Henry's Law and Noisy Knuckles.

ERIC Educational Resources Information Center

Kimbrough, Doris R.

1999-01-01

Discusses Henry's Law which describes the relationship between the pressure of gas and the concentration of that gas in a solution. Presents an application of Henry's Law to the cracking of knuckles. (CCM)

Measurement of Henry's Law Constants Using Internal Standards: A Quantitative GC Experiment for the Instrumental Analysis or Environmental Chemistry Laboratory

ERIC Educational Resources Information Center

Ji, Chang; Boisvert, Susanne M.; Arida, Ann-Marie C.; Day, Shannon E.

2008-01-01

An internal standard method applicable to undergraduate instrumental analysis or environmental chemistry laboratory has been designed and tested to determine the Henry's law constants for a series of alkyl nitriles. In this method, a mixture of the analytes and an internal standard is prepared and used to make a standard solution (organic solvent)…

Determination of Henry`s law constants by equilibrium partitioning in a closed system using a new in situ optical absorbance method

DOE Office of Scientific and Technical Information (OSTI.GOV)

Allen, J.M.; Balcavage, W.X.; Ramachandran, B.R.

Currently, a great deal of interest exists in developing quantitative descriptions of the transport behavior for organic chemical compounds in the environment. Transport between water and air is of particular significance in this regard. A new method for measurement of thermodynamic Henry`s law constants (H) is reported. In this method, the optical absorbance of a dilute aqueous solution containing an organic compound is followed with time as the compound partitions into the air above the solution in a sealed vessel. The change in optical absorbance and the vapor to liquid volume ratio of the vessel are then used to calculatemore » the value for H. The concentration of the organic compound in the aqueous and vapor phases need not be known. This method allows the approach to equilibrium to be observed in real time so that attainment of equilibrium is readily apparent. This method works particularly well for water-soluble compounds having low vapor pressures. The applicability of this method is limited to compounds that exhibit significant optical absorbance in the ultraviolet and visible regions of the electromagnetic spectrum. Values for H and their temperature dependencies measured using this new method are reported for methacrolein, methyl vinyl ketone, benzaldehyde, and acetophenone. Values for H are also reported for benzene, toluene, and ethylbenzene at 298 K. All reported H data are compared with previously reported values.« less

Effect analysis of quantum chemical descriptors and substituent characteristics on Henry's law constants of polybrominated diphenyl ethers at different temperatures.

PubMed

Long, Jiang; Youli, Qiu; Yu, Li

2017-11-01

Twelve substituent descriptors, 17 quantum chemical descriptors and 1/T were selected to establish a quantitative structure-property relationship (QSPR) model of Henry's law constants for 7 polybrominated diphenyl ethers (PBDEs) at five different temperatures. Then, the lgH of 202 congeners at different temperatures were predicted. The variation rule and regulating mechanism of lgH was studied from the perspectives of both quantum chemical descriptors and substituent characteristics. The R 2 for modeling and testing sets of the final QSPR model are 0.977 and 0.979, respectively, thus indicating good fitness and predictive ability for Henry' law constants of PBDEs at different temperatures. The favorable hydrogen binding sites are the 5,5',6,6'-positions for high substituent congeners and the O atom of the ether bond for low substituent congeners, which affects the interaction between PBDEs and water molecules. lgH is negatively and linearly correlated with 1/T, and the variation trends of lgH with temperature are primarily regulated by individual substituent characteristics, wherein: the more substituents involved, the smaller the lgH. The significant sequence for the main effect of substituent positions is para>meta>ortho, where the ortho-positions are mainly involved in second-order interaction effect (64.01%). Having two substituents in the same ring also provides a significant effect, with 81.36% of second-order interaction effects, particularly where there is an adjacent distribution (55.02%). Copyright © 2017 Elsevier Inc. All rights reserved.

A Laboratory Experiment To Measure Henry's Law Constants of Volatile Organic Compounds with a Bubble Column and a Gas Chromatography Flame Ionization Detector (GC-FID)

ERIC Educational Resources Information Center

Lee, Shan-Hu; Mukherjee, Souptik; Brewer, Brittany; Ryan, Raphael; Yu, Huan; Gangoda, Mahinda

2013-01-01

An undergraduate laboratory experiment is described to measure Henry's law constants of organic compounds using a bubble column and gas chromatography flame ionization detector (GC-FID). This experiment is designed for upper-division undergraduate laboratory courses and can be implemented in conjunction with physical chemistry, analytical…

Effects of temperature, pH, and ionic strength on the Henry's law constant of triethylamine

NASA Astrophysics Data System (ADS)

Leng, Chun-Bo; Roberts, Jason E.; Zeng, Guang; Zhang, Yun-Hong; Liu, Yong

2015-05-01

The Henry's law constants (KH) of triethylamine (TEA) in pure water and in 1-octanol were measured for the temperatures pertinent to the lower troposphere (278-298 K) using a bubble column system coupled to a Fourier transform infrared spectrometer. The KH values of TEA in water and 1-octanol at 298 K are 5.75 ± 0.86 mol L-1 atm-1 and 115.62 ± 5.78 mol L-1 atm-1. The KH values display strong dependence on temperature, pH, and ionic strength. The characteristic times for TEA to establish an equilibrium between gas and droplet with a size of 5.6 µm are ~33 s (298 K, pH = 5.6); ~8.9 × 102 s (278 K, pH = 5.6); ~1.3 × 103 s (298 K, pH = 4.0); and 3.6 × 104 s (278 K, pH = 4.0). The evaluation of TEA partitioning between gas phase and condensed phase implies that TEA predominantly resides in rainwater, and TEA loss to organic aerosol is negligible.

A Henry's Law Test for Experimental Partitioning Studies of Iron Meteorites

NASA Technical Reports Server (NTRS)

Chabot, N. L.; Campbell, A. J.; Humayun, M.; Agee, C. B.

2001-01-01

Low-level doped solid metal/liquid metal experiments analyzed by laser ablation ICP-MS allow Henry's Law to be tested. The results indicate Henry's Law is obeyed and the experimental partition coefficients can be applied to iron meteorites. Additional information is contained in the original extended abstract.

Reinvestigation of the Henry's law constant for hydrogen peroxide with temperature and acidity variation.

PubMed

Huang, Daoming; Chen, Zhongming

2010-01-01

Hydrogen peroxide is not only an important oxidant in itself; it also serves as both sink and temporary reservoir for other important oxidants including HOx (OH and HO2) radicals and O3 in the atmosphere. Its partitioning between gas and aqueous phases in the atmosphere, usually described by its Henry's law constant (K(H)), significantly influences its role in atmospheric processes. Large discrepancies between the K(H) values reported in previous work, however, have created uncertainty for atmospheric modelers. Based on our newly developed online instrumentation, we have re-determined the temperature and acidity dependence of K(H) for hydrogen peroxide at an air pressure of (0.960 +/- 0.013) atm (1 atm = 1.01325 x 10(5) Pa). The results indicated that the temperature dependence of K(H) for hydrogen peroxide fits to the Van't Hoff equation form, expressed as lnK(H) = a/T - b, and a = -deltaH/R, where K(H) is in M/atm (M is mol/L), T is in degrees Kelvin, R is the ideal gas constant, and deltaH is the standard heat of solution. For acidity dependence, results demonstrated that the K(H) value of hydrogen peroxide appeared to have no obvious dependence on decreasing pH level (from pH 7 to pH 1). Combining the dependence of both temperature and acidity, the obtained a and b were 7024 +/- 138 and 11.97 +/- 0.48, respectively, deltaH was (58.40 +/- 1.15) kJ/(K x mol), and the uncertainties represent sigma. Our determined K(H) values for hydrogen peroxide will therefore be of great use in atmospheric models.

On the Henry constant and isosteric heat at zero loading in gas phase adsorption.

PubMed

Do, D D; Nicholson, D; Do, H D

2008-08-01

The Henry constant and the isosteric heat of adsorption at zero loading are commonly used as indicators of the strength of the affinity of an adsorbate for a solid adsorbent. It is assumed that (i) they are observable in practice, (ii) the Van Hoff's plot of the logarithm of the Henry constant versus the inverse of temperature is always linear and the slope is equal to the heat of adsorption, and (iii) the isosteric heat of adsorption at zero loading is either constant or weakly dependent on temperature. We show in this paper that none of these three points is necessarily correct, first because these variables might not be observable since they are outside the range of measurability; second that the linearity of the Van Hoff plot breaks down at very high temperature, and third that the isosteric heat versus loading is a strong function of temperature. We demonstrate these points using Monte Carlo integration and Monte Carlo simulation of adsorption of various gases on a graphite surface. Another issue concerning the Henry constant is related to the way the adsorption excess is defined. The most commonly used equation is the one that assumes that the void volume is the volume extended all the way to a boundary passing through the centres of the outermost solid atoms. With this definition the Henry constant can become negative at high temperatures. Although adsorption at these temperatures may not be practical because of the very low value of the Henry constant, it is more useful to define the Henry constant in such a way that it is always positive at all temperatures. Here we propose the use of the accessible volume; the volume probed by the adsorbate when it is in nonpositive regions of the potential, to calculate the Henry constant.

Should bulk cloudwater or fogwater samples obey Henry's law?

NASA Astrophysics Data System (ADS)

Pandis, Spyros N.; Seinfeld, John H.

1991-06-01

Mixing of droplets with different pH that are individually in Henry's law equilibrium with the surrounding atmosphere always results in a bulk mixture that is supersaturated with weak acids like S(IV) and HCOOH, and bases like NH3 with respect to the original atmosphere. High supersaturations result only when the pH of the bulk droplet mixture exceeds the pKa of the species, in which pH range large pH differences among droplets of different sizes lead to large deviations from Henry's law for the bulk mixture. The deviation is shown to depend on the ratio of the arithmetic mean to the harmonic mean of the hydrogen ion concentrations of the droplets with the liquid water content used as weighting factor in the calculation of the means. The theory developed can explain observed discrepancies from Henry's law in atmospheric samples and also other observed phenomena like the reported increase of pH values of bulk aqueous samples during storage.

Structure-activity relationships to estimate the effective Henry's law coefficients of organics of atmospheric interest

NASA Astrophysics Data System (ADS)

Raventos-Duran, Teresa; Valorso, Richard; Aumont, Bernard; Camredon, Marie

2010-05-01

The oxidation of volatile organic compounds emitted in the atmosphere involves complex reaction mechanisms which leads to the formation of oxygenated organic intermediates, usually denoted as secondary organics. The fate of these secondary organics remains poorly quantified due to a lack of information about their speciation, distribution and evolution in the gas and condensed phases. A significant fraction of secondary organics may dissolve into the tropospheric aqueous phase owing to the presence of polar moieties generated during the oxidation processes. The partitioning of organics between the gas and the aqueous atmospheric phases is usually described in the basis of Henry's law. Atmospheric models require a knowledge of the Henry's law coefficient (H) for every water soluble organic species described in the chemical mechanism. Methods that can predict reliable H values for the vast number of organic compounds are therefore required. We have compiled a data set of experimental Henry's law constants for compounds bearing functional groups of atmospheric relevance. This data set was then used to develop GROMHE, a structure activity relationship to predict H values based on a group contribution approach. We assessed its performance with two other available estimation methods. The results show that for all these methods the reliability of the estimates decreases with increasing solubility. We discuss differences between methods and found that GROMHE had greater prediction ability.

Optimal experimental designs for estimating Henry's law constants via the method of phase ratio variation.

PubMed

Kapelner, Adam; Krieger, Abba; Blanford, William J

2016-10-14

When measuring Henry's law constants (k H ) using the phase ratio variation (PRV) method via headspace gas chromatography (G C ), the value of k H of the compound under investigation is calculated from the ratio of the slope to the intercept of a linear regression of the inverse G C response versus the ratio of gas to liquid volumes of a series of vials drawn from the same parent solution. Thus, an experimenter collects measurements consisting of the independent variable (the gas/liquid volume ratio) and dependent variable (the G C -1 peak area). A review of the literature found that the common design is a simple uniform spacing of liquid volumes. We present an optimal experimental design which estimates k H with minimum error and provides multiple means for building confidence intervals for such estimates. We illustrate performance improvements of our design with an example measuring the k H for Naphthalene in aqueous solution as well as simulations on previous studies. Our designs are most applicable after a trial run defines the linear G C response and the linear phase ratio to the G C -1 region (where the PRV method is suitable) after which a practitioner can collect measurements in bulk. The designs can be easily computed using our open source software optDesignSlopeInt, an R package on CRAN. Copyright © 2016 Elsevier B.V. All rights reserved.

Henry's Constants of Persistent Organic Pollutants by a Group-Contribution Method Based on Scaled-Particle Theory.

PubMed

Razdan, Neil K; Koshy, David M; Prausnitz, John M

2017-11-07

A group-contribution method based on scaled-particle theory was developed to predict Henry's constants for six families of persistent organic pollutants: polychlorinated benzenes, polychlorinated biphenyls, polychlorinated dibenzodioxins, polychlorinated dibenzofurans, polychlorinated naphthalenes, and polybrominated diphenyl ethers. The group-contribution model uses limited experimental data to obtain group-interaction parameters for an easy-to-use method to predict Henry's constants for systems where reliable experimental data are scarce. By using group-interaction parameters obtained from data reduction, scaled-particle theory gives the partial molar Gibbs energy of dissolution, Δg̅ 2 , allowing calculation of Henry's constant, H 2 , for more than 700 organic pollutants. The average deviation between predicted values of log H 2 and experiment is 4%. Application of an approximate van't Hoff equation gives the temperature dependence of Henry's constants for polychlorinated biphenyls, polychlorinated naphthalenes, and polybrominated diphenyl ethers in the environmentally relevant range 0-40 °C.

Smog chamber experiments to investigate Henry's law constants of glyoxal using different seed aerosols as well as imidazole formation in the presence of ammonia

NASA Astrophysics Data System (ADS)

Jakob, Ronit

2015-04-01

Aerosols play an important role in the chemistry and physics of the atmosphere. Hence, they have a direct as well as an indirect impact on the earth's climate. Depending on their formation, one distinguishes between primary and secondary aerosols[1]. Important groups within the secondary aerosols are the secondary organic aerosols (SOAs). In order to improve predictions about these impacts on the earth's climate the existing models need to be optimized, because they still underestimate SOA formation[2]. Glyoxal, the smallest α-dicarbonyl, not only acts as a tracer for SOA formation but also as a direct contributor to SOA. Because glyoxal has such a high vapour pressure, it was common knowledge that it does not take part in gas-particle partitioning and therefore has no impact on direct SOA formation. However, the Henry's law constant for glyoxal is surprisingly high. This has been explained by the hydration of the aldehyde groups, which means that a species with a lower vapour pressure is produced. Therefore the distribution of glyoxal between gas- and particle phase is atmospherically relevant and the direct contribution of glyoxal to SOA can no longer be neglected[3]. Besides this particulate glyoxal is able to undergo heterogeneous chemistry with gaseous ammonia to form imidazoles. This plays an important role for regions with aerosols exhibiting alkaline pH values for example from lifestock or soil dust because imidazoles as nitrogen containing compounds change the optical properties of aerosols[4]. A high salt concentration present in chamber seed aerosols leads to an enhanced glyoxal uptake into the particle. This effect is called "salting-in". The salting effect depends on the composition of the seed aerosol as well as the soluble compound. For very polar compounds, like glyoxal, a "salting-in" is observed[3]. Glyoxal particle formation during a smog chamber campaign at Paul-Scherrer-Institut (PSI) in Switzerland was examined using different seed aerosols

Henry constant and isosteric heat at zero-loading for gas adsorption in carbon nanotubes.

PubMed

Do, D D; Do, H D; Wongkoblap, A; Nicholson, D

2008-12-28

The Henry constant and the isosteric heat of adsorption at zero loading in a carbon nanotube bundle are studied with Monte Carlo integration for the adsorption of gases over a range of temperatures. The spacing between nanotubes in a bundle is determined from the minimization of potential energy of interaction between these tubes. We study different tube configurations with bundles of 2, 3, 4 and 7 tubes. Depending on the configuration it is found that the spacing is of between 0.31 to 0.333 nm, and this falls within the range reported in the literature. The Henry constant has been carefully defined so that it will not become negative at high temperatures. This is done with the aid of accessible volume, rather than the usual absolute void volume. We show that linearity of the van't Hoff plot for the Henry constant is not strictly followed. Furthermore the slope of this plot is not equal to the isosteric heat of adsorption at zero loading, which is found to be a strong function of temperature. From the results we find that the Henry constant and the heat of adsorption depend on the tube configuration. In general the adsorption in the cusp interstices is strongest followed by that inside the tube and finally on the outer surface. However for very small tubes adsorption occurs inside the tube first. For molecules with orientation, the behaviour is even more interesting and the shape of the isosteric heat versus temperature depends on the degree of orientation, tube configuration and the domain of adsorption (interstices, inside the tube and on the outer surface).

Temperature dependencies of Henry's law constants and octanol/water partition coefficients for key plant volatile monoterpenoids.

PubMed

Copolovici, Lucian O; Niinemets, Ulo

2005-12-01

To model the emission dynamics and changes in fractional composition of monoterpenoids from plant leaves, temperature dependencies of equilibrium coefficients must be known. Henry's law constants (H(pc), Pa m3 mol(-1) and octanol/water partition coefficients (K(OW), mol mol(-1)) were determined for 10 important plant monoterpenes at physiological temperature ranges (25-50 degrees C for H(pc) and 20-50 degrees C for K(OW)). A standard EPICS procedure was established to determine H(pc) and a shake flask method was used for the measurements of K(OW). The enthalpy of volatilization (deltaH(vol)) varied from 18.0 to 44.3 kJ mol(-1) among the monoterpenes, corresponding to a range of temperature-dependent increase in H(pc) between 1.3- and 1.8-fold per 10 degrees C rise in temperature. The enthalpy of water-octanol phase change varied from -11.0 to -23.8 kJ mol(-1), corresponding to a decrease of K(OW) between 1.15- and 1.32-fold per 10 degrees C increase in temperature. Correlations among physico-chemical characteristics of a wide range of monoterpenes were analyzed to seek the ways of derivation of H(pc) and K(OW) values from other monoterpene physico-chemical characteristics. H(pc) was strongly correlated with monoterpene saturated vapor pressure (P(v)), and for lipophilic monoterpenes, deltaH(vol) scaled positively with the enthalpy of vaporization that characterizes the temperature dependence of P(v) Thus, P(v) versus temperature relations may be employed to derive the temperature relations of H(pc) for these monoterpenes. These data collectively indicate that monoterpene differences in H(pc) and K(OW) temperature relations can importantly modify monoterpene emissions from and deposition on plant leaves.

Recent advances in thermal desorption-gas chromatography-mass spectrometery method to eliminate the matrix effect between air and water samples: application to the accurate determination of Henry's law constant.

PubMed

Kim, Yong-Hyun; Kim, Ki-Hyun

2014-05-16

Accurate values for the Henry's law constants are essential to describe the environmental dynamics of a solute, but substantial errors are recognized in many reported data due to practical difficulties in measuring solubility and/or vapor pressure. Despite such awareness, validation of experimental approaches has scarcely been made. An experimental approach based on thermal desorption-gas chromatography-mass spectrometery (TD-GC-MS) method was developed to concurrently allow the accurate determination of target compounds from the headspace and aqueous samples in closed equilibrated system. The analysis of six aromatics and eight non-aromatic oxygenates was then carried out in a static headspace mode. An estimation of the potential bias and mass balance (i.e., sum of mass measured individually from gas and liquid phases vs. the mass initially added to the system) demonstrates compound-specific phase dependency so that the best results are obtained by aqueous (less soluble aromatics) and headspace analysis (more soluble non-aromatics). Accordingly, we were able to point to the possible sources of biases in previous studies and provide the best estimates for the Henry's constants (Matm(-1)): benzene (0.17), toluene (0.15), p-xylene (0.13), m-xylene (0.13), o-xylene (0.19), styrene (0.27); propionaldehyde (9.26), butyraldehyde (6.19), isovaleraldehyde (2.14), n-valeraldehyde (3.98), methyl ethyl ketone (10.5), methyl isobutyl ketone (3.93), n-butyl acetate (2.41), and isobutyl alcohol (22.2). Copyright © 2014 Elsevier B.V. All rights reserved.

Estimation of Henry's Law Constant for a Diverse Set of Organic Compounds from Molecular Structure

EPA Science Inventory

The SPARC (SPARC Performs Automated Reasoning in Chemistry) vapor pressure and activity coefficient models were coupled to estimate Henry’s Law Constant (HLC) in water and in hexadecane for a wide range of non-polar and polar organic compounds without modification or additional p...

Determination of temperature dependent Henry's law constants of polychlorinated naphthalenes: Application to air-sea exchange in Izmir Bay, Turkey

NASA Astrophysics Data System (ADS)

Odabasi, Mustafa; Adali, Mutlu

2016-12-01

The Henry's law constant (H) is a crucial variable to investigate the air-water exchange of persistent organic pollutants. H values for 32 polychlorinated naphthalene (PCN) congeners were measured using an inert gas-stripping technique at five temperatures ranging between 5 and 35 °C. H values in deionized water (at 25 °C) varied between 0.28 ± 0.08 Pa m3 mol-1 (PCN-73) and 18.01 ± 0.69 Pa m3 mol-1 (PCN-42). The agreement between the measured and estimated H values from the octanol-water and octanol-air partition coefficients was good (measured/estimated ratio = 1.00 ± 0.41, average ± SD). The calculated phase change enthalpies (ΔHH) were within the interval previously determined for other several semivolatile organic compounds (42.0-106.4 kJ mol-1). Measured H values, paired atmospheric and aqueous concentrations and meteorological variables were also used to reveal the level and direction of air-sea exchange fluxes of PCNs at the coast of Izmir Bay, Turkey. The net PCN air-sea exchange flux varied from -0.55 (volatilization, PCN-24/14) to 2.05 (deposition, PCN-23) ng m-2 day-1. PCN-19, PCN-24/14, PCN-42, and PCN-33/34/37 were mainly volatilized from seawater while the remaining congeners were mainly deposited. The overall number of the cases showing deposition was higher (67.9%) compared to volatilization (21.4%) and near equilibrium (10.7%).

Measuring Uptake Coefficients and Henry's Law Constants of Gas-Phase Species with Models for Secondary Organic Aerosol

NASA Astrophysics Data System (ADS)

Fairhurst, M. C.; Waring-Kidd, C.; Ezell, M. J.; Finlayson-Pitts, B. J.

2014-12-01

Volatile organic compounds (VOC) are oxidized in the atmosphere and their products contribute to secondary organic aerosol (SOA) formation. These particles have been shown to have effects on visibility, climate, and human health. Current models typically under-predict SOA concentrations from field measurements. Underestimation of these concentrations could be a result of how models treat particle growth. It is often assumed that particles grow via instantaneous thermal equilibrium partitioning between liquid particles and gas-phase species. Recent work has shown that growth may be better represented by irreversible, kinetically limited uptake of gas-phase species onto more viscous, tar-like SOA. However, uptake coefficients for these processes are not known. The goal of this project is to measure uptake coefficients and solubilities for different gases onto models serving as proxies for SOA and determine how they vary based on the chemical composition of the gas and the condensed phase. Experiments were conducted using two approaches: attenuated total reflectance-Fourier transform infrared (ATR-FTIR) spectroscopy and a flow system coupled to a mass spectrometer. The ATR crystal was coated with the SOA proxy and the gas-phase species introduced via a custom flow system. Uptake of the gas-phase species was characterized by measuring the intensity of characteristic IR bands as a function of time, from which a Henry's law constant and initial estimate of uptake coefficients could be obtained. Uptake coefficients were also measured in a flow system where the walls of the flow tube were coated with the SOA proxy and gas-phase species introduced via a moveable inlet. Uptake coefficients were derived from the decay in gas-phase species measured by mass spectrometry. The results of this work will establish a structure-interaction relationship for uptake of gases into SOA that can be implemented into regional and global models.

Temperature dependence of Henry's law constants and KOA for simple and heteroatom-substituted PAHs by COSMO-RS

NASA Astrophysics Data System (ADS)

Parnis, J. Mark; Mackay, Donald; Harner, Tom

2015-06-01

Henry's Law constants (H) and octanol-air partition coefficients (KOA) for polycyclic aromatic hydrocarbons (PAHs) and selected nitrogen-, oxygen- and sulfur-containing derivatives have been computed using the COSMO-RS method between -5 and 40 °C in 5 °C intervals. The accuracy of the estimation was assessed by comparison of COSMOtherm values with published experimental temperature-dependence data for these and similar PAHs. COSMOtherm log H estimates with temperature-variation for parent PAHs are shown to have a root-mean-square (RMS) error of 0.38 (PAH), based on available validation data. Estimates of O-, N- and S-substituted derivative log H values are found to have RMS errors of 0.30 at 25 °C. Log KOA estimates with temperature variation from COSMOtherm are shown to be strongly correlated with experimental values for a small set of unsubstituted PAHs, but with a systematic underestimation and associated RMS error of 1.11. Similar RMS error of 1.64 was found for COSMO-RS estimates of a group of critically-evaluated log KOA values at room temperature. Validation demonstrates that COSMOtherm estimates of H and KOA are of sufficient accuracy to be used for property screening and preliminary environmental risk assessment, and perform very well for modeling the influence of temperature on partitioning behavior in the temperature range -5 to 40 °C. Temperature-dependent shifts of up to 2 log units in log H and one log unit for log KOA are predicted for PAH species over the range -5 and 40 °C. Within the family of PAH molecules, COSMO-RS is sufficiently accurate to make it useful as a source of estimates for modeling purposes, following corrections for systematic underestimation of KOA. Average changes in the values for log H and log KOA upon substitution are given for various PAH substituent categories, with the most significant shifts being associated with the ionizing nitro functionality and keto groups.

Experimental determination of Henry's law constants of difluoromethane (HFC-32) and the salting-out effects in aqueous salt solutions relevant to seawater

NASA Astrophysics Data System (ADS)

Kutsuna, Shuzo

2017-06-01

Gas-to-water equilibrium coefficients, KeqS (in M atm-1), of difluoromethane (CH2F2), a hydrofluorocarbon refrigerant (HFC-32), in aqueous salt solutions relevant to seawater were determined over a temperature (T) range from 276 to 313 K and a salinity (S) range up to 51 ‰ by means of an inert-gas stripping method. From the van't Hoff equation, the KeqS value in water, which corresponds to the Henry's law constant (KH), at 298 K was determined to be 0.065 M atm-1. The salinity dependence of KeqS (the salting-out effect), ln(KH/KeqS), did not obey the Sechenov equation but was proportional to S0. 5. Overall, the KeqS(T) value was expressed by ln(KeqS(T)) = -49.71 + (77.70 - 0.134 × S0. 5) × (100/T) + 19.14 × ln(T/100). By using this equation in a lower-tropospheric semi-hemisphere (30-90 °S) of the Advanced Global Atmospheric Gases Experiment (AGAGE) 12-box model, we estimated that 1 to 4 % of the atmospheric burden of CH2F2 resided in the ocean mixed layer and that this percentage was at least 4 % in the winter; dissolution of CH2F2 in the ocean may partially influence estimates of CH2F2 emissions from long-term observational data of atmospheric CH2F2 concentrations.

BUBBLE STRIPPING TO DETERMINE HYDROGEN CONCENTRATIONS IN GROUND WATER: A PRACTICAL APPLICATION OF HENRY'S LAW

EPA Science Inventory

The Bubble Stripping Method is a chemical testing method that operates on the principle of Henry's Law. It is useful for determining concentrations of hydrogen in well water, and it is capable of detecting concentrations on the order of nanomoles per liter. The method provides ...

Development of Monopole Interaction Models for Ionic Compounds. Part I: Estimation of Aqueous Henry's Law Constants for Ions and Gas Phase pKa Values for Acidic Compounds.

PubMed

Hilal, S H; Saravanaraj, A N; Carreira, L A

2014-02-01

The SPARC (SPARC Performs Automated Reasoning in Chemistry) physicochemical mechanistic models for neutral compounds have been extended to estimate Henry's Law Constant (HLC) for charged species by incorporating ionic electrostatic interaction models. Combinations of absolute aqueous pKa values, relative pKa values in the gas phase, and aqueous HLC for neutral compounds have been used to develop monopole interaction models that quantify the energy differences upon moving an ionic solute molecule from the gas phase to the liquid phase. Inter-molecular interaction energies were factored into mechanistic contributions of monopoles with polarizability, dipole, H-bonding, and resonance. The monopole ionic models were validated by a wide range of measured gas phase pKa data for 450 acidic compounds. The RMS deviation error and R(2) for the OH, SH, CO2 H, CH3 and NR2 acidic reaction centers (C) were 16.9 kcal/mol and 0.87, respectively. The calculated HLCs of ions were compared to the HLCs of 142 ions calculated by quantum mechanics. Effects of inter-molecular interaction of the monopoles with polarizability, dipole, H-bonding, and resonance on acidity of the solutes in the gas phase are discussed. Copyright © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Systematic harmonic power laws inter-relating multiple fundamental constants

NASA Astrophysics Data System (ADS)

Chakeres, Donald; Buckhanan, Wayne; Andrianarijaona, Vola

2017-01-01

Power laws and harmonic systems are ubiquitous in physics. We hypothesize that 2, π, the electron, Bohr radius, Rydberg constant, neutron, fine structure constant, Higgs boson, top quark, kaons, pions, muon, Tau, W, and Z when scaled in a common single unit are all inter-related by systematic harmonic powers laws. This implies that if the power law is known it is possible to derive a fundamental constant's scale in the absence of any direct experimental data of that constant. This is true for the case of the hydrogen constants. We created a power law search engine computer program that randomly generated possible positive or negative powers searching when the product of logical groups of constants equals 1, confirming they are physically valid. For 2, π, and the hydrogen constants the search engine found Planck's constant, Coulomb's energy law, and the kinetic energy law. The product of ratios defined by two constants each was the standard general format. The search engine found systematic resonant power laws based on partial harmonic fraction powers of the neutron for all of the constants with products near 1, within their known experimental precision, when utilized with appropriate hydrogen constants. We conclude that multiple fundamental constants are inter-related within a harmonic power law system.

Generation of sub-part-per-billion gaseous volatile organic compounds at ambient temperature by headspace diffusion of aqueous standards through decoupling between ideal and nonideal Henry's law behavior.

PubMed

Kim, Yong-Hyun; Kim, Ki-Hyun

2013-05-21

In the analysis of volatile organic compounds in air, the preparation of their gaseous standards at low (sub-ppb) concentration levels with high reliability is quite difficult. In this study, a simple dynamic headspace-based approach was evaluated as a means of generating vapor-phase volatile organic compounds from a liquid standard in an impinger at ambient temperature (25 °C). For a given sampling time, volatile organic compound vapor formed in the headspace was swept by bypassing the sweep gas through the impinger and collected four times in quick succession in separate sorbent tubes. In each experiment, a fresh liquid sample was used for each of the four sampling times (5, 10, 20, and 30 min) at a steady flow rate of 50 mL min(-1). The air-water partitioning at the most dynamic (earliest) sweeping stage was established initially in accord with ideal Henry's law, which was then followed by considerably reduced partitioning in a steady-state equilibrium (non-ideal Henry's law). The concentrations of gaseous volatile organic compounds, collected after the steady-state equilibrium, reached fairly constant values: for instance, the mole fraction of toluene measured at a sweeping interval of 10 and 30 min averaged 1.10 and 0.99 nmol mol(-1), respectively (after the initial 10 min sampling). In the second stage of our experiment, the effect of increasing the concentrations of liquid spiking standard was also examined by collecting sweep gas samples from two consecutive 10 min runs. The volatile organic compounds, collected in the first and second 10 min sweep gas samples, exhibited ideal and nonideal Henry's law behavior, respectively. From this observation, we established numerical relationships to predict the mole fraction (or mixing ratio) of each volatile organic compound in steady-state equilibrium in relation to the concentration of standard spiked into the system. This experimental approach can thus be used to produce sub-ppb levels of gaseous volatile organic

Use of experimentally determined Henry's Law and salting-out constants for ethanol in seawater for determination of the saturation state of ethanol in coastal waters.

PubMed

Willey, Joan D; Powell, Jacqueline P; Avery, G Brooks; Kieber, Robert J; Mead, Ralph N

2017-09-01

The Henry's law constant for ethanol in seawater was experimentally determined to be 221 ± 4 M/atm at 22 °C compared with 247 ± 6 M/atm in pure water. The salting out coefficient for ethanol was 0.13 M -1 . In seawater ln(K H ) = -(12.8 ± 0.7) + (5310 ± 197)/T where K H is in M atm -1 and temperature is in K. This plus the salting out coefficient allow calculation of K H for any estuarine or sea water between 1 and 35 °C. High concentrations of dissolved organic carbon do not affect K H values in fresh or seawater. Nearshore surface waters were usually undersaturated with respect to gas phase ethanol except when air concentrations decreased, whereas surface seawater 40 km from shore was supersaturated. The percent saturation in surface waters is driven primarily by changes in air concentrations because these change quickly (hours) and more extensively than surface water. This study allows calculation of ethanol saturation states from air and surface water concentrations which is a necessary step to define the role of surface oceans in the global biogeochemical cycling of ethanol both now and in the future as use of ethanol biofuel continues to grow. Copyright © 2017 Elsevier Ltd. All rights reserved.

Partition coefficients for REE between garnets and liquids - Implications of non-Henry's Law behaviour for models of basalt origin and evolution

NASA Technical Reports Server (NTRS)

Harrison, W. J.

1981-01-01

An experimental investigation of Ce, Sm and Tm rare earth element (REE) partition coefficients between coexisting garnets (both natural and synthetic) and hydrous liquids shows that Henry's Law may not be obeyed over a range of REE concentrations of geological relevance. Systematic differences between the three REE and the two garnet compositions may be explained in terms of the differences between REE ionic radii and those of the dodecahedral site into which they substitute, substantiating the Harrison and Wood (1980) model of altervalent substitution. Model calculations demonstrate that significant variation can occur in the rare earth contents of melts produced from a garnet lherzolite, if Henry's Law partition coefficients do not apply for the garnet phase.

Perturbation theory in the catalytic rate constant of the Henri-Michaelis-Menten enzymatic reaction.

PubMed

Bakalis, Evangelos; Kosmas, Marios; Papamichael, Emmanouel M

2012-11-01

The Henry-Michaelis-Menten (HMM) mechanism of enzymatic reaction is studied by means of perturbation theory in the reaction rate constant k (2) of product formation. We present analytical solutions that provide the concentrations of the enzyme (E), the substrate (S), as well as those of the enzyme-substrate complex (C), and the product (P) as functions of time. For k (2) small compared to k (-1), we properly describe the entire enzymatic activity from the beginning of the reaction up to longer times without imposing extra conditions on the initial concentrations E ( o ) and S ( o ), which can be comparable or much different.

Halogenated methyl-phenyl ethers (anisoles) in the environment: determination of vapor pressures, aqueous solubilities, Henry's law constants, and gas/water- (Kgw), n-octanol/water- (Kow) and gas/n-octanol (Kgo) partition coefficients.

PubMed

Pfeifer, O; Lohmann, U; Ballschmiter, K

2001-11-01

Halogenated methyl-phenyl ethers (methoxybenzenes, anisoles) are ubiquitous organics in the environment although they are not produced in industrial quantities. Modelling the fate of organic pollutants such as halogenated anisoles requires a knowledge of the fundamental physico-chemical properties of these compounds. The isomer-specific separation and detection of 60 of the 134 possible congeners allowing an environmental fingerprinting are reported in this study. The vapor pressure p0(L) of more than 60 and further physico-chemical properties of 26 available congeners are given. Vapor pressures p0(L), water solubilities S(L)W, and n-octanol/water partition coefficients Kow were determined by capillary HR-GC (High Resolution Gas Chromatography) on a non-polar phase and by RP-HPLC (Reversed Phase High Performance Liquid Chromatography) on a C18 phase with chlorobenzenes as reference standards. From these experimental data the Henry's law constants H, and the gas/water Kgw and gas/n-octanol Kgo partition coefficients were calculated. We found that vapor pressures, water solubilities, and n-octanol/water partition coefficients of the halogenated anisoles are close to those of the chlorobenzenes. A similar environmental fate of both groups can, therefore, be predicted.

A Simple Method to Calculate the Temperature Dependence of the Gibbs Energy and Chemical Equilibrium Constants

ERIC Educational Resources Information Center

Vargas, Francisco M.

2014-01-01

The temperature dependence of the Gibbs energy and important quantities such as Henry's law constants, activity coefficients, and chemical equilibrium constants is usually calculated by using the Gibbs-Helmholtz equation. Although, this is a well-known approach and traditionally covered as part of any physical chemistry course, the required…

Joseph Henry and the Telegraph

NASA Astrophysics Data System (ADS)

Hochfelder, David

1997-04-01

Morse's telegraph rested upon three scientific advances which occured between 1800 and 1830: the development of battery technology, the formulation of laws governing the behavior of electrical components in circuits, and the discovery of electromagnetic phenomena. Joseph Henry was crucial to the development of the early telegraph. His work on electromagnetism made it possible for the electric current to manifest itself as useful mechanical work. Henry developed electromagnets of sufficient lifting power, but which drew relatively small currents; these magnets were the heart of Morse's telegraph receiver. Morse also used electromagnets as relays, which allowed him to transmit signals over great distances. Morse often acknowledged his debt to Henry, and the two enjoyed a cordial working relationship until the mid-1840s. But during the bitter and protracted litigation over Morse's patent, Henry testified (unwillingly, he claimed) against the inventor. This began a lifelong quarrel between the two men, the specifics of which were tedious and petty. In general terms, however, their conflict arose over different notions regarding scientific discovery and technological innovation.

Analytical Phase Equilibrium Function for Mixtures Obeying Raoult's and Henry's Laws

NASA Astrophysics Data System (ADS)

Hayes, Robert

When a mixture of two substances exists in both the liquid and gas phase at equilibrium, Raoults and Henry's laws (ideal solution and ideal dilute solution approximations) can be used to estimate the gas and liquid mole fractions at the extremes of either very little solute or solvent. By assuming that a cubic polynomial can reasonably approximate the intermediate values to these extremes as a function of mole fraction, the cubic polynomial is solved and presented. A closed form equation approximating the pressure dependence on mole fraction of the constituents is thereby obtained. As a first approximation, this is a very simple and potentially useful means to estimate gas and liquid mole fractions of equilibrium mixtures. Mixtures with an azeotrope require additional attention if this type of approach is to be utilized. This work supported in part by federal Grant NRC-HQ-84-14-G-0059.

Investigation of Saltwater Intrusion and Recirculation of Seawater for Henry Constant Dispersion and Velocity-Dependent Dispersion Problems and Field-Scale Problem

NASA Astrophysics Data System (ADS)

Motz, L. H.; Kalakan, C.

2013-12-01

Three problems regarding saltwater intrusion, namely the Henry constant dispersion and velocity-dependent dispersion problems and a larger, field-scale velocity-dependent dispersion problem, have been investigated to determine quantitatively how saltwater intrusion and the recirculation of seawater at a coastal boundary are related to the freshwater inflow and the density-driven buoyancy flux. Based on dimensional analysis, saltwater intrusion and the recirculation of seawater are dependent functions of the independent ratio of freshwater advective flux relative to the density-driven vertical buoyancy flux, defined as az (or a for an isotropic aquifer), and the aspect ratio of horizontal and vertical dimensions of the cross-section. For the Henry constant dispersion problem, in which the aquifer is isotropic, saltwater intrusion and recirculation are related to an additional independent dimensionless parameter that is the ratio of the constant dispersion coefficient treated as a scalar quantity, the porosity, and the freshwater advective flux, defined as b. For the Henry velocity-dependent dispersion problem, the ratio b is zero, and saltwater intrusion and recirculation are related to an additional independent dimensionless parameter that is the ratio of the vertical and horizontal dispersivities, or rα = αz/αx. For an anisotropic aquifer, saltwater intrusion and recirculation are also dependent on the ratio of vertical and horizontal hydraulic conductivities, or rK = Kz/Kx. For the field-scale velocity-dependent dispersion problem, saltwater intrusion and recirculation are dependent on the same independent ratios as the Henry velocity-dependent dispersion problem. In the two-dimensional cross-section for all three problems, freshwater inflow occurs at an upgradient boundary, and recirculated seawater outflow occurs at a downgradient coastal boundary. The upgradient boundary is a specified-flux boundary with zero freshwater concentration, and the downgradient

Temperature dependence of the Henry's law constant for hydrogen storage in NaA zeolites: a Monte Carlo simulation study.

PubMed

Sousa, João Miguel; Ferreira, António Luís; Fagg, Duncan Paul; Titus, Elby; Krishna, Rahul; Gracio, José

2012-08-01

Grand canonical Monte Carlo simulations of hydrogen adsorption in zeolites NaA were carried out for a wide range of temperatures between 77 and 300 K and pressures up to 180 MPa. A potential model was used that comprised of three main interactions: van der Waals, coulombic and induced polarization by the electric field in the system. The computed average number of adsorbed molecules per unit cell was compared with available results and found to be in agreement in the regime of moderate to high pressures. The particle insertion method was used to calculate the Henry coefficient for this model and its dependence on temperature.

Nonlocal conservation laws of the constant astigmatism equation

NASA Astrophysics Data System (ADS)

Hlaváč, Adam; Marvan, Michal

2017-03-01

For the constant astigmatism equation, we construct a system of nonlocal conservation laws (an abelian covering) closed under the reciprocal transformations. The corresponding potentials are functionally independent modulo a Wronskian type relation.

Numerical determination of Paris law constants for carbon steel using a two-scale model

NASA Astrophysics Data System (ADS)

Mlikota, M.; Staib, S.; Schmauder, S.; Božić, Ž.

2017-05-01

For most engineering alloys, the long fatigue crack growth under a certain stress level can be described by the Paris law. The law provides a correlation between the fatigue crack growth rate (FCGR or da/dN), the range of stress intensity factor (ΔK), and the material constants C and m. A well-established test procedure is typically used to determine the Paris law constants C and m, considering standard specimens, notched and pre-cracked. Definition of all the details necessary to obtain feasible and comparable Paris law constants are covered by standards. However, these cost-expensive tests can be replaced by appropriate numerical calculations. In this respect, this paper deals with the numerical determination of Paris law constants for carbon steel using a two-scale model. A micro-model containing the microstructure of a material is generated using the Finite Element Method (FEM) to calculate the fatigue crack growth rate at a crack tip. The model is based on the Tanaka-Mura equation. On the other side, a macro-model serves for the calculation of the stress intensity factor. The analysis yields a relationship between the crack growth rates and the stress intensity factors for defined crack lengths which is then used to determine the Paris law constants.

Determination of Henry’s Law Constants Using Internal Standards with Benchmark Values

EPA Science Inventory

It is shown that Henry’s law constants can be experimentally determined by comparing headspace content of compounds with known constants to interpolate the constants of other compounds. Studies were conducted over a range of water temperatures to identify temperature dependence....

Henry's law constants measurements of the nonylphenol isomer 4(3‧,5‧-dimethyl-3‧-heptyl)-phenol, tertiary octylphenol and γ-hexachlorocyclohexane between 278 and 298 K

NASA Astrophysics Data System (ADS)

Xie, Zhiyong; Le Calvé, Stéphane; Feigenbrugel, Valérie; Preuß, Thomas G.; Vinken, Ralph; Ebinghaus, Ralf; Ruck, Wolfgang

2004-09-01

Henry's Law Constants (HLC, M atm-1) were determined for the diastereomeric mixture of the nonylphenol isomer 4(3‧,5‧-dimethyl-3‧-heptyl)-phenol diastereomers (NP353(+) and NP353(-)), tertiary octylphenol (t-OP) and γ-hexachlorocyclohexane (γ-HCH) in artificial seawater over a temperature range 278-298 K using a dynamic equilibrium system. Trace organic substances present in the gas phase were trapped by tandem XAD-2 cartridges and extracted with a soxhlet extractor. The extracts were derivatived with N,O-bis(trimethylsilyl)-trifluoroacetamide (BSTFA), and then analyzed with GC-MS in the selective ion mode. At 293 K and in artificial seawater, HLC (M atm-1) were found to be equal to: NP353(+), HLC=(483±169); NP353(-), HLC=(551±193); t-OP, HLC=(400±140); γ-HCH, HLC=(876±307). The obtained data were used to derive the following Van't Hoff expressions: ln HLC (NP353(+))=8.73 (±0.95)×(1000/T) -23.61 (±3.30); ln HLC (NP353(-))=8.61 (±0.91)×(1000/T)-23.08 (±3.18); ln HLC (t-OP)=9.03 (±1.40)×(1000/T)-24.83 (±4.86); ln HLC (γ-HCH)=6.17 (±1.08)×(1000/T)-14.28 (±3.75). The derived enthalpies of solvation for NP353(+), NP353(-), t-OP and γ-HCH are -72.6±7.9, -71.6±7.6, -75.1±11.5 and -51.3±9.0 kJ mol-1, respectively. The HLC measurements of γ-HCH, which was used as reference substance, were in good agreement with literature values and its corresponding derived enthalpy of solvation agrees well to the previous values reported in the literature. A reassessment of the air/water gas exchange based on experimentally derived HLC was made for the nonylphenol (NP) in the Lower Hudson River estuary (New York/New Jersey, USA) that was previously reported by Van Ry. A net atmospheric deposition was calculated for the gas exchange of NP in the Lower Bay (Ffw=0.13), and it nearly reaches the condition of equilibrium in the Upper Bay (Ffw=0.46).

Adsorption of n-hexane and intermediate molecular weight aromatic hydrocarbons on LaY zeolite

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ruthven, D.M.; Kaul, B.K.

Experimental equilibrium isotherms, Henry`s law constants, and heats of sorption are reported for n-hexane, benzene, toluene, p-xylene, mesitylene, naphthalene, trimethylbenzene (TMP), and hexamethylbenzene (HMB) in La-exchanged zeolite Y (Si/Al = 1.8). Henry`s law constants and energies of adsorption are substantially smaller than those for NaX zeolite, reflecting the absence of accessible cations in LaY. These data provide a basis for the estimation of adsorbed phase concentrations of the relevant hydrocarbons on REY cracking catalysts under reaction conditions.

Temperature dependencies of Henry’s law constants for different plant sesquiterpenes

PubMed Central

Copolovici, Lucian; Niinemets, Ülo

2018-01-01

Sesquiterpenes are plant-produced hydrocarbons with important ecological functions in plant-to-plant and plant-to-insect communication, but due to their high reactivity they can also play a significant role in atmospheric chemistry. So far, there is little information of gas/liquid phase partition coefficients (Henry’s law constants) and their temperature dependencies for sesquiterpenes, but this information is needed for quantitative simulation of the release of sesquiterpenes from plants and modeling atmospheric reactions in different phases. In this study, we estimated Henry’s law constants (Hpc) and their temperature responses for 12 key plant sesquiterpenes with varying structure (aliphatic, mono-, bi- and tricyclic sesquiterpenes). At 25 °C, Henry’s law constants varied 1.4-fold among different sesquiterpenes, and the values were within the range previously observed for monocyclic monoterpenes. Hpc of sesquiterpenes exhibited a high rate of increase, on average ca. 1.5-fold with a 10 °C increase in temperature (Q10). The values of Q10 varied 1.2-fold among different sesquiterpenes. Overall, these data demonstrate moderately high variation in Hpc values and Hpc temperature responses among different sesquiterpenes. We argue that these variations can importantly alter the emission kinetics of sesquiterpenes from plants. PMID:26291755

Thermodynamic constraints on a varying cosmological-constant-like term from the holographic equipartition law with a power-law corrected entropy

NASA Astrophysics Data System (ADS)

Komatsu, Nobuyoshi

2017-11-01

A power-law corrected entropy based on a quantum entanglement is considered to be a viable black-hole entropy. In this study, as an alternative to Bekenstein-Hawking entropy, a power-law corrected entropy is applied to Padmanabhan's holographic equipartition law to thermodynamically examine an extra driving term in the cosmological equations for a flat Friedmann-Robertson-Walker universe at late times. Deviations from the Bekenstein-Hawking entropy generate an extra driving term (proportional to the α th power of the Hubble parameter, where α is a dimensionless constant for the power-law correction) in the acceleration equation, which can be derived from the holographic equipartition law. Interestingly, the value of the extra driving term in the present model is constrained by the second law of thermodynamics. From the thermodynamic constraint, the order of the driving term is found to be consistent with the order of the cosmological constant measured by observations. In addition, the driving term tends to be constantlike when α is small, i.e., when the deviation from the Bekenstein-Hawking entropy is small.

In-cloud multiphase behaviour of acetone in the troposphere: gas uptake, Henry's law equilibrium and aqueous phase photooxidation.

PubMed

Poulain, Laurent; Katrib, Yasmine; Isikli, Estelle; Liu, Yao; Wortham, Henri; Mirabel, Philippe; Le Calvé, Stéphane; Monod, Anne

2010-09-01

Acetone is ubiquitous in the troposphere. Several papers have focused in the past on its gas phase reactivity and its impact on tropospheric chemistry. However, acetone is also present in atmospheric water droplets where its behaviour is still relatively unknown. In this work, we present its gas/aqueous phase transfer and its aqueous phase photooxidation. The uptake coefficient of acetone on water droplets was measured between 268 and 281K (γ=0.7 x 10(-2)-1.4 x 10(-2)), using the droplet train technique coupled to a mass spectrometer. The mass accommodation coefficient α (derived from γ) was found in the range (1.0-3.0±0.25) x 10(-2). Henry's law constant of acetone was directly measured between 283 and 298K using a dynamic equilibrium system (H((298K))=(29±5)Matm(-1)), with the Van't Hoff expression lnH(T)=(5100±1100)/T-(13.4±3.9). A recommended value of H was suggested according to comparison with literature. The OH-oxidation of acetone in the aqueous phase was carried out at 298K, under two different pH conditions: at pH=2, and under unbuffered conditions. In both cases, the formation of methylglyoxal, formaldehyde, hydroxyacetone, acetic acid/acetate and formic acid/formate was observed. The formation of small amounts of four hydroperoxides was also detected, and one of them was identified as peroxyacetic acid. A drastic effect of pH was observed on the yields of formaldehyde, one hydroperoxide, and, (to a lesser extent) acetic acid/acetate. Based on the experimental observations, a chemical mechanism of OH-oxidation of acetone in the aqueous phase was proposed and discussed. Atmospheric implications of these findings were finally discussed. Copyright © 2010 Elsevier Ltd. All rights reserved.

Obituary: Henry Emil Kandrup, 1955-2003

NASA Astrophysics Data System (ADS)

Merritt, David; Gottesman, Stephen T.

2004-12-01

Henry Emil Kandrup died on 18 October 2003 at his home in Gainesville Florida. Henry was a theoretical astrophysicist specializing in the application of chaotic dynamics to stellar systems. At the time of his death, Henry was a Professor at the University of Florida where he had taught for 13 years. Henry was born in Manhasset, New York on July 24, 1955 and spent most of his childhood in Great Neck. His parents, Jytte and Fred, were immigrants from Denmark where his father had worked as a silver smith. Henry was a precocious child, skipping both third and fifth grades. With the help of Sidney Spivack, a professor of sociology at Columbia University, his parents enrolled Henry in the Brooks Preparatory School in Andover, Massachusetts. After graduating at age 16, Henry enrolled at Cornell, transferring to Princeton the following year. Henry's parents adored their only child and worked hard to provide him with intellectual opportunities. Henry became an accomplished musician (organ, piano, French horn) and linguist (English, Danish, German) and was a passionate devotee of opera and ballet. Henry received his PhD in 1980 from the University of Chicago, where his thesis advisor was James Ipser. He taught at Oakland University in Michigan and Syracuse University in New York before coming to the University of Florida in 1990. Henry was sui generis. He shunned conventionality in his personal appearance and in his public demeanor, and always chose forthrightness and candor over polite silence. But to those of us who knew Henry well, his bluntness was a reflection of his intellectual consistency. Henry always said exactly what he thought, both in his published work and his public presentations, and never compromised himself for the sake of appearances. Nothing that he said or wrote was less than fully thought out. Henry's PhD thesis was entitled "Stochastic Problems in Stellar Dynamics," and most of his subsequent research was in this field. Motion in stellar systems can be

Henry (Hank) J. Moore (1928-1998)

NASA Astrophysics Data System (ADS)

Thompson, Thomas W.

