. The concentrations of total dissolved solids (TDS), TH, Mg(2+), Na(+), K(+), [Formula: see text], Cl(-), [Formula: see text], and F(-) are above the recommended limits prescribed for drinking water in many locations. The quality of groundwater is of mostly moderate in comparison with the salinity hazard versus sodium hazard, the total salt concentration versus percent sodium, the residual sodium carbonate, and the magnesium hazard, but is of mostly suitable with respect to the permeability index for irrigation. The higher concentrations of TDS, TH, [Formula: see text], Cl(-), and [Formula: see text] in the groundwater cause the undesirable effects of incrustation and corrosion in many locations. Appropriate management measures are, therefore, suggested to improve the groundwater quality.

Ground-water quality assessment of the central Oklahoma Aquifer, Oklahoma; project description

USGS Publications Warehouse

Christenson, S.C.; Parkhurst, D.L.

1987-01-01

In April 1986, the U.S. Geological Survey began a pilot program to assess the quality of the Nation's surface-water and ground-water resources. The program, known as the National Water-Quality Assessment (NAWQA) program, is designed to acquire and interpret information about a variety of water-quality issues. The Central Oklahoma aquifer project is one of three ground-water pilot projects that have been started. The NAWQA program also incudes four surface-water pilot projects. The Central Oklahoma aquifer project, as part of the pilot NAWQA program, will develop and test methods for performing assessments of ground-water quality. The objectives of the Central Oklahoma aquifer assessment are: (1) To investigate regional ground-water quality throughout the aquifer in the manner consistent with the other pilot ground-water projects, emphasizing the occurrence and distribution of potentially toxic substances in ground water, including trace elements, organic compounds, and radioactive constituents; (2) to describe relations between ground-water quality, land use, hydrogeology, and other pertinent factors; and (3) to provide a general description of the location, nature, and possible causes of selected prevalent water-quality problems within the study unit; and (4) to describe the potential for water-quality degradation of ground-water zones within the study unit. The Central Oklahoma aquifer, which includes in descending order the Garber Sandstone and Wellington Formation, the Chase Group, the Council Grove Group, the Admire Group, and overlying alluvium and terrace deposits, underlies about 3,000 square miles of central Oklahoma and is used extensively for municipal, industrial, commercial, and domestic water supplies. The aquifer was selected for study by the NAWQA program because it is a major source for water supplies in central Oklahoma and because it has several known or suspected water-quality problems. Known problems include concentrations of arsenic, chromium, selenium, and gross-alpha activity that exceed drinking-water standards. Suspected problems include possible contamination of the aquifer by oil-field brines and drilling fluids, pesticides, industrial chemicals, septic-tank effluent, fertilizers, and leakage from sewage systems and underground tanks used for storage of hydrocarbons. There are four major components of the Central Oklahoma aquifer project. The first component is the collection and analysis of existing information, including chemical, hydrologic, and land-use data. The second component is the geohydrologic and geochemical investigations of the aquifer flow system. The third component is the sampling for a wide variety of inorganic, organic, and radioactive constituents as part a regional survey that will produce a consistent set of data among all ground-water pilot projects. These data can be used to: (1) Define regional ground-water quality within the Central Oklahoma aquifer, and (2) compare water quality in the Central Oklahoma aquifer to the water quality in the other ground-water study units of the NAWQA program. The fourth component is topical studies that will address, in more detail, some of the major water-quality issues pertaining to the aquifer.

Groundwater monitoring plan for the Missouri River alluvial aquifer in the vicinity of the City of Independence, Missouri, well field

USGS Publications Warehouse

Wilkison, Donald H.

2012-01-01

Source contributions to monitoring and supply wells, contributing recharge areas, groundwater travel times, and current (2012) understanding of alluvial water quality were used to develop a groundwater monitoring plan for the Missouri River alluvial aquifer in the vicinity of the City of Independence, Missouri well field. The plan was designed to evaluate long-term alluvial water quality and assess potential changes in, and threats to, well-field water quality. Source contributions were determined from an existing groundwater flow model in conjunction with particle-tracking analysis and verified with water-quality data collected from 1997 through 2010 from a network of 68 monitoring wells. Three conjunctive factors - well-field pumpage, Missouri River discharge, and aquifer recharge - largely determined groundwater flow and, therefore, source contributions. The predominant source of groundwater to most monitoring wells and supply wells is the Missouri River, and this was reflected, to some extent, in alluvial water quality. To provide an estimate of the maximum potential lead time available for remedial action, monitoring wells where groundwater travel times from the contributing recharge areas are less than 2 years and predominately singular sources (such as the Missouri River or the land surface) were selected for annual sampling. The sample interval of the remaining wells, which have varying travel times and intermediate mixtures of river and land-surface contributions, were staggered on a 2-, 3-, or 4-year rotation. This was done to provide data from similar contributing areas and account for inherent aquifer variability yet minimize sample redundancy.

Groundwater-quality data from the National Water-Quality Assessment Project, January through December 2014 and select quality-control data from May 2012 through December 2014

USGS Publications Warehouse

Arnold, Terri L.; Bexfield, Laura M.; Musgrove, MaryLynn; Lindsey, Bruce D.; Stackelberg, Paul E.; Barlow, Jeannie R.; Desimone, Leslie A.; Kulongoski, Justin T.; Kingsbury, James A.; Ayotte, Joseph D.; Fleming, Brandon J.; Belitz, Kenneth

2017-10-05

Groundwater-quality data were collected from 559 wells as part of the National Water-Quality Assessment Project of the U.S. Geological Survey National Water-Quality Program from January through December 2014. The data were collected from four types of well networks: principal aquifer study networks, which are used to assess the quality of groundwater used for public water supply; land-use study networks, which are used to assess land-use effects on shallow groundwater quality; major aquifer study networks, which are used to assess the quality of groundwater used for domestic supply; and enhanced trends networks, which are used to evaluate the time scales during which groundwater quality changes. Groundwater samples were analyzed for a large number of water-quality indicators and constituents, including major ions, nutrients, trace elements, volatile organic compounds, pesticides, radionuclides, and some constituents of special interest (arsenic speciation, chromium [VI] and perchlorate). These groundwater-quality data, along with data from quality-control samples, are tabulated in this report and in an associated data release.

Geohydrology of the Antelope Valley Area, California and design for a ground-water-quality monitoring network

USGS Publications Warehouse

Duell, L.F.

1987-01-01

A basinwide ideal network and an actual network were designed to identify ambient groundwater quality, trends in groundwater quality, and degree of threat from potential pollution sources in Antelope Valley, California. In general, throughout the valley groundwater quality has remained unchanged, and no specific trends are apparent. The main source of groundwater for the valley is generally suitable for domestic, irrigation, and most industrial uses. Water quality data for selected constituents of some network wells and surface-water sites are presented. The ideal network of 77 sites was selected on the basis of site-specific criteria, geohydrology, and current land use (agricultural, residential, and industrial). These sites were used as a guide in the design of the actual network consisting of 44 existing wells. Wells are currently being monitored and were selected whenever possible because of budgetary constraints. Of the remaining ideal sites, 20 have existing wells not part of a current water quality network, and 13 are locations where no wells exist. The methodology used for the selection of sites, constituents monitored, and frequency of analysis will enable network users to make appropriate future changes to the monitoring network. (USGS)

Ground-water quality in Douglas County, western Nevada

USGS Publications Warehouse

Garcia, K.T.

1989-01-01

A 182% increase in population within the last 10 years in Douglas County, Nevada, has raised concerns by county officials as to the possible effects land development may have on groundwater quality. Most groundwater in Douglas County meets the State of Nevada drinking water standards. Of the 333 water samples used in this analysis, 6 equaled or were greater than the drinking water standards for sulfates, 44 for fluoride, 4 for dissolved solids, 5 for nitrate as nitrate, 12 for arsenic, 33 for iron, and 18 for manganese. Groundwater in the west-central, northern, and northeastern part of Carson Valley is influenced by geothermal water. Some areas in the county may have septic-tank effluent contaminating the groundwater. Temporal changes in most municipal wells showed no overall trend for dissolved-solids and nitrate concentrations spanning the years 1969-83. However, a municipal well in the Topaz Lake area has shown a general increases in the nitrate concentration from 1961 to 1984, but the concentration does not exceed the drinking-water standard. A future groundwater quality monitoring program in Douglas County would include periodic sampling of primary or heavily pumped wells, long-term trend wells, and supplemental wells. (Thacker-USGS)

Quality and age of shallow groundwater in the Bakken Formation production area, Williston Basin, Montana and North Dakota.

PubMed

McMahon, P B; Caldwell, R R; Galloway, J M; Valder, J F; Hunt, A G

2015-04-01

The quality and age of shallow groundwater in the Bakken Formation production area were characterized using data from 30 randomly distributed domestic wells screened in the upper Fort Union Formation. Comparison of inorganic and organic chemical concentrations to health based drinking-water standards, correlation analysis of concentrations with oil and gas well locations, and isotopic data give no indication that energy-development activities affected groundwater quality. It is important, however, to consider these results in the context of groundwater age. Most samples were recharged before the early 1950s and had 14C ages ranging from <1000 to >30,000 years. Thus, domestic wells may not be as well suited for detecting contamination associated with recent surface spills as shallower wells screened near the water table. Old groundwater could be contaminated directly by recent subsurface leaks from imperfectly cemented oil and gas wells, but horizontal groundwater velocities calculated from 14C ages imply that the contaminants would still be less than 0.5 km from their source. For the wells sampled in this study, the median distance to the nearest oil and gas well was 4.6 km. Because of the slow velocities, a long-term commitment to groundwater monitoring in the upper Fort Union Formation is needed to assess the effects of energy development on groundwater quality. In conjunction with that effort, monitoring could be done closer to energy-development activities to increase the likelihood of early detection of groundwater contamination if it did occur. Published 2014. This article is a U.S. Government work and is in the public domain in the USA.

Calendar Year 2009 Groundwater Monitoring Report, U.S. Department of Energy, Y-12 National Security Complex, Oak Ridge, Tennessee

DOE Office of Scientific and Technical Information (OSTI.GOV)

Elvado Environmental LLC

2010-12-01

This report contains the groundwater and surface water monitoring data that were obtained during calendar year (CY) 2009 at the U.S. Department of Energy (DOE) Y-12 National Security Complex (hereafter referenced as Y-12) on the DOE Oak Ridge Reservation (ORR) in Oak Ridge, Tennessee. The CY 2009 monitoring data were obtained from wells, springs, and surface water sampling locations in three hydrogeologic regimes at Y-12. The Bear Creek Hydrogeologic Regime (Bear Creek Regime) encompasses a section of Bear Creek Valley (BCV) between the west end of Y-12 and the west end of the Bear Creek Watershed (directions are in referencemore » to the Y-12 grid system). The Upper East Fork Poplar Creek Hydrogeologic Regime (East Fork Regime) encompasses the Y-12 industrial facilities and support structures in BCV. The Chestnut Ridge Hydrogeologic Regime (Chestnut Ridge Regime) encompasses a section of Chestnut Ridge directly south of Y-12. Section 2 of this report provides background information pertinent to groundwater and surface water quality monitoring in each hydrogeologic regime, including the topography and bedrock geology, surface water drainage, groundwater system, and extent of groundwater contamination. The CY 2009 groundwater and surface water monitoring data in this report were obtained from sampling and analysis activities implemented under the Y-12 Groundwater Protection Program (GWPP) managed by Babcock & Wilcox Technical Services Y-12, LLC (B&W Y-12) and from sampling and analysis activities implemented under several monitoring programs managed by Bechtel Jacobs Company LLC (BJC). Cooperative implementation of the monitoring programs directed by the Y-12 GWPP and BJC (i.e., coordinating sample collection and sharing data) ensures that the CY 2009 monitoring results fulfill requirements of all the applicable monitoring drivers with no duplication of sampling and analysis efforts. Section 3 of this report contains a summary of information regarding the groundwater and surface water sampling and analysis activities implemented under the Y-12 GWPP including sampling locations and frequency; quality assurance (QA)/quality control (QC) sampling; sample collection and handling; field measurements and laboratory analytes; data management and data quality objective (DQO) evaluation; and groundwater elevation monitoring. However, this report does not include equivalent QA/QC or DQO evaluation information regarding the groundwater and surface water sampling and analysis activities associated with the monitoring programs implemented by BJC. Such details are deferred to the respective programmatic plans and reports issued by BJC (see Section 3.0). Collectively, the groundwater and surface water monitoring data obtained during CY 2009 by the Y-12 GWPP and BJC address DOE Order 450.1A (Environmental Protection Program) requirements for monitoring groundwater and surface water quality in areas: (1) which are, or could be, affected by operations at Y-12 (surveillance monitoring); and (2) where contaminants from Y-12 are most likely to migrate beyond the boundaries of the ORR (exit pathway/perimeter monitoring). Section 4 of this report presents a summary evaluation of the monitoring data with regard to the respective objectives of surveillance monitoring and exit pathway/perimeter monitoring, based on the analytical results for the principal groundwater contaminants at Y-12: nitrate, uranium, volatile organic compounds (VOCs), gross alpha activity, and gross beta activity. Section 5 of this report summarizes the most pertinent findings regarding the principal contaminants, along with recommendations proposed for ongoing groundwater and surface water quality monitoring performed under the Y-12 GWPP. Narrative sections of this report reference several appendices. Figures (maps and diagrams) and tables (excluding data summary tables presented in the narrative sections) are in Appendix A and Appendix B, respectively. Appendix C contains construction details for the wells in each regime that were sampled during CY 2009 by either the Y-12 GWPP or BJC. Field measurements recorded during collection of the groundwater and surface water samples and results of laboratory analyses of the samples are in Appendix D (Bear Creek Regime), Appendix E (East Fork Regime and surrounding areas), and Appendix F (Chestnut Ridge Regime). Appendix G contains data for the QA/QC samples associated with monitoring performed in each regime by the Y-12 GWPP.« less

Hydrochemical characteristics and quality assessment of groundwater along the Manavalakurichi coast, Tamil Nadu, India

NASA Astrophysics Data System (ADS)

Srinivas, Y.; Aghil, T. B.; Hudson Oliver, D.; Nithya Nair, C.; Chandrasekar, N.

2017-06-01

The present study was carried out to find the groundwater quality of coastal aquifer along Manavalakurichi coast. For this study, a total of 30 groundwater samples were collected randomly from open wells and borewells. The concentration of major ions and other geochemical parameters in the groundwater were analyzed in the laboratory by adopting standard procedures suggested by the American Public Health Association. The order of the dominant cations in the study area was found to be Na+ > Ca2+ > Mg2+ > K+, whereas the sequence of dominant anions was {{Cl}}^{ - } > {{HCO}}3^{ - } > {{SO}}4^{2 - }. The hydrogeochemical facies of the groundwater samples were studied by constructing piper trilinear diagram which revealed the evidence of saltwater intrusion into the study area. The obtained geochemical parameters were compared with the standard permissible limits suggested by the World Health Organization and Indian Standard Institution to determine the drinking water quality in the study area. The analysis suggests that the groundwater from the wells W25 and W26 is unsuitable for drinking. The suitability of groundwater for irrigation was studied by calculating percent sodium, sodium absorption ratio and residual sodium carbonate values. The Wilcox and USSL plots were also prepared. It was found that the groundwater from the stations W1, W25 and W26 is unfit for irrigation. The Gibbs plots were also sketched to study the mechanisms controlling the geochemical composition of groundwater in the study area.

Groundwater-quality data for the Sierra Nevada study unit, 2008: Results from the California GAMA program

USGS Publications Warehouse

Shelton, Jennifer L.; Fram, Miranda S.; Munday, Cathy M.; Belitz, Kenneth

2010-01-01

Groundwater quality in the approximately 25,500-square-mile Sierra Nevada study unit was investigated in June through October 2008, as part of the Priority Basin Project of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The GAMA Priority Basin Project is being conducted by the U.S. Geological Survey (USGS) in cooperation with the California State Water Resources Control Board (SWRCB). The Sierra Nevada study was designed to provide statistically robust assessments of untreated groundwater quality within the primary aquifer systems in the study unit, and to facilitate statistically consistent comparisons of groundwater quality throughout California. The primary aquifer systems (hereinafter, primary aquifers) are defined by the depth of the screened or open intervals of the wells listed in the California Department of Public Health (CDPH) database of wells used for public and community drinking-water supplies. The quality of groundwater in shallower or deeper water-bearing zones may differ from that in the primary aquifers; shallow groundwater may be more vulnerable to contamination from the surface. In the Sierra Nevada study unit, groundwater samples were collected from 84 wells (and springs) in Lassen, Plumas, Butte, Sierra, Yuba, Nevada, Placer, El Dorado, Amador, Alpine, Calaveras, Tuolumne, Madera, Mariposa, Fresno, Inyo, Tulare, and Kern Counties. The wells were selected on two overlapping networks by using a spatially-distributed, randomized, grid-based approach. The primary grid-well network consisted of 30 wells, one well per grid cell in the study unit, and was designed to provide statistical representation of groundwater quality throughout the entire study unit. The lithologic grid-well network is a secondary grid that consisted of the wells in the primary grid-well network plus 53 additional wells and was designed to provide statistical representation of groundwater quality in each of the four major lithologic units in the Sierra Nevada study unit: granitic, metamorphic, sedimentary, and volcanic rocks. One natural spring that is not used for drinking water was sampled for comparison with a nearby primary grid well in the same cell. Groundwater samples were analyzed for organic constituents (volatile organic compounds [VOC], pesticides and pesticide degradates, and pharmaceutical compounds), constituents of special interest (N-nitrosodimethylamine [NDMA] and perchlorate), naturally occurring inorganic constituents (nutrients, major ions, total dissolved solids, and trace elements), and radioactive constituents (radium isotopes, radon-222, gross alpha and gross beta particle activities, and uranium isotopes). Naturally occurring isotopes and geochemical tracers (stable isotopes of hydrogen and oxygen in water, stable isotopes of carbon, carbon-14, strontium isotopes, and tritium), and dissolved noble gases also were measured to help identify the sources and ages of the sampled groundwater. Three types of quality-control samples (blanks, replicates, and samples for matrix spikes) each were collected at approximately 10 percent of the wells sampled for each analysis, and the results for these samples were used to evaluate the quality of the data for the groundwater samples. Field blanks rarely contained detectable concentrations of any constituent, suggesting that contamination from sample collection, handling, and analytical procedures was not a significant source of bias in the data for the groundwater samples. Differences between replicate samples were within acceptable ranges, with few exceptions. Matrix-spike recoveries were within acceptable ranges for most compounds. This study did not attempt to evaluate the quality of water delivered to consumers; after withdrawal from the ground, groundwater typically is treated, disinfected, or blended with other waters to maintain water quality. Regulatory benchmarks apply to finished drinking water that is served to the consumer, not to untre

Evaluation of drinking quality of groundwater through multivariate techniques in urban area.

PubMed

Das, Madhumita; Kumar, A; Mohapatra, M; Muduli, S D

2010-07-01

Groundwater is a major source of drinking water in urban areas. Because of the growing threat of debasing water quality due to urbanization and development, monitoring water quality is a prerequisite to ensure its suitability for use in drinking. But analysis of a large number of properties and parameter to parameter basis evaluation of water quality is not feasible in a regular interval. Multivariate techniques could streamline the data without much loss of information to a reasonably manageable data set. In this study, using principal component analysis, 11 relevant properties of 58 water samples were grouped into three statistical factors. Discriminant analysis identified "pH influence" as the most distinguished factor and pH, Fe, and NO₃⁻ as the most discriminating variables and could be treated as water quality indicators. These were utilized to classify the sampling sites into homogeneous clusters that reflect location-wise importance of specific indicator/s for use to monitor drinking water quality in the whole study area.

Sustainable solar energy capability studies by using S2H model in treating groundwater supply

NASA Astrophysics Data System (ADS)

Musa, S.; Anuar, M. F.; Shahabuddin, M. M.; Ridzuan, M. B.; Radin Mohamed, R. M. S.; Madun, M. A.

2018-04-01

Groundwater extracted in Research Centre for Soft Soil Malaysia (RECESS) contains a number of pollutants that exceed the safe level for consumption. A Solar-Hydro (S2H) model which is a practical prototype has been introduced to treat the groundwater sustainably by solar energy process (evaporation method). Selected parameters was tested which are sulphate, nitrate, chloride, fluoride, pH and dissolved oxygen. The water quality result shows that all parameters have achieved 100% of the drinking water quality standard issued by the Ministry of Health Malaysia. Evaporation method was proven that this solar energy can be applied in sustainably treating groundwater quality with up to 90% effectiveness. On the other hand, the quantitative analysis has shown that the production of clean water is below than 2% according to time constraints and design factors. Thus, this study can be generate clean and fresh water from groundwater by using a simplified model and it has huge potential to be implemented by the local communities with a larger scale and affordable design.

Assessment of chemical quality of groundwater in coastal volcano-sedimentary aquifer of Djibouti, Horn of Africa

NASA Astrophysics Data System (ADS)

Ahmed, Abdoulkader Houssein; Rayaleh, Waiss Elmi; Zghibi, Adel; Ouddane, Baghdad

2017-07-01

This research is conducted to evaluate the current status of hydrogeochemical contaminants and their sources in groundwater in the volcano-sedimentary aquifer of Djibouti. Groundwater samples were mostly collected from the volcanic and inferoflux aquifers and then were analyzed for quality on physicochemical parameters (EC, pH, Temperature, Cl-, SO42-, HCO3-, NO3-, Na+, Ca2+, Mg2+, K+, Br-, F-), minor and trace elements (Li, Ba, B, Sr, Si, Al, Cr, Fe, Mn, Mo, Pb, Co, Cu, Ni, Zn, Ti, V, As, Se). The interpretations of hydrochemical data are shown numerically and graphically through the Piper diagram such as the multivariate statistical analysis, binary diagram, the calculation of the saturation indexes, the index of base exchanges and ratio of Na+/Cl-, SO42-/Cl-, HCO3-/Cl-. The seawater ratio and ionic deviation in the groundwater were calculated using the chloride concentration. These processes can be used as indicators of seawater intrusion progress. This study reveals three groundwater quality groups and how the quality of water supply has been deteriorated through the process of seawater intrusion. The seawater intrusion extends into the Gulf basalts aquifer that covers nearly 12% of the whole area according to some observations. Some toxic elements present in drinking water (As and Se) have already exceeded the maximum permissible in almost the entire of the Gulf basalts aquifer affected by seawater intrusion. Indeed, some correlations were found between As, Se, with electrical conductivity and among other minor and trace elements such as Br, B, Sr, Co and Cr. It indicates that all these elements are mainly controlled by naturel/geogenic processes. The Principal component Analysis and the Hierarchical Cluster Analysis have led to the confirmation of the hypotheses developed in the previous hydrochemical study in which two factors explain the major hydrochemical processes in the aquifer. These factors reveal first the existence of an intensive intrusion of seawater and second the mechanisms of contamination through the recharge processes of groundwater. Consequently, the assessment of water quality and the determination of the risk of water contamination by pollution seems to be very useful for an effective management of groundwater resources, and also for preventing salinization and minimizing the phenomena of seawater intrusion.

Python tools for rapid development, calibration, and analysis of generalized groundwater-flow models

NASA Astrophysics Data System (ADS)

Starn, J. J.; Belitz, K.

2014-12-01

National-scale water-quality data sets for the United States have been available for several decades; however, groundwater models to interpret these data are available for only a small percentage of the country. Generalized models may be adequate to explain and project groundwater-quality trends at the national scale by using regional scale models (defined as watersheds at or between the HUC-6 and HUC-8 levels). Coast-to-coast data such as the National Hydrologic Dataset Plus (NHD+) make it possible to extract the basic building blocks for a model anywhere in the country. IPython notebooks have been developed to automate the creation of generalized groundwater-flow models from the NHD+. The notebook format allows rapid testing of methods for model creation, calibration, and analysis. Capabilities within the Python ecosystem greatly speed up the development and testing of algorithms. GeoPandas is used for very efficient geospatial processing. Raster processing includes the Geospatial Data Abstraction Library and image processing tools. Model creation is made possible through Flopy, a versatile input and output writer for several MODFLOW-based flow and transport model codes. Interpolation, integration, and map plotting included in the standard Python tool stack also are used, making the notebook a comprehensive platform within on to build and evaluate general models. Models with alternative boundary conditions, number of layers, and cell spacing can be tested against one another and evaluated by using water-quality data. Novel calibration criteria were developed by comparing modeled heads to land-surface and surface-water elevations. Information, such as predicted age distributions, can be extracted from general models and tested for its ability to explain water-quality trends. Groundwater ages then can be correlated with horizontal and vertical hydrologic position, a relation that can be used for statistical assessment of likely groundwater-quality conditions. Convolution with age distributions can be used to quickly ascertain likely future water-quality conditions. Although these models are admittedly very general and are still being tested, the hope is that they will be useful for answering questions related to water quality at the regional scale.

Groundwater Quality beneath an Asian Megacity on a Delta: Kolkata's (Calcutta's) Disappearing Arsenic and Present Manganese.

PubMed

McArthur, J M; Sikdar, P K; Leng, M J; Ghosal, U; Sen, I

2018-05-01

Kolkata, the capital city of West Bengal, exploits groundwater for public water-supply. The groundwater has been reported to be widely polluted by arsenic (As). Analysis for As in 280 groundwaters from across Kolkata, failed to detect As concentrations >10 μg/L from natural processes. Arsenic concentrations between 10 and 79 μg/L found in 14 of the 280 groundwaters are remnant from a pollution-plume emanating from a single factory site where Paris Green, an arsenical pesticide, was manufactured between 1965 and 1985. In 45% of groundwaters sampled, concentrations of Mn exceed 0.4 mg/L, a putative health guideline value for drinking water. Sporadic minor hazards are posed by Pb > 10 μg/L introduced into groundwater from well-fittings, from 4% of groundwaters with F concentrations between 0.75 and 1 mg/L, and the 14% of groundwaters containing more than 500 mg/L Na, concentrations that might contribute to excessive daily intake of Na. Compounding hazards from As, F, Mn, Na, and Pb, shows that 64% of public wells and 40% of municipal wells supply groundwater of suspect quality. Groundwaters comply with WHO Guideline Values for drinking water in terms of Cr, Cu, Co, NO 2 , NO 3 , Sb, Se, and U. Aesthetic guideline values for Fe, Mn, SO 4 , and Cl are exceeded for many groundwaters.

Investigation and Evaluation of Groundwater Resources of Juxian

NASA Astrophysics Data System (ADS)

Xinyi, Li; Wanglin, Li; Xiaojiao, Zhang; Deling, Zhu; Huadan, Yan

2018-03-01

The investigation and evaluation of groundwater resources refers to the analysis of groundwater quantity, quality, spatial-temporal property and exploitation status. Based on the collected data and field investigation, the groundwater resources in plain and hilly area of Juxian were calculated by replenishment method, discharge method and comprehensive infiltration coefficient method, and the groundwater quality was analyzed and evaluated. The conclusions are as follows: (1) The amount of groundwater resources is 224.940 million m3/a, including 89.585 million m3/a of plain area and 142.523 million m3/a of hilly area respectively. (2) The allowable yield of groundwater is about 162.948 million m3/a, in which the amounts in the plain area and the hilly area are 74 .585million m3/a and 88.363 million m3/a, respectively. (3) The pH value of groundwater ranges from 6.5∼7.5 and the degree of mineralization of groundwater was lower than 1 g/L at most. In addition, the total hardness varies from 150 mg/L to 450 mg/L in plain area and 300 mg/L to 550 mg/L in hilly area, respectively. The investigation and evaluation of groundwater resources was of great significance in ensuring the sustainable development of groundwater resources, establishing the scheme of groundwater resources exploitation and utilization.

Time series analysis for the estimation of tidal fluctuation effect on different aquifers in a small coastal area of Saijo plain, Ehime prefecture, Japan.

PubMed

Kumar, Pankaj; Tsujimura, Maki; Nakano, Takanori; Minoru, Tokumasu

2013-04-01

Considering the current poor understanding of the seawater-freshwater (SW-FW) interaction pattern at dynamic hydro-geological boundary of coastal aquifers, this work strives to study tidal effect on groundwater quality using chemical tracers combined with environmental isotopes. In situ measurement data of electrical conductivity and groundwater level along with laboratory measurement data of hydro-chemical species were compared with tidal level data measured by Hydrographic and Oceanographic Department, Saijo City, Japan for time series analysis. Result shows that diurnal tides have significant effect on groundwater level as well as its chemical characteristics; however, the magnitude of effect is different in case of different aquifers. Various scatter diagrams were plotted in order to infer mechanisms responsible for water quality change with tidal phase, and results show that cations exchange, selective movement and local SW-FW mixing were likely to be the main processes responsible for water quality changes. It was also found that geological structure of the aquifers is the most important factor affecting the intensity of tidal effect on water quality.

Statistical trend analysis of groundwater data at Louisiana Army Ammunition Plant

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bhinge, D; Patel, J.; Skibinski, J.N.

1994-12-31

Statistical regression techniques were used to characterize temporal trends in groundwater monitoring data collected between 1980 and 1994 at Former Area P Lagoons, Louisiana Army Ammunition Plant (LAAP), a National Priorities List (NPL) site. Groundwater sampling data were evaluated for 12 wells (9 in the shallow aquifer and 3 in the deeper aquifer) and 9 contaminants of concern (COCs). A trend index (TI) was calculated from the sum of the number of improving and stable trends minus the number of deteriorating trends for each contaminant, each well, and the overall site. A positive TI indicates an improving trend for themore » site, contaminant, or well. Conversely, a negative TI indicates a deteriorating trend. The overall trend indices at the site for the shallow and deeper aquifers were found to be positive, indicating that the groundwater quality at Area P is generally improving. Interim remedial action was conducted at Area P from 1988 through 1990. The effect of remedial activities on groundwater quality was assessed by comparing the groundwater concentrations of nitro compounds measured immediately after the site remediation to those measured prior to the remedial action. The regression curves and the data indicated that a downward trend in the groundwater concentrations was observed immediately following the remediation activity at Area P. The trends from the regression analysis indicated that the overall remedy at Area P has been effective in reducing COC concentrations in groundwater.« less

Assessment of groundwater and soil quality degradation using multivariate and geostatistical analyses, Dakhla Oasis, Egypt

NASA Astrophysics Data System (ADS)

Masoud, Alaa A.; El-Horiny, Mohamed M.; Atwia, Mohamed G.; Gemail, Khaled S.; Koike, Katsuaki

2018-06-01

Salinization of groundwater and soil resources has long been a serious environmental hazard in arid regions. This study was conducted to investigate and document the factors controlling such salinization and their inter-relationships in the Dakhla Oasis (Egypt). To accomplish this, 60 groundwater samples and 31 soil samples were collected in February 2014. Factor analysis (FA) and hierarchical cluster analysis (HCA) were integrated with geostatistical analyses to characterize the chemical properties of groundwater and soil and their spatial patterns, identify the factors controlling the pattern variability, and clarify the salinization mechanism. Groundwater quality standards revealed emergence of salinization (av. 885.8 mg/L) and extreme occurrences of Fe2+ (av. 17.22 mg/L) and Mn2+ (av. 2.38 mg/L). Soils were highly salt-affected (av. 15.2 dS m-1) and slightly alkaline (av. pH = 7.7). Evaporation and ion-exchange processes governed the evolution of two main water types: Na-Cl (52%) and Ca-Mg-Cl (47%), respectively. Salinization leads the chemical variability of both resources. Distinctive patterns of slight salinization marked the northern part and intense salinization marked the middle and southern parts. Congruence in the resources clusters confirmed common geology, soil types, and urban and agricultural practices. Minimizing the environmental and socioeconomic impacts of the resources salinization urges the need for better understanding of the hydrochemical characteristics and prediction of quality changes.

Development of Relative Risk Model for Regional Groundwater Risk Assessment: A Case Study in the Lower Liaohe River Plain, China

PubMed Central

Li, Xianbo; Zuo, Rui; Teng, Yanguo; Wang, Jinsheng; Wang, Bin

2015-01-01

Increasing pressure on water supply worldwide, especially in arid areas, has resulted in groundwater overexploitation and contamination, and subsequent deterioration of the groundwater quality and threats to public health. Environmental risk assessment of regional groundwater is an important tool for groundwater protection. This study presents a new approach for assessing the environmental risk assessment of regional groundwater. It was carried out with a relative risk model (RRM) coupled with a series of indices, such as a groundwater vulnerability index, which includes receptor analysis, risk source analysis, risk exposure and hazard analysis, risk characterization, and management of groundwater. The risk map is a product of the probability of environmental contamination and impact. The reliability of the RRM was verified using Monte Carlo analysis. This approach was applied to the lower Liaohe River Plain (LLRP), northeastern China, which covers 23604 km2. A spatial analysis tool within GIS which was used to interpolate and manipulate the data to develop environmental risk maps of regional groundwater, divided the level of risk from high to low into five ranks (V, IV, III, II, I). The results indicate that areas of relative risk rank (RRR) V cover 2324 km2, covering 9.8% of the area; RRR IV covers 3986 km2, accounting for 16.9% of the area. It is a new and appropriate method for regional groundwater resource management and land use planning, and is a rapid and effective tool for improving strategic decision making to protect groundwater and reduce environmental risk. PMID:26020518

DOE Office of Scientific and Technical Information (OSTI.GOV)

N /A

This report contains the groundwater and surface water monitoring data that were obtained during calendar year (CY) 2006 at the U.S. Department of Energy (DOE) Y-12 National Security Complex (hereafter referenced as Y-12) on the DOE Oak Ridge Reservation (ORR) in Oak Ridge, Tennessee. The CY 2006 monitoring data were obtained from wells, springs, and surface water sampling locations in three hydrogeologic regimes at Y-12 (Figure A.1). The Bear Creek Hydrogeologic Regime (Bear Creek Regime) encompasses a section of Bear Creek Valley (BCV) between the west end of Y-12 and the west end of the Bear Creek Watershed (directions aremore » in reference to the Y-12 grid system). The Upper East Fork Poplar Creek Hydrogeologic Regime (East Fork Regime) encompasses the Y-12 industrial facilities and support structures in BCV. The Chestnut Ridge Hydrogeologic Regime (Chestnut Ridge Regime) encompasses a section of Chestnut Ridge directly south of Y-12. Section 2 of this report provides background information pertinent to groundwater and surface water quality monitoring in each hydrogeologic regime, including the topography and bedrock geology, surface water drainage, groundwater system, and extent of groundwater contamination. The CY 2006 groundwater and surface water monitoring data in this report were obtained from sampling and analysis activities implemented under the Y-12 Groundwater Protection Program (GWPP) managed by BWXT Y-12, L.L.C. (BWXT), and from sampling and analysis activities implemented under several monitoring programs managed by Bechtel Jacobs Company LLC (BJC). Cooperative implementation of the monitoring programs directed by the Y-12 GWPP and BJC (i.e., preparing SAPs, coordinating sample collection, and sharing data) ensures that the CY 2006 monitoring results fulfill requirements of all the applicable monitoring drivers with no duplication of sampling and analysis efforts. Section 3 of this report contains a summary of information regarding the groundwater and surface water sampling and analysis activities implemented under the Y-12 GWPP including sampling locations and frequency; quality assurance (QA)/quality control (QC) sampling; sample collection and handling; field measurements and laboratory analytes; data management and data quality objective (DQO) evaluation; and groundwater elevation monitoring. However, this report does not include equivalent information regarding the groundwater and surface water sampling and analysis activities associated with the monitoring programs implemented by BJC. Such details are deferred to the respective programmatic plans and reports issued by BJC (see Section 3.0). Collectively, the groundwater and surface water monitoring data obtained during CY 2006 by the Y-12 GWPP and BJC address DOE Order 450.1 (Environmental Protection Program) requirements for monitoring groundwater and surface water quality in areas: (1) which are, or could be, affected by operations at Y-12 (surveillance monitoring); and (2) where contaminants from Y-12 are most likely to migrate beyond the boundaries of the ORR (exit pathway/perimeter monitoring). Section 4 of this report presents a summary evaluation of the monitoring data with regard to the respective objectives of surveillance monitoring and exit pathway/perimeter monitoring, based on the analytical results for the principal groundwater and surface water contaminants at Y-12: nitrate, uranium, volatile organic compounds (VOCs), gross alpha activity, and gross beta activity. Section 5 of this report summarizes the most pertinent findings regarding the principal contaminants, along with recommendations proposed for ongoing groundwater and surface water quality monitoring performed under the Y-12 GWPP. Narrative sections of this report reference several appendices. Figures (maps and diagrams) and tables (excluding data summary tables presented in the narrative sections) are in Appendix A and Appendix B, respectively. Appendix C contains construction details for the wells in each regime that were sampled during CY 2006 by either the Y-12 GWPP or BJC. Field measurements recorded during collection of the groundwater and surface water samples and results of laboratory analyses of the samples are in Appendix D (Bear Creek Regime), Appendix E (East Fork Regime and surrounding areas), and Appendix F (Chestnut Ridge Regime). Appendix G contains data for the QA/QC samples associated with monitoring performed in each regime by the Y-12 GWPP.« less

Characteristics of Leachate at Sukawinatan Landfill, Palembang, Indonesia

NASA Astrophysics Data System (ADS)

Sri Yusmartini, Eka; Setiabudidaya, Dedi; Ridwan; Marsi; Faizal

2013-04-01

Landfill (TPA) Sukawinatan Palembang is an open dumping system which covers an area of 25 hectares. This system may bring an environmental damage to the surrounding area because it does not provide leachate treatment. Leachate is the landfill waste that dissolves many compounds that contain pollutants from both organic substances and heavy metal origin. This paper presents the results of laboratory analysis on samples of leachate as well as shallow groundwater from the surrounding area. The results were compared to established quality standards to evaluate whether the leachate has influenced the quality of the shallow groundwater in the surrounding area. The results show that there are some indications that the quality of groundwater has been polluted by the leachate of both organic substances and heavy metals produced by the Sukawinatan landfill.

Groundwater quality in the San Francisco Bay groundwater basins, California

USGS Publications Warehouse

Parsons, Mary C.; Kulongoski, Justin T.; Belitz, Kenneth

2013-01-01

Groundwater provides more than 40 percent of California’s drinking water. To protect this vital resource, the State of California created the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The Priority Basin Project of the GAMA Program provides a comprehensive assessment of the State’s groundwater quality and increases public access to groundwater-quality information. Selected groundwater basins of the San Francisco Bay area constitute one of the study units being evaluated.

Nitrate in groundwater of the United States, 1991-2003

USGS Publications Warehouse

Burow, Karen R.; Nolan, Bernard T.; Rupert, Michael G.; Dubrovsky, Neil M.

2010-01-01

An assessment of nitrate concentrations in groundwater in the United States indicates that concentrations are highest in shallow, oxic groundwater beneath areas with high N inputs. During 1991-2003, 5101 wells were sampled in 51 study areas throughout the U.S. as part of the U.S. Geological Survey National Water-Quality Assessment (NAWQA) program. The well networks reflect the existing used resource represented by domestic wells in major aquifers (major aquifer studies), and recently recharged groundwater beneath dominant land-surface activities (land-use studies). Nitrate concentrations were highest in shallow groundwater beneath agricultural land use in areas with well-drained soils and oxic geochemical conditions. Nitrate concentrations were lowest in deep groundwater where groundwater is reduced, or where groundwater is older and hence concentrations reflect historically low N application rates. Classification and regression tree analysis was used to identify the relative importance of N inputs, biogeochemical processes, and physical aquifer properties in explaining nitrate concentrations in groundwater. Factors ranked by reduction in sum of squares indicate that dissolved iron concentrations explained most of the variation in groundwater nitrate concentration, followed by manganese, calcium, farm N fertilizer inputs, percent well-drained soils, and dissolved oxygen. Overall, nitrate concentrations in groundwater are most significantly affected by redox conditions, followed by nonpoint-source N inputs. Other water-quality indicators and physical variables had a secondary influence on nitrate concentrations.

Land use change and conversion effects on ground water quality trends: An integration of land change modeler in GIS and a new Ground Water Quality Index developed by fuzzy multi-criteria group decision-making models.

PubMed

Shooshtarian, Mohammad Reza; Dehghani, Mansooreh; Margherita, Ferrante; Gea, Oliveri Conti; Mortezazadeh, Shima

2018-04-01

This study aggregated Land Change Modeller (LCM) as a useful model in GIS with an extended Groundwater Quality Index (GWQI) developed by fuzzy Multi-Criteria Group Decision-Making models to investigate the effect of land use change and conversion on groundwater quality being supplied for drinking. The model's performance was examined through an applied study in Shiraz, Iran, in a five year period (2011 to 2015). Four land use maps including urban, industrial, garden, and bare were employed in LCM model and the impact of change in area and their conversion to each other on GWQI changes was analysed. The correlation analysis indicated that increase in the urban land use area and conversion of bare to the residential/industrial land uses, had a relation with water quality decrease. Integration of LCM and GWQI can accurately and logically provide a numerical analysis of the possible impact of land use change and conversion, as one of the influencing factors, on the groundwater quality. Hence, the methodology could be used in urban development planning and management in macro level. Copyright © 2018. Published by Elsevier Ltd.

[Medical hydrogeology is an independent interdisciplinary branch of the science about groundwater].

PubMed

Elpiner, L I

The use of groundwater in population water supply systems gains more and more importance because of increasing degradation of the quality of surface water sources. At the same time there are changed concepts on ubiquitous high quality of groundwater. The executed analysis offoreign and domestic literature allowed authors to determine the character and causes of negative changes in the composition of groundwater. In the large body of investigations there were established cause-and-effect relationships between a number of noninfectious (including cardiovascular and cancer) and infectious diseases and anthropogenic pollution and the natural composition of groundwater. In the article there is substantiated the formation of a new interdisciplinary scientific direction - medical hydrogeology. On the basis of current data on the medical and ecological significance of the quality, quantity and regime of the groundwater, geological conditions of the shaping of their composition, there was shown the need of the consideration of the hydrological situation in making water supply management solutions safe for the health of the population. In this regard, there were considered the interrelationship and interdependence of allied disciplines - hygiene, ecological toxicology and epidemiology, hydrogeochemistry, hydrogeology. There was pointed the importance of the acquisition of based on hydrogeology medical specialists of the water supply profile for sharing with hygienists of the effective solution of tasks of the management of groundwater sources.

40 CFR 258.53 - Ground-water sampling and analysis requirements.

Code of Federal Regulations, 2012 CFR

2012-07-01

... considering the number of samples in the background data base, the data distribution, and the range of the... the background data base, the data distribution, and the range of the concentration values for each... samples collected to establish ground-water quality data must be consistent with the appropriate...

40 CFR 258.53 - Ground-water sampling and analysis requirements.

Code of Federal Regulations, 2014 CFR

2014-07-01

... considering the number of samples in the background data base, the data distribution, and the range of the... the background data base, the data distribution, and the range of the concentration values for each... samples collected to establish ground-water quality data must be consistent with the appropriate...

Characterization of shallow groundwater quality in the Lower St. Johns River Basin: a case study

Treesearch

Ying Ouyang; Jia-En Zhang; Prem Parajuli

2013-01-01

Characterization of groundwater quality allows the evaluation of groundwater pollution and provides information for better management of groundwater resources. This study characterized the shallow groundwater quality and its spatial and seasonal variations in the Lower St. Johns River Basin, Florida, USA, under agricultural, forest, wastewater, and residential land...

Conceptual understanding and groundwater quality of selected basin-fill aquifers in the Southwestern United States

USGS Publications Warehouse

Thiros, Susan A.; Bexfield, Laura M.; Anning, David W.; Huntington, Jena M.

2010-01-01

The National Water-Quality Assessment (NAWQA) Program of the U.S. Geological Survey has been conducting a regional analysis of water quality in the principal aquifer systems in the southwestern United States (hereinafter, “Southwest”) since 2005. Part of the NAWQA Program, the objective of the Southwest Principal Aquifers (SWPA) study is to develop a better understanding of water quality in basin-fill aquifers in the region by synthesizing information from case studies of 15 basins into a common set of important natural and human-related factors found to affect groundwater quality.The synthesis consists of three major components:1. Summary of current knowledge about the groundwater systems, and the status of, changes in, and influential factors affecting quality of groundwater in basin-fill aquifers in 15 basins previously studied by NAWQA (this report).2. Development of a conceptual model of the primary natural and human-related factors commonly affecting groundwater quality, thereby building a regional understanding of the susceptibility and vulnerability of basin-fill aquifers to contaminants.3. Development of statistical models that relate the concentration or occurrence of specific chemical constituents in groundwater to natural and human-related factors linked to the susceptibility and vulnerability of basin-fill aquifers to contamination.Basin-fill aquifers occur in about 200,000 mi2 of the 410,000 mi2 SWPA study area and are the primary source of groundwater supply for cities and agricultural communities. Four of the principal aquifers or aquifer systems of the United States are included in the basin-fill aquifers of the study area: (1) the Basin and Range basin-fill aquifers in California, Nevada, Utah, and Arizona; (2) the Rio Grande aquifer system in New Mexico and Colorado; (3) the California Coastal Basin aquifers; and (4) the Central Valley aquifer system in California. Because of the generally limited availability of surface-water supplies in the arid to semiarid climate, cultural and economic activities in the Southwest are particularly dependent on supplies of good-quality groundwater. Irrigation and public-supply withdrawals from basin-fill aquifers in the study area account for about one quarter of the total withdrawals from all aquifers in the United States.Many factors influence the quality of groundwater in the 15 case-study basins, but some common factors emerge from the basin summaries presented in this report. These factors include the chemical composition of the recharge water, consolidated rock geology and composition of aquifer materials derived from consolidated rock, and land and water use. The major water-quality issues in many of the developed case-study basins are increased concentrations of dissolved solids, nitrate, and VOCs in groundwater as a result of human activities.The information presented and the citations listed in this report serve as a resource for those interested in the groundwater-flow systems in the NAWQA case-study basins. The summaries of water-development history, hydrogeology, conceptual understanding of the groundwater system under both predevelopment and modern conditions, and effects of natural and human-related factors on groundwater quality presented in the sections on each basin also serve as a foundation for the synthesis and modeling phases of the SWPA regional study.

Groundwater Quality Data for the Tahoe-Martis Study Unit, 2007: Results from the California GAMA Program

USGS Publications Warehouse

Fram, Miranda S.; Munday, Cathy; Belitz, Kenneth

2009-01-01

Groundwater quality in the approximately 460-square-mile Tahoe-Martis study unit was investigated in June through September 2007 as part of the Priority Basin Project of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The GAMA Priority Basin Project was developed in response to the Groundwater Quality Monitoring Act of 2001 and is being conducted by the U.S. Geological Survey (USGS) in cooperation with the California State Water Resources Control Board (SWRCB). The study was designed to provide a spatially unbiased assessment of the quality of raw groundwater used for public water supplies within the Tahoe-Martis study unit (Tahoe-Martis) and to facilitate statistically consistent comparisons of groundwater quality throughout California. Samples were collected from 52 wells in El Dorado, Placer, and Nevada Counties. Forty-one of the wells were selected using a spatially distributed, randomized grid-based method to provide statistical representation of the study area (grid wells), and 11 were selected to aid in evaluation of specific water-quality issues (understanding wells). The groundwater samples were analyzed for a large number of synthetic organic constituents (volatile organic compounds [VOC], pesticides and pesticide degradates, and pharmaceutical compounds), constituents of special interest (perchlorate and N-nitrosodimethylamine [NDMA]), naturally occurring inorganic constituents (nutrients, major and minor ions, and trace elements), radioactive constituents, and microbial indicators. Naturally occurring isotopes (tritium, carbon-14, strontium isotope ratio, and stable isotopes of hydrogen and oxygen of water), and dissolved noble gases also were measured to help identify the sources and ages of the sampled groundwater. In total, 240 constituents and water-quality indicators were investigated. Three types of quality-control samples (blanks, replicates, and samples for matrix spikes) each were collected at 12 percent of the wells, and the results obtained from these samples were used to evaluate the quality of the data for the groundwater samples. Field blanks rarely contained detectable concentrations of any constituent, suggesting that data for the groundwater samples were not compromised by possible contamination during sample collection, handling or analysis. Differences between replicate samples were within acceptable ranges. Matrix spike recoveries were within acceptable ranges for most compounds. This study did not attempt to evaluate the quality of water delivered to consumers; after withdrawal from the ground, raw water typically is treated, disinfected, or blended with other waters to maintain water quality. Regulatory thresholds apply to water that is served to the consumer, not to raw groundwater. However, to provide some context for the results, concentrations of constituents measured in the raw groundwater were compared with regulatory and nonregulatory health-based thresholds established by the U.S. Environmental Protection Agency (USEPA) and the California Department of Public Health (CDPH), and with aesthetic and technical thresholds established by CDPH. Comparisons between data collected for this study and drinking-water thresholds are for illustrative purposes only and do not indicate of compliance or noncompliance with regulatory thresholds. The concentrations of most constituents detected in groundwater samples from the Tahoe-Martis wells were below drinking-water thresholds. Organic compounds (VOCs and pesticides) were detected in about 40 percent of the samples from grid wells, and most concentrations were less than 1/100th of regulatory and nonregulatory health-based thresholds, although the conentration of perchloroethene in one sample was above the USEPA maximum contaminant level (MCL-US). Concentrations of all trace elements and nutrients in samples from grid wells were below regulatory and nonregulatory health-based thresholds, with five exceptions. Concentra

Hydrogeochemical analysis and evaluation of groundwater in the reclaimed small basin of Abu Mina, Egypt

NASA Astrophysics Data System (ADS)

Salem, Zenhom E.; Atwia, Mohamed G.; El-Horiny, Mohamed M.

2015-12-01

Agricultural reclamation activities during the last few decades in the Western Nile Delta have led to great changes in the groundwater levels and quality. In Egypt, changing the desert land into agricultural land has been done using transferred Nile water (through irrigation canal systems) or/and groundwater. This research investigates the hydrogeochemical changes accompanying the reclamation processes in the small basin of Abu Mina, which is part of the Western Nile Delta region. In summer 2008, 23 groundwater samples were collected and groundwater levels were measured in 40 observation wells. Comparing the groundwater data of the pre-reclamation (1974) and the post-reclamation (2008) periods, groundwater seems to have been subjected to many changes: rise in water level, modification of the flow system, improvement of water quality, and addition of new salts through dissolution processes. Generally, Abu Mina basin is subdivided into two areas, recharge and discharge. The dissolution and mixing were recognized in the recharge areas, while the groundwater of the discharge region carries the signature of the diluted pre-reclamation groundwater. The salts of soil and aquifer deposits play an important role in the salt content of the post and pre-reclamation groundwater. NaCl was the predominant water type in the pre-reclamation groundwater, while CaSO4, NaCl and MgSO4 are the common chemical facies in the post-reclamation groundwater. The post-reclamation groundwater mostly indicates mixing between the pre-reclamation groundwater and the infiltrated freshwater with addition of some ions due to interaction with soil and sediments.

Hydraulic fracturing near domestic groundwater wells.

PubMed

Jasechko, Scott; Perrone, Debra

2017-12-12

Hydraulic fracturing operations are generating considerable discussion about their potential to contaminate aquifers tapped by domestic groundwater wells. Groundwater wells located closer to hydraulically fractured wells are more likely to be exposed to contaminants derived from on-site spills and well-bore failures, should they occur. Nevertheless, the proximity of hydraulic fracturing operations to domestic groundwater wells is unknown. Here, we analyze the distance between domestic groundwater wells (public and self-supply) constructed between 2000 and 2014 and hydraulically fractured wells stimulated in 2014 in 14 states. We show that 37% of all recorded hydraulically fractured wells stimulated during 2014 exist within 2 km of at least one recently constructed (2000-2014) domestic groundwater well. Furthermore, we identify 11 counties where most ([Formula: see text]50%) recorded domestic groundwater wells exist within 2 km of one or more hydraulically fractured wells stimulated during 2014. Our findings suggest that understanding how frequently hydraulic fracturing operations impact groundwater quality is of widespread importance to drinking water safety in many areas where hydraulic fracturing is common. We also identify 236 counties where most recorded domestic groundwater wells exist within 2 km of one or more recorded oil and gas wells producing during 2014. Our analysis identifies hotspots where both conventional and unconventional oil and gas wells frequently exist near recorded domestic groundwater wells that may be targeted for further water-quality monitoring.

Hydraulic fracturing near domestic groundwater wells

PubMed Central

Jasechko, Scott; Perrone, Debra

2017-01-01

Hydraulic fracturing operations are generating considerable discussion about their potential to contaminate aquifers tapped by domestic groundwater wells. Groundwater wells located closer to hydraulically fractured wells are more likely to be exposed to contaminants derived from on-site spills and well-bore failures, should they occur. Nevertheless, the proximity of hydraulic fracturing operations to domestic groundwater wells is unknown. Here, we analyze the distance between domestic groundwater wells (public and self-supply) constructed between 2000 and 2014 and hydraulically fractured wells stimulated in 2014 in 14 states. We show that 37% of all recorded hydraulically fractured wells stimulated during 2014 exist within 2 km of at least one recently constructed (2000–2014) domestic groundwater well. Furthermore, we identify 11 counties where most (>50%) recorded domestic groundwater wells exist within 2 km of one or more hydraulically fractured wells stimulated during 2014. Our findings suggest that understanding how frequently hydraulic fracturing operations impact groundwater quality is of widespread importance to drinking water safety in many areas where hydraulic fracturing is common. We also identify 236 counties where most recorded domestic groundwater wells exist within 2 km of one or more recorded oil and gas wells producing during 2014. Our analysis identifies hotspots where both conventional and unconventional oil and gas wells frequently exist near recorded domestic groundwater wells that may be targeted for further water-quality monitoring. PMID:29180405

Spatial analysis of groundwater electrical conductivity using ordinary kriging and artificial intelligence methods (Case study: Maharlu-Bakhtegan and Tashk salt lakes basin, Iran)

NASA Astrophysics Data System (ADS)

Ghader, Fatemeh; Aljoumani, Basem; Tröger, Uwe

2017-04-01

The main resources of fresh water are the groundwater. In Iran, the quality and quantity of groundwater is affected significantly by rapid population growth and unsustainable water management in the agricultural and industrial sectors. in Maharlu-Bakhtegan and Tashk salt lakes basin, the overexploitation of groundwater for irrigation purpose caused the salt water intrusion from the lakes to the area's aquifers, moreover, the basin is located in south of Iran with semiarid climate, faces a significant decline in rainfall. All these reasons cause the degradation of ground water quality. For this study, geographical coordinates of 406 observation wells will be defined as inputs and groundwater electrical conductivities (EC) will be set as output. Ordinary kriging (OK) and artificial neural networks (ANN) will be investigated for modeling groundwater salinity. Eighty percent of data will be randomly selected to train and develop mentioned models and twenty percent of data will be used for testing and validating. Finally, the outputs of models will be compared with the corresponding measured values in observation wells.

High-throughput DNA microarray detection of pathogenic bacteria in shallow well groundwater in the Kathmandu Valley, Nepal.

PubMed

Inoue, Daisuke; Hinoura, Takuji; Suzuki, Noriko; Pang, Junqin; Malla, Rabin; Shrestha, Sadhana; Chapagain, Saroj Kumar; Matsuzawa, Hiroaki; Nakamura, Takashi; Tanaka, Yasuhiro; Ike, Michihiko; Nishida, Kei; Sei, Kazunari

2015-01-01

Because of heavy dependence on groundwater for drinking water and other domestic use, microbial contamination of groundwater is a serious problem in the Kathmandu Valley, Nepal. This study investigated comprehensively the occurrence of pathogenic bacteria in shallow well groundwater in the Kathmandu Valley by applying DNA microarray analysis targeting 941 pathogenic bacterial species/groups. Water quality measurements found significant coliform (fecal) contamination in 10 of the 11 investigated groundwater samples and significant nitrogen contamination in some samples. The results of DNA microarray analysis revealed the presence of 1-37 pathogen species/groups, including 1-27 biosafety level 2 ones, in 9 of the 11 groundwater samples. While the detected pathogens included several feces- and animal-related ones, those belonging to Legionella and Arthrobacter, which were considered not to be directly associated with feces, were detected prevalently. This study could provide a rough picture of overall pathogenic bacterial contamination in the Kathmandu Valley, and demonstrated the usefulness of DNA microarray analysis as a comprehensive screening tool of a wide variety of pathogenic bacteria.

Environmental impact of leachate characteristics on water quality.

PubMed

Cumar, Sampath Kumar Mandyam; Nagaraja, Balasubramanya

2011-07-01

Improper urbanization and industrialization are causing a critical stress on groundwater quality in urban areas of the developing countries. The present study under investigation describes the pollution caused by leachate from a waste management site in southwestern Bangalore city causing pollution of the surface water and groundwater reserves. The characterization of 20 groundwater samples and Haralukunte lake sample indicated high pollution of these water reserves by leachate entry into the groundwater and surface water sources. The study area focuses around the solid waste management site, carrying out bio-composting and vermi-composting of municipal solid waste. Further investigations on the severe health problems faced by the public in the study area has revealed a clear pointer towards the usage of polluted water for rearing live-stock, farming, and domestic activities. The characterization of the leachate with high values of BOD at 1,450 mg/l, TDS at 17,200 mg/l, nitrates at 240 mg/l, and MPN at 545/100 ml indicates a clear nuisance potential, which has been substantiated by the characterization of lake water sample with chlorides at 3,400 mg/l, TDS at 8,020 mg/l, and lead and cadmium at 0.18 and 0.08 mg/l, respectively. Analysis of groundwater samples shows alarming physicochemical values closer to the waste disposal site and relatively reduced values away from the source of the waste management site. Bureau of Indian Standards have been adapted as the benchmark for the analysis and validation of observed water quality criteria.

Overview of groundwater management approaches at salinisation risk

NASA Astrophysics Data System (ADS)

Polemio, Maurizio; Zuffianò, Livia Emanuela

2013-04-01

All natural waters contain dissolved minerals from interactions with atmospheric and soil gases, mixing with other solutions, and/or interactions with the biosphere and lithosphere. In many cases, these processes result in natural waters containing solute or salinity above concentrations recommended for a specified use, which creates significant social and economic problems. Groundwater salinisation can be caused by natural phenomena and anthropogenic activities. For the former case, we can distinguish terrestrial and marine phenomena. Approximately 16% of the total area of continental earth is potentially involved in groundwater salinisation. Seawater intrusion can be considered to be the primary phenomenon to be studied in terms of groundwater salinisation. Three schematic approaches to the protection of groundwater via salinisation mitigation and/or groundwater salinity improvement are described based on the classifications of the primary salinisation sources and focusing on the effect of seawater intrusion. The complexity of these approaches generally increases due to difficulties caused by groundwater quality and quantity degradation and increased demand for quality water. In order from the lowest to the highest complexity, these approaches are the engineering approach, the discharge management approach, and the water and land management approach. The engineering approach is realised on the local or detailed scale with the purpose of controlling the salinisation, optimising the well discharge with specific technical solutions and/or completing works to improve the quality and/or quantity of the discharged fresh groundwater. The discharge management approach encompasses at least an entire coastal aquifer and defines rules concerning groundwater utilisation and well discharge. The water and land management approach should be applied on the regional scale. Briefly, this approach becomes necessary when one or more need creates an overall framework of high-quality water scarcity. These conditions, sometimes combined with an awareness of negative environmental effects, force people to accept new water saving practices and land use modifications. As the natural effects of salinisation can be enhanced by a multiplicity of human actions, the discharge management approach and the water and land management approach should generally be applied by water authorities or institutional and governmental organisations that are responsible for groundwater quality and availability. The practical study of Apulian karstic coastal aquifers is discussed in detail. Previously experienced management difficulties are described, as well as a proposed multi-methodological approach based on monitoring networks, the spatiotemporal analysis of groundwater quality changes, and multiparameter well logging. The core of this approach is the definition of the salinity threshold value between pure fresh groundwater and any fresh and saline groundwater mixture. The basic or single tools were defined to be simple, quick and cost-effective to be applicable to the widest range of situations.

A method of groundwater quality assessment based on fuzzy network-CANFIS and geographic information system (GIS)

NASA Astrophysics Data System (ADS)

Gholami, V.; Khaleghi, M. R.; Sebghati, M.

2017-11-01

The process of water quality testing is money/time-consuming, quite important and difficult stage for routine measurements. Therefore, use of models has become commonplace in simulating water quality. In this study, the coactive neuro-fuzzy inference system (CANFIS) was used to simulate groundwater quality. Further, geographic information system (GIS) was used as the pre-processor and post-processor tool to demonstrate spatial variation of groundwater quality. All important factors were quantified and groundwater quality index (GWQI) was developed. The proposed model was trained and validated by taking a case study of Mazandaran Plain located in northern part of Iran. The factors affecting groundwater quality were the input variables for the simulation, whereas GWQI index was the output. The developed model was validated to simulate groundwater quality. Network validation was performed via comparison between the estimated and actual GWQI values. In GIS, the study area was separated to raster format in the pixel dimensions of 1 km and also by incorporation of input data layers of the Fuzzy Network-CANFIS model; the geo-referenced layers of the effective factors in groundwater quality were earned. Therefore, numeric values of each pixel with geographical coordinates were entered to the Fuzzy Network-CANFIS model and thus simulation of groundwater quality was accessed in the study area. Finally, the simulated GWQI indices using the Fuzzy Network-CANFIS model were entered into GIS, and hence groundwater quality map (raster layer) based on the results of the network simulation was earned. The study's results confirm the high efficiency of incorporation of neuro-fuzzy techniques and GIS. It is also worth noting that the general quality of the groundwater in the most studied plain is fairly low.

Dynamic factor analysis of groundwater quality trends in an agricultural area adjacent to Everglades National Park.

PubMed

Muñoz-Carpena, R; Ritter, A; Li, Y C

2005-11-01

The extensive eastern boundary of Everglades National Park (ENP) in south Florida (USA) is subject to one of the most expensive and ambitious environmental restoration projects in history. Understanding and predicting the water quality interactions between the shallow aquifer and surface water is a key component in meeting current environmental regulations and fine-tuning ENP wetland restoration while still maintaining flood protection for the adjacent developed areas. Dynamic factor analysis (DFA), a recent technique for the study of multivariate non-stationary time-series, was applied to study fluctuations in groundwater quality in the area. More than two years of hydrological and water quality time series (rainfall; water table depth; and soil, ground and surface water concentrations of N-NO3-, N-NH4+, P-PO4(3-), Total P, F-and Cl-) from a small agricultural watershed adjacent to the ENP were selected for the study. The unexplained variability required for determining the concentration of each chemical in the 16 wells was greatly reduced by including in the analysis some of the observed time series as explanatory variables (rainfall, water table depth, and soil and canal water chemical concentration). DFA results showed that groundwater concentration of three of the agrochemical species studied (N-NO3-, P-PO4(3-)and Total P) were affected by the same explanatory variables (water table depth, enriched topsoil, and occurrence of a leaching rainfall event, in order of decreasing relative importance). This indicates that leaching by rainfall is the main mechanism explaining concentration peaks in groundwater. In the case of N-NH4+, in addition to leaching, groundwater concentration is governed by lateral exchange with canals. F-and Cl- are mainly affected by periods of dilution by rainfall recharge, and by exchange with the canals. The unstructured nature of the common trends found suggests that these are related to the complex spatially and temporally varying land use patterns in the watershed. The results indicate that peak concentrations of agrochemicals in groundwater could be reduced by improving fertilization practices (by splitting and modifying timing of applications) and by operating the regional canal system to maintain the water table low, especially during the rainy periods.

Dynamic factor analysis of groundwater quality trends in an agricultural area adjacent to Everglades National Park

NASA Astrophysics Data System (ADS)

Muñoz-Carpena, R.; Ritter, A.; Li, Y. C.

2005-11-01

The extensive eastern boundary of Everglades National Park (ENP) in south Florida (USA) is subject to one of the most expensive and ambitious environmental restoration projects in history. Understanding and predicting the water quality interactions between the shallow aquifer and surface water is a key component in meeting current environmental regulations and fine-tuning ENP wetland restoration while still maintaining flood protection for the adjacent developed areas. Dynamic factor analysis (DFA), a recent technique for the study of multivariate non-stationary time-series, was applied to study fluctuations in groundwater quality in the area. More than two years of hydrological and water quality time series (rainfall; water table depth; and soil, ground and surface water concentrations of N-NO 3-, N-NH 4+, P-PO 43-, Total P, F -and Cl -) from a small agricultural watershed adjacent to the ENP were selected for the study. The unexplained variability required for determining the concentration of each chemical in the 16 wells was greatly reduced by including in the analysis some of the observed time series as explanatory variables (rainfall, water table depth, and soil and canal water chemical concentration). DFA results showed that groundwater concentration of three of the agrochemical species studied (N-NO 3-, P-PO 43-and Total P) were affected by the same explanatory variables (water table depth, enriched topsoil, and occurrence of a leaching rainfall event, in order of decreasing relative importance). This indicates that leaching by rainfall is the main mechanism explaining concentration peaks in groundwater. In the case of N-NH 4+, in addition to leaching, groundwater concentration is governed by lateral exchange with canals. F -and Cl - are mainly affected by periods of dilution by rainfall recharge, and by exchange with the canals. The unstructured nature of the common trends found suggests that these are related to the complex spatially and temporally varying land use patterns in the watershed. The results indicate that peak concentrations of agrochemicals in groundwater could be reduced by improving fertilization practices (by splitting and modifying timing of applications) and by operating the regional canal system to maintain the water table low, especially during the rainy periods.

Geochemical evolution of groundwater in southern Bengal Basin: The example of Rajarhat and adjoining areas, West Bengal, India

NASA Astrophysics Data System (ADS)

Sahu, Paulami; Sikdar, P. K.; Chakraborty, Surajit

2016-02-01

Detailed geochemical analysis of groundwater beneath 1223 km2 area in southern Bengal Basin along with statistical analysis on the chemical data was attempted, to develop a better understanding of the geochemical processes that control the groundwater evolution in the deltaic aquifer of the region. Groundwater is categorized into three types: `excellent', `good' and `poor' and seven hydrochemical facies are assigned to three broad types: `fresh', `mixed' and `brackish' waters. The `fresh' water type dominated with sodium indicates active flushing of the aquifer, whereas chloride-rich `brackish' groundwater represents freshening of modified connate water. The `mixed' type groundwater has possibly evolved due to hydraulic mixing of `fresh' and `brackish' waters. Enrichment of major ions in groundwater is due to weathering of feldspathic and ferro-magnesian minerals by percolating water. The groundwater of Rajarhat New Town (RNT) and adjacent areas in the north and southeast is contaminated with arsenic. Current-pumping may induce more arsenic to flow into the aquifers of RNT and Kolkata cities. Future large-scale pumping of groundwater beneath RNT can modify the hydrological system, which may transport arsenic and low quality water from adjacent aquifers to presently unpolluted aquifer.

Wyoming groundwater-quality monitoring network

USGS Publications Warehouse

Boughton, Gregory K.

2011-01-01

A wide variety of human activities have the potential to contaminate groundwater. In addition, naturally occurring constituents can limit the suitability of groundwater for some uses. The State of Wyoming has established rules and programs to evaluate and protect groundwater quality based on identified uses. The Wyoming Groundwater-Quality Monitoring Network (WGQMN) is a cooperative program between the U.S. Geological Survey (USGS) and the Wyoming Department of Environmental Quality (WDEQ) and was implemented in 2009 to evaluate the water-quality characteristics of the State's groundwater. Representatives from USGS, WDEQ, U.S. Environmental Protection Agency (USEPA), Wyoming Water Development Office, and Wyoming State Engineer's Office formed a steering committee, which meets periodically to evaluate progress and consider modifications to strengthen program objectives. The purpose of this fact sheet is to describe the WGQMN design and objectives, field procedures, and water-quality analyses. USGS groundwater activities in the Greater Green River Basin also are described.

Assessing the impact of dairy waste lagoons on groundwater quality using a spatial analysis of vadose zone and groundwater information in a coastal phreatic aquifer.

PubMed

Baram, S; Kurtzman, D; Ronen, Z; Peeters, A; Dahan, O

2014-01-01

Dairy waste lagoons are considered to be point sources of groundwater contamination by chloride (Cl(-)), different nitrogen-species and pathogens/microorganisms. The objective of this work is to introduce a methodology to assess the past and future impacts of such lagoons on regional groundwater quality. The method is based on a spatial statistical analysis of Cl(-) and total nitrogen (TN) concentration distributions in the saturated and the vadose (unsaturated) zones. The method provides quantitative data on the relation between the locations of dairy lagoons and the spatial variability in Cl(-) and TN concentrations in groundwater. The method was applied to the Beer-Tuvia region, Israel, where intensive dairy farming has been practiced for over 50 years above the local phreatic aquifer. Mass balance calculations accounted for the various groundwater recharge and abstraction sources and sinks in the entire region. The mass balances showed that despite the small surface area covered by the dairy lagoons in this region (0.8%), leachates from lagoons have contributed 6.0% and 12.6% of the total mass of Cl(-) and TN (mainly as NO3(-)-N) added to the aquifer. The chemical composition of the aquifer and vadose zone water suggested that irrigated agricultural activity in the region is the main contributor of Cl(-) and TN to the groundwater. A low spatial correlation between the Cl(-) and NO3(-)-N concentrations in the groundwater and the on-land location of the dairy farms strengthened this assumption, despite the dairy waste lagoon being a point source for groundwater contamination by Cl(-) and NO3(-)-N. Mass balance calculations, for the vadose zone of the entire region, indicated that drying of the lagoons would decrease the regional groundwater salinization process (11% of the total Cl(-) load is stored under lagoons). A more considerable reduction in the groundwater contamination by NO3(-)-N is expected (25% of the NO3(-)-N load is stored under lagoons). Results demonstrate that analyzing vadose zone and groundwater data by spatial statistical analysis methods can significantly contribute to the understanding of the relations between groundwater contaminating sources, and to assessing appropriate remediation steps. Copyright © 2013 Elsevier Ltd. All rights reserved.

Mapping groundwater quality distinguishing geogenic and anthropogenic contribution using NBL

NASA Astrophysics Data System (ADS)

Preziosi, Elisabetta; Ducci, Daniela; Condesso de Melo, Maria Teresa; Parrone, Daniele; Sellerino, Mariangela; Ghergo, Stefano; Oliveira, Joana; Ribeiro, Luis

2015-04-01

Groundwaters are threatened by anthropic activities and pollution is interesting a large number of aquifers worldwide. Qualitative and quantitative monitoring is required to assess the status and track its evolution in time and space especially where anthropic pressures are stronger. Up to now, groundwater quality mapping has been performed separately from the assessment of its natural status, i.e. the definition of the natural background level of a particular element in a particular area or groundwater body. The natural background level (NBL) of a substance or element allows to distinguish anthropogenic pollution from contamination of natural origin in a population of groundwater samples. NBLs are the result of different atmospheric, geological, chemical and biological interaction processes during groundwater infiltration and circulation. There is an increasing need for the water managers to have sound indications on good quality groundwater exploitation. Indeed the extension of a groundwater body is often very large, in the order of tens or hundreds of square km. How to select a proper location for good quality groundwater abstraction is often limited to a question of facility for drilling (access, roads, authorizations, etc.) or at the most related to quantitative aspects driven by geophysical exploration (the most promising from a transmissibility point of view). So how to give indications to the administrators and water managers about the exploitation of good quality drinking water? In the case of anthropic contamination, how to define which area is to be restored and to which threshold (e.g. background level) should the concentration be lowered through the restoration measures? In the framework of a common project between research institutions in Italy (funded by CNR) and Portugal (funded by FCT), our objective is to establish a methodology aiming at merging together 1) the evaluation of NBL and 2) the need to take into account the drinking water standards with a spatial analysis. We compare diverse case studies using geochemical maps built by kriging in which we interpolate the conditional probability of exceeding the reference value (i.e. the drinking water standard) OR the local natural background level. The resulting maps provide a useful reference for management purposes.

Quality Assurance Project Plan Development Tool

EPA Pesticide Factsheets

This tool contains information designed to assist in developing a Quality Assurance (QA) Project Plan that meets EPA requirements for projects that involve surface or groundwater monitoring and/or the collection and analysis of water samples.

Use of Principal Components Analysis and Kriging to Predict Groundwater-Sourced Rural Drinking Water Quality in Saskatchewan

PubMed Central

McLeod, Lianne; Bharadwaj, Lalita; Epp, Tasha; Waldner, Cheryl L.

2017-01-01

Groundwater drinking water supply surveillance data were accessed to summarize water quality delivered as public and private water supplies in southern Saskatchewan as part of an exposure assessment for epidemiologic analyses of associations between water quality and type 2 diabetes or cardiovascular disease. Arsenic in drinking water has been linked to a variety of chronic diseases and previous studies have identified multiple wells with arsenic above the drinking water standard of 0.01 mg/L; therefore, arsenic concentrations were of specific interest. Principal components analysis was applied to obtain principal component (PC) scores to summarize mixtures of correlated parameters identified as health standards and those identified as aesthetic objectives in the Saskatchewan Drinking Water Quality Standards and Objective. Ordinary, universal, and empirical Bayesian kriging were used to interpolate arsenic concentrations and PC scores in southern Saskatchewan, and the results were compared. Empirical Bayesian kriging performed best across all analyses, based on having the greatest number of variables for which the root mean square error was lowest. While all of the kriging methods appeared to underestimate high values of arsenic and PC scores, empirical Bayesian kriging was chosen to summarize large scale geographic trends in groundwater-sourced drinking water quality and assess exposure to mixtures of trace metals and ions. PMID:28914824

Use of Principal Components Analysis and Kriging to Predict Groundwater-Sourced Rural Drinking Water Quality in Saskatchewan.

PubMed

McLeod, Lianne; Bharadwaj, Lalita; Epp, Tasha; Waldner, Cheryl L

2017-09-15

Groundwater drinking water supply surveillance data were accessed to summarize water quality delivered as public and private water supplies in southern Saskatchewan as part of an exposure assessment for epidemiologic analyses of associations between water quality and type 2 diabetes or cardiovascular disease. Arsenic in drinking water has been linked to a variety of chronic diseases and previous studies have identified multiple wells with arsenic above the drinking water standard of 0.01 mg/L; therefore, arsenic concentrations were of specific interest. Principal components analysis was applied to obtain principal component (PC) scores to summarize mixtures of correlated parameters identified as health standards and those identified as aesthetic objectives in the Saskatchewan Drinking Water Quality Standards and Objective. Ordinary, universal, and empirical Bayesian kriging were used to interpolate arsenic concentrations and PC scores in southern Saskatchewan, and the results were compared. Empirical Bayesian kriging performed best across all analyses, based on having the greatest number of variables for which the root mean square error was lowest. While all of the kriging methods appeared to underestimate high values of arsenic and PC scores, empirical Bayesian kriging was chosen to summarize large scale geographic trends in groundwater-sourced drinking water quality and assess exposure to mixtures of trace metals and ions.

Groundwater quality in the South Coast Range Coastal groundwater basins, California

USGS Publications Warehouse

Burton, Carmen A.; Belitz, Kenneth

2013-01-01

Groundwater provides more than 40 percent of California’s drinking water. To protect this vital resource, the State of California created the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The Priority Basin Project (PBP) of the GAMA Program provides a comprehensive assessment of the State’s untreated groundwater quality and increases public access to groundwater-quality information. The coastal basins in the Southern Coast Ranges constitute one of the study units being evaluated.

Groundwater-Quality Impacts from Natural-Gas Wellbore Leakage: Numerical Sensitivity Analysis of Hydrogeologic, Geostatistical, and Source-Term Parameterization at Varying Depths

NASA Astrophysics Data System (ADS)

Rice, A. K.; McCray, J. E.; Singha, K.

2016-12-01

The development of directional drilling and stimulation of reservoirs by hydraulic fracturing has transformed the energy landscape in the U.S. by making recovery of hydrocarbons from shale formations not only possible but economically viable. Activities associated with hydraulic fracturing present a set of water-quality challenges, including the potential for impaired groundwater quality. In this project, we use a three-dimensional, multiphase, multicomponent numerical model to investigate hydrogeologic conditions that could lead to groundwater contamination from natural gas wellbore leakage. This work explores the fate of methane that enters a well annulus, possibly from an intermediate formation or from the production zone via a flawed cement seal, and leaves the annulus at one of two depths: at the elevation of groundwater or below a freshwater aquifer. The latter leakage scenario is largely ignored in the current scientific literature, where focus has been on leakage directly into freshwater aquifers, despite modern regulations requiring steel casings and cement sheaths at these depths. We perform a three-stage sensitivity analysis, examining (1) hydrogeologic parameters of media surrounding a methane leakage source zone, (2) geostatistical variations in intrinsic permeability, and (3) methane source zone pressurization. Results indicate that in all cases methane reaches groundwater within the first year of leakage. To our knowledge, this is the first study to consider natural gas wellbore leakage in the context of multiphase flow through heterogeneous permeable media; advantages of multiphase modeling include more realistic analysis of methane vapor-phase relative permeability as compared to single-phase models. These results can be used to inform assessment of aquifer vulnerability to hydrocarbon wellbore leakage at varying depths.

Hydrochemical characteristics and spatial analysis of groundwater quality in parts of Bundelkhand Massif, India

NASA Astrophysics Data System (ADS)

Ali, Syed Ahmad; Ali, Umair

2018-03-01

The tribulations of water quality have become more serious than the quantity, as the environmental evils are getting more severe day by day in different parts of the world. Large number of components like soil, geology, sewage disposal, effluents and other environmental conditions in which the water tends to reside or move and interact with ground and biological characteristics, greatly persuade the groundwater quality. Therefore, hydrochemical study has been carried out graphically and spatially in GIS environment in part of Bundelkhand Massif. The hydrochemical study exposes the water quality by measuring the concentration of parameters and comparing them with the drinking water and irrigation standards. Groundwater samples have been collected and analysed for physiochemical characteristics in order to understand the hydrochemistry of the water. The results revealed that ground water is alkaline in nature and total hardness observed in all samples falls under moderately hard to very hard category. At some places higher concentration of Cl- could be dangerous from health point of view. Major hydrochemical facies were identified using Piper Trilinear diagram and Durov diagrams, etc. Analysis of different determinations such as sodium adsorption ratio, residual sodium carbonate and per cent sodium revealed that most of the samples are unsuitable for irrigation. It was also observed that the quality of groundwater was not suitable for drinking purpose in industrial and irrigation area. In the area, few sampling sites showed unsuitability because of influences of urban and industrial waste discharge, aquifer material mineralogy, other anthropogenic activities and increased human interventions.

Natural and anthropogenic factors affecting the groundwater quality in Serbia.

PubMed

Devic, Gordana; Djordjevic, Dragana; Sakan, Sanja

2014-01-15

Various chemometric techniques were used to analyze the quality of groundwater data sets. Seventeen water quality parameters: the cations Na, K, Ca, Mg, the anions Cl, SO4, NO3, HCO3 and nine trace elements Pb, As, Mn, Ni, Cu, Cd, Fe, Zn and Cr were measured at 66 different key sampling sites in ten representative areas (low land-Northern Autonomous Province of Serbia, Vojvodina and central Serbia) for the summer period of 2009. HCA grouped the sample sites into four clusters based on the similarities of the characteristics of the groundwater quality. DA showed two parameters, HCO3 and Zn, affording more than 90% correct assignments in the spatial analysis of four/three different regions in Serbia. Factor analysis was applied on the log-transformed data sets and allowed the identification of a reduced number of factors with hydrochemical meaning. The results showed severe pollution with Mn, As, NO3, Ni, Pb whereby anthropogenic origin of these contaminants was indicated. The pollution comes from both scattered point sources (industrial and urban effluent) and diffuse source agricultural activity. These samples may not be suitable for human consumption; the water quality belongs to class III/IV (contaminated). The Fe anomalies (7.1mg/L) in the water from the Vetrnica site can be attributed to natural sources, such as the dissolution of rock masses and rock fragments. The serious groundwater contamination with As (25.7-137.8 μg/L) in the area of Banat (Northern Autonomous Province of Serbia, Vojvodina) and a sample No. 9 at the Great Morava River requires urgent attention. © 2013.

