Photon momentum transfer plane for asteroid, meteoroid, and comet orbit shaping

NASA Technical Reports Server (NTRS)

Campbell, Jonathan W. (Inventor)

2004-01-01

A spacecraft docks with a spinning and/or rotating asteroid, meteoroid, comet, or other space object, utilizing a tether shaped in a loop and utilizing subvehicles appropriately to control loop instabilities. The loop is positioned about a portion of the asteroid and retracted thereby docking the spacecraft to the asteroid, meteoroid, comet, or other space object. A deployable rigidized, photon momentum transfer plane of sufficient thickness may then be inflated and filled with foam. This plane has a reflective surface that assists in generating a larger momentum from impinging photons. This plane may also be moved relative to the spacecraft to alter the forces acting on it, and thus on the asteroid, meteoroid, comet, or other space object to which it is attached. In general, these forces may be utilized, over time, to alter the orbits of asteroids, meteoroids, comets, or other space objects. Sensors and communication equipment may be utilized to allow remote operation of the rigidized, photon momentum transfer plane and tether.

NASA's Orbital Space Plane Risk Reduction Strategy

NASA Technical Reports Server (NTRS)

Dumbacher, Dan

2003-01-01

This paper documents the transformation of NASA s Space Launch Initiative (SLI) Second Generation Reusable Launch Vehicle Program under the revised Integrated Space Transportation Plan, announced November 2002. Outlining the technology development approach followed by the original SLI, this paper gives insight into the current risk-reduction strategy that will enable confident development of the Nation s first orbital space plane (OSP). The OSP will perform an astronaut and contingency cargo transportation function, with an early crew rescue capability, thus enabling increased crew size and enhanced science operations aboard the International Space Station. The OSP design chosen for full-scale development will take advantage of the latest innovations American industry has to offer. The OSP Program identifies critical technologies that must be advanced to field a safe, reliable, affordable space transportation system for U.S. access to the Station and low-Earth orbit. OSP flight demonstrators will test crew safety features, validate autonomous operations, and mature thermal protection systems. Additional enabling technologies may be identified during the OSP design process as part of an overall risk-management strategy. The OSP Program uses a comprehensive and evolutionary systems acquisition approach, while applying appropriate lessons learned.

THE CANADA-FRANCE ECLIPTIC PLANE SURVEY-L3 DATA RELEASE: THE ORBITAL STRUCTURE OF THE KUIPER BELT

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kavelaars, J. J.; Jones, R. L.; Murray, I.

2009-06-15

We report the orbital distribution of the trans-Neptunian comets discovered during the first discovery year of the Canada-France Ecliptic Plane Survey (CFEPS). CFEPS is a Kuiper Belt object survey based on observations acquired by the Very Wide component of the Canada-France-Hawaii Telescope Legacy Survey (LS-VW). The first year's detections consist of 73 Kuiper Belt objects, 55 of which have now been tracked for three years or more, providing precise orbits. Although this sample size is small compared to the world-wide inventory, because we have an absolutely calibrated and extremely well-characterized survey (with known pointing history) we are able to de-biasmore » our observed population and make unbiased statements about the intrinsic orbital distribution of the Kuiper Belt. By applying the (publically available) CFEPS Survey Simulator to models of the true orbital distribution and comparing the resulting simulated detections to the actual detections made by the survey, we are able to rule out several hypothesized Kuiper Belt object orbit distributions. We find that the main classical belt's so-called 'cold' component is confined in semimajor axis (a) and eccentricity (e) compared to the more extended 'hot' component; the cold component is confined to lower e and does not stretch all the way out to the 2:1 resonance but rather depletes quickly beyond a = 45 AU. For the cold main classical belt population we find a robust population estimate of N(H{sub g} < 10) = 50 {+-} 5 x 10{sup 3} and find that the hot component of the main classical belt represents {approx}60% of the total population. The inner classical belt (sunward of the 3:2 mean-motion resonance) has a population of roughly 2000 trans-Neptunian objects with absolute magnitudes H{sub g} < 10, and may not share the inclination distribution of the main classical belt. We also find that the plutino population lacks a cold low-inclination component, and so, the population is somewhat larger than recent

Hubble Space Telescope On-orbit NiH2 Battery Performance

NASA Technical Reports Server (NTRS)

Rao, Gopalakrishna M.; Krol, Stanley J., Jr.

2002-01-01

This paper summarizes the Hubble Space Telescope (HST) nickel-hydrogen (NiH2) battery performance from launch to the present time. Over the life of HST vehicle configuration, charge system degradation and failures together with thermal design limitations have had a significant effect on the capacity of the HST batteries. Changes made to the charge system configuration in order to protect against power system failures and to maintain battery thermal stability resulted in undercharging of the batteries. This undercharging resulted in decreased usable battery capacity as well as battery cell voltage/capacity divergence. This cell divergence was made evident during on-orbit battery capacity measurements by a relatively shallow slope of the discharge curve following the discharge knee. Early efforts to improve the battery performance have been successful. On-orbit capacity measurement data indicates increases in the usable battery capacity of all six batteries as well as improvements in the battery cell voltage/capacity divergence. Additional measures have been implemented to improve battery performance, however, failures within the HST Power Control Unit (PCU) have prevented verification of battery status. As this PCU fault prevents the execution of on-orbit capacity testing, the HST Project has based the battery capacity on trends, which utilizes previous on-orbit battery capacity test data, for science mission and servicing mission planning. The Servicing Mission 38 (SM-3B) in March 2002 replaced the faulty PCU. Following the servicing mission, on-orbit capacity test resumed. A summary of battery performance is reviewed since launch in this paper.

In-plane Schottky-barrier field-effect transistors based on 1T/2H heterojunctions of transition-metal dichalcogenides

NASA Astrophysics Data System (ADS)

Fan, Zhi-Qiang; Jiang, Xiang-Wei; Luo, Jun-Wei; Jiao, Li-Ying; Huang, Ru; Li, Shu-Shen; Wang, Lin-Wang

2017-10-01

As Moore's law approaches its end, two-dimensional (2D) materials are intensely studied for their potentials as one of the "More than Moore' (MM) devices. However, the ultimate performance limits and the optimal design parameters for such devices are still unknown. One common problem for the 2D-material-based device is the relative weak on-current. In this study, two-dimensional Schottky-barrier field-effect transistors (SBFETs) consisting of in-plane heterojunctions of 1T metallic-phase and 2H semiconducting-phase transition-metal dichalcogenides (TMDs) are studied following the recent experimental synthesis of such devices at a much larger scale. Our ab initio simulation reveals the ultimate performance limits of such devices and offers suggestions for better TMD materials. Our study shows that the Schottky-barrier heights (SBHs) of the in-plane 1T/2H contacts are smaller than the SBHs of out-of-plane contacts, and the contact coupling is also stronger in the in-plane contact. Due to the atomic thickness of the monolayer TMD, the average subthreshold swing of the in-plane TMD-SBFETs is found to be close to the limit of 60 mV/dec, and smaller than that of the out-of-plane TMD-SBFET device. Different TMDs are considered and it is found that the in-plane WT e2-SBFET provides the best performance and can satisfy the performance requirement of the sub-10-nm high-performance transistor outlined by the International Technology Roadmap for Semiconductors, and thus could be developed into a viable sub-10-nm MM device in the future.

Orbital selectivity causing anisotropy and particle-hole asymmetry in the charge density wave gap of 2 H - TaS 2

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhao, J.; Wijayaratne, K.; Butler, A.

We report an in-depth angle-resolved photoemission spectroscopy study on 2H-TaS2, a canonical incommensurate charge density wave (CDW) system. This study demonstrates that just as in related incommensurate CDW systems, 2H-TaSe2 and 2H-NbSe2, the energy gap (triangle(CDW)) of 2H-TaS2 is localized along the K-centered Fermi surface barrels and is particle-hole asymmetric. The persistence of triangle(CDW) even at temperatures higher than the CDW transition temperature T-CDW in 2H-TaS2, reflects the similar pseudogap behavior observed previously in 2H-TaSe2 and 2H-NbSe2. However, in sharp contrast to 2H-NbSe2, where triangle(CDW) is nonzero only in the vicinity of a few "hot spots" on the innerK-centered Fermimore » surface barrels, triangle(CDW) in 2H-TaS2 is nonzero along the entirety of both K-centered Fermi surface barrels. Based on a tight-binding model, we attribute this dichotomy in the momentum dependence and the Fermi surface specificity of triangle(CDW) between otherwise similar CDW compounds to the different orbital orientations of their electronic states that participate in the CDW pairing. Our results suggest that the orbital selectivity plays a critical role in the description of incommensurate CDW materials.« less

Orbital selectivity causing anisotropy and particle-hole asymmetry in the charge density wave gap of 2 H -TaS2

NASA Astrophysics Data System (ADS)

Zhao, J.; Wijayaratne, K.; Butler, A.; Yang, J.; Malliakas, C. D.; Chung, D. Y.; Louca, D.; Kanatzidis, M. G.; van Wezel, J.; Chatterjee, U.

2017-09-01

We report an in-depth angle-resolved photoemission spectroscopy study on 2 H -TaS2 , a canonical incommensurate charge density wave (CDW) system. This study demonstrates that just as in related incommensurate CDW systems, 2 H -TaSe2 and 2 H -NbSe2 , the energy gap (ΔCDW) of 2 H -TaS2 is localized along the K -centered Fermi surface barrels and is particle-hole asymmetric. The persistence of ΔCDW even at temperatures higher than the CDW transition temperature TCDW in 2 H -TaS2 , reflects the similar pseudogap behavior observed previously in 2 H -TaSe2 and 2 H -NbSe2 . However, in sharp contrast to 2 H -NbSe2 , where ΔCDW is nonzero only in the vicinity of a few "hot spots" on the inner K -centered Fermi surface barrels, ΔCDW in 2 H -TaS2 is nonzero along the entirety of both K -centered Fermi surface barrels. Based on a tight-binding model, we attribute this dichotomy in the momentum dependence and the Fermi surface specificity of ΔCDW between otherwise similar CDW compounds to the different orbital orientations of their electronic states that participate in the CDW pairing. Our results suggest that the orbital selectivity plays a critical role in the description of incommensurate CDW materials.

I + (H2O)2 → HI + (H2O)OH Forward and Reverse Reactions. CCSD(T) Studies Including Spin-Orbit Coupling.

PubMed

Wang, Hui; Li, Guoliang; Li, Qian-Shu; Xie, Yaoming; Schaefer, Henry F

2016-03-03

The potential energy profile for the atomic iodine plus water dimer reaction I + (H2O)2 → HI + (H2O)OH has been explored using the "Gold Standard" CCSD(T) method with quadruple-ζ correlation-consistent basis sets. The corresponding information for the reverse reaction HI + (H2O)OH → I + (H2O)2 is also derived. Both zero-point vibrational energies (ZPVEs) and spin-orbit (SO) coupling are considered, and these notably alter the classical energetics. On the basis of the CCSD(T)/cc-pVQZ-PP results, including ZPVE and SO coupling, the forward reaction is found to be endothermic by 47.4 kcal/mol, implying a significant exothermicity for the reverse reaction. The entrance complex I···(H2O)2 is bound by 1.8 kcal/mol, and this dissociation energy is significantly affected by SO coupling. The reaction barrier lies 45.1 kcal/mol higher than the reactants. The exit complex HI···(H2O)OH is bound by 3.0 kcal/mol relative to the asymptotic limit. At every level of theory, the reverse reaction HI + (H2O)OH → I + (H2O)2 proceeds without a barrier. Compared with the analogous water monomer reaction I + H2O → HI + OH, the additional water molecule reduces the relative energies of the entrance stationary point, transition state, and exit complex by 3-5 kcal/mol. The I + (H2O)2 reaction is related to the valence isoelectronic bromine and chlorine reactions but is distinctly different from the F + (H2O)2 system.

Innovative compact focal plane array for wide field vis and ir orbiting telescopes

NASA Astrophysics Data System (ADS)

Hugot, Emmanuel; Vives, Sébastien; Ferrari, Marc; Gaeremynck, Yann; Jahn, Wilfried

2017-11-01

The future generation of high angular resolution space telescopes will require breakthrough technologies to combine large diameters and large focal plane arrays with compactness and lightweight mirrors and structures. Considering the allocated volume medium-size launchers, short focal lengths are mandatory, implying complex optical relays to obtain diffraction limited images on large focal planes. In this paper we present preliminary studies to obtain compact focal plane arrays (FPA) for earth observations on low earth orbits at high angular resolution. Based on the principle of image slicers, we present an optical concept to arrange a 1D FPA into a 2D FPA, allowing the use of 2D detector matrices. This solution is particularly attractive for IR imaging requiring a cryostat, which volume could be considerably reduced as well as the relay optics complexity. Enabling the use of 2D matrices for such an application offers new possibilities. Recent developments on curved FPA allows optimization without concerns on the field curvature. This innovative approach also reduces the complexity of the telescope optical combination, specifically for fast telescopes. This paper will describe the concept and optical design of an F/5 - 1.5m telescope equipped with such a FPA, the performances and the impact on the system with a comparison with an equivalent 1.5m wide field Korsch telescope.

Control of spin-orbit torques through crystal symmetry in WTe2/ferromagnet bilayers

NASA Astrophysics Data System (ADS)

MacNeill, D.; Stiehl, G. M.; Guimaraes, M. H. D.; Buhrman, R. A.; Park, J.; Ralph, D. C.

2017-03-01

Recent discoveries regarding current-induced spin-orbit torques produced by heavy-metal/ferromagnet and topological-insulator/ferromagnet bilayers provide the potential for dramatically improved efficiency in the manipulation of magnetic devices. However, in experiments performed to date, spin-orbit torques have an important limitation--the component of torque that can compensate magnetic damping is required by symmetry to lie within the device plane. This means that spin-orbit torques can drive the most current-efficient type of magnetic reversal (antidamping switching) only for magnetic devices with in-plane anisotropy, not the devices with perpendicular magnetic anisotropy that are needed for high-density applications. Here we show experimentally that this state of affairs is not fundamental, but rather one can change the allowed symmetries of spin-orbit torques in spin-source/ferromagnet bilayer devices by using a spin-source material with low crystalline symmetry. We use WTe2, a transition-metal dichalcogenide whose surface crystal structure has only one mirror plane and no two-fold rotational invariance. Consistent with these symmetries, we generate an out-of-plane antidamping torque when current is applied along a low-symmetry axis of WTe2/Permalloy bilayers, but not when current is applied along a high-symmetry axis. Controlling spin-orbit torques by crystal symmetries in multilayer samples provides a new strategy for optimizing future magnetic technologies.

THE CANADA-FRANCE ECLIPTIC PLANE SURVEY-FULL DATA RELEASE: THE ORBITAL STRUCTURE OF THE KUIPER BELT

DOE Office of Scientific and Technical Information (OSTI.GOV)

Petit, J.-M.; Rousselot, P.; Mousis, O.

2011-10-15

We report the orbital distribution of the trans-Neptunian objects (TNOs) discovered during the Canada-France Ecliptic Plane Survey (CFEPS), whose discovery phase ran from early 2003 until early 2007. The follow-up observations started just after the first discoveries and extended until late 2009. We obtained characterized observations of 321 deg{sup 2} of sky to depths in the range g {approx} 23.5-24.4 AB mag. We provide a database of 169 TNOs with high-precision dynamical classification and known discovery efficiency. Using this database, we find that the classical belt is a complex region with sub-structures that go beyond the usual splitting of innermore » (interior to 3:2 mean-motion resonance [MMR]), main (between 3:2 and 2:1 MMR), and outer (exterior to 2:1 MMR). The main classical belt (a = 40-47 AU) needs to be modeled with at least three components: the 'hot' component with a wide inclination distribution and two 'cold' components (stirred and kernel) with much narrower inclination distributions. The hot component must have a significantly shallower absolute magnitude (H{sub g} ) distribution than the other two components. With 95% confidence, there are 8000{sup +1800}{sub -1600} objects in the main belt with H{sub g} {<=} 8.0, of which 50% are from the hot component, 40% from the stirred component, and 10% from the kernel; the hot component's fraction drops rapidly with increasing H{sub g} . Because of this, the apparent population fractions depend on the depth and ecliptic latitude of a trans-Neptunian survey. The stirred and kernel components are limited to only a portion of the main belt, while we find that the hot component is consistent with a smooth extension throughout the inner, main, and outer regions of the classical belt; in fact, the inner and outer belts are consistent with containing only hot-component objects. The H{sub g} {<=} 8.0 TNO population estimates are 400 for the inner belt and 10,000 for the outer belt to within a factor of two

Analysis of orbital perturbations acting on objects in orbits near geosynchronous earth orbit

NASA Technical Reports Server (NTRS)

Friesen, Larry J.; Jackson, Albert A., IV; Zook, Herbert A.; Kessler, Donald J.

1992-01-01

The paper presents a numerical investigation of orbital evolution for objects started in GEO or in orbits near GEO in order to study potential orbital debris problems in this region. Perturbations simulated include nonspherical terms in the earth's geopotential field, lunar and solar gravity, and solar radiation pressure. Objects simulated include large satellites, for which solar radiation pressure is insignificant, and small particles, for which solar radiation pressure is an important force. Results for large satellites are largely in agreement with previous GEO studies that used classical perturbation techniques. The orbit plane of GEO satellites placed in a stable plane orbit inclined approximately 7.3 deg to the equator experience very little precession, remaining always within 1.2 percent of their initial orientation. Solar radiation pressure generates two major effects on small particles: an orbital eccentricity oscillation anticipated from previous research, and an oscillation in orbital inclination.

In-plane magnetic anisotropy in strontium iridate S r2Ir O4

NASA Astrophysics Data System (ADS)

Nauman, Muhammad; Hong, Yunjeong; Hussain, Tayyaba; Seo, M. S.; Park, S. Y.; Lee, N.; Choi, Y. J.; Kang, Woun; Jo, Younjung

2017-10-01

Magnetic anisotropy in strontium iridate (S r2Ir O4 ) is found to be large because of the strong spin-orbit interactions. In our work, we studied the in-plane magnetic anisotropy of S r2Ir O4 and traced the anisotropic exchange interactions between the isospins in the crystal. The magnetic-field-dependent torque τ(H ) showed a prominent transition from the canted antiferromagnetic state to the weak ferromagnetic (WFM) state. A comprehensive analysis was conducted to examine the isotropic and anisotropic regimes and probe the easy magnetization axis along the a b plane. The angle-dependent torque τ(θ) revealed a deviation from the sinusoidal behavior, and small differences in hysteresis were observed around 0° and 90° in the low-magnetic-field regime. This indicates that the orientation of the easy axis of the FM component is along the b axis, where the antiferromagnetic to WFM spin-flop transition occurs. We compared the coefficients of the magnetic susceptibility tensors and captured the anisotropy of the material. The in-plane τ(θ) revealed a tendency toward isotropic behavior for fields with values above the field value of the WFM transition.

Resonant obliquity of Mars?. [climate driven by spin axis and orbit plane precession caused oscillations

NASA Technical Reports Server (NTRS)

Ward, William R.; Rudy, Donald J.

1991-01-01

The large-scale oscillations generated by the obliquity of Mars through spin-axis and orbit-plane precessions constitute basic climate system drivers with periodicities of 100,000 yrs in differential spin axis-orbit precession rates and of over 1 million yrs in amplitude modulations due to orbital-inclination changes. Attention is presently given to a third time-scale for climate change, which involves a possible spin-spin resonance and whose mechanism operates on a 10-million-yr time-scale: this effect implies an average obliquity increase for Mars of 15 deg only 5 million yrs ago, with important climatic consequences.

H4: A challenging system for natural orbital functional approximations

NASA Astrophysics Data System (ADS)

Ramos-Cordoba, Eloy; Lopez, Xabier; Piris, Mario; Matito, Eduard

2015-10-01

The correct description of nondynamic correlation by electronic structure methods not belonging to the multireference family is a challenging issue. The transition of D2h to D4h symmetry in H4 molecule is among the most simple archetypal examples to illustrate the consequences of missing nondynamic correlation effects. The resurgence of interest in density matrix functional methods has brought several new methods including the family of Piris Natural Orbital Functionals (PNOF). In this work, we compare PNOF5 and PNOF6, which include nondynamic electron correlation effects to some extent, with other standard ab initio methods in the H4 D4h/D2h potential energy surface (PES). Thus far, the wrongful behavior of single-reference methods at the D2h-D4h transition of H4 has been attributed to wrong account of nondynamic correlation effects, whereas in geminal-based approaches, it has been assigned to a wrong coupling of spins and the localized nature of the orbitals. We will show that actually interpair nondynamic correlation is the key to a cusp-free qualitatively correct description of H4 PES. By introducing interpair nondynamic correlation, PNOF6 is shown to avoid cusps and provide the correct smooth PES features at distances close to the equilibrium, total and local spin properties along with the correct electron delocalization, as reflected by natural orbitals and multicenter delocalization indices.

K2-137 b: an Earth-sized planet in a 4.3-h orbit around an M-dwarf

NASA Astrophysics Data System (ADS)

Smith, A. M. S.; Cabrera, J.; Csizmadia, Sz; Dai, F.; Gandolfi, D.; Hirano, T.; Winn, J. N.; Albrecht, S.; Alonso, R.; Antoniciello, G.; Barragán, O.; Deeg, H.; Eigmüller, Ph; Endl, M.; Erikson, A.; Fridlund, M.; Fukui, A.; Grziwa, S.; Guenther, E. W.; Hatzes, A. P.; Hidalgo, D.; Howard, A. W.; Isaacson, H.; Korth, J.; Kuzuhara, M.; Livingston, J.; Narita, N.; Nespral, D.; Nowak, G.; Palle, E.; Pätzold, M.; Persson, C. M.; Petigura, E.; Prieto-Arranz, J.; Rauer, H.; Ribas, I.; Van Eylen, V.

2018-03-01

We report the discovery in K2's Campaign 10 of a transiting terrestrial planet in an ultra-short-period orbit around an M3-dwarf. K2-137 b completes an orbit in only 4.3 h, the second shortest orbital period of any known planet, just 4 min longer than that of KOI 1843.03, which also orbits an M-dwarf. Using a combination of archival images, adaptive optics imaging, radial velocity measurements, and light-curve modelling, we show that no plausible eclipsing binary scenario can explain the K2 light curve, and thus confirm the planetary nature of the system. The planet, whose radius we determine to be 0.89 ± 0.09 R⊕, and which must have an iron mass fraction greater than 0.45, orbits a star of mass 0.463 ± 0.052 M⊙ and radius 0.442 ± 0.044 R⊙.

Significant Enhancement of H2 Formation in Disk Galaxies under Strong Ram Pressure

NASA Astrophysics Data System (ADS)

Henderson, Benjamin; Bekki, Kenji

2016-05-01

We show for the first time that H2 formation on dust grains can be enhanced in disk galaxies under strong ram pressure (RP). We numerically investigate how the time evolution of H I and H2 components in disk galaxies orbiting a group/cluster of galaxies can be influenced by the hydrodynamical interaction between the gaseous components of the galaxies and the hot intracluster medium. We find that compression of H I caused by RP increases H2 formation in disk galaxies before RP rapidly strips H I, cutting off the fuel supply and causing a drop in H2 density. We also find that the level of this H2 formation enhancement in a disk galaxy under RP depends on the mass of its host cluster dark matter halo, the initial positions and velocities of the disk galaxy, and the disk inclination angle with respect to the orbital plane. We demonstrate that dust growth is a key factor in the evolution of the H I and H2 mass in disk galaxies under strong RP. We discuss how the correlation between H2 fractions and surface gas densities of disk galaxies evolves with time in the galaxies under RP. We also discuss whether galaxy-wide star formation rates (SFRs) in cluster disk galaxies can be enhanced by RP if the SFRs depend on H2 densities.

Spin-orbit quenching of the C+(2P) ion by collisions with para- and ortho-H2.

PubMed

Lique, François; Werfelli, Ghofran; Halvick, Philippe; Stoecklin, Thierry; Faure, Alexandre; Wiesenfeld, Laurent; Dagdigian, Paul J

2013-05-28

Spin-orbit (de-)excitation of C(+)((2)P) by collisions with H2, a key process for astrochemistry, is investigated. Quantum-mechanical calculations of collisions between C(+) ions and para- and ortho-H2 have been performed in order to determine the cross section for the C(+) (2)P3∕2 → (2)P1∕2 fine-structure transition at low and intermediate energies. The calculation are based on new ab initio potential energy surfaces obtained using the multireference configuration interaction method. Corresponding rate coefficients were obtained for temperatures ranging from 5 to 500 K. These rate coefficients are compared to previous estimations, and their impact is assessed through radiative transfer computation. They are found to increase the flux of the (2)P3∕2 → (2)P1∕2 line at 158 μm by up to 30% for typical diffuse interstellar cloud conditions.

Tidal Friction in the Earth-Moon System and Laplace Planes: Darwin Redux

NASA Technical Reports Server (NTRS)

Rubincam, David P.

2015-01-01

The dynamical evolution of the Earth-Moon system due to tidal friction is treated here. George H. Darwin used Laplace planes (also called proper planes) in his study of tidal evolution. The Laplace plane approach is adapted here to the formalisms of W.M. Kaula and P. Goldreich. Like Darwin, the approach assumes a three-body problem: Earth, Moon, and Sun, where the Moon and Sun are point-masses. The tidal potential is written in terms of the Laplace plane angles. The resulting secular equations of motion can be easily integrated numerically assuming the Moon is in a circular orbit about the Earth and the Earth is in a circular orbit about the Sun. For Earth-Moon distances greater than 10 Earth radii, the Earth's approximate tidal response can be characterized with a single parameter, which is a ratio: a Love number times the sine of a lag angle divided by another such product. For low parameter values it can be shown that Darwin's low-viscosity molten Earth, M. Ross's and G. Schubert's model of an Earth near melting, and Goldreich's equal tidal lag angles must all give similar histories. For higher parameter values, as perhaps has been the case at times with the ocean tides, the Earth's obliquity may have decreased slightly instead of increased once the Moon's orbit evolved further than 50 Earth radii from the Earth, with possible implications for climate. This is contrast to the other tidal friction models mentioned, which have the obliquity always increasing with time. As for the Moon, its orbit is presently tilted to its Laplace plane by 5.2deg. The equations do not allow the Moon to evolve out of its Laplace plane by tidal friction alone, so that if it was originally in its Laplace plane, the tilt arose with the addition of other mechanisms, such as resonance passages.

Characterizing the spin orbit torque field-like term in in-plane magnetic system using transverse field

DOE Office of Scientific and Technical Information (OSTI.GOV)

Luo, Feilong; Data Storage Institute, A*STAR Agency for Science, Technology and Research, DSI Building, 5 Engineering Drive 1, Singapore 117608; Goolaup, Sarjoosing

2016-08-28

In this work, we present an efficient method for characterizing the spin orbit torque field-like term in an in-plane magnetized system using the harmonic measurement technique. This method does not require a priori knowledge of the planar and anomalous hall resistances and is insensitive to non-uniformity in magnetization, as opposed to the conventional harmonic technique. We theoretically and experimentally demonstrate that the field-like term in the Ta/Co/Pt film stack with in-plane magnetic anisotropy can be obtained by an in-plane transverse field sweep as expected, and magnetization non-uniformity is prevented by the application of fixed magnetic field. The experimental results aremore » in agreement with the analytical calculations.« less

Derivation of force field parameters for SnO2-H2O surface systems from plane-wave density functional theory calculations.

PubMed

Bandura, A V; Sofo, J O; Kubicki, J D

2006-04-27

Plane-wave density functional theory (DFT-PW) calculations were performed on bulk SnO2 (cassiterite) and the (100), (110), (001), and (101) surfaces with and without H2O present. A classical interatomic force field has been developed to describe bulk SnO2 and SnO2-H2O surface interactions. Periodic density functional theory calculations using the program VASP (Kresse et al., 1996) and molecular cluster calculations using Gaussian 03 (Frisch et al., 2003) were used to derive the parametrization of the force field. The program GULP (Gale, 1997) was used to optimize parameters to reproduce experimental and ab initio results. The experimental crystal structure and elastic constants of SnO2 are reproduced reasonably well with the force field. Furthermore, surface atom relaxations and structures of adsorbed H2O molecules agree well between the ab initio and force field predictions. H2O addition above that required to form a monolayer results in consistent structures between the DFT-PW and classical force field results as well.

Wobbly Planet Orbital Schematic Illustration

NASA Image and Video Library

2014-02-04

This illustration shows the unusual orbit of planet Kepler-413b around a close pair of orange and red dwarf stars. The planet 66-day orbit is tilted 2.5 degrees with respect to the plane of the binary stars orbit.

Temperature Dependence of Raman-Active In-Plane E2g Phonons in Layered Graphene and h-BN Flakes

NASA Astrophysics Data System (ADS)

Li, Xiaoli; Liu, Jian; Ding, Kai; Zhao, Xiaohui; Li, Shuai; Zhou, Wenguang; Liang, Baolai

2018-01-01

Thermal properties of sp2 systems such as graphene and hexagonal boron nitride (h-BN) have attracted significant attention because of both systems being excellent thermal conductors. This research reports micro-Raman measurements on the in-plane E2g optical phonon peaks ( 1580 cm-1 in graphene layers and 1362 cm-1 in h-BN layers) as a function of temperature from - 194 to 200 °C. The h-BN flakes show higher sensitivity to temperature-dependent frequency shifts and broadenings than graphene flakes. Moreover, the thermal effect in the c direction on phonon frequency in h-BN layers is more sensitive than that in graphene layers but on phonon broadening in h-BN layers is similar as that in graphene layers. These results are very useful to understand the thermal properties and related physical mechanisms in h-BN and graphene flakes for applications of thermal devices.

Computation provides chemical insight into the diverse hydride NMR chemical shifts of [Ru(NHC)4(L)H]0/+ species (NHC = N-heterocyclic carbene; L = vacant, H2, N2, CO, MeCN, O2, P4, SO2, H-, F- and Cl-) and their [Ru(R2PCH2CH2PR2)2(L)H]+ congeners.

PubMed

Häller, L Jonas L; Mas-Marzá, Elena; Cybulski, Mateusz K; Sanguramath, Rajashekharayya A; Macgregor, Stuart A; Mahon, Mary F; Raynaud, Christophe; Russell, Christopher A; Whittlesey, Michael K

2017-02-28

Relativistic density functional theory calculations, both with and without the effects of spin-orbit coupling, have been employed to model hydride NMR chemical shifts for a series of [Ru(NHC) 4 (L)H] 0/+ species (NHC = N-heterocyclic carbene; L = vacant, H 2 , N 2 , CO, MeCN, O 2 , P 4 , SO 2 , H - , F - and Cl - ), as well as selected phosphine analogues [Ru(R 2 PCH 2 CH 2 PR 2 ) 2 (L)H] + (R = i Pr, Cy; L = vacant, O 2 ). Inclusion of spin-orbit coupling provides good agreement with the experimental data. For the NHC systems large variations in hydride chemical shift are shown to arise from the paramagnetic term, with high net shielding (L = vacant, Cl - , F - ) being reinforced by the contribution from spin-orbit coupling. Natural chemical shift analysis highlights the major orbital contributions to the paramagnetic term and rationalizes trends via changes in the energies of the occupied Ru d π orbitals and the unoccupied σ* Ru-H orbital. In [Ru(NHC) 4 (η 2 -O 2 )H] + a δ-interaction with the O 2 ligand results in a low-lying LUMO of d π character. As a result this orbital can no longer contribute to the paramagnetic shielding, but instead provides additional deshielding via overlap with the remaining (occupied) d π orbital under the L z angular momentum operator. These two effects account for the unusual hydride chemical shift of +4.8 ppm observed experimentally for this species. Calculations reproduce hydride chemical shift data observed for [Ru( i Pr 2 PCH 2 CH 2 P i Pr 2 ) 2 (η 2 -O 2 )H] + (δ = -6.2 ppm) and [Ru(R 2 PCH 2 CH 2 PR 2 ) 2 H] + (ca. -32 ppm, R = i Pr, Cy). For the latter, the presence of a weak agostic interaction trans to the hydride ligand is significant, as in its absence (R = Me) calculations predict a chemical shift of -41 ppm, similar to the [Ru(NHC) 4 H] + analogues. Depending on the strength of the agostic interaction a variation of up to 18 ppm in hydride chemical shift is possible and this factor (that is not necessarily

Investigation of Martian H2O and CO2 via orbital gamma ray spectroscopy

NASA Technical Reports Server (NTRS)

Evans, Larry G.; Squyres, Steven W.

1987-01-01

The capability of an orbital gamma ray spectrometer to address presently unanswered questions concerning H2O and CO2 on Mars is investigated. The gamma ray signal produced by the Martian atmosphere and by several simple models of Martian surface materials is calculated. Results are reported for: (1) the production of neutrons in the atmosphere and in the subsurface material by cosmic ray interactions, (2) the scattering of neutrons and the resultant neutron energy spectrum and spatial distributions, (3) the reproduction of gamma rays by neutron prompt capture and nonelastic scatter reactions, (4) the production of gamma rays by natural radionuclides, (5) the attenuation of the gamma ray signal by passage through surface materials and the Martian atmosphere, (6) the production of the gamma ray continuum background, and (7) the uncertainty in gamma ray line strengths that results from the combined signal and background observed by the detector.

SIGNIFICANT ENHANCEMENT OF H{sub 2} FORMATION IN DISK GALAXIES UNDER STRONG RAM PRESSURE

DOE Office of Scientific and Technical Information (OSTI.GOV)

Henderson, Benjamin; Bekki, Kenji

We show for the first time that H{sub 2} formation on dust grains can be enhanced in disk galaxies under strong ram pressure (RP). We numerically investigate how the time evolution of H i and H{sub 2} components in disk galaxies orbiting a group/cluster of galaxies can be influenced by the hydrodynamical interaction between the gaseous components of the galaxies and the hot intracluster medium. We find that compression of H i caused by RP increases H{sub 2} formation in disk galaxies before RP rapidly strips H i, cutting off the fuel supply and causing a drop in H{sub 2}more » density. We also find that the level of this H{sub 2} formation enhancement in a disk galaxy under RP depends on the mass of its host cluster dark matter halo, the initial positions and velocities of the disk galaxy, and the disk inclination angle with respect to the orbital plane. We demonstrate that dust growth is a key factor in the evolution of the H i and H{sub 2} mass in disk galaxies under strong RP. We discuss how the correlation between H{sub 2} fractions and surface gas densities of disk galaxies evolves with time in the galaxies under RP. We also discuss whether galaxy-wide star formation rates (SFRs) in cluster disk galaxies can be enhanced by RP if the SFRs depend on H{sub 2} densities.« less

Low Earth orbit communications satellite

NASA Technical Reports Server (NTRS)

Moroney, D.; Lashbrook, D.; Mckibben, B.; Gardener, N.; Rivers, T.; Nottingham, G.; Golden, B.; Barfield, B.; Bruening, J.; Wood, D.

1992-01-01

A current thrust in satellite communication systems considers a low-Earth orbiting constellations of satellites for continuous global coverage. Conceptual design studies have been done at the time of this design project by LORAL Aerospace Corporation under the program name GLOBALSTAR and by Motorola under their IRIDIUM program. This design project concentrates on the spacecraft design of the GLOBALSTAR low-Earth orbiting communication system. Overview information on the program was gained through the Federal Communications Commission licensing request. The GLOBALSTAR system consists of 48 operational satellites positioned in a Walker Delta pattern providing global coverage and redundancy. The operational orbit is 1389 km (750 nmi) altitude with eight planes of six satellites each. The orbital planes are spaced 45 deg., and the spacecraft are separated by 60 deg. within the plane. A Delta 2 launch vehicle is used to carry six spacecraft for orbit establishment. Once in orbit, the spacecraft will utilize code-division multiple access (spread spectrum modulation) for digital relay, voice, and radio determination satellite services (RDSS) yielding position determination with accuracy up to 200 meters.

Conjugate gradient determination of optimal plane changes for a class of three-impulse transfers between noncoplanar circular orbits

NASA Technical Reports Server (NTRS)

Burrows, R. R.

1972-01-01

A particular type of three-impulse transfer between two circular orbits is analyzed. The possibility of three plane changes is recognized, and the problem is to optimally distribute these plane changes to minimize the sum of the individual impulses. Numerical difficulties and their solution are discussed. Numerical results obtained from a conjugate gradient technique are presented for both the case where the individual plane changes are unconstrained and for the case where they are constrained. Possibly not unexpectedly, multiple minima are found. The techniques presented could be extended to the finite burn case, but primarily the contents are addressed to preliminary mission design and vehicle sizing.

The H.E.S.S. Galactic plane survey

NASA Astrophysics Data System (ADS)

H. E. S. S. Collaboration; Abdalla, H.; Abramowski, A.; Aharonian, F.; Benkhali, F. Ait; Angüner, E. O.; Arakawa, M.; Arrieta, M.; Aubert, P.; Backes, M.; Balzer, A.; Barnard, M.; Becherini, Y.; Tjus, J. Becker; Berge, D.; Bernhard, S.; Bernlöhr, K.; Blackwell, R.; Böttcher, M.; Boisson, C.; Bolmont, J.; Bonnefoy, S.; Bordas, P.; Bregeon, J.; Brun, F.; Brun, P.; Bryan, M.; Büchele, M.; Bulik, T.; Capasso, M.; Carrigan, S.; Caroff, S.; Carosi, A.; Casanova, S.; Cerruti, M.; Chakraborty, N.; Chaves, R. C. G.; Chen, A.; Chevalier, J.; Colafrancesco, S.; Condon, B.; Conrad, J.; Davids, I. D.; Decock, J.; Deil, C.; Devin, J.; deWilt, P.; Dirson, L.; Djannati-Ataï, A.; Domainko, W.; Donath, A.; Drury, L. O.'C.; Dutson, K.; Dyks, J.; Edwards, T.; Egberts, K.; Eger, P.; Emery, G.; Ernenwein, J.-P.; Eschbach, S.; Farnier, C.; Fegan, S.; Fernandes, M. V.; Fiasson, A.; Fontaine, G.; Förster, A.; Funk, S.; Füßling, M.; Gabici, S.; Gallant, Y. A.; Garrigoux, T.; Gast, H.; Gaté, F.; Giavitto, G.; Giebels, B.; Glawion, D.; Glicenstein, J. F.; Gottschall, D.; Grondin, M.-H.; Hahn, J.; Haupt, M.; Hawkes, J.; Heinzelmann, G.; Henri, G.; Hermann, G.; Hinton, J. A.; Hofmann, W.; Hoischen, C.; Holch, T. L.; Holler, M.; Horns, D.; Ivascenko, A.; Iwasaki, H.; Jacholkowska, A.; Jamrozy, M.; Jankowsky, D.; Jankowsky, F.; Jingo, M.; Jouvin, L.; Jung-Richardt, I.; Kastendieck, M. A.; Katarzyński, K.; Katsuragawa, M.; Katz, U.; Kerszberg, D.; Khangulyan, D.; Khélifi, B.; King, J.; Klepser, S.; Klochkov, D.; Kluźniak, W.; Komin, Nu.; Kosack, K.; Krakau, S.; Kraus, M.; Krüger, P. P.; Laffon, H.; Lamanna, G.; Lau, J.; Lees, J.-P.; Lefaucheur, J.; Lemière, A.; Lemoine-Goumard, M.; Lenain, J.-P.; Leser, E.; Lohse, T.; Lorentz, M.; Liu, R.; López-Coto, R.; Lypova, I.; Marandon, V.; Malyshev, D.; Marcowith, A.; Mariaud, C.; Marx, R.; Maurin, G.; Maxted, N.; Mayer, M.; Meintjes, P. J.; Meyer, M.; Mitchell, A. M. W.; Moderski, R.; Mohamed, M.; Mohrmann, L.; Morå, K.; Moulin, E.; Murach, T.; Nakashima, S.; de Naurois, M.; Ndiyavala, H.; Niederwanger, F.; Niemiec, J.; Oakes, L.; O'Brien, P.; Odaka, H.; Ohm, S.; Ostrowski, M.; Oya, I.; Padovani, M.; Panter, M.; Parsons, R. D.; Paz Arribas, M.; Pekeur, N. W.; Pelletier, G.; Perennes, C.; Petrucci, P.-O.; Peyaud, B.; Piel, Q.; Pita, S.; Poireau, V.; Poon, H.; Prokhorov, D.; Prokoph, H.; Pühlhofer, G.; Punch, M.; Quirrenbach, A.; Raab, S.; Rauth, R.; Reimer, A.; Reimer, O.; Renaud, M.; de los Reyes, R.; Rieger, F.; Rinchiuso, L.; Romoli, C.; Rowell, G.; Rudak, B.; Rulten, C. B.; Safi-Harb, S.; Sahakian, V.; Saito, S.; Sanchez, D. A.; Santangelo, A.; Sasaki, M.; Schandri, M.; Schlickeiser, R.; Schüssler, F.; Schulz, A.; Schwanke, U.; Schwemmer, S.; Seglar-Arroyo, M.; Settimo, M.; Seyffert, A. S.; Shafi, N.; Shilon, I.; Shiningayamwe, K.; Simoni, R.; Sol, H.; Spanier, F.; Spir-Jacob, M.; Stawarz, Ł.; Steenkamp, R.; Stegmann, C.; Steppa, C.; Sushch, I.; Takahashi, T.; Tavernet, J.-P.; Tavernier, T.; Taylor, A. M.; Terrier, R.; Tibaldo, L.; Tiziani, D.; Tluczykont, M.; Trichard, C.; Tsirou, M.; Tsuji, N.; Tuffs, R.; Uchiyama, Y.; van der Walt, D. J.; van Eldik, C.; van Rensburg, C.; van Soelen, B.; Vasileiadis, G.; Veh, J.; Venter, C.; Viana, A.; Vincent, P.; Vink, J.; Voisin, F.; Völk, H. J.; Vuillaume, T.; Wadiasingh, Z.; Wagner, S. J.; Wagner, P.; Wagner, R. M.; White, R.; Wierzcholska, A.; Willmann, P.; Wörnlein, A.; Wouters, D.; Yang, R.; Zaborov, D.; Zacharias, M.; Zanin, R.; Zdziarski, A. A.; Zech, A.; Zefi, F.; Ziegler, A.; Zorn, J.; Żywucka, N.

2018-04-01

We present the results of the most comprehensive survey of the Galactic plane in very high-energy (VHE) γ-rays, including a public release of Galactic sky maps, a catalog of VHE sources, and the discovery of 16 new sources of VHE γ-rays. The High Energy Spectroscopic System (H.E.S.S.) Galactic plane survey (HGPS) was a decade-long observation program carried out by the H.E.S.S. I array of Cherenkov telescopes in Namibia from 2004 to 2013. The observations amount to nearly 2700 h of quality-selected data, covering the Galactic plane at longitudes from ℓ = 250° to 65° and latitudes |b|≤ 3°. In addition to the unprecedented spatial coverage, the HGPS also features a relatively high angular resolution (0.08° ≈ 5 arcmin mean point spread function 68% containment radius), sensitivity (≲1.5% Crab flux for point-like sources), and energy range (0.2-100 TeV). We constructed a catalog of VHE γ-ray sources from the HGPS data set with a systematic procedure for both source detection and characterization of morphology and spectrum. We present this likelihood-based method in detail, including the introduction of a model component to account for unresolved, large-scale emission along the Galactic plane. In total, the resulting HGPS catalog contains 78 VHE sources, of which 14 are not reanalyzed here, for example, due to their complex morphology, namely shell-like sources and the Galactic center region. Where possible, we provide a firm identification of the VHE source or plausible associations with sources in other astronomical catalogs. We also studied the characteristics of the VHE sources with source parameter distributions. 16 new sources were previously unknown or unpublished, and we individually discuss their identifications or possible associations. We firmly identified 31 sources as pulsar wind nebulae (PWNe), supernova remnants (SNRs), composite SNRs, or gamma-ray binaries. Among the 47 sources not yet identified, most of them (36) have possible

A Herschel [C ii] Galactic plane survey. II. CO-dark H2 in clouds

NASA Astrophysics Data System (ADS)

Langer, W. D.; Velusamy, T.; Pineda, J. L.; Willacy, K.; Goldsmith, P. F.

2014-01-01

Context. H i and CO large scale surveys of the Milky Way trace the diffuse atomic clouds and the dense shielded regions of molecular hydrogen clouds, respectively. However, until recently, we have not had spectrally resolved C+ surveys in sufficient lines of sight to characterize the ionized and photon dominated components of the interstellar medium, in particular, the H2 gas without CO, referred to as CO-dark H2, in a large sample of interstellar clouds. Aims: We use a sparse Galactic plane survey of the 1.9 THz (158 μm) [C ii] spectral line from the Herschel open time key programme, Galactic Observations of Terahertz C+ (GOT C+), to characterize the H2 gas without CO in a statistically significant sample of interstellar clouds. Methods: We identify individual clouds in the inner Galaxy by fitting the [C ii] and CO isotopologue spectra along each line of sight. We then combine these spectra with those of H i and use them along with excitation models and cloud models of C+ to determine the column densities and fractional mass of CO-dark H2 clouds. Results: We identify1804 narrow velocity [C ii] components corresponding to interstellar clouds in different categories and evolutionary states. About 840 are diffuse molecular clouds with no CO, ~510 are transition clouds containing [C ii] and 12CO, but no 13CO, and the remainder are dense molecular clouds containing 13CO emission. The CO-dark H2 clouds are concentrated between Galactic radii of ~3.5 to 7.5 kpc and the column density of the CO-dark H2 layer varies significantly from cloud to cloud with a global average of 9 × 1020 cm-2. These clouds contain a significant fraction by mass of CO-dark H2, that varies from ~75% for diffuse molecular clouds to ~20% for dense molecular clouds. Conclusions: We find a significant fraction of the warm molecular ISM gas is invisible in H i and CO, but is detected in [C ii]. The fraction of CO-dark H2 is greatest in the diffuse clouds and decreases with increasing total column

Sentinel-2A: Orbit Modelling Improvements and their Impact on the Orbit Prediction

NASA Astrophysics Data System (ADS)

Peter, Heike; Otten, Michiel; Fernández Sánchez, Jaime; Fernández Martín, Carlos; Féménias, Pierre

2016-07-01

Sentinel-2A is the second satellite of the European Copernicus Programme. The satellite has been launched on 23rd June 2015 and it is operational since mid October 2015. This optical mission carries a GPS receiver for precise orbit determination. The Copernicus POD (Precise Orbit Determination) Service is in charge of generating precise orbital products and auxiliary files for Sentinel-2A as well as for the Sentinel-1 and -3 missions. The accuracy requirements for the Sentinel-2A orbit products are not very stringent with 3 m in 3D (3 sigma) for the near real-time (NRT) orbit and 10 m in 2D (3 sigma) for the predicted orbit. The fulfilment of the orbit accuracy requirements is normally not an issue. The Copernicus POD Service aims, however, to provide the best possible orbits for all three Sentinel missions. Therefore, a sophisticated box-wing model is generated for the Sentinel-2 satellite as it is done for the other two missions as well. Additionally, the solar wing of the satellite is rewound during eclipse, which has to be modelled accordingly. The quality of the orbit prediction is dependent on the results of the orbit estimation performed before it. The values of the last estimation of each parameter is taken for the orbit propagation, i.e. estimating ten atmospheric drag coefficients per 24h, the value of the last coefficient is used as a fix parameter for the subsequent orbit prediction. The question is whether the prediction might be stabilised by, e.g. using an average value of all ten coefficients. This paper presents the status and the quality of the Sentinel-2 orbit determination in the operational environment of the Copernicus POD Service. The impact of the orbit model improvements on the NRT and predicted orbits is studied in detail. Changes in the orbit parametrization as well as in the settings for the orbit propagation are investigated. In addition, the impact of the quality of the input GPS orbit and clock product on the Sentinel-2A orbit

Orbit determination of the Next-Generation Beidou satellites with Intersatellite link measurements and a priori orbit constraints

NASA Astrophysics Data System (ADS)

Ren, Xia; Yang, Yuanxi; Zhu, Jun; Xu, Tianhe

2017-11-01

Intersatellite Link (ISL) technology helps to realize the auto update of broadcast ephemeris and clock error parameters for Global Navigation Satellite System (GNSS). ISL constitutes an important approach with which to both improve the observation geometry and extend the tracking coverage of China's Beidou Navigation Satellite System (BDS). However, ISL-only orbit determination might lead to the constellation drift, rotation, and even lead to the divergence in orbit determination. Fortunately, predicted orbits with good precision can be used as a priori information with which to constrain the estimated satellite orbit parameters. Therefore, the precision of satellite autonomous orbit determination can be improved by consideration of a priori orbit information, and vice versa. However, the errors of rotation and translation in a priori orbit will remain in the ultimate result. This paper proposes a constrained precise orbit determination (POD) method for a sub-constellation of the new Beidou satellite constellation with only a few ISLs. The observation model of dual one-way measurements eliminating satellite clock errors is presented, and the orbit determination precision is analyzed with different data processing backgrounds. The conclusions are as follows. (1) With ISLs, the estimated parameters are strongly correlated, especially the positions and velocities of satellites. (2) The performance of determined BDS orbits will be improved by the constraints with more precise priori orbits. The POD precision is better than 45 m with a priori orbit constrain of 100 m precision (e.g., predicted orbits by telemetry tracking and control system), and is better than 6 m with precise priori orbit constraints of 10 m precision (e.g., predicted orbits by international GNSS monitoring & Assessment System (iGMAS)). (3) The POD precision is improved by additional ISLs. Constrained by a priori iGMAS orbits, the POD precision with two, three, and four ISLs is better than 6, 3, and 2

Universal two-dimensional characteristics in perovskite-type oxyhydrides ATiO2H (A = Li, Na, K, Rb, Cs)

NASA Astrophysics Data System (ADS)

Sato, Nobuya; Akashi, Ryosuke; Tsuneyuki, Shinji

2017-07-01

A series of unsynthesized perovskite-type oxyhydrides ATiO2H (A = Li, Na, K, Rb, Cs) are investigated by the density functional calculations. These oxyhydrides are stable in the sense of the formation energies for some possible synthesis reactions. They are crystallized into quite similar crystal structures with the long c-axis, and the corner-sharing TiO4H2 octahedra of the ideal perovskite-type structure are deformed into the 5-fold coordinated titanium atoms with the OH plane and the apical oxygen atoms. All of these oxyhydrides exhibit two-dimensional electronic states at the valence band maximum characterized by the in-plane oxygen 2p and the hydrogen 1s orbitals. While the c-axis becomes short as the ionic radius of the A atom becomes small and the two-dimensional characteristics are weakened, the electronic state at the valence band maximum is still characterized as the O-H in-plane state. Additionally, the Born effective charge tensors, spontaneous electric polarizations, dielectric tensors, and piezoelectric tensors are evaluated. It is found that the spontaneous electric polarizations of these oxyhydrides are much larger than that of tetragonal BaTiO3.

