Spatial and temporal patterns of carbon storage in forest ecosystems on Hainan island, southern China.

PubMed

Ren, Hai; Li, Linjun; Liu, Qiang; Wang, Xu; Li, Yide; Hui, Dafeng; Jian, Shuguang; Wang, Jun; Yang, Huai; Lu, Hongfang; Zhou, Guoyi; Tang, Xuli; Zhang, Qianmei; Wang, Dong; Yuan, Lianlian; Chen, Xubing

2014-01-01

Spatial and temporal patterns of carbon (C) storage in forest ecosystems significantly affect the terrestrial C budget, but such patterns are unclear in the forests in Hainan Province, the largest tropical island in China. Here, we estimated the spatial and temporal patterns of C storage from 1993-2008 in Hainan's forest ecosystems by combining our measured data with four consecutive national forest inventories data. Forest coverage increased from 20.7% in the 1950s to 56.4% in the 2010s. The average C density of 163.7 Mg C/ha in Hainan's forest ecosystems in this study was slightly higher than that of China's mainland forests, but was remarkably lower than that in the tropical forests worldwide. Total forest ecosystem C storage in Hainan increased from 109.51 Tg in 1993 to 279.17 Tg in 2008. Soil C accounted for more than 70% of total forest ecosystem C. The spatial distribution of forest C storage in Hainan was uneven, reflecting differences in land use change and forest management. The potential carbon sequestration of forest ecosystems was 77.3 Tg C if all forested lands were restored to natural tropical forests. To increase the C sequestration potential on Hainan Island, future forest management should focus on the conservation of natural forests, selection of tree species, planting of understory species, and implementation of sustainable practices.

Spatial and Temporal Patterns of Carbon Storage in Forest Ecosystems on Hainan Island, Southern China

PubMed Central

Tang, Xuli; Zhang, Qianmei; Wang, Dong; Yuan, Lianlian; Chen, Xubing

2014-01-01

Spatial and temporal patterns of carbon (C) storage in forest ecosystems significantly affect the terrestrial C budget, but such patterns are unclear in the forests in Hainan Province, the largest tropical island in China. Here, we estimated the spatial and temporal patterns of C storage from 1993–2008 in Hainan's forest ecosystems by combining our measured data with four consecutive national forest inventories data. Forest coverage increased from 20.7% in the 1950s to 56.4% in the 2010s. The average C density of 163.7 Mg C/ha in Hainan's forest ecosystems in this study was slightly higher than that of China's mainland forests, but was remarkably lower than that in the tropical forests worldwide. Total forest ecosystem C storage in Hainan increased from 109.51 Tg in 1993 to 279.17 Tg in 2008. Soil C accounted for more than 70% of total forest ecosystem C. The spatial distribution of forest C storage in Hainan was uneven, reflecting differences in land use change and forest management. The potential carbon sequestration of forest ecosystems was 77.3 Tg C if all forested lands were restored to natural tropical forests. To increase the C sequestration potential on Hainan Island, future forest management should focus on the conservation of natural forests, selection of tree species, planting of understory species, and implementation of sustainable practices. PMID:25229628

A checklist of the cicadas (Hemiptera: Cicadidae) of Hainan Island, China, with description of a new species.

PubMed

Yang, Mingsheng; Wei, Cong

2013-10-29

A total of 54 cacada species, belonging to 28 genera, nine tribes and three subfamilies of the family Cicadidae, are identified to comprise the cicada fauna of Hainan Island, based on the examination of material collected between 2007 and 2011. One species, Semia hainanensis sp. n., is described as new to science. Nine species are recorded as new to Hainan Island, of which two species, Pomponia subtilita Lee, 2009 and Becquartina bleuzeni Boulard, 2005, are reported for the first time from China. In addition, six species formerly recorded from Hainan are removed from the list of Hainan cicadas. Taxonomic remarks and information on geographic distributions are also provided.

Renewed classification within Goniurosaurus (Squamata: Eublepharidae) uncovers the dual roles of a continental island (Hainan) in species evolution.

PubMed

Liang, Bin; Zhou, Run-Bang; Liu, Yan-Lin; Chen, Bei; Grismer, L Lee; Wang, Ning

2018-06-12

Continental islands are often dynamic in regard to the origin and evolution of their biota. Although colonizations from mainland Southeast Asia to Hainan Island have been reported, the role of Hainan Island as a source for continental biota has not been considered. Goniurosaurus is a genus comprised of nocturnal ground geckos. We reexamined the evolutionary history of Goniurosaurus using both molecular phylogenetics and morphological comparisons. All phylogenetic trees recovered G. zhoui as sister to G. hainanensis + G. lichtenfelderi, which together are the sister lineage of G. bawanglingensis. The recovery of this "Hainan clade" contradicts previous classifications that placed G. bawanglingensis within the G. luii group. Moreover, ancestral trait reconstruction revealed that body band number might have decreased two or three times independently within Goniurosaurus from four to three. The divergence between the continental G. luii group and the Hainan clade was estimated at ∼34.7 Mya (CI = 22.3-48.6), possibly correlating with the vicariance event between Hainan Island and the mainland. G. lichtenfelderi diverged from G. hainanensis very recently, which might be associated with a historical dispersal event from Hainan Island to Vietnam during glacial periods. Our study improves the understanding of Goniurosaurus systematics and reveals the important role of Hainan Island in bidirectional colonizations. Copyright © 2018 Elsevier Inc. All rights reserved.

Deforestation and fragmentation of natural forests in the upper Changhua watershed, Hainan, China: implications for biodiversity conservation.

PubMed

Zhai, De-Li; Cannon, Charles H; Dai, Zhi-Cong; Zhang, Cui-Ping; Xu, Jian-Chu

2015-01-01

Hainan, the largest tropical island in China, belongs to the Indo-Burma biodiversity hotspot. The Changhua watershed is a center of endemism for plants and birds and the cradle of Hainan's main rivers. However, this area has experienced recent and ongoing deforestation and habitat fragmentation. To quantify habitat loss and fragmentation of natural forests, as well as the land-cover changes in the Changhua watershed, we analyzed Landsat images obtained in 1988, 1995, and 2005. Land-cover dynamics analysis showed that natural forests increased in area (97,909 to 104,023 ha) from 1988 to 1995 but decreased rapidly to 76,306 ha over the next decade. Rubber plantations increased steadily throughout the study period while pulp plantations rapidly expanded after 1995. Similar patterns of land cover change were observed in protected areas, indicating a lack of enforcement. Natural forests conversion to rubber and pulp plantations has a general negative effect on biodiversity, primarily through habitat fragmentation. The fragmentation analysis showed that natural forests area was reduced and patch number increased, while patch size and connectivity decreased. These land-cover changes threatened local biodiversity, especially island endemic species. Both natural forests losses and fragmentation should be stopped by strict enforcement to prevent further damage. Preserving the remaining natural forests and enforcing the status of protected areas should be a management priority to maximize the watershed's biodiversity conservation value.

Epidemic Distribution and Variation of Plasmodium falciparum and Plasmodium vivax Malaria in Hainan, China during 1995–2008

PubMed Central

Xiao, Dan; Long, Yong; Wang, Shanqing; Wu, Kejian; Xu, Dezhong; Li, Haitao; Wang, Guangze; Yan, Yongping

2012-01-01

Hainan Province is the main area threatened by malaria in China. However, the epidemiologic patterns of malaria in this region are not yet defined. In this study, we determined the spatio-temporal distribution and variation of Plasmodium falciparum and Plasmodium vivax malaria in Hainan during 1995–2008 by using wavelet and cluster quantitative approaches. The results indicated a decreasing secular trend and obvious seasonal fluctuation of malaria in Hainan. In addition, the characteristic annual peak of malaria could not be detected after 2005. The southcentral region of Hainan has remained an area of relatively high malaria risk, but the incidence of P. falciparum malaria increased significantly in the southeast and southwest regions during 2002–2008. These findings identify epidemic patterns of malaria in Hainan, and are applicable for designing an effective and dynamic public health campaign to combat malaria in this region. PMID:22869636

Whole rock major element chemistry of KREEP basalt clasts in lunar breccia 15205: Implications for the petrogenesis of volcanic KREEP basalts

NASA Technical Reports Server (NTRS)

Vetter, Scott K.; Shervais, John W.

1993-01-01

KREEP basalts are a major component of soils and regolith at the Apollo 15 site. Their origin is controversial: both endogenous (volcanic) and exogenous (impact melt) processes have been proposed, but it is now generally agreed that KREEP basalts are volcanic rocks derived from the nearby Apennine Bench formation. Because most pristine KREEP basalts are found only as small clasts in polymict lunar breccias, reliable chemical data are scarce. The primary aim of this study is to characterize the range in chemical composition of pristine KREEP basalt, and to use these data to decipher the petrogenesis of these unique volcanic rocks.

Non-specific alarm calls trigger mobbing behavior in Hainan gibbons (Nomascus hainanus).

PubMed

Deng, Huaiqing; Gao, Kai; Zhou, Jiang

2016-09-30

Alarm calls are important defensive behaviors. Here, we report the acoustic spectrum characteristics of alarm calls produced by Hainan gibbons (Nomascus hainanus) inhabiting Bawangling National Nature Reserve in Hainan, China. Analysis of call data collected from 2002-2014 shows that alarm calls are emitted by all family group members, except infants. Alarm behavior included simple short alarming calls (7-10 min) followed by longer variable-frequency mobbing calls lasting 5-12 min. The duration of individual alarming and mobbing calls was 0.078 ± 0.014 s and 0.154 ± 0.041 s at frequency ranges of 520-1000 Hz and 690-3920 Hz, respectively. Alarming call duration was positively associated with group size. The alarm calls can trigger mobbing behavior in Hainan gibbons; this is a defense way of social animals, and first report among the primates' species. The system of vocal alarm behavior described in this critically endangered species is simple and effective.

[Prevalence and risk factors of bronchial asthma among Li nationality in Hainan province].

PubMed

Ding, Yi-peng; Yao, Hong-xia; Tang, Xiao-lan; He, Hai-wu; Shi, Hui-fang; Lin, Li; Li, Min; Chen, Shan; Chen, Jing; Wang, Hai-jiao

2011-02-01

To study the risk factors of bronchial asthma of Li nationality in Hainan. A total of 13 050 subjects of Li nationality were selected by random unequal ratio stratified cluster sampling method from southern, central and western part of Hainan and investigated with Hainan Epidemiological Asthma Survey Questionnaire of Li Nationality. There were 441 cases of bronchial asthma, and 1296 cases of control that were sampled by random number table method. The logistic regression method was used to analyze risk factors. The asthma prevalence of Li nationality in Hainan was 3.38%(441/13 050). The main risk factors of asthma were family asthma (OR = 4.323, 95%CI = 3.259 - 5.735), hypersensitiveness (OR = 7.775, 95%CI = 5.686 - 10.632), smoking (OR = 1.494, 95%CI = 1.174 - 1.902), cooking fuels and living environment. Cold air change (OR = 1.604, 95%CI = 1.286 - 2.001) and respirable dust or irritant gas (OR = 2.123, 95%CI = 1.702 - 2.648) were the important incentives. The main risk factors of asthma among Li nationality were family asthma, hypersensitiveness, smoking, cooking fuels by means of fuel oil, hay or wood, living environment by means of couch grass room and human-livestock mix live, cold air change, respirable dust or irritant gas.

Fractionation products of basaltic komatiite magmas at lower crustal pressures: implications for genesis of silicic magmas in the Archean

NASA Astrophysics Data System (ADS)

Mandler, B. E.; Grove, T. L.

2015-12-01

Hypotheses for the origin of crustal silicic magmas include both partial melting of basalts and fractional crystallization of mantle-derived melts[1]. Both are recognized as important processes in modern environments. When it comes to Archean rocks, however, partial melting hypotheses dominate the literature. Tonalite-trondhjemite-granodiorite (TTG)-type silicic magmas, ubiquitous in the Archean, are widely thought to be produced by partial melting of subducted, delaminated or otherwise deeply buried hydrated basalts[2]. The potential for a fractional crystallization origin for TTG-type magmas remains largely unexplored. To rectify this asymmetry in approaches to modern vs. ancient rocks, we have performed experiments at high pressures and temperatures to closely simulate fractional crystallization of a basaltic komatiite magma in the lowermost crust. These represent the first experimental determinations of the fractionation products of komatiite-type magmas at elevated pressures. The aim is to test the possibility of a genetic link between basaltic komatiites and TTGs, which are both magmas found predominantly in Archean terranes and less so in modern environments. We will present the 12-kbar fractionation paths of both Al-depleted and Al-undepleted basaltic komatiite magmas, and discuss their implications for the relative importance of magmatic fractionation vs. partial melting in producing more evolved, silicic magmas in the Archean. [1] Annen et al., J. Petrol., 47, 505-539, 2006. [2] Moyen J-F. & Martin H., Lithos, 148, 312-336, 2012.

Mercury contamination in fish and human hair from Hainan Island, South China Sea: Implication for human exposure.

PubMed

Liu, Jin-Ling; Xu, Xiang-Rong; Yu, Shen; Cheng, Hefa; Peng, Jia-Xi; Hong, Yi-Guo; Feng, Xin-Bin

2014-11-01

Hair has long been recognized as a good biomarker for human exposure to Hg. The mercury concentrations in 14 species of marine fish and hair samples from 177 coastal residents in Hainan, South China Sea were investigated to assess the status of mercury exposure associated with marine fish consumption. Concentrations of total Hg (THg) and methylmercury (MeHg) in the fish muscles were 0.094 ± 0.008 and 0.066 ± 0.006 μg/gww, respectively, which were far below the limit considered safe for consumption (0.5 μg/g). The average THg concentrations in hair of adults (1.02 ± 0.92 μg/g) were lower than the provisional tolerable weekly intake (PTWI) level of 2.2 μg/g. However, 23.7% of children had a hair THg level exceeding the RfD level of 1μg/g, indicating a great risk of Hg exposure to children via fish consumption. The concentration of THg in hair was significantly correlated with fish consumption but not with gender-specific fish intake. With higher fish consumption frequency, the fishermen had significantly elevated hair Hg levels compared to the students and the other general public, who had similar hair THg levels but different fish consumption patterns, indicating the existence of other sources of Hg exposure to the residents of Hainan Island. Copyright © 2014 Elsevier Inc. All rights reserved.

The implications of basalt in the formation and evolution of mountains on Venus

NASA Astrophysics Data System (ADS)

Jull, Matthew G.; Arkani-Hamed, Jafar

1995-06-01

The highland region of Ishtar Terra on Venus has mountains that reach up to 11 km in height and are thought to be basaltic in composition. Assuming that dynamic uplift of crust to this height is unlikely, we examine the topography produced by an isostatically supported thickening basaltic crust. It is found that regardless of whether the crust thickens by crustal shortening or by volcanic construction, the high-density basalt-eclogite phase transition is the limiting factor for producing significant elevation of the mountains. The maximum height attained by basaltic mountains depends on the nature of the basalt-eclogite phase transition. Without a phase transition, a basaltic crust must thicken to greater than 100 km to reach heights over 10 km. An instantaneous phase transition of basalt to eclogite allows a maximum topographic height of less than about 2 km. However, with a time lag of 100 Ma owing to slow rates of solid-state diffusion, our calculations show that the mountains can reach elevations greater than 10 km only if they are less than 25 Ma old. Higher temperatures within the Venusian crust may decrease the extent of the stability fields of high-density basalt phases and allow high topography if the thickening crust melts. This can occur if the radioactive element concentrations measured on the surface of Venus are uniformly distributed throughout the crust, the crust thickens to greater than 65 km, and the thickened crust is older than about 400 Ma. The conflicting results of a young age predicted for high basaltic mountains and an almost uniform surface age of 500 Ma from crater populations, coupled with similarities in bulk physical properties of Venus and Earth, suggest that the basaltic surface composition found at several landing sites on the planet may not be representative of the entire crust. We suggest that Ishtar Terra formed from the collision of continent-like highly silicic cratons over a region of mantle downwelling. Lakshmi Planum

Non-specific alarm calls trigger mobbing behavior in Hainan gibbons (Nomascus hainanus)

PubMed Central

Deng, Huaiqing; Gao, Kai; Zhou, Jiang

2016-01-01

Alarm calls are important defensive behaviors. Here, we report the acoustic spectrum characteristics of alarm calls produced by Hainan gibbons (Nomascus hainanus) inhabiting Bawangling National Nature Reserve in Hainan, China. Analysis of call data collected from 2002–2014 shows that alarm calls are emitted by all family group members, except infants. Alarm behavior included simple short alarming calls (7–10 min) followed by longer variable-frequency mobbing calls lasting 5–12 min. The duration of individual alarming and mobbing calls was 0.078 ± 0.014 s and 0.154 ± 0.041 s at frequency ranges of 520–1000 Hz and 690–3920 Hz, respectively. Alarming call duration was positively associated with group size. The alarm calls can trigger mobbing behavior in Hainan gibbons; this is a defense way of social animals, and first report among the primates’ species. The system of vocal alarm behavior described in this critically endangered species is simple and effective. PMID:27686623

Spatial genetic structure of the cyprinid fish Onychostoma lepturum on Hainan Island.

PubMed

Zhou, Tian-Qi; Lin, Hung-Du; Hsu, Kui-Ching; Kuo, Po-Hsun; Wang, Wei-Kuang; Tang, Wen-Qiao; Liu, Dong; Yang, Jin-Quan

2017-11-01

Population genetic structure of Onychostoma lepturum on Hainan Island was investigated based on mitochondrial CR + cyt b region in 63 specimens collected from four populations. Population analyses indicated significant genetic structure (F ST  = 0.749) and displayed a significant relationship between phylogeny and geography (N ST  = 0.750 and G ST  = 0.140). Thirty-one mtDNA haplotypes were classified into four lineages, and these lineages had an almost allopatric distribution. The results of a statistical dispersal-vicariance analysis suggest that the ancestral populations were distributed widely on Hainan Island, and the rising of the central mountainous area of Hainan Island, the Wuzhi and Yinggeling Mountain Range, separated these four drainages into independent lineages. According to a spatial analysis of molecular variance analysis, we divided these populations into three units: ND, CH and WQ + LS, running into Qiongzhou Strait, the Gulf of Tokin and the South China Sea, respectively. According to our study, the exposure of straits and shelf under water retreat gave chances for population dispersion during the glaciations.

Erratum: Correction to: Emplacement controls for the basaltic-andesitic radial dikes of Summer Coon volcano and implications for flank vents at stratovolcanoes

NASA Astrophysics Data System (ADS)

Harp, A. G.; Valentine, G. A.

2018-06-01

In the article "Emplacement controls for the basaltic-andesitic radial dikes of Summer Coon volcano and implications for flank vents at stratovolcanoes", the vertical axis for Fig. 8 a was incorrectly labeled (i.e., the value for dikes per km2).

Study on Hainan Tourism Development Strategy from the Perspective of Regional Tourism

NASA Astrophysics Data System (ADS)

Luo, Xi

2017-12-01

At present, Regional tourism has become the focus of all walks of life. It marks a new stage of China’s tourism development and makes a profound change in development strategy. Regional tourism will lead China’s tourism industry to a new level, open up a new world of the overall strategy. Hainan was identified as the country’s first “regional tourism to create demonstration province”, for the exploration experience, making a demonstration, It’s not only the trend, but also the inevitable result of experience in the construction of Hainan International Tourism Island, which has the overall strategic significance

Seismic wave propagation through an extrusive basalt sequence

NASA Astrophysics Data System (ADS)

Sanford, Oliver; Hobbs, Richard; Brown, Richard; Schofield, Nick

2016-04-01

Layers of basalt flows within sedimentary successions (e.g. in the Faeroe-Shetland Basin) cause complex scattering and attenuation of seismic waves during seismic exploration surveys. Extrusive basaltic sequences are highly heterogeneous and contain strong impedance contrasts between higher velocity crystalline flow cores (˜6 km s-1) and the lower velocity fragmented and weathered flow crusts (3-4 km s-1). Typically, the refracted wave from the basaltic layer is used to build a velocity model by tomography. This velocity model is then used to aid processing of the reflection data where direct determination of velocity is ambiguous, or as a starting point for full waveform inversion, for example. The model may also be used as part of assessing drilling risk of potential wells, as it is believed to constrain the total thickness of the sequence. In heterogeneous media, where the scatter size is of the order of the seismic wavelength or larger, scattering preferentially traps the seismic energy in the low velocity regions. This causes a build-up of energy that is guided along the low velocity layers. This has implications for the interpretation of the observed first arrival of the seismic wave, which may be a biased towards the low velocity regions. This will then lead to an underestimate of the velocity structure and hence the thickness of the basalt, with implications for the drilling of wells hoping to penetrate through the base of the basalts in search of hydrocarbons. Using 2-D acoustic finite difference modelling of the guided wave through a simple layered basalt sequence, we consider the relative importance of different parameters of the basalt on the seismic energy propagating through the layers. These include the proportion of high to low velocity material, the number of layers, their thickness and the roughness of the interfaces between the layers. We observe a non-linear relationship between the ratio of high to low velocity layers and the apparent velocity

Genesis of zircon megacrysts in Cenozoic alkali basalts and the heterogeneity of subcontinental lithospheric mantle, eastern China

NASA Astrophysics Data System (ADS)

Yu, Yao; Xu, Xisheng; Chen, Xiaoming

2010-09-01

Zircon megacrysts are found in alluvial deposits associated with Cenozoic basalts from Changle in Shandong Province, Mingxi in Fujian Province and Penglai in Hainan Province within the coastal area of eastern China. They are colourless, transparent to light brown-maroon, and some of them are up to 16 mm long. U-Pb ages of zircon megacrysts from Changle, Mingxi and Penglai are 19.2 ± 0.7 Ma, 1.2 ± 0.1 Ma and 4.1 ± 0.2 Ma respectively, slightly older than the eruption ages of their corresponding host rocks (16.05-18.87 Ma, 0.9-2.2 Ma, 3 Ma). ɛHf(t) values of zircon megacrysts are 9.02 ± 0.49, 6.83 ± 0.47, 4.46 ± 0.48 for Changle, Mingxi and Penglai, respectively, which indicates their mantle origin. We suggest that the zircon megacrysts originated from metasomatised lithospheric mantle and were later brought up quickly by the host basaltic magma. The euhedral forms, uniform internal structure and chemical homogeneity within a single grain suggest crystallization under stable conditions. Pronounced positive Ce anomalies and negligible Eu anomalies suggest oxidizing conditions and little or no fractional crystallization of plagioclase. The differences in Hf-isotope compositions among the zircon megacrysts from different localities are consistent with the Sr-Nd-Pb isotopic compositions of their respective host basalts. This indicates that the host basalts acquired their isotopic signatures from the lithospheric mantle from which the zircon megacrysts derived. These data document the lateral compositional heterogeneity in the upper mantle beneath eastern China. Like mantle xenoliths, zircon megacrysts also have the potential to fingerprint the composition and evolution of the subcontinental lithospheric mantle.

The application of MATLAB-based analytic hierarchy process in Hainan residential quarter function factor evaluation

NASA Astrophysics Data System (ADS)

Qiu, Dongdong; Liu, Peiqi

2017-04-01

Since being designated as an international tourist island, Hainan has become an overwhelmingly favored choice of real estate investment. This paper first constructed Hainan residential quarter function factor index system, then evaluated relevant factors, and finally solved the problem of factor importance ranking. In this specific case, the software MATLAB was used to facilitate AHP calculation. The evaluation results have guiding and referential value to both real estate developers and residential consumers.

Melt rock components in KREEPy breccia 15205: Petrography and mineral chemistry of KREEP basalts and quartz-normative mare basalts

NASA Astrophysics Data System (ADS)

Shervais, John W.; Vetter, Scott K.

1993-05-01

Many current models for the origin of lunar highland rocks feature as an essential component the assimilation of KREEPy material by primitive magmas parental to the Mg-rich suite and alkali suite plutonic rocks. Similar models have also been proposed for the origin of various mare basalt suites. However, any model which considers assimilation of KREEP an important petrologic process must sooner-or-later deal with the question: what is KREEP? Because pristine KREEP basalts are rare, and most known samples are small (e.g., 15382/15386), the geochemical variability of KREEP basalts is poorly known. Other KREEP compositions which are commonly used in these models include the hypothetical 'high-K KREEP' component of Warren and Wasson, which is derived from Apollo 14 soil data, and the 'superKREEP' quartz-monzodiorite 15405. Lunar breccia 15205 is a polymict regolith breccia that consists of approximately 20% KREEP basalt clasts and 20% quartz-normative basalt clasts in a KREEP-rich matrix. Bulk rock mixing calculations show that this sample comprises about 84% KREEP. The clasts range up to 1 cm in size, but most are considerably smaller. The primary aim is to characterize pristine KREEP basalts petrographically, to establish the range in chemical compositions of KREEP basalts, and to test models that were proposed for their origin. In addition, we may be able to extend the compositional range recognized in the quartz-normative basalt suite and cast some light on its origin as well. Preliminary whole rock geochemical data on the KREEP basalts are presented in a companion paper by M.M. Lindstrom and co-workers. Concentration is on petrography and mineral chemistry of these clasts, and the implications these data have for the origin of the different melt rock suites.

Melt rock components in KREEPy breccia 15205: Petrography and mineral chemistry of KREEP basalts and quartz-normative mare basalts

NASA Technical Reports Server (NTRS)

Shervais, John W.; Vetter, Scott K.

1993-01-01

Many current models for the origin of lunar highland rocks feature as an essential component the assimilation of KREEPy material by primitive magmas parental to the Mg-rich suite and alkali suite plutonic rocks. Similar models have also been proposed for the origin of various mare basalt suites. However, any model which considers assimilation of KREEP an important petrologic process must sooner-or-later deal with the question: what is KREEP? Because pristine KREEP basalts are rare, and most known samples are small (e.g., 15382/15386), the geochemical variability of KREEP basalts is poorly known. Other KREEP compositions which are commonly used in these models include the hypothetical 'high-K KREEP' component of Warren and Wasson, which is derived from Apollo 14 soil data, and the 'superKREEP' quartz-monzodiorite 15405. Lunar breccia 15205 is a polymict regolith breccia that consists of approximately 20% KREEP basalt clasts and 20% quartz-normative basalt clasts in a KREEP-rich matrix. Bulk rock mixing calculations show that this sample comprises about 84% KREEP. The clasts range up to 1 cm in size, but most are considerably smaller. The primary aim is to characterize pristine KREEP basalts petrographically, to establish the range in chemical compositions of KREEP basalts, and to test models that were proposed for their origin. In addition, we may be able to extend the compositional range recognized in the quartz-normative basalt suite and cast some light on its origin as well. Preliminary whole rock geochemical data on the KREEP basalts are presented in a companion paper by M.M. Lindstrom and co-workers. Concentration is on petrography and mineral chemistry of these clasts, and the implications these data have for the origin of the different melt rock suites.

Basaltic Volcanism and Ancient Planetary Crusts

NASA Technical Reports Server (NTRS)

Shervais, John W.

1993-01-01

The purpose of this project is to decipher the origin of rocks which form the ancient lunar crust. Our goal is to better understand how the moon evolved chemically and, more generally, the processes involved in the chemical fractionation of terrestrial planetoids. This research has implications for other planetary bodies besides the Moon, especially smaller planetoids which evolved early in the history of the solar system and are now thermally stable. The three main areas focused on in our work (lunar mare basalts, KREEP basalts, and plutonic rocks of the lunar highlands) provide complementary information on the lunar interior and the processes that formed it.

Incipient speciation with gene flow on a continental island: Species delimitation of the Hainan Hwamei (Leucodioptron canorum owstoni, Passeriformes, Aves).

PubMed

Wang, Ning; Liang, Bin; Wang, Jichao; Yeh, Chia-Fen; Liu, Yang; Liu, Yanlin; Liang, Wei; Yao, Cheng-Te; Li, Shou-Hsien

2016-09-01

Because of their isolation, continental islands (e.g., Madagascar) are often thought of as ideal systems to study allopatric speciation. However, many such islands have been connected intermittently to their neighboring continent during recent periods of glaciation, which may cause frequent contact between the diverging populations on the island and continent. As a result, the speciation processes on continental islands may not meet the prerequisites for strictly allopatric speciation. We used multiple lines of evidence to re-evaluate the taxonomic status of the Hainan Hwamei (Leucodioptron canorum owstoni), which is endemic to Hainan, the largest continental island in the South China Sea. Our analysis of mitochondrial DNA and twelve nuclear loci suggests that the Hainan Hwamei can be regarded as an independent species (L. owstoni); the morphological traits of the Hainan Hwamei also showed significant divergence from those of their mainland sister taxon, the Chinese Hwamei (L. canorum). We also inferred the divergence history of the Hainan and Chinese Hwamei to see whether their divergence was consistent with a strictly allopatric model. Our results suggest that the two Hwameis split only 0.2 million years ago with limited asymmetrical post-divergence gene flow. This implies that the Hainan Hwamei is an incipient species and that speciation occurred through ecologically divergent selection and/or assortative mating rather than a strictly allopatric process. Copyright © 2016 Elsevier Inc. All rights reserved.

Spatiotemporal requirements of the Hainan gibbon: Does home range constrain recovery of the world's rarest ape?

PubMed

Bryant, Jessica V; Zeng, Xingyuan; Hong, Xiaojiang; Chatterjee, Helen J; Turvey, Samuel T

2017-03-01

Conservation management requires an evidence-based approach, as uninformed decisions can signify the difference between species recovery and loss. The Hainan gibbon, the world's rarest ape, reportedly exploits the largest home range of any gibbon species, with these apparently large spatial requirements potentially limiting population recovery. However, previous home range assessments rarely reported survey methods, effort, or analytical approaches, hindering critical evaluation of estimate reliability. For extremely rare species where data collection is challenging, it also is unclear what impact such limitations have on estimating home range requirements. We re-evaluated Hainan gibbon spatial ecology using 75 hr of observations from 35 contact days over 93 field-days across dry (November 2010-February 2011) and wet (June 2011-September 2011) seasons. We calculated home range area for three social groups (N = 21 individuals) across the sampling period, seasonal estimates for one group (based on 24 days of observation; 12 days per season), and between-group home range overlap using multiple approaches (Minimum Convex Polygon, Kernel Density Estimation, Local Convex Hull, Brownian Bridge Movement Model), and assessed estimate reliability and representativeness using three approaches (Incremental Area Analysis, spatial concordance, and exclusion of expected holes). We estimated a yearly home range of 1-2 km 2 , with 1.49 km 2 closest to the median of all estimates. Although Hainan gibbon spatial requirements are relatively large for gibbons, our new estimates are smaller than previous estimates used to explain the species' limited recovery, suggesting that habitat availability may be less important in limiting population growth. We argue that other ecological, genetic, and/or anthropogenic factors are more likely to constrain Hainan gibbon recovery, and conservation attention should focus on elucidating and managing these factors. Re-evaluation reveals

Evidence for biological activity in mineralization of secondary sulphate deposits in a basaltic environment: implications for the search for life in the Martian subsurface

NASA Astrophysics Data System (ADS)

Richardson, C. Doc; Hinman, Nancy W.; Scott, Jill R.

2013-10-01

Evidence of microbial activity associated with mineralization of secondary Na-sulphate minerals (thenardite, mirabilite) in the basaltic subsurface of Craters of the Moon National Monument (COM), Idaho were examined by scanning electron microscopy, X-ray diffraction, laser desorption Fourier transform ion cyclotron resonance mass spectrometry (LD-FTICR-MS), Fourier transform infrared spectroscopy (FTIR) and isotope ratio mass spectrometry. Peaks suggestive of bio/organic compounds were observed in the secondary Na-sulphate deposits by LD-FTICR-MS. FTIR provided additional evidence for the presence of bio/organic compounds. Sulphur fractionation was explored to assist in determining if microbes may play a role in oxidizing sulphur. The presence of bio/organic compounds associated with Na-sulphate deposits, along with the necessity of oxidizing reduced sulphur to sulphate, suggests that biological activity may be involved in the formation of these secondary minerals. The secondary Na-sulphate minerals probably form from the overlying basalt through leached sodium ions and sulphate ions produced by bio-oxidation of Fe-sulphide minerals. Since the COM basalts are one of the most comparable terrestrial analogues for their Martian counterparts, the occurrence of biological activity in the formation of sulphate minerals at COM has direct implications for the search for life on Mars. In addition, the presence of caves on Mars suggests the importance of these environments as possible locations for growth and preservation of microbial activity. Therefore, understanding the physiochemical pathways of abiotic and biotic mineralization in the COM subsurface and similar basaltic settings has direct implications for the search for extinct or extant life on Mars.

Basaltic glass as a habitat for microbial life: Implications for astrobiology and planetary exploration

NASA Astrophysics Data System (ADS)

Izawa, M. R. M.; Banerjee, N. R.; Flemming, R. L.; Bridge, N. J.; Schultz, C.

2010-03-01

Recent studies have demonstrated that terrestrial subaqueous basalts and hyaloclastites are suitable microbial habitats. During subaqueous basaltic volcanism, glass is produced by the quenching of basaltic magma upon contact with water. On Earth, microbes rapidly begin colonizing the glassy surfaces along fractures and cracks that have been exposed to water. Microbial colonization of basaltic glass leads to the alteration and modification of the rocks and produces characteristic granular and/or tubular bioalteration textures. Infilling of the alteration textures by minerals such as phyllosilicates, zeolites and titanite may enable their preservation through geologic time. Basaltic rocks are a major component of the Martian crust and are widespread on other solar system bodies. A variety of lines of evidence strongly suggests the long-term existence of abundant liquid water on ancient Mars. Recent orbiter, lander and rover missions have found evidence for the presence of transient liquid water on Mars, perhaps persisting to the present day. Many other solar system bodies, notably Europa, Enceladus and other icy satellites, may contain (or have once hosted) subaqueous basaltic glasses. The record of terrestrial glass bioalteration has been interpreted to extend as far back as ˜3.5 billion years ago and is widespread in oceanic crust and its metamorphic equivalents. The terrestrial record of glass bioalteration strongly suggests that glassy or formerly glassy basaltic rocks on extraterrestrial bodies that have interacted with liquid water are high-value targets for astrobiological exploration.

Volatile contents of magmas from the Deccan and Columbia River provinces: implications for atmospheric gas release from flood basalt eruptions

NASA Astrophysics Data System (ADS)

Self, S.; Blake, S.; Sharma, K.; Widdowson, M.

2008-12-01

Sulphur (S) and chlorine (Cl) contents of magmas from the Mesozoic Deccan basalt province have been measured directly on rare, preserved glass inclusions within crystals and on glassy selvages in these ancient lava flows (Self et al., 2008). Lava flows of the Deccan Traps, India, were emplaced around 66-65 Ma ago. S and Cl concentrations range from high values of ~ 1400 ppm S and 500 ppm Cl in inclusions down to a few hundred ppm in lava selvages. The data indicate that the basaltic magmas of certain (and by implication, many) Deccan eruptions would have emitted up to 0.15 wt % SO2 and up to 0.03 wt % HCl, using an approach that accounts for the variable degree of melt evolution. Such values imply atmospheric releases of ~ 4 Tg of SO2 (and 0.8 Tg HCl) per cubic kilometer (km) of basaltic lava erupted, with most of this being released above the vents. Although eruptive volumes of individual Deccan flood basalt lava fields are not known, the SO2 masses released are indicated to be around 4000 Tg for a 1000 cubic km eruption. Similar, to slightly higher, values for S and Cl have been recently obtained by the same method on two other lava flow fields besides the already-studied Roza lava (Thordarson and Self, 1996) from the 15 Ma Columbia River flood basalt province (CRB) in the Pacific NW of the USA. Volumes of individual eruptive units are known for the CRB (those studied are from 1300-2600 cubic km) and it can be shown that the studied eruptions released SO2 masses in the range 8,000 to 12000 Tg, depending upon flow-field volume. In some cases, the vent areas for these eruptions can be explored. Understanding the eruptive style indicated by proximal deposits will help in future modeling of the atmospheric behavior of the eruption columns, and in heights attained. These results provide a solid basis for interpretation and modeling of the environmental impact of gas releases from past flood basalt activity, which has long been assumed to have been severe. The

Research on feature extraction techniques of Hainan Li brocade pattern

NASA Astrophysics Data System (ADS)

Zhou, Yuping; Chen, Fuqiang; Zhou, Yuhua

2016-03-01

Hainan Li brocade skills has been listed as world non-material cultural heritage preservation, therefore, the research on Hainan Li brocade patterns plays an important role in Li brocade culture inheritance. The meaning of Li brocade patterns was analyzed and the shape feature extraction techniques to original Li brocade patterns were advanced in this paper, based on the contour tracking algorithm. First, edge detection was made on the design patterns, and then the morphological closing operation was used to smooth the image, and finally contour tracking was used to extract the outer contours of Li brocade patterns. The extracted contour features were processed by means of morphology, and digital characteristics of contours are obtained by invariant moments. At last, different patterns of Li brocade design are briefly analyzed according to the digital characteristics. The results showed that the pattern extraction method to Li brocade pattern shapes is feasible and effective according to above method.

Typhoon Haiyan Near Hainan Island, China

NASA Image and Video Library

2013-11-12

On Nov. 10 at 03:30 UTC/Nov. 9 at 10:30 p.m. EDT, the MODIS instrument aboard NASA's Terra satellite showed the center of Typhoon Haiyan just south of Hainan Island, China in the South China Sea. Credit: NASA Goddard MODIS Rapid Response Team NASA image use policy. NASA Goddard Space Flight Center enables NASA’s mission through four scientific endeavors: Earth Science, Heliophysics, Solar System Exploration, and Astrophysics. Goddard plays a leading role in NASA’s accomplishments by contributing compelling scientific knowledge to advance the Agency’s mission. Follow us on Twitter Like us on Facebook Find us on Instagram

Evidence for biological activity in mineralization of secondary sulphate deposits in a basaltic environment: implications for the search for life in the Martian subsurface

DOE Office of Scientific and Technical Information (OSTI.GOV)

C. Doc Richardson; Nancy W. Hinman; Jill R. Scott

Evidence of microbial activity associated with mineralization of secondary Na-sulphate minerals (thenardite, mirabilite) in the basaltic subsurface of Craters of the Moon National Monument (COM), Idaho were examined by scanning electron microscopy, X-ray diffraction, laser desorption Fourier transform ion cyclotron resonance mass spectrometry (LD-FTICR-MS), Fourier transform infrared spectroscopy (FTIR) and isotope ratio mass spectrometry. Peaks suggestive of bio/organic compounds were observed in the secondary Na-sulphate deposits by LD-FTICR-MS. FTIR provided additional evidence for the presence of bio/organic compounds. Sulphur fractionation was explored to assist in determining if microbes may play a role in oxidizing sulphur. The presence of bio/organic compoundsmore » associated with Na-sulphate deposits, along with the necessity of oxidizing reduced sulphur to sulphate, suggests that biological activity may be involved in the formation of these secondary minerals. The secondary Na-sulphate minerals probably form from the overlying basalt through leached sodium ions and sulphate ions produced by bio-oxidation of Fe-sulphide minerals. Since the COM basalts are one of the most comparable terrestrial analogues for their Martian counterparts, the occurrence of biological activity in the formation of sulphate minerals at COM has direct implications for the search for life on Mars. In addition, the presence of caves on Mars suggests the importance of these environments as possible locations for growth and preservation of microbial activity. Therefore, understanding the physiochemical pathways of abiotic and biotic mineralization in the COM subsurface and similar basaltic settings has direct implications for the search for extinct or extant life on Mars.« less

The Ninole Basalt - Implications for the structural evolution of Mauna Loa volcano, Hawaii

USGS Publications Warehouse

Lipman, P.W.; Rhodes, J.M.; Dalrymple, G.B.

1990-01-01

Lava flows of the Ninole Basalt, the oldest rocks exposed on the south side of the island of Hawaii, provide age and compositional constraints on the evolution of Mauna Loa volcano and the southeastward age progression of Hawaiian volcanism. Although the tholeiitic Ninole Basalt differs from historic lavas of Mauna Loa volcano in most major-element contents (e.g., variably lower K, Na, Si; higher Al, Fe, Ti, Ca), REE and other relatively immobile minor elements are similar to historic and prehistoric Mauna Loa lavas, and the present major-element differences are mainly due to incipient weathering in the tropical environment. New K-Ar whole-rock ages, from relatively fresh roadcut samples, suggest that the age of the Ninole Basalt is approximately 0.1-0.2 Ma, although resolution is poor because of low contents of K and radiogenic Ar. Originally considered the remnants of a separate volcano, the Ninole Hills are here interpreted as faulted remnants of the old south flank of Mauna Loa. Deep canyons in the Ninole Hills, eroded after massive landslide failure of flanks of the southwest rift zone, have been preserved from burial by younger lava due to westward migration of the rift zone. Landslide-induced depressurization of the southwest rift zone may also have induced phreatomagmatic eruptions that could have deposited widespread Basaltic ash that overlies the Ninole Basalt. Subaerial presence of the Ninole Basalt documents that the southern part of Hawaii Island had grown to much of its present size above sea level by 0.1-0.2 Ma, and places significant limits on subsequent enlargement of the south flank of Mauna Loa. ?? 1990 Springer-Verlag.

Geochemical nature of sub-ridge mantle and opening dynamics of the South China Sea

NASA Astrophysics Data System (ADS)

Zhang, Guo-Liang; Luo, Qing; Zhao, Jian; Jackson, Matthew G.; Guo, Li-Shuang; Zhong, Li-Feng

2018-05-01

The Indian-type mantle (i.e., above the north hemisphere reference line on the plot of 208Pb/204Pb vs. 206Pb/204Pb) has been considered as a "Southern Hemisphere" geochemical signature, whose origin remains enigmatic. The South China Sea is an extensional basin formed after rifting of the Euro-Asia continent in the Northern Hemisphere, however, the geochemical nature of the igneous crust remains unexplored. For the first time, IODP Expedition 349 has recovered seafloor basalts covered by the thick sediments in the Southwest sub-basin (Sites U1433 and U1434) and the East sub-basin (Site U1431). The Southwest sub-basin consists of enriched (E)-MORB type basalts, and the East sub-basin consists of both normal (N)-MORB-type and E-MORB-type basalts based on trace element compositions. The basalts of the two sub-basins are Indian-type MORBs based on Sr-Nd-Pb-Hf isotope compositions, and the Southwest sub-basin basalts show isotopic compositions (i.e., 206Pb/204Pb of 17.59-17.89) distinctly different from the East sub-basin (i.e., 206Pb/204Pb of 18.38-18.57), suggesting a sub-basin scale mantle compositional heterogeneity and different histories of mantle compositional evolution. Two different enriched mantle end-members (EM1 and EM2) are responsible for the genesis of the Indian-type mantle in the South China Sea. We have modeled the influences of Hainan mantle plume and lower continental crust based on Sr-Nd-Pb-Hf isotope compositions. The results indicate that the influence of Hainan plume can explain the elevated 206Pb/204Pb of the East sub-basin basalts, and the recycling of lower continental crust can explain the low 206Pb/204Pb of the Southwest sub-basin basalts. Based on the strong geochemical imprints of Hainan plume in the ridge magmatism, we propose that the Hainan plume might have promoted the opening of the South China Sea, during which the Hainan plume contributed enriched component to the sub-ridge mantle and caused thermal erosion and return of lower

A Brillouin scattering study of hydrous basaltic glasses: the effect of H2O on their elastic behavior and implications for the densities of basaltic melts

NASA Astrophysics Data System (ADS)

Wu, Lei; Yang, De-Bin; Liu, Jun-Xiu; Hu, Bo; Xie, Hong-Sen; Li, Fang-Fei; Yu, Yang; Xu, Wen-Liang; Gao, Chun-Xiao

2017-06-01

Hydrous basalt glasses with water contents of 0-6.82% were synthesized using a multi-anvil press at 1.0-2.0 GPa and 1200-1400 °C. The starting materials were natural Mesozoic basalts from the eastern North China Craton (NCC). Their sound velocities and elastic properties were measured by Brillouin scattering spectroscopy. The longitudinal ( V P) and shear ( V S) wave velocities decreased with increasing water content. Increasing the synthesis pressure resulted in the glass becoming denser, and finally led to an increase in V P. As the degree of depolymerization increased, the V P, V S, and shear and bulk moduli of the hydrous basalt glasses decreased, whereas the adiabatic compressibility increased. The partial molar volumes of water (ν) under ambient conditions were independent of composition, having values of 11.6 ± 0.8, 10.9 ± 0.6 and 11.5 ± 0.5 cm3/mol for the FX (Feixian), FW (Fuxin), and SHT (Sihetun) basalt glasses, respectively. However, the {{V}_{{{{H}}_{{2}}}{O}}} values measured at elevated temperatures and pressures are increasing with increasing temperature or decreasing pressure. The contrasting densities of these hydrous basalt melts with those previously reported for mid-ocean ridge basalt and preliminary reference Earth model data indicate that hydrous basalt melts may not maintain gravitational stability at the base of the upper mantle.

Low Temperature Reaction Experiments Between Basalt, Seawater and CO2, and Implications for Carbon Dioxide Sequestration in Deep-Sea Basalts

NASA Astrophysics Data System (ADS)

Marieni, C.; Teagle, D. A. H.; Matter, J. M.

2015-12-01

Reactions between divalent cation-rich silicate minerals and CO2-bearing fluids to form (Ca, Mg, Fe) carbonate minerals could facilitate the safe and permanent storage of anthropogenic carbon dioxide. Deep-sea basalt formations provide large storage reservoir capacities and huge potential sources of Ca2+, Mg2+ and Fe2+. However, better knowledge of silicate mineral reaction rates with carbonate-bearing fluids is required to understand the overall carbon storage potential of these reservoirs. This study investigates key reactions associated with progressive seawater-rock interaction using far-from equilibrium dissolution experiments. The experiments were carried out at 40 ˚C and at constant CO2 partial pressure of 1 atm. Mid-ocean ridge basalts from the Juan de Fuca and Mid-Atlantic Ridges and a gabbro from the Troodos ophiolite were reacted with 500 mL of CO2-charged seawater using thick-walled fluorinated polypropylene bottles combined with rubber stoppers. The starting material was crushed, sieved and thoroughly cleaned to remove fine particles (< 63 μm) to ensure a particle grain size between 63 and 125 μm for all the samples. The seawater chemistry and the pH were monitored throughout the experiments by daily analysis of 1 mL of fluid. The pH increased rapidly from 4.8 to 5.0 before stabilizing at 5.1 after 10 days of reaction time. The analysis of anions (S, Cl) highlighted a substantial evaporation (up to 15 %) during the experiments, requiring a correction factor for the measured dissolved ion concentrations. Evaporation corrected silicon (Si) and calcium (Ca) concentrations in the seawater increased by 5900 % and 14 %, resulting in total dissolved Si and Ca from basalt of 0.3 % and 2.4 %, respectively. The results are comparable with literature data for fresh water experiments conducted on basaltic glass at higher temperature or pressure, illustrating the considerable potential of the mineral sequestration of CO2 in submarine basalts.

Volatile Behavior in Lunar and Terrestrial Basalts During Shock: Implications for Martian Magmas

NASA Technical Reports Server (NTRS)

Chaklader, Johny; Shearer, C. K.; Hoerz, F.; Newsom, H. E.

2004-01-01

The amount of water in martian magmas has significant ramifications for the martian atmosphere-hydrosphere cycle. Large D-enrichments have been observed in kaersutitic amphiboles in Zagami, Chassigny and Shergotty meteorites (delta-D values up to 4400 per mil) suggesting that substantial amounts of H escaped Mars in its past. Furthermore, martian meteorites with inclusions of biotite and apatite imply possible origins in a hydrous mantle. However, whether martian magmas ever possessed considerable proportions of water remains controversial and unclear. The H-content of mica and amphibole melt inclusions has been found to be low, while bulk-rock H2O content is also low ranging from 0.013 to 0.035 wt. % in Shergotty. Hydrous martian magmas were considered responsible for light lithophile element (LLE) zoning patterns observed in Nakhlite and Shergottite pyroxenes. Since LLEs, such as Li and B, partition into aqueous fluids at temperatures greater than 350 C, workers interpreted Li-B depletions in pyroxene rims as evidence that supercritical fluid exsolution occurred during magma degassing. In that many martian basalts experienced substantial shock (15-45 GPa) it is possible that the magmatic volatile record preserved in martian basalts has been disturbed. Previous shock experiments suggest that shock processes may effect water content and H/D. To better understand the possible effects of shock on this volatile record, we are studying the redistribution of volatile elements in naturally and experimentally shocked basalts. Here, we report the initial results from shocked basalts associated with the Lonar Crater, India and an experimentally shocked lunar basalt.

[Temporal and spatial characteristics of atmospheric NO2 over Hainan Island and the pollutant sources in recent 10 years].

PubMed

Fu, Chuan-bo; Chen, You-long; Dan, Li; Tang, Jia-xiang

2015-01-01

The temporal-spatial characteristics of the tropospheric column NO2 (TroNO2) and total column NO2 (TotNO2) over Hainan Island are analyzed using remote sensing data derived from OMI sensor, and also combining surface wind, SO2, HYSPLIT model to research the source of atmospheric pollutants over Hainan Island. The results show that: The value of NO2 in northern area is higher than that in southern area, and the value of NO, in central mountainous area is lower than those other places. In addition, the seasonal variation of NO2 indicates that NO2 is higher in winter and lower in summer, which can be attributed to precipitation in summer and external transport of atmospheric pollutants in winter. Long-term changes of NO2 in Hainan Island appear opposite trends during winter and summer, which is declining in winter and has a weak increase in summer. The reasonable explanation is that local emissions of pollutants play an important role in summer, but external transport is the main resource of pollutants over Hainan Island. The TroNO2 in Haikou City has a good relationship with favorable delivered days in PRD, the correlation coefficient is 0.84 with 99% confidence level. Moreover, there are 3 transport paths in Dec. 2013 which can impact Haikou City from backward trajectory analysis, but all of them pass through the PRD, which can further prove that atmospheric pollutants of Hainan Island in winter are mainly delivery from PRD region.

The Ninole Basalt — Implications for the structural evolution of Mauna Loa volcano, Hawaii

NASA Astrophysics Data System (ADS)

Lipman, Peter W.; Rhodes, J. M.; Dalrymple, G. Brent

1990-12-01

Lava flows of the Ninole Basalt, the oldest rocks exposed on the south side of the island of Hawaii, provide age and compositional constraints on the evolution of Mauna Loa volcano and the southeastward age progression of Hawaiian volcanism. Although the tholeiitic Ninole Basalt differs from historic lavas of Mauna Loa volcano in most major-element contents (e.g., variably lower K, Na, Si; higher Al, Fe, Ti, Ca), REE and other relatively immobile minor elements are similar to historic and prehistoric Mauna Loa lavas, and the present major-element differences are mainly due to incipient weathering in the tropical environment. New K-Ar whole-rock ages, from relatively fresh roadcut samples, suggest that the age of the Ninole Basalt is approximately 0.1 0.2 Ma, although resolution is poor because of low contents of K and radiogenic Ar. Originally considered the remnants of a separate volcano, the Ninole Hills are here interpreted as faulted remnants of the old south flank of Mauna Loa. Deep canyons in the Ninole Hills, eroded after massive landslide failure of flanks of the southwest rift zone, have been preserved from burial by younger lava due to westward migration of the rift zone. Landslide-induced depressurization of the southwest rift zone may also have induced phreatomagmatic eruptions that could have deposited widespread Basaltic ash that overlies the Ninole Basalt. Subaerial presence of the Ninole Basalt documents that the southern part of Hawaii Island had grown to much of its present size above sea level by 0.1 0.2 Ma, and places significant limits on subsequent enlargement of the south flank of Mauna Loa.

Morphological evidence uncovers a new species of Goniurosaurus (Squamata: Eublepharidae) from the Hainan Island, China.

PubMed

Zhou, Run-Bang; Wang, Ning; Chen, Bei; Liang, Bin

2018-01-03

A new species of the genus Goniurosaurus, G. zhoui sp. nov., is described based on specimens collected from karst areas in Hainan Island, China. Quantitative comparison of morphological traits and egg size with two known endemic species in Hainan Island and other known congeners confirmed the distinctiveness of G. zhoui sp. nov., which has a moderate size with a snout-vent length of 93.4-97.4 mm; light purple-brown dorsal ground color in adults; a posteriorly protracted nuchal loop on nape; four faint, purple-gray body bands bearing dark purple spots between and on them; eight nasal scales surrounding nares; single internasal; 49-62 eyelid fringe scales; 130-140 scales around midbody; 11 granular scales surrounding the dorsal tubercles; 36-38 precloacal pores in males (absent in females); claws sheathed by four scales, two lateral scales long and curved. We provide the first data on the natural history of the new species and an expanded key to Goniurosaurus species on Hainan Island and the adjacent mainland. The discovery of the new species facilitates our understanding of the speciation process on continental islands.

Planetary basalts - Chemistry and petrology

NASA Technical Reports Server (NTRS)

Papike, J. J.; Bence, A. E.

1979-01-01

Recent literature (1975-1978) on planetary basalts is reviewed. Terrestrial basalts are considered in relation to Nd and Sm isotopic studies, magma mixing, chemical and mineralogical heterogeneities in basalt source regions, and partial melting controls on basalt chemistry. Attention is also given to features of mare basalts, eucrites, and comparisons of basalts for the earth, the moon, and the parent body of basaltic achondrites.

Degassing of basaltic magma: decompression experiments and implications for interpreting the textures of volcanic rocks

NASA Astrophysics Data System (ADS)

Le Gall, Nolwenn; Pichavant, Michel; Cai, Biao; Lee, Peter; Burton, Mike

2017-04-01

chemical equilibrium. In line with this, a strong correlation was found between experimental and natural bubble textures (bubble number densities, shapes, sizes and distributions), having implications for interpreting bubbles in volcanic rocks and quantifying magma ascent rates. Next step will be to perform in situ decompression experiments to simulate both degassing and crystallization of basaltic magma during ascent in the shallow volcanic conduit (P < 50 MPa), using synchrotron X-ray imaging. The obtained 4D (3D + time) data will help us refine our understanding of magma ascent processes. This experimental programme requires first technology adaptation and development, which is in progress.

Sulfur K-edge XANES analysis of natural and synthetic basaltic glasses: Implications for S speciation and S content as function of oxygen fugacity

NASA Astrophysics Data System (ADS)

Jugo, Pedro J.; Wilke, Max; Botcharnikov, Roman E.

2010-05-01

-dominated (most likely because of photo-reduction effects during analysis) whereas S6+/ΣS data from XANES provide a close match to the expected theoretical values. The XANES-derived relationship for S6+/ΣS as a function of fO2 indicates that the transition from S2- to S6+ with increasing fO2 occurs over a narrower interval than what is predicted by the EPMA-derived relationship. The implications for natural systems is that small variation of fO2 above FMQ+1 will have a large effect on S behavior in basaltic systems, in particular regarding the amount of S that can be transported by basaltic melts before sulfide saturation can occur.

Sulfur K-edge XANES analysis of natural and synthetic basaltic glasses: Implications for S speciation and S content as function of oxygen fugacity

NASA Astrophysics Data System (ADS)

Jugo, Pedro J.; Wilke, Max; Botcharnikov, Roman E.

2010-10-01

are sulfate-dominated (most likely because of photo-reduction effects during analysis) whereas S 6+/ΣS from XANES provide a close match to the expected theoretical values. The XANES-derived relationship for S 6+/ΣS as a function of fO 2 indicates that the transition from S 2- to S 6- with increasing fO 2 occurs over a narrower interval than what is predicted by the EPMA-derived relationship. The implications for natural systems is that small variation of fO 2 above FMQ + 1 will have a large effect on S behavior in basaltic systems, in particular regarding the amount of S that can be transported by basaltic melts before sulfide saturation can occur.

Experimental research on continuous basalt fiber and basalt-fibers-reinforced polymers

NASA Astrophysics Data System (ADS)

Zhang, Xueyi; Zou, Guangping; Shen, Zhiqiang

2008-11-01

The interest for continuous basalt fibers and reinforced polymers has recently grown because of its low price and rich natural resource. Basalt fiber was one type of high performance inorganic fibers which were made from natural basalt by the method of melt extraction. This paper discusses basic mechanical properties of basalt fiber. The other work in this paper was to conduct tensile testing of continuous basalt fiber-reinforced polymer rod. Tensile strength and stress-strain curve were obtained in this testing. The strength of rod was fairly equal to rod of E-glass fibers and weaker than rod of carbon fibers. Surface of crack of rod was studied. An investigation of fracture mechanism between matrix and fiber was analyzed by SEM (Scanning electron microscopy) method. A poor adhesion between the matrix and fibers was also shown for composites analyzing SEM photos. The promising tensile properties of the presented basalt fibers composites have shown their great potential as alternative classical composites.

The Use of Basalt, Basalt Fibers and Modified Graphite for Nuclear Waste Repository - 12150

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gulik, V.I.; Biland, A.B.

2012-07-01

New materials enhancing the isolation of radioactive waste and spent nuclear fuel are continuously being developed.. Our research suggests that basalt-based materials, including basalt roving chopped basalt fiber strands, basalt composite rebar and materials based on modified graphite, could be used for enhancing radioactive waste isolation during the storage and disposal phases and maintaining it during a significant portion of the post-closure phase. The basalt vitrification process of nuclear waste is a viable alternative to glass vitrification. Basalt roving, chopped basalt fiber strands and basalt composite rebars can significantly increase the strength and safety characteristics of nuclear waste and spentmore » nuclear fuel storages. Materials based on MG are optimal waterproofing materials for nuclear waste containers. (authors)« less

Field observations of Flood Basalt structure: Implications for offshore interpretation and sub-volcanic investigation

NASA Astrophysics Data System (ADS)

Single, R.; Jerram, D.; Pearson, D.; Hobbs, R.

2003-04-01

Field investigations in Skye and Namibia have provided insight into structure and architecture of CFBs. The studies have been developed into lava sequence models in 3-D software GoCad. The understanding has been applied to interpretation of lavas in the Faeroe-Shetland trough. Volcanics hinder petroleum exploration in this play due to their complex internal geometries and velocity structure. Seismic resolution is poor beneath volcanics. Fieldwork has shown that lavas on Skye have developed from (olivine-phyric) compound basalts towards the base of the sequence, into more massive flows higher up the succession. Fieldwork in the Etendeka CFBs reveal a similar style of lava field development. The focus of the offshore study is through the area of the GFA-99 seismic data. Detailed 3-D interpretation over the central data area is 20x20km in dimensions. The lava sequence present may be sub-divided vertically and laterally into 4 zones between the following seismic picks: Base basalt/sub-basalt sills, top compound lava-dominated series, top Middle Series, top hyaloclastites, top massive basalt. Within the lava sequence, the surfaces have rugose topographies. Lower zone lavas are characterised by discontinuous, indistinct reflectors. These are interpreted to be sub-aerially effused basalts with compound-braided architecture. Middle Series basalts are considered to be a combination of compound lavas and more massive, tabular flows. Steeply dipping seismic reflectors also form part of the Middle Series and are interpreted as foreset-bedded hyaloclastites. The uppermost lavas have strong reflection characteristics and are laterally extensive. These are interpreted to be massive tabular lavas covering an area >8.4 x10^3 km^2. Such flows exist in upper parts of CFB sequences as evidenced from fieldwork. Complex stacking arrangements of lavas seen in the field, and the complexities observed in seismic, suggest that many factors need to be considered within CFBs for improved sub

Evidence for a basalt-free surface on Mercury and implications for internal heat.

PubMed

Jeanloz, R; Mitchell, D L; Sprague, A L; de Pater, I

1995-06-09

Microwave and mid-infrared observations reveal that Mercury's surface contains less FeO + TiO2 and at least as much feldspar as the lunar highlands. The results are compatible with the high albedo (brightness) of Mercury's surface at visible wavelengths in suggesting a rock and soil composition that is devoid of basalt, the primary differentiate of terrestrial mantles. The occurrence of a basalt-free, highly differentiated crust is in accord with recent models of the planet's thermal evolution and suggests that Mercury has retained a hot interior as a result of a combination of inefficient mantle convection and minimal volcanic heat loss.

A mantle plume beneath California? The mid-Miocene Lovejoy Flood Basalt, northern California

USGS Publications Warehouse

Garrison, N.J.; Busby, C.J.; Gans, P.B.; Putirka, K.; Wagner, D.L.

2008-01-01

The Lovejoy basalt represents the largest eruptive unit identified in California, and its age, volume, and chemistry indicate a genetic affinity with the Columbia River Basalt Group and its associated mantle-plume activity. Recent field mapping, geochemical analyses, and radiometric dating suggest that the Lovejoy basalt erupted during the mid-Miocene from a fissure at Thompson Peak, south of Susanville, California. The Lovejoy flowed through a paleovalley across the northern end of the Sierra Nevada to the Sacramento Valley, a distance of 240 km. Approximately 150 km3 of basalt were erupted over a span of only a few centuries. Our age dates for the Lovejoy basalt cluster are near 15.4 Ma and suggest that it is coeval with the 16.1-15.0 Ma Imnaha and Grande Ronde flows of the Columbia River Basalt Group. Our new mapping and age dating support the interpretation that the Lovejoy basalt erupted in a forearc position relative to the ancestral Cascades arc, in contrast with the Columbia River Basalt Group, which erupted in a backarc position. The arc front shifted trenchward into the Sierran block after 15.4 Ma. However, the Lovejoy basalt appears to be unrelated to volcanism of the predominantly calc-alkaline Cascade arc; instead, the Lovejoy is broadly tholeiitic, with trace-element characteristics similar to the Columbia River Basalt Group. Association of the Lovejoy basalt with mid-Miocene flood basalt volcanism has considerable implications for North American plume dynamics and strengthens the thermal "point source" explanation, as provided by the mantle-plume hypothesis. Alternatives to the plume hypothesis usually call upon lithosphere-scale cracks to control magmatic migrations in the Yellowstone-Columbia River basalt region. However, it is difficult to imagine a lithosphere-scale flaw that crosses Precambrian basement and accreted terranes to reach the Sierra microplate, where the Lovejoy is located. Therefore, we propose that the Lovejoy represents a rapid

Mafic enclaves record syn-eruptive basalt intrusion and mixing

NASA Astrophysics Data System (ADS)

Plail, Melissa; Edmonds, Marie; Woods, Andrew W.; Barclay, Jenni; Humphreys, Madeleine C. S.; Herd, Richard A.; Christopher, Thomas

2018-02-01

Mafic enclaves hosted by andesite erupted at the Soufrière Hills Volcano between 1995 and 2010 yield insights into syn-eruptive mafic underplating of an andesite magma reservoir, magma mixing and its role in sustaining eruptions that may be widely applicable in volcanic arc settings. The mafic enclaves range in composition from basalt to andesite and are generated from a hybrid thermal boundary layer at the interface between the two magmas, where the basalt quenches against the cooler andesite, and the two magmas mix. We show, using an analytical model, that the enclaves are generated when the hybrid layer, just a few tens of centimetres thick, becomes buoyant and forms plumes which rise up into the andesite. Mafic enclave geochemistry suggests that vapour-saturated basalt was underplated quasi-continuously throughout the first three eruptive phases of the eruption (the end member basalt became more Mg and V-rich over time). The andesite erupted during the final phases of the eruption contained more abundant and larger enclaves, and the enclaves were more extensively hybridised with the andesite, suggesting that at some time during the final few years of the eruption, the intrusion of mafic magma at depth ceased, allowing the hybrid layer to reach a greater thickness, generating larger mafic enclaves. The temporal trends in mafic enclave composition and abundance suggests that basalt recharge and underplating sustained the eruption by the transfer of heat and volatiles across the interface and when the recharge ceased, the eruption waned. Our study has important implications for the petrological monitoring of long-lived arc eruptions.

Fingerprints of the Paleotethyan back-arc basin in Central Hainan, South China: geochronological and geochemical constraints on the Carboniferous metabasites

NASA Astrophysics Data System (ADS)

He, Huiying; Wang, Yuejun; Zhang, Yanhua; Qian, Xin; Zhang, Yuzhi

2018-03-01

Hainan of Southeast Asia has been regarded as a key area for understanding the Late Paleozoic tectonic regime and amalgamation process of the Indochina with South China Blocks that are not well constrained. This paper presents a set of new geochronological, elemental, and Sr-Nd isotopic data for the Paleozoic Bangxi and Chenxing metabasites in Central Hainan. The geochronological data show that the representative samples yield the 40Ar/39Ar plateau age of 328.1 ± 2.6 Ma and zircon U-Pb age of 330.7 ± 4.4 Ma, respectively. They are SiO2- and TiO2-poor, Al2O3-rich mafic rocks. The Chenxing samples are characterized by left-sloping chondrite-normalized REE and N-MORB-like multi-elemental patterns. The Bangxi samples have the E-MORB-like geochemical affinity. All samples show high ɛ Nd(t) values ranging from +5.61 to +9.85. Such signatures suggest their origination of a MORB-like source with the input of subduction-derived components. Our investigation has verified the presence of the Carboniferous metabasites with both MORB- and arc- like geochemical affinities at the Bangxi-Chenxing area in Central Hainan. In combination with the available data from the Jinshajiang, Ailaoshan, and Song Ma suture zones, it is proposed for the development of a Carboniferous back-arc basin along the Ailaoshan-Song Ma and Central Hainan suture zones in response to the subduction of the Paleotethyan main Ocean.

The genus Conocephalus Thunberg (Orthoptera: Tettigoniidae: Conocephalinae) in Hainan, China with description of one new species.

PubMed

Shi, Fu-Ming; Wang, Ping

2015-07-30

This paper reports four species of the genus Conocephalus from Hainan, China, including Conocephalus (Xiphidion) hainanensis sp. nov. and two new records: C. (Anisoptera) maculatus (Le Guillou, 1841) and C. (Conocephalus) bambusanus Ingrisch, 1990.

Identifying recycled ash in basaltic eruptions

PubMed Central

D'Oriano, Claudia; Bertagnini, Antonella; Cioni, Raffaello; Pompilio, Massimo

2014-01-01

Deposits of mid-intensity basaltic explosive eruptions are characterized by the coexistence of different types of juvenile clasts, which show a large variability of external properties and texture, reflecting alternatively the effects of primary processes related to magma storage or ascent, or of syn-eruptive modifications occurred during or immediately after their ejection. If fragments fall back within the crater area before being re-ejected during the ensuing activity, they are subject to thermally- and chemically-induced alterations. These ‘recycled' clasts can be considered as cognate lithic for the eruption/explosion they derive. Their exact identification has consequences for a correct interpretation of eruption dynamics, with important implications for hazard assessment. On ash erupted during selected basaltic eruptions (at Stromboli, Etna, Vesuvius, Gaua-Vanuatu), we have identified a set of characteristics that can be associated with the occurrence of intra-crater recycling processes, based also on the comparison with results of reheating experiments performed on primary juvenile material, at variable temperature and under different redox conditions. PMID:25069064

Compositional diversity of Late Cenozoic basalts in a transect across the southern Washington Cascades: Implications for subduction zone magmatism

NASA Astrophysics Data System (ADS)

Leeman, William P.; Smith, Diane R.; Hildreth, Wes; Palacz, Zen; Rogers, Nick

1990-11-01

Major volcanoes of the Southern Washington Cascades (SWC) include the large Quaternary stratovolcanoes of Mount St. Helens (MSH) and Mount Adams (MA) and the Indian Heaven (IH) and Simcoe Mountain (SIM) volcanic fields. There are significant differences among these volcanic centers in terms of their composition and evolutionary history. The stratovolcanoes consist largely of andesitic to dacitic lavas and pyroclastics with minor basalt flows. IH consists dominantly of basaltic with minor andesite lavas, all erupted from monogenetic rift and cinder cone vents. SIM has a poorly exposed andesite to rhyolite core but mainly consists of basaltic lavas erupted from numerous widely dispersed vents; it has the morphology of a shield volcano. Distribution of mafic lavas across the SWC is related to north-northwest trending faults and fissure zones that indicate a significant component of east-west extension within the area. There is overlap in eruptive history for the areas studied, but it appears that peak activity was progressively older (MSH (<40 Ka), IH (mostly <0.5 Ma), MA (<0.5 Ma), SIM (1-4 Ma)) and more alkalic toward the east. A variety of compositionally distinct mafic magma types has been identified in the SWC, including low large ion lithophile element (LILE) tholeiitic basalts, moderate LILE calcalkalic basalts, basalts transitional between these two, LILE-enriched mildly alkalic basalts, and basaltic andesites. Compositional diversity among basaltic lavas, both within individual centers as well as across the arc, is an important characteristic of the SWC traverse. The fact that the basaltic magmas either show no correlation between isotopic and trace element components or show trends quite distinct from those of the associated evolved lavas, suggests that their compositional variability is attributable to subcrustal processes. Both the primitive nature of the erupted basalts and the fact that they are relatively common in the SWC sector also imply that such

Weathering and hydrothermal alteration of basalts in Iceland: mineralogy from VNIR, TIR, XRD, and implications for Mars

NASA Astrophysics Data System (ADS)

Ehlmann, B. L.; Mustard, J. F.; Bish, D. L.

2009-12-01

Recent orbital investigations have revealed that aqueous alteration on early Mars took place in diverse alteration environments indicated by distinctive assemblages of minerals (Murchie et al., 2009, JGR). There is growing evidence for past diagenetic or low-temperature/pressure hydrothermal activity on Mars at neutral to alkaline pH, indicated by the presence of Fe/Mg smectites, chlorite, prehnite, serpentine, opaline silica, and zeolites such as analcime in Noachian terrains (Ehlmann et al., 2009, JGR). In recent investigations of terrestrial Mars analog sites, neutral to alkaline pH alteration of basalt, both pedogenic and hydrothermal, has been understudied in favor of sulfur-rich, acidic systems including those at the Hawaiian volcanoes and Rio Tinto, Spain. We began study of the alteration of basalt lava flows in Iceland as a geochemical analog for Noachian Mars. Because the basaltic bedrock is recently formed (<16Ma) with few localities of more highly evolved composition and has poorly formed soils and spare vegetation, the ground and surface waters are broadly similar to those which might have existed on Noachian Mars. Iceland has a variety of geothermal spring systems--low T, low S; low T, high S; and high T, high S--each of which creates distinctive mineralogic assemblages. Here we examine rocks of the Hvalfjordur peninsula, collected from basalt flows that were in some places altered at the surface by pedogenesis and in other locations were hydrothermally altered by non-sulfurous groundwater circulation (low T, low S) following the emplacement of a later hot basalt flow. Rock samples were surveyed in the field using a portable VNIR spectrometer. Altered and unaltered rocks that were typical for the locality were collected as were altered rocks whose spectra were most similar to those measured by CRISM from Mars orbit. Ten rocks were ultimately selected for detailed laboratory analyses: zeolitized basaltic rocks bearing minerals including analcime and

Was the exposed continental shelf a long-distance colonization route in the ice age? The Southeast Asia origin of Hainan and Taiwan partridges.

PubMed

Chen, De; Chang, Jiang; Li, Shou-Hsien; Liu, Yang; Liang, Wei; Zhou, Fang; Yao, Cheng-Te; Zhang, Zhengwang

2015-02-01

Research on island biotas has greatly contributed to the development of modern evolutionary and biogeographic theories. Until now, most studies have suggested that continental islands received their biotas directly from the adjacent mainland. However, only a few studies have indicated that species on continental islands might originate from other distantly non-adjacent regions. Here, we used the hill partridges (genus Arborophila) that are widely distributed in the southwest and southeast China mainland, Indochina, Hainan and Taiwan islands to test whether species on continental islands might originate from distant regions rather than the adjacent mainland. Based on molecular phylogenies inferred from three mitochondrial fragments and three nuclear introns, together with ancestral area reconstruction, we found that the ancestors of the endemic Hainan and Taiwan partridges (A. ardens and A. crudigularis) likely originated from Indochina, rather than the nearby southeast China mainland. The divergence time estimates demonstrate that their ancestors likely colonized Hainan and Taiwan islands using the long exposed continental shelf between Indochina, Hainan and Taiwan islands during glacial periods, which had not been demonstrated before. Thus, integrating distribution data with phylogenetic information can shed new lights on the historical biogeography of continental islands and surrounding mainland regions. Copyright © 2014 Elsevier Inc. All rights reserved.

Relationships among basaltic lunar meteorites

NASA Technical Reports Server (NTRS)

Lindstrom, Marilyn M.

1991-01-01

During the past two years four meteorites of dominantly mare basalt composition were identified in the Japanese and US Antarctic collections. Basalts represent a much higher proportion of the lunar meteorites than is expected from photogeologic mapping of mare and highland regions. Also, the basaltic lunar meteorites are all described as VLT mare basalt, which is a relatively uncommon type among returned lunar samples. The significance of the basaltic meteorites to the understanding of the lunar crust depends on the evaluation of possible relationships among the individual meteorites. None of the specimens are paired meteorites. They differ from each other in petrography and composition. It is important to determine whether they might be paired ejecta which were ejected from the same mare region by the same impact. The question of paired ejecta must be addressed using a combination of exposure histories and petrographic/compositional characteristics. It is possible that the basaltic lunar meteorites are paired ejecta from the same region of the Moon. However, the relationships among them are more complicated than the basaltic breccias being simply brecciated mare gabbros.

Carbonate Mineralization of Volcanic Province Basalts

DOE Office of Scientific and Technical Information (OSTI.GOV)

Schaef, Herbert T.; McGrail, B. Peter; Owen, Antionette T.

2010-03-31

Flood basalts are receiving increasing attention as possible host formations for geologic sequestration of anthropogenic CO2, with studies underway in the United States, India, Iceland, and Canada. As an extension of our previous experiments with Columbia River basalt, basalts from the eastern United States, India, and South Africa were reacted with aqueous dissolved CO2 and aqueous dissolved CO2-H2S mixtures under supercritical CO2 (scCO2) conditions to study the geochemical reactions resulting from injection of CO2 in such formations. The results of these studies are consistent with cation release behavior measured in our previous experiments (in press) for basalt samples tested inmore » single pass flow through dissolution experiments under dilute solution and mildly acidic conditions. Despite the basalt samples having similar bulk chemistry, mineralogy and apparent dissolution kinetics, long-term static experiments show significant differences in rates of mineralization as well as compositions and morphologies of precipitates that form when the basalts are reacted with CO2-saturated water. For example, basalt from the Newark Basin in the United States was by far the most reactive of any basalt tested to date. Carbonate reaction products for the Newark Basin basalt were globular in form and contained significantly more Fe than the secondary carbonates that precipitated on the other basalt samples. In comparison, the post-reacted samples associated with the Columbia River basalts from the United States contained calcite grains with classic dogtooth spar morphology and trace cation substitution (Mg and Mn). Carbonation of the other basalts produced precipitates with compositions that varied chemically throughout the entire testing period. Examination of polished cross sections of the reacted grains by scanning electron microscopy and energy dispersive x-ray spectroscopy show precipitate overgrowths with varying chemical compositions. Compositional differences in

Basaltic Soil of Gale Crater: Crystalline Component Compared to Martian Basalts and Meteorites

NASA Technical Reports Server (NTRS)

Treiman, A. H.; Bish, D. L.; Ming, D. W.; Morris, R. V.; Schmidt, M.; Downs, R. T.; Stolper, E. M.; Blake, D. F.; Vaniman, D. T.; Achilles, C. N.;

Laboratory Simulated Acid-Sulfate Weathering of Basaltic Materials: Implications for Formation of Sulfates at Meridiani Planum and Gusev Crater, Mars

NASA Technical Reports Server (NTRS)

Golden, D. C.; Ming, Douglas W.; Morris, Richard V.; Mertzman, A.

2006-01-01

Acid-sulfate weathering of basaltic materials is a candidate formation process for the sulfate-rich outcrops and rocks at the MER rover Opportunity and Spirit landing sites. To determine the style of acid-sulfate weathering on Mars, we weathered basaltic materials (olivine-rich glassy basaltic sand and plagioclase feldspar-rich basaltic tephra) in the laboratory under different oxidative, acid-sulfate conditions and characterized the alteration products. We investigated alteration by (1) sulfuric-acid vapor (acid fog), (2) three-step hydrothermal leaching treatment approximating an open system and (3) single-step hydrothermal batch treatment approximating a "closed system." In acid fog experiments, Al, Fe, and Ca sulfates and amorphous silica formed from plagioclase-rich tephra, and Mg and Ca sulfates and amorphous silica formed from the olivine-rich sands. In three-step leaching experiments, only amorphous Si formed from the plagioclase-rich basaltic tephra, and jarosite, Mg and Ca sulfates and amorphous silica formed from olivine-rich basaltic sand. Amorphous silica formed under single-step experiments for both starting materials. Based upon our experiments, jarosite formation in Meridiani outcrop is potential evidence for an open system acid-sulfate weathering regime. Waters rich in sulfuric acid percolated through basaltic sediment, dissolving basaltic phases (e.g., olivine) and forming jarosite, other sulfates, and iron oxides. Aqueous alteration of outcrops and rocks on the West Spur of the Columbia Hills may have occurred when vapors rich in SO2 from volcanic sources reacted with basaltic materials. Soluble ions from the host rock (e.g., olivine) reacted with S to form Ca-, Mg-, and other sulfates along with iron oxides and oxyhydroxides.

Experimental Partitioning of Chalcophile Elements between Mantle Silicate Minerals and Basaltic Melt at High Pressures and Temperatures - Implications for Sulfur Geochemistry of Mantle and Crust

NASA Astrophysics Data System (ADS)

Dasgupta, R.; Jego, S.; Ding, S.; Li, Y.; Lee, C. T.

2015-12-01

crystallization. The model results are compared with the chalcophile element abundance in oceanic basalts. We will discuss the implications of our new partitioning data and model results on sulfur and chalcophile element geochemistry of mantle source regions of ocean floor basalts and the fate of sulfides during mantle melting.

Lunar basalt chronology, mantle differentiation and implications for determining the age of the Moon

NASA Astrophysics Data System (ADS)

Snape, Joshua F.; Nemchin, Alexander A.; Bellucci, Jeremy J.; Whitehouse, Martin J.; Tartèse, Romain; Barnes, Jessica J.; Anand, Mahesh; Crawford, Ian A.; Joy, Katherine H.

2016-10-01

Despite more than 40 years of studying Apollo samples, the age and early evolution of the Moon remain contentious. Following the formation of the Moon in the aftermath of a giant impact, the resulting Lunar Magma Ocean (LMO) is predicted to have generated major geochemically distinct silicate reservoirs, including the sources of lunar basalts. Samples of these basalts, therefore, provide a unique opportunity to characterize these reservoirs. However, the precise timing and extent of geochemical fractionation is poorly constrained, not least due to the difficulty in determining accurate ages and initial Pb isotopic compositions of lunar basalts. Application of an in situ ion microprobe approach to Pb isotope analysis has allowed us to obtain precise crystallization ages from six lunar basalts, typically with an uncertainty of about ± 10 Ma, as well as constrain their initial Pb-isotopic compositions. This has enabled construction of a two-stage model for the Pb-isotopic evolution of lunar silicate reservoirs, which necessitates the prolonged existence of high-μ reservoirs in order to explain the very radiogenic compositions of the samples. Further, once firm constraints on U and Pb partitioning behaviour are established, this model has the potential to help distinguish between conflicting estimates for the age of the Moon. Nonetheless, we are able to constrain the timing of a lunar mantle reservoir differentiation event at 4376 ± 18 Ma, which is consistent with that derived from the Sm-Nd and Lu-Hf isotopic systems, and is interpreted as an average estimate of the time at which the high-μ urKREEP reservoir was established and the Ferroan Anorthosite (FAN) suite was formed.