Sources of salinity and urban pollution in the Quaternary sand aquifers of Dar es Salaam, Tanzania

NASA Astrophysics Data System (ADS)

Walraevens, Kristine; Mjemah, Ibrahimu Chikira; Mtoni, Yohana; Van Camp, Marc

2015-02-01

Groundwater is globally important for human consumption, and changes in quality can have serious consequences. The study area is within a coastal aquifer where groundwater quality is influenced by various potential sources of salinity that determine the composition of water extracted from wells. Groundwater chemistry data from the aquifer have been acquired to determine the geochemical conditions and processes that occur in this area and assess their implications for aquifer susceptibility. Analysis of groundwater samples shows that the dominant watertype is mostly NaCl with pH < 7 in both aquifers (i.e. upper and lower) except for the shallow wells where CaHCO3 prevails with pH ⩾ 7, and boreholes located near the Indian Ocean, where coral reef limestone deposits are located and the watertype evolves towards CaHCO3. In the lower aquifer, Cl- is higher than in the upper aquifer. The origin of salinity in the area is strongly influenced by groundwater ascending from deep marine Miocene Spatangid Shales through faults, seawater incursion on the border of the Indian Ocean, and throughout, there is some salinity within the Quaternary aquifer, especially in intercalated deltaic clays in the fluviatile deposits, showing some marine influences. The seawater intrusion is linked to the strongly increasing groundwater exploitation since 1997. Another process that plays a major role to the concentration of major ions in the groundwater is calcite dissolution. Next to geogenic salinity and seawater intrusion, anthropogenic pollution as well is affecting groundwater quality in the aquifer. An important result of this study is the observation of high nitrate concentrations, that call for improved sanitation in the area, where domestic sewage with on-site sanitation (mainly pit latrines) also threatens the groundwater resource.

Probability-based nitrate contamination map of groundwater in Kinmen.

PubMed

Liu, Chen-Wuing; Wang, Yeuh-Bin; Jang, Cheng-Shin

2013-12-01

Groundwater supplies over 50% of drinking water in Kinmen. Approximately 16.8% of groundwater samples in Kinmen exceed the drinking water quality standard (DWQS) of NO3 (-)-N (10 mg/L). The residents drinking high nitrate-polluted groundwater pose a potential risk to health. To formulate effective water quality management plan and assure a safe drinking water in Kinmen, the detailed spatial distribution of nitrate-N in groundwater is a prerequisite. The aim of this study is to develop an efficient scheme for evaluating spatial distribution of nitrate-N in residential well water using logistic regression (LR) model. A probability-based nitrate-N contamination map in Kinmen is constructed. The LR model predicted the binary occurrence probability of groundwater nitrate-N concentrations exceeding DWQS by simple measurement variables as independent variables, including sampling season, soil type, water table depth, pH, EC, DO, and Eh. The analyzed results reveal that three statistically significant explanatory variables, soil type, pH, and EC, are selected for the forward stepwise LR analysis. The total ratio of correct classification reaches 92.7%. The highest probability of nitrate-N contamination map presents in the central zone, indicating that groundwater in the central zone should not be used for drinking purposes. Furthermore, a handy EC-pH-probability curve of nitrate-N exceeding the threshold of DWQS was developed. This curve can be used for preliminary screening of nitrate-N contamination in Kinmen groundwater. This study recommended that the local agency should implement the best management practice strategies to control nonpoint nitrogen sources and carry out a systematic monitoring of groundwater quality in residential wells of the high nitrate-N contamination zones.

Hydrogeochemistry and groundwater quality assessment along Wadi Al Showat, Khamis Mushiet District, Southwest Saudi Arabia

NASA Astrophysics Data System (ADS)

Alhumidan, S. M.; Alfaifi, H. J.; Ibrahim, E. K. E.; Abdel Rahman, K.

2015-12-01

In the present study, the hydrochemistry and geologic characteristics of the shallow groundwater aquifer along Wadi Al Showat, Khamis Mushiet District, Southwest Saudi Arabia was evaluated and assessed. Along this wadi the fractured/weathered basement rocks house significant quantity of groundwater that usually used by local people for agricultural and domestic purposes. Assessing and evaluation of the quality of the groundwater in such shallow aquifers is very important; especially the groundwater is generally occurred within the fractured basement rocks at shallow depths, thus exposing the groundwater to surface or near-surface contaminants is expected. For this purpose hydrochemical and biological analysis was conducted for 25 water samples collected from the available shallow dug wells along the studied wadi. The study reveals that the groundwater quality changed due to the agriculture and urbanization practices along the wadi. The effect of domestic waste water and septic tanks was obvious. In addition, the field investigation indicates that the basement rocks in the area is dissected by two main sets of fractures that oriented in the west-northwest and east-west directions. In some places, the basement rocks is intruded by coarse-grained, quartz-rich quartzite grained monzogranite, and pegmatite veins that have a coarse-grained weathering product, therefore, they tend to develop and preserve open joint systems between the granitic blocks. These fracturing system are important from the hydrogeological point of view, as they facilitate the storage, water flow movement through them and also facilitate the vertical infiltration of the surface pollutants. These results led to a better understanding of the groundwater characteristics that is important in groundwater management in the study area.

Groundwater quality in the Northern Sacramento Valley, California

USGS Publications Warehouse

Bennett, George L.; Fram, Miranda S.; Belitz, Kenneth

2011-01-01

Groundwater provides more than 40 percent of California's drinking water. To protect this vital resource, the State of California created the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The Priority Basin Project of the GAMA Program provides a comprehensive assessment of the State's groundwater quality and increases public access to groundwater-quality information. The Northern Sacramento Valley is one of the study units being evaluated.

Groundwater quality in the Southern Sacramento Valley, California

USGS Publications Warehouse

Bennett, George L.; Fram, Miranda S.; Belitz, Kenneth

2011-01-01

Groundwater provides more than 40 percent of California's drinking water. To protect this vital resource, the State of California created the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The Priority Basin Project of the GAMA Program provides a comprehensive assessment of the State's groundwater quality and increases public access to groundwater-quality information. The Southern Sacramento Valley is one of the study units being evaluated.

Groundwater quality in the Santa Barbara Coastal Plain, California

USGS Publications Warehouse

Davis, Tracy A.; Belitz, Kenneth

2016-10-03

Groundwater provides more than 40 percent of California’s drinking water. To protect this vital resource, the State of California established the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The Priority Basin Project of the GAMA Program provides a comprehensive assessment of the State’s groundwater quality and increases public access to groundwater-quality information. The Santa Barbara Coastal Plain is one of the study units.

Groundwater quality in the Klamath Mountains, California

USGS Publications Warehouse

Bennett, George L.; Fram, Miranda S.

2014-01-01

Groundwater provides more than 40 percent of California’s drinking water. To protect this vital resource, the State of California created the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The Priority Basin Project of the GAMA Program provides a comprehensive assessment of the State’s groundwater quality and increases public access to groundwater-quality information. The Klamath Mountains constitute one of the study units being evaluated.

Temperature change affected groundwater quality in a confined marine aquifer during long-term heating and cooling.

PubMed

Saito, Takeshi; Hamamoto, Shoichiro; Ueki, Takashi; Ohkubo, Satoshi; Moldrup, Per; Kawamoto, Ken; Komatsu, Toshiko

2016-05-01

Global warming and urbanization together with development of subsurface infrastructures (e.g. subways, shopping complexes, sewage systems, and Ground Source Heat Pump (GSHP) systems) will likely cause a rapid increase in the temperature of relatively shallow groundwater reservoirs (subsurface thermal pollution). However, potential effects of a subsurface temperature change on groundwater quality due to changed physical, chemical, and microbial processes have received little attention. We therefore investigated changes in 34 groundwater quality parameters during a 13-month enhanced-heating period, followed by 14 months of natural or enhanced cooling in a confined marine aquifer at around 17 m depth on the Saitama University campus, Japan. A full-scale GSHP test facility consisting of a 50 m deep U-tube for circulating the heat-carrying fluid and four monitoring wells at 1, 2, 5, and 10 m from the U-tube were installed, and groundwater quality was monitored every 1-2 weeks. Rapid changes in the groundwater level in the area, especially during the summer, prevented accurate analyses of temperature effects using a single-well time series. Instead, Dual-Well Analysis (DWA) was applied, comparing variations in subsurface temperature and groundwater chemical concentrations between the thermally-disturbed well and a non-affected reference well. Using the 1 m distant well (temperature increase up to 7 °C) and the 10 m distant well (non-temperature-affected), the DWA showed an approximately linear relationships for eight components (B, Si, Li, dissolved organic carbon (DOC), Mg(2+), NH4(+), Na(+), and K(+)) during the combined 27 months of heating and cooling, suggesting changes in concentration between 4% and 31% for a temperature change of 7 °C. Copyright © 2016 Elsevier Ltd. All rights reserved.

Effects of seasonal operation on the quality of water produced by public-supply wells.

PubMed

Bexfield, Laura M; Jurgens, Bryant C

2014-09-01

Seasonal variability in groundwater pumping is common in many places, but resulting effects of seasonal pumping stress on the quality of water produced by public-supply wells are not thoroughly understood. Analysis of historical water-quality samples from public-supply wells completed in deep basin-fill aquifers in Modesto, California (134 wells) and Albuquerque, New Mexico (95 wells) indicates that several wells have seasonal variability in concentrations of contaminants of concern. In Modesto, supply wells are more likely to produce younger groundwater with higher nitrate and uranium concentrations during the summer (high) pumping season than during the winter (low) pumping season. In Albuquerque, supply wells are more likely to produce older groundwater with higher arsenic concentrations during the winter pumping season than during the summer pumping season. Seasonal variability in contaminant concentrations in Modesto is influenced primarily by effects of summer pumping on vertical hydraulic gradients that drive migration of shallow groundwater through the aquifer to supply wells. Variability in Albuquerque is influenced primarily by the period of time that a supply well is idle, allowing its wellbore to act as a conduit for vertical groundwater flow and contaminant migration. However, both processes are observed in each study area. Similar findings would appear to be likely in other alluvial basins with stratified water quality and substantial vertical head gradients. Results suggest that even in aquifers dominated by old groundwater, changes to seasonal pumping patterns and/or to depth of well completion can help reduce vulnerability to selected contaminants of either natural or anthropogenic origin. Published 2014. This article is a U.S. Government work and is in the public domain in the USA. Groundwater published by Wiley Periodicals, Inc. on behalf of National Ground Water Association.

Methods of Statistical Control for Groundwater Quality Indicators

NASA Astrophysics Data System (ADS)

Yankovich, E.; Nevidimova, O.; Yankovich, K.

2016-06-01

The article describes the results of conducted groundwater quality control. Controlled quality indicators included the following microelements - barium, manganese, iron, mercury, iodine, chromium, strontium, etc. Quality control charts - X-bar chart and R chart - were built. For the upper and the lower threshold limits, maximum permissible concentration of components in water and the lower limit of their biologically significant concentration, respectively, were selected. The charts analysis has shown that the levels of microelements content in water at the area of study are stable. Most elements in the underground water are contained in concentrations, significant for human organisms consuming the water. For example, such elements as Ba, Mn, Fe have concentrations that exceed maximum permissible levels for drinking water.

Effects of natural and human factors on groundwater quality of basin-fill aquifers in the southwestern United States-conceptual models for selected contaminants

USGS Publications Warehouse

Bexfield, Laura M.; Thiros, Susan A.; Anning, David W.; Huntington, Jena M.; McKinney, Tim S.

2011-01-01

As part of the U.S. Geological Survey National Water-Quality Assessment (NAWQA) Program, the Southwest Principal Aquifers (SWPA) study is building a better understanding of the factors that affect water quality in basin-fill aquifers in the Southwestern United States. The SWPA study area includes four principal aquifers of the United States: the Basin and Range basin-fill aquifers in California, Nevada, Utah, and Arizona; the Rio Grande aquifer system in New Mexico and Colorado; and the California Coastal Basin and Central Valley aquifer systems in California. Similarities in the hydrogeology, land- and water-use practices, and water-quality issues for alluvial basins within the study area allow for regional analysis through synthesis of the baseline knowledge of groundwater-quality conditions in basins previously studied by the NAWQA Program. Resulting improvements in the understanding of the sources, movement, and fate of contaminants are assisting in the development of tools used to assess aquifer susceptibility and vulnerability.This report synthesizes previously published information about the groundwater systems and water quality of 15 information-rich basin-fill aquifers (SWPA case-study basins) into conceptual models of the primary natural and human factors commonly affecting groundwater quality with respect to selected contaminants, thereby helping to build a regional understanding of the susceptibility and vulnerability of basin-fill aquifers to those contaminants. Four relatively common contaminants (dissolved solids, nitrate, arsenic, and uranium) and two contaminant classes (volatile organic compounds (VOCs) and pesticide compounds) were investigated for sources and controls affecting their occurrence and distribution above specified levels of concern in groundwater of the case-study basins. Conceptual models of factors that are important to aquifer vulnerability with respect to those contaminants and contaminant classes were subsequently formed. The conceptual models are intended in part to provide a foundation for subsequent development of regional-scale statistical models that relate specific constituent concentrations or occurrence in groundwater to natural and human factors.

Monitoring-well installation, slug testing, and groundwater quality for selected sites in South Park, Park County, Colorado, 2013

USGS Publications Warehouse

Arnold, Larry R. Rick

2015-01-01

During May–June, 2013, the U.S. Geological Survey, in cooperation with Park County, Colorado, drilled and installed four groundwater monitoring wells in areas identified as needing new wells to provide adequate spatial coverage for monitoring water quality in the South Park basin. Lithologic logs and well-construction reports were prepared for each well, and wells were developed after drilling to remove mud and foreign material to provide for good hydraulic connection between the well and aquifer. Slug tests were performed to estimate hydraulic-conductivity values for aquifer materials in the screened interval of each well, and groundwater samples were collected from each well for analysis of major inorganic constituents, trace metals, nutrients, dissolved organic carbon, volatile organic compounds, ethane, methane, and radon. Documentation of lithologic logs, well construction, well development, slug testing, and groundwater sampling are presented in this report.

Nutrients in the Nation?s streams and groundwater: National Findings and Implications

USGS Publications Warehouse

Dubrovsky, Neil M.; Hamilton, Pixie A.

2010-01-01

A comprehensive national analysis of the distribution and trends of nutrient concentrations in streams and groundwater from 1992 through 2004 is provided by the National Water-Quality Assessment (NAWQA) Program of the United States Geological Survey (USGS). Findings describe the distribution and causes of varying nutrient concentrations in streams and groundwater throughout the Nation and examine the primary sources that contribute to elevated concentrations. Results show that excessive nutrient enrichment is a widespread cause of ecological degradation in streams and that nitrate contamination of groundwater used for drinking water, particularly shallow domestic wells in agricultural areas, is a continuing human-health concern. Finally, despite major Federal, State and local nonpoint-source nutrient control efforts for streams and watersheds across the Nation, USGS trend analyses for 1993?2003 suggest limited national progress to reduce the impacts of nonpoint sources of nutrients during this period. Instead, concentrations have remained the same or increased in many streams and aquifers across the Nation, and continue to pose risks to aquatic life and human health. This Fact Sheet highlights selected national findings and their implications, and serves as a companion product to the complete analysis reported in the USGS Circular titled ?The Quality of Our Nation?s Waters?Nutrients in the Nation?s Streams and Groundwater, 1992?2004.?

Derivation of groundwater threshold values for analysis of impacts predicted at potential carbon sequestration sites

DOE Office of Scientific and Technical Information (OSTI.GOV)

Last, G. V.; Murray, C. J.; Bott, Y.

2016-06-01

The U.S. Department of Energy’s (DOE’s) National Risk Assessment Partnership (NRAP) Project is developing reduced-order models to evaluate potential impacts to groundwater quality due to carbon dioxide (CO 2) or brine leakage, should it occur from deep CO 2 storage reservoirs. These efforts targeted two classes of aquifer – an unconfined fractured carbonate aquifer based on the Edwards Aquifer in Texas, and a confined alluvium aquifer based on the High Plains Aquifer in Kansas. Hypothetical leakage scenarios focus on wellbores as the most likely conduits from the storage reservoir to an underground source of drinking water (USDW). To facilitate evaluationmore » of potential degradation of the USDWs, threshold values, below which there would be no predicted impacts, were determined for each of these two aquifer systems. These threshold values were calculated using an interwell approach for determining background groundwater concentrations that is an adaptation of methods described in the U.S. Environmental Protection Agency’s Unified Guidance for Statistical Analysis of Groundwater Monitoring Data at RCRA Facilities. Results demonstrate the importance of establishing baseline groundwater quality conditions that capture the spatial and temporal variability of the USDWs prior to CO 2 injection and storage.« less

Increasing the utility of regional water table maps: a new method for estimating groundwater recharge

NASA Astrophysics Data System (ADS)

Gilmore, T. E.; Zlotnik, V. A.; Johnson, M.

2017-12-01

Groundwater table elevations are one of the most fundamental measurements used to characterize unconfined aquifers, groundwater flow patterns, and aquifer sustainability over time. In this study, we developed an analytical model that relies on analysis of groundwater elevation contour (equipotential) shape, aquifer transmissivity, and streambed gradient between two parallel, perennial streams. Using two existing regional water table maps, created at different times using different methods, our analysis of groundwater elevation contours, transmissivity and streambed gradient produced groundwater recharge rates (42-218 mm yr-1) that were consistent with previous independent recharge estimates from different methods. The three regions we investigated overly the High Plains Aquifer in Nebraska and included some areas where groundwater is used for irrigation. The three regions ranged from 1,500 to 3,300 km2, with either Sand Hills surficial geology, or Sand Hills transitioning to loess. Based on our results, the approach may be used to increase the value of existing water table maps, and may be useful as a diagnostic tool to evaluate the quality of groundwater table maps, identify areas in need of detailed aquifer characterization and expansion of groundwater monitoring networks, and/or as a first approximation before investing in more complex approaches to groundwater recharge estimation.

A city scale study on the effects of intensive groundwater heat pump systems on heavy metal contents in groundwater.

PubMed

García-Gil, Alejandro; Epting, Jannis; Garrido, Eduardo; Vázquez-Suñé, Enric; Lázaro, Jesús Mateo; Sánchez Navarro, José Ángel; Huggenberger, P; Calvo, Miguel Ángel Marazuela

2016-12-01

As a result of the increasing use of shallow geothermal resources, hydraulic, thermal and chemical impacts affecting groundwater quality can be observed with ever increasing frequency (Possemiers et al., 2014). To overcome the uncertainty associated with chemical impacts, a city scale study on the effects of intensive geothermal resource use by groundwater heat pump systems on groundwater quality, with special emphasis on heavy metal contents was performed. Statistical analysis of geochemical data obtained from several field campaigns has allowed studying the spatiotemporal relationship between temperature anomalies in the aquifer and trace element composition of groundwater. The relationship between temperature and the concentrations of trace elements resulted in weak correlations, indicating that temperature changes are not the driving factor in enhancing heavy metal contaminations. Regression models established for these correlations showed a very low reactivity or response of heavy metal contents to temperature changes. The change rates of heavy metal contents with respect to temperature changes obtained indicate a low risk of exceeding quality threshold values by means of the exploitation regimes used, neither producing nor enhancing contamination significantly. However, modification of pH, redox potential, electrical conductivity, dissolved oxygen and alkalinity correlated with the concentrations of heavy metals. In this case, the change rates of heavy metal contents are higher, with a greater risk of exceeding threshold values. Copyright © 2016 Elsevier B.V. All rights reserved.

Geology and ground-water resources of Dane County, Wisconsin

USGS Publications Warehouse

Cline, Denzel R.

1965-01-01

The purpose of the ground-water investigation of Dane County, Wis., was to determine the occurrence, movement, quantity, quality, and availability of ground water in the unconsolidated deposits and the underlying bedrock. The relationships between ground water and surface water were studied in general in Dane County and in detail in the Madison metropolitan area. An analysis was made of the hydrologic system of the Yahara River valley and of the effects of ground-water pumpage on that system.

Technology Transfer Opportunities: Automated Ground-Water Monitoring, A Proven Technology

USGS Publications Warehouse

Smith, Kirk P.; Granato, Gregory E.

1998-01-01

Introduction The U.S. Geological Survey (USGS) has developed and tested an automated ground-water monitoring system that measures and records values of selected water-quality properties and constituents using protocols approved for manual sampling. Prototypes using the automated process have demonstrated the ability to increase the quantity and quality of data collected and have shown the potential for reducing labor and material costs for ground-water quality data collection. Automated ground-water monitoring systems can be used to monitor known or potential contaminant sites, such as near landfills, underground storage tanks, or other facilities where potential contaminants are stored, to serve as early warning systems monitoring ground-water quality near public water-supply wells, and for ground-water quality research.

Groundwater quality in the Sierra Nevada, California

USGS Publications Warehouse

Fram, Miranda S.; Belitz, Kenneth

2014-01-01

Groundwater provides more than 40 percent of California’s drinking water. To protect this vital resource, the State of California created the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The Priority Basin Project (PBP) of the GAMA Program provides a comprehensive assessment of the State’s groundwater quality and increases public access to groundwater-quality information. The Sierra Nevada Regional study unit constitutes one of the study units being evaluated.

Groundwater quality in the Tahoe and Martis Basins, California

USGS Publications Warehouse

Fram, Miranda S.; Belitz, Kenneth

2012-01-01

Groundwater provides more than 40 percent of California's drinking water. To protect this vital resource, the State of California created the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The Priority Basin Project of the GAMA Program provides a comprehensive assessment of the State's groundwater quality and increases public access to groundwater-quality information. The Tahoe and Martis Basins and surrounding watersheds constitute one of the study units being evaluated.

Groundwater quality in the South Coast Interior Basins, California

USGS Publications Warehouse

Parsons, Mary C.; Belitz, Kenneth

2014-01-01

Groundwater provides more than 40 percent of California’s drinking water. To protect this vital resource, the State of California created the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The Priority Basin Project of the GAMA Program provides a comprehensive assessment of the State’s untreated groundwater quality and increases public access to groundwater-quality information. The South Coast Interior Basins constitute one of the study units being evaluated.

Groundwater quality in the western San Joaquin Valley, California

USGS Publications Warehouse

Fram, Miranda S.

2017-06-09

Groundwater provides more than 40 percent of California’s drinking water. To protect this vital resource, the State of California created the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The Priority Basin Project of the GAMA Program provides a comprehensive assessment of the State’s groundwater quality and increases public access to groundwater-quality information. The Western San Joaquin Valley is one of the study units being evaluated. 

Groundwater quality in the shallow aquifers of the Tulare, Kaweah, and Tule Groundwater Basins and adjacent highlands areas, Southern San Joaquin Valley, California

USGS Publications Warehouse

Fram, Miranda S.

2017-01-18

Groundwater provides more than 40 percent of California’s drinking water. To protect this vital resource, the State of California created the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The Priority Basin Project of the GAMA Program provides a comprehensive assessment of the State’s groundwater quality and increases public access to groundwater-quality information. The shallow aquifers of the Tulare, Kaweah, and Tule groundwater basins and adjacent highlands areas of the southern San Joaquin Valley constitute one of the study units being evaluated.

40 CFR 257.23 - Ground-water sampling and analysis requirements.

Code of Federal Regulations, 2014 CFR

2014-07-01

... parameters shall be determined after considering the number of samples in the background data base, the data... considering the number of samples in the background data base, the data distribution, and the range of the... of § 257.22(a)(1). (f) The number of samples collected to establish ground-water quality data must be...

40 CFR 257.23 - Ground-water sampling and analysis requirements.

Code of Federal Regulations, 2012 CFR

2012-07-01

... parameters shall be determined after considering the number of samples in the background data base, the data... considering the number of samples in the background data base, the data distribution, and the range of the... of § 257.22(a)(1). (f) The number of samples collected to establish ground-water quality data must be...

Evaluation of groundwater quality and assessment of scaling potential and corrosiveness of water samples in Kadkan aquifer, Khorasan-e-Razavi Province, Iran.

PubMed

Esmaeili-Vardanjani, Mostafa; Rasa, Iraj; Amiri, Vahab; Yazdi, Mohammad; Pazand, Kaveh

2015-02-01

The chemical analysis of 129 groundwater samples in the Kadkan area, Khorasan-e-Razavi Province, NE of Iran was evaluated to determine the hydrochemical processes, assessment of groundwater quality for irrigation purposes, corrosiveness, and scaling potential of the groundwater. Accordingly, the suitability of groundwater for irrigation was evaluated based on the sodium adsorption ratio, residual sodium carbonate, sodium percent, salinity hazard, and US Salinity Laboratory hazard diagram. Based on the electrical conductivity and sodium adsorption ratio, the dominant classes are C3-S1, C3-S2, C2-S1, and C4-S2. According to the Wilcox plot, about 50 % of the samples fall in the "Excellent to Good" and "Good to Permissible" classes. Besides, the Langelier saturation index, Ryznar stability index (RSI), Larson-Skold index, and Puckorius scaling index were evaluated for assessing the corrosiveness and scaling potential of the groundwater. Corrosiveness and scaling indices stated that the majority of samples are classified into "Aggressive" and "Very Aggressive" category. In addition, chloride and sulfate interfere in 90 % of the samples. Assessment of hydrochemical characteristics indicates Na-Mg-Cl as the predominant hydrochemical type. Spatial distribution of hydrochemical parameters indicates that hydrochemical processes are influenced by geology and hydrogeology of Kadkan aquifer. The Gibbs plots gave an indication that groundwater chemistry in this area may have acquired the chemistry mainly from evaporation and mineral precipitation. Grouping the samples based on Q-mode hierarchical cluster analysis helped to more separation of similar samples. The R-mode HCA grouped analyzed parameters into two groups based on similarity of hydrochemical characteristics. As a result, the samples collected in northern and southern parts of the study area show the best quality (i.e., lowest salinity) for some purposes such as irrigation and drinking.

Regional Analysis of the Effects of Oil and Gas Development on Groundwater Resources in California

NASA Astrophysics Data System (ADS)

Landon, M. K.; McMahon, P. B.; Kulongoski, J. T.; Ball, L. B.; Gillespie, J. M.; Shimabukuro, D.; Taylor, K. A.

2016-12-01

The California State Water Resources Control Board is collaborating with the U.S. Geological Survey to implement a Regional Monitoring Program (RMP) to assess potential interactions between oil/gas stimulation treatment and groundwater resources. The effects of stimulation on groundwater resources will be difficult to distinguish from the effects of other past or present components of oil and gas development. As a result, the RMP is designed to provide an overall assessment of the effects of oil and gas development on groundwater quality. During 2016-17, the study is focused on selected priority oilfields in the eastern and western portions of the San Joaquin Valley in Kern County to: (1) produce three-dimensional (3D) salinity maps, (2) characterize the chemical composition of groundwater and produced water, and (3) identify the extent to which fluids from oil and gas development may be moving into protected (total dissolved solids less than 10,000 milligrams per liter) groundwater at regional scales. Analysis of available salinity data near oil/gas fields indicates there are regional patterns to salinity depth profiles; however, data gaps between the depths of water and oil/gas wells are common. These results provide a foundation for more detailed oilfield-scale salinity mapping, which includes geophysical methods (borehole, surface, and airborne) to fill data gaps. The RMP sampling-well networks are designed to evaluate groundwater quality along transects from oil/gas fields into adjacent aquifers and consist of existing wells supplemented by monitoring-well installation in priority locations identified by using 3D visualization of hydrogeologic data. The analytes include constituents with different transport characteristics such as dissolved gases, inorganic components (brines), and petroleum compounds. Analytes were selected because of their potential usefulness for understanding processes and pathways by which fluids from oilfield sources reach groundwater.

Groundwater quality assessment in semi-arid regions using integrated approaches: the case of Grombalia aquifer (NE Tunisia).

PubMed

Kammoun, Siwar; Trabelsi, Rim; Re, Viviana; Zouari, Kamel; Henchiri, Jihed

2018-01-19

As many arid and semi-arid regions in the Mediterranean Basin, the Grombalia coastal aquifer (NE Tunisia) is affected by severe groundwater exploitation and contamination. Therefore, quality assessments are becoming increasingly important as the long-term protection of water resources is at stake. Multidisciplinary investigations, like the one presented in this paper, are particularly effective in identifying the different origins of mineralization within an aquifer and investigating the impact of anthropogenic activities on groundwater quality. An integrated assessment, focused on the combined use of geostatistical, geochemical and isotopic (δ 18 O, δ 2 H and 3 H) tools, was performed in the Grombalia aquifer between February and March 2014. The overall goal was to study the main processes controlling aquifer salinization, with special focus to nitrate contamination. Results indicate a persisting deterioration of water quality over the whole basin except the south-eastern zone juxtaposing the recharge area of the aquifer. Nitrate contents exceed the drinking water standard (50 mg/l) in 70% of groundwater samples, mainly due to the excessive use of fertilizers and urban activities. Stable isotope measurements showed the contribution of modern rainwater to aquifer recharge and proved the presence of evaporation contributing to the salinity increase. Tritium values of groundwater samples suggested two hypotheses: the existence of mixture between old and recent water or/and the existence of two recharge periods of the aquifer, pre- and post-nuclear weapons test. Principal component analysis confirmed the geochemical interpretation, highlighting that water-rock interaction evaporation effect and intensive anthropogenic activities constitute the main processes controlling the regional groundwater mineralization.

The impact of on-site wastewater from high density cluster developments on groundwater quality

NASA Astrophysics Data System (ADS)

Morrissey, P. J.; Johnston, P. M.; Gill, L. W.

2015-11-01

The net impact on groundwater quality from high density clusters of unsewered housing across a range of hydro(geo)logical settings has been assessed. Four separate cluster development sites were selected, each representative of different aquifer vulnerability categories. Groundwater samples were collected on a monthly basis over a two year period for chemical and microbiological analysis from nested multi-horizon sampling boreholes upstream and downstream of the study sites. The field results showed no statistically significant difference between upstream and downstream water quality at any of the study areas, although there were higher breakthroughs in contaminants in the High and Extreme vulnerability sites linked to high intensity rainfall events; these however, could not be directly attributed to on-site effluent. Linked numerical models were then built for each site using HYDRUS 2D to simulate the attenuation of contaminants through the unsaturated zone from which the resulting hydraulic and contaminant fluxes at the water table were used as inputs into MODFLOW MT3D models to simulate the groundwater flows. The results of the simulations confirmed the field observations at each site, indicating that the existing clustered on-site wastewater discharges would only cause limited and very localised impacts on groundwater quality, with contaminant loads being quickly dispersed and diluted downstream due to the relatively high groundwater flow rates. Further simulations were then carried out using the calibrated models to assess the impact of increasing cluster densities revealing little impact at any of the study locations up to a density of 6 units/ha with the exception of the Extreme vulnerability site.

Effects of seasonal operation on the quality of water produced by public-supply wells

USGS Publications Warehouse

Bexfield, Laura M.; Jurgens, Bryant C.

2014-01-01

Seasonal variability in groundwater pumping is common in many places, but resulting effects of seasonal pumping stress on the quality of water produced by public-supply wells are not thoroughly understood. Analysis of historical water-quality samples from public-supply wells completed in deep basin-fill aquifers in Modesto, California (134 wells) and Albuquerque, New Mexico (95 wells) indicates that several wells have seasonal variability in concentrations of contaminants of concern. In Modesto, supply wells are more likely to produce younger groundwater with higher nitrate and uranium concentrations during the summer (high) pumping season than during the winter (low) pumping season. In Albuquerque, supply wells are more likely to produce older groundwater with higher arsenic concentrations during the winter pumping season than during the summer pumping season. Seasonal variability in contaminant concentrations in Modesto is influenced primarily by effects of summer pumping on vertical hydraulic gradients that drive migration of shallow groundwater through the aquifer to supply wells. Variability in Albuquerque is influenced primarily by the period of time that a supply well is idle, allowing its wellbore to act as a conduit for vertical groundwater flow and contaminant migration. However, both processes are observed in each study area. Similar findings would appear to be likely in other alluvial basins with stratified water quality and substantial vertical head gradients. Results suggest that even in aquifers dominated by old groundwater, changes to seasonal pumping patterns and/or to depth of well completion can help reduce vulnerability to selected contaminants of either natural or anthropogenic origin.

Effects of Seasonal Operation on the Quality of Water Produced by Public-Supply Wells

PubMed Central

Bexfield, Laura M; Jurgens, Bryant C

2014-01-01

Seasonal variability in groundwater pumping is common in many places, but resulting effects of seasonal pumping stress on the quality of water produced by public-supply wells are not thoroughly understood. Analysis of historical water-quality samples from public-supply wells completed in deep basin-fill aquifers in Modesto, California (134 wells) and Albuquerque, New Mexico (95 wells) indicates that several wells have seasonal variability in concentrations of contaminants of concern. In Modesto, supply wells are more likely to produce younger groundwater with higher nitrate and uranium concentrations during the summer (high) pumping season than during the winter (low) pumping season. In Albuquerque, supply wells are more likely to produce older groundwater with higher arsenic concentrations during the winter pumping season than during the summer pumping season. Seasonal variability in contaminant concentrations in Modesto is influenced primarily by effects of summer pumping on vertical hydraulic gradients that drive migration of shallow groundwater through the aquifer to supply wells. Variability in Albuquerque is influenced primarily by the period of time that a supply well is idle, allowing its wellbore to act as a conduit for vertical groundwater flow and contaminant migration. However, both processes are observed in each study area. Similar findings would appear to be likely in other alluvial basins with stratified water quality and substantial vertical head gradients. Results suggest that even in aquifers dominated by old groundwater, changes to seasonal pumping patterns and/or to depth of well completion can help reduce vulnerability to selected contaminants of either natural or anthropogenic origin. PMID:24593780

Geophysical detection of on-site wastewater plumes in the North Carolina Coastal Plain, USA

NASA Astrophysics Data System (ADS)

Smith, Matthew

Nonpoint source pollution (NPS) continues to be the leading cause of water quality degradation in the United States. On-site wastewater systems (OWS) contribute to NPS; however, due to the range of system designs and complexity of the subsurface, OWS contributions to groundwater pollution are not well understood. As the population of coastal North Carolina continues to increase, better methods to locate and characterize wastewater impacted groundwater are needed. Previous studies have demonstrated the ability of non-intrusive geophysical methods to provide high resolution information on various contaminants in different geologic settings. The goals of this study were to evaluate the utility of ground penetrating radar (GPR) and capacitively coupled resistivity (CCR) for detecting OWS components, delineating associated wastewater plumes, and monitoring temporal variations in groundwater quality. Cross-sectional and three dimensional (3D) geophysical surveys were conducted periodically over a one year period (February 2011--January 2012) at two schools utilizing OWS in the lower Neuse River Basin (NRB) in the North Carolina Coastal Plain (NCCP). Cores were collected at both study sites; as well as monthly groundwater depth, temperature, and specific conductivity measurements to better constrain the geophysical interpretations. Additionally, dissolved inorganic nitrogen (DIN) and Cl concentrations were monitored bi-monthly to assess nutrient transport at the sites. The 3D GPR surveys effectively located the wastewater drainage trenches at both sites, in close agreement with locations described in as-built OWS blueprints. Regression analysis of resistivity versus groundwater specific conductivity revealed an inverse relationship, suggesting resistivity ≤ 250 ohm.m was indicative of wastewater impacted groundwater at both sites. The 3D resistivity models identified regions of low resistivity beneath the drainfields relative to background values. Regression analysis of GPR signal absolute peak amplitude (APA) versus groundwater specific conductivity revealed a decrease in APA indicative of radar signal attenuation at locations where groundwater specific conductivity was elevated. The 3D GPR models identified regions of attenuated radar signal beneath the drainfields relative to background locations. Comparisons of groundwater specific conductivity, GPR, and CCR lateral wastewater plume estimates indicated similar dimensions at both sites. The sensitivity of resistivity measurements tended to decline with increased water-table depth; although, differences in resistivity associated with seasonal water-table depth changes were noticeable. Overall, results of this study suggest that GPR and CCR surveys combined with sediment, hydrologic, and water quality data may provide reliable information on the location of OWS components and extent of associated wastewater plumes. The GPR surveys successfully located the wastewater drainage trenches and helped image the uppermost surface of the wastewater plumes. The CCR surveys delineated the lateral wastewater plume dimensions and revealed temporal changes in groundwater quality associated with differences in groundwater recharge.

Groundwater quality in the North San Francisco Bay shallow aquifer, California

USGS Publications Warehouse

Bennett, George L.; Fram, Miranda S.

2018-02-23

Groundwater provides more than 40 percent of California’s drinking water. To protect this vital resource, the State of California created the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The Priority Basin Project of the GAMA Program provides a comprehensive assessment of the State’s groundwater quality and increases public access to groundwater-quality information. The North San Francisco Bay Shallow Aquifer constitutes one of the study units being evaluated.

Groundwater quality in the Borrego Valley, Central Desert, and Low-Use Basins of the Mojave and Sonoran Deserts, California

USGS Publications Warehouse

Parsons, Mary C.; Belitz, Kenneth

2014-01-01

Groundwater provides more than 40 percent of California’s drinking water. To protect this vital resource, the State of California created the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The Priority Basin Project of the GAMA Program provides a comprehensive assessment of the State’s untreated groundwater quality and increases public access to groundwater-quality information. Selected groundwater basins in the Borrego Valley, Central Desert, and Low-Use Basins of the Mojave and Sonoran Deserts constitute one of the study units being evaluated.

Groundwater quality in the shallow aquifers of the Monterey Bay, Salinas Valley, and adjacent highland areas, California

USGS Publications Warehouse

Burton, Carmen

2018-05-30

Groundwater provides more than 40 percent of California’s drinking water. To protect this vital resource, the State of California created the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The Priority Basin Project of the GAMA Program provides a comprehensive assessment of the State’s groundwater quality and increases public access to groundwater-quality information. The shallow aquifers of the groundwater basins around Monterey Bay, the Salinas Valley, and the highlands adjacent to the Salinas Valley constitute one of the study units.

Response of the groundwater system in the Guanzhong Basin (central China) to climate change and human activities

NASA Astrophysics Data System (ADS)

Wang, Wenke; Zhang, Zaiyong; Duan, Lei; Wang, Zhoufeng; Zhao, Yaqian; Zhang, Qian; Dai, Meiling; Liu, Huizhong; Zheng, Xiaoyan; Sun, Yibo

2018-03-01

The Guanzhong Basin in central China features a booming economy and has suffered severe drought, resulting in serious groundwater depletion in the last 30 years. As a major water resource, groundwater plays a significant role in water supply. The combined impact of climate change and intensive human activities has caused a substantial decline in groundwater recharge and groundwater levels, as well as degradation of groundwater quality and associated changes in the ecosystems. Based on observational data, an integrated approach was used to assess the impact of climate change and human activities on the groundwater system and the base flow of the river basin. Methods included: river runoff records and a multivariate statistical analysis of data including historical groundwater levels and climate; hydro-chemical investigation and trend analysis of the historical hydro-chemical data; wavelet analysis of climate data; and the base flow index. The analyses indicate a clear warming trend and a decreasing trend in rainfall since the 1960s, in addition to increased human activities since the 1970s. The reduction of groundwater recharge in the past 30 years has led to a continuous depletion of groundwater levels, complex changes of the hydro-chemical environment, localized salinization, and a strong decline of the base flow to the river. It is expected that the results will contribute to a more comprehensive management plan for groundwater and the related eco-environment in the face of growing pressures from intensive human activities superimposed on climate change in this region.

Identifying the hydrochemical characteristics of rivers and groundwater by multivariate statistical analysis in the Sanjiang Plain, China

NASA Astrophysics Data System (ADS)

Cao, Yingjie; Tang, Changyuan; Song, Xianfang; Liu, Changming; Zhang, Yinghua

2016-06-01

Two multivariate statistical technologies, factor analysis (FA) and discriminant analysis (DA), are applied to study the river and groundwater hydrochemistry and its controlling processes in the Sanjiang Plain of the northeast China. Factor analysis identifies five factors which account for 79.65 % of the total variance in the dataset. Four factors bearing specific meanings as the river and groundwater hydrochemistry controlling processes are divided into two groups, the "natural hydrochemistry evolution" group and the "pollution" group. The "natural hydrochemistry evolution" group includes the salinity factor (factor 1) caused by rock weathering and the residence time factor (factor 2) reflecting the groundwater traveling time. The "pollution" group represents the groundwater quality deterioration due to geogenic pollution caused by elevated Fe and Mn (factor 3) and elevated nitrate (NO3 -) introduced by human activities such as agriculture exploitations (factor 5). The hydrochemical difference and hydraulic connection among rivers (surface water, SW), shallow groundwater (SG) and deep groundwater (DG) group are evaluated by the factor scores obtained from FA and DA (Fisher's method). It is showed that the river water is characterized as low salinity and slight pollution, and the shallow groundwater has the highest salinity and severe pollution. The SW is well separated from SG and DG by Fisher's discriminant function, but the SG and DG can not be well separated showing their hydrochemical similarities, and emphasize hydraulic connections between SG and DG.

Groundwater impacts on surface water quality and nutrient loads in lowland polder catchments: monitoring the greater Amsterdam area

NASA Astrophysics Data System (ADS)

Yu, Liang; Rozemeijer, Joachim; van Breukelen, Boris M.; Ouboter, Maarten; van der Vlugt, Corné; Broers, Hans Peter

2018-01-01

The Amsterdam area, a highly manipulated delta area formed by polders and reclaimed lakes, struggles with high nutrient levels in its surface water system. The polders receive spatially and temporally variable amounts of water and nutrients via surface runoff, groundwater seepage, sewer leakage, and via water inlets from upstream polders. Diffuse anthropogenic sources, such as manure and fertiliser use and atmospheric deposition, add to the water quality problems in the polders. The major nutrient sources and pathways have not yet been clarified due to the complex hydrological system in lowland catchments with both urban and agricultural areas. In this study, the spatial variability of the groundwater seepage impact was identified by exploiting the dense groundwater and surface water monitoring networks in Amsterdam and its surrounding polders. A total of 25 variables (concentrations of total nitrogen (TN), total phosphorus (TP), NH4, NO3, HCO3, SO4, Ca, and Cl in surface water and groundwater, N and P agricultural inputs, seepage rate, elevation, land-use, and soil type) for 144 polders were analysed statistically and interpreted in relation to sources, transport mechanisms, and pathways. The results imply that groundwater is a large source of nutrients in the greater Amsterdam mixed urban-agricultural catchments. The groundwater nutrient concentrations exceeded the surface water environmental quality standards (EQSs) in 93 % of the polders for TP and in 91 % for TN. Groundwater outflow into the polders thus adds to nutrient levels in the surface water. High correlations (R2 up to 0.88) between solutes in groundwater and surface water, together with the close similarities in their spatial patterns, confirmed the large impact of groundwater on surface water chemistry, especially in the polders that have high seepage rates. Our analysis indicates that the elevated nutrient and bicarbonate concentrations in the groundwater seepage originate from the decomposition of organic matter in subsurface sediments coupled to sulfate reduction and possibly methanogenesis. The large loads of nutrient-rich groundwater seepage into the deepest polders indirectly affect surface water quality in the surrounding area, because excess water from the deep polders is pumped out and used to supply water to the surrounding infiltrating polders in dry periods. The study shows the importance of the connection between groundwater and surface water nutrient chemistry in the greater Amsterdam area. We expect that taking account of groundwater-surface water interaction is also important in other subsiding and urbanising deltas around the world, where water is managed intensively in order to enable agricultural productivity and achieve water-sustainable cities.

Identifying and assessing human activity impacts on groundwater quality through hydrogeochemical anomalies and NO3-, NH4+, and COD contamination: a case study of the Liujiang River Basin, Hebei Province, P.R. China.

PubMed

Peng, Cong; He, Jiang-Tao; Wang, Man-Li; Zhang, Zhen-Guo; Wang, Lei

2018-02-01

In the face of rapid economic development and increasing human activity, the deterioration of groundwater quality has seriously affected the safety of the groundwater supply in eastern China. Identifying and assessing the impact of human activities is key to finding solutions to this problem. This study is an effort to scientifically and systematically identify and assess the influence of human activities on groundwater based on irregularities in hydrochemical properties and water contamination, which are considered to directly result from anthropogenic activity. The combination of the hydrochemical anomaly identification (HAI) and the contaminant identification (CI) was proposed to identify the influence of human activities on groundwater quality. And the degree of abnormality was quantified by the background threshold value. The principal component analysis (PCA) and land use map were used to verify the reliability of the identification result. The final result show that the strong influence areas mainly distributed in the south of the basin and the affected indicators contained the major elements and NO 3 - , NH 4 + , COD. Impacts from anthropogenic activities can be divided into two types: mine drainage that disrupts natural water-rock interaction processes, agricultural cultivation, and sewage emissions that contribute to nitrate pollution.

Hydro-environmental management of groundwater resources: A fuzzy-based multi-objective compromise approach

NASA Astrophysics Data System (ADS)

Alizadeh, Mohammad Reza; Nikoo, Mohammad Reza; Rakhshandehroo, Gholam Reza

2017-08-01

Sustainable management of water resources necessitates close attention to social, economic and environmental aspects such as water quality and quantity concerns and potential conflicts. This study presents a new fuzzy-based multi-objective compromise methodology to determine the socio-optimal and sustainable policies for hydro-environmental management of groundwater resources, which simultaneously considers the conflicts and negotiation of involved stakeholders, uncertainties in decision makers' preferences, existing uncertainties in the groundwater parameters and groundwater quality and quantity issues. The fuzzy multi-objective simulation-optimization model is developed based on qualitative and quantitative groundwater simulation model (MODFLOW and MT3D), multi-objective optimization model (NSGA-II), Monte Carlo analysis and Fuzzy Transformation Method (FTM). Best compromise solutions (best management policies) on trade-off curves are determined using four different Fuzzy Social Choice (FSC) methods. Finally, a unanimity fallback bargaining method is utilized to suggest the most preferred FSC method. Kavar-Maharloo aquifer system in Fars, Iran, as a typical multi-stakeholder multi-objective real-world problem is considered to verify the proposed methodology. Results showed an effective performance of the framework for determining the most sustainable allocation policy in groundwater resource management.

Technology Transfer Opportunities: Automated Ground-Water Monitoring

USGS Publications Warehouse

Smith, Kirk P.; Granato, Gregory E.

1997-01-01

Introduction A new automated ground-water monitoring system developed by the U.S. Geological Survey (USGS) measures and records values of selected water-quality properties and constituents using protocols approved for manual sampling. Prototypes using the automated process have demonstrated the ability to increase the quantity and quality of data collected and have shown the potential for reducing labor and material costs for ground-water quality data collection. Automation of water-quality monitoring systems in the field, in laboratories, and in industry have increased data density and utility while reducing operating costs. Uses for an automated ground-water monitoring system include, (but are not limited to) monitoring ground-water quality for research, monitoring known or potential contaminant sites, such as near landfills, underground storage tanks, or other facilities where potential contaminants are stored, and as an early warning system monitoring groundwater quality near public water-supply wells.

Quality assessment of groundwater from the south-eastern Arabian Peninsula.

PubMed

Zhang, H W; Sun, Y Q; Li, Y; Zhou, X D; Tang, X Z; Yi, P; Murad, A; Hussein, S; Alshamsi, D; Aldahan, A; Yu, Z B; Chen, X G; Mugwaneza, V D P

2017-08-01

Assessment of groundwater quality plays a significant role in the utilization of the scarce water resources globally and especially in arid regions. The increasing abstraction together with man-made contamination and seawater intrusion have strongly affected groundwater quality in the Arabia Peninsula, exemplified by the investigation given here from the United Arab Emirates, where the groundwater is seldom reviewed and assessed. In the aim of assessing current groundwater quality, we here present a comparison of chemical data linked to aquifers types. The results reveal that most of the investigated groundwater is not suitable for drinking, household, and agricultural purposes following the WHO permissible limits. Aquifer composition and climate have vital control on the water quality, with the carbonate aquifers contain the least potable water compared to the ophiolites and Quaternary clastics. Seawater intrusion along coastal regions has deteriorated the water quality and the phenomenon may become more intensive with future warming climate and rising sea level.

Ratio of Major Ions in Groundwater to Determine Saltwater Intrusion in Coastal Areas

NASA Astrophysics Data System (ADS)

Sudaryanto; Naily, Wilda

2018-02-01

Saltwater or seawater intrusion into groundwater aquifers occurs mostly in big cities and developing coastal cities. Coastal hydrology is associated with complex and highly dynamic environmental characteristics of interactions between groundwater, surface water, and water from the estuary. The rise of sea levels and excessive use of groundwater for clean water source trigger saltwater intrusion. Identification of saltwater intrusion into groundwater can be done by groundwater sampling and major ion analysis. The major ions dissolved in water are Ca, Mg, Na, K, Cl, HCO3, and SO4; the major ion ratios are Cl/Br, Ca/Mg, Ca/ (HCO3 and SO4), and Na/Cl. By knowing whether groundwater quality has been or has not been influenced by saltwater, groundwater zones can be determined in every coastal area. In addition, by analyzing and reviewing some concepts about the intrusion or contamination of saltwater into groundwater, there will be sufficient results for the identification of saltwater intrusion.

Groundwater quality in the Central Sierra Nevada, California

USGS Publications Warehouse

Fram, Miranda S.; Belitz, Kenneth

2012-01-01

Groundwater provides more than 40 percent of California's drinking water. To protect this vital resource, the State of California created the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The Priority Basin Project of the GAMA Program provides a comprehensive assessment of the State's groundwater quality and increases public access to groundwater-quality information. Two small watersheds of the Fresno and San Joaquin Rivers in the Central Sierra Nevada constitute one of the study units being evaluated.

Groundwater quality in the Southern Sierra Nevada, California

USGS Publications Warehouse

Fram, Miranda S.; Belitz, Kenneth

2012-01-01

Groundwater provides more than 40 percent of California's drinking water. To protect this vital resource, the State of California created the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The Priority Basin Project of the GAMA Program provides a comprehensive assessment of the State's groundwater quality and increases public access to groundwater-quality information. The Tehachapi-Cummings Valley and Kern River Valley basins and surrounding watersheds in the Southern Sierra Nevada constitute one of the study units being evaluated.

Groundwater quality in the Bear Valley and Lake Arrowhead Watershed, California

USGS Publications Warehouse

Mathany, Timothy; Burton, Carmen; Fram, Miranda S.

2017-06-20

Groundwater provides more than 40 percent of California’s drinking water. To protect this vital resource, the State of California created the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The Priority Basin Project of the GAMA Program provides a comprehensive assessment of the State’s groundwater quality and increases public access to groundwater-quality information. The Bear Valley and Lake Arrowhead Watershed study areas in southern California compose one of the study units being evaluated.

Assessment of groundwater quality of Ballia district, Uttar Pradesh, India, with reference to arsenic contamination using multivariate statistical analysis

NASA Astrophysics Data System (ADS)

Singh, Asha Lata; Singh, Vipin Kumar

2018-06-01

A total of 22 water quality parameters were selected for the analysis of groundwater samples with reference to arsenic contamination. Samples were collected in the pre-monsoon and monsoon seasons of the year 2013. The maximum arsenic concentration in both the pre-monsoon and monsoon seasons was approximately the same, i.e., the maximum arsenic concentration being 75.60 and 74.46 µg/L in pre-monsoon and monsoon, respectively. Out of 72 collected samples, three were below the WHO guideline value of 10 µg/L for arsenic concentration. In 95.83% of the groundwater samples, the arsenic concentration was above the permissible limit. Nickel, manganese, and chromium concentrations were above the permissible limits in nearly all samples except for chromium concentration in a few pre-monsoon samples. However, the total iron concentrations in 23 samples (31.94%) were above the permissible limit. A total of six and seven principal components (PCs) were extracted using principal component analysis during the pre-monsoon and monsoon seasons, respectively, accounting for 76.25 and 78.52% of the total variation during two consecutive seasons. Correlation statistics revealed that the arsenic concentration was positively correlated with phosphate, iron, ammonium, bicarbonate, and manganese concentrations but negatively correlated with oxidation reduction potential (ORP), sulfate concentration, electrical conductivity, and total dissolved solids concentration. The negative correlation of arsenic with ORP suggested reducing conditions prevailing in the groundwater. The trilinear Piper diagram revealed calcium and magnesium enrichment of groundwater with an abundance of chloride ions but no predominance of bicarbonate ions. Thus, the groundwater fell into Ca2+ - Mg2+ - Cl- - SO4 2- category.

A combined geostatistical-optimization model for the optimal design of a groundwater quality monitoring network

NASA Astrophysics Data System (ADS)

Kolosionis, Konstantinos; Papadopoulou, Maria P.

2017-04-01

Monitoring networks provide essential information for water resources management especially in areas with significant groundwater exploitation due to extensive agricultural activities. In this work, a simulation-optimization framework is developed based on heuristic optimization methodologies and geostatistical modeling approaches to obtain an optimal design for a groundwater quality monitoring network. Groundwater quantity and quality data obtained from 43 existing observation locations at 3 different hydrological periods in Mires basin in Crete, Greece will be used in the proposed framework in terms of Regression Kriging to develop the spatial distribution of nitrates concentration in the aquifer of interest. Based on the existing groundwater quality mapping, the proposed optimization tool will determine a cost-effective observation wells network that contributes significant information to water managers and authorities. The elimination of observation wells that add little or no beneficial information to groundwater level and quality mapping of the area can be obtain using estimations uncertainty and statistical error metrics without effecting the assessment of the groundwater quality. Given the high maintenance cost of groundwater monitoring networks, the proposed tool could used by water regulators in the decision-making process to obtain a efficient network design that is essential.

Model-based evaluation of subsurface monitoring networks for improved efficiency and predictive certainty of regional groundwater models

NASA Astrophysics Data System (ADS)

Gosses, M. J.; Wöhling, Th.; Moore, C. R.; Dann, R.; Scott, D. M.; Close, M.

2012-04-01

Groundwater resources worldwide are increasingly under pressure. Demands from different local stakeholders add to the challenge of managing this resource. In response, groundwater models have become popular to make predictions about the impact of different management strategies and to estimate possible impacts of changes in climatic conditions. These models can assist to find optimal management strategies that comply with the various stakeholder needs. Observations of the states of the groundwater system are essential for the calibration and evaluation of groundwater flow models, particularly when they are used to guide the decision making process. On the other hand, installation and maintenance of observation networks are costly. Therefore it is important to design monitoring networks carefully and cost-efficiently. In this study, we analyse the Central Plains groundwater aquifer (~ 4000 km2) between the Rakaia and Waimakariri rivers on the Eastern side of the Southern Alps in New Zealand. The large sedimentary groundwater aquifer is fed by the two alpine rivers and by recharge from the land surface. The area is mainly under agricultural land use and large areas of the land are irrigated. The other major water use is the drinking water supply for the city of Christchurch. The local authority in the region, Environment Canterbury, maintains an extensive groundwater quantity and quality monitoring programme to monitor the effects of land use and discharges on groundwater quality, and the suitability of the groundwater for various uses, especially drinking-water supply. Current and projected irrigation water demand has raised concerns about possible impacts on groundwater-dependent lowland streams. We use predictive uncertainty analysis and the Central Plains steady-state groundwater flow model to evaluate the worth of pressure head observations in the existing groundwater well monitoring network. The data worth of particular observations is dependent on the problem-specific prediction target under consideration. Therefore, the worth of individual observation locations may differ for different prediction targets. Our evaluation is based on predictions of lowland stream discharge resulting from changes in land use and irrigation in the upper Central Plains catchment. In our analysis, we adopt the model predictive uncertainty analysis method by Moore and Doherty (2005) which accounts for contributions from both measurement errors and uncertain structural heterogeneity. The method is robust and efficient due to a linearity assumption in the governing equations and readily implemented for application in the model-independent parameter estimation and uncertainty analysis toolkit PEST (Doherty, 2010). The proposed methods can be applied not only for the evaluation of monitoring networks, but also for the optimization of networks, to compare alternative monitoring strategies, as well as to identify best cost-benefit monitoring design even prior to any data acquisition.

Data on assessment of groundwater quality for drinking and irrigation in rural area Sarpol-e Zahab city, Kermanshah province, Iran.

PubMed

Soleimani, Hamed; Abbasnia, Abbas; Yousefi, Mahmood; Mohammadi, Ali Akbar; Khorasgani, Fazlollah Changani

2018-04-01

In present study 30 groundwater samples were collected from Sarpol-e Zahab area, Kermanshah province of Iran in order to assess the quality of groundwater in subjected area and determining its suitability for drinking and agricultural purposes. Also the variations in the quality levels of groundwater were compared over the years of 2015 and 2016. Statistical analyses including Spearman correlation coefficients and factor analysis display good correlation between physicochemical parameters (EC, TDS and TH) and Na + , Mg 2+ , Ca 2+ , Cl - and [Formula: see text] ionic constituents. Also in order to assess water quality for irrigation we used the United States Department of Agriculture (USDA) classification which is based on SAR for irrigation suitability assessment. In addition, the residual sodium carbonate (RSC), %Na, PI, KR, SSP, MH, EC characteristics were calculated for all samples and used for assessment of irrigation suitability. Based on these indicators, for every two years, the quality of water for agriculture is in good and excellent category. The Piper classification for hydro geochemical facies indicates that the water in the study area is of Ca-HCO 3 - type. However, the study of water hardness shows that more than 80% of samples are in hard and very hard water class. Therefore, there is a need for decisions to refine and soften the water.

Groundwater quality in the Yuba River and Bear River Watersheds, Sierra Nevada, California

USGS Publications Warehouse

Fram, Miranda S.; Jasper, Monica; Taylor, Kimberly A.

2017-09-27

Groundwater provides more than 40 percent of California’s drinking water. To protect this vital resource, the State of California created the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The GAMA Program’s Priority Basin Project assesses the quality of groundwater resources used for drinking water supply and increases public access to groundwater-quality information. In the Yuba River and Bear River Watersheds of the Sierra Nevada, many rural households rely on private wells for their drinking water supplies. 

Groundwater quality in the Mokelumne, Cosumnes, and American River Watersheds, Sierra Nevada, California

USGS Publications Warehouse

Fram, Miranda S.; Shelton, Jennifer L.

2018-03-23

Groundwater provides more than 40 percent of California’s drinking water. To protect this vital resource, the State of California created the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The GAMA Program’s Priority Basin Project assesses the quality of groundwater resources used for drinking water supply and increases public access to groundwater-quality information. In the Mokelumne, Cosumnes, and American River Watersheds of the Sierra Nevada, many rural households rely on private wells for their drinking-water supplies.

Ground-water geochemistry of the Albuquerque-Belen Basin, central New Mexico

USGS Publications Warehouse

Anderholm, S.K.

1988-01-01

The purpose of this study was to define the areal distribution of different water types, use the distribution to help define the groundwater flow system, and identify processes resulting in differences in groundwater quality in the Albuquerque-Belen Basin in central New Mexico. The chemistry of surface water inflow from adjacent areas, which infiltrates and recharges the aquifer along the basin margin, affects the groundwater quality in the eastern and southeastern areas of the basin. Groundwater in the eastern area generally has a specific conductance less than 400 microsiemens, and calcium and bicarbonate are the dominant ions. Mixing of recharge, groundwater inflow, and surface inflow from adjacent areas, which have different chemical compositions, is the major process affecting groundwater quality in the southwestern, western, and northern areas of the basin. In these areas, there is a large range in specific conductance and distribution of dissolved ions. Groundwater quality in the Rio Grande valley is affected by the infiltration of excess irrigation water. The excess irrigation water generally has a larger specific conductance than other groundwater in the valley, so mixing of these waters results in shallow groundwater generally having larger specific conductance than the deeper groundwater. (USGS)

Groundwater quality assessment of the quaternary unconsolidated sedimentary basin near the Pi river using fuzzy evaluation technique

NASA Astrophysics Data System (ADS)

Mohamed, Adam Khalifa; Liu, Dan; Mohamed, Mohamed A. A.; Song, Kai

2018-05-01

The present study was carried out to assess the groundwater quality for drinking purposes in the Quaternary Unconsolidated Sedimentary Basin of the North Chengdu Plain, China. Six groups of water samples (S1, S2, S3, S4, S5, and S6) are selected in the study area. These samples were analyzed for 19 different physicochemical water quality parameters to assess groundwater quality. The physicochemical parameters of groundwater were compared with China's Quality Standards for Groundwater (GB/T14848-93). Interpretation of physicochemical data revealed that groundwater in the basin was slightly alkaline. Total hardness and total dissolved solid values show that the investigated water is classified as very hard and fresh water, respectively. The sustainability of groundwater for drinking purposes was assessed based on the fuzzy mathematics evaluation (FME) method. The results of the assessment were classified into five groups based on their relative suitability for portable use (grade I = most suitable to grade V = least suitable), according to (GB/T 14848-93). The assessment results reveal that the quality of groundwater in most of the wells was class I, II and III and suitable for drinking purposes, but well (S2) has been found to be in class V, which is classified as very poor and cannot be used for drinking. Also, the FME method was compared with the comprehensive evaluation method. The FME method was found to be more comprehensive and reasonable to assess groundwater quality. This study can provide an important frame of reference for decision making on improving groundwater quality in the study area and nearby surrounding.

Surface-water, water-quality, and ground-water assessment of the Municipio of Carolina, Puerto Rico, 1997-99

USGS Publications Warehouse

Rodríguez-Martínez, Jesús; Gómez-Gómez, Fernando; Santiago-Rivera, Luis; Oliveras-Feliciano, M. L.

2001-01-01

To meet the increasing need for a safe and adequate supply of water in the municipio of Carolina, an integrated surface-water, water-quality, and ground-water assessment of the area was conducted. The major results of this study and other important hydrologic and water-quality features were compiled in a Geographic Information System and are presented in two 1:30,000-scale map plates to facilitate interpretation and use of the diverse water-resources data. Because the supply of safe drinking water was a critical issue during recent dry periods, the surface-water assessment portion of this study focused on analysis of low-flow characteristics in local streams and rivers. Low-flow characteristics were evaluated for one continuous-record gaging station, based on graphical curve-fitting techniques and log-Pearson Type III frequency analysis. Estimates of low-flow characteristics for seven partial-record stations were generated using graphical-correlation techniques. Flow-duration characteristics were computed for the one continuous-record gaging station and were estimated for the partial-record stations using the relation curves developed from the low-flow study. Stream low-flow statistics document the general hydrology under current land and water use. Low-flow statistics may substantially change as a result of streamflow diversions for public supply, and an increase in ground-water development, waste-water discharges, and flood-control measures; the current analysis provides baseline information to evaluate these impacts and develop water budgets. A sanitary quality survey of streams utilized 29 sampling stations to evaluate the sanitary quality of about 87 miles of stream channels. River and stream samples were collected on two occasions during base-flow conditions and were analyzed for fecal coliform and fecal streptococcus. Bacteriological analyses indicate that a significant portion of the stream reaches within the municipio of Carolina may have fecal coliform concentrations above the water-quality goal established by the Puerto Rico Environmental Quality Board (Junta de Calidad Ambiental de Puerto Rico) for inland surface waters. Sources of fecal contamination may include: illegal discharge of sewage to storm-water drains, malfunctioning sanitary sewer ejectors, clogged and leaking sewage pipes, septic tank leakage, unfenced livestock, and runoff from livestock pens. Long-term fecal coliform data at two sampling stations, Quebrada Blasina in Carolina and the Rio Grande de Loiza, downstream from the town of Trujillo Alto, indicate that the sanitary quality of Quebrada Blasina is and has generally been poor for more than a decade. The sanitary quality of the Rio Grande de Loiza has generally been in compliance with the water-quality goal standard fecal coliform concentrations established in July 1990 by the Puerto Rico Environmental Quality Board. Geologic, topographic, soil, hydrogeologic, and streamflow data were used to divide the municipio of Carolina into five hydrogeologic terranes. This integrated database was then used to evaluate the ground-water potential of each hydrogeologic terrane. Analysis suggests that areas with slopes greater than 15 degrees have relatively low ground-water development potential. Fractures may be locally important in enhancing the water-bearing properties in the hydrogeologic terranes containing igneous rocks. Potentiometric-surface elevations recorded in piezometers installed in the coastal area during this study were used to define ground-water flow directions in the hydrogeologic terranes composed of coastal plain clastic and limestone units. The resultant potentiometric map indicates that the coastal plain aquifer and streams in the lowland parts of the municipio of Carolina are hydraulically connected. The potentiometric map also indicates that ground-water discharge to the Rio Grande de Loiza, downstream from highway PR-3, has been enhanced by dredging of the streambed for

Groundwater flow system under a rapidly urbanizing coastal city as determined by hydrogeochemistry

NASA Astrophysics Data System (ADS)

Kagabu, Makoto; Shimada, Jun; Delinom, Robert; Tsujimura, Maki; Taniguchi, Makoto

2011-01-01

In the Jakarta area (Indonesia), excessive groundwater pumping due to the rapidly increasing population has caused groundwater-related problems such as brackish water contamination in coastal areas and land subsidence. In this study, we adopted multiple hydrogeochemical techniques to demonstrate the groundwater flow system in the Jakarta area. Although almost all groundwater existing in the Jakarta basin is recharged at similar elevations, the water quality and residence time demonstrates a clear difference between the shallow and deep aquifers. Due to the rapid decrease in the groundwater potential in urban areas, we found that the seawater intrusion and the shallow and deep groundwaters are mixing, a conclusion confirmed by major ions, Br -:Cl - ratios, and chlorofluorocarbon (CFC)-12 analysis. Spring water and groundwater samples collected from the southern mountainside area show younger age characteristics with high concentrations of 14C and Ca-HCO 3 type water chemistry. We estimated the residence times of these groundwaters within 45 years under piston flow conditions by tritium analysis. Also, these groundwater ages can be limited to 20-30 years with piston flow evaluated by CFCs. Moreover, due to the magnitude of the CFC-12 concentration, we can use a pseudo age indicator in this field study, because we found a positive correlation between the major type of water chemistry and the CFC-12 concentration.

A nested observation and model approach to non linear groundwater surface water interactions.

NASA Astrophysics Data System (ADS)

van der Velde, Y.; Rozemeijer, J. C.; de Rooij, G. H.

2009-04-01

Surface water quality measurements in The Netherlands are scattered in time and space. Therefore, water quality status and its variations and trends are difficult to determine. In order to reach the water quality goals according to the European Water Framework Directive, we need to improve our understanding of the dynamics of surface water quality and the processes that affect it. In heavily drained lowland catchment groundwater influences the discharge towards the surface water network in many complex ways. Especially a strong seasonal contracting and expanding system of discharging ditches and streams affects discharge and solute transport. At a tube drained field site the tube drain flux and the combined flux of all other flow routes toward a stretch of 45 m of surface water have been measured for a year. Also the groundwater levels at various locations in the field and the discharge at two nested catchment scales have been monitored. The unique reaction of individual flow routes on rainfall events at the field site allowed us to separate the discharge at a 4 ha catchment and at a 6 km2 into flow route contributions. The results of this nested experimental setup combined with the results of a distributed hydrological model has lead to the formulation of a process model approach that focuses on the spatial variability of discharge generation driven by temporal and spatial variations in groundwater levels. The main idea of this approach is that discharge is not generated by catchment average storages or groundwater heads, but is mainly generated by points scale extremes i.e. extreme low permeability, extreme high groundwater heads or extreme low surface elevations, all leading to catchment discharge. We focused on describing the spatial extremes in point scale storages and this led to a simple and measurable expression that governs the non-linear groundwater surface water interaction. We will present the analysis of the field site data to demonstrate the potential of nested-scale, high frequency observations. The distributed hydrological model results will be used to show transient catchment scale relations between groundwater levels and discharges. These analyses lead to a simple expression that can describe catchment scale groundwater surface water interactions.

A conceptual ground-water-quality monitoring network for San Fernando Valley, California

USGS Publications Warehouse

Setmire, J.G.

1985-01-01

A conceptual groundwater-quality monitoring network was developed for San Fernando Valley to provide the California State Water Resources Control Board with an integrated, basinwide control system to monitor the quality of groundwater. The geology, occurrence and movement of groundwater, land use, background water quality, and potential sources of pollution were described and then considered in designing the conceptual monitoring network. The network was designed to monitor major known and potential point and nonpoint sources of groundwater contamination over time. The network is composed of 291 sites where wells are needed to define the groundwater quality. The ideal network includes four specific-purpose networks to monitor (1) ambient water quality, (2) nonpoint sources of pollution, (3) point sources of pollution, and (4) line sources of pollution. (USGS)

Interactions of water quality and integrated groundwater management: Examples from the United States and Europe: Chapter 14

USGS Publications Warehouse

Warner, Kelly L.; Barataud, Fabienne; Hunt, Randall J.; Benoit, Marc; Anglade, Juliette; Borchardt, Mark A.

2015-01-01

Groundwater is available in many parts of the world, but the quality of the water may limit its use. Contaminants can limit the use of groundwater through concerns associated with human health, aquatic health, economic costs, or even societal perception. Given this broad range of concerns, this chapter focuses on examples of how water quality issues influence integrated groundwater management. One example evaluates the importance of a naturally occurring contaminant Arsenic (As) for drinking water supply, one explores issues resulting from agricultural activities on the land surface and factors that influence related groundwater management, and the last examines unique issues that result from human-introduced viral pathogens for groundwater-derived drinking water vulnerability. The examples underscore how integrated groundwater management lies at the intersections of environmental characterization, engineering constraints, societal needs, and human perception of acceptable water quality. As such, water quality factors can be a key driver for societal decision making.

Ground-water-quality assessment of the Carson River basin, Nevada and California; analysis of available water-quality data through 1987

USGS Publications Warehouse

Welch, A.H.; Plume, R.W.; Frick, E.A.; Hughes, J.L.

1989-01-01

Data on groundwater quality, hydrogeology, and land and water use for the Carson River basin, Nevada and California were analyzed as part of the U. S. Geological Survey National Water-Quality Assessment program. The basin consists of six hydrographic areas--a mountainous headwaters area and five downstream areas interconnected by the Carson River. Each valley contains one or more basin-fill aquifers. The data on groundwater quality came from several agencies and were screened to verify site location and to avoid analyses of treated water. The screened data are stored in the U. S. Geological Survey National Water Information System data base. Differences in sample-collection and preservation procedures among some of the data-collection agencies restrict use of the data to a descriptive analysis. Drinking water standards were employed as the basis for evaluating reported concentrations. Frequencies with which primary or secondary standards are exceeded increase from upstream parts of the basin to downstream parts. Primary standards commonly exceeded are fluoride in upstream areas and arsenic and fluoride in downstream areas. Secondary standards commonly exceeded are iron and manganese in upstream areas and chloride, dissolved solids, iron, manganese, and sulfate in downstream areas. The poorer-quality groundwater generally is a result of natural geochemical reactions, rather than the introduction of chemicals by man. Limited data indicate, however , that manmade organic compounds are present, mostly at or near urban land. (USGS)

Ground-water quality in the Santa Rita, Buellton, and Los Olivos hydrologic subareas of the Santa Ynez River basin, Santa Barbara County, California

USGS Publications Warehouse

Hamlin, S.N.

1985-01-01

Groundwater quality in the upper Santa Ynez River Valley in Santa Barbara County has degraded due to both natural and anthropogenic causes. The semiarid climate and uneven distribution of rainfall has limited freshwater recharge and caused salt buildup in water supplies. Tertiary rocks supply mineralized water. Agricultural activities (irrigation return flow containing fertilizers and pesticides, cultivation, feedlot waste disposal) are a primary cause of water quality degradation. Urban development, which also causes water quality degradation (introduced contaminants, wastewater disposal, septic system discharge, and land fill disposal of waste), has imposed stricter requirements on water supply quality. A well network was designed to monitor changes in groundwater quality related to anthropogenic activities. Information from this network may aid in efficient management of the groundwater basins as public water supplies, centered around three basic goals. First is to increase freshwater recharge to the basins by conjunctive surface/groundwater use and surface-spreading techniques. Second is to optimize groundwater discharge by efficient timing and spacing of pumping. Third is to control and reduce sources of groundwater contamination by regulating wastewater quality and distribution and, preferably, by exporting wastewaters from the basin. (USGS)

Plan of study for the regional aquifer-system analysis of the Snake River plain, Idaho and eastern Oregon

USGS Publications Warehouse

Lindholm, Gerald F.

1981-01-01

The 15,600-square-mile Snake River Plain is largely in southern Idaho and includes one of the Nation 's major regional aquifers. A comprehensive investigation of the area 's ground-water resources will be made as part of the U.S. Geological Survey 's Regional Aquifer-System Analysis (RASA) program. Basaltic and sedimentary rocks in the Snake River Plain yield large quantities of water that are vital to the area 's agricultural economy. Basaltic rocks predominate in the eastern Snake River Plain and have especially high water-yielding capabilities. Surface water, largely from the Snake River, is extensively used for irrigation and is a major source of recharge to the ground-water system. Springs issuing from basaltic rocks that form the Snake River Canyon wall near Twin Falls are the major points of ground-water discharge. Increased use of ground water for irrigation is causing concern as to the effect of large-scale withdrawals on spring flow. Ground-water flow models will be used to improve understanding of the hydrologic system, and, if feasible, to aid in evaluating management alternatives. Ground-water quality will be defined and geochemical techniques used to determine the effects of water-rock reactions on water quality. Several reports are planned on different phases of the project, concluding with a summary report. (USGS)

The Grand Challenge of Basin-Scale Groundwater Quality Management Modelling

NASA Astrophysics Data System (ADS)

Fogg, G. E.

2017-12-01

The last 50+ years of agricultural, urban and industrial land and water use practices have accelerated the degradation of groundwater quality in the upper portions of many major aquifer systems upon which much of the world relies for water supply. In the deepest and most extensive systems (e.g., sedimentary basins) that typically have the largest groundwater production rates and hold fresh groundwaters on decadal to millennial time scales, most of the groundwater is not yet contaminated. Predicting the long-term future groundwater quality in such basins is a grand scientific challenge. Moreover, determining what changes in land and water use practices would avert future, irreversible degradation of these massive freshwater stores is a grand challenge both scientifically and societally. It is naïve to think that the problem can be solved by eliminating or reducing enough of the contaminant sources, for human exploitation of land and water resources will likely always result in some contamination. The key lies in both reducing the contaminant sources and more proactively managing recharge in terms of both quantity and quality, such that the net influx of contaminants is sufficiently moderate and appropriately distributed in space and time to reverse ongoing groundwater quality degradation. Just as sustainable groundwater quantity management is greatly facilitated with groundwater flow management models, sustainable groundwater quality management will require the use of groundwater quality management models. This is a new genre of hydrologic models do not yet exist, partly because of the lack of modeling tools and the supporting research to model non-reactive as well as reactive transport on large space and time scales. It is essential that the contaminant hydrogeology community, which has heretofore focused almost entirely on point-source plume-scale problems, direct it's efforts toward the development of process-based transport modeling tools and analyses capable of appropriately upscaling advection-dispersion and reactions at the basin scale (10^2 km). A road map for research and development in groundwater quality management modeling and its application toward securing future groundwater resources will be discussed.

Water quality studied in areas of unconventional oil and gas development, including areas where hydraulic fracturing techniques are used, in the United States

USGS Publications Warehouse

Susong, David D.; Gallegos, Tanya J.; Oelsner, Gretchen P.

2012-01-01

The U.S. Geological Survey (USGS) John Wesley Powell Center for Analysis and Synthesis is hosting an interdisciplinary working group of USGS scientists to conduct a temporal and spatial analysis of surface-water and groundwater quality in areas of unconventional oil and gas development. The analysis uses existing national and regional datasets to describe water quality, evaluate water-quality changes over time where there are sufficient data, and evaluate spatial and temporal data gaps.

Hydrochemical Impacts of CO2 Leakage on Fresh Groundwater: a Field Scale Experiment

NASA Astrophysics Data System (ADS)

Lions, J.; Gal, F.; Gombert, P.; Lafortune, S.; Darmoul, Y.; Prevot, F.; Grellier, S.; Squarcioni, P.

2013-12-01

One of the questions related to the emerging technology for Carbon Geological Storage concerns the risk of CO2 migration beyond the geological storage formation. In the event of leakage toward the surface, the CO2 might affect resources in neighbouring formations (geothermal or mineral resources, groundwater) or even represent a hazard for human activities at the surface or in the subsurface. In view of the preservation of the groundwater resources mainly for human consumption, this project studies the potential hydrogeochemical impacts of CO2 leakage on fresh groundwater quality. One of the objectives is to characterize the bio-geochemical mechanisms that may impair the quality of fresh groundwater resources in case of CO2 leakage. To reach the above mentioned objectives, this project proposes a field experiment to characterize in situ the mechanisms that could impact the water quality, the CO2-water-rock interactions and also to improve the monitoring methodology by controlled CO2 leakage in shallow aquifer. The tests were carried out in an experimental site in the chalk formation of the Paris Basin. The site is equipped with an appropriate instrumentation and was previously characterized (8 piezometers, 25 m deep and 4 piezairs 11 m deep). The injection test was preceded by 6 months of monitoring in order to characterize hydrodynamics and geochemical baselines of the site (groundwater, vadose and soil). Leakage into groundwater is simulated via the injection of a small quantity of food-grade CO2 (~20 kg dissolved in 10 m3 of water) in the injection well at a depth of about 20 m. A plume of dissolved CO2 is formed and moves downward according to the direction of groundwater flow and probably by degassing in part to the surface. During the injection test, hydrochemical monitoring of the aquifer is done in situ and by sampling. The parameters monitored in the groundwater are the piezometric head, temperature, pH and electrical conductivity. Analysis on water samples provide chemical elements (major, minor and trace metals), dissolved gases, microbiological diversity and isotopes (13C). The evolution of the composition of the groundwater in terms of major elements, trace elements and isotope signatures is interpreted in terms of geochemical mechanisms, and the water-rock-CO2 interactions are characterized. Modification of the chemical composition of water in the aquifer due to CO2 injection is assessed in term of groundwater quality i.e. metal element release and the possibility of exceeding references and quality of water for human consumption. One outcome of the CIPRES project will be to highlight mechanisms that can impact groundwater quality when a CO2 leakage occurs and to propose recommendations to prevent or/and eliminate negative effects and any risks to the environment and human health. This project is partially funded by the French Research Agency (ANR).