Search for and Study of Nearly Periodic Orbits in the Plane Problem of Three Equal-Mass Bodies

NASA Astrophysics Data System (ADS)

Martynova, A. I.; Orlov, V. V.

2005-09-01

We analyze nearly periodic solutions in the plane problem of three equal-mass bodies by numerically simulating the dynamics of triple systems. We identify families of orbits in which all three points are on one straight line (syzygy) at the initial time. In this case, at fixed total energy of a triple system, the set of initial conditions is a bounded region in four-dimensional parameter space. We scan this region and identify sets of trajectories in which the coordinates and velocities of all bodies are close to their initial values at certain times (which are approximately multiples of the period). We classify the nearly periodic orbits by the structure of trajectory loops over one period. We have found the families of orbits generated by von Schubart’s stable periodic orbit revealed in the rectilinear three-body problem. We have also found families of hierarchical, nearly periodic trajectories with prograde and retrograde motions. In the orbits with prograde motions, the trajectory loops of two close bodies form looplike structures. The trajectories with retrograde motions are characterized by leafed structures. Orbits with central and axial symmetries are identified among the families found.

On the ultraviolet photodissociation of H2Te

NASA Astrophysics Data System (ADS)

Alekseyev, Aleksey B.; Liebermann, Heinz-Peter; Wittig, Curt

2004-11-01

The photodissociation of H2Te through excitation in the first absorption band is investigated by means of multireference spin-orbit configuration interaction (CI) calculations. Bending potentials for low-lying electronic states of H2Te are obtained in C2v symmetry for Te-H distances fixed at the ground state equilibrium value of 3.14a0, as well as for the minimum energy path constrained to R1=R2. Asymmetric cuts of potential energy surfaces for excited states (at R1=3.14a0 and θ=90.3°) are obtained for the first time. It is shown that vibrational structure in the 380-400 nm region of the long wavelength absorption tail is due to transitions to 3A', which has a shallow minimum at large HTe-H separations. Transitions to this state are polarized in the molecular plane, and this state converges to the excited TeH(2Π1/2)+H(2S) limit. These theoretical data are in accord with the selectivity toward TeH(2Π1/2) relative to TeH(2Π3/2) that has been found experimentally for 355 nm H2Te photodissociation. The calculated 3A'←X˜A' transition dipole moment increases rapidly with HTe-H distance; this explains the observation of 3A' vibrational structure for low vibrational levels, despite unfavorable Franck-Condon factors. According to the calculated vertical energies and transition moment data, the maximum in the first absorption band at ≈245 nm is caused by excitation to 4A″, which has predominantly 21A″ (1B1 in C2v symmetry) character.

An adaptive guidance algorithm for an aerodynamically assisted orbital plane change maneuver. M.S. Thesis

NASA Technical Reports Server (NTRS)

Blissit, J. A.

1986-01-01

Using analysis results from the post trajectory optimization program, an adaptive guidance algorithm is developed to compensate for density, aerodynamic and thrust perturbations during an atmospheric orbital plane change maneuver. The maneuver offers increased mission flexibility along with potential fuel savings for future reentry vehicles. Although designed to guide a proposed NASA Entry Research Vehicle, the algorithm is sufficiently generic for a range of future entry vehicles. The plane change analysis provides insight suggesting a straight-forward algorithm based on an optimized nominal command profile. Bank angle, angle of attack, and engine thrust level, ignition and cutoff times are modulated to adjust the vehicle's trajectory to achieve the desired end-conditions. A performance evaluation of the scheme demonstrates a capability to guide to within 0.05 degrees of the desired plane change and five nautical miles of the desired apogee altitude while maintaining heating constraints. The algorithm is tested under off-nominal conditions of + or -30% density biases, two density profile models, + or -15% aerodynamic uncertainty, and a 33% thrust loss and for various combinations of these conditions.

2. VIEW SOUTH, INCLINE PLANE CAR, INCLINE PLANE TRACK, UPPER ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

2. VIEW SOUTH, INCLINE PLANE CAR, INCLINE PLANE TRACK, UPPER STATION. - Monongahela Incline Plane, Connecting North side of Grandview Avenue at Wyoming Street with West Carson Street near Smithfield Street, Pittsburgh, Allegheny County, PA

Mechanisms for the Production of Fast HI from Dissociation of H2 on Saturn

NASA Astrophysics Data System (ADS)

Liu, Xianming; Johnson, Paul; Malone, Charles; Young, Jason; Kanik, Isik; Shemansky, Donald

2010-05-01

Images of the Saturn system obtained by the Cassini UVIS at a pixel resolution of 0.1 × 0.1 Saturn radii (Rs) reveal atomic hydrogen in ballistic and escaping trajectories sourced at the top of the thermosphere, primarily in the southern sunlit hemisphere. The main feature in the image is a distinctive H Lyman-α plume structure with FWHM of 0.56 Rs at the exobase sub-solar limb at ~ -13.5° latitude constituting the core of the distributed outward flow of atomic hydrogen from the sunlit hemisphere, with a counterpart on the anti-solar side peaking near the equator above the exobase limb. The structure of the image indicates that part of the out-flowing population is sub-orbital and re-enters the thermosphere in ~ 5 hour time scale. A larger and more broadly distributed component fills the magnetosphere to beyond 45 Rs in the orbital plane and 20 Rs latitudinally above and below the plane in an asymmetric distribution in local time. Molecular hydrogen emission in extreme and far ultraviolet regions collected with the H Lyman-α into the image mosaic reveals a distinctive resonance property correlated with the atomic hydrogen plume and shows a strong deviation of H2 X 1Σg+ from local thermodynamic equilibrium in the main source region. The inferred approximate globally averaged energy deposition at the top of the thermosphere from the production of the hot atomic hydrogen accounts for the measured atmospheric temperature. Possible processes for the fast atomic hydrogen formation from dissociation of H2 include the excitation of singlet-ungerade states and doubly excited states by photons and electrons, and the excitation of the singlet-gerade and triplet states by electrons, and chemical reactions involving the formation and dissociative recombination of H3+. Based on the available laboratory measurements and quantum mechanics calculations, the assessment of various mechanisms for H2 - H production, especially those producing H atoms with sufficient energy to

Focal plane subsystem design and performance for atmospheric chemistry from geostationary orbit tropospheric emissions monitoring of pollution

NASA Astrophysics Data System (ADS)

Gilmore, A. S.; Philbrick, R. H.; Funderburg, J.

2017-09-01

Remote sensing of pollutants are enabled from a satellite in a geostationary orbit containing an imaging spectrometer encompassing the wavelength ranges of 290 - 490 nm and 540 - 740 nm. As the first of NASA's Earth Venture Instrument Program, the Tropospheric Emissions: Monitoring of Pollution (TEMPO) program will utilize this instrument to measure hourly air quality over a large portion of North America. The focal plane subsystem (FPS) contains two custom designed and critically aligned full frame transfer charge coupled devices (active area: 1028 x 2048, 18 μm) within a focal plane array package designed for radiation tolerance and space charging rejection. In addition, the FPS contains custom distributed focal plane electronics that provide all necessary clocks and biases to the sensors, receives all analog data from the sensors and performs 14 bit analog to digital conversion for upstream processing. Finally, the FPS encompasses custom low noise cables connecting the focal plane array and associated electronics. This paper discusses the design and performance of this novel focal plane subsystem with particular emphasis on the optical performance achieved including alignment, quantum efficiency, and modulation transfer function.

Exospheric perturbations by radiation pressure. 2: Solution for orbits in the ecliptic plane

NASA Technical Reports Server (NTRS)

Chamberlain, J. W.

1980-01-01

The instantaneous rates of change for the orbital elements eccentricity, longitude of perigee from the Sun, and longitude from the Sun of the ascending node are integrated simultaneously for the case of the inclination i = 0. The results confirm the validity of using mean rates when the orbits are tightly bound to the planet and serve as examples to be reproduced by the complicated numerical solutions required for arbitrary inclination. Strongly bound hydrogen atoms escaping from Earth due to radiation pressure do not seem a likely cause of the geotail extending in the anti-sun direction. Instead, radiation pressure will cause those particles' orbits to deteriorate into the Earth's atmosphere.

Lunar Reconnaissance Orbiter Orbit Determination Accuracy Analysis

NASA Technical Reports Server (NTRS)

Slojkowski, Steven E.

2014-01-01

Results from operational OD produced by the NASA Goddard Flight Dynamics Facility for the LRO nominal and extended mission are presented. During the LRO nominal mission, when LRO flew in a low circular orbit, orbit determination requirements were met nearly 100% of the time. When the extended mission began, LRO returned to a more elliptical frozen orbit where gravity and other modeling errors caused numerous violations of mission accuracy requirements. Prediction accuracy is particularly challenged during periods when LRO is in full-Sun. A series of improvements to LRO orbit determination are presented, including implementation of new lunar gravity models, improved spacecraft solar radiation pressure modeling using a dynamic multi-plate area model, a shorter orbit determination arc length, and a constrained plane method for estimation. The analysis presented in this paper shows that updated lunar gravity models improved accuracy in the frozen orbit, and a multiplate dynamic area model improves prediction accuracy during full-Sun orbit periods. Implementation of a 36-hour tracking data arc and plane constraints during edge-on orbit geometry also provide benefits. A comparison of the operational solutions to precision orbit determination solutions shows agreement on a 100- to 250-meter level in definitive accuracy.

More on accreting black hole spacetime in equatorial plane

NASA Astrophysics Data System (ADS)

Salahshoor, K.; Nozari, K.; Khesali, A. R.

2017-02-01

Spacetime around an accreting black hole is an interesting issue to study. The metric of an isolated black hole (rotating or non-rotating) spacetime has been well-known for decades. Although metrics of some spacetimes containing accreting black holes are known in some situations, the issue has some faces that are not well-known yet and need further investigation. In this paper, we construct a new form of metric which the effect of accretion disk on black hole spacetime is taken into account in the equatorial plane. We study motion and trajectories of massive particles and also photons falling from infinity towards black hole in equatorial plane around the black hole. We use an exponential form for the density profile of the accretion disk in equatorial plane as ρ =ρ0e^{-α r}. We show that with this density profile, the disk is radially stable if α ≤ 3 × 10^{-3} (in units of length inverse). In order to study some important quantities related to the accretion disks such as locations of marginally stable circular orbits (r_{ms} or r_{ISCO}), marginally bounded circular orbits (r_{mb}), and also photon orbits in equatorial plane, we use the effective potential approach. We show that in this spacetime metric the innermost stable circular orbit in equatorial plane is given by r_{ISCO}=4.03 μ (where μ =MG/c 2) which is different, but comparable, with the Schwarzschild spacetime result, r^{(Sch)}_{ISCO}=6 μ . We show that the maximum radiation efficiency of the accretion disk, η , in equatorial plane is 8.6 percent which is greater than the corresponding value for Schwarzschild spacetime. Finally, we show that in this setup photons can have stable circular orbits in equatorial plane unlike the Schwarzschild spacetime.

Orbit on demand - Will cost determine best design?

NASA Technical Reports Server (NTRS)

Macconochie, J. O.; Mackley, E. A.; Morris, S. J.; Phillips, W. P.; Breiner, C. A.; Scotti, S. J.

1985-01-01

Eleven design concepts for vertical (V) and horizontal (H) take-off launch-on-demand manned orbital vehicles are discussed. Attention is given to up to three stages, Mach numbers (sub-, 2, or 3), expendable boosters, drop tanks (DT), and storable (S) or cryogenic fuels. All the concepts feature lifting bodies with circular cross-section and most have a 7 ft diam, 15 ft long payload bay as well as a crew compartment. Expendable elements impose higher costs and in some cases reduce all-azimuth launch capabilities. Single-stage vehicles simplify the logistics whether in H or V configuration. A two-stage H vehicle offers launch offset for the desired orbital plane before firing the rocket engines after take-off and subsonic acceleration. A two-stage fully reusable V form has the second lowest weight of the vehicles studied and an all-azimuth launch capability. Better definition of the prospective mission requirements is needed before choosing among the alternatives.

In-Orbit Operation of the ASTRO-H SXS

NASA Technical Reports Server (NTRS)

Tsujimoto, Masahiro; Mitsuda, Kazuhisa; Kelley, Richard L.; den Herder, Jan-Willem A.; Akamatsu, Hiroki; Bialas, Thomas G.; Boyce, Kevin R.; Brown, Gregory V.; Chiao, Meng P.; Costantini, Elisa;

In-orbit operation of the ASTRO-H SXS

NASA Astrophysics Data System (ADS)

Tsujimoto, Masahiro; Mitsuda, Kazuhisa; Kelley, Richard L.; den Herder, Jan-Willem A.; Akamatsu, Hiroki; Bialas, Thomas G.; Boyce, Kevin R.; Brown, Gregory V.; Chiao, Meng P.; Costantini, Elisa; de Vries, Cor P.; DiPirro, Michael J.; Eckart, Megan E.; Ezoe, Yuichiro; Fujimoto, Ryuichi; Haas, Daniel; Hoshino, Akio; Ishikawa, Kumi; Ishisaki, Yoshitaka; Iyomoto, Naoko; Kilbourne, Caroline A.; Kitamoto, Shunji; Koyama, Shu; Leutenegger, Maurice A.; McCammon, Dan; Mitsuishi, Ikuyuki; Murakami, Hiroshi; Murakami, Masahide; Noda, Hirofumi; Ogawa, Mina; Ota, Naomi; Paltani, Stéphane; Porter, Frederick S.; Sato, Kosuke; Sato, Yoichi; Sawada, Makoto; Seta, Hiromi; Shinozaki, Keisuke; Shirron, Peter J.; Sneiderman, Gary A.; Sugita, Hiroyuki; Szymkowiak, Andrew E.; Takei, Yoh; Tamagawa, Toru; Tashiro, Makoto S.; Terada, Yukikatsu; Yamada, Shinya; Yamasaki, Noriko Y.; Yatsu, Yoichi

2016-07-01

We summarize all the in-orbit operations of the Soft X-ray Spectrometer (SXS) onboard the ASTRO-H (Hit- omi) satellite. The satellite was launched on 2016/02/17 and the communication with the satellite ceased on 2016/03/26. The SXS was still in the commissioning phase, in which the setups were progressively changed. This article is intended to serve as a reference of the events in the orbit to properly interpret the SXS data taken during its short life time, and as a test case for planning the in-orbit operation for future micro-calorimeter missions.

Approaching the theoretical limit in periodic local MP2 calculations with atomic-orbital basis sets: the case of LiH.

PubMed

Usvyat, Denis; Civalleri, Bartolomeo; Maschio, Lorenzo; Dovesi, Roberto; Pisani, Cesare; Schütz, Martin

2011-06-07

The atomic orbital basis set limit is approached in periodic correlated calculations for solid LiH. The valence correlation energy is evaluated at the level of the local periodic second order Møller-Plesset perturbation theory (MP2), using basis sets of progressively increasing size, and also employing "bond"-centered basis functions in addition to the standard atom-centered ones. Extended basis sets, which contain linear dependencies, are processed only at the MP2 stage via a dual basis set scheme. The local approximation (domain) error has been consistently eliminated by expanding the orbital excitation domains. As a final result, it is demonstrated that the complete basis set limit can be reached for both HF and local MP2 periodic calculations, and a general scheme is outlined for the definition of high-quality atomic-orbital basis sets for solids. © 2011 American Institute of Physics

Shuttle on-orbit rendezvous targeting: Circular orbits

NASA Technical Reports Server (NTRS)

Bentley, E. L.

1972-01-01

The strategy and logic used in a space shuttle on-orbit rendezvous targeting program are described. The program generates ascent targeting conditions for boost to insertion into an intermediate parking orbit, and generates on-orbit targeting and timeline bases for each maneuver to effect rendezvous with a space station. Time of launch is determined so as to eliminate any plane change, and all work was performed for a near-circular space station orbit.

The role of the F spin-orbit excited state in the F+H(2) and F+HD reactions

NASA Astrophysics Data System (ADS)

Tzeng, Yi-Ren

In this dissertation we study the role of the F spin-orbit excited state (F*) in the F + H2 and F + HD reactions using quantum mechanical calculations. The calculations involve multiple potential energy surfaces (the Alexander-Stark-Werner, or ASW, PESs), and include an accurate treatment of the couplings (non-adiabatic, spin-orbit, and Coriolis) among all three electronic states. For the F + H2 reaction, we calculate the center-of-mass differential cross sections and laboratory-frame angular distributions at the four different combinations of collision energies and hydrogen isotopomer investigated in the experiments of Neumark et al. [J. Chem. Phys., 82, 3045 (1985)]. Comparisons with the calculations on the Stark-Werner (SW) and Hartke-Stark-Werner (HSW) PESs, which are limited to the lowest electronically adiabatic state, show that non-adiabatic couplings greatly reduce backward scattering. Surprisingly, we find the shapes of both the CM DCSs and LAB ADs are insensitive to the fraction of F* presented in the F beam. For the F + HD reaction, we calculate the excitation functions and product translational energy distribution functions to study the reactivity of F*. Comparisons with the experiment by Liu and co-workers [J. Chem. Phys., 113, 3633 (2000)] confirm the relatively low reactivity of spin-orbit excited state (F*) atoms. Excellent agreement with the experiment is obtained under the assumption that the F*:F concentration ratio equals 0.16:0.84 in the molecular beam, which corresponds to a thermal equilibrium of the two spin-orbit states at the experimental temperature (600K). From the accurate calculation of the F* reactivity and its relatively small contribution to the overall reactivity of the reaction, we attribute discrepancies between calculation and experiment to an inadequacy in the simulation of the reactivity of the F ground state, likely a result of the residual errors in the ground electronic potential energy surface.

[Pb(H2O)]2+ and [Pb(OH)]+: four-component density functional theory calculations, correlated scalar relativistic constrained-space orbital variation energy decompositions, and topological analysis.

PubMed

Gourlaouen, Christophe; Piquemal, Jean-Philip; Parisel, Olivier

2006-05-07

Within the scope of studying the molecular implications of the Pb(2+) cation in environmental and polluting processes, this paper reports Hartree-Fock and density functional theory (B3LYP) four-component relativistic calculations using an all-electron basis set applied to [Pb(H(2)O)](2+) and [Pb(OH)](+), two complexes expected to be found in the terrestrial atmosphere. It is shown that full-relativistic calculations validate the use of scalar relativistic approaches within the framework of density functional theory. [Pb(H(2)O)](2+) is found C(2v) at any level of calculations whereas [Pb(OH)](+) can be found bent or linear depending of the computational methodology used. When C(s) is found the barrier to inversion through the C(infinityv) structure is very low, and can be overcome at high enough temperature, making the molecule floppy. In order to get a better understanding of the bonding occurring between the Pb(2+) cation and the H(2)O and OH(-) ligands, natural bond orbital and atoms-in-molecule calculations have been performed. These approaches are supplemented by a topological analysis of the electron localization function. Finally, the description of these complexes is refined using constrained-space orbital variation complexation energy decompositions.

Orbiter 'Enterprise' rides 'piggy-back' atop NASA 747 carrier

NASA Technical Reports Server (NTRS)

1977-01-01

The Orbiter 101 'Enterprise' rides 'piggy-back' atop the NASA 747 carrier aircraft during the second free flight of the Shuttle Apporach and Landing Tests (ALTs) conducted on September 13, 1977 at Dryden Flight Research Center in Southern California. One chase plane can be seen in the left background, another appearing to be directly under the Boeing 747. Astronauts Joe H. Engle, and Richard H. Truly were the crew of the 'Enterprise.' The ALT free flights are designed to verify Orbiter subsonic airworthiness, integrated systems operations and pilot-guided approach and landing capability and satisfying prerequisites to automatic flight control and navigation mode.

Optimal trajectories for an aerospace plane. Part 2: Data, tables, and graphs

NASA Technical Reports Server (NTRS)

Miele, Angelo; Lee, W. Y.; Wu, G. D.

1990-01-01

Data, tables, and graphs relative to the optimal trajectories for an aerospace plane are presented. A single-stage-to-orbit (SSTO) configuration is considered, and the transition from low supersonic speeds to orbital speeds is studied for a single aerodynamic model (GHAME) and three engine models. Four optimization problems are solved using the sequential gradient-restoration algorithm for optimal control problems: (1) minimization of the weight of fuel consumed; (2) minimization of the peak dynamic pressure; (3) minimization of the peak heating rate; and (4) minimization of the peak tangential acceleration. The above optimization studies are carried out for different combinations of constraints, specifically: initial path inclination that is either free or given; dynamic pressure that is either free or bounded; and tangential acceleration that is either free or bounded.

Etude des trois molecules H 2P-NH 2, ClHP-NH 2, H 2P-NHCl au moyen d'une methode de pseudopotentiels

NASA Astrophysics Data System (ADS)

Barthelat, M.; Mathis, R.; Mathis, F.

The three molecules H 2P-NH 2, ClHP-NH 2 and H 2P-NHCl have been studied by a pseudo-potential method, with a minimal basis of quality mono-zeta, with 3 d functions on the phosphorus atom. The geometry of each molecule was optimized and the phosphorus-nitrogen rotation barrier calculated. The results of the calculations confirm that the polarity of the phosphorus-nitrogen bond is P +-N -. Three weak interactions appear: a partial coordinative bond between the nitrogen doublet and a 3 d orbital of the phosphorus atom, hyperconjugation between the nitrogen doublet and the P-H bonds, and participation of the 3 d orbital of phosphorus in the P-N bond.

β -decay scheme of 140Te to I 140 : Suppression of Gamow-Teller transitions between the neutron h9 /2 and proton h11 /2 partner orbitals

NASA Astrophysics Data System (ADS)

Moon, B.; Moon, C.-B.; Odahara, A.; Lozeva, R.; Söderström, P.-A.; Browne, F.; Yuan, C.; Yagi, A.; Hong, B.; Jung, H. S.; Lee, P.; Lee, C. S.; Nishimura, S.; Doornenbal, P.; Lorusso, G.; Sumikama, T.; Watanabe, H.; Kojouharov, I.; Isobe, T.; Baba, H.; Sakurai, H.; Daido, R.; Fang, Y.; Nishibata, H.; Patel, Z.; Rice, S.; Sinclair, L.; Wu, J.; Xu, Z. Y.; Yokoyama, R.; Kubo, T.; Inabe, N.; Suzuki, H.; Fukuda, N.; Kameda, D.; Takeda, H.; Ahn, D. S.; Shimizu, Y.; Murai, D.; Bello Garrote, F. L.; Daugas, J. M.; Didierjean, F.; Ideguchi, E.; Ishigaki, T.; Morimoto, S.; Niikura, M.; Nishizuka, I.; Komatsubara, T.; Kwon, Y. K.; Tshoo, K.

2017-07-01

We report for the first time the β -decay scheme of 140Te (Z =52 ) to 140I (Z =53 ), with a specific focus on the Gamow-Teller strength along N =87 isotones. These results were obtained in an experiment performed at the Radioactive Ion Beam Factory (RIBF), RIKEN, where the parent nuclide, 140Te, was produced through the in-flight fission of a 238U beam at 345 MeV per nucleon impinging on a 9Be target. Based on data from the high-efficiency γ -ray spectrometer, EUROBALL-RIKEN Cluster Array (EURICA), we constructed a decay scheme of 140I. The half-life of 140Te has been determined to be 350(5) ms. A level at 926 keV has been assigned as a (1+) state based on the logf t value of 4.89(6). This (1+) state, commonly observed in odd-odd nuclei, can be interpreted in terms of the π h11 /2ν h9 /2 configuration formed by the Gamow-Teller transition between a neutron in the h9 /2 orbital and a proton in the h11 /2 orbital. We observe a sharp contrast to this type of β -decay branching to the lower-lying 1+ states between 140I and 136I, where we see a large reduction as the number of neutrons increases. This is in contrast to the prediction by large-scale shell model calculations. To investigate this type of the suppression, results of the Nilsson model calculations will be discussed. Along the isotones with N =87 , we discuss a characteristic feature of the Gamow-Teller distributions at 1+ states with respect to the isospin difference.

Crystal structure and spectroscopic behavior of synthetic novgorodovaite Ca2(C2O4)Cl2·2H2O and its twinned triclinic heptahydrate analog

NASA Astrophysics Data System (ADS)

Piro, Oscar E.; Echeverría, Gustavo A.; González-Baró, Ana C.; Baran, Enrique J.

2018-02-01

Synthetic novgorodovaite analog Ca2(C2O4)Cl2·2H2O is identical to its natural counterpart. It crystallizes in the monoclinic I2/ m space group with a = 6.9352(3), b = 7.3800(4), c = 7.4426(3) Å, β = 94.303(4)°, V = 379.85(3) Å3 and Z = 2. The heptahydrate analog, Ca2(C2O4)Cl2·7H2O, crystallizes as triclinic twins in the P \\overline{1} space group with a = 7.3928(8), b = 8.9925(4), c = 10.484(2) Å, α = 84.070(7), β = 70.95(1), γ = 88.545(7)°, V = 655.3(1) Å3 and Z = 2. The crystal packing of both calcium oxalate-chloride double salts favors the directional bonding of oxalate, C2O4 2-, ligands to calcium ions as do other related calcium oxalate minerals. The π-bonding between C and O atoms of the C2O4 2- oxalate group leaves sp 2-hydridised orbitals of the oxygen atoms available for bonding to Ca. Thus, the Ca-O bonds in both calcium oxalate-chloride double salts are directed so as to lie in the plane of the oxalate group. This behavior is reinforced by the short O···O distances between the oxygens attached to a given carbon atom, which favors them bonding to a shared Ca atom in bidentate fashion. Strong bonding in the plane of the oxalate anion and wide spacing perpendicular to that plane due to repulsion between oxalate π-electron clouds gives rise to a polymerized structural units which are common to both hydrates, explaining the nearly equal cell constants 7.4 Å which are defined by the periodicity of Ca-oxalate chains in the framework (monoclinic b ≈ triclinic a). When compared with novgorodovaite, the higher water content of Ca2(C2O4)Cl2·7H2O leads to some major differences in their structures and ensuing physical properties. While novgorodovaite has a three-dimensional framework structure, in the higher hydrate, the highly polar water molecules displace chloride ions from the calcium coordination sphere and surround them through OwH···Cl hydrogen bonds. As a result, polymerization in Ca2(C2O4)Cl2·7H2O solid is limited to the formation

Communications satellites in non-geostationary orbits

NASA Technical Reports Server (NTRS)

Price, Kent M.; Doong, Wen; Nguyen, Tuan Q.; Turner, Andrew E.; Weyandt, Charles

1988-01-01

The design of a satellite communications system in an orbit lower than GEO is described. Two sun-synchronous orbits which lie in the equatorial plane have been selected: (1) the apogee at constant time-of-day equatorial orbit, a highly eccentric orbit with five revolutions per day, which allows 77-135 percent more satellite mass to be placed in orbit than for GEO; and (2) the sun-synchronous 12-hour equatorial orbit, a circular orbit with two revolutions per day, which allows 23-29 percent more mass. The results of a life cycle economic analysis illustrate that nongeostationary satellite systems could be competitive with geostationary satellite systems.

Non-plane-wave Hartree-Fock states and nuclear homework potentials

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gutierrez, G.; Plastino, A.; de Llano, M.

1979-12-01

It is shown that non-plane-wave single-particle Hartree-Fock orbitals giving rise to a ''spin-density-wave-like'' structure give lower energy than plane waves beyond a certain relatively low density in both nuclear and neutron matter with homework pair potentials v/sub 1/ and v/sub 2/.

Analytic model for the long-term evolution of circular Earth satellite orbits including lunar node regression

NASA Astrophysics Data System (ADS)

Zhu, Ting-Lei; Zhao, Chang-Yin; Zhang, Ming-Jiang

2017-04-01

This paper aims to obtain an analytic approximation to the evolution of circular orbits governed by the Earth's J2 and the luni-solar gravitational perturbations. Assuming that the lunar orbital plane coincides with the ecliptic plane, Allan and Cook (Proc. R. Soc. A, Math. Phys. Eng. Sci. 280(1380):97, 1964) derived an analytic solution to the orbital plane evolution of circular orbits. Using their result as an intermediate solution, we establish an approximate analytic model with lunar orbital inclination and its node regression be taken into account. Finally, an approximate analytic expression is derived, which is accurate compared to the numerical results except for the resonant cases when the period of the reference orbit approximately equals the integer multiples (especially 1 or 2 times) of lunar node regression period.

Precise Tracking of the Magellan and Pioneer Venus Orbiters by Same-Beam Interferometry. Part 2: Orbit Determination Analysis

NASA Technical Reports Server (NTRS)

Folkner, W. M.; Border, J. S.; Nandi, S.; Zukor, K. S.

1993-01-01

A new radio metric positioning technique has demonstrated improved orbit determination accuracy for the Magellan and Pioneer Venus Orbiter orbiters. The new technique, known as Same-Beam Interferometry (SBI), is applicable to the positioning of multiple planetary rovers, landers, and orbiters which may simultaneously be observed in the same beamwidth of Earth-based radio antennas. Measurements of carrier phase are differenced between spacecraft and between receiving stations to determine the plane-of-sky components of the separation vector(s) between the spacecraft. The SBI measurements complement the information contained in line-of-sight Doppler measurements, leading to improved orbit determination accuracy. Orbit determination solutions have been obtained for a number of 48-hour data arcs using combinations of Doppler, differenced-Doppler, and SBI data acquired in the spring of 1991. Orbit determination accuracy is assessed by comparing orbit solutions from adjacent data arcs. The orbit solution differences are shown to agree with expected orbit determination uncertainties. The results from this demonstration show that the orbit determination accuracy for Magellan obtained by using Doppler plus SBI data is better than the accuracy achieved using Doppler plus differenced-Doppler by a factor of four and better than the accuracy achieved using only Doppler by a factor of eighteen. The orbit determination accuracy for Pioneer Venus Orbiter using Doppler plus SBI data is better than the accuracy using only Doppler data by 30 percent.

Viewing Saturn from the Plane

NASA Image and Video Library

2006-04-19

This view of the ringed planet shows its tilt relative to the plane of its orbit around the Sun. The planet tilts nearly 27 degrees relative to the ecliptic plane giving rise to seasons in which the rings shadow each hemisphere in its respective winter

Quantum superalgebra slq( {2}/{1}) on the Poincaré half-plane

NASA Astrophysics Data System (ADS)

Jellal, A.

2001-02-01

We find that the symmetry algebra for the motion of a spin- {1}/{2} electron moving in the Poincaré upper half-plane ( H) under the action of a constant magnetic field (orthogonal to H) is the quantum superalgebra slq( {2}/{1}). From this, and using representation theory, we are able to determine the degree of degeneracy of the lowest Landau level when q is a root of unity.

Electronic structure and energetics of the tetragonal distortion for TiH2, ZrH2 and HfH2: a first principles study

DOE Office of Scientific and Technical Information (OSTI.GOV)

Quijano, Ramiro; DeCoss, Romeo; Singh, David J

2009-01-01

The electronic structure and energetics of the tetragonal distortion for the fluorite-type dihydrides TiH{sub 2}, ZrH{sub 2}, and HfH{sub 2} are studied by means of highly accurate first-principles total-energy calculations. For HfH{sub 2}, in addition to the calculations using the scalar relativistic (SR) approximation, calculations including the spin-orbit coupling have also been performed. The results show that TiH{sub 2}, ZrH{sub 2}, and HfH{sub 2} in the cubic phase are unstable against tetragonal strain. For the three systems, the total energy shows two minima as a function of the c/a ratio with the lowest-energy minimum at c/a < 1 in agreementmore » with the experimental observations. The band structure of TiH{sub 2}, ZrH{sub 2}, and HfH{sub 2} (SR) around the Fermi level shows two common features along the two major symmetry directions of the Brillouin zone, {Lambda}?L and {Lambda}?K, a nearly flat doubly degenerate band, and a van Hove singularity, respectively. In cubic HfH{sub 2} the spin-orbit coupling lifts the degeneracy of the partially filled bands in the {Lambda}?L path, while the van Hove singularity in the {Lambda}?K path remains unchanged. The density of states of the three systems in the cubic phase shows a sharp peak at the Fermi level. We found that the tetragonal distortion produces a strong reduction in the density of states at the Fermi level resulting mainly from the splitting of the doubly-degenerate bands in the {Lambda}?L direction and the shift of the van Hove singularity to above the Fermi level. The validity of the Jahn-Teller model in explaining the tetragonal distortion in this group of dihydrides is discussed.« less

dxz/yz subband structure and Chiral Orbital Angular Momentum of Nb doped SrTiO3 surface states

NASA Astrophysics Data System (ADS)

Soltani, Shoresh; Cho, Soohyun; Ryu, Hanyoung; Han, Garam; Kim, Timur; Hoesch, Moritz; Kim, Changyoung

Using angle resolved photoemission spectroscopy (ARPES), we investigate subband structure and chiral orbital angular momentum (OAM) texture on the surface of lightly electron doped SrTiO3 single crystals. Our linearly polarized light ARPES data taken with 51 eV photons, reveal additional subbands for out-of-plane dxz/yzorbitals in addition to the previously reported ones. Our CD-ARPES data reveal a chiral OAM structure which we use as a clue to explain the origin of linear Rashba-like surface band splitting of Ti 3d t2g orbitals. The observed CD signal is enhanced near crossing points, where different orbitals hybridize, compatible with a linear Rashba-like surface band splitting. The work was supported by IBS-R009-G2. S.S., S.C., H.Y. and G. H. acknowledge were supported by Yonsei university, BK21 program.

Polar orbits around binary stars

NASA Astrophysics Data System (ADS)

Egan, Greg

2018-01-01

Oks proposes the existence of a new class of stable planetary orbits around binary stars, in the shape of a helix on a conical surface whose axis of symmetry coincides with the interstellar axis, and rotates with the same orbital frequency as the binary pair. We show that this claim relies on the inappropriate use of an effective potential that is only applicable when the stars are held motionless. We also present numerical evidence that the only planetary orbits whose planes are initially orthogonal to the interstellar axis that remain stable on the time scale of the stellar orbit are ordinary polar orbits around one of the stars, and that the perturbations due to the binary companion do not rotate the plane of the orbit to maintain a fixed relationship with the axis.

Stability of the Nagaoka-type ferromagnetic state in a t2 g orbital system on a cubic lattice

NASA Astrophysics Data System (ADS)

Bobrow, Eric; Li, Yi

2018-04-01

We generalize the previous exact results of the Nagaoka-type itinerant ferromagnetic states in a three-dimensional t2 g orbital system to allow for multiple holes. The system is a simple cubic lattice with each site possessing dx y,dy z, and dx z orbitals, which allow two-dimensional hopping within each orbital plane. In the strong-coupling limit of U →∞ , the orbital-generalized Nagaoka ferromagnetic states are proved to be degenerate with the ground state in the thermodynamic limit when the hole number per orbital layer scales slower than L1/2. This result is valid for arbitrary values of the ferromagnetic Hund's coupling J >0 and interorbital repulsion V ≥0 . The stability of the Nagaoka-type state at finite electron densities with respect to a single spin flip is investigated. These results provide helpful guidance for studying the mechanism of itinerant ferromagnetism for the t2 g orbital materials.

Orbital Transfer Techniques for Round-Trip Mars Missions

NASA Technical Reports Server (NTRS)

Landau, Damon

2013-01-01

The human exploration of Phobos and Deimos or the retrieval of a surface sample launched to low-Mars orbit presents a highly constrained orbital transfer problem. In general, the plane of the target orbit will not be accessible from the arrival or departure interplanetary trajectories with an (energetically optimal) tangential burn at periapsis. The orbital design is further complicated by the addition of a high-energy parking orbit for the relatively massive Deep Space Vehicle to reduce propellant expenditure, while the crew transfers to and from the target orbit in a smaller Space Exploration Vehicle. The proposed strategy shifts the arrival and departure maneuvers away from periapsis so that the apsidal line of the parking orbit lies in the plane of the target orbit, permitting highly efficient plane change maneuvers at apoapsis of the elliptical parking orbit. An apsidal shift during the arrival or departure maneuver is approximately five times as efficient as maneuvering while in Mars orbit, thus significantly reducing the propellant necessary to transfer between the arrival, target, and departure orbits.

A qualitative study of the complete set of solutions of the differential equation of motion of a test particle in the equatorial plane of the Kerr gravitational field

NASA Technical Reports Server (NTRS)

Montgomery, H. E.; Chan, F. K.

1973-01-01

A study is made of the mathematical solution of the differential equation of motion of a test particle in the equatorial plane of the Kerr gravitational field, using S (Schwarzschild-like) coordinates. A qualitative solution of this equation leads to the conclusion that there can only be 25 different types of orbits. For each value of a, the results are presented in a master diagram for which h and e are the parameters. A master diagram divides the h, e parameter space into regions such that at each point within one of these regions the types of admissible orbits are qualitatively the same. A pictorial representation of the physical orbits in the r, phi plane is also given.

Mercury's spin-orbit model and signature of C/MR2

NASA Astrophysics Data System (ADS)

Rambaux, N.; Bois, E.

2003-04-01

The upcoming missions, MESSENGER (Solomon etal 2001, Planet. Space Sci 49) and Bepi Colombo (Milani etal 2001, Planet. Space Sci 49) with onboard instrumentation capable of measuring the rotational parameters stimulate the objective to reach an accurate theory of the rotational motion of Mercury. Our work deals with the physical and dynamical causes that induce librations around an equilibrium state defined by the 3:2 spin-orbit resonance of Mercury. In order to integrate the spin-orbit motion of Mercury, we have used our gravitational model of the solar System including the Moon's spin-orbit motion. This model, called SONYR (acronym of Spin-Orbit N-bodY Relativistic model), was previously built by Bois, Journet and Vokrouhlicky in accordance with the requirements of the Lunar Laser Ranging observational accuracy (see for instance a review by Bois 2000, C. R. Acad. Sci. Série IV, or Bois and Vokrouhlický 1995). Using the model, the present study is devoted to the main perturbations acting on the spin-orbit motion of Mercury such as the planetary interactions (and their hierarchy) and the dynamical figure of the planet. The effect of the torque of Venus is 105 times smaller in magnitude than the one due to the Sun. Moreover, the complete rotation of Mercury exhibits two proper frequencies, namely 15.825 and 1089 years, and one secular variation of 271043 years which is due to the nodal precession between the equatorial plane of Mercury and its orbital plane. It is the second synchronism of Mercury mentioned by Beletski in 1986. We have made into evidence that the 3:2 resonance of Mercury is preserved by this second synchronism, which can be understood as a spin-orbit secular resonance. We have shown that the secular resonance variable ψ - Ω librates with a frequency of 1089 years. Our model integration starts with an initial obliquity of 1.65 arcminute (re-evaluate from the Cassini state) and gives an amplitude of libration in longitude of the order of 20

Tetrahedral silsesquioxane-C2H2Ti complex for hydrogen storage

NASA Astrophysics Data System (ADS)

Konda, Ravinder; Tavhare, Priyanka; Ingale, Nilesh; Chaudhari, Ajay

2018-04-01

The interaction of molecular hydrogen with tetrahedral silsesquioxane (T4)-C2H2Ti complex has been studied using Density Functional Theory with M06-2X functional and MP2 method with 6-311++G** basis set. T4-C2H2Ti complex can absorb maximum five hydrogen molecules with the gravimetric hydrogen storage capacity of 3.4 wt %. Adsorption energy calculations show that H2 adsorption on T4-C2H2Ti complex is favorable at room temperature by both the methods. We have studied the effect of temperature and pressure on Gibbs free energy corrected adsorption energies. Molecular dynamics simulations for H2 adsorbed T4-C2H2Ti complex have also been performed at 300K and show that loosely bonded H2 molecule flies away within 1fs. Various interaction energies within the complex are studied. Stability of a complex is predicted by means of a gap between Highest Occupied Molecular Orbital (HUMO) and Lowest Unoccupied Molecular Orbital (LUMO). The H2 desorption temperature for T4-C2H2Ti complex is calculated with Van't Hoff equation and it is found to be 229K.

Exploring the Nature of the H[subscript 2] Bond. 1. Using Spreadsheet Calculations to Examine the Valence Bond and Molecular Orbital Methods

ERIC Educational Resources Information Center

Halpern, Arthur M.; Glendening, Eric D.

2013-01-01

A three-part project for students in physical chemistry, computational chemistry, or independent study is described in which they explore applications of valence bond (VB) and molecular orbital-configuration interaction (MO-CI) treatments of H[subscript 2]. Using a scientific spreadsheet, students construct potential-energy (PE) curves for several…

Metal alkyls programmed to generate metal alkylidenes by α-H abstraction: prognosis from NMR chemical shift† †Electronic supplementary information (ESI) available: Experimental and computational details, NMR spectra, results of NMR calculations and NCS analysis, graphical representation of shielding tensors, molecular orbital diagrams of selected compounds, optimized structures for all calculated species. See DOI: 10.1039/c7sc05039a

PubMed Central

Gordon, Christopher P.; Yamamoto, Keishi; Searles, Keith; Shirase, Satoru

2018-01-01

Metal alkylidenes, which are key organometallic intermediates in reactions such as olefination or alkene and alkane metathesis, are typically generated from metal dialkyl compounds [M](CH2R)2 that show distinctively deshielded chemical shifts for their α-carbons. Experimental solid-state NMR measurements combined with DFT/ZORA calculations and a chemical shift tensor analysis reveal that this remarkable deshielding originates from an empty metal d-orbital oriented in the M–Cα–Cα′ plane, interacting with the Cα p-orbital lying in the same plane. This π-type interaction inscribes some alkylidene character into Cα that favors alkylidene generation via α-H abstraction. The extent of the deshielding and the anisotropy of the alkyl chemical shift tensors distinguishes [M](CH2R)2 compounds that form alkylidenes from those that do not, relating the reactivity to molecular orbitals of the respective molecules. The α-carbon chemical shifts and tensor orientations thus predict the reactivity of metal alkyl compounds towards alkylidene generation. PMID:29675237

Strong spin-orbit coupling and Zeeman spin splitting in angle dependent magnetoresistance of Bi{sub 2}Te{sub 3}

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dey, Rik, E-mail: rikdey@utexas.edu; Pramanik, Tanmoy; Roy, Anupam

We have studied angle dependent magnetoresistance of Bi{sub 2}Te{sub 3} thin film with field up to 9 T over 2–20 K temperatures. The perpendicular field magnetoresistance has been explained by the Hikami-Larkin-Nagaoka theory alone in a system with strong spin-orbit coupling, from which we have estimated the mean free path, the phase coherence length, and the spin-orbit relaxation time. We have obtained the out-of-plane spin-orbit relaxation time to be small and the in-plane spin-orbit relaxation time to be comparable to the momentum relaxation time. The estimation of these charge and spin transport parameters are useful for spintronics applications. For parallel field magnetoresistance,more » we have confirmed the presence of Zeeman effect which is otherwise suppressed in perpendicular field magnetoresistance due to strong spin-orbit coupling. The parallel field data have been explained using both the contributions from the Maekawa-Fukuyama localization theory for non-interacting electrons and Lee-Ramakrishnan theory of electron-electron interactions. The estimated Zeeman g-factor and the strength of Coulomb screening parameter agree well with the theory. Finally, the anisotropy in magnetoresistance with respect to angle has been described by the Hikami-Larkin-Nagaoka theory. This anisotropy can be used in anisotropic magnetic sensor applications.« less

H2MBH2 and M(μ-H)2BH2 Molecules Isolated in Solid Argon: Interelement M-B and M-H-B Bonds (M = Ge, Sn).

PubMed

Zhao, Jie; Beckers, Helmut; Huang, Tengfei; Wang, Xuefeng; Riedel, Sebastian

2018-02-19

Laser-ablated boron atoms react with GeH 4 molecules to form novel germylidene borane H 2 GeBH 2 , which undergoes a photochemical rearrangement to the germanium tetrahydroborate Ge(μ-H) 2 BH 2 upon irradiation with light of λ = 405 nm. For comparison, the boron atom reactions with SnH 4 only gave the tin tetrahydroborate Sn(μ-H) 2 BH 2 . Infrared matrix-isolation spectroscopy with deuterium substitution and the state-of-the-art quantum-chemical calculations are used to identify these species in solid argon. A planar structure of H 2 GeBH 2 with an electron-deficient B-Ge bond with a partial multiple bond character (bond order = 1.5) is predicted by quantum-chemical calculations. In the case of M(μ-H) 2 BH 2 (M = Ge, Sn) two 3c-2e B-H-M hydrogen bridged bonds are formed by donation of electrons from the B-H σ-bonds into empty p-orbitals of M.

Photoabsorption and photoionization cross sections of NH3, PH3, H2S, C2H2, and C2H4 in the VUV region

NASA Technical Reports Server (NTRS)

Xia, T. J.; Chien, T. S.; Wu, C. Y. Robert; Judge, D. L.

1991-01-01

Using synchrotron radiation as a continuum light source, the photoabsorption and photoionization cross sections of NH3, PH3, H2S, C2H2, and C2H4 have been measured from their respective ionization thresholds to 1060 A. The vibrational constants associated with the nu(2) totally symmetric, out-of-plane bending vibration of the ground electronic state of PH3(+) have been obtained. The cross sections and quantum yields for producing neutral products through photoexcitation of these molecules in the given spectral regions have also been determined. In the present work, autoionization processes were found to be less important than dissociation and predissociation processes in NH3, PH3, and C2H4. Several experimental techniques have been employed in order to examine the various possible systematic errors critically.