Nanoparticulate mineral matter from basalt dust wastes.

PubMed

Dalmora, Adilson C; Ramos, Claudete G; Querol, Xavier; Kautzmann, Rubens M; Oliveira, Marcos L S; Taffarel, Silvio R; Moreno, Teresa; Silva, Luis F O

2016-02-01

Ultra-fine and nano-particles derived from basalt dust wastes (BDW) during "stonemeal" soil fertilizer application have been the subject of some concern recently around the world for their possible adverse effects on human health and environmental pollution. Samples of BDW utilized were obtained from companies in the mining district of Nova Prata in southern Brazil for chemical characterization and nano-mineralogy investigation, using an integrated application of advanced characterization techniques such as X-ray diffraction (XRD), High Resolution-Transmission Electron microscopy (HR-TEM)/(Energy Dispersive Spectroscopy) EDS/(selected-area diffraction pattern) SAED, Field Emission-Scanning Electron Microscopy (FE-SEM)/EDS and granulometric distribution analysis. The investigation has revealed that BDW materials are dominated by SiO2, Al2O3 and Fe2O3, with a complex micromineralogy including alkali feldspar, augite, barite, labradorite, hematite, heulandrite, gypsum, kaolinite, quartz, and smectite. In addition we have identified a number of trace metals such as Cd, Cu, Cr, Zn that are preferentially concentrated into the finer, inhalable, dust fraction and could so present a health hazard in the urban areas around the basalt mining zone. The implication of this observation is that use of these nanometric-sized particulates as soil fertilizer may present different health challenges to those of conventional fertilizers, inviting future work regarding the relative toxicities of these materials. Our investigation on the particle size distribution, nano-particle mineralogy and chemical composition in typical BDW samples highlights the need to develop cleaning procedures to minimise exposure to these natural fertilizing basalt dust wastes and is thus of direct relevance to both the industrial sector of basalt mining and to agriculture in the region. Copyright © 2015 Elsevier Ltd. All rights reserved.

Heterogeneity in small aliquots of Apolllo 15 olivine-normative basalt: Implications for breccia clast studies

NASA Astrophysics Data System (ADS)

Lindstrom, Marilyn M.; Shervais, John W.; Vetter, Scott K.

1993-05-01

Most of the recent advances in lunar petrology are the direct result of breccia pull-apart studies, which have identified a wide array of new highland and mare basalt rock types that occur only as clasts within the breccias. These rocks show that the lunar crust is far more complex than suspected previously, and that processes such as magma mixing and wall-rock assimilation were important in its petrogenesis. These studies are based on the implicit assumption that the breccia clasts, which range in size from a few mm to several cm across, are representative of the parent rock from which they were derived. In many cases, the aliquot allocated for analysis may be only a few grain diameters across. While this problem is most acute for coarse-grained highland rocks, it can also cause considerable uncertainty in the analysis of mare basalt clasts. Similar problems arise with small aliquots of individual hand samples. Our study of sample heterogeneity in 9 samples of Apollo 15 olivine normative basalt (ONB) which exhibit a range in average grain size from coarse to fine are reported. Seven of these samples have not been analyzed previously, one has been analyzed by INAA only, and one has been analyzed by XRF+INAA. Our goal is to assess the effects of small aliquot size on the bulk chemistry of large mare basalt samples, and to extend this assessment to analyses of small breccia clasts.

Heterogeneity in small aliquots of Apolllo 15 olivine-normative basalt: Implications for breccia clast studies

NASA Technical Reports Server (NTRS)

Lindstrom, Marilyn M.; Shervais, John W.; Vetter, Scott K.

1993-01-01

Most of the recent advances in lunar petrology are the direct result of breccia pull-apart studies, which have identified a wide array of new highland and mare basalt rock types that occur only as clasts within the breccias. These rocks show that the lunar crust is far more complex than suspected previously, and that processes such as magma mixing and wall-rock assimilation were important in its petrogenesis. These studies are based on the implicit assumption that the breccia clasts, which range in size from a few mm to several cm across, are representative of the parent rock from which they were derived. In many cases, the aliquot allocated for analysis may be only a few grain diameters across. While this problem is most acute for coarse-grained highland rocks, it can also cause considerable uncertainty in the analysis of mare basalt clasts. Similar problems arise with small aliquots of individual hand samples. Our study of sample heterogeneity in 9 samples of Apollo 15 olivine normative basalt (ONB) which exhibit a range in average grain size from coarse to fine are reported. Seven of these samples have not been analyzed previously, one has been analyzed by INAA only, and one has been analyzed by XRF+INAA. Our goal is to assess the effects of small aliquot size on the bulk chemistry of large mare basalt samples, and to extend this assessment to analyses of small breccia clasts.

Aqueous Alteration of Basalts: Earth, Moon, and Mars

NASA Technical Reports Server (NTRS)

Ming, Douglas W.

2007-01-01

The geologic processes responsible for aqueous alteration of basaltic materials on Mars are modeled beginning with our knowledge of analog processes on Earth, i.e., characterization of elemental and mineralogical compositions of terrestrial environments where the alteration and weathering pathways related to aqueous activity are better understood. A key ingredient to successful modeling of aqueous processes on Mars is identification of phases that have formed by those processes. The purpose of this paper is to describe what is known about the elemental and mineralogical composition of aqueous alteration products of basaltic materials on Mars and their implications for specific aqueous environments based upon our knowledge of terrestrial systems. Although aqueous alteration has not occurred on the Moon, it is crucial to understand the behaviors of basaltic materials exposed to aqueous environments in support of human exploration to the Moon over the next two decades. Several methods or indices have been used to evaluate the extent of basalt alteration/weathering based upon measurements made at Mars by the Mars Exploration Rover (MER) Moessbauer and Alpha Particle X-Ray Spectrometers. The Mineralogical Alteration Index (MAI) is based upon the percentage of total Fe (Fe(sub T)) present as Fe(3+) in alteration products (Morris et al., 2006). A second method is the evaluation of compositional trends to determine the extent to which elements have been removed from the host rock and the likely formation of secondary phases (Nesbitt and Young, 1992; Ming et al., 2007). Most of the basalts that have been altered by aqueous processes at the two MER landing sites in Gusev crater and on Meridiani Planum have not undergone extensive leaching in an open hydrolytic system with the exception of an outcrop in the Columbia Hills. The extent of aqueous alteration however ranges from relatively unaltered to pervasively altered materials. Several experimental studies have focused upon

Crystal Stratigraphy of Two Basalts from Apollo 16: Unique Crystallization of Picritic Basalt 606063,10-16 and Very-Low-Titanium Basalt 65703,9-13

NASA Technical Reports Server (NTRS)

Donohue, P. H.; Neal, C. R.; Stevens, R. E.; Zeigler, R. A.

2014-01-01

A geochemical survey of Apollo 16 regolith fragments found five basaltic samples from among hundreds of 2-4 mm regolith fragments of the Apollo 16 site. These included a high-Ti vitrophyric basalt (60603,10-16) and one very-low-titanium (VLT) crystalline basalt (65703,9-13). Apollo 16 was the only highlands sample return mission distant from the maria (approx. 200 km). Identification of basaltic samples at the site not from the ancient regolith breccia indicates input of material via lateral transport by post-basin impacts. The presence of basaltic rocklets and glass at the site is not unprecedented and is required to satisfy mass-balance constraints of regolith compositions. However, preliminary characterization of olivine and plagioclase crystal size distributions indicated the sample textures were distinct from other known mare basalts, and instead had affinities to impact melt textures. Impact melt textures can appear qualitatively similar to pristine basalts, and quantitative analysis is required to distinguish between the two in thin section. The crystal stratigraphy method is a powerful tool in studying of igneous systems, utilizing geochemical analyses across minerals and textural analyses of phases. In particular, trace element signatures can aid in determining the ultimate origin of these samples and variations document subtle changes occurring during their petrogenesis.

Petrogenesis of Neogene basaltic volcanism associated with the Lut block, eastern Iran: Implication for tectonic and metallogenic evolution

NASA Astrophysics Data System (ADS)

Saadat, Saeed

This dissertation presents petrochemical data concerning Neogene olivine basalts erupted both along the margins and within the micro-continental Lut block, eastern Iran, which is a part of the active Alpine-Himalayan orogenic belt. These data demonstrate the following: (1) Basalts that erupted from small monogenetic parasitic cones around the Bazman stratovolcano, Makran arc area, in the southern Lut block, are low-Ti sub-alkaline olivine basalts. Enrichments of LILE relative to LREE, and depletions in Nb and Ta relatively to LILE, are similar to those observed for other convergent plate boundary arc magmas around the world and suggest that these basalts formed by melting of subcontinental mantle modified by dehydration of the subducted Oman Sea oceanic lithosphere. (2) Northeast of Iran, an isolated outcrop of Neogene/Quaternary alkali olivine basalt, containing mantle and crustal xenoliths, formed by mixing of small melt fractions from both garnet and spinel-facies mantle. These melts rose to the surface along localized pathways associated with extension at the junction between the N-S right-lateral strike-slip faults and E-W left-lateral strike slip faults. The spinel-peridotite mantle xenoliths contained in the basalts, which equilibrated in the subcontinental lithosphere at depths of 30 to 60 km and temperatures of 965°C to 1065°C, do not preserve evidence of extensive metasomatic enrichment as has been inferred for the mantle below the Damavand volcano further to the west in north-central Iran. (3) Neogene mafic rocks within the central Lut block represent the last manifestation of a much more extensive mid-Tertiary magmatic event. These basalts formed from both OIB-like asthenosphere and subcontinental lithosphere which preserved chemical characteristics inherited from mid-Tertiary subduction associated with the collision of the Arabian with the Eurasian plate and closing of the Neotethys Ocean. Neogene/Quternary alkali olivine basalts erupted mainly along

Coatings on Atacama Desert Basalt: A Possible Analog for Coatings on Gusev Plains Basalt

NASA Technical Reports Server (NTRS)

Sutter, B.; Golden, D. C.; Amundson, R.; Chong-Diaz, G.; Ming, D. W.

2007-01-01

Surface coatings on Gusev Plains basalt have been observed and may contain hematite and nanophase Fe-oxides along with enrichments in P, S, Cl, and K relative to the underlying rock. The Gusev coatings may be derived from the dissolution of adhering soil and/or parent rock along with the addition of S and Cl from outside sources. Transient water for dissolution could be sourced from melting snow during periods of high obliquity, acid fog, and/or ground water (Haskin et al., 2005). Coatings on basalt in the hyper-arid (less than 2mm y(sup -1)) Atacama Desert may assist in understanding the chemistry, mineralogy and formation mechanisms of the Gusev basalt coatings. The Atacama Desert climate is proposed to be analogous to a paleo-Mars climate that was characterized by limited aqueous activity when the Gusev coatings could have formed. The objectives of this work are to (i) determine the chemical nature and extent of surface coatings on Atacama Desert basalt, and (ii) assess coating formation mechanisms in the Atacama Desert. Preliminary backscattered electron imaging of Atacama basalt thin-sections indicated that the coatings are as thick as 20 m. The boundary between the coating and the basalt labradorite, ilmenite, and augite grains was abrupt indicating that the basalt minerals underwent no chemical dissolution. The Atacama coatings have been added to the basalt instead of being derived from basalt chemical weathering. Semi-quantitative energy dispersive spectroscopy shows the coatings to be chemically homogeneous. The coating is depleted in Ca (0.9 wt% CaO) and enriched in K (1.3 wt.% K2O) and Si (69.1 wt.% SiO2) relative to the augite and labradorite grains. A dust source enriched in Si (e.g., poorly crystalline silica) and K and depleted in Ca appears to have been added to the basalt surface. Unlike the Gusev coatings, no P, S, and Cl enrichment was observed. However, Fe (3.2 wt.% FeO) was present in the Atacama coatings suggesting the present of Fe

Mars: Difference Between Lowland and Highland Basalts Confirms A Tendency Observed In Terrestrial and Lunar Basaltic Compositions

NASA Astrophysics Data System (ADS)

Kochemasov, G.

Basalts are very widespread lithology on surfaces of terrestrial planets because their mantles, by general opinion, are predominantly basic in composition. Planetary sur- face unevennesses are often filled with this very fluid under high temperatures ma- terial. Basaltic compositions are however variable and this is helped by a wide iso- morphism of constituent minerals: Na-Ca feldspars and Fe-Mg dark minerals. Ratios between light and dark minerals as well as Fe/Mg ratios in dark minerals play an important role in regulation of basaltic densities. Rock density is a very important factor for constructing tectonic blocks in celestial bodies (Theorem 4, [1]). Angular momenta regulation of different level tectonic blocks in rotating bodies is more effec- tively fulfilled at the crustal level as this level has the longest radius. Thus, composition of crustal basalts is very sensitive to hypsometric (tectonic0 position of certain plan- etary blocks. At Earth oceanic hollows are filled with Fe-rich tholeiites (the deepest Pacific depression is filled with the richest in Fe tholeiites), on continents prevail com- paratively Mg-rich continental basalts. Mare basalts of the Moon are predominantly Fe,Ti-rich. At higher crustal levels appear less dense feldspar-rich, KREEP basalts. This tendency for martian basalts became clear after TES experiment on MGS [2]. The TES data on mineralogy of low-albedo regions show that type1 spectra belong to less dense basic rocks (feldspar 50%, pyroxene 25%) than type2 spectra (feldspar 35%, pyroxene + glass 35%). It means that the highland basaltoids are less dense than the lowland ones. It is interesting that the type1 spectral shape is similar to a spec- trum of the Deccan Traps flood basalts [2]. These continental basalts of the low-lying Indostan subcontinent are known to be relatively Fe-rich and approach the oceanic tholeiites. Global gravity, magnetic, basaltic composition data, available upto now for these bodies: Earth, Moon, Mars

Crystallization of oxidized, moderately hydrous arc basalt at mid- to lower-crustal pressures: implications for andesite genesis

NASA Astrophysics Data System (ADS)

Blatter, Dawnika L.; Sisson, Thomas W.; Hankins, W. Ben

2013-09-01

This study focuses on the production of convergent margin calc-alkaline andesites by crystallization-differentiation of basaltic magmas in the lower to middle crust. Previous experimental studies show that dry, reduced, subalkaline basalts differentiate to tholeiitic (high Fe/Mg) daughter liquids, but the influences of H2O and oxidation on differentiation are less well established. Accordingly, we performed crystallization experiments at controlled oxidized fO2 (Re-ReO2 ≈ ΔNi-NiO + 2) on a relatively magnesian basalt (8.7 wt% MgO) typical of mafic magmas erupted in the Cascades near Mount Rainier, Washington. The basalt was synthesized with 2 wt% H2O and run at 900, 700, and 400 MPa and 1,200 to 950 °C. A broadly clinopyroxenitic crystallization interval dominates near the liquidus at 900 and 700 MPa, consisting of augite + olivine + orthopyroxene + Cr-spinel (in decreasing abundance). With decreasing temperature, plagioclase crystallizes, Fe-Ti-oxide replaces spinel, olivine dissolves, and finally amphibole appears, producing gabbroic and then amphibole gabbroic crystallization stages. Enhanced plagioclase stability at lower pressure narrows the clinopyroxenitic interval and brings the gabbroic interval toward the liquidus. Liquids at 900 MPa track along Miyashiro's (Am J Sci 274(4):321-355, 1974) tholeiitic versus calc-alkaline boundary, whereas those at 700 and 400 MPa become calc-alkaline at silica contents ≥56 wt%. This difference is chiefly due to higher temperature appearance of magnetite (versus spinel) at lower pressures. Although the evolved liquids are similar in many respects to common calc-alkaline andesites, the 900 and 700 MPa liquids differ in having low CaO concentrations due to early and abundant crystallization of augite, with the result that those liquids become peraluminous (ASI: molar Al/(Na + K + 2Ca) > 1) at ≥61 wt% SiO2, similar to liquids reported in other studies of the high-pressure crystallization of hydrous basalts (M�

Crystallization of oxidized, moderately hydrous arc basalt at mid- to lower-crustal pressures: Implications for andesite genesis

USGS Publications Warehouse

Blatter, Dawnika L.; Sisson, Thomas W.; Hankins, W. Ben

2013-01-01

This study focuses on the production of convergent margin calc-alkaline andesites by crystallization–differentiation of basaltic magmas in the lower to middle crust. Previous experimental studies show that dry, reduced, subalkaline basalts differentiate to tholeiitic (high Fe/Mg) daughter liquids, but the influences of H2O and oxidation on differentiation are less well established. Accordingly, we performed crystallization experiments at controlled oxidized fO2 (Re–ReO2 ≈ ΔNi–NiO + 2) on a relatively magnesian basalt (8.7 wt% MgO) typical of mafic magmas erupted in the Cascades near Mount Rainier, Washington. The basalt was synthesized with 2 wt% H2O and run at 900, 700, and 400 MPa and 1,200 to 950 °C. A broadly clinopyroxenitic crystallization interval dominates near the liquidus at 900 and 700 MPa, consisting of augite + olivine + orthopyroxene + Cr-spinel (in decreasing abundance). With decreasing temperature, plagioclase crystallizes, Fe–Ti-oxide replaces spinel, olivine dissolves, and finally amphibole appears, producing gabbroic and then amphibole gabbroic crystallization stages. Enhanced plagioclase stability at lower pressure narrows the clinopyroxenitic interval and brings the gabbroic interval toward the liquidus. Liquids at 900 MPa track along Miyashiro’s (Am J Sci 274(4):321–355, 1974) tholeiitic versus calc-alkaline boundary, whereas those at 700 and 400 MPa become calc-alkaline at silica contents ≥56 wt%. This difference is chiefly due to higher temperature appearance of magnetite (versus spinel) at lower pressures. Although the evolved liquids are similar in many respects to common calc-alkaline andesites, the 900 and 700 MPa liquids differ in having low CaO concentrations due to early and abundant crystallization of augite, with the result that those liquids become peraluminous (ASI: molar Al/(Na + K + 2Ca) > 1) at ≥61 wt% SiO2, similar to liquids reported in other studies of the high-pressure crystallization of hydrous basalts

Flood basalts and mass extinctions

NASA Technical Reports Server (NTRS)

Morgan, W. Jason

1988-01-01

There appears to be a correlation between the times of flood basalts and mass-extinction events. There is a correlation of flood basalts and hotspot tracks--flood basalts appear to mark the beginning of a new hotspot. Perhaps there is an initial instability in the mantle that bursts forth as a flood basalt but then becomes a steady trickle that persists for many tens of millions of years. Suppose that flood basalts and not impacts cause the environmental changes that lead to mass-extinctions. This is a very testable hypothesis: it predicts that the ages of the flows should agree exactly with the times of extinctions. The Deccan and K-T ages agree with this hypothesis; An iridium anomaly at extinction boundaries apparently can be explained by a scaled-up eruption of the Hawaiian type; the occurrence of shocked-quartz is more of a problem. However if the flood basalts are all well dated and their ages indeed agree with extinction times, then surely some mechanism to appropriately produce shocked-quartz will be found.

Trace elements in ocean ridge basalts

NASA Technical Reports Server (NTRS)

Kay, R. W.; Hubbard, N. J.

1978-01-01

A study is made of the trace elements found in ocean ridge basalts. General assumptions regarding melting behavior, trace element fractionation, and alteration effects are presented. Data on the trace elements are grouped according to refractory lithophile elements, refractory siderophile elements, and volatile metals. Variations in ocean ridge basalt chemistry are noted both for regional and temporal characteristics. Ocean ridge basalts are compared to other terrestrial basalts, such as those having La/Yb ratios greater than those of chondrites, and those having La/Yb ratios less than those of chondrites. It is found that (1) as compared to solar or chondrite ratios, ocean ridge basalts have low ratios of large, highly-charged elements to smaller less highly-charged elements, (2) ocean ridge basalts exhibit low ratios of volatile to nonvolatile elements, and (3) the transition metals Cr through Zn in ocean ridge basalts are not fractionated more than a factor of 2 or 3 from the chondritic abundance ratios.

Risk assessment of trace metal-polluted coastal sediments on Hainan Island: A full-scale set of 474 geographical locations covering the entire island.

PubMed

Li, Feng; Lin, Ze-Feng; Wen, Jia-Sheng; Wei, Yan-Sha; Gan, Hua-Yang; He, Hai-Jun; Lin, Jin-Qin; Xia, Zhen; Chen, Bi-Shuang; Guo, Wen-Jie; Tan, Cha-Sheng; Cai, Hua-Yang

2017-12-15

Hainan Island is the second largest island and one of the most famous tourist destinations in China, but sediment contamination by trace metals in coastal areas is a major issue. However, full-scale risk assessments of trace metal-polluted coastal sediments are lacking. In this study, coastal surface sediments from 474 geographical locations covering almost the entire island were collected to identify risk-related variables. Controlling factors and possible sources of trace metals were identified, and the toxicity effects were carefully evaluated. Our results suggest that trace-metal pollution in coastal sediments, which was mainly caused by Pb, Zn and Cu emissions, has primarily resulted from industrial sewage and shipping activities and has threatened the offshore ecosystem of Hainan Island and warrants extensive consideration. This is the first study that has systematically investigated trace metal-polluted coastal sediments throughout the entirety of Hainan Island and provides solid evidence for sustainable marine management in the region. Copyright © 2017 Elsevier Ltd. All rights reserved.

Geochemistry of 24 Ma Basalts from Northeast Egypt: Implications for Small-Scale Convection Beneath the East African Rift System

NASA Astrophysics Data System (ADS)

Endress, C. A.; Furman, T.; Ali Abu El-Rus, M.

2009-12-01

Basalts ~24 Ma in the Cairo-Suez and Fayyum districts of NE Egypt represent the youngest and northernmost lavas potentially associated with the initiation of rifting of the Red Sea. The age of these basalts corresponds to a time period of significant regional magmatism that occurred subsequent to emplacement of 30 Ma flood basalts attributed to the Afar Plume in Ethiopia and Yemen. Beginning ~28 Ma, widespread magmatism occurred across supra-equatorial Africa in Hoggar (Algeria), Tibesti (Chad), Darfur (Sudan), Turkana (Kenya) and Samalat, Bahariya, Quesir and the Sinai Peninsula (Egypt) (e.g. Allegre et al., 1981; Meneisy, 1990; Baldridge et al., 1991; Wilson and Guiraud, 1992; Furman et al., 2006; Lucassen et al., 2008). Available geochemical and isotopic data indicate that Hoggar and Darfur basalts are similar to Turkana lavas, although no direct link between the N African lavas and the Kenya Plume has been made. New geochemical data on the NE Egyptian basalts provide insight into the thermochemical, isotopic, and mineralogical characteristics of the mantle beneath the region in which they were emplaced. The basalts are subalkaline with OIB-like incompatible trace element abundances and homogeneous major element, trace element and isotopic geochemistry. They display relatively flat ITE patterns, with notable positive Pb and negative P anomalies. Isotopic (143Nd/144Nd = 0.51274-0.51285, 87Sr/86Sr = 0.7049-0.7050) and trace element signatures (Ce/Pb = 16-22, Ba/Nb = 9-14, and La/Nb = 0.9-1.0) are consistent with melting of a sub-lithospheric source that has been slightly contaminated by continental crust during ascent and emplacement. The Pb isotopic ratios (206Pb/204Pb = 18.53-18.62, 207Pb/204Pb = 15.59-15.64, and 208Pb/204Pb = 38.80-39.00) in the Egyptian basalts are close to the range of those found in the 30 Ma Ethiopian flood basalts, which are distinct from the more highly radiogenic, high-μ type signature seen in basalts from Turkana, Darfur, and Hoggar

Geochronology and geochemistry of basaltic rocks from the Sartuohai ophiolitic mélange, NW China: Implications for a Devonian mantle plume within the Junggar Ocean

NASA Astrophysics Data System (ADS)

Yang, Gaoxue; Li, Yongjun; Santosh, M.; Yang, Baokai; Yan, Jing; Zhang, Bing; Tong, Lili

2012-10-01

The West Junggar domain in NW China is a distinct tectonic unit of the Central Asian Orogenic Belt (CAOB). It is composed of Paleozoic ophiolitic mélanges, arcs and accretionary complexes. The Sartuohai ophiolitic mélange in the eastern West Junggar forms the northeastern part of the Darbut ophiolitic mélange, which contains serpentinized harzburgite, pyroxenite, dunite, cumulate, pillow lava, abyssal radiolarian chert and podiform chromite, overlain by the Early Carboniferous volcano-sedimentary rocks. In this paper we report new geochronological and geochemical data from basaltic and gabbroic blocks embedded within the Sartuohai ophiolitic mélange, to assess the possible presence of a Devonian mantle plume in the West Junggar, and evaluate the petrogenesis and implications for understanding of the Paleozoic continental accretion of CAOB. Zircon U-Pb analyses from the alkali basalt and gabbro by laser ablation inductively coupled plasma mass spectrometry yielded weighted mean ages of 375 ± 2 Ma and 368 ± 11 Ma. Geochemically, the Sartuohai ophiolitic mélange includes at least two distinct magmatic units: (1) a Late Devonian fragmented ophiolite, which were produced by ca. 2-10% spinel lherzolite partial melting in arc-related setting, and (2) contemporary alkali lavas, which were derived from 5% to 10% garnet + minor spinel lherzolite partial melting in an oceanic plateau or a seamount. Based on detailed zircon U-Pb dating and geochemical data for basalts and gabbros from the Sartuohai ophiolitic mélange, in combination with previous work, indicate a complex evolution by subduction-accretion processes from the Devonian to the Carboniferous. Furthermore, the alkali basalts from the Sartuohai ophiolitic mélange might be correlated to a Devonian mantle plume-related magmatism within the Junggar Ocean. If the plume model as proposed here is correct, it would suggest that mantle plume activity significantly contributed to the crustal growth in the CAOB.

Modeling magma flow and cooling in dikes: Implications for emplacement of Columbia River flood basalts

NASA Astrophysics Data System (ADS)

Petcovic, Heather L.; Dufek, Josef D.

2005-10-01

The Columbia River flood basalts include some of the world's largest individual lava flows, most of which were fed by the Chief Joseph dike swarm. The majority of dikes are chilled against their wall rock; however, rare dikes caused their wall rock to undergo partial melting. These partial melt zones record the thermal history of magma flow and cooling in the dike and, consequently, the emplacement history of the flow it fed. Here, we examine two-dimensional thermal models of basalt injection, flow, and cooling in a 10-m-thick dike constrained by the field example of the Maxwell Lake dike, a likely feeder to the large-volume Wapshilla Ridge unit of the Grande Ronde Basalt. Two types of models were developed: static conduction simulations and advective transport simulations. Static conduction simulation results confirm that instantaneous injection and stagnation of a single dike did not produce wall rock melt. Repeated injection generated wall rock melt zones comparable to those observed, yet the regular texture across the dike and its wall rock is inconsistent with repeated brittle injection. Instead, advective flow in the dike for 3-4 years best reproduced the field example. Using this result, we estimate that maximum eruption rates for Wapshilla Ridge flows ranged from 3 to 5 km3 d-1. Local eruption rates were likely lower (minimum 0.1-0.8 km3 d-1), as advective modeling results suggest that other fissure segments as yet unidentified fed the same flow. Consequently, the Maxwell Lake dike probably represents an upper crustal (˜2 km) exposure of a long-lived point source within the Columbia River flood basalts.

Investigation of magnesium isotope fractionation during basalt differentiation: Implications for a chondritic composition of the terrestrial mantle

USGS Publications Warehouse

Teng, F.-Z.; Wadhwa, M.; Helz, R.T.

2007-01-01

To investigate whether magnesium isotopes are fractionated during basalt differentiation, we have performed high-precision Mg isotopic analyses by multi-collector inductively coupled plasma mass spectrometry (MC-ICP-MS) on a set of well-characterized samples from Kilauea Iki lava lake, Hawaii, USA. Samples from the Kilauea Iki lava lake, produced by closed-system crystal-melt fractionation, range from olivine-rich cumulates to highly differentiated basalts with MgO content ranging from 2.37 to 26.87??wt.%. Our results demonstrate that although these basalts have diverse chemical compositions, mineralogies, crystallization temperatures and degrees of differentiation, their Mg isotopic compositions display no measurable variation within the limits of our external precision (average ??26Mg = - 0.36 ?? 0.10 and ??25Mg = - 0.20 ?? 0.07; uncertainties are 2SD). This indicates that Mg isotopic fractionation during crystal-melt fractionation at temperatures of ??? 1055????C is undetectable at the level of precision of the current investigation. Calculations based on our data suggest that at near-magmatic temperatures the maximum fractionation in the 26Mg/24Mg ratio between olivine and melt is 0.07???. Two additional oceanic basalts, two continental basalts (BCR-1 and BCR-2), and two primitive carbonaceous chondrites (Allende and Murchison) analyzed in this study have Mg isotopic compositions similar to the Kilauea Iki lava lake samples. In contrast to a recent report [U. Wiechert, A.N. Halliday, Non-chondritic magnesium and the origins of the inner terrestrial planets, Earth and Planetary Science Letters 256 (2007) 360-371], the results presented here suggest that the Bulk Silicate Earth has a chondritic Mg isotopic composition. ?? 2007.

[Analysis on the relationship between malaria epidemics and NOAA-AVHRR NDVI in Hainan province].

PubMed

Wen, Liang; Xu, De-zhong; Wang, Shan-qing; Li, Cai-xu; Zhang, Zhi-ying; Su, Yong-qiang

2005-04-01

To explore the relationship between malaria epidemics and NOAA-AVHRR NDVI. Data on malaria were collected in all 19 counties in Hainan province from Feb, 1995 to Jan, 1996. Values regarding normalized difference vegetation index (NDVI)-related indicators including mean and maximum values of NDVI, the area proportion of NDVI values of 145- and 145+, months with NDVI values of 135+, 140+, 145+, 150+ of these counties in this period were all extracted from NOAA-AVHRR images, using ERDAS8.5 software. The coefficients of correlation of malaria incidences and these NDVI-related indicator values were then calculated with SPSS 11.0. The incidence of malaria showed positive correlations to mean and maximum values of NDVI, the area proportion of NDVI values of 145+ and months with NDVI values of 135+, 140+, 145+, 150+ respectively, but having negative correlation to the area of NDVI values of 145-. The malaria epidemic regions were in accordance with those regions that the NDVI values of 145+ were continuing for 9 months or more. Malaria prevalence was associated with NOAA-AVHRR NDVI value which could be considered to be use for malaria surveillance in Hainan province.

Basaltic cannibalism at Thrihnukagigur volcano, Iceland

NASA Astrophysics Data System (ADS)

Hudak, M. R.; Feineman, M. D.; La Femina, P. C.; Geirsson, H.

2014-12-01

Magmatic assimilation of felsic continental crust is a well-documented, relatively common phenomenon. The extent to which basaltic crust is assimilated by magmas, on the other hand, is not well known. Basaltic cannibalism, or the wholesale incorporation of basaltic crustal material into a basaltic magma, is thought to be uncommon because basalt requires more energy than higher silica rocks to melt. Basaltic materials that are unconsolidated, poorly crystalline, or palagonitized may be more easily ingested than fully crystallized massive basalt, thus allowing basaltic cannibalism to occur. Thrihnukagigur volcano, SW Iceland, offers a unique exposure of a buried cinder cone within its evacuated conduit, 100 m below the main vent. The unconsolidated tephra is cross-cut by a NNE-trending dike, which runs across the ceiling of this cave to a vent that produced lava and tephra during the ~4 Ka fissure eruption. Preliminary petrographic and laser ablation inductively coupled mass spectrometry (LA-ICP-MS) analyses indicate that there are two populations of plagioclase present in the system - Population One is stubby (aspect ratio < 1.7) with disequilibrium textures and low Ba/Sr ratios while Population Two is elongate (aspect ratio > 2.1), subhedral to euhedral, and has much higher Ba/Sr ratios. Population One crystals are observed in the cinder cone, dike, and surface lavas, whereas Population Two crystals are observed only in the dike and surface lavas. This suggests that a magma crystallizing a single elongate population of plagioclase intruded the cinder cone and rapidly assimilated the tephra, incorporating the stubbier population of phenocrysts. This conceptual model for basaltic cannibalism is supported by field observations of large-scale erosion upward into the tephra, which is coated by magma flow-back indicating that magma was involved in the thermal etching. While the unique exposure at Thrihnukagigur makes it an exceptional place to investigate basaltic

Observations on the Daytime F-region Irregularities in Two Magnetic Quiet Days Using Hainan Coherent Scatter Phased Array Radar (HCOPAR)

NASA Astrophysics Data System (ADS)

Jin, H.; Chen, G.

2017-12-01

In the magnetic quiet afternoon on 22 July 2013 and noon on 23 May 2016 , Hainan coherent scatter phased array radar (HCOPAR) located at low latitude of China has recorded two cases of the extremely rare daytime F region irregularities. The field-aligned irregularities (FAIs) appeared in the topside F2 layer with small Doppler velocities and narrow spectral widths. The time sequence of the fan sector maps shows the FAIs of 2016 moved northward with almost no zonal drift velocity. The Kp and DST indexes indicate that the irregularities emerged in the magnetic quiet days, so the irregularities were irrelevant to the storm-induced eastward electric field as other daytime cases. More than 2 h after the emergency of the daytime irregularities over Hainan, the Shaoyang digisonde situated 870 km north to the HCOPAR recorded the spread-F in ionospheric F1 layer. According to the echo altitudes, the spread-F may connect the daytime bubbles via magnetic field line. It is difficult for F-region irregularities to survive in the sunlit ionosphere due to the strong photoionization after sunrise. Consequently, the daytime FAIs over Hainan may travel from higher altitudes in the south along the geomagnetic field and are most likely the remnant of postsunset/postmidnight plasma bubbles.

Recent volcanism in the Siqueiros transform fault: Picritic basalts and implications for MORB magma genesis

USGS Publications Warehouse

Perfit, M.R.; Fornari, D.J.; Ridley, W.I.; Kirk, P.D.; Casey, J.; Kastens, K.A.; Reynolds, J.R.; Edwards, M.; Desonie, D.; Shuster, R.; Paradis, S.

1996-01-01

Small constructional volcanic landforms and very fresh-looking lava flows are present along one of the inferred active strike-slip faults that connect two small spreading centers (A and B) in the western portion of the Siqueiros transform domain. The most primitive lavas (picritic and olivine-phyric basalts), exclusively recovered from the young-looking flows within the A-B strike-slip fault, contain millimeter-sized olivine phenocrysts (up to 20 modal%) that have a limited compositional range (Fo91.5-Fo89.5) and complexly zoned Cr-Al spinels. High-MgO (9.5-10.6 wt%) glasses sampled from the young lava flows contain 1-7% olivine phenocrysts (Fo90.5-Fo89) that could have formed by equilibrium crystallization from basaltic melts with Mg# values between 71 and 74. These high MgO (and high Al2O3) glasses may be near-primary melts from incompatible-element depleted oceanic mantle and little modified by crustal mixing and/or fractionation processes. Phase chemistry and major element systematics indicate that the picritic basalts are not primary liquids and formed by the accumulation of olivine and minor spinel from high-MgO melts (10% < MgO < 14%). Compared to typical N-MORB from the East Pacific Rise, the Siqueiros lavas are more primitive and depleted in incompatible elements. Phase equilibria calculations and comparisons with experimental data and trace element modeling support this hypothesis. They indicate such primary mid-ocean ridge basalt magmas formed by 10-18% accumulative decompression melting in the spinel peridotite field (but small amounts of melting in the garnet peridotite field are not precluded). The compositional variations of the primitive magmas may result from the accumulation of different small batch melt fractions from a polybaric melting column.

Basaltic volcanism - The importance of planet size

NASA Technical Reports Server (NTRS)

Walker, D.; Stolper, E. M.; Hays, J. F.

1979-01-01

The volumetrically abundant basalts on the earth, its moon, and the eucrite parent planet all have chemical compositions that are controlled to a large extent by dry, low-pressure, crystal-liquid equilibria. Since this generalization is valid for these three planetary bodies, we infer that it may also apply to the other unsampled terrestrial planets. Other characteristics of basaltic volcanism show variations which appear to be related to planet size: the eruption temperatures, degrees of fractionation, and chemical variety of basalts and the endurance of basaltic volcanism all increase with planet size. Although the processes responsible for chemical differences between basalt suites are known, no simple systematization of the chemical differences between basalts from planet to planet has emerged.

Calcium Sulfate in Atacama Desert Basalt: A Possible Analog for Bright Material in Adirondack Basalt, Gusev Crater

NASA Technical Reports Server (NTRS)

Sutter, B.; Golden, D. C.; Amundson, R.; Chong-Diaz, G.; Ming, D. W.

2007-01-01

The Atacama Desert in northern Chile is one of the driest deserts on Earth (< 2mm/y). The hyper-arid conditions allow extraordinary accumulations of sulfates, chlorides, and nitrates in Atacama soils. Examining salt accumulations in the Atacama may assist understanding salt accumulations on Mars. Recent work examining sulfate soils on basalt parent material observed white material in the interior vesicles of surface basalt. This is strikingly similar to the bright-white material present in veins and vesicles of the Adirondack basalt rocks at Gusev Crater which are presumed to consist of S, Cl, and/or Br. The abundance of soil gypsum/anhydrite in the area of the Atacama basalt suggested that the white material consisted of calcium sulfate (Ca-SO4) which was later confirmed by SEM/EDS analysis. This work examines the Ca-SO4 of Atacama basalt in an effort to provide insight into the possible nature of the bright material in the Adirondack basalt of Gusev Crater. The objectives of this work are to (i) discuss variations in Ca-SO4 crystal morphology in the vesicles and (ii) examine the Ca-SO4 interaction(s) with the basalt interior.

Acidic weathering of basalt and basaltic glass: 1. Near-infrared spectra, thermal infrared spectra, and implications for Mars

NASA Astrophysics Data System (ADS)

Horgan, Briony H. N.; Smith, Rebecca J.; Cloutis, Edward A.; Mann, Paul; Christensen, Philip R.

2017-01-01

Acid-leached rinds and coatings occur in volcanic environments on Earth and have been identified using orbital spectroscopy on Mars, but their development is poorly understood. We simulated long-term open-system acidic weathering in a laboratory by repeatedly rinsing and submerging crystalline and glassy basalts in pH 1 and pH 3 acidic solutions for 213 days and compared their visible/near-infrared (0.3-2.5 µm) and thermal infrared (5-50 µm) spectral characteristics to their microscopic physical and chemical properties from scanning electron microscopy (SEM). We find that while alteration at moderately low pH ( 3) can produce mineral precipitates from solution, it has very little spectral or physical effect on the underlying parent material. In contrast, alteration at very low pH ( 1) results in clear silica spectral signatures for all crystalline samples while glasses exhibit strong blue concave-up near-infrared slopes. SEM indicates that these spectral differences correspond to different modes of alteration. In glass, alteration occurs only at the surface and produces a silica-enriched leached rind, while in more crystalline samples, alteration penetrates the interior to cause dissolution and replacement by silica. We confirm that glass is more stable than crystalline basalt under long-term acidic leaching, suggesting that glass could be enriched and common in terrains on Mars that have been exposed to acidic weathering. Leached glasses are consistent with both OMEGA and Thermal Emission Spectrometer (TES) spectra of the Martian northern lowlands and may contribute to the high-silica phases detected globally in TES Surface Type 2. Thus, both glass-rich deposits and acidic weathering may have been widespread on Mars.

Karyology of eight species of bats (Mammalia: Chiroptera) from Hainan Island, China

PubMed Central

Wu, Yi; Motokawa, Masaharu; Li, Yu-Chun; Harada, Masashi; Chen, Zhong; Lin, Liang-Kong

2009-01-01

Karyotypes and chromosomal data are presented for eight bat species representing two families (Rhinolophidae and Vespertilionidae) from Hainan Island, China. The species investigated were Rhinolophus lepidus (2n = 62, FN = 60), R. pusillus (2n = 62, FN = 60), R. affinis (2n = 62, FN = 60), R. sinicus (2n = 36, FN = 60), Myotis horsfieldi (2n = 44, FN = 52), Pipistrellus abramus (2n = 26, FN = 44), Miniopterus australis (2n = 46, FN = 50) and M. schreibersii (2n = 46, FN = 50). The karyotype of Rhinolophus lepidus is reported for the first time. PMID:19847322

Antibacterial Constituents of Hainan Morinda citrifolia (Noni) Leaves.

PubMed

Zhang, Wei-Min; Wang, Wei; Zhang, Jing-Jing; Wang, Zhi-Rong; Wang, Yu; Hao, Wang-Jun; Huang, Wu-Yang

2016-05-01

Noni (Morinda citrifolia L.) is an edible and medicinal plant distributed in Hainan, China. The antibacterial activities of the extracts of water (WE), petroleum ether (PEE), ethyl acetate (EAE), chloroform (CE), and n-butanol (BE) were assayed by the disk diffusion method. The results showed that the extracts from Noni leaves possessed antibacterial effects against Bacillus subtilis, Escherichia coli, Proteus vulgaris, and Staphylococcus aureus. Among 5 different extracts, the BE produced the best antibacterial activity. The samples were first extracted by ethanol, and the primary compounds in the BE fraction of ethanol extract was further isolated and identified. Six phenolic compounds, including 5, 15-dimethylmorindol, ferulic acid, p-hydroxycinamic acid, methyl 4-hydroxybenzoate, methyl ferulate, and methyl 4-hydroxycinnamate, were identifiedby NMR. The results indicated that the phenolic compounds might significantly contribute to antibacterial activities of Noni leaves. © 2016 Institute of Food Technologists®

Diversity of basaltic lunar volcanism associated with buried impact structures: Implications for intrusive and extrusive events

NASA Astrophysics Data System (ADS)

Zhang, F.; Zhu, M.-H.; Bugiolacchi, R.; Huang, Q.; Osinski, G. R.; Xiao, L.; Zou, Y. L.

2018-06-01

Relatively denser basalt infilling and the upward displacement of the crust-mantle interface are thought to be contributing factors for the quasi-circular mass anomalies for buried impact craters in the lunar maria. Imagery and gravity observations from the Lunar Reconnaissance Orbiter (LRO) and dual Gravity Recovery and Interior Laboratory (GRAIL) missions have identified 10 partially or fully buried impact structures where diversity of observable basaltic mare volcanism exists. With a detailed investigation of the characteristics of associated volcanic landforms, we describe their spatial distribution relationship with respect to the subsurface tectonic structure of complex impact craters and propose possible models for the igneous processes which may take advantage of crater-related zones of weakness and enable magmas to reach the surface. We conclude that the lunar crust, having been fractured and reworked extensively by cratering, facilitates substance and energy exchange between different lunar systems, an effect modulated by tectonic activities both at global and regional scales. In addition, we propose that the intrusion-caused contribution to gravity anomalies should be considered in future studies, although this is commonly obscured by other physical factors such as mantle uplift and basalt load.

Miocene Basaltic Lava Flows and Dikes of the Intervening Area Between Picture Gorge and Steens Basalt of the CRBG, Eastern Oregon

NASA Astrophysics Data System (ADS)

Cahoon, E. B.; Streck, M. J.

2016-12-01

Mid-Miocene basaltic lavas and dikes are exposed in the area between the southern extent of the Picture Gorge Basalt (PGB) and the northern extent of Steens Basalt in a wide corridor of the Malheur National Forest, eastern Oregon. An approximate mid-Miocene age of sampled basaltic units is indicated by stratigraphic relationships to the 16 Ma Dinner Creek Tuff. Lavas provide an opportunity to extend and/or revise distribution areas of either CRBG unit and explore the petrologic transition between them. The PGB and the Steens Basalt largely represent geochemically distinct tholeiitic units of the CRBG; although each unit displays internal complexity. Lavas of PGB are relatively primitive (MgO 5-9 wt.%) while Steens Basalt ranges in MgO from >9 to 3 wt.% but both units are commonly coarsely porphyritic. Conversely, Steens Basalt compositions are on average more enriched in highly incompatible elements (e.g. Rb, Th) and relatively enriched in the lesser incompatible elements (e.g. Y, Yb) compared to the Picture Gorge basalts. These compositional signatures produce inclined and flat patterns on mantle-normalized incompatible trace element plots but with similar troughs and spikes, respectively. New compositional data from our study area indicate basaltic lavas can be assigned as PGB lava flows and dikes, and also to a compositional group chemically distinct between Steens Basalt and PGB. Distribution of lava flows with PGB composition extend this CRBG unit significantly south/southeast closing the exposure gap between PGB and Steens Basalt. We await data that match Steens Basalt compositions but basaltic lavas with petrographic features akin to Steens Basalt have been identified in the study area. Lavas of the transitional unit share characteristics with Upper Steens and Picture Gorge basalt types, but identify a new seemingly unique composition. This composition is slightly more depleted in the lesser incompatible elements (i.e. steeper pattern) on mantle normalized

Characteristics of terrestrial basaltic rock populations: Implications for Mars lander and rover science and safety

NASA Astrophysics Data System (ADS)

Craddock, Robert A.; Golombek, Matthew P.

2016-08-01

We analyzed the morphometry of basaltic rock populations that have been emplaced or affected by a variety of geologic processes, including explosive volcanic eruptions (as a proxy for impact cratering), catastrophic flooding, frost shattering, salt weathering, alluvial deposition, and chemical weathering. Morphometric indices for these rock populations were compared to an unmodified population of rocks that had broken off a solidified lava flow to understand how different geologic processes change rock shape. We found that a majority of rocks have an sphericity described as either a disc or sphere in the Zingg classification system and posit that this is a function of cooling fractures in the basalt (Zingg [1935] Schweiz. Miner. Petrogr. Mitt., 15, 39-140). Angularity (roundness) is the most diagnostic morphometric index, but the Corey Shape Factor (CSF), Oblate-Prolate Index (OPI) and deviation from compactness (D) also sometimes distinguished weathering processes. Comparison of our results to prior analyses of rock populations found at the Mars Pathfinder, Spirit, and Curiosity landing sites support previous conclusions. The observation that the size-frequency distribution of terrestrial rock populations follow exponential functions similar to lander and orbital measurements of rocks on Mars, which is expected from fracture and fragmentation theory, indicates that these distributions are being dominantly controlled by the initial fracture and fragmentation of the basalt.

The complete sequence of Cymbidium mosaic virus from Vanilla fragrans in Hainan, China.

PubMed

He, Zhen; Jiang, Dongmei; Liu, Aiqin; Sang, Liwei; Li, Wenfeng; Li, Shifang

2011-06-01

The complete nucleotide sequence of Cymbidium mosaic virus (CymMV) isolated from vanilla in Hainan province, China was determined for the first time. It comprised 6,224 nucleotides; sequence analysis suggested that the isolate we obtained was a member of the genus Potexvirus, and its sequence shared 86.67-96.61% identities with previously reported sequences. Phylogenetic analysis suggested that CymMV from vanilla fragrans was clustered into subgroup A and the isolates in this subgroup displayed little regional difference.

Geochemistry of Woranso-Mille Pliocene basalts from west-central Afar, Ethiopia: Implications for mantle source characteristics and rift evolution

NASA Astrophysics Data System (ADS)

Alene, Mulugeta; Hart, William K.; Saylor, Beverly Z.; Deino, Alan; Mertzman, Stanley; Haile-Selassie, Yohannes; Gibert, Luis B.

2017-06-01

The Woranso-Mille (WORMIL) area in the west-central Afar, Ethiopia, contains several Pliocene basalt flows, tuffs, and fossiliferous volcaniclastic beds. We present whole-rock major- and trace-element data including REE, and Sr-Nd-Pb isotope ratios from these basalts to characterize the geochemistry, constrain petrogenetic processes, and infer mantle sources. Six basalt groups are distinguished stratigraphically and geochemically within the interval from 3.8 to 3 Ma. The elemental and isotopic data show intra- and inter-group variations derived primarily from source heterogeneity and polybaric crystallization ± crustal inputs. The combined Sr-Nd-Pb isotope data indicate the involvement of three main reservoirs: the Afar plume, depleted mantle, and enriched continental lithosphere (mantle ± crust). Trace element patterns and ratios further indicate the basalts were generated from spinel-dominated shallow melting, consistent with significantly thinned Pliocene lithosphere in western Afar. The on-land continuation of the Aden rift into western Afar during the Pliocene is reexamined in the context of the new geochemistry and age constraints of the WORMIL basalts. The new data reinforce previous interpretations that progressive rifting and transformation of the continental lithosphere to oceanic lithosphere allows for increasing asthenospheric inputs through time as the continental lithosphere is thinned. Accepted trace element values for BHVO-2 are those recently recommended by Jochum et al. (2016) rounded to provide the same significant figures as the data. Ternary model after Schilling et al. (1992); Endmembers from Rooney et al. (2012).

Different mechanisms for acid weathering of crystalline basalt vs. basaltic glass and implications for detection on Mars

NASA Astrophysics Data System (ADS)

Horgan, B. H. N.; Smith, R.; Christensen, P. R.; Cloutis, E.

2016-12-01

Silica-rich acid leached rinds and coatings occur in volcanic environments on Earth and have been identified using orbital spectroscopy on Mars, but their development is poorly understood. We simulated long-term open-system acid weathering in a laboratory by repeatedly submerging and rinsing crystalline and glassy basalts in pH 1 and 3 acidic solutions for 220 days. Visible/near-infrared (VNIR; 0.3-2.5 μm) and thermal-infrared (TIR; 5-50 μm) spectra of the samples were compared to their microscopic properties from scanning electron microscopy (SEM). While previous studies have shown that exposure to moderately low pH ( 3) solutions can produce mineral precipitates, we find that there is very little spectral or microphysical effect on the underlying parent material. In contrast, materials exposed to very low pH ( 1) solutions were visibly altered in SEM images, and contained regions enriched in amorphous silica. These samples exhibited clear silica VNIR and TIR spectral signatures that increased in intensity with their glass content. In addition, glass exposed to low pH solutions often exhibited blue and concave up VNIR slopes. SEM indicates that these spectral differences correspond to different modes of alteration. In glass, low pH alteration occurs only at the surface and produces a silica-enriched rind. In more crystalline samples, alteration penetrates the interior to cause dissolution and replacement by silica. Thus, along with the pH of the aqueous environment, the crystallinity of a rock can greatly affect the way and the degree to which it is weathered. Because alteration is restricted to the surface of glassy materials, bulk glass is more stable than crystalline basalt under long-term acidic leaching. Leached glasses are consistent with OMEGA and TES spectra of the martian northern lowlands, and may contribute to the high-silica phases detected globally in TES Surface Type 2. Thus, both glass-rich deposits and acidic weathering may have been widespread

Lu-Hf constraints on the evolution of lunar basalts

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fujimaki, H.; Tatsumoto, M.

1984-02-15

Very low Ti basalts andd green glass samples from the moon show high Lu/Hf ratios and low Hf concentrations. Low-Ti lunar basalts show high and variable Lu/Hf ratios and higher Hf concentrations, whereas high-Ti lunar basalts show low Lu/Hf ratios and high Hf concentrations. KREEP basalts have constant Lu/Hf ratios and high but variable Hf concentrations. Using the Lu-Hf behavior as a constraint, we propose a model for the mare basalts evolution. This constraint requires extensive crystallization of the primary lunar magma ocean prior to formation of the lunar mare basalt sources and the KREEP basalts. Mare basalts are producedmore » by the melting of the cumulate rocks, and KREEP basalts represent the residual liquid of the magma ocean.« less

Origin of Permian OIB-like basalts in NW Thailand and implication on the Paleotethyan Ocean

NASA Astrophysics Data System (ADS)

Wang, Yuejun; He, Huiying; Zhang, Yuzhi; Srithai, Boontarika; Feng, Qinglai; Cawood, Peter A.; Fan, Weiming

2017-03-01

The basaltic rocks in NW Thailand belong to part of giant Southeast Asian igneous zone that delineates the extension of the Paleotethyan Ocean from SW China into NW Thailand. The Chiang Mai basaltic samples from the Chiang Dao, Fang, Lamphun and Ban Sahakorn sections are divisible into two groups of high-iron basalt. Group 1 has SiO2 of 38.30-49.18 wt.%, FeOt of 13.09-25.37 wt.%, MgO of 8.38-1.60 wt.%, TiO2 of 3.92-6.30 wt.%, which is rarely observed in nature. Group 2 shows SiO2 = 44.71-49.21 wt.%, FeOt = 10.88-14.34 wt.%, MgO = 5.24-16.11 wt.%, TiO2 = 2.22-3.07 wt.% and mg# = 44-70. Olivine and pyroxene are responsible for the fractionation of the Group 2 magma whereas low oxygen fugacity during the late-stage differentiation of the Group 1 magma prolonged fractionation of ilmenite and magnetite. The onset of ilmenite and magnetite fractionations controls the distinct differentiation commencing at MgO = 7 wt.%. Both groups show similar REE and primitive mantle-normalized patterns with insignificant Eu, Nb-Ta and Zr-Hf anomalies. They have similar Nd isotopic compositions with εNd (t) values ranging from + 2.8 to + 3.7 and similar Nb/La, Nb/U, Th/La, Zr/Nb, Th/Ta, La/Yb, Nb/Th, Nb/Y and Zr/Y, resembling those of OIB-like rocks. The representative basaltic sample yields the argon plateau age of 282.3 ± 1.4 Ma, suggestive of Early Permian origin. Our data argue for Group 1 and Group 2 are coeval in the intra-oceanic seamount setting within the Paleotethyan Ocean, which at least continued till 283 Ma. These data, along with other observations, suggest that the Inthanon zone defines the main Paleotethyan suture zone, which northerly links with the Changning-Menglian suture zone in SW China.

Apollo 17 KREEPy basalts - Evidence for nonuniformity of KREEP

NASA Technical Reports Server (NTRS)

Salpas, Peter A.; Taylor, Lawrence A.; Lindstrom, Marilyn M.

1987-01-01

Breccia 72275 contains pristine KREEPy basalt clasts that are not found among other samples collected at Apollo 17. These basalts occur as discrete clasts and as clasts enclosed within basaltic microbreccias. Mineral and whole-rock chemical analyses reveal that the microbreccias are compositionally indistinguishable from the basalt clasts. Samples of the 72275 matrix also have the same compositions as the basalts and the basaltic microbreccias. 72275 was assembled in situ from a single flow or series of closely related flows of Apollo 17 KREEPy basalt before it was transported to the Apollo 17 site. As a rock type, Apollo 17 KREEPy basalts are distinct from Apollo 15 KREEP basalts. The Apollo 17 samples have lower REE concentrations, steeper negative slopes of the HREE, and are less magnesian than the Apollo 15 samples. The two basalt types cannot be related by fractional crystallization, partial melting, or assimilation. This is evidence for the compositional nonuniformity of KREEP as a function of geography.

Carbon contents in reduced basalts at graphite saturation: Implications for the degassing of Mars, Mercury, and the Moon

NASA Astrophysics Data System (ADS)

Li, Yuan; Dasgupta, Rajdeep; Tsuno, Kyusei

2017-06-01

Carbon contents in reduced Martian basalts at graphite saturation were experimentally studied at 1400-1550°C, 1-2 GPa, and logfO2 of IW - 0.4 to IW + 1.5 (IW denotes the Fe-FeO buffer). The results show that carbon solubility in Martian basalts, determined by secondary ion mass spectrometry, is 20 to 1400 ppm, increasing with increasing fO2. Raman and Fourier transform infrared spectroscopic measurements on the quenched silicate glasses show that the dominant carbon species in Martian basalts is carbonate (CO32-). The experimental data generated here were combined with literature data on similar graphite-saturated carbon solubility for mafic-ultramafic compositions to develop an empirical model that can be used to predict carbon content of graphite-saturated reduced basalts at vapor-absent conditions: At IW+1.7 ≥logfO2 ≥ IW-1: (Cppm)=-3702(±534)/T-194(±49)P/T-0.0034(±0.043) logXH2O +0.61(±0.07)NBO/T+0.55(±0.02) ΔIW +3.5(±0.3)R2=0.89 At IW-5.3 ≤ logfO2 ≤ IW-1: (Cppm)=0.96(±0.19) logXH2O-0.25(±0.04)ΔIW+2.83(±0.34)R2=0.6) in which T is temperature in K, P is pressure in GPa, XH2O is mole fraction of water in basalts, ΔIW is the oxygen fugacity relative to the IW buffer, and NBO/T = 2 total O/T - 4 (T = Si + Ti + Al + Cr + P). This model was applied to predict carbon content in graphite-saturated mantle melts of the Mercury, Mars, and the Moon. The results show that graphite may be consumed during the production and extraction of some Martian basalts, and CO2 released by volcanism on Mars cannot be an efficient greenhouse gas in the early Mars. The lunar mantle carbon may be one of the main propellant driving the fire-fountain eruption on the Moon; however, the Mercurian mantle carbon may not be an important propellant for the explosive eruption on Mercury.

Geophysical Measurements of Basalt Intraflow Structures.

DTIC Science & Technology

1997-12-01

COVERED Final 4. TITLE AND SUBTITLE Geophysical Measurements of Basalt Intraflow Structures 6. AUTHOR(S) William K. Hudson 7. PERFORMING...horm 29B (Hi ^ 29 ev. 5-88) by ANISE Sad Z39-18 Prescribed 298-102 GEOPHYSICAL MEASUREMENTS OF BASALT INTRAFLOW STRUCTURES by William K. Hudson A...region. The physical properties of basalt can change dramatically within a single flow and may be associated with changes in intraflow structure. The

The basalts of Mare Frigoris

NASA Astrophysics Data System (ADS)

Kramer, G. Y.; Jaiswal, B.; Hawke, B. R.; Öhman, T.; Giguere, T. A.; Johnson, K.

2015-10-01

This paper discusses the methodology and results of a detailed investigation of Mare Frigoris using remote sensing data from Clementine, Lunar Prospector, and Lunar Reconnaissance Orbiter, with the objective of mapping and characterizing the compositions and eruptive history of its volcanic units. With the exception of two units in the west, Mare Frigoris and Lacus Mortis are filled with basalts having low-TiO2 to very low TiO2, low-FeO, and high-Al2O3 abundances. These compositions indicate that most of the basalts in Frigoris are high-Al basalts—a potentially undersampled, yet important group in the lunar sample collection for its clues about the heterogeneity of the lunar mantle. Thorium abundances of most of the mare basalts in Frigoris are also low, although much of the mare surface appears elevated due to contamination from impact gardening with the surrounding high-Th Imbrium ejecta. There are, however, a few regional thorium anomalies that are coincident with cryptomare units in the east, the two youngest mare basalt units, and some of the scattered pyroclastic deposits and volcanic constructs. In addition, Mare Frigoris lies directly over the northern extent of the major conduit for a magma plumbing system that fed many of the basalts that filled Oceanus Procellarum, as interpreted by Andrews-Hanna et al. (2014) using data from the Gravity Recovery and Interior Laboratory mission. The relationship between this deep-reaching magma conduit and the largest extent of high-Al basalts on the Moon makes Mare Frigoris an intriguing location for further investigation of the lunar mantle.

Graphite solubility and co-vesiculation in basalt-like melts at one-ATM

NASA Technical Reports Server (NTRS)

Colson, R. O.

1993-01-01

The identity and source of the vapor phase that caused lunar lava-fountaining and vesiculation in lunar basalts continues to be of interest because of its implications for the composition and state of the lunar interior and because of its implications for lunar resources. In light of the apparent near-absence of H2O on the Moon, it has been suggested that the vapor phase may be CO2-CO. This premise is supported by the presence of carbon on the surface of volcanic glass beads. However, although the rapid exsolution of CO2 from a melt during decompression may be consistent with firefountaining, it fails to provide a satisfying explanation for vesiculation in mare basalt where exsolution of the gas phase would more reasonably be related to cooling/crystallization at low pressure rather than decompression from high pressure. Also, geochemical trends in lunar volcanic glasses suggest that their source has an oxygen fugacity more reducing than the iron-wustite buffer, an oxygen fugacity that is inconsistent with presence of dissolved CO2-CO at depth. The results of experiments in which a vesicular 'basalt' is produced from a melt equilibrated with graphite and pure CO gas at one atmosphere pressure are reported. The vesiculation is apparently related to exsolution of CO or a CO species during cooling of the melt or growth of quench crystals. Additionally, particulate carbon dispersed through the quenched sample suggests that elemental carbon is either in solution in the melt prior to quenching or tends to go into suspension perhaps as colloid-like particles. These two observations may provide insight into the nature of fire-fountaining and vesiculation on the Moon.

Hyper-localized carbon mineralization in diffusion-limited basalt fractures

NASA Astrophysics Data System (ADS)

Menefee, A. H.; Giammar, D.; Ellis, B. R.

2017-12-01

clays filling the advective path, no permeability changes were measured. Our coupled experiment-modeling approach further elucidates the geochemical conditions controlling carbonation reactions and extends unique microstructural observations to implications for long-term CO2 mineralization in basalt reservoirs.

Evidence of extreme storm events from coral boulder deposits on the southern coast of Hainan Island, China

NASA Astrophysics Data System (ADS)

Zhou, L.; Gao, S.

2017-12-01

The southern coast of Hainan Island in China is one of the most frequently hit areas of tropical cyclones in the Pacific Northwest regions. Long-term storm data are important to reconstruct past extreme wave events, for understanding present-day coastal vulnerability. However, the magnitude of storm and typhoon events in the historical period over the northwestern South China Sea is still poorly understood. A primary study was carried out to investigate into the characteristics of a carbonate boulder field found at the Xiaodonghai (XDH) site on the southern coast of Hainan Island, in order to derive the maximum spatial extent, wave height, and velocity of coastal flooding and to determine the type of extreme wave events responsible for the boulder distributions. We recorded the position, shape, size, and the long axis orientation of 1247 of the boulders, with the a-axes being between 0.52 and 3.76 m. A morphometric analysis of the boulders shows that they are distributed within 160 m of the reef edge, with an exponential fining trend shoreward. Numerical models are used to estimate the minimum wave height and minimum flow velocity required to move these boulders. Flow velocities of 1.76-14.73 m/s and storm wave height of 0.47-15.87 m are needed to displace the measured boulders deposited near the mean sea level. These values are consistent with the dataset of storm boulder transport at other sites in the Asia-Pacific region and local instrumental records. Overall, the carbonate boulder deposits at the XDH site implies that the area is exposed to giant storm waves capable of displacing the very large boulders observed here. The recurrence of a similar storm event in the future will have the potential to cause severe coastal flooding damage on this densely populated part of the low-lying coastlines of Hainan Island.

Linking benthic community structure to terrestrial runoff and upwelling in the coral reefs of northeastern Hainan Island

NASA Astrophysics Data System (ADS)

Li, Xiubao; Wang, Daoru; Huang, Hui; Zhang, Jing; Lian, Jiansheng; Yuan, Xiangcheng; Yang, Jianhui; Zhang, Guoseng

2015-04-01

Near-shore coral reefs in northeastern Hainan Island are close to river mouths and aquaculture ponds, and also located at the center of the Qiongdong Upwelling (QDU). However, it is still unclear how terrestrial runoff and upwelling influence the community composition and spatial distribution of the benthos. During three cruises in 2010 and 2011 in Wenchang, northeastern Hainan Island, we determined a subset of environmental parameters in seawater (e.g. temperature, salinity, DO, dissolved inorganic nutrient (DIN), turbidity and transparency) and macroalgal δ15N and investigated the benthic communities (e.g. live coral cover, coral species richness, juvenile coral density, macroalgal cover and coverage of calcified algae) by video transect and visual census techniques at 10 stations (i.e. 1S-6D). The results showed that the QDU has influenced the reef waters in Wenchang. In 2011, the upwelling started in early May, peaked in July and disappeared in September and most upwelling events lasted for 1-2 weeks between May and July. The results also demonstrated that the reef water was nutrient enriched. Stations close to the river mouth and aquaculture ponds had higher levels of DIN and a higher percentage of ammonia in DIN, and there was consistently lower live coral cover, juvenile coral density and higher macroalgal cover. At some stations in this study, live coral cover was negatively correlated with macroalgal cover (i.e. 2S-6D). Live coral cover, species richness, and juvenile coral density all increased with the distance away from the river outlet and decreased with the rise of DIN. These results suggest that terrestrial runoff and upwelling stimulate nutrient enrichment, and that overgrowing macroalgae has an important influence on the coral communities in northeastern Hainan Island.

The Mineralogy of the Youngest Lunar Basalts

NASA Astrophysics Data System (ADS)

Staid, M. I.; Pieters, C. M.

1999-01-01

The last stage of lunar volcanism produced spectrally distinct basalts on the western nearside of the Moon, which remain unsampled by landing missions. The spectral properties of these late-stage basalts are examined using high-spatial-resolution Clementine images to constrain their mineralogic composition. The young high-Ti basalts in the western Procellarum and Imbrium Basins display a significantly stronger ferrous absorption than earlier mare basalts, suggesting that they may be the most Fe-rich deposits on the Moon. The distinct long-wavelength shape of this ferrous absorption is found to be similar for surface soils and materials excavated from depth. The pervasive character of this absorption feature supports the interpretation of abundant olivine within these late-stage lunar deposits. Important distinctions exist between the early-stage eastern maria and the late-stage western basalts, even though both appear to be Ti-rich. For example, the western maria are more radiogenic than eastern deposits. Telescopic spectra of the high-Ti western maria also exhibit a unique combination of a strong 1 micron feature and a relatively weak or attenuated 2-micron absorption. Pieters et al. concluded that the unusual strength and shape of the 1-micron absorption in western basalts results from an additional absorption from abundant olivine and/or Fe-bearing glass. Either mineralogy could produce the strong long wavelength 1-micron band, but a glassy Fe-rich surface could only form by rapid cooling along the exterior surfaces of flows. Clementine UV-VIS data of late-stage basalts are examined for regions in Oceanus Procellarum and Mare Imbrium. The spectral properties of western regions are compared to the sampled Apollo 11 basalts in Mare Tranquillitatis, which contain similar albedos and UV-VIS spectral properties. For reference, the western basalts are also compared to the low-Ti and Fe-rich basalts in Mare Serenitatis (mISP). Serenitatis basalts have the strongest

Naming Lunar Mare Basalts: Quo Vadimus Redux

NASA Astrophysics Data System (ADS)

Ryder, G.

1999-01-01

Nearly a decade ago, I noted that the nomenclature of lunar mare basalts was inconsistent, complicated, and arcane. I suggested that this reflected both the limitations of our understanding of the basalts, and the piecemeal progression made in lunar science by the nature of the Apollo missions. Although the word "classification" is commonly attached to various schemes of mare basalt nomenclature, there is still no classification of mare basalts that has any fundamental grounding. We remain basically at a classification of the first kind in the terms of Shand; that is, things have names. Quoting John Stuart Mill, Shand discussed classification of the second kind: "The ends of scientific classification are best answered when the objects are formed into groups respecting which a greater number of propositions can be made, and those propositions more important than could be made respecting any other groups into which the same things could be distributed." Here I repeat some of the main contents of my discussion from a decade ago, and add a further discussion based on events of the last decade. A necessary first step of sample studies that aims to understand lunar mare basalt processes is to associate samples with one another as members of the same igneous event, such as a single eruption lava flow, or differentiation event. This has been fairly successful, and discrete suites have been identified at all mare sites, members that are eruptively related to each other but not to members of other suites. These eruptive members have been given site-specific labels, e.g., Luna24 VLT, Apollo 11 hi-K, A12 olivine basalts, and Apollo 15 Green Glass C. This is classification of the first kind, but is not a useful classification of any other kind. At a minimum, a classification is inclusive (all objects have a place) and exclusive (all objects have only one place). The answer to "How should rocks be classified?" is far from trivial, for it demands a fundamental choice about nature

Eliminating Plasmodium falciparum in Hainan, China: a study on the use of behavioural change communication intervention to promote malaria prevention in mountain worker populations.

PubMed

He, Chang-hua; Hu, Xi-min; Wang, Guang-ze; Zhao, Wei; Sun, Ding-wei; Li, Yu-chun; Chen, Chun-xiang; Du, Jian-wei; Wang, Shan-qing

2014-07-13

In the island of Hainan, the great majority of malaria cases occur in mountain worker populations. Using the behavioral change communication (BCC) strategy, an interventional study was conducted to promote mountain worker malaria prevention at a test site. This study found the methods and measures that are suitable for malaria prevention among mountain worker populations. During the Plasmodium falciparum elimination stage in Hainan, a representative sampling method was used to establish testing and control sites in areas of Hainan that were both affected by malaria and had a relatively high density of mountain workers. Two different methods were used: a BCC strategy and a conventional strategy as a control. Before and after the intervention, house visits, core group discussions, and structural surveys were utilized to collect qualitative and quantitative data regarding mountain worker populations (including knowledge, attitudes, and practices [KAPs]; infection status; and serological data), and these data from the testing and control areas were compared to evaluate the effectiveness of BCC strategies in the prevention of malaria. In the BCC malaria prevention strategy testing areas, the accuracy rates of malaria-related KAP were significantly improved among mountain worker populations. The accuracy rates in the 3 aspects of malaria-related KAP increased from 37.73%, 37.00%, and 43.04% to 89.01%, 91.53%, and 92.25%, respectively. The changes in all 3 aspects of KAP were statistically significant (p < 0.01). In the control sites, the changes in the indices were not as marked as in the testing areas, and the change was not statistically significant (p > 0.05). Furthermore, in the testing areas, both the percentage testing positive in the serum malaria indirect fluorescent antibody test (IFAT) and the number of people inflicted decreased more significantly than in the control sites (p < 0.01). The use of the BCC strategy significantly improved the ability of mountain

Mass dependent fractionation of stable chromium isotopes in mare basalts: Implications for the formation and the differentiation of the Moon

NASA Astrophysics Data System (ADS)

Bonnand, Pierre; Parkinson, Ian J.; Anand, Mahesh

2016-02-01

We present the first stable chromium isotopic data from mare basalts in order to investigate the similarity between the Moon and the Earth's mantle. A double spike technique coupled with MC-ICP-MS measurements was used to analyse 19 mare basalts, comprising high-Ti, low-Ti and KREEP-rich varieties. Chromium isotope ratios (δ53Cr) for mare basalts are positively correlated with indices of magmatic differentiation such as Mg# and Cr concentration which suggests that Cr isotopes were fractionated during magmatic differentiation. Modelling of the results provides evidence that spinel and pyroxene are the main phases controlling the Cr isotopic composition during fractional crystallisation. The most evolved samples have the lightest isotopic compositions, complemented by cumulates that are isotopically heavy. Two hypotheses are proposed to explain this fractionation: (i) equilibrium fractionation where heavy isotopes are preferentially incorporated into the spinel lattice and (ii) a difference in isotopic composition between Cr2+ and Cr3+ in the melt. However, both processes require magmatic temperatures below 1200 °C for appreciable Cr3+ to be present at the low oxygen fugacities found in the Moon (IW -1 to -2 log units). There is no isotopic difference between the most primitive high-Ti, low-Ti and KREEP basalts, which suggest that the sources of these basalts were homogeneous in terms of stable Cr isotopes. The least differentiated sample in our sample set is the low-Ti basalt 12016, characterised by a Cr isotopic composition of -0.222 ± 0.025‰, which is within error of the current BSE value (-0.124 ± 0.101‰). The similarity between the mantles of the Moon and Earth is consistent with a terrestrial origin for a major fraction of the lunar Cr. This similarity also suggests that Cr isotopes were not fractionated by core formation on the Moon.

Thermal and mass implications of magmatic evolution in the Lassen volcanic region, California, and minimum constraints on basalt influx to the lower crust

USGS Publications Warehouse

Guffanti, M.; Clynne, M.A.; Muffler, L.J.P.

1996-01-01

We have analyzed the heat and mass demands of a petrologic model of basaltdriven magmatic evolution in which variously fractionated mafic magmas mix with silicic partial melts of the lower crust. We have formulated steady state heat budgets for two volcanically distinct areas in the Lassen region: the large, late Quaternary, intermediate to silicic Lassen volcanic center and the nearby, coeval, less evolved Caribou volcanic field. At Caribou volcanic field, heat provided by cooling and fractional crystallization of 52 km3 of basalt is more than sufficient to produce 10 km3 of rhyolitic melt by partial melting of lower crust. Net heat added by basalt intrusion at Caribou volcanic field is equivalent to an increase in lower crustal heat flow of ???7 mW m-2, indicating that the field is not a major crustal thermal anomaly. Addition of cumulates from fractionation is offset by removal of erupted partial melts. A minimum basalt influx of 0.3 km3 (km2 Ma)-1 is needed to supply Caribou volcanic field. Our methodology does not fully account for an influx of basalt that remains in the crust as derivative intrusives. On the basis of comparison to deep heat flow, the input of basalt could be ???3 to 7 times the amount we calculate. At Lassen volcanic center, at least 203 km3 of mantle-derived basalt is needed to produce 141 km3 of partial melt and drive the volcanic system. Partial melting mobilizes lower crustal material, augmenting the magmatic volume available for eruption at Lassen volcanic center; thus the erupted volume of 215 km3 exceeds the calculated basalt input of 203 km3. The minimum basalt input of 1.6 km3 (km2 Ma)-1 is >5 times the minimum influx to the Caribou volcanic field. Basalt influx high enough to sustain considerable partial melting, coupled with locally high extension rate, is a crucial factor in development of Lassen volcanic center; in contrast. Caribou volcanic field has failed to develop into a large silicic center primarily because basalt supply

Basement Basalts from IODP Site 1438, Amami-Sankaku Basin: Implications for Sources and Melting Processes during Subduction Initiation in the Izu-Bonin-Mariana System

NASA Astrophysics Data System (ADS)

McCarthy, A. J.; Hickey-Vargas, R.; Yogodzinski, G. M.; Ishizuka, O.; Hocking, B.; Bizimis, M.; Savov, I. P.; Kusano, Y.; Arculus, R. J.

2016-12-01

IODP Expedition 351 Site 1438 is located in the Amami-Sankaku basin, just west of the Kyushu-Palau Ridge (KPR), a remnant of the early Izu-Bonin-Mariana (IBM) volcanic arc. 150 meters of basement basalt were drilled beneath 1460 m of volcaniclastic sediments and sedimentary rock. The age range inferred for these basalts is 51-52 Ma, close to the 48-52 Ma age of basalts associated with subduction initiation in the IBM forearc (forearc basalts or FABs). Site 1438 basement basalts form several distinct subunits, all relatively mafic (MgO = 6-14 %; Mg# = 51-83). Non-fluid-mobile incompatible trace element patterns are profoundly depleted. Sm/Nd (0.34-0.43) and Lu/Hf (0.18-0.37) reach values higher than most normal MORBs while La/Yb (0.31-0.98) and Ti/V (15.8-27.0) are lower. These features are shared with basalts drilled just west of the KPR at ODP Site 1201 and DSDP Site 447, and many FABs. Abundances of fluid-mobile incompatible elements vary together and are correlated with subunits defined by flow margins and rock physical properties, suggesting control by post-eruptive seawater alteration rather than varying inputs of subduction fluids. Hf-Nd isotopes for Site 1438 basement basalts range from (present-day) ɛNd of 7.0 to 9.5 and ɛHf of 14.5 to 19.8 in a well-correlated array. Their more radiogenic Hf-isotope character could indicate an Indian-type MORB source, however, basalts with ɛHf >16.5, are more radiogenic than many Indian MORB. Pb isotope data will help distinguish differing mantle source domains and origins for fluid-mobile elements. Overall, the combined geochemical data indicate that the mantle source of basement basalts in drill sites west of the KPR (1438, 1201, 447) are closely similar to those for FAB, and that as a group, these rocks are more depleted than more than 90% of global MORB. Our interpretation is that both IBM forearc basalts and basalts from drill sites immediately west of the KPR formed by melting of the same uniquely depleted mantle

A new species of Eunice (Polychaeta: Eunicidae) from Hainan Island, South China Sea

NASA Astrophysics Data System (ADS)

Wu, Xuwen; Sun, Ruiping; Liu, Ruiyu

2013-01-01

A taxonomic survey of benthic marine animals from coastal regions of Hainan Island, South China Sea, revealed specimens of a new species of Eunice (Polychaeta: Eunicida: Eunicidae), Eunice uschakovi n. sp., collected from the intertidal zone. The species belongs to the group of Eunice that has yellow tridentate subacicular hooks and branchiae scattered over an extensive region of the body. It resembles E. miurai and E. havaica in having both bidentate and tridentate falcigers, but can be readily distinguished by branchial features. Comparisons between E. uschakovi and the two related species are presented.

Thermoluminescence dating of Hawaiian basalt

USGS Publications Warehouse

May, Rodd James

1979-01-01

The thermoluminescence (TL) properties of plagioclase separates from 11 independently dated alkalic basalts 4,500 years to 3.3 million years old and 17 tholeiitic basalts 16 years to 450,000 years old from the Hawaiian Islands were investigated for the purpose of developing a TL dating method for young volcanic rocks. Ratios of natural to artificial TL intensity, when normalized for natural radiation dose rates, were used to quantify the thermoluminescence response of individual samples for age-determination purposes. The TL ratios for the alkalic basalt plagioclase were found to increase with age at a predictable exponential rate that permits the use of the equation for the best-fit line through a plot of the TL ratios relative to known age as a TL age equation. The equation is applicable to rocks ranging in composition from basaltic andesite to trachyte over the age range from about 2,000 to at least 250,000 years before present (B.P.). The TL ages for samples older than 50,000 years have a calculated precision of less than :t 10 percent and a potential estimated accuracy relative to potassium-argon ages of approximately :t 10 percent. An attempt to develop a similar dating curve for the tholeiitic basalts was not as successful, primarily because the dose rates are on the average lower than those for the alkalic basalts by a factor of 6, resulting in lower TL intensities in the tholeiitic basalts for samples of equivalent age, and also because the age distribution of dated material is inadequate. The basic TL properties of the plagioclase from the two rock types are similar, however, and TL dating of tholeiitic basalts should eventually be feasible over the age range 10,000 to at least 200,000 years B.P. The average composition of the plagioclase separates from the alkalic basalts ranges from oligoclase to andesine; compositional variations within this range have no apparent effect on the TL ratios. The average composition of the plagioclase from the tholeiitic

Investigation of Basalt Woven Fabrics for Military Applications

DTIC Science & Technology

2011-11-01

investigates the use of basalt fibers in a composite along with SC-15 epoxy resin for ballistic protection. Basalt fibers are not known as a ballistic...material but rather as a structural one. Even though basalt fibers are not expected to outperform some of the higher ballistic performing materials...such as the aramid and polyethylene fibers ; however, due to the lower manufacturing costs, basalt fibers are an interesting alternative. The objective

Geologic structure of the eastern mare basins. [lunar basalts

NASA Technical Reports Server (NTRS)

Dehon, R. A.; Waskom, J. D.