Calendar year 1993 groundwater quality report for the Chestnut Ridge Hydrogeologic Regime, Y-12 Plant, Oak Ridge, Tennessee. 1993 groundwater quality data and calculated rate of contaminant migration, Part 1

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1994-02-01

This annual groundwater report contains groundwater quality data obtained during the 1993 calendar year (CY) at several hazardous and non-hazardous waste-management facilities associated with the US Department of Energy (DOE) Y-12 Plant located on the DOE Oak Ridge Reservation (ORR) southeast of Oak Ridge, Tennessee. These sites are located south of the Y-12 Plant in the Chestnut Ridge Hydrogeologic Regime (Chestnut Ridge Regime), which is one of three regimes defined for the purposes of groundwater quality monitoring at the Y-12 Plant. The Environmental Management Department of the Y-12 Plant Health, Safety, Environment, and Accountability Organization manages the groundwater monitoring activitiesmore » in each regime as part of the Y-12 Plant Groundwater Protection Program (GWPP). The annual groundwater report for the Chestnut Ridge Regime is completed in two-parts; Part 1 (this report) containing the groundwater quality data and Part 2 containing a detailed evaluation of the data. The primary purpose of this report is to serve as a reference for the groundwater quality data obtained each year under the lead of the Y-12 Plant GWPP. However, because it contains information needed to comply with Resource Conservation and Recovery Act (RCRA) interim status assessment monitoring and reporting requirements, this report is submitted to the Tennessee Department of Health and Environment (TDEC) by the RCRA reporting deadline.« less

Assessment of groundwater quality at a MSW landfill site using standard and AHP based water quality index: a case study from Ranchi, Jharkhand, India.

PubMed

Chakraborty, Shubhrasekhar; Kumar, R Naresh

2016-06-01

Landfill leachate generated from open MSW dumpsite can cause groundwater contamination. The impact of open dumping of MSW on the groundwater of adjacent area was studied. To assess the spatial and temporal variations in groundwater quality, samples were collected around an open MSW dumping site in Ranchi city, Jharkhand, India. Groundwater samples were analysed for various physicochemical and bacteriological parameters for 1 year. Results indicated that the groundwater is getting contaminated due to vertical and horizontal migration of landfill leachate. Extent of contamination was higher in areas closer to the landfill as indicated by high alkalinity, total dissolved solids and ammonia concentration. Metals such as lead, iron, and manganese were present at concentrations of 0.097, 0.97 and 0.36 mg/L, respectively exceeding the Bureau of Indian Standards (BIS) 10,500 for drinking water. Enterobacteriaceae were also detected in several groundwater samples and highest coliform count of 2.1×10(4) CFU/mL was recorded from a dug well. In order to determine the overall groundwater quality, water quality index (WQI) was calculated using weighted arithmetic index method and this index was further modified by coupling with the analytical hierarchy process (AHP) to get specific information. WQI values indicated that the overall groundwater quality of the region came under "poor" category while zone wise classification indicated the extent of impact of landfill leachate on groundwater.

Hydrochemical characteristics and quality assessment of deep groundwater from the coal-bearing aquifer of the Linhuan coal-mining district, Northern Anhui Province, China.

PubMed

Lin, Man-Li; Peng, Wei-Hua; Gui, He-Rong

2016-04-01

There is little information available about the hydrochemical characteristics of deep groundwater in the Linhuan coal-mining district, Northern Anhui Province, China. In this study, we report information about the physicochemical parameters, major ions, and heavy metals of 17 groundwater samples that were collected from the coal-bearing aquifer. The results show that the concentrations of total dissolved solids, electrical conductivity, and potassium and sodium (K(+) + Na(+)) in most of the groundwater samples exceeded the guidelines of the World Health Organization (WHO) and the Chinese National Standards for Drinking Water Quality (GB 5749-2006). The groundwater from the coal-bearing aquifer was dominated by the HCO3·Cl-K + Na and HCO3·SO4-K + Na types. Analysis with a Gibbs plot suggested that the major ion chemistry of the groundwater was primarily controlled by weathering of rocks and that the coal-bearing aquifer in the Linhuan coal-mining district was a relatively closed system. K(+) and Na(+) originated from halite and silicate weathering reactions, while Ca(2+) and Mg(2+) originated from the dissolution of calcite, dolomite, and gypsum or anhydrite. Ion exchange reactions also had an influence on the formation of major ions in groundwater. The concentrations of selected heavy metals decreased in the order Mn > Zn > Cr > Cu > Ni > Pb. In general, the heavy metal concentrations were low; however, the Cr, Mn, and Ni concentrations in some of the groundwater samples exceeded the standards outlined by the WHO, the GB 5749-2006, and the Chinese National Standards for Groundwater (GB/T 14848-93). Analysis by various indices (% Na, SAR, and EC), a USSL diagram, and a Wilcox diagram showed that both the salinity and alkalinity of the groundwater were high, such that the groundwater could not be used for irrigating agricultural land without treatment. These results will be significant for water resource exploiting and utilization in coal mine area.

Assessment of quality and geochemical processes occurring in groundwaters near central air conditioning plant site in Trombay, Maharashtra, India.

PubMed

Tirumalesh, K; Shivanna, K; Sriraman, A K; Tyagi, A K

2010-04-01

This paper summarizes the findings obtained in a monitoring study to understand the sources and processes affecting the quality of shallow and deep groundwater near central air conditioning plant site in Trombay region by making use of physicochemical and biological analyses. All the measured parameters of the groundwaters indicate that the groundwater quality is good and within permissible limits set by (Indian Bureau of Standards 1990). Shallow groundwater is dominantly of Na-HCO(3) type whereas deep groundwater is of Ca-Mg-HCO(3) type. The groundwater chemistry is mainly influenced by dissolution of minerals and base exchange processes. High total dissolved solids in shallow groundwater compared to deeper ones indicate faster circulation of groundwater in deep zone preferably through fissures and fractures whereas groundwater flow is sluggish in shallow zone. The characteristic ionic ratio values and absence of bromide point to the fact that seawater has no influence on groundwater system.

Hydrogeochemical Analysis of an Overexploited Aquifer In Bangladesh Toward Managed Aquifer Recharge Project Implementation

NASA Astrophysics Data System (ADS)

Rahman, M. A.; Wiegand, B. A.; Pervin, M.; Sauter, M.

2012-12-01

In most parts of the upper Dupitila aquifer (Dhaka City, Bangladesh) the average groundwater depletion reaches 2-3 m/year due to increasing water demands of the growing population. To counteract overexploitation of the aquifer, a more sustainable water management is required. The analysis of the local water resources system suggests that Managed Aquifer Recharge (MAR) would help to restore groundwater resources to strengthen water supply of Dhaka City, e.g., by using collected urban monsoon runoff and excess surface water from rivers. To assess possible effects of surface water or rainwater injection on groundwater quality, a comprehensive hydrogeochemical survey of the Dupitila aquifer is required. This paper presents hydrogeochemical data to document the current status of groundwater quality and to evaluate potential groundwater pollution by mobilization of hazardous chemicals as a result of changes in the hydrochemical equilibria. We performed a comprehensive review of available secondary data sources and will present new results from hydrochemical and Sr isotope investigations of water samples that were conducted within this study. Currently, groundwater quality in the upper Dupitila aquifer is characterized by variations in the electrical conductivity in the range of 200 to 1100 μS/cm, which may indicate some anthropogenic contamination by leakage from waste disposal including the sewage network and from surface water infiltration into the groundwater aquifer. Dissolved oxygen concentrations range from 1.0 to 4.9 mg/L (average 2.5 mg/L) in the upper Dupitila aquifer, while the lower Dupilita aquifer shows dissolved oxygen concentrations in the range 0 to 0.7 mg/L. Concentrations of major ions show some variation primarily due to a sedimentologically/mineralogically heterogeneous aquifer composition (sand, gravel, clay horizons), but may also be affected by anthropogenic processes. The groundwater composition is predominated by Ca-Mg-HCO3 and saturation values with respect to calcite are between -0.1 and -2.0. Trace elements are generally below WHO and Bangladesh standard values, except for higher iron and manganese concentrations in some wells. Groundwater from the Dupitila aquifer is not contaminated by arsenic, but mobilisation of arsenic from the aquifer sediments may occur when iron (III) oxides are dissolved in the storage zone. Based on the evaluation of hydrogeochemical data the major challenges and uncertainties of a MAR project implementation in Dhaka City will be discussed.

Identification of surface water-groundwater interaction by hydrogeochemical indicators and assessing its suitability for drinking and irrigational purposes in Chennai, Southern India

NASA Astrophysics Data System (ADS)

Brindha, K.; Neena Vaman, K. V.; Srinivasan, K.; Sathis Babu, M.; Elango, L.

2014-06-01

Large cities face water quality and quantity problems due to increasing population and improper disposal of solid and liquid wastes. It is essential to monitor the water quality to take corrective measures. This study was carried out in one of the densely populated metropolitan cities in India to ascertain the suitability of groundwater for drinking and irrigation activity, identify the processes controlling the geochemistry of groundwater and the impact of Adyar River on the groundwater quality. Magnesium and pH concentration in groundwater of this area were within the maximum permissible limits of WHO standards. Sodium and potassium concentration of groundwater were greater than the permissible limit in 30.8 % and in 50 % of the samples, respectively. About 35 % of the groundwater samples were not permissible for drinking based on the electrical conductivity (EC). The EC of groundwater was increasing towards the coast. In general, the quality of groundwater for irrigation purpose vary from moderate to good based on Na%, magnesium hazard, residual sodium carbonate, sodium absorption ratio, permeability index, and USDA classification. Na-Cl and Ca-Mg-Cl were the dominant groundwater and surface water type. Increased ionic concentration of groundwater towards the eastern part of the study area is due to the discharge of industrial effluents and domestic sewage into the Adyar River. Seawater intrusion is also one of the reasons for Na-Cl dominant groundwater near the coast. Evaporation and ion exchange were the major processes controlling groundwater chemistry in this area. The groundwater quality of this region is affected by the contaminated surface water.

Waste deposit influences on groundwater quality as a tool for waste type and site selection for final storage quality

NASA Astrophysics Data System (ADS)

Arneth, Jan-Dirk; Milde, Gerald; Kerndorff, Helmut; Schleyer, Ruprecht

Leachates from deposits of wastes may, in the long run, adversely influence groundwater quality. Since tipping still constitutes the most important form of waste disposal, strategies must be developed which are capable of protecting groundwater against contamination from leachates. In the first instance such protective measures must provide for a minimization of contamination by setting up optimal barriers. Since it would seem difficult to reach this goal in a forseeable future, the avoidance of substances with a high potential for groundwater hazards has to be attributed much importance. In former times, little attention was given to impermeability or avoidance of substances with a high potential for groundwater hazards contained in wastes. Therefore, results of the investigation of groundwater near abandoned sites can be used to optimize groundwater protection on future tipping sites. In the present study, the results of chemical investigation of groundwater from the vicinity of 92 waste disposal sites in the Federal Republic of Germany are presented and the changes in groundwater quality owing to the penetration of leachates are discussed separately for inorganic and organic contaminants.

Groundwater studies: principal aquifer surveys

USGS Publications Warehouse

Burow, Karen R.; Belitz, Kenneth

2014-01-01

In 1991, the U.S. Congress established the National Water-Quality Assessment (NAWQA) program within the U.S. Geological Survey (USGS) to develop nationally consistent long-term datasets and provide information about the quality of the Nation’s streams and groundwater. The USGS uses objective and reliable data, water-quality models, and systematic scientific studies to assess current water-quality conditions, to identify changes in water quality over time, and to determine how natural factors and human activities affect the quality of streams and groundwater. NAWQA is the only non-regulatory Federal program to perform these types of studies; participation is voluntary. In the third decade (Cycle 3) of the NAWQA program (2013–2023), the USGS will evaluate the quality and availability of groundwater for drinking supply, improve our understanding of where and why water quality is degraded, and assess how groundwater quality could respond to changes in climate and land use. These goals will be addressed through the implementation of a new monitoring component in Cycle 3: Principal Aquifer Surveys.

Framework for a ground-water quality monitoring and assessment program for California

USGS Publications Warehouse

Belitz, Kenneth; Dubrovsky, Neil M.; Burow, Karen; Jurgens, Bryant C.; John, Tyler

2003-01-01

The State of California uses more ground water than any other State in the Nation. With a population of over 30 million people, an agricultural economy based on intensive irrigation, large urban industrial areas, and naturally elevated concentrations of some trace elements, there is a wide range of contaminant sources that have the potential to contaminate ground water and limit its beneficial uses. In response to the many-and different-potential sources of ground-water contamination, the State of California has evolved an extensive set of rules and programs to protect ground-water quality, and agencies to implement the rules and programs. These programs have in common a focus on compliance with regulations governing chemical use and (or) ground-water quality. Although appropriate for, and successful at, their specific missions, these programs do not at present provide a comprehensive view of ground-water quality in the State of California. In October 2001, The California Assembly passed a bill, AB 599, establishing the Ground-Water- Quality Monitoring Act of 2001.' The goal of AB 599 is to improve Statewide comprehensive ground-water monitoring and increase availability of information about ground-water quality to the public. AB 599 requires the State Water Resources Control Board (SWRCB), in collaboration with an interagency task force (ITF) and a public advisory committee (PAC), to develop a plan for a comprehensive ground-water monitoring program. AB 599 specifies that the comprehensive program should be capable of assessing each ground-water basin in the State through direct and other statistically reliable sampling approaches, and that the program should integrate existing monitoring programs and design new program elements, as necessary. AB 599 also stresses the importance of prioritizing ground-water basins that provide drinking water. The United States Geological Survey (USGS), in cooperation with the SWRCB, and in coordination with the ITF and PAC, has developed a framework for a comprehensive ground-water-quality monitoring and assessment program for California. The proposed framework relies extensively on previous work conducted by the USGS through its National Water-Quality Assessment (NAWQA) program. In particular, the NAWQA program defines three types of ground-water assessment: (1) status, the assessment of the current quality of the ground-water resource; (2) trends, the detection of changes in water quality, and (3) understanding, assessing the human and natural factors that affect ground-water quality. A Statewide, comprehensive ground-water quality-monitoring and assessment program is most efficiently accomplished by applying uniform and consistent study-design and data-collection protocols to the entire State. At the same time, a comprehensive program should be relevant at a variety of scales, and therefore needs to retain flexibility to address regional and local issues. Consequently, many of the program components include a predominant element that will be consistently applied in all basins, and a secondary element that may be applied in specific basins where local conditions warrant attention.

A ground-water-quality monitoring program for Nevada

USGS Publications Warehouse

Nowlin, Jon O.

1986-01-01

A program was designed for the systematic monitoring of ground-water quality in Nevada. Basic hydrologic and water-quality principles are discussed in the formulation of a rational approach to developing a statewide monitoring program. A review of ground-water monitoring efforts in Nevada through 1977 indicates that few requirements for an effective statewide program are being met. A suggested program has been developed that consists of five major elements: (1) A Background-Quality Network to assess the existing water quality in Nevada aquifers, (2) a Contamination Source Inventory of known or potential threats to ground-water quality, (3) Surveillance Networks to monitor ground-water quality in selected hydrographic areas, (4) Intensive Surveys of individual instances of known or potential ground-water contamination, and (5) Ground-Water Data File to manage data generated by the other monitoring elements. Two indices have been developed to help assign rational priorities for monitoring ground water in the 255 hydrographic areas of Nevada: (1) A Hydrographic-Area Priority Index for surveillance monitoring, and (2) A Development-Potential Index for background monitoring of areas with little or no current development. Requirements for efficient management of data from ground-water monitoring are discussed and the three major systems containing Nevada ground-water data are reviewed. More than 11,000 chemical analyses of ground water have been acquired from existing systems and incorporated into a prototype data base.

Groundwater age for identification of baseline groundwater quality and impacts of land-use intensification - The National Groundwater Monitoring Programme of New Zealand

NASA Astrophysics Data System (ADS)

Morgenstern, Uwe; Daughney, Christopher J.

2012-08-01

SummaryWe identified natural baseline groundwater quality and impacts caused by land use intensification by relating groundwater chemistry with water age. Tritium, the most direct tracer for groundwater dating, including the time of water passage through the unsaturated zone, was overwhelmed over the recent decades by contamination from bomb-tritium from nuclear weapons testing in the early 1960s. In the Southern Hemisphere, this situation has changed now with the fading of the bomb-tritium, and tritium has become a tool for accurate groundwater dating. Tritium dating will become efficient also in the Northern Hemisphere over the next decade. Plotting hydrochemistry and field parameters versus groundwater age allowed us to identify those parameters that have increasing concentrations with age and are therefore from geological sources. These indicators for natural groundwater evolution are: Na, HCO3, SiO2, F, PO4, the redox-sensitive elements and compounds Fe, Mn, NH4, CH4, and pH and conductivity. In young groundwater that was recharged after the intensification of agriculture, nitrate, sulphate, CFC-11 and CFC-12, and pesticides are the most representative indicators for the impact of land-use intensification on groundwater quality, with 66% of the sites showing such an impact. Elevated concentrations of nitrate in oxic groundwater allowed us to reconstruct the timing and magnitude of the impact of land-use intensification on groundwater which in New Zealand occurred in two stages. Old pristine groundwater reflects the natural baseline quality. A transition to slightly elevated concentration due to low-intensity land-use was observed in groundwater recharged since around 1880. A sharp increase in nitrate and other agrochemicals due to high-intensity agriculture was observed in groundwater recharged since 1955. The threshold concentrations that distinguish natural baseline quality water from low-intensity land-use water, and low-intensity from high intensity land-use water, are 0.25 and 2.5 mg/L NO3-N, respectively. The change in groundwater quality from pristine baseline to low-intensity impact around 1880 coincides with the start of the meat export industry. The change in groundwater quality from low to high intensity landuse impact around 1955 coincides with the start of industrialised agriculture. No elevated levels of phosphate, a main compound in agricultural fertilisers and, together with nitrogen, a trigger of algae blooms in lakes, were found in young groundwater. This implies that fertiliser phosphate from non-point sources is still retained in the soil and has not yet reached the saturated groundwater systems. The source of elevated PO4, observed only in old groundwater, is therefore due purely to natural geochemical factors.

Groundwater quality in the shallow aquifers of the Madera–Chowchilla and Kings subbasins, San Joaquin Valley, California

USGS Publications Warehouse

Fram, Miranda S.; Shelton, Jennifer L.

2018-01-08

Groundwater provides more than 40 percent of California’s drinking water. To protect this vital resource, the State of California created the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The GAMA Program’s Priority Basin Project assesses the quality of groundwater resources used for drinking-water supply and increases public access to groundwater-quality information. Many households and small communities in the Madera– Chowchilla and Kings subbasins of the San Joaquin Valley rely on private domestic wells for their drinking-water supplies.

Well-construction, water-level, geophysical, and water-quality data for ground-water monitoring wells for Arnold Air Force Base, Tennessee

USGS Publications Warehouse

Hough, C.J.; Mahoney, E.N.; Robinson, J.A.

1992-01-01

Sixty-five wells were installed at 39 sites in the Arnold Air Force Base area in Coffee and Franklin Counties, Tennessee. The wells were installed to provide information on subsurface lithology, aquifer characteristics, ground-water levels, and ground-water quality. Well depths ranged from 11 to 384 feet. Water-quality samples were collected from 60 wells and analyzed for common inorganic ions, trace metals, and volatile organic compounds. The median dissolved-solids concentrations were 60 milligrams per liter in the shallow aquifer, 48 million gallons per liter in the Manchester aquifer, 1,235 milligrams per liter in the Fort Payne aquifer, and 1,712 milligrams per liter in the upper Central Basin aquifer. Caliper, temperature, natural gamma, electric, neutron porosity, gamma-gamma density, and acoustic velocity borehole-geophysical logs were obtained for the six deep wells completed below the Chattanooga Shale. Petrographic and modal analysis were performed on rock samples from each deep well. These six deep wells provide the first information in the study area on hydraulic head and water quality from below the Chattanooga Shale.

Groundwater quality in Ghaziabad district, Uttar Pradesh, India: Multivariate and health risk assessment.

PubMed

Chabukdhara, Mayuri; Gupta, Sanjay Kumar; Kotecha, Yatharth; Nema, Arvind K

2017-07-01

This study aimed to assess the quality of groundwater and potential health risk due to ingestion of heavy metals in the peri-urban and urban-industrial clusters of Ghaziabad district, Uttar Pradesh, India. Furthermore, the study aimed to evaluate heavy metals sources and their pollution level using multivariate analysis and fuzzy comprehensive assessment (FCA), respectively. Multivariate analysis using principle component analysis (PCA) showed mixed origin for Pb, Cd, Zn, Fe, and Ni, natural source for Cu and Mn and anthropogenic source for Cr. Among all the metals, Pb, Cd, Fe and Ni were above the safe limits of Bureau of Indian Standards (BIS) and World Health Organization (WHO) except Ni. Health risk in terms of hazard quotient (HQ) showed that the HQ values for children were higher than the safe level (HQ = 1) for Pb (2.4) and Cd (2.1) in pre-monsoon while in post-monsoon the value exceeded only for Pb (HQ = 1.23). The health risks of heavy metals for the adults were well within safe limits. The finding of this study indicates potential health risks to the children due to chronic exposure to contaminated groundwater in the region. Based on FCA, groundwater pollution could be categorized as quite high in the peri-urban region, and absolutely high in the urban region of Ghaziabad district. This study showed that different approaches are required for the integrated assessment of the groundwater pollution, and provides a scientific basis for the strategic future planning and comprehensive management. Copyright © 2017 Elsevier Ltd. All rights reserved.

A Use Case for implementing Earth observation (EO) to avoid regional groundwater contamination in the Midwest US

NASA Astrophysics Data System (ADS)

Bernknopf, R.; Pearlman, J.

2016-12-01

A use case to implement Landsat data for application in decisions in the agricultural sector is being developed. Stakeholders are at both the farm level and regional level. Decisions by individual farmers and communities about the intensity of use of agrochemicals on crops can affect the future quality of the groundwater in Iowa. An initial case study was completed to examine some of the technical perspectives of adapting and coupling satellite imagery and in situ water quality measurements to forecast changes in groundwater quality. This analysis was conducted to identify the benefits of EO to assist in specific decisions to improve agricultural land management and regulation of groundwater contamination. Results demonstrated that Landsat information facilitates spatiotemporal analysis of the impact of nitrates on groundwater resources. Value is dependent on whether additional information reduces the variance (uncertainty) in outcomes. The use case ultimately involves scientific experts, farmers and their representatives, and the Government. Decisions involve some level of uncertainty in scientific measurement and statistical variability affects its informational value. These issues are concerns with implementing remote sensing technology and must be examined with end users and their impact discussed and understood. Thus, the study team held meetings with subject experts from Iowa State University and the Iowa Farm Bureau to explore the next steps in developing the use case. Discussion with the subject experts focused on more detail to capture new agricultural science advances and engineering options that could be linked in a multi-scale approach. A second meeting between the study and the Iowa Farm Bureau centered on the need for efficient regulation of land use and regulation of agrochemical application in the Midwest. The impacts of these discussions and other user inputs on the directions of the use case will be presented.

Modelling of the Water Exchange between Shallow Groundwater and River during bank filtration and changing conditions

NASA Astrophysics Data System (ADS)

Wang, Weishi; Munz, Matthias; Oswald, Sascha E.

2015-04-01

The interaction of river water and groundwater is of importance for the hydrological cycle and water quality in rivers. Moreover, drinking water is often obtained by pumping groundwater in the direct vicinity of rivers, called bank filtration. Typically this implies a considerable dynamics, because changes in river water level and pumping activities will cause varying conditions, and in its effects modified by the local hydrogeology. Numerical modelling can be a tool to study spatial patterns and temporal changes. Often this is limited by model performance, uncertainty of geological structure and lack of sufficient observation values beyond water heads, for example water quality or temperature data. The aim of this research is to model the hydraulic conditions for transient conditions, including a period of substantial re-construction works in the river. Later this will then be used to include the temperature and other water quality data to improve the model performance. As shown from the geological information analysis, the majority of the water volume pumped is from the first and second aquifers, where a strong exchange between the river and groundwater can happen. The implementation of the geological structure is based on 7 main geological profiles and several scattered drilling wells of difference depths. A first model has been built in FEFLOW 6.2 as a steady fluid flow model, while the pilot-points auto-calibration method is used for estimating the hydraulic conductivity of different sediment types, based on water head information of 19 observation wells. Then a transient model during the year 2011-2013 is further calibrated based on estimated hydraulic conductivity. Furthermore, the observation wells are used to make a statistic analysis with the hydrograph of the river to clarify the correlation of changes in river to changes in groundwater.

Analysis of water quality in the Blue River watershed, Colorado, 1984 through 2007

USGS Publications Warehouse

Bauch, Nancy J.; Miller, Lisa D.; Yacob, Sharon

2014-01-01

Water quality of streams, reservoirs, and groundwater in the Blue River watershed in the central Rocky Mountains of Colorado has been affected by local geologic conditions, historical hard-rock metal mining, and recent urban development. With these considerations, the U.S. Geological Survey, in cooperation with the Summit Water Quality Committee, conducted a study to compile historical water-quality data and assess water-quality conditions in the watershed. To assess water-quality conditions, stream data were primarily analyzed from October 1995 through December 2006, groundwater data from May 1996 through September 2004, and reservoir data from May 1984 through November 2007. Stream data for the Snake River, upper Blue River, and Tenmile Creek subwatersheds upstream from Dillon Reservoir and the lower Blue River watershed downstream from Dillon Reservoir were analyzed separately. (The complete abstract is provided in the report)

The complexity of earth observation valuation: Modeling the patterns and processes of agricultural production and groundwater quality to construct a production possibilities frontier

NASA Astrophysics Data System (ADS)

Forney, W.; Raunikar, R. P.; Bernknopf, R.; Mishra, S.

2012-12-01

A production possibilities frontier (PPF) is a graph comparing the production interdependencies for two commodities. In this case, the commodities are defined as the ecosystem services of agricultural production and groundwater quality. This presentation focuses on the refinement of techniques used in an application to estimate the value of remote sensing information. Value of information focuses on the use of uncertain and varying qualities of information within a specific decision-making context for a certain application, which in this case included land use, biogeochemical, hydrogeologic, economic and geospatial data and models. The refined techniques include deriving alternate patterns and processes of ecosystem functions, new estimates of ecosystem service values to construct a PPF, and the extension of this work into decision support systems. We have coupled earth observations of agricultural production with groundwater quality measurements to estimate the value of remote sensing information in northeastern Iowa to be 857M ± 198M (at the 2010 price level) per year. We will present an improved method for modeling crop rotation patterns to include multiple years of rotation, reduction in the assumptions associated with optimal land use allocations, and prioritized improvement of the resolution of input data (for example, soil resources and topography). The prioritization focuses on watersheds that were identified at a coarse-scale of analysis to have higher intensities of agricultural production and lower probabilities of groundwater survivability (in other words, remaining below a regulatory threshold for nitrate pollution) over time, and thus require finer-scaled modeling and analysis. These improved techniques and the simulation of certain scale-dependent policy and management actions, which trade-off the objectives of optimizing crop value versus maintaining potable groundwater, and provide new estimates for the empirical values of the PPF. The calculation of a PPF in this way provides a decision maker with a tool to consider the ramifications of different policies, management practices and regional objectives.

Indexing method for assessment of pollution potential of leachate from non-engineered landfill sites and its effect on ground water quality.

PubMed

Rana, Rishi; Ganguly, Rajiv; Gupta, Ashok Kumar

2017-12-26

Dumping of solid waste in a non-engineered landfill site often leads to contamination of ground water due to leachate percolation into ground water. The present paper assesses the pollution potential of leachate generated from three non-engineered landfill sites located in the Tricity region (one each in cities of Chandigarh, Mohali and Panchkula) of Northern India and its possible effects of contamination of groundwater. Analysis of physico-chemical properties of leachate from all the three landfill sites and the surrounding groundwater samples from five different downwind distances from each of the landfill sites were collected and tested to determine the leachate pollution index (LPI) and the water quality index (WQI). The Leachate Pollution Index values of 26.1, 27 and 27.8 respectively for landfill sites of Chandigarh (CHD), Mohali (MOH) and Panchkula (PKL) cities showed that the leachate generated are contaminated. The average pH values of the leachate samples over the sampling period (9.2 for CHD, 8.97 for MOH and 8.9 for PKL) show an alkaline nature indicating that all the three landfill sites could be classified as mature to old stage. The WQI calculated over the different downwind distances from the contamination sites showed that the quality of the groundwater improved with an increase in the downwind distance. Principal component analysis (PCA) carried out established major components mainly from natural and anthropogenic sources with cumulative variance of 88% for Chandigarh, 87.1% for Mohali and 87.8% for Panchkula. Hierarchical cluster analysis (HCA) identifies three distinct cluster types for the groundwater samples. These clusters corresponds to a relatively low pollution, moderate pollution and high pollution regions. It is suggested that all the three non-engineered landfill sites be converted to engineered landfill sites to prevent groundwater contamination and also new sites be considered for construction of these engineered landfill sites as the present dumpsites are nearing the end of their lifespan capacity.

A review of distributed parameter groundwater management modeling methods

USGS Publications Warehouse

Gorelick, Steven M.

1983-01-01

Models which solve the governing groundwater flow or solute transport equations in conjunction with optimization techniques, such as linear and quadratic programing, are powerful aquifer management tools. Groundwater management models fall in two general categories: hydraulics or policy evaluation and water allocation. Groundwater hydraulic management models enable the determination of optimal locations and pumping rates of numerous wells under a variety of restrictions placed upon local drawdown, hydraulic gradients, and water production targets. Groundwater policy evaluation and allocation models can be used to study the influence upon regional groundwater use of institutional policies such as taxes and quotas. Furthermore, fairly complex groundwater-surface water allocation problems can be handled using system decomposition and multilevel optimization. Experience from the few real world applications of groundwater optimization-management techniques is summarized. Classified separately are methods for groundwater quality management aimed at optimal waste disposal in the subsurface. This classification is composed of steady state and transient management models that determine disposal patterns in such a way that water quality is protected at supply locations. Classes of research missing from the literature are groundwater quality management models involving nonlinear constraints, models which join groundwater hydraulic and quality simulations with political-economic management considerations, and management models that include parameter uncertainty.

A Review of Distributed Parameter Groundwater Management Modeling Methods

NASA Astrophysics Data System (ADS)

Gorelick, Steven M.

1983-04-01

Models which solve the governing groundwater flow or solute transport equations in conjunction with optimization techniques, such as linear and quadratic programing, are powerful aquifer management tools. Groundwater management models fall in two general categories: hydraulics or policy evaluation and water allocation. Groundwater hydraulic management models enable the determination of optimal locations and pumping rates of numerous wells under a variety of restrictions placed upon local drawdown, hydraulic gradients, and water production targets. Groundwater policy evaluation and allocation models can be used to study the influence upon regional groundwater use of institutional policies such as taxes and quotas. Furthermore, fairly complex groundwater-surface water allocation problems can be handled using system decomposition and multilevel optimization. Experience from the few real world applications of groundwater optimization-management techniques is summarized. Classified separately are methods for groundwater quality management aimed at optimal waste disposal in the subsurface. This classification is composed of steady state and transient management models that determine disposal patterns in such a way that water quality is protected at supply locations. Classes of research missing from the literature are groundwater quality management models involving nonlinear constraints, models which join groundwater hydraulic and quality simulations with political-economic management considerations, and management models that include parameter uncertainty.

Water quality in riparian boreal forest: a multi-method approach to scale biogeochemical drivers from groundwater hotspots to catchment outlets.

NASA Astrophysics Data System (ADS)

Ploum, Stefan; Kuglerová, Lenka; Leach, Jason; Laudon, Hjalmar

2017-04-01

Stream chemistry in boreal regions is for a large degree defined by the riparian zone. Within the riparian zone, groundwater hotspots represent a very small area, but likely play a major role in controlling stream water quality. Hotspots have shown to be unique in their plant species richness, soil texture and biogeochemistry. Also in terms of stream metabolism, hotspots show different responses, either due to local biotic or abiotic conditions. Readily available hydrological mapping tools, combined with biogeochemical data (stream temperature and stable water isotopes) show that there is great potential in predicting groundwater hotspots using terrain-based approaches. However, the role of individual hotspots varies in time. Presumably their hydrological regime is highly dependent on landscape properties of the upstream area. To improve the predictability of hotspots in space and time, a mechanistic understanding is needed. We achieve this by a combined approach including a damming experiment, high resolution optic fiber stream temperature measurements (DTS), a dense groundwater well network, stream and groundwater trace element analysis, frost monitoring and infrared (IR) imagery. This field-based strategy sheds light on the underlying drivers of groundwater hotspots and links them to landscape characteristics. This allows to move away from highly monitored reaches, and evaluate the relation between upland landscape features and the temporal variability of groundwater exfiltration rates on a catchment scale.

Groundwater quality around Tummalapalle area, Cuddapah District, Andhra Pradesh, India

NASA Astrophysics Data System (ADS)

Sreedhar, Y.; Nagaraju, A.

2017-11-01

The suitability of groundwater for drinking and irrigation was assessed in Tummalapalle area. Forty groundwater samples were analysed for major cations, anions and other parameters such as pH, electrical conductivity, total dissolved solids (TDS), total alkalinity and total hardness (TH). The parameters such as sodium adsorption ratio, adjusted sodium adsorption ratio (adj.SAR), per cent sodium, potential salinity, residual sodium carbonate, non-carbonate hardness, Kelly's ratio and permeability index were calculated for the evaluation of irrigation water quality. Groundwater chemistry was also analysed by statistical analysis, USSL, Wilcox, Doneen, Piper and Chadhas diagrams, to find out their suitability for irrigation. TDS and TH were used as main parameters to interpret the suitability of groundwater for drinking purpose. The correlation coefficient matrix between the hydrochemical parameters was carried out using Pearson's correlation to infer the possible water-rock interactions responsible for the variation of groundwater chemistry and this has been supported by Gibbs diagram. The results indicate that the groundwater in Tummalapalle area is alkaline in nature. Ca-Mg-HCO3 is the dominant hydrogeochemical facies. Water chemistry of the study area strongly reflects the dominance of weathering of rock-forming minerals such as bicarbonates and silicates. All parameters and diagrams suggest that the water samples of the study are good for irrigation, and the plots of TDS and TH suggest that 12.5% of the samples are good for human consumption.

Data from exploratory sampling of groundwater in selected oil and gas areas of coastal Los Angeles County and Kern and Kings Counties in southern San Joaquin Valley, 2014–15: California oil, gas, and groundwater project

USGS Publications Warehouse

Dillon, David B.; Davis, Tracy A.; Landon, Matthew K.; Land, Michael T.; Wright, Michael T.; Kulongoski, Justin T.

2016-12-09

Exploratory sampling of groundwater in coastal Los Angeles County and Kern and Kings Counties of the southern San Joaquin Valley was done by the U.S. Geological Survey from September 2014 through January 2015 as part of the California State Water Resources Control Board’s Water Quality in Areas of Oil and Gas Production Regional Groundwater Monitoring Program. The Regional Groundwater Monitoring Program was established in response to the California Senate Bill 4 of 2013 mandating that the California State Water Resources Control Board design and implement a groundwater-monitoring program to assess potential effects of well-stimulation treatments on groundwater resources in California. The U.S. Geological Survey is in cooperation with the California State Water Resources Control Board to collaboratively implement the Regional Groundwater Monitoring Program through the California Oil, Gas, and Groundwater Project. Many researchers have documented the utility of different suites of chemical tracers for evaluating the effects of oil and gas development on groundwater quality. The purpose of this exploratory sampling effort was to determine whether tracers reported in the literature could be used effectively in California. This reconnaissance effort was not designed to assess the effects of oil and gas on groundwater quality in the sampled areas. A suite of water-quality indicators and geochemical tracers were sampled at groundwater sites in selected areas that have extensive oil and gas development. Groundwater samples were collected from a total of 51 wells, including 37 monitoring wells at 17 multiple-well monitoring sites in coastal Los Angeles County and 5 monitoring wells and 9 water-production wells in southern San Joaquin Valley, primarily in Kern and Kings Counties. Groundwater samples were analyzed for field waterquality indicators; organic constituents, including volatile and semi-volatile organic compounds and dissolved organic carbon indicators; naturally present inorganic constituents, including trace elements, nutrients, major and minor ions, and iron species; naturally present stable and radioactive isotopes; dissolved noble gases; dissolved standard and hydrocarbon gases, δ13C of methane, ethane, and δ2 H of methane. In total, 249 constituents and water-quality indicators were measured. Four types of quality-control samples (blanks, replicates, matrix spikes, and surrogates spiked in environmental and blank samples) were collected at approximately 10 percent of the wells. The quality-control data were used to determine whether the groundwater-sample data were of sufficient quality for the measured analytes to be used as potential indicators of oil and gas effects. The data from the 51 groundwater samples and from the quality-control samples are presented in this report.

Evaluation of Calendar Year 1997 Groundwater and Surface Water Quality Data For The Upper East Fork Poplar Creek Hydrogeologic Regime At The U.S. Department of Energy Y-12 Plant, Oak Ridge, Tennessee

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jones, S.B.

1998-09-01

1 1.0 INTRODUCTION This report presents an evaluation of the groundwater quality monitoring data reported in: Calendar Year 1997 Annual Groundwatw Monitoring Report for the Upper East Fork Poplar Creek Hydrogeologtc Rep-meat the US. Department of Energy Y-12 Plant, Oak Ridge, Tennessee (AJA Technical Services, Inc. 1998), which is hereafter referenced as the Annual Monitoring Report. Section 2.0 presents background information for the Upper East Fork Poplar Creek Hydrogeologic Regime (East Fork Regime) that is relevant to data evaluation, including brief descriptions of the geology, the groundwater flow system, the contaminant source areas, and the extent of groundwater contamination inmore » the regime. Section 3.0 provides an overview of the groundwater sampling and analysis activities petiormed during calendar year (CY) 1997, including monitoring well locations, sampling frequency and methods, and laboratory analyses. Evaluation and interpretation of the monitoring da% described in Section 4.0, is generally focused on an overview of data quality assurance/quality control (QA/QC), long-term concentration trends for selected inorganic, organic, and radiological contaminants, and consistency with applicable site-specific conceptual contaminant transport models described in: Report on the Remedial Investigation of the Upper East Fork Poplar Creek Characterization Area at the Oak Ridge Y-12 Plant, Oak Ridge, Tennessee (U.S. Department of Energy 1998), which is referenced hereafter as the Remedial Investigation @I) Report. Findings of the data evaluations are summarized :in Section 5.0 and a list of technical reports and regulatory documents cited for more detailed irdormation (Section 6.0) concludes the report. All of the illustrations (maps and trend graphs) and data summary tables referenced in the text are presented in Appendm A and Appendix B, respectively. Appendix C provides a summary of the analytical results that meet applicable data quality objectives (DQOS) of the Y-12 Plant Groundwater Protection Program.« less

Spatial analysis of health risk assessment with arsenic intake of drinking water in the LanYang plain

NASA Astrophysics Data System (ADS)

Chen, C. F.; Liang, C. P.; Jang, C. S.; Chen, J. S.

2016-12-01

Groundwater is one of the most component water resources in Lanyang plain. The groundwater of the Lanyang Plain contains arsenic levels that exceed the current Taiwan Environmental Protection Administration (Taiwan EPA) limit of 10 μg/L. The arsenic of groundwater in some areas of the Lanyang Plain pose great menace for the safe use of groundwater resources. Therefore, poor water quality can adversely impact drinking water uses, leading to human health risks. This study analyzed the potential health risk associated with the ingestion of arsenic-affected groundwater in the arseniasis-endemic Lanyang plain. Geostatistical approach is widely used in spatial variability analysis and distributions of field data with uncertainty. The estimation of spatial distribution of the arsenic contaminant in groundwater is very important in the health risk assessment. This study used indicator kriging (IK) and ordinary kriging (OK) methods to explore the spatial variability of arsenic-polluted parameters. The estimated difference between IK and OK estimates was compared. The extent of arsenic pollution was spatially determined and the Target cancer risk (TR) and dose response were explored when the ingestion of arsenic in groundwater. Thus, a zonal management plan based on safe groundwater use is formulated. The research findings can provide a plan reference of regional water resources supplies for local government administrators and developing groundwater resources in the Lanyang Plain.

Simulated groundwater flow paths, travel time, and advective transport of nitrogen in the Kirkwood-Cohansey aquifer system, Barnegat Bay–Little Egg Harbor Watershed, New Jersey

USGS Publications Warehouse

Voronin, Lois M.; Cauller, Stephen J.

2017-07-31

Elevated concentrations of nitrogen in groundwater that discharges to surface-water bodies can degrade surface-water quality and habitats in the New Jersey Coastal Plain. An analysis of groundwater flow in the Kirkwood-Cohansey aquifer system and deeper confined aquifers that underlie the Barnegat Bay–Little Egg Harbor (BB-LEH) watershed and estuary was conducted by using groundwater-flow simulation, in conjunction with a particle-tracking routine, to provide estimates of groundwater flow paths and travel times to streams and the BB-LEH estuary.Water-quality data from the Ambient Groundwater Quality Monitoring Network, a long-term monitoring network of wells distributed throughout New Jersey, were used to estimate the initial nitrogen concentration in recharge for five different land-use classes—agricultural cropland or pasture, agricultural orchard or vineyard, urban non-residential, urban residential, and undeveloped. Land use at the point of recharge within the watershed was determined using a geographic information system (GIS). Flow path starting locations were plotted on land-use maps for 1930, 1973, 1986, 1997, and 2002. Information on the land use at the time and location of recharge, time of travel to the discharge location, and the point of discharge were determined for each simulated flow path. Particle-tracking analysis provided the link from the point of recharge, along the particle flow path, to the point of discharge, and the particle travel time. The travel time of each simulated particle established the recharge year. Land use during the year of recharge was used to define the nitrogen concentration associated with each flow path. The recharge-weighted average nitrogen concentration for all flow paths that discharge to the Toms River upstream from streamflow-gaging station 01408500 or to the BB-LEH estuary was calculated.Groundwater input into the Barnegat Bay–Little Egg Harbor estuary from two main sources— indirect discharge from base flow to streams that eventually flow into the bay and groundwater discharge directly into the estuary and adjoining coastal wetlands— is summarized by quantity, travel time, and estimated nitrogen concentration. Simulated average groundwater discharge to streams in the watershed that flow into the BB-LEH estuary is approximately 400 million gallons per day. Particle-tracking results indicate that the travel time of 56 percent of this discharge is less than 7 years. Fourteen percent of the groundwater discharge to the streams in the BB-LEH watershed has a travel time of less than 7 years and originates in urban land. Analysis of flow-path simulations indicate that approximately 13 percent of the total groundwater flow through the study area discharges directly to the estuary and adjoining coastal wetlands (approximately 64 million gallons per day). The travel time of 19 percent of this discharge is less than 7 years. Ten percent of this discharge (1 percent of the total groundwater flow through the study area) originates in urban areas and has a travel time of less than 7 years. Groundwater that discharges to the streams that flow into the BB-LEH, in general, has shorter travel times, and a higher percentage of it originates in urban areas than does direct groundwater discharge to the Barnegat Bay–Little Egg Harbor estuary.The simulated average nitrogen concentration in groundwater that discharges to the Toms River, upstream from streamflow-gaging station 01408500 was computed and compared to summary concentrations determined from analysis of multiple surface-water samples. The nitrogen concentration in groundwater that discharges directly to the estuary and adjoining coastal wetlands is a current data gap. The particle tracking methodology used in this study provides an estimate of this concentration."

Occurrence of geogenic contaminants in private wells from a crystalline bedrock aquifer in western Quebec, Canada: Geochemical sources and health risks

NASA Astrophysics Data System (ADS)

Bondu, Raphaël; Cloutier, Vincent; Rosa, Eric

2018-04-01

Nineteen private wells were investigated in order to evaluate the groundwater quality and the issues associated with well water use in a fractured metasedimentary aquifer of the Canadian Shield, in western Quebec (Canada). Groundwater sampling and analysis reveal that the quality of well water is both a potential aesthetic and health concern for the residents. Aesthetic problems are mainly related to the high levels of hardness and dissolved iron and manganese. Potential health risks are associated with the occurrence of brackish groundwater, high manganese concentrations, and arsenic concentrations exceeding the Canadian guideline value of 10 μg/l. Brackish groundwater is suspected to be derived from the mixing of fresh groundwaters with deep calcium-sodium-chloride brines of the Canadian Shield. The occurrences of iron, manganese and arsenic, primarily derived from the natural weathering of bedrock, are highly dependent on the geochemical conditions in groundwater, particularly the redox potential. Arsenic occurs mainly as arsenite (As(III)) and is thought to be released by the dissolution of iron and manganese oxyhydroxides under reducing conditions. Information obtained from well owners indicates that most households use ion exchange water softeners to minimize aesthetic problems of excessive hardness and dissolved iron and manganese concentrations. Homeowners generally take protective measures to reduce their exposure to arsenic when they are aware of the contamination. The exposure to arsenic and manganese may pose health risks for residents that do not take protective measures. The quality of well water is of paramount importance for human health in rural areas. Information on the contaminant sources and individual mitigation measures is essential to assess the health risks associated with groundwater consumption and to ensure the protection of public health.

Dissolved organic matter signatures vary between naturally acidic, circumneutral and groundwater-fed freshwaters in Australia.

PubMed

Holland, Aleicia; Stauber, Jenny; Wood, Chris M; Trenfield, Melanie; Jolley, Dianne F

2018-06-15

Dissolved organic matter (DOM) plays important roles in both abiotic and biotic processes within aquatic ecosystems, and these in turn depend on the quality of the DOM. We collected and characterized chromophoric DOM (CDOM) from different Australian freshwater types (circumneutral, naturally acidic and groundwater-fed waterways), climatic regions and seasons. CDOM quality was characterized using absorbance and fluorescence spectroscopy. Excitation emission scans followed by parallel factor (PARAFAC) analysis showed that CDOM was characterized by three main components: protein-like, fulvic-like and humic-like components commonly associated with various waters globally in the Openfluor database. Principal component analysis showed that CDOM quality varied between naturally acidic, circumneutral and groundwater-fed waters, with unique CDOM quality signatures shown for each freshwater type. CDOM quality also differed significantly within some sites between seasons. Clear differences in dominant CDOM components were shown between freshwater types. Naturally acidic waters were dominated by highly aromatic (as indicated by the specific absorbance co-efficient (SAC 340 ) and the specific UV absorbance (SUVA 254 ) values which ranged between 31 and 50 cm 2  mg -1 and 3.9-5.7 mg C -1  m -1 respectively), humic-like CDOM of high molecular weight (as indicated by abs 254/365 which ranged from 3.8 to 4.3). In contrast, circumneutral waters were dominated by fulvic-like CDOM of lower aromaticity (SAC 340 : 7-21 cm 2  mg -1 and SUVA 254 : 1.5-3.0 mg C -1  m -1 ) and lower molecular weight (abs 254/365 5.1-9.3). The groundwater-fed site had a higher abundance of protein-like CDOM, which was the least aromatic (SAC 340 : 2-5 cm 2  mg -1 and SUVA 254 : 0.58-1.1 mg C -1  m -1 ). CDOM was generally less aromatic, of a lower molecular weight and more autochthonous in nature during the summer/autumn sampling compared to winter/spring. Significant relationships were shown between various CDOM quality parameters and pH. This is the first study to show that different freshwater types (circumneutral, naturally acidic and groundwater-fed) contain distinct CDOM quality signatures in Australia, a continent with unique flora and geology. Crown Copyright © 2018. Published by Elsevier Ltd. All rights reserved.

The Slow Moving Threat of Groundwater Salinization: Mechanisms, Costs, and Adaptation Strategies

NASA Astrophysics Data System (ADS)

Pauloo, R.; Guo, Z.; Fogg, G. E.

2016-12-01

Population growth, the Green Revolution, and climate uncertainties have accelerated overdraft in groundwater basins worldwide, which in some regions is converting these basins into closed hydrologic systems, where the dominant exits for water are evapotranspiration and pumping. Irrigated agricultural basins are particularly at risk to groundwater salinization, as naturally occurring (i.e., sodium, potassium, chloride) and anthropogenic (i.e., nitrate fertilizers) salts leach back into the water table through the root zone, while a large portion of pumped groundwater leaves the system as it is evapotranspired by crops. Decreasing water quality associated with increases in Total Dissolved Solids (TDS) has been documented in aquifers across the United States in the past half century. This study suggests that the increase in TDS in aquifers can be partially explained by closed basin hydrogeology and rock-water interactions leading to groundwater salinization. This study will present: (1) a report on historical water quality in the Tulare basin, (2) a forward simulation of salt balance in Tulare Basin based on the Department of Water Resources numerical model C2VSim, and a simple mixing model, (3) an economic analysis forecasting the cost of desalination under varying degrees of managed groundwater recharge where the basin is gradually filled, avoiding hydraulic closure.

Hydrogeology and ground-water-quality conditions at the Linn County landfill, eastern Kansas, 1988-89

DOE Office of Scientific and Technical Information (OSTI.GOV)

Falwell, R.; Bigsby, P.R.; Myers, N.C.

1991-01-01

An investigation of the hydrogeology and groundwater quality conditions near the Linn County Landfill, eastern Kansas was conducted from July 1988 through June 1989. The landfill is located in an unreclaimed coal strip-mine area near Prescott. Analysis of water levels from nine temporary wells and from strip-mine ponds indicated that groundwater flows southwest through the present landfill. A county road west of the landfill acts as a barrier to shallow westerly groundwater flow. Seasonal variations in the direction of groundwater flow may occur. Water samples from monitoring wells and a strip-mine pond were analyzed for inorganic and organic compounds. Iron,more » manganese, and dissolved-organic-carbon concentrations were good indicators of the presence of landfill leachate in the groundwater. Benzene, carbon tetrachloride, 1,1-dichloroethane, and 1,1,1-trichloroethane were also detected. None of the inorganic or organic compounds detected exceeded Kansas primary drinking-water standards. Chemical concentrations and water levels in some nested wells indicate there is a hydraulic connection between the strip-mine spoil material and the underlying limestone. Leachate-contaminated groundwater has the potential to migrate southwest corner of the landfill through either strip-mine spoil material or through the underlying Pawnee Limestone.« less

Modeling the impact of the nitrate contamination on groundwater at the groundwater body scale : The Geer basin case study (Invited)

NASA Astrophysics Data System (ADS)

Brouyere, S.; Orban, P.; Hérivaux, C.

2009-12-01

In the next decades, groundwater managers will have to face regional degradation of the quantity and quality of groundwater under pressure of land-use and socio-economic changes. In this context, the objectives of the European Water Framework Directive require that groundwater be managed at the scale of the groundwater body, taking into account not only all components of the water cycle but also the socio-economic impact of these changes. One of the main challenges remains to develop robust and efficient numerical modeling applications at such a scale and to couple them with economic models, as a support for decision support in groundwater management. An integrated approach between hydrogeologists and economists has been developed by coupling the hydrogeological model SUFT3D and a cost-benefit economic analysis to study the impact of agricultural practices on groundwater quality and to design cost-effective mitigation measures to decrease nitrate pressure on groundwater so as to ensure the highest benefit to the society. A new modeling technique, the ‘Hybrid Finite Element Mixing Cell’ approach has been developed for large scale modeling purposes. The principle of this method is to fully couple different mathematical and numerical approaches to solve groundwater flow and solute transport problems. The mathematical and numerical approaches proposed allows an adaptation to the level of local hydrogeological knowledge and the amount of available data. In combination with long time series of nitrate concentrations and tritium data, the regional scale modelling approach has been used to develop a 3D spatially distributed groundwater flow and solute transport model for the Geer basin (Belgium) of about 480 km2. The model is able to reproduce the spatial patterns of nitrate concentrations together nitrate trends with time. The model has then been used to predict the future evolution of nitrate trends for two types of scenarios: (i) a “business as usual scenario” where current polluting pressures remain the same and (ii) two contrasted scenarios that simulate the implementation of programs of measures aiming at reaching good chemical status. The results of the hydrogeological model under the “business as usual scenario” have been used to assess the cost for the society of the continuous degradation of the groundwater quality. The results of the hydrogeological model under the two contrasted scenarios have been used to assess the economical benefit as avoided damage resulting from the decrease in the nitrate load. A cost-benefit analysis has been thus performed to assess the programme of mitigation measures which provides the largest benefits at the lowest cost.

Groundwater flow, quality (2007-10), and mixing in the Wind Cave National Park area, South Dakota

USGS Publications Warehouse

Long, Andrew J.; Ohms, Marc J.; McKaskey, Jonathan D.R.G.

2012-01-01

A study of groundwater flow, quality, and mixing in relation to Wind Cave National Park in western South Dakota was conducted during 2007-11 by the U.S. Geological Survey in cooperation with the National Park Service because of water-quality concerns and to determine possible sources of groundwater contamination in the Wind Cave National Park area. A large area surrounding Wind Cave National Park was included in this study because to understand groundwater in the park, a general understanding of groundwater in the surrounding southern Black Hills is necessary. Three aquifers are of particular importance for this purpose: the Minnelusa, Madison, and Precambrian aquifers. Multivariate methods applied to hydrochemical data, consisting of principal component analysis (PCA), cluster analysis, and an end-member mixing model, were applied to characterize groundwater flow and mixing. This provided a way to assess characteristics important for groundwater quality, including the differentiation of hydrogeologic domains within the study area, sources of groundwater to these domains, and groundwater mixing within these domains. Groundwater and surface-water samples collected for this study were analyzed for common ions (calcium, magnesium, sodium, bicarbonate, chloride, silica, and sulfate), arsenic, stable isotopes of oxygen and hydrogen, specific conductance, and pH. These 12 variables were used in all multivariate methods. A total of 100 samples were collected from 60 sites from 2007 to 2010 and included stream sinks, cave drip, cave water bodies, springs, and wells. In previous approaches that combined PCA with end-member mixing, extreme-value samples identified by PCA typically were assumed to represent end members. In this study, end members were not assumed to have been sampled but rather were estimated and constrained by prior hydrologic knowledge. Also, the end-member mixing model was quantified in relation to hydrogeologic domains, which focuses model results on major hydrologic processes. Finally, conservative tracers were weighted preferentially in model calibration, which distributed model errors of optimized values, or residuals, more appropriately than would otherwise be the case The latter item also provides an estimate of the relative effect of geochemical evolution along flow paths in comparison to mixing. The end-member mixing model estimated that Wind Cave sites received 38 percent of their groundwater inflow from local surface recharge, 34 percent from the upgradient Precambrian aquifer, 26 percent from surface recharge to the west, and 2 percent from regional flow. Artesian springs primarily received water from end members assumed to represent regional groundwater flow. Groundwater samples were collected and analyzed for chlorofluorocarbons, dissolved gasses (argon, carbon dioxide, methane, nitrogen, and oxygen), and tritium at selected sites and used to estimate groundwater age. Apparent ages, or model ages, for the Madison aquifer in the study area indicate that groundwater closest to surface recharge areas is youngest, with increasing age in a downgradient direction toward deeper parts of the aquifer. Arsenic concentrations in samples collected for this study ranged from 0.28 to 37.1 micrograms per liter (μg/L) with a median value of 6.4 μg/L, and 32 percent of these exceeded 10 μg/L. The highest arsenic concentrations in and near the study area are approximately coincident with the outcrop of the Minnelusa Formation and likely originated from arsenic in shale layers in this formation. Sample concentrations of nitrate plus nitrite were less than 2 milligrams per liter for 92 percent of samples collected, which is not a concern for drinking-water quality. Water samples were collected in the park and analyzed for five trace metals (chromium, copper, lithium, vanadium, and zinc), the concentrations of which did not correlate with arsenic. Dye tracing indicated hydraulic connection between three water bodies in Wind Cave.

Evaluation of Several Biological Monitoring Techniques for Hazard Assessment of Potentially Contaminated Wastewater and Groundwater. Volume 3. Old O-Field Groundwater

DTIC Science & Technology

1992-03-01

I I 3 TABLE 15. SUMMARY OF THE WATER QUALITY DURING THE OLD O-FIELD GROUNDWATER PILOT SCALE TOXICITY TESTS - UNTREATED GROUNDWATER ( FRESHWATER ...SUBJECT TERMS (Coftinut on reverse of necessary and identity by block number) FIELD IGROUP SUB-GROUP Groundwater , aquatic , to*’teltyi- daphnia,--Daphnia...FATHEAD MINNOWS AND DAPHNIDS ........................................... 30 12. SUMMARY OF THE WATER QUALITY DURING THE OLD O-FIELD GROUNDWATER BENCH

The Report of the Expert Panel on the Sustainable Management of Groundwater in Canada: The Council of Canadian Academies

NASA Astrophysics Data System (ADS)

Bruce, J. P.

2009-05-01

The Expert Panel on Groundwater was established in response to a request from the Minister of Natural Resources Canada, asking the Council of Canadian Academies to assess what is needed to achieve sustainable management of Canada's groundwater resources, from a science perspective. To this end, the Council of Canadian Academies assembled an interdisciplinary panel of experts who interpreted science, in the context of this assessment, to include natural and social sciences as well as local, provincial, and federal governance. The panel's report, released on May 11th 2009, noted that nearly 10 million Canadians rely on groundwater for household purposes, in addition to uses for agriculture and industry. Both media and public have expressed many recent concerns about water supplies and their quality. The concept of groundwater sustainability developed by the panel encompasses five interrelated goals: three that involve primarily the physical sciences and engineering, and two that are essentially socio-economic in nature. These goals are as follows: i. Protection of groundwater supplies from depletion ii. Protection of groundwater quality from contamination iii. Protection of ecosystem viability iv. Achievement of economic and social well-being v. Application of good governance The achievement of groundwater sustainability requires a careful analysis and balancing of the five goals; a comprehensive sustainability framework for groundwater has not yet been implemented in Canada. Adoption by federal, provincial and local jurisdictions of such a framework, based on the goals outlined above, would be invaluable in guiding efforts to improve the understanding and management of groundwater. To contextualize the components of the sustainability framework, the panel examined a series of case studies that typify examples along a spectrum, from near-sustainable, to situations that are fail to meet the outlined criteria. The panel identified the fragmentation of water management at all levels, between groundwater and surface water and between quantity and quality, as a major hindrance to the sustainable management of groundwater in Canada. Several problem areas were highlighted in the report, including the need for a cooperative data management system; inadequate numbers of well-trained hydrogeologists and other water specialists; and a frequent failure to consider groundwater as part of the hydrological cycle in watersheds or ground-watersheds. A series of recommendations to address these, and other problems, were developed by the Panel and will be outlined in the presentation.

Assessment and uncertainty analysis of groundwater risk.

PubMed

Li, Fawen; Zhu, Jingzhao; Deng, Xiyuan; Zhao, Yong; Li, Shaofei

2018-01-01

Groundwater with relatively stable quantity and quality is commonly used by human being. However, as the over-mining of groundwater, problems such as groundwater funnel, land subsidence and salt water intrusion have emerged. In order to avoid further deterioration of hydrogeological problems in over-mining regions, it is necessary to conduct the assessment of groundwater risk. In this paper, risks of shallow and deep groundwater in the water intake area of the South-to-North Water Transfer Project in Tianjin, China, were evaluated. Firstly, two sets of four-level evaluation index system were constructed based on the different characteristics of shallow and deep groundwater. Secondly, based on the normalized factor values and the synthetic weights, the risk values of shallow and deep groundwater were calculated. Lastly, the uncertainty of groundwater risk assessment was analyzed by indicator kriging method. The results meet the decision maker's demand for risk information, and overcome previous risk assessment results expressed in the form of deterministic point estimations, which ignore the uncertainty of risk assessment. Copyright © 2017 Elsevier Inc. All rights reserved.

Evaluation of groundwater quality and its suitability for drinking and agricultural use in Thanjavur city, Tamil Nadu, India.

PubMed

Nagarajan, R; Rajmohan, N; Mahendran, U; Senthamilkumar, S

2010-12-01

As groundwater is a vital source of water for domestic and agricultural activities in Thanjavur city due to lack of surface water resources, groundwater quality and its suitability for drinking and agricultural usage were evaluated. In this study, 102 groundwater samples were collected from dug wells and bore wells during March 2008 and analyzed for pH, electrical conductivity, temperature, major ions, and nitrate. Results suggest that, in 90% of groundwater samples, sodium and chloride are predominant cation and anion, respectively, and NaCl and CaMgCl are major water types in the study area. The groundwater quality in the study site is impaired by surface contamination sources, mineral dissolution, ion exchange, and evaporation. Nitrate, chloride, and sulfate concentrations strongly express the impact of surface contamination sources such as agricultural and domestic activities, on groundwater quality, and 13% of samples have elevated nitrate content (>45 mg/l as NO(3)). PHREEQC code and Gibbs plots were employed to evaluate the contribution of mineral dissolution and suggest that mineral dissolution, especially carbonate minerals, regulates water chemistry. Groundwater suitability for drinking usage was evaluated by the World Health Organization and Indian standards and suggests that 34% of samples are not suitable for drinking. Integrated groundwater suitability map for drinking purposes was created using drinking water standards based on a concept that if the groundwater sample exceeds any one of the standards, it is not suitable for drinking. This map illustrates that wells in zones 1, 2, 3, and 4 are not fit for drinking purpose. Likewise, irrigational suitability of groundwater in the study region was evaluated, and results suggest that 20% samples are not fit for irrigation. Groundwater suitability map for irrigation was also produced based on salinity and sodium hazards and denotes that wells mostly situated in zones 2 and 3 are not suitable for irrigation. Both integrated suitability maps for drinking and irrigation usage provide overall scenario about the groundwater quality in the study area. Finally, the study concluded that groundwater quality is impaired by man-made activities, and proper management plan is necessary to protect valuable groundwater resources in Thanjavur city.

Y-12 Groundwater Protection Program Groundwater and Surface water Sampling and Analysis Plan for Calendar Year 2006

DOE Office of Scientific and Technical Information (OSTI.GOV)

N /A

2006-01-01

This plan provides a description of the groundwater and surface water quality monitoring activities planned for calendar year (CY) 2006 at the U.S. Department of Energy (DOE) Y-12 National Security Complex (Y-12) that will be managed by the Y-12 Groundwater Protection Program (GWPP). Groundwater and surface water monitoring performed by the GWPP during CY 2006 will be in accordance with DOE Order 540.1 requirements and the following goals: {sm_bullet} to maintain surveillance of existing and potential groundwater contamination sources; {sm_bullet} to provide for the early detection of groundwater contamination and determine the quality of groundwater and surface water where contaminantsmore » are most likely to migrate beyond the Oak Ridge Reservation property line; {sm_bullet} to identify and characterize long-term trends in groundwater quality at Y-12; and ! to provide data to support decisions concerning the management and protection of groundwater resources. Groundwater and surface water monitoring during CY 2006 will be performed primarily in three hydrogeologic regimes at Y-12: the Bear Creek Hydrogeologic Regime (Bear Creek Regime), the Upper East Fork Poplar Creek Hydrogeologic Regime (East Fork Regime), and the Chestnut Ridge Hydrogeologic Regime (Chestnut Ridge Regime). The Bear Creek and East Fork regimes are located in Bear Creek Valley, and the Chestnut Ridge Regime is located south of Y-12 (Figure A.1). Additional surface water monitoring will be performed north of Pine Ridge, along the boundary of the Oak Ridge Reservation (Figure A.1). Modifications to the CY 2006 monitoring program may be necessary during implementation. Changes in programmatic requirements may alter the analytes specified for selected monitoring wells or may add or remove wells from the planned monitoring network. All modifications to the monitoring program will be approved by the Y-12 GWPP manager and documented as addenda to this sampling and analysis plan. The following sections of this report provide details regarding the CY 2006 groundwater and surface water monitoring activities. Section 2 describes the monitoring locations in each regime and the processes used to select the sampling locations. A description of the field measurements and laboratory analytes is provided in Section 3; sample collection methods and procedures are described in Section 4; and Section 5 lists the documents cited for more detailed operational and technical information. The narrative sections of the report reference several appendices. Figures (maps and diagrams) and tables (excluding data summary tables presented in the narrative sections) are in Appendix A and Appendix B, respectively. The monitoring frequency and selection criteria for each sampling location is in Appendix C. Laboratory requirements (bottle lists, holding times, etc.) are provided in Appendix D. If issued, addenda to this plan will be inserted in Appendix E, and Groundwater Monitoring Schedules (when issued) will be inserted in Appendix F. Guidance for managing purged groundwater is provided in Appendix G.« less

Water Resources Data, Florida, Water Year 2003, Volume 3B: Southwest Florida Ground Water

USGS Publications Warehouse

Kane, Richard L.; Fletcher, William L.; Lane, Susan L.

2004-01-01

Water resources data for the 2003 water year in Florida consist of continuous or daily discharges for 385 streams, periodic discharge for 13 streams, continuous daily stage for 255 streams, periodic stage for 13 streams, peak stage for 36 streams and peak discharge for 36 streams, continuous or daily elevations for 13 lakes, periodic elevations for 46 lakes; continuous ground-water levels for 441 wells, periodic ground-water levels for 1,227 wells, and quality-of-water data for 133 surface-water sites and 308 wells. The data for Southwest Florida include records of stage, discharge, and water quality of streams; stage, contents, water quality of lakes and reservoirs, and water levels and water quality of ground-water wells. Volume 3B contains records for continuous ground-water elevations for 128 wells; periodic ground-water elevations at 31 wells; miscellaneous ground-water elevations at 405 wells; and water quality at 32 ground-water sites. These data represent the national Water Data System records collected by the U.S. Geological Survey and cooperating local, state, and federal agencies in Florida.

Factors controlling groundwater salinization and hydrogeochemical processes in coastal aquifers from southern Spain.

PubMed

Argamasilla, M; Barberá, J A; Andreo, B

2017-02-15

In detrital coastal aquifers, seawater and surface water may interact with groundwater in multiple ways. Understanding the interference of water fluxes in this type of environment is essential to effectively manage the groundwater resources in water-stressed regions, such as the Mediterranean coastal fringe. In this research, the characterization of the main hydrogeochemical processes and the interaction between surface water and groundwater in the Marbella-Estepona coastal aquifers (southern Spain) have been carried out by means of the combined use of different hydrogeochemical indicators along with isotope data. The results show that the diversity of source lithologies (peridotite, carbonate and/or metapelitic) substantially conditions the groundwater geochemistry. The analysis of ionic deltas made it possible a preliminary screening of the geochemical reactions that occur in the Marbella-Estepona aquifers, while the Discriminant Analysis allowed for a consistent classification of sampled groundwater types. The dissolution of calcite and dolomite determines the chemical composition of the groundwater from the eastern sector that are more conditioned by the rainwater infiltration. The dissolution of magnesium-bearing minerals (predominantly forming peridotite rocks) is observed in groundwater samples from the western and central sectors, whose chemical composition showed a greater influence of surface water. The spatial analysis of rCl - /Br - in groundwater has permitted to corroborate that saline intrusion is negligible, hardly affecting to its original water quality. The irregularly distributed recharge by precipitation (seasonal effect) and the atmospheric circulation of cloud fronts (coastal/continental effect) explains why most of groundwater sampled is isotopically impoverished with respect to the rainfall signature. The isotope approach also suggests the hydraulic relationship between surface water and groundwater in the study site. A deeper knowledge of spatial hydrogeochemical variations in coastal groundwater and the influence of water sources over them are crucial for a sustainable groundwater management and global change adaptation in equivalent Mediterranean water-stressed regions. Copyright © 2016 Elsevier B.V. All rights reserved.

Transfer of European Approach to Groundwater Monitoring in China

NASA Astrophysics Data System (ADS)

Zhou, Y.

2007-12-01

Major groundwater development in North China has been a key factor in the huge economic growth and the achievement of self sufficiency in food production. Groundwater accounts for more than 70 percent of urban water supply and provides important source of irrigation water during dry period. This has however caused continuous groundwater level decline and many associated problems: hundreds of thousands of dry wells, dry river beds, land subsidence, seawater intrusion and groundwater quality deterioration. Groundwater levels in the shallow unconfined aquifers have fallen 10m up to 50m, at an average rate of 1m/year. In the deep confined aquifers groundwater levels have commonly fallen 30m up to 90m, at an average rate of 3 to 5m/year. Furthermore, elevated nitrate concentrations have been found in shallow groundwater in large scale. Pesticides have been detected in vulnerable aquifers. Urgent actions are necessary for aquifer recovery and mitigating groundwater pollution. Groundwater quantity and quality monitoring plays a very important role in formulating cost-effective groundwater protection strategies. In 2000 European Union initiated a Water Framework Directive (2000/60/EC) to protect all waters in Europe. The objective is to achieve good water and ecological status by 2015 cross all member states. The Directive requires monitoring surface and groundwater in all river basins. A guidance document for monitoring was developed and published in 2003. Groundwater monitoring programs are distinguished into groundwater level monitoring and groundwater quality monitoring. Groundwater quality monitoring is further divided into surveillance monitoring and operational monitoring. The monitoring guidance specifies key principles for the design and operation of monitoring networks. A Sino-Dutch cooperation project was developed to transfer European approach to groundwater monitoring in China. The project aims at building a China Groundwater Information Centre. Case studies in 3 pilot areas have been conducted to build research capacities of the central and provincial groundwater information centers in providing groundwater information services to decision makers and public. Groundwater regime zoning and pollution risk maps were used to lay-out groundwater quantity and quality monitoring networks, respectively. Automatic groundwater recorders were installed in selected observation wells. ArcGIS based regional groundwater information systems were constructed and used to create groundwater regime zoning and pollution risk maps. Steady state groundwater models have been constructed and calibrated. Transient groundwater models are under calibration. Groundwater resources development scenarios were formulated. The model will be used to predict what will be consequences in next 20 years if current situation continues as business as usual. Possibilities of reducing groundwater abstraction and opportunities of artificially enhanced groundwater recharge will be analyzed. Combination of decreasing abstraction and increasing recharge may lead to a sustainable plan of future groundwater resources development.

Effects of three highway-runoff detention methods on water quality of the surficial aquifer system in central Florida

USGS Publications Warehouse

Schiffer, D.M.

1989-01-01

Water quality of the surficial aquifer system in central Florida was evaluated at one exfiltration pipe, two ponds (detention and retention), and two swales in central Florida, representing three runoff-detention methods, to detect any effect from infiltrating highway runoff. Concentrations of major ions, metals, and nutrients in groundwater and bottom sediments were measured from 1984 through 1986. At each study area, constituent concentrations in groundwater near the structure were compared to concentrations in groundwater from an upgradient control site. Groundwater quality data were also pooled by detention method and statistically compared to detect any significant differences between methods. Significantly greater mean phosphorus concentrations in groundwater near the exfiltration pipe than those in the control well was the only evidence of increasing constituent concentrations in groundwater near structures. The quality of water was more variable, and had greater constituent concentrations in the unsaturated zone than in the saturated zone near the exfiltration pipe. Values of water quality variables measured in groundwater at all study areas generally were within State drinking water standards. The main exception was dissolved iron, which commonly exceeded 300 micrograms/L at one swale and the detention pond. Results of the study indicate that natural processes occurring in soils attenuate inorganic constituent concentrations prior to reaching the receiving groundwater. However, organic compounds detected in bottom sediments at the retention pond indicate a potential problem that may eventually affect the quality of the receiving groundwater. (USGS)

Plan of study for the Ohio-Indiana carbonate-bedrock and glacial- aquifer system

USGS Publications Warehouse

Bugliosi, E.F.

1990-01-01

The major aquifers of 35,000 sq mi area in western Ohio and eastern Indiana consist of Silurian and Devonian carbonate bedrock and Quaternary glacial deposits. These bedrock units and glacial deposits have been designated for study as part of the U.S. Geological Survey 's Regional Aquifer System Analysis program, a nationwide program to assess the regional hydrology, geology and water quality of the Nation 's most important aquifers. The purpose of the study is to define the hydrology, geochemistry, and geologic framework of the aquifer system within the Silurian and Devonian rocks and glacial deposits, with emphasis on describing the groundwater flow patterns and characterizing the water quality. The study, which began in 1988 , is expected to be completed in 1993. In 1980, the aquifers in the study area supplied more than 280 million gallons of water/day to industry, agriculture, and a population of more than 6.3 million people. With a projected future population growth to 7.1 million in 1990, and with intensified agricultural and industrial uses, water withdrawals from these bedrock and glacial aquifers are expected to be increased. The most significant groundwater problems in the study area result from the pronounced areal differences in availability and quality of the groundwater. These differences are related to the lateral discontinuity of many of the glacial deposits and to variations in secondary permeability of the bedrock aquifers associated with patterns of fracturing. Planned activities of the study include compilation of available geohydrologic and water quality data, such as groundwater levels, geohydrologic properties of aquifers, chemical analyses, land use and water use data, and ancillary data such as digital satellite images. Additional geohydrologic and water quality data may be collected from existing wells or wells that may be drilled for this study. A computerized, geographic information system will be used as a data base management tool and for spatial analysis and presentation of the data. A digital computer model will be developed to study the regional groundwater flow system and to investigate the effects of development on the aquifer system. (USGS)

Ground-water age, flow, and quality near a landfill, and changes in ground-water conditions from 1976 to 1996 in the Swinomish Indian Reservation, northwestern Washington

USGS Publications Warehouse

Thomas, B.E.; Cox, S.E.

1998-01-01

This report describes the results of two related studies: a study of ground-water age, flow, and quality near a landfill in the south-central part of the Swinomish Indian Reservation; and a study of changes in ground-water conditions for the entire reservation from 1976 to 1996. The Swinomish Indian Reservation is a 17-square-mile part of Fidalgo Island in northwestern Washington. The groundwater flow system in the reservation is probably independent of other flow systems in the area because it is almost completely surrounded by salt water. There has been increasing stress on the ground-water resources of the reservation because the population has almost tripled during the past 20 years, and 65 percent of the population obtain their domestic water supply from the local ground-water system. The Swinomish Tribe is concerned that increased pumping of ground water might have caused decreased ground-water discharge into streams, declines in ground-water levels, and seawater intrusion into the ground-water system. There is also concern that leachate from an inactive landfill containing mostly household and wood-processing wastes may be contaminating the ground water. The study area is underlain by unconsolidated glacial and interglacial deposits of Quaternary age that range from about 300 to 900 feet thick. Five hydrogeologic units have been defined in the unconsolidated deposits. From top to bottom, the hydrogeologic units are a till confining bed, an outwash aquifer, a clay confining bed, a sea-level aquifer, and an undifferentiated unit. The ground-water flow system of the reservation is similar to other island-type flow systems. Water enters the system through the water table as infiltration and percolation of precipitation (recharge), then the water flows downward and radially outward from the center of the island. At the outside edges of the system, ground water flows upward to discharge into the surrounding saltwater bodies. Average annual recharge is estimated to be about 3 inches, or 12 percent of the average annual precipitation. Ground water in the outwash aquifer near the landfill is estimated to be between 15 and 43 years old. Some deeper ground waters and ground water near the discharge areas close to the shoreline are older than 43 years. Analysis of water-quality data collected for this study and review of existing data indicate that material in the landfill has had no appreciable impact on the current quality of ground water outside of the landfill. The water quality of samples from seven wells near to and downgradient from the landfill appears to be similar to the ground-water quality throughout the entire study area. The high iron and manganese concentrations found in most of the samples from wells near the landfill are probably within the range of natural concentrations for the study area. Ground-water pumping during the past 20 years has not caused any large changes in ground-water discharge to streams, ground-water levels, or seawater intrusion into the ground-water system. Ground-water discharge into Snee-oosh Creek and Munks Creek had similar magnitudes in the summers of 1976 and 1996; flows in both creeks during those summers ranged from 0.07 t 0.15 cubic feet per second. Ground-water levels changed minimally between 1976 and 1996. The average water-level change for 20 wells with more than 10 years between measurements was -0.7 feet and the two largest waterlevel declines were 6 and 9 feet. No appreciable seawater intrusion was found in the ground water in 1996, and there was no significant increase in the extent of seawater intrusion from 1976 to 1996. Median chloride concentrations of water samples collected from wells were 22 milligrams per liter in 1976 and 18 milligrams per liter in 1996.

Residence time, chemical and isotopic analysis of nitrate in the groundwater and surface water of a small agricultural watershed in the Coastal Plain, Bucks Branch, Sussex County, Delaware

USGS Publications Warehouse

Clune, John W.; Denver, Judith M.

2012-01-01

Nitrate is a common contaminant in groundwater and surface water throughout the Nation, and water-resource managers need more detailed small-scale watershed research to guide conservation efforts aimed at improving water quality. Concentrations of nitrate in Bucks Branch are among the highest in the state of Delaware and a scientific investigation was performed to provide water-quality information to assist with the management of agriculture and water resources. A combination of major-ion chemistry, nitrogen isotopic composition and age-dating techniques was used to estimate the residence time and provide a chemical and isotopic analysis of nitrate in the groundwater in the surficial aquifer of the Bucks Branch watershed in Sussex County, Delaware. The land use was more than 90 percent agricultural and most nitrogen inputs were from manure and fertilizer. The apparent median age of sampled groundwater is 18 years and the estimated residence time of groundwater contributing to the streamflow for the entire Bucks Branch watershed at the outlet is approximately 19 years. Concentrations of nitrate exceeded the U.S. Environmental Protection Agency drinking-water standard of 10 milligrams per liter (as nitrogen) in 60 percent of groundwater samples and 42 percent of surface-water samples. The overall geochemistry in the Bucks Branch watershed indicates that agriculture is the predominant source of nitrate contamination and the observed patterns in major-ion chemistry are similar to those observed in other studies on the Mid-Atlantic Coastal Plain. The pattern of enrichment in nitrogen and oxygen isotopes (δ15N and δ18O) of nitrate in groundwater and surface water indicates there is some loss of nitrate through denitrification, but this process is not sufficient to remove all of the nitrate from groundwater discharging to streams, and concentrations of nitrate in streams remain elevated.

Social Perception of Public Water Supply Network and Groundwater Quality in an Urban Setting Facing Saltwater Intrusion and Water Shortages

NASA Astrophysics Data System (ADS)

Alameddine, Ibrahim; Jawhari, Gheeda; El-Fadel, Mutasem

2017-04-01

Perceptions developed by consumers regarding the quality of water reaching their household can affect the ultimate use of the water. This study identified key factors influencing consumers' perception of water quality in a highly urbanized coastal city, experiencing chronic water shortages, overexploitation of groundwater, and accelerated saltwater intrusion. Household surveys were administered to residents to capture views and perceptions of consumed water. Concomitantly, groundwater and tap water samples were collected and analyzed at each residence for comparison with perceptions. People's rating of groundwater quality was found to correlate to the measured water quality both in the dry and wet seasons. In contrast, perceptions regarding the water quality of the public water supply network did not show any correlation with the measured tap water quality indicators. Logistic regression models developed to predict perception based on salient variables indicated that age, apartment ownership, and levels of total dissolved solids play a significant role in shaping perceptions regarding groundwater quality. Perceptions concerning the water quality of the public water supply network appeared to be independent of the measured total dissolved solids levels at the tap but correlated to those measured in the wells. The study highlights misconceptions that can arise as a result of uncontrolled cross-connections of groundwater to the public supply network water and the development of misaligned perceptions based on prior consumption patterns, water shortages, and a rapidly salinizing groundwater aquifer.

Social Perception of Public Water Supply Network and Groundwater Quality in an Urban Setting Facing Saltwater Intrusion and Water Shortages.