Orbital-2 Mission

NASA Image and Video Library

2014-07-11

The Orbital Sciences Corporation Antares rocket, with the Cygnus spacecraft onboard, is seen on launch Pad-0A, Friday, July 11, 2014, at NASA's Wallops Flight Facility in Virginia. The Antares will launch with the Cygnus spacecraft filled with over 3,000 pounds of supplies for the International Space Station, including science experiments, experiment hardware, spare parts, and crew provisions. The Orbital-2 mission is Orbital Sciences' second contracted cargo delivery flight to the space station for NASA. Photo Credit: (NASA/Bill Ingalls)

Orbital-2 Mission

NASA Image and Video Library

2014-07-12

The Orbital Sciences Corporation Antares rocket, with the Cygnus spacecraft onboard, is seen, Saturday, July 12, 2014, at launch Pad-0A of NASA's Wallops Flight Facility in Virginia. The Antares will launch with the Cygnus spacecraft filled with over 3,000 pounds of supplies for the International Space Station, including science experiments, experiment hardware, spare parts, and crew provisions. The Orbital-2 mission is Orbital Sciences' second contracted cargo delivery flight to the space station for NASA. Photo Credit: (NASA/Bill Ingalls)

Out-of-plane spin polarization of edge currents in Chern insulator with Rashba spin-orbit interaction

NASA Astrophysics Data System (ADS)

Chen, Tsung-Wei; Hsiao, Chin-Lun; Hu, Chong-Der

2016-07-01

We investigate the change in the non-zero Chern number and out-of-plane spin polarization of the edge currents in a honeycomb lattice with the Haldane-Rashba interaction. This interaction breaks the time-reversal symmetry due to the Haldane phase caused by a current loop at the site-I and site-II atoms, and also accounts for the Rashba-type spin-orbit interaction. The Rashba spin-orbit interaction increases the number of Dirac points and the band-touching phenomenon can be generated by tuning the on-site potential in the non-zero Haldane phase. By using the Pontryagin winding number and numerical Berry curvature methods, we find that the Chern number pattern is {+2, -1, 0} and {-2, +1, 0} for the positive and negative Haldane phase, respectively. A non-zero Chern number is called a Chern-insulating phase. We discovered that changes in both the Haldane phase and on-site potential leads to a change in the orientation of the bulk spin polarization of site-I and site-II atoms. Interestingly, in a ribbon with a zigzag edge, which naturally has site-I atoms at one outer edge and site-II atoms at the opposite outer edge, the spin polarization of the edge states approximately obeys the properties of bulk spin polarization regardless of the change in the Chern number. In addition, even when the Chern number changes from  +2 to  -1 (or  -2 to  +1), by tuning the strength of the on-site potential, the sign of the spin polarization of the edge states persists. This approximate bulk-edge correspondence of the spin polarization in the Haldane-Rashba system would play an important role in spintronics, because it enables us to control the orientation of the spin polarization in a single Chern-insulating phase.

Out-of-plane spin polarization of edge currents in Chern insulator with Rashba spin-orbit interaction.

PubMed

Chen, Tsung-Wei; Hsiao, Chin-Lun; Hu, Chong-Der

2016-07-13

We investigate the change in the non-zero Chern number and out-of-plane spin polarization of the edge currents in a honeycomb lattice with the Haldane-Rashba interaction. This interaction breaks the time-reversal symmetry due to the Haldane phase caused by a current loop at the site-I and site-II atoms, and also accounts for the Rashba-type spin-orbit interaction. The Rashba spin-orbit interaction increases the number of Dirac points and the band-touching phenomenon can be generated by tuning the on-site potential in the non-zero Haldane phase. By using the Pontryagin winding number and numerical Berry curvature methods, we find that the Chern number pattern is {+2, -1, 0} and {-2, +1, 0} for the positive and negative Haldane phase, respectively. A non-zero Chern number is called a Chern-insulating phase. We discovered that changes in both the Haldane phase and on-site potential leads to a change in the orientation of the bulk spin polarization of site-I and site-II atoms. Interestingly, in a ribbon with a zigzag edge, which naturally has site-I atoms at one outer edge and site-II atoms at the opposite outer edge, the spin polarization of the edge states approximately obeys the properties of bulk spin polarization regardless of the change in the Chern number. In addition, even when the Chern number changes from  +2 to  -1 (or  -2 to  +1), by tuning the strength of the on-site potential, the sign of the spin polarization of the edge states persists. This approximate bulk-edge correspondence of the spin polarization in the Haldane-Rashba system would play an important role in spintronics, because it enables us to control the orientation of the spin polarization in a single Chern-insulating phase.

Reactivity of Cyclopentadienyl Molybdenum Compounds towards Formic Acid: Structural Characterization of CpMo(PMe3)(CO)2H, CpMo(PMe3)2(CO)H, [CpMo(μ-O)(μ-O2CH)]2, and [Cp*Mo(μ-O)(μ-O2CH)]2.

PubMed

Neary, Michelle C; Parkin, Gerard

2017-02-06

The molecular structures of CpMo(PMe 3 )(CO) 2 H and CpMo(PMe 3 ) 2 (CO)H have been determined by X-ray diffraction, thereby revealing four-legged piano-stool structures in which the hydride ligand is trans to CO. However, in view of the different nature of the four basal ligands, the geometries of CpMo(PMe 3 )(CO) 2 H and CpMo(PMe 3 ) 2 (CO)H deviate from that of an idealized four-legged piano stool, such that the two ligands that are orthogonal to the trans H-Mo-CO moiety are displaced towards the hydride ligand. While Cp R Mo(PMe 3 ) 3-x (CO) x H (Cp R = Cp, Cp*; x = 1, 2, 3) are catalysts for the release of H 2 from formic acid, the carbonyl derivatives, Cp R Mo(CO) 3 H, are also observed to form dinuclear formate compounds, namely, [Cp R Mo(μ-O)(μ-O 2 CH)] 2 . The nature of the Mo···Mo interactions in [CpMo(μ-O)(μ-O 2 CH)] 2 and [Cp*Mo(μ-O)(μ-O 2 CH)] 2 have been addressed computationally. In this regard, the two highest occupied molecular orbitals of [CpMo(μ-O)(μ-O 2 CH)] 2 correspond to metal-based δ* (HOMO) and σ (HOMO-1) orbitals. The σ 2 δ* 2 configuration thus corresponds to a formal direct Mo-Mo bond order of zero. The preferential occupation of the δ* orbital rather than the δ orbital is a consequence of the interaction of the latter orbital with p orbitals of the bridging oxo ligands. In essence, lone-pair donation from oxygen increases the electron count so that the molybdenum centers can achieve an 18-electron configuration without the existence of a Mo-Mo bond, whereas a Mo═Mo double bond is required in the absence of lone-pair donation.

Requirements and capabilities for planetary missions. Volume 2: Mars polar orbiter penetrator 1981

NASA Technical Reports Server (NTRS)

Ball, G. G.; Bird, T. H.

1976-01-01

The Mars Polar Orbiter/Penetrator 1981 mission, intended to investigate the manner in which Mars has evolved, and which surveys its geochemistry, performs climatological investigations, and attempts to determine the planet's gravitational field, was described. The spacecraft, modified from the Viking Orbiter design, carries a new remote-sensing payload and six penetrators. The penetrators are released from a 2.46-h, 1000-km sun synchronous circular orbit and interrogated daily throughout the 2-year orbital mission. X-band telemetry is used to increase data return.

Pristine Basal- and Edge-Plane-Oriented Molybdenite MoS2 Exhibiting Highly Anisotropic Properties.

PubMed

Tan, Shu Min; Ambrosi, Adriano; Sofer, Zdenĕk; Huber, Štěpán; Sedmidubský, David; Pumera, Martin

2015-05-04

The layered structure of molybdenum disulfide (MoS2 ) is structurally similar to that of graphite, with individual sheets strongly covalently bonded within but held together through weak van der Waals interactions. This results in two distinct surfaces of MoS2 : basal and edge planes. The edge plane was theoretically predicted to be more electroactive than the basal plane, but evidence from direct experimental comparison is elusive. Herein, the first study comparing the two surfaces of MoS2 by using macroscopic crystals is presented. A careful investigation of the electrochemical properties of macroscopic MoS2 pristine crystals with precise control over the exposure of one plane surface, that is, basal plane or edge plane, was performed. These crystals were characterized thoroughly by AFM, Raman spectroscopy, X-ray photoelectron spectroscopy, voltammetry, digital simulation, and DFT calculations. In the Raman spectra, the basal and edge planes show anisotropy in the preferred excitation of E2g and A1g phonon modes, respectively. The edge plane exhibits a much larger heterogeneous electron transfer rate constant k(0) of 4.96×10(-5) and 1.1×10(-3)  cm s(-1) for [Fe(CN)6 ](3-/4-) and [Ru(NH3 )6 ](3+/2+) redox probes, respectively, compared to the basal plane, which yielded k(0) tending towards zero for [Fe(CN)6 ](3-/4-) and about 9.3×10(-4)  cm s(-1) for [Ru(NH3 )6 ](3+/2+) . The industrially important hydrogen evolution reaction follows the trend observed for [Fe(CN)6 ](3-/4-) in that the basal plane is basically inactive. The experimental comparison of the edge and basal planes of MoS2 crystals is supported by DFT calculations. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Near ultraviolet photodissociation spectroscopy of Mn+(H2O) and Mn+(D2O)

NASA Astrophysics Data System (ADS)

Pearson, Wright L.; Copeland, Christopher; Kocak, Abdulkadir; Sallese, Zachary; Metz, Ricardo B.

2014-11-01

The electronic spectra of Mn+(H2O) and Mn+(D2O) have been measured from 30 000 to 35 000 cm-1 using photodissociation spectroscopy. Transitions are observed from the 7A1 ground state in which the Mn+ is in a 3d54s1 electronic configuration, to the 7B2 (3d54py) and 7B1 (3d54px) excited states with T0 = 30 210 and 32 274 cm-1, respectively. Each electronic transition has partially resolved rotational and extensive vibrational structure with an extended progression in the metal-ligand stretch at a frequency of ˜450 cm-1. There are also progressions in the in-plane bend in the 7B2 state, due to vibronic coupling, and the out-of-plane bend in the 7B1 state, where the calculation illustrates that this state is slightly non-planar. Electronic structure computations at the CCSD(T)/aug-cc-pVTZ and TD-DFT B3LYP/6-311++G(3df,3pd) level are also used to characterize the ground and excited states, respectively. These calculations predict a ground state Mn-O bond length of 2.18 Å. Analysis of the experimentally observed vibrational intensities reveals that this bond length decreases by 0.15 ± 0.015 Å and 0.14 ± 0.01 Å in the excited states. The behavior is accounted for by the less repulsive px and py orbitals causing the Mn+ to interact more strongly with water in the excited states than the ground state. The result is a decrease in the Mn-O bond length, along with an increase in the H-O-H angle. The spectra have well resolved K rotational structure. Fitting this structure gives spin-rotation constants ɛaa″ = -3 ± 1 cm-1 for the ground state and ɛaa' = 0.5 ± 0.5 cm-1 and ɛaa' = -4.2 ± 0.7 cm-1 for the first and second excited states, respectively, and A' = 12.8 ± 0.7 cm-1 for the first excited state. Vibrationally mediated photodissociation studies determine the O-H antisymmetric stretching frequency in the ground electronic state to be 3658 cm-1.

Orbital-2 Mission

NASA Image and Video Library

2014-07-12

The full Moon sets in the fog behind the Orbital Sciences Corporation Antares rocket, with the Cygnus spacecraft onboard, Saturday, July 12, 2014, launch Pad-0A, NASA's Wallops Flight Facility in Virginia. The Antares will launch with the Cygnus spacecraft filled with over 3,000 pounds of supplies for the International Space Station, including science experiments, experiment hardware, spare parts, and crew provisions. The Orbital-2 mission is Orbital Sciences' second contracted cargo delivery flight to the space station for NASA. Photo Credit: (NASA/Bill Ingalls)

Orbital-2 Mission

NASA Image and Video Library

2014-07-12

The Orbital Sciences Corporation Antares rocket, with the Cygnus spacecraft onboard, is seen during sunrise, Saturday, July 12, 2014, at launch Pad-0A of NASA's Wallops Flight Facility in Virginia. The Antares will launch with the Cygnus spacecraft filled with over 3,000 pounds of supplies for the International Space Station, including science experiments, experiment hardware, spare parts, and crew provisions. The Orbital-2 mission is Orbital Sciences' second contracted cargo delivery flight to the space station for NASA. Photo Credit: (NASA/Bill Ingalls)

Activating and optimizing MoS 2 basal planes for hydrogen evolution through the formation of strained sulphur vacancies

DOE PAGES

Li, Hong; Tsai, Charlie; Koh, Ai Leen; ...

2015-11-09

As a promising non-precious catalyst for the hydrogen evolution reaction, molybdenum disulphide (MoS 2) is known to contain active edge sites and an inert basal plane. Activating the MoS 2 basal plane could further enhance its HER activity but is not often a strategy for doing so. Herein, we report the first activation and optimization of the basal plane of monolayer 2H-MoS 2 for HER by introducing sulphur (S) vacancies and strain. Our theoretical and experimental results show that the S-vacancies are new catalytic sites in the basal plane, where gap states around the Fermi level allow hydrogen to bindmore » directly to exposed Mo atoms. The hydrogen adsorption free energy (ΔG H) can be further manipulated by straining the surface with S-vacancies, which fine-tunes the catalytic activity. Furthermore, proper combinations of S-vacancy and strain yield the optimal ΔG H = 0 eV, which allows us to achieve the highest intrinsic HER activity among molybdenum-sulphide-based catalysts.« less

Analysis of direct transfer trajectories from LL2 halo orbits to LLOs

NASA Astrophysics Data System (ADS)

Cao, Pengfei; He, Boyong; Li, Haiyang

2017-09-01

A convenient procedure for designing the direct transfer trajectory from lunar L2 point (LL2) halo orbit to a low lunar orbit (LLO) is presented in this paper. The trajectory characteristics are analyzed to support the manned lunar missions design aimed at lunar surface global access. The concise procedure is established based on the circular restricted three-body problem (CR3BP) model. An analytical algorithm is employed to estimate an initial maneuver vector for approaching the Moon in its close vicinity. An iteration process is adopted to generate favorable trajectory that satisfies the constraints at perilune. By introducing a number of intermediate coordinate frames, an algorithm to compute the arriving LLO inclination and right ascension of ascending node (RAAN) is proposed. The orbital inclination and RAAN in this paper are defined and established in the J2000 frame rather than in the synodical frame. Numerical results show that, regardless of value of out-of-plane amplitude (Az) of the halo orbit, the overall maneuver cost of the trajectory largely depends on departure position, and it has two minima around 0.65 km/s. Further study shows that the values of the arriving LLO inclination and RAAN largely depend on the choices of the departure time and the value of Az. The periodicity, due to the natural motion of the Moon, is discovered to play a role in this time dependency. It is concluded that the fuel optimal trajectory permits access to almost any final lunar orbit, including a polar orbit, by means of varying the departure time and Az value.

Reactivity of cyclopentadienyl molybdenum compounds towards formic acid: Structural characterization of CpMo(PMe 3)(CO) 2H, CpMo(PMe 3) 2(CO)H, [CpMo(μ-O)(μ-O 2CH)] 2, and [Cp*Mo(μ-O)(μ-O 2CH)] 2

DOE Office of Scientific and Technical Information (OSTI.GOV)

Neary, Michelle C.; Parkin, Gerard

Here, the molecular structures of CpMo(PMe 3)(CO) 2H and CpMo(PMe 3) 2(CO)H have been determined by X-ray diffraction, thereby revealing four-legged piano-stool structures in which the hydride ligand is trans to CO. However, in view of the different nature of the four basal ligands, the geometries of CpMo(PMe 3)(CO) 2H and CpMo(PMe 3) 2(CO)H deviate from that of an idealized four-legged piano stool, such that the two ligands that are orthogonal to the trans H–Mo–CO moiety are displaced towards the hydride ligand. While CpRMo(PMe 3) 3–x(CO) xH (Cp R = Cp, Cp*; x = 1, 2, 3) are catalysts formore » the release of H 2 from formic acid, the carbonyl derivatives, CpRMo(CO)3H, are also observed to form dinuclear formate compounds, namely, [Cp RMo(μ-O)(μ-O 2CH)] 2. The nature of the Mo···Mo interactions in [CpMo(μ-O)(μ-O 2CH)] 2 and [Cp*Mo(μ-O)(μ-O 2CH)] 2 have been addressed computationally. In this regard, the two highest occupied molecular orbitals of [CpMo(μ-O)(μ-O 2CH)] 2 correspond to metal-based δ* (HOMO) and σ (HOMO–1) orbitals. The σ 2δ *2 configuration thus corresponds to a formal direct Mo–Mo bond order of zero. The preferential occupation of the δ* orbital rather than the δ orbital is a consequence of the interaction of the latter orbital with p orbitals of the bridging oxo ligands. In essence, lone-pair donation from oxygen increases the electron count so that the molybdenum centers can achieve an 18-electron configuration without the existence of a Mo–Mo bond, whereas a Mo=Mo double bond is required in the absence of lone-pair donation.« less

Reactivity of cyclopentadienyl molybdenum compounds towards formic acid: Structural characterization of CpMo(PMe 3)(CO) 2H, CpMo(PMe 3) 2(CO)H, [CpMo(μ-O)(μ-O 2CH)] 2, and [Cp*Mo(μ-O)(μ-O 2CH)] 2

DOE PAGES

Neary, Michelle C.; Parkin, Gerard

2017-01-19

Here, the molecular structures of CpMo(PMe 3)(CO) 2H and CpMo(PMe 3) 2(CO)H have been determined by X-ray diffraction, thereby revealing four-legged piano-stool structures in which the hydride ligand is trans to CO. However, in view of the different nature of the four basal ligands, the geometries of CpMo(PMe 3)(CO) 2H and CpMo(PMe 3) 2(CO)H deviate from that of an idealized four-legged piano stool, such that the two ligands that are orthogonal to the trans H–Mo–CO moiety are displaced towards the hydride ligand. While CpRMo(PMe 3) 3–x(CO) xH (Cp R = Cp, Cp*; x = 1, 2, 3) are catalysts formore » the release of H 2 from formic acid, the carbonyl derivatives, CpRMo(CO)3H, are also observed to form dinuclear formate compounds, namely, [Cp RMo(μ-O)(μ-O 2CH)] 2. The nature of the Mo···Mo interactions in [CpMo(μ-O)(μ-O 2CH)] 2 and [Cp*Mo(μ-O)(μ-O 2CH)] 2 have been addressed computationally. In this regard, the two highest occupied molecular orbitals of [CpMo(μ-O)(μ-O 2CH)] 2 correspond to metal-based δ* (HOMO) and σ (HOMO–1) orbitals. The σ 2δ *2 configuration thus corresponds to a formal direct Mo–Mo bond order of zero. The preferential occupation of the δ* orbital rather than the δ orbital is a consequence of the interaction of the latter orbital with p orbitals of the bridging oxo ligands. In essence, lone-pair donation from oxygen increases the electron count so that the molybdenum centers can achieve an 18-electron configuration without the existence of a Mo–Mo bond, whereas a Mo=Mo double bond is required in the absence of lone-pair donation.« less

Catalyst Bed Instability Within the USFE H2O2/JP-8 Rocket Engine

NASA Technical Reports Server (NTRS)

Johnson, Curtis W.; Anderson, William; Ross, Robert; Lyles, G. (Technical Monitor)

2000-01-01

Orbital Sciences Corporation has been awarded a contract by NASA's Marshall Space Flight Center, in cooperation with the U.S. Air Force Research Laboratory's Military Space Plane Technology Program Office, for the Upper Stage Flight Experiment (USFE) program. Orbital is designing, developing, and will flight test a new low-cost, 10,000 lbf hydrogen peroxide/ JP-8 pressure fed liquid rocket. During combustion chamber tests at NASA Stennis Space Center (SSC) of the USFE engine, the catalyst bed showed a low frequency instability occurring as the H202 flow reached about 1/3 its design rate. This paper reviews the USFE catalyst bed and combustion chamber and its operation, then discusses the dynamics of the instability. Next the paper describes the dynamic computer model used to recreate the instability. The model was correlated to the SSC test data, and used to investigate possible solutions to the problem. The combustion chamber configuration which solved the instability is shown, and the subsequent stable operation presented.

Mars Geoscience Climatology Orbiter (MGCO) extended study: Technical volume

NASA Technical Reports Server (NTRS)

1983-01-01

The FLTSATCOM Earth orbiting communications satellite is a prominent candidate to serve as the Mars Geoscience Climatology Orbiter (MGCO) spacecraft. Major aspects directly applicable are: (1) the incorporation of solid orbit insertion motor; (2) the ability to cruise to Mars in the spin-stabilized mode; (3) ample capability for payload mass and power; (4) attitude control tried to nadir and orbit plane coordinates; (5) exemplary Earth orbital performance record and projected lifetime; and (6) existence of an on-going procurement into the MGCO time period.

Origin of the orbital architecture of the giant planets of the Solar System.

PubMed

Tsiganis, K; Gomes, R; Morbidelli, A; Levison, H F

2005-05-26

Planetary formation theories suggest that the giant planets formed on circular and coplanar orbits. The eccentricities of Jupiter, Saturn and Uranus, however, reach values of 6 per cent, 9 per cent and 8 per cent, respectively. In addition, the inclinations of the orbital planes of Saturn, Uranus and Neptune take maximum values of approximately 2 degrees with respect to the mean orbital plane of Jupiter. Existing models for the excitation of the eccentricity of extrasolar giant planets have not been successfully applied to the Solar System. Here we show that a planetary system with initial quasi-circular, coplanar orbits would have evolved to the current orbital configuration, provided that Jupiter and Saturn crossed their 1:2 orbital resonance. We show that this resonance crossing could have occurred as the giant planets migrated owing to their interaction with a disk of planetesimals. Our model reproduces all the important characteristics of the giant planets' orbits, namely their final semimajor axes, eccentricities and mutual inclinations.

Passage through the Ring Plane

NASA Image and Video Library

2004-06-03

The path that lies ahead for the Cassini-Huygens mission is indicated in this image which illustrates where the spacecraft will be just 27 days from now, when it arrives at Saturn and crosses the ring plane 33 minutes before performing its critical orbital insertion maneuver. The X indicates the point where Cassini will pierce the ring plane on June 30, 2004, going from south to north of the ring plane, 33 minutes before the main engine fires to begin orbital insertion. The indicated point is between the narrow F-ring on the left and Saturn's tenuous G-ring which is too faint to be seen in this exposure. The image was taken on May 11, 2004 when the spacecraft was 26.3 million kilometers (16.3 million miles) from Saturn. Image scale is 158 kilometers (98 miles) per pixel. Moons visible in this image: Janus (181 kilometers or 113 miles across), one of the co-orbital moons; Pandora (84 kilometers or 52 miles across), one of the F ring shepherding moons; and Enceladus (499 kilometers or 310 miles across), a moon which may be heated from within and thus have a liquid sub-surface ocean. http://photojournal.jpl.nasa.gov/catalog/PIA06061

Orbital electronic occupation effect on metal-insulator transition in Ti x V1-x O2.

PubMed

Huang, Kang; Meng, Yifan; Xu, XiaoFeng; Chen, Pingping; Lu, Aijiang; Li, Hui; Wu, Binhe; Wang, Chunrui; Chen, Xiaoshuang

2017-09-06

A series of Ti x V 1-x O 2 (0%  ⩽  x  ⩽  4.48%) thin films on c-plane sapphire substrates have been fabricated by co-sputtering oxidation solutions, and the metal-insulator transition temperature (T MIT ) of Ti x V 1-x O 2 films rises monotonically at the rate of 1.64 K/at.% Ti. The x-ray diffraction measurement results show that, after Ti 4+ ion doping, the rutile structure expands along the c r axis while shrinking along the a r and b r axis simultaneously. It makes the V-O bond length shorter, which is believed to upshift the π * orbitals. The rising of π * orbitals in Ti-doped VO 2 has been illustrated by ultraviolet-infrared spectroscopy and first-principles calculation. With the Ti 4+ ion doping concentration increasing, the energy levels of π * orbitals are elevated and the electronic occupation of π * orbitals decreases, which weakens the shielding for the strong electron-electron correlations in the d || orbital and result in the T MIT rising. The research reveals that the T MIT of VO 2 can be effected by the electronic occupancy of π * orbitals in a rutile state, which is helpful for developing VO 2 -based thermal devices.

Electrochemical generation of sulfur vacancies in the basal plane of MoS2 for hydrogen evolution

PubMed Central

Tsai, Charlie; Li, Hong; Park, Sangwook; Park, Joonsuk; Han, Hyun Soo; Nørskov, Jens K.; Zheng, Xiaolin; Abild-Pedersen, Frank

2017-01-01

Recently, sulfur (S)-vacancies created on the basal plane of 2H-molybdenum disulfide (MoS2) using argon plasma exposure exhibited higher intrinsic activity for the electrochemical hydrogen evolution reaction than the edge sites and metallic 1T-phase of MoS2 catalysts. However, a more industrially viable alternative to the argon plasma desulfurization process is needed. In this work, we introduce a scalable route towards generating S-vacancies on the MoS2 basal plane using electrochemical desulfurization. Even though sulfur atoms on the basal plane are known to be stable and inert, we find that they can be electrochemically reduced under accessible applied potentials. This can be done on various 2H-MoS2 nanostructures. By changing the applied desulfurization potential, the extent of desulfurization and the resulting activity can be varied. The resulting active sites are stable under extended desulfurization durations and show consistent HER activity. PMID:28429782

Electrochemical generation of sulfur vacancies in the basal plane of MoS2 for hydrogen evolution

DOE PAGES

Tsai, Charlie; Li, Hong; Park, Sangwook; ...

2017-04-21

Recently, sulfur (S)-vacancies created on the basal plane of 2H-molybdenum disulfide (MoS 2) using argon plasma exposure exhibited higher intrinsic activity for the electrochemical hydrogen evolution reaction than the edge sites and metallic 1T-phase of MoS 2 catalysts. But, a more industrially viable alternative to the argon plasma desulfurization process is needed. In this work, we introduce a scalable route towards generating S-vacancies on the MoS 2 basal plane using electrochemical desulfurization. We found that they can be electrochemically reduced under accessible applied potentials, even though sulfur atoms on the basal plane are known to be stable and inert. Thismore » can be done on various 2H-MoS 2 nanostructures. Furthermore, by changing the applied desulfurization potential, the extent of desulfurization and the resulting activity can be varied. The resulting active sites are stable under extended desulfurization durations and show consistent HER activity.« less

Orbital-plane precessional resonances for binary black-hole systems

NASA Astrophysics Data System (ADS)

Kesden, Michael; Zhao, Xinyu; Gerosa, Davide

2016-03-01

We derive a new class of post-Newtonian precessional resonances for binary black holes (BBHs) with misaligned spins. According to the orbit-averaged spin-precession equations, the angle between the orbital angular momentum L and the total angular momentum J oscillates with a period τ during which time L precesses about J by an angle α. If α is a rational multiple of 2 π, the precession of L will be closed indicating a resonance between the polar and azimuthal evolution of L . If α is an integer multiple of 2 π, the misalignment between the angular momentum ΔL radiated over the period τ and J will be minimized, as will the opening angle of the cone about which J precesses in an inertial frame. However, the direction of ΔL will remain nearly fixed in an inertial frame over many precessional periods, causing the direction of J to tilt as inspiraling BBHs pass through such a resonance. Generic BBHs encounter many such resonances during an inspiral from large separations. We derive the evolution of J near a resonance and assess their detectability by gravitational-wave detectors and astrophysical implications.

Interface-induced perpendicular magnetic anisotropy of Co nanoparticles on single-layer h-BN/Pt(111)

NASA Astrophysics Data System (ADS)

Watanabe, Takahiro; Yamada, Yoichi; Koide, Akihiro; Entani, Shiro; Li, Songtian; Popov, Zakhar I.; Sorokin, Pavel B.; Naramoto, Hiroshi; Sasaki, Masahiro; Amemiya, Kenta; Sakai, Seiji

2018-01-01

Ferromagnetism with perpendicular magnetic anisotropy (PMA) was observed at room temperature in cobalt nanoparticles (NPs) grown on hexagonal boron nitride (h-BN) on a Pt(111) surface. It was shown that the Co NPs have planar hexagonal shapes with a mean diameter of ˜20 nm and a mean height of ˜1.6 nm. The depth-resolved analysis of X-ray magnetic circular dichroism at the Co L2,3-edges revealed that in the ferromagnetic Co NPs, the ratio of the orbital magnetic moment to the spin magnetic moment in the out-of-plane direction becomes larger at the Co NP/h-BN interface than the ratio in bulk Co. The B and N K-edge near edge X-ray absorption fine structures showed the orbital hybridization between the π orbitals of h-BN and d orbitals of Co at the interface, as an origin of the orbital magnetic moment enhancement possibly giving rise to PMA in the Co NPs.

Accurate potential energy functions, non-adiabatic and spin-orbit couplings in the ZnH(+) system.

PubMed

Liang, Guiying; Liu, Xiaoting; Zhang, Xiaomei; Xu, Haifeng; Yan, Bing

2016-03-05

A high-level ab initio calculation on the ZnH(+) cation has been carried out with the multi-reference configuration interaction method plus Davison correction (MRCI+Q). The scalar relativistic effect is included by using the Douglas-Kroll-Hess (DKH) method. The calculated potential energy curves (PECs) of the 7 Λ-S states are associated with the dissociation limits of Zn(+)((2)Sg)+H((2)Sg), Zn((1)Sg)+H(+)((1)Sg), and Zn(+)((2)Pu)+H((2)Sg), respectively (The Λ-S state is labeled as (2S+1)Λ, in which Λ is the quantum number for the projection along the internuclear axis of the total electronic orbital angular momentum and S is the total electron spin). The spectroscopic constants of the bound states are determined and in good agreement with the available theoretical and experimental results. The permanent dipole moments (PDMs) of Λ-S states and the spin-orbit (SO) matrix elements between Λ-S states are also computed. The results show that the abrupt changes of the PDMs and SO matrix elements come into being for the reason of the avoided crossing between the states with the same symmetry. In addition, the non-adiabatic couplings matrix elements between Λ-S states are also evaluated. Finally, the spin-orbit couplings (SOCs) for the low-lying states are considered with Breit-Pauli operator. The SOC effect makes the 7 Λ-S states of the ZnH(+) cation split into 12 Ω states (Ω=Λ+Sz, in which Sz is projection of the total electron spin S along the internuclear Z-axis). For the (3)0(+) state, the two energy minima exhibit in the potential, which could be attributed to the formation of the new avoided crossing point. The transition dipole moments (TDMs), Franck-Condon factors, and the radiative lifetimes of the selected transitions (2)0(+)-X0(+), (3)0(+)-X0(+), (2)1-X0(+) and (3)1-X0(+) have been reported. Copyright © 2015 Elsevier B.V. All rights reserved.

2-({4-[4-(1H-Benzimidazol-2-yl)phen­yl]-1H-1,2,3-triazol-1-yl}meth­oxy)ethanol

PubMed Central

Ouahrouch, Abdelaaziz; Taourirte, Moha; Lazrek, Hassan B.; Bats, Jan W.; Engels, Joachim W.

2012-01-01

In the title molecule, C18H17N5O2, the dihedral angle between the benzene plane and the benzimidazole plane is 19.8 (1)° and the angle between the benzene plane and the triazole plane is 16.7 (1)°. In the crystal, mol­ecules are connected by O—H⋯N hydrogen bonds, forming zigzag chains along the c-axis direction. The chains are connected by bifurcated N—H⋯(N,N) hydrogen bonds into layers parallel to (100). These layers are connected along the a-axis direction by weak C—H⋯O contacts, forming a three-dimensional network. PMID:22719663

Electronic structure differences between H(2)-, Fe-, Co-, and Cu-phthalocyanine highly oriented thin films observed using NEXAFS spectroscopy.

PubMed

Willey, T M; Bagge-Hansen, M; Lee, J R I; Call, R; Landt, L; van Buuren, T; Colesniuc, C; Monton, C; Valmianski, I; Schuller, Ivan K

2013-07-21

Phthalocyanines, a class of macrocyclic, square planar molecules, are extensively studied as semiconductor materials for chemical sensors, dye-sensitized solar cells, and other applications. In this study, we use angular dependent near-edge x-ray absorption fine structure (NEXAFS) spectroscopy as a quantitative probe of the orientation and electronic structure of H2-, Fe-, Co-, and Cu-phthalocyanine molecular thin films. NEXAFS measurements at both the carbon and nitrogen K-edges reveal that phthalocyanine films deposited on sapphire have upright molecular orientations, while films up to 50 nm thick deposited on gold substrates contain prostrate molecules. Although great similarity is observed in the carbon and nitrogen K-edge NEXAFS spectra recorded for the films composed of prostrate molecules, the H2-phthalocyanine exhibits the cleanest angular dependence due to its purely out-of-plane π* resonances at the absorption onset. In contrast, organometallic-phthalocyanine nitrogen K-edges have a small in-plane resonance superimposed on this π* region that is due to a transition into molecular orbitals interacting with the 3dx(2)-y(2) empty state. NEXAFS spectra recorded at the metal L-edges for the prostrate films reveal dramatic variations in the angular dependence of specific resonances for the Cu-phthalocyanines compared with the Fe-, and Co-phthalocyanines. The Cu L3,2 edge exhibits a strong in-plane resonance, attributed to its b1g empty state with dx(2)-y(2) character at the Cu center. Conversely, the Fe- and Co- phthalocyanine L3,2 edges have strong out-of-plane resonances; these are attributed to transitions into not only b1g (dz(2)) but also eg states with dxz and dyz character at the metal center.

Computational study of red- and blue-shifted Csbnd H⋯Se hydrogen bond in Q3Csbnd H⋯SeH2 (Q = Cl, F, H) complexes

NASA Astrophysics Data System (ADS)

Chopra, Pragya; Chakraborty, Shamik

2018-01-01

This work presents Csbnd H⋯Se hydrogen bonding interaction at the MP2 level of theory. The system Q3Csbnd H⋯SeH2 (Q = Cl, F, and H) provides an opportunity to investigate red- and blue-shifted hydrogen bonds. The origin of the red- and blue-shift in Csbnd H stretching frequency has been investigated using Natural Bond Orbital analysis. A large amount of electron density is being transferred to the σ∗Csbnd H orbital in red-shifted Cl3Csbnd H⋯SeH2. Electron density transfer in the blue-shifted F3Csbnd H⋯SeH2 is primarily to the remote fluorine atoms. Further, due to polarization of the Csbnd H bond, the contradicting effects of rehybridization and hyperconjugation are important. The extent of hyperconjugation reigns predominant in explaining the nature of the Csbnd H⋯Se hydrogen bond in Q3Csbnd H⋯SeH2 complexes as the hydrogen bond acceptor remain same in this investigation. Red- and blue-shift in Q3Csbnd H⋯SeH2 (Q = Cl and F) complexes is best described by pro-improper hydrogen bond donor concept.

Co3(PO4)2·4H2O

PubMed Central

Lee, Young Hoon; Clegg, Jack K.; Lindoy, Leonard F.; Lu, G. Q. Max; Park, Yu-Chul; Kim, Yang

2008-01-01

Single crystals of Co3(PO4)2·4H2O, tricobalt(II) bis­[ortho­phosphate(V)] tetra­hydrate, were obtained under hydro­thermal conditions. The title compound is isotypic with its zinc analogue Zn3(PO4)2·4H2O (mineral name hopeite) and contains two independent Co2+ cations. One Co2+ cation exhibits a slightly distorted tetra­hedral coordination, while the second, located on a mirror plane, has a distorted octa­hedral coordination environment. The tetra­hedrally coordinated Co2+ is bonded to four O atoms of four PO4 3− anions, whereas the six-coordinate Co2+ is cis-bonded to two phosphate groups and to four O atoms of four water mol­ecules (two of which are located on mirror planes), forming a framework structure. In addition, hydrogen bonds of the type O—H⋯O are present throughout the crystal structure. PMID:21200978

Raman scattering studies of the orbital, magnetic, and conducting phases in double layer ruthenates

NASA Astrophysics Data System (ADS)

Karpus, John Francis

In this dissertation, light scattering techniques are used to probe the exotic orbital, magnetic, and conducting phases of the double layer ruthenate, Ca3Ru2O7, as functions of temperature, applied pressure, and applied magnetic field. These phases result from a rich interplay between the orbital, spin, and electronic degrees of freedom in such a strongly coupled system as Ca3Ru2O7. The Raman-active phonon and magnon excitations in Ca3Ru2O7 convey sufficient information to map out the orbital, magnetic, and conducting (H, T) and (P, T) phase diagrams of this material. This study finds that quasihydrostatic pressure causes a linear suppression of the orbital-ordering temperature (TOO = 48 K at P = 0), up to a T = 0 critical point near P* ˜ 55 kbar, above which the material is in a metallic, orbital-degenerate phase. This pressure-induced collapse of the antiferromagnetic orbital-ordered phase is associated with a suppression of the RuO6 octahedral distortions that are responsible for orbital-ordering. It is also shown that an applied magnetic field at low temperatures induces a change from an orbital-ordered to an orbital-degenerate phase for fields aligned along the in-plane hard-axis, but induces a reentrant orbital-ordered to orbital-disordered to orbital-ordered phase change for fields aligned along the in-plane easy-axis. This complex magnetic field dependence betrays the importance of the spin-orbit coupling in this system, which makes the field-induced phase behavior highly sensitive to both the applied magnetic field magnitude and direction. It is further shown that rapid field-induced changes in the structure and orbital populations are responsible for the highly field-tunable conducting properties of Ca3Ru2O7, and that the most dramatic magneto-conductivities are associated with an "orbital disordered" phase regime in which there is a random mixture of a- and b-axis oriented Ru moments and d-orbital populations on the Ru ions. Dilute La doping in Ca3Ru2O7

Kinetic Energy Distribution of H(2p) Atoms from Dissociative Excitation of H2

NASA Technical Reports Server (NTRS)

Ajello, Joseph M.; Ahmed, Syed M.; Kanik, Isik; Multari, Rosalie

1995-01-01

The kinetic energy distribution of H(2p) atoms resulting from electron impact dissociation of H2 has been measured for the first time with uv spectroscopy. A high resolution uv spectrometer was used for the measurement of the H Lyman-alpha emission line profiles at 20 and 100 eV electron impact energies. Analysis of the deconvolved 100 eV line profile reveals the existence of a narrow line peak and a broad pedestal base. Slow H(2p) atoms with peak energy near 80 meV produce the peak profile, which is nearly independent of impact energy. The wings of H Lyman-alpha arise from dissociative excitation of a series of doubly excited Q(sub 1) and Q(sub 2) states, which define the core orbitals. The fast atom energy distribution peaks at 4 eV.

Quantum Anomalous Hall Effect in Low-buckled Honeycomb Lattice with In-plane Magnetization

NASA Astrophysics Data System (ADS)

Ren, Yafei; Pan, Hui; Yang, Fei; Li, Xin; Qiao, Zhenhua; Zhenhua Qiao's Group Team; Hui Pan's Group Team

With out-of-plane magnetization, the quantum anomalous Hall effect has been extensively studied in quantum wells and two-dimensional atomic crystal layers. Here, we investigate the possibility of realizing quantum anomalous Hall effect (QAHE) in honeycomb lattices with in-plane magnetization. We show that the QAHE can only occur in low-buckled honeycomb lattice where both intrinsic and intrinsic Rashba spin-orbit coupling appear spontaneously. The extrinsic Rashba spin-orbit coupling is detrimental to this phase. In contrast to the out-of-plane magnetization induced QAHE, the QAHE from in-plane magnetization is achieved in the vicinity of the time reversal symmetric momenta at M points rather than Dirac points. In monolayer case, the QAHE can be characterized by Chern number  = +/- 1 whereas additional phases with Chern number  = +/- 2 appear in chiral stacked bilayer system. The Chern number strongly depends on the orientation of the magnetization. The bilayer system also provides additional tunability via out-of-plane electric field, which can reduce the critical magnetization strength required to induce QAHE. It can also lead to topological phase transitions from  = +/- 2 to +/- 1 and finally to 0 Equal contribution from Yafei Ren and Hui Pan.

Analytically reduced form for the class of integrals containing multicenter products of 1s hydrogenic orbitals, Coulomb or Yukawa potentials, and plane waves

NASA Technical Reports Server (NTRS)

Straton, Jack C.

1989-01-01

The class of integrals containing the product of N 1s hydrogenic orbitals and M Coulomb or Yukawa potentials with m plane waves is investigated analytically. The results obtained by Straton (1989) are extended and generalized. It is shown that the dimensionality of the entire class can be reduced from 3m to M+N-1.

On orbital stability of planar oscillations of a satellite in a circular orbit on the boundary of the parametric resonance

NASA Astrophysics Data System (ADS)

Bardin, B. S.; Chekina, E. A.

2018-05-01

We consider the motion of a satellite about its center of mass in a circular orbit. We study the problem of orbital stability for planar pendulum-like oscillations of the satellite. It is supposed that the satellite is a rigid body whose mass geometry is that of a plate. For the unperturbed motion the plane of the satellite-plate is perpendicular to the plane of the orbit. We perform a nonlinear analysis of the orbital stability of planar pendulum-like oscillations for previously unexplored parameter values corresponding to the combination resonance. It appears that in this case both formal orbital stability and instability can take place. The results of stability study are shown in stability diagrams.

The Solar Orbiter Heliospheric Imager (SoloHI) for the Solar Orbiter Mission

NASA Astrophysics Data System (ADS)

Howard, R.; Colaninno, R. C.; Plunkett, S. P.; Thernisien, A. F.; Wang, D.; Rich, N.; Korendyke, C.; Socker, D. G.; Linton, M.; McMullin, D. R.; Vourlidas, A.; Liewer, P. C.; De Jong, E.; Velli, M.; Mikic, Z.; Bothmer, V.; Philippe, L.; Carter, M. T.

2017-12-01

The SoloHI instrument has completed its development effort and has been integrated onto the Solar Orbiter (SolO) spacecraft. The SolO mission, scheduled for launch in February 2019, will undergo gravity assist maneuvers around Venus to change both the perihelion distance as well as the plane of the orbit to ultimately achieve a minimum perihelion of 0.28 AU and an orbital inclination of about 35° relative to the ecliptic plane. The remote sensing instruments will operate for three 10-day periods out of the nominal 6-month orbit. SoloHI will observe sunlight scattered by free electrons in the corona/solar wind from 5° to 45° elongation in visible wavelengths and will provide a coupling between remote sensing and in situ observations. It is very similar to the HI-1 instrument on STEREO/SECCHI except that the FOV is twice the size at 40o. We present our efforts to prepare for the mission including our observing plans, quick-look plans and some results of the calibration activities. We gratefully acknowledge the support of the NASA Solar Orbiter Collaboration project.

Analysis of HY2A precise orbit determination using DORIS

NASA Astrophysics Data System (ADS)

Gao, Fan; Peng, Bibo; Zhang, Yu; Evariste, Ngatchou Heutchi; Liu, Jihua; Wang, Xiaohui; Zhong, Min; Lin, Mingsen; Wang, Nazi; Chen, Runjing; Xu, Houze

2015-03-01

HY2A is the first Chinese marine dynamic environment satellite. The payloads include a radar altimeter to measure the sea surface height in combination with a high precision orbit to be determined from tracking data. Onboard satellite tracking includes GPS, SLR, and the DORIS DGXX receiver which delivers phase and pseudo-range measurements. CNES releases raw phase and pseudo-range measurements with RINEX DORIS 3.0 format and pre-processed Doppler range-rate with DORIS 2.2 data format. However, the VMSI software package developed by Van Martin Systems, Inc which is used to estimate HY2A DORIS orbits can only process Doppler range-rate but not the DORIS phase data which are available with much shorter latency. We have proposed a method of constructing the phase increment data, which are similar to range-rate data, from RINEX DORIS 3.0 phase data. We compute the HY2A orbits from June, 2013 to August, 2013 using the POD strategy described in this paper based on DORIS 2.2 range-rate data and our reconstructed phase increment data. The estimated orbits are evaluated by comparing with the CNES precise orbits and SLR residuals. Our DORIS-only orbits agree with the precise GPS + SLR + DORIS CNES orbits radially at 1-cm and about 3-cm in the other two directions. SLR test with the 50° cutoff elevation shows that the CNES orbit can achieve about 1.1-cm accuracy in radial direction and our DORIS-only POD solutions are slightly worse. In addition, other HY2A DORIS POD concerns are discussed in this paper. Firstly, we discuss the frequency offset values provided with the RINEX data and find that orbit accuracy for the case when the frequency offset is applied is worse than when it is not applied. Secondly, HY2A DORIS antenna z-offsets are estimated using two kinds of measurements from June, 2013 to August, 2013. The results show that the measurement errors contribute a total of about 2-cm difference of estimated z-offset. Finally, we estimate HY2A orbits selecting 3 days with

Characterizing K2 Planetary Systems Orbiting Cool Dwarfs

NASA Astrophysics Data System (ADS)

Dressing, Courtney D.; Newton, Elisabeth R.; Schlieder, Joshua; Vanderburg, Andrew; Charbonneau, David; Knutson, Heather; K2C2

2017-01-01

The NASA K2 mission is using the repurposed Kepler spacecraft to search for transiting planets in multiple fields along the ecliptic plane. K2 observes 10,000 - 30,000 stars in each field for roughly 80 days, which is too short to observe multiple transits of planets in the habitable zones of Sun-like stars, but long enough to detect potentially habitable planets orbiting low-mass dwarfs. Accordingly, M and K dwarfs are frequently nominated as K2 Guest Observer targets and K2 has already observed significantly more low-mass stars than the original Kepler mission. While the K2 data are therefore an enticing resource for studying the properties and frequency of planetary systems orbiting low-mass stars, many K2 cool dwarfs are not well-characterized. We are refining the properties of K2 planetary systems orbiting cool dwarfs by acquiring medium-resolution NIR spectra with SpeX on the IRTF and TripleSpec on the Palomar 200". In our initial sample of 144 potential cool dwarfs hosting candidate planetary systems detected by K2, we noted a high contamination rate from giants (16%) and reddened hotter dwarfs (31%). After employing empirically-based relations to determine the temperatures, radii, masses, luminosities, and metallicities of K2 planet candidate host stars, we found that our new cool dwarf radius estimates were 10-40% larger than the initial values, indicating that the radii of the associated planet candidates were also underestimated. Refining the stellar parameters allows us to identify astrophysical false positives and better constrain the radii and insolation flux environments of bona fide transiting planets. I will present our resulting catalog of system properties and highlight the most attractive K2 planets for radial velocity mass measurement and atmospheric characterization with Spitzer, HST, JWST, and the next generation of extremely large ground- and space-based telescopes. We gratefully acknowledge funding from the NASA Sagan Fellowship Program

Hierarchical Li1.2 Ni0.2 Mn0.6 O2 nanoplates with exposed {010} planes as high-performance cathode material for lithium-ion batteries.

PubMed

Chen, Lai; Su, Yuefeng; Chen, Shi; Li, Ning; Bao, Liying; Li, Weikang; Wang, Zhao; Wang, Meng; Wu, Feng

2014-10-22

Hierarchical Li1.2 Ni0.2 Mn0.6 O2 nanoplates with exposed {010} planes are designed and synthesized. In combination with the advantages from the hierarchical archi-tecture and the exposed electrochemically active {010} planes of layered materials, this material satisfies both efficient ion and electron transport and thus shows superior rate capability and excellent cycling stability. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Searching for orbits around the triple system 45 Eugenia

NASA Astrophysics Data System (ADS)

Mescolotti, B. Y. P. M.; Prado, A. F. B. A.; Chiaradia, A. P. M.; Gomes, V. M.