Henry (Hank) J. Moore, a member of the AGU Planetary Sciences section, died of a heart attack on September 21, 1998. He was in Utah while on a family trip to visit his daughter. His 70th birthday occurred just 3 weeks before his death. Henry, who was born in Albuquerque, New Mexico, took great pride in having found and visited the small town of Albuquerque in the Extremadura region of Spain, noting the geologic similarities between that part of Spain and his birthplace in America.Henry, known for his contributions to the Apollo,Viking, Magellan, and Mars Pathfinder missions, attributed his career to a chance encounter with Gene Shoemaker in 1960. Henry was completing his Ph.D. work in geology at Stanford University and Gene obviously had spotted Henry's keen analytical mind. I suspect this pivotal meeting was far from a chance encounter.

Henry Gray's Anatomy.

PubMed

Pearce, J M S

2009-04-01

Little is generally known of Henry Gray, the author of Gray's Anatomy, and even less of his colleague Henry Vandyke Carter, who played a vital role in the dissections and illustrations leading to the production of the first volume in 1859. This essay attempts to sketch briefly the salient, know aspects of these two men and their divergent careers. It traces succinctly the subsequent fate of the unique anatomy book that has influenced and instructed almost every student of medicine. (c) 2009 Wiley-Liss, Inc.

Recommended Henry’s Law Constants for Non-Groundwater Pathways Models in GoldSim

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dyer, J.

This memorandum documents the source and numerical value of Henry’s law constants for volatile radionuclides of interest used in the non-groundwater (air and radon) pathways models for the 2018 E-Area Performance Assessment.

Application of the two-film model to the volatilization of acetone and t-butyl alcohol from water as a function of temperature

USGS Publications Warehouse

Rathbun, R.E.; Tai, D.Y.

1988-01-01

The two-film model is often used to describe the volatilization of organic substances from water. This model assumes uniformly mixed water and air phases separated by thin films of water and air in which mass transfer is by molecular diffusion. Mass-transfer coefficients for the films, commonly called film coefficients, are related through the Henry's law constant and the model equation to the overall mass-transfer coefficient for volatilization. The films are modeled as two resistances in series, resulting in additive resistances. The two-film model and the concept of additivity of resistances were applied to experimental data for acetone and t-butyl alcohol. Overall mass-transfer coefficients for the volatilization of acetone and t-butyl alcohol from water were measured in the laboratory in a stirred constant-temperature bath. Measurements were completed for six water temperatures, each at three water mixing conditions. Wind-speed was constant at about 0.1 meter per second for all experiments. Oxygen absorption coefficients were measured simultaneously with the measurement of the acetone and t-butyl alcohol mass-transfer coefficients. Gas-film coefficients for acetone, t-butyl alcohol, and water were determined by measuring the volatilization fluxes of the pure substances over a range of temperatures. Henry's law constants were estimated from data from the literature. The combination of high resistance in the gas film for solutes with low values of the Henry's law constants has not been studied previously. Calculation of the liquid-film coefficients for acetone and t-butyl alcohol from measured overall mass-transfer and gas-film coefficients, estimated Henry's law constants, and the two-film model equation resulted in physically unrealistic, negative liquid-film coefficients for most of the experiments at the medium and high water mixing conditions. An analysis of the two-film model equation showed that when the percentage resistance in the gas film is large and

Henri Poincaré: Death centenary (1854-1912)

NASA Astrophysics Data System (ADS)

Heinzmann, Gerhard; Villani, Cédric

2014-08-01

The year 2012 marked the centenary of the death of Henri Poincaré (Nancy, 1854-Paris, 1912), and through the agency of the Henri-Poincaré Institute in Paris, the Henri-Poincaré Archives in Nancy and The London Mathematical Society, brought with it several exhibitions and meetings commemorating one of the greatest minds in contemporary times. Often referred to as the last polymath, Poincaré embraced multiple branches of mathematics, theoretical physics and celestial mechanics, and made significant contributions to philosophy of science (Heinzmann & Stump, Henri Poincaré, 2013). He wrote 25 textbooks and monographs, 500-plus articles, and was deeply involved in the organization and administration of science at both the national and international levels.1

The solubility of the noble gases He, Ne, Ar, Kr, and Xe in water up to the critical point

USGS Publications Warehouse

Potter, R.W.; Clynne, M.A.

1978-01-01

The solubility of the noble gases Ar, He, Ne, Kr, and Xe in pure water was measured from 298 to 561??K. These data in turn were extrapolated to the critical point of water, thus providing a complete set of Henry's law constants from 274 to 647??K when combined with the existing literature data. Equations describing the behavior of the Henry's law constants over this temperature range are also given. The data do not confirm extrapolations of empirical correlations based on low-temperature solubility data. ?? 1978 Plenum Publishing Corporation.

Solubility and diffusivity of nitrous oxide in ternary mixtures of water, monoethanolamine, and N-methyldiethanolamine and solution densities and viscosities

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hagewiesche, D.P.; Ashour, S.S.; Sandall, O.C.

1995-05-01

Recently, several researchers have suggested using aqueous mixtures of small amounts of monoethanolamine and much larger amounts of N-methyldiethanolamine for the absorption of CO{sub 2} and for the selective removal of H{sub 2}S from gas streams of mixtures of CO{sub 2} and H{sub 2}S. The densities and viscosities of aqueous N-methyldiethanolamine/monoethanolamine (MDEA/MEA) blends containing 30 and 40 mass % total amine with MEA concentrations of 5, 10, and 15 mass % of the total amine concentration were measured at temperatures of 303, 313, and 323 K. The diffusion coefficients and Henry`s law constants of N{sub 2}O in these solutions weremore » also measured and were used to estimate the diffusion coefficients and Henry`s law constants of CO{sub 2} in these solutions according to the N{sub 2}O/CO{sub 2} analogy technique.« less

Henry VIII, McLeod syndrome and Jacquetta's curse.

PubMed

Stride, P; Lopes Floro, K

2013-01-01

The mental decline of King Henry VIII from being a jovial, charismatic and athletic young man into an increasingly paranoid, brutal tyrant in later life, ever more concerned at his lack of one or more male heirs, has attracted many medical diagnostic theories. Previous hypotheses have included diabetes, syphilis and hypothyroidism, among others. However, these inadequately explain Henry's failure to produce a male heir, despite multiple pairings. The latest postulated diagnoses for Henry are the coexistence of both Kell blood group antigenicity (possibly inherited from Jacquetta Woodville, Henry's maternal great grandmother) causing related impaired fertility, and McLeod syndrome, causing psychotic changes. As the mutated McLeod protein of the syndrome significantly reduces the expression, effectively inactivating the Kell antigen, we critically review this theory, examining in detail the pathophysiology of these conditions and assessing the genealogy of Henry VIII and its effect in subsequent generations.

Thermodynamic models for vapor-liquid equilibria of nitrogen + oxygen + carbon dioxide at low temperatures

NASA Astrophysics Data System (ADS)

Vrabec, Jadran; Kedia, Gaurav Kumar; Buchhauser, Ulrich; Meyer-Pittroff, Roland; Hasse, Hans

2009-02-01

For the design and optimization of CO 2 recovery from alcoholic fermentation processes by distillation, models for vapor-liquid equilibria (VLE) are needed. Two such thermodynamic models, the Peng-Robinson equation of state (EOS) and a model based on Henry's law constants, are proposed for the ternary mixture N 2 + O 2 + CO 2. Pure substance parameters of the Peng-Robinson EOS are taken from the literature, whereas the binary parameters of the Van der Waals one-fluid mixing rule are adjusted to experimental binary VLE data. The Peng-Robinson EOS describes both binary and ternary experimental data well, except at high pressures approaching the critical region. A molecular model is validated by simulation using binary and ternary experimental VLE data. On the basis of this model, the Henry's law constants of N 2 and O 2 in CO 2 are predicted by molecular simulation. An easy-to-use thermodynamic model, based on those Henry's law constants, is developed to reliably describe the VLE in the CO 2-rich region.

John Henry--The Steel Driving Man

ERIC Educational Resources Information Center

Murphy, David E.; Gulley, Laura L.

2005-01-01

The story of John Henry provided the setting for sixth-grade class to participate in a John Henry Day of mathematics experiments. The students collected data from experiments where students competed against machines and technology. The student analyzed the data by comparing two box plots, a box plot of human data, and a box plot of machine or…

Joseph Henry's Conception of Scientific Knowledge

NASA Astrophysics Data System (ADS)

Theerman, Paul

1997-04-01

Joseph Henry, America's premier physicist and physics teacher in the mid-nineteenth century, had decided views of scientific knowledge. These were expressed in two ways. First of all, scientific knowledge led to moral betterment. Thus the study of science was a morally good thing. This was not only because it led to the contemplation of God's creation, which was a standard reason justifying the study of science dating from the Scientific Revolution and even earlier. More importantly, the study of science itself was a moral discipline, imparting to scientists the habits and virtues of truthfulness, respect for others, care and diligence, and the discernment of meaningful patterns from experience. The moral ideals of science were expressed most strongly in Henry's upholding the international "Republic of Science"; conversely, cheapening science was a sign of moral failure. Second, for Henry and his generation, science provided a path to sure truth, separate from falsehood of both the politics and the quackery that characterized mid-century public life. Henry promoted this in his championing of the Smithsonian Institution a scientific establishment, against the ideas of others who wanted to make it a literary establishment or a training school for teachers. For Henry, the Smithsonian's scientific reputation would be established by relying on careful peer review in its publications, and supporting established scientists to write authoritative popular works. The purpose of both these activities was to raise the profile of science in the United States and further establish science and the scientific method as a guide to public life.

A Unified Kinetics and Equilibrium Experiment: Rate Law, Activation Energy, and Equilibrium Constant for the Dissociation of Ferroin

ERIC Educational Resources Information Center

Sattar, Simeen

2011-01-01

Tris(1,10-phenanthroline)iron(II) is the basis of a suite of four experiments spanning 5 weeks. Students determine the rate law, activation energy, and equilibrium constant for the dissociation of the complex ion in acid solution and base dissociation constant for phenanthroline. The focus on one chemical system simplifies a daunting set of…

The Don Henry Story. Teaching with Documents.

ERIC Educational Resources Information Center

National Archives and Records Administration, Washington, DC.

Don Henry was a student at the University of Kansas (Lawrence, Kansas) who experienced a profound political change during his years on campus. Henry became a leader in radical campus organizations, volunteered to fight in the Spanish Civil War with the Lincoln Brigade, and died on the battlefield in Aragon (Spain) in September 1937. An article in…

Effect of Applied Stress, Thermal Environment and Water in Epoxy Resins.

DTIC Science & Technology

1980-12-01

reported to be represented by phenomenological power law functions of the Relative Humidity with exponents ranging from I to 2 or higher values...combination of a Henry’s law dis- solved term and a Langmuir "preexisting hole filling" term in accordance with the Dual Mode Sorptiori Theory (28,29) * -k...34" C’b() a k( 1a + "() (2) where .kdis the Henry’s law constant for dissolved .species, a is the ex- ternal activity and C’ho and b the Langmuir

Experimental measurements of vapor-liquid equilibria of the H2O + CO2 + CH4 ternary system

USGS Publications Warehouse

Qin, J.; Rosenbauer, R.J.; Duan, Zhenhao

2008-01-01

Reported are the experimental measurements on vapor-liquid equilibria in the H2O + CO2 + CH4 ternary system at temperatures from (324 to 375) K and pressures from (10 to 50) MPa. The results indicate that the CH4 solubility in the ternary mixture is about 10 % to 40 % more than that calculated by interpolation from the Henry's law constants of the binary system, H2O + CH4, and the solubility of CO2 is 6 % to 20 % more than what is calculated by the interpolation from the Henry's law constants of the binary mixture, H 2O + CO2. ?? 2008 American Chemical Society.

Biodegradation testing of chemicals with high Henry's constants - Separating mass and effective concentration reveals higher rate constants.

PubMed

Birch, Heidi; Andersen, Henrik R; Comber, Mike; Mayer, Philipp

2017-05-01

During simulation-type biodegradation tests, volatile chemicals will continuously partition between water phase and headspace. This study addressed how (1) this partitioning affects test results and (2) can be accounted for by combining equilibrium partition and dynamic biodegradation models. An aqueous mixture of 9 (semi)volatile chemicals was first generated using passive dosing and then diluted with environmental surface water producing concentrations in the ng/L to μg/L range. After incubation for 2 h to 4 weeks, automated Headspace Solid Phase Microextraction (HS-SPME) was applied directly on the test systems to measure substrate depletion by biodegradation relatively to abiotic controls. HS-SPME was also applied to determine air to water partitioning ratios. Biodegradation rate constants relating to the chemical in the water phase, k water , were generally a factor 1 to 11 times higher than biodegradation rate constants relating to the total mass of chemical in the test system, k system , with one exceptional factor of 72 times for a long chain alkane. True water phase degradation rate constants were found (i) more appropriate for risk assessment than test system rate constants, (ii) to facilitate extrapolation to other air-water systems and (iii) to be better defined input parameters for aquatic exposure and fate models. Copyright © 2017 Elsevier Ltd. All rights reserved.

[Henri Atlan's levels of ethics and the challenge of the "fourth level"].

PubMed

Aleksandrowicz, Ana Maria Coutinho

2008-01-01

This article presents the ideas on ethics by the contemporary French biophysicist and Spinozist philosopher Henri Atlan, based on his singular epistemological position, in constant transit between naturalistic philosophy (in alliance with cognitive sciences) and his refusal to a natural foundations of ethics. It underlines Atlan's defense of casuistry towards bioethics dilemmas and associates it to his proposal of different levels of ethics. The text introduces a reflection concerning Atlan's ideas about the possible passage between the third and the fourth levels of ethics, stressing its positive impact in individuals and social groups' life quality.

Finding exact constants in a Markov model of Zipfs law generation

NASA Astrophysics Data System (ADS)

Bochkarev, V. V.; Lerner, E. Yu.; Nikiforov, A. A.; Pismenskiy, A. A.

2017-12-01

According to the classical Zipfs law, the word frequency is a power function of the word rank with an exponent -1. The objective of this work is to find multiplicative constant in a Markov model of word generation. Previously, the case of independent letters was mathematically strictly investigated in [Bochkarev V V and Lerner E Yu 2017 International Journal of Mathematics and Mathematical Sciences Article ID 914374]. Unfortunately, the methods used in this paper cannot be generalized in case of Markov chains. The search of the correct formulation of the Markov generalization of this results was performed using experiments with different ergodic matrices of transition probability P. Combinatory technique allowed taking into account all the words with probability of more than e -300 in case of 2 by 2 matrices. It was experimentally proved that the required constant in the limit is equal to the value reciprocal to conditional entropy of matrix row P with weights presenting the elements of the vector π of the stationary distribution of the Markov chain.

Henry Ford Health Systems

Cancer.gov

Henry Ford Health Systems evolved from a hospital into a system delivering care to 2.5 million patients and includes the Cancer Epidemiology, Prevention and Control Program, which focuses on epidemiologic and public health aspects of cancer.

Possible Pasts: Historiography and Legitimation in "Henry VIII."

ERIC Educational Resources Information Center

Kamps, Ivo

1996-01-01

Aims to rehabilitate the reputation of Shakespeare's "Henry VIII" and emphasizes its potential usefulness in the classroom by reconsidering it in the context of Renaissance history writing. Shows how "Henry VIII" can be taught as a commentary on or seen as a continuation of incipient themes in "The Tempest" and…

Change is a Constant.

PubMed

Lubowitz, James H; Provencher, Matthew T; Brand, Jefferson C; Rossi, Michael J; Poehling, Gary G

2015-06-01

In 2015, Henry P. Hackett, Managing Editor, Arthroscopy, retires, and Edward A. Goss, Executive Director, Arthroscopy Association of North America (AANA), retires. Association is a positive constant, in a time of change. With change comes a need for continuing education, research, and sharing of ideas. While the quality of education at AANA and ISAKOS is superior and most relevant, the unique reason to travel and meet is the opportunity to interact with innovative colleagues. Personal interaction best stimulates new ideas to improve patient care, research, and teaching. Through our network, we best create innovation. Copyright © 2015 Arthroscopy Association of North America. Published by Elsevier Inc. All rights reserved.

77 FR 70159 - Knueppel, Henry W.; Notice of Filing

Federal Register 2010, 2011, 2012, 2013, 2014

2012-11-23

... DEPARTMENT OF ENERGY Federal Energy Regulatory Commission [Docket No. ID-7020-000] Knueppel, Henry W.; Notice of Filing Take notice that on November 15, 2012, Henry W. Knueppel submitted for filing, an application for authority to hold interlocking positions, pursuant to section 305(b) of the...

Revisiting Yasinsky and Henry`s benchmark using modern nodal codes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Feltus, M.A.; Becker, M.W.

1995-12-31

The numerical experiments analyzed by Yasinsky and Henry are quite trivial by comparison with today`s standards because they used the finite difference code WIGLE for their benchmark. Also, this problem is a simple slab (one-dimensional) case with no feedback mechanisms. This research attempts to obtain STAR (Ref. 2) and NEM (Ref. 3) code results in order to produce a more modern kinetics benchmark with results comparable WIGLE.

Lagrangian circulation study near Cape Henry, Virginia. [Chesapeake Bay

NASA Technical Reports Server (NTRS)

Johnson, R. E.

1981-01-01

A study of the circulation near Cape Henry, Virginia, was made using surface and seabed drifters and radar tracked surface buoys coupled to subsurface drag plates. Drifter releases were conducted on a line normal to the beach just south of Cape Henry. Surface drifter recoveries were few; wind effects were strongly noted. Seabed drifter recoveries all exhibited onshore motion into Chesapeake Bay. Strong winds also affected seabed recoveries, tending to move them farther before recovery. Buoy trajectories in the vicinity of Cape Henry appeared to be of an irrotational nature, showing a clockwise rotary tide motion. Nearest the cape, the buoy motion elongated to almost parallel depth contours around the cape. Buoy motion under the action of strong winds showed that currents to at least the depth of the drag plates substantially are altered from those of low wind conditions near the Bay mouth. Only partial evidence could be found to support the presence of a clockwise nontidal eddy at Virginia Beach, south of Cape Henry.

DETERMINATION OF HENRY'S LAW CONSTANTS FOR VOCS IN ROOM TEMPERATURE IONIC LIQUIDS

EPA Science Inventory

Ionic liquids (ILs) have been shown to be a newer medium for a wide variety of chemical reactions and are considered as the potential replacements for traditional volatile organic solvents. However, the separation and recovery of organic compounds from ILs has not been systematic...

Uncertain Henry's law constants compromise equilibrium partitioning calculations of atmospheric oxidation products

NASA Astrophysics Data System (ADS)

Wang, Chen; Yuan, Tiange; Wood, Stephen A.; Goss, Kai-Uwe; Li, Jingyi; Ying, Qi; Wania, Frank

2017-06-01

Gas-particle partitioning governs the distribution, removal, and transport of organic compounds in the atmosphere and the formation of secondary organic aerosol (SOA). The large variety of atmospheric species and their wide range of properties make predicting this partitioning equilibrium challenging. Here we expand on earlier work and predict gas-organic and gas-aqueous phase partitioning coefficients for 3414 atmospherically relevant molecules using COSMOtherm, SPARC Performs Automated Reasoning in Chemistry (SPARC), and poly-parameter linear free-energy relationships. The Master Chemical Mechanism generated the structures by oxidizing primary emitted volatile organic compounds. Predictions for gas-organic phase partitioning coefficients (KWIOM/G) by different methods are on average within 1 order of magnitude of each other, irrespective of the numbers of functional groups, except for predictions by COSMOtherm and SPARC for compounds with more than three functional groups, which have a slightly higher discrepancy. Discrepancies between predictions of gas-aqueous partitioning (KW/G) are much larger and increase with the number of functional groups in the molecule. In particular, COSMOtherm often predicts much lower KW/G for highly functionalized compounds than the other methods. While the quantum-chemistry-based COSMOtherm accounts for the influence of intra-molecular interactions on conformation, highly functionalized molecules likely fall outside of the applicability domain of the other techniques, which at least in part rely on empirical data for calibration. Further analysis suggests that atmospheric phase distribution calculations are sensitive to the partitioning coefficient estimation method, in particular to the estimated value of KW/G. The large uncertainty in KW/G predictions for highly functionalized organic compounds needs to be resolved to improve the quantitative treatment of SOA formation.

Abiotic Reductive Dechlorination of Tetrachloroethylene and Trichloroethylene in Anaerobic Environments

DTIC Science & Technology

2009-01-15

Measurement of Henry’s Law Constant for methyl tert-butyl ether Using Solid-phase Microextraction. Environmental Toxicology and Chemistry 2001, 20, 1625...and Environmental Microbiology 2005, 71, 3413-3419. Nirmalakhandan, N. N., R. E. Speece. QSAR Model for Predicting Henry’s Constant. Environmental

Dialogue of Differences: The Writing of Henry Holmes Smith.

ERIC Educational Resources Information Center

Bossen, Howard

In addition to surveying the writings of Henry Holmes Smith, this paper explains his importance as a theoretician and practitioner of photography. After a discussion of Smith's ideas on "reading photographs" and his concerns with the ethics of photography, particularly of photojournalism, the essays in the book, "Henry Holmes Smith:…

Australian Family Research Conference Proceedings (Canberra, Australia, November 23-25, 1983). Volume II: Family Law.

ERIC Educational Resources Information Center

Institute of Family Studies, Melbourne (Australia).

Second in a series of seven volumes containing the proceedings of the 1983 Australian Family Research Conference, this publication deals with family law. Papers and authors included are: "Attitudes of Divorced Men and Women to the Family" (Margaret Harrison), "Dispute Resolution in Australian Family Law" (Henry Finlay),…

Steering Law Controlling the Constant Speeds of Control Moment Gyros

NASA Astrophysics Data System (ADS)

KOYASAKO, Y.; TAKAHASHI, M.

2016-09-01

To enable the agile control of satellites, using control moment gyros (CMGs) has become increasingly necessary because of their ability to generate large amounts of torque. However, CMGs have a singularity problem whereby the torque by the CMGs degenerates from three dimensions to two dimensions, affecting spacecraft attitude control performance. This study proposes a new steering control law for CMGs by controlling the constant speed of a CMG. The proposed method enables agile attitude changes, according to the required task, by managing the total angular momentum of the CMGs by considering the distance to external singularities. In the proposed method, the total angular momentum is biased in a specific direction and the angular momentum envelope is extended. The design method can increase the net angular momentum of CMGs which can be exchanged with the satellite. The effectiveness of the proposed method is demonstrated by numerical simulations.

[Hypospadia and infertility of Henry II of France (1519-1559)].

PubMed

Hatzinger, M; Al-Shajlawi, S; Sohn, M

2014-03-01

Henry II (1519-1559) of France was the second son of Francis I (1494-1547) and Claude de France (1498-1524) born in 1519 in St. Germain-en-Laye. After his older brother's and his father's death in 1547, he was anointed the French king in Reims. In 1533 already, as a 14-year-old boy, for reasons of state, he was married to the same aged Catherine de Medici (1519-1589), as her uncle was Pope Clement VII (1478-1534). The marriage remained childless for 11 years since Henry, due to a distinct hypospadia and a completely sexually inexperienced wife was unable to conceive children with her. His existing liaison to Diane de Poitiers (1499-1566) - a 19-year-older maid of honor of his father Francis I from 1537 until his death - influenced his sexual life immensely.The blame for the childless marriage was placed primarily on his wife, as Henry had become father of an illegitimate daughter with a mistress. Catherine then underwent all possible medical and alchemical procedures to finally give birth to the hoped Dauphin. Ironically, her rival for the favor of her husband, Diane de Poitiers was one of her greatest allies. She made clear that the cause lay with Henry and not with his wife. This was confirmed by the added solid physician Jean Fernel (1497-1558). His treatment of Henry and the simultaneous training of the unexperienced Catherine by Diane de Poitiers led to success.The result was the birth of Francis II (1544-1560) in 1544, the first of 10 children in 12 years. Thus, the dynasty was saved. After the death of Henry in a tragic tournament accident in 1559, three of his sons became kings of France. But the line of Valois remained without further descendants and was continued by Henry IV, the first Bourbon king in 1589.

UAS stealth: target pursuit at constant distance using a bio-inspired motion camouflage guidance law.

PubMed

Strydom, Reuben; Srinivasan, Mandyam V

2017-09-21

The aim of this study is to derive a guidance law by which an unmanned aerial system(s) (UAS) can pursue a moving target at a constant distance, while concealing its own motion. We derive a closed-form solution for the trajectory of the UAS by imposing two key constraints: (1) the shadower moves in such a way as to be perceived as a stationary object by the shadowee, and (2) the distance between the shadower and shadowee is kept constant. Additionally, the theory presented in this paper considers constraints on the maximum achievable speed and acceleration of the shadower. Our theory is tested through Matlab simulations, which validate the camouflage strategy for both 2D and 3D conditions. Furthermore, experiments using a realistic vision-based implementation are conducted in a virtual environment, where the results demonstrate that even with noisy state information it is possible to remain well camouflaged using the constant distance motion camouflage technique.

Teaching Students about the Environment with Henry David Thoreau

ERIC Educational Resources Information Center

Curriculum Review, 2008

2008-01-01

"Walden: The Ballad of Thoreau" is a two-act four-character play about the final two days writer Henry David Thoreau spent in his cabin before leaving Walden Pond. Teachers can use this play to teach about preserving the earth to students. This article presents a brief synopsis of the play and a brief biography of Henry David Thoreau.

Henry Gray, plagiarist.

PubMed

Richardson, Ruth

2016-03-01

The first edition of Anatomy Descriptive and Surgical (1858) was greeted with accolades, but also provoked serious controversy concerning Henry Gray's failure to acknowledge the work of earlier anatomists. A review in the Medical Times (1859) accused Gray of intellectual theft. The journal took the unusual step of substantiating its indictment by publishing twenty parallel texts from Gray and from a pre-existing textbook, Quain's Anatomy. At the recent "Vesalius Continuum" conference in Zakynthos, Greece (2014) Professor Brion Benninger disputed the theft by announcing from the floor the results of a computer analysis of both texts, which he reported exonerated Gray by revealing no evidence of plagiarism. The analysis has not been forthcoming, however, despite requests. Here the historian of Gray's Anatomy supplements the argument set out in the Medical Times 150 years ago with data suggesting unwelcome personality traits in Henry Gray, and demonstrating the utility of others' work to his professional advancement. Fair dealing in the world of anatomy and indeed the genuineness of the lustre of medical fame are important matters, but whether quantitative evidence has anything to add to the discussion concerning Gray's probity can be assessed only if Benninger makes public his computer analysis. © 2015 Wiley Periodicals, Inc.

Henri Poincaré and the principle of relativity

NASA Astrophysics Data System (ADS)

Messager, Valérie; Gilmore, Robert; Letellier, Christophe

2012-09-01

Often considered as the last 'encyclopedist', Henri Poincaré died one hundred years ago. If he was a prominent man in 1900 French Society, his heritage is not so clearly recognised, particularly in France. Among his too often misunderstood works is his contribution to the theory of relativity, mainly because it is almost never presented within Poincaré's general approach to science, including his philosophical writings. Our aim is therefore to provide an historical account of the main steps (experimental as well as theoretical) which led Poincaré to contribute to the theory of relativity. Starting from the optical experiments which led to the inconsistency of the classical (Galilean) composition law for velocities to explain light propagation, we introduce the FitzGerald and Lorentz contraction which was viewed as the 'sole hypothesis' to explain the Michelson and Morley experiment. We then show that Poincaré's contribution starts with a discussion of the principles governing the mechanics and was built step by step up to express in all its generality the principle of relativity. Poincaré thus showed the invariance of the Maxwell equations under the Lorentz transformation. In doing so, he also discovered the right composition law for velocities. Poincaré's approach to philosophy is detailed to help the reader to understand what a theory meant to him.

[The pharmacist and deputy Henri Schmidt, the law voted in 1913 and said «for three years» and the position of mobilized pharmacists at the beginning of First World War].

PubMed

Labrude, Pierre

2017-03-01

Henri Schmidt was, with his fellow the senator Paul Cazeneuve, the main defender of the mention of pharmacists and pharmacy students in the articles of the law voted in 1913 for the recruitment of the army. After the description of their interventions to attain this end, and a short biography of these two politicians, the paper explains the activities of the pharmaceutical parliamentary group, during the early years of the war, in view to obtain the admittance in the medical corps of the pharmacists and students unprovided of rank, for the new creation of «auxiliary pharmacists», for the appointment as soon as possible of the maximum number of colleagues at this rank, and then for their promotion to the rank of «aide-major», resolution that appeared more difficult to obtain.

Resurrecting the Power-law, Intermediate, and Logamediate Inflations in the DBI Scenario with Constant Sound Speed

NASA Astrophysics Data System (ADS)

Amani, Roonak; Rezazadeh, Kazem; Abdolmaleki, Asrin; Karami, Kayoomars

2018-02-01

We investigate the power-law, intermediate, and logamediate inflationary models in the framework of DBI non-canonical scalar field with constant sound speed. In the DBI setting, we first represent the power spectrum of both scalar density and tensor gravitational perturbations. Then, we derive different inflationary observables including the scalar spectral index n s , the running of the scalar spectral index {{dn}}s/d{ln}k, and the tensor-to-scalar ratio r. We show that the 95% CL constraint of the Planck 2015 T + E data on the non-Gaussianity parameter {f}{NL}{DBI} leads to the sound speed bound {c}s≥slant 0.087 in the DBI inflation. Moreover, our results imply that, although the predictions of the power-law, intermediate, and logamediate inflations in the standard canonical framework (c s = 1) are not consistent with the Planck 2015 data, in the DBI scenario with constant sound speed {c}s< 1, the result of the r-{n}s diagram for these models can lie inside the 68% CL region favored by Planck 2015 TT,TE,EE+lowP data. We also specify the parameter space of the power-law, intermediate, and logamediate inflations for which our models are compatible with the 68% or 95% CL regions of the Planck 2015 TT,TE,EE+lowP data. Using the allowed ranges of the parameter space of the intermediate and logamediate inflationary models, we estimate the running of the scalar spectral index and find that it is compatible with the 95% CL constraint from the Planck 2015 TT,TE,EE+lowP data.

75 FR 21288 - Henry Gas Storage LLC; Notice of Application

Federal Register 2010, 2011, 2012, 2013, 2014

2010-04-23

... DEPARTMENT OF ENERGY Federal Energy Regulatory Commission [Docket No. CP10-125-000] Henry Gas Storage LLC; Notice of Application April 16, 2010. Take notice that on April 5, 2010, Henry Gas Storage... developing the Cote Blanche Island salt dome for natural gas storage in St. Mary Parish, Louisiana, all as...

Equivalent refractive-index structure constant of non-Kolmogorov turbulence.

PubMed

Li, Yujie; Zhu, Wenyue; Wu, Xiaoqing; Rao, Ruizhong

2015-09-07

The relationship between the non-Kolmogorov refractive-index structure constant and the Kolmogorov refractive-index structure constant is derived by using the refractive-index structure function and the variance of refractive-index fluctuations. It shows that the non-Kolmogorov structure constant is proportional to the Kolmogorov structure constant and the scaling factor depends on the outer scale and the spectral power law. For a fixed Kolmogorov structure constant, the non-Kolmogorov structure constant increases with a increasing outer scale for the power law less than 11/3, the trend is opposite for the power law greater than 11/3. This equivalent relation provides a way of obtaining the non-Kolmogorov structure constant by using the Kolmogorov structure constant.

Salting Constants of Small Organic Molecules in Aerosol-Relevant Salts and Application to Aerosol Formation in the Southeastern United States

NASA Astrophysics Data System (ADS)

Waxman, E.; Carlton, A. M. G.; Ziemann, P. J.; Volkamer, R. M.

2014-12-01

Secondary organic aerosol (SOA) formation from small water-soluble molecules such as glyoxal and methyl glyoxal is a topic of emerging interest. Results from recent field campaigns, e.g. Waxman et al. (2013, GRL) and Knote et al. (2014, ACP), show that these molecules can form significant SOA mass as a result of 'salting-in'. Salting-in happens when a molecule's solubility increases with salt concentration and salting-out is the reverse. Salting effects modify the solubility exponentially with increasing salt concentration, and thus the effective Henry's law constant can strongly modify partitioning, and multiphase chemical reaction rates in aerosol water. Moreover, the solubility in aerosol water cannot easily inferred based on the solubility in cloud water, as the salting effects could change the solubility by a factor of 104 or more. In this work, we have devised and applied a novel experimental setup to measure salting constants using an ion trap mass spectrometer. We focus on small, water soluble molecules like methyl glyoxal and similar compounds and measure salting constants for aerosol-relevant salts including ammonium sulfate, ammonium nitrate, and sodium chloride. The Setschenow salting-constant values are then used to parameterize the effects of salting in CMAQ. We present a series of sensitivity studies of the effects that inorganic aerosols have on the SOA formation from small soluble molecules in the southeastern United States.

The Rice University Press Initiative: An Interview with Charles Henry

ERIC Educational Resources Information Center

Trevitte, Chad; Henry, Charles

2007-01-01

In this interview Charles Henry, publisher of the Rice University Press (RUP), discusses RUP's rebirth as a fully digital university press. Henry addresses the circumstances that led to this decision, and he further outlines the RUP business model whereby the press will publish its own titles--both digitally and in print-on-demand--while…

Air-Liquid Partition Coefficient for a Diverse Set of Organic Compounds: Henry’s Law Constant in Water and Hexadecane

EPA Science Inventory

The SPARC vapor pressure and activity coefficient models were coupled to estimate Henry’s Law Constant (HLC) in water and in hexadecane for a wide range of non-polar and polar solute organic compounds without modification to/or additional parameterization of the vapor pressure or...

West Harlem Walk (Hudson River Valley Greenway) beneath Henry Hudson ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

West Harlem Walk (Hudson River Valley Greenway) beneath Henry Hudson Parkway (HHP) Viaduct at West 155th Street vicinity, with Palisades, George Washington Bridge, and Little Red Lighthouse (visible to left of bridge tower) in background, looking northeast. - Henry Hudson Parkway, Extending 11.2 miles from West 72nd Street to Bronx-Westchester border, New York County, NY

Henry's voices: the representation of auditory verbal hallucinations in an autobiographical narrative.

PubMed

Demjén, Zsófia; Semino, Elena

2015-06-01

The book Henry's Demons (2011) recounts the events surrounding Henry Cockburn's diagnosis of schizophrenia from the alternating perspectives of Henry himself and his father Patrick. In this paper, we present a detailed linguistic analysis of Henry's first-person accounts of experiences that could be described as auditory verbal hallucinations. We first provide a typology of Henry's voices, taking into account who or what is presented as speaking, what kinds of utterances they produce and any salient stylistic features of these utterances. We then discuss the linguistically distinctive ways in which Henry represents these voices in his narrative. We focus on the use of Direct Speech as opposed to other forms of speech presentation, the use of the sensory verbs hear and feel and the use of 'non-factive' expressions such as I thought and as if. We show how different linguistic representations may suggest phenomenological differences between the experience of hallucinatory voices and the perception of voices that other people can also hear. We, therefore, propose that linguistic analysis is ideally placed to provide in-depth accounts of the phenomenology of voice hearing and point out the implications of this approach for clinical practice and mental healthcare. Published by the BMJ Publishing Group Limited. For permission to use (where not already granted under a licence) please go to http://group.bmj.com/group/rights-licensing/permissions.

W.E. Henry Symposium compendium: The importance of magnetism in physics and material science

DOE Office of Scientific and Technical Information (OSTI.GOV)

Carwell, H.

This compendium contains papers presented at the W. E. Henry Symposium, The Importance of Magnetism in Physics and Material Science. The one-day symposium was conducted to recognize the achievements of Dr. Warren Elliot Henry as educator, scientist, and inventor in a career spanning almost 70 years. Dr. Henry, who is 88 years old, attended the symposium. Nobel Laureate, Dr. Glenn Seaborg, a friend and colleague for over 40 years, attended the event and shared his personal reminiscences. Dr. Seaborg is Associate Director-At-Large at the Lawrence Berkeley National Laboratory. The Compendium begins with three papers which demonstrate the ongoing importance ofmore » magnetism in physics and material science. Other contributions cover the highlights of Dr. Henry`s career as a researcher, educator, and inventor. Colleagues and former students share insights on the impact of Dr. Henry`s research in the field of magnetism, low temperature physics, and solid state physics; his influence on students as an educator; and his character, intellect and ingenuity, and passion for learning and teaching. They share a glimpse of the environment and times that molded him as a man, and the circumstances under which he made his great achievements despite the many challenges he faced.« less

HENRY'S LAW CONSTANTS AND MICELLAR PARTITIONING OF VOLATILE ORGANIC COMPOUNDS IN SURFACTANT SOLUTIONS

EPA Science Inventory

Partitioning of volatile organic compounds (VOCs) into surfactant micelles affects the apparent vapor-liquid equilibrium of VOCs in surfactant solutions. This partitioning will complicate removal of VOCs from surfactant solutions by standard separation processes. Headspace expe...

15. Historic American Buildings Survey. Plan of Fort McHenry, by ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

15. Historic American Buildings Survey. Plan of Fort McHenry, by William Tell Poussin, 1819. National Archives, Records of the War Department, Cartographic Section, Record Group 77, drawer 51, sheet 2. - Fort McHenry National Monument & Historic Shrine, East Fort Avenue at Whetstone Point, Baltimore, Independent City, MD

BOOK REVIEW: Joseph Henry: The Rise of an American Scientist

NASA Astrophysics Data System (ADS)

Crawford, Elspeth

1998-09-01

Albert Moyer has clearly done his research into the events of Joseph Henry's life. The personal, professional, sociological and scientific aspects have been meticulously detailed throughout and the ordering, as in the chapter headings, is chronological, so that there is some element of each of these aspects in each chapter. This is unfortunately both the strength and the weakness of the biography, as the detail seemed to me to be the most remarkable characteristic of the writing. But, the bigger stories, or the themes, which might have been possible, seemed to get lost. Hence, I found this a book for those who are seriously interested in Joseph Henry; but for those whose interest might be more general, say having an interest in nineteenth century growth of scientific institutions, or wanting to understand the conceptual development of electromagnetism, there seemed to be too much which came from the Henry point of view, rather than locating Henry within his time and context. This is a remark about style, rather than omission of content, as the myriad of details in each paragraph certainly inform the reader about the context. For instance, some sociology of the USA in the nineteenth century could be inferred, say showing how a young man from a modest background might make his way into a professional life, but the information is so particularly a description of Henry's experience that one has to rely on prior knowledge or make assumptions in order to create a sociological perspective. That is, I now know, what happened to Henry, but I do not know if his case was in any sense typical or atypical. Similarly there is information about education in general at that time, and scientific education, research and its publication, as it applied to Henry. The relationships between science in the USA and in Europe have a place, and there is quite a bit of information about the institutions in which Henry worked, particularly Albany Academy, Princeton and the Smithsonian. Henry

Fort McHenry alternative transportation study

DOT National Transportation Integrated Search

2004-06-01

This project assesses transportation management issues at Fort McHenry National Monument and Historic Shrine in the Locust Point area of Baltimore. Goals of the study include mitigating traffic congestion and idling of school or tour buses, encouragi...

HAZARDOUS AIR POLLUTANTS: WET REMOVAL RATES AND MECHANISMS

EPA Science Inventory

Fourteen hazardous organic air pollutants were evaluated for their potentials to be wet deposited by precipitation scavenging. This effort included a survey of solubilities (Henry's Law constants) in the literature, measurement of solubilities of three selected species, developme...

Who was... John Henri Fabre?

PubMed

Malcolm, Alan D B

2002-04-01

The books of Jean Henri Fabre, replete with lively accounts of his observations on nature, inspired generations of children from all over the world. The detail in his study of insects and the entertaining presentation allowed readers to absorb his fascination. Yet, he was a physics teacher by profession and virtually self taught on matters of entomology.

Beer Law Constants and Vapor Pressures of HgI2 over HgI2(s,l)

NASA Technical Reports Server (NTRS)

Su, Ching-Hua; Zhu, Shen; Ramachandran, N.; Burger, A.; Whitaker, Ann F. (Technical Monitor)

2001-01-01

The optical absorption spectra of the vapor phase over HgI2(s,l) were measured for wavelengths between 200 and 600 nm. The spectra show that the sample sublimed congruently into HgI2 with no Hg or I2 absorption spectrum observed. The Beer's Law constants for 15 wavelengths between 200 and 440 nm were determined. From these constants the vapor pressure of H912, P, was established as a function of temperatures for the liquid and the solid Beta-phases. The expressions correspond to the enthalpies of vaporization and sublimation of 15.30 and 20.17 Kcal/mole, respectively, for the liquid and the Beta-phase HgI2. The difference in the enthalpies gives an enthalpy of fusion of 4.87 Kcal/mole and the intersection of the two expressions gives a melting point of 537 K.

Solute and heat transport model of the Henry and Hilleke laboratory experiment

USGS Publications Warehouse

Langevin, C.D.; Dausman, A.M.; Sukop, M.C.

2010-01-01

SEAWAT is a coupled version of MODFLOW and MT3DMS designed to simulate variable-density ground water flow and solute transport. The most recent version of SEAWAT, called SEAWAT Version 4, includes new capabilities to represent simultaneous multispecies solute and heat transport. To test the new features in SEAWAT, the laboratory experiment of Henry and Hilleke (1972) was simulated. Henry and Hilleke used warm fresh water to recharge a large sand-filled glass tank. A cold salt water boundary was represented on one side. Adjustable heating pads were used to heat the bottom and left sides of the tank. In the laboratory experiment, Henry and Hilleke observed both salt water and fresh water flow systems separated by a narrow transition zone. After minor tuning of several input parameters with a parameter estimation program, results from the SEAWAT simulation show good agreement with the experiment. SEAWAT results suggest that heat loss to the room was more than expected by Henry and Hilleke, and that multiple thermal convection cells are the likely cause of the widened transition zone near the hot end of the tank. Other computer programs with similar capabilities may benefit from benchmark testing with the Henry and Hilleke laboratory experiment. Journal Compilation ?? 2009 National Ground Water Association.

Solubilities of Peroxyacetyl Nitrate and Peroxynitrate in Water and Aqueous H(sub 2)SO(sub 4)

NASA Technical Reports Server (NTRS)

Leu, M. T.; Zhang, R.

1998-01-01

In addition, the effective Henry's law constant and the associative enthalpy change of solvation of PNA in water are determined to be 39.95 mol kg^-1 atm^-1 and -69.84 kJ mol^-1 at 298.15K, respectively.

Henry Giroux on Democracy Unsettled: From Critical Pedagogy to the War on Youth--An Interview

ERIC Educational Resources Information Center

Peters, Michael A.

2012-01-01

This interview conducted with Henry Giroux begins by probing Henry's childhood, upbringing and undergraduate years to discover where his sense of social justice took hold. It also questions Henry about his working-class background and the major influences on his thought, including his relationships with Paulo Freire and Howard Zinn. The interview…

Henry’s Law Constant and Overall Mass Transfer Coefficient for Formaldehyde Emission from Small Water Pools under Simulated Indoor Environmental Conditions

EPA Science Inventory

The Henry’s law constant (HLC) and the overall mass transfer coefficient are both important parameters for modeling formaldehyde emissions from aqueous solutions. In this work, the apparent HLCs for aqueous formaldehyde solutions were determined in the concentration range from 0....

The medical life of Henry Norman Bethune

PubMed Central

Deslauriers, Jean; Goulet, Denis

2015-01-01

BACKGROUND: Henry Norman Bethune is one of the most exciting and incredible surgeons that Canada has ever produced. Indeed, he is often characterized as one of the world’s best-known surgeons. He was an innovator and his scientific contributions have stood the test of time. In Canada, he will forever be remembered as a social activist committed to the welfare of the poor and to the reform of the health care system. In the People’s Republic of China, he is idolized and remains the only foreigner to ever become a national hero. OBJECTIVE: To detail the numerous and significant achievements of Henry Norman Bethune in the field of thoracic surgery and as a social activist and describe his heroic war-time actions on the battlefields of both Spain and China. METHOD: Information was gathered through the reading of the numerous publications written about the life and work of Bethune, interviews with knowledgeable people from Canadian and Chinese universities, analysis of Bethune’s own publications, and extensive experience of one of the authors in China. RESULTS: In the social sense, Henry Norman Bethune had a difficult personality, but he was deeply caring about the plight of his patients, especially the poor. As a thoracic surgeon, he could be ingenious, thoughtful and effective but he could also be abrasive, restless and temperamental. His scientific contributions were sound and, at the time, gained worldwide attention. As an activist, he led a crusade to reform the Canadian health care system, demanding free health care for all. His outstanding work during the Spanish Civil War, where he organized the first ever mobile blood transfusion unit, and during the Sino-Japanese war, where he was totally committed to the welfare of both soldiers and civilian population, were deliberate acts of resistance against Fascist onslaught and enthusiasm for the Communist cause. CONCLUSIONS: Henry Norman Bethune was unconventional and a revolutionary, but he was brilliant. He will

46 CFR 7.55 - Cape Henry, VA to Cape Fear, NC.

Code of Federal Regulations, 2010 CFR

2010-10-01

... 46 Shipping 1 2010-10-01 2010-10-01 false Cape Henry, VA to Cape Fear, NC. 7.55 Section 7.55 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY PROCEDURES APPLICABLE TO THE PUBLIC BOUNDARY LINES Atlantic Coast § 7.55 Cape Henry, VA to Cape Fear, NC. (a) A line drawn from Rudee Inlet Jetty Light “2” to...

The "Global" Formulation of Thermodynamics and the First Law: 50 Years On

ERIC Educational Resources Information Center

Gislason, Eric A.; Craig, Norman C.

2011-01-01

Nearly 50 years ago, Henry Bent published his groundbreaking article in this "Journal" introducing the "global" formulation of thermodynamics. In the following years, the global formulation was elaborated by Bent and by one of the present authors. The global formulation of the first law focuses on conservation of energy and the recognition that…

American Chemical Society division of fuel chemistry Henry H. Storch award.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chemistry

American Chemical Society Division of Fuel Chemistry Henry H. Storch Award ... The purpose of the Henry H. Storch Award is to recognize distinguished contributions worldwide to fundamental or engineering research on the chemistry and utilization of all hydrocarbon fuels, with the exception of petroleum. ... The award was established in 1964 by the American Chemical Society Division of Fuel Chemistry and administered by the Division until 1985.

Uptake of Organic Gas Phase Species by 1-Methylnaphthalene

NASA Astrophysics Data System (ADS)

Zhang, H.; Xia, J.; Davidovits, P.; Jayne, J. T.; Kolb, C. E.; Worsnop, D. R.

2002-12-01

Using a droplet train apparatus, the mass accommodation coefficients (α) on 1-methylnapthalene of gas phase m-xylene, ethylbenzene, butylbenzene, α-pinene, γ-terpinene, and 2-methyl-2-hexanol were measured as a function of temperature (265 K to 296 K). 1-methylnapthalene was selected as a surrogate for hydrophobic and aromatic hydrocarbons found in tropospheric aerosols. The mass accommodation coefficients (α) of all the molecules obtained from these measurements exhibit negative temperature dependence. The upper and lower values of α at 265 K and 296 K respectively are: for m-xylene 0.44 and 0.26; for ethylbenzene 0.37 and 0.22; for butylbenzene 0.47 and 0.31; for α-pinene 0.47 and 0.096; for γ-terpinene 0.39 and 0.12; for 2-methyl-2-hexanol 0.44 and 0.26. The uptake measurements also yielded values for the product HDl1/2 for most of the molecules studied (H = Henry's law constant, Dl = liquid phase diffusion coefficient). Using calculated values of Dl the Henry's law constant is obtained, and expressed in the form ln H (M/atm) = -A + B/T. The A and B values for the molecules studied are listed in Table 1. Table 1: A and B values for the Henry's law constant H expressed as ln H (M/atm) = -A + B/T \\ m-xylene: A=7.20, B=4060\\ethylbenzene: A=5.81, B=3660\\butylbenzene: A=16.95, B=7330α-pinene: A=15.69, B=6360\\2-methyl-2-hexanol: A=9.95, B=4760

In the Style of Henry Moore

ERIC Educational Resources Information Center

Hinshaw, Craig

2010-01-01

In this article, the author describes an art project inspired by Henry Moore's sculptures. This project consists of two activities. In the first activity, students select, sand and stain a wood block that would become a base for their plaster sculpture. This activity would keep the students independently engaged (classroom management) while the…

Henry Ward Beecher: A Nation's Tribune.

ERIC Educational Resources Information Center

Chandler, Daniel Ross

Henry Ward Beecher was America's most prominent 19th century liberal preacher and a major spokesperson for New England Transcendentalism. His philosophy integrated four fundamental themes: the creation of a moral code based on the internalization of values and peer group pressures, the establishment of the reform ideal of the impartial nonpartisan…

Transcendentalism and Henry Barnard's "School Architecture"

ERIC Educational Resources Information Center

Rothfork, John

1977-01-01

Sketches the intellectual and sociological climate that led Henry Barnard to advocate Greek Revival architecture for school buildings, takes a look at why this style and its implicit values were popular in the era between 1820-1860, and examines a few of the plans in Barnard's "School Architecture" (1838-48). (Author/RK)

Henri Matisse's "Beasts of the Sea"

ERIC Educational Resources Information Center

Graff, Robert

2010-01-01

Henri Matisse (1869-1954) was a very prolific Impressionist/Post-Impressionist artist whose longevity allowed him to produce many wonderful, brightly colored pieces of art that spanned different styles, movements and media. Elementary-school children love color and appreciate any project that does not require their work to be exact or totally…

Factors affecting the process performance of biofiltration

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kopchynski, D.M.; Farmer, R.W.; Maier, W.J.

1996-11-01

Biofiltration is an emerging biological treatment technology for the removal of airborne VOCs from industrial process waste streams. Removal of air-phase VOCs by biofiltration is accomplished by contacting a process airstream with an active microbial biofilm attached to a solid phase packing. VOCs that partition into the biofilm are aerobically oxidized to the endproducts of water, carbon dioxide and salts. A multiple reactor biofiltration pilot plant test program has been in progress at the University of Minnesota Environmental Engineering Laboratories since 1992. The primary goal of the program is to study factors that affect biofiltration process performance. Initial results ofmore » this test program were reported in a previous conference paper and master`s thesis. This paper presents the results of more recent studies that focus on the effects of: (1) biofilm accumulation (which in turn causes a decrease in biofilter bed porosity and packing bed surface area), (2) rates of nutrient addition, and (3) chemical properties of the target contaminant, on biofiltration removal performance. Removal performance was evaluated by determining biofilter removal capacities and efficiencies for various substrate feeds. The performance parameters were measured under constant contaminant inlet concentrations and under constant temperature. Three VOCs were selected for study and they are: MEK, (methyl ethyl ketone), xylene, and hexane. MEK, xylene, and hexane were chosen because they are representative of widely used industrial solvents and they have significantly different Henry`s law constants relative to each other (the MEK value < Xylene value < Hexane value). Henry`s law constants quantify the partitioning of a chemical between the air and water-biofilm phase and therefore can be used to correlate the effect of chemical properties on biofilter removal capacities. This paper also introduces a new model for the biofiltration process.« less

Environmental Fate Studies on Certain Munition Wastewater Constituents - Literature Review

DTIC Science & Technology

1980-03-01

gram-negative bacteria , actinaycetes, yeasts, and fungi. They found that TNT at 50 Mgtter severely inhibited the growth of these organisms in wost...i , conditions . I Biodegradation ,. Chambers et al. (1963) reported evidence of degradation of 2,4-DNT with phenol-adapted bacteria and 100 mg/liter...coefficient based on organic carbon contentoc H - Henry’s Law constant kA - Hydrolysis rate constant under acidic conditions k.M - Hydrolysis rate constant

Antoine-Henri Jomini: A Bibliographical Survey.