PubMed

Alameddine, Ibrahim; Jawhari, Gheeda; El-Fadel, Mutasem

2017-04-01

Perceptions developed by consumers regarding the quality of water reaching their household can affect the ultimate use of the water. This study identified key factors influencing consumers' perception of water quality in a highly urbanized coastal city, experiencing chronic water shortages, overexploitation of groundwater, and accelerated saltwater intrusion. Household surveys were administered to residents to capture views and perceptions of consumed water. Concomitantly, groundwater and tap water samples were collected and analyzed at each residence for comparison with perceptions. People's rating of groundwater quality was found to correlate to the measured water quality both in the dry and wet seasons. In contrast, perceptions regarding the water quality of the public water supply network did not show any correlation with the measured tap water quality indicators. Logistic regression models developed to predict perception based on salient variables indicated that age, apartment ownership, and levels of total dissolved solids play a significant role in shaping perceptions regarding groundwater quality. Perceptions concerning the water quality of the public water supply network appeared to be independent of the measured total dissolved solids levels at the tap but correlated to those measured in the wells. The study highlights misconceptions that can arise as a result of uncontrolled cross-connections of groundwater to the public supply network water and the development of misaligned perceptions based on prior consumption patterns, water shortages, and a rapidly salinizing groundwater aquifer.

Water resources management strategies and its implications on hydrodynamic and hydrochemical changes of costal groundwater: Case of Grombalia shallow aquifer, NE Tunisia

NASA Astrophysics Data System (ADS)

Lachaal, Fethi; Chekirbane, Anis; Chargui, Sameh; Sellami, Haykel; Tsujimura, Maki; Hezzi, Hmida; Faycel, Jelassi; Mlayah, Ammar

2016-12-01

Information on groundwater quantity as well as quality is required by water managers and decision-makers for defining a sustainable management strategy. This requires a comprehensive assessment of the surface water and groundwater resources. This paper provides an assessment of water resources management strategy in the Grombalia region (Northeast Tunisia) and its impact on quantity and quality evolution of groundwater resources based on an approach that combines (i) hydro-climatic data, (ii) field monitoring, (iii) historic piezometric records, and (iv) geochemical and stable isotopes (δ18O and δ2H) analyses. We apply this approach to identify the origin of the various water resources and outline how the actual water management impact the quantity and quality of the groundwater in the region. As consequence of poor water resources management, the shallow groundwater levels have been disrupted: a groundwater rise is observed in the centre and a piezometric drawdown is observed in the upstream regions. Groundwater quality degradation was registered especially in the centre and downstream zones.

A proposed ground-water quality monitoring network for Idaho

USGS Publications Warehouse

Whitehead, R.L.; Parliman, D.J.

1979-01-01

A ground water quality monitoring network is proposed for Idaho. The network comprises 565 sites, 8 of which will require construction of new wells. Frequencies of sampling at the different sites are assigned at quarterly, semiannual, annual, and 5 years. Selected characteristics of the water will be monitored by both laboratory- and field-analysis methods. The network is designed to: (1) Enable water managers to keep abreast of the general quality of the State 's ground water, and (2) serve as a warning system for undesirable changes in ground-water quality. Data were compiled for hydrogeologic conditions, ground-water quality, cultural elements, and pollution sources. A ' hydrologic unit priority index ' is used to rank 84 hydrologic units (river basins or segments of river basins) of the State for monitoring according to pollution potential. Emphasis for selection of monitoring sites is placed on the 15 highest ranked units. The potential for pollution is greatest in areas of privately owned agricultural land. Other areas of pollution potential are residential development, mining and related processes, and hazardous waste disposal. Data are given for laboratory and field analyses, number of site visits, manpower, subsistence, and mileage, from which costs for implementing the network can be estimated. Suggestions are made for data storage and retrieval and for reporting changes in water quality. (Kosco-USGS)

Quality of water in the alluvial aquifer, American Bottoms, East St Louis, Illinois

USGS Publications Warehouse

Voelker, David C.

1984-01-01

Ground-water levels in the American Bottoms regions around East St. Louis, Illinois, have risen several feet since the early 1970's. Artificial dewatering of the aquifer by increased pumping is being investigated by the U.S. Army Corps of Engineers to alleviate economic and health concerns resulting from elevated ground-water levels. A ground-water quality evaluation is necessary for selecting a feasible dewatering scheme. Analyses of water samples from 63 wells show that except for iron, manganese, and dissolved solids, constituent concentrations do not exceed Illinois water-quality standards. The waters are primarily of the calcium-magnesium-bicarbonate type with some calcium-sulfate type water. Iron concentrations ranged from less than 3 to 82,000 micrograms per liter, manganese from 5 to 5,300 micrograms per liter, and dissolved solids from 140 to 3,000 milligrams per liter. These constituent concentrations exceed Illinois ' public water supply, effluent, and general water-quality standards in most samples and analysis indicates the concentrations are representative of the ambient water quality. Concentrations of nitrite + nitrate nitrogen fluoride, zinc, lead, and sulfate also exceeded Illinois water-quality standards in a few samples. Concentrations of organic pesticides, polychlorinated biphenyls, and polychlorinated naphthalenes were below analytical detection limits. (USGS)

The quality of our Nation's waters: Water quality in principal aquifers of the United States, 1991-2010

USGS Publications Warehouse

DeSimone, Leslie A.; McMahon, Peter B.; Rosen, Michael R.

2015-01-01

About 130 million people in the United States rely on groundwater for drinking water, and the need for high-quality drinking-water supplies becomes more urgent as our population grows. Although groundwater is a safe, reliable source of drinking water for millions of people nationwide, high concentrations of some chemical constituents can pose potential human-health concerns. Some of these contaminants come from the rocks and sediments of the aquifers themselves, and others are chemicals that we use in agriculture, industry, and day-to-day life. When groundwater supplies are contaminated, millions of dollars can be required for treatment so that the supplies can be usable. Contaminants in groundwater can also affect the health of our streams and valuable coastal waters. By knowing where contaminants occur in groundwater, what factors control contaminant concentrations, and what kinds of changes in groundwater quality might be expected in the future, we can ensure the availability and quality of this vital natural resource in the future.

Water quality responses to the interaction between surface water and groundwater along the Songhua River, NE China

NASA Astrophysics Data System (ADS)

Teng, Yanguo; Hu, Bin; Zheng, Jieqiong; Wang, Jinsheng; Zhai, Yuanzheng; Zhu, Chen

2018-03-01

Investigation of surface water and groundwater interaction (SW-GW interaction) provides basic information for regional water-resource protection, management, and development. In this survey of a 10-km-wide area along both sides of the Songhua River, northeast China, the hydrogeochemical responses to different SW-GW interactions were studied. Three types of SW-GW interactions were identified—"recharge", "discharge", and "flow-through"—according to the hydraulic connection between the surface water and groundwater. The single factor index, principal component analysis, and hierarchical cluster analysis of the hydrogeochemistry and pollutant data illuminated the hydrogeochemical response to the various SW-GW interactions. Clear SW-GW interactions along the Songhua River were revealed: (1) upstream in the study area, groundwater usually discharges into the surface water, (2) groundwater is recharged by surface water downstream, and (3) discharge and flow-through coexist in between. Statistical analysis indicated that the degree of hydrogeochemical response in different types of hydraulic connection varied, being clear in recharge and flow-through modes, and less obvious in discharge mode. During the interaction process, dilution, adsorption, redox reactions, nitrification, denitrification, and biodegradation contributed to the pollutant concentration and affected hydrogeochemical response in the hyporheic zone.

Village-Level Identification of Nitrate Sources: Collaboration of Experts and Local Population in Benin, Africa

NASA Astrophysics Data System (ADS)

Crane, P.; Silliman, S. E.; Boukari, M.; Atoro, I.; Azonsi, F.

2005-12-01

Deteriorating groundwater quality, as represented by high nitrates, in the Colline province of Benin, West Africa was identified by the Benin national water agency, Direction Hydraulique. For unknown reasons the Colline province had consistently higher nitrate levels than any other region of the country. In an effort to address this water quality issue, a collaborative team was created that incorporated professionals from the Universite d'Abomey-Calavi (Benin), the University of Notre Dame (USA), Direction l'Hydraulique (a government water agency in Benin), Centre Afrika Obota (an educational NGO in Benin), and the local population of the village of Adourekoman. The goals of the project were to: (i) identify the source of nitrates, (ii) test field techniques for long term, local monitoring, and (iii) identify possible solutions to the high levels of groundwater nitrates. In order to accomplish these goals, the following methods were utilized: regional sampling of groundwater quality, field methods that allowed the local population to regularly monitor village groundwater quality, isotopic analysis, and sociological methods of surveys, focus groups, and observations. It is through the combination of these multi-disciplinary methods that all three goals were successfully addressed leading to preliminary identification of the sources of nitrates in the village of Adourekoman, confirmation of utility of field techniques, and initial assessment of possible solutions to the contamination problem.

Federal-State Cooperative Program in Kansas, seminar proceedings, July 1985

USGS Publications Warehouse

Huntzinger, T.L.

1985-01-01

During the past few years, water-resource management in Kansas has undergone reorientation with the creation of the Kansas Water Authority and the Kansas Water office. New thrusts toward long-term goals based on the Kansas State Water plan demand strong communication and coordination between all water-related agencies within the State. The seminar discussed in this report was an initial step by the Kansas Water Office to assure the continued presence of a technical-coordination process and to provide an opportunity for the U.S. Geological Survey to summarize their technical-informational activities in Kansas for the benefit of State and Federal water agencies with the State. The seminar was held on July 8 and 9, 1985, in Lawrence, Kansas. The agenda included a summary of the data-collection activities and short synopses of projects completed within the past year and those currently underway. The data program discussions described the information obtained at the surface water, groundwater, water quality, and sediment sites in Kansas. Interpretive projects summarized included studies in groundwater modeling, areal hydrologic analysis, regional analysis of floods , low-flow, high-flow, and flow-volume characteristics, water quality of groundwater and lakes, and traveltime and transit-loss analysis. (USGS)

Assessing quality and quantity of groundwater DOC in relation to plant export from different over-winter green-cover treatments in tillage farming systems

NASA Astrophysics Data System (ADS)

Premrov, Alina; Coxon, Catherine; Hackett, Richard; Richards, Karl

2010-05-01

The biogeochemistry of nitrogen is often connected to carbon and C/N dynamics. The dissolved organic carbon (DOC) electron donor availability can be related to groundwater denitrification (Buss, et al. 2005). Therefore groundwater nitrate attenuation processes are also frequently linked to carbon availability. In recent years the role of over-winter green cover in tillage farming has been studied extensively. Nevertheless further research on the biogeochemical effect of green cover on soil/sediment and groundwater quality is still needed. In particular plant roots are known to exude different types of organic compounds, but their role in groundwater quality has not been investigated in depth. According to Cannavo et al. (2004a,b), in addition to quantity, the quality of water-extractable soil organic matter (e.g. molecular size/weight) has also an important role for microbial activity. In this study we investigate the effect of over-winter green-cover on potential DOC export to shallow groundwater (2 - 5 m below ground level), located on tillage land in Oak Park, Carlow, Ireland. The experiment includes three over-winter green-cover treatments: natural green-cover, mustard and no-cover (sprayed with herbicide following harvest); and is underlain by a sand and gravel aquifer. The site is equipped with 4 shallow piezometers per treatment (total no. of piezometers is 20, including treatments and surrounding piezometers). In addition to monitoring the quantity of DOC concentrations in shallow groundwater under different green cover treatments over time, an attempt was made to evaluate the quality of dissolved organic matter in shallow groundwater using Excitation Emission Fluorescence Matrix (EEFM) profiles obtained from analyses performed on a Varian Fluorescence Spectrophotometer of a single batch of samples (from all 20 installed piezometers in September 2009). To evaluate the quality of dissolved organic matter in shallow groundwater, computation of the humification index (HIX) was performed. Computation of HIX was adapted from the methodology described in Zsolnay (2003) and Cannavo et al. (2004b) using emission spectra from excitation at 245nm, and the HIX was expressed as the H/L ratio. H/L is defined as the ratio between the area of the higher and lower usable quarter of emission spectrum peak [i.e. H (352 - 382nm), L (450 - 480nm)], corresponding to the pools of high (H) and low (L) organic molecule sizes (Cannavo et al., 2004b). Quantitatively the results showed generally low DOC values (< 3mg/L). However, the groundwater DOC concentrations under mustard-cover were higher if compared to two other treatments, which indicated possible mustard plant DOC export to shallow groundwater (Premrov et al., 2009). Qualitative analyses showed an EEFM profile pattern typical for water extractable organic matter. Mean HIX values were generally low (< 2), as expected for shallow groundwater, corresponding to small organic molecules. The HIX levels obtained in this study were also generally comparable to the low HIX values found by Cannavo (2004b) (e.g. HIX of c. 2 at 1- 2 m unsaturated zone depth). Despite slightly higher mean HIX values under mustard-cover, no clear trend was observed in the quality of dissolved organic matter in groundwater in relation to different green cover treatments: i.e. mean groundwater HIX value under mustard treatment (n=4 per treatment) was 1.84, std.err.= 0.19; while the mean value for natural regeneration was 1.62 (std.err.=0.15) and that for the no-cover treatment was 1.60 (std.err.=0.16). The results indicate the importance of further studies using EEFM analysis to assess the quality of dissolved organic matter in shallow groundwater. Acknowledgements This work was funded by a Teagasc Walsh Fellowship and a Trinity College Dublin One-year Postgraduate Student Award. The authors thank Dr. Norman Allot and Dr. Carlos Rocha from Trinity College Dublin for their support and suggestions regarding the Fluorescence Spectrophotometrical analysis. Literature: Buss, S.R., Rivett, M.O., Morgan, P., Bemment, C.D., 2005. Using science to create a better place: Attenuation of nitrate in the sub-surface environment. Science Report SC030155/SR2. Environment Agency, UK. Cannavo, P., Richaume, A., Lafolie, F., 2004a. Fate of nitrogen and carbon in the vadose zone: in situ and laboratory measurements of seasonal variations in aerobic respiratory and denitrifying activities. Soil Biology and Biochemistry 36, p. 463-478. Cannavo, P., Dudal, Y., Boudenne, J.L., Lafolie, F., 2004b. Potential for Fluorescence Spectroscopy To Assess the Quality of Soil Water-Extracted Organic Matter. Soil Science 169, p. 688-696. Premrov, A., Coxon, C.E., Hackett, R., Brennan D., Sills, P. & Richards, K. 2009. Over-winter green cover in a spring barley system: Role in exporting dissolved organic carbon to shallow groundwater and implications for denitrification. 16th Nitrogen Workshop: Connecting different scales of nitrogen use in agriculture. Turin, Italy. (Eds.: Grignani, C., Acutis, M., Zavattaro, L., Bechini, L., Bertora, C., Gallina, P. M. and Sacco, D.), p. 11-12. Zsolnay, Á., 2003. Dissolved organic matter: artefacts, definitions, and functions. Geoderma 113, p. 187-209.

Groundwater-quality monitoring program in Chester County, Pennsylvania, 1980-2008

USGS Publications Warehouse

Senior, Lisa A.; Sloto, Ronald A.

2010-01-01

The U.S. Geological Survey in cooperation with the Chester County Water Resources Authority and the Chester County Health Department began a groundwater-quality monitoring program in 1980 in Chester County, Pa., where a large percentage of the population relies on wells for drinking-water supply. This report documents the program and serves as a reference for data collected through the program from 1980 through 2008. The initial focus of the program was to collect data on groundwater quality near suspected localized sources of contamination, such as uncontrolled landfills and suspected industrial wastes, to determine if contaminants were present that might pose a health risk to those using the groundwater. Subsequently, the program was expanded to address the effects of widely distributed contaminant sources associated with agricultural and residential land uses on groundwater quality and to document naturally occurring constituents, such as radium, radon, and arsenic, that are potential hazards in drinking water. Since 2000, base-flow stream samples have been collected in addition to well-water and spring samples in a few small drainage areas to investigate the relation between groundwater quality measured in well samples and streams. The program has primarily consisted of spatial assessment with limited temporal data collected on groundwater quality. Most data were collected through the monitoring program for reconnaissance purposes to identify and locate groundwater-quality problems and generally were not intended for rigorous statistical analyses that might determine land-use or geochemical factors affecting groundwater quality in space or through time. Results of the program found several contaminants associated with various land uses and human activities in groundwater in Chester County. Volatile organic compounds (such as trichloroethylene) were measured in groundwater near suspected localized contaminant sources in concentrations that exceeded drinking-water standards. Groundwater in some agricultural areas had concentrations of nitrate and some pesticides that exceeded drinking-water standards. Elevated concentrations of chloride were measured near salt storage areas and highways. Formaldehyde was detected in groundwater near cemeteries. In residential areas with on-site wastewater disposal, effects on groundwater quality included elevated nitrate concentrations and low concentrations of volatile organic compounds and wastewater compounds, such as antibiotics and detergents. Base-flow samples indicated that groundwater discharge to streams carried contaminants such as nitrate, pesticides, wastewater compounds, and other contaminants. Radionuclides, including radium-226, radium-228, radium-224, and radon-222, and gross alpha-particle activity were measured in groundwater at levels above established and proposed drinking-water standards in some geologic units, particularly in quartzite and quartzite schists. Arsenic concentrations above drinking-water standards were measured in a few samples and were most likely to occur in groundwater in the shales and sandstones in the northern part of the county. Other potential natural hazards, such as lead from aquifer materials or leached from plumbing because of pH, were present in concentrations above drinking-water standards infrequently (less than 10 percent of samples). Limited temporal sampling suggested that chloride concentrations in groundwater increased in the county since the program began in 1980 through 2008, reflecting increasing population and urbanization in that period.

The international scale of the groundwater issue

USGS Publications Warehouse

Fienen, Michael; Arshad, Muhammad

2016-01-01

Throughout history, and throughout the world, groundwater has been a major source of water for sustaining human life. Use of this resource has increased dramatically over the last century. In many areas of the world, the balance between human and ecosystem needs is difficult to maintain. Understanding the international scale of the groundwater issue requires metrics and analysis at a commensurate scale. Advances in remote sensing supplement older traditional direct measurement methods for understanding the magnitude of depletion, and all measurements motivate the need for common data standards to collect and share information. In addition to metrics of groundwater availability, four key international groundwater issues are depletion of water, degradation of water quality, the water-energy nexus, and transboundary water conflicts. This chapter is devoted to introducing these issues, which are also discussed in more detail in later chapters.

Groundwater-quality data from the eastern Snake River Plain Aquifer, Jerome and Gooding Counties, south-central Idaho, 2017

USGS Publications Warehouse

Skinner, Kenneth D.

2018-05-11

Groundwater-quality samples and water-level data were collected from 36 wells in the Jerome/Gooding County area of the eastern Snake River Plain aquifer during June 2017. The wells included 30 wells sampled for the U.S. Geological Survey’s National Water-Quality Assessment project, plus an additional 6 wells were selected to increase spatial distribution. The data provide water managers with the ability for an improved understanding of groundwater quality and flow directions in the area. Groundwater-quality samples were analyzed for nutrients, major ions, trace elements, and stable isotopes of water. Quality-assurance and quality-control measures consisted of multiple blank samples and a sequential replicate sample. All data are available online at the USGS National Water Information System.

Quality of groundwater in the Denver Basin aquifer system, Colorado, 2003-5

USGS Publications Warehouse

Musgrove, MaryLynn; Beck, Jennifer A.; Paschke, Suzanne; Bauch, Nancy J.; Mashburn, Shana L.

2014-01-01

Water-quality data were synthesized to evaluate factors that affect spatial and depth variability in water quality and to assess aquifer vulnerability to contaminants from geologic materials and those of human origin. The quality of shallow groundwater in the alluvial aquifer and shallow bedrock aquifer system has been adversely affected by development of agricultural and urban areas. Land use has altered the pattern and composition of recharge. Increased recharge from irrigation water has mobilized dissolved constituents and increased concentrations in the shallow groundwater. Concentrations of most constituents associated with poor or degraded water quality in shallow groundwater decreased with depth; many of these constituents are not geochemically conservative and are affected by geochemical reactions such as oxidation-reduction reactions. Groundwater age tracers provide additional insight into aquifer vulnerability and help determine if young groundwater of potentially poor quality has migrated to deeper parts of the bedrock aquifers used for drinking-water supply. Age-tracer results were used to group samples into categories of young, mixed, and old groundwater. Groundwater ages transitioned from mostly young in the water-table wells to mostly mixed in the shallowest bedrock aquifer, the Dawson aquifer, to mostly old in the deeper bedrock aquifers. Although the bedrock aquifers are mostly old groundwater of good water quality, several lines of evidence indicate that young, contaminant-bearing recharge has reached shallow to moderate depths in some areas of the bedrock aquifers. The Dawson aquifer is the most vulnerable of the bedrock aquifers to contamination, but results indicate that the older (deeper) bedrock aquifers are also vulnerable to groundwater contamination and that mixing with young recharge has occurred in some areas. Heavy pumping has caused water-level declines in the bedrock aquifers in some parts of the Denver Basin, which has the potential to enhance the transport of contaminants from overlying units. Results of this study are consistent with the existing conceptual understanding of aquifer processes and groundwater issues in the Denver Basin and add new insight into the vulnerability of the bedrock aquifers to groundwater contamination.

Y-12 Groundwater Protection Program Groundwater And Surface Water Sampling And Analysis Plan For Calendar Year 2010

DOE Office of Scientific and Technical Information (OSTI.GOV)

Elvado Environmental LLC

2009-09-01

This plan provides a description of the groundwater and surface water quality monitoring activities planned for calendar year (CY) 2010 at the U.S. Department of Energy (DOE) Y-12 National Security Complex (Y-12) that will be managed by the Y-12 Groundwater Protection Program (GWPP). Groundwater and surface water monitoring performed by the GWPP during CY 2010 will be in accordance with requirements of DOE Order 540.1A and the following goals: (1) to protect the worker, the public, and the environment; (2) to maintain surveillance of existing and potential groundwater contamination sources; (3) to provide for the early detection of groundwater contaminationmore » and determine the quality of groundwater and surface water where contaminants are most likely to migrate beyond the Oak Ridge Reservation property line; (4) to identify and characterize long-term trends in groundwater quality at Y-12; and (5) to provide data to support decisions concerning the management and protection of groundwater resources. Groundwater and surface water monitoring during CY 2010 will be performed primarily in three hydrogeologic regimes at Y-12: the Bear Creek Hydrogeologic Regime (Bear Creek Regime), the Upper East Fork Poplar Creek Hydrogeologic Regime (East Fork Regime), and the Chestnut Ridge Hydrogeologic Regime (Chestnut Ridge Regime). The Bear Creek and East Fork regimes are located in Bear Creek Valley, and the Chestnut Ridge Regime is located south of Y-12 (Figure A.1). Additional surface water monitoring will be performed north of Pine Ridge, along the boundary of the Oak Ridge Reservation. Modifications to the CY 2010 monitoring program may be necessary during implementation. Changes in programmatic requirements may alter the analytes specified for selected monitoring wells or may add or remove wells from the planned monitoring network. All modifications to the monitoring program will be approved by the Y-12 GWPP manager and documented as addenda to this sampling and analysis plan. The following sections of this report provide details regarding the CY 2010 groundwater and surface water monitoring activities. Section 2 describes the monitoring locations in each regime and the processes used to select the sampling locations. A description of the field measurements and laboratory analytes is provided in Section 3. Sample collection methods and procedures are described in Section 4, and Section 5 lists the documents cited for more detailed operational and technical information. The narrative sections of the report reference several appendices. Figures (maps and diagrams) and tables (excluding data summary tables presented in the narrative sections) are in Appendix A and Appendix B, respectively. Groundwater Monitoring Schedules (when issued throughout CY 2010) will be inserted in Appendix C, and addenda to this plan (if issued) will be inserted in Appendix D. Laboratory requirements (bottle lists, holding times, etc.) are provided in Appendix E, and an approved Waste Management Plan is provided in Appendix F.« less

Geochemical evolution processes and water-quality observations based on results of the National Water-Quality Assessment Program in the San Antonio segment of the Edwards aquifer, 1996-2006

USGS Publications Warehouse

Musgrove, MaryLynn; Fahlquist, Lynne; Houston, Natalie A.; Lindgren, Richard J.; Ging, Patricia B.

2010-01-01

As part of the National Water-Quality Assessment Program, the U.S. Geological Survey collected and analyzed groundwater samples during 1996-2006 from the San Antonio segment of the Edwards aquifer of central Texas, a productive karst aquifer developed in Cretaceous-age carbonate rocks. These National Water-Quality Assessment Program studies provide an extensive dataset of groundwater geochemistry and water quality, consisting of 249 groundwater samples collected from 136 sites (wells and springs), including (1) wells completed in the shallow, unconfined, and urbanized part of the aquifer in the vicinity of San Antonio (shallow/urban unconfined category), (2) wells completed in the unconfined (outcrop area) part of the regional aquifer (unconfined category), and (3) wells completed in and springs discharging from the confined part of the regional aquifer (confined category). This report evaluates these data to assess geochemical evolution processes, including local- and regional-scale processes controlling groundwater geochemistry, and to make water-quality observations pertaining to sources and distribution of natural constituents and anthropogenic contaminants, the relation between geochemistry and hydrologic conditions, and groundwater age tracers and travel time. Implications for monitoring water-quality trends in karst are also discussed. Geochemical and isotopic data are useful tracers of recharge, groundwater flow, fluid mixing, and water-rock interaction processes that affect water quality. Sources of dissolved constituents to Edwards aquifer groundwater include dissolution of and geochemical interaction with overlying soils and calcite and dolomite minerals that compose the aquifer. Geochemical tracers such as magnesium to calcium and strontium to calcium ratios and strontium isotope compositions are used to evaluate and constrain progressive fluid-evolution processes. Molar ratios of magnesium to calcium and strontium to calcium in groundwater typically increase along flow paths; results for samples of Edwards aquifer groundwater show an increase from shallow/urban unconfined, to unconfined, to confined groundwater categories. These differences are consistent with longer residence times and greater extents of water-rock interaction controlling fluid compositions as groundwater evolves from shallow unconfined groundwater to deeper confined groundwater. Results for stable isotopes of hydrogen and oxygen indicate specific geochemical processes affect some groundwater samples, including mixing with downdip saline water, mixing with recent recharge associated with tropical cyclonic storms, or mixing with recharge water than has undergone evaporation. The composition of surface water recharging the aquifer, as well as mixing with downdip water from the Trinity aquifer or the saline zone, also might affect water quality. A time-series record (1938-2006) of discharge at Comal Springs, one of the major aquifer discharge points, indicates an upward trend for nitrate and chloride concentrations, which likely reflects anthropogenic activities. A small number of organic contaminants were routinely or frequently detected in Edwards aquifer groundwater samples. These were the pesticides atrazine, its degradate deethylatrazine, and simazine; the drinking-water disinfection byproduct chloroform; and the solvent tetrachloroethene. Detection of these contaminants was most frequent in samples of the shallow/urban unconfined groundwater category and least frequent in samples of the unconfined groundwater category. Results indicate that the shallow/urban unconfined part of the aquifer is most affected by anthropogenic contaminants and the unconfined part of the aquifer is the least affected. The high frequency of detection for these anthropogenic contaminants aquifer-wide and in samples of deep, confined groundwater indicates that the entire aquifer is susceptible to water-quality changes as a result of anthropogenic activities. L

Placement of riparian forest buffers to improve water quality

Treesearch

Mark D. Tomer; Michael G. Dosskey; Michael R. Burkart; David E. James; Matthew J. Helmers; Dean E. Eisenhauer

2005-01-01

Riparian forest buffers can improve stream water quality, provided they intercept and remove contaminants from surface runoff and/or shallow groundwater. Soils, topography, hydrology, and surficial geology detemine the capability of forest buffers to intercept and treat these flows. This paper describes landscape analysis techniques for identifying and mapping...

Groundwater Pollution Sources Apportionment in the Ghaen Plain, Iran.

PubMed

Vesali Naseh, Mohammad Reza; Noori, Roohollah; Berndtsson, Ronny; Adamowski, Jan; Sadatipour, Elaheh

2018-01-22

Although Iran's Ghaen Plain provides saffron to much of the world, no regional groundwater quality (GQ) assessment has yet been undertaken. Given the region's potential for saltwater intrusion and heavy metal contamination, it is important to assess the GQ and determine its main probable source of pollution (MPSP). Such knowledge would allow for informed mitigation or elimination of the potential adverse health effects of this groundwater through its use as drinking water, or indirectly as a result of the consumption of groundwater-irrigated crops. Total dissolved solids, sodium, and chloride in the water of the majority of 16 wells sampled within the region exceeded World Health Organization and Iranian permissible standards for drinking water. The groundwater proved to only be suitable for irrigating salt tolerant crops under good drainage conditions. Due to the precipitation of calcium carbonate in the water supply facilities, the water from all wells was deemed unsuitable for industrial purposes. Heavy metal pollution and contamination indices showed no groundwater contamination. Analysis of ionic ratios and the application of principal components analysis indicated the MPSP to be saltwater intrusion, with the geology subtending the plain, and to a lesser extent, anthropogenic activities. Reducing groundwater withdrawals, particularly those for agricultural production by using high performance irrigation methods could reduce saltwater intrusion and improve GQ in the Ghaen Plain.

Seasonal and Spatial Variability of Anthropogenic and Natural Factors Influencing Groundwater Quality Based on Source Apportionment

PubMed Central

Guo, Xueru; Zuo, Rui; Meng, Li; Wang, Jinsheng; Teng, Yanguo; Liu, Xin; Chen, Minhua

2018-01-01

Globally, groundwater resources are being deteriorated by rapid social development. Thus, there is an urgent need to assess the combined impacts of natural and enhanced anthropogenic sources on groundwater chemistry. The aim of this study was to identify seasonal characteristics and spatial variations in anthropogenic and natural effects, to improve the understanding of major hydrogeochemical processes based on source apportionment. 34 groundwater points located in a riverside groundwater resource area in northeast China were sampled during the wet and dry seasons in 2015. Using principal component analysis and factor analysis, 4 principal components (PCs) were extracted from 16 groundwater parameters. Three of the PCs were water-rock interaction (PC1), geogenic Fe and Mn (PC2), and agricultural pollution (PC3). A remarkable difference (PC4) was organic pollution originating from negative anthropogenic effects during the wet season, and geogenic F enrichment during the dry season. Groundwater exploitation resulted in dramatic depression cone with higher hydraulic gradient around the water source area. It not only intensified dissolution of calcite, dolomite, gypsum, Fe, Mn and fluorine minerals, but also induced more surface water recharge for the water source area. The spatial distribution of the PCs also suggested the center of the study area was extremely vulnerable to contamination by Fe, Mn, COD, and F−. PMID:29415516

Determining sources of elevated salinity in pre-hydraulic fracturing water quality data using a multivariate discriminant analysis model

NASA Astrophysics Data System (ADS)

Lautz, L. K.; Hoke, G. D.; Lu, Z.; Siegel, D. I.

2013-12-01

Hydraulic fracturing has the potential to introduce saline water into the environment due to migration of deep formation water to shallow aquifers and/or discharge of flowback water to the environment during transport and disposal. It is challenging to definitively identify whether elevated salinity is associated with hydraulic fracturing, in part, due to the real possibility of other anthropogenic sources of salinity in the human-impacted watersheds in which drilling is taking place and some formation water present naturally in shallow groundwater aquifers. We combined new and published chemistry data for private drinking water wells sampled across five southern New York (NY) counties overlying the Marcellus Shale (Broome, Chemung, Chenango, Steuben, and Tioga). Measurements include Cl, Na, Br, I, Ca, Mg, Ba, SO4, and Sr. We compared this baseline groundwater quality data in NY, now under a moratorium on hydraulic fracturing, with published chemistry data for 6 different potential sources of elevated salinity in shallow groundwater, including Appalachian Basin formation water, road salt runoff, septic effluent, landfill leachate, animal waste, and water softeners. A multivariate random number generator was used to create a synthetic, low salinity (< 20 mg/L Cl) groundwater data set (n=1000) based on the statistical properties of the observed low salinity groundwater. The synthetic, low salinity groundwater was then artificially mixed with variable proportions of different potential sources of salinity to explore chemical differences between groundwater impacted by formation water, road salt runoff, septic effluent, landfill leachate, animal waste, and water softeners. We then trained a multivariate, discriminant analysis model on the resulting data set to classify observed high salinity groundwater (> 20 mg/L Cl) as being affected by formation water, road salt, septic effluent, landfill leachate, animal waste, or water softeners. Single elements or pairs of elements (e.g. Cl and Br) were not effective at discriminating between sources of salinity, indicating multivariate methods are needed. The discriminant analysis model classified most accurately samples affected by formation water and landfill leachate, whereas those contaminated by road salt, animal waste, and water softeners were more likely to be discriminated as contaminated by a different source. Using this approach, no shallow groundwater samples from NY appear to be affected by formation water, suggesting the source of salinity pre-hydraulic fracturing is primarily a combination of road salt, septic effluent, landfill leachate, and animal waste.

Effects of land use on quality of water in stratified-drift aquifers in Connecticut

USGS Publications Warehouse

Grady, Stephen J.

1994-01-01

Human activities associated with agricultural, residential, commercial, and industrial land uses have affected the quality of water in the four stratified-drift aquifers examined in Connecticut. A study to evaluate quantitatively the effects of human activities, expressed as land use, on regional ground-water quality was initiated in 1984 as part of the U.S. Geological Survey's Toxic Waste-round-Water Contamination Program. Water-quality data were collected from 116 shallow stainless-steel wells installed beneath or immediately downgradient from seven types of land use areas within the Pootatuck, Pomperaug, Farmington, and Hockanum River valleys in Connecticut. Analysis of variance on the ranked concentrations of 21 largely uncensored or slightly censored constituents, and contingency-table analysis of the frequency of detection of 49 moderately to highly censored constituents indicate that 27 water-quality variables differ at the 0.05 level of significance for samples from at least one land use area. For most constituents, concentrations or detection frequencies are lowest in samples from the undeveloped areas, which characterize background water-quality conditions. The effect of agricultural land use on groundwater quality reflects tillage practices; tilled areas affect the water quality to a greater degree than do untilled areas. Twenty percent of the wells in the tilled agricultural areas yielded water with concentrations of nitrate plus nitrite-nitrogen exceeding 10 milligrams per liter. Atrazine detections in one-third of the wells in areas of tilled agricultural land use were significantly more common than in the undeveloped areas. Ground-water quality beneath sewered residential areas is more severely affected by inorganic and organic nonpoint-source contaminants than is water quality beneath unsewered residential areas. Median concentrations or detection frequencies of most physical properties and inorganic constituents of ground water are higher in sewered than in unsewered residential areas. Generally low concentrations (less than 1.0 microgram per liter) of one or more of 17 volatile organic compounds were detected in samples from 62 percent of the wells in the unsewered residential areas. Most of these compounds were detected in less than 10 percent of the ground-water samples from the unsewered residential areas, however, and consequently, their frequency of detections was not significantly different than in samples from other land use areas. The detection of chloroform in ground-water samples from 47 percent of the wells in the sewered residential areas is significantly higher than the frequency of detection of chloroform in samples from the undeveloped, tilled agricultural, and unsewered residential areas. The quality of ground water is adversely affected beneath commercial areas more so than beneath all other land use areas. Median concentrations of sodium (22.5 milligrams per liter), chloride (36 milligrams per liter), and dissolved solids (286 milligrams per liter) are highest in ground-water samples in commercial areas. Detections of tetrachloroethylene, trichloroethylene, and 1,2-transdichloroethylene were significantly more common in ground-water samples from the commercial areas than in samples from one or more of the other land use areas. Tetrachloroethylene was detected in water samples from 50 percent of the observation wells in the commercial areas at concentrations of up to 1,300 micrograms per liter. Trichloroethylene and 1,2-transdichloroethylene were found at concentrations of up to 20 and 55 micrograms per liter, respectively, in samples from more than 40 percent of the wells in the commercial areas. Although industrial areas occupy only a small part of each of the study areas, they have a disproportionately large effect on ground-water quality. One or more of 12 volatile organic compounds were detected in water samples from 91 percent of the observation wells in the industrial areas

Fluor Hanford, Inc. Groundwater and Technical Integration Support (Master Project) Quality Assurance Management Plan

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fix, N. J.

The scope of the Fluor Hanford, Inc. Groundwater and Technical Integration Support (Master Project) is to provide technical and integration support to Fluor Hanford, Inc., including operable unit investigations at 300-FF-5 and other groundwater operable units, strategic integration, technical integration and assessments, remediation decision support, and science and technology. This Quality Assurance Management Plan provides the quality assurance requirements and processes that will be followed by the Fluor Hanford, Inc. Groundwater and Technical Integration Support (Master Project).

Impact of Coastal Development and Marsh Width Variability on Groundwater Quality in Estuarine Tidal Creeks

NASA Astrophysics Data System (ADS)

Shanahan, M.; Wilson, A. M.; Smith, E. M.

2017-12-01

Coastal upland development has been shown to negatively impact surface water quality in tidal creeks in the southeastern US, but less is known about its impact on groundwater. We sampled groundwater in the upland and along the marsh perimeter of tidal creeks located within developed and undeveloped watersheds. Samples were analyzed for salinity, dissolved organic carbon, nitrogen and phosphorus concentrations. Groundwater samples collected from the upland in developed and undeveloped watersheds were compared to study the impact of development on groundwater entering the marsh. Groundwater samples collected along the marsh perimeter were analyzed to study the impact of marsh width variability on groundwater quality within each creek. Preliminary results suggest a positive correlation between salinity and marsh width in undeveloped watersheds, and a higher concentration of nutrients in developed versus undeveloped watersheds.

Effect of Ditching, Fertilization, and Herbicide Application on Groundwater Levels and Groundwater Quality in a Flatwood Spodosol

Treesearch

D.S. Segal; D.G. Neary; G.R. Best; J.L. Michael

1987-01-01

Groundwater levels and associated water quality parameters were studied in a young slash pine (Pinus elliottii Engelm.) plantation following ditching, fertilization, and herbicide application. Drainage ditches surrounding each watershed significantly lowered groundwater levels up to 45 m from the ditch for mean and high water table conditions....

Ground-water flow and quality beneath sewage-sludge lagoons, and a comparison with the ground-water quality beneath a sludge-amended landfill, Marion County, Indiana

USGS Publications Warehouse

Bobay, K.E.

1988-01-01

The groundwater beneath eight sewage sludge lagoons, was studied to characterize the flow regime and to determine whether leachate had infiltrated into the glacio-fluvial sediments. Groundwater quality beneath the lagoons was compared with the groundwater quality beneath a landfill where sludge had been applied. The lagoons and landfills overlie outwash sand and gravel deposits separated by discontinuous clay layers. Shallow groundwater flows away from the lagoons and discharges into the White River. Deep groundwater discharges to the White River and flows southwest beneath Eagle Creek. After an accumulation of at least 2 inches of precipitation during 1 week, groundwater flow is temporarily reversed in the shallow aquifer, and all deep flow is along a relatively steep hydraulic gradient to the southwest. The groundwater is predominantly a calcium bicarbonate type, although ammonium accounts for more than 30% of the total cations in water from three wells. Concentrations of sodium, chloride, sulfate, iron, arsenic, boron, chemical oxygen demand, total dissolved solids, and methylene-blue-active substances indicate the presence of leachate in the groundwater. Concentrations of cadmium, chromium, copper, lead, mercury, nickel, selenium, and zinc were less than detection limits. The concentrations of 16 of 19 constituents or properties of groundwater beneath the lagoons are statistically different than groundwater beneath the landfill at the 0.05 level of significance. Only pH and concentrations of dissolved oxygen and bromide are higher in groundwater beneath the landfill than beneath the lagoons. 

Statistical robustness of machine-learning estimates for characterizing a groundwater-surface water system, Southland, New Zealand

NASA Astrophysics Data System (ADS)

Friedel, M. J.; Daughney, C.

2016-12-01

The development of a successful surface-groundwater management strategy depends on the quality of data provided for analysis. This study evaluates the statistical robustness when using a modified self-organizing map (MSOM) technique to estimate missing values for three hypersurface models: synoptic groundwater-surface water hydrochemistry, time-series of groundwater-surface water hydrochemistry, and mixed-survey (combination of groundwater-surface water hydrochemistry and lithologies) hydrostratigraphic unit data. These models of increasing complexity are developed and validated based on observations from the Southland region of New Zealand. In each case, the estimation method is sufficiently robust to cope with groundwater-surface water hydrochemistry vagaries due to sample size and extreme data insufficiency, even when >80% of the data are missing. The estimation of surface water hydrochemistry time series values enabled the evaluation of seasonal variation, and the imputation of lithologies facilitated the evaluation of hydrostratigraphic controls on groundwater-surface water interaction. The robust statistical results for groundwater-surface water models of increasing data complexity provide justification to apply the MSOM technique in other regions of New Zealand and abroad.

Groundwater quality in the glacial aquifer system, United States

USGS Publications Warehouse

Stackelberg, Paul E.

2017-12-07

Groundwater provides nearly 50 percent of the Nation’s drinking water. To help protect this vital resource, the U.S. Geological Survey (USGS) National Water-Quality Assessment (NAWQA) Project assesses groundwater quality in aquifers that are important sources of drinking water (Burow and Belitz, 2014). The glacial aquifer system constitutes one of the important areas being evaluated.

Status of groundwater quality in the San Fernando--San Gabriel study unit, 2005--California GAMA Priority Basin Project

USGS Publications Warehouse

Land, Michael; Kulongoski, Justin T.; Belitz, Kenneth

2012-01-01

Groundwater quality in the approximately 460-square-mile San Fernando--San Gabriel (FG) study unit was investigated as part of the Priority Basin Project of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The study area is in Los Angeles County and includes Tertiary-Quaternary sedimentary basins situated within the Transverse Ranges of southern California. The GAMA Priority Basin Project is being conducted by the California State Water Resources Control Board in collaboration with the U.S. Geological Survey (USGS) and the Lawrence Livermore National Laboratory. The GAMA FG study was designed to provide a spatially unbiased assessment of the quality of untreated (raw) groundwater in the primary aquifer systems (hereinafter referred to as primary aquifers) throughout California. The assessment is based on water-quality and ancillary data collected in 2005 by the USGS from 35 wells and on water-quality data from the California Department of Public Health (CDPH) database. The primary aquifers were defined by the depth interval of the wells listed in the CDPH database for the FG study unit. The quality of groundwater in primary aquifers may be different from that in the shallower or deeper water-bearing zones; shallow groundwater may be more vulnerable to surficial contamination. This study assesses the status of the current quality of the groundwater resource by using data from samples analyzed for volatile organic compounds (VOCs), pesticides, and naturally occurring inorganic constituents, such as major ions and trace elements. This status assessment is intended to characterize the quality of groundwater resources in the primary aquifers of the FG study unit, not the treated drinking water delivered to consumers by water purveyors.

Factors controlling stream water nitrate and phosphor loads during precipitation events

NASA Astrophysics Data System (ADS)

Rozemeijer, J. C.; van der Velde, Y.; van Geer, F. G.; de Rooij, G. H.; Broers, H. P.; Bierkens, M. F. P.

2009-04-01

Pollution of surface waters in densely populated areas with intensive land use is a serious threat to their ecological, industrial and recreational utilization. European and national manure policies and several regional and local pilot projects aim at reducing pollution loads to surface waters. For the evaluation of measures, water authorities and environmental research institutes are putting a lot of effort into monitoring surface water quality. Fro regional surface water quality monitoring, the measurement locations are usually situated in the downstream part of the catchment to represent a larger area. The monitoring frequency is usually low (e.g. monthly), due to the high costs for sampling and analysis. As a consequence, human induced trends in nutrient loads and concentrations in these monitoring data are often concealed by the large variability of surface water quality caused by meteorological variations. Because natural surface water quality variability is poorly understood, large uncertainties occur in the estimates of (trends in) nutrient loads or average concentrations. This study aims at uncertainty reduction in the estimates of mean concentrations and loads of N and P from regional monitoring data. For this purpose, we related continuous N and P records of stream water to variations in precipitation, discharge, groundwater level and tube drain discharge. A specially designed multi scale experimental setup was installed in an agricultural lowland catchment in The Netherlands. At the catchment outlet, continuous measurements of water quality and discharge were performed from July 2007-January 2009. At an experimental field within the catchment continuous measurements of precipitation, groundwater levels and tube drain discharges were collected. 20 significant rainfall events with a variety of antecedent conditions, durations and intensities were selected for analysis. Singular and multiple regression analysis was used to identify relations between the continuous N and P records and characteristics of the dynamics of discharge, precipitation, groundwater level and tube drain discharge. From this study, we conclude that generally available and easy to measure explanatory data (such as continuous records of discharge, precipitation and groundwater level) can reduce uncertainty in estimations of N and P loads and mean concentrations. However, for capturing the observed short load pulses of P, continuous or discharge proportional sampling is needed.

Concurrence of aqueous and gas phase contamination of groundwater in the Wattenberg oil and gas field of northern Colorado.

PubMed

Li, Huishu; Son, Ji-Hee; Carlson, Kenneth H

2016-01-01

The potential impact of rapid development of unconventional oil and natural gas resources using hydraulic fracturing and horizontal drilling on regional groundwater quality has received significant attention. Major concerns are methane or oil/gas related hydrocarbon (such as TPHs, BTEX including benzene, toluene, ethybenzene and xylene) leaks into the aquifer due to the failure of casing and/or stray gas migration. Previously, we investigated the relationship between oil and gas activity and dissolved methane concentration in a drinking water aquifer with the major finding being the presence of thermogenic methane contamination, but did not find detectable concentrations of TPHs or BTEX. To understand if aqueous and gas phases from the producing formation were transported concurrently to drinking water aquifers without the presence of oil/gas related hydrocarbons, the ionic composition of three water groups was studied: (1) uncontaminated deep confined aquifer, (2) suspected contaminated groundwater - deep confined aquifer containing thermogenic methane, and (3) produced water from nearby oil and gas wells that would represent aqueous phase contaminants. On the basis of quantitative and spatial analysis, we identified that the "thermogenic methane contaminated" groundwater did not have similarities to produced water in terms of ionic character (e.g. Cl/TDS ratio), but rather to the "uncontaminated" groundwater. The analysis indicates that aquifer wells with demonstrated gas phase contamination have not been contacted by an aqueous phase from oil and gas operations according to the methodology we use in this study and the current groundwater quality data from COGCC. However, the research does not prove conclusively that this the case. The results may provide insight on contamination mechanisms since improperly sealed well casing may result in stray gas but not aqueous phase transport. Copyright © 2015 Elsevier Ltd. All rights reserved.

Toxic aluminium and heavy metals in groundwater of middle Russia: health risk assessment.

PubMed

Momot, Olga; Synzynys, Boris

2005-08-01

Two approaches are distinguished in modern ecological monitoring. The first one is physicochemical analysis of environmental objects with respect to maximum allowable concentrations (MACs) of chemical substances, which is performed by standards methods in accordance with state regulations. The second approach (biological monitoring) is based on the methodology of biotesting and bio indication. The task of this work is to create biotests for estimation of Al and other metals toxicity in ground water and to compare these results with physicochemical analysis dates. Risk assessment for heavy metals contaminated groundwater was also performed. Risk assessment was performed accordingly EPA US recommendation and gave results about 90 per 100000 citizens for Al and 402 per 100000 for mixture of different heavy metals. For comparison: risk for earth background radiation for Middle Russia is (Individual dose 1 millisivert per year) consist 5 per 100000 people. It was shown that groundwater consist HCO3- ions (360 mg/l), sometimes Al compounds 0.21-0.65 mg/l (MAC for Al is 0.5 mg/l for Russia). Other groundwater contain Hg - 0.004 mg/l (MAC - 0.0005 mg/l); Cr - 0.072 mg/l (MAC - 0.05 mg/l); As - less than 0.03 mg/l (MAC - 0.05 mg/l). We developed plant biotest for estimation of groundwater quality with barley roots, tradescatia and others. Some biotests parameters correlate with HCO3-, Cl-, SO(4)2- and metal ions content positively, for another biotest this correlation is strongly negative. The quality of groundwater near Obninsk and in Kaluga Region is very different but hasnit been changed since the year 1998.

Permeable Asphalt: A New Tool to Reduce Road Salt Contamination of Groundwater in Urban Areas.

PubMed

Dietz, Michael E; Angel, Derek R; Robbins, Gary A; McNaboe, Lukas A

2017-03-01

Chloride contamination of groundwater in urban areas due to deicing is a well-documented phenomenon in northern climates. The objective of this study was to evaluate the effects of permeable pavement on degraded urban groundwater. Although low impact development practices have been shown to improve stormwater quality, no infiltration practice has been found to prevent road salt chlorides from entering groundwater. The few studies that have investigated chlorides in permeable asphalt have involved sampling directly beneath the asphalt; no research has looked more broadly at surrounding groundwater conditions. Monitoring wells were installed upgradient and downgradient of an 860 m 2 permeable asphalt parking lot at the University of Connecticut (Storrs, Connecticut). Water level and specific conductance were measured continuously, and biweekly samples were analyzed for chloride. Samples were also analyzed for sodium (Na), calcium (Ca), and magnesium (Mg). Analysis of variance analysis indicated a significantly (p < 0.001) lower geometric mean Cl concentration downgradient (303.7 mg/L) as compared to upgradient (1280 mg/L). Concentrations of all alkali metals increased upgradient and downgradient during the winter months as compared to nonwinter months, indicating that cation exchange likely occurred. Despite the frequent high peaks of chloride in the winter months as well as the increases in alkali metals observed, monitoring revealed lower Cl concentrations downgradient than upgradient for the majority of the year. These results suggest that the use of permeable asphalt in impacted urban environments with high ambient chloride concentrations can be beneficial to shallow groundwater quality, although these results may not be generalizable to areas with low ambient chloride concentrations. © 2016, National Ground Water Association.

Data collection and compilation for a geodatabase of groundwater, surface-water, water-quality, geophysical, and geologic data, Pecos County Region, Texas, 1930-2011

USGS Publications Warehouse

Pearson, Daniel K.; Bumgarner, Johnathan R.; Houston, Natalie A.; Stanton, Gregory P.; Teeple, Andrew; Thomas, Jonathan V.

2012-01-01

The U.S. Geological Survey, in cooperation with Middle Pecos Groundwater Conservation District, Pecos County, City of Fort Stockton, Brewster County, and Pecos County Water Control and Improvement District No. 1, compiled groundwater, surface-water, water-quality, geophysical, and geologic data for site locations in the Pecos County region, Texas, and developed a geodatabase to facilitate use of this information. Data were compiled for an approximately 4,700 square mile area of the Pecos County region, Texas. The geodatabase contains data from 8,242 sampling locations; it was designed to organize and store field-collected geochemical and geophysical data, as well as digital database resources from the U.S. Geological Survey, Middle Pecos Groundwater Conservation District, Texas Water Development Board, Texas Commission on Environmental Quality,and numerous other State and local databases. The geodatabase combines these disparate database resources into a simple data model. Site locations are geospatially enabled and stored in a geodatabase feature class for cartographic visualization and spatial analysis within a Geographic Information System. The sampling locations are related to hydrogeologic information through the use of geodatabase relationship classes. The geodatabase relationship classes provide the ability to perform complex spatial and data-driven queries to explore data stored in the geodatabase.

Quality-Assurance Plan for Water-Quality Activities of the U.S. Geological Survey Montana Water Science Center

USGS Publications Warehouse

Lambing, John H.

2006-01-01

In accordance with guidelines set forth by the Office of Water Quality in the Water Resources Discipline of the U.S. Geological Survey (USGS), a quality-assurance plan has been created for use by the USGS Montana Water Science Center in conducting water-quality activities. This quality-assurance plan documents the standards, policies, and procedures used by the USGS Montana Water Science Center for activities related to the collection, processing, storage, analysis, and publication of water-quality data. The policies and procedures presented in this quality-assurance plan for water-quality activities complement the quality-assurance plans for surface-water and ground-water activities and suspended-sediment analysis.

Evaluation of subsurface exploration, sampling, and water-quality-analysis methods at an abandoned wood-preserving plant site at Jackson, Tennessee

USGS Publications Warehouse

Parks, W.S.; Carmichael, J.K.; Mirecki, J.E.

1993-01-01

Direct Push Technology (DPT) and a modified-auger method of sampling were used at an abandoned wood-preserving plant site at Jackson, Tennessee, to collect lithologic data and ground-water samples in an area known to be affected by a subsurface creosote plume. The groundwater samples were analyzed using (1) gas chromatography with photo-ionization detection (GS/PID), (2) high- performance liquid chromatography (HPLC), (3) colonmetric phenol analysis, and (4) toxicity bioassay. DPT piezocone and cone-penetrometer-type tools provided lithologic data and ground-water samples at two onsite stations to a depth of refusal of about 35 feet below land surface. With the assistance of an auger rig, this depth was extended to about 65 feet by pushing the tools in advance of the augers. Following the DPT work, a modified-auger method was tested by the USGS. This method left doubt as to the integrity of the samples collected once zones of contamination were penetrated. GC/PID and HPLC methods of water-quality analysis provided the most data concerning contaminants in the ground-water and proved to be the most effective in creosote plume detection. Analyses from these methods showed that the highest concentrations of contaminants were detected at depths less than about 35 feet below land surface. Phenol analyses provided data supplemental to the HPLC analyses. Bioassay data indicated that toxicity associated with the plume extended to depths of about 55 feet below land surface.

Monitoring-well network and sampling design for ground-water quality, Wind River Indian Reservation, Wyoming

USGS Publications Warehouse

Mason, Jon P.; Sebree, Sonja K.; Quinn, Thomas L.

2005-01-01

The Wind River Indian Reservation, located in parts of Fremont and Hot Springs Counties, Wyoming, has a total land area of more than 3,500 square miles. Ground water on the Wind River Indian Reservation is a valuable resource for Shoshone and Northern Arapahoe tribal members and others who live on the Reservation. There are many types of land uses on the Reservation that have the potential to affect the quality of ground-water resources. Urban areas, rural housing developments, agricultural lands, landfills, oil and natural gas fields, mining, and pipeline utility corridors all have the potential to affect ground-water quality. A cooperative study was developed between the U.S. Geological Survey and the Wind River Environmental Quality Commission to identify areas of the Reservation that have the highest potential for ground-water contamination and develop a comprehensive plan to monitor these areas. An arithmetic overlay model for the Wind River Indian Reservation was created using seven geographic information system data layers representing factors with varying potential to affect ground-water quality. The data layers used were: the National Land Cover Dataset, water well density, aquifer sensitivity, oil and natural gas fields and petroleum pipelines, sites with potential contaminant sources, sites that are known to have ground-water contamination, and National Pollutant Discharge Elimination System sites. A prioritization map for monitoring ground-water quality on the Reservation was created using the model. The prioritization map ranks the priority for monitoring ground-water quality in different areas of the Reservation as low, medium, or high. To help minimize bias in selecting sites for a monitoring well network, an automated stratified random site-selection approach was used to select 30 sites for ground-water quality monitoring within the high priority areas. In addition, the study also provided a sampling design for constituents to be monitored, sampling frequency, and a simple water-table level observation well network.

Groundwater quality assessment using geoelectrical and geochemical approaches: case study of Abi area, southeastern Nigeria

NASA Astrophysics Data System (ADS)

Ebong, Ebong D.; Akpan, Anthony E.; Emeka, Chimezie N.; Urang, Job G.

2017-09-01

The electrical resistivity technique which involved the Schlumberger depth sounding method and geochemical analyses of water samples collected from boreholes was used to investigate the suitability of groundwater aquifers in Abi for drinking and irrigation purposes. Fifty randomly located electrical resistivity data were collected, modeled, and interpreted after calibration with lithologic logs. Ten borehole water samples were collected and analysed to determine anion, cation concentrations and some physical and chemical parameters, such as water colour, temperature, total dissolved solids, and electrical conductivity. The results show that the lithostratigraphy of the study area is composed of sands, sandstones (fractured, consolidated and loosed), siltstones, shales (compacted and fractured) of the Asu River Group, Eze-Aku Formation which comprises the aquifer units, and the Nkporo Shale Formation. The aquifer conduits are known to be rich in silicate minerals, and the groundwater samples in some locations show a significant amount of Ca2+, Mg2+, and Na+. These cations balanced the consumption of H+ during the hydrolytic alteration of silicate minerals. The geochemical analysis of groundwater samples revealed dominant calcium-magnesium-carbonate-bicarbonate water facies. Irrigation water quality parameters, such as sodium absorption ratio, percentage of sodium, and permeability index, were calculated based on the physico-chemical analyses. The groundwater quality was observed to be influenced by the interaction of some geologic processes but was classified to be good to excellent, indicating its suitability for domestic and irrigation purposes.

Impacts of a Rural Subdivision on Groundwater Quality: Results of Long-Term Monitoring.

PubMed

Rayne, Todd W; Bradbury, Kenneth R; Krause, Jacob J

2018-03-30

A rural subdivision in south central Wisconsin was instrumented with monitoring wells and lysimeters before, during, and after its construction to examine the impacts of the unsewered subdivision on groundwater quality and quantity. Prior to construction, the 78-acre (32 ha) site was farmland. Sixteen homes were constructed beginning in 2003. Initial monitoring from 2002 to 2005 showed that groundwater beneath the site had been impacted by previous agricultural use, with nitrate-N values as high as 30 mg/L and some detections of the herbicide atrazine. Our 12-year study shows that the transition from agricultural to residential land use has changed groundwater quality in both negative and positive ways. Although groundwater elevations showed typical seasonal fluctuations each year, there were no measurable changes in groundwater levels or general flow directions during the 12-year study period. Chloride values increased in many wells, possibly as a result of road salting or water softener discharge. Nitrate concentrations varied spatially and temporally over the study period, with some initial concentrations substantially above the drinking water standard. In some wells, nitrate and atrazine levels have declined substantially since agriculture ceased. However, atrazine was still present at trace concentrations throughout the site in 2014. Wastewater tracers show there are small but detectable impacts from septic effluent on groundwater quality. Particle traces based on a groundwater flow model are consistent with the hypothesis that septic leachate has impacted groundwater quality. © 2018, National Ground Water Association.

Appraisal of ground-water quality near wastewater-treatment facilities, Glacier National Park, Montana

USGS Publications Warehouse

Moreland, Joe A.; Wood, Wayne A.

1982-01-01

Water-level and water-quality data were collected from monitoring wells at wastewater-treatment facilities in Glacier National Park. Five additional shallow observation wells were installed at the Glacier Park Headquarters facility to monitor water quality in the shallow ground-water system.Water-level, water-quality, and geologic information indicate that some of the initial monitoring wells are not ideally located to sample ground water most likely to be affected by waste disposal at the sites. Small differences in chemical characteristics between samples from monitor wells indicate that effluent may be affecting ground-water quality but that impacts are not significant.Future monitoring of ground-water quality could be limited to selected wells most likely to be impacted by percolating effluent. Laboratory analyses for common ions could detect future impacts.

Groundwater Ecosystems Vary with Land Use across a Mixed Agricultural Landscape.

PubMed

Korbel, K L; Hancock, P J; Serov, P; Lim, R P; Hose, G C

2013-01-01

Changes in surface land use may threaten groundwater quality and ecosystem integrity, particularly in shallow aquifers where links between groundwater and surface activities are most intimate. In this study we examine the response of groundwater ecosystem to agricultural land uses in the shallow alluvial aquifer of the Gwydir River valley, New South Wales, Australia. We compared groundwater quality and microbial and stygofauna assemblages among sites under irrigated cropping, non-irrigated cropping and grazing land uses. Stygofauna abundance and richness was greatest at irrigated sites, with the composition of the assemblage suggestive of disturbance. Microbial assemblages and water quality also varied with land use. Our study demonstrates significant differences in the composition of groundwater ecosystems in areas with different surface land use, and highlights the utility of groundwater biota for biomonitoring, particularly in agricultural landscapes. Copyright © by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, Inc.

Microbial analysis of in situ biofilm formation in drinking water distribution systems: implications for monitoring and control of drinking water quality.

PubMed

Douterelo, Isabel; Jackson, M; Solomon, C; Boxall, J

2016-04-01

Biofilm formation in drinking water distribution systems (DWDS) is influenced by the source water, the supply infrastructure and the operation of the system. A holistic approach was used to advance knowledge on the development of mixed species biofilms in situ, by using biofilm sampling devices installed in chlorinated networks. Key physico-chemical parameters and conventional microbial indicators for drinking water quality were analysed. Biofilm coverage on pipes was evaluated by scanning electron microscopy (SEM) and confocal laser scanning microscopy (CLSM). The microbial community structure, bacteria and fungi, of water and biofilms was assessed using pyrosequencing. Conventional wisdom leads to an expectation for less microbial diversity in groundwater supplied systems. However, the analysis of bulk water showed higher microbial diversity in groundwater site samples compared with the surface water site. Conversely, higher diversity and richness were detected in biofilms from the surface water site. The average biofilm coverage was similar among sites. Disinfection residual and other key variables were similar between the two sites, other than nitrates, alkalinity and the hydraulic conditions which were extremely low at the groundwater site. Thus, the unexpected result of an exceptionally low diversity with few dominant genera (Pseudomonas and Basidiobolus) in groundwater biofilm samples, despite the more diverse community in the bulk water, is attributed to the low-flow hydraulic conditions. This finding evidences that the local environmental conditions are shaping biofilm formation, composition and amount, and hence managing these is critical for the best operation of DWDS to safeguard water quality.

Hydrogeological evaluation of an over-exploited aquifer in Dhaka, Bangladesh towards the implementation of groundwater artificial recharge

NASA Astrophysics Data System (ADS)

Azizur Rahman, M.; Rusteberg, Bernd; Sauter, Martin

2010-05-01

The population of Dhaka City is presently about 12 million and according to present trends in population growth, that number will most likely increase to 17.2 million by the year 2025. A serious water crisis is expected due to the extremely limited quality and quantity of water resources in the region. Previous studies have shown that the current trend in groundwater resource development is non-sustainable due to over-exploitation of the regional aquifer system, resulting in rapidly decreasing groundwater levels of about 2 to 3 meters per year. Today, annual groundwater extraction clearly exceeds natural groundwater recharge. New water management strategies are needed to guarantee future generations of Dhaka City a secured and sustained water supply as well as sustainable development of the city. The implementation of groundwater artificial recharge (AR) is one potential measure. As the first step towards a new water management strategy for Dhaka City, the authors report on the hydrogeological conditions of the greater Dhaka region and from this are able to present the location of potential recharge sites and identify appropriate recharge technologies for AR implementation. The aquifers of greater Dhaka can be grouped in three major categories: Holocene Deposit, Pleistocene Deposit and Plio-Pleistocene Deposit. The aquifers are generally thick and multilayered with relatively high transmissivity and storage coefficients. AR is considered feasible due to the fact these aquifers are alluvium deposit aquifers which characteristically have moderate to high hydraulic conductivity. Low costs for recovery of recharged water and large recharge volume capacity are generally associated with aquifers of unconsolidated sediments. Spatial analysis of the region has shown that Karaniganj, Kotoali, Savar, Dhamrai, Singair upazila, which are situated in greater Dhaka region and close to Dhaka City, could serve as recharge sites to the subsurface by pond infiltration technique. A study involving the use of a 3-D mathematical model shows that the abstraction or recharge in the area within and around Dhaka City does not affect the groundwater level below the city. Therefore, in order to improve the groundwater level, artificial groundwater recharge directly at the city area would be mostly appropriate. As the thickness of the surface impermeable layer varies from 5 m to 45 m, the combination of infiltration and injection technology would be a proper choice. Detailed studies are required using the most appropriate state of the art spatial analysis to support the final selection and ranking of suitable locations for the AR facilities, according to flood risk, urbanization, underground characteristics, water sources, AR technology and later use of the recovered water. Groundwater quality data reveal that the upper aquifer below Dhaka City contains relatively high concentrations of dissolved ions, quite variable in space. The ground water is predominantly of Ca-Mg-HCO3 type. Cation exchange and oxidation may enhance the biogeochemical processes in the aquifer under the existing prevailing conditions. Many reports conclude that that the groundwater chemistry of the upper aquifer has been influenced by various anthropogenic processes, showing wide variations of groundwater quality depending on the area, which would complicate the implementation of AR projects. The preliminary evaluation of the potential for AR implementation, considering environmental and social impacts, as well as the available water sources for infiltration and injection (conventional or non-conventional), AR may be considered a viable response measure with regards to the problems Dhaka City is facing. Without the implementation of groundwater artificial recharge or similar measures, groundwater availability and groundwater quality will further decrease and serious water crisis are to be expected. Measures to avoid groundwater contamination must also be taken to complement the benefits provided by AR implementation.

Determination of toxic inorganic elements pollution in ground waters of Kahuta Industrial Triangle Islamabad, Pakistan using inductively coupled plasma mass spectrometry.

PubMed

Kausar, Rubina; Ahmad, Zulfiqar

2009-10-01

The present study deals with the ground water quality assessment in Kahuta Industrial Triangle Islamabad, Pakistan. The objective of the study was to assess ground water quality against the drinking water standards for various toxic inorganic elements. Representative groundwater samples were collected and analyzed in the Water Quality Laboratory of Pakistan Council of Research in Water Resources (PCRWR) at Islamabad, Pakistan. The samples were run on ICP-MS (Inductively coupled plasma mass spectrometry), which has the capability to separate and quantify 70 elements at a time. One of the finding of study is that ICP-MS is a very good tool to analyze broad range of toxic inorganic elements to the level of parts per billion (ppb). World Health Organization drinking water standards shows that these toxic inorganic elements such as heavy metals even at this concentration level (ppb) are injurious to human health. This analysis indicated pollution of various toxic elements including Selenium. Vertical leachate through industrial waste septic tanks is identified as major cause of groundwater pollution in the Industrial Triangle. Monitoring of the septic tanks and groundwater quality in study area is suggested along with remedial measures.

Groundwater quality in the Rio Grande aquifer system, southwestern United States

USGS Publications Warehouse

Musgrove, MaryLynn; Bexfield, Laura M.

2017-12-07

Groundwater provides nearly 50 percent of the Nation’s drinking water. To help protect this vital resource, the U.S. Geological Survey (USGS) National Water-Quality Assessment (NAWQA) Project assesses groundwater quality in aquifers that are important sources of drinking water (Burow and Belitz, 2014). The Rio Grande aquifer system constitutes one of the important areas being evaluated.

Groundwater quality in the Cambrian-Ordovician aquifer system, midwestern United States

USGS Publications Warehouse

Stackelberg, Paul E.

2017-12-07

Groundwater provides nearly 50 percent of the Nation’s drinking water. To help protect this vital resource, the U.S. Geological Survey (USGS) National Water-Quality Assessment (NAWQA) Project assesses groundwater quality in aquifers that are important sources of drinking water (Burow and Belitz, 2014). The Cambrian-Ordovician aquifer system constitutes one of the important areas being evaluated.

Ground-water hydrology and water quality of the southern high plains aquifer, Melrose Air Force Range, Cannon Air Force Base, Curry and Roosevelt Counties, New Mexico, 2002-03

USGS Publications Warehouse

Langman, Jeff B.; Gebhardt, Fredrick E.; Falk, Sarah E.

2004-01-01

In cooperation with the U.S. Air Force, the U.S. Geological Survey characterized the ground-water hydrology and water quality at Melrose Air Force Range in east-central New Mexico. The purpose of the study was to provide baseline data to Cannon Air Force Base resource managers to make informed decisions concerning actions that may affect the ground-water system. Five periods of water-level measurements and four periods of water-quality sample collection were completed at Melrose Air Force Range during 2002 and 2003. The water-level measurements and water-quality samples were collected from a 29-well monitoring network that included wells in the Impact Area and leased lands of Melrose Air Force Range managed by Cannon Air Force Base personnel. The purpose of this report is to provide a broad overview of ground-water flow and ground-water quality in the Southern High Plains aquifer in the Ogallala Formation at Melrose Air Force Range. Results of the ground-water characterization of the Southern High Plains aquifer indicated a local flow system in the unconfined aquifer flowing northeastward from a topographic high, the Mesa (located in the southwestern part of the Range), toward a regional flow system in the unconfined aquifer that flows southeastward through the Portales Valley. Ground water was less than 55 years old across the Range; ground water was younger (less than 25 years) near the Mesa and ephemeral channels and older (25 years to 55 years) in the Portales Valley. Results of water-quality analysis indicated three areas of different water types: near the Mesa and ephemeral channels, in the Impact Area of the Range, and in the Portales Valley. Within the Southern High Plains aquifer, a sodium/chloride-dominated ground water was found in the center of the Impact Area of the Range with water-quality characteristics similar to ground water from the underlying Chinle Formation. This sodium/chloride-dominated ground water of the unconfined aquifer in the Impact Area indicates a likely connection with the deeper water-producing zone. No pesticides, explosives, volatile organic compounds, semivolatile organic compounds, organic halogens, or perchlorate were found in water samples from the Southern High Plains aquifer at the Range.

A methodology for space-time classification of groundwater quality.

PubMed

Passarella, G; Caputo, M C

2006-04-01

Safeguarding groundwater from civil, agricultural and industrial contamination is matter of great interest in water resource management. During recent years, much legislation has been produced stating the importance of groundwater as a source for drinking water supplies, underlining its vulnerability and defining the required quality standards. Thus, schematic tools, able to characterise the quality and quantity of groundwater systems, are of very great interest in any territorial planning and/or water resource management activity. This paper proposes a groundwater quality classification method which has been applied to a real aquifer, starting from several studies published by the Italian National Hydrogeologic Catastrophe Defence Group (GNDCI). The methodology is based on the concentration values of several parameters used as indexes of the natural hydro-chemical water condition and of potential man-induced modifications of groundwater quality. The resulting maps, although representative of the quality, do not include any information on its evolution in time. In this paper, this "stationary" classification method has been improved by crossing the quality classes with three indexes of temporal behaviour during recent years. It was then applied to data from monitoring campaigns, performed in spring and autumn, from 1990 to 1996, in the plain of Modena aquifer (central Italy). The results are reported in the form of space-time classification table and maps.

Water quality analysis of groundwater in crystalline basement rocks, Northern Ghana

USGS Publications Warehouse

Anku, Y.S.; Banoeng-Yakubo, B.; Asiedu, D.K.; Yidana, S.M.

2009-01-01

Hydrochemical data are presented for groundwater samples, collected from fractured aquifers in parts of northern Ghana. The data was collected to assess the groundwater suitability for domestic and agricultural use. Results of the study reveal that the pH of the groundwater in the area is slightly acidic to slightly alkaline. The electrical conductivity values, total dissolved solids (TDS) values and calcium, magnesium and sodium concentrations in the groundwater are generally below the limit set by the WHO for potable water supply. On the basis of activity diagrams, groundwater from the fractured aquifers appears to be stable within the montmorillonite field, suggesting weathering of silicate minerals. An inverse distance weighting interpolator with a power of 2 was applied to the data points to produce prediction maps for nitrate and fluoride. The distribution maps show the presence of high nitrate concentrations (50-194??mg/l) in some of the boreholes in the western part of the study area indicating anthropogenic impact on the groundwater. Elevated fluoride level (1.5-4??mg/l), higher than the WHO allowable fluoride concentration of 1.5, is recorded in the groundwater underlying the northeastern part of the study area, more specifically Bongo and its surrounding communities of the Upper East region. Results of this study suggest that groundwater from the fractured aquifers in the area exhibit low sodicity-low salinity (S1-C1), low sodicity-medium salinity (S1-C2) characteristics [United States Salinity Laboratory (USSL) classification scheme]. All data points from this study plot within the 'Excellent to good' category on a Wilcox diagram. Groundwater in this area thus appears to provide irrigation water of excellent quality. The hydrochemical results indicate that, although nitrate and fluoride concentrations in some boreholes are high, the groundwater in the study area, based on the parameters analyzed, is chemically potable and suitable for domestic and agricultural purposes. ?? Springer-Verlag 2008.

Vadose Zone Monitoring as a Key to Groundwater Protection from Pollution Hazard

NASA Astrophysics Data System (ADS)

Dahan, Ofer

2016-04-01

Minimization subsurface pollution is much dependent on the capability to provide real-time information on the chemical and hydrological properties of the percolating water. Today, most monitoring programs are based on observation wells that enable data acquisitions from the saturated part of the subsurface. Unfortunately, identification of pollutants in well water is clear evidence that the contaminants already crossed the entire vadose-zone and accumulated in the aquifer water to detectable concentration. Therefore, effective monitoring programs that aim at protecting groundwater from pollution hazard should include vadose zone monitoring technologies that are capable to provide real-time information on the chemical composition of the percolating water. Obviously, identification of pollution process in the vadose zone may provide an early warning on potential risk to groundwater quality, long before contaminates reach the water-table and accumulate in the aquifers. Since productive agriculture must inherently include down leaching of excess lower quality water, understanding the mechanisms controlling transport and degradation of pollutants in the unsaturated is crucial for water resources management. A vadose-zone monitoring system (VMS), which was specially developed to enable continuous measurements of the hydrological and chemical properties of percolating water, was used to assess the impact of various agricultural setups on groundwater quality, including: (a) intensive organic and conventional greenhouses, (b) citrus orchard and open field crops , and (c) dairy farms. In these applications frequent sampling of vadose zone water for chemical and isotopic analysis along with continuous measurement of water content was used to assess the link between agricultural setups and groundwater pollution potential. Transient data on variation in water content along with solute breakthrough at multiple depths were used to calibrate flow and transport models. These models where then used to assess the long term impact of various agricultural setups on the quantity and quality of groundwater recharge. Relevant publications: Turkeltaub et al., WRR. 2016; Turkeltaub et al., J. Hydrol. 2015: Dahan et al., HESS 2014. Baram et al., J. Hydrol. 2012.

The Impact of Climate Change on Groundwater Resources and Groundwater Quality in the Patcham Catchment, England.

NASA Astrophysics Data System (ADS)

Phillips, R. J.; Smith, M.; Pope, D. J.; Gumm, L.

2012-04-01

The CLIMAWAT project is an EU-Regional Development Fund Interreg IV funded research programme to study the impacts of climate change on groundwater resources and groundwater quality from the Chalk aquifer of SE England. The use of partially treated wastewater for artificial recharge will also be extensively studied in both the field and laboratory. The Chalk is a major aquifer and regionally supplies 70% of potable water supplies. The long term sustainable use of this resource is of paramount importance and the outcomes of this project will better inform and enhance long term management strategies for this. Project partners include water companies, regulatory bodies and industry consultancies. The four main objectives of the CLIMAWAT project are: i) better improve the prediction of the impact of climate change on this groundwater resource; ii) better understand and quantify how recharge mechanisms will vary due to the uncertainty associated with climate change; iii) better understand the storage mechanisms and fate of contaminants (e.g. nitrates and pesticides) in this aquifer and iv) investigate the impact of using partially treated wastewater for artificial recharge. An extensive field monitoring and data collection programme is underway in the Patcham Catchment (SE of England). Simultaneous monitoring of climatic, unsaturated zone potentiometric, groundwater level and chemistry data will allow for a better understanding of how changes in recharge patterns will effect groundwater quality and quantity. Isoptopic analysis of sampled groundwaters has allowed for interpretations and a better understanding of the storage and movement of water through this aquifer. The laboratory experimental programme is also underway and the results from this will compliment the field based studies to further enhance the understanding of contaminant behaviour in the both unsaturated and saturated zones. Core experiments are being used to investigate how nutrient and other contaminants are transported and retained in the Chalk aquifer. The results of which will better help understand how these contaminants are transported and held in the Chalk matrix and will provide quantitative information on the risk associated with the use of partially treated wastewater for artificial recharge and the contamination of groundwater reserves. This poster will present the findings of the research project so far.

Assessment and modeling of groundwater quality using WQI and GIS in Upper Egypt area.

PubMed

Rabeiy, Ragab ElSayed

2017-04-04

The continuous growth and development of population need more fresh water for drinking, irrigation, and domestic in arid countries like Egypt. Evaluation the quality of groundwater is an essential study to ensure its suitability for different purposes. In this study, 812 groundwater samples were taken within the middle area of Upper Egypt (Sohag Governorate) to assess the quality of groundwater for drinking and irrigation purposes. Eleven water parameters were analyzed at each groundwater sample (Na + , K + , Ca 2+ , Mg 2+ , HCO 3 - SO 4 2- , Fe 2+ , Mn 2+ , Cl - , electrical conductivity, and pH) to exploit them in water quality evaluation. A classical statistics were applied for the raw data to examine the distribution of physicochemical parameters in the investigated area. The relationship between groundwater parameters was tested using the correlation coefficient where a strong relationship was found between several water parameters such as Ca 2+ and Cl - . Water quality index (WQI) is a mathematical model used to transform many water parameters into a single indicator value which represents the water quality level. Results of WQI showed that 20% of groundwater samples are excellent, 75% are good for drinking, and 7% are very poor water while only 1% of samples are unsuitable for drinking. To test the suitability of groundwater for irrigation, three indices are used; they are sodium adsorption ration (SAR), sodium percentage (Na%), and permeability index (PI). For irrigation suitability, the study proved that most sampling sites are suitable while less than 3% are unsuitable for irrigation. The spatial distribution of the estimated values of WQI, SAR, Na%, PI, and each groundwater parameter was spatially modeled using GIS.

Impacts of land-use and soil properties on groundwater quality in the hard rock aquifer of an irrigated catchment: the Berambadi (Southern India)

NASA Astrophysics Data System (ADS)

Buvaneshwari, Sriramulu; Riotte, Jean; Ruiz, Laurent; Sekhar, Muddu; Sharma, Amit Kumar; Duprey, Jean Louis; Audry, Stephane; Braun, Jean Jacques; Mohan Kumar, Mandalagiri S.

2017-04-01

Irrigated agriculture has large impacts on groundwater resources, both in terms of quantity and quality: when combined with intensive chemical fertilizer application, it can lead to progressive groundwater salinization. Mapping the spatial heterogeneity of groundwater quality is not only essential for assessing the impacts of different types of agricultural systems but also for identifying hotspots of water quality degradation that are posing a risk to human and ecosystem health. In peninsular India the development of minor irrigation led to high density of borewells which constitute an ideal situation for studying the heterogeneity of groundwater quality. The annual groundwater abstraction reaches 400 km3, which leads to depletion of the resource and degradation of water quality. In the agricultural Berambadi catchment (84km2, Southern India, part of the environmental observatory BVET/ Kabini CZO) the groundwater table level and chemistry are monitored in 200 tube wells. We recently demonstrated that in this watershed, irrigation history and groundwater depletion can lead to hot spots of NO3 concentration in groundwater, up to 360 ppm (Buvaneshwari et al., 2017). Here we focus on the respective roles of evapotranspiration, groundwater recycling and chemical fertilizer application on chlorine concentration [Cl] in groundwater. Groundwater [Cl] in Berambadi spans over two orders of magnitude with hotspots up to 380 ppm. Increase in groundwater [Cl] results from evapotranspiration and recycling, that concentrates the rain Cl inputs ("Natural [Cl]") and/or from KCl fertilization ("Anthropogenic [Cl]"). To quantify the origin of Cl in each tube well, we used a novel method based on (1) a reference element, sodium, originating only from atmosphere and Na-plagioclase weathering and (2) data from a nearby pristine site, the Mule Hole forested watershed (Riotte et al., 2014). In the forested watershed, the ranges of Cl concentration and Na/Cl molar ratio are 9-23 ppm and 2.5-6, respectively, while in Berambadi Na/Cl drops down to 0.3 due to the addition of KCl-chlorine. Natural [Cl] estimated in Berambadi groundwater was on average 44 ppm (from 8 to 170 ppm). This means that on average, evapotranspiration and recycling in Berambadi groundwater was 2 to 4 times greater than evapotranspiration in the nearby forest. Hot spots (8 to 20 times forest ET) were all located along the stream, associated with Vertisols and long irrigation history. Anthropogenic [Cl] ranged from 0 to 270 ppm, accounting for up to 90% of the total Cl in some wells. Hotspots were also associated with long irrigation history, however extreme values were found in the severely depleted groundwater area, associated with the nitrate hotspot. Our approach allowed to quantify the respective contributions of groundwater recycling and chemical fertilizer inputs to the progressive salinization of groundwater. Using the AICHA model coupling the crop model STICS and a groundwater model under different climate scenarios, we show that the development of contamination hot spots can be mitigated by adequate management options. Keywords: Groundwater quality; salinization; agriculture; hot spots

Assessment of groundwater quality and evaluation of scaling and corrosiveness potential of drinking water samples in villages of Chabahr city, Sistan and Baluchistan province in Iran.