2017-10-01

Asteroids are small bodies that raises high interest, because they have unknown characteristics. The present research aims to study orbits for a spacecraft around the triple asteroid 45 Eugenia. The quality of the observations made by the spacecraft depends on the distance the spacecraft remains from the bodies of the system. It is used a semi-analytical model that is simple but able to represent the main characteristics of that system. This model is called “Precessing Inclined Bi-Elliptical Problem” (PIBEP). A reference system centered on the main body (Eugenia) and with the reference plane assumed to be in the orbital plane of the second more massive body, here called Petit-Prince, is used. The secondary bodies are assumed to be in elliptical orbits. In addition, it is assumed that the orbits of the smaller bodies are precessing due to the presence of the flattening of the main body (J2). This work analyzes orbits for the spacecraft with passages near Petit-Prince and Princesses, which are the two smaller bodies of the triple system.

The INTELSAT Experience with Reconditioning of NiH2 Batteries

NASA Technical Reports Server (NTRS)

Scalici, Frank; Dunnet, Andrew; Xu, Daphne

1997-01-01

INTELSAT has been reconditioning NiH2 batteries since 1983 when the INTELSAT V F-6 geosynchronous communications satellite was launched. This was the first commercial use of NiH2 batteries. INTELSAT has continued this practice on all 46 NiH2 batteries it has operated in-orbit. The batteries are of several types including the classic INTELSAT cell, the HAC re-circulating design, and the Gates Mantech design. Reconditioning is performed twice each year, prior to the Eclipse Season. At this time Water Migration problems, if present, are dealt with. Temperature limits are imposed for the discharge and charge cycles as a safety precaution. In support of in-orbit operations, it is INTELSAT's practice to perform ground based life tests. In-orbit data and ground tests results are presented and the benefits of reconditioning noted.

Dual-Native Vacancy Activated Basal Plane and Conductivity of MoSe2 with High-Efficiency Hydrogen Evolution Reaction.

PubMed

Gao, Daqiang; Xia, Baorui; Wang, Yanyan; Xiao, Wen; Xi, Pinxian; Xue, Desheng; Ding, Jun

2018-04-01

Although transition metal dichalcogenide MoSe 2 is recognized as one of the low-cost and efficient electrocatalysts for the hydrogen evolution reaction (HER), its thermodynamically stable basal plane and semiconducting property still hamper the electrocatalytic activity. Here, it is demonstrated that the basal plane and edges of 2H-MoSe 2 toward HER can be activated by introducing dual-native vacancy. The first-principle calculations indicate that both the Se and Mo vacancies together activate the electrocatalytic sites in the basal plane and edges of MoSe 2 with the optimal hydrogen adsorption free energy (ΔG H* ) of 0 eV. Experimentally, 2D MoSe 2 nanosheet arrays with a large amount of dual-native vacancies are fabricated as a catalytic working electrode, which possesses an overpotential of 126 mV at a current density of 100 mV cm -2 , a Tafel slope of 38 mV dec -1 , and an excellent long-term durability. The findings pave a rational pathway to trigger the activity of inert MoSe 2 toward HER and also can be extended to other layered dichalcogenide. © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Electronic properties of in-plane phase engineered 1T'/2H/1T' MoS2

NASA Astrophysics Data System (ADS)

Thakur, Rajesh; Sharma, Munish; Ahluwalia, P. K.; Sharma, Raman

2018-04-01

We present the first principles studies of semi-infinite phase engineered MoS2 along zigzag direction. The semiconducting (2H) and semi-metallic (1T') phases are known to be stable in thin-film MoS2. We described the electronic and structural properties of the infinite array of 1T'/2H/1T'. It has been found that 1T'phase induced semi-metallic character in 2H phase beyond interface but, only Mo atoms in 2H phase domain contribute to the semi-metallic nature and S atoms towards semiconducting state. 1T'/2H/1T' system can act as a typical n-p-n structure. Also high holes concentration at the interface of Mo layer provides further positive potential barriers.

Density functional theory investigation of the geometric and electronic structures of [UO2(H2O)m(OH)n](2 - n) (n + m = 5).

PubMed

Ingram, Kieran I M; Häller, L Jonas L; Kaltsoyannis, Nikolas

2006-05-28

Gradient corrected density functional theory has been used to calculate the geometric and electronic structures of the family of molecules [UO2(H2O)m(OH)n](2 - n) (n + m = 5). Comparisons are made with previous experimental and theoretical structural and spectroscopic data. r(U-O(yl)) is found to lengthen as water molecules are replaced by hydroxides in the equatorial plane, and the nu(sym) and nu(asym) uranyl vibrational wavenumbers decrease correspondingly. GGA functionals (BP86, PW91 and PBE) are generally found to perform better for the cationic complexes than for the anions. The inclusion of solvent effects using continuum models leads to spurious low frequency imaginary vibrational modes and overall poorer agreement with experimental data for nu(sym) and nu(asym). Analysis of the molecular orbital structure is performed in order to trace the origin of the lengthening and weakening of the U-O(yl) bond as waters are replaced by hydroxides. No evidence is found to support previous suggestions of a competition for U 6d atomic orbitals in U-O(yl) and U-O(hydroxide)pi bonding. Rather, the lengthening and weakening of U-O(yl) is attributed to reduced ionic bonding generated in part by the sigma-donating ability of the hydroxide ligands.

Variable Mixed Orbital Character in the Photoelectron Angular Distribution of NO_{2}

NASA Astrophysics Data System (ADS)

Laws, Benjamin A.; Cavanagh, Steven J.; Lewis, Brenton R.; Gibson, Stephen T.

2017-06-01

NO_{2} a key component of photochemical smog and an important species in the Earth's atmosphere, is an example of a molecule which exhibits significant mixed orbital character in the HOMO. In photoelectron experiments the geometric properties of the parent anion orbital are reflected in the photoelectron angular distribution (PAD), an area of research that has benefited largely from the ability of velocity-map imaging (VMI) to simultaneously record both the energetic and angular information, with 100% collection efficiency. Photoelectron spectra of NO_{2}^{-}, taken over a range of wavelengths (355nm-520nm) with the ANU's VMI spectrometer, reveal an anomalous jump in the anisotropy parameter near threshold. Consequently, the orbital behavior of NO_{2}^{-} appears to be quite different near threshold compared to detachment at higher photon energies. This surprising effect is due to the Wigner Threshold law, which causes p orbital character to dominate the photodetachment cross-section near threshold, before the mixed s/d orbital character becomes significant at higher electron kinetic energies. By extending recent work on binary character models to form a more general expression, the variable mixed orbital character of NO_{2}^{-} is able to be described. This study provides the first multi-wavelength NO_{2} anisotropy data, which is shown to be in decent agreement with much earlier zero-core model predictions of the anisotropy parameter. K. J. Reed, A. H. Zimmerman, H. C. Andersen, and J. I. Brauman, J. Chem. Phys. 64, 1368, (1976). doi:10.1063/1.432404 D. Khuseynov, C. C. Blackstone, L. M. Culberson, and A. Sanov, J. Chem. Phys. 141, 124312, (2014). doi:10.1063/1.4896241 W. B. Clodius, R. M. Stehman, and S. B. Woo, Phys. Rev. A. 28, 760, (1983). doi:10.1103/PhysRevA.28.760 Research supported by the Australian Research Council Discovery Project Grant DP160102585

Orbital dynamics of high area-to-mass ratio spacecraft with J2 and solar radiation pressure for novel Earth observation and communication services

NASA Astrophysics Data System (ADS)

Colombo, Camilla; Lücking, Charlotte; McInnes, Colin R.

2012-12-01

This paper investigates the effect of planetary oblateness and solar radiation pressure on the orbits of high area-to-mass spacecraft. A planar Hamiltonian model shows the existence of equilibrium orbits with the orbit apogee pointing towards or away from the Sun. These solutions are numerically continued to non-zero inclinations and considering the obliquity of the ecliptic plane relative to the equator. Quasi-frozen orbits are identified in eccentricity, inclination and the angle between the Sun-line and the orbit perigee. The long-term evolution of these orbits is then verified through numerical integration. A set of 'heliotropic' orbits with apogee pointing in the direction of the Sun is proposed for enhancing imaging and telecommunication on the day side of the Earth. The effects of J2 and solar radiation pressure are exploited to obtain a passive rotation of the apsides line following the Sun; moreover the effect of solar radiation pressure enables such orbits at higher eccentricities with respect to the J2 only case.

The family of planar periodic orbits generated by the equal-mass four-body Schubart interplay orbit

NASA Astrophysics Data System (ADS)

Chopovda, Valerie; Sweatman, Winston L.

2018-05-01

We locate members of a one-parameter family of equal-mass four-body periodic orbits in the plane. The family begins and ends with the rectilinear four-body equal-mass Schubart interplay orbit and passes through a double choreography orbit. The first-order stability of these orbits is computed. Some members of this symmetric family are stable to symmetric perturbations; however, they are unstable when all perturbations are allowed.

Space-Plane Spreadsheet Program

NASA Technical Reports Server (NTRS)

Mackall, Dale

1993-01-01

Basic Hypersonic Data and Equations (HYPERDATA) spreadsheet computer program provides data gained from three analyses of performance of space plane. Equations used to perform analyses derived from Newton's second law of physics, derivation included. First analysis is parametric study of some basic factors affecting ability of space plane to reach orbit. Second includes calculation of thickness of spherical fuel tank. Third produces ratio between volume of fuel and total mass for each of various aircraft. HYPERDATA intended for use on Macintosh(R) series computers running Microsoft Excel 3.0.

[Vertical retraction syndrome caused by anomalous orbital structures].

PubMed

Yang, Qiong; Jiao, Yong-hong; Man, Feng-yuan; Wang, Zhen-chang; Chang, Qing-lin; Lu, Wei; Wang, Jing-hui; Zhao, Kan-xing

2011-11-01

To described the clinical feature and MRI imaging of six children with vertical retraction syndrome. Six children with unilateral vertical retraction syndrome between 15 months and 8 years of age, mean age was (5.01 ± 1.27) years old. Strabismus examination included diopter, prism diopters, eye movement examination, binocular vision and fundus examination. Imaging of the ocular motor nerves at the brainstem was performed in 0.8 mm thickness image planes using 3D-FIESTA sequence, the orbits were imaged with FSE T1, T2WI using surface coils, and within 2.0 mm thick planes. Four children showed hypertropia, characterized by limited depression, a light retraction of the globe during downward gaze and eyelid lag. The MRI imaging showed anomalous orbital structure in the superonasal quadrant that between medial rectus and superior rectus or adjacent to the superior rectus. Two children showed intermittent exotropia, characterized by limited elevation, retraction of the globe and narrowing of the palpebral fissure during upward gaze. The MRI imaging showed anomalous orbital structure was present in the inferotemporal quadrant, one originate in inferior rectus and another close to the lateral rectus. Anomalous orbital structures are a main cause of vertical retraction syndrome. The presence of specific unusual eye movement and MRI imaging may assist in diagnosis. When the eyelid lag was found since the early age, anomalous orbital structures were implied.

Orbit-orbit relativistic correction calculated with all-electron molecular explicitly correlated Gaussians.

PubMed

Stanke, Monika; Palikot, Ewa; Kȩdziera, Dariusz; Adamowicz, Ludwik

2016-12-14

An algorithm for calculating the first-order electronic orbit-orbit magnetic interaction correction for an electronic wave function expanded in terms of all-electron explicitly correlated molecular Gaussian (ECG) functions with shifted centers is derived and implemented. The algorithm is tested in calculations concerning the H 2 molecule. It is also applied in calculations for LiH and H 3 + molecular systems. The implementation completes our work on the leading relativistic correction for ECGs and paves the way for very accurate ECG calculations of ground and excited potential energy surfaces (PESs) of small molecules with two and more nuclei and two and more electrons, such as HeH - , H 3 + , HeH 2 + , and LiH 2 + . The PESs will be used to determine rovibrational spectra of the systems.

Autonomous orbital navigation using Kepler's equation

NASA Technical Reports Server (NTRS)

Boltz, F. W.

1974-01-01

A simple method of determining the six elements of elliptic satellite orbits has been developed for use aboard manned and unmanned spacecraft orbiting the earth, moon, or any planet. The system requires the use of a horizon sensor or other device for determining the local vertical, a precision clock or timing device, and Apollo-type navigation equipment including an inertial measurement unit (IMU), a digital computer, and a coupling data unit. The three elements defining the in-plane motion are obtained from simultaneous measurements of central angle traversed around the planet and elapsed flight time using a linearization of Kepler's equation about a reference orbit. It is shown how Kalman filter theory may also be used to determine the in-plane orbital elements. The three elements defining the orbit orientation are obtained from position angles in celestial coordinates derived from the IMU with the spacecraft vertically oriented after alignment of the IMU to a known inertial coordinate frame.

Stable Satellite Orbits for Global Coverage of the Moon

NASA Technical Reports Server (NTRS)

Ely, Todd; Lieb, Erica

2006-01-01

A document proposes a constellation of spacecraft to be placed in orbit around the Moon to provide navigation and communication services with global coverage required for exploration of the Moon. There would be six spacecraft in inclined elliptical orbits: three in each of two orthogonal orbital planes, suggestive of a linked-chain configuration. The orbits have been chosen to (1) provide 99.999-percent global coverage for ten years and (2) to be stable under perturbation by Earth gravitation and solar-radiation pressure, so that no deterministic firing of thrusters would be needed to maintain the orbits. However, a minor amount of orbit control might be needed to correct for such unmodeled effects as outgassing of the spacecraft.

Potential energy surfaces of LaH + and LaH + 2

NASA Astrophysics Data System (ADS)

Das, Kalyan K.; Balasubramanian, K.

1991-03-01

Using the complete active space multiconfiguration self-consistent field (CAS-MCSCF) followed by full second-order configuration interaction (SOCI) calculations, 16 electronic states of LaH+ and 8 electronic states of LaH+2 are investigated. The potential energy surface of these electronic states of LaH+2 and LaH+ are computed. These calculations show that the 3F(5d2) ground state of La+ ion forms a weak complex with H2. The La+(1D) excited state inserts into H2 with a small barrier (<8 kcal/mol) to form the 1A1 ground state of LaH+2 (re=2.057 Å, θe=106°). At the SOCI level of theory LaH+2 is found to be 11 kcal/mol more stable than La+(3F)+H2. Our calculations explain the experimental observations on La++H2→LaH++H reaction. The adiabatic ionization potential (IP) of LaH2 and LaH are calculated as 5.23 and 5.33 eV, respectively. The ground state of LaH+ was found to be a 2Δ state. We compute De(LaH+) and De(HLa-H+) as 2.54 eV in excellent agreement with the experimental De(LaH+)=2.57 eV measured by Armentrout and co-workers. The spin-orbit effects of LaH+ were also studied using the relativistic configuration interaction (RCI) method.

Optimal multiple-pass aeroassisted plane change

NASA Technical Reports Server (NTRS)

Vinh, Nguyen X.; Ma, Der-Ming

1990-01-01

This paper presents the exact dimensionless equation of motion and the necessary conditions for the computation of the optimal trajectories of a hypervelocity vehicle flying through a non-rotating spherical planetary atmosphere. Numerical solution is then presented for the case when the vehicle makes several passages through the atmosphere near the perigee of its orbit. While the orbit is slowly contracting, aerodynamic maneuver is performed to obtain the maximum plane change. Several plots were presented to show the optimal variations of the lift coefficient and the bank angle and the various elements of the orbit.

Origin of the Local Group satellite planes

NASA Astrophysics Data System (ADS)

Banik, Indranil; O'Ryan, David; Zhao, Hongsheng

2018-04-01

We attempt to understand the planes of satellite galaxies orbiting the Milky Way (MW) and M31 in the context of Modified Newtonian Dynamics (MOND), which implies a close MW-M31 flyby occurred ≈8 Gyr ago. Using the timing argument, we obtain MW-M31 trajectories consistent with cosmological initial conditions and present observations. We adjust the present M31 proper motion within its uncertainty in order to simulate a range of orbital geometries and closest approach distances. Treating the MW and M31 as point masses, we follow the trajectories of surrounding test particle disks, thereby mapping out the tidal debris distribution. Around each galaxy, the resulting tidal debris tends to cluster around a particular orbital pole. We find some models in which these preferred spin vectors align fairly well with those of the corresponding observed satellite planes. The radial distributions of material in the simulated satellite planes are similar to what we observe. Around the MW, our best-fitting model yields a significant fraction (0.22) of counter-rotating material, perhaps explaining why Sculptor counter-rotates within the MW satellite plane. In contrast, our model yields no counter-rotating material around M31. This is testable with proper motions of M31 satellites. In our best model, the MW disk is thickened by the flyby 7.65 Gyr ago to a root mean square height of 0.75 kpc. This is similar to the observed age and thickness of the Galactic thick disk. Thus, the MW thick disk may have formed together with the MW and M31 satellite planes during a past MW-M31 flyby.

Origin of the Local Group satellite planes

NASA Astrophysics Data System (ADS)

Banik, Indranil; O'Ryan, David; Zhao, Hongsheng

2018-07-01

We attempt to understand the planes of satellite galaxies orbiting the Milky Way (MW) and M31 in the context of Modified Newtonian Dynamics, which implies a close MW-M31 flyby occurred ≈8 Gyr ago. Using the timing argument, we obtain MW-M31 trajectories consistent with cosmological initial conditions and present observations. We adjust the present M31 proper motion within its uncertainty in order to simulate a range of orbital geometries and closest approach distances. Treating the MW and M31 as point masses, we follow the trajectories of surrounding test particle discs, thereby mapping out the tidal debris distribution. Around each galaxy, the resulting tidal debris tends to cluster around a particular orbital pole. We find some models in which these preferred spin vectors align fairly well with those of the corresponding observed satellite planes. The radial distributions of material in the simulated satellite planes are similar to what we observe. Around the MW, our best-fitting model yields a significant fraction (0.22) of counter-rotating material, perhaps explaining why Sculptor counter-rotates within the MW satellite plane. In contrast, our model yields no counter-rotating material around M31. This is testable with proper motions of M31 satellites. In our best model, the MW disc is thickened by the flyby 7.65 Gyr ago to a root mean square height of 0.75 kpc. This is similar to the observed age and thickness of the Galactic thick disc. Thus, the MW thick disc may have formed together with the MW and M31 satellite planes during a past MW-M31 flyby.

Hybrid near-optimal aeroassisted orbit transfer plane change trajectories

NASA Technical Reports Server (NTRS)

Calise, Anthony J.; Duckeman, Gregory A.

1994-01-01

In this paper, a hybrid methodology is used to determine optimal open loop controls for the atmospheric portion of the aeroassisted plane change problem. The method is hybrid in the sense that it combines the features of numerical collocation with the analytically tractable portions of the problem which result when the two-point boundary value problem is cast in the form of a regular perturbation problem. Various levels of approximation are introduced by eliminating particular collocation parameters and their effect upon problem complexity and required number of nodes is discussed. The results include plane changes of 10, 20, and 30 degrees for a given vehicle.

A vast, thin plane of corotating dwarf galaxies orbiting the Andromeda galaxy.

PubMed

Ibata, Rodrigo A; Lewis, Geraint F; Conn, Anthony R; Irwin, Michael J; McConnachie, Alan W; Chapman, Scott C; Collins, Michelle L; Fardal, Mark; Ferguson, Annette M N; Ibata, Neil G; Mackey, A Dougal; Martin, Nicolas F; Navarro, Julio; Rich, R Michael; Valls-Gabaud, David; Widrow, Lawrence M

2013-01-03

Dwarf satellite galaxies are thought to be the remnants of the population of primordial structures that coalesced to form giant galaxies like the Milky Way. It has previously been suspected that dwarf galaxies may not be isotropically distributed around our Galaxy, because several are correlated with streams of H I emission, and may form coplanar groups. These suspicions are supported by recent analyses. It has been claimed that the apparently planar distribution of satellites is not predicted within standard cosmology, and cannot simply represent a memory of past coherent accretion. However, other studies dispute this conclusion. Here we report the existence of a planar subgroup of satellites in the Andromeda galaxy (M 31), comprising about half of the population. The structure is at least 400 kiloparsecs in diameter, but also extremely thin, with a perpendicular scatter of less than 14.1 kiloparsecs. Radial velocity measurements reveal that the satellites in this structure have the same sense of rotation about their host. This shows conclusively that substantial numbers of dwarf satellite galaxies share the same dynamical orbital properties and direction of angular momentum. Intriguingly, the plane we identify is approximately aligned with the pole of the Milky Way's disk and with the vector between the Milky Way and Andromeda.

LLOFX earth orbit to lunar orbit delta V estimation program user and technical documentation

NASA Technical Reports Server (NTRS)

1988-01-01

The LLOFX computer program calculates in-plane trajectories from an Earth-orbiting space station to Lunar orbit in such a way that the journey requires only two delta V burns (one to leave Earth circular orbit and one to circularize into Lunar orbit). The program requires the user to supply the Space Station altitude and Lunar orbit altitude (in km above the surface), and the desired time of flight for the transfer (in hours). It then determines and displays the trans-Lunar injection (TLI) delta V required to achieve the transfer, the Lunar orbit insertion (LOI) delta V required to circularize the orbit around the Moon, the actual time of flight, and whether the transfer orbit is elliptical or hyperbolic. Return information is also displayed. Finally, a plot of the transfer orbit is displayed.

Modal control of an unstable periodic orbit

NASA Astrophysics Data System (ADS)

Wiesel, W.; Shelton, W.

1983-03-01

Floquet theory is applied to the problem of designing a control system for a satellite in an unstable periodic orbit. Expansion about a periodic orbit produces a time-periodic linear system, which is augmented by a time-periodic control term. It is shown that this can be done such that (1) the application of control produces only inertial accelerations, (2) positive real Poincareexponents are shifted into the left half-plane, and (3) the shift of the exponent is linear with control gain. These developments are applied to an unstable orbit near the earth-moon L(3) point pertubed by the sun. Finally, it is shown that the control theory can be extended to include first order perturbations about the periodic orbit without increase in control cost.

Modal control of an unstable periodic orbit

NASA Technical Reports Server (NTRS)

Wiesel, W.; Shelton, W.

1983-01-01

Floquet theory is applied to the problem of designing a control system for a satellite in an unstable periodic orbit. Expansion about a periodic orbit produces a time-periodic linear system, which is augmented by a time-periodic control term. It is shown that this can be done such that (1) the application of control produces only inertial accelerations, (2) positive real Poincareexponents are shifted into the left half-plane, and (3) the shift of the exponent is linear with control gain. These developments are applied to an unstable orbit near the earth-moon L(3) point pertubed by the sun. Finally, it is shown that the control theory can be extended to include first order perturbations about the periodic orbit without increase in control cost.

The Mid-plane of the Main Asteroid Belt

NASA Astrophysics Data System (ADS)

Cambioni, Saverio; Malhotra, Renu

2018-03-01

We measure the mid-plane of the main asteroid belt by using the observational data of a nearly complete and unbiased sample of asteroids and find that it has inclination \\bar{I}=0\\buildrel{\\circ}\\over{.} 93+/- 0\\buildrel{\\circ}\\over{.} 04 and longitude of ascending node \\bar{{{Ω }}}=87\\buildrel{\\circ}\\over{.} 6+/- 2\\buildrel{\\circ}\\over{.} 6 (in J2000 ecliptic-equinox coordinate system). This plane differs significantly from previously published measurements, and it is also distinctly different than the solar system’s invariable plane as well as Jupiter’s orbit plane. The mid-plane of the asteroid belt is theoretically expected to be a slightly warped sheet whose local normal is controlled by the gravity of the major planets. Specifically, its inclination and longitude of ascending node varies with semimajor axis and time (on secular timescales) and is defined by the forced solution of secular perturbation theory; the ν 16 nodal secular resonance is predicted to cause a significant warp of the mid-plane in the inner asteroid belt. We test the secular theory by measuring the current location of the asteroids’ mid-plane in finer semimajor axis bins. We find that the measured mid-plane in the middle and outer asteroid belt is consistent, within the 3σ confidence level, with the prediction of secular perturbation theory, but a notable discrepancy is present in the inner asteroid belt near ∼2 au.

Spin-orbit torque induced magnetization switching in Ta/Co{sub 20}Fe{sub 60}B{sub 20}/MgO structures under small in-plane magnetic fields

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cao, Jiangwei, E-mail: caojw@lzu.edu.cn; Zheng, Yuqiang; Su, Xianpeng

2016-04-25

Spin-orbit torque (SOT)-induced magnetization switching under small in-plane magnetic fields in as-deposited and annealed Ta/CoFeB/MgO structures is studied. For the as-deposited samples, partial SOT-induced switching behavior is observed under an in-plane field of less than 100 Oe. Conversely, for the annealed samples, an in-plane field of 10 Oe is large enough to achieve full deterministic magnetization switching. The Dzyaloshinskii-Moriya interaction at the Ta/CoFeB interface is believed to be the main reason for the discrepancy of the requisite in-plane magnetic fields for switching in the as-deposited and annealed samples. In addition, asymmetric field dependence behavior of SOT-induced magnetization switching is observed in themore » annealed samples. Deterministic magnetization switching in the absence of an external magnetic field is obtained in the annealed samples, which is extremely important to develop SOT-based magnetoresistive random access memory.« less

Application of Probabilistic Risk Assessment (PRA) During Conceptual Design for the NASA Orbital Space Plane (OSP)

NASA Technical Reports Server (NTRS)

Rogers, James H.; Safie, Fayssal M.; Stott, James E.; Lo, Yunnhon

2004-01-01

In order to meet the space transportation needs for a new century, America's National Aeronautics and Space Administration (NASA) has implemented an Integrated Space Transportation Plan to produce safe, economical, and reliable access to space. One near term objective of this initiative is the design and development of a next-generation vehicle and launch system that will transport crew and cargo to and from the International Space Station (ISS), the Orbital Space Plane (OSP). The OSP system is composed of a manned launch vehicle by an existing Evolved Expendable Launch Vehicle (EELV). The OSP will provide emergency crew rescue from the ISS by 2008, and provide crew and limited cargo transfer to and from the ISS by 2012. A key requirement is for the OSP to be safer and more reliable than the Soyuz and Space Shuttle, which currently provide these capabilities.

Discovery of A New Retrograde Trans-Neptunian Object: Hint of A Common Orbital Plane for Low Semi-Major Axis, High Inclination TNOs and Centaurs

NASA Astrophysics Data System (ADS)

Chen, Ying-Tung; Lin, Hsing-Wen; Holman, Matthew J.; Payne, Matthew John; Fraser, Wesley Cristopher; Lacerda, Pedro; Ip, Wing-Huen; Pan-STARRS 1 Builders

2016-10-01

The origin of high inclination objects beyond Jupiter, including trans-Neptunian objects (TNOs) and Centaurs, remains uncertain. We report the discovery of a retrograde TNO, which we nickname "Niku", detected by the Pan-STARRS 1 Outer Solar System Survey. The numerical integrations show that the orbital dynamics of Niku are very similar to those of 2008 KV42 (Drac), with a half-life of ~ 500 Myr and analogous orbital evolution. Comparing similar high inclination members announced by the Minor-Planet Center (q > 10 AU, a < 100 AU and i > 60), we find these objects exhibit a surprising clustering of ascending node, populating a common orbital plane. The statistical significance of 3.8-sigma suggests it is unlikely to be coincidental. An unknown mechanism is required to explain the observed clustering. This discovery may provide a pathway to investigating a possible reservoir of high-inclination objects.

[Subcostal transversus abdominis plane block can improve analgesia after laparoscopic cholecystectomy].

PubMed

Vrsajkov, Vladimir; Mančić, Nedjica; Mihajlović, Dunja; Milićević, Suzana Tonković; Uvelin, Arsen; Vrsajkov, Jelena Pantić

After laparoscopic cholecystectomy, patients have moderate pain in the early postoperative period. Some studies shown beneficial effects of subcostal transversus abdominis plane block on reducing this pain. Our goal was to investigate influence of subcostal transversus abdominis plane block on postoperative pain scores and opioid consumption. We have randomized 76 patients undergoing laparoscopic cholecystectomy to receive either subcostal transversus abdominis plane block (n=38) or standard postoperative analgesia (n=38). First group received bilateral ultrasound guided subcostal transversus abdominis plane block with 20mL of 0.33% bupivacaine per side before operation and tramadol 1mg.kg -1 IV for pain breakthrough (≥6). Second group received after operation tramadol 1mg.kg -1 /6h as standard hospital analgesia protocol. Both groups received acetaminophen 1g/8h IV and metamizole 2.5g/12h. Pain at rest was recorded for each patient using NR scale (0-10) in period of 10min, 30min, 2h, 4h, 8h, 12h and 16h after the surgery. We obtained no difference between groups according age, weight, intraoperative fentanyl consumption and duration of surgery. Subcostal transversus abdominis plane block significantly reduced postoperative pain scores compared to standard analgesia in all periods after surgery. Tramadol consumption was significantly lower in the subcostal transversus abdominis plane (24.29±47.54g) than in the standard analgesia group (270.2±81.9g) (p=0.000). Our results show that subcostal transversus abdominis plane block can provide superior postoperative analgesia and reduction in opioid requirements after laparoscopic cholecystectomy. Copyright © 2017 Sociedade Brasileira de Anestesiologia. Publicado por Elsevier Editora Ltda. All rights reserved.

The Sentinel-4 UVN focal plane assemblies

NASA Astrophysics Data System (ADS)

Hinger, Jürgen; Hohn, Rüdiger; Gebhardt, Eyk; Reichardt, Jörg

2017-09-01

The Sentinel-4 UVN Instrument is a dispersive imaging spectrometer covering the UV-VIS and the NIR wavelength. It is developed and built under an ESA contract by an industrial consortium led by Airbus Defence and Space. It will be accommodated on board of the MTG-S (Meteosat Third Generation - Sounder) satellite that will be placed in a geostationary orbit over Europe sampling data for generating two-dimensional maps of a number of atmospheric trace gases. The incoming light is dispersed by reflective gratings and detected by the two (UVVIS and NIR) CCDs mounted inside the focal plane assemblies. Both CCD detectors acquire spectral channels and spatial sampling in two orthogonal directions and will be operated at about 215 K mainly to minimize random telegraph signal effects and to reduce dark current. Stringent detector temperature as well as alignment stability requirements of less than +/-0.1 K per day respectively of less than 2 micrometers/2 arcseconds from ground to orbit are driving the FPA thermo-mechanical design. A specific FPA design feature is the redundant LED-calibration system for bad pixel detection as well as pixel gain and linearity monitoring. This paper reports on the design and qualification of the Focal Plane Assemblies with emphasis on thermo-mechanical as well as alignment stability verification.

HP-9810A calculator programs for plotting the 2-dimensional motion of cyclindrical payloads relative to the shuttle orbiter

NASA Technical Reports Server (NTRS)

Wilson, S. W.

1976-01-01

The HP-9810A calculator programs described provide the capability to generate HP-9862A plotter displays which depict the apparent motion of a free-flying cyclindrical payload relative to the shuttle orbiter body axes by projecting the payload geometry into the orbiter plane of symmetry at regular time intervals.

Intercorrelated In-Plane and Out-of-Plane Ferroelectricity in Ultrathin Two-Dimensional Layered Semiconductor In2Se3.

PubMed

Cui, Chaojie; Hu, Wei-Jin; Yan, Xingxu; Addiego, Christopher; Gao, Wenpei; Wang, Yao; Wang, Zhe; Li, Linze; Cheng, Yingchun; Li, Peng; Zhang, Xixiang; Alshareef, Husam N; Wu, Tom; Zhu, Wenguang; Pan, Xiaoqing; Li, Lain-Jong

2018-02-14

Enriching the functionality of ferroelectric materials with visible-light sensitivity and multiaxial switching capability would open up new opportunities for their applications in advanced information storage with diverse signal manipulation functions. We report experimental observations of robust intralayer ferroelectricity in two-dimensional (2D) van der Waals layered α-In 2 Se 3 ultrathin flakes at room temperature. Distinct from other 2D and conventional ferroelectrics, In 2 Se 3 exhibits intrinsically intercorrelated out-of-plane and in-plane polarization, where the reversal of the out-of-plane polarization by a vertical electric field also induces the rotation of the in-plane polarization. On the basis of the in-plane switchable diode effect and the narrow bandgap (∼1.3 eV) of ferroelectric In 2 Se 3 , a prototypical nonvolatile memory device, which can be manipulated both by electric field and visible light illumination, is demonstrated for advancing data storage technologies.

Optimal trajectories for an aerospace plane. Part 1: Formulation, results, and analysis

NASA Technical Reports Server (NTRS)

Miele, Angelo; Lee, W. Y.; Wu, G. D.

1990-01-01

The optimization of the trajectories of an aerospace plane is discussed. This is a hypervelocity vehicle capable of achieving orbital speed, while taking off horizontally. The vehicle is propelled by four types of engines: turbojet engines for flight at subsonic speeds/low supersonic speeds; ramjet engines for flight at moderate supersonic speeds/low hypersonic speeds; scramjet engines for flight at hypersonic speeds; and rocket engines for flight at near-orbital speeds. A single-stage-to-orbit (SSTO) configuration is considered, and the transition from low supersonic speeds to orbital speeds is studied under the following assumptions: the turbojet portion of the trajectory has been completed; the aerospace plane is controlled via the angle of attack and the power setting; the aerodynamic model is the generic hypersonic aerodynamics model example (GHAME). Concerning the engine model, three options are considered: (EM1), a ramjet/scramjet combination in which the scramjet specific impulse tends to a nearly-constant value at large Mach numbers; (EM2), a ramjet/scramjet combination in which the scramjet specific impulse decreases monotonically at large Mach numbers; and (EM3), a ramjet/scramjet/rocket combination in which, owing to stagnation temperature limitations, the scramjet operates only at M approx. less than 15; at higher Mach numbers, the scramjet is shut off and the aerospace plane is driven only by the rocket engines. Under the above assumptions, four optimization problems are solved using the sequential gradient-restoration algorithm for optimal control problems: (P1) minimization of the weight of fuel consumed; (P2) minimization of the peak dynamic pressure; (P3) minimization of the peak heating rate; and (P4) minimization of the peak tangential acceleration.

Stochastic Orbit Prediction Using KAM Tori

DTIC Science & Technology

2011-03-24

the plane . The debris was later identified as a reentering Russian Progress 23P cargo freighter for the ISS...elements. The eccentricity and angular momentum scalar quantities define the orbit in the plane [25:208]. The inclination, right ascension of the ascending...Since ⃑ is a constant vector perpendicular to ⃑ and ⃑ , the satellite’s motion is fixed in the plane containing ⃑ and ⃑ called the

Static Orbits in Rotating Spacetimes

NASA Astrophysics Data System (ADS)

Collodel, Lucas G.; Kleihaus, Burkhard; Kunz, Jutta

2018-05-01

We show that under certain conditions an axisymmetric rotating spacetime contains a ring of points in the equatorial plane, where a particle at rest with respect to an asymptotic static observer remains at rest in a static orbit. We illustrate the emergence of such orbits for boson stars. Further examples are wormholes, hairy black holes, and Kerr-Newman solutions.

π-stacking and C-X...D (X = H, NO2; D = O, π) interactions in the crystal network of both C-H...N and π-stacked dimers of 1,2-bis(4-bromophenyl)-1H-benzimidazole and 2-(4-bromophenyl)-1-(4-nitrophenyl)-1H-benzimidazole.

PubMed

González-Padilla, Jazmin E; Rosales-Hernández, Martha C; Padilla-Martínez, Itzia I; García-Báez, Efren V; Rojas-Lima, Susana; Salazar-Pereda, Veronica

2014-01-01

Molecules of 1,2-bis(4-bromophenyl)-1H-benzimidazole, C19H12Br2N2, (I), and 2-(4-bromophenyl)-1-(4-nitrophenyl)-1H-benzimidazole, C19H12BrN3O2, (II), are arranged in dimeric units through C-H...N and parallel-displaced π-stacking interactions favoured by the appropriate disposition of N- and C-bonded phenyl rings with respect to the mean benzimidazole plane. The molecular packing of the dimers of (I) and (II) arises by the concurrence of a diverse set of weak intermolecular C-X...D (X = H, NO2; D = O, π) interactions.

Unified mechanism of alkali and alkaline earth catalyzed gasification reactions of carbon by CO2 and H2O

USGS Publications Warehouse

Chen, S.G.; Yang, R.T.

1997-01-01

From molecular orbital calculations, a unified mechanism is proposed for the gasification reactions of graphite by CO2 and H2O, both uncatalyzed and catalyzed by alkali and alkaline earth catalysts. In this mechanism, there are two types of oxygen intermediates that are bonded to the active edge carbon atoms: an in-plane semiquinone type, Cf(O), and an off-plane oxygen bonded to two saturated carbon atoms that are adjacent to the semiquinone species, C(O)Cf(O). The rate-limiting step is the decomposition of these intermediates by breaking the C-C bonds that are connected to Cf(O). A new rate equation is derived for the uncatalyzed reactions, and that for the catalyzed reactions is readily available from the proposed mechanism. The proposed mechanism can account for several unresolved experimental observations: TPD and TK (transient kinetics) desorption results of the catalyzed systems, the similar activation energies for the uncatalyzed and catalyzed reactions, and the relative activities of the alkali and alkaline earth elements. The net charge of the edge carbon active site is substantially changed by gaining electron density from the alkali or alkaline earth element (by forming C-O-M, where M stands for metal). The relative catalytic activities of these elements can be correlated with their abilities of donating electrons and changing the net charge of the edge carbon atom. As shown previously (Chen, S. G.; Yang, R. T. J. Catal. 1993, 141, 102), only clusters of the alkali compounds are active. This derives from the ability of the clusters to dissociate CO2 and H2O to form O atoms and the mobility of the dissociated O atoms facilitated by the clusters.

Update on the X-Ray Variability Plane for Active Galactic Nuclei: The Role of the Obscuration

NASA Astrophysics Data System (ADS)

González-Martín, Omaira

2018-05-01

Scaling relations are the most powerful astrophysical tools to set constraints on the physical mechanisms of astronomical sources and to infer properties that cannot be accessed directly. We reinvestigate here one of these scaling relations in active galactic nuclei (AGNs); the so-called X-ray variability plane (or mass–luminosity timescale relation). This relation links the power-spectral density (PSD) break frequency with the super-massive black hole (SMBH) mass and the bolometric luminosity. We used the available XMM-Newton observations of a sample of 22 AGNs to study the PSD and spectra in short segments within each observation. This allows us to report for the first time that the PSD break frequency varies for each object, showing variations in 19 out of the 22 AGNs analyzed. Our analysis of the variability plane confirms the relation between the break frequency and the SMBH mass and finds that the obscuration along the line of sight N H (or the variations on the obscuration using its standard deviation, ΔN H) is also a required parameter, at least for the range of frequencies analyzed here (∼ 3 × {10}-5-5× {10}-2 {Hz}). We constrain a new variability plane of the following form: {log}({ν }Break})=(-0.589 +/- 0.005) {log}({{{M}}}BH})+(0.10+/- 0.01) {log}({{{N}}}{{H}})-(1.5+/- 0.3) (or {log}({ν }Break})=(-0.549+/- 0.009) {log}({{{M}}}BH}) +(0.56+/- 0.06) {{Δ }}{N}{{H}}+(0.19+/- 0.08)). The X-ray variability plane found by McHardy et al. is roughly recovered when we use unobscured segments. We speculate that this behavior is well explained if most of the reported frequencies are related to inner clouds (within 1 pc), following Kepler orbits under the gravitational field of the SMBH.

Pluto and Charon: A Case of Precession-Orbit Resonance?

NASA Technical Reports Server (NTRS)

Rubincam, David Parry; Smith, David E. (Technical Monitor)

2000-01-01

Pluto may be the only known case of precession-orbit resonance in the solar system. The Pluto-Charon system orbits the Sun with a period of 1 Plutonian year, which is 250.8 Earth years. The observed parameters of the system are such that Charon may cause Pluto to precess with a period near 250.8 Earth years. This gives rise to two possible resonances, heretofore unrecognized. The first is due to Pluto's orbit being highly eccentric, giving solar torques on Charon with a period of 1 Plutonian year. Charon in turn drives Pluto near its precession period. Volatiles, which are expected to shuttle across Pluto's surface between equator and pole as Pluto's obliquity oscillates, might change the planet's dynamical flattening enough so that Pluto crosses the nearby resonance, forcing the planet's equatorial plane to depart from Charon's orbital plane. The mutual tilt can reach as much as 2 deg after integrating over 5.6 x 10(exp 6) years, depending upon how close Pluto is to the resonance and the supply of volatiles. The second resonance is due to the Sun's traveling above and below Charon's orbital plane; it has a period half that of the eccentricity resonance. Reaching this half-Plutonian year resonance requires a much larger but still theoretically possible amount of volatiles. In this case the departure of Charon from an equatorial orbit is about 1 deg after integrating for 5.6 x 10(exp 6) years. The calculations ignore libration and tidal friction. It is not presently known how large the mutual tilt can grow over the age of the solar system, but if it remains only a few degrees, then observing such small angles from a Pluto flyby mission would be difficult. It is not clear why the parameters of the Pluto-Charon system are so close to the eccentricity resonance.

Half-metallicity in the ferrimagnet [MnII(enH)(H2O)][CrIII(CN)6]·H2O: Ab initio study

NASA Astrophysics Data System (ADS)

Li, N.; Yao, K. L.; Zhong, G. H.; Ching, W. Y.

2013-03-01

The density-functional theory (DFT) within the full potential linearized augmented plane wave (FPLAPW) method is applied to study the two-dimensional achiral soft ferrimagnet [MnII(enH)(H2O)][CrIII(CN)6]·H2O. The phase stability, electronic structure, magnetic and conducting properties are investigated. Our results reveal that the compound has a stable ferrimagnetic ground state in good agreement with the experiment. From the spin density distribution, the spin magnetic moment of the compound is mainly from Cr3+ and Mn2+ ions with small contributions from the oxygen, nitrogen and carbon ions. The calculated electronic band structure predicts the compound to be a half-metal with the spin magnetic moment of 1.000 μB per molecule.

Orbital ordering in FeV2O4: Spinel with two orbitally active sites

NASA Astrophysics Data System (ADS)

Sarkar, Soumyajit; Saha-Dasgupta, T.

2011-12-01

By employing first-principles electronic structure calculations, we investigate orbital ordering in FeV2O4, a spinel with orbital degrees of freedom both at Fe and V sites that exhibits two tetragonal phases, one compressed at high temperature and another elongated at low temperature. Our first-principles study shows the ferro-orbital ordering of dx2-y2 and d3z2-r2 types at Fe sites at the high- and low-temperature phases, respectively. The orbital ordering at V sites is found to consist of orbital chains running along different directions with orbitals rotated alternatively within each chain, similar to that found for MnV2O4 [S. Sarkar , Phys. Rev. Lett.PRLTAO0031-900710.1103/PhysRevLett.102.216405 102, 216405 (2009)]. Further, we find that the single-ion anisotropy effect with hard and easy c axis favors the compressed and elongated tetrahedral shapes. This gives rise to magnetocrystalline anisotropy-dependent shapes, similar to that reported in the context of rare-earth-based magnetic shape memory alloys.

Electric propulsion for geostationary orbit insertion

NASA Technical Reports Server (NTRS)

Oleson, Steven R.; Curran, Francis M.; Myers, Roger M.

1995-01-01

Solar electric propulsion (SEP) technology is already being used for geostationary satellite stationkeeping to increase payload mass. By using this same technology to perform part of the orbit transfer additional increases in payload mass can be achieved. Advanced chemical and N2H4 arcjet systems are used to increase the payload mass by performing stationkeeping and part of the orbit transfer. Four mission options are analyzed which show the impact of either sharing the orbit transfer between chemical and SEP systems or having either complete the transfer alone. Results show that for an Atlas 2AS payload increases in net mass (geostationary satellite mass less wet propulsion system mass) of up to 100 kg can be achieved using advanced chemical for the transfer and advanced N2H4 arcjets for stationkeeping. An additional 100 kg can be added using advanced N2H4 arcjets for part of a 40 day orbit transfer.

CASA Uno GPS orbit and baseline experiments

NASA Technical Reports Server (NTRS)

Schutz, B. E.; Ho, C. S.; Abusali, P. A. M.; Tapley, B. D.

1990-01-01

CASA Uno data from sites distributed in longitude from Australia to Europe have been used to determine orbits of the GPS satellites. The characteristics of the orbits determined from double difference phase have been evaluated through comparisons of two-week solutions with one-week solutions and by comparisons of predicted and estimated orbits. Evidence of unmodeled effects is demonstrated, particularly associated with the orbit planes that experience solar eclipse. The orbit accuracy has been assessed through the repeatability of unconstrained estimated baseline vectors ranging from 245 km to 5400 km. Both the baseline repeatability and the comparison with independent space geodetic methods give results at the level of 1-2 parts in 100,000,000. In addition, the Mojave/Owens Valley (245 km) and Kokee Park/Ft. Davis (5409 km) estimates agree with VLBI and SLR to better than 1 part in 100,000,000.

Military Aircraft Emissions Research - Case of Hercules Cargo Plane (C-130H) Emissions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cheng, Mengdawn; Corporan, E.; DeWitt, M.

2007-01-01

Tactical airlifter like C-130H has been in use for more than 50 years, and is expected to serve for many years to come. However, the emission characteristics data of the aircraft are scarce. To increase our understanding of turboprop engine emissions, emissions from a military C-130H cargo aircraft were characterized in field conditions in the fall of 2005. Particulate and gaseous pollutants were measured by conventional and advanced instrumentation platforms that were built with in-situ extractive or remote optical sensing technologies. The measurements performed at the C-130H engine exhaust exit showed increased levels of emissions as the engine power settingmore » increased. In contrast, there was no such a relationship found for the C-130H emitted particulate matter (as a function of engine power setting) measured at about 15-m downstream of the engine exhaust plane. The emitted gaseous species measured at both locations were, however, proportional to the engine power setting and comparable (at both locations) when corrected for ambient dilution indicating the lack of particulate emission-power setting relationship at the far field is unique. The result clearly indicates that the aircraft emission factor or index for particulate matter cannot be experimentally determined at a downstream location away from the exhaust exit and has to be determined right at the engine exhaust plane. Emission indices that are needed for air quality modeling will be presented.« less

Determining The Plane of The Kuiper Belt with OSSOS

NASA Astrophysics Data System (ADS)

Van Laerhoven, Christa; Kavelaars, J. J.; Volk, Kathryn; Gladman, Brett; Petit, Jean-Marc

2018-04-01

We present the OSSOS-based measurement of the semi-major axes dependent orientation of the Kuiper Belt plane. A Kuiper Belt object's (KBO's) inclination can be broken down into a forced component and a free component. The inclination and longitude of ascending node of the forced inclination define the 'forced plane,' the plane about which the KBO's inclination will precess. Secular theory predicts that this forced plane should depend on semi-major axis. For example, the nu18 secular resonance should create a significant warp in the forced planet near 40.5 au (Chiang and Choi 2008). Not predicted by secular theory is a warp in the distant Kuiper Belt (semi-major axes greater than 50 au) seen by Volk and Malhotra 2016 using KBOs from the Minor Planet Catalog. We investigate what the inclination distribution is for objects beyond Neptune as a function of semi-major axis using the OSSOS characterized sample. Through use of the OSSOS survey simulator we test various underlying orbital distributions and compare how the survey would have observed those populations to the actual observed sample. In particular, we test various widths for the inclination distribution about various local forcing planes for the kernel, stirred, and hot classical Kuiper Belt. We find that the forced plane in matches well with the expected forced plane from secular theory. Through most of the main Kuiper Belt (between the 3:2 and 2:1 resonances), we can reject both the ecliptic plane and the invariable plane as the true forced plane. Only as the expected secularly forced plane approaches the invariable plane does the invariable plane become non-rejectable. In the outer Kuiper Belt we reject the nominal mean-plane measured by Volk and Malhotra, but smaller warps are still allowed by the data.

Tidal friction and the early history of the moon's orbit

NASA Technical Reports Server (NTRS)

Rubincam, D. P.