1976-01-01

The thickness of mare basalts in the eastern maria are estimated and isopachs of the basalts are constructed. Sub-basalt basin floor topography is determined, and correlations of topographic variations of the surface with variations in basalt thickness or basin floor topography are investigated.

Two new species of the purse-web spider genus Atypus Latreille, 1804 from Hainan Island, China (Araneae, Atypidae).

PubMed

Li, Fan; Xu, Xin; Zhang, Zengtao; Liu, Fengxiang; Zhang, Hongli; Li, Daiqin

2018-01-01

Two species of the purse-web spider genus Atypus Latreille, 1804 collected from Hainan Island, China, are diagnosed and described as new to science based on genital morphology, A. baotingensis sp. n. (♂♀) and A. jianfengensis sp. n. (♀). The DNA barcodes of the two species are also provided for future use.

Submarine basalt from the Revillagigedo Islands region, Mexico

USGS Publications Warehouse

Moore, J.G.

1970-01-01

Ocean-floor dredging and submarine photography in the Revillagigedo region off the west coast of Mexico reveal that the dominant exposed rock of the submarine part of the large island-forming volcanoes (Roca Partida and San Benedicto) is a uniform alkali pillow basalt; more siliceous rocks are exposed on the upper, subaerial parts of the volcanoes. Basalts dredged from smaller seamounts along the Clarion fracture zone south of the Revillagigedo Islands are tholeiitic pillow basalts. Pillows of alkali basalts are more vesicular than Hawaiian tholeiitic pillows collected from the same depths. This difference probably reflects a higher original volatile content of the alkali basalts. Manganese-iron oxide nodules common in several dredge hauls generally contain nucleii of rhyolitic pumice or basalt pillow fragments. The pumice floated to its present site from subaerial eruptions, became waterlogged and sank, and was then coated with manganese-iron oxides. The thickness of palagonite rinds on the glassy pillow fragments is proportional to the thickness of manganese-iron oxide layers, and both are a measure of the age of the nodule. Both oldest basalts (10-100 m.y.) and youngest (less than 1 m.y.) are along the Clarion fracture zone, whereas basalts from Roca Partida and San Benedicto volcanoes are of intermediate age. ?? 1970.

Peridotites and basalts reveal broad congruence between two independent records of mantle fO2 despite local redox heterogeneity

NASA Astrophysics Data System (ADS)

Birner, Suzanne K.; Cottrell, Elizabeth; Warren, Jessica M.; Kelley, Katherine A.; Davis, Fred A.

2018-07-01

The oxygen fugacity (fO2) of the oceanic upper mantle has fundamental implications for the production of magmas and evolution of the Earth's interior and exterior. Mid-ocean ridge basalts and peridotites sample the oceanic upper mantle, and retain a record of oxygen fugacity. While fO2 has been calculated for mid-ocean ridge basalts worldwide (>200 locations), ridge peridotites have been comparatively less well studied (33 samples from 11 locations), and never in the same geographic location as basalts. In order to determine whether peridotites and basalts from mid-ocean ridges record congruent information about the fO2 of the Earth's interior, we analyzed 31 basalts and 41 peridotites from the Oblique Segment of the Southwest Indian Ridge. By measuring basalts and peridotites from the same ridge segment, we can compare samples with maximally similar petrogenetic histories. We project the composition and oxygen fugacity of each lithology back to source conditions, and evaluate the effects of factors such as subsolidus diffusion in peridotites and fractional crystallization in basalts. We find that, on average, basalts and peridotites from the Oblique Segment both reflect a source mantle very near the quartz-fayalite-magnetite (QFM) buffer. However, peridotites record a significantly wider range of values (nearly 3 orders of magnitude in fO2), with a single dredge recording a range in fO2 greater than that previously reported for mid-ocean ridge peridotites worldwide. This suggests that mantle fO2 may be heterogeneous on relatively short length scales, and that this heterogeneity may be obscured within aggregated basalt melts. We further suggest that the global peridotite fO2 dataset may not provide a representative sample of average basalt-source mantle. Our study motivates further investigation of the fO2 recorded by ridge peridotites, as peridotites record information about the fO2 of the Earth's interior that cannot be gleaned from analysis of basalts alone.

Improved understanding of magnetic signatures of basaltic lava flows and cones with implication for extraterrestrial exploration

NASA Astrophysics Data System (ADS)

Arlensiú Ordóñez Cencerrado, Amanda; Kilian, Rolf; Díaz-Michelena, Marina

2017-04-01

Large areas of Mars and other celestial bodies are covered with basaltic lava flows and their associated craters. Depending on the individual cooling history and related single versus multi-domain status of the magnetites, as well as the global magnetic field characteristic during crystallization, such rocks could be characterized by very distinct remanent and induced magnetic signatures. Thus, a characterization of analogue craters and lava flows on Earth, and the creation of a database of their distinct magnetic parameters is of key importance for the near future exploration of planetary surfaces like Mars and the Moon. For example, three potential landing sites of the ExoMars 2020 mission include such geological scenarios. Complete on ground measurements of their distinct magnetic properties would also allow information about the characteristics of the early Martian magnetic field. As case study in the former context we selected a small crater (56°07' S, 69°42' E), which represents an agglutinated spatter cone, and its surrounding lava flows within the Pali Aike Volcano Field in Patagonia. Although the chemical composition of the basalts formed along and outside of the crater is similar, distinct local cooling, outgassing and crystallization histories are likely to produced huge differences in the magnetic signatures. With the objective to achieve a better interpretation of future more extended on ground geophysical characterization on board planetary vehicles, we performed a profound magnetic characterization of the Pali Aike crater including: • magnetic surveys with scalar, vector and gradiometric measurements providing high-resolution vector magnetic maps of the crater, • paleomagnetic data obtained from drilled oriented samples along a transect across the crater. Further laboratory data including remanence, susceptibility, coercitivity which have been also drawn in Day plots to analyse single versus multi domain status of magnetites in the basaltic

Modeling Cooling Rates of Martian Flood Basalt Columns

NASA Astrophysics Data System (ADS)

Weiss, D. K.; Jackson, B.; Milazzo, M. P.; Barnes, J. W.

2011-12-01

Columnar jointing in large basalt flows have been extensively studied and can provide important clues about the emplacement conditions and cooling history of a basalt flow. The recent discovery of basalt columns on Mars in crater walls near Marte Vallis provides an opportunity to infer conditions on early Mars when the Martian basalt flows were laid down. Comparison of the Martian columns to Earth analogs allows us to gain further insight into the early Martian climate, and among the best terrestrial analogs are the basalt columns in the Columbia River Basalt Group (CRBG) in eastern Washington. The CRBG is one of the youngest (< 17 Myrs old) and most extensively studied basalt provinces in the world, extending over 163,700 square km with total thickness exceeding 1 km in some places. The morphologies and textures of CRBG basalt columns suggest that in many places flows ~100 m thick cooled at uniform rates, even deep in the flow interior. Such cooling seems to require the presence of water in the column joints since the flow interiors should have cooled much more slowly than the flow margins if conductive cooling dominated. Secondary features, such pillow basalts, likewise suggest the basalt flows were in direct contact with standing water in many places. At the resolution provided by the orbiting HiRISE camera (0.9 m), the Martian basalt columns resemble the CRBG columns in many respects, and so, subject to important caveats, inferences linking the morphologies of the CRBG columns to their thermal histories can be extended in some respects to the Martian columns. In this presentation, we will describe our analysis of the HiRISE images of the Martian columns and what can be reasonably inferred about their thermal histories and the conditions under which they were emplaced. We will also report on a field expedition to the CRBG in eastern Washington State. During that expedition, we surveyed basalt column outcrops on the ground and from the air using Unmanned Aerial

Chemical characterization, nano-particle mineralogy and particle size distribution of basalt dust wastes.

PubMed

Dalmora, Adilson C; Ramos, Claudete G; Oliveira, Marcos L S; Teixeira, Elba C; Kautzmann, Rubens M; Taffarel, Silvio R; de Brum, Irineu A S; Silva, Luis F O

2016-01-01

Understanding the geochemistry of basalt alteration is central to the study of agriculture systems. Various nano-minerals play an important role in the mobilization of contaminants and their subsequent uptake by plants. We present a new analytical experimental approach in combination with an integrated analytical protocol designed to study basalt alteration processes. Recently, throughout the world, ultra-fine and nano-particles derived from basalt dust wastes (BDW) during "stonemeal" soil fertilizer application have been of great concern for their possible adverse effects on human health and environmental pollution. Samples of BDW utilized were obtained from companies in the Nova Prata mining district in southern Brazil for chemical characterization and nano-mineralogy investigation, using an integrated application of advanced characterization techniques such as X-ray diffraction (XRD), High Resolution-Transmission Electron microscopy (HR-TEM)/Energy Dispersive Spectroscopy (EDS)/(selected-area diffraction pattern) SAED, Field Emission-Scanning Electron Microscopy (FE-SEM/EDS), and granulometric distribution analysis. The investigation has revealed that BDW materials are dominated by SiO2, Al2O3, and Fe2O3, with a complex micromineralogy including alkali feldspar, augite, barite, labradorite, hematite, heulandrite, gypsum, kaolinite, quartz, and smectite. In addition, we have identified a number of trace metals such as Cd, Cu, Cr, and Zn, that are preferentially concentrated into the finer, inhalable, dust fraction and, thus, could present a health hazard in the urban areas around the basalt mining zone. The implication of this observation is that use of these nanometric-sized particulates as soil fertilizer may present different health challenges to those of conventional fertilizers, inviting future work regarding the relative toxicities of these materials. Our investigation on the particle size distribution, nano-particle mineralogy and chemical composition in

Determination of Oxygen Fugacity using Olivine-Melt Equilibrium: Implications for the Redox States of Mid-Ocean Ridge Basalt, Ocean Island Basalt, and Island Arc Basalt Mantle Source Regions

NASA Astrophysics Data System (ADS)

Peterman, K. J.; Bryson, S.; Rilling-Hall, S.; Barton, M.

2017-12-01

In order to connect volcanic rocks to their mantle sources, it is essential to consider redox equilibria and their dependence on temperature, pressure, chemical composition, and oxygen fugacity. Oxygen fugacity (fO2) is an intensive variable that strongly affects the behavior of those elements in magmas that are sensitive to changes in redox state, such as Fe, and therefore Mg-Fe silicates, such as olivine. Since fO2 plays an important role in fractional crystallization, in principle it is possible to estimate fO2 from analyses of olivine in equilibrium with the melt. This research describes a new method based on this principle called the Olivine-Melt Equilibrium Method. The Fe3+ and Fe2+ contents of melt in equilibrium with olivine are calculated from the relationship of Gee and Sack (1988) that describes the partitioning of Mg and Fe2+ between olivine and melt. The Fe3+ and Fe2+ contents of the melt are then used to calculate the fO2 at which olivine and melt are in equilibrium using the model of Kress and Carmichael (1991) for the relationship between Fe3+/Fe2+ , fO2, T, P, and melt composition. We have calculated oxygen fugacities from published analyses of coexisting glass and olivine pairs in 1020 samples from three different tectonic settings. The results (expressed as ΔFMQ) for Mid-Ocean Ridge Basalts from the Mid-Atlantic Ridge (-1.55 ± 0.75), the East Pacific Rise (-0.65 ± 0.51), the Juan de Fuca Ridge (-0.77 ± 0.42), and the Galápagos Spreading Center (+0.08 ± 0.48) agree with results obtained using other methods and average -1.09 ± 0.89. Ocean Island Basalts from Iceland and the Galápagos Islands (ΔFMQ = -0.43 ± 0.71 and -0.33 ± 0.35 respectively) also yield values consistent with those obtained by other methods and fall in the same range as MORB. However, lavas from the Canary Islands are more oxidized than typical MORB and OIB, with values (average = +0.68 ± 0.52) approaching those for island arc magmas. We obtain ΔFMQ = +1.03 ± 0.52 for

Model suggests potential for Porites coral population recovery after removal of anthropogenic disturbance (Luhuitou, Hainan, South China Sea).

PubMed

Zhao, Meixia; Riegl, Bernhard; Yu, Kefu; Shi, Qi; Zhang, Qiaomin; Liu, Guohui; Yang, Hongqiang; Yan, Hongqiang

2016-09-13

Population models are important for resource management and can inform about potential trajectories useful for planning purposes, even with incomplete monitoring data. From size frequency data on Luhuitou fringing reef, Hainan, South China Sea, a matrix population model of massive corals (Porites lutea) was developed and trajectories over 100 years under no disturbance and random disturbances were projected. The model reflects a largely open population of Porites lutea, with low local recruitment and preponderance of imported recruitment. Under no further disturbance, the population of Porites lutea will grow and its size structure will change from predominance of small size classes to large size classes. Therewith, total Porites cover will increase. Even under random disturbances every 10 to 20 years, the Porites population could remain viable, albeit at lower space cover. The models suggest recovery at Luhuitou following the removal of chronic anthropogenic disturbance. Extending the area of coral reef reserves to protect the open coral community and the path of connectivity is advisable and imperative for the conservation of Hainan's coral reefs.

Pixels and patterns: A satellite-based investigation of changes to urban features in the Sanya Region, Hainan Special Economic Zone, China

NASA Astrophysics Data System (ADS)

Millward, Andrew Allan

Throughout most of China, and particularly in the coastal areas of its south, ecological resources and traditional culture are viewed by many to be negatively impacted by accelerating urbanization. As a result, achieving an appropriate balance between development and environmental protection has become a significant problem facing policy-makers in these urbanizing areas. The establishment of a Special Economic Zone in the Chinese Province of Hainan has made its coastal areas attractive locations for business and commerce. Development activities that support a burgeoning tourism industry, but which are damaging the environment, are now prominent components of the landscape in the Sanya Region of Hainan. In this study, patterns of urban growth in the Sanya Region of Hainan Province are investigated. Specifically, using several forms of satellite imagery, statistical tools and ancillary data, urban morphology and changes to the extent and spatial arrangement of urban features are researched and documented. A twelve-year chronology of data was collected which consists of four dates of satellite imagery (1987, 1991, 1997, 1999) acquired by three different satellite sensors (SPOT 2 HRV, Landsat 5 TM, Landsat 7 ETM+). A method of assessing inter-temporal variance in unchanged features is developed as a surrogate for traditional evaluations of change detection that require spatially accurate and time-specific data. Results reveal that selective PCA using visible bands with the exclusion of an ocean mask yield the most interpretable components representative of landscape urbanization in the Sanya Region. The geostatistical approach of variography is employed to measure spatial dependence and to test for the presence of directional change in urban morphology across a time series of satellite images. Interpreted time-series geostatistics identify and quantify landscape structure, and changes to structure, and provide a valuable quantitative description of landscape change

Structure of Multi-component Basaltic Glasses under Static and Dynamic Compression: Implications for Mantle Melting and Impact Processes on Planetary Surfaces

NASA Astrophysics Data System (ADS)

Lee, S.; Mosenfelder, J. L.; Tschauner, O. D.; Asimow, P. D.; Park, S.; Kim, H.

2012-12-01

The structures of basaltic melts under both static and dynamic compression are essential to understand the changes in the corresponding melt properties and to provide atomistic insights into impact-induced events in Earth's crust and planetary surfaces. Despite the importance, structural changes in basaltic glasses due both to dynamic and static compression have not been well understood. The advances in multi-nuclear NMR and multi-edge inelastic x-ray scattering allow us to obtain details of the pressure-induced changes in the degree of melt polymerization and cation coordination number in multi-component melts under static and dynamic compression (e.g. Lee, Proc. Nat. Aca. Sci. 2011, 108, 6847; Sol. St. NMR. 2010, 38, 45; Lee et al. Geophys. Res. Letts. 39 5306; Proc. Nat. Aca. Sci. 2008, 105, 7925). Here, we explore the structures of shock compressed silicate glass with a diopside-anorthite eutectic composition (Di64An36), a common Fe-free model basaltic composition, using oxygen K-edge X-ray Raman scattering and high- resolution Al-27 solid-state NMR spectroscopy and report details of shock-induced changes in the atomic configurations. A topologically driven densification of the Di64An36 glass is indicated by the increase in oxygen K-edge energy for the glass upon shock compression with peak pressure up to 20 GPa. The first experimental evidence of the increase in the fraction of highly coordinated Al in shock compressed glass is found in the Al-27 NMR spectra. This result provides atomistic insights into shock compression in basaltic glasses and allows us to microscopically constrain the magnitude of impact events or relevant processes involving natural basalts on Earth and planetary surfaces. We also report the first high pressure multi-nuclear NMR spectrum for basaltic glass up to 5 GPa. While [4]Al species is dominant at 1atm, the significant fraction of [5,6]Al in the glass is apparent, leading to changes in oxygen connectivity in the multi-component. The

Sardinian basalt. An ancient georesource still en vougue

NASA Astrophysics Data System (ADS)

Careddu, Nicola; Grillo, Silvana Maria

2017-04-01

Commercially quarried Sardinian basalt was the result of extensive volcanic activity during the Pliocene and Pleistocene ages, following the opening of the Campidano plain and Tyrrhenian sea rift. Extensive areas of Sardinia have been modelled by large volumes of basalt and andesite rock. An example is provided by the 'Giare' tablelands and other large plateaus located in central Sardinia. Other basalt-rich areas exist in the Island. Sardinia is featured by a vast array of basalt monuments, dating back to the II-I millennium BC, bearing witness to the great workability, durability and resistance to weathering of the rock. The complex of circular defensive towers, known as "Su Nuraxi di Barumini" was included in the World Heritage List by Unesco in 1997. Basalt is currently produced locally to be used for architectural and ornamental purposes. It is obtained by quarrying stone deposits or mining huge boulders which are moved and sawn by means of mechanical machinery. Stone-working is carried out in plants located in various sites of the Island. The paper begins with an historical introduction and then focusses on the current state of the art of Sardinian basalt quarrying, processing and using. An analysis of the basalt market has been carried out.

Insecticide resistance of Anopheles sinensis and An. vagus in Hainan Island, a malaria-endemic area of China.

PubMed

Qin, Qian; Li, Yiji; Zhong, Daibin; Zhou, Ning; Chang, Xuelian; Li, Chunyuan; Cui, Liwang; Yan, Guiyun; Chen, Xiao-Guang

2014-03-03

Malaria is one of the most important public health problems in Southeast Asia, including Hainan Island, China. Vector control is the main malaria control measure, and insecticide resistance is a major concern for the effectiveness of chemical insecticide control programs. The objective of this study is to determine the resistance status of the main malaria vector species to pyrethroids and other insecticides recommended by the World Health Organization (WHO) for indoor residual sprays. The larvae and pupae of Anopheles mosquitoes were sampled from multiple sites in Hainan Island, and five sites yielded sufficient mosquitoes for insecticide susceptibility bioassays. Bioassays of female adult mosquitoes three days after emergence were conducted in the two most abundant species, Anopheles sinensis and An. vagus, using three insecticides (0.05% deltamethrin, 4% DDT, and 5% malathion) and following the WHO standard tube assay procedure. P450 monooxygenase, glutathione S-transferase and carboxylesterase activities were measured. Mutations at the knockdown resistance (kdr) gene and the ace-1 gene were detected by DNA sequencing and PCR-RFLP analysis, respectively. An. sinensis and An. vagus were the predominant Anopheles mosquito species. An. sinensis was found to be resistant to DDT and deltamethrin. An. vagus was susceptible to deltamethrin but resistant to DDT and malathion. Low kdr mutation (L1014F) frequency (<10%) was detected in An. sinensis, but no kdr mutation was detected in An. vagus populations. Modest to high (45%-75%) ace-1 mutation frequency was found in An. sinensis populations, but no ace-1 mutation was detected in An. vagus populations. Significantly higher P450 monooxygenase and carboxylesterase activities were detected in deltamethrin-resistant An. sinensis, and significantly higher P450 monooxygenase, glutathione S-transferase and carboxylesterase activities were found in malathion-resistant An. vagus mosquitoes. Multiple insecticide resistance was

Trace element composition of Luna 24 Crisium VLT basalt

NASA Technical Reports Server (NTRS)

Haskin, L. A.

1978-01-01

The origins of the individual particles analyzed from the Luna 24 core and the information they provide on the trace-element composition of Mare Crisium basalt are considered. Previous analyses of several Luna 24 soil fragments are reviewed. It is concluded that: (1) the average trace-element concentrations for 12 VLT basalt fragments are the best available estimates for bulk samples of Crisium VLT basalt; (2) there is weak evidence that the average Crisium basalt might have a small positive Eu anomaly relative to chondritic matter; (3) the soils contain components from sources other than the Crisium VLT basalt; and (4) there is no convincing information in concentrations of rare-earth elements, Co, Sc, FeO, or Na2O among the analyzed fragments to indicate more than one parent basalt.

Can we identify source lithology of basalt?

PubMed

Yang, Zong-Feng; Zhou, Jun-Hong

2013-01-01

The nature of source rocks of basaltic magmas plays a fundamental role in understanding the composition, structure and evolution of the solid earth. However, identification of source lithology of basalts remains uncertainty. Using a parameterization of multi-decadal melting experiments on a variety of peridotite and pyroxenite, we show here that a parameter called FC3MS value (FeO/CaO-3*MgO/SiO2, all in wt%) can identify most pyroxenite-derived basalts. The continental oceanic island basalt-like volcanic rocks (MgO>7.5%) (C-OIB) in eastern China and Mongolia are too high in the FC3MS value to be derived from peridotite source. The majority of the C-OIB in phase diagrams are equilibrium with garnet and clinopyroxene, indicating that garnet pyroxenite is the dominant source lithology. Our results demonstrate that many reputed evolved low magnesian C-OIBs in fact represent primary pyroxenite melts, suggesting that many previous geological and petrological interpretations of basalts based on the single peridotite model need to be reconsidered.

Can we identify source lithology of basalt?

PubMed Central

Yang, Zong-Feng; Zhou, Jun-Hong

2013-01-01

The nature of source rocks of basaltic magmas plays a fundamental role in understanding the composition, structure and evolution of the solid earth. However, identification of source lithology of basalts remains uncertainty. Using a parameterization of multi-decadal melting experiments on a variety of peridotite and pyroxenite, we show here that a parameter called FC3MS value (FeO/CaO-3*MgO/SiO2, all in wt%) can identify most pyroxenite-derived basalts. The continental oceanic island basalt-like volcanic rocks (MgO>7.5%) (C-OIB) in eastern China and Mongolia are too high in the FC3MS value to be derived from peridotite source. The majority of the C-OIB in phase diagrams are equilibrium with garnet and clinopyroxene, indicating that garnet pyroxenite is the dominant source lithology. Our results demonstrate that many reputed evolved low magnesian C-OIBs in fact represent primary pyroxenite melts, suggesting that many previous geological and petrological interpretations of basalts based on the single peridotite model need to be reconsidered. PMID:23676779

[Growth characteristics of Porites lutea skeleton in east sea area of Hainan Island, China and main affecting environmental factors.

PubMed

Jiang, Qiao Wen; Cao, Zhi Min; Wang, Dao Ru; Li, Yuan Chao; Ni, Jian Yu

2016-03-01

The growth characteristics of Porites lutea skeleton in east sea area of Hainan Island were studied by CoralXDS software based on X-ray chronology. The growth parameters obtained included extension rate (ER), skeleton density (D), and calcification rate (CR). The results showed that ER varied from 0.49 to 1.10 cm·a -1 with an annual average of 0.76 cm·a -1 , D varied from 1.11 to 1.35 g·cm -3 with an annual average of 1.22 g·cm -3 , and CR varied from 0.55 to 1.41 g·cm -2 ·a -1 with an annual average of 0.94 g·cm -2 ·a -1 . Statistical analyses indicated that sea surface temperature (SST) was the key environmental factor that controlled the growth characteristics, as it highly co-varied with ER and CR, less so with D. All of the three growth characteristics increased with the increase of SST. There were other factors that influenced the growth characteristics of the coral column, such as light, water salinity, and hydrodynamics, etc. In addition, typhoon and severe tropical storms also imposed a significant impact on the growth pattern of Porites lutea coral. The change in growth pattern of coral skeleton in east of Hainan Island was a response to complex climate fluctuation. Over the past century, SST of east Hainan Island dramatically increased at a rate of 0.15 ℃·(10 a) -1 . The SST increase trend for the oceanic region could be divided into two stages, early 1940s and early 1980s. The human activities and global warming was the main causes for the increase of SST.

Evidence of climate change impact on stream low flow from the tropical mountain rainforest watershed in Hainan Island, China

Treesearch

Z. Zhou; Y. Ouyang; Z. Qiu; G. Zhou; M. Lin; Y. Li

2017-01-01

Stream low flow estimates are central to assessing climate change impact, water resource management, and ecosystem restoration. This study investigated the impacts of climate change upon stream low flows from a rainforest watershed in Jianfengling (JFL) Mountain, Hainan Island, China, using the low flow selection method as well as the frequency and probability analysis...

Are flood basalt eruptions monogenetic or polygenetic?

NASA Astrophysics Data System (ADS)

Sheth, Hetu C.; Cañón-Tapia, Edgardo

2015-11-01

A fundamental classification of volcanoes divides them into "monogenetic" and "polygenetic." We discuss whether flood basalt fields, the largest volcanic provinces, are monogenetic or polygenetic. A polygenetic volcano, whether a shield volcano or a stratovolcano, erupts from the same dominant conduit for millions of years (excepting volumetrically small flank eruptions). A flood basalt province, built from different eruptive fissures dispersed over wide areas, can be considered a polygenetic volcano without any dominant vent. However, in the same characteristic, a flood basalt province resembles a monogenetic volcanic field, with only the difference that individual eruptions in the latter are much smaller. This leads to the question how a flood basalt province can be two very different phenomena at the same time. Individual flood basalt eruptions have previously been considered monogenetic, contrasted by only their high magma output (and lava fluidity) with typical "small-volume monogenetic" volcanoes. Field data from Hawaiian shield volcanoes, Iceland, and the Deccan Traps show that whereas many feeder dykes were single magma injections, and the eruptions can be considered "large monogenetic" eruptions, multiple dykes are equally abundant. They indicate that the same dyke fissure repeatedly transported separate magma batches, feeding an eruption which was thus polygenetic by even the restricted definition (the same magma conduit). This recognition helps in understanding the volcanological, stratigraphic, and geochemical complexity of flood basalts. The need for clear concepts and terminology is, however, strong. We give reasons for replacing "monogenetic volcanic fields" with "diffuse volcanic fields" and for dropping the term "polygenetic" and describing such volcanoes simply and specifically as "shield volcanoes," "stratovolcanoes," and "flood basalt fields."

Petrogenesis of mare basalts - A record of lunar volcanism

NASA Astrophysics Data System (ADS)

Neal, Clive R.; Taylor, Lawrence A.

1992-06-01

The classification, sources, and overall petrogenesis of mare basalts are reviewed. All mare basalt analyses are used to define a sixfold classification scheme using TiO2 contents as the primary division. A secondary division is made using Al2O3 contents, and a tertiary division is defined using K contents. Such divisions and subdivisions yield a classification containing 12 categories, of which six are accounted for by the existing Apollo and Luna collections. A variety of postmagma-generation such as fractional crystallization, either alone or combined with wallrock assimilation, are invoked to explain the compositional ranges of the various mare basalt suites. High-Ti mare basalts are found at Apollo 1 and Apollo 17 sites; the A-11 basalts contain lower TiO2 abundances, a considerably larger range in trace-element contents, and the only occurrence of high-Ti/high-K mare basalts. The low-Ti basalts exhibit a wide range of major-and trace-element compositions and require source heterogeneity, fractional crystallization, and some assimilation.

[Determination of Total Iron and Fe2+ in Basalt].

PubMed

Liu, Jian-xun; Chen, Mei-rong; Jian, Zheng-guo; Wu, Gang; Wu, Zhi-shen

2015-08-01

Basalt is the raw material of basalt fiber. The content of FeO and Fe2O3 has a great impact on the properties of basalt fibers. ICP-OES and dichromate method were used to test total Fe and Fe(2+) in basalt. Suitable instrument parameters and analysis lines of Fe were chosen for ICP-OES. The relative standard deviation (RSD) of ICP-OES is 2.2%, and the recovery is in the range of 98%~101%. The method shows simple, rapid and highly accurate for determination of total Fe and Fe(2+) in basalt. The RSD of ICP-OES and dichromate method is 0.42% and 1.4%, respectively.

The Origin of Noble Gas Isotopic Heterogeneity in Icelandic Basalts

NASA Technical Reports Server (NTRS)

Dixon, E. T.; Honda, M.; McDougall, I.

2001-01-01

Two models for generation of heterogeneous He, Ne and Ar isotopic ratios in Icelandic basalts are evaluated using a mixing model and the observed noble gas elemental ratios in Icelandic basalts,Ocean island Basalt (OIBs) and Mid-Ocean Ridge Basalt (MORBs). Additional information is contained in the original extended abstract.

Chemical composition of the essential oils of Clausena lansium from Hainan Island, China.

PubMed

Zhao, Jiayuan; Nan, Peng; Zhong, Yang; Zhao, Jiayuan; Nan, Peng; Zhong, Yang

2004-01-01

The essential oils of wild Clausena lansium collected in Hainan Island, China were extracted from leaves, flowers, sarcocarps and seeds, and then analyzed by using GC/MS. The main constituents of the essential oils were: beta-santalol (35.2%), bisabolol (13.7%), methyl santalol (6.9%), ledol (6.5%) and sinensal (5.6%) in the leaves; beta-santalol (50.6%), 9-octadecenamide (17.2%) and sinensal (4.1%) in the flowers; beta-santalol (52.0%), alpha-santalol (15.5%), farnesol (5.2%) and sinensal (4.0%) in the sarcocarps; and phellandrene (54.8%), limonene (23.6%), and p-menth-1-en-4-ol (7.5%) in the seeds.

Quantifying glassy and crystalline basalt partitioning in the oceanic crust

NASA Astrophysics Data System (ADS)

Moore, Rachael; Ménez, Bénédicte

2016-04-01

The upper layers of the oceanic crust are predominately basaltic rock, some of which hosts microbial life. Current studies of microbial life within the ocean crust mainly focus on the sedimentary rock fraction, or those organisms found within glassy basalts while the potential habitability of crystalline basalts are poorly explored. Recently, there has been recognition that microbial life develops within fractures and grain boundaries of crystalline basalts, therefore estimations of total biomass within the oceanic crust may be largely under evaluated. A deeper understanding of the bulk composition and fractionation of rocks within the oceanic crust is required before more accurate estimations of biomass can be made. To augment our understanding of glassy and crystalline basalts within the oceanic crust we created two end-member models describing basalt fractionation: a pillow basalt with massive, or sheet, flows crust and a pillow basalt with sheeted dike crust. Using known measurements of massive flow thickness, dike thickness, chilled margin thickness, pillow lava size, and pillow lava glass thickness, we have calculated the percentage of glassy versus crystalline basalts within the oceanic crust for each model. These models aid our understanding of textural fractionation within the oceanic crust, and can be applied with bioenergetics models to better constrain deep biomass estimates.

Reduction of mare basalts by sulfur loss

USGS Publications Warehouse

Brett, R.

1976-01-01

Metallic Fe content and S abundance are inversely correlated in mare basalts. Either S volatilization from the melt results in reduction of Fe2+ to Fe0 or else high S content decreases Fe0 activity in the melt, thus explaining the correlation. All considerations favor the model that metallic iron in mare basalts is due to sulfur loss. The Apollo 11 and 17 mare basalt melts were probably saturated with S at the time of eruption; the Apollo 12 and 15 basalts were probably not saturated. Non-mare rocks show a positive correlation of S abundance with metallic Fe content; it is proposed that this is due to the addition of meteoritic material having a fairly constant Fe0/S ratio. If true, metallic Fe content or S abundance in non-mare rocks provides a measure of degree of meteoritic contamination. ?? 1976.

Volatiles in basaltic glasses from a subglacial volcano in northern British Columbia (Canada): Implications for ice sheet thickness and mantle volatiles

USGS Publications Warehouse

Dixon, J.E.; Filiberto, J.R.; Moore, J.G.; Hickson, C.J.

2002-01-01

Dissolved H2O, CO2, S and Cl concentrations were measured in glasses from Tanzilla Mountain, a 500 m-high, exposed subglacial volcano from the Tuya-Teslin region, north central British Columbia, Canada. The absence of a flat-topped subaerial lava cap and the dominance of pillows and pillow breccias imply that the Tanzilla Mountain volcanic edifice did not reach a subaerial eruptive phase. Lavas are dominantly tholeiitic basalt with minor amounts of alkalic basalt erupted at the summit and near the base. Tholeiites have roughly constant H2O (c.0.56 ?? 0.07 wt%), CO2 (<30 ppm), S (980 ?? 30 ppm) and Cl (200 ?? 20 ppm) concentrations. Alkalic basalts have higher and more variable volatile concentrations that decrease with increasing elevation (0.62-0.92 wt% H2O, <30 ppm CO2, 870-1110 ppm S and 280-410 ppm Cl) consistent with eruptive degassing. Calculated vapour saturation pressures for the alkalic basalts are 36 to 81 bars corresponding to ice thicknesses of 400 to 900 m. Maximum calculated ice thickness (c. 1 km) is at the lower end of the range of predicted maximum Fraser glaciation (c. 1-2 km), and may indicate initiation of volcanism during the waning stages of glaciation. Temporal evolution from tholeiitic to alkalic compositions may reflect compositional gradients within a melting column, instead of convective processes within a stratified magma chamber. The mantle source region for the subglacial volcanoes is enriched in incompatible elements similar to that for enriched mid-oceanic ridge basalt (e.g. Endeavour Ridge) and does not contain residual amphibole. Thus, metasomatic enrichment most likely reflects small degree partial melts rather than hydrous fluids.

Pre-drilling prediction techniques on the high-temperature high-pressure hydrocarbon reservoirs offshore Hainan Island, China

NASA Astrophysics Data System (ADS)

Zhang, Hanyu; Liu, Huaishan; Wu, Shiguo; Sun, Jin; Yang, Chaoqun; Xie, Yangbing; Chen, Chuanxu; Gao, Jinwei; Wang, Jiliang

2018-02-01

Decreasing the risks and geohazards associated with drilling engineering in high-temperature high-pressure (HTHP) geologic settings begins with the implementation of pre-drilling prediction techniques (PPTs). To improve the accuracy of geopressure prediction in HTHP hydrocarbon reservoirs offshore Hainan Island, we made a comprehensive summary of current PPTs to identify existing problems and challenges by analyzing the global distribution of HTHP hydrocarbon reservoirs, the research status of PPTs, and the geologic setting and its HTHP formation mechanism. Our research results indicate that the HTHP formation mechanism in the study area is caused by multiple factors, including rapid loading, diapir intrusions, hydrocarbon generation, and the thermal expansion of pore fluids. Due to this multi-factor interaction, a cloud of HTHP hydrocarbon reservoirs has developed in the Ying-Qiong Basin, but only traditional PPTs have been implemented, based on the assumption of conditions that do not conform to the actual geologic environment, e.g., Bellotti's law and Eaton's law. In this paper, we focus on these issues, identify some challenges and solutions, and call for further PPT research to address the drawbacks of previous works and meet the challenges associated with the deepwater technology gap. In this way, we hope to contribute to the improved accuracy of geopressure prediction prior to drilling and provide support for future HTHP drilling offshore Hainan Island.

Basalt: Biologic Analog Science Associated with Lava Terrains

NASA Astrophysics Data System (ADS)

Lim, D. S. S.; Abercromby, A.; Kobs-Nawotniak, S. E.; Kobayashi, L.; Hughes, S. S.; Chappell, S.; Bramall, N. E.; Deans, M. C.; Heldmann, J. L.; Downs, M.; Cockell, C. S.; Stevens, A. H.; Caldwell, B.; Hoffman, J.; Vadhavk, N.; Marquez, J.; Miller, M.; Squyres, S. W.; Lees, D. S.; Fong, T.; Cohen, T.; Smith, T.; Lee, G.; Frank, J.; Colaprete, A.

2015-12-01

This presentation will provide an overview of the BASALT (Biologic Analog Science Associated with Lava Terrains) program. BASALT research addresses Science, Science Operations, and Technology. Specifically, BASALT is focused on the investigation of terrestrial volcanic terrains and their habitability as analog environments for early and present-day Mars. Our scientific fieldwork is conducted under simulated Mars mission constraints to evaluate strategically selected concepts of operations (ConOps) and capabilities with respect to their anticipated value for the joint human and robotic exploration of Mars. a) Science: The BASALT science program is focused on understanding habitability conditions of early and present-day Mars in two relevant Mars-analog locations (the Southwest Rift Zone (SWRZ) and the East Rift Zone (ERZ) flows on the Big Island of Hawai'i and the eastern Snake River Plain (ESRP) in Idaho) to characterize and compare the physical and geochemical conditions of life in these environments and to learn how to seek, identify, and characterize life and life-related chemistry in basaltic environments representing these two epochs of martian history. b) Science Operations: The BASALT team will conduct real (non-simulated) biological and geological science at two high-fidelity Mars analogs, all within simulated Mars mission conditions (including communication latencies and bandwidth constraints) that are based on current architectural assumptions for Mars exploration missions. We will identify which human-robotic ConOps and supporting capabilities enable science return and discovery. c) Technology: BASALT will incorporate and evaluate technologies in to our field operations that are directly relevant to conducting the scientific investigations regarding life and life-related chemistry in Mars-analogous terrestrial environments. BASALT technologies include the use of mobile science platforms, extravehicular informatics, display technologies, communication

East Mariana Basin tholeiites: Cretaceous intraplate basalts or rift basalts related to the Ontong Java plume?

USGS Publications Warehouse

Castillo, P.R.; Pringle, M.S.; Carlson, R.W.

1994-01-01

Studies of seafloor magnetic anomaly patterns suggest the presence of Jurassic oceanic crust in a large area in the western Pacific that includes the East Mariana, Nauru and Pigafetta Basins. Sampling of the igneous crust in this area by the Deep Sea Drilling Program (DSDP) and the Ocean Drilling Program (ODP) allows direct evaluation of the age and petrogenesis of this crust. ODP Leg 129 drilled a 51 m sequence of basalt pillows and massive flows in the central East Mariana Basin. 40Ar 39Ar ages determined in this study for two Leg 129 basalts average 114.6 ?? 3.2 Ma. This age is in agreement with the Albian-late Aptian paleontologic age of the overlying sediments, but is distinctively younger than the Jurassic age predicted by magnetic anomaly patterns in the basin. Compositionally, the East Mariana Basin basalts are uniformly low-K tholeiites that are depleted in highly incompatible elements compared to moderately incompatible ones, which is typical of mid-ocean ridge basalts (MORB) erupted near hotspots. The Sr, Nd and Pb isotopic compositions of the tholeiites ( 87Sr 86Srinit = 0.70360-0.70374; 143Nd 144Ndinit = 0.512769-0.512790; 206Pb 204Pbmeas = 18.355-18.386) also overlap with some Indian Ocean Ridge MORB, although they are distinct from the isotopic compositions of Jurassic basalts drilled in the Pigafetta Basin, the oldest Pacific MORB. The isotopic compositions of the East Mariana Basin tholeiites are also similar to those of intraplate basalts, and in particular, to the isotopic signature of basalts from the nearby Ontong Java and Manihiki Plateaus. The East Mariana Basin tholeiites also share many petrologic and isotopic characteristics with the oceanic basement drilled in the Nauru Basin at DSDP Site 462. In addition, the new 110.8 ?? 1.0 Ma 40Ar 39Ar age for two flows from the bottom of Site 462 in the Nauru Basin is indistinguishable from the age of the East Mariana Basin flows. Thus, while magnetic anomaly patterns predict that the igneous

Ibitira: A basaltic achondrite from a distinct parent asteroid

NASA Technical Reports Server (NTRS)

Mittlefehldt, David W.

2004-01-01

I have done detailed petrologic study of Ibitira, nominally classified as a basaltic eucrite. The Fe/Mn ratio of Ibitira pyroxenes with <10 mole % wollastonite component is 36.4 0.4, and is well-resolved from those of five basaltic eucrites studied for comparison; 31.2-32.2. Data for the latter completely overlap. Ibitira pyroxenes have lower Fe/Mg than the basaltic eucrite pyroxenes. Thus, the higher Fe/Mn ratio does not reflect a simple difference in oxidation state. Ibitira also has an oxygen isotopic composition, alkali element contents and a Ti/Hf ratio that distinguish it from basaltic eucrites. These differences support derivation from a distinct parent asteroid. Ibitira is the first recognized representative of the fifth known asteroidal basaltic crust.

Mineral chemistry of Pangidi basalt flows from Andhra Pradesh

NASA Astrophysics Data System (ADS)

Nageswara Rao, P. V.; Swaroop, P. C.; Karimulla, Syed

2012-04-01

This paper elucidates the compositional studies on clinopyroxene, plagioclase, titaniferous magnetite and ilmenite of basalts of Pangidi area to understand the geothermometry and oxybarometry conditions. Petrographic evidence and anorthite content (up to 85%) of plagioclase and temperature estimates of clinopyroxene indicate that the clinopyroxene is crystallized later than or together with plagioclase. The higher An content indicates that the parent magma is tholeiitic composition. The equilibration temperatures of clinopyroxene (1110-1190°C) and titaniferous magnetite and ilmenite coexisting mineral phases (1063-1103°C) are almost similar in lower basalt flow and it is higher for clinopyroxene (900-1110°C) when compared to titaniferous magnetite and ilmenite coexisting mineral phases (748-898°C) in middle and upper basalt flows. From this it can be inferred that the clinopyroxene is crystallized earlier than Fe-Ti oxide phases reequilibration, which indicates that the clinopyroxene temperature is the approximate eruption temperature of the present lava flows. The wide range of temperatures (900-1190°C) attained by clinopyroxene may point out that the equilibration of clinopyroxene crystals initiated from depth till closer to the surface before the melt erupted. Pangidi basalts follow the QFM buffer curve which indicates the more evolved tholeiitic composition. This suggests the parent tholeiitic magma suffered limited fractionation at high temperature under increasing oxygen fugacity in lower basalt flow and more fractionation at medium to lower temperatures under decreasing oxygen fugacity conditions during cooling of middle and upper basalt flows. The variation of oxygen fugacity indicates the oxidizing conditions for lower basalt flow (9.48-10.3) and extremely reducing conditions for middle (12.1-15.5) and upper basalt (12.4-15.54) flows prevailed at the time of cooling. Temperature vs. (FeO+Fe2O3)/(FeO+Fe2O3 +MgO) data plots for present basalts suggested

Germanium abundances in lunar basalts: Evidence of mantle metasomatism

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dickinson, T.; Taylor, G.J.; Keil, T.K.

1988-01-01

To fill in gaps in the present Ge data base, mare basalts were analyzed for Ge and other elements by RNAA and INAA. Mare basalts from Apollo 11, 12, 15, 17 landing sites are rather uniform in Ge abundance, but Apollo 14 aluminous mare basalts and KREEP are enriched in Ge by factors of up to 300 compared to typical mare basalts. These Ge enrichments are not associated with other siderophile element enrichments and, thus, are not due to differences in the amount of metal segregated during core formation. Based on crystal-chemical and inter-element variations, it does not appear thatmore » the observed Ge enrichments are due to silicate liquid immiscibility. Elemental ratios in Apollo 14 aluminous mare basalts, green and orange glass, average basalts and KREEP suggest that incorporation of late accreting material into the source regions or interaction of the magmas with primitive undifferentiated material is not a likely cause for the observed Ge enrichments. We speculate that the most plausible explanation for these Ge enrichments is complexing and concentration of Ge by F, Cl or S in volatile phases. In this manner, the KREEP basalt source regions may have been metasomatized and Apollo 14 aluminous mare basalt magmas may have become enriched in Ge by interacting with these metasomatized areas. The presence of volatile- and Ge-rich regions in the Moon suggests that the Moon was never totally molten. 71 refs., 1 fig., 6 tabs.« less

[Comparison of green coffee beans volatiles chemical composition of Hainan main area].

PubMed

Hu, Rong-Suo; Chu, Zhong; Gu, Feng-Lin; Lu, Min-Quan; Lu, Shao-Fang; Wu, Gui-Ping; Tan, Le-He

2013-02-01

Chemical component of Hainan green coffee beans was analyzed with solid phase microextraction-gas chromatography-mass spectrometry, and the discrepancy between two green coffee beans was differentiated through the spectrum database retrieval and retention index of compound characterization. The experimental results show that: the chemical composition of Wanning coffee beans and Chengmai coffee beans is basically the same. The quantity of analyzed compound in Wanning area coffee is 91, and in Chengmai area coffee is 106, the quantity of the same compound is 66, and the percent of the same component is 75.52%. The same compounds accounted for 89.86% of the total content of Wanning area coffee, and accounted for 85.70% of the total content of Chengmai area coffee.

Study on basalt fiber parameters affecting fiber-reinforced mortar

NASA Astrophysics Data System (ADS)

Orlov, A. A.; Chernykh, T. N.; Sashina, A. V.; Bogusevich, D. V.

2015-01-01

This article considers the effect of different dosages and diameters of basalt fibers on tensile strength increase during bending of fiberboard-reinforced mortar samples. The optimal dosages of fiber, providing maximum strength in bending are revealed. The durability of basalt fiber in an environment of cement, by means of microscopic analysis of samples of fibers and fiberboard-reinforced mortar long-term tests is examined. The article also compares the behavior of basalt fiber in the cement stone environment to a glass one and reveals that the basalt fiber is not subject to destruction.

Os isotope systematics in ocean island basalts

NASA Astrophysics Data System (ADS)

Reisberg, Laurie; Zindler, Alan; Marcantonio, Franco; White, William; Wyman, Derek; Weaver, Barry

1993-12-01

New Re-Os isotopic results for Os-poor basalts from St. Helena, the Comores, Samoa, Pitcairn and Kerguelen dramatically expand the known range of initial Os-186/Os-187 ratios in Ocean Island Basalts (OIBs) to values as high as 1.7. In contrast to the Os isotopic uniformity of Os-rich basalts from the HIMU islands of Tubuai and Mangaia found by Hauri and Hart, our values for St. Helena span most of the known range of Os isotopic variability in oceanic basalts (initial O-187/Os-186 ranges from 1.2 to 1.7). Generation of such radiogenic Os in the mantle requires melting of source materials that contain large proportions of recycled oceanic crust. The very low Os concentrations of most of the basalts analyzed here, however, leave them susceptible to modification via interaction with materials containing radiogenic Os in the near-surface environment. Thus the high Os-186/Os-187 ratios may result from assimilation of radiogenic Os-rich marine sediments, such as Mn oxides, within the volcanic piles traversed by these magmas en route to the surface. Furthermore, the Os isotopic signatures of Os-rich, olivine-laden OIBs may reflect the accumulation of lithospheric olivine, rather than simply their mantle source characteristics. The extent to which these processes alter the view of the mantle obtained via study of Re-Os systematics in oceanic basalts is uncertain. These effects must be quantified before Re-Os systematics in OIBs can be used with confidence to investigate the nature of mantle heterogeneity and its causes.

Stability of Basalt plus Anhydrite plus Calcite at HP-HT: Implications for Venus, the Earth and Mars

NASA Technical Reports Server (NTRS)

Martin, A. M.; Righter, K.; Treiman, A. H.

2010-01-01

"Canali" observed at Venus surface by Magellan are evidence for very long melt flows, but their composition and origin remain uncertain. The hypothesis of water-rich flow is not reasonable regarding the temperature at Venus surface. The length of these channels could not be explained by a silicate melt composition but more likely, by a carbonate-sulfate melt which has a much lower viscosity (Kargel et al 1994). One hypothesis is that calcite CaCO3 and anhydrite CaSO4 which are alteration products of basalts melted during meteorite impacts. A famous example recorded on the Earth (Chicxulub) produced melt and gas rich in carbon and sulfur. Calcite and sulfate evaporites are also present on Mars surface, associated with basalts. An impact on these materials might release C- and S-rich melt or fluid. Another type of planetary phenomenon (affecting only the Earth) might provoke a high pressure destabilization of basalt+anhydrite+calcite. Very high contents of C and S are measured in some Earth s magmas, either dissolved or in the form of crystals (Luhr 2008). As shown by the high H content and high fO2 of primary igneous anhydrite-bearing lavas, the high S content in their source may be explained by subduction of an anhydrite-bearing oceanic crust, either directly (by melting followed by eruption) or indirectly (by release of S-rich melt or fluid that metasomatize the mantle) . Calcite is a major product of oceanic sedimentation and alteration of the crust. Therefore, sulfate- and calcite-rich material may be subducted to high pressures and high temperatures (HP-HT) and release S- and C-rich melts or fluids which could influence the composition of subduction zone lavas or gases. Both phenomena - meteorite impact and subduction - imply HP-HT conditions - although the P-T-time paths are different. Some HP experimental/theoretical studies have been performed on basalt/eclogite, calcite and anhydrite separately or on a combination of two. In this study we performed piston

Lu-Hf AND Sm-Nd EVOLUTION IN LUNAR MARE BASALTS.

USGS Publications Warehouse

Unruh, D.M.; Stille, P.; Patchett, P.J.; Tatsumoto, M.

1984-01-01

Lu-Hf and Sm-Nd data for mare basalts combined with Rb-Sr and total REE data taken from the literature suggest that the mare basalts were derived by small ( less than equivalent to 10%) degrees of partial melting of cumulate sources, but that the magma ocean from which these sources formed was light REE and hf-enriched. Calculated source compositions range from lherzolite to olivine websterite. Nonmodal melting of small amounts of ilmenite ( less than equivalent to 3%) in the sources seems to be required by the Lu/Hf data. A comparison of the Hf and Nd isotopic characteristics between the mare basalts and terrestrial oceanic basalts reveals that the epsilon Hf/ epsilon Nd ratios in low-Ti mare basalts are much higher than in terrestrial ocean basalts.

Continental Basalts and Mantle Xenoliths

NASA Astrophysics Data System (ADS)

Zartman, Robert E.

In this decade of the International Lithosphere Program, much scientific attention is being directed toward the deep continental crust and subadjacent mantle. The petrologic, geochemical, and isotopic signatures of basaltic magmas, which transect much of the lithosphere as they ascend from their site of melting, and of contained cognate and accidental xenoliths, which are found along the path of ascent, give us, perhaps, the best clues to composition and structure in the third dimension. Continental Basalts and Mantle Xenoliths provides an opportunity to sample the British school of thought on subjects such as differences between oceanic and continental basalts, effects of mantle metasomatism, and relationships between events in the subcontinental mantle and those in the overlying crust. This volume is recommended by the publisher as being of interest to senior undergraduates and postgraduate researchers; I would extend that readership to all scientists who seek access to a potpourri of recent findings and current ideas in a rapidly evolving field of research.

Basalt-Trachybasalt Fractionation in Gale Crater, Mars

NASA Astrophysics Data System (ADS)

Bridges, J. C.; Edwards, P. H.; Filiberto, J.; Schwenzer, S. P.; Gasda, P.; Wiens, R.

2016-08-01

A set of igneous float rocks in Gale Crater have been analysed by ChemCam. They are basalt-trachybasalts, 47 to 53 ± 5 wt% SiO2 and formed by ol-dominated crystal fractionation from an Adirondack type basalt, in magmatism with tholeiitic affinities.

Undercooled water in basaltic regoliths and implications for fluidized debris flows on Mars

NASA Technical Reports Server (NTRS)

Gooding, James L.

1987-01-01

Pursuant to the past attribution of many geomorphic features on Mars to the movements of water- or ice-lubricated debris, experiments have been conducted for water freezing in wet, sand-like basaltic substrates. It is found that substantial undercooling can be achieved under Martian conditions, independently of freezing-point depressions due to soluble salts. Attention is given to results for a clay-poor soil with negligible salinity from Mauna Kea, Hawaii, which demonstrate that the degree of undercooling is essentially independent of both soil particle size and water/soil mass ratio, albeit with cooling rate variations.

Geochemistry of Apollo 15 basalt 15555 and soil 15531.

NASA Technical Reports Server (NTRS)

Schnetzler, C. C.; Philpotts, J. A.; Nava, D. F.; Schuhmann, S.; Thomas, H. H.

1972-01-01

Data are presented on major and trace element concentrations determined by atomic absorption spectrophotometry, colorimetry, and isotope dilution in Apollo 15 mare basalt 15555 from the Hadley Rille area, as well as on trace element concentrations determined in plagioclase and pyroxene separates from basalt 15555 and in soil 15531 from the same area. Most of the chemical differences between basalt 15555 and soil 15531 could be accounted for if the soil were a mixture of 88% basalt, 6% KREEP (a component, identified in other Apollo soils, rich in potassium, rare-earth elements, and phosphorus), and 6% plagioclase.

Association of multiple genetic variants with chronic obstructive pulmonary disease susceptibility in Hainan region.

PubMed

Ding, Yipeng; Niu, Huan; Zhou, Long; Zhou, Wenjing; Chen, Jiannan; Xie, Shiliang; Geng, Tingting; Ouyang, Yanhong; He, Ping; Sun, Pei; Feng, Tian; Jin, Tianbo

2017-11-01

Recent genome-wide association studies have shown associations between variants in loci (4q28.1, 6p21.32, 6p21.1, 6q16.1, 10q22.1 and 10q22.3) and chronic obstructive pulmonary disease (COPD) or smoking behaviors. The objective of this study was to look for associations between 16 single nucleotide polymorphisms (SNP) at these six loci and COPD susceptibility in Hainan region. A case-control cohort was composed of 200 COPD cases and 401 controls that were genotyped and analyzed statistically. Odds ratios (OR) and 95% confidence intervals (CIs) were computed by chi-square (χ 2 ) test and genetic models by unconditional logistic regression. After Hardy-Weinberg equilibrium (HWE) P value screening, we excluded the SNP rs12220777 with P < 0.001. By χ 2 test only rs9296092 which located on 6p21.32 was provided the strongest evidence of an increasing risk of COPD with an OR of 3.28 (95% CI = 1.03 - 2.32; P = 0.003) between cases and controls. By genetic models analysis, we not only found rs9296092 increased COPD risk, but also found in the over-dominant model the genotype 'C/T' (OR = 0.55; 95% CI = 0.33 - 0.93; P = 0.023) of rs950063 was proved to be associated with decreased COPD risk. This study is the first to provide evidence of importance of rs9296092 and rs950063 for risk of COPD in Hainan Province. Further studies are needed to characterize the functional sequences that cause COPD. © 2015 John Wiley & Sons Ltd.

Radiolytic Hydrogen Production in the Subseafloor Basaltic Aquifer.

PubMed

Dzaugis, Mary E; Spivack, Arthur J; Dunlea, Ann G; Murray, Richard W; D'Hondt, Steven

2016-01-01

Hydrogen (H2) is produced in geological settings by dissociation of water due to radiation from radioactive decay of naturally occurring uranium ((238)U, (235)U), thorium ((232)Th) and potassium ((40)K). To quantify the potential significance of radiolytic H2 as an electron donor for microbes within the South Pacific subseafloor basaltic aquifer, we use radionuclide concentrations of 43 basalt samples from IODP Expedition 329 to calculate radiolytic H2 production rates in basement fractures. The samples are from three sites with very different basement ages and a wide range of alteration types. U, Th, and K concentrations vary by up to an order of magnitude from sample to sample at each site. Comparison of our samples to each other and to the results of previous studies of unaltered East Pacific Rise basalt suggests that significant variations in radionuclide concentrations are due to differences in initial (unaltered basalt) concentrations (which can vary between eruptive events) and post-emplacement alteration. However, there is no clear relationship between alteration type and calculated radiolytic yields. Local maxima in U, Th, and K produce hotspots of H2 production, causing calculated radiolytic rates to differ by up to a factor of 80 from sample to sample. Fracture width also greatly influences H2 production, where microfractures are hotspots for radiolytic H2 production. For example, H2 production rates normalized to water volume are 190 times higher in 1 μm wide fractures than in fractures that are 10 cm wide. To assess the importance of water radiolysis for microbial communities in subseafloor basaltic aquifers, we compare electron transfer rates from radiolysis to rates from iron oxidation in subseafloor basalt. Radiolysis appears likely to be a more important electron donor source than iron oxidation in old (>10 Ma) basement basalt. Radiolytic H2 production in the volume of water adjacent to a square cm of the most radioactive SPG basalt may support as

An Apollo 15 Mare Basalt Fragment and Lunar Mare Provinces

NASA Technical Reports Server (NTRS)

Ryder, Graham; Burling, Trina Cox

1996-01-01

Lunar sample 15474,4 is a tiny fragment of olivine-augite vitrophyre that is a mare basalt. Although petroraphically distinct from all other Apollo 15 samples, it has been ignored since its first brief description. Our new petrographic and mineral chemical data show that the olivines and pyroxenes are distinct from those in other basalts. The basalt cooled and solidified extremely rapidly; some of the olivine might be cumulate or crystallized prior to extrusion. Bulk-chemical data show that the sample is probably similar to an evolved Apollo 15 olivine-normative basalt in major elements but is distinct in its rare earth element pattern. Its chemical composition and petrography both show that 15474,4 cannot be derived from other Apollo 15 mare basalts by shallow-level crystal fractionation. It represents a distinct extrusion of magma. Nonetheless, the chemical features that 15474,4 has in common with other Apollo 15 mare basalts, including the high FeO/Sc, the general similarity of the rare earth element pattern, and the common (and chondritic) TiO2/Sm ratio, emphasize the concept of a geochemical province at the Apollo 15 site that is distinct from basalts and provinces elsewhere. In making a consistent picture for the derivation of all of the Apollo 15 basalts, both the commonalities and the differences among the basalts must be explained. The Apollo 15 commonalities and differences suggest that the sources must have consisted of major silicate phases with the same composition but with varied amounts of a magma trapped from a contemporary magma ocean. They probably had a high olivine/pyroxene ratio and underwent small and reasonably consistent degrees of partial melting to produce the basalts. These inferences may be inconsistent with models that suggest greatly different depths of melting among basalts, primitive sources for the green glasses, or extensive olivine fractionation during ascent. An integrated approach to lunar mare provinces, of which the Apollo 15

Lu-Hf and Sm-Nd evolution in lunar mare basalts

DOE Office of Scientific and Technical Information (OSTI.GOV)

Unruh, D.M.; Stille, P.; Patchett, P.J.

1984-02-15

Lu-Hf and Sm-Nd data for mare basalts combined with Rb-Sr and total REE data taken from the literature suggest that the mare basalts were derived by small (< or =10%) degrees of partial melting of cumulate sources, but that the magma ocean from which these sources formed was light REE and Hf-enriched. Calculated source compositions range fromm lherzolite to olivine websterite. Nonmodal melting of small amounts of ilmenite (< or =3%) in the sources seems to be required by the Lu/Hf data. A comparison of the Hf and Nd isotopic characteristics between the mare basalts and terrestrial oceanic basalts revealsmore » that the epsilonHf/epsilonNd ratios of low-Ti mare basalts are much higher than in terrestrial oceanic basalts. The results are qualitatively consistent with the hypothesis that terrestrial basalt sources are partial melt residues whereas mare basalt sources are cumulates. Alternatively, the results may imply that the terrestrial mantle has evolved in two (or more) stages of evolution, and that the net effect was depletion of the mantle during the first approx.1-3 b.y. followed by enrichment during the last 1-2 b.y.; or simply that there is a difference in Lu-Hf crystal-liquid partitioning (relative to Sm-Nd) between the lunar and terrestrial mantles.« less

Thermal infrared spectroscopy and modeling of experimentally shocked basalts

USGS Publications Warehouse

Johnson, J. R.; Staid, M.I.; Kraft, M.D.

2007-01-01

New measurements of thermal infrared emission spectra (250-1400 cm-1; ???7-40 ??m) of experimentally shocked basalt and basaltic andesite (17-56 GPa) exhibit changes in spectral features with increasing pressure consistent with changes in the structure of plagioclase feldspars. Major spectral absorptions in unshocked rocks between 350-700 cm-1 (due to Si-O-Si octahedral bending vibrations) and between 1000-1250 cm-1 (due to Si-O antisymmetric stretch motions of the silica tetrahedra) transform at pressures >20-25 GPa to two broad spectral features centered near 950-1050 and 400-450 cm-1. Linear deconvolution models using spectral libraries composed of common mineral and glass spectra replicate the spectra of shocked basalt relatively well up to shock pressures of 20-25 GPa, above which model errors increase substantially, coincident with the onset of diaplectic glass formation in plagioclase. Inclusion of shocked feldspar spectra in the libraries improves fits for more highly shocked basalt. However, deconvolution models of the basaltic andesite select shocked feldspar end-members even for unshocked samples, likely caused by the higher primary glass content in the basaltic andesite sample.

Sulfur Concentration of High-FeO* Basalts at Sulfide Saturation at High Pressures and Temperatures - Implications for Deep Sulfur Cycle on Mars (Invited)

NASA Astrophysics Data System (ADS)

Dasgupta, R.; Ding, S.

2013-12-01

One of the chief influences of magma in the mantles terrestrial planets is its role in outgassing and ingassing of key volatiles and thus affecting planetary dynamics and climate over long timescales. For Mars, magmatic release of greenhouse gases has been argued to be a major factor in creating warm ancient climate. However, the responsible magmatic gas has not been unequivocally identified. SO2 or H2S could have been the main greenhouse gases, yet the magmatic outflux of S from the martian mantle is poorly constrained. Righter et al. [1] showed that the use of sulfur content at sulfide saturation (SCSS) models based on low-FeO*, high-alumina terrestrial basalts to martian basalts leads to significant error. However, experiments on high-FeO* basalts remain limited to ≤0.8 GPa [1], although the onset of melting in the martian mantle may take place at 250-400 km depth (3-5 GPa) [2]. To constrain SCSS of martian magmas at mantle conditions, we simulated basalt-sulfide melt equilibria using two synthesized meteorite compositions, i.e., Yamato980459 (FeO* ˜17 wt.%; Al2O3 ˜6 wt.%) and NWA2990 (FeO* ˜16 wt.%; Al2O3 ˜9 wt.%) in both anhydrous and hydrous conditions at 1-3 GPa and 1500-1700 °C. Experiments were conducted in graphite capsules, using an end-loaded piston cylinder device. Sulfur contents of sulfide melt-saturated experimental quenched basalts were determined using electron microprobe. Our experimental results show that SCSS decreases with increasing pressure and increases with increasing temperature and melt hydration. Based on our experimental SCSS and those from previous low-pressure experiments on high-FeO* martian basalts [2], we developed a new parameterization to predict martian basalt SCSS as a function of depth, temperature, and melt composition. Our model suggests that at the conditions of last equilibration with the sulfide-saturated mantle [2], martian basalts may contain as high as 3500-4700 ppm S and thus S-rich gases might have caused the

Petrologic models of 15388, a unique Apollo 15 mare basalt

NASA Technical Reports Server (NTRS)

Hughes, S. S.; Dasch, E. J.; Nyquist, L. E.

1993-01-01

Mare basalt 15388, a feldspathic microgabbro from the Apennine Front, is chemically and petrographically distinct from Apollo 15 picritic, olivine-normative (ON), and quartz-normative basalts. The evolved chemistry, coarse texture, lack of olivine, and occurrence of cristobalite in 15388 argue for derivation by a late-stage magmatic process that is significantly removed from parental magma. It either crystallized from a magma evolved from the more mafic Apollo 15 basalts, or it crystallized from a currently unrepresented magma. Rb-Sr and Sm-Nd isotopic systematics yield isochron ages of 3.391 plus or minus 0.036 and 3.42 plus or minus 0.07 Ga, respectively, and epsilon(sub Nd) = 8.6 plus or minus 2.4, which is relatively high for Apollo 15 mare basalts. In contrast to chemical patterns of average Apollo 15 ON basalts and Apollo 15 picritic basalt, 15388 has a strongly positive LREE slope, high Ti, shallower HREE slope and a slightly positive Eu anomaly. These features argue against 15388 evolution by simple olivine fractionation of a parental ON or picritic basalt magma, although olivine is a dominant liquidus phase in both potential parents.

Bimodal TiO2 Contents of Mare Basalts at Apollo and Luna Sites and Implications for TiO2 Derived from Clementine Spectral Reflectance

NASA Technical Reports Server (NTRS)

Gillis, J. J.; Jolliff, B. L.

2001-01-01

A revised algorithm to estimate Ti contents of mare regions centered on Apollo and Luna sites shows a bimodal distribution, consistent with mare-basalt sample data. A global TiO2 map shows abundant intermediate TiO2 basalts in western Procellarum. Additional information is contained in the original extended abstract.

Flood basalts and extinction events

NASA Technical Reports Server (NTRS)

Stothers, Richard B.

1993-01-01

The largest known effusive eruptions during the Cenozoic and Mesozoic Eras, the voluminous flood basalts, have long been suspected as being associated with major extinctions of biotic species. Despite the possible errors attached to the dates in both time series of events, the significance level of the suspected correlation is found here to be 1 percent to 4 percent. Statistically, extinctions lag eruptions by a mean time interval that is indistinguishable from zero, being much less than the average residual derived from the correlation analysis. Oceanic flood basalts, however, must have had a different biological impact, which is still uncertain owing to the small number of known examples and differing physical factors. Although not all continental flood basalts can have produced major extinction events, the noncorrelating eruptions may have led to smaller marine extinction events that terminated at least some of the less catastrophically ending geologic stages. Consequently, the 26 Myr quasi-periodicity seen in major marine extinctions may be only a sampling effect, rather than a manifestation of underlying periodicity.

A basalt trigger for the 1991 eruptions of Pinatubo volcano?

USGS Publications Warehouse

Pallister, J.S.; Hoblitt, R.P.; Reyes, A.G.

1992-01-01

THE eruptive products of calc-alkaline volcanos often show evidence for the mixing of basaltic and acid magmas before eruption (see, for example, refs 1, 2). These observations have led to the suggestion3 that the injection of basaltic magma into the base of a magma chamber (or the catastrophic overturn of a stably stratified chamber containing basaltic magma at its base) might trigger an eruption. Here we report evidence for the mixing of basaltic and dacitic magmas shortly before the paroxysmal eruptions of Pinatubo volcano on 15 June 1991. Andesitic scoriae erupted on 12 June contain minerals and glass with disequilibrium compositions, and are considerably more mafic than the dacitic pumices erupted on 15 June. Differences in crystal abundance and glass composition among the pumices may arise from pre-heating of the dacite magma by the underlying basaltic liquid before mixing. Degassing of this basaltic magma may also have contributed to the climatologically important sulphur dioxide emissions that accompanied the Pinatubo eruptions.

The degassing and crystallisation behaviour of basaltic lavas

NASA Astrophysics Data System (ADS)

Applegarth, L. J.; Tuffen, H.; Pinkerton, H.; James, M. R.

2010-12-01

Degassing is a fundamental volcanic process that can play a major role in controlling eruptive styles. Volatile loss during magma ascent and decompression increases the liquidus temperature of the residual melt, resulting in undercooling that can trigger crystallisation (1,2). Late-stage crystallisation and vesiculation are significant factors in controlling the eruptive behaviour of volcanoes of intermediate composition (2), but their effects on basaltic volcanic activity have yet to be fully investigated. We present the results of experiments designed to measure the degassing and crystallisation behaviour of volcanic rocks at temperatures up to 1250°C, using thermo-gravimetric analysis coupled with differential scanning calorimetry and mass spectrometry (TGA-DSC-MS). During TGA-DSC-MS analysis, volatiles released from a sample under a controlled heating programme are identified in a mass spectrometer whilst changes to the sample weight and heat flow are simultaneously recorded. By subjecting samples of basaltic lava and bombs to two heating cycles, we have shown that the onset of degassing (mass loss) is systematically followed by crystallisation (exothermic events) on the first heating cycle. During the second cycle, when the sample has been fully degassed, no mass loss or crystallisation are recorded. Our results also highlight complexities in the processes; in some cases up to four pulses of degassing and crystallisation have been identified during a single heating cycle. Our results allow us to measure the total volatile content of samples, the onset temperatures of degassing and crystallisation and the time lag between the two processes, and the enthalpy, hence percentage, of crystallisation taking place. These results have important implications for our understanding of basaltic volcanic eruptions. During effusive basaltic eruptions, lava can travel many kilometres, threatening property and infrastructure. The final areal flow extent is partly dependent on

Thermal models for basaltic volcanism on Io

USGS Publications Warehouse

Keszthelyil, L.; McEwen, A.

1997-01-01

We present a new model for the thermal emissions from active basaltic eruptions on Io. While our methodology shares many similarities with previous work, it is significantly different in that (1) it uses a field tested cooling model and (2) the model is more applicable to pahoehoe flows and lava lakes than fountain-fed, channelized, 'a'a flows. This model demonstrates the large effect lava porosity has on the surface cooling rate (with denser flows cooling more slowly) and provides a preliminary tool for examining some of the hot spots on Io. The model infrared signature of a basaltic eruption is largely controlled by a single parameter, ??, the average survival time for a lava surface. During an active eruption surfaces are quickly covered or otherwise destroyed and typical values of ?? for a basaltic eruption are expected to be on the order of 10 seconds to 10 minutes. Our model suggests that the Galileo SSI eclipse data are consistent with moderately active to quiescent basaltic lava lakes but are not diagnostic of such activity. Copyright 1997 by the American Geophysical Union.

The Thickness and Volume of Young Basalts Within Mare Imbrium

NASA Astrophysics Data System (ADS)

Chen, Yuan; Li, Chunlai; Ren, Xin; Liu, Jianjun; Wu, Yunzhao; Lu, Yu; Cai, Wei; Zhang, Xunyu

2018-02-01

Basaltic volcanism is one of the most important geologic processes of the Moon. Research on the thickness and volume of late-stage basalts of Mare Imbrium helps better understand the source of lunar volcanism and eruption styles. Based on whether apparent flow fronts exist or not, the late-stage basalts within Mare Imbrium were divided into two groups, namely, Upper Eratosthenian basalts (UEm) and Lower Eratosthenian basalts (LEm). Employing the topographic profile analysis method for UEm and the crater excavation technique for LEm, we studied the thickness and distribution of Eratosthenian basalts in Mare Imbrium. For the UEm units, their thicknesses were estimated to be 16-34 (±2) m with several layers of individual lava ( 8-13 m) inside. The estimated thickness of LEm units was 14-45(±1) m, with a trend of reducing thickness from north to south. The measured thickness of late-stage basalts around the Chang'E-3 landing site ( 37 ± 1 m) was quite close to the results acquired by the lunar penetrating radar carried on board the Yutu Rover ( 35 m). The total volume of the late-stage basalts in Mare Imbrium was calculated to be 8,671 (±320) km3, which is 4 times lower than that of Schaber's estimation ( 4 × 104 km3). Our results indicate that the actual volume is much lower than previous estimates of the final stage of the late basaltic eruption of Mare Imbrium. Together, the area flux and transport distance of the lava flows gradually decreased with time. These results suggest that late-stage volcanic evolution of the Moon might be revised.

Eruptive History and Chemical Evolution of the Precaldera and Postcaldera Basalt-Dacite Sequences, Long Valley, California: Implications for Magma Sources, Current Seismic Unrest, and Future Volcanism

USGS Publications Warehouse

Bailey, Roy A.

2004-01-01

The Long Valley Volcanic Field in east-central California straddles the East Sierran frontal fault zone, overlapping the Sierra Nevada and western Basin and Range Provinces. The volcanic field overlies a mature mid-Tertiary erosional surface that truncates a basement composed mainly of Mesozoic plutons and associated roof pendants of Mesozoic metavolcanic and Paleozoic metasedimentary rocks. Long Valley volcanism began about 4 Ma during Pliocene time and has continued intermittently through the Holocene. The volcanism is separable into two basalt-rhyolite episodes: (1) an earlier, precaldera episode related to Long Valley Caldera that climaxed with eruption of the Bishop Tuff and collapse of the caldera; and (2) a later, postcaldera episode structurally related to the north-south-trending Mono-Inyo Craters fissure system, which extends from the vicinity of Mammoth Mountain northward through the west moat of the caldera to Mono Lake. Eruption of the basalt-dacite sequence of the precaldera basalt-rhyolite episode peaked volumetrically between 3.8 and 2.5 Ma; few basalts were erupted during the following 1.8 m.y. (2.5?0.7 Ma). Volcanism during this interval was dominated by eruption of the voluminous rhyolites of Glass Mountain (2.2?0.8 Ma) and formation of the Bishop Tuff magma chamber. Catastrophic rupture of the roof of this magma chamber caused eruption of the Bishop Tuff and collapse of Long Valley Caldera (760 ka), after which rhyolite eruptions resumed on the subsided caldera floor. The earliest postcaldera rhyolite flows (700?500 ka) contain quenched globular basalt enclaves (mafic magmatic inclusions), indicating that basaltic magma had reentered shallow parts of the magmatic system after a 1.8-m.y. hiatus. Later, at about 400 ka, copious basalts, as well as dacites, began erupting from vents mainly in the west moat of the caldera. These later eruptions initiated the postcaldera basalt-rhyolite episode related to the Mono-Inyo Craters fissure system, which

Lu-Hf CONSTRAINTS ON THE EVOLUTION OF LUNAR BASALTS.

USGS Publications Warehouse

Fujimaki, Hirokazu; Tatsumoto, Mistunobu

1984-01-01

The authors show that a cumulate-remelting model best explains the recently acquired data on the Lu-Hf systematics of lunar mare basalts. The authors model is first constructed using the Lu and Hf concentration data and it is then further strengthened by the Hf isotopic evidence. The authors also show that the similarity of MgO/FeO ratios and the Cr//2O//3 contents between high-Ti and low-Ti basalts, which have been given significance by A. E. Ringwood and D. H. Green are not important constraints for lunar basalt petrogenesis. The authors principal aim is to revive the remelting model for further consideration with the powerful constraints of Lu-Hf systematics of lunar basalts.

Petrogenesis of early Jurassic basalts in southern Jiangxi Province, South China: Implications for the thermal state of the Mesozoic mantle beneath South China

NASA Astrophysics Data System (ADS)

Cen, Tao; Li, Wu-xian; Wang, Xuan-ce; Pang, Chong-jin; Li, Zheng-xiang; Xing, Guang-fu; Zhao, Xi-lin; Tao, Jihua

2016-07-01

Early Jurassic bimodal volcanic and intrusive rocks in southern South China show distinct associations and distribution patterns in comparison with those of the Middle Jurassic and Cretaceous rocks in the area. It is widely accepted that these rocks formed in an extensional setting, although the timing of the onset and the tectonic driver for extension are debated. Here, we present systematic LA-ICP-MS zircon U-Pb ages, whole-rock geochemistry and Sr-Nd isotope data for bimodal volcanic rocks from the Changpu Formation in the Changpu-Baimianshi and Dongkeng-Linjiang basins in southern Jiangxi Province, South China. Zircon U-Pb ages indicate that the bimodal volcanic rocks erupted at ca. 190 Ma, contemporaneous with the Fankeng basalts ( 183 Ma). A compilation of geochronological results demonstrates that basin-scale basaltic eruptions occurred during the Early Jurassic within a relatively short interval (< 5 Ma). These Early Jurassic basalts have tholeiitic compositions and OIB-like trace element distribution patterns. Geochemical analyses show that the basalts were derived from depleted asthenospheric mantle, dominated by a volatile-free peridotite source. The calculated primary melt compositions suggest that the basalts formed at 1.9-2.1 GPa, with melting temperatures of 1378 °C-1405 °C and a mantle potential temperature (TP) ranging from 1383 °C to 1407 °C. The temperature range is somewhat hotter than normal mid-ocean-basalt (MORB) mantle but similar to an intra-plate continental mantle setting, such as the Basin and Range Province in western North America. This study provides an important constraint on the Early Jurassic mantle thermal state beneath South China. Reference: Raczek, I., Stoll, B., Hofmann, A.W., Jochum, K.P. 2001. High-precision trace element data for the USGS reference materials BCR-1, BCR-2, BHVO-1, BHVO-2, AGV-1, AGV-2, DTS-1, DTS-2, GSP-1 and GSP-2 by ID-TIMS and MIC-SSMS. Geostandards Newsletter 25(1), 77-86.

Chemical magnetization when determining Thellier paleointensity experiments in oceanic basalts

NASA Astrophysics Data System (ADS)

Tselebrovskiy, Alexey; Maksimochkin, Valery

2017-04-01

The natural remanent magnetization (NRM) of oceanic basalts selected in the rift zones of the Mid-Atlantic Ridge (MAR) and the Red Sea has been explored. Laboratory simulation shows that the thermoremanent magnetization and chemical remanent magnetization (CRM) in oceanic basalts may be separated by using Tellier-Coe experiment. It was found that the rate of CRM destruction is about four times lower than the rate of the partial thermoremanent magnetization formation in Thellier cycles. The blocking temperatures spectrum of chemical component shifted toward higher temperatures in comparison with the spectrum of primary thermoremanent magnetization. It was revealed that the contribution of the chemical components in the NRM increases with the age of oceanic basalts determined with the analysis of the anomalous geomagnetic field (AGF) and spreading theory. CRM is less than 10% at the basalts aged 0.2 million years, less than 50% at basalts aged 0.35 million years, from 60 to 80% at basalts aged 1 million years [1]. Geomagnetic field paleointensity (Hpl) has been determined through the remanent magnetization of basalt samples of different ages related to Brunhes, Matuyama and Gauss periods of the geomagnetic field polarity. The value of the Hpl determined by basalts of the southern segment of MAR is ranged from 17.5 to 42.5 A/m, by the Reykjanes Ridge basalts — from 20.3 to 44 A/m, by the Bouvet Ridge basalts — from 21.7 to 34.1 A/m. VADM values calculated from these data are in good agreement with the international paleointensity database [2] and PISO-1500 model [3]. Literature 1. Maksimochkin V., Tselebrovskiy A., (2015) The influence of the chemical magnetization of oceanic basalts on determining the geomagnetic field paleointensity by the thellier method, moscow university physics bulletin, 70(6):566-576, 2. Perrin, M., E. Schnepp, and V. Shcherbakov (1998), Update of the paleointensity database, Eos Trans. AGU, 79, 198. 3. Channell JET, Xuan C, Hodell DA (2009

Additive Construction using Basalt Regolith Fines

NASA Technical Reports Server (NTRS)

Mueller, Robert P.; Sibille, Laurent; Hintze, Paul E.; Lippitt, Thomas C.; Mantovani, James G.; Nugent, Matthew W.; Townsend, Ivan I.