PubMed

Abbasnia, Abbas; Alimohammadi, Mahmood; Mahvi, Amir Hossein; Nabizadeh, Ramin; Yousefi, Mahmood; Mohammadi, Ali Akbar; Pasalari, Hassan; Mirzabeigi, Majid

2018-02-01

The aims of this study were to assess and analysis of drinking water quality of Chabahar villages in Sistan and Baluchistan province by water quality index (WQI) and to investigate the water stability in subjected area. The results illustrated that the average values of LSI, RSI, PSI, LS, and AI was 0.5 (±0.34), 6.76 (±0.6), 6.50 (±0.99), 2.71 (±1.59), and 12.63 (±0.34), respectively. The calculation of WQI for groundwater samples indicated that 25% of the samples could be considered as excellent water, 50% of the samples were classified as good water category and 25% of the samples showed poor water category.

Groundwater quality and simulation of sources of water to wells in the Marsh Creek valley at the U.S. Geological Survey Northern Appalachian Research Laboratory, Tioga County, Pennsylvania

USGS Publications Warehouse

Risser, Dennis W.; Breen, Kevin J.

2012-01-01

This report provides a November 2010 snapshot of groundwater quality and an analysis of the sources of water to wells at the U.S. Geological Survey (USGS) Northern Appalachian Research Laboratory (NARL) near Wellsboro, Pennsylvania. The laboratory, which conducts fisheries research, currently (2011) withdraws 1,000 gallons per minute of high-quality groundwater from three wells completed in the glacial sand and gravel aquifer beneath the Marsh Creek valley; a fourth well that taps the same aquifer provides the potable supply for the facility. The study was conducted to document the source areas and quality of the water supply for this Department of Interior facility, which is surrounded by the ongoing development of natural gas from the Marcellus Shale. Groundwater samples were collected from the four wells used by the NARL and from two nearby domestic-supply wells. The domestic-supply wells withdraw groundwater from bedrock of the Catskill Formation. Samples were analyzed for major ions, nutrients, trace metals, radiochemicals, dissolved gases, and stable isotopes of oxygen and hydrogen in water and carbon in dissolved carbonate to document groundwater quality. Organic constituents (other than hydrocarbon gases) associated with hydraulic fracturing and other human activities were not analyzed as part of this assessment. Results show low concentrations of all constituents. Only radon, which ranged from 980 to 1,310 picocuries per liter, was somewhat elevated. These findings are consistent with the pristine nature of the aquifer in the Marsh Creek valley, which is the reason the laboratory was sited at this location. The sources of water and areas contributing recharge to wells were identified by the use of a previously documented MODFLOW groundwater-flow model for the following conditions: (1) withdrawals of 1,000 to 3,000 gallons per minute from the NARL wells, (2) average or dry hydrologic conditions, and (3) withdrawals of 1,000 gallons per minute from a new well 3,500 feet to the southwest that was drilled to provide water for Marcellus gas-well operations. Results of simulations indicate that during average hydrologic conditions, infiltration from Straight Run, a tributary to Marsh Creek, provides nearly all the water to the NARL wells. During dry conditions, the areas contributing recharge expand such that Asaph Run contributes about half of the water to the NARL wells when withdrawals are 1,000 or 2,000 gallons per minute. The addition of a simulated withdrawal of 1,000 gallons per minute from the nearby new well does not substantially affect the sources of water captured by the NARL wells. These results are subject to some limitations. The water-quality samples represent a snapshot of groundwater chemistry for only one hydrologic condition; the concentrations of some constituents may change temporally. In addition, samples were collected and analyzed for hydrocarbon gases, but not organic constituents associated with hydraulic fracturing; additional sampling for these constituents would provide a more complete water-quality baseline. The sources contributing water to the NARL wells and the new well were simulated by use of a simplified one-layer model of the glacial sand and gravel aquifer for steady-state conditions that in reality are never achieved. Steady-state simulations of dry hydrologic conditions show that it is possible for the NARL wells to capture water from Asaph Run; however, maps of simulated groundwater time-of-travel indicate that a dry period of unusually long duration would be required. A better analysis could be done by recalibrating the groundwater-flow model with a finite-difference grid having multiple layers, cells smaller than the 200-foot by 200-foot cells used in this study, and transient stress periods.

Hydrogeochemistry and groundwater quality appraisal of part of south Chennai coastal aquifers, Tamil Nadu, India using WQI and fuzzy logic method

NASA Astrophysics Data System (ADS)

Krishna Kumar, S.; Bharani, R.; Magesh, N. S.; Godson, Prince S.; Chandrasekar, N.

2014-12-01

The present study was carried out to evaluate the groundwater quality and its suitability for drinking purposes in the urban coastal aquifers of part of south Chennai, Tamil Nadu, India. Twenty-three groundwater samples were collected during March 2012. The minimum and maximum values of pH (6.3-8 on scale), electrical conductivity (620-12,150 μS/cm), total dissolved solids (399.28-7,824.6 mg/l), carbonate (0-30 mg/l), bicarbonate (0.9-58.9 mg/l), chloride (70.9-4,067.89 mg/l), sulphate (17.4-105 mg/l), nitrate (0.4-6.0 mg/l), calcium (30-200 mg/l), magnesium (1.2-164 mg/l), sodium (69-1,490 mg/l) and potassium (8-340 mg/l) were recorded in the coastal aquifers of Chennai city. The groundwater samples show that the majority of the sampling points clustered on the NaCl and mixed CaMgCl facies of the piper trilinear diagram. In the Gibbs diagram, the majority of the sampling points fall under rock water and evaporation dominance field. Fuzzy membership classification suggests that the majority of the samples fall under good water type followed by excellent water and poor water categories. Groundwater quality index showing the majority of the samples falls under excellent to poor category of water. A positive correlation was observed with Cl-, SO4 2-, Ca2+, Na+, K+, EC and TDS. The extracted results of the correlation matrix and geochemical analysis suggest that the dominant ions of groundwater (Na+, Ca2+, K+, Cl- and SO4 2-) were derived from seawater intrusion and gypsum dissolution process. Nitrate concentration is most significantly derived from anthropogenic sources.

Assessment of hydro-geochemistry and groundwater quality of Rajshahi City in Bangladesh

NASA Astrophysics Data System (ADS)

Mostafa, M. G.; Uddin, S. M. Helal; Haque, A. B. M. H.

2017-12-01

The study was carried out to understand the hydro-geochemistry and ground water quality in the Rajshahi City of Bangladesh. A total of 240 groundwater samples were collected in 2 years, i.e., 2009 and 2010 covering the pre-monsoon, monsoon and post-monsoon seasons. Aquifer soil samples were collected from 30 locations during the monsoon in 2000. All the samples were analyzed for various physicochemical parameters according to standard methods of analysis, these includes pH, electrical conductivity, total dissolved solids, total hardness, and total alkalinity, major cations such as Na+, K+, Ca2+, Mg2+, and Fe2+, major anions such as HCO3 -, NO3 -, Cl-, and SO4 2- and heavy metals such as Mn, Zn, Cu, As, Cd and Pb. The results illustrated that the groundwater was slightly acidic to neutral in nature, total hardness observed in all samples fall under the hard to a very hard category. The bicarbonate and calcium concentration in the groundwater exceeded the permissible limits may be due to the dissolution of calcite. The concentration of calcium, iron, manganese, arsenic and lead were far above the permissible limit in most of the shallow tube well samples. The study found that the major hydrochemical facies was identified to be calcium-bicarbonate-type (CaHCO3). A higher concentration of metals including Fe, Mn, As and Pb was found indicating various health hazards. The rock-water interaction was the major geochemical process controlling the chemistry of groundwater in the study area. The study results revealed that the quality of the groundwater in Rajshahi City area was of great concern and not suitable for human consumption without adequate treatment.

Methods to prioritize placement of riparian buffers for improved water quality

Treesearch

Mark D. Tomer; Michael G. Dosskey; Michael R. Burkart; David E. James; Matthew J. Helmers; Dean E. Eisenhauer

2008-01-01

Agroforestry buffers in riparian zones can improve stream water quality, provided they intercept and remove contaminants from surface runoff and/or shallow groundwater. Soils, topography, surficial geology, and hydrology determine the capability of forest buffers to intercept and treat these flows. This paper describes two landscape analysis techniques for identifying...

Appraisal of long term groundwater quality of peninsular India using water quality index and fractal dimension

NASA Astrophysics Data System (ADS)

Rawat, Kishan Singh; Singh, Sudhir Kumar; Jacintha, T. German Amali; Nemčić-Jurec, Jasna; Tripathi, Vinod Kumar

2017-12-01

A review has been made to understand the hydrogeochemical behaviour of groundwater through statistical analysis of long term water quality data (year 2005-2013). Water Quality Index ( WQI), descriptive statistics, Hurst exponent, fractal dimension and predictability index were estimated for each water parameter. WQI results showed that majority of samples fall in moderate category during 2005-2013, but monitoring site four falls under severe category (water unfit for domestic use). Brownian time series behaviour (a true random walk nature) exists between calcium (Ca^{2+}) and electric conductivity (EC); magnesium (Mg^{2+}) with EC; sodium (Na+) with EC; sulphate (SO4^{2-}) with EC; total dissolved solids (TDS) with chloride (Cl-) during pre- (2005-2013) and post- (2006-2013) monsoon season. These parameters have a closer value of Hurst exponent ( H) with Brownian time series behaviour condition (H=0.5). The result of times series analysis of water quality data shows a persistent behaviour (a positive autocorrelation) that has played a role between Cl- and Mg^{2+}, Cl- and Ca^{2+}, TDS and Na+, TDS and SO4^{2-}, TDS and Ca^{2+} in pre- and post-monsoon time series because of the higher value of H (>1). Whereas an anti-persistent behaviour (or negative autocorrelation) was found between Cl- and EC, TDS and EC during pre- and post-monsoon due to low value of H. The work outline shows that the groundwater of few areas needs treatment before direct consumption, and it also needs to be protected from contamination.

Evaluation of surface water and groundwater contamination in a MSW landfill area using hydrochemical analysis and electrical resistivity tomography: a case study in Sichuan province, Southwest China.

PubMed

Ling, Chengpeng; Zhang, Qiang

2017-04-01

As a primary disposal mean of municipal solid waste in China, the landfill has been recognized as one of the major threats to the surrounding surface water and groundwater environment due to the emission of leachate. The aim of this study was to determine the impact of leachate on the surface water and groundwater environment of the region of the Chang'an landfill, which is located in Sichuan province, China. The surface water and groundwater were sampled for hydrochemical analysis. Three electrical resistivity tomography profiles were conducted to evaluate the impact of leachate on the groundwater environment, and several laboratory tests were carried out to build the relationship between the soil bulk resistivity and the void fluid resistivity. The results showed that a seasonal creek named Longfeng creek, which crosses the landfill site, was contaminated by the leachate. The concentrations of COD, BOD5, and chlorides (Cl) of surface water samples increased by 12.3-105.7 times. The groundwater quality in the surface loose sediments along the valley deteriorated obviously from the landfill to 500 m downstream area. The laboratory tests of soil samples indicated that the resistivity value of 13 Ωm is a critical value whether the groundwater in the loose sediments is polluted. The groundwater at the site adjacent to the spillway in the landfill was partially contaminated by the emission of leachate. The groundwater contamination zones at 580 m downstream of the landfill were recognized at the shallow zones from 60 m left bank to 30 m right bank of Longfeng creek. The improved understanding of groundwater contamination around the landfill is beneficial for the landfill operation and groundwater environment remediation.

Applying linear discriminant analysis to predict groundwater redox conditions conducive to denitrification

NASA Astrophysics Data System (ADS)

Wilson, S. R.; Close, M. E.; Abraham, P.

2018-01-01

Diffuse nitrate losses from agricultural land pollute groundwater resources worldwide, but can be attenuated under reducing subsurface conditions. In New Zealand, the ability to predict where groundwater denitrification occurs is important for understanding the linkage between land use and discharges of nitrate-bearing groundwater to streams. This study assesses the application of linear discriminant analysis (LDA) for predicting groundwater redox status for Southland, a major dairy farming region in New Zealand. Data cases were developed by assigning a redox status to samples derived from a regional groundwater quality database. Pre-existing regional-scale geospatial databases were used as training variables for the discriminant functions. The predictive accuracy of the discriminant functions was slightly improved by optimising the thresholds between sample depth classes. The models predict 23% of the region as being reducing at shallow depths (<15 m), and 37% at medium depths (15-75 m). Predictions were made at a sub-regional level to determine whether improvements could be made with discriminant functions trained by local data. The results indicated that any gains in predictive success were offset by loss of confidence in the predictions due to the reduction in the number of samples used. The regional scale model predictions indicate that subsurface reducing conditions predominate at low elevations on the coastal plains where poorly drained soils are widespread. Additional indicators for subsurface denitrification are a high carbon content of the soil, a shallow water table, and low-permeability clastic sediments. The coastal plains are an area of widespread groundwater discharge, and the soil and hydrology characteristics require the land to be artificially drained to render the land suitable for farming. For the improvement of water quality in coastal areas, it is therefore important that land and water management efforts focus on understanding hydrological bypassing that may occur via artificial drainage systems.

40 CFR 265.91 - Ground-water monitoring system.

Code of Federal Regulations, 2010 CFR

2010-07-01

... sufficient to yield ground-water samples that are: (i) Representative of background ground-water quality in... not required provided that provisions for sampling upgradient and downgradient water quality will... perforated, and packed with gravel or sand where necessary, to enable sample collection at depths where...

Public Health Risk Conditioned by Chemical Composition of Ground Water

NASA Astrophysics Data System (ADS)

Yankovich, E.; Osipova, N.; Yankovich, K.; Matveenko, I.

2016-03-01

The article studies the public health potential risk originated from water consumption and estimated on the basis of the groundwater chemical composition. We have processed the results of chemical groundwater analysis in different aquifers of Tomsk district (Tomsk Oblast, Russia). More than 8400 samples of chemical groundwater analyses were taken during long-term observation period. Human health risk assessment of exposure to contaminants in drinking water was performed in accordance with the risk assessment guidance for public health concerning chemical pollution of the environment (Russian reference number: 2.1.10.1920-04-M, 2004). Identified potential risks were estimated for consuming water of each aquifer. The comparative analysis of water quality of different aquifers was performed on the basis of the risk coefficient of the total non-carcinogenic effects. The non-carcinogenic risk for the health of the Tomsk district population due to groundwater consumption without prior sanitary treatment was admitted acceptable. A rather similar picture is observed for all aquifers, although deeper aquifers show lower hazard coefficients.

Assessment of Groundwater quality in Krishnagiri and Vellore Districts in Tamil Nadu, India

NASA Astrophysics Data System (ADS)

Shanmugasundharam, A.; Kalpana, G.; Mahapatra, S. R.; Sudharson, E. R.; Jayaprakash, M.

2017-07-01

Groundwater quality is important as it is the main factor determining its suitability for drinking, domestic, agricultural and industrial purposes. The suitability of groundwater for drinking and irrigation has been assessed in north and eastern part of Krishnagiri district, South-western part of Vellore district and contiguous with Andhra Pradesh states, India. A total of 31 groundwater samples were collected in the study area. The groundwater quality assessment has been carried out by evaluating the physicochemical parameters such as pH, EC, TDS, {HCO}3^{ - }, Cl-, {SO}4^{2 - }, Ca2+, Mg2+, Na+ and K+. The dominant cations are in the order of Na+ > K+ > Ca2+ > Mg2+ while the dominant anions have the trends of Cl- > {HCO}3^{ - } > {SO}4^{2 - } > CO3. The quality of the water is evaluated using Wilcox diagram and the results reveals that most of the samples are found to be suitable for irrigation. Based on these parameters, groundwater has been assessed in favor of its suitability for drinking and irrigation purpose.

The comparison of rapid bioassays for the assessment of urban groundwater quality.

PubMed

Dewhurst, R E; Wheeler, J R; Chummun, K S; Mather, J D; Callaghan, A; Crane, M

2002-05-01

Groundwater is a complex mixture of chemicals that is naturally variable. Current legislation in the UK requires that groundwater quality and the degree of contamination are assessed using chemical methods. Such methods do not consider the synergistic or antagonistic interactions that may affect the bioavailability and toxicity of pollutants in the environment. Bioassays are a method for assessing the toxic impact of whole groundwater samples on the environment. Three rapid bioassays, Eclox, Microtox and ToxAlert, and a Daphnia magna 48-h immobilisation test were used to assess groundwater quality from sites with a wide range of historical uses. Eclox responses indicated that the test was very sensitive to changes in groundwater chemistry; 77% of the results had a percentage inhibition greater than 90%. ToxAlert, although suitable for monitoring changes in water quality under laboratory conditions, produced highly variable results due to fluctuations in temperature and the chemical composition of the samples. Microtox produced replicable results that correlated with those from D. magna tests.

Field Sampling Plan/Quality Assurance Project Plan Volume I of III

EPA Pesticide Factsheets

This document contains procedures related to the collection and analysis of soil, sediment, groundwater, surface water, air and biota samples at GE’s Pittsfield, Massachusetts facility and at other areas.

Public Policy on Ground-Water Quality Protection. Proceedings of a National Conference (Virginia Polytechnic Inst. and State University, Blacksburg, Virginia, April 13-16, 1977).

ERIC Educational Resources Information Center

Kerns, Waldon R., Ed.

This publication contains the papers presented at a National Conference on Ground Water Quality Protection Policy held in April of 1977. Paper titles include: (1) Magnitude of the Ground-Water Contamination Problem; (2) Limited Degredation as a Ground-Water Quality Policy; (3) Surface and Subsurface Mining: Policy Implications; (4) Oil Well…

Groundwater quality in the Piedmont and Blue Ridge crystalline-rock aquifers, eastern United States

USGS Publications Warehouse

Lindsey, Bruce

2017-12-07

Groundwater provides nearly 50 percent of the Nation’s drinking water. To help protect this vital resource, the U.S. Geological Survey (USGS) National Water-Quality Assessment (NAWQA) Project assesses groundwater quality in aquifers that are important sources of drinking water (Burow and Belitz, 2014). The Piedmont and Blue Ridge crystalline-rock aquifers constitute one of the important areas being evaluated.

Groundwater-Quality Data in the South Coast Interior Basins Study Unit, 2008: Results from the California GAMA Program

USGS Publications Warehouse

Mathany, Timothy M.; Kulongoski, Justin T.; Ray, Mary C.; Belitz, Kenneth

2009-01-01

Groundwater quality in the approximately 653-square-mile South Coast Interior Basins (SCI) study unit was investigated from August to December 2008, as part of the Priority Basins Project of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The GAMA Priority Basins Project was developed in response to Legislative mandates (Supplemental Report of the 1999 Budget Act 1999-00 Fiscal Year; and, the Groundwater-Quality Monitoring Act of 2001 [Sections 10780-10782.3 of the California Water Code, Assembly Bill 599]) to assess and monitor the quality of groundwater used as public supply for municipalities in California, and is being conducted by the U.S. Geological Survey (USGS) in cooperation with the California State Water Resources Control Board (SWRCB). SCI was the 27th study unit to be sampled as part of the GAMA Priority Basins Project. This study was designed to provide a spatially unbiased assessment of the quality of untreated groundwater used for public water supplies within SCI, and to facilitate statistically consistent comparisons of groundwater quality throughout California. Samples were collected from 54 wells within the three study areas [Livermore, Gilroy, and Cuyama] of SCI in Alameda, Santa Clara, San Benito, Santa Barbara, Ventura, and Kern Counties. Thirty-five of the wells were selected using a spatially distributed, randomized grid-based method to provide statistical representation of the study unit (grid wells), and 19 were selected to aid in evaluation of specific water-quality issues (understanding wells). The groundwater samples were analyzed for organic constituents [volatile organic compounds (VOCs), pesticides and pesticide degradates, polar pesticides and metabolites, and pharmaceutical compounds], constituents of special interest [perchlorate and N-nitrosodimethylamine (NDMA)], naturally occurring inorganic constituents [trace elements, nutrients, major and minor ions, silica, total dissolved solids (TDS), and alkalinity], and radioactive constituents [gross alpha and gross beta radioactivity and radon-222]. Naturally occurring isotopes [stable isotopes of hydrogen, oxygen, and carbon, and activities of tritium and carbon-14] and dissolved noble gases also were measured to help identify the sources and ages of the sampled groundwater. In total, 288 constituents and water-quality indicators (field parameters) were investigated. Three types of quality-control samples (blanks, replicates, and matrix spikes) each were collected at approximately 4-11 percent of the wells, and the results for these samples were used to evaluate the quality of the data for the groundwater samples. Field blanks rarely contained detectable concentrations of any constituent, suggesting that contamination was not a significant source of bias in the data obtained from the groundwater samples. Differences between replicate samples generally were less than 10 percent relative standard deviation, indicating acceptable analytical reproducibility. Matrix spike recoveries were within the acceptable range (70 to 130 percent) for most compounds. This study did not attempt to evaluate the quality of water delivered to consumers; after withdrawal from the ground, untreated groundwater typically is treated, disinfected, and/or blended with other waters to maintain water quality. Regulatory thresholds apply to water that is served to the consumer, not to untreated groundwater. However, to provide some context for the results, concentrations of constituents measured in the untreated groundwater were compared with regulatory and nonregulatory health-based thresholds established by the U.S. Environmental Protection Agency (USEPA) and California Department of Public Health (CDPH), and to nonregulatory thresholds established for aesthetic and technical concerns by CDPH. Comparisons between data collected for this study and thresholds for drinking water are for illustrative purposes only, and are not indicative of complia

California Groundwater Ambient Monitoring and Assessment (GAMA) Program Priority Basin Project--shallow aquifer assessment

USGS Publications Warehouse

,

2013-01-01

The California State Water Resources Control Board’s (SWRCB) GAMA Program is a comprehensive assessment of statewide groundwater quality in California. From 2004 to 2012, the GAMA Program’s Priority Basin Project focused on assessing groundwater resources used for public drinking-water supplies. More than 2,000 public-supply wells were sampled by U.S. Geological Survey (USGS) for this effort. Starting in 2012, the GAMA Priority Basin Project began an assessment of water resources in shallow aquifers in California. These shallow aquifers provide water for domestic and small community-supply wells, which are often drilled to shallower depths in the groundwater system than public-supply wells. Shallow aquifers are of interest because shallow groundwater may respond more quickly and be more susceptible to contamination from human activities at the land surface, than the deeper aquifers. The SWRCB’s GAMA Program was developed in response to the Groundwater Quality Monitoring Act of 2001 (Water Code sections 10780-10782.3): a public mandate to assess and monitor the quality of groundwater resources used for drinking-water supplies, and to increase the availability of information about groundwater quality to the public. The U.S. Geological Survey is the technical lead of the Priority Basin Project. Stewardship of California’s groundwater resources is a responsibility shared between well owners, communities, and the State. Participants and collaborators in the GAMA Program include Regional Water Quality Control Boards, Department of Water Resources, Department of Public Health, local and regional groundwater management entities, county and local water agencies, community groups, and private citizens. Well-owner participation in the GAMA Program is entirely voluntary.

Laboratory and quality assurance protocols for the analysis of herbicides in ground water from the Management Systems Evaluation Area, Princeton, Minnesota

USGS Publications Warehouse

Larson, S.J.; Capel, P.D.; VanderLoop, A.G.

1996-01-01

Laboratory and quality assurance procedures for the analysis of ground-water samples for herbicides at the Management Systems Evaluation Area near Princeton, Minnesota are described. The target herbicides include atrazine, de-ethylatrazine, de-isopropylatrazine, metribuzin, alachlor, 2,6-diethylaniline, and metolachlor. The analytical techniques used are solid-phase extraction, and analysis by gas chromatography with mass-selective detection. Descriptions of cleaning procedures, preparation of standard solutions, isolation of analytes from water, sample transfer methods, instrumental analysis, and data analysis are included.

Management decision of optimal recharge water in groundwater artificial recharge conditions- A case study in an artificial recharge test site

NASA Astrophysics Data System (ADS)

He, H. Y.; Shi, X. F.; Zhu, W.; Wang, C. Q.; Ma, H. W.; Zhang, W. J.

2017-11-01

The city conducted groundwater artificial recharge test which was taken a typical site as an example, and the purpose is to prevent and control land subsidence, increase the amount of groundwater resources. To protect groundwater environmental quality and safety, the city chose tap water as recharge water, however, the high cost makes it not conducive to the optimal allocation of water resources and not suitable to popularize widely. To solve this, the city selects two major surface water of River A and B as the proposed recharge water, to explore its feasibility. According to a comprehensive analysis of the cost of recharge, the distance of the water transport, the quality of recharge water and others. Entropy weight Fuzzy Comprehensive Evaluation Method is used to prefer tap water and water of River A and B. Evaluation results show that water of River B is the optimal recharge water, if used; recharge cost will be from 0.4724/m3 to 0.3696/m3. Using Entropy weight Fuzzy Comprehensive Evaluation Method to confirm water of River B as optimal water is scientific and reasonable. The optimal water management decisions can provide technical support for the city to carry out overall groundwater artificial recharge engineering in deep aquifer.

Hydrogeologic framework, hydrology, and water quality in the Pearce Creek Dredge Material Containment Area and vicinity, Cecil County, Maryland, 2010-11

USGS Publications Warehouse

Dieter, Cheryl A.; Koterba, Michael T.; Zapecza, Otto S.; Walker, Charles W.; Rice, Donald E.

2013-01-01

In 2009, to support an evaluation of the feasibility of reopening the Pearce Creek Dredge Material Containment Area (DMCA) in Cecil County, Maryland, for dredge-spoil disposal, the U.S. Geological Survey (USGS) began to implement a comprehensive study designed to improve the understanding of the hydrogeologic framework, hydrology, and water quality of shallow aquifers underlying the DMCA and adjacent communities, to determine whether or not the DMCA affected groundwater quality, and to assess whether or not groundwater samples contained chemical constituents at levels greater than maximum allowable or recommended levels established by the U.S. Environmental Protection Agency Safe Drinking Water Act. The study, conducted in 2010-11 by USGS in cooperation with the U.S. Army Corps of Engineers, included installation of observation wells in areas where data gaps led earlier studies to be inconclusive. The data from new wells and existing monitoring locations were interpreted and show the DMCA influences the groundwater flow and quality. Groundwater flow in the two primary aquifers used for local supplies-the Magothy aquifer and upper Patapsco aquifer (shallow water-bearing zone)-is radially outward from the DMCA toward discharge areas, including West View Shores, the Elk River, and Pearce Creek Lake. In addition to horizontal flow outward from the DMCA, vertical gradients primarily are downward in most of the study area, and upward near the Elk River on the north side of the DMCA property, and the western part of West View Shores. Integrating groundwater geochemistry data in the analysis, the influence of the DMCA is not only a source of elevated concentrations of dissolved solids but also a geochemical driver of redox processes that enhances the mobilization and transport of redox-sensitive metals and nutrients. Groundwater affected by the DMCA is in the Magothy aquifer and upper Patapsco aquifer (shallow water-bearing zone). Based on minimal data, the water quality in the upper Patapsco aquifer deep water-bearing zone does not seem to have been impacted by the DMCA.

Groundwater quality and occurrence and distribution of selected constituents in the Aquia and Upper Patapsco aquifers, Naval Air Station Patuxent River, St. Mary's County, Maryland, July 2008

USGS Publications Warehouse

Dieter, Cheryl A.; Campo, Kimberly W.; Baker, Anna C.

2012-01-01

The Naval Air Station Patuxent River in southern Maryland has continued to expand in the first decade of the 21st century, contributing to rapid population growth in the surrounding area. The increase in population has caused State and County water managers and others to be concerned about the impact of population growth on the quantity and quality of groundwater supplies. The U.S. Geological Survey has been investigating the groundwater resources of the air station since 1998. As part of that ongoing investigation, groundwater was sampled in 2008 in six wells in the Aquia aquifer and two wells in the Upper Patapsco aquifer in the vicinity of Naval Air Station Patuxent River and Webster Outlying Field. Groundwater samples were analyzed for basic chemistry (field parameters, major ions, and nutrients) as well as several water-quality issues of concern including the occurrence of arsenic and tungsten, and saltwater intrusion. The results of the 2008 groundwater-quality sampling indicate that the overall quality of groundwater in the Aquia aquifer has not changed since 1943; data are too limited to determine if groundwater quality has changed in the Upper Patapsco aquifer. At one well in the Aquia aquifer, the arsenic concentration exceeded the U.S. Environmental Protection Agency standard for drinking water. Arsenic was not detected in samples from the Upper Patapsco aquifer. Tungsten concentrations were detected at low concentrations near the laboratory reporting level in all eight samples. There was no evidence of saltwater intrusion in any of the wells.

Geohydrology, geochemistry, and groundwater simulation (1992-2011) and analysis of potential water-supply management options, 2010-60, of the Langford Basin, California

USGS Publications Warehouse

Voronin, Lois M.; Densmore, Jill N.; Martin, Peter; Brush, Charles F.; Carlson, Carl S.; Miller, David M.

2013-01-01

Groundwater withdrawals began in 1992 from the Langford Basin within the Fort Irwin National Training Center (NTC), California. From April 1992 to December 2010, approximately 12,300 acre-feet of water (averaging about 650 acre-feet per year) has been withdrawn from the basin and transported to the adjacent Irwin Basin. Since withdrawals began, water levels in the basin have declined by as much as 40 feet, and the quality of the groundwater withdrawn from the basin has deteriorated. The U.S. Geological Survey collected geohydrologic data from Langford Basin during 1992–2011 to determine the quantity and quality of groundwater available in the basin. Geophysical surveys, including gravity, seismic refraction, and time-domain electromagnetic induction surveys, were conducted to determine the depth and shape of the basin, to delineate depths to the Quaternary-Tertiary interface, and to map the depth to the water table and changes in water quality. Data were collected from existing wells and test holes, as well as 11 monitor wells that were installed at 5 sites as part of this study. Water-quality samples collected from wells in the basin were used to determine the groundwater chemistry within the basin and to delineate potential sources of poor-quality groundwater. Analysis of stable isotopes of oxygen and hydrogen in groundwater indicates that present-day precipitation is not a major source of recharge to the basin. Tritium and carbon-14 data indicate that most of the basin was recharged prior to 1952, and the groundwater in the basin has an apparent age of 12,500 to 30,000 years. Recharge to the basin, estimated to be less than 50 acre-feet per year, has not been sufficient to replenish the water that is being withdrawn from the basin. A numerical groundwater-flow model was developed for the Langford Basin to better understand the aquifer system used by the Fort Irwin NTC as part of its water supply, and to provide a tool to help manage groundwater resources at the NTC. Measured groundwater-level declines since the initiation of withdrawals (1992–2011) were used to calibrate the groundwater-flow model. The simulated recharge was about 46 acre-feet per year, including approximately 6 acre-feet per year of natural recharge derived from precipitation runoff and as much as 40 acre-feet per year of underflow from the Irwin Basin. Between April 1992 and December 2010, an average of about 650 acre-feet per year of water was withdrawn from the Langford Basin. Groundwater withdrawals in excess of natural recharge resulted in a net loss of 11,670 acre-feet of groundwater storage within the basin for the simulation period. The Fort Irwin NTC is considering various groundwater-management options to address the limited water resources in the Langford Basin. The calibrated Langford Basin groundwater-flow model was used to evaluate the hydrologic effects of four groundwater-withdrawal scenarios being considered by the Fort Irwin NTC over the next 50 years (January 2011 through December 2060). Continuation of the 2010 withdrawal rate in the three existing production wells will result in 70 feet of additional drawdown in the central part of the basin. Redistributing the 2010 withdrawal rate equally to the three existing wells and two proposed new wells in the northern and southern parts of the basin would result in about 10 feet less drawdown in the central part of the basin but about 100 feet of additional drawdown in the new well in the northern part of the basin and about 50 feet of additional drawdown in the new well in the southern part of the basin. Reducing the withdrawals from the three existing production wells in the central part of the basin from about 45,000 acre-feet to about 32,720 acre-feet would result in about 40 feet of additional drawdown in the central basin near the pumping wells, about 25 feet less than if withdrawals were not reduced. The combination of reducing and redistributing the cumulative withdrawals to the three existing and two proposed new wells results in about 40 feet of additional drawdown in the central and southern parts of the basin and about 70 feet in the northern part of the basin. These results show that reducing and redistributing the groundwater withdrawals would maintain the upper aquifer at greater than 50 percent of its predevelopment saturated thickness throughout the groundwater basin. The scenarios simulated for this study demonstrate how the calibrated model can be utilized to evaluate the hydrologic effects of different water-management strategies.

Oregon ground-water quality and its relation to hydrogeological factors; a statistical approach

USGS Publications Warehouse

Miller, T.L.; Gonthier, J.B.

1984-01-01

An appraisal of Oregon ground-water quality was made using existing data accessible through the U.S. Geological Survey computer system. The data available for about 1,000 sites were separated by aquifer units and hydrologic units. Selected statistical moments were described for 19 constituents including major ions. About 96 percent of all sites in the data base were sampled only once. The sample data were classified by aquifer unit and hydrologic unit and analysis of variance was run to determine if significant differences exist between the units within each of these two classifications for the same 19 constituents on which statistical moments were determined. Results of the analysis of variance indicated both classification variables performed about the same, but aquifer unit did provide more separation for some constituents. Samples from the Rogue River basin were classified by location within the flow system and type of flow system. The samples were then analyzed using analysis of variance on 14 constituents to determine if there were significant differences between subsets classified by flow path. Results of this analysis were not definitive, but classification as to the type of flow system did indicate potential for segregating water-quality data into distinct subsets. (USGS)

Water quality analysis of the Rapur area, Andhra Pradesh, South India using multivariate techniques

NASA Astrophysics Data System (ADS)

Nagaraju, A.; Sreedhar, Y.; Thejaswi, A.; Sayadi, Mohammad Hossein

2017-10-01

The groundwater samples from Rapur area were collected from different sites to evaluate the major ion chemistry. The large number of data can lead to difficulties in the integration, interpretation, and representation of the results. Two multivariate statistical methods, hierarchical cluster analysis (HCA) and factor analysis (FA), were applied to evaluate their usefulness to classify and identify geochemical processes controlling groundwater geochemistry. Four statistically significant clusters were obtained from 30 sampling stations. This has resulted two important clusters viz., cluster 1 (pH, Si, CO3, Mg, SO4, Ca, K, HCO3, alkalinity, Na, Na + K, Cl, and hardness) and cluster 2 (EC and TDS) which are released to the study area from different sources. The application of different multivariate statistical techniques, such as principal component analysis (PCA), assists in the interpretation of complex data matrices for a better understanding of water quality of a study area. From PCA, it is clear that the first factor (factor 1), accounted for 36.2% of the total variance, was high positive loading in EC, Mg, Cl, TDS, and hardness. Based on the PCA scores, four significant cluster groups of sampling locations were detected on the basis of similarity of their water quality.

Groundwater.

ERIC Educational Resources Information Center

Braids, Olin C.; Gillies, Nola P.

1978-01-01

Presents a literature review of groundwater quality covering publications of 1977. This review includes: (1) sources of groundwater contamination; and (2) management of groundwater. A list of 59 references is also presented. (HM)

Hydrogeology and effects of landfills on ground-water quality, southern Franklin County, Ohio

USGS Publications Warehouse

De Roche, J.T.

1985-01-01

Hydrogeology and water quality were evaluated near five land-fills along a 5-mile segment of the Scioto River valley south of Columbus, Ohio. Heterogenous surficial deposits o sand, gravel, and till up to 160 feet thick are hydraulically connected to the underlying Devonian limestone, the landfills and Scioto River, which has been leveed with 12 to 35 feet of refuse. Ground-water withdrawals caused a maximum 21-foot decline in ground-water levels from 1979 to 1982. The study reach of Scioto River within the influence of ground-water pumping is a losing stream, except for s small segment adjacent to one landfill. Analysis of variance indicated significant difference in ground-water quality between wells upgradient of landfills, down-gradient of landfills, and wells penetrating refuse. Elevated specific conductance and concentrations of total dissolved solids, ammonia, carbon dioxide, and dissolved organic carbon in water from wells downgradient from and penetrating landfills indicate leachate production and migration is occurring. Analysis of bed-material samples from Scioto River and Scioto Big Run revealed concentrations of polynuclear aromatic hydrocarbons ranging from 220 to 9,440 micograms per kilogram of sediment (?g/kg) and concentrations of toxic metals ranging from 1 to 720 ?g/kg. Samples from an upstream control station on Scioto River contained no organic compounds and lower concentrations of metals (ranging from 1 to 260 ?g/kg). Because of multiple land uses within the study area, organic compounds recovered from the streamed sediments cannot be attributed to any single source. The generation of hydrogen sulfide and methane gases, presence of a zone of increased hardness, elevated concentrations of common ionic species, and dominance of ammonia over other nitrogen species indicate that leachate is being produced and its migrating from four landfills and the river levee. Based on hydraulic relationships between ground water and surface water, it is highly probable that ground water contaminated by leachate from the levee and from one of the landfills is discharging to Scioto River. Leachate-enriched groundwater from other landfills also may begin to discharge to the river if water-withdrawal patterns in the study area change.

Groundwater Pollution Sources Apportionment in the Ghaen Plain, Iran

PubMed Central

Berndtsson, Ronny; Adamowski, Jan; Sadatipour, Elaheh

2018-01-01

Although Iran’s Ghaen Plain provides saffron to much of the world, no regional groundwater quality (GQ) assessment has yet been undertaken. Given the region’s potential for saltwater intrusion and heavy metal contamination, it is important to assess the GQ and determine its main probable source of pollution (MPSP). Such knowledge would allow for informed mitigation or elimination of the potential adverse health effects of this groundwater through its use as drinking water, or indirectly as a result of the consumption of groundwater-irrigated crops. Total dissolved solids, sodium, and chloride in the water of the majority of 16 wells sampled within the region exceeded World Health Organization and Iranian permissible standards for drinking water. The groundwater proved to only be suitable for irrigating salt tolerant crops under good drainage conditions. Due to the precipitation of calcium carbonate in the water supply facilities, the water from all wells was deemed unsuitable for industrial purposes. Heavy metal pollution and contamination indices showed no groundwater contamination. Analysis of ionic ratios and the application of principal components analysis indicated the MPSP to be saltwater intrusion, with the geology subtending the plain, and to a lesser extent, anthropogenic activities. Reducing groundwater withdrawals, particularly those for agricultural production by using high performance irrigation methods could reduce saltwater intrusion and improve GQ in the Ghaen Plain. PMID:29361791

Assessing groundwater quality in Greece based on spatial and temporal analysis.

PubMed

Dokou, Zoi; Kourgialas, Nektarios N; Karatzas, George P

2015-12-01

The recent industrial growth together with the urban expansion and intensive agriculture in Greece has increased groundwater contamination in many regions of the country. In order to design successful remediation strategies and protect public health, it is very important to identify those areas that are most vulnerable to groundwater contamination. In this work, an extensive contamination database from monitoring wells that cover the entire Greek territory during the last decade (2000-2008) was used in order to study the temporal and spatial distribution of groundwater contamination for the most common and serious anionic and cationic trace element pollutants (heavy metals). Spatial and temporal patterns and trends in the occurrence of groundwater contamination were also identified highlighting the regions where the higher groundwater contamination rates have been detected across the country. As a next step, representative contaminated aquifers in Greece, which were identified by the above analysis, were selected in order to analyze the specific contamination problem in more detail. To this end, geostatistical techniques (various types of kriging, co-kriging, and indicator kriging) were employed in order to map the contaminant values and the probability of exceeding critical thresholds (set as the parametric values of the contaminant of interest in each case). The resulting groundwater contamination maps could be used as a useful tool for water policy makers and water managers in order to assist the decision-making process.

Looking at groundwater research landscape of Jakarta Basin for better water management

NASA Astrophysics Data System (ADS)

Irawan, Dasapta Erwin; Priyambodho, Adhi; Novianti Rachmi, Cut; Maulana Wibowo, Dimas

2017-07-01

Based on our experience, defining the gap between what we know and what we don’t know is the hardest part in proposing water management strategy. Many techniques have been introduced to make this stage easier, and one of them is bibliometric analysis. The following paper is the second part of our bibliometric project in the search for a gap in the water resources research in Jakarta. This paper starts to analyse the visualisations that had been extracted from the previous paper based on our database. Using the keyword “groundwater Jakarta”, we managed to get 70 relevant papers. Several visualisations have been built using open source applications. Word cloud analysis shows that the trend to discuss groundwater in scientific sense had only been started in the early 2000’s. This is presumably due to the emerging regional autonomy in which forcing regions to understand their groundwater setting before creating a management strategy. More papers in the later time has been induced by more geo-hazards (land subsidence and floods) resulted in the vast groundwater pumping. More and more resources have been utilized to get more groundwater data. Water scientists by then understood that these hazards had been started long before the 2000’s. This had become the starting point of data era later on. The next era will be the era of water management. Hydrologists had been proposing integrated water management Jakarta and its nearby groundwater basins. Most of them have been strongly suggested to manage all water bodies, rainfall, surface water, and groundwater as one system. In the 2010’s we identify more papers are discussing in water quality following the vast discussion in water quantity in the previous era. People have been more aware the importance of quality in providing water system for the citizen. Then five years later, we believe that water researchers have also put their mind in the interactions between surface water and groundwater, especially in the riverbank, where most of the slums are located. Based on the results, we believe that more researches to understand interactions between groundwater and surface water would fill the gap to come up with better water management system in Jakarta.

Groundwater-Quality Data in the South Coast Range-Coastal Study Unit, 2008: Results from the California GAMA Program

USGS Publications Warehouse

Mathany, Timothy M.; Burton, Carmen A.; Land, Michael; Belitz, Kenneth

2010-01-01

Groundwater quality in the approximately 766-square-mile South Coast Range-Coastal (SCRC) study unit was investigated from May to December 2008, as part of the Priority Basins Project of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The GAMA Priority Basins Project was developed in response to legislative mandates (Supplemental Report of the 1999 Budget Act 1999-00 Fiscal Year; and, the Groundwater Quality Monitoring Act of 2001 [Sections 10780-10782.3 of the California Water Code, Assembly Bill 599]) to assess and monitor the quality of groundwater in California, and is being conducted by the U.S. Geological Survey (USGS) in cooperation with the California State Water Resources Control Board (SWRCB). The SCRC study unit was the 25th study unit to be sampled as part of the GAMA Priority Basins Project. The SCRC study unit was designed to provide a spatially unbiased assessment of untreated groundwater quality in the primary aquifer systems and to facilitate statistically consistent comparisons of untreated groundwater quality throughout California. The primary aquifer systems (hereinafter referred to as primary aquifers) were defined as that part of the aquifer corresponding to the perforation interval of wells listed in the California Department of Public Health (CDPH) database for the SCRC study unit. The quality of groundwater in shallow or deep water-bearing zones may differ from the quality of groundwater in the primary aquifers; shallow groundwater may be more vulnerable to surficial contamination. In the SCRC study unit, groundwater samples were collected from 70 wells in two study areas (Basins and Uplands) in Santa Barbara and San Luis Obispo Counties. Fifty-five of the wells were selected using a spatially distributed, randomized grid-based method to provide statistical representation of the study unit (grid wells), and 15 wells were selected to aid in evaluation of specific water-quality issues (understanding wells). In addition to the 70 wells sampled, 3 surface-water samples were collected in streams near 2 of the sampled wells in order to better comprehend the interaction between groundwater and surface water in the area. The groundwater samples were analyzed for organic constituents (volatile organic compounds [VOC], pesticides and pesticide degradates, polar pesticides and metabolites, and pharmaceutical compounds), constituents of special interest (perchlorate, N-nitrosodimethylamine [NDMA], and 1,2,3-TCP), naturally occurring inorganic constituents (trace elements, nutrients, dissolved organic carbon [DOC], major and minor ions, silica, total dissolved solids [TDS], and alkalinity), and radioactive constituents (gross alpha and gross beta radioactivity). Naturally occurring isotopes (stable isotopes of hydrogen and oxygen in water, stable isotopes of nitrogen and oxygen in dissolved nitrate, stable isotopes of sulfur in dissolved sulfate, stable isotopes of carbon in dissolved inorganic carbon, activities of tritium, and carbon-14 abundance), and dissolved gases (including noble gases) also were measured to help identify the sources and ages of the sampled groundwater. In total, 298 constituents and field water-quality indicators were investigated. Three types of quality-control samples (blanks, replicates, and matrix-spikes) were collected at approximately 3 to 12 percent of the wells in the SCRC study unit, and the results for these samples were used to evaluate the quality of the data for the groundwater samples. Field blanks rarely contained detectable concentrations of any constituent, suggesting that contamination from sample collection procedures was not a significant source of bias in the data for the groundwater samples. Differences between replicate samples generally were less than 10 percent relative and/or standard deviation, indicating acceptable analytical reproducibility. Matrix-spike recoveries were within the acceptable range (70 to 130 percent) for approximately 84

Explaining nitrate pollution pressure on the groundwater resource in Kinshasa using a multivariate statistical modelling approach

NASA Astrophysics Data System (ADS)

Mfumu Kihumba, Antoine; Vanclooster, Marnik

2013-04-01

Drinking water in Kinshasa, the capital of the Democratic Republic of Congo, is provided by extracting groundwater from the local aquifer, particularly in peripheral areas. The exploited groundwater body is mainly unconfined and located within a continuous detrital aquifer, primarily composed of sedimentary formations. However, the aquifer is subjected to an increasing threat of anthropogenic pollution pressure. Understanding the detailed origin of this pollution pressure is important for sustainable drinking water management in Kinshasa. The present study aims to explain the observed nitrate pollution problem, nitrate being considered as a good tracer for other pollution threats. The analysis is made in terms of physical attributes that are readily available using a statistical modelling approach. For the nitrate data, use was made of a historical groundwater quality assessment study, for which the data were re-analysed. The physical attributes are related to the topography, land use, geology and hydrogeology of the region. Prior to the statistical modelling, intrinsic and specific vulnerability for nitrate pollution was assessed. This vulnerability assessment showed that the alluvium area in the northern part of the region is the most vulnerable area. This area consists of urban land use with poor sanitation. Re-analysis of the nitrate pollution data demonstrated that the spatial variability of nitrate concentrations in the groundwater body is high, and coherent with the fragmented land use of the region and the intrinsic and specific vulnerability maps. For the statistical modeling use was made of multiple regression and regression tree analysis. The results demonstrated the significant impact of land use variables on the Kinshasa groundwater nitrate pollution and the need for a detailed delineation of groundwater capture zones around the monitoring stations. Key words: Groundwater , Isotopic, Kinshasa, Modelling, Pollution, Physico-chemical.

Using vadose zone data and spatial statistics to assess the impact of cultivated land and dairy waste lagoons on groundwater contamination

NASA Astrophysics Data System (ADS)

Baram, S.; Ronen, Z.; Kurtzman, D.; Peeters, A.; Dahan, O.

2013-12-01

Land cultivation and dairy waste lagoons are considered to be nonpoint and point sources of groundwater contamination by chloride (Cl-) and nitrate (NO3-). The objective of this work is to introduce a methodology to assess the past and future impacts of such agricultural activities on regional groundwater quality. The method is based on mass balances and on spatial statistical analysis of Cl- and NO3-concentration distributions in the saturated and unsaturated zones. The method enables quantitative analysis of the relation between the locations of pollution point sources and the spatial variability in Cl- and NO3- concentrations in groundwater. The method was applied to the Beer-Tuvia region, Israel, where intensive dairy farming along with land cultivation has been practiced for over 50 years above the local phreatic aquifer. Mass balance calculations accounted for the various groundwater recharge and abstraction sources and sinks in the entire region. The mass balances showed that leachates from lagoons and the cultivated land have contributed 6.0 and 89.4 % of the total mass of Cl- added to the aquifer and 12.6 and 77.4 % of the total mass of NO3-. The chemical composition of the aquifer and vadose zone water suggested that irrigated agricultural activity in the region is the main contributor of Cl- and NO3- to the groundwater. A low spatial correlation between the Cl- and NO3- concentrations in the groundwater and the on-land location of the dairy farms strengthened this assumption, despite the dairy waste lagoon being a point source for groundwater contamination by Cl- and NO3-. Results demonstrate that analyzing vadose zone and groundwater data by spatial statistical analysis methods can significantly contribute to the understanding of the relations between groundwater contaminating sources, and to assessing appropriate remediation steps.

Geohydrology and ground-water quality at selected sites in Meade County, Kentucky, 1987-88

USGS Publications Warehouse

Mull, D.S.; Alexander, A.G.; Schultz, P.E.

1989-01-01

Meade County in north-central Kentucky is about 305 sq mi in size, and is underlain by thick beds of limestone and dolomite which are the principal sources of drinking water for about 8 ,500 residents. About half the area contains mature, karst terrain with abundant sinkholes, springs, and caves. Because of this karst terrain, groundwater is susceptible to rapid changes in water quality and contamination from human sources. Thirty-seven wells and 12 springs were selected as sampling points to characterize groundwater quality in the area. Water was analyzed for major anions and cations, nitrates, trace elements, and organic compounds. Water from selected sites was also analyzed for fecal species of coliform streptococci bacteria and total coliform content. Except for fluoride and lead, the water quality was within the range expected for carbonate aquifers.The fluoride content was significantly higher in water from wells than in water from springs. Concentrations of detectable lead ranged from 10 to 50 micrograms/L and had a median value of 7.5 microg/L. Dissolved solids ranged from 100 to 2,200 mg/L and the median value was 512 mg/L. Hardness ranged from 20 to 1,100 mg/L and the median value was 290 mg/L. Organic compounds detected by the gas chromatographic/flame ionization detection scans, did not indicate evidence of concentrations in excess of the current Federal drinking water standards. Analysis for specific organic compounds indicated that the presence of these compounds was associated with agricultural chemicals, usually pesticides. Total coliform content exceeded drinking water standards in water from all 12 springs and in 18 wells. Statistical analysis of the groundwater quality data indicates that the variance of the concentrations of fluoride and chloride may be attributed to the site type. There was strong correlation between hardness and dissolved solids, hardness and sulfate, and sulfate and dissolved solids. No apparent relations were detected between water quality and the geographic location of sampling sites. However, seasonal variations were detected in the concentrations of dissolved solids, hardness, and iron. (Lantz-PTT)

Groundwater-quality data in the Klamath Mountains study unit, 2010: results from the California GAMA Program

USGS Publications Warehouse

Mathany, Timothy M.; Belitz, Kenneth

2014-01-01

Groundwater quality in the 8,806-square-mile Klamath Mountains (KLAM) study unit was investigated by the U.S. Geological Survey (USGS) from October to December 2010, as part of the California State Water Resources Control Board (SWRCB) Groundwater Ambient Monitoring and Assessment (GAMA) Program’s Priority Basin Project (PBP). The GAMA-PBP was developed in response to the California Groundwater Quality Monitoring Act of 2001 and is being conducted in collaboration with the SWRCB and Lawrence Livermore National Laboratory (LLNL). The KLAM study unit was the thirty-third study unit to be sampled as part of the GAMA-PBP. The GAMA Klamath Mountains study was designed to provide a spatially unbiased assessment of untreated-groundwater quality in the primary aquifer system and to facilitate statistically consistent comparisons of untreated-groundwater quality throughout California. The primary aquifer system is defined by the perforation intervals of wells listed in the California Department of Public Health (CDPH) database for the KLAM study unit. Groundwater quality in the primary aquifer system may differ from the quality in the shallower or deeper water-bearing zones; shallower groundwater may be more vulnerable to surficial contamination. In the KLAM study unit, groundwater samples were collected from sites in Del Norte, Siskiyou, Humboldt, Trinity, Tehama, and Shasta Counties, California. Of the 39 sites sampled, 38 were selected by using a spatially distributed, randomized grid-based method to provide statistical representation of the primary aquifer system in the study unit (grid sites), and the remaining site was non-randomized (understanding site). The groundwater samples were analyzed for basic field parameters, organic constituents (volatile organic compounds [VOCs] and pesticides and pesticide degradates), inorganic constituents (trace elements, nutrients, major and minor ions, total dissolved solids [TDS]), radon-222, gross alpha and gross beta radioactivity, and microbial indicators (total coliform and Escherichia coli [E. coli]). Isotopic tracers (stable isotopes of hydrogen and oxygen in water, isotopic ratios of dissolved strontium in water, and stable isotopes of carbon in dissolved inorganic carbon), dissolved noble gases, and age-dating tracers (tritium and carbon-14) were measured to help identify sources and ages of sampled groundwater. Quality-control samples (field blanks, replicate sample pairs, and matrix spikes) were collected at 13 percent of the sites in the KLAM study unit, and the results were used to evaluate the quality of the data from the groundwater samples. Field blank samples rarely contained detectable concentrations of any constituent, indicating that contamination from sample collection or analysis was not a significant source of bias in the data for the groundwater samples. More than 99 percent of the replicate pair samples were within acceptable limits of variability. Matrix-spike sample recoveries were within the acceptable range (70 to 130 percent) for approximately 91 percent of the compounds. This study did not evaluate the quality of water delivered to consumers. After withdrawal, groundwater typically is treated, disinfected, and (or) blended with other waters to maintain water quality. Regulatory benchmarks apply to water that is delivered to the consumer, not to untreated groundwater. However, to provide some context for the results, concentrations of constituents measured in the untreated groundwater were compared with regulatory and non-regulatory health-based benchmarks established by the U.S. Environmental Protection Agency (USEPA) and CDPH, and to non-health-based benchmarks established for aesthetic concerns by the CDPH. Comparisons between data collected for this study and benchmarks for drinking water are for illustrative purposes only and are not indicative of compliance or non-compliance with those benchmarks. All concentrations of organic constituents from grid sites sampled in the KLAM study unit were less than health-based benchmarks. In total, VOCs were detected in 16 of the 38 grid sites sampled (approximately 42 percent), pesticides and pesticide degradates were detected in 8 grid sites (about 21 percent), and microbial indicators were detected in 14 grid sites (approximately 37 percent). Inorganic constituents (trace elements, major and minor ions, nutrients, and uranium and other radioactive constituents) and microbial indicators were sampled for at 38 grid sites, and all concentrations were less than health-based benchmarks, with the exception of one detection of boron greater than the CDPH notification level of 1,000 micrograms per liter (μg/L). Generally, concentrations of inorganic constituents with non-health-based benchmarks (iron, manganese, chloride, and TDS) were less than the CDPH secondary maximum contaminant level (SMCL-CA). Exceptions include three detections of iron greater than the SMCL-CA of 300 μg/L, four detections of manganese greater than the SMCL-CA of 50 μg/L, one detection of chloride greater than the recommended SMCL-CA of 250 μg/L, and one detection of TDS greater than the recommended SMCL-CA of 500 μg/L.

Identification and level of organochlorine insecticide contamination in groundwater and iridology analysis for people in Upper Citarum cascade

NASA Astrophysics Data System (ADS)

Oginawati, K.; Pratama, M. A.

2016-03-01

Organochlorines are the main pollutants in the class of persistent organic pollutants which are types of pollutants that are being questioned worldwide due to chronic persistence, toxicity and bioaccumulation. Human around the Citarum River are still using groundwater as a drinking source. It is very risky for people health that consume groundwater because in 2009 the application of organochlorine still found in the Upper Citarum watershed rice field and had potential to contaminate groundwater. Groundwater was analyzed with nine species belonging to the organochlorine pollutants Organic Peristent types. 7 types of organochlorinesAldrin was detected with an average concentration of 0.09 ppb, dieldrin with an average concentration of 24 ppb, heptaklor with an average concentration of 0.51 ppb, with concentrations of endosulfan on average 0.73 ppb, DDT with average concentration of 0.13 ppb, Lindan with an average concentration of 1.2 ppb, endrin with an average concentration of 0.03 ppb. Types with the highest concentration of organochlorine a lindan and endosulfan. Residues of aldrin, dieldrin and heptaklor in groundwater already exceeds the quality standards for drinking water Permenkes 492/2010. Based on the iridology analysis obtained several systems are expected to nervous, immune and reproductive system disorders and toxin deposits under the skin.

Origin of hexavalent chromium in groundwater: The example of Sarigkiol Basin, Northern Greece.

PubMed

Kazakis, N; Kantiranis, N; Kalaitzidou, K; Kaprara, E; Mitrakas, M; Frei, R; Vargemezis, G; Tsourlos, P; Zouboulis, A; Filippidis, A

2017-09-01

Hexavalent chromium constitutes a serious deterioration factor for the groundwater quality of several regions around the world. High concentrations of this contaminant have been also reported in the groundwater of the Sarigkiol hydrological basin (near Kozani city, NW Greece). Specific interest was paid to this particular study area due to the co-existence here of two important factors both expected to contribute to Cr(VI) presence and groundwater pollution; namely the area's exposed ophiolitic rocks and its substantial fly ash deposits originating from the local lignite burning power plant. Accordingly, detailed geochemical, mineralogical, hydro-chemical, geophysical and hydrogeological studies were performed on the rocks, soils, sediments and water resources of this basin. Cr(VI) concentrations varied in the different aquifers, with the highest concentration (up to 120μgL -1 ) recorded in the groundwater of the unconfined porous aquifer situated near the temporary fly ash disposal site. Recharge of the porous aquifer is related mainly to precipitation infiltration and occasional surface run-off. Nevertheless, a hydraulic connection between the porous and neighboring karst aquifers could not be delineated. Therefore, the presence of Cr(VI) in the groundwater of this area is thought to originate from both the ophiolitic rock weathering products in the soils, and the local leaching of Cr(VI) from the diffused fly ash located in the area surrounding the lignite power plant. This conclusion was corroborated by factor analysis, and the strongly positively fractionated Cr isotopes (δ 53 Cr up to 0.83‰) recorded in groundwater, an ash leachate, and the bulk fly ash. An anthropogenic source of Cr(VI) that possibly influences groundwater quality is especially apparent in the eastern part of the Sarigkiol basin. Copyright © 2017 Elsevier B.V. All rights reserved.

Temporal trends of selected agricultural chemicals in Iowa's groundwater, 1982-1995: Are things getting better?

USGS Publications Warehouse

Kolpin, D.W.; Sneck-Fahrer, D.; Hallberg, G.R.; Libra, R.D.

1997-01-01

Since 1982, the Iowa Groundwater Monitoring (IGWM) Program has been used to sample untreated groundwater from Iowa municipal wells for selected agricultural chemicals. This long-term database was used to determine if concentrations of select agricultural chemicals in groundwater have changed with time. Nitrate, alachlor [2-chloro-2′-6′-diethyl-N-(methoxymethyl)-acetanilide], atrazine (2-chloro-4-ethylamino-6-isopropylamino-s-triazine), cyanazine [2-[[4-chloro-6-(ethylamino)-1,3,5-triazin-2-yl]amino]-2-methylpropionitrile)], and metolachlor [2-chloro-N-(2-ethyl-6-methylphenyl)-N-(2-methoxy-1-methylethyl) acetamide] were selected for this temporal analysis of the data. Conclusive temporal changes in frequency of detection and median chemical concentrations were found only for atrazine (decrease) and metolachlor (increase). The greatest temporal chemical changes occurred in the shallowest wells and in alluvial aquifers—both relating to groups of wells generally having the youngest groundwater age. The temporal patterns found for atrazine and metolachlor are consistent with their patterns of chemical use and/or application rates and are suggestive of a causal relation. Only continued data collection, however, will indicate if the trends in chemical concentrations described here represent long-term temporal patterns or only short-term changes in groundwater. No definitive answers could be made in regards to the question of overall improvements in groundwater quality with respect to agricultural chemical contamination and time, due to the inherent problems with the simplistic measurement of overall severity (summation of alachlor + atrazine + cyanazine + metolachlor concentrations) examined for this study. To adequately determine if there is an actual decreasing trend in the overall severity of contamination (improving groundwater quality), the collection of additional water-chemistry data and the investigation of other measures of severity are needed.

Fresh Groundwater Resources in Georgia and Management Problems

NASA Astrophysics Data System (ADS)

Gaprindashvili, George; Gaprindashvili, Merab

2015-04-01

Fresh water represents conditioned factor for human body's life. That's why the superiority of drinking water is recognized as human body's priority according to the international declarations. World is experiencing deficit of quality water. Natural Disasters caused by the pollution of the fresh groundwater is also very painful and acute, because it needed more time, more material and financial means for the liquidation of their results, and what the most important practically is, it is impossible to renew the initial natural conditions completely. All these conditions that the rational use of fresh groundwater passed by the interests of separate countries and became worldwide, international problem - fresh water became as considerable raw material for the worlds import and export. The fresh groundwater place the important role among the water recourses of Georgia. Their existing is considerably connected to the development of industry and agriculture, also with water supply issue of populated area. Groundwater management requires precise knowledge of sources (aquifers). Monitoring of Georgia's most important aquifers started many years ago and has provided large amount of data. This was interrupted at the beginning of the 1990s. It could be noted that fresh water existing in the country is distinguished with high quality. According to the mineralization and temperature parameters groundwater is generally divided into the following groups: 1) Fresh drinking waters (mineralization not exceeding 1.0 g/l); 2) Mineral waters (mineralization over 1.0 g/l); 3) Thermal waters -- healing (20˚C - 35˚C), Geothermal (40˚C - 108˚C). Below we present briefly review about the situation of fresh groundwater resources, started recovery of groundwater monitoring network and the analysis of the management problems.

Effects of 1992 farming systems on ground-water quality at the management systems evaluation area near Princeton, Minnesota

USGS Publications Warehouse

Delin, G.N.; Landon, M.K.; Lamb, J.A.; Dowdy, R.H.

1995-01-01

Results indicate that the effects of the 1992 potassium-chloride and N fertilizer applications were reduced compared to the effects of 1991 applications. The most important factors associated with these differences were lower chemical application rates and lower recharge rates during 1992 than during 1991. Some of the chloride and N fertilizer applied to the cropped areas in 1992 likely did not reach the saturated zone in 1993 due to a 60-percent reduction in recharge compared to 1991. Therefore, analysis of data from additional years will be required to fully evaluate the effects of the fanning systems on ground-water quality.

Human interactions with ground-water

USGS Publications Warehouse

Zaporozec, A.

1983-01-01

Ground-Water could be considered as an immense reservoir, from which only a certain amount of water can be withdrawn without affecting the quantity and quality of water. This amount is determined by the characteristics of the environment in which ground-water occurs and by the interactions of ground-water with precipitation, surface water, and people. It should be recognized that quantity and quality of ground-water are intimately related and should be considered accordingly. Quantity refers to usable water and water is usable for any specific purpose only so long as its quality has not deteriorated beyond acceptable limits. Thus an overall quantitative and qualitative management of ground water is inevitable, and its should also involve the uses of ground-water reservoirs for purposes other than water supply. The main objective of ground-water management is to ensure that ground-water resources will be available in appropriate time and in appropriate quantity and quality to meet the most important demands of our society. Traditional, and obvious uses of ground-water are the extraction of water for water supplies (domestic, municipal, agricultural, and industrial) and the natural discharge feeding lakes and maintaining base flow of streams. Not so obvious are the uses of ground-water reservoirs, the very framework within which ground-water occurs and moves, and in which other fluids or materials can be stored. In the last two decades, ground-water reservoirs have been intensively considered for many other purposes than water supplies. Diversified and very often conflicting uses need to be evaluated and dealt with in the most efficient way in order to determine the importance of each possible use, and to assign priorities of these uses. With rising competition for the use of ground-water reservoirs, we will also need to increase the potential for effective planning of ground-water development and protection. Man's development and use of ground-water necessarily modifies the natural conditions and the total natural system must be successfully blended with the unnatural stresses placed upon it. This can be accomplished by introducing new methods (such as ground-water zoning) in and by developing alternative strategies for ground-water management and protection. ?? 1983 D. Reidel Publishing Company.

Assessment of groundwater quality data for the Turtle Mountain Indian Reservation, Rolette County, North Dakota

USGS Publications Warehouse

Lundgren, Robert F.; Vining, Kevin C.

2013-01-01

The Turtle Mountain Indian Reservation relies on groundwater supplies to meet the demands of community and economic needs. The U.S. Geological Survey, in cooperation with the Turtle Mountain Band of Chippewa Indians, examined historical groundwater-level and groundwater-quality data for the Fox Hills, Hell Creek, Rolla, and Shell Valley aquifers. The two main sources of water-quality data for groundwater were the U.S. Geological Survey National Water Information System database and the North Dakota State Water Commission database. Data included major ions, trace elements, nutrients, field properties, and physical properties. The Fox Hills and Hell Creek aquifers had few groundwater water-quality data. The lack of data limits any detailed assessments that can be made about these aquifers. Data for the Rolla aquifer exist from 1978 through 1980 only. The concentrations of some water-quality constituents exceeded the U.S. Environmental Protection Agency secondary maximum contaminant levels. No samples were analyzed for pesticides and hydrocarbons. Numerous water-quality samples have been obtained from the Shell Valley aquifer. About one-half of the water samples from the Shell Valley aquifer had concentrations of iron, manganese, sulfate, and dissolved solids that exceeded the U.S. Environmental Protection Agency secondary maximum contaminant levels. Overall, the data did not indicate obvious patterns in concentrations.

Water-quality observations of the San Antonio segment of the Edwards aquifer, Texas, with an emphasis on processes influencing nutrient and pesticide geochemistry and factors affecting aquifer vulnerability, 2010–16

USGS Publications Warehouse

Opsahl, Stephen P.; Musgrove, MaryLynn; Mahler, Barbara J.; Lambert, Rebecca B.

2018-06-07

As questions regarding the influence of increasing urbanization on water quality in the Edwards aquifer are raised, a better understanding of the sources, fate, and transport of compounds of concern in the aquifer—in particular, nutrients and pesticides—is needed to improve water management decision-making capabilities. The U.S. Geological Survey, in cooperation with the San Antonio Water System, performed a study from 2010 to 2016 to better understand how water quality changes under a range of hydrologic conditions and in contrasting land-cover settings (rural and urban) in the Edwards aquifer. The study design included continuous hydrologic monitoring, continuous water-quality monitoring, and discrete sample collection for a detailed characterization of water quality at a network of sites throughout the aquifer system. The sites were selected to encompass a “source-to-sink” (that is, from aquifer recharge to aquifer discharge) approach. Network sites were selected to characterize rainfall, recharging surface water, and groundwater; groundwater sites included wells in the unconfined part of the aquifer (unconfined wells) and in the confined part of the aquifer (confined wells) and a major discharging spring. Storm-related samples—including rainfall samples, stormwater-runoff (surface-water) samples, and groundwater samples—were collected to characterize the aquifer response to recharge.Elevated nitrate concentrations relative to national background values and the widespread detection of pesticides indicate that the Edwards aquifer is vulnerable to contamination and that vulnerability is affected by factors such as land cover, aquifer hydrogeology, and changes in hydrologic conditions. Greater vulnerability of groundwater in urban areas relative to rural areas was evident from results for urban groundwater sites, which generally had higher nitrate concentrations, elevated δ15N-nitrate values, a greater diversity of pesticides, and higher pesticide concentrations. The continuum of water quality from unconfined rural groundwater sites (least affected by anthropogenic contamination) to unconfined urban groundwater sites (most affected by anthropogenic contamination) demonstrates enhanced vulnerability of urban versus rural land cover. Differences in contaminant occurrences and concentration among unconfined urban wells indicate that the urban parts of the aquifer are not uniformly vulnerable, but rather are affected by spatial differences in the sources of nutrients and pesticides. In urban areas, the shallow, unconfined groundwater sites showed greater temporal variability in both nutrient and pesticide concentrations, as well as a greater degree of contamination, than did deeper, confined groundwater sites. In comparison to that of the shallow, unconfined groundwater sites, the water quality of the deeper, confined groundwater sites was relatively invariant during this multiyear study. Although aquifer hydrogeology is an important factor related to aquifer vulnerability, land cover likely has a greater influence on pesticide contamination of groundwater. Temporal variability in hydrologic conditions for the Edwards aquifer is apparent in data for surface water as a source of groundwater recharge, water-level altitude in wells, spring discharge, and groundwater quality. This temporal variability affects recharge sources, recharge amounts, groundwater traveltimes, flow routing, water-rock interaction processes, dilution, mixing, and, in turn, water quality. Relations of land cover, aquifer hydrogeology, and changing hydrologic conditions to water quality are complex but provide insight into the vulnerability of Edwards aquifer groundwater—a vital drinking-water resource.

Spatial interpolation methods and geostatistics for mapping groundwater contamination in a coastal area.

PubMed

Elumalai, Vetrimurugan; Brindha, K; Sithole, Bongani; Lakshmanan, Elango

2017-04-01

Mapping groundwater contaminants and identifying the sources are the initial steps in pollution control and mitigation. Due to the availability of different mapping methods and the large number of emerging pollutants, these methods need to be used together in decision making. The present study aims to map the contaminated areas in Richards Bay, South Africa and compare the results of ordinary kriging (OK) and inverse distance weighted (IDW) interpolation techniques. Statistical methods were also used for identifying contamination sources. Na-Cl groundwater type was dominant followed by Ca-Mg-Cl. Data analysis indicate that silicate weathering, ion exchange and fresh water-seawater mixing are the major geochemical processes controlling the presence of major ions in groundwater. Factor analysis also helped to confirm the results. Overlay analysis by OK and IDW gave different results. Areas where groundwater was unsuitable as a drinking source were 419 and 116 km 2 for OK and IDW, respectively. Such diverse results make decision making difficult, if only one method was to be used. Three highly contaminated zones within the study area were more accurately identified by OK. If large areas are identified as being contaminated such as by IDW in this study, the mitigation measures will be expensive. If these areas were underestimated, then even though management measures are taken, it will not be effective for a longer time. Use of multiple techniques like this study will help to avoid taking harsh decisions. Overall, the groundwater quality in this area was poor, and it is essential to identify alternate drinking water source or treat the groundwater before ingestion.

Examining the impacts of increased corn production on groundwater quality using a coupled modeling system.

PubMed

Garcia, Valerie; Cooter, Ellen; Crooks, James; Hinckley, Brian; Murphy, Mark; Xing, Xiangnan

2017-05-15

This study demonstrates the value of a coupled chemical transport modeling system for investigating groundwater nitrate contamination responses associated with nitrogen (N) fertilizer application and increased corn production. The coupled Community Multiscale Air Quality Bidirectional and Environmental Policy Integrated Climate modeling system incorporates agricultural management practices and N exchange processes between the soil and atmosphere to estimate levels of N that may volatilize into the atmosphere, re-deposit, and seep or flow into surface and groundwater. Simulated values from this modeling system were used in a land-use regression model to examine associations between groundwater nitrate-N measurements and a suite of factors related to N fertilizer and groundwater nitrate contamination. Multi-variable modeling analysis revealed that the N-fertilizer rate (versus total) applied to irrigated (versus rainfed) grain corn (versus other crops) was the strongest N-related predictor variable of groundwater nitrate-N concentrations. Application of this multi-variable model considered groundwater nitrate-N concentration responses under two corn production scenarios. Findings suggest that increased corn production between 2002 and 2022 could result in 56% to 79% increase in areas vulnerable to groundwater nitrate-N concentrations ≥5mg/L. These above-threshold areas occur on soils with a hydraulic conductivity 13% higher than the rest of the domain. Additionally, the average number of animal feeding operations (AFOs) for these areas was nearly 5 times higher, and the mean N-fertilizer rate was 4 times higher. Finally, we found that areas prone to high groundwater nitrate-N concentrations attributable to the expansion scenario did not occur in new grid cells of irrigated grain-corn croplands, but were clustered around areas of existing corn crops. This application demonstrates the value of the coupled modeling system in developing spatially refined multi-variable models to provide information for geographic locations lacking complete observational data; and in projecting possible groundwater nitrate-N concentration outcomes under alternative future crop production scenarios. Published by Elsevier B.V.

Groundwater conditions in Utah, spring of 2014

USGS Publications Warehouse

Burden, Carole B.; Birken, Adam S.; Gerner, Steven J.; Carricaburu, John P.; Derrick, V. Noah; Downhour, Paul; Smith, Lincoln; Eacret, Robert J.; Gibson, Travis L.; Slaugh, Bradley A.; Whittier, Nickolas R.; Howells, James H.; Christiansen, Howard K.; Fisher, Martel J.

2014-01-01

This is the fifty-first in a series of annual reports that describe groundwater conditions in Utah. Reports in this series, published cooperatively by the U.S. Geological Survey and the Utah Department of Natural Resources, Division of Water Rights, and the Utah Department of Environmental Quality, Division of Water Quality, provide data to enable interested parties to maintain awareness of changing groundwater conditions.This report, like the others in the series, contains information on well construction, groundwater withdrawal from wells, water-level changes, precipitation, streamflow, and chemical quality of water. Information on well construction included in this report refers only to wells constructed for new appropriations of groundwater. Supplementary data are included in reports of this series only for those years or areas that are important to a discussion of changing groundwater conditions and for which applicable data are available.This report includes individual discussions of selected significant areas of groundwater development in the State for calendar year 2013. Most of the reported data were collected by the U.S. Geological Survey in cooperation with the Utah Department of Natural Resources, Division of Water Rights, and the Utah Department of Environmental Quality, Division of Water Quality. This report is also available online at http://www.waterrights.utah.gov/techinfo/ and http://ut.water. usgs.gov/publications/GW2014.pdf. Groundwater conditions in Utah for calendar year 2012 are reported in Burden and others (2013) and are available online at http://ut.water.usgs. gov/publications/GW2013.pdf

Groundwater conditions in Utah, Spring of 2017

USGS Publications Warehouse

Burden, Carole B.

2017-01-01

This is the fifty-fourth in a series of annual reports that describe groundwater conditions in Utah. Reports in this series, published cooperatively by the U.S. Geological Survey and the Utah Department of Natural Resources, Division of Water Rights, and the Utah Department of Environmental Quality, Division of Water Quality, provide data to enable interested parties to maintain awareness of changing groundwater conditions.This report, like the others in the series, contains information on well construction, groundwater withdrawals from wells, water-level changes, precipitation, streamflow, and chemical quality of water. Information on well construction included in this report refers only to new wells constructed for withdrawal of groundwater. Supplementary data are included in reports of this series only for those years or areas that are important to a discussion of changing groundwater conditions and for which applicable data are available.This report includes individual discussions of selected significant areas of groundwater development in the State for calendar year 2016. Most of the reported data were collected by the U.S. Geological Survey in cooperation with the Utah Department of Natural Resources, Division of Water Rights, and the Utah Department of Environmental Quality, Division of Water Quality. This report is also available online at http://www.waterrights.utah.gov/techinfo/ and http://ut.water.usgs.gov/publications/GW2017.pdf. Groundwater conditions in Utah for calendar year 2015 are reported in Burden and others (2016) and are available online at http://ut.water.usgs.gov/publications/GW2016.pdf.

Groundwater conditions in Utah, spring of 2014

USGS Publications Warehouse

Burden, Carole B.

2014-01-01

This is the fifty-first in a series of annual reports that describe groundwater conditions in Utah. Reports in this series, published cooperatively by the U.S. Geological Survey and the Utah Department of Natural Resources, Division of Water Rights, and the Utah Department of Environmental Quality, Division of Water Quality, provide data to enable interested parties to maintain awareness of changing groundwater conditions. This report, like the others in the series, contains information on well construction, groundwater withdrawal from wells, water-level changes, precipitation, streamflow, and chemical quality of water. Information on well construction included in this report refers only to wells constructed for new appropriations of groundwater. Supplementary data are included in reports of this series only for those years or areas that are important to a discussion of changing groundwater conditions and for which applicable data are available.This report includes individual discussions of selected significant areas of groundwater development in the State for calendar year 2013. Most of the reported data were collected by the U.S. Geological Survey in cooperation with the Utah Department of Natural Resources, Division of Water Rights, and the Utah Department of Environmental Quality, Division of Water Quality. This report is also available online at http://www.waterrights.utah.gov/techinfo/ and http://ut.water. usgs.gov/publications/GW2014.pdf. Groundwater conditions in Utah for calendar year 2012 are reported in Burden and others (2013) and are available online at http://ut.water.usgs. gov/publications/GW2013.pdf

Groundwater conditions in Utah, spring of 2013

USGS Publications Warehouse

Burden, Carole B.; Birken, Adam S.; Derrick, V. Noah; Fisher, Martel J.; Holt, Christopher M.; Downhour, Paul; Smith, Lincoln; Eacret, Robert J.; Gibson, Travis L.; Slaugh, Bradley A.; Whittier, Nickolas R.; Howells, James H.; Christiansen, Howard K.

2013-01-01

This is the fiftieth in a series of annual reports that describe groundwater conditions in Utah. Reports in this series, published cooperatively by the U.S. Geological Survey and the Utah Department of Natural Resources, Division of Water Rights, and the Utah Department of Environmental Quality, Division of Water Quality, provide data to enable interested parties to maintain awareness of changing groundwater conditions. This report, like the others in the series, contains information on well construction, groundwater withdrawals from wells, water-level changes, precipitation, streamflow, and chemical quality of water. Information on well construction included in this report refers only to wells constructed for new appropriations of groundwater. Supplementary data are included in reports of this series only for those years or areas that are important to a discussion of changing groundwater conditions and for which applicable data are available.This report includes individual discussions of selected significant areas of groundwater development in the State for calendar year 2012. Most of the reported data were collected by the U.S. Geological Survey in cooperation with the Utah Department of Natural Resources, Division of Water Rights, and the Utah Department of Environmental Quality, Division of Water Quality. This report is also available online at http://www.waterrights.utah.gov/techinfo/ and http://ut.water. usgs.gov/publications/GW2013.pdf. Groundwater conditions in Utah for calendar year 2011 are reported in Burden and others (2012) and available online at http://ut.water.usgs.gov/ publications/GW2012.pdf

Groundwater conditions in Utah, spring of 2012

USGS Publications Warehouse

Burden, Carole B.; Allen, David V.; Holt, Christopher M.; Fisher, Martel J.; Downhour, Paul; Smith, Lincoln; Eacret, Robert J.; Gibson, Travis L.; Slaugh, Bradley A.; Whittier, Nickolas R.; Howells, James H.; Christiansen, Howard K.

2012-01-01

This is the forty-ninth in a series of annual reports that describe groundwater conditions in Utah. Reports in this series, published cooperatively by the U.S. Geological Survey and the Utah Department of Natural Resources, Division of Water Rights, and the Utah Department of Environmental Quality, Division of Water Quality, provide data to enable interested parties to maintain awareness of changing groundwater conditions. This report, like the others in the series, contains information on well construction, groundwater withdrawal from wells, water-level changes, precipitation, streamflow, and chemical quality of water. Information on well construction included in this report refers only to wells constructed for new appropriations of groundwater. Supplementary data are included in reports of this series only for those years or areas that are important to a discussion of changing groundwater conditions and for which applicable data are available.This report includes individual discussions of selected significant areas of groundwater development in the State for calendar year 2011. Most of the reported data were collected by the U.S. Geological Survey in cooperation with the Utah Department of Natural Resources, Division of Water Rights, and the Utah Department of Environmental Quality, Division of Water Quality. This report is also available online at http:// www.waterrights.utah.gov/techinfo/ and http://ut.water.usgs. gov/publications/GW2012.pdf. Groundwater conditions in Utah for calendar year 2010 are reported in Burden and others (2011) and available online at http://ut.water.usgs.gov/ publications/GW2011.pdf.