1975-01-01

The present work investigates the consequences implied by various rheological models of the early earth for the orbital history of the moon subsequent to its formation. Models of the earth that yield small tidal angles, such as low-viscosity models, imply that the moon never orbited in the earth's equatorial plane, thereby ruling out an equatorial origin for the moon. A high-viscosity model is shown to permit the moon to originate in the equatorial plane and still account for the present-day characteristics of the moon's orbit.

X-ray diffraction analysis of 4- and 4'-substituted C n H2 n + 1O-C6H3(OH)-CH=N-C6H4-C m H2 m + 1 ( n/ m = 2/1 and 3/4) salicylideneanilines

NASA Astrophysics Data System (ADS)

Kuz'mina, L. G.; Navasardyan, M. A.; Mikhailov, A. A.

2017-11-01

X-ray diffraction study of two crystalline modifications of C2H5O-C6H3(OH)-CH=N-C6H4-CH3 ( 1a, sp. gr. P21/ n, and 1b, sp. gr. C2/c) and C3H7O-C6H3(OH)-CH=N-C6H4-C4H9 ( 2, sp. gr. P212121) has been performed. The 1a crystal structure contains two independent molecules. The molecules are conformationally nonrigid with respect to the mutual rotation of benzene rings; the dihedral angles between their planes are 29.19° and 26.00° in the independent molecules of 1a, 18.72° in the molecule of 1b, and 50.35° in the molecule of 2. The crystal packing of the compounds is discussed.

What is the best bonding model of the (σ-H-BR) species bound to a transition metal? Bonding analysis in complexes [(H)2Cl(PMe3)2M(σ-H-BR)] (M = Fe, Ru, Os).

PubMed

Pandey, Krishna K

2012-03-21

Density Functional Theory calculations have been performed for the σ-hydroboryl complexes of iron, ruthenium and osmium [(H)(2)Cl(PMe(3))(2)M(σ-H-BR)] (M = Fe, Ru, Os; R = OMe, NMe(2), Ph) at the BP86/TZ2P/ZORA level of theory in order to understand the interactions between metal and HBR ligands. The calculated geometries of the complexes [(H)(2)Cl(PMe(3))(2)Ru(HBNMe(2))], [(H)(2)Cl(PMe(3))(2)Os(HBR)] (R = OMe, NMe(2)) are in excellent agreement with structurally characterized complexes [(H)(2)Cl(P(i)Pr(3))(2)Os(σ-H-BNMe(2))], [(H)(2)Cl(P(i)Pr(3))(2)Os{σ-H-BOCH(2)CH(2)OB(O(2)CH(2)CH(2))}] and [(H)(2)Cl(P(i)Pr(3))(2)Os(σ-H-BNMe(2))]. The longer calculated M-B bond distance in complex [(H)(2)Cl(PMe(3))(2)M(σ-H-BNMe(2))] are due to greater B-N π bonding and as a result, a weaker M-B π-back-bonding. The B-H2 bond distances reveal that (i) iron complexes contain bis(σ-borane) ligand, (ii) ruthenium complexes contain (σ-H-BR) ligands with a stretched B-H2 bond, and (iii) osmium complexes contain hydride (H2) and (σ-H-BR) ligands. The H-BR ligands in osmium complexes are a better trans-directing ligand than the Cl ligand. Values of interaction energy, electrostatic interaction, orbital interaction, and bond dissociation energy for interactions between ionic fragments are very large and may not be consistent with M-(σ-H-BR) bonding. The EDA as well as NBO and AIM analysis suggest that the best bonding model for the M-σ-H-BR interactions in the complexes [(H)(2)Cl(PMe(3))(2)M(σ-H-BR)] is the interaction between neutral fragments [(H)(2)Cl(PMe(3))(2)M] and [σ-H-BR]. This becomes evident from the calculated values for the orbital interactions. The electron configuration of the fragments which is shown for C in Fig. 1 experiences the smallest change upon the M-σ-H-BR bond formation. Since model C also requires the least amount of electronic excitation and geometry changes of all models given by the ΔE(prep) values, it is clearly the most appropriate choice of

Laser sculpting of atomic sp, sp(2) , and sp(3) hybrid orbitals.

PubMed

Liu, Chunmei; Manz, Jörn; Yang, Yonggang

2015-01-12

Atomic sp, sp(2) , and sp(3) hybrid orbitals were introduced by Linus Pauling to explain the nature of the chemical bond. Quantum dynamics simulations show that they can be sculpted by means of a selective series of coherent laser pulses, starting from the 1s orbital of the hydrogen atom. Laser hybridization generates atoms with state-selective electric dipoles, opening up new possibilities for the study of chemical reaction dynamics and heterogeneous catalysis. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Interactive orbital proximity operations planning system

NASA Technical Reports Server (NTRS)

Grunwald, Arthur J.; Ellis, Stephen R.

1989-01-01

An interactive, graphical proximity operations planning system was developed which allows on-site design of efficient, complex, multiburn maneuvers in the dynamic multispacecraft environment about the space station. Maneuvering takes place in, as well as out of, the orbital plane. The difficulty in planning such missions results from the unusual and counterintuitive character of relative orbital motion trajectories and complex operational constraints, which are both time varying and highly dependent on the mission scenario. This difficulty is greatly overcome by visualizing the relative trajectories and the relative constraints in an easily interpretable, graphical format, which provides the operator with immediate feedback on design actions. The display shows a perspective bird's-eye view of the space station and co-orbiting spacecraft on the background of the station's orbital plane. The operator has control over two modes of operation: (1) a viewing system mode, which enables him or her to explore the spatial situation about the space station and thus choose and frame in on areas of interest; and (2) a trajectory design mode, which allows the interactive editing of a series of way-points and maneuvering burns to obtain a trajectory which complies with all operational constraints. Through a graphical interactive process, the operator will continue to modify the trajectory design until all operational constraints are met. The effectiveness of this display format in complex trajectory design is presently being evaluated in an ongoing experimental program.

Has Nemesis' orbit been detected?

NASA Technical Reports Server (NTRS)

Delsemme, A. H.

1986-01-01

The orbital angular momenta of 126 very young comets are calculated from the orbital data of Marsden and Roemer (1982) and analyzed statistically. A large anisotropy is detected in a plane almost perpendicular to the ecliptic and shown to have a characteristic dissipation lifetime of 10-30 Myr. Dynamic evolution computations indicate that the impulse which produced the anisotropy is that of a very slow massive (10-90 Jupiter mass) body, which is bound to the solar system, passed its 15,000-35,000-AU perihelion about 2-15 Myr ago, and has period 5-50 Myr. It is suggested that this body could well be identical to Nemesis, the object proposed to explain mass faunal extinctions.

Orbital selective spin-texture in a topological insulator

DOE Office of Scientific and Technical Information (OSTI.GOV)

Singh, Bahadur, E-mail: bahadursingh24@gmail.com; Prasad, R.

Three-dimensional topological insulators support a metallic non-trivial surface state with unique spin texture, where spin and momentum are locked perpendicular to each other. In this work, we investigate the orbital selective spin-texture associated with the topological surface states in Sb2Te{sub 3}, using the first principles calculations. Sb2Te{sub 3} is a strong topological insulator with a p-p type bulk band inversion at the Γ-point and supports a single topological metallic surface state with upper (lower) Dirac-cone has left (right) handed spin-texture. Here, we show that the topological surface state has an additional locking between the spin and orbitals, leading to anmore » orbital selective spin-texture. The out-of-plane orbitals (p{sub z} orbitals) have an isotropic orbital texture for both the Dirac cones with an associated left and right handed spin-texture for the upper and lower Dirac cones, respectively. In contrast, the in-planar orbital texture (p{sub x} and p{sub y} projections) is tangential for the upper Dirac-cone and is radial for the lower Dirac-cone surface state. The dominant in-planar orbital texture in both the Dirac cones lead to a right handed orbital-selective spin-texture.« less

Out of plane magnetoresistance of organic superconductors; κ-(BEDT)2 salts

NASA Astrophysics Data System (ADS)

Maki, Kazumi; Won, Hye Kyung

1998-03-01

It is well documented that the out of plane manetoresistances of κ-(BEDT)_2X with X=Cu(NCS)2 and Cu[N(Cu)_2]Br exhibit a sharp peak before disappearance in the superconducting state (H. Ito et al. J. of Superconductivity 7), 667 (1994). ^, (M. V. Kartsovnik, (private communication).). We analyze this feature in terms of the superconducting fluctuation. Indeed, generalizing the formula for the clean limit (V. V. Dorin et al. Phys. Rev. B 48), 12951 (1993)., the superconducting fluctuation accounts for both the field and the temperature dependence of the magnetoresistance. In this description, d-wave nature of the superconducting order parameter in organic superconductors is crucial.

Spin-Orbit Torque-Assisted Switching in Magnetic Insulator Thin Films with Perpendicular Magnetic Anisotropy

NASA Astrophysics Data System (ADS)

Wu, Mingzhong

As an in-plane charge current flows in a heavy metal film with spin-orbit coupling, it produces a torque that can induce magnetization switching in a neighboring ferromagnetic metal film. Such spin-orbit torque (SOT)-induced switching has been studied extensively in recent years and has shown higher efficiency than switching using conventional spin-transfer torque. This presentation reports the SOT-assisted switching in heavy metal/magnetic insulator systems.1 The experiments made use of Pt/BaFe12O19 bi-layered structures. Thanks to its strong spin-orbit coupling, Pt has been widely used to produce pure spin currents in previous studies. BaFe12O19 is an M-type barium hexagonal ferrite and is often referred as BaM. It is one of the few magnetic insulators with strong magneto-crystalline anisotropy and shows an effective uniaxial anisotropy field of about 17 kOe. It's found that the switching response in the BaM film strongly depends on the charge current applied to the Pt film. When a constant magnetic field is applied in the film plane, the charge current in the Pt film can switch the normal component of the magnetization (M⊥) in the BaM film between the up and down states. The current also dictates the up and down states of the remnant magnetization when the in-plane field is reduced to zero. When M⊥ is measured by sweeping an in-plane field, the response manifests itself as a hysteresis loop, which evolves in a completely opposite manner if the sign of the charge current is flipped. When the coercivity is measured by sweeping an out-of-plane field, its value can be reduced or increased by as much as about 500 Oe if an appropriate charge current is applied. 1. P. Li, T. Liu, H. Chang, A. Kalitsov, W. Zhang, G. Csaba, W. Li, D. Richardson, A. Demann, G. Rimal, H. Dey, J. S. Jiang, W. Porod, S. Field, J. Tang, M. C. Marconi, A. Hoffmann, O. Mryasov, and M. Wu, Nature Commun. 7:12688 doi: 10.1038/ncomms12688 (2016).

Interactive orbital proximity operations planning system

NASA Technical Reports Server (NTRS)

Grunwald, Arthur J.; Ellis, Stephen R.

1990-01-01

An interactive graphical planning system for on-site planning of proximity operations in the congested multispacecraft environment about the space station is presented. The system shows the astronaut a bird's eye perspective of the space station, the orbital plane, and the co-orbiting spacecraft. The system operates in two operational modes: (1) a viewpoint mode, in which the astronaut is able to move the viewpoint around in the orbital plane to range in on areas of interest; and (2) a trajectory design mode, in which the trajectory is planned. Trajectory design involves the composition of a set of waypoints which result in a fuel-optimal trajectory which satisfies all operational constraints, such as departure and arrival constraints, plume impingement constraints, and structural constraints. The main purpose of the system is to present the trajectory and the constraints in an easily interpretable graphical format. Through a graphical interactive process, the trajectory waypoints are edited until all operational constraints are satisfied. A series of experiments was conducted to evaluate the system. Eight airline pilots with no prior background in orbital mechanics participated in the experiments. Subject training included a stand-alone training session of about 6 hours duration, in which the subjects became familiar with orbital mechanics concepts and performed a series of exercises to familiarize themselves with the control and display features of the system. They then carried out a series of production runs in which 90 different trajectory design situations were randomly addressed. The purpose of these experiments was to investigate how the planning time, planning efforts, and fuel expenditures were affected by the planning difficulty. Some results of these experiments are presented.

Structures, molecular orbitals and UV-vis spectra investigations on methyl 1-benzyl-1H-1,2,3-triazole-4-carboxylate: a computational study.

PubMed

Wang, Tsang-Hsiu; Chu, Hsing-Yu; Wang, I-Teng

2014-10-15

The methyl 1-benzyl-1H-1,2,3-triazole-4-carboxylate (C11H11N3O2) has been studied by theoretically methods. The structure of this compound is optimized by density functional theory (DFT), the second-order Møller-Plesset perturbation theory (MP2) and G3 theory (G3(MP2)) levels. Our calculation results are in very good agreement with experimental values. Compared to a perfect pentagonal structure, the geometrical structures of C11H11N3O2 show a little distortion of 1,2,3-triazole ring due to the highly electronegativity of substitution groups. In addition, dipole moment and frontier molecular orbitals (FMOs) of the C11H11N3O2 are calculated as well. Because of solvent effect, the HOMO-LUMO energy gap in methanol is predicted to be smaller than in gas phase by 0.367eV. The simulated UV-vis spectra are investigated by time-dependent density functional theory (TD-DFT), and two obviously absorption features have been predicted. These two absorption features are located between 170nm and 210nm, which is in ultraviolet C range. Moreover, the UV absorption features in methanol are predicted to be more intense than in gas phase; besides, the red shift is predicted in methanol as well. Copyright © 2014 Elsevier B.V. All rights reserved.

Human Mars Mission: Launch Window from Earth Orbit. Pt. 1

NASA Technical Reports Server (NTRS)

Young, Archie

1999-01-01

The determination of orbital window characteristics is of major importance in the analysis of human interplanetary missions and systems. The orbital launch window characteristics are directly involved in the selection of mission trajectories, the development of orbit operational concepts, and the design of orbital launch systems. The orbital launch window problem arises because of the dynamic nature of the relative geometry between outgoing (departure) asymptote of the hyperbolic escape trajectory and the earth parking orbit. The orientation of the escape hyperbola asymptotic relative to earth is a function of time. The required hyperbola energy level also varies with time. In addition, the inertial orientation of the parking orbit is a function of time because of the perturbations caused by the Earth's oblateness. Thus, a coplanar injection onto the escape hyperbola can be made only at a point in time when the outgoing escape asymptote is contained by the plane of parking orbit. Even though this condition may be planned as a nominal situation, it will not generally represent the more probable injection geometry. The general case of an escape injection maneuver performed at a time other than the coplanar time will involve both a path angle and plane change and, therefore, a DELTA V penalty. Usually, because of the DELTA V penalty the actual departure injection window is smaller in duration than that determined by energy requirement alone. This report contains the formulation, characteristics, and test cases for five different launch window modes for Earth orbit. These modes are: (1) One impulsive maneuver from a Highly Elliptical Orbit (HEO) (2) Two impulsive maneuvers from a Highly Elliptical Orbit (HEO) (3) One impulsive maneuver from a Low Earth Orbit (LEO) (4) Two impulsive maneuvers from LEO (5) Three impulsive maneuvers from LEO.

Spin-orbit torques from interfacial spin-orbit coupling for various interfaces

NASA Astrophysics Data System (ADS)

Kim, Kyoung-Whan; Lee, Kyung-Jin; Sinova, Jairo; Lee, Hyun-Woo; Stiles, M. D.

2017-09-01

We use a perturbative approach to study the effects of interfacial spin-orbit coupling in magnetic multilayers by treating the two-dimensional Rashba model in a fully three-dimensional description of electron transport near an interface. This formalism provides a compact analytic expression for current-induced spin-orbit torques in terms of unperturbed scattering coefficients, allowing computation of spin-orbit torques for various contexts, by simply substituting scattering coefficients into the formulas. It applies to calculations of spin-orbit torques for magnetic bilayers with bulk magnetism, those with interface magnetism, a normal-metal/ferromagnetic insulator junction, and a topological insulator/ferromagnet junction. It predicts a dampinglike component of spin-orbit torque that is distinct from any intrinsic contribution or those that arise from particular spin relaxation mechanisms. We discuss the effects of proximity-induced magnetism and insertion of an additional layer and provide formulas for in-plane current, which is induced by a perpendicular bias, anisotropic magnetoresistance, and spin memory loss in the same formalism.

Spin-orbit torques from interfacial spin-orbit coupling for various interfaces.

PubMed

Kim, Kyoung-Whan; Lee, Kyung-Jin; Sinova, Jairo; Lee, Hyun-Woo; Stiles, M D

2017-09-01

We use a perturbative approach to study the effects of interfacial spin-orbit coupling in magnetic multilayers by treating the two-dimensional Rashba model in a fully three-dimensional description of electron transport near an interface. This formalism provides a compact analytic expression for current-induced spin-orbit torques in terms of unperturbed scattering coefficients, allowing computation of spin-orbit torques for various contexts, by simply substituting scattering coefficients into the formulas. It applies to calculations of spin-orbit torques for magnetic bilayers with bulk magnetism, those with interface magnetism, a normal metal/ferromagnetic insulator junction, and a topological insulator/ferromagnet junction. It predicts a dampinglike component of spin-orbit torque that is distinct from any intrinsic contribution or those that arise from particular spin relaxation mechanisms. We discuss the effects of proximity-induced magnetism and insertion of an additional layer and provide formulas for in-plane current, which is induced by a perpendicular bias, anisotropic magnetoresistance, and spin memory loss in the same formalism.

Spin-orbit torques from interfacial spin-orbit coupling for various interfaces

PubMed Central

Kim, Kyoung-Whan; Lee, Kyung-Jin; Sinova, Jairo; Lee, Hyun-Woo; Stiles, M. D.

2017-01-01

We use a perturbative approach to study the effects of interfacial spin-orbit coupling in magnetic multilayers by treating the two-dimensional Rashba model in a fully three-dimensional description of electron transport near an interface. This formalism provides a compact analytic expression for current-induced spin-orbit torques in terms of unperturbed scattering coefficients, allowing computation of spin-orbit torques for various contexts, by simply substituting scattering coefficients into the formulas. It applies to calculations of spin-orbit torques for magnetic bilayers with bulk magnetism, those with interface magnetism, a normal metal/ferromagnetic insulator junction, and a topological insulator/ferromagnet junction. It predicts a dampinglike component of spin-orbit torque that is distinct from any intrinsic contribution or those that arise from particular spin relaxation mechanisms. We discuss the effects of proximity-induced magnetism and insertion of an additional layer and provide formulas for in-plane current, which is induced by a perpendicular bias, anisotropic magnetoresistance, and spin memory loss in the same formalism. PMID:29333523

A comparative study of the Au + H{sub 2}, Au{sup +} + H{sub 2}, and Au{sup −} + H{sub 2} systems: Potential energy surfaces and dynamics of reactive collisions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dorta-Urra, Anaís; Zanchet, Alexandre; Roncero, Octavio

2015-04-21

In order to study the Au{sup −} + H{sub 2} collision, a new global potential energy surface (PES) describing the ground electronic state of AuH{sub 2}{sup −} system is developed and compared with the PESs of the neutral [Zanchet et al., J. Chem. Phys. 132, 034301 (2010)] and cationic systems [Anaís et al., J. Chem. Phys. 135, 091102 (2011)]. We found that Au{sup −} − H{sub 2} presents a H-Au-H insertion minimum attributed to the stabilization of the LUMO 3b{sub 2} orbital, which can be considered as the preamble of the chemisorption well appearing in larger gold clusters. While themore » LUMO orbital is stabilized, the HOMO 6a{sub 1} is destabilized, creating a barrier at the geometry where the energy orbitals’ curves are crossing. In the anion, this HOMO is doubly occupied, while in the neutral system is half-filled and completely empty in the cation, explaining the gradual disappearance of the well and the barrier as the number of electrons decreases. The cation presents a well in the entrance channel partially explained by electrostatic interactions. The three systems’ reactions are highly endothermic, by 1.66, 2.79, and 3.23 eV for AuH, AuH{sup +}, and AuH{sup −} products, respectively. The reaction dynamics is studied using quasi-classical trajectory method for the three systems. The one corresponding to the anionic system is new in this work. Collision energies between 1.00 and 8.00 eV, measured for the cation, are in good agreement with the simulated cross section for the AuH{sup +}. It was also found that the total fragmentation, in three atoms, competes becoming dominant at sufficiently high energy. Here, we study the competition between the two different reaction pathways for the anionic, cationic, and neutral species, explaining the differences using a simple model based on the topology of the potential energy surfaces.« less

Tunable anomalous orbital structure in a spinel-perovskite interface γ-Al2O3/SrTiO3

NASA Astrophysics Data System (ADS)

Cao, Yanwei; Liu, Xiaoran; Shafer, Padraic; Middey, Srimanta; Meyers, Derek; Kareev, Mikhail; Zhong, Zhicheng; Kim, Jong-Woo; Ryan, Philip; Arenholz, Elke; Chakhalian, Jak

In all archetypical reported (001)-oriented perovskite heterostructures, for example LaTiO3/SrTiO3, LaAlO3/SrTiO3,YTiO3/SrTiO3 and so on, it has been deduced that the preferential occupation of two-dimensional electron gases is in-plane dxy state. In sharp contrast to this, the investigated electronic structure of a spinel-perovskite heterostructure γ-Al2O3/SrTiO3 by resonant soft X-ray linear dichroism, demonstrates that the preferential occupation is in out-of-plane dxz/dyz states for interfacial electrons. Moreover, the impact of strain further corroborates that this anomalous orbital structure can be linked to the altered crystal field at the interface and symmetry breaking of the interfacial structural units. Our findings provide another interesting route to engineer emergent quantum states with deterministic orbital symmetry. J.C. and Y.C. was supported by the Gordon and Betty Moore Foundation EPiQS Initiative through Grant No. GBMF4534. S.M. and M.K. were supported by the DOD-ARO under Grant No. 0402-172.

2-tier in-plane motion correction and out-of-plane motion filtering for contrast-enhanced ultrasound.

PubMed

Ta, Casey N; Eghtedari, Mohammad; Mattrey, Robert F; Kono, Yuko; Kummel, Andrew C

2014-11-01

Contrast-enhanced ultrasound (CEUS) cines of focal liver lesions (FLLs) can be quantitatively analyzed to measure tumor perfusion on a pixel-by-pixel basis for diagnostic indication. However, CEUS cines acquired freehand and during free breathing cause nonuniform in-plane and out-of-plane motion from frame to frame. These motions create fluctuations in the time-intensity curves (TICs), reducing the accuracy of quantitative measurements. Out-of-plane motion cannot be corrected by image registration in 2-dimensional CEUS and degrades the quality of in-plane motion correction (IPMC). A 2-tier IPMC strategy and adaptive out-of-plane motion filter (OPMF) are proposed to provide a stable correction of nonuniform motion to reduce the impact of motion on quantitative analyses. A total of 22 cines of FLLs were imaged with dual B-mode and contrast specific imaging to acquire a 3-minute TIC. B-mode images were analyzed for motion, and the motion correction was applied to both B-mode and contrast images. For IPMC, the main reference frame was automatically selected for each cine, and subreference frames were selected in each respiratory cycle and sequentially registered toward the main reference frame. All other frames were sequentially registered toward the local subreference frame. Four OPMFs were developed and tested: subsample normalized correlation (NC), subsample sum of absolute differences, mean frame NC, and histogram. The frames that were most dissimilar to the OPMF reference frame using 1 of the 4 above criteria in each respiratory cycle were adaptively removed by thresholding against the low-pass filter of the similarity curve. Out-of-plane motion filter was quantitatively evaluated by an out-of-plane motion metric (OPMM) that measured normalized variance in the high-pass filtered TIC within the tumor region-of-interest with low OPMM being the goal. Results for IPMC and OPMF were qualitatively evaluated by 2 blinded observers who ranked the motion in the cines

Dynamics of chiral domain wall under the spin-orbit torques in heavy metal/ferromagnet bilayers with in-plane anisotropy

NASA Astrophysics Data System (ADS)

Yan, Han; He, Peng-Bin; Cai, Meng-Qiu; Li, Zai-Dong

2017-11-01

The dynamics of domain wall driven by the spin-orbit torques is theoretically studied in the heavy metal/ferromagnet bilayer with Dzyaloshinskii-Moriya interaction (DMI) and in-plane magnetic anisotropy. Based on the Walker profile, we infer that DMI has a selectivity for the chirality of head-to-head (tail-to-tail) static wall. By analyzing the dynamic equations obtained from the collective coordinates methods, we find that there exists a switching or a hysteresis of the polarity of wall in the low-current regime. In the presence of DMI, the wall can keep sustained propagation which velocity saturates for high current and is proportional to the strength of DMI. Furthermore, the DMI makes the adjacent walls possess the same chirality and move in the same direction.

Nearly massless Dirac fermions hosted by Sb square net in BaMnSb2

PubMed Central

Liu, Jinyu; Hu, Jin; Cao, Huibo; Zhu, Yanglin; Chuang, Alyssa; Graf, D.; Adams, D. J.; Radmanesh, S. M. A.; Spinu, L.; Chiorescu, I.; Mao, Zhiqiang

2016-01-01

Layered compounds AMnBi2 (A = Ca, Sr, Ba, or rare earth element) have been established as Dirac materials. Dirac electrons generated by the two-dimensional (2D) Bi square net in these materials are normally massive due to the presence of a spin-orbital coupling (SOC) induced gap at Dirac nodes. Here we report that the Sb square net in an isostructural compound BaMnSb2 can host nearly massless Dirac fermions. We observed strong Shubnikov-de Haas (SdH) oscillations in this material. From the analyses of the SdH oscillations, we find key signatures of Dirac fermions, including light effective mass (~0.052m0; m0, mass of free electron), high quantum mobility (1280 cm2V−1S−1) and a π Berry phase accumulated along cyclotron orbit. Compared with AMnBi2, BaMnSb2 also exhibits much more significant quasi two-dimensional (2D) electronic structure, with the out-of-plane transport showing nonmetallic conduction below 120 K and the ratio of the out-of-plane and in-plane resistivity reaching ~670. Additionally, BaMnSb2 also exhibits a G-type antiferromagnetic order below 283 K. The combination of nearly massless Dirac fermions on quasi-2D planes with a magnetic order makes BaMnSb2 an intriguing platform for seeking novel exotic phenomena of massless Dirac electrons. PMID:27466151

Isotropic and anisotropic regimes of the field-dependent spin dynamics in Sr 2 IrO 4 : Raman scattering studies

DOE PAGES

Gim, Y.; Sethi, A.; Zhao, Q.; ...

2016-01-11

A major focus of experimental interest in Sr 2IrO 4 has been to clarify how the magnetic excitations of this strongly spin-orbit coupled system differ from the predictions of an isotropic 2D spin-1/2 Heisenberg model and to explore the extent to which strong spin-orbit coupling affects the magnetic properties of iridates. Here, we present a high-resolution inelastic light (Raman) scattering study of the low energy magnetic excitation spectrum of Sr 2IrO 4 and doped Eu-doped Sr 2IrO 4 as functions of both temperature and applied magnetic field. We show that the high-field (H > 1.5 T) in-plane spin dynamics ofmore » Sr 2IrO 4 are isotropic and governed by the interplay between the applied field and the small in-plane ferromagnetic spin components induced by the Dzyaloshinskii-Moriya interaction. However, the spin dynamics of Sr 2IrO 4 at lower fields (H < 1.5 T) exhibit important effects associated with interlayer coupling and in-plane anisotropy, including a spin-flop transition at Hc in Sr 2IrO 4 that occurs either discontinuously or via a continuous rotation of the spins, depending upon the in-plane orientation of the applied field. Furthermore, these results show that in-plane anisotropy and interlayer coupling effects play important roles in the low-field magnetic and dynamical properties of Sr 2IrO 4.« less

Orbital resonances of Taiwan's FORMOSAT-2 remote sensing satellite

NASA Astrophysics Data System (ADS)

Lin, Shin-Fa; Hwang, Cheinway

2018-06-01

Unlike a typical remote sensing satellite that has a global coverage and non-integral orbital revolutions per day, Taiwan's FORMOSAT-2 (FS-2) satellite has a non-global coverage due to the mission requirements of one-day repeat cycle and daily visit around Taiwan. These orbital characteristics result in an integer number of revolutions a day and orbital resonances caused by certain components of the Earth's gravity field. Orbital flight data indicated amplified variations in the amplitudes of FS-2's Keplerian elements. We use twelve years of orbital observations and maneuver data to analyze the cause of the resonances and explain the differences between the simulated (at the pre-launch stage) and real orbits of FS-2. The differences are quantified using orbital perturbation theories that describe secular and long-period orbital evolutions caused by resonances. The resonance-induced orbital rising rate of FS-2 reaches +1.425 m/day, due to the combined (modeled) effect of resonances and atmospheric drags (the relative modeling errors < 10%). The concave shapes in the time-evolution of the longitude of descending node (LonDN) coincide with the positive rates of daily semi-major axis (SMA) change, also caused by resonances. The non-zonal geopotential coefficients causing the resonance effects contributed up to 45% of FS-2's inclination decline. Our retrospective analysis of FS-2's resonant orbit can provide lessons for a remote sensing mission similar to FS-2, especially in the early mission design and planning phase.

Quantum scattering studies of spin-orbit effects in the Cl({sup 2}P) + HCl {yields} ClH + Cl({sup 2}P) reaction

DOE Office of Scientific and Technical Information (OSTI.GOV)

Schatz, G.C.; McCabe, P.; Connor, J.N.L.

1998-07-01

The authors present quantum scattering calculations for the Cl + HCl {yields} ClH + Cl reaction in which they include the three electronic states that correlate asymptotically to the ground state of Cl({sup 2}P) + HCl(X{sup 1}{Sigma}{sup +}). The potential surfaces and couplings are taken from the recent work of C.S. Maierle, G.C. Schatz, M.S. Gordon, P. McCabe and J.N.L. Connor, J. Chem. Soc. Farad. Trans. (1997). They are based on extensive ab initio calculations for geometries in the vicinity of the lowest energy saddle point, and on an electrostatic expansion (plus empirical dispersion and repulsion) for long range geometriesmore » including the van der Waals wells. Spin-orbit coupling has been included using a spin-orbit coupling parameter {lambda} that is assumed to be independent of nuclear geometry, and Coriolis interactions are incorporated accurately. The scattering calculations use a hyperspherical coordinate coupled channel method in full dimensionality. AJ-shifting approximation is employed to convert cumulative reaction probabilities for total angular momentum quantum number J = 1/2 into state selected and thermal rate coefficients. Two issues have been studied: (a) the influence of the magnitude of {lambda} on the fine-structure resolved cumulative probabilities and rate coefficients (the authors consider {lambda}`s that vary from 0 to {+-}100% of the true Cl value), and (b) the transition state resonance spectrum, and its variation with {lambda} and with other parameters in the calculations. Cl + HCl is a simple hydrogen transfer reaction which serves as a canonical model both for heavy-light-heavy atom reactions, and for the reactions of halogen atoms with closed shell molecules.« less

The 1995 Saturn Ring-Plane Crossings: Ring Thickness and Small Inner Satellites

NASA Astrophysics Data System (ADS)

Poulet, F.; Sicardy, B.

1996-09-01

The May 22() th and August 10() th, 1995, Saturn ring-plane crossings by the Earth were observed from the 2-m and 1-m telescopes at Pic du Midi, the 2.2-m telescope of the University of Hawaii, and with the Adonis adaptive optics camera at the 3.6-m telescope of the European Southern Observatory (ESO). Observations were made with either a 0.9 mu m or 2.2 mu m (short K) methane band filter. The radial brightness profiles of the rings indicate that the outer F ring dominates the apparent edge-on thickness of the system, with a vertically integrated equivalent width of 0.8-1.0 km near a radius of 130,000 km. The photometric behaviors of the A, B, and C rings and of the Cassini Division have been analyzed using a classical radiative transfer code which includes illumination by the Sun and by the planet. The F ring is modelled as a physically thick ribbon (thickness h) composed of large particles embedded in dust. The observed profiles can be explained if the F ring is both optically thick (tau ~ 0.15-0.25), and physically thick (h at least ~ 1.5 km). The large particles dominate the F ring's photometric behavior in backscattered light. Constraints on the particle properties in the other rings have been derived. The dimming of the rings around August 10, 1995 provided ideal conditions to study the small inner satellites. Besides Janus, Epimetheus and Pandora, two unresolved objects were detected in the ESO frames. They have been identified with the objects 1995S5 and 1995S6, detected several hours later by the Hubble Space Telescope (Nicholson et al. 1996, Science 272, 509--515). Combining the ESO and HST data, we derive orbital and photometric parameters for these objects. In particular, we improve the orbital parameters of 1995S5, whose orbital radius is now close to that of the F ring.

The Orbit and Distance of WR140

NASA Astrophysics Data System (ADS)

Dougherty, S. M.; Trenton, V.; Beasley, A. J.

2011-01-01

A campaign of 35 epochs of milli-arcsecond resolution VLBA observations of the archetype colliding-wind WR+O star binary system WR 140 show the wind-collision region (WCR) as a bow-shaped arc of emission that rotates as the highly eccentric orbit progresses. The observations comprise 21 epochs from the 1993-2001 orbit, discussed by Dougherty et al. (2005), and 14 epochs from the 2001-2009 orbit, and span orbital phase 0.43 to 0.95. Assuming the WCR is symmetric about the line-of-centres of the two stars and ``points'' at the WR star, this rotation shows the O star moving from SE to E of the WR star between these orbital phases. Using IR interferometry observations from IOTA that resolve both stellar components at phase 0.297 in conjunction with orbital parameters derived from radial velocity variations, the VLBA observations constrain the inclination of the orbit plane as 120°±4°, the longitude of the ascending node as 352°±2°, and the orbit semi-major axis as 9.0±0.1 mas. This leads to a distance estimate to WR 140 of 1.81±0.08 kpc. Further refinements of the orbit and distance await more IR interferometric observations of the stellar components directly.

Orbitally excited spectra and decay of cc¯ meson

NASA Astrophysics Data System (ADS)

Chaturvedi, Raghav; Rai, A. K.

2018-05-01

We use the hydrogen like trial wave function for computation of the mass spectra and decay properties of charmonia within the framework of phenomenological quark anti-quark Coulomb plus power potential with varying potential index from 0.5 to 2.0. The spin-spin hyperfine interaction is considered to incorporate splitting of the ground and radially excited states energy levels, further spin-orbit and tensor interactions are employed to calculate the masses of orbitally excited states. We construct the Regge trajectories from the mass spectra in (J, M2) and (nr, M2) planes. We also compute γγ decay width of P wave states of cc¯.

Orbital stability of the unseen solar companion linked to periodic extinction events

NASA Technical Reports Server (NTRS)

Torbett, M. V.; Smoluchowski, R.

1984-01-01

Evidence from three-dimensional numerical modelling is presented that only cometary orbits with a limited range in inclination with respect to the galactic plane are formally stable for the length of time required to cause periodic extinction events. The calculations were done using Cowell's method employing a fourth-order Runge-Kutta integration scheme in an inertial reference frame in orbit about the Galaxy. Tidal perturbations in the radial direction due to the Galaxy and the Coriolis forces are included. The vertical component of the gravitational field of the galactic disk is superimposed on these forces. The results indicate that orbits for Nemesis that are inclined at more than 30 deg to the galactic plane are not allowed and suggests that the search for Nemesis should be concentrated toward the plane of the Galaxy. Perturbations by passing stars or molecular clouds may make even the low-inclination orbits unstable.

Dehydration of the Uranyl Peroxide Studtite, [UO 2(η 2-O 2)(H 2O) 2]·2H 2O, Affords a Drastic Change in the Electronic Structure: A Combined X-ray Spectroscopic and Theoretical Analysis

DOE Office of Scientific and Technical Information (OSTI.GOV)

Vitova, Tonya; Pidchenko, Ivan; Biswas, Saptarshi

The dehydration of studtite, [UO 2(2-O 2)(H 2O)2]·2H 2O, to metastudtite, [UO 2(2-O 2)(H 2O) 2], uranyl peroxide minerals that are major oxidative alteration phases of UO2 under conditions of geological storage, has been studied using X-ray photoelectron spectroscopy (XPS) and X-ray absorption spectroscopy. XPS of the U 4f region shows small but significant differences between studtite and metastudtite, with the 4f binding energy of studtite the highest reported for a uranyl mineral studied by this technique. Further information on the changes in the electronic structure was elucidated using U M4-edge High Energy Resolution XANES (HR-XANES) spectroscopy, which directly probesmore » f-orbital states. The transition from the 3d to the 5f* orbital is sensitive to variations of the U=Oaxial bond length and to changes in the bond covalency. We report evidences that the covalence in the uranyl fragment decreases upon dehydration. Photoluminescence spectroscopy at near liquid helium temperatures reveals significant spectral differences between the two materials, correlating with the X-ray spectroscopy results. A theoretical investigation has been conducted on the structures of both studtite and metastudtite and benchmarked to the HR-XANES spectra. These illustrate the sensitivity of the 3d to the 5f * transition towards U=Oaxial bond variation.« less

Spin orbit coupling in graphene through gold intercalation

NASA Astrophysics Data System (ADS)

Mukherjee, Paromita; O'Farrell, Eoin; Tan, Jun You; Yeo, Yuting; Koon, G. K. W.; Özyilmaz, Barbaros; Watanabe, K.; Taniguchi, T.

Graphene has a very low value of spin orbit coupling. There have been several efforts to enhance the spin orbit interaction in graphene. Our previous work has provided clear evidence that spin orbit coupling can be induced in graphene through Rashba interaction with intercalated gold. By applying an additional electric field, this splitting can be increased or decreased depending on its relative direction with the internal electric field induced by gold in graphene. A large negative magnetoresistance due to an in-plane magnetic field has been observed which can be attributed to the fact that a magnetic moment is induced in gold due to spin-orbit coupling. Anomalous Hall Effect which decreases with an in-plane magnetic field further suggests the formation of a collective magnetic phase. We would like to further elaborate on the spin-orbit coupling in graphene using non local measurements. Hence, by intercalating graphene with gold, we can have a direct electric manipulation of the spin degrees of freedom and lead to its much awaited applications in spintronics, quantum computing. National University of Singapore, Singapore.

Orbits of Selected Globular Clusters in the Galactic Bulge

NASA Astrophysics Data System (ADS)

Pérez-Villegas, A.; Rossi, L.; Ortolani, S.; Casotto, S.; Barbuy, B.; Bica, E.

2018-05-01

We present orbit analysis for a sample of eight inner bulge globular clusters, together with one reference halo object. We used proper motion values derived from long time base CCD data. Orbits are integrated in both an axisymmetric model and a model including the Galactic bar potential. The inclusion of the bar proved to be essential for the description of the dynamical behaviour of the clusters. We use the Monte Carlo scheme to construct the initial conditions for each cluster, taking into account the uncertainties in the kinematical data and distances. The sample clusters show typically maximum height to the Galactic plane below 1.5 kpc, and develop rather eccentric orbits. Seven of the bulge sample clusters share the orbital properties of the bar/bulge, having perigalactic and apogalatic distances, and maximum vertical excursion from the Galactic plane inside the bar region. NGC 6540 instead shows a completely different orbital behaviour, having a dynamical signature of the thick disc. Both prograde and prograde-retrograde orbits with respect to the direction of the Galactic rotation were revealed, which might characterise a chaotic behaviour.

New LaMAsH(x) (M = Co, Ni, or Cu) arsenides with covalent M-H chains.

PubMed

Mizoguchi, Hiroshi; Park, SangWon; Hiraka, Haruhiro; Ikeda, Kazutaka; Otomo, Toshiya; Hosono, Hideo

2014-12-17

A new series of tetragonal LaPtSi-type mixed-anion arsenides, LaMAsH(x) (M = Co, Ni, or Cu), has been synthesized using high-temperature and high-pressure techniques. The crystal structure of these intermetallic compounds determined via powder neutron diffraction is composed of a 3D framework of three connected planes with the La ions filling the cavities in the structure. Each late transition-metal ion M, all of which have relatively large electronegativities, behaves like a main group element and forms a planar coordination configuration with three As ions. The trigonal-bipyramidal coordination adopted by the H in the cavity, HM2La3, is compressed along the C3 axis, and unusual M-H chains run along the x and y directions, reinforcing the covalent framework. These chains, which are unique in solids, are stabilized by covalent interactions between the M 4s and H 1s orbitals.

2. VIEW SOUTH, PERSPECTIVE OF ABUTMENT AND INCLINED PLANE ON ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

2. VIEW SOUTH, PERSPECTIVE OF ABUTMENT AND INCLINED PLANE ON WEST SIDE OF PA ROUTE 56 - Laurel Hill Quarry, Incline Plane, Both sides of State Route 56, 2.4 miles East of State Route 711, Seward, Westmoreland County, PA

4-(4-Methoxy­phen­yl)-1-phenyl­pyridine-2,6(1H,3H)-dione

PubMed Central

Das, Ushati; Chheda, Shardul B.; Pednekar, Suhas R.; Karambelkar, Narendra P.; Guru Row, T. N.

2009-01-01

In the title compound, C18H15NO3, the pyridine-2,6-dione ring adopts an envelope conformation. The phenyl ring lies approximately perpendicular to the mean plane of the pyridine-2,6-dione ring [dihedral angle = 81.5 (1)°], while the methoxy­phenyl ring is tilted to the same plane by a dihedral angle of 34.8 (1)°. Inter­molecular C—H⋯O inter­actions link the mol­ecules into chains along [100]. PMID:21583176

Orbital alignment of circumbinary planets that form in misaligned circumbinary discs: the case of Kepler-413b

NASA Astrophysics Data System (ADS)

Pierens, A.; Nelson, R. P.

2018-06-01

Although most of the circumbinary planets detected by the Kepler spacecraft are on orbits that are closely aligned with the binary orbital plane, the systems Kepler-413 and Kepler-453 exhibit small misalignments of ˜2.5°. One possibility is that these planets formed in a circumbinary disc whose midplane was inclined relative to the binary orbital plane. Such a configuration is expected to lead to a warped and twisted disc, and our aim is to examine the inclination evolution of planets embedded in these discs. We employed 3D hydrodynamical simulations that examine the disc response to the presence of a modestly inclined binary with parameters that match the Kepler-413 system, as a function of disc parameters and binary inclinations. The discs all develop slowly varying warps, and generally display very small amounts of twist. Very slow solid body precession occurs because a large outer disc radius is adopted. Simulations of planets embedded in these discs resulted in the planet aligning with the binary orbit plane for disc masses close to the minimum mass solar nebular, such that nodal precession of the planet was controlled by the binary. For higher disc masses, the planet maintains near coplanarity with the local disc midplane. Our results suggest that circumbinary planets born in tilted circumbinary discs should align with the binary orbit plane as the disc ages and loses mass, even if the circumbinary disc remains misaligned from the binary orbit. This result has important implications for understanding the origins of the known circumbinary planets.

A proposal for climate stability on H2-greenhouse planets

NASA Astrophysics Data System (ADS)

Abbot, D. S.

2015-12-01

A terrestrial planet in an orbit far outside of the standard habitable zone could maintain surface liquid water as a result of H2-H2 collision-induced absorption by a thick H2 atmosphere. Without a stabilizing climate feedback, however, habitability would be accidental and likely brief. We propose a stabilizing climate feedback for such a planet that requires only biological production of H2 to balance net loss to space that has some optimal temperature, and operates less efficiently at higher temperatures. A stable feedback is possible on such a planet through which a perturbation increasing temperature decreases H2 production, which decreases H2 greenhouse warming and therefore temperature. The potential of such a feedback makes H2-warmed planets more attractive astrobiological targets.

The intriguing near-ultraviolet photochemistry of H 2Te

NASA Astrophysics Data System (ADS)

Underwood, J.; Chastaing, D.; Lee, S.; Boothe, P.; Flood, T. C.; Wittig, C.

2002-08-01

The ultraviolet absorption spectrum of H 2Te has a long wavelength tail that extends to 400 nm. Photodissociation at 355 nm yields TeH( 2Π 1/2) selectively relative to the 2Π 3/2 ground state; the transition moments for these channels lie in, and perpendicular to, the molecular plane, respectively. Vibrational structure in the region 380-400 nm is consistent with a shallow well in the adiabat leading to 2Π 1/2, akin to the one in HI leading to I( 2P 1/2). These effects have no counterparts with the light Group 6A dihydrides.

Synthesis, DFT calculations, electronic structure, electronic absorption spectra, natural bond orbital (NBO) and nonlinear optical (NLO) analysis of the novel 5-methyl-8H-benzo[h]chromeno[2,3-b][1,6] naphthyridine-6(5H),8-dione (MBCND)

NASA Astrophysics Data System (ADS)

Halim, Shimaa Abdel; Ibrahim, Magdy A.

2017-02-01

New derivative of heteroannulated chromone identified as 5-methyl-8H-benzo[h]chromeno[2,3-b][1,6]naphthyridine-6(5H),8-dione (5, MBCND) was easily and efficiently synthesized from DBU catalyzed condensation reaction of 2-aminochromone-3-carboxaldehyde (1) with 4-hydroxy-1-methylquinolin-2(1H)-one (2). The same product 5 was isolated from condensation reaction of aldeyde 1 with 3-(4-hydroxy-1-methyl-2-oxo-1,2-dihydroquinolin-3-yl)-3-oxopropanoic acid (3) or ethyl 4-(4-hydroxy-1-methyl-2-oxo-1,2-dihydroquinolin-3-yl)-2,4-dioxobutanoate (4). Structure of compound (5, MBCND) was deduced based on their elemental analyses and spectral data (IR, 1H NMR and mass spectra). Density Functional Theory (DFT) calculations at the B3LYP/6-311G (d,p) level of theory have been carried out to investigate the equilibrium geometry of the novel compound (5, MBCND). Moreover, total energy, energy of HOMO and LUMO and Mullikan atomic charges were calculated. In addition, the dipole moment, theoretical study of the electronic structure, nonlinear optical properties (NLO), and natural bonding orbital (NBO) analysis and orientation have been performed and discussed. Also the electronic absorption spectra were measured in polar (methanol) as well as non polar (dioxane) solvents and the assignment of the observed bands has been discussed by TD-DFT calculations. The correspondences between calculated and experimental transitions energies are satisfactory.

Importance of projectile-target interactions in the triple differential cross sections for Low energy (e,2e) ionization of aligned H2

NASA Astrophysics Data System (ADS)

Ali, Esam; Madison, Don; Ren, X.; Dorn, A.; Ning, Chuangang

2014-10-01

Experimental and theoretical Triple Differential Cross Sections (TDCS) are presented for electron impact ionization-excitation of the 2 sσg state of H2 in the perpendicular plane. The excited 2 sσg state immediately dissociates and the alignment of the molecule is determined by detecting one of the fragments. Results are presented for three different alignments in the xy-plane (scattering plane is xz)-alignment along y-axis, x-axis, and 45° between the x- and y-axes for incident electron energies of 4, 10, and 25 eV and different scattered electron angles of 20° and 30° in the perpendicular plane. Theoretical M4DW (molecular 4-body distorted wave) results are compared to experimental data, and overall we found reasonably good agreement between experiment and theory. The Results show that (e,2e) cross sections for excitation-ionization depend strongly on the orientation of the H2 molecule.

2,2',5,5'-Tetra-methyl-1,1'-(hexane-1,6-di-yl)di-1H-pyrrole.

PubMed

Santos, Ana C; Ramos Silva, Manuela; Monsanto, Paula V; Matos Beja, Ana; Sobral, Abilio J F N

2009-06-17

The mol-ecule of the title compound, C(18)H(28)N(2), composed of two 2,5-dimethyl-pyrrole groups linked by a hexane chain, lies across a crystallographic inversion centre. The mean plane of the pyrrole ring is almost perpendicular to the mean plane of the central chain, making a dihedral angle of 89.09 (8)°. The crystal structure is stabilized by inter-molecular C-H⋯π inter-actions.

KOI2138 -- a Spin-Orbit Aligned Intermediate Period Super-Earth

NASA Astrophysics Data System (ADS)

Barnes, Jason W.