2014-01-01

Planetary surfaces are often covered in regolith (crushed rock), whose geologic origin is largely basalt. The lunar surface is made of small-particulate regolith and areas of boulders located in the vicinity of craters. Regolith composition also varies with location, reflecting the local bedrock geology and the nature and efficiency of the micrometeorite-impact processes. In the lowland mare areas (suitable for habitation), the regolith is composed of small granules (20 - 100 microns average size) of mare basalt and volcanic glass. Impacting micrometeorites may cause local melting, and the formation of larger glassy particles, and this regolith may contain 10-80% glass. Studies of lunar regolith are traditionally conducted with lunar regolith simulant (reconstructed soil with compositions patterned after the lunar samples returned by Apollo). The NASA Kennedy Space Center (KSC) Granular Mechanics & Regolith Operations (GMRO) lab has identified a low fidelity but economical geo-technical simulant designated as Black Point-1 (BP-1). It was found at the site of the Arizona Desert Research and Technology Studies (RATS) analog field test site at the Black Point lava flow in adjacent basalt quarry spoil mounds. This paper summarizes activities at KSC regarding the utilization of BP-1 basalt regolith and comparative work with lunar basalt simulant JSC-1A as a building material for robotic additive construction of large structures. In an effort to reduce the import or in-situ fabrication of binder additives, we focused this work on in-situ processing of regolith for construction in a single-step process after its excavation. High-temperature melting of regolith involves techniques used in glassmaking and casting (with melts of lower density and higher viscosity than those of metals), producing basaltic glass with high durability and low abrasive wear. Most Lunar simulants melt at temperatures above 1100 C, although melt processing of terrestrial regolith at 1500 C is not

Architecture and emplacement of flood basalt flow fields: case studies from the Columbia River Basalt Group, NW USA

NASA Astrophysics Data System (ADS)

Vye-Brown, C.; Self, S.; Barry, T. L.

2013-03-01

The physical features and morphologies of collections of lava bodies emplaced during single eruptions (known as flow fields) can be used to understand flood basalt emplacement mechanisms. Characteristics and internal features of lava lobes and whole flow field morphologies result from the forward propagation, radial spread, and cooling of individual lobes and are used as a tool to understand the architecture of extensive flood basalt lavas. The features of three flood basalt flow fields from the Columbia River Basalt Group are presented, including the Palouse Falls flow field, a small (8,890 km2, ˜190 km3) unit by common flood basalt proportions, and visualized in three dimensions. The architecture of the Palouse Falls flow field is compared to the complex Ginkgo and more extensive Sand Hollow flow fields to investigate the degree to which simple emplacement models represent the style, as well as the spatial and temporal developments, of flow fields. Evidence from each flow field supports emplacement by inflation as the predominant mechanism producing thick lobes. Inflation enables existing lobes to transmit lava to form new lobes, thus extending the advance and spread of lava flow fields. Minimum emplacement timescales calculated for each flow field are 19.3 years for Palouse Falls, 8.3 years for Ginkgo, and 16.9 years for Sand Hollow. Simple flow fields can be traced from vent to distal areas and an emplacement sequence visualized, but those with multiple-layered lobes present a degree of complexity that make lava pathways and emplacement sequences more difficult to identify.

Sulfur in Hydrous, Oxidized Basaltic Magmas: Phase Equilibria and Melt Solubilities

NASA Astrophysics Data System (ADS)

Pichavant, M.; Scaillet, B.; di Carlo, I.; Rotolo, S.; Metrich, N.

2006-05-01

Basaltic magmas from subduction zone settings are typically S-rich and may be the ultimate source of sulfur in vapor phases emitted during eruptions of more silicic systems. To understand processes of sulfur recycling in subduction zones, the behaviour of S in hydrous, oxidized, mafic arc magmas must be known. Although experimental data on S-bearing basaltic melts are available for dry conditions, and under both reduced and oxidized fO2, no study has yet examined the effect of S in hydrous mafic melts. In this work, 3 starting compositions were investigated, a basaltic andesite, a K basalt and a picritic basalt. For each composition, experimental data for S-added (1 wt % elemental sulfur) and S-free charges were obtained under similar P-T- H2O-fO2. All experiments were performed at 4 kbar and at either 950 ° C (basaltic andesite), 1100 ° C (K basalt) or 1150 ° C (picritic basalt). These were carried out in an internally heated vessel pressurized with Ar-H2 mixtures and fitted with a drop-quench device, and lasted for between 15 and 99 h. Either Au (950 ° C) or AuPd alloys (1100 and 1150 ° C) were used as containers. These latter perform satisfactorily under strongly oxidizing conditions, i.e., for fO2 above NNO+1 at 1100 and 1150 ° C. Below NNO+1, Pd- Au-S-Fe phases appear in the charges, suggesting extensive interaction between S and the capsule material. Experimental redox conditions, determined from Ni-Pd-O sensors, ranged between NNO+1.3 to +4.1 (basaltic andesite), +0.6 to +2.0 (K basalt), and +0.3 to +3.6 (picritic basalt). H2O concentrations in melt ranged from 8.2 wt % (basaltic andesite), decreasing to 2.2-3.9 wt % (K basalt) and 2.5-5.0 wt % (picritic basalt). All 3 compositions studied crystallize anhydrite and Fe-Ni-S-O sulphide as saturating S-bearing phases, anhydrite at high fO2 and sulphide at lower fO2, although melt composition also influences their stability. Anhydrite is present at a fO2 as low as NNO+1.5 in the K basalt. In the picritic

Testing the Origins of Basalt Fragments fro Apollo 16

NASA Technical Reports Server (NTRS)

Donohue, P. H.; Stevens, R. E.; Neal, C. R.; Zeigler, R. A.

2013-01-01

Several 2-4 mm regolith fragments of basalt from the Apollo 16 site were recently described by [1]. These included a high-Ti vitrophyric basalts (60603,10-16) and one very-low-titanium (VLT) crystalline basalt (65703,9-13). As Apollo 16 was the only highlands sample return mission distant from the maria, identification of basaltic samples at the site indicates input from remote sites via impact processes [1]. However, distinguishing between impact melt and pristine basalt can be notoriously difficult and requires significant sample material [2-6]. The crystal stratigraphy method utilizes essentially non-destructive methods to make these distinctions [7,8]. Crystal stratigraphy combines quantitative petrography in the form of crystal size distributions (CSDs) coupled with mineral geochemistry to reveal the petrogenetic history of samples. The classic CSD plot of crystal size versus population density can reveal insights on growth/cooling rates, residence times, and magma history which in turn can be used to evaluate basaltic vs impact melt origin [7-9]. Electron microprobe (EMP) and laser ablation (LA)-ICP-MS analyses of mineral phases complement textural investigations. Trace element variations document subtle changes occurring during the formation of the samples, and are key in the interpretation and preservation of this rare lunar sample collection.

Experimental investigation of the reaction between corundum xenocrysts and alkaline basaltic host magma: Constraints on magma residence times of basalt-hosted sapphires

NASA Astrophysics Data System (ADS)

Baldwin, L. C.; Ballhaus, C.

2018-03-01

Megacrystic sapphires (Fe-Ti-rich corundum) of up to 5 cm in size are well known from alkaline mafic rocks from intra-continental rift-related magmatic fields. There is no doubt that these sapphires represent xenocrysts that were trapped from their original lithology by ascending basaltic magmas carrying them to the Earth's surface. Most studies about basalt-hosted sapphires address the question about the origin of the sapphires, but there is hardly any information available about the time the sapphires resided inside the carrier melt. Sapphires are in reaction relationship with basalt and produce spinel coronas at the sapphire-basalt interface, spatially separating the mutually incompatible phases from one another. Assuming isothermal and isobaric conditions of spinel rim formation, the rim-thickness should be a function of the reaction time with the basaltic melt. In this paper, we report time-series experiments aimed at investigating the kinetics of spinel rim formation due to igneous corrosion of corundum. Therefore, we reacted corundum fragments with alkaline basalt powder at 1250 °C and 1GPa, using a Piston Cylinder Apparatus. The width of the spinel rim was used to estimate a residence time. Extrapolating the experimentally derived reaction rates to the thickness of natural spinel rims as described from the Siebengebirge Volcanic Field, Germany, and from Changle, China, we estimated residence times in the order of a few weeks to months.

Scarification of basalt milkvetch (Astragalus filipes) seed for improved emergence

Treesearch

Clinton C. Shock; Erik Feibert; Lamont D. Saunders

2008-01-01

Basalt milkvetch (Astragalus nlipes) is a forb (non woody perennial) native to western North America. Basalt milkvetch is a legume forb species of interest for revegetating rangelands of the intermountain northwest; it can contribute high quality feed, valuable seed for wildlife, and nitrogen fixation to help maintain range productivity. Basalt milkvetch has a hard...

Basalt fiber reinforced polymer composites: Processing and properties

NASA Astrophysics Data System (ADS)

Liu, Qiang

A high efficiency rig was designed and built for in-plane permeability measurement of fabric materials. A new data derivation procedure to acquire the flow fluid pattern in the experiment was developed. The measurement results of the in-plane permeability for basalt twill 31 fabric material showed that a high correlation exists between the two principal permeability values for this fabric at 35% fiber volume fraction. This may be the most important scientific contribution made in this thesis. The results from radial measurements corresponded quite well with those from Unidirectional (UD) measurements, which is a well-established technique. No significant differences in mechanical properties were found between basalt fabric reinforced polymer composites and glass composites reinforced by a fabric of similar weave pattern. Aging results indicate that the interfacial region in basalt composites may be more vulnerable to environmental damage than that in glass composites. However, the basalt/epoxy interface may have been more durable than the glass/epoxy interface in tension-tension fatigue because the basalt composites have significantly longer fatigue life. In this thesis, chapter I reviews the literature on fiber reinforced polymer composites, with concentration on permeability measurement, mechanical properties and durability. Chapter II discusses the design of the new rig for in-plane permeability measurement, the new derivation procedure for monitoring of the fluid flow pattern, and the permeability measurement results. Chapter III compares the mechanical properties and durability between basalt fiber and glass fiber reinforced polymer composites. Lastly, chapter IV gives some suggestions and recommendations for future work.

Aqueous Alteration of Basaltic Glass Under a Simulated Mars Atmosphere

NASA Technical Reports Server (NTRS)

Bullock, M. A.; Moore, J. M.

2005-01-01

For the past several years we have been performing experiments designed to produce brines under Mars-simulated conditions. Previously, we had generated and analyzed Mars-analog brines by allowing a mixture of minerals derived from SNC mineralogy to soak in pure water under a synthetic current-Mars atmosphere and under a gas similar to the present Mars atmosphere but with added acidic gases. The latest version of these experiments incubates basaltic glass, obtained from recent Kilauea flows (Mother's Day flow in December 2002), in pure water under a present-day Mars analog atmosphere at 25 C. This abstract and our presentation will discuss the composition of these Mars-analog brines and implications for Mars surface chemistry.

[Comparative carcinogenic properties of basalt fiber and chrysotile-asbestos].

PubMed

Nikitina, O V; Kogan, F M; Vanchugova, N N; Frash, V N

1989-01-01

In order to eliminate asbestos adverse effect on workers' health it was necessary to use mineral rayon, primarily basalt fibre, instead of asbestos. During a chronic experiment on animals the oncogenicity of 2 kinds of basalt fibre was studied compared to chrysotile asbestos. The dust dose of 25 mg was twice administered by intraperitonial route. All types of dust induced the onset of intraperitonial mesotheliomas but neoplasm rates were significantly lower in the groups exposed to basalt fibre. There was no credible data on the differences between the groups exposed to various types of basalt fibre. Since the latter produced some oncogenic effect, it was necessary to develop a complex of antidust measures, fully corresponding to the measures adopted for carcinogenic dusts.

Carbon isotope and abundance systematics of Icelandic geothermal gases, fluids and subglacial basalts with implications for mantle plume-related CO2 fluxes

NASA Astrophysics Data System (ADS)

Barry, P. H.; Hilton, D. R.; Füri, E.; Halldórsson, S. A.; Grönvold, K.

2014-06-01

We report new carbon dioxide (CO2) abundance and isotope data for 71 geothermal gases and fluids from both high-temperature (HT > 150 °C at 1 km depth) and low-temperature (LT < 150 °C at 1 km depth) geothermal systems located within neovolcanic zones and older segments of the Icelandic crust, respectively. These data are supplemented by CO2 data obtained by stepped heating of 47 subglacial basaltic glasses collected from the neovolcanic zones. The sample suite has been characterized previously for He-Ne (geothermal) and He-Ne-Ar (basalt) systematics (Füri et al., 2010), allowing elemental ratios to be calculated for individual samples. Geothermal fluids are characterized by a wide range in carbon isotope ratios (δ13C), from -18.8‰ to +4.6‰ (vs. VPDB), and CO2/3He values that span eight orders of magnitude, from 1 × 104 to 2 × 1012. Extreme geothermal values suggest that original source compositions have been extensively modified by hydrothermal processes such as degassing and/or calcite precipitation. Basaltic glasses are also characterized by a wide range in δ13C values, from -27.2‰ to -3.6‰, whereas CO2/3He values span a narrower range, from 1 × 108 to 1 × 1012. The combination of both low δ13C values and low CO2 contents in basalts indicates that magmas are extensively and variably degassed. Using an equilibrium degassing model, we estimate that pre-eruptive basaltic melts beneath Iceland contain ∼531 ± 64 ppm CO2 with δ13C values of -2.5 ± 1.1‰, in good agreement with estimates from olivine-hosted melt inclusions (Metrich et al., 1991) and depleted MORB mantle (DMM) CO2 source estimates (Marty, 2012). In addition, pre-eruptive CO2 compositions are estimated for individual segments of the Icelandic axial rift zones, and show a marked decrease from north to south (Northern Rift Zone = 550 ± 66 ppm; Eastern Rift Zone = 371 ± 45 ppm; Western Rift Zone = 206 ± 24 ppm). Notably, these results are model dependent, and selection of a lower

Mars Crust: Made of Basalt

NASA Astrophysics Data System (ADS)

Taylor, G. J.

2009-05-01

By combining data from several sources, Harry Y. (Hap) McSween (University of Tennessee), G. Jeffrey Taylor (University of Hawaii) and Michael B. Wyatt (Brown University) show that the surface of Mars is composed mostly of basalt not unlike those that make up the Earth's oceanic crust. McSween and his colleagues used data from Martian meteorites, analyses of soils and rocks at robotic landing sites, and chemical and mineralogical information from orbiting spacecraft. The data show that Mars is composed mostly of rocks similar to terrestrial basalts called tholeiites, which make up most oceanic islands, mid-ocean ridges, and the seafloor beneath sediments. The Martian samples differ in some respects that reflect differences in the compositions of the Martian and terrestrial interiors, but in general are a lot like Earth basalts. Cosmochemistst have used the compositions of Martian meteorites to discriminate bulk properties of Mars and Earth, but McSween and coworkers' synthesis shows that the meteorites differ from most of the Martian crust (the meteorites have lower aluminum, for example), calling into question how diagnostic the meteorites are for understanding the Martian interior.

Similar microbial communities found on two distant seafloor basalts

NASA Astrophysics Data System (ADS)

Singer, E.; Chong, L. S.; Heidelberg, J. F.; Edwards, K. J.

2016-12-01

The oceanic crust forms two thirds of the Earth's surface and hosts a large phylogenetic and functional diversity of microorganisms. While advances have been made in the sedimentary realm, our understanding of the igneous rock portion as a microbial habitat has remained limited. We present a comparative metagenomic microbial community analysis from ocean floor basalt environments at the Lō'ihi Seamount, Hawai'i, and the East Pacific Rise (EPR) (9°N). Phylogenetic analysis indicates the presence of a total of 43 bacterial and archaeal mono-phyletic groups, dominated by Alpha- and Gammaproteobacteria, as well as Thaumarchaeota. Functional gene analysis suggests that these Thaumarchaeota play an important role in ammonium oxidation on seafloor basalts. In addition to ammonium oxidation, the seafloor basalt habitat reveals a wide spectrum of other metabolic potentials, including CO2 fixation, denitrification, dissimilatory sulfate reduction, and sulfur oxidation. Basalt communities from Lō'ihi and the EPR show considerable metabolic and phylogenetic overlap down to the genus level despite geographic distance and slightly different seafloor basalt mineralogy.

Petrogenesis of an Early Cretaceous lamprophyre dike from Kyoto Prefecture, Japan: Implications for the generation of high-Nb basalt magmas in subduction zones

NASA Astrophysics Data System (ADS)

Imaoka, Teruyoshi; Kawabata, Hiroshi; Nagashima, Mariko; Nakashima, Kazuo; Kamei, Atsushi; Yagi, Koshi; Itaya, Tetsumaru; Kiji, Michio

2017-10-01

We studied a 107 Ma vogesite (a kind of lamprophyre with alkali-feldspar > plagioclase, and hornblende ± clinopyroxene ± biotite) dike in the Kinki district of the Tamba Belt, Kyoto Prefecture, SW Japan, using petrography, mineralogy, K-Ar ages, and geochemistry to evaluate its petrogenesis and tectonic implications. The dike has the very specific geochemical characteristics of a primitive high-Mg basalt, with 48-50 wt.% SiO2 (anhydrous basis), high values of Mg# (67.3-72.4), and high Cr ( 431 ppm), Ni ( 371 ppm), and Co ( 52 ppm) contents. The vogesite is alkaline and ne-normative with high concentrations of large ion lithophile elements (LILEs: Sr = 1270-2200 ppm, Ba = 3910-26,900 ppm), light rare earth elements (LREEs) [(La/Yb)n = 58-62), and high field strength elements (HFSEs: TiO2 = 1.5-1.8 wt.%, Nb = 24-33 ppm, Zr = 171-251 ppm), and the vogesite can be classified as a high-Nb basalt (HNB). The vogesite was formed by the lowest degree of melting of metasomatized mantle in the garnet stability field, and it may also have been formed at higher melting pressures than other Kyoto lamprophyres. The low degree of melting is the primary reason for the high-Nb content of the vogesite, not mantle metasomatism, and a higher degree of melting would have changed the primary magma composition from a HNB to a Nb-enriched basalt (NEB). The vogesite magma was contaminated at an early stage of its development by melts derived from sediments drawn down a subduction zone, as indicated by some geochemical indices and the initial Nd isotope ratios. The vogesite exhibits positive correlations between εSr(107 Ma) values (5.4-50.9) and its high Ba and Sr concentrations, and it has a limited range of εNd(107 Ma) values (+ 0.97 to + 2.4). The fact that the vogesite contains centimeter-sized xenoliths of chert, which are composed of polycrystalline quartz, calcite, barite, pyrite, and magnetite, indicates that the barium contamination took place during the ascent of the

Distribution and stratigraphy of basaltic units in Maria Tranquillitatis and Fecunditatis: A Clementine perspective

NASA Technical Reports Server (NTRS)

Rajmon, D.; Spudis, P.

2004-01-01

Maria Tranquillitatis and Fecunditatis have been mapped based on Clementine image mosaics and derived iron and titanium maps. Impact craters served as stratigraphic probes enabling better delineation of compositionally different basaltic units, determining the distribution of subsurface basalts, and providing estimates of total basalt thickness and the thickness of the surface units. Collected data indicate that volcanism in these maria started with the eruption of low-Ti basalts and evolved toward medium- and high-Ti basalts. Some of the high-Ti basalts in Mare Tranquillitatis began erupting early and were contemporaneous with the low- and medium-Ti basalts; these units form the oldest units exposed on the mare surface. Mare Tranquillitatis is mostly covered with high- Ti basalts. In Mare Fecunditatis, the volume of erupting basalts clearly decreased as the Ti content increased, and the high-Ti basalts occur as a few patches on the mare surface. The basalt in both maria is on the order of several hundred meters thick and locally may be as thick as 1600 m. The new basalt thickness estimates generally fall within the range set by earlier studies, although locally differ. The medium- to high-Ti basalts exposed at the surfaces of both maria are meters to tens of meters thick.

Project Hotspot: Temporal Compositional Variation in Basalts of the Kimama Core and Implications for Magma Source Evolution, Snake River Scientific Drilling Project, Idaho

NASA Astrophysics Data System (ADS)

Potter, K. E.; Shervais, J. W.; Champion, D.; Duncan, R. A.; Christiansen, E. H.

2012-12-01

, evolved lava flows (FeOT 17.2 and 17.0 wt %; TiO2 4.20 and 4.09 wt %, respectively) of negative polarity are stratigraphically bounded by more primitive tholeittic lava flows (FeOT 13.6 and 14.5 wt %; TiO2 2.92 and 3.24 wt %, respectively) of positive polarity, a chronological transition that may represent many millennia and magma source variability. Kimama core stratigraphy as well as paleomagnetic, and radiometric age data demonstrate that mafic volcanism on the central Snake River Plain has been relatively continuous for the last 6.5 Ma. The compositional variability in Kimama basalts introduces broader implications for the timing of cyclic fractionation processes and the development of regional magma sources.

Crystallization of oxidized, moderately hydrous arc basalt at mid-to-lower crustal pressures

NASA Astrophysics Data System (ADS)

Blatter, D. L.; Sisson, T. W.; Hankins, W. B.

2012-12-01

basalts to rhyolites or granites (ASI/wt% SiO2: 0.012-0.014), and do not commonly become peraluminous until SiO2 exceeds 69 wt%. These relations are consistent with plagioclase accompanying mafic silicates during nearly all evolution of arc magmas, with little or no early crystallization interval dominated by augite, unlike these and other high-pressure crystallization results. Possible implications are: (1) Parental basaltic arc magmas generally have <3 wt% H2O, and so saturate with plagioclase earlier than in these and other investigators' experiments, (2) These and other investigators' basaltic starting compositions have appropriate H2O but insufficient normative plagioclase, and so crystallize excessive augite before saturating with plagioclase, (3) Common parental arc magmas are basaltic andesites, not basalts, and undergo early crystallization dominated by orthopyroxene that does not modify melt ASI, and/or (4) The spectrum of common arc magma compositions is dominantly due to mixing of mafic magmas with evolved crustal melts or residual liquids that are saturated with plagioclase, thereby causing the coupled and consistent increase in SiO2 with ASI. What can be stated with confidence is that the simple case of deep crystallization-differentiation of hydrous basalt produces daughter liquids that differ in important aspects from common arc magmas.

Rhyolite, dacite, andesite, basaltic andesite, and basalt volcanism on the Alarcon Rise spreading-center, Gulf of California

NASA Astrophysics Data System (ADS)

Dreyer, B. M.; Portner, R. A.; Clague, D. A.; Castillo, P. R.; Paduan, J. B.; Martin, J. F.

2012-12-01

The Alarcon Rise is a ~50 km long intermediate-rate (~50mm/a) spreading segment at the southern end of the Gulf of California. The Rise is bounded by the Tamayo and Pescadero transforms to the south and north. In Spring 2012, an MBARI-led expedition mapped a ~1.5- 3km wide swath of the ridge axis at 1-m resolution and completed 9 ROV dives (Clague et al., this session). Sampling during the ROV dives was supplemented by use of a wax-tip corer to recover volcanic glass: 194 glassy lava samples were recovered from the Rise. The vast majority of lava flows along the axis are basalt and rare basaltic andesite. More than half the basalts are plagioclase-phyric to ultraphyric (Martin et al., this session), and the rest are aphyric. Rare samples also include olivine or olivine and clinopyroxene phenocrysts. Analyses of half of the recovered glass basalt rinds range in MgO from 4.3 to 8.5 wt.% and those with MgO > 6 wt % have K2O/TiO2 = 0.07-0.11. The basalts are broadly characterized as normal mid-ocean ridge basalts (N-MORB). E-MORB is also present near the center of the ridge segment, but has been found only as pyroclasts in sediment cores. A much greater range in lava composition is associated with an unusual volcanic dome-like edifice that lies ~9 km south of the Pescadero transform. Two dives in the vicinity of the dome collected lava and volcaniclastic samples consisting of moderately to sparsely phyric light brown to colorless volcanic glass. Feldspar is the dominant phase, but magnetite, fayalitic olivine, light tan and light green clinopyroxene, orthopyroxene, zircon, and rare pyrite blebs also occur. Melt-inclusions are common in many phenocrysts, especially of plagioclase. Hydrous mineral phases are not observed. These samples have rhyolitic glass compositions (75.8- 77.4 SiO2 wt %), but their whole-rock compositions will be somewhat less silicic. Pillow flows to the immediate west have dacitic glass compositions (67.4- 68.8 wt % SiO2). Basaltic andesitic

Aquifers and Their Tectonic Connectivity in Flood Basalts Using AEM

NASA Astrophysics Data System (ADS)

Chandra, S.; Auken, E.; Sonkamble, S.; Maurya, P. K.; Ahmed, S.; Clausen, O. R.; Verma, S. K.

2016-12-01

Aquifers, the major freshwater storage providing water for human consumption, agriculture, industry and groundwater-dependent ecosystems, are subjected to increasing stress resulting into drying up of large number of wells in major parts of world. The climate change with erratic rainfall pattern and increasing temperature enhances the rate of evapotranspiration causing reduction in groundwater recharge as well as enhancement in the groundwater withdrawal. Not only the wells, but also springs, ponds and non glacial rivers, mostly fed by base flow during non-monsoon periods, also go dry during droughts. Water crisis is very severe in the basaltic and hard rock areas in India where the weathered zone, principal aquifer, has almost dried up and the water is mostly confined within the underlying vesicular and weathered-fractured basalts, and occasionally within green bole beds. The paper presents results from Basaltic hard rock terrains in India based on integrated geophysical surveys including airborne electromagnetic (AEM) and airborne magnetic methods. Due to good resistivity contrasts, AEM results showed strong signatures of multiple basaltic flows, their alterations and associated major intertrappeans. In combination with ground geophysics, geological and borehole information, AEM was found to be very effective in mapping the multiple flows, Gondwana and basaltic interface, and inter- and infra-trappeans (Figure 1). In addition to the basaltic flows, we could map the tectonic groundwater pathways, which is a completely new knowledge. The tectonic pathways connect different aquifers (water saturated vesicular basalt) located in various flows. The results demonstrate that the AEM is very effective for groundwater prospecting in basalts and in delineating suitable recharge zones to create strategic groundwater reserves.

The radiogenic and stable Sr isotope geochemistry of basalt weathering in Iceland: Role of hydrothermal calcite and implications for long-term climate regulation

NASA Astrophysics Data System (ADS)

Andrews, M. Grace; Jacobson, Andrew D.

2017-10-01

Several studies have examined the geochemistry of Icelandic rivers to quantify the relationship between basalt weathering and long-term climate regulation. Recent research has suggested that the chemical weathering of hydrothermal and metamorphic calcite contributes significant quantities of HCO3- to the Icelandic riverine flux (Jacobson et al., 2015). Because the HCO3- derives from volcanic CO2 that was sequestered in mineral form prior to atmospheric injection, the strength of the basalt weathering feedback occurring in Iceland may be lower than previously realized. To test these hypotheses, we analyzed the radiogenic and stable Sr isotope composition (87Sr/86Sr and δ88/86Sr) of the same suite of water, rock, and mineral samples as examined in Jacobson et al. (2015), and we developed a simple model of the long-term C cycle that considers the transformation of volcanic CO2 to HCO3- during subsurface silicate weathering, which is a precursor to hydrothermal calcite formation. Interpretations based on 87Sr/86Sr and Ca/Sr ratios suggest that conservative, three-component mixing between basalt, calcite, and atmospheric deposition adequately explains river geochemistry. On average, the δ88/86Sr values of glacial and non-glacial rivers (0.414‰ and 0.388‰, respectively) are generally higher than those for basalt (0.276‰); however, calcite δ88/86Sr values (0.347‰) are also higher than those for basalt and span the range of riverine values. Thus, riverine δ88/86Sr values are also consistent three-component mixing between basalt, calcite, and atmospheric deposition. Isotopic fractionation is not required to explain riverine trends. Finally, model equations for the long-term C cycle demonstrate that subsurface silicate weathering reduces the magnitude of the volcanic CO2 degassing flux, which in turn causes the atmosphere to stabilize at lower pCO2 values compared to the case where no subsurface silicate weathering occurs. However, the proportion of the net

Is formation segregation melts in basaltic lava flows a viable analogue to melt generation in basaltic systems?

NASA Astrophysics Data System (ADS)

Thordarson, Thorvaldur; Sigmarsson, Olgeir; Hartley, Margaret E.; Miller, Jay

2010-05-01

Pahoehoe sheet lobes commonly exhibit a three-fold structural division into upper crust, core and lower crust, where the core corresponds to the liquid portion of an active lobe sealed by crust. Segregations are common in pahoehoe lavas and are confined to the core of individual lobes. Field relations and volume considerations indicate that segregation is initiated by generation of volatile-rich melt at or near the lower crust to core boundary via in-situ crystallization. Once buoyant, the segregated melt rises through the core during last stages of flow emplacement and accumulates at the base of the upper crust. The segregated melt is preserved as vesicular and aphyric, material within well-defined vesicle cylinders and horizontal vesicle sheets that make up 1-4% of the total lobe volume. We have undertaken a detailed sampling and chemical analysis of segregations and their host lava from three pahoehoe flow fields; two in Iceland and one in the Columbia River Basalt Group (CRBG). The Icelandic examples are: the olivine-tholeiite Thjorsa lava (24 cubic km) of the Bardarbunga-Veidivotn volcanic system and mildly alkalic Surtsey lavas (1.2 cubic km) of the Vestmannaeyjar volcanic system. The CRBG example is the tholeiitic ‘high-MgO group' Levering lava (>100? cubic km) of the N2 Grande Ronde Basalt. The thicknesses of the sampled lobes ranges from 2.3 to 14 m and each lobe feature well developed network of segregation structures [1,2,3]. Our whole-rock analyses show that the segregated melt is significantly more evolved than the host lava, with enrichment factors of 1.25 (Thjorsa) to 2.25 (Surtsey) for incompatible trace elements (Ba, Zr). Calculations indicate that the segregation melt was formed by 20 to 50% closed-system fractional crystallization of plagioclase (plus minor pyroxene and/or olivine). A more striking feature is the whole-rock composition of the segregations. In the olivine-tholeiite Thjorsa lava the segregations exhibit quartz tholeiite

The cooling of terrestrial basaltic lava flows and implications for lava flow emplacement on Venus from surface morphology and radar data

NASA Astrophysics Data System (ADS)

Hultgrien, Lynn Kerrell

Basalt is the most common surface rock on the terrestrial planets. Understanding the emplacement mechanisms for basaltic lava flows facilitates study of the geologic history of a planet and in volcanic hazards assessment. Lava flow cooling is examined through two different models, one applicable to aa and the second to pahoehoe. Occurrence of these basaltic flow types is evaluated in an extensive global survey of lava flows on Venus using Magellan data. First, a basic heat balance model is considered for as flow cooling with terms for conduction, radiation, viscous dissipation and entrainment of cooler material. Pahoehoe cooling is modeled through three different analytic solutions to the one-dimensional, time-dependent heat conduction equation, with constant surface temperature, linear heat transfer at the surface, and surface radiation. The models are compared with thermal data from the Hawaiian 1984 Mauna Loa and 1990 Puu Oo-Kupaianaha, Kilauea eruptions, for as and pahoehoe, respectively. Although commonly omitted in other models, heat conduction is found here to be important in the cooling of both aa and pahoehoe. Equally important is entrainment in as flows and both radiation and atmospheric convection for pahoehoe cooling. Morphology measurements and surface properties are determined for ninety individual lava flows from forty-four volcanic features on Venus. Radar backscatter and rms slope values, relative to terrestrial studies, indicate Venusian lavas are predominately pahoehoe. Emissivities and dielectric constants are consistent with basalt as the principal lithology. Effusion rates and flow velocities, determined using Earth-calibrated parametric relationships, and lava flow dimensions are greater than those found on Earth. Modeling lava flows on the terrestrial planets should involve careful consideration of the type of lava flow being studied. This investigation finds that heat conduction is an important limitation in the ability of a basalt flow to

Diffusion of hydrous species in model basaltic melt

NASA Astrophysics Data System (ADS)

Zhang, Li; Guo, Xuan; Wang, Qinxia; Ding, Jiale; Ni, Huaiwei

2017-10-01

Water diffusion in Fe-free model basaltic melt with up to 2 wt% H2O was investigated at 1658-1846 K and 1 GPa in piston-cylinder apparatus using both hydration and diffusion couple techniques. Diffusion profiles measured by FTIR are consistent with a model in which both molecular H2O (H2Om) and hydroxyl (OH) contribute to water diffusion. OH diffusivity is roughly 13% of H2Om diffusivity, showing little dependence on temperature or water concentration. Water diffusion is dominated by the motion of OH until total H2O (H2Ot) concentration reaches 1 wt%. The dependence of apparent H2Ot diffusivity on H2Ot concentration appears to be overestimated by a previous study on MORB melt, but H2Ot diffusivity at 1 wt% H2Ot in basaltic melt is still greater than those in rhyolitic to andesitic melts. The appreciable contribution of OH to water diffusion in basaltic melt can be explained by enhanced mobility of OH, probably associated with the development of free hydroxyl bonded with network-modifying cations, as well as higher OH concentration. Calculation based on the Nernst-Einstein equation demonstrates that OH may serve as an effective charge carrier in hydrous basaltic melt, which could partly account for the previously observed strong influence of water on electrical conductivity of basaltic melt.

CO 2 Mineral Sequestration in Naturally Porous Basalt

DOE Office of Scientific and Technical Information (OSTI.GOV)

Xiong, Wei; Wells, Rachel K.; Horner, Jake A.

2018-02-27

Continental flood basalts are extensive geologic features currently being evaluated as reservoirs that are suitable for long-term storage of carbon emissions. Favorable attributes of these formations for containment of injected carbon dioxide (CO2) include high mineral trapping capacity, unique structural features, and enormous volumes. We experimentally investigated mineral carbonation in whole core samples retrieved from the Grand Ronde basalt, the same formation into which ~1000 t of CO2 was recently injected in an eastern Washington pilot-scale demonstration. The rate and extent of carbonate mineral formation at 100 °C and 100 bar were tracked via time-resolved sampling of bench-scale experiments. Basaltmore » cores were recovered from the reactor after 6, 20, and 40 weeks, and three-dimensional X-ray tomographic imaging of these cores detected carbonate mineral formation in the fracture network within 20 weeks. Under these conditions, a carbon mineral trapping rate of 1.24 ± 0.52 kg of CO2/m3 of basalt per year was estimated, which is orders of magnitude faster than rates for deep sandstone reservoirs. On the basis of these calculations and under certain assumptions, available pore space within the Grand Ronde basalt formation would completely carbonate in ~40 years, resulting in solid mineral trapping of ~47 kg of CO2/m3 of basalt.« less

Clinopyroxene dissolution in basaltic melt

NASA Astrophysics Data System (ADS)

Chen, Yang; Zhang, Youxue

2009-10-01

The history of magmatic systems may be inferred from reactions between mantle xenoliths and host basalt if the thermodynamics and kinetics of the reactions are quantified. To study diffusive and convective clinopyroxene dissolution in silicate melts, diffusive clinopyroxene dissolution experiments were conducted at 0.47-1.90 GPa and 1509-1790 K in a piston-cylinder apparatus. Clinopyroxene saturation is found to be roughly determined by MgO and CaO content. The effective binary diffusivities, DMgO and DCaO, and the interface melt saturation condition, C0MgO×C0CaO, are extracted from the experiments. DMgO and DCaO show Arrhenian dependence on temperature. The pressure dependence is small and not resolved within 0.47-1.90 GPa. C0MgO×C0CaO in the interface melt increases with increasing temperature, but decreases with increasing pressure. Convective clinopyroxene dissolution, where the convection is driven by the density difference between the crystal and melt, is modeled using the diffusivities and interface melt saturation condition. Previous studies showed that the convective dissolution rate depends on the thermodynamics, kinetics and fluid dynamics of the system. Comparing our results for clinopyroxene dissolution to results from a previous study on convective olivine dissolution shows that the kinetic and fluid dynamic aspects of the two minerals are quite similar. However, the thermodynamics of clinopyroxene dissolution depends more strongly on the degree of superheating and composition of the host melt than that of olivine dissolution. The models for clinopyroxene and olivine dissolution are tested against literature experiments on mineral-melt interaction. They are then applied to previously proposed reactions between Hawaii basalts and mantle minerals, mid-ocean ridge basalts and mantle minerals, and xenoliths digestion in a basalt at Kuandian, Northeast China.

High-Mg subduction-related Tertiary basalts in Sardinia, Italy

NASA Astrophysics Data System (ADS)

Morra, V.; Secchi, F. A. G.; Melluso, L.; Franciosi, L.

1997-03-01

The Oligo-Miocene volcanics (32-15 Ma), which occur in the Oligo-Miocene Sardinian Rift, were interpreted in the literature as an intracontinental volcanic arc built upon continental crust about 30 km thick. They are characterized by a close field association of dominantly andesites and acid ignimbrites, with subordinate basalts. In this paper we deal with the origin and evolution of recently discovered high-magnesia basalts aged ca. 18 Ma occurring in the Montresta area, northern Sardinia, relevant to the petrogenesis of the Cenozoic volcanics of Sardinia. The igneous rocks of the Montresta area form a tholeiitic, subduction-related suite. Major-element variation from the high-magnesia basalts (HMB) to high-alumina basalts (HAB) are consistent with crystal/liquid fractionation dominated by olivine and clinopyroxene. Proportions of plagioclase and titanomagnetite increase from HAB to andesites. Initial {87Sr }/{86Sr } ratios increase with differentiation from 0.70398 for the HMB to 0.70592 for the andesites. This suggests concomitant crustal contamination. The geochemical characteristics of the high-magnesia basalts are typical of subduction-related magmas, with negative Nb, Zr and Ti spikes in mantle-normalized diagrams. It is proposed that these high-magnesia basalts were produced by partial melting of a mantle source characterized by large-ion lithophile elements (LILE) enrichment related principally to dehydration of subducted oceanic crust. Chondrite-normalized rare earth elements (REE) patterns indicate that the lavas are somewhat enriched in light rare earth elements (LREE), with flat heavy rare earth elements (HREE) patterns. This evidence is consistent with a spinel-bearing mantle source. The sub-parallel chondrite-normalized patterns show enrichment with differentiation, with a greater increase of LREE than HREE. The occurrence of high-magnesia basalts at 18 Ma in Sardinia appears to be correlated with and favoured by pronounced extensional tectonics at

The Influence of Conduit Processes During Basaltic Plinian Eruptions.

NASA Astrophysics Data System (ADS)

Houghton, B. F.; Sable, J. E.; Wilson, C. J.; Coltelli, M.; Del Carlo, P.

2001-12-01

Basaltic volcanism is most typically thought to produce effusion of lava, with the most explosive manifestations ranging from mild Strombolian activity to more energetic fire fountain eruptions. However, some basaltic eruptions are now recognized as extremely violent, i.e. generating widespread phreatomagmatic, subplinian and Plinian fall deposits. These eruptions are particularly dangerous because the ascent rate of basaltic magma prior to eruption can be very rapid (giving warning times as little as a few hours) and because their precursors may be ignored or misunderstood. The main question addressed in this talk is: what conditions in the conduit cause basaltic magma to adopt an eruption style more typical of chemically evolved, highly viscous magmas? Possible mechanisms (acting singly, or in concert) are: (1) interaction between magma and water, (ii) very rapid ascent producing a delayed onset of degassing then exceptionally rapid "runaway" vesiculation at shallow levels in the conduit, (iii) microlite crystallization and degassing of the magma during ascent leading to increased viscosity. We focus here on two examples of basaltic Plinian volcanism: the 1886 eruption of Tarawera, New Zealand, which is the youngest known basaltic Plinian eruption and the only one for which there are detailed written eyewitness accounts, and the well documented 122 BC eruption of Mount Etna, Italy. Field and laboratory evidence suggests that the Plinian phase of the 1886 eruption was a consequence of two processes. Firstly rheologic changes during magma ascent accompanied early (pre-fragmentation) interaction between the basaltic melt and water-bearing rhyolitic units forming the conduit walls and, secondly, late-stage magma:water interaction. In contrast, during the 122 BC eruption tectonic processes, such as slope failure or permanent displacement of a mobile flank of the volcano, appear to have triggered exceptionally rapid ascent, delayed onset of degassing and exceptionally

Plate tectonics and continental basaltic geochemistry throughout Earth history

NASA Astrophysics Data System (ADS)

Keller, Brenhin; Schoene, Blair

2018-01-01

Basaltic magmas constitute the primary mass flux from Earth's mantle to its crust, carrying information about the conditions of mantle melting through which they were generated. As such, changes in the average basaltic geochemistry through time reflect changes in underlying parameters such as mantle potential temperature and the geodynamic setting of mantle melting. However, sampling bias, preservation bias, and geological heterogeneity complicate the calculation of representative average compositions. Here we use weighted bootstrap resampling to minimize sampling bias over the heterogeneous rock record and obtain maximally representative average basaltic compositions through time. Over the approximately 4 Ga of the continental rock record, the average composition of preserved continental basalts has evolved along a generally continuous trajectory, with decreasing compatible element concentrations and increasing incompatible element concentrations, punctuated by a comparatively rapid transition in some variables such as La/Yb ratios and Zr, Nb, and Ti abundances approximately 2.5 Ga ago. Geochemical modeling of mantle melting systematics and trace element partitioning suggests that these observations can be explained by discontinuous changes in the mineralogy of mantle partial melting driven by a gradual decrease in mantle potential temperature, without appealing to any change in tectonic process. This interpretation is supported by the geochemical record of slab fluid input to continental basalts, which indicates no long-term change in the global proportion of arc versus non-arc basaltic magmatism at any time in the preserved rock record.

Magnesium Isotopic Compositions of Continental Basalts From Various Tectonic Settings

NASA Astrophysics Data System (ADS)

Yang, W.; Li, S.; Tian, H.; Ke, S.

2016-12-01

Recycled sedimentary carbonate through subduction is the main light Mg isotopic reservoir in Earth's deep interior, thus Mg isotopic variation of mantle-derived melts provides a fresh perspective on investigating deep carbon cycling. Here we investigate Mg isotopic compositions of continental basalts from various tectonic settings: (1) The Cenozoic basalts from eastern China, coinciding with the stagnant Pacific slab in the mantle transition zone revealed by seismic tomography; (2) The Cenozoic basalts from Tengchong area, southwestern China, which comprises a crucial part of the collision zone between the Indian and Eurasian plates; (3) The Permian basalts from Emeishan large igneous province, related to a mantle plume. The Cenozoic basalts from both eastern China and Tengchong area exhibit light Mg isotopic compositions (δ26Mg = -0.60 to -0.30‰ and -0.51 to -0.33‰), suggesting recycled sedimentary carbonates in their mantle sources. This is supported by their low Fe/Mn, high CaO/Al2O3, low Hf/Hf* and low Ti/Ti* ratios, which are typical features of carbonated peridotite-derived melt. The Tengchong basalts also show high 87Sr/86Sr, high radiogenic Pb and upper crustal-like trace element pattern, indicating contribution of recycled continental crustal materials. By contrast, all Emeishan basalts display a mantle-like Mg isotopic composition, with δ26Mg ranging from -0.35 to -0.19‰. Since the Emeishan basalts derived from a mantle plume, their mantle-like Mg isotopic composition may indicate limited sedimentary carbonated recycled into the lower mantle. This is consistent with a recent experimental study which concluded that direct recycling of carbon into the lower mantle may have been highly restricted throughout most of the Earth's history.

An analysis of Apollo lunar soil samples 12070,889, 12030,187, and 12070,891: Basaltic diversity at the Apollo 12 landing site and implications for classification of small-sized lunar samples

NASA Astrophysics Data System (ADS)

Alexander, Louise; Snape, Joshua F.; Joy, Katherine H.; Downes, Hilary; Crawford, Ian A.

2016-09-01

Lunar mare basalts provide insights into the compositional diversity of the Moon's interior. Basalt fragments from the lunar regolith can potentially sample lava flows from regions of the Moon not previously visited, thus, increasing our understanding of lunar geological evolution. As part of a study of basaltic diversity at the Apollo 12 landing site, detailed petrological and geochemical data are provided here for 13 basaltic chips. In addition to bulk chemistry, we have analyzed the major, minor, and trace element chemistry of mineral phases which highlight differences between basalt groups. Where samples contain olivine, the equilibrium parent melt magnesium number (Mg#; atomic Mg/[Mg + Fe]) can be calculated to estimate parent melt composition. Ilmenite and plagioclase chemistry can also determine differences between basalt groups. We conclude that samples of approximately 1-2 mm in size can be categorized provided that appropriate mineral phases (olivine, plagioclase, and ilmenite) are present. Where samples are fine-grained (grain size <0.3 mm), a "paired samples t-test" can provide a statistical comparison between a particular sample and known lunar basalts. Of the fragments analyzed here, three are found to belong to each of the previously identified olivine and ilmenite basalt suites, four to the pigeonite basalt suite, one is an olivine cumulate, and two could not be categorized because of their coarse grain sizes and lack of appropriate mineral phases. Our approach introduces methods that can be used to investigate small sample sizes (i.e., fines) from future sample return missions to investigate lava flow diversity and petrological significance.

Estimation on rubber tree disturbance caused by typhoon Damery (200518) with Landsat and MODIS data in Hainan Island of China

NASA Astrophysics Data System (ADS)

Tan, Chenyan; Fang, Weihua; Li, Jian

2016-04-01

In 2005, Typhoon Damery (200518) caused severe damage to the rubber trees in Hainan Island with its destructive winds and rainfall. Selection of proper vegetation indices using multi-source remote sensing data is critical to the assessment of forest disturbance and damage loss for this event. In this study, we will compare the performance of seven vegetation indices derived from MODIS and Landsat TM imageries prior to and after typhoon Damery, in order to select an optimal index for identifying rubber tree disturbance. The indices to be compared are normalized difference vegetation index (NDVI), Normalized Difference Water Index (NDWI), Normalized Difference Infrared Index (NDII), Enhanced vegetation index (EVI), Leaf area index (LAI), forest z-score (IFZ), and Disturbance Index (DI). The ground truth data of rubber tree damage collected through field investigation was used to verify and compare the results. Our preliminary result for the area with ground-truth data shows that DI has the most significant performance for disturbance detection for this typhoon event. This index DI is then applied to all the areas in Hainan Island hit by Darmey to evaluate the overall forest damage severity. At last, rubber tree damage severity is analyzed with other typhoon hazard factors such as wind, topography, soil and precipitation.

Importance of lunar granite and KREEP in very high potassium (VHK) basalt petrogenesis

NASA Technical Reports Server (NTRS)

Neal, Clive R.; Taylor, Lawrence A.; Lindstrom, Marilyn M.

1988-01-01

Analysis of five very high potassium (VHK) basalts from Apollo 14 breccia 14303 shows the presence of a KREEP component. An assimilation and fractional crystallization model is presented to describe the basalt evolution. The influence of granite assimilation on the basalt evolution is discussed. The presence of VHK basalts containing only a granite signature and those with both granite and KREEP signatures suggests that there are at least two different VHK basalt flows at the Apollo 14 site.

Chemistry of Apollo 11 low-K mare basalts

NASA Technical Reports Server (NTRS)

Rhodes, J. M.; Blanchard, D. P.

1980-01-01

A reexamination of the bulk major and trace element geochemistry of Apollo 11 low-K mare basalts is presented. New analyses are given for seven previously unanalyzed samples (10003, 10020, 10044, 10047, 10050, 10058, and 10062) and for two low-K basalts (10029 and 10092) and one high-K basalt (10071) for which comprehensive compositional data were previously lacking. The data show that three distinct magma types have been sampled, as proposed by Beaty and Albee (1978), and that these magma types are unrelated by near-surface crystal fractionation. Each magma type is characterized by distinctive magmaphile element ratios, which enable previously unclassified samples (10050 and 10062) to be assigned to an appropriate magma type.

How thick are lunar mare basalts

NASA Technical Reports Server (NTRS)

Hoerz, F.

1978-01-01

It is argued that De Hon's estimates of the thickness of lunar mare basalts, made by analyzing 'ghost' craters on mare surfaces, were inflated as the result of the crater morphometric data of Pike (1977) to reconstruct rim heights of degraded craters. Crater rim heights of 82 randomly selected highland craters of various states of degradation were determined, and median rim height was compared to that of corresponding fresh impact structures. Results indicate that the thickness estimates of De Hon may be reduced by a factor of 2, and that the total volume of mare basalt produced throughout lunar history could be as little as 1-2 million cubic kilometers. A survey of geochemical and petrographic evidence indicates that lateral transport of regolith components over distances of much greater than 10 km is relatively inefficient; it is suggested that vertical mixing of a highland substrate underlying the basaltic fill may have had a primordial role in generating the observed mare width distributions and high concentrations of exotic components in intrabasin regoliths.

Iron isotopic systematics of oceanic basalts

NASA Astrophysics Data System (ADS)

Teng, Fang-Zhen; Dauphas, Nicolas; Huang, Shichun; Marty, Bernard

2013-04-01

The iron isotopic compositions of 93 well-characterized basalts from geochemically and geologically diverse mid-ocean ridge segments, oceanic islands and back arc basins were measured. Forty-three MORBs have homogeneous Fe isotopic composition, with δ56Fe ranging from +0.07‰ to +0.14‰ and an average of +0.105 ± 0.006‰ (2SD/√n, n = 43, MSWD = 1.9). Three back arc basin basalts have similar δ56Fe to MORBs. By contrast, OIBs are slightly heterogeneous with δ56Fe ranging from +0.05‰ to +0.14‰ in samples from Koolau and Loihi, Hawaii, and from +0.09‰ to +0.18‰ in samples from the Society Islands and Cook-Austral chain, French Polynesia. Overall, oceanic basalts are isotopically heavier than mantle peridotite and pyroxenite xenoliths, reflecting Fe isotope fractionation during partial melting of the mantle. Iron isotopic variations in OIBs mainly reflect Fe isotope fractionation during fractional crystallization of olivine and pyroxene, enhanced by source heterogeneity in Koolau samples.

Making rhyolite in a basalt crucible

NASA Astrophysics Data System (ADS)

Eichelberger, John

2016-04-01

Iceland has long attracted the attention of those concerned with the origin of rhyolitic magmas and indeed of granitic continental crust, because it presents no alternative for such magmas other than deriving them from a basaltic source. Hydrothermally altered basalt has been identified as the progenitor. The fact that rhyolite erupts as pure liquid requires a process of melt-crustal separation that is highly efficient despite the high viscosity of rhyolite melt. Volcanoes in Iceland are foci of basaltic magma injection along the divergent plate boundary. Repeated injection produces remelting, digestion, and sometimes expulsion or lateral withdrawal of material resulting in a caldera, a "crucible" holding down-dropped and interlayered lava flows, tephras, and injected sills. Once melting of this charge begins, a great deal of heat is absorbed in the phase change. Just 1% change in crystallinity per degree gives a melt-present body an effective heat capacity >5 times the subsolidus case. Temperature is thus buffered at the solidus and melt composition at rhyolite. Basalt inputs are episodic ("fires") so likely the resulting generation of rhyolite by melting is too. If frequent enough to offset cooling between events, rhyolite melt extractions will accumulate as a rhyolite magma reservoir rather than as discrete crystallized sills. Evidently, such magma bodies can survive multiple firings without themselves erupting, as the 1875 eruption of Askja Caldera of 0.3 km3 of rhyolite equilibrated at 2-km depth without previous leakage over a ten-millennium period and the surprise discovery of rhyolite magma at 2-km depth in Krafla suggest. Water is required for melting; otherwise melting cannot begin at a temperature lower than that of the heat source. Because the solubility of water in melt is pressure-dependent and almost zero at surface pressure, there must be a minimum depth at which basalt-induced melting can occur and a rhyolite reservoir sustained. In practice, the

Partial melting of the Allende (CV3) meteorite - Implications for origins of basaltic meteorites

NASA Technical Reports Server (NTRS)

Jurewicz, A. J. G.; Mittlefehldt, D. W.; Jones, J. H.

1991-01-01

Eucrites and angrites are distinct types of basaltic meteorites whose origins are poorly known. Experiments in which samples of the Allende (CV3) carbonaceous chondrite were partially melted indicate that partial melts can resemble either eucrites or angrites, depending only on the oxygen fugacity. Melts are eucritic if this variable is below that of the iron-wuestite buffer or angritic if above it. With changing pressure, the graphite-oxygen redox reaction can produce oxygen fugacities that are above or below those of the iron-wuestite buffer. Therefore, a single, homogeneous, carbonaceous planetoid greater than 110 kilometers in radius could produce melts of drastically different composition, depending on the depth of melting.

Bonding Properties of Basalt Fiber and Strength Reduction According to Fiber Orientation

PubMed Central

Choi, Jeong-Il; Lee, Bang Yeon

2015-01-01

The basalt fiber is a promising reinforcing fiber because it has a relatively higher tensile strength and a density similar to that of a concrete matrix as well as no corrosion possibility. This study investigated experimentally the bonding properties of basalt fiber with cementitious material as well as the effect of fiber orientation on the tensile strength of basalt fiber for evaluating basalt fiber’s suitability as a reinforcing fiber. Single fiber pullout tests were performed and then the tensile strength of fiber was measured according to fiber orientation. The test results showed that basalt fiber has a strong chemical bond with the cementitious matrix, 1.88 times higher than that of polyvinyl alcohol fibers with it. However, other properties of basalt fiber such as slip-hardening coefficient and strength reduction coefficient were worse than PVA and polyethylene fibers in terms of fiber bridging capacity. Theoretical fiber-bridging curves showed that the basalt fiber reinforcing system has a higher cracking strength than the PVA fiber reinforcing system, but the reinforcing system showed softening behavior after cracking. PMID:28793595

Bonding Properties of Basalt Fiber and Strength Reduction According to Fiber Orientation.

PubMed

Choi, Jeong-Il; Lee, Bang Yeon

2015-09-30

The basalt fiber is a promising reinforcing fiber because it has a relatively higher tensile strength and a density similar to that of a concrete matrix as well as no corrosion possibility. This study investigated experimentally the bonding properties of basalt fiber with cementitious material as well as the effect of fiber orientation on the tensile strength of basalt fiber for evaluating basalt fiber's suitability as a reinforcing fiber. Single fiber pullout tests were performed and then the tensile strength of fiber was measured according to fiber orientation. The test results showed that basalt fiber has a strong chemical bond with the cementitious matrix, 1.88 times higher than that of polyvinyl alcohol fibers with it. However, other properties of basalt fiber such as slip-hardening coefficient and strength reduction coefficient were worse than PVA and polyethylene fibers in terms of fiber bridging capacity. Theoretical fiber-bridging curves showed that the basalt fiber reinforcing system has a higher cracking strength than the PVA fiber reinforcing system, but the reinforcing system showed softening behavior after cracking.

The discovery of late Quaternary basalt on Mount Bambouto: Implications for recent widespread volcanic activity in the southern Cameroon Line

NASA Astrophysics Data System (ADS)

Kagou Dongmo, Armand; Nkouathio, David; Pouclet, André; Bardintzeff, Jacques-Marie; Wandji, Pierre; Nono, Alexandre; Guillou, Hervé

2010-04-01

At the north-eastern flank of Mount Bambouto, a lateral cone, the Totap volcano, is dated at 0.480 ± 0.014 Ma, which corresponds to the most recent activity of this area. The lava is a basanite similar to the older basanites of Mount Bambouto. Two new datations of the lavas of the substratum are 11.75 ± 0.25 Ma, and 21.12 ± 0.45 Ma. A synthetic revision of the volcanic story of Mount Bambouto is proposed as follows. The first stage, ca. 21 Ma, corresponds to the building of the initial basaltic shield volcano. The second stage, from 18.5 to 15.3 Ma, is marked by the collapse of the caldera linked to the pouring out of ignimbritic rhyolites and trachytes. The third stage, from 15 to 4.5 Ma, renews with basaltic effusive activity, together with post-caldera extrusions of trachytes and phonolites. The 0.5 Ma Totap activity could be a fourth stage. In the recent Quaternary, a number of basaltic activities, similar to that of the Totap volcano, are encountered elsewhere in the Cameroon Line, from Mount Oku to Mount Cameroon. The very long-live activity at Mount Bambouto and the volcanic time-space distribution in the southern Cameroon Line are linked to the working of a hotline.

87Sr/86Sr ratios in basalts from islands in the Indian Ocean

USGS Publications Warehouse

Hedge, C.E.; Watkins, N.D.; Hildreth, R.A.; Doering, W.P.

1973-01-01

87Sr/86Sr ratios of basalts from islands in the Indian Ocean (0.7040) are higher than those of basalts dredged from the Mid-Indian Ocean Ridge (0.7034). The sources of the island basalts have apparently not been in equilibrium with the source of the ridge basalts for roughly 109 years. Both ridge and island basalts in the Indian Ocean are higher in 87Sr/86Sr than are rocks from similar settings in the eastern Pacific. ?? 1973.

A Strongly Calc-alkaline Suite in the Midst of the Tholeiitic Columbia River Basalt Province: Implications for Generating the Calc-alkaline Trend Without Subduction Processes

NASA Astrophysics Data System (ADS)

Steiner, A. R.; Streck, M. J.

2012-12-01

The mid-Miocene lavas of the Strawberry Volcanics (SV), distributed over 3,400 km2 in NE Oregon, comprise a diverse volcanic suite, which span the range of compositions from basalt to rhyolite. The volcanic suite is mainly composed of calc-alkaline (CA) basaltic andesite and andesite, yet tholeiitic (TH) lavas of basalt to andesite occur as well. The SV lies in the heart of nearly coeval flood basalts of the Columbia River province of the Pacific Northwest. The unique combination of strongly CA rocks of the SV in a non-subduction setting provide an excellent opportunity to study controls on inducing CA evolution in the midst of a TH province and independent of processes taking places at an active subduction zone. New 40Ar/39Ar ages indicate CA basaltic andesites to andesites of the SV erupted at least from 14.78±0.13 Ma to 12.44±0.12 Ma demonstrating that CA magmatism of the SV was ongoing during the eruptions of the tholeiitic Wanapum Basalt member of the Columbia River Basalt Group (CRBG). This range will likely be extended to even older ages in the future because existent age dates did not include samples from near the base of the SV. Thickness of intermediate lavas flows of the SV range from 15 m to as thin as 2 m and lavas are characterized by mostly phenocryst poor lithologies. When phenocrysts are abundant they are very small suggesting growth late during eruption. Single lava flow sections can include on the order of 30 conformable flows, testifying to a vigorous eruption history. The thickest andesitic sections are located in the glacially carved mountains of the Strawberry Mountain Wilderness (i.e. Strawberry Mountain, High Lake, and Slide Lake) where several vent complexes are exposed, which are delineated by dikes and plugs with finely interlocking plutonic textures, cross-cutting SV lava flows. Dikes generally strike NW-SE. Subtle variations in major and trace element compositions exist between TH and CA lavas of the SV. The CA lavas of the SV are

Comparative Planetary Mineralogy: Basaltic Plagioclase from Earth, Moon, Mars and 4 Vesta

NASA Technical Reports Server (NTRS)

Karner, J. M.; Papike, J. J.; Shearer, C. K.

2003-01-01

Major, minor and trace element analysis of silicates has allowed for the study of planetary basalts in a comparative planetary mineralogy context. We continue this initiative by exploring the chemistry of plagioclase feldspar in basalts from the Earth, Moon, Mars and 4 Vesta. This paper presents new data on plagioclase from six terrestrial basalt suites including Keweenawan, Island Arc, Hawaiian, Columbia Plateau, Taos Plateau, and Ocean Floor; six lunar basalt suites including Apollo 11 Low K, Apollo 12 Ilmenite, Apollo 12 Olivine, Apollo 12 Pigeonite, Apollo 15 Olivine, and Apollo 15 Pigeonite; two basaltic martian meteorites, Shergotty and QUE 94201; and one unequilibrated eucrite, Pasamonte.

Mineralogy and geochemistry of picro-dolerite dykes from the central Deccan Traps flood basaltic province, India, and their geodynamic significance

NASA Astrophysics Data System (ADS)

Dongre, Ashish; Viljoen, K. S.; Rathod, A.

2018-04-01

Constituent mineral compositions and whole rock major element geochemistry of picro-dolerite dykes from the central part of the Deccan flood basalt province are presented and discussed. The dykes are characterized by an MgO content of about 13 wt%, coupled with 13-16 modal percents of olivine. A high whole rock molar Mg# value of 71 and the presence of magnesian olivine phenocrysts ( Fo78) are consistent with a primitive (i.e. unevolved) geochemistry. The nature and composition of clinopyroxene (augite and pigeonite), plagioclase feldspar (labradorite) and Fe-Ti oxides (mostly ilmenite and magnetite) are also discussed, with implications drawn with respect to the geodynamics. High MgO magmas and rocks such as picrites are generally considered to be indicative of plume magmatism, formed by high degrees of partial melting in, e.g. the high-temperature region of a plume head. Recent age data is consistent with a model in which the Deccan LIP picritic magmatism is associated with the main phase of Deccan Trap activity at 66 Ma, as a result of a syn- to post rifting phase associated with the impact of the Rèunion mantle plume. It is speculated that the differentiation of primary olivine basaltic magma of picritic composition, may have been the mechanism for the generation of alkalic basalts which occurs in the Deccan Trap basaltic sequence.

Phase relations of a simulated lunar basalt as a function of oxygen fugacity, and their bearing on the petrogenesis of the Apollo 11 basalts

USGS Publications Warehouse

Tuthill, R.L.; Sato, M.

1970-01-01

A glass of Apollo 11 basalt composition crystallizing at 1 atm at low f{hook}02 showed the following crystallization sequence; ferropseudobrookite at 1210??C, olivine at 1200??C, ilmenite and plagioclase at 1140??C, clinopyroxene at 1113??C. Ferropseudobrookite and olivine have a reaction relation to the melt. This sequence agrees with that assumed on textural grounds for some Apollo 11 basalts. It also indicates that the Apollo 11 basalts cannot have been modified by low-pressure fractionation. ?? 1970.

Growing magma chambers control the distribution of small-scale flood basalts.

PubMed

Yu, Xun; Chen, Li-Hui; Zeng, Gang

2015-11-19

Small-scale continental flood basalts are a global phenomenon characterized by regular spatio-temporal distributions. However, no genetic mechanism has been proposed to explain the visible but overlooked distribution patterns of these continental basaltic volcanism. Here we present a case study from eastern China, combining major and trace element analyses with Ar-Ar and K-Ar dating to show that the spatio-temporal distribution of small-scale flood basalts is controlled by the growth of long-lived magma chambers. Evolved basalts (SiO2 > 47.5 wt.%) from Xinchang-Shengzhou, a small-scale Cenozoic flood basalt field in Zhejiang province, eastern China, show a northward younging trend over the period 9.4-3.0 Ma. With northward migration, the magmas evolved only slightly ((Na2O + K2O)/MgO = 0.40-0.66; TiO2/MgO = 0.23-0.35) during about 6 Myr (9.4-3.3 Ma). When the flood basalts reached the northern end of the province, the magmas evolved rapidly (3.3-3.0 Ma) through a broad range of compositions ((Na2O + K2O)/MgO = 0.60-1.28; TiO2/MgO = 0.30-0.57). The distribution and two-stage compositional evolution of the migrating flood basalts record continuous magma replenishment that buffered against magmatic evolution and induced magma chamber growth. Our results demonstrate that the magma replenishment-magma chamber growth model explains the spatio-temporal distribution of small-scale flood basalts.

Nutrient dynamics in tropical rivers, lagoons, and coastal ecosystems of eastern Hainan Island, South China Sea

NASA Astrophysics Data System (ADS)

Li, R. H.; Liu, S. M.; Li, Y. W.; Zhang, G. L.; Ren, J. L.; Zhang, J.

2014-01-01

Nutrient dynamics based on field observations made along the eastern Hainan Island during the period 2006-2009 were investigated to understand nutrient biogeochemical processes, and to provide an overview of human perturbations of coastal ecosystems in this tropical region. The rivers showed seasonal variations in nutrient concentrations, with enrichment of dissolved inorganic nitrogen and dissolved silicate, and depletion of PO43-. High riverine concentrations of nitrate mainly originated from agricultural fertilizer inputs. The DIN : PO43- ratios ranged from 37 to 1063, suggesting preferential depletion of PO43- relative to nitrogen in rivers. Chemical weathering in the drainage area might explain the high levels of dissolved silicate. Aquaculture ponds contained high concentrations of NH4+ and dissolved organic nitrogen. The particulate phosphorus concentrations in the study area were lower than those reported for estuaries worldwide. The particulate silicate levels in rivers and lagoons were lower than the global average level. Nutrient biogeochemistry in coastal areas was affected by human activities (e.g., aquaculture, agriculture), and by natural phenomena including typhoons. The nutrient concentrations in coastal waters were low because of dispersion of land-derived nutrients in the sea. Nutrient budgets were built based on a steady-state box model, which showed that riverine fluxes are magnified by estuarine processes (e.g., regeneration, desorption) in estuaries and Laoyehai Lagoon, but not in Xiaohai Lagoon. Riverine and groundwater inputs were the major sources of nutrients to Xiaohai and Laoyehai lagoons, respectively, and riverine inputs and aquaculture effluents were the major sources for the eastern coast of Hainan Island. Nutrient inputs to the coastal ecosystem increased with typhoon-induced runoff of rainwater, elucidating the important influence of typhoons on small tropical rivers.

Tree Biomass Allocation and Its Model Additivity for Casuarina equisetifolia in a Tropical Forest of Hainan Island, China.

PubMed

Xue, Yang; Yang, Zhongyang; Wang, Xiaoyan; Lin, Zhipan; Li, Dunxi; Su, Shaofeng

2016-01-01

Casuarina equisetifolia is commonly planted and used in the construction of coastal shelterbelt protection in Hainan Island. Thus, it is critical to accurately estimate the tree biomass of Casuarina equisetifolia L. for forest managers to evaluate the biomass stock in Hainan. The data for this work consisted of 72 trees, which were divided into three age groups: young forest, middle-aged forest, and mature forest. The proportion of biomass from the trunk significantly increased with age (P<0.05). However, the biomass of the branch and leaf decreased, and the biomass of the root did not change. To test whether the crown radius (CR) can improve biomass estimates of C. equisetifolia, we introduced CR into the biomass models. Here, six models were used to estimate the biomass of each component, including the trunk, the branch, the leaf, and the root. In each group, we selected one model among these six models for each component. The results showed that including the CR greatly improved the model performance and reduced the error, especially for the young and mature forests. In addition, to ensure biomass additivity, the selected equation for each component was fitted as a system of equations using seemingly unrelated regression (SUR). The SUR method not only gave efficient and accurate estimates but also achieved the logical additivity. The results in this study provide a robust estimation of tree biomass components and total biomass over three groups of C. equisetifolia.

[Distributions and seasonal variations of total dissolved inorganic arsenic in the estuaries and coastal area of eastern Hainan].

PubMed

Cao, Xiu-Hong; Ren, Jing-Ling; Zhang, Gui-Ling; Zhang, Jin-E; Du, Jin-Zhou; Zhu, De-Di

2012-03-01

The concentrations of total dissolved inorganic arsenic (TDIAs) were measured by Hydride Generation-Atomic Fluorescence Spectrometry (HG-AFS). Two cruises were carried out in the river, estuary, coastal area and groundwater of eastern Hainan in December 2006 and August 2007. The concentrations of TDIAs in the Wanquan and Wenchang/Wenjiao rivers and their estuaries, coastal area in December 2006 were 4.0-9.4, 1.3-13.3, 13.3-17.3 nmol x L(-1), respectively. The concentrations of TDIAs in the Wanquan and Wenchang/Wenjiao rivers and their estuaries, coastal area in August 2007 were 1.6-15.5, 2.4-15.9, 10.8-17.6 nmol x L(-1), respectively. There was no significantly seasonal variation of TDIAs in the rivers and estuaries during the dry and wet seasons. Compared with other areas in the world, the concentration of TDIAs in the Eastern Hainan remained at pristine levels. TDIAs showed conservatively mixing in the both estuaries. The concentration of TDIAs of groundwater was below detection limit (BDL)-41.7 nmol x L(-1). The submarine groundwater discharge (SGD) to the coastal area was estimated in the drainage basin of Wenchang/Wenjiao river based on the average concentration of TDIAs in the groundwater and SGD water discharge, with the value of 1 153 mol x a(-1). Budget estimation indicated that the SGD discharge is one of the important sources of arsenic in the coastal area.

Tree Biomass Allocation and Its Model Additivity for Casuarina equisetifolia in a Tropical Forest of Hainan Island, China

PubMed Central

Xue, Yang; Yang, Zhongyang; Wang, Xiaoyan; Lin, Zhipan; Li, Dunxi; Su, Shaofeng

2016-01-01

Casuarina equisetifolia is commonly planted and used in the construction of coastal shelterbelt protection in Hainan Island. Thus, it is critical to accurately estimate the tree biomass of Casuarina equisetifolia L. for forest managers to evaluate the biomass stock in Hainan. The data for this work consisted of 72 trees, which were divided into three age groups: young forest, middle-aged forest, and mature forest. The proportion of biomass from the trunk significantly increased with age (P<0.05). However, the biomass of the branch and leaf decreased, and the biomass of the root did not change. To test whether the crown radius (CR) can improve biomass estimates of C. equisetifolia, we introduced CR into the biomass models. Here, six models were used to estimate the biomass of each component, including the trunk, the branch, the leaf, and the root. In each group, we selected one model among these six models for each component. The results showed that including the CR greatly improved the model performance and reduced the error, especially for the young and mature forests. In addition, to ensure biomass additivity, the selected equation for each component was fitted as a system of equations using seemingly unrelated regression (SUR). The SUR method not only gave efficient and accurate estimates but also achieved the logical additivity. The results in this study provide a robust estimation of tree biomass components and total biomass over three groups of C. equisetifolia. PMID:27002822

Preliminary Hydrogeologic Characterization Results from the Wallula Basalt Pilot Study

DOE Office of Scientific and Technical Information (OSTI.GOV)

B.P. McGrail; E. C. Sullivan; F. A. Spane

2009-12-01

The DOE's Big Sky Regional Carbon Sequestration Partnership has completed drilling the first continental flood basalt sequestration pilot borehole to a total depth (TD) of 4,110 feet on the Boise White Paper Mill property at Wallula, Washington. Site suitability was assessed prior to drilling by the 2007-2008 acquisition, processing and analysis of a four-mile, five-line three component seismic swath, which was processed as a single data-dense line. Analysis of the seismic survey data indicated a composite basalt formation thickness of {approx}8,000 feet and absence of major geologic structures (i.e., faults) along the line imaged by the seismic swath. Drilling ofmore » Wallula pilot borehole was initiated on January 13, 2009 and reached TD on April 6, 2009. Based on characterization results obtained during drilling, three basalt breccia zones were identified between the depth interval of 2,716 and 2,910 feet, as being suitable injection reservoir for a subsequent CO2 injection pilot study. The targeted injection reservoir lies stratigraphically below the massive Umtanum Member of the Grande Ronde Basalt, whose flow-interior section possesses regionally recognized low-permeability characteristics. The identified composite injection zone reservoir provides a unique and attractive opportunity to scientifically study the reservoir behavior of three inter-connected reservoir intervals below primary and secondary caprock confining zones. Drill cuttings, wireline geophysical logs, and 31one-inch diameter rotary sidewall cores provided geologic data for characterization of rock properties. XRF analyses of selected rock samples provided geochemical characterizations of the rocks and stratigraphic control for the basalt flows encountered by the Wallula pilot borehole. Based on the geochemical results, the pilot borehole was terminated in the Wapshilla Ridge 1 flow of the Grande Ronde Basalt Formation. Detailed hydrologic test characterizations of 12 basalt interflow

Results of test drilling in the Basalt aquifer near Fallon, Nevada

USGS Publications Warehouse

Maurer, Douglas K.

2002-01-01

Drilling of two test holes into the Fallon basalt aquifer commenced August 14, 2001. The basalt aquifer is located beneath the Carson Desert, near Fallon, Nevada, and is the sole source of drinking water for the City of Fallon, the Naval Air Station (NAS) Fallon, and the Fallon Paiute-Shoshone Tribe. Basalt comprising the aquifer is exposed at Rattlesnake Hill, an eroded volcanic cone, about 1 mile northeast of Fallon, and the remainder is buried beneath sediments deposited by the Carson River and ancient Lake Lahontan to depths of 600 feet near its edges (fig. 1). The basalt-aquifer system is a mushroom-shaped body of highly permeable volcanic rock. Viewed from above, the lateral extent of the basalt body is oval-shaped, about 4-miles wide and 10-miles long (fig. 1). Drilling was part of a cooperative study between the U.S. Geological Survey (USGS), the Bureau of Reclamation, and NAS Fallon. The study was started because of concern about the continued viability of the basalt-aquifer system as a source of municipal water supply. Increased pumping from about 1,700 acre-feet per year (acre-ft/yr) in the 1970?s to over 3,000 acre-ft/yr in the late 1990?s has caused water levels in the basalt to decline as much as 12 feet (fig. 2). During this same time period, water pumped from the aquifer at NAS Fallon and the City of Fallon wells showed that concentrations of dissolved chloride increased, although chloride concentrations were well within the U.S. Environmental Protection Agency?s (EPA) drinking-water standards; at this rate of increase, it would take decades to exceed the present standard (Maurer and Welch, 2001, p. 46). Concentrations of arsenic in the aquifer are about 0.1 milligrams per liter (mg/L), exceeding the drinking-water standard of 0.01 mg/L, but show no apparent change over time (Maurer and Welch, 2001, p. 10 and 48; U. S. Environmental Protection Agency, 2001). Increasing concentrations of chloride may be caused by increased pumping, that induces

Petrology of basalts from Loihi Seamount, Hawaii

NASA Astrophysics Data System (ADS)

Hawkins, James; Melchior, John

1983-12-01

Loihi Seamount is the southeasternmost active volcano of the Emperor-Hawaii linear volcanic chain. It comprises a spectrum of basalt compositional varieties including basanite, alkali basalt, transitional basalt and tholeiite. Samples from four dredge collections made on Scripps Institution of Oceanography Benthic Expedition in October 1982 are tholeiite. The samples include highly vesicular, olivine-rich basalt and dense glass-rich pillow fragments containing olivine and augite phenocrysts. Both quartz-normative and olivine-normative tholeiites are present. Minor and trace element data indicate relatively high abundances of low partition coefficient elements (e.g., Ti, K, P. Rb, Ba, Zr) and suggest that the samples were derived by relatively small to moderate extent of partial melting, of an undepleted mantle source. Olivine composition, MgO, Cr and Ni abundances, and Mg/(Mg+Fe), are typical of moderately fractionated to relatively unfractionated "primary" magmas. The variations in chemistry between samples cannot be adequately explained by low-pressure fractional crystallization but can be satisfied by minor variations in extent of melting if a homogeneous source is postulated. Alternatively, a heterogeneous source with variable abundances of certain trace elements, or mixing of liquids, may have been involved. Data for 3He/ 4He, presented in a separate paper, implies a mantle plume origin for the helium composition of the Loihi samples. There is little variation in the helium isotope ratio for samples having different compositions and textures. The helium data are not distinctive enough to unequivocally separate the magma sources for the tholeiitic rocks from the other rock types such as Loihi alkalic basalts and the whole source region for Loihi may have a nearly uniform helium compositions even though other element abundances may be variable. Complex petrologic processes including variable melting, fractional crystallization and magma mixing may have blurred

MSL SAM-like Analyses of Hawaiian Altered Basaltic Materials: Implications for Analyses by the Mars Science Laboratory

NASA Astrophysics Data System (ADS)

McAdam, A.; Eigenbrode, J. L.; Young, K. E.; Bleacher, J. E.; Knudson, C. A.; Rogers, D.; Glotch, T. D.; Sutter, B.; Mahaffy, P. R.; Navarro-Gonzalez, R.; Downs, R. T.

2015-12-01

Samples of basaltic materials were collected during several traverses of the Kau Desert on the leeward side of the Kilauea Volcano, Hawaii, conducted by the Remote, In Situ, and Synchrotron Studies for Science and Exploration (RIS4E) team, a node of the Solar System Exploration and Research Virtual Institute (SSERVI) program. Some of these samples had been exposed to circumneutral to slightly acidic alteration conditions from exposure to fog/rain, and acidic fog/rain, while others had been exposed to more acidic conditions due to proximity to fumaroles. The samples consisted of basalts with coatings, sands and soils, and ash, and were collected using organically clean protocols to enable investigation of organic chemistry and organic-mineral associations, in addition to mineralogy. The Mars Science Laboratory (MSL) rover has analyzed basaltic materials inferred to have been altered under conditions ranging from circumneutral to acidic, but several aspects of the Sample Analysis at Mars (SAM) instrument suite results are still being investigated and analyses of relevant terrestrial analogs can play an important role in interpretation of the data. For example, all materials analyzed to date have a significant amorphous component. Comparisons of the mineralogy obtained with the MSL CheMin instrument and volatiles evolved during SAM analyses indicate that, by mass balance, some portion of the volatiles, such as SO2 and H2O, are likely associated with this component. Many of the RIS4E samples also have a significant amorphous component, and field x-ray diffraction (XRD) and x-ray fluorescence (XRF) data indicate differences in the chemistry of this material in samples exposed to different alteration conditions. Preliminary SAM-like analyses indicate that the amorphous materials in some of these samples evolve volatiles such as H2O and SO2 during heating. Here we will discuss these results, and others, obtained through SAM-like analyses of selected samples.

Extracellular enzyme activity and microbial diversity measured on seafloor exposed basalts from Loihi seamount indicate the importance of basalts to global biogeochemical cycling.

PubMed

Jacobson Meyers, Myrna E; Sylvan, Jason B; Edwards, Katrina J

2014-08-01

Seafloor basalts are widely distributed and host diverse prokaryotic communities, but no data exist concerning the metabolic rates of the resident microbial communities. We present here potential extracellular enzyme activities of leucine aminopeptidase (LAP) and alkaline phosphatase (AP) measured on basalt samples from different locations on Loihi Seamount, HI, coupled with analysis of prokaryotic biomass and pyrosequencing of the bacterial 16S rRNA gene. The community maximum potential enzyme activity (Vmax) of LAP ranged from 0.47 to 0.90 nmol (g rock)(-1) h(-1); the Vmax for AP was 28 to 60 nmol (g rock)(-1) h(-1). The Km of LAP ranged from 26 to 33 μM, while the Km for AP was 2 to 7 μM. Bacterial communities on Loihi basalts were comprised primarily of Alpha-, Delta-, andGammaproteobacteria, Bacteroidetes, and Planctomycetes. The putative ability to produce LAP is evenly distributed across the most commonly detected bacterial orders, but the ability to produce AP is likely dominated by bacteria in the orders Xanthomonadales, Flavobacteriales, and Planctomycetales. The enzyme activities on Loihi basalts were compared to those of other marine environments that have been studied and were found to be similar in magnitude to those from continental shelf sediments and orders of magnitude higher than any measured in the water column, demonstrating that the potential for exposed basalts to transform organic matter is substantial. We propose that microbial communities on basaltic rock play a significant, quantifiable role in benthic biogeochemical processes. Copyright © 2014, American Society for Microbiology. All Rights Reserved.

Geochemistry of komatiites and basalts from the Rio das Velhas and Pitangui greenstone belts, São Francisco Craton, Brazil: Implications for the origin, evolution, and tectonic setting

NASA Astrophysics Data System (ADS)

Verma, Sanjeet K.; Oliveira, Elson P.; Silva, Paola M.; Moreno, Juan A.; Amaral, Wagner S.