Groundwater conditions in Utah, spring of 2016

USGS Publications Warehouse

Burden, Carole B.

2016-01-01

This is the fifty-third in a series of annual reports that describe groundwater conditions in Utah. Reports in this series, published cooperatively by the U.S. Geological Survey and the Utah Department of Natural Resources, Division of Water Rights, and the Utah Department of Environmental Quality, Division of Water Quality, provide data to enable interested parties to maintain awareness of changing groundwater conditions. This report, like the others in the series, contains information on well construction, groundwater withdrawals from wells, water-level changes, precipitation, streamflow, and chemical quality of water. Information on well construction included in this report refers only to new wells constructed for withdrawal of groundwater. Supplementary data are included in reports of this series only for those years or areas that are important to a discussion of changing groundwater conditions and for which applicable data are available.This report includes individual discussions of selected significant areas of groundwater development in the State for calendar year 2015. Most of the reported data were collected by the U.S. Geological Survey in cooperation with the Utah Department of Natural Resources, Division of Water Rights, and the Utah Department of Environmental Quality, Division of Water Quality. This report is also available online at http://www.waterrights.utah.gov/techinfo/ and http://ut.water.usgs.gov/publications/GW2016.pdf. Groundwater conditions in Utah for calendar year 2014 are reported in Burden and others (2015) and are available online at http://ut.water.usgs.gov/publications/GW2015.pdf

Assessment of hydrogeochemical status of groundwater in a coastal region of Southeast coast of India

NASA Astrophysics Data System (ADS)

Chidambaram, S.; Sarathidasan, J.; Srinivasamoorthy, K.; Thivya, C.; Thilagavathi, R.; Prasanna, M. V.; Singaraja, C.; Nepolian, M.

2018-03-01

A study was conducted in a coastal region of Cuddalore district of Tamil Nadu, India, to identify the hydrogeochemical processes controlling the groundwater chemistry. The major geological units of the study area are sandstone, clay, alluvium, and laterite soils of Tertiary and Quaternary age. A total of 64 groundwater samples were measured for major ions and stable isotopes. Higher electrical conductivity values indicate the poor quality groundwater along the coastal region. Saline water intrusion mainly affects the hydrochemical composition of the aquifer water reflected by Na-Cl-type waters. Cl-/(Cl- + HCO3 -) ratio also indicates the mixing of fresh groundwater with saline water. The results of δD and δ18O analyses show that isotopic compositions of groundwater ranges from - 7.7 to - 2.1‰ for δ18O and from - 55.6 to - 18.5‰ for δD. Correlation and factor analysis were carried out to find the association of ions and to determine the major factors controlling the groundwater chemistry of the region. The study indicates that ion exchange, weathering, salt water intrusion along the coast, and anthropogenic impacts are the major controlling factors for the groundwater chemistry of the region.

Political ecology of groundwater: the contrasting case of water-abundant West Bengal and water-scarce Gujarat, India

NASA Astrophysics Data System (ADS)

Mukherji, Aditi

2006-03-01

Three apparently disparate themes (groundwater, farmers and politics) interweave in this account of how groundwater-related policies in India have very little to do with the scarcity, depletion or quality of groundwater, and more to do with rural politics manifested, among other things, in terms of the presence or absence of farmer lobbies. Examples from two states of India, the water-abundant state of West Bengal and water-scarce state of Gujarat, were investigated using readily available data, analysis of the literature, interviews and fieldwork. In the case of West Bengal, although there is no pressing groundwater crisis, the government of West Bengal (GOWB) was able to successfully implement strict groundwater regulations along with a drastic increase in electricity tariff. More importantly, GOWB was able to implement these without any form of visible farmer protest, though these measures negatively affected farmer incomes. On the other hand, in Gujarat, where there is a real and grave groundwater crisis, the government of Gujarat has neither been able to implement strict groundwater regulations, nor has it been able to increase electricity tariff substantially. Thus, through the lens of ‘political ecology’ the contrasting case of these two Indian states is explained.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Elvado Environmental LLC

This plan provides a description of the groundwater and surface water quality monitoring activities planned for calendar year (CY) 2009 at the U.S. Department of Energy (DOE) Y-12 National Security Complex (Y-12) that will be managed by the Y-12 Groundwater Protection Program (GWPP). Groundwater and surface water monitoring performed by the GWPP during CY 2009 will be in accordance with DOE Order 540.1 requirements and the following goals: (1) to protect the worker, the public, and the environment; (2) to maintain surveillance of existing and potential groundwater contamination sources; (3) to provide for the early detection of groundwater contamination andmore » determine the quality of groundwater and surface water where contaminants are most likely to migrate beyond the Oak Ridge Reservation property line; (4) to identify and characterize long-term trends in groundwater quality at Y-12; and (5) to provide data to support decisions concerning the management and protection of groundwater resources. Groundwater and surface water monitoring during CY 2009 will be performed primarily in three hydrogeologic regimes at Y-12: the Bear Creek Hydrogeologic Regime (Bear Creek Regime), the Upper East Fork Poplar Creek Hydrogeologic Regime (East Fork Regime), and the Chestnut Ridge Hydrogeologic Regime (Chestnut Ridge Regime). The Bear Creek and East Fork regimes are located in Bear Creek Valley, and the Chestnut Ridge Regime is located south of Y-12 (Figure A.1). Additional surface water monitoring will be performed north of Pine Ridge, along the boundary of the Oak Ridge Reservation. Modifications to the CY 2009 monitoring program may be necessary during implementation. Changes in programmatic requirements may alter the analytes specified for selected monitoring wells or may add or remove wells from the planned monitoring network. All modifications to the monitoring program will be approved by the Y-12 GWPP manager and documented as addenda to this sampling and analysis plan. The following sections of this report provide details regarding the CY 2009 groundwater and surface water monitoring activities. Section 2 describes the monitoring locations in each regime and the processes used to select the sampling locations. A description of the field measurements and laboratory analytes is provided in Section 3; sample collection methods and procedures are described in Section 4; and Section 5 lists the documents cited for more detailed operational and technical information.« less

Analysis of ground-water data for selected wells near Holloman Air Force Base, New Mexico, 1950-95

USGS Publications Warehouse

Huff, G.F.

1996-01-01

Ground-water-level, ground-water-withdrawal, and ground- water-quality data were evaluated for trends. Holloman Air Force Base is located in the west-central part of Otero County, New Mexico. Ground-water-data analyses include assembly and inspection of U.S. Geological Survey and Holloman Air Force Base data, including ground-water-level data for public-supply and observation wells and withdrawal and water-quality data for public-supply wells in the area. Well Douglas 4 shows a statistically significant decreasing trend in water levels for 1972-86 and a statistically significant increasing trend in water levels for 1986-90. Water levels in wells San Andres 5 and San Andres 6 show statistically significant decreasing trends for 1972-93 and 1981-89, respectively. A mixture of statistically significant increasing trends, statistically significant decreasing trends, and lack of statistically significant trends over periods ranging from the early 1970's to the early 1990's are indicated for the Boles wells and wells near the Boles wells. Well Boles 5 shows a statistically significant increasing trend in water levels for 1981-90. Well Boles 5 and well 17S.09E.25.343 show no statistically significant trends in water levels for 1990-93 and 1988-93, respectively. For 1986-93, well Frenchy 1 shows a statistically significant decreasing trend in water levels. Ground-water withdrawal from the San Andres and Douglas wells regularly exceeded estimated ground-water recharge from San Andres Canyon for 1963-87. For 1951-57 and 1960-86, ground-water withdrawal from the Boles wells regularly exceeded total estimated ground-water recharge from Mule, Arrow, and Lead Canyons. Ground-water withdrawal from the San Andres and Douglas wells and from the Boles wells nearly equaled estimated ground- water recharge for 1989-93 and 1986-93, respectively. For 1987- 93, ground-water withdrawal from the Escondido well regularly exceeded estimated ground-water recharge from Escondido Canyon, and ground-water withdrawal from the Frenchy wells regularly exceeded total estimated ground-water recharge from Dog and Deadman Canyons. Water-quality samples were collected from selected Douglas, San Andres, and Boles public-supply wells from December 1994 to February 1995. Concentrations of dissolved nitrate show the most consistent increases between current and historical data. Current concentrations of dissolved nitrate are greater than historical concentrations in 7 of 10 wells.

Presence of faecal indicator bacteria in groundwaters in Kathmandu Valley, Nepal

NASA Astrophysics Data System (ADS)

Nishida, K.; Shrestha, S.; Tanaka, Y.; Haramoto, E.; Nakamura, T.; Osaka, K.; Chapagain, S.

2010-12-01

Groundwater quality is a critical problem in Kathmandu Valley, Nepal. The population of the city increased 6 times in the last six decades and more than half of water demand depends on groundwater resource. Nevertheless, few data of microorganism presence have been reported qualitatively in the central area of the valley. We investigated distribution of faecal indicator bacteria (Total coliforms and Escherichia coli) detected in wells and analyzed the variations of the concentrations. Groundwater samples were collected from 12 deep tube wells (170-300m depths) and 36 shallow tube wells and dug wells (3-20m depths) in Aug 2008, Jan 2009, Aug 2009 and Aug 2010. River waters were also collected for analyzing effect on groundwater quality. E. coli was detected from most of all wells; the concentrations were within 1 log cfu/100mL in deep tube wells and shallow tube wells while those in dug wells ranged from 1 to 3 log cfu/100mL. E. coli was detected at extremely high level in river water, from 5 to 7 log cfu/100mL, however, no clear relation was observed between E. coli concentrations in any types of groundwaters and distance of wells from adjacent rivers. These results indicate that both types of tube wells were rather protected and dug wells were most vulnerable for faecal contamination at very local scale. Genetic analysis of bacterial communities for deep well samples showed the existence of Enterobacter, Acinetobacter as well as Methane-metabolizing groups which provide information of possible indicators other than total coliforms or E. coli for groundwater management in the valley.

Inference of Stream Network Fragmentation Patterns from Ground Water - Surface Water Interactions on the High Plains Aquifer

NASA Astrophysics Data System (ADS)

Chandler, D. G.; Yang, X.; Steward, D. R.; Gido, K.

2007-12-01

Stream networks in the Great Plains integrate fluxes from precipitation as surface runoff in discrete events and groundwater as base flow. Changes in land cover and agronomic practices and development of ground water resources to support irrigated agriculture have resulted in profound changes in the occurrence and magnitude of stream flows, especially near the Ogallala aquifer, where precipitation is low. These changes have demonstrably altered the aquatic habitat of western Kansas, with documented changes in fish populations, riparian communities and groundwater quality due to stream transmission losses. Forecasting future changes in aquatic and riparian ecology and groundwater quality requires a large scale spatially explicit model of groundwater- surface water interaction. In this study, we combine historical data on land use, stream flow, production well development and groundwater level observations with groundwater elevation modeling to support a geospatial framework for assessing changes in refugia for aquatic species in four rivers in western Kansas between 1965 and 2005. Decreased frequency and duration of streamflow occurred in all rivers, but the extent of change depended on the geomorphology of the river basin and the extent of groundwater development. In the absence of streamflow, refugia for aquatic species were defined as the stream reaches below the phreatic surface of the regional aquifer. Changes in extent, location and degree of fragmentation of gaining reaches was found to be a strong predictor of surface water occurrence during drought and a robust hydrological template for the analysis of changes in recharge to alluvial and regional aquifers and riparian and aquatic habitat.

Trace elements in groundwater used for water supply in Latvia

NASA Astrophysics Data System (ADS)

Retike, Inga; Kalvans, Andis; Babre, Alise; Kalvane, Gunta; Popovs, Konrads

2014-05-01

Latvia is rich with groundwater resources of various chemical composition and groundwater is the main drinking source. Groundwater quality can be easily affected by pollution or overexploitation, therefore drinking water quality is an issue of high importance. Here the first attempt is made to evaluate the vast data base of trace element concentrations in groundwater collected by Latvian Environment, Geology and Meteorology Centre. Data sources here range from National monitoring programs to groundwater resources prospecting and research projects. First available historical records are from early 1960, whose quality is impossible to test. More recent systematic research has been focused on the agricultural impact on groundwater quality (Levins and Gosk, 2007). This research was mainly limited to Quaternary aquifer. Monitoring of trace elements arsenic, cadmium and lead was included in National groundwater monitoring program of Latvia in 2008 and 2009, but due to lack of funding the monitoring was suspended until 2013. As a result there are no comprehensive baseline studies regarding the trace elements concentration in groundwater. The aim of this study is to determine natural major and trace element concentration in aquifers mainly used for water supply in Latvia and to compare the results with EU potable water standards. A new overview of artesian groundwater quality will be useful for national and regional planning documents. Initial few characteristic traits of trace element concentration have been identified. For example, elevated fluorine, strontium and lithium content can be mainly associated with gypsum dissolution, but the highest barium concentrations are found in groundwaters with low sulphate content. The groundwater composition data including trace element concentrations originating from heterogeneous sources will be processed and analyzed as a part of a newly developed geologic and hydrogeological data management and modeling system with working name "GeoVipum". This study is supported by the European Social Fund project Nr.2013/0054/2DP/2.1.1.1.0/13/APIA/VIAA/007 in Latvia and European Social Fund Mobilitas grant No MJD309 in Estonia. Reference: Levins I., Gosk, E. 2007. Trace elements in groundwater as indicators of anthropogenic impact. Environmental Geology, 55, 285-290.

Impact of leachate on groundwater pollution due to non-engineered municipal solid waste landfill sites of erode city, Tamil Nadu, India

PubMed Central

2012-01-01

Leachate and groundwater samples were collected from Vendipalayam, Semur and Vairapalayam landfill sites in Erode city, Tamil Nadu, India, to study the possible impact of leachate percolation on groundwater quality. Concentrations of various physicochemical parameters including heavy metals (Cd, Cr, Cu, Fe, Ni, Pb, Fe and Zn) were determined in leachate samples and are reported. The concentrations of Cl-, NO3-, SO42-, NH4+ were found to be in considerable levels in the groundwater samples particularly near to the landfill sites, likely indicating that groundwater quality is being significantly affected by leachate percolation. Further they were proved to be the tracers for groundwater contamination near Semur and Vendipalayam dumpyards. The presence of contaminants in groundwater particularly near the landfill sites warns its quality and thus renders the associated aquifer unreliable for domestic water supply and other uses. Although some remedial measures are suggested to reduce further groundwater contamination via leachate percolation, the present study demands for the proper management of waste in Erode city. PMID:23369323

Water-quality and hydrogeologic data used to evaluate the effects of farming systems on ground-water quality at the Management Systems Evaluation Area near Princeton,Minnesota, 1991-95

USGS Publications Warehouse

Landon, M.K.; Delin, G.N.; Nelson, K.J.; Regan, C.P.; Lamb, J.A.; Larson, S.J.; Capel, P.D.; Anderson, J.L.; Dowdy, R.H.

1997-01-01

The Minnesota Management Systems Evaluation Area (MSEA) project was part of a multi-scale, inter-agency initiative to evaluate the effects of agricultural management systems on water quality in the midwest corn belt. The research area was located in the Anoka Sand Plain about 5 kilometers southwest of Princeton, Minnesota. The ground-water-quality monitoring network within and immediately surrounding the research area consisted of 73 observation wells and 25 multiport wells. The primary objectives of the ground-water monitoring program at the Minnesota MSEA were to: (1) determine the effects of three farming systems on ground-water quality, and (2) understand the processes and factors affecting the loading, transport, and fate of agricultural chemicals in ground water at the site. This report presents well construction, geologic, water-level, chemical application, water-quality, and quality-assurance data used to evaluate the effects of farming systems on ground-water quality during 1991-95.

Assessment of groundwater and soil quality for agricultural purposes in Kopruoren basin, Kutahya, Turkey

NASA Astrophysics Data System (ADS)

Arslan, Sebnem

2017-07-01

This research evaluated the irrigation water and agricultural soil quality in the Kopruoren Basin by using hierarchical cluster analysis. Physico-chemical properties and major ion chemistry of 19 groundwater samples were used to determine the irrigation water quality indices. The results revealed out that the groundwaters are in general suitable for irrigation and have low sodium hazard, although they are very hard in nature due to the dominant presence of Ca+2, Mg+2 and HCO3- ions. Water samples contain arsenic in concentrations below the recommended guidelines for irrigation (59.7 ± 14.7 μg/l), however, arsenic concentrations in 89% of the 9 soil samples exceed the maximum allowable concentrations set for agricultural soils (81 ± 24.3 mg/kg). Nickel element, albeit not present in high concentrations in water samples, is enriched in all of the agricultural soil samples (390 ± 118.2 mg/kg). Hierarchical cluster analysis studies conducted to identify the sources of chemical constituents in water and soil samples elicited that the chemistry of the soils in the study area are highly impacted by the soil parent material and both geogenic and anthropogenic pollution sources are responsible for the metal contents of the soil samples. On the other hand, water chemistry in the area is affected by water-rock interactions, anthropogenic and agricultural pollution.

Integrated assessment of the impact of climate and land use changes on groundwater quantity and quality in the Mancha Oriental system (Spain)

NASA Astrophysics Data System (ADS)

Pulido-Velazquez, M.; Peña-Haro, S.; García-Prats, A.; Mocholi-Almudever, A. F.; Henriquez-Dole, L.; Macian-Sorribes, H.; Lopez-Nicolas, A.

2015-04-01

Climate and land use change (global change) impacts on groundwater systems cannot be studied in isolation. Land use and land cover (LULC) changes have a great impact on the water cycle and contaminant production and transport. Groundwater flow and storage are changing in response not only to climatic changes but also to human impacts on land uses and demands, which will alter the hydrologic cycle and subsequently impact the quantity and quality of regional water systems. Predicting groundwater recharge and discharge conditions under future climate and land use changes is essential for integrated water management and adaptation. In the Mancha Oriental system (MOS), one of the largest groundwater bodies in Spain, the transformation from dry to irrigated lands during the last decades has led to a significant drop of the groundwater table, with the consequent effect on stream-aquifer interaction in the connected Jucar River. Understanding the spatial and temporal distribution of water quantity and water quality is essential for a proper management of the system. On the one hand, streamflow depletion is compromising the dependent ecosystems and the supply to the downstream demands, provoking a complex management issue. On the other hand, the intense use of fertilizer in agriculture is leading to locally high groundwater nitrate concentrations. In this paper we analyze the potential impacts of climate and land use change in the system by using an integrated modeling framework that consists in sequentially coupling a watershed agriculturally based hydrological model (Soil and Water Assessment Tool, SWAT) with a groundwater flow model developed in MODFLOW, and with a nitrate mass-transport model in MT3DMS. SWAT model outputs (mainly groundwater recharge and pumping, considering new irrigation needs under changing evapotranspiration (ET) and precipitation) are used as MODFLOW inputs to simulate changes in groundwater flow and storage and impacts on stream-aquifer interaction. SWAT and MODFLOW outputs (nitrate loads from SWAT, groundwater velocity field from MODFLOW) are used as MT3DMS inputs for assessing the fate and transport of nitrate leached from the topsoil. Three climate change scenarios have been considered, corresponding to three different general circulation models (GCMs) for emission scenario A1B that covers the control period, and short-, medium- and long-term future periods. A multi-temporal analysis of LULC change was carried out, helped by the study of historical trends (from remote-sensing images) and key driving forces to explain LULC transitions. Markov chains and European scenarios and projections were used to quantify trends in the future. The cellular automata technique was applied for stochastic modeling future LULC maps. Simulated values of river discharge, crop yields, groundwater levels and nitrate concentrations fit well to the observed ones. The results show the response of groundwater quantity and quality (nitrate pollution) to climate and land use changes, with decreasing groundwater recharge and an increase in nitrate concentrations. The sequential modeling chain has been proven to be a valuable assessment tool for supporting the development of sustainable management strategies.

Integrated assessment of the impact of climate and land use changes on groundwater quantity and quality in Mancha Oriental (Spain)

NASA Astrophysics Data System (ADS)

Pulido-Velazquez, M.; Peña-Haro, S.; Garcia-Prats, A.; Mocholi-Almudever, A. F.; Henriquez-Dole, L.; Macian-Sorribes, H.; Lopez-Nicolas, A.

2014-09-01

Climate and land use change (global change) impacts on groundwater systems cannot be studied in isolation, as various and complex interactions in the hydrological cycle take part. Land-use and land-cover (LULC) changes have a great impact on the water cycle and contaminant production and transport. Groundwater flow and storage are changing in response not only to climatic changes but also to human impacts on land uses and demands (global change). Changes in future climate and land uses will alter the hydrologic cycles and subsequently impact the quantity and quality of regional water systems. Predicting the behavior of recharge and discharge conditions under future climatic and land use changes is essential for integrated water management and adaptation. In the Mancha Oriental system in Spain, in the last decades the transformation from dry to irrigated lands has led to a significant drop of the groundwater table in one of the largest groundwater bodies in Spain, with the consequent effect on stream-aquifer interaction in the connected Jucar River. Streamflow depletion is compromising the related ecosystems and the supply to the downstream demands, provoking a complex management issue. The intense use of fertilizer in agriculture is also leading to locally high groundwater nitrate concentrations. Understanding the spatial and temporal distribution of water availability and water quality is essential for a proper management of the system. In this paper we analyze the potential impact of climate and land use change in the system by using an integrated modelling framework consisting of the sequentially coupling of a watershed agriculturally-based hydrological model (SWAT) with the ground-water model MODFLOW and mass-transport model MT3D. SWAT model outputs (mainly groundwater recharge and pumping, considering new irrigation needs under changing ET and precipitation) are used as MODFLOW inputs to simulate changes in groundwater flow and storage and impacts on stream-aquifer interaction. SWAT and MODFLOW outputs (nitrate loads from SWAT, groundwater velocity field from MODFLOW) are used as MT3D inputs for assessing the fate and transport of nitrate leached from the topsoil. Results on river discharge, crop yields, groundwater levels and groundwater nitrate concentrations obtained from simulation fit well to the observed values. Three climate change scenarios have been considered, corresponding to 3 different GCMs for emission scenario A1B, covering the control period, and short, medium and long-term future periods. A multi-temporal analysis of LULC change was carried out, helped by the study of historical trends by remote sensing images and key driving forces to explain LULC transitions. Markov chains and European scenarios and projections have been used to quantify trends in the future. The cellular automata technique was applied for stochastic modeling future LULC maps. The results show the sensitivity of groundwater quantity and quality (nitrate pollution) to climate and land use changes, and the need to implement adaptation measures in order to prevent further groundwater level declines and increasing nitrate concentrations. The sequential modelling chain has been proved to be a valuable assessment and management tool for supporting the development of sustainable management strategies.

Analysis of Best Management Practices for Storm Water Compliance at Air Force Airfields

DTIC Science & Technology

1993-09-01

before selecting an infiltration system. These factors include the local vegetation, soil type and condition, groundwater condition, and storm water quality . The...reduce the peak flow rate of storm water discharges and remove sediments in order to improve storm water quality . Detention facilities should be...discharge rate of runoff and/or provide significant detention time to improve storm water quality through natural physical, chemical, and biological

[Heavy metals distribution characteristics and risk assessment of water below an electroplating factory].

PubMed

Hang, Xiao-Shuai; Wang, Huo-Yan; Zhou, Jian-Min

2008-10-01

Surface water and shallow groundwater within the flow of an electroplating factory was analyzed in order to study the resulting impact. The analysis method of ICP-AES was used to analyze content of zinc, manganese, chromium, copper and nickel in surface water and groundwater samples. The results indicate acidic pollutants of zinc, manganese, chromium, copper and nickel were discharged from the factory with concentrations of 1.34, 3.77, 28.1, 6.40 and 9.37 mg x L(-1), respectively; and pH was 2.32. They all exceeded permissible levels according to Integrated Wastewater Discharge Standard except zinc. Factory discharge is responsible for the longitudinal distribution characteristics of heavy metals in the stream water downstream from the factory. Heavy metals variations in the well water do not suggest they were affected by heavy metals in the stream, indicating that the migration rates of heavy metals in soils were relatively low. Risk assessment shows surface water quality significantly deteriorated. Nickel and manganese in the stream water exceeded the standard levels seriously, and chromium and copper in some samples were also above Grade III standard levels according to Environmental Quality Standard for Surface Water. Moreover, all studied heavy metals in 14 groundwater samples measured within drinking water standard, except manganese in 4 groundwater samples, which were Grade IV according to Quality Standard for Ground water.

Hydrogeochemical and vertical electrical soundings for groundwater investigations, Burg El-Arab area, Northwestern Coast of Egypt

NASA Astrophysics Data System (ADS)

Atwia, Mohamed G.; Abu-Heleika, Mohamed M.; El-Horiny, Mohamed M.

2013-04-01

An integrated geological, hydrochemical, and geoelectrical investigation of shallow groundwater occurrence in Burg El-Arab area, northwestern coastal zone of Egypt is carried out. Groundwater of oolitic limestone and clastic aquifers is the principal source of water supply for agriculture in the area. The purpose of this study is to describe the hydrogeologic characteristics of aquifers and to provide a general evaluation of the chemical quality of water in aquifers. Chemical analysis was used to evaluate the chemical characteristics of groundwater and assessment of water quality. Electrical soundings were employed to delineate different water bearing formations and the configuration of the interface between them. Thirty-four water samples were collected and chemically analyzed from the two main aquifers in the area. Groundwaters of oolitic limestone aquifer are dominated by NaCl and have average TDS of approximately 2830 mg/l. Groundwater samples from clastic aquifer are slightly weakly mineralized (TDS approximately 2700 mg/l) and dominated by CaSO4. The hydrochemical data indicate that the groundwater is of meteoric origin. The variation in the chemistry of water is thought to be related to the weathering of minerals of the water-bearing sediments, mixing with marine water, and leaching of fertilizers in the newly reclaimed areas. Groundwater of the area can be used for irrigation under special circumstances management as the sodium hazard is medium while the salinity hazard ranges from high to very high. Thirty-four profiles of vertical electrical soundings (VESs) were obtained in Burg El-Arab area to examine the variations of subsurface geology and associated groundwater chemistry. Resistivity and thickness of aquifers, resistivity of the unsaturated zone and depth to the confining bed have been delineated from the interpretation of electrical sounding data. The range of electrical resistivity values have been assigned to different layers by calibrating electrical resistivity with the borehole data. Results of the vertical electrical soundings and the hydrochemistry of the groundwater samples show that the brackish groundwater is dominated in the study area whereas the fresh groundwater is found as isolated patches in oolitic limestone aquifer.

Effects of Hydrogeologic Conditions on Groundwater Contamination of CVOCs in the North Coast Karst Aquifer of Puerto Rico

NASA Astrophysics Data System (ADS)

Torres Torres, N. I.; Howard, J.; Padilla, I. Y.; Torres, P.; Cotto, I.; Irizarry, C.

2012-12-01

The karst system of northern Puerto Rico is the most productive aquifer of the island. It serves freshwater to industrial, domestic and agricultural purposes, and contributes to the ecological integrity of the region. The same characteristics that make this a highly productive aquifer, make it vulnerable to contamination of groundwater. Of particular importance is contamination with chlorinated volatile organic compounds (CVOCs), which have been related to preterm birth problems. A great extent of CVOC contamination has been seen in the North Coast of Puerto Rico since the 1970s. The main purposes of this study are (1) to relate the water quality of wells and springs with the hydrogeological conditions in the north coast limestone aquifer of Puerto Rico, and (2) to make a statistical analysis of the historical groundwater contamination in that area. To achieve these objectives, groundwater samples are collected from wells and springs during dry and wet seasons. Results show that trichloroethylene (TCE), tetrachloroethylene (PCE) and chloroform (TCM) are frequently detected in groundwater samples. A greater detection of CVOCs is detected during the wet season than the dry season. This is attributed to a greater capacity to flush stored contaminants during the wet season. Historical analysis of contamination in the north coast of Puerto Rico shows a high capacity of the aquifer to store and release contaminants. Future work will be focused the statistical analysis of the historical groundwater contamination data to understand the behavior of the contaminants in different hydrologic conditions.

Agricultural conversion of floodplain ecosystems: implications for groundwater quality.

PubMed

Schilling, Keith E; Jacobson, Peter J; Vogelgesang, Jason A

2015-04-15

With current trends of converting grasslands to row crop agriculture in vulnerable areas, there is a critical need to evaluate the effects of land use on groundwater quality in large river floodplain systems. In this study, groundwater hydrology and nutrient dynamics associated with three land cover types (grassland, floodplain forest and cropland) were assessed at the Cedar River floodplain in southeastern Iowa. The cropland site consisted of newly-converted grassland, done specifically for our study. Our objectives were to evaluate spatial and temporal variations in groundwater hydrology and quality, and quantify changes in groundwater quality following land conversion from grassland to row crop in a floodplain. We installed five shallow and one deep monitoring wells in each of the three land cover types and recorded water levels and quality over a three year period. Crop rotations included soybeans in year 1, corn in year 2 and fallow with cover crops during year 3 due to river flooding. Water table levels behaved nearly identically among the sites but during the second and third years of our study, NO₃-N concentrations in shallow floodplain groundwater beneath the cropped site increased from 0.5 mg/l to more than 25 mg/l (maximum of 70 mg/l). The increase in concentration was primarily associated with application of liquid N during June of the second year (corn rotation), although site flooding may have exacerbated NO₃-N leaching. Geophysical investigation revealed differences in ground conductivity among the land cover sites that related significantly to variations in groundwater quality. Study results provide much-needed information on the effects of different land covers on floodplain groundwater and point to challenges ahead for meeting nutrient reduction goals if row crop land use expands into floodplains. Copyright © 2015 Elsevier Ltd. All rights reserved.

Hydro-chemical Survey and Quantifying Spatial Variations of Groundwater Quality in Dwarka, Sub-city of Delhi, India

NASA Astrophysics Data System (ADS)

Rawat, Kishan Singh; Tripathi, Vinod Kumar

2015-06-01

Hydrological and geological aspect of the region play vital role for water resources utilization and development. Protection and management of groundwater resources are possible with the study of spatio-temporal water quality parameters. The study was undertaken to assess the deterioration in groundwater quality, through systematic sampling during post monsoon seasons of the year 2008 by collecting water samples from thirty bore wells located in Dwarka, sub-city of Delhi, India. The average concentrations of groundwater quality parameters namely Calcium (Ca2+), Magnesium (Mg2+), Nitrate (NO3 -), Chloride (Cl-), sulphate (SO4 2-), total hardness (TH), total dissolved solids (TDS), and electrical conductivity were 300, 178, 26.5, 301, 103, 483, 1042 mg/l and 1909 μS/cm respectively. Estimated physico-chemical parameters revealed that 7 % of the groundwater samples shown nitrate concentrations higher than safe limit prescribed by World Health Organization (WHO). Groundwater quality the in study region was poor due to come out result that NO3 - concentration exceeding the threshold value of 50 mg/l, and main cause is disposal of sewage and animal wastes to Najafgarh drain. Dominant cations are Mg2+, Ca2+ and anions are SO4 2- and Cl-. The abundance of the major ions in groundwater is in the order: Ca2+ > Mg2+ and Cl- > SO4 2- > NO3. TH have strong correlation with Ca2+ (r = 0.81), Mg2+ (r = 0.82), Cl- (r = 0.86) but poor correlation with TDS (r = 0.52). Knowledge of correlation values between water quality parameters is helpful to take decision of appropriate management strategy for controlling groundwater pollution.

Factor weighting in DRASTIC modelling for assessing the groundwater vulnerability in Salatiga groundwater basin, Central Java Province, Indonesia

NASA Astrophysics Data System (ADS)

Kesuma, D. A.; Purwanto, P.; Putranto, T. T.; Rahmani, T. P. D.

2017-06-01

The increase in human population as well as area development in Salatiga Groundwater Basin, Central Java Province, will increase the potency of groundwater contamination in that area. Groundwater quality, especially the shallow groundwater, is very vulnerable to the contamination from industrial waste, fertilizer/agricultural waste, and domestic waste. The first step in the conservation of groundwater quality is by conducting the mapping of the groundwater vulnerability zonation against the contamination. The result of this research was groundwater vulnerability map which showed the areas vulnerable to the groundwater contamination. In this study, groundwater vulnerability map was assessed based on the DRASTIC Method and was processed spatially using Geographic Information System. The DRASTIC method is used to assess the level of groundwater vulnerability based on weighting on seven parameters, which are: depth to the water table (D), recharge (R), aquifer material (A), soil media (S), topography (T), impact of vadose zone (I), and hydraulic conductivity (C). The higher the DRASTIC Index will result in the higher vulnerability level of groundwater contamination in that area. The DRASTIC Indexes in the researched area were 85 - 100 (low vulnerability level), 101 -120 (low to moderate vulnerability level), 121 - 140 (moderate vulnerability level), 141 - 150, (moderate to high vulnerability level), and 151 - 159 (high vulnerability level). The output of this study can be used by local authority as a tool for consideration to arrange the policy for sustainable area development, especially the development in an area affecting the quality of Salatiga Groundwater Basin.

The determination of ground water quality based on the presence of Escherichia coli on populated area (a case study: Pasar Minggu, South Jakarta)

NASA Astrophysics Data System (ADS)

Rohmah, Y.; Rinanti, A.; Hendrawan, D. I.

2018-01-01

This study aims to determine the quality of groundwater in densely populated areas in the Pasar Minggu district, which focuses on examination of Escherichia coli bacteria as biological parameters. E.coli analysis was conducted in 3 sub-districtin the Pasar Minggu district, South Jakarta (106° 45‧0″E - 6° 15‧40″S), which included Pejaten Barat, Jati Padang and Kebagusan sub-district based on topography. The method used is Most Probable Number (MPN), referring to SNI 01-2332.1-2006. The results showed that the presence of E. coli in the highest groundwater ranged from 1100 MPN/100 ml to > 1100 MPN/100 ml, present in Pejaten Barat sub-district (06° 16‧39 "S-106° 49‧48" E) whereas the lowest number ranged from 11.5 MPN/100 ml to 23 MPN/100 ml occurred in Jati Padang sub-district (06° 17‧6 "S - 106° 49‧48" E).The correlation test results show that the amount of E.coli in ground water is affected by the distance of the septic tank to the groundwater well. The amount of E.coli contained in groundwater is also increasing, 1100 MPN/100 ml in groundwater samples at <10 m and < 20 MPN/100 ml in groundwater samples at> 15 m depth. This study provides information that topography and water flow affect the amount of E. coli.

Groundwater-quality data in the northern Coast Ranges study unit, 2009: Results from the California GAMA Program

USGS Publications Warehouse

Mathany, Timothy M.; Dawson, Barbara J.; Shelton, Jennifer L.; Belitz, Kenneth

2011-01-01

This study did not attempt to evaluate the quality of water delivered to consumers; after withdrawal from the ground, untreated groundwater typically is treated, disinfected, and (or) blended with other waters to maintain water quality. Regulatory benchmarks apply to water that is served to the consumer, not to untreated groundwater. However, to provide some context for the results, concentrations of constituents measured in the untreated groundwa

Groundwater-quality data in the Bear Valley and Selected Hard Rock Areas study unit, 2010: Results from the California GAMA Program

USGS Publications Warehouse

Mathany, Timothy M.; Belitz, Kenneth

2013-01-01

Groundwater quality in the 112-square-mile Bear Valley and Selected Hard Rock Areas (BEAR) study unit was investigated by the U.S. Geological Survey (USGS) from April to August 2010, as part of the California State Water Resources Control Board (SWRCB) Groundwater Ambient Monitoring and Assessment (GAMA) Program’s Priority Basin Project (PBP). The GAMA-PBP was developed in response to the California Groundwater Quality Monitoring Act of 2001 and is being conducted in collaboration with the SWRCB and Lawrence Livermore National Laboratory (LLNL). The BEAR study unit was the thirty-first study unit to be sampled as part of the GAMA-PBP. The GAMA Bear Valley and Selected Hard Rock Areas study was designed to provide a spatially unbiased assessment of untreated-groundwater quality in the primary aquifer system and to facilitate statistically consistent comparisons of untreated groundwater quality throughout California. The primary aquifer system is defined as the zones corresponding to the perforation intervals of wells listed in the California Department of Public Health (CDPH) database for the BEAR study unit. Groundwater quality in the primary aquifer system may differ from the quality in the shallow or deep water-bearing zones; shallow groundwater may be more vulnerable to surficial contamination. In the BEAR study unit, groundwater samples were collected from two study areas (Bear Valley and Selected Hard Rock Areas) in San Bernardino County. Of the 38 sampling sites, 27 were selected by using a spatially distributed, randomized grid-based method to provide statistical representation of the primary aquifer system in the study unit (grid sites), and the remaining 11 sites were selected to aid in the understanding of the potential groundwater-quality issues associated with septic tank use and with ski areas in the study unit (understanding sites). The groundwater samples were analyzed for organic constituents (volatile organic compounds [VOCs], pesticides and pesticide degradates, pharmaceutical compounds, and wastewater indicator compounds [WICs]), constituents of special interest (perchlorate, N-nitrosodimethylamine [NDMA], and 1,2,3-trichloropropane [1,2,3-TCP]), and inorganic constituents (trace elements, nutrients, dissolved organic carbon [DOC], major and minor ions, silica, total dissolved solids [TDS], alkalinity, and arsenic and iron species), and uranium and other radioactive constituents (radon-222 and activities of tritium and carbon-14). Isotopic tracers (of hydrogen and oxygen in water, of nitrogen and oxygen in dissolved nitrate, of dissolved boron, isotopic ratios of strontium in water, and of carbon in dissolved inorganic carbon) and dissolved noble gases (argon, helium-4, krypton, neon, and xenon) were measured to help identify the sources and ages of sampled groundwater. In total, groundwater samples were analyzed for 289 unique constituents and 8 water-quality indicators in the BEAR study unit. Quality-control samples (blanks, replicate pairs, or matrix spikes) were collected at 13 percent of the sites in the BEAR study unit, and the results for these samples were used to evaluate the quality of the data from the groundwater samples. Blank samples rarely contained detectable concentrations of any constituent, indicating that contamination from sample collection or analysis was not a significant source of bias in the data for the groundwater samples. Replicate pair samples all were within acceptable limits of variability. Matrix-spike sample recoveries were within the acceptable range (70 to 130 percent) for approximately 84 percent of the compounds. This study did not evaluate the quality of water delivered to consumers. After withdrawal, groundwater typically is treated, disinfected, and (or) blended with other waters to maintain water quality. Regulatory benchmarks apply to water that is delivered to the consumer, not to untreated groundwater. However, to provide some context for the results, concentrations of constituents measured in the untreated groundwater were compared with regulatory and non-regulatory health-based benchmarks established by the U.S. Environmental Protection Agency (USEPA) and CDPH, and to non-health-based benchmarks established for aesthetic concerns by CDPH. Comparisons between data collected for this study and benchmarks for drinking water are for illustrative purposes only and are not indicative of compliance or non-compliance with those benchmarks. All concentrations of organic and special-interest constituents from grid sites sampled in the BEAR study unit were less than health-based benchmarks. In total, VOCs were detected in 17 of the 27 grid sites sampled (approximately 63 percent), pesticides and pesticide degradates were detected in 4 grid sites (approximately 15 percent), and perchlorate was detected in 21 grid sites (approximately 78 percent). Inorganic constituents (trace elements, major and minor ions, nutrients, and uranium and other radioactive constituents) were sampled for at 27 grid sites; most concentrations were less than health-based benchmarks. Exceptions include one detection of arsenic greater than the USEPA maximum contaminant level (MCL-US) of 10 micrograms per liter (μg/L), three detections of uranium greater than the MCL-US of 30 μg/L, nine detections of radon-222 greater than the proposed MCL-US of 4,000 picocuries per liter (pCi/L), and one detection of fluoride greater than the CDPH maximum contaminant level (MCL-CA) of 2 milligrams per liter. Concentrations of inorganic constituents with non-health-based benchmarks (iron, manganese, chloride, and TDS) were less than the CDPH secondary maximum contaminant level (SMCL-CA) in most grid sites. Exceptions include two detections of iron greater than the SMCL-CA of 300 μg/L and one detection of manganese greater than the SMCL-CA of 50 μg/L.

Temporal and spatial variation of groundwater in quantity and quality in sand dune at coastal region, Kamisu city, central Japan.

NASA Astrophysics Data System (ADS)

Umei, Yohei; Tsujimura, Maki; Sakakibara, Koichi; Watanabe, Yasuto; Minema, Motomitsu

2016-04-01

The role of groundwater in integrated water management has become important in recent 10 years, though the surface water is the major source of drinking water in Japan. Especially, it is remarked that groundwater recharge changed due to land cover change under the anthropogenic and climatic condition factors. Therefore, we need to investigate temporal and spatial variation of groundwater in quantity and quality focusing on the change during recent 10-20 years in specific region. We performed research on groundwater level and quality in sand dune at coastal region facing Pacific Ocean, Kamisu city, Ibaraki Prefecture, which have been facing environmental issues, such as land cover change due to soil mining for construction and urbanization. We compared the present situation of groundwater with that in 2000 using existed data to clarify the change of groundwater from 2000 to 2015. The quality of water is dominantly characterized by Ca2+-HCO3- in both 2000 and 2015, and nitrate was not observed in 2015, though it was detected in some locations in 2000. This may be caused by improvement of the domestic wastewater treatment. The topography of groundwater table was in parallel with that of ground surface in 2015, same as that in 2000. However, a depletion of groundwater table was observed in higher elevation area in 2015 as compared with that in 2000, and this area corresponds to the locations where the land cover has changed due to soil mining and urbanization between 2015 and 2000. In the region of soil mining, the original soil is generally replaced by impermeable soil after mining, and this may cause a decrease of percolation and net groundwater recharge, thus the depletion of groundwater table occurred after the soil mining.

Groundwater Recharge Assessment in a Remote Region of Colombia Through Citizen Science

NASA Astrophysics Data System (ADS)

Gomez, A. M.; Wise, E.; Riveros-Iregui, D.

2017-12-01

Understanding water dynamic and storage is essential for decision making in hydrology issues. In remote groundwater-dependent regions affected by population displacement and land over exploitation, especially in developing economies, limited data hinders the production of information necessary to formulate and implement effective water management plans. The community science research approach, which seeks to solve scientific questions with the participation of the community at various levels, represents an opportunity in these regions. We present results of a citizen science project developed to improve the conceptualization of groundwater flow path and to estimate the monthly direct recharge to the shallow aquifer in a remote rural region, the Man River watershed, located in one of the last foothills between the Western and Central Andes cordillera in Colombia. This project was conducted by: i) implementing a water level monitoring network aided by the community to collect weekly data from 2007 to 2010; ii) comparing the precipitation data and water table time series to identify the response of the shallow aquifer to the wet season; iii) conceptualizing specific groundwater-surface interactions through water table spatial analysis; and iv) estimating direct groundwater recharge using the Water Table Fluctuation method. Water quality test results were shared with the local community. Results show that groundwater interacts with the main tributaries to the Man River. Two scenarios were identified related to water table temporal behavior: (1) the water table rises during the transition from the dry to the wet season (between March and April), and (2) it increases one month after this transition. In general, groundwater levels descend in November, which is the end of the wet season. The work with the community provided useful insights for interpreting the collected data and allowed for information exchange concerning the groundwater quality and methods for improving the sanitary conditions of the dug wells. This project represents a valuable strategy for adding information to the hydrogeological conceptual model at low cost. It also provides opportunities for the implementation of a more informed water management plan while improving water quality and accessibility at the domestic household level.

Prediction of Groundwater Quality Trends Resulting from Anthropogenic Changes in Southeast Florida.

PubMed

Yi, Quanghee; Stewart, Mark

2018-01-01

The effects of surface water flow system changes caused by constructing water-conservation areas and canals in southeast Florida on groundwater quality under the Atlantic Coastal Ridge was investigated with numerical modeling. Water quality data were used to delineate a zone of groundwater with low total dissolved solids (TDS) within the Biscayne aquifer under the ridge. The delineated zone has the following characteristics. Its location generally coincides with an area where the Biscayne aquifer has high transmissivities, corresponds to a high recharge area of the ridge, and underlies a part of the groundwater mound formed under the ridge prior to completion of the canals. This low TDS groundwater appears to be the result of pre-development conditions rather than seepage from the canals constructed after the 1950s. Numerical simulation results indicate that the time for low TDS groundwater under the ridge to reach equilibrium with high TDS surface water in the water-conservation areas and Everglades National Park are approximately 70 and 60 years, respectively. The high TDS groundwater would be restricted to the water-conservation areas and the park due to its slow eastward movement caused by small hydraulic gradients in Rocky Glades and its mixing with the low TDS groundwater under the high-recharge area of the ridge. The flow or physical boundary conditions such as high recharge rates or low hydraulic conductivity layers may affect how the spatial distribution of groundwater quality in an aquifer will change when a groundwater flow system reaches equilibrium with an associated surface water flow system. © 2017, National Ground Water Association.

Interactions of water quality and integrated groundwater management: exampled from the United States

USDA-ARS?s Scientific Manuscript database

Groundwater is available in many parts of the world, but the quality of the water may limit its use. Contaminants can limit the use of groundwater through concerns associated with human health, aquatic health, economic costs, or even societal perception. Given this broad range of concerns, this chap...

Environmental impacts on the hydrology of ephemeral streams and alluvial aquifers

NASA Astrophysics Data System (ADS)

Kuells, C.; Marx, V.; Bittner, A.; Ellmies, R.; Seely, M.

2009-04-01

In arid and semi-arid regions alluvial groundwater resources of ephemeral streams are highly important for water supplies and ecosystems. Recent projects have studied processes of indirect recharge in situ and in detail (Dahan et al., 2008; Klaus et al., 2008). Still, little is known about the vulnerability of these aquifers to environmental impacts like surface dam constructions, land-use changes and climatic conditions as well as the time and type of response to such external impacts. With a catchment size of about 30.000 km² the Swakop River in Namibia is the largest of the country's twelve major ephemeral streams draining westwards into the Atlantic Ocean. The alluvial groundwater resources have been affected by the construction of two major surface water dams in the upper catchment as well as by abstractions for rural water supply, farming and mining downstream of the constructed dams (referred to as lower catchment). The determination of environmental impacts in the Swakop River catchment is difficult due to scarce hydrometric and water quality data. In order to obtain a better understanding of the hydrological system under changing environmental conditions a spatially distributed environmental tracer approach was applied. A longitudinal profile of groundwater samples was taken within a field study along the alluvial aquifer of the Swakop River. The samples were analysed for stable isotopes (18O, 2H), major ions and trace elements as well as for the residence time indicators CFC and SF6. The combined application of groundwater residence time analysis, stable isotope measurements and hydrochemical characterisation was used in order to associate a time scale with groundwater quality data. This method provides dated information on recharge and water quality before and after dam construction and can be used to detect environmental impacts on the hydrological system. CFC-12 analysis resulted in recharge years ranging from 1950 (0.01 pmol/l) to 1992 (1.4 pmol/l). Seven of 14 groundwater samples represent mainly groundwater recharged before or between the construction of surface water dams (1970 and 1978), the remaining samples represent groundwater recharge after dam construction. The groundwater residence time is generally short (recharge mainly after 1980) in the upper catchment and much higher (recharge mainly before 1980 and before dam construction) in the lower part of the catchment. Combining the age and isotope information shows how the surface water dams modified the pattern of groundwater recharge. The lower catchment has been partly cut off from the upper part in terms of indirect groundwater recharge by floods which means that most large floods originating in the headwaters of the Swakop River do not reach the lower alluvial aquifer anymore. The relationship between groundwater age and groundwater constituents helped to define baselines of hydrological properties (origin of water, recharge altitude) and of hydrochemical composition prior to the construction of dams (and other anthropogenic impacts). The well defined relationship between groundwater age and altitude of the river further helps to assess how fast different segments will be affected by these environmental impacts. References Dahan, O., Tatarsky, B., Enzel, Y., Kuells, C., Seely, M., Benito, G. (2008) Dynamics of Flood Water Infiltration and Ground Water Recharge in Hyperarid Desert. Ground Water, Vol. 46, 3. (6-2008), pp. 450-461. Klaus, J., Kuells, C., Dahan, O. (2008): Evaluating the recharge mechanism of the Lower Kuiseb Dune Area using mixing cell modeling and residence time data. Journal of Hydrology, v. 358, p. 304-316.

Hydrogeochemistry and water quality of the Kordkandi-Duzduzan plain, NW Iran: application of multivariate statistical analysis and PoS index.

PubMed

Soltani, Shahla; Asghari Moghaddam, Asghar; Barzegar, Rahim; Kazemian, Naeimeh; Tziritis, Evangelos

2017-08-18

Kordkandi-Duzduzan plain is one of the fertile plains of East Azarbaijan Province, NW of Iran. Groundwater is an important resource for drinking and agricultural purposes due to the lack of surface water resources in the region. The main objectives of the present study are to identify the hydrogeochemical processes and the potential sources of major, minor, and trace metals and metalloids such as Cr, Mn, Cd, Fe, Al, and As by using joint hydrogeochemical techniques and multivariate statistical analysis and to evaluate groundwater quality deterioration with the use of PoS environmental index. To achieve these objectives, 23 groundwater samples were collected in September 2015. Piper diagram shows that the mixed Ca-Mg-Cl is the dominant groundwater type, and some of the samples have Ca-HCO 3 , Ca-Cl, and Na-Cl types. Multivariate statistical analyses indicate that weathering and dissolution of different rocks and minerals, e.g., silicates, gypsum, and halite, ion exchange, and agricultural activities influence the hydrogeochemistry of the study area. The cluster analysis divides the samples into two distinct clusters which are completely different in EC (and its dependent variables such as Na + , K + , Ca 2+ , Mg 2+ , SO 4 2- , and Cl - ), Cd, and Cr variables according to the ANOVA statistical test. Based on the median values, the concentrations of pH, NO 3 - , SiO 2 , and As in cluster 1 are elevated compared with those of cluster 2, while their maximum values occur in cluster 2. According to the PoS index, the dominant parameter that controls quality deterioration is As, with 60% of contribution. Samples of lowest PoS values are located in the southern and northern parts (recharge area) while samples of the highest values are located in the discharge area and the eastern part.

Preliminary development of a GIS-tool to assess threats to shallow groundwater quality from soil pollutants in Glasgow, UK (GRASP).

NASA Astrophysics Data System (ADS)

Dochartaigh, B. É. Ó.; Fordyce, F. M.; Ander, E. L.; Bonsor, H. C.

2009-04-01

The protection of groundwater and related surface water quality is a key aspect of the European Union Water Framework Directive and environmental legislation in many countries worldwide. Globally, the protection of urban groundwater resources and related ecosystem services is of growing concern as urbanisation increases. Although urban areas are often where groundwater resources are most in need of protection, there is frequently a lack of information about threats to groundwater quality. Most studies of soil and groundwater contamination, although detailed, are site-specific, and city-wide overviews are generally lacking. The British Geological Survey (BGS) is currently undertaking the Clyde Urban Super-Project (CUSP), delivering multi-disciplinary geoscience products for the Glasgow conurbation. Under this project, a GIS-based prioritisation tool known as GRASP (GRoundwater And Soil Pollutants) has been trialled to aid urban planning and sustainable development by providing a broad-scale assessment of threats to groundwater quality across the conurbation. GRASP identifies areas where shallow groundwater quality is at greatest threat from the leaching and downward movement of potentially harmful metals in the soil. Metal contamination is a known problem in many urban centres including Glasgow, which has a long industrial heritage and associated contamination legacy, notably with respect to Cr. GRASP is based primarily upon an existing British Standard - International Standards Organisation methodology to determine the leaching potential of metals from soils, which has been validated for 11 metals: Al, Fe, Cd, Co, Cr, Cu, Hg, Ni, Mn, Pb and Zn (BS-ISO 15175:2004). However, the GRASP tool is innovative as it combines assessments of soil leaching potential with soil metal content data to highlight threats to shallow groundwater quality. The input parameters required for GRASP (soil pH, clay, organic matter, sesquioxide and metal content) are based upon a systematic geochemical dataset of 1600 soils (4 per km2) collected across Glasgow as part of the BGS Geochemical Baseline Survey of the Environment (G-BASE) project. These parameters are combined with assessments of climate, groundwater levels and the leaching potential of unsaturated Quaternary deposits to produce maps that prioritise the likely threats to shallow groundwater quality. Data processing for the GRASP methodology is carried out in five steps in Microsoft Excel®, using Visual Basic® programming language, and ArcGIS® software. The GRASP prioritisation tool is in the process of development; however, the rationale and initial derivation of the methodology for the city of Glasgow will be presented.

An integrated approach to asses origin and mobilization of As, Fe and Mn in groundwater: the case study of Cremona (northern Italy)

NASA Astrophysics Data System (ADS)

Rotiroti, Marco; Bonomi, Tullia; Fumagalli, Letizia

2013-04-01

The present work concerns the analysis of the hydrogeology and the hydrogeochemistry of the As, Fe, Mn rich groundwater of the alluvial multi-layer aquifer in the lower Po Plain of Cremona (northern Italy). In this analysis, an integrated approach is applied in order to understand the origins (natural or anthropic) and chemical mechanisms of high groundwater As, Fe and Mn concentrations found in the study area. The study area covers a 50 km2 wide area around the urban territory of Cremona. It is located near the confluence between Adda and Po rivers. The multi-aquifer system which interests the first 200-250 m of depth is investigated. The integrated approach involves the (a) collection of historical data related to water quality, water levels and well logs; (b) storage of collected data in specific databases and geographical information systems; (c) design and execution of two field surveys of water levels and water quality, realized in July 2010 and July 2012, concerning also groundwater sampling for isotope and microbiological analysis; (d) construction of a 3D model of aquifer hydrogeological properties (deposits texture, hydraulic conductivity and effective porosity), built by means of ordinary kriging interpolation of numerical values derived from the coding of well logs; (e) analysis of the hydrodynamic properties of the system on the basis of the field measurements; (f) analysis of water quality data (both field and historical data) considering the hydrogeological and hydrodynamic properties of the aquifer system; (g) analysis of isotope and microbiological measurements; (h) implementation of a 1D reactive transport model in order to better understand the hydrogeochemical mechanisms in the system; (i) elaboration of a general hydrogeochemical conceptual model concerning possible origins and chemical mechanisms for the high groundwater As, Fe, Mn and NH4 concentrations, considering also possible anthropogenic influences; (j) development of management tools, as natural background levels (NBL) derivation, supporting groundwater resources protection by public authorities. This approach allows to assume the process of natural organic matter degradation (i.e. peat) as primary control factor on high As, Fe, Mn and NH4 concentrations. Degradation of peat is associated with the consecutive reduction of O2, NO3-, Mn(IV), Fe(III), SO42-, CO2. The reductive dissolution of Mn and Fe oxides (contained in the aquifer sediments) leads to high concentrations of dissolved Fe and Mn, but also to high concentrations of dissolved As, which is generally sorbed on Mn and Fe oxides. Dissolved As concentration can be also lowered by different processes (co-precipitation of As in iron sulfides, precipitation of arsenic sulfides, sorption of As on the remaining Fe-oxides and Mn-oxides, etc.). NH4 is released from the degradation of organic nitrogen of peat. Therefore, a natural origin of As, Fe, Mn and NH4 can be assumed. In addiction, anthropogenic influences on groundwater As, Fe, Mn and NH4 concentrations are locally identified in two sites located in the study area, that are affected by hydrocarbons and organic leachate pollution.

Groundwater-Quality Data in the Antelope Valley Study Unit, 2008: Results from the California GAMA Program

USGS Publications Warehouse

Schmitt, Stephen J.; Milby Dawson, Barbara J.; Belitz, Kenneth

2009-01-01

Groundwater quality in the approximately 1,600 square-mile Antelope Valley study unit (ANT) was investigated from January to April 2008 as part of the Priority Basin Project of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The GAMA Priority Basin Project was developed in response to the Groundwater Quality Monitoring Act of 2001, and is being conducted by the U.S. Geological Survey (USGS) in cooperation with the California State Water Resources Control Board (SWRCB). The study was designed to provide a spatially unbiased assessment of the quality of raw groundwater used for public water supplies within ANT, and to facilitate statistically consistent comparisons of groundwater quality throughout California. Samples were collected from 57 wells in Kern, Los Angeles, and San Bernardino Counties. Fifty-six of the wells were selected using a spatially distributed, randomized, grid-based method to provide statistical representation of the study area (grid wells), and one additional well was selected to aid in evaluation of specific water-quality issues (understanding well). The groundwater samples were analyzed for a large number of organic constituents (volatile organic compounds [VOCs], gasoline additives and degradates, pesticides and pesticide degradates, fumigants, and pharmaceutical compounds), constituents of special interest (perchlorate, N-nitrosodimethylamine [NDMA], and 1,2,3-trichloropropane [1,2,3-TCP]), naturally occurring inorganic constituents (nutrients, major and minor ions, and trace elements), and radioactive constituents (gross alpha and gross beta radioactivity, radium isotopes, and radon-222). Naturally occurring isotopes (strontium, tritium, and carbon-14, and stable isotopes of hydrogen and oxygen in water), and dissolved noble gases also were measured to help identify the sources and ages of the sampled groundwater. In total, 239 constituents and water-quality indicators (field parameters) were investigated. Quality-control samples (blanks, replicates, and samples for matrix spikes) were collected at 12 percent of the wells, and the results for these samples were used to evaluate the quality of the data for the groundwater samples. Field blanks rarely contained detectable concentrations of any constituent, suggesting that contamination was not a noticeable source of bias in the data for the groundwater samples. Differences between replicate samples generally were within acceptable ranges, indicating acceptably low variability. Matrix spike recoveries were within acceptable ranges for most compoundsThis study did not evaluate the quality of water delivered to consumers; after withdrawal from the ground, water typically is treated, disinfected, or blended with other waters to maintain water quality. Regulatory thresholds apply to water that is served to the consumer, not to raw groundwater. However, to provide some context for the results, concentrations of constituents measured in the raw groundwater were compared with regulatory and non-regulatory health-based thresholds established by the U.S. Environmental Protection Agency (USEPA) and California Department of Public Health (CDPH) and thresholds established for aesthetic concerns (secondary maximum contaminant levels, SMCL-CA) by CDPH. Comparisons between data collected for this study and drinking-water thresholds are for illustrative purposes only, and are not indicative of compliance or non-compliance with drinking water standards. Most constituents that were detected in groundwater samples were found at concentrations below drinking-water thresholds. Volatile organic compounds (VOCs) were detected in about one-half of the samples and pesticides detected in about one-third of the samples; all detections of these constituents were below health-based thresholds. Most detections of trace elements and nutrients in samples from ANT wells were below health-based thresholds. Exceptions include: one detection of nitrite plus nitr

Groundwater-Quality Data in the Colorado River Study Unit, 2007: Results from the California GAMA Program

USGS Publications Warehouse

Goldrath, Dara A.; Wright, Michael T.; Belitz, Kenneth

2010-01-01

Groundwater quality in the 188-square-mile Colorado River Study unit (COLOR) was investigated October through December 2007 as part of the Priority Basin Project of the California State Water Resources Control Board (SWRCB) Groundwater Ambient Monitoring and Assessment (GAMA) Program. The GAMA Priority Basin Project was developed in response to the Groundwater Quality Monitoring Act of 2001, and the U.S. Geological Survey (USGS) is the technical project lead. The Colorado River study was designed to provide a spatially unbiased assessment of the quality of raw groundwater used for public water supplies within COLOR, and to facilitate statistically consistent comparisons of groundwater quality throughout California. Samples were collected from 28 wells in three study areas in San Bernardino, Riverside, and Imperial Counties. Twenty wells were selected using a spatially distributed, randomized grid-based method to provide statistical representation of the Study unit; these wells are termed 'grid wells'. Eight additional wells were selected to evaluate specific water-quality issues in the study area; these wells are termed `understanding wells.' The groundwater samples were analyzed for organic constituents (volatile organic compounds [VOC], gasoline oxygenates and degradates, pesticides and pesticide degradates, pharmaceutical compounds), constituents of special interest (perchlorate, 1,4-dioxane, and 1,2,3-trichlorpropane [1,2,3-TCP]), naturally occurring inorganic constituents (nutrients, major and minor ions, and trace elements), and radioactive constituents. Concentrations of naturally occurring isotopes (tritium, carbon-14, and stable isotopes of hydrogen and oxygen in water), and dissolved noble gases also were measured to help identify the sources and ages of the sampled groundwater. In total, approximately 220 constituents and water-quality indicators were investigated. Quality-control samples (blanks, replicates, and matrix spikes) were collected at approximately 30 percent of the wells, and the results were used to evaluate the quality of the data obtained from the groundwater samples. Field blanks rarely contained detectable concentrations of any constituent, suggesting that contamination was not a significant source of bias in the data. Differences between replicate samples were within acceptable ranges and matrix-spike recoveries were within acceptable ranges for most compounds. This study did not attempt to evaluate the quality of water delivered to consumers; after withdrawal from the ground, raw groundwater typically is treated, disinfected, or blended with other waters to maintain acceptable water quality. Regulatory thresholds apply to water that is served to the consumer, not to raw groundwater. However, to provide some context for the results, concentrations of constituents measured in the raw groundwater were compared to regulatory and nonregulatory health-based thresholds established by the U.S. Environmental Protection Agency (USEPA) and the California Department of Public Health (CDPH) and to thresholds established for aesthetic concerns by CDPH. Comparisons between data collected for this study and drinking-water thresholds are for illustrative purposes only and do not indicate compliance or noncompliance with those thresholds. The concentrations of most constituents detected in groundwater samples were below drinking-water thresholds. Volatile organic compounds (VOC) were detected in approximately 35 percent of grid well samples; all concentrations were below health-based thresholds. Pesticides and pesticide degradates were detected in about 20 percent of all samples; detections were below health-based thresholds. No concentrations of constituents of special interest or nutrients were detected above health-based thresholds. Most of the major and minor ion constituents sampled do not have health-based thresholds; the exception is chloride. Concentrations of chloride, sulfate, and total dis

Using groundwater age to understand sources and dynamics of nutrient contamination through the catchment into Lake Rotorua, New Zealand

NASA Astrophysics Data System (ADS)

Morgenstern, U.; Daughney, C. J.; Leonard, G.; Gordon, D.; Donath, F. M.; Reeves, R.

2014-08-01

The water quality of Lake Rotorua has declined continuously over the past 50 yr despite mitigation efforts over recent decades. Delayed response of the groundwater discharges to historic land-use intensification 50 yr ago was the reason suggested by early tritium measurements, which indicated large transit times through the groundwater system. We use the isotopic and chemistry signature of the groundwater for detailed understanding of the origin, fate, flow pathways, lag times, and future loads of contaminants. A unique set of high-quality tritium data over more than four decades, encompassing the time when the tritium spike from nuclear weapons testing moved through the groundwater system, allows us to determine detailed age distribution parameters of the water discharging into Lake Rotorua. The Rotorua volcanic groundwater system is complicated due to the highly complex geology that has evolved through volcanic activity. Vertical and steeply-inclined geological contacts preclude a simple flow model. The extent of the Lake Rotorua groundwater catchment is difficult to establish due to the deep water table in large areas, combined with inhomogeneous groundwater flow patterns. Hierarchical cluster analysis of the water chemistry parameters provided evidence of the recharge source of the large springs near the lake shore, with discharge from the Mamaku ignimbrite through lake sediment layers. Groundwater chemistry and age data show clearly the source of nutrients that cause lake eutrophication, nitrate from agricultural activities and phosphate from geologic sources. With a naturally high phosphate load reaching the lake continuously via all streams, the only effective way to limit algae blooms and improve lake water quality in such environments is by limiting the nitrate load. The groundwater in the Rotorua catchment, once it has passed through the soil zone, shows no further decrease in dissolved oxygen, indicating absence of electron donors in the aquifer that could facilitate microbial denitrification reactions. Nitrate from land-use activities that leaches out of the root zone of agricultural land into the deeper part of the groundwater system must be expected to travel with the groundwater to the lake. The old age and the highly mixed nature of the water discharges imply a very slow and lagged response of the streams and the lake to anthropogenic contaminants in the catchment, such as nitrate. Using the age distribution as deduced from tritium time series data measured in the stream discharges into the lake allows prediction of future nutrient loads from historic land-use activities 50 yr ago. For Hamurana Stream, the largest stream to Lake Rotorua, it takes more than a hundred years for the groundwater-dominated stream discharge to adjust to changes in land-use activities. These time scales apply to activities that cause contamination, but also to remediation action.

Agriculture-related trends in groundwater quality of the glacial deposits aquifer, central Wisconsin

USGS Publications Warehouse

Saad, D.A.

2008-01-01

Measuring and understanding trends in groundwater quality is necessary for determining whether changes in land-management practices have an effect on groundwater quality. This paper describes an approach that was used to measure and understand trends using data from two groundwater studies conducted in central Wisconsin as part of the USGS NAWQA program. One of the key components of this approach, determining the age of sampled groundwater, gave a temporal component to the snapshots of water quality that were obtained through synoptic-sampling efforts. This approach can be used at other locations where groundwater quality data are collected, groundwater age can be determined, and associated temporal data are available. Results of these studies indicate measured concentrations of nitrate and atrazine plus deethylatrazine were correlated to historical patterns of fertilizer and atrazine use. Concentrations of nitrate in groundwater have increased over time; concentrations of atrazine plus deethylatrazine increased and then decreased. Concentrations of nitrate also were correlated to screen depth below the water level and concentrations of dissolved O2; concentrations of atrazine plus deethylatrazine were correlated to dissolved O2 and annual precipitation. To measure trends in concentrations of atrazine plus deethylatrazine, the data, collected over a near-decadal period, were adjusted to account for changes in laboratory-reporting levels and analytical recoveries. Only after accounting for these changes was it apparent that the median concentrations of atrazine plus deethylatrazine decreased over the near-decadal interval between sampling efforts. Copyright ?? 2008 by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America. All rights reserved.

U.S. Geological Survey ground-water studies in Missouri

USGS Publications Warehouse

Smith, B.J.

1993-01-01

The activities of the USGS Water Resources Division in Missouri are conducted by scientists, technicians, and support staff in offices in Rolla, Olivette, and Independence. During 1992, the USGS had cooperative or cost-sharing agreements with about 30 Federal, State, and local agencies involving 20 hydrologic investigations in Missouri; 12 of these investigations included studies of groundwater quantity and quality. Several examples of groundwater studies by the USGS that address specific groundwater issues in Missouri include the occurrence of pesticides, groundwater flow and quality in the Missouri River alluvium near Kansas City, groundwater flow in claypan soils, radioactive- and nitroaromatic-compound contami- nation at Weldon Spring, and hydrologic monitoring of a wetland complex. (USGS)

Water quality assessment for groundwater around a municipal waste dumpsite.

PubMed

Kayode, Olusola T; Okagbue, Hilary I; Achuka, Justina A

2018-04-01

The dataset for this article contains geostatistical analysis of the level to which groundwater quality around a municipal waste dumpsite located in Oke-Afa, Oshodi/Isolo area of Lagos state, southwestern has been compromised for drinking. Groundwater samples were collected from eight hand-dug wells and two borehole wells around or near the dumpsite. The pH, turbidity, salinity, conductivity, total hydrocarbon, total dissolved solids (TDS), dissolved oxygen, chloride, Sulphate (SO 4 ), Nitrate (NO 3 ) and Phosphate (PO 4 ) were determined for the water samples and compared with World Health Organization (WHO) drinking water standard. Notably, the turbidity, TDS, chloride and conductivity of some of the samples were above the WHO acceptable limits. Also, high quantities of heavy metals such as Aluminum and Barium were also present as shown from the data. The dataset can provide insights into the health implications of the contaminants especially when the mean concentration levels of the contaminants are above the recommended WHO drinking water standard.

The Soils and Groundwater – EM-20 S&T Roadmap Quality Assurance Project Plan

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fix, N. J.

The Soils and Groundwater – EM-20 Science and Technology Roadmap Project is a U.S. Department of Energy, Office of Environmental Management-funded initiative designed to develop new methods, strategies and technology for characterizing, modeling, remediating, and monitoring soils and groundwater contaminated with metals, radionuclides, and chlorinated organics. This Quality Assurance Project Plan provides the quality assurance requirements and processes that will be followed by EM-20 Roadmap Project staff.

Hydrogeology and ground-water/surface water interactions in the Des Moines River valley, southwestern Minnesota, 1997-2001

USGS Publications Warehouse

Cowdery, Timothy K.

2005-01-01

Long-term withdrawals of water for public supplies may cause a net decrease in ground-water discharge to surface water. Water that does not evaporate, or that is not exported, is discharged to the Des Moines River but with changed water quality. Because ground-water and surface-water qualities in the study area are similar, the ground-water discharge probably has little effect on river water quality.

Quality of ground water in the Payette River basin, Idaho

USGS Publications Warehouse

Parliman, D.J.

1986-01-01

As part of a study to obtain groundwater quality data in areas of Idaho were land- and water-resource development is expected to increase, water quality, geologic, and hydrologic data were collected for 74 wells in the Payette River basin, west-central Idaho, from July to October 1982. Historical (pre-1982) data from 13 wells were compiled with more recent (1982) data to define, on a reconnaissance level, water quality conditions in major aquifers and to identify factors that may have affected groundwater quality. Water from the major aquifers generally contains predominantly calcium, magnesium, and bicarbonate plus carbonate ions. Sodium and bicarbonate or sulfate are the predominant ions in groundwater from 25% of the 1982 samples. Areally, groundwater from the upper Payette River basin has proportionately lower ion concentrations than water from the lower Payette River basin. Water samples from wells < 100 ft deep generally have lower ion concentrations than samples from wells > 100 ft deep. Variations in groundwater quality probably are most affected by differences in aquifer composition and proximity to source(s) of recharge. Groundwater in the study area is generally suitable for most uses. In localized areas, pH and concentrations of hardness, alkalinity, dissolved solids, or dissolved nitrite plus nitrate as nitrogen, sulfate, fluoride, iron, or manganese exceed Federal drinking water limits and may restrict some uses of the water.

Surface-Water, Water-Quality, and Ground-Water Assessment of the Municipio of Mayaguez, Puerto Rico, 1999-2002

USGS Publications Warehouse

Rodríguez-Martínez, Jesús; Santiago-Rivera, Luis; Guzman-Rios, Senen; Gómez-Gómez, Fernando; Oliveras-Feliciano, Mario L.

2004-01-01

The surface-water assessment portion of this study focused on analysis of low-flow characteristics in local streams and rivers, because the supply of safe drinking water was a critical issue during recent dry periods. Low-flow characteristics were evaluated at one continuous-record gaging station based on graphical curve-fitting techniques and log-Pearson Type III frequency curves. Estimates of low-flow characteristics for 20 partial-record stations were generated using graphical-correlation techniques. Flow-duration characteristics for the continuous- and partial-record stations were estimated using the relation curves developed for the low-flow study. Stream low-flow statistics document the general hydrology under current land use, water-use, and climatic conditions. A survey of streams and rivers utilized 37 sampling stations to evaluate the sanitary quality of about 165 miles of stream channels. River and stream samples for fecal coliform and fecal streptococcus analyses were collected on two occasions at base-flow conditions. Bacteriological analyses indicate that a significant portion of the stream reaches within the municipio of Mayaguez may have fecal coliform bacteria concentrations above the water-quality goal (standard) established by the Puerto Rico Environmental Quality Board (Junta de Calidad Ambiental de Puerto Rico) for inland surface waters. Sources of fecal contamination may include: illegal discharge of sewage to storm-water drains, malfunctioning sanitary sewer ejectors, clogged and leaking sewage pipes, septic tank leakage, unfenced livestock, and runoff from livestock pens. Long-term fecal coliform data from five sampling stations located within or in the vicinity of the municipio of Mayaguez have been in compliance with the water-quality goal for fecal coliform concentration established in July 1990. Geologic, topographic, soil, hydrogeologic, and streamflow data were compiled into a database and used to divide the municipio of Mayaguez into five hydrogeologic terranes. This integrated database then was used to evaluate the ground-water potential of each hydrogeologic terrane. Lineament-trace analysis was used to help assess the ground-water development potential in the hydrogeologic terranes containing igneous rocks. Analyses suggest that areas with slopes greater than 15 degrees have relatively low ground-water development potential. The presence of fractures, independent of the topographic slope, may locally enhance the water-bearing properties in the hydrogeologic terranes containing igneous rocks. The results of this study indicate that induced streamflow generally is needed to sustain low to moderate ground-water withdrawal rates in the five hydrogeologic terranes. The ground-water flow systems in the hydrogeologic terranes are only able to sustain small withdrawal rates that rarely exceed 50 gallons per minute. Areas with a high density of fractures, as could be the case at the intersection of lineament traces in the upper parts of the Rio Ca?as and Rio Yaguez watersheds, are worthy of exploratory drilling for ground-water development.

From Global to Local and Vice Versa: On the Importance of the `Globalization' Agenda in Continental Groundwater Research and Policy-Making

NASA Astrophysics Data System (ADS)

Filimonau, Viachaslau; Barth, Johannes A. C.

2016-09-01

Groundwater is one of the most important environmental resources and its use continuously rises globally for industrial, agricultural, and drinking water supply purposes. Because of its importance, more knowledge about the volume of usable groundwater is necessary to satisfy the global demand. Due to the challenges in quantifying the volume of available global groundwater, studies which aim to assess its magnitude are limited in number. They are further restricted in scope and depth of analysis as, in most cases, they do not explain how the estimates of global groundwater resources have been obtained, what methods have been used to generate the figures and what levels of uncertainty exist. This article reviews the estimates of global groundwater resources. It finds that the level of uncertainty attached to existing numbers often exceeds 100 % and strives to establish the reasons for discrepancy. The outcome of this study outlines the need for a new agenda in water research with a more pronounced focus on groundwater. This new research agenda should aim at enhancing the quality and quantity of data provision on local and regional groundwater stocks and flows. This knowledge enhancement can serve as a basis to improve policy-making on groundwater resources globally. Research-informed policies will facilitate more effective groundwater management practices to ensure a more rapid progress of the global water sector towards the goal of sustainability.

Quality of groundwater resources in Afghanistan.

PubMed

Hayat, Ehsanullah; Baba, Alper

2017-07-01

Water is the main source of energy production and economy in Afghanistan where agriculture accounts for more than 50% of the country's gross domestic product (GDP). Access to safe drinking water is still a problem in the country, which has caused different health issues and even child mortality especially in rural areas. Groundwater is the main source of drinking water in the country. However, little knowledge is available about the quality of groundwater throughout the entire country, and its quality has not been investigated extensively yet like in other countries in the world. While most people think that consuming groundwater is a reliable and safe source of drinking water for health, the United Nations (UN) agencies report various kinds of waterborne diseases and even child mortalities due to drinking water quality in the country. In this article, significant geogenic and anthropogenic factors that play a vital role in groundwater contamination of the country are identified and explained. Different geogenic contaminations such as arsenic, fluoride, sulfate, and boron occur in several areas of Afghanistan that have a direct effect on human health. The water quality mapping for Afghanistan is completed for half of the country, which shows that groundwater is plagued by high levels of fluoride and arsenic in some areas. The water quality mapping of the other half of the country cannot be completed due to security concerns currently. Also, there are different kinds of waterborne diseases such as diarrhea, cholera, and dysentery that can be seen in different parts of the country because of anthropogenic activities which continuously deteriorate groundwater.

Automated ground-water monitoring with Robowell: case studies and potential applications

NASA Astrophysics Data System (ADS)

Granato, Gregory E.; Smith, Kirk P.

2002-02-01

Robowell is an automated system and method for monitoring ground-water quality. Robowell meets accepted manual- sampling protocols without high labor and laboratory costs. Robowell periodically monitors and records water-quality properties and constituents in ground water by pumping a well or multilevel sampler until one or more purge criteria have been met. A record of frequent water-quality measurements from a monitoring site can indicate changes in ground-water quality and can provide a context for the interpretation of laboratory data from discrete samples. Robowell also can communicate data and system performance through a remote communication link. Remote access to ground-water data enables the user to monitor conditions and optimize manual sampling efforts. Six Robowell prototypes have successfully monitored ground-water quality during all four seasons of the year under different hydrogeologic conditions, well designs, and geochemical environments. The U.S. Geological Survey is seeking partners for research with robust and economical water-quality monitoring instruments designed to measure contaminants of concern in conjunction with the application and commercialization of the Robowell technology. Project publications and information about technology transfer opportunities are available on the Internet at URL http://ma.water.usgs.gov/automon/

Automated ground-water monitoring with robowell-Case studies and potential applications

USGS Publications Warehouse

Granato, G.E.; Smith, K.P.; ,

2001-01-01

Robowell is an automated system and method for monitoring ground-water quality. Robowell meets accepted manual-sampling protocols without high labor and laboratory costs. Robowell periodically monitors and records water-quality properties and constituents in ground water by pumping a well or multilevel sampler until one or more purge criteria have been met. A record of frequent water-quality measurements from a monitoring site can indicate changes in ground-water quality and can provide a context for the interpretation of laboratory data from discrete samples. Robowell also can communicate data and system performance through a remote communication link. Remote access to ground-water data enables the user to monitor conditions and optimize manual sampling efforts. Six Robowell prototypes have successfully monitored ground-water quality during all four seasons of the year under different hydrogeologic conditions, well designs, and geochemical environments. The U.S. Geological Survey is seeking partners for research with robust and economical water-quality monitoring instruments designed to measure contaminants of concern in conjunction with the application and commercialization of the Robowell technology. Project publications and information about technology transfer opportunities are available on the Internet at URL http://ma.water.usgs.gov/automon/.

Assessment of shrimp farming impact on groundwater quality using analytical hierarchy process

NASA Astrophysics Data System (ADS)

Anggie, Bernadietta; Subiyanto, Arief, Ulfah Mediaty; Djuniadi

2018-03-01

Improved shrimp farming affects the groundwater quality conditions. Assessment of shrimp farming impact on groundwater quality conventionally has less accuracy. This paper presents the implementation of Analytical Hierarchy Process (AHP) method for assessing shrimp farming impact on groundwater quality. The data used is the impact data of shrimp farming in one of the regions in Indonesia from 2006-2016. Criteria used in this study were 8 criteria and divided into 49 sub-criteria. The weighting by AHP performed to determine the importance level of criteria and sub-criteria. Final priority class of shrimp farming impact were obtained from the calculation of criteria's and sub-criteria's weights. The validation was done by comparing priority class of shrimp farming impact and water quality conditions. The result show that 50% of the total area was moderate priority class, 37% was low priority class and 13% was high priority class. From the validation result impact assessment for shrimp farming has been high accuracy to the groundwater quality conditions. This study shows that assessment based on AHP has a higher accuracy to shrimp farming impact and can be used as the basic fisheries planning to deal with impacts that have been generated.

Ground-water quality and geochemistry of Las Vegas Valley, Clark County, Nevada, 1981-83; implementation of a monitoring network

USGS Publications Warehouse

Dettinger, M.D.