2015-11-01

A planet's formation and evolution are encoded in spin-orbit alignment -- the planet's inclination relative to its star's equatorial plane. While the solar system's spin-orbit aligned planets indicate our own relatively quiescent history, many close-in giant planets show significant misalignment. Some planets even orbit retrograde! Hot Jupiters, then, have experienced fundamentally different histories than we experienced here in the solar system. In this presentation, I will show a new determination of the spin-orbit alignment of 2.1 REarth exoplanet candidate KOI2138. KOI2138 shows a gravity-darkened transit lightcurve that is consistent with spin-orbit alignment. This measurement is important because the only other super-Earth with an alignment determination (55 Cnc e, orbit period 0.74 days) is misaligned. With an orbital period of 23.55 days, KOI2138 is far enough from its star to avoid tidal orbit evolution. Therefore its orbit is likely primordial, and hence it may represent the tip of an iceberg of terrestrial, spin-orbit aligned planets that have histories that more closely resemble that of the solar system's terrestrial planets.

The Eccentric Behavior of Nearly Frozen Orbits

NASA Technical Reports Server (NTRS)

Sweetser, Theodore H.; Vincent, Mark A.

2013-01-01

Frozen orbits are orbits which have only short-period changes in their mean eccentricity and argument of periapse, so that they basically keep a fixed orientation within their plane of motion. Nearly frozen orbits are those whose eccentricity and argument of periapse have values close to those of a frozen orbit. We call them "nearly" frozen because their eccentricity vector (a vector whose polar coordinates are eccentricity and argument of periapse) will stay within a bounded distance from the frozen orbit eccentricity vector, circulating around it over time. For highly inclined orbits around the Earth, this distance is effectively constant over time. Furthermore, frozen orbit eccentricity values are low enough that these orbits are essentially eccentric (i.e., off center) circles, so that nearly frozen orbits around Earth are bounded above and below by frozen orbits.

Complexes in the Photocatalytic Reaction of CO2 and H2O: Theoretical Studies

PubMed Central

Luo, Dongmei; Zhang, Ning; Hong, Sanguo; Wu, Huanwen; Liu, Zhihua

2010-01-01

Complexes (H2O/CO2, e–(H2O/CO2) and h+–(H2O/CO2)) in the reaction system of CO2 photoreduction with H2O were researched by B3LYP and MP2 methods along with natural bond orbital (NBO) analysis. Geometries of these complexes were optimized and frequencies analysis performed. H2O/CO2 captured photo-induced electron and hole produced e–(H2O/CO2) and h+–(H2O/CO2), respectively. The results revealed that CO2 and H2O molecules could be activated by the photo-induced electrons and holes, and each of these complexes possessed two isomers. Due to the effect of photo-induced electrons, the bond length of C=O and H-O were lengthened, while H-O bonds were shortened, influenced by holes. The infrared (IR) adsorption frequencies of these complexes were different from that of CO2 and H2O, which might be attributed to the synergistic effect and which could not be captured experimentally. PMID:21152274

Terahertz laser spectroscopy of the water dimer intermolecular vibrations. II. (H2O)2

NASA Astrophysics Data System (ADS)

Braly, L. B.; Liu, K.; Brown, M. G.; Keutsch, F. N.; Fellers, R. S.; Saykally, R. J.

2000-06-01

Terahertz VRT laser spectra of four (H2O)2 intermolecular vibrations consisting of 362 transitions have been measured between 87 and 108 cm-1 with ca. 2 MHz precision. The results differ both qualitatively and quantitatively from the predictions of dimer potentials tested. The spectra also reveal an ordering of the intermolecular vibrations which differs dramatically from that predicted by normal mode analysis. Strong coupling is indicated between the low barrier tunneling motions and the intermolecular vibrations as well as among different vibrations. In particular the 102.1 cm-1 (H2O)2 vibration assigned as the acceptor wag (ν8) exhibits two types of perturbations. In one of these a component of Ka=1 coupling with a tunneling component of Ka=0 in the 108 cm-1 acceptor twist (ν11) vibration. There is also an indication that the 103.1 cm-1 (H2O)2 band assigned as the donor in-plane bend (ν6) is coupled to the acceptor wag resulting in a lower of the in-plane bend frequency and a higher acceptor wag frequency. Detailed analysis of the VRT levels confirms the extreme nonrigidity of this complex, indicating that the use of approximate models with reduced dimensionality to calculate its properties are likely to fail.

A contact binary asteroid evolutionary cycle driven by BYORP & the classical Laplace plane

NASA Astrophysics Data System (ADS)

Rieger, Samantha; Scheeres, Daniel J.

2017-10-01

Several contact binaries have been observed to have high obliquities distributed around 90°. With this information, we explore the possibility of these high obliquities being a key characteristic that causes an evolutionary cycle of contact binary formation and separation.The contact binary cycle begins with a single asteroid that is spinning up due to the YORP effect. For the binary cycle we assume YORP will drive the obliquity to 90°. Eventually, the asteroid will reach a critical spin frequency that will cause the asteroid to fission into a binary. We assume that the mass-ratio, q, of the system is greater than 0.2. With a high q, the secondary will not escape/impact the primary but will evolve through tides into a stable circular double-synchronous orbit. The binary being synchronous will cause the forces from BYORP to have secular effects on the system. For this cycle, BYORP will need to expand the secondary away from the primary.As the system expands, we have found that the secondary will follow the classical Laplace plane. Therefore, the secondary’s orbit will increase in inclination with respect to the equator as the secondary’s orbit expands. The Laplace plane is a stable orbit to perturbations from J2 & Sun tides except for an instability region that exists for primaries with obliquities above 68.875° & a secondary orbital radius of 13.5-19.5 primary radii. Once BYORP expands the secondary into this instability region, the eccentricity of the secondary’s orbit will increase until the orbit intersects with the primary & causes an impact. This impact will create a contact binary with a new obliquity that will randomly range from 23°-150°. The cycle will begin again with YORP driving the contact binary to an obliquity of 90°.Our contribution will discuss the proposed contact binary cycle in more detail, including the mechanics of the system that drives the events given above. We will include investigations into how losing synchronous lock will

Strong spin-orbit effects in transition metal oxides with tetrahedral coordination

NASA Astrophysics Data System (ADS)

Forte, Filomena; Guerra, Delia; Autieri, Carmine; Romano, Alfonso; Noce, Canio; Avella, Adolfo

2018-05-01

To prove that spin-orbit coupling can play a relevant role in determining the magnetic structure of transition metal oxides with tetrahedral coordination, we investigate the d1 Mott insulator KOsO4, combining density functional theory calculations and the exact diagonalization approach. We find that the interplay between crystal field, strong spin-orbit coupling, electronic correlations and structural distortions brings the system towards an antiferromagnetic phase, characterized by a non-vanishing orbital angular momentum and anisotropy among the in-plane and the out-of-plane antiferromagnetic correlations. We also show that, due to the peculiar interplay between spin-orbit coupling, Hund's coupling and hopping connectivity the system is on the verge of developing short range ferromagnetic correlations marked by strong directionality.

Field-Free Programmable Spin Logics via Chirality-Reversible Spin-Orbit Torque Switching.

PubMed

Wang, Xiao; Wan, Caihua; Kong, Wenjie; Zhang, Xuan; Xing, Yaowen; Fang, Chi; Tao, Bingshan; Yang, Wenlong; Huang, Li; Wu, Hao; Irfan, Muhammad; Han, Xiufeng

2018-06-21

Spin-orbit torque (SOT)-induced magnetization switching exhibits chirality (clockwise or counterclockwise), which offers the prospect of programmable spin-logic devices integrating nonvolatile spintronic memory cells with logic functions. Chirality is usually fixed by an applied or effective magnetic field in reported studies. Herein, utilizing an in-plane magnetic layer that is also switchable by SOT, the chirality of a perpendicular magnetic layer that is exchange-coupled with the in-plane layer can be reversed in a purely electrical way. In a single Hall bar device designed from this multilayer structure, three logic gates including AND, NAND, and NOT are reconfigured, which opens a gateway toward practical programmable spin-logic devices. © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

NASA Educational Briefs for the Classroom. Orbits of Bodies in Space

NASA Technical Reports Server (NTRS)

1982-01-01

The difference between an orbit and a revolution is explained and it is shown why space shuttle Columbia's period of revolution was longer than its orbital period. Parameters of orbits examined include apoapsis, periapsis, apogee, perigee, aphelion, perihelion, orbital plane, and inclination. Orbit velocity and duration, Newton's law of gravitation, and Kepler's three laws of motion are considered. The principles involved in geostationary satellites are also explored.

Orbiting Carbon Observatory-2 (OCO-2)

NASA Image and Video Library

2014-06-29

The launch gantry, surrounding the United Launch Alliance Delta II rocket with the Orbiting Carbon Observatory-2 (OCO-2) satellite onboard, is seen at the Space Launch Complex 2, Sunday, June 29, 2014, Vandenberg Air Force Base, Calif. OCO-2 will measure the global distribution of carbon dioxide, the leading human-produced greenhouse gas driving changes in Earth’s climate. OCO-2 is set for a July 1, 2014 launch. Photo Credit: (NASA/Bill Ingalls)

The national aero-space plane

NASA Technical Reports Server (NTRS)

Mendez, Bruce

1988-01-01

The National Aerospace Plane is an extremely versatile and adaptable aircraft. It can be developed into an Orient Express that would dramatically improve trade with countries in Asia and elsewhere: a commuter transport to ferry men and materials to space, an advanced tactical fighter or bomber, and an unparalleled high altitude spy-plane to observe troubled spots all over the globe. Utilizing the technology developed by this pilot program, it will be possible to quickly and easily get to low Earth orbit, go halfway around the world in a fraction of the time it previously took, and lead the world in the development of advanced technology to improve our lives and the lives of many others.

A three-dimensional coordination polymer based on 1,2,3-triazole-4,5-dicarboxylic acid (H{sub 3}tda): ([Cd{sub 12}(tda){sub 8}(H{sub 2}O){sub 11}] · (H{sub 2}O)6.25){sub n}

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhou, Xin-Hui, E-mail: iamxhzhou@njupt.edu.cn; Chen, Qiang

The title coordination polymer ([Cd{sub 12}(tda){sub 8}(H{sub 2}O){sub 11}] · (H{sub 2}O){sub 6.25}){sub n} (H{sub 3}tda = 1,2,3-triazole-4,5-dicarboxylic acid), has been hydrothermally synthesized and structurally characterized by single-crystal X-ray diffraction. Complex crystallizes in orthorhombic sp. gr. Pmn2{sub 1} with Z = 4. The Cd{sub 2} unit doublebridged by one carboxylate oxygen atom and two neighboring nitrogen atoms from the tda{sup 3–} ligands are linked by the tda{sup 3–}ligands to lead to the 2D (4,4) network in the ac plane. The almost coplanar Cd{sub 2}(μ{sub 5}-tda){sub 2} unit comprised of two Cd ions double-bridged by two tda{sup 3–} ligands through themore » neighboring nitrogen atoms is connected with the other four Cd{sub 2}(μ{sub 5}-tda){sub 2} units form the undulating 2D network in the ac plane. The (4,4) networks and undulating 2D networks are alternatively connected along the b axis by the tda{sup 3–} ligands coordinating to the Cd ions to form the 3D framework.« less

Low-T magnetometry study of S = 1 Q2D [Ni(pyz) 2(H 2O) 2](BF 4) 2 (pyz = pyrazine)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Manson, J. L.; Villa, D. Y.; Blackmore, W. J. A.

2017-02-13

[Ni(pyz) 2(H 2O) 2](BF 4) 2 (pyz = N 2C 4H 4) was synthesized by a solvent-free technique and its structure solved by synchrotron X-ray powder diffraction.1 The compound contains S = 1 Ni(II) ions and has tetragonal symmetry. Two-D [Ni(pyz) 2(H 2O) 2] 2+ square lattices propagate in the ab-plane and stack along the c-axis (Fig. 1). Water ligands occupy axial sites and form H-bonds with interlayer BF 4 - ions. SQUID magnetometry shows a possible transition to long-range magnetic order near 3 K. We measured the magnetization of [Ni(pyz) 2(H 2O) 2](BF 4) 2 as a function ofmore » temperature to search for field-induced phase transitions and briefly report those findings here.« less

Two-center interference effects in (e, 2e) ionization of H2 and CO2 at large momentum transfer

NASA Astrophysics Data System (ADS)

Yamazaki, Masakazu; Nakajima, Isao; Satoh, Hironori; Watanabe, Noboru; Jones, Darryl; Takahashi, Masahiko

2015-09-01

In recent years, there has been considerable interest in understanding quantum mechanical interference effects in molecular ionization. Since this interference appears as a consequence of coherent electron emission from the different molecular centers, it should depend strongly on the nature of the ionized molecular orbital. Such molecular orbital patterns can be investigated by means of binary (e, 2e) spectroscopy, which is a kinematically-complete electron-impact ionization experiment performed under the high-energy Bethe ridge conditions. In this study, two-center interference effects in the (e, 2e) cross sections of H2 and CO2 at large momentum transfer are demonstrated with a high-statistics experiment, in order to elucidate the relationship between molecular orbital patterns and the interference structure. It is shown that the two-center interference is highly sensitive to the phase, spatial pattern, symmetry of constituent atomic orbital, and chemical bonding nature of the molecular orbital. This work was partially supported by Grant-in-Aids for Scientific Research (S) (No. 20225001) and for Young Scientists (B) (No. 21750005) from the Ministry of Education, Culture, Sports, Science and Technology.

The spectroscopic orbits and the geometrical configuration of the symbiotic binary AR Pavonis

NASA Astrophysics Data System (ADS)

Quiroga, C.; Mikołajewska, J.; Brandi, E.; Ferrer, O.; García, L.

2002-05-01

We analyze optical and near infrared spectra of intermediate and high resolution of the eclipsing symbiotic system AR Pavonis. We have obtained the radial velocity curves for the red and the hot component from the M-giant absorption lines and from the wings of Hα , Hβ and He II lambda 4686 emission profiles, respectively. From the orbital elements we have derived the masses, Mg=2.5 Msun and Mh=1.0 Msun, for the red giant and the hot component, respectively. We also present and discuss radial velocity patterns in the blue cF absorption spectrum as well as various emission lines. In particular, we confirm that the blue absorption lines are associated with the hot component. The radial velocity curve of the blue absorption system, however, does not track the hot companion's orbital motion in a straightforward way, and its departures from an expected circular orbit are particularly strong when the hot component is active. We suggest that the cF-type absorption system is formed in material streaming from the giant presumably in a region where the stream encounters an accretion disk or an extended envelope around the hot component. The broad emission wings originate from the inner accretion disk or the envelope around the hot star. We also suggest that the central absorption in H profiles is formed in a neutral portion of the cool giant's wind which is strongly concentrated towards the orbital plane. The nebula in AR Pav seems to be bounded by significant amount of neutral material in the orbital plane. The forbidden emission lines are probably formed in low density ionized regions extended in polar directions and/or the wind-wind interaction zone. Based on observations taken at Complejo Astronómico El Leoncito (CASLEO), operated under an agreement between the Consejo Nacional de Investigaciones Científicas y Técnicas de la República Argentina, the Secretaría de Ciencia y Tecnología de la Nación and the National Universities of La Plata, Córdoba and San Juan.

Time-dependent quantum wave packet calculation for nonadiabatic F(2P3/2,2P1/2)+H2 reaction

NASA Astrophysics Data System (ADS)

Zhang, Yan; Xie, Ting-Xian; Han, Ke-Li; Zhang, John Z. H.

2003-12-01

In this paper we present a time-dependent quantum wave packet calculation for the reaction of F(2P3/2,2P1/2)+H2 on the Alexander-Stark-Werner potential energy surface. The reaction probabilities and the integral cross sections for the reaction of F(2P3/2,2P1/2)+H2 (v=j=0) are computed using time-dependent quantum methods with the centrifugal sudden approximate. The results are compared with recent time-independent quantum calculations. The two-surface reaction probability for the initial ground spin-orbit state of J=0.5 is similar to the time-independent result obtained by Alexander et al. [J. Chem. Phys. 113, 11084 (2000)]. Our calculation also shows that electronic coupling has a relatively minor effect on the reactivity from the 2P3/2 state but a non-negligible one from the 2P1/2 state. By comparison with exact time-independent calculations, it is found that the Coriolis coupling plays a relatively minor role. In addition, most of the reactivity of the excited state of fluorine atom results from the spin-orbit coupling.

Crystal structures of three indole derivatives: 3-ethnyl-2-methyl-1-phenyl­sulfonyl-1H-indole, 4-phenyl­sulfonyl-3H,4H-cyclo­penta­[b]indol-1(2H)-one and 1-{2-[(E)-2-(5-chloro-2-nitro­phen­yl)ethen­yl]-1-phenyl­sulfonyl-1H-indol-3-yl}ethan-1-one chloro­form monosolvate

PubMed Central

Gopinath, S.; Sethusankar, K.; Ramalingam, Bose Muthu; Mohanakrishnan, Arasambattu K.

2015-01-01

The title compounds, C17H13NO2S, (I), C17H13NO3S, (II), and C24H17ClN2O5S·CHCl3, (III), are indole derivatives. Compounds (I) and (II) crystalize with two independent mol­ecules in the asymmetric unit. The indole ring systems in all three structures deviate only slightly from planarity, with dihedral angles between the planes of the pyrrole and benzene rings spanning the tight range 0.20 (9)–1.65 (9)°. These indole ring systems, in turn, are almost orthogonal to the phenyl­sulfonyl rings [range of dihedral angles between mean planes = 77.21 (8)–89.26 (8)°]. In the three compounds, the mol­ecular structure is stabilized by intra­molecular C—H⋯O hydrogen bonds, generating S(6) ring motifs with the sulfone O atom. In compounds (I) and (II), the two independent mol­ecules are linked by C—H⋯O hydrogen bonds and C—H⋯π inter­actions, while in compound (III), the mol­ecules are linked by C—H⋯O hydrogen bonds, generating R 2 2(22) inversion dimers. PMID:26396842

Controlling the superconducting transition by spin-orbit coupling

NASA Astrophysics Data System (ADS)

Banerjee, N.; Ouassou, J. A.; Zhu, Y.; Stelmashenko, N. A.; Linder, J.; Blamire, M. G.

2018-05-01

Whereas considerable evidence exists for the conversion of singlet Cooper pairs into triplet Cooper pairs in the presence of inhomogeneous magnetic fields, recent theoretical proposals have suggested an alternative way to exert control over triplet generation: intrinsic spin-orbit coupling in a homogeneous ferromagnet coupled to a superconductor. Here, we proximity couple Nb to an asymmetric Pt/Co/Pt trilayer, which acts as an effective spin-orbit-coupled ferromagnet owing to structural inversion asymmetry. Unconventional modulation of the superconducting critical temperature as a function of in-plane and out-of-plane applied magnetic fields suggests the presence of triplets that can be controlled by the magnetic orientation of a single homogeneous ferromagnet. Our studies demonstrate an active role of spin-orbit coupling in controlling the triplets, an important step towards the realization of novel superconducting spintronic devices.

Orbiting Carbon Observatory-2 (OCO-2)

NASA Image and Video Library

2014-06-30

The United Launch Alliance Delta II rocket with the Orbiting Carbon Observatory-2 (OCO-2) satellite onboard, is seen as the launch gantry is moved at the Space Launch Complex 2, Monday, June 30, 2014, Vandenberg Air Force Base, Calif. OCO-2 will measure the global distribution of carbon dioxide, the leading human-produced greenhouse gas driving changes in Earth’s climate. OCO-2 is set for a July 1, 2014 launch. Photo Credit: (NASA/Bill Ingalls)

Orbiting Carbon Observatory-2 (OCO-2)

NASA Image and Video Library

2014-06-30

The United Launch Alliance Delta II rocket with the Orbiting Carbon Observatory-2 (OCO-2) satellite onboard, is seen moments after the launch gantry was moved at the Space Launch Complex 2, Monday, June 30, 2014, Vandenberg Air Force Base, Calif. OCO-2 will measure the global distribution of carbon dioxide, the leading human-produced greenhouse gas driving changes in Earth’s climate. OCO-2 is set for a July 1, 2014 launch. Photo Credit: (NASA/Bill Ingalls)

Orbiting Carbon Observatory-2 (OCO-2)

NASA Image and Video Library

2014-06-30

The launch gantry is rolled back to reveal the United Launch Alliance Delta II rocket with the Orbiting Carbon Observatory-2 (OCO-2) satellite onboard, at the Space Launch Complex 2, Monday, June 30, 2014, Vandenberg Air Force Base, Calif. OCO-2 will measure the global distribution of carbon dioxide, the leading human-produced greenhouse gas driving changes in Earth’s climate. OCO-2 is set for a July 1, 2014 launch. Photo Credit: (NASA/Bill Ingalls)

Orbiting Carbon Observatory-2 (OCO-2)

NASA Image and Video Library

2014-06-29

The upper levels of the launch gantry, surrounding the United Launch Alliance Delta II rocket with the Orbiting Carbon Observatory-2 (OCO-2) satellite onboard, are seen at the Space Launch Complex 2, Sunday, June 29, 2014, Vandenberg Air Force Base, Calif. OCO-2 will measure the global distribution of carbon dioxide, the leading human-produced greenhouse gas driving changes in Earth’s climate. OCO-2 is set for a July 1, 2014 launch. Photo Credit: (NASA/Bill Ingalls)

The relationship of the globe to the orbital rim.

PubMed

Eckstein, Lauren A; Shadpour, Joseph M; Menghani, Ravi; Goldberg, Robert A

2011-01-01

To present a novel method for accurately characterizing the position of the globe relative to the orbital rim. The appearance and function of the eyelids are dependent on the underlying orbital bony architecture and globe position; however, no comprehensive language to describe these complex 3-dimensional relationships exists. Three-dimensional orbital reconstructions were generated from computed tomographic scans of 15 Occidental and 12 Oriental orbits without orbital pathologic disease. Globe and orbital rim anatomy were identified and outlined. Reference points were measured along 2 independent axes: (1) the distance between a plane defined by the corneal apex and the sagittal projection of the orbital rim and (2) the distance between the circumference of the globe and the coronal projection of the orbital rim. For Occidental orbits, the mean (SD) elevation of the sagittal projection of the orbital rim relative to the anterior projection of the globe was 4.6 (4.2) mm superiorly, 5.9 (3.0) mm nasally, 12.6 (3.7) mm inferiorly, and 20.6 (2.6) mm laterally. The mean (SD) radial distance between the coronal projection of the orbital rim and the circumference of the globe was 3.7 (2.1) mm superiorly, 7.6 (1.8) mm nasally, 6.6 (2.2) mm inferiorly, and 4.6 (2.3) mm laterally. For Oriental orbits, the mean (SD) elevation of the sagittal projection of the orbital rim relative to the anterior projection of the globe was 5.0 (4.5) mm superiorly, 6.8 (4.1) mm nasally, 11.1 (4.3) mm inferiorly, and 17.5 (3.3) mm laterally. The mean (SD) radial distance between the coronal projection of the orbital rim and the circumference of the globe was 2.1 (1.2) mm superiorly, 8.2 (2.0) mm nasally, 6.5 (1.9) mm inferiorly, and 4.5 (1.7) mm laterally. Comparison of Occidental and Oriental orbital rim and globe configurations revealed quantitative and qualitative differences. In addition to differences in soft-tissue anatomy, bony architectural variations may contribute substantially to

Estimating the Value of the Inclination Angle of the Lunar Plane to the Ecliptic Plane

ERIC Educational Resources Information Center

Isildak, R. Suat; Isik, Hakan; Küçüközer, H. Asuman

2018-01-01

Sky appears to our students as a vast volume surrounding the Earth. The most striking astronomical events that they can witness in the sky are lunar phases and eclipses. However, eclipses do not occur as often as full and new phases of the Moon. This difference is due to the fact that the orbital planes of the Moon and the Earth do not overlap.…

Planes of satellite galaxies and the cosmic web

NASA Astrophysics Data System (ADS)

Libeskind, Noam I.; Hoffman, Yehuda; Tully, R. Brent; Courtois, Helene M.; Pomarède, Daniel; Gottlöber, Stefan; Steinmetz, Matthias

2015-09-01

Recent observational studies have demonstrated that the majority of satellite galaxies tend to orbit their hosts on highly flattened, vast, possibly corotating planes. Two nearly parallel planes of satellites have been confirmed around the M31 galaxy and around the Centaurus A galaxy, while the Milky Way also sports a plane of satellites. It has been argued that such an alignment of satellites on vast planes is unexpected in the standard Λ cold dark matter (ΛCDM) model of cosmology if not even in contradiction to its generic predictions. Guided by ΛCDM numerical simulations, which suggest that satellites are channelled towards hosts along the axis of the slowest collapse as dictated by the ambient velocity shear tensor, we re-examine the planes of local satellites systems within the framework of the local shear tensor derived from the Cosmicflows-2 data set. The analysis reveals that the Local Group and Centaurus A reside in a filament stretched by the Virgo cluster and compressed by the expansion of the Local Void. Four out of five thin planes of satellite galaxies are indeed closely aligned with the axis of compression induced by the Local Void. Being the less massive system, the moderate misalignment of the Milky Way's satellite plane can likely be ascribed to its greater susceptibility to tidal torques, as suggested by numerical simulations. The alignment of satellite systems in the local Universe with the ambient shear field is thus in general agreement with predictions of the ΛCDM model.

The stability of steady motion of magnetic domain wall: Role of higher-order spin-orbit torques

DOE Office of Scientific and Technical Information (OSTI.GOV)

He, Peng-Bin, E-mail: hepengbin@hnu.edu.cn; Yan, Han; Cai, Meng-Qiu

The steady motion of magnetic domain wall driven by spin-orbit torques is investigated analytically in the heavy/ferromagnetic metal nanowires for three cases with a current transverse to the in-plane and perpendicular easy axis, and along the in-plane easy axis. By the stability analysis of Walker wall profile, we find that if including the higher-order spin-orbit torques, the Walker breakdown can be avoided in some parameter regions of spin-orbit torques with a current transverse to or along the in-plane easy axis. However, in the case of perpendicular anisotropy, even considering the higher-order spin-orbit torques, the velocity of domain wall cannot bemore » efficiently enhanced by the current. Furthermore, the direction of wall motion is dependent on the configuration and chirality of domain wall with a current along the in-plane easy axis or transverse to the perpendicular one. Especially, the direction of motion can be controlled by the initial chirality of domain wall. So, if only involving the spin-orbit mechanism, it is preferable to adopt the scheme of a current along the in-plane easy axis for enhancing the velocity and controlling the direction of domain wall.« less

Orbiter/Space lab momentum management for POP orientations

NASA Technical Reports Server (NTRS)

Cox, J. W.

1974-01-01

An angular momentum management scheme applicable to the orbiter/spacelab is described. The basis of the scheme is to periodically maneuver the vehicle through a small angle thereby using the gravity gradient torque to dump momentum from the control moment gyro (CMG) control system. The orbiter is operated with its principal vehicle axis perpendicular to the orbital plane. Numerous case runs were conducted on the hybrid simulation and representative cases are included.

Delineating the role of ripples on the thermal expansion of 2D honeycomb materials: graphene, 2D h-BN and monolayer (ML)-MoS2.

PubMed

Anees, P; Valsakumar, M C; Panigrahi, B K

2017-04-19

We delineated the role of thermally excited ripples on the thermal expansion properties of 2D honeycomb materials (free-standing graphene, 2D h-BN, and ML-MoS 2 ), by explicitly carrying out three-dimensional (3D) and two-dimensional (2D) molecular dynamics simulations. In 3D simulations, the in-plane lattice parameter (a-lattice) of graphene and 2D h-BN shows thermal contraction over a wide range of temperatures and exhibits a strong system size dependence. The 2D simulations of the very same system show a reverse trend, where the a-lattice expands in the whole computed temperature range. In contrast to graphene and 2D h-BN, the a-lattice of ML-MoS 2 shows thermal expansion in both 2D and 3D simulations and their system size dependence is marginal. By analyzing the phonon dispersion at 300 K, we found that the discrepancy between 2D and 3D simulations of graphene and 2D h-BN is due to the absence of out-of-plane bending modes (ZA) in 2D simulations, which is responsible for the thermal contraction of the a-lattice at low temperature. Meanwhile, all the phonon modes are present in the 2D phonon dispersion of ML-MoS 2 , which indicates that the origin of the ZA mode is not purely due to the out-of-plane movement of atoms and also its effect on thermal expansion is not significant as found in graphene and 2D h-BN.

Phonon thermal transport in 2H, 4H and 6H silicon carbide from first principles

DOE PAGES

Protik, Nakib Haider; Katre, Ankita; Lindsay, Lucas R.; ...

2017-06-07

Here, silicon carbide (SiC) is a wide band gap semiconductor with a variety of industrial applications. Among its many useful properties is its high thermal conductivity, which makes it advantageous for thermal management applications. In this paper we present ab initio calculations of the in-plane and cross-plane thermal conductivities, κ in and κ out, of three common hexagonal polytypes of SiC: 2H, 4H and 6H. The phonon Boltzmann transport equation is solved iteratively using as input interatomic force constants determined from density functional theory. Both κ in and κ out decrease with increasing n in nH SiC because of additionalmore » low-lying optic phonon branches. These optic branches are characterized by low phonon group velocities, and they increase the phase space for phonon-phonon scattering of acoustic modes. Also, for all n, κ in is found to be larger than κ out in the temperature range considered. At electron concentrations present in experimental samples, scattering of phonons by electrons is shown to be negligible except well below room temperature where it can lead to a significant reduction of the lattice thermal conductivity. This work highlights the power of ab initio approaches in giving quantitative, predictive descriptions of thermal transport in materials. It helps explain the qualitative disagreement that exists among different sets of measured thermal conductivity data and provides information of the relative quality of samples from which measured data was obtained.« less

Phonon thermal transport in 2H, 4H and 6H silicon carbide from first principles

DOE Office of Scientific and Technical Information (OSTI.GOV)

Protik, Nakib Haider; Katre, Ankita; Lindsay, Lucas R.

Here, silicon carbide (SiC) is a wide band gap semiconductor with a variety of industrial applications. Among its many useful properties is its high thermal conductivity, which makes it advantageous for thermal management applications. In this paper we present ab initio calculations of the in-plane and cross-plane thermal conductivities, κ in and κ out, of three common hexagonal polytypes of SiC: 2H, 4H and 6H. The phonon Boltzmann transport equation is solved iteratively using as input interatomic force constants determined from density functional theory. Both κ in and κ out decrease with increasing n in nH SiC because of additionalmore » low-lying optic phonon branches. These optic branches are characterized by low phonon group velocities, and they increase the phase space for phonon-phonon scattering of acoustic modes. Also, for all n, κ in is found to be larger than κ out in the temperature range considered. At electron concentrations present in experimental samples, scattering of phonons by electrons is shown to be negligible except well below room temperature where it can lead to a significant reduction of the lattice thermal conductivity. This work highlights the power of ab initio approaches in giving quantitative, predictive descriptions of thermal transport in materials. It helps explain the qualitative disagreement that exists among different sets of measured thermal conductivity data and provides information of the relative quality of samples from which measured data was obtained.« less

57. LOOKING UP TAILRACE OF PLANE 2 EAST. WATER DISCHARGING ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

57. LOOKING UP TAILRACE OF PLANE 2 EAST. WATER DISCHARGING FROM CULVERT ON LEFT HAD JUST PASSED THROUGH THE FLUME AND POWER HOUSE IN ORDER TO OPERATE THE LIFT MACHINERY. TAILRACE ON RIGHT IS A BYPASS FLUME SO THAT LEVEL OF CANAL BELOW PLANE 2 EAST CAN BE MAINTAINED. - Morris Canal, Phillipsburg, Warren County, NJ

Quartic scaling MP2 for solids: A highly parallelized algorithm in the plane wave basis

NASA Astrophysics Data System (ADS)

Schäfer, Tobias; Ramberger, Benjamin; Kresse, Georg

2017-03-01

We present a low-complexity algorithm to calculate the correlation energy of periodic systems in second-order Møller-Plesset (MP2) perturbation theory. In contrast to previous approximation-free MP2 codes, our implementation possesses a quartic scaling, O ( N 4 ) , with respect to the system size N and offers an almost ideal parallelization efficiency. The general issue that the correlation energy converges slowly with the number of basis functions is eased by an internal basis set extrapolation. The key concept to reduce the scaling is to eliminate all summations over virtual orbitals which can be elegantly achieved in the Laplace transformed MP2 formulation using plane wave basis sets and fast Fourier transforms. Analogously, this approach could allow us to calculate second order screened exchange as well as particle-hole ladder diagrams with a similar low complexity. Hence, the presented method can be considered as a step towards systematically improved correlation energies.

Interactive orbital proximity operations planning system

NASA Technical Reports Server (NTRS)

Grunwald, Arthur J.; Ellis, Stephen R.

1988-01-01

An interactive graphical proximity operations planning system was developed, which allows on-site design of efficient, complex, multiburn maneuvers in a dynamic multispacecraft environment. Maneuvering takes place in and out of the orbital plane. The difficulty in planning such missions results from the unusual and counterintuitive character of orbital dynamics and complex time-varying operational constraints. This difficulty is greatly overcome by visualizing the relative trajectories and the relevant constraints in an easily interpretable graphical format, which provides the operator with immediate feedback on design actions. The display shows a perspective bird's-eye view of a Space Station and co-orbiting spacecraft on the background of the Station's orbital plane. The operator has control over the two modes of operation: a viewing system mode, which enables the exporation of the spatial situation about the Space Station and thus the ability to choose and zoom in on areas of interest; and a trajectory design mode, which allows the interactive editing of a series of way points and maneuvering burns to obtain a trajectory that complies with all operational constraints. A first version of this display was completed. An experimental program is planned in which operators will carry out a series of design missions which vary in complexity and constraints.

Orbiting Carbon Observatory-2 (OCO-2)

NASA Image and Video Library

2014-06-27

The launch gantry, surrounding the United Launch Alliance Delta II rocket with the Orbiting Carbon Observatory-2 (OCO-2) satellite onboard, is seen in this black and white infrared view at Space Launch Complex 2, Friday, June 27, 2014, Vandenberg Air Force Base, Calif. OCO-2 will measure the global distribution of carbon dioxide, the leading human-produced greenhouse gas driving changes in Earth’s climate. OCO-2 is set for a July 1, 2014 launch. Photo Credit: (NASA/Bill Ingalls)

Orbiting Carbon Observatory-2 (OCO-2)

NASA Image and Video Library

2014-06-30

NASA Administrator Charles Bolden, left, talks with an engineer at the base of the United Launch Alliance Delta II rocket with the Orbiting Carbon Observatory-2 (OCO-2) satellite onboard, Monday, June 30, 2014, Space Launch Complex 2, Vandenberg Air Force Base, Calif. OCO-2 will measure the global distribution of carbon dioxide, the leading human-produced greenhouse gas driving changes in Earth’s climate. OCO-2 is set for a July 1, 2014 launch. Photo Credit: (NASA/Bill Ingalls)

Orbiting Carbon Observatory-2 (OCO-2)

NASA Image and Video Library

2014-06-30

Workers monitor the progress of the rollback of the launch gantry from the United Launch Alliance Delta II rocket with the Orbiting Carbon Observatory-2 (OCO-2) satellite onboard, at Space Launch Complex 2, Monday, June 30, 2014, Vandenberg Air Force Base, Calif. OCO-2 will measure the global distribution of carbon dioxide, the leading human-produced greenhouse gas driving changes in Earth’s climate. OCO-2 is set for a July 1, 2014 launch. Photo Credit: (NASA/Bill Ingalls)

A high-velocity black hole on a Galactic-halo orbit in the solar neighbourhood.

PubMed

Mirabel, I F; Dhawan, V; Mignani, R P; Rodrigues, I; Guglielmetti, F

2001-09-13

Only a few of the dozen or so known stellar-mass black holes have been observed away from the plane of the Galaxy. Those few could have been ejected from the plane as a result of a 'kick' received during a supernova explosion, or they could be remnants of the population of massive stars formed in the early stages of evolution of the Galaxy. Determining their orbital motion should help to distinguish between these options. Here we report the transverse motion (in the plane of the sky) for the black-hole X-ray nova XTE J1118+480 (refs 2, 3, 4, 5), from which we derive a large space velocity. This X-ray binary system has an eccentric orbit around the Galactic Centre, like most objects in the halo of the Galaxy, such as ancient stars and globular clusters. The properties of the system suggest that its age is comparable to or greater than the age of the Galactic disk. Only an extraordinary 'kick' from a supernova could have launched the black hole into an orbit like this from a birthplace in the disk of the Galaxy.

Orbiting Carbon Observatory-2 (OCO-2) Launch

NASA Image and Video Library

2014-07-02

A United Launch Alliance Delta II rocket launches with the Orbiting Carbon Observatory-2 (OCO-2)satellite onboard from Space Launch Complex 2 at Vandenberg Air Force Base, Calif. on Wednesday, July 2, 2014. OCO-2 will measure the global distribution of carbon dioxide, the leading human-produced greenhouse gas driving changes in Earth’s climate. Photo Credit: (NASA/Bill Ingalls)

Spacecraft Orbit Design in the Circular Restricted Three-Body Problem Using Higher-Dimensional Poincare Maps

DTIC Science & Technology

2013-12-01

the plane of the primary bodies. That is, motion is possible only in the x and y directions. For example, in the ...Earth-Moon planar CR3BP, the S/C path remains in the same plane as the Moon’s orbit about the Earth—more precisely, the orbit of both the Earth and...travels out of the plane of the massive primaries, in the z direction as well. Importantly, there is added complexity in the spatial

Human Exploration Missions Study Launch Window from Earth Orbit

NASA Technical Reports Server (NTRS)

Young, Archie

2001-01-01

The determination of orbital launch window characteristics is of major importance in the analysis of human interplanetary missions and systems. The orbital launch window characteristics are directly involved in the selection of mission trajectories, the development of orbit operational concepts, and the design of orbital launch systems. The orbital launch window problem arises because of the dynamic nature of the relative geometry between outgoing (departure) asymptote of the hyperbolic escape trajectory and the earth parking orbit. The orientation of the escape hyperbola asymptotic relative to earth is a function of time. The required hyperbola energy level also varies with time. In addition, the inertial orientation of the parking orbit is a function of time because of the perturbations caused by the Earth's oblateness. Thus, a coplanar injection onto the escape hyperbola can be made only at a point in time when the outgoing escape asymptote is contained by the plane of parking orbit. Even though this condition may be planned as a nominal situation, it will not generally represent the more probable injection geometry. The general case of an escape injection maneuver performed at a time other than the coplanar time will involve both a path angle and plane change and, therefore, a Delta(V) penalty. Usually, because of the Delta(V) penalty the actual departure injection window is smaller in duration than that determined by energy requirement alone. This report contains the formulation, characteristics, and test cases for five different launch window modes for Earth orbit. These modes are: (1) One impulsive maneuver from a Low Earth Orbit (LEO), (2) Two impulsive maneuvers from LEO, (3) Three impulsive maneuvers from LEO, (4) One impulsive maneuvers from a Highly Elliptical Orbit (HEO), (5) Two impulsive maneuvers from a Highly Elliptical Orbit (HEO) The formulation of these five different launch window modes provides a rapid means of generating realistic parametric

The VLBI time delay function for synchronous orbits

NASA Technical Reports Server (NTRS)

Rosenbaum, B.

1972-01-01

The VLBI is a satellite tracking technique that to date was applied largely to the tracking of synchronous orbits. These orbits are favorable for VLBI in that the remote satellite range allows continuous viewing from widely separated stations. The primary observable, geometric time delay is the time difference for signal propagation between satellite and baseline terminals. Extraordinary accuracy in angular position data on the satellite can be obtained by observation from baselines of continental dimensions. In satellite tracking though the common objective is to derive orbital elements. A question arises as to how the baseline vector bears on the accuracy of determining the elements. Our approach to this question is to derive an analytic expression for the time delay function in terms of Kepler elements and station coordinates. The analysis, which is for simplicity based on elliptic motion, shows that the resolution for the inclination of the orbital plane depends on the magnitude of the baseline polar component and the resolution for in-plane elements depends on the magnitude of a projected equatorial baseline component.

The planes of satellite galaxies problem, suggested solutions, and open questions

NASA Astrophysics Data System (ADS)

Pawlowski, Marcel S.

2018-02-01

Satellite galaxies of the Milky Way and of the Andromeda galaxy have been found to preferentially align in significantly flattened planes of satellite galaxies, and available velocity measurements are indicative of a preference of satellites in those structures to co-orbit. There is an increasing evidence that such kinematically correlated satellite planes are also present around more distant hosts. Detailed comparisons show that similarly anisotropic phase-space distributions of sub-halos are exceedingly rare in cosmological simulations based on the ΛCDM paradigm. Analogs to the observed systems have frequencies of ≤ 0.5% in such simulations. In contrast to other small-scale problems, the satellite planes issue is not strongly affected by baryonic processes because the distribution of sub-halos on scales of hundreds of kpc is dominated by gravitational effects. This makes the satellite planes one of the most serious small-scale problems for ΛCDM. This review summarizes the observational evidence for planes of satellite galaxies in the Local Group and beyond, and provides an overview of how they compare to cosmological simulations. It also discusses scenarios which aim at explaining the coherence of satellite positions and orbits, and why they all are currently unable to satisfactorily resolve the issue.

Distinguishing black-hole spin-orbit resonances by their gravitational-wave signatures

NASA Astrophysics Data System (ADS)

Gerosa, Davide; O'Shaughnessy, Richard; Kesden, Michael; Berti, Emanuele; Sperhake, Ulrich

2014-06-01

If binary black holes form following the successive core collapses of sufficiently massive binary stars, precessional dynamics may align their spins, Smathvariant="bold">1 and Smathvariant="bold">2, and the orbital angular momentum L into a plane in which they jointly precess about the total angular momentum J. These spin orientations are known as spin-orbit resonances since S1, S2, and L all precess at the same frequency to maintain their planar configuration. Two families of such spin-orbit resonances exist, differentiated by whether the components of the two spins in the orbital plane are either aligned or antialigned. The fraction of binary black holes in each family is determined by the stellar evolution of their progenitors, so if gravitational-wave detectors could measure this fraction they could provide important insights into astrophysical formation scenarios for binary black holes. In this paper, we show that even under the conservative assumption that binary black holes are observed along the direction of J (where precession-induced modulations to the gravitational waveforms are minimized), the waveforms of many members of each resonant family can be distinguished from all members of the other family in events with signal-to-noise ratios ρ ≃10, typical of those expected for the first detections with Advanced LIGO and Virgo. We hope that our preliminary findings inspire a greater appreciation of the capability of gravitational-wave detectors to constrain stellar astrophysics and stimulate further studies of the distinguishability of spin-orbit resonant families in more expanded regions of binary black-hole parameter space.

Pediatric orbital cellulitis in the Haemophilus influenzae vaccine era.

PubMed

Sharma, Abhishek; Liu, Eugene S; Le, Tran D; Adatia, Feisal A; Buncic, J Raymond; Blaser, Susan; Richardson, Susan

2015-06-01

To evaluate the microbiology of pediatric orbital cellulitis in blood cultures and abscess drainage cultures following the introduction of the Haemophilus influenzae serotype b (Hib) vaccine. The medical records of all pediatrics patients (aged <18 years) at a tertiary pediatric hospital during the period January 2000 to July 2011 with a computed tomography orbital imaging querying "orbital cellulitis," "periorbital cellulitis," "preseptal cellulitis," or "post-septal cellulitis" were retrospectively reviewed. The records, microbiology, and radiology of these patients were reviewed to assess the rates and complications of H. influenzae orbital cellulitis, including bacteremia and meningitis. A total of 149 patients were diagnosed with preseptal or orbital cellulitis, of whom 101 (mean age, 7.2 ± 4.0) had true orbital cellulitis. No patients grew H. influenzae from blood cultures. Of the 101 patients, 30 (29.7%) required surgical drainage and had abscess drainage fluid sent for microbiology. Of these, 18 (64.3%) had a positive culture: 4 (13.3%) grew H. influenzae from their abscess drainage fluid samples; 1 grew H. influenzae alone; and 3 had mixed growth that included H. influenzae. The patients positive for H. influenzae were significantly older and had significantly larger abscesses. Although there were no cases of H. influenzae bacteremia or meningitis in our cases of orbital cellulitis, abscess drainage fluid microbiology indicated that H. influenzae remains a cause of orbital cellulitis. H. influenzae abscess volume was significantly larger than other bacterial abscesses and was associated with abscesses of mixed bacterial growth in older children. Crown Copyright © 2015. Published by Elsevier Inc. All rights reserved.

Advanced Low-Cost O2/H2 Engines for the SSTO Application

NASA Technical Reports Server (NTRS)

Goracke, B. David; Levack, Daniel J. H.; Nixon, Robert F.

1994-01-01

The recent NASA Access to Space study examined future Earth to orbit (ETO) transportation needs and fleets out to 2030. The baseline in the option 3 assessment was a single stage to orbit (SSTO) vehicle. A study was conducted to assess the use of new advanced low cost O2/H2 engines for this SSTO application. The study defined baseline configurations and ground rules and defined six engine cycles to explore engine performance. The cycles included an open cycle, and a series of closed cycles with varying abilities to extract energy from the propellants to power he turbomachinery. The cycles thus varied in the maximum chamber pressure they could reach and in their weights at any given chamber pressure. The weight of each cycle was calculated for two technology levels versus chamber pressure up to the power limit of the cycle. The performance in the SSTO mission was then modeled using the resulting engine weights and specific impulse performance using the Access to Space option 3 vehicle. The results showed that new O2/H2 engines are viable and competitive candidates for the SSTO application using chamber pressures of 4,000 psi.

55. LOOKING EAST FROM HEAD OF PLANE 2 EAST. POWER ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

55. LOOKING EAST FROM HEAD OF PLANE 2 EAST. POWER HOUSE AND FLUME VISIBLE TO RIGHT, TAILRACE RUNNING THROUGH CENTER OF PHOTOGRAPH. CRADLE TO INCLINED PLANE 3 EAST IS VISIBLE IN BACKGROUND TO LEFT. - Morris Canal, Phillipsburg, Warren County, NJ

Orbital frustration induced unusual ordering in semiconductor alloys

NASA Astrophysics Data System (ADS)

Liu, Kai; Yin, Wanjian; Chen, Shiyou; Gong, Xingao; Wei, Suhuai; Xiang, Hongjun

It is well known that ternary zinc-blende semiconductors are always more stable in the chalcopyrite (CH) structure than the Cu-Au (CA) structure because CH structure has large Coulomb interaction and reduced strain energy. Surprisingly, an experimental study showed that ZnFeSe2 alloy takes the CA order as the ground state structure, which is consistent with our density function theory (DFT) calculations showing that the CA order has lower energy than the CH order for ZnFeSe2. We reveal that the orbital degree of freedom of high-spin Fe2+ ion (d6) in the tetrahedral crystal field plays a key role in stabilizing the CA order. First, the spin-minority d electron of the Fe2+ ion tends to occupy the dx2-y 2 -like orbital instead of the d3z2 -r2 -like orbital because of its large negative Coulomb energy. Second, for a nearest-neighboring Fe2+ pair, two spin-minority d electrons with occupied dx2-y 2 -like orbitals in the plane containing the Fe-Fe bond has lower electronic kinetic energy. Both conditions can be satisfied in the CA ordered ZnFeSe2 alloy, while there is an orbital frustration in the CH structure. Our results suggest that orbital degree of freedom provides a new way to manipulate the structure and properties of alloys. Work at Fudan was supported by NSFC (11374056), the Special Funds for Major State Basic Research (2012CB921400, 2015CB921700), Program for Professor of Special Appointment (Eastern Scholar), and Fok Ying Tung Education Foundation.

Geosynchronous inclined orbits for high-latitude communications

NASA Astrophysics Data System (ADS)

Fantino, E.; Flores, R. M.; Di Carlo, M.; Di Salvo, A.; Cabot, E.