ERIC Educational Resources Information Center

Alger, John I.

Although the writings of Antoine-Henri Jomini influenced military thought during the 19th and 20th centuries, the obscurity of their publishing history has led to misunderstandings of the development and substance of Jomini's thought. This review attempts to (1) point out the continuity of his thought on the conduct of war, and (2) provide an…

Proceedings of the 1990 Annual Meeting of the Association for Education in Journalism and Mass Communication (73rd, Minneapolis, Minnesota, August 1-4, 1990). Part I: Media and Law.

ERIC Educational Resources Information Center

Association for Education in Journalism and Mass Communication.

This section of the proceedings is comprised of 11 papers dealing with the relationship between media and the law. Papers include: "Equal before the Law: Three Media Myths of the American Legal System" (Henry Itkin); "The Role of Senator Albert Gore, Jr. in Satellite/Cable Legislation" (Michael B. Doyle); "The Law of…

Henry Morgenthau's voice in history.

PubMed

Steiner, Pamela

2015-01-01

Henry Morgenthau (1856-1946) distinguished himself as the U.S. Ambassador to the Ottoman Empire, 1913-1916, and as the chairman of the League of Nations Refugee Settlement Commission (RSC) for Greece, 1923-24. I describe aspects of his early life that shaped the man he became, his accomplishments in these two posts, and his feelings about himself over time. At the end I briefly describe his attitude toward a possible Jewish state in Palestine.

HENRY'S LAW CALCULATOR

EPA Science Inventory

On-Site was developed to provide modelers and model reviewers with prepackaged tools ("calculators") for performing site assessment calculations. The philosophy behind OnSite is that the convenience of the prepackaged calculators helps provide consistency for simple calculations,...

Diffusion constant of slowly rotating black three-brane

NASA Astrophysics Data System (ADS)

Amoozad, Z.; Sadeghi, J.

2018-01-01

In this paper, we take the slowly rotating black three-brane background and perturb it by introducing a vector gauge field. We find the components of the gauge field through Maxwell equations and Bianchi identities. Using currents and some ansatz we find Fick's first law at long wavelength regime. An interesting result for this non-trivial supergravity background is that the diffusion constant on the stretched horizon which emerges from Fick's first law is a complex constant. The pure imaginary part of the diffusion constant appears because the black three-brane has angular momentum. By taking the static limit of the corresponding black brane the well known diffusion constant will be recovered. On the other hand, from the point of view of the Fick's second law, we have the dispersion relation ω = - iDq2 and we found a damping of hydrodynamical flow in the holographically dual theory. Existence of imaginary term in the diffusion constant introduces an oscillating propagation of the gauge field in the dual field theory.

An Inverse Square Law Variation for Hubble's Constant

NASA Astrophysics Data System (ADS)

Day, Orville W., Jr.

1999-11-01

The solution to Einstein's gravitational field equations is examined, using a Robertson-Walker metric with positive curvature, when Hubble's parameter, H_0, is taken to be a constant divided by R^2. R is the cosmic scale factor for the universe treated as a three-dimensional hypersphere in a four-dimensional Euclidean space. This solution produces a self-energy of the universe, W^(0)_self, proportional to the square of the total mass, times the universal gravitational constant divided by the cosmic scale factor, R. This result is totally analogous to the self-energy of the electromagnetic field of a charged particle, W^(0)_self = ke^2/2r, where the total charge e is squared, k is the universal electric constant and r is the scale factor, usually identified as the radius of the particle. It is shown that this choice for H0 leads to physically meaningful results for the average mass density and pressure, and a deacceleration parameter q_0=1.

Beer Law Constants and Vapor Pressures of HgI2 over HgI2(s,l)

NASA Technical Reports Server (NTRS)

Su, Ching-Hua; Zhu, Shen; Ramachandran, N.; Burger, A.

2002-01-01

Optical absorption spectra of the vapor phase over HgI2(s,l) were measured at sample temperatures between 349 and 610 K for wavelengths between 200 and 600 nm. The spectra show the samples sublimed congruently into HGI2 without any observed Hg or I2 absorption spectra. The Beer's Law constants for 15 wavelengths between 200 and 440 nm were derived. From these constants the vapor pressure of HgI2, P, was found to be a function of temperature for the liquid and the solid beta-phases: ln P(atm) = -7700/T(K) + 12.462 (liquid phase) and ln P(atm) = -10150/T(K) + 17.026 (beta-phase). The expressions match the enthalpies of vaporization and sublimation of 15.30 and 20.17 kcal/mole respectively, for the liquid and the beta-phase HgI2. The difference in the enthalpies gives an enthalpy of fusion of 4.87 kcal/mole, and the intersection of the two expressions gives a melting point of 537 K.

Formation of multi-stereogenic centers using a catalytic diastereoselective Henry reaction.

PubMed

Arai, Takayoshi; Taneda, Yoshinori; Endo, Yoko

2010-11-14

A diastereoselective Henry reaction of chiral aldehydes with nitroalkanes was developed using a chiral sulfonyldiamine (L1)-CuCl complex. The reaction of (R)-2-phenylpropanal and nitromethane was smoothly catalyzed by the (S,S,S)-L1-CuCl complex to give the adduct with 99/1 syn/anti selectivity in 99% ee. In the reaction of (S)-2-phenylpropanal and nitroethane, the (R,R,R)-L1-CuCl catalyst yielded the expected three contiguous stereogenic centers in a highly syn-selective Henry reaction.

The Teaching Approach of Henry Schaefer-Simmern.

ERIC Educational Resources Information Center

Abrahamson, Roy E.

1980-01-01

This description of the teaching approach of Henry Schaefer-Simmern emphasizes his use of questioning to evoke student self-evaluation and to develop clarity of vision and interfunctional unity in students' art products and their mental, artistic conceiving. Two case reports of his work with elementary students are included. (Author/SJL)

Henry James on the Art of Acting.

ERIC Educational Resources Information Center

Thompson, David W.

Henry James, the nineteenth-century American novelist, also served on occasion as a theatre critic. Between 1875 and 1890 he reviewed several productions in Boston, New York, London, and Paris for "Atlantic Monthly" and other periodicals. The reviews are of interest because of James' high standards regarding acting and his often…

Robert Henry Thurston: Professionalism and Engineering Education

ERIC Educational Resources Information Center

Nienkamp, Paul

2016-01-01

Robert Henry Thurston is presented in this article. He provides one the most significant examples of professionalizing engineering through innovative education and promoting scientific education practices in the late nineteenth century. The son of a draftsmen and steam engine mechanic, Thurston spent his early years in Providence, Rhode Island.…

Effectiveness of an implementation optimisation intervention aimed at increasing parent engagement in HENRY, a childhood obesity prevention programme - the Optimising Family Engagement in HENRY (OFTEN) trial: study protocol for a randomised controlled trial.

PubMed

Bryant, Maria; Burton, Wendy; Cundill, Bonnie; Farrin, Amanda J; Nixon, Jane; Stevens, June; Roberts, Kim; Foy, Robbie; Rutter, Harry; Hartley, Suzanne; Tubeuf, Sandy; Collinson, Michelle; Brown, Julia

2017-01-24

Family-based interventions to prevent childhood obesity depend upon parents' taking action to improve diet and other lifestyle behaviours in their families. Programmes that attract and retain high numbers of parents provide an enhanced opportunity to improve public health and are also likely to be more cost-effective than those that do not. We have developed a theory-informed optimisation intervention to promote parent engagement within an existing childhood obesity prevention group programme, HENRY (Health Exercise Nutrition for the Really Young). Here, we describe a proposal to evaluate the effectiveness of this optimisation intervention in regard to the engagement of parents and cost-effectiveness. The Optimising Family Engagement in HENRY (OFTEN) trial is a cluster randomised controlled trial being conducted across 24 local authorities (approximately 144 children's centres) which currently deliver HENRY programmes. The primary outcome will be parental enrolment and attendance at the HENRY programme, assessed using routinely collected process data. Cost-effectiveness will be presented in terms of primary outcomes using acceptability curves and through eliciting the willingness to pay for the optimisation from HENRY commissioners. Secondary outcomes include the longitudinal impact of the optimisation, parent-reported infant intake of fruits and vegetables (as a proxy to compliance) and other parent-reported family habits and lifestyle. This innovative trial will provide evidence on the implementation of a theory-informed optimisation intervention to promote parent engagement in HENRY, a community-based childhood obesity prevention programme. The findings will be generalisable to other interventions delivered to parents in other community-based environments. This research meets the expressed needs of commissioners, children's centres and parents to optimise the potential impact that HENRY has on obesity prevention. A subsequent cluster randomised controlled pilot

Cosmological constant is a conserved charge

NASA Astrophysics Data System (ADS)

Chernyavsky, Dmitry; Hajian, Kamal

2018-06-01

Cosmological constant can always be considered as the on-shell value of a top form in gravitational theories. The top form is the field strength of a gauge field, and the theory enjoys a gauge symmetry. We show that cosmological constant is the charge of the global part of the gauge symmetry, and is conserved irrespective of the dynamics of the metric and other fields. In addition, we introduce its conjugate chemical potential, and prove the generalized first law of thermodynamics which includes variation of cosmological constant as a conserved charge. We discuss how our new term in the first law is related to the volume–pressure term. In parallel with the seminal Wald entropy, this analysis suggests that pressure can also be considered as a conserved charge.

1787 and 1776: Patrick Henry, James Madison, and the Revolutionary Legitimacy of the Constitution.

ERIC Educational Resources Information Center

Banning, Lance

1988-01-01

Discusses Patrick Henry's and James Madison's opinions on how the U.S. Constitution should be constructed. Describes how Henry introduced a set of substantive objections which were shared by Antifederalists throughout the country and persuaded many Revolutionaries that the Constitution was essentially at odds with the principles of 1776. (BSR)

The Ideas of Henry Jenkins and Libraries

ERIC Educational Resources Information Center

Anderson, Byron

2008-01-01

Henry Jenkins, director of the Comparative Media Studies Program at the Massachusetts Institute of Technology and keynote speaker at the 2007 American Library Association's "Gaming, Learning and Libraries Symposium" in Chicago is a visionary leader in the areas of new media and media convergence. In a white paper on digital media and learning…

Equilibrium Relationship between SVOCs in PVC Products and the Air in Contact with the Product.

PubMed

Eichler, Clara M A; Wu, Yaoxing; Cao, Jianping; Shi, Shanshan; Little, John C

2018-03-06

Phthalates and phthalate alternatives are semivolatile organic compounds (SVOCs) present in many PVC products as plasticizers to enhance product performance. Knowledge of the mass-transfer parameters, including the equilibrium concentration in the air in contact with the product surface ( y 0 ), will greatly improve the ability to estimate the emission rate of SVOCs from these products and to assess human exposure. The objective of this study was to measure y 0 for different PVC products and to evaluate its relationship with the material-phase concentrations ( C 0 ). Also, C 0 and y 0 data from other sources were included, resulting in a substantially larger data set ( N total = 34, T = 25 °C) than found in previous studies. The results show that the material/gas equilibrium relationship does not follow Raoult's law and that therefore the assumption of an ideal solution is invalid. Instead, Henry's law applies, and the Henry's law constant for all target SVOCs consists of the respective pure liquid vapor pressure and an activity coefficient γ, which accounts for the nonideal nature of the solution. For individual SVOCs, a simple partitioning relationship exists, but Henry's law is more generally applicable and will be of greater value in rapid exposure assessment procedures.

Control-Structure Ratings on the Fox River at McHenry and Algonquin, Illinois

USGS Publications Warehouse

Straub, Timothy D.; Johnson, Gary P.; Hortness, Jon E.; Parker, Joseph R.

2009-01-01

The Illinois Department of Natural Resources-Office of Water Resources operates control structures on a reach of the Fox River in northeastern Illinois between McHenry and Algonquin. The structures maintain water levels in the river for flood-control and recreational purposes. This report documents flow ratings for hinged-crest gates, a broad-crested weir, sluice gates, and an ogee spillway on the control structures at McHenry and Algonquin. The ratings were determined by measuring headwater and tailwater stage along with streamflow at a wide range of flows at different gate openings. Standard control-structure rating techniques were used to rate each control structure. The control structures at McHenry consist of a 221-feet(ft)-long broad-crested weir, a 4-ft-wide fish ladder, a 50-ft-wide hinged-crest gate, five 13.75-ft-wide sluice gates, and a navigational lock. Sixty measurements were used to rate the McHenry structures. The control structures at Algonquin consist of a 242-ft-long ogee spillway and a 50-ft-wide hinged-crest gate. Forty-one measurements were used to rate the Algonquin control structures.

Dissolved-Solids Load in Henrys Fork Upstream from the Confluence with Antelope Wash, Wyoming, Water Years 1970-2009

USGS Publications Warehouse

Foster, Katharine; Kenney, Terry A.

2010-01-01

Annual dissolved-solids load at the mouth of Henrys Fork was estimated by using data from U.S. Geological Survey streamflow-gaging station 09229500, Henrys Fork near Manila, Utah. The annual dissolved-solids load for water years 1970-2009 ranged from 18,300 tons in 1977 to 123,300 tons in 1983. Annual streamflows for this period ranged from 14,100 acre-feet in 1977 to 197,500 acre-feet in 1983. The 25-percent trimmed mean dissolved-solids load for water years 1970-2009 was 44,300 tons per year at Henrys Fork near Manila, Utah. Previous simulations using a SPAtially Referenced Regression On Watershed attributes (SPARROW) model for dissolved solids specific to water year 1991 conditions in the Upper Colorado River Basin predicted an annual dissolved-solids load of 25,000 tons for the Henrys Fork Basin upstream from Antelope Wash. On the basis of computed dissolved-solids load data from Henrys Fork near Manila, Utah, together with estimated annual dissolved-solids load from Antelope Wash and Peoples Canal, this prediction was adjusted to 37,200 tons. As determined by simulations with the Upper Colorado River Basin SPARROW model, approximately 56 percent (14,000 tons per year) of the dissolved-solids load at Henrys Fork upstream from Antelope Wash is associated with the 21,500 acres of irrigated agricultural lands in the upper Henrys Fork Basin.

Mass-sheet degeneracy, power-law models and external convergence: Impact on the determination of the Hubble constant from gravitational lensing

NASA Astrophysics Data System (ADS)

Schneider, Peter; Sluse, Dominique

2013-11-01

The light travel time differences in strong gravitational lensing systems allows an independent determination of the Hubble constant. This method has been successfully applied to several lens systems. The formally most precise measurements are, however, in tension with the recent determination of H0 from the Planck satellite for a spatially flat six-parameters ΛCDM cosmology. We reconsider the uncertainties of the method, concerning the mass profile of the lens galaxies, and show that the formal precision relies on the assumption that the mass profile is a perfect power law. Simple analytical arguments and numerical experiments reveal that mass-sheet like transformations yield significant freedom in choosing the mass profile, even when exquisite Einstein rings are observed. Furthermore, the characterization of the environment of the lens does not break that degeneracy which is not physically linked to extrinsic convergence. We present an illustrative example where the multiple imaging properties of a composite (baryons + dark matter) lens can be extremely well reproduced by a power-law model having the same velocity dispersion, but with predictions for the Hubble constant that deviate by ~20%. Hence we conclude that the impact of degeneracies between parametrized models have been underestimated in current H0 measurements from lensing, and need to be carefully reconsidered.

Obituary: Henry Albers (1925-2009)

NASA Astrophysics Data System (ADS)

Chromey, Fred

2011-12-01

Henry Albers, professor of astronomy at Vassar College for over thirty years, died March 29, 2009, in Fairhope, Alabama. For his work at Vassar, where he held the Maria Mitchell Chair, Albers received the first Maria Mitchell Women in Science Award for his inspiration of women astronomers. He said "In the final analysis it is the students who bring the joy into teaching." As a professional astronomer, Albers did observational work on Galactic structure in the southern Milky Way, and on the structure of the Magellanic Clouds. In retirement, Albers published Maria Mitchell - A Life in Journals and Letters, the firsthand account of America's first woman astronomer. Albers's research was on photographic near-infrared spectroscopy of red giant stars in the southern Milky Way, some proper motion studies, and on the structure of the Magellanic Clouds. A series of seven NSF grants supported his six trips to Chile to make spectroscopic observations, as well as his sabbatical collaborations at Minnesota, Leiden, and the Royal Observatory in Edinburgh. Henry Albers arrived at Vassar in 1958, to find an astronomy program that had been recently absorbed by the physics department, and that was suffering neglect after the retirement of Maud Makemson. For the next 31 years, with incredible energy -- he sometimes taught seven courses a year -- he built the astronomy program into one double in size (from one to two tenure lines), whose th century facilities have been replaced with a st century observatory. For a remarkable stretch of 20-some-years, Albers and physicist Bob Stearns, with considerable grace, alternated chairmanship of the joint department of physics and astronomy. Henry Albers was a devoted citizen of Vassar College and an enthusiastic participant in the process of faculty governance at that institution. He would have been the first to concede that his enthusiasm was sometimes excessive, and that his contributions at faculty meetings occasionally failed to move the

7. Historic American Buildings Survey. Photographed by Henry F. Withey ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

7. Historic American Buildings Survey. Photographed by Henry F. Withey September, 1936 NAVE TOWARD SANCTUARY. - Mission San Buenaventura, East Main Street & South Figueroa Street, Ventura, Ventura County, CA

1. Historic American Buildings Survey Photographed by Henry F. Withey ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

1. Historic American Buildings Survey Photographed by Henry F. Withey September, 1936 FRONT FACADE SOUTH. - Mission San Buenaventura, East Main Street & South Figueroa Street, Ventura, Ventura County, CA

6. Historic American Buildings Survey Photographed by Henry F. Withey ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

6. Historic American Buildings Survey Photographed by Henry F. Withey September, 1936 EAST ENTRANCE TO NAVE. - Mission San Buenaventura, East Main Street & South Figueroa Street, Ventura, Ventura County, CA

3. Historic American Buildings Survey Photographed by Henry F. Withey ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

3. Historic American Buildings Survey Photographed by Henry F. Withey December, 1936. SOUTH AND EAST FACADE. - Mission San Buenaventura, East Main Street & South Figueroa Street, Ventura, Ventura County, CA

5. Historic American Buildings Survey Photographed by Henry F. Withey, ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

5. Historic American Buildings Survey Photographed by Henry F. Withey, September, 1936 NORTH AND EAST FACADE. - Mission San Buenaventura, East Main Street & South Figueroa Street, Ventura, Ventura County, CA

Solubility of HCL in sulfuric acid at stratospheric temperatures

NASA Technical Reports Server (NTRS)

Williams, Leah R.; Golden, David M.

1993-01-01

The solubility of HCl in sulfuric acid was measured using a Knudsen cell technique. Effective Henry's law constants are reported for sulfuric acid concentrations between 50 and 60 weight percent and for temperatures between 220 and 230 K. The measured values indicate that very little HCl will be dissolved in the stratospheric sulfate aerosol particles.

2. Historic American Buildings Survey Photographed by Henry F. Withey ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

2. Historic American Buildings Survey Photographed by Henry F. Withey December, 1936 FRONT FACADE FROM SOUTH WEST. - Mission San Buenaventura, East Main Street & South Figueroa Street, Ventura, Ventura County, CA

4. Historic American Buildings Survey Photographed by Henry F. Withey ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

4. Historic American Buildings Survey Photographed by Henry F. Withey September 1936 SOUTH PORTION OF EAST FACADE. - Mission San Buenaventura, East Main Street & South Figueroa Street, Ventura, Ventura County, CA

The delusion of the Master: the last days of Henry James.

PubMed

Bartolomeo, Paolo

2013-11-01

The novelist Henry James shared with his brother William, the author of the Principles of Psychology, a deep interest in the ways in which personal identity is built through one's history and experiences. At the end of his life, Henry James suffered a vascular stroke in the right hemisphere and developed a striking identity delusion. He dictated in a perfectly clear and coherent manner two letters as if they were written by Napoleon Bonaparte. He also showed signs of reduplicative paramnesia. Negative symptoms resulting from right hemisphere damage may disrupt the feelings of "warmth and intimacy and immediacy" and the "resemblance among the parts of a continuum of feelings (especially bodily feelings)", which are the foundation of personal identity according to William James. On the other hand, a left hemisphere receiving inadequate input from the damaged right hemisphere may produce positive symptoms such as delusional, confabulatory narratives. Other fragments dictated during Henry James's final disease reveal some form of insight, if partial and disintegrated, into his condition. Thus, even when consciousness is impaired by brain damage, something of its deep nature may persist, as attested by the literary characteristics of the last fragments of the Master.

Solid phase microextraction method development for measuring Henry's Law constants of formaldehyde in aqueous solutions

EPA Science Inventory

Formaldehyde (HCHO) has been of special concern as an indoor air pollutant because of its existence in a wide range of products and its adverse health effects. The air-water partitioning behavior of volatile organic compounds (VOCs) such as formaldehyde is an important process th...

3. Historic American Buildings Survey Photographed by Henry F. Withey ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

3. Historic American Buildings Survey Photographed by Henry F. Withey December 1936 SOUTH ELEVATION - Jose Antonio Estudillo House, Mason Street & San Diego Avenue, Old Town, San Diego, San Diego County, CA

4. Historic American Buildings Survey Photographed by Henry F. Withey ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

4. Historic American Buildings Survey Photographed by Henry F. Withey December 1936 NORTH ELEVATION - Jose Antonio Estudillo House, Mason Street & San Diego Avenue, Old Town, San Diego, San Diego County, CA

A Teacher's Guide for William Shakespeare's "Henry V."

ERIC Educational Resources Information Center

WGBH-TV, Boston, MA.

This teacher's guide for William Shakespeare's play "Henry V" is designed to accompany the Kenneth Branagh Masterpiece Theater film production of the play, and to help teachers use the film in a variety of ways. The guide includes pre-viewing background information, five teaching units, and a pullout poster for classroom display. The…

A Re-examination of Henry Grady's New South.

ERIC Educational Resources Information Center

Mixon, Harold

Historian Henry Grady's speeches, particularly one delivered to the New England Club of New York City in 1886, are credited with persuading the North of the South's continued domination of blacks, its need for increased industrialization, and its broadened agriculture. Grady's term "The New South" is defined as a racially conservative,…

1. Historic American Buildings Survey Photographed by Henry F. Withey ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

1. Historic American Buildings Survey Photographed by Henry F. Withey June 1937 VIEW FROM NORTHWEST - Jose Antonio Estudillo House, Mason Street & San Diego Avenue, Old Town, San Diego, San Diego County, CA

2. Historic American Buildings Survey Photographed by Henry F. Withey ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

2. Historic American Buildings Survey Photographed by Henry F. Withey June 1937 VIEW FROM SOUTHWEST - Jose Antonio Estudillo House, Mason Street & San Diego Avenue, Old Town, San Diego, San Diego County, CA

5. Historic American Buildings Survey Photographed by Henry F. Withey ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

5. Historic American Buildings Survey Photographed by Henry F. Withey June 1937 DETAIL OF NORTH ELEVATION - Jose Antonio Estudillo House, Mason Street & San Diego Avenue, Old Town, San Diego, San Diego County, CA

9. Historic American Buildings Survey, Photographed by Henry F. Withey, ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

9. Historic American Buildings Survey, Photographed by Henry F. Withey, April 4th, 1934 SOUTH PORCH, LOOKING EAST - Mrs. A. L. M. Vhay House, 835 Leguna Street, Santa Barbara, Santa Barbara County, CA

Toxic Acid Gas Absorber Design Considerations for Air Pollution Control in Process Industries

ERIC Educational Resources Information Center

Manyele, S. V.

2008-01-01

This paper analyses the design parameters for an absorber used for removal of toxic acid gas (in particular sulfur dioxide) from a process gas stream for environmental health protection purposes. Starting from the equilibrium data, Henry's law constant was determined from the slope of the y-x diagram. Based on mass balances across the absorber,…

Joseph Henry and Astronomy

NASA Astrophysics Data System (ADS)

Rothenberg, Marc

2016-01-01

Joseph Henry (1797-1878) is best known for his work in electromagnetism and as the first secretary of the Smithsonian Institution. But he was also a pioneer solar physicist, an early advocate of US participation in astrophysics, and a facilitator of international cooperation in astronomy. This paper will briefly trace his role in the development of the US astronomical community from the time he taught astronomy at Princeton in the 1830s through his death, focusing on failed efforts to persuade US astronomers and patrons of astronomy that the best path for US astronomy should be astrophysics. He thought that the US could make a more significant contribution to astronomy science by striking out on a less travelled path rather than competing with the established European observatories.

4. Historic American Buildings Survey, Henry Pleasants, History of the ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

4. Historic American Buildings Survey, Henry Pleasants, History of the Old Eagle School, John C. Winston Co., 1909 PHOTOCOPY. - Eagle School, Old Eagle School Road (State Route 543) (Tredyffrin Township), Strafford, Chester County, PA

3. Historic American Buildings Survey, Henry Pleasants, History of the ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

3. Historic American Buildings Survey, Henry Pleasants, History of the Old Eagle School, John C. Winston Co., 1909 PHOTOCOPY. - Eagle School, Old Eagle School Road (State Route 543) (Tredyffrin Township), Strafford, Chester County, PA

7. Historic American Buildings Survey Photographed by Henry F. Withey ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

7. Historic American Buildings Survey Photographed by Henry F. Withey December 1936 WINDOW DETAIL (EXTERIOR, SOUTH ELEVATION) - Jose Antonio Estudillo House, Mason Street & San Diego Avenue, Old Town, San Diego, San Diego County, CA

7. Historic American Buildings Survey, Photographed by Henry F. Withey, ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

7. Historic American Buildings Survey, Photographed by Henry F. Withey, April 4th, 1934. SOUTH PORCH FROM THE SOUTHWEST - Mrs. A. L. M. Vhay House, 835 Leguna Street, Santa Barbara, Santa Barbara County, CA

8. Historic American Buildings Survey Photographed by Henry F. Withey ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

8. Historic American Buildings Survey Photographed by Henry F. Withey April 4th, 1934 SOUTH PORCH AT SOUTHWEST CORNER - Mrs. A. L. M. Vhay House, 835 Leguna Street, Santa Barbara, Santa Barbara County, CA

2. Historic American Buildings Survey Photographed by Henry F. Withey ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

2. Historic American Buildings Survey Photographed by Henry F. Withey April 4th, 1934 DETAIL OF FRONT FROM THE SOUTHWEST (NORTH?) - Yorbe-Abadie House, de la Guerra Plaza, Santa Barbara, Santa Barbara County, CA

Oxalate Content of the Herb Good-King-Henry, Blitum Bonus-Henricus

PubMed Central

Li, Wanying; Savage, Geoffrey P.

2015-01-01

The total, soluble and insoluble oxalate contents of the leaves, stems and buds of Good-King-Henry (Blitum Bonus-Henricus) were extracted and measured using HPLC chromatography. The large, mature leaves contained 42% more total oxalate than in the small leaves and the soluble oxalate content of the large leaves was 33% higher than the smaller leaves. Cooking the mixed leaves, stems and buds in boiling water for two minutes significantly (p < 0.05) reduced the total oxalate when compared to the raw plant parts. Pesto sauce made from mixed leaves contained 257 mg total oxalate/100 g fresh weight; this was largely made up of insoluble oxalates (85% of the total oxalate content). Soup made from mixed leaves contained lower levels of total oxalates (44.26 ± 0.49 mg total oxalate/100 g fresh weight) and insoluble oxalate made up 49% of the oxalate contents. The levels of oxalates in the Good-King-Henry leaves were high, suggesting that the leaves should be consumed occasionally as a delicacy because of their unique taste rather than as a significant part of the diet. However, the products made from Good-King-Henry leaves indicated that larger amounts could be consumed as the oxalate levels were reduced by dilution and processing. PMID:28231194

Geology of the Henry Mountains

USGS Publications Warehouse

Gilbert, G.K.

1877-01-01

If these pages fail to give a correct account of the structure of the Henry Mountains the fault is mine and I have no excuse. In all the earlier exploration of the Rocky Mountain Region, as well as in much of the more recent survey, the geologist has merely accompanied the geographer and has had no voice in the determination of either the route or the rate of travel. When the structure of a mountain was in doubt he was rarely able to visit the points which should resolve the doubt, but was compelled to turn regretfully away. Not so in the survey of the Henry Mountains. Geological exploration had shown that they were well disposed for examination, and that they promised to give the key to a type of structure which was at best obscurely known; and I was sent by Professor Powell to make a study of them, without restriction as to my order or method. I was limited only in time, the snow stopping my work two months after it was begun. Two months would be far too short a period in which to survey a thousand square miles in Pennsylvania or Illinois, but among the Colorado Plateaus it proved sufficient. A few comprehensive views from mountain tops gave the general distribution of the formations, and the remainder of the time was spent in the examination of the localities which best displayed the peculiar features of the structure. So thorough was the display and so satisfactory the examination, that in preparing my report I have felt less than ever before the desire to revisit the field and prove my conclusions by more extended observation.

Predictor laws for pictorial flight displays

NASA Technical Reports Server (NTRS)

Grunwald, A. J.

1985-01-01

Two predictor laws are formulated and analyzed: (1) a circular path law based on constant accelerations perpendicular to the path and (2) a predictor law based on state transition matrix computations. It is shown that for both methods the predictor provides the essential lead zeros for the path-following task. However, in contrast to the circular path law, the state transition matrix law furnishes the system with additional zeros that entirely cancel out the higher-frequency poles of the vehicle dynamics. On the other hand, the circular path law yields a zero steady-state error in following a curved trajectory with a constant radius. A combined predictor law is suggested that utilizes the advantages of both methods. A simple analysis shows that the optimal prediction time mainly depends on the level of precision required in the path-following task, and guidelines for determining the optimal prediction time are given.

3. Historic American Buildings Survey Photographed by Henry F. Withey ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

3. Historic American Buildings Survey Photographed by Henry F. Withey April 1937. RUINS OF SMITHY (LOOKING S.W.) - Mission San Gabriel Arcangel, Industrial Shop (Ruins), West Mission Drive & Junipero Serra Street, San Gabriel, Los Angeles County, CA

9. Historic American Buildings Survey Photographed by Henry F. Withey ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

9. Historic American Buildings Survey Photographed by Henry F. Withey April 1937 RUINS OF TANNERY (FROM WEST CORNER) - Mission San Gabriel Arcangel, Industrial Shop (Ruins), West Mission Drive & Junipero Serra Street, San Gabriel, Los Angeles County, CA

6. Historic American Buildings Survey Photographed by Henry F. Withey, ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

6. Historic American Buildings Survey Photographed by Henry F. Withey, December 1936 DETAIL OF NORTH WING AND CORRIDOR (EAST END) - Jose Antonio Estudillo House, Mason Street & San Diego Avenue, Old Town, San Diego, San Diego County, CA

4. Historic American Buildings Survey Photographed by Henry F. Withey ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

4. Historic American Buildings Survey Photographed by Henry F. Withey April 1937 RUINS OF SMITHY FROM SO. WEST CORNER. - Mission San Gabriel Arcangel, Industrial Shop (Ruins), West Mission Drive & Junipero Serra Street, San Gabriel, Los Angeles County, CA

2. Historic American Buildings Survey Photographed by Henry F. Withey ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

2. Historic American Buildings Survey Photographed by Henry F. Withey March 1936 VIEW OF FOUNTAIN IN MISSION PARK, MISSION PROPERTY AT ONE TIME. - Mission San Fernando Rey de Espana, Fountains, Mission Boulevard, San Fernando, Los Angeles County, CA

8. Historic American Buildings Survey Photographed by Henry F. Withey ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

8. Historic American Buildings Survey Photographed by Henry F. Withey April 1937 RUINS OF SOAP FACTORY FROM EAST CORNER. - Mission San Gabriel Arcangel, Industrial Shop (Ruins), West Mission Drive & Junipero Serra Street, San Gabriel, Los Angeles County, CA

7. Historic American Buildings Survey Photographed by Henry F. Withey ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

7. Historic American Buildings Survey Photographed by Henry F. Withey April 1937 RUINS OF SOAP FACTORY (S. W. Side) - Mission San Gabriel Arcangel, Industrial Shop (Ruins), West Mission Drive & Junipero Serra Street, San Gabriel, Los Angeles County, CA

2. Historic American Buildings Survey Photographed by Henry F. Withey ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

2. Historic American Buildings Survey Photographed by Henry F. Withey December 1936 VIEW OF MISSION FROM SOUTH SIDE OF VALLEY (DISTANCE ABOUT 3 MILES) - Mission San Diego de Alcala, Misson Valley Road, San Diego, San Diego County, CA

The Transformative Intellectual: An Examination of Henry Giroux's Ethics

ERIC Educational Resources Information Center

Kashani, Tony

2012-01-01

This article explores Henry Giroux's contributions to critical pedagogy. The author demonstrates how Giroux, as a public intellectual, has found his Ethics in the right place. The author further argues that Giroux's Ethics of virtue are present not only in the public person but also in his transformative writing.

George Henry Hepting: Pioneer Leader in Forest Pathology

Treesearch

Ellis B. Cowling; Arthur Kelman; Harry R. Powers

1999-01-01

George Henry Hepting grew up in the city environment of Brooklyn, but early in his life developed a deep love and scientific interest in forestry. He became America's most skilled scientist in the theory and practice of forest pathology. He studied how long-lived forest trees, unlike most plants, cope with the long-term changes in their biological, physical, and...

5. Historic American Buildings Survey Photographed by Henry F. Withey ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

5. Historic American Buildings Survey Photographed by Henry F. Withey April 1937 RUINS OF SMITHY AND SOAP FACTORY (LOOKING SOUTH) - Mission San Gabriel Arcangel, Industrial Shop (Ruins), West Mission Drive & Junipero Serra Street, San Gabriel, Los Angeles County, CA

Determination of Activities of Niobium in Cu-Nb Melts Containing Dilute Nb

NASA Astrophysics Data System (ADS)

Wang, Daya; Yan, Baijun; Sichen, Du

2015-04-01

The activity coefficients of niobium in Cu-Nb melts were measured by equilibrating solid NbO2 with liquid copper under controlled oxygen potentials in the temperature range of 1773 K to 1898 K (1500 °C to 1625 °C). Either CO-CO2 gas mixture or H2-CO2 gas mixture was employed to obtain the desired oxygen partial pressures. Cu-Nb system was found to follow Henry's law in the composition range studied. The temperature dependence of Henry's constant in the Cu-Nb melts could be expressed as follows: The partial molar excess Gibbs energy change of niobium in Cu-Nb melts can be expressed as follows:

2. Historic American Buildings Survey Photographed by Henry F. Withey ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

2. Historic American Buildings Survey Photographed by Henry F. Withey April 1937 RUINS OF FOUNTAIN, SMITHY AND SOAP FACTORY (LOOKING EAST) - Mission San Gabriel Arcangel, Industrial Shop (Ruins), West Mission Drive & Junipero Serra Street, San Gabriel, Los Angeles County, CA

7. Historic American Buildings Survey Photographed by Henry F. Withey, ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

7. Historic American Buildings Survey Photographed by Henry F. Withey, MaY 1937 SHOP RUINS (DETAIL OF SOAP OVEN) - Mission San Juan Capistrano, Industrial Shops, Olive Street, between U.S. Highway 101 & Main Street, San Juan Capistrano, Orange County, CA

22. Historic American Buildings Survey Photographed by Henry F. Withey ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

22. Historic American Buildings Survey Photographed by Henry F. Withey June 1936 STONE CHURCH, ARCHES OF SANCTUARY AND WEST TRANSEPT - Mission San Juan Capistrano, Stone Church, Olive Street, between U.S. Highway 101 & Main Street, San Juan Capistrano, Orange County, CA

Environmental Containment Property Estimation Using QSARs in an Expert System

DTIC Science & Technology

1991-10-15

economical method to estimate aqueous solubility, octanol/ water partition coefficients, vapor pressures, organic carbon, normalized soil sorption...PROPERTY ESTIMATION USING QSARs IN AN EXPERT SYSTEM William J. Doucette Mark S. Holt Doug J. Denne Joan E. McLean Utah State University Utah Water ...persistence of a chemical are aqueous solubility, octanol/ water partition coefficient, soil/ water sorption coefficient, Henry’s Law constant

Development of Monopole Interaction Models for Ionic Compounds. Part I: Estimation of Aqueous Henry’s Law Constants for Ions and Gas Phase pKa Values for Acidic Compounds

EPA Science Inventory

The SPARC (SPARC Performs Automated Reasoning in Chemistry) physicochemical mechanistic models for neutral compounds have been extended to estimate Henry’s Law Constant (HLC) for charged species by incorporating ionic electrostatic interaction models. Combinations of absolute aq...

6. Historic American Buildings Survey Photographed by Henry F. Withey ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

6. Historic American Buildings Survey Photographed by Henry F. Withey April 1937 RUINS OF SOAP FACTORY & SMITHY (FROM S. E. END OF SOAP FACTORY) - Mission San Gabriel Arcangel, Industrial Shop (Ruins), West Mission Drive & Junipero Serra Street, San Gabriel, Los Angeles County, CA

Gas evolution from spheres

NASA Astrophysics Data System (ADS)

Longhurst, G. R.

1991-04-01

Gas evolution from spherical solids or liquids where no convective processes are active is analyzed. Three problem classes are considered: (1) constant concentration boundary, (2) Henry's law (first order) boundary, and (3) Sieverts' law (second order) boundary. General expressions are derived for dimensionless times and transport parameters appropriate to each of the classes considered. However, in the second order case, the non-linearities of the problem require the presence of explicit dimensional variables in the solution. Sample problems are solved to illustrate the method.

Soliton solutions, stability analysis and conservation laws for the brusselator reaction diffusion model with time- and constant-dependent coefficients

NASA Astrophysics Data System (ADS)

Inc, Mustafa; Yusuf, Abdullahi; Isa Aliyu, Aliyu; Hashemi, M. S.

2018-05-01

This paper studies the brusselator reaction diffusion model (BRDM) with time- and constant-dependent coefficients. The soliton solutions for BRDM with time-dependent coefficients are obtained via first integral (FIM), ansatz, and sine-Gordon expansion (SGEM) methods. Moreover, it is well known that stability analysis (SA), symmetry analysis and conservation laws (CLs) give several information for modelling a system of differential equations (SDE). This is because they can be used for investigating the internal properties, existence, uniqueness and integrability of different SDE. For this reason, we investigate the SA via linear stability technique, symmetry analysis and CLs for BRDM with constant-dependent coefficients in order to extract more physics and information on the governing equation. The constraint conditions for the existence of the solutions are also examined. The new solutions obtained in this paper can be useful for describing the concentrations of diffusion problems of the BRDM. It is shown that the examined dependent coefficients are some of the factors that are affecting the diffusion rate. So, the present paper provides much motivational information in comparison to the existing results in the literature.

The effect of solvent relaxation time constants on free energy gap law for ultrafast charge recombination following photoinduced charge separation.

PubMed

Mikhailova, Valentina A; Malykhin, Roman E; Ivanov, Anatoly I

2018-05-16

To elucidate the regularities inherent in the kinetics of ultrafast charge recombination following photoinduced charge separation in donor-acceptor dyads in solutions, the simulations of the kinetics have been performed within the stochastic multichannel point-transition model. Increasing the solvent relaxation time scales has been shown to strongly vary the dependence of the charge recombination rate constant on the free energy gap. In slow relaxing solvents the non-equilibrium charge recombination occurring in parallel with solvent relaxation is very effective so that the charge recombination terminates at the non-equilibrium stage. This results in a crucial difference between the free energy gap laws for the ultrafast charge recombination and the thermal charge transfer. For the thermal reactions the well-known Marcus bell-shaped dependence of the rate constant on the free energy gap is realized while for the ultrafast charge recombination only a descending branch is predicted in the whole area of the free energy gap exceeding 0.2 eV. From the available experimental data on the population kinetics of the second and first excited states for a series of Zn-porphyrin-imide dyads in toluene and tetrahydrofuran solutions, an effective rate constant of the charge recombination into the first excited state has been calculated. The obtained rate constant being very high is nearly invariable in the area of the charge recombination free energy gap from 0.2 to 0.6 eV that supports the theoretical prediction.

New perspectives on constant-roll inflation

NASA Astrophysics Data System (ADS)

Cicciarella, Francesco; Mabillard, Joel; Pieroni, Mauro

2018-01-01

We study constant-roll inflation using the β-function formalism. We show that the constant rate of the inflaton roll is translated into a first order differential equation for the β-function which can be solved easily. The solutions to this equation correspond to the usual constant-roll models. We then construct, by perturbing these exact solutions, more general classes of models that satisfy the constant-roll equation asymptotically. In the case of an asymptotic power law solution, these corrections naturally provide an end to the inflationary phase. Interestingly, while from a theoretical point of view (in particular in terms of the holographic interpretation) these models are intrinsically different from standard slow-roll inflation, they may have phenomenological predictions in good agreement with present cosmological data.

Challenging Texts: Teaching Deliberately--Reading Henry David Thoreau's "Walden"

ERIC Educational Resources Information Center

Davis, Andrea

2011-01-01

One of the more difficult 19th-century American texts for high school students to read is undoubtedly Henry David Thoreau's "Walden." His erudite allusions, often page-long sentences, and sophisticated sense of the ironic initially leave many students cold. Still, the author encourages them to read amid the din of a cultural cacophony that shouts…

The Failed Educations of John Stuart Mill and Henry Adams.

ERIC Educational Resources Information Center

Crossley, Robert

1979-01-01

Analyzes and contrasts Mill's "Autobiography" and Adams'"The Education of Henry Adams" in order to present two approaches to the nature of education and of failure. Maintains that their perspectives may serve as catalysts and cautions for contemporary theories of education and its utility and relevance. (CAM)

1. Historic American Buildings Survey Photographed by Henry F. Withey ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

1. Historic American Buildings Survey Photographed by Henry F. Withey December 1936 VIEW OF MISSION VALLEY AND THE MISSION (LOOKING EAST FROM PRESIDIO HILL AT OLD TOWN, ORIGINAL SITE OF FIRST MISSION. - Mission San Diego de Alcala, Misson Valley Road, San Diego, San Diego County, CA

Report on the geology of the Henry Mountains

USGS Publications Warehouse

Gilbert, G.K.

1877-01-01

The Henry Mountains have been visited only by the explorer. Previous to 1869 they were not placed upon any map, nor was mention made of them in any of the published accounts of exploration or survey in the Rocky Mountain region. In that year Professor Powell while descending the Colorado River in boats passed near their foot, and gave to them the name which they bear in honor of Prof. Joseph Henry, the distinguished physicist. In 1872 Prof. A. H. Thompson, engaged in the continuance of the survey of the river, led a party across the mountains by the Penellen Pass, and climbed some of the highest peaks. Frontiersmen in search of farming and grazing lands or of the precious metals have since that time paid several visits to the mountains; but no survey was made of them until the years 1875 and 1876, when Mr. Walter H. Graves and the writer visited them for that purpose. They are situated in Southern Utah, and are crossed by the meridian of 110° 45' and the thirty-eighth parallel. They stand upon the right bank of the Colorado River of the West, and between its tributaries, the Dirty Devil and the Escalante.

Dynamics of gas bubble growth in a supersaturated solution with Sievert's solubility law.

PubMed

Gor, G Yu; Kuchma, A E

2009-07-21

This paper presents a theoretical description of diffusion growth of a gas bubble after its nucleation in supersaturated liquid solution. We study systems where gas molecules completely dissociate in the solvent into two parts, thus making Sievert's solubility law valid. We show that the difference between Henry's and Sievert's laws for chemical equilibrium conditions causes the difference in bubble growth dynamics. Assuming that diffusion flux is steady we obtain a differential equation on bubble radius. Bubble dynamics equation is solved analytically for the case of homogeneous nucleation of a bubble, which takes place at a significant pressure drop. We also obtain conditions of diffusion flux steadiness. The fulfillment of these conditions is studied for the case of nucleation of water vapor bubbles in magmatic melts.

COASTAL CONDITIONS IN THE VIRGINIAN PROVINCE (CAPE COD TO CAPE HENRY)

EPA Science Inventory

The U.S. EPA Environmental Monitoring and Assessment Program (EMAP) collected ecological condition data during 1990 through 1993 from the estuarine waters of the Virginian Biogeographic Province (Cape Henry to Cape Cod) to answer broad-scale questions on environmental conditions...

Fort McHenry National Monument and Historic Shrine. Teacher's Guide.

ERIC Educational Resources Information Center

Rogers, Jim

This teacher's guide explores Fort McHenry and the British attack on Baltimore Harbor (Maryland) in 1814. The guide contains 11 lessons: (1) "Where in the World Is Baltimore?" (no handout-use classroom resources); (2) "Why Baltimore?" (Handout-Why Baltimore?); (3) "Now Where Do We Place the Fort?" (Handout-Map of…

AdaMeasure: An Implementation of the Halstead and Henry Metrics.

DTIC Science & Technology

1987-06-01

of Departne t o Computer Science Kneale T..Nar4 ___. Dean of Information and Policy bScic:-n-- 2 Allr ABSTRACT I A software metric is a tool that...CONTENTS INTRODUCTION AND BACKGROUND ......................... 6 A. DEFINITIONS ..................................................... 6 B. SALLIE HENRY’S...METRIC.................................... 6 C. INFORMATION FLOW .......................................... 7 D. RELATIONS

Taxing junk food: applying the logic of the Henry tax review to food.

PubMed

Bond, Molly E; Williams, Michael J; Crammond, Brad; Loff, Bebe

2010-10-18

The recent review of taxation in Australia - the Henry tax review - has recommended that the federal government increase the taxes already levied on tobacco and alcohol. Tobacco and alcohol taxes are put forward as the best way of reducing the social harms caused by the use and misuse of these substances. Junk foods have the same pattern of misuse and the same social costs as tobacco and alcohol. The Henry tax review rejects the idea of taxing fatty foods, and to date the government has not implemented a tax on junk food. We propose that a tax on junk food be implemented as a tool to reduce consumption and address the obesity epidemic.

Reexamine Business Law for High School Students.

ERIC Educational Resources Information Center

Spiro, George

1980-01-01

In teaching business law, the content of the course must reflect the needs of the student and emphasize conceptual learning. Class preparation takes time and effort because law constantly changes. (JOW)

Theoretical Evaluation of the Transient Response of Constant Head and Constant Flow-Rate Permeability Tests

USGS Publications Warehouse

Zhang, M.; Takahashi, M.; Morin, R.H.; Esaki, T.

1998-01-01

A theoretical analysis is presented that compares the response characteristics of the constant head and the constant flowrate (flow pump) laboratory techniques for quantifying the hydraulic properties of geologic materials having permeabilities less than 10-10 m/s. Rigorous analytical solutions that describe the transient distributions of hydraulic gradient within a specimen are developed, and equations are derived for each method. Expressions simulating the inflow and outflow rates across the specimen boundaries during a constant-head permeability test are also presented. These solutions illustrate the advantages and disadvantages of each method, including insights into measurement accuracy and the validity of using Darcy's law under certain conditions. The resulting observations offer practical considerations in the selection of an appropriate laboratory test method for the reliable measurement of permeability in low-permeability geologic materials.

[From apprenticeship to Nobel Prize: Henri Moissan's fabulous destiny].

PubMed

Lafont, O

2008-01-01

Born in Paris on September 28, 1852, son of an eastern railways' employee and of a dressmaker, Henri Moissan's secondary schooling in Meaux did not allow him to get access to the sesame diploma "baccalauréat" (GCE). In 1869, he did obtain a special certificate of secondary schooling so that he could become an apprentice in watch making. That could have been the end of the story, but dreadful event for France appeared to have beneficial effects for Moissan. Under the threat of the Prussian army, Moissan's family took refuge near Paris. This gave the young Henri the opportunity to register as a student for the second-class pharmacy diploma, which did not need, at the time, the GCE. Moissan became then a trainee in pharmacy in 1871. Meanwhile, he followed the special schooling of "Ecole de chimie" founded by E. Frémy, and then joined the laboratory of Dehérain at the Museum, where he worked in plant physiology. He finally obtained the famous "baccalauréat" (GCE) and could register as a student in first-class pharmacy. He became a pharmacist as well as a doctor in sciences. In 1883, Moissan was named professor at the school of pharmacy in Paris. In 1886, he isolated fluorine by electrolysis of fluorhydric acid, in the presence of potassium fluoride, at a low temperature. He then studied diamond synthesis and gave a start to high temperature chemistry, designing his famous furnace. These findings and many others allowed Moissan to rise to membership in many learned academies around the world. Crowning achievement, Moissan won the Nobel Prize in 1906. A man of culture, collector of autographs and paintings, he died in 1907. Nothing of that would have been possible if there had not been a second-class pharmacist diploma. The history of Henri Moissan is one of a rise from apprenticeship to the Nobel Prize.

A New Physical Constant And Its Importance To Energy Production

NASA Astrophysics Data System (ADS)

Angus, Andrew

2003-03-01

The purpose of this paper is to introduce a new physical constant symbolized by the Greek letter lambda. This paper explains how the new physical constant was derived. This paper also explains the significance of the new physical constant as an alternative explanation to Einstein's Law of Photoelectric Effect. The new physical constant leads to a deeper understanding of the nature of the photon. Furthermore, this new physical constant leads us to the existence of two types of photon, the Planck photon and the Angus photon. Finally, the author also explains the importance of this new physical constant in energy production.

HABS DC,WASH,515A (sheet 1 of 4) Captain Henry Saunders ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

HABS DC,WASH,515A- (sheet 1 of 4) - Captain Henry Saunders House, Virginia Room, National Museum of American History, Smithsonian Institution (moved from VA, Windsor vicinity, U.S. Route 460), Washington, District of Columbia, DC

HABS DC,WASH,515A (sheet 4 of 4) Captain Henry Saunders ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

HABS DC,WASH,515A- (sheet 4 of 4) - Captain Henry Saunders House, Virginia Room, National Museum of American History, Smithsonian Institution (moved from VA, Windsor vicinity, U.S. Route 460), Washington, District of Columbia, DC

HABS DC,WASH,515A (sheet 2 of 4) Captain Henry Saunders ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

HABS DC,WASH,515A- (sheet 2 of 4) - Captain Henry Saunders House, Virginia Room, National Museum of American History, Smithsonian Institution (moved from VA, Windsor vicinity, U.S. Route 460), Washington, District of Columbia, DC

HABS DC,WASH,515A (sheet 3 of 4) Captain Henry Saunders ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

HABS DC,WASH,515A- (sheet 3 of 4) - Captain Henry Saunders House, Virginia Room, National Museum of American History, Smithsonian Institution (moved from VA, Windsor vicinity, U.S. Route 460), Washington, District of Columbia, DC

The last ride of Henry II of France: orbital injury and a king's demise.

PubMed

Eftekhari, Kian; Choe, Christina H; Vagefi, M Reza; Eckstein, Lauren A

2015-01-01

Jousting was a popular pastime for royalty in the Renaissance era. Injuries were common, and the eye was particularly at risk from the splinters of the wooden lance. On June 30, 1559, Henry II of France participated in a jousting tournament to celebrate two royal weddings. In the third match, Gabriel de Montgomery struck Henry on the right shoulder and the lance splintered, sending wooden shards into his face and right orbit. Despite being cared for by the prominent physicians Ambroise Paré and Andreas Vesalius, the king died 10 days later and was found to have a cerebral abscess. The wound was not explored immediately after the injury; nevertheless, wooden foreign bodies were discovered in the orbit at the time of autopsy. The dura had not been violated, suggesting that an infection may have traveled from the orbit into the brain. Nostradamus and Luca Guarico, the astrologer to the Medici family, had prophesied the death of Henry II of France, but he ignored their warnings and thus changed the course of history in Renaissance Europe. Copyright © 2015 Elsevier Inc. All rights reserved.