1987-01-01

As a result of rapid urban growth in Las Vegas Valley, rates of water use and wastewater disposal have grown rapidly during the last 25 years. Concern has developed over the potential water quality effects of this growth. The deep percolation of wastewater and irrigation return flow (much of which originates as imported water from Lake Mead), along with severe overdraft conditions in the principal aquifers of the valley, could combine to pose a long-term threat to groundwater quality. The quantitative investigations of groundwater quality and geochemical conditions in the valley necessary to address these concerns would include the establishment of data collection networks on a valley-wide scale that differ substantially from existing networks. The valley-wide networks would have a uniform areal distribution of sampling sites, would sample from all major depth zones, and would entail repeated sampling from each site. With these criteria in mind, 40 wells were chosen for inclusion in a demonstration monitoring network. Groundwater in the northern half of the valley generally contains 200 to 400 mg/L of dissolved solids, and is dominated by calcium, magnesium , and bicarbonate ions, reflecting a chemical equilibrium between the groundwater and the dominantly carbonate rocks in the aquifers of this area. The intermediate to deep groundwater in the southern half of the valley is of poorer quality (containing 700 to 1,500 mg/L of dissolved solids) and is dominated by calcium, magnesium, sulfate, and bicarbonate ions, reflecting the occurrence of other rock types including evaporite minerals among the still-dominant carbonate rocks in the aquifers of this part of the valley. The poorest quality groundwater in the valley is generally in the lowland parts of the valley in the first few feet beneath the water table, where dissolved solids concentrations range from 2,000 to > 7,000 mg/L , and probably reflects the effects of evaporite dissolution, secondary recharge, and evapotranspiration. The most common water quality constraint on potential groundwater use is the high salinity. No evidence of large-scale contamination of deep groundwater was found in this study. (Author 's abstract)

Effects of a constructed wetland and pond system upon shallow groundwater quality

Treesearch

Ying Ouyang

2013-01-01

Constructed wetland (CW) and constructed pond (CP) are commonly utilized for removal of excess nutrients and certain pollutants from stormwater. This study characterized shallow groundwater quality for pre- and post-CW and CP system conditions using data from monitoring wells. Results showed that the average concentrations of groundwater phosphorus (P) decreased from...

Groundwater recharge in suburban areas of Hanoi, Vietnam: effect of decreasing surface-water bodies and land-use change

NASA Astrophysics Data System (ADS)

Kuroda, Keisuke; Hayashi, Takeshi; Do, An Thuan; Canh, Vu Duc; Nga, Tran Thi Viet; Funabiki, Ayako; Takizawa, Satoshi

2017-05-01

Over-exploited groundwater is expected to remain the predominant source of domestic water in suburban areas of Hanoi, Vietnam. In order to evaluate the effect on groundwater recharge, of decreasing surface-water bodies and land-use change caused by urbanization, the relevant groundwater systems and recharge pathways must be characterized in detail. To this end, water levels and water quality were monitored for 3 years regarding groundwater and adjacent surface-water bodies, at two typical suburban sites in Hanoi. Stable isotope (δ18O, δD of water) analysis and hydrochemical analysis showed that the water from both aquifers and aquitards, including the groundwater obtained from both the monitoring wells and the neighboring household tubewells, was largely derived from evaporation-affected surface-water bodies (e.g., ponds, irrigated farmlands) rather than from rivers. The water-level monitoring results suggested distinct local-scale flow systems for both a Holocene unconfined aquifer (HUA) and Pleistocene confined aquifer (PCA). That is, in the case of the HUA, lateral recharge through the aquifer from neighboring ponds and/or irrigated farmlands appeared to be dominant, rather than recharge by vertical rainwater infiltration. In the case of the PCA, recharge by the above-lying HUA, through areas where the aquitard separating the two aquifers was relatively thin or nonexistent, was suggested. As the decrease in the local surface-water bodies will likely reduce the groundwater recharge, maintaining and enhancing this recharge (through preservation of the surface-water bodies) is considered as essential for the sustainable use of groundwater in the area.

Water quality impacts from on-site waste disposal systems to coastal areas through groundwater discharge

NASA Astrophysics Data System (ADS)

Harris, P. J.

1995-12-01

This report summarizes research studies linking on-site waste disposal systems (OSDS) to pathogen and nutrient concentrations in groundwater with the potential to impact coastal embayments. Few studies connect OSDS to coastal water quality. Most studies examined pathogen and nutrient impacts to groundwater and omitted estimations of contaminants discharged to surface water. The majority of studies focused on nitrogen, with little information on pathogens and even less on phosphorus. Nitrogen discharged from OSDS poses the greatest threat to water quality. Vertical distance of septic tank infiltration system from the water table, septic system design, and siting remain the key components in minimizing potential impacts from OSDS for control of both pathogens and nutrients. The most comprehensive information connecting nutrient contributions from OSDS to surface water quality was the study conducted on Buttermilk Bay in Massachusetts where 74% of nitrogen to the bay was attributed to onsite disposal systems. In conclusion, further studies on the viability and transport of pathogens and nutrients through the groundwater aquifer and across the groundwater/surface-water interface are needed. Additional research on the importance of septic system design on the availability of contaminants to groundwater as well as the minimum distance between the septic system and water table necessary to protect groundwater are also indicated.

Impact of changes in land use on the ground-water system in the Sequim-Dungeness Peninsula, Clallam County, Washington

USGS Publications Warehouse

Drost, B.W.

1983-01-01

A digital-computer model was developed to simulate three-dimensional ground-water flow in aquifers underlying the Sequim-Dungeness peninsula, Clallam County, Washington. Analysis using the model shows that leakage from irrigation ditches is the area 's most important source of ground-water recharge. Termination of the irrigation system would lead to lower heads throughout the ground-water system. After 10-20 years of no irrigation, the water-table aquifer would have average drawdowns of about 20 feet and some areas would become completely unsaturated. Several hundred wells could be in danger of going dry. If irrigation were terminated, leakage from the Dungeness River would become the major source of ground-water recharge. As of June 1980, ground-water quality has apparently not been affected in the study area by the use of on-site domestic sewage-disposal systems. The median nitrate-plus-nitrite (as N) concentration in the water-table aquifer was 0.25 milligrams per liter, and the maximum concentration was 2.5 milligrams per liter. (USGS)

Development of a microbial contamination susceptibility model for private domestic groundwater sources

NASA Astrophysics Data System (ADS)

Hynds, Paul D.; Misstear, Bruce D.; Gill, Laurence W.

2012-12-01

Groundwater quality analyses were carried out on samples from 262 private sources in the Republic of Ireland during the period from April 2008 to November 2010, with microbial quality assessed by thermotolerant coliform (TTC) presence. Assessment of potential microbial contamination risk factors was undertaken at all sources, and local meteorological data were also acquired. Overall, 28.9% of wells tested positive for TTC, with risk analysis indicating that source type (i.e., borehole or hand-dug well), local bedrock type, local subsoil type, groundwater vulnerability, septic tank setback distance, and 48 h antecedent precipitation were all significantly associated with TTC presence (p < 0.05). A number of source-specific design parameters were also significantly associated with bacterial presence. Hierarchical logistic regression with stepwise parameter entry was used to develop a private well susceptibility model, with the final model exhibiting a mean predictive accuracy of >80% (TTC present or absent) when compared to an independent validation data set. Model hierarchies of primary significance are source design (20%), septic tank location (11%), hydrogeological setting (10%), and antecedent 120 h precipitation (2%). Sensitivity analysis shows that the probability of contamination is highly sensitive to septic tank setback distance, with probability increasing linearly with decreases in setback distance. Likewise, contamination probability was shown to increase with increasing antecedent precipitation. Results show that while groundwater vulnerability category is a useful indicator of aquifer susceptibility to contamination, its suitability with regard to source contamination is less clear. The final model illustrates that both localized (well-specific) and generalized (aquifer-specific) contamination mechanisms are involved in contamination events, with localized bypass mechanisms dominant. The susceptibility model developed here could be employed in the appropriate location, design, construction, and operation of private groundwater wells, thereby decreasing the contamination risk, and hence health risk, associated with these sources.

[Influence of human activities on groundwater environment based on coefficient variation method].

PubMed

Zhao, Wei; Lin, Jian; Wang, Shu-Fang; Liu, Ji-Lai; Chen, Zhong-Rong; Kou, Wen-Jie

2013-04-01

Groundwater system in the plain area of Beijing can be divided into six subsystems. Due to the different hydrogeological conditions of the subsystems, the degrees to which human activities affect the subsystems are also diverse. In order to evaluate the influence of human activities on each subsystem, the first and second aquifer with relatively poor water quality were chosen to be the evaluating positions, based on the data of groundwater sampled in September, 2011. With respect to human activities affect index such as total hardness, TDS, sulfate and ammonium, variation coefficient methods were used to calculate the weight of each index. Then scores were obtained for each index with national standard as reference, and superposition calculations were used to gain comprehensive scores, finally the groundwater quality conditions were evaluated. Contrast analyses were used to evaluate the incidence of human activities with groundwater subsystems as evaluation unit and water quality partitions as evaluation factors. The results indicate that the influence of human activities on the first aquifer is greater than that of the second aquifer, the Yongding river groundwater subsystems and the Chaobai river groundwater subsystems are affected more than other groundwater subsystems.

Geomorphology and its implication in urban groundwater environment: case study from Mumbai, India

NASA Astrophysics Data System (ADS)

Rani, V. R.; Pandalai, H. S.; Sajinkumar, K. S.; Pradeepkumar, A. P.

2015-06-01

Landforms of Mumbai Island have been largely modified by the urban sprawl and the demand for groundwater will increase exponentially in the future. Quality and quantity of groundwater occurrence in island are highly influenced by the geomorphic units. As this metropolis receives heavy rainfall, the area rarely faces the issue of water scarcity, nevertheless, quality always remains a question. The landforms of Mumbai Island have been shaped by a combination of fluvial, denudational and marine processes. These landforms are categorized into two broad zones on the basis of its influence in groundwater occurrence. Denudational landforms are categorized as runoff zones whereas the other two are categorized as storage zones. This classification is on the basis of occurrence and storage of groundwater. Mumbai Island is exposed to frequent sea water incursion and groundwater quality has deteriorated. The varied hydrogeological conditions prevalent in this area prevent rapid infiltration. This combined with the overextraction of groundwater resources for agriculture and industry has caused serious concern about the continued availability of potable water. This study aims at validating the geomorphic classification of the landforms with hydrogeochemistry and borehole data and it proved that geomorphology corroborates with groundwater chemistry and subsurface geology.

Deep groundwater quantity and quality in the southwestern US

NASA Astrophysics Data System (ADS)

Kang, M.; Ayars, J. E.; Jackson, R. B.

2017-12-01

Groundwater demands are growing in many arid regions and adaptation through the use of non-traditional resources during extreme droughts is increasingly common. One such resource is deep groundwater, which we define as deeper than 300 m and up to several kilometer-depths. Although deep groundwater has been studied in the context of oil and gas, geothermal, waste disposal, and other uses, it remains poorly characterized, especially for the purposes of human consumption and irrigation uses. Therefore, we evaluate deep groundwater quantity and quality within these contexts. We compile and analyze data from water management agencies and oil and gas-based sources for the southwestern US, with a detailed look at California's Central Valley. We also use crop tolerance thresholds to evaluate deep groundwater quality for irrigation purposes. We find fresh and usable groundwater volume estimates in California's Central Valley to increase by three- and four-fold respectively when depths of up to 3 km are considered. Of the ten basins in the southwestern US with the most data, we find that the Great Basin has the greatest proportions of fresh and usable deep groundwater. Given the potentially large deep groundwater volumes, it is important to characterize the resource, guard against subsidence where extracted, and protect it for use in decades and centuries to come.

Modeling impacts of change in Landuse/ Landcover on groundwater system in Shiwaliks of Punjab using Remote Sensing and GIS

NASA Astrophysics Data System (ADS)

Singh, C. K.; Mukherjee, S.; Shashtri, S.

2009-04-01

The dependency of people has increased on groundwater due to tremendous increase in crop production, population and industrialization in past few decades. The groundwater is the main source of irrigation in Shiwaliks of Punjab. Loss of massive forest cover in Shiwaliks is resulting in drying-up of several sub-rivers and natural stream, as a result, the groundwater availability in Punjab is drastically hampered. At present Jayanti, Budki, Siswan the three major tributaries of river Satluj flowing through the district of Rupnagar have disappeared. Since infiltration, recharge, accumulation, and flow of ground water is controlled by various geological, morphological, topographical and other surface parameters by different degrees, study and analysis of these parameters provide vital clues and knowledge about groundwater occurrence and recharge. The characteristic of groundwater is reflected on the soil and vegetation of the surface above it in unconfined aquifers. Hence, the characteristics of the groundwater at a particular area can be determined to a particular extent, by its surface manifestation in terms of the landuse/ landcover pattern. This is the basis on which the classification of the images was performed by using clustering algorithms, that examine the unknown pixels in an image and aggregate them into a number of classes based on the natural groupings or clusters present in the image values. Unsupervised classification was performed on landsat images of year 1989, 2000 and LISS III image of 2005. In the last two decades we observed certain trends that were not very encouraging from environmental viewpoint. Primary among these are the trends displayed by area under river, dense forest, cropland and settlements. In the first three categories there is a continuous decrease with the ultimate difference accruing to around 17% and 22% and 31% respectively, the fourth field, which is settlement, has registered an alarming increase of 534%. The effect of gradually increasing influence of green revolution is continuously being manifested in the form of escalating area under salinization; the total increase being registered is around 94%. The areas lying within the vicinity of river have shown concentrations of several heavy metals to be higher than the desirable limits. Impact of agriculture has also shown alarming increase in nitrate concentration in some of the areas. Thematic maps for geology, geomorphology, slope, drainage, lineament density, distance from the lineaments, soil type, were prepared using GIS platform and a suitability analysis was performed for quantitative variation of groundwater in the study area. Several water quality parameters were analyzed and to observe spatial variation of suitability of groundwater in terms of quality a water quality index (WQI) was generated. Parameters such as relative humidity, temperature and rainfall for the last two decades were also analyzed in relation to decline in level of groundwater.

Ground-water levels, water quality, and potential effects of toxic-substance spills or cessation of quarry dewatering near a municipal ground-water supply, southeastern Franklin County, Ohio

USGS Publications Warehouse

Sedam, A.C.; Eberts, S.M.; Bair, E.S.

1989-01-01

A newly completed municipal ground-water supply that produces from a sand and gravel aquifer in southern Franklin County, Ohio, may be susceptible to potential sources of pollution. Among these are spills of toxic substances that could enter recharge areas of the aquifer or be carried by surface drainage and subsequently enter the aquifer by induced infiltration. Ground water of degraded quality also is present in the vicinity of several landfills located upstream from the municipal supply. Local dewatering by quarrying operations has created a ground-water divide which, at present, prevents direct movement of the degraded ground water to the municipal supply. In addition, the dewatering has held water levels at the largest landfills below the base of the landfill. Should the dewatering cease, concern would be raised regarding the rise of water levels at this landfills and transport of contaminants through the aquifer to the Scioto River and subsequently by the river to the well field. From June 1984 through July 1986, the U.S. Geological Survey, in cooperation with the City of Columbus, Ohio, investigated the relations among the ground-water supply and potential sources of contamination by means of an observation-well network and a program of measuring water levels and sampling for water quality. Sample collections included those made to determine the baseline levels of organic chemicals and metals, as well as periodic sampling and analysis for common constituents to evaluate any changes taking place in the system. Finally, a steady-state, three-dimensional numerical model was used to determine ground-water flow directions and average ground-water velocities to asses potential effects of toxic-substance spills. The model also was used to simulate changes in the ground-water flow system that could result if part or all of the quarry dewatering ceased. Few of the organic-chemical and metal constituents analyzed for were present at detectable levels. With respect to chemical analysis of water and soil materials reported in earlier studies, no new problem areas were discovered as a result of either the baseline or periodic samplings. Model simulations suggest that, under March 1986 conditions, a toxic-substance spill along the major highways in the northern two-thirds of the study area eventually could discharge into one of the two quarries being dewatered or into the Scioto River. A toxic-substance spill in the southern one-third of the study area ultimately may discharge into the Scioto River, Big Walnut Creek, or possibly into the municipal ground-water supply. Model simulations also indicate that concentrated landfill leachate probably would not reach the municipal ground-water supply under current or well-field pumping conditions if dewatering ceased at either or both of the quarries.

Groundwater quality in alluvial and prolluvial areas under the influence of irrigated agriculture activities.

PubMed

Kovacevik, Biljana; Boev, Blazo; Panova, Vesna Zajkova; Mitrev, Sasa

2016-12-05

The aim of this study was to investigate the groundwater pollution from alluvial aquifers lying under surface agriculture activities in two geologically different areas: alluvial and prolluvial. The groundwater in investigated areas is neutral to alkaline (pH 7.05-8.45), and the major dissolved ions are bicarbonate and calcium. Groundwater samples from the alluvial area are characterized by nitrate concentration above the national maximum concentration limit (MCL) at 20.5% of samples [mean value (Me) 6.31 mg/L], arsenic concentrations greater than national MCL at 35.6% of investigated samples (Me 12.12 µg/L) and elevated concentrations of iron (Me 202.37 µg/L) and manganese (Me 355.22 µg/L) at 22.7% and 81% of investigated samples, respectively. Groundwater samples from the prolluvial area did not show significantly elevated concentrations of heavy metals, but the concentration of nitrate was considerably higher (Me 65.06 mg/L). Factor analysis positively correlates As with Mn and Fe, suggesting its natural origin. Nitrate was found in positive correlation with SO 4 2- and Ni but in negative with NH 4 + , suggesting its anthropogenic origin and the relationship of these ions in the process of denitrification. The t-test analysis showed a significant difference between nitrate pollution of groundwater from alluvial and prolluvial areas. According to the chemical composition of groundwater, the process of denitrification is considered to be the main reason for the reduced presence of nitrate in the groundwater lying under alluvial deposits represented by chalk and sandstones. Denitrification in groundwater lying under prolluvial deposits represented by magmatic and metamorphic rock formations was not observed.

Quality of ground water around Vadnais Lake and in Lambert Creek watershed, and interaction of ground water with Vadnais Lake, Ramsey County, Minnesota

USGS Publications Warehouse

Ruhl, J.F.

1994-01-01

The results of the seepage analysis and ground-water quality evaluation indicate that the effect of the quality of the surrounding ground water on the quality of Vadnais Lake probably was small. Ground water that discharged to the lake generally had lower concentrations of calcium, magnesium, bicarbonate, and total dissolved solids than the lake. The mixing of ground water with the lake slightly diluted the lake with respect to these constituents.

Western USA groundwater drilling

NASA Astrophysics Data System (ADS)

Jasechko, S.; Perrone, D.

2016-12-01

Groundwater in the western US supplies 40% of the water used for irrigated agriculture, and provides drinking water to individuals living in rural regions distal to perennial rivers. Unfortunately, current groundwater use is not sustainable in a number of key food producing regions. While substantial attention has been devoted to mapping groundwater depletion rates across the western US, the response of groundwater users via well drilling to changing land uses, water demands, pump and drilling technologies, pollution vulnerabilities, and economic conditions remains unknown. Here we analyze millions of recorded groundwater drilling events in the western US that span years 1850 to 2015. We show that groundwater wells are being drilled deeper in some, but not all, regions where groundwater levels are declining. Groundwater wells are generally deeper in arid and mountainous regions characterized by deep water tables (e.g., unconfined alluvial and fractured bedrock aquifers), and in regions that have productive aquifers with high water quality deep under the ground (e.g., confined sedimentary aquifers). Further, we relate water quality and groundwater drilling depths in 40 major aquifer systems across the western US. We show that there is substantial room for improvement to the existing 2-D continental-scale assessments of domestic well water vulnerability to pollution if one considers the depth that the domestic well is screened in addition to pollutant loading, surficial geology, and vertical groundwater flow rates. These new continental-scale maps can be used to (i) better assess economic, water quality, and water balance limitations to groundwater usage, (ii) steer domestic well drilling into productive strata bearing clean and protected groundwater resources, and (iii) assess groundwater management schemes across the western US.

Ground-water flow and water quality in the Upper Floridan aquifer, southwestern Albany area, Georgia, 1998-2001

USGS Publications Warehouse

Warner, Debbie; Lawrence, Stephen J.

2005-01-01

During 1997, the Dougherty County Health Department sampled more than 700 wells completed in the Upper Floridan aquifer in Dougherty County, Georgia, and determined that nitrate as nitrogen (hereinafter called nitrate) concentrations were above 10 milligrams per liter (mg/L) in 12 percent of the wells. Ten mg/L is the Georgia primary drinking-water standard. The ground-water flow system is complex and poorly understood in this predominantly agricultural area. Therefore, the U.S. Geological Survey (USGS) - in cooperation with Albany Water, Gas and Light Commission - conducted a study to better define ground-water flow and water quality in the Upper Florida aquifer in the southwestern Albany area, Georgia. Ground-water levels were measured in the southwestern Albany area, Georgia, during May 1998 and March 1999 (spring), and October 1998 and September 1999 (fall). Groundwater levels measured in 75 wells open only to the Upper Floridan aquifer were used to construct potentiometric-surface maps for those four time periods. These maps show that ground water generally flows from northwest to southeast at gradients ranging from about 2 to greater than 10 feet per mile. During spring and fall 1998, ground-water levels were high and mounding of the potentiometric surface occurred in the central part of the study area, indicating a local recharge area. Water levels declined from December through February, and by March 1999 the mound in the potentiometric surface had dissipated. Of the 75 wells in the potentiometric network, 24 were selected for a water-quality network. These 24 wells and 1 spring were sampled during fall 1998 and spring 1999. Samples were analyzed for major chemical constituents, selected minor constituents, selected nutrients, and chlorofluorocarbons (CFC). Water-quality field measurements - such as water temperature, pH, specific conductance (SC), and dissolved oxygen (DO) - were taken at each well. During August 2000, a ground-water sample was collected and analyzed for selected sewage tracers. During March 2001, water samples from selected wells were analyzed for nitrogen and oxygen isotopes. Age-dating analysis using CFCs yield apparent groundwater ages that range from modern to greater than 50 years. The chemistry of ground water in the Upper Floridan aquifer varies widely throughout the southwestern Albany area, Georgia, and in general represents the chemistry commonly found in recharge areas. From fall 1998 through spring 1999, median values of pH, SC, and DO concentration were 7.6 standard units, 266 microsiemens per centimeter at 25 degrees Celsius (uS/cm), and 5.6 mg/L, respectively. The SC is highest (350 - 400 uS/cm) where mounding of the potentiometric surface exists. Specific DO concentrations indicate an area of anoxic ground water in the north-central part of the study area. Water samples indicate that ground water in the study area is dominated by calcium and bicarbonate ions, which is consistent with the limestone lithology of the aquifer. About 25 percent of the samples contained sodium and chloride at ratios similar to those in rainfall, indicating a close proximity to recharge areas. The remaining water samples, however, had sodiumchloride ratios less than 0.90, the ratio in Tift County, Georgia, rainfall samples. These low sodium-chloride ratios are consistent with chloride enrichment. Minor constituent and nutrient concentrations typically are below laboratory reporting limits; however, the maximum nitrate concentration measured during the study period was 12.2 mg/L, and the median concentration for the study period was 3.0 mg/L. Samples collected during 1999 had a higher median nitrate concentration than the 1998 samples. Regression analysis indicated that nitrate concentrations are related exponentially to chloride concentrations. Four distinct groups of ground-water-quality samples, plus four unique samples, were identified using cluster analysis. Water-quality groups I and

Arsenic, manganese and aluminum contamination in groundwater resources of Western Amazonia (Peru).

PubMed

de Meyer, Caroline M C; Rodríguez, Juan M; Carpio, Edward A; García, Pilar A; Stengel, Caroline; Berg, Michael

2017-12-31

This paper presents a first integrated survey on the occurrence and distribution of geogenic contaminants in groundwater resources of Western Amazonia in Peru. An increasing number of groundwater wells have been constructed for drinking water purposes in the last decades; however, the chemical quality of the groundwater resources in the Amazon region is poorly studied. We collected groundwater from the regions of Iquitos and Pucallpa to analyze the hydrochemical characteristics, including trace elements. The source aquifer of each well was determined by interpretation of the available geological information, which identified four different aquifer types with distinct hydrochemical properties. The majority of the wells in two of the aquifer types tap groundwater enriched in aluminum, arsenic, or manganese at levels harmful to human health. Holocene alluvial aquifers along the main Amazon tributaries with anoxic, near pH-neutral groundwater contained high concentrations of arsenic (up to 700μg/L) and manganese (up to 4mg/L). Around Iquitos, the acidic groundwater (4.2≤pH≤5.5) from unconfined aquifers composed of pure sand had dissolved aluminum concentrations of up to 3.3mg/L. Groundwater from older or deeper aquifers generally was of good chemical quality. The high concentrations of toxic elements highlight the urgent need to assess the groundwater quality throughout Western Amazonia. Copyright © 2017 Elsevier B.V. All rights reserved.

Multivariate statistical techniques for the evaluation of groundwater quality of Amaravathi River Basin: South India

NASA Astrophysics Data System (ADS)

Loganathan, K.; Ahamed, A. Jafar

2017-12-01

The study of groundwater in Amaravathi River basin of Karur District resulted in large geochemical data set. A total of 24 water samples were collected and analyzed for physico-chemical parameters, and the abundance of cation and anion concentrations was in the following order: Na+ > Ca2+ > Mg2+ > K+ = Cl- > HCO3 - > SO4 2-. Correlation matrix shows that the basic ionic chemistry is influenced by Na+, Ca2+, Mg2+, and Cl-, and also suggests that the samples contain Na+-Cl-, Ca2+-Cl- an,d mixed Ca2+-Mg2+-Cl- types of water. HCO3 -, SO4 2-, and F- association is less than that of other parameters due to poor or less available of bearing minerals. PCA extracted six components, which are accountable for the data composition explaining 81% of the total variance of the data set and allowed to set the selected parameters according to regular features as well as to evaluate the frequency of each group on the overall variation in water quality. Cluster analysis results show that groundwater quality does not vary extensively as a function of seasons, but shows two main clusters.

Regional assessment of groundwater quality for drinking purpose.

PubMed

Jang, Cheng-Shin

2012-05-01

Owing to limited surface water during a long-term drought, this work attempted to locate clean and safe groundwater in the Choushui River alluvial fan of Taiwan based on drinking-water quality standards. Because aquifers contained several pollutants, multivariate indicator kriging (MVIK) was adopted to integrate the multiple pollutants in groundwater based on drinking- and raw-water quality standards and to explore spatial uncertainty. According to probabilities estimated by MVIK, safe zones were determined under four treatment conditions--no treatment; ammonium-N and iron removal; manganese and arsenic removal; and ammonium-N, iron, manganese, and arsenic removal. The analyzed results reveal that groundwater in the study area is not appropriate for drinking use without any treatments because of high ammonium-N, iron, manganese, and/or arsenic concentrations. After ammonium-N, iron, manganese, and arsenic removed, about 81.9-94.9% of total areas can extract safe groundwater for drinking. The proximal-fan, central mid-fan, southern mid-fan, and northern regions are the excellent locations to pump safe groundwater for drinking after treatment. Deep aquifers of exceeding 200 m depth have wider regions to obtain excellent groundwater than shallow aquifers do.

Sustainable yield of a karst aquifer system: a case study of Jinan springs in northern China

NASA Astrophysics Data System (ADS)

Kang, Fengxin; Jin, Menggui; Qin, Pinrui

2011-06-01

Based on the long-term monitoring data of rainfall, groundwater levels, groundwater abstraction, spring flow rates and groundwater quality, an assessment has been undertaken of the sustainable yield of a karst aquifer system in Shandong Province, northern China, to maintain perennial outflow of the karst springs while meeting water demands. One of the fundamental indicators for sustainable yield of groundwater is identified as maximum allowable water-level drawdown. A regional three-dimensional finite-difference numerical model has been developed to optimize the schemes associated with well fields and their locations and sustainable yields, in the Jinan spring catchment and its adjacent karst groundwater catchments, with the aim of maintaining the water level higher than the allowable lowest water level of 27.5 m above sea level. Furthermore, measures necessary to move towards sustainable use of the karst groundwater are outlined, drawing on contingency plans of water-source replacement and artificial recharge, dual water supply (based in water quality), use of the spring waters themselves, and groundwater quality protection.

The potential use of fauna and bacteria as ecological indicators for the assessment of groundwater quality.

PubMed

Stein, Heide; Kellermann, Claudia; Schmidt, Susanne I; Brielmann, Heike; Steube, Christian; Berkhoff, Sven E; Fuchs, Andreas; Hahn, Hans Jürgen; Thulin, Barbara; Griebler, Christian

2010-01-01

The use of ecological criteria for the assessment of aquatic ecosystem status is routine for surface waters. So far no ecological parameters are considered for the assessment and monitoring of groundwater quality. It has been well known for decades that aquifers are ecosystems harbouring a vast diversity of invertebrates and microorganisms. The growing knowledge on groundwater microbial and faunal communities as well as the molecular and statistical tools available form a solid ground for the development of first ecologically sound assessment schemes. The sensitivity of groundwater communities towards impacts from land use and surface waters is exemplarily demonstrated by a data set of two geologically similar but hydrologically partially separated aquifer systems. Subgroups of the fauna in groundwater (stygobites vs. stygophiles and stygoxenes) successfully indicated elevated nitrate impacts linked to land use activities. Within the microbial communities, impacts from land use are mirrored by high bacterial biodiversity values atypical for pristine groundwater of comparable systems. The data show that there is legitimate hope for the application of ecological criteria for groundwater quality assessment in the future.

Groundwater ages and mixing in the Piceance Basin natural gas province, Colorado

USGS Publications Warehouse

McMahon, Peter B.; Thomas, Judith C.; Hunt, Andrew G.

2013-01-01

Reliably identifying the effects of energy development on groundwater quality can be difficult because baseline assessments of water quality completed before the onset of energy development are rare and because interactions between hydrocarbon reservoirs and aquifers can be complex, involving both natural and human processes. Groundwater age and mixing data can strengthen interpretations of monitoring data from those areas by providing better understanding of the groundwater flow systems. Chemical, isotopic, and age tracers were used to characterize groundwater ages and mixing with deeper saline water in three areas of the Piceance Basin natural gas province. The data revealed a complex array of groundwater ages (50,000 years) and mixing patterns in the basin that helped explain concentrations and sources of methane in groundwater. Age and mixing data also can strengthen the design of monitoring programs by providing information on time scales at which water quality changes in aquifers might be expected to occur. This information could be used to establish maximum allowable distances of monitoring wells from energy development activity and the appropriate duration of monitoring.

Investigation of the geochemical evolution of groundwater under agricultural land: A case study in northeastern Mexico

NASA Astrophysics Data System (ADS)

Ledesma-Ruiz, Rogelio; Pastén-Zapata, Ernesto; Parra, Roberto; Harter, Thomas; Mahlknecht, Jürgen

2015-02-01

Zona Citrícola is an important area for Mexico due to its citriculture activity. Situated in a sub-humid to humid climate adjacent to the Sierra Madre Oriental, this valley hosts an aquifer system that represents sequences of shales, marls, conglomerates, and alluvial deposits. Groundwater flows from mountainous recharge areas to the basin-fill deposits and provides base flows to supply drinking water to the adjacent metropolitan area of Monterrey. Recent studies examining the groundwater quality of the study area urge the mitigation of groundwater pollution. The objective of this study was to characterize the physical and chemical properties of the groundwater and to assess the processes controlling the groundwater's chemistry. Correlation was used to identify associations among various geochemical constituents. Factor analysis was applied to identify the water's chemical characteristics that were responsible for generating most of the variability within the dataset. Hierarchical cluster analysis was employed in combination with a post-hoc analysis of variance to partition the water samples into hydrochemical water groups: recharge waters (Ca-HCO3), transition zone waters (Ca-HCO3-SO4 to Ca-SO4-HCO3) and discharge waters (Ca-SO4). Inverse geochemical models of these groups were developed and constrained using PHREEQC to elucidate the chemical reactions controlling the water's chemistry between an initial (recharge) and final water. The primary reactions contributing to salinity were the following: (1) water-rock interactions, including the weathering of evaporitic rocks and dedolomitization; (2) dissolution of soil gas carbon dioxide; and (3) input from animal/human wastewater and manure in combination with by denitrification processes. Contributions from silicate weathering to salinity ranged from less important to insignificant. The findings suggest that it may not be cost-effective to regulate manure application to mitigate groundwater pollution.

Hydro-geochemistry and application of water quality index (WQI) for groundwater quality assessment, Anna Nagar, part of Chennai City, Tamil Nadu, India

NASA Astrophysics Data System (ADS)

Krishna kumar, S.; Logeshkumaran, A.; Magesh, N. S.; Godson, Prince S.; Chandrasekar, N.

2015-12-01

In the present study, the geochemical characteristics of groundwater and drinking water quality has been studied. 24 groundwater samples were collected and analyzed for pH, electrical conductivity, total dissolved solids, carbonate, bicarbonate, chloride, sulphate, nitrate, calcium, magnesium, sodium, potassium and total hardness. The results were evaluated and compared with WHO and BIS water quality standards. The studied results reveal that the groundwater is fresh to brackish and moderately high to hard in nature. Na and Cl are dominant ions among cations and anions. Chloride, calcium and magnesium ions are within the allowable limit except few samples. According to Gibbs diagram, the predominant samples fall in the rock-water interaction dominance and evaporation dominance field. The piper trilinear diagram shows that groundwater samples are Na-Cl and mixed CaMgCl type. Based on the WQI results majority of the samples are falling under excellent to good category and suitable for drinking water purposes.

Groundwater quality assessment plan for single-shell waste management area B-BX-BY at the Hanford Site

DOE Office of Scientific and Technical Information (OSTI.GOV)

SM Narbutovskih

2000-03-31

Pacific Northwest National Laboratory conducted a first determination groundwater quality assessment at the Hanford Site. This work was performed for the US Department of Energy, Richland Operations Office, in accordance with the Federal Facility Compliance Agreement during the time period 1996--1998. The purpose of the assessment was to determine if waste from the Single-Shell Tank (SST) Waste Management Area (WMA) B-BX-BY had entered the groundwater at levels above the drinking water standards (DWS). The resulting assessment report documented evidence demonstrating that waste from the WMA has, most likely, impacted groundwater quality. Based on 40 CFR 265.93 [d] paragraph (7), themore » owner-operator must continue to make the minimum required determinations of contaminant level and of rate/extent of migrations on a quarterly basis until final facility closure. These continued determinations are required because the groundwater quality assessment was implemented prior to final closure of the facility.« less

Groundwater resource vulnerability and spatial variability of nitrate contamination: Insights from high density tubewell monitoring in a hard rock aquifer.

PubMed

Buvaneshwari, Sriramulu; Riotte, Jean; Sekhar, M; Mohan Kumar, M S; Sharma, Amit Kumar; Duprey, Jean Louis; Audry, Stephane; Giriraja, P R; Praveenkumarreddy, Yerabham; Moger, Hemanth; Durand, Patrick; Braun, Jean-Jacques; Ruiz, Laurent

2017-02-01

Agriculture has been increasingly relying on groundwater irrigation for the last decades, leading to severe groundwater depletion and/or nitrate contamination. Understanding the links between nitrate concentration and groundwater resource is a prerequisite for assessing the sustainability of irrigated systems. The Berambadi catchment (ORE-BVET/Kabini Critical Zone Observatory) in Southern India is a typical example of intensive irrigated agriculture and then an ideal site to study the relative influences of land use, management practices and aquifer properties on NO 3 spatial distribution in groundwater. The monitoring of >200 tube wells revealed nitrate concentrations from 1 to 360mg/L. Three configurations of groundwater level and elevation gradient were identified: i) NO 3 hot spots associated to deep groundwater levels (30-60m) and low groundwater elevation gradient suggest small groundwater reserve with absence of lateral flow, then degradation of groundwater quality due to recycling through pumping and return flow; ii) high groundwater elevation gradient, moderate NO 3 concentrations suggest that significant lateral flow prevented NO 3 enrichment; iii) low NO 3 concentrations, low groundwater elevation gradient and shallow groundwater indicate a large reserve. We propose that mapping groundwater level and gradient could be used to delineate zones vulnerable to agriculture intensification in catchments where groundwater from low-yielding aquifers is the only source of irrigation. Then, wells located in low groundwater elevation gradient zones are likely to be suitable for assessing the impacts of local agricultural systems, while wells located in zones with high elevation gradient would reflect the average groundwater quality of the catchment, and hence should be used for regional mapping of groundwater quality. Irrigation with NO 3 concentrated groundwater induces a "hidden" input of nitrogen to the crop which can reach 200kgN/ha/yr in hotspot areas, enhancing groundwater contamination. Such fluxes, once taken into account in fertilizer management, would allow optimizing fertilizer consumption and mitigate high nitrate concentrations in groundwater. Copyright © 2016 Elsevier B.V. All rights reserved.

Screening of sustainable groundwater sources for integration into a regional drought-prone water supply system

NASA Astrophysics Data System (ADS)

Stigter, T. Y.; Monteiro, J. P.; Nunes, L. M.; Vieira, J.; Cunha, M. C.; Ribeiro, L.; Nascimento, J.; Lucas, H.

2009-01-01

This paper reports on the qualitative and quantitative screening of groundwater sources for integration into the public water supply system of the Algarve, Portugal. The results are employed in a decision support system currently under development for an integrated water resources management scheme in the region. Such a scheme is crucial for several reasons, including the extreme seasonal and annual variations in rainfall, the effect of climate change on more frequent and long-lasting droughts, the continuously increasing water demand and the high risk of a single-source water supply policy. The latter was revealed during the severe drought of 2004 and 2005, when surface reservoirs were depleted and the regional water demand could not be met, despite the drilling of emergency wells. For screening and selection, quantitative criteria are based on aquifer properties and well yields, whereas qualitative criteria are defined by water quality indices. These reflect the well's degree of violation of drinking water standards for different sets of variables, including toxicity parameters, nitrate and chloride, iron and manganese and microbiological parameters. Results indicate the current availability of at least 1100 l s-1 of high quality groundwater (55% of the regional demand), requiring only disinfection (900 l s-1) or basic treatment, prior to human consumption. These groundwater withdrawals are sustainable when compared to mean annual recharge, considering that at least 40% is preserved for ecological demands. A more accurate and comprehensive analysis of sustainability is performed with the help of steady-state and transient groundwater flow simulations, which account for aquifer geometry, boundary conditions, recharge and discharge rates, pumping activity and seasonality. They permit an advanced analysis of present and future scenarios and show that increasing water demands and decreasing rainfall will make the water supply system extremely vulnerable, with a high risk of groundwater salinization and ecosystem degradation.

Screening of sustainable groundwater sources for integration into a regional drought-prone water supply system

NASA Astrophysics Data System (ADS)

Stigter, T. Y.; Monteiro, J. P.; Nunes, L. M.; Vieira, J.; Cunha, M. C.; Ribeiro, L.; Nascimento, J.; Lucas, H.

2009-07-01

This paper reports on the qualitative and quantitative screening of groundwater sources for integration into the public water supply system of the Algarve, Portugal. The results are employed in a decision support system currently under development for an integrated water resources management scheme in the region. Such a scheme is crucial for several reasons, including the extreme seasonal and annual variations in rainfall, the effect of climate change on more frequent and long-lasting droughts, the continuously increasing water demand and the high risk of a single-source water supply policy. The latter was revealed during the severe drought of 2004 and 2005, when surface reservoirs were depleted and the regional water demand could not be met, despite the drilling of emergency wells. For screening and selection, quantitative criteria are based on aquifer properties and well yields, whereas qualitative criteria are defined by water quality indices. These reflect the well's degree of violation of drinking water standards for different sets of variables, including toxicity parameters, nitrate and chloride, iron and manganese and microbiological parameters. Results indicate the current availability of at least 1100 l s-1 of high quality groundwater (55% of the regional demand), requiring only disinfection (900 l s-1) or basic treatment, prior to human consumption. These groundwater withdrawals are sustainable when compared to mean annual recharge, considering that at least 40% is preserved for ecological demands. A more accurate and comprehensive analysis of sustainability is performed with the help of steady-state and transient groundwater flow simulations, which account for aquifer geometry, boundary conditions, recharge and discharge rates, pumping activity and seasonality. They permit an advanced analysis of present and future scenarios and show that increasing water demands and decreasing rainfall will make the water supply system extremely vulnerable, with a high risk of groundwater salinization and ecosystem degradation.

What surface water tells about groundwater in lowlands - and what it does not

NASA Astrophysics Data System (ADS)

Steidl, Jörg; Lischeid, Gunnar; Kalettka, Thomas; Dannowski, Ralf; Merz, Christoph

2017-04-01

Lowland regions often exhibit a high density streams, lakes, ponds and wetlands. This holds, e.g., for Northeast Europe. As a consequence of heterogeneous sedimentation during and after glaciation, and temporarily dead ice blocks left behind in the late stage of the last glaciation, the landscape is now spotted by small depressions that are often filled with water, called kettle holes. Tight coupling between groundwater and surface water with non-stationary gradients and flow directions is often considered rather complex and surely is a challenge for hydrological models. However, on the other hand, close links imply that the one system bears information about the other and vice versa. For example, for the 170 km2 Quillow catchment in Northeast Germany a detailed groundwater map was generated from airborne remote sensing data exclusively, that is, from laser scan data of water level elevation in streams and kettle holes. On average, about 12 points of support per km2 were used. Such a high density can hardly be achieved at that scale based on groundwater wells. The resulting map was checked for consistency and plausibility. The groundwater map allowed delineating the catchments of the single kettle holes in order to assess the impact of land use of water quality. These catchments differed substantially from those determined based on topography. In general, the former usually exhibited a clearly elongated shape of up to some km length, resembling more single groundwater flowpaths rather than exhibiting the typical shape of stream catchments. Analysis of water quality monitoring data revealed that kettle hole water reflected the concentration of earth and alkaline earth metals of the shallow groundwater. However, this did not hold for nutrients and redox sensitive solutes due to rapid biogeochemical turnover in the eutrophic to hypertrophic small lentic systems.

Monitoring concentration and isotopic composition of methane in groundwater in the Utica Shale hydraulic fracturing region of Ohio.

PubMed

Claire Botner, E; Townsend-Small, Amy; Nash, David B; Xu, Xiaomei; Schimmelmann, Arndt; Miller, Joshua H

2018-05-03

Degradation of groundwater quality is a primary public concern in rural hydraulic fracturing areas. Previous studies have shown that natural gas methane (CH 4 ) is present in groundwater near shale gas wells in the Marcellus Shale of Pennsylvania, but did not have pre-drilling baseline measurements. Here, we present the results of a free public water testing program in the Utica Shale of Ohio, where we measured CH 4 concentration, CH 4 stable isotopic composition, and pH and conductivity along temporal and spatial gradients of hydraulic fracturing activity. Dissolved CH 4 ranged from 0.2 μg/L to 25 mg/L, and stable isotopic measurements indicated a predominantly biogenic carbonate reduction CH 4 source. Radiocarbon dating of CH 4 in combination with stable isotopic analysis of CH 4 in three samples indicated that fossil C substrates are the source of CH 4 in groundwater, with one 14 C date indicative of modern biogenic carbonate reduction. We found no relationship between CH 4 concentration or source in groundwater and proximity to active gas well sites. No significant changes in CH 4 concentration, CH 4 isotopic composition, pH, or conductivity in water wells were observed during the study period. These data indicate that high levels of biogenic CH 4 can be present in groundwater wells independent of hydraulic fracturing activity and affirm the need for isotopic or other fingerprinting techniques for CH 4 source identification. Continued monitoring of private drinking water wells is critical to ensure that groundwater quality is not altered as hydraulic fracturing activity continues in the region. Graphical abstract A shale gas well in rural Appalachian Ohio. Photo credit: Claire Botner.

Y-12 Groundwater Protection Program Groundwater Monitoring Data Compendium, Revision 1

DOE Office of Scientific and Technical Information (OSTI.GOV)

None

This document is a compendium of water quality and hydrologic characterization data obtained through December 2005 from the network of groundwater monitoring wells and surface water sampling stations (including springs and building sumps) at the U.S. Department of Energy (DOE) Y-12 National Security Complex (Y-12) in Oak Ridge, Tennessee that have been sampled since January 2003. The primary objectives of this document, hereafter referenced as the Y-12 Groundwater Protection Program (GWPP) Compendium, are to: (1) Serve as a single-source reference for monitoring data that meet the requirements of the Y-12 GWPP, as defined in the Y-12 GWPP Management Plan (BWXTmore » Y-12 L.L.C. [BWXT] 2004); (2) Maintain a detailed analysis and evaluation of the monitoring data for each applicable well, spring, and surface water sampling station, with a focus on results for the primary inorganic, organic, and radiological contaminants in groundwater and surface water at Y-12; and (3) Ensure retention of ''institutional knowledge'' obtained over the long-term (>20-year) history of groundwater and surface water monitoring at Y-12 and the related sources of groundwater and surface water contamination. To achieve these goals, the Y-12 GWPP Compendium brings together salient hydrologic, geologic, geochemical, water-quality, and environmental compliance information that is otherwise disseminated throughout numerous technical documents and reports prepared in support of completed and ongoing environmental contamination assessment, remediation, and monitoring activities performed at Y-12. The following subsections provide background information regarding the overall scope and format of the Y-12 GWPP Compendium and the planned approach for distribution and revision (i.e., administration) of this ''living'' document.« less

Impacts of swine manure pits on groundwater quality

USGS Publications Warehouse

Krapac, I.G.; Dey, W.S.; Roy, W.R.; Smyth, C.A.; Storment, E.; Sargent, S.L.; Steele, J.D.

2002-01-01

Manure deep-pits are commonly used to store manure at confined animal feeding operations. However, previous to this study little information had been collected on the impacts of deep-pits on groundwater quality to provide science-based guidance in formulating regulations and waste management strategies that address risks to human health and the environment. Groundwater quality has been monitored since January 1999 at two hog finishing facilities in Illinois that use deep-pit systems for manure storage. Groundwater samples were collected on a monthly basis and analyzed for inorganic and bacteriological constituent concentrations. The two sites are located in areas with geologic environments representing different vulnerabilities for local groundwater contamination. One site is underlain by more than 6 m of clayey silt, and 7-36 m of shale. Concentrations of chloride, ammonium, phosphate, and potassium indicated that local groundwater quality had not been significantly impacted by pit leakage from this facility. Nitrate concentrations were elevated near the pit, often exceeding the 10 mg N/l drinking water standard. Isotopic nitrate signatures suggested that the nitrate was likely derived from soil organic matter and fertilizer applied to adjacent crop fields. At the other site, sandstone is located 4.6-6.1 m below land surface. Chloride concentrations and ??15N and ??18O values of dissolved nitrate indicated that this facility may have limited and localized impacts on groundwater. Other constituents, including ammonia, potassium, phosphate, and sodium were generally at or less than background concentrations. Trace- and heavy-metal concentrations in groundwater samples collected from both facilities were at concentrations less than drinking water standards. The concentration of inorganic constituents in the groundwater would not likely impact human health. Fecal streptococcus bacteria were detected at least once in groundwater from all monitoring wells at both sites. Fecal streptococcus was more common and at greater concentrations than fecal coliform. The microbiological data suggest that filtration of bacteria by soils may not be as effective as commonly assumed. The presence of fecal bacteria in the shallow groundwater may pose a significant threat to human health if the ground water is used for drinking. Both facilities are less than 4 years old and the short-term impacts of these manure storage facilities on groundwater quality have been limited. Continued monitoring of these facilities will determine if they have a long-term impact on groundwater resources. ?? 2002 Elsevier Science Ltd. All rights reserved.

Effects of ground-water chemistry and flow on quality of drainflow in the western San Joaquin Valley, California

USGS Publications Warehouse

Fio, John L.; Leighton, David A.

1994-01-01

Chemical and geohydrologic data were used to assess the effects of regional ground-water flow on the quality of on-farm drainflows in a part of the western San Joaquin Valley, California. Shallow ground water beneath farm fields has been enriched in stable isotopes and salts by partial evaporation from the shallow water table and is being displaced by irrigation, drainage, and regional ground-water flow. Ground-water flow is primarily downward in the study area but can flow upward in some down- slope areas. Transitional areas exist between the downward and upward flow zones, where ground water can move substantial horizontal distances (0.3 to 3.6 kilometers) and can require 10 to 90 years to reach the downslope drainage systems. Simulation of ground-water flow to drainage systems indicates that regional ground water contributes to about 11 percent of annual drainflow. Selenium concentrations in ground water and drainwater are affected by geologic source materials, partial evaporation from a shallow water table, drainage-system, and regional ground-water flow. Temporal variability in drainflow quality is affected in part by the distribution of chemical constituents in ground water and the flow paths to the drainage systems. The mass flux of selenium in drainflows, or load, generally is proportional to flow, and reductions in drainflow quantity should reduce selenium loads over the short-term. Uncertain changes in the distribution of ground-water quality make future changes in drainflow quality difficult to quantify.

Groundwater Quality Protection in Oakland County: A Sourcebook for Teachers.

ERIC Educational Resources Information Center

East Michigan Environmental Action Council, Troy.

This sourcebook consists of background information and activities related to groundwater protection. The first section focuses on the characteristics of groundwater, the water cycle, stormwater runoff, and uses of groundwater. The second section addresses household hazardous materials--both from a safety standpoint and a groundwater standpoint.…

Groundwater-quality and quality-control data for two monitoring wells near Pavillion, Wyoming, April and May 2012

USGS Publications Warehouse

Wright, Peter R.; McMahon, Peter B.; Mueller, David K.; Clark, Melanie L.

2012-01-01

In June 2010, the U.S. Environmental Protection Agency installed two deep monitoring wells (MW01 and MW02) near Pavillion, Wyoming, to study groundwater quality. During April and May 2012, the U.S Geological Survey, in cooperation with the Wyoming Department of Environmental Quality, collected groundwater-quality data and quality-control data from monitoring well MW01 and, following well redevelopment, quality-control data for monitoring well MW02. Two groundwater-quality samples were collected from well MW01—one sample was collected after purging about 1.5 borehole volumes, and a second sample was collected after purging 3 borehole volumes. Both samples were collected and processed using methods designed to minimize atmospheric contamination or changes to water chemistry. Groundwater-quality samples were analyzed for field water-quality properties (water temperature, pH, specific conductance, dissolved oxygen, oxidation potential); inorganic constituents including naturally occurring radioactive compounds (radon, radium-226 and radium-228); organic constituents; dissolved gasses; stable isotopes of methane, water, and dissolved inorganic carbon; and environmental tracers (carbon-14, chlorofluorocarbons, sulfur hexafluoride, tritium, helium, neon, argon, krypton, xenon, and the ratio of helium-3 to helium-4). Quality-control sample results associated with well MW01 were evaluated to determine the extent to which environmental sample analytical results were affected by bias and to evaluate the variability inherent to sample collection and laboratory analyses. Field documentation, environmental data, and quality-control data for activities that occurred at the two monitoring wells during April and May 2012 are presented.

Questa baseline and pre-mining ground-water quality investigation. 3. Historical ground-water quality for the Red River Valley, New Mexico

USGS Publications Warehouse

LoVetere, Sara H.; Nordstrom, D. Kirk; Maest, Ann S.; Naus, Cheryl A.

2003-01-01

Historical ground-water quality data for 100 wells in the Red River Valley between the U.S. Geological Survey streamflow-gaging station (08265000), near Questa, and Placer Creek east of the town of Red River, New Mexico, were compiled and reviewed. The tabulation included 608 water-quality records from 23 sources entered into an electronic database. Groundwater quality data were first collected at the Red River wastewater-treatment facility in 1982. Most analyses, however, were obtained between 1994 and 2002, even though the first wells were developed in 1962. The data were evaluated by considering (a) temporal consistency, (b) quality of sampling methods, (c) charge imbalance, and (d) replicate analyses. Analyses that qualified on the basis of these criteria were modeled to obtain saturation indices for gypsum, calcite, fluorite, gibbsite, manganite, and rhodocrosite. Plots created from the data illustrate that water chemistry in the Red River Valley is predominantly controlled by calcite dissolution, congruent gypsum dissolution, and pyrite oxidation.

Water resources data Virginia water year 2005 Volume 2. Ground-water level and ground-water quality records

USGS Publications Warehouse

Wicklein, Shaun M.; Powell, Eugene D.; Guyer, Joel R.; Owens, Joseph A.

2006-01-01

Water-resources data for the 2005 water year for Virginia consist of records of water levels and water quality of ground-water wells. This report (Volume 2. Ground-Water-Level and Ground-Water-Quality Records) contains water levels at 349 observation wells and water quality at 29 wells. Locations of these wells are shown on figures 3 through 8. The data in this report represent that part of the National Water Data System collected by the U.S. Geological Survey and cooperating State and Federal agencies in Virginia.

Geochemistry of groundwater in parts of Guntur district, Andhra Pradesh, India

NASA Astrophysics Data System (ADS)

Subba Rao, N.

2002-01-01

Hydrogeochemical investigations, which are significant for the assessment of water quality, have been carried out to study the sources of dissolved ions in groundwaters of some rural areas of Guntur district, Andhra Pradesh, India. Groundwaters in the area are mostly brackish. High contents of SiO2, and Na+ and Cl- ions in groundwater, in comparison with those of seawater, suggests a meteoric origin of groundwater. The high concentration of SiO2 and various geochemical signatures reflect the weathering of minerals. However, the Na++K+ vs Cl- ratio suggests weathering, has occurred only to some extent. The chemistry of groundwater favours the formation of clay minerals (montmorillonite, illite and chlorite), because of evapotranspiration. The positive saturation index of CaCO3 and the high signatures of Ma2+:Ca2+ and Na+:Ca2+ reveals the occurrence of evaporation. The evaporation enhances the concentration of ions (which occurred originally in the water) in the soils during summer. The very high SO{4/2-} and Cl- contents in some groundwaters and the occurrence of kankar (CaCO3) in the area suggest a long history of evaporation. Greater ionic concentration in the groundwaters of post-monsoon compared with pre-monsoon indicates the increasing addition of leachates into the groundwater from the soils in the monsoon and anthropogenic activities, which leads to a deteriorating quality of groundwater. According to the Gibbs' diagrams, rock weathering, to some extent, and evaporation are the dominant phenomena responsible for the higher ionic concentrations found in groundwater. Measures that benefit sustainable management of groundwater quality are suggested in this study.

Fraser River watershed, Colorado : assessment of available water-quantity and water-quality data through water year 1997

USGS Publications Warehouse

Apodaca, Lori Estelle; Bails, Jeffrey B.

1999-01-01

The water-quantity and water-quality data for the Fraser River watershed through water year 1997 were compiled for ground-water and surface-water sites. In order to assess the water-quality data, the data were related to land use/land cover in the watershed. Data from 81 water-quantity and water-quality sites, which consisted of 9 ground-water sites and 72 surface-water sites, were available for analysis. However, the data were limited and frequently contained only one or two water-quality analyses per site.The Fraser River flows about 28 miles from its headwaters at the Continental Divide to the confluence with the Colorado River. Ground-water resources in the watershed are used for residential and municipal drinking-water supplies. Surface water is available for use, but water diversions in the upper parts of the watershed reduce the flow in the river. Land use/land cover in the watershed is predominantly forested land, but increasing urban development has the potential to affect the quantity and quality of the water resources.Analysis of the limited ground-water data in the watershed indicates that changes in the land use/land cover affect the shallow ground-water quality. Water-quality data from eight shallow monitoring wells in the alluvial aquifer show that iron and manganese concentrations exceeded the U.S. Environmental Protection Agency secondary maximum contaminant level. Radon concentrations from these monitoring wells exceeded the U.S. Environmental Protection Agency proposed maximum contaminant level. The proposed radon contaminant level is currently being revised. The presence of volatile organic compounds at two monitoring wells in the watershed indicates that land use affects the shallow ground water. In addition, bacteria detected in three samples are at concentrations that would be a concern for public health if the water was to be used as a drinking supply. Methylene blue active substances were detected in the ground water at some sites and are a possible indication of contamination from wastewater. Age of the alluvial ground water ranged from 10 to 30 years; therefore, results of land-management practices to improve water quality may not be apparent for many years.Surface-water-quality data for the Fraser River watershed are sparse. The surface-water-quality data show that elevated concentrations of selected constituents generally are related to specific land uses in the watershed. For one sample (about 2 percent; 1 of 53), dissolved manganese concentration exceeded the U.S. Environmental Protection Agency secondary maximum contaminant level. Two samples from two surface-water sites in the watershed exceeded the un-ionized ammonia chronic criterion. Spatial distribution of nutrient species (ammonia, nitrite, nitrate, and total phosphorus) shows that elevated concentrations occur primarily downstream from urban areas. Sites with five or more years of record were analyzed for temporal trends in concentration of nutrient species. Downward trends were identified for ammonia and nitrite for three surface-water sites. For nitrate, no trends were observed at two sites and a downward trend was observed at one site. Total phosphorus showed no trend for the site near the mouth of the Fraser River. Downward trends in the nutrient species may reflect changes in the wastewater-treatment facilities in the watershed. Bacteria sampling completed in the watershed indicates that more bacteria are present in the water near urban settings.The limited ground-water and surface-water data for the Fraser River watershed provide a general assessment of the quantity and quality of these resources. Concentrations of most water-quality constituents generally are less than ground- and surface-water-quality standards, but the presence of bacteria, some volatile organic compounds, methylene blue active substances, and increased nutrients in the water may indicate that land use is affecting the water quality..

Tracing freshwater nitrate sources in pre-alpine groundwater catchments using environmental tracers

NASA Astrophysics Data System (ADS)

Stoewer, M. M.; Knöller, K.; Stumpp, C.

2015-05-01

Groundwater is one of the main resources for drinking water. Its quality is still threatened by the widespread contaminant nitrate (NO3-). In order to manage groundwater resources in a sustainable manner, we need to find options of lowering nitrate input. Particularly, a comprehensive knowledge of nitrate sources is required in areas which are important current and future drinking water reservoirs such as pre-alpine aquifers covered with permanent grassland. The objective of the present study was to identify major sources of nitrate in groundwater with low mean nitrate concentrations (8 ± 2 mg/L). To achieve the objective, we used environmental tracer approaches in four pre-alpine groundwater catchments. The stable isotope composition and tritium content of water were used to study the hydrogeology and transit times. Furthermore, nitrate stable isotope methods were applied to trace nitrogen from its sources to groundwater. The results of the nitrate isotope analysis showed that groundwater nitrate was derived from nitrification of a variety of ammonium sources such as atmospheric deposition, mineral and organic fertilizers and soil organic matter. A direct influence of mineral fertilizer, atmospheric deposition and sewage was excluded. Since temporal variation in stable isotopes of nitrate were detected only in surface water and locally at one groundwater monitoring well, aquifers appeared to be well mixed and influenced by a continuous nitrate input mainly from soil derived nitrogen. Hydrogeological analysis supported that the investigated aquifers were less vulnerable to rapid impacts due to long average transit times, ranging from 5 to 21 years. Our study revealed the importance of combining environmental tracer approaches and a comprehensive sampling campaign (local sources of nitrate, soil water, river water, and groundwater) to identify the nitrate sources in groundwater and its vulnerability. In future, the achieved results will help develop targeted strategies for a sustainable groundwater management focusing more on soil nitrogen storage.

Application of δ18O, δD, 3H-3He and CFCs to characterize the nitrate contamination of groundwater in Eumsung, Korea

NASA Astrophysics Data System (ADS)

Ju, Y. J.; Kaown, D.; Hahm, D.; Kim, I.; Lee, S. S.; Koh, E. H.; Kim, M.; Yoon, Y. Y.; Lee, K. K.

2015-12-01

We measured the major ions, stable oxygen and hydrogen isotopes, 3H-3He and CFCs concentration in groundwater to identify the characteristics of nitrate contamination and to understand the groundwater recharge patterns. In this study, 17 groundwater samples were collected for 5days (from March 3rd to 7th, 2015) in Eumseong, Korea. In the study area, NO3- concentrations in some groundwater samples (16 of 17) ranged from 5.7 to 103.7 mg/L (avg. 43.3 mg/L), which were substantially higher than the drinking water quality standard (10 mg/L). These excess NO3- inputs in groundwater seem to be originated from the agricultural use of chemical fertilizers because major ions associated with fertilizers were significantly correlated with NO3-. It seems that major groundwater recharge event during monsoon season is highly probable from the analysis of δ18O and δD. The apparent groundwater age using 3H-3He and CFCs varies from 5 to 40 yrs although the study area is small (1 km2). For the samples showed large deficiency of 3He, the sensitivity analysis was performed using NOBLE 90 in an effort to quantify the degassed amount. Since nitrate sources are quite evenly distributed through the field site, groundwater ages from shallow aquifer is inversely correlated with the nitrate concentrations. Our result implies that the 3H-3He ratio can be a useful indicator of tracing the recharge pattern of groundwater but also the nitrate loading characteristic in a small scale agricultural area. Acknowlegments: Financial support was provided by the "R&D Project on Environmental Management of Geologic CO2 Storage" from the KEITI (Project Number: 2014001810003) and the research project of "Advanced Technology for Groundwater Development and Application in Riversides (Geowater+)" in "Water Resources Management Program (code 11 Technology Innovation C05)" of the MOLIT and the KAIA in Korea.

Field demonstration of CO2 leakage detection and potential impacts on groundwater quality at Brackenridge Field Laboratory

NASA Astrophysics Data System (ADS)

Zou, Y.; Yang, C.; Guzman, N.; Delgado, J.; Mickler, P. J.; Horvoka, S.; Trevino, R.

2015-12-01

One concern related to GCS is possible risk of unintended CO2 leakage from the storage formations into overlying potable aquifers on underground sources of drinking water (USDW). Here we present a series of field tests conducted in an alluvial aquifer which is on a river terrace at The University of Texas Brackenridge Field Laboratory. Several shallow groundwater wells were completed to the limestone bedrock at a depth of 6 m and screened in the lower 3 m. Core sediments recovered from the shallow aquifer show that the sediments vary in grain size from clay-rich layers to coarse sandy gravels. Two main types of field tests were conducted at the BFL: single- (or double-) well push-pull test and pulse-like CO2 release test. A single- (or double-) well push-pull test includes three phases: the injection phase, the resting phase and pulling phase. During the injection phase, groundwater pumped from the shallow aquifer was stored in a tank, equilibrated with CO2 gasand then injected into the shallow aquifer to mimic CO2 leakage. During the resting phase, the groundwater charged with CO2 reacted with minerals in the aquifer sediments. During the pulling phase, groundwater was pumped from the injection well and groundwater samples were collected continuously for groundwater chemistry analysis. In such tests, large volume of groundwater which was charged with CO2 can be injected into the shallow aquifer and thus maximize contact of groundwater charged with CO2. Different than a single- (or double-) well push-pull test, a pulse-like CO2 release test for validating chemical sensors for CO2 leakage detection involves a CO2 release phase that CO2 gas was directly bubbled into the testing well and a post monitoring phase that groundwater chemistry was continuously monitored through sensors and/or grounder sampling. Results of the single- (or double-) well push-pull tests conducted in the shallow aquifer shows that the unintended CO2 leakage could lead to dissolution of carbonates and some silicates and mobilization of heavy metals from the aquifer sediments to groundwater, however, such mobilization posed no risks on groundwater quality at this site. The pulse-like tests have demonstrated it is plausible to use chemical sensors for CO2 leakage detection in groundwater.

Redox Conditions in Selected Principal Aquifers of the United States

USGS Publications Warehouse

McMahon, P.B.; Cowdery, T.K.; Chapelle, F.H.; Jurgens, B.C.

2009-01-01

Reduction/oxidation (redox) processes affect the quality of groundwater in all aquifer systems. Redox processes can alternately mobilize or immobilize potentially toxic metals associated with naturally occurring aquifer materials, contribute to the degradation or preservation of anthropogenic contami-nants, and generate undesirable byproducts, such as dissolved manganese (Mn2+), ferrous iron (Fe2+), hydrogen sulfide (H2S), and methane (CH4). Determining the kinds of redox processes that occur in an aquifer system, documenting their spatial distribution, and understanding how they affect concentrations of natural or anthropogenic contaminants are central to assessing and predicting the chemical quality of groundwater. This Fact Sheet extends the analysis of U.S. Geological Survey authors to additional principal aquifer systems by applying a framework developed by the USGS to a larger set of water-quality data from the USGS national water databases. For a detailed explanation, see the 'Introduction' in the Fact Sheet.

Groundwater-flow parameter estimation and quality modeling of the Equus Beds aquifer in Kansas, U.S.A.

USGS Publications Warehouse

Sophocleous, M.A.

1984-01-01

The salinity problems created in the Burrton area as a result of poor oil-field brine disposal practices of the past continue to be a major concern to the area depending on the Equus Beds aquifer for water, including the City of Wichita, Kansas. In this paper, an attempt is made to predict where and how fast the brine plume will move in this area, and what the average chloride concentrations in different parts of the aquifer are. In order to make such predictions, it was necessary to get a calibrated model of the groundwater-flow velocity field. Multiple regression analysis is used for parameter estimation of the steady-state groundwater-flow equation applied in the most critical area of the Equus Beds aquifer. Results of such an analysis produced a correlation coefficient of 0.992 between calculated and observed values of hydraulic head. A chloride transport modeling effort is then carried out despite some serious data deficiencies, the significance of which are evaluated through sensitivity analysis. Thus, starting with the quasi steady-state conditions of the early 1940's, it was possible to match the present chloride distribution satisfactorily. Chloride concentration predictions made for the year 2000 indicate that the quality of the Wichita well-field waters will not generally deteriorate from their present condition by that time. ?? 1984.

Resilience of Groundwater Impacted by Land Use and Climate Change in a Karst Aquifer, South China.

PubMed

Guo, Fang; Jiang, Guanghui; Polk, Jason S; Huang, Xiufeng; Huang, Siyu

2015-11-01

Changes of groundwater flow and quality were investigated in a subtropical karst aquifer to determine the driving mechanism. Decreases in groundwater flow are more distinct in discharge zones than those in recharge and runoff zones. Long-term measurement of the represented regional groundwater outlet reveals that groundwater discharge decrease by nearly 50% during the dry season. The hydrochemistry of groundwater in the runoff and discharge zones is of poorer quality than in the recharge zone. Indications of intensive land resource exploitation and changes in land use patterns were attributed to changes in groundwater conditions since 1990, but the influence of climate change was likely from 2001, because the water temperature exhibited increasing trends at a mean rate of 0.02 °C/yr even though groundwater depth was high in the aquifer. These conclusions imply the need for further groundwater monitoring and reevaluation to understand the resilience of aquifer during urbanization and development.

Groundwater nitrate pollution and climate change: learnings from a water balance-based analysis of several aquifers in a western Mediterranean region (Catalonia).

PubMed

Mas-Pla, Josep; Menció, Anna

2018-04-11

Climate change will affect the dynamics of the hydrogeological systems and their water resources quality; in particular nitrate, which is herein taken as a paradigmatic pollutant to illustrate the effects of climate change on groundwater quality. Based on climatic predictions of temperature and precipitation for the horizon of 2021 and 2050, as well as on land use distribution, water balances are recalculated for the hydrological basins of distinct aquifer systems in a western Mediterranean region as Catalonia (NE Spain) in order to determine the reduction of available water resources. Besides the fact that climate change will represent a decrease of water availability, we qualitatively discuss the modifications that will result from the future climatic scenarios and their impact on nitrate pollution according to the geological setting of the selected aquifers. Climate effects in groundwater quality are described according to hydrological, environmental, socio-economic, and political concerns. Water reduction stands as a major issue that will control stream-aquifer interactions and subsurface recharge, leading to a general modification of nitrate in groundwater as dilution varies. A nitrate mass balance model provides a gross estimation of potential nitrate evolution in these aquifers, and it points out that the control of the fertilizer load will be crucial to achieve adequate nitrate content in groundwater. Reclaimed wastewater stands as local reliable resource, yet its amount will only satisfy a fraction of the loss of available resources due to climate change. Finally, an integrated management perspective is necessary to avoid unplanned actions from private initiatives that will jeopardize the achievement of sustainable water resources exploitation under distinct hydrological scenarios.

Impact of geochemical stressors on shallow groundwater quality

USGS Publications Warehouse

An, Y.-J.; Kampbell, D.H.; Jeong, S.-W.; Jewell, K.P.; Masoner, J.R.

2005-01-01

Groundwater monitoring wells (about 70 wells) were extensively installed in 28 sites surrounding Lake Texoma, located on the border of Oklahoma and Texas, to assess the impact of geochemical stressors to shallow groundwater quality. The monitoring wells were classified into three groups (residential area, agricultural area, and oil field area) depending on their land uses. During a 2-year period from 1999 to 2001 the monitoring wells were sampled every 3 months on a seasonal basis. Water quality assay consisted of 25 parameters including field parameters, nutrients, major ions, and trace elements. Occurrence and level of inorganics in groundwater samples were related to the land use and temporal change. Groundwater of the agricultural area showed lower levels of ferrous iron and nitrate than the residential area. The summer season data revealed more distinct differences in inorganic profiles of the two land use groundwater samples. There is a possible trend that nitrate concentrations in groundwater increased as the proportions of cultivated area increased. Water-soluble ferrous iron occurred primarily in water samples with a low dissolved oxygen concentration and/or a negative redox potential. The presence of brine waste in shallow groundwater was detected by chloride and conductivity in oil field area. Dissolved trace metals and volatile organic carbons were not in a form of concentration to be stressors. This study showed that the quality of shallow ground water could be related to regional geochemical stressors surrounding the lake. ?? 2005 Elsevier B.V. All rights reserved.

The High Plains Aquifer, USA: Groundwater development and sustainability

USGS Publications Warehouse

Dennehy, K.F.; Litke, D.W.; McMahon, P.B.

2002-01-01

The High Plains Aquifer, located in the United States, is one of the largest freshwater aquifers in the world and is threatened by continued decline in water levels and deteriorating water quality. Understanding the physical and cultural features of this area is essential to assessing the factors that affect this groundwater resource. About 27% of the irrigated land in the United States overlies this aquifer, which yields about 30% of the nation's groundwater used for irrigation of crops including wheat, corn, sorghum, cotton and alfalfa. In addition, the aquifer provides drinking water to 82% of the 2.3 million people who live within the aquifer boundary. The High Plains Aquifer has been significantly impacted by human activities. Groundwater withdrawals from the aquifer exceed recharge in many areas, resulting in substantial declines in groundwater level. Residents once believed that the aquifer was an unlimited resource of high-quality water, but they now face the prospect that much of the water may be gone in the near future. Also, agricultural chemicals are affecting the groundwater quality. Increasing concentrations of nitrate and salinity can first impair the use of the water for public supply and then affect its suitability for irrigation. A variety of technical and institutional measures are currently being planned and implemented across the aquifer area in an attempt to sustain this groundwater resource for future generations. However, because groundwater withdrawals remain high and water quality impairments are becoming more commonplace, the sustainability of the High Plains Aquifer is uncertain.

Variable infiltration and river flooding resulting in changing groundwater quality - A case study from Central Europe

NASA Astrophysics Data System (ADS)

Miotliński, Konrad; Postma, Dieke; Kowalczyk, Andrzej

2012-01-01

SummaryThe changes in groundwater quality occurring in a buried valley aquifer following a reduction in groundwater exploitation and enhanced infiltration due to extensive flooding of the Odra River in 1997 were investigated. Long-time series data for the chemical composition of groundwater in a large well field for drinking water supply indicated the deterioration of groundwater quality in the wells capturing water from the flooded area, which had been intensively cultivated since the 1960s. Infiltration of flooded river water into the aquifer is suggested by an elevated chloride concentration, although salt flushing from the rewatered unsaturated zone due to the enhanced recharge event is much more feasible. Concomitantly with chloride increases in the concentrations of sulphate, ferrous iron, manganese, and nickel imply the oxidation of pyrite (FeS 2) which is abundant in the aquifer. The proton production resulting from pyrite oxidation is buffered by the dissolution of calcite, while the Ca:SO 4 stoichiometry of the groundwater indicates that pyrite oxidation coupled with nitrate reduction is the dominant process occurring in the aquifer. The pyritic origin of SO42- is confirmed by the sulphur isotopic composition. The resultant Fe 2+ increase induces Mn-oxide dissolution and the mobilisation of Ni 2+ previously adsorbed to Mn-oxide surfaces. The study has a major implication for groundwater quality prediction studies where there are considerable variations in water level associated with groundwater management and climate change issues.

Hydrochemical analysis of groundwater using multivariate statistical methods - The Volta region, Ghana

USGS Publications Warehouse

Banoeng-Yakubo, B.; Yidana, S.M.; Nti, E.

2009-01-01

Q and R-mode multivariate statistical analyses were applied to groundwater chemical data from boreholes and wells in the northern section of the Volta region Ghana. The objective was to determine the processes that affect the hydrochemistry and the variation of these processes in space among the three main geological terrains: the Buem formation, Voltaian System and the Togo series that underlie the area. The analyses revealed three zones in the groundwater flow system: recharge, intermediate and discharge regions. All three zones are clearly different with respect to all the major chemical parameters, with concentrations increasing from the perceived recharge areas through the intermediate regions to the discharge areas. R-mode HCA and factor analysis (using varimax rotation and Kaiser Criterion) were then applied to determine the significant sources of variation in the hydrochemistry. This study finds that groundwater hydrochemistry in the area is controlled by the weathering of silicate and carbonate minerals, as well as the chemistry of infiltrating precipitation. This study finds that the ??D and ??18O data from the area fall along the Global Meteoric Water Line (GMWL). An equation of regression derived for the relationship between ??D and ??18O bears very close semblance to the equation which describes the GMWL. On the basis of this, groundwater in the study area is probably meteoric and fresh. The apparently low salinities and sodicities of the groundwater seem to support this interpretation. The suitability of groundwater for domestic and irrigation purposes is related to its source, which determines its constitution. A plot of the sodium adsorption ratio (SAR) and salinity (EC) data on a semilog axis, suggests that groundwater serves good irrigation quality in the area. Sixty percent (60%), 20% and 20% of the 67 data points used in this study fall within the medium salinity - low sodicity (C2-S1), low salinity -low sodicity (C1-S1) and high salinity - low sodicity (C3-S1) fields, which ascribe good irrigation quality to groundwater from this area. Salinities range from 28.1 to 1956 ??S/cm, whilst SAR values fall within the range 0-3. Extremely low sodicity waters of this kind, with salinities lower than 600 ??S/cm, have the tendency to affect the dispersive properties of irrigation soils when used for irrigation. About 50% of the groundwater in the study area fall within this category and need prior treatment before usage. ?? 2009 Korean Society of Civil Engineers and Springer-Verlag Berlin Heidelberg GmbH.

A decision tree model to estimate the value of information provided by a groundwater quality monitoring network

NASA Astrophysics Data System (ADS)

Khader, A. I.; Rosenberg, D. E.; McKee, M.

2013-05-01

Groundwater contaminated with nitrate poses a serious health risk to infants when this contaminated water is used for culinary purposes. To avoid this health risk, people need to know whether their culinary water is contaminated or not. Therefore, there is a need to design an effective groundwater monitoring network, acquire information on groundwater conditions, and use acquired information to inform management options. These actions require time, money, and effort. This paper presents a method to estimate the value of information (VOI) provided by a groundwater quality monitoring network located in an aquifer whose water poses a spatially heterogeneous and uncertain health risk. A decision tree model describes the structure of the decision alternatives facing the decision-maker and the expected outcomes from these alternatives. The alternatives include (i) ignore the health risk of nitrate-contaminated water, (ii) switch to alternative water sources such as bottled water, or (iii) implement a previously designed groundwater quality monitoring network that takes into account uncertainties in aquifer properties, contaminant transport processes, and climate (Khader, 2012). The VOI is estimated as the difference between the expected costs of implementing the monitoring network and the lowest-cost uninformed alternative. We illustrate the method for the Eocene Aquifer, West Bank, Palestine, where methemoglobinemia (blue baby syndrome) is the main health problem associated with the principal contaminant nitrate. The expected cost of each alternative is estimated as the weighted sum of the costs and probabilities (likelihoods) associated with the uncertain outcomes resulting from the alternative. Uncertain outcomes include actual nitrate concentrations in the aquifer, concentrations reported by the monitoring system, whether people abide by manager recommendations to use/not use aquifer water, and whether people get sick from drinking contaminated water. Outcome costs include healthcare for methemoglobinemia, purchase of bottled water, and installation and maintenance of the groundwater monitoring system. At current methemoglobinemia and bottled water costs of 150/person and 0.6/baby/day, the decision tree results show that the expected cost of establishing the proposed groundwater quality monitoring network exceeds the expected costs of the uninformed alternatives and there is no value to the information the monitoring system provides. However, the monitoring system will be preferred to ignoring the health risk or using alternative sources if the methemoglobinemia cost rises to 300/person or the bottled water cost increases to 2.3/baby/day. Similarly, the monitoring system has value if the system can more accurately report actual aquifer concentrations and the public more fully abides by manager recommendations to use/not use the aquifer. The system also has value if it will serve a larger population or if its installation costs can be reduced, for example using a smaller number of monitoring wells. The VOI analysis shows how monitoring system design, accuracy, installation and operating costs, public awareness of health risks, costs of alternatives, and demographics together affect the value of implementing a system to monitor groundwater quality.

A decision tree model to estimate the value of information provided by a groundwater quality monitoring network

NASA Astrophysics Data System (ADS)

Khader, A.; Rosenberg, D.; McKee, M.

2012-12-01

Nitrate pollution poses a health risk for infants whose freshwater drinking source is groundwater. This risk creates a need to design an effective groundwater monitoring network, acquire information on groundwater conditions, and use acquired information to inform management. These actions require time, money, and effort. This paper presents a method to estimate the value of information (VOI) provided by a groundwater quality monitoring network located in an aquifer whose water poses a spatially heterogeneous and uncertain health risk. A decision tree model describes the structure of the decision alternatives facing the decision maker and the expected outcomes from these alternatives. The alternatives include: (i) ignore the health risk of nitrate contaminated water, (ii) switch to alternative water sources such as bottled water, or (iii) implement a previously designed groundwater quality monitoring network that takes into account uncertainties in aquifer properties, pollution transport processes, and climate (Khader and McKee, 2012). The VOI is estimated as the difference between the expected costs of implementing the monitoring network and the lowest-cost uninformed alternative. We illustrate the method for the Eocene Aquifer, West Bank, Palestine where methemoglobinemia is the main health problem associated with the principal pollutant nitrate. The expected cost of each alternative is estimated as the weighted sum of the costs and probabilities (likelihoods) associated with the uncertain outcomes resulting from the alternative. Uncertain outcomes include actual nitrate concentrations in the aquifer, concentrations reported by the monitoring system, whether people abide by manager recommendations to use/not-use aquifer water, and whether people get sick from drinking contaminated water. Outcome costs include healthcare for methemoglobinemia, purchase of bottled water, and installation and maintenance of the groundwater monitoring system. At current methemoglobinemia and bottled water costs of 150 $/person and 0.6 $/baby/day, the decision tree results show that the expected cost of establishing the proposed groundwater quality monitoring network exceeds the expected costs of the uninformed alternatives and there is not value to the information the monitoring system provides. However, the monitoring system will be preferred to ignoring the health risk or using alternative sources if the methemoglobinemia cost rises to 300 $/person or the bottled water cost increases to 2.3 $/baby/day. Similarly, the monitoring system has value if the system can more accurately report actual aquifer concentrations and the public more fully abides by managers' recommendations to use/not use the aquifer. The system also has value if it will serve a larger population or if its installation costs can be reduced, for example using a smaller number of monitoring wells. The VOI analysis shows how monitoring system design, accuracy, installation and operating costs, public awareness of health risks, costs of alternatives, and demographics together affect the value of implementing a system to monitor groundwater quality.

Accessing groundwater quality in lower part of Nagapattinam district, Southern India: using hydrogeochemistry and GIS interpolation techniques

NASA Astrophysics Data System (ADS)

Gnanachandrasamy, G.; Ramkumar, T.; Venkatramanan, S.; Vasudevan, S.; Chung, S. Y.; Bagyaraj, M.

2015-03-01

The aim of this present study was to evaluate groundwater quality in the lower part of Nagapattinam district, Tamil Nadu, Southern India. A detailed geochemical study of groundwater region is described, and the origin of the chemical composition of groundwater has been qualitatively evaluated, using observations over a period of two seasons premonsoon (June) and monsoon (November) in the year of 2010. To attempt this goal, samples were analysed for various physico-chemical parameters such as temperature, pH, salinity, Na+, Ca2+, K+, Mg2+, Cl-, HCO3 - and SO4 2-. The abundance of major cations concentration in groundwater is as Na > Ca > Mg > K, while that of anions is Cl > SO4 > HCO3. The Piper trilinear diagram indicates Ca-Cl2 facies, and according to USSL diagram, most of the sample exhibits high salinity hazard (C3S1) type in both seasons. It indicates that high salinity (C3) and low sodium (S1) are moderately suitable for irrigation purposes. Gibbs boomerang exhibits most of the samples mainly controlled by evaporation and weathering process sector in both seasons. Irrigation status of the groundwater samples indicates that it was moderately suitable for agricultural purpose. ArcGIS 9.3 software was used for the generation of various thematic maps and the final groundwater quality map. An interpolation technique inverse distance weighting was used to obtain the spatial distribution of groundwater quality parameters. The final map classified the ground quality in the study area. The results of this research show that the development of the management strategies for the aquifer system is vitally necessary.

Hydrochemical characterization of a groundwater aquifer and its water quality in relation to irrigation in the Jinghuiqu irrigation district of China.

PubMed

Liu, Xiuhua; Li, Lin; Hu, Anyan

2013-03-01

The Jinghuiqu irrigation district is located in the semi-arid regions of northwestern China, where groundwater is the most important natural source for local industry, agriculture and residents. The present work was conducted in the Jinghuiqu irrigation district to characterize the groundwater aquifer, which has undergone long-term flood irrigation for over 2000 years. Isotopic and hydrochemical analyses, along with geological and hydrogeological tools, were used to determine the chemical properties and evolutionary processes of the groundwater aquifer. Results showed that the groundwater chemistry had changed significantly from 1990 to 2009. Water with concentrations of CaMgSO4 had decreased significantly, from 60% to 28% of the total water samples, during the period, while water with concentrations of NaSO4 and NaCl increased significantly, from 28% to 72%. The salinity of the groundwater increased rapidly and the affected area had expanded to most of the irrigation district. Stable isotope studies showed that most of the groundwater concentrations were derived from sulfate mineral dissolution. The minerals saturation indices (SI), ion ratios and oxygen isotope values of the groundwater indicated that the shallow groundwater had mainly experienced mineral dissolution, cation exchange, and mixing of the irrigated surface waters and groundwater. The groundwater quality had continuously evolved toward salinization as concentrations of SO4(2-) and Na+ grew to dominate it. Water quality risk analyses showed that most of the saline groundwater is not suitable for domestic and irrigation uses, especially in the middle and eastern parts of the irrigation district. These findings indicate that the irrigation district should strengthen the groundwater resources management.

Groundwater Quality Data for the Northern Sacramento Valley, 2007: Results from the California GAMA Program

USGS Publications Warehouse

Bennett, Peter A.; Bennett, George L.; Belitz, Kenneth

2009-01-01

Groundwater quality in the approximately 1,180-square-mile Northern Sacramento Valley study unit (REDSAC) was investigated in October 2007 through January 2008 as part of the Priority Basin Project of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The GAMA Priority Basin Project was developed in response to the Groundwater Quality Monitoring Act of 2001, and is being conducted by the U.S. Geological Survey (USGS) in cooperation with the California State Water Resources Control Board (SWRCB). The study was designed to provide a spatially unbiased assessment of the quality of raw groundwater used for public water supplies within REDSAC and to facilitate statistically consistent comparisons of groundwater quality throughout California. Samples were collected from 66 wells in Shasta and Tehama Counties. Forty-three of the wells were selected using a spatially distributed, randomized grid-based method to provide statistical representation of the study area (grid wells), and 23 were selected to aid in evaluation of specific water-quality issues (understanding wells). The groundwater samples were analyzed for a large number of synthetic organic constituents (volatile organic compounds [VOC], pesticides and pesticide degradates, and pharmaceutical compounds), constituents of special interest (perchlorate and N-nitrosodimethylamine [NDMA]), naturally occurring inorganic constituents (nutrients, major and minor ions, and trace elements), radioactive constituents, and microbial constituents. Naturally occurring isotopes (tritium, and carbon-14, and stable isotopes of nitrogen and oxygen in nitrate, stable isotopes of hydrogen and oxygen of water), and dissolved noble gases also were measured to help identify the sources and ages of the sampled ground water. In total, over 275 constituents and field water-quality indicators were investigated. Three types of quality-control samples (blanks, replicates, and sampmatrix spikes) were collected at approximately 8 to 11 percent of the wells, and the results for these samples were used to evaluate the quality of the data obtained from the groundwater samples. Field blanks rarely contained detectable concentrations of any constituent, suggesting that contamination was not a noticeable source of bias in the data for the groundwater samples. Differences between replicate samples were within acceptable ranges for nearly all compounds, indicating acceptably low variability. Matrix-spike recoveries were within acceptable ranges for most compounds. This study did not attempt to evaluate the quality of water delivered to consumers; after withdrawal from the ground, raw groundwater typically is treated, disinfected, or blended with other waters to maintain water quality. Regulatory thresholds apply to water that is served to the consumer, not to raw ground water. However, to provide some context for the results, concentrations of constituents measured in the raw groundwater were compared with regulatory and nonregulatory health-based thresholds established by the U.S. Environmental Protection Agency (USEPA) and California Department of Public Health (CDPH) and with aesthetic and technical thresholds established by CDPH. Comparisons between data collected for this study and drinking-water thresholds are for illustrative purposes only and do not indicate compliance or noncompliance with those thresholds. The concentrations of most constituents detected in groundwater samples from REDSAC were below drinking-water thresholds. Volatile organic compounds (VOC) and pesticides were detected in less than one-quarter of the samples and were generally less than a hundredth of any health-based thresholds. NDMA was detected in one grid well above the NL-CA. Concentrations of all nutrients and trace elements in samples from REDSAC wells were below the health-based thresholds except those of arsenic in three samples, which were above the USEPA maximum contaminant level (MCL-US). However

Using artificial sweeteners to identify contamination sources and infiltration zones in a coupled river-aquifer system

NASA Astrophysics Data System (ADS)

Bichler, Andrea; Muellegger, Christian; Hofmann, Thilo

2014-05-01

In shallow or unconfined aquifers the infiltration of contaminated river water might be a major threat to groundwater quality. Thus, the identification of possible contamination sources in coupled surface- and groundwater systems is of paramount importance to ensure water quality. Micropollutants like artificial sweeteners are promising markers for domestic waste water in natural water bodies. Compounds, such as artificial sweeteners, might enter the aquatic environment via discharge of waste water treatment plants, leaky sewer systems or septic tanks and are ubiquitously found in waste water receiving waters. The hereby presented field study aims at the (1) identification of contamination sources and (2) delineation of infiltration zones in a connected river-aquifer system. River bank filtrate in the groundwater body was assessed qualitatively and quantitatively using a combined approach of hydrochemical analysis and artificial sweeteners (acesulfame ACE) as waste water markers. The investigated aquifer lies within a mesoscale alpine head water catchment and is used for drinking water production. It is hypothesized that a large proportion of the groundwater flux originates from bank filtrate of a nearby losing stream. Water sampling campaigns in March and July 2012 confirmed the occurrence of artificial sweeteners at the investigated site. The municipal waste water treatment plant was identified as point-source for ACE in the river network. In the aquifer ACE was present in more than 80% of the monitoring wells. In addition, water samples were classified according to their hydrochemical composition, identifying two predominant types of water in the aquifer: (1) groundwater influenced by bank filtrate and (2) groundwater originating from local recharge. In combination with ACE concentrations a third type of water could be discriminated: (3) groundwater influence by bank filtrate but infiltrated prior to the waste water treatment plant. Moreover, the presence of ACE at elevated concentrations in aquifer zones dominated by local recharge indicated another point-source of domestic waste water. The combined analysis of ACE and conventional hydrochemical data proved to be useful to identify different sources of waste water. It is shown that the combination of physicochemical parameters and artificial sweeteners allow for a clear delineation of infiltration areas in the investigated aquifer system.

Groundwater quality assessment/corrective action feasibility plan: New TNX Seepage Basin

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nichols, R.L.

1989-12-05

The New TNX Seepage Basin is located across River Road east of the TNX Area at the Savannah River Site. Currently the basin is out of service and is awaiting closure in accordance with the Consent Decree settled under Civil Act No. 1:85-2583. Groundwater monitoring data from the detection monitoring network around the New TNX Seepage Basin was recently analyzed using South Carolina Hazardous Waste Management Regulations R.61-79.264.92 methods to determine if groundwater downgradient of the New TNX Seepage Basin had been impacted. Results from the data analysis indicate that the groundwater has been impacted by inorganic constituents with nomore » associated health risks. The impacts resulting from elevated levels of inorganic constituents, such as Mn, Na, and Total PO{sub 4} in the water table, do not pose a threat to human health and the environment.« less

Plan of study for the regional aquifer-system analysis of the San Juan structural basin, New Mexico, Colorado, Arizona, and Utah

USGS Publications Warehouse

Welder, G.E.

1986-01-01

The San Juan structural basin is an 18,000 sq mi area that contains several extensive aquifers. The basin includes three surface drainage basins and parts of New Mexico, Colorado, Arizona, and Utah. Surface water in the area is fully appropriated, and the steadily increasing demand for groundwater has resulted in water supply concerns. Competition is great between mining and electric power companies, municipalities, and Indian communities for the limited groundwater supplies. This report outlines a 4-year plan for a study of the regional aquifer system in the San Juan structural basin. The purposes of the study are to define and understand the aquifer system; to assess the effects of groundwater use on the aquifers and streams; and to determine the availability and quality of groundwater in the basin. (Author 's abstract)

California Groundwater Management During Drought: Existing and Future Regulatory Approaches

NASA Astrophysics Data System (ADS)

Ekdahl, E.; Boland-Brien, S.; Vanderburgh, B.; Landau, K.; Bean, J.; Peltier, T.

2015-12-01

Groundwater has served as an effective buffer to California's crippling drought of 2012-2015, allowing continued agricultural production in many areas where surface water deliveries have been curtailed. However, over-reliance on groundwater has caused plummeting groundwater levels in much of the state's heavily agricultural regions, with annual groundwater overdraft state-wide estimated in the millions of acre-feet per year. Prior to 2015, California water law did not allow for the effective monitoring or assessment of groundwater use; passage of new state regulations will require development of locally-managed plans that, for the first time, require comprehensive groundwater management and groundwater basin sustainability. Because these plans are not required to be implemented for another 25 years, groundwater levels will likely continue to decrease. Some communities that are 100-percent reliant on groundwater as a source of municipal supply may face shortages and supply issues, which may exacerbate known water quality concerns. Examination of community water systems that are reliant on groundwater, their existing water quality issues, and their response to the current drought (through existing mandatory conservation requirements imposed by California state regulators) can identify areas that are particularly susceptible to continued groundwater overdraft.

Integrated hydrochemical and geophysical studies for assessment of groundwater pollution in basaltic settings in Central India.

PubMed

Pujari, Paras R; Padmakar, C; SuriNaidu, L; Vaijnath, V U; Kachawe, Bhusan; Gurunadha Rao, V V S; Labhasetwar, P K

2012-05-01

The Pithampur Industrial sectors I, II, and III, located approximately, 45 km from Indore in Central India have emerged as one of the largest industrial clusters in the region. Various types of industries ranging from automobiles to chemicals and pharmaceuticals have been set up in the region since 1990. Most of the industries have effluent treatment plants (ETP) for treating wastewater before its disposal on land and/or in water body. The present study is an attempt to assess the groundwater quality in the watersheds surrounding these industrial sectors to develop the baseline groundwater quality in order to enable the policy makers to facilitate decisions on the development of industries in this region. The industries are located in two sub-watersheds, namely, Gambhir river sub-watershed and Chambal river sub-watershed. Geologically, the study area is located in the Deccan traps of Cretaceous to Paleocene age. The different basaltic flow units underlie clayey soils varying in thickness from 2-3 m. The aquifer is mostly of unconfined nature. Samples have been collected from a network of observation wells set up in the watersheds. The water quality analysis of the groundwater samples has been carried out six times during three hydrological cycles of 2004, 2005, and 2006. The results indicate that a few observation wells in the vicinity of the industrial clusters have very high TDS concentration and exceed the Bureau of Indian Standards (BIS) guideline for TDS concentration. The contamination of groundwater has been more severe in the Gambhir watershed as compared to the Chambal watershed. The presence of the impermeable clay layers has resulted in a slow migration of contaminants from the sources. The findings reveal that there is no significant groundwater contamination in the Pithampur industrial sectors except in the vicinity of the industrial clusters, which indicates that there is good environmental space available for the expansion of industrial units in the Pithampur industrial hub.

Groundwater quality & sustainability in Ulaanbaatar, the fast growing Capital of Mongolia

NASA Astrophysics Data System (ADS)

Batsaikhan, N.; Woo, N. C.; Nemer, B.

2011-12-01

About 40% (1.1 million out of 2.7 million total) of Mongolian population lives in the capital city, Ulaanbaatar. The city's drinking water totally depends on groundwater pumped from the alluvial aquifer along the Tuul River and some private wells for domestic usage. As a measure to evaluate groundwater conditions, a total 55 samples from groundwater and surface waters were collected in the public central well-field and its adjacent area from August 2010 to Feb. 2011, for characteristics of water chemistry and environmental isotopic signatures. The water types were classified with Ca-Mg-HCO3, Ca-Na-HCO3 and Ca-HCO3 in summer, but predominantly Ca-HCO3 in winter. Statistical analysis of water compositions shows two groups of water: group-A waters from the Public central supply well-field with Tuul river waters, and group-B from other area including Ger dwelling areas. In terms of water quality, nitrate concentrations exceeded the WHO Guidelines for drinking-water quality (50 mg/l) in 55% (15 out of 27 samples) of the group-B; it implies that the potential sources of groundwater contamination be domestic waste-disposal practices and underdeveloped sewage systems. Environmental isotopes and water-level monitoring data indicated that shallow wells, showing the depth to water less than 3 m bgs, appear to be directly recharged from rainfalls and river water. In contrast, wells with the depth to water in between 5 and 7 m and located some distance from Tuul River take approximately 2 to 3 months to be recharged in rainy season. Since Ulaanbaatar has been growing fast as the Capital of Mongolia, various types of potential sources of groundwater contamination have also been located inside the city boundary including tanning industries, coal-based thermal power plants, gas stations, etc. Thus, for the sustainable development of the Capitol, it is warranted to develop better management measures with long-term and systematic monitoring to protect water-supply sources.

Selected water-quality data from the Cedar River and Cedar Rapids well fields, Cedar Rapids, Iowa, 2006-10

USGS Publications Warehouse

Littin, Gregory R.

2012-01-01

The Cedar River alluvial aquifer is the primary source of municipal water in the Cedar Rapids, Iowa area. Municipal wells are completed in the alluvial aquifer approximately 40 to 80 feet below land surface. The City of Cedar Rapids and the U.S. Geological Survey have been conducting a cooperative study of the groundwater-flow system and water quality of the aquifer since 1992. Cooperative reports between the City of Cedar Rapids and the U.S. Geological Survey have documented hydrologic and water-quality data, geochemistry, and groundwater models. Water-quality samples were collected for studies involving well field monitoring, trends, source-water protection, groundwater geochemistry, surface-water-groundwater interaction, and pesticides in groundwater and surface water. Water-quality analyses were conducted for major ions (boron, bromide, calcium, chloride, fluoride, iron, magnesium, manganese, potassium, silica, sodium, and sulfate), nutrients (ammonia as nitrogen, nitrite as nitrogen, nitrite plus nitrate as nitrogen, and orthophosphate as phosphorus), dissolved organic carbon, and selected pesticides including two degradates of the herbicide atrazine. Physical characteristics (alkalinity, dissolved oxygen, pH, specific conductance and water temperature) were measured in the field and recorded for each water sample collected. This report presents the results of routine water-quality data-collection activities from January 2006 through December 2010. Methods of data collection, quality-assurance, and water-quality analyses are presented. Data include the results of water-quality analyses from quarterly sampling from monitoring wells, municipal wells, and the Cedar River.

Environmental quality assessment of groundwater resources in Al Jabal Al Akhdar, Sultanate of Oman

NASA Astrophysics Data System (ADS)

Al-Kalbani, Mohammed Saif; Price, Martin F.; Ahmed, Mushtaque; Abahussain, Asma; O'Higgins, Timothy

2017-11-01

The research was conducted to assess the quality of groundwater resources of Al Jabal Al Akhdar, Oman. 11 drinking water sources were sampled during summer and winter seasons during 2012-2013 to evaluate their physico-chemical quality indicators; and assess their suitability for drinking and other domestic purposes. Sample collection, handling and processing followed the standard methods recommended by APHA and analyzed in quality assured laboratories using appropriate analytical methods and instrumental techniques. The results show that the quality parameters in all drinking water resources are within the permissible limits set by Omani and WHO standards; and the drinking water quality index is good or medium in quality based on NFS-WQI classification criteria, indicating their suitability for human consumption. There is an indication of the presence of high nitrate concentrations in some groundwater wells, which require more investigations and monitoring program to be conducted on regular basis to ensure good quality water supply for the residents in the mountain. The trilinear Piper diagram shows that most of the drinking water resources of the study area fall in the field of calcium and bicarbonate type with some magnesium bicarbonate type indicating that most of the major ions are natural in origin due to the geology of the region. This study is a first step towards providing indicators on groundwater quality of this fragile mountain ecosystem, which will be the basis for future planning decisions on corrective demand management measures to protect groundwater resources of Al Jabal Al Akhdar.

30 CFR 950.16 - Required program amendments.

Code of Federal Regulations, 2011 CFR

2011-07-01

... provide that the groundwater quality description in a permit application must include pH. (i) By June 30... propose to amend its program to specify the minimum groundwater quality parameters that must be monitored...

30 CFR 950.16 - Required program amendments.

Code of Federal Regulations, 2013 CFR

2013-07-01

... provide that the groundwater quality description in a permit application must include pH. (i) By June 30... propose to amend its program to specify the minimum groundwater quality parameters that must be monitored...

30 CFR 950.16 - Required program amendments.

Code of Federal Regulations, 2012 CFR

2012-07-01

... provide that the groundwater quality description in a permit application must include pH. (i) By June 30... propose to amend its program to specify the minimum groundwater quality parameters that must be monitored...

Estimates of natural ground-water discharge and characterization of water quality in Dry Valley, Washoe County, West-Central Nevada, 2002-2003

USGS Publications Warehouse

Berger, David L.; Maurer, Douglas K.; Lopes, Thomas J.; Halford, Keith J.

2004-01-01

The Dry Valley Hydrographic Area is being considered as a potential source area for additional water supplies for the Reno-Sparks area, which is about 25 miles south of Dry Valley. Current estimates of annual ground-water recharge to Dry Valley have a considerable range. In undeveloped valleys, such as Dry Valley, long-term ground-water discharge can be assumed the same as long-term ground-water recharge. Because estimating ground-water discharge has more certainty than estimating ground-water recharge from precipitation, the U.S. Geological Survey, in cooperation with Washoe County, began a three-year study to re-evaluate the ground-water resources by estimating natural ground-water discharge and characterize ground-water quality in Dry Valley. In Dry Valley, natural ground-water discharge occurs as subsurface outflow and by ground-water evapotranspiration. The amount of subsurface outflow from the upper part of Dry Valley to Winnemucca and Honey Lake Valleys likely is small. Subsurface outflow from Dry Valley westward to Long Valley, California was estimated using Darcy's Law. Analysis of two aquifer tests show the transmissivity of poorly sorted sediments near the western side of Dry Valley is 1,200 to 1,500 square feet per day. The width of unconsolidated sediments is about 4,000 feet between exposures of tuffaceous deposits along the State line, and decreases to about 1,500 feet (0.5 mile) west of the State line. The hydraulic gradient east and west of the State line ranges from 0.003 to 0.005 foot per foot. Using these values, subsurface outflow to Long Valley is estimated to be 50 to 250 acre-feet per year. Areas of ground-water evapotranspiration were field mapped and partitioned into zones of plant cover using relations derived from Landsat imagery acquired July 8, 2002. Evapotranspiration rates for each plant-cover zone were multiplied by the corresponding area and summed to estimate annual ground-water evapotranspiration. About 640 to 790 acre-feet per year of ground water is lost to evapotranspiration in Dry Valley. Combining subsurface-outflow estimates with ground-water evapotranspiration estimates, total natural ground-water discharge from Dry Valley ranges from a minimum of about 700 acre-feet to a maximum of about 1,000 acre-feet annually. Water quality in Dry Valley generally is good and primary drinking-water standards were not exceeded in any samples collected. The secondary standard for manganese was exceeded in three ground-water samples. One spring sample and two surface-water samples exceeded the secondary standard for pH. Dry Valley has two primary types of water chemistry that are distinguishable by cation ratios and related to the two volcanic-rock units that make up much of the surrounding mountains. In addition, two secondary types of water chemistry appear to have evolved by evaporation of the primary water types. Ground water near the State line appears to be an equal mixture of the two primary water chemistries and has as an isotopic characteristic similar to evaporated surface water.

Knowing requires data

USGS Publications Warehouse

Naranjo, Ramon C.

2017-01-01

Groundwater-flow models are often calibrated using a limited number of observations relative to the unknown inputs required for the model. This is especially true for models that simulate groundwater surface-water interactions. In this case, subsurface temperature sensors can be an efficient means for collecting long-term data that capture the transient nature of physical processes such as seepage losses. Continuous and spatially dense network of diverse observation data can be used to improve knowledge of important physical drivers, conceptualize and calibrate variably saturated groundwater flow models. An example is presented for which the results of such analysis were used to help guide irrigation districts and water management decisions on costly upgrades to conveyance systems to improve water usage, farm productivity and restoration efforts to improve downstream water quality and ecosystems.

Groundwater-quality data in seven GAMA study units: results from initial sampling, 2004-2005, and resampling, 2007-2008, of wells: California GAMA Program Priority Basin Project

USGS Publications Warehouse

Kent, Robert; Belitz, Kenneth; Fram, Miranda S.

2014-01-01

The Priority Basin Project (PBP) of the Groundwater Ambient Monitoring and Assessment (GAMA) Program was developed in response to the Groundwater Quality Monitoring Act of 2001 and is being conducted by the U.S. Geological Survey (USGS) in cooperation with the California State Water Resources Control Board (SWRCB). The GAMA-PBP began sampling, primarily public supply wells in May 2004. By the end of February 2006, seven (of what would eventually be 35) study units had been sampled over a wide area of the State. Selected wells in these first seven study units were resampled for water quality from August 2007 to November 2008 as part of an assessment of temporal trends in water quality by the GAMA-PBP. The initial sampling was designed to provide a spatially unbiased assessment of the quality of raw groundwater used for public water supplies within the seven study units. In the 7 study units, 462 wells were selected by using a spatially distributed, randomized grid-based method to provide statistical representation of the study area. Wells selected this way are referred to as grid wells or status wells. Approximately 3 years after the initial sampling, 55 of these previously sampled status wells (approximately 10 percent in each study unit) were randomly selected for resampling. The seven resampled study units, the total number of status wells sampled for each study unit, and the number of these wells resampled for trends are as follows, in chronological order of sampling: San Diego Drainages (53 status wells, 7 trend wells), North San Francisco Bay (84, 10), Northern San Joaquin Basin (51, 5), Southern Sacramento Valley (67, 7), San Fernando–San Gabriel (35, 6), Monterey Bay and Salinas Valley Basins (91, 11), and Southeast San Joaquin Valley (83, 9). The groundwater samples were analyzed for a large number of synthetic organic constituents (volatile organic compounds [VOCs], pesticides, and pesticide degradates), constituents of special interest (perchlorate, N-nitrosodimethylamine [NDMA], and 1,2,3-trichloropropane [1,2,3-TCP]), and naturally-occurring inorganic constituents (nutrients, major and minor ions, and trace elements). Naturally-occurring isotopes (tritium, carbon-14, and stable isotopes of hydrogen and oxygen in water) also were measured to help identify processes affecting groundwater quality and the sources and ages of the sampled groundwater. Nearly 300 constituents and water-quality indicators were investigated. Quality-control samples (blanks, replicates, and samples for matrix spikes) were collected at 24 percent of the 55 status wells resampled for trends, and the results for these samples were used to evaluate the quality of the data for the groundwater samples. Field blanks rarely contained detectable concentrations of any constituent, suggesting that contamination was not a noticeable source of bias in the data for the groundwater samples. Differences between replicate samples were mostly within acceptable ranges, indicating acceptably low variability in analytical results. Matrix-spike recoveries were within the acceptable range (70 to 130 percent) for 75 percent of the compounds for which matrix spikes were collected. This study did not attempt to evaluate the quality of water delivered to consumers. After withdrawal, groundwater typically is treated, disinfected, and blended with other waters to maintain acceptable water quality. The benchmarks used in this report apply to treated water that is served to the consumer, not to untreated groundwater. To provide some context for the results, however, concentrations of constituents measured in these groundwater samples were compared with benchmarks established by the U.S. Environmental Protection Agency (USEPA) and California Department of Public Health (CDPH). Comparisons between data collected for this study and benchmarks for drinking water are for illustrative purposes only and are not indicative of compliance or non-compliance with those benchmarks. Most constituents that were detected in groundwater samples from the trend wells were found at concentrations less than drinking-water benchmarks. Four VOCs—trichloroethene, tetrachloroethene, 1,2-dibromo-3-chloropropane, and methyl tert-butyl ether—were detected in one or more wells at concentrations greater than their health-based benchmarks, and six VOCs were detected in at least 10 percent of the samples during initial sampling or resampling of the trend wells. No pesticides were detected at concentrations near or greater than their health-based benchmarks. Three pesticide constituents—atrazine, deethylatrazine, and simazine—were detected in more than 10 percent of the trend-well samples during both sampling periods. Perchlorate, a constituent of special interest, was detected more frequently, and at greater concentrations during resampling than during initial sampling, but this may be due to a change in analytical method between the sampling periods, rather than to a change in groundwater quality. Another constituent of special interest, 1,2,3-TCP, was also detected more frequently during resampling than during initial sampling, but this pattern also may not reflect a change in groundwater quality. Samples from several of the wells where 1,2,3-TCP was detected by low-concentration-level analysis during resampling were not analyzed for 1,2,3-TCP using a low-level method during initial sampling. Most detections of nutrients and trace elements in samples from trend wells were less than health-based benchmarks during both sampling periods. Exceptions include nitrate, arsenic, boron, and vanadium, all detected at concentrations greater than their health-based benchmarks in at least one well during both sampling periods, and molybdenum, detected at concentrations greater than its health-based benchmark during resampling only. The isotopic ratios of oxygen and hydrogen in water and tritium and carbon-14 activities generally changed little between sampling periods, suggesting that the predominant sources and ages of groundwater in most trend wells were consistent between the sampling periods.

Assessing local planning to control groundwater depletion: California as a microcosm of global issues

NASA Astrophysics Data System (ADS)

Nelson, Rebecca L.

2012-01-01

Groundwater pumping has caused excessive groundwater depletion around the world, yet regulating pumping remains a profound challenge. California uses more groundwater than any other U.S. state, and serves as a microcosm of the adverse effects of pumping felt worldwide—land subsidence, impaired water quality, and damaged ecosystems, all against the looming threat of climate change. The state largely entrusts the control of depletion to the local level. This study uses internationally accepted water resources planning theories systematically to investigate three key aspects of controlling groundwater depletion in California, with an emphasis on local-level action: (a) making decisions and engaging stakeholders; (b) monitoring groundwater; and (c) using mandatory, fee-based and voluntary approaches to control groundwater depletion (e.g., pumping restrictions, pumping fees, and education about water conservation, respectively). The methodology used is the social science-derived technique of content analysis, which involves using a coding scheme to record these three elements in local rules and plans, and State legislation, then analyzing patterns and trends. The study finds that Californian local groundwater managers rarely use, or plan to use, mandatory and fee-based measures to control groundwater depletion. Most use only voluntary approaches or infrastructure to attempt to reduce depletion, regardless of whether they have more severe groundwater problems, or problems which are more likely to have irreversible adverse effects. The study suggests legal reforms to the local groundwater planning system, drawing upon its empirical findings. Considering the content of these recommendations may also benefit other jurisdictions that use a local groundwater management planning paradigm.

Status of groundwater quality in the Southern, Middle, and Northern Sacramento Valley study units, 2005-08: California GAMA Priority Basin Project

USGS Publications Warehouse

Bennett, George L.; Fram, Miranda S.; Belitz, Kenneth

2011-01-01

Groundwater quality in the Southern, Middle, and Northern Sacramento Valley study units was investigated as part of the Priority Basin Project of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The study units are located in California's Central Valley and include parts of Butte, Colusa, Glenn, Placer, Sacramento, Shasta, Solano, Sutter, Tehama, Yolo, and Yuba Counties. The GAMA Priority Basin Project is being conducted by the California State Water Resources Control Board in collaboration with the U.S. Geological Survey and the Lawrence Livermore National Laboratory. The three study units were designated to provide spatially-unbiased assessments of the quality of untreated groundwater in three parts of the Central Valley hydrogeologic province, as well as to provide a statistically consistent basis for comparing water quality regionally and statewide. Samples were collected in 2005 (Southern Sacramento Valley), 2006 (Middle Sacramento Valley), and 2007-08 (Northern Sacramento Valley). The GAMA studies in the Southern, Middle, and Northern Sacramento Valley were designed to provide statistically robust assessments of the quality of untreated groundwater in the primary aquifer systems that are used for drinking-water supply. The assessments are based on water-quality data collected by the USGS from 235 wells in the three study units in 2005-08, and water-quality data from the California Department of Public Health (CDPH) database. The primary aquifer systems (hereinafter, referred to as primary aquifers) assessed in this study are defined by the depth intervals of the wells in the CDPH database for each study unit. The quality of groundwater in shallow or deep water-bearing zones may differ from quality of groundwater in the primary aquifers; shallow groundwater may be more vulnerable to contamination from the surface. The status of the current quality of the groundwater resource was assessed by using data from samples analyzed for volatile organic compounds (VOC), pesticides, and naturally occurring inorganic constituents, such as major ions and trace elements. This status assessment is intended to characterize the quality of groundwater resources within the primary aquifers of the three Sacramento Valley study units, not the treated drinking water delivered to consumers by water purveyors. Relative-concentrations (sample concentrations divided by benchmark concentrations) were used for evaluating groundwater quality for those constituents that have Federal or California regulatory or non-regulatory benchmarks for drinking-water quality. A relative-concentration greater than 1.0 indicates a concentration greater than a benchmark. For organic (volatile organic compounds and pesticides) and special-interest (perchlorate) constituents, relative-concentrations were classified as high (greater than 1.0); moderate (equal to or less than 1.0 and greater than 0.1); or low (equal to or less than 0.1). For inorganic (major ion, trace element, nutrient, and radioactive) constituents, the boundary between low and moderate relative-concentrations was set at 0.5. Aquifer-scale proportions were used in the status assessment for evaluating regional-scale groundwater quality. High aquifer-scale proportion is defined as the percentage of the area of the primary aquifers that have a relative-concentration greater than 1.0 for a particular constituent or class of constituents; percentage is based on an areal rather than a volumetric basis. Moderate and low aquifer-scale proportions were defined as the percentage of the primary aquifers that have moderate and low relative-concentrations, respectively. Two statistical approaches-grid-based, which used one value per grid cell, and spatially-weighted, which used the full dataset-were used to calculate aquifer-scale proportions for individual constituents and classes of constituents. High and moderate aquifer-scale proportions were significantly greater for inorgani

40 CFR 257.22 - Ground-water monitoring systems.

Code of Federal Regulations, 2012 CFR

2012-07-01

... defined in § 257.5(b)) that: (1) Represent the quality of background ground water that has not been affected by leakage from a unit. A determination of background quality may include sampling of wells that... at other wells will provide an indication of background ground-water quality that is as...

40 CFR 258.51 - Ground-water monitoring systems.

Code of Federal Regulations, 2010 CFR

2010-07-01

... the uppermost aquifer (as defined in § 258.2) that: (1) Represent the quality of background ground water that has not been affected by leakage from a unit. A determination of background quality may...; or (ii) Sampling at other wells will provide an indication of background ground-water quality that is...

U.S. Geological Survey quality-assurance plan for continuous water-quality monitoring in Kansas, 2014

USGS Publications Warehouse

Bennett, Trudy J.; Graham, Jennifer L.; Foster, Guy M.; Stone, Mandy L.; Juracek, Kyle E.; Rasmussen, Teresa J.; Putnam, James E.

2014-01-01

A quality-assurance plan for use in conducting continuous water-quality monitoring activities has been developed for the Kansas Water Science Center in accordance with guidelines set forth by the U.S. Geological Survey. This quality-assurance plan documents the standards, policies, and procedures used by the U.S. Geological Survey in Kansas for activities related to the collection, processing, storage, analysis, and release of continuous water-quality monitoring data. The policies and procedures that are documented in this quality-assurance plan for continuous water-quality monitoring activities complement quality-assurance plans for surface-water and groundwater activities in Kansas.

Quality-assurance plan for water-quality activities in the U.S. Geological Survey Washington Water Science Center

USGS Publications Warehouse

Conn, Kathleen E.; Huffman, Raegan L.; Barton, Cynthia

2017-05-08

In accordance with guidelines set forth by the Office of Water Quality in the Water Mission Area of the U.S. Geological Survey, a quality-assurance plan has been created for use by the Washington Water Science Center (WAWSC) in conducting water-quality activities. This qualityassurance plan documents the standards, policies, and procedures used by the WAWSC for activities related to the collection, processing, storage, analysis, and publication of water-quality data. The policies and procedures documented in this quality-assurance plan for water-quality activities complement the quality-assurance plans for surface-water and groundwater activities at the WAWSC.

Groundwater conditions in Utah, spring of 2015

USGS Publications Warehouse

Burden, Carole B.

2015-01-01

This is the fifty-second in a series of annual reports that describe groundwater conditions in Utah. Reports in this series, published cooperatively by the U.S. Geological Survey and the Utah Department of Natural Resources, Division of Water Rights, and the Utah Department of Environmental Quality, Division of Water Quality, provide data to enable interested parties to maintain awareness of changing groundwater conditions. This report, like the others in the series, contains information on well construction, groundwater withdrawals from wells, water-level changes, precipitation, streamflow, and chemical quality of water. Information on well construction included in this report refers only to new wells constructed for withdrawal of groundwater. Supplementary data are included in reports of this series only for those years or areas that are important to a discussion of changing groundwater conditions and for which applicable data are available.This report includes individual discussions of selected significant areas of groundwater development in the State for calendar year 2014. Most of the reported data were collected by the U.S. Geological Survey in cooperation with the Utah Department of Natural Resources, Division of Water Rights, and the Utah Department of Environmental Quality, Division of Water Quality. This report is also available online at http://www.waterrights.utah.gov/techinfo/ and http://ut.water.usgs.gov/publications/GW2015.pdf. Groundwater conditions in Utah for calendar year 2013 are reported in Burden and others (2014) and are available online at http://ut.water.usgs.gov/publications/GW2014.pdf.The water-level change maps in this report show the difference between water levels measured in the same well at two distinct times: in the spring of 1985 and the spring of 2015. Throughout the state, many groundwater levels were near their peak in or around 1985 following a multiple-year period of above average precipitation in the early 1980s. Conversely, consecutive years of significant drought have contributed to low groundwater levels in 2015. For these reasons, the difference between 1985 and 2015 groundwater levels may not accurately portray long-term changes in an aquifer. An evaluation of water-level trends should also include consideration of the annual water-level measurement plots provided for each of the major areas of groundwater development in this report.

Impact of Past Land Use Changes on Drinking Water Quantity and Quality in Ljubljana Aquifer

NASA Astrophysics Data System (ADS)

Bracic Zeleznik, Branka; Cencur Curk, Barbara

2010-05-01

Most of the practical problems that we face today with the on-site management of drinking water sources and distribution of healthy drinking water, originate from past actions, interventions and political decisions. In Ljubljana, the capital of the Republic of Slovenia, underlying groundwater is the main drinking water source. The main threat to drinking water sources is constant input of pollutant loads from roads, roofs, sewers, industry and agricultural areas. The main problems are directly and indirectly related to the significant decrease of groundwater level and deterioration of groundwater quality observed in the last decades as an effect of land use practices under varying climate conditions. The Vodovod-Kanalizacija Public Utility is responsible for water supply of the city residents as well as for management of the water supply system, its surveillance and maintenance. In the past, the Ljubljana Municipality was responsible for the protection of water resources and the first delineation of groundwater protection areas was issued in Decree in 1955. In 2004 a Decree on the water protection zones for the aquifer of Ljubljansko polje on the state level was issued and passed the competences of proclamation of the water protection zones to the state. Spatial planning is a domain of The Municipality and land use is limited according to water protection legislation. For several observation wells long-time data sets about groundwater levels and quality are available, which enable us to analyse changes in groundwater quantity and quality parameters. From the data it is obvious that climate variations are affecting groundwater recharge. In addition, changing of land use affects groundwater quality. In spite of the Decree on the water protection there is a heavy pressure of investors to change land use plans and regulations on protection zones, which causes every day problems in managing the drinking water source. Groundwater management in Ljubljana demands strong and effective co-operation between state, municipality, public water supply company and consumers.

Monitoring of Emerging and Legacy Contaminants in Groundwater and Tap Water of the Karst Region in Northern Puerto Rico for Assessment of Sources and Fate and Transport Processes

NASA Astrophysics Data System (ADS)

Padilla, I. Y.; Cotto, I.; Torres, P. M.

2014-12-01

The karst aquifer region of northern Puerto Rico is the area with the highest groundwater extraction in the island. Urban and industrial development has led to extensive contamination of the groundwater in the region. Of particular concern, is the presence of emerging and legacy organic contaminants, such as phthalates and chlorinated organic compounds (CVOCs), because there high risk for exposure and adverse health impact. Variable sources and the heterogeneous and dynamic conditions of karst groundwater systems, limits the ability to properly assess and manage the water quality of these precious water resources. This work develops a monitoring and water analysis scheme to assess spatial-temporal exposure of hazardous contaminants trough karst water in northern Puerto Rico. Groundwater and tap water are sampled in the region and analyzed for phthalates, CVOCs, and common ions. Detections and concentrations of phthalates and CVOCs are determined by using modified EPA methods, which rely on liquid-liquid extractions and gas chromatography techniques. The modified methods have reduced the volume of samples and solvent waste, decreased the time of analysis, increased analysis outcomes, and lower potential for hazardous exposure. Results show intermittent presence of di-ethyl, di-butyl and di (2-ethyl hexyl) phthalates in 36% of the groundwater and 53% of tap water samples, with detected concentrations ranging between 0.1-88.7 μg/L. These results indicate that karst groundwater can serve as a route of exposure for phthalates, but there are additional disperse sources in the water system. CVOCs are detected in groundwater at much higher frequencies (50%) than phthalates, and include trichloromethane (TCM), carbon tetrachloride (CT), trichloroethylene (TCE), and tetrachloroethylene (TCE). CVOCs, except for TCM, are found at lower frequencies on tap water (5.8%) than groundwater (27%). TCM is detected more frequently and at higher concentrations in tap water (56.8%) than tap water (30%). Results indicated that most CVOCs on tap water come from groundwater sources. Spatial-temporal analysis of CVOC data shows that transport through karst system is highly heterogeneous variable, and reflect high capacity of the system to store and slowly release contaminants through rate-limited mass transport process.

The CHPRC Groundwater and Technical Integration Support (Master Project) Quality Assurance Management Plan

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fix, N. J.

The scope of the CH2M Hill Plateau Remediation Company, LLC (CHPRC) Groundwater and Technical Integration Support (Master Project) is for Pacific Northwest National Laboratory staff to provide technical and integration support to CHPRC. This work includes conducting investigations at the 300-FF-5 Operable Unit and other groundwater operable units, and providing strategic integration, technical integration and assessments, remediation decision support, and science and technology. The projects under this Master Project will be defined and included within the Master Project throughout the fiscal year, and will be incorporated into the Master Project Plan. This Quality Assurance Management Plan provides the quality assurancemore » requirements and processes that will be followed by the CHPRC Groundwater and Technical Integration Support (Master Project) and all releases associated with the CHPRC Soil and Groundwater Remediation Project. The plan is designed to be used exclusively by project staff.« less

Overview of groundwater sources and water-supply systems, and associated microbial pollution, in Finland, Norway and Iceland

NASA Astrophysics Data System (ADS)

Kløve, Bjørn; Kvitsand, Hanne Margrethe Lund; Pitkänen, Tarja; Gunnarsdottir, Maria J.; Gaut, Sylvi; Gardarsson, Sigurdur M.; Rossi, Pekka M.; Miettinen, Ilkka

2017-06-01

The characteristics of groundwater systems and groundwater contamination in Finland, Norway and Iceland are presented, as they relate to outbreaks of disease. Disparities among the Nordic countries in the approach to providing safe drinking water from groundwater are discussed, and recommendations are given for the future. Groundwater recharge is typically high in autumn or winter months or after snowmelt in the coldest regions. Most inland aquifers are unconfined and therefore vulnerable to pollution, but they are often without much anthropogenic influence and the water quality is good. In coastal zones, previously emplaced marine sediments may confine and protect aquifers to some extent. However, the water quality in these aquifers is highly variable, as the coastal regions are also most influenced by agriculture, sea-water intrusion and urban settlements resulting in challenging conditions for water abstraction and supply. Groundwater is typically extracted from Quaternary deposits for small and medium municipalities, from bedrock for single households, and from surface water for the largest cities, except for Iceland, which relies almost entirely on groundwater for public supply. Managed aquifer recharge, with or without prior water treatment, is widely used in Finland to extend present groundwater resources. Especially at small utilities, groundwater is often supplied without treatment. Despite generally good water quality, microbial contamination has occurred, principally by norovirus and Campylobacter, with larger outbreaks resulting from sewage contamination, cross-connections into drinking water supplies, heavy rainfall events, and ingress of polluted surface water to groundwater.

Ground-water conditions in Utah, spring of 2007

USGS Publications Warehouse

Burden, Carole B.; Allen, David V.; Danner, M.R.; Enright, Michael; Cillessen, J.L.; Gerner, S.J.; Eacret, Robert J.; Downhour, Paul; Slaugh, Bradley A.; Swenson, Robert L.; Howells, James H.; Christiansen, Howard K.; Fisher, Martel J.

2007-01-01

This is the forty-fourth in a series of annual reports that describe ground-water conditions in Utah. Reports in this series, published cooperatively by the U.S. Geological Survey and the Utah Department of Natural Resources, Division of Water Resources and Division of Water Rights, and the Utah Department of Environmental Quality, Division of Water Quality, provide data to enable interested parties to maintain awareness of changing ground-water conditions.This report, like the others in the series, contains information on well construction, ground-water withdrawal from wells, water-level changes, precipitation, streamflow, and chemical quality of water. Information on well construction included in this report refers only to wells constructed for new appropriations of ground water. Supplementary data are included in reports of this series only for those years or areas which are important to a discussion of changing ground-water conditions and for which applicable data are available.This report includes individual discussions of selected significant areas of ground-water development in the State for calendar year 2006. Most of the reported data were collected by the U.S. Geological Survey in cooperation with the Utah Department of Natural Resources, Division of Water Resources and Division of Water Rights, and the Utah Department of Environmental Quality, Division of Water Quality. This report is available online at http://www.waterrights.utah. gov/ and http://ut.water.usgs.gov/newUTAH/GW2007.pdf.

Ground-water conditions in Utah, spring of 2008

USGS Publications Warehouse

Burden, Carole B.; Allen, David V.; Danner, M.R.; Fisher, Martel J.; Freeman, Michael L.; Downhour, Paul; Wilkowske, C.D.; Eacret, Robert J.; Enright, Michael; Swenson, Robert L.; Howells, James H.; Christiansen, Howard K.

2008-01-01

This is the forty-fifth in a series of annual reports that describe ground-water conditions in Utah. Reports in this series, published cooperatively by the U.S. Geological Survey and the Utah Department of Natural Resources, Division of Water Resources and Division of Water Rights, and the Utah Department of Environmental Quality, Division of Water Quality, provide data to enable interested parties to maintain awareness of changing ground-water conditions.This report, like the others in the series, contains information on well construction, ground-water withdrawal from wells, water-level changes, precipitation, streamflow, and chemical quality of water. Information on well construction included in this report refers only to wells constructed for new appropriations of ground water. Supplementary data are included in reports of this series only for those years or areas which are important to a discussion of changing ground-water conditions and for which applicable data are available.This report includes individual discussions of selected significant areas of ground-water development in the State for calendar year 2007. Most of the reported data were collected by the U.S. Geological Survey in cooperation with the Utah Department of Natural Resources, Division of Water Resources and Division of Water Rights, and the Utah Department of Environmental Quality, Division of Water Quality. This report is available online at http://www.waterrights.utah.gov/techinfo/ and http://ut.water.usgs.gov/publications/GW2008.pdf.

Ground-water conditions in Utah, spring of 2009

USGS Publications Warehouse

Burden, Carole B.; Allen, David V.; Rowland, Ryan C.; Fisher, Martel J.; Freeman, Michael L.; Downhour, Paul; Nielson, Ashley; Eacret, Robert J.; Myers, Andrew; Slaugh, Bradley A.; Swenson, Robert L.; Howells, James H.; Christiansen, Howard K.

2009-01-01

This is the forty-sixth in a series of annual reports that describe ground-water conditions in Utah. Reports in this series, published cooperatively by the U.S. Geological Survey and the Utah Department of Natural Resources, Division of Water Resources and Division of Water Rights, and the Utah Department of Environmental Quality, Division of Water Quality, provide data to enable interested parties to maintain awareness of changing ground-water conditions. This report, like the others in the series, contains information on well construction, ground-water withdrawal from wells, water-level changes, precipitation, streamflow, and chemical quality of water. Information on well construction included in this report refers only to wells constructed for new appropriations of ground water. Supplementary data are included in reports of this series only for those years or areas which are important to a discussion of changing ground-water conditions and for which applicable data are available.This report includes individual discussions of selected significant areas of ground-water development in the State for calendar year 2008. Most of the reported data were collected by the U.S. Geological Survey in cooperation with the Utah Department of Natural Resources, Division of Water Resources and Division of Water Rights, and the Utah Department of Environmental Quality, Division of Water Quality. This report is available online at http://www.waterrights. utah.gov/techinfo/ and http://ut.water.usgs.gov/publications/ GW2009.pdf.

Impact of textile dyeing industries effluent on groundwater quality in Karur Amaravathi River basin, Tamil Nadu (India)--a field study.

PubMed

Rajamanickam, R; Nagan, S

2010-10-01

Karur is an industrial town located on the bank of river Amaravathi. There are 487 textile processing units in operation and discharge about 14610 kilo litres per day of treated effluent into the river. The groundwater quality in the downstream is deteriorated due to continuous discharge of effluent. In order to assess the present quality of groundwater, 13 open wells were identified in the river basin around Karur and samples were collected during pre-monsoon, post monsoon and summer, and analyzed for physico-chemical parameters. TDS, total alkalinity, total hardness, calcium, chlorides and sulphates exceeded the desirable limit. Amaravathi River water samples were also colleted at the upstream and downstream of Karur and the result shows the river is polluted. During summer season, there is no flow in the river and the river acts as a drainage for the effluent. Hence, there is severe impact on the groundwater quality in the downstream. The best option to protect the groundwater quality in the river basin is that the textile processing units should adopt zero liquid discharge (ZLD) system and completely recycle the treated effluent.

An analysis of the chemical and microbiological quality of ground water from boreholes and shallow wells in Zimbabwe

NASA Astrophysics Data System (ADS)

Moyo, N. A. G.

Groundwater from boreholes and shallow wells is a major source of drinking water in most rural areas of Zimbabwe. The quality of groundwater has been taken for granted and the status and the potential threats to groundwater quality have not been investigated on a large scale in Zimbabwe. A borehole and shallow well water quality survey was undertaken between January, 2009 and February, 2010 to determine the chemical and microbial aspects of drinking water in three catchment areas. Groundwater quality physico-chemical indicators used in this study were nitrates, chloride, water hardness, conductivity, alkalinity, total dissolved solids, iron, magnesium, manganese, potassium, calcium, fluoride, sulphates, sodium and pH. The microbiological indicators were total coliforms, faecal coliforms and heterotrophs. Principal component analysis (PCA) showed that most of the variation in ground water quality in all catchment areas is accounted for by Total Dissolved Solids (TDS), electrical conductivity (EC), sodium, bicarbonate and magnesium. The principal dissolved constituents in ground water are in the form of electrically charged ions. Nitrate is a significant problem as the World Health Organization recommended levels were exceeded in 36%, 37% and 22% of the boreholes in the Manyame, Mazowe and Gwayi catchment areas respectively. The nitrate levels were particularly high in commercial farming areas. Iron and manganese also exceeded the recommended levels. The probable source of high iron levels is the underlying geology of the area which is dominated by dolerites. Dolerites weather to give soils rich in iron and other mafic minerals. The high level of manganese is probably due to the lithology of the rock as well as mining activity in some areas. Water hardness is a problem in all catchment areas, particularly in the Gwayi catchment area where a value of 2550 mg/l was recorded in one borehole. The problems with hard water use are discussed. Chloride levels exceeded the recommended levels in a few areas under irrigation. Most of the chloride is probably from agricultural activity particularly the application of potassium chloride. Fluoride levels were particularly elevated in the Gwayi catchment area and this is because of the geology of the area. There was no evidence of microbial contamination in all the boreholes sampled as the total coliform, faecal coliforms, heterotrophs count was nil. However, severe microbial contamination was found in the wells especially those in clay areas.

Ground-water quality near a sewage-sludge recycling site and a landfill near Denver, Colorado

USGS Publications Warehouse

Robson, Stanley G.

1977-01-01

The Metropolitan Denver Sewage Disposal District and the City and County of Denver operate a sewage-sludge recycling site and a landfill in an area about 15 miles (24 kilometers) east of Denver. The assessment of the effects of these facilities on the ground-water system included determining the direction of ground-water movement in the area, evaluating the impact of the wastedisposal activities on the chemical quality of local ground water, and evaluating the need for continued water-quality monitoring.Surficial geology of the area consists of two principal units: (1) Alluvium with a maximum thickness of about 25 feet (7.6 meters) deposited along stream channels, and (2) bedrock consisting of undifferentiated Denver and Dawson Formations. Ground water in formations less than 350 feet (110 meters) deep moves to the north, as does surface flow, while ground water in formations between 570 and 1,500 feet (170 and 460 meters) deep moves to the west. Estimates of ground-water velocity were made using assumed values for hydraulic conductivity and porosity, and the observed hydraulic gradient from the study area. Lateral velocities are estimated to be 380 feet (120 meters) per year in alluvium and 27 feet (8.2 meters) per year in the upper part of the bedrock formations. Vertical velocity is estimated to be 0.58 foot (0.18 meter) per year in the upper part of the bedrock formations.Potentiometric head decreases with depth in the bedrock formations indicating a potential for downward movement of ground water. However, waterquality analysis and the rate and direction of ground-water movement suggest that ground-water movement in the area is primarily in the lateral rather than the vertical direction. Five wells perforated in alluvium were found to have markedly degraded water quality. One well was located in the landfill and water that was analyzed was obtained from near the base of the buried refuse, two others were located downgradient and near sewage-sludge burial areas, and the remaining two are located near stagnant surface ponds. Concentrations of nitrate in wells downgradient from fields where sludge is plowed into the soil were higher than background concentrations due to the effects of the sludge disposal. No evidence of water-quality degradation was detected in deeper wells perforated in the bedrock formations. Continued water-quality monitoring is needed because of the continuing disposal of wastes. A suggested monitoring program would consist of monitoring wells near the landfill twice a year and monitoring wells near the sludge-disposal areas on an annual basis.

Groundwater quality and depletion in the Indo-Gangetic Basin mapped from in situ observations

NASA Astrophysics Data System (ADS)

MacDonald, A. M.; Bonsor, H. C.; Ahmed, K. M.; Burgess, W. G.; Basharat, M.; Calow, R. C.; Dixit, A.; Foster, S. S. D.; Gopal, K.; Lapworth, D. J.; Lark, R. M.; Moench, M.; Mukherjee, A.; Rao, M. S.; Shamsudduha, M.; Smith, L.; Taylor, R. G.; Tucker, J.; van Steenbergen, F.; Yadav, S. K.

2016-10-01

Groundwater abstraction from the transboundary Indo-Gangetic Basin comprises 25% of global groundwater withdrawals, sustaining agricultural productivity in Pakistan, India, Nepal and Bangladesh. Recent interpretations of satellite gravity data indicate that current abstraction is unsustainable, yet these large-scale interpretations lack the spatio-temporal resolution required to govern groundwater effectively. Here we report new evidence from high-resolution in situ records of groundwater levels, abstraction and groundwater quality, which reveal that sustainable groundwater supplies are constrained more by extensive contamination than depletion. We estimate the volume of groundwater to 200 m depth to be >20 times the combined annual flow of the Indus, Brahmaputra and Ganges, and show the water table has been stable or rising across 70% of the aquifer between 2000 and 2012. Groundwater levels are falling in the remaining 30%, amounting to a net annual depletion of 8.0 +/- 3.0 km3. Within 60% of the aquifer, access to potable groundwater is restricted by excessive salinity or arsenic. Recent groundwater depletion in northern India and Pakistan has occurred within a longer history of groundwater accumulation from extensive canal leakage. This basin-wide synthesis of in situ groundwater observations provides the spatial detail essential for policy development, and the historical context to help evaluate recent satellite gravity data.

Assessment and modeling of the groundwater hydrogeochemical quality parameters via geostatistical approaches

NASA Astrophysics Data System (ADS)

Karami, Shawgar; Madani, Hassan; Katibeh, Homayoon; Fatehi Marj, Ahmad

2018-03-01

Geostatistical methods are one of the advanced techniques used for interpolation of groundwater quality data. The results obtained from geostatistics will be useful for decision makers to adopt suitable remedial measures to protect the quality of groundwater sources. Data used in this study were collected from 78 wells in Varamin plain aquifer located in southeast of Tehran, Iran, in 2013. Ordinary kriging method was used in this study to evaluate groundwater quality parameters. According to what has been mentioned in this paper, seven main quality parameters (i.e. total dissolved solids (TDS), sodium adsorption ratio (SAR), electrical conductivity (EC), sodium (Na+), total hardness (TH), chloride (Cl-) and sulfate (SO4 2-)), have been analyzed and interpreted by statistical and geostatistical methods. After data normalization by Nscore method in WinGslib software, variography as a geostatistical tool to define spatial regression was compiled and experimental variograms were plotted by GS+ software. Then, the best theoretical model was fitted to each variogram based on the minimum RSS. Cross validation method was used to determine the accuracy of the estimated data. Eventually, estimation maps of groundwater quality were prepared in WinGslib software and estimation variance map and estimation error map were presented to evaluate the quality of estimation in each estimated point. Results showed that kriging method is more accurate than the traditional interpolation methods.

Groundwater science relevant to the Great Lakes Water Quality Agreement: A status report

USGS Publications Warehouse

Grannemann, Norman G.; Van Stempvoort, Dale

2016-01-01

When the Great Lakes Water Quality Agreement (GLWQA) was signed in 1972 by the Governments of Canada and the United States (the “Parties”) (Environment Canada, 2013a), groundwater was not recognized as important to the water quality of the Lakes. At that time, groundwater and surface water were still considered as two separate systems, with almost no appreciation for their interaction. When the GLWQA was revised in 1978 (US Environmental Protection Agency (USEPA), 2012), groundwater contamination, such as that reported at legacy industrial sites such as those at Love Canal near the Niagara River, was squarely in the news. Consequently, the potential impacts of contaminated groundwater from such sites on Great Lakes water quality became a concern (Beck, 1979), and Annex 16 was added to the agreement, to address “pollution from contaminated groundwater” (Francis, 1989). However, no formal process for reporting under this annex was provided. The GLWQA Protocol in 1987 modified Annex 16 and called for progress reports beginning in 1988 (USEPA, 1988). The Protocol in 2012 provided a new Annex 8 to address groundwater more holistically (Environment 2 Canada, 2013b). Annex 8 (Environment Canada, 2013b) commits the Parties to coordinate groundwater science and management actions; as a first step, to “publish a report on the relevant and available groundwater science” by February 2015 (this report); and to “identify priorities for science activities and actions for groundwater management, protection, and remediation…” The broader mandate of Annex 8 is to (1) “identify groundwater impacts on the chemical, physical and biological integrity of the Waters of the Great Lakes;” (2) “analyze contaminants, including nutrients in groundwater, derived from both point and non-point sources impacting the Waters of the Great Lakes;” (3) “assess information gaps and science needs related to groundwater to protect the quality of the Waters of the Great Lakes;” and (4) “analyze other factors, such as climate change, that individually or cumulatively affect groundwater’s impact on the quality of the Waters of the Great Lakes.” A binational Annex 8 Subcommittee was formed to lead efforts to fulfill the mandate of this annex (members listed on p. i of this report). In turn, this subcommittee has recruited a task team to prepare this report (listed as authors of each chapter). This report addresses all of the above four objectives, based on a compilation of the “relevant and available groundwater science.” Specifically, the second objective (to “analyze contaminants”) is addressed by incorporating information obtained in ongoing monitoring and research activities conducted by the Parties, and by various other members of the Great Lakes Executive Committee.

Effect of land use and urbanization on hydrochemistry and contamination of groundwater from Taejon area, Korea

NASA Astrophysics Data System (ADS)

Jeong, Chan Ho

2001-11-01

Taejon Metropolitan City located in the central part of South Korea has grown and urbanized rapidly. The city depends heavily on groundwater as a water resource. Because of ubiquitous pollution sources, the quality and contamination have become important issues for the urban groundwater supply. This study has investigated the chemical characteristics and the contamination of groundwater in relation to land use. An attempt was made to distinguish anthrophogenic inputs from the influence of natural chemical weathering on the chemical composition of groundwater at Taejon. Groundwater samples collected at 170 locations in the Taejon area show very variable chemical composition of groundwater, e.g. electrical conductance ranges from 65 to 1,290 μS/cm. Most groundwater is weakly acidic and the groundwater chemistry is more influenced by land use and urbanization than by aquifer rock type. Most groundwater from green areas and new town residential districts has low electrical conductance, and is of Ca-HCO3 type, whereas the chemical composition of groundwater from the old downtown and industrial district is shifted towards a Ca-Cl (NO3+SO4) type with high electrical conductance. A number of groundwater samples in the urbanized area are contaminated by high nitrate and chlorine, and exhibit high hardness. The EpCO2, that is the CO2 content of a water sample relative to pure water, was computed to obtain more insight into the origin of CO2 and bicarbonate in the groundwater. The CO2 concentration of groundwater in the urbanized area shows a rough positive relationship with the concentration of major inorganic components. The sources of nitrate, chlorine and excess CO2 in the groundwater are likely to be municipal wastes of unlined landfill sites, leaky latrines and sewage lines. Chemical data of commercial mineral water from other Jurassic granite areas were compared to the chemical composition of the groundwater in the Taejon area. Factor analysis of the chemical data shows that the HCO3- and NO3- concentrations have the highest factor loadings on factor 1 and factor 2, respectively. Factors 1 and 2 represent major contributions from natural processes and human activities, respectively. The results of the factor analysis indicate that the levels of Ca2+, Mg2+, Na+, Cl- and SO42- derive from both pollution sources and natural weathering reactions.

From Global to Local and Vice Versa: On the Importance of the 'Globalization' Agenda in Continental Groundwater Research and Policy-Making.

PubMed

Filimonau, Viachaslau; Barth, Johannes A C

2016-09-01

Groundwater is one of the most important environmental resources and its use continuously rises globally for industrial, agricultural, and drinking water supply purposes. Because of its importance, more knowledge about the volume of usable groundwater is necessary to satisfy the global demand. Due to the challenges in quantifying the volume of available global groundwater, studies which aim to assess its magnitude are limited in number. They are further restricted in scope and depth of analysis as, in most cases, they do not explain how the estimates of global groundwater resources have been obtained, what methods have been used to generate the figures and what levels of uncertainty exist. This article reviews the estimates of global groundwater resources. It finds that the level of uncertainty attached to existing numbers often exceeds 100 % and strives to establish the reasons for discrepancy. The outcome of this study outlines the need for a new agenda in water research with a more pronounced focus on groundwater. This new research agenda should aim at enhancing the quality and quantity of data provision on local and regional groundwater stocks and flows. This knowledge enhancement can serve as a basis to improve policy-making on groundwater resources globally. Research-informed policies will facilitate more effective groundwater management practices to ensure a more rapid progress of the global water sector towards the goal of sustainability.

Groundwater pollution by nitrates from livestock wastes.

PubMed Central

Goldberg, V M

1989-01-01

Utilization of wastes from livestock complexes for irrigation involves the danger of groundwater pollution by nitrates. In order to prevent and minimize pollution, it is necessary to apply geological-hydrogeological evidence and concepts to the situation of wastewater irrigation for the purposes of studying natural groundwater protectiveness and predicting changes in groundwater quality as a result of infiltrating wastes. The procedure of protectiveness evaluation and quality prediction is described. With groundwater pollution by nitrate nitrogen, the concentration of ammonium nitrogen noticeably increases. One of the reasons for this change is the process of denitrification due to changes in the hydrogeochemical conditions in a layer. At representative field sites, it is necessary to collect systematic stationary observations of the concentrations of nitrogenous compounds in groundwater and changes in redox conditions and temperature. PMID:2620669

Total coliform and Escherichia coli contamination in rural well water: analysis for passive surveillance.

PubMed

Invik, Jesse; Barkema, Herman W; Massolo, Alessandro; Neumann, Norman F; Checkley, Sylvia

2017-10-01

With increasing stress on our water resources and recent waterborne disease outbreaks, understanding the epidemiology of waterborne pathogens is crucial to build surveillance systems. The purpose of this study was to explore techniques for describing microbial water quality in rural drinking water wells, based on spatiotemporal analysis, time series analysis and relative risk mapping. Tests results for Escherichia coli and coliforms from private and small public well water samples, collected between 2004 and 2012 in Alberta, Canada, were used for the analysis. Overall, 14.6 and 1.5% of the wells were total coliform and E. coli-positive, respectively. Private well samples were more often total coliform or E. coli-positive compared with untreated public well samples. Using relative risk mapping we were able to identify areas of higher risk for bacterial contamination of groundwater in the province not previously identified. Incorporation of time series analysis demonstrated peak contamination occurring for E. coli in July and a later peak for total coliforms in September, suggesting a temporal dissociation between these indicators in terms of groundwater quality, and highlighting the potential need to increase monitoring during certain periods of the year.

Wetlands monitoring - hydrological conditions and water quality in selected transects of Biebrza National Park.

NASA Astrophysics Data System (ADS)

Stelmaszczyk, Mateusz; Okruszko, Tomasz

2010-05-01

Water Framework Directive (WFD) obligates Member States to prevent further deterioration as well as to protect and enhance the status of aquatic ecosystems and wetlands. In order to fulfill one of the WFD objectives - to keep wetlands in good surface water and groundwater status (determined by good ecological, chemical and quantitative status) it is necessary to specify most favourable conditions for them. In that case monitoring of factors responsible for wetlands status in natural areas is a key issue. Further, achieved knowledge of existing relations in ecosystems can be implemented in protection and restoration projects. There are a number of factors influencing diversity of habitats responsible for developing different wetland ecosystems and their sustaining in good ecological status. It's believed that among significant factors such as hydrological conditions, water quality, nutrient availability in the soil, pH value and management (e.g. grazing, mowing) the hydrological conditions are the most important. In presented work authors concentrated on hydrological conditions and water quality and theirs influence on wetland vegetation of Biebrza National Park (BNP). BNP located north-east part of Poland is recognized by many scientist as a unique undisturbed wetland reference area. Five transects located in different basins of BNP were chosen. Transects consist of piezometers in which the water table levels and water quality were measured. Analysis of electroconductivity (EC), alkalinity (HCO3-) and pH were done directly in the field. In the laboratory anions (NO3-, PO43-, Cl-, SO42-) and cations (NH4+, Ca2+, Mg2+, Br+, Li+, Na+, K+) concentration was determined using High Performance Liquid Chromatography (HPLC). D-divers, electronic devices to permanent measurement of groundwater level changes were located in some of the piezometers. Piezometers were located in the sites characterized by different hydrological conditions, from groundwater fed to river fed areas. Studied locations were covered mainly by Magnocaricion vegetation (e.g. Caricetum gracilis and Caricetum elatae), Molinio-Arrhenatheretea vegetation (Molinietum caeruleae), and Scheuchzerio-Caricetea nigrae vegetation (e.g. Caricetum lasiocarpae). In presented work authors show results of water quality measurements and monitoring of hydrological conditions, characterized by changes of groundwater table, period and size of inundation. During six years long monitoring period (2004 - 2009 hydrological years) there were observed high diversification of groundwater and surface water levels among locations. They fluctuate in some places from very low groundwater levels, observed in late summer and in early autumn (over 1 m beneath the ground), to levels reaching surface of the ground or laying nearly below it, occurring in winter and spring. There are also places where quite high inundations in winter and spring are observed. Collected chemical and hydrological data were statistically analyzed using STATISTICA 8 software with a use of one of the multivariate analysis - Principal Component Analysis (PCA) method. Owing to the usage of PCA analysis it was possible to define most important parameters characterizing habitats were occurs selected vegetation. The impact of hydrological conditions (presented as a main factor) on forming particular wetland plant communities can be discussed. Authors determine that some other factors (e.g. management) can be more responsible for occurrence of particular plant communities and their sustaining in good status in specific locations.

Groundwater Nitrate Contamination Risk Assessment in Canicattì area (Sicily)

NASA Astrophysics Data System (ADS)

Pisciotta, Antonino; Cusimano, Gioacchino; Favara, Rocco

2010-05-01

Groundwaters play a dominant role in the Sicily, because as most part of Mediterranean countries this island is interested by the phenomenon of desertification and the quality of the groundwater reservoir is one of the most important aim for the management policy strategies. During last decade most of the Italian regions the nitrate levels in river and groundwaters have increased gradually over mainly as a consequence of large-scale agricultural application of manure and fertilizers, thereby threatening drinking water quality. The excessive use of chemicals and fertilizers increases the risk to pollution of surface and groundwater from diffuse source, an important reflex to human health and the environment. The studied area is located in Canicattì (central Sicily, Italy), the current land use (grape, olive grove and almond) is the main source of groundwater pollution. In order to investigate the effect of the over farming on the groundwater quality we report the study on the potential risk of contamination from nitrate of agricultural origin through the join of the application of two parametric methods: the IPNOA method (the intrinsic nitrate contamination risk from Agricultural sources) applied to define the Nitrate Vulnerable Zones and the SINTACS method applied to determine the aquifer vulnerability to contamination.

Hydrochemical processes regulating groundwater quality in the coastal plain of Al Musanaah, Sultanate of Oman

NASA Astrophysics Data System (ADS)

Askri, Brahim

2015-06-01

The Al Batinah coastal aquifer is the principal source of water in northwestern Oman. The rainfall in the Jabal Al Akhdar mountain region recharges the plain with freshwater that allowed agricultural and industrial activities to develop. The over-exploitation of this aquifer since the 1970s for municipal, agricultural and industrial purposes, excessive use of fertilizers in agriculture and leakage from septic tanks led to the deterioration of groundwater quality. The objective of this study was to investigate the hydrochemical processes regulating the groundwater quality in the southwestern section of Al Batinah. From available data collected during the spring of 2010 from 58 wells located in Al Musanaah wilayat, it was determined that the groundwater salinity increased in the direction from the south to the north following the regional flow direction. In addition to salinisation, the groundwater in the upstream and intermediate regions was contaminated with nitrate, while groundwater in the downstream region was affected by fluoride. Calculations of ionic ratios and seawater fraction indicated that seawater intrusion was not dominant in the study area. The primary factors controlling the groundwater chemistry in Al Musanaah appear to be halite dissolution, reverse ion exchange with clay material and anthropogenic pollutants.

Assessment of major ions and trace elements in groundwater supplied to the Monterrey metropolitan area, Nuevo León, Mexico.

PubMed

Mora, Abrahan; Mahlknecht, Jürgen; Rosales-Lagarde, Laura; Hernández-Antonio, Arturo

2017-08-01

The Monterrey metropolitan area (MMA) is the third greatest urban area and the second largest economic city of Mexico. More than four million people living in this megacity use groundwater for drinking, industrial and household purposes. Thus, major ion and trace element content were assessed in order to investigate the main hydrochemical properties of groundwater and determine if groundwater of the area poses a threat to the MMA population. Hierarchical cluster analysis using all the groundwater chemical data showed five groups of water. The first two groups were classified as recharge waters (Ca-HCO 3 ) coming from the foothills of mountain belts. The third group was also of Ca-HCO 3 water type flowing through lutites and limestones. Transition zone waters of group four (Ca-HCO 3 -SO 4 ) flow through the valley of Monterrey, whereas discharge waters of group 5 (Ca-SO 4 ) were found toward the north and northeast of the MMA. Principal component analysis performed in groundwater data indicates four principal components (PCs). PC1 included major ions Si, Co, Se, and Zn, suggesting that these are derived by rock weathering. Other trace elements such as As, Mo, Mn, and U are coupled in PC2 because they show redox-sensitive properties. PC3 indicates that Pb and Cu could be the less mobile elements in groundwater. Although groundwater supplied to MMA showed a high-quality, high mineralized waters of group 5 have NO 3 - concentrations higher than the maximum value proposed by international guidelines and SO 4 2- , NO 3 - , and total dissolved solid concentrations higher than the maximum levels allowed by the Mexican normative.

Artificial neural networks for defining the water quality determinants of groundwater abstraction in coastal aquifer

NASA Astrophysics Data System (ADS)

Lallahem, S.; Hani, A.

2017-02-01

Water sustainability in the lower Seybouse River basin, eastern Algeria, must take into account the importance of water quantity and quality integration. So, there is a need for a better knowledge and understanding of the water quality determinants of groundwater abstraction to meet the municipal and agricultural uses. In this paper, the artificial neural network (ANN) models were used to model and predict the relationship between groundwater abstraction and water quality determinants in the lower Seybouse River basin. The study area chosen is the lower Seybouse River basin and real data were collected from forty five wells for reference year 2006. Results indicate that the feed-forward multilayer perceptron models with back-propagation are useful tools to define and prioritize the important water quality parameters of groundwater abstraction and use. The model evaluation shows that the correlation coefficients are more than 95% for training, verification and testing data. The model aims to link the water quantity and quality with the objective to strengthen the Integrated Water Resources Management approach. It assists water planners and managers to better assess the water quality parameters and progress towards the provision of appropriate quantities of water of suitable quality.

A longitudinal study of long-term change in contamination hazards and shallow well quality in two neighbourhoods of Kisumu, Kenya.

PubMed

Okotto-Okotto, Joseph; Okotto, Lorna; Price, Heather; Pedley, Steve; Wright, Jim

2015-04-17

Sub-Saharan Africa is experiencing rapid urbanisation and many urban residents use groundwater where piped supplies are intermittent or unavailable. This study aimed to investigate long-term changes in groundwater contamination hazards and hand-dug well water quality in two informal settlements in Kisumu city, Kenya. Buildings, pit latrines, and wells were mapped in 1999 and 2013-2014. Sanitary risk inspection and water quality testing were conducted at 51 hand-dug wells in 2002 to 2004 and 2014. Pit latrine density increased between 1999 and 2014, whilst sanitary risk scores for wells increased between 2002 to 2004 and 2014 (n = 37, Z = -1.98, p = 0.048). Nitrate levels dropped from 2004 to 2014 (n = 14, Z = -3.296, p = 0.001), but multivariate analysis suggested high rainfall in 2004 could account for this. Thermotolerant coliform counts dropped between 2004 and 2014, with this reduction significant in one settlement. Hand-dug wells had thus remained an important source of domestic water between 1999 and 2014, but contamination risks increased over this period. Water quality trends were complex, but nitrate levels were related to both sanitary risks and rainfall. Given widespread groundwater use by the urban poor in sub-Saharan Africa, the study protocol could be further refined to monitor contamination in hand-dug wells in similar settings.

A Longitudinal Study of Long-Term Change in Contamination Hazards and Shallow Well Quality in Two Neighbourhoods of Kisumu, Kenya

PubMed Central

Okotto-Okotto, Joseph; Okotto, Lorna; Price, Heather; Pedley, Steve; Wright, Jim

2015-01-01

Sub-Saharan Africa is experiencing rapid urbanisation and many urban residents use groundwater where piped supplies are intermittent or unavailable. This study aimed to investigate long-term changes in groundwater contamination hazards and hand-dug well water quality in two informal settlements in Kisumu city, Kenya. Buildings, pit latrines, and wells were mapped in 1999 and 2013–2014. Sanitary risk inspection and water quality testing were conducted at 51 hand-dug wells in 2002 to 2004 and 2014. Pit latrine density increased between 1999 and 2014, whilst sanitary risk scores for wells increased between 2002 to 2004 and 2014 (n = 37, Z = −1.98, p = 0.048). Nitrate levels dropped from 2004 to 2014 (n = 14, Z = −3.296, p = 0.001), but multivariate analysis suggested high rainfall in 2004 could account for this. Thermotolerant coliform counts dropped between 2004 and 2014, with this reduction significant in one settlement. Hand-dug wells had thus remained an important source of domestic water between 1999 and 2014, but contamination risks increased over this period. Water quality trends were complex, but nitrate levels were related to both sanitary risks and rainfall. Given widespread groundwater use by the urban poor in sub-Saharan Africa, the study protocol could be further refined to monitor contamination in hand-dug wells in similar settings. PMID:25898406

Quality of groundwater and surface water, Wood River Valley, south-central Idaho, July and August 2012

USGS Publications Warehouse

Hopkins, Candice B.; Bartolino, James R.

2013-01-01

Residents and resource managers of the Wood River Valley of south-central Idaho are concerned about the effects that population growth might have on the quality of groundwater and surface water. As part of a multi-phase assessment of the groundwater resources in the study area, the U.S. Geological Survey evaluated the quality of water at 45 groundwater and 5 surface-water sites throughout the Wood River Valley during July and August 2012. Water samples were analyzed for field parameters (temperature, pH, specific conductance, dissolved oxygen, and alkalinity), major ions, boron, iron, manganese, nutrients, and Escherichia coli (E.coli) and total coliform bacteria. This study was conducted to determine baseline water quality throughout the Wood River Valley, with special emphasis on nutrient concentrations. Water quality in most samples collected did not exceed U.S. Environmental Protection Agency standards for drinking water. E. coli bacteria, used as indicators of water quality, were detected in all five surface-water samples and in two groundwater samples collected. Some analytes have aesthetic-based recommended drinking water standards; one groundwater sample exceeded recommended iron concentrations. Nitrate plus nitrite concentrations varied, but tended to be higher near population centers and in agricultural areas than in tributaries and less populated areas. These higher nitrate plus nitrite concentrations were not correlated with boron concentrations or the presence of bacteria, common indicators of sources of nutrients to water. None of the samples collected exceeded drinking-water standards for nitrate or nitrite. The concentration of total dissolved solids varied considerably in the waters sampled; however a calcium-magnesium-bicarbonate water type was dominant (43 out of 50 samples) in both the groundwater and surface water. Three constituents that may be influenced by anthropogenic activity (chloride, boron, and nitrate plus nitrite) deviate from this pattern and show a wide distribution of concentrations in the unconfined aquifer, indicating possible anthropogenic influence. Time-series plots of historical water-quality data indicated that nitrate does not seem to be increasing or decreasing in groundwater over time; however, time-series plots of chloride concentrations indicate that chloride may be increasing in some wells. The small amount of temporal variability in nitrate concentrations indicates a lack of major temporal changes to groundwater inputs.

Groundwater Age in Multi-Level Water Quality Monitor Wells on California Central Valley Dairies

NASA Astrophysics Data System (ADS)

Esser, B. K.; Visser, A.; Hillegonds, D. J.; Singleton, M. J.; Moran, J. E.; Harter, T.

2011-12-01

Dairy farming in California's Central Valley is a significant source of nitrate to underlying aquifers. One approach to mitigation is to implement farm-scale management plans that reduce nutrient loading to groundwater while sustaining crop yield. While the effect of different management practices on crop yield is easily measured, their effect on groundwater quality has only infrequently been evaluated. Documenting and predicting the impact of management on water quality requires a quantitative assessment of transport (including timescale and mixing) through the vadose and saturated zones. In this study, we measured tritium, helium isotopic composition, and noble gas concentrations in groundwater drawn from monitor wells on several dairies in the Lower San Joaquin Valley and Tulare Lake Basin of California's Central Valley in order to predict the timescales on which changes in management may produce observable changes in groundwater quality. These dairies differ in age (from <10 to >100 years old), thickness of the vadose zone (from <10 to 60 m), hydrogeologic setting, and primary source of irrigation water (surface or groundwater). All of the dairies use manure wastewater for irrigation and fertilization. Three of the dairies have implemented management changes designed to reduce nutrient loading and/or water usage. Monitor wells in the southern Tulare Lake Basin dairies were installed by UC-Davis as multi-level nested wells allowing depth profiling of tritium and noble gases at these sites. Tritium/helium-3 groundwater ages, calculated using a simple piston-flow model, range from <2 to >50 years. Initial tritium (the sum of measured tritium and tritiogenic helium-3) is close to or slightly above precipitation in the calculated recharge year for young samples; and significantly above the precipitation curve for older samples. This pattern is consistent with the use of 20-30 year old groundwater recharged before 1980 for irrigation, and illustrates how irrigation with groundwater can complicate the use of tritium alone for age dating. The presence of radiogenic helium-4 in several samples with measurable tritium provides evidence of mixing between pre-modern and younger groundwater. Groundwater age-depth relationships are complicated, consistent with transient flow patterns in shallow agricultural groundwaters affected by irrigation pumping and recharge. For the multi-level installations in the southern dairies, both depth profiles and re-sampling after significant changes in groundwater elevation emphasize the need to sample groundwater within 3 meters of the water table to obtain "first-encounter" groundwater with a tritium/helium-3 age of less than 5 years, and to use age tracers to identify wells and groundwater conditions suitable for monitoring and assessment of best management practice impacts on underlying groundwater quality. This work was carried out with funding from Sustainable Conservation and the California State Water Resources Control Board in collaboration with UC-Davis, and was performed under the auspices of the U.S. DOE by LLNL under Contract DE-AC52-07NA27344.