2017-11-01

We present and discuss a solution to the growing demand for satellite telecommunication coverage in the high-latitude geographical regions (beyond 55°N), where the signal from geostationary satellites is limited or unavailable. We focus on the dynamical issues associated to the design, the coverage, the maintenance and the disposal of a set of orbits selected for the purpose. Specifically, we identify a group of highly inclined, moderately eccentric geosynchronous orbits derived from the Tundra orbit (geosynchronous, eccentric and critically inclined). Continuous coverage can be guaranteed by a constellation of three satellites in equally spaced planes and suitably phased. By means of a high-precision model of the terrestrial gravity field and the relevant environmental perturbations, we study the evolution of these orbits. The effects of the different perturbations on the ground track (which is more important for coverage than the orbital elements themselves) are isolated and analyzed. The physical model and the numerical setup are optimized with respect to computing time and accuracy. We show that, in order to maintain the ground track unchanged, the key parameters are the orbital period and the argument of perigee. Furthermore, corrections to the right ascension of the ascending node are needed in order to preserve the relative orientation of the orbital planes. A station-keeping strategy that minimizes propellant consumption is then devised, and comparisons are made between the cost of a solution based on impulsive maneuvers and one with continuous thrust. Finally, the issue of end-of-life disposal is discussed.

Orbiting Carbon Observatory-2 (OCO-2)

NASA Image and Video Library

2014-06-30

NASA Administrator Charles Bolden answers social media attendees questions from just outside the launch pad where the United Launch Alliance Delta II rocket with the Orbiting Carbon Observatory-2 (OCO-2) satellite onboard sits ready to launch, Monday, June 30, 2014, Space Launch Complex 2 Vandenberg Air Force Base, Calif. OCO-2 will measure the global distribution of carbon dioxide, the leading human-produced greenhouse gas driving changes in Earth’s climate. OCO-2 is set for a July 1, 2014 launch. Photo Credit: (NASA/Bill Ingalls)

Determination of celestial bodies orbits and probabilities of their collisions with the Earth

NASA Astrophysics Data System (ADS)

Medvedev, Yuri; Vavilov, Dmitrii

In this work we have developed a universal method to determine the small bodies orbits in the Solar System. In the method we consider different planes of body’s motion and pick up which is the most appropriate. Given an orbit plane we can calculate geocentric distances at time of observations and consequence determinate all orbital elements. Another technique that we propose here addresses the problem of estimation probability of collisions celestial bodies with the Earth. This technique uses the coordinate system associated with the nominal osculating orbit. We have compared proposed technique with the Monte-Carlo simulation. Results of these methods exhibit satisfactory agreement, whereas, proposed method is advantageous in time performance.

Influence of basal-plane dislocation structures on expansion of single Shockley-type stacking faults in forward-current degradation of 4H-SiC p-i-n diodes

NASA Astrophysics Data System (ADS)

Hayashi, Shohei; Yamashita, Tamotsu; Senzaki, Junji; Miyazato, Masaki; Ryo, Mina; Miyajima, Masaaki; Kato, Tomohisa; Yonezawa, Yoshiyuki; Kojima, Kazutoshi; Okumura, Hajime

2018-04-01

The origin of expanded single Shockley-type stacking faults in forward-current degradation of 4H-SiC p-i-n diodes was investigated by the stress-current test. At a stress-current density lower than 25 A cm-2, triangular stacking faults were formed from basal-plane dislocations in the epitaxial layer. At a stress-current density higher than 350 A cm-2, both triangular and long-zone-shaped stacking faults were formed from basal-plane dislocations that converted into threading edge dislocations near the interface between the epitaxial layer and the substrate. In addition, the conversion depth of basal-plane dislocations that expanded into the stacking fault was inside the substrate deeper than the interface. These results indicate that the conversion depth of basal-plane dislocations strongly affects the threshold stress-current density at which the expansion of stacking faults occurs.

Genealogy and stability of periodic orbit families around uniformly rotating asteroids

NASA Astrophysics Data System (ADS)

Hou, Xiyun; Xin, Xiaosheng; Feng, Jinglang

2018-03-01

Resonance orbits around a uniformly rotating asteroid are studied from the approach of periodic orbits in this work. Three periodic families (denoted as I, II, and III in the paper) are fundamental in organizing the resonance families. For the planar case: (1) Genealogy and stability of Families I, II and the prograde resonance families are studied. For extremely irregular asteroids, family genealogy close to the asteroid is greatly distorted from that of the two body-problem (2BP), indicating that it is inappropriate to treat the orbital motions as perturbed Keplerian orbits. (2) Genealogy and stability of Family III are also studied. Stability of this family may be destroyed by the secular resonance between the orbital ascending node's precession and the asteroid's rotation. For the spatial case: (1) Genealogy of the near circular three-dimensional periodic families are studied. The genealogy may be broken apart by families of eccentric frozen orbits whose argument of perigee is ;frozen; in space. (2) The joint effects between the secular resonance and the orbital resonances may cause instability to three-dimensional orbital motion with orbit inclinations close to the critical values. Applying the general methodology to a case study - the asteroid Eros and also considering higher order non-spherical terms, some extraordinary orbits are found, such as the ones with orbital plane co-rotating with the asteroid, and the stable frozen orbits with argument of perigee librating around values different from 0°, 90°, 180°, 270°.

Cassini at Saturn Proximal Orbits - Attitude Control Challenges

NASA Technical Reports Server (NTRS)

Burk, Thomas A.

2013-01-01

The Cassini mission at Saturn will come to an end in the spring and summer of 2017 with a series of 22 orbits that will dip inside the rings of Saturn. These are called proximal orbits and will conclude with spacecraft disposal into the atmosphere of the ringed world on September 15, 2017. These unique orbits that cross the ring plane only a few thousand kilometers above the cloud tops of the planet present new attitude control challenges for the Cassini operations team. Crossing the ring plane so close to the inner edge of the rings means that the Cassini orientation during the crossing will be tailored to protect the sensitive electronics bus of the spacecraft. This orientation will put the sun sensors at some extra risk so this paper discusses how the team prepares for dust hazards. Periapsis is so close to the planet that spacecraft controllability with RCS thrusters needs to be evaluated because of the predicted atmospheric torque near closest approach to Saturn. Radiation during the ring plane crossings will likely trigger single event transients in some attitude control sensors. This paper discusses how the attitude control team deals with radiation hazards. The angular size and unique geometry of the rings and Saturn near periapsis means that star identification will be interrupted and this paper discusses how the safe mode attitude is selected to best deal with these large bright bodies during the proximal orbits.

Connection between in-plane upper critical field Hc 2 and gap symmetry in layered d -wave superconductors

NASA Astrophysics Data System (ADS)

Wang, Jing-Rong; Liu, Guo-Zhu; Zhang, Chang-Jin

2016-07-01

Angle-resolved upper critical field Hc 2 provides an efficient tool to probe the gap symmetry of unconventional superconductors. We revisit the behavior of in-plane Hc 2 in d -wave superconductors by considering both the orbital effect and Pauli paramagnetic effect. After carrying out systematic analysis, we show that the maxima of Hc 2 could be along either nodal or antinodal directions of a d -wave superconducting gap, depending on the specific values of a number of tuning parameters. This behavior is in contrast to the common belief that the maxima of in-plane Hc 2 are along the direction where the superconducting gap takes its maximal value. Therefore, identifying the precise d -wave gap symmetry through fitting experiments results of angle-resolved Hc 2 with model calculations at a fixed temperature, as widely used in previous studies, is difficult and practically unreliable. However, our extensive analysis of angle-resolved Hc 2 show that there is a critical temperature T*: in-plane Hc 2 exhibits its maxima along nodal directions at T 2 at T* appears to be a general feature. Thus a better method to identify the precise d -wave gap symmetry is to measure Hc 2 at a number of different temperatures, and examine whether there is a π /4 shift in its angular dependence at certain T*. We further show that Landau level mixing does not change this general feature. However, in the presence of Fulde-Ferrell-Larkin-Ovchinnikov state, the angular dependence of Hc 2 becomes quite complicated, which makes it more difficult to determine the gap symmetry by measuring Hc 2. Our results indicate that some previous studies on the gap symmetry of CeCu2Si2 are unreliable and need to be reexamined, and also provide a candidate solution to an experimental discrepancy in the angle-resolved Hc 2 in CeCoIn5.

Electron-positron momentum density in Tl 2Ba 2CuO 6

NASA Astrophysics Data System (ADS)

Barbiellini, B.; Gauthier, M.; Hoffmann, L.; Jarlborg, T.; Manuel, A. A.; Massidda, S.; Peter, M.; Triscone, G.

1994-08-01

We present calculations of the electron-positron momentum density for the high- Tc superconductor Tl 2Ba 2CuO 6, together with some preliminary two-dimensional angular correlation of the annihilation radiation (2D-ACAR) measurements. The calculations are based on the first-principles electronic structure obtained using the full-potential linearized augmented plane wave (FLAPW) and the linear muffin-tin orbital (LMTO) methods. We also use a linear combination of the atomic orbitals-molecular orbital method (LCAO-MO) to discuss orbital contributions to the anisotropies. Some agreement between calculated and measured 2D-ACAR anisotropies encourage sample improvement for further Fermi surface investigations. Indeed, our results indicate a non-negligle overlap of the positron wave function with the CuOo 2 plane electrons. Therefore, this compound may be well suited for investigating the relevant CuO 2 Fermi surface by 2D-ACAR.

Direct Detection and Orbit Analysis of the Exoplanets HR 8799 bcd from Archival 2005 Keck/NIRC2 Data

NASA Technical Reports Server (NTRS)

Currie, Thayne; Fukagawa, Misato; Thalmann, Christian; Matsumura, Soko; Plavchan, Peter

2012-01-01

We present previously unpublished July 2005 H-band coronagraphic data of the young, planet-hosting star HR 8799 from the newly-released Keck/NIRC2 archive. Despite poor observing conditions, we detect three of the planets (HR 8799 bcd), two of them (HR 8799 bc) without advanced image processing. Comparing these data with previously published 1998-2011 astrometry and that from re-reduced October 2010 Keck data constrains the orbits of the planets. Analyzing the planets' astrometry separately, HR 8799 d's orbit is likely inclined at least 25 deg from face-on and the others may be on in inclined orbits. For semimajor axis ratios consistent with a 4:2:1 mean-motion resonance our analysis yields precise values for HR 8799 bcd's orbital parameters and strictly constrains the planets' eccentricities to be less than 0.18-0.3. However, we find no acceptable orbital solutions with this resonance that place the planets in face-on orbits; HR 8799 d shows the largest deviation from such orbits. Moreover, few orbits make HR 8799 d coplanar with b and c, whereas dynamical stability analyses used to constrain the planets' masses typically assume coplanar and/or fare.on orbits. This paper illustrates the significant science gain enabled with the release of the NIRC2 archive.

Orbiting Carbon Observatory-2 (OCO-2) Briefing

NASA Image and Video Library

2014-06-29

Ken Jucks, OCO-2 program scientist, NASA Headquarters talks during an Orbiting Carbon Observatory-2 (OCO-2) science briefing, Sunday, June 29, 2014, Vandenberg Air Force Base, Calif. OCO-2 will measure the global distribution of carbon dioxide, the leading human-produced greenhouse gas driving changes in Earth’s climate. OCO-2 is set to launch on July 1, 2014 at 2:59 a.m. PDT. Photo Credit: (NASA/Bill Ingalls)

Orbiting Carbon Observatory-2 (OCO-2) Briefing

NASA Image and Video Library

2014-06-29

Dave Crisp, OCO-2 science team leader, JPL talks during an Orbiting Carbon Observatory-2 (OCO-2) science briefing, Sunday, June 29, 2014, Vandenberg Air Force Base, Calif. OCO-2 will measure the global distribution of carbon dioxide, the leading human-produced greenhouse gas driving changes in Earth’s climate. OCO-2 is set to launch on July 1, 2014 at 2:59 a.m. PDT. Photo Credit: (NASA/Bill Ingalls)

Orbiting Carbon Observatory-2 (OCO-2) Briefing

NASA Image and Video Library

2014-06-29

Annmarie Eldering, OCO-2 deputy project scientist, JPL talks during an Orbiting Carbon Observatory-2 (OCO-2) science briefing, Sunday, June 29, 2014, Vandenberg Air Force Base, Calif. OCO-2 will measure the global distribution of carbon dioxide, the leading human-produced greenhouse gas driving changes in Earth’s climate. OCO-2 is set to launch on July 1, 2014 at 2:59 a.m. PDT. Photo Credit: (NASA/Bill Ingalls)

CONSTRAINTS ON CHARON'S ORBITAL ELEMENTS FROM THE DOUBLE STELLAR OCCULTATION OF 2008 JUNE 22

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sicardy, B.; Lecacheux, J.; Boissel, Y.

Pluto and its main satellite, Charon, occulted the same star on 2008 June 22. This event was observed from Australia and La Reunion Island, providing the east and north Charon Plutocentric offset in the sky plane (J2000): X= + 12,070.5 {+-} 4 km (+ 546.2 {+-} 0.2 mas), Y= + 4,576.3 {+-} 24 km (+ 207.1 {+-} 1.1 mas) at 19:20:33.82 UT on Earth, corresponding to JD 2454640.129964 at Pluto. This yields Charon's true longitude L= 153.483 {+-} 0.{sup 0}071 in the satellite orbital plane (counted from the ascending node on J2000 mean equator) and orbital radius r= 19,564 {+-}more » 14 km at that time. We compare this position to that predicted by (1) the orbital solution of Tholen and Buie (the 'TB97' solution), (2) the PLU017 Charon ephemeris, and (3) the solution of Tholen et al. (the 'T08' solution). We conclude that (1) our result rules out solution TB97, (2) our position agrees with PLU017, with differences of {Delta}L= + 0.073 {+-} 0.{sup 0}071 in longitude, and {Delta}r= + 0.6 {+-} 14 km in radius, and (3) while the difference with the T08 ephemeris amounts to only {Delta}L= 0.033 {+-} 0.{sup 0}071 in longitude, it exhibits a significant radial discrepancy of {Delta}r= 61.3 {+-} 14 km. We discuss this difference in terms of a possible image scale relative error of 3.35 x 10{sup -3}in the 2002-2003 Hubble Space Telescope images upon which the T08 solution is mostly based. Rescaling the T08 Charon semi-major axis, a = 19, 570.45 km, to the TB97 value, a = 19636 km, all other orbital elements remaining the same ('T08/TB97' solution), we reconcile our position with the re-scaled solution by better than 12 km (or 0.55 mas) for Charon's position in its orbital plane, thus making T08/TB97 our preferred solution.« less

Transport through graphenelike flakes with intrinsic spin-orbit interactions

NASA Astrophysics Data System (ADS)

Weymann, I.; Barnaś, J.; Krompiewski, S.

2015-07-01

It was shown recently [J. L. Lado and J. Fernández-Rossier, Phys. Rev. Lett. 113, 027203 (2014), 10.1103/PhysRevLett.113.027203] that edge magnetic moments in graphene-like nanoribbons are strongly influenced by the intrinsic spin-orbit interaction. Due to this interaction an anisotropy comes about which makes the in-plane arrangement of magnetic moments energetically more favorable than that corresponding to the out-of-plane configuration. In this paper we raise both the edge magnetism problem and the differential conductance and shot noise Fano factor issues, in the context of finite-size flakes within the Coulomb blockade (CB) transport regime. Our findings elucidate the following problems: (i) modification of CB diamonds by the appearance of in-plane magnetic moments and (ii) modification of CB diamonds by the intrinsic spin-orbit interaction.

Stability and evolution of orbits around the binary asteroid 175706 (1996 FG3): Implications for the MarcoPolo-R mission

NASA Astrophysics Data System (ADS)

Hussmann, Hauke; Oberst, Jürgen; Wickhusen, Kai; Shi, Xian; Damme, Friedrich; Lüdicke, Fabian; Lupovka, Valery; Bauer, Sven

2012-09-01

In support of the MarcoPolo-R mission, we have carried out numerical simulations of spacecraft trajectories about the binary asteroid 175706 (1996 FG3) under the influence of solar radiation pressure. We study the effects of (1) the asteroid's mass, shape, and rotational parameters, (2) the secondary's mass, shape, and orbit parameters, (3) the spacecraft's mass, surface area, and reflectivity, and (4) the time of arrival, and therefore the relative position to the sun and planets. We have considered distance regimes between 5 and 20 km, the typical range for a detailed characterization of the asteroids - primary and secondary - with imaging systems, spectrometers and by laser altimetry. With solar radiation pressure and gravity forces of the small asteroid competing, orbits are found to be unstable, in general. However, limited orbital stability can be found in the so-called Self-Stabilized Terminator Orbits (SSTO), where initial orbits are circular, orbital planes are oriented approximately perpendicular to the solar radiation pressure, and where the orbital plane of the spacecraft is shifted slightly (between 0.2 and 1 km) from the asteroid in the direction away from the sun. Under the effect of radiation pressure, the vector perpendicular to the orbit plane is observed to follow the sun direction. Shape and rotation parameters of the asteroid as well as gravitational perturbations by the secondary (not to mention sun and planets) were found not to affect the results. Such stable orbits may be suited for long radio tracking runs, which will allow for studying the gravity field. As the effect of the solar radiation pressure depends on the spacecraft mass, shape, and albedo, good knowledge of the spacecraft model and persistent monitoring of the spacecraft orientation are required.

Charge efficiency of Ni/H2 cells during transfer orbit of Telstar 4 satellites

NASA Technical Reports Server (NTRS)

Fang, W. C.; Maurer, Dean W.; Vyas, B.; Thomas, M. N.

1994-01-01

The TELSTAR 4 communication satellites being manufactured by Martin Marietta Astro Space (Astro Space) for AT&T are three axis stabilized spacecraft scheduled to be launched on expendable vehicles such as the Atlas or Ariane rockets. Typically, these spacecraft consist of a box that holds the electronics and supports the antenna reflectors and the solar array wings. The wings and reflectors are folded against the sides of the box during launch and the spacecraft is spun for attitude control in that phase; they are then deployed after achieving the final orbit. The launch phase and transfer orbits required to achieve the final geosynchronous orbit typically take 4 to 5 days during which time the power required for command, telemetry, attitude control, heaters, etc., is provided by two 50 AH nickel hydrogen batteries augmented by the exposed outboard solar panels. In the past, this situation has presented no problem since there was a considerable excess of power available from the array. In the case of large high powered spacecraft such as TELSTAR 4, however, the design power levels in transfer orbit approach the time-averaged power available from the exposed surface area of the solar arrays, resulting in a very tight power margin. To compound the difficulty, the array output of the spinning spacecraft in transfer orbit is shaped like a full wave rectified sine function and provides very low charging rates to the batteries during portions of the rotation. In view of the typically low charging efficiency of alkaline nickel batteries at low rates, it was decided to measure the efficiency during a simulation of the TELSTAR 4 conditions at the expected power levels and temperatures on three nickel hydrogen cells of similar design. The unique feature of nickel hydrogen cells that makes the continuous measurement of efficiency possible is that hydrogen is one of the active materials and thus, cell pressure is a direct measure of the state of charge or available capacity

Penetration Depth Study of Superconducting Gap Structure of 2H-NbSe2

NASA Astrophysics Data System (ADS)

Fletcher, J. D.; Carrington, A.; Diener, P.; Rodière, P.; Brison, J. P.; Prozorov, R.; Olheiser, T.; Giannetta, R. W.

2007-02-01

We report measurements of the temperature dependence of both in-plane and out-of-plane penetration depths (λa and λc, respectively) in 2H-NbSe2. Measurements were made with a radio-frequency tunnel diode oscillator circuit at temperatures down to 100 mK. Analysis of the anisotropic superfluid density shows that a reduced energy gap is located on one or more of the quasi-two-dimensional Nb Fermi surface sheets rather than on the Se sheet, in contrast with some previous reports. This result suggests that the gap structure is not simply related to the weak electron-phonon coupling on the Se sheet and is therefore important for microscopic models of anisotropic superconductivity in this compound.

On the stability of satellite planes - I. Effects of mass, velocity, halo shape and alignment

NASA Astrophysics Data System (ADS)

Fernando, Nuwanthika; Arias, Veronica; Guglielmo, Magda; Lewis, Geraint F.; Ibata, Rodrigo A.; Power, Chris

2017-02-01

The recently discovered vast thin plane of dwarf satellites orbiting the Andromeda Galaxy (M31) adds to the mystery of the small-scale distribution of the Local Group's galaxy population. Such well-defined planar structures are apparently rare occurrences in cold dark matter cosmological simulations, and we lack a coherent explanation of their formation and existence. In this paper, we explore the long-term survivability of thin planes of dwarfs in galactic haloes, focusing, in particular, on systems mimicking the observed Andromeda distribution. The key results show that, in general, planes of dwarf galaxies are fragile, sensitive to the shape of the dark matter halo and other perturbing effects. In fact, long-lived planes of satellites only exist in polar orbits in spherical dark matter haloes, presenting a challenge to the observed Andromeda plane that is significantly tilted with respect to the optical disc. Our conclusion is that, in the standard cosmological models, planes of satellites are generally short lived, and hence we must be located at a relatively special time in the evolution of the Andromeda Plane, lucky enough to see its coherent pattern.

Exospheric perturbations by radiation pressure. II - Solution for orbits in the ecliptic plane

NASA Technical Reports Server (NTRS)

Chamberlain, J. W.

1980-01-01

A previous study (Chamberlain, 1979) gave solutions for the mean time rates of change of orbital elements of satellite atoms in an exosphere influenced by solar radiation pressure; each element was assumed to behave independently. In the present paper, the instantaneous rates of changes for three elements (e, Omega, and phi = omega + Omega) are integrated simultaneously for the case of the inclination i = 0. The results confirm the validity of using mean rates when the orbits are tighly bound to the planet, and serve as examples to be reproduced by the complicated numerical solutions required for arbitrary inclination. Strongly bound hydrogen atoms perturbed in earth orbit by radiation pressure do not seem a likely cause of the geotail extending in the anti-sun direction. Instead, radiation pressure will cause those particles' orbits to form a broad fan-shaped tail and to deteriorate into the earth's atmosphere.

Resolving z ~2 galaxy using adaptive coadded source plane reconstruction

NASA Astrophysics Data System (ADS)

Sharma, Soniya; Richard, Johan; Kewley, Lisa; Yuan, Tiantian

2018-06-01

Natural magnification provided by gravitational lensing coupled with Integral field spectrographic observations (IFS) and adaptive optics (AO) imaging techniques have become the frontier of spatially resolved studies of high redshift galaxies (z>1). Mass models of gravitational lenses hold the key for understanding the spatially resolved source–plane (unlensed) physical properties of the background lensed galaxies. Lensing mass models very sensitively control the accuracy and precision of source-plane reconstructions of the observed lensed arcs. Effective source-plane resolution defined by image-plane (observed) point spread function (PSF) makes it challenging to recover the unlensed (source-plane) surface brightness distribution.We conduct a detailed study to recover the source-plane physical properties of z=2 lensed galaxy using spatially resolved observations from two different multiple images of the lensed target. To deal with PSF’s from two data sets on different multiple images of the galaxy, we employ a forward (Source to Image) approach to merge these independent observations. Using our novel technique, we are able to present a detailed analysis of the source-plane dynamics at scales much better than previously attainable through traditional image inversion methods. Moreover, our technique is adapted to magnification, thus allowing us to achieve higher resolution in highly magnified regions of the source. We find that this lensed system is highly evident of a minor merger. In my talk, I present this case study of z=2 lensed galaxy and also discuss the applications of our algorithm to study plethora of lensed systems, which will be available through future telescopes like JWST and GMT.

Stable Orbits in the Didymos Binary Asteroid System - Useful Platforms for Exploration

NASA Astrophysics Data System (ADS)

Damme, Friedrich; Hussmann, Hauke; Wickhusen, Kai; Enrico, Mai; Oberst, Jürgen

2016-04-01

We have analyzed particle motion in binary asteroid systems to search for stable orbits. In particular, we studied the motion of particles near the asteroid 1996 GT (Didymos), proposed as a target for the AIDA mission. The combined gravity fields of the odd-shaped rotating objects moving about each other are complex. In addition, orbiting spacecraft or dust particles are affected by radiation pressure, possibly exceeding the faint gravitational forces. For the numerical integrations, we adopt parameters for size, shape, and rotation from telescopic observations. To simulate the effect of radiation pressure during a spacecraft mission, we apply a spacecraft wing-box shape model. Integrations were carried out beginning in near-circular orbits over 11 days, during which the motion of the particles were examined. Most orbits are unstable with particles escaping quickly or colliding with the asteroid bodies. However, with carefully chosen initial positions, we found stable motion (in the orbiting plane of the secondary) associated with the Lagrangian points (L4 and L5), in addition to horseshoe orbits, where particles move from one of the Lagrangian point to the other. Finally, we examined orbits in 1:2 resonances with the motion of the orbital period of the secondary. Stable conditions depend strongly on season caused by the inclination of the mutual orbit plane with respect to Didymos solar orbit. At larger distance from the asteroid pair, we find the well-known terminator orbits where gravitational attraction is balanced against radiation pressure. Stable orbits and long motion arcs are useful for long tracking runs by radio or Laser instruments and are well-suited for modelling of the ephemerides of the asteroid pair and gravity field mapping. Furthermore, these orbits may be useful as observing posts or as platforms for approach. These orbits may also represent traps for dust particles, an opportunity for dust collection - or possibly a hazard to spacecraft

Introduction to orbital flight planning (1)

NASA Technical Reports Server (NTRS)

Blackwell, H. E. (Editor); Davis, E. L.; Dell, D. D.

1981-01-01

This workbook is designed for students interested in space flight planning, who after training, may serve as flight planning aides. Routine flight planning activities requiring engineering-type calculations and analysis are covered. Practice exercises and brief instructions are given for the programming and use of the hand calculator as well as the calculation of position and velocity in the orbital plane. Calculation of relative orbital position is also covered with emphasis upon celestial coordinates and time measurement.

Orbiting Carbon Observatory-2 (OCO-2) Launch

NASA Image and Video Library

2014-07-02

Lights shine on the umbilical tower shortly after a United Launch Alliance Delta II rocket launched with the Orbiting Carbon Observatory-2 (OCO-2)satellite onboard from Space Launch Complex 2 at Vandenberg Air Force Base, Calif. on Wednesday, July 2, 2014. OCO-2 will measure the global distribution of carbon dioxide, the leading human-produced greenhouse gas driving changes in Earth’s climate. Photo Credit: (NASA/Bill Ingalls)

Optimum Orbit Plane Change Using a Skip Reentry Trajectory for the Space Shuttle Orbiter.

DTIC Science & Technology

1978-12-01

by the hat symbol, " , and i,j,k represent unit vectors for the YW frame. The angular velocity of the earth is constant and denoted by w. Thus V re is...the equations of motion can be found. In component form the equations are: (6M/r3)x + 4 (Cos - sn ) vst 1 mm Msv 3 b1 bm y - (uM/r3)y + L (coso...plane change, due to the skip reentry maneuver is determined by comparing the states of the system before and after the maneuver. The angular momentum

Relativity mission with two counter-orbiting polar satellites. [nodal dragging effect on earth orbiting satellites

NASA Technical Reports Server (NTRS)

Van Patten, R. A.; Everitt, C. W. F.

1975-01-01

In 1918, J. Lense and H. Thirring calculated that a moon in orbit around a massive rotating planet would experience a nodal dragging effect due to general relativity. We describe an experiment to measure this effect with two counter-orbiting drag-free satellites in polar earth orbit. For a 2 1/2 year experiment, the measurement accuracy should approach 1%. In addition to precision tracking data from existing ground stations, satellite-to-satellite Doppler ranging data are taken at points of passing near the poles. New geophysical information on both earth harmonics and tidal effects is inherent in the polar ranging data.

Self-doping processes between planes and chains in the metal-to-superconductor transition of YBa2Cu3O6.9.

PubMed

Magnuson, M; Schmitt, T; Strocov, V N; Schlappa, J; Kalabukhov, A S; Duda, L-C

2014-11-12

The interplay between the quasi 1-dimensional CuO-chains and the 2-dimensional CuO2 planes of YBa(2)Cu(3)O(6+x) (YBCO) has been in focus for a long time. Although the CuO-chains are known to be important as charge reservoirs that enable superconductivity for a range of oxygen doping levels in YBCO, the understanding of the dynamics of its temperature-driven metal-superconductor transition (MST) remains a challenge. We present a combined study using x-ray absorption spectroscopy and resonant inelastic x-ray scattering (RIXS) revealing how a reconstruction of the apical O(4)-derived interplanar orbitals during the MST of optimally doped YBCO leads to substantial hole-transfer from the chains into the planes, i.e. self-doping. Our ionic model calculations show that localized divalent charge-transfer configurations are expected to be abundant in the chains of YBCO. While these indeed appear in the RIXS spectra from YBCO in the normal, metallic, state, they are largely suppressed in the superconducting state and, instead, signatures of Cu trivalent charge-transfer configurations in the planes become enhanced. In the quest for understanding the fundamental mechanism for high-Tc-superconductivity (HTSC) in perovskite cuprate materials, the observation of such an interplanar self-doping process in YBCO opens a unique novel channel for studying the dynamics of HTSC.

Phase formation and strain relaxation of Ga2O3 on c-plane and a-plane sapphire substrates as studied by synchrotron-based x-ray diffraction

NASA Astrophysics Data System (ADS)

Cheng, Zongzhe; Hanke, Michael; Vogt, Patrick; Bierwagen, Oliver; Trampert, Achim

2017-10-01

Heteroepitaxial Ga2O3 was deposited on c-plane and a-plane oriented sapphire by plasma-assisted molecular beam epitaxy and probed by ex-situ and in-situ synchrotron-based x-ray diffraction. The investigation on c-plane sapphire determined a critical thickness of around 33 Å, at which the monoclinic β-phase forms on top of the hexagonal α-phase. A 143 Å thick single phase α-Ga2O3 was observed on a-plane sapphire, much thicker than the α-Ga2O3 on c-plane sapphire. The α-Ga2O3 relaxed very fast in the first 30 Å in both out-of-plane and in-plane directions as measured by the in-situ study.

MICROWAVE SPECTRA AND GEOMETRIES OF C2H_{2\\cdots AgI} and C2H_{4\\cdots AgI}

NASA Astrophysics Data System (ADS)

Stephens, Susanna L.; Tew, David Peter; Walker, Nick; Legon, Anthony

2015-06-01

A chirped-pulse Fourier transform microwave spectrometer has been used to measure the microwave spectra of both C2H_{2\\cdots AgI} and C2H_{4\\cdots AgI}. These complexes are generated via laser ablation at 532 nm of a silver surface in the presence of CF3I and either C2H_{2} or C2H_{4} and argon and are stabilized by a supersonic expansion. Rotational (A0, B0, C0) and centrifugal distortion constants (ΔJ and ΔJK) of each molecule have been determined as well the nuclear electric quadrupole coupling constants the iodine atom (χaa(I) and χbb-χcc(I)). The spectrum of each molecule is consistent with a C2v structure in which the metal atom interacts with the π-orbital of the ethene or ethyne molecule. Isotopic substitutions of atoms within the C2H_{2} or C2H_{4} subunits are in progress and in conjunction with high level ab initio calculations will allow for accurate determination of the geometry of each molecule. These to complexes are put in the context of the recently studied H2S\\cdots AgI, OC\\cdotsAgI, H3N\\cdots AgI and (CH3)_{3N\\cdots AgI}. S.Z. Riaz, S.L. Stephens, W. Mizukami, D.P. Tew, N.R. Walker, A.C. Legon, Chem. Phys. Let., 531, 1-12 (2012) S.L. Stephens, W. Mizukami, D.P. Tew, N.R. Walker, A.C. Legon, J. Chem. Phys., 136(6), 064306 (2012) D.M. Bittner, D.P. Zaleski, S.L. Stephens, N.R. Walker, A.C. Legon, Study in progress.

Orbit Determination of Spacecraft in Earth-Moon L1 and L2 Libration Point Orbits

NASA Technical Reports Server (NTRS)

Woodard, Mark; Cosgrove, Daniel; Morinelli, Patrick; Marchese, Jeff; Owens, Brandon; Folta, David

2011-01-01

The ARTEMIS mission, part of the THEMIS extended mission, is the first to fly spacecraft in the Earth-Moon Lissajous regions. In 2009, two of the five THEMIS spacecraft were redeployed from Earth-centered orbits to arrive in Earth-Moon Lissajous orbits in late 2010. Starting in August 2010, the ARTEMIS P1 spacecraft executed numerous stationkeeping maneuvers, initially maintaining a lunar L2 Lissajous orbit before transitioning into a lunar L1 orbit. The ARTEMIS P2 spacecraft entered a L1 Lissajous orbit in October 2010. In April 2011, both ARTEMIS spacecraft will suspend Lissajous stationkeeping and will be maneuvered into lunar orbits. The success of the ARTEMIS mission has allowed the science team to gather unprecedented magnetospheric measurements in the lunar Lissajous regions. In order to effectively perform lunar Lissajous stationkeeping maneuvers, the ARTEMIS operations team has provided orbit determination solutions with typical accuracies on the order of 0.1 km in position and 0.1 cm/s in velocity. The ARTEMIS team utilizes the Goddard Trajectory Determination System (GTDS), using a batch least squares method, to process range and Doppler tracking measurements from the NASA Deep Space Network (DSN), Berkeley Ground Station (BGS), Merritt Island (MILA) station, and United Space Network (USN). The team has also investigated processing of the same tracking data measurements using the Orbit Determination Tool Kit (ODTK) software, which uses an extended Kalman filter and recursive smoother to estimate the orbit. The orbit determination results from each of these methods will be presented and we will discuss the advantages and disadvantages associated with using each method in the lunar Lissajous regions. Orbit determination accuracy is dependent on both the quality and quantity of tracking measurements, fidelity of the orbit force models, and the estimation techniques used. Prior to Lissajous operations, the team determined the appropriate quantity of tracking

In-orbit performance of a helium dewar for the soft X-ray spectrometer onboard ASTRO-H

NASA Astrophysics Data System (ADS)

Yoshida, Seiji; Miyaoka, Mikio; Kanao, Ken'ichi; Tsunematsu, Shoji; Otsuka, Kiyomi; Hoshika, Shunji; Narasaki, Katsuhiro; Mitsuda, Kazuhisa; Yamasaki, Noriko; Takei, Yoh; Fujimoto, Ryuichi; Ezoe, Yuichiro; Sato, Yoichi; Okamoto, Atsushi; Noda, Hirofumi; DiPirro, Michael; Shirron, Peter

2018-04-01

ASTRO-H was an X-ray astronomy satellite that the Japan Aerospace Exploration Agency (JAXA) developed to study the evolution of the universe and physical phenomena yet to be discovered. The primary scientific instrument of ASTRO-H was the Soft X-ray Spectrometer (SXS). Its detectors were to be cooled to 50 m K using a complex cryogenic system with a multistage adiabatic demagnetization refrigerator (ADR) developed by the National Aeronautics and Space Administration (NASA), and a cryogenic system developed by Sumitomo Heavy Industries, Ltd. (SHI). SHI's cryogenic system was required to cool the ADR's heatsink to 1.3 K or less in orbit for three years or longer. To meet these requirements, SHI developed a hybrid cryogenic system consisting of a liquid helium tank, a 4 K Joule-Thomson cooler, and two two-stage Stirling coolers. ASTRO-H was launched from Tanegashima Space Center on February 17, 2016. The initial operation of the SXS cryogenic system in orbit was completed successfully. The cooling performance was as expected and could have exceeded the lifetime requirement of three years. This paper describes results of ground tests, results of top-off filling of superfluid liquid helium just before launch, and cooling performance in orbit.

Human Mars Mission: Launch Window from Earth Orbit. Pt. 1

NASA Technical Reports Server (NTRS)

Young, Archie

1999-01-01

The determination of orbital window characteristics is of major importance in the analysis of human interplanetary missions and systems. The orbital launch window characteristics are directly involved in the selection of mission trajectories, the development of orbit operational concepts, and the design of orbital launch systems. The orbital launch window problem arises because of the dynamic nature of the relative geometry between outgoing (departure) asymptote of the hyperbolic escape trajectory and the earth parking orbit. The orientation of the escape hyperbola asymptotic relative to the earth is a function of time. The required hyperbola energy level also varies with time. In addition, the inertial orientation of the parking orbit is a function of time because of the perturbations caused by the Earth's oblateness. Thus, a coplanar injection onto the escape hyperbola can be made only at a point in time when the outgoing escape asymptote is contained by the plane of parking orbit. Even though this condition may be planned as a nominal situation, it will not generally represent the more probable injection geometry. The general case of an escape injection maneuver performed at a time other than the coplanar time will involve both a path angle and plane change and, therefore, a delta V penalty. Usually, because of the delta V penalty the actual departure injection window is smaller in duration than that determined by energy requirement alone. This report contains the formulation, characteristics, and test cases for five different launch window modes for Earth orbit. These modes are: 1) One impulsive maneuver from a Highly Elliptical Orbit (HEO); 2) Two impulsive maneuvers from a Highly Elliptical Orbit (HEO); 3) One impulsive maneuver from a Low Earth Orbit (LEO); 4) Two impulsive maneuvers form LEO; and 5) Three impulsive maneuvers form LEO. The formulation of these five different launch window modes provides a rapid means of generating realistic parametric data

Orbit Selection for Earth Observation Missions

NASA Technical Reports Server (NTRS)

King, J. C.

1978-01-01

The orbit selection process is simplified for most earth-oriented satellite missions by a restriction to circular orbits, which reduces the primary orbit characteristics to be determined to only two: altitude and inclination. A number of important mission performance characteristics depend on these choices, however, so a major part of the orbit selection task is concerned with developing the correlating relationships in clear and convenient forms to provide a basis for rational orbit selection procedures. The present approach to that task is organized around two major areas of mission performance, orbit plane precession and coverage pattern development, whose dependence on altitude and inclination is delineated graphically in design chart form. These charts provide a visual grasp of the relationships between the quantities cited above, as well as other important mission performance parameters including viewing time of day (solar), sensor swath width (and fields of view), swath sequencing, and pattern repeat condition and repeat periods.

Orbiting Carbon Observatory-2 (OCO-2) Briefing

NASA Image and Video Library

2014-06-29

Annmarie Eldering, OCO-2 deputy project scientist, JPL is seen talking on the monitors during an Orbiting Carbon Observatory-2 (OCO-2) science briefing, Sunday, June 29, 2014, Vandenberg Air Force Base, Calif. OCO-2 will measure the global distribution of carbon dioxide, the leading human-produced greenhouse gas driving changes in Earth’s climate. OCO-2 is set to launch on July 1, 2014 at 2:59 a.m. PDT. Photo Credit: (NASA/Bill Ingalls)

Orbiting Carbon Observatory-2 (OCO-2) Launch

NASA Image and Video Library

2014-07-02

Members of the media are unable to see the launch of the United Launch Alliance Delta II rocket with the Orbiting Carbon Observatory-2 (OCO-2) satellite onboard due to heavy fog at Vandenberg Air Force Base, Calif. on Wednesday, July 2, 2014. OCO-2 launched at 2:56 a.m. PDT. OCO-2 will measure the global distribution of carbon dioxide, the leading human-produced greenhouse gas driving changes in Earth’s climate. Photo Credit: (NASA/Bill Ingalls)

DFT studies on H 2O adsorption and its effect on CO oxidation over spinel Co 3O 4 (110) surface

NASA Astrophysics Data System (ADS)

Xu, Xiang Lan; Li, Jun Qian

2011-12-01

Adsorption of H2O and its effect on CO oxidation over spinel Co3O4 (110) surface were studied by density functional theory calculations. H2O is adsorbed favorably at the octahedral cobalt (Cooct) site through O atom on the surface. Hydrogen bonding interaction between 1s orbitals of H atoms in H2O and the 2p orbitals of surface active oxygen sites plays a key role for H2O adsorption. The inhibition effect of H2O adsorption on the CO oxidation over the surfaces is attributed to the competition between H2O and CO molecules for the surface twofold coordinated oxygen site.

Ofeq-2 orbit, attitude, and flight evaluation

NASA Astrophysics Data System (ADS)

Grumer, Michael; Komem, Joseph; Kronenfeld, Joseph; Kubitski, Ophir; Lorber, Vitaly; Shyldkrot, Haim

1992-02-01

The most significant events and phenomena that occurred during the Ofeq-2 flight are evaluated in this work. Particular attention is paid to the physical and technological factors which affected its orbital lifetime. Comparison of Ofeq-2 telemetry results with prelaunch estimations and with Ofeq-1 flight data are presented. The satellite's orbit and mission characteristics are defined and the principal systems of Ofeq-2 are described. Topics addressed include the interaction between the spinner's attitude with respect to the sun and consequent electric power generation. The coning angle development history, the role of the solar data evaluation, and the factors influencing drag are also analyzed. All of these affected the Ofeq-2 power outage-recovery event. The orbit determination and the coning angle evolution estimation methods are discussed in some detail. A brief report on radiation effects on computer RAM (random access memory) is also given. An integrative systems engineering approach summary of the telemetry data reconstruction and analysis concludes the paper.

Structure and spectra of H/sub 2/O in hydrated. beta. -alumina

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bates, J.B.; Dudney, N.J.; Brown, G.M.

1982-11-15

The structure and spectra of hydrated Li and Na ..beta..-alumina were investigated using neutron diffraction, infrared absorption, and Raman scattering. The dimensions of the hexagonal unit cell of a hydrated Li ..beta..-alumina crystal containing 1.55 H/sub 2/O molecules per unit cell are a = 5.591 A and c = 22.715 A. The oxygen atoms of the water molecules are located in the conduction plane between the mO, and the aBR sites; the protons, located above the below the plane, form bent hydrogen bonds with the O(4) oxygen ions. The HOH bond angle of water in Li ..beta..-alumina is 114/sup 0/more » and the Vertical BarO--HVertical Bar bond distance is 0.992 A. Based on polarized infrared spectra, H/sub 2/O adopts a similar structure and orientation in Na ..beta..-alumina. Spectra of absorbed H/sub 2/O, D/sub 2/O, and HDO species show that water molecules dissociate in Li ..beta..-alumina to form OH/sup -/ and H(H/sub 2/O)/sup +//sub n/ species. No evidence was found for the dissociation of water in Na ..beta..-alumina. The absorption coefficients determined for OH/sup -/ and H/sub 2/O in Li ..beta..-alumina include local field corrections. A large local field anisotropy at the protons of H/sub 2/O is responsible for the large ratio of the intensities of ..nu../sub 3/ and ..nu../sub 1/ observed for water in Li and Na ..beta..-alumina.« less

Hydrogen bonding: part 78. Ab initio molecular orbital study of intra- and intermolecular hydrogen bonding in choline and betaine and their compounds with HF and H 2O

NASA Astrophysics Data System (ADS)

Harmon, K. M.; Avci, G. F.; Madeira, S. L.; Mounts, P. A.; Thiel, A. C.

2001-10-01

We previously prepared several compounds of the zwitterions [(CH3)3NCH2CH2O]0 (deprotonated choline, herein named cholaine) and [(CH3)3NCH2CO2]0 (betaine) and proposed structures based on infrared spectroscopy. We now examine these compounds with use of ab initio molecular orbital methods to further elucidate possible structure. These calculations demonstrate that: (1) cholaine and betaine both have internal CHO hydrogen bonds, and these are retained in some form in all other compounds. (2) Cholaine hydrate and hydrofluoride and betaine hydrofluoride monomers have covalent three-center hydrogen bonds between H2O or HF and negative zwitterion oxygen, and additional CHX hydrogen bonds to H2O oxygen or HF fluorine. (3) Cholaine monohydrate and cholaine hydrofluoride monohydrate form dimers of Ci symmetry which contain planar C2h (H2O·O)2 and (HOH·F)2 clusters. (4) Cholaine hydrofluoride forms head-to-tail dimers bound by intermolecular CHX hydrogen bonds; this arrangement could lead to extended linear structures in the solid state. (5) Betaine hydrofluoride, in contrast, forms a tightly bound discrete dimeric unit in which two molecules join in a head-to-head manner held together by five intermolecular hydrogen bonds and by the mutual proximities of negative fluorides to positive nitrogens.

Orbital Engineering: Photoactivation of an Organofunctionalized Polyoxotungstate.

PubMed

Cameron, Jamie M; Fujimoto, Satomi; Kastner, Katharina; Wei, Rong-Jia; Robinson, David; Sans, Victor; Newton, Graham N; Oshio, H Hiroki

2017-01-01

Tungsten-based polyoxometalates (POMs) have been employed as UV-driven photo-catalysts for a range of organic transformations. Their photoactivity is dependent on electronic transitions between frontier orbitals and thus manipulation of orbital energy levels provides a promising means of extending their utility into the visible regime. Herein, an organic-inorganic hybrid polyoxometalate, K 6 [P 2 W 17 O 57 (PO 5 H 5 C 7 ) 2 ]⋅6 C 4 H 9 NO, was found to exhibit enhanced redox behaviour and photochemistry compared to its purely inorganic counterparts. Hybridization with electron-withdrawing moieties was shown to tune the frontier orbital energy levels and reduce the HOMO-LUMO gap, leading to direct visible-light photoactivation of the hybrid and establishing a simple, cheap and effective approach to the generation of visible-light-activated hybrid nanomaterials. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Spin-orbit coupling effects in indium antimonide quantum well structures

NASA Astrophysics Data System (ADS)

Dedigama, Aruna Ruwan

Indium antimonide (InSb) is a narrow band gap material which has the smallest electron effective mass (0.014m0) and the largest electron Lande g-facture (-51) of all the III-V semiconductors. Spin-orbit effects of III-V semiconductor heterostructures arise from two different inversion asymmetries namely bulk inversion asymmetry (BIA) and structural inversion asymmetry (SIA). BIA is due to the zinc-blende nature of this material which leads to the Dresselhaus spin splitting consisting of both linear and cubic in-plane wave vector terms. As its name implies SIA arises due to the asymmetry of the quantum well structure, this leads to the Rashba spin splitting term which is linear in wave vector. Although InSb has theoretically predicted large Dresselhaus (760 eVA3) and Rashba (523 eA 2) coefficients there has been relatively little experimental investigation of spin-orbit coefficients. Spin-orbit coefficients can be extracted from the beating patterns of Shubnikov--de Haas oscillations (SdH), for material like InSb it is hard to use this method due to the existence of large electron Lande g-facture. Therefore it is essential to use a low field magnetotransport technique such as weak antilocalization to extract spin-orbit parameters for InSb. The main focus of this thesis is to experimentally determine the spin-orbit parameters for both symmetrically and asymmetrically doped InSb/InxAl 1-xSb heterostructures. During this study attempts have been made to tune the Rashba spin-orbit coupling coefficient by using a back gate to change the carrier density of the samples. Dominant phase breaking mechanisms for InSb/InxAl1-xSb heterostructures have been identified by analyzing the temperature dependence of the phase breaking field from weak antilocalization measurements. Finally the strong spin-orbit effects on InSb/InxAl1-xSb heterostructures have been demonstrated with ballistic spin focusing devices.

Orbiting Carbon Observatory-2 (OCO-2) Briefing

NASA Image and Video Library

2014-06-29

NASA Kennedy Space Center Public Affairs Officer George Diller, moderates a briefing ahead of the planned launch of the Orbiting Carbon Observatory-2 (OCO-2), Sunday, June 29, 2014, Vandenberg Air Force Base, Calif. OCO-2 will measure the global distribution of carbon dioxide, the leading human-produced greenhouse gas driving changes in Earth’s climate. OCO-2 is set to launch on July 1, 2014 at 2:59 a.m. PDT. Photo Credit: (NASA/Bill Ingalls)

CCC calculated integrated cross sections of electron-H2 scattering

NASA Astrophysics Data System (ADS)

Zammit, Mark; Fursa, Dmitry; Savage, Jeremy; Bray, Igor

2016-09-01

Recently we applied the molecular convergent close-coupling (CCC) method to electron scattering from molecular hydrogen H2. Convergence of the major integrated cross sections has been explicitly demonstrated in the fixed-nuclei approximation by increasing the number of H2 target states in the close-coupling expansion from 9 to 491. The calculations have been performed using a projectile partial wave expansion with maximum orbital angular momentum Lmax = 8 and total orbital angular momentum projections | M | <= 8 . Coupling to the ionization continuum is modeled via a large pseudo state expansion, which we found is required to obtain reliable elastic and excitation cross sections. Here we present benchmark elastic, single-ionization, electronic excitation and total integrated cross sections over a broad energy range (0.1 to 300 eV) and compare with available experiment and previous calculations. Los Alamos National Laboratory and Curtin University.