Guy V. Henry: A Study in Military Leadership

DTIC Science & Technology

1985-05-13

supplies; and obtain recruits for his black regiments. In approving Gillmore’s plan, President Lincoln hoped to accomplish an even more ambitious objective...defenses of Jacksonville, Baldwin, and the South Fork of the St. Mary’s (Barber’s Ford). Gillmore considered it well understood that there would be no...September 9, 1891, Williams-Henry Papers. 47 q., 290R, XXV, pt I, p. 279. For overview of the Florida campaign see Shelby Foote, The Civil War, A Narrative

Derivation of the Biot-Savart Law from Ampere's Law Using the Displacement Current

ERIC Educational Resources Information Center

Buschauer, Robert

2013-01-01

The equation describing the magnetic field due to a single, nonrelativistic charged particle moving at constant velocity is often referred to as the "Biot-Savart law for a point charge." Introductory calculus-based physics books usually state this law without proof. Advanced texts often present it either without proof or as a special…

How fundamental are fundamental constants?

NASA Astrophysics Data System (ADS)

Duff, M. J.

2015-01-01

I argue that the laws of physics should be independent of one's choice of units or measuring apparatus. This is the case if they are framed in terms of dimensionless numbers such as the fine structure constant, ?. For example, the standard model of particle physics has 19 such dimensionless parameters whose values all observers can agree on, irrespective of what clock, rulers or scales? they use to measure them. Dimensional constants, on the other hand, such as ?, c, G, e and k ?, are merely human constructs whose number and values differ from one choice of units to the next. In this sense, only dimensionless constants are 'fundamental'. Similarly, the possible time variation of dimensionless fundamental 'constants' of nature is operationally well defined and a legitimate subject of physical enquiry. By contrast, the time variation of dimensional constants such as ? or ? on which a good many (in my opinion, confusing) papers have been written, is a unit-dependent phenomenon on which different observers might disagree depending on their apparatus. All these confusions disappear if one asks only unit-independent questions. We provide a selection of opposing opinions in the literature and respond accordingly.

Governmental Immunity: Legal Basis and Implications for Public Education.

ERIC Educational Resources Information Center

Connors, Eugene T.

The concept of sovereign immunity in English law originated in both early canon law and the feudal system, became formalized in case law under King Henry II, and as the royal prerogative, became established into statutory law under King Henry VIII. This concept of governmental immunity was adopted by the states when the union was founded. The case…

Planning in Public Education: Lessons from Horace Mann and Henry Barnard

ERIC Educational Resources Information Center

Henkin, Alan B.; Ignasias, C. Dennis

1978-01-01

A handful of educational reformers from each generation effectively muster and sustain public support in efforts to advance their visions for education. Here is an account of the efforts of Horace Mann and Henry Barnard acting as educational advocates and consensus builders who evoked public responsiveness and guided their constituencies toward…

Enter the Madcap Prince of Wales: Students Directing "Henry IV, Part I."

ERIC Educational Resources Information Center

Earthman, Elise Ann

1993-01-01

Argues that William Shakespeare's "Henry IV, Part I" is an appropriate and useful text for secondary English classrooms. Shows how the play lends itself to performance-based instruction. Outlines ways of accomplishing student engagement, using film versions, and assigning written work. (HB)

Mounting a Curricular Revolution: An Interview with Henry Louis Gates, Jr.

ERIC Educational Resources Information Center

von Zastrow, Claus

2009-01-01

This article presents an interview with Henry Louis Gates, Jr., Harvard professor and cultural critic who has captured 25 million viewers with his PBS documentary series, African American Lives (WNET). Using genealogical research and DNA science, Gates traces the family history of 19 famous African Americans. What results is a rich and moving…

Henry Evelyn Bliss--The Other Immortal, or a Prophet without Honour?

ERIC Educational Resources Information Center

Broughton, Vanda

2008-01-01

The paper takes a retrospective look at the work of Henry Evelyn Bliss, classificationist theorist and author of the "Bibliographic Classification". Major features of his writings and philosophy are examined and evaluated for the originality of their contribution to the corpus of knowledge in the discipline. Reactions to Bliss's work are analysed,…

Glyoxal and Methylglyoxal Setschenow Salting Constants in Sulfate, Nitrate, and Chloride Solutions: Measurements and Gibbs Energies.

PubMed

Waxman, Eleanor M; Elm, Jonas; Kurtén, Theo; Mikkelsen, Kurt V; Ziemann, Paul J; Volkamer, Rainer

2015-10-06

Knowledge about Setschenow salting constants, KS, the exponential dependence of Henry's Law coefficients on salt concentration, is of particular importance to predict secondary organic aerosol (SOA) formation from soluble species in atmospheric waters with high salt concentrations, such as aerosols. We have measured KS of glyoxal and methylglyoxal for the atmospherically relevant salts (NH4)2SO4, NH4NO3, NaNO3, and NaCl and find that glyoxal consistently "salts-in" (KS of -0.16, -0.06, -0.065, -0.1 molality(-1), respectively) while methylglyoxal "salts-out" (KS of +0.16, +0.075, +0.02, +0.06 molality(-1)). We show that KS values for different salts are additive and present an equation for use in atmospheric models. Additionally, we have performed a series of quantum chemical calculations to determine the interactions between glyoxal/methylglyoxal monohydrate with Cl(-), NO3(-), SO4(2-), Na(+), and NH4(+) and find Gibbs free energies of water displacement of -10.9, -22.0, -22.9, 2.09, and 1.2 kJ/mol for glyoxal monohydrate and -3.1, -10.3, -7.91, 6.11, and 1.6 kJ/mol for methylglyoxal monohydrate with uncertainties of 8 kJ/mol. The quantum chemical calculations support that SO4(2-), NO3(-), and Cl(-) modify partitioning, while cations do not. Other factors such as ion charge or partitioning volume effects likely need to be considered to fully explain salting effects.

Environmental Containment Property Estimation Using OSARs in an Expert System

DTIC Science & Technology

1990-09-14

point , melting point , aqueous solubility, octanol/water partition coefficient, vapor pressure, soil/water sorption coefficients, Henry’s Law constants...name, boiling point , melting point , or molecular weight, and the ability to transfer to any of the PEP modules. The chemical property database screen is...Yalkowski et al., 1980): log Ssupercooled liquid = log Ssolid = 0.01(MP - 25) (13) where MP is the compound’s melting point in *C. Property/protiny

Henry Barton Jacobs, William Osler's intimate friend

PubMed Central

2017-01-01

William Osler was considered a universal friend by physicians of his era but, as with most people, his intimate friends were few. Henry Barton Jacobs became a close friend as one of the “latchkeyers” who lived next door to the Oslers in Baltimore, and the friendship intensified after Jacobs married Mary Sloan Frick Garrett, the fabulously wealthy widow of a former patient. The couples stayed close after the Oslers moved to Oxford, vacationing together and corresponding frequently. The couple friendship between the Oslers and the Jacobses benefited American medicine in specific ways, including the care of patients with tuberculosis and the care of children. PMID:28127152

78 FR 57154 - Granting of Request for Early Termination of the Waiting Period Under the Premerger Notification...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-09-17

... Company. 20131129 G Genossenschaft Constanter; DW Healthcare Partners, L.P.; Genossenschaft Constanter.... Henry; The New York Times Company; Mr. John W. Henry. FOR FURTHER INFORMATION CONTACT: Renee Chapman...

[Assassination of Henri IV, mental disorders and criminal responsibility].

PubMed

Bouchard, Jean-Pierre

2010-01-01

On 14th May 1610, François Ravaillac, a delusional mystic, assassinated King Henri IV. Under the Ancien Regime, regicide was considered as a supreme act of patricide and received the ultimate punishment even if the perpetrator showed obvious signs of insanity. What would the situation be today? A study of this notorious historical episode provides a reflection on the way dangerousness linked to mental disorders has been viewed and treated over the last four centuries.

Henry Carmichael [1796 to 1862]: Australia's Pioneer Adult Educator

ERIC Educational Resources Information Center

Morris, Roger K.

2016-01-01

This paper outlines the important role that Henry Carmichael played in the foundation of adult education in Australia. He was the driving force in the foundation and early success of the Sydney Mechanics' School of Arts. He also played a very significant role in the establishment of public schooling. His wide interest in educational thought is…

Movement, Memory and Mathematics: Henri Bergson and the Ontology of Learning

ERIC Educational Resources Information Center

de Freitas, Elizabeth; Ferrara, Francesca

2015-01-01

Using the work of philosopher Henri Bergson (1859-1941) to examine the nature of movement and memory, this article contributes to recent research on the role of the body in learning mathematics. Our aim in this paper is to introduce the ideas of Bergson and to show how these ideas shed light on mathematics classroom activity. Bergson's monist…

Universe of constant

NASA Astrophysics Data System (ADS)

Yongquan, Han

2016-10-01

The ideal gas state equation is not applicable to ordinary gas, it should be applied to the Electromagnetic ``gas'' that is applied to the radiation, the radiation should be the ultimate state of matter changes or initial state, the universe is filled with radiation. That is, the ideal gas equation of state is suitable for the Singular point and the universe. Maybe someone consider that, there is no vessel can accommodate radiation, it is because the Ordinary container is too small to accommodate, if the radius of your container is the distance that Light through an hour, would you still think it can't accommodates radiation? Modern scientific determinate that the radius of the universe now is about 1027 m, assuming that the universe is a sphere whose volume is approximately: V = 4.19 × 1081 cubic meters, the temperature radiation of the universe (cosmic microwave background radiation temperature of the universe, should be the closest the average temperature of the universe) T = 3.15k, radiation pressure P = 5 × 10-6 N / m 2, according to the law of ideal gas state equation, PV / T = constant = 6 × 1075, the value of this constant is the universe, The singular point should also equal to the constant Author: hanyongquan

View of Crew Commander Henry Hartsfield Jr. loading film into IMAX camera

NASA Image and Video Library

1984-09-08

41D-11-004 (8 September 1984 --- View of Crew Commander Henry Hartsfield Jr. loading film into the IMAX camera during the 41-D mission. The camera is floating in front of the middeck lockers. Above it is a sticker of the University of Kansas mascott, the Jayhawk.

The Imaginary World of Henri Rousseau. Teacher's Guide. School Arts: Looking/Learning.

ERIC Educational Resources Information Center

Henderson, Anne

While Henri Rousseau's work was not easily classified into any definitive artistic style of the time--impressionism, post-impressionism, fauvism, or cubism--it has been considered a forerunner of surrealism because of its dreamlike sensibility. This teaching guide provides information about Rousseau and his work, focusing on "Tropical Forest…

Investigation of Solvent Effects on the Rate and Stereoselectivity of the Henry Reaction

PubMed Central

Kostal, Jakub; Voutchkova, Adelina M.; Jorgensen, William L.

2011-01-01

A combined computational and experimental kinetic study on the Henry reaction is reported. The effects of salvation on the transition structures and the rates of reaction between nitromethane and formaldehyde, and between nitropropane and benzaldehyde are elucidated with QM/MM calculations. PMID:22168236

[Henri Ellenberger, Henri Ey and the Traité de Psychiatrie in the "Encyclopédie Médico-Chirurgicale": an American career under the auspices of the "Evolution Psychiatrique"].

PubMed

Delille, Emmanuel

2006-01-01

Henri Ellenberger, psychiatrist and historian, experienced a decisive period in his career in the early fifties of the last century. Educated in France, intern at Sainte-Anne Hospital, he was working in Switzerland after the war and then tried to move to the United States. It was during his participation in the French group "l'Evolution Psychiatrique" that he happened to contribute to the treatise of psychiatry (1955) of the French medical and surgical encyclopaedia ("EMC") and organise an observation trip to the United States. He was supported at that time by Henri Ey, key figure of French psychiatry. While going back to his career, we would like to emphasise on his comments about the "Psychotherapy of schizophrenia". Even though later Ellenberger became a well-known researcher in North America, it is more a question for us to discuss the scientific ambition he had in this particular context of a French learned society as a member of "l'Evolution Psychiatrique" and as a psychiatrist formerly intern from the "Hôpitaux psychiatriques de la Seine" (Parisian district).

VOLATILIZATION OF ALKYLBENZENES FROM WATER.

USGS Publications Warehouse

Rathbun, R.E.; Tai, D.Y.

1985-01-01

Volatilization is a physical process of importance in determining the fate of many organic compounds in streams and rivers. This process is frequently described by the conceptual-two-film model. The model assumes uniformly mixed water and air phases separated by thin films of water and air in which mass transfer is by molecular diffusion. Mass-transfer coefficients for the water and air films are related to an overall mass-transfer coefficient for volatilization through the Henry's law constant.

Henry Mayhew: journalist, social investigator, and foreshadower of qualitative research.

PubMed

Nunes, Everardo Duarte

2012-09-01

As a journalist, Henry Mayhew recorded daily life in London in the latter half of the nineteenth century. His approach remains of interest to historians and social scientists today in that it foreshadowed qualitative research. The article highlights methodological aspects of Mayhew's investigations and analyzes two of his reports, one on a cholera outbreak and the other on a female street vendor. It also addresses some analyses that have critiqued his work.

Ionic strength dependence of the oxidation of SO2 by H2O2 in sodium chloride particles

NASA Astrophysics Data System (ADS)

Ali, H. M.; Iedema, M.; Yu, X.-Y.; Cowin, J. P.

2014-06-01

The reaction of sulfur dioxide and hydrogen peroxide in the presence of deliquesced (>75% RH) sodium chloride (brine) particles was studied by utilizing a cross flow mini-reactor. The reaction kinetics were followed by observing chloride depletion in particles by computer-controlled scanning electron microscope with energy dispersive X-ray analysis, namely CCSEM/EDX. The reactions take place in concentrated mixed salt brine aerosols, for which no complete kinetic equilibrium data previously existed. We measured the Henry's law solubility of H2O2 in brine solutions to close that gap. We also calculated the reaction rate as the particle transforms continuously from concentrated NaCl brine to, eventually, a mixed NaHSO4 plus H2SO4 brine solution. The reaction rate of the SO2 oxidation by H2O2 was found to be influenced by the change in ionic strength as the particle undergoes compositional transformation, following closely the dependence of the third order rate constant on ionic strength as predicted using established rate equations. This is the first study that has measured the ionic strength dependence of sulfate formation (in non-aqueous media) from oxidation of mixed salt brine aerosols in the presence of H2O2. It also gives the first report of the dependence of the Henry's law constant of H2O2 on ionic strength.

Air sparging: Air-water mass transfer coefficients

NASA Astrophysics Data System (ADS)

Braida, Washington J.; Ong, Say Kee

1998-12-01

Experiments investigating the mass transfer of several dissolved volatile organic compounds (VOCs) across the air-water interface were conducted using a single-air- channel air-sparging system. Three different porous media were used in the study. Air velocities ranged from 0.2 cm s-1 to 2.5 cm s-1. The tortuosity factor for each porous medium and the air-water mass transfer coefficients were estimated by fitting experimental data to a one-dimensional diffusion model. The estimated mass transfer coefficients KG ranged from 1.79 × 10-3 cm min-1 to 3.85 × 10-2 cm min-1. The estimated lumped gas phase mass transfer coefficients KGa were found to be directly related to the air diffusivity of the VOC, air velocity, and particle size, and inversely related to the Henry's law constant of the VOCs. Of the four parameters investigated, the parameter that controlled or had a dominant effect on the lumped gas phase mass transfer coefficient was the air diffusivity of the VOC. Two empirical models were developed by correlating the Damkohler and the modified air phase Sherwood numbers with the air phase Peclet number, Henry's law constant, and the reduced mean particle size of porous media. The correlation developed in this study may be used to obtain better predictions of mass transfer fluxes for field conditions.

A French description of German psychology laboratories in 1893 by Victor Henri, a collaborator of Binet.

PubMed

Nicolas, Serge; Barnes, Marissa E; Murray, David J

2015-05-01

There is a rich tradition of writings about the foundation of psychology laboratories, particularly in the United States but also in France. Various documents exist concerning former German laboratories in American and French literature. But the most interesting French paper was certainly written by a young psychologist named Victor Henri (1872-1940) who was a close collaborator of Alfred Binet (1857-1911) in the 1890s. Visiting various psychology laboratories, he wrote, in 1893, a clear description of the laboratories of Wundt, G. E. Müller, Martius and Ebbinghaus. An English translation is given of Henri's paper and the historical importance of his contribution is here expounded by contrasting the German and French psychologies of the time.

The Rhetoric of Bishop Henry McNeal Turner, Renowned Speaker and Journalist.

ERIC Educational Resources Information Center

Cummings, Melbourne S.

Bishop Henry McNeal Turner, a journalist and speaker, headed a back-to-Africa movement in the second half of the nineteenth century that was one of the first black rhetorical movements to meet the challenges of institutionalized racism in the United States. Turner was a preacher in the African Methodist Episcopal Church, becoming first an elder…

Wildfire rehabilitation success with and without chaining on the Henry Mountains, Utah

Treesearch

Cristina Juran; Bruce A. Roundy; James N. Davis

2008-01-01

We sampled unchained and chained areas in 2004 and 2005 on the Henry Mountains that had been aerially seeded after the Bulldog Fire of 2003. Establishment of seeded grasses was high on unchained and chained areas although chaining increased seeded grass establishment on some sites. Western yarrow established well on unchained areas. Initially, high seedling emergence...

A procedure to find thermodynamic equilibrium constants for CO2 and CH4 adsorption on activated carbon.

PubMed

Trinh, T T; van Erp, T S; Bedeaux, D; Kjelstrup, S; Grande, C A

2015-03-28

Thermodynamic equilibrium for adsorption means that the chemical potential of gas and adsorbed phase are equal. A precise knowledge of the chemical potential is, however, often lacking, because the activity coefficient of the adsorbate is not known. Adsorption isotherms are therefore commonly fitted to ideal models such as the Langmuir, Sips or Henry models. We propose here a new procedure to find the activity coefficient and the equilibrium constant for adsorption which uses the thermodynamic factor. Instead of fitting the data to a model, we calculate the thermodynamic factor and use this to find first the activity coefficient. We show, using published molecular simulation data, how this procedure gives the thermodynamic equilibrium constant and enthalpies of adsorption for CO2(g) on graphite. We also use published experimental data to find similar thermodynamic properties of CO2(g) and of CH4(g) adsorbed on activated carbon. The procedure gives a higher accuracy in the determination of enthalpies of adsorption than ideal models do.

78 FR 8682 - Culturally Significant Objects Imported for Exhibition Determinations: “Henri Labrouste...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-02-06

... DEPARTMENT OF STATE [Public Notice 8176] Culturally Significant Objects Imported for Exhibition Determinations: ``Henri Labrouste: Structure Brought to Light'' SUMMARY: Notice is hereby given of the following determinations: Pursuant to the authority vested in me by the Act of October 19, 1965 (79 Stat. 985; 22 U.S.C...

Apportionment of NMHC tailpipe vs non-tailpipe emissions in the Fort McHenry and Tuscarora mountain tunnels

NASA Astrophysics Data System (ADS)

Gertler, Alan W.; Fujita, Eric M.; Pierson, William R.; Wittorff, David N.

Measurements of on-road emissions of non-methane hydrocarbons (NMHCs) were made in the Fort McHenry Tunnel (Baltimore) and Tuscarora Mountain Tunnel (Pennsylvania) during the summer of 1992. Measurements were made during 11 one-hour periods in the Fort McHenry Tunnel and during 11 one-hour periods in the Tuscarora Mountain Tunnel. The observed light-duty fleets were quite new, with a median model year of approximately 1989. Speciated NMHC values were obtained from analyses of canister and Tenax samples, and light-duty speciated emission factors were calculated for the two tunnels. Fuel samples were collected in the area around the tunnels for use in constructing headspace and liquid fuel profiles for the chemical mass balance (CMB) receptor model. Profiles of tailpipe emissions were obtained from the literature. The CMB was used to apportion tailpipe from non-tailpipe emissions. Non-tailpipe sources were found to constitute approximately 15% of the light-duty NMHC emissions. The Federal automotive emission-rate models, MOBILE4.1 and MOBILE5, underpredicted non-tailpipe emissions, assigning approximately 9% and 6.5%, respectively, to non-tailpipe sources. In terms of total absolute emissions, MOBILE5 predictions were approximately a factor of 2 greater than MOBILE4.1 predictions. Both MOBILE4.1 and MOBILE5 underestimated the NMHC emissions in the Fort McHenry Tunnel and overpredicted the NMHC emissions in the Tuscarora Mountain Tunnel. In all cases, the MOBILE models underestimated the absolute value of the non-tailpipe emissions. The ability of the MOBILE models to account for observed emissions when conditions are more variable than those studies in the Fort McHenry and Tuscarora Mountain tunnels is still an open question.

Derivation of the Biot-Savart Law from Ampere's Law Using the Displacement Current

NASA Astrophysics Data System (ADS)

Buschauer, Robert

2013-12-01

The equation describing the magnetic field due to a single, nonrelativistic charged particle moving at constant velocity is often referred to as the "Biot-Savart law for a point charge." Introductory calculus-based physics books usually state this law without proof.2 Advanced texts often present it either without proof or as a special case of a complicated mathematical formalism.3 Either way, little or no physical insight is provided to the student regarding the underlying physics. This paper presents a novel, basic, and transparent derivation of the Biot-Savart law for a point charge based only on Maxwell's displacement current term in Ampere's law. This derivation can serve many pedagogical purposes. For example, it can be used as lecture material at any academic level to obtain the Biot-Savart law for a point charge from simple principles. It can also serve as a practical example of the important fact that a changing electric flux produces a magnetic field.

William Henry Welch (1850–1934): the road to Johns Hopkins

PubMed Central

2011-01-01

William Henry Welch's selection in 1884 as the first faculty member of the new medical school at Johns Hopkins created the invigorating atmosphere that generated the revolutionary changes in medical training and laboratory medicine that transformed medicine in America. Dr. Welch's family traditions, his New England upbringing, Yale education, and German university experience prepared a unique individual to lead American medicine into the 20th century. PMID:21738298

W. Henry Robinson: Popularising astronomy in Victorian Walsall and Birmingham

NASA Astrophysics Data System (ADS)

Williams, S.

William Henry Robinson was one of the most prominent citizens of Walsall, then part of Staffordshire, in the Victorian and Edwardian periods. An influential businessman, he managed to combine printing, publishing, editing a newspaper, writing books and poetry, maintaining a library and retail trading with founding the town's literary institute, and bringing the scientists, explorers, authors and cultural pursuits of the day to his home town. An amateur astronomer in his own right, Robinson was instrumental in setting up the BAA's Midland Branch.

Solubility of oxygen in a seawater medium in equilibrium with a high-pressure oxy-helium atmosphere.

PubMed

Taylor, C D

1979-06-01

The molar oxygen concentration in a seawater medium in equilibrium with a high-pressure oxygen-helium atmosphere was measured directly in pressurized subsamples, using a modified version of the Winkler oxygen analysis. At a partial pressure of oxygen of 1 atm or less, its concentration in the aqueous phase was adequately described by Henry's Law at total pressures up to 600 atm. This phenomenon, which permits a straightforward determination of dissolved oxygen within hyperbaric systems, resulted from pressure-induced compensatory alterations in the Henry's Law variables rather than from a true obedience to the Ideal Gas Law. If the partial pressure of a gas contributes significantly to the hydrostatic pressure, Henry's Law is no longer adequate for determining its solubility within the compressed medium.

The Treatment of the Laws of Dynamics in Higher Level Schools.

ERIC Educational Resources Information Center

Kikoin, I. K.

1979-01-01

Describes how Newton's three laws of dynamics are taught in high school in the Soviet Union. Rejects introducing Newton's second law as an equation defining mass as a proportionality constant. Shows how the concept of mass can be introduced independently of Newton's Law. (GA)

From the "metaphysics of the individual" to the critique of society: on the practical significance of Michel Henry's phenomenology of life.

PubMed

Staudigl, Michael

This essay explores the practical significance of Michel Henry's "material phenomenology." Commencing with an exposition of his most basic philosophical intuition, i.e., his insight that transcendental affectivity is the primordial mode of revelation of our selfhood, the essay then brings to light how this intuition also establishes our relation to both the world and others. Animated by a radical form of the phenomenological reduction, Henry's material phenomenology brackets the exterior world in a bid to reach the concrete interior transcendental experience at the base of all exteriority. The essay argues that this "counter reduction," designed as a practical orientation to the world, suspends all traditional parameters of onto(theo)logical individuation in order to rethink subjectivity in terms of its transcendental corporeality, i.e., in terms of the invisible display of "affective flesh." The development of this "metaphysics of the individual" anchors his "practical philosophy" as he developed it-under shifting accents-throughout his oeuvre. In particular, the essay brings into focus Henry's reflections on modernity, the industry of mass culture and their "barbaric" movements. The essay briefly puts these cultural and political areas of Henry's of thinking into contact with his late "theological turn," i.e., his Christological account of Life and the (inter)subjective self-realization to which it gives rise.

Actively Experiencing Shakespeare: Students "Get on Their Feet" for "Henry IV, Part One."

ERIC Educational Resources Information Center

Meyer, Herbert M.; Thomsen, Lee

1999-01-01

Discusses how a literature and multimedia course for 11th and 12th graders used active-learning experiences to engage students with Shakespeare's "Henry IV, Part One." Describes how shouting Hal's soliloquy; constructing a chart of character relations; rewriting a scene in their own words; performing, filming, and critiquing a scene; and…

Relativistic covariance of Ohm's law

NASA Astrophysics Data System (ADS)

Starke, R.; Schober, G. A. H.

2016-04-01

The derivation of Lorentz-covariant generalizations of Ohm's law has been a long-term issue in theoretical physics with deep implications for the study of relativistic effects in optical and atomic physics. In this article, we propose an alternative route to this problem, which is motivated by the tremendous progress in first-principles materials physics in general and ab initio electronic structure theory in particular. We start from the most general, Lorentz-covariant first-order response law, which is written in terms of the fundamental response tensor χμ ν relating induced four-currents to external four-potentials. By showing the equivalence of this description to Ohm's law, we prove the validity of Ohm's law in every inertial frame. We further use the universal relation between χμ ν and the microscopic conductivity tensor σkℓ to derive a fully relativistic transformation law for the latter, which includes all effects of anisotropy and relativistic retardation. In the special case of a constant, scalar conductivity, this transformation law can be used to rederive a standard textbook generalization of Ohm's law.

Henri Ey's neojacksonism and the psychopathology of disintegrated mind.

PubMed

Farina, Benedetto; Ceccarelli, Maurizio; Di Giannantonio, Massimo

2005-01-01

The French psychiatrist Henri Ey developed his organo-dynamic theory of the mind function and consciousness 50 years ago incorporating Hughling Jackson's thinking, along with psychiatric and philosophical theorizations by Janet and Bergson. This model has not received the attention it deserved, but recent advances in neuroscience rekindled interest for Ey's theory. By overcoming the Cartesian mind-body dualism and treating the mind-body unit as an inseparable whole, this model opens the way for the integrated treatment of mental disorders. Ey's conceptualization of consciousness as being simultaneously both synchronous and diachronic anticipates current theories of consciousness (Damasio, Edelman, Mesulam).

New broadband square-law detector

NASA Technical Reports Server (NTRS)

Reid, M. S.; Gardner, R. A.; Stelzried, C. T.

1975-01-01

Compact device has wide dynamic range, accurate square-law response, good thermal stability, high-level dc output with immunity to ground-loop problems, ability to insert known time constants for radiometric applications, and fast response times compatible with computer systems.

Neostusakia, a new name for preoccupied Stusakia Kment and Henry, 2008 (Hemiptera: Heteroptera: Berytidae)

USDA-ARS?s Scientific Manuscript database

A case of homonymy in the heteropteran family Berytidae is addressed. The genus Stusakia Kment and Henry, 2008 (Hemiptera) is preoccupied by Stusakia Frýda, 1998 (Mollusca: Gastropoda). As a consequence, the replacement name Neostusakia, new name, is proposed. In addition, the only two included s...

Fin-de-Siecle Advances in Neuroeducation: Henry Herbert Donaldson and Reuben Post Halleck

ERIC Educational Resources Information Center

Theodoridou, Zoe D.; Triarhou, Lazaros C.

2009-01-01

This article focuses on two early attempts at bridging neuroscience and education, made by Henry Herbert Donaldson (1857-1938), a neurologist, and Reuben Post Halleck (1859-1936), an educator. Their works, respectively entitled "The Growth of the Brain: A Study of the Nervous System in Relation to Education" (1895) and "The Education of the…

A new broadband square law detector. [microwave radiometers

NASA Technical Reports Server (NTRS)

Reid, M. S.; Gardner, R. A.; Stelzried, C. T.

1975-01-01

A broadband constant law detector was developed for precision power measurements, radio metric measurements, and other applications. It has a wide dynamic range and an accurate square law response. Other desirable characteristics, which are all included in a single compact unit, are: (1) high-level dc output with immunity to ground loop problems; (2) fast response times; (3) ability to insert known time constants; and (4) good thermal stability. The detector and its performance are described in detail. The detector can be operated in a programmable system with a ten-fold increase in accuracy. The use and performance of the detector in a noise-adding radiometer system is also discussed.

Optimization of motion control laws for tether crawler or elevator systems

NASA Technical Reports Server (NTRS)

Swenson, Frank R.; Von Tiesenhausen, Georg

1988-01-01

Based on the proposal of a motion control law by Lorenzini (1987), a method is developed for optimizing motion control laws for tether crawler or elevator systems in terms of the performance measures of travel time, the smoothness of acceleration and deceleration, and the maximum values of velocity and acceleration. The Lorenzini motion control law, based on powers of the hyperbolic tangent function, is modified by the addition of a constant-velocity section, and this modified function is then optimized by parameter selections to minimize the peak acceleration value for a selected travel time or to minimize travel time for the selected peak values of velocity and acceleration. It is shown that the addition of a constant-velocity segment permits further optimization of the motion control law performance.

Neoliberalism, Democracy and the University as a Public Sphere: An Interview with Henry A. Giroux

ERIC Educational Resources Information Center

Harper, Victoria

2014-01-01

"Truthout" contributor, director of "Truthout's" Public Intellectual Project (truth-out.org/public-intellectual-project) and Truthout board member Henry A. Giroux responds to questions about how the excesses of neoliberal politics have reshaped and subverted the democratic mission of higher education.

Assessing the Teaching and Student Learning Outcomes of the Katz/Henry Faculty Development Model.

ERIC Educational Resources Information Center

Finkelstein, Martin

The impact of the Katz/Henry Faculty Development Model on teaching behaviors and student learning outcomes was assessed with 24 faculty members at 4 institutions in New Jersey. This model, known as "Partners in Learning" involved: faculty pairs who observe one another's class, partner meetings to discuss shared experience in the…

Gladstone-Dale constant for CF4. [experimental design

NASA Technical Reports Server (NTRS)

Burner, A. W., Jr.; Goad, W. K.

1980-01-01

The Gladstone-Dale constant, which relates the refractive index to density, was measured for CF4 by counting fringes of a two-beam interferometer, one beam of which passes through a cell containing the test gas. The experimental approach and sources of systematic and imprecision errors are discussed. The constant for CF4 was measured at several wavelengths in the visible region of the spectrum. A value of 0.122 cu cm/g with an uncertainty of plus or minus 0.001 cu cm/g was determined for use in the visible region. A procedure for noting the departure of the gas density from the ideal-gas law is discussed.

Child-Langmuir law applicability for a cathode sheath description of glow discharge in hydrogen

NASA Astrophysics Data System (ADS)

Lisovskiy, V. A.; Artushenko, K. P.; Yegorenkov, V. D.

2016-08-01

The present paper reveals that the Child-Langmuir law version with the constant ion mobility has to be applied for the cathode sheath description of the glow discharge in hydrogen. Using the analytical model we demonstrate that even in a high electric field the constant mobility law version rather than that for the constant ion mean free path has to hold in the case of impeded charge exchange and the dominant effect of polarization forces on the ion motion through the cathode sheath.

Bringing metabolic networks to life: convenience rate law and thermodynamic constraints

PubMed Central

Liebermeister, Wolfram; Klipp, Edda

2006-01-01

Background Translating a known metabolic network into a dynamic model requires rate laws for all chemical reactions. The mathematical expressions depend on the underlying enzymatic mechanism; they can become quite involved and may contain a large number of parameters. Rate laws and enzyme parameters are still unknown for most enzymes. Results We introduce a simple and general rate law called "convenience kinetics". It can be derived from a simple random-order enzyme mechanism. Thermodynamic laws can impose dependencies on the kinetic parameters. Hence, to facilitate model fitting and parameter optimisation for large networks, we introduce thermodynamically independent system parameters: their values can be varied independently, without violating thermodynamical constraints. We achieve this by expressing the equilibrium constants either by Gibbs free energies of formation or by a set of independent equilibrium constants. The remaining system parameters are mean turnover rates, generalised Michaelis-Menten constants, and constants for inhibition and activation. All parameters correspond to molecular energies, for instance, binding energies between reactants and enzyme. Conclusion Convenience kinetics can be used to translate a biochemical network – manually or automatically - into a dynamical model with plausible biological properties. It implements enzyme saturation and regulation by activators and inhibitors, covers all possible reaction stoichiometries, and can be specified by a small number of parameters. Its mathematical form makes it especially suitable for parameter estimation and optimisation. Parameter estimates can be easily computed from a least-squares fit to Michaelis-Menten values, turnover rates, equilibrium constants, and other quantities that are routinely measured in enzyme assays and stored in kinetic databases. PMID:17173669

The Politics of Knowledge and the Revitalization of American Democracy: A Response to Henry Giroux's "The University in Chains: Confronting the Military-Industrial-Academic Complex"

ERIC Educational Resources Information Center

Fraser, Cary

2009-01-01

This article presents the author's response to Henry Giroux's "The University in Chains: Confronting the Military-Industrial-Academic Complex." Henry Giroux has written a provocative assessment of the contemporary challenges facing the United States as a society, which over the course of the 20th century had assumed the role of leader and exemplar…

[Medical Devices Law for pain therapists].

PubMed

Regner, M; Sabatowski, R

2016-08-01

Medical Devices Law is a relatively new legal system, which has replaced the Medical Devices Regulations still well-known in Germany. German Medical Devices Law is based on European directives, which are, in turn, incorporated into national law by the Medical Devices Act. The Medical Devices Act is a framework law and covers a number of regulations that address specific topics within Medical Devices Law. In turn, in individual regulations, reference is made to guidelines, recommendations, etc. from other sources that provide detailed technical information on specific topics. Medical Devices Law is a very complex legal system, which needs to be permanently observed due to constant updating and adjustment. In the current article, the design and the structure of the system will be described, but special emphasis will be laid on important problem areas that need to be considered when applying and operating medical products, in this case by pain therapists in particular.

Hispanic Storyteller: Unity through the Use of Narrative in the Speaking of Henry Cisneros.

ERIC Educational Resources Information Center

Hanson, Trudy L.

Henry Cisneros, speaking on the theme, "the colorful past and promising future of Hispanic heroes in Texas," in Amarillo, Texas, on February 7, 1989, was successful in eliciting a positive response from his Anglo/Hispanic audience. An analysis of Cisneros' use of narrative demonstrates its effectiveness in leading to a feeling of…

No actual measurement … was required: Maxwell and Cavendish's null method for the inverse square law of electrostatics.

PubMed

Falconer, Isobel

In 1877 James Clerk Maxwell and his student Donald MacAlister refined Henry Cavendish's 1773 null experiment demonstrating the absence of electricity inside a charged conductor. This null result was a mathematical prediction of the inverse square law of electrostatics, and both Cavendish and Maxwell took the experiment as verifying the law. However, Maxwell had already expressed absolute conviction in the law, based on results of Michael Faraday's. So, what was the value to him of repeating Cavendish's experiment? After assessing whether the law was as secure as he claimed, this paper explores its central importance to the electrical programme that Maxwell was pursuing. It traces the historical and conceptual re-orderings through which Maxwell established the law by constructing a tradition of null tests and asserting the superior accuracy of the method. Maxwell drew on his developing 'doctrine of method' to identify Cavendish's experiment as a member of a wider class of null methods. By doing so, he appealed to the null practices of telegraph engineers, diverted attention from the flawed logic of the method, and sought to localise issues around the mapping of numbers onto instrumental indications, on the grounds that 'no actual measurement … was required'. Copyright © 2017 Elsevier Ltd. All rights reserved.

On geological interpretations of crystal size distributions: Constant vs. proportionate growth

USGS Publications Warehouse

Eberl, D.D.; Kile, D.E.; Drits, V.A.

2002-01-01

Geological interpretations of crystal size distributions (CSDs) depend on understanding the crystal growth laws that generated the distributions. Most descriptions of crystal growth, including a population-balance modeling equation that is widely used in petrology, assume that crystal growth rates at any particular time are identical for all crystals, and, therefore, independent of crystal size. This type of growth under constant conditions can be modeled by adding a constant length to the diameter of each crystal for each time step. This growth equation is unlikely to be correct for most mineral systems because it neither generates nor maintains the shapes of lognormal CSDs, which are among the most common types of CSDs observed in rocks. In an alternative approach, size-dependent (proportionate) growth is modeled approximately by multiplying the size of each crystal by a factor, an operation that maintains CSD shape and variance, and which is in accord with calcite growth experiments. The latter growth law can be obtained during supply controlled growth using a modified version of the Law of Proportionate Effect (LPE), an equation that simulates the reaction path followed by a CSD shape as mean size increases.

[The electric furnace of Henri Moissan at one hundred years: connection with the electric furnace, the solar furnace, the plasma furnace?].

PubMed

Royère, C

1999-03-01

The trace of Henri Moissan's pioneer work 100 years ago is clearly evidenced by an overview of achievements in high temperature devices; 1987: "Le four électrique" by Henri Moissan; 1948-1952: "High temperature heating in a cavity rotary kiln using focusing of solar radiation" by Félix Trombe; 1962: "The cavity rotary kiln using focused solar radiation jointly with a plasma gun" by Marc Foëx; 1970: "The rotary kiln with two plasma guns and arc transfer" by Marc Foëx; 1984: "The plasma furnace" by Electricité de France (EDF) at Renardières; 1997: "The plasma furnace" by the Atomic Energy Center (CEA) at Cadarache, the VULCANO program. The first part of this contribution is devoted to Henri Moissan. Re-reading his early book on the electric furnace, especially the first chapter and the sections on silica, carbon vapor and experiments performed in casting molten metal--the conclusions are outstanding--provides modern readers with an amazing insight into future developments. The last two parts are devoted to Félix Trombe and Marc Foëx, tracing the evolution of high temperature cavity processus leading to the solar furnace and the present day plasma furnace at the CEA. Focus is placed on research conducted by the French National Center for Scientific Research (CNRS) with the solar and plasma furnaces at Odeillo. The relationships with Henri Moissan's early work are amazing, offering a well deserved homage to this pioneer researcher.

Henry Giroux and the Politics of Higher Education under George W. Bush: An Interview

ERIC Educational Resources Information Center

Pozo, Mike Alexander

2005-01-01

In May of 2004 Henry Giroux, a creator of the field of critical pedagogy and a leading advocate for young people, democracy, and education in the United States, reluctantly left Penn State University after twelve years as a Distinguished Professor in the education department. He has been a critic of the corporatization of and conservative…

Determination of saltiness from the laws of thermodynamics--estimating the gas constant from psychophysical experiments.

PubMed

Norwich, K H

2001-10-01

One can relate the saltiness of a solution of a given substance to the concentration of the solution by means of one of the well-known psychophysical laws. One can also compare the saltiness of solutions of different solutes which have the same concentration, since different substances are intrinsically more salty or less salty. We develop here an equation that relates saltiness both to the concentration of the substance (psychophysical) and to a distinguishing physical property of the salt (intrinsic). For a fixed standard molar entropy of the salt being tasted, the equation simplifies to Fechner's law. When one allows for the intrinsic 'noise' in the chemoreceptor, the equation generalizes to include Stevens's law, with corresponding decrease in the threshold for taste. This threshold reduction exemplifies the principle of stochastic resonance. The theory is validated with reference to experimental data.

On the Occurrence of Mass Inflation for the Einstein-Maxwell-Scalar Field System with a Cosmological Constant and an Exponential Price Law

NASA Astrophysics Data System (ADS)

Costa, João L.; Girão, Pedro M.; Natário, José; Silva, Jorge Drumond

2018-03-01

In this paper we study the spherically symmetric characteristic initial data problem for the Einstein-Maxwell-scalar field system with a positive cosmological constant in the interior of a black hole, assuming an exponential Price law along the event horizon. More precisely, we construct open sets of characteristic data which, on the outgoing initial null hypersurface (taken to be the event horizon), converges exponentially to a reference Reissner-Nördstrom black hole at infinity. We prove the stability of the radius function at the Cauchy horizon, and show that, depending on the decay rate of the initial data, mass inflation may or may not occur. In the latter case, we find that the solution can be extended across the Cauchy horizon with continuous metric and Christoffel symbols in {L^2_{loc}} , thus violating the Christodoulou-Chruściel version of strong cosmic censorship.

[Henry Beecher and medical science: the 50th anniversary of a famous article].

PubMed

Jacobs, N; Huisman, F G

2017-01-01

In 2016, it had been exactly half a century ago that Henry Beecher published his article 'Ethics and clinical research' in The New England Journal of Medicine. Today, this article is considered a turning point in the history of medical research ethics. On the occasion of the fiftieth anniversary of this famous article, we are looking back on this turbulent period in the history of medicine.

A conservation law for virus infection kinetics in vitro.

PubMed

Kakizoe, Yusuke; Morita, Satoru; Nakaoka, Shinji; Takeuchi, Yasuhiro; Sato, Kei; Miura, Tomoyuki; Beauchemin, Catherine A A; Iwami, Shingo

2015-07-07

Conservation laws are among the most important properties of a physical system, but are not commonplace in biology. We derived a conservation law from the basic model for viral infections which consists in a small set of ordinary differential equations. We challenged the conservation law experimentally for the case of a virus infection in a cell culture. We found that the derived, conserved quantity remained almost constant throughout the infection period, implying that the derived conservation law holds in this biological system. We also suggest a potential use for the conservation law in evaluating the accuracy of experimental measurements. Copyright © 2015 Elsevier Ltd. All rights reserved.

James Paget Henry--a retrospective.

PubMed

Meehan, J P; Meehan, W P

1997-01-01

James Paget Henry really began his productive research career at the outset of the second world war. His studies of acceleration and the anoxia of high altitude were supported by the development of then new techniques of measuring and recording critical physiologic parameters such as vascular pressures, respiratory functions and haemoglobin saturation. His inquisitive mind made productive use of the instruments that had to be made by skilled instrument makers working in university shops. Much of this instrumentation has now found its way into the clinical arena where it is now the main armamentarium of cardiac diagnostic and respiratory function laboratories. His work in the space program preceeded that of the Russians but did not get recognition until Sputnik awakened the world to the possibilities of space flight. His development of the concept of a cardiovascular basis for fluid volume control and the supportive investigative work undertaken constitute a milestone in the annals of experimental physiology. The chimpanzees used in Project Mercury were found to be hypertensive which was related to the method of capture used by the commercial suppliers. This lead Jim to study the effect of early experience on resting blood pressure, an effort that soon developed into provocative studies of the biological basis of the stress response.

Alternative Derivations of the Statistical Mechanical Distribution Laws

PubMed Central

Wall, Frederick T.

1971-01-01

A new approach is presented for the derivation of statistical mechanical distribution laws. The derivations are accomplished by minimizing the Helmholtz free energy under constant temperature and volume, instead of maximizing the entropy under constant energy and volume. An alternative method involves stipulating equality of chemical potential, or equality of activity, for particles in different energy levels. This approach leads to a general statement of distribution laws applicable to all systems for which thermodynamic probabilities can be written. The methods also avoid use of the calculus of variations, Lagrangian multipliers, and Stirling's approximation for the factorial. The results are applied specifically to Boltzmann, Fermi-Dirac, and Bose-Einstein statistics. The special significance of chemical potential and activity is discussed for microscopic systems. PMID:16578712

Alternative derivations of the statistical mechanical distribution laws.

PubMed

Wall, F T

1971-08-01

A new approach is presented for the derivation of statistical mechanical distribution laws. The derivations are accomplished by minimizing the Helmholtz free energy under constant temperature and volume, instead of maximizing the entropy under constant energy and volume. An alternative method involves stipulating equality of chemical potential, or equality of activity, for particles in different energy levels. This approach leads to a general statement of distribution laws applicable to all systems for which thermodynamic probabilities can be written. The methods also avoid use of the calculus of variations, Lagrangian multipliers, and Stirling's approximation for the factorial. The results are applied specifically to Boltzmann, Fermi-Dirac, and Bose-Einstein statistics. The special significance of chemical potential and activity is discussed for microscopic systems.

An adaptive-binning method for generating constant-uncertainty/constant-significance light curves with Fermi -LAT data

DOE PAGES

Lott, B.; Escande, L.; Larsson, S.; ...

2012-07-19

Here, we present a method enabling the creation of constant-uncertainty/constant-significance light curves with the data of the Fermi-Large Area Telescope (LAT). The adaptive-binning method enables more information to be encapsulated within the light curve than with the fixed-binning method. Although primarily developed for blazar studies, it can be applied to any sources. Furthermore, this method allows the starting and ending times of each interval to be calculated in a simple and quick way during a first step. The reported mean flux and spectral index (assuming the spectrum is a power-law distribution) in the interval are calculated via the standard LATmore » analysis during a second step. In the absence of major caveats associated with this method Monte-Carlo simulations have been established. We present the performance of this method in determining duty cycles as well as power-density spectra relative to the traditional fixed-binning method.« less

Origins of Newton's First Law

NASA Astrophysics Data System (ADS)

Hecht, Eugene

2015-02-01

Anyone who has taught introductory physics should know that roughly a third of the students initially believe that any object at rest will remain at rest, whereas any moving body not propelled by applied forces will promptly come to rest. Likewise, about half of those uninitiated students believe that any object moving at a constant speed must be continually pushed if it is to maintain its motion.1 That's essentially Aristotle's law of motion and it is so "obviously" borne out by experience that it was accepted by scholars for 2000 years, right through the Copernican Revolution. But, of course, it's fundamentally wrong. This paper tells the story of how the correct understanding, the law of inertia, evolved and how Newton came to make it his first law.

Probing Planck's Law at Home

ERIC Educational Resources Information Center

Bonnet, I.; Gabelli, J.

2010-01-01

We report on the physics around an incandescent lamp. Using a consumer-grade digital camera, we combine electrical and optical measurements to explore Planck's law of black-body radiation. This simple teaching experiment is successfully used to measure both Stefan's and Planck's constants. Our measurements lead to a strikingly accurate value for…

How Darcy's Law sparked various fields of subsurface hydrology.

NASA Astrophysics Data System (ADS)

de Rooij, Gerrit H.

2016-04-01

Henry Darcy built the drinking water supply system of the French city of Dijon in the mid-19th century. In doing so, he developed an interest in the flow of water through sands, and, experimented with water flow in a vertical cylinder filled with different sands. He found Darcy's Law in this way, and until this day it is the cornerstone of the theory of water flow in porous media. Darcy's Law was quickly adopted for calculating groundwater flow, which blossomed after the introduction of a few very useful simplifying assumptions that permitted a host of analytical solutions to groundwater problems, including flows toward pumped drinking water wells and toward drain tubes. In soil hydrology, Darcy's Law itself required modification to facilitate its application for different soil water contents. The understanding of the relationship between the potential energy of soil water and the soil water content emerged early in the 20th century. The mathematical formalization of the consequences for the flow rate and storage change of soil water was established in the 1930s, but only after the 1970s did computers become powerful enough to tackle unsaturated flows head-on. In combination with crop growth models, this allowed Darcy-based models to aid in the setup of irrigation practices and to optimize drainage designs. In the past decades, spatial variation of the hydraulic properties of aquifers and soils has been shown to affect the transfer of solutes from soils to groundwater and from groundwater to surface water. All this emerged from a law derived from a few experiments on a cylinder filled with sand in the 1850s. The poster tracks this development of groundwater hydrology and soil water hydrology through seminal contributions over the past 160 years.

The Henry Cecil Ranson McBay Chair in Space Science

NASA Technical Reports Server (NTRS)

Bota, Kofi B.; King, James, Jr.

1999-01-01

The goals and objectives of the Henry Cecil Ransom McBay Chair in Space Sciences were to: (1) provide leadership in developing and expanding Space Science curriculum; (2) contribute to the research and education endeavors of NASA's Mission to Planet Earth program; (3) expand opportunities for education and hands-on research in Space and Earth Sciences; (4) enhance scientific and technological literacy at all educational levels and to increase awareness of opportunities in the Space Sciences; and (5) develop a pipeline, starting with high school, of African American students who will develop into a cadre of well-trained scientists with interest in Space Science Research and Development.

The Heuristic Method, Precursor of Guided Inquiry: Henry Armstrong and British Girls' Schools, 1890-1920

ERIC Educational Resources Information Center

Rayner-Canham, Geoff; Rayner-Canham, Marelene

2015-01-01

Though guided-inquiry learning, discovery learning, student-centered learning, and problem-based learning are commonly believed to be recent new approaches to the teaching of chemistry, in fact, the concept dates back to the late 19th century. Here, we will show that it was the British chemist, Henry Armstrong, who pioneered this technique,…

Documentation for the machine-readable version of the Henry Draper Catalogue (edition 1985)

NASA Technical Reports Server (NTRS)

Roman, N. G.; Warren, W. H., Jr.

1985-01-01

An updated, corrected and extended machine-readable version of the catalog is described. Published and unpublished errors discovered in the previous version was corrected; letters indicating supplemental stars in the BD have been moved to a new byte to distinguish them from double-star components; and the machine readable portion of The Henry Draper Extension (HDE) (HA 100) was converted to the same format as the main catalog, with additional data added as necessary.

Modified circular velocity law

NASA Astrophysics Data System (ADS)

Djeghloul, Nazim

2018-05-01

A modified circular velocity law is presented for a test body orbiting around a spherically symmetric mass. This law exhibits a distance scale parameter and allows to recover both usual Newtonian behaviour for lower distances and a constant velocity limit at large scale. Application to the Galaxy predicts the known behaviour and also leads to a galactic mass in accordance with the measured visible stellar mass so that additional dark matter inside the Galaxy can be avoided. It is also shown that this circular velocity law can be embedded in a geometrical description of spacetime within the standard general relativity framework upon relaxing the usual asymptotic flatness condition. This formulation allows to redefine the introduced Newtonian scale limit in term of the central mass exclusively. Moreover, a satisfactory answer to the galactic escape speed problem can be provided indicating the possibility that one can also get rid of dark matter halo outside the Galaxy.

Simulating Supercapacitors: Can We Model Electrodes As Constant Charge Surfaces?

PubMed

Merlet, Céline; Péan, Clarisse; Rotenberg, Benjamin; Madden, Paul A; Simon, Patrice; Salanne, Mathieu

2013-01-17

Supercapacitors based on an ionic liquid electrolyte and graphite or nanoporous carbon electrodes are simulated using molecular dynamics. We compare a simplified electrode model in which a constant, uniform charge is assigned to each carbon atom with a realistic model in which a constant potential is applied between the electrodes (the carbon charges are allowed to fluctuate). We show that the simulations performed with the simplified model do not provide a correct description of the properties of the system. First, the structure of the adsorbed electrolyte is partly modified. Second, dramatic differences are observed for the dynamics of the system during transient regimes. In particular, upon application of a constant applied potential difference, the increase in the temperature, due to the Joule effect, associated with the creation of an electric current across the cell follows Ohm's law, while unphysically high temperatures are rapidly observed when constant charges are assigned to each carbon atom.

Adsorption of xenon and krypton on shales

NASA Technical Reports Server (NTRS)

Podosek, F. A.; Bernatowicz, T. J.; Kramer, F. E.

1981-01-01

A method that uses a mass spectrometer as a manometer is employed in the measurement of Xe and Kr adsorption parameters on shales and related samples, where gas partial pressures were lower than 10 to the -11th atm, corresponding adsorption coverages are only small fractions of a monolayer, and Henry's Law behavior is expected and observed. Results show heats of adsorption in the 2-7 kcal/mol range, and Henry constants at 0-25 C of 1 cu cm STP/g per atmosphere are extrapolated. Although the adsorption properties obtained are variable by sample, the range obtained suggests that shales may be capable of an equilibrium adsorption with modern air high enough to account for a significant fraction of the atmospheric inventory of Xe, and perhaps even of Kr. This effect will nevertheless not account for the factor-of-25 defficiency of atmospheric Xe, in comparison with the planetary gas patterns observed in meteorites.

Simulation evaluation of a speed-guidance law for Harrier approach transitions

NASA Technical Reports Server (NTRS)

Merrick, Vernon K.; Moralez, Ernesto; Stortz, Michael W.; Hardy, Gordon H.; Gerdes, Ronald M.

1991-01-01

An exponential-deceleration speed guidance law is formulated which mimics the technique currently used by Harrier pilots to perform decelerating approaches to a hover. This guidance law was tested along with an existing two-step constant deceleration speed guidance law, using a fixed-base piloted simulator programmed to represent a YAV-8B Harrier. Decelerating approaches to a hover at a predetermined station-keeping point were performed along a straight (-3 deg glideslope) path in headwinds up to 40 knots and turbulence up to 6 ft./sec. Visibility was fixed at one-quarter nautical mile and 100 ft. cloud ceiling. Three Harrier pilots participated in the experiment. Handling qualities with the aircraft equipped with the standard YAV-8B rate damped attitude stability augmentation system were adequate (level 2) using either speed guidance law. However, the exponential deceleration speed guidance law was rated superior to the constant-deceleration speed guidance law by a Cooper-Harper handling qualities rating of about one unit independent of the level of wind and turbulence. Replacing the attitude control system of the YAV-8B with a high fidelity model following attitude flight controller increased the approach accuracy and reduced the pilot workload. With one minor exception, the handling qualities for the approach were rated satisfactory (level 1). It is concluded that the exponential deceleration speed guidance law is the most cost effective.

A simple thermodynamic model useful for calculating gas solubilities in water/brine/hydrocarbon mixtures from 0 to 250 C and 1 to 150 bars

NASA Astrophysics Data System (ADS)

Perez, R. J.; Shevalier, M.; Hutcheon, I.

2004-05-01

Gas solubility is of considerable interest, not only for the theoretical understanding of vapor-liquid equilibria, but also due to extensive applications in combined geochemical, engineering, and environmental problems, such as greenhouse gas sequestration. Reliable models for gas solubility calculations in salt waters and hydrocarbons are also valuable when evaluating fluid inclusions saturated with gas components. We have modeled the solubility of methane, ethane, hydrogen, carbon dioxide, hydrogen sulfide, and five other gases in a water-brine-hydrocarbon system by solving a non-linear system of equations composed by modified Henry's Law Constants (HLC), gas fugacities, and assuming binary mixtures. HLCs are a function of pressure, temperature, brine salinity, and hydrocarbon density. Experimental data of vapor pressures and mutual solubilities of binary mixtures provide the basis for the calibration of the proposed model. It is demonstrated that, by using the Setchenow equation, only a relatively simple modification of the pure water model is required to assess the solubility of gases in brine solutions. Henry's Law constants for gases in hydrocarbons are derived using regular solution theory and Ostwald coefficients available from the literature. We present a set of two-parameter polynomial expressions, which allow simple computation and formulation of the model. Our calculations show that solubility predictions using modified HLCs are acceptable within 0 to 250 C, 1 to 150 bars, salinity up to 5 molar, and gas concentrations up to 4 molar. Our model is currently being used in the IEA Weyburn CO2 monitoring and storage project.

The Evolution of the Exponent of Zipf's Law in Language Ontogeny

PubMed Central

Baixeries, Jaume; Elvevåg, Brita; Ferrer-i-Cancho, Ramon

2013-01-01

It is well-known that word frequencies arrange themselves according to Zipf's law. However, little is known about the dependency of the parameters of the law and the complexity of a communication system. Many models of the evolution of language assume that the exponent of the law remains constant as the complexity of a communication systems increases. Using longitudinal studies of child language, we analysed the word rank distribution for the speech of children and adults participating in conversations. The adults typically included family members (e.g., parents) or the investigators conducting the research. Our analysis of the evolution of Zipf's law yields two main unexpected results. First, in children the exponent of the law tends to decrease over time while this tendency is weaker in adults, thus suggesting this is not a mere mirror effect of adult speech. Second, although the exponent of the law is more stable in adults, their exponents fall below 1 which is the typical value of the exponent assumed in both children and adults. Our analysis also shows a tendency of the mean length of utterances (MLU), a simple estimate of syntactic complexity, to increase as the exponent decreases. The parallel evolution of the exponent and a simple indicator of syntactic complexity (MLU) supports the hypothesis that the exponent of Zipf's law and linguistic complexity are inter-related. The assumption that Zipf's law for word ranks is a power-law with a constant exponent of one in both adults and children needs to be revised. PMID:23516390

Development of a Career Student Guide for the Tech Prep Program for Henry County High School.

ERIC Educational Resources Information Center

Winchester, Ruth Ann

This practicum report describes the research conducted in preparation for developing a career student guide to acquaint students attending Henry County High School (HCHS) in McDonough, Georgia, with the school's new tech prep program. Chapters 1 and 2 contain background information about HCHS' tech prep program and a review of literature regarding…

Scalar field and time varying cosmological constant in f(R,T) gravity for Bianchi type-I universe

NASA Astrophysics Data System (ADS)

Singh, G. P.; Bishi, Binaya K.; Sahoo, P. K.

2016-04-01

In this article, we have analysed the behaviour of scalar field and cosmological constant in $f(R,T)$ theory of gravity. Here, we have considered the simplest form of $f(R,T)$ i.e. $f(R,T)=R+2f(T)$, where $R$ is the Ricci scalar and $T$ is the trace of the energy momentum tensor and explored the spatially homogeneous and anisotropic Locally Rotationally Symmetric (LRS) Bianchi type-I cosmological model. It is assumed that the Universe is filled with two non-interacting matter sources namely scalar field (normal or phantom) with scalar potential and matter contribution due to $f(R,T)$ action. We have discussed two cosmological models according to power law and exponential law of the volume expansion along with constant and exponential scalar potential as sub models. Power law models are compatible with normal (quintessence) and phantom scalar field whereas exponential volume expansion models are compatible with only normal (quintessence) scalar field. The values of cosmological constant in our models are in agreement with the observational results. Finally, we have discussed some physical and kinematical properties of both the models.

anti-Selective Asymmetric Henry Reaction Catalyzed by a Heterobimetallic Cu-Sm-Aminophenol Sulfonamide Complex.

PubMed

Li, Yang; Deng, Ping; Zeng, Youmao; Xiong, Yan; Zhou, Hui

2016-04-01

A novel heterobimetallic Cu/Sm/aminophenol sulfonamide complex has been developed by a convenient one-pot method for the anti-selective asymmetric Henry reaction. The corresponding anti-β-nitro alcohols are obtained in up to 99% yield, >30:1 dr, and 98% ee. The results of control experiments and ESI-MS analysis of the complex indicate that the monomeric bimetallic Cu/Sm/1 complex would be the active species.

Victor Henri: 111 years of his equation.

PubMed

Cornish-Bowden, Athel; Mazat, Jean-Pierre; Nicolas, Serge

2014-12-01

Victor Henri's great contribution to the understanding of enzyme kinetics and mechanism is not always given the credit that it deserves. In addition, his earlier work in experimental psychology is totally unknown to biochemists, and his later work in spectroscopy and photobiology almost equally so. Applying great rigour to his analysis he succeeded in obtaining a model of enzyme action that explained all of the observations available to him, and he showed why the considerable amount of work done in the preceding decade had not led to understanding. His view was that only physical chemistry could explain the behaviour of enzymes, and that models should be judged in accordance with their capacity not only to explain previously known facts but also to predict new observations against which they could be tested. The kinetic equation usually attributed to Michaelis and Menten was in reality due to him. His thesis of 1903 is now available in English. Copyright © 2014 Elsevier B.V. and Société française de biochimie et biologie Moléculaire (SFBBM). All rights reserved.

76 FR 63906 - Henry Gordy International, Inc., Provisional Acceptance of a Settlement Agreement and Order

Federal Register 2010, 2011, 2012, 2013, 2014

2011-10-14

...'' (``Target Set''). Each Target Set consisted of the following: A toy gun; soft, pliable, plastic toy darts... report of a death involving a Target Set on or about May 1, 2006, after an 8-year-old boy choked on a dart and died on March 9, 2006. 8. In response to the death reported on or about May 1, 2006, Henry...

Copper-Catalyzed Enantioselective Henry Reaction of β,γ-Unsaturated α-Ketoesters with Nitromethane in Water.

PubMed

Li, Yanan; Huang, Yekai; Gui, Yang; Sun, Jianan; Li, Jindong; Zha, Zhenggen; Wang, Zhiyong

2017-12-01

A highly enantioselective Henry reaction of β,γ-unsaturated α-ketoesters with nitromethane in water by virtue of chiral copper complexes has been developed. A series of unsaturated β-nitro-α-hydroxy esters bearing tetrasubstituted carbon stereocenters were obtained exclusively with high yields and excellent enantioselectivities. This method could avoid tedious anaerobic anhydrous manipulation and reduce the environmental pollution caused by organic solvents.

Timing of continuous motor imagery: the two-thirds power law originates in trajectory planning.

PubMed

Karklinsky, Matan; Flash, Tamar

2015-04-01

The two-thirds power law, v = γκ(-1/3), expresses a robust local relationship between the geometrical and temporal aspects of human movement, represented by curvature κ and speed v, with a piecewise constant γ. This law is equivalent to moving at a constant equi-affine speed and thus constitutes an important example of motor invariance. Whether this kinematic regularity reflects central planning or peripheral biomechanical effects has been strongly debated. Motor imagery, i.e., forming mental images of a motor action, allows unique access to the temporal structure of motor planning. Earlier studies have shown that imagined discrete movements obey Fitts's law and their durations are well correlated with those of actual movements. Hence, it is natural to examine whether the temporal properties of continuous imagined movements comply with the two-thirds power law. A novel experimental paradigm for recording sparse imagery data from a continuous cyclic tracing task was developed. Using the likelihood ratio test, we concluded that for most subjects the distributions of the marked positions describing the imagined trajectory were significantly better explained by the two-thirds power law than by a constant Euclidean speed or by two other power law models. With nonlinear regression, the β parameter values in a generalized power law, v = γκ(-β), were inferred from the marked position records. This resulted in highly variable yet mostly positive β values. Our results imply that imagined trajectories do follow the two-thirds power law. Our findings therefore support the conclusion that the coupling between velocity and curvature originates in centrally represented motion planning. Copyright © 2015 the American Physiological Society.

Some Dynamical Effects of the Cosmological Constant

NASA Astrophysics Data System (ADS)

Axenides, M.; Floratos, E. G.; Perivolaropoulos, L.

Newton's law gets modified in the presence of a cosmological constant by a small repulsive term (antigravity) that is proportional to the distance. Assuming a value of the cosmological constant consistent with the recent SnIa data (Λ~=10-52 m-2), we investigate the significance of this term on various astrophysical scales. We find that on galactic scales or smaller (less than a few tens of kpc), the dynamical effects of the vacuum energy are negligible by several orders of magnitude. On scales of 1 Mpc or larger however we find that the vacuum energy can significantly affect the dynamics. For example we show that the velocity data in the local group of galaxies correspond to galactic masses increased by 35% in the presence of vacuum energy. The effect is even more important on larger low density systems like clusters of galaxies or superclusters.

Rapid nondestructive spectrometric measurement of temperature-dependent gas-liquid solubility equilibria.

PubMed

Ma, Jian; Dasgupta, Purnendu K; Yang, Bingcheng

2011-02-01

Gas-liquid solubility equilibria (Henry's Law behavior) are of basic interest to many different areas. Temperature-dependent aqueous solubilities of various organic compounds are of fundamental importance in many branches of environmental science. In a number of situations, the gas/dissolved solute of interest has characteristic spectroscopic absorption that is distinct from that of the solvent. For such cases, we report facile nondestructive rapid measurement of the temperature-dependent Henry's law constant (K(H)) in a static sealed spectrometric cell. Combined with a special cell design, multiwavelength measurement permits a large range of K(H) to be spanned. It is possible to derive the K(H) values from the absorbance measured in the gas phase only, the liquid phase only (preferred), and both phases. Underlying principles are developed, and all three approaches are illustrated for a solute like acetone in water. A thermostatic spectrophotometer cell compartment, widely used and available, facilitates rapid temperature changes and allows rapid temperature-dependent equilibrium measurements. Applicability is shown for both acetone and methyl isobutyl ketone. Very little sample is required for the measurement; the K(H) for 4-hydroxynonenal, a marker for oxidative stress, is measured to be 56.9 ± 2.6 M/atm (n = 3) at 37.4 °C with 1 mg of the material available.

The solvation radius of silicate melts based on the solubility of noble gases and scaled particle theory.

PubMed

Ottonello, Giulio; Richet, Pascal

2014-01-28

The existing solubility data on noble gases in high-temperature silicate melts have been analyzed in terms of Scaling Particle Theory coupled with an ab initio assessment of the electronic, dispersive, and repulsive energy terms based on the Polarized Continuum Model (PCM). After a preliminary analysis of the role of the contracted Gaussian basis sets and theory level in reproducing appropriate static dipole polarizabilities in a vacuum, we have shown that the procedure returns Henry's law constants consistent with the values experimentally observed in water and benzene at T = 25 °C and P = 1 bar for the first four elements of the series. The static dielectric constant (ɛ) of the investigated silicate melts and its optical counterpart (ɛ(∞)) were then resolved through the application of a modified form of the Clausius-Mossotti relation. Argon has been adopted as a probe to depict its high-T solubility in melts through an appropriate choice of the solvent diameter σs, along the guidelines already used in the past for simple media such as water or benzene. The σs obtained was consistent with a simple functional form based on the molecular volume of the solvent. The solubility calculations were then extended to He, Ne, and Kr, whose dispersive and repulsive coefficients are available from theory and we have shown that their ab initio Henry's constants at high T reproduce the observed increase with the static polarizability of the series element with reasonable accuracy. At room temperature (T = 25 °C) the calculated Henry's constants of He, Ne, Ar, and Kr in the various silicate media predict higher solubilities than simple extrapolations (i.e., Arrhenius plots) based on high-T experiments and give rise to smooth trends not appreciably affected by the static polarizabilities of the solutes. The present investigation opens new perspectives on a wider application of PCM theory which can be extended to materials of great industrial interest at the core of

Exact Electromagnetic Fields Produced by a Finite Wire with Constant Current

ERIC Educational Resources Information Center

Jimenez, J. L.; Campos, I.; Aquino, N.

2008-01-01

We solve exactly the problem of calculating the electromagnetic fields produced by a finite wire with a constant current, by using two methods: retarded potentials and Jefimenko's formalism. One result in this particular case is that the usual Biot-Savart law of magnetostatics gives the correct magnetic field of the problem. We also show…

On New Rhetoric, John Henry Newman and the Language of Metaphors: Implications for Branding Higher Education

ERIC Educational Resources Information Center

Lawler-Brunner, Jennifer Lynne

2012-01-01

This project interprets how John Henry Newman's (1801-1890) system of thought informs the philosophical and theoretical grounds for rhetorical praxis in the marketplace. His seminal lessons in "An Essay in Aid of a Grammar of Assent" (1870) and "The Idea of a University" (1873 ed.) demonstrate the metaphoric power of words…

Combating child obesity: impact of HENRY on parenting and family lifestyle.

PubMed

Willis, T A; George, J; Hunt, C; Roberts, K P J; Evans, C E L; Brown, R E; Rudolf, M C J

2014-10-01

One-quarter of children in England are overweight/obese at school entry. We investigated the impact of a programme designed to provide parents of infants and preschool children with the skills required for a healthier family lifestyle. A cohort of families was followed across the 8-week HENRY (Health Exercise Nutrition for the Really Young) parent course at nine locations in England. Seventy-seven parents enrolled on the course, of which 71 agreed to complete questionnaires addressing eating behaviours, dietary intake and parental self-efficacy. Pre- and post-course data was available from 60 (84.5%) parents (8-week follow-up data from 58 parents) and was analysed using repeated measures analyses. Significant changes were observed, with most sustained at follow-up. Parents reported increased self-efficacy and ability to encourage good behaviour (P < 0.001). Increased consumption of fruits and vegetables was reported in both children and adults, together with reduced consumption of sweets, cakes and fizzy drinks in adults (all P < 0.01). There were also positive changes in eating behaviours (e.g., frequency of family mealtimes and eating while watching television or in response to negative emotion [P < 0.01] ) and reduced screen time in adults (P < 0.001). The results build upon earlier evaluation, indicating that the HENRY intervention has a beneficial impact upon the families of infants and preschool children. Furthermore, the findings suggest that positive changes inspired by the programme can be maintained beyond its completion. Such changes may serve to protect against later obesity. © 2013 The Authors. Pediatric Obesity © 2013 International Association for the Study of Obesity.

Speculative Truth - Henry Cavendish, Natural Philosophy, and the Rise of Modern Theoretical Science

NASA Astrophysics Data System (ADS)

McCormmach, Russell

2004-03-01

With a never-before published paper by Lord Henry Cavendish, as well as a biography on him, this book offers a fascinating discourse on the rise of scientific attitudes and ways of knowing. A pioneering British physicist in the late 18th and early 19th centuries, Cavendish was widely considered to be the first full-time scientist in the modern sense. Through the lens of this unique thinker and writer, this book is about the birth of modern science.

Deviations from Newton's law in supersymmetric large extra dimensions

NASA Astrophysics Data System (ADS)

Callin, P.; Burgess, C. P.

2006-09-01

Deviations from Newton's inverse-squared law at the micron length scale are smoking-gun signals for models containing supersymmetric large extra dimensions (SLEDs), which have been proposed as approaches for resolving the cosmological constant problem. Just like their non-supersymmetric counterparts, SLED models predict gravity to deviate from the inverse-square law because of the advent of new dimensions at sub-millimeter scales. However SLED models differ from their non-supersymmetric counterparts in three important ways: (i) the size of the extra dimensions is fixed by the observed value of the dark energy density, making it impossible to shorten the range over which new deviations from Newton's law must be seen; (ii) supersymmetry predicts there to be more fields in the extra dimensions than just gravity, implying different types of couplings to matter and the possibility of repulsive as well as attractive interactions; and (iii) the same mechanism which is purported to keep the cosmological constant naturally small also keeps the extra-dimensional moduli effectively massless, leading to deviations from general relativity in the far infrared of the scalar-tensor form. We here explore the deviations from Newton's law which are predicted over micron distances, and show the ways in which they differ and resemble those in the non-supersymmetric case.

Disposable Youth/Damaged Democracy: Youth, Neoliberalism, and the Promise of Pedagogy in the Work of Henry Giroux

ERIC Educational Resources Information Center

Robbins, Christopher G.

2012-01-01

Perhaps more extensively and provocatively than any other contemporary theorist, Henry Giroux has theorized the relationship between youth and democratic public life. Beginning arguably with his first book, Ideology, Culture, and the Process of Schooling (Temple University Press, 1981), and continuing across a number of critically acclaimed works…

A modification of Murray's law for shear-thinning rheology.

PubMed

McGah, Patrick M; Capobianchi, Massimo

2015-05-01

This study reformulates Murray's well-known principle of minimum work as applied to the cardiovascular system to include the effects of the shear-thinning rheology of blood. The viscous behavior is described using the extended modified power law (EMPL), which is a time-independent, but shear-thinning rheological constitutive equation. The resulting minimization problem is solved numerically for typical parameter ranges. The non-Newtonian analysis still predicts the classical cubic diameter dependence of the volume flow rate and the cubic branching law. The current analysis also predicts a constant wall shear stress throughout the vascular tree, albeit with a numerical value about 15-25% higher than the Newtonian analysis. Thus, experimentally observed deviations from the cubic branching law or the predicted constant wall shear stress in the vasculature cannot likely be attributed to blood's shear-thinning behavior. Further differences between the predictions of the non-Newtonian and the Newtonian analyses are highlighted, and the limitations of the Newtonian analysis are discussed. Finally, the range and limits of applicability of the current results as applied to the human arterial tree are also discussed.

Entanglement Generation and Area Law with Long-Range Interactions

NASA Astrophysics Data System (ADS)

Gorshkov, Alexey

In short-range interacting systems, the speed at which entanglement can be established between two separated points is limited by a constant Lieb-Robinson velocity. This same limit also leads to the so-called area-law bound on entanglement in one-dimensional gapped short-range interacting systems. In this talk, we will show that long-range interactions that decay with distance as a power law allow for faster entanglement generation and state transfer. We will also present sufficient conditions for the area law in gapped systems to hold even in the presence of long-range interactions.

Henri Wallon's Theory of Early Child Development: The Role of Emotions

PubMed

Veer

1996-12-01

The present paper gives an account of part of the stage theory of early child development of the French theorist Henri Wallon (1879-1962). Unlike his contemporary Jean Piaget, Wallon concentrated his efforts upon a description of the child's emotional development and the role emotions play in establishing the bond between child and caregiver. The description of Wallon's stage theory is preceded by biographical information and a presentation of his methodological views. It is argued that Wallon's theory is unique in its focus, exerted influence upon theorists such as Lev Vygotsky, and is basically compatible with modern insights about the nature of child development and the growth of intersubjectivity.

Modeling and controlling a robotic convoy using guidance laws strategies.

PubMed

Belkhouche, Fethi; Belkhouche, Boumediene

2005-08-01

This paper deals with the problem of modeling and controlling a robotic convoy. Guidance laws techniques are used to provide a mathematical formulation of the problem. The guidance laws used for this purpose are the velocity pursuit, the deviated pursuit, and the proportional navigation. The velocity pursuit equations model the robot's path under various sensors based control laws. A systematic study of the tracking problem based on this technique is undertaken. These guidance laws are applied to derive decentralized control laws for the angular and linear velocities. For the angular velocity, the control law is directly derived from the guidance laws after considering the relative kinematics equations between successive robots. The second control law maintains the distance between successive robots constant by controlling the linear velocity. This control law is derived by considering the kinematics equations between successive robots under the considered guidance law. Properties of the method are discussed and proven. Simulation results confirm the validity of our approach, as well as the validity of the properties of the method. Index Terms-Guidance laws, relative kinematics equations, robotic convoy, tracking.

Applicability of Child-Langmuir collision laws for describing a dc cathode sheath in N2O

NASA Astrophysics Data System (ADS)

Lisovskiy, V. A.; Artushenko, E. P.; Yegorenkov, V. D.; Yegorenkov

2014-06-01

It is established which of the Child-Langmuir collision law versions are most appropriate for describing the processes in the cathode sheath in the N2O. At low pressure (up to 0.3 Torr), the Child-Langmuir law version relating to the constant ion mobility holds. At N2O pressure values starting from 0.75 Torr and above, one has to employ the law version for which it is assumed that the ion mean free path within the cathode sheath is constant. In the intermediate pressure range (between 0.3 and 0.75 Torr), neither of the Child-Langmuir law versions gives a correct description of the cathode sheath of the glow discharge in the N2O.

VIDEO: Dr. Henry Rodriguez - Proteogenomics in Cancer Medicine | Office of Cancer Clinical Proteomics Research

Cancer.gov

Dr. Henry Rodriguez, director of the Office of Cancer Clinical Proteomics Research (OCCPR) at NCI, speaks with ecancer television at WIN 2017 about the translation of the proteins expressed in a patient's tumor into a map for druggable targets. By combining genomic and proteomic information (proteogenomics), leading scientists are gaining new insights into ways to detect and treat cancer due to a more complete and unified understanding of complex biological processes.

The Child-Langmuir laws and cathode sheath in the N2O

NASA Astrophysics Data System (ADS)

Lisovskiy, Valeriy; Artushenko, Ekaterina; Yegorenkov, Vladimir

2013-09-01

It is established which of the Child-Langmuir collisional laws are most appropriate for describing the cathode sheath in the N2O. At low pressure p < 0 . 3 Torr the Child-Langmuir law version relating to the constant ion mobility. At p > 0 . 75 Torr one has to employ the law version for which it is assumed that ion mean free path within the cathode sheath is constant. In the intermediate pressure range 0 . 3 < p < 0 . 75 Torr neither of the Child-Langmuir law versions gives a correct description of the cathode sheath in the N2O. The ratio of the normal current density to the gas pressure squared J /p2 , the normal voltage drop and the cathode sheath thickness are determined. For the stainless steel cathode they equals to U = 364 V and pd = 2 . 5 Torr .mm. At large N2O pressure the above ratio remains constant and it amounts to J /p2 = 0.44 mA/(cm .Torr)2 for any inter-electrode gap value we studied. On decreasing the N2O pressure the ratio J /p2 increases and for narrow gaps between electrodes it may approach several or even several tens mA/(cm .Torr)2. and Scientific Center of Physical Technologies, Svobody Sq.6, Kharkov, 61022, Ukraine.

"Undoubtedly a Powerful Influence": Victor Henry's "Antinomies linguistiques" (1896) with an Annotated Translation of the First Chapter.

ERIC Educational Resources Information Center

Joseph, John E.

1996-01-01

Discusses Victor Henry's innovative presentation of some underlying contradictions in the premises on which linguistics is founded, cast in the Kantian form of antinomies. The review argues that no science remains more strongly contested than linguistics, a science whose origins are paradoxical and that contains outdated concepts. (30 references)…

All Are Worthy to Know the Earth: Henry De la Beche and the Origin of Geological Literacy

ERIC Educational Resources Information Center

Clary, Renee M.; Wandersee, James H.

2009-01-01

Henry T. De la Beche (1796-1855) began his geological career within an elite circle (Geological Society of London, 1817; FRS, 1819), collaborating with influential gentlemen geologists and publishing original research. When his independent income dwindled, De la Beche managed to secure governmental funding for his mapping projects. This led to…

Ohm's law for a current sheet

NASA Technical Reports Server (NTRS)

Lyons, L. R.; Speiser, T. W.

1985-01-01

The paper derives an Ohm's law for single-particle motion in a current sheet, where the magnetic field reverses in direction across the sheet. The result is considerably different from the resistive Ohm's law often used in MHD studies of the geomagnetic tail. Single-particle analysis is extended to obtain a self-consistency relation for a current sheet which agrees with previous results. The results are applicable to the concept of reconnection in that the electric field parallel to the current is obtained for a one-dimensional current sheet with constant normal magnetic field. Dissipated energy goes directly into accelerating particles within the current sheet.

Systematic Breakdown of Amontons' Law of Friction for an Elastic Object Locally Obeying Amontons' Law

PubMed Central

Otsuki, Michio; Matsukawa, Hiroshi

2013-01-01

In many sliding systems consisting of solid object on a solid substrate under dry condition, the friction force does not depend on the apparent contact area and is proportional to the loading force. This behaviour is called Amontons' law and indicates that the friction coefficient, or the ratio of the friction force to the loading force, is constant. Here, however, using numerical and analytical methods, we show that Amontons' law breaks down systematically under certain conditions for an elastic object experiencing a friction force that locally obeys Amontons' law. The macroscopic static friction coefficient, which corresponds to the onset of bulk sliding of the object, decreases as pressure or system length increases. This decrease results from precursor slips before the onset of bulk sliding, and is consistent with the results of certain previous experiments. The mechanisms for these behaviours are clarified. These results will provide new insight into controlling friction. PMID:23545778

Stopping time: Henry Fox Talbot and the origins of freeze-frame photography.

PubMed

Ramalingam, Chitra

2008-09-01

As an image-making tool for scientists studying the transient, instantaneous photography has long been seen as opening up a visual realm previously inaccessible to the inferior testimony of the human eye. But when photographic pioneer Henry Fox Talbot took the first photograph of a moving object by the light of an electric spark in 1851, he was guided by existing visual practices designed to create instantaneous vision in the eye itself. Exploring the background behind the peculiar subject of his experiment - a mechanically spinning disc - reveals a hidden prehistory of spark-illuminated photography: physicists' pre-photographic techniques for stopping time.

Development of guidance laws for a variable-speed missile

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gazit, R.; Gutman, S.

1991-05-01

The most used guidance law for short-range homing missiles is proportional navigation (PN). In PN, the acceleration command is proportional to the line-of-sight (LOS) angular velocity. Indeed, if a missile and a target move on a collision course with constant speeds, the LOS rate is zero. The speed of a highly maneuverable modern missile varies considerably during flight. The performance of PN is far from being satisfactory in that case. In this article the collision course for a variable-speed missile is analyzed and a guidance law that steers the heading of the missile to the collision course is defined. Guidancemore » laws based on optimal control and differential game formulations are developed, and note that both optimal laws coincide with the Guidance to Collision law at impact. The performance improvement of the missile using the new guidance law as compared to PN is demonstrated. 19 refs.« less

A relationship between dissolved CO2 and the non-volatile chemistry of rainwater.

NASA Astrophysics Data System (ADS)

Durham, Brian; Pfrang, Christian

2016-04-01

Measurements of a volatile acid component in UK rainwater in 2009 implicated CO2, and speculated `a concentrating mechanism (that) could mean that this weakly soluble molecule is recycled at a faster rate than inferred by its Henry's Law constant'. Last year's EGU Presentation 2015-3386 confirmed that the `saturated CO2 content (of UK rainwater) is insignificant, the bulk transport being the volatile component'. However the atmospheric capture mechanism remains enigmatic. For pure water, improved temperature control has discounted the predicted upturn in the Henry coefficient for 450Pa CO2 as the temperature approached freezing point (http://presentations.copernicus.org/EGU2015-3386_presentation.pptx), and the focus has therefore turned to rainwater chemistry. For a mid-range sample the Henry value was: • significantly higher than pure water at 20'C; • but decreasing with lower temperatures. The higher Henry constant might suggest that, as an acid anhydride, CO2 is subject to selective capture where cloud water is alkaline (terrestrial dust or marine aerosol). Analysis has however shown no simple relationship between [CO2]aq and either acidity or conductivity of the carrier water. Seeking therefore a coherent distribution, stripped CO2 was plotted against Δ[H+], from which this paper presents a tight wedge-shaped distribution of 263 UK rain/snow events. The inference is that [CO2]aq is not related directly to [H+], but possibly to Group 1 and 2 cations from marine aerosol that are buffering the cloud water acidity. By contrast, the unexpected decrease in CO2 yield with lower temperatures proved to be an artefact of a progressively slower rate of de-gassing, cooler samples still equilibrating after 100 minutes. An ultrasound stripper is therefore being developed to speed the Henry measurements, and for reproducibility it is proposed to dilute a proprietary `standard Atlantic sea water' to a representative range of conductivities, to be called `standard

Effect of confinement in nano-porous materials on the solubility of a supercritical gas

NASA Astrophysics Data System (ADS)

Hu, Yaofeng; Huang, Liangliang; Zhao, Shuangliang; Liu, Honglai; Gubbins, Keith E.

2016-11-01

By combining Gibbs Ensemble Monte Carlo simulations and density functional theory, we investigate the influence of confinement in a slit-shaped carbon pore on the solubility of a supercritical solute gas in a liquid solvent. In the cases studied here, competing adsorption of the solvent and solute determines whether the solubility is enhanced or suppressed for larger pores. We find that the solubility in the confined system is strongly dependent on pore width, and that molecular packing effects are important for small pore widths. In addition, the solubility decreases on increase in the temperature, as for the bulk mixture, but the rate of decrease is greater in the pore due to a decrease in the partial molar enthalpy of the solute in the pore; this effect becomes greater as pore width is decreased. The solubility is increased on increasing the bulk pressure of the gas in equilibrium with the pore, and obeys Henry's law at lower pressures. However, the Henry constant differs significantly from that for the bulk mixture, and the range of pressure over which Henry's law applies is reduced relative to that for the bulk mixture. The latter observation indicates that solute-solute interactions become more important in the pore than for the bulk at a given bulk pressure. Finally, we note that different authors use different definitions of the solubility in pores, leading to some confusion over the reported phenomenon of 'oversolubility'. We recommend that solubility be defined as the overall mole fraction of solute in the pores, since it takes into account the increase in density of the solvent in the pores, and avoids ambiguity in the definition of the pore volume.

"Young People Are No Longer at Risk--They Are the Risk": Henry Giroux's "Youth in a Suspect Society"

ERIC Educational Resources Information Center

McClennen, Sophia A.

2012-01-01

This article analyzes Henry Giroux's recent book Youth in a Suspect Society: democracy or disposability? (Palgrave, 2009) and situates it within his post-9/11 critical interventions. Giroux has focused his recent work on theorizing, critiquing and challenging the confluence of militarization, corporatization and right-wing ideology that has…

Inverse modeling for seawater intrusion in coastal aquifers: Insights about parameter sensitivities, variances, correlations and estimation procedures derived from the Henry problem

USGS Publications Warehouse

Sanz, E.; Voss, C.I.

2006-01-01

Inverse modeling studies employing data collected from the classic Henry seawater intrusion problem give insight into several important aspects of inverse modeling of seawater intrusion problems and effective measurement strategies for estimation of parameters for seawater intrusion. Despite the simplicity of the Henry problem, it embodies the behavior of a typical seawater intrusion situation in a single aquifer. Data collected from the numerical problem solution are employed without added noise in order to focus on the aspects of inverse modeling strategies dictated by the physics of variable-density flow and solute transport during seawater intrusion. Covariances of model parameters that can be estimated are strongly dependent on the physics. The insights gained from this type of analysis may be directly applied to field problems in the presence of data errors, using standard inverse modeling approaches to deal with uncertainty in data. Covariance analysis of the Henry problem indicates that in order to generally reduce variance of parameter estimates, the ideal places to measure pressure are as far away from the coast as possible, at any depth, and the ideal places to measure concentration are near the bottom of the aquifer between the center of the transition zone and its inland fringe. These observations are located in and near high-sensitivity regions of system parameters, which may be identified in a sensitivity analysis with respect to several parameters. However, both the form of error distribution in the observations and the observation weights impact the spatial sensitivity distributions, and different choices for error distributions or weights can result in significantly different regions of high sensitivity. Thus, in order to design effective sampling networks, the error form and weights must be carefully considered. For the Henry problem, permeability and freshwater inflow can be estimated with low estimation variance from only pressure or only

Searching for Politics with Henry Giroux: Through Cultural Studies to Public Pedagogy and the "Terror of Neoliberalism"

ERIC Educational Resources Information Center

Robbins, Christopher G.

2009-01-01

Henry A. Giroux is recognized as one of the fifty most significant thinkers on education in the 20th century. He is also considered a scholar of immense influence in a number of fields internationally, hardly an inconsequential accolade in a century noted for a glut of educational and social thinkers. Yet, its wide-ranging and ever-expanding…

The venality of human body parts and products in French law and common law.

PubMed

Haoulia, Naima

2012-03-01

The successive bioethics laws in France have constantly argued that the human body is not for sale and consecrated an absolute principle of free and anonymous donations, whether of semen, ova, blood, tissues or organs. Nonetheless, this position is not shared by all countries. These legal divergences upset today our moral principles and the development of these practices leads us to question the legal status of human biological material and its gradual commodification. This paper outlines the current law principles that protect people's interests in their bodies, excised body parts and tissues without conferring the rights of full legal ownership in French law and in Common law. Contrary to what many people believe, people do not legally 'own' their bodies, body parts or tissues. However, they do have some legal rights in relation to their bodies and excised body material. For lawyers, the exact relationship people have with their bodies has raised a host of complex questions and long debates about the status we should grant to human body parts. The significance of this issue is due to two reasons:first, because of the imperative protection we have to assure to human dignity and then, because of the economic value which is attached to human products.

Elongational flow of polymer melts at constant strain rate, constant stress and constant force

NASA Astrophysics Data System (ADS)

Wagner, Manfred H.; Rolón-Garrido, Víctor H.

2013-04-01

Characterization of polymer melts in elongational flow is typically performed at constant elongational rate or rarely at constant tensile stress conditions. One of the disadvantages of these deformation modes is that they are hampered by the onset of "necking" instabilities according to the Considère criterion. Experiments at constant tensile force have been performed even more rarely, in spite of the fact that this deformation mode is free from necking instabilities and is of considerable industrial relevance as it is the correct analogue of steady fiber spinning. It is the objective of the present contribution to present for the first time a full experimental characterization of a long-chain branched polyethylene melt in elongational flow. Experiments were performed at constant elongation rate, constant tensile stress and constant tensile force by use of a Sentmanat Extensional Rheometer (SER) in combination with an Anton Paar MCR301 rotational rheometer. The accessible experimental window and experimental limitations are discussed. The experimental data are modelled by using the Wagner I model. Predictions of the steady-start elongational viscosity in constant strain rate and creep experiments are found to be identical, albeit only by extrapolation of the experimental data to Hencky strains of the order of 6. For constant stress experiments, a minimum in the strain rate and a corresponding maximum in the elongational viscosity is found at a Hencky strain of the order of 3, which, although larger than the steady-state value, follows roughly the general trend of the steady-state elongational viscosity. The constitutive analysis also reveals that constant tensile force experiments indicate a larger strain hardening potential than seen in constant elongation rate or constant tensile stress experiments. This may be indicative of the effect of necking under constant elongation rate or constant tensile stress conditions according to the Considère criterion.

The Geometry of Snell's Law

ERIC Educational Resources Information Center

Metz, James

2014-01-01

Light refracts as it travels from one medium to another. The angle of incidence "i" and the angle of refraction "r" are related by Snell's law, sin"i" ÷ sin"r"="k," where "k" is a constant. The diagram in Fig. 1 shows a geometric representation of the formula for light passing from…

Biotrickling filter modeling for styrene abatement. Part 2: Simulating a two-phase partitioning bioreactor.

PubMed

San-Valero, Pau; Dorado, Antonio D; Quijano, Guillermo; Álvarez-Hornos, F Javier; Gabaldón, Carmen

2018-01-01

A dynamic model describing styrene abatement was developed for a two-phase partitioning bioreactor operated as a biotrickling filter (TPPB-BTF). The model was built as a coupled set of two different systems of partial differential equations depending on whether an irrigation or a non-irrigation period was simulated. The maximum growth rate was previously calibrated from a conventional BTF treating styrene (Part 1). The model was extended to simulate the TPPB-BTF based on the hypothesis that the main change associated with the non-aqueous phase is the modification of the pollutant properties in the liquid phase. The three phases considered were gas, a water-silicone liquid mixture, and biofilm. The selected calibration parameters were related to the physical properties of styrene: Henry's law constant, diffusivity, and the gas-liquid mass transfer coefficient. A sensitivity analysis revealed that Henry's law constant was the most sensitive parameter. The model was successfully calibrated with a goodness of fit of 0.94. It satisfactorily simulated the performance of the TPPB-BTF at styrene loads ranging from 13 to 77 g C m -3 h -1 and empty bed residence times of 30-15 s with the mass transfer enhanced by a factor of 1.6. The model was validated with data obtained in a TPPB-BTF removing styrene continuously. The experimental outlet emissions associated to oscillating inlet concentrations were satisfactorily predicted by using the calibrated parameters. Model simulations demonstrated the potential improvement of the mass-transfer performance of a conventional BTF degrading styrene by adding silicone oil. Copyright © 2017 Elsevier Ltd. All rights reserved.

NASA Data Evaluation (2015): Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies

NASA Astrophysics Data System (ADS)

Burkholder, J. B.; Sander, S. P.; Abbatt, J.; Barker, J. R.; Huie, R. E.; Kolb, C. E., Jr.; Kurylo, M. J., III; Orkin, V. L.; Wilmouth, D. M.; Wine, P. H.

2015-12-01

Atmospheric chemistry models must include a large number of processes to accurately describe the temporal and spatial behavior of atmospheric composition. They require a wide range of chemical and physical data (parameters) that describe elementary gas-phase and heterogeneous processes. The review and evaluation of chemical and physical data has, therefore, played an important role in the development of chemical models and in their use in environmental assessment activities. The NASA data panel evaluation has a broad atmospheric focus that includes Ox, O(1D), singlet O2, HOx, NOx, Organic, FOx, ClOx, BrOx, IOx, SOx, and Na reactions, three-body reactions, equilibrium constants, photochemistry, Henry's Law coefficients, aqueous chemistry, heterogeneous chemistry and processes, and thermodynamic parameters. The 2015 evaluation includes critical coverage of ~700 bimolecular reactions, 86 three-body reactions, 33 equilibrium constants, ~220 photochemical species, ~360 aqueous and heterogeneous processes, and thermodynamic parameters for ~800 species with over 5000 literature citations reviewed. Each evaluation includes (1) recommended values (e.g. rate coefficients, absorption cross sections, solubilities, and uptake coefficients) with estimated uncertainty factors and (2) a note describing the available experimental and theoretical data and an explanation for the recommendation. This presentation highlights some of the recent additions to the evaluation that include: (1) expansion of thermochemical parameters, including Hg species, (2) CH2OO (Criegee) chemistry, (3) Isoprene and its major degradation product chemistry, (4) halocarbon chemistry, (5) Henry's law solubility data, and (6) uptake coefficients. In addition, a listing of complete references with the evaluation notes has been implemented. Users of the data evaluation are encouraged to suggest potential improvements and ways that the evaluation can better serve the atmospheric chemistry community.

Geomorphological and hydrological implications of a given hydraulic geometry relationship, beyond the power-law

NASA Astrophysics Data System (ADS)

Kim, JongChun; Paik, Kyungrock

2015-04-01

Channel geometry and hydraulic characteristics of a given river network, i.e., spatio-temporal variability of width, depth, and velocity, can be described as power functional relationships of flow discharge, named 'hydraulic geometry' (Leopold and Maddock, 1953). Many studies have focused on the implication of this power-law itself, i.e., self-similarity, and accordingly its exponents. Coefficients of the power functional relationships, on the contrary, have received little attention. They are often regarded as empirical constants, determined by 'best fitting' to the power-law without significant scientific implications. Here, we investigate and claim that power-law coefficients of hydraulic geometry relationships carry vital information of a given river system. We approach the given problem on the basis of 'basin hydraulic geometry' formulation (Stall and Fok, 1968) which decomposes power-law coefficients into more elementary constants. The linkage between classical power-law relationship (Leopold and Maddock, 1953) and the basin hydraulic geometry is provided by Paik and Kumar (2004). On the basis of this earlier study, it can be shown that coefficients and exponents of power-law hydraulic geometry are interrelated. In this sense, we argue that more elementary constants that constitute both exponents and coefficients carry important messages. In this presentation, we will demonstrate how these elementary constants vary over a wide range of catchments provided from Stall and Fok (1968) and Stall and Yang (1970). Findings of this study can provide new insights on fundamental understanding about hydraulic geometry relationships. Further, we expect that this understanding can help interpretation of hydraulic geometry relationship in the context of flood propagation through a river system as well. Keywords: Hydraulic geometry; Power-law; River network References Leopold, L. B., & Maddock, T. J. (1953). The hydraulic geometry of stream channels and some physiographic

Cooling and Warming Laws: An Exact Analytical Solution

ERIC Educational Resources Information Center

Besson, Ugo

2010-01-01

This paper deals with temperature variations over time of objects placed in a constant-temperature environment in the presence of thermal radiation. After a historical introduction, the paper discusses cooling and warming laws, by taking into account first solely object-environment energy exchange by thermal radiation, and then adding…

A New Rate Law Describing Microbial Respiration

PubMed Central

Jin, Qusheng; Bethke, Craig M.

2003-01-01

The rate of microbial respiration can be described by a rate law that gives the respiration rate as the product of a rate constant, biomass concentration, and three terms: one describing the kinetics of the electron-donating reaction, one for the kinetics of the electron-accepting reaction, and a thermodynamic term accounting for the energy available in the microbe's environment. The rate law, derived on the basis of chemiosmotic theory and nonlinear thermodynamics, is unique in that it accounts for both forward and reverse fluxes through the electron transport chain. Our analysis demonstrates how a microbe's respiration rate depends on the thermodynamic driving force, i.e., the net difference between the energy available from the environment and energy conserved as ATP. The rate laws commonly applied in microbiology, such as the Monod equation, are specific simplifications of the general law presented. The new rate law is significant because it affords the possibility of extrapolating in a rigorous manner from laboratory experiment to a broad range of natural conditions, including microbial growth where only limited energy is available. The rate law also provides a new explanation of threshold phenomena, which may reflect a thermodynamic equilibrium where the energy released by electron transfer balances that conserved by ADP phosphorylation. PMID:12676718

A new rate law describing microbial respiration.

PubMed

Jin, Qusheng; Bethke, Craig M

2003-04-01

The rate of microbial respiration can be described by a rate law that gives the respiration rate as the product of a rate constant, biomass concentration, and three terms: one describing the kinetics of the electron-donating reaction, one for the kinetics of the electron-accepting reaction, and a thermodynamic term accounting for the energy available in the microbe's environment. The rate law, derived on the basis of chemiosmotic theory and nonlinear thermodynamics, is unique in that it accounts for both forward and reverse fluxes through the electron transport chain. Our analysis demonstrates how a microbe's respiration rate depends on the thermodynamic driving force, i.e., the net difference between the energy available from the environment and energy conserved as ATP. The rate laws commonly applied in microbiology, such as the Monod equation, are specific simplifications of the general law presented. The new rate law is significant because it affords the possibility of extrapolating in a rigorous manner from laboratory experiment to a broad range of natural conditions, including microbial growth where only limited energy is available. The rate law also provides a new explanation of threshold phenomena, which may reflect a thermodynamic equilibrium where the energy released by electron transfer balances that conserved by ADP phosphorylation.

Constant Stress Drop Fits Earthquake Surface Slip-Length Data

NASA Astrophysics Data System (ADS)

Shaw, B. E.

2011-12-01

Slip at the surface of the Earth provides a direct window into the earthquake source. A longstanding controversy surrounds the scaling of average surface slip with rupture length, which shows the puzzling feature of continuing to increase with rupture length for lengths many times the seismogenic width. Here we show that a more careful treatment of how ruptures transition from small circular ruptures to large rectangular ruptures combined with an assumption of constant stress drop provides a new scaling law for slip versus length which (1) does an excellent job fitting the data, (2) gives an explanation for the large crossover lengthscale at which slip begins to saturate, and (3) supports constant stress drop scaling which matches that seen for small earthquakes. We additionally discuss how the new scaling can be usefully applied to seismic hazard estimates.

Style and non-style in anatomical illustration: From Renaissance Humanism to Henry Gray.

PubMed

Kemp, Martin

2010-02-01

Style is a familiar category for the analysis of art. It is less so in the history of anatomical illustration. The great Renaissance and Baroque picture books of anatomy illustrated with stylish woodcuts and engravings, such as those by Charles Estienne, Andreas Vesalius and Govard Bidloo, showed figures in dramatic action in keeping with philosophical and theological ideas about human nature. Parallels can be found in paintings of the period, such as those by Titian, Michelangelo and Hans Baldung Grien. The anatomists also claimed to portray the body in an objective manner, and showed themselves as heroes of the discovery of human knowledge. Rembrandt's painting of Dr Nicholas Tulp is the best-known image of the anatomist as hero. The British empirical tradition in the 18th century saw William Cheselden and William Hunter working with techniques of representation that were intended to guarantee detailed realism. The ambition to portray forms life-size led to massive volumes, such as those by Antonio Mascagni. John Bell, the Scottish anatomist, criticized the size and pretensions of the earlier books and argued for a plain style adapted to the needs of teaching and surgery. Henry Gray's famous Anatomy of 1858, illustrated by Henry Vandyke Carter, aspired to a simple descriptive mode of functional representation that avoided stylishness, resulting in a style of its own. Successive editions of Gray progressively saw the replacement of Gray's method and of all his illustrations. The 150th anniversary edition, edited by Susan Standring, radically re-thinks the role of Gray's book within the teaching of medicine.

Solubility and reactivity of HNCO in water: insights into HNCO's fate in the atmosphere

NASA Astrophysics Data System (ADS)

Borduas, N.; Place, B.; Wentworth, G. R.; Abbatt, J. P. D.; Murphy, J. G.

2015-09-01

A growing number of ambient measurements of isocyanic acid (HNCO) are being made, yet little is known about its fate in the atmosphere. To better understand HNCO's loss processes and particularly its atmospheric partitioning behavior, we measure its effective Henry's Law solubility coefficient KHeff with a bubbler experiment using chemical ionization mass spectrometry as the gas phase analytical technique. By conducting experiments at different pH values and temperature, a Henry's Law coefficient KH of 26 ± 2 M atm-1 is obtained, with an enthalpy of dissolution of -34 ± 2 kJ mol-1. Our approach also allows for the determination of HNCO's acid dissociation constant, which we determine to be Ka = 2.1 ± 0.2 × 10-4 M at 298 K. Furthermore, by using ion chromatography to analyze aqueous solution composition, we revisit the hydrolysis kinetics of HNCO at different pH and temperature conditions. Three pH dependent hydrolysis mechanisms are in play and we determine the Arrhenius expressions for each rate to be k1 = (4.4 ± 0.2) × 107 exp (-6000 ± 240/T) M s-1, k2 = (8.9±0.9) × 106 exp (-6770 ± 450/T) s-1 and k3 = (7.2±1.5) × 108 exp (-10 900 ± 1400/T) s-1 where k1 is for HNCO + H+ + H2O → NH4+ + CO2, k2 is for HNCO + H2 O → NH3 + CO2 and k3 is for NCO- + 2H2 O → NH3 + HCO3-. HNCO's lifetime against hydrolysis is therefore estimated to be 10 days to 28 years at pH values, liquid water contents, and temperatures relevant to tropospheric clouds, years in oceans and months in human blood. In all, a better parameterized Henry's Law coefficient and hydrolysis rates of HNCO allow for more accurate predictions of its concentration in the atmosphere and consequently help define exposure of this toxic molecule.

[Dr. Henry Wigderson--the first neurosurgeon in Eretz-Israel].

PubMed

Feinsod, Moshe

2006-07-01

The vision of Hadassah Medical Organization and the Hebrew University in Jerusalem was to establish a University Hospital where clinical excellence and high academic level will be the hallmark of its departments. More than seventy years ago, guided by this spirit, the leaders of the two institutions attempted to establish a department of neurosurgery, which, at the time in only a few countries, was making its initial steps as an independent discipline. It was only during World War II that Hadassah could bring over a specialist in neurosurgery who worked for nearly three years in the Hadassah Hospital on Mount Scopus. This article describes the way Dr. Henry Wigderson was selected to be the first neurosurgeon in Eretz-Israel, his activities and the incorporation of the idea, in spite of the disappointment caused by his departure, that even at times of distress, neurosurgery is not a luxury but an indispensable part of an forward-looking medical institution.

James Henry Marriott: New Zealand's first professional telescope-maker

NASA Astrophysics Data System (ADS)

Orchiston, Wayne; Romick, Carl; Brown, Pendreigh.

2015-11-01

James Henry Marriott was born in London in 1799 and trained as an optician and scientific instrument- maker. In 1842 he emigrated to New Zealand and in January 1843 settled in the newly-established town of Wellington. He was New Zealand's first professional telescope-maker, but we have only been able to locate one telescope made by him while in New Zealand, a brass 1-draw marine telescope with a 44-mm objective, which was manufactured in 1844. In 2004 this marine telescope was purchased in Hawaii by the second author of this paper. In this paper we provide biographical information about Marriott, describe his 1844 marine telescope and speculate on its provenance. We conclude that although he may have been New Zealand's first professional telescope-maker Marriot actually made very few telescopes or other scientific instruments. As such, rather than being recognised as a pioneer of telescope-making in New Zealand he should be remembered as the founder of New Zealand theatre.

Demonstrating Kinematics and Newton's Laws in a Jump

ERIC Educational Resources Information Center

Kamela, Martin

2007-01-01

When students begin the study of Newton's laws they are generally comfortable with static equilibrium type problems, but dynamic examples where forces are not constant are more challenging. The class exercise presented here helps students to develop an intuitive grasp of both the position-velocity-acceleration relation and the force-acceleration…

"Extraordinary Understandings" of Composition at the University of Chicago: Frederick Champion Ward, Kenneth Burke, and Henry W. Sams

ERIC Educational Resources Information Center

Beasley, James P.

2007-01-01

While Richard Weaver, R. S. Crane, Richard McKeon, and Robert Streeter have been most identified with rhetoric at the University of Chicago and its institutional return in the 1950s, the archival record demonstrates that Frederick Champion Ward, dean of the undergraduate "College" from 1947 to 1954, and Henry W. Sams, director of English…

Terminal attack trajectories of peregrine falcons are described by the proportional navigation guidance law of missiles

PubMed Central

Brighton, Caroline H.; Thomas, Adrian L. R.

2017-01-01

The ability to intercept uncooperative targets is key to many diverse flight behaviors, from courtship to predation. Previous research has looked for simple geometric rules describing the attack trajectories of animals, but the underlying feedback laws have remained obscure. Here, we use GPS loggers and onboard video cameras to study peregrine falcons, Falco peregrinus, attacking stationary targets, maneuvering targets, and live prey. We show that the terminal attack trajectories of peregrines are not described by any simple geometric rule as previously claimed, and instead use system identification techniques to fit a phenomenological model of the dynamical system generating the observed trajectories. We find that these trajectories are best—and exceedingly well—modeled by the proportional navigation (PN) guidance law used by most guided missiles. Under this guidance law, turning is commanded at a rate proportional to the angular rate of the line-of-sight between the attacker and its target, with a constant of proportionality (i.e., feedback gain) called the navigation constant (N). Whereas most guided missiles use navigation constants falling on the interval 3 ≤ N ≤ 5, peregrine attack trajectories are best fitted by lower navigation constants (median N < 3). This lower feedback gain is appropriate at the lower flight speed of a biological system, given its presumably higher error and longer delay. This same guidance law could find use in small visually guided drones designed to remove other drones from protected airspace. PMID:29203660

Terminal attack trajectories of peregrine falcons are described by the proportional navigation guidance law of missiles.

PubMed

Brighton, Caroline H; Thomas, Adrian L R; Taylor, Graham K

2017-12-19

The ability to intercept uncooperative targets is key to many diverse flight behaviors, from courtship to predation. Previous research has looked for simple geometric rules describing the attack trajectories of animals, but the underlying feedback laws have remained obscure. Here, we use GPS loggers and onboard video cameras to study peregrine falcons, Falco peregrinus , attacking stationary targets, maneuvering targets, and live prey. We show that the terminal attack trajectories of peregrines are not described by any simple geometric rule as previously claimed, and instead use system identification techniques to fit a phenomenological model of the dynamical system generating the observed trajectories. We find that these trajectories are best-and exceedingly well-modeled by the proportional navigation (PN) guidance law used by most guided missiles. Under this guidance law, turning is commanded at a rate proportional to the angular rate of the line-of-sight between the attacker and its target, with a constant of proportionality (i.e., feedback gain) called the navigation constant ( N ). Whereas most guided missiles use navigation constants falling on the interval 3 ≤ N ≤ 5, peregrine attack trajectories are best fitted by lower navigation constants (median N < 3). This lower feedback gain is appropriate at the lower flight speed of a biological system, given its presumably higher error and longer delay. This same guidance law could find use in small visually guided drones designed to remove other drones from protected airspace. Copyright © 2017 the Author(s). Published by PNAS.

Physical Absorption of Green House Gases in Amines: The Influence of Functionality, Structure, and Cross-Interactions.

PubMed

Orozco, Gustavo A; Lachet, Véronique; Mackie, Allan D

2016-12-29

Monte Carlo simulations were performed in the isothermal-isobaric ensemble (NPT) to calculate the Henry constants of methane (CH 4 ), nitrous oxide (N 2 O), and carbon dioxide (CO 2 ) in pure H 2 O, amines, and alkanolamines using the classical Lorentz-Berthelot combining rules (L-B). The Henry constants of N 2 O and CO 2 in water are highly overestimated and motivated us to propose a new set of unlike interactions. Contrarily, the Henry constant of N 2 O in MEA is underestimated by around 40%, and again, a new reoptimized cross unlike parameter is able to reproduce the constant to within 10%. An analysis is given of the relationship between the physical absorption of these gases and the chemical structure or functionality of 12 molecules including amines and alkanolamines using the anisotropic united atom intermolecular potential (AUA4). Finally, the solubility of N 2 O in an aqueous solution of monoethanolamine (MEA) at 30% (wt) was also studied. A Henry constant within 7% of the experimental value was found by using the reoptimized parameters along with L-B to account for the MEA + H 2 O unlike interactions. This very good agreement without additional adjustments for the MEA + H 2 O system may be attributed to the good excess properties predictions found in previous works for the binary mixture (MEA + H 2 O). However, further work, including additional alkanolamines in aqueous solutions at several concentrations, is required to verify this particular point.

Implementing an Equilibrium Law Teaching Sequence for Secondary School Students to Learn Chemical Equilibrium

ERIC Educational Resources Information Center

Ghirardi, Marco; Marchetti, Fabio; Pettinari, Claudio; Regis, Alberto; Roletto, Ezio

2015-01-01

A didactic sequence is proposed for the teaching of chemical equilibrium law. In this approach, we have avoided the kinetic derivation and the thermodynamic justification of the equilibrium constant. The equilibrium constant expression is established empirically by a trial-and-error approach. Additionally, students learn to use the criterion of…

A generalized law for brittle deformation of Westerly granite

USGS Publications Warehouse

Lockner, D.A.

1998-01-01

A semiempirical constitutive law is presented for the brittle deformation of intact Westerly granite. The law can be extended to larger displacements, dominated by localized deformation, by including a displacement-weakening break-down region terminating in a frictional sliding regime often described by a rate- and state-dependent constitutive law. The intact deformation law, based on an Arrhenius type rate equation, relates inelastic strain rate to confining pressure Pc, differential stress ????, inelastic strain ??i, and temperature T. The basic form of the law for deformation prior to fault nucleation is In ????i = c - (E*/RT) + (????/a??o)sin-??(???? i/2??o) where ??o and ??o are normalization constants (dependent on confining pressure), a is rate sensitivity of stress, and ?? is a shape parameter. At room temperature, eight experimentally determined coefficients are needed to fully describe the stress-strain-strain rate response for Westerly granite from initial loading to failure. Temperature dependence requires apparent activation energy (E* ??? 90 kJ/mol) and one additional experimentally determined coefficient. The similarity between the prefailure constitutive law for intact rock and the rate- and state-dependent friction laws for frictional sliding on fracture surfaces suggests a close connection between these brittle phenomena.

Questions on universal constants and four-dimensional symmetry from a broad viewpoint. I

NASA Technical Reports Server (NTRS)

Hsu, J. P.

1983-01-01

It is demonstrated that there is a flexibility in clock synchronizations and that four-dimensional symmetry framework can be viewed broadly. The true universality of basic constants is discussed, considering a class of measurement processes based on the velocity = distance/time interval, which always yields some number when used by an observer. The four-dimensional symmetry framework based on common time for all observers is formulated, and related processes of measuring light speed are discussed. Invariant 'action functions' for physical laws in the new four-dimensional symmetry framework with the common time are established to discuss universal constants. Truly universal constants are demonstrated, and it is shown that physics in this new framework and in special relativity are equivalent as far as one-particle systems and the S-matrix in field theories are concerned.

Search for a Variation of Fundamental Constants

NASA Astrophysics Data System (ADS)

Ubachs, W.

2013-06-01

Since the days of Dirac scientists have speculated about the possibility that the laws of nature, and the fundamental constants appearing in those laws, are not rock-solid and eternal but may be subject to change in time or space. Such a scenario of evolving constants might provide an answer to the deepest puzzle of contemporary science, namely why the conditions in our local Universe allow for extreme complexity: the fine-tuning problem. In the past decade it has been established that spectral lines of atoms and molecules, which can currently be measured at ever-higher accuracies, form an ideal test ground for probing drifting constants. This has brought this subject from the realm of metaphysics to that of experimental science. In particular the spectra of molecules are sensitive for probing a variation of the proton-electron mass ratio μ, either on a cosmological time scale, or on a laboratory time scale. A comparison can be made between spectra of molecular hydrogen observed in the laboratory and at a high redshift (z=2-3), using the Very Large Telescope (Paranal, Chile) and the Keck telescope (Hawaii). This puts a constraint on a varying mass ratio Δμ/μ at the 10^{-5} level. The optical work can also be extended to include CO molecules. Further a novel direction will be discussed: it was discovered that molecules exhibiting hindered internal rotation have spectral lines in the radio-spectrum that are extremely sensitive to a varying proton-electron mass ratio. Such lines in the spectrum of methanol were recently observed with the radio-telescope in Effelsberg (Germany). F. van Weerdenburg, M.T. Murphy, A.L. Malec, L. Kaper, W. Ubachs, Phys. Rev. Lett. 106, 180802 (2011). A. Malec, R. Buning, M.T. Murphy, N. Milutinovic, S.L. Ellison, J.X. Prochaska, L. Kaper, J. Tumlinson, R.F. Carswell, W. Ubachs, Mon. Not. Roy. Astron. Soc. 403, 1541 (2010). E.J. Salumbides, M.L. Niu, J. Bagdonaite, N. de Oliveira, D. Joyeux, L. Nahon, W. Ubachs, Phys. Rev. A 86, 022510

A Vision for the Future: Henry G. Bennett Memorial Library, Southeastern Oklahoma State University Strategic Plan, 2002-2007.

ERIC Educational Resources Information Center

Davis, Dorothy

This document presents the five-year strategic plan developed by the library director, staff, and the Library Committee for the Henry G. Bennett Memorial Library, Southeastern Oklahoma State University. The goal of this plan is to provide a framework that the library can use to focus energy and resources in fulfilling the mission of the library…

Plastic (wire-combed) grooving of a slip-formed concrete runway overlay at Patrick Henry Airport: An initial evaluation

NASA Technical Reports Server (NTRS)

Marlin, E. C.; Horne, W. B.

1977-01-01

A wire-comb technique is described for transversely grooving the surface of a freshly laid (plastic state) slip-formed concrete overlay installed at Patrick Henry Airport. This method of surface texturing yields better water drainage and pavement skid resistance than that obtained with an older conventional burlap drag concrete surface treatment installed on an adjacent portion of the runway.

New Quasar Studies Keep Fundamental Physical Constant Constant

NASA Astrophysics Data System (ADS)

2004-03-01

Very Large Telescope sets stringent limit on possible variation of the fine-structure constant over cosmological time Summary Detecting or constraining the possible time variations of fundamental physical constants is an important step toward a complete understanding of basic physics and hence the world in which we live. A step in which astrophysics proves most useful. Previous astronomical measurements of the fine structure constant - the dimensionless number that determines the strength of interactions between charged particles and electromagnetic fields - suggested that this particular constant is increasing very slightly with time. If confirmed, this would have very profound implications for our understanding of fundamental physics. New studies, conducted using the UVES spectrograph on Kueyen, one of the 8.2-m telescopes of ESO's Very Large Telescope array at Paranal (Chile), secured new data with unprecedented quality. These data, combined with a very careful analysis, have provided the strongest astronomical constraints to date on the possible variation of the fine structure constant. They show that, contrary to previous claims, no evidence exist for assuming a time variation of this fundamental constant. PR Photo 07/04: Relative Changes with Redshift of the Fine Structure Constant (VLT/UVES) A fine constant To explain the Universe and to represent it mathematically, scientists rely on so-called fundamental constants or fixed numbers. The fundamental laws of physics, as we presently understand them, depend on about 25 such constants. Well-known examples are the gravitational constant, which defines the strength of the force acting between two bodies, such as the Earth and the Moon, and the speed of light. One of these constants is the so-called "fine structure constant", alpha = 1/137.03599958, a combination of electrical charge of the electron, the Planck constant and the speed of light. The fine structure constant describes how electromagnetic forces hold

Energy laws in human travel behaviour

NASA Astrophysics Data System (ADS)

Kölbl, Robert; Helbing, Dirk

2003-05-01

We show that energy concepts can contribute to the understanding of human travel behaviour. First, the average journey times for different modes of transport are inversely proportional to the energy consumption rates measured for the respective human physical activities. Second, when daily travel-time distributions for different modes of transport such as walking, cycling, bus or car travel are appropriately scaled, they turn out to have a universal functional relationship. This corresponds to a canonical-like energy distribution with exceptions for short trips, which can be theoretically explained. Combined, this points to a law of constant average energy consumption for the physical activity of daily travel. Applying these natural laws could help to improve long-term urban and transport planning.

2006 Henry f. Smyth jr. Award lecture historical review--employer responsibility for workplace health and safety.

PubMed

Henshaw, John L

2007-02-01

The Academy of Industrial Hygiene established the Henry F. Smyth Jr. Award in 1981. The Award is presented to that individual who has recognized the needs of the industrial hygiene profession and has made major contributions to fulfill those needs, thereby contributing to the improvement of the public welfare. This year's Award was presented to John L. Henshaw, CIH, at the 2006 Professional Conference on Industrial Hygiene (PCIH) in San Jose, California.

Cecilia Payne-Gaposchkin, Henry Norris Russell Lecture: Fifty Years of Novae

NASA Astrophysics Data System (ADS)

Burbidge, E. M.

1999-05-01

It is easy to pick out my most memorable meeting of the AAS: the 149th meeting held in January, 1977, and hosted by the University of Hawaii, in Honolulu, HI. It was the meeting at which two traditions of the Society were broken, and we moved into the era of equal opportunity for women astronomers. Cecilia Payne-Gaposchkin received the highest award of the AAS: the Henry Norris Russell Lectureship. This award had never before been available to women, otherwise Cecilia would, years earlier, have been honored for the many achievements in her lifetime of renowned astronomical research. And I, the first woman to be elected President of the AAS, had the honor of presenting the illuminated scroll to Cecilia, and of introducing her on the platform where she delivered the Henry Norris Russell Prize Lecture, entitled ``Fifty Years of Novae"(1) . Cecilia opened by comparing the experience of young and old scientists in achieving exciting results from their research, and then led us through the history of the discoveries of and about some famous novae. She described the physical picture that emerged from studies of their light curves, their spectra, and the discovery of their binary nature. Three important tables were included, listing data on cataclysmic binaries (dwarf novae) and their link to the nova phenomenon in general. She recalled that she and Sergei Gaposchkin had hesitated between the names catastrophic and cataclysmic for the dwarf novae, and decided on the latter, from the dictionary definitions of those two terms: ``a cataclysm is a great and general flood" while a catastrophe ``is a final event". The nova phenomenon is recurrent, as are the dwarf novae, and both involve an outpouring of a flood of energy. She concluded by describing her 50 years' experience with novae as presenting ``the contemporary portrait of a nova", rather than a final picture, and by forecasting that the next 50 years of discovering and studying novae will be as full of surprises as the

High resolution in-line analyses of precipitation at two UK ground locations, and possible relevance to convective cooling at cloud level.

NASA Astrophysics Data System (ADS)

Durham, Brian

2015-04-01

Wet deposition of many molecular pollutants can be simulated `sufficiently well' by a simple meteorological model, including the poorly soluble ozone (Tost et al, 2007, 2754). Carbon dioxide (CO2) has a Henry constant similar to that of ozone, but perhaps because its boundary layer presence is three orders of magnitude greater than ozone it has been widely assumed to be immune to significant cleansing by scavenging and deposition. In 2009 this `elephant' was approached (cautiously!) at the first of two UK locations using high time-resolution analyses of delivered rainwater, and some initial observations seem relevant to the `organised convection' theme of the present session. Six variables are measured every second, averaged every 60 seconds, including: conductivity; acidity ([H3O+] = 10 ^-pH ) and; stripped CO2 (by NDIRS). Convective precipitation typically delivers significantly more CO2 than predicted from Henry's Law, is supersaturated on arrival and shows a characteristic `spiky' profile against time. In assessing the above, this paper revisits eighty years of measurements of the Henry's Law equilibrium for the CO2/water system at partial pressures less than 1 atmosphere, and (more recently) low-pressure solubility at temperatures down to 4°C (Carroll, Slupski and Mather, 1991, 1203; Faraday Discuss. 2013, 167, 462-3). The observed solute load and supersaturation would become plausible if the reported upturn in solubility between 20°C and 4°C continued into the super-cooled zone. In a cloud, super-cooling will arise under convection when condensing droplets are chilled by adiabatic expansion of the carrier air. Droplets will increase in molar volume by up to 2.5% at -34°C (the temperature of spontaneous ice nucleation, Hare and Sorensen, 1987), offering a physical framework for the observed characteristics, and the possibility that `spikiness' reflects the degree of organisation of convection.

Solute-Gas Equilibria in Multi-Organic Aqueous Systems

DTIC Science & Technology

1981-11-30

THIS PAGK(*7@nDae~ Kht.Eero*g) Block 20 (cont.) --z Henry’s constants for selected organic solvents were determined at ionic strengths up to 1.0 M (KC1...equili- brium, batch stripping reactor. Data were fit to a regression equation. Henry’s constants for selected organic solvents were determined at ionic...organic systems. The presence of additional or- ganics (some perhaps not even strippable ) likely to be found along with a particular volatile should be

Style and non-style in anatomical illustration: From Renaissance Humanism to Henry Gray

PubMed Central

Kemp, Martin

2010-01-01

Style is a familiar category for the analysis of art. It is less so in the history of anatomical illustration. The great Renaissance and Baroque picture books of anatomy illustrated with stylish woodcuts and engravings, such as those by Charles Estienne, Andreas Vesalius and Govard Bidloo, showed figures in dramatic action in keeping with philosophical and theological ideas about human nature. Parallels can be found in paintings of the period, such as those by Titian, Michelangelo and Hans Baldung Grien. The anatomists also claimed to portray the body in an objective manner, and showed themselves as heroes of the discovery of human knowledge. Rembrandt’s painting of Dr Nicholas Tulp is the best-known image of the anatomist as hero. The British empirical tradition in the 18th century saw William Cheselden and William Hunter working with techniques of representation that were intended to guarantee detailed realism. The ambition to portray forms life-size led to massive volumes, such as those by Antonio Mascagni. John Bell, the Scottish anatomist, criticized the size and pretensions of the earlier books and argued for a plain style adapted to the needs of teaching and surgery. Henry Gray’s famous Anatomy of 1858, illustrated by Henry Vandyke Carter, aspired to a simple descriptive mode of functional representation that avoided stylishness, resulting in a style of its own. Successive editions of Gray progressively saw the replacement of Gray’s method and of all his illustrations. The 150th anniversary edition, edited by Susan Standring, radically re-thinks the role of Gray’s book within the teaching of medicine. PMID:20447244

Design of a gap tunable flux qubit with FastHenry

NASA Astrophysics Data System (ADS)

Akhtar, Naheed; Zheng, Yarui; Nazir, Mudassar; Wu, Yulin; Deng, Hui; Zheng, Dongning; Zhu, Xiaobo

2016-12-01

In the preparations of superconducting qubits, circuit design is a vital process because the parameters and layout of the circuit not only determine the way we address the qubits, but also strongly affect the qubit coherence properties. One of the most important circuit parameters, which needs to be carefully designed, is the mutual inductance among different parts of a superconducting circuit. In this paper we demonstrate how to design a gap-tunable flux qubit by layout design and inductance extraction using a fast field solver FastHenry. The energy spectrum of the gap-tunable flux qubit shows that the measured parameters are close to the design values. Project supported by the National Natural Science Foundation of China (Grant Nos. 11374344, 11404386, and 91321208), the National Basic Research Program of China (Grant No. 2014CB921401), and the Strategic Priority Research Program of the Chinese Academy of Sciences (Grant No. XDB07010300).

Can the tricyanomethanide anion improve CO2 absorption by acetate-based ionic liquids?

PubMed

Lepre, L F; Szala-Bilnik, J; Pison, L; Traïkia, M; Pádua, A A H; Ando, R A; Costa Gomes, M F

2017-05-17

Carbon dioxide absorption by mixtures of two ionic liquids with a common cation-1-butyl-3-methylimidazolium acetate, [C 4 C 1 Im][OAc], and 1-butyl-3-methylimidazolium tricyanomethanide, [C 4 C 1 Im][C(CN) 3 ]-was determined experimentally at pressures below atmospheric pressure as a function of temperature between 303 K and 343 K, and at 303 K as a function of pressure up to 10 bar. It is observed that the absorption of carbon dioxide decreases with increasing tricyanomethanide anion concentration and with increasing temperature, showing a maximum of 0.4 mole fraction of carbon dioxide in pure [C 4 C 1 Im][OAc] at 303 K. At this temperature, the CO 2 absorption in the mixtures [C 4 C 1 Im][OAc] (1-x) [C(CN) 3 ] x is approximately the mole-fraction average of that in the pure ionic liquids. By applying an appropriate thermodynamic treatment, after identification of the species in solution, it was possible to calculate both the equilibrium constant, K eq , and Henry's law constant, K H , in the different mixtures studied thus obtaining an insight into the relative contribution of chemical and physical absorption of the gas. It is shown that chemical sorption proceeds through a 1 : 2 stoichiometry between CO 2 and acetate-based ionic liquid. The presence of the C(CN) 3 - anion does not significantly affect the chemical reaction of the gas with the solvent (K eq = 75 ± 2 at 303 K) but leads to lower Henry's law constants (from K H = 77.8 ± 0.6 bar to K H = 49.5 ± 0.5 bar at 303 K), thus pointing towards larger physical absorption of the gas. The tricyanomethanide anion considerably improves the mass transfer by increasing the fluidity of the absorbent as proven by the larger diffusivities of all the ions when the concentration of the C(CN) 3 - anion increases in the mixtures.

On the "Critique of Everyday Life" to "Metaphilosophy": Henri Lefebvre's Philosophical-Political Legacy of the Cultural Revolution

ERIC Educational Resources Information Center

Sünker, Heinz

2014-01-01

Henri Lefebvre (1901-91), philosopher and sociologist, is, together with Theodor W. Adorno, Max Horkheimer, Walter Benjamin and Ernst Bloch, one of the most relevant representatives of the first generation in Western Marxism. His engagement with Marxism led him to analyse everyday life in post-war France in order to decipher the possibilities of,…

[Sauveur-Henri-Victor Bouvier (1799-1877): orthopaedist, surgeon and promoter of physical education].

PubMed

Monet, Jacques; Quin, Grégory

2013-01-01

This article establishes the biography of a little known physician of the 19th century., whose commitment with orthopaedics and formulation of medical gymnastics was important: the surgeon-orthopaedist Sauveur-Henri-Victor Bouvier. Several constitutive processes of the medical field of the 19th century are analysed: specialization (around orthopaedics), professionalization and development of various therapeutic and hygienic methods (among them medical gymnastics). Bouvier's biography is particularly instructive and sheds new light on these different processes, as well as on the institutionalization of orthopaedics from the 1820's up to the 1870's, at the intersection between medical and educative fields, between hospital, medical faculty and teaching of gymnastics.

On the variability of the Charnock constant and the functional dependence of the drag coefficient on wind speed: Part II-Observations

NASA Astrophysics Data System (ADS)

Bye, John A. T.; Wolff, Jörg-Olaf; Lettmann, Karsten A.

2014-07-01

An analytical expression for the 10 m drag law in terms of the 10 m wind speed at the maximum in the 10 m drag coefficient, and the Charnock constant is presented, which is based on the results obtained from a model of the air-sea interface derived in Bye et al. (2010). This drag law is almost independent of wave age and over the mid-range of wind speeds (5-17 ms-1) is very similar to the drag law based on observed data presented in Foreman and Emeis (2010). The linear fit of the observed data which incorporates a constant into the traditional definition of the drag coefficient is shown to arise to first-order as a consequence of the momentum exchange across the air-sea boundary layer brought about by wave generation and spray production which are explicitly represented in the theoretical model.

[Charles-Henri Fialon (1846-1933). Creator of the historical museum of the faculty of pharmacy of Paris].

PubMed

Bzoura, Elie; Flahaut, Jean

2004-01-01

Charles-Henri Fialon stopped his pharmaceutical activities in 1892 and he devoted his time to artistic and historic works. He achieved an important collection of pharmaceutical pots and objects which he gave to the school of Pharmacy of Paris. These gifts were collected in a room named "Musée Fialon ". This museum was enlarged twice and presently is in the "Guillaume Valette" gallery. His content is described in this paper.

Conservation laws and conserved quantities for (1+1)D linearized Boussinesq equations

NASA Astrophysics Data System (ADS)

Carvalho, Cindy; Harley, Charis

2017-05-01

Conservation laws and physical conserved quantities for the (1+1)D linearized Boussinesq equations at a constant water depth are presented. These equations describe incompressible, inviscid, irrotational fluid flow in the form of a non steady solitary wave. A systematic multiplier approach is used to obtain the conservation laws of the system of third order partial differential equations (PDEs) in dimensional form. Physical conserved quantities are derived by integrating the conservation laws in the direction of wave propagation and imposing decaying boundary conditions in the horizontal direction. One of these is a newly discovered conserved quantity which relates to an energy flux density.

Operation of Darrieus turbines in constant circulation framework

NASA Astrophysics Data System (ADS)

Gorle, J. M. R.; Chatellier, L.; Pons, F.; Ba, M.

2017-07-01

Analytical and computational studies of flow across a low-speed marine turbine of Darrieus type with pitching blades have been carried out for flowfield and performance evaluation. The objective of this study is to develop efficient blade pitching laws to arrest or control the vortex shedding from the blades during turbine's operation. This is achieved by imparting an arbitrary constant amount of circulation to the blades, where Kelvin's theorem is respected. This paper presents the extension of the application of conformal mapping to produce the time-dependent flow over a rotating turbine blade in order to develop a quantified relationship between the blade's orientation with respect to the rotor's tangent and its rotational motion. The flow development is based on the analytical treatment given to potential flow formulation through Laurent series decomposition, where the Kutta condition is satisfied. The pitch control law and the analytical modeling of the hydrodynamic forces acting on the blade are derived based on Kelvin's theorem for the conservation of circulation. The application of this pitch control law in the real flow conditions is however limited due to viscous losses and rotational effects. Therefore, a 2D computational fluid dynamics (CFD) study with the shear stress transport (SST) k -ω turbulence model has been performed to examine the flow across a 4-bladed turbine model. While validating the analytical work, the numerical investigation reveals the applicability and limitations of circulation-controlled blade pitching laws in real flow conditions. In particular, a reference equivalent angle of attack is defined, which must be contained in a tight range in order to effectively prevent vortex shedding at a given tip-speed ratio.

Henry Beecher's Contributions to the Ethics of Clinical Research.

PubMed

Veatch, Robert M

2016-01-01

In the 1950s and '60s, Henry Beecher pioneered the discussion of the ethics of clinical research, leading eventually to the publication of the famous New England Journal of Medicine article summarizing 22 research studies that Beecher suggests were unethical. Those studies generally showed a pattern of posing serious risks to subjects without anticipated proportional benefit. Beecher famously claimed that the problem was not that researchers were malicious or evil; rather, he claimed the problem was they manifested thoughtlessness or carelessness. He called for more rigorous self-scrutiny rather than public review.This article argues that Beecher's reliance on conscientious investigators is problematic. In particular, it focuses on benefits and harms to the exclusion of other moral criteria. However, both research subjects and public regulators are also concerned about autonomy and the consent requirement, confidentiality, and fairness in subject selection and research design. The movement in the 1970s toward more public scrutiny was critical, even though Beecher was right in holding that it was not "vicious disregard for subject welfare" that explained unethical protocols.

Sapflow of hybrid poplar (Populus nigra L. x P. maximowiczii A. Henry 'NM6') during phytoremediation of landfill leachate

Treesearch

Ronald S., Jr. Zalesny; Adam H. Wiese; Edmund O. Bauer; Don E. Riemenschneider

2006-01-01

Poplars are ideal for phytoremediation because of their high water usage, fast growth, and deep root systems. We measured in 2002 and 2003 the sapflow of hybrid poplars (Populus nigra L. x P. maximowiczii A. Henry 'NM6') planted in 1999 for phytoremediation of a landfill in Rhinelander, WI, USA (45.6?N, 89.4?W).

Power-law modeling based on least-squares minimization criteria.

PubMed

Hernández-Bermejo, B; Fairén, V; Sorribas, A

1999-10-01

The power-law formalism has been successfully used as a modeling tool in many applications. The resulting models, either as Generalized Mass Action or as S-systems models, allow one to characterize the target system and to simulate its dynamical behavior in response to external perturbations and parameter changes. The power-law formalism was first derived as a Taylor series approximation in logarithmic space for kinetic rate-laws. The especial characteristics of this approximation produce an extremely useful systemic representation that allows a complete system characterization. Furthermore, their parameters have a precise interpretation as local sensitivities of each of the individual processes and as rate-constants. This facilitates a qualitative discussion and a quantitative estimation of their possible values in relation to the kinetic properties. Following this interpretation, parameter estimation is also possible by relating the systemic behavior to the underlying processes. Without leaving the general formalism, in this paper we suggest deriving the power-law representation in an alternative way that uses least-squares minimization. The resulting power-law mimics the target rate-law in a wider range of concentration values than the classical power-law. Although the implications of this alternative approach remain to be established, our results show that the predicted steady-state using the least-squares power-law is closest to the actual steady-state of the target system.

A method for measuring enthalpy of volatilization of a compound, Delta(vol)H, from dilute aqueous solution.

PubMed

Wang, Tianshu

2006-01-01

This study has developed a method for measuring the enthalpy of volatilization (Delta(vol)H) of a compound in a dilute solution via ion-molecule reactions and gas-phase analysis using selected ion flow tube mass spectrometry (SIFT-MS). The Delta(vol)H/R value was obtained using an equation with three variant forms either from the headspace concentration of the solution or from individual product ion(s). Under certain experimental conditions, the equation has the simplest form [formula: see text], where R is the gas constant (8.314 J . mol(-1) . K(-1)), i(n) and I are the respective product and precursor ion count rates, and T is the temperature of the solution. As an example, a series of 27.0 micromol/L aqueous solutions of acetone was analyzed over a temperature range of 25-50 degrees C at 5 degrees C intervals using H3O+, NO+ and O2+* precursor ions, producing a mean Delta(vol)H/R value of 4700 +/- 200 K. This corresponds with current literature values and supports the consistency of the new method. Notably, using this method, as long as the concentration of the solution falls into the range of Henry's law, the exact concentration does not have to be known and it can require only one sample at each temperature. Compared with previous methods which involve the measurement of Henry's law constant at each temperature, this method significantly reduces the number of samples required and avoids the labour and difficulties in preparing standard solutions at very low concentrations. Further to this, if the contents of a solution were unknown the measured Delta(vol)H/R from individual product ion(s) can help to identify the origin of the ion(s). Copyright 2006 John Wiley & Sons, Ltd.

An analytic model for accurate spring constant calibration of rectangular atomic force microscope cantilevers.

PubMed

Li, Rui; Ye, Hongfei; Zhang, Weisheng; Ma, Guojun; Su, Yewang

2015-10-29

Spring constant calibration of the atomic force microscope (AFM) cantilever is of fundamental importance for quantifying the force between the AFM cantilever tip and the sample. The calibration within the framework of thin plate theory undoubtedly has a higher accuracy and broader scope than that within the well-established beam theory. However, thin plate theory-based accurate analytic determination of the constant has been perceived as an extremely difficult issue. In this paper, we implement the thin plate theory-based analytic modeling for the static behavior of rectangular AFM cantilevers, which reveals that the three-dimensional effect and Poisson effect play important roles in accurate determination of the spring constants. A quantitative scaling law is found that the normalized spring constant depends only on the Poisson's ratio, normalized dimension and normalized load coordinate. Both the literature and our refined finite element model validate the present results. The developed model is expected to serve as the benchmark for accurate calibration of rectangular AFM cantilevers.

The anisotropic Hooke's law for cancellous bone and wood.

PubMed

Yang, G; Kabel, J; van Rietbergen, B; Odgaard, A; Huiskes, R; Cowin, S C

A method of data analysis for a set of elastic constant measurements is applied to data bases for wood and cancellous bone. For these materials the identification of the type of elastic symmetry is complicated by the variable composition of the material. The data analysis method permits the identification of the type of elastic symmetry to be accomplished independent of the examination of the variable composition. This method of analysis may be applied to any set of elastic constant measurements, but is illustrated here by application to hardwoods and softwoods, and to an extraordinary data base of cancellous bone elastic constants. The solid volume fraction or bulk density is the compositional variable for the elastic constants of these natural materials. The final results are the solid volume fraction dependent orthotropic Hooke's law for cancellous bone and a bulk density dependent one for hardwoods and softwoods.

High School Forum: Boyle's/Hooke's/Towneley and Power's/Mariotte's Law.

ERIC Educational Resources Information Center

Hawthorne, Robert M.; Herron, J. Dudley, Ed.

1979-01-01

This column for high school teachers, written by high school teachers, discusses several interesting anecdotes related to the formulation of laws and the determination of constants. Science history is presented in a manner that can enliven classroom presentations and aid in understanding the principle itself. (Authur/SA)

Modeling water quality effects of structural and operational changes to Scoggins Dam and Henry Hagg Lake, Oregon

USGS Publications Warehouse

Sullivan, Annett B.; Rounds, Stewart A.

2006-01-01

To meet water quality targets and the municipal and industrial water needs of a growing population in the Tualatin River Basin in northwestern Oregon, an expansion of Henry Hagg Lake is under consideration. Hagg Lake is the basin's primary storage reservoir and provides water during western Oregon's typically dry summers. Potential modifications include raising the dam height by 6.1 meters (20 feet), 7.6 meters (25 feet), or 12.2 meters (40 feet); installing additional outlets (possibly including a selective withdrawal tower); and adding additional inflows to provide greater reliability of filling the enlarged reservoir. One method of providing additional inflows is to route water from the upper Tualatin River through a tunnel and into Sain Creek, a tributary to the lake. Another option is to pump water from the Tualatin River (downstream of the lake) uphill and into the reservoir during the winter--the 'pump-back' option. A calibrated CE-QUAL-W2 model of Henry Hagg Lake's hydrodynamics, temperature, and water quality was used to examine the effect of these proposed changes on water quality in the lake and downstream. Most model scenarios were run with the calibrated model for 2002, a typical water year; a few scenarios were run for 2001, a drought year. More...

Robust model comparison disfavors power law cosmology

NASA Astrophysics Data System (ADS)

Shafer, Daniel L.

2015-05-01

Late-time power law expansion has been proposed as an alternative to the standard cosmological model and shown to be consistent with some low-redshift data. We test power law expansion against the standard flat Λ CDM cosmology using goodness-of-fit and model comparison criteria. We consider type Ia supernova (SN Ia) data from two current compilations (JLA and Union2.1) along with a current set of baryon acoustic oscillation (BAO) measurements that includes the high-redshift Lyman-α forest measurements from BOSS quasars. We find that neither power law expansion nor Λ CDM is strongly preferred over the other when the SN Ia and BAO data are analyzed separately but that power law expansion is strongly disfavored by the combination. We treat the Rh=c t cosmology (a constant rate of expansion) separately and find that it is conclusively disfavored by all combinations of data that include SN Ia observations and a poor overall fit when systematic errors in the SN Ia measurements are ignored, despite a recent claim to the contrary. We discuss this claim and some concerns regarding hidden model dependence in the SN Ia data.

THE ONSET OF ELECTRICAL BREAKDOWN IN DUST LAYERS: II. EFFECTIVE DIELECTRIC CONSTANT AND LOCAL FIELD ENHANCEMENT

EPA Science Inventory

Part 1 of the work has shown that electrical breakdown in dust layers obeys Paschen's Law, but occurs at applied field values which appear too small to initiate the breakdown. In this paper the authors show how an effective dielectric constant characterizing the dust layer can be...

Constants and pseudo-constants of the Kadomtsev-Petviashvili equation.

PubMed

Case, K M

1985-08-01

Elucidating earlier work, it is shown that the Kadomtsev-Petviashvili equation has n + 2 constants for all n >/= 0. It also has a pseudo-constant from which the constants can be obtained by differentiation with respect to time. The pseudo-constant can be obtained from a basis functional J(n) ((n+2)) = -1/18 [unk] y(n+2)q by taking repeated Poisson brackets with the Hamiltonian.

Fugitive from Labor Cases: Henry Garnett (1850) and Moses Honner (1860). The Constitution Community: Civil War and Reconstruction (1850-1870).

ERIC Educational Resources Information Center

Lawlor, John M., Jr.

The cases of Henry Garnett and Moses Honner bookend the 1850s, a decade of intensifying political crisis that was deeply connected to the institution of slavery. In both court actions, which were tried in the Third Circuit Court, Eastern District, Philadelphia, Pennsylvania, the defendants were charged with being "fugitives from labor."…

Constants and pseudo-constants of the Kadomtsev-Petviashvili equation

PubMed Central

Case, K. M.

1985-01-01

Elucidating earlier work, it is shown that the Kadomtsev-Petviashvili equation has n + 2 constants for all n ≥ 0. It also has a pseudo-constant from which the constants can be obtained by differentiation with respect to time. The pseudo-constant can be obtained from a basis functional Jn(n+2) = -1/18 [unk] yn+2q by taking repeated Poisson brackets with the Hamiltonian. PMID:16593588

Development of a digital automatic control law for steep glideslope capture and flare

NASA Technical Reports Server (NTRS)

Halyo, N.

1977-01-01

A longitudinal digital guidance and control law for steep glideslopes using MLS (Microwave Landing System) data is developed for CTOL aircraft using modern estimation and control techniques. The control law covers the final approach phases of glideslope capture, glideslope tracking, and flare to touchdown for automatic landings under adverse weather conditions. The control law uses a constant gain Kalman filter to process MLS and body-mounted accelerometer data to form estimates of flight path errors and wind velocities including wind shear. The flight path error estimates and wind estimates are used for feedback in generating control surface commands. Results of a digital simulation of the aircraft dynamics and the guidance and control law are presented for various wind conditions.

Laws of organization and chemical analysis: Blainville and Müller.

PubMed

Duchesneau, François

2016-12-01

When "general physiology" emerged as a basic field of research within biology in the early nineteenth century, Henri Ducrotay de Blainville (1777-1850) on the one hand and Johannes Peter Müller (1801-1858) on the other appealed to chemical analysis to account for the properties and operations of organisms that were observed to differ from what was found in inorganic compounds. Their aim was to establish laws of vital organization that would be based on organic chemical processes, but would also be of use to explain morphological and functional differences among life forms. The intent of this paper is to specify for each of these leading physiologists the different presuppositions that provided theoretical frameworks for their interpretation of what they conceived of as laws of organization underpinning the dynamics of vital phenomena. Blainville presumed that the properties of organic compounds depended on the chemical properties of their constitutive molecules, but combined according to patterns of functional development, and that the latter could only be inferred from an empirical survey of modes of organization across the spectrum of life forms. For Müller, while all vital processes involved chemical reactions, in the formative and functional operations of organisms, these reactions would result from the action of life forces that were responsible for the production of organic combinations and thus for vital and animal functions. As both physiologists set significant methodological patterns for their many disciples and followers, their respective quasi-reductionist and anti-reductionist positions need to be accounted for.

Rime-, mixed- and glaze-ice evaluations of three scaling laws

NASA Technical Reports Server (NTRS)

Anderson, David N.

1994-01-01

This report presents the results of tests at NASA Lewis to evaluate three icing scaling relationships or 'laws' for an unheated model. The laws were LWC x time = constant, one proposed by a Swedish-Russian group and one used at ONERA in France. Icing tests were performed in the NASA Lewis Icing Research Tunnel (IRT) with cylinders ranging from 2.5- to 15.2-cm diameter. Reference conditions were chosen to provide rime, mixed and glaze ice. Scaled conditions were tested for several scenarios of size and velocity scaling, and the resulting ice shapes compared. For rime-ice conditions, all three of the scaling laws provided scaled ice shapes which closely matched reference ice shapes. For mixed ice and for glaze ice none of the scaling laws produced consistently good simulation of the reference ice shapes. Explanations for the observed results are proposed, and scaling issues requiring further study are identified.

Constants and pseudo-constants of the Kadomtsev-Petviashvili equation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Case, K.M.

1985-08-01

Elucidating earlier work, it is shown that the Kadomtsev-Petviashvili equation has n + 2 constants for all n greater than or equal to 0. It also has a pseudo-constant from which the constants can be obtained by differentiation with respect to time. The pseudo-constant can be obtained from a basis functional J/sub n/sup (n+2)/ = -1/18 integral y/sup n+2/ q by taking repeated Poisson brackets with the Hamiltonian.

Samuel Hartlib on the death of Descartes: a rediscovered letter to Henry More

PubMed Central

Penman, Leigh T. I.

2015-01-01

This paper discloses the content of a previously overlooked epistle by the Anglo-Prussian intelligencer Samuel Hartlib to Henry More concerning the death of René Descartes. After a discussion situating the letter within the sequence of the More–Hartlib correspondence, an analysis of the rhetorical structure of the epistle is offered, followed by a brief assessment of Hartlib's attitude towards Descartes, and the identification of his source concerning the news of the philosopher's death. An account of the transmission of the letter via a nineteenth-century periodical is also provided. The text of Hartlib's letter and an overlooked passage of Hartlib's diary concerning Descartes's death, which draws on the content of the More letter, are presented as appendixes.

Why Henry III of Navarre’s Hair Probably did not Turn White Overnight

PubMed Central

Navarini, Alexander A; Trüeb, Ralph M

2010-01-01

Although a rare event, sudden whitening of hair (canities subita) has reportedly affected a number of well-known historical figures, usually in relation to dramatic events in their lives. Although early accounts are substantiated by more recent case reports in scientific literature, we suspect that the phenomenon is not only used as a literary means in fiction, with the aim of dramatizing, but probably also in historical accounts. For this purpose, we examine the case history of Henry III of Navarre who allegedly turned white on the evening of the Saint Bartholomew’s day massacre, and challenge this claim, due to inconsistencies in his biography, with the current pathophysiological understanding of canities subita. PMID:21188015

Unified Scaling Law for flux pinning in practical superconductors: II. Parameter testing, scaling constants, and the Extrapolative Scaling Expression

NASA Astrophysics Data System (ADS)

Ekin, Jack W.; Cheggour, Najib; Goodrich, Loren; Splett, Jolene; Bordini, Bernardo; Richter, David

2016-12-01

A scaling study of several thousand Nb3Sn critical-current (I c) measurements is used to derive the Extrapolative Scaling Expression (ESE), a relation that can quickly and accurately extrapolate limited datasets to obtain full three-dimensional dependences of I c on magnetic field (B), temperature (T), and mechanical strain (ɛ). The relation has the advantage of being easy to implement, and offers significant savings in sample characterization time and a useful tool for magnet design. Thorough data-based analysis of the general parameterization of the Unified Scaling Law (USL) shows the existence of three universal scaling constants for practical Nb3Sn conductors. The study also identifies the scaling parameters that are conductor specific and need to be fitted to each conductor. This investigation includes two new, rare, and very large I c(B,T,ɛ) datasets (each with nearly a thousand I c measurements spanning magnetic fields from 1 to 16 T, temperatures from ˜2.26 to 14 K, and intrinsic strains from -1.1% to +0.3%). The results are summarized in terms of the general USL parameters given in table 3 of Part 1 (Ekin J W 2010 Supercond. Sci. Technol. 23 083001) of this series of articles. The scaling constants determined for practical Nb3Sn conductors are: the upper-critical-field temperature parameter v = 1.50 ± 0.04 the cross-link parameter w = 3.0 ± 0.3 and the strain curvature parameter u = 1.7 ± 0.1 (from equation (29) for b c2(ɛ) in Part 1). These constants and required fitting parameters result in the ESE relation, given by I c ( B , T , ɛ ) B = C [ b c 2 ( ɛ ) ] s ( 1 - t 1.5 ) η - μ ( 1 - t 2 ) μ b p ( 1 - b ) q with reduced magnetic field b ≡ B/B c2*(T,ɛ) and reduced temperature t ≡ T/T c*(ɛ), where: B c 2 * ( T , ɛ ) = B c 2 * ( 0 , 0 ) ( 1 - t 1.5 ) b c 2 ( ɛ ) T c * ( ɛ ) = T c * ( 0 ) [ b c 2 ( ɛ ) ] 1/3 and fitting parameters: C, B c2*(0,0), T c*(0), s, either η or μ (but not both), plus the parameters in the strain function b c2

Computing gas solubility in reservoir waters for environmental chemistry applications: the role of satellite observations

NASA Astrophysics Data System (ADS)

Rosa, R.; Lima, I.; Ramos, F.; Bambace, L.; Assireu, A.; Stech, J.; Novo, E.; Lorenzeti, L.

Atmospheric greenhouse gases concentration has increased during the past centuries basically due to biogenic and pyrogenic anthopogenic emissions Recent investigations have shown that gas emission methane as an important example from tropical hydroelectric reservoirs may comprise a considerable fraction of the total anthropogenic bulk In order to evaluate the concentration of gases of potential importance in environmental chemistry the solubility of such gases have been collected and converted into a uniform format using the Henry s law which states that the solubility of a gas in a liquid is directly proportional to its partial pressure However the Henry s law can be derived as a function of temperature density molar mixing ratio in the aqueous phase and molar mass of water In this paper we show that due to the complex temperature variation and water composition measured in brazilian tropical reservoirs as Serra da Mesa and Manso expressive secular variation on the traditional solubility constants concentration of a species in the aqueous phase by the partial pressure of that species in the gas phase can change in a rate of approximately 30 in 6 decades This estimation comes from a computational analysis of temperature variation measured during 6 months in Serra da Mesa and Manso reservoirs taking into account a simulated density and molar mass variation of the aqueous composition in these environments As an important global change issue from this preliminary analysis we discuss its role in the current estimations on the concentration emission rates

Power-Law Dynamics of Membrane Conductances Increase Spiking Diversity in a Hodgkin-Huxley Model.

PubMed

Teka, Wondimu; Stockton, David; Santamaria, Fidel

2016-03-01

We studied the effects of non-Markovian power-law voltage dependent conductances on the generation of action potentials and spiking patterns in a Hodgkin-Huxley model. To implement slow-adapting power-law dynamics of the gating variables of the potassium, n, and sodium, m and h, conductances we used fractional derivatives of order η≤1. The fractional derivatives were used to solve the kinetic equations of each gate. We systematically classified the properties of each gate as a function of η. We then tested if the full model could generate action potentials with the different power-law behaving gates. Finally, we studied the patterns of action potential that emerged in each case. Our results show the model produces a wide range of action potential shapes and spiking patterns in response to constant current stimulation as a function of η. In comparison with the classical model, the action potential shapes for power-law behaving potassium conductance (n gate) showed a longer peak and shallow hyperpolarization; for power-law activation of the sodium conductance (m gate), the action potentials had a sharp rise time; and for power-law inactivation of the sodium conductance (h gate) the spikes had wider peak that for low values of η replicated pituitary- and cardiac-type action potentials. With all physiological parameters fixed a wide range of spiking patterns emerged as a function of the value of the constant input current and η, such as square wave bursting, mixed mode oscillations, and pseudo-plateau potentials. Our analyses show that the intrinsic memory trace of the fractional derivative provides a negative feedback mechanism between the voltage trace and the activity of the power-law behaving gate variable. As a consequence, power-law behaving conductances result in an increase in the number of spiking patterns a neuron can generate and, we propose, expand the computational capacity of the neuron.

Universal scaling laws of diffusion in two-dimensional granular liquids.

PubMed

Wang, Chen-Hung; Yu, Szu-Hsuan; Chen, Peilong

2015-06-01

We find, in a two-dimensional air table granular system, that the reduced diffusion constant D* and excess entropy S(2) follow two distinct scaling laws: D*∼e(S(2)*) for dense liquids and D∼e(3S(2)*) for dilute ones. The scaling for dense liquids is very similar to that for three-dimensional liquids proposed previously [M. Dzugutov, Nature (London) 381, 137 (1996); A. Samanta et al., Phys. Rev. Lett. 92, 145901 (2004)]. In the dilute regime, a power law [Y. Rosenfeld, J. Phys.: Condens. Matter 11, 5415 (1999)] also fits our data reasonably well. In our system, particles experience low air drag dissipation and interact with each others through embedded magnets. These near-conservative many-body interactions are responsible for the measured Gaussian velocity distribution functions and the scaling laws. The dominance of cage relaxations in dense liquids leads to the different scaling laws for dense and dilute regimes.

Band gap scaling laws in group IV nanotubes.

PubMed

Wang, Chongze; Fu, Xiaonan; Guo, Yangyang; Guo, Zhengxiao; Xia, Congxin; Jia, Yu

2017-03-17

By using the first-principles calculations, the band gap properties of nanotubes formed by group IV elements have been investigated systemically. Our results reveal that for armchair nanotubes, the energy gaps at K points in the Brillouin zone decrease as 1/r scaling law with the radii (r) increasing, while they are scaled by -1/r 2  + C at Γ points, here, C is a constant. Further studies show that such scaling law of K points is independent of both the chiral vector and the type of elements. Therefore, the band gaps of nanotubes for a given radius can be determined by these scaling laws easily. Interestingly, we also predict the existence of indirect band gap for both germanium and tin nanotubes. Our new findings provide an efficient way to determine the band gaps of group IV element nanotubes by knowing the radii, as well as to facilitate the design of functional nanodevices.

Algebraic aspects of evolution partial differential equation arising in the study of constant elasticity of variance model from financial mathematics

NASA Astrophysics Data System (ADS)

Motsepa, Tanki; Aziz, Taha; Fatima, Aeeman; Khalique, Chaudry Masood

2018-03-01

The optimal investment-consumption problem under the constant elasticity of variance (CEV) model is investigated from the perspective of Lie group analysis. The Lie symmetry group of the evolution partial differential equation describing the CEV model is derived. The Lie point symmetries are then used to obtain an exact solution of the governing model satisfying a standard terminal condition. Finally, we construct conservation laws of the underlying equation using the general theorem on conservation laws.

Evaluation and Prediction of Henry’s Law Constants and Aqueous Solubilities for Solvents and Hydrocarbon Fuel Components. Volume 1. Technical Discussion

DTIC Science & Technology

1987-09-01

spectrum cap with a Teflonýliner facing toward the bottle headspace. These liners are used only once to prevent adsorption of test compound into the...used to predict carbon adsorption of contaminants, and the air or steam stripping behavior for a given organic. For highly soluble materials these data...first of these stems from the organic-solute losses due to adsorption of the solute on the flask walls or to evaporation. This quantity is somewhat

On the behavior of solutions of xenon in liquid n-alkanes: solubility of xenon in n-pentane and n-hexane.

PubMed

Bonifácio, Rui P M F; Martins, Luís F G; McCabe, Clare; Filipe, Eduardo J M

2010-12-09

The solubility of xenon in liquid n-pentane and n-hexane has been studied experimentally, theoretically, and by computer simulation. Measurements of the solubility are reported for xenon + n-pentane as a function of temperature from 254 to 305 K. The uncertainty in the experimental data is less than 0.15%. The thermodynamic functions of solvation such as the standard Gibbs energy, enthalpy, and entropy of solvation have been calculated from Henry's law coefficients for xenon + n-pentane solutions and also for xenon + n-hexane, which were reported in previous work. The results provide a further example of the similarity between the xenon + n-alkane interaction and the n-alkane + n-alkane interactions. Using the SAFT-VR approach we were able to quantitatively predict the experimental solubility for xenon in n-pentane and semiquantitatively that of xenon in n-hexane using simple Lorentz-Berthelot combining rules to describe the unlikely interaction. Henry's constants at infinite dilution for xenon + n-pentane and xenon + n-hexane were also calculated by Monte Carlo simulation using a united atom force field to describe the n-alkane and the Widom test particle insertion method.

Avalanches and power-law behaviour in lung inflation

NASA Astrophysics Data System (ADS)

Suki, Béla; Barabási, Albert-László; Hantos, Zoltán; Peták, Ferenc; Stanley, H. Eugene

1994-04-01

WHEN lungs are emptied during exhalation, peripheral airways close up1. For people with lung disease, they may not reopen for a significant portion of inhalation, impairing gas exchange2,3. A knowledge of the mechanisms that govern reinflation of collapsed regions of lungs is therefore central to the development of ventilation strategies for combating respiratory problems. Here we report measurements of the terminal airway resistance, Rt , during the opening of isolated dog lungs. When inflated by a constant flow, Rt decreases in discrete jumps. We find that the probability distribution of the sizes of the jumps and of the time intervals between them exhibit power-law behaviour over two decades. We develop a model of the inflation process in which 'avalanches' of airway openings are seen-with power-law distributions of both the size of avalanches and the time intervals between them-which agree quantitatively with those seen experimentally, and are reminiscent of the power-law behaviour observed for self-organized critical systems4. Thus power-law distributions, arising from avalanches associated with threshold phenomena propagating down a branching tree structure, appear to govern the recruitment of terminal airspaces.

Atomistic simulation of CO2 solubility in poly(ethylene oxide) oligomers

NASA Astrophysics Data System (ADS)

Hong, Bingbing; Panagiotopoulos, Athanassios Z.

2014-06-01

We have performed atomistic molecular dynamics simulations coupled with thermodynamic integration to obtain the excess chemical potential and pressure-composition phase diagrams for CO2 in poly(ethylene oxide) oligomers. Poly(ethylene oxide) dimethyl ether, CH3O(CH2CH2O)nCH3 (PEO for short) is a widely applied physical solvent that forms the major organic constituent of a class of novel nanoparticle-based absorbents. Good predictions were obtained for pressure-composition-density relations for CO2 + PEO oligomers (2 ≤ n ≤ 12), using the Potoff force field for PEO [J. Chem. Phys. 136, 044514 (2012)] together with the TraPPE model for CO2 [AIChE J. 47, 1676 (2001)]. Water effects on Henry's constant of CO2 in PEO have also been investigated. Addition of modest amounts of water in PEO produces a relatively small increase in Henry's constant. Dependence of the calculated Henry's constant on the weight percentage of water falls on a temperature-dependent master curve, irrespective of PEO chain length.

A test of star formation laws in disk galaxies. II. Dependence on dynamical properties

DOE Office of Scientific and Technical Information (OSTI.GOV)

Suwannajak, Chutipong; Tan, Jonathan C.; Leroy, Adam K.

2014-05-20

We use the observed radial profiles of the mass surface densities of total, Σ {sub g}, and molecular, Σ{sub H2}, gas, rotation velocity, and star formation rate (SFR) surface density, Σ{sub sfr}, of the molecular-rich (Σ{sub H2} ≥ Σ{sub HI}/2) regions of 16 nearby disk galaxies to test several star formation (SF) laws: a 'Kennicutt-Schmidt (K-S)' law, Σ{sub sfr}=A{sub g}Σ{sub g,2}{sup 1.5}; a 'Constant Molecular' law, Σ{sub sfr} = A {sub H2}Σ{sub H2,2}; the turbulence-regulated laws of Krumholz and McKee (KM05) and Krumholz, McKee, and Tumlinson (KMT09); a 'Gas-Ω' law, Σ{sub sfr}=B{sub Ω}Σ{sub g}Ω; and a shear-driven 'giant molecular cloudmore » (GMC) Collision' law, Σ{sub sfr} = B {sub CC}Σ {sub g}Ω(1-0.7β), where β ≡ d ln v {sub circ}/d ln r. If allowed one free normalization parameter for each galaxy, these laws predict the SFR with rms errors of factors of 1.4-1.8. If a single normalization parameter is used by each law for the entire galaxy sample, then rms errors range from factors of 1.5-2.1. Although the Constant Molecular law gives the smallest rms errors, the improvement over the KMT, K-S, and GMC Collision laws is not especially significant, particularly given the different observational inputs that the laws utilize and the scope of included physics, which ranges from empirical relations to detailed treatment of interstellar medium processes. We next search for systematic variation of SF law parameters with local and global galactic dynamical properties of disk shear rate (related to β), rotation speed, and presence of a bar. We demonstrate with high significance that higher shear rates enhance SF efficiency per local orbital time. Such a trend is expected if GMC collisions play an important role in SF, while an opposite trend would be expected if the development of disk gravitational instabilities is the controlling physics.« less

Piéron’s Law and Optimal Behavior in Perceptual Decision-Making

PubMed Central

van Maanen, Leendert; Grasman, Raoul P. P. P.; Forstmann, Birte U.; Wagenmakers, Eric-Jan

2012-01-01

Piéron’s Law is a psychophysical regularity in signal detection tasks that states that mean response times decrease as a power function of stimulus intensity. In this article, we extend Piéron’s Law to perceptual two-choice decision-making tasks, and demonstrate that the law holds as the discriminability between two competing choices is manipulated, even though the stimulus intensity remains constant. This result is consistent with predictions from a Bayesian ideal observer model. The model assumes that in order to respond optimally in a two-choice decision-making task, participants continually update the posterior probability of each response alternative, until the probability of one alternative crosses a criterion value. In addition to predictions for two-choice decision-making tasks, we extend the ideal observer model to predict Piéron’s Law in signal detection tasks. We conclude that Piéron’s Law is a general phenomenon that may be caused by optimality constraints. PMID:22232572

A reservoir of time constants for memory traces in cortical neurons

PubMed Central

Bernacchia, Alberto; Seo, Hyojung; Lee, Daeyeol; Wang, Xiao-Jing

2011-01-01

According to reinforcement learning theory of decision making, reward expectation is computed by integrating past rewards with a fixed timescale. By contrast, we found that a wide range of time constants is available across cortical neurons recorded from monkeys performing a competitive game task. By recognizing that reward modulates neural activity multiplicatively, we found that one or two time constants of reward memory can be extracted for each neuron in prefrontal, cingulate, and parietal cortex. These timescales ranged from hundreds of milliseconds to tens of seconds, according to a power-law distribution, which is consistent across areas and reproduced by a “reservoir” neural network model. These neuronal memory timescales were weakly but significantly correlated with those of monkey's decisions. Our findings suggest a flexible memory system, where neural subpopulations with distinct sets of long or short memory timescales may be selectively deployed according to the task demands. PMID:21317906

Solubility and reactivity of HNCO in water: insights into HNCO's fate in the atmosphere

NASA Astrophysics Data System (ADS)

Borduas, N.; Place, B.; Wentworth, G. R.; Abbatt, J. P. D.; Murphy, J. G.

2016-01-01

A growing number of ambient measurements of isocyanic acid (HNCO) are being made, yet little is known about its fate in the atmosphere. To better understand HNCO's loss processes and particularly its atmospheric partitioning behaviour, we measure its effective Henry's Law coefficient KHeff with a bubbler experiment using chemical ionization mass spectrometry as the gas phase analytical technique. By conducting experiments at different pH values and temperature, a Henry's Law coefficient KH of 26 ± 2 M atm-1 is obtained, with an enthalpy of dissolution of -34 ± 2 kJ mol-1, which translates to a KHeff of 31 M atm-1 at 298 K and at pH 3. Our approach also allows for the determination of HNCO's acid dissociation constant, which we determine to be Ka = 2.1 ± 0.2 × 10-4 M at 298 K. Furthermore, by using ion chromatography to analyze aqueous solution composition, we revisit the hydrolysis kinetics of HNCO at different pH and temperature conditions. Three pH-dependent hydrolysis mechanisms are in play and we determine the Arrhenius expressions for each rate to be k1 = (4.4 ± 0.2) × 107 exp(-6000 ± 240/T) M s-1, k2 = (8.9 ± 0.9) × 106 exp(-6770 ± 450/T) s-1 and k3 = (7.2 ± 1.5) × 108 exp(-10 900 ± 1400/T) s-1, where k1 is for HNCO + H++ H2O → NH4++ CO2, k2 is for HNCO + H2O → NH3 + CO2 and k3 is for NCO-+ 2 H2O → NH3+ HCO3-. HNCO's lifetime against hydrolysis is therefore estimated to be 10 days to 28 years at pH values, liquid water contents, and temperatures relevant to tropospheric clouds, years in oceans and months in human blood. In all, a better parameterized Henry's Law coefficient and hydrolysis rates of HNCO allow for more accurate predictions of its concentration in the atmosphere and consequently help define exposure of this toxic molecule.

Modular rate laws for enzymatic reactions: thermodynamics, elasticities and implementation.

PubMed

Liebermeister, Wolfram; Uhlendorf, Jannis; Klipp, Edda

2010-06-15

Standard rate laws are a key requisite for systematically turning metabolic networks into kinetic models. They should provide simple, general and biochemically plausible formulae for reaction velocities and reaction elasticities. At the same time, they need to respect thermodynamic relations between the kinetic constants and the metabolic fluxes and concentrations. We present a family of reversible rate laws for reactions with arbitrary stoichiometries and various types of regulation, including mass-action, Michaelis-Menten and uni-uni reversible Hill kinetics as special cases. With a thermodynamically safe parameterization of these rate laws, parameter sets obtained by model fitting, sampling or optimization are guaranteed to lead to consistent chemical equilibrium states. A reformulation using saturation values yields simple formulae for rates and elasticities, which can be easily adjusted to the given stationary flux distributions. Furthermore, this formulation highlights the role of chemical potential differences as thermodynamic driving forces. We compare the modular rate laws to the thermodynamic-kinetic modelling formalism and discuss a simplified rate law in which the reaction rate directly depends on the reaction affinity. For automatic handling of modular rate laws, we propose a standard syntax and semantic annotations for the Systems Biology Markup Language. An online tool for inserting the rate laws into SBML models is freely available at www.semanticsbml.org. Supplementary data are available at Bioinformatics online.

Henry Adams’s Life of George Cabot Lodge: A Portrait of the Artist as an Alienated Man

DTIC Science & Technology

1994-07-20

literary tradition, especially as had been handed down from Adams’s Puritan forebears. My aim is to present the most complete critical study of this...several critics have pointed to this book as evidence of Adams’s diminished talents--when a careful study of the book in fact demonstrates otherwise...critical studies have given more than cursory attention to the Life of Lodge: J. C. Levenson, The Mind and Art of Henry Adams (1957); George Hochfield

Surface-water/ground-water interaction along reaches of the Snake River and Henrys Fork, Idaho

USGS Publications Warehouse

Hortness, Jon E.; Vidmar, Peter

2005-01-01

Declining water levels in the eastern Snake River Plain aquifer and decreases in spring discharges from the aquifer to the Snake River have spurred studies to improve understanding of the surface-water/ground-water interaction on the plain. This study was done to estimate streamflow gains and losses along specific reaches of the Snake River and Henrys Fork and to compare changes in gain and loss estimates to changes in ground-water levels over time. Data collected during this study will be used to enhance the conceptual model of the hydrologic system and to refine computer models of ground-water flow and surface-water/ground-water interactions. Estimates of streamflow gains and losses along specific subreaches of the Snake River and Henrys Fork, based on the results of five seepage studies completed during 2001?02, varied greatly across the study area, ranging from a loss estimate of 606 ft3/s in a subreach of the upper Snake River near Heise to a gain estimate of 3,450 ft3/s in a subreach of the Snake River that includes Thousand Springs. Some variations over time also were apparent in specific subreaches. Surface spring flow accounted for much of the inflow to subreaches having large gain estimates. Several subreaches alternately gained and lost streamflow during the study. Changes in estimates of streamflow gains and losses along some of the subreaches were compared with changes in water levels, measured at three different times during 2001?02, in adjacent wells. In some instances, a strong relation between changes in estimates of gains or losses and changes in ground-water levels was apparent.

Thomas Henry Osler (1875-1936): a descendant of Sir William Osler's great-uncle and the founder of a South African medical dynasty.

PubMed

Myers, Edward D

2009-08-01

Sir William Osler's great-uncle Benjamin emigrated from England to South Africa with his wife and children in 1820. From Benjamin's son, Stephen, descended a large family of Oslers including at least seven doctors and dentists. This paper describes the lives and careers of Thomas Henry, and his medical and dental descendants.

The cosmological constant and dark energy

NASA Astrophysics Data System (ADS)

Peebles, P. J.; Ratra, Bharat

2003-04-01

Physics welcomes the idea that space contains energy whose gravitational effect approximates that of Einstein’s cosmological constant, Λ; today the concept is termed dark energy or quintessence. Physics also suggests that dark energy could be dynamical, allowing for the arguably appealing picture of an evolving dark-energy density approaching its natural value, zero, and small now because the expanding universe is old. This would alleviate the classical problem of the curious energy scale of a millielectron volt associated with a constant Λ. Dark energy may have been detected by recent cosmological tests. These tests make a good scientific case for the context, in the relativistic Friedmann-Lemaître model, in which the gravitational inverse-square law is applied to the scales of cosmology. We have well-checked evidence that the mean mass density is not much more than one-quarter of the critical Einstein de Sitter value. The case for detection of dark energy is not yet as convincing but still serious; we await more data, which may be derived from work in progress. Planned observations may detect the evolution of the dark-energy density; a positive result would be a considerable stimulus for attempts at understanding the microphysics of dark energy. This review presents the basic physics and astronomy of the subject, reviews the history of ideas, assesses the state of the observational evidence, and comments on recent developments in the search for a fundamental theory.

When is an imine not an imine? Unusual reactivity of a series of Cu(II) imine-pyridine complexes and their exploitation for the Henry reaction.

PubMed

Cooper, Christine J; Jones, Matthew D; Brayshaw, Simon K; Sonnex, Benjamin; Russell, Mark L; Mahon, Mary F; Allan, David R

2011-04-14

In this paper we report the synthesis and solid-state structures for a series of pyridine based Cu(II) complexes and preliminary data for the asymmetric Henry reaction. Interestingly, the solid-state structures indicate the incorporation of an alcohol into one of the imine groups of the ligand, forming a rare α-amino ether group. The complexes have been studied via single crystal X-ray diffraction, EPR spectroscopy and mass spectrometry. Intriguingly, it has been observed that the alcohol only adds to one of the imine moieties. Density functional theory (DFT) calculations have also been employed to rationalise the observed structures. The Cu(II) complexes have been tested in the asymmetric Henry reaction (benzaldehyde + nitromethane or nitroethane) with ee's up to 84% being achieved as well as high conversions and modest diastereoselectivities. © The Royal Society of Chemistry 2011

Protein dielectric constants determined from NMR chemical shift perturbations.

PubMed

Kukic, Predrag; Farrell, Damien; McIntosh, Lawrence P; García-Moreno E, Bertrand; Jensen, Kristine Steen; Toleikis, Zigmantas; Teilum, Kaare; Nielsen, Jens Erik

2013-11-13

Understanding the connection between protein structure and function requires a quantitative understanding of electrostatic effects. Structure-based electrostatic calculations are essential for this purpose, but their use has been limited by a long-standing discussion on which value to use for the dielectric constants (ε(eff) and ε(p)) required in Coulombic and Poisson-Boltzmann models. The currently used values for ε(eff) and ε(p) are essentially empirical parameters calibrated against thermodynamic properties that are indirect measurements of protein electric fields. We determine optimal values for ε(eff) and ε(p) by measuring protein electric fields in solution using direct detection of NMR chemical shift perturbations (CSPs). We measured CSPs in 14 proteins to get a broad and general characterization of electric fields. Coulomb's law reproduces the measured CSPs optimally with a protein dielectric constant (ε(eff)) from 3 to 13, with an optimal value across all proteins of 6.5. However, when the water-protein interface is treated with finite difference Poisson-Boltzmann calculations, the optimal protein dielectric constant (ε(p)) ranged from 2 to 5 with an optimum of 3. It is striking how similar this value is to the dielectric constant of 2-4 measured for protein powders and how different it is from the ε(p) of 6-20 used in models based on the Poisson-Boltzmann equation when calculating thermodynamic parameters. Because the value of ε(p) = 3 is obtained by analysis of NMR chemical shift perturbations instead of thermodynamic parameters such as pK(a) values, it is likely to describe only the electric field and thus represent a more general, intrinsic, and transferable ε(p) common to most folded proteins.

Comparative study of flare control laws. [optimal control of b-737 aircraft approach and landing

NASA Technical Reports Server (NTRS)

Nadkarni, A. A.; Breedlove, W. J., Jr.

1979-01-01

A digital 3-D automatic control law was developed to achieve an optimal transition of a B-737 aircraft between various initial glid slope conditions and the desired final touchdown condition. A discrete, time-invariant, optimal, closed-loop control law presented for a linear regulator problem, was extended to include a system being acted upon by a constant disturbance. Two forms of control laws were derived to solve this problem. One method utilized the feedback of integral states defined appropriately and augmented with the original system equations. The second method formulated the problem as a control variable constraint, and the control variables were augmented with the original system. The control variable constraint control law yielded a better performance compared to feedback control law for the integral states chosen.

HCl Vapour Pressures and Reaction Probabilities for ClONO2 + HCl on Liquid H2SO4-HNO3-HCl-H20 Solutions

NASA Technical Reports Server (NTRS)

Elrod, M. J.; Koch, R. E.; Kim, J. E.; Molina, M. J.

1995-01-01

Henry's Law solubility constants for HCl have been measured for liquid H2SO4-HNO3-HCl-H2O solutions; the results are in good agreement with predictions from published semiempirical models. The ClONO2 + HCl reaction on the surfaces of such solutions with compositions simulating those of stratospheric aerosols has been investigated; as the composition changes following the temperature drop characteristic of the high-latitude stratosphere the reaction probability gamma increases rapidly. Furthermore, the gamma values remain essentially unchanged when HN03 uptake is neglected; the controlling factor appears to be the solubility of HCl. These results corroborate our earlier suggestion that supercooled liquid sulfate aerosols promote chlorine activation at low temperatures as efficiently as solid polar stratospheric cloud particles.

Heterogeneous Interactions of Acetaldehyde and Sulfuric Acid

NASA Technical Reports Server (NTRS)

Michelsen, R. R.; Ashbourn, S. F. M.; Iraci, L. T.

2004-01-01

The uptake of acetaldehyde [CH3CHO] by aqueous sulfuric acid has been studied via Knudsen cell experiments over ranges of temperature (210-250 K) and acid concentration (40-80 wt. %) representative of the upper troposphere. The Henry's law constants for acetaldehyde calculated from these data range from 6 x 10(exp 2) M/atm for 40 wt. % H2SO4 at 228 K to 2 x 10(exp 5) M/atm for 80 wt. % H2SO4 at 212 K. In some instances, acetaldehyde uptake exhibits apparent steady-state loss. The possible sources of this behavior, including polymerization, will be explored. Furthermore, the implications for heterogeneous reactions of aldehydes in sulfate aerosols in the upper troposphere will be discussed.

Improved one-dimensional area law for frustration-free systems

NASA Astrophysics Data System (ADS)

Arad, Itai; Landau, Zeph; Vazirani, Umesh

2012-05-01

We present a new proof for the 1D area law for frustration-free systems with a constant gap, which exponentially improves the entropy bound in Hastingsâ 1D area law and which is tight to within a polynomial factor. For particles of dimension d, spectral gap ɛ>0, and interaction strength at most J, our entropy bound is S1D≤O(1)·X3log8X, where X=def(Jlogd)/ɛ. Our proof is completely combinatorial, combining the detectability lemma with basic tools from approximation theory. In higher dimensions, when the bipartitioning area is |∂L|, we use additional local structure in the proof and show that S≤O(1)·|∂L|2log6|∂L|·X3log8X. This is at the cusp of being nontrivial in the 2D case, in the sense that any further improvement would yield a subvolume law.

Contingency and statistical laws in replicate microbial closed ecosystems.

PubMed

Hekstra, Doeke R; Leibler, Stanislas

2012-05-25

Contingency, the persistent influence of past random events, pervades biology. To what extent, then, is each course of ecological or evolutionary dynamics unique, and to what extent are these dynamics subject to a common statistical structure? Addressing this question requires replicate measurements to search for emergent statistical laws. We establish a readily replicated microbial closed ecosystem (CES), sustaining its three species for years. We precisely measure the local population density of each species in many CES replicates, started from the same initial conditions and kept under constant light and temperature. The covariation among replicates of the three species densities acquires a stable structure, which could be decomposed into discrete eigenvectors, or "ecomodes." The largest ecomode dominates population density fluctuations around the replicate-average dynamics. These fluctuations follow simple power laws consistent with a geometric random walk. Thus, variability in ecological dynamics can be studied with CES replicates and described by simple statistical laws. Copyright © 2012 Elsevier Inc. All rights reserved.

77 FR 13491 - Approval and Promulgation of Implementation Plans and Designations of Areas for Air Quality...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-03-07

..., Douglas, Fayette, Forsyth, Fulton, Gwinnett, Hall, Henry, Newton, Paulding, Rockdale, Spalding and Walton... would not impose additional requirements beyond those imposed by state law. For that reason, this action... substantial direct costs on tribal governments or preempt tribal law. The Congressional Review Act, 5 U.S.C...

76 FR 77950 - Approval and Promulgation of Implementation Plans and Designations of Areas for Air Quality...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-12-15

..., Gwinnett, Hall, Henry, Newton, Paulding, Rockdale, Spalding and Walton Counties in Georgia. On June 23... additional requirements beyond those imposed by state law. For that reason, this proposed action: Is not a... tribal law. List of Subjects in 40 CFR Part 52 Environmental protection, Air pollution control...

Participatory Lecture Demonstrations.

ERIC Educational Resources Information Center

Battino, Rubin

1979-01-01

The use of participatory lecture demonstrations in the classroom is described. Examples are given for the following topics: chromatography, chemical kinetics, balancing equations, the gas laws, kinetic molecular theory, Henry's law of gas solubility, electronic energy levels in atoms, and translational, vibrational, and rotational energies of…

Artist as Educator? Assessing the Pedagogic Role of Folly in the Early Work of the Anglo-Swiss Artist Henry Fuseli (1741-1825)

ERIC Educational Resources Information Center

Smith, Hester Camilla

2010-01-01

This article examines a group of five ink, pen and wash drawings produced by the Anglo-Swiss artist Henry Fuseli in the mid-eighteenth century in Zurich. The drawings were produced for a "Narrenbuch" (Book of Fools) uniting visual images of folly with humorous slogans. The drawings are significant in that they imitate sixteenth-century…

Scaling laws in decaying helical hydromagnetic turbulence

NASA Astrophysics Data System (ADS)

Christensson, M.; Hindmarsh, M.; Brandenburg, A.

2005-07-01

We study the evolution of growth and decay laws for the magnetic field coherence length ξ, energy E_M and magnetic helicity H in freely decaying 3D MHD turbulence. We show that with certain assumptions, self-similarity of the magnetic power spectrum alone implies that ξ σm t1/2. This in turn implies that magnetic helicity decays as Hσm t-2s, where s=(ξ_diff/ξH)2, in terms of ξ_diff, the diffusion length scale, and ξ_H, a length scale defined from the helicity power spectrum. The relative magnetic helicity remains constant, implying that the magnetic energy decays as E_M σm t-1/2-2s. The parameter s is inversely proportional to the magnetic Reynolds number Re_M, which is constant in the self-similar regime.

From laws of inference to protein folding dynamics.

PubMed

Tseng, Chih-Yuan; Yu, Chun-Ping; Lee, H C

2010-08-01

Protein folding dynamics is one of major issues constantly investigated in the study of protein functions. The molecular dynamic (MD) simulation with the replica exchange method (REM) is a common theoretical approach considered. Yet a trade-off in applying the REM is that the dynamics toward the native configuration in the simulations seems lost. In this work, we show that given REM-MD simulation results, protein folding dynamics can be directly derived from laws of inference. The applicability of the resulting approach, the entropic folding dynamics, is illustrated by investigating a well-studied Trp-cage peptide. Our results are qualitatively comparable with those from other studies. The current studies suggest that the incorporation of laws of inference and physics brings in a comprehensive perspective on exploring the protein folding dynamics.

The enigmatic figure of Dr Henry Maudsley (1835-1918).

PubMed

Pantelidou, Maria; Demetriades, Andreas K

2014-08-01

In spite of his contribution to psychiatry in 19th century Britain, Henry Maudsley remains a mysterious figure, a man mostly known for his donation to the London County Council for the building of the Maudsley Hospital and for The Maudsley Annual Lecture created in honour of his benevolence. Besides Sir Aubrey Lewis' article in 1951 and Michael Collie's attempt in 1988 to construct a biographical study on Maudsley, there does not seem to be any current endeavour to tell the story of his life, whereas Trevor Turner's contribution to the 2004 Oxford Dictionary of National Biography gives a somewhat scathing but unattributed account of Maudsley's personality. This essay attempts to explore his contributions to the Medico-Psychological Association (MPA), the current Royal College of Psychiatrists, his editorship of the Journal of Mental Health (currently named the British Journal of Psychiatry), his literary contributions and his vision for a psychiatric hospital. This essay is an attempt to demystify his figure and to explore some of the rumours and criticisms surrounding his name and the reasons why so little has been written about him. It is also a venture to unravel his complex personality and his intricate philosophy. © The Author(s) 2014 Reprints and permissions: sagepub.co.uk/journalsPermissions.nav.

HENRY H. CHEEK AND TRANSFORMISM: NEW LIGHT ON CHARLES DARWIN'S EDINBURGH BACKGROUND.

PubMed

Jenkins, Bill

2015-06-20

Evidence for the transformist ideas espoused by Henry H. Cheek (1807-33), a contemporary of Charles Darwin's at the University of Edinburgh, sheds new light on the intellectual environment of Edinburgh in the late 1820s and early 1830s. Cheek was the author of several papers dealing with the transmutation of species influenced by the theories of Etienne Geoffroy Saint-Hilaire (1772-1844), Jean-Baptiste Lamarck (1744-1829) and the Comte de Buffon (1707-88). Some of these were read to student societies, others appeared in the Edinburgh Journal of Natural and Geographical Science, which Cheek edited between 1829 and 1831. His writings give us a valuable window onto some of the transformist theories that were circulating among Darwin's fellow medical students in the late 1820s, to which Darwin would have been exposed during his time in Edinburgh, and for which little other concrete evidence survives.

Constraints on cosmological parameters in power-law cosmology

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rani, Sarita; Singh, J.K.; Altaibayeva, A.

In this paper, we examine observational constraints on the power law cosmology; essentially dependent on two parameters H{sub 0} (Hubble constant) and q (deceleration parameter). We investigate the constraints on these parameters using the latest 28 points of H(z) data and 580 points of Union2.1 compilation data and, compare the results with the results of ΛCDM . We also forecast constraints using a simulated data set for the future JDEM, supernovae survey. Our studies give better insight into power law cosmology than the earlier done analysis by Kumar [arXiv:1109.6924] indicating it tuning well with Union2.1 compilation data but not withmore » H(z) data. However, the constraints obtained on and i.e. H{sub 0} average and q average using the simulated data set for the future JDEM, supernovae survey are found to be inconsistent with the values obtained from the H(z) and Union2.1 compilation data. We also perform the statefinder analysis and find that the power-law cosmological models approach the standard ΛCDM model as q → −1. Finally, we observe that although the power law cosmology explains several prominent features of evolution of the Universe, it fails in details.« less

Slow Crack Growth of Brittle Materials With Exponential Crack-Velocity Formulation. Part 3; Constant Stress and Cyclic Stress Experiments

NASA Technical Reports Server (NTRS)

Choi, Sung R.; Nemeth, Noel N.; Gyekenyesi, John P.

2002-01-01

The previously determined life prediction analysis based on an exponential crack-velocity formulation was examined using a variety of experimental data on advanced structural ceramics tested under constant stress and cyclic stress loading at ambient and elevated temperatures. The data fit to the relation between the time to failure and applied stress (or maximum applied stress in cyclic loading) was very reasonable for most of the materials studied. It was also found that life prediction for cyclic stress loading from data of constant stress loading in the exponential formulation was in good agreement with the experimental data, resulting in a similar degree of accuracy as compared with the power-law formulation. The major limitation in the exponential crack-velocity formulation, however, was that the inert strength of a material must be known a priori to evaluate the important slow-crack-growth (SCG) parameter n, a significant drawback as compared with the conventional power-law crack-velocity formulation.

Excuse Me. Do You Speak Digital?: Harvard's John Palfrey Explores What It's Like to Be a Digital Native

ERIC Educational Resources Information Center

Harris, Christopher

2009-01-01

John Palfrey is one busy guy, with an impressive gig. In 2008, he was named the Henry N. Ess III Professor of Law and Vice Dean for Library and Information Resources at Harvard Law School. And when he's not teaching courses on intellectual property and Internet law, there's a good chance he's overseeing the L school's research library. Palfrey,…

A Naturally-Calibrated Flow Law for Quartz

NASA Astrophysics Data System (ADS)

Lusk, A. D.; Platt, J. P.

2017-12-01

Flow laws for power-law behavior of quartz deforming by crystal-plastic processes with grain size sensitive creep included take the general form: ė = A σn f(H2O) exp(-Q/RT) dmWhere A - prefactor; σ - differential stress; n - stress exponent; f(H2O) - water fugacity; Q - activation energy; R - gas constant; T - temperature (K); d - grain size sensitivity raised to power m. Assuming the dynamically recrystallized grain size for quartz follows the peizometric relationship, substitute dm = (K σ-p)m, where K - piezometric constant; σ - differential stress; p - piezometric exponent. Rearranging the above flow law: ė = A K σ(n-pm) f(H2O) exp(-Q/RT)We use deformation temperatures, paleo-stresses, and strain rates calculated from rocks deformed in the Caledonian Orogeny, NW Scotland, along with existing experimental data, to compare naturally-calibrated values of stress exponent (n-pm) and activation energy (Q) to those determined experimentally. Microstructures preserved in the naturally-strained rocks closely resemble those produced by experimental work, indicating that quartz was deformed by the same mechanism(s). These observations validate the use of predetermined values for A as well as the addition of experimental data to calculate Q. Values for f(H2O) are based on calculated pressure and temperature conditions. Using the abovementioned constraints, we compare results, discuss challenges, and explore implications of naturally- vs. experimentally-derived flow laws for dislocation creep in quartz. Rocks used for this study include quartzite and quartz-rich psammite of the Cambrian-Ordovician shelf sequence and tectonically overlying Moine Supergroup. In both cases, quartz is likely the primary phase that controlled rheological behavior. We use the empirically derived piezometer for the dynamically recrystallized grain size of quartz to calculate the magnitude of differential stress, along with the Ti-in-quartz thermobarometer and the c-axis opening angle

The Universal Statistical Distributions of the Affinity, Equilibrium Constants, Kinetics and Specificity in Biomolecular Recognition

PubMed Central

Zheng, Xiliang; Wang, Jin

2015-01-01

We uncovered the universal statistical laws for the biomolecular recognition/binding process. We quantified the statistical energy landscapes for binding, from which we can characterize the distributions of the binding free energy (affinity), the equilibrium constants, the kinetics and the specificity by exploring the different ligands binding with a particular receptor. The results of the analytical studies are confirmed by the microscopic flexible docking simulations. The distribution of binding affinity is Gaussian around the mean and becomes exponential near the tail. The equilibrium constants of the binding follow a log-normal distribution around the mean and a power law distribution in the tail. The intrinsic specificity for biomolecular recognition measures the degree of discrimination of native versus non-native binding and the optimization of which becomes the maximization of the ratio of the free energy gap between the native state and the average of non-native states versus the roughness measured by the variance of the free energy landscape around its mean. The intrinsic specificity obeys a Gaussian distribution near the mean and an exponential distribution near the tail. Furthermore, the kinetics of binding follows a log-normal distribution near the mean and a power law distribution at the tail. Our study provides new insights into the statistical nature of thermodynamics, kinetics and function from different ligands binding with a specific receptor or equivalently specific ligand binding with different receptors. The elucidation of distributions of the kinetics and free energy has guiding roles in studying biomolecular recognition and function through small-molecule evolution and chemical genetics. PMID:25885453

The mathematical formulation of a generalized Hooke's law for blood vessels.

PubMed

Zhang, Wei; Wang, Chong; Kassab, Ghassan S

2007-08-01

It is well known that the stress-strain relationship of blood vessels is highly nonlinear. To linearize the relationship, the Hencky strain tensor is generalized to a logarithmic-exponential (log-exp) strain tensor to absorb the nonlinearity. A quadratic nominal strain potential is proposed to derive the second Piola-Kirchhoff stresses by differentiating the potential with respect to the log-exp strains. The resulting constitutive equation is a generalized Hooke's law. Ten material constants are needed for the three-dimensional orthotropic model. The nondimensional constant used in the log-exp strain definition is interpreted as a nonlinearity parameter. The other nine constants are the elastic moduli with respect to the log-exp strains. In this paper, the proposed linear stress-strain relation is shown to represent the pseudoelastic Fung model very well.

Development of an optimal automatic control law and filter algorithm for steep glideslope capture and glideslope tracking

NASA Technical Reports Server (NTRS)

Halyo, N.

1976-01-01

A digital automatic control law to capture a steep glideslope and track the glideslope to a specified altitude is developed for the longitudinal/vertical dynamics of a CTOL aircraft using modern estimation and control techniques. The control law uses a constant gain Kalman filter to process guidance information from the microwave landing system, and acceleration from body mounted accelerometer data. The filter outputs navigation data and wind velocity estimates which are used in controlling the aircraft. Results from a digital simulation of the aircraft dynamics and the control law are presented for various wind conditions.

The validation of a generalized Hooke's law for coronary arteries.

PubMed

Wang, Chong; Zhang, Wei; Kassab, Ghassan S

2008-01-01

The exponential form of constitutive model is widely used in biomechanical studies of blood vessels. There are two main issues, however, with this model: 1) the curve fits of experimental data are not always satisfactory, and 2) the material parameters may be oversensitive. A new type of strain measure in a generalized Hooke's law for blood vessels was recently proposed by our group to address these issues. The new model has one nonlinear parameter and six linear parameters. In this study, the stress-strain equation is validated by fitting the model to experimental data of porcine coronary arteries. Material constants of left anterior descending artery and right coronary artery for the Hooke's law were computed with a separable nonlinear least-squares method with an excellent goodness of fit. A parameter sensitivity analysis shows that the stability of material constants is improved compared with the exponential model and a biphasic model. A boundary value problem was solved to demonstrate that the model prediction can match the measured arterial deformation under experimental loading conditions. The validated constitutive relation will serve as a basis for the solution of various boundary value problems of cardiovascular biomechanics.

Henry Solomon Wellcome: A philanthropist and a pioneer sponsor of medical research in the Sudan

PubMed Central

2013-01-01

Henry Solomon Wellcome, the famous drug manufacturer had a fascinating association with the Sudan. Besides supporting tropical medicine research in this country, he established an extensive project in the Sudan that aimed at combining archeological excavations, philanthropy and social reform. This article is an archives-based account on this side of Wellcome’s association with the Sudan. The article starts with Wellcome’s early years in the American Midwest and the evolution of his career and his rise as a world-renowned drug manufacturer. After the battle of Omdurman, Wellcome visited Sudan in 1900 – 1901 where he offered to support the establishment of the research laboratories which later came to be known as the Wellcome Tropical Research Laboratories in Khartoum. He then became directly involved in the planning and running of extensive archeological excavations in the central Sudan. This project served as a field in which Wellcome found an outlet for his philanthropy. More than 4000 labourers were employed in Jebel Moya. Professional archeologists and anatomists were recruited by Wellcome to supervise the work, and all the requirements in terms of equipment were catered for. Wellcome devised a Savings Bank System whereby part of the earnings of each labourer were saved to him till the end of the season. He also introduced one of his innovations: aerial photography using box kite which was used for the first time in archeology. Wellcome made it a rule that no applicant should be turned away. The Camp Commandant had to find suitable work for each applicant, including the handicapped who were assigned to appropriate jobs like mending baskets or cutting grass for building huts. Wellcome’s welfare work had a significant impact on the local inhabitants of Jebel Moya. Henry Solomon Wellcome, 1906. Oil painting by Hugh Goldwin Riviere. Credit: Wellcome Library PMID:27493379

Analytical Considerations about the Cosmological Constant and Dark Energy

NASA Astrophysics Data System (ADS)

Abreu, Everton M. C.; de Assis, Leonardo P. G.; Dos Reis, Carlos M. L.

The accelerated expansion of the universe has now been confirmed by several independent observations including those of high redshift type Ia supernovae, and the cosmic microwave background combined with the large scale structure of the universe. Another way of presenting this kinematic property of the universe is to postulate the existence of a new and exotic entity, with negative pressure, the dark energy (DE). In spite of observationally well established, no single theoretical model provides an entirely compelling framework within which cosmic acceleration or DE can be understood. At present all existing observational data are in agreement with the simplest possibility that the cosmological constant be a candidate for DE. This case is internally self-consistent and noncontradictory. The extreme smallness of the cosmological constant expressed in either Planck, or even atomic units means only that its origin is not related to strong, electromagnetic, and weak interactions. Although in this case DE reduces to only a single fundamental constant we still have no derivation from any underlying quantum field theory for its small value. From the principles of quantum cosmologies, for example, it is possible to obtain the reason for an inverse-square law for the cosmological constant with no conflict with observations. Despite the fact that this general expression is well known, in this work we introduce families of analytical solutions for the scale factor different from the current literature. The knowledge of the scale factor behavior might shed some light on these questions mentioned above since the entire evolution of a homogeneous isotropic universe is contained in the scale factor. We use different parameters for these solutions and with these parameters we establish a connection with the equation of state for different DE scenarios.

Accurate Determination of the Values of Fundamental Physical Constants: The Basis of the New "Quantum" SI Units

NASA Astrophysics Data System (ADS)

Karshenboim, S. G.

2018-03-01

standards (such as the International prototype of the kilogram) and the isotopic composition of substances involved in precision studies in general (as standard measures for the triple point of water) and, in particular, in the determination of the fundamental constants are discussed. The perspectives of the introduction of the new quantum units, which will be free from the mentioned problems, are considered. Many physicists feel no sympathy for the International system of units (SI), believing that it does not properly reflect the character of physical laws. In fact, there are three parallel systems, namely the systems of quantities, system of their units and the related standards. The definition of the units, in particular, the SI units, above all, reflects our ability to perform precision measurements of physical values under certain conditions, in particular, to create appropriate standards. This requirement is not related to the beauty of fundamental laws of nature. More accurate determination of the fundamental constants is one of the areas where we accumulate such experience.

Unimodular Einstein-Cartan gravity: Dynamics and conservation laws

NASA Astrophysics Data System (ADS)

Bonder, Yuri; Corral, Cristóbal

2018-04-01

Unimodular gravity is an interesting approach to address the cosmological constant problem, since the vacuum energy density of quantum fields does not gravitate in this framework, and the cosmological constant appears as an integration constant. These features arise as a consequence of considering a constrained volume element 4-form that breaks the diffeomorphisms invariance down to volume preserving diffeomorphisms. In this work, the first-order formulation of unimodular gravity is presented by considering the spin density of matter fields as a source of spacetime torsion. Even though the most general matter Lagrangian allowed by the symmetries is considered, dynamical restrictions arise on their functional dependence. The field equations are obtained and the conservation laws associated with the symmetries are derived. It is found that, analogous to torsion-free unimodular gravity, the field equation for the vierbein is traceless; nevertheless, torsion is algebraically related to the spin density as in standard Einstein-Cartan theory. The particular example of massless Dirac spinors is studied, and comparisons with standard Einstein-Cartan theory are shown.

Constant fields and constant gradients in open ionic channels.

PubMed Central

Chen, D P; Barcilon, V; Eisenberg, R S

1992-01-01

Ions enter cells through pores in proteins that are holes in dielectrics. The energy of interaction between ion and charge induced on the dielectric is many kT, and so the dielectric properties of channel and pore are important. We describe ionic movement by (three-dimensional) Nemst-Planck equations (including flux and net charge). Potential is described by Poisson's equation in the pore and Laplace's equation in the channel wall, allowing induced but not permanent charge. Asymptotic expansions are constructed exploiting the long narrow shape of the pore and the relatively high dielectric constant of the pore's contents. The resulting one-dimensional equations can be integrated numerically; they can be analyzed when channels are short or long (compared with the Debye length). Traditional constant field equations are derived if the induced charge is small, e.g., if the channel is short or if the total concentration gradient is zero. A constant gradient of concentration is derived if the channel is long. Plots directly comparable to experiments are given of current vs voltage, reversal potential vs. concentration, and slope conductance vs. concentration. This dielectric theory can easily be tested: its parameters can be determined by traditional constant field measurements. The dielectric theory then predicts current-voltage relations quite different from constant field, usually more linear, when gradients of total concentration are imposed. Numerical analysis shows that the interaction of ion and channel can be described by a mean potential if, but only if, the induced charge is negligible, that is to say, the electric field is spatially constant. Images FIGURE 1 PMID:1376159

An insight into Newton's cooling law using fractional calculus

NASA Astrophysics Data System (ADS)

Mondol, Adreja; Gupta, Rivu; Das, Shantanu; Dutta, Tapati

2018-02-01

For small temperature differences between a heated body and its environment, Newton's law of cooling predicts that the instantaneous rate of change of temperature of any heated body with respect to time is proportional to the difference in temperature of the body with the ambient, time being measured in integer units. Our experiments on the cooling of different liquids (water, mustard oil, and mercury) did not fit the theoretical predictions of Newton's law of cooling in this form. The solution was done using both Caputo and Riemann-Liouville type fractional derivatives to check if natural phenomena showed any preference in mathematics. In both cases, we find that cooling of liquids has an identical value of the fractional derivative of time that increases with the viscosity of the liquid. On the other hand, the cooling studies on metal alloys could be fitted exactly by integer order time derivative equations. The proportionality constant between heat flux and temperature difference was examined with respect to variations in the depth of liquid and exposed surface area. A critical combination of these two parameters signals a change in the mode of heat transfer within liquids. The equivalence between the proportionality constants for the Caputo and Riemann-Liouville type derivatives is established.

About Time. Physics, Philosophy and the Battle Between Albert Einstein and Henri Bergson

NASA Astrophysics Data System (ADS)

Frank, Adam

The historical relationship between physics and philosophy has had many famous high and low points. The two function best when both can challenge and support each other. In this talk I explore the famous debate between Albert Einstein and Henri Bergson over the nature of time. While history rightly judged Einstein to have won the debate in terms of relativity, there were deeper aspects of Bergsons critique that remain unappreciated. We will explore the different ways philosophy approaches the issue of time. In particular, we will look at the Continental Schools\\x9D, such as Phenomenology, which brings a unique perspective to the debate lying outside the traditional approach of physicists. From this perspective questions related to the act of being an observer, its essential subjective nature and the proper context of physics can be explored.

Mapping Henry: Synchrotron-sourced X-ray fluorescence mapping and ultra-high-definition scanning of an early Tudor portrait of Henry VIII

NASA Astrophysics Data System (ADS)

Dredge, Paula; Ives, Simon; Howard, Daryl L.; Spiers, Kathryn M.; Yip, Andrew; Kenderdine, Sarah

2015-11-01

A portrait of Henry VIII on oak panel c. 1535 has recently undergone technical examination to inform questions regarding authorship and the painting's relationship to a group of similar works in the collections of the National Portrait Gallery, London, and the Society of Antiquaries. Due to previous conservation treatments of the painting, the conventional transmission X-radiograph image was difficult to interpret. As a result, the painting underwent high-definition X-ray fluorescence (XRF) elemental mapping on the X-ray fluorescence microscopy beamline of the Australian Synchrotron. Scans were conducted at 12.6 and 18.5 keV, below and above the lead (Pb) L edges, respectively. Typical scan parameters were 120 μm pixel size at 7 ms dwell time, with the largest scan covering an area 545 × 287 mm2 collected in 23 h (10.8 MP). XRF mapping of the panel has guided the conservation treatment of the painting and the revelation of previously obscured features. It has also provided insight into the process of making of the painting. The informative and detailed elemental maps, alongside ultra-high-definition scans of the painting undertaken before and after varnish and over-paint removal, have assisted in comparison of the finely painted details with the London paintings. The resolution offered by the combination of imaging techniques identifies pigment distribution at an extremely fine scale, enabling a new understanding of the artist's paint application.

Solubility of methane in water: the significance of the methane-water interaction potential.

PubMed

Konrad, Oliver; Lankau, Timm

2005-12-15

The influence of the methane-water interaction potential on the value of the Henry constant obtained from molecular dynamics simulations was investigated. The SPC, SPC/E, MSPC/E, and TIP3P potentials were used to describe water and the OPLS-UA and TraPPE potentials for methane. Nonbonding interactions between unlike atoms were calculated both with one of four mixing rules and with our new methane-water interaction potential. The Henry constants obtained from simulations using any of the mixing rules differed significantly from the experimental ones. Good agreement between simulation and experiment was achieved with the new potential over the whole temperature range.

Frequency modulation at a moving material interface and a conservation law for wave number. [acoustic wave reflection and transmission

NASA Technical Reports Server (NTRS)

Kleinstein, G. G.; Gunzburger, M. D.

1976-01-01

An integral conservation law for wave numbers is considered. In order to test the validity of the proposed conservation law, a complete solution for the reflection and transmission of an acoustic wave impinging normally on a material interface moving at a constant speed is derived. The agreement between the frequency condition thus deduced from the dynamic equations of motion and the frequency condition derived from the jump condition associated with the integral equation supports the proposed law as a true conservation law. Additional comparisons such as amplitude discontinuities and Snells' law in a moving media further confirm the stated proposition. Results are stated concerning frequency and wave number relations across a shock front as predicted by the proposed conservation law.

Henry H. Cheek and transformism: new light on Charles Darwin's Edinburgh background

PubMed Central

Jenkins, Bill

2015-01-01

Evidence for the transformist ideas espoused by Henry H. Cheek (1807–33), a contemporary of Charles Darwin's at the University of Edinburgh, sheds new light on the intellectual environment of Edinburgh in the late 1820s and early 1830s. Cheek was the author of several papers dealing with the transmutation of species influenced by the theories of Étienne Geoffroy Saint-Hilaire (1772–1844), Jean-Baptiste Lamarck (1744–1829) and the Comte de Buffon (1707–88). Some of these were read to student societies, others appeared in the Edinburgh Journal of Natural and Geographical Science, which Cheek edited between 1829 and 1831. His writings give us a valuable window onto some of the transformist theories that were circulating among Darwin's fellow medical students in the late 1820s, to which Darwin would have been exposed during his time in Edinburgh, and for which little other concrete evidence survives. PMID:26665300

Inflation with a smooth constant-roll to constant-roll era transition

NASA Astrophysics Data System (ADS)

Odintsov, S. D.; Oikonomou, V. K.

2017-07-01

In this paper, we study canonical scalar field models, with a varying second slow-roll parameter, that allow transitions between constant-roll eras. In the models with two constant-roll eras, it is possible to avoid fine-tunings in the initial conditions of the scalar field. We mainly focus on the stability of the resulting solutions, and we also investigate if these solutions are attractors of the cosmological system. We shall calculate the resulting scalar potential and, by using a numerical approach, we examine the stability and attractor properties of the solutions. As we show, the first constant-roll era is dynamically unstable towards linear perturbations, and the cosmological system is driven by the attractor solution to the final constant-roll era. As we demonstrate, it is possible to have a nearly scale-invariant power spectrum of primordial curvature perturbations in some cases; however, this is strongly model dependent and depends on the rate of the final constant-roll era. Finally, we present, in brief, the essential features of a model that allows oscillations between constant-roll eras.

Enantioselective addition of nitromethane to 2-acylpyridine N-oxides. Expanding the generation of quaternary stereocenters with the Henry reaction.

PubMed

Holmquist, Melireth; Blay, Gonzalo; Muñoz, M Carmen; Pedro, José R

2014-02-21

The direct asymmetric Henry reaction with prochiral ketones, leading to tertiary nitroaldols, is an elusive reaction so far limited to a reduced number of reactive substrates such as trifluoromethyl ketones or α-keto carbonyl compounds. Expanding the scope of this important reaction, the direct asymmetric addition of nitromethane to 2-acylpyridine N-oxides catalyzed by a BOX-Cu(II) complex to give the corresponding pyridine-derived tertiary nitroaldols having a quaternary stereogenic center with variable yields and good enantioselectivity, is described.

Diversity-oriented asymmetric catalysis (DOAC): stereochemically divergent synthesis of thiochromanes using an imidazoline-aminophenol-nickel-catalyzed Michael/Henry reaction.

PubMed

Arai, Takayoshi; Yamamoto, Yushi

2014-03-21

The (S,S)-diphenylethylenediamine-derived imidazoline-aminophenol-Ni complex catalyzed tandem asymmetric Michael/Henry reaction of 2-mercaptobenzaldehydes with β-nitrostyrenes to give the corresponding (2S,3R,4R)-2-aryl-3-nitrothiochroman-4-ols in up to 99% diastereoselectivity with 95% ee was demonstrated in diversity-oriented asymmetric catalysis. Reduction of the nitro group of the chiral thiochromanes gave a new series of (2S,3R,4R)-3-amino-2-arylthiochroman-4-ols with retention of the strereoselectivity.

Applicability of the Child-Langmuir laws versions for describing the glow discharge cathode sheath in CO2

NASA Astrophysics Data System (ADS)

Lisovskiy, Valeriy; Krol, Hennadii; Osmayev, Ruslan; Yegorenkov, Vladimir

2016-09-01

This work is devoted to the determination of the law that may be applicable to the description of the cathode sheath in CO2. To this end three versions of the Child-Langmuir law have been considered - a collision free one (for the ions moving through a cathode sheath without collisions with gas molecules) as well as two collision- related versions- one for a constant mean free path of positive ions and one for a constant mobility of positive ions. The current-voltage characteristics and the cathode sheath thickness of the glow discharge in carbon oxide have been simultaneously measured in the pressure range from 0.05 to 1 Torr and with the discharge current values up to 80 mA. The inter-electrode distance has been chosen such that the discharge consists only of the cathode sheath and a small portion of the negative glow, i.e. the experiments have been performed in short tubes. In this case the voltage drop across the cathode sheath is equal approximately to the voltage drop across the electrodes. In the whole range of the discharge conditions we have studied the cathode sheath characteristics are found to obey correctly only to the Child-Langmuir law version with a constant ion mobility. The reason for this phenomenon may be related with a significant conversion of carbon dioxide molecules.

Existence of dark matter with observed properties of cosmic microwave background radiation substantiates three conservation laws of classical physics and all principles of quantum mechanics as creates the value of Planck’s constant

NASA Astrophysics Data System (ADS)

Boriev, I. A.

2018-03-01

Astronomical data indicate a presence of dark matter (DM) in the space, what is necessary for explanation of observed dynamics of the galaxies within Newtonian mechanics. DM, at its very low density (∼10-26kg/m3), constitutes main part of the matter in the Universe, 10 times the mass of all visible cosmic bodies. No doubt, namely properties of DM, which fills space, must determine its physical properties and fundamental physical laws. Taking into account observed properties of cosmic microwave background radiation (CMBR), whose energy is ∼90% of all cosmic radiation, and understanding that this radiation is produced by DM motion, conservation laws of classical physics and principles of quantum mechanics receive their materialistic substantiation. Thus, CMBR high homogeneity and isotropy (∼10-4), and hence the same properties of DM (and space) justify momentum and angular momentum conservation laws, respectively, according to E. Noether's theorems. CMBR has black body spectrum at ∼2.7K with maximum wavelength ∼1.9·10-3m, what allows calculate the value of mechanical action produced by DM thermal motion (∼7·10-34 J·s). This value corresponds well to the Planck’s constant, which is the mechanical action too, what gives materialistic basis for all principles of quantum mechanics. Obtained results directly confirm the reality of DM existence, and show that CMBR is an observed display of DM thermal motion. Understanding that namely from DM occur known creation of electron-positron pairs as contrarily rotating material vortexes (according to their spins) let substantiate positron nature of ball lightning what first explains all its observed specific properties.

Insights into Igneous Geochemistry from Trace Element Partitioning

NASA Technical Reports Server (NTRS)

Jones, J. H.; Hanson, B. Z.

2001-01-01

Partitioning of trivalent elements into olivine are used to explore basic issues relevant to igneous geochemistry, such as Henry's law. Additional information is contained in the original extended abstract.

The hubble constant.

PubMed

Huchra, J P

1992-04-17

The Hubble constant is the constant of proportionality between recession velocity and distance in the expanding universe. It is a fundamental property of cosmology that sets both the scale and the expansion age of the universe. It is determined by measurement of galaxy The Hubble constant is the constant of proportionality between recession velocity and development of new techniques for the measurements of galaxy distances, both calibration uncertainties and debates over systematic errors remain. Current determinations still range over nearly a factor of 2; the higher values favored by most local measurements are not consistent with many theories of the origin of large-scale structure and stellar evolution.

COSMOLOGY OF CHAMELEONS WITH POWER-LAW COUPLINGS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mota, David F.; Winther, Hans A.

2011-05-20

In chameleon field theories, a scalar field can couple to matter with gravitational strength and still evade local gravity constraints due to a combination of self-interactions and the couplings to matter. Originally, these theories were proposed with a constant coupling to matter; however, the chameleon mechanism also extends to the case where the coupling becomes field dependent. We study the cosmology of chameleon models with power-law couplings and power-law potentials. It is found that these generalized chameleons, when viable, have a background expansion very close to {Lambda}CDM, but can in some special cases enhance the growth of the linear perturbationsmore » at low redshifts. For the models we consider, it is found that this region of the parameter space is ruled out by local gravity constraints. Imposing a coupling to dark matter only, the local constraints are avoided, and it is possible to have observable signatures on the linear matter perturbations.« less

Diel variation in fig volatiles across syconium development: making sense of scents.

PubMed

Borges, Renee M; Bessière, Jean-Marie; Ranganathan, Yuvaraj

2013-05-01

Plants produce volatile organic compounds (VOCs) in a variety of contexts that include response to abiotic and biotic stresses, attraction of pollinators and parasitoids, and repulsion of herbivores. Some of these VOCs may also exhibit diel variation in emission. In Ficus racemosa, we examined variation in VOCs released by fig syconia throughout syconium development and between day and night. Syconia are globular enclosed inflorescences that serve as developing nurseries for pollinating and parasitic fig wasps. Syconia are attacked by gallers early in their development, serviced by pollinators in mid phase, and are attractive to parasitoids in response to the development of gallers at later stages. VOC bouquets of the different development phases of the syconium were distinctive, as were their day and night VOC profiles. VOCs such as α-muurolene were characteristic of the pollen-receptive diurnal phase, and may serve to attract the diurnally-active pollinating wasps. Diel patterns of release of volatiles could not be correlated with their predicted volatility as determined by Henry's law constants at ambient temperatures. Therefore, factors other than Henry's law constant such as stomatal conductance or VOC synthesis must explain diel variation in VOC emission. A novel use of weighted gene co-expression network analysis (WGCNA) on the volatilome resulted in seven distinct modules of co-emitted VOCs that could be interpreted on the basis of syconium ecology. Some modules were characterized by the response of fig syconia to early galling by parasitic wasps and consisted largely of green leaf volatiles (GLVs). Other modules, that could be characterized by a combination of syconia response to oviposition and tissue feeding by larvae of herbivorous galler pollinators as well as of parasitized wasps, consisted largely of putative herbivore-induced plant volatiles (HIPVs). We demonstrated the usefulness of WGCNA analysis of the volatilome in making sense of the scents

Performance of ultraviolet photocatalytic oxidation for indoor air cleaning applications.

PubMed

Hodgson, A T; Destaillats, H; Sullivan, D P; Fisk, W J

2007-08-01

Ultraviolet photocatalytic oxidation (UVPCO) systems for removal of volatile organic compounds (VOCs) from air are being considered for use in office buildings. Here, we report an experimental evaluation of a UVPCO device with tungsten oxide modified titanium dioxide (TiO2) as the photocatalyst. The device was challenged with complex VOC mixtures. One mixture contained 27 VOCs characteristic of office buildings and another comprised 10 VOCs emitted by cleaning products, in both cases at realistic concentrations (low ppb range). VOC conversion efficiencies varied widely, usually exceeded 20%, and were as high as approximately 80% at about 0.03 s residence time. Conversion efficiency generally diminished with increased airflow rate, and followed the order: alcohols and glycol ethers > aldehydes, ketones, and terpene hydrocarbons > aromatic and alkane hydrocarbons > halogenated aliphatic hydrocarbons. Conversion efficiencies correlated with the Henry's law constant more closely than with other physicochemical parameters. An empirical model based on the Henry's law constant and the gas-phase reaction rate with hydroxyl radical provided reasonable estimates of pseudo-first order photocatalytic reaction rates. Formaldehyde, acetaldehyde, acetone, formic acid and acetic acid were produced by the device due to incomplete mineralization of common VOCs. Formaldehyde outlet/inlet concentration ratios were in the range 1.9-7.2. Implementation of air cleaning technologies for both VOCs and particles in office buildings may improve indoor air quality, or enable indoor air quality levels to be maintained with reduced outdoor air supply and concomitant energy savings. One promising air cleaning technology is ultraviolet photocatalytic oxidation (UVPCO) air cleaning. For the prototype device evaluated here with realistic mixtures of VOCs, conversion efficiencies typically exceeded the minimum required to counteract predicted VOC concentration increases from a 50% reduction in

Accurate physical laws can permit new standard units: The two laws F→=ma→ and the proportionality of weight to mass

NASA Astrophysics Data System (ADS)

Saslow, Wayne M.

2014-04-01

Three common approaches to F→=ma→ are: (1) as an exactly true definition of force F→ in terms of measured inertial mass m and measured acceleration a→; (2) as an exactly true axiom relating measured values of a→, F→ and m; and (3) as an imperfect but accurately true physical law relating measured a→ to measured F→, with m an experimentally determined, matter-dependent constant, in the spirit of the resistance R in Ohm's law. In the third case, the natural units are those of a→ and F→, where a→ is normally specified using distance and time as standard units, and F→ from a spring scale as a standard unit; thus mass units are derived from force, distance, and time units such as newtons, meters, and seconds. The present work develops the third approach when one includes a second physical law (again, imperfect but accurate)—that balance-scale weight W is proportional to m—and the fact that balance-scale measurements of relative weight are more accurate than those of absolute force. When distance and time also are more accurately measurable than absolute force, this second physical law permits a shift to standards of mass, distance, and time units, such as kilograms, meters, and seconds, with the unit of force—the newton—a derived unit. However, were force and distance more accurately measurable than time (e.g., time measured with an hourglass), this second physical law would permit a shift to standards of force, mass, and distance units such as newtons, kilograms, and meters, with the unit of time—the second—a derived unit. Therefore, the choice of the most accurate standard units depends both on what is most accurately measurable and on the accuracy of physical law.

Accurate Calibration and Uncertainty Estimation of the Normal Spring Constant of Various AFM Cantilevers

PubMed Central

Song, Yunpeng; Wu, Sen; Xu, Linyan; Fu, Xing

2015-01-01

Measurement of force on a micro- or nano-Newton scale is important when exploring the mechanical properties of materials in the biophysics and nanomechanical fields. The atomic force microscope (AFM) is widely used in microforce measurement. The cantilever probe works as an AFM force sensor, and the spring constant of the cantilever is of great significance to the accuracy of the measurement results. This paper presents a normal spring constant calibration method with the combined use of an electromagnetic balance and a homemade AFM head. When the cantilever presses the balance, its deflection is detected through an optical lever integrated in the AFM head. Meanwhile, the corresponding bending force is recorded by the balance. Then the spring constant can be simply calculated using Hooke’s law. During the calibration, a feedback loop is applied to control the deflection of the cantilever. Errors that may affect the stability of the cantilever could be compensated rapidly. Five types of commercial cantilevers with different shapes, stiffness, and operating modes were chosen to evaluate the performance of our system. Based on the uncertainty analysis, the expanded relative standard uncertainties of the normal spring constant of most measured cantilevers are believed to be better than 2%. PMID:25763650

Accurate calibration and uncertainty estimation of the normal spring constant of various AFM cantilevers.

PubMed

Song, Yunpeng; Wu, Sen; Xu, Linyan; Fu, Xing

2015-03-10

Measurement of force on a micro- or nano-Newton scale is important when exploring the mechanical properties of materials in the biophysics and nanomechanical fields. The atomic force microscope (AFM) is widely used in microforce measurement. The cantilever probe works as an AFM force sensor, and the spring constant of the cantilever is of great significance to the accuracy of the measurement results. This paper presents a normal spring constant calibration method with the combined use of an electromagnetic balance and a homemade AFM head. When the cantilever presses the balance, its deflection is detected through an optical lever integrated in the AFM head. Meanwhile, the corresponding bending force is recorded by the balance. Then the spring constant can be simply calculated using Hooke's law. During the calibration, a feedback loop is applied to control the deflection of the cantilever. Errors that may affect the stability of the cantilever could be compensated rapidly. Five types of commercial cantilevers with different shapes, stiffness, and operating modes were chosen to evaluate the performance of our system. Based on the uncertainty analysis, the expanded relative standard uncertainties of the normal spring constant of most measured cantilevers are believed to be better than 2%.

Lambert-Beer law in ocean waters: optical properties of water and of dissolved/suspended material, optical energy budgets.

PubMed

Stavn, R H

1988-01-15

The role of the Lambert-Beer law in ocean optics is critically examined. The Lambert-Beer law and the three-parameter model of the submarine light field are used to construct an optical energy budget for any hydrosol. It is further applied to the analytical exponential decay coefficient of the light field and used to estimate the optical properties and effects of the dissolved/suspended component in upper ocean layers. The concepts of the empirical exponential decay coefficient (diffuse attenuation coefficient) of the light field and a constant exponential decay coefficient for molecular water are analyzed quantitatively. A constant exponential decay coefficient for water is rejected. The analytical exponential decay coefficient is used to analyze optical gradients in ocean waters.

Bianchi Type-I Anisotropic Dark Energy Model with Constant Deceleration Parameter

NASA Astrophysics Data System (ADS)

Pradhan, Anirudh; Amirhashchi, H.; Saha, Bijan

2011-09-01

A new dark energy model in anisotropic Bianchi type-I (B-I) space-time with time dependent equation of state (EoS) parameter and constant deceleration parameter has been investigated in the present paper. The Einstein's field equations have been solved by applying a variation law for generalized Hubble's parameter (Berman in Il Nuovo Cimento B 74:182, 1983) which generates two types of solutions, one is of power-law type and other is of the exponential form. The existing range of the dark energy EoS parameter ω for derived model is found to be in good agreement with the three recent observations (i) SNe Ia data (Knop et al. in Astrophys. J. 598:102, 2003), (ii) SNe Ia data collaborated with CMBR anisotropy and galaxy clustering statistics (Tegmark et al. in Astrophys. J. 606:702, 2004) and (iii) a combination of cosmological datasets coming from CMB anisotropies, luminosity distances of high redshift type Ia supernovae and galaxy clustering (Hinshaw et al. in Astrophys. J. Suppl. Ser. 180:225, 2009 and Komatsu et al. in Astrophys. J. Suppl. Ser. 180:330, 2009). The cosmological constant Λ is found to be a decreasing function of time and it approaches a small positive value at the present epoch which is corroborated by results from recent supernovae Ia observations. It has also been suggested that the dark energy that explains the observed accelerating universe may arise due to the contribution to the vacuum energy of the EoS in a time dependent background. Geometric and kinematic properties of the model and the behaviour of the anisotropy of the dark energy have been carried out.

The Works of Henry Moseley, 1887-1915

NASA Astrophysics Data System (ADS)

Scerri, Eric

2013-04-01

In 1913 Henry Moseley, an unknown young English physicist published an article in the Philosophical Magazine under the title of ``The High Frequency Spectra of the Elements.'' The 10-page article was to have far reaching implications in both chemistry and physics and helped to resolve a major conundrum in the periodic table of the elements. The talk will briefly examine the life and work of Moseley who died tragically while fighting in the trenches of World War I in 1915. The build-up to the discovery of atomic number took several different avenues including contributions from Rutherford and Barkla. However the more direct motivation for Moseley's work, as he readily acknowledged, were the articles of an unknown Dutch econometrician Anton Van den Broek who attempted to improve on Mendeleev's periodic table. Moseley began as a student of Rutherford at Manchester and took a keen interest in the development of research using X-rays following the work of Roentgen, von Laue and Bragg. Although Rutherford was at first reluctant to enter this new field he soon yielded to young Moseley's request and sent him to Leeds for brief training with Bragg. On returning to Manchester, Moseley devised an ingenious apparatus in which a set of metal samples could be rotated so as to become the target for a beam of electrons in order to measure the frequencies of the emitted K X-rays. The first set of such experiments used nine successive elements in the periodic table, from titanium to zinc. Moseley's now immense fame rests with the results of this study as well as a subsequent one which extended the study into a further 30 elements, in addition to the use that his method was put to by himself as well as subsequent chemists and physicists.

The Implications of Cognitive-Developmental Theory for Law Related Curriculum in the Elementary School.

ERIC Educational Resources Information Center

Cole, Peggy

Law-related education programs for elementary school should be based on children's perceptions of reality. Psychologist Jean Piaget's studies of cognitive development indicate that children constantly reconstruct reality as they undergo new experiences. Children at early developmental stages may not be capable of understanding the origin and…

Quantum adiabatic computation with a constant gap is not useful in one dimension.

PubMed

Hastings, M B

2009-07-31

We show that it is possible to use a classical computer to efficiently simulate the adiabatic evolution of a quantum system in one dimension with a constant spectral gap, starting the adiabatic evolution from a known initial product state. The proof relies on a recently proven area law for such systems, implying the existence of a good matrix product representation of the ground state, combined with an appropriate algorithm to update the matrix product state as the Hamiltonian is changed. This implies that adiabatic evolution with such Hamiltonians is not useful for universal quantum computation. Therefore, adiabatic algorithms which are useful for universal quantum computation either require a spectral gap tending to zero or need to be implemented in more than one dimension (we leave open the question of the computational power of adiabatic simulation with a constant gap in more than one dimension).

UNIVERSALITY OF THE NEAR-INFRARED EXTINCTION LAW BASED ON THE APOGEE SURVEY

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wang, Shu; Jiang, B. W., E-mail: shuwang@mail.bnu.edu.cn, E-mail: bjiang@bnu.edu.cn

Whether the near-infrared (NIR) extinction law is universal has long been a debated topic. Based on the APOGEE H-band spectroscopic survey, a key project of SDSS-III, the intrinsic colors of a large number of giant stars are accurately determined from the stellar effective temperature. Taking advantage of this and using a sample of 5942 K-type giants, the NIR extinction law is carefully revisited. The color excess ratio E(J – H)/E(J – K {sub S}), representative of the NIR extinction law, shows no dependence on the color excess when E(J – K {sub S}) changes from ∼0.3 to ∼4.0, which implies amore » universal NIR extinction law from diffuse to dense regions. The constant value of E(J – H)/E(J – K {sub S}), 0.64, corresponds to a power law index of 1.95. The other two ratios, E(H – K {sub S})/E(J – K {sub S}) and E(J – H)/E(H – K {sub S}), are 0.36 and 1.78, respectively. The results are consistent with the MRN dust size distribution.« less

Exploiting the hidden symmetry of spinning black holes: conservation laws and numerical tests

NASA Astrophysics Data System (ADS)

Witzany, Vojtěch

2018-01-01

The Kerr black hole is stationary and axisymmetric, which leads to conservation of energy and azimuthal angular momentum along the orbits of free test particles in its vicinity, but also to conservation laws for the evolution of continuum matter fields. However, the Kerr space-time possesses an additional 'hidden symmetry', which exhibits itself in an unexpected conserved quantity along geodesics known as the Carter constant. We investigate the possibility of using this hidden symmetry to obtain conservation laws and other identities that could be used to test astrophysical simulations of the evolution of matter fields near spinning black holes. After deriving such identities, we set up a simple numerical toy model on which we demonstrate how they can detect the violations of evolution equations in a numerical simulation. Even though one of the expressions we derive is in the form of a conservation law, we end up recommending an equivalent but simpler expression that is not in the form of a conservation law for practical implementation.

Administrative Law: The Hidden Comparative Law Course.

ERIC Educational Resources Information Center

Strauss, Peter L.

1996-01-01

Argues that the main contribution of the Administrative Law course to law students is that it presents problems which contrast with those of the standard court-centered curriculum and can illuminate other areas of law, repeatedly confronting students with doctrinal differences. Offers several examples from civil procedure, constitutional law, and…

Physicochemical properties of an insensitive munitions compound, N-methyl-4-nitroaniline (MNA).

PubMed

Boddu, Veera M; Abburi, Krishnaiah; Maloney, Stephen W; Damavarapu, Reddy

2008-06-30

Accurate information on physicochemical properties of an organic contaminant is essential for predicting its environmental impact and fate. These properties also provide invaluable information for the overall understanding of environmental distribution, biotransformation, and potential treatment processes. In this study the aqueous solubility (Sw), octanol-water partition coefficient (Kow), and Henry's law constant (K(H)) were determined for an insensitive munitions (IM) compound, N-methyl-4-nitroaniline (MNA), at 298.15, 308.15, and 318.15 K. Effect of ionic strength on solubility, using electrolytes such as NaCl and CaCl2, was also studied. The data on the physicochemical parameters were correlated using the standard Van't Hoff equation. All three properties exhibited a linear relationship with reciprocal temperature. The enthalpy and entropy of phase transfer were derived from the experimental data.

Outbreak statistics and scaling laws for externally driven epidemics.

PubMed

Singh, Sarabjeet; Myers, Christopher R

2014-04-01

Power-law scalings are ubiquitous to physical phenomena undergoing a continuous phase transition. The classic susceptible-infectious-recovered (SIR) model of epidemics is one such example where the scaling behavior near a critical point has been studied extensively. In this system the distribution of outbreak sizes scales as P(n)∼n-3/2 at the critical point as the system size N becomes infinite. The finite-size scaling laws for the outbreak size and duration are also well understood and characterized. In this work, we report scaling laws for a model with SIR structure coupled with a constant force of infection per susceptible, akin to a "reservoir forcing". We find that the statistics of outbreaks in this system fundamentally differ from those in a simple SIR model. Instead of fixed exponents, all scaling laws exhibit tunable exponents parameterized by the dimensionless rate of external forcing. As the external driving rate approaches a critical value, the scale of the average outbreak size converges to that of the maximal size, and above the critical point, the scaling laws bifurcate into two regimes. Whereas a simple SIR process can only exhibit outbreaks of size O(N1/3) and O(N) depending on whether the system is at or above the epidemic threshold, a driven SIR process can exhibit a richer spectrum of outbreak sizes that scale as O(Nξ), where ξ∈(0,1]∖{2/3} and O((N/lnN)2/3) at the multicritical point.

An Historical Note on the Conservation of Mass

ERIC Educational Resources Information Center

Whitaker, Robert D.

1975-01-01

Discusses the fact that although most historians of science attribute the formulation of the law of conservation of matter in chemical reactions to Antoine Lavoisier at the end of the eighteenth century, several earlier researchers had already assumed this law in their work. These researchers include Joseph Black, Henry Cavendish, M. V. Lomonosov,…

A novel guidance law using fast terminal sliding mode control with impact angle constraints.

PubMed

Sun, Lianghua; Wang, Weihong; Yi, Ran; Xiong, Shaofeng

2016-09-01

This paper is concerned with the question of, for a missile interception with impact angle constraints, how to design a guidance law. Firstly, missile interception with impact angle constraints is modeled; secondly, a novel guidance law using fast terminal sliding mode control based on extended state observer is proposed to optimize the trajectory and time of interception; finally, for stationary targets, constant velocity targets and maneuvering targets, the guidance law and the stability of the closed loop system is analyzed and the stability of the closed loop system is analyzed, respectively. Simulation results show that when missile and target are on a collision course, the novel guidance law using fast terminal sliding mode control with extended state observer has more optimized trajectory and effectively reduces the time of interception which has a great significance in modern warfare. Copyright © 2016 ISA. Published by Elsevier Ltd. All rights reserved.

Henry Ingersoll Bowditch and Oliver Wendell Holmes: stethoscopists and reformers.

PubMed

Felts, John H

2002-01-01

Two Bostonians, Henry Ingersoll Bowditch (1808-1892) and Oliver Wendell Holmes (1809-1894), went to Paris for advanced medical training and came home ardent disciples of Pierre Charles Alexandre Louis, leader of the French school that derived its eminence from expert auscultation and careful correlation of bedside and autopsy findings. Both Bowditch and Holmes became leaders in 19th-century American medicine. Bowditch, a successful practitioner and prolific medical writer, wrote the first important American text on physical examination and became our first specialist in pulmonary disease. He pioneered in the public health movement, was a charter member and later president of the American Medical Association, and was an abolitionist and an advocate for equal rights for women in medicine. Holmes left practice to become a medical educator. As Dean of Harvard Medical School, he tried unsuccessfully to admit white women and free black men to the school. Although his greatest fame came as a man of letters, Holmes considered himself first a physician and medical educator, and was justifiably proud of his definitive study, "The Contagiousness of Puerperal Fever" (1843). Today, Bowditch and Holmes are little appreciated as pioneers and reformers, but we remain in debt to them both.

ExtLaw_H18: Extinction law code

NASA Astrophysics Data System (ADS)

Hosek, Matthew W., Jr.; Lu, Jessica R.; Anderson, Jay; Do, Tuan; Schlafly, Edward F.; Ghez, Andrea M.; Clarkson, William I.; Morris, Mark R.; Albers, Saundra M.

2018-03-01

ExtLaw_H18 generates the extinction law between 0.8 - 2.2 microns. The law is derived using the Westerlund 1 (Wd1) main sequence (A_Ks 0.6 mag) and Arches cluster field Red Clump at the Galactic Center (A_Ks 2.7 mag). To derive the law a Wd1 cluster age of 5 Myr is assumed, though changing the cluster age between 4 Myr - 7 Myr has no effect on the law. This extinction law can be applied to highly reddened stellar populations that have similar foreground material as Wd1 and the Arches RC, namely dust from the spiral arms of the Milky Way in the Galactic Plane.

Solubility of nitrous oxide in aqueous blends of N-methyldiethanolamine and 2-amino-2-methyl-1-propanol

DOE Office of Scientific and Technical Information (OSTI.GOV)

Davis, R.A.; Pogainis, B.J.

1995-11-01

Aqueous solutions of alkanolamines have applications in acid gas treatment for the removal of acid gases such as carbon dioxide and hydrogen sulfide. The solubility of nitrous oxide in aqueous blends of N-methyldiethanolamine and 2-amino-2-methyl-1 propanol was measured over the temperature range 10--60 C. The total composition of the alkanolamines in water ranged from 30 to 50 mass %. The experimental results were interpreted in terms of Henry`s constants.

Henry Sigerist and the history of medicine in Latin America: his correspondence with Juan R. Beltran.

PubMed

de Asúa, Miguel

2005-01-01

During the years of World War II, the American Association for the History of Medicine fostered a Pan-American policy aimed at establishing relationships with Latin American historians of medicine. Juan R. Beltrán, professor of history of medicine at the University of Buenos Aires, also pursued an energetic program of academic diplomacy. The correspondence between Henry Sigerist and Beltrán makes manifest that by 1941 good channels of communication were established between Baltimore and Buenos Aires, but the friendly links did not last long. The motives for this can be found in the competing aims of the AAHM and Beltrán, and the pattern of international relationships during the war years.

Henry Currey FRIBA (1820-1900): leading Victorian hospital architect, and early exponent of the "pavilion principle".

PubMed

Cook, G C

2002-06-01

The "pavilion plan" for hospital design originated in France in the 18th century and was popularised in England by John Roberton and George Godwin in the mid-19th century; the underlying rationale was that with improved ventilation the mortality rate (at that time exceedingly high) was significantly reduced. Among the enthusiasts for this new style was Florence Nightingale (herself a miasmatist)--who had experienced astronomically high death rates in the hospital at Scutari during the Crimean War (1854-6). One of the leading exponents of this style of hospital architecture was Henry Currey (1820-1900) whose greatest achievement was undoubtedly the design for the new St Thomas's Hospital on the Lambeth Palace Road.

The LSU Law Center -- Canada Bijuralism Conference. Introduction: Global Law and the Law School Curriculum.

ERIC Educational Resources Information Center

Costonis, John J.

2002-01-01

Introduces papers from a conference focused on the bijural programs of Louisiana State University Law Center and McGill University Faculty of Law. The programs educate all first-degree law students in both the common law and civil law traditions, preparing them for the increasing globalization of legal practice. (EV)

Comparisons of Hamaker constants for ceramic systems with intervening vacuum or water: From force laws and physical properties

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ackler, H.D.; Chiang, Y.M.; French, R.H.

1996-05-10

Van der Waals dispersive forces produce attractive interactions between bodies, playing an important role in many material systems influencing colloidal and emulsion stability, wetting behavior, and intergranular forces in glass-ceramic systems. It is of technological importance to accurately quantify these interactions, conveniently represented by the Hamaker constant, A. To set the current level of accuracy for determining A, they were calculated from Lifshitz theory using full spectral data for muscovite mica, Al{sub 2}O{sub 3}, SiO{sub 2}, Si{sub 3}N{sub 4}, and rutile TiO{sub 2}, separated by vacuum or water. These were compared to Hamaker constants calculated from physical properties using themore » Tabor-Winterton approximation, a single oscillator model, a multiple oscillator model, and A`s calculated using force vs separation data from surface force apparatus and atomic force microscope studies. For materials with refractive indices between 1.4 and 1.8 separated by vacuum, all methods produce similar values, but for indices larger than 1.8 separated by vacuum, and any of these materials separated by water, results span a broader range. The present level of accuracy for the determination of Hamaker constants, here taken to be represented by the level of agreement between various methods, ranges from about 10% for the case of SiO{sub 2}/vacuum/SiO{sub 2} and TiO{sub 2}/water/TiO{sub 2} to a factor of approximately 7 for mica/water/mica.« less

The critical impact of Frantz Fanon and Henri Collomb: race, gender, and personality testing of North and West Africans.

PubMed

Bullard, Alice

2005-01-01

In 2001, the U.S. Surgeon General declared publicly that culture counts in mental health care. This welcome recognition of the role of culture in mental health appears somewhat belated. In 1956, Frantz Fanon and Henri Collomb both presented culturally sensitive studies of the Thematic Apperception Test at the major French-language mental health conference. The contrast between these two studies and between the careers of Fanon and Collomb reveals some of the difficulties in creating cultural and gender sensitivity in psychiatry or psychology. Copyright 2005 Wiley Periodicals, Inc.

Dr Walter Henry Anderson (1870-1937) and the mission hospital at Safed, Palestine.

PubMed

Stokes, Gordon S

2013-02-01

Walter Henry Anderson, a brewer's clerk in Burton-upon-Trent, became a missionary doctor, supported by a society promoting welfare and evangelism in Jewish communities abroad. His family background was rich in pastoral ministry at home and adventure abroad. Arguably, this background played a part in his decision to serve the Jews of Safed. His life in Palestine entailed much enterprise and hardship as he raised a family, fought disease and set up a mission hospital serving not only the Jewish community but persons of all faiths. His years in Palestine, from 1894 to 1915, were times of peace in the Middle East before the turmoil unleashed by the Great War. Jews from the Diaspora were gaining an increasing foothold in Palestine, their 'Promised Land'. Themes of that era - the rise of Zionism, confrontation between Judaism and evangelical Christianity, conflict between immigrant Jew and Palestinian Arab and the remarkable travels of Lawrence of Arabia were interwoven with the lives of Dr Anderson and his family.

Two-relaxation-time lattice Boltzmann method for the anisotropic dispersive Henry problem

NASA Astrophysics Data System (ADS)

Servan-Camas, Borja; Tsai, Frank T.-C.

2010-02-01

This study develops a lattice Boltzmann method (LBM) with a two-relaxation-time collision operator (TRT) to cope with anisotropic heterogeneous hydraulic conductivity and anisotropic velocity-dependent hydrodynamic dispersion in the saltwater intrusion problem. The directional-speed-of-sound technique is further developed to address anisotropic hydraulic conductivity and dispersion tensors. Forcing terms are introduced in the LBM to correct numerical errors that arise during the recovery procedure and to describe the sink/source terms in the flow and transport equations. In order to facilitate the LBM implementation, the forcing terms are combined with the equilibrium distribution functions (EDFs) to create pseudo-EDFs. This study performs linear stability analysis and derives LBM stability domains to solve the anisotropic advection-dispersion equation. The stability domains are used to select the time step at which the lattice Boltzmann method provides stable solutions to the numerical examples. The LBM was implemented for the anisotropic dispersive Henry problem with high ratios of longitudinal to transverse dispersivities, and the results compared well to the solutions in the work of Abarca et al. (2007).

Power law versus exponential state transition dynamics: application to sleep-wake architecture.

PubMed

Chu-Shore, Jesse; Westover, M Brandon; Bianchi, Matt T

2010-12-02

Despite the common experience that interrupted sleep has a negative impact on waking function, the features of human sleep-wake architecture that best distinguish sleep continuity versus fragmentation remain elusive. In this regard, there is growing interest in characterizing sleep architecture using models of the temporal dynamics of sleep-wake stage transitions. In humans and other mammals, the state transitions defining sleep and wake bout durations have been described with exponential and power law models, respectively. However, sleep-wake stage distributions are often complex, and distinguishing between exponential and power law processes is not always straightforward. Although mono-exponential distributions are distinct from power law distributions, multi-exponential distributions may in fact resemble power laws by appearing linear on a log-log plot. To characterize the parameters that may allow these distributions to mimic one another, we systematically fitted multi-exponential-generated distributions with a power law model, and power law-generated distributions with multi-exponential models. We used the Kolmogorov-Smirnov method to investigate goodness of fit for the "incorrect" model over a range of parameters. The "zone of mimicry" of parameters that increased the risk of mistakenly accepting power law fitting resembled empiric time constants obtained in human sleep and wake bout distributions. Recognizing this uncertainty in model distinction impacts interpretation of transition dynamics (self-organizing versus probabilistic), and the generation of predictive models for clinical classification of normal and pathological sleep architecture.

Electromagnetic fluctuations for anisotropic media and the generalized Kirchhoff's law

NASA Technical Reports Server (NTRS)

Yueh, Simon H.; Kwok, R.

1993-01-01

In this paper the polarimetric emission parameters for anisotropic media are derived using the generalized Kirchhoff's law for media with a uniform temperature and the fluctuation-dissipation theory for media with a temperature profile. Both finite-size objects and half-space media are considered. When the object has a uniform temperature across its body, the Kirchhoff's law, based on the condition of energy conservation in thermal equilibrium is generalized to obtain the emission parameters of an anisotropic medium, which can be interpreted as the absorptivity or the absorption cross section of the complementary object with a permittivity that is the transpose of the original object. When the medium has a nonuniform temperature distribution, the fluctuation-dissipation theory is applied for deriving the covariances between vector components of the thermal currents and, consequently, the covariances of the polarizations of electric fields radiated by the thermal currents. To verify the formulas derived from the fluctuation-dissipation theory, we let the temperature of the object be a constant and show that the results reduce to those obtained from the generalized Kirchhoff's law.

[Charles-Henri Fialon (1846-1933), creator of the Museum of the Faculty of Pharmacy of Paris. His family and professional life].

PubMed

Flahaut, Jean

2004-01-01

Henri Fialon was pharmacist in 1871, and worked in the family apothecary, at Rueil near Paris. At 46 years, he stopped his pharmaceutical activity, and livre quietly, being specially interested by the ancient pharmaceutical pots. He realized a very important collection, which he gave to the French Society of Pharmaceutical History. A museum was installed at the Faculty of Pharmacy of Paris which is presently in the Guillaume Valette Gallery and contains more than 500 pieces.

New constraints on time-dependent variations of fundamental constants using Planck data

NASA Astrophysics Data System (ADS)

Hart, Luke; Chluba, Jens

2018-02-01

Observations of the cosmic microwave background (CMB) today allow us to answer detailed questions about the properties of our Universe, targeting both standard and non-standard physics. In this paper, we study the effects of varying fundamental constants (i.e. the fine-structure constant, αEM, and electron rest mass, me) around last scattering using the recombination codes COSMOREC and RECFAST++. We approach the problem in a pedagogical manner, illustrating the importance of various effects on the free electron fraction, Thomson visibility function and CMB power spectra, highlighting various degeneracies. We demonstrate that the simpler RECFAST++ treatment (based on a three-level atom approach) can be used to accurately represent the full computation of COSMOREC. We also include explicit time-dependent variations using a phenomenological power-law description. We reproduce previous Planck 2013 results in our analysis. Assuming constant variations relative to the standard values, we find the improved constraints αEM/αEM, 0 = 0.9993 ± 0.0025 (CMB only) and me/me, 0 = 1.0039 ± 0.0074 (including BAO) using Planck 2015 data. For a redshift-dependent variation, αEM(z) = αEM(z0) [(1 + z)/1100]p with αEM(z0) ≡ αEM, 0 at z0 = 1100, we obtain p = 0.0008 ± 0.0025. Allowing simultaneous variations of αEM(z0) and p yields αEM(z0)/αEM, 0 = 0.9998 ± 0.0036 and p = 0.0006 ± 0.0036. We also discuss combined limits on αEM and me. Our analysis shows that existing data are not only sensitive to the value of the fundamental constants around recombination but also its first time derivative. This suggests that a wider class of varying fundamental constant models can be probed using the CMB.

Tachyon with an inverse power-law potential in a braneworld cosmology

NASA Astrophysics Data System (ADS)

Bilić, Neven; Domazet, Silvije; Djordjevic, Goran S.

2017-08-01

We study a tachyon cosmological model based on the dynamics of a 3-brane in the bulk of the second Randall-Sundrum model extended to more general warp functions. A well known prototype of such a generalization is the bulk with a selfinteracting scalar field. As a consequence of a generalized bulk geometry the cosmology on the observer brane is modified by the scale dependent four-dimensional gravitational constant. In particular, we study a power law warp factor which generates an inverse power-law potential V\\propto \\varphi-n of the tachyon field φ. We find a critical power n cr that divides two subclasses with distinct asymptotic behaviors: a dust universe for n>n_cr and a quasi de Sitter universe for 0.

[Law and the phase of life old age].

PubMed

Klie, Thomas

2017-06-01

In spite of the greatly increased role, which the law attributes to the design of individual life styles and living of elderly people, there is no special legal area known in the German legal system, such as "rights of the elderly", which is the case in the field of the youth law. Special legal regulations covering the concerns/issues of elderly people were always considered to be in danger, as they may have the potential to discrimination, either in a positive or negative way. Due to this fact, the rights of the elderly can be described as synthetic and are subject to constant changes, as can be observed within the pension act. The legal areas and legal regulations, which are of particular importance for the life style and living situations of elderly people are presented. The legal need for action regarding the special protection of vulnerable elderly people is discussed and in the further course utilized for a conception of "rights of the elderly".

Nucleophilic substitution rates and solubilities for methyl halides in seawater

NASA Astrophysics Data System (ADS)

Elliott, Scott; Rowland, F. Sherwood

1993-06-01

Ozone depletion potentials indicate that methyl bromide is among halogen containing gases which may be scheduled for international level regulation. The oceanic component of its global budget is currently unquantifiable because of a lack of surface seawater measurements. Given values for internal removal and for solubility, marine mixed layer modelling can set bounds for air-sea transfer. Rate constants have been measured in seawater, 0.5m NaCl and distilled water for attack on methyl bromide by the chief oceanic nucleophiles chloride ion and H2O, over much of the oceanographic temperature range (0°C to 22°C). Henry's Law constants have been determined for the same conditions. All results are consistent with classical aqueous phase research adjusted for ionic strength effects. The lifetime of methyl bromide with respect to chemical decay in seawater is three weeks at average surface temperatures, and a factor of ten larger and smaller at the extremes. Its dimensionless solubility ranges from 0.1 to 0.3. Analogous experiments are reported for the other natural methyl halides, CH3Cl and CH3I.

Effect of natural gas exsolution on specific storage in a confined aquifer undergoing water level decline.

PubMed

Yager, R M; Fountain, J C

2001-01-01

The specific storage of a porous medium, a function of the compressibility of the aquifer material and the fluid within it, is essentially constant under normal hydrologic conditions. Gases dissolved in ground water can increase the effective specific storage of a confined aquifer, however, during water level declines. This causes a reduction in pore pressure that lowers the gas solubility and results in exsolution. The exsolved gas then displaces water from storage, and the specific storage increases because gas compressibility is typically much greater than that of water or aquifer material. This work describes the effective specific storage of a confined aquifer exsolving dissolved gas as a function of hydraulic head and the dimensionless Henry's law constant for the gas. This relation is applied in a transient simulation of ground water discharge from a confined aquifer system to a collapsed salt mine in the Genesee Valley in western New York. Results indicate that exsolution of gas significantly increased the effective specific storage in the aquifer system, thereby decreasing the water level drawdown.

Effect of natural gas exsolution on specific storage in a confined aquifer undergoing water level decline

USGS Publications Warehouse

Yager, R.M.; Fountain, J.C.

2001-01-01

The specific storage of a porous medium, a function of the compressibility of the aquifer material and the fluid within it, is essentially constant under normal hydrologic conditions. Gases dissolved in ground water can increase the effective specific storage of a confined aquifer, however, during water level declines. This causes a reduction in pore pressure that lowers the gas solubility and results in exsolution. The exsolved gas then displaces water from storage, and the specific storage increases because gas compressibility is typically much greater than that of water or aquifer material. This work describes the effective specific storage of a confined aquifer exsolving dissolved gas as a function of hydraulic head and the dimensionless Henry's law constant for the gas. This relation is applied in a transient simulation of ground water discharge from a confined aquifer system to a collapsed salt mine in the Genesee Valley in western New York. Results indicate that exsolution of gas significantly increased the effective specific storage in the aquifer system, thereby decreasing the water level drawdown.

Sonochemical degradation of PAH in aqueous solution. Part I: monocomponent PAH solution.

PubMed

David, Bernard

2009-02-01

The sonolysis of selected monocomponent PAH aqueous solution is studied at 20 and 506 kHz in the microg l(-1) range. The highest activity observed at 506 kHz, compared to 20 kHz, is tentatively explained by examination of the physical characteristics of bubbles (size and life-time) as well as by the calculation of the number of bubble at both frequency (5 x 10(3)bubbles l(-1) at 20 kHz and 4.5 x 10(9)bubbles l(-1) at 506 kHz). It is demonstrated that the main mechanism of sonodegradation is the pyrolysis of PAHs in the heart of the cavitation bubbles, and that a possible PAH oxidation by means of HO degrees appears as a minor way, since gaseous byproducts such as CO, CO2, C2H2 and CH4 have been detected. Correlations have been found by examination of kinetic variations in terms of the physical-chemical properties of PAHs. The rate constants of PAH degradation increase when the water solubility, the vapour pressure and the Henry's law constant increase.

Constants of the motion, universal time and the Hamilton-Jacobi function in general relativity

NASA Astrophysics Data System (ADS)

O'Hara, Paul

2013-04-01

In most text books of mechanics, Newton's laws or Hamilton's equations of motion are first written down and then solved based on initial conditions to determine the constants of the motions and to describe the trajectories of the particles. In this essay, we take a different starting point. We begin with the metrics of general relativity and show how they can be used to construct by inspection constants of motion, which can then be used to write down the equations of the trajectories. This will be achieved by deriving a Hamiltonian-Jacobi function from the metric and showing that its existence requires all of the above mentioned properties. The article concludes by showing that a consistent theory of such functions also requires the need for a universal measure of time which can be identified with the "worldtime" parameter, first introduced by Steuckelberg and later developed by Horwitz and Piron.

Numerical simulation of conservation laws

NASA Technical Reports Server (NTRS)

Chang, Sin-Chung; To, Wai-Ming

1992-01-01

A new numerical framework for solving conservation laws is being developed. This new approach differs substantially from the well established methods, i.e., finite difference, finite volume, finite element and spectral methods, in both concept and methodology. The key features of the current scheme include: (1) direct discretization of the integral forms of conservation laws, (2) treating space and time on the same footing, (3) flux conservation in space and time, and (4) unified treatment of the convection and diffusion fluxes. The model equation considered in the initial study is the standard one dimensional unsteady constant-coefficient convection-diffusion equation. In a stability study, it is shown that the principal and spurious amplification factors of the current scheme, respectively, are structurally similar to those of the leapfrog/DuFort-Frankel scheme. As a result, the current scheme has no numerical diffusion in the special case of pure convection and is unconditionally stable in the special case of pure diffusion. Assuming smooth initial data, it will be shown theoretically and numerically that, by using an easily determined optimal time step, the accuracy of the current scheme may reach a level which is several orders of magnitude higher than that of the MacCormack scheme, with virtually identical operation count.

Bianchi type-I domain walls with negative constant deceleration parameter in Brans-Dicke theory

NASA Astrophysics Data System (ADS)

Katore, S. D.

2011-04-01

Bianchi type-I space-time is considered in the presence of a domain walls source in the scalar-tensor theory of gravitation proposed by Brans and Dicke (C.H. Brans and R.H. Dicke, Phys. Rev. 24, 925 (1961)). With the help of the special law of variation for Hubble's parameter proposed by Bermann (M.S. Berman, Nuovo Cimento B 74, 182 (1983)) a cosmological model with negative constant deceleration parameter is obtained in the presence of domain walls. Some physical properties of the model are also discussed.

A Cultural Resources Survey of Proposed Excess Tracts within the Harry S. Truman Reservoir Project Henry, St. Clair, and Bates Counties, Missouri

DTIC Science & Technology

1988-03-01

Survey of Proposed Exccess Tracts within the Harry S. Truman Reservoir Projec :. PERFORMING ORG. REPORT NUMSER Henry. St. Clair- and Bates Counties...region surrounding the Harry S. Truman Reservoir have been set out in several prior reports (LeeDecker et al. 1983:34-53; Killer 1983; Roper 1983a:15...construction of the Harry S. Truman Reservoir recorded 38 prehistoric sites, only 3 of which were previously known and reported to the Archaeological

Modified Van der Waals equation and law of corresponding states

NASA Astrophysics Data System (ADS)

Zhong, Wei; Xiao, Changming; Zhu, Yongkai

2017-04-01

It is well known that the Van der Waals equation is a modification of the ideal gas law, yet it can be used to describe both gas and liquid, and some important messages can be obtained from this state equation. However, the Van der Waals equation is not a precise state equation, and it does not give a good description of the law of corresponding states. In this paper, we expand the Van der Waals equation into its Taylor's series form, and then modify the fourth order expansion by changing the constant Virial coefficients into their analogous ones. Via this way, a more precise result about the law of corresponding states has been obtained, and the law of corresponding states can then be expressed as: in terms of the reduced variables, all fluids should obey the same equation with the analogous Virial coefficients. In addition, the system of 3 He with quantum effects has also been taken into consideration with our modified Van der Waals equation, and it is found that, for a normal system without quantum effect, the modification on ideal gas law from the Van der Waals equation is more significant than the real case, however, for a system with quantum effect, this modification is less significant than the real case, thus a factor is introduced in this paper to weaken or strengthen the modification of the Van der Waals equation, respectively.

Health care law versus constitutional law.

PubMed

Hall, Mark A

2013-04-01

National Federation of Independent Business v. Sebelius, the Supreme Court's ruling on the Patient Protection and Affordable Care Act, is a landmark decision - both for constitutional law and for health care law and policy. Others will study its implications for constitutional limits on a range of federal powers beyond health care. This article considers to what extent the decision is also about health care law, properly conceived. Under one view, health care law is the subdiscipline that inquires how courts and government actors take account of the special features of medicine that make legal or policy issues especially problematic - rather than regarding health care delivery and finance more generically, like most any other economic or social enterprise. Viewed this way, the opinions from the Court's conservative justices are mainly about general constitutional law principles. In contrast, Justice Ruth Bader Ginsburg's dissenting opinion for the four more liberal justices is just as much about health care law as it is about constitutional law. Her opinion gives detailed attention to the unique features of health care finance and delivery in order to inform her analysis of constitutional precedents and principles. Thus, the Court's multiple opinions give a vivid depiction of the compelling contrasts between communal versus individualistic conceptions of caring for those in need, and between health care and health insurance as ordinary commodities versus ones that merit special economic, social, and legal status.

Predicting the Cosmological Constant from the CausalEntropic Principle

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bousso, Raphael; Harnik, Roni; Kribs, Graham D.

2007-02-20

We compute the expected value of the cosmological constant in our universe from the Causal Entropic Principle. Since observers must obey the laws of thermodynamics and causality, it asserts that physical parameters are most likely to be found in the range of values for which the total entropy production within a causally connected region is maximized. Despite the absence of more explicit anthropic criteria, the resulting probability distribution turns out to be in excellent agreement with observation. In particular, we find that dust heated by stars dominates the entropy production, demonstrating the remarkable power of this thermodynamic selection criterion. Themore » alternative approach--weighting by the number of ''observers per baryon''--is less well-defined, requires problematic assumptions about the nature of observers, and yet prefers values larger than present experimental bounds.« less

Simple control laws for low-thrust orbit transfers

NASA Technical Reports Server (NTRS)

Petropoulos, Anastassios E.

2003-01-01

Two methods are presented by which to determine both a thrust direction and when to apply thrust to effect specified changes in any of the orbit elements except for true anomaly, which is assumed free. The central body is assumed to be a point mass, and the initial and final orbits are assumed closed. Thrust, when on, is of a constant value, and specific impulse is constant. The thrust profiles derived from the two methods are not propellant-optimal, but are based firstly on the optimal thrust directions and location on the osculating orbit for changing each of the orbit elements and secondly on the desired changes in the orbit elements. Two examples of transfers are presented, one in semimajor axis and inclination, and one in semimajor axis and eccentricity. The latter compares favourably with a propellant-optimized transfer between the same orbits. The control laws have few input parameters, but can still capture the complexity of a wide variety of orbit transfers.

Gravitational domain walls and the dynamics of the gravitational constant G

NASA Astrophysics Data System (ADS)

Bunster, Claudio; Gomberoff, Andrés

2017-07-01

From the point of view of elementary particle physics, the gravitational constant G is extraordinarily small. This has led to asking whether it could have decayed to its present value from an initial one commensurate with microscopical units. A mechanism that leads to such a decay is proposed herein. It is based on assuming that G may take different values within regions of the universe separated by a novel kind of domain wall, a "G -wall." The idea is implemented by introducing a gauge potential Aμ ν ρ, and its conjugate D , which determines the value of G as an integration constant rather than a fundamental constant. The value of G jumps when one goes through a G -wall. The procedure extends one previously developed for the cosmological constant, but the generalization is far from straightforward: (i) The intrinsic geometry of a G -wall is not the same as seen from its two sides because the second law of black hole thermodynamics mandates that the jump in G must cause a discontinuity in the scale of length. (ii) The size of the decay step in G is controlled by a function G (D ) which may be chosen so as to diminish the value of G towards the asymptote G =0 . It is shown that: (i) The dynamics of the gravitational field with G treated as a dynamical variable, coupled to G -walls and matter, follows from an action principle, which is given. (ii) A particle that impinges on a G -wall may be refracted or reflected. (iii) The various forces between two particles change when a G -wall is inserted in between them. (iv) G -walls may be nucleated trough tunneling and thermal effects, whose semiclassical probabilities are evaluated. (v) If the action principle is constructed properly, the entropy of a black hole increases when the value of the gravitational constant is changed through the absorption of a G-wall by the hole.

Visual reaction time for chromaticity changes at constant luminance in different color representation systems

NASA Astrophysics Data System (ADS)

Jimenezdel Barco, L.; Jimenez, J. R.; Rubino, M.; Diaz, J. A.

1996-09-01

The results obtained by different authors show that when a color stimulus changes in both luminance and chromaticity, the visual reaction time (VRT) of an observer in detecting this chromatic change depends on nothing more than the luminance change and is regulated by Pieron's law. In the present work, we evaluate the VRT needed by an observer to detect the chromaticity difference between an adapting and variable stimulus. For this, we have used the experimental method of hue substitution, which allows us to maintain the luminance channel constant and thereby study the temporal response to changes only in chromaticity. The experiments were carried out with a CRT color monitor and the experimental results are expressed in different color-representation systems. The systems UCS-CIE 1964 (U*, V*, W*) and CIELUV show good correlations between the VRT and the chromaticity difference expressed in these systems, adjusting the VRT to an expression following Pieron's law: VRT-VRTon=k( Delta E)- beta .

Touchless attitude correction for satellite with constant magnetic moment

NASA Astrophysics Data System (ADS)

Ao, Hou-jun; Yang, Le-ping; Zhu, Yan-wei; Zhang, Yuan-wen; Huang, Huan

2017-09-01

Rescue of satellite with attitude fault is of great value. Satellite with improper injection attitude may lose contact with ground as the antenna points to the wrong direction, or encounter energy problems as solar arrays are not facing the sun. Improper uploaded command may set the attitude out of control, exemplified by Japanese Hitomi spacecraft. In engineering practice, traditional physical contact approaches have been applied, yet with a potential risk of collision and a lack of versatility since the mechanical systems are mission-specific. This paper puts forward a touchless attitude correction approach, in which three satellites are considered, one having constant dipole and two having magnetic coils to control attitude of the first. Particular correction configurations are designed and analyzed to maintain the target's orbit during the attitude correction process. A reference coordinate system is introduced to simplify the control process and avoid the singular value problem of Euler angles. Based on the spherical triangle basic relations, the accurate varying geomagnetic field is considered in the attitude dynamic mode. Sliding mode control method is utilized to design the correction law. Finally, numerical simulation is conducted to verify the theoretical derivation. It can be safely concluded that the no-contact attitude correction approach for the satellite with uniaxial constant magnetic moment is feasible and potentially applicable to on-orbit operations.

Gaussian Curvature as an Identifier of Shell Rigidity

NASA Astrophysics Data System (ADS)

Harutyunyan, Davit

2017-11-01

In the paper we deal with shells with non-zero Gaussian curvature. We derive sharp Korn's first (linear geometric rigidity estimate) and second inequalities on that kind of shell for zero or periodic Dirichlet, Neumann, and Robin type boundary conditions. We prove that if the Gaussian curvature is positive, then the optimal constant in the first Korn inequality scales like h, and if the Gaussian curvature is negative, then the Korn constant scales like h 4/3, where h is the thickness of the shell. These results have a classical flavour in continuum mechanics, in particular shell theory. The Korn first inequalities are the linear version of the famous geometric rigidity estimate by Friesecke et al. for plates in Arch Ration Mech Anal 180(2):183-236, 2006 (where they show that the Korn constant in the nonlinear Korn's first inequality scales like h 2), extended to shells with nonzero curvature. We also recover the uniform Korn-Poincaré inequality proven for "boundary-less" shells by Lewicka and Müller in Annales de l'Institute Henri Poincare (C) Non Linear Anal 28(3):443-469, 2011 in the setting of our problem. The new estimates can also be applied to find the scaling law for the critical buckling load of the shell under in-plane loads as well as to derive energy scaling laws in the pre-buckled regime. The exponents 1 and 4/3 in the present work appear for the first time in any sharp geometric rigidity estimate.

Constant load and constant volume response of municipal solid waste in simple shear.

PubMed

Zekkos, Dimitrios; Fei, Xunchang

2017-05-01

Constant load and constant volume simple shear testing was conducted on relatively fresh municipal solid waste (MSW) from two landfills in the United States, one in Michigan and a second in Texas, at respective natural moisture content below field capacity. The results were assessed in terms of two failure strain criteria, at 10% and 30% shear strain, and two interpretations of effective friction angle. Overall, friction angle obtained assuming that the failure plane is horizontal and at 10% shear strain resulted in a conservative estimation of shear strength of MSW. Comparisons between constant volume and constant load simple shear testing results indicated significant differences in the shear response of MSW with the shear resistance in constant volume being lower than the shear resistance in constant load. The majority of specimens were nearly uncompacted during specimen preparation to reproduce the state of MSW in bioreactor landfills or in uncontrolled waste dumps. The specimens had identical percentage of <20mm material but the type of <20mm material was different. The <20mm fraction from Texas was finer and of high plasticity. MSW from Texas was overall weaker in both constant load and constant volume conditions compared to Michigan waste. The results of these tests suggest the possibility of significantly lower shear strength of MSW in bioreactor landfills where waste is placed with low compaction effort and constant volume, i.e., "undrained", conditions may occur. Compacted MSW specimens resulted in shear strength parameters that are higher than uncompacted specimens and closer to values reported in the literature. However, the normalized undrained shear strength in simple shear for uncompacted and compacted MSW was still higher than the normalized undrained shear strength reported in the literature for clayey and silty soils. Copyright © 2016 Elsevier Ltd. All rights reserved.