2017-07-01

The Neoarchean Rio das Velhas and Pitangui greenstone belts are situated in the southern São Francisco Craton, Minas Gerais, Brazil. These greenstone belts were formed between ca. 2.79-2.73 Ga, and consist mostly of mafic to ultramafic volcanics and clastic sediments, with minor chemical sediments and felsic volcanics that were metamorphosed under greenschist facies. Komatiites are found only in the Rio das Velhas greenstone belt, which is composed of high-MgO volcanic rocks that have been identified as komatiites and high-Mg basalts, based on their distinctive geochemical characteristics. The Rio das Velhas komatiites are composed of tremolite + actinolite + serpentine + albite with a relict spinifex-texture. The Rio das Velhas komatiites have a high magnesium content ((MgO)adj ≥ 28 wt.%), an Al-undepleted Munro-type [(Al2O3/TiO2)adj and (CaO/Al2O3)adj] ratio ranging from 27 to 47 and 0.48 to 0.89, relatively low abundances of incompatible elements, a depletion of light rare earth elements (LREE), a pattern of non-fractionated heavy rare- earth elements (HREE), and a low (Gd/Yb)PM ratio (≤ 1.0). Negative Ce anomalies suggest that alteration occurred during greenschist facies metamorphism for the komatiites and high-Mg basalts. The low [(Gd/Yb)PM < 1.0] and [(CaO/Al2O3)adj < 0.9)], high [(Al2O3/TiO2)adj > 18] and high HREE, Y, and Zr content suggest that the Rio das Velhas komatiites were derived from the shallow upper mantle without garnet involvement in the residue. The chemical compositions [(Al2O3/TiO2)adj, (FeO)adj, (MgO)adj, (CaO/Al2O3)adj, Na, Th, Ta, Ni, Cr, Zr, Y, Hf, and REE] indicate that the formation of the komatiites, high-Mg basalts and basalts occurred at different depths and temperatures in a heterogeneous mantle. The komatiites and high-Mg basalts melted at liquidus temperatures of 1450-1550 °C. The Pitangui basalts are enriched in the highly incompatible LILE (large-ion lithophile elements) relative to the moderately incompatible HFS (high

The origin of plagioclase phenocrysts in basalts from continental monogenetic volcanoes of the Kaikohe-Bay of Islands field, New Zealand: implications for magmatic assembly and ascent

NASA Astrophysics Data System (ADS)

Coote, Alisha; Shane, Phil; Stirling, Claudine; Reid, Malcolm

2018-02-01

Late Quaternary, porphyritic basalts erupted in the Kaikohe-Bay of Islands area, New Zealand, provide an opportunity to explore the crystallization and ascent history of small volume magmas in an intra-continental monogenetic volcano field. The plagioclase phenocrysts represent a diverse crystal cargo. Most of the crystals have a rim growth that is compositionally similar to groundmass plagioclase ( An65) and is in equilibrium with the host basalt rock. The rims surround a resorbed core that is either less calcic ( An20-45) or more calcic (> An70), having crystallized in more differentiated or more primitive melts, respectively. The relic cores, particularly those that are less calcic (< An45), have 87Sr/86Sr ratios that are either mantle-like ( 0.7030) or crustal-like ( 0.7040 to 0.7060), indicating some are antecrysts formed in melts fractionated from plutonic basaltic forerunners, while others are true xenocrysts from greywacke basement and/or Miocene arc volcanics. It is envisaged that intrusive basaltic forerunners produced a zone where various degrees of crustal assimilation and fractional crystallization occurred. The erupted basalts represent mafic recharge of this system, as indicated by the final crystal rim growths around the entrained antecrystic and xenocrystic cargo. The recharge also entrained cognate gabbros that occur as inclusions, and produced mingled groundmasses. Multi-stage magmatic ascent and interaction is indicated, and is consistent with the presence of a partial melt body in the lower crust detected by geophysical methods. This crystallization history contrasts with traditional concepts of low-flux basaltic systems where rapid ascent from the mantle is inferred. From a hazards perspective, the magmatic system inferred here increases the likelihood of detecting eruption precursor phenomena such as seismicity, degassing and surface deformation.

Basalt-Limestone and Andesite-Limestone Interaction in the Arc Crust - Implications for Volcanic Degassing of CO2

NASA Astrophysics Data System (ADS)

Carter, L. B.; Dasgupta, R.

2014-12-01

Volcanically emitted CO2 is generally mantle-derived, but high degassing rates at some arcs (e.g. Merapi [1] and Colli Albani Volcanic District [2]) are thought to be affected by magma-carbonate interaction in the upper plate. However, the effects of depth, temperature, and composition on this process are poorly known. We experimentally simulated magma (50%)-limestone (50%) wallrock interactions at 0.5-1.0 GPa, 1100-1200 °C using pure calcite and a hydrous (~3-5 wt.% H2O) melt (basalt, andesite, or dacite). At 1.0 GPa, 1200 °C starting melts are superliquidus, whereas in the presence of calcite, Ca-rich cpx ± Ca-scapolite are produced. With increasing T, basalt-calcite interaction causes the melt, on a volatile-free basis, to become silica-poor and Ca-rich with alumina decreasing as cpx becomes more CaTs-rich. The same trend is seen with all starting melt compositions as P decreases at a constant T (1200 °C), producing melts similar to ultracalcic (CaO/Al2O3>>1) melt inclusions found in arc settings. Shifting from basalt to andesite has little effect on SiO2 and CaO of the reacted melt (e.g. 37 wt.% SiO2, 42 wt.% CaO at 0.5 GPa, 1200 °C), whereas Al2O3 of andesite-derived reacted melt is lower, likely a result of lower alumina in the starting andesite. Wall-rock calcite consumption is observed to increase with increasing T, decreasing P, and increasing melt XSiO2. At 0.5 GPa between 1100 and 1200 °C, our basalt experiments yield carbonate assimilation from 22 to 48 wt.%. This decreases to 20 wt.% at 1.0 GPa, 1200 °C, whereas an andesitic composition assimilates 59 to 52 wt.% from 0.5 to 1.0 GPa at 1200 °C. The higher assimilation in andesite-added runs at high-T is because of lower silicate liquidus as evidenced by lower modal proportion or absence of cpx ± scapolite. Using a magma flux rate estimated for Mt. Vesuvius [3], we obtain a CO2 outflux for a single such volcano experiencing arc magma-calcite reaction [4] of at least 2-4% of the present

Field Validation of Supercritical CO 2 Reactivity with Basalts

DOE Office of Scientific and Technical Information (OSTI.GOV)

McGrail, B. Peter; Schaef, Herbert T.; Spane, Frank A.

2017-01-10

Continued global use of fossil fuels places a premium on developing technology solutions to minimize increases in atmospheric CO 2 levels. CO 2 storage in reactive basalts might be one of these solutions by permanently converting injected gaseous CO 2 into solid carbonates. Herein we report results from a field demonstration where ~1000 MT of CO 2 was injected into a natural basalt formation in Eastern Washington State. Following two years of post-injection monitoring, cores were obtained from within the injection zone and subjected to detailed physical and chemical analysis. Nodules found in vesicles throughout the cores were identified asmore » the carbonate mineral, ankerite Ca[Fe, Mg, Mn](CO 3) 2. Carbon isotope analysis showed the nodules are chemically distinct as compared with natural carbonates present in the basalt and clear correlation with the isotopic signature of the injected CO 2. These findings provide field validation of rapid mineralization rates observed from years of laboratory testing with basalts.« less

Th-230 - U-238 series disequilibrium of the Olkaria basalts Gregory Rift Valley, Kenya

NASA Technical Reports Server (NTRS)

Black, S.; Macdonald, R.; Kelly, M.

1993-01-01

U-Th disequilibrium analyses of the Naivasha basalts show a very small (U-238/Th-230) ratios which are lower than any previously analyzed basalts. The broadly positive internal isochron trend from one sample indicates that the basalts may have source heterogeneities, this is supported by earlier work. The Naivasha complex comprises a bimodal suite of basalts and rhyolites. The basalts are divided into two stratigraphic groups each of a transitional nature. The early basalt series (EBS) which were erupted prior to the Group 1 comendites and, the late basalt series (LBS) which erupted temporally between the Broad Acres and the Ololbutot centers. The basalts represent a very small percentage of the overall eruptive volume of material at Naivasha (less than 2 percent). The analyzed samples come from four stratigraphic units in close proximity around Ndabibi, Hell's Gate and Akira areas. The earliest units occur as vesicular flows from the Ndabibi plain. These basalts are olivine-plagioclase phyric with the associated hawaiites being sparsely plagioclase phyric. An absolute age of 0.5Ma was estimated for these basalts. The next youngest basalts flows occur as younger tuft cones in the Ndabibi area and are mainly olivine-plagioclase-clinopyroxcene phyric with one purely plagioclase phyric sample. The final phase of activity at Ndabibi resulted in much younger tuft cones consisting of air fall ashes and lapilli tufts. Many of these contain resorbed plagioclase phenocrysts with sample number 120c also being clinopyroxene phyric. The isotopic evidence for the basalt formation is summarized.

Complex layering of the Orange Mountain Basalt: New Jersey, USA

NASA Astrophysics Data System (ADS)

Puffer, John H.; Block, Karin A.; Steiner, Jeffrey C.; Laskowich, Chris

2018-06-01

The Orange Mountain Basalt of New Jersey is a Mesozoic formation consisting of three units: a single lower inflated sheet lobe about 70 m thick (OMB1), a middle pillow basalt about 10 to 20 m thick (OMB2), and an upper compound pahoehoe flow about 20 to 40 m thick (OMB3). The Orange Mountain Basalt is part of the Central Atlantic Magmatic Province. Quarry and road-cut exposures of OMB1 near Paterson, New Jersey, display some unusual layering that is the focus of this study. OMB1 exposures displays the typical upper crust, core, and basal crust layers of sheet lobes but throughout the Patterson area also display distinct light gray layers of microvesicular basalt mineralized with albite directly over the basal crust and under the upper crust. The lower microvesicular layer is associated with mega-vesicular diapirs. We propose that the upper and lower microvesicular layers were composed of viscous crust that was suddenly quenched before it could devolatilize immediately before the solidification of the core. During initial cooling, the bottom of the basal layer was mineralized with high concentrations of calcite and albite during a high-temperature hydrothermal event. Subsequent albitization, as well as zeolite, prehnite, and calcite precipitation events, occurred during burial and circulation of basin brine heated by recurring Palisades magmatism below the Orange Mountain Basalt. Some of the events experienced by the Orange Mountain Basalt are unusual and place constraints on the fluid dynamics of thick flood basalt flows in general. The late penetration of vesicular diapirs through the entire thickness of the flow interior constrains its viscosity and solidification history.

Potential for microbial oxidation of ferrous iron in basaltic glass.

PubMed

Xiong, Mai Yia; Shelobolina, Evgenya S; Roden, Eric E

2015-05-01

Basaltic glass (BG) is an amorphous ferrous iron [Fe(II)]-containing material present in basaltic rocks, which are abundant on rocky planets such as Earth and Mars. Previous research has suggested that Fe(II) in BG can serve as an energy source for chemolithotrophic microbial metabolism, which has important ramifications for potential past and present microbial life on Mars. However, to date there has been no direct demonstration of microbially catalyzed oxidation of Fe(II) in BG. In this study, three different culture systems were used to investigate the potential for microbial oxidation of Fe(II) in BG, including (1) the chemolithoautotrophic Fe(II)-oxidizing, nitrate-reducing "Straub culture"; (2) the mixotrophic Fe(II)-oxidizing, nitrate-reducing organism Desulfitobacterium frappieri strain G2; and (3) indigenous microorganisms from a streambed Fe seep in Wisconsin. The BG employed consisted of clay and silt-sized particles of freshly quenched lava from the TEB flow in Kilauea, Hawaii. Soluble Fe(II) or chemically reduced NAu-2 smectite (RS) were employed as positive controls to verify Fe(II) oxidation activity in the culture systems. All three systems demonstrated oxidation of soluble Fe(II) and/or structural Fe(II) in RS, whereas no oxidation of Fe(II) in BG material was observed. The inability of the Straub culture to oxidize Fe(II) in BG was particularly surprising, as this culture can oxidize other insoluble Fe(II)-bearing minerals such as biotite, magnetite, and siderite. Although the reason for the resistance of the BG toward enzymatic oxidation remains unknown, it seems possible that the absence of distinct crystal faces or edge sites in the amorphous glass renders the material resistant to such attack. These findings have implications with regard to the idea that Fe(II)-Si-rich phases in basalt rocks could provide a basis for chemolithotrophic microbial life on Mars, specifically in neutral-pH environments where acid-promoted mineral dissolution and

Injection and Monitoring at the Wallula Basalt Pilot Project

DOE PAGES

McGrail, B. Peter; Spane, Frank A.; Amonette, James E.; ...

2014-01-01

Continental flood basalts represent one of the largest geologic structures on earth but have received comparatively little attention for geologic storage of CO2. Flood basalt lava flows have flow tops that are porous, permeable, and have large potential capacity for storage of CO2. In appropriate geologic settings, interbedded sediment layers and dense low-permeability basalt rock flow interior sections may act as effective seals allowing time for mineralization reactions to occur. Previous laboratory experiments showed the relatively rapid chemical reaction of CO2-saturated pore water with basalts to form stable carbonate minerals. However, recent laboratory tests with water-saturated supercritical CO2 show thatmore » mineralization reactions occur in this phase as well, providing a second and potentially more important mineralization pathway than was previously understood. Field testing of these concepts is proceeding with drilling of the world’s first supercritical CO2 injection well in flood basalt being completed in May 2009 near the township of Wallula in Washington State and corresponding CO2 injection permit granted by the State of Washington in March 2011. Injection of a nominal 1000 MT of CO2 was completed in August 2013 and site monitoring is in progress. Well logging conducted immediately after injection termination confirmed the presence of CO2 predominantly within the upper flow top region, and showed no evidence of vertical CO2 migration outside the well casing. Shallow soil gas samples collected around the injection well show no evidence of leakage and fluid and gas samples collected from the injection zone show strongly elevated concentrations of Ca, Mg, Mn, and Fe and 13C/18O isotopic shifts that are consistent with basalt-water chemical reactions. If proven viable by this field test and others that are in progress or being planned, major flood basalts in the U.S., India, and perhaps Australia would provide significant additional CO2 storage

Growing magma chambers control the distribution of small-scale flood basalts

PubMed Central

Yu, Xun; Chen, Li-Hui; Zeng, Gang

2015-01-01

Small-scale continental flood basalts are a global phenomenon characterized by regular spatio-temporal distributions. However, no genetic mechanism has been proposed to explain the visible but overlooked distribution patterns of these continental basaltic volcanism. Here we present a case study from eastern China, combining major and trace element analyses with Ar–Ar and K–Ar dating to show that the spatio-temporal distribution of small-scale flood basalts is controlled by the growth of long-lived magma chambers. Evolved basalts (SiO2 > 47.5 wt.%) from Xinchang–Shengzhou, a small-scale Cenozoic flood basalt field in Zhejiang province, eastern China, show a northward younging trend over the period 9.4–3.0 Ma. With northward migration, the magmas evolved only slightly ((Na2O + K2O)/MgO = 0.40–0.66; TiO2/MgO = 0.23–0.35) during about 6 Myr (9.4–3.3 Ma). When the flood basalts reached the northern end of the province, the magmas evolved rapidly (3.3–3.0 Ma) through a broad range of compositions ((Na2O + K2O)/MgO = 0.60–1.28; TiO2/MgO = 0.30–0.57). The distribution and two-stage compositional evolution of the migrating flood basalts record continuous magma replenishment that buffered against magmatic evolution and induced magma chamber growth. Our results demonstrate that the magma replenishment–magma chamber growth model explains the spatio-temporal distribution of small-scale flood basalts. PMID:26581905

Geochronology and petrogenesis of Apollo 14 very high potassium mare basalts

NASA Technical Reports Server (NTRS)

Shih, C.-Y.; Bansal, B. M.; Wiesmann, H.; Nyquist, L. E.; Bogard, D. D.

1986-01-01

Rb-Sr, K-Ar, and Sm-Nd isotopic studies were undertaken for two Apollo 14 very high potassium (VHK) highly radiogenic mare basaltic clasts from breccias 14305 and 14168. Rb-Sr data indicate ages of 3.83 + or - 0.08 b.y., and 3.82 + or - 0.12 b.y. for samples 14305 and 14168 respectively, for lambda(Rb-87) = 0.0 139/b.y. Their corresponding initial Sr-87/Sr-86 ratios are nearly identical, as well as their Ar-39 to Ar-40 age spectra, and it is proposed that they were derived from the same flow. The Sm-Nd isotopic data of whole rock and mineral separates for the two VHK basalts define an internal isochrone age of 3.94 + or - 0.16 b.y. for lambda (Sm-147) = 0.00654/b.y. and an initial Nd-143/Nd-144 of 0.50673 + or - 21. The similarity in isotopic ages suggests that VHK basalts crystallized from a melt about 3.85 b.y. ago. VHK basalts show very large Rb/Sr fractionation but no significant Sm/Nd fractionation at the time of crystallization. The source material had a Rb/Sr ratio similar to those of Apollo 14 high-Al mare basalts and a nearly chrondritic Sm/Nd ratio. Basalt/granite interaction was found to be responsible for the extreme enrichments of Rb/Sr and K/La during the formation of VHK basalts. It is concluded that K, Rb-rich components of granitic wall rocks in the highland crust were selectively introduced into ascending hot high-Al mare basaltic magma upon contact.

[Study of dermatomycosis and survey of pathogens in troops of Hainan area].

PubMed

Suo, J; Li, H; Liang, J; Chen, S; Yu, R

1997-08-01

Subtropical area is the prevalent area of dermatomycosis with natural conditions suptable for the growth and proliferation of fungi causing suterficial dermatomycosis. Dermatomycosis not only brings about certain sufferings to the military personnel in peacetime, but also causes nonbattle loss in manpower in war time. In the present work, a survey of dermatomycosis in Hainan subtropical area of China and isolation of the pathogens were carried out. The results were as follows: The morbidity of superficial dermatomycosis was 34.1% and it was manifested clinically as tinea pedis, tinea versicolor, tinea corporis, tinea axillaris, tinea cruris, etc.; The main pathogen causing dermatomycosis in this area was Trichophyton rubrum which accounted for 50.4% of the pathogens isolated and the next was Trichophyton gypseum which accounted for 20.3%; Trichophyton rubrum could cause dermatomycosis of many sites of the body in this area, but the main lesious were tinea corporis and tinea cruris.

[Molecular characterization of 71 cases of glucose-6-phosphate dehydrogenase deficiency in Hainan province].

PubMed

Huang, Dong-Ai; Wang, Xiao-Ying; Wang, Zheng; Zhou, Dai-Feng; Cai, Wang-Wei

2007-04-01

To molecularly analyze in Han and Li individuals of glucose-6-phosphate dehydrogenase deficiency in Hainan, China. The amplification refractory mutation system (ARMS) was employed to detect G1376T, G1388A and A95G mutations. The coding regions and flanking intronic regions from the second to the thirteenth exons of G6PD gene was analyzed by DNA sequencing to characterize the gene mutations in samples without G1376T, G1388A and A95G mutations. Among 29 Han cases of G6PD deficiency, 11 had G1376T (37.9%), 2 G1388A (6.9%), 1 G1376T and G1388A (3.4%) and 1 G1376T and A95G (3.4%) were identified. Mutations of G1376T, G1388A, A95G and their complex accounted for 51.7% of G6PD deficiency in the Han individuals. Among 42 Li cases of G6PD deficiency, 25 had G1376T (59.5%), 6 G1388A (14.3%), 2 A95G (4.8%), 4 G1376T and G1388A (9.5%), 1 G1376T and A95G (2.4% )were identified. These mutations accounted for 90.5% of the Li individuals. Gene mutation of 18 cases (14 Han and 4 Li individuals) remained unknown. Sequencing results of the 18 samples indicated that one case had a single base of T deletion at nucleotide 636 or 637 in the 5th intron (IVS-5 636 or 637 T del) and two cases had C1311T with IVS-11 T93C mutation. G6PD G1376T and G1388A are the most common mutations in the populations of the Han and Li nationalities in Hainan. The IVS-5 636 or 637 T del mutation is first reported in Chinese, and the complex mutation of G1376T/A95G is first found in the Li nationality.

Novel antimicrobial peptides isolated from the skin secretions of Hainan odorous frog, Odorrana hainanensis.

PubMed

Wang, Hui; Yu, Zhijun; Hu, Yuhong; Li, Fengjiao; Liu, Limeng; Zheng, Hongyuan; Meng, Hao; Yang, Shujie; Yang, Xiaolong; Liu, Jingze

2012-06-01

Long time geographical isolation of Hainan Island from the China continent has resulted in appearance of many novel frog species. As one of them, Hainan odorous frog, Odorrana hainanensis possesses some special antimicrobial peptides distinct from those found in other Odorrana. In this study, three antimicrobial peptides have been purified and characterized from the skin secretion of O. hainanensis. With the similarity to the temporin family, two peptides are characterized by amidated C-terminals, so they are named as temporin-HN1 (AILTTLANWARKFL-NH(2)) and temporin-HN2 (NILNTIINLAKKIL-NH(2)). The third antimicrobial peptide belongs to the brevinin-1 family which is widely distributed in Eurasian ranids, and thus, it is named as brevinin-1HN1 (FLPLIASLAANFVPKIFCKITKKC). Furthermore, after sequencing 68 clones, eight cDNAs encoding antimicrobial peptide precursors were cloned from the skin-derived cDNA library of O. hainanensis. These eight cDNAs can encode seven mature antimicrobial peptides including the above three, as well as brevinin-1V, brevinin-2HS2, odorranain-A6, and odorranain-B1. Twelve different species of microorganisms were chosen, including Gram-positive, Gram-negative and fungi, to test the antimicrobial activities of temporin-HN1, temporin-HN2, brevinin-1HN1, brevinin-1V, and brevinin-2HS2. The result shows that, in addition to their activities against Gram-positive bacteria, temporin-HN1 and temporin-HN2 also possess activities against some Gram-negative bacteria and fungi. However, the two antimicrobial peptides, brevinin-1HN1 and brevinin-1V of the brevinin-1 family have stronger antimicrobial activities than temporin-HN1 and temporin-HN2 of the temporin family. Brevinin-1HN1 possesses activity against Staphylococcus aureus (ATCC25923), Rhodococcus rhodochrous X15, and Slime mould 090223 at the concentration of 1.2 μM. Copyright © 2012 Elsevier Inc. All rights reserved.

Rock types of South Pole-Aitken basin and extent of basaltic volcanism

USGS Publications Warehouse

Pieters, C.M.; Head, J. W.; Gaddis, L.; Jolliff, B.; Duke, M.

2001-01-01

The enormous pre-Nectarian South Pole-Aitken (SPA) basin represents a geophysically and compositionally unique region on the Moon. We present and analyze the mineralogical diversity across this basin and discuss the implications for basin evolution. Rock types are derived from Clementine multispectral data based on diagnostic characteristics of ferrous absorptions in fresh materials. Individual areas are characterized as noritic (dominated by low-Ca pyroxene), gabbroic/basaltic (dominated by high-Ca pyroxene), feldspathic (<3-6% FeO), and olivine-gabbro (dominated by high-Ca pyroxene and olivine). The anorthositic crust has effectively been removed from the interior of the basin. The style of volcanism within the basin extends over several 100 Myr and includes mare basalt and pyroclastic deposits. Several areas of ancient (pre-Orientale) volcanism, or cryptomaria, have also been identified. The nonmare mafic lithology that occurs across the basin is shown to be noritic in composition and is pervasive laterally and vertically. We interpret this to represent impact melt/breccia deposits derived from the lower crust. A few localized areas are identified within the basin that contain more diverse lithologies (gabbro, olivine-gabbro), some of which may represent material from the deepest part of the lower crust and perhaps uppermost mantle involved in the SPA event. Copyright 2001 by the American Geophysical Union.

The Effect of Shock on the Amorphous Component in Altered Basalt

NASA Technical Reports Server (NTRS)

Eckley, S. A.; Wright, S. P.; Rampe, E. B.; Niles, P. B.

2017-01-01

Investigation of the geochemical and mineralogical composition of the Martian surface provides insight into the geologic history of the predominantly basaltic crust. The Chemistry and Mineralogy (CheMin) instrument onboard the Curiosity rover has returned the first X-Ray diffraction data from the Martian surface. However, large proportions (27 +/- 14 with some estimates as high as 50 weight percentage) of an amorphous component have been reported. As a remedy to this problem, mass balance equations using geochemistry, volatile chemistry, and mineralogy have been employed to constrain the geochemistry of the amorphous component. However, "the nature and number of amorphous phases that constitute the amorphous component is not unequivocally known". Multiple hypotheses have been proposed to explain the origin of this amorphous component: Allophane (Al2O); Basaltic glass (Volcanic and impact); Palagonite (Altered basaltic glass); Hisingerite (Fe (sup 3 plus)-bearing phyllosilicate); S/Cl-rich component (sulfates and/or akaganeite); Nanophase ferric oxide component (npOx). Establishing a multi-phase amorphous component from a basaltic precursor that has undergone physical and chemical weathering within geochemical constraints is of paramount importance to better understand the composition of a large portion of the Martian surface (up to 50 weight percentage). Shocked basalts from Lonar Crater in India are valuable analogs for the Martian surface because it is a well-preserved impact crater in a basaltic target. Having undergone pre- and post-shock aqueous alteration, these rocks provide crucial data regarding the effect of shock on the amorphous component in altered basalt. By conducting mass balance equations similar to what has been performed for Gale crater materials, we attempt to calculate the geochemistry of the amorphous component in altered basalts ranging from unshocked to Class 5 (Table 1). This has the potential to reveal the nature and origin (i.e. primary

Carbon storage potential of Columbia River flood basalt

NASA Astrophysics Data System (ADS)

Wells, R. K.; Xiong, W.; Giammar, D.; Skemer, P. A.

2017-12-01

Basalt reservoirs are an important option for sequestering carbon through dissolution of host rock and precipitation of stable carbonate minerals. This study seeks to understand the nature of dissolution and surface roughening processes and their influence on the timing and spatial distribution of carbonation, in static experiments at 150 °C and 100 bar CO2. Intact samples and cores with milled pathways from Ca-rich and Fe-rich Columbia River flood basalt formations were reacted for up to 40 weeks. Experimental specimens were analyzed using SEM-EDS, microprobe, and μCT scanning, Raman spectroscopy, and 2D profilometer to characterize changes in composition and surface roughness. ICP-MS was used to examine bulk fluid chemistry. Initial dissolution of olivine grains results in higher Mg2+ and Fe2+ concentrations within the bulk solution in the first week of reaction. However, once available olivine grains are gone, Ca-rich pyroxene becomes the primary contributor of Ca2+, Mg2+, and Fe2+ within the bulk solution. The complete dissolution of olivine grains resulted in pits up to 200 μm deep. Dissolution of other minerals resulted in the formation of microscale textures, primarily along grain boundaries and fractures. The surface roughness increased by factors of up to 42, while surface area increased 20%. Based on these results, pyroxene is the sustaining contributor of divalent metal cations during dissolution of basalt, and the limited connectivity of olivine and pyroxene grains limits the exposure of new reactive surface areas. Within 6 weeks, aragonite precipitated in Ca-rich basalt samples, while Fe-rich samples precipitated of siderite. The highest concentration of carbonates occurs 1/3 into milled pathways, which simulate dead-end fractures, in low porosity basalts, and near the fracture tip in high porosity basalts. Even at elevated temperatures, the fractures are not blocked nor filled within 40 weeks of reaction. When vesicles are present, carbonates can

Antifriction basalt-plastics based on polypropylene

NASA Astrophysics Data System (ADS)

Bashtannik, P. I.; Ovcharenko, V. G.

1997-05-01

A study is made of the dependence of the mechanical and friction-engineering properties of polypropylene reinforced with basalt fibers on the viscosity of the polymer matrix. It is established that the main factors that determine the mechanical properties of the plastics are the quality of impregnation of the fibers by the binder and the residual length of the reinforcing filler in the composite after extrusion and injection molding. The material that was developed has a low friction coefficient and low rate of wear within a relatively brood range of friction conditions. The basalt-plastics can be used in the rubbing parts of machines and mechanisms subjected to dry friction.

BASALT A: Basaltic Terrains in Idaho and Hawaii as Planetary Analogs for Mars Geology and Astrobiology

NASA Technical Reports Server (NTRS)

Hughes, Scott S.; Haberle, Christopher W.; Nawotniak, Shannon E. Kobs; Sehlke, Alexander; Garry, W. Brent; Elphic, Richard C.; Payler, Sam J.; Stevens, Adam H.; Cockell, Charles S.; Brady, Allyson L.;

New high pressure experiments on sulfide saturation of high-FeO∗ basalts with variable TiO2 contents - Implications for the sulfur inventory of the lunar interior

NASA Astrophysics Data System (ADS)

Ding, Shuo; Hough, Taylor; Dasgupta, Rajdeep

2018-02-01

In order to constrain sulfur concentration in intermediate to high-Ti mare basalts at sulfide saturation (SCSS), we experimentally equilibrated FeS melt and basaltic melt using a piston cylinder at 1.0-2.5 GPa and 1400-1600 °C, with two silicate compositions similar to high-Ti (Apollo 11: A11, ∼11.1 wt.% TiO2, 19.1 wt.% FeO∗, and 39.6 wt.% SiO2) and intermediate-Ti (Luna 16, ∼5 wt.% TiO2, 18.7 wt.% FeO∗, and 43.8 wt.% SiO2) mare basalts. Our experimental results show that SCSS increases with increasing temperature, and decreases with increasing pressure, which are similar to the results from previous experimental studies. SCSS in the A11 melt is systematically higher than that in the Luna 16 melt, which is likely due to higher FeO∗, and lower SiO2 and Al2O3 concentration in the former. Compared to the previously constructed SCSS models, including those designed for high-FeO∗ basalts, the SCSS values determined in this study are generally lower than the predicted values, with overprediction increasing with increasing melt TiO2 content. We attribute this to the lower SiO2 and Al2O3 concentration of the lunar magmas, which is beyond the calibration range of previous SCSS models, and also more abundant FeTiO3 complexes in our experimental melts that have higher TiO2 contents than previous models' calibration range. The formation of FeTiO3 complexes lowers the activity of FeO∗, a FeO∗silicatemelt , and therefore causes SCSS to decrease. To accommodate the unique lunar compositions, we have fitted a new SCSS model for basaltic melts of >5 wt.% FeO∗ and variable TiO2 contents. Using previous chalcophile element partitioning experiments that contained more complex Fe-Ni-S sulfide melts, we also derived an empirical correction that allows SCSS calculation for basalts where the equilibrium sulfides contain variable Ni contents of 10-50 wt.%. At the pressures and temperatures of multiple saturation points, SCSS of lunar magmas with compositions from

Giant Plagioclase "Mosaicrysts" and Other Textures in the Steens Basalt, Columbia River Flood Basalt Province

NASA Astrophysics Data System (ADS)

Grunder, A.; Moore, N. E.; Bohrson, W. A.

2015-12-01

The Steens Basalts (~16.7 Ma), the oldest and most mafic stage of Columbia River flood basalt volcanism, are known for lavas with conspicuous giant plagioclase laths (2 - 5 cm in diameter). Such flows are intercalated with ones that are nearly aphyric or that bear plagioclase (plag) phenocrysts of 0.5-2 cm. Addition textures are distinctive radial, snowflake plag clusters and sandwich glomerocrysts of plag, with olivine trapped between laths. These clusters and glomerocrysts are typically 1, but as large as 3 cm in diameter. Plag composition of all textural types is limited (An76-60). Plag dominates the phenocryst mode; rare flows, mainly low in the section, have olivine > plag and phenocrystic clinopyroxene occurs rarely, and mainly high in the section. Unlike the flows, dikes have few phenocrysts; giant laths are rare and the snowflake texture has not been observed. Giant plag laths are euhedral and make up a few percent to more than 50% of the rock. Many plag megacrysts are made of several plag crystals that form a mosaic, where the constituent crystals are crystallographically distinct and are overgrown with feldspar to make the crystal euhedral. We describe these composite megacrysts as "mosaicrysts". We are exploring magmatic conditions that would trigger oversaturation to spawn rapid growth yielding clusters and overgrowths that form mosaicrysts. Giant plagioclase basalts (so-called GPB) are also described for the Deccan and Emeishan flood basalt provinces attesting to similar magmatic processes. Plag laths typically define strong flow foliation at the flow base, have a swirled distribution in the flow core, and are sparse in the top. Some particularly crystal-rich flows (or sills) have an abrupt transition to a crystal-poor upper few decimeters of the several-m- thick flow. We interpret the crystal-poor top to be the expelled melt from crystal accumulation in the flow, which locally reinjects and is entrained in lower crystal mush.

Explosive eruption of coal and basalt and the end-Permian mass extinction

PubMed Central

Ogden, Darcy E.; Sleep, Norman H.

2012-01-01

The end-Permian extinction decimated up to 95% of carbonate shell-bearing marine species and 80% of land animals. Isotopic excursions, dissolution of shallow marine carbonates, and the demise of carbonate shell-bearing organisms suggest global warming and ocean acidification. The temporal association of the extinction with the Siberia flood basalts at approximately 250 Ma is well known, and recent evidence suggests these flood basalts may have mobilized carbon in thick deposits of organic-rich sediments. Large isotopic excursions recorded in this period are potentially explained by rapid venting of coal-derived methane, which has primarily been attributed to metamorphism of coal by basaltic intrusion. However, recently discovered contemporaneous deposits of fly ash in northern Canada suggest large-scale combustion of coal as an additional mechanism for rapid release of carbon. This massive coal combustion may have resulted from explosive interaction with basalt sills of the Siberian Traps. Here we present physical analysis of explosive eruption of coal and basalt, demonstrating that it is a viable mechanism for global extinction. We describe and constrain the physics of this process including necessary magnitudes of basaltic intrusion, mixing and mobilization of coal and basalt, ascent to the surface, explosive combustion, and the atmospheric rise necessary for global distribution. PMID:22184229

Stratigraphy of Oceanus Procellarum basalts - Sources and styles of emplacement

NASA Technical Reports Server (NTRS)

Whitford-Stark, J. L.; Head, J. W., III

1980-01-01

The basaltic fill of Oceanus Procellarum has been formally subdivided into four lithostratigraphic formations: The Repsold Formation, the Telemann Formation, the Hermann Formation, and the Sharp Formation. The Repsold Formation is composed of high-Ti basalts and pyroclastic deposits with an estimated age of 3.75 + or - 0.05 b.y. and an estimated volume of about 2.1 x 10 to the 5th cu km. This is overlain by the Telemann Formation composed of very low-Ti basalts and pyroclastic deposits with an estimated age of 3.6 + or - 0.2 b.y. and a volume of 4.2 x 10 to the 5th cu km. The Hermann Formation, composed of intermediate basalts with an estimated age of 3.3 + or - 0.3 b.y., represents the next youngest unit with an estimated volume of 2.2 x 10 to the 5th cu km. The youngest materials in Procellarum are the medium-to-high-Ti basalts comprising the Sharp Formation with an estimated age of 2.7 + or - 0.7 b.y. and a volume of 1.8 x 10 to the 4th cu km.

Searching for neuKREEP: An EMP study of Apollo 11 Group A basalts

NASA Technical Reports Server (NTRS)

Jerde, Eric A.; Taylor, Lawrence A.

1993-01-01

The Apollo 11 and 17 landing sites are characterized by the presence of high-Ti basalts (TiO2 greater than 6 percent). The Group A basalts of Apollo 11 have elevated K compositions (greater than 2000 ppm); and are enriched in incompatible trace elements relative to the other types of high-Ti basalt found in the region. These unique basalts also are the youngest of all high-Ti basalts, with an age of 3.56 +/- 0.02 Ga. Recent modelling of the Apollo 11 Group A basalts by Jerde et al. has demonstrated that this unique variety of high-Ti basalt may have formed through fractionation of a liquid with the composition of the Apollo 11 orange glass, coupled with assimilation of evolved material (dubbed neuKREEP and having similarities to lunar quartz monzodiorite). Assimilation of this material would impart its REE signature on the liquid, resulting in the elevated REE abundances observed. Minerals such as whitlockite which contain a large portion of the REE budget can be expected to reflect the REE characteristics of the assimilant. To this end, an examination of the whitlockite present in the Apollo 11 Group A basalts was undertaken to search for evidence of the neuKREEP material assimilated.

On causal links between flood basalts and continental breakup

NASA Astrophysics Data System (ADS)

Courtillot, V.; Jaupart, C.; Manighetti, I.; Tapponnier, P.; Besse, J.

1999-03-01

Temporal coincidence between continental flood basalts and breakup has been noted for almost three decades. Eight major continental flood basalts have been produced over the last 300 Ma. The most recent, the Ethiopian traps, erupted in about 1 Myr at 30 Ma. Rifting in the Red Sea and Gulf of Aden, and possibly East African rift started at about the same time. A second trap-like episode occurred around 2 Ma and formation of true oceanic crust is due in the next few Myr. We find similar relationships for the 60 Ma Greenland traps and opening of the North Atlantic, 65 Ma Deccan traps and opening of the NW Indian Ocean, 132 Ma Parana traps and South Atlantic, 184 Ma Karoo traps and SW Indian Ocean, and 200 Ma Central Atlantic Margin flood basalts and opening of the Central Atlantic Ocean. The 250 Ma Siberian and 258 Ma Emeishan traps seem to correlate with major, if aborted, phases of rifting. Rifting asymmetry, apparent triple junctions and rift propagation (towards the flood basalt area) are common features that may, together with the relative timings of flood basalt, seaward dipping reflector and oceanic crust production, depend on a number of plume- and lithosphere- related factors. We propose a mixed scenario of `active/passive' rifting to account for these observations. In all cases, an active component (a plume and resulting flood basalt) is a pre-requisite for the breakup of a major oceanic basin. But rifting must be allowed by plate-boundary forces and is influenced by pre-existing heterogeneities in lithospheric structure. The best example is the Atlantic Ocean, whose large-scale geometry with three large basins was imposed by the impact points of three mantle plumes.

Implications of Eocene-age Philippine Sea and forearc basalts for initiation and early history of the Izu-Bonin-Mariana arc

NASA Astrophysics Data System (ADS)

Yogodzinski, Gene M.; Bizimis, Michael; Hickey-Vargas, Rosemary; McCarthy, Anders; Hocking, Benjamin D.; Savov, Ivan P.; Ishizuka, Osamu; Arculus, Richard

2018-05-01

Whole-rock isotope ratio (Hf, Nd, Pb, Sr) and trace element data for basement rocks at ocean drilling Sites U1438, 1201 and 447 immediately west of the KPR (Kyushu-Palau Ridge) are compared to those of FAB (forearc basalts) previously interpreted to be the initial products of IBM subduction volcanism. West-of-KPR basement basalts (drill sites U1438, 1201, 447) and FAB occupy the same Hf-Nd and Pb-Pb isotopic space and share distinctive source characteristics with εHf mostly > 16.5 and up to εHf = 19.8, which is more radiogenic than most Indian mid-ocean ridge basalts (MORB). Lead isotopic ratios are depleted, with 206Pb/204Pb = 17.8-18.8 accompanying relatively high 208Pb/204Pb, indicating an Indian-MORB source unlike that of West Philippine Basin plume basalts. Some Sr isotopes show affects of seawater alteration, but samples with 87Sr/86Sr < 0.7034 and εNd > 8.0 appear to preserve magmatic compositions and also indicate a common source for west-of-KPR basement and FAB. Trace element ratios resistant to seawater alteration (La/Yb, Lu/Hf, Zr/Nb, Sm/Nd) in west-of-KPR basement are generally more depleted than normal MORB and so also appear similar to FAB. At Site U1438, only andesite sills intruding sedimentary rocks overlying the basement have subduction-influenced geochemical characteristics (εNd ∼ 6.6, εHf ∼ 13.8, La/Yb > 2.5, Nd/Hf ∼ 9). The key characteristic that unites drill site basement rocks west of KPR and FAB is the nature of their source, which is more depleted in lithophile trace elements than average MORB but with Hf, Nd, and Pb isotope ratios that are common in MORB. The lithophile element-depleted nature of FAB has been linked to initiation of IBM subduction in the Eocene, but Sm-Nd model ages and errorchron relationships in Site U1438 basement indicate that the depleted character of the rocks is a regional characteristic that was produced well prior to the time of subduction initiation and persists today in the source of modern IBM arc

Sulfur concentration of mare basalts at sulfide saturation at high pressures and temperatures-Implications for S in the lunar mantle

NASA Astrophysics Data System (ADS)

Ding, S.; Hough, T.; Dasgupta, R.

2016-12-01

Low estimate of S in the bulk silicate moon (BSM) [e.g., 1] suggests that sulfide in the lunar mantle is likely exhausted during melting. This agrees with estimates of HSE depletion in the BSM [2], but challenges the S-rich core proposed by previous studies [e.g., 3]. A key parameter to constrain the fate of sulfide during mantle melting is the sulfur carrying capacity of the mantle melts (SCSS). However, the SCSS of variably high-Ti lunar basalts at high P-Tare unknown. Basalt-sulfide melt equilibria experiments were run in graphite capsules using a piston cylinder at 1.0-2.5 GPa and 1400-1600 °C, on high-Ti (Apollo11, 11.1 wt.%; [4]) and intermediate-Ti (Luna16, 5 wt.%; [5]) mare basalts. At 1.5 GPa, SCSS of Apollo11 increases from 3940 ppm S to 5860 ppm, as temperature increases from 1400 °C to 1600 °C. And at 1500 °C, SCSS decreases from 5350 ppm S to 3830 ppm, as pressure increases from 1 to 2.5 GPa. SCSS of Luna16 shows a similar P-T dependence. Previous models [e.g., 6] tend to overestimate the SCSS values determined in our study, with the model overprediction increasing with increasing melt TiO2. Consequently, we derive a new SCSS parameterization for high-FeO* silicate melts of variable TiO2content. At multiple saturation points [e.g., 7], the SCSS of primary lunar melts is 3500-5500 ppm. With these values, 0.02-0.05 wt.% sulfide (70-200 ppm S) in the mantle can be consumed by 2-6% melting. In order to generate primary lunar basalts with S of 800-1000 ppm [1], sulfide in the mantle must be exhausted, and the mode of sulfide cannot exceed 0.025 wt.% (100 ppm S). This estimate corresponds with lower end values in the terrestrial mantle and further agrees with previous calculations of HSE depletion in the BSM [2]. [1] Hauri et al.,2015, EPSL; [2] Day et al.,2007, Science; [3] Jing et al., 2014, EPSL; [4] Synder et al.,1992, GCA; [5] Warren & Taylor, 2014, Treatise on Geochemistry; [6] Li & Ripley, 2009, Econ.Geol ; [7] Krawczynski & Grove, 2012, GCA.

Basalt generation at the Apollo 12 site. Part 1: New data, classification, and re-evaluation

NASA Technical Reports Server (NTRS)

Neal, Clive R.; Hacker, Matthew D.; Snyder, Gregory A.; Taylor, Lawrence A.; Liu, Yun-Gang; Schmitt, Roman A.

1994-01-01

New data are reported from five previously unanalyzed Apollo 12 mare basalts that are incorporated into an evaluation of previous petrogenetic models and classification schemes for these basalts. This paper proposes a classification for Apollo 12 mare basalts on the basis of whole-rock Mg# (molar 100*(Mg/(Mg+Fe))) and Rb/Sr ratio (analyzed by isotope dilution), whereby the ilmenite, olivine, and pigeonite basalt groups are readily distinguished from each other. Scrutiny of the Apollo 12 feldspathic 'suite' demonstrates that two of the three basalts previously assigned to this group (12031, 12038, 12072) can be reclassified: 12031 is a plagioclase-rich pigeonite basalt; and 12072 is an olivine basalt. Only basalt 12038 stands out as a unique sample to the Apollo 12 site, but whether this represents a single sample from another flow at the Apollo 12 site or is exotic to this site is equivocal. The question of whether the olivine and pigeonite basalt suites are co-magmatic is addressed by incompatible trace-element chemistry: the trends defined by these two suites when Co/Sm and Sm/Eu ratios are plotted against Rb/Sr ratio demonstrate that these two basaltic types cannot be co-magmatic. Crystal fractionation/accumulation paths have been calculated and show that neither the pigeonite, olivine, or ilmenite basalts are related by this process. Each suite requires a distinct and separate source region. This study also examines sample heterogeneity and the degree to which whole-rock analyses are representative, which is critical when petrogenetic interpretation is undertaken. Sample heterogeneity has been investigated petrographically (inhomogeneous mineral distribution) with consideration of duplicate analyses, and whether a specific sample (using average data) plots consistently upon a fractionation trend when a number of different compostional parameters are considered. Using these criteria, four basalts have been identified where reported analyses are not

Determination of Geochemical Bio-Signatures in Mars-Like Basaltic Environments

PubMed Central

Olsson-Francis, Karen; Pearson, Victoria K.; Steer, Elisabeth D.; Schwenzer, Susanne P.

2017-01-01

Bio-signatures play a central role in determining whether life existed on early Mars. Using a terrestrial basalt as a compositional analog for the martian surface, we applied a combination of experimental microbiology and thermochemical modeling techniques to identify potential geochemical bio-signatures for life on early Mars. Laboratory experiments were used to determine the short-term effects of biota on the dissolution of terrestrial basalt, and the formation of secondary alteration minerals. The chemoorganoheterotrophic bacterium, Burkholderia sp. strain B_33, was grown in a minimal growth medium with and without terrestrial basalt as the sole nutrient source. No growth was detected in the absence of the basalt. In the presence of basalt, during exponential growth, the pH decreased rapidly from pH 7.0 to 3.6 and then gradually increased to a steady-state of equilibrium of between 6.8 and 7.1. Microbial growth coincided with an increase in key elements in the growth medium (Si, K, Ca, Mg, and Fe). Experimental results were compared with theoretical thermochemical modeling to predict growth of secondary alteration minerals, which can be used as bio-signatures, over a geological timescale. We thermochemically modeled the dissolution of the basalt (in the absence of biota) in very dilute brine at 25°C, 1 bar; the pH was buffered by the mineral dissolution and precipitation reactions. Preliminary results suggested that at the water to rock ratio of 1 × 107, zeolite, hematite, chlorite, kaolinite, and apatite formed abiotically. The biotic weathering processes were modeled by varying the pH conditions within the model to adjust for biologic influence. The results suggested that, for a basaltic system, the microbially-mediated dissolution of basalt would result in “simpler” secondary alteration, consisting of Fe-hydroxide and kaolinite, under conditions where the abiotic system would also form chlorite. The results from this study demonstrate that, by using

Determination of Geochemical Bio-Signatures in Mars-Like Basaltic Environments.

PubMed

Olsson-Francis, Karen; Pearson, Victoria K; Steer, Elisabeth D; Schwenzer, Susanne P

2017-01-01

Bio-signatures play a central role in determining whether life existed on early Mars. Using a terrestrial basalt as a compositional analog for the martian surface, we applied a combination of experimental microbiology and thermochemical modeling techniques to identify potential geochemical bio-signatures for life on early Mars. Laboratory experiments were used to determine the short-term effects of biota on the dissolution of terrestrial basalt, and the formation of secondary alteration minerals. The chemoorganoheterotrophic bacterium, Burkholderia sp. strain B_33, was grown in a minimal growth medium with and without terrestrial basalt as the sole nutrient source. No growth was detected in the absence of the basalt. In the presence of basalt, during exponential growth, the pH decreased rapidly from pH 7.0 to 3.6 and then gradually increased to a steady-state of equilibrium of between 6.8 and 7.1. Microbial growth coincided with an increase in key elements in the growth medium (Si, K, Ca, Mg, and Fe). Experimental results were compared with theoretical thermochemical modeling to predict growth of secondary alteration minerals, which can be used as bio-signatures, over a geological timescale. We thermochemically modeled the dissolution of the basalt (in the absence of biota) in very dilute brine at 25°C, 1 bar; the pH was buffered by the mineral dissolution and precipitation reactions. Preliminary results suggested that at the water to rock ratio of 1 × 10 7 , zeolite, hematite, chlorite, kaolinite, and apatite formed abiotically. The biotic weathering processes were modeled by varying the pH conditions within the model to adjust for biologic influence. The results suggested that, for a basaltic system, the microbially-mediated dissolution of basalt would result in "simpler" secondary alteration, consisting of Fe-hydroxide and kaolinite, under conditions where the abiotic system would also form chlorite. The results from this study demonstrate that, by using

Middle Triassic back-arc basalts from the blocks in the Mersin Mélange, southern Turkey: Implications for the geodynamic evolution of the Northern Neotethys

NASA Astrophysics Data System (ADS)

Sayit, Kaan; Bedi, Yavuz; Tekin, U. Kagan; Göncüoglu, M. Cemal; Okuyucu, Cengiz

2017-01-01

The Mersin Mélange is a tectonostratigraphic unit within the allochthonous Mersin Ophiolitic Complex in the Taurides, southern Turkey. This chaotic structure consists of blocks and tectonic slices of diverse origins and ages set in a clastic matrix of Upper Cretaceous age. In this study, we examine two blocks at two different sections characterized by basaltic lava flows alternating with radiolarian-bearing pelagic sediments. The radiolarian assemblage extracted from the mudstone-chert alternation overlying the lavas yields an upper Anisian age (Middle Triassic). The immobile element geochemistry suggests that the lava flows are predominantly characterized by sub-alkaline basalts. All lavas display pronounced negative Nb anomalies largely coupled with normal mid-ocean basalt (N-MORB)-like high field strength element (HFSE) patterns. On the basis of geochemical modelling, the basalts appear to have dominantly derived from spinel-peridotite and pre-depleted spinel-peridotite sources, while some enriched compositions can be explained by contribution of garnet-facies melts from enriched domains. The overall geochemical characteristics suggest generation of these Middle Triassic lavas at an intra-oceanic back-arc basin within the northern branch of Neotethys. This finding is of significant importance, since these rocks may represent the presence of the oldest subduction zone found thus far from the Neotethyan branches. This, in turn, suggests that the rupturing of the Gondwanan lithosphere responsible for the opening of the northern branch of Neotethys should have occurred during the Lower Triassic or earlier.

Ecotourism and community development: case studies from Hainan, China.

PubMed

Stone, Mike; Wall, Geoffrey

2004-01-01

The connections between people, parks, and tourism have received significant attention in recent years, recognizing the potential for mutually beneficial relationships. Ecotourism has been promoted and widely adopted as a strategy for funding conservation initiatives, while at the same time contributing to the socioeconomic development of host communities and providing for quality tourism experiences. Parks are among the most common ecotourism destinations. Employing interviews, observations and secondary sources, this study assesses the current status of ecotourism at two protected areas in Hainan, China, where it is being promoted as a strategy for balancing regional economic growth and conservation objectives. Through an evaluation of the existing tourism-park-community relationships, opportunities and constraints are identified. Ecotourism development was found to be at an early stage at both study sites. Socioeconomic benefits for the local communities have been limited and tourism activity has not contributed revenues towards conservation to date. Community residents, nevertheless, generally support conservation and are optimistic that tourism growth will yield benefits. In light of the study findings and the salient literature, planning direction is offered with the intention of enhancing the capacity of ecotourism to generate benefits for both communities and the parks, and thus contribute to the sustainable development of the region more generally. Lessons derived have broad applicability for ecotourism destinations elsewhere.

Some volcanologic aspects of Columbia River basalt volcanism relevant to the extinction controversy

NASA Technical Reports Server (NTRS)

Swanson, Donald A.

1988-01-01

The Columbia River Basalt Group is the youngest and most thoroughly studied flood-basalt province known; information about it should be relevant to questions about the possible relation of flood-basalt volcanism to mass extinctions. The group has a total volume of about 174,000 cu km and covers an area of about 164,000 sq km. It was erupted between 17.5 and 6 Ma, as measured by K-Ar and Ar-40/Ar-39 dates. Early eruptions formed the Imnaha Basalt. More than 85 percent of the group was produced during a 1.5 my period between 17 and 15.5 Ma, forming the Grande Ronde and greatly subordinate Picture Gorge Basalts. Later flows formed the Wanapum Basalt, which includes the well-known Roza Member, and the Saddle Mountains Basalt. Linear vent systems for many of the flows are known and are located only in the eastern third of the Columbia Plateau. No systematic migration of vents occurred throughout the 11.5 my period of activity; this and other considerations make it unlikely that the province is related to a hot spot. Model calculations based on observations that little cooling occurred during flow of hundreds of kilometers suggest eruption and emplacement durations of a few days. Some voluminous flows occur in all formations, but most such flows apparently were erupted during Grande Ronde time. The eruption and emplacement of more than 1,000 cu km of 1100 C basaltic lava on the surface within several days doubtless had at least local meteorologic effects. Whether the effects were broader can at present only be hypothesized. Grande Ronde Basalt and Picture Gorge Basalts contain moderately common but thin sedimentary interbeds between flows, whereas earlier and later formations contain numerous, locally thick sediment accumulations. Volcaniclastic debris derived from extra-plateau sources commonly occurs in the testbeds.

Grain shape of basaltic ash populations: implications for fragmentation

NASA Astrophysics Data System (ADS)

Schmith, Johanne; Höskuldsson, Ármann; Holm, Paul Martin

2017-02-01

Here, we introduce a new quantitative method to produce grain shape data of bulk samples of volcanic ash, and we correlate the bulk average grain shape with magma fragmentation mechanisms. The method is based on automatic shape analysis of 2D projection ash grains in the size range 125-63 μm. Loose bulk samples from the deposits of six different basaltic eruptions were analyzed, and 20,000 shape measurements for each were obtained within 45 min using the Particle Insight™ dynamic shape analyzer (PIdsa). We used principal component analysis on a reference grain dataset to show that circularity, rectangularity, form factor, and elongation best discriminate between the grain shapes when combined. The grain population data show that the studied eruptive environments produce nearly the same range of grain shapes, although to different extents. Our new shape index (the regularity index (RI)) places an eruption on a spectrum between phreatomagmatic and dry magmatic fragmentation. Almost vesicle-free Surtseyan ash has an RI of 0.207 ± 0.002 (2σ), whereas vesiculated Hawaiian ash has an RI of 0.134 ± 0.001 (2σ). These two samples define the end-member RI, while two subglacial, one lacustrine, and another submarine ash sample show intermediate RIs of 0.168 ± 0.002 (2σ), 0.175 ± 0.002 (2σ), 0.187 ± 0.002 (2σ), and 0.191 ± 0.002 (2σ), respectively. The systematic change in RI between wet and dry eruptions suggests that the RI can be used to assess the relative roles of magmatic vs. phreatomagmatic fragmentation. We infer that both magmatic and phreatomagmatic fragmentation processes played a role in the subglacial eruptions.

Rb-Sr and Sm-Nd chronology and genealogy of mare basalts from the Sea of Tranquility

NASA Technical Reports Server (NTRS)

Papanastassiou, D. A.; Depaolo, D. J.; Wasserburg, G. J.

1977-01-01

Rb-Sr and Sm-Nd ages of two Apollo 11 mare basalts, high-K basalt 10072 and low-K basalt 10062, are reported. Rb-Sr, Sm-Nd, and Ar-40-Ar-39 ages are in good agreement and indicate an extensive time interval for filling of the Sea of Tranquility, presumably by thin lava flows, in agreement with similar observations for the Ocean of Storms. Initial Sr and Nd isotopic compositions on Apollo 11 basalts reveal at least two parent sources producing basalts. The Sm-Nd isotopic data demonstrate that low-K and high-Ti basalts from Apollo 11 and 17 derived from distinct reservoirs, while low-Ti Apollo 15 mare basalt sources have Sm/Nd similar to the sources of Apollo 11 basalts. Groupings of mare basalt based on Ti content and on isotopic data do not coincide.

Northwest Africa 5298: A Basaltic Shergottite

NASA Technical Reports Server (NTRS)

Hui, Hejiu; Peslier, Anne; Lapen, Thomas J.; Brandon, Alan; Shafer, John

2009-01-01

NWA 5298 is a single 445 g meteorite found near Bir Gandouz, Morocco in March 2008 [1]. This rock has a brown exterior weathered surface instead of a fusion crust and the interior is composed of green mineral grains with interstitial dark patches containing small vesicles and shock melts [1]. This meteorite is classified as a basaltic shergottite [2]. A petrologic study of this Martian meteorite is being carried out with electron microprobe analysis and soon trace element analyses by laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS). Oxygen fugacity is calculated from Fe-Ti oxides pairs in the sample. The data from this study constrains the petrogenesis of basaltic shergottites.

Influence of surface modified basalt fiber on strength of cinder lightweight aggregate concrete

NASA Astrophysics Data System (ADS)

Xiao, Liguang; Li, Jiheng; Liu, Qingshun

2017-12-01

In order to improve the bonding and bridging effect between volcanic slag lightweight aggregate concrete cement and basalt fiber, The basalt fiber was subjected to etching and roughening treatment by NaOH solution, and the surface of the basalt fiber was treated with a mixture of sodium silicate and micro-silica powder. The influence of modified basalt fiber on the strength of volcanic slag lightweight aggregate concrete was systematically studied. The experimental results show that the modified basalt fiber volcanic slag lightweight aggregate concrete has a flexural strength increased by 47%, the compressive strength is improved by 16% and the toughness is increased by 27% compared with that of the non-fiber.

Bacterial mineralization patterns in basaltic aquifers: implications for possible life in martian meteorite ALH84001

NASA Technical Reports Server (NTRS)

Thomas-Keprta, K. L.; McKay, D. S.; Wentworth, S. J.; Stevens, T. O.; Taunton, A. E.; Allen, C. C.; Coleman, A.; Gibson, E. K. Jr; Romanek, C. S.

1998-01-01

To explore the formation and preservation of biogenic features in igneous rocks, we have examined the organisms in experimental basaltic microcosms using scanning and transmission electron microscopy. Four types of microorganisms were recognized on the basis of size, morphology, and chemical composition. Some of the organisms mineralized rapidly, whereas others show no evidence of mineralization. Many mineralized cells are hollow and do not contain evidence of microstructure. Filaments, either attached or no longer attached to organisms, are common. Unattached filaments are mineralized and are most likely bacterial appendages (e.g., prosthecae). Features similar in size and morphology to unattached, mineralized filaments are recognized in martian meteorite ALH84001.

Comparison of TIMS and MC-ICP-MS Analyses of Pb Isotopic Compositions on Prehistoric Mauna Loa Basalts: Implications for Plume Source Components

NASA Astrophysics Data System (ADS)

De Jong, J.; Weis, D.; Maerschalk, C.; Rhodes, J. M.

2001-12-01

Recent isotopic studies on Hawaiian lavas have shown the necessity of constraining fractionation for Pb isotopes. This isotopic system presents systematic variations reflecting the presence of different plume components in the source of Hawaiian basalts. We have analyzed a series of 23 tholeiitic Mauna Loa basalts ranging in age from 36,780 to 140 y for their Pb isotopic compositions by TIMS (Micromass Sector 54) and MC-ICP-MS (Nu Plasma) to directly compare results from the same, carefully leached, samples. These analyses indicate an internal precision better than 120 ppm for the MC-ICP-MS Pb ratios, while for the TIMS ratios, it is in the per mil range. This results in a more coherent dataset for the MC-ICP-MS analyses, with the range of 207Pb/204Pb variations decreasing by a factor of 3 and of 208Pb/204Pb ratios by a factor of 1.5. The co-variations between the Pb isotopic data and other geochemical parameters for the Hawaiian lavas are now much stronger and better defined. There are clearly two groups amongst the prehistoric Mauna Loa basalts: one group with higher 87Sr/86Sr (>0.7038) and low 206Pb/204Pb (<18.15) that covers the entire range of Nb/Y (0.31 to 0.51) observed in this volcano, and the other group with low 87Sr/86Sr (<0.7038) and higher 206Pb/204Pb with Nb/Y<0.4. The second group is only present in basalts younger than 3,000 y or older than 24,000 y. The high 87Sr/86Sr group was not sampled in the HSDP I drill core, which covers an age range of 100,000 y. This either reflects a sampling bias, as the upper flow units (<10,000 y) were not sampled for geochemistry, or variations in magma supply. Altogether, Mauna Loa lava flows that are younger than 20,000 y show much more isotopic variation than older flows and there is a nearly continuous transition away from the Kilauea component. This may indicate that the transition between the Mauna Loa and Mauna Kea trends is not as sharp as previously documented. This study shows the importance of reducing the

Mare basalts on the Apennine Front and the mare stratigraphy of the Apollo 15 landing site

NASA Technical Reports Server (NTRS)

Ryder, Graham

1989-01-01

Olivine-normative mare basalts are present on the Apennine Front as crystalline particles and shocked or shock-melted fragments. Picritic basalts, which may be related to the olivine-normative basalts by olivine accumulation, not only occur on the Front but such samples so far recognized are confined to it. Mare volcanic and impact glasses also occur on the Front; all are olivine-normative, though none are quite the equivalent of the typical olivine-normative mare group. The quartz-normative mare basalts are not present (or are extremely rare) on the Front either as crystalline basalts or shocked or glass equivalents. These observations are consistent with the olivine-normative mare basalts being both local and the youngest flows at the site, and the fragments being emplaced on the Front by impacts. The picritic basalts raise the distinct possibility that the olivine-normative basalts also ponded on the Front. An influx of olivine-normative basalts from exotic sources (e.g., a ray from Aristillus) is inconsistent with their abundance, their dominance in the mare soil chemistry, and their age, isotopic, and trace element similarities with the quartz-normative basalts. However, the thermal histories of the olivine-normative basalts require elucidation.

Lunar sample studies. [breccias basalts, and anorthosites

NASA Technical Reports Server (NTRS)

1977-01-01

Lunar samples discussed and the nature of their analyses are: (1) an Apollo 15 breccia which is thoroughly analyzed as to the nature of the mature regolith from which it derived and the time and nature of the lithification process, (2) two Apollo 11 and one Apollo 12 basalts analyzed in terms of chemistry, Cross-Iddings-Pirsson-Washington norms, mineralogy, and petrography, (3) eight Apollo 17 mare basalts, also analyzed in terms of chemistry, Cross-Iddings-Pirsson-Washington norms, mineralogy, and petrography. The first seven are shown to be chemically similar although of two main textural groups; the eighth is seen to be distinct in both chemistry and mineralogy, (4) a troctolitic clast from a Fra Mauro breccia, analyzed and contrasted with other high-temperature lunar mineral assemblages. Two basaltic clasts from the same breccia are shown to have affinities with rock 14053, and (5) the uranium-thorium-lead systematics of three Apollo 16 samples are determined; serious terrestrial-lead contamination of the first two samples is attributed to bandsaw cutting in the lunar curatorial facility.

Electrical conductivity of basaltic and carbonatite melt-bearing peridotites at high pressures: Implications for melt distribution and melt fraction in the upper mantle

NASA Astrophysics Data System (ADS)

Yoshino, Takashi; Laumonier, Mickael; McIsaac, Elizabeth; Katsura, Tomoo

2010-07-01

Electrical impedance measurements were performed on two types of partial molten samples with basaltic and carbonatitic melts in a Kawai-type multi-anvil apparatus in order to investigate melt fraction-conductivity relationships and melt distribution of the partial molten mantle peridotite under high pressure. The silicate samples were composed of San Carlos olivine with various amounts of mid-ocean ridge basalt (MORB), and the carbonate samples were a mixture of San Carlos olivine with various amounts of carbonatite. High-pressure experiments on the silicate and carbonate systems were performed up to 1600 K at 1.5 GPa and up to at least 1650 K at 3 GPa, respectively. The sample conductivity increased with increasing melt fraction. Carbonatite-bearing samples show approximately one order of magnitude higher conductivity than basalt-bearing ones at the similar melt fraction. A linear relationship between log conductivity ( σbulk) and log melt fraction ( ϕ) can be expressed well by the Archie's law (Archie, 1942) ( σbulk/ σmelt = Cϕn) with parameters C = 0.68 and 0.97, n = 0.87 and 1.13 for silicate and carbonate systems, respectively. Comparison of the electrical conductivity data with theoretical predictions for melt distribution indicates that the model assuming that the grain boundary is completely wetted by melt is the most preferable melt geometry. The gradual change of conductivity with melt fraction suggests no permeability jump due to melt percolation at a certain melt fraction. The melt fraction of the partial molten region in the upper mantle can be estimated to be 1-3% and ˜ 0.3% for basaltic melt and carbonatite melt, respectively.

Mineralogy, Petrology and Oxygen Fugacity of the LaPaz Icefield Lunar Basaltic Meteorites and the Origin of Evolved Lunar Basalts

NASA Technical Reports Server (NTRS)

Collins, S. J.; Righter, K.; Brandon, A. D.

2005-01-01

LAP 02205 is a 1.2 kg lunar mare basalt meteorite found in the Lap Paz ice field of Antarctica in 2002 [1]. Four similar meteorites were also found within the same region [1] and all five have a combined mass of 1.9 kg (LAP 02224, LAP 02226, LAP 02436 and LAP 03632, hereafter called the LAP meteorites). The LAP meteorites all contain a similar texture, mineral assemblage, and composition. A lunar origin for these samples comes from O isotopic data for LAP 02205 [1], Fe/Mn ratios of pyroxenes [1-5], and the presence of distinct lunar mineralogy such as Fe metal and baddeleyite. The LAP meteorites may represent an area of the Moon, which has never been sampled by Apollo missions, or by other lunar meteorites. The data from this study will be used to compare the LAP meteorites to Apollo mare basalts and lunar basaltic meteorites, and will ultimately help to constrain their origin.

H2S Injection and Sequestration into Basalt - The SulFix Project

NASA Astrophysics Data System (ADS)

Gudbrandsson, S.; Moola, P.; Stefansson, A.

2014-12-01

Atmospheric H2S emissions are among major environmental concern associated with geothermal energy utilization. It is therefore of great importance for the geothermal power sector to reduce H2S emissions. Known solutions for H2S neutralization are both expensive and include production of elemental sulfur and sulfuric acid that needs to be disposed of. Icelandic energy companies that utilize geothermal power for electricity production have decided to try to find an environmentally friendly and economically feasible solution to reduce the H2S emission, in a joint venture called SulFix. The aim of SulFix project is to explore the possibilities of injecting H2S dissolved in water into basaltic formations in close proximity to the power plants for permanent fixation as sulfides. The formation of sulfides is a natural process in geothermal systems. Due to basalt being rich in iron and dissolving readily at acidic conditions, it is feasible to re-inject the H2S dissolved in water, into basaltic formations to form pyrite. To estimate the mineralization rates of H2S, in the basaltic formation, flow through experiments in columns were conducted at various H2S concentrations, temperatures (100 - 240°C) and both fresh and altered basaltic glass. The results indicate that pyrite rapidly forms during injection into fresh basalt but the precipiation in altered basalt is slower. Three different alteration stages, as a function of distance from inlet, can be observed in the column with fresh basaltic glass; (1) dissolution features along with precipitation, (2) precipitation increases, both sulfides and other secondary minerals and (3) the basalt looks to be unaltered and little if any precipitation is observed. The sulfur has precipitated in the first half of the column and thereafter the solution is possibly close to be supersaturated with respect to the rock. These results indicate that the H2S sequestration into basalt is possible under geothermal conditions. The rate limiting

Basalt-trachybasalt samples in Gale Crater, Mars

NASA Astrophysics Data System (ADS)

Edwards, Peter H.; Bridges, John C.; Wiens, Roger; Anderson, Ryan; Dyar, Darby; Fisk, Martin; Thompson, Lucy; Gasda, Patrick; Filiberto, Justin; Schwenzer, Susanne P.; Blaney, Diana; Hutchinson, Ian

2017-11-01

The ChemCam instrument on the Mars Science Laboratory (MSL) rover, Curiosity, observed numerous igneous float rocks and conglomerate clasts, reported previously. A new statistical analysis of single-laser-shot spectra of igneous targets observed by ChemCam shows a strong peak at 55 wt% SiO2 and 6 wt% total alkalis, with a minor secondary maximum at 47-51 wt% SiO2 and lower alkali content. The centers of these distributions, together with the rock textures, indicate that many of the ChemCam igneous targets are trachybasalts, Mg# = 27 but with a secondary concentration of basaltic material, with a focus of compositions around Mg# = 54. We suggest that all of these igneous rocks resulted from low-pressure, olivine-dominated fractionation of Adirondack (MER) class-type basalt compositions. This magmatism has subalkaline, tholeiitic affinities. The similarity of the basalt endmember to much of the Gale sediment compositions in the first 1000 sols of the MSL mission suggests that this type of Fe-rich, relatively low-Mg#, olivine tholeiite is the dominant constituent of the Gale catchment that is the source material for the fine-grained sediments in Gale. The similarity to many Gusev igneous compositions suggests that it is a major constituent of ancient Martian magmas, and distinct from the shergottite parental melts thought to be associated with Tharsis and the Northern Lowlands. The Gale Crater catchment sampled a mixture of this tholeiitic basalt along with alkaline igneous material, together giving some analogies to terrestrial intraplate magmatic provinces.

Basalt-trachybasalt samples in Gale Crater, Mars

DOE Office of Scientific and Technical Information (OSTI.GOV)

Edwards, Peter H.; Bridges, John C.; Wiens, Roger Craig

The ChemCam instrument on the Mars Science Laboratory (MSL) rover, Curiosity, observed numerous igneous float rocks and conglomerate clasts, reported previously. A new statistical analysis of single-laser-shot spectra of igneous targets observed by ChemCam shows a strong peak at ~55 wt% SiO 2 and 6 wt% total alkalis, with a minor secondary maximum at 47–51 wt% SiO 2 and lower alkali content. The centers of these distributions, together with the rock textures, indicate that many of the ChemCam igneous targets are trachybasalts, Mg# = 27 but with a secondary concentration of basaltic material, with a focus of compositions around Mg#more » = 54. We suggest that all of these igneous rocks resulted from low-pressure, olivine-dominated fractionation of Adirondack (MER) class-type basalt compositions. This magmatism has subalkaline, tholeiitic affinities. The similarity of the basalt endmember to much of the Gale sediment compositions in the first 1000 sols of the MSL mission suggests that this type of Fe-rich, relatively low-Mg#, olivine tholeiite is the dominant constituent of the Gale catchment that is the source material for the fine-grained sediments in Gale. The similarity to many Gusev igneous compositions suggests that it is a major constituent of ancient Martian magmas, and distinct from the shergottite parental melts thought to be associated with Tharsis and the Northern Lowlands. Finally, the Gale Crater catchment sampled a mixture of this tholeiitic basalt along with alkaline igneous material, together giving some analogies to terrestrial intraplate magmatic provinces.« less

Basalt-trachybasalt samples in Gale Crater, Mars

DOE PAGES

Edwards, Peter H.; Bridges, John C.; Wiens, Roger Craig; ...

2017-09-14

The ChemCam instrument on the Mars Science Laboratory (MSL) rover, Curiosity, observed numerous igneous float rocks and conglomerate clasts, reported previously. A new statistical analysis of single-laser-shot spectra of igneous targets observed by ChemCam shows a strong peak at ~55 wt% SiO 2 and 6 wt% total alkalis, with a minor secondary maximum at 47–51 wt% SiO 2 and lower alkali content. The centers of these distributions, together with the rock textures, indicate that many of the ChemCam igneous targets are trachybasalts, Mg# = 27 but with a secondary concentration of basaltic material, with a focus of compositions around Mg#more » = 54. We suggest that all of these igneous rocks resulted from low-pressure, olivine-dominated fractionation of Adirondack (MER) class-type basalt compositions. This magmatism has subalkaline, tholeiitic affinities. The similarity of the basalt endmember to much of the Gale sediment compositions in the first 1000 sols of the MSL mission suggests that this type of Fe-rich, relatively low-Mg#, olivine tholeiite is the dominant constituent of the Gale catchment that is the source material for the fine-grained sediments in Gale. The similarity to many Gusev igneous compositions suggests that it is a major constituent of ancient Martian magmas, and distinct from the shergottite parental melts thought to be associated with Tharsis and the Northern Lowlands. Finally, the Gale Crater catchment sampled a mixture of this tholeiitic basalt along with alkaline igneous material, together giving some analogies to terrestrial intraplate magmatic provinces.« less

Lithospheric control on basaltic magma compositions within a long-lived monogenetic magmatic province: the Cainozoic basalts of eastern Victoria, south-eastern Australia

NASA Astrophysics Data System (ADS)

Price, R. C.; Nicholls, I. A.; Maas, R.

2012-12-01

Basaltic volcanism, ranging in age from Late Jurassic to Holocene and extending across southern Victoria in south-eastern Australia was initiated ~ 95 Ma ago during the earliest stages of rifting associated with opening of the Tasman Sea and Southern Ocean. Volcanic activity has continued sporadically since that time with the only major hiatus being between 18 and 7 Ma (Price et al, 2003). Basaltic rocks with ages in the range 18-90 Ma occur in small lava fields scattered across eastern and south-eastern Victoria and have also been recovered from bore holes in the west of the state. These have in the past been referred to as the "Older Volcanics" to differentiate them from more volumetrically extensive and younger (< 5 Ma) lava fields to the west. Older Volcanics vary in composition from SiO2-undersaturated basanites, basalts and hawaiites through transitional basalts to hypersthene normative tholeiites. Strontium, Nd and Pb isotopic compositions lie between DM and EM 2 in Sr-Nd-Pb isotopic space. They are isotopically similar to Samoan OIB but different from intra-plate rocks of the New Zealand-Antarctic diffuse alkaline magmatic province (DAMP). Trace element compositions are generally characterised by enrichment of Cs, Ba, Rb, Th, U, Nb, K and light REE over heavy REE, Ti, Zr and Y but there is subtle diversity within and between particular lava fields. (La/Yb)n and K/Nb ratios show significant variation and some basalts are relatively enriched in Sr, P and Pb. Potassium and Rb show distinctive relative depletions in some samples and this could be indicating low degree melting with residual phlogopite. When Sr isotope data for Older Volcanics are projected onto an east-west profile they outline distinctive discontinuities that can be related to surface and subsurface structural features within the basement. This has previously been identified in the "Newer Volcanics" (< 5 Ma) province of western Victoria (Price et al., 1997, 2003). Both Proterozoic and

Basalt fiber manufacturing technology and the possibility of its use in dentistry

NASA Astrophysics Data System (ADS)

Karavaeva, E.; Rogozhnikov, A.; Nikitin, V.; Cherepennikov, Yu; Lysakov, A.

2015-11-01

The article touches upon the technology of basalt fiber manufacturing and prospects of its use in dental practice. Two kinds of construction using basalt fiber have been proposed. The first one is a splinting construction for mobile teeth and the second one is the reinforced base for removable plate-denture. The work presents the results of the investigation of physical and mechanical properties of the constructions based on basalt fiber. It also describes the aspects of biomechanical modeling of such constructions in the ANSYS software package. The results of the investigation have proved that applying constructions using basalt fiber is highly promising for prosthetic dentistry practice.

Structural studies in columnar basalts from crystallographic and magnetic fabrics

NASA Astrophysics Data System (ADS)

Tiphaine, Boiron; Jérôme, Bascou; Pierre, Camps; Eric, Ferre; Claire, Maurice; Bernard, Guy; Marie-Christine, Gerbe

2010-05-01

The purpose of this study is to better characterize the columnar and the associated microstructure development in basalt flows. The thermal contraction (O'Reilly, 1879) is the main hypothesis to explain the columnar formation. However, neither the structures which appear in basalt flow constituted of three levels (Tomkeieff, 1940) nor circular and radial structures within the prisms (for which weathering nor fracturing can account for) can be explained by the thermal contraction theory alone. An early structuring process during solidification (Guy and Le Coze, 1990) could play for a part that must be discussed (Guy, 2010). We studied two recent basalt flows (75 000 years) from the French Massif Central, in which the three flow levels are clearly observed. In the first basalt flow (La Palisse, Ardèche), the emission centre and the flow direction are known. In the second one (Saint Arcons d'Allier, Haute Loire), the prismatic columns are particularly well developed. In order to characterize the flow structure at different scales, from the flow to the grain scale, anisotropy of magnetic susceptibility (AMS) measurements were performed. The AMS data were coupled with crystallographic preferred orientation measurements of magnetite, plagioclase and clinopyroxene using Electron Backscattered Diffraction (EBSD) and image analyses from perpendicular thin sections. Magnetic mineralogy studies of the La Palisse basalts, in particular the thermomagnetic curves, indicate that the main carrier of AMS is high-Ti titanomagnetite (Tc≈130°C). AMS measurements of about a hundred samples show a higher degree of AMS (P parameter) in the middle level in comparison to the base. Inversely, the bulk magnetic susceptibility (Km) is higher at the flow base. Distinctive parameters for the different levels of the basaltic flows could be then provided by AMS measurements.. Moreover, the comparison between AMS and EBSD data indicate that the magnetic susceptibility carried by the magnetic

Comparative Planetary Mineralogy: Co, Ni Systematics in Chromite from Planetary Basalts

NASA Technical Reports Server (NTRS)

Karner, J. M.; Shearer, C. K.; Papike, J. J.; Righter,K.

2005-01-01

Spinel is a minor but important phase in planetary basalts because its variable composition often reflects basalt petrogenesis. For example, complicated zoning trends in spinel can give clues to melt evolution [1], and V concentrations in chromite lend insight into magma oxygen fugacity (fO2) conditions [2]. Nickel and Co are two elements that are commonly used as a measure of melt fractionation, and their partitioning between olivine and melt is fairly well understood. Less clear is their partitioning into spinel, although [3] has explored Ni and Co systematics in experimental charges. This study documents Ni and Co behavior in early crystallizing spinel (chromite) from several planetary basalts in an attempt to compare our results with [3], and also gain insight into basalt evolution on the three planets.

Submarine Basaltic Glass Colonization by the Heterotrophic Fe(II)-Oxidizing and Siderophore-Producing Deep-Sea Bacterium Pseudomonas stutzeri VS-10: The Potential Role of Basalt in Enhancing Growth

PubMed Central

Sudek, Lisa A.; Wanger, Greg; Templeton, Alexis S.; Staudigel, Hubert; Tebo, Bradley M.

2017-01-01

Phylogenetically and metabolically diverse bacterial communities have been found in association with submarine basaltic glass surfaces. The driving forces behind basalt colonization are for the most part unknown. It remains ambiguous if basalt provides ecological advantages beyond representing a substrate for surface colonization, such as supplying nutrients and/or energy. Pseudomonas stutzeri VS-10, a metabolically versatile bacterium isolated from Vailulu’u Seamount, was used as a model organism to investigate the physiological responses observed when biofilms are established on basaltic glasses. In Fe-limited heterotrophic media, P. stutzeri VS-10 exhibited elevated growth in the presence of basaltic glass. Diffusion chamber experiments demonstrated that physical attachment or contact of soluble metabolites such as siderophores with the basaltic glass plays a pivotal role in this process. Electrochemical data indicated that P. stutzeri VS-10 is able to use solid substrates (electrodes) as terminal electron donors and acceptors. Siderophore production and heterotrophic Fe(II) oxidation are discussed as potential mechanisms enhancing growth of P. stutzeri VS-10 on glass surfaces. In correlation with that we discuss the possibility that metabolic versatility could represent a common and beneficial physiological trait in marine microbial communities being subject to oligotrophic and rapidly changing deep-sea conditions. PMID:28344573

Petrochemistry of a xenolith-bearing Neogene alkali olivine basalt from northeastern Iran

NASA Astrophysics Data System (ADS)

Saadat, Saeed; Stern, Charles R.

2012-05-01

A small isolated Neogene, possibly Quaternary, monogenetic alkali olivine basalt cone in northeastern Iran contains both mantle peridotite and crustal gabbroic xenoliths, as well as plagioclase megacrysts. The basaltic magma rose to the surface along pathways associated with local extension at the junction between the N-S right-lateral and E-W left-lateral strike slip faults that form the northeastern boundary of the Lut microcontinental block. This basalt is enriched in LREE relative to HREE, and has trace-element ratios similar to that of oceanic island basalts (OIB). Its 87Sr/86Sr (0.705013 to 0.705252), 143Nd/144Nd (0.512735 to 0.512738), and Pb isotopic compositions all fall in the field of OIB derived from enriched (EM-2) mantle. It formed by mixing of small melt fractions from both garnet-bearing asthenospheric and spinel-facies lithospheric mantle. Plagioclase (An26-32) megacrysts, up to 4 cm in length, have euhedral crystal faces and show no evidence of reaction with the host basalt. Their trace-element concentrations suggest that these megacrysts are co-genetic with the basalt host, although their 87Sr/86Sr (0.704796) and 143Nd/144Nd (0.512687) ratios are different than this basalt. Round to angular, medium-grained granoblastic meta-igneous gabbroic xenoliths, ranging from ~ 1 to 6 cm in dimension, are derived from the lower continental crust. Spinel-peridotite xenoliths equilibrated in the subcontinental lithosphere at depths of 30 to 60 km and temperatures of 965 °C to 1065 °C. These xenoliths do not preserve evidence of extensive metasomatic enrichment as has been inferred for the mantle below the Damavand volcano further to the west in north-central Iran, and clinopyroxenes separated from two different mantle xenoliths have 87Sr/86Sr (0.704309 and 0.704593) and 143Nd/144Nd (0.512798) ratios which are less radiogenic than either their host alkali basalt or Damavand basalts, implying significant regional variations in the composition and extent of

Nutrient dynamics in tropical rivers, estuarine-lagoons, and coastal ecosystems along the eastern Hainan Island

NASA Astrophysics Data System (ADS)

Li, R. H.; Liu, S. M.; Li, Y. W.; Zhang, G. L.; Ren, J. L.; Zhang, J.

2013-06-01

Nutrient dynamics were studied along the eastern Hainan Island based on field observations during 2006-2009, to understand nutrient biogeochemical processes and to have an overview of human perturbations on coastal ecosystems in this tropical region. The concentrations of nutrients in the rivers had seasonal variations enriched with dissolved inorganic nitrogen (DIN). High riverine concentrations of nitrate were mainly originated from agricultural fertilizer input. The ratios of DIN : PO43- ranged from 37 to 1063, suggesting preferential PO43- relative to nitrogen in the rivers. The areal yields of dissolved silicate (DSi) varied from 76 to 448 × 103 mol km-2 yr-1 due to erosion over the drainage area, inducing high levels of DSi among worldwide tropical systems. Aquaculture ponds contained high concentrations of NH4+ (up to 157 μM) and DON (up to 130 μM). Particulate phosphorus concentrations (0.5 ∼1.4 μM) were in lower level comparied with estuaries around the world. Particulate silicate levels in rivers and lagoons were lower than global average level. Nutrient biogeochemistry in coastal areas were affected by human activities (e.g. aquaculture, agriculture), as well as natural events such as typhoon. Nutrient concentrations were low because open sea water dispersed land-derived nutrients. Nutrient budgets were built based on a steady-state box model, which showed that riverine fluxes would be magnified by estuarine processes (e.g. regeneration, desorption) in the Wenchanghe/Wenjiaohe Estuary, Wanquan River estuary, and the Laoyehai Lagoon except in the Xiaohai Lagoon. Riverine and groundwater input were the major sources of nutrients to the Xiaohai Lagoon and the Laiyehai Lagoon, respectively. Riverine input and aquaculture effluent were the major sources of nutrients to the eastern coastal of Hainan Island. Nutrient inputs to the coastal ecosystem can be increased by typhoon-induced runoff of rainwater, and phytoplankton bloom in the sea would be

Subseafloor basalts as fungal habitats

NASA Astrophysics Data System (ADS)

Ivarsson, M.; Bengtson, S.

2013-12-01

The oceanic crust makes up the largest potential habitat for life on Earth, yet next to nothing is known about the abundance, diversity and ecology of its biosphere. Our understanding of the deep biosphere of subseafloor crust is, with a few exceptions, based on a fossil record. Surprisingly, a majority of the fossilized microorganisms have been interpreted or recently re-interpreted as remnants of fungi rather than prokaryotes. Even though this might be due to a bias in fossilization the presence of fungi in these settings can not be neglected. We have examined fossilized microorganisms in drilled basalt samples collected at the Emperor Seamounts in the Pacific Ocean. Synchrotron-radiation X-ray tomography microscopy (SRXTM) studies has revealed a complex morphology and internal structure that corresponds to characteristic fungal morphology. Chitin was detected in the fossilized hyphae, which is another strong argument in favour of a fungal interpretation. Chitin is absent in prokaryotes but a substantial constituent in fungal cell walls. The fungal colonies consist of both hyphae and yeast-like growth states as well as resting structures and possible fruit bodies, thus, the fungi exist in vital colonies in subseafloor basalts. The fungi have also been involved in extensive weathering of secondary mineralisations. In terrestrial environments fungi are known as an important geobiological agent that promotes mineral weathering and decomposition of organic matter, and they occur in vital symbiosis with other microorganisms. It is probable to assume that fungi would play a similar role in subseafloor basalts and have great impact on the ecology and on biogeochemical cycles in such environments.

Derivation of Apollo 14 High-Al Basalts at Discrete Times: Rb-Sr Isotopic Constraints

NASA Technical Reports Server (NTRS)

Hui. Hejiu; Neal, Clive, R.; Shih, Chi-Yu; Nyquist, Laurence E.

2012-01-01

Pristine Apollo 14 (A-14) high-Al basalts represent the oldest volcanic deposits returned from the Moon [1,2] and are relatively enriched in Al2O3 (>11 wt%) compared to other mare basalts (7-11 wt%). Literature Rb-Sr isotopic data suggest there are at least three different eruption episodes for the A-14 high-Al basalts spanning the age range approx.4.3 Ga to approx.3.95 Ga [1,3]. Therefore, the high-Al basalts may record lunar mantle evolution between the formation of lunar crust (approx.4.4 Ga) and the main basin-filling mare volcanism (<3.85 Ga) [4]. The high-Al basalts were originally classified into five compositional groups [5,6], and then regrouped into three with a possible fourth comprising 14072 based on the whole-rock incompatible trace element (ITE) ratios and Rb-Sr radiometric ages [7]. However, Rb-Sr ages of these basalts from different laboratories may not be consistent with each other because of the use of different 87Rb decay constants [8] and different isochron derivation methods over the last four decades. This study involved a literature search for Rb-Sr isotopic data previously reported for the high-Al basalts. With the re-calculated Rb-Sr radiometric ages, eruption episodes of A-14 high-Al basalts were determined, and their petrogenesis was investigated in light of the "new" Rb-Sr isotopic data and published trace element abundances of these basalts.

Prokaryotic diversity, distribution, and insights into their role in biogeochemical cycling in marine basalts

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mason, Olivia U.; Di Meo-Savoie, Carol A.; Van Nostrand, Joy D.

2008-09-30

We used molecular techniques to analyze basalts of varying ages that were collected from the East Pacific Rise, 9 oN, from the rift axis of the Juan de Fuca Ridge, and from neighboring seamounts. Cluster analysis of 16S rDNA Terminal Restriction Fragment Polymorphism data revealed that basalt endoliths are distinct from seawater and that communities clustered, to some degree, based on the age of the host rock. This age-based clustering suggests that alteration processes may affect community structure. Cloning and sequencing of bacterial and archaeal 16S rRNA genes revealed twelve different phyla and sub-phyla associated with basalts. These include themore » Gemmatimonadetes, Nitrospirae, the candidate phylum SBR1093 in the c, andin the Archaea Marine Benthic Group B, none of which have been previously reported in basalts. We delineated novel ocean crust clades in the gamma-Proteobacteria, Planctomycetes, and Actinobacteria that are composed entirely of basalt associated microflora, and may represent basalt ecotypes. Finally, microarray analysis of functional genes in basalt revealed that genes coding for previously unreported processes such as carbon fixation, methane-oxidation, methanogenesis, and nitrogen fixation are present, suggesting that basalts harbor previously unrecognized metabolic diversity. These novel processes could exert a profound influence on ocean chemistry.« less

Basaltic caves at Craters of the Moon National Monument and Preserve as analogs for Mars

NASA Astrophysics Data System (ADS)

Hinman, N. W.; Richardson, C. D.; McHenry, L.; Scott, J. R.

2010-12-01

minerals were not included as no iron was detected in solution. Results compared well with evaporation of solutions generated by simulating chemical weathering of minerals found in the basalt; this approach allowed iron minerals to precipitate during evaporation because minerals in the basalt contained iron. The minerals modeled upon evaporation included the minerals observed in the actual deposits - hematite, calcite, and quartz. Na-minerals neared saturation in simulations but were normally not saturated, leaving open the question of their origin. One possible explanation for the presence of Na-minerals could be seasonal ice formation in the caves followed by sublimation, leaving more concentrated solutions behind than were sampled here. A seasonal model for mineral deposition in caves could be relevant to deposits in martian caves. While the formation mechanism for the secondary minerals at COM is not completely understood, the presence of secondary minerals that harbor organic compounds in a cave environment that may be analogous to Mar has implications for where to search for signs of martian life.

Wallula Basalt Pilot Demonstration Project: Post-injection Results and Conclusions

DOE Office of Scientific and Technical Information (OSTI.GOV)

McGrail, Bernard Pete; Schaef, Herbert T.; Spane, Frank A.

Deep underground geologic formations are emerging as a reasonable option for long-term storage of CO 2, including large continental flood basalt formations. At the GHGT-11 and GHGT-12 conferences, progress was reported on the initial phases for Wallula Basalt Pilot demonstration test (located in Eastern Washington state), where nearly 1,000 metric tons of CO 2 were injected over a 3-week period during July/August 2013. The target CO 2 injection intervals were two permeable basalt interflow reservoir zones with a combined thickness of ~20 m that occur within a layered basalt sequence between a depth of 830-890 m below ground surface. Duringmore » the two-year post-injection period, downhole fluid samples were periodically collected during this post-injection monitoring phase, coupled with limited wireline borehole logging surveys that provided indirect evidence of on-going chemical geochemical reactions/alterations and CO 2 disposition. A final detailed post-closure field characterization program that included downhole fluid sampling, and performance of hydrologic tests and wireline geophysical surveys. Included as part of the final wireline characterization activities was the retrieval of side-wall cores from within the targeted injection zones. These cores were examined for evidence of in-situ mineral carbonization. Visual observations of the core material identified small globular nodules, translucent to yellow in color, residing within vugs and small cavities of the recovered basalt side-wall cores, which were not evident in pre-injection side-wall cores obtained from the native basalt formation. Characterization by x-ray diffraction identified these nodular precipitates as ankerite, a commonly occurring iron and calcium rich carbonate. Isotopic characterization (δ 13C, δ 18O) conducted on the ankerite nodules indicate a distinct isotopic signature that is closely aligned with that of the injected CO 2. Both the secondary mineral nodules and injected CO 2

Wallula Basalt Pilot Demonstration Project: Post-injection Results and Conclusions

DOE PAGES

McGrail, Bernard Pete; Schaef, Herbert T.; Spane, Frank A.; ...

2017-08-18

Deep underground geologic formations are emerging as a reasonable option for long-term storage of CO 2, including large continental flood basalt formations. At the GHGT-11 and GHGT-12 conferences, progress was reported on the initial phases for Wallula Basalt Pilot demonstration test (located in Eastern Washington state), where nearly 1,000 metric tons of CO 2 were injected over a 3-week period during July/August 2013. The target CO 2 injection intervals were two permeable basalt interflow reservoir zones with a combined thickness of ~20 m that occur within a layered basalt sequence between a depth of 830-890 m below ground surface. Duringmore » the two-year post-injection period, downhole fluid samples were periodically collected during this post-injection monitoring phase, coupled with limited wireline borehole logging surveys that provided indirect evidence of on-going chemical geochemical reactions/alterations and CO 2 disposition. A final detailed post-closure field characterization program that included downhole fluid sampling, and performance of hydrologic tests and wireline geophysical surveys. Included as part of the final wireline characterization activities was the retrieval of side-wall cores from within the targeted injection zones. These cores were examined for evidence of in-situ mineral carbonization. Visual observations of the core material identified small globular nodules, translucent to yellow in color, residing within vugs and small cavities of the recovered basalt side-wall cores, which were not evident in pre-injection side-wall cores obtained from the native basalt formation. Characterization by x-ray diffraction identified these nodular precipitates as ankerite, a commonly occurring iron and calcium rich carbonate. Isotopic characterization (δ 13C, δ 18O) conducted on the ankerite nodules indicate a distinct isotopic signature that is closely aligned with that of the injected CO 2. Both the secondary mineral nodules and injected CO 2

The Effect of Adhesion Interaction on the Mechanical Properties of Thermoplastic Basalt Plastics

NASA Astrophysics Data System (ADS)

Bashtannik, P. I.; Kabak, A. I.; Yakovchuk, Yu. Yu.

2003-01-01

The effect of temperature, adhesion time, and surface treatment of a reinforcing filler on the mechanical properties of thermoplastic basalt plastics based on a high-density polyethylene and a copolymer of 1,3,5-trioxane with 1,3-dioxolan is investigated. An extreme dependence for the adhesive strength in a thermoplastic-basalt fiber system is established and its effect on the mechanical properties of basalt plastics and the influence of the adhesion contact time on the adhesive strength in the system are clarified. The surface modification of basalt fibers in acidic and alkaline media intensifies the adhesion of thermoplastics to them owing to a more developed surface of the reinforcing fibers after etching. It is found that the treatment in the acidic medium is more efficient and considerably improves the mechanical properties of basalt plastics.

Viscous flow behavior of tholeiitic and alkaline Fe-rich martian basalts

NASA Astrophysics Data System (ADS)

Chevrel, Magdalena Oryaëlle; Baratoux, David; Hess, Kai-Uwe; Dingwell, Donald B.

2014-01-01

The chemical compositions of martian basalts are enriched in iron with respect to terrestrial basalts. Their rheology is poorly known and liquids of this chemical composition have not been experimentally investigated. Here, we determine the viscosity of five synthetic silicate liquids having compositions representative of the diversity of martian volcanic rocks including primary martian mantle melts and alkali basalts. The concentric cylinder method has been employed between 1500 °C and the respective liquidus temperatures of these liquids. The viscosity near the glass transition has been derived from calorimetric measurements of the glass transition. Although some glass heterogeneity limits the accuracy of the data near the glass transition, it was nevertheless possible to determine the parameters of the non-Arrhenian temperature-dependence of viscosity over a wide temperature range (1500 °C to the glass transition temperature). At superliquidus conditions, the martian basalt viscosities are as low as those of the Fe-Ti-rich lunar basalts, similar to the lowest viscosities recorded for terrestrial ferrobasalts, and 0.5 to 1 order of magnitude lower than terrestrial tholeiitic basalts. Comparison with empirical models reveals that Giordano et al. (2008) offers the best approximation, whereas the model proposed by Hui and Zhang (2007) is inappropriate for the compositions considered. The slightly lower viscosities exhibited by the melts produced by low degree of mantle partial melting versus melts produced at high degree of mantle partial melting (likely corresponding to the early history of Mars), is not deemed sufficient to lead to viscosity variations large enough to produce an overall shift of martian lava flow morphologies over time. Rather, the details of the crystallization sequence (and in particular the ability of some of these magmas to form spinifex texture) is proposed to be a dominant effect on the viscosity during martian lava flow emplacement and

Back-arc basalts from the Loncopue graben (Province of Neuquen, Argentina)

NASA Astrophysics Data System (ADS)

Varekamp, J. C.; Hesse, A.; Mandeville, C. W.

2010-11-01

Young basaltic back-arc volcanoes occur east of the main Andes chain at about 37.5°-39°S in the Loncopue graben, Province of Neuquen, Argentina. These olivine-rich basalts and trachybasalts have up to 8% MgO, with high Ni and Cr contents, but highly variable incompatible element concentrations. Mafic lava flows and cinder cones at the southern end of the graben lack phenocrystic plagioclase. The northern samples have relative Ta-Nb depletions and K, Pb and LREE enrichment. These samples strongly resemble rocks of the nearby arc volcanoes Copahue and Caviahue, including their Fe-Ti enrichment relative to the main Andes arc rocks. The Sr, Nd and Pb isotope ratios show that the source regions of these back-arc basalts are enriched in subducted components that were depleted in the aqueous mobile elements such as Cs, Sr and Ba as a result of prior extractions from the subducted complex below the main arc. Some mafic flows show slightly low 206Pb/ 204Pb and 143Nd/ 144Nd values as well as incompatible trace element ratios similar to southern Patagonia plateau back-arc basalts, suggesting contributions from an EM1 mantle source. Geothermometry and barometry suggest that the basalts crystallized and fractionated small amounts of olivine and spinel at ˜ 35 km depth at temperatures of 1170-1220 °C, at about QFM + 0.5 to QFM + 1 with 1-2% H 2O, and then rose rapidly to the surface. The Loncopue graben back-arc basalts are transitional in composition between the South Patagonia back-arc plateau basalts and the Caviahue and Copahue arc volcanoes to the northwest. The EM1 source endmember is possibly the subcontinental lithospheric mantle. Strong variations in incompatible element enrichment and isotopic compositions between closely spaced cinder cones and lava flows suggest a heterogeneous mantle source for the Loncopue graben volcanics.

Bacterial mineralization patterns in basaltic aquifers: Implications for possible life in Martian meteorite ALH84001

DOE Office of Scientific and Technical Information (OSTI.GOV)

Thomas-Keprta, K.L.; Wentworth, S.J.; Allen, C.C.

To explore the formation and preservation of biogenic features in igneous rocks, the authors have examined the organisms in experimental basaltic microcosms using scanning and transmission electron microscopy. Four types of microorganisms were recognized on the basis of size, morphology, and chemical composition. Some of the organisms mineralized rapidly, whereas others show no evidence of mineralization. Many mineralized cells are hollow and do not contain evidence of microstructure. Filaments, either attached or no longer attached to organisms, are common. Unattached filaments are mineralized and are most likely bacterial appendages (e.g., prosthecae). Features similar in size and morphology to unattached, mineralizedmore » filaments are recognized in martial meteorite ALH84001.« less

Submarine basaltic fountain eruptions in a back-arc basin during the opening of the Japan Sea

NASA Astrophysics Data System (ADS)

Hosoi, Jun; Amano, Kazuo

2017-11-01

Basaltic rock generated during the middle Miocene opening of the Japan Sea, is widely distributed on the back-arc side of the Japanese archipelago. Few studies have investigated on submarine volcanism related to opening of the Japan Sea. The present study aimed to reconstruct details of the subaqueous volcanism that formed the back-arc basin basalts (BABB) during this event, and to discuss the relationship between volcanism and the tectonics of back-arc opening, using facies analyses based on field investigation. The study area of the southern Dewa Hills contains well-exposed basalt related to the opening of the Japan Sea. Five types of basaltic rock facies are recognized: (1) coherent basalt, (2) massive platy basalt, (3) jigsaw-fit monomictic basaltic breccia, (4) massive or stratified coarse monomictic basaltic breccia with fluidal clasts, and (5) massive or stratified fine monomictic basaltic breccia. The basaltic rocks are mainly hyaloclastite. Based on facies distributions, we infer that volcanism occurred along fissures developed mainly at the center of the study area. Given that the rocks contain many fluidal clasts, submarine lava fountaining is inferred to have been the dominant eruption style. The basaltic rocks are interpreted as the products of back-arc volcanism that occurred by tensional stress related to opening of the Japan Sea, which drove strong tectonic subsidence and active lava fountain volcanism.

Lunar Mare Basalts as Analogues for Martian Volcanic Compositions: Evidence from Visible, Near-IR, and Thermal Emission Spectroscopy

NASA Technical Reports Server (NTRS)

Graff, T. G.; Morris, R. V.; Christensen, P. R.

2003-01-01

The lunar mare basalts potentially provide a unique sample suite for understanding the nature of basalts on the martian surface. Our current knowledge of the mineralogical and chemical composition of the basaltic material on Mars comes from studies of the basaltic martian meteorites and from orbital and surface remote sensing observations. Petrographic observations of basaltic martian meteorites (e.g., Shergotty, Zagami, and EETA79001) show that the dominant phases are pyroxene (primarily pigeonite and augite), maskelynite (a diaplectic glass formed from plagioclase by shock), and olivine [1,2]. Pigeonite, a low calcium pyroxene, is generally not found in abundance in terrestrial basalts, but does often occur on the Moon [3]. Lunar samples thus provide a means to examine a variety of pigeonite-rich basalts that also have bulk elemental compositions (particularly low-Ti Apollo 15 mare basalts) that are comparable to basaltic SNC meteorites [4,5]. Furthermore, lunar basalts may be mineralogically better suited as analogues of the martian surface basalts than the basaltic martian meteorites because the plagioclase feldspar in the basaltic Martian meteorites, but not in the lunar surface basalts, is largely present as maskelynite [1,2]. Analysis of lunar mare basalts my also lead to additional endmember spectra for spectral libraries. This is particularly important analysis of martian thermal emission spectra, because the spectral library apparently contains a single pigeonite spectrum derived from a synthetic sample [6].

Mare basalt magma source region and mare basalt magma genesis

DOE Office of Scientific and Technical Information (OSTI.GOV)

Binder, A.B.

1982-11-15

Given the available data, we find that the wide range of mare basaltic material characteristics can be explained by a model in which: (1) The mare basalt magma source region lies between the crust-mantle boundary and a maximum depth of 200 km and consists of a relatively uniform peridotite containing 73--80% olivine, 11--14% pyroxene, 4--8% plagioclase, 0.2--9% ilmenite and 1--1.5% chromite. (2) The source region consists of two or more density-graded rhythmic bands, whose compositions grade from that of the very low TiO/sub 2/ magma source regions (0.2% ilmenite) to that of the very high TiO/sub 2/ magma source regionsmore » (9% ilmenite). These density-graded bands are proposed to have formed as co-crystallizing olivine, pyroxene, plagioclase, ilmenite, and chromite settled out of a convecting magma (which was also parental to the crust) in which these crystals were suspended. Since the settling rates of the different minerals were governed by Stoke's law, the heavier minerals settled out more rapidly and therefore earlier than the lighter minerals. Thus the crystal assemblages deposited nearest the descending side of each convection cell were enriched in heavy ilmenite and chromite with respect to lighter olivine and pyroxene and very much lighter plagioclase. The reverse being the case for those units deposited near the ascending sides of the convection cells.« less

Experimentally reproduced textures and mineral chemistries of high-titanium mare basalts

NASA Technical Reports Server (NTRS)

Usselman, T. M.; Lofgren, G. E.; Williams, R. J.; Donaldson, C. H.

1975-01-01

Many of the textures, morphologies, and mineral chemistries of the high-titanium mare basalts have been experimentally duplicated using single-stage cooling histories. Lunar high-titanium mare basalts are modeled in a 1 m thick gravitationally differentiating flow based on cooling rates, thermal models, and modal olivine contents. The low-pressure equilibrium phase relations of a synthetic high-titanium basalt composition were investigated as a function of oxygen fugacity, and petrographic criteria are developed for the recognition of phenocrysts which were present in the liquid at the time of eruption.

Source, evolution and emplacement of Permian Tarim Basalts: Evidence from U-Pb dating, Sr-Nd-Pb-Hf isotope systematics and whole rock geochemistry of basalts from the Keping area, Xinjiang Uygur Autonomous region, northwest China

NASA Astrophysics Data System (ADS)

Zhang, Dayu; Zhou, Taofa; Yuan, Feng; Jowitt, Simon M.; Fan, Yu; Liu, Shuai

2012-04-01

Permian basalts distribute at least 250,000 km2, and underlie the southwest Tarim Basin in Xinjiang Uygur Autonomous region, northwest China. This vast accumulation of basalt is the main part of the Tarim Large Igneous Province (LIP). The basaltic units in the Lower Permian Kupukuziman and Kaipaizileike Formations in the Keping area, Tarim Basin; were the best exposure of the Permian basalt sequence in the basin. LA-ICP-MS U-Pb dating of zircon from the basal basaltic unit in the section gives an age of 291.9 ± 2.2 Ma (MSWD = 0.30, n = 17); this age, combined with previously published geochronological data, indicates that the basalts in the Tarim Basin were emplaced between 292 Ma and 272 Ma, with about 90% of the basalts being emplaced between 292 and 287 Ma. Basalts from the Keping area have high FeOT (10.8-18.6 wt.%), low Mg#s (0.26-0.60), and exhibit primitive mantle normalized patterns with positive Pb, P and Ti but negative Zr, Y and Ta anomalies. The basalts from both formations have similar 206Pb/204Pb (18.192-18.934), 207Pb/204Pb (15.555-15.598) and 208Pb/204Pb (38.643-38.793) ratios. The basalts also have high ɛSr(t) (45.7-62.1), low ɛNd(t) (-3.6 to -2.2) and low zircon ɛHf(t) (-4.84 to -0.65) values. These characteristics are typical of alkali basalts and suggest that the basalts within the Tarim Basin were derived from an OIB-type mantle source and interacted with enriched mantle (EMI-type) before emplacement. Rare earth element systematics indicate that the parental melts for the basalts were high-degree partial melts derived from garnet lherzolite mantle at the base of the lithosphere. Prior to emplacement, the Tarim Permian Basalts (TPB) underwent fractional crystallization and assimilated crustal material; the basalts were finally emplaced during crustal extension in an intra-plate setting. The wide distribution, deep source and high degree partial melting of the TPB was consistent with a mantle plume origin. The TPB and other coeval igneous

Vapor deposition in basaltic stalactites, Kilauea, Hawaii

NASA Astrophysics Data System (ADS)

Baird, A. K.; Mohrig, D. C.; Welday, E. E.

Basaltic stalacties suspended from the ceiling of a large lava tube at Kilauea, Hawaii, have totally enclosed vesicles whose walls are covered with euhedral FeTi oxide and silicate crystals. The walls of the vesicles and the exterior surfaces of stalactites are Fe and Ti enriched and Si depleted compared to common basalt. Minerals in vesicles have surface ornamentations on crystal faces which include alkali-enriched, aluminosilicate glass(?) hemispheres. No sulfide-, chloride-, fluoride-, phosphate- or carbonate-bearing minerals are present. Minerals in the stalactites must have formed by deposition from an iron oxide-rich vapor phase produced by the partial melting and vaporization of wall rocks in the tube.

Volatiles in High-K Lunar Basalts

NASA Technical Reports Server (NTRS)

Barnes, Jessica J.; McCubbin, Francis M.; Messenger, Scott R.; Nguyen, Ann; Boyce, Jeremy

2017-01-01

Chlorine is an unusual isotopic system, being essentially unfractionated ((delta)Cl-37 approximately 0 per mille ) between bulk terrestrial samples and chondritic meteorites and yet showing large variations in lunar (approximately -4 to +81 per mille), martian, and vestan (HED) samples. Among lunar samples, the volatile-bearing mineral apatite (Ca5(PO4)3[F,Cl,OH]) has been studied for volatiles in K-, REE-, and P (KREEP), very high potassium (VHK), low-Ti and high-Ti basalts, as well as samples from the lunar highlands. These studies revealed a positive correlation between in-situ (delta)Cl-37 measurements and bulk incompatible trace elements (ITEs) and ratios. Such trends were interpreted to originate from Cl isotopic fractionation during the degassing of metal chlorides during or shortly after the differentiation of the Moon via a magma ocean. In this study, we investigate the volatile inventories of a group of samples for which new-era volatile data have yet to be reported - the high-K (greater than 2000 ppm bulk K2O), high-Ti, trace element-rich mare basalts. We used isotope imaging on the Cameca NanoSIMS 50L at JSC to obtain the Cl isotopic composition [((Cl-37/(35)Clsample/C-37l/(35)Clstandard)-1)×1000, to get a value in per thousand (per mille)] which ranges from approximately -2.7 +/- 2 per mille to +16.1 +/- 2 per mille (2sigma), as well as volatile abundances (F & Cl) of apatite in samples 10017, 10024 & 10049. Simply following prior models, as lunar rocks with high bulk-rock abundances of ITEs we might expect the high-K, high-Ti basalts to contain apatite characterized by heavily fractionated (delta)Cl-37 values, i.e., Cl obtained from mixing between unfractionated mantle Cl (approximately 0 per mille) and the urKREEP reservoir (possibly fractionated to greater than +25 per mille.). However, the data obtained for the studied samples do not conform to either the early degassing or mixing models. Existing petrogentic models for the origin of the high

Transition Element Abundances in MORB Basalts

NASA Astrophysics Data System (ADS)

Yang, S.; Humayun, M.; Salters, V. J.; Fields, D.; Jefferson, G.; Perfit, M. R.

2012-12-01

The mineralogy of the mantle sources of basalts is an important, but hard to constrain parameter, especially with the basalts as chemical probes of major element mantle composition. Geophysical models imply that the deep mantle may have significant variations in Fe and Si relative to the ambient mantle sampled by MORB. Some petrological models of sub-ridge melting involve both pyroxenite and peridotite, implying that basalts preferentially sample a pyroxenite endmember. The First-Row Transition Elements (FRTE), Ga and Ge are compatible to moderately incompatible during partial melting, and are sensitive to mineralogical variability in the mantle and thus can provide constraints on mantle source mineralogy for MORB. We have analyzed major elements, FRTE, Ga and Ge on 231 basaltic glasses from the Middle Atlantic Ridge (MAR between -23°S to 36.44°N), 30 Mid-Cayman Rise basaltic glasses, 12 glasses from the Siqueiros Fracture Zone (EPR), 9 glasses from the Blanco Trough, Juan de Fuca ridge, and Galapagos Spreading Centers (EPR), and 4 Indian Ocean MORB. Large spots (150 μm) were precisely (±1%) analyzed by a New Wave UP193FX excimer (193 nm) laser ablation system coupled to a high-resolution ICP-MS at the National High Magnetic Field Laboratory using a high ablation rate (50 Hz) to yield blank contributions <1% for all elements, particularly Ge. The data demonstrate that the Ge/Si (6.96 x 10E-6 ± 3%, 1σ) and Fe/Mn (55 ± 2%) ratios for MORB are insensitive to fractional crystallization within the MgO range 6%-10%. MORB have Zn/Fe (9.9 x 10E-4 ± 7%), Ga/Sc (0.37-0.50), Ga/Al (2.2 x 10E-4 ± 11%) ratios, with the variations mostly due to the effects of fractional crystallization. Recent experimental determination of FRTE, Ga and Ge partition coefficients provide a framework within which to interpret these data [1]. Using these new partition coefficients, we have modeled the sensitivity of each element to mineralogical variations in the mantle source. Olivine

Lunar basalt meteorite EET 87521: Petrology of the clast population

NASA Technical Reports Server (NTRS)

Semenova, A. S.; Nazarov, M. A.; Kononkova, N. N.

1993-01-01

The Elephant Moraine meteorite EET 87521 was classified as a lunar mare basalt breccia which is composed mainly of VLT basalt clasts. Here we report on our petrological study of lithic clasts and monomineralic fragments in the thin sections EET 87521,54 and EET 87521,47,1, which were prepared from the meteorite. The results of the study show that EET 87521 consists mainly of Al-rich ferrobasalt clasts and olivine pyroxenite clasts. The bulk composition of the meteorite can be well modelled by the mixing of these lithic components which appear to be differentiates of the Luna 25 basalt melt. KREEP and Mg-rich gabbro components are minor constituents of EET 87521.

Automated identification of basalt spectra in Clementine lunar data

NASA Astrophysics Data System (ADS)

Antonenko, I.; Osinski, G. R.

2011-06-01

The identification of fresh basalt spectra plays an important role in lunar stratigraphic studies; however, the process can be time consuming and labor intensive. Thus motivated, we developed an empirically derived algorithm for the automated identification of fresh basalt spectra from Clememtine UVVIS data. This algorithm has the following four parameters and limits: BC Ratio=3(R950-R900)/(R900-R750)<1.1, CD Delta=(R1000-R950)/R750-1.09(R950-R900)/R750>0.003 and <0.06, B Slope=(R900-R750)/(3R750)<-0.012, and Band Depth=(R750-R950)/(R750-R415)>0.1, where R750 represents the unnormalized reflectance of the 750 nm Clementine band, and so on. Algorithm results were found to be accurate to within an error of 4.5% with respect to visual classification, though olivine spectra may be under-represented. Overall, fresh basalts identified by the algorithm are consistent with expectations and previous work in the Mare Humorum area, though accuracy in other areas has not yet been tested. Great potential exists in using this algorithm for identifying craters that have excavated basalts, estimating the thickness of mare and cryptomare deposits, and other applications.

Rare earth element contents and multiple mantle sources of the transform-related Mount Edgecumbe basalts, southeastern Alaska

USGS Publications Warehouse

Riehle, J.R.; Budahn, J.R.; Lanphere, M.A.; Brew, D.A.

1994-01-01

Pleistocene basalt of the Mount Edgecumbe volcanic field (MEF) is subdivided into a plagioclase type and an olivine type. Th/La ratios of plagioclase basalt are similar to those of mid-ocean-ridge basalt (MORB), whereas those of olivine basalt are of continental affinity. Rare earth element (REE) contents of the olivine basalt, which resemble those of transitional MORB, are modelled by 10-15% partial melting of fertile spinel-plagioclase lherzolite followed by removal of 8-13% olivine. It is concluded that olivine basalt originated in subcontinental spinel lherzolite and that plagioclase basalt may have originated in suboceanic lithosphere of the Pacific plate. -from Authors

Evaluation of Basalt Fibre Composites for Marine Applications

NASA Astrophysics Data System (ADS)

Davies, P.; Verbouwe, W.

2018-04-01

Basalt fibres offer potential for use in marine structures, but few data exist to evaluate the influence of seawater immersion on their mechanical behaviour. This paper provides the results from a study in which basalt fibre reinforced epoxy composites were aged in natural seawater at different temperatures. Tests were performed under quasi-static and cyclic loading, first in the as-received state then after saturation in natural seawater. Results are compared to those for an E-glass reinforced composite with the same epoxy matrix. They indicate similar mechanical performance for both materials after seawater saturation.

Genesis of highland basalt breccias - A view from 66095

NASA Technical Reports Server (NTRS)

Garrison, J. R., Jr.; Taylor, L. A.

1980-01-01

Electron microprobe and defocused beam analyses of the lunar highland breccia sample 66095 show it consists of a fine-grained subophitic matrix containing a variety of mineral and lithic clasts, such as intergranular and cataclastic ANT, shocked and unshocked plagioclase, and basalts. Consideration of the chemistries of both matrix and clasts provides a basis for a qualitative three-component mixing model consisting of an ANT plutonic complex, a Fra Mauro basalt, and minor meteoric material.

Chemical differences between small subsamples of Apollo 15 olivine-normative basalts

NASA Technical Reports Server (NTRS)

Shervais, J. W.; Vetter, S. K.; Lindstrom, M. M.

1990-01-01

Results are presented on the chemical and petrological characterization of nine samples of an Apollo 15 mare basalt suite. The results show that all nine samples are low-silica olivine normative basalts (ONBs) similar to those described earlier for low-silica ONBs from Apollo 15 site. The samples were found to vary in texture and grain size, from fine-grained intergranular or subophitic basalts to coarse-grained granular 'microgabbros'. Several displayed macroscopic heterogeneity. Variation diagrams show that the overall trend of the data is consistent with the fractionation of olivine (plus minor Cr-spinel) from a high-MgO parent magma.

Interpretation of trace element and isotope features of basalts: relevance of field relations, petrology, major element data, phase equilibria, and magma chamber modeling in basalt petrogenesis

NASA Astrophysics Data System (ADS)

O'Hara, M. J.; Herzberg, C.

2002-06-01

The concentrations and ratios of the major elements determine the physical properties and the phase equilibria behavior of peridotites and basalts in response to the changing energy contents of the systems. The behavior of the trace elements and isotopic features are influenced in their turn by the phase equilibria, by the physical character of the partial melting and partial crystallization processes, and by the way in which a magma interacts with its wall rocks. Concentrating on the trace element and isotope contents of basalts to the exclusion of the field relations, petrology, major element data, and phase equilibria is as improvident as slaughtering the buffalo for the sake of its tongue. The crust is a cool boundary layer and a density filter, which impedes the upward transfer of hot, dense "primary" picritic and komatiitic liquids. Planetary crusts are sites of large-scale contamination and extensive partial crystallization of primitive melts striving to escape to the surface. Escape of truly unmodified primitive melts to the surface is a rare event, requiring the resolution of daunting problems in chemical and mechanical engineering. Primary status for volumetrically abundant basalts such as mid-ocean ridge basalt, ocean island basalt, and continental flood basalts is denied by their low-pressure cotectic character, first remarked upon on petrological grounds in 1928 and on experimental grounds in 1962. These basalt liquids are products of crystal-liquid separation at low pressure. Primary status for these common basalts is further denied by the phase equilibria of such compositions at elevated pressures, when the required residual mantle mineralogy (magnesian olivine and orthopyroxene) is not stable at the liquidus. It is also denied by the picritic or komatiitic nature of partial melts of candidate upper-mantle compositions at high pressures - a conclusion supported by calculation of the melt composition, which would need to be extracted in order to

Carbon sequestration via reaction with basaltic rocks: geochemical modeling and experimental results

USGS Publications Warehouse

Rosenbauer, Robert J.; Thomas, Burt; Bischoff, James L.; Palandri, James

2012-01-01

Basaltic rocks are potential repositories for sequestering carbon dioxide (CO2) because of their capacity for trapping CO2 in carbonate minerals. We carried out a series of thermodynamic equilibrium models and high pressure experiments, reacting basalt with CO2-charged fluids over a range of conditions from 50 to 200 °C at 300 bar. Results indicate basalt has a high reactivity to CO2 acidified brine. Carbon dioxide is taken up from solution at all temperatures from 50 to 200 °C, 300 bar, but the maximum extent and rate of reaction occurs at 100 °C, 300 bar. Reaction path simulations utilizing the geochemical modeling program CHILLER predicted an equilibrium carbonate alteration assemblage of calcite, magnesite, and siderite, but the only secondary carbonate identified in the experiments was a ferroan magnesite. The amount of uptake at 100 °C, 300 bar ranged from 8% by weight for a typical tholeite to 26% for a picrite. The actual amount of CO2 uptake and extent of rock alteration coincides directly with the magnesium content of the rock suggesting that overall reaction extent is controlled by bulk basalt Mg content. In terms of sequestering CO2, an average basaltic MgO content of 8% is equivalent to 2.6 × 108 metric ton CO2/km3 basalt.

Basalt Fiber for Volcanic Slag Lightweight Aggregate Concrete Research on the Impact of Performance

NASA Astrophysics Data System (ADS)

Xiao, Li-guang; Li, Gen-zhuang

2018-03-01

In order to study the effect of basalt fiber on the mechanical properties and durability of volcanic slag lightweight aggregate concrete, the experimental study on the flexural strength, compressive strength and freeze-thaw resistance of volcanic slag concrete with different basalt fiber content were carried out, the basalt fiber was surface treated with NaOH and water glass, the results show that the surface treatment of basalt fiber can significantly improve the mechanical properties, durability and other properties of volcanic slag lightweight aggregate concrete.

Age distribution of Serra Geral (Paraná) flood basalts, southern Brazil

USGS Publications Warehouse

Fodor, R.V.; McKee, E.H.; Roisenberg, A.

1989-01-01

We evaluated 193 K-Ar ages (10 newly determined) of basaltic and differentiated rocks of the Serra Geral (Paraná) flood-basalt province for indications of magmatism occurring systematically with progressive rifting and complete separation ( ≈130-105 Ma) of South America from Africa. The K-Ar ages represent basalt emplacement between 35° and 19°S covering about 1,200,000 km2. We note that volcanism appears ubiquitous across the province between about 140 and 115 Ma, and that there are no significant age differences within that relate directly to progressive south-to-north tectonism. On the other hand, the oldest samples, about 140–160 Ma, are among those nearest the Brazil coastline (rift margin), perhaps suggesting migration of activity away from the rift with time. Studies of other flood-basalt provinces now indicate short (<3 m.y.) eruption periods, thereby pointing to the need for re-examination of Serra Geral ages by 40Ar-39Ar incremental heating techniques.

Concentrations and isotope ratios of carbon, nitrogen and sulfur in ocean-floor basalts

USGS Publications Warehouse

Sakai, H.; Marais, D.J.D.; Ueda, A.; Moore, J.G.

1984-01-01

Fresh submarine basalt glasses from Galapagos Ridge, FAMOUS area, Cayman Trough and Kilauea east rift contain 22 to 160 ppm carbon and 0.3 to 2.8 ppm nitrogen, respectively, as the sums of dissolved species and vesicle-filling gases (CO2 and N2). The large range of variation in carbon content is due to combined effect of depth-dependency of the solubility of carbon in basalt melt and varying extents of vapour loss during magma emplacement as well as in sample crushing. The isotopic ratios of indigenous carbon and nitrogen are in very narrow ranges,-6.2 ?? 0.2% relative to PDB and +0.2 ?? 0.6 %. relative to atmospheric nitrogen, respectively. In basalt samples from Juan de Fuca Ridge, however, isotopically light carbon (??13C = around -24%.) predominates over the indigenous carbon; no indigenous heavy carbon was found. Except for Galapagos Ridge samples, these ocean-floor basalts contain 670 to 1100 ppm sulfur, averaging 810 ppm, in the form of both sulfide and sulfate, whereas basalts from Galapagos Ridge are higher in both sulfur (1490 and 1570 ppm) and iron (11.08% total iron as FeO). The ??34S values average +0.3 ?? 0.5%. with average fractionation factor between sulfate and sulfide of +7.4 ?? 1.6%.. The sulfate/sulfide ratios tend to increase with increasing water content of basalt, probably because the oxygen fugacity increases with increasing water content in basalt melt. ?? 1984.

Concentrations and isotope ratios of carbon, nitrogen and sulfur in ocean-floor basalts.

PubMed

Sakai, H; Des Marais, D J; Ueda, A; Moore, J G

1984-01-01

Fresh submarine basalt glasses from Galapagos Ridge, FAMOUS area, Cayman Trough and Kilauea east rift contain 22 to 160 ppm carbon and 0.3 to 2.8 ppm nitrogen, respectively, as the sums of dissolved species and vesicle-filling gases (CO2 and N2). The large range of variation in carbon content is due to combined effect of depth-dependency of the solubility of carbon in basalt melt and varying extents of vapour loss during magma emplacement as well as in sample crushing. The isotopic ratios of indigenous carbon and nitrogen are in very narrow ranges, -6.2 +/- 0.2% relative to PDB and +0.2 +/- 0.6% relative to atmospheric nitrogen, respectively. In basalt samples from Juan de Fuca Ridge, however, isotopically light carbon (delta 13 C = around -24%) predominates over the indigenous carbon; no indigenous heavy carbon was found. Except for Galapagos Ridge samples, these ocean-floor basalts contain 670 to 1100 ppm sulfur, averaging 810 ppm in the form of both sulfide and sulfate, whereas basalts from Galapagos Ridge are higher in both sulfur (1490 and 1570 ppm) and iron (11.08% total iron as FeO). the delta 34S values average +0.3 +/- 0.5% with average fractionation factor between sulfate and sulfide of +7.4 +/- 1.6%. The sulfate/sulfide ratios tend to increase with increasing water content of basalt, probably because the oxygen fugacity increases with increasing water content in basalt melt.

Spitzer IRS Spectra of Basaltic Asteroids: Preliminary Results

NASA Technical Reports Server (NTRS)

Lim, Lucy F.; Emery, Joshua P.; Moskovitz, Nick; Stewart, Heather; Marchis, Frank

2008-01-01

We present preliminary results of a Spitzer program to observe the 5.2--38 micron spectra of small basaltic asteroids using the Spitzer IRS (Infrared Spectrograph). Our targets include members of the dynamical family of the unique large differentiated asteroid 4 Vesta ("Vestoids"), four outer-main-belt basaltic asteroids whose orbits exclude them from originating on 4 Vesta, and the basaltic near-Earth asteroid (NEA) 4055 Magellan. We will compare the compositions and thermophysical properties of the non-Vestoid objects with those of the dynamical vestoids to provide insight on the extent of metal-silicate differentiation on planetsimals during the epoch of planet formation in the early Solar System. As of this writing, spectra of asteroids 10537 (1991 RY16) and 2763 Jeans have been returned. Analysis of these data are ongolng. Observations of 956 Elisa, 2653 Principia, 4215 Kamo, 7472 Kumakiri, and 1459 Magnya have been scheduled and are expected to be available by the time of the DPS meeting. NIR spectra and lightcurves o f the target asteroids are also being observed in support of this program.

Carbon uptake in granular basalt is mitigated by added organic carbon.

NASA Astrophysics Data System (ADS)

Howard, E. L.; Van Haren, J. L. M.; Dontsova, K.

2017-12-01

Soils represent a large, and potentially long-term, storage component of the global carbon budget. Accurate projections of the response of soil respiration -the release of CO2 from soils generated either through root respiration or microbial respiration- to rainfall events remains one of the largest uncertainties in global carbon cycling models. Similarly poorly represented in models is the uptake of CO2 by basalt soils. In an attempt to address these unknowns, we have investigated how the addition of carbon influences the negative CO2 flux observed after wetting basalt. At Biosphere 2 we have constructed a large scale environmentally controlled experiment known as the Landscape Evolution Observatory (LEO). The objective of LEO is to observe the interactions between water, microbes, and climate in the formation of soil and landscapes utilizing granular basalt as a young soil. Previous studies show that water addition to the LEO soil leads to considerable CO2 uptake and that the addition of plants does not alter this response. In this study, we conducted soil incubations to investigate the effect of varying soil carbon content on CO2 fluxes. During incubations we measured CO2 emissions from two types of soil (granular basalt and sand soil) mixed with seven (0, 5, 10, 25, 50, 75, 100%) different proportions of Kalso prairie. The carbon content varied from nearly zero in the basalt to 6.5% in the Kalso Prarie soil. Other parameters that influence soil CO2 fluxes such as pH were taken into account. In conclusion, our experiments confirm that unweathered basalt will consume CO2 when wetted, whereas added carbon will cause a strong pulse of CO2 following water addition. This supports our hypotheses that the carbon content is a large contributor and that maturation of basalt flows will lead to a shift in the carbon dynamics from inorganic to organic dominated. Likewise, these transitions would be expected to be present during soil formation after primary succession and

Discovery of a basaltic asteroid in the outer main belt

PubMed

Lazzaro; Michtchenko; Carvano; Binzel; Bus; Burbine; Mothe-Diniz; Florczak; Angeli; Harris

2000-06-16

Visible and near-infrared spectroscopic observations of the asteroid 1459 Magnya indicate that it has a basaltic surface. Magnya is at 3. 15 astronomical units (AU) from the sun and has no known dynamical link to any family, to any nearby large asteroid, or to asteroid 4 Vesta at 2.36 AU, which is the only other known large basaltic asteroid. We show that the region of the belt around Magnya is densely filled by mean-motion resonances, generating slow orbital diffusion processes and providing a potential mechanism for removing other basaltic fragments that may have been created on the same parent body as Magnya. Magnya may represent a rare surviving fragment from a larger, differentiated planetesimal that was disrupted long ago.

The Mantle and Basalt-Crust Interaction Below the Mount Taylor Volcanic Field, New Mexico

NASA Technical Reports Server (NTRS)

Schrader, Christian M.; Crumpler, Larry S.; Schmidt, Marick E.

2010-01-01

The Mount Taylor Volcanic Field (MTVF) lies on the Jemez Lineament on the southeastern margin of the Colorado Plateau. The field is centered on the Mt. Taylor composite volcano and includes Mesa Chivato to the NE and Grants Ridge to the WSW. MTVF magmatism spans approximately 3.8-1.5 Ma (K-Ar). Magmas are dominantly alkaline with mafic compositions ranging from basanite to hy-basalt and felsic compositions ranging from ne-trachyte to rhyolite. We are investigating the state of the mantle and the spatial and temporal variation in basalt-crustal interaction below the MTVF by examining mantle xenoliths and basalts in the context of new mapping and future Ar-Ar dating. The earliest dated magmatism in the field is a basanite flow south of Mt. Taylor. Mantle xenolith-bearing alkali basalts and basanites occur on Mesa Chivato and in the region of Mt. Taylor, though most basalts are peripheral to the main cone. Xenolith-bearing magmatism persists at least into the early stages of conebuilding. Preliminary examination of the mantle xenolith suite suggests it is dominantly lherzolitic but contains likely examples of both melt-depleted (harzburgitic) and melt-enriched (clinopyroxenitic) mantle. There are aphyric and crystal-poor hawaiites, some of which are hy-normative, on and near Mt. Taylor, but many of the more evolved MTVF basalts show evidence of complex histories. Mt. Taylor basalts higher in the cone-building sequence contain >40% zoned plagioclase pheno- and megacrysts. Other basalts peripheral to Mt. Taylor and at Grants Ridge contain clinopyroxene and plagioclase megacrysts and cumulate-textured xenoliths, suggesting they interacted with lower crustal cumulates. Among the questions we are addressing: What was the chemical and thermal state of the mantle recorded by the basaltic suites and xenoliths and how did it change with time? Are multiple parental basalts (Si-saturated vs. undersaturated) represented and, if so, what changes in the mantle or in the tectonic

Mineralogy of the last lunar basalts: Results from Clementine

USGS Publications Warehouse

Staid, M.I.; Pieters, C.M.

2001-01-01

The last major phase of lunar volcanism produced extensive high-titanium mare deposits on the western nearside which remain unsampled by landing missions. The visible and near-infrared reflectance properties of these basalts are examined using Clementine multispectral images to better constrain their mineralogy. A much stronger 1 ??m ferrous absorption was observed for the western high-titanium basalts than within earlier maria, suggesting that these last major mare eruptions also may have been the most iron-rich. These western basalts also have a distinctly long-wavelength, 1 ??m ferrous absorption which was found to be similar for both surface soils and materials excavated from depth, supporting the interpretation of abundant olivine within these deposits. Spectral variation along flows within the Imbrium basin also suggests variations in ilmenite content along previously mapped lava flows as well as increasing olivine content within subsequent eruptions. Copyright 2001 by the American Geophysical Union.

Euphorbia Section Hainanensis (Euphorbiaceae), a New Section Endemic to the Hainan Island of China From Biogeographical, Karyological, and Phenotypical Evidence.

PubMed

Tian, Xinmin; Wang, Qiuyan; Zhou, Yongfeng

2018-01-01

Euphorbia hainanensis is an endangered species endemic to the tropical Hainan Island in southern China and of historical importance for Chinese medicine. It is currently the only unplaced species of the genus Euphorbia (Euphorbiaceae) due to its isolated island distribution and debated placement by a previous molecular phylogenetic study. We sequenced nuclear ITS and chloroplast rbcL and ndhF for newly collected accessions of E. hainanensis and additional Euphorbia species found in Hainan, and analyzed the sequences in the context of the entire genus together with published data. All gene regions highly supported that E. hainanensis occupied an isolated phylogenetic position, showing no close affinity with any known Euphorbia sections suggesting it was a new section. ITS placed E. hainanensis sister to sect. Crossadenia (subgenus Chamaesyce ) from Brazil with an estimated divergence time of 9.3-30.6 Mya while the chloroplast markers placed E. hainanensis at a position sister to the entire New World clade of Euphorbia subgenus Chamaesyce . In addition, our karyological results suggested a close affinity between E. hainanensis and the New World species of Euphorbia subg. Chamaesyce , with which shared the same chromosome number 2n = 28 and basic chromosome number x = 7. Phenotypically, E. hainanensis is unique with no close resemblance to other species in Euphorbia subg. Chamaesyce . Based on its isolated biogeographical, karyological, and phenotypical position, we propose a new section E . subgenus Chamaesyce section Hainanensis that might origin from long distance dispersal events because collective evidences showed a close affinity between the species from the Old World with those from the New World.

Petrological and Geochemical characterization of central Chihuahua basalts: a possible local sign of rifting activity

NASA Astrophysics Data System (ADS)

Espejel-Garcia, V. V.; Garcia-Rascon, M.; Villalobos-Aragon, A.; Morton-Bermea, O.

2012-12-01

The central part of the mexican state, Chihuahua, is the oriental border of the Sierra Madre Occidental (silicic large igneous province), which consist of series of ignimbrites divided into two volcanic groups of andesites and rhyolites. In the central region of Chihuahua, the volcanic rocks are now part of the Basin and Range, allowing the presence of mafic rocks in the lower areas. The study area is located approximately 200 km to the NW of Chihuahua city near to La Guajolota town, in the Namiquipa County. There are at least 5 outcrops of basalts to the west of the road, named Puerto de Lopez, Malpaises, El Tascate, Quebrada Honda, and Carrizalio, respectively. These outcrops have only been previously described by the Mexican Geologic Survey (SGM) as thin basaltic flows, with vesicles filled with quartz, and phenocrystals of labradorite, andesine, oligoclase and olivine. Petrologically, the basalts present different textures, from small phenocrysts of plagioclase in a very fine matrix to large, zoned and sometimes broken phenocrysts of plagioclase in a coarser matrix. All samples have olivine in an advanced state of alteration, iddingsite. The geochemical analyses report that these basaltic flows contain characteristics of rift basalts. The rocks have a normative olivine values from 5.78 to 27.26 and nepheline values from 0 to 2.34. In the TAS diagram the samples straddle the join between basalt and trachy-basalt, reflecting a high K2O content. The Mg# average is 0.297, a value that suggests that the basalts do not come from a primitive magma. The basalts have high values of Ba (945-1334 ppm), Cu (54-147 ppm), and Zn (123-615 ppm). The contents of Rb (23-57 ppm), Sr (659-810 ppm), Y (26-33 ppm), Zr (148-217 ppm) and Cr (79-98 ppm) are characteristics of rift basalts. Using discrimination diagrams, the basalts plot in the field of within plate, supporting the rifting origin. Outcrops of other basalts, at about 80 to 100 km to the east of the study area, Lomas El

Flame-resistant pure and hybrid woven fabrics from basalt

NASA Astrophysics Data System (ADS)

Jamshaid, H.; Mishra, R.; Militky, J.

2017-10-01

This work has been formulated to investigate the burning behavior of different type of fabrics. The main concentration is to see how long the fabric resists after it catches the fire and the propagation of fire can be reduced by using flame resistant fiber i.e basalt. Basalt fiber is an environmental friendly material with low input, high output, low energy consumption and less emission. The goal of present investigations is to show the dependence of fabric flammability on its structure parameters i.e weave type, blend type etc. Fabric weaves have strong effect on flammability properties. Plain weave has the lowest burning rate as the density of the plain weave fabric is more and the structure is tight which gives less chances of flame passing through the fabric. Thermal stability is evaluated with TGA of all hybrid and nonhybrid fabrics and compared. The thermal stability of the basalt fiber is excellent. When comparing thermal analysis curves for hybrid samples it demonstrates that thermal stability of the samples containing basalt is much higher than the non- hybrid samples. Percentage weight loss is less in hybrid samples as compared to non-hybrid samples. The effectiveness of hybridization on samples may be indicated by substantial lowering of the decomposition mass. Correlation was made between flammability with the infrared radiations (IR)

Pyroxenes as recorders of lunar basalt petrogenesis - Chemical trends due to crystal-liquid interaction.

NASA Technical Reports Server (NTRS)

Bence, A. E.; Papike, J. J.

1972-01-01

Review of the crystallization histories suggested by the chemical, crystallographic, morphological, and paragenetic relationships observed in pyroxenes from basalts collected on the Apollo 11, 12, 14, 15, and Luna 16 missions. Although the final stages of lunar basalt crystallization appear to be rapid near-surface events, the initial stages are shown to vary considerably among the different basalt types.

Characterization and utilization potential of basalt rock from East-Lampung district

NASA Astrophysics Data System (ADS)

Isnugroho, K.; Hendronursito, Y.; Birawidha, D. C.

2018-01-01

The aim of this research was to study the petrography and chemical properties of basalt rock from East Lampung district, Lampung province. Petrography analysis was performed using a polarization microscope, and analysis of chemical composition using X-RF method. From the analysis of basalt rock samples, the mineral composition consists of pyroxene, plagioclase, olivine, and opaque minerals. Basic mass of basalt rock samples is, composed of plagioclase and pyroxene with subhedral-anhedral shape, forming intergranular texture, and uniform distribution. Mineral plagioclase is colorless and blade shape, transformed into opaque minerals with a size of <0.2 mm, whereas pyroxene present among the blades of plagioclase, with a greenish tint looked and a size of <0.006 mm. Mineral opaque has a rectangular shape to irregular, with a size of <0.16 mm. The chemical composition of basalt rock samples, consisting of 37.76-59.64 SiO2; 10.10-20.93 Fe2O3; 11.77-14.32 Al2O3; 5.57-14.75 CaO; 5.37-9.15 MgO; 1.40-3.34 Na2O. From the calculation, obtained the value of acidity ratio (Ma) = 3.81. With these values, indicate that the basalt rock from East Lampung district has the potential to be utilized as stone wool fiber.

Selective environmental stress from sulphur emitted by continental flood basalt eruptions

NASA Astrophysics Data System (ADS)

Schmidt, Anja; Skeffington, Richard; Thordarson, Thorvaldur; Self, Stephen; Forster, Piers; Rap, Alexandru; Ridgwell, Andy; Fowler, David; Wilson, Marjorie; Mann, Graham; Wignall, Paul; Carslaw, Ken

2016-04-01

Several biotic crises during the past 300 million years have been linked to episodes of continental flood basalt volcanism, and in particular to the release of massive quantities of magmatic sulphur gas species. Flood basalt provinces were typically formed by numerous individual eruptions, each lasting years to decades. However, the environmental impact of these eruptions may have been limited by the occurrence of quiescent periods that lasted hundreds to thousands of years. Here we use a global aerosol model to quantify the sulphur-induced environmental effects of individual, decade-long flood basalt eruptions representative of the Columbia River Basalt Group, 16.5-14.5 million years ago, and the Deccan Traps, 65 million years ago. For a decade-long eruption of Deccan scale, we calculate a decadal-mean reduction in global surface temperature of 4.5 K, which would recover within 50 years after an eruption ceased unless climate feedbacks were very different in deep-time climates. Acid mists and fogs could have caused immediate damage to vegetation in some regions, but acid-sensitive land and marine ecosystems were well-buffered against volcanic sulphur deposition effects even during century-long eruptions. We conclude that magmatic sulphur from flood basalt eruptions would have caused a biotic crisis only if eruption frequencies and lava discharge rates had been high and sustained for several centuries at a time.

Selective environmental stress from sulphur emitted by continental flood basalt eruptions

NASA Astrophysics Data System (ADS)

Schmidt, Anja; Skeffington, Richard A.; Thordarson, Thorvaldur; Self, Stephen; Forster, Piers M.; Rap, Alexandru; Ridgwell, Andy; Fowler, David; Wilson, Marjorie; Mann, Graham W.; Wignall, Paul B.; Carslaw, Kenneth S.

2016-01-01

Several biotic crises during the past 300 million years have been linked to episodes of continental flood basalt volcanism, and in particular to the release of massive quantities of magmatic sulphur gas species. Flood basalt provinces were typically formed by numerous individual eruptions, each lasting years to decades. However, the environmental impact of these eruptions may have been limited by the occurrence of quiescent periods that lasted hundreds to thousands of years. Here we use a global aerosol model to quantify the sulphur-induced environmental effects of individual, decade-long flood basalt eruptions representative of the Columbia River Basalt Group, 16.5-14.5 million years ago, and the Deccan Traps, 65 million years ago. For a decade-long eruption of Deccan scale, we calculate a decadal-mean reduction in global surface temperature of 4.5 K, which would recover within 50 years after an eruption ceased unless climate feedbacks were very different in deep-time climates. Acid mists and fogs could have caused immediate damage to vegetation in some regions, but acid-sensitive land and marine ecosystems were well-buffered against volcanic sulphur deposition effects even during century-long eruptions. We conclude that magmatic sulphur from flood basalt eruptions would have caused a biotic crisis only if eruption frequencies and lava discharge rates had been high and sustained for several centuries at a time.

Effect of Fluorine on Near-Liquidus Phase Equilibria of Basalts

NASA Technical Reports Server (NTRS)

Filiberto, Justin; Wood, Justin; Loan, Le; Dasgupta, Rajdeep; Shimizu, Nobumichi; Treiman, Allan H.

2010-01-01

Volatile species such as H2O, CO2, F, and Cl have significant impact in generation and differentiation of basaltic melts. Thus far experimental work has primarily focused on the effect of water and carbon dioxide on basalt crystallization, liquid-line of descent, and mantle melting [e.g., 1, 2] and the effects of halogens have received far less attention [3-4]. However, melts in the planetary interiors can have non-negligible chlorine and fluorine concentrations. Here, we explore the effects of fluorine on near-liquidus phase equilibria of basalt. We have conducted nominally anhydrous piston cylinder experiments using graphite capsules at 0.6 - 1.5 GPa on an Fe-rich model basalt composition. 1.75 wt% fluorine was added to the starting mix in the form of AgF2. Fluorine in the experimental glass was measured by SIMS and major elements of glass and minerals were analyzed by EPMA. Nominally volatile free experiments yield a liquidus temperature from 1330 C at 0.8GPa to 1400 at 1.6GPa and an olivine(Fo72)-pyroxene(En68)-liquid multiple saturation point at 1.25 GPa and 1375 C. The F-bearing experiments yield a liquiudus temperature from 1260 C at 0.6GPa to 1305 at 1.5GPa and an ol(Fo66)-pyx(En64)-MSP at 1 GPa and 1260 C. This shows that F depresses the basalt liquidus, extends the pyroxene stability field to lower pressure, and forces the liquidus phases to be more Fe-rich. KD(Fe-Mg/mineral-melt) calculated for both pyroxenes and olivines show an increase with increasing F content of the melt. Therefore, we infer that F complexes with Mg in the melt and thus increases the melt s silica activity, depressing the liquidus and changing the composition of the crystallizing minerals. Our study demonstrates that on a weight percent basis, the effect of fluorine is similar to the effect of H2O [1] and Cl [3] on freezing point depression of basalts. But on an atomic fraction basis, the effect of F on liquidus depression of basalts is xxxx compared to the effect of H. Future

Permeability, porosity, and mineral surface area changes in basalt cores induced by reactive transport of CO2-rich brine

NASA Astrophysics Data System (ADS)

Luhmann, Andrew J.; Tutolo, Benjamin M.; Bagley, Brian C.; Mildner, David F. R.; Seyfried, William E.; Saar, Martin O.

2017-03-01

Four reactive flow-through laboratory experiments (two each at 0.1 mL/min and 0.01 mL/min flow rates) at 150°C and 150 bar (15 MPa) are conducted on intact basalt cores to assess changes in porosity, permeability, and surface area caused by CO2-rich fluid-rock interaction. Permeability decreases slightly during the lower flow rate experiments and increases during the higher flow rate experiments. At the higher flow rate, core permeability increases by more than one order of magnitude in one experiment and less than a factor of two in the other due to differences in preexisting flow path structure. X-ray computed tomography (XRCT) scans of pre- and post-experiment cores identify both mineral dissolution and secondary mineralization, with a net decrease in XRCT porosity of ˜0.7%-0.8% for the larger pores in all four cores. (Ultra) small-angle neutron scattering ((U)SANS) data sets indicate an increase in both (U)SANS porosity and specific surface area (SSA) over the ˜1 nm to 10 µm scale range in post-experiment basalt samples, with differences due to flow rate and reaction time. Net porosity increases from summing porosity changes from XRCT and (U)SANS analyses are consistent with core mass decreases. (U)SANS data suggest an overall preservation of the pore structure with no change in mineral surface roughness from reaction, and the pore structure is unique in comparison to previously published basalt analyses. Together, these data sets illustrate changes in physical parameters that arise due to fluid-basalt interaction in relatively low pH environments with elevated CO2 concentration, with significant implications for flow, transport, and reaction through geologic formations.

Prokaryotic diversity, distribution, and insights into their role in biogeochemical cycling in marine basalts and gabbros

NASA Astrophysics Data System (ADS)

Mason, O. U.; di Meo-Savoie, C. A.; Nakagawa, T.; van Nostrand, J. D.; Rosner, M.; Maruyama, A.; Zhou, J.; Fisk, M. R.; Giovannoni, S. J.

2008-12-01

Oceanic crust covers nearly 70% of the Earth's surface, of which, the upper, sediment layer is estimated to harbor substantial microbial biomass. Marine crust, however, extends several kilometers beyond this surficial layer, and includes the basalt and gabbro layers. The microbial diversity in basalts is well characterized, yet metabolic diversity is unknown. To date, the microflora associated with gabbros, including microbial and metabolic diversity has not been reported. In our analyses basaltic and gabbroic endoliths were analyzed using terminal restriction fragment length polymorphism, cloning and sequencing, and microarray analysis of functional genes. Our results suggest that despite nearly identical chemical compositions of basalt and gabbro the associated microflora did not overlap. Basalt samples harbor a surprising diversity of seemingly cosmopolitan microorganisms, some of which appear to be basalt specialists. Conversely, gabbros have a low diversity of endoliths, none of which appear to be specifically adapted to the gabbroic environment. Microarray analysis (GeoChip) was used to assay for functional gene diversity in basalts and gabbros. In basalt genes coding for previously unreported processes such as carbon fixation, methane-oxidation, methanogenesis, and nitrogen fixation were present, suggesting that basalts harbor previously unrecognized metabolic diversity. Similar processes were observed in gabbroic samples, yet metabolic inference from phylogenetic relationships of gabbroic endoliths with other microorganisms, suggests that hydrocarbon oxidation is the prevailing metabolism in this environment. Our analyses revealed that the basalt and gabbro layers harbor microorganisms with the genetic potential to significantly impact biogeochemical cycling in the lithosphere and overlying hydrosphere.

Anthropogenic protection alters the microbiome in intertidal mangrove wetlands in Hainan Island.

PubMed

Yun, Juanli; Deng, Yongcui; Zhang, Hongxun

2017-08-01

Intertidal mangrove wetlands are of great economic and ecological importance. The regular influence of tides has led to the microbial communities in these wetlands differing significantly from those in other habitats. In this study, we investigated the microbiomes of the two largest mangrove wetlands in Hainan Island, China, which have different levels of anthropogenic protection. Soil samples were collected from the root zone of 13 mangrove species. The microbial composition, including key functional groups, was assessed using Illumina sequencing. Bioinformatics analysis showed that there was a significant difference in the microbiomes between the protected Bamen Bay and the unprotected Dongzhai Bay. The overall microbiome was assigned into 78 phyla and Proteobacteria was the most abundant phylum at both sites. In the protected wetland, there were fewer marine-related microbial communities, such as sulfate-reducing bacteria, and more terrestrial-related communities, such as Verrucomicrobia methanotrophs. We also observed distinct microbial compositions among the different mangrove species at the protected site. Our data suggest that the different microbiomes of the two mangrove wetlands are the result of a complex interaction of the different environmental variables at the two sites.

Biogenic Mn-Oxides in Subseafloor Basalts

PubMed Central

Ivarsson, Magnus; Broman, Curt; Gustafsson, Håkan; Holm, Nils G.

2015-01-01

The deep biosphere of the subseafloor basalts is recognized as a major scientific frontier in disciplines like biology, geology, and oceanography. Recently, the presence of fungi in these environments has involved a change of view regarding diversity and ecology. Here, we describe fossilized fungal communities in vugs in subseafloor basalts from a depth of 936.65 metres below seafloor at the Detroit Seamount, Pacific Ocean. These fungal communities are closely associated with botryoidal Mn oxides composed of todorokite. Analyses of the Mn oxides by Electron Paramagnetic Resonance spectroscopy (EPR) indicate a biogenic signature. We suggest, based on mineralogical, morphological and EPR data, a biological origin of the botryoidal Mn oxides. Our results show that fungi are involved in Mn cycling at great depths in the seafloor and we introduce EPR as a means to easily identify biogenic Mn oxides in these environments. PMID:26107948

Petrology of dune sand derived from basalt on the Ka'u Desert, Hawaii

NASA Technical Reports Server (NTRS)

Gooding, J. L.

1982-01-01

Dune sand from the Ka'u Desert, southwest flank of Kilauea volcano, Hawaii, is moderately well-sorted (median = 1.60 Phi, deviation = 0.60, skewness = 0.25, kurtosis = 0.68) and composed mostly of frosted subangular particles of basalt glass ('unfractionated' olivine-normative tholeitte), olivine, lithic fragments (subophitic and intersertal basalts; magnetite-ilmenite-rich basalts), reticular basalt glass, magnetite, ilmenite, and plagioclase, in approximately that order of abundance. Quantitative lithological comparison of the dune sand with sand-sized ash from the Keanakakoi Formation supports suggestions that the dune sand was derived largely from Keanakakoi ash. The dune sand is too well sorted to have been emplaced in its present form by base-surge but could have evolved by post-eruption reworking of the ash.

Assessing Causes and Consequences of Columbia River Basalt Volcanism with Zircon Geochronology

NASA Astrophysics Data System (ADS)

Kasbohm, J.; Schoene, B.

2017-12-01

The Columbia River Basalt (CRB) is the youngest and best-preserved continental flood basalt province, but its mechanism of origin remains disputed. While some workers favor a mantle plume source to generate the large volume of flood basalts, others prefer subduction-related processes such as slab breakoff. Additionally, based on current geochronological (K-Ar and 40Ar/39Ar) estimates for the age of the CRB, there appears to be a very broad temporal coincidence between the main eruptive phase of the CRB and the Mid-Miocene Climate Optimum (MMCO), a period of elevated global temperatures and atmospheric CO2. Currently, large analytical uncertainties preclude the detailed calculation of volumetric eruption rates, which will be essential to test models of origin and to pinpoint correlation to climate records. To develop a complete record of eruption rates through the CRB, we use CA-ID-TIMS U-Pb zircon geochronology, which is capable of yielding 2σ uncertainties on single analyses of ca. 10 kyr. While basalt does not typically saturate zircon, interflow sediments, paleosols, and volcaniclastic layers in the CRB stratigraphy contain felsic zircon-bearing ash, likely sourced from both the Cascades arc and incipient Snake River plain volcanism. We use U-Pb zircon dates from these horizons to bracket the age of basalt flows. Preliminary results show that 88% of the total volume of the CRB (the Imnaha, Grande Ronde, and Wanapum Basalts) erupted in 700 kyr, beginning 16.6 Ma, with an average effusion rate of 0.26 km3/yr and with occurrence of lava flows propagating from south to north at a minimum rate of 0.3 m/yr. Thus far, these results do not preclude a mantle plume origin, but do place quantitative constraints on geodynamic numerical models hoping to constrain flood basalt origins. Although models based on prior geochronology have suggested that degassing from the CRB was insufficient to cause the MMCO, our calculated reduction in the duration of the main phase of CRB

Role of syn-eruptive plagioclase disequilibrium crystallization in basaltic magma ascent dynamics.

PubMed

La Spina, G; Burton, M; De' Michieli Vitturi, M; Arzilli, F

2016-12-12

Timescales of magma ascent in conduit models are typically assumed to be much longer than crystallization and gas exsolution for basaltic eruptions. However, it is now recognized that basaltic magmas may rise fast enough for disequilibrium processes to play a key role on the ascent dynamics. The quantification of the characteristic times for crystallization and exsolution processes are fundamental to our understanding of such disequilibria and ascent dynamics. Here we use observations from Mount Etna's 2001 eruption and a magma ascent model to constrain timescales for crystallization and exsolution processes. Our results show that plagioclase reaches equilibrium in 1-2 h, whereas ascent times were <1 h. Using these new constraints on disequilibrium plagioclase crystallization we also reproduce observed crystal abundances for different basaltic eruptions. The strong relation between magma ascent rate and disequilibrium crystallization and exsolution plays a key role in controlling eruption dynamics in basaltic volcanism.

Deep-ocean basalts: inert gas content and uncertainties in age dating.

PubMed

Noble, C S; Naughton, J J

1968-10-11

The radiogenic argon and helium contents of three basalts erupted into the deep ocean from an active volcano (Kilauea) have been measured. Ages calculated from these measurements increase with sample depth up to 22 million years for lavas deduced to be recent. Caution is urged in applying dates from deep-ocean basalts in studies on ocean-floor spreading.

Heat resistance study of basalt fiber material via mechanical tests

NASA Astrophysics Data System (ADS)

Gao, Y. Q.; Jia, C.; Meng, L.; Li, X. H.

2017-12-01

This paper focuses on the study of the relationship between the fracture strength of basalt rovings and temperature. Strong stretching performance of the rovings has been tested after the treatment at fixed temperatures but different heating time and then the fracture strength of the rovings exposed to the heating at different temperatures and cooled in different modes investigated. Finally, the fracture strength of the basalt material after the heat treatment was studied. The results showed that the room-temperature strength tends to decrease with an increase of the heat treatment time at 250 °C, but it has the local maximum after 2h heating. And the basalt rovings strength increased after the heat treatment up to 200 °C. It was 16.7 percent higher than the original strength. The strength depends not only on the temperature and duration of the heating, but also on the cooling mode. The value of the strength measured after cold water cooling was less by 6.3% compared with an ambient air cooling mode. The room-temperature breaking strength of the rovings heated at 200 °C and 100 °C for 2 hours each increased by about 14.6% with respect to unpretreated basalt rovings.

Petrogenesis of high-Ti and low-Ti basalts: high-pressure and high-temperature experimental study

NASA Astrophysics Data System (ADS)

Yang, J.; WANG, C.; Jin, Z.

2017-12-01

Geochemical and petrological studies have revealed the existence of high-Ti and low-Ti basalts in large igneous provinces. However, the petrogenesis of them are still under debate. Several different mechanisms have been proposed: (1) the high-Ti basalts are formed by the melting of mantle plume containing recycled oceanic crust or delaminated lower crust (Spandler et al., 2008) while low-Ti basalts are formed by the melting of subcontinental lithospheric mantle (Xiao et al., 2004); (2) both of them are from mantle plume or asthenospheric source, but the production of high-Ti basalts are associated with the thick lithosphere and relevant low degrees of melting while the low-Ti basalts are controlled by the thin lithosphere with high degrees of melting (Arndt et al., 1993; Xu et al., 2001). Almost all authors emphasize the role of partial melting but less discuss the crystallization differentiation process. The low Mg# (< 0.7) of these basalts provides that they are far away from direct melting of mantle peridotite. In addition, seismic data indicate unusually high seismic velocities bodies beneath LIPs which explained by the fractionated cumulates from picritic magmas (Farnetani et al., 1996). Therefore, we believed that the crystallization differentiation process might play a more significant role in the genesis of high-Ti and low-Ti basalts. In order to investigate the generation of these basalts, a series of high pressure and high temperature partial crystallization experiments were performed by using piston-cylinder and multi-anvil press at pressures of 1.5, 3.0 and 5.0 GPa and a temperature range of 1200-1700°. Two synthetic picrite glass with different chemical compositions were used as starting materials. Our experimental results show that Ti is preferred to be concentrated in the residual melt during crystallization differentiation. For the same melt fraction, the residual melt of higher pressure experiments has relatively higher TiO2 concentration and

Chemistry and isotope ratios of sulfur in basalts and volcanic gases at Kilauea volcano, Hawaii

USGS Publications Warehouse

Sakai, H.; Casadevall, T.J.; Moore, J.G.

1982-01-01

Eighteen basalts and some volcanic gases from the submarine and subaerial parts of Kilauea volcano were analyzed for the concentration and isotope ratios of sulfur. By means of a newly developed technique, sulfide and sulfate sulfur in the basalts were separately but simultaneously determined. The submarine basalt has 700 ?? 100 ppm total sulfur with ??34S??s of 0.7 ?? 0.1 ???. The sulfate/sulfide molar ratio ranges from 0.15 to 0.56 and the fractionation factor between sulfate and sulfide is +7.5 ?? 1.5???. On the other hand, the concentration and ??34S??s values of the total sulfur in the subaerial basalt are reduced to 150 ?? 50 ppm and -0.8 ?? 0.2???, respectively. The sulfate to sulfide ratio and the fractionation factor between them are also smaller, 0.01 to 0.25 and +3.0???, respectively. Chemical and isotopic evidence strongly suggests that sulfate and sulfide in the submarine basalt are in chemical and isotopic equilibria with each other at magmatic conditions. Their relative abundance and the isotope fractionation factors may be used to estimate the f{hook}o2 and temperature of these basalts at the time of their extrusion onto the sea floor. The observed change in sulfur chemistry and isotopic ratios from the submarine to subaerial basalts can be interpreted as degassing of the SO2 from basalt thereby depleting sulfate and 34S in basalt. The volcanic sulfur gases, predominantly SO2, from the 1971 and 1974 fissures in Kilauea Crater have ??34S values of 0.8 to 0.9%., slightly heavier than the total sulfur in the submarine basalts and definitely heavier than the subaerial basalts, in accord with the above model. However, the ??34S value of sulfur gases (largely SO2) from Sulfur Bank is 8.0%., implying a secondary origin of the sulfur. The ??34S values of native sulfur deposits at various sites of Kilauea and Mauna Loa volcanos, sulfate ions of four deep wells and hydrogen sulfide from a geothermal well along the east rift zone are also reported. The high

Seeking a paleontological signature for mass extinctions caused by flood basalt eruptions

NASA Astrophysics Data System (ADS)

Payne, J.; Bush, A. M.; Chang, E. T.; Heim, N. A.; Knope, M. L.; Pruss, S. B.

2016-12-01

Flood basalt eruptions coincide with numerous extinction events in the fossil record. Increasingly precise absolute age determinations for both the timing of eruption and of species extinctions have strengthened the case for flood basalt eruptions as the single most important trigger for major mass extinction events in the fossil record. However, the extent to which flood basalt eruptions cause a pattern of biotic loss distinctive from extinctions triggered by other geological or biological processes remains an open question. In the absence of diagnostic mapping between geological triggers and biological losses, establishing the identities of causal agents for mass extinctions will continue to depend primarily on evidence for temporal coincidence. Here we use a synoptic database of marine animal genera spanning the Phanerozoic, including times of first and last occurrence, body size, motility, life position, feeding mode, and respiratory physiology to assess whether extinction events temporally associated with flood basalt eruptions exhibit a diagnostic pattern of extinction selectivity. We further ask whether any events not associated with known large igneous provinces nevertheless display extinction patterns suggestive of such a cause. Finally, we ask whether extinction events associated with other primary causes, such as glaciation or bolide impact, are distinguishable from events apparently triggered by flood basalt eruptions on the basis of extinction selectivity patterns

Corrosion and tribological properties of basalt fiber reinforced composite materials

NASA Astrophysics Data System (ADS)

Ha, Jin Cheol; Kim, Yun-Hae; Lee, Myeong-Hoon; Moon, Kyung-Man; Park, Se-Ho

2015-03-01

This experiment has examined the corrosion and tribological properties of basalt fiber reinforced composite materials. There were slight changes of weight after the occurring of corrosion based on time and H2SO4 concentration, but in general, the weight increased. It is assumed that this happens due to the basalt fiber precipitate. Prior to the corrosion, friction-wear behavior showed irregular patterns compared to metallic materials, and when it was compared with the behavior after the corrosion, the coefficient of friction was 2 to 3 times greater. The coefficient of friction of all test specimen ranged from 0.1 to 0.2. Such a result has proven that the basalt fiber, similar to the resin rubber, shows regular patterns regardless of time and H2SO4 concentration because of the space made between resins and reinforced materials.

Oxygen-isotope composition of ground water and secondary minerals in Columbia Plateau basalts: implications for the paleohydrology of the Pasco Basin

USGS Publications Warehouse

Hearn, P.P.; Steinkampf, W.C.; Horton, D.G.; Solomon, G.C.; White, L.D.; Evans, J.R.

1989-01-01

Concentrations of 18O and deuterium in ground waters beneath the Hanford Reservation, Washington State, suggest that the meteoric waters recharging the basalt aquifers have been progressively depleted in these isotopes since at least Pleistocene time. This conclusion is supported by oxygen-isotope analyses of low-temperature secondary minerals filling vugs and fractures in the basalts, which are used to approximate the 18O content of ground water at the time the mineral assemblage formed. A fossil profile of ??18O values projected for ground water in a 1500 m vertical section beneath the reservation suggests that the vertical mixing of shallow and deep ground water indicated by present-day hydrochemical data was also occurring during Neogene time. These data also suggest that a unidirectional depletion of 18O and deuterium recorded in Pleistocene ground waters may have extended considerably further back in time. This shift is tentatively attributed to the orographic depletion of 18O associated with the progressive uplift of the Cascade Range since the middle Miocene. -Authors

Pyroclastic Deposits in Floor-Fractured Craters: A Unique Style or Lunar Basaltic Volcanism?

NASA Technical Reports Server (NTRS)

Allen, Carlton C.; DonaldsonHanna, Kerri L.; Pieters, Carle M.; Moriarty, Daniel P.; Greenhagen, Benjamin T.; Bennett, Kristen A.; Kramer, Georgiana Y.; Paige, David A.

2013-01-01

The lunar maria were formed by effusive fissure flows of low-viscosity basalt. Regional pyroclastic deposits were formed by deep-sourced fire-fountain eruptions dominated by basaltic glass. Basaltic material is also erupted from small vents within floor-fractured impact craters. These craters are characterized by shallow, flat floors cut by radial, concentric and/or polygonal fractures. Schultz [1] identified and classified over 200 examples. Low albedo pyroclastic deposits originate from depressions along the fractures in many of these craters.

Mineralization of Basalts in the CO 2-H 2O-H 2S System

DOE Office of Scientific and Technical Information (OSTI.GOV)

Schaef, Herbert T.; McGrail, B. Peter; Owen, Antionette T.

2013-05-10

Basalt samples representing five different formations were immersed in water equilibrated with supercritical carbon dioxide containing 1% hydrogen sulfide (H2S) at reservoir conditions (100 bar, 90°C) for up to 3.5 years. Surface coatings in the form of pyrite and metal cation substituted carbonates were identified as reaction products associated with all five basalts. In some cases, high pressure tests contained excess H2S, which produced the most corroded basalts and largest amount of secondary products. In comparison, tests containing limited amounts of H2S appeared least reacted with significantly less concentrations of reaction products. In all cases, pyrite appeared to precede carbonation,more » and in some instances, was observed in the absence of carbonation such as in cracks, fractures, and within the porous glassy mesostasis. Armoring reactions from pyrite surface coatings observed in earlier shorter duration tests were found to be temporary with carbonate mineralization observed with all the basalts tested in these long duration experiments. Geochemical simulations conducted with the geochemical code EQ3/6 accurately predicted early pyrite precipitation followed by formation of carbonates. Reactivity with H2S was correlated with measured Fe(II)/Fe(III) ratios in the basalts with more facile pyrite formation occurring with basalts containing more Fe(III) phases. These experimental and modeling results confirm potential for long term sequestration of acid gas mixtures in continental flood basalt formations.« less

Basalts, gabbroic cumulates and andesite generation in the Lesser Antilles - An experimental perspective

NASA Astrophysics Data System (ADS)

Pichavant, M.; Di Carlo, I.; Lesne, P.; Wulput, L.; Maury, R. C.; Macdonald, R.

2012-12-01

New experiments have been performed to explore the petrological relationships between basaltic magmas, gabbroic cumulates, amphibole (Amph) crystallization and andesite generation in the Lesser Antilles arc. Four natural basalt starting materials representative of typical high-MgO (HMB) and high-Al2O3 (HAB) along the arc have been selected. Results are combined with previous experimental work on mafic melts from Mt Pelée and St Vincent. Under H2O-saturated conditions, Amph stability is about 25°C higher in HMB than HAB, being limited to a maximum of1050-1100°C at 10 kbar. Amph is the liquidus phase for the 3 high-Al2O3 basalts above 4 kbar (> 6 wt% H2O in melt), and very close to the liquidus for the high-MgO basalt at 10 kbar (9-10 wt% H2O in melt). Derivative liquids from the crystallization of Amph-bearing assemblages are basaltic to dacitic, depending on parental melt composition, extent of crystallization and experimental fO2. Fractionation of > 20 wt% Amph is necessary to produce andesitic-dacitic liquids from basaltic parents. Amph composition reflects the Al/Si and Mg# of their parental melts. It generally divides into two groups, one Si-poor and Al-rich (pargasite: gabbroic cumulates, basalts, andesites) and the other Si-rich and Al-poor (edenite: dioritic cumulates, andesites, dacites). The systematic presence of Amph in gabbroic cumulate blocks, its near-absence in basaltic to andesitic lavas, plus the compositional contrast between the two Amph groups, suggest the existence of an Amph-free "window" along the P-T-X magma evolution trend. In gabbroic cumulates, Amph shows systematic differences between islands (similar Mg# but higher AlIV in Martinique than in St Vincent). Our experimental results suggest that the origin of the St Vincent gabbroic assemblages can be traced back to residual melts generated from the crystallization of high-MgO basalts. However, Amph with the highest AlIV(eg, Martinique, Montserrat) have not been reproduced in our

Geochemistry, 40Ar/39Ar geochronology, and geodynamic implications of Early Cretaceous basalts from the western Qinling orogenic belt, China

NASA Astrophysics Data System (ADS)

Zhang, Feifei; Wang, Yuejun; Cawood, Peter A.; Dong, Yunpeng

2018-01-01

The Qinling-Dabie orogenic belt was formed by the collision of the North and South China Cratons during the Early Mesozoic and subsequently developed into an intracontinental tectonic process during late Mesozoic. Field investigations identified the presence of late Mesozoic basalts in the Duofutun and Hongqiang areas in the western Qinling orogenic belt. The petrogenesis of these basalts provides an important constraint on the late Mesozoic geodynamics of the orogen. The representative basaltic samples yield the 40Ar/39Ar plateau age of about 112 Ma. These samples belong to the alkaline series and have SiO2 ranging from 44.98 wt.% to 48.19 wt.%, Na2O + K2O from 3.44 wt% to 5.44 wt%, and MgO from 7.25 wt.% to 12.19 wt.%. They demonstrate the right-sloping chondrite-normalized REE patterns with negligible Eu anomalies (1.00-1.10) and PM-normalized patterns enriched in light rare earth element, large ion lithophile element and high field strength element, similar to those of OIB rocks. These samples additionally show an OIB-like Sr-Nd isotopic signature with εNd(t) values ranging from +6.13 to +10.15 and initial 87Sr/86Sr ratios from 0.7028 to 0.7039, respectively. These samples are geochemically subdivided into two groups. Group 1 is characterized by low Al2O3 and high TiO2 and P2O5 contents, as well as high La/Yb ratios (>20), being the product of the high-pressure garnet fractionation from the OIB-derived magma. Group 2 shows higher Al2O3 but lower P2O5 contents and La/Yb ratios (<20) than Group 1, originating from asthenospheric mantle with input of delaminated lithospheric component. In combination with available data, it is proposed for the petrogenetic model of the Early Cretaceous thickened lithospheric delamination in response to the asthenospheric upwelling along the western Qinling orogenic belt.

Subduction of hydrated basalt of the oceanic crust: Implications for recycling of water into the upper mantle and continental growth

NASA Technical Reports Server (NTRS)

Rapp, R. P.

1994-01-01

Subduction zones are presently the dominant sites on Earth for recycling and mass transfer between the crust and mantle; they feed hydrated basaltic oceanic crust into the upper mantle, where dehydration reactions release aqueous fluids and/or hydrous melts. The loci for fluid and/or melt generation will be determined by the intersection of dehydration reaction boundaries of primary hydrous minerals within the subducted lithosphere with slab geotherms. For metabasalt of the oceanic crust, amphibole is the dominant hydrous mineral. The dehydration melting solidus, vapor-absent melting phase relationships; and amphibole-out phase boundary for a number of natural metabasalts have been determined experimentally, and the pressure-temperature conditions of each of these appear to be dependent on bulk composition. Whether or not the dehydration of amphibole is a fluid-generating or partial melting reaction depends on a number of factors specific to a given subduction zone, such as age and thickness of the subducting oceanic lithosphere, the rate of convergence, and the maturity of the subduction zone. In general, subduction of young, hot oceanic lithosphere will result in partial melting of metabasalt of the oceanic crust within the garnet stability field; these melts are characteristically high-Al2O3 trondhjemites, tonalites and dacites. The presence of residual garnet during partial melting imparts a distinctive trace element signature (e.g., high La/Yb, high Sr/Y and Cr/Y combined with low Cr and Y contents relative to demonstrably mantle-derived arc magmas). Water in eclogitized, subducted basalt of the oceanic crust is therefore strongly partitioned into melts generated below about 3.5 GPa in 'hot' subduction zones. Although phase equilibria experiments relevant to 'cold' subduction of hydrated natural basalts are underway in a number of high-pressure laboratories, little is known with respect to the stability of more exotic hydrous minerals (e.g., ellenbergite) and

Seismic imaging of Late Cretaceous magmatic system in the northern margin of South China Sea

NASA Astrophysics Data System (ADS)

Xia, S.; Xu, H.; Sun, J.; Zhao, F.; Fan, C.

2017-12-01

The origin and evolution of magmatism in the rifting margins are the fundamentally geological subjects, and remain the focus of intense study. Different from the classical volcanic or nonvolcanic rifting margins, the northern margin of South China Sea (SCS) experienced uniquely regional tectonic processes, and formed plentiful intraplate seamounts mainly at the postrift period. There is considerable controversy over what caused the intensively postrift intraplate volcanism. Here we combine a new crustal structure with previously systematic petrologic and seismic tomographic results to first provide importantly new insights into a mantle plume origin and complex multilevel plumbing system of intraplate seamounts in the northern margin of SCS. Large amounts of active melts from the lower mantle migrated upward and reached the base of the lithosphere. The volatile-rich and overheated magmas continued ascending along the weak zone through the lithosphere and intruded into the lower crust. The intrusion magmas then ascended forward along the faults formed during the rifting, and supplied the magma source for the formation of intraplate seamounts in the northern margin of SCS. It supplies an important implication for the volume and range of late Cenozoic basaltic magmatism deriving from the Hainan mantle plume. Keywords: South China Sea; Late Cretaceous; Magmatic System; Hainan Plume AcknowledgementsThe field work of this study was assisted by the captain and crew of the R/V Shiyan 2. Prof. Xuelin Qiu supplied great helps for the successful implementation of the cruise. This work was partially supported by grants from the National Natural Science Foundation of China (Grant Nos. 91328206 and 41576041).

Role of syn-eruptive plagioclase disequilibrium crystallization in basaltic magma ascent dynamics

PubMed Central

La Spina, G.; Burton, M.; de' Michieli Vitturi, M.; Arzilli, F.

2016-01-01

Timescales of magma ascent in conduit models are typically assumed to be much longer than crystallization and gas exsolution for basaltic eruptions. However, it is now recognized that basaltic magmas may rise fast enough for disequilibrium processes to play a key role on the ascent dynamics. The quantification of the characteristic times for crystallization and exsolution processes are fundamental to our understanding of such disequilibria and ascent dynamics. Here we use observations from Mount Etna's 2001 eruption and a magma ascent model to constrain timescales for crystallization and exsolution processes. Our results show that plagioclase reaches equilibrium in 1–2 h, whereas ascent times were <1 h. Using these new constraints on disequilibrium plagioclase crystallization we also reproduce observed crystal abundances for different basaltic eruptions. The strong relation between magma ascent rate and disequilibrium crystallization and exsolution plays a key role in controlling eruption dynamics in basaltic volcanism. PMID:27941750

South Pole-Aitken Sample Return Mission: Collecting Mare Basalts from the Far Side of the Moon

NASA Technical Reports Server (NTRS)

Gillis, J. J.; Jolliff, B. L.; Lucey, P. G.

2003-01-01

We consider the probability that a sample mission to a site within the South Pole-Aitken Basin (SPA) would return basaltic material. A sample mission to the SPA would be the first opportunity to sample basalts from the far side of the Moon. The near side basalts are more abundant in terms of volume and area than their far-side counterparts (16:1), and the basalt deposits within SPA represent approx. 28% of the total basalt surface area on the far side. Sampling far-side basalts is of particular importance because as partial melts of the mantle, they could have derived from a mantle that is mineralogically and chemically different than determined for the nearside, as would be expected if the magma ocean solidified earlier on the far side. For example, evidence to support the existence of high-Th basalts like those that appear to be common on the nearside in the Procellarum KREEP Terrane has been found. Although SPA is the deepest basin on the Moon, it is not extensively filled with mare basalt, as might be expected if similar amounts of partial melting occurred in the mantle below SPA as for basins on the near side. These observations may mean that mantle beneath the far-side crust is lower in Th and other heat producing elements than the nearside. One proposed location for a sample-return landing site is 60 S, 160 W. This site was suggested to maximize the science return with respect to sampling crustal material and SPA impact melt, however, basaltic samples would undoubtedly occur there. On the basis of Apollo samples, we should expect that basaltic materials would be found in the vicinity of any landing site within SPA, even if located away from mare deposits. For example, the Apollo 16 mission landed in an ancient highlands region 250-300 km away from the nearest mare-highlands boundary yet it still contains a small component of basaltic samples (20 lithic fragments ranging is size from <1 to .01 cm). A soil sample from the floor of SPA will likely contain an

Role for syn-eruptive plagioclase disequilibrium crystallisation in basaltic magma ascent dynamics

NASA Astrophysics Data System (ADS)

La Spina, Giuseppe; Burton, Mike; de'Michieli Vitturi, Mattia; Arzilli, Fabio

2017-04-01

Magma ascent dynamics in volcanic conduits play a key role in determining the eruptive style of a volcano. The lack of direct observations inside the conduit means that numerical conduit models, constrained with observational data, provide invaluable tools for quantitative insights into complex magma ascent dynamics. The highly nonlinear, interdependent processes involved in magma ascent dynamics require several simplifications when modelling their ascent. For example, timescales of magma ascent in conduit models are typically assumed to be much longer than crystallisation and gas exsolution for basaltic eruptions. However, it is now recognized that basaltic magmas may rise fast enough for disequilibrium processes to play a key role on the ascent dynamics. The quantification of the characteristic times for crystallisation and exsolution processes are fundamental to our understanding of such disequilibria and ascent dynamics. Using observations from Mount Etna's 2001 eruption and a magma ascent model we are able to constrain timescales for crystallisation and exsolution processes. Our results show that plagioclase reaches equilibrium in 1-2 h, whereas ascent times were 1 h. Furthermore, we have related the amount of plagioclase in erupted products with the ascent dynamics of basaltic eruptions. We find that relatively high plagioclase content requires crystallisation in a shallow reservoir, whilst a low plagioclase content reflects a disequilibrium crystallisation occurring during a fast ascent from depth to the surface. Using these new constraints on disequilibrium plagioclase crystallisation we also reproduce observed crystal abundances for different basaltic eruptions: Etna 2002/2003, Stromboli 2007 (effusive eruption) and 1930 (paroxysm) and different Pu'u' O'o eruptions at Kilauea (episodes 49-53). Therefore, our results show that disequilibrium processes play a key role on the ascent dynamics of basaltic magmas and cannot be neglected when describing basaltic

Deep Crustal Structure beneath Large Igneous Provinces and the Petrologic Evolution of Flood Basalts

NASA Astrophysics Data System (ADS)

Richards, Mark; Ridley, Victoria

2010-05-01

We present a review of seismological constraints on deep crustal structures underlying large igneous provinces (LIPs), largely from wide-angle seismic refraction surveys. The main purpose of this review is to ascertain whether this seismic evidence is consistent with, or contrary to, petrological models for the genesis of flood basalt lavas. Where high-quality data are available beneath continental flood basalt (CFB) provinces (Emeishan, Columbia River, Deccan, Siberia), high-velocity structures (Vp ~6.9-7.5 km/sec) are typically found immediately overlying the Moho in layers of order ~5-15 km thick. Oceanic plateau (OP) LIPs exhibit similar layers, with a conspicuous layer of very high crustal velocity (Vp~7.7 km/sec) beneath the enormous Ontong-Java plateau. These structures are similar to inferred ultramafic underplating structures seen beneath active hotspots such as Hawaii, the Marqueses, and La Reunion. Petrogenetic models for flood basalt volcanism based on hot plume melting beneath mature lithosphere suggest that these deep seismic structures may consist in large part of cumulate bodies of olivine and clinopyroxene which result from ponding and deep-crustal fractionation of ultramafic primary melts. Such fractionation is necessary to produce basalts with typical MgO contents of ~6-8%, as observed for the vast bulk of observed flood basalts, from primary melts with MgO contents of order ~15-18% (or greater) such as result from hot, deep melting beneath the lithosphere. The volumes of cumulate bodies and ultramafic intrusions in the lowermost crust, often described in the literature as "underplating," are comparable to those of the overlying basaltic formations, also consistent with petrological models. Further definition of the deep seismic structure beneath such prominent LIPs as the Ontong-Java Plateau could place better constraints on flood basalt petrogenesis by determining the relative volumes of ultramafic bodies and basaltic lavas, thereby better

Sm-Nd and Rb-Sr Isotopic Studies of Meteorite Kalahari 009: An Old VLT Mare Basalt

NASA Technical Reports Server (NTRS)

Shih, C.-Y.; Nyquist, L. E.; Reese, Y.; Bischoff, A.

2008-01-01

Lunar meteorite Kalahari 009 is a fragmental basaltic breccia contain ing various very-low-Ti (VLT) mare basalt clasts embedded in a fine-g rained matrix of similar composition. This meteorite and lunar meteorite Kalahari 008, an anorthositic breccia, were suggested to be paired mainly due to the presence of similar fayalitic olivines in fragment s found in both meteorites. Thus, Kalahari 009 probably represents a VLT basalt that came from a locality near a mare-highland boundary r egion of the Moon, as compared to the typical VLT mare basalt samples collected at Mare Crisium during the Luna-24 mission. The concordant Sm-Nd and Ar-Ar ages of such a VLT basalt (24170) suggest that the extrusion of VLT basalts at Mare Crisium occurred 3.30 +/- 0.05 Ga ag o. Previous age results for Kalahari 009 range from approximately 4.2 Ga by its Lu-Hf isochron age to 1.70?0.04 Ga of its Ar-Ar plateau ag e. However, recent in-situ U-Pb dating of phosphates in Kalahari 009 defined an old crystallization age of 4.35+/- 0.15 Ga. The authors su ggested that Kalahari 009 represents a cryptomaria basalt. In this r eport, we present Sm-Nd and Rb-Sr isotopic results for Kalahari 009, discuss the relationship of its age and isotopic characteristics to t hose of other L-24 VLT mare basalts and other probable cryptomaria ba salts represented by Apollo 14 aluminous mare basalts, and discuss it s petrogenesis.

Investigation on mechanical properties of basalt composite fabrics (experiment study)

NASA Astrophysics Data System (ADS)

Talebi Mazraehshahi, H.; Zamani, H.

2010-06-01

To fully appreciate the role and application of composite materials to structures, correct understanding of mechanical behaviors required for selection of optimum material. Fabric reinforced composites are composed of a matrix that is reinforced with pliable fabric, glass fabric is most popular reinforcement for different application specially in aircraft structure, although other fabric material are also used. At this study new fabric material called basalt with epoxy resin introduced and mechanical behaviors of this material investigated from view point of testing. For this study two type of fabric with different thickness used. Comparison between this composite reinforcement with popular reinforcement as carbon, glass, kevlar performed. To determine mechanical properties of epoxy based basalt fabric following test procedure performed : 1). Tensile testing according to ASTM D3039 in 0° and 90° direction to find ultimate strength in tension and shear, modulus of elasticity, elangation and ultimate strain. 2). Compression testing according to EN 2850 ultimate compression strength and maximum deformation under compression loading. 3). Shear testing according to ASTM D3518-94 to find in plane shear response of polymer matrix composites materials. 4). Predict flexural properties of sandwich construction which manufactured from basalt facing with PVC foam core according to ASTM C393-94. Material strength properties must be based on enough tests of material to meet the test procedure specifications [1]. For this reason six specimens were manufactured for testing and the tests were performed on them using an INSTRON machine model 5582. In the study, the effect of percent of resin in basalt reinforced composite was investigated. Also the weights of the ballast based composites with different percent of resin were measured with conventional composites. As the weight is an important parameter in aerospace industry when the designer wants to replace one material with

Basaltic material in the main belt: a tale of two (or more) parent bodies?

NASA Astrophysics Data System (ADS)

Ieva, S.; Dotto, E.; Lazzaro, D.; Fulvio, D.; Perna, D.; Epifani, E. Mazzotta; Medeiros, H.; Fulchignoni, M.

2018-06-01

The majority of basaltic objects in the main belt are dynamically connected to Vesta, the largest differentiated asteroid known. Others, due to their current orbital parameters, cannot be easily dynamically linked to Vesta. This is particularly true for all the basaltic asteroids located beyond 2.5 au, where lies the 3:1 mean motion resonance with Jupiter. In order to investigate the presence of other V-type asteroids in the middle and outer main belt (MOVs) we started an observational campaign to spectroscopically characterize in the visible range MOV candidates. We observed 18 basaltic candidates from TNG and ESO - NTT between 2015 and 2016. We derived spectral parameters using the same approach adopted in our recent statistical analysis and we compared our data with orbital parameters to look for possible clusters of MOVs in the main belt, symptomatic for a new basaltic family. Our analysis seemed to point out that MOVs show different spectral parameters respect to other basaltic bodies in the main belt, which could account for a diverse mineralogy than Vesta; moreover, some of them belong to the Eos family, suggesting the possibility of another basaltic progenitor. This could have strong repercussions on the temperature gradient present in the early Solar System, and on our current understanding of differentiation processes.

Effects of nutritional level of concentrate-based diets on meat quality and expression levels of genes related to meat quality in Hainan black goats.

PubMed

Wang, Dingfa; Zhou, Luli; Zhou, Hanlin; Hou, Guanyu; Shi, Liguang; Li, Mao; Huang, Xianzhou; Guan, Song

2015-02-01

The present study investigated the effects of the nutritional levels of diets on meat quality and related gene expression in Hainan black goat. Twenty-four goats were divided into six dietary treatments and were fed a concentrate-based diet with two levels of crude protein (CP) (15% or 17%) and three levels of digestive energy (DE) (11.72, 12.55 or 13.39 MJ/kg DM) for 90 days. Goats fed the concentrate-based diet with 17% CP had significantly (P < 0.05) higher average daily gains (ADG) and better feed conversion rates (FCR). The pH 24h value tended to decrease (P < 0.05) with increasing DE levels. The tenderness of Longissimus dorsi muscle (LD) and Semimembranosus muscle (SM) reduced with increasing CP levels (P < 0.05). With increasing DE levels, tenderness was increased (P < 0.05). The heart fatty acid-binding protein (H-FABP) mRNA expression levels in LD and SM increased with increasing DE levels (P < 0.05), but decreased with increasing CP levels (P < 0.05). The calpastatin (CAST) and μ-calpain mRNA expressions levels in LD and SM were affected significantly (P < 0.05) by CP and DE levels in the diet. Therefore, the nutritional levels of diets affect meat quality and expression levels of genes associated with meat quality in Hainan black goats. © 2014 Japanese Society of Animal Science.

The Cenozoic magmatism of East-Africa: Part I - Flood basalts and pulsed magmatism

NASA Astrophysics Data System (ADS)

Rooney, Tyrone O.

2017-08-01

Cenozoic magmatism in East Africa results from the interplay between lithospheric extension and material upwelling from the African Large Low Shear Velocity Province (LLSVP). The modern focusing of East African magmatism into oceanic spreading centers and continental rifts highlights the modern control of lithospheric thinning in magma generation processes, however the widespread, and volumetrically significant flood basalt events of the Eocene to Early Miocene suggest a significant role for material upwelling from the African LLSVP. The slow relative motion of the African plate during the Cenozoic has resulted in significant spatial overlap in lavas derived from different magmatic events. This complexity is being resolved with enhanced geochronological precision and a focus on the geochemical characteristics of the volcanic products. It is now apparent that there are three distinct pulses of basaltic volcanism, followed by either bimodal lavas or silicic volcanic products during this period: (A) Eocene Initial Phase from 45 to 34 Ma. This is a period of dominantly basaltic volcanism focused in Southern Ethiopia and Northern Kenya (Turkana). (B) Oligocene Traps phase from 33.9 to 27 Ma. This period coincides with a significant increase in the aerial extent of volcanism with broadly age equivalent 1 to 2 km thick sequences of dominantly basalt centered on the NW Ethiopian Plateau and Yemen, (C) Early Miocene resurgence phase from 26.9 to 22 Ma. This resurgence in basaltic volcanism is seen throughout the region at ca. 24-23 Ma, but is less volumetrically significant than the prior two basaltic pulses. With our developing understanding of the persistence of LLSVP anomalies within the mantle, I propose that the three basaltic pulses are ostensibly manifestations of the same plume-lithosphere interaction, requiring revision to the duration, magmatic extent, and magma volume of the African-Arabian Large Igneous Province.

The Age of Rift-Related Basalts in East Antarctica

NASA Astrophysics Data System (ADS)

Leitchenkov, G. L.; Belyatsky, B. V.; Kaminsky, V. D.

2018-01-01

The Lambert Rift, which is a large intracontinental rift zone in East Antarctica, developed over a long period of geological time, beginning from the Late Paleozoic, and its evolution was accompanied by magmatic activity. The latest manifestation of magmatism is eruption of alkaline olivine-leucite basalts on the western side of the Lambert Rift; Rb-Sr dating referred its time to the Middle Eocene, although its genesis remained vague. In order to solve this problem, we found geochronometer minerals in basaltic samples and 68 apatite grains appeared to be suitable for analysis. Their ages and ages of host basalts, determined by the U-Pb local method on the SIMS SHRIMP-II, were significantly different (323 ± 31 Ma) from those assumed earlier. This age corresponds to the earliest stage of crustal extension in East Antarctica and to most of Gondwana. The new data crucially change the ideas about the evolution of Lambert Rift and demonstrate the ambiguity of K-Ar dates of the alkali effusive formed under long-term rifting.

Suitability of Spatial Interpolation Techniques in Varying Aquifer Systems of a Basaltic Terrain for Monitoring Groundwater Availability

NASA Astrophysics Data System (ADS)

Katpatal, Y. B.; Paranjpe, S. V.; Kadu, M. S.

2017-12-01

Geological formations act as aquifer systems and variability in the hydrological properties of aquifers have control over groundwater occurrence and dynamics. To understand the groundwater availability in any terrain, spatial interpolation techniques are widely used. It has been observed that, with varying hydrogeological conditions, even in a geologically homogenous set up, there are large variations in observed groundwater levels. Hence, the accuracy of groundwater estimation depends on the use of appropriate interpretation techniques. The study area of the present study is Venna Basin of Maharashtra State, India which is a basaltic terrain with four different types of basaltic layers laid down horizontally; weathered vesicular basalt, weathered and fractured basalt, highly weathered unclassified basalt and hard massive basalt. The groundwater levels vary with topography as different types of basalts are present at varying depths. The local stratigraphic profiles were generated at different types of basaltic terrains. The present study aims to interpolate the groundwater levels within the basin and to check the co-relation between the estimated and the observed values. The groundwater levels for 125 observation wells situated in these different basaltic terrains for 20 years (1995 - 2015) have been used in the study. The interpolation was carried out in Geographical Information System (GIS) using ordinary kriging and Inverse Distance Weight (IDW) method. A comparative analysis of the interpolated values of groundwater levels is carried out for validating the recorded groundwater level dataset. The results were co-related to various types of basaltic terrains present in basin forming the aquifer systems. Mean Error (ME) and Mean Square Errors (MSE) have been computed and compared. It was observed that within the interpolated values, a good correlation does not exist between the two interpolation methods used. The study concludes that in crystalline basaltic

Stress Corrosion Cracking of Basalt/Epoxy Composites under Bending Loading

NASA Astrophysics Data System (ADS)

Shokrieh, Mahmood M.; Memar, Mahdi

2010-04-01

The purpose of this research is to study the stress corrosion behavior of basalt/epoxy composites under bending loading and submerged in 5% sulfuric acid corrosive medium. There are limited numbers of research in durability of fiber reinforced polymer composites. Moreover, studies on basalt fibers and its composites are very limited. In this research, mechanical property degradation of basalt/epoxy composites under bending loading and submerged in acidic corrosive medium is investigated. Three states of stress, equal to 30%, 50% and 70% of the ultimate strength of composites, are applied on samples. High stress states are applied to the samples to accelerate the testing procedure. Mechanical properties degradation consists of bending strength, bending modulus of elasticity and fracture energy of samples are examined. Also, a normalized strength degradation model for stress corrosion condition is presented. Finally, microscopic images of broken cross sections of samples are examined.

Electron microprobe evaluation of terrestrial basalts for whole-rock K-Ar dating

USGS Publications Warehouse

Mankinen, E.A.; Brent, Dalrymple G.

1972-01-01

Four basalt samples for whole-rock K-Ar dating were analyzed with an electron microprobe to locate potassium concentrations. Highest concentrations of potassium were found in those mineral phases which were the last to crystallize. The two reliable samples had potassium concentrated in fine-grained interstitial feldspar and along grain boundaries of earlier formed plagioclase crystals. The two unreliable samples had potassium concentrated in the glassy matrix, demonstrating the ineffectiveness of basaltic glass as a retainer of radiogenic argon. In selecting basalt samples for whole-rock K-Ar dating, particular emphasis should be placed on determining the nature and condition of the fine-grained interstitial phases. ?? 1972.

Petrogenesis of the Northwest Africa 4898 high-Al mare basalt

NASA Astrophysics Data System (ADS)

Li, Shaolin; Hsu, Weibiao; Guan, Yunbin; Wang, Linyan; Wang, Ying

2016-07-01

Northwest Africa (NWA) 4898 is the only low-Ti, high-Al basaltic lunar meteorite yet recognized. It predominantly consists of pyroxene (53.8 vol%) and plagioclase (38.6 vol%). Pyroxene has a wide range of compositions (En12-62Fs25-62Wo11-36), which display a continuous trend from Mg-rich cores toward Ca-rich mantles and then to Fe-rich rims. Plagioclase has relatively restricted compositions (An87-96Or0-1Ab4-13), and was transformed to maskelynite. The REE zoning of all silicate minerals was not significantly modified by shock metamorphism and weathering. Relatively large (up to 1 mm) olivine phenocrysts have homogenous inner parts with Fo ~74 and sharply decrease to 64 within the thin out rims (~30 μm in width). Four types of inclusions with a variety of textures and modal mineralogy were identified in olivine phenocrysts. The contrasting morphologies of these inclusions and the chemical zoning of olivine phenocrysts suggest NWA 4898 underwent at least two stages of crystallization. The aluminous chromite in NWA 4898 reveals that its high alumina character was inherited from the parental magma, rather than by fractional crystallization. The mineral chemistry and major element compositions of NWA 4898 are different from those of 12038 and Luna 16 basalts, but resemble those of Apollo 14 high-Al basalts. However, the trace element compositions demonstrate that NWA 4898 and Apollo 14 high-Al basalts could not have been derived from the same mantle source. REE compositions of its parental magma indicate that NWA 4898 probably originated from a unique depleted mantle source that has not been sampled yet. Unlike Apollo 14 high-Al basalts, which assimilated KREEPy materials during their formation, NWA 4898 could have formed by closed-system fractional crystallization.

Feldspar basalts in lunar soil and the nature of the lunar continents

NASA Technical Reports Server (NTRS)

Reid, A. M.; Ridley, W. I.; Harmon, R. S.; Warner, J.; Brett, R.; Jakes, P.; Brown, R. W.

1974-01-01

It is found that 25% on the Apollo-14 glasses have the same composition as the glasses in two samples taken from the Luna-16 column. The compositions are equivalent to feldspar basalt and anorthosite gabbro, and are similar to the feldspar basalts identified from Surveyor-7 analysis for lunar continents.

K-Rich Basaltic Sources beneath Ultraslow Spreading Central Lena Trough in the Arctic Ocean

NASA Astrophysics Data System (ADS)

Ling, X.; Snow, J. E.; Li, Y.

2016-12-01

Magma sources fundamentally influence accretion processes at ultraslow spreading ridges. Potassium enriched Mid-Ocean Ridge Basalt (K-MORB) was dredged from the central Lena Trough (CLT) in the Arctic Ocean (Nauret et al., 2011). Its geochemical signatures indicate a heterogeneous mantle source with probable garnet present under low pressure. To explore the basaltic mantle sources beneath the study area, multiple models are carried out predicting melting sources and melting P-T conditions in this study. P-T conditions are estimated by the experimental derived thermobarometer from Hoang and Flower (1998). Batch melting model and major element model (AlphaMELTs) are used to calculate the heterogeneous mantle sources. The modeling suggests phlogopite is the dominant H2O-K bearing mineral in the magma source. 5% partial melting of phlogopite and amphibole mixing with depleted mantle (DM) melt is consistent with the incompatible element pattern of CLT basalt. P-T estimation shows 1198-1212oC/4-7kbar as the possible melting condition for CLT basalt. Whereas the chemical composition of north Lena Trough (NLT) basalt is similar to N-MORB, and the P-T estimation corresponds to 1300oC normal mantle adiabat. The CLT basalt bulk composition is of mixture of 40% of the K-MORB endmember and an N-MORB-like endmember similar to NLT basalt. Therefore the binary mixing of the two endmembers exists in the CLT region. This kind of mixing infers to the tectonic evolution of the region, which is simultaneous to the Arctic Ocean opening.

A novel basalt fiber-reinforced polylactic acid composite for hard tissue repair.

PubMed

Chen, Xi; Li, Yan; Gu, Ning

2010-08-01

A basalt fiber (BF) was, for the first time, introduced into a poly(l-lactic acid) (PLLA) matrix as innovative reinforcement to fabricate composite materials for hard tissue repair. Firstly, BF/PLLA composites and pure PLLA were produced by the methods of solution blending and freeze drying. The results showed that basalt fibers can be uniformly dispersed in the PLLA matrix and significantly improve the mechanical properties and hydrophilicity of the PLLA matrix. The presence of basalt fibers may retard the polymer degradation rate and neutralize the acid degradation from PLLA. Osteoblasts were cultured in vitro to evaluate the cytocompatibility of the composite. An MTT assay revealed that osteoblasts proliferated well for 7 days and there was little difference found in their viability on both PLLA and BF/PLLA films, which was consistent with the alkaline phosphatase (ALP) activity results. A fluorescent staining observation showed that osteoblasts grew well on the composites. SEM images displayed that osteoblasts tended to grow along the fiber axis. The formation of mineralized nodules was observed on the films by Alizarin red S staining. These results suggest that the presence of basalt fibers does not noticeably affect osteoblastic behavior and the designed composites are osteoblast compatible. It is concluded that basalt fibers, as reinforcing fibers, may have promising applications in hard tissue repair.

Genetic relations of oceanic basalts as indicated by lead isotopes

USGS Publications Warehouse

Tatsumoto, M.

1966-01-01

The isotopic compositions of lead and the concentrations of lead, uranium, and thorium in samples of oceanic tholeiite and alkali suites are determined, and the genetic relations of the oceanic basalts are discussed. Lead of the oceanic tholeiites has a varying lead-206 : lead-204 ratio between 17.8 and 18.8, while leads of the alkali basalt suites from Easter Island and Guadalupe Island are very radiogenic with lead-206 : lead-204 ratios between 19.3 and 20.4. It is concluded that (i) the isotopic composition of lead in oceanic tholeiite suggests that the upper mantle source region of the tholeiite was differentiated from an original mantle material more than 1 billion years ago and that the upper mantle is not homogeneous at the present time, (ii) less than 20 million years was required for the crystal differentiation within the alkali suite from Easter Island, (iii) no crustal contamination was involved in the course of differentiation of rocks from Easter Island; however, some crustal contamination may have affected Guadalupe Island rocks, and (iv) alkali basalt may be produced from the tholeiite in the oceanic region by crystal differentiation. Alternatively the difference in the isotopic composition of lead in oceanic basalts may be produced by partial melting at different depths of a differentiated upper mantle.

Modelling the upwelling offthe east Hainan Island coast in summer 2010

NASA Astrophysics Data System (ADS)

Bai, Peng; Gu, Yanzhen; Li, Peiliang; Wu, Kejian

2016-11-01

A synoptic-scale upwelling event that developed offthe east coast of the Hainan Island (EHIU) in the summer of 2010 is defined well via processing the Moderate Resolution Imaging Spectroradiometer (MODIS) sea surface temperature (SST) data. The Regional Ocean Modeling System (ROMS) with high spatial resolution has been used to investigate this upwelling event. By comparing the ROMS results against tide station data, Argo float profiles and MODIS SST, it is confirmed that the ROMS reproduces the EHIU well. The cooler-water core (CWC) distinguished by waters < 27.5°C in the EHIU, which occurred in the east Qiongzhou Strait mouth area and was bounded by a high temperature gradient, was the focus of this paper. Vertical structure of the CWC suggests that interaction between the westward flow and the bathymetry slope played a significant role in the formation of CWC. Numerical experiments indicated that the westward flow in the Qiongzhou Strait was the result of tidal rectification over variable topography (Shi et al., 2002), thus tides played a critical role on the development of the CWC. The negative wind stress curl that dominated the east Qiongzhou Strait mouth area suppressed the intensity of the CWC by 0.2-0.4°C. Further, nonlinear interaction between tidal currents and wind stress enhanced vertical mixing greatly, which would benefit the development of the CWC.

A 242-year seasonal-resolved speleothem record from Hainan Island: A window into variability of the precipitation δ18O in East Asia

NASA Astrophysics Data System (ADS)

Cai, Y.; An, Z.; Cheng, H.; Edwards, R. L.; Fung, I. Y.; Zhang, H.; Tan, L.; Bi, H.

2016-12-01

Hainan Island is located at the gateway of East Asian summer monsoon to the continent. The typical tropical monsoon climate at Hainan island is characterized by wet season during the summer and autumn and dry season during the winter and spring. Here, we present a seasonal resolved speleothem record spanning 242 years ( 50-292 AD) from Xianren Cave (E109°25`, N18°34`), which is situated in the Baoting County, Hainan Province. The monitoring inside the cave shows that the relative humidity kept saturated during the observed periods (one and half years) while the temperature varied seasonally following the temperature changes outside the cave, but with much smaller amplitude. Monthly observation of drip water inside the cave indicates that the isotope composition of drip water mainly responds to the changes in the precipitation isotope composition with less than two months' resident time. The visible annual lamination and distinct fluctuations of calcite Mg, Sr and Ba concentrations corroborate that the high-frequency oscillations of calcite δ18O largely capture the seasonal variation of the isotope composition of precipitation, although the temperature effect cannot be excluded. By setting the heaviest value of annual variation of calcite δ18O as the beginning of each annual cycle, we transferred the δ18O record of 11.2 cm in depth to a δ18O record of 242-year in age. The δ18O record of stalagmite XR-3 demonstrate clearly the annual, decadal and multi-decadal variations of amplitude from 2 to 4‰, in addition to the seasonal oscillation of amplitude varied from 1.5 to 2.5‰. The ensemble empirical mode decomposition results show that the dominant variability (54.6% of the total variance) is captured by the components at the timescale of 3-7 year, while the components on timescales of 22-24 -year, 80-year and 120-year capture 35.0%, 7.0% and 3.4% of the variance, respectively. We contribute the variability of speleothem δ18O at the timescale of 3-7 -year to

An experimental study of basaltic glass-H2O-CO2 interaction at 22 and 50 ° C: Implications for subsurface storage of CO2

NASA Astrophysics Data System (ADS)

Galeczka, Iwona; Wolff-Boenisch, Domenik; Oelkers, Eric H.; Gislason, Sigurdur R.

2014-05-01

A novel high pressure column flow reactor (HPCFR) was used to investigate the evolution of fluid chemistry along a 2.3 meter flow path during 37-104 days of pure water- and CO2-charged water- (0.3 M CO2(aq)) basaltic glass interaction experiments at 22 and 50 ° C. The scale of the HPCFR, the ability to sample a reactive fluid at discrete spatial intervals under pressure and the possibility to measure the dissolved inorganic carbon and pH in situ all render the HPCFR unique in comparison with other reactors constructed for studies of CO2-charged water-rock interaction. During the pure water-basaltic glass interaction experiment, the pH of the injected water evolved rapidly from 6.7 to 9-9.5 and most of the dissolved iron was consumed by secondary mineral formation, similar to natural basaltic groundwater systems. In contrast to natural systems, however, the dissolved aluminium concentration remained relatively high along the entire flow path. The reactive fluid was undersaturated with respect to basaltic glass and carbonate minerals, but supersaturated with respect to zeolites, clays, and Fe hydroxides. Basaltic glass dissolution in the CO2-charged water was closer to stoichiometry than in pure water. The mobility of metals increased significantly in the reactive fluid and the concentration of some metals, including Mn, Fe, Cr, Al, and As exceeded the WHO (World Health Organisation) allowable drinking water limits. Iron was mobile and the aqueous Fe2+/Fe3+ ratio increased along the flow path. Basaltic glass dissolution in the CO2-charged water did not overcome the pH buffer capacity of the fluid. The pH rose only from an initial pH of 3.4 to 4.5 along the first 18.5 cm of the column, then remained constant during the remaining 2.1 meters of the flow path. Increasing the temperature of the CO2-charged fluid from 22 to 50 ° C increased the relative amount of dissolved divalent iron along the flow path. After a significant initial increase along the first metre of

Expanding the Planetary Analog Test Sites in Hawaii - Planetary Basalt Manipulation

NASA Astrophysics Data System (ADS)

Kelso, R.

2013-12-01

The Pacific International Space Center for Exploration Systems (PISCES) is one of the very few planetary surface research test sites in the country that is totally funded by the state legislature. In recent expansions, PISCES is broadening its work in planetary test sites to include much more R&D work in the planetary surface systems, and the manipulation of basalt materials. This is to include laser 3D printing of basalt, 'lunar-concrete' construction in state projects for Hawaii, renewable energy, and adding lava tubes/skylights to their mix of high-quality planetary analog test sites. PISCES Executive Director, Rob Kelso, will be providing program updates on the interest of the Hawaii State Legislature in planetary surface systems, new applied research initiatives in planetary basalts and interests in planetary construction.

Paraná-Etendeka basalts in Misiones, Argentina; characterization and petrogenetic inferences

NASA Astrophysics Data System (ADS)

Rämö, O. T.; Heikkilä, P. A.

2013-12-01

The Early Cretaceous (ca. 130 Ma) Paraná-Etendeka flood basalts constitute one of the major Phanerozoic LIP sequences with an original volume probably in excess of 2.3 Mkm3.The bulk of this volcanic system is preserved in South America (Brazil, Uruguay, Paraguay, Argentina), where it manifests the onset of South Atlantic opening at present 25 degrees Southern Latitude. The sequence is overwhelmingly basaltic (ca. 90%), but also includes contemporaneous silicic volcanic rocks. Known as the Serra Geral Suite (e.g., Bellieni et al., 1984), it fills the Paraná Basin with a northward deepening strata of lavas with a maximum thickness of ca. 1500 m. We have collected and examined basalt samples from the west-central part (western flank) of the Paraná Basin in Misiones State, northeastern Argentina (54-55 degrees Western Longitude), where the estimated thickness of the basalt succession decreases from ca. 700 m in the east to ca. 300 m in the west. The examined samples are massive, aphyric (or microphyric with plagioclase and altered olivine microphenocrysts), and geochemically relatively evolved (Mg number 50-35) basalts and basaltic andesites. Their MgO values are between 6 and 3.7 wt.% and Ni content is relatively low (65-20 ppm). Incompatible trace element values increase with increasing fractionation (decreasing Mg number), e.g., Zr from 135 to 290 ppm, Ce from 45 to 105 ppm, Nd from 20 to 50 ppm, Sm from 5 to 11 ppm, Ba from 280 to 600 ppm, and Y from 25 to 50 ppm. In terms of Ti, the samples fall into two groups (1.9-2.3 and ca. 3.8 wt.% TiO2). These values conform, respectively, to the high-Ti, high-Ti/Y Paranapanema and Pitanga magma types of Peate et al. (1992) that govern the northern half of the Paraná basalt succession. Initial Nd and Sr isotope compositions of the two groups are remarkably uniform. Our analyzed ten samples have an average initial (at 134.6 Ma) epsilon-Nd value of -4.2 × 0.3 (1 SD) and an average initial 87Sr/86Sr of 0.70570 × 0

Similarities in basalt and rhyolite lava flow emplacement processes

NASA Astrophysics Data System (ADS)

Magnall, Nathan; James, Mike; Tuffen, Hugh; Vye-Brown, Charlotte

2016-04-01

Here we use field observations of rhyolite and basalt lava flows to show similarities in flow processes that span compositionally diverse lava flows. The eruption, and subsequent emplacement, of rhyolite lava flows is currently poorly understood due to the infrequency with which rhyolite eruptions occur. In contrast, the emplacement of basaltic lava flows are much better understood due to very frequent eruptions at locations such as Mt Etna and Hawaii. The 2011-2012 eruption of Cordón Caulle in Chile enabled the first scientific observations of the emplacement of an extensive rhyolite lava flow. The 30 to 100 m thick flow infilled a topographic depression with a negligible slope angle (0 - 7°). The flow split into two main channels; the southern flow advanced 4 km while the northern flow advanced 3 km before stalling. Once the flow stalled the channels inflated and secondary flows or breakouts formed from the flow front and margins. This cooling rather than volume-limited flow behaviour is common in basaltic lava flows but had never been observed in rhyolite lava flows. We draw on fieldwork conducted at Cordón Caulle and at Mt Etna to compare the emplacement of rhyolite and basaltic flows. The fieldwork identified emplacement features that are present in both lavas, such as inflation, breakouts from the flow font and margins, and squeeze-ups on the flow surfaces. In the case of Cordón Caulle, upon extrusion of a breakout it inflates due to a combination of continued lava supply and vesicle growth. This growth leads to fracturing and breakup of the breakout surface, and in some cases a large central fracture tens of metres deep forms. In contrast, breakouts from basaltic lava flows have a greater range of morphologies depending on the properties of the material in the flows core. In the case of Mt Etna, a range of breakout morphologies are observed including: toothpaste breakouts, flows topped with bladed lava as well as breakouts of pahoehoe or a'a lava. This

MARIUS HILLS REGION, MOON: Stratigraphy of low shields and mare basalts

NASA Astrophysics Data System (ADS)

Gebhart, Jennifer; Hiesinger, Harry; van der Bogert, Carolyn; Hendrik Pasckert, Jan; Weinauer, Julia; Lawrence, Samuel; Stopar, Julie; Robinson, Mark

2016-04-01

The Marius Hills region consists of more than 250 individual basaltic low shields (usually referred to as "domes") and cones, located on a broad topographic rise. The bases of numerous low shields have slope angles of ~2-3° whereas the upper portions have slopes of ~6-7° [1], interpreted to reflect changes in composition over time [1]. However, the absence of spectral differences between the two dome morphologies and the surrounding mare basalts suggests that the observed morphologies are more plausibly explained by changes in effusion rates, temperature (viscosity), and/or crystallization over time [e.g., 2]. Previous studies indicate that volcanism in this region occurred in the Upper Imbrian (3.2-3.8 Ga) [3], although several other authors reported ages ranging from the Imbrian (~3.3 Ga) to the Eratosthenian (~2.5 Ga) [e.g., 1,2,4]. [2,5] reported that all low shields are embayed by younger mare units, indicating that they formed during an older stage of volcanic activity. Mare basalts surrounding the Marius Hills exhibit absolute model ages of 1.2-3.7 Ga [6]. We used 36 LRO NAC images to perform crater size-frequency distribution (CSFD) measurements. The images were calibrated and map-projected with ISIS 3 and imported into ArcGIS. Within ArcGIS, we used CraterTools [7] to perform our CSFD measurements. The crater size-frequency distributions were then plotted with CraterStats [8], using the production and chronology functions of [9]. We conducted CSFD measurements for 50 Marius Hills low shields. Our count area sizes ranged from 1.06 x 101 to 8.75 x 101 km2; those for adjacent basalts varied between 6.17 x 100 and 8.01 x 101 km2. We determined absolute model ages (AMAs) of 1.03 to 3.65 Ga for the low shields and did not find a spatial correlation of ages versus their locations. CSFD measurements for 27 adjacent basalts show AMAs of 1.20-3.69 Ga. Of those basalts, 24 exhibit AMAs of 3-3.5 Ga; there is no correlation of AMAs and the geographic position of the

Mafic mantle sources indicated by the olivine-spinifex basalt-ferropicrite lavas in the accreted Permian oceanic LIP fragments and Miocene low-Ni basalt and adakite lavas in central Japan

NASA Astrophysics Data System (ADS)

Ishiwatari, A.; Ichiyama, Y.; Yamazaki, R.; Katsuragi, T.; Tsuchihashi, H.

2008-12-01

Melting of mafic (eclogitic) rocks in the peridotite mantle diapir may be important to generate a large quantity of magma in a short period of time as required for the LIP basaltic magmatism (e.g. Takahashi et al. 1998; EPSL, 162, 63-). Ferropicritic rocks also occur in some LIPs, and Ichiyama et al. (2006; Lithos, 89, 47-) propose a non-peridotitic, Ti- and Fe-rich eclogitic source (recycled oceanic ferrogabbro?) entrained in the peridotitic LIP mantle plume for the origin of ferropicritic rocks, that occur with olivine-spinifex basalt (Ichiyama et al., 2007; Island Arc, 16, 493-) in a Permian LIP fragment that was captured in the Jurassic Tamba accretionary complex in central Japan. Although Ti-poor ferrokomatiitic magma might form through high- degree melting of a primitive chondritic mantle (25wt% MgO and 25wt% Fe+FeO), Ti- and HFSE-rich ferropicritic and meimechitic magmas can not form in this way. On the other hand, Miocene volcanic rocks distributed along the Japan Sea coast of central Japan also represent a product of large-scale arc magmatism that happened coeval to the spreading of the Japan Sea floor. The chemical and isotopic signatures of the magmas are consistent with the secular change of tectonic setting from continental arc (22- 20 Ma) to island arc (15-11 Ma) (Shuto et al. 2006; Lithos, 86, 1-). Some adakites have already been found from these Miocene volcanic rocks by Shuto"fs group, and mafic rock melting in either subducting slab or lower arc crust has been proposed. We have recently found a wide distribution of low-Ni basalt from Fukui City. The low-Ni basalt contains olivine phenocrysts which are one order of magnitude poorer in Ni (less than 0.02 wt% NiO at Fo87) than those in normal basalt (more than 0.2 wt% NiO at Fo87). The rock is also poor in bulk-rock Ni, rich in K and Ti, and may have formed from an olivine-free pyroxenitic source. Close association of adakite and low-Ni basalt with normal tholeiitic basalt, calc-alkaline andesite

Dynamics of basaltic glass dissolution - Capturing microscopic effects in continuum scale models

NASA Astrophysics Data System (ADS)

Aradóttir, E. S. P.; Sigfússon, B.; Sonnenthal, E. L.; Björnsson, G.; Jónsson, H.

2013-11-01

The method of 'multiple interacting continua' (MINC) was applied to include microscopic rate-limiting processes in continuum scale reactive transport models of basaltic glass dissolution. The MINC method involves dividing the system up to ambient fluid and grains, using a specific surface area to describe the interface between the two. The various grains and regions within grains can then be described by dividing them into continua separated by dividing surfaces. Millions of grains can thus be considered within the method without the need to explicity discretizing them. Four continua were used for describing a dissolving basaltic glass grain; the first one describes the ambient fluid around the grain, while the second, third and fourth continuum refer to a diffusive leached layer, the dissolving part of the grain and the inert part of the grain, respectively. The model was validated using the TOUGHREACT simulator and data from column flow through experiments of basaltic glass dissolution at low, neutral and high pH values. Successful reactive transport simulations of the experiments and overall adequate agreement between measured and simulated values provides validation that the MINC approach can be applied for incorporating microscopic effects in continuum scale basaltic glass dissolution models. Equivalent models can be used when simulating dissolution and alteration of other minerals. The study provides an example of how numerical modeling and experimental work can be combined to enhance understanding of mechanisms associated with basaltic glass dissolution. Column outlet concentrations indicated basaltic glass to dissolve stoichiometrically at pH 3. Predictive simulations with the developed MINC model indicated significant precipitation of secondary minerals within the column at neutral and high pH, explaining observed non-stoichiometric outlet concentrations at these pH levels. Clay, zeolite and hydroxide precipitation was predicted to be most abundant within

Detection of reduced carbon in basalt using Raman spectroscopy: a signpost to habitat on Mars

NASA Astrophysics Data System (ADS)

Harris, L. V.; Hutchinson, I. B.; Parnell, J.; Ingley, R.; Edwards, H. G. M.

2013-09-01

In the search for evidence of the environmental history of the Martian surface, and the possibility of life at some stage in the planet's history, a key component is reduced carbon. Carbon is available to the surface environment through meteoritic infall [1] and erosion of abundant volcanic rocks which contain magmatic carbon [2][3], in addition to the possibility of some biogenic carbonaceous matter. However, reduced carbon has not yet been detected by a range of missions to Mars. Carbonate minerals, containing carbon in inorganic oxidized form, have been recorded [4], which together with carbon dioxide in the Martian atmosphere and magmatic carbon in Martian meteorites provide evidence for a carbon cycle on Mars [5][6]. The mobility of carbon on Mars is also evident in fracture-bound carbon in the Nakhla meteorite, derived from Martian basalt [7] [8]. Basalts are widespread on Mars, so are readily accessible for sampling and analysis. Basalt-hosted carbon could have a relationship to life in both a consequential or causative manner. Basalt could incorporate carbon from organic matter disseminated in sediments through which the basaltic magma passed. It is even possible that basalt could concentrate carbon scavenged from sediments into carbon-rich structures. Alternatively, basalt could act as a feedstock of carbon to provide biomass for colonizing microbes. In this way, the discovery of carbon in (Martian) basalt could be regarded as a signpost to habitat, i.e. the identification of carbon is a key aspect of the strategy for targeting where evidence of life should be sought. The ExoMars mission, currently intended to fly in 2018, includes a Raman spectroscopy instrument, whose targets for detection include reduced carbon. We report here the study of an analogue for the carbon-bearing Nakhla meteorite, representing nearsurface Martian crust, using Raman spectroscopy and other techniques to demonstrate the potential to detect the reduced carbon therein. The

Deep crustal structure beneath large igneous provinces and the petrologic evolution of flood basalts

NASA Astrophysics Data System (ADS)

Ridley, Victoria A.; Richards, Mark A.

2010-09-01

We present a review of seismological constraints on deep crustal structures underlying large igneous provinces (LIPs), largely from wide-angle seismic refraction surveys. The main purpose of this review is to ascertain whether this seismic evidence is consistent with, or contrary to, petrological models for the genesis of flood basalt lavas. Where high-quality data are available beneath continental flood basalt (CFB) provinces (Emeishan, Columbia River, Deccan, Siberia), high-velocity structures (Vp ˜ 6.9-7.5 km/sec) are typically found immediately overlying the Moho in layers of order ˜5-15 km thick. Oceanic plateau (OP) LIPs exhibit similar layers, with a conspicuous layer of very high crustal velocity (Vp ˜ 7.7 km/sec) beneath the enormous Ontong-Java plateau. These structures are similar to inferred ultramafic underplating structures seen beneath active hot spots such as Hawaii, the Marquesas, and La Reunion. Petrogenetic models for flood basalt volcanism based on hot plume melting beneath mature lithosphere suggest that these deep seismic structures may consist in large part of cumulate bodies of olivine and clinopyroxene which result from ponding and deep-crustal fractionation of ultramafic primary melts. Such fractionation is necessary to produce basalts with typical MgO contents of ˜6-8%, as observed for the vast bulk of observed flood basalts, from primary melts with MgO contents of order ˜15-18% (or greater) such as result from hot, deep melting beneath the lithosphere. The volumes of cumulate bodies and ultramafic intrusions in the lowermost crust, often described in the literature as "underplating," are comparable to those of the overlying basaltic formations, also consistent with petrological models. Further definition of the deep seismic structure beneath such prominent LIPs as the Ontong-Java Plateau could place better constraints on flood basalt petrogenesis by determining the relative volumes of ultramafic bodies and basaltic lavas, thereby

Deep Crustal Structure beneath Large Igneous Provinces and the Petrologic Evolution of Flood Basalts

NASA Astrophysics Data System (ADS)

Richards, M. A.; Ridley, V. A.

2010-12-01

We present a review of seismological constraints on deep crustal structures underlying large igneous provinces (LIPs), largely from wide-angle seismic refraction surveys. The main purpose of this review is to ascertain whether this seismic evidence is consistent with, or contrary to, petrological models for the genesis of flood basalt lavas. Where high-quality data are available beneath continental flood basalt (CFB) provinces (Emeishan, Columbia River, Deccan, Siberia), high-velocity structures (Vp ~6.9-7.5 km/sec) are typically found immediately overlying the Moho in layers of order ~5-15 km thick. Oceanic plateau (OP) LIPs exhibit similar layers, with a conspicuous layer of very high crustal velocity (Vp~7.7 km/sec) beneath the enormous Ontong-Java plateau. These structures are similar to inferred ultramafic underplating structures seen beneath active hotspots such as Hawaii, the Marquesas, and La Reunion. Petrogenetic models for flood basalt volcanism based on hot plume melting beneath mature lithosphere suggest that these deep seismic structures may consist in large part of cumulate bodies of olivine and clinopyroxene which result from ponding and deep-crustal fractionation of ultramafic primary melts. Such fractionation is necessary to produce basalts with typical MgO contents of ~6-8%, as observed for the vast bulk of observed flood basalts, from primary melts with MgO contents of order ~15-18% (or greater) such as result from hot, deep melting beneath the lithosphere. The volumes of cumulate bodies and ultramafic intrusions in the lowermost crust, often described in the literature as “underplating,” are comparable to those of the overlying basaltic formations, also consistent with petrological models. Further definition of the deep seismic structure beneath such prominent LIPs as the Ontong-Java Plateau could place better constraints on flood basalt petrogenesis by determining the relative volumes of ultramafic bodies and basaltic lavas, thereby better

Investigation of Zn2+ and Cd2+ Adsorption Performanceby Different Weathering Basalts

NASA Astrophysics Data System (ADS)

Xue, Q.; Shuo, Q.; Chen, H.

2016-12-01

Geological barriers play an important role in preventing pollution of groundwater. Basalts are common geological media; however, there have not been any studies that report the effect of basalt type on the metal ion adsorption performance. In this study, we explored the metal ion (Zn2+ and Cd2+) adsorption ability of two kinds of weathering basalts: the origin weathering basalt (WB) and the eluvial deposit (ED), both of which were derived from same basaltic formation. Characteristics of the sediments were examined by scanning electron microscopy (SEM), X-ray powder diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), Barrett-Joyner-Halenda (BJH) measurement and the rapid potentiometric titration (RPT) method. Batch experiments were performed to evaluate the Zn2+ and Cd2+ adsorption performance of WB and ED and how adsorption was affected by contact time, initial metal ion concentration, pH and ionic strength. Despite WB and ED having similar chemical compositions, WB exhibited better adsorption than ED likely due to the fact that WB was rougher and had more small-sized spherical structures and stronger electrostatic forces. The adsorption process fit the Freundlich isotherm model well. The adsorption efficiency decreased with a decrease of pH (from 4 to 2) and with increasing ionic strength. These results suggest that a geological barrier composed of WB media might be able to effectively sequester metallic contaminants to prevent them from reaching groundwater.

Palagonitic Mars: A Basalt Centric View of Surface Composition and Aqueous Alteration

NASA Technical Reports Server (NTRS)

Morris, R. V.; Graff, T. G.; Ming, D. W.; Bell, J. F., III; Le, L.; Mertzman, S. A.; Christensen, P. R.

2004-01-01

Palagonitic tephra from certain areas on Mauna Kea Volcano (Hawaii) are well-established spectral and magnetic analogues of high-albedo regions on Mars. By definition, palagonite is "a yellow or orange isotropic mineraloid formed by hydration and devitrification of basaltic glass." The yellow to orange pigment is nanometer-sized ferric oxide particles (np-Ox) dispersed throughout the hydrated basaltic glass matrix. The hydration state of the np-Ox particles and the matrix is not known, but the best Martian spectral analogues contain allophane-like materials and not crystalline phyllosilicates. Martian low-albedo regions are also characterized by a palagonite-like ferric absorption edge, but, unlike the highalbedo regions, they also show evidence for absorption by ferrous iron. Thermal emission spectra (TES) obtained by the Mars Global Surveyor Thermal Emission Spectrometer suggest that basaltic (surface Type 1) and andesitic (surface Type 2) volcanic compositions preferentially occur in southern (Syrtis Major) and northern (Acidalia) hemispheres, respectively. The absence of a ferric-bearing component in the modeling of TES spectra is in apparent conflict with VNIR spectra of Martian dark regions, as discussed above. However, the andesitic spectra have also been interpreted as oxidized basalt using phyllosilicates instead of high-SiO2 glass as endmembers in the spectral deconvolution of surface Type 2 TES spectra. We show here that laboratory VNIR and TES spectra of rinds on basaltic rocks are spectral endmembers that provide a consistent explanation for both VNIR and TES data of Martian dark regions.

Constraining the effects of permeability uncertainty for geologic CO2 sequestration in a basalt reservoir

NASA Astrophysics Data System (ADS)

Jayne, R., Jr.; Pollyea, R.

2016-12-01

Carbon capture and sequestration (CCS) in geologic reservoirs is one strategy for reducing anthropogenic CO2 emissions from large-scale point-source emitters. Recent developments at the CarbFix CCS pilot in Iceland have shown that basalt reservoirs are highly effective for permanent mineral trapping on the basis of CO2-water-rock interactions, which result in the formation of carbonates minerals. In order to advance our understanding of basalt sequestration in large igneous provinces, this research uses numerical simulation to evaluate the feasibility of industrial-scale CO2 injections in the Columbia River Basalt Group (CRBG). Although bulk reservoir properties are well constrained on the basis of field and laboratory testing from the Wallula Basalt Sequestration Pilot Project, there remains significant uncertainty in the spatial distribution of permeability at the scale of individual basalt flows. Geostatistical analysis of hydrologic data from 540 wells illustrates that CRBG reservoirs are reasonably modeled as layered heterogeneous systems on the basis of basalt flow morphology; however, the regional dataset is insufficient to constrain permeability variability at the scale of an individual basalt flow. As a result, permeability distribution for this modeling study is established by centering the lognormal permeability distribution in the regional dataset over the bulk permeability measured at Wallula site, which results in a spatially random permeability distribution within the target reservoir. In order to quantify the effects of this permeability uncertainty, CO2 injections are simulated within 50 equally probable synthetic reservoir domains. Each model domain comprises three-dimensional geometry with 530,000 grid blocks, and fracture-matrix interaction is simulated as interacting continua for the two low permeability layers (flow interiors) bounding the injection zone. Results from this research illustrate that permeability uncertainty at the scale of

182W in Modern Ocean Island Basalts

NASA Astrophysics Data System (ADS)

Mundl, A.; Touboul, M.; Walker, R. J.; Jackson, M. G.; Kurz, M. D.; Day, J. M.; Horan, M. F.; Helz, R. L.

2016-12-01

The short lived Hf-W isotopic system (182Hf → 182W, t½ = 8.9 Ma) can be used as an important tracer for very early geochemical processes in the Earth's mantle, as well as for possible detection of core-mantle interactions. To date, most high precision 182W/184W data have been obtained for ancient rocks, with most of these characterized by having positive 182W anomalies. Here we report data for modern ocean island basalts (OIB). Although most OIB examined to date show no 182W anomalies, some basalts from Hawaii and Samoa are characterized by well-resolved negative anomalies with µ182W values ranging to -16 (µ182W is the ppm deviation in 182W/184W of a sample relative to a terrestrial reference standard). Further, for both OIB systems the W isotopic data are negatively correlated with 3He/4He, whereby the samples with the lowest µ182W values are characterized by the highest 3He/4He. Thus, both OIB systems sample one or more primordial reservoirs. A primordial mantle domain characterized by negative 182W anomalies could have been created as a result of silicate crystal-liquid fractionation, such as by a magma ocean process, within the first 50 Ma of Solar System history. Tungsten is similarly incompatible to U and Th (from which 4He is generated), so it is difficult to envision a single-stage, early Earth process that would lead to the low Hf/W and high He/(U+Th) implied by the observed correlation. A second option is that the mantle sources of the 182W-depleted, 3He/4He-enriched basalts contain a core component. This is difficult to reconcile with the normal abundances of highly siderophile elements in the rocks. Positive 182W anomalies have been reported for high-3He/4He samples from the 60 Ma Baffin Bay picrites, so isotopically anomalous W is accessed by modern OIB and flood basalt systems from at least two high 3He/4He domains.

Assessing eruption column height in ancient flood basalt eruptions

NASA Astrophysics Data System (ADS)

Glaze, Lori S.; Self, Stephen; Schmidt, Anja; Hunter, Stephen J.

2017-01-01

A buoyant plume model is used to explore the ability of flood basalt eruptions to inject climate-relevant gases into the stratosphere. An example from the 1986 Izu-Oshima basaltic fissure eruption validates the model's ability to reproduce the observed maximum plume heights of 12-16 km above sea level, sustained above fire-fountains. The model predicts maximum plume heights of 13-17 km for source widths of between 4-16 m when 32% (by mass) of the erupted magma is fragmented and involved in the buoyant plume (effective volatile content of 6 wt%). Assuming that the Miocene-age Roza eruption (part of the Columbia River Basalt Group) sustained fire-fountains of similar height to Izu-Oshima (1.6 km above the vent), we show that the Roza eruption could have sustained buoyant ash and gas plumes that extended into the stratosphere at ∼ 45 ° N. Assuming 5 km long active fissure segments and 9000 Mt of SO2 released during explosive phases over a 10-15 year duration, the ∼ 180km of known Roza fissure length could have supported ∼36 explosive events/phases, each with a duration of 3-4 days. Each 5 km fissure segment could have emitted 62 Mt of SO2 per day into the stratosphere while actively fountaining, the equivalent of about three 1991 Mount Pinatubo eruptions per day. Each fissure segment could have had one to several vents, which subsequently produced lava without significant fountaining for a longer period within the decades-long eruption. Sensitivity of plume rise height to ancient atmospheric conditions is explored. Although eruptions in the Deccan Traps (∼ 66Ma) may have generated buoyant plumes that rose to altitudes in excess of 18 km, they may not have reached the stratosphere because the tropopause was substantially higher in the late Cretaceous. Our results indicate that some flood basalt eruptions, such as Roza, were capable of repeatedly injecting large masses of SO2 into the stratosphere. Thus sustained flood basalt eruptions could have influenced

Assessing Eruption Column Height in Ancient Flood Basalt Eruptions

NASA Technical Reports Server (NTRS)

Glaze, Lori S.; Self, Stephen; Schmidt, Anja; Hunter, Stephen J.

2015-01-01

A buoyant plume model is used to explore the ability of flood basalt eruptions to inject climate-relevant gases into the stratosphere. An example from the 1986 Izu-Oshima basaltic fissure eruption validates the model's ability to reproduce the observed maximum plume heights of 12-16 km above sea level, sustained above fire-fountains. The model predicts maximum plume heights of 13-17 km for source widths of between 4-16 m when 32% (by mass) of the erupted magma is fragmented and involved in the buoyant plume (effective volatile content of 6 wt%). Assuming that the Miocene-age Roza eruption (part of the Columbia River Basalt Group) sustained fire-fountains of similar height to Izu-Oshima (1.6 km above the vent), we show that the Roza eruption could have sustained buoyant ash and gas plumes that extended into the stratosphere at approximately 45 deg N. Assuming 5 km long active fissure segments and 9000 Mt of SO2 released during explosive phases over a 10-15 year duration, the approximately 180 km of known Roza fissure length could have supported approximately 36 explosive events/phases, each with a duration of 3-4 days. Each 5 km fissure segment could have emitted 62 Mt of SO2 per day into the stratosphere while actively fountaining, the equivalent of about three 1991 Mount Pinatubo eruptions per day. Each fissure segment could have had one to several vents, which subsequently produced lava without significant fountaining for a longer period within the decades-long eruption. Sensitivity of plume rise height to ancient atmospheric conditions is explored. Although eruptions in the Deccan Traps (approximately 66 Ma) may have generated buoyant plumes that rose to altitudes in excess of 18 km, they may not have reached the stratosphere because the tropopause was substantially higher in the late Cretaceous. Our results indicate that some flood basalt eruptions, such as Roza, were capable of repeatedly injecting large masses of SO2 into the stratosphere. Thus sustained

Volcanic diapirs in the Orange Mountain flood basalt: New Jersey, USA

NASA Astrophysics Data System (ADS)

Puffer, John H.; Laskowich, Chris

2012-09-01

Diapir-shaped structures, 4-30 m high, consisting of vesicular basalt have intruded into the interior of a 50-70 m-thick subaerial Orange Mountain Basalt flow exposed at several rock quarries in northern New Jersey. The basalt flowed onto a travertine encrusted mudflat saturated with alkali salts. We propose that pressurized alkali vapors trapped under the lava created a vesicular and viscous flow bottom layer about 10 m thick. Vesicle coalescence within this layer increased its buoyancy where it locally accumulated into diapirs and displaced overlying lava. Large bubbles within the diapirs expanded upon intrusion into hot flow interiors where they explosively escaped leaving lenses of breccia. Some early diapirs reached the base of the upper lava crust. These diapirs document vapor driven convection of large blobs of contaminated lava into the lava core of the Orange Mountain flow.

Tectonic affinities of the accreted basalts in southern Taiwan

NASA Astrophysics Data System (ADS)

Chen, Hsin-Yu; Yang, Huai-Jen; Liu, Yung-Hsin; Huang, Kuo-Fang; Takazawa, Eiichi

2018-06-01

Tectonic affinities of accreted basalts provide constraints on mass transport in convergent boundaries, improving our understandings on the evolution of regional geology. In this study, nineteen accreted basalts from the southernmost tip of Taiwan Island, which is on the convergent boundary between the Eurasian and Philippine Sea Plates, were analyzed for element concentrations as well as Sr, Nd, Hf, and Pb isotope ratios to investigate their tectonic affinities. All the samples contain > 3% LOI, reflecting post-magmatic alteration. LOI and Nb variation diagrams together with comparisons to oceanic basalt compositions indicated that the concentrations of most major elements and Rb, Sr, and Ba were modified by post-magmatic processes to varying extents, while P2O5, REE and HFSE remained immobile. Although some samples show Pb loss, most samples have Pb concentrations not affected by post-magmatic processes. Isotope ratios of Pb, Nd and Hf, generally reflect the mantle source characteristics. The εNd-εHf relationship and trace element abundance ratios indicated that the LREE-depleted samples were mostly scraped off the subducting South China Sea floor, reflecting the volumetric dominance of N-MORB on ocean floors. The overriding Philippine Sea Plate contributed both N-MORB and E-MORB to the accretionary prism. The tectonic affinities of the LREE-enriched samples, however, could not be unambiguously determined for the large geochemical variability of OIB from both subducting and overlying slabs. Based on our results, it is proposed that the tectonic affinity of the basalts in an accretionary prism can indicate the subduction polarity of the associated convergent boundary, providing a constraint for regional geology evolution.

The analyses of risk factors for COPD in the Li ethnic group in Hainan, People's Republic of China.

PubMed

Ding, Yipeng; Xu, Junxu; Yao, Jinjian; Chen, Yu; He, Ping; Ouyang, Yanhong; Niu, Huan; Tian, Zhongjie; Sun, Pei

2015-01-01

To study the risk factors for chronic obstructive pulmonary disease (COPD) in Li population in Hainan province, People's Republic of China. Li people above 40 years of age from Hainan were chosen by stratified random cluster sampling between 2012 and 2014. All participants were interviewed with a home-visiting questionnaire, and spirometry was performed on all eligible participants. Patients with airflow limitation (forced expiratory volume in 1 second [FEV1]/forced vital capacity [FVC] <0.70) were further examined by postbronchodilator spirometry, and those with a postbronchodilator FEV1/FVC <0.70 was diagnosed with COPD. The information of physical condition and history, smoking intensity, smoking duration, second-hand smoking, education, job category, monthly household income, working years, residential environment, primary fuel for cooking and heating (biomass fuel including wood, crop residues, dung, and charcoal, or modern fuel such as natural gas, liquefied petroleum gas, electricity, and solar energy), ventilated kitchen, heating methods, air pollution, recurrent respiratory infections, family history of respiratory diseases, cough incentives, and allergies of COPD and non-COPD subjects was analyzed by univariate and multivariate logistic regression models to identify correlated risk factors for COPD. Out of the 5,463 Li participants, a total of 277 COPD cases were identified by spirometry, and 307 healthy subjects were randomly selected as controls. Univariate logistic regression analyses showed that older people (65 years and above), low body mass index (BMI), biomass smoke, 11-20 and >20 cigarettes/day, smoking for 40 years or more, second-hand smoking, recurrent respiratory infections, and induced cough were risk factors for COPD, whereas high BMI, high education level, and presence of ventilated kitchen were protective factors. Subsequent multivariate logistic regression model further demonstrated that aging, low BMI, biomass smoke, >20 cigarettes

Scaling law deduced from impact-cratering experiments on basalt targets

NASA Astrophysics Data System (ADS)

Takagi, Y.; Hasegawa, S.; Suzuki, A.

2014-07-01

Since impact-cratering phenomena on planetary bodies were the key process which modified the surface topography and formed regolith layers, many experiments on non-cohesive materials (sand, glass beads) were performed. On the other hand, experiments on natural rocks were limited. Especially, experiments on basalt targets are rare, although basalt is the most common rocky material on planetary surfaces. The reason may be the difficulties of obtaining basalt samples suitable for cratering experiments. Recently, we obtained homogenous and crackless large basalt blocks. We performed systematic cratering experiments using the basalt targets. Experimental Procedure: Impact experiments were performed using a double stage light-gas (hydrogen) gun on the JAXA Sagamihara campus. Spherical projectiles of nylon, aluminum, stainless steel, and tungsten carbide were launched at velocities between 2400 and 6100 m/sec. The projectiles were 1.0 to 7.1 mm in diameter and 0.004 to 0.22 g in mass. The incidence angle was fixed at 90 degrees. The targets were rectangular blocks of Ukrainian basalt. The impact plane was a square with 20-cm sides. The thickness was 9 cm. Samples were cut out from a columnar block so that the impact plane might become perpendicular to the axis of the columnar joint. The mass was about 10.5 kg. The density was 2920 ± 10 kg/m^3 . Twenty eight shots were performed. Three-dimensional shapes of craters were measured by an X-Y stage with a laser displacement sensor (Keyence LK-H150). The interval between the measurement points was 200 micrometer. The volume, depth, and aperture area of the crater were calculated from the 3-D data using analytical software. Since the shapes of the formed craters are markedly asymmetrical, the diameter of the circle whose area is equal to the aperture area was taken as the crater diameter. Results: The diameter, depth, and the volume of the formed craters are normalized by the π parameters. Experimental conditions are also

Experimental constraints on the destabilization of basalt + calcite + anhydrite at high pressure-high temperature and implications for meteoroid impact modeling

NASA Astrophysics Data System (ADS)

Martin, A. M.; Righter, K.; Treiman, A. H.

2012-05-01

Calcite CaCO3 and anhydrite CaSO4 are two sedimentary components or alteration products of basalts on the Earth, Venus, and Mars. The fate of anhydrite-, calcite-bearing crust during a meteoroid impact must be addressed in order to evaluate: (1) the potential S- and C-gas release to the atmosphere, (2) the formation of S- and C-rich melts, and (3) the crystallization of S- and C-rich minerals which may be recognized by spectral analyses of planetary surfaces. We performed piston-cylinder experiments at 1 GPa, between 1200 and 1750 °C, on a mixture of 70 wt.% tholeiitic basalt + 15 wt.% anhydrite + 15 wt.% calcite. Up to ~ 1440 °C, an ultracalcic (CaO > 19.8 wt.%; CaO/Al2O3 > 1 wt.%) picrobasaltic (SiO2 ~ 39-43 wt.%; Na2O + K2O < 2 wt.%) melt containing up to 5.7 wt.% SO3 and up to 5.1 wt.% CO2 + H2O (calculated by difference) is present in equilibrium with fassaitic clinopyroxene, anhydrite, scapolite, chromian spinel and a gas composed mainly of CO and, occasionally, aliphatic thiols like CH3(CH2)3SH. Hydrogen was incorporated either by contact between the starting material and air or by diffusion through the capsule during the experiments. Above ~ 1440 °C, a CaO-rich (~ 35 wt.%) sulfate-carbonate (SC) melt which contains 41-47 wt.% SO3, 7-12 wt.% CO2 + H2O and a few percent of Na2O, forms in equilibrium with the picrobasaltic melt. This study shows that a meteoroid impact onto an anhydrite- and calcite-bearing basaltic crust is likely to release CO gas to the atmosphere, while S is trapped in solid or liquid phases. Under hydrous conditions, however, the S/C in the gas may increase. The importance of the temperature parameter on the impact phase relations is also demonstrated. In particular, SC melt may form by meteoroid impact, and flow rapidly on a planetary surface. Physical modeling must therefore be combined with high P-high T phase diagrams of complex assemblages similar to planetary lithologies in order to evaluate the effects of a meteoroid impact.

Geochemical constraints on the spatial distribution of recycled oceanic crust in the mantle source of late Cenozoic basalts, Vietnam

NASA Astrophysics Data System (ADS)

Hoang, Thi Hong Anh; Choi, Sung Hi; Yu, Yongjae; Pham, Trung Hieu; Nguyen, Kim Hoang; Ryu, Jong-Sik

2018-01-01

This study presents a comprehensive analysis of the major and trace element, mineral, and Sr, Nd, Pb and Mg isotopic compositions of late Cenozoic intraplate basaltic rocks from central and southern Vietnam. The Sr, Nd, and Pb isotopic compositions of these basalts define a tight linear array between Indian mid-ocean-ridge basalt (MORB)-like mantle and enriched mantle type 2 (EM2) components. These basaltic rocks contain low concentrations of CaO (6.4-9.7 wt%) and have high Fe/Mn ratios (> 60) and FeO/CaO-3MgO/SiO2 values (> 0.54), similar to partial melts derived from pyroxenite/eclogite sources. This similarity is also supported by the composition of olivine within these samples, which contains low concentration of Ca and high concentrations of Ni, and shows high Fe/Mn ratios. The basaltic rocks have elevated Dy/Yb ratios that fall within the range of melts derived from garnet lherzolite material, although their Yb contents are much higher than those of modeled melts derived from only garnet lherzolite material and instead plot near the modeled composition of eclogite-derived melts. The Vietnamese basaltic rocks have lighter δ26Mg values (- 0.38 ± 0.06‰) than is expected for the normal mantle (- 0.25 ± 0.07‰), and these values decrease with decreasing Hf/Hf* and Ti/Ti* ratios, indicating that these basalts were derived from a source containing carbonate material. On primitive mantle-normalized multi-element variation diagrams, the central Vietnamese basalts are characterized by positive Sr, Eu, and Ba anomalies. These basalts also plot within the pelagic sediment field in Pbsbnd Pb isotopic space. This suggests that the mantle source of the basalts contained both garnet peridotite and recycled oceanic crust. A systematic analysis of variations in geochemical composition in basalts from southern to central Vietnam indicates that the recycled oceanic crust (possibly the paleo-Pacific slab) source material contains varying proportions of gabbro, basalt, and

Comparison of mechanical and tribotechnical properties of UHMWPE reinforced with basalt fibers and particles

NASA Astrophysics Data System (ADS)

Panin, S. V.; Kornienko, L. A.; Alexenko, V. O.; Qitao, Huang; Ivanova, L. R.

2016-11-01

Mechanical and tribotechnical properties of UHMWPE composites reinforced with basalt fibers and particles under dry sliding friction and abrasion were investigated. It is shown that adding of the basalt particles provides higher wear resistance under the dry sliding friction while at abrasion filling by the basalt fibers is more efficient since the wear resistance of the reinforced UHMWPE composites is by 3.7 times higher in contrast with the neat polymer. Wear mechanisms of the polymeric UHMWPE composites under various types of wear are discussed.

Lunar cryptomaria: Physical characteristics, distribution, and implications for ancient volcanism

NASA Astrophysics Data System (ADS)

Whitten, Jennifer L.; Head, James W.

2015-02-01

Cryptomaria, lunar volcanic deposits obscured by crater and basin impact ejecta, can provide important information about the thermal and volcanic history of the Moon. The timing of cryptomare deposition has implications for the duration and flux of mare basalt volcanism. In addition, knowing the distribution of cryptomaria can provide information about mantle convection and lunar magma ocean solidification. Here we use multiple datasets (e.g., M3, LOLA, LROC, Diviner) to undertake a global analysis to identify the general characteristics (e.g., topography, surface roughness, rock abundance, albedo, etc.) of lunar light plains in order to better distinguish between ancient volcanic deposits (cryptomaria) and impact basin and crater ejecta deposits. We find 20 discrete regions of cryptomaria, covering approximately 2% of the Moon, which increase the total area covered by mare volcanism to 18% of the lunar surface. Comparisons of light plains deposits indicate that the two deposit types (volcanic and impact-produced) are best distinguished by mineralogic data. On the basis of cryptomaria locations, the distribution of mare volcanism does not appear to have changed in the time prior to its exposed mare basalt distribution. There are several hypotheses explaining the distribution of mare basalts, which include the influence of crustal thickness, mantle convection patterns, asymmetric distribution of source regions, KREEP distribution, and the influence of a proposed Procellarum impact basin. The paucity of farside mare basalts means that multiple factors, such as crustal thickness variations and mantle convection, are likely to play a role in mare basalt emplacement.

Project Hotspot: Linear accumulation rates of late Cenozoic basalt at Kimama, Idaho, and implications for crustal strain and subsidence rates of the central Snake River Plain

NASA Astrophysics Data System (ADS)

Rodgers, D. W.; Potter, K. E.; Shervais, J. W.; Champion, D. E.; Duncan, R. A.

2013-12-01

Project Hotspot's Kimama drill hole on the Snake River Plain, Idaho recovered a 1912 m thick section of basalt core that ranges in age from ~700 ka to at least 6.14 Ma, based on five 40Ar/39Ar analyses and twenty paleomagnetic age assignments. Fifty-four flow groups comprising 510 individual flows were defined, yielding an average recurrence interval of ~11,400 years between flows. Age-depth analysis indicate that, over thicknesses >150 m and age spans >500 k.y., accumulation rates were constant at 30 m/100 k.y. The existence and persistence of this linear accumulation rate for greater than 5 m.y. documents an external tectonic control on eruption dynamics. One conceptual model relates accumulation rates to horizontal crustal strain, such that far-field extension rate controls the periodicity of dikes that feed basalt flows. In this model, each of the 54 flow groups would have a deep-seated, relatively wide (1-10m) dike that branches upward into a network of narrow (10-100 cm) dikes feeding individual lava flows. Assuming an east-west lateral lava flow extent of up to 50 km, the Kimama data record a steady-state crustal strain rate of 10-9 to 10-10 y-1. This rate is comparable to modern, decadal strain rates measured with GPS in the adjacent Basin & Range province, but exceeds decadal strain rates of zero measured in the eastern Snake River Plain. Linear accumulation rates also provide insight into basalt subsidence history. In this model, the middle-upper crust subsides due to the added weight of lava flows, the added weight of mid-crustal sills/dikes, and thermal contraction in the wake of the Yellowstone hot spot. Isostatic compensation would occur in the (nearly) molten lower crust. Assuming constant surface elevation and a basalt density of 2.6 g/cm3, the lava flow weight would account for 87% of the burial through time, yielding a steady-state "tectonic" subsidence rate of 4 m/100 k.y. attributed to the driving forces of mid-crustal injection and/or thermal

Investigating the Origin of Th in Mare Basalts of the Western Procellarum Region

NASA Technical Reports Server (NTRS)

Flor, E. L.; Gillis, J. J.; Jolliff, B. L.; Lawrence, D. L.

2002-01-01

Clementine spectral reflectance and compositional data and Lunar Prospector gamma-ray data are used to map individual basalt flows in the western Procellarum and to investigate whether Th was inherent to the basalts or the result of surface contamination. Additional information is contained in the original extended abstract.

Does the presence of bacteria effect basaltic glass dissolution rates? 1: Dead Pseudomonas reactants

NASA Astrophysics Data System (ADS)

Stockmann, Gabrielle J.; Shirokova, Liudmila S.; Pokrovsky, Oleg S.; Oelkers, Eric H.; Benezeth, Pascale

2010-05-01

Basaltic glass and crystalline basalt formations in Iceland have been suggested for industrial CO2 storage due to their porous and permeable properties and high reactivity. Acid CO2-saturated waters in contact with basaltic glass will lead to rapid dissolution of the glass and release of divalent cations, (Ca2+, Mg2+, Fe2+) that can react to form stable carbonates and thereby trap the CO2. However, the basalt formations in Iceland not only contains glass and mineral assemblages, but also host microbiological communities that either by their presence or by active involvement in chemical reactions could affect the amount of basaltic glass being dissolved and CO2 being trapped. Samples of natural bacteria communities from the CO2 storage grounds in Iceland were collected, separated, and purified using agar plate technique and cultured under laboratory conditions in nutrient broth-rich media. Heterotrophic aerobic Gram-negative strain of Pseudomonas reactants was selected for a series of flow-through experiments aimed at evaluation of basaltic glass dissolution rate in the presense of increasing amounts of dead bacteria and their lysis products. The experiments were carried out using mixed-flow reactors at pH 4, 6, 8 and 10 at 25 °C. Each of the four reactors contained 1 gram of basaltic glass of the size fraction 45-125 μm. This glass was dissolved in ~ 0.01 M buffer solutions (acetate, MES, bicarbonate and carbonate+bicarbonate mixture) of the desired pH. All experiments ran 2 months, keeping the flowrate and temperature stable and only changing the concentration of dead bacteria in the inlet solutions (from 0 to 430 mg/L). Experiments were performed in sterile conditions, and bacterial growth was prevented by adding NaN3 to the inlet solutions. Routine culturing of bacteria on the agar plates confirmed the sterility of experiments. Samples of outlet solutions were analyzed for major cations and trace elements by ICP-MS. Results demonstrate a slight decrease in the

A LREE-depleted component in the Afar plume: Further evidence from Quaternary Djibouti basalts

NASA Astrophysics Data System (ADS)

Daoud, Mohamed A.; Maury, René C.; Barrat, Jean-Alix; Taylor, Rex N.; Le Gall, Bernard; Guillou, Hervé; Cotten, Joseph; Rolet, Joël

2010-02-01

Major, trace element and isotopic (Sr, Nd, Pb) data and unspiked K-Ar ages are presented for Quaternary (0.90-0.95 Ma old) basalts from the Hayyabley volcano, Djibouti. These basalts are LREE-depleted (La n/Sm n = 0.76-0.83), with 87Sr/ 86Sr ratios ranging from 0.70369 to 0.70376, and rather homogeneous 143Nd/ 144Nd ( ɛNd = + 5.9-+ 7.3) and Pb isotopic compositions ( 206Pb/ 204Pb = 18.47-18.55, 207Pb/ 204Pb = 15.52-15.57, 208Pb/ 204Pb = 38.62-38.77). They are very different from the underlying enriched Tadjoura Gulf basalts, and from the N-MORB erupted from the nascent oceanic ridges of the Red Sea and Gulf of Aden. Their compositions closely resemble those of (1) depleted Quaternary Manda Hararo basalts from the Afar depression in Ethiopia and (2) one Oligocene basalt from the Ethiopian Plateau trap series. Their trace element and Sr, Nd, Pb isotope systematics suggest the involvement of a discrete but minor LREE-depleted component, which is probably an intrinsic part of the Afar plume.

Basalt models for the Mars penetrator mission: Geology of the Amboy Lava Field, California

NASA Technical Reports Server (NTRS)

Greeley, R.; Bunch, T. E.

1976-01-01

Amboy lava field (San Bernardino County, California) is a Holocene basalt flow selected as a test site for potential Mars Penetrators. A discussion is presented of (1) the general relations of basalt flow features and textures to styles of eruptions on earth, (2) the types of basalt flows likely to be encountered on Mars and the rationale for selection of the Amboy lava field as a test site, (3) the general geology of the Amboy lava field, and (4) detailed descriptions of the target sites at Amboy lava field.

Geochemistry of Central Snake River Plain Basalts From Camas Prairie to Glenns Ferry, Southern Idaho

NASA Astrophysics Data System (ADS)

Vetter, S. K.; Johnston, S. A.; Shervais, J.; Hanan, B.

2006-12-01

The Snake River Plain (SRP) of southern Idaho represents the track of a hot-spot (mantle plume) which links voluminous flood basalts of the Miocene Columbia River province to Quaternary volcanic centers at Island Park and Yellowstone. However, much of the volcanism associated with this province either lies off the main volcanic trend or differs in age from the postulated plume passage. The Camas Prairie and the Mount Bennett Hills lie north of the Snake River-Yellowstone plume track, near the intersection of the eastern and western Snake River Plain trends. Young basalt flows cap highlands overlooking the Snake River near King Hill, but farther north in the Mount Bennett Hills and Camas Prairie these young lava flows are juxtaposed against older basalts along a series of WNW trending normal faults. These older basalt flows rest directly on rhyolite of the Mount Bennett Hills, making them the oldest basalts known in outcrop in this area. The older basalts in the Mount Bennett Hills include at least six major flows with a total thickness of 110 m. Although they have been strongly dissected by erosion, they still cover an outcrop area of 300 km2 . Eighty samples were collected as part of our petrologic survey of basaltic volcanism in the central Snake River Plain. These samples were studied petrographically and analyzed for their major elements, trace elements, and REE. The basalts consist of plagioclase and olivine microphenocrysts set in a groundmass of olivine, plagioclase, clinopyroxene, oxides and interstitial glass. The majority of samples have Mg# ranging from 50- 59. However there are samples that are more evolved as indicated by Mg# ranging from less than 50 to 29. The high Mg# samples have the following chemical ranges: TiO2 0.87 - 2.6 wt.%; FeO 9.95 - 13.7 wt.%; Nb 8 to 23 ppm; Zr 111 to 243 ppm; Ni 81 to 151 ppm; La 10.9 to 26.9 ppm. The more evolved samples have TiO2 1.4 3.93 wt.%; FeO 9.7 16.8 wt%; Nb 11 to 40 ppm; Zr 110 to 500 ppm; Ni 4 to 85 ppm; La

Mantle sources for Central Atlantic Magmatic Province basalts from Hf isotopes

NASA Astrophysics Data System (ADS)

Elkins, L. J.; Marzoli, A.; Bizimis, M.; Meyzen, C. M.; Callegaro, S.; Sorsen, N.; Lassiter, J. C.; Ernesto, M.

2017-12-01

The Central Atlantic Magmatic Province (CAMP) was one of the most voluminous LIP events in Earth history and likely triggered the end-Triassic mass extinction. The tectonic and mantle processes that produced such significant magmatic emplacement are thus of great interest. To further explore the origins of CAMP, we present new 176Hf/177Hf isotope data for a broad geographic sampling of CAMP dikes, sills, and basalt flows. We find that basaltic intrusions from the Carolinas in Eastern North America trend along a shallower slope than the terrestrial array on a diagram of 176Hf/177Hf vs. 143Nd/144Nd. This trend may reflect the presence of variable quantities of sediment-derived material in the mantle source region. This is consistent with previous suggestions that the asthenosphere beneath CAMP has been partially metasomatised by fluids derived from subducted sediments, as well as with isotopic trends observed in other LIP, such as Karoo [Jourdan et al., 2007, Jour. Petrology, doi:10.1093/petrology/egm010]. Distinct from the Carolina trend, we further observe that high-TiO2 basalts from Amazonia exhibit unusually radiogenic 176Hf/177Hf for a given 208Pb/206Pb ratio. The high-TiO­2 basalts, which trend towards EM1-type compositions, may be asthenospheric melts that have experienced the addition of melts from local subcontinental lithospheric mantle (SCLM). Similarly high-TiO2 CAMP rocks from Sierra Leone may likewise have incorporated enriched lithospheric melts of lamproite-like composition in the source region [Callegaro et al., JPet, accepted; GSA Abstract #302853, 2017]. Low-TiO2 basalts from the same region in Brazil and of similar age to the high-TiO2 basalts lack the observed radiogenic 176Hf/177Hf ratios. This suggests that the melt source region beneath Brazil was heterogeneous, containing variable material with relatively radiogenic 176Hf/177Hf ratios, perhaps due to the greater age of subcontinental lithosphere and the presence of garnet. It remains unclear

Characterization and Distribution of Lunar Mare Basalt Types Using Remote Sensing Techniques. Ph.D. Thesis

NASA Technical Reports Server (NTRS)

Pieters, C.

1977-01-01

The types of basal to be found on the moon were identified using reflectance spectra from a variety of lunar mare surfaces and craters as well as geochemical interpretations of laboratory measurements of reflectance from lunar, terrestrial, and meteoritic samples. Findings indicate that major basaltic units are not represented in lunar sample collections. The existence of late stage high titanium basalts is confirmed. All maria contain lateral variations of compositionally heterogenous basalts; some are vertically inhomogenous with distinctly different subsurface composition. Some basalt types are spectrally gradational, suggesting minor variations in composition. Mineral components of unsampled units can be defined if spectra are obtained with sufficient spectral coverage (.3 to 2.5 micron m) and spatial resolution (approximating .5 km).

Crust recycling induced compositional-temporal-spatial variations of Cenozoic basalts in the Trans-North China Orogen

NASA Astrophysics Data System (ADS)

Xu, Rong; Liu, Yongsheng; Wang, Xiaohong; Zong, Keqing; Hu, Zhaochu; Chen, Haihong; Zhou, Lian

2017-03-01

It has been advocated that the stagnant Pacific slab within the mantle transition zone played a critical role in the genesis of the Cenozoic basalts in the eastern part of the North China Craton (NCC); however, it is not clear whether this recycled oceanic crust contributed to the chemical makeup of the Cenozoic basalts in the Trans-North China Orogen (TNCO, the central zone of the NCC). Here, we show that Cenozoic basalts from the TNCO are featured by low CaO contents, high TiO2 and FeOT contents and high Fe/Mn and Zn/Fe ratios, indicating a mantle source of pyroxenite. Temporally, these basalts evolved from alkali basalts of Late Eocene-Oligocene age to coexisting alkali and tholeiitic basalts of Late Miocene-Quaternary age. Spatially, their isotopic and chemical compositions vary symmetrically from the center to both the north and the south sides along the TNCO, i.e., SiO2 contents and 87Sr/86Sr ratios increase, FeOT contents and 143Nd/144Nd, Sm/Yb and Ce/Pb ratios decrease. The estimated average melting pressure of the TNCO tholeiitic basalts ( 3 GPa) agrees well with the present lithosphere thickness beneath the north region of the TNCO ( 90-120 km). The temporal and spatial chemical variations of Cenozoic basalts in the TNCO suggest that the recycled oceanic crust in the mantle of the TNCO is mainly related to the southward subduction of the Paleo-Asian oceanic plate and the northward subduction of the Tethyan ocean plate. The westward subduction of Pacific slab may not have contributed much than previously thought.

Geochemistry and stratigraphic correlation of basalt lavas beneath the Idaho Chemical Processing Plant, Idaho National Engineering Laboratory

USGS Publications Warehouse

Reed, M.F.; Bartholomay, R.C.; Hughes, S.S.

1997-01-01

Thirty-nine samples of basaltic core were collected from wells 121 and 123, located approximately 1.8 km apart north and south of the Idaho Chemical Processing Plant at the Idaho National Engineering Laboratory. Samples were collected from depths ranging from 15 to 221 m below land surface for the purpose of establishing stratigraphic correlations between these two wells. Elemental analyses indicate that the basalts consist of three principal chemical types. Two of these types are each represented by a single basalt flow in each well. The third chemical type is represented by many basalt flows and includes a broad range of chemical compositions that is distinguished from the other two types. Basalt flows within the third type were identified by hierarchical K-cluster analysis of 14 representative elements: Fe, Ca, K, Na, Sc, Co, La, Ce, Sm, Eu, Yb, Hf, Ta, and Th. Cluster analyses indicate correlations of basalt flows between wells 121 and 123 at depths of approximately 38-40 m, 125-128 m, 131-137 m, 149-158 m, and 183-198 m. Probable correlations also are indicated for at least seven other depth intervals. Basalt flows in several depth intervals do not correlate on the basis of chemical compositions, thus reflecting possible flow margins in the sequence between the wells. Multi-element chemical data provide a useful method for determining stratigraphic correlations of basalt in the upper 1-2 km of the eastern Snake River Plain.

Experimental Parameters for Wax Modeling of the Deccan Traps Flood Basalt Province

NASA Astrophysics Data System (ADS)

Rader, E. L.; Vanderkluysen, L.; Clarke, A. B.

2015-12-01

The Deccan Traps consist of ~1,000,000 km3 of predominantly tholeiitic basaltic lava flows, which cover the western Indian subcontinent. Their eruption occurred over a ~1-3 million year period overlapping with the Cretaceous-Paleogene (K-Pg) boundary and, hence, has been implicated in one of the most significant extinction events in the history of the planet. The extent of environmental impacts caused by flood basalt eruptions is thought to be related, in part, to the amount, species, and timescales of volcanic gases released. Therefore, constraining the effusion rate of Deccan Traps lava flows is fundamental to understanding the K-Pg extinction event. Previous field and experimental work with polyethylene glycol (PEG) wax has shown that effusion rate is a primary factor controlling flow morphology. While sinuous flows and lava domes have been successfully recreated with PEG wax, the two most common morphologies seen in the Deccan Traps (compound and inflated sheet lobes) have not. We used heated PEG-400 wax injected into a tank of chilled water with a peristaltic pump to form experimental eruptions with high flow rate and low viscosity to replicate inflated flow lobes, and low flow rate with higher viscosity for compound flows. Unlike previous experiments, flow rate was varied during a single experiment to examine the effect on flow morphology. The Psi value is used as a scaling parameter to estimate effusion rates for compound and 'simple' inflated flows in the Deccan Traps. When combined with field work for volume estimates of the two flow types, these experiments will provide the best constraint on eruption rates to date.

Continental flood basalt weathering as a trigger for Neoproterozoic Snowball Earth

NASA Astrophysics Data System (ADS)

Cox, Grant M.; Halverson, Galen P.; Stevenson, Ross K.; Vokaty, Michelle; Poirier, André; Kunzmann, Marcus; Li, Zheng-Xiang; Denyszyn, Steven W.; Strauss, Justin V.; Macdonald, Francis A.

2016-07-01

Atmospheric CO2 levels and global climate are regulated on geological timescales by the silicate weathering feedback. However, this thermostat has failed multiple times in Earth's history, most spectacularly during the Cryogenian (c. 720-635 Ma) Snowball Earth episodes. The unique middle Neoproterozoic paleogeography of a rifting, low-latitude, supercontinent likely favored a globally cool climate due to the influence of the silicate weathering feedback and planetary albedo. Under these primed conditions, the emplacement and weathering of extensive continental flood basalt provinces may have provided the final trigger for runaway global glaciation. Weathering of continental flood basalts may have also contributed to the characteristically high carbon isotope ratios (δ13 C) of Neoproterozoic seawater due to their elevated P contents. In order to test these hypotheses, we have compiled new and previously published Neoproterozoic Nd isotope data from mudstones in northern Rodinia (North America, Australia, Svalbard, and South China) and Sr isotope data from carbonate rocks. The Nd isotope data are used to model the mafic detrital input into sedimentary basins in northern Rodinia. The results reveal a dominant contribution from continental flood basalt weathering during the ca. 130 m.y. preceding the onset of Cryogenian glaciation, followed by a precipitous decline afterwards. These data are mirrored by the Sr isotope record, which reflects the importance of chemical weathering of continental flood basalts on solute fluxes to the early-middle Neoproterozoic ocean, including a pulse of unradiogenic Sr input into the oceans just prior to the onset of Cyrogenian glaciation. Hence, our new data support the hypotheses that elevated rates of flood basalt weathering contributed to both the high average δ13 C of seawater in the Neoproterozoic and to the initiation of the first (Sturtian) Snowball Earth.

Chemical variation and fractionation of KREEP basalt magmas

NASA Technical Reports Server (NTRS)

Irving, A. J.

1977-01-01

The fact that 53 Apollo 15 igneous KREEP basalts show a range of 100 Mg/(Mg + Fe) from 73 to 35, and that there are systematic variations in K2O and trace element abundances with the Mg/(Mg + Fe) ratio, suggests that the KREEP basalts are a magma series generated by fractional crystallization processes. Experimental and chemical evidence indicate that this magma series results from low-pressure, possibly subvolcanic, fractional crystallization of a magnesian parental liquid (100 Mg/(Mg + Fe) equal to approximately 72) by removal of low-Ca pyroxene and plagioclase, with eventual production of liquids similar in composition to 15405 quartz-monozodiorites. One soil sample, SAO 465-11, corresponds to the postulated parental liquid, which might have been a direct partial melt of troctolitic materials in the deep lunar crust.

Is plagioclase removal responsible for the negative Eu anomaly in the source regions of mare basalts

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shearer, C.K.; Papike, J.J.

1989-12-01

The nearly ubiquitous presence of a negative Eu anomaly in the mare basalts has been suggested to indicate prior separation and flotation of plagioclase from the basalt source region during its crystallization from a lunar magma ocean (LMO). Are there any mare basalts derived from a mantle source which did not experience prior plagioclase separation Crystal chemical rationale for REE substitution in pyroxene suggests that the combination of REE size and charge, M2 site characteristics of pyroxene, fO{sub 2}, magma chemistry, and temperature may account for the negative Eu anomaly in the source region of some types of primitive, lowmore » TiO{sub 2} mare basalts. This origin for the negative Eu anomaly does not preclude the possibility of the LMO as many mare basalts still require prior plagioclase crystallization and separation and/or hybridization involving a KREEP component.« less

Physical structure and algae community of summer upwelling off eastern Hainan

NASA Astrophysics Data System (ADS)

Xu, H.; Liu, S.; Xie, Q.; Hong, B.; Long, T.

2017-12-01

The upwelling system is the most productive ecosystem along the continental shelf of the northern South China Sea Shelf. It brings nutrient from bottom to surface and blooms biotic community driven by summer monsoon. In this study, we present observed results of physical and biotic community structures during August, 2015 in the upwelling system along Hainan eastern coast, which is one the strongest upwelling systems in the northern South China Sea. By using hydrological data collected by CTD, we found a significant cold water tongue with high salinity which extended from offshore to 100 m isobaths. However, dissolved oxygen (DO) showed a sandwich structure in which high core of DO concentration appeared at the layer from 5 m to 30 m. It possibly was caused by the advection transport of high DO from adjacent area. Basically, this upwelling system was constrained at northern area of 18.8ºN in horizontal due to the weakening summer monsoon in August. In addition, we collected water sample at the upwelling area and measured algae categories and concentration by high performance liquid chromatography (HPLC). Results show the biotic community was dominated by five types of algae mainly, they were diatoms, dinoflagellates, green algae, prokaryotes and prochlorococcus. And different patterns of different algae were demonstrated. In the upwelling area, diatoms and prokaryotes show opposite structures, and more complex pattern for the rest three algae indicating an active biotic community in the upwelling system.

Alteration of submarine basaltic glass from the Ontong Java Plateau: A STXM and TEM study

NASA Astrophysics Data System (ADS)

Benzerara, K.; Menguy, N.; Banerjee, N. R.; Tyliszczak, Tolek; Brown, G. E.; Guyot, F.

2007-08-01

Frequent observations of tubular to vermicular microchannels in altered basalt glass have led to increasing appreciation of a possible significant role of microbes in the low-temperature alteration of seafloor basalt. We have examined such microchannel alteration features at the nanoscale in basalt glass shards from the Ontong Java Plateau using a combination of focused ion beam milling, transmission electron microscopy and scanning transmission X-ray microscopy. Three types of materials were found in ultrathin cross-sections cut through the microchannels by FIB milling: fresh basalt glass, amorphous Si-rich rims surrounding the microchannels, and palagonite within the microchannels. X-ray absorption spectroscopy at the C K-edge and Fe L 2,3-edges showed the presence of organic carbon in association with carbonates within the microchannels and partial oxidation of iron in palagonite compared with basalt glass. Although these observations alone cannot discriminate between a biotic or abiotic origin for the microchannels, they provide new information on their mineralogical and chemical composition and thus better constrain the physical and chemical conditions prevailing during the alteration process.

Numerical modeling of time-lapse monitoring of CO2 sequestration in a layered basalt reservoir

USGS Publications Warehouse

Khatiwada, M.; Van Wijk, K.; Clement, W.P.; Haney, M.

2008-01-01

As part of preparations in plans by The Big Sky Carbon Sequestration Partnership (BSCSP) to inject CO2 in layered basalt, we numerically investigate seismic methods as a noninvasive monitoring technique. Basalt seems to have geochemical advantages as a reservoir for CO2 storage (CO2 mineralizes quite rapidly while exposed to basalt), but poses a considerable challenge in term of seismic monitoring: strong scattering from the layering of the basalt complicates surface seismic imaging. We perform numerical tests using the Spectral Element Method (SEM) to identify possibilities and limitations of seismic monitoring of CO2 sequestration in a basalt reservoir. While surface seismic is unlikely to detect small physical changes in the reservoir due to the injection of CO2, the results from Vertical Seismic Profiling (VSP) simulations are encouraging. As a perturbation, we make a 5%; change in wave velocity, which produces significant changes in VSP images of pre-injection and post-injection conditions. Finally, we perform an analysis using Coda Wave Interferometry (CWI), to quantify these changes in the reservoir properties due to CO2 injection.

Evolution of the Craters of the Moon Lavas from primitive Snake River Plain basalts: inferences from plagioclase-melt thermobarometers and whole rock compositions

NASA Astrophysics Data System (ADS)

Vaid, N.; Putirka, K.; Kuntz, M.

2005-12-01

The volcanic rocks of the Craters of the Mon Lava field provide an ideal laboratory for testing models of magma transport and evolution. Their compositions, relative ages and volumes are well known, as are the fractionation processes leading to their evolution (Leeman, 1976). The COM is somewhat distinctive in the Snake River Plain (SRP) region, due to its evolved character, and an apparent compositional segregation from associated SRP basalts. Some have suggested that the high Fe liquids of the COM demand an origin separate from that of SRP basalts, possibly involving an Fe-enriched mantle, while others have suggested that the COM lavas may be derived by fractionation at moderate depths (30 km). In either case, there are important implications in regard to mantle composition and the nature and distribution of thermal energy. We use plagioclase-melt pairs and an analysis of whole rock compositions in attempt to test models of COM magmatic evolution. Plagioclase-melt thermobarometers provide rough estimates of crystallization depths, and show that COM and SRP lavas partially crystallized at similar depths of 14 +/- 6 km. However, plagioclase crystallization temperatures for SRP basalts (1400 +/- 25 K; Kings Bowl, Cerro Grande, North and South Robbers) exceed temperatures for COM lavas (1358 +/- 45 K) by 40 K. Our data also show that fractional crystallization (ol + plag) can explain the evolution of surrounding SRP basalt flows, and that the most evolved SRP basalts approach primitive COM lava compositions. The most primitive of COM magmas appear to be characterized by the appearance of apatite + magnetite as fractionating phases. Our results thus confirm the geochemical model of Leeman (1976) and the physical model of Kuntz (1992), with the added insight that SRP basalts are parental to the more evolved COM lavas, through low-pressure fractional crystallization in the upper crust. The principal differences between SRP and COM magmas appear to relate more to the

Is Ishtar Terra a thickened basaltic crust?

NASA Technical Reports Server (NTRS)

Arkani-Hamed, Jafar

1992-01-01

The mountain belts of Ishtar Terra and the surrounding tesserae are interpreted as compressional regions. The gravity and surface topography of western Ishtar Terra suggest a thick crust of 60-110 km that results from crustal thickening through tectonic processes. Underthrusting was proposed for the regions along Danu Montes and Itzpapalotl Tessera. Crustal thickening was suggested for the entire Ishtar Terra. In this study, three lithospheric models with total thicknesses of 40.75 and 120 km and initial crustal thicknesses of 3.9 and 18 km are examined. These models could be produced by partial melting and chemical differentiation in the upper mantle of a colder, an Earth-like, and a hotter Venus having temperatures of respectively 1300 C, 1400 C, and 1500 C at the base of their thermal boundary layers associated with mantle convection. The effects of basalt-granulite-eclogite transformation (BGET) on the surface topography of a thickening basaltic crust is investigated adopting the experimental phase diagram and density variations through the phase transformation.

The flexural stiffness and tension state of basalt filter

NASA Astrophysics Data System (ADS)

Khalmuradovich, Sattarov Laziz; Ahmedovich, Kurbanov Abdirahim

2017-03-01

In recent years, there is a growing demand in Uzbekistan for new, cheap and competitive products from local raw materials, the demand being directly connected with the expansion and development opportunities of the mining, metallurgical and processing industries. In such conditions, the need for providing a solution of the problems faced by these industries is a very urgent one and requires further comprehensive studies. One of these tasks includes assessment of the force parameters and bending stiffness of basalt fibre filters, aimed at further improving the efficiency of local basalt raw materials and aiding in the manufacture of new, long-lasting, reliable and high-quality products. In this case, we studied the interaction of basalt fibre filter with a gas or liquid medium, the deformed state of the fibres under the action force of the gas or liquid, and the filter recovery process after removal of the load, all of which occur during mechanical filtration. These tasks are of interest because during the mechanical filtration of a gas or liquid (hereinafter, mechanical filtration) from solids, all attention is paid to the quality of the filtering process. The filtering quality, as known, is determined by the degree of contamination in the liquid undergoing treatment, duration of separation of the pulp into solid and liquid phases during the decantation process of the mixture and the amount of gas/ liquid released into the atmosphere along with carbon monoxide and toxic impurities. At the same time, the state and behaviour of the filtering material remain as minor factors, the consideration of which can play a decisive role in the establishment of filter life and work capacity. Solutions to these problems are very urgent and allow one to create new technologies for the production of basalt filters based on force parameters and bending stiffness, wherein the purification occurs without the intervention of chemicals.

Basalt generation at the Apollo 12 site. Part 2: Source heterogeneity, multiple melts, and crustal contamination

NASA Technical Reports Server (NTRS)

Neal, Clive R.; Hacker, Matthew D.; Snyder, Gregory A.; Taylor, Lawrence A.; Liu, Yun-Gang; Schmitt, Roman A.

1994-01-01

The petrogenesis of Apollo 12 mare basalts has been examined with emphasis on trace-element ratios and abundances. Vitrophyric basalts were used as parental compositions for the modeling, and proportions of fractionating phases were determined using the MAGFOX prograqm of Longhi (1991). Crystal fractionation processes within crustal and sub-crustal magma chambers are evaluated as a function of pressure. Knowledge of the fractionating phases allows trace-element variations to be considered as either source related or as a product of post-magma-generation processes. For the ilmenite and olivine basalts, trace-element variations are inherited from the source, but the pigeonite basalt data have been interpreted with open-system evolution processes through crustal assimilation. Three groups of basalts have been examined: (1) Pigeonite basalts-produced by the assimilation of lunar crustal material by a parental melt (up to 3% assimilation and 10% crystal fractionation, with an 'r' value of 0.3). (2) Ilmenite basalts-produced by variable degrees of partial melting (4-8%) of a source of olivine, pigeonite, augite, and plagioclase, brought together by overturn of the Lunar Magma Ocean (LMO) cumulate pile. After generation, which did not exhaust any of the minerals in the source, these melts experienced closed-system crystal fractionation/accumulation. (3) Olivine basalts-produced by variable degrees of partial melting (5-10%) of a source of olivine, pigeonite, and augite. After generation, again without exhausting any of the minerals in the source, these melts evolved through crystal accumulation. The evolved liquid counterparts of these cumulates have not been sampled. The source compositions for the ilmenite and olivine basalts were calculated by assuming that the vitrophyric compositions were primary and the magmas were produced by non-modal batch melting. Although the magnitude is unclear, evaluation of these source regions indicates that both be composed of early- and

Microseismic monitoring of columnar jointed basalt fracture activity: a trial at the Baihetan Hydropower Station, China

NASA Astrophysics Data System (ADS)

Chen, Bing-Rui; Li, Qing-Peng; Feng, Xia-Ting; Xiao, Ya-Xun; Feng, Guang-Liang; Hu, Lian-Xing

2014-10-01

Severe stress release has occurred to the surrounding rocks of the typically columnar jointed basalt after excavation at the Baihetan Hydropower Station, Jinsha River, China, where cracking, collapse, and other types of failure may take place occasionally due to relaxation fracture. In order to understand the relaxation fracture characteristics of the columnar jointed basalt in the entire excavation process at the diversion tunnel of the Baihetan Hydropower Station, real-time microseismic monitoring tests were performed. First, the applicability of a geophone and accelerometer was analyzed in the columnar jointed basalt tunnel, and the results show that the accelerometer was more applicable to the cracking monitoring of the columnar jointed basalt. Next, the waveform characteristics of the microseismic signals were analyzed, and the microseismic signals were identified as follows: rock fracture signal, drilling signal, electrical signal, heavy vehicle passing signal, and blast signal. Then, the attenuation characteristics of the microseismic signals in the columnar jointed basalt tunnel were studied, as well as the types and characteristics of the columnar jointed basalt fracture. Finally, location analysis was conducted on the strong rock fracture events, in which four or more sensors were triggered, to obtain the temporal and spatial evolution characteristics and laws of the columnar jointed basalt relaxation fracture after excavation. The test results are not only of important reference value to the excavation and support of diversion tunnel at the Baihetan Hydropower Station, but also of great referential significance and value to the conduction of similar tests.

Ambient Effects on Basalt and Rhyolite Lavas under Venusian, Subaerial, and Subaqueous Conditions

NASA Technical Reports Server (NTRS)

Bridges, Nathan T.

1997-01-01

Both subaerial and subaqueous environments have been used as analog settings for Venus volcanism. To assess the merits of this, the effects of ambient conditions on the physical properties of lava on Venus, the seafloor, and land on Earth are evaluated. Rhyolites on Venus and on the surface of Earth solidify before basalts do because of their lower eruption temperatures. Rhyolite crust is thinner than basalt crust at times less than about an hour, especially on Venus. At later times, rhyolite crust is thicker because of its lower latent heat relative to basalt. The high pressure on the seafloor and Venus inhibits the exsolution of volatiles in lavas. Vesicularity and bulk density are proportional, so that lavas of the same composition should be more dense on the seafloor and less dense on land. Because viscosity depends partly upon the fraction of unvesiculated water in a melt, basalts with the same initial volatile abundance will be least viscous on the seafloor and most viscous on land. Assuming the same preeruptive H2O contents, molten rhyolites on Venus will have viscosities approx. 10% that of rhyolites on land. Despite lower expected viscosities, under-water flows are more buoyant and should have heights like subaerial and Venusian lavas of the same composition and extrusive history. In cases where the influence of crust is insignificant, a volume of rhyolite will have a higher aspect ratio than the same volume of basalt, no matter what the environment. If flow rheology is dominated by the presence of strong crust, aspect ratios differ little among environments or between compositions. These analyses support a rhyolitic interpretation for the composition of Venusian festooned flows and a basaltic interpretation for the composition of Venusian steep-sided domes. Although ambient effects are significant, extrusion rate and eruption history must also be considered to explain analogous volcanic landforms on Earth and Venus.

Movement of coliform bacteria and nutrients in ground water flowing through basalt and sand aquifers.

PubMed

Entry, J A; Farmer, N

2001-01-01

Large-scale deposition of animal manure can result in contamination of surface and ground water and in potential transfer of disease-causing enteric bacteria to animals or humans. We measured total coliform bacteria (TC), fecal coliform bacteria (FC), NO3, NH4, total P, and PO4 in ground water flowing from basalt and sand aquifers, in wells into basalt and sand aquifers, in irrigation water, and in river water. Samples were collected monthly for 1 yr. Total coliform and FC numbers were always higher in irrigation water than in ground water, indicating that soil and sediment filtered most of these bacteria before they entered the aquifers. Total coliform and FC numbers in ground water were generally higher in the faster flowing basalt aquifer than in the sand aquifer, indicating that the slower flow and finer grain size may filter more TC and FC bacteria from water. At least one coliform bacterium/100 mL of water was found in ground water from both basalt and sand aquifers, indicating that ground water pumped from these aquifers is not necessarily safe for human consumption according to the American Public Health Association and the USEPA. The NO3 concentrations were usually higher in water flowing from the sand aquifer than in water flowing from the basalt aquifer or in perched water tables in the basalt aquifer. The PO4 concentrations were usually higher in water flowing from the basalt aquifer than in water flowing from the sand aquifer. The main concern is fecal contamination of these aquifers and health consequences that may arise from human consumption.

Nitrogen isotope geochemistry of basaltic glasses: implications for mantle degassing and structure?

NASA Astrophysics Data System (ADS)

Exley, R. A.; Boyd, S. R.; Mattey, D. P.; Pillinger, C. T.

1987-01-01

The nitrogen isotope geochemistry of 15 basaltic glasses has been investigated using stepped heating and high sensitivity static vacuum mass spectrometry. At low temperature (< 600°C) the glasses release small amounts of nitrogen with δ 15N AIR, averaging -0.3‰, suggesting surficial adsorption of atmospheric nitrogen. At high temperature, usually with a maximum at 1000°C, indigenous nitrogen with a concentration ranging from 0.2 to 2.1 ppm is released. The δ 15N values of this high temperature release show a wide range from -4.5‰ to +15.5‰. There is no correlation between N ppm and δ 15N, and the samples apparently form 3 groups with distinctive δ 15N. Six MORB glasses from the Mid-Atlantic Ridge, East Pacific Rise and Juan de Fuca Ridge define a group with δ 15N = +7.5 ± 1.3‰. In contrast two Indian Ocean MORB glasses (Carlsberg Ridge and Gulf of Aden) gave negative δ 15N averaging -3.2‰. Glasses from Loihi Seamount have high δ 15N averaging +14.0 ± 1.0‰. Comparison of the δ 15N data with the mantle models derived from helium and argon isotope studies suggests that the wide range in δ 15N may reflect in part heterogeneities in the mantle related to its degassing history. It is possible, however, that magmatic degassing processes have also affected nitrogen isotopic compositions, and the data cannot yet be unambiguously interpreted in terms of source variations.

Pb, Sr, and Nd isotopes in seamount basalts from the Juan de Fuca Ridge and Kodiak-Bowie seamount chain, northeast Pacific

USGS Publications Warehouse

Hegner, E.; Tatsumoto, M.

1989-01-01

Pb, Sr, and Nd isotopic ratios and their parent/daughter element concentrations for 28 basalts from 10 hotspot and nonhotspot seamounts are reported. Nd and Sr isotopic compositions (143Nd/144Nd = 0.51325-0.51304; 87Sr/86Sr = 0.70237-0.70275) plot in the envelope for Juan de Fuca-Gorda ridge basalts with tholeiitic basalts showing more depleted sources and a better negative correlation than transitional to alkalic basalts. Pb isotopic ratios in tholeiitic and alkalic basalts overlap (206Pb/204Pb = 18.29-19.44) and display a trend toward more radiogenic Pb in alkalic basalts. The isotopic data for hotspot and nonhotspot basalts are indistinguishable and correlate broadly with rock composition, implying that they are controlled by partial melting. The isotopic variation in the seamount basalts is about 60% (Nd-Sr) to 100% (Pb) of that in East Pacific Rise basalts and is interpreted as a lower limit for the magnitude of mantle heterogeneity in the northeast Pacific. The data indicate absence of a chemically distinct plume component in the linear seamount chains and strongly suggest an origin from mid-ocean ridge basalt-like east Pacific mantle. -Authors

Green glass vitrophyre 78526 - An impact of very low-Ti mare basalt composition

NASA Technical Reports Server (NTRS)

Warner, R. D.; Taylor, G. J.; Kiel, K.; Planner, H. H.; Nehru, C. E.; Ma, M.-S.; Schmitt, R. A.

1978-01-01

Rake sample 78526 is an 8.77 g rock consisting primarily of vitrophyric pale green glass with subordinate mineral and lithic relics. Petrographic and compositional evidence leads to the following conclusions: (1) the bulk composition represents that of a mixture formed by impact melting of at least two different textural and compositional varieties of VLT mare basalt that are now present in the rock as lithic relics and a poorly defined low-Ti mare basalt component observed in thin section only in the form of isolated mineral relics; (2) the admixed VLT mare basalts had REE abundances lower than those found in other mare basalts (but probably higher than emerald green glass) and REE patterns showing significant enrichment of the heavy relative to light REE's, suggesting that they were derived by comparatively high degrees of partial melting of a clinopyroxene-rich source region; and (3) the impact melt supercooled to produce the vitrophyre, with rather sharply contrasting textural domains present in the vitrophyre resulting from differences in nucleation kinetics and degrees of supercooling in various portions of the sample.

A kinetic rate model for crystalline basalt dissolution at temperature and pressure conditions relevant for geologic CO2 sequestration

NASA Astrophysics Data System (ADS)

Pollyea, R.; Rimstidt, J. D.

2016-12-01

Geologic carbon sequestration in terrestrial basalt reservoirs is predicated on permanent CO2 trapping through CO2-water-rock dissolution reactions followed by carbonate precipitation. Bench-scale experiments have shown these reaction paths to be rapid, occurring on a timescale 100 - 102 years. Moreover, recent results from the CarbFix basalt sequestration pilot project in Iceland demonstrate >95% CO2 isolation two years after a small-scale injection. In order to assess the viability of basalt sequestration worldwide (e.g., Deccan Traps, Columbia Plateau, etc.), flexible simulation tools are required that distill the dissolution reactions into a user-friendly format that is readily transmissible to existing reactive transport numerical simulators. In the present research, we combine experimental results extant in the literature for Icelandic basalt to develop kinetic rate models describing the pH-dependent dissolution of (1) basaltic glass and (2) an aggregate mineral assemblage for crystalline basalt comprising olivine, pyroxene, and plagioclase phases. In order to utilize these kinetic rate models with numerical simulation, a thermodynamic solubility model for each phase is developed for use with the reactive transport simulation code, TOUGHREACT. We use reactive transport simulation in a simple 1-D reactor to compare dissolution of the aggregate crystalline basalt phase with the traditional formulation comprising individual mineral phases for the crystalline basalt. Simulation results are in general agreement, illustrating the efficacy of this simplified approach for modeling basalt dissolution at temperature and pressure conditions typical of geologic CO2 reservoirs. Moreover, this approach may be of value to investigators seeking dissolution models for crystalline basalt in other mafic provinces.

Brittle strength of basaltic rock masses with applications to Venus

NASA Astrophysics Data System (ADS)

Schultz, R. A.

1993-06-01

Spacecraft images of surfaces with known or suspected basaltic composition on Venus (as well as on moon and Mars) indicate that these rocks have been deformed in the brittle regime to form faults and perhaps joints, in addition to folding and more distributed types of deformation. This paper presents results of detailed examinations and interpretations of Venus surface materials which show that the strengths of basaltic rocks on planetary surfaces and in the shallow subsurface are significantly different from strength values commonly used in tectonic modeling studies which assume properties of either intact rock samples or single planar shear surface.

Correlation between compressive strength and ultrasonic pulse velocity of high strength concrete incorporating chopped basalt fibre

NASA Astrophysics Data System (ADS)

Shafiq, Nasir; Fadhilnuruddin, Muhd; Elshekh, Ali Elheber Ahmed; Fathi, Ahmed

2015-07-01

Ultrasonic pulse velocity (UPV), is considered as the most important test for non-destructive techniques that are used to evaluate the mechanical characteristics of high strength concrete (HSC). The relationship between the compressive strength of HSC containing chopped basalt fibre stands (CBSF) and UPV was investigated. The concrete specimens were prepared using a different ratio of CBSF as internal strengthening materials. The compressive strength measurements were conducted at the sample ages of 3, 7, 28, 56 and 90 days; whilst, the ultrasonic pulse velocity was measured at 28 days. The result of HSC's compressive strength with the chopped basalt fibre did not show any improvement; instead, it was decreased. The UPV of the chopped basalt fibre reinforced concrete has been found to be less than that of the control mix for each addition ratio of the basalt fibre. A relationship plot is gained between the cube compressive strength for HSC and UPV with various amounts of chopped basalt fibres.

The consanguinity of the oldest Apollo 11 mare basalts

NASA Technical Reports Server (NTRS)

Gamble, R. P.; Coish, R. A.; Taylor, L. A.

1978-01-01

The textural, mineralogical, and chemical relationships between three of the oldest dates lunar mare basalt samples returned by Apollo 11 (10003, 10029 and 10062) were investigated. Very strong resemblances were noted between the modal minerologies of 10003 and 10029. Significantly more modal olivine and cristobalite was observed in 10062 than in the other basalt samples. A detailed examination of mineral-chemical relationships among the samples revealed similarities between 10003 and 10062 and differences between these two rocks and 10029, the most significant of which is the presence of akaganeite in 10029, implying that lawrencite was present in the pristine sample of 10029 but not in 10003 and 10062. Results of a Wright-Doherty mixing program used to test various fractional crystallization schemes show that 10062 can be derived from a liquid with the composition of either 10003 or 10029 by removing 2-5% ilmenite and 5% olivine. By removing about 6% plagioclase, 10003 can be derived from a liquid with the bulk composition of 10062. It is concluded that 10003 and 10029 may have come from different basaltic flows, whereas it is possible that 10003 and 10062 were derived from the same parental magma by near-surface fractionation of olivine plus ilmenite or of plagioclase plus or minus olivine.

Zircon evidence for incorporation of terrigenous sediments into the magma source of continental basalts.

PubMed

Xu, Zheng; Zheng, Yong-Fei; Zhao, Zi-Fu

2018-01-09

Crustal components may be incorporated into continental basalts by either shallow contamination or deep mixing. While the former proceeds at crustal depths with common preservation of refractory minerals, the latter occurs at mantle depths with rare survival of relict minerals. Discrimination between the two mechanisms has great bearing to subcontinental mantle geochemistry. Here we report the occurrence of relict zircons in Cenozoic continental basalts from eastern China. A combined study of zircon U-Pb ages and geochemistry indicates that detrital zircons were carried by terrigenous sediments into a subcontinental subduction zone, where the zircon were transferred by fluids into the magma sources of continental basalts. The basalts were sampled from three petrotectonic units with distinct differences in their magmatic and metamorphic ages, making the crustal contamination discernible. The terrigenous sediments were carried by the subducting oceanic crust into the asthenospheric mantle, producing both soluble and insoluble materials at the slab-mantle interface. These materials were served as metasomatic agents to react with the overlying mantle wedge peridotite, generating a kind of ultramafic metasomatites that contain the relict zircons. Therefore, the occurrence of relict zircons in continental basalts indicates that this refractory mineral can survive extreme temperature-pressure conditions in the asthenospheric mantle.

Thermal control of low-pressure fractionation processes. [in basaltic magma solidification

NASA Technical Reports Server (NTRS)

Usselman, T. M.; Hodge, D. S.

1978-01-01

Thermal models detailing the solidification paths for shallow basaltic magma chambers (both open and closed systems) were calculated using finite-difference techniques. The total solidification time for closed chambers are comparable to previously published calculations; however, the temperature-time paths are not. These paths are dependent on the phase relations and the crystallinity of the system, because both affect the manner in which the latent heat of crystallization is distributed. In open systems, where a chamber would be periodically replenished with additional parental liquid, calculations indicate that the possibility is strong that a steady-state temperature interval is achieved near a major phase boundary. In these cases it is straightforward to analyze fractionation models of the basaltic liquid evolution and their corresponding cumulate sequences. This steady thermal fractionating state can be invoked to explain large amounts of erupted basalts of similar composition over long time periods from the same volcanic center and some rhythmically layered basic cumulate sequences.

Relationships among multiple trace elements in coastal Casuarina equisetifolia ecosystems on Hainan Island, South China.

PubMed

Liu, Qiang; Bi, Hua; Hung, Lan; Peng, Shaolin; Sheng, Chengde

2006-01-01

Forty-six trace elements in coastal Casuarina equisetifolia plant-soil systems at nine sampling sites on Hainan Island were analyzed using ICP-MS. The relationships among the trace elements of the same group or the same periodicity of the Periodic Table in the plants and soils were complex and no consistent patterns were found. More combinations of elements occurred with high positive correlation coefficients within the same periodicity than within the same group of the Periodic Table, and there were more high positive correlations in soils than in plants. However, there were many element combinations in Block d (transition elements) with high positive correlation coefficients in plants. Markedly high positive correlation coefficients between individual rare earth elements and Y and among Zr, Nb, Cd existed in both plants and soils. The dendrograms obtained by cluster analysis show that rare earth elements had very similar occurrence and distribution in both soils and plants. Thus, they behaved as a coherent group of elements both geochemically and biogeochemically. The transition elements were more coherent in plants than in soils.

Two new basaltic objects in the Outer Main Belt

NASA Astrophysics Data System (ADS)

Duffard, R.; Roig, F.; Gil-Hutton, R.; Moskovitz, N. A.

2007-08-01

The existence of basalt on the surface of asteroids provides information about their thermal history that is likely related to their formation and collisional evolution. Basaltic materials on the surface of an asteroid are indicators of past partial melting, a phenomenon that occurs due to the complicated interplay of heating and cooling processes within the interior of rocky bodies. Until recently, most of the known basaltic asteroids, taxonomically classified as V-type, were members of the Vesta dynamical family. Currently, several V-type asteroids are know to reside outside the Vesta family (e.g. [3][8]), and several NEAs with basaltic mineralogical surface composition have been recognized (e.g. [5] [1][6]). The asteroid (1459) Magnya, a basaltic object in the outer asteroid belt [10], is sufficiently distant from the Vesta family so that its probability of origin from this family is very low [11]. [12] presented the possibility of searching yet unknown V-type asteroids using photometric data from the Sloan Digital Sky Survey (SDSS). A sub-product of this survey is the Moving Objects Catalog (MOC), which in its third release provides five band photometry for 43424 asteroids [7][9]. [12] introduced a systematic method to identify possible candidate V-type asteroids from the SDSS-MOC, applying the Principal Components Analysis to the data. They found 263 V-type candidates that are not members of the Vesta dynamical family. The most interesting result is the presence of 8 V-type candidates in the middle/outer asteroid belt, i.e. with a > 2.5 AU: (7472), (10537), (21238), (40521), (44496), (55613), (66905) and (105041). These asteroids are quite isolated in proper elements space and do not belong to any of the major dynamical families. They are not close in proper elements space to (1459) Magnya either. In a recent study, [2] analyzed the spectra of (21238) in the near infrared (NIR) and confirmed its basaltic nature. In this work we present low resolution spectra

Genetic interpretation of lead-isotopic data from the Columbia River basalt group, Oregon, Washington, and Idaho.

USGS Publications Warehouse

Church, S.E.

1985-01-01

Lead-isotopic data for the high-alumina olivine plateau basalts and most of the Colombia River basalt group plot within the Cascade Range mixing array. The data for several of the formations form small, tight clusters and the Nd and Sr isotopic data show discrete variation between these basalt groups. The observed isotopic and trace-element data from most of the Columbia River basalt group can be accounted for by a model which calls for partial melting of the convecting oceanic-type mantle and contamination by fluids derived from continental sediments which were subducted along the trench. These sediments were transported in the low-velocity zone at least 400 km behind the active arc into a back-arc environment represented by the Columbia Plateau province. With time, the zone of melting moved up, resulting in the formation of the Saddle Mt basalt by partial melting of a 2600 m.y.-old sub-continental lithosphere characterized by high Th/U, Th/Pb, Rb/Sr and Nd/Sm ratios and LREE enrichment. Partial melting of old sub-continental lithosphere beneath the continental crust may be an important process in the formation of continental tholeiite flood basalt sequences world-wide. -L.di H.

Evidence for pressure-release melting beneath magmatic arcs from basalt at Galunggung, Indonesia

USGS Publications Warehouse

Sisson, T.W.; Bronto, S.

1998-01-01

The melting of peridotite in the mantle wedge above subduction zones is generally believed to involve hydrous fluids derived from the subducting slab. But if mantle peridotite is upwelling within the wedge, melting due to pressure release could also contribute to magma production. Here we present measurements of the volatile content of primitive magmas from Galunggung volcano in the Indonesian are which indicate that these magmas were derived from the pressure-release melting of hot mantle peridotite. The samples that we have analysed consist of mafic glass inclusions in high-magnesium basalts. The inclusions contain uniformly low H2O concentrations (0.21-0.38 wt%), yet relatively high levels of CO2 (up to 750 p.p.m.) indicating that the low H2O concentrations are primary and not due to degassing of the magma. Results from previous anhydrous melting experiments on a chemically similar Aleutian basalts indicate that the Galunggung high-magnesium basalts were last in equilibrium with peridotite at ~1,320 ??C and 1.2 GPa. These high temperatures at shallow sub-crustal levels (about 300-600 ??C hotter than predicted by geodynamic models), combined with the production of nearly H2O- free basaltic melts, provide strong evidence that pressure-release melting due to upwelling in the sub-are mantle has taken place. Regional low- potassium and low-H2O (ref. 5) basalts found in the Cascade are indicate that such upwelling-induced melting can be widespread.

Surface chemistry associated with the cooling and subaerial weathering of recent basalt flows

USGS Publications Warehouse

White, A.F.; Hochella, M.F.

1992-01-01

The surface chemistry of fresh and weathered historical basalt flows was characterized using surface-sensitive X-ray photoelectron spectroscopy (XPS). Surfaces of unweathered 1987-1990 flows from the Kilauea Volcano, Hawaii, exhibited variable enrichment in Al, Mg, Ca, and F due to the formation of refractory fluoride compounds and pronounced depletion in Si and Fe from the volatilization of SiF4 and FeF3 during cooling. These reactions, as predicted from shifts in thermodynamic equilibrium with temperature, are induced by diffusion of HF from the flow interiors to the cooling surface. The lack of Si loss and solid fluoride formation for recent basalts from the Krafla Volcano, Iceland, suggest HF degassing at higher temperatures. Subsequent short-term subaerial weathering reactions are strongly influenced by the initial surface composition of the flow and therefore its cooling history. Successive samples collected from the 1987 Kilauea flow demonstrated that the fluoridated flow surfaces leached to a predominantly SiO2 composition by natural weathering within one year. These chemically depleted surfaces were also observed on Hawaiian basalt flows dating back to 1801 AD. Solubility and kinetic models, based on thermodynamic and kinetic data for crystalline AlF3, MgF2, and CaF2, support observed elemental depletion rates due to chemical weathering. Additional loss of alkalis from the Hawaiian basalt occurs from incongruent dissolution of the basalt glass substrate during weathering. ?? 1992.

New absolute paleointensity determinations for the Permian-Triassic boundary from the Kuznetsk Trap Basalts.

NASA Astrophysics Data System (ADS)

Kulakov, E.; Metelkin, D. V.; Kazansky, A.

2015-12-01

We report the results of a pilot absolute paleointensity study of the ~250 Ma basalts of Kuznetsk traps (Kuznetsk Basin, Altai-Sayan folded area). Studied samples are characterized by a reversed polarity of natural remanent magnetization that corresponds to the lower part of Siberian Trap basalts sequence. Geochemical similarity of Kuznets basalts with those from Norilsk region supports this interpretation. Primary origin of thermal remanence in our sample is confirmed by a positive backed contact test. Rock magnetic analyses indicate that the ChRM is carried by single-domain titanomagnetite. The Coe-version of the Thellier-Therllier double-heating method was utilized for the paleointensity determinations. In contrast to the previous studies of the Permian-Triassic Siberian trap basalts, our data indicate that by the P-T boundary the paleofield intensity was relatively high and comparable with geomagnetic field strength for the last 10 millions of years. New results question the duration of the "Mesozoic dipole-low".

Effects of nutrition level of concentrate-based diets on growth performance and carcass characteristics of Hainan black goats.

PubMed

Wang, Dingfa; Zhou, Luli; Zhou, Hanlin; Hou, Guanyu; Li, Mao; Shi, Liguang; Huang, Xianzhou; Guan, Song

2014-06-01

This study assessed the effects of different nutrition levels of diets on growth performance and carcass characteristics of Hainan black goat. Twenty-four goats were divided into six diet treatments, which consisted of two levels of crude protein (CP; 15 and 17 %) and three levels of digestive energy (DE; 11.72, 12.55, and 13.39 MJ/kg). The results revealed that 17 % CP significantly (P < 0.05) increased ADG and improved FCR compared with 15 % CP. Therefore, the CP levels of diet affected growth performance. CP and DE levels in the diet had no significant effects (P > 0.05) on carcass characteristics of the goats. The mRNA expression levels of insulin-like growth factor 1 in muscle tissues increased with increasing CP and DE levels (P < 0.05).

Characterization and petrologic interpretation of olivine-rich basalts at Gusev Crater, Mars

USGS Publications Warehouse

McSween, H.Y.; Wyatt, M.B.; Gellert, Ralf; Bell, J.F.; Morris, R.V.; Herkenhoff, K. E.; Crumpler, L.S.; Milam, K.A.; Stockstill, K.R.; Tornabene, L.L.; Arvidson, R. E.; Bartlett, P.; Blaney, D.; Cabrol, N.A.; Christensen, P.R.; Clark, B. C.; Crisp, J.A.; Des Marais, D.J.; Economou, T.; Farmer, J.D.; Farrand, W.; Ghosh, A.; Golombek, M.; Gorevan, S.; Greeley, R.; Hamilton, V.E.; Johnson, J. R.; Joliff, B.L.; Klingelhofer, G.; Knudson, A.T.; McLennan, S.; Ming, D.; Moersch, J.E.; Rieder, R.; Ruff, S.W.; Schrorder, C.; de Souza, P.A.; Squyres, S. W.; Wanke, H.; Wang, A.; Yen, A.; Zipfel, J.

2006-01-01

Rocks on the floor of Gusev crater are basalts of uniform composition and mineralogy. Olivine, the only mineral to have been identified or inferred from data by all instruments on the Spirit rover, is especially abundant in these rocks. These picritic basalts are similar in many respects to certain Martian meteorites (olivine-phyric shergottites). The olivine megacrysts in both have intermediate compositions, with modal abundances ranging up to 20-30%. Associated minerals in both include low-calcium and high-calcium pyroxenes, plagioclase of intermediate composition, iron-titanium-chromium oxides, and phosphate. These rocks also share minor element trends, reflected in their nickel-magnesium and chromium-magnesium ratios. Gusev basalts and shergottites appear to have formed from primitive magmas produced by melting an undepleted mantle at depth and erupted without significant fractionation. However, apparent differences between Gusev rocks and shergottites in their ages, plagioclase abundances, and volatile contents preclude direct correlation. Orbital determinations of global olivine distribution and compositions by thermal emission spectroscopy suggest that olivine-rich rocks may be widespread. Because weathering under acidic conditions preferentially attacks olivine and disguises such rocks beneath alteration rinds, picritic basalts formed from primitive magmas may even be a common component of the Martian crust formed during ancient and recent times. Copyright 2006 by the American Geophysical Union.

A unique basaltic micrometeorite expands the inventory of solar system planetary crusts

PubMed Central

Gounelle, Matthieu; Chaussidon, Marc; Morbidelli, Alessandro; Barrat, Jean-Alix; Engrand, Cécile; Zolensky, Michael E.; McKeegan, Kevin D.

2009-01-01

Micrometeorites with diameter ≈100–200 μm dominate the flux of extraterrestrial matter on Earth. The vast majority of micrometeorites are chemically, mineralogically, and isotopically related to carbonaceous chondrites, which amount to only 2.5% of meteorite falls. Here, we report the discovery of the first basaltic micrometeorite (MM40). This micrometeorite is unlike any other basalt known in the solar system as revealed by isotopic data, mineral chemistry, and trace element abundances. The discovery of a new basaltic asteroidal surface expands the solar system inventory of planetary crusts and underlines the importance of micrometeorites for sampling the asteroids' surfaces in a way complementary to meteorites, mainly because they do not suffer dynamical biases as meteorites do. The parent asteroid of MM40 has undergone extensive metamorphism, which ended no earlier than 7.9 Myr after solar system formation. Numerical simulations of dust transport dynamics suggest that MM40 might originate from one of the recently discovered basaltic asteroids that are not members of the Vesta family. The ability to retrieve such a wealth of information from this tiny (a few micrograms) sample is auspicious some years before the launch of a Mars sample return mission. PMID:19366660

Characterization and Petrologic Interpretation of Olivine-Rich Basalts at Gusev Crater, Mars

NASA Technical Reports Server (NTRS)

McSween, H. Y.; Wyatt, M. B.; Gellert, R.; Bell, J. F., III; Morris, R. V.; Herkenhoff, K. E.; Crumpler, L. S.; Milam, K. A.; Stockstill, K. R.; Tornabene, L. L.;

A study on the crushing behavior of basalt fiber reinforced composite structures

NASA Astrophysics Data System (ADS)

Pandian, A.; Veerasimman, A. P.; Vairavan, M.; Francisco, C.; Sultan, M. T. H.

2016-10-01

The crushing behavior and energy absorption capacity of basalt fiber reinforced hollow square structure composites are studied under axial compression. Using the hand layup technique, basalt fiber reinforced composites were fabricated using general purpose (GP) polyester resin with the help of wooden square shaped mould of varying height (100 mm, 150 mm and 200 mm). For comparison, similar specimens of glass fiber reinforced polymer composites were also fabricated and tested. Axial compression load is applied over the top end of the specimen with cross head speed as 2 mm/min using Universal Testing Machine (UTM). From the experimental results, the load-deformation characteristics of both glass fiber and basalt fiber composites were investigated. Crashworthiness and mode of collapse for the composites were determined from load-deformation curve, and they were then compared to each other in terms of their crushing behaviors.

Influence of length-to-diameter ratio on shrinkage of basalt fiber concrete

NASA Astrophysics Data System (ADS)

Ruijie, MA; Yang, Jiansen; Liu, Yuan; Zheng, Xiaojun

2017-09-01

In order to study the shrinkage performance of basalt concrete, using the shrinkage rate as index, the work not only studied the influence of different length-to-diameter ratio (LDR) on plastic shrinkage and drying shrinkage of basalt fiber concrete, but also analyzed the action mechanism. The results show that when the fiber content is 0.1%, the LDR of 800 and 1200 take better effects on reducing plastic shrinkage, however the fiber content is 0.3%, that of LDR 600 is better. To improve drying shrinkage, the fiber of LDR 800 takes best effect. In the concrete structure, the adding basalt fibers form a uniform and chaotic supporting system, optimize the pore and the void structure of concrete, make the material further compacted, reduce the water loss, so as to decrease the shrinkage of concrete effectively.

Valence State Partitioning of Cr and V Between Pyroxene - Melt: Estimates of Oxygen Fugacity for Martian Basalt QUE 94201

NASA Technical Reports Server (NTRS)

Karner, J. M.; Papike, J. J.; Shearer, C. K.; McKay, G.; Le, L.; Burger, P.

2007-01-01

Several studies, using different oxybarometers, have suggested that the variation of fO2 in martian basalts spans about 3 log units from approx. IW-1 to IW+2. The relatively oxidized basalts (e.g., pyroxene-phyric Shergotty) are enriched in incompatible elements, while the relatively reduced basalts (e.g., olivine-phyric Y980459) are depleted in incompatible elements. A popular interpretation of the above observations is that the martian mantle contains two reservoirs; 1) oxidized and enriched, and 2) reduced and depleted. The basalts are thus thought to represent mixing between these two reservoirs. Recently, Shearer et al. determined the fO2 of primitive olivine-phyric basalt Y980459 to be IW+0.9 using the partitioning of V between olivine and melt. In applying this technique to other basalts, Shearer et al. concluded that the martian mantle shergottite source was depleted and varied only slightly in fO2 (IW to IW+1). Thus the more oxidized, enriched basalts had assimilated a crustal component on their path to the martian surface. In this study we attempt to address the above debate on martian mantle fO2 using the partitioning of Cr and V into pyroxene in pyroxene-phyric basalt QUE 94201.

Quantitative 3-D elemental mapping by LA-ICP-MS of a basaltic clast from the Hanford 300 Area, Washington, USA.

PubMed

Peng, Sheng; Hu, Qinhong; Ewing, Robert P; Liu, Chongxuan; Zachara, John M

2012-02-21

Laser ablation with inductively coupled plasma-mass spectrometry (LA-ICP-MS) was used to measure elemental concentrations at the 100-μm scale in a 3-dimensional manner within a basaltic clast sample collected from the Hanford 300 Area in south-central Washington State, United States. A calibration method was developed to quantify the LA-ICP-MS signal response using a constant-sum mass fraction of eight major elements; the method produced reasonable concentration measurements for both major and trace elements when compared to a standard basalt sample with known concentrations. 3-Dimensional maps (stacked 2-D contour layers, each representing 2100 μm × 2100 μm) show relatively uniform concentration with depth for intrinsic elements such as Si, Na, and Sr. However, U and Cu accumulation were observed near the sample surface, consistent with the site's release history of these contaminants. U and Cu show substantial heterogeneity in their concentration distributions within horizontal slices, while the intrinsic elements are essentially uniformly distributed. From these measured U concentrations and published grain size distributions, gravel and cobbles were estimated to contain about 1% of the contaminant U, implicating the coarse fraction as a long-term release source.

Reactive transport modeling of CO2 mineral sequestration in basaltic rocks

NASA Astrophysics Data System (ADS)

Aradottir, E. S.; Sonnenthal, E. L.; Bjornsson, G.; Jonsson, H.

2011-12-01

CO2 mineral sequestration in basalt may provide a long lasting, thermodynamically stable, and environmentally benign solution to reduce greenhouse gases in the atmosphere. Multi-dimensional, field scale, reactive transport models of this process have been developed with a focus on the CarbFix pilot CO2 injection in Iceland. An extensive natural analog literature review was conducted in order to identify the primary and secondary minerals associated with water-basalt interaction at low and elevated CO2 conditions. Based on these findings, an internally consistent thermodynamic database describing the mineral reactions of interest was developed and validated. Hydrological properties of field scale mass transport models were properly defined by calibration to field data using iTOUGH2. Reactive chemistry was coupled to the models and TOUGHREACT used for running predictive simulations carried out with the objective of optimizing long-term management of injection sites, to quantify the amount of CO2 that can be mineralized, and to identify secondary minerals that compete with carbonates for cations leached from the primary rock. Calibration of field data from the CarbFix reservoir resulted in a horizontal permeability for lava flows of 300 mD and a vertical permeability of 1700 mD. Active matrix porosity was estimated to be 8.5%. The CarbFix numerical models were a valuable engineering tool for designing optimal injection and production schemes aimed at increasing groundwater flow. Reactive transport simulations confirm dissolution of primary basaltic minerals as well as carbonate formation, and thus indicate in situ CO2 mineral sequestration in basalts to be a viable option. Furthermore, the simulations imply that clay minerals are most likely to compete with magnesite-siderite solid solutions for Mg and Fe leached from primary minerals, whereas zeolites compete with calcite for dissolved Ca. In the case of the CarbFix pilot injection, which involves a continuous

The Columbia River Basalt Group: from the gorge to the sea

USGS Publications Warehouse

Wells, Ray E.; Niem, Alan R.; Evarts, Russell C.; Hagstrum, Jonathan T.

2009-01-01

Miocene flood basalts of the Columbia River Basalt Group inundated eastern Washington, Oregon, and adjacent Idaho between 17 and 6 Ma. Some of the more voluminous flows followed the ancestral Columbia River across the Cascade arc, Puget-Willamette trough, and the Coast Range to the Pacific Ocean. We have used field mapping, chemistry, and paleomagnetic directions to trace individual flows and flow packages from the Columbia River Gorge westward into the Astoria Basin, where they form pillow palagonite complexes and mega-invasive bodies into older marine sedimentary rocks. Flows of the Grande Ronde, Wanapum, and Saddle Mountains Basalts all made it to the ocean; at least 33 flows are recognized in the western Columbia River Gorge, 50 in the Willamette Valley, 16 in the lower Columbia River Valley, and at least 12 on the Oregon side of the Astoria Basin. In the Astoria Basin, the basalt flows loaded and invaded the wet marine sediments, producing peperite breccias, soft sediment deformation, and complex invasive relations. Mega-invasive sills up to 500 m thick were emplaced into strata as old as Eocene, and invasive dikes up to 90 m thick can be traced continuously for 25 km near the basin margin. Mega-pillow complexes up to a kilometer thick are interpreted as the remains of lava deltas that prograded onto the shelf and a filled submarine canyon southeast of Astoria, possibly providing the hydraulic head for injection of invasive sills and dikes at depth.

Using Apollo 17 high-Ti mare basalts as windows to the lunar mantle

NASA Technical Reports Server (NTRS)

Neal, Clive R.; Taylor, Lawrence A.

1992-01-01

The Apollo 17 high-Ti mare basalts are derived from source regions containing plagioclase that was not retained in the residue. Ilmenite appears to remain as a residual phase, but plagioclase is exhausted. The open-system behavior of the type B2 basalts results in slightly higher Yb/Hf and La/Sm ratios. The nature of the added component is not clear, but may be a KREEP derivative or residue. The recognition of plagioclase in the source(s) of these basalts suggests that the location of the source region(s) would be more likely to be less than 150 km (i.e., closer to the plagioclase-rich crust), which would allow incorporation of plagioclase into the source through incomplete separation of crustal feldspar.

Back-arc with frontal-arc component origin of Triassic Karmutsen basalt, British Columbia, Canada

USGS Publications Warehouse

Barker, F.; Sutherland, Brown A.; Budahn, J.R.; Plafker, G.

1989-01-01

The largely basaltic, ???4.5-6.2-km-thick, Middle to Upper Triassic Karmutsen Formation is a prominent part of the Wrangellian sequence. Twelve analyses of major and minor elements of representative samples of pillowed and massive basalt flows and sills from Queen Charlotte and Vancouver Islands are ferrotholeiites that show a range of 10.2-3.8% MgO (as normalized, H2O- and CO2-free) and related increases in TiO2 (1.0-2.5%), Zr (43-147 ppm) and Nb (5-16 ppm). Other elemental abundances are not related simply to MgO: distinct groupings are evident in Al2O3, Na2O and Cr, but considerable scatter is present in FeO* (FeO + 0.9Fe2O3) and CaO. Some of the variation is attributed to alteration during low-rank metamorphism or by seawater - including variation of Ba, Rb, Sr and Cu, but high-field-strength elements (Sc, Ti, Y, Zr and Nb) as well as Cr, Ni, Cu and rare-earth elements (REE's) were relatively immobile. REE's show chondrite-normalized patterns ranging from light-REE depleted to moderately light-REE enriched. On eleven discriminant plots these analyses fall largely into or across fields of within-plate basalt (WIP), normal or enriched mid-ocean-ridge tholeiite (MORB) and island-arc tholeiite (IAT). Karmutsen basalts are chemically identical to the stratigraphically equivalent Nikolai Greenstone of southern Alaska and Yukon Territory. These data and the fact that the Karmutsen rests on Sicker Group island-arc rocks of Paleozoic age suggest to us that: 1. (1) the basal arc, after minor carbonate-shale deposition, underwent near-axial back-arc rifting (as, e.g., the Mariana arc rifted at different times); 2. (2) the Karmutsen basalts were erupted along this rift or basin as "arc-rift" tholeiitite; and 3. (3) after subsequent deposition of carbonates and other rocks, and Jurassic magmatism, a large fragment of this basalt-sediment-covered island arc was accreted to North America as Wrangellia. The major- and minor-elemental abundances of Karmutsen basalt is modeled

Geochemical insights into the lithology of mantle sources for Cenozoic alkali basalts in West Qinling, China

NASA Astrophysics Data System (ADS)

Dai, Li-Qun; Zheng, Fei; Zhao, Zi-Fu; Zheng, Yong-Fei

2018-03-01

Although alkali basalts are common in oceanic islands and continental rifts, the lithology of their mantle sources is still controversial. While the peridotite is usually viewed as a common source lithology, there are increasing studies suggesting significant contributions from ultramafic metasomatites such as carbonated peridotite, pyroxenite and hornblendite to the origin of alkali basalts. The present study indicates that carbonated peridotite plus hornblendite would have served as the mantle sources of Cenozoic alkali basalts from the West Qinling orogen in China. The target basalts show low SiO2 contents of 36.9 to 40.8 wt% and highly variable Na2O + K2O contents from 0.86 to 4.77 wt%, but high CaO contents of 12.5 to 16.3 wt% and CaO/Al2O3 ratios of 1.42 to 2.19. They are highly enriched in the majority of incompatible trace elements, but depleted in Rb, K, Pb, Zr, Hf, and Ti. Furthermore, they exhibit high (La/Yb)N, Zr/Hf, Ce/Pb and Nb/Ta ratios, but low Ti/Eu and Hf/Sm ratios. Generally, with increasing (La/Yb)N and CaO/Al2O3 ratios, their Ti/Eu and Hf/Sm ratios decrease whereas their Zr/Hf, Ce/Pb and Nb/Ta ratios increase. These major and trace element features are similar to those of carbonatites and hornblendite-derived melts to some extent, but significantly different from those of mid-ocean ridge basalts (MORB). This suggests that the alkali basalts would be originated from metasomatic mantle sources. A comparison of the major-trace elements in the alkali basalts with those of some representative mantle-derived melts indicates that the source lithology of alkali basalts is a kind of ultramafic metasomatites that are composed of carbonated peridotite and hornblendite. Such metasomatites would be generated by reaction of the depleted MORB mantle peridotite with hydrous, carbonate-bearing felsic melts derived from partial melting of the subducted Paleotethyan oceanic crust. Therefore, the melt-peridotite reaction at the slab-mantle interface in the

Self organizing map neural networks approach for lithologic interpretation of nuclear and electrical well logs in basaltic environment, Southern Syria.

PubMed

Asfahani, J; Ahmad, Z; Ghani, B Abdul

2018-07-01

An approach based on self organizing map (SOM) artificial neural networks is proposed herewith oriented towards interpreting nuclear and electrical well logging data. The well logging measurements of Kodana well in Southern Syria have been interpreted by applying the proposed approach. Lithological cross-section model of the basaltic environment has been derived and four different kinds of basalt have been consequently distinguished. The four basalts are hard massive basalt, hard basalt, pyroclastic basalt and the alteration basalt products- clay. The results obtained by SOM artificial neural networks are in a good agreement with the previous published results obtained by other different techniques. The SOM approach is practiced successfully in the case study of the Kodana well logging data, and can be therefore recommended as a suitable and effective approach for handling huge well logging data with higher number of variables required for lithological discrimination purposes. Copyright © 2018 Elsevier Ltd. All rights reserved.

Acidification mediated by a river plume and coastal upwelling on a fringing reef at the east coast of Hainan Island, Northern South China Sea

NASA Astrophysics Data System (ADS)

Dong, Xu; Huang, Haining; Zheng, Nan; Pan, Aijun; Wang, Sumin; Huo, Cheng; Zhou, Kaiwen; Lin, Hui; Ji, Weidong

2017-09-01

We investigated the dynamics of carbonate system which was greatly modulated by a river plume and coastal upwelling in July 2014 and July 2015 at the east coast of Hainan Island where a fringing reef distributes inshore. By using a three end-member mixing model, we semiquantitatively estimated the removal of dissolved inorganic carbon (DIC) mediated by biological production in the river plume and upwelled water to be 13 ± 17 and 15 ± 16 μmol kg-1, respectively. The enhanced organic production was mainly responsible for these DIC consumptions in both two regimes, however, nearly a half of DIC removal was attributed to biocalcification in the plume system while it was negligible in the upwelling system. Furthermore, the modeled results over reefs revealed that river plume and coastal upwelling were two major threats of acidification to coral communities at the east coast of Hainan Island during cruises. In comparison, the biological contribution to acidification was limited for balancing between organic production and biocalcification during July 2014 cruise, whereas the acidification was greatly intensified by organic degradation during July 2015 cruise. It was verified that naturally local acidification (physical and biological processes) played a major role in great pH decreases on a short-term scale, leading to coastal waters more vulnerable to anthropogenic "ocean acidification" (uptake of atmospheric CO2) by reducing buffering capacity of waters. Finally, effects of acidification associated with other local threats on a fringing reef were further depicted with a conceptual model.