Orbital flight test shuttle external tank aerothermal flight evaluation, volume 2

NASA Technical Reports Server (NTRS)

Praharaj, Sarat C.; Engel, Carl D.; Warmbrod, John D.

1986-01-01

This 3-volume report discusses the evaluation of aerothermal flight measurements made on the orbital flight test Space Shuttle External Tanks (ETs). Six ETs were instrumented to measure various quantities during flight; including heat transfer, pressure, and structural temperature. The flight data was reduced and analyzed against math models established from an extensive wind tunnel data base and empirical heat-transfer relationships. This analysis has supported the validity of the current aeroheating methodology and existing data base; and, has also identified some problem areas which require methodology modifications. Volume 1 is the Executive Summary. This is volume 2, containing Appendix A (Aerothermal Comparisons), and Appendix B (Flight-Derived h sub i/h sub u vs. M sub inf. Plots). Volume 3 contains Appendix C (Comparison of Interference Factors between OFT Flight, Prediction and 1H-97A Data), Appendix D (Freestream Stanton Number and Reynolds Number Correlation for Flight and Tunnel Data), and Appendix E (Flight-Derived h sub i/h sub u Tables).

The Actual Mass of the Object Orbiting Epsilon Eridani

NASA Astrophysics Data System (ADS)

Gatewood, G.

2000-10-01

We have tested our 112 Multichannel Astrometric Photometer (MAP) (Gatewood 1987, AJ 94, 213) observations (beginning in 1988) of Epsilon Eridani against the orbital elements provided to us by W. Cochran (private communication). The reduction algorithm is detailed most recently by Gatewood, Han, and Black (2000 ApJ Letters, in press). The seven year period is clearly shown in a variance vs trial periods plot. Although it is near the limit of the current instrument, the astrometric orbital motion is apparent in the residuals to a standard derivation of the star's proper motion and parallax. The astrometric orbital parameters derived by forcing the spectroscopic elements are: semimajor axis = 1.51 +/- 0.44 mas, node of the orbit on the sky = 120 +/- 28 deg, inclination out of the plane of the sky = 46 +/- 17 deg, actual mass = 1.2 +/- 0.33 times that of Jupiter. Our study confirms this object (this is not a minimum mass) as the nearest extrasolar Jupiter mass companion to our solar system. In view of its large orbital eccentricity, however, its exact nature remains unclear.

Lunar Ice Cube: Searching for Lunar Volatiles with a lunar cubesat orbiter

NASA Astrophysics Data System (ADS)

Clark, Pamela E.; Malphrus, Ben; Brown, Kevin; Hurford, Terry; Brambora, Cliff; MacDowall, Robert; Folta, David; Tsay, Michael; Brandon, Carl; Lunar Ice Cube Team

2016-10-01

Lunar Ice Cube, a NASA HEOMD NextSTEP science requirements-driven deep space exploration 6U cubesat, will be deployed, with 12 others, by NASA's EM1 mission. The mission's high priority science application is understanding volatile origin, distribution, and ongoing processes in the inner solar system. JPL's Lunar Flashlight, and Arizona State University's LunaH-Map, also lunar orbiters to be deployed by EM1, will provide complementary observations. Lunar Ice Cube utilizes a versatile GSFC-developed payload: BIRCHES, Broadband InfraRed Compact, High-resolution Exploration Spectrometer, a miniaturized version of OVIRS on OSIRIS-REx. BIRCHES is a compact (1.5U, 2 kg, 20 W including cryocooler) point spectrometer with a compact cryocooled HgCdTe focal plane array for broadband (1 to 4 micron) measurements and Linear Variable Filter enabling 10 nm spectral resolution. The instrument will achieve sufficient SNR to identify water in various forms, mineral bands, and potentially other volatiles seen by LCROSS (e.g., CH4) as well. GSFC is developing compact instrument electronics easily configurable for H1RG family of focal plane arrays. The Lunar Ice Cube team is led by Morehead State University, who will provide build, integrate and test the spacecraft and provide mission operations. Onboard communication will be provided by the X-band JPL Iris Radio and dual X-band patch antennas. Ground communication will be provided by the DSN X-band network, particularly the Morehead State University 21-meter substation. Flight Dynamics support is provided by GSFC. The Busek micropropulsion system in a low energy trajectory will allow the spacecraft to achieve the science orbit less than a year. The high inclination, equatorial periapsis orbit will allow coverage of overlapping swaths once every lunar cycle at up to six different times of day (from dawn to dusk) as the mission progresses during its nominal six month science mapping period. Led by the JPL Science PI, the Lunar Ice Cube

Independent Orbiter Assessment (IOA): Assessment of the orbital maneuvering subsystem, volume 2

NASA Technical Reports Server (NTRS)

Haufler, W. A.

1988-01-01

The results of the Independent Orbiter Assessment (IOA) of the Failure Modes and Effects Analysis (FMEA) and Critical Items List (CIL) are presented. The IOA effort first completed an analysis of the Orbital Maneuvering System (OMS) hardware and electrical power distribution and control (EPD and C), generating draft failure modes and potential critical items. To preserve independence, this analysis was accomplished without reliance upon the results contained within the NASA FMEA/CIL documentation. The IOA results were then compared to the proposed Post 51-L NASA FMEA/CIL baseline. This report documents the results of that comparison for the Orbiter OMS hardware and EPD and C systems. Volume 2 continues the presentation of IOA worksheets and contains the critical items list and the NASA FMEA to IOA worksheet cross reference and recommendations.

A plane of high-velocity galaxies across the Local Group

NASA Astrophysics Data System (ADS)

Banik, Indranil; Zhao, Hongsheng

2018-01-01

We recently showed that several Local Group (LG) galaxies have much higher radial velocities (RVs) than predicted by a 3D dynamical model of the standard cosmological paradigm. Here, we show that six of these seven galaxies define a thin plane with root mean square thickness of only 101 kpc despite a widest extent of nearly 3 Mpc, much larger than the conventional virial radius of the Milky Way (MW) or M31. This plane passes within ∼70 kpc of the MW-M31 barycentre and is oriented so the MW-M31 line is inclined by 16° to it. We develop a toy model to constrain the scenario whereby a past MW-M31 flyby in Modified Newtonian Dynamics (MOND) forms tidal dwarf galaxies that settle into the recently discovered planes of satellites around the MW and M31. The scenario is viable only for a particular MW-M31 orbital plane. This roughly coincides with the plane of LG dwarfs with anomalously high RVs. Using a restricted N-body simulation of the LG in MOND, we show how the once fast-moving MW and M31 gravitationally slingshot test particles outwards at high speeds. The most distant such particles preferentially lie within the MW-M31 orbital plane, probably because the particles ending up with the highest RVs are those flung out almost parallel to the motion of the perturber. This suggests a dynamical reason for our finding of a similar trend in the real LG, something not easily explained as a chance alignment of galaxies with an isotropic or mildly flattened distribution (probability = 0.0015).

Orbiting Carbon Observatory-2 (OCO-2) Briefing

NASA Image and Video Library

2014-06-29

Betsy Edwards, OCO-2 program executive, NASA Headquarters, discusses the Orbiting Carbon Observatory-2 (OCO-2), NASA’s first spacecraft dedicated to studying carbon dioxide, during a press briefing, Sunday, June 29, 2014, at the Vandenberg Air Force Base, Calif. OCO-2 will measure the global distribution of carbon dioxide, the leading human-produced greenhouse gas driving changes in Earth’s climate. OCO-2 is set to launch on July 1, 2014 at 2:59 a.m. PDT. Photo Credit: (NASA/Bill Ingalls)

Orbiting Carbon Observatory-2 (OCO-2) Briefing

NASA Image and Video Library

2014-06-29

Ralph Basilio, OCO-2 project manager, JPL, discusses the Orbiting Carbon Observatory-2 (OCO-2), NASA’s first spacecraft dedicated to studying carbon dioxide, during a press briefing, Sunday, June 29, 2014, at the Vandenberg Air Force Base, Calif. OCO-2 will measure the global distribution of carbon dioxide, the leading human-produced greenhouse gas driving changes in Earth’s climate. OCO-2 is set to launch on July 1, 2014 at 2:59 a.m. PDT. Photo Credit: (NASA/Bill Ingalls)

Pair 2-electron reduced density matrix theory using localized orbitals

NASA Astrophysics Data System (ADS)

Head-Marsden, Kade; Mazziotti, David A.

2017-08-01

Full configuration interaction (FCI) restricted to a pairing space yields size-extensive correlation energies but its cost scales exponentially with molecular size. Restricting the variational two-electron reduced-density-matrix (2-RDM) method to represent the same pairing space yields an accurate lower bound to the pair FCI energy at a mean-field-like computational scaling of O (r3) where r is the number of orbitals. In this paper, we show that localized molecular orbitals can be employed to generate an efficient, approximately size-extensive pair 2-RDM method. The use of localized orbitals eliminates the substantial cost of optimizing iteratively the orbitals defining the pairing space without compromising accuracy. In contrast to the localized orbitals, the use of canonical Hartree-Fock molecular orbitals is shown to be both inaccurate and non-size-extensive. The pair 2-RDM has the flexibility to describe the spectra of one-electron RDM occupation numbers from all quantum states that are invariant to time-reversal symmetry. Applications are made to hydrogen chains and their dissociation, n-acene from naphthalene through octacene, and cadmium telluride 2-, 3-, and 4-unit polymers. For the hydrogen chains, the pair 2-RDM method recovers the majority of the energy obtained from similar calculations that iteratively optimize the orbitals. The localized-orbital pair 2-RDM method with its mean-field-like computational scaling and its ability to describe multi-reference correlation has important applications to a range of strongly correlated phenomena in chemistry and physics.

Use of density functional theory orbitals in the GVVPT2 variant of second-order multistate multireference perturbation theory.

PubMed

Hoffmann, Mark R; Helgaker, Trygve

2015-03-05

A new variation of the second-order generalized van Vleck perturbation theory (GVVPT2) for molecular electronic structure is suggested. In contrast to the established procedure, in which CASSCF or MCSCF orbitals are first obtained and subsequently used to define a many-electron model (or reference) space, the use of an orbital space obtained from the local density approximation (LDA) variant of density functional theory is considered. Through a final, noniterative diagonalization of an average Fock matrix within orbital subspaces, quasicanonical orbitals that are otherwise indistinguishable from quasicanonical orbitals obtained from a CASSCF or MCSCF calculation are obtained. Consequently, all advantages of the GVVPT2 method are retained, including use of macroconfigurations to define incomplete active spaces and rigorous avoidance of intruder states. The suggested variant is vetted on three well-known model problems: the symmetric stretching of the O-H bonds in water, the dissociation of N2, and the stretching of ground and excited states C2 to more than twice the equilibrium bond length of the ground state. It is observed that the LDA-based GVVPT2 calculations yield good results, of comparable quality to conventional CASSCF-based calculations. This is true even for the C2 model problem, in which the orbital space for each state was defined by the LDA orbitals. These results suggest that GVVPT2 can be applied to much larger problems than previously accessible.

Photoelectron wave function in photoionization: Plane wave or Coulomb wave? [Does photoionization of neutral targets produce Coulomb or plane waves?

DOE PAGES

Gozem, Samer; Gunina, Anastasia O.; Ichino, Takatoshi; ...

2015-10-28

The calculation of absolute total cross sections requires accurate wave functions of the photoelectron and of the initial and final states of the system. The essential information contained in the latter two can be condensed into a Dyson orbital. We employ correlated Dyson orbitals and test approximate treatments of the photoelectron wave function, that is, plane and Coulomb waves, by comparing computed and experimental photoionization and photodetachment spectra. We find that in anions, a plane wave treatment of the photoelectron provides a good description of photodetachment spectra. For photoionization of neutral atoms or molecules with one heavy atom, the photoelectronmore » wave function must be treated as a Coulomb wave to account for the interaction of the photoelectron with the +1 charge of the ionized core. For larger molecules, the best agreement with experiment is often achieved by using a Coulomb wave with a partial (effective) charge smaller than unity. This likely derives from the fact that the effective charge at the centroid of the Dyson orbital, which serves as the origin of the spherical wave expansion, is smaller than the total charge of a polyatomic cation. Finally, the results suggest that accurate molecular photoionization cross sections can be computed with a modified central potential model that accounts for the nonspherical charge distribution of the core by adjusting the charge in the center of the expansion.« less

Imaging features of orbital myxosarcoma in dogs.

PubMed

Dennis, Ruth

2008-01-01

Myxomas and myxosarcomas are infiltrative connective tissue tumors of fibroblastic origin that can be distinguished by the presence of abundant mucinous stroma. This paper describes the clinical and imaging features of orbital myxosarcoma in five dogs and suggests a predilection for the orbit. The main clinical signs were slowly progressive exophthalmos with soft swelling of the pterygopalatine fossa, and in two dogs, of the periorbital area. No pain was associated with the eye or orbit but one dog had pain on opening the mouth. The dogs were imaged using combinations of ultrasonography, radiography, and magnetic resonance imaging. In four dogs, extensive fluid-filled cavities in the orbit and fascial planes were seen and in the fifth dog, the tumor appeared more solid with small, peripheral cystic areas. In all dogs, the lesion extended along fascial planes to involve the temporomandibular joint, with osteolysis demonstrable in two dogs. Fluid aspirated from the cystic areas was viscous and sticky, mimicking that from a salivary mucocoele. Myxomas and myxosarcomas are known to be infiltrative and not readily amenable to surgical removal but their clinical course seems to be slow, with a reasonable survival time with palliative treatment. In humans, a juxta-articular form is recognized in which a prominent feature is the presence of dilated, cyst-like spaces filled with mucinous material. It is postulated that orbital myxosarcoma in dogs may be similar to the juxta-articular form in man, and may arise from the temporomandibular joint.

In-Orbit Operation of the ASTRO-H SXS

NASA Technical Reports Server (NTRS)

Tsujimoto, Masahiro; Mitsuda, Kazuhisa; Kelley, Richard L.; den Herder, Jan-Willem A.; Akamatsu, Hiroki; Bialas, Thomas G.; Boyce, Kevin R.; Brown, Gregory V.; Chiao, Meng P.; Costantini, Elisa;

Vibrational, NMR and quantum chemical investigations of acetoacetanilde, 2-chloroacetoacetanilide and 2-methylacetoacetanilide.

PubMed

Arjunan, V; Kalaivani, M; Senthilkumari, S; Mohan, S

2013-11-01

The vibrational assignment and analysis of the fundamental modes of the compounds acetoacetanilide (AAA), 2-chloroacetoacetanilide (2CAAA) and 2-methylacetoacetanilide (2MAAA) have been performed. Density functional theory studies have been carried out with B3LYP method utilising 6-311++G(**) and cc-pVTZ basis sets to determine structural, thermodynamic and vibrational characteristics of the compounds and also to understand the influence of chloro and methyl groups on the characteristic frequencies of amide (CONH) group. Intramolecular hydrogen bond exists in acetoacetanilide and o-substituted acetoacetanilide molecules and the N⋯O distance is found to be around 2.7Å. The (1)H and (13)C nuclear magnetic resonance chemical shifts of the molecules were determined and the same have been calculated using the gauge independent atomic orbital (GIAO) method. The energies of the frontier molecular orbitals have been determined. In AAA, 2CAAA and 2MAAA molecules, the nN→πCO(∗) interaction between the nitrogen lone pair and the amide CO antibonding orbital gives strong stabilization of 64.75, 62.84 and 64.18kJmol(-1), respectively. The blue shift in amide-II band of 2MAAA is observed by 45-50cm(-1) than that of AAA. The steric effect of ortho methyl group significantly operating on the NH bond properties. The amide-III, the CN stretching mode of methyl and chloro substituted acetoacetanilide compounds are not affected by the substitution while the amide-V band, the NH out of plane bending mode of 2-chloroacetoacetanilide compound is shifted to a higher frequency than that of AAA. The substituent chlorine plays significantly and the blue shift in o-substituted compounds than the parent in the amide-V vibration is observed. The amide-VI, CO out of plane bending modes of 2MAAA and 2CAAA are significantly raised than that of AAA. A blue shift of amide-VI, CO out of plane bending modes of 2MAAA and 2CAAA than AAA is observed. Copyright © 2013 Elsevier B.V. All rights

Orbiting Carbon Observatory-2 (OCO-2) Briefing

NASA Image and Video Library

2014-06-29

Tim Dunn, NASA launch director, Kennedy Space Center, discusses the Orbiting Carbon Observatory-2 (OCO-2), NASA’s first spacecraft dedicated to studying carbon dioxide, during a press briefing, Sunday, June 29, 2014, at the Vandenberg Air Force Base, Calif. OCO-2 will measure the global distribution of carbon dioxide, the leading human-produced greenhouse gas driving changes in Earth’s climate. OCO-2 is set to launch on July 1, 2014 at 2:59 a.m. PDT. Photo Credit: (NASA/Bill Ingalls)

Diagrams for comprehensive molecular orbital-based chemical reaction analyses: reactive orbital energy diagrams.

PubMed

Tsuneda, Takao; Singh, Raman Kumar; Chattaraj, Pratim Kumar

2018-05-15

Reactive orbital energy diagrams are presented as a tool for comprehensively performing orbital-based reaction analyses. The diagrams rest on the reactive orbital energy theory, which is the expansion of conceptual density functional theory (DFT) to an orbital energy-based theory. The orbital energies on the intrinsic reaction coordinates of fundamental reactions are calculated by long-range corrected DFT, which is confirmed to provide accurate orbital energies of small molecules, combining with a van der Waals (vdW) correlation functional, in order to examine the vdW effect on the orbital energies. By analysing the reactions based on the reactive orbital energy theory using these accurate orbital energies, it is found that vdW interactions significantly affect the orbital energies in the initial reaction processes and that more than 70% of reactions are determined to be initially driven by charge transfer, while the remaining structural deformation (dynamics)-driven reactions are classified into identity, cyclization and ring-opening, unimolecular dissociation, and H2 reactions. The reactive orbital energy diagrams, which are constructed using these results, reveal that reactions progress so as to delocalize the occupied reactive orbitals, which are determined as contributing orbitals and are usually not HOMOs, by hybridizing the unoccupied reactive orbitals, which are usually not LUMOs. These diagrams also raise questions about conventional orbital-based diagrams such as frontier molecular orbital diagrams, even for the well-established interpretation of Diels-Alder reactions.

N-(2-Allyl-4-chloro-2H-indazol-5-yl)-4-meth-oxy-benzene-sulfonamide hemi-hydrate.

PubMed

Chicha, Hakima; Kouakou, Assoman; Rakib, El Mostapha; Saadi, Mohamed; El Ammari, Lahcen

2013-01-01

The fused five- and six-membered rings in the title compound, C17H16ClN3O3S·0.5H2O, are practically coplanar, with the maximum deviation from the mean plane being 0.057 (3) Å for the C atom bound to the exocyclic N atom. The indazole system makes a dihedral angle of 66.18 (12)° with the plane through the benzene ring, and it is nearly perpendicular to the allyl group, as indicated by the N-N-C-C torsion angle of 79.2 (3)°. In the crystal, the water mol-ecule, lying on a twofold axis, forms O-H⋯N and accepts N-H⋯O hydrogen bonds. Additional C-H⋯O hydrogen bonds contribute to the formation of a chain along the b-axis direction.

Communication: THz absorption spectrum of the CO2-H2O complex: observation and assignment of intermolecular van der Waals vibrations.

PubMed

Andersen, J; Heimdal, J; Mahler, D W; Nelander, B; Larsen, R Wugt

2014-03-07

Terahertz absorption spectra have been recorded for the weakly bound CO2-H2O complex embedded in cryogenic neon matrices at 2.8 K. The three high-frequency van der Waals vibrational transitions associated with out-of-plane wagging, in-plane rocking, and torsional motion of the isotopic H2O subunit have been assigned and provide crucial observables for benchmark theoretical descriptions of this systems' flat intermolecular potential energy surface. A (semi)-empirical value for the zero-point energy of 273 ± 15 cm(-1) from the class of intermolecular van der Waals vibrations is proposed and the combination with high-level quantum chemical calculations provides a value of 726 ± 15 cm(-1) for the dissociation energy D0.

Surface interaction of H2S, SO2, and SO3 on fullerene-like gallium nitride (GaN) nanostructure semiconductor

NASA Astrophysics Data System (ADS)

Salimifard, M.; Rad, A. Shokuhi; Mahanpoor, K.

2017-10-01

Density functional theory (DFT) using MPW1PW91 and B3LYP hybrid functionals was utilized for quantum-based investigations of three major sulfur compounds (H2S, SO2, and SO3) adsorption onto fullerene-like Ga12N12 nanocluster. All chemicals showed high chemisorption with the order of SO3>SO2>>H2S. Results of charge analysis showed that during adsorption, transfer of charge is from H2S to nanocluster while reverse direction of charge transfer is found for SO2 and SO3 molecules. Partial dissociation is found for adsorbates especially for SO2 and SO3 molecules. Results of thermochemistry analysis show negative values for enthalpy and Gibbs free energy of adsorption, confirming exothermic spontaneous process. Analysis of frontier molecular orbital (FMO) showed important role of orbital hybridizing towards formation of new bonds upon adsorption. As a result, we introduce Ga12N12 nanocluster as a strong adsorbent for sulfur compounds.

Conformation-Specific Spectroscopy of a Prototypical γ-PEPTIDE-WATER Complex: Ac-γ2-hPhe-NHMe-(H2O)1

NASA Astrophysics Data System (ADS)

Buchanan, Evan G.; James, William H., III; Zwier, Timothy S.; Guo, Li; Gellman, Samuel H.

2010-06-01

The prototypical γ-peptide, Ac-γ2-hPhe-NHMe, has been previously studied in a supersonic jet expansion, with three different conformers observed. Two of the monomers form nine atom, intramolecular hydrogen bonded rings, which differ by the position of the aromatic chromophore relative to the backbone. The third monomer conformer has no intramolecular H-bonds, but forms instead an intramolecular, amide-amide stacked structure unique to the γ-peptide backbone. This talk focuses attention on the conformation-specific IR spectra of the Ac-γ2-hPhe-NHMe-(H2O)1 complex, which is observed to form six unique conformational isomers, all of which preserve the two distinct monomer structural motifs. Three conformers are assigned to the nine atom intramolecular hydrogen bond family with the water hydrogen bonded to it as donor in different locations. The other three belong to the amide-amide stacking family with the water forming a bridge between the two amide planes. Infrared photodissocation of the water molecule from the complex to form γ-peptide monomer conformations will also be discussed.

On-Orbit Operation of the Adiabatic Demagnetization Refrigerator on the Astro-H/Hitomi Soft X-ray Spectrometer Instrument

NASA Technical Reports Server (NTRS)

Shirron, Peter; Kimball, Mark; James, Bryan; Muench, Theodore; Canavan, Edgar; DiPirro, Michael; Bialas, Thomas; Sneiderman, Gary; Boyce, Kevin; Kilbourne, Caroline;

The TWA 3 Young Triple System: Orbits, Disks, Evolution

NASA Astrophysics Data System (ADS)

Kellogg, Kendra; Prato, L.; Torres, Guillermo; Schaefer, G. H.; Avilez, I.; Ruíz-Rodríguez, D.; Wasserman, L. H.; Bonanos, Alceste Z.; Guenther, E. W.; Neuhäuser, R.; Levine, S. E.; Bosh, A. S.; Morzinski, Katie M.; Close, Laird; Bailey, Vanessa; Hinz, Phil; Males, Jared R.

2017-08-01

We have characterized the spectroscopic orbit of the TWA 3A binary and provide preliminary families of probable solutions for the TWA 3A visual orbit, as well as for the wide TWA 3A-B orbit. TWA 3 is a hierarchical triple located at 34 pc in the ˜10 Myr old TW Hya association. The wide component separation is 1.″55 the close pair was first identified as a possible binary almost 20 years ago. We initially identified the 35-day period orbital solution using high-resolution infrared spectroscopy that angularly resolved the A and B components. We then refined the preliminary orbit by combining the infrared data with a reanalysis of our high-resolution optical spectroscopy. The orbital period from the combined spectroscopic solution is ˜35 days, the eccentricity is ˜0.63, and the mass ratio is ˜0.84 although this high mass ratio would suggest that optical spectroscopy alone should be sufficient to identify the orbital solution, the presence of the tertiary B component likely introduced confusion in the blended optical spectra. Using millimeter imaging from the literature, we also estimate the inclinations of the stellar orbital planes with respect to the TWA 3A circumbinary disk inclination and find that all three planes are likely misaligned by at least ˜30°. The TWA 3A spectroscopic binary components have spectral types of M4.0 and M4.5; TWA 3B is an M3. We speculate that the system formed as a triple, is bound, and that its properties were shaped by dynamical interactions between the inclined orbits and disk.

The TWA 3 Young Triple System: Orbits, Disks, Evolution

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kellogg, Kendra; Prato, L.; Avilez, I.

2017-08-01

We have characterized the spectroscopic orbit of the TWA 3A binary and provide preliminary families of probable solutions for the TWA 3A visual orbit, as well as for the wide TWA 3A–B orbit. TWA 3 is a hierarchical triple located at 34 pc in the ∼10 Myr old TW Hya association. The wide component separation is 1.″55; the close pair was first identified as a possible binary almost 20 years ago. We initially identified the 35-day period orbital solution using high-resolution infrared spectroscopy that angularly resolved the A and B components. We then refined the preliminary orbit by combining themore » infrared data with a reanalysis of our high-resolution optical spectroscopy. The orbital period from the combined spectroscopic solution is ∼35 days, the eccentricity is ∼0.63, and the mass ratio is ∼0.84; although this high mass ratio would suggest that optical spectroscopy alone should be sufficient to identify the orbital solution, the presence of the tertiary B component likely introduced confusion in the blended optical spectra. Using millimeter imaging from the literature, we also estimate the inclinations of the stellar orbital planes with respect to the TWA 3A circumbinary disk inclination and find that all three planes are likely misaligned by at least ∼30°. The TWA 3A spectroscopic binary components have spectral types of M4.0 and M4.5; TWA 3B is an M3. We speculate that the system formed as a triple, is bound, and that its properties were shaped by dynamical interactions between the inclined orbits and disk.« less

Performance and technological feasibility of rocket powered HTHL-SSTO with take-off assist (aerospace plane/ekranoplane)

NASA Astrophysics Data System (ADS)

Tomita, Nobuyuki; Nebylov, Alexander V.; Sokolov, Victor V.; Ohkami, Yoshiaki

It might be said that it is common understanding that rocket-powered single stage to orbit (SSTO) aerospace planes will become feasible with near-term technology as described in [1] (Koelle, D. E. Survey and comparison of winged launch vehicle options, ISTS 94-g-11 V 1994) and [2] (Bekey, I. Why SSTO rocket launch vehicles are now feasible and practical, IAF-94-V.1.524 1994). Among two methods of launching aerospace planes into orbit, vertical take-off (VT) and horizontal take-off (HT), it seems that VT takes the lead from HT [1, 2]. The decision for the X-33 program by NASA, also, seems to favor VT. In retrospect, almost all of the launch vehicles in the past have been VT, mainly because VT solved the problem of exit from atmosphere to space. However, broadening the range of requirements for space transportation systems from military to commercial and unmanned to manned seems to favor the need for HT. In this paper, the authors are going to prove that aerospace plane/ekranoplane system, which is a reusable launch vehicle system based on the HT concept, with ekranoplane as a take-off and possibly, landing assist, could be competitive with the VT concept from both technological and economical view points. Ekranoplane is a wing-in-ground-effect craft (WIG), which moves at a speed of approximately 0.5 M, carrying heavy loads above the sea surface. Combination of high initial velocity and high performance tri-propellant engine for aerospace plane makes it possible to configure an aerospace plane which is competitive with VT. Other specific features of HT in comparison with VT are discussed.

Orbiting Carbon Observatory-2 (OCO-2) Briefing

NASA Image and Video Library

2014-06-29

Dave Crisp, OCO-2 science team leader, JPL, left, and Annmarie Eldering, OCO-2 deputy project scientist, JPL, are seen during a science briefing ahead of the planned launch of the Orbiting Carbon Observatory-2 (OCO-2), Sunday, June 29, 2014, Vandenberg Air Force Base, Calif. OCO-2 will measure the global distribution of carbon dioxide, the leading human-produced greenhouse gas driving changes in Earth’s climate. OCO-2 is set to launch on July 1, 2014 at 2:59 a.m. PDT. Photo Credit: (NASA/Bill Ingalls)

A spin-orbit alignment for the hot Jupiter HATS-3b

DOE Office of Scientific and Technical Information (OSTI.GOV)

Addison, B. C.; Tinney, C. G.; Wright, D. J.

We have measured the alignment between the orbit of HATS-3b (a recently discovered, slightly inflated Hot Jupiter) and the spin axis of its host star. Data were obtained using the CYCLOPS2 optical-fiber bundle and its simultaneous calibration system feeding the UCLES spectrograph on the Anglo-Australian Telescope. The sky-projected spin-orbit angle of λ = 3° ± 25° was determined from spectroscopic measurements of the Rossiter-McLaughlin effect. This is the first exoplanet discovered through the HATSouth transit survey to have its spin-orbit angle measured. Our results indicate that the orbital plane of HATS-3b is consistent with being aligned to the spin axismore » of its host star. The low obliquity of the HATS-3 system, which has a relatively hot mid F-type host star, agrees with the general trend observed for Hot Jupiter host stars with effective temperatures >6250 K to have randomly distributed spin-orbit angles.« less

Structures of M2(SO2)6B12F12 (M = Ag or K) and Ag2(H2O)4B12F12: Comparison of the Coordination of SO2 versus H2O and of B12F122- versus Other Weakly Coordinating Anions to Metal Ions in the Solid State.

PubMed

Malischewski, Moritz; Peryshkov, Dmitry V; Bukovsky, Eric V; Seppelt, Konrad; Strauss, Steven H

2016-12-05

The structures of three solvated monovalent cation salts of the superweak anion B 12 F 12 2- (Y 2- ), K 2 (SO 2 ) 6 Y, Ag 2 (SO 2 ) 6 Y, and Ag 2 (H 2 O) 4 Y, are reported and discussed with respect to previously reported structures of Ag + and K + with other weakly coordinating anions. The structures of K 2 (SO 2 ) 6 Y and Ag 2 (SO 2 ) 6 Y are isomorphous and are based on expanded cubic close-packed arrays of Y 2- anions with M(OSO) 6 + complexes centered in the trigonal holes of one expanded close-packed layer of B 12 centroids (⊙). The K + and Ag + ions have virtually identical bicapped trigonal prism MO 6 F 2 coordination spheres, with M-O distances of 2.735(1)-3.032(2) Å for the potassium salt and 2.526(5)-2.790(5) Å for the silver salt. Each M(OSO) 6 + complex is connected to three other cationic complexes through their six μ-SO 2 -κ 1 O,κ 2 O' ligands. The structure of Ag 2 (H 2 O) 4 Y is unique [different from that of K 2 (H 2 O) 4 Y]. Planes of close-packed arrays of anions are offset from neighboring planes along only one of the linear ⊙···⊙···⊙ directions of the close-packed arrays, with [Ag(μ-H 2 O) 2 Ag(μ-H 2 O) 2 )] ∞ infinite chains between the planes of anions. There are two nearly identical AgO 4 F 2 coordination spheres, with Ag-O distances of 2.371(5)-2.524(5) Å and Ag-F distances of 2.734(4)-2.751(4) Å. This is only the second structurally characterized compound with four H 2 O molecules coordinated to a Ag + ion in the solid state. Comparisons with crystalline H 2 O and SO 2 solvates of other Ag + and K + salts of weakly coordinating anions show that (i) N[(SO 2 ) 2 (1,2-C 6 H 4 )] - , BF 4 - , SbF 6 - , and Al(OC(CF 3 ) 3 ) 4 - coordinate much more strongly to Ag + than does Y 2- , (ii) SnF 6 2- coordinates somewhat more strongly to K + than does Y 2- , and (iii) B 12 Cl 12 2- coordinates to K + about the same as, if not slightly weaker than, Y 2- .

Driving magnetization dynamics with interfacial spin-orbit torques (Conference Presentation)

NASA Astrophysics Data System (ADS)

Hoffmann, Axel F.; Zhang, Wei; Sklenar, Joseph; Jungfleisch, Matthias Benjamin; Jiang, Wanjun; Hsu, Bo; Xiao, Jiao; Pearson, John E.; Fradin, Frank Y.; Liu, Yaohua; Ketterson, John B.; Yang, Zheng

2016-10-01

Bulk spin Hall effects are well know to provide spin orbit torques, which can be used to drive magnetization dynamics [1]. But one of the reoccurring questions is to what extend spin orbit torques may also originate at the interface between materials with strong spin orbit coupling and the ferromagnets. Using spin torque driven ferromagnetic resonance we show for two systems, where interfacial torques dominate, that they can be large enough to be practically useful. First, we show spin transfer torque driven magnetization dynamics based on Rashba-Edelstein effects at the Bi/Ag interface [2]. Second, we will show that combining permalloy with monolayer MoS2 gives rise to sizable spin-orbit torques. Given the monolayer nature of MoS2 it is clear that bilk spin Hall effects are negligible and therefore the spin transfer torques are completely interfacial in nature. Interestingly the spin orbit torques with MoS2 show a distinct dependence on the orientation of the magnetization in the permalloy, and become strongly enhanced, when the magnetization is pointing perpendicular to the interfacial plane. This work was supported by the U.S. Department of Energy, Office of Science, Materials Science and Engineering Division. [1] A. Hoffmann, IEEE Trans. Mag. 49, 5172 (2013). [2] W. Zhang et al., J. Appl. Phys. 117, 17C727 (2015). [3] M. B. Jungfleisch et al., arXiv:1508.01410.

NiH2 Reliability Impact Upon Hubble Space Telescope Battery Replacement

NASA Technical Reports Server (NTRS)

Rao, Gopalakrishna M.; Hollandsworth, Roger; Armantrout, Jon; Day, John H. (Technical Monitor)

2002-01-01

The NASA Hubble Space Telescope (HST) was designed to be deployed and later serviced for maintenance and upgrades, as required, by the space shuttle fleet, with a Goodyear mission life for the batteries. HST was deployed 380 miles above the Earth, from Space Shuttle Discovery, on April 25, 1990. Four servicing missions, (SM1, SM2, SM3A, AND SM3B) have been performed. Astronauts have replaced or modified optics, solar arrays, a power control unit, and various science packages. A fifth Servicing Mission, SM4 scheduled for early 2004, is planned to replace the batteries for the first time. The HST is powered by solar array wings and nickel hydrogen (NiH2) Duracell batteries, which are grouped into two parallel battery modules of three parallel batteries each. With a design life of 7 years at launch, these batteries have surpassed 12 years in orbit, which gives HST the highest number of charge/discharge cycles of any NiH2 battery currently in low earth orbit (LEO) application. Being in a LEO orbit, HST has a 45-minute umbra period, during which spacecraft power requirements normally force the batteries into discharge, and a 60-minute sun period, which is available for battery recharge. The intent of this paper is to address the issue of NiH2 battery reliability and how battery capacity degradation can impact scheduling of a Servicing Mission to bring replacement batteries to HST, and extend mission life till deployment of Next Generation Space Telescope (NGST), planned for 2008 at the earliest.

Orbiting Carbon Observatory-2 (OCO-2) Briefing

NASA Image and Video Library

2014-06-29

Vern Thorp, United Launch Alliance program manager, NASA missions, discusses the launch of NASA’s Orbiting Carbon Observatory-2 (OCO-2) onboard a ULA Delta II rocket, during a press briefing, Sunday, June 29, 2014, at the Vandenberg Air Force Base, Calif. OCO-2 will measure the global distribution of carbon dioxide, the leading human-produced greenhouse gas driving changes in Earth’s climate. OCO-2 is set to launch on July 1, 2014 at 2:59 a.m. PDT. Photo Credit: (NASA/Bill Ingalls)

Postcard from the Ring Plane

NASA Image and Video Library

2018-05-07

On March 13, 2006 Cassini's narrow-angle camera captured this look at Saturn and its rings, seen here nearly edge on. The frame also features Mimas and tiny Janus (above the rings), and Tethys (below the rings). "Above" and "below" the rings is mostly a matter of perspective here. All three moons and the rings orbit Saturn in roughly the same plane. The night side of Mimas is gently illuminated by "Saturnshine," sunlight reflected from the planet's cloud tops. Images taken using red, green and blue spectral filters were combined to create this natural color view, taken at a distance of approximately 1.7 million miles (2.7 million kilometers) from Saturn. The Cassini spacecraft ended its mission on Sept. 15, 2017. https://photojournal.jpl.nasa.gov/catalog/PIA18323

LO2/LH2 propulsion for outer planet orbiter spacecraft

NASA Technical Reports Server (NTRS)

Garrison, P. W.; Sigurdson, K. B.

1983-01-01

Galileo class orbiter missions (750-1500 kg) to the outer planets require a large postinjection delta-V for improved propulsion performance. The present investigation shows that a pump-fed low thrust LO2/LH2 propulsion system can provide a significantly larger net on-orbit mass for a given delta-V than a state-of-the-art earth storable, N2O4/monomethylhydrazine pressure-fed propulsion system. A description is given of a conceptual design for a LO2/LH2 pump-fed propulsion system developed for a Galileo class mission to the outer planets. Attention is given to spacecraft configuration, details regarding the propulsion system, the thermal control of the cryogenic propellants, and aspects of mission performance.

Subperiosteal orbital abscess: volumetric criteria for surgical drainage.

PubMed

Tabarino, Florian; Elmaleh-Bergès, Monique; Quesnel, Stéphanie; Lorrot, Mathie; Van Den Abbeele, Thierry; Teissier, Natacha

2015-02-01

To investigate predictive factors of surgical management of subperiosteal orbital abscess in children. A retrospective monocentric study was conducted between 2000 and 2011 with children hospitalized for acute pediatric orbital cellulitis (APOC). Clinical, biological and radiological data as well as medical and surgical management were collected and analyzed. All patients received intravenous antibiotics and underwent a CT-scan. Orbit and subperiosteal intraorbital abscess dimensions were measured on axial and coronal planes and the abscess volume was calculated using a spheroid model. Eighty-three children with APOC (mean age: 4.5 years) were included, 53 were boys (63.9%). Thirty-two children (38.6%) presented with a subperiosteal orbital abscess. Mean abscess volume was 570mm(3) and mean exophthalmos was 4.7mm. Twenty patients were treated surgically, 11 of which by an endoscopic approach. A positive correlation was observed between the volume of the abscess or exophthalmos and surgical drainage: 57.9% of patients underwent surgery when exophthalmos was >4mm, 29.4% between 2 and 4mm, and none when <2mm. All patients with an abscess volume >500mm(3) or >5% of orbital volume were operated on whereas only 30% or 39% of patients, respectively, in case of smaller volumes (P<0.05). Surgery for subperiosteal orbital abscess is usually performed in case of visual complications or unfavorable medical outcome. The importance of the exophthalmos and the volume of the abscess measured on the CT-scan are predictive factors of surgery in children with subperiosteal orbital abscess without visual complications. Copyright © 2014 Elsevier Ireland Ltd. All rights reserved.

Topological Fulde-Ferrell and Larkin-Ovchinnikov states in spin-orbit-coupled lattice system

NASA Astrophysics Data System (ADS)

Guo, Yao-Wu; Chen, Yan

2018-04-01

The spin-orbit coupled lattice system under Zeeman fields provides an ideal platform to realize exotic pairing states. Notable examples range from the topological superfluid/superconducting (tSC) state, which is gapped in the bulk but metallic at the edge, to the Fulde-Ferrell (FF) state (having a phase-modulated order parameter with a uniform amplitude) and the Larkin-Ovchinnikov (LO) state (having a spatially varying order parameter amplitude). Here, we show that the topological FF state with Chern number ( C = -1) (tFF1) and topological LO state with C= 2 (tLO2) can be stabilized in Rashba spin-orbit coupled lattice systems in the presence of both in-plane and out-of-plane Zeeman fields. Besides the inhomogeneous tSC states, in the presence of a weak in-plane Zeeman field, two topological BCS phases may emerge with C = -1 (tBCS1) far from half filling and C = 2 (tBCS2) near half filling. We show intriguing effects such as different spatial profiles of order parameters for FF and LO states, the topological evolution among inhomogeneous tSC states, and different non-trivial Chern numbers for the tFF1 and tLO1,2 states, which are peculiar to the lattice system. Global phase diagrams for various topological phases are presented for both half-filling and doped cases. The edge states as well as local density of states spectra are calculated for tSC states in a 2D strip.

On-Orbit Performance Verification and End-to-End Characterization of the TDRS-H Ka-Band Communications Payload

NASA Technical Reports Server (NTRS)

Toral, Marco; Wesdock, John; Kassa, Abby; Pogorelc, Patsy; Jenkens, Robert (Technical Monitor)

2002-01-01

In June 2000, NASA launched the first of three next generation Tracking and Data Relay Satellites (TDRS-H) equipped with a Ka-band forward and return service capability. This Ka-band service supports forward data rates up to 25 Mb/sec using the 22.55 - 23.55 GHz space-to-space allocation. Return services are supported via channel bandwidths of 225 and 650 MHz for data rates up to 800 Mb/sec (QPSK) using the 25.25 - 27.5 GHz space-to-space allocation. As part of NASA's acceptance of the TDRS-H spacecraft, an extensive on-orbit calibration, verification and characterization effort was performed to ensure that on-orbit spacecraft performance is within specified limits. This process verified the compliance of the Ka-band communications payload with all performance specifications and demonstrated an end-to-end Ka-band service capability. This paper summarizes the results of the TDRS-H Ka-band communications payload on-orbit performance verification and end-to-end service characterization. Performance parameters addressed include Effective Isotropically Radiated Power (EIRP), antenna Gain-to-System Noise Temperature (G/T), antenna gain pattern, frequency tunability and accuracy, channel magnitude response, and Ka-band service Bit-Error-Rate (BER) performance.

On-Orbit Performance Verification and End-To-End Characterization of the TDRS-H Ka-band Communications Payload

NASA Technical Reports Server (NTRS)

Toral, Marco; Wesdock, John; Kassa, Abby; Pogorelc, Patsy; Jenkens, Robert (Technical Monitor)

2002-01-01

In June 2000, NASA launched the first of three next generation Tracking and Data Relay Satellites (TDRS-H) equipped with a Ka-band forward and return service capability. This Ka-band service supports forward data rates of up to 25 Mb/sec using the 22.55-23.55 GHz space-to-space allocation. Return services are supported via channel bandwidths of 225 and 650 MHz for data rates up to at least 800 Mb/sec using the 25.25 - 27.5 GHz space-to-space allocation. As part of NASA's acceptance of the TDRS-H spacecraft, an extensive on-orbit calibration, verification and characterization effort was performed to ensure that on-orbit spacecraft performance is within specified limits. This process verified the compliance of the Ka-band communications payload with all performance specifications, and demonstrated an end-to-end Ka-band service capability. This paper summarizes the results of the TDRS-H Ka-band communications payload on-orbit performance verification and end-to-end service characterization. Performance parameters addressed include antenna gain pattern, antenna Gain-to-System Noise Temperature (G/T), Effective Isotropically Radiated Power (EIRP), antenna pointing accuracy, frequency tunability, channel magnitude response, and Ka-band service Bit-Error-Rate (BER) performance.

Adsorbent testing and mathematical modeling of a solid amine regenerative CO2 and H2O removal system

NASA Technical Reports Server (NTRS)

Jeng, F. F.; Williamson, R. G.; Quellette, F. A.; Edeen, M. A.; Lin, C. H.

1991-01-01

The paper examines the design and the construction details of the test bed built for testing a solid-amine-based Regenerable CO2 Removal System (RCRS) built at the NASA/Johnson Space Center for the extended Orbiter missions. The results of tests are presented, including those for the adsorption breakthrough and the adsorption and desorption of CO2 and H2O vapor. A model for predicting the performance of regenerative CO2 and H2O vapor adsorption of the solid amine system under various operating conditions was developed in parallel with the testing of the test stand, using the coefficient of mass transfer calculated from test results. The results of simulations are shown to predict the adsorption performance of the Extended Duration Orbiter test bed fairly well. For the application to the RCRS at various operating conditions the model has to be modified.

The mechanism for water exchange in [UO(2)(H(2)O)(5)](2+) and [UO(2)(oxalate)(2)(H(2)O)](2-), as studied by quantum chemical methods.

PubMed

Vallet, V; Wahlgren, U; Schimmelpfennig, B; Szabó, Z; Grenthe, I

2001-12-05

(2)(H(2)O)(5)](2+) and [UO(2)(oxalate)(2)(H(2)O)](2-) indicates that the entering/leaving water molecules are located outside the plane formed by the spectator ligands.

Calculated electric dipole moment of NiH X2Delta

NASA Technical Reports Server (NTRS)

Walch, S.; Bauschlicher, C. W., Jr.; Langhoff, S. R.

1985-01-01

A calculated dipole moment of 2.39 D at R sub e = 2.79 a sub 0 is reported, obtained from complete active space SCF/configuration interaction calculations plus one natural orbital iteration. The calculation is in good agreement with the experimental value of 2.4 + or - 0.1 D measured for the lowest vibrational level. In agreement with Gray et al. (1985), it is found that the dipole moment is strongly correlated with the 3d electron population; the good agreement with experiment thus provides verification of the mixed state model of NiH. It is concluded that the electric dipole moment of NiH is a sensitive test of the quality of the NiH wave function.

Orbiting Carbon Observatory-2 (OCO-2) Briefing

NASA Image and Video Library

2014-06-29

Lt. Joseph Round, launch weather officer, USAF 30th Space Wing Weather Squadron, discusses the weather forecast for launch of NASA’s Orbiting Carbon Observatory-2 (OCO-2) onboard a ULA Delta II rocket, during a press briefing, Sunday, June 29, 2014, at the Vandenberg Air Force Base, Calif. OCO-2 will measure the global distribution of carbon dioxide, the leading human-produced greenhouse gas driving changes in Earth’s climate. OCO-2 is set to launch on July 1, 2014 at 2:59 a.m. PDT. Photo Credit: (NASA/Bill Ingalls)

Landsat 9 OLI 2 focal plane subsystem: design, performance, and status

NASA Astrophysics Data System (ADS)

Malone, Kevin J.; Schrein, Ronald J.; Bradley, M. Scott; Irwin, Ronda; Berdanier, Barry; Donley, Eric

2017-09-01

The Landsat 9 mission will continue the legacy of Earth remote sensing that started in 1972. The Operational Land Imager 2 (OLI 2) is one of two instruments on the Landsat 9 satellite. The OLI 2 instrument is essentially a copy of the OLI instrument flying on Landsat 8. A key element of the OLI 2 instrument is the focal plane subsystem, or FPS, which consists of the focal plane array (FPA), the focal plane electronics (FPE) box, and low-thermal conductivity cables. This paper presents design details of the OLI 2 FPS. The FPA contains 14 critically-aligned focal plane modules (FPM). Each module contains 6 visible/near-IR (VNIR) detector arrays and three short-wave infrared (SWIR) arrays. A complex multi-spectral optical filter is contained in each module. Redundant pixels for each array provide exceptional operability. Spare detector modules from OLI were recharacterized after six years of storage. Radiometric test results are presented and compared with data recorded in 2010. Thermal, optical, mechanical and structural features of the FPA will be described. Special attention is paid to the thermal design of the FPA since thermal stability is crucial to ensuring low-noise and low-drift operation of the detectors which operate at -63°C. The OLI 2 FPE provides power, timing, and control to the focal plane modules. It also digitizes the video data and formats it for the solid-state recorder. Design improvements to the FPA-FPE cables will be discussed and characterization data will be presented. The paper will conclude with the status of the flight hardware assembly and testing.