Science.gov

Sample records for high kinetic energy

  1. Limiting Energy Dissipation Induces Glassy Kinetics in Single-Cell High-Precision Responses

    PubMed Central

    Das, Jayajit

    2016-01-01

    Single cells often generate precise responses by involving dissipative out-of-thermodynamic-equilibrium processes in signaling networks. The available free energy to fuel these processes could become limited depending on the metabolic state of an individual cell. How does limiting dissipation affect the kinetics of high-precision responses in single cells? I address this question in the context of a kinetic proofreading scheme used in a simple model of early-time T cell signaling. Using exact analytical calculations and numerical simulations, I show that limiting dissipation qualitatively changes the kinetics in single cells marked by emergence of slow kinetics, large cell-to-cell variations of copy numbers, temporally correlated stochastic events (dynamic facilitation), and ergodicity breaking. Thus, constraints in energy dissipation, in addition to negatively affecting ligand discrimination in T cells, can create a fundamental difficulty in determining single-cell kinetics from cell-population results. PMID:26958894

  2. Distinctive features of kinetics of plasma at high specific energy deposition

    NASA Astrophysics Data System (ADS)

    Lepikhin, Nikita; Popov, Nikolay; Starikovskaia, Svetlana

    2016-09-01

    A nanosecond capillary discharge in pure nitrogen at moderate pressures is used as an experimental tool for plasma kinetics studies at conditions of high specific deposited energy up to 1 eV/molecule. Experimental observations based on electrical (back current shunts, capacitive probe) and spectroscopic measurements (quenching rates; translational, rotational and vibrational temperature measurements) demonstrate that high specific deposited energy, at electric fields of 200-300 Td, can significantly change gas kinetics in the discharge and in the afterglow. The numerical calculations in 1D axially symmetric geometry using experimental data as input parameters show that changes in the plasma kinetics are caused by extremely high excitation degree: up to 10% of molecular nitrogen is electronically excited at present conditions. Distinctive features of kinetics of plasma at high specific energy deposition as well as details of the experimental technique and numerical calculations will be present. The work was partially supported by French National Agency, ANR (PLASMAFLAME Project, 2011 BS09 025 01), AOARD AFOSR, FA2386-13-1-4064 grant (Program Officer Prof. Chiping Li), LabEx Plas@Par and Linked International Laboratory LIA KaPPA (France-Russia).

  3. KINETIC ENERGY FROM SUPERNOVA FEEDBACK IN HIGH-RESOLUTION GALAXY SIMULATIONS

    SciTech Connect

    Simpson, Christine M.; Bryan, Greg L.; Ostriker, Jeremiah P.; Hummels, Cameron

    2015-08-10

    We describe a new method for adding a prescribed amount of kinetic energy to simulated gas modeled on a cartesian grid by directly altering grid cells’ mass and velocity in a distributed fashion. The method is explored in the context of supernova (SN) feedback in high-resolution (∼10 pc) hydrodynamic simulations of galaxy formation. Resolution dependence is a primary consideration in our application of the method, and simulations of isolated explosions (performed at different resolutions) motivate a resolution-dependent scaling for the injected fraction of kinetic energy that we apply in cosmological simulations of a 10{sup 9} M{sub ⊙} dwarf halo. We find that in high-density media (≳50 cm{sup −3}) with coarse resolution (≳4 pc per cell), results are sensitive to the initial kinetic energy fraction due to early and rapid cooling. In our galaxy simulations, the deposition of small amounts of SN energy in kinetic form (as little as 1%) has a dramatic impact on the evolution of the system, resulting in an order-of-magnitude suppression of stellar mass. The overall behavior of the galaxy in the two highest resolution simulations we perform appears to converge. We discuss the resulting distribution of stellar metallicities, an observable sensitive to galactic wind properties, and find that while the new method demonstrates increased agreement with observed systems, significant discrepancies remain, likely due to simplistic assumptions that neglect contributions from SNe Ia and stellar winds.

  4. Kinetic Energy from Supernova Feedback in High-resolution Galaxy Simulations

    NASA Astrophysics Data System (ADS)

    Simpson, Christine M.; Bryan, Greg L.; Hummels, Cameron; Ostriker, Jeremiah P.

    2015-08-01

    We describe a new method for adding a prescribed amount of kinetic energy to simulated gas modeled on a cartesian grid by directly altering grid cells’ mass and velocity in a distributed fashion. The method is explored in the context of supernova (SN) feedback in high-resolution (˜10 pc) hydrodynamic simulations of galaxy formation. Resolution dependence is a primary consideration in our application of the method, and simulations of isolated explosions (performed at different resolutions) motivate a resolution-dependent scaling for the injected fraction of kinetic energy that we apply in cosmological simulations of a 109 M⊙ dwarf halo. We find that in high-density media (≳50 cm-3) with coarse resolution (≳4 pc per cell), results are sensitive to the initial kinetic energy fraction due to early and rapid cooling. In our galaxy simulations, the deposition of small amounts of SN energy in kinetic form (as little as 1%) has a dramatic impact on the evolution of the system, resulting in an order-of-magnitude suppression of stellar mass. The overall behavior of the galaxy in the two highest resolution simulations we perform appears to converge. We discuss the resulting distribution of stellar metallicities, an observable sensitive to galactic wind properties, and find that while the new method demonstrates increased agreement with observed systems, significant discrepancies remain, likely due to simplistic assumptions that neglect contributions from SNe Ia and stellar winds.

  5. Kinetic energy of throughfall in a highly diverse forest ecosystem in the humid subtropics

    NASA Astrophysics Data System (ADS)

    Geißler, Christian; Kühn, Peter; Scholten, Thomas

    2010-05-01

    conditions. Most of the energy is supposed to be absorbed by shrubs, herbs and the litter layer. For some species in the shrub and herb layer throughfall drops are crucial for seed dispersal (Nakanishi 2002). A higher kinetic energy of throughfall should be advantageous for seed dispersal and probably support biodiversity. Further, it is shown that the variability of kinetic energy in forests varies among the age of the forest stand which can be related to the forest structure. In our case there is a high variability in young forests (< 30 years) due to selective logging (some older trees were left out) and gaps in the tree layer. Old forests (> 80 years) also have a high variability in kinetic energy. There, external influences like snow and wind break result in a fragmentary tree layer which allows less erosive rainfall to reach the forest floor. Medium aged forests are more homogenous regarding canopy closure or tree heights. Generally, the variability of kinetic energy in forests is increasing with the amount of rainfall. Moreover, it is shown that the kinetic energy of throughfall is species specific. For the investigated tree species the values range between 24.41 J m-2 mm-1 (Daphniphyllum oldhamii) and 33.24 J m-2 mm-1 (Schima superba) while the concurrent rainfall in the open field has an average kinetic energy of 6.75 J m-2 mm-1. Leaf size and canopy architecture are supposed to be two of the controlling variables for specific species. These results give implications for afforestation measures and are important input variables for modeling of erosion processes. Chapman, G., 1948. Size of raindrops and their striking force at the soil surface in a Red Pine plantation. Transactions - American Geophysical Union, 29: 664-670. Ellison, W.D., 1947. Soil Erosion Studies - Part II. Agricultural Engineering, 28: 197-201. Geißler, C., Kühn, P., Böhnke, M., Bruelheide, H., Shi, X., Scholten, T., under review: Measuring splash erosion potential under vegetation using sand

  6. Enhancing Understanding of High Energy Density Plasmas Using Fluid Modeling with Kinetic Closures

    NASA Astrophysics Data System (ADS)

    Hansen, David; Held, Eric; Srinivasan, Bhuvana; Masti, Robert; King, Jake

    2016-10-01

    This work seeks to understand possible stabilization mechanisms of the early-time electrothermal instability in the evolution of the Rayleigh-Taylor instability in MagLIF (Magnetized Liner Inertial Fusion) experiments. Such mechanisms may include electron thermal conduction, viscosity, and large magnetic fields. Experiments have shown that the high-energy density plasmas from wire-array implosions require physics modelling that goes well beyond simple models such as ideal MHD. The plan is to develop a multi-fluid extended-MHD model that includes kinetic closures for thermal conductivity, resistivity, and viscosity using codes that are easily available to the wider research community. Such an effort would provide the community with a well-benchmarked tool capable of advanced modeling of high-energy-density plasmas.

  7. Hybrid Kinetic-Fluid Electromagnetic Simulations of Imploding High Energy Density Plasmas for IFE

    NASA Astrophysics Data System (ADS)

    Welch, Dale; Rose, Dave; Thoma, Carsten; Genoni, Thomas; Bruner, Nichelle; Clark, Robert; Stygar, William; Leeper, Ramon

    2011-10-01

    A new simulation technique is being developed to study high current and moderate density-radius product (ρR) z-pinch plasmas relevant to Inertial Fusion Energy (IFE). Fully kinetic, collisional, and electromagnetic simulations of the time evolution of up to 40-MA current (deuterium and DT) z-pinches, but with relatively low ρR, have yielded new insights into the mechanisms of neutron production. At fusion relevant conditions (ρR > 0.01 gm/cm2) , however, this technique requires a prohibitively large number of cells and particles. A new hybrid implicit technique has been developed that accurately describes high-density and magnetized imploding plasmas. The technique adapts a recently published algorithm, that enables accurate descriptions of highly magnetized particle orbits, to high density plasmas and also makes use of an improved kinetic particle remap technique. We will discuss the new technique, stable range of operation, and application to an IFE relevant z-pinch design at 60 MA. Work supported by Sandia National Laboratories.

  8. Fully-kinetic simulations of the Rayleigh-Taylor instability in high-energy-density plasmas

    NASA Astrophysics Data System (ADS)

    Alves, E. Paulo; Mori, Warren B.; Fiuza, Frederico

    2016-10-01

    The Rayleigh-Taylor instability (RTI) in high-energy-density (HED) plasmas is a central problem in a wide range of scenarios. It dictates, for instance, the dynamics of supernovae in astrophysical plasmas, and is also recognized as a critical challenge to achieving ignition in inertial confinement fusion. In some of these conditions the Larmor radius or Coulomb mean free path (m.f.p.) is finite, allowing kinetic effects to become important, and it is not fully clear how the development of the RTI deviates from standard hydrodynamic behavior. In order to obtain an accurate description of the RTI in these HED conditions it is essential to capture the self-consistent interplay between collisional and collisionless plasma processes, and the role of self-generated electric and magnetic fields. We have explored the dynamics of the RTI in HED plasma conditions using first-principles particle-in-cell simulations combined with Monte Carlo binary collisions. Our simulations capture the role of kinetic diffusion as well as the self-generated electric (e.g. space-charge) and magnetic (e.g. Biermann battery) fields on the growth rate and nonlinear evolution of the RTI for different plasma conditions. We will discuss how different collisional m.f.p. relative to the collisionless plasma skin depth affect the RTI development. This work was supported by the DOE Office of Science, Fusion Energy Science (FWP 100182).

  9. Quantifying the Nucleation and Growth Kinetics of Microwave Nanochemistry Enabled by in Situ High-Energy X-ray Scattering.

    PubMed

    Liu, Qi; Gao, Min-Rui; Liu, Yuzi; Okasinski, John S; Ren, Yang; Sun, Yugang

    2016-01-13

    The fast reaction kinetics presented in the microwave synthesis of colloidal silver nanoparticles was quantitatively studied, for the first time, by integrating a microwave reactor with in situ X-ray diffraction at a high-energy synchrotron beamline. Comprehensive data analysis reveals two different types of reaction kinetics corresponding to the nucleation and growth of the Ag nanoparticles. The formation of seeds (nucleation) follows typical first-order reaction kinetics with activation energy of 20.34 kJ/mol, while the growth of seeds (growth) follows typical self-catalytic reaction kinetics. Varying the synthesis conditions indicates that the microwave colloidal chemistry is independent of concentration of surfactant. These discoveries reveal that the microwave synthesis of Ag nanoparticles proceeds with reaction kinetics significantly different from the synthesis present in conventional oil bath heating. The in situ X-ray diffraction technique reported in this work is promising to enable further understanding of crystalline nanomaterials formed through microwave synthesis.

  10. High order magnetic optics for high dynamic range proton radiography at a kinetic energy of 800 MeV

    NASA Astrophysics Data System (ADS)

    Sjue, S. K. L.; Mariam, F. G.; Merrill, F. E.; Morris, C. L.; Saunders, A.

    2016-01-01

    Flash radiography with 800 MeV kinetic energy protons at Los Alamos National Laboratory is an important experimental tool for investigations of dynamic material behavior driven by high explosives or pulsed power. The extraction of quantitative information about density fields in a dynamic experiment from proton generated images requires a high fidelity model of the proton imaging process. It is shown that accurate calculations of the transmission through the magnetic lens system require terms beyond second order for protons far from the tune energy. The approach used integrates the correlated multiple Coulomb scattering distribution simultaneously over the collimator and the image plane. Comparison with a series of static calibration images demonstrates the model's accurate reproduction of both the transmission and blur over a wide range of tune energies in an inverse identity lens that consists of four quadrupole electromagnets.

  11. High order magnetic optics for high dynamic range proton radiography at a kinetic energy 800 MeV

    SciTech Connect

    Sjue, Sky K. L.; Morris, Christopher L.; Merrill, Frank Edward; Mariam, Fesseha Gebre; Saunders, Alexander

    2016-01-14

    Flash radiography with 800 MeV kinetic energy protons at Los Alamos National Laboratory is an important experimental tool for investigations of dynamic material behavior driven by high explosives or pulsed power. The extraction of quantitative information about density fields in a dynamic experiment from proton generated images requires a high fidelity model of the protonimaging process. It is shown that accurate calculations of the transmission through the magnetic lens system require terms beyond second order for protons far from the tune energy. The approach used integrates the correlated multiple Coulomb scattering distribution simultaneously over the collimator and the image plane. Furthermore, comparison with a series of static calibrationimages demonstrates the model’s accurate reproduction of both the transmission and blur over a wide range of tune energies in an inverse identity lens that consists of four quadrupole electromagnets.

  12. High order magnetic optics for high dynamic range proton radiography at a kinetic energy of 800 MeV

    SciTech Connect

    Sjue, S. K. L. Mariam, F. G.; Merrill, F. E.; Morris, C. L.; Saunders, A.

    2016-01-15

    Flash radiography with 800 MeV kinetic energy protons at Los Alamos National Laboratory is an important experimental tool for investigations of dynamic material behavior driven by high explosives or pulsed power. The extraction of quantitative information about density fields in a dynamic experiment from proton generated images requires a high fidelity model of the proton imaging process. It is shown that accurate calculations of the transmission through the magnetic lens system require terms beyond second order for protons far from the tune energy. The approach used integrates the correlated multiple Coulomb scattering distribution simultaneously over the collimator and the image plane. Comparison with a series of static calibration images demonstrates the model’s accurate reproduction of both the transmission and blur over a wide range of tune energies in an inverse identity lens that consists of four quadrupole electromagnets.

  13. High order magnetic optics for high dynamic range proton radiography at a kinetic energy 800 MeV

    DOE PAGES

    Sjue, Sky K. L.; Morris, Christopher L.; Merrill, Frank Edward; ...

    2016-01-14

    Flash radiography with 800 MeV kinetic energy protons at Los Alamos National Laboratory is an important experimental tool for investigations of dynamic material behavior driven by high explosives or pulsed power. The extraction of quantitative information about density fields in a dynamic experiment from proton generated images requires a high fidelity model of the protonimaging process. It is shown that accurate calculations of the transmission through the magnetic lens system require terms beyond second order for protons far from the tune energy. The approach used integrates the correlated multiple Coulomb scattering distribution simultaneously over the collimator and the image plane.more » Furthermore, comparison with a series of static calibrationimages demonstrates the model’s accurate reproduction of both the transmission and blur over a wide range of tune energies in an inverse identity lens that consists of four quadrupole electromagnets.« less

  14. Systematics of kinetic freeze-out properties in high energy collisions from STAR

    NASA Astrophysics Data System (ADS)

    Kumar, Lokesh

    2014-11-01

    The main aim of the RHIC Beam Energy Scan (BES) program is to explore the QCD phase diagram which includes search for a possible QCD critical point and the phase boundary between QGP and hadronic phase. We report the collision energy and centrality dependence of kinetic freeze-out properties from the measured mid-rapidity (| y | < 0.1) light hadrons (pions, kaons, protons and their anti-particles) for Au + Au collisions at the center-of-mass energy √{sNN} = 7.7 , 11.5 , 19.6 , 27 , and 39 GeV. The STAR detector, with a large uniform acceptance and excellent particle identification is used in the data collection and analysis. The kinetic freeze-out temperature Tkin and average collective velocity < β > parameters are extracted from blast-wave fits to the identified hadron spectra and systematically compared with the results from other collision energies including those at AGS, SPS and LHC. It is found that all results fall into an anti-correlation band in the 2-dimensional (Tkin, < β >) distribution: the largest value of collective velocity and lowest temperature is reached in the most central collisions at the highest collision energy. The energy dependence of these freeze-out parameters is discussed.

  15. High energy efficiency and high power density proton exchange membrane fuel cells: Electrode kinetics and mass transport

    NASA Technical Reports Server (NTRS)

    Srinivasan, Supramaniam; Velev, Omourtag A.; Parthasathy, Arvind; Manko, David J.; Appleby, A. John

    1991-01-01

    The development of proton exchange membrane (PEM) fuel cell power plants with high energy efficiencies and high power densities is gaining momentum because of the vital need of such high levels of performance for extraterrestrial (space, underwater) and terrestrial (power source for electric vehicles) applications. Since 1987, considerable progress has been made in achieving energy efficiencies of about 60 percent at a current density of 200 mA/sq cm and high power densities (greater than 1 W/sq cm) in PEM fuel cells with high (4 mg/sq cm) or low (0.4 mg/sq cm) platinum loadings in electrodes. The following areas are discussed: (1) methods to obtain these high levels of performance with low Pt loading electrodes - by proton conductor impregnation into electrodes, localization of Pt near front surface; (2) a novel microelectrode technique which yields electrode kinetic parameters for oxygen reduction and mass transport parameters; (3) demonstration of lack of water transport from anode to cathode; (4) modeling analysis of PEM fuel cell for comparison with experimental results and predicting further improvements in performance; and (5) recommendations of needed research and development for achieving the above goals.

  16. Comminution of solids caused by kinetic energy of high shear strain rate, with implications for impact, shock, and shale fracturing.

    PubMed

    Bazant, Zdenek P; Caner, Ferhun C

    2013-11-26

    Although there exists a vast literature on the dynamic comminution or fragmentation of rocks, concrete, metals, and ceramics, none of the known models suffices for macroscopic dynamic finite element analysis. This paper outlines the basic idea of the macroscopic model. Unlike static fracture, in which the driving force is the release of strain energy, here the essential idea is that the driving force of comminution under high-rate compression is the release of the local kinetic energy of shear strain rate. The density of this energy at strain rates >1,000/s is found to exceed the maximum possible strain energy density by orders of magnitude, making the strain energy irrelevant. It is shown that particle size is proportional to the -2/3 power of the shear strain rate and the 2/3 power of the interface fracture energy or interface shear stress, and that the comminution process is macroscopically equivalent to an apparent shear viscosity that is proportional (at constant interface stress) to the -1/3 power of this rate. A dimensionless indicator of the comminution intensity is formulated. The theory was inspired by noting that the local kinetic energy of shear strain rate plays a role analogous to the local kinetic energy of eddies in turbulent flow.

  17. Laser sustained discharge nozzle apparatus for the production of an intense beam of high kinetic energy atomic species

    DOEpatents

    Cross, Jon B.; Cremers, David A.

    1988-01-01

    Laser sustained discharge apparatus for the production of intense beams of high kinetic energy atomic species. A portion of the plasma resulting from a laser sustained continuous optical discharge which generates energetic atomic species from a gaseous source thereof is expanded through a nozzle into a region of low pressure. The expanded plasma contains a significant concentration of the high kinetic energy atomic species which may be used to investigate the interaction of surfaces therewith. In particular, O-atoms having velocities in excess of 3.5 km/s can be generated for the purpose of studying their interaction with materials in order to develop protective materials for spacecraft which are exposed to such energetic O-atoms during operation in low earth orbit.

  18. Laser sustained discharge nozzle apparatus for the production of an intense beam of high kinetic energy atomic species

    DOEpatents

    Cross, J.B.; Cremers, D.A.

    1986-01-10

    Laser sustained discharge apparatus for the production of intense beams of high kinetic energy atomic species is described. A portion of the plasma resulting from a laser sustained continuous optical discharge which generates energetic atomic species from a gaseous source thereof is expanded through a nozzle into a region of low pressure. The expanded plasma contains a significant concentration of the high kinetic energy atomic species which may be used to investigate the interaction of surfaces therewith. In particular, O-atoms having velocities in excess of 3.5 km/s can be generated for the purpose of studying their interaction with materials in order to develop protective materials for spacecraft which are exposed to such energetic O-atoms during operation in low earth orbit.

  19. Seasonal variability of eddy kinetic energy in a global high-resolution ocean model

    NASA Astrophysics Data System (ADS)

    Rieck, Jan K.; Böning, Claus W.; Greatbatch, Richard J.; Scheinert, Markus

    2015-11-01

    A global ocean model with 1/12° horizontal resolution is used to assess the seasonal cycle of surface eddy kinetic energy (EKE). The model reproduces the salient features of the observed mean surface EKE, including amplitude and phase of its seasonal cycle in most parts of the ocean. In all subtropical gyres of the Pacific and Atlantic, EKE peaks in summer down to a depth of ˜350 m, below which the seasonal cycle is weak. Investigation of the possible driving mechanisms reveals the seasonal changes in the thermal interactions with the atmosphere to be the most likely cause of the summer maximum of EKE. The development of the seasonal thermocline in spring and summer is accompanied by stronger mesoscale variations in the horizontal temperature gradients near the surface which corresponds, by thermal wind balance, to an intensification of mesoscale velocity anomalies toward the surface.

  20. Kinetic energy transducing system

    SciTech Connect

    Danihel, M.

    1986-07-08

    A device is described for converting wave energy to mechanical motion comprising: a frame, at least one wave energy transducer each of which has a float to ride upon the undulating surface of a body of water, a rocker shaft rotatably mounted in the frame and connected to the float by a rocker arm to turn in response to movement of the float upon the undulating water surface, a pair of unidirectional clutch mechanisms coupled to the rocker shaft, a drive shaft rotatably mounted on the frame and connected to the clutch mechanisms to turn in a single direction of rotation responsive to alternative engagement of the clutch mechanisms therewith and turning movement of the rocker shaft in both directions of rotation, and a hydrofoil system for each float including a vertical shaft extending downwardly from the bottom of each float, a transverse rod which is rotatably coupled to the vertical shaft, a pair of hydrofoil wings secured to the transverse rod on opposite sides of the vertical shaft, and means for centering the hydrofoil wings acting between the vertical shaft and the transverse rod to urge the hydrofoil wings toward horizontal orientation.

  1. Mass yields and kinetic energy of fragments from fission of highly-excited nuclei with A≲220

    NASA Astrophysics Data System (ADS)

    Denisov, V. Yu.; Margitych, T. O.; Sedykh, I. Yu.

    2017-02-01

    It is shown that the potential energy surface of the two separated fragments has the saddle point, which takes place at small distance between the surfaces of well-deformed fragments. The height of this two-body saddle point is larger than the height of one-body fission barrier for nuclei with A ≲ 220. The mass yields of the fission fragments, which are appearing at the fission of nuclei with A ≲ 220, are related to the number of states of the two-fragment systems at the two-body saddle points. The characteristics of kinetic energy of fragments are described by using the trajectory motion equations with the dissipation terms. The Gaussian distribution of the final kinetic energy around the classical value of this energy induced by the stochastic fluctuations is taken into account at an evaluation of the total kinetic energy distributions of the fission fragments.

  2. Conversion of laser energy to gas kinetic energy

    NASA Technical Reports Server (NTRS)

    Caledonia, G. E.

    1976-01-01

    Techniques for the gas phase absorption of laser radiation for ultimate conversion to gas kinetic energy are discussed. Particular emphasis is placed on absorption by the vibration rotation bands of diatomic molecules at high pressures. This high pressure absorption appears to offer efficient conversion of laser energy to gas translational energy. Bleaching and chemical effects are minimized and the variation of the total absorption coefficient with temperature is minimal.

  3. On a consistent high-order finite difference scheme with kinetic energy conservation for simulating turbulent reacting flows

    NASA Astrophysics Data System (ADS)

    Trisjono, Philipp; Kang, Seongwon; Pitsch, Heinz

    2016-12-01

    The main objective of this study is to present an accurate and consistent numerical framework for turbulent reacting flows based on a high-order finite difference (HOFD) scheme. It was shown previously by Desjardins et al. (2008) [4] that a centered finite difference scheme discretely conserving the kinetic energy and an upwind-biased scheme for the scalar transport can be combined into a useful scheme for turbulent reacting flows. With a high-order spatial accuracy, however, an inconsistency among discretization schemes for different conservation laws is identified, which can disturb a scalar field spuriously under non-uniform density distribution. Various theoretical and numerical analyses are performed on the sources of the unphysical error. From this, the derivative of the mass-conserving velocity and the local Péclet number are identified as the primary factors affecting the error. As a solution, an HOFD stencil for the mass conservation is reformulated into a flux-based form that can be used consistently with an upwind-biased scheme for the scalar transport. The effectiveness of the proposed formulation is verified using two-dimensional laminar flows such as a scalar transport problem and a laminar premixed flame, where unphysical oscillations in the scalar fields are removed. The applicability of the proposed scheme is demonstrated in an LES of a turbulent stratified premixed flame.

  4. High Kinetic Energy Penetrator Shielding and High Wear Resistance Materials Fabricated with Boron Nitride Nanotubes (BNNTS) and BNNT Polymer Composites

    NASA Technical Reports Server (NTRS)

    Kang, Jin Ho (Inventor); Park, Cheol (Inventor); Sauti, Godfrey (Inventor); Smith, Michael W. (Inventor); Jordan, Kevin C. (Inventor); Lowther, Sharon E. (Inventor); Bryant, Robert George (Inventor)

    2015-01-01

    Boron nitride nanotubes (BNNTs), boron nitride nanoparticles (BNNPs), carbon nanotubes (CNTs), graphites, or combinations, are incorporated into matrices of polymer, ceramic or metals. Fibers, yarns, and woven or nonwoven mats of BNNTs are used as toughening layers in penetration resistant materials to maximize energy absorption and/or high hardness layers to rebound or deform penetrators. They can be also used as reinforcing inclusions combining with other polymer matrices to create composite layers like typical reinforcing fibers such as Kevlar.RTM., Spectra.RTM., ceramics and metals. Enhanced wear resistance and usage time are achieved by adding boron nitride nanomaterials, increasing hardness and toughness. Such materials can be used in high temperature environments since the oxidation temperature of BNNTs exceeds 800.degree. C. in air. Boron nitride based composites are useful as strong structural materials for anti-micrometeorite layers for spacecraft and space suits, ultra strong tethers, protective gear, vehicles, helmets, shields and safety suits/helmets for industry.

  5. Protein-energy status and 15N-glycine kinetic study of child a cirrhotic patients fed low- to high-protein energy diets.

    PubMed

    Dichi, I; Dichi, J B; Papini-Berto, S J; Angeleli, A Y; Bicudo, M H; Rezende, T A; Burini, R C

    1996-01-01

    In five male cirrhotic patients (Child A) and in four age- and sex-matched healthy control subjects, whole-body protein turnover was measured using a single oral dose of 15N-glycine as a tracer and urinary ammonia as end product. Subjects were studied in the fasting and feeding state, with different levels of protein and energy intake. The patients were underweight and presented lower plasma transthyretin and retinol-binding protein levels. When compared with controls, the kinetic studies showed patients to be hypometabolic in the fasting (D0) state and with the control diet [D1 = (0.85 g of protein/ 154 kJ) x kg-1.day-1]. However, when corrected by body weight, the kinetic differences between groups disappeared, whereas the N-retention in the feeding state showed better results for the patients due mainly to their efficient breakdown decrease. When fed high-level protein or energy diets [D1 = (0.9 g protein/195 kJ) and D3 = (1.56 g protein/158 kJ) x kg-1.day-1], the patients showed D0 = D1 = D2 < D3 for N-flux and (D0 = D1) < D3 (D2 is intermediary) for protein synthesis. Thus, the present data suggest that the remaining mass of the undernourished mild cirrhotic patients has fairly good protein synthesis activity and also that protein, rather than energy intake, would be the limiting factor for increasing their whole-body protein synthesis.

  6. High Voltage-Cylinder Sector Analyzer 300/15: A cylindrical sector analyzer for electron kinetic energies up to 15 keV

    NASA Astrophysics Data System (ADS)

    Rubio-Zuazo, J.; Escher, M.; Merkel, M.; Castro, G. R.

    2010-04-01

    We have developed an energy analyzer, High Voltage-Cylinder Sector Analyzer 300/15, for electron kinetic energies up to 15 keV. It is especially suited for hard x-ray photoelectron spectroscopy, but also for ultraviolet and soft x-ray photoelectron spectroscopy (ultraviolet photoemission spectroscopy, x-ray photoemission spectroscopy), Auger electron spectroscopy, and reflection high energy electron spectroscopy. The analyzer is based on a cylinder sector with 90° deflection, 300 mm slit-to-slit distance, and a four-element pre-retarding lens system with 50 mm sample-to-lens distance. The result is a very compact design of the analyzer that is easily integrated into a multipurpose experiment with different techniques. A low noise/low drift electronics is capable of continuous energy scans from 0 to 15 keV using nonlinear lens curves. The first analyzer is allocated at the Spanish CRG SpLine beamline at the ESRF at an end station where simultaneous surface x-ray diffraction is possible. The analyzer is operated routinely since 2006 up to 15 keV electron kinetic energy, expanding the achievable electron kinetic energy range compared to other commercial analyzers. In this work we present a detailed description of the developed electron analyzer. The analyzer capabilities, in terms of energy resolution and transmission, are shown by using an electron gun, an ultraviolet-discharge lamp, and hard x-ray synchrotron radiation as excitation sources.

  7. Quantitative detection of benzene in toluene- and xylene-rich atmospheres using high-kinetic-energy ion mobility spectrometry (IMS).

    PubMed

    Langejuergen, Jens; Allers, Maria; Oermann, Jens; Kirk, Ansgar; Zimmermann, Stefan

    2014-12-02

    One major drawback of ion mobility spectrometry (IMS) is the dependence of the response to a certain analyte on the concentration of water or the presence of other compounds in the sample gas. Especially for low proton affine analytes, e.g., benzene, which often exists in mixtures with other volatile organic compounds, such as toluene and xylene (BTX), a time-consuming preseparation is necessary. In this work, we investigate BTX mixtures using a compact IMS operated at decreased pressure (20 mbar) and high kinetic ion energies (HiKE-IMS). The reduced electric field in both the reaction tube and the drift tube can be independently increased up to 120 Td. Under these conditions, the water cluster distribution of reactant ions is shifted toward smaller clusters independent of the water content in the sample gas. Thus, benzene can be ionized via proton transfer from H3O(+) reactant ions. Also, a formation of benzene ions via charge transfer from NO(+) is possible. Furthermore, the time for interaction between ions and neutrals of different analytes is limited to such an extent that a simultaneous quantification of benzene, toluene, and xylene is possible from low ppbv up to several ppmv concentrations. The mobility resolution of the presented HiKE-IMS varies from R = 65 at high field (90 Td) to R = 73 at lower field (40 Td) in the drift tube, which is sufficient to separate the analyzed compounds. The detection limit for benzene is 29 ppbv (2 s of averaging) with 3700 ppmv water, 12.4 ppmv toluene, and 9 ppmv xylene present in the sample gas. Furthermore, a less-moisture-dependent benzene measurement with a detection limit of 32 ppbv with ca. 21 000 ppmv (90% relative humidity (RH) at 20 °C) water present in the sample gas is possible evaluating the signal from benzene ions formed via charge transfer.

  8. Conversion of laser energy to gas kinetic energy

    NASA Technical Reports Server (NTRS)

    Caledonia, G. E.

    1975-01-01

    Techniques for the gas phase absorption of laser radiation for conversion to gas kinetic energy are discussed. Absorption by inverse Bremsstrahlung, in which laser energy is converted at a gas kinetic rate in a spectrally continuous process, is briefly described, and absorption by molecular vibrational rotation bands is discussed at length. High pressure absorption is proposed as a means of minimizing gas bleaching and dissociation, the major disadvantages of the molecular absorption process. A band model is presented for predicting the molecular absorption spectra in the high pressure absorption region and is applied to the CO molecule. Use of a rare gas seeded with Fe(CO)5 for converting vibrational modes to translation modes is described.

  9. Conversion of laser energy to gas kinetic energy

    NASA Technical Reports Server (NTRS)

    Caledonia, G. E.

    1977-01-01

    Techniques for the gas-phase absorption of laser energy with ultimate conversion to heat or directed kinetic energy are reviewed. It is shown that the efficiency of resonance absorption by the vibration/rotation bands of the working gas can be enhanced by operating at sufficiently high pressures so that the linewidths of the absorbing transition exceed the line spacing. Within this limit, the gas can absorb continuously over the full spectral region of the band, and bleaching can be minimized since the manifold of molecular vibrational levels can simultaneously absorb the laser radiation.

  10. Kinetic energy budgets in areas of convection

    NASA Technical Reports Server (NTRS)

    Fuelberg, H. E.

    1979-01-01

    Synoptic scale budgets of kinetic energy are computed using 3 and 6 h data from three of NASA's Atmospheric Variability Experiments (AVE's). Numerous areas of intense convection occurred during the three experiments. Large kinetic energy variability, with periods as short as 6 h, is observed in budgets computed over each entire experiment area and over limited volumes that barely enclose the convection and move with it. Kinetic energy generation and transport processes in the smaller volumes are often a maximum when the enclosed storms are near peak intensity, but the nature of the various energy processes differs between storm cases and seems closely related to the synoptic conditions. A commonly observed energy budget for peak storm intensity indicates that generation of kinetic energy by cross-contour flow is the major energy source while dissipation to subgrid scales is the major sink. Synoptic scale vertical motion transports kinetic energy from lower to upper levels of the atmosphere while low-level horizontal flux convergence and upper-level horizontal divergence also occur. Spatial fields of the energy budget terms show that the storm environment is a major center of energy activity for the entire area.

  11. High-kinetic-energy photoemission spectroscopy of Ni at 1s : 6-eV satellite at 4 eV

    NASA Astrophysics Data System (ADS)

    Karis, O.; Svensson, S.; Rusz, J.; Oppeneer, P. M.; Gorgoi, M.; Schäfers, F.; Braun, W.; Eberhardt, W.; Mårtensson, N.

    2008-12-01

    Electron correlations are responsible for many profound phenomena in solid-state physics. A classical example is the 6-eV satellite in the photoelectron spectrum of Ni. Until now the satellite structure has only been investigated at the L shell and more shallow levels. Here we report a high-kinetic-energy photoemission spectroscopy (HIKE) investigation of Ni metal. We present 1s and 2p photoelectron spectra, obtained using excitation energies up to 12.6 keV. Our investigation demonstrates that the energy position of the satellite relative to the main line is different for the 1s and the 2p levels. In combination with electronic structure calculations, we show that this energy shift is attributed to unique differences in the core-valence coupling for the K and L2,3 shells in 3d transition metals, resulting in different screening of the core holes.

  12. Seasonal variability of eddy kinetic energy in the North Atlantic subtropical gyre: A high-resolution ocean model analysis

    NASA Astrophysics Data System (ADS)

    Rieck, Jan Klaus; Böning, Claus W.; Greatbatch, Richard J.; Scheinert, Markus

    2016-04-01

    A global ocean model with 1/12° horizontal resolution is used to assess the seasonal cycle of surface eddy kinetic energy (EKE) in the North Atlantic. The model reproduces the salient features of the observed mean surface EKE, including amplitude and phase of its seasonal cycle in most parts of the basin. In the interior North Atlantic subtropical gyre, EKE peaks in summer down to a depth of ˜200 m, below which the seasonal cycle is weak. Investigation of the possible driving mechanisms reveals the seasonal changes in the thermal interactions with the atmosphere to be the most likely cause of the summer maximum of EKE. The development of the seasonal thermocline in spring and summer is accompanied by stronger mesoscale variations in the horizontal temperature gradients near the surface which corresponds, by thermal wind balance, to an intensification of mesoscale velocity anomalies toward the surface. An extension of the analysis leads to similar results in the South Atlantic, North Pacific and South Pacific subtropical gyres.

  13. Analysis of Flow Cytometry DNA Damage Response Protein Activation Kinetics Following X-rays and High Energy Iron Nuclei Exposure

    SciTech Connect

    Universities Space Research Association; Chappell, Lori J.; Whalen, Mary K.; Gurai, Sheena; Ponomarev, Artem; Cucinotta, Francis A.; Pluth, Janice M.

    2010-12-15

    We developed a mathematical method to analyze flow cytometry data to describe the kinetics of {gamma}H2AX and pATF2 phosphorylations ensuing various qualities of low dose radiation in normal human fibroblast cells. Previously reported flow cytometry kinetic results for these DSB repair phospho-proteins revealed that distributions of intensity were highly skewed, severely limiting the detection of differences in the very low dose range. Distributional analysis reveals significant differences between control and low dose samples when distributions are compared using the Kolmogorov-Smirnov test. Radiation quality differences are found in the distribution shapes and when a nonlinear model is used to relate dose and time to the decay of the mean ratio of phosphoprotein intensities of irradiated samples to controls. We analyzed cell cycle phase and radiation quality dependent characteristic repair times and residual phospho-protein levels with these methods. Characteristic repair times for {gamma}H2AX were higher following Fe nuclei as compared to X-rays in G1 cells (4.5 {+-} 0.46 h vs 3.26 {+-} 0.76 h, respectively), and in S/G2 cells (5.51 {+-} 2.94 h vs 2.87 {+-} 0.45 h, respectively). The RBE in G1 cells for Fe nuclei relative to X-rays for {gamma}H2AX was 2.05 {+-} 0.61 and 5.02 {+-} 3.47, at 2 h and 24-h postirradiation, respectively. For pATF2, a saturation effect is observed with reduced expression at high doses, especially for Fe nuclei, with much slower characteristic repair times (>7 h) compared to X-rays. RBEs for pATF2 were 0.66 {+-} 0.13 and 1.66 {+-} 0.46 at 2 h and 24 h, respectively. Significant differences in {gamma}H2AX and pATF2 levels comparing irradiated samples to control were noted even at the lowest dose analyzed (0.05 Gy) using these methods of analysis. These results reveal that mathematical models can be applied to flow cytometry data to uncover important and subtle differences following exposure to various qualities of low dose radiation.

  14. Trends in Southern Ocean Eddy Kinetic Energy

    NASA Astrophysics Data System (ADS)

    Chambers, Don

    2016-04-01

    A recent study by Hogg et al. (JGR, 2015) has demonstrated a 20-year trend in eddy kinetic energy (EKE) computed from satellite altimetry data. However, this estimate is based on an averaging over large spatial areas. In this study, we use the same methods to examine regional EKE trends throughout the Southern Ocean, from 1993-2015. We do find significant positive trends in several areas of the Southern Ocean, mainly in regions with high mean EKE associated with interactions between jets and bathymetry. At the same time, however, there are also regions with significant negative trends. Overall, EKE in the majority of the Southern Ocean has not changed. These results suggest that the estimates of Hogg et al. may have been biased by these regional extremes, and that more work is needed to quantify climatic changes in EKE.

  15. Kinetic-energy-momentum tensor in electrodynamics

    NASA Astrophysics Data System (ADS)

    Sheppard, Cheyenne J.; Kemp, Brandon A.

    2016-01-01

    We show that the Einstein-Laub formulation of electrodynamics is invalid since it yields a stress-energy-momentum (SEM) tensor that is not frame invariant. Two leading hypotheses for the kinetic formulation of electrodynamics (Chu and Einstein-Laub) are studied by use of the relativistic principle of virtual power, mathematical modeling, Lagrangian methods, and SEM transformations. The relativistic principle of virtual power is used to demonstrate the field dynamics associated with energy relations within a relativistic framework. Lorentz transformations of the respective SEM tensors demonstrate the relativistic frameworks for each studied formulation. Mathematical modeling of stationary and moving media is used to illustrate the differences and discrepancies of specific proposed kinetic formulations, where energy relations and conservation theorems are employed. Lagrangian methods are utilized to derive the field kinetic Maxwell's equations, which are studied with respect to SEM tensor transforms. Within each analysis, the Einstein-Laub formulation violates special relativity, which invalidates the Einstein-Laub SEM tensor.

  16. Turbulence kinetic energy equation for dilute suspensions

    NASA Technical Reports Server (NTRS)

    Abou-Arab, T. W.; Roco, M. C.

    1989-01-01

    A multiphase turbulence closure model is presented which employs one transport equation, namely the turbulence kinetic energy equation. The proposed form of this equation is different from the earlier formulations in some aspects. The power spectrum of the carrier fluid is divided into two regions, which interact in different ways and at different rates with the suspended particles as a function of the particle-eddy size ratio and density ratio. The length scale is described algebraically. A mass/time averaging procedure for the momentum and kinetic energy equations is adopted. The resulting turbulence correlations are modeled under less retrictive assumptions comparative to previous work. The closures for the momentum and kinetic energy equations are given. Comparisons of the predictions with experimental results on liquid-solid jet and gas-solid pipe flow show satisfactory agreement.

  17. Density Scaling of Noninteracting Kinetic Energy Functionals.

    PubMed

    Borgoo, Alex; Tozer, David J

    2013-05-14

    The influence of imposing an approximate density scaling condition on a noninteracting kinetic energy functional is investigated. A simple generalized gradient approximation (GGA) is presented, which satisfies both the density scaling condition and the usual coordinate scaling condition; the remaining multiplicative constant is determined from an energy criterion. In post-Kohn-Sham calculations, noninteracting kinetic energies of the closed-shell molecules of the G1 set determined using the GGA are a modest improvement over those determined using the corresponding local functional, which does not satisfy the density scaling condition. Potential energy curves of CO, F2, and P2 exhibit binding with the GGA, compared to purely repulsive curves with the local functional. Adjusting the exponent in the GGA form in order to optimize energy accuracy violates the density scaling condition, and two of the diatomics no longer exhibit binding. Results are compared with those from other local/GGA functionals in the literature.

  18. Impact comminution of solids due to local kinetic energy of high shear strain rate: II-Microplane model and verification

    NASA Astrophysics Data System (ADS)

    Caner, Ferhun C.; Bažant, Zdeněk P.

    2014-03-01

    The new theory presented in the preceding paper, which models the dynamic comminution of concrete due to very high shear strain rate, is now compared to recent test data on the penetration of projectiles through concrete walls of different thicknesses, ranging from 127 to 254 mm. These data are analyzed by an explicit finite element code using the new microplane constitutive model M7 for concrete, which was previously shown to provide the most realistic description of the quasi-static uni-, bi- and tri-axial test data with complex loading path and unloading. Model M7 incorporates the quasi-static strain rate effects due viscoelasticity and to the rate of cohesive crack debonding based on activation energy of bond ruptures, which are expected to extend to very high rates. Here model M7 is further enhanced by apparent viscosity capturing the energy dissipation due to the strain-rate effect of comminution. The maximum shear strain rates in the computations are of the order of 105 s-1. The simulations document that, within the inevitable uncertainties, the measured exit velocities of the projectiles can be matched quite satisfactorily and the observed shapes of the entry and exit craters can be reproduced correctly.

  19. Nonlocal kinetic-energy-density functionals

    SciTech Connect

    Garcia-Gonzalez, P.; Alvarellos, J.E.; Chacon, E. |

    1996-04-01

    In this paper we present nonlocal kinetic-energy functionals {ital T}[{ital n}] within the average density approximation (ADA) framework, which do not require any extra input when applied to any electron system and recover the exact kinetic energy and the linear response function of a homogeneous system. In contrast with previous ADA functionals, these present good behavior of the long-range tail of the exact weight function. The averaging procedure for the kinetic functional (averaging the Fermi momentum of the electron gas, instead of averaging the electron density) leads to a functional without numerical difficulties in the calculation of extended systems, and it gives excellent results when applied to atoms and jellium surfaces. {copyright} {ital 1996 The American Physical Society.}

  20. Filamentary and hierarchical pictures - Kinetic energy criterion

    NASA Technical Reports Server (NTRS)

    Klypin, Anatoly A.; Melott, Adrian L.

    1992-01-01

    We present a new criterion for formation of second-generation filaments. The criterion called the kinetic energy ratio, KR, is based on comparison of peculiar velocities at different scales. We suggest that the clumpiness of the distribution in some cases might be less important than the 'coldness' or 'hotness' of the flow for formation of coherent structures. The kinetic energy ratio is analogous to the Mach number except for one essential difference. If at some scale KR is greater than 1, as estimated at the linear stage, then when fluctuations of this scale reach nonlinearity, the objects they produce must be anisotropic ('filamentary'). In the case of power-law initial spectra the kinetic ratio criterion suggests that the border line is the power-spectrum with the slope n = -1.

  1. Excess kinetic energy dissipation in materials

    SciTech Connect

    Corrales, Louis R.; Chartier, Alain; Devanathan, Ram

    2005-01-12

    Molecular dynamics computer simulations are used to study the evolution of thermal spikes arising from PKAs in zircon and copper. The effects of thermostats employed to remove energy from the system is characterized and compared to the case where kinetic energy is not removed from the system. Strong effects on the trajectory of the collision sequence is found for zircon, but in contrast, little effects are found for copper.

  2. A Note on Kinetic Energy, Dissipation and Enstrophy

    NASA Technical Reports Server (NTRS)

    Wu, Jie-Zhi; Zhou, Ye; Fan, Meng

    1998-01-01

    The dissipation rate of a Newtonian fluid with constant shear viscosity can be shown to include three constituents: dilatation, vorticity, and surface strain. The last one is found to make no contributions to the change of kinetic energy. These dissipation constituents arc used to identify typical compact turbulent flow structures at high Reynolds numbers. The incompressible version of the simplified kinetic-energy equation is then cast to a novel form, which is free from the work rate done by surface stresses but in which the full dissipation re-enters.

  3. Estimation of turbulent kinetic energy dissipation

    NASA Astrophysics Data System (ADS)

    Chen, Huey-Long; Hondzo, Miki; Rao, A. Ramachandra

    2001-06-01

    The kinetic energy dissipation rate is one of the key intrinsic fluid flow parameters in environmental fluid dynamics. In an indirect method the kinetic energy dissipation rate is estimated from the Batchelor spectrum. Because the Batchelor spectrum has a significant difference between the highest and lowest spectral values, the spectral bias in the periodogram causes the lower spectral values at higher frequencies to increase. Consequently, the accuracy in fitting the Batchelor spectrum is affected. In this study, the multitaper spectral estimation method is compared to conventional methods in estimating the synthetic temperature gradient spectra. It is shown in the results that the multitaper spectra have less bias than the Hamming window smoothed spectra and the periodogram in estimating the synthetic temperature gradient spectra. The results of fitting the Batchelor spectrum based on four error functions are compared. When the theoretical noise spectrum is available and delineated at the intersection of the estimated spectrum, the fitting results of the kinetic energy dissipation rate corresponding to the four error functions do not have significant differences. However, when the noise spectrum is unknown and part of the Batchelor spectrum overlaps the region where the noise spectrum dominates, the weighted chi-square distributed error function has the best fitting results.

  4. Imperfect dark energy from kinetic gravity braiding

    SciTech Connect

    Deffayet, Cédric; Pujolàs, Oriol; Sawicki, Ignacy; Vikman, Alexander E-mail: oriol.pujolas@cern.ch E-mail: alexander.vikman@nyu.edu

    2010-10-01

    We introduce a large class of scalar-tensor models with interactions containing the second derivatives of the scalar field but not leading to additional degrees of freedom. These models exhibit peculiar features, such as an essential mixing of scalar and tensor kinetic terms, which we have named kinetic braiding. This braiding causes the scalar stress tensor to deviate from the perfect-fluid form. Cosmology in these models possesses a rich phenomenology, even in the limit where the scalar is an exact Goldstone boson. Generically, there are attractor solutions where the scalar monitors the behaviour of external matter. Because of the kinetic braiding, the position of the attractor depends both on the form of the Lagrangian and on the external energy density. The late-time asymptotic of these cosmologies is a de Sitter state. The scalar can exhibit phantom behaviour and is able to cross the phantom divide with neither ghosts nor gradient instabilities. These features provide a new class of models for Dark Energy. As an example, we study in detail a simple one-parameter model. The possible observational signatures of this model include a sizeable Early Dark Energy and a specific equation of state evolving into the final de-Sitter state from a healthy phantom regime.

  5. Kinetics and energy states of nanoclusters in the initial stage of homogeneous condensation at high supersaturation degrees

    SciTech Connect

    Vorontsov, A. G.; Gel'chinskii, B. R.; Korenchenko, A. E.

    2012-11-15

    The condensation of metal vapor in an inert gas is studied by the molecular dynamics method. Two condensation regimes are investigated: with maintenance of partial pressure of the metal vapor and with a fixed number of metal atoms in the system. The main focus is the study of the cluster energy distribution over the degrees of freedom and mechanisms of the establishment of thermal equilibrium. It is shown that the internal temperature of a cluster considerably exceeds the buffer gas temperature and the thermal balance is established for a time considerably exceeding the nucleation time. It is found that, when the metal vapor concentration exceeds 0.1 of the argon concentration, the growth of clusters with the highest possible internal energy occurs, the condensation rate being determined only by the rate of heat removal from clusters.

  6. Kinetic energy recovery systems in motor vehicles

    NASA Astrophysics Data System (ADS)

    Śliwiński, C.

    2016-09-01

    The article draws attention to the increasing environmental pollution caused by the development of vehicle transport and motorization. Different types of design solutions used in vehicles for the reduction of fuel consumption, and thereby emission of toxic gasses into the atmosphere, were specified. Historical design solutions concerning energy recovery devices in mechanical vehicles which used flywheels to accumulate kinetic energy were shown. Developmental tendencies in the area of vehicle manufacturing in the form of hybrid electric and electric devices were discussed. Furthermore, designs of energy recovery devices with electrical energy storage from the vehicle braking and shock absorbing systems were presented. A mechanical energy storing device using a flywheel operating under vacuum was presented, as were advantages and disadvantages of both systems, the limitations they impose on individual constructions and safety issues. The paper also discusses a design concept of an energy recovery device in mechanical vehicles which uses torsion springs as the main components of energy accumulation during braking. The desirability of a cooperation of both the mechanical- and electrical energy recovery devices was indicated.

  7. Exploring the interfacial structure of protein adsorbates and the kinetics of protein adsorption: an in situ high-energy X-ray reflectivity study.

    PubMed

    Evers, Florian; Shokuie, Kaveh; Paulus, Michael; Sternemann, Christian; Czeslik, Claus; Tolan, Metin

    2008-09-16

    The high energy X-ray reflectivity technique has been applied to study the interfacial structure of protein adsorbates and protein adsorption kinetics in situ. For this purpose, the adsorption of lysozyme at the hydrophilic silica-water interface has been chosen as a model system. The structure of adsorbed lysozyme layers was probed for various aqueous solution conditions. The effect of solution pH and lysozyme concentration on the interfacial structure was measured. Monolayer formation was observed for all cases except for the highest concentration. The adsorbed protein layers consist of adsorbed lysozyme molecules with side-on or end-on orientation. By means of time-dependent X-ray reflectivity scans, the time-evolution of adsorbed proteins was monitored as well. The results of this study demonstrate the capabilities of in situ X-ray reflectivity experiments on protein adsorbates. The great advantages of this method are the broad wave vector range available and the high time resolution.

  8. Evaluating rainfall kinetic energy - intensity relationships with observed disdrometric data

    NASA Astrophysics Data System (ADS)

    Angulo-Martinez, Marta; Begueria, Santiago; Latorre, Borja

    2016-04-01

    Rainfall kinetic energy is required for determining erosivity, the ability of rainfall to detach soil particles and initiate erosion. Its determination relay on the use of disdrometers, i.e. devices capable of measuring the drop size distribution and velocity of falling raindrops. In the absence of such devices, rainfall kinetic energy is usually estimated with empirical expressions relating rainfall energy and intensity. We evaluated the performance of 14 rainfall energy equations in estimating one-minute rainfall energy and event total energy, in comparison with observed data from 821 rainfall episodes (more than 100 thousand one-minute observations) by means of an optical disdrometer. In addition, two sources of bias when using such relationships were evaluated: i) the influence of using theoretical terminal raindrop fall velocities instead of measured values; and ii) the influence of time aggregation (rainfall intensity data every 5-, 10-, 15-, 30-, and 60-minutes). Empirical relationships did a relatively good job when complete events were considered (R2 > 0.82), but offered poorer results for within-event (one-minute resolution) variation. Also, systematic biases where large for many equations. When raindrop size distribution was known, estimating the terminal fall velocities by empirical laws produced good results even at fine time resolution. The influence of time aggregation was very high in the estimated kinetic energy, although linear scaling may allow empirical correction. This results stress the importance of considering all these effects when rainfall energy needs to be estimated from more standard precipitation records. , and recommends the use of disdrometer data to locally determine rainfall kinetic energy.

  9. Partitioning kinetic energy during freewheeling wheelchair maneuvers.

    PubMed

    Medola, Fausto O; Dao, Phuc V; Caspall, Jayme J; Sprigle, Stephen

    2014-03-01

    This paper describes a systematic method to partition the kinetic energy (KE) of a free-wheeling wheelchair. An ultralightweight rigid frame wheelchair was instrumented with two axle-mounted encoders and data acquisition equipment to accurately measure the velocity of the drive wheels. A mathematical model was created combining physical specifications and geometry of the wheelchair and its components. Two able-bodied subjects propelled the wheelchair over four courses that involved straight and turning maneuvers at differing speeds. The KE of the wheelchair was divided into three components: translational, rotational, and turning energy. This technique was sensitive to the changing contributions of the three energy components across maneuvers. Translational energy represented the major component of total KE in all maneuvers except a zero radius turn in which turning energy was dominant. Both translational and rotational energies are directly related to wheelchair speed. Partitioning KE offers a useful means of investigating the dynamics of a moving wheelchair. The described technique permits analysis of KE imparted to the wheelchair during maneuvers involving changes in speed and direction, which are most representative of mobility in everyday life. This technique can be used to study the effort required to maneuver different types and configurations of wheelchairs.

  10. On Kinetics Modeling of Vibrational Energy Transfer

    NASA Technical Reports Server (NTRS)

    Gilmore, John O.; Sharma, Surendra P.; Cavolowsky, John A. (Technical Monitor)

    1996-01-01

    Two models of vibrational energy exchange are compared at equilibrium to the elementary vibrational exchange reaction for a binary mixture. The first model, non-linear in the species vibrational energies, was derived by Schwartz, Slawsky, and Herzfeld (SSH) by considering the detailed kinetics of vibrational energy levels. This model recovers the result demanded at equilibrium by the elementary reaction. The second model is more recent, and is gaining use in certain areas of computational fluid dynamics. This model, linear in the species vibrational energies, is shown not to recover the required equilibrium result. Further, this more recent model is inconsistent with its suggested rate constants in that those rate constants were inferred from measurements by using the SSH model to reduce the data. The non-linear versus linear nature of these two models can lead to significant differences in vibrational energy coupling. Use of the contemporary model may lead to significant misconceptions, especially when integrated in computer codes considering multiple energy coupling mechanisms.

  11. Kinetic energy decomposition scheme based on information theory.

    PubMed

    Imamura, Yutaka; Suzuki, Jun; Nakai, Hiromi

    2013-12-15

    We proposed a novel kinetic energy decomposition analysis based on information theory. Since the Hirshfeld partitioning for electron densities can be formulated in terms of Kullback-Leibler information deficiency in information theory, a similar partitioning for kinetic energy densities was newly proposed. The numerical assessments confirm that the current kinetic energy decomposition scheme provides reasonable chemical pictures for ionic and covalent molecules, and can also estimate atomic energies using a correction with viral ratios.

  12. Systems engineering analysis of kinetic energy weapon concepts

    SciTech Connect

    Senglaub, M.

    1996-06-01

    This study examines, from a systems engineering design perspective, the potential of kinetic energy weapons being used in the role of a conventional strategic weapon. Within the Department of Energy (DOE) complex, strategic weapon experience falls predominantly in the nuclear weapons arena. The techniques developed over the years may not be the most suitable methodologies for use in a new design/development arena. For this reason a more fundamental approach was pursued with the objective of developing an information base from which design decisions might be made concerning the conventional strategic weapon system concepts. The study examined (1) a number of generic missions, (2) the effects of a number of damage mechanisms from a physics perspective, (3) measures of effectiveness (MOE`s), and (4) a design envelope for kinetic energy weapon concepts. With the base of information a cut at developing a set of high-level system requirements was made, and a number of concepts were assessed against these requirements.

  13. A Suggested Resource Unit on the Kinetic Theory of Gases and Associated Heat Energy Theory for the Use of Junior High School Teachers.

    ERIC Educational Resources Information Center

    Hansen, John R.

    The intent of this investigation was to design a resource unit to be used by junior high school science teachers to teach the concept of the kinetic theory of gases. The document was prepared to aid teachers with minimal preparation in physics. The research design consisted of three main subproblems: (1) the identification of the subtopics of the…

  14. Nontargeted Stressful Effects in Normal Human Fibroblast Cultures Exposed to Low Fluences of High Charge, High Energy (HZE) Particles: Kinetics of Biologic Responses and Significance of Secondary Radiations

    PubMed Central

    Gonon, Géraldine; Groetz, Jean-Emmanuel; de Toledo, Sonia M.; Howell, Roger W.; Fromm, Michel; Azzam, Edouard I.

    2014-01-01

    The induction of nontargeted stressful effects in cell populations exposed to low fluences of high charge (Z) and high energy (E) particles is relevant to estimates of the health risks of space radiation. We investigated the up-regulation of stress markers in confluent normal human fibroblast cultures exposed to 1,000 MeV/u iron ions [linear energy transfer (LET) ~151 keV/μm] or 600 MeV/u silicon ions (LET ~50 keV/μm) at mean absorbed doses as low as 0.2 cGy, wherein 1–3% of the cells were targeted through the nucleus by a primary particle. Within 24 h postirradiation, significant increases in the levels of phospho-TP53 (serine 15), p21Waf1 (CDKN1A), HDM2, phospho-ERK1/2, protein carbonylation and lipid peroxidation were detected, which suggested participation in the stress response of cells not targeted by primary particles. This was supported by in situ studies that indicated greater increases in 53BP1 foci formation, a marker of DNA damage. than expected from the number of primary particle traversals. The effect was expressed as early as 15 min after exposure, peaked at 1 h and decreased by 24 h. A similar tendency occurred after exposure of the cell cultures to 0.2 cGy of 3.7 MeV α particles (LET ~109 keV/μm) that targets ~1.6% of nuclei, but not after 0.2 cGy from 290 MeV/u carbon ions (LET ~13 keV/μm) by which, on average, ~13% of the nuclei were hit, which highlights the importance of radiation quality in the induced effect. Simulations with the FLUKA multi-particle transport code revealed that fragmentation products, other than electrons, in cell cultures exposed to HZE particles comprise <1% of the absorbed dose. Further, the radial spread of dose due to secondary heavy ion fragments is confined to approximately 10–20 μm. Thus, the latter are unlikely to significantly contribute to stressful effects in cells not targeted by primary HZE particles. PMID:23465079

  15. Reaction wheels for kinetic energy storage

    NASA Technical Reports Server (NTRS)

    Studer, P. A.

    1984-01-01

    In contrast to all existing reaction wheel implementations, an order of magnitude increase in speed can be obtained efficiently if power to the actuators can be recovered. This allows a combined attitude control-energy storage system to be developed with structure mounted reaction wheels. The feasibility of combining reaction wheels with energy storage wwheels is demonstrated. The power required for control torques is a function of wheel speed but this energy is not dissipated; it is stored in the wheel. The I(2)R loss resulting from a given torque is shown to be constant, independent of the design speed of the motor. What remains, in order to efficiently use high speed wheels (essential for energy storage) for control purposes, is to reduce rotational losses to acceptable levels. Progress was made in permanent magnet motor design for high speed operation. Variable field motors offer more control flexibility and efficiency over a broader speed range.

  16. The Kinetic Energy of a Rotating Figure Skater.

    ERIC Educational Resources Information Center

    Chen, Wei R.; Troelstra, Arne A.

    1998-01-01

    When a rotating figure skater's fully extended arms are pulled back toward the torso, the angular velocity is noticeably increased and the kinetic energy of the skater can also be shown to increase. Discusses the change of the kinetic energy during such a process, and the work necessary for such an increase is derived using a dynamic equilibrium…

  17. Kinetic energy budgets in areas of intense convection

    NASA Technical Reports Server (NTRS)

    Fuelberg, H. E.; Berecek, E. M.; Ebel, D. M.; Jedlovec, G. J.

    1980-01-01

    A kinetic energy budget analysis of the AVE-SESAME 1 period which coincided with the deadly Red River Valley tornado outbreak is presented. Horizontal flux convergence was found to be the major kinetic energy source to the region, while cross contour destruction was the major sink. Kinetic energy transformations were dominated by processes related to strong jet intrusion into the severe storm area. A kinetic energy budget of the AVE 6 period also is presented. The effects of inherent rawinsonde data errors on widely used basic kinematic parameters, including velocity divergence, vorticity advection, and kinematic vertical motion are described. In addition, an error analysis was performed in terms of the kinetic energy budget equation. Results obtained from downward integration of the continuity equation to obtain kinematic values of vertical motion are described. This alternate procedure shows promising results in severe storm situations.

  18. Zero kinetic energy photoelectron spectroscopy of pyrene.

    PubMed

    Zhang, Jie; Han, Fangyuan; Kong, Wei

    2010-10-28

    We report zero kinetic energy photoelectron (ZEKE) spectroscopy of pyrene via resonantly enhanced multiphoton ionization. Our analysis centers on the symmetry of the first electronically excited state (S(1)), its vibrational modes, and the vibration of the ground cationic state (D(0)). From comparisons between the observed vibrational frequencies and those from ab initio calculations at the configuration interaction singles level using the 6-311G (d,p) basis set, and based on other previous experimental and theoretical reports, we confirm the (1)B(2u) symmetry for the S(1) state. This assignment represents a reversal in the energy order of the two closely spaced electronically excited states from our theoretical calculation, and extensive configuration interactions are attributed to this result. Among the observed vibrational levels of the S(1) state, three are results of vibronic coupling due to the nearby second electronically excited state. The ZEKE spectroscopy obtained via the vibronic levels of the S(1) state reveals similar modes for the cation as those of the intermediate state. Although we believe that the ground ionic state can be considered a single electron configuration, the agreement between theoretical and experimental frequencies for the cation is limited. This result is somewhat surprising based on our previous work on cata-condensed polycyclic aromatic hydrocarbons and small substituted aromatic compounds. Although a relatively small molecule, pyrene demonstrates its nonrigidity via several out-of-plane bending modes corresponding to corrugation of the molecular plane. The adiabatic ionization potential of neutral pyrene is determined to be 59 888 ± 7 cm(-1).

  19. Decay and Spatial Diffusion of Turbulent Kinetic Energy In The Presence of a Linear Kinetic Energy Gradient

    NASA Astrophysics Data System (ADS)

    Meneveau, Charles

    2015-11-01

    A topic that elicited the interest of John Lumley is pressure transport in turbulence. In 1978 (JL, in Advances in Applied Mechanics, pages 123-176) he showed that pressure transport likely acts in the opposite direction to the spatial flux of kinetic energy due to triple velocity correlations. Here we examine a flow in which the interplay of turbulent decay and spatial transport is particularly relevant. Specifically, using a specially designed active grid and screens placed in the Corrsin wind tunnel, such a flow is realized. Data are acquired using X-wire thermal anemometry at different spanwise and downstream locations. In order to resolve the dissipation rate accurately, measurements are also acquired using the NSTAP probe developed and manufactured by Princeton researchers and kindly provided to us (M. Hultmark, Y. Fan, L. Smits). The results show power-law decay with downstream distance, with a decay exponent that becomes larger in the high kinetic energy side of the flow. Measurements of the dissipation enable us to obtain the spanwise gradient of the spatial flux. One possible explanation for the observations is upgrading transport of kinetic energy due to pressure-velocity correlations, although its magnitude required to close the budget appears very large. Absence of simultaneous pressure velocity measurement preclude us to fully elucidate the observed trends. In collaboration with Adrien Thormann, Johns Hopkins University. Financial support: National Science Foundation.

  20. Feynman and the kinetic energy of an ice skater

    NASA Astrophysics Data System (ADS)

    Pérez, José-Philippe

    2016-01-01

    By employing the angular momentum and mechanical energy theorems, we analyse the increase of the angular velocity for an ice skater who changes his arms, initially in an horizontal position, along the axis of the body, first with respect to the lab frame, in which a variation of kinetic energy is observed, and then with respect to the rotating frame moving with the skater. In the last one, while there is no variation of kinetic energy between initial and final positions, the work of the centrifugal force is the opposite to the variation of kinetic energy in the lab frame. We discuss the explanation given by Richard Feynman in his Mechanics course.

  1. HIGH PRESSURE COAL COMBUSTON KINETICS PROJECT

    SciTech Connect

    Stefano Orsino

    2005-03-30

    As part of the U.S. Department of Energy (DoE) initiative to improve the efficiency of coal-fired power plants and reduce the pollution generated by these facilities, DOE has funded the High-Pressure Coal Combustion Kinetics (HPCCK) Projects. A series of laboratory experiments were conducted on selected pulverized coals at elevated pressures with the specific goals to provide new data for pressurized coal combustion that will help extend to high pressure and validate models for burnout, pollutant formation, and generate samples of solid combustion products for analyses to fill crucial gaps in knowledge of char morphology and fly ash formation. Two series of high-pressure coal combustion experiments were performed using SRI's pressurized radiant coal flow reactor. The first series of tests characterized the near burner flame zone (NBFZ). Three coals were tested, two high volatile bituminous (Pittsburgh No.8 and Illinois No.6), and one sub-bituminous (Powder River Basin), at pressures of 1, 2, and 3 MPa (10, 20, and 30 atm). The second series of experiments, which covered high-pressure burnout (HPBO) conditions, utilized a range of substantially longer combustion residence times to produce char burnout levels from 50% to 100%. The same three coals were tested at 1, 2, and 3 MPa, as well as at 0.2 MPa. Tests were also conducted on Pittsburgh No.8 coal in CO2 entrainment gas at 0.2, 1, and 2 MPa to begin establishing a database of experiments relevant to carbon sequestration techniques. The HPBO test series included use of an impactor-type particle sampler to measure the particle size distribution of fly ash produced under complete burnout conditions. The collected data have been interpreted with the help of CFD and detailed kinetics simulation to extend and validate devolatilization, char combustion and pollutant model at elevated pressure. A global NOX production sub-model has been proposed. The submodel reproduces the performance of the detailed chemical reaction

  2. Zero kinetic energy photoelectron spectroscopy of triphenylene

    SciTech Connect

    Harthcock, Colin; Zhang, Jie; Kong, Wei

    2014-06-28

    We report vibrational information of both the first electronically excited state and the ground cationic state of jet-cooled triphenylene via the techniques of resonantly enhanced multiphoton ionization (REMPI) and zero kinetic energy (ZEKE) photoelectron spectroscopy. The first excited electronic state S{sub 1} of the neutral molecule is of A{sub 1}′ symmetry and is therefore electric dipole forbidden in the D{sub 3h} group. Consequently, there are no observable Franck-Condon allowed totally symmetric a{sub 1}′ vibrational bands in the REMPI spectrum. All observed vibrational transitions are due to Herzberg-Teller vibronic coupling to the E′ third electronically excited state S{sub 3}. The assignment of all vibrational bands as e′ symmetry is based on comparisons with calculations using the time dependent density functional theory and spectroscopic simulations. When an electron is eliminated, the molecular frame undergoes Jahn-Teller distortion, lowering the point group to C{sub 2v} and resulting in two nearly degenerate electronic states of A{sub 2} and B{sub 1} symmetry. Here we follow a crude treatment by assuming that all e′ vibrational modes resolve into b{sub 2} and a{sub 1} modes in the C{sub 2v} molecular frame. Some observed ZEKE transitions are tentatively assigned, and the adiabatic ionization threshold is determined to be 63 365 ± 7 cm{sup −1}. The observed ZEKE spectra contain a consistent pattern, with a cluster of transitions centered near the same vibrational level of the cation as that of the intermediate state, roughly consistent with the propensity rule. However, complete assignment of the detailed vibrational structure due to Jahn-Teller coupling requires much more extensive calculations, which will be performed in the future.

  3. Zero kinetic energy photoelectron spectroscopy of triphenylene

    NASA Astrophysics Data System (ADS)

    Harthcock, Colin; Zhang, Jie; Kong, Wei

    2014-06-01

    We report vibrational information of both the first electronically excited state and the ground cationic state of jet-cooled triphenylene via the techniques of resonantly enhanced multiphoton ionization (REMPI) and zero kinetic energy (ZEKE) photoelectron spectroscopy. The first excited electronic state S1 of the neutral molecule is of A1' symmetry and is therefore electric dipole forbidden in the D3h group. Consequently, there are no observable Franck-Condon allowed totally symmetric a1' vibrational bands in the REMPI spectrum. All observed vibrational transitions are due to Herzberg-Teller vibronic coupling to the E' third electronically excited state S3. The assignment of all vibrational bands as e' symmetry is based on comparisons with calculations using the time dependent density functional theory and spectroscopic simulations. When an electron is eliminated, the molecular frame undergoes Jahn-Teller distortion, lowering the point group to C2v and resulting in two nearly degenerate electronic states of A2 and B1 symmetry. Here we follow a crude treatment by assuming that all e' vibrational modes resolve into b2 and a1 modes in the C2v molecular frame. Some observed ZEKE transitions are tentatively assigned, and the adiabatic ionization threshold is determined to be 63 365 ± 7 cm-1. The observed ZEKE spectra contain a consistent pattern, with a cluster of transitions centered near the same vibrational level of the cation as that of the intermediate state, roughly consistent with the propensity rule. However, complete assignment of the detailed vibrational structure due to Jahn-Teller coupling requires much more extensive calculations, which will be performed in the future.

  4. Zero kinetic energy photoelectron spectroscopy of triphenylene.

    PubMed

    Harthcock, Colin; Zhang, Jie; Kong, Wei

    2014-06-28

    We report vibrational information of both the first electronically excited state and the ground cationic state of jet-cooled triphenylene via the techniques of resonantly enhanced multiphoton ionization (REMPI) and zero kinetic energy (ZEKE) photoelectron spectroscopy. The first excited electronic state S1 of the neutral molecule is of A1' symmetry and is therefore electric dipole forbidden in the D3h group. Consequently, there are no observable Franck-Condon allowed totally symmetric a1' vibrational bands in the REMPI spectrum. All observed vibrational transitions are due to Herzberg-Teller vibronic coupling to the E' third electronically excited state S3. The assignment of all vibrational bands as e' symmetry is based on comparisons with calculations using the time dependent density functional theory and spectroscopic simulations. When an electron is eliminated, the molecular frame undergoes Jahn-Teller distortion, lowering the point group to C2v and resulting in two nearly degenerate electronic states of A2 and B1 symmetry. Here we follow a crude treatment by assuming that all e' vibrational modes resolve into b2 and a1 modes in the C2v molecular frame. Some observed ZEKE transitions are tentatively assigned, and the adiabatic ionization threshold is determined to be 63 365 ± 7 cm(-1). The observed ZEKE spectra contain a consistent pattern, with a cluster of transitions centered near the same vibrational level of the cation as that of the intermediate state, roughly consistent with the propensity rule. However, complete assignment of the detailed vibrational structure due to Jahn-Teller coupling requires much more extensive calculations, which will be performed in the future.

  5. A Detailed Level Kinetics Model of NO Vibrational Energy Distributions

    NASA Technical Reports Server (NTRS)

    Sharma, Surendra P.; Gilmore, John; Cavolowsky, John A. (Technical Monitor)

    1996-01-01

    Several contemporary problems have pointed to the desirability of a detailed level kinetics approach to modeling the distribution of vibrational energy in NO. Such a model is necessary when vibrational redistribution reactions are insufficient to maintain a Boltzmann distribution over the vibrational energy states. Recent calculations of the rate constant for the first reaction of the Zeldovich mechanism (N2 + O (goes to) NO + N) have suggested that the product NO is formed in high vibrational states. In shock layer flowfields, the product NO molecules may experience an insufficient number of collisions to establish a Boltzmann distribution over vibrational states, thus necessitating a level kinetics model. In other flows, such as expansions of high temperature air, fast, near-resonance vibrational energy exchanges with N2 and O2 may also require a level specific model for NO because of the relative rates of vibrational exchange and redistribution. The proposed report will integrate computational and experimental components to construct such a model for the NO molecule.

  6. Sulfidation kinetics of dolomite at high pressure and high temperature

    SciTech Connect

    Misro, S.K.; Jadhav, R.; Gupta, H.; Agnihotri, R.; Chauk, S.; Fan, L.S.

    1999-07-01

    Kinetic studies of the dolomite sulfidation reaction are carried out at high pressure (15 atm) and high temperature (600--900 C) in a differential bed flow-through reactor. The dolomite particles are exposed to simulated coal gas environments and the extent of conversion determined. Experiments are carried out to determine the influence of total pressure, reaction temperature and partial pressure of H{sub 2}S on the extent of fully calcined dolomite (FCD) sulfidation. Based on the grain theory it is found that towards the later stages of the reaction the FCD sulfidation is product layer diffusion controlled. The reaction is found to be first order with respect to H{sub 2}S partial pressure. A low apparent activation energy of 4.6 kcal/gmol for the product layer diffusion controlled reaction is attributed to the presence of porous MgO along with the low porosity CaS product layer. A comparison of the performance of dolomite and limestone as sorbents for desulfurization shows that dolomite is a better sorbent with higher conversions even at higher CO{sub 2} partial pressures. The high pressure sulfidation kinetic data obtained in this study would be useful in understanding and optimizing the in-gasifier H{sub 2}S capture using dolomite sorbents.

  7. Nowcasting of kinetic energy of hail precipitation using radar

    NASA Astrophysics Data System (ADS)

    Sánchez, J. L.; López, L.; García-Ortega, E.; Gil, B.

    2013-04-01

    The detection of hail precipitation generated by a storm is a complicated task due to the limited spatial extension and the space-time irregularity of impacts generated on the ground. Some of the most extensive methods to create climatology of these impacts are observer networks or hailpad networks. Both methods are affected by numerous inconveniences, overall when it is necessary to work with an extensive area, in which it is necessary to maintain an operating network that has numerous maintenance costs. In this sense, there are numerous works done that have developed different models with the objective of detecting hail precipitation using meteorological radar. Some of these methods use discriminant statistic techniques that, through the combination of different radar parameters, can achieve very satisfactory results. On the other hand, it would be very interesting to know not only the probability of hail, but also some of the characteristics of the hailstones precipitated, such as the number or their kinetic energy, since these parameters are directly related to the damage generated in infrastructures and/or crops. The estimation of kinetic energy of hail precipitation using meteorological radar has caught the interest of some authors. In our case, we used the databases obtained by hailpad networks and the databases of C-band and S-Band radar to build an algorithm to estimate the vertical component of kinetic energy produced by a hail precipitation. In order to carry out this study, data on hail was gathered and analyzed from the hailpad networks in the province of Zaragoza (in the north-east of Spain) and the province of Mendoza (in Argentina, close to the Andes range on the border with Chile). These are two geographically distant regions, but which share a common characteristic: a high frequency of storms with hail precipitation, mainly during the summer months (Sánchez et al., 2009a). In order to compile the database, we have established two categories of

  8. Spectral kinetic energy transfer in turbulent premixed reacting flows.

    PubMed

    Towery, C A Z; Poludnenko, A Y; Urzay, J; O'Brien, J; Ihme, M; Hamlington, P E

    2016-05-01

    Spectral kinetic energy transfer by advective processes in turbulent premixed reacting flows is examined using data from a direct numerical simulation of a statistically planar turbulent premixed flame. Two-dimensional turbulence kinetic-energy spectra conditioned on the planar-averaged reactant mass fraction are computed through the flame brush and variations in the spectra are connected to terms in the spectral kinetic energy transport equation. Conditional kinetic energy spectra show that turbulent small-scale motions are suppressed in the burnt combustion products, while the energy content of the mean flow increases. An analysis of spectral kinetic energy transfer further indicates that, contrary to the net down-scale transfer of energy found in the unburnt reactants, advective processes transfer energy from small to large scales in the flame brush close to the products. Triadic interactions calculated through the flame brush show that this net up-scale transfer of energy occurs primarily at spatial scales near the laminar flame thermal width. The present results thus indicate that advective processes in premixed reacting flows contribute to energy backscatter near the scale of the flame.

  9. Kinetic Energy Principle And Neoclassical Toroidal Torque In Tokamaks

    SciTech Connect

    Jong-Kyu Park

    2011-11-07

    It is shown that when tokamaks are perturbed the kinetic energy principle is closely related to the neoclassical toroidal torque by the action invariance of particles. Especially when tokamaks are perturbed from scalar pressure equilibria, the imaginary part of the potential energy in the kinetic energy principle is equivalent to the toroidal torque by the Neoclassical Toroidal Viscosity (NTV). A unified description therefore should be made for both physics. It is also shown in this case that the potential energy operator can be self-adjoint and thus the stability calculation can be simplified by minimizing the potential energy

  10. On the Linearly-Balanced Kinetic Energy Spectrum

    NASA Technical Reports Server (NTRS)

    Lu, Huei,-Iin; Robertson, F. R.

    1999-01-01

    It is well known that the earth's atmospheric motion can generally be characterized by the two dimensional quasi-geostrophic approximation, in which the constraints on global integrals of kinetic energy, entrophy and potential vorticity play very important roles in redistributing the wave energy among different scales of motion. Assuming the hypothesis of Kolmogrov's local isotropy, derived a -3 power law of the equilibrium two-dimensional kinetic energy spectrum that entails constant vorticity and zero energy flows from the energy-containing wave number up to the viscous cutoff. In his three dimensional quasi-geostrophic theory, showed that the spectrum function of the vertical scale turbulence - expressible in terms of the available potential energy - possesses the same power law as the two dimensional kinetic energy spectrum. As the slope of kinetic energy spectrum in the inertial range is theoretically related to the predictability of the synoptic scales (Lorenz, 1969), many general circulation models includes a horizontal diffusion to provide reasonable kinetic energy spectra, although the actual power law exhibited in the atmospheric general circulation is controversial. Note that in either the atmospheric modeling or the observational analyses, the proper choice of wave number Index to represent the turbulence scale Is the degree of the Legendre polynomial.

  11. Rainfall kinetic energy-intensity and rainfall momentum-intensity relationships for Cape Verde

    NASA Astrophysics Data System (ADS)

    Sanchez-Moreno, Juan Francisco; Mannaerts, Chris M.; Jetten, Victor; Löffler-Mang, Martin

    2012-08-01

    Momentum and kinetic energy of rainfall are widely used indices to describe erosivity, the ability of rainfall to detach soil particles and erode the landscape. An optical laser disdrometer was installed in Santiago Island, Cape Verde, between September 2008 and September 2010 to measure rainfall intensity and size distribution of raindrops. A total time series of 5129 observations of radar reflectivity, visibility, rainfall intensity and number of particles were gathered. Rainfall kinetic energy expenditure KEtime (J m-2 h-1), kinetic energy content KEmm (J m-2 mm-1) and momentum flux MtA (kg m s-1 m-2 s-1) were calculated and fitted to different known experimental equations. The best fit between rainfall intensity and kinetic energy expenditure, kinetic energy content and momentum were obtained with power-law equations. These equations were validated in two independent events corresponding to 2008 and 2009, producing high correlation coefficients. The results show that for Cape Verde, KEtime is a more appropriate index to relate with rainfall intensity, and that kinetic energy expenditure and momentum flux are interchangeable parameters for erosivity estimation. New relationships relating kinetic energy and rainfall intensity, and momentum and rainfall intensity were derived, which contribute to the characterization of rainfall originating from tropical depressions at lower latitudes.

  12. Kinetic equilibria of very high- β plasmas

    NASA Astrophysics Data System (ADS)

    Steinhauer, Loren; TAE Team

    2015-11-01

    Plasma equilibria with many large ion orbits, such as an advanced beam-driven field-reversed configuration, are neither static (Grad-Shafranov) nor describable as a flowing, multi-fluid. A fully-kinetic treatment of the ions is essential for such high- β plasmas. A kinetic equilibrium is needed to properly support realistic stability and transport analyses, both of which are strongly affected by large-orbit ions. A hybrid equilibrium model has been developed with a fully-kinetic treatment of both thermal ions and a rapidly-rotating ``beam-ion'' component, such as produced by neutral beam injection, relevant to the C-2U experiments at TAE. It employs analytic Vlasov solutions in that the distribution depends only on the two constants of motion, the Hamiltonian (H) and the canonical angular momentum (Pθ) . Electrons are treated as a pressure-bearing fluid. Since realistic forms of f (H ,Pθ) are affected by collisions, f is limited to solutions of a simplified Fokker-Planck equation. Importantly, a kinetic end-loss condition applies to unconfined ions, using a particle sink at a rate consistent with Monte-Carlo-like simulations of end loss accounting for a strong end mirror.

  13. Analysis of flow cytometry DNA damage response protein activation kinetics after exposure to x rays and high-energy iron nuclei.

    PubMed

    Chappell, Lori J; Whalen, Mary K; Gurai, Sheena; Ponomarev, Artem; Cucinotta, Francis A; Pluth, Janice M

    2010-12-01

    We developed a mathematical method to analyze flow cytometry data to describe the kinetics of γ-H2AX and pATF2 phosphorylation in normal human fibroblast cells after exposure to various qualities of low-dose radiation. Previously reported flow cytometry kinetics for these DSB repair phospho-proteins revealed that distributions of intensity were highly skewed, severely limiting the detection of differences in the very low-dose range. Distributional analysis revealed significant differences between control and low-dose samples when distributions were compared using the Kolmogorov-Smirnov test. Differences in radiation quality were found in the distribution shapes and when a nonlinear model was used to relate dose and time to the decay of the mean ratio of phospho-protein intensities of irradiated samples to controls. We analyzed cell cycle phase- and radiation quality-dependent characteristic repair times and residual phospho-protein levels with these methods. Characteristic repair times for γ-H2AX were higher after exposure to iron nuclei compared to X rays in G(1) cells and in S/G(2) cells. The RBE in G(1) cells for iron nuclei relative to X rays for γ-H2AX was 2.1 ± 0.6 and 5.0 ± 3.5 at 2 and 24 h after irradiation, respectively. For pATF2, a saturation effect was observed with reduced expression at high doses, especially for iron nuclei, with much slower characteristic repair times (>7 h) compared to X rays. RBEs for pATF2 were 0.7 ± 0.1 and 1.7 ± 0.5 at 2 and 24 h, respectively. Significant differences in γ-H2AX and pATF2 levels when irradiated samples were compared to controls were noted even at the lowest dose analyzed (0.05 Gy). These results show that mathematical models can be applied to flow cytometry data to identify important and subtle differences after exposure to various qualities of low-dose radiation.

  14. Transition of energy transfer from MHD turbulence to kinetic plasma

    NASA Astrophysics Data System (ADS)

    Yang, Yan; Matthaeus, William; Parashar, Tulasi; Shi, Yipeng; Wan, Minping; Chen, Shiyi

    2016-11-01

    The classical energy cascade scenario is of great importance in explaining the heating of corona and solar wind. One can envision that energy residing in large-scale fluctuations is transported to smaller scales where dissipation occurs and finally drives kinetic processes that absorb the energy flux and energize charged particles. Here we inquire how the cascade operates in a compressible plasma, and how the characteristics of energy transfer vary going from MHD to kinetic scales. When filtering MHD equations, we can get an apparent inertial range over which the conservative energy cascade occurs and the scale locality of energy transfer is similar to the cases of incompressible MHD turbulence. Pervasive shocks not only make a significant difference on energy cascade and magnetic amplification, but can also introduce considerable pressure dilation, a complement of viscous and ohmic dissipation that can trigger an alternative channel of the conversion between kinetic and internal energy. The procedure can also be applied to the Vlasov equation and kinetic simulation, in comparison with MHD turbulence, and is a good candidate to investigate the energy cascade process and the analogous role of the (tensor) pressure dilation in collisionless plasma.

  15. Energy scavenging strain absorber: application to kinetic dielectric elastomer generator

    NASA Astrophysics Data System (ADS)

    Jean-Mistral, C.; Beaune, M.; Vu-Cong, T.; Sylvestre, A.

    2014-03-01

    Dielectric elastomer generators (DEGs) are light, compliant, silent energy scavengers. They can easily be incorporated into clothing where they could scavenge energy from the human kinetic movements for biomedical applications. Nevertheless, scavengers based on dielectric elastomers are soft electrostatic generators requiring a high voltage source to polarize them and high external strain, which constitutes the two major disadvantages of these transducers. We propose here a complete structure made up of a strain absorber, a DEG and a simple electronic power circuit. This new structure looks like a patch, can be attached on human's wear and located on the chest, knee, elbow… Our original strain absorber, inspired from a sailing boat winch, is able to heighten the external available strain with a minimal factor of 2. The DEG is made of silicone Danfoss Polypower and it has a total area of 6cm per 2.5cm sustaining a maximal strain of 50% at 1Hz. A complete electromechanical analytical model was developed for the DEG associated to this strain absorber. With a poling voltage of 800V, a scavenged energy of 0.57mJ per cycle is achieved with our complete structure. The performance of the DEG can further be improved by enhancing the imposed strain, by designing a stack structure, by using a dielectric elastomer with high dielectric permittivity.

  16. Renormalizing the Kinetic Energy Operator in Elementary Quantum Mechanics

    ERIC Educational Resources Information Center

    Coutinho, F. A. B.; Amaku, M.

    2009-01-01

    In this paper, we consider solutions to the three-dimensional Schrodinger equation of the form [psi](r) = u(r)/r, where u(0) [is not equal to] 0. The expectation value of the kinetic energy operator for such wavefunctions diverges. We show that it is possible to introduce a potential energy with an expectation value that also diverges, exactly…

  17. High energy neutron radiography

    SciTech Connect

    Gavron, A.; Morley, K.; Morris, C.; Seestrom, S.; Ullmann, J.; Yates, G.; Zumbro, J.

    1996-06-01

    High-energy spallation neutron sources are now being considered in the US and elsewhere as a replacement for neutron beams produced by reactors. High-energy and high intensity neutron beams, produced by unmoderated spallation sources, open potential new vistas of neutron radiography. The authors discuss the basic advantages and disadvantages of high-energy neutron radiography, and consider some experimental results obtained at the Weapons Neutron Research (WNR) facility at Los Alamos.

  18. Kinetic Energy Corrections for Slip-Stick Behavior in Brittle Adhesives

    NASA Technical Reports Server (NTRS)

    Macon, David J.; Anderson, Greg L.; McCool, Alex (Technical Monitor)

    2001-01-01

    Fracture mechanics is the study of the failure of a body that contains a flaw. In the energy balance approach to fracture mechanics, contributions from the external work and elastic strain energy are accounted for but rarely are corrections for the kinetic energy given. Under slip-stick conditions, part of the external work is expended as kinetic energy. The magnitude of this kinetic energy depends upon the shape of the crack. A specimen with a blunt crack will fail at a high load and the crack will catastrophically travel through the material until the kinetic energy is dissipated. Material with a sharp crack will fail at a lower load but will still be catastrophic in nature. A kinetic term is incorporated into the energy balance approach. This term accounts for the velocity of the crack after failure and how far the crack travels before arresting. This correction makes the shape of the initiation crack irrelevant. When applied to data generated by tapered double cantilever beam specimens under slip-stick conditions, the scatter in the measured critical strain energy release rate is significantly reduced.

  19. Nucleation and growth kinetics of biochemicals measured at high supersaturations

    NASA Astrophysics Data System (ADS)

    Mahajan, Amarjit J.; Kirwan, Donald J.

    1994-12-01

    A grid mixer device (characteristic micromixing time < 3 ms) was successfully used to measure both nucleation and growth kinetics of lovastatin in 60 vol% methanol and asparagine monohydrate in 50 vol% 2-propanol at 23°C at high supersaturations but in the absence of mixing limitations. The supersaturation ratios investigated were in the range 1.25-8.8 for the lovastatin system and 1.17-4.1 for the asparagine system. When plotted according to primary nucleation theory, the induction time and nucleation rate measurements for both systems exhibited a homogeneous nucleation region at high supersaturations and a heterogeneous nucleation region at low supersaturations. The values of interfacial free energy extracted from these measurements for lovastatin (1.4-1.6 mJ/m 2) and asparagine (4.5-6.1 mJ/m 2) were an order-of-magnitude lower than those for inorganic salts reflecting the weaker intermolecular bonding in such biochemical solutes. The measured crystal growth rates for both solutes over the entire range of supersaturation could be represented with a power law dependence on chemical potential driving force. The kinetic orders of crystal growth were found to be 6.7 and 2.9 for lovastatin and asparagine, respectively. These unusually high kinetic orders could be represented by a polynuclear surface nucleation growth mechanism. The activation energy for the growth of lovastatin was measured as 280 kJ/mol.

  20. Energy landscapes, folding mechanisms, and kinetics of RNA tetraloop hairpins.

    PubMed

    Chakraborty, Debayan; Collepardo-Guevara, Rosana; Wales, David J

    2014-12-31

    RNA hairpins play a pivotal role in a diverse range of cellular functions, and are integral components of ribozymes, mRNA, and riboswitches. However, the mechanistic and kinetic details of RNA hairpin folding, which are key determinants of most of its biological functions, are poorly understood. In this work, we use the discrete path sampling (DPS) approach to explore the energy landscapes of two RNA tetraloop hairpins, and provide insights into their folding mechanisms and kinetics in atomistic detail. Our results show that the potential energy landscapes have a distinct funnel-like bias toward the folded hairpin state, consistent with efficient structure-seeking properties. Mechanistic and kinetic information is analyzed in terms of kinetic transition networks. We find microsecond folding times, consistent with temperature jump experiments, for hairpin folding initiated from relatively compact unfolded states. This process is essentially driven by an initial collapse, followed by rapid zippering of the helix stem in the final phase. Much lower folding rates are predicted when the folding is initiated from extended chains, which undergo longer excursions on the energy landscape before nucleation events can occur. Our work therefore explains recent experiments and coarse-grained simulations, where the folding kinetics exhibit precisely this dependency on the initial conditions.

  1. The role of mesoscale kinetic energy in natural occurring phytoplankton blooms and export in Drake Passage.

    NASA Astrophysics Data System (ADS)

    Davies, A. R.; Veron, F.; Oliver, M. J.

    2014-12-01

    The Southern Ocean is an iron limited, high nitrate, low chlorophyll region that draws considerable attention as a potential site for carbon drawdown through iron fertilization. However, there are no prolonged in-situ observations of the mechanisms driving naturally occurring blooms in this region. Here we present results from an APEX biofloat that continuously profiled the Drake Passage from ~ 2,000 m to the surface every two days. The biofloat measured the development and export of a naturally occurring phytoplankton bloom in the Drake Passage. Our analysis indicates that low levels of mesoscale kinetic energy coincided with the observed phytoplankton bloom. We postulate that low KE level are a precondition for bloom onset in the Drake Passage, which is confirmed by satellite observations. High levels of mesoscale kinetic energy immediately followed the phytoplankton bloom and appear to have facilitated organic carbon export to the deep ocean by changing the neutral density depths of aggregated cells. Furthermore, satellite observations in Drake Passage suggest that high levels of mesoscale kinetic energy limit bloom formation. We suggest that low mesoscale kinetic energy is a precondition for bloom formation in the Drake Passage before other potentially limiting factors become significant (e.g. grazing relation, macronutrients, micronutrients). If mesoscale kinetic energy were to impose a limitation on phytoplankton concentrations across the entire Southern Ocean, there may be regions unsuitable for geoengineered draw down of atmospheric carbon dioxide through large scale iron additions.

  2. Momentum and Kinetic Energy: Confusable Concepts in Secondary School Physics

    ERIC Educational Resources Information Center

    Bryce, T. G. K.; MacMillan, K.

    2009-01-01

    Researchers and practitioners alike express concerns about the conceptual difficulties associated with the concepts of momentum and kinetic energy currently taught in school physics. This article presents an in-depth analysis of the treatment given to them in 44 published textbooks written for UK secondary school certificate courses. This is set…

  3. Mass, Momentum and Kinetic Energy of a Relativistic Particle

    ERIC Educational Resources Information Center

    Zanchini, Enzo

    2010-01-01

    A rigorous definition of mass in special relativity, proposed in a recent paper, is recalled and employed to obtain simple and rigorous deductions of the expressions of momentum and kinetic energy for a relativistic particle. The whole logical framework appears as the natural extension of the classical one. Only the first, second and third laws of…

  4. Unified Technical Concepts. Module 7: Potential and Kinetic Energy.

    ERIC Educational Resources Information Center

    Technical Education Research Center, Waco, TX.

    This concept module on potential and kinetic energy is one of thirteen modules that provide a flexible, laboratory-based physics instructional package designed to meet the specialized needs of students in two-year, postsecondary technical schools. Each of the thirteen concept modules discusses a single physics concept and how it is applied to each…

  5. On the theoretical limits of detecting cyclic changes in cardiac high-energy phosphates and creatine kinase reaction kinetics using in vivo ³¹P MRS.

    PubMed

    Weiss, Kilian; Bottomley, Paul A; Weiss, Robert G

    2015-06-01

    Adenosine triphosphate (ATP) is absolutely required to fuel normal cyclic contractions of the heart. The creatine kinase (CK) reaction is a major energy reserve reaction that rapidly converts creatine phosphate (PCr) to ATP during the cardiac cycle and at times of stress and ischemia, but is significantly impaired in conditions such as hypertrophy and heart failure. Because the magnitudes of possible in vivo cyclic changes in cardiac high-energy phosphates (HEPs) during the cardiac cycle are not well known from previous work, this study uses mathematical modeling to assess whether, and to what extent, cyclic variations in HEPs and in the rate of ATP synthesis through CK (CK flux) could exist in the human heart, and whether they could be measured with current in vivo (31)P MRS methods. Multi-site exchange models incorporating enzymatic rate equations were used to study the cyclic dynamics of the CK reaction, and Bloch equations were used to simulate (31)P MRS saturation transfer measurements of the CK reaction. The simulations show that short-term buffering of ATP by CK requires temporal variations over the cardiac cycle in the CK reaction velocities modeled by enzymatic rate equations. The maximum variation in HEPs in the normal human heart beating at 60 min(-1) was approximately 0.4 mM and proportional to the velocity of ATP hydrolysis. Such HEP variations are at or below the current limits of detection by in vivo (31)P MRS methods. Bloch equation simulations show that (31)P MRS saturation transfer estimates the time-averaged, pseudo-first-order forward rate constant, k(f,ap)', of the CK reaction, and that periodic short-term fluctuations in kf ' and CK flux are not likely to be detectable in human studies employing current in vivo (31)P MRS methods.

  6. Kinetic energy of rainfall an important driver of soil erosion - how reliable are our estimates?

    NASA Astrophysics Data System (ADS)

    Wilken, Florian; Sommer, Michael; Fiener, Peter

    2016-04-01

    The most important process initiating interrill erosion is the detachment of soil particles via splash processes. Splash erosion intensity is depending on soil and rainfall characteristics. Rainfall characteristics are essentially determined by the drop size and fall velocity, leading to a specific kinetic energy of rainfall. In consequence, the kinetic energy of rain events is often directly or indirectly included in erosion models to calculate splash erosion. Therefore, rainfall kinetic energy is commonly derived by empirical functions (e.g. RUSLE; Renard et al. 1997) from available rainfall intensity measurements. The aim of this study is to analyze the event type-specific uncertainties inherent in these empirical functions purely based on rainfall intensity measurements. Therefore, we compare rainfall energies calculated from rainfall intensities measured with a standard tipping bucket rain gauge to rainfall energy measurements taken by laser distrometers. These allow to calculate rainfall kinetic energy from a spectrum of measured drop sizes and fall velocities. The study was carried out in NE-Germany in a test area with an average annual precipitation of approximately 500 mm dominated by intense convective precipitation. We compare one year of data from two laser distrometers and two tipping buckets installed at two locations about 1 km apart. Our results show distinct differences for high intensity events between the measuring techniques. We found notably higher rainfall kinetic energy for high intensity events measured by the laser distrometer compared to the tipping bucked derived kinetic energy. This points to a measurement bias of high erosive rainfall events which would be of particular relevance for erosion studies.

  7. High-Throughput Enzyme Kinetics Using Microarrays

    SciTech Connect

    Guoxin Lu; Edward S. Yeung

    2007-11-01

    We report a microanalytical method to study enzyme kinetics. The technique involves immobilizing horseradish peroxidase on a poly-L-lysine (PLL)- coated glass slide in a microarray format, followed by applying substrate solution onto the enzyme microarray. Enzyme molecules are immobilized on the PLL-coated glass slide through electrostatic interactions, and no further modification of the enzyme or glass slide is needed. In situ detection of the products generated on the enzyme spots is made possible by monitoring the light intensity of each spot using a scientific-grade charged-coupled device (CCD). Reactions of substrate solutions of various types and concentrations can be carried out sequentially on one enzyme microarray. To account for the loss of enzyme from washing in between runs, a standard substrate solution is used for calibration. Substantially reduced amounts of substrate solution are consumed for each reaction on each enzyme spot. The Michaelis constant K{sub m} obtained by using this method is comparable to the result for homogeneous solutions. Absorbance detection allows universal monitoring, and no chemical modification of the substrate is needed. High-throughput studies of native enzyme kinetics for multiple enzymes are therefore possible in a simple, rapid, and low-cost manner.

  8. Detailed Kinetic Modeling of Processes Relevant To Fusion Energy

    NASA Astrophysics Data System (ADS)

    Mehl, Marco; Armstrong, Michael; Zaug, Joseph; Crowhurst, Jonathan; Radousky, Harry; Stavrou, Elissaios

    2016-10-01

    Carbon based materials have been proposed as candidates for the fabrication of plasma-facing components in the design of fusion energy devices. Although these components are not supposed to be in direct contact with the core fusion plasma, plasma instabilities and the harsh environment they are exposed to can cause the degradation of plasma-exposed components and the transfer of contaminants into the plasma followed by deposition of byproducts. In order to investigate the chemistry involved in these processes and to assist the development of models suitable to understand the long term consequences of the carbon ablation/deposition cycle, an inductively coupled plasma flow reactor (ICPFR) has been developed. The ICPFR allows the atomization of carbon containing precursors to high temperatures (in the order of 10000K) and the characterization of the gas and solid species formed downsteam from the plasma source through spectroscopic techniques. In parallel to the experimental analysis a comprehensive set of fluid dynamic and detailed kinetic simulations are used to analyze the data. The combination of these two approaches resulted in a validated and comprehensive chemical model for the formation of carbon deposits in carbon contaminated cooling plasmas. This work was performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under Contract DE-AC52-07NA27344.

  9. Estimates of meteoroid kinetic energies from observations of infrasonic airwaves

    NASA Astrophysics Data System (ADS)

    Edwards, Wayne N.; Brown, Peter G.; Revelle, Douglas O.

    2006-06-01

    Signal properties of the acoustic waves produced from meteoroids impacting the Earth's atmosphere in the approximate size range of 0.1 10 m diameter have been analyzed at infrasonic frequencies. From these data, we have produced a series of empirical relations between the far-field acoustic signature of the bolide shocks and meteor source energies by correlating infrasonic observations of those fireballs which are also detected by earth-observing satellites. Adopting a similar approach as has been previously employed for man-made explosives, signal properties such as acoustic amplitude, signal energy/power and signal-to-noise ratio, are shown, after high-altitude wind corrections, to be useful tools in estimating the kinetic energy of a bolide. Comparison of bolide infrasound data to ground-based explosive tests show that the acoustic amplitudes from airwaves generated by small bolide events (<7 kt TNT equivalent) attenuate more rapidly than nuclear or chemical explosions. As well, acoustic amplitude values for bolides are systematically lower than acoustic amplitudes measured for equivalent ground-based explosions. This is interpreted to be largely due to bolide acoustic sources being at high altitudes in the atmosphere. We find from our analysis that these heights are on average located between 20 and 30 km. Larger events (>7 kt) mimic man-made explosions in terms of range dependence, but offset in amplitude equivalent to ˜20 km source altitudes. This is consistent with instrumental observations of fireballs and the expectation that larger meteoroids (greater than a few meters in diameter), should penetrate deeper into the atmosphere on average. Applying these new relationships to historical events, we find that the August 3, 1963 bolide detected infrasonically near the Prince Edward Islands off the coast of South Africa, previously estimated to have an energy of 1100 kt, may have had a much smaller energy of 266±90 kt. This energy revision brings the

  10. Accurate spectral numerical schemes for kinetic equations with energy diffusion

    NASA Astrophysics Data System (ADS)

    Wilkening, Jon; Cerfon, Antoine J.; Landreman, Matt

    2015-08-01

    We examine the merits of using a family of polynomials that are orthogonal with respect to a non-classical weight function to discretize the speed variable in continuum kinetic calculations. We consider a model one-dimensional partial differential equation describing energy diffusion in velocity space due to Fokker-Planck collisions. This relatively simple case allows us to compare the results of the projected dynamics with an expensive but highly accurate spectral transform approach. It also allows us to integrate in time exactly, and to focus entirely on the effectiveness of the discretization of the speed variable. We show that for a fixed number of modes or grid points, the non-classical polynomials can be many orders of magnitude more accurate than classical Hermite polynomials or finite-difference solvers for kinetic equations in plasma physics. We provide a detailed analysis of the difference in behavior and accuracy of the two families of polynomials. For the non-classical polynomials, if the initial condition is not smooth at the origin when interpreted as a three-dimensional radial function, the exact solution leaves the polynomial subspace for a time, but returns (up to roundoff accuracy) to the same point evolved to by the projected dynamics in that time. By contrast, using classical polynomials, the exact solution differs significantly from the projected dynamics solution when it returns to the subspace. We also explore the connection between eigenfunctions of the projected evolution operator and (non-normalizable) eigenfunctions of the full evolution operator, as well as the effect of truncating the computational domain.

  11. Kinetic-energy density functional: Atoms and shell structure

    SciTech Connect

    Garcia-Gonzalez, P.; Alvarellos, J.E.; Chacon, E. |

    1996-09-01

    We present a nonlocal kinetic-energy functional which includes an anisotropic average of the density through a symmetrization procedure. This functional allows a better description of the nonlocal effects of the electron system. The main consequence of the symmetrization is the appearance of a clear shell structure in the atomic density profiles, obtained after the minimization of the total energy. Although previous results with some of the nonlocal kinetic functionals have given incipient structures for heavy atoms, only our functional shows a clear shell structure for most of the atoms. The atomic total energies have a good agreement with the exact calculations. Discussion of the chemical potential and the first ionization potential in atoms is included. The functional is also extended to spin-polarized systems. {copyright} {ital 1996 The American Physical Society.}

  12. Covalent bonding: the fundamental role of the kinetic energy.

    PubMed

    Bacskay, George B; Nordholm, Sture

    2013-08-22

    This work addresses the continuing disagreement between two prevalent schools of thought concerning the mechanism of covalent bonding. According to Hellmann, Ruedenberg, and Kutzelnigg, a lowering of the kinetic energy associated with electron delocalization is the key stabilization mechanism. The opposing view of Slater, Feynman, and Bader has maintained that the source of stabilization is electrostatic potential energy lowering due to electron density redistribution to binding regions between nuclei. Despite the large body of accurate quantum chemical work on a range of molecules, the debate concerning the origin of bonding continues unabated, even for H2(+), the simplest of covalently bound molecules. We therefore present here a detailed study of H2(+), including its formation, that uses a sequence of computational methods designed to reveal the relevant contributing mechanisms as well as the spatial density distributions of the kinetic and potential energy contributions. We find that the electrostatic mechanism fails to provide real insight or explanation of bonding, while the kinetic energy mechanism is sound and accurate but complex or even paradoxical to those preferring the apparent simplicity of the electrostatic model. We further argue that the underlying mechanism of bonding is in fact of dynamical character, and analyses that focus on energy do not reveal the origin of covalent bonding in full clarity.

  13. Programmable energy landscapes for kinetic control of DNA strand displacement.

    PubMed

    Machinek, Robert R F; Ouldridge, Thomas E; Haley, Natalie E C; Bath, Jonathan; Turberfield, Andrew J

    2014-11-10

    DNA is used to construct synthetic systems that sense, actuate, move and compute. The operation of many dynamic DNA devices depends on toehold-mediated strand displacement, by which one DNA strand displaces another from a duplex. Kinetic control of strand displacement is particularly important in autonomous molecular machinery and molecular computation, in which non-equilibrium systems are controlled through rates of competing processes. Here, we introduce a new method based on the creation of mismatched base pairs as kinetic barriers to strand displacement. Reaction rate constants can be tuned across three orders of magnitude by altering the position of such a defect without significantly changing the stabilities of reactants or products. By modelling reaction free-energy landscapes, we explore the mechanistic basis of this control mechanism. We also demonstrate that oxDNA, a coarse-grained model of DNA, is capable of accurately predicting and explaining the impact of mismatches on displacement kinetics.

  14. Effects of directed and kinetic energy weapons on spacecraft

    SciTech Connect

    Fraas, A P

    1986-12-01

    The characteristics of the various directed energy beams are reviewed, and their damaging effects on typical materials are examined for a wide range of energy pulse intensities and durations. Representative cases are surveyed, and charts are presented to indicate regions in which damage to spacecraft structures, particularly radiators for power plants, would be likely. The effects of kinetic energy weapons, such as bird-shot, are similarly examined. The charts are then applied to evaluate the effectiveness of various measures designed to reduce the vulnerability of spacecraft components, particularly nuclear electric power plants.

  15. High energy colliders

    SciTech Connect

    Palmer, R.B.; Gallardo, J.C.

    1997-02-01

    The authors consider the high energy physics advantages, disadvantages and luminosity requirements of hadron (pp, p{anti p}), lepton (e{sup +}e{sup {minus}}, {mu}{sup +}{mu}{sup {minus}}) and photon-photon colliders. Technical problems in obtaining increased energy in each type of machine are presented. The machines relative size are also discussed.

  16. Possible explanation of the atmospheric kinetic and potential energy spectra.

    PubMed

    Vallgren, Andreas; Deusebio, Enrico; Lindborg, Erik

    2011-12-23

    We hypothesize that the observed wave number spectra of kinetic and potential energy in the atmosphere can be explained by assuming that there are two related cascade processes emanating from the same large-scale energy source, a downscale cascade of potential enstrophy, giving rise to the k(-3) spectrum at synoptic scales and a downscale energy cascade giving rise to the k(-5/3) spectrum at mesoscales. The amount of energy which is going into the downscale energy cascade is determined by the rate of system rotation, with negligible energy going downscale in the limit of very fast rotation. We present a set of simulations of a system with strong rotation and stratification, supporting these hypotheses and showing good agreement with observations.

  17. Reaction Path Optimization with Holonomic Constraints and Kinetic Energy Potentials

    SciTech Connect

    Brokaw, Jason B.; Haas, Kevin R.; Chu, Jhih-wei

    2009-08-11

    Two methods are developed to enhance the stability, efficiency, and robustness of reaction path optimization using a chain of replicas. First, distances between replicas are kept equal during path optimization via holonomic constraints. Finding a reaction path is, thus, transformed into a constrained optimization problem. This approach avoids force projections for finding minimum energy paths (MEPs), and fast-converging schemes such as quasi-Newton methods can be readily applied. Second, we define a new objective function - the total Hamiltonian - for reaction path optimization, by combining the kinetic energy potential of each replica with its potential energy function. Minimizing the total Hamiltonian of a chain determines a minimum Hamiltonian path (MHP). If the distances between replicas are kept equal and a consistent force constant is used, then the kinetic energy potentials of all replicas have the same value. The MHP in this case is the most probable isokinetic path. Our results indicate that low-temperature kinetic energy potentials (<5 K) can be used to prevent the development of kinks during path optimization and can significantly reduce the required steps of minimization by 2-3 times without causing noticeable differences between a MHP and MEP. These methods are applied to three test cases, the C₇eq-to-Cax isomerization of an alanine dipeptide, the ⁴C₁- to-¹C₄ transition of an α-D-glucopyranose, and the helix-to-sheet transition of a GNNQQNY heptapeptide. By applying the methods developed in this work, convergence of reaction path optimization can be achieved for these complex transitions, involving full atomic details and a large number of replicas (>100). For the case of helix-to-sheet transition, we identify pathways whose energy barriers are consistent with experimental measurements. Further, we develop a method based on the work energy theorem to quantify the accuracy of reaction paths and to determine whether the atoms used to define a

  18. Reaction Path Optimization with Holonomic Constraints and Kinetic Energy Potentials.

    PubMed

    Brokaw, Jason B; Haas, Kevin R; Chu, Jhih-Wei

    2009-08-11

    Two methods are developed to enhance the stability, efficiency, and robustness of reaction path optimization using a chain of replicas. First, distances between replicas are kept equal during path optimization via holonomic constraints. Finding a reaction path is, thus, transformed into a constrained optimization problem. This approach avoids force projections for finding minimum energy paths (MEPs), and fast-converging schemes such as quasi-Newton methods can be readily applied. Second, we define a new objective function - the total Hamiltonian - for reaction path optimization, by combining the kinetic energy potential of each replica with its potential energy function. Minimizing the total Hamiltonian of a chain determines a minimum Hamiltonian path (MHP). If the distances between replicas are kept equal and a consistent force constant is used, then the kinetic energy potentials of all replicas have the same value. The MHP in this case is the most probable isokinetic path. Our results indicate that low-temperature kinetic energy potentials (<5 K) can be used to prevent the development of kinks during path optimization and can significantly reduce the required steps of minimization by 2-3 times without causing noticeable differences between a MHP and MEP. These methods are applied to three test cases, the C7eq-to-Cax isomerization of an alanine dipeptide, the (4)C1-to-(1)C4 transition of an α-d-glucopyranose, and the helix-to-sheet transition of a GNNQQNY heptapeptide. By applying the methods developed in this work, convergence of reaction path optimization can be achieved for these complex transitions, involving full atomic details and a large number of replicas (>100). For the case of helix-to-sheet transition, we identify pathways whose energy barriers are consistent with experimental measurements. Further, we develop a method based on the work energy theorem to quantify the accuracy of reaction paths and to determine whether the atoms used to define a path

  19. Plasmadynamics and ionization kinetics of thermionic energy conversion

    SciTech Connect

    Lawless, J.L. Jr.; Lam, S.H.

    1982-02-01

    To reduce the plasma arc-drop, thermionic energy conversion is studied with both analytical and numerical tools. Simplifications are made in both the plasmadynamic and ionization-recombination theories. These are applied to a scheme proposed presently using laser irradiation to enhance the ionization kinetics of the thermionic plasma and thereby reduce the arc-drop. It is also predicted that it is possible to generate the required laser light from a thermionic-type cesium plasma. The analysis takes advantage of theoretical simplifications derived for the ionization-recombination kinetics. It is shown that large laser ionization enhancements can occur and that collisional cesium recombination lasing is expected. To complement the kinetic theory, a numerical method is developed to solve the thermionic plasma dynamics. To combine the analysis of ionization-recombination kinetics with the plasma dynamics of thermionic conversion, a finite difference computer program is constructed. It is capable of solving for both unsteady and steady thermionic converter behavior including possible laser ionization enhancement or atomic recombination lasing. A proposal to improve thermionic converter performance using laser radiation is considered. In this proposed scheme, laser radiation impinging on a thermionic plasma enhances the ionization process thereby raising the plasma density and reducing the plasma arc-drop. A source for such radiation may possibly be a cesium recombination laser operating in a different thermionic converter. The possibility of this being an energy efficient process is discussed. (WHK)

  20. Exact kinetic energy enables accurate evaluation of weak interactions by the FDE-vdW method

    SciTech Connect

    Sinha, Debalina; Pavanello, Michele

    2015-08-28

    The correlation energy of interaction is an elusive and sought-after interaction between molecular systems. By partitioning the response function of the system into subsystem contributions, the Frozen Density Embedding (FDE)-vdW method provides a computationally amenable nonlocal correlation functional based on the adiabatic connection fluctuation dissipation theorem applied to subsystem density functional theory. In reproducing potential energy surfaces of weakly interacting dimers, we show that FDE-vdW, either employing semilocal or exact nonadditive kinetic energy functionals, is in quantitative agreement with high-accuracy coupled cluster calculations (overall mean unsigned error of 0.5 kcal/mol). When employing the exact kinetic energy (which we term the Kohn-Sham (KS)-vdW method), the binding energies are generally closer to the benchmark, and the energy surfaces are also smoother.

  1. Exact kinetic energy enables accurate evaluation of weak interactions by the FDE-vdW method.

    PubMed

    Sinha, Debalina; Pavanello, Michele

    2015-08-28

    The correlation energy of interaction is an elusive and sought-after interaction between molecular systems. By partitioning the response function of the system into subsystem contributions, the Frozen Density Embedding (FDE)-vdW method provides a computationally amenable nonlocal correlation functional based on the adiabatic connection fluctuation dissipation theorem applied to subsystem density functional theory. In reproducing potential energy surfaces of weakly interacting dimers, we show that FDE-vdW, either employing semilocal or exact nonadditive kinetic energy functionals, is in quantitative agreement with high-accuracy coupled cluster calculations (overall mean unsigned error of 0.5 kcal/mol). When employing the exact kinetic energy (which we term the Kohn-Sham (KS)-vdW method), the binding energies are generally closer to the benchmark, and the energy surfaces are also smoother.

  2. High-energy detector

    DOEpatents

    Bolotnikov, Aleksey E [South Setauket, NY; Camarda, Giuseppe [Farmingville, NY; Cui, Yonggang [Upton, NY; James, Ralph B [Ridge, NY

    2011-11-22

    The preferred embodiments are directed to a high-energy detector that is electrically shielded using an anode, a cathode, and a conducting shield to substantially reduce or eliminate electrically unshielded area. The anode and the cathode are disposed at opposite ends of the detector and the conducting shield substantially surrounds at least a portion of the longitudinal surface of the detector. The conducting shield extends longitudinally to the anode end of the detector and substantially surrounds at least a portion of the detector. Signals read from one or more of the anode, cathode, and conducting shield can be used to determine the number of electrons that are liberated as a result of high-energy particles impinge on the detector. A correction technique can be implemented to correct for liberated electron that become trapped to improve the energy resolution of the high-energy detectors disclosed herein.

  3. A study of the kinetic energy generation with general circulation models

    NASA Technical Reports Server (NTRS)

    Chen, T.-C.; Lee, Y.-H.

    1983-01-01

    The history data of winter simulation by the GLAS climate model and the NCAR community climate model are used to examine the generation of atmospheric kinetic energy. The contrast between the geographic distributions of the generation of kinetic energy and divergence of kinetic energy flux shows that kinetic energy is generated in the upstream side of jets, transported to the downstream side and destroyed there. The contributions from the time-mean and transient modes to the counterbalance between generation of kinetic energy and divergence of kinetic energy flux are also investigated. It is observed that the kinetic energy generated by the time-mean mode is essentially redistributed by the time-mean flow, while that generated by the transient flow is mainly responsible for the maintenance of the kinetic energy of the entire atmospheric flow.

  4. Thermal ablation of plasma-facing surfaces in tokamak disruptions: Sensitivity to particle kinetic energy

    SciTech Connect

    Ehst, D.A.; Hassanein, A.

    1996-02-01

    Ablation damage to solid targets with high heat flux impulses is generally greater high-energy electron beam heat sources compared to low-energy plasma guns. This sensitivity to incoming particle kinetic energy is explored with computer modelling; a fast-running routine (DESIRE) is developed for initial scoping analysis and is found to be in reasonable agreement with several experiments on graphite and tungsten targets. If tokamak disruptions are characterized by particle energies less than {approximately}1 keV, then we expect plasma guns are a better analogue than electron beams for simulating disruption behavior and testing candidate plasma-facing materials.

  5. High energy beam lines

    NASA Astrophysics Data System (ADS)

    Marchetto, M.; Laxdal, R. E.

    2014-01-01

    The ISAC post accelerator comprises an RFQ, DTL and SC-linac. The high energy beam lines connect the linear accelerators as well as deliver the accelerated beams to two different experimental areas. The medium energy beam transport (MEBT) line connects the RFQ to the DTL. The high energy beam transport (HEBT) line connects the DTL to the ISAC-I experimental stations (DRAGON, TUDA-I, GPS). The DTL to superconducting beam (DSB) transport line connects the ISAC-I and ISAC-II linacs. The superconducting energy beam transport (SEBT) line connects the SC linac to the ISAC-II experimental station (TUDA-II, HERACLES, TIGRESS, EMMA and GPS). All these lines have the function of transporting and matching the beams to the downstream sections by manipulating the transverse and longitudinal phase space. They also contain diagnostic devices to measure the beam properties.

  6. Kinetic ways of tailoring phases in high entropy alloys.

    PubMed

    He, Feng; Wang, Zhijun; Li, Yiyan; Wu, Qingfeng; Li, Junjie; Wang, Jincheng; Liu, C T

    2016-09-30

    The comprehensive performance of high entropy alloys (HEAs) depends on the phase selection significantly. However, up to now, investigations of the phase selection in HEAs mainly focused on the thermodynamic equilibrium phase, while kinetic ways of tailoring the phases in HEAs are seldom considered. In HEAs, the kinetics of sluggish diffusion and the numerous possible phases make the kinetics of phase transformation more complex and intriguing. Here, the kinetic effect in CoCrFeNiTi0.4 HEAs was investigated to reveal the possibility of controlling phase selection via kinetic ways for HEAs. The σ, γ' and R phases in the CoCrFeNiTi0.4 HEA can be controlled under different cooling rate both in solidification and solid transformation. The theoretical analyses revealed the kinetic effect on phase selection. The method proposed here, tailoring the phases with different kinetic ways, could be used to prepare promising HEAs with very rich composition design.

  7. Kinetic ways of tailoring phases in high entropy alloys

    NASA Astrophysics Data System (ADS)

    He, Feng; Wang, Zhijun; Li, Yiyan; Wu, Qingfeng; Li, Junjie; Wang, Jincheng; Liu, C. T.

    2016-09-01

    The comprehensive performance of high entropy alloys (HEAs) depends on the phase selection significantly. However, up to now, investigations of the phase selection in HEAs mainly focused on the thermodynamic equilibrium phase, while kinetic ways of tailoring the phases in HEAs are seldom considered. In HEAs, the kinetics of sluggish diffusion and the numerous possible phases make the kinetics of phase transformation more complex and intriguing. Here, the kinetic effect in CoCrFeNiTi0.4 HEAs was investigated to reveal the possibility of controlling phase selection via kinetic ways for HEAs. The σ, γ‧ and R phases in the CoCrFeNiTi0.4 HEA can be controlled under different cooling rate both in solidification and solid transformation. The theoretical analyses revealed the kinetic effect on phase selection. The method proposed here, tailoring the phases with different kinetic ways, could be used to prepare promising HEAs with very rich composition design.

  8. Determining the band gap and mean kinetic energy of atoms from reflection electron energy loss spectra

    SciTech Connect

    Vos, M.; Marmitt, G. G.; Finkelstein, Y.; Moreh, R.

    2015-09-14

    Reflection electron energy loss spectra from some insulating materials (CaCO{sub 3}, Li{sub 2}CO{sub 3}, and SiO{sub 2}) taken at relatively high incoming electron energies (5–40 keV) are analyzed. Here, one is bulk sensitive and a well-defined onset of inelastic excitations is observed from which one can infer the value of the band gap. An estimate of the band gap was obtained by fitting the spectra with a procedure that includes the recoil shift and recoil broadening affecting these measurements. The width of the elastic peak is directly connected to the mean kinetic energy of the atom in the material (Doppler broadening). The experimentally obtained mean kinetic energies of the O, C, Li, Ca, and Si atoms are compared with the calculated ones, and good agreement is found, especially if the effect of multiple scattering is taken into account. It is demonstrated experimentally that the onset of the inelastic excitation is also affected by Doppler broadening. Aided by this understanding, we can obtain a good fit of the elastic peak and the onset of inelastic excitations. For SiO{sub 2}, good agreement is obtained with the well-established value of the band gap (8.9 eV) only if it is assumed that the intensity near the edge scales as (E − E{sub gap}){sup 1.5}. For CaCO{sub 3}, the band gap obtained here (7 eV) is about 1 eV larger than the previous experimental value, whereas the value for Li{sub 2}CO{sub 3} (7.5 eV) is the first experimental estimate.

  9. Determining the band gap and mean kinetic energy of atoms from reflection electron energy loss spectra

    NASA Astrophysics Data System (ADS)

    Vos, M.; Marmitt, G. G.; Finkelstein, Y.; Moreh, R.

    2015-09-01

    Reflection electron energy loss spectra from some insulating materials (CaCO3, Li2CO3, and SiO2) taken at relatively high incoming electron energies (5-40 keV) are analyzed. Here, one is bulk sensitive and a well-defined onset of inelastic excitations is observed from which one can infer the value of the band gap. An estimate of the band gap was obtained by fitting the spectra with a procedure that includes the recoil shift and recoil broadening affecting these measurements. The width of the elastic peak is directly connected to the mean kinetic energy of the atom in the material (Doppler broadening). The experimentally obtained mean kinetic energies of the O, C, Li, Ca, and Si atoms are compared with the calculated ones, and good agreement is found, especially if the effect of multiple scattering is taken into account. It is demonstrated experimentally that the onset of the inelastic excitation is also affected by Doppler broadening. Aided by this understanding, we can obtain a good fit of the elastic peak and the onset of inelastic excitations. For SiO2, good agreement is obtained with the well-established value of the band gap (8.9 eV) only if it is assumed that the intensity near the edge scales as (E - Egap)1.5. For CaCO3, the band gap obtained here (7 eV) is about 1 eV larger than the previous experimental value, whereas the value for Li2CO3 (7.5 eV) is the first experimental estimate.

  10. High Energy Astrophysics Program

    NASA Technical Reports Server (NTRS)

    1996-01-01

    This report reviews activities performed by members of the USRA (Universities Space Research Association) contract team during the six months during the reporting period (10/95 - 3/96) and projected activities during the coming six months. Activities take place at the Goddard Space Flight Center, within the Laboratory for High Energy Astrophysics. Developments concern instrumentation, observation, data analysis, and theoretical work in Astrophysics. Missions supported include: Advanced Satellite for Cosmology and Astrophysics (ASCA), X-ray Timing Experiment (XTE), X-ray Spectrometer (XRS), Astro-E, High Energy Astrophysics Science, Archive Research Center (HEASARC), and others.

  11. High Energy Astrophysics Program

    NASA Technical Reports Server (NTRS)

    1996-01-01

    This report reviews activities performed-by members of the USRA contract team during the six months of the reporting period and projected activities during the coming six months. Activities take place at the Goddard Space Flight Center, visiting the Laboratory for High Energy Astrophysics. Developments concern instrumentation, observation, data analysis, and theoretical work in Astrophysics. Missions supported include: Advanced Satellite for Cosmology and Astrophysics (ASCA); X-ray Timing Experiment (XTE); X-ray Spectrometer (XRS); Astro-E; High Energy Astrophysics Science Archive Research Center (HEASARC), and others.

  12. Biomineralization mechanisms: a kinetics and interfacial energy approach

    NASA Astrophysics Data System (ADS)

    Nancollas, George H.; Wu, Wenju

    2000-04-01

    The calcium phosphates and oxalates are among the most frequently encountered biomineral phases and numerous kinetics studies have been made of their crystallization and dissolution in supersaturated and undersaturated solutions, respectively. These have focused mainly on parameters such as solution composition, ionic strength, pH, temperature, and solid surface characteristics. There is considerable interest in extending such studies to solutions more closely simulating the biological milieu. The constant composition method is especially useful for investigating the mechanisms of these reactions, and in the present work, the interfacial tensions between water and each of these surfaces have been calculated from measured contact angles using surface tension component theory. Values for the calcium phosphate phases such as dicalcium phosphate dihydrate (DCPD), octacalcium phosphate (OCP), hydroxyapatite (HAP), and fluorapatite (FAP) may be compared with data calculated from dissolution kinetics experiments invoking different reaction mechanisms. Agreement between the directly measured interfacial energies and those calculated from the kinetics experiments provides valuable corroborative information about individual growth and dissolution mechanisms. For the calcium phosphates, the much smaller interfacial tensions of OCP and DCPD in contact with water as compared with those of HAP and FAP support the suggestion that the former phases are precursors in HAP and FAP biomineralization. The ability of a surface to nucleate mineral phases is closely related to the magnitude of the interfacial energies. Constant composition studies have also shown that HAP is an effective nucleator of calcium oxalate monohydrate, both of which are frequently observed in renal stones.

  13. Translational and rotational excitation of the CO{sub 2}(00{sup 0}0) vibrationless state in the collisional quenching of highly vibrationally excited 2-methylpyrazine: Kinetics and dynamics of large energy transfers

    SciTech Connect

    Sevy, Eric T.; Rubin, Seth M.; Lin, Zhen; Flynn, George W.

    2000-09-22

    The relaxation of highly vibrationally excited methylpyrazine (C{sub 5}N{sub 2}H{sub 6}) by collisions with CO{sub 2} molecules has been investigated over the temperature range 243-364 K using diode laser transient absorption spectroscopy. Particular focus is placed on understanding both the dynamical features and the kinetics of collisions which are accompanied by large energy transfers into the CO{sub 2} rotational and translational degrees of freedom. Vibrationally hot methylpyrazine (E{sup '}=40 987 cm{sup -1}) was prepared by 248 nm excimer laser pumping, followed by rapid radiationless transitions to the ground electronic state. The nascent rotational population distributions (J=58-80) of the 00{sup 0}0 ground state of CO{sub 2} resulting from collisions with hot methylpyrazine were probed at short times following the excimer laser pulse. Doppler spectroscopy was used to measure the distributions of CO{sub 2} recoil velocities for individual rotational levels of the 00{sup 0}0 state. In addition, the temperature dependence of the state resolved, absolute rate constants for collisions populating high J states of CO{sub 2} was determined. The rotational population distributions, distributions of recoil velocities, and quenching rates for production of CO{sub 2} high J states (J=58-80) exhibit a very weak temperature dependence. The slight temperature dependence indicates that CO{sub 2} molecules which scatter into high J states of the ground vibrationless level originate from rotational levels near the mean of the precollision thermal rotational distribution. A gap law model is used to estimate the average initial rotational state and velocity of the CO{sub 2} bath, which allows for the calculation of the energy transfer magnitudes, {delta}E. The measured energy transfer probabilities which are indexed by final bath state are resorted as a function of {delta}E to create the energy transfer distribution function, P(E,E{sup '}) from E{sup '}-E{approx}1500-6000 cm

  14. Spectral Energy Transfer and Dissipation of Magnetic Energy from Fluid to Kinetic Scales

    SciTech Connect

    Bowers, K.; Li, H.

    2007-01-19

    We investigate the magnetic energy transfer from the fluid to kinetic scales and dissipation processes using three-dimensional fully kinetic particle-in-cell plasma simulations. The nonlinear evolution of a sheet pinch is studied where we show that it exhibits both fluid scale global relaxation and kinetic scale collisionless reconnection at multiple resonant surfaces. The interactions among collisionless tearing modes destroy the original flux surfaces and produce stochastic fields, along with generating sheets and filaments of intensified currents. In addition, the magnetic energy is transferred from the original shear length scale both to the large scales due to the global relaxation and to the smaller, kinetic scales for dissipation. The dissipation is dominated by the thermal or pressure effect in the generalized Ohm's law, and electrons are preferentially accelerated.

  15. Carbonate mineral dissolution kinetics in high pressure experiments

    NASA Astrophysics Data System (ADS)

    Dethlefsen, F.; Dörr, C.; Schäfer, D.; Ebert, M.

    2012-04-01

    The potential CO2 reservoirs in the North German Basin are overlain by a series of Mesozoic barrier rocks and aquifers and finally mostly by Tertiary and Quaternary close-to-surface aquifers. The unexpected rise of stored CO2 from its reservoir into close-to-surface aquifer systems, perhaps through a broken well casing, may pose a threat to groundwater quality because of the acidifying effect of CO2 dissolution in water. The consequences may be further worsening of the groundwater quality due to the mobilization of heavy metals. Buffer mechanisms counteracting the acidification are for instance the dissolution of carbonates. Carbonate dissolution kinetics is comparably fast and carbonates can be abundant in close-to-surface aquifers. The disadvantages of batch experiments compared to column experiments in order to determine rate constants are well known and have for instance been described by v. GRINSVEN and RIEMSDIJK (1992). Therefore, we have designed, developed, tested, and used a high-pressure laboratory column system to simulate aquifer conditions in a flow through setup within the CO2-MoPa project. The calcite dissolution kinetics was determined for CO2-pressures of 6, 10, and 50 bars. The results were evaluated by using the PHREEQC code with a 1-D reactive transport model, applying a LASAGA (1984) -type kinetic dissolution equation (PALANDRI and KHARAKA, 2004; eq. 7). While PALANDRI and KHARAKA (2004) gave calcite dissolution rate constants originating from batch experiments of log kacid = -0.3 and log kneutral = -5.81, the data of the column experiment were best fitted using log kacid = -2.3 and log kneutral = -7.81, so that the rate constants fitted using the lab experiment applying 50 bars pCO2 were approximately 100 times lower than according to the literature data. Rate constants of experiments performed at less CO2 pressure (pCO2 = 6 bars: log kacid = -1.78; log kneutral = -7.29) were only 30 times lower than literature data. These discrepancies in the

  16. High Energy Astronomy Observatory

    NASA Technical Reports Server (NTRS)

    1980-01-01

    An overview of the High Energy Astronomy Observatory 2 contributions to X-ray astronomy is presented along with a brief description of the satellite and onboard telescope. Observations relating to galaxies and galactic clusters, black holes, supernova remnants, quasars, and cosmology are discussed.

  17. High energy particle astronomy.

    NASA Technical Reports Server (NTRS)

    Buffington, A.; Muller, R. A.; Smith, L. H.; Smoot, G. F.

    1972-01-01

    Discussion of techniques currently used in high energy particle astronomy for measuring charged and neutral cosmic rays and their isotope and momentum distribution. Derived from methods developed for accelerator experiments in particle physics, these techniques help perform important particle astronomy experiments pertaining to nuclear cosmic ray and gamma ray research, electron and position probes, and antimatter searches.

  18. Thermodynamic properties and crystallization kinetics at high liquid undercooling

    NASA Technical Reports Server (NTRS)

    Fecht, Hans J.

    1990-01-01

    The heat capacities of liquid and crystalline Au-Pb-Sb alloys in the glass-forming composition range were measured with droplet emulsion and bulk samples. Based on the measured C(sub p) data, the entropy, enthalpy, and Gibbs free energy functions of the eutectic, solid mixture, and undercooled liquid were determined as a function of undercooling and compared with theoretical predictions. The results indicate an isentropic temperature at 313 + or - 5 K, which agrees well with experimental data for the glass transition. A kinetics analysis of the nucleation undercooling response suggests that the proper choice for the Gibbs free energy change during crystallization is most important in analyzing the nucleation kinetics. By classical nucleation theory, the prefactors obtained, based on a variety of theoretical predictions for the driving force, can differ by six orders of magnitude. If the nucleation rates are extrapolated to high undercooling, the extrapolations based on measured heat capacity data show agreement, whereas the predicted nucleation rates are inconsistent with results from drop tower experiments. The implications for microg experiments are discussed.

  19. Momentum and kinetic energy before the tackle in rugby union.

    PubMed

    Hendricks, Sharief; Karpul, David; Lambert, Mike

    2014-09-01

    Understanding the physical demands of a tackle in match situations is important for safe and effective training, developing equipment and research. Physical components such as momentum and kinetic energy, and it relationship to tackle outcome is not known. The aim of this study was to compare momenta between ball-carrier and tackler, level of play (elite, university and junior) and position (forwards vs. backs), and describe the relationship between ball-carrier and tackler mass, velocity and momentum and the tackle outcome. Also, report on the ball-carrier and tackler kinetic energy before contact and the estimated magnitude of impact (energy distributed between ball-carrier and tackler upon contact). Velocity over 0.5 seconds before contact was determined using a 2-dimensional scaled version of the field generated from a computer alogorithm. Body masses of players were obtained from their player profiles. Momentum and kinetic energy were subsequently calculated for 60 tackle events. Ball-carriers were heavier than the tacklers (ball-carrier 100 ± 14 kg vs. tackler 93 ± 11 kg, d = 0.52, p = 0.0041, n = 60). Ball-carriers as forwards had a significantly higher momentum than backs (forwards 563 ± 226 Kg(.)m(.)s(-1) n = 31 vs. backs 438 ± 135 Kg(.)m(.)s(-1), d = 0.63, p = 0.0012, n = 29). Tacklers dominated 57% of tackles and ball-carriers dominated 43% of tackles. Despite the ball-carrier having a mass advantage before contact more frequently than the tackler, momentum advantage and tackle dominance between the ball-carrier and tackler was proportionally similar. These findings may reflect a characteristic of the modern game of rugby where efficiently heavier players (particularly forwards) are tactically predetermined to carry the ball in contact. Key PointsFirst study to quantify momentum, kinetic energy, and magnitude of impact in rugby tackles across different levels in matches without a device attached to a player.Physical components alone, of either ball

  20. Momentum and Kinetic Energy Before the Tackle in Rugby Union

    PubMed Central

    Hendricks, Sharief; Karpul, David; Lambert, Mike

    2014-01-01

    Understanding the physical demands of a tackle in match situations is important for safe and effective training, developing equipment and research. Physical components such as momentum and kinetic energy, and it relationship to tackle outcome is not known. The aim of this study was to compare momenta between ball-carrier and tackler, level of play (elite, university and junior) and position (forwards vs. backs), and describe the relationship between ball-carrier and tackler mass, velocity and momentum and the tackle outcome. Also, report on the ball-carrier and tackler kinetic energy before contact and the estimated magnitude of impact (energy distributed between ball-carrier and tackler upon contact). Velocity over 0.5 seconds before contact was determined using a 2-dimensional scaled version of the field generated from a computer alogorithm. Body masses of players were obtained from their player profiles. Momentum and kinetic energy were subsequently calculated for 60 tackle events. Ball-carriers were heavier than the tacklers (ball-carrier 100 ± 14 kg vs. tackler 93 ± 11 kg, d = 0.52, p = 0.0041, n = 60). Ball-carriers as forwards had a significantly higher momentum than backs (forwards 563 ± 226 Kg.m.s-1 n = 31 vs. backs 438 ± 135 Kg.m.s-1, d = 0.63, p = 0.0012, n = 29). Tacklers dominated 57% of tackles and ball-carriers dominated 43% of tackles. Despite the ball-carrier having a mass advantage before contact more frequently than the tackler, momentum advantage and tackle dominance between the ball-carrier and tackler was proportionally similar. These findings may reflect a characteristic of the modern game of rugby where efficiently heavier players (particularly forwards) are tactically predetermined to carry the ball in contact. Key Points First study to quantify momentum, kinetic energy, and magnitude of impact in rugby tackles across different levels in matches without a device attached to a player. Physical components alone, of either ball-carrier or

  1. Theoretical High Energy Physics

    SciTech Connect

    Christ, Norman H.; Weinberg, Erick J.

    2014-07-14

    we provide reports from each of the six faculty supported by the Department of Energy High Energy Physics Theory grant at Columbia University. Each is followed by a bibliography of the references cited. A complete list of all of the publications in the 12/1/2010-04/30/2014 period resulting from research supported by this grant is provided in the following section. The final section lists the Ph.D. dissertations based on research supported by the grant that were submitted during this period.

  2. The transfer between electron bulk kinetic energy and thermal energy in collisionless magnetic reconnection

    SciTech Connect

    Lu, San; Lu, Quanming; Huang, Can; Wang, Shui

    2013-06-15

    By performing two-dimensional particle-in-cell simulations, we investigate the transfer between electron bulk kinetic and electron thermal energy in collisionless magnetic reconnection. In the vicinity of the X line, the electron bulk kinetic energy density is much larger than the electron thermal energy density. The evolution of the electron bulk kinetic energy is mainly determined by the work done by the electric field force and electron pressure gradient force. The work done by the electron gradient pressure force in the vicinity of the X line is changed to the electron enthalpy flux. In the magnetic island, the electron enthalpy flux is transferred to the electron thermal energy due to the compressibility of the plasma in the magnetic island. The compression of the plasma in the magnetic island is the consequence of the electromagnetic force acting on the plasma as the magnetic field lines release their tension after being reconnected. Therefore, we can observe that in the magnetic island the electron thermal energy density is much larger than the electron bulk kinetic energy density.

  3. High temperature heterogeneous reaction kinetics and mechanisms of tungsten oxidation

    NASA Astrophysics Data System (ADS)

    Sabourin, Justin L.

    energy systems. The primary application for this research topic is the migration of erosion processes in solid rocket motor nozzles. Since oxidation is the primary erosion mechanism of tungsten based nozzles, mitigation of this process through improved comprehension of the chemical mechanisms will increase performance of future rocket systems. In this dissertation, results of the high temperature reaction rates of bulk tungsten are studied using TG analysis in oxidizing atmospheres of O2, CO2, and H2O using helium (He) as an inert carrier gas. Isothermal reaction rates were determined at temperatures up to 1970 K, and oxidizing species partial pressures up to 64.6 torr. Kinetic parameters such as activation energies, frequency factors, and pressure exponents were determined for each reactive system. An important contribution of this work was quantifying the effects of carbon monoxide (CO) on the CO2 reaction, and hydrogen (H2) on the H2O reaction. In both cases the non-oxidizing species significantly reduced oxidation rates. Results have led to new interpretations and thought processes for limiting nozzle erosion in rocket motors. Combined with the TG analysis, as well as recent theoretical interpretations of reaction thermodynamics and kinetics, a new mechanism for tungsten and O2 oxidation has been developed using a one-dimensional numerical model of the TG flow reactor. Important chemical processes and species are also identified for reaction systems involving H2O and CO2. In the future, additional studies are needed to improve our understanding of these chemical species and processes so that more advanced kinetic mechanisms may be developed. In addition to a detailed analysis of high temperature tungsten corrosion processes, synthetic graphite corrosion processes are studied in detail as well. Details of these studies are presented in an attached appendix of this dissertation. These studies considered not only oxidation processes, but decomposition of synthetic

  4. Conversion of magnetic field energy into kinetic energy in the solar wind

    NASA Technical Reports Server (NTRS)

    Whang, Y. C.

    1972-01-01

    The outflow of the solar magnetic field energy (the radial component of the Poynting vector) per steradian is inversely proportional to the solar wind velocity. It is a decreasing function of the heliocentric distance. When the magnetic field effect is included in the one-fluid model of the solar wind, the transformation of magnetic field energy into kinetic energy during the expansion process increases the solar wind velocity at 1 AU by 17 percent.

  5. High energy from space

    NASA Technical Reports Server (NTRS)

    Margon, Bruce; Canizares, Claude; Catura, Richard C.; Clark, George W.; Fichtel, Carl E.; Friedman, Herbert; Giacconi, Riccardo; Grindlay, Jonathan E.; Helfand, David J.; Holt, Stephen S.

    1991-01-01

    The following subject areas are covered: (1) important scientific problems for high energy astrophysics (stellar activity, the interstellar medium in galaxies, supernovae and endpoints of stellar evolution, nucleosynthesis, relativistic plasmas and matter under extreme conditions, nature of gamma-bursts, identification of black holes, active nuclei, accretion physics, large-scale structures, intracluster medium, nature of dark matter, and the X- and gamma-ray background); (2) the existing experimental programs (Advanced X-Ray Astrophysics Facility (AXAF), Gamma Ray Observatory (GRO), X-Ray Timing Explorer (XTE), High Energy Transient Experiment (HETE), U.S. participation in foreign missions, and attached Shuttle and Space Station Freedom payloads); (3) major missions for the 1990's; (4) a new program of moderate missions; (5) new opportunities for small missions; (6) technology development issues; and (7) policy issues.

  6. High energy transients

    NASA Technical Reports Server (NTRS)

    Woosley, S. E.

    1984-01-01

    A meeting was convened on the campus of the University of California at Santa Cruz during the two-week interval July 11 through July 22, 1983. Roughly 100 participants were chosen so as to give broad representation to all aspects of high energy transients. Ten morning review sessions were held in which invited speakers discussed the current status of observations and theory of the above subjects. Afternoon workshops were also held, usually more than one per day, to informally review various technical aspects of transients, confront shortcomings in theoretical models, and to propose productive courses for future research. Special attention was also given to the instrumentation used to study high energy transient and the characteristics and goals of a dedicated space mission to study transients in the next decade were determined. A listing of articles written by various members of the workshop is included.

  7. Electrochemical oxidation of COD from real textile wastewaters: Kinetic study and energy consumption.

    PubMed

    Zou, Jiaxiu; Peng, Xiaolan; Li, Miao; Xiong, Ying; Wang, Bing; Dong, Faqin; Wang, Bin

    2017-03-01

    In the present study, the electrochemical oxidation of real wastewaters discharged by textile industry was carried out using a boron-doped diamond (BDD) anode. The effect of operational variables, such as applied current density (20-100 mA·cm(-2)), NaCl concentration added to the real wastewaters (0-3 g·L(-1)), and pH value (2.0-10.0), on the kinetics of COD oxidation and on the energy consumption was carefully investigated. The obtained experimental results could be well matched with a proposed kinetic model, in which the indirect oxidation mediated by electrogenerated strong oxidants would be described through a pseudo-first-order kinetic constant k. Values of k exhibited a linear increase with increasing applied current density and decreasing pH value, and an exponential increase with NaCl concentration. Furthermore, high oxidation kinetics resulted in low specific energy consumption, but this conclusion was not suitable to the results obtained under different applied current density. Under the optimum operational conditions, it only took 3 h to complete remove the COD in the real textile wastewaters and the specific energy consumption could be as low as 11.12 kWh·kg(-1) COD. The obtained results, low energy consumption and short electrolysis time, allowed to conclude that the electrochemical oxidation based on BDD anodes would have practical industrial application for the treatment of real textile wastewater.

  8. Kinetic energy management in road traffic injury prevention: a call for action

    PubMed Central

    Khorasani-Zavareh, Davoud; Bigdeli, Maryam; Saadat, Soheil; Mohammadi, Reza

    2015-01-01

    Abstract: By virtue of their variability, mass and speed have important roles in transferring energies during a crash incidence (kinetic energy). The sum of kinetic energy is important in determining an injury severity and that is equal to one half of the vehicle mass multiplied by the square of the vehicle speed. To meet the Vision Zero policy (a traffic safety policy) prevention activities should be focused on vehicle speed management. Understanding the role of kinetic energy will help to develop measures to reduce the generation, distribution, and effects of this energy during a road traffic crash. Road traffic injury preventive activities necessitate Kinetic energy management to improve road user safety. PMID:24284810

  9. Implementation of high throughput experimentation techniques for kinetic reaction testing.

    PubMed

    Nagy, Anton J

    2012-02-01

    Successful implementation of High throughput Experimentation (EE) tools has resulted in their increased acceptance as essential tools in chemical, petrochemical and polymer R&D laboratories. This article provides a number of concrete examples of EE systems, which have been designed and successfully implemented in studies, which focus on deriving reaction kinetic data. The implementation of high throughput EE tools for performing kinetic studies of both catalytic and non-catalytic systems results in a significantly faster acquisition of high-quality kinetic modeling data, required to quantitatively predict the behavior of complex, multistep reactions.

  10. Spectral Kinetic Energy Transfer Through a Premixed Flame Brush

    NASA Astrophysics Data System (ADS)

    Towery, Colin A. Z.; Poludnenko, Alexei Y.; Hamlington, Peter E.

    2014-11-01

    Turbulence-flame interactions are of fundamental importance for understanding and modeling premixed turbulent reacting flows. These interactions can result in nonlinear feedback leading to large changes in both the turbulence and flame. Recent computational studies have indicated, however, that not all scales of turbulent motion are affected equally. Small-scale motions appear to be suppressed while larger-scale motions are unaffected or even enhanced. In order to determine the scale-dependence of turbulence-flame interactions, direct numerical simulations of statistically planar, premixed flames have been performed and analyzed. Two-dimensional kinetic energy spectra, conditioned on the planar-averaged fuel mass-fraction, are measured through the flame brush and compared to both compressible and incompressible non-reacting flow spectra. Changes in the spectra with respect to fuel mass-fraction are then connected to the dynamics of the kinetic energy spectrum transport equation. Particular focus is placed on understanding triadic velocity, pressure, and dilatation interactions, including the characterization of backscatter due to heat release and compressibility. Finally, the implications of these results for modeling practical premixed combustion problems are outlined.

  11. The kinetic energy interceptor: Shooting a bullet with a bullet

    SciTech Connect

    1995-04-01

    Although the Cold War has ended, the threat of proliferation with chemical, biological, and nuclear warheads continues. Two factors further increase the threat from these weapons of mass destruction: knowledge of missile technology has spread extensively, and, in recent years, many countries - some of them unfriendly to the US and its allies - have obtained short- and intermediate-range missiles. The threat posed by such missiles was amply demonstrated during the Gulf War. Thus, the need to protect US and allied forces from these weapons has never been greater. When nuclear-tipped defensive missiles, such as Sprint and Spartan, were phased out years ago, the US turned for its defense to kinetic-energy {open_quotes}kill{close_quotes} interceptors - missiles that destroy an enemy missile by striking it with lethal force and accuracy at some point in its trajectory. The Patriot missile is probably the best-known kinetic-energy (KE) interceptor in the US defensive arsenal. To counter the spreading threat of proliferation, LLNL and other laboratories have been participating in a joint program funded by the Ballistic Missile Defense Organization (BMDO), within the Department of Defense, to develop defensive missile systems. Participants are designing, testing, and certifying KE interceptors to defend against current and future missile threats. These research efforts are described.

  12. Kinetic Energy of Tornadoes in the United States.

    PubMed

    Fricker, Tyler; Elsner, James B

    2015-01-01

    Tornadoes can cause catastrophic destruction. Here total kinetic energy (TKE) as a metric of destruction is computed from the fraction of the tornado path experiencing various damage levels and a characteristic wind speed for each level. The fraction of the path is obtained from a model developed for the Nuclear Regulatory Commission that combines theory with empirical data. TKE is validated as a useful metric by comparing it to other indexes and loss indicators. Half of all tornadoes have TKE exceeding 62.1 GJ and a quarter have TKE exceeding 383.2 GJ. One percent of the tornadoes have TKE exceeding 31.9 TJ. April has more energy than May with fewer tornadoes; March has more energy than June with half as many tornadoes. September has the least energy but November and December have the fewest tornadoes. Alabama ranks number one in terms of tornado energy with 2.48 PJ over the period 2007-2013. TKE can be used to help better understand the changing nature of tornado activity.

  13. Kinetic Energy of Tornadoes in the United States

    PubMed Central

    Fricker, Tyler; Elsner, James B.

    2015-01-01

    Tornadoes can cause catastrophic destruction. Here total kinetic energy (TKE) as a metric of destruction is computed from the fraction of the tornado path experiencing various damage levels and a characteristic wind speed for each level. The fraction of the path is obtained from a model developed for the Nuclear Regulatory Commission that combines theory with empirical data. TKE is validated as a useful metric by comparing it to other indexes and loss indicators. Half of all tornadoes have TKE exceeding 62.1 GJ and a quarter have TKE exceeding 383.2 GJ. One percent of the tornadoes have TKE exceeding 31.9 TJ. April has more energy than May with fewer tornadoes; March has more energy than June with half as many tornadoes. September has the least energy but November and December have the fewest tornadoes. Alabama ranks number one in terms of tornado energy with 2.48 PJ over the period 2007–2013. TKE can be used to help better understand the changing nature of tornado activity. PMID:26132830

  14. Efficiency of pulse high-current generator energy transfer into plasma liner energy

    NASA Astrophysics Data System (ADS)

    Oreshkin, V. I.

    2013-08-01

    The efficiency of capacitor-bank energy transfer from a high-current pulse generator into kinetic energy of a plasma liner has been analyzed. The analysis was performed using a model including the circuit equations and equations of the cylindrical shell motion. High efficiency of the energy transfer into kinetic energy of the liner is shown to be achieved only by a low-inductance generator. We considered an "ideal" liner load in which the load current is close to zero in the final of the shell compression. This load provides a high (up to 80%) efficiency of energy transfer and higher stability when compressing the liner.

  15. High quality factor platinum silicide microwave kinetic inductance detectors

    NASA Astrophysics Data System (ADS)

    Szypryt, P.; Mazin, B. A.; Ulbricht, G.; Bumble, B.; Meeker, S. R.; Bockstiegel, C.; Walter, A. B.

    2016-10-01

    We report on the development of microwave kinetic inductance detectors (MKIDs) using platinum silicide as the sensor material. MKIDs are an emerging superconducting detector technology, capable of measuring the arrival times of single photons to better than two microseconds and their energies to around ten percent. Previously, MKIDs have been fabricated using either sub-stoichiometric titanium nitride or aluminum, but TiN suffers from the spatial inhomogeneities in the superconducting critical temperature and Al has a low kinetic inductance fraction, causing low detector sensitivity. To address these issues, we have instead fabricated the PtSi microresonators with the superconducting critical temperatures of 944 ± 12 mK and high internal quality factors ( Q i ≳ 10 6 ). These devices show typical quasiparticle lifetimes of τ q p ≈ 30 - 40 μ s and spectral resolution, R = λ / Δ λ , of 8 at 406.6 nm. We compare PtSi MKIDs to those fabricated with TiN and detail the substantial advantages that PtSi MKIDs have to offer.

  16. Energy deposition by heavy ions: Additivity of kinetic and potential energy contributions in hillock formation on CaF2

    NASA Astrophysics Data System (ADS)

    Wang, Y. Y.; Grygiel, C.; Dufour, C.; Sun, J. R.; Wang, Z. G.; Zhao, Y. T.; Xiao, G. Q.; Cheng, R.; Zhou, X. M.; Ren, J. R.; Liu, S. D.; Lei, Y.; Sun, Y. B.; Ritter, R.; Gruber, E.; Cassimi, A.; Monnet, I.; Bouffard, S.; Aumayr, F.; Toulemonde, M.

    2014-07-01

    Modification of surface and bulk properties of solids by irradiation with ion beams is a widely used technique with many applications in material science. In this study, we show that nano-hillocks on CaF2 crystal surfaces can be formed by individual impact of medium energy (3 and 5 MeV) highly charged ions (Xe22+ to Xe30+) as well as swift (kinetic energies between 12 and 58 MeV) heavy xenon ions. For very slow highly charged ions the appearance of hillocks is known to be linked to a threshold in potential energy (Ep) while for swift heavy ions a minimum electronic energy loss per unit length (Se) is necessary. With our results we bridge the gap between these two extreme cases and demonstrate, that with increasing energy deposition via Se the Ep-threshold for hillock production can be lowered substantially. Surprisingly, both mechanisms of energy deposition in the target surface seem to contribute in an additive way, which can be visualized in a phase diagram. We show that the inelastic thermal spike model, originally developed to describe such material modifications for swift heavy ions, can be extended to the case where both kinetic and potential energies are deposited into the surface.

  17. Energy deposition by heavy ions: additivity of kinetic and potential energy contributions in hillock formation on CaF2.

    PubMed

    Wang, Y Y; Grygiel, C; Dufour, C; Sun, J R; Wang, Z G; Zhao, Y T; Xiao, G Q; Cheng, R; Zhou, X M; Ren, J R; Liu, S D; Lei, Y; Sun, Y B; Ritter, R; Gruber, E; Cassimi, A; Monnet, I; Bouffard, S; Aumayr, F; Toulemonde, M

    2014-07-18

    Modification of surface and bulk properties of solids by irradiation with ion beams is a widely used technique with many applications in material science. In this study, we show that nano-hillocks on CaF2 crystal surfaces can be formed by individual impact of medium energy (3 and 5 MeV) highly charged ions (Xe(22+) to Xe(30+)) as well as swift (kinetic energies between 12 and 58 MeV) heavy xenon ions. For very slow highly charged ions the appearance of hillocks is known to be linked to a threshold in potential energy (Ep) while for swift heavy ions a minimum electronic energy loss per unit length (Se) is necessary. With our results we bridge the gap between these two extreme cases and demonstrate, that with increasing energy deposition via Se the Ep-threshold for hillock production can be lowered substantially. Surprisingly, both mechanisms of energy deposition in the target surface seem to contribute in an additive way, which can be visualized in a phase diagram. We show that the inelastic thermal spike model, originally developed to describe such material modifications for swift heavy ions, can be extended to the case where both kinetic and potential energies are deposited into the surface.

  18. High energy electron cooling

    SciTech Connect

    Parkhomchuk, V.

    1997-09-01

    High energy electron cooling requires a very cold electron beam. The questions of using electron cooling with and without a magnetic field are presented for discussion at this workshop. The electron cooling method was suggested by G. Budker in the middle sixties. The original idea of the electron cooling was published in 1966. The design activities for the NAP-M project was started in November 1971 and the first run using a proton beam occurred in September 1973. The first experiment with both electron and proton beams was started in May 1974. In this experiment good result was achieved very close to theoretical prediction for a usual two component plasma heat exchange.

  19. ENERGY DISSIPATION IN MAGNETIC NULL POINTS AT KINETIC SCALES

    SciTech Connect

    Olshevsky, Vyacheslav; Lapenta, Giovanni; Divin, Andrey; Eriksson, Elin; Markidis, Stefano

    2015-07-10

    We use kinetic particle-in-cell and MHD simulations supported by an observational data set to investigate magnetic reconnection in clusters of null points in space plasma. The magnetic configuration under investigation is driven by fast adiabatic flux rope compression that dissipates almost half of the initial magnetic field energy. In this phase powerful currents are excited producing secondary instabilities, and the system is brought into a state of “intermittent turbulence” within a few ion gyro-periods. Reconnection events are distributed all over the simulation domain and energy dissipation is rather volume-filling. Numerous spiral null points interconnected via their spines form null lines embedded into magnetic flux ropes; null point pairs demonstrate the signatures of torsional spine reconnection. However, energy dissipation mainly happens in the shear layers formed by adjacent flux ropes with oppositely directed currents. In these regions radial null pairs are spontaneously emerging and vanishing, associated with electron streams and small-scale current sheets. The number of spiral nulls in the simulation outweighs the number of radial nulls by a factor of 5–10, in accordance with Cluster observations in the Earth's magnetosheath. Twisted magnetic fields with embedded spiral null points might indicate the regions of major energy dissipation for future space missions such as the Magnetospheric Multiscale Mission.

  20. Prospects at high energies

    SciTech Connect

    Quigg, C.

    1988-11-01

    I discuss some possibilities for neutrino experiments in the fixed-target environment of the SPS, Tevatron, and UNK, with their primary proton beams of 0.4, 0.9, and 3.0 TeV. The emphasis is on unfinished business: issues that have been recognized for some time, but not yet resolved. Then I turn to prospects for proton-proton colliders to explore the 1-TeV scale. I review the motivation for new physics in the neighborhood of 1 TeV and mention some discovery possibilities for high-energy, high-luminosity hadron colliders and the implications they would have for neutrino physics. I raise the possibility of the direct study of neutrino interactions in hadron colliders. I close with a report on the status of the SSC project. 38 refs., 17 figs.

  1. Electron scattering as a tool to study zero-point kinetic energies of atoms in molecules

    NASA Astrophysics Data System (ADS)

    Moreh, R.; Finkelstein, Y.; Vos, M.

    2015-07-01

    High resolution electron compton scattering (ECS) is being used to study the atomic momentum distributions and hence the zero-point kinetic energies (ZPKE) of the scattering atoms. Such studies have shown that the scattering is from a single atom of the scattering sample. For an electron beam with a well defined incident energy, the scattered electron energy at any angle from each atomic species is Doppler broadened. The broadening reflects the atomic momentum distribution contributed by both the internal and external motions of the molecular system. By measuring the Doppler broadening of the scattered electron lines it was possible to determine the kinetic energy of the scattering atom including that of its zero-point motion. Thus, the atomic kinetic energies in gases such as H2, D2, HD, CH4 and in H2O, D2O and NH3 were measured and compared with those calculated semi-empirically using the measured optical infra red (IR) and Raman frequencies of the internal vibrations of the molecules. In general, good agreement between the measured and calculated values was found. Electron scattering was also used to study the ratio of e-scattering intensities from the H- and O-atoms in water (H2O), where some anomalies were reported to exist.

  2. Notepad-like triboelectric generator for efficiently harvesting low-velocity motion energy by interconversion between kinetic energy and elastic potential energy.

    PubMed

    Liu, Guanlin; Leng, Qiang; Lian, Jiawei; Guo, Hengyu; Yi, Xi; Hu, Chenguo

    2015-01-21

    Great attention has been paid to nanogenerators that harvest energy from ambient environments lately. In order to give considerable output current, most nanogenerators require high-velocity motion that in most cases can hardly be provided in our daily life. Here we report a notepad-like triboelectric generator (NTEG), which uses simple notepad-like structure to generate elastic deformation so as to turn a low-velocity kinetic energy into high-velocity kinetic energy through the conversion of elastic potential energy. Therefore, the NTEG can achieve high current output under low-velocity motion, which completely distinguishes it from tribogenerators previously reported. The factors that may affect the output performance are explored, including the number of slices, active length of slice, press speed, and vertical displacement. In addition, the working mechanism is systematically studied, indicating that the efficiency of the generator can be greatly enhanced by interconversion between kinetic energy and elastic potential energy. The short-circuit current, the open-circuit voltage, and power density are 205 μA and 470 V and 9.86 W/m(2), respectively, which is powerful enough to light up hundreds of light-emitting diodes (LEDs) and charge a commercial capacitor. Besides, NTEGs have been successfully applied to a self-powered door monitor.

  3. A comparison of observed and numerically predicted eddy kinetic energy budgets for a developing extratropical cyclone

    NASA Technical Reports Server (NTRS)

    Dare, P. M.; Smith, P. J.

    1983-01-01

    The eddy kinetic energy budget is calculated for a 48-hour forecast of an intense occluding winter cyclone associated with a strong well-developed jet stream. The model output consists of the initialized (1200 GMT January 9, 1975) and the 12, 24, 36, and 48 hour forecast fields from the Drexel/NCAR Limited Area Mesoscale Prediction System (LAMPS) model. The LAMPS forecast compares well with observations for the first 24 hours, but then overdevelops the low-level cyclone while inadequately developing the upper-air wave and jet. Eddy kinetic energy was found to be concentrated in the upper-troposphere with maxima flanking the primary trough. The increases in kinetic energy were found to be due to an excess of the primary source term of kinetic energy content, which is the horizontal flux of eddy kinetic energy over the primary sinks, and the generation and dissipation of eddy kinetic energy.

  4. Recruiting at the Edge: Kinetic Energy Inhibits Anchovy Populations in the Western Mediterranean

    PubMed Central

    Ruiz, Javier; Macías, Diego; Rincón, Margarita M.; Pascual, Ananda; Catalán, Ignacio A.; Navarro, Gabriel

    2013-01-01

    The Strait of Gibraltar replenishes the Mediterranean with Atlantic waters through an intense eastward current known as the Atlantic Jet (AJ). The AJ fertilizes the southwestern Mediterranean and is considered to be the ultimate factor responsible for the comparatively high fish production of this region. Here, we perform an analysis of the available historical catches and catch per unit effort (CPUE), together with a long series of surface currents, kinetic energy and chlorophyll concentration. We show that the high kinetic energy of the AJ increases primary production but also negatively impacts the recruitment of anchovy. We contend that anchovy recruitment in the region is inhibited by the advection and dispersion of larvae and post-larvae during periods of strong advection by the AJ. The inhibitory impact of kinetic energy on anchovy landings is not a transient but rather a persistent state of the system. An exceptional combination of events creates an outbreak of this species in the Alboran Sea. These events depend on the Mediterranean-Atlantic exchange of water masses and, therefore, are highly sensitive to climate changes that are projected, though not always negatively, for fish landings. PMID:23451027

  5. Mass independent kinetic energy reducing inlet system for vacuum environment

    DOEpatents

    Reilly, Peter T. A. [Knoxville, TN

    2010-12-14

    A particle inlet system comprises a first chamber having a limiting orifice for an incoming gas stream and a micrometer controlled expansion slit. Lateral components of the momentum of the particles are substantially cancelled due to symmetry of the configuration once the laminar flow converges at the expansion slit. The particles and flow into a second chamber, which is maintained at a lower pressure than the first chamber, and then moves into a third chamber including multipole guides for electromagnetically confining the particle. The vertical momentum of the particles descending through the center of the third chamber is minimized as an upward stream of gases reduces the downward momentum of the particles. The translational kinetic energy of the particles is near-zero irrespective of the mass of the particles at an exit opening of the third chamber, which may be advantageously employed to provide enhanced mass resolution in mass spectrometry.

  6. Mass independent kinetic energy reducing inlet system for vacuum environment

    DOEpatents

    Reilly, Peter T.A.

    2014-05-13

    A particle inlet system comprises a first chamber having a limiting orifice for an incoming gas stream and a micrometer controlled expansion slit. Lateral components of the momentum of the particles are substantially cancelled due to symmetry of the configuration once the laminar flow converges at the expansion slit. The particles and flow into a second chamber, which is maintained at a lower pressure than the first chamber, and then moves into a third chamber including multipole guides for electromagnetically confining the particle. The vertical momentum of the particles descending through the center of the third chamber is minimized as an upward stream of gases reduces the downward momentum of the particles. The translational kinetic energy of the particles is near-zero irrespective of the mass of the particles at an exit opening of the third chamber, which may be advantageously employed to provide enhanced mass resolution in mass spectrometry.

  7. Mass independent kinetic energy reducing inlet system for vacuum environment

    DOEpatents

    Reilly, Peter T.A.

    2013-12-03

    A particle inlet system comprises a first chamber having a limiting orifice for an incoming gas stream and a micrometer controlled expansion slit. Lateral components of the momentum of the particles are substantially cancelled due to symmetry of the configuration once the laminar flow converges at the expansion slit. The particles and flow into a second chamber, which is maintained at a lower pressure than the first chamber, and then moves into a third chamber including multipole guides for electromagnetically confining the particle. The vertical momentum of the particles descending through the center of the third chamber is minimized as an upward stream of gases reduces the downward momentum of the particles. The translational kinetic energy of the particles is near-zero irrespective of the mass of the particles at an exit opening of the third chamber, which may be advantageously employed to provide enhanced mass resolution in mass spectrometry.

  8. An integral turbulent kinetic energy analysis of free shear flows

    NASA Technical Reports Server (NTRS)

    Peters, C. E.; Phares, W. J.

    1973-01-01

    Mixing of coaxial streams is analyzed by application of integral techniques. An integrated turbulent kinetic energy (TKE) equation is solved simultaneously with the integral equations for the mean flow. Normalized TKE profile shapes are obtained from incompressible jet and shear layer experiments and are assumed to be applicable to all free turbulent flows. The shear stress at the midpoint of the mixing zone is assumed to be directly proportional to the local TKE, and dissipation is treated with a generalization of the model developed for isotropic turbulence. Although the analysis was developed for ducted flows, constant-pressure flows were approximated with the duct much larger than the jet. The axisymmetric flows under consideration were predicted with reasonable accuracy. Fairly good results were also obtained for the fully developed two-dimensional shear layers, which were computed as thin layers at the boundary of a large circular jet.

  9. Utilization of rotor kinetic energy storage for hybrid vehicles

    SciTech Connect

    Hsu, John S.

    2011-05-03

    A power system for a motor vehicle having an internal combustion engine, the power system comprises an electric machine (12) further comprising a first excitation source (47), a permanent magnet rotor (28) and a magnetic coupling rotor (26) spaced from the permanent magnet rotor and at least one second excitation source (43), the magnetic coupling rotor (26) also including a flywheel having an inertial mass to store kinetic energy during an initial acceleration to an operating speed; and wherein the first excitation source is electrically connected to the second excitation source for power cycling such that the flywheel rotor (26) exerts torque on the permanent magnet rotor (28) to assist braking and acceleration of the permanent magnet rotor (28) and consequently, the vehicle. An axial gap machine and a radial gap machine are disclosed and methods of the invention are also disclosed.

  10. Statistical model of a flexible inextensible polymer chain: The effect of kinetic energy

    NASA Astrophysics Data System (ADS)

    Pergamenshchik, V. M.; Vozniak, A. B.

    2017-01-01

    Because of the holonomic constraints, the kinetic energy contribution in the partition function of an inextensible polymer chain is difficult to find, and it has been systematically ignored. We present the first thermodynamic calculation incorporating the kinetic energy of an inextensible polymer chain with the bending energy. To explore the effect of the translation-rotation degrees of freedom, we propose and solve a statistical model of a fully flexible chain of N +1 linked beads which, in the limit of smooth bending, is equivalent to the well-known wormlike chain model. The partition function with the kinetic and bending energies and correlations between orientations of any pair of links and velocities of any pair of beads are found. This solution is precise in the limits of small and large rigidity-to-temperature ratio b /T . The last exact solution is essential as even very "harmless" approximation results in loss of the important effects when the chain is very rigid. For very high b /T , the orientations of different links become fully correlated. Nevertheless, the chain does not go over into a hard rod even in the limit b /T →∞ : While the velocity correlation length diverges, the correlations themselves remain weak and tend to the value ∝T /(N +1 ). The N dependence of the partition function is essentially determined by the kinetic energy contribution. We demonstrate that to obtain the correct energy and entropy in a constrained system, the T derivative of the partition function has to be applied before integration over the constraint-setting variable.

  11. Statistical model of a flexible inextensible polymer chain: The effect of kinetic energy.

    PubMed

    Pergamenshchik, V M; Vozniak, A B

    2017-01-01

    Because of the holonomic constraints, the kinetic energy contribution in the partition function of an inextensible polymer chain is difficult to find, and it has been systematically ignored. We present the first thermodynamic calculation incorporating the kinetic energy of an inextensible polymer chain with the bending energy. To explore the effect of the translation-rotation degrees of freedom, we propose and solve a statistical model of a fully flexible chain of N+1 linked beads which, in the limit of smooth bending, is equivalent to the well-known wormlike chain model. The partition function with the kinetic and bending energies and correlations between orientations of any pair of links and velocities of any pair of beads are found. This solution is precise in the limits of small and large rigidity-to-temperature ratio b/T. The last exact solution is essential as even very "harmless" approximation results in loss of the important effects when the chain is very rigid. For very high b/T, the orientations of different links become fully correlated. Nevertheless, the chain does not go over into a hard rod even in the limit b/T→∞: While the velocity correlation length diverges, the correlations themselves remain weak and tend to the value ∝T/(N+1). The N dependence of the partition function is essentially determined by the kinetic energy contribution. We demonstrate that to obtain the correct energy and entropy in a constrained system, the T derivative of the partition function has to be applied before integration over the constraint-setting variable.

  12. Fragmentation of multiply charged hydrocarbon molecules C{sub n}H{sup q+} (n{<=} 4, q{<=} 9) produced in high-velocity collisions: Branching ratios and kinetic energy release of the H{sup +} fragment

    SciTech Connect

    Beroff, K.; Pino, T.; Carpentier, Y.; Van-Oanh, N. T.; Chabot, M.; Tuna, T.; Martinet, G.; Le Padellec, A.; Lavergne, L.

    2011-09-15

    Fragmentation branching ratios for channels involving H{sup +} emission and associated kinetic energy release of the H{sup +} fragment [KER(H{sup +})] have been measured for multicharged C{sub n}H{sup q+} molecules produced in high velocity (3.6 a.u.) collisions between C{sub n}H{sup +} projectiles and helium atoms. For CH{sup q+} (q{<=} 4) molecules, measured KER(H{sup +}) were found well below predictions of the simple point charge Coulomb model (PCCM) for all q values. Multireference configuration interaction (MRCI) calculations for ground as well as electronic excited states were performed which allowed a perfect interpretation of the CH{sup q+} experimental results for low charges (q = 2-3) as well as for the highest charge (q = 4). In this last case we could show, on the basis of ionization cross sections calculations and experimental measurements performed on the same systems at slightly higher velocity (4.5 a.u.), the prominent role played by inner-shell ionization followed by Auger relaxation and could extract the lifetime of this Auger relaxation giving rise to the best agreement between the experiment and the calculations. For dissociation of C{sub 2}H{sup q+} and C{sub 3}H{sup q+} with the highest charges (q{>=} 5), inner-shell ionization contributed in a prominent way to the ion production. In these two cases it was shown that measured KER(H{sup +}) were in good agreement with PCCM predictions when those were corrected for Auger relaxation with the same Auger lifetime value as in CH{sup 3+}.

  13. Experimental evidence of the decrease of kinetic energy of hadrons in passing through atomic nuclei

    NASA Technical Reports Server (NTRS)

    Strugalski, Z.

    1985-01-01

    Hadrons with kinetic energies higher than the pion production threshold lose their kinetic energies monotonically in traversing atomic nuclei, due to the strong interactions in nuclear matter. This phenomenon is a crude analogy to the energy loss of charged particles in their passage through materials. Experimental evidence is presented.

  14. Energy flow in high speed perforation and cutting

    SciTech Connect

    van Thiel, M.

    1980-10-07

    It is demonstrated that effects of long rod penetrators on targets can be modeled by introducing a high pressure (energy) column on the penetration path in place of the projectile. This energy can be obtained from the kinetic energy of the penetrator; the equations of state of the materials used and a Bernoulli penetration condition. The model is supported by detailed hydro calculations.

  15. High Energy Astrophysics Mission

    NASA Technical Reports Server (NTRS)

    White, Nicholas E.; Ormes, Jonathan F. (Technical Monitor)

    2000-01-01

    The nature of gravity and its relationship to the other three forces and to quantum theory is one of the major challenges facing us as we begin the new century. In order to make progress we must challenge the current theories by observing the effects of gravity under the most extreme conditions possible. Black holes represent one extreme, where the laws of physics as we understand them break down. The Universe as whole is another extreme, where its evolution and fate is dominated by the gravitational influence of dark matter and the nature of the Cosmological constant. The early universe represents a third extreme, where it is thought that gravity may somehow be unified with the other forces. NASA's "Cosmic Journeys" program is part of a NASA/NSF/DoE tri-agency initiative designed to observe the extremes of gravity throughout the universe. This program will probe the nature of black holes, ultimately obtaining a direct image of the event horizon. It will investigate the large scale structure of the Universe to constrain the location and nature of dark matter and the nature of the cosmological constant. Finally it will search for and study the highest energy processes, that approach those found in the early universe. I will outline the High Energy Astrophysics part of this program.

  16. High energy physics

    SciTech Connect

    Kernan, A.; Shen, B.C.; Ma, E.

    1997-07-01

    This proposal is for the continuation of the High Energy Physics program at the University of California at Riverside. In hadron collider physics the authors will complete their transition from experiment UA1 at CERN to the DZERO experiment at Fermilab. On experiment UA1 their effort will concentrate on data analysis at Riverside. At Fermilab they will coordinate the high voltage system for all detector elements. They will also carry out hardware/software development for the D0 muon detector. The TPC/Two-Gamma experiment has completed its present phase of data-taking after accumulating 160 pb{sup {minus}}1 of luminosity. The UC Riverside group will continue data and physics analysis and make minor hardware improvement for the high luminosity run. The UC Riverside group is participating in design and implementation of the data acquisition system for the OPAL experiment at LEP. Mechanical and electronics construction of the OPAL hadron calorimeter strip readout system is proceeding on schedule. Data analysis and Monte Carlo detector simulation efforts are proceeding in preparation for the first physics run when IEP operation comenses in fall 1989.

  17. Redistribution of carbonyl stretch mode energy in isolated and solvated N-methylacetamide: Kinetic energy spectral density analyses

    NASA Astrophysics Data System (ADS)

    Jeon, Jonggu; Cho, Minhaeng

    2011-12-01

    The vibrational energy transfer from the excited carbonyl stretch mode in N-deuterated N-methylacetamide (NMA-d), both in isolation and in a heavy water cluster, is studied with nonequilibrium molecular dynamics (NEMD) simulations, employing a quantum mechanical/molecular mechanical (QM/MM) force field at the semiempirical PM3 level. The nonequilibrium ensemble of vibrationally excited NMA-d is prepared by perturbing the positions and velocities of the carbonyl C and O atoms and its NEMD trajectories are obtained with a leap-frog algorithm properly modified for the initial perturbation. In addition to the time-domain analysis of the kinetic and potential energies, a novel method for the spectral analysis of the atomic kinetic energies is developed, in terms of the spectral density of kinetic energy, which provides the time-dependent changes of the frequency-resolved kinetic energies without the complications of normal mode analysis at every MD time step. Due to the QM description of the solute electronic structure, the couplings among the normal modes are captured more realistically than with classical force fields. The energy transfer in the isolated NMA-d is found to proceed first from the carbonyl bond to other modes with time scales of 3 ps or less, and then among the other modes over 3-21 ps. In the solvated NMA-d, most of the excess energy is first transferred to other intramolecular modes within 5 ps, which is subsequently dissipated to solvent with 7-19 ps time scales. The contribution of the direct energy transfer from the carbonyl bond to solvent was only 5% with ˜7 ps time scale. Solvent reorganization that leads to destabilization of the electrostatic interactions is found to be crucial in the long time relaxation of the excess energy, while the water intramolecular modes do not contribute significantly. Detailed mode-specific energy transfer pathways are deduced for the isolated and solvated NMA-d and they show that the energy transfer in NMA-d is a

  18. Redistribution of carbonyl stretch mode energy in isolated and solvated N-methylacetamide: kinetic energy spectral density analyses.

    PubMed

    Jeon, Jonggu; Cho, Minhaeng

    2011-12-07

    The vibrational energy transfer from the excited carbonyl stretch mode in N-deuterated N-methylacetamide (NMA-d), both in isolation and in a heavy water cluster, is studied with nonequilibrium molecular dynamics (NEMD) simulations, employing a quantum mechanical/molecular mechanical (QM∕MM) force field at the semiempirical PM3 level. The nonequilibrium ensemble of vibrationally excited NMA-d is prepared by perturbing the positions and velocities of the carbonyl C and O atoms and its NEMD trajectories are obtained with a leap-frog algorithm properly modified for the initial perturbation. In addition to the time-domain analysis of the kinetic and potential energies, a novel method for the spectral analysis of the atomic kinetic energies is developed, in terms of the spectral density of kinetic energy, which provides the time-dependent changes of the frequency-resolved kinetic energies without the complications of normal mode analysis at every MD time step. Due to the QM description of the solute electronic structure, the couplings among the normal modes are captured more realistically than with classical force fields. The energy transfer in the isolated NMA-d is found to proceed first from the carbonyl bond to other modes with time scales of 3 ps or less, and then among the other modes over 3-21 ps. In the solvated NMA-d, most of the excess energy is first transferred to other intramolecular modes within 5 ps, which is subsequently dissipated to solvent with 7-19 ps time scales. The contribution of the direct energy transfer from the carbonyl bond to solvent was only 5% with ~7 ps time scale. Solvent reorganization that leads to destabilization of the electrostatic interactions is found to be crucial in the long time relaxation of the excess energy, while the water intramolecular modes do not contribute significantly. Detailed mode-specific energy transfer pathways are deduced for the isolated and solvated NMA-d and they show that the energy transfer in NMA-d is a

  19. Wave-particle energy exchange directly observed in a kinetic Alfvén-branch wave

    NASA Astrophysics Data System (ADS)

    Gershman, Daniel J.; F-Viñas, Adolfo; Dorelli, John C.; Boardsen, Scott A.; Avanov, Levon A.; Bellan, Paul M.; Schwartz, Steven J.; Lavraud, Benoit; Coffey, Victoria N.; Chandler, Michael O.; Saito, Yoshifumi; Paterson, William R.; Fuselier, Stephen A.; Ergun, Robert E.; Strangeway, Robert J.; Russell, Christopher T.; Giles, Barbara L.; Pollock, Craig J.; Torbert, Roy B.; Burch, James L.

    2017-03-01

    Alfvén waves are fundamental plasma wave modes that permeate the universe. At small kinetic scales, they provide a critical mechanism for the transfer of energy between electromagnetic fields and charged particles. These waves are important not only in planetary magnetospheres, heliospheres and astrophysical systems but also in laboratory plasma experiments and fusion reactors. Through measurement of charged particles and electromagnetic fields with NASA's Magnetospheric Multiscale (MMS) mission, we utilize Earth's magnetosphere as a plasma physics laboratory. Here we confirm the conservative energy exchange between the electromagnetic field fluctuations and the charged particles that comprise an undamped kinetic Alfvén wave. Electrons confined between adjacent wave peaks may have contributed to saturation of damping effects via nonlinear particle trapping. The investigation of these detailed wave dynamics has been unexplored territory in experimental plasma physics and is only recently enabled by high-resolution MMS observations.

  20. Kinetic ways of tailoring phases in high entropy alloys

    PubMed Central

    He, Feng; Wang, Zhijun; Li, Yiyan; Wu, Qingfeng; Li, Junjie; Wang, Jincheng; Liu, C. T.

    2016-01-01

    The comprehensive performance of high entropy alloys (HEAs) depends on the phase selection significantly. However, up to now, investigations of the phase selection in HEAs mainly focused on the thermodynamic equilibrium phase, while kinetic ways of tailoring the phases in HEAs are seldom considered. In HEAs, the kinetics of sluggish diffusion and the numerous possible phases make the kinetics of phase transformation more complex and intriguing. Here, the kinetic effect in CoCrFeNiTi0.4 HEAs was investigated to reveal the possibility of controlling phase selection via kinetic ways for HEAs. The σ, γ′ and R phases in the CoCrFeNiTi0.4 HEA can be controlled under different cooling rate both in solidification and solid transformation. The theoretical analyses revealed the kinetic effect on phase selection. The method proposed here, tailoring the phases with different kinetic ways, could be used to prepare promising HEAs with very rich composition design. PMID:27687976

  1. When and how does a prominence-like jet gain kinetic energy?

    SciTech Connect

    Liu, Jiajia; Liu, Rui; Zhang, Quanhao; Liu, Kai; Shen, Chenglong; Wang, S.; Wang, Yuming

    2014-02-20

    A jet is a considerable amount of plasma being ejected from the chromosphere or lower corona into the higher corona and is a common phenomenon. Usually, a jet is triggered by a brightening or a flare, which provides the first driving force to push plasma upward. In this process, magnetic reconnection is thought to be the mechanism to convert magnetic energy into thermal, nonthermal, and kinetic energies. However, most jets could reach an unusual high altitude and end much later than the end of its associated flare. This fact implies that there is another way to continuously transfer magnetic energy into kinetic energy even after the reconnection. The picture described above is well known in the community, but how and how much magnetic energy is released through a way other than reconnection is still unclear. By studying a prominence-like jet observed by SDO/AIA and STEREO-A/EUVI, we find that the continuous relaxation of the post-reconnection magnetic field structure is an important process for a jet to climb up higher than it could through only reconnection. The kinetic energy of the jet gained through the relaxation is 1.6 times that gained from the reconnection. The resultant energy flux is hundreds of times larger than the flux required for the local coronal heating, suggesting that such jets are a possible source to keep the corona hot. Furthermore, rotational motions appear all the time during the jet. Our analysis suggests that torsional Alfvén waves induced during reconnection could not be the only mechanism to release magnetic energy and drive jets.

  2. Kinetic energy distributions of sputtered neutral aluminum clusters: Al--Al[sub 6

    SciTech Connect

    Coon, S.R.; Calaway, W.F.; Pellin, M.J. ); Curlee, G.A. . Dept. of Physics); White, J.M. . Dept. of Chemistry and Biochemistry)

    1992-01-01

    Neutral aluminum clusters sputtered from polycrystalline aluminum were analyzed by laser postionization time-of-flight (TOF) mass spectrometry. The kinetic energy distributions of Al through Al[sub 6] were measured by a neutrals time-of-flight technique. The interpretation of laser postionization TOF data to extract velocity and energy distributions is presented. The aluminum cluster distributions are qualitatively similar to previous copper cluster distribution measurements from our laboratory. In contrast to the steep high energy tails predicted by the single- or multiple- collision models, the measured cluster distributions have high energy power law dependences in the range of E[sup [minus]3] to E[sup [minus]4.5]. Correlated collision models may explain the substantial abundance of energetic clusters that are observed in these experiments. Possible influences of cluster fragmentation on the distributions are discussed.

  3. Kinetic energy distributions of sputtered neutral aluminum clusters: Al--Al{sub 6}

    SciTech Connect

    Coon, S.R.; Calaway, W.F.; Pellin, M.J.; Curlee, G.A.; White, J.M.

    1992-12-01

    Neutral aluminum clusters sputtered from polycrystalline aluminum were analyzed by laser postionization time-of-flight (TOF) mass spectrometry. The kinetic energy distributions of Al through Al{sub 6} were measured by a neutrals time-of-flight technique. The interpretation of laser postionization TOF data to extract velocity and energy distributions is presented. The aluminum cluster distributions are qualitatively similar to previous copper cluster distribution measurements from our laboratory. In contrast to the steep high energy tails predicted by the single- or multiple- collision models, the measured cluster distributions have high energy power law dependences in the range of E{sup {minus}3} to E{sup {minus}4.5}. Correlated collision models may explain the substantial abundance of energetic clusters that are observed in these experiments. Possible influences of cluster fragmentation on the distributions are discussed.

  4. FSU High Energy Physics

    SciTech Connect

    Prosper, Harrison B.; Adams, Todd; Askew, Andrew; Berg, Bernd; Blessing, Susan K.; Okui, Takemichi; Owens, Joseph F.; Reina, Laura; Wahl, Horst D.

    2014-12-01

    The High Energy Physics group at Florida State University (FSU), which was established in 1958, is engaged in the study of the fundamental constituents of matter and the laws by which they interact. The group comprises theoretical and experimental physicists, who sometimes collaborate on projects of mutual interest. The report highlights the main recent achievements of the group. Significant, recent, achievements of the group’s theoretical physicists include progress in making precise predictions in the theory of the Higgs boson and its associated processes, and in the theoretical understanding of mathematical quantities called parton distribution functions that are related to the structure of composite particles such as the proton. These functions are needed to compare data from particle collisions, such as the proton-proton collisions at the CERN Large Hadron Collider (LHC), with theoretical predictions. The report also describes the progress in providing analogous functions for heavy nuclei, which find application in neutrino physics. The report highlights progress in understanding quantum field theory on a lattice of points in space and time (an area of study called lattice field theory), the progress in constructing several theories of potential new physics that can be tested at the LHC, and interesting new ideas in the theory of the inflationary expansion of the very early universe. The focus of the experimental physicists is the Compact Muon Solenoid (CMS) experiment at CERN. The report, however, also includes results from the D0 experiment at Fermilab to which the group made numerous contributions over a period of many years. The experimental group is particularly interested in looking for new physics at the LHC that may provide the necessary insight to extend the standard model (SM) of particle physics. Indeed, the search for new physics is the primary task of contemporary particle physics, one motivated by the need to explain certain facts, such as the

  5. High energy physics

    SciTech Connect

    Kernan, A.; Shen, B.C.; Ma, E.

    1997-07-01

    This proposal is for the continuation of the High Energy Physics Program at the University of California, Riverside. In 1990, we will concentrate on analysis of LEP data from the OPAL detector. We expect to record 10{sup 5} Z`s by the end of 1989 and 10{sup 6} in 1990. This data will be used to measure the number of quark-lepton families in the universe. In the second half of 1990 we will also be occupied with the installation of the D-Zero detector in the Tevatron Collider and the preparation of software for the 1991 run. A new initiative made possible by generous university support is a laboratory for detector development at UCR. The focus will be on silicon strip tracking detectors both for the D-Zero upgrade and for SSC physics. The theory program will pursue further various mass-generating radiative mechanisms for understanding small quark and lepton masses as well as some novel phenomenological aspects of supersymmetry.

  6. High Energy Density Capacitors

    SciTech Connect

    2010-07-01

    BEEST Project: Recapping is developing a capacitor that could rival the energy storage potential and price of today’s best EV batteries. When power is needed, the capacitor rapidly releases its stored energy, similar to lightning being discharged from a cloud. Capacitors are an ideal substitute for batteries if their energy storage capacity can be improved. Recapping is addressing storage capacity by experimenting with the material that separates the positive and negative electrodes of its capacitors. These separators could significantly improve the energy density of electrochemical devices.

  7. RNA folding pathways and kinetics using 2D energy landscapes.

    PubMed

    Senter, Evan; Dotu, Ivan; Clote, Peter

    2015-01-01

    RNA folding pathways play an important role in various biological processes, such as (i) the hok/sok (host-killing/suppression of killing) system in E. coli to check for sufficient plasmid copy number, (ii) the conformational switch in spliced leader (SL) RNA from Leptomonas collosoma, which controls trans splicing of a portion of the '5 exon, and (iii) riboswitches--portions of the 5' untranslated region of messenger RNA that regulate genes by allostery. Since RNA folding pathways are determined by the energy landscape, we describe a novel algorithm, FFTbor2D, which computes the 2D projection of the energy landscape for a given RNA sequence. Given two metastable secondary structures A, B for a given RNA sequence, FFTbor2D computes the Boltzmann probability p(x, y) = Z(x,y)/Z that a secondary structure has base pair distance x from A and distance y from B. Using polynomial interpolationwith the fast Fourier transform,we compute p(x, y) in O(n(5)) time and O(n(2)) space, which is an improvement over an earlier method, which runs in O(n(7)) time and O(n(4)) space. FFTbor2D has potential applications in synthetic biology, where one might wish to design bistable switches having target metastable structures A, B with favorable pathway kinetics. By inverting the transition probability matrix determined from FFTbor2D output, we show that L. collosoma spliced leader RNA has larger mean first passage time from A to B on the 2D energy landscape, than 97.145% of 20,000 sequences, each having metastable structures A, B. Source code and binaries are freely available for download at http://bioinformatics.bc.edu/clotelab/FFTbor2D. The program FFTbor2D is implemented in C++, with optional OpenMP parallelization primitives.

  8. Aluminium-oxide wires for superconducting high kinetic inductance circuits

    NASA Astrophysics Data System (ADS)

    Rotzinger, H.; Skacel, S. T.; Pfirrmann, M.; Voss, J. N.; Münzberg, J.; Probst, S.; Bushev, P.; Weides, M. P.; Ustinov, A. V.; Mooij, J. E.

    2017-02-01

    We investigate thin films of conducting aluminium-oxide, also known as granular aluminium, as a material for superconducting high quality, high kinetic inductance circuits. The films are deposited by an optimised reactive DC magnetron sputter process and characterised using microwave measurement techniques at milli-Kelvin temperatures. We show that, by precise control of the reactive sputter conditions, a high room temperature sheet resistance and therefore high kinetic inductance at low temperatures can be obtained. For a coplanar waveguide resonator with 1.5 kΩ sheet resistance and a kinetic inductance fraction close to unity, we measure a quality factor in the order of 700 000 at 20 mK. Furthermore, we observe a sheet resistance reduction by gentle heat treatment in air. This behaviour is exploited to study the kinetic inductance change using the microwave response of a coplanar wave guide resonator. We find the correlation between the kinetic inductance and the sheet resistance to be in good agreement with theoretical expectations.

  9. A Comparison of Kinetic Energy and Momentum in Special Relativity and Classical Mechanics

    ERIC Educational Resources Information Center

    Riggs, Peter J.

    2016-01-01

    Kinetic energy and momentum are indispensable dynamical quantities in both the special theory of relativity and in classical mechanics. Although momentum and kinetic energy are central to understanding dynamics, the differences between their relativistic and classical notions have not always received adequate treatment in undergraduate teaching.…

  10. The Rainfall and Rainfall Kinetic Energy Intensity-Duration of Landslides and Debris flow in Taiwan

    NASA Astrophysics Data System (ADS)

    Chang, Jui-Ming; Chen, Hongey

    2016-04-01

    This research used Joss-Waldvogel Disdrometers (JWD) which set in Shiment catchment, Northern Taiwan and Chishan catchment, Southern Taiwan to record rainfall kinetic energy data, to find the relationship between rainfall kinetic energy and rainfall intensity in these two areas. The distance between the two areas is less than 150 km. These data help the researchers and showed that the equations of relationship were ekN =28.7* (1-0.7027*exp(-0.0395*I)) and ekS=27.4*(1-0.5954*exp(-0.0345*I)). Generally, rainfall kinetic energy in Northern Taiwan is higher than in Southern Taiwan during rainfall period. Also, the occurring time and rainfall records of 143 landslide events from 2006 to 2012 were analyzed. The rainfall-intensity (I-D) relationship could be used to build rainfall threshold which were IN=15.13 D-0.28 and IS=47.58 D-0.35. In brief, the rainfall feature in landslide of Northern Taiwan had low rainfall intensity, long rainfall duration and low average accumulative rainfall. By combining rainfall kinetic energy and rainfall threshold, rainfall kinetic energy threshold could be established, which were ¯E N=13.83 D-0.04 and ¯E S =15.59 D-0.02. The results showed that not only for rainfall but also for rainfall kinetic energy threshold, the values of thresholds in North were lower than those in South. Due to impaction energy of rainfall to ground surface, rainfall kinetic energy would not forever increase. Therefore, rainfall kinetic energy threshold is also a useful tool for landslide warning. Key words: Rainfall kinetic energy, Rainfall threshold, Rainfall kinetic energy threshold, Landslide

  11. Vertical kinetic energy and turbulent dissipation in the ocean

    NASA Astrophysics Data System (ADS)

    Thurnherr, A. M.; Kunze, E.; Toole, J. M.; St. Laurent, L.; Richards, K. J.; Ruiz-Angulo, A.

    2015-09-01

    Oceanic internal waves are closely linked to turbulence. Here a relationship between vertical wave number (kz) spectra of fine-scale vertical kinetic energy (VKE) and turbulent dissipation ɛ is presented using more than 250 joint profiles from five diverse dynamic regimes, spanning latitudes between the equator and 60°. In the majority of the spectra VKE varies as kz-2. Scaling VKE with √ɛ collapses the off-equatorial spectra to within √2 but underestimates the equatorial spectrum. The simple empirical relationship between VKE and ɛ fits the data better than a common shear-and-strain fine-scale parameterization, which significantly underestimates ɛ in the two data sets that are least consistent with the Garrett-Munk (GM) model. The new relationship between fine-scale VKE and dissipation rate can be interpreted as an alternative, single-parameter scaling for turbulent dissipation in terms of fine-scale internal wave vertical velocity that requires no reference to the GM model spectrum.

  12. NonBoussinesq effects on vorticity and kinetic energy production

    NASA Astrophysics Data System (ADS)

    Ravichandran, S.; Dixit, Harish; Govindarajan, Rama

    2015-11-01

    The Boussinesq approximation, commonly employed in weakly compressible or incompressible flows, neglects changes in inertia due to changes in the density. However, the nonBoussinesq terms can lead to a kind of centrifugal instability for small but sharp density variations, and therefore cannot be neglected under such circumstances (see, e.g., DIXIT & GOVINDARAJAN, JFM , 2010, 415). Here, we study the evolution of a light-cored Gaussian vortex and find that the nonBoussinesq terms can lead to significant changes in how vortices evolve. The problem is governed by three nondimensional numbers--Reynolds number (i.e. viscosity), Atwood number, and a ratio of gravitational and centrifugal Froude numbers. We find that the production of kinetic energy and vorticity in a light-cored Gaussian vortex are affected significantly by the nonBoussinesq terms, and varies non-monotonically with the parameters of the problem. In general, these nonBoussinesq effects depend both on the strength of gravity and on the Reynolds number associated with the initial vortex.

  13. High Pressure Solution Kinetics of Metal Complexes.

    ERIC Educational Resources Information Center

    Suvachittanont, Surapong

    1983-01-01

    Describes use of activation volumes derived from the effect of pressure reaction rates in aiding the understanding of reaction mechanism. Topics discussed include determination and interpretation of activation volumes, high pressure equipment/techniques, and application of activation volumes in mechanistic elucidation of several inorganic…

  14. Neutron emission effects on final fragments mass and kinetic energy distribution from low energy fission of 34U

    NASA Astrophysics Data System (ADS)

    Montoya, M.; Rojas, J.; Lobato, I.

    2008-12-01

    The kinetic energy distribution as a function of mass of final fragments (m) from low energy fission of $^{234}U$, measured with the Lohengrin spectrometer by Belhafaf et al. presents a peak around m=108 and another around m = 122. The authors attribute the first peak to the evaporation of a large number of neutrons around the corresponding mass number; and the second peak to the distribution of the primary fragment kinetic energy. Nevertheless, the theoretical calculations related to primary distribution made by Faust et al. do not result in a peak around m = 122. In order to clarify this apparent controversy, we have made a numerical experiment in which the masses and the kinetic energy of final fragments are calculated, assuming an initial distribution of the kinetic energy without peaks on the standard deviation as function of fragment mass. As a result we obtain a pronounced peak on the standard deviation of the kinetic energy distribution around m = 109, a depletion from m = 121 to m = 129, and an small peak around m = 122, which is not as big as the measured by Belhafaf et al. Our simulation also reproduces the experimental results on the yield of the final mass, the average number of emitted neutrons as a function of the provisional mass (calculated from the values of the final kinetic energy of the complementary fragments) and the average value of fragment kinetic energy as a function of the final mass.

  15. High Energy Colliders

    NASA Astrophysics Data System (ADS)

    Palmer, R. B.; Gallardo, J. C.

    INTRODUCTION PHYSICS CONSIDERATIONS GENERAL REQUIRED LUMINOSITY FOR LEPTON COLLIDERS THE EFFECTIVE PHYSICS ENERGIES OF HADRON COLLIDERS HADRON-HADRON MACHINES LUMINOSITY SIZE AND COST CIRCULAR e^{+}e^- MACHINES LUMINOSITY SIZE AND COST e^{+}e^- LINEAR COLLIDERS LUMINOSITY CONVENTIONAL RF SUPERCONDUCTING RF AT HIGHER ENERGIES γ - γ COLLIDERS μ ^{+} μ^- COLLIDERS ADVANTAGES AND DISADVANTAGES DESIGN STUDIES STATUS AND REQUIRED R AND D COMPARISION OF MACHINES CONCLUSIONS DISCUSSION

  16. From the Kinetic Energy Recovery System to the Thermo-Hydraulic Hybrid Motor Vehicle

    NASA Astrophysics Data System (ADS)

    Cristescu, Corneliu; Drumea, Petrin; Guta, Dragos; Dumitrescu, Catalin

    2011-12-01

    The paper presents some theoretical and experimental results obtained by the Hydraulics and Pneumatics Research Institute INOE 2000-IHP with its partners, regarding the creating of one hydraulic system able to recovering the kinetic energy of the motor vehicles, in the braking phases, and use this recovered energy in the starting and accelerating phases. Also, in the article is presented a testing stand, which was especially designed for testing the hydraulic system for recovery the kinetic energy. Through mounting of the kinetic energy recovering hydraulic system, on one motor vehicle, this vehicle became a thermo-hydraulic hybrid vehicle. Therefore, the dynamic behavior was analyzed for the whole hybrid motor vehicle, which includes the energy recovery system. The theoretical and experimental results demonstrate the possible performances of the hybrid vehicle and that the kinetic energy recovery hydraulic systems are good means to increase energy efficiency of the road motor vehicles and to decrease of the fuel consumption.

  17. HIGH PRESSURE COAL COMBUSTION KINETICS PROJECT

    SciTech Connect

    Chris Guenther, Ph.D.

    2003-01-28

    SRI has completed the NBFZ test program, made modification to the experimental furnace for the HPBO test. The NBFZ datasets provide the information NEA needs to simulate the combustion and fuel-N conversion with detailed chemical reaction mechanisms. BU has determined a linear swell of 1.55 corresponding to a volumetric increase of a factor of 3.7 and a decrease in char density by the same factor. These results are highly significant, and indicate significantly faster burnout at elevated pressure due to the low char density and large diameter.

  18. Total Kinetic Energy Release in the Fast Neutron Induced Fission of 235U

    NASA Astrophysics Data System (ADS)

    Loveland, Walter; Yanez, Ricardo

    2016-09-01

    We have measured the total kinetic energy (TKE) release, its variance and associated fission product mass distributions for the neutron induced fission of 235U for En = 2-90 MeV using the 2E method. The neutron energies were determined,event by event, by time of flight measurements with the white spectrum neutron beam from LANSCE. The TKE decreases with increasing neutron energy. This TKE decrease is due to increasing symmetric fission (and decreasing asymmetric fission)with increasing neutron energy, in accord with Brosa model predictions. Our measurement of the TKE release for 235U(nth,f) is in excellent agreement with the known value, indicating our measurements are absolute measurements. The TKE variances are sensitive indicators of nth chance fission. Due to the occurrence of nth chance fission and pre-fission neutron emission, the average fissioning system and its excitation energy is a complex function of the incident neutron energy. Detailed comparisons of our data with previous measurements will be made. This work was supported, in part, by the Director, Office of Energy Research, Division of Nuclear Physics of the Office of High Energy and Nuclear Physics of the U.S. Department of Energy under Grant DE-SC0014380.

  19. Spectroscopy and kinetics of combustion gases at high temperatures

    SciTech Connect

    Hanson, R.K.; Bowman, C.T.

    1993-12-01

    This program involves two complementary activities: (1) development and application of cw ring dye laser absorption methods for sensitive detection of radical species and measurement of fundamental spectroscopic parameters at high temperatures; and (2) shock tube studies of reaction kinetics relevant to combustion. Species currently under investigation in the spectroscopic portion of the research include NO and CH{sub 3}; this has necessitated the continued operated at wavelengths in the range 210-230 nm. Shock tube studies of reaction kinetics currently are focussed on reactions involving CH{sub 3} radicals.

  20. High Level Ab Initio Kinetics as a Tool for Astrochemistry

    NASA Astrophysics Data System (ADS)

    Klippenstein, Stephen

    2015-05-01

    We will survey the application of ab initio theoretical kinetics to reactions of importance to astrochemistry. Illustrative examples will be taken from our calculations for (i) interstellar chemistry, (ii) Titan's atmospheric chemistry, and (iii) the chemistry of extrasolar giant planets. The accuracy of various aspects of the calculations will be summarized including (i) the underlying ab initio electronic structure calculations, (ii) the treatment of the high pressure recombination process, and (iii) the treatment of the pressure dependence of the kinetics. The applications will consider the chemistry of phosphorous on giant planets, the kinetics of water dimerization, the chemistry of nitrogen on Titan's atmosphere, as well as various reactions of interstellar chemistry interest such as the recombination of OH with H, and O(3P) reacting with C2H5, CH2, and CCS. Chemical Sciences and Engineering Division.

  1. Materials implications of advanced thermal and kinetic energy threats

    NASA Astrophysics Data System (ADS)

    Fitpatrick, R.; Mescall, J.

    1983-05-01

    The behavior of materials subjected to laser radiation rather than issues of target acquisition, pointing and tracking, fire control, and damage recognition are discussed. These target acquisition and fire control requirements represents extremely difficult technological problems that must be solved if the Laser is ever to be used as a weapon against hard targets. Questions that must be resolved are outlined as follows: Can laser beams be propagated over large distances along predictable paths? Can available active and passive countermeasures be overcome? Is there a place for large scale, high power, high value directed energy weapons on the battlefield? While these questions are being addressed, the Army materials community is developing a data base on materials and structures vulnerability. This data base will not only serve the hardening community, which has the task of offering protection against directed energy, but also will help the weapon developers determine the effectiveness of their systems.

  2. Fragment mass and kinetic-energy distributions from spontaneous fission of the neutron-deficient isotopes, 1. 2-s /sup 246/Fm and 38-s /sup 248/Fm

    SciTech Connect

    Hoffman, D.; Lee, D.; Ghiorso, A.; Nurmia, M.; Aleklett, K.

    1980-10-01

    We have measured the mass and kinetic-energy distributions for fragments from the spontaneous fission of 1.2-s /sup 246/Fm and 38-s /sup 248/Fm. The mass distributions are highly asymmetric and the average total kinetic energies of 199 +- 4 MeV and 198 +- 4 MeV, respectively, are consistent with systematics for lower Z actinides. Their properties are in contrast to those of /sup 258/Fm and /sup 259/Fm, whose spontaneous fission results in narrowly symmetric mass distributions accompanied by unusually high total kinetic energies.

  3. Spectral study of wintertime kinetic energy of the Northern Hemisphere in the troposphere

    NASA Technical Reports Server (NTRS)

    Lee, H. N.; Zhao, Z.; Kao, S. K.

    1983-01-01

    Characteristics of the kinetic energy of wind fields at various pressure levels were analyzed, and significant wavenumbers in the wavenumber-frequency domain were identified. The nonlinear interaction terms of the kinetic energy equation were examined, and the distribution of the kinetic energy at the 850 mb, 500 mb, and 200 mb levels was calculated. A 5 deg latitude-longitude square grid was used, with NMC data for the 1975-1976 winter in the 20-60 deg N at 500 mb and 20-85 deg N for the 200 mb and 850 mb levels. The kinetic energy distribution was determined to be geography-dependent, with wavenumbers 6-9 westerly waves in the midfrequency range contributing significantly to kinetic energy maxima over the North Pacific and the east coast of North America. The contribution of the nonlinear interactions of these waves, which correspond to the longitudinal convergence of the kinetic energy flux, was found to be larger than the meridional convergence of the kinetic energy flux, and to occur mainly between 30-50 deg N. The nonlinear interactions were a negative contribution over the North Pacific at the 200 mb level.

  4. High temperature steam gasification of solid wastes: Characteristics and kinetics

    NASA Astrophysics Data System (ADS)

    Gomaa, Islam Ahmed

    Greater use of renewable energy sources is of pinnacle importance especially with the limited reserves of fossil fuels. It is expected that future energy use will have increased utilization of different energy sources, including biomass, municipal solid wastes, industrial wastes, agricultural wastes and other low grade fuels. Gasification is a good practical solution to solve the growing problem of landfills, with simultaneous energy extraction and nonleachable minimum residue. Gasification also provides good solution to the problem of plastics and rubber in to useful fuel. The characteristics and kinetics of syngas evolution from the gasification of different samples is examined here. The characteristics of syngas based on its quality, distribution of chemical species, carbon conversion efficiency, thermal efficiency and hydrogen concentration has been examined. Modeling the kinetics of syngas evolution from the process is also examined. Models are compared with the experimental results. Experimental results on the gasification and pyrolysis of several solid wastes, such as, biomass, plastics and mixture of char based and plastic fuels have been provided. Differences and similarities in the behavior of char based fuel and a plastic sample has been discussed. Global reaction mechanisms of char based fuel as well polystyrene gasification are presented based on the characteristic of syngas evolution. The mixture of polyethylene and woodchips gasification provided superior results in terms of syngas yield, hydrogen yield, total hydrocarbons yield, energy yield and apparent thermal efficiency from polyethylene-woodchips blends as compared to expected weighed average yields from gasification of the individual components. A possible interaction mechanism has been established to explain the synergetic effect of co-gasification of woodchips and polyethylene. Kinetics of char gasification is presented with special consideration of sample temperature, catalytic effect of ash

  5. High energy forming facility

    NASA Technical Reports Server (NTRS)

    Ciurlionis, B.

    1967-01-01

    Watertight, high-explosive forming facility, 25 feet in diameter and 15 feet deep, withstands repeated explosions of 10 pounds of TNT equivalent. The shell is fabricated of high strength steel and allows various structural elements to deform or move elastically and independently while retaining structural integrity.

  6. Kinetic energy releases of small amino acids upon interaction with keV ions

    NASA Astrophysics Data System (ADS)

    Bari, S.; Alvarado, F.; Postma, J.; Sobocinski, P.; Hoekstra, R.; Schlathölter, T.

    2009-01-01

    In chromatin, DNA is tightly packed into one complex together with histone and non-histone proteins. These proteins are known to protect the DNA against indirect and to some extent even direct radiation damage. Radiation action upon amino acids is thus one of the primary steps in biological radiation action. In this paper we investigate the ionization and fragmentation of the gas-phase amino acids glycine, alanine and valine upon interaction with keV α-particles. High resolution coincidence time-of-flight mass spectrometry is used to determine the dominant fragmentation channels as well as fragment kinetic energies.

  7. Statistical properties of kinetic and total energy densities in reverberant spaces.

    PubMed

    Jacobsen, Finn; Molares, Alfonso Rodríguez

    2010-04-01

    Many acoustical measurements, e.g., measurement of sound power and transmission loss, rely on determining the total sound energy in a reverberation room. The total energy is usually approximated by measuring the mean-square pressure (i.e., the potential energy density) at a number of discrete positions. The idea of measuring the total energy density instead of the potential energy density on the assumption that the former quantity varies less with position than the latter goes back to the 1930s. However, the phenomenon was not analyzed until the late 1970s and then only for the region of high modal overlap, and this analysis has never been published. Moreover, until fairly recently, measurement of the total sound energy density required an elaborate experimental arrangement based on finite-difference approximations using at least four amplitude and phase matched pressure microphones. With the advent of a three-dimensional particle velocity transducer, it has become somewhat easier to measure total rather than only potential energy density in a sound field. This paper examines the ensemble statistics of kinetic and total sound energy densities in reverberant enclosures theoretically, experimentally, and numerically.

  8. Energy spectra of high energy atmospheric neutrinos

    NASA Technical Reports Server (NTRS)

    Mitsui, K.; Minorikawa, Y.

    1985-01-01

    Focusing on high energy neutrinos ( or = 1 TeV), a new calculation of atmospheric neutrino intensities was carried out taking into account EMC effects observed in P-A collisions by accelerator, recent measurement of primary cosmic ray spectrum and results of cosmic ray muon spectrum and charge ratio. Other features of the present calculation are (1) taking into account kinematics of three body decays of kaons and charm particles in diffusion equations and (2) taking into account energy dependence of kaon production.

  9. High-temperature steam oxidation kinetics of the E110G cladding alloy

    NASA Astrophysics Data System (ADS)

    Király, Márton; Kulacsy, Katalin; Hózer, Zoltán; Perez-Feró, Erzsébet; Novotny, Tamás

    2016-07-01

    In the course of recent years, several experiments were performed at MTA EK (Centre for Energy Research, Hungarian Academy of Sciences) on the isothermal high-temperature oxidation of the improved Russian cladding alloy E110G in steam/argon atmosphere. Using these data and designing additional supporting experiments, the oxidation kinetics of the E110G alloy was investigated in a wide temperature range, between 600 °C and 1200 °C. For short durations (below 500 s) or high temperatures (above 1065 °C) the oxidation kinetics was found to follow a square-root-of-time dependence, while for longer durations and in the intermediate temperature range (800-1000 °C) it was found to approach a cube-root-of-time dependence rather than a square-root one. Based on the results a new best-estimate and a conservative oxidation kinetics model were created.

  10. Alternative analytically calculation procedure of two-center kinetic energy integral in molecular coordinate system

    NASA Astrophysics Data System (ADS)

    Mamedov, Bahtiyar Akber; Copuroglu, Ebru

    2017-02-01

    By using the Löwdin-α function method, we have analytically calculated the two-center kinetic energy integrals over Slater type orbitals (STOs). The two-center kinetic energy integrals are presented in terms of the two-center overlap integrals. A new approach is applicable to accurate calculations of two-center kinetic energy integral over STOs for arbitrary values of scaling parameters and interatomic distances. Obtained results show that the proposed method is easy to apply to the real systems, and has better calculation CPU time with compared to the existing approximations.

  11. Bidirectional Energy Cascades and the Origin of Kinetic Alfvenic and Whistler Turbulence in the Solar Wind

    NASA Technical Reports Server (NTRS)

    Che, H.; Goldstein, M. L.; Vinas, A. F.

    2014-01-01

    The observed steep kinetic scale turbulence spectrum in the solar wind raises the question of how that turbulence originates. Observations of keV energetic electrons during solar quiet time suggest them as a possible source of free energy to drive kinetic turbulence. Using particle-in-cell simulations, we explore how the free energy released by an electron two-stream instability drives Weibel-like electromagnetic waves that excite wave-wave interactions. Consequently, both kinetic Alfvénic and whistler turbulence are excited that evolve through inverse and forward magnetic energy cascades.

  12. Prediction of free turbulent mixing using a turbulent kinetic energy method

    NASA Technical Reports Server (NTRS)

    Harsha, P. T.

    1973-01-01

    Free turbulent mixing of two-dimensional and axisymmetric one- and two-stream flows is analyzed by a relatively simple turbulent kinetic energy method. This method incorporates a linear relationship between the turbulent shear and the turbulent kinetic energy and an algebraic relationship for the length scale appearing in the turbulent kinetic energy equation. Good results are obtained for a wide variety of flows. The technique is shown to be especially applicable to flows with heat and mass transfer, for which nonunity Prandtl and Schmidt numbers may be assumed.

  13. Variational energy principle for compressible, baroclinic flow. 1: First and second variations of total kinetic action

    NASA Technical Reports Server (NTRS)

    Schmid, L. A.

    1977-01-01

    The case of a cold gas in the absence of external force fields is considered. Since the only energy involved is kinetic energy, the total kinetic action (i.e., the space-time integral of the kinetic energy density) should serve as the total free-energy functional in this case, and as such should be a local minimum for all possible fluctuations about stable flow. This conjecture is tested by calculating explicit, manifestly covariant expressions for the first and second variations of the total kinetic action in the context of Lagrangian kinematics. The general question of the correlation between physical stability and the convexity of any action integral that can be interpreted as the total free-energy functional of the flow is discussed and illustrated for the cases of rectillinear and rotating shearing flows.

  14. The role of latent heat in kinetic energy conversions of South Pacific cyclones

    NASA Technical Reports Server (NTRS)

    Kann, Deirdre M.; Vincent, Dayton G.

    1986-01-01

    The four-dimensional behavior of cyclone systems in the South Pacific Convergence Zone (SPCZ) is analyzed. Three cyclone systems, which occurred during the period from January 10-16, 1979, are examined using the data collected during the first special observing period of the FGGE. The effects of latent heating on the life cycles of the cyclones are investigated. Particular attention is given to the conversions of eddy available potential energy to eddy kinetic energy and of mean kinetic energy to eddy kinetic energy. The net radiation profile, sensible heat flux, total field of vertical motion, and latent heat component were computed. The life cycles of the cyclones are described. It is observed that the latent heating component accounts for nearly all the conversion in the three cyclones, and latent heating within the SPCZ is the major source of eddy kinetic energy for the cyclones.

  15. Energy Conservation Tests of a Coupled Kinetic-kinetic Plasma-neutral Transport Code

    SciTech Connect

    Stotler, D. P.; Chang, C. S.; Ku, S. H.; Lang, J.; Park, G.

    2012-08-29

    A Monte Carlo neutral transport routine, based on DEGAS2, has been coupled to the guiding center ion-electron-neutral neoclassical PIC code XGC0 to provide a realistic treatment of neutral atoms and molecules in the tokamak edge plasma. The DEGAS2 routine allows detailed atomic physics and plasma-material interaction processes to be incorporated into these simulations. The spatial pro le of the neutral particle source used in the DEGAS2 routine is determined from the uxes of XGC0 ions to the material surfaces. The kinetic-kinetic plasma-neutral transport capability is demonstrated with example pedestal fueling simulations.

  16. On the Equipartition of Kinetic Energy in an Ideal Gas Mixture

    ERIC Educational Resources Information Center

    Peliti, L.

    2007-01-01

    A refinement of an argument due to Maxwell for the equipartition of translational kinetic energy in a mixture of ideal gases with different masses is proposed. The argument is elementary, yet it may work as an illustration of the role of symmetry and independence postulates in kinetic theory. (Contains 1 figure.)

  17. High energy fuel compositions

    SciTech Connect

    Fisher, D.H.

    1983-07-19

    A high density liquid hydrocarbon fuel composition is disclosed, singularly suited for propelling turbojet limited volume missile systems designed for shipborne deployment. The contemplated fuels are basically composed of the saturated analogues of dimers of methyl cyclopentadiene and of dicyclopentadiene and optionally include the saturated analogues of the co-trimers of said dienes or the trimers of cyclopentadiene. The various dimers and trimers are combined in a relative relationship to provide optimal performing fuels for the indicated purpose.

  18. Vibrational Energy Transfer and Kinetics of High Energy Molecular Lasers.

    DTIC Science & Technology

    1979-08-17

    babi1ities were measured for the—MCi, HP—HCN, DF—HCN, and 1~ ‘-HcN systems from 220—450°K. Two—p~otonp~otodissociation of HgC1, Hg~r, and HgI was observed to...HgBr , and MgI are of considerable current interest.(19 24) Laser output has been recently observed from HgBr(B21) and HgI (B2E) molecules produced by

  19. Determination of equivalent amounts of kinetic energy, work, and heat energy in the human body.

    PubMed

    Cinar, Yildirim

    2002-07-01

    The goal of this study is determine the mechanical equivalent of heat and the functional capacity of metabolism of walking at a slow pace (velocity = 4022m/hour, length of a step=75cm, energy utilization of a 70 kg person is 200kcal/hour). 50 healthy physicians were chosen randomly, and up and down motion of the body were determined as 6cm while stepping. Based on these, the heat equivalent is 37.5kcal/hour for horizontal motion and 52.7kcal/hour for 6cm up-and-down bobbing motions of body, and the functional capacity of metabolism is at least 45% ([37.5+52.7]/200=45%) for slow walking state, that this capacity is twofold more than earlier information. Muscle converts kinetic energy (work) to heat via friction, and heat sources of the body, and the concepts of thermogenesis and the functional capacity of metabolism should be revised.

  20. High energy cosmic ray composition

    NASA Astrophysics Data System (ADS)

    Seo, E. S.

    Cosmic rays are understood to result from energetic processes in the galaxy, probably from supernova explosions. However, cosmic ray energies extend several orders of magnitude beyond the limit thought possible for supernova blast waves. Over the past decade several ground-based and space-based investigations were initiated to look for evidence of a limit to supernova acceleration in the cosmic-ray chemical composition at high energies. These high-energy measurements are difficult because of the very low particle fluxes in the most interesting regions. The space-based detectors must be large enough to collect adequate statistics, yet stay within the weight limit for space flight. Innovative approaches now promise high quality measurements over an energy range that was not previously possible. The current status of high energy cosmic-ray composition measurements and planned future missions are discussed in this paper.

  1. On the Exchange of Kinetic and Magnetic Energy between Clouds and the Interstellar Medium

    NASA Astrophysics Data System (ADS)

    Miniati, Francesco; Jones, T. W.; Ryu, Dongsu

    1999-05-01

    We investigate, through two-dimensional MHD numerical simulations, the interaction of a uniform magnetic field oblique to a moving interstellar cloud. In particular we explore the transformation of cloud kinetic energy into magnetic energy as a result of field line stretching. Some previous simulations have emphasized the possible dynamical importance of a ``magnetic shield'' formed around clouds when the magnetic field is perpendicular to the cloud motion. It was not clear, however, how dependent those findings were on the assumed field configuration and cloud properties. To expand our understanding of this effect, we examine several new cases by varying the magnetic field orientation angle with respect to the cloud motion (θ), the cloud-background density contrast, and the cloud Mach number. We show that in two dimensions and with θ large enough, the magnetic field tension can become dominant in the dynamics of the motion of high density contrast, low Mach number clouds. In such a case, a significant fraction of the cloud's kinetic energy can be transformed into magnetic energy with the magnetic pressure at the cloud's nose exceeding the ram pressure of the impinging flow. We derive a characteristic timescale, τma, for this process of energy ``conversion.'' We find also that unless the cloud motion is highly aligned with the magnetic field, reconnection through tearing-mode instabilities in the cloud wake limits the formation of a strong flux-rope feature following the cloud. Finally we attempt to interpret some observed properties of the magnetic field in view of our results.

  2. High energy physics

    SciTech Connect

    Kernan, A.; Shen, B.C.; Ma, E.

    1997-07-01

    Hadron collider studies will focus on: (i) the search for the top quark with the newly installed D0 detector at the Fermilab Tevatron collider, (ii) the upgrade of the D0 detector to match the new main injector luminosity and (iii) R&D on silicon microstrip tracking devices for the SSC. High statistics studies of Z{sup 0} decay will continue with the OPAL detector at LEP. These studies will include a direct measurement of Z decay to neutrinos, the search for Higgs and heavy quark decays of Z. Preparations for the Large Scintillation Neutrino Detector (LSND) to measure neutrino oscillations at LAMPF will focus on data acquisition and testing of photomultiplier tubes. In the theoretical area E. Ma will concentrate on mass-generating radiative mechanisms for light quarks and leptons in renormalizable gauge field theories. J. Wudka`s program includes a detailed investigation of the magnetic-flip approach to the solar neutrino.

  3. Numerical and experimental assessment of turbulent kinetic energy in an aortic coarctation.

    PubMed

    Lantz, Jonas; Ebbers, Tino; Engvall, Jan; Karlsson, Matts

    2013-07-26

    The turbulent blood flow through an aortic coarctation in a 63-year old female patient was studied experimentally using magnetic resonance imaging (MRI), and numerically using computational fluid dynamics (CFD), before and after catheter intervention. Turbulent kinetic energy (TKE) was computed in the numerical model using large eddy simulation and compared with direct in vivo MRI measurements. Despite the two totally different methods to obtain TKE values, both quantitative and qualitative results agreed very well. The results showed that even though both blood flow rate and Reynolds number increased after intervention, total turbulent kinetic energy levels decreased in the coarctation. Therefore, the use of the Reynolds number alone as a measure of turbulence in cardiovascular flows should be used with caution. Furthermore, the change in flow field and kinetic energy were assessed, and it was found that before intervention a jet formed in the throat of the coarctation, which impacted the arterial wall just downstream the constriction. After intervention the jet was significantly weaker and broke up almost immediately, presumably resulting in less stress on the wall. As there was a good agreement between measurements and numerical results (the increase and decrease of integrated TKE matched measurements almost perfectly while peak values differed by approximately 1mJ), the CFD results confirmed the MRI measurements while at the same time providing high-resolution details about the flow. Thus, this preliminary study indicates that MR-based TKE measurements might be useful as a diagnostic tool when evaluating intervention outcome, while the detailed numerical results might be useful for further understanding of the flow for treatment planning.

  4. New Ro-Vibrational Kinetic Energy Operators using Polyspherical Coordinates for Polyatomic Molecules

    NASA Technical Reports Server (NTRS)

    Schwenke, David W.; Kwak, Dochan (Technical Monitor)

    2002-01-01

    We illustrate how one can easily derive kinetic energy operators for polyatomic molecules using polyspherical coordinates with very general choices for z-axis embeddings arid angles used to specify relative orientations of internal vectors. Computer algebra is not required.

  5. Efficient first-principles calculation of the quantum kinetic energy and momentum distribution of nuclei.

    PubMed

    Ceriotti, Michele; Manolopoulos, David E

    2012-09-07

    Light nuclei at room temperature and below exhibit a kinetic energy which significantly deviates from the predictions of classical statistical mechanics. This quantum kinetic energy is responsible for a wide variety of isotope effects of interest in fields ranging from chemistry to climatology. It also furnishes the second moment of the nuclear momentum distribution, which contains subtle information about the chemical environment and has recently become accessible to deep inelastic neutron scattering experiments. Here, we show how, by combining imaginary time path integral dynamics with a carefully designed generalized Langevin equation, it is possible to dramatically reduce the expense of computing the quantum kinetic energy. We also introduce a transient anisotropic Gaussian approximation to the nuclear momentum distribution which can be calculated with negligible additional effort. As an example, we evaluate the structural properties, the quantum kinetic energy, and the nuclear momentum distribution for a first-principles simulation of liquid water.

  6. Spectroscopy and kinetics of combustion gases at high temperatures

    SciTech Connect

    Hanson, R.K.; Bowman, C.T.

    1991-12-01

    This program involves two complementary activities: (1) development and application of cw ring dye laser absorption methods for sensitive detection of radical species and measurement of fundamental spectroscopic parameters at high temperatures; and (2) shock tube studies of radical-molecule and radical-radical reactions relevant to combustion. Species currently under investigation in the spectroscopic portion of the research include NO and CH{sub 3}; this has necessitated the development of a unique intracavity frequency-doubling system for our cw laser which operates at wavelengths in the range 210--230 nm. Shock tube studies of reaction kinetics currently are focused on reactions of CH{sub 3} radicals. Work during the current reporting period has been focused on the following activities: High resolution spectroscopy, and methyl diagnostics and kinetics.

  7. Crystallization Kinetics and Excess Free Energy of H2O and D2O Nanoscale Films of Amorphous Solid Water

    SciTech Connect

    Smith, R. Scott; Matthiesen, Jesper; Knox, Jake R.; Kay, Bruce D.

    2011-06-16

    Temperature-programmed desorption (TPD) and reflection absorption infrared spectroscopy (RAIRS) are used to investigate the crystallization kinetics and measure the excess free energy of metastable amorphous solid water films (ASW) of H2O and D2O grown using molecular beams. The desorption rates from the amorphous and crystalline phases of ASW are distinct, and as such, crystallization manifests can be observed in the TPD spectrum. The crystallization kinetics were studied by varying the TPD heating rate from 0.001 to 3 K/s. A coupled desorptioncrystallization kinetic model accurately simulates the desorption spectra and accurately predicts the observed temperature shifts in the crystallization. Isothermal crystallization studies using RAIRS are in agreement with the TPD results. Furthermore, highly sensitive measurements of the desorption rates were used to determine the excess free energy of ASW near 150 K. The excess entropy obtained from these data are consistent with there being a thermodynamic continuity between ASW and supercooled liquid water.

  8. High energy physics

    SciTech Connect

    Not Available

    1992-04-10

    The Counter Group continues to work on data analysis for Fermilab Experiment E653. Altogether, they expect several thousand reconstructed charm events and approximately 25 B pair events of which 12 have been observed thus far. Preparation continue for Fermilab Experiment E781, a high statistics study of charm baryon production. In the Theory Group, Cutkosky and collaborators study hadron phenomenology and non-perturbative QCD calculations. Levine has a long standing program in computational QED to obtain improved theoretical values for g-2 of the electron. Wolfenstein, Li, and their collaborators have worked on areas of weak interaction phenomenology that may yield insights beyond the standard model, e.g. CP violation and non-zero neutrino masses. Holman has been concerned with phase transitions in gauge theories relevant to cosmological problems. During 1991 most of the group effort was concentrated on the L3 experiment at CERN. Highlights of the results from the analysis of the Z[degrees] resonance include (a) a measurement of the strong coupling constant [alpha][sub s] for b quarks (b) a precision measurement of the average time of B hadrons and (c) a direct determination of the number of light neutrino faculties from the reaction e[sup +]e[sup [minus

  9. High-energy spectroscopic astrophysics

    NASA Astrophysics Data System (ADS)

    Güdel, Manuel; Walter, Roland

    After three decades of intense research in X-ray and gamma-ray astronomy, the time was ripe to summarize basic knowledge on X-ray and gamma-ray spectroscopy for interested students and researchers ready to become involved in new high-energy missions. This volume exposes both the scientific basics and modern methods of high-energy spectroscopic astrophysics. The emphasis is on physical principles and observing methods rather than a discussion of particular classes of high-energy objects, but many examples and new results are included in the three chapters as well.

  10. Experimental High Energy Neutrino Astrophysics

    SciTech Connect

    Distefano, Carla

    2005-10-12

    Neutrinos are considered promising probes for high energy astrophysics. More than four decades after deep water Cerenkov technique was proposed to detect high energy neutrinos. Two detectors of this type are successfully taking data: BAIKAL and AMANDA. They have demonstrated the feasibility of the high energy neutrino detection and have set first constraints on TeV neutrino production astrophysical models. The quest for the construction of km3 size detectors have already started: in the South Pole, the IceCube neutrino telescope is under construction; the ANTARES, NEMO and NESTOR Collaborations are working towards the installation of a neutrino telescope in the Mediterranean Sea.

  11. Modelling rainfall kinetic energy: a novel approach to erosion prediction and management

    NASA Astrophysics Data System (ADS)

    Nissan, H.; Toumi, R.

    2013-12-01

    Soil erosion is already a major global problem. Climate change and the rising world population will exert growing pressure on our land to deliver food and stability. This study presents a new and innovative application of a cloud resolving model, for use in soil erosion prediction studies. Rainfall kinetic energy flux is an important variable in erosion prediction, but is generally parameterized from intensity due to measurement difficulties. Instead, we show that a cloud resolving model can be used to dynamically simulate the kinetic energy of rain from basic physics, using four commonly used microphysics schemes. Rainfall kinetic energy flux is modelled during an idealized supercell storm with the Weather Research and Forecasting model. Results are within the range of observations and also capture the observed variability in kinetic energy flux for a given rainfall intensity, where current methods fail. Large raindrops are shown to contribute disproportionately to total kinetic energy flux compared with their number, suggesting that several existing relations between terminal velocity and size of raindrops are poorly suited for kinetic energy modelling. Treatment of raindrop size is tested and compared between the schemes, and factors influencing the erosive potential of rainfall will also be discussed. This work demonstrates the potential for conducting erosion prediction studies using a regional climate model. The method presented here may be easily extended for use in a full regional climate model with a microphysics parameterization scheme. This paves the way for full climate, and climate change, simulations of rainfall erosivity on regional to global scales and may contribute towards the ultimate integration of an erosion prediction scheme into climate models to allow coupled interactions with the atmosphere. Reference: Geophys. Res. Lett., 40, doi:10.1002/grl.50622 Schematic showing raindrop number density, rain mass flux and kinetic energy flux as

  12. High energy physics

    SciTech Connect

    Not Available

    1992-04-10

    The Counter Group continues to work on data analysis for Fermilab Experiment E653. Altogether, they expect several thousand reconstructed charm events and approximately 25 B pair events of which 12 have been observed thus far. Preparation continue for Fermilab Experiment E781, a high statistics study of charm baryon production. In the Theory Group, Cutkosky and collaborators study hadron phenomenology and non-perturbative QCD calculations. Levine has a long standing program in computational QED to obtain improved theoretical values for g-2 of the electron. Wolfenstein, Li, and their collaborators have worked on areas of weak interaction phenomenology that may yield insights beyond the standard model, e.g. CP violation and non-zero neutrino masses. Holman has been concerned with phase transitions in gauge theories relevant to cosmological problems. During 1991 most of the group effort was concentrated on the L3 experiment at CERN. Highlights of the results from the analysis of the Z{degrees} resonance include (a) a measurement of the strong coupling constant {alpha}{sub s} for b quarks (b) a precision measurement of the average time of B hadrons and (c) a direct determination of the number of light neutrino faculties from the reaction e{sup +}e{sup {minus}} {yields} {nu}{bar {nu}}{gamma}. We also began a major upgrade of the L3 luminosity monitor by replacing PWC chamber by a Si strip system in front of the BGO calorimeters. Finally we have continued our SSC R&D work on BaF{sub 2} by joining the GEM collaboration.

  13. Future of high energy physics

    SciTech Connect

    Panofsky, W.K.H.

    1984-06-01

    A rough overview is given of the expectations for the extension of high energy colliders and accelerators into the xtremely high energy range. It appears likely that the SSC or something like it will be the last gasp of the conventional method of producing high energy proton-proton collisions using synchrotron rings with superconducting magnets. It is likely that LEP will be the highest energy e+e/sup -/ colliding beam storage ring built. The future beyond that depends on the successful demonstrations of new technologies. The linear collider offers hope in this respect for some extension in energy for electrons, and maybe even for protons, but is too early to judge whether, by how much, or when such an extension will indeed take place.

  14. Approach to kinetic energy density functionals: Nonlocal terms with the structure of the von Weizsaecker functional

    SciTech Connect

    Garcia-Aldea, David; Alvarellos, J. E.

    2008-02-15

    We propose a kinetic energy density functional scheme with nonlocal terms based on the von Weizsaecker functional, instead of the more traditional approach where the nonlocal terms have the structure of the Thomas-Fermi functional. The proposed functionals recover the exact kinetic energy and reproduce the linear response function of homogeneous electron systems. In order to assess their quality, we have tested the total kinetic energies as well as the kinetic energy density for atoms. The results show that these nonlocal functionals give as good results as the most sophisticated functionals in the literature. The proposed scheme for constructing the functionals means a step ahead in the field of fully nonlocal kinetic energy functionals, because they are capable of giving better local behavior than the semilocal functionals, yielding at the same time accurate results for total kinetic energies. Moreover, the functionals enjoy the possibility of being evaluated as a single integral in momentum space if an adequate reference density is defined, and then quasilinear scaling for the computational cost can be achieved.

  15. Large-scale self-tuning solid-state kinetic energy harvester

    NASA Astrophysics Data System (ADS)

    Pletner, Baruch; Swan, Lukas; Wettels, Nicholas; Joseph, Alain

    2012-04-01

    In recent years there has been a strong emphasis on kinetic (vibration) energy harvesting using smart structure technology. This emphasis has been driven in large part by industry demand for powering sensors and wireless telemetry of sensor data in places into which running power and data cables is difficult or impossible. Common examples are helicopter drive shafts and other rotating equipment. In many instances, available space in these locations is highly limited, resulting in a trend for miniaturization of kinetic energy harvesters. While in some cases size limitations are dominant, in other cases large and even very large harvesters are possible and even desirable since they may produce significantly more power. Examples of large-scale energy harvesting include geomatics, which is the discipline of gathering, storing, processing, and delivering spatially referenced information on vast scales. Geomatics relies on suites of various sensors and imaging devices such as meteorological sensors, seismographs, high-resolution cameras, and LiDAR's. These devices may be stationed for prolonged periods of time in remote and poorly accessible areas and are required to operate continuously over prolonged periods of time. In other cases, sensing and imaging equipment may be mounted on land, sea, or airborne platforms and expected to operate for many hours on its own power. Providing power to this equipment constitutes a technological challenge. Other cases may include commercial buildings, unmanned powered gliders and more. Large scale kinetic energy harvesting thus constitutes a paradigm shift in the approach to kinetic energy harvesting as a whole and as often happens it poses its own unique technological challenges. Primarily these challenges fall into two categories: the cost-effective manufacturing of large and very large scale transducing elements based on smart structure technology and the continuous optimization (tuning) of these transducers for various operating

  16. Quantifying Turbulent Kinetic Energy in an Aortic Coarctation with Large Eddy Simulation and Magnetic Resonance Imaging

    NASA Astrophysics Data System (ADS)

    Lantz, Jonas; Ebbers, Tino; Karlsson, Matts

    2012-11-01

    In this study, turbulent kinetic energy (TKE) in an aortic coarctation was studied using both a numerical technique (large eddy simulation, LES) and in vivo measurements using magnetic resonance imaging (MRI). High levels of TKE are undesirable, as kinetic energy is extracted from the mean flow to feed the turbulent fluctuations. The patient underwent surgery to widen the coarctation, and the flow before and after surgery was computed and compared to MRI measurements. The resolution of the MRI was about 7 × 7 voxels in axial cross-section while 50x50 mesh cells with increased resolution near the walls was used in the LES simulation. In general, the numerical simulations and MRI measurements showed that the aortic arch had no or very low levels of TKE, while elevated values were found downstream the coarctation. It was also found that TKE levels after surgery were lowered, indicating that the diameter of the constriction was increased enough to decrease turbulence effects. In conclusion, both the numerical simulation and MRI measurements gave very similar results, thereby validating the simulations and suggesting that MRI measured TKE can be used as an initial estimation in clinical practice, while LES results can be used for detailed quantification and further research of aortic flows.

  17. Effective atomic numbers, electron densities and kinetic energy released in matter of vitamins for photon interaction

    NASA Astrophysics Data System (ADS)

    Shantappa, A.; Hanagodimath, S. M.

    2014-01-01

    Effective atomic numbers, electron densities of some vitamins (Retinol, Riboflavin, Niacin, Biotin, Folic acid, Cobalamin, Phylloquinone and Flavonoids) composed of C, H, O, N, Co, P and S have been calculated for total and partial photon interactions by the direct method for energy range 1 keV-100 GeV by using WinXCOM and kinetic energy released in matter (Kerma) relative to air is calculated in energy range of 1 keV-20 MeV. Change in effective atomic number and electron density with energy is calculated for all photon interactions. Variation of photon mass attenuation coefficients with energy are shown graphically only for total photon interaction. It is observed that change in mass attenuation coefficient with composition of different chemicals is very large below 100 keV and moderate between 100 keV and 10 MeV and negligible above 10 MeV. Behaviour of vitamins is almost indistinguishable except biotin and cobalamin because of large range of atomic numbers from 1(H) to 16 (S) and 1(H) to 27(Co) respectively. K a value shows a peak due to the photoelectric effect around K-absorption edge of high- Z constituent of compound for biotin and cobalamin.

  18. Isospin quartic term in the kinetic energy of neutron-rich nucleonic matter

    NASA Astrophysics Data System (ADS)

    Cai, Bao-Jun; Li, Bao-An

    2015-07-01

    The energy of a free gas of neutrons and protons is well known to be approximately isospin parabolic with a negligibly small quartic term of only 0.45 MeV at the saturation density of nuclear matter ρ0=0.16 fm-3 . Using an isospin-dependent single-nucleon momentum distribution including a high (low) momentum tail (depletion) with its shape parameters constrained by recent high-energy electron scattering and medium-energy nuclear photodisintegration experiments as well as the state-of-the-art calculations of the deuteron wave function and the equation of state of pure neutron matter near the unitary limit within several modern microscopic many-body theories, we show for the first time that the kinetic energy of interacting nucleons in neutron-rich nucleonic matter has a significant quartic term of 7.18 ±2.52 MeV. Such a large quartic term has broad ramifications in determining the equation of state of neutron-rich nucleonic matter using observables of nuclear reactions and neutron stars.

  19. Multiplicities in high energy interactions

    SciTech Connect

    Derrick, M.

    1985-05-13

    This paper reviews the data on multiplicities in high energy interactions. Results from e/sup +/e/sup -/ annihilation, from neutrino interactions, and from hadronic collisions, both diffractive and nondiffractive, are compared and contrasted. The energy dependence of the mean charged multiplicity, , as well as the rapidity density at Y = 0 are presented. For hadronic collisions, the data on neutral pion production shows a strong correlation with . The heavy particle fractions increase with ..sqrt..s up to the highest energies. The charged particle multiplicity distributions for each type of reaction show a scaling behavior when expressed in terms of the mean. Attempts to understand this behavior, which was first predicted by Koba, Nielsen, and Olesen, are discussed. The multiplicity correlations and the energy variation of the shape of the KNO scaling distribution provide important constraints on models. Some extrapolations to the energies of the Superconducting Super Collider are made. 51 refs., 27 figs.

  20. Effect of kinetic energy on the doping efficiency of cesium cations into superfluid helium droplets

    SciTech Connect

    Chen, Lei; Zhang, Jie; Freund, William M.; Kong, Wei

    2015-07-28

    We present an experimental investigation of the effect of kinetic energy on the ion doping efficiency of superfluid helium droplets using cesium cations from a thermionic emission source. The kinetic energy of Cs{sup +} is controlled by the bias voltage of a collection grid collinearly arranged with the droplet beam. Efficient doping from ions with kinetic energies from 20 eV up to 480 V has been observed in different sized helium droplets. The relative ion doping efficiency is determined by both the kinetic energy of the ions and the average size of the droplet beam. At a fixed source temperature, the number of doped droplets increases with increasing grid voltage, while the relative ion doping efficiency decreases. This result implies that not all ions are captured upon encountering with a sufficiently large droplet, a deviation from the near unity doping efficiency for closed shell neutral molecules. We propose that this drop in ion doping efficiency with kinetic energy is related to the limited deceleration rate inside a helium droplet. When the source temperature changes from 14 K to 17 K, the relative ion doping efficiency decreases rapidly, perhaps due to the lack of viable sized droplets. The size distribution of the Cs{sup +}-doped droplet beam can be measured by deflection and by energy filtering. The observed doped droplet size is about 5 × 10{sup 6} helium atoms when the source temperature is between 14 K and 17 K.

  1. Effect of kinetic energy on the doping efficiency of cesium cations into superfluid helium droplets.

    PubMed

    Chen, Lei; Zhang, Jie; Freund, William M; Kong, Wei

    2015-07-28

    We present an experimental investigation of the effect of kinetic energy on the ion doping efficiency of superfluid helium droplets using cesium cations from a thermionic emission source. The kinetic energy of Cs(+) is controlled by the bias voltage of a collection grid collinearly arranged with the droplet beam. Efficient doping from ions with kinetic energies from 20 eV up to 480 V has been observed in different sized helium droplets. The relative ion doping efficiency is determined by both the kinetic energy of the ions and the average size of the droplet beam. At a fixed source temperature, the number of doped droplets increases with increasing grid voltage, while the relative ion doping efficiency decreases. This result implies that not all ions are captured upon encountering with a sufficiently large droplet, a deviation from the near unity doping efficiency for closed shell neutral molecules. We propose that this drop in ion doping efficiency with kinetic energy is related to the limited deceleration rate inside a helium droplet. When the source temperature changes from 14 K to 17 K, the relative ion doping efficiency decreases rapidly, perhaps due to the lack of viable sized droplets. The size distribution of the Cs(+)-doped droplet beam can be measured by deflection and by energy filtering. The observed doped droplet size is about 5 × 10(6) helium atoms when the source temperature is between 14 K and 17 K.

  2. An efficient method for energy levels calculation using full symmetry and exact kinetic energy operator: tetrahedral molecules.

    PubMed

    Nikitin, A V; Rey, M; Tyuterev, Vl G

    2015-03-07

    A simultaneous use of the full molecular symmetry and of an exact kinetic energy operator (KEO) is of key importance for accurate predictions of vibrational levels at a high energy range from a potential energy surface (PES). An efficient method that permits a fast convergence of variational calculations would allow iterative optimization of the PES parameters using experimental data. In this work, we propose such a method applied to tetrahedral AB4 molecules for which a use of high symmetry is crucial for vibrational calculations. A symmetry-adapted contracted angular basis set for six redundant angles is introduced. Simple formulas using this basis set for explicit calculation of the angular matrix elements of KEO and PES are reported. The symmetric form (six redundant angles) of vibrational KEO without the sin(q)(-2) type singularity is derived. The efficient recursive algorithm based on the tensorial formalism is used for the calculation of vibrational matrix elements. A good basis set convergence for the calculations of vibrational levels of the CH4 molecule is demonstrated.

  3. An efficient method for energy levels calculation using full symmetry and exact kinetic energy operator: Tetrahedral molecules

    SciTech Connect

    Nikitin, A. V.; Rey, M.; Tyuterev, Vl. G.

    2015-03-07

    A simultaneous use of the full molecular symmetry and of an exact kinetic energy operator (KEO) is of key importance for accurate predictions of vibrational levels at a high energy range from a potential energy surface (PES). An efficient method that permits a fast convergence of variational calculations would allow iterative optimization of the PES parameters using experimental data. In this work, we propose such a method applied to tetrahedral AB{sub 4} molecules for which a use of high symmetry is crucial for vibrational calculations. A symmetry-adapted contracted angular basis set for six redundant angles is introduced. Simple formulas using this basis set for explicit calculation of the angular matrix elements of KEO and PES are reported. The symmetric form (six redundant angles) of vibrational KEO without the sin(q){sup −2} type singularity is derived. The efficient recursive algorithm based on the tensorial formalism is used for the calculation of vibrational matrix elements. A good basis set convergence for the calculations of vibrational levels of the CH{sub 4} molecule is demonstrated.

  4. High-energy neutrino astrophysics

    NASA Astrophysics Data System (ADS)

    Halzen, Francis

    2017-03-01

    The chargeless, weakly interacting neutrinos are ideal astronomical messengers as they travel through space without scattering, absorption or deflection. But this weak interaction also makes them notoriously di cult to detect, leading to neutrino observatories requiring large-scale detectors. A few years ago, the IceCube experiment discovered neutrinos originating beyond the Sun with energies bracketed by those of the highest energy gamma rays and cosmic rays. I discuss how these high-energy neutrinos can be detected and what they can tell us about the origins of cosmic rays and about dark matter.

  5. High flux solar energy transformation

    DOEpatents

    Winston, Roland; Gleckman, Philip L.; O'Gallagher, Joseph J.

    1991-04-09

    Disclosed are multi-stage systems for high flux transformation of solar energy allowing for uniform solar intensification by a factor of 60,000 suns or more. Preferred systems employ a focusing mirror as a primary concentrative device and a non-imaging concentrator as a secondary concentrative device with concentrative capacities of primary and secondary stages selected to provide for net solar flux intensification of greater than 2000 over 95 percent of the concentration area. Systems of the invention are readily applied as energy sources for laser pumping and in other photothermal energy utilization processes.

  6. High flux solar energy transformation

    DOEpatents

    Winston, R.; Gleckman, P.L.; O'Gallagher, J.J.

    1991-04-09

    Disclosed are multi-stage systems for high flux transformation of solar energy allowing for uniform solar intensification by a factor of 60,000 suns or more. Preferred systems employ a focusing mirror as a primary concentrative device and a non-imaging concentrator as a secondary concentrative device with concentrative capacities of primary and secondary stages selected to provide for net solar flux intensification of greater than 2000 over 95 percent of the concentration area. Systems of the invention are readily applied as energy sources for laser pumping and in other photothermal energy utilization processes. 7 figures.

  7. A kinetic energy analysis of the meso beta-scale severe storm environment

    NASA Technical Reports Server (NTRS)

    Fuelberg, H. E.; Printy, M. F.

    1984-01-01

    Analyses are performed of the meso beta-scale (20-200 km wavelengths and several hours to one-day periods) severe storm kinetic energy balance on the fifth day of the AVE SESAME campaign of May 1979. A 24-hr interval covering the antecedent, active and post-convective outbreak activity over Oklahoma are considered. Use is made of the kinetic energy budget equation (KEBE) for a finite volume in an isobaric coordinate system. Rawindsonde data with 75 km resolution were treated. The KEBE model covered changes in kinetic energy due to the cross contour flows, horizontal and vertical components of flux divergence, and volumic mass changes on synoptic and subsynoptic scales. The greatest variability was concentrated above 400 mb height and over the most intense storm activity. Energy was generated at the highest rates in divergence and decreased the most in convection. The meso beta-scale lacked sufficient resolution for analyzing mesoscale activity.

  8. Spectroscopy and kinetics of combustion gases at high temperatures

    SciTech Connect

    Hanson, R.K.; Bowman, C.T.

    1992-11-01

    This program involves two complementary activities: (1) development and application of cw ring dye laser absorption. methods for sensitive detection of radical species and measurement of fundamental spectroscopic parameters at high temperatures; and (2) shock tube studies of radical-molecule and radical-radical reactions relevant to combustion. Species currently under investigation in the spectroscopic portion of the research include NO and CH[sub 3]; this has necessitated the development of a unique intracavity frequency-doubling system for our cw laser which operates at wavelengths in the range 210--230 nm. Shock tube studies of reaction kinetics currently are focussed on reactions of CH[sub 3] radicals.

  9. Relativistic Momentum and Kinetic Energy, and E = mc[superscript 2

    ERIC Educational Resources Information Center

    Hu, Ben Yu-Kuang

    2009-01-01

    Based on relativistic velocity addition and the conservation of momentum and energy, I present simple derivations of the expressions for the relativistic momentum and kinetic energy of a particle, and for the formula E = mc[superscript 2]. (Contains 5 footnotes and 2 figures.)

  10. Measurement of the Kinetic Energy of a Body by Means of a Deformation.

    ERIC Educational Resources Information Center

    Perez, Pedro J.; And Others

    1996-01-01

    Describes a technique that measures the deformation produced in a plastic material by a falling ball in order to compute the ball's kinetic energy. Varying the parameters produces accurate results and gives students a good understanding of the measurement of energy. Combines various mechanical concepts that students have learned separately in…

  11. NEW APPROACHES: Measurement of the kinetic energy of a body by means of a deformation

    NASA Astrophysics Data System (ADS)

    Pérez, Pedro J.; Castellvi, Francesc; Rosell, Joan I.

    1996-07-01

    The simple technique of measuring the deformation produced in a plastic material by a falling ball can be used to compute the ball's kinetic energy. Varying the parameters in this simple experiment can produce accurate results and give students a good understanding of the measurement of energy.

  12. Extraterrestrial high energy neutrino fluxes

    NASA Technical Reports Server (NTRS)

    Stecker, F. W.

    1979-01-01

    Using the most recent cosmic ray spectra up to 2x10 to the 20th power eV, production spectra of high energy neutrinos from cosmic ray interactions with interstellar gas and extragalactic interactions of ultrahigh energy cosmic rays with 3K universal background photons are presented and discussed. Estimates of the fluxes from cosmic diffuse sources and the nearby quasar 3C273 are made using the generic relationship between secondary neutrinos and gammas and using recent gamma ray satellite data. These gamma ray data provide important upper limits on cosmological neutrinos. Quantitative estimates of the observability of high energy neutrinos from the inner galaxy and 3C273 above atmospheric background for a DUMAND type detector are discussed in the context of the Weinberg-Salam model with sq sin theta omega = 0.2 and including the atmospheric background from the decay of charmed mesons. Constraints on cosmological high energy neutrino production models are also discussed. It appears that important high energy neutrino astronomy may be possible with DUMAND, but very long observing times are required.

  13. Kinetic Kaleidoscope: Exploring Movement and Energy in the Visual Arts.

    ERIC Educational Resources Information Center

    Herman, Gail Neary; Hollingsworth, Patricia

    Works of visual art contain an inner dynamism and energy that an individual's perceptual apparatus can translate into kinesthetic impressions, movement, and sound. Through this translation, a child's natural energies can interact with the artwork through multiple sensory experiences, enriching art appreciation. After a brief examination of the…

  14. High Energy Astrophysics Program (HEAP)

    NASA Technical Reports Server (NTRS)

    Angelini, Lorella; Corcoran, Michael; Drake, Stephen; McGlynn, Thomas A.; Snowden, Stephen; Mukai, Koji; Cannizzo, John; Lochner, James; Rots, Arnold; Christian, Eric; Barthelmy, Scott; Palmer, David; Mitchell, John; Esposito, Joseph; Sreekumar, P.; Hua, Xin-Min; Mandzhavidze, Natalie; Chan, Kai-Wing; Soong, Yang; Barrett, Paul

    1998-01-01

    This report reviews activities performed by the members of the USRA contract team during the 6 months of the reporting period and projected activities during the coming 6 months. Activities take place at the Goddard Space Flight Center, within the Laboratory for High Energy Astrophysics. Developments concern instrumentation, observation, data analysis, and theoretical work in astrophysics. Supported missions include advanced Satellite for Cosmology and Astrophysics (ASCA), X-Ray Timing Experiment (XTE), X-Ray Spectrometer (XRS), Astro-E, High Energy Astrophysics Science Archive Research Center (HEASARC) and others.

  15. High Energy Astrophysics Program (HEAP)

    NASA Technical Reports Server (NTRS)

    Angelini, L.

    1998-01-01

    This report reviews activities performed by members of the USRA contract team during the six months of the reporting period and projected activities during the coming six months. Activities take place at the Goddard Space Flight Center, within the Laboratory for High Energy Astrophysics. Developments concern instrumentation, observation, data analysis, and theoretical work in Astrophysics Missions supported include: Advanced Satellite for Cosmology and Astrophysics (ASCA), X-ray Timing Experiment (XTE), X-ray Spectrometer (XRS), Astro-E, High Energy Astrophysics Science Archive Research Center (HEASARC), and others.

  16. Highly multiplexible thermal kinetic inductance detectors for x-ray imaging spectroscopy

    SciTech Connect

    Ulbricht, Gerhard Mazin, Benjamin A.; Szypryt, Paul; Walter, Alex B.; Bockstiegel, Clint; Bumble, Bruce

    2015-06-22

    For X-ray imaging spectroscopy, high spatial resolution over a large field of view is often as important as high energy resolution, but current X-ray detectors do not provide both in the same device. Thermal Kinetic Inductance Detectors (TKIDs) are being developed as they offer a feasible way to combine the energy resolution of transition edge sensors with pixel counts approaching CCDs and thus promise significant improvements for many X-ray spectroscopy applications. TKIDs are a variation of Microwave Kinetic Inductance Detectors (MKIDs) and share their multiplexibility: working MKID arrays with 2024 pixels have recently been demonstrated and much bigger arrays are under development. In this work, we present a TKID prototype, which is able to achieve an energy resolution of 75 eV at 5.9 keV, even though its general design still has to be optimized. We further describe TKID fabrication, characterization, multiplexing, and working principle and demonstrate the necessity of a data fitting algorithm in order to extract photon energies. With further design optimizations, we expect to be able to improve our TKID energy resolution to less than 10 eV at 5.9 keV.

  17. Stereodynamical Origin of Anti-Arrhenius Kinetics: Negative Activation Energy and Roaming for a Four-Atom Reaction.

    PubMed

    Coutinho, Nayara D; Silva, Valter H C; de Oliveira, Heibbe C B; Camargo, Ademir J; Mundim, Kleber C; Aquilanti, Vincenzo

    2015-05-07

    The OH + HBr → H2O + Br reaction, prototypical of halogen-atom liberating processes relevant to mechanisms for atmospheric ozone destruction, attracted frequent attention of experimental chemical kinetics: the nature of the unusual reactivity drop from low to high temperatures eluded a variety of theoretical efforts, ranking this one among the most studied four-atom reactions. Here, inspired by oriented molecular-beams experiments, we develop a first-principles stereodynamical approach. Thermalized sets of trajectories, evolving on a multidimensional potential energy surface quantum mechanically generated on-the-fly, provide a map of most visited regions at each temperature. Visualizations of rearrangements of bonds along trajectories and of the role of specific angles of reactants' mutual approach elucidate the mechanistic change from the low kinetic energy regime (where incident reactants reorient to find the propitious alignment leading to reaction) to high temperature (where speed hinders adjustment of directionality and roaming delays reactivity).

  18. Estimation of the kinetic energy dissipation in fall-arrest system and manikin during fall impact.

    PubMed

    Wu, John Z; Powers, John R; Harris, James R; Pan, Christopher S

    2011-04-01

    Fall-arrest systems (FASs) have been widely applied to provide a safe stop during fall incidents for occupational activities. The mechanical interaction and kinetic energy exchange between the human body and the fall-arrest system during fall impact is one of the most important factors in FAS ergonomic design. In the current study, we developed a systematic approach to evaluate the energy dissipated in the energy absorbing lanyard (EAL) and in the harness/manikin during fall impact. The kinematics of the manikin and EAL during the impact were derived using the arrest-force time histories that were measured experimentally. We applied the proposed method to analyse the experimental data of drop tests at heights of 1.83 and 3.35 m. Our preliminary results indicate that approximately 84-92% of the kinetic energy is dissipated in the EAL system and the remainder is dissipated in the harness/manikin during fall impact. The proposed approach would be useful for the ergonomic design and performance evaluation of an FAS. STATEMENT OF RELEVANCE: Mechanical interaction, especially kinetic energy exchange, between the human body and the fall-arrest system during fall impact is one of the most important factors in the ergonomic design of a fall-arrest system. In the current study, we propose an approach to quantify the kinetic energy dissipated in the energy absorbing lanyard and in the harness/body system during fall impact.

  19. Numerical Simulations of the Kinetic Energy Transfer in the Bath of a BOF Converter

    NASA Astrophysics Data System (ADS)

    Zhou, Xiaobin; Ersson, Mikael; Zhong, Liangcai; Jönsson, Pär

    2016-02-01

    The paper focuses on the fundamental aspects of the kinetic energy transfer from a top and bottom gas injection to the bath of the basic oxygen furnace (BOF) by applying a mathematical model. The analyses revealed that the energy transfer is less efficient when top lance height is lowered or the flowrate is increased in the top blowing operations. However, an inverse trend was found that the kinetic energy transfer is increased when the bottom flowrate is increased for the current bottom blowing operation conditions. The kinetic energy transfer index results indicated that the energy transfer for the bottom blowing is much more efficient than that of the top blowing operations. To understand the effects of the upper buoyant phase on the energy dissipation of the bulk liquid in the bath, different mass and physical properties of slag and foam were considered in the bottom blowing simulations. The slag on top of the bath is found to dissipate by 6.6, 9.4, and 11.2 pct for slag mass values of 5, 9, and 15 t compared to the case without slag atop the surface of the bath, respectively. The results showed that the kinetic energy transfer is not largely influenced by the viscosity of the upper slag or the foaming phases.

  20. Measurement of velocity and kinetic energy of turbulence in swirling flows and their numerical prediction

    NASA Astrophysics Data System (ADS)

    Sampath, S.; Ganesan, V.

    1986-04-01

    A method is offered for measuring turbulence levels in three directions in gas turbine combustion systems and high intensity industrial furnaces, using a hot wire anemometer. A detailed analysis of the turbulence in the flow is necessary to achieve optimum combustion conditions, and until now there has been no established method available for measuring turbulence in swirling and recirculating flows. The merit of the new method is the use of a single-wire probe rather than the X-probe. The method has been used to measure turbulence levels in swirling recirculating flows generated by vane swirlers. From the measured turbulence levels, the kinetic energy of turbulence has been calculated and the results are compared with a well-established numerical prediction method. Mean velocity measurements have also been made using a 3-hole Pitot probe. The agreement between the measured and predicted values is quite satisfactory.

  1. Mexican High Energy Physics Network

    NASA Astrophysics Data System (ADS)

    D'Olivo, J. C.; Napsuciale, M.; Pérez-Angón, M. A.

    2016-10-01

    The Mexican High Energy Physics Network is one of CONACYT's thematic research networks, created with the aim of increasing the communication and cooperation of the scientific and technology communities of Mexico in strategic areas. In this report we review the evolution, challenges, achievements and opportunities faced by the network.

  2. High energy gamma ray astronomy

    NASA Technical Reports Server (NTRS)

    Fichtel, Carl E.

    1987-01-01

    High energy gamma ray astronomy has evolved with the space age. Nonexistent twenty-five years ago, there is now a general sketch of the gamma ray sky which should develop into a detailed picture with the results expected to be forthcoming over the next decade. The galactic plane is the dominant feature of the gamma ray sky, the longitude and latitude distribution being generally correlated with galactic structural features including the spiral arms. Two molecular clouds were already seen. Two of the three strongest gamma ray sources are pulsars. The highly variable X-ray source Cygnus X-3 was seen at one time, but not another in the 100 MeV region, and it was also observed at very high energies. Beyond the Milky Way Galaxy, there is seen a diffuse radiation, whose origin remains uncertain, as well as at least one quasar, 3C 273. Looking to the future, the satellite opportunities for high energy gamma ray astronomy in the near term are the GAMMA-I planned to be launched in late 1987 and the Gamma Ray Observatory, scheduled for launch in 1990. The Gamma Ray Observatory will carry a total of four instruments covering the entire energy range from 30,000 eV to 3 x 10 to the 10th eV with over an order of magnitude increase in sensitivity relative to previous satellite instruments.

  3. Energy dynamics and current sheet structure in fluid and kinetic simulations of decaying magnetohydrodynamic turbulence

    DOE PAGES

    Makwana, K. D.; Zhdankin, V.; Li, H.; ...

    2015-04-10

    We performed simulations of decaying magnetohydrodynamic (MHD) turbulence with a fluid and a kinetic code. The initial condition is an ensemble of long-wavelength, counter-propagating, shear-Alfvén waves, which interact and rapidly generate strong MHD turbulence. The total energy is conserved and the rate of turbulent energy decay is very similar in both codes, although the fluid code has numerical dissipation, whereas the kinetic code has kinetic dissipation. The inertial range power spectrum index is similar in both the codes. The fluid code shows a perpendicular wavenumber spectral slope of k-1.3⊥k⊥-1.3. The kinetic code shows a spectral slope of k-1.5⊥k⊥-1.5 for smallermore » simulation domain, and k-1.3⊥k⊥-1.3 for larger domain. We then estimate that collisionless damping mechanisms in the kinetic code can account for the dissipation of the observed nonlinear energy cascade. Current sheets are geometrically characterized. Their lengths and widths are in good agreement between the two codes. The length scales linearly with the driving scale of the turbulence. In the fluid code, their thickness is determined by the grid resolution as there is no explicit diffusivity. In the kinetic code, their thickness is very close to the skin-depth, irrespective of the grid resolution. Finally, this work shows that kinetic codes can reproduce the MHD inertial range dynamics at large scales, while at the same time capturing important kinetic physics at small scales.« less

  4. Energy dynamics and current sheet structure in fluid and kinetic simulations of decaying magnetohydrodynamic turbulence

    SciTech Connect

    Makwana, K. D.; Zhdankin, V.; Li, H.; Daughton, W.; Cattaneo, F.

    2015-04-10

    We performed simulations of decaying magnetohydrodynamic (MHD) turbulence with a fluid and a kinetic code. The initial condition is an ensemble of long-wavelength, counter-propagating, shear-Alfvén waves, which interact and rapidly generate strong MHD turbulence. The total energy is conserved and the rate of turbulent energy decay is very similar in both codes, although the fluid code has numerical dissipation, whereas the kinetic code has kinetic dissipation. The inertial range power spectrum index is similar in both the codes. The fluid code shows a perpendicular wavenumber spectral slope of k-1.3⊥k⊥-1.3. The kinetic code shows a spectral slope of k-1.5⊥k⊥-1.5 for smaller simulation domain, and k-1.3⊥k⊥-1.3 for larger domain. We then estimate that collisionless damping mechanisms in the kinetic code can account for the dissipation of the observed nonlinear energy cascade. Current sheets are geometrically characterized. Their lengths and widths are in good agreement between the two codes. The length scales linearly with the driving scale of the turbulence. In the fluid code, their thickness is determined by the grid resolution as there is no explicit diffusivity. In the kinetic code, their thickness is very close to the skin-depth, irrespective of the grid resolution. Finally, this work shows that kinetic codes can reproduce the MHD inertial range dynamics at large scales, while at the same time capturing important kinetic physics at small scales.

  5. High Temperature Chemical Kinetic Combustion Modeling of Lightly Methylated Alkanes

    SciTech Connect

    Sarathy, S M; Westbrook, C K; Pitz, W J; Mehl, M

    2011-03-01

    Conventional petroleum jet and diesel fuels, as well as alternative Fischer-Tropsch (FT) fuels and hydrotreated renewable jet (HRJ) fuels, contain high molecular weight lightly branched alkanes (i.e., methylalkanes) and straight chain alkanes (n-alkanes). Improving the combustion of these fuels in practical applications requires a fundamental understanding of large hydrocarbon combustion chemistry. This research project presents a detailed high temperature chemical kinetic mechanism for n-octane and three lightly branched isomers octane (i.e., 2-methylheptane, 3-methylheptane, and 2,5-dimethylhexane). The model is validated against experimental data from a variety of fundamental combustion devices. This new model is used to show how the location and number of methyl branches affects fuel reactivity including laminar flame speed and species formation.

  6. Cell survival fraction estimation based on the probability densities of domain and cell nucleus specific energies using improved microdosimetric kinetic models.

    PubMed

    Sato, Tatsuhiko; Furusawa, Yoshiya

    2012-10-01

    Estimation of the survival fractions of cells irradiated with various particles over a wide linear energy transfer (LET) range is of great importance in the treatment planning of charged-particle therapy. Two computational models were developed for estimating survival fractions based on the concept of the microdosimetric kinetic model. They were designated as the double-stochastic microdosimetric kinetic and stochastic microdosimetric kinetic models. The former model takes into account the stochastic natures of both domain and cell nucleus specific energies, whereas the latter model represents the stochastic nature of domain specific energy by its approximated mean value and variance to reduce the computational time. The probability densities of the domain and cell nucleus specific energies are the fundamental quantities for expressing survival fractions in these models. These densities are calculated using the microdosimetric and LET-estimator functions implemented in the Particle and Heavy Ion Transport code System (PHITS) in combination with the convolution or database method. Both the double-stochastic microdosimetric kinetic and stochastic microdosimetric kinetic models can reproduce the measured survival fractions for high-LET and high-dose irradiations, whereas a previously proposed microdosimetric kinetic model predicts lower values for these fractions, mainly due to intrinsic ignorance of the stochastic nature of cell nucleus specific energies in the calculation. The models we developed should contribute to a better understanding of the mechanism of cell inactivation, as well as improve the accuracy of treatment planning of charged-particle therapy.

  7. Contributions of divergent and nondivergent winds to the kinetic energy balance of a severe storm environment

    NASA Technical Reports Server (NTRS)

    Browning, P. A.; Fuelberg, H. E.

    1983-01-01

    Divergent and rotational components of the synoptic scale kinetic energy balance are presented using rawinsonde data at 3 and 6 h intervals from the Atmospheric Variability Experiment (AVE 4). Two intense thunderstorm complexes occurred during the period. Energy budgets are described for the entire computational region and for limited volumes that enclose and move with the convection. Although small in magnitude, the divergent wind component played an important role in the cross contour generation and horizontal flux divergence of kinetic energy. The importance of V sub D appears directly to the presence and intensity of convection within the area. Although K sub D usually comprised less than 10 percent of the total kinetic energy content within the storm environment, as much as 87 percent of the total horizontal flux divergence and 68 percent of the total cross contour generation was due to the divergent component in the upper atmosphere. Generation of kinetic energy by the divergent component appears to be a major factor in the creation of an upper level wind maximum on the poleward side of one of the complexes. A random error analysis is presented to assess confidence limits in the various energy parameters.

  8. Highly Anomalous Energetics of Protein Cold Denaturation Linked to Folding-Unfolding Kinetics

    PubMed Central

    Romero-Romero, M. Luisa; Inglés-Prieto, Alvaro; Ibarra-Molero, Beatriz; Sanchez-Ruiz, Jose M.

    2011-01-01

    Despite several careful experimental analyses, it is not yet clear whether protein cold-denaturation is just a “mirror image” of heat denaturation or whether it shows unique structural and energetic features. Here we report that, for a well-characterized small protein, heat denaturation and cold denaturation show dramatically different experimental energetic patterns. Specifically, while heat denaturation is endothermic, the cold transition (studied in the folding direction) occurs with negligible heat effect, in a manner seemingly akin to a gradual, second-order-like transition. We show that this highly anomalous energetics is actually an apparent effect associated to a large folding/unfolding free energy barrier and that it ultimately reflects kinetic stability, a naturally-selected trait in many protein systems. Kinetics thus emerges as an important factor linked to differential features of cold denaturation. We speculate that kinetic stabilization against cold denaturation may play a role in cold adaptation of psychrophilic organisms. Furthermore, we suggest that folding-unfolding kinetics should be taken into account when analyzing in vitro cold-denaturation experiments, in particular those carried out in the absence of destabilizing conditions. PMID:21829584

  9. CRYSTALLINE BEAMS AT HIGH ENERGIES.

    SciTech Connect

    WEI, J.; OKAMOTO, H.; YURI, Y.; SESSLER, A.; MACHIDA, S.

    2006-06-23

    Previously it was shown that by crystallizing each of the two counter-circulating beams, a much larger beam-beam tune shift can be tolerated during the beam-beam collisions; thus a higher luminosity can be reached for colliding beams [1]. On the other hand, crystalline beams can only be formed at energies below the transition energy ({gamma}{sub T}) of the accelerators [2]. In this paper, we investigate the formation of crystals in a high-{gamma}{sub T} lattice that also satisfies the maintenance condition for a crystalline beam [3].

  10. Release kinetics of highly porous floating tablets containing cilostazol.

    PubMed

    Hwang, Kyu-Mok; Cho, Cheol-Hee; Tung, Nguyen-Thach; Kim, Ju-Young; Rhee, Yun-Seok; Park, Eun-Seok

    2017-02-20

    This study focuses on developing a highly porous floating tablet containing cilostazol. The underlying release mechanism of cilostazol from porous and floating tablets in dissolution media containing surfactants was investigated. The tablets were prepared by compressing granules and excipients with a sublimating agent, followed by sublimation under vacuum. The volatile material for the sublimating agent was chosen based on its flow properties using conventional methods as well as the twisted blade method. Resultant tablets could float immediately and had significantly higher tensile strengths than conventional tablets of similar porosities, holding a promising potential for increasing gastroretentive properties. Fitting the release profiles to the Korsmeyer-Peppas equation indicated Super Case II, Case II and non-Fickian kinetics, which implied that the release was affected by both floating behavior and matrix erosion. Abrupt changes in release kinetic parameters and erosional behaviors were found between the tablets containing different amounts of HPMC, indicating the existence of an excipient percolation threshold. Neither the surfactant in the media nor the porosity affected the dominant release mechanism, which was matrix erosion. Understanding the dominant release mechanism and percolation threshold allows for tuning the formulation to obtain various release profiles.

  11. Energy-Driven Kinetic Monte Carlo Method and Its Application in Fullerene Coalescence.

    PubMed

    Ding, Feng; Yakobson, Boris I

    2014-09-04

    Mimicking the conventional barrier-based kinetic Monte Carlo simulation, an energy-driven kinetic Monte Carlo (EDKMC) method was developed to study the structural transformation of carbon nanomaterials. The new method is many orders magnitude faster than standard molecular dynamics or Monte Marlo (MC) simulations and thus allows us to explore rare events within a reasonable computational time. As an example, the temperature dependence of fullerene coalescence was studied. The simulation, for the first time, revealed that short capped single-walled carbon nanotubes (SWNTs) appear as low-energy metastable structures during the structural evolution.

  12. [Responses of biological soil crust to and its relief effect on raindrop kinetic energy].

    PubMed

    Qin, Ning-qiang; Zhao, Yun-ge

    2011-09-01

    Based on the field investigation and by the method of simulated single-drop rain, this paper studied the responses of different types of biological soil crusts (biocrusts) in the wind-water erosion interleaving region of Loess Plateau to and their relief effect on the kinetic energy of raindrops. The responses of the biocrusts to raindrop kinetic energy had close relations with their biological composition. The cyanobacteria-dominated biocrusts with a thickness of 1 cm and the moss-dominated biocrusts with the coverage of 80% could resist in 0.99 J and 75.56 J of cumulative rain drop kinetic energy, respectively, and the potential resistance of the biocrusts with the same biological compositions was relative to the biomass of the biological compositions, i.e., the larger the biomass, the higher the resistance. As the chlorophyll a content of cyanobacteria- dominated biocrusts (which characterizes the cyanobacterial biomass) increased from 3.32 to 3.73 microg x g(-1), the resistance of the biocrusts against the cumulative raindrop kinetic energy increased from 0.99 to 2.17 J; when the moss biomass in the moss- dominated biocrusts increased from 2.03 to 4.73 g x dm(-2), the resistance of the crusts increased from 6.08 to 75.56 J. During the succession of the biocrusts, their responses to the raindrop kinetic energy presented an "S" pattern. No significant differences in the resistance against raindrop cumulative kinetic energy were observed between the cyanobacteria-dominated biocrusts with variable biomass, but the resistance of moss-dominated biocrusts increased significantly as their biomass per unit area increased. The resistance of moss-dominated biocrusts increased linearly when their biomass increased from 2.03 g x dm(-2) to 4.73 g x dm(-2). The moss-dominated biocrusts could resist in 62.03 J of raindrop kinetic energy when their biomass was up to 3.70 g x dm(-2). Biocrusts had obvious effects in relieving raindrop kinetic energy, and the relief effect

  13. Flywheel set for accumulating kinetic energy of rotation

    SciTech Connect

    Theyse, F.H.

    1980-09-16

    A flywheel set is described for accumulating energy with elastically supported bearings, resulting in a low critical speed, lying at all times under the operational flywheel speed. The axial thrust taking bearings, or one bearing, may be operating with magnetic forces.

  14. Bio-kinetic energy harvesting using electroactive polymers

    NASA Astrophysics Data System (ADS)

    Slade, Jeremiah R.; Bowman, Jeremy; Kornbluh, Roy

    2012-06-01

    In hybrid vehicles, electric motors are used on each wheel to not only propel the car but also to decelerate the car by acting as generators. In the case of the human body, muscles spend about half of their time acting as a brake, absorbing energy, or doing what is known as negative work. Using dielectric elastomers it is possible to use the "braking" phases of walking to generate power without restricting or fatiguing the Warfighter. Infoscitex and SRI have developed and demonstrated methods for using electroactive polymers (EAPs) to tap into the negative work generated at the knee during the deceleration phase of the human gait cycle and convert it into electrical power that can be used to support wearable information systems, including display and communication technologies. The specific class of EAP that has been selected for these applications is termed dielectric elastomers. Because dielectric elastomers dissipate very little mechanical energy into heat, greater amounts of energy can be converted into electricity than by any other method. The long term vision of this concept is to have EAP energy harvesting cells located in components of the Warfighter ensemble, such as the boot uppers, knee pads and eventually even the clothing itself. By properly locating EAPs at these sites it will be possible to not only harvest power from the negative work phase but to actually reduce the amount of work done by the Warfighter's muscles during this phase, thereby reducing fatigue and minimizing the forces transmitted to the joints.

  15. Polysaccharide chemistry regulates kinetics of calcite nucleation through competition of interfacial energies

    PubMed Central

    Hamm, Laura M.; Han, Nizhou; De Yoreo, James J.; Dove, Patricia M.

    2013-01-01

    Calcified skeletons are produced within complex assemblages of proteins and polysaccharides whose roles in mineralization are not well understood. Here we quantify the kinetics of calcite nucleation onto a suite of high-purity polysaccharide (PS) substrates under controlled conditions. The energy barriers to nucleation are PS-specific by a systematic relationship to PS charge density and substrate structure that is rooted in minimization of the competing substrate–crystal and substrate–liquid interfacial energies. Chitosan presents a low-energy barrier to nucleation because its near-neutral charge favors formation of a substrate–crystal interface, thus reducing substrate interactions with water. Progressively higher barriers are measured for negatively charged alginates and heparin that favor contact with the solution over the formation of new substrate–crystal interfaces. The findings support a directing role for PS in biomineral formation and demonstrate that substrate–crystal interactions are one end-member in a larger continuum of competing forces that regulate heterogeneous crystal nucleation. PMID:23690577

  16. Concept of variable activation energy and its validity in nonisothermal kinetics.

    PubMed

    Tan, Guanglei; Wang, Qi; Zheng, Hongxia; Zhao, Wei; Zhang, Song; Liu, Zhongsuo

    2011-06-09

    The concept of variable activation energy in solid-state kinetics under nonisothermal conditions has been suffering from doubt and controversy. Rate equations of nonisothermal kinetics of solid decomposition, which involve the factors of thermodynamics conditions, pressure of gaseous product, structure parameters of solid, and/or extent of conversion, are derived from the models of the interface reaction, the diffusion of gaseous product, and the nuclei growth of the solid product, respectively. The definition of the validity function in the rate equations represents the influence of the factors on the reaction rate. A function of variable activation energy depending on the validity function is also developed. The changing trend and degree of activation energy are extrapolated from the function of variable activation energy and based on the data of nonisothermal thermal decomposition of calcium carbonate. It is shown that the concept of variable activation energy is meaningfully applicable to solid-state reactions under nonisothermal conditions.

  17. A universal homogeneous assay for high-throughput determination of binding kinetics.

    PubMed

    Schiele, Felix; Ayaz, Pelin; Fernández-Montalván, Amaury

    2015-01-01

    There is an increasing demand for assay technologies that enable accurate, cost-effective, and high-throughput measurements of drug-target association and dissociation rates. Here we introduce a universal homogeneous kinetic probe competition assay (kPCA) that meets these requirements. The time-resolved fluorescence energy transfer (TR-FRET) procedure combines the versatility of radioligand binding assays with the advantages of homogeneous nonradioactive techniques while approaching the time resolution of surface plasmon resonance (SPR) and related biosensors. We show application of kPCA for three important target classes: enzymes, protein-protein interactions, and G protein-coupled receptors (GPCRs). This method is capable of supporting early stages of drug discovery with large amounts of kinetic information.

  18. Measurement of turbulent kinetic energy dissipation rates in the mesosphere by a 3 MHz Doppler radar

    NASA Astrophysics Data System (ADS)

    Singer, W.; Latteck, R.; Hocking, W. K.

    A new narrow beam Doppler radar at 3.17 MHz has been installed close to the Andöya Rocket Range in Andenes, Norway in summer 2002 to improve the ground based capabilities for measurements of turbulence in the mesosphere. The main feature of the radar is the transmitting/receiving antenna (Mills Cross antenna of 29 crossed half-wave dipoles) which provides in combination with the modular transceiver system high flexibility in beam forming and pointing. In general, vertical and oblique beams with a minimum beam width of about 7 (FWHP, one way) are used; the observations are done with a height resolution of 1 km. Off-zenith beams at 7.3 are directed towards NW, NE, SE, and SW. In addition, beams with different widths at the same pointing angle can be formed for the application of dual-beam width techniques. Turbulence intensities are estimated from the width of the observed signal spectra. Exact and approximate methods of removing non-turbulent processes such as wind shear and beam width broadening are applied. The exact, but computer time consuming correction method requires the knowledge of the antenna radiation pattern and of the measured wind field. The standard approximation is based on background winds and beam width, the dual-beam width approximation needs the beam width only. Examples of the various methods are discussed. Results of measurements of turbulent kinetic energy dissipation rates obtained with the exact correction method for beam and shear broadening are presented for the period September 2003 to January 2004. In September, mean turbulent kinetic energy dissipation rates amount about 5 mW/kg at 60km and about 20 mW/kg at 80km in agreement with mean turbulence intensities obtained from rocket soundings at Andenes.

  19. Measurement of turbulent kinetic energy dissipation rates in the mesosphere by a 3 MHz Doppler radar

    NASA Astrophysics Data System (ADS)

    Latteck, R.; Singer, W.; Hocking, W. K.

    A new narrow beam Doppler radar operating at 3.17 MHz has been installed close to the Andøya Rocket Range in Andenes, Norway in summer 2002 in order to improve the ground based capabilities for measurements of turbulence in the mesosphere. The main feature of the radar is a Mills Cross transmitting/receiving antenna consisting of 29 crossed half-wave dipoles. In combination with the modular transceiver system this provides high flexibility in beam forming and pointing. In general, vertical and oblique beams with a minimum one way half-power full-beam width (HPFW) of 6.6° are used. The observations are usually performed with a height resolution of 1 km and with off-zenith beams at 7.3° directed towards NW, NE, SE, and SW. Turbulence intensities have been estimated from the width of the observed signal spectra using an computationally intensive correction method which requires precise knowledge of the antenna radiation pattern. The program uses real-time measurements of the wind field in all determinations. Turbulent kinetic energy dissipation rates based on radar observations are presented and compared with corresponding climatological summer and winter profiles from rocket measurements, as well as with single profiles from model runs for selected periods from September 2003 to Summer 2004. The mean turbulent kinetic energy dissipation rates based on these radar measurements are about 5 mW/kg at 60 km altitude and about 20 mW/kg at 80 km, in reasonable agreement with mean turbulence intensities obtained from previous rocket soundings at Andenes.

  20. High-energy neutrino astronomy

    NASA Astrophysics Data System (ADS)

    Montaruli, Teresa

    2012-07-01

    Neutrino astronomy, conceptually conceived four decades ago, has entered an exciting phase for providing results on the quest for the sources of the observed highest energy particles. IceCube and ANTARES are now completed and are scanning in space and time possible signals of high energy neutrinos indicating the existence of such sources. DeepCore, inside IceCube, is a playground for vetoed neutrino measurement with better potential below 1 TeV. A larger and denser detector is now being discussed. ARA, now in test phase, will be composed by radio stations that could cover up to ~ 100 km2 and aims at the highest energy region of cosmogenic neutrinos. The non observation of cosmic events is on one side a source of disappointment, on the other it represents by itself an important result. If seen in the context of a multi-messenger science, the combination of photon and cosmic ray experiment results brings invaluable information. The experimental upper bounds of the cubic-kilometer telescope IceCube are now below the theoretical upper bounds for extragalactic fluxes of neutrinos from optically thin sources. These are responsible for accelerating the extragalactic cosmic rays. Such limits constrain the role of gamma-ray bursts, described by the fireball picture, as sources of ultra-high energy cosmic rays. Neutrino telescopes are exciting running multi-task experiments that produce astrophysics and particle physics results some of which have been illustrated at this conference and are summarized in this report.

  1. Magnetic to magnetic and kinetic to magnetic energy transfers at the top of the Earth's core

    NASA Astrophysics Data System (ADS)

    Huguet, Ludovic; Amit, Hagay; Alboussière, Thierry

    2016-11-01

    We develop the theory for the magnetic to magnetic and kinetic to magnetic energy transfer between different spherical harmonic degrees due to the interaction of fluid flow and radial magnetic field at the top of the Earth's core. We show that non-zero secular variation of the total magnetic energy could be significant and may provide evidence for the existence of stretching secular variation, which suggests the existence of radial motions at the top of the Earth's core-whole core convection or MAC waves. However, the uncertainties of the small scales of the geomagnetic field prevent a definite conclusion. Combining core field and flow models we calculate the detailed magnetic to magnetic and kinetic to magnetic energy transfer matrices. The magnetic to magnetic energy transfer shows a complex behaviour with local and non-local transfers. The spectra of magnetic to magnetic energy transfers show clear maxima and minima, suggesting an energy cascade. The kinetic to magnetic energy transfers, which are much weaker due to the weak poloidal flow, are either local or non-local between degree one and higher degrees. The patterns observed in the matrices resemble energy transfer patterns that are typically found in 3-D MHD numerical simulations.

  2. Effect of canopy thickness and canopy saturation on the amount and kinetic energy of throughfall: An experimental approach

    NASA Astrophysics Data System (ADS)

    Nanko, Kazuki; Onda, Yuichi; Ito, Akane; Moriwaki, Hiromu

    2008-03-01

    To investigate how canopy thickness and canopy saturation affect the amount and kinetic energy of throughfall, we conducted indoor experiments using a 9.8-m-tall transplanted Japanese cypress (Chamaecyparis obtusa) and a large-scale rainfall simulator with spray nozzles at a height of 16 m. The amount of throughfall and raindrop sizes and velocities were measured at twenty-four points under four canopy structures generated by staged branch pruning. Decreasing the canopy thickness resulted in increases of the initial throughfall amount, volume proportion of large throughfall drops, the number of drops with high velocities, and throughfall kinetic energy. Compared to a saturated canopy, a canopy undergoing wetting had lower throughfall amounts and volume proportion of large drops, but higher mean drop velocity. Canopy thickness affected throughfall generation by affecting the processes of canopy saturation and drop generation within the canopy.

  3. Energy transfer and dual cascade in kinetic magnetized plasma turbulence.

    PubMed

    Plunk, G G; Tatsuno, T

    2011-04-22

    The question of how nonlinear interactions redistribute the energy of fluctuations across available degrees of freedom is of fundamental importance in the study of turbulence and transport in magnetized weakly collisional plasmas, ranging from space settings to fusion devices. In this Letter, we present a theory for the dual cascade found in such plasmas, which predicts a range of new behavior that distinguishes this cascade from that of neutral fluid turbulence. These phenomena are explained in terms of the constrained nature of spectral transfer in nonlinear gyrokinetics. Accompanying this theory are the first observations of these phenomena, obtained via direct numerical simulations using the gyrokinetic code AstroGK. The basic mechanisms that are found provide a framework for understanding the turbulent energy transfer that couples scales both locally and nonlocally.

  4. Kinetic-energy induced smoothening and delay of epitaxial breakdown in pulsed-laser deposition

    SciTech Connect

    Shin, Byungha; Aziz, Michael J.

    2007-08-15

    We have isolated the effect of kinetic energy of depositing species from the effect of flux pulsing during pulsed-laser deposition (PLD) on surface morphology evolution of Ge(001) homoepitaxy at low temperature (100 deg. C). Using a dual molecular beam epitaxy (MBE) PLD chamber, we compare morphology evolution from three different growth methods under identical experimental conditions except for the differing nature of the depositing flux: (a) PLD with average kinetic energy 300 eV (PLD-KE); (b) PLD with suppressed kinetic energy comparable to thermal evaporation energy (PLD-TH); and (c) MBE. The thicknesses at which epitaxial breakdown occurs are ranked in the order PLD-KE>MBE>PLD-TH; additionally, the surface is smoother in PLD-KE than in MBE. The surface roughness of the films grown by PLD-TH cannot be compared due to the early epitaxial breakdown. These results demonstrate convincingly that kinetic energy is more important than flux pulsing in the enhancement of epitaxial growth, i.e., the reduction in roughness and the delay of epitaxial breakdown.

  5. An Estimation of Turbulent Kinetic Energy and Energy Dissipation Rate Based on Atmospheric Boundary Layer Similarity Theory

    NASA Technical Reports Server (NTRS)

    Han, Jongil; Arya, S. Pal; Shaohua, Shen; Lin, Yuh-Lang; Proctor, Fred H. (Technical Monitor)

    2000-01-01

    Algorithms are developed to extract atmospheric boundary layer profiles for turbulence kinetic energy (TKE) and energy dissipation rate (EDR), with data from a meteorological tower as input. The profiles are based on similarity theory and scalings for the atmospheric boundary layer. The calculated profiles of EDR and TKE are required to match the observed values at 5 and 40 m. The algorithms are coded for operational use and yield plausible profiles over the diurnal variation of the atmospheric boundary layer.

  6. High energy density aluminum battery

    SciTech Connect

    Brown, Gilbert M.; Paranthaman, Mariappan Parans; Dai, Sheng; Dudney, Nancy J.; Manthiram, Arumugan; McIntyre, Timothy J.; Sun, Xiao-Guang; Liu, Hansan

    2016-10-11

    Compositions and methods of making are provided for a high energy density aluminum battery. The battery comprises an anode comprising aluminum metal. The battery further comprises a cathode comprising a material capable of intercalating aluminum or lithium ions during a discharge cycle and deintercalating the aluminum or lithium ions during a charge cycle. The battery further comprises an electrolyte capable of supporting reversible deposition and stripping of aluminum at the anode, and reversible intercalation and deintercalation of aluminum or lithium at the cathode.

  7. A high energy physics perspective

    SciTech Connect

    Marciano, W.J.

    1997-01-13

    The status of the Standard model and role of symmetry in its development are reviewed. Some outstanding problems are surveyed and possible solutions in the form of additional {open_quotes}Hidden Symmetries {close_quotes} are discussed. Experimental approaches to uncover {open_quotes}New Physics{close_quotes} associated with those symmetries are described with emphasis on high energy colliders. An outlook for the future is given.

  8. Cosmology for high energy physicists

    SciTech Connect

    Albrecht, A.

    1987-11-01

    The standard big bang model of cosmology is presented. Although not perfect, its many successes make it a good starting point for most discussions of cosmology. Places are indicated where well understood laboratory physics is incorporated into the big bang, leading to successful predictions. Much less established aspects of high energy physics and some of the new ideas they have introduced into the field of cosmology are discussed, such as string theory, inflation and monopoles. 49 refs., 5 figs.

  9. Recent Results in Quantum Chemical Kinetics from High Resolution Spectroscopy

    SciTech Connect

    Quack, Martin

    2007-12-26

    We outline the approach of our group to derive intramolecular kinetic primary processes from high resolution spectroscopy. We then review recent results on intramolecular vibrational redistribution (IVR) and on tunneling processes. Examples are the quantum dynamics of the C-H-chromophore in organic molecules, hydrogen bond dynamics in (HF){sub 2} and stereomutation dynamics in H{sub 2}O{sub 2} and related chiral molecules. We finally discuss the time scales for these and further processes which range from 10 fs to more than seconds in terms of successive symmetry breakings, leading to the question of nuclear spin symmetry and parity violation as well as the question of CPT symmetry.

  10. The gas kinetics of very high flight speeds

    NASA Technical Reports Server (NTRS)

    Sanger, Eugen

    1950-01-01

    The aerodynamic forces on bodies of arbitrary shape were investigated under conditions such that the mean free path of the air molecule is greater than the dimensions of the body. Air pressures and friction forces were calculated from gas kinetic theory for surfaces facing both toward and away from the air stream at any angle. Air forces for an atmosphere of definite composition (molecular hydrogen) were calculated as a function of the flight velocity. The results indicate that the friction stresses between the air and the body surface are of the same magnitude as the dynamic pressure and as the air pressures normal to the surface. The application of the general method to the specific cases such as thin airfoils and projectiles leads to high drag coefficients and poor glide ratios even for the theoretically best wing sections.

  11. AGN JET KINETIC POWER AND THE ENERGY BUDGET OF RADIO GALAXY LOBES

    SciTech Connect

    Godfrey, L. E. H.; Shabala, S. S.

    2013-04-10

    Recent results based on the analysis of radio galaxies and their hot X-ray emitting atmospheres suggest that non-radiating particles dominate the energy budget in the lobes of FR I radio galaxies, in some cases by a factor of more than 1000, while radiating particles dominate the energy budget in FR II radio galaxy lobes. This implies a significant difference in the radiative efficiency of the two morphological classes. To test this hypothesis, we have measured the kinetic energy flux for a sample of 3C FR II radio sources using a new method based on the observed parameters of the jet terminal hotspots, and compared the resulting Q{sub jet}-L{sub radio} relation to that obtained for FR I radio galaxies based on X-ray cavity measurements. Contrary to expectations, we find approximate agreement between the Q{sub jet}-L{sub radio} relations determined separately for FR I and FR II radio galaxies. This result is ostensibly difficult to reconcile with the emerging scenario in which the lobes of FR I and FR II radio galaxies have vastly different energy budgets. However, a combination of lower density environment, spectral aging and strong shocks driven by powerful FR II radio galaxies may reduce the radiative efficiency of these objects relative to FR Is and counteract, to some extent, the higher radiative efficiency expected to arise due to the lower fraction of energy in non-radiating particles. An unexpected corollary is that extrapolating the Q{sub jet}-L{sub radio} relation determined for low power FR I radio galaxies provides a reasonable approximation for high power sources, despite their apparently different lobe compositions.

  12. Spider orb webs rely on radial threads to absorb prey kinetic energy.

    PubMed

    Sensenig, Andrew T; Lorentz, Kimberly A; Kelly, Sean P; Blackledge, Todd A

    2012-08-07

    The kinetic energy of flying insect prey is a formidable challenge for orb-weaving spiders. These spiders construct two-dimensional, round webs from a combination of stiff, strong radial silk and highly elastic, glue-coated capture spirals. Orb webs must first stop the flight of insect prey and then retain those insects long enough to be subdued by the spiders. Consequently, spider silks rank among the toughest known biomaterials. The large number of silk threads composing a web suggests that aerodynamic dissipation may also play an important role in stopping prey. Here, we quantify energy dissipation in orb webs spun by diverse species of spiders using data derived from high-speed videos of web deformation under prey impact. By integrating video data with material testing of silks, we compare the relative contributions of radial silk, the capture spiral and aerodynamic dissipation. Radial silk dominated energy absorption in all webs, with the potential to account for approximately 100 per cent of the work of stopping prey in larger webs. The most generous estimates for the roles of capture spirals and aerodynamic dissipation show that they rarely contribute more than 30 per cent and 10 per cent of the total work of stopping prey, respectively, and then only for smaller orb webs. The reliance of spider orb webs upon internal energy absorption by radial threads for prey capture suggests that the material properties of the capture spirals are largely unconstrained by the selective pressures of stopping prey and can instead evolve freely in response to alternative functional constraints such as adhering to prey.

  13. High energy overcurrent protective device

    DOEpatents

    Praeg, Walter F.

    1982-01-01

    Electrical loads connected to capacitance elements in high voltage direct current systems are protected from damage by capacitance discharge overcurrents by connecting between the capacitance element and the load, a longitudinal inductor comprising a bifilar winding wound about a magnetic core, which forms an incomplete magnetic circuit. A diode is connected across a portion of the bifilar winding which conducts a unidirectional current only. Energy discharged from the capacitance element is stored in the inductor and then dissipated in an L-R circuit including the diode and the coil winding. Multiple high voltage circuits having capacitance elements may be connected to loads through bifilar windings all wound about the aforementioned magnetic core.

  14. Simulations of thermodynamics and kinetics on rough energy landscapes with milestoning.

    PubMed

    Bello-Rivas, Juan M; Elber, Ron

    2016-03-05

    We investigated by computational means the kinetics and stationary behavior of stochastic dynamics on an ensemble of rough two-dimensional energy landscapes. There are no obvious separations of temporal scales in these systems, which constitute a simple model for the behavior of glasses and some biomaterials. Even though there are significant computational challenges present in these systems due to the large number of metastable states, the Milestoning method is able to compute their kinetic and thermodynamic properties exactly. We observe two clearly distinguished regimes in the overall kinetics: one in which diffusive behavior dominates and another that follows an Arrhenius law (despite the absence of a dominant barrier). We compare our results with those obtained with an exactly-solvable one-dimensional model, and with the results from the rough one-dimensional energy model introduced by Zwanzig. © 2015 Wiley Periodicals, Inc.

  15. Kinetic reconstruction of the free-energy landscape.

    PubMed

    Wedekind, Jan; Reguera, David

    2008-09-04

    We present a new general method to trace back a lot of valuable information from direct simulations and experiments of activated processes. In particular, it allows the reconstruction of the free-energy landscape for an arbitrary reaction coordinate directly from the out-of-equilibrium dynamics of the process. We demonstrate the power of this concept by its application to a molecular dynamics simulation of nucleation of a Lennard-Jones vapor. The same method can be also applied to Brownian dynamics and stochastic simulations.

  16. Skin penetration assessment of less lethal kinetic energy munitions.

    PubMed

    Bir, Cynthia A; Stewart, Shelby J; Wilhelm, Marianne

    2005-11-01

    The development of less-lethal technologies has provided law enforcement personnel with an alternative to lethal force. Although the less lethal projectile was produced to engender non-penetrating wounds, case studies show that there have been a number of reported penetrating injuries ranging from minor to significant in morbidity. The objective of this study was to determine the energy per unit area required to penetrate various regions of the body. Eight unembalmed postmortem human specimens were procured for this testing. Each specimen sustained a maximum of 25 impacts consisting of shots to the anterior and posterior thorax, abdomen, and legs. A 12-gauge, fin-stabilized, rubber rocket round was used as the impactor for all of the conducted tests. The energy density required for 50% risk of penetration varied from 23.99 J/cm2 for the location on the anterior rib (p = 0.000) to 52.74 J/cm2 for the location on the posterior rib (p = 0.001).

  17. Characteristics of turbulent kinetic energy dissipation rate and turbidity near the coast of East China Sea

    NASA Astrophysics Data System (ADS)

    Zhang, Yanwei; Xu, Huiping; Qin, Rufu; Xu, Changwei; Fan, Daidu

    2016-09-01

    The East China Sea (ECS) has a high suspended-sediment concentration because of the influence of the Changjiang River, indicated by high turbidity in the water. Considering the islands offthe coast and the complex topography, and the strong influence of tides and wind, the coast offthe ECS is a typical region with strong oceanic mixing processes. The changes in the dynamic processes near the bottom play an important role in the control of water turbidity. The turbulent kinetic energy dissipation rate ( ɛ ) is a parameter that shows the strength of ocean mixing. This is estimated based on a structure method using current velocity that is measured by a high-frequency Acoustic Doppler Current Profiler (ADCP) from a seafloor observatory in the ECS. The results indicate strong ocean mixing processes with a mean ɛ value of 5.7×10-5 W/kg and distinct tidal variations in the dissipation rate. Conversely, the variation of the water turbidity leads to changes in the water dynamical structure near the bottom. Comparing the dissipation rate with the turbidity near the bottom boundary layer, we find that the high turbidity mimics strong ocean mixing.

  18. Low Energy Building for High Energy People.

    ERIC Educational Resources Information Center

    American School and University, 1982

    1982-01-01

    The Huston Huffman Center at the University of Oklahoma's Norman campus has a jogging track as well as facilities for exercise and court games that are fully accessible to the handicapped. The building is set eight feet in the ground both to reduce its bulk and to conserve energy. (Author/MLF)

  19. Pressure and kinetic energy transport across the cavity mouth in resonating cavities.

    PubMed

    Bailey, Peter Roger; Abbá, Antonella; Tordella, Daniela

    2013-01-01

    Basic properties of the incompressible fluid motion in a rectangular cavity located along one wall of a plane channel are considered. For Mach numbers of the order of 1×10(-3) and using the incompressible formulation, we look for observable properties that can be associated with acoustic emission, which is normally observed in this kind of flow beyond a critical value of Reynolds number. The focus is put on the energy dynamics, in particular on the accumulation of energy in the cavity which takes place in the form of pressure and kinetic energy. By increasing the external forcing, we observe that the pressure flow into the cavity increases very rapidly, then peaks. However, the flow of kinetic energy, which is many orders of magnitude lower than that of the pressure, slowly but continuously grows. This leads to the pressure-kinetic energy flows ratio reaching an asymptotic state around the value 1000 for the channel bulk speed Reynolds number. It is interesting to note that beyond this threshold when the channel flow is highly unsteady-a sort of coarse turbulent flow-a sequence of high and low pressure spots is seen to depart from the downward cavity step in the statistically averaged field. The set of spots forms a steady spatial structure, a sort of damped standing wave stretching along the spanwise direction. The line joining the centers of the spots has an inclination similar to the normal to the fronts of density or pressure waves, which are observed to propagate from the downstream cavity edge in compressible cavity flows (at Mach numbers of 1×10(2) to 1×10(3), larger than those considered here). The wavelength of the standing wave is of the order of 1/8 the cavity depth and observed at the channel bulk Reynolds number, Re~2900. In this condition, the measure of the maximum pressure differences in the cavity field shows values of the order of 1×10(-1) Pa. We interpret the presence of this sort of wave as the fingerprint of the noise emission spots which

  20. Kinetic-energy matrix elements for atomic Hylleraas-CI wave functions.

    PubMed

    Harris, Frank E

    2016-05-28

    Hylleraas-CI is a superposition-of-configurations method in which each configuration is constructed from a Slater-type orbital (STO) product to which is appended (linearly) at most one interelectron distance rij. Computations of the kinetic energy for atoms by this method have been difficult due to the lack of formulas expressing these matrix elements for general angular momentum in terms of overlap and potential-energy integrals. It is shown here that a strategic application of angular-momentum theory, including the use of vector spherical harmonics, enables the reduction of all atomic kinetic-energy integrals to overlap and potential-energy matrix elements. The new formulas are validated by showing that they yield correct results for a large number of integrals published by other investigators.

  1. The influence of energy migration on luminescence kinetics parameters in upconversion nanoparticles

    NASA Astrophysics Data System (ADS)

    Alyatkin, Sergey; Asharchuk, Ilya; Khaydukov, Kirill; Nechaev, Andrey; Lebedev, Oleg; Vainer, Yuri; Semchishen, Vladimir; Khaydukov, Evgeny

    2017-01-01

    The mechanism of upconversion at the nanoscale is still under discussion. In this paper, we report on the experimental results of anti-Stokes luminescence kinetics in the upconversion nanoparticles of β-NaYF4: 20%Yb3+; 0.6%Tm3+. The parameters of the luminescence kinetics were found to be unambiguously dependent on the number of excitation quanta n, which are necessary for certain transitions between the energy states of thulium ions. The observed correlation has been explained by means of the long-lasting energy migration between the ytterbium ions. The spread in time between the luminescent maxima of the corresponding thulium transitions not only shows the nonlinear character of upconversion, but also reveals the time scale of energy migration as well. From these, we derive that the conventional Förster formalism applied to the estimation of energy transfer efficiency in UCNP-fluorophore pairs can provide misleading results.

  2. Kinetic energies to analyze the experimental auger electron spectra by density functional theory calculations

    NASA Astrophysics Data System (ADS)

    Endo, Kazunaka

    2016-02-01

    In the Auger electron spectra (AES) simulations, we define theoretical modified kinetic energies of AES in the density functional theory (DFT) calculations. The modified kinetic energies correspond to two final-state holes at the ground state and at the transition-state in DFT calculations, respectively. This method is applied to simulate Auger electron spectra (AES) of 2nd periodic atom (Li, Be, B, C, N, O, F)-involving substances (LiF, beryllium, boron, graphite, GaN, SiO2, PTFE) by deMon DFT calculations using the model molecules of the unit cell. Experimental KVV (valence band electrons can fill K-shell core holes or be emitted during KVV-type transitions) AES of the (Li, O) atoms in the substances agree considerably well with simulation of AES obtained with the maximum kinetic energies of the atoms, while, for AES of LiF, and PTFE substance, the experimental F KVV AES is almost in accordance with the spectra from the transitionstate kinetic energy calculations.

  3. Employing Magnetic Levitation to Monitor Reaction Kinetics and Measure Activation Energy

    ERIC Educational Resources Information Center

    Benz, Lauren; Cesafsky, Karen E.; Le, Tran; Park, Aileen; Malicky, David

    2012-01-01

    This article describes a simple and inexpensive undergraduate-level kinetics experiment that uses magnetic levitation to monitor the progress and determine the activation energy of a condensation reaction on a polymeric solid support. The method employs a cuvette filled with a paramagnetic solution positioned between two strong magnets. The…

  4. Measurement of the Turbulence Kinetic Energy Budget of a Turbulent Planar Wake Flow in Pressure Gradients

    NASA Technical Reports Server (NTRS)

    Liu, Xiao-Feng; Thomas, Flint O.; Nelson, Robert C.

    2001-01-01

    Turbulence kinetic energy (TKE) is a very important quantity for turbulence modeling and the budget of this quantity in its transport equation can provide insight into the flow physics. Turbulence kinetic energy budget measurements were conducted for a symmetric turbulent wake flow subjected to constant zero, favorable and adverse pressure gradients in year-three of research effort. The purpose of this study is to clarify the flow physics issues underlying the demonstrated influence of pressure gradient on wake development and provide experimental support for turbulence modeling. To ensure the reliability of these notoriously difficult measurements, the experimental procedure was carefully designed on the basis of an uncertainty analysis. Four different approaches, based on an isotropic turbulence assumption, a locally axisymmetric homogeneous turbulence assumption, a semi-isotropy assumption and a forced balance of the TKE equation, were applied for the estimate of the dissipation term. The pressure transport term is obtained from a forced balance of the turbulence kinetic energy equation. This report will present the results of the turbulence kinetic energy budget measurement and discuss their implication on the development of strained turbulent wakes.

  5. Statistical evaporation of rotating clusters. I. Kinetic energy released

    NASA Astrophysics Data System (ADS)

    Calvo, F.; Parneix, P.

    2003-07-01

    Unimolecular evaporation in rotating atomic clusters is investigated using phase space theory (PST) and molecular dynamics simulations. The rotational densities of states are calculated in the sphere+atom approximation, and analytical expressions are given for a radial interaction potential with the form -C/rp. The vibrational densities of states are calculated using Monte Carlo simulations, and the average radial potential at finite temperature is obtained using a recent extension of the multiple range random-walk algorithm. These ideas are tested on simple argon clusters modeled with the Lennard-Jones interaction potential, at several excitation energies and angular momenta of the parent cluster. Our results show that PST successfully reproduces the simulation data, not only the average KER but its probability distribution, for dissociations from LJ14, for which the product cluster can effectively be considered as spherical. Even for dissociations from the nonspherical LJ8, simulation results remain very close to the predictions of the statistical theory.

  6. The Control Based on Internal Average Kinetic Energy in Complex Environment for Multi-robot System

    NASA Astrophysics Data System (ADS)

    Yang, Mao; Tian, Yantao; Yin, Xianghua

    In this paper, reference trajectory is designed according to minimum energy consumed for multi-robot system, which nonlinear programming and cubic spline interpolation are adopted. The control strategy is composed of two levels, which lower-level is simple PD control and the upper-level is based on the internal average kinetic energy for multi-robot system in the complex environment with velocity damping. Simulation tests verify the effectiveness of this control strategy.

  7. Pion exchange at high energies

    SciTech Connect

    Jones, L.M.

    1980-07-01

    The state of Regge pion exchange calculations for high-energy reactions is reviewed. Experimental evidence is summarized to show that (i) the pion trajectory has a slope similar to that of other trajectories; (ii) the pion exchange contribution can dominate contributions of higher trajectories up to quite a large energy; (iii) many two-body cross sections with large pion contributions can be fit only by models which allow for kinematical conspiracy at t=0. The theory of kinematic conspiracy is reviewed for two-body amplitudes, and calculations of the conspiring pion--Pomeron cut discussed. The author then summarizes recent work on pion exchange in Reggeized Deck models for multiparticle final states, with emphasis on the predictions of various models (with and without resonances) for phases of the partial wave amplitudes.

  8. Soft X-ray Charged Piezoelectret for Kinetic Energy Harvesting

    NASA Astrophysics Data System (ADS)

    Lu, J.; Cho, HJ; Suzuki, Y.

    2016-11-01

    Piezoelectret polymer attracts much attention for its high piezoelectric coefficient. Multilayered piezoelectret structures are often charged with corona discharge, but it is difficult to get high surface charge density. To address this issue, a multilayered piezoelectret structure with embedded electrode is proposed, which can be efficiently poled with soft X-ray charging. With the aid of embedded electrodes, the bias voltage is directly applied to each unit cell, rather than divided and distributed to multiple layers. With an early PTFE-based prototype, output power of 0.5 μJ has been obtained for 0.3 mm displacement in 0.2 s.

  9. Equilibrium, kinetic and thermodynamic study of cesium adsorption onto nanocrystalline mordenite from high-salt solution.

    PubMed

    Lee, Keun-Young; Park, Minsung; Kim, Jimin; Oh, Maengkyo; Lee, Eil-Hee; Kim, Kwang-Wook; Chung, Dong-Yong; Moon, Jei-Kwon

    2016-05-01

    In this study, the equilibrium, kinetics and thermodynamics of cesium adsorption by nanocrystalline mordenite were investigated under cesium contamination with high-salt solution, simulating the case of an operation and decommissioning of nuclear facilities or an accident during the processes. The adsorption rate constants were determined using a pseudo second-order kinetic model. The kinetic results strongly demonstrated that the cesium adsorption rate of nano mordenite is extremely fast, even in a high-salt solution, and much faster than that of micro mordenite. In the equilibrium study, the Langmuir isotherm model fit the cesium adsorption data of nano mordenite better than the Freundlich model, which suggests that cesium adsorption onto nano mordenite is a monolayer homogeneous adsorption process. The obtained thermodynamic parameters indicated that the adsorption involved a very stable chemical reaction. In particular, the combination of rapid particle dispersion and rapid cesium adsorption of the nano mordenite in the solution resulted in a rapid and effective process for cesium removal without stirring, which may offer great advantages for low energy consumption and simple operation.

  10. Effective homogeneity of the exchange-correlation and non-interacting kinetic energy functionals under density scaling.

    PubMed

    Borgoo, Alex; Teale, Andrew M; Tozer, David J

    2012-01-21

    Correlated electron densities, experimental ionisation potentials, and experimental electron affinities are used to investigate the homogeneity of the exchange-correlation and non-interacting kinetic energy functionals of Kohn-Sham density functional theory under density scaling. Results are presented for atoms and small molecules, paying attention to the influence of the integer discontinuity and the choice of the electron affinity. For the exchange-correlation functional, effective homogeneities are highly system-dependent on either side of the integer discontinuity. By contrast, the average homogeneity-associated with the potential that averages over the discontinuity-is generally close to 4/3 when the discontinuity is computed using positive affinities for systems that do bind an excess electron and negative affinities for those that do not. The proximity to 4/3 becomes increasingly pronounced with increasing atomic number. Evaluating the discontinuity using a zero affinity in systems that do not bind an excess electron instead leads to effective homogeneities on the electron abundant side that are close to 4/3. For the non-interacting kinetic energy functional, the effective homogeneities are less system-dependent and the effect of the integer discontinuity is less pronounced. Average values are uniformly below 5/3. The study provides information that may aid the development of improved exchange-correlation and non-interacting kinetic energy functionals.

  11. Enhancing kinetic energy entrainment in LES of large wind farms by unconventional forcing at the turbine rotors

    NASA Astrophysics Data System (ADS)

    Verhulst, Claire; Meneveau, Charles

    2015-11-01

    Vertical entrainment of mean kinetic energy is believed to be a limiting factor for power generation in very large wind farms, which operate in the turbulent atmospheric boundary layer and experience detrimental wake effects. A new approach, meant to increase vertical entrainment and aid wake recovery, is proposed and evaluated with a preliminary ``proof of concept'' test using Large Eddy Simulation (LES) with periodic boundary conditions to obtain realistic fully developed flow. In addition to the traditional actuator thrust force, a synthetic vertical force is applied at the turbine rotors to force high-speed flow downward and low-speed flow upward. The ratio of the vertical force and the thrust force, held constant within each case, ranges from 0 to 1 across six cases and is applied independently at each turbine. The proposed approach is found to increase the power extraction and mean kinetic energy entrainment significantly, by up to 95% when the vertical force is similar in magnitude to the thrust force. The effect of the forcing scheme on the mean velocity field is considered in detail. In addition, a quadrant analysis is performed to determine how the synthetic forcing changes the statistical characteristics of the mean kinetic energy entrainment within the wind farm. This work was supported by NSF grant 1243482 (the WINDINSPIRE project).

  12. Including the relativistic kinetic energy in a spline-augmented plane-wave band calculation

    SciTech Connect

    Fehrenbach, G.M.; Schmidt, G.

    1997-03-01

    The first-order relativistic correction to the kinetic energy of an electron, the mass-velocity term, is not bounded from below. It can, therefore, not be used within a variational framework. To overcome this deficiency we developed a method to include the entire relativistic kinetic energy {radical}(p{sup 2}c{sup 2}+m{sub 0}{sup 2}c{sup 4}){minus}m{sub 0}c{sup 2} in a spline-augmented plane-wave band calculation. The first results for silver are quite promising, especially for d and p states: The analysis of the energies of the core states as well as of the valence band structure suggests that the energies of d bands are reproduced within 1 mRy. However, the combination of the relativistic kinetic energy with the Darwin term leads to energies which are too low for s-like valence states by 10 mRy. Therefore, the s and d valence band complex is spread out and the Fermi level is lowered by the same amount as the s states. We expect to overcome these deficiencies in future investigations by using a alternative form of the relativistic potential correction along the lines proposed by Douglas and Kroll. {copyright} {ital 1997} {ital The American Physical Society}

  13. Turbulent Kinetic Energy in the Oklahoma City Urban Environment

    SciTech Connect

    Lundquist, J; Leach, M; Gouveia, F

    2004-06-24

    A major field experiment, Joint URBAN 2003 (JU2003), was conducted in Oklahoma City in July 2003 to collect meteorological and tracer data sets for evaluating dispersion models in urban areas. The Department of Homeland Security and the Defense Threat Reduction Agency were the primary sponsors of JU2003. Investigators from five Department of Energy national laboratories, several other government agencies, universities, private companies, and international agencies conducted the experiment. Observations to characterize the meteorology in and around the urban area complemented the observation of the dispersion of SF6, an inert tracer gas. Over one hundred threedimensional sonic anemometers were deployed in and around the urban area to monitor wind speed, direction, and turbulence fluxes during releases of SF6. Sonic deployment locations included a profile of eight sonic anemometers mounted on a crane less than 1 km north of the central business district (CBD). Using data from these and other sonic anemometers deployed in the urban area, we can quantify the effect of the urban area on atmospheric turbulence and compare results seen in OKC to those in other urban areas to assess the parameters typically used in parameterizations of urban turbulence.

  14. High Energy Laser Diagnostic Sensors

    NASA Astrophysics Data System (ADS)

    Luke, James R.; Goddard, Douglas N.; Lewis, Jay; Thomas, David

    2010-10-01

    Recent advancements in high energy laser (HEL) sources have outpaced diagnostic tools capable of accurately quantifying system performance. Diagnostic tools are needed that allow system developers to measure the parameters that define HEL effectiveness. The two critical parameters for quantifying HEL effectiveness are the irradiance on target and resultant rise in target temperature. Off-board sensing has its limitations, including unpredictable changes in the reflectivity of the target, smoke and outgassing, and atmospheric distortion. On-board sensors overcome the limitations of off-board techniques but must survive high irradiance levels and extreme temperatures. We have developed sensors for on-target diagnostics of high energy laser beams and for the measurement of the thermal response of the target. The conformal sensors consist of an array of quantum dot photodetectors and resistive temperature detectors. The sensor arrays are lithographically fabricated on flexible substrates and can be attached to a variety of laser targets. We have developed a nanoparticle adhesive process that provides good thermal contact with the target and that ensures the sensor remains attached to the target for as long as the target survives. We have calibrated the temperature and irradiance sensors and demonstrated them in a HEL environment.

  15. HIGH ENERGY GASEOUS DISCHARGE DEVICES

    DOEpatents

    Josephson, V.

    1960-02-16

    The high-energy electrical discharge device described comprises an envelope, a pair of main discharge electrodes supported in opposition in the envelope, and a metallic shell symmetrically disposed around and spaced from the discharge path between the electrodes. The metallic shell comprises a first element of spaced helical turns of metallic material and a second element of spaced helical turns of methllic material insulatedly supported in superposition outside the first element and with the turns overlapping the gap between the turns of the first element.

  16. High Energy Astronomy Observatory (HEAO)

    NASA Technical Reports Server (NTRS)

    1972-01-01

    This is an artist's concept describing the High Energy Astronomy Observatory (HEAO). The HEAO project involved the launching of three unmarned scientific observatories into low Earth orbit between 1977 and 1979 to study some of the most intriguing mysteries of the universe; pulsars, black holes, neutron stars, and super nova. This concept was painted by Jack Hood of the Marshall Space Flight Center (MSFC). Hardware support for the imaging instruments was provided by American Science and Engineering. The HEAO spacecraft were built by TRW, Inc. under project management of the MSFC.

  17. Structural and thermodynamic factors of suppressed interdiffusion kinetics in multi-component high-entropy materials.

    PubMed

    Chang, Shou-Yi; Li, Chen-En; Huang, Yi-Chung; Hsu, Hsun-Feng; Yeh, Jien-Wei; Lin, Su-Jien

    2014-02-24

    We report multi-component high-entropy materials as extraordinarily robust diffusion barriers and clarify the highly suppressed interdiffusion kinetics in the multi-component materials from structural and thermodynamic perspectives. The failures of six alloy barriers with different numbers of elements, from unitary Ti to senary TiTaCrZrAlRu, against the interdiffusion of Cu and Si were characterized, and experimental results indicated that, with more elements incorporated, the failure temperature of the barriers increased from 550 to 900°C. The activation energy of Cu diffusion through the alloy barriers was determined to increase from 110 to 163 kJ/mole. Mechanistic analyses suggest that, structurally, severe lattice distortion strains and a high packing density caused by different atom sizes, and, thermodynamically, a strengthened cohesion provide a total increase of 55 kJ/mole in the activation energy of substitutional Cu diffusion, and are believed to be the dominant factors of suppressed interdiffusion kinetics through the multi-component barrier materials.

  18. Structural and Thermodynamic Factors of Suppressed Interdiffusion Kinetics in Multi-component High-entropy Materials

    PubMed Central

    Chang, Shou-Yi; Li, Chen-En; Huang, Yi-Chung; Hsu, Hsun-Feng; Yeh, Jien-Wei; Lin, Su-Jien

    2014-01-01

    We report multi-component high-entropy materials as extraordinarily robust diffusion barriers and clarify the highly suppressed interdiffusion kinetics in the multi-component materials from structural and thermodynamic perspectives. The failures of six alloy barriers with different numbers of elements, from unitary Ti to senary TiTaCrZrAlRu, against the interdiffusion of Cu and Si were characterized, and experimental results indicated that, with more elements incorporated, the failure temperature of the barriers increased from 550 to 900°C. The activation energy of Cu diffusion through the alloy barriers was determined to increase from 110 to 163 kJ/mole. Mechanistic analyses suggest that, structurally, severe lattice distortion strains and a high packing density caused by different atom sizes, and, thermodynamically, a strengthened cohesion provide a total increase of 55 kJ/mole in the activation energy of substitutional Cu diffusion, and are believed to be the dominant factors of suppressed interdiffusion kinetics through the multi-component barrier materials. PMID:24561911

  19. High-Energy-Density Capacitors

    NASA Technical Reports Server (NTRS)

    Slenes, Kirk

    2003-01-01

    Capacitors capable of storing energy at high densities are being developed for use in pulse-power circuits in such diverse systems as defibrillators, particle- beam accelerators, microwave sources, and weapons. Like typical previously developed energy-storage capacitors, these capacitors are made from pairs of metal/solid-dielectric laminated sheets that are wound and pressed into compact shapes to fit into cans, which are then filled with dielectric fluids. Indeed, these capacitors can be fabricated largely by conventional fabrication techniques. The main features that distinguish these capacitors from previously developed ones are improvements in (1) the selection of laminate materials, (2) the fabrication of the laminated sheets from these materials, and (3) the selection of dielectric fluids. In simplest terms, a high-performance laminated sheet of the type used in these capacitors is made by casting a dielectric polymer onto a sheet of aluminized kraft paper. The dielectric polymer is a siloxane polymer that has been modified with polar pendant groups to increase its permittivity and dielectric strength. Potentially, this polymer is capable of withstanding an energy density of 7.5 J/cm3, which is four times that of the previous state-of-the-art-capacitor dielectric film material. However, the full potential of this polymer cannot be realized at present because (1) at thicknesses needed for optimum performance (.8.0 m), the mechanical strength of a film of this polymer is insufficient for incorporation into a wound capacitor and (2) at greater thickness, the achievable energy density decreases because of a logarithmic decrease in dielectric strength with increasing thickness. The aluminized kraft paper provides the mechanical strength needed for processing of the laminate and fabrication of the capacitor, and the aluminum film serves as an electrode layer. Because part of the thickness of the dielectric is not occupied by the modified siloxane polymer, the

  20. Electron-Vibrational Energy Exchange in Nitrogen-Containing Plasma: a Comparison Between an Analytical Approach and a Kinetic Model

    NASA Astrophysics Data System (ADS)

    Yang, Wei; Dong, Zhiwei

    2016-01-01

    This paper investigates the electron-vibrational (e-V) energy exchange in nitrogen-containing plasma, which is very efficient in the case of gas discharge and high speed flow. Based on Harmonic oscillator approximation and the assumption of the e-V relaxation through a continuous series of Boltzmann distributions over the vibrational states, an analytic approach is derived from the proposed scaling relation of e-V transition rates. A full kinetic model is then investigated by numerically solving the state-to-state master equation for all vibrational levels. The analytical approach leads to a Landau-Teller (LT)-type equation for relaxation of vibrational energy, and predicts the relaxation time on the right order of magnitude. By comparison with the kinetic model, the LT-type equation is valid in typical electron temperatures in gas discharge. However, the analytical approach is not capable of describing the vibrational distribution function during the e-V process in which a full kinetic model is required. supported by National Natural Science Foundation of China (No. 11505015) and the National High-Tech Research and Development Program of China (863 Program)

  1. High-temperature quantum kinetic effect in silicon nanosandwiches

    NASA Astrophysics Data System (ADS)

    Bagraev, N. T.; Grigoryev, V. Yu.; Klyachkin, L. E.; Malyarenko, A. M.; Mashkov, V. A.; Romanov, V. V.; Rul, N. I.

    2017-01-01

    The negative-U impurity stripes confining the edge channels of semiconductor quantum wells are shown to allow the effective cooling inside in the process of the spin-dependent transport, with the reduction of the electron-electron interaction. The aforesaid promotes also the creation of composite bosons and fermions by the capture of single magnetic flux quanta on the edge channels under the conditions of low sheet density of carriers, thus opening new opportunities for the registration of the quantum kinetic phenomena in weak magnetic fields at high-temperatures up to the room temperature. As a certain version noted above we present the first findings of the high temperature de Haas-van Alphen, 300 K, quantum Hall, 77 K, effects as well as quantum conductance staircase in the silicon sandwich structure that represents the ultra-narrow, 2 nm, p-type quantum well (Si-QW) confined by the delta barriers heavily doped with boron on the n-type Si (100) surface.

  2. Fully kinetic particle simulations of high pressure streamer propagation

    NASA Astrophysics Data System (ADS)

    Rose, David; Welch, Dale; Thoma, Carsten; Clark, Robert

    2012-10-01

    Streamer and leader formation in high pressure devices is a dynamic process involving a hierarchy of physical phenomena. These include elastic and inelastic particle collisions in the gas, radiation generation, transport and absorption, and electrode interactions. We have performed 2D and 3D fully EM implicit particle-in-cell simulation model of gas breakdown leading to streamer formation under DC and RF fields. The model uses a Monte Carlo treatment for all particle interactions and includes discrete photon generation, transport, and absorption for ultra-violet and soft x-ray radiation. Central to the realization of this fully kinetic particle treatment is an algorithm [D. R. Welch, et al., J. Comp. Phys. 227, 143 (2007)] that manages the total particle count by species while preserving the local momentum distribution functions and conserving charge. These models are being applied to the analysis of high-pressure gas switches [D. V. Rose, et al., Phys. Plasmas 18, 093501 (2011)] and gas-filled RF accelerator cavities [D. V. Rose, et al. Proc. IPAC12, to appear].

  3. High Energy Density Laboratory Astrophysics

    SciTech Connect

    Remington, B A

    2004-11-11

    High-energy-density (HED) physics refers broadly to the study of macroscopic collections of matter under extreme conditions of temperature and density. The experimental facilities most widely used for these studies are high-power lasers and magnetic-pinch generators. The HED physics pursued on these facilities is still in its infancy, yet new regimes of experimental science are emerging. Examples from astrophysics include work relevant to planetary interiors, supernovae, astrophysical jets, and accreting compact objects (such as neutron stars and black holes). In this paper, we will review a selection of recent results in this new field of HED laboratory astrophysics and provide a brief look ahead to the coming decade.

  4. Development of the cycloidal propeller StECon as a new small hydropower plant for kinetic energy

    NASA Astrophysics Data System (ADS)

    Schmidt, J.; Jensen, J.; Wieland, J.; Lohr, W.; Metzger, J.; Stiller, H.-L.

    2016-11-01

    The StECon (Stiller Energy Converter) is a promising new small hydropower plant for kinetic energy. It is an invention of Mr. Hans-Ludwig Stiller and has several advantages compared to the technologies for the use of hydropower known for millennia. It runs completely submerged forwards and backwards, with horizontal or vertical axis and has a compact design by using a single or a double-sided planetary gear with optimum alignment to the flow direction. The possible applications include mobile and stationary tide and current generators as well as hybrid solutions, either as a generator or as a propulsion system. The high expectations have to be confirmed in a research project StEwaKorad at the University of Siegen. Aim of this research project is to investigate the performance and characteristics of the StECon as an energy converter for producing renewable energy from hydropower with low fall heights including sea currents.

  5. Fast electron energy deposition in a magnetized plasma: Kinetic theory and particle-in-cell simulation

    SciTech Connect

    Robiche, J.; Rax, J.-M.; Bonnaud, G.; Gremillet, L.

    2010-03-15

    The collisional dynamics of a relativistic electron jet in a magnetized plasma are investigated within the framework of kinetic theory. The relativistic Fokker-Planck equation describing slowing down, pitch angle scattering, and cyclotron rotation is derived and solved. Based on the solution of this Fokker-Planck equation, an analytical formula for the root mean square spot size transverse to the magnetic field is derived and this result predicts a reduction in radial transport. Some comparisons with particle-in-cell simulation are made and confirm striking agreement between the theory and the simulation. For fast electron with 1 MeV typical kinetic energy interacting with a solid density hydrogen plasma, the energy deposition density in the transverse direction increases by a factor 2 for magnetic field of the order of 1 T. Along the magnetic field, the energy deposition profile is unaltered compared with the field-free case.

  6. Kinetic Energy of Hydrocarbons as a Function of Electron Density and Convolutional Neural Networks.

    PubMed

    Yao, Kun; Parkhill, John

    2016-03-08

    We demonstrate a convolutional neural network trained to reproduce the Kohn-Sham kinetic energy of hydrocarbons from an input electron density. The output of the network is used as a nonlocal correction to conventional local and semilocal kinetic functionals. We show that this approximation qualitatively reproduces Kohn-Sham potential energy surfaces when used with conventional exchange correlation functionals. The density which minimizes the total energy given by the functional is examined in detail. We identify several avenues to improve on this exploratory work, by reducing numerical noise and changing the structure of our functional. Finally we examine the features in the density learned by the neural network to anticipate the prospects of generalizing these models.

  7. Buoyant production and consumption of turbulence kinetic energy in cloud-topped mixed layers

    NASA Technical Reports Server (NTRS)

    Randall, D. A.

    1984-01-01

    It is pointed out that studies of the entraining planetary boundary layer (PBL) have generally emphasized the role of buoyancy fluxes in driving entrainment. The buoyancy flux is proportional to the rate of conversion of the potential energy of the mean flow into the kinetic energy of the turbulence. It is not unusual for conversion to proceed in both directions simultaneously. This occurs, for instance, in both clear and cloudy convective mixed layers which are capped by inversions. A partitioning of the net conversion into positive parts, generating turbulence kinetic energy (TKE), and negative parts (TKE-consuming), would make it possible to include the positive part in the gross production rate, and closure would be achieved. Three different approaches to partitioning have been proposed. The present investigation is concerned with a comparison of the three partitioning theories. Particular attention is given to the cloud-topped mixed layer because in this case the differences between two partitioning approaches are most apparent.

  8. Rock Cutting Depth Model Based on Kinetic Energy of Abrasive Waterjet

    NASA Astrophysics Data System (ADS)

    Oh, Tae-Min; Cho, Gye-Chun

    2016-03-01

    Abrasive waterjets are widely used in the fields of civil and mechanical engineering for cutting a great variety of hard materials including rocks, metals, and other materials. Cutting depth is an important index to estimate operating time and cost, but it is very difficult to predict because there are a number of influential variables (e.g., energy, geometry, material, and nozzle system parameters). In this study, the cutting depth is correlated to the maximum kinetic energy expressed in terms of energy (i.e., water pressure, water flow rate, abrasive feed rate, and traverse speed), geometry (i.e., standoff distance), material (i.e., α and β), and nozzle system parameters (i.e., nozzle size, shape, and jet diffusion level). The maximum kinetic energy cutting depth model is verified with experimental test data that are obtained using one type of hard granite specimen for various parameters. The results show a unique curve for a specific rock type in a power function between cutting depth and maximum kinetic energy. The cutting depth model developed here can be very useful for estimating the process time when cutting rock using an abrasive waterjet.

  9. Proton kinetic effects and turbulent energy cascade rate in the solar wind.

    PubMed

    Osman, K T; Matthaeus, W H; Kiyani, K H; Hnat, B; Chapman, S C

    2013-11-15

    The first observed connection between kinetic instabilities driven by proton temperature anisotropy and estimated energy cascade rates in the turbulent solar wind is reported using measurements from the Wind spacecraft at 1 AU. We find enhanced cascade rates are concentrated along the boundaries of the (β∥, T⊥/T∥) plane, which includes regions theoretically unstable to the mirror and firehose instabilities. A strong correlation is observed between the estimated cascade rate and kinetic effects such as temperature anisotropy and plasma heating, resulting in protons 5-6 times hotter and 70%-90% more anisotropic than under typical isotropic plasma conditions. These results offer new insights into kinetic processes in a turbulent regime.

  10. Proton Kinetic Effects and Turbulent Energy Cascade Rate in the Solar Wind

    NASA Astrophysics Data System (ADS)

    Osman, K. T.; Matthaeus, W. H.; Kiyani, K. H.; Hnat, B.; Chapman, S. C.

    2013-11-01

    The first observed connection between kinetic instabilities driven by proton temperature anisotropy and estimated energy cascade rates in the turbulent solar wind is reported using measurements from the Wind spacecraft at 1 AU. We find enhanced cascade rates are concentrated along the boundaries of the (β∥, T⊥/T∥) plane, which includes regions theoretically unstable to the mirror and firehose instabilities. A strong correlation is observed between the estimated cascade rate and kinetic effects such as temperature anisotropy and plasma heating, resulting in protons 5-6 times hotter and 70%-90% more anisotropic than under typical isotropic plasma conditions. These results offer new insights into kinetic processes in a turbulent regime.

  11. Proton Kinetic Effects and Turbulent Energy Cascade Rate in the Solar Wind

    NASA Astrophysics Data System (ADS)

    Osman, K.; Matthaeus, W. H.; Kiyani, K. H.; Hnat, B.; Chapman, S. C.

    2013-12-01

    The first observed connection between kinetic instabilities driven by proton temperature anisotropy and estimated energy cascade rates in the turbulent solar wind is reported using measurements from the Wind spacecraft at 1 AU. We find enhanced cascade rates are concentrated along the boundaries of the (β‖,T⊥/T‖)-plane, which includes regions theoretically unstable to the mirror and firehose instabilities. A strong correlation is observed between the estimated cascade rates and kinetic effects such as temperature anisotropy and plasma heating, resulting in protons 5-6 times hotter and 70-90% more anisotropic than under typical isotropic plasma conditions. These results offer new insights into kinetic processes in a turbulent regime.

  12. Membrane bending energy and fusion pore kinetics in Ca(2+)-triggered exocytosis.

    PubMed

    Zhang, Zhen; Jackson, Meyer B

    2010-06-02

    A fusion pore composed of lipid is an obligatory kinetic intermediate of membrane fusion, and its formation requires energy to bend membranes into highly curved shapes. The energetics of such deformations in viral fusion is well established, but the role of membrane bending in Ca(2+)-triggered exocytosis remains largely untested. Amperometry recording showed that during exocytosis in chromaffin and PC12 cells, fusion pores formed by smaller vesicles dilated more rapidly than fusion pores formed by larger vesicles. The logarithm of 1/(fusion pore lifetime) varied linearly with vesicle curvature. The vesicle size dependence of fusion pore lifetime quantitatively accounted for the nonexponential fusion pore lifetime distribution. Experimentally manipulating vesicle size failed to alter the size dependence of fusion pore lifetime. Manipulations of membrane spontaneous curvature altered this dependence, and applying the curvature perturbants to the opposite side of the membrane reversed their effects. These effects of curvature perturbants were opposite to those seen in viral fusion. These results indicate that during Ca(2+)-triggered exocytosis membrane bending opposes fusion pore dilation rather than fusion pore formation. Ca(2+)-triggered exocytosis begins with a proteinaceous fusion pore with less stressed membrane, and becomes lipidic as it dilates, bending membrane into a highly curved shape.

  13. Isoflavone Profiles and Kinetic Changes during Ultra-High Temperature Processing of Soymilk.

    PubMed

    Zhang, Yan; Chang, Sam K C

    2016-03-01

    Isoflavone profile is greatly affected by heating process. However, kinetic analyses of isoflavone conversion and degradation using a continuous industry processing method have never been characterized. In this study, Proto soybean was soaked and blanched at 80 °C for 2 min and then processed into soymilk, which underwent UHT (ultra-high temperature) at 135 to 150 °C for 10 to 50 s with a pilot plant-scale Microthermics processor. The isoflavone profile was determined at different time/temperature combinations. The results showed that all isoflavone forms exhibited distinct changing patterns over time. In the soymilk under UHT conditions, the degradation (disappearance) of malonyldaizin and malonylgenistin exhibited first-order kinetics with activation energies of 59 and 84 kj/mole, respectively. At all UHT temperatures, malonylgenistin showed higher rate constants than malonyldaidzin. However, malonylglycitin changed irregularly under these UHT temperatures. The increase of genistin, daidzin, glycitein and acetlydaidzin during heating demonstrated zero-order kinetics and the rate constants increased with temperature except for the conditions of 145 to 150 °C for 50 s. Overall, genistein series exhibited higher stability than daidzein series. Under all UHT conditions, total isoflavone decreased from 12% to 24%.

  14. Kinetics and Microstructural Investigation of High-Temperature Oxidation of IN-738LC Super Alloy

    NASA Astrophysics Data System (ADS)

    Hamidi, S.; Rahimipour, M. R.; Eshraghi, M. J.; Hadavi, S. M. M.; Esfahani, H.

    2016-12-01

    The present study was carried out to investigate the kinetics and the surface chemistry of the oxide layers formed on the IN-738LC super alloy during high-temperature oxidation at 950 °C in air from 1 to 260 h. Oxidation kinetics were studied by mass gain measurement. The oxide layers were characterized by field emission scanning electron microscope, elemental distribution map, energy-dispersive spectroscopy as well as x-ray diffractometry (XRD). The oxidation kinetics followed the parabolic law. The XRD analysis revealed that the oxide scale contained mainly NiO, Ni (Cr, Al)2O4, Al2O3, TiO2 and Cr2O3. The oxide structure, from the top surface down to the substrate, was clarified by elemental map distribution studies as Ni-Ti oxides, Cr-Ti oxides, Cr2O3 oxide band, Ni-Co-Cr-W oxide and finally a blocky Al2O3 region. The oxidation scales were composed of three distinct layers of the outer and mid layers enriched by TiO2 and Cr2O3, NiCr2O4 oxide, respectively, and the innermost layer was composed of Al2O3 and matrix alloy. The depleted gamma prime layer was formed under the oxidation scales due to the impoverishment of Al and Ti which were induced by the formation of Al2O3 and TiO2.

  15. Kinetics and Microstructural Investigation of High-Temperature Oxidation of IN-738LC Super Alloy

    NASA Astrophysics Data System (ADS)

    Hamidi, S.; Rahimipour, M. R.; Eshraghi, M. J.; Hadavi, S. M. M.; Esfahani, H.

    2017-02-01

    The present study was carried out to investigate the kinetics and the surface chemistry of the oxide layers formed on the IN-738LC super alloy during high-temperature oxidation at 950 °C in air from 1 to 260 h. Oxidation kinetics were studied by mass gain measurement. The oxide layers were characterized by field emission scanning electron microscope, elemental distribution map, energy-dispersive spectroscopy as well as x-ray diffractometry (XRD). The oxidation kinetics followed the parabolic law. The XRD analysis revealed that the oxide scale contained mainly NiO, Ni (Cr, Al)2O4, Al2O3, TiO2 and Cr2O3. The oxide structure, from the top surface down to the substrate, was clarified by elemental map distribution studies as Ni-Ti oxides, Cr-Ti oxides, Cr2O3 oxide band, Ni-Co-Cr-W oxide and finally a blocky Al2O3 region. The oxidation scales were composed of three distinct layers of the outer and mid layers enriched by TiO2 and Cr2O3, NiCr2O4 oxide, respectively, and the innermost layer was composed of Al2O3 and matrix alloy. The depleted gamma prime layer was formed under the oxidation scales due to the impoverishment of Al and Ti which were induced by the formation of Al2O3 and TiO2.

  16. High content kinetic assays of neuronal signaling implemented on BD pathway HT.

    PubMed

    Chan, Grace K Y; Richards, Gillian R; Peters, Marco; Simpson, Peter B

    2005-12-01

    A great deal of information can be gained from kinetic fluorescence-based measurement of cellular responses; however, until recently the use of such approaches has been limited by the manual nature of the instrumentation available. Higher-throughput kinetic studies of signaling pathways are greatly facilitated by new confocal, liquid handling-enabled, high content screening (HCS) platforms. In the present work, we have implemented one such instrument, the BD(TM) Pathway HT bioimager (BD Biosciences, Rockville, MD), for studying regulation of neuronal signaling pathways. We have established a neuronal calcium oscillation model, whereby rate of oscillation, amplitude of oscillation, and level of synchronicity across the culture can be measured. We have implemented membrane potential measurement using fluorescence resonance energy transfer-based dyes, for single cell characterization on this platform, showing the benefits of a truly flexible excitation and recording system; this dye combination cannot be readily implemented on all HCS platforms because of constraints of excitation wavelengths. We have validated long-term intracellular calcium imaging experiments, using innovative dyes and BD Pathway HT's spinning disk-based confocal excitation. To maximize both throughput and reproducibility, walk-away automation integration of this bioimaging technology has been implemented, producing an affordable, compact platform for fully automated kinetic HCS.

  17. Effects of crystal-melt interfacial energy anisotropy on dendritic morphology and growth kinetics

    NASA Technical Reports Server (NTRS)

    Glicksman, M. E.; Singh, N. B.

    1989-01-01

    Morphological and kinetic studies of succinonitrile, a BCC crystal with a low (0.5 percent) anisotropy and pivalic acid, and FCC crystal with relatively large (5 percent) anisotropy in solid-liquid interfacial energy, show clearly that anisotropy in the solid-liquid interfacial energy does not affect the tip radius-velocity relationship, but has a profound influence on the tip region and the rate of amplification of branching waves. Anisotropy of the solid-liquid interfacial energy may be one of the key factors by which the microstructural characteristics of cast structures reflect individual material behavior, especially crystal symmetry.

  18. A diaphragmless shock tube for high temperature kinetic studies

    SciTech Connect

    Tranter, Robert S.; Giri, Binod R.

    2008-09-15

    A novel, diaphragmless shock tube (DFST) has been developed for use in high temperature chemical kinetic studies. The design of the apparatus is presented along with performance data that demonstrate the range and reproducibility of reaction conditions that can be generated. The ability to obtain data in the fall off region, confined to much narrower pressure ranges than can be obtained with a conventional shock tube is shown, and results from laser schlieren densitometry experiments on the unimolecular dissociation of phenyl iodide (P{sub 2}=57{+-}9 and 122{+-}7 torr, T{sub 2}=1250-1804 K) are presented. These are compared with results similar to those that would be obtained from a classical shock tube and the implications for extrapolation by theoretical methods are discussed. Finally, the use of the DFST with an online mass spectrometer to create reproducible experiments that can be signal averaged to improve signal/noise and the quality of mass peaks is demonstrated; something that is not possible with a conventional shock tube where each experiment has to be considered unique.

  19. Mapping the High-Dimensional ISM with Kinetic Tomography

    NASA Astrophysics Data System (ADS)

    Zasowski, Gail; Peek, Joshua Eli Goldston; Tchernyshyov, Kirill

    2017-01-01

    The interstellar medium (ISM) of a galaxy plays a critical role in its chemical evolution, via flows of enriched material into and out of star-forming molecular clouds, and even more expansive flows on kiloparsec scales through the disk and halo. The Milky Way is the only large galaxy in which we can resolve these motions at the level of individual molecular clouds, measure the kinematics of interstellar dust, and map the full three-dimensional velocity field of multiple ISM components; all of these are necessary to understand the evolution of spiral arms and molecular clouds, along with the redistribution of heavy elements throughout the Galaxy. I will present early results from a novel technique called "kinetic tomography", in which we combine stellar reddening (from Pan-STARRS), interstellar emission (CO and HI), and interstellar absorption (from APOGEE) data into high-dimensional datasets, and then extract distance-resolved kinematic information on multiple phases of the ISM. These methods are providing new views on the evolution of molecular clouds and chemical mixing in the ISM.

  20. Experimental High Energy Physics Research

    SciTech Connect

    Hohlmann, Marcus

    2016-01-13

    This final report summarizes activities of the Florida Tech High Energy Physics group supported by DOE under grant #DE-SC0008024 during the period June 2012 – March 2015. We focused on one of the main HEP research thrusts at the Energy Frontier by participating in the CMS experiment. We were exploiting the tremendous physics opportunities at the Large Hadron Collider (LHC) and prepared for physics at its planned extension, the High-Luminosity LHC. The effort comprised a physics component with analysis of data from the first LHC run and contributions to the CMS Phase-2 upgrades in the muon endcap system (EMU) for the High-Luminosity LHC. The emphasis of our hardware work was the development of large-area Gas Electron Multipliers (GEMs) for the CMS forward muon upgrade. We built a production and testing site for such detectors at Florida Tech to complement future chamber production at CERN. The first full-scale CMS GE1/1 chamber prototype ever built outside of CERN was constructed at Florida Tech in summer 2013. We conducted two beam tests with GEM prototype chambers at CERN in 2012 and at FNAL in 2013 and reported the results at conferences and in publications. Principal Investigator Hohlmann served as chair of the collaboration board of the CMS GEM collaboration and as co-coordinator of the GEM detector working group. He edited and authored sections of the detector chapter of the Technical Design Report (TDR) for the GEM muon upgrade, which was approved by the LHCC and the CERN Research Board in 2015. During the course of the TDR approval process, the GEM project was also established as an official subsystem of the muon system by the CMS muon institution board. On the physics side, graduate student Kalakhety performed a Z' search in the dimuon channel with the 2011 and 2012 CMS datasets that utilized 20.6 fb⁻¹ of p-p collisions at √s = 8 TeV. For the dimuon channel alone, the 95% CL lower limits obtained on the mass of a Z' resonance are 2770 GeV for a Z

  1. High energy beam lifetime analysis

    SciTech Connect

    Howell, R.H.; Sterne, P.A.; Hartley, J.; Cowan, T.E.

    1997-05-01

    We have developed a positron lifetime defect analysis capability based on a 3 MeV electrostatic accelerator. The high energy beam lifetime spectrometer is operational with a 60 mCi {sup 22}Na source providing a current of 7 10{sup 5} positrons per second. Lifetime data are derived from a thin plastic transmission detector providing an implantation time and a BaF{sub 2} detector to determine the annihilation time. Positron lifetime analysis is performed with a 3 MeV positron beam on thick sample specimens at counting rates in excess of 2000 per second. The instrument is being used for bulk sample analysis and analysis of samples encapsulated in controlled environments for in situ measurements.

  2. High energy femtosecond pulse compression

    NASA Astrophysics Data System (ADS)

    Lassonde, Philippe; Mironov, Sergey; Fourmaux, Sylvain; Payeur, Stéphane; Khazanov, Efim; Sergeev, Alexander; Kieffer, Jean-Claude; Mourou, Gerard

    2016-07-01

    An original method for retrieving the Kerr nonlinear index was proposed and implemented for TF12 heavy flint glass. Then, a defocusing lens made of this highly nonlinear glass was used to generate an almost constant spectral broadening across a Gaussian beam profile. The lens was designed with spherical curvatures chosen in order to match the laser beam profile, such that the product of the thickness with intensity is constant. This solid-state optics in combination with chirped mirrors was used to decrease the pulse duration at the output of a terawatt-class femtosecond laser. We demonstrated compression of a 33 fs pulse to 16 fs with 170 mJ energy.

  3. Oxides having high energy densities

    DOEpatents

    Ceder, Gerbrand; Kang, Kisuk

    2013-09-10

    Certain disclosed embodiments generally relate to oxide materials having relatively high energy and/or power densities. Various aspects of the embodiments are directed to oxide materials having a structure B.sub.i(M.sub.jY.sub.k)O.sub.2, for example, a structure Li.sub.j(Ni.sub.jY.sub.k)O.sub.2 such as Li(Ni.sub.0.5Mn.sub.0.5)O.sub.2. In this structure, Y represents one or more atoms, each independently selected from the group consisting of alkaline earth metals, transition metals, Group 14 elements, Group 15, or Group 16 elements. In some embodiments, such an oxide material may have an O3 crystal structure, and/or a layered structure such that the oxide comprises a plurality of first, repeating atomic planes comprising Li, and a plurality of second, repeating atomic planes comprising Ni and/or Y.

  4. High Energy Efficiency Air Conditioning

    SciTech Connect

    Edward McCullough; Patrick Dhooge; Jonathan Nimitz

    2003-12-31

    This project determined the performance of a new high efficiency refrigerant, Ikon B, in a residential air conditioner designed to use R-22. The refrigerant R-22, used in residential and small commercial air conditioners, is being phased out of production in developed countries beginning this year because of concerns regarding its ozone depletion potential. Although a replacement refrigerant, R-410A, is available, it operates at much higher pressure than R-22 and requires new equipment. R-22 air conditioners will continue to be in use for many years to come. Air conditioning is a large part of expensive summer peak power use in many parts of the U.S. Previous testing and computer simulations of Ikon B indicated that it would have 20 - 25% higher coefficient of performance (COP, the amount of cooling obtained per energy used) than R-22 in an air-cooled air conditioner. In this project, a typical new R-22 residential air conditioner was obtained, installed in a large environmental chamber, instrumented, and run both with its original charge of R-22 and then with Ikon B. In the environmental chamber, controlled temperature and humidity could be maintained to obtain repeatable and comparable energy use results. Tests with Ikon B included runs with and without a power controller, and an extended run for several months with subsequent analyses to check compatibility of Ikon B with the air conditioner materials and lubricant. Baseline energy use of the air conditioner with its original R-22 charge was measured at 90 deg F and 100 deg F. After changeover to Ikon B and a larger expansion orifice, energy use was measured at 90 deg F and 100 deg F. Ikon B proved to have about 19% higher COP at 90 deg F and about 26% higher COP at 100 deg F versus R-22. Ikon B had about 20% lower cooling capacity at 90 deg F and about 17% lower cooling capacity at 100 deg F versus R-22 in this system. All results over multiple runs were within 1% relative standard deviation (RSD). All of these

  5. Effect of heating rate and kinetic model selection on activation energy of nonisothermal crystallization of amorphous felodipine.

    PubMed

    Chattoraj, Sayantan; Bhugra, Chandan; Li, Zheng Jane; Sun, Changquan Calvin

    2014-12-01

    The nonisothermal crystallization kinetics of amorphous materials is routinely analyzed by statistically fitting the crystallization data to kinetic models. In this work, we systematically evaluate how the model-dependent crystallization kinetics is impacted by variations in the heating rate and the selection of the kinetic model, two key factors that can lead to significant differences in the crystallization activation energy (Ea ) of an amorphous material. Using amorphous felodipine, we show that the Ea decreases with increase in the heating rate, irrespective of the kinetic model evaluated in this work. The model that best describes the crystallization phenomenon cannot be identified readily through the statistical fitting approach because several kinetic models yield comparable R(2) . Here, we propose an alternate paired model-fitting model-free (PMFMF) approach for identifying the most suitable kinetic model, where Ea obtained from model-dependent kinetics is compared with those obtained from model-free kinetics. The most suitable kinetic model is identified as the one that yields Ea values comparable with the model-free kinetics. Through this PMFMF approach, nucleation and growth is identified as the main mechanism that controls the crystallization kinetics of felodipine. Using this PMFMF approach, we further demonstrate that crystallization mechanism from amorphous phase varies with heating rate.

  6. Hierarchical expansion of the kinetic energy operator in curvilinear coordinates for the vibrational self-consistent field method.

    PubMed

    Strobusch, D; Scheurer, Ch

    2011-09-28

    A new hierarchical expansion of the kinetic energy operator in curvilinear coordinates is presented and modified vibrational self-consistent field (VSCF) equations are derived including all kinematic effects within the mean field approximation. The new concept for the kinetic energy operator is based on many-body expansions for all G matrix elements and its determinant. As a test application VSCF computations were performed on the H(2)O(2) molecule using an analytic potential (PCPSDE) and different hierarchical approximations for the kinetic energy operator. The results indicate that coordinate-dependent reduced masses account for the largest part of the kinetic energy. Neither kinematic couplings nor derivatives of the G matrix nor its determinant had significant effects on the VSCF energies. Only the zero-point value of the pseudopotential yields an offset to absolute energies which, however, is irrelevant for spectroscopic problems.

  7. Kinetic-Energy Distribution of D(2p) Atoms from Analysis of the D Lyman-Alpha Line Profile

    NASA Technical Reports Server (NTRS)

    Ciocca, M.; Ajello, Joseph M.; Liu, Xianming; Maki, Justin

    1997-01-01

    The kinetic-energy distribution of D(2p) atoms resulting from electron-impact dissociation of D2 has been measured. A high-resolution vacuum ultraviolet spectrometer was employed for the first measurement of the D Lyman-alpha (D L(alpha)) emission line profiles at 20- and 100-eV excitation energies. Analysis of the deconvoluted line profile of D L(alpha) at 100 eV reveals the existence of a narrow line central peak of 29+/-2 mA full width at half maximum and a broad pedestal wing structure about 190 mA wide. The wings of the line can be used to determine the fast atom distribution. The wings of D L(alpha) arise from dissociative excitation of a series of doubly excited states that cross the Franck-Condon region between 23 and 40 eV. The fast atom distribution at 100-eV electron impact energy spans the energy range from 1 to 10 eV with a peak value near 6 eV. Slow D(2p) atoms characterized by a distribution function with peak energy near 100 meV produce the central peak profile, which is nearly independent of the impact energy. The deconvoluted line profiles of the central peak at 20 eV for dissociative excitation of D2 and H2 are fitted with an analytical function for use in calibration of space flight instrumentation equipped with a D/H absorption cell. The kinetic-energy and line profile results are compared to similar measurements for H2. The absolute cross sections for the line center (slow atoms) and wings (fast atoms) and total emission line profile were measured from threshold to 400 eV. Analytical model coefficients are given for the energy dependence of the measured slow atom cross section.

  8. High-resolution threshold photoelectron-photoion coincidence experiments performed on beamline 9.0.2.2: Kinetic energy release study of the process SF{sub 6} + hv {yields} SF{sub 5}{sup +} F + e{sup -}

    SciTech Connect

    Evans, M.; Ng, C.Y.; Hsu, C.W.; Heimann, P.

    1997-04-01

    Vacuum ultraviolet (VUV) photoionization mass spectrometry has been used extensively to determine the energetics of neutral radicals and radical cations, as well as to study the dynamics of the dissociative photoionization process. Very often these measurements are concerned with determining the appearance energy (AE) for a dissociative ionization process, as well as determining the heats of formation of the species involved. One such photoionization mass spectrometric technique employed on End Station 2 of the Chemical Dynamics Beamline (9.0.2.2) at the Advanced Light Source is the threshold photoelectron-photoion coincidence (TPEPICO) method. TPEPICO involves measuring the time-of-flight (TOF) mass spectrum of a given cation in coincidence with threshold photoelectrons at a known photoionization energy.

  9. Quantum oscillations in the kinetic energy density: Gradient corrections from the Airy gas

    NASA Astrophysics Data System (ADS)

    Lindmaa, Alexander; Mattsson, Ann E.; Armiento, Rickard

    2014-03-01

    We show how one can systematically derive exact quantum corrections to the kinetic energy density (KED) in the Thomas-Fermi (TF) limit of the Airy gas (AG). The resulting expression is of second order in the density variation and we demonstrate how it applies universally to a certain class of model systems in the slowly varying regime, for which the accuracy of the gradient corrections of the extended Thomas-Fermi (ETF) model is limited. In particular we study two kinds of related electronic edges, the Hermite gas (HG) and the Mathieu gas (MG), which are both relevant for discussing periodic systems. We also consider two systems with finite integer particle number, namely non-interacting electrons subject to harmonic confinement as well as the hydrogenic potential. Finally we discuss possible implications of our findings mainly related to the field of functional development of the local kinetic energy contribution.

  10. Budget of Turbulent Kinetic Energy in a Shock Wave Boundary-Layer Interaction

    NASA Technical Reports Server (NTRS)

    Vyas, Manan A.; Waindim, Mbu; Gaitonde, Datta V.

    2016-01-01

    Implicit large-eddy simulation (ILES) of a shock wave/boundary-layer interaction (SBLI) was performed. Quantities present in the exact equation of the turbulent kinetic energy transport were accumulated and used to calculate terms like production, dissipation, molecular diffusion, and turbulent transport. The present results for a turbulent boundary layer were validated by comparison with direct numerical simulation data. It was found that a longer development domain was necessary for the boundary layer to reach an equilibrium state and a finer mesh resolution would improve the predictions. In spite of these findings, trends of the present budget match closely with that of the direct numerical simulation. Budgets for the SBLI region are presented at key axial stations. These budgets showed interesting dynamics as the incoming boundary layer transforms and the terms of the turbulent kinetic energy budget change behavior within the interaction region.

  11. Optimisation of dynamic vibration absorbers to minimise kinetic energy and maximise internal power dissipation

    NASA Astrophysics Data System (ADS)

    Zilletti, Michele; Elliott, Stephen J.; Rustighi, Emiliano

    2012-08-01

    The tuning of a dynamic vibration absorber is considered such that either the kinetic energy of the host structure is minimised or the power dissipation within the absorber is maximised. If the host structure is approximated as a damped single degree of freedom, the optimal values for the ratio of the absorber's natural frequency to the host structure and the optimal damping ratio of the absorber are shown to be the same whether the kinetic energy of the host structure is minimised or the power dissipation of the absorber is maximised. It is also demonstrated that the total power input into the system does not depend on the two parameters but only on the host structure's mass.

  12. The onset of sediment transport in vegetated channels predicted by turbulent kinetic energy

    NASA Astrophysics Data System (ADS)

    Yang, J. Q.; Chung, H.; Nepf, H. M.

    2016-11-01

    This laboratory study advances our understanding of sediment transport in vegetated regions, by describing the impact of stem density on the critical velocity, Ucrit, at which sediment motion is initiated. Sparse emergent vegetation was modeled with rigid cylinders arranged in staggered arrays of different stem densities. The sediment transport rate, Qs, was measured over a range of current speeds using digital imaging, and the critical velocity was selected as the condition at which the magnitude of Qs crossed the noise threshold. For both grain sizes considered here (0.6-0.85 mm and 1.7-2 mm), Ucrit decreased with increasing stem density. This dependence can be explained by a threshold condition based on turbulent kinetic energy, kt, suggesting that near-bed turbulence intensity may be a more important control than bed shear stress on the initiation of sediment motion. The turbulent kinetic energy model unified the bare bed and vegetated channel measurements.

  13. Connectivity of Marine Protected Areas and Its Relation with Total Kinetic Energy

    PubMed Central

    D’Agostini, Andressa; Gherardi, Douglas Francisco Marcolino; Pezzi, Luciano Ponzi

    2015-01-01

    The East Continental Shelf (ECS) of Brazil is a hotspot of endemism and biodiversity of reef biota in the South Atlantic, hosting a number of Marine Protected Areas (MPAs). Connectivity of MPAs through larval dispersal influences recruitment, population dynamics, genetic structure and biogeography in coral reef ecosystems. Connectivity of protected reef ecosystem in the ECS was investigated with a hydrodynamic model (ROMS) forcing an Individual Based Model (IBM—Ichthyop), and used groupers (genus Mycteroperca) as functional group. The hydrodynamic output from ROMS was compared with satellite data and showed good agreement with observed surface fields. Eggs were released, in IBM experiments, from April to September along six years (2002–2007) in five MPAs along the ECS. Intrannual variability in recruitment and self-recruitment of grouper larvae was observed, as well as a negative correlation of these population parameters with total Kinetic Energy (KE) used as a metric of the physical environment. Higher KE leads to increased offshore advection of larvae, reduced total recruitment and connectivity of MPAs. Our results indicate high and uni-directional connectivity between MPAs from north to south influenced by the Brazil Current flowing in the same direction. Results also showed that some MPAs act predominantly as “sink” while others are mainly “source” areas. PMID:26448650

  14. Large-scale kinetic energy spectra from Eulerian analysis of EOLE wind data

    NASA Technical Reports Server (NTRS)

    Desbois, M.

    1975-01-01

    A data set of 56,000 winds determined from the horizontal displacements of EOLE balloons at the 200 mb level in the Southern Hemisphere during the period October 1971-February 1972 is utilized for the computation of planetary- and synoptic-scale kinetic energy space spectra. However, the random distribution of measurements in space and time presents some problems for the spectral analysis. Two different approaches are used, i.e., a harmonic analysis of daily wind values at equi-distant points obtained by space-time interpolation of the data, and a correlation method using the direct measurements. Both methods give similar results for small wavenumbers, but the second is more accurate for higher wavenumbers (k above or equal to 10). The spectra show a maximum at wavenumbers 5 and 6 due to baroclinic instability and then decrease for high wavenumbers up to wavenumber 35 (which is the limit of the analysis), according to the inverse power law k to the negative p, with p close to 3.

  15. Eigenvalue spectrum of the independent-fermion kinetic-energy kernel

    SciTech Connect

    Joubert, D.

    1996-09-01

    The constrained minimization independent-fermion kinetic-energy kernel, {delta}{sup 2}{ital T}{sub {ital s}}[{rho}]/{delta}{rho}({bold r}){delta}{rho}({bold r}{sup {prime}}), has a zero mode for all {rho}({bold r}), while it is non-negative for {rho}({bold r}) noninteracting {ital v} representable. {copyright} {ital 1996 The American Physical Society.}

  16. Budget of Turbulent Kinetic Energy in a Shock Wave Boundary-Layer Interaction

    NASA Technical Reports Server (NTRS)

    Vyas, Manan; Waindim, Mbu; Gaitonde, Datta

    2016-01-01

    Implicit large-eddy simulation (ILES) of a shock wave boundary-layer interaction (SBLI) was performed. Quantities present in the exact equation of the turbulent kinetic energy (TKE) transport were accumulated. These quantities will be used to calculate the components of TKE-like production, dissipation, transport, and dilatation. Correlations of these terms will be presented to study the growth and interaction between various terms. A comparison with its RANS (Reynolds-Averaged Navier-Stokes) counterpart will also be presented.

  17. Intercomparison of the seasonal cycle in 200 hPa kinetic energy in AMIP GCM simulations

    SciTech Connect

    Boyle, J.S.

    1996-10-01

    The 200 hPa kinetic energy is represented by means of the spherical harmonic components for the Atmospheric Model Intercomparison Project (AMIP) simulations, the National Center for Environmental Prediction/National Center for Atmospheric Research (NCEP/NCAR) reanalysis and the European Centre for Medium Range Weather Forecast Reanalysis (ERA). The data used are the monthly mean wind fields from 1979 to 1988. The kinetic energy is decomposed into the divergent (DKE) and rotational (RKE) components and emphasis is placed on examining the former. The two reanalysis data sets show reasonable agreement that is best for the rotational kinetic energy. The largest difference in the divergent kinetic energy occurs during the northern summer. As might be expected, the two analyses are closet in regions where there are sufficient observations such that the effect of the model used in the assimilation cycle are minimized. The observed RKE show only a slight seasonal cycle with a maximum occuring during the northern winter. The DKE, on the other hand, has a very pronounced seasonal cycle with maxima at the solsticial seasons and minima during the equinoctial seasons. The model results show a very large spread in the magnitudes of the RKE and DKE although the models all evince a seasonal variation in phase with that observed. The median values of the seasonal cycle of RKE and DKE for the models are usually superior to those of any individual model. Results are also presented for simulation following the AMIP protocol but using updated versions of the original AMIP entries. In most cases these new integrations show better agreement with the observations.

  18. Revisiting the density scaling of the non-interacting kinetic energy.

    PubMed

    Borgoo, Alex; Teale, Andrew M; Tozer, David J

    2014-07-28

    Scaling relations play an important role in the understanding and development of approximate functionals in density functional theory. Recently, a number of these relationships have been redefined in terms of the Kohn-Sham orbitals [Calderín, Phys. Rev. A: At., Mol., Opt. Phys., 2013, 86, 032510]. For density scaling the author proposed a procedure involving a multiplicative scaling of the Kohn-Sham orbitals whilst keeping their occupation numbers fixed. In the present work, the differences between this scaling with fixed occupation numbers and that of previous studies, where the particle number change implied by the scaling was accommodated through the use of the grand canonical ensemble, are examined. We introduce the terms orbital and ensemble density scaling for these approaches, respectively. The natural ambiguity of the density scaling of the non-interacting kinetic energy functional is examined and the ancillary definitions implicit in each approach are highlighted and compared. As a consequence of these differences, Calderín recovered a homogeneity of degree 1 for the non-interacting kinetic energy functional under orbital scaling, contrasting recent work by the present authors [J. Chem. Phys., 2012, 136, 034101] where the functional was found to be inhomogeneous under ensemble density scaling. Furthermore, we show that the orbital scaling result follows directly from the linearity and the single-particle nature of the kinetic energy operator. The inhomogeneity of the non-interacting kinetic energy functional under ensemble density scaling can be quantified by defining an effective homogeneity. This quantity is shown to recover the homogeneity values for important approximate forms that are exact for limiting cases such as the uniform electron gas and one-electron systems. We argue that the ensemble density scaling provides more insight into the development of new functional forms.

  19. Initiation and Modification of Reaction by Energy Addition: Kinetic and Transport Phenomena

    DTIC Science & Technology

    1993-10-01

    MODIFICATION OF REACTION BY ENERGY ADDITION: KINETIC AND TRANSPORT PHENOMENA by Francis E. Fendell and Mau-Song Chou Center for Propulsion Technology...TA - A2 L AUHOWAC - F49620-90-C-0070 Francis E. Fendell and Mau-Song Chou 7. PEMOS101IG ORGANIZATION NAME(S AND...a gaseous mixture is more pertinent for the supersonic-combustor applications of interest to the Air Force (compare Figs. 1 and 2) (Carrier, Fendell

  20. Kinetic energy release distributions for C+2 emission from multiply charged C60 and C70 fullerenes

    NASA Astrophysics Data System (ADS)

    Cederquist, H.; Haag, N.; Berényi, Z.; Reinhed, P.; Fischer, D.; Gudmundsson, M.; Johansson, H. A. B.; Schmidt, H. T.; Zettergren, H.

    2009-04-01

    We present a systematic study of experimental kinetic energy release distributions for the asymmetric fission processes Cq+60 → C(iq-1<)+70+ C+2 and Cq+70 → C(q-1)+60+ C+2 for mother ions in charge states q = 4-8 produced in collisions with slow highly charged ions. Somewhat to our surprise, we find that the KERD for asymmetric fission from Cq+60 are considerably wider and have larger most likely values than the Cq+70 distributions in the corresponding charge states when q > 4.

  1. One method of describing the transfer of energy of the kinetic degrees of freedom to the electronic states of molecules

    NASA Astrophysics Data System (ADS)

    Ivanov, V. N.

    1996-09-01

    An analysis is made of the process of transferring the kinetic energy of highly excited vibrational terms of a molecule to an electronic state of one of its constituent atoms. This is done by utilizing a wave equation for the effective wave functions of the atom, corresponding to mixed states, in which the velocity of this atom relative to the neighboring atoms in the molecule enters as a parameter. An expression is found for the excitation probability in the case of a hydroge-like atom in the resonant approximation.

  2. State-to-State Internal Energy Relaxation Following the Quantum-Kinetic Model in DSMC

    NASA Technical Reports Server (NTRS)

    Liechty, Derek S.

    2014-01-01

    A new model for chemical reactions, the Quantum-Kinetic (Q-K) model of Bird, has recently been introduced that does not depend on macroscopic rate equations or values of local flow field data. Subsequently, the Q-K model has been extended to include reactions involving charged species and electronic energy level transitions. Although this is a phenomenological model, it has been shown to accurately reproduce both equilibrium and non-equilibrium reaction rates. The usefulness of this model becomes clear as local flow conditions either exceed the conditions used to build previous models or when they depart from an equilibrium distribution. Presently, the applicability of the relaxation technique is investigated for the vibrational internal energy mode. The Forced Harmonic Oscillator (FHO) theory for vibrational energy level transitions is combined with the Q-K energy level transition model to accurately reproduce energy level transitions at a reduced computational cost compared to the older FHO models.

  3. Thermodynamic and Kinetic Response of Microbial Reactions to High CO2

    PubMed Central

    Jin, Qusheng; Kirk, Matthew F.

    2016-01-01

    Geological carbon sequestration captures CO2 from industrial sources and stores the CO2 in subsurface reservoirs, a viable strategy for mitigating global climate change. In assessing the environmental impact of the strategy, a key question is how microbial reactions respond to the elevated CO2 concentration. This study uses biogeochemical modeling to explore the influence of CO2 on the thermodynamics and kinetics of common microbial reactions in subsurface environments, including syntrophic oxidation, iron reduction, sulfate reduction, and methanogenesis. The results show that increasing CO2 levels decreases groundwater pH and modulates chemical speciation of weak acids in groundwater, which in turn affect microbial reactions in different ways and to different extents. Specifically, a thermodynamic analysis shows that increasing CO2 partial pressure lowers the energy available from syntrophic oxidation and acetoclastic methanogenesis, but raises the available energy of microbial iron reduction, hydrogenotrophic sulfate reduction and methanogenesis. Kinetic modeling suggests that high CO2 has the potential of inhibiting microbial sulfate reduction while promoting iron reduction. These results are consistent with the observations of previous laboratory and field studies, and highlight the complexity in microbiological responses to elevated CO2 abundance, and the potential power of biogeochemical modeling in evaluating and quantifying these responses. PMID:27909425

  4. Compact, high energy gas laser

    DOEpatents

    Rockwood, Stephen D.; Stapleton, Robert E.; Stratton, Thomas F.

    1976-08-03

    An electrically pumped gas laser amplifier unit having a disc-like configuration in which light propagation is radially outward from the axis rather than along the axis. The input optical energy is distributed over a much smaller area than the output optical energy, i.e., the amplified beam, while still preserving the simplicity of parallel electrodes for pumping the laser medium. The system may thus be driven by a comparatively low optical energy input, while at the same time, owing to the large output area, large energies may be extracted while maintaining the energy per unit area below the threshold of gas breakdown.

  5. Kinetic Energy and Angular Distributions of He and Ar Atoms Evaporating from Liquid Dodecane.

    PubMed

    Patel, Enamul-Hasan; Williams, Mark A; Koehler, Sven P K

    2017-01-12

    We report both kinetic energy and angular distributions for He and Ar atoms evaporating from C12H26. All results were obtained by performing molecular dynamics simulations of liquid C12H26 with around 10-20 noble gas atoms dissolved in the liquid and by subsequently following the trajectories of the noble gas atoms after evaporation from the liquid. Whereas He evaporates with a kinetic energy distribution of (1.05 ± 0.03) × 2RT (corrected for the geometry used in experiments: (1.08 ± 0.03) × 2RT, experimentally obtained value: (1.14 ± 0.01) × 2RT), Ar displays a kinetic energy distribution that better matches a Maxwell-Boltzmann distribution at the temperature of the liquid ((0.99 ± 0.04) × 2RT). This behavior is also reflected in the angular distributions, which are close to a cosine distribution for Ar but slightly narrower, especially for faster atoms, in the case of He. This behavior of He is most likely due to the weak interaction potential between He and the liquid hydrocarbon.

  6. Nucleation of diindenoperylene and pentacene at thermal and hyperthermal incident kinetic energies

    SciTech Connect

    Kish, Edward R.; Desai, Tushar V.; Greer, Douglas R.; Engstrom, James R.; Woll, Arthur R.

    2015-05-15

    The authors have examined the nucleation of diindenoperylene (DIP) on SiO{sub 2} employing primarily atomic force microscopy and focusing on the effect of incident kinetic energy employing both thermal and supersonic sources. For all incident kinetic energies examined (E{sub i} = 0.09–11.3 eV), the nucleation of DIP is homogeneous and the dependence of the maximum island density on the growth rate is described by a power law. A critical nucleus of approximately two molecules is implicated by our data. A re-examination of the nucleation of pentacene on SiO{sub 2} gives the same major result that the maximum island density is determined by the growth rate, and it is independent of the incident kinetic energy. These observations are readily understood by factoring in the size of the critical nucleus in each case, and the island density, which indicates that diffusive transport of molecules to the growing islands dominate the dynamics of growth in the submonolayer regime.

  7. Measuring kinetic energy changes in the mesoscale with low acquisition rates

    SciTech Connect

    Roldán, É.; Martínez, I. A.; Rica, R. A.; Dinis, L.

    2014-06-09

    We report on the measurement of the average kinetic energy changes in isothermal and non-isothermal quasistatic processes in the mesoscale, realized with a Brownian particle trapped with optical tweezers. Our estimation of the kinetic energy change allows to access to the full energetic description of the Brownian particle. Kinetic energy estimates are obtained from measurements of the mean square velocity of the trapped bead sampled at frequencies several orders of magnitude smaller than the momentum relaxation frequency. The velocity is tuned applying a noisy electric field that modulates the amplitude of the fluctuations of the position and velocity of the Brownian particle, whose motion is equivalent to that of a particle in a higher temperature reservoir. Additionally, we show that the dependence of the variance of the time-averaged velocity on the sampling frequency can be used to quantify properties of the electrophoretic mobility of a charged colloid. Our method could be applied to detect temperature gradients in inhomogeneous media and to characterize the complete thermodynamics of biological motors and of artificial micro and nanoscopic heat engines.

  8. Ion-polycyclic aromatic hydrocarbon collisions: kinetic energy releases for specific fragmentation channels

    NASA Astrophysics Data System (ADS)

    Reitsma, G.; Zettergren, H.; Boschman, L.; Bodewits, E.; Hoekstra, R.; Schlathölter, T.

    2013-12-01

    We report on 30 keV He2 + collisions with naphthalene (C10H8) molecules, which leads to very extensive fragmentation. To unravel such complex fragmentation patterns, we designed and constructed an experimental setup, which allows for the determination of the full momentum vector by measuring charged collision products in coincidence in a recoil ion momentum spectrometer type of detection scheme. The determination of fragment kinetic energies is found to be considerably more accurate than for the case of mere coincidence time-of-flight spectrometers. In fission reactions involving two cationic fragments, typically kinetic energy releases of 2-3 eV are observed. The results are interpreted by means of density functional theory calculations of the reverse barriers. It is concluded that naphthalene fragmentation by collisions with keV ions clearly is much more violent than the corresponding photofragmentation with energetic photons. The ion-induced naphthalene fragmentation provides a feedstock of various small hydrocarbonic species of different charge states and kinetic energy, which could influence several molecule formation processes in the cold interstellar medium and facilitates growth of small hydrocarbon species on pre-existing polycyclic aromatic hydrocarbons.

  9. Size Resolved High Temperature Oxidation Kinetics of Nano-Sized Titanium and Zirconium Particles.

    PubMed

    Zong, Yichen; Jacob, Rohit J; Li, Shuiqing; Zachariah, Michael R

    2015-06-18

    While ultrafine metal particles offer the possibility of very high energy density fuels, there is considerable uncertainty in the mechanism by which metal nanoparticles burn, and few studies that have examined the size dependence to their kinetics at the nanoscale. In this work we quantify the size dependence to the burning rate of titanium and zirconium nanoparticles. Nanoparticles in the range of 20-150 nm were produced via pulsed laser ablation, and then in-flight size-selected using differential electrical mobility. The size-selected oxide free metal particles were directly injected into the post flame region of a laminar flame to create a high temperature (1700-2500 K) oxidizing environment. The reaction was monitored using high-speed videography by tracking the emission from individual nanoparticles. We find that sintering occurs prior to significant reaction, and that once sintering is accounted for, the rate of combustion follows a near nearly (diameter)(1) power-law dependence. Additionally, Arrhenius parameters for the combustion of these nanoparticles were evaluated by measuring the burn times at different ambient temperatures. The optical emission from combustion was also used to model the oxidation process, which we find can be reasonably described with a kinetically controlled shrinking core model.

  10. Fission foil detector calibrations with high energy protons

    NASA Technical Reports Server (NTRS)

    Benton, E. V.; Frank, A. L.

    1995-01-01

    Fission foil detectors (FFD's) are passive devices composed of heavy metal foils in contact with muscovite mica films. The heavy metal nuclei have significant cross sections for fission when irradiated with neutrons and protons. Each isotope is characterized by threshold energies for the fission reactions and particular energy-dependent cross sections. In the FFD's, fission fragments produced by the reactions are emitted from the foils and create latent particle tracks in the adjacent mica films. When the films are processed surface tracks are formed which can be optically counted. The track densities are indications of the fluences and spectra of neutrons and/or protons. In the past, detection efficiencies have been calculated using the low energy neutron calibrated dosimeters and published fission cross sections for neutrons and protons. The problem is that the addition of a large kinetic energy to the (n,nucleus) or (p,nucleus) reaction could increase the energies and ranges of emitted fission fragments and increase the detector sensitivity as compared with lower energy neutron calibrations. High energy calibrations are the only method of resolving the uncertainties in detector efficiencies. At high energies, either proton or neutron calibrations are sufficient since the cross section data show that the proton and neutron fission cross sections are approximately equal. High energy proton beams have been utilized (1.8 and 4.9 GeV, 80 and 140 MeV) for measuring the tracks of fission fragments emitted backward and forward.

  11. Fission foil detector calibrations with high energy protons

    SciTech Connect

    Benton, E.V.; Frank, A.L.

    1995-03-01

    Fission foil detectors (FFD`s) are passive devices composed of heavy metal foils in contact with muscovite mica films. The heavy metal nuclei have significant cross sections for fission when irradiated with neutrons and protons. Each isotope is characterized by threshold energies for the fission reactions and particular energy-dependent cross sections. In the FFD`s, fission fragments produced by the reactions are emitted from the foils and create latent particle tracks in the adjacent mica films. When the films are processed surface tracks are formed which can be optically counted. The track densities are indications of the fluences and spectra of neutrons and/or protons. In the past, detection efficiencies have been calculated using the low energy neutron calibrated dosimeters and published fission cross sections for neutrons and protons. The problem is that the addition of a large kinetic energy to the (n,nucleus) or (p,nucleus) reaction could increase the energies and ranges of emitted fission fragments and increase the detector sensitivity as compared with lower energy neutron calibrations. High energy calibrations are the only method of resolving the uncertainties in detector efficiencies. At high energies, either proton or neutron calibrations are sufficient since the cross section data show that the proton and neutron fission cross sections are approximately equal. High energy proton beams have been utilized (1.8 and 4.9 GeV, 80 and 140 MeV) for measuring the tracks of fission fragments emitted backward and forward.

  12. Bidirectional energy cascades and the origin of kinetic Alfvénic and whistler turbulence in the solar wind.

    PubMed

    Che, H; Goldstein, M L; Viñas, A F

    2014-02-14

    The observed steep kinetic scale turbulence spectrum in the solar wind raises the question of how that turbulence originates. Observations of keV energetic electrons during solar quiet time suggest them as a possible source of free energy to drive kinetic turbulence. Using particle-in-cell simulations, we explore how the free energy released by an electron two-stream instability drives Weibel-like electromagnetic waves that excite wave-wave interactions. Consequently, both kinetic Alfvénic and whistler turbulence are excited that evolve through inverse and forward magnetic energy cascades.

  13. Extended Thomas-Fermi kinetic energy density functional with spatially varying effective mass in d=1,2,3 dimensions

    SciTech Connect

    Berkane, K.; Bencheikh, K.

    2005-08-15

    For first-principles density functional theory of a many fermion system, the determination of the kinetic energy functional is important. We consider N independent fermions with spatially varying effective mass in two dimensions, we derive the corresponding kinetic energy density using the ({Dirac_h}/2{pi}) semiclassical approach. Our result reduces, as expected, to the one obtained in the literature for a constant effective mass. We examine the analytical expressions of the position dependent effective mass terms in the kinetic energy density functional with respect to the dimensionality d=1,2,3 of the space.

  14. Ion kinetic energy distributions and cross sections for the electron impact ionization of ethyl tert-butyl ether

    NASA Astrophysics Data System (ADS)

    Di Palma, T. M.; Apicella, B.; Armenante, M.; Velotta, R.; Wang, X.; Spinelli, N.

    2005-11-01

    The kinetic energy distributions and the cross sections of the ions produced in the electron impact of ethyl tert-butyl ether (ETBE) have been studied by time of flight (TOF) mass spectrometry. The kinetic energy distributions have been deduced from the TOF peak shape analysis and a Montecarlo simulation method of the ion trajectories has been used to evaluate the collection efficiency of the spectrometer as a function of the ion initial kinetic energy. The measured ion yields have been corrected for the collection efficiency and the partial and total ionization cross sections of ETBE determined in the range 20-150 eV.

  15. High energy chemical laser system

    DOEpatents

    Gregg, D.W.; Pearson, R.K.

    1975-12-23

    A high energy chemical laser system is described wherein explosive gaseous mixtures of a reducing agent providing hydrogen isotopes and interhalogen compounds are uniformly ignited by means of an electrical discharge, flash- photolysis or an electron beam. The resulting chemical explosion pumps a lasing chemical species, hydrogen fluoride or deuterium fluoride which is formed in the chemical reaction. The generated lasing pulse has light frequencies in the 3- micron range. Suitable interhalogen compounds include bromine trifluoride (BrF$sub 3$), bromine pentafluoride (BrF$sub 5$), chlorine monofluoride (ClF), chlorine trifluoride (ClF$sub 3$), chlorine pentafluoride (ClF$sub 5$), iodine pentafluoride (IF$sub 5$), and iodine heptafluoride (IF$sub 7$); and suitable reducing agents include hydrogen (H$sub 2$), hydrocarbons such as methane (CH$sub 4$), deuterium (D$sub 2$), and diborane (B$sub 2$H$sub 6$), as well as combinations of the gaseous compound and/or molecular mixtures of the reducing agent.

  16. High Energy Plasma Space Propulsion

    NASA Technical Reports Server (NTRS)

    Wu, S. T.

    2000-01-01

    In order to meet NASA's challenge on advanced concept activity in the propulsion area, we initiated a new program entitled "High Energy Plasma Space Propulsion Studies" within the current cooperative agreement in 1998. The goals of this work are to gain further understanding of the engine of the AIMStar spacecraft, a concept which was developed at Penn State University, and to develop a prototype concept for the engine. The AIMStar engine concept was developed at Penn State University several years ago as a hybrid between antimatter and fusion technologies. Because of limited amounts of antimatter available, and concurrently the demonstrated ability for antiprotons to efficiently ignite nuclear fusion reactions, it was felt that this was a very good match. Investigations have been made concerning the performance of the reaction trap. This is a small Penning-like electromagnetic trap, which is used to simultaneously confine antiprotons and fusion fuels. Small DHe3 or DT droplets, containing a few percent molar of a fissile material, are injected into the trap, filled with antiprotons. We have found that it is important to separate the antiprotons into two adjacent wells, to inject he droplet between them and to simultaneously bring the antiprotons to the center of the trap, surrounding the droplet. Our previous concept had the droplet falling onto one cloud of antiprotons. This proved to be inefficient, as the droplet tended to evaporate away from the cloud as it interacted on its surface.

  17. Fundamental kinetics and innovative applications of nonequilibrium atomic vibration in thermal energy transport and conversion

    NASA Astrophysics Data System (ADS)

    Shin, Seungha

    All energy conversion inefficiencies begin with emission of resonant atomic motions, e.g., vibrations, and are declared as waste heat once these motions thermalize to equilibrium. The nonequilibrium energy occupancy of the vibrational modes can be targeted as a harvestable, low entropy energy source for direct conversion to electric energy. Since the lifetime of these resonant vibrations is short, special nanostructures are required with the appropriate tuning of the kinetics. These in turn require multiscale, multiphysics treatments. Atomic vibration is described with quasiparticle phonon in solid, and the optical phonon emission is dominant relaxation channel in semiconductors. These optical modes become over-occupied when their emission rate becomes larger than their decay rate, thus hindering energy relaxation and transport in devices. Effective removal of these phonons by drifting electrons is investigated by manipulating the electron distribution to have higher population in the low-energy states, thus allowing favorable phonon absorption. This is done through introduction, design and analysis of a heterobarrier conducting current, where the band gap is controlled by alloying, thus creating a spatial variation which is abrupt followed by a linear gradient (to ensure directed current). Self-consistent ensemble Monte Carlo simulations based on interaction kinetics between electron and phonon show that up to 19% of the phonon energy is converted to electric potential with an optimized GaAs/AlxGa1-xAs barrier structure over a range of current and electron densities, and this system is also verified through statistical entropy analysis. This direct energy conversion improves the device performance with lower operation temperature and enhances overall energy conversion efficiency. Through this study, the paradigm for harvesting the resonant atomic vibration is proposed, reversing the general role of phonon as only causing electric potential drop. Fundamentals

  18. Chemical bond as a test of density-gradient expansions for kinetic and exchange energies

    SciTech Connect

    Perdew, J.P.; Levy, M.; Painter, G.S.; Wei, S.; Lagowski, J.B.

    1988-01-15

    Errors in kinetic and exchange contributions to the molecular bonding energy are assessed for approximate density functionals by reference to near-exact Hartree-Fock values. From the molecular calculations of Allan et al. and of Lee and Ghosh, it is demonstrated that the density-gradient expansion does not accurately describe the noninteracting kinetic contribution to the bonding energy, even when this expansion is carried to fourth order and applied in its spin-density-functional form to accurate Hartree-Fock densities. In a related study, it is demonstrated that the overbinding of molecules such as N/sub 2/ and F/sub 2/, which occurs in the local-spin-density (LSD) approximation for the exchange-correlation energy, is not attributable to errors in the self-consistent LSD densities. Contrary to expectations based upon the Gunnarsson-Jones nodality argument, it is found that the LSD approximation for the exchange energy can seriously overbind a molecule even when bonding does not create additional nodes in the occupied valence orbitals. LSD and exact values for the exchange contribution to the bonding energy are displayed and discussed for several molecules.

  19. High-energy thermal synchrotron emission

    NASA Technical Reports Server (NTRS)

    Imamura, J. N.; Epstein, R. I.; Petrosian, V.

    1985-01-01

    It is shown how the thermal synchrotron emission spectrum is modified when the photon energy is greater than the mean energy of the radiating particles. The effect if applying this energy conservation constraint is to produce spectra which have less high-energy photon emission than had been previously estimated. The thermal synchrotron spectra provide satisfactory fits to recently observed very high energy gamma ray spectra of certain burst sources.

  20. Convective kinetic energy equation under the mass-flux subgrid-scale parameterization

    NASA Astrophysics Data System (ADS)

    Yano, Jun-Ichi

    2015-03-01

    The present paper originally derives the convective kinetic energy equation under mass-flux subgrid-scale parameterization in a formal manner based on the segmentally-constant approximation (SCA). Though this equation is long since presented by Arakawa and Schubert (1974), a formal derivation is not known in the literature. The derivation of this formulation is of increasing interests in recent years due to the fact that it can explain basic aspects of the convective dynamics such as discharge-recharge and transition from shallow to deep convection. The derivation is presented in two manners: (i) for the case that only the vertical component of the velocity is considered and (ii) the case that both the horizontal and vertical components are considered. The equation reduces to the same form as originally presented by Arakwa and Schubert in both cases, but with the energy dissipation term defined differently. In both cases, nevertheless, the energy "dissipation" (loss) term consists of the three principal contributions: (i) entrainment-detrainment, (ii) outflow from top of convection, and (iii) pressure effects. Additionally, inflow from the bottom of convection contributing to a growth of convection is also formally counted as a part of the dissipation term. The eddy dissipation is also included for a completeness. The order-of-magnitude analysis shows that the convective kinetic energy "dissipation" is dominated by the pressure effects, and it may be approximately described by Rayleigh damping with a constant time scale of the order of 102-103 s. The conclusion is also supported by a supplementary analysis of a cloud-resolving model (CRM) simulation. The Appendix discusses how the loss term ("dissipation") of the convective kinetic energy is qualitatively different from the conventional eddy-dissipation process found in turbulent flows.

  1. Classical trajectory studies of gas phase reaction dynamics and kinetics using ab initio potential energy surfaces

    NASA Technical Reports Server (NTRS)

    Jaffe, Richard L.; Pattengill, Merle D.; Schwenke, David W.

    1989-01-01

    Strategies for constructing global potential energy surfaces from a limited number of accurate ab initio electronic energy calculations are discussed. Generally, these data are concentrated in small regions of configuration space (e.g., in the vicinity of saddle points and energy minima) and difficulties arise in generating a potential function that is globally well-behaved. Efficient computer codes for carrying out classical trajectory calculations on vector and parallel processors are also described. Illustrations are given from recent work on the following chemical systems: Ca + HF yields CaF + H, H + H + H2 yields H2 + H2, N + O2 yields NO + O and O + N2 yields NO + N. The dynamics and kinetics of metathesis, dissociation, recombination, energy transfer and complex formation processes will be discussed.

  2. The ANSTO high energy heavy ion microprobe

    NASA Astrophysics Data System (ADS)

    Siegele, Rainer; Cohen, David D.; Dytlewski, Nick

    1999-10-01

    Recently the construction of the ANSTO High Energy Heavy Ion Microprobe (HIMP) at the 10 MV ANTARES tandem accelerator has been completed. The high energy heavy ion microprobe focuses not only light ions at energies of 2-3 MeV, but is also capable of focusing heavy ions at high energies with ME/ q2 values up to 150 MeV amu and greater. First performance tests and results are reported here.

  3. Enzymatic Kinetic Isotope Effects from Path-Integral Free Energy Perturbation Theory.

    PubMed

    Gao, J

    2016-01-01

    Path-integral free energy perturbation (PI-FEP) theory is presented to directly determine the ratio of quantum mechanical partition functions of different isotopologs in a single simulation. Furthermore, a double averaging strategy is used to carry out the practical simulation, separating the quantum mechanical path integral exactly into two separate calculations, one corresponding to a classical molecular dynamics simulation of the centroid coordinates, and another involving free-particle path-integral sampling over the classical, centroid positions. An integrated centroid path-integral free energy perturbation and umbrella sampling (PI-FEP/UM, or simply, PI-FEP) method along with bisection sampling was summarized, which provides an accurate and fast convergent method for computing kinetic isotope effects for chemical reactions in solution and in enzymes. The PI-FEP method is illustrated by a number of applications, to highlight the computational precision and accuracy, the rule of geometrical mean in kinetic isotope effects, enhanced nuclear quantum effects in enzyme catalysis, and protein dynamics on temperature dependence of kinetic isotope effects.

  4. The dehydration kinetics of gypsum at high pressure and high temperature

    NASA Astrophysics Data System (ADS)

    Liu, Chuanjiang; Zheng, Haifei; Wang, Duojun

    2015-07-01

    An in situ dehydration kinetics study of gypsum under water-saturated condition was performed in the temperature and pressure ranges of 383-423 K and 343-1085 MPa by using a hydrothermal diamond anvil cell and Raman spectroscopy. Kinetic analysis shows that the dehydration rate k increases with pressure, suggesting a negative pressure dependence on dehydration rate. The elevation of temperature can contribute to the dehydration. The n values increase with pressure, indicating that the nucleation process becomes slower relative to the growth process. According to the n values of ∼1.0, the dehydration of gypsum is dominated by an instantaneous nucleation and diffusion-controlled growth mechanism. The obtained average activation volume ▵V is equal to 5.69 cm3/mol and the calculated activation energy Ea and the pre-exponential factor A are 66.9 kJ/mol and 4.66 × 105 s-1. The activation energy may be dependent upon grain size, shape, temperature and pressure, and surrounding water.

  5. Dynamics of heavy flavor quarks in high energy nuclear collisions

    NASA Astrophysics Data System (ADS)

    Beraudo, Andrea

    2014-11-01

    A general overview on the role of heavy quarks as probes of the medium formed in high energy nuclear collisions is presented. Experimental data compared to model calculations at low and moderate pT are exploited to extract information on the transport coefficients of the medium, on possible modifications of heavy flavor hadronization in a hot environment and to provide quantitative answers to the issue of kinetic (and chemical, at conceivable future experimental facilities) thermalization of charm. Finally, the role of heavy flavor at high pT as a tool to study the mass and color-charge dependence the jet quenching is also analyzed.

  6. Statistical rate theory and kinetic energy-resolved ion chemistry: theory and applications.

    PubMed

    Armentrout, P B; Ervin, Kent M; Rodgers, M T

    2008-10-16

    Ion chemistry, first discovered 100 years ago, has profitably been coupled with statistical rate theories, developed about 80 years ago and refined since. In this overview, the application of statistical rate theory to the analysis of kinetic-energy-dependent collision-induced dissociation (CID) reactions is reviewed. This procedure accounts for and quantifies the kinetic shifts that are observed as systems increase in size. The statistical approach developed allows straightforward extension to systems undergoing competitive or sequential dissociations. Such methods can also be applied to the reverse of the CID process, association reactions, as well as to quantitative analysis of ligand exchange processes. Examples of each of these types of reactions are provided and the literature surveyed for successful applications of this statistical approach to provide quantitative thermochemical information. Such applications include metal-ligand complexes, metal clusters, proton-bound complexes, organic intermediates, biological systems, saturated organometallic complexes, and hydrated and solvated species.

  7. Kinetic Energy Recovery from the Chimney Flue Gases Using Ducted Turbine System

    NASA Astrophysics Data System (ADS)

    Mann, Harjeet S.; Singh, Pradeep K.

    2017-03-01

    An innovative idea of extracting kinetic energy from man-made wind resources using ducted turbine system for on-site power generation is introduced in this paper. A horizontal axis ducted turbine is attached to the top of the chimney to harness the kinetic energy of flue gases for producing electricity. The turbine system is positioned beyond the chimney outlet, to avoid any negative impact on the chimney performance. The convergent-divergent duct causes increase in the flue gas velocity and hence enhances the performance of the turbine. It also acts as a safety cover to the energy recovery system. The results from the CFD based simulation analysis indicate that significant power 34 kW can be harnessed from the chimney exhaust. The effect of airfoils NACA4412 and NACA4416 and the diffuser angle on the power extraction by the energy recovery system using a 6-bladed ducted turbine has been studied with the CFD simulation. It is observed that the average flue gas velocity in the duct section at the throat is approximately twice that of the inlet velocity, whereas maximum velocity achieved is 2.6 times the inlet velocity. The simulated results show that about power may be extracted from the chimney flue gases of 660 MW power plant. The system can be retrofitted to existing chimneys of thermal power plants, refineries and other industries.

  8. Kinetic study of solid waste pyrolysis using distributed activation energy model.

    PubMed

    Bhavanam, Anjireddy; Sastry, R C

    2015-02-01

    The pyrolysis characteristics of municipal solid waste, agricultural residues such as ground nut shell, cotton husk and their blends are investigated using non-isothermal thermogravimetric analysis (TGA) with in a temperature range of 30-900 °C at different heating rates of 10 °C, 30 °C and 50 °C/min in inert atmosphere. From the thermograms obtained from TGA, it is observed that the maximum rate of degradation occurred in the second stage of the pyrolysis process for all the solid wastes. The distributed activation energy model (DAEM) is used to study the pyrolysis kinetics of the solid wastes. The kinetic parameters E (activation energy), k0 (frequency factor) are calculated from this model. It is found that the range of activation energies for agricultural residues are lower than the municipal solid waste. The activation energies for the municipal solid waste pyrolysis process drastically decreased with addition of agricultural residues. The proposed DAEM is successfully validated with TGA experimental data.

  9. Turbulence power and kinetic energy spectra measured by a temporal-to-spatial record conversion

    NASA Astrophysics Data System (ADS)

    Buchhave, Preben; Velte, Clara

    2015-11-01

    A method of converting a time record of turbulent velocity measured at a point in a flow to a spatial velocity record consisting of consecutive streak line elements that allows computation of turbulent kinetic wavenumber spectra is briefly introduced (more detail in a related paper at this conference, see ref). The method completely bypasses the problems with Taylor's hypothesis caused by fluctuating convection velocities. In the present contribution, we discuss the interpretation of the first order static moments (e.g. mean and rms velocity) and second order dynamic moments (e.g. spatial correlation function and energy spectrum) computed from the spatial record, which was derived from the measured temporal record. We compare several possible versions of the new energy spectra with the classical 1D and 3D energy spectra and the so-called total kinetic energy spectrum and discuss the range of validity of any equivalence between the new computations and the classical ones. Ref.: Clara M. Velte: A novel time-to-space conversion methods bypassing the problems with Taylor's hypothesis caused by fluctuating convection velocities

  10. A simplified model for average kinetic energy flux within large wind turbine arrays

    NASA Astrophysics Data System (ADS)

    Markfort, Corey; Zhang, Wei; Porte-Agel, Fernando

    2015-11-01

    We investigate the kinetic energy distribution within an array of wind turbines using a 1-D model for the interactions between large-scale wind farms and the atmospheric boundary layer (ABL). Obstructed shear flow scaling is used to predict the development length of the wind farm flow as well as vertical momentum flux. Within the region of flow development, momentum and energy is advected into the wind farm and wake turbulence draws excess momentum in from between turbines. This is characterized by large dispersive fluxes. Once the flow within the farm is developed, the area - averaged velocity profile exhibits an inflection point, characteristic of obstructed shear flows. The inflected velocity profile is responsible for a characteristic turbulence eddy scale, which may be responsible for a significant amount of the vertical momentum and energy flux. Prediction of this scale is useful for determining the amount of available power for harvesting. The model result for kinetic energy flux is compared to wind tunnel measurements. The model is useful for optimizing wind turbine spacing and layout, and for assessing the impacts of wind farms on nearby wind resources and the environment.

  11. States of high energy density

    SciTech Connect

    Murray, M.

    1988-02-01

    The transverse energy, E/sub tau/ spectra for O/sup 16/ and S/sup 32/ incident for various elements at 200 GeVnucleon are shown. The target and projectile dependencies of the data are discussed. The energy density achieved is estimated. For O/sup 16/ on Tungsten the multiplicity spectrum is also presented as well as the pseudorapidity spectra as a function of the transverse energy. The multiplicity cross section dsigmadN as measured in the backward hemisphere (0.9 < /eta/ < 2.9/ is found to be very similar in shape to the transverse energy distribution dsigmadE/tau/ reflecting the particular geometry of nucleus nucleus nucleus collisions. The dependence on the atomic mass of the target, A/sub tau/ and projectile A/sub p/ is not what one would expect from naive considerations.

  12. Kinetic Modeling of Slow Energy Release in Non-Ideal Carbon Rich Explosives

    SciTech Connect

    Vitello, P; Fried, L; Glaesemann, K; Souers, C

    2006-06-20

    We present here the first self-consistent kinetic based model for long time-scale energy release in detonation waves in the non-ideal explosive LX-17. Non-ideal, insensitive carbon rich explosives, such as those based on TATB, are believed to have significant late-time slow release in energy. One proposed source of this energy is diffusion-limited growth of carbon clusters. In this paper we consider the late-time energy release problem in detonation waves using the thermochemical code CHEETAH linked to a multidimensional ALE hydrodynamics model. The linked CHEETAH-ALE model dimensional treats slowly reacting chemical species using kinetic rate laws, with chemical equilibrium assumed for species coupled via fast time-scale reactions. In the model presented here we include separate rate equations for the transformation of the un-reacted explosive to product gases and for the growth of a small particulate form of condensed graphite to a large particulate form. The small particulate graphite is assumed to be in chemical equilibrium with the gaseous species allowing for coupling between the instantaneous thermodynamic state and the production of graphite clusters. For the explosive burn rate a pressure dependent rate law was used. Low pressure freezing of the gas species mass fractions was also included to account for regions where the kinetic coupling rates become longer than the hydrodynamic time-scales. The model rate parameters were calibrated using cylinder and rate-stick experimental data. Excellent long time agreement and size effect results were achieved.

  13. High-Energy Astrophysics: An Overview

    NASA Technical Reports Server (NTRS)

    Fishman, Gerald J.

    2007-01-01

    High-energy astrophysics is the study of objects and phenomena in space with energy densities much greater than that found in normal stars and galaxies. These include black holes, neutron stars, cosmic rays, hypernovae and gamma-ray bursts. A history and an overview of high-energy astrophysics will be presented, including a description of the objects that are observed. Observing techniques, space-borne missions in high-energy astrophysics and some recent discoveries will also be described. Several entirely new types of astronomy are being employed in high-energy astrophysics. These will be briefly described, along with some NASA missions currently under development.

  14. Static and kinetic friction of granite at high normal stress

    USGS Publications Warehouse

    Byerlee, J.D.

    1970-01-01

    Frictional sliding on ground surfaces of granite, angle of sliding planes 30?? and 45??, was investigated as a function of confining pressure. Over the normal stress range of 2-12 kb, the static frictional shear stress ??s follows the relationship ??s = 0??5 + 0?? ??n and the kinetic frictional shear stress ??k was calculated to be ??k = 0??25 + 0??47 ??n. ?? 1970.

  15. Total kinetic energy release in 239Pu(n ,f ) post-neutron emission from 0.5 to 50 MeV incident neutron energy

    NASA Astrophysics Data System (ADS)

    Meierbachtol, K.; Tovesson, F.; Duke, D. L.; Geppert-Kleinrath, V.; Manning, B.; Meharchand, R.; Mosby, S.; Shields, D.

    2016-09-01

    The average total kinetic energy (T K E ¯) in 239Pu(n ,f ) has been measured for incident neutron energies between 0.5 and 50 MeV. The experiment was performed at the Los Alamos Neutron Science Center (LANSCE) using the neutron time-of-flight technique, and the kinetic energy of fission fragments post-neutron emission was measured in a double Frisch-gridded ionization chamber. This represents the first experimental study of the energy dependence of T K E ¯ in 239Pu above neutron energies of 6 MeV.

  16. When and How Does A Prominence-like Jet Gain Kinetic Energy?

    NASA Astrophysics Data System (ADS)

    Liu, J.; Wang, Y.; Zhang, Q.; Liu, K.; Shen, C.

    2013-12-01

    Usually a jet is triggered by a brightening or flare, which provides the first driving force. In this process, magnetic reconnection is thought to be the mechanism to convert magnetic energy into jet's kinetic energy. However, most jets could reach an unusual height and end far after the end of its associated flare. This fact implies another way continuously transferring magnetic energy into kinetic energy after the reconnection. This picture is well known, but how and how much magnetic energy is released through the way other than the reconnection is still unclear. Here, through studying a prominence-like jet observed by AIA and EUVI, we reveal the continuously relaxation of post-reconnection magnetic field structure is an important process to support a jet. The kinetic energy of the jet gained through this way is 1.6 times of that from the reconnection. The resultant energy flux is hundreds of the required for local coronal heating, suggesting such jets are a possible source to keep corona hot. Rotational motion appearing all the time during the jet implies the torsional Alfven wave induced during reconnection is not the only mechanism to release magnetic energy and drive jets. Left column: Difference images taken by SDO/AIA at 304A passband. The FOV of the images is 430"x430". Right column: Difference images from STEREO-A/EUVI at the same passband. The FOV is 450"x450". Since STEREO-A was 120 degree apart away from SDO on 2012 July 8, the SDO limb event right happened ondisk in the view of STEREO-A. Black and red solid curve: integrated intensity over the cross-section of the jet at different height at 19:11 UT and 19:47 UT, respectively. The two horizontal dashed lines are their average values. Black and red dashed curve with asterisks: axial speed with errors of the eight sub-jets shown in Figure 3 at 19:11 UT and 19:47 UT , respectively. Blue dashed curve with diamonds: angular speed with errors of the jet at different height.

  17. Kinetic-energy density functionals with nonlocal terms with the structure of the Thomas-Fermi functional

    SciTech Connect

    Garcia-Aldea, David; Alvarellos, J. E.

    2007-11-15

    We study two families of approximate nonlocal kinetic-energy functionals that include a full von Weizsaecker functional, and that have nonlocal terms with the mathematical structure of the Thomas-Fermi functional. The functionals recover the exact kinetic energy and the linear response function of a homogeneous electron system. The first family is a generalization of a successful previous nonlocal functional. The second family is proposed in the paper, and is designed to obtain functionals suitable for use in both localized and extended systems. Furthermore, this family has been designed to be evaluated by a single integration in momentum space when a constant reference density is used. The atomic total kinetic energies are in good agreement with the exact calculations. The kinetic-energy density corresponding to each functional has been assessed to control its quality. The results show that, in general, these functionals behave better than both the Thomas-Fermi and all semilocal generalized gradient approximation functionals when describing the kinetic-energy density of atoms, providing a better description of the nonlocal effects of the kinetic energy of electron systems.

  18. Testing the nonlocal kinetic energy functional of an inhomogeneous, two-dimensional degenerate Fermi gas within the average density approximation

    NASA Astrophysics Data System (ADS)

    Towers, J.; van Zyl, B. P.; Kirkby, W.

    2015-08-01

    In a recent paper [B. P. van Zyl et al., Phys. Rev. A 89, 022503 (2014), 10.1103/PhysRevA.89.022503], the average density approximation (ADA) was implemented to develop a parameter-free, nonlocal kinetic energy functional to be used in the orbital-free density functional theory of an inhomogeneous, two-dimensional (2D) Fermi gas. In this work, we provide a detailed comparison of self-consistent calculations within the ADA with the exact results of the Kohn-Sham density functional theory and the elementary Thomas-Fermi (TF) approximation. We demonstrate that the ADA for the 2D kinetic energy functional works very well under a wide variety of confinement potentials, even for relatively small particle numbers. Remarkably, the TF approximation for the kinetic energy functional, without any gradient corrections, also yields good agreement with the exact kinetic energy for all confining potentials considered, although at the expense of the spatial and kinetic energy densities exhibiting poor pointwise agreement, particularly near the TF radius. Our findings illustrate that the ADA kinetic energy functional yields accurate results for both the local and global equilibrium properties of an inhomogeneous 2D Fermi gas, without the need for any fitting parameters.

  19. Sensory Agreement Guides Kinetic Energy Optimization of Arm Movements during Object Manipulation.

    PubMed

    Farshchiansadegh, Ali; Melendez-Calderon, Alejandro; Ranganathan, Rajiv; Murphey, Todd D; Mussa-Ivaldi, Ferdinando A

    2016-04-01

    The laws of physics establish the energetic efficiency of our movements. In some cases, like locomotion, the mechanics of the body dominate in determining the energetically optimal course of action. In other tasks, such as manipulation, energetic costs depend critically upon the variable properties of objects in the environment. Can the brain identify and follow energy-optimal motions when these motions require moving along unfamiliar trajectories? What feedback information is required for such optimal behavior to occur? To answer these questions, we asked participants to move their dominant hand between different positions while holding a virtual mechanical system with complex dynamics (a planar double pendulum). In this task, trajectories of minimum kinetic energy were along curvilinear paths. Our findings demonstrate that participants were capable of finding the energy-optimal paths, but only when provided with veridical visual and haptic information pertaining to the object, lacking which the trajectories were executed along rectilinear paths.

  20. The analysis and kinetic energy balance of an upper-level wind maximum during intense convection

    NASA Technical Reports Server (NTRS)

    Fuelberg, H. E.; Jedlovec, G. J.

    1982-01-01

    The purpose of this paper is to analyze the formation and maintenance of the upper-level wind maximum which formed between 1800 and 2100 GMT, April 10, 1979, during the AVE-SESAME I period, when intense storms and tornadoes were experienced (the Red River Valley tornado outbreak). Radiosonde stations participating in AVE-SESAME I are plotted (centered on Oklahoma). National Meteorological Center radar summaries near the times of maximum convective activity are mapped, and height and isotach plots are given, where the formation of an upper-level wind maximum over Oklahoma is the most significant feature at 300 mb. The energy balance of the storm region is seen to change dramatically as the wind maximum forms. During much of its lifetime, the upper-level wind maximum is maintained by ageostrophic flow that produces cross-contour generation of kinetic energy and by the upward transport of midtropospheric energy. Two possible mechanisms for the ageostrophic flow are considered.

  1. Potential to kinetic energy conversion in wave number domain for the Southern Hemisphere

    NASA Technical Reports Server (NTRS)

    Huang, H.-J.; Vincent, D. G.

    1984-01-01

    Preliminary results of a wave number study conducted for the South Pacific Convergence Zone (SPCZ) using FGGE data for the period January 10-27, 1979 are reported. In particular, three variables (geomagnetic height, z, vertical p-velocity, omega, and temperature, T) and one energy conversion quantity, omega-alpha (where alpha is the specific volume), are shown. It is demonstrated that wave number 4 plays an important role in the conversion from available potential energy to kinetic energy in the Southern Hemisphere tropics, particularly in the vicinity of the SPCZ. It is therefore suggested that the development and movement of wave number 4 waves be carefully monitored in making forecasts for the South Pacific region.

  2. Surfing the High Energy Output Branch of Nonlinear Energy Harvesters.

    PubMed

    Mallick, D; Amann, A; Roy, S

    2016-11-04

    Hysteresis and multistability are fundamental phenomena of driven nonlinear oscillators, which, however, restrict many applications such as mechanical energy harvesting. We introduce an electrical control mechanism to switch from the low to the high energy output branch of a nonlinear energy harvester by exploiting the strong interplay between its electrical and mechanical degrees of freedom. This method improves the energy conversion efficiency over a wide bandwidth in a frequency-amplitude-varying environment using only a small energy budget. The underlying effect is independent of the device scale and the transduction method and is explained using a modified Duffing oscillator model.

  3. Surfing the High Energy Output Branch of Nonlinear Energy Harvesters

    NASA Astrophysics Data System (ADS)

    Mallick, D.; Amann, A.; Roy, S.

    2016-11-01

    Hysteresis and multistability are fundamental phenomena of driven nonlinear oscillators, which, however, restrict many applications such as mechanical energy harvesting. We introduce an electrical control mechanism to switch from the low to the high energy output branch of a nonlinear energy harvester by exploiting the strong interplay between its electrical and mechanical degrees of freedom. This method improves the energy conversion efficiency over a wide bandwidth in a frequency-amplitude-varying environment using only a small energy budget. The underlying effect is independent of the device scale and the transduction method and is explained using a modified Duffing oscillator model.

  4. Computing kinetic isotope effects for chorismate mutase with high accuracy. A new DFT/MM strategy.

    PubMed

    Martí, Sergio; Moliner, Vicent; Tuñón, Iñaki; Williams, Ian H

    2005-03-10

    A novel procedure has been applied to compute experimentally unobserved intrinsic kinetic isotope effects upon the rearrangement of chorismate to prephenate catalyzed by B. subtilis chorismate mutase. In this modified QM/MM approach, the "low-level" QM description of the quantum region is corrected during the optimization procedure by means of a "high-level" calculation in vacuo, keeping the QM-MM interaction contribution at a quantum "low-level". This allows computation of energies, gradients, and Hessians including the polarization of the QM subsystem and its interaction with the MM environment, both terms calculated using the low-level method at a reasonable computational cost. New information on an important enzymatic transformation is provided with greater reliability than has previously been possible. The predicted kinetic isotope effects on Vmax/Km are 1.33 and 0.86 (at 30 degrees C) for 5-3H and 9-3H2 substitutions, respectively, and 1.011 and 1.055 (at 22 degrees C) for 1-13C and 7-18O substitutions, respectively.

  5. High energy resolution plastic scintillator

    NASA Astrophysics Data System (ADS)

    van Loef, Edgar V.; Feng, Patrick; Markosyan, Gary; Shirwadkar, Urmila; Doty, Patrick; Shah, Kanai S.

    2016-09-01

    In this paper we present results on a novel tin-loaded plastic scintillator. We will show that this particular plastic scintillator has a light output similar to that of BGO, a fast scintillation decay (< 10 ns), exhibits good neutron/gamma PSD with a Figure-of-Merit of 1.3 at 2.5 MeVee cut-off energy, and excellent energy resolution of about 12% (FWHM) at 662 keV. Under X-ray excitation, the radioluminescence spectrum exhibits a broad band between 350 and 500 nm peaking at 420 nm which is well-matched to bialkali photomultiplier tubes and UV-enhanced photodiodes.

  6. Moderate to high throughput in vitro binding kinetics for drug discovery.

    PubMed

    Zhang, Rumin; Barbieri, Christopher M; Garcia-Calvo, Margarita; Myers, Robert W; McLaren, David; Kavana, Michael

    2016-06-01

    This review provides a concise summary for state of the art, moderate to high throughput in vitro technologies being employed to study drug-target binding kinetics. These technologies cover a wide kinetic timescale spanning up to nine orders of magnitude from milliseconds to days. Automated stopped flow measures transient and (pre)steady state kinetics from milliseconds to seconds. For seconds to hours timescale kinetics we discuss surface plasmon resonance-based biosensor, global progress curve analysis for high throughput kinetic profiling of enzyme inhibitors and activators, and filtration plate-based radioligand or fluorescent binding assays for receptor binding kinetics. Jump dilution after pre-incubation is the preferred method for very slow kinetics lasting for days. The basic principles, best practices and simulated data for these technologies are described. Finally, the application of a universal label-free technology, liquid chromatography coupled tandem mass spectrometry (LC/MS/MS), is briefly reviewed. Select literature references are highlighted for in-depth understanding. A new reality is dawning wherein binding kinetics is an integral and routine part of mechanism of action elucidation and translational, quantitative pharmacology for drug discovery.

  7. Electromagnetic energy conversion in downstream fronts from three dimensional kinetic reconnection

    SciTech Connect

    Lapenta, Giovanni; Goldman, Martin; Newman, David; Markidis, Stefano; Divin, Andrey

    2014-05-15

    The electromagnetic energy equation is analyzed term by term in a 3D simulation of kinetic reconnection previously reported by Vapirev et al. [J. Geophys. Res.: Space Phys. 118, 1435 (2013)]. The evolution presents the usual 2D-like topological structures caused by an initial perturbation independent of the third dimension. However, downstream of the reconnection site, where the jetting plasma encounters the yet unperturbed pre-existing plasma, a downstream front is formed and made unstable by the strong density gradient and the unfavorable local acceleration field. The energy exchange between plasma and fields is most intense at the instability, reaching several pW/m{sup 3}, alternating between load (energy going from fields to particles) and generator (energy going from particles to fields) regions. Energy exchange is instead purely that of a load at the reconnection site itself in a region focused around the x-line and elongated along the separatrix surfaces. Poynting fluxes are generated at all energy exchange regions and travel away from the reconnection site transporting an energy signal of the order of about S≈10{sup −3}W/m{sup 2}.

  8. High energy hadrons in extensive air showers

    NASA Technical Reports Server (NTRS)

    Tonwar, S. C.

    1985-01-01

    Experimental data on the high energy hadronic component in extensive air showers of energies approx. 10 to the 14 to 10 to the 16 eV when compared with expectations from Monte Carlo simulations have shown the observed showers to be deficient in high energy hadrons relative to simulated showers. An attempt is made to understand these anomalous features with more accurate comparison of observations with expectations, taking into account the details of the experimental system. Results obtained from this analysis and their implications for the high energy physics of particle interactions at energy approx. 10 to the 15 eV are presented.

  9. Evaluation of Monte Carlo tools for high energy atmospheric physics

    NASA Astrophysics Data System (ADS)

    Rutjes, Casper; Sarria, David; Broberg Skeltved, Alexander; Luque, Alejandro; Diniz, Gabriel; Østgaard, Nikolai; Ebert, Ute

    2016-11-01

    The emerging field of high energy atmospheric physics (HEAP) includes terrestrial gamma-ray flashes, electron-positron beams and gamma-ray glows from thunderstorms. Similar emissions of high energy particles occur in pulsed high voltage discharges. Understanding these phenomena requires appropriate models for the interaction of electrons, positrons and photons of up to 40 MeV energy with atmospheric air. In this paper, we benchmark the performance of the Monte Carlo codes Geant4, EGS5 and FLUKA developed in other fields of physics and of the custom-made codes GRRR and MC-PEPTITA against each other within the parameter regime relevant for high energy atmospheric physics. We focus on basic tests, namely on the evolution of monoenergetic and directed beams of electrons, positrons and photons with kinetic energies between 100 keV and 40 MeV through homogeneous air in the absence of electric and magnetic fields, using a low energy cutoff of 50 keV. We discuss important differences between the results of the different codes and provide plausible explanations. We also test the computational performance of the codes. The Supplement contains all results, providing a first benchmark for present and future custom-made codes that are more flexible in including electrodynamic interactions.

  10. Asymptotic domination of cold relativistic MHD winds by kinetic energy flux

    NASA Technical Reports Server (NTRS)

    Begelman, Mitchell C.; Li, Zhi-Yun

    1994-01-01

    We study the conditions which lead to the conversion of most Poynting flux into kinetic energy flux in cold, relativistic hydromagnetic winds. It is shown that plasma acceleration along a precisely radial flow is extremely inefficient due to the near cancellation of the toroidal magnetic pressure and tension forces. However, if the flux tubes in a flow diverge even slightly faster than radially, the fast magnetosonic point moves inward from infinity to a few times the light cylinder radius. Once the flow becomes supermagnetosonic, further divergence of the flux tubes beyond the fast point can accelerate the flow via the 'magnetic nozzle' effect, thereby further converting Poynting flux to kinetic energy flux. We show that the Grad-Shafranov equation admits a generic family of kinetic energy-dominated asymptotic wind solutions with finite total magnetic flux. The Poynting flux in these solutions vanishes logarithmically with distance. The way in which the flux surfaces are nested within the flow depends only on the ratio of angular velocity to poliodal 4-velocity as a function of magnetic flux. Radial variations in flow structure can be expressed in terms of a pressure boundary condition on the outermost flux surface, provided that no external toriodal field surrounds the flow. For a special case, we show explicitly how the flux surfaces merge gradually to their asymptotes. For flows confined by an external medium of pressure decreasing to zero at infinity we show that, depending on how fast the ambient pressure declines, the final flow state could be either a collimated jet or a wind that fills the entire space. We discuss the astrophysical implications of our results for jets from active galactic nuclei and for free pulsar winds such as that believed to power the Crab Nebula.

  11. Numerical investigation of kinetic energy dynamics during autoignition of n-heptane/air mixture

    NASA Astrophysics Data System (ADS)

    Lucena Kreppel Paes, Paulo; Brasseur, James; Xuan, Yuan

    2015-11-01

    Many engineering applications involve complex turbulent reacting flows, where nonlinear, multi-scale turbulence-combustion couplings are important. Direct representation of turbulent reacting flow dynamics is associated with prohibitive computational costs, which makes it necessary to employ turbulent combustion models to account for the effects of unresolved scales on resolved scales. Classical turbulence models are extensively employed in reacting flow simulations. However, they rely on assumptions about the energy cascade, which are valid for incompressible, isothermal homogeneous isotropic turbulence. A better understanding of the turbulence-combustion interactions is required for the development of more accurate, physics-based sub-grid-scale models for turbulent reacting flows. In order to investigate the effects of reaction-induced density, viscosity, and pressure variations on the turbulent kinetic energy, Direct Numerical Simulation (DNS) of autoignition of partially-premixed, lean n-heptane/air mixture in three-dimensional homogeneous isotropic turbulence has been performed. This configuration represents standard operating conditions of Homogeneous-Charge Compression-Ignition (HCCI) engines. The differences in the turbulent kinetic energy balance between the present turbulent reacting flow and incompressible, isothermal homogeneous isotropic turbulence are highlighted at different stages during the autoignition process.

  12. High temperature transformations of waste printed circuit boards from computer monitor and CPU: Characterisation of residues and kinetic studies.

    PubMed

    Rajagopal, Raghu Raman; Rajarao, Ravindra; Sahajwalla, Veena

    2016-11-01

    This paper investigates the high temperature transformation, specifically the kinetic behaviour of the waste printed circuit board (WPCB) derived from computer monitor (single-sided/SSWPCB) and computer processing boards - CPU (multi-layered/MLWPCB) using Thermo-Gravimetric Analyser (TGA) and Vertical Thermo-Gravimetric Analyser (VTGA) techniques under nitrogen atmosphere. Furthermore, the resulting WPCB residues were subjected to characterisation using X-ray Fluorescence spectrometry (XRF), Carbon Analyser, X-ray Photoelectron Spectrometer (XPS) and Scanning Electron Microscopy (SEM). In order to analyse the material degradation of WPCB, TGA from 40°C to 700°C at the rates of 10°C, 20°C and 30°C and VTGA at 700°C, 900°C and 1100°C were performed respectively. The data obtained was analysed on the basis of first order reaction kinetics. Through experiments it is observed that there exists a substantial difference between SSWPCB and MLWPCB in their decomposition levels, kinetic behaviour and structural properties. The calculated activation energy (EA) of SSWPCB is found to be lower than that of MLWPCB. Elemental analysis of SSWPCB determines to have high carbon content in contrast to MLWPCB and differences in materials properties have significant influence on kinetics, which is ceramic rich, proving to have differences in the physicochemical properties. These high temperature transformation studies and associated analytical investigations provide fundamental understanding of different WPCB and its major variations.

  13. Vibrational Energy Levels via Finite-Basis Calculations Using a Quasi-Analytic Form of the Kinetic Energy.

    PubMed

    Vázquez, Juana; Harding, Michael E; Stanton, John F; Gauss, Jürgen

    2011-05-10

    A variational method for the calculation of low-lying vibrational energy levels of molecules with small amplitude vibrations is presented. The approach is based on the Watson Hamiltonian in rectilinear normal coordinates and characterized by a quasi-analytic integration over the kinetic energy operator (KEO). The KEO beyond the harmonic approximation is represented by a Taylor series in terms of the rectilinear normal coordinates around the equilibrium configuration. This formulation of the KEO enables its extension to arbitrary order until numerical convergence is reached for those states describing small amplitude motions and suitably represented with a rectilinear system of coordinates. A Gauss-Hermite quadrature grid representation of the anharmonic potential is used for all the benchmark examples presented. Results for a set of molecules with linear and nonlinear configurations, i.e., CO2, H2O, and formyl fluoride (HFCO), illustrate the performance of the method and the versatility of our implementation.

  14. Nonlinear Cascades of Surface Oceanic Geostrophic Kinetic Energy in the Frequency Domain

    DTIC Science & Technology

    2012-09-01

    spectral transfers T(v) 5 2 › ›v P(v) of kinetic energy in frequency v space, as diagnostics of the impact of nonlinearity on the frequency spectra of...surface ocean geostrophic flows. Our analysis of non- linearities in the frequency domain is somewhat similar to the diagnostics employed by Sheng and...transfers T(v) could be useful diagnostics of the role of non- linearity in maintaining low-frequency variability in the climate system. In ocean models, T

  15. Method and turbine for extracting kinetic energy from a stream of two-phase fluid

    NASA Technical Reports Server (NTRS)

    Elliott, D. G. (Inventor)

    1979-01-01

    An axial flow separator turbine is described which includes a number of nozzles for delivering streams of a two-phase fluid along linear paths. A phase separator which responsively separates the vapor and liquid is characterized by concentrically related annuli supported for rotation within the paths. The separator has endless channels for confining the liquid under the influence of centrifugal forces. A vapor turbine fan extracts kinetic energy from the liquid. Angular momentum of both the liquid phase and the vapor phase of the fluid is converted to torque.

  16. Surface-catalyzed recombination into excited electronic, vibrational, rotational, and kinetic energy states: A review

    NASA Technical Reports Server (NTRS)

    Kofsky, I. L.; Barrett, J. L.

    1985-01-01

    Laboratory experiments in which recombined CO, CO2, D2O, OH, N2, H2, and O2 molecules desorb from surfaces in excited internal and translational states are briefly reviewed. Unequilibrated distributions predominate from the principally catalytic metal substrates so far investigated. Mean kinetic energies have been observed up to approx. 3x, and in some cases less than, wall-thermal; the velocity distributions generally vary with emission angle, with non-Lambertian particle fluxes. The excitation state populations are found to depend on surface impurities, in an as yet unexplained way.

  17. Estimates of turbulent kinetic energy dissipation rate for a stratified flow in a wind tunnel

    NASA Astrophysics Data System (ADS)

    Puhales, Franciano Scremin; Demarco, Giuliano; Martins, Luis Gustavo Nogueira; Acevedo, Otávio Costa; Degrazia, Gervásio Annes; Welter, Guilherme Sausen; Costa, Felipe Denardin; Fisch, Gilberto Fernando; Avelar, Ana Cristina

    2015-08-01

    In this work a method to estimate turbulent kinetic energy dissipation rate (TKEDR) was presented. The technique uses the second-order structure function and Kolmogorov's law for inertial subrange. This methodology was applied on both neutral and stable stratification wind tunnel data, where the frozen turbulence hypothesis was assumed. The experiments were made with Reynolds Number ranging from 103 up to 104. The results show difference between the neutral and stable cases, but this gap decreases with the mean wind speed. Furthermore, TKEDR evaluated was used to describe the inertial subrange in the longitudinal velocity spectrum with a good agreement with the experimental data.

  18. Spectroscopy and Kinetics of Combustion Gases at High Temperatures

    SciTech Connect

    Hanson, Ronald; Bowman, Craig

    2016-02-01

    This report describes our research program that involves two complementary activities: (1) development and application of cw laser absorption methods for the measurement of concentration time-histories and fundamental spectroscopic parameters for species of interest in combustion; and (2) shock tube studies of reaction kinetics relevant to combustion. This first part of this report covers research during the final three-year support period, i.e. March 2012 – November 2015. The later part of this report summarizes research conducted over multiple-year periods between March 1988 to March 2012. Publications supported by DOE for each period are summarized at the end of that report section.

  19. Graph-based analysis of kinetics on multidimensional potential-energy surfaces.

    PubMed

    Okushima, T; Niiyama, T; Ikeda, K S; Shimizu, Y

    2009-09-01

    The aim of this paper is twofold: one is to give a detailed description of an alternative graph-based analysis method, which we call saddle connectivity graph, for analyzing the global topography and the dynamical properties of many-dimensional potential-energy landscapes and the other is to give examples of applications of this method in the analysis of the kinetics of realistic systems. A Dijkstra-type shortest path algorithm is proposed to extract dynamically dominant transition pathways by kinetically defining transition costs. The applicability of this approach is first confirmed by an illustrative example of a low-dimensional random potential. We then show that a coarse-graining procedure tailored for saddle connectivity graphs can be used to obtain the kinetic properties of 13- and 38-atom Lennard-Jones clusters. The coarse-graining method not only reduces the complexity of the graphs, but also, with iterative use, reveals a self-similar hierarchical structure in these clusters. We also propose that the self-similarity is common to many-atom Lennard-Jones clusters.

  20. Harvard University High Energy Physics progress report

    SciTech Connect

    Not Available

    1992-10-01

    The principal goals of this work are to carry out forefront programs in high energy physics research and to provide first rate educational opportunities for students. The experimental program supported through HEPL is carried out at the major accelerator centers in the world and addresses some of the most important questions in high energy physics. The program is based at Harvard`s High Energy Physics Laboratory, which has offices, computing facilities, and engineering support, and both electronics and machine shops.

  1. Harvard University High Energy Physics progress report

    SciTech Connect

    Not Available

    1992-01-01

    The principal goals of this work are to carry out forefront programs in high energy physics research and to provide first rate educational opportunities for students. The experimental program supported through HEPL is carried out at the major accelerator centers in the world and addresses some of the most important questions in high energy physics. The program is based at Harvard's High Energy Physics Laboratory, which has offices, computing facilities, and engineering support, and both electronics and machine shops.

  2. Analysis and prediction of integrated kinetic energy in Atlantic tropical cyclones

    NASA Astrophysics Data System (ADS)

    Kozar, Michael E.

    Integrated kinetic energy (IKE) is a recently developed metric that approximates the destructive potential of a tropical cyclone by assessing the size and strength of its wind field. Despite the potential usefulness of the IKE metric, there are few, if any, operational tools that are specifically designed to forecast IKE in real-time. Therefore, IKE and tropical cyclone structure are analyzed within historical Atlantic tropical cyclones from the past two decades in order to develop an understanding of the environmental and internal storm-driven processes that govern IKE variability. This analysis concurs with past research that IKE growth and decay is influenced by both traditional tropical cyclone development mechanisms and by other features such as extratropical transition and trough interactions. Using this framework, a series of statistical prediction tools are created in an effort to project IKE in Atlantic tropical cyclones from a series of relevant normalized input parameters. The resulting IKE prediction schemes are titled the "Statistical Prediction of Integrated Kinetic Energy (SPIKE)". The first version of SPIKE utilizes simple linear regression to project historical IKE quantities in a perfect prognostic mode for all storms between 1990 and 2011. This primitive model acts as a proof of concept, revealing that IKE can be skillfully forecasted relative to persistence out to 72 hours by even the simplest of statistical models if given accurate estimates of various metrics measured throughout the storm and its environment. The proof-of-concept version of SPIKE is improved upon in its second version, SPIKE2, by incorporating a more sophisticated system of adaptive statistical models. A system of artificial neural networks replaces the linear regression model to better capture the nonlinear relationships in the TC-environment system. In a perfect prognostic approach with analyzed input parameters, the neural networks outperform the linear models in nearly

  3. Electrochemical cell and electrode designs for high-temperature/high-pressure kinetic measurements

    SciTech Connect

    Nagy, Z.; Yonco, R.M.

    1987-05-01

    Many corrosion processes of interest to the nuclear power industry occur in high-temperature/high-pressure aqueous systems. The investigation of the kinetics of the appropriate electrode reactions is a serious experimental challenge, partially because of the high temperatures and pressures and partially because many of these reactions are very rapid, requiring fast relaxation measurements. An electrochemical measuring system is described which is suitable for measurements of the kinetics of fast electrode reactions at temperatures extending to at least 300C and pressures to at least 10 MPa (100 atmospheres). The system includes solution preparation and handling equipment, the electrochemical cell, and several electrode designs. One of the new designs is a coaxial working electrode-counter electrode assembly; this electrode can be used with very fast-rising pulses, and it provides a well defined, repeatedly-polishable working surface. Low-impedance reference electrodes are also described, based on electrode concepts responding to the pH or the redox potential of the test solution. Additionally, a novel, long-life primary reference electrode design is reported, based on a modification of the external, pressure-balanced Ag/AgCl reference electrode.

  4. On energy balance and the structure of radiated waves in kinetics of crystalline defects

    NASA Astrophysics Data System (ADS)

    Sharma, Basant Lal

    2016-11-01

    Traveling waves, with well-known closed form expressions, in the context of the defects kinetics in crystals are excavated further with respect to their inherent structure of oscillatory components. These are associated with, so called, Frenkel-Kontorova model with a piecewise quadratic substrate potential, corresponding to the symmetric as well as asymmetric energy wells of the substrate, displacive phase transitions in bistable chains, and brittle fracture in triangular lattice strips under mode III conditions. The paper demonstrates that the power expended theorem holds so that the sum of rate of working and the rate of total energy flux into a control strip moving steadily with the defect equals the rate of energy sinking into the defect, in the sense of N.F. Mott. In the conservative case of the Frenkel-Kontorova model with asymmetric energy wells, this leads to an alternative expression for the mobility in terms of the energy flux through radiated lattice waves. An application of the same to the case of martensitic phase boundary and a crack, propagating uniformly in bistable chains and triangular lattice strips, respectively, is also provided and the energy release is expressed in terms of the radiated energy flux directly. The equivalence between the well-known expressions and their alternative is established via an elementary identity, which is stated and proved in the paper as the zero lemma. An intimate connection between the three distinct types of defects is, thus, revealed in the framework of energy balance, via a structural similarity between the corresponding variants of the 'zero' lemma containing the information about radiated energy flux. An extension to the dissipative models, in the presence of linear viscous damping, is detailed and analog of the zero lemma is proved. The analysis is relevant to the dynamics of dislocations, brittle cracks, and martensitic phase boundaries, besides possible applications to analogous physical contexts which are

  5. Minimal Model of Quantum Kinetic Clusters for the Energy-Transfer Network of a Light-Harvesting Protein Complex.

    PubMed

    Wu, Jianlan; Tang, Zhoufei; Gong, Zhihao; Cao, Jianshu; Mukamel, Shaul

    2015-04-02

    The energy absorbed in a light-harvesting protein complex is often transferred collectively through aggregated chromophore clusters. For population evolution of chromophores, the time-integrated effective rate matrix allows us to construct quantum kinetic clusters quantitatively and determine the reduced cluster-cluster transfer rates systematically, thus defining a minimal model of energy-transfer kinetics. For Fenna-Matthews-Olson (FMO) and light-havrvesting complex II (LCHII) monomers, quantum Markovian kinetics of clusters can accurately reproduce the overall energy-transfer process in the long-time scale. The dominant energy-transfer pathways are identified in the picture of aggregated clusters. The chromophores distributed extensively in various clusters can assist a fast and long-range energy transfer.

  6. Maximum proton kinetic energy and patient-generated neutron fluence considerations in proton beam arc delivery radiation therapy

    PubMed Central

    Sengbusch, E.; Pérez-Andújar, A.; DeLuca, P. M.; Mackie, T. R.

    2009-01-01

    Several compact proton accelerator systems for use in proton therapy have recently been proposed. Of paramount importance to the development of such an accelerator system is the maximum kinetic energy of protons, immediately prior to entry into the patient, that must be reached by the treatment system. The commonly used value for the maximum kinetic energy required for a medical proton accelerator is 250 MeV, but it has not been demonstrated that this energy is indeed necessary to treat all or most patients eligible for proton therapy. This article quantifies the maximum kinetic energy of protons, immediately prior to entry into the patient, necessary to treat a given percentage of patients with rotational proton therapy, and examines the impact of this energy threshold on the cost and feasibility of a compact, gantry-mounted proton accelerator treatment system. One hundred randomized treatment plans from patients treated with IMRT were analyzed. The maximum radiological pathlength from the surface of the patient to the distal edge of the treatment volume was obtained for 180° continuous arc proton therapy and for 180° split arc proton therapy (two 90° arcs) using CT# profiles from the Pinnacle™ (Philips Medical Systems, Madison, WI) treatment planning system. In each case, the maximum kinetic energy of protons, immediately prior to entry into the patient, that would be necessary to treat the patient was calculated using proton range tables for various media. In addition, Monte Carlo simulations were performed to quantify neutron production in a water phantom representing a patient as a function of the maximum proton kinetic energy achievable by a proton treatment system. Protons with a kinetic energy of 240 MeV, immediately prior to entry into the patient, were needed to treat 100% of patients in this study. However, it was shown that 90% of patients could be treated at 198 MeV, and 95% of patients could be treated at 207 MeV. Decreasing the proton kinetic

  7. Kinetic energy of shakeoff atomic electrons from 37K β+ decay

    NASA Astrophysics Data System (ADS)

    Behr, J. A.; Gorelov, A.; Farfan, C.; Smale, S.; Olchanski, K.; Kurchananov, L.; Anholm, M.; Behling, R. S.; Fenker, B.; Shidling, P. D.; Mehlman, M.; Melconian, D.; Ashery, D.; Gwinner, G.; Trinat Collaboration

    2013-10-01

    We have measured the kinetic energies from 0 to 30 eV of atomic shakeoff electrons from the β+ decay of 37K. Despite much experimental and theoretical work on the distribution of final ion charge states, shakeoff electrons from β- decay have only been measured with energies above 150 eV [Mitrokhovich, Nucl. Phys. Atom. Energy, 11, 125 (2010)]. We use our magneto-optical trap's time-varying magnetic quadrupole field combined with a uniform electric field as a spectrometer. Our result has more 15 eV electrons than a model using the sudden approximation and hydrogenic wavefunctions [Levinger, Phys. Rev. 90, 11 (1958)]. The total energy carried away by electrons is, as expected, a negligible correction to superallowed Ft values. Understanding the energy of these low-energy electrons is important for their use in precision β decay to select events coming from trapped atoms and start time-of-flight for the recoil ions. Our results could provide a benchmark for shakeoff electron calculations used for biological radiation damage [Lee, Comp. Math. Meth in Medicine doi:10.1155/2012/651475]. Support: NSERC, NRC through TRIUMF, DOE ER41747 ER40773, State of Texas, Israel Science Foundation.

  8. Energy Activities for Junior High Science.

    ERIC Educational Resources Information Center

    Beaver, David; And Others

    This document is a collection of six energy education activities for junior high school science. Its purpose is to help promote knowledge about energy, provide laboratory experiences, provoke inquiry, and relate energy to society through the science curriculum. The six activities are designed to take one to three class periods. Two of the…

  9. High Average Power, High Energy Short Pulse Fiber Laser System

    SciTech Connect

    Messerly, M J

    2007-11-13

    Recently continuous wave fiber laser systems with output powers in excess of 500W with good beam quality have been demonstrated [1]. High energy, ultrafast, chirped pulsed fiber laser systems have achieved record output energies of 1mJ [2]. However, these high-energy systems have not been scaled beyond a few watts of average output power. Fiber laser systems are attractive for many applications because they offer the promise of high efficiency, compact, robust systems that are turn key. Applications such as cutting, drilling and materials processing, front end systems for high energy pulsed lasers (such as petawatts) and laser based sources of high spatial coherence, high flux x-rays all require high energy short pulses and two of the three of these applications also require high average power. The challenge in creating a high energy chirped pulse fiber laser system is to find a way to scale the output energy while avoiding nonlinear effects and maintaining good beam quality in the amplifier fiber. To this end, our 3-year LDRD program sought to demonstrate a high energy, high average power fiber laser system. This work included exploring designs of large mode area optical fiber amplifiers for high energy systems as well as understanding the issues associated chirped pulse amplification in optical fiber amplifier systems.

  10. Turbulent kinetic energy dissipation rates in the polar mesosphere measured by a 3-MHz-Doppler radar

    NASA Astrophysics Data System (ADS)

    Latteck, R.; Singer, W.; Hocking, W. K.

    2005-08-01

    Turbulence produces changes in the spectral width of a backscattered radar signal which can be used to deduce turbulent energy dissipation rates at the region of the scatter. Since the radar signal spectrum is also influenced by the background wind field causing broadening effects of the spectrum, a system with a relative small beam width as well as corresponding methods to correct for the non-turbulent broadening of the spectrum are necessary for the estimation of reliable energy dissipation rates. The new narrow beam MF radar at Saura on Andøya island in northern Norway has got a Mills-Cross antenna with a minimum beam width of θ = 6.6° (Half-Power-Full-Width, one way) and a modular transceiver system which provides high flexibility in beam pointing as well as beam forming. An correction method for non-turbulent spectral broadening effects has been implemented for the estimation of turbulence intensities from the width of the observed signal spectra. The method requires the precise knowledge of the antenna radiation pattern and real-time measurements of the wind field. The critical steps of the estimation of the turbulent part of the signal spectrum are discussed. Turbulent kinetic energy dissipation rates based on the spectral width method are obtained with the Saura MF radar since September 2003. The radar results are compared with corresponding data from rocket measurements at Andenes under summer and winter conditions, as well as with the results from the Kühlungsborn Mechanistic Circulation Model (KMCM). The mean turbulent kinetic energy dissipation rates basing on these radar measurements are about 5 mW/kg at 60 km altitude and about 20 mW/kg at 80 km, in reasonable agreement with mean turbulence intensities obtained from previous rocket soundings at Andenes.

  11. On the Origin of Ultra High Energy Cosmic Rays

    SciTech Connect

    Fowler, T; Colgate, S; Li, H

    2009-07-01

    Turbulence-driven plasma accelerators produced by magnetized accretion disks around black holes are proposed as the mechanism mainly responsible for observed cosmic ray protons with ultra high energies 10{sup 19}-10{sup 21} eV. The magnetized disk produces a voltage comparable to these cosmic ray energies. Here we present a Poynting model in which this voltage provides all of the energy to create the jet-like structures observed to be ejected from accretion disks, and this voltage also accelerates ions to high energies at the top of the expanding structure. Since the inductive electric field E = -v x B driving expansion has no component parallel to the magnetic field B, ion acceleration requires plasma wave generation - either a coherent wave accelerator as recently proposed, or instability-driven turbulence. We find that turbulence can tap the full inductive voltage as a quasi-steady accelerator, and even higher energies are produced by transient events on this structure. We find that both MHD modes due to the current and ion diffusion due to kinetic instability caused by the non-Maxwellian ion distribution contribute to acceleration. We apply our results to extragalactic giant radiolobes, whose synchrotron emissions serve to calibrate the model, and we discuss extrapolating to other astrophysical structures. Approximate calculations of the cosmic ray intensity and energy spectrum are in rough agreement with data and serve to motivate more extensive MHD and kinetic simulations of turbulence that could provide more accurate cosmic ray and synchrotron spectra to be compared with observations. A distinctive difference from previous models is that the cosmic ray and synchrotron emissions arise from different parts of the magnetic structure, thus providing a signature for the model.

  12. Cars and Kinetic Energy -- Some Simple Physics with Real-World Relevance

    NASA Astrophysics Data System (ADS)

    Parthasarathy, Raghuveer

    2012-10-01

    Understanding energy usage is crucial to understanding modern civilization, as well as many of the challenges it faces. Energy-related issues also offer real-world examples of important physical concepts, and as such have been the focus of several articles in The Physics Teacher in the past few decades (e.g., Refs. 1-5, noted further below). Here, I illustrate how a basic understanding of kinetic energy—a topic encountered early in any introductory physics course—enables significant insights into the nature of automobile transportation. Specifically, we can accurately predict how much power the average driver in the United States uses, and explain what determines this, without needing to consider any aspects of mechanical engineering or engine design.

  13. Low-energy signals from kinetic mixing with a warped abelian hidden sector

    NASA Astrophysics Data System (ADS)

    McDonald, Kristian L.; Morrissey, David E.

    2011-02-01

    We investigate the detailed phenomenology of a light Abelian hidden sector in the Randall-Sundrum framework. Relative to other works with light hidden sectors, the main new feature is a tower of hidden Kaluza-Klein vectors that kinetically mix with the Standard Model photon and Z. We investigate the decay properties of the hidden sector fields in some detail, and develop an approach for calculating processes initiated on the ultraviolet brane of a warped space with large injection momentum relative to the infrared scale. Using these results, we determine the detailed bounds on the light warped hidden sector from precision electroweak measurements and low-energy experiments. We find viable regions of parameter space that lead to significant production rates for several of the hidden Kaluza-Klein vectors in meson factories and fixed-target experiments. This offers the possibility of exploring the structure of an extra spacetime dimension with lower-energy probes.

  14. Dependence of single-walled carbon nanotube adsorption kinetics on temperature and binding energy.

    PubMed

    Rawat, D S; Krungleviciute, V; Heroux, L; Bulut, M; Calbi, M M; Migone, A D

    2008-12-02

    We present results for the isothermal adsorption kinetics of methane, hydrogen, and tetrafluoromethane on closed-ended single-walled carbon nanotubes. In these experiments, we monitor the pressure decrease as a function of time as equilibrium is approached, after a dose of gas is added to the cell containing the nanotubes. The measurements were performed at different fractional coverages limited to the first layer. The results indicate that, for a given coverage and temperature, the equilibration time is an increasing function of E/(k(B)T), where E is the binding energy of the adsorbate and k(B)T is the thermal energy. These findings are consistent with recent theoretical predictions and computer simulations results that we use to interpret the experimental measurements.

  15. Kinetic and geometric isotope effects originating from different adsorption potential energy surfaces: cyclohexane on Rh(111).

    PubMed

    Koitaya, Takanori; Shimizu, Sumera; Mukai, Kozo; Yoshimoto, Shinya; Yoshinobu, Jun

    2012-06-07

    Novel isotope effects were observed in desorption kinetics and adsorption geometry of cyclohexane on Rh(111) by the use of infrared reflection absorption spectroscopy, temperature programmed desorption, photoelectron spectroscopy, and spot-profile-analysis low energy electron diffraction. The desorption energy of deuterated cyclohexane (C(6)D(12)) is lower than that of C(6)H(12). In addition, the work function change by adsorbed C(6)D(12) is smaller than that by adsorbed C(6)H(12). These results indicate that C(6)D(12) has a shallower adsorption potential than C(6)H(12) (vertical geometric isotope effect). The lateral geometric isotope effect was also observed in the two-dimensional cyclohexane superstructures as a result of the different repulsive interaction between interfacial dipoles. The observed isotope effects should be ascribed to the quantum nature of hydrogen involved in the C-H···metal interaction.

  16. Kinetic energy density and agglomerate abrasion rate during blending of agglomerates into powders.

    PubMed

    Willemsz, Tofan A; Hooijmaijers, Ricardo; Rubingh, Carina M; Tran, Thanh N; Frijlink, Henderik W; Vromans, Herman; van der Voort Maarschalk, Kees

    2012-01-23

    Problems related to the blending of a cohesive powder with a free flowing bulk powder are frequently encountered in the pharmaceutical industry. The cohesive powder often forms lumps or agglomerates which are not dispersed during the mixing process and are therefore detrimental to blend uniformity. Achieving sufficient blend uniformity requires that the blending conditions are able to break up agglomerates, which is often an abrasion process. This study was based on the assumption that the abrasion rate of agglomerates determines the required blending time. It is shown that the kinetic energy density of the moving powder bed is a relevant parameter which correlates with the abrasion rate of agglomerates. However, aspects related to the strength of agglomerates should also be considered. For this reason the Stokes abrasion number (St(Abr)) has been defined. This parameter describes the ratio between the kinetic energy density of the moving powder bed and the work of fracture of the agglomerate. The St(Abr) number is shown to predict the abrasion potential of agglomerates in the dry-mixing process. It appeared possible to include effects of filler particle size and impeller rotational rate into this concept. A clear relationship between abrasion rate of agglomerates and the value of St(Abr) was demonstrated.

  17. A kinetic energy model of two-vehicle crash injury severity.

    PubMed

    Sobhani, Amir; Young, William; Logan, David; Bahrololoom, Sareh

    2011-05-01

    An important part of any model of vehicle crashes is the development of a procedure to estimate crash injury severity. After reviewing existing models of crash severity, this paper outlines the development of a modelling approach aimed at measuring the injury severity of people in two-vehicle road crashes. This model can be incorporated into a discrete event traffic simulation model, using simulation model outputs as its input. The model can then serve as an integral part of a simulation model estimating the crash potential of components of the traffic system. The model is developed using Newtonian Mechanics and Generalised Linear Regression. The factors contributing to the speed change (ΔV(s)) of a subject vehicle are identified using the law of conservation of momentum. A Log-Gamma regression model is fitted to measure speed change (ΔV(s)) of the subject vehicle based on the identified crash characteristics. The kinetic energy applied to the subject vehicle is calculated by the model, which in turn uses a Log-Gamma Regression Model to estimate the Injury Severity Score of the crash from the calculated kinetic energy, crash impact type, presence of airbag and/or seat belt and occupant age.

  18. The Effects of Kinetic Energy on Concentric and Eccentric Isokinetic Work

    PubMed Central

    Boggess, Brian; Moffit, Jeff; Morales, Jacobo; Anderson, Tim

    2008-01-01

    This investigation examined inertial effects on work output during isokinetic concentric knee extension and eccentric knee flexion. Total work (Wtotal) included work due to kinetic energy (Wkin), with respect to gravity (Wgrav), and against the dynamometer (Wdyn). Eighteen resistance-trained participants (9 males, 9 females) performed maximal voluntary concentric (90, 150, 210, 270 deg/s) and eccentric (-150, -90, -30 deg/s) actions with the dominant leg. Differences between work measurement type (WMT), i.e., gravity-corrected work and Wtotal, were assessed. ANOVA (2 WMT x 2 mode x 2 gender x 4 speed) revealed significant main effects (p < 0. 05) for both factors concentrically but only for WMT eccentrically. It was concluded that the effect of kinetic energy during isokinetic leg extension may elicit differences in measurement where the associated error (Kerr) significantly increases with increasing velocity concentrically and decreases eccentrically. Key pointsTotal isokinetic work is underestimated by standard gravity corrected techniques.Standard gravity corrected work measurements overestimate isometric eccentric total work.The overestimation of isometric eccentric total work increases with greater angular velocity. PMID:24150138

  19. A multiple-time-scale turbulence model based on variable partitioning of turbulent kinetic energy spectrum

    NASA Technical Reports Server (NTRS)

    Kim, S.-W.; Chen, C.-P.

    1987-01-01

    A multiple-time-scale turbulence model of a single point closure and a simplified split-spectrum method is presented. In the model, the effect of the ratio of the production rate to the dissipation rate on eddy viscosity is modeled by use of the multiple-time-scales and a variable partitioning of the turbulent kinetic energy spectrum. The concept of a variable partitioning of the turbulent kinetic energy spectrum and the rest of the model details are based on the previously reported algebraic stress turbulence model. Example problems considered include: a fully developed channel flow, a plane jet exhausting into a moving stream, a wall jet flow, and a weakly coupled wake-boundary layer interaction flow. The computational results compared favorably with those obtained by using the algebraic stress turbulence model as well as experimental data. The present turbulence model, as well as the algebraic stress turbulence model, yielded significantly improved computational results for the complex turbulent boundary layer flows, such as the wall jet flow and the wake boundary layer interaction flow, compared with available computational results obtained by using the standard kappa-epsilon turbulence model.

  20. Hypovalency--a kinetic-energy density description of a 4c-2e bond.

    PubMed

    Jacobsen, Heiko

    2009-06-07

    A bond descriptor based on the kinetic energy density, the localized-orbital locator (LOL), is used to characterize the nature of the chemical bond in electron deficient multi-center bonds. The boranes B(2)H(6), B(4)H(4), B(4)H(10), [B(6)H(6)](2-), and [B(6)H(7)](-) serve as prototypical examples of hypovalent 3c-2e and 4c-2e bonding. The kinetic energy density is derived from a set of Kohn-Sham orbitals obtained from pure density functional calculations (PBE/TZVP), and the topology of LOL is analyzed in terms of (3,-3) attractors (Gamma). The B-B-B and B-H-B 3c-2e, and the B-B-H-B 4c-2e bonding situations are defined by their own characteristic LOL profiles. The presence of one attractor in relation to the three or four atoms that are engaged in electron deficient bonding provides sufficient indication of the type of 3c-2e or 4c-2e bond present. For the 4c-2e bond in [B(6)H(7)](-) the LOL analysis is compared to results from an experimental QTAIM study.

  1. Kinetic energy entrainment in wind turbine and actuator disc wakes: an experimental analysis

    NASA Astrophysics Data System (ADS)

    Lignarolo, L. E. M.; Ragni, D.; Simão Ferreira, C. J.; van Bussel, G. J. W.

    2014-06-01

    The present experimental study focuses on the comparison between the wake of a two-bladed wind turbine and the one of an actuator disk. The flow field at the middle plane of the wake is measured with a stereoscopic particle image velocimetry setup, in the low-speed Open Jet Facility wind tunnel of the Delft University of Technology. The wind turbine wake is characterized by the complex dynamics of the tip vortex development and breakdown. Analysis of the flow statistics show anisotropic turbulent fluctuations in the turbine wake, with stronger components in the radial direction. The wake of the actuator disc is instead characterized by isotropic random fluctuations. The mixing process in the shear layer is further analysed in terms of flux of mean flow kinetic energy, to show the main differences between the kinetic energy entrainment in the actuator and the turbine wake. This project is intended to provide the basis for understanding the origin of the limitations of the current wake models based on the actuator disc assumption.

  2. Kinetic analysis and energy efficiency of phenol degradation in a plasma-photocatalysis system.

    PubMed

    Wang, Hui-juan; Chen, Xiao-yang

    2011-02-28

    Combination of two kinds of advanced oxidation processes (AOPs) is an effective approach to control wastewater pollution. In this research, a pulsed discharge plasma system with multi-point-to-plate electrode and an immobilized TiO(2) photocatalysis system is coupled to oxidize target pollutant in aqueous solution. Kinetic analysis (pseudo-first order kinetic constant, k) and energy efficiency (energy yield value at 50% phenol conversion, G(50)) of phenol oxidation in different reaction systems (plasma alone and plasma-photocatalysis) are reviewed to account for the synergistic mechanism of plasma and photocatalysis. The experimental results show that higher k and G(50) of phenol oxidation can be obtained in the plasma-photocatalysis system under the conditions of different gas bubbling varieties, initial solution pH and radical scavenger addition. Moreover, the investigation tested hydroxyl radical (OH) is the most important species for phenol removal in the synergistic system of plasma-photocatalysis as well as in the plasma alone system.

  3. High-bay Lighting Energy Conservation Measures

    SciTech Connect

    Ian Metzger, Jesse Dean

    2010-12-31

    This software requires inputs of simple high-bay lighting system inventory information and calculates the energy and cost benefits of various retrofit opportunities. This tool includes energy conservation measures for: 1000 Watt to 750 Watt High-pressure Sodium lighting retrofit, 400 Watt to 360 Watt High Pressure Sodium lighting retrofit, High Intensity Discharge to T5 lighting retrofit, High Intensity Discharge to T8 lighting retrofit, and Daylighting. This tool calculates energy savings, demand reduction, cost savings, building life cycle costs including: simple payback, discounted payback, net-present value, and savings to investment ratio. In addition this tool also displays the environmental benefits of a project.

  4. High energy physics in the United States

    SciTech Connect

    Month, M.

    1985-10-16

    The US program in high energy physics from 1985 to 1995 is reviewed. The program depends primarily upon work at the national accelerator centers, but includes a modest but diversified nonaccelerator program. Involvement of universities is described. International cooperation in high energy physics is discussed, including the European, Japanese, USSR, and the People's Republic of China's programs. Finally, new facilities needed by the US high energy physics program are discussed, with particular emphasis given to a Superconducting Super Collider for achieving ever higher energies in the 20 TeV range. (LEW)

  5. Turbulent Flame Speeds and NOx Kinetics of HHC Fuels with Contaminants and High Dilution Levels

    SciTech Connect

    Peterson, Eric; Krejci, Michael; Mathieu, Olivier; Vissotski, Andrew; Ravi, Sankat; Plichta, Drew; Sikes, Travis; Levacque, Anthony; Camou, Alejandro; Aul, Christopher

    2014-01-24

    This final report documents the technical results of the 3-year project entitled, “Turbulent Flame Speeds and NOx Kinetics of HHC Fuels with Contaminants and High Dilution Levels,” funded under the NETL of DOE. The research was conducted under six main tasks: 1) program management and planning; 2) turbulent flame speed measurements of syngas mixtures; 3) laminar flame speed measurements with diluents; 4) NOx mechanism validation experiments; 5) fundamental NOx kinetics; and 6) the effect of impurities on NOx kinetics. Experiments were performed using primary constant-volume vessels for laminar and turbulent flame speeds and shock tubes for ignition delay times and species concentrations. In addition to the existing shock- tube and flame speed facilities, a new capability in measuring turbulent flame speeds was developed under this grant. Other highlights include an improved NOx kinetics mechanism; a database on syngas blends for real fuel mixtures with and without impurities; an improved hydrogen sulfide mechanism; an improved ammonia kintics mechanism; laminar flame speed data at high pressures with water addition; and the development of an inexpensive absorption spectroscopy diagnostic for shock-tube measurements of OH time histories. The Project Results for this work can be divided into 13 major sections, which form the basis of this report. These 13 topics are divided into the five areas: 1) laminar flame speeds; 2) Nitrogen Oxide and Ammonia chemical kinetics; 3) syngas impurities chemical kinetics; 4) turbulent flame speeds; and 5) OH absorption measurements for chemical kinetics.

  6. Thermogravimetric and model-free kinetic studies on CO2 gasification of low-quality, high-sulphur Indian coals

    NASA Astrophysics Data System (ADS)

    Das, Tonkeswar; Saikia, Ananya; Mahanta, Banashree; Choudhury, Rahul; Saikia, Binoy K.

    2016-10-01

    Coal gasification with CO2 has emerged as a cleaner and more efficient way for the production of energy, and it offers the advantages of CO2 mitigation policies through simultaneous CO2 sequestration. In the present investigation, a feasibility study on the gasification of three low-quality, high-sulphur coals from the north-eastern region (NER) of India in a CO2 atmosphere using thermogravimetric analysis (TGA-DTA) has been made in order to have a better understanding of the physical and chemical characteristics in the process of gasification of coal. Model-free kinetics was applied to determine the activation energies (E) and pre-exponential factors (A) of the CO2 gasification process of the coals. Multivariate non-linear regression analyses were performed to find out the formal mechanisms, kinetic model, and the corresponding kinetic triplets. The results revealed that coal gasification with CO2 mainly occurs in the temperature range of 800∘-1400∘C and a maximum of at around 1100∘C. The reaction mechanisms responsible for CO2 gasification of the coals were observed to be of the ` nth order with autocatalysis (CnB)' and ` nth order (Fn) mechanism'. The activation energy of the CO2 gasification was found to be in the range 129.07-146.81 kJ mol-1.

  7. Quantitation of fluorescence energy transfer between cell surface proteins via fluorescence donor photobleaching kinetics.

    PubMed Central

    Young, R M; Arnette, J K; Roess, D A; Barisas, B G

    1994-01-01

    We describe practical aspects of photobleaching fluorescence energy transfer measurements on individual living cells. The method introduced by T. M. Jovin and co-workers (see, most recently, Kubitscheck et al. 1993. Biophys. J. 64:110) is based on the reduced rate of irreversible photobleaching of donor fluorophores when acceptor fluorophores are present. Measuring differences in donor photobleaching rates on cells labeled with donor only (fluorescein isothiocyanate-conjugated proteins) and with both donor and acceptor (tetramethylrhodamine-conjugated proteins) allows calculation of the fluorescence energy transfer efficiency. We assess possible methods of data analysis in light of the underlying processes of photobleaching and energy transfer and suggest optimum strategies for this purpose. Single murine B lymphocytes binding various ratios of donor and acceptor conjugates of tetravalent concanavalin A (Con A) and divalent succinyl Con A were examined for interlectin energy transfer by these methods. For Con A, a maximum transfer efficiency of 0.49 +/- 0.02 was observed. Under similar conditions flow cytometric measurements of donor quenching yielded a value of 0.54 +/- 0.03. For succinyl Con A, the maximum transfer efficiency was 0.36. To provide concrete examples of quantities arising in such energy transfer determinations, we present examples of individual cell data and kinetic analyses, population rate constant distributions, and error estimates for the various quantities involved. PMID:7948701

  8. The spin-forbidden a 4Π(nu =13-15) and b 4Sigma - (nu =3) <-- X 2Π(nu =0) bands of nitric oxide: A new scheme for quantum state-specific high-resolution kinetic energy measurements

    NASA Astrophysics Data System (ADS)

    Drabbels, Marcel; Morgan, C. G.; Wodtke, A. M.

    1995-11-01

    A new scheme for performing high-resolution kinetic energy measurements on single quantum states of NO is described. Laser excitation of the a 4Π(ν=13-15) and b 4Σ-(ν=3)←X 2Π(ν=0) spin-forbidden bands has been used to produce NO a 4Π, either by direct excitation or after excitation to NO b 4Σ- followed by b→a emission. The sensitivity is compared to previous experiments on CO, employing the forbidden Cameron system. In the course of these experiments, three previously unknown vibronic levels of the a 4Π state were observed for which high precision molecular constants have been obtained. The derived molecular constants have been used to construct a chemically accurate RKR potential for the a 4Π state to within 0.2 eV of the dissociation limit. In addition, the electric dipole moments for the a 4Π(ν=13-14) levels have been determined. By comparing the experimental results with two ab initio calculations, the polarity of the dipole moment of the a 4Π state at equilibrium separation could be determined. A set of supplementary molecular beam laser-induced fluorescence studies on the b 4Σ-(ν=3)←X 2Π(ν=0) band were also carried out. These allowed the fluorescence lifetime of b 4Σ-(ν=3) state to be obtained under collision-free conditions and the electronic origin of the quartet manifold to be determined within 0.03 cm-1.

  9. Black holes and high energy physics

    NASA Astrophysics Data System (ADS)

    Grib, A. A.; Pavlov, Yu. V.

    2016-01-01

    Three mechanisms of getting high energies in particle collisions in the ergosphere of the rotating black holes are considered. The consequences of these mechanisms for observation of ultra high energy cosmic rays particles on the Earth as result of conversion of superheavy dark matter particles into ordinary particles are discussed.

  10. GEANT4: Applications in High Energy Physics

    SciTech Connect

    Mahmood, Tariq; Zafar, Abrar Ahmed; Hussain, Talib; Rashid, Haris

    2007-02-14

    GEANT4 is a detector simulation toolkit aimed at studying, mainly experimental high energy physics. In this paper we will give an overview of this software with special reference to its applications in high energy physics experiments. A brief of process methods is given. Object-oriented nature of the simulation toolkit is highlighted.

  11. High energy interactions of cosmic ray particles

    NASA Technical Reports Server (NTRS)

    Jones, L. W.

    1986-01-01

    The highlights of seven sessions of the Conference dealing with high energy interactions of cosmic rays are discussed. High energy cross section measurements; particle production-models of experiments; nuclei and nuclear matter; nucleus-nucleus collision; searches for magnetic monopoles; and studies of nucleon decay are covered.

  12. Numerical evaluation of high energy particle effects in magnetohydrodynamics

    SciTech Connect

    White, R.B.; Wu, Y.

    1994-03-01

    The interaction of high energy ions with magnetohydrodynamic modes is analyzed. A numerical code is developed which evaluates the contribution of the high energy particles to mode stability using orbit averaging of motion in either analytic or numerically generated equilibria through Hamiltonian guiding center equations. A dispersion relation is then used to evaluate the effect of the particles on the linear mode. Generic behavior of the solutions of the dispersion relation is discussed and dominant contributions of different components of the particle distribution function are identified. Numerical convergence of Monte-Carlo simulations is analyzed. The resulting code ORBIT provides an accurate means of comparing experimental results with the predictions of kinetic magnetohydrodynamics. The method can be extended to include self consistent modification of the particle orbits by the mode, and hence the full nonlinear dynamics of the coupled system.

  13. Kinetic Processes in High Pressure Gases: Excited State Collisions.

    DTIC Science & Technology

    1980-12-01

    Missouri-Rolla Rolla, MO 65401 Technical Report to the Office of Naval Research Grant No. N00014-75-C-0477 for the period December 1979 - December 1980...DESCRIPTION The purpose of the research program is to investigate energy exchange and energy loss mechanisms in discharge plasmas and their afterglows...pressure of 10-6 Torr. Sodium was titrated into a reservoir attached to the reaction cell. Research grade argon was admitted to the desired pressure

  14. High Energy Continuum of High Redshift Quasars

    NASA Technical Reports Server (NTRS)

    Elvis, Martin

    2000-01-01

    Discussion with the RXTE team at GSFC showed that a sufficiently accurate background subtraction procedure had now, been derived for sources at the flux level of PKS 2126-158. However this solution does not apply to observations carried out before April 1997, including our observation. The prospect of an improved solution becoming available soon is slim. As a result the RXTE team agreed to re-observe PKS2126-158. The new observation was carried out in April 1999. Quasi-simultaneous optical observations were obtained, as Service observing., at the 4-meter Anglo-Australian Telescope, and ftp-ed from the AAT on 22April. The RXTE data was processed in late June, arriving at SAO in early July. Coincidentally, our collaborative Beppo-SAX observation of PKS2126-158 was made later in 1999, and a GTO Chandra observation (with which we are involved) was made on November 16. Since this gives us a unique monitoring data for a high redshift quasar over a broad pass-band we are now combining all three observations into a single comprehensive study Final publication of the RXTE data will thus take place under another grant.

  15. High energy physics at UCR

    SciTech Connect

    Kernan, A.; Shen, B.C.

    1997-07-01

    The hadron collider group is studying proton-antiproton interactions at the world`s highest collision energy 2 TeV. Data-taking with the D0 detector is in progress at Fermilab and the authors have begun the search for the top quark. S. Wimpenny is coordinating the effort to detect t{bar t} decaying to two leptons, the most readily identifiable channel. At UC Riverside design and testing for a silicon tracker for the D0 upgrade is in progress; a parallel development for the SDC detector at SSC is also underway. The major group effort of the lepton group has been devoted to the OPAL experiment at LEP. They will continue to focus on data-taking to improve the quality and quantity of their data sample. A large number of papers have been published based on approximately 500,000 events taken so far. The authors will concentrate on physics analysis which provides stringent tests of the Standard Model. The authors are continuing participation in the RD5 experiment at the SPS to study muon triggering and tracking. The results of this experiment will provide critical input for the design of the Compact Muon Solenoid experiment being proposed for the LHC. The theory group has been working on problems concerning the possible vilation of e-{mu}-{tau} universality, effective Lagrangians, neutrino physics, as well as quark and lepton mass matrices.

  16. Particle kinetic simulation of high altitude hypervelocity flight

    NASA Technical Reports Server (NTRS)

    Haas, Brian L.

    1993-01-01

    In this grant period, the focus has been on enhancement and application of the direct simulation Monte Carlo (DSMC) particle method for computing hypersonic flows of re-entry vehicles. Enhancement efforts dealt with modeling gas-gas interactions for thermal non-equilibrium relaxation processes and gas-surface interactions for prediction of vehicle surface temperatures. Both are important for application to problems of engineering interest. The code was employed in a parametric study to improve future applications, and in simulations of aeropass maneuvers in support of the Magellan mission. Detailed comparisons between continuum models for internal energy relaxation and DSMC models reveals that several discrepancies exist. These include definitions of relaxation parameters and the methodologies for implementing them in DSMC codes. These issues were clarified and all differences were rectified in a paper (Appendix A) submitted to Physics of Fluids A, featuring several key figures in the DSMC community as co-authors and B. Haas as first author. This material will be presented at the Fluid Dynamics meeting of the American Physical Society on November 21, 1993. The aerodynamics of space vehicles in highly rarefied flows are very sensitive to the vehicle surface temperatures. Rather than require prescribed temperature estimates for spacecraft as is typically done in DSMC methods, a new technique was developed which couples the dynamic surface heat transfer characteristics into the DSMC flow simulation code to compute surface temperatures directly. This model, when applied to thin planar bodies such as solar panels, was described in AIAA Paper No. 93-2765 (Appendix B) and was presented at the Thermophysics Conference in July 1993. The paper has been submitted to the Journal of Thermophysics and Heat Transfer. Application of the DSMC method to problems of practical interest requires a trade off between solution accuracy and computational expense and limitations. A

  17. High-energy cosmic rays and neutrinos from semirelativistic hypernovae

    SciTech Connect

    Wang Xiangyu; Razzaque, Soebur; Meszaros, Peter; Dai Zigao

    2007-10-15

    The origin of the ultrahigh-energy (UHE) cosmic rays (CRs) from the second knee ({approx}6x10{sup 17} eV) above in the CR spectrum is still unknown. Recently, there has been growing evidence that a peculiar type of supernovae, called hypernovae, are associated with subenergetic gamma-ray bursts, such as SN1998bw/GRB980425 and SN2003lw/GRB031203. Such hypernovae appear to have high (up to mildly relativistic) velocity ejecta, which may be linked to the subenergetic gamma-ray bursts. Assuming a continuous distribution of the kinetic energy of the hypernova ejecta as a function of its velocity E{sub k}{proportional_to}({gamma}{beta}){sup -{alpha}} with {alpha}{approx}2, we find that (1) the external shock wave produced by the high-velocity ejecta of a hypernova can accelerate protons up to energies as high as 10{sup 19} eV; (2) the cosmological hypernova rate is sufficient to account for the energy flux above the second knee; and (3) the steeper spectrum of CRs at these energies can arise in these sources. In addition, hypernovae would also give rise to a faint diffuse UHE neutrino flux, due to p{gamma} interactions of the UHE CRs with hypernova optical-UV photons.

  18. Zero kinetic energy photoelectron spectroscopy of tryptamine and the dissociation pathway of the singly hydrated cation cluster.

    PubMed

    Gu, Quanli; Knee, J L

    2012-09-14

    The relative ionization energies of tryptamine conformations are determined by zero kinetic energy photoelectron spectroscopy and photoionization efficiency measurements. The relative cationic conformational stabilities are compared to the published results for the neutral molecule. In the cation, the interaction strength changes significantly between amino group and either the phenyl or the pyrrole moiety of the indole chromophore where most of the positive charge is located, leading to different conformational structures and relative conformer energies in the cation. In particular, the measured adiabatic ionization potential of isomer B is 60,928 ± 5 cm(-1), at least 400 cm(-1) higher than any of the 6 other tryptamine isomers which all have ionization potentials within 200 cm(-1) of each other. In addition to the monomer, measurements were made on the A conformer of the tryptamine(+)-H(2)O complex including the ionization threshold and cation dissociation energy measured using a threshold photoionization fragmentation method. The water cluster exhibits an unexpectedly high ionization potential of 60,307 ± 100 cm(-1), close to the conformer A monomer of 60 320 ± 100 cm(-1). It also exhibits surprisingly low dissociation energy of 1750 ± 150 cm(-1) compared to other H-bonding involved cation-H(2)O complexes which are typically several thousands of wavenumbers higher. Quantum chemical calculations indicate that upon ionization the structure of the parent molecule in the water complex remains mostly unchanged due to the rigid intermolecular double hydrogen bonded water molecule bridging the monomer backbone and its side chain thus leading to the high ionization potential in the water cluster. The surprisingly low dissociation energy measured in the cationic water complex is attributed to the formation of a much more stable structural isomer H(+) in the exit channel.

  19. CFD modelling of small particle dispersion: The influence of the turbulence kinetic energy in the atmospheric boundary layer

    NASA Astrophysics Data System (ADS)

    Gorlé, C.; van Beeck, J.; Rambaud, P.; Van Tendeloo, G.

    When considering the modelling of small particle dispersion in the lower part of the Atmospheric Boundary Layer (ABL) using Reynolds Averaged Navier Stokes simulations, the particle paths depend on the velocity profile and on the turbulence kinetic energy, from which the fluctuating velocity components are derived to predict turbulent dispersion. It is therefore important to correctly reproduce the ABL, both for the velocity profile and the turbulence kinetic energy profile. For RANS simulations with the standard k- ɛ model, Richards and Hoxey (1993. Appropriate boundary conditions for computational wind engineering models using the k-ɛ turbulence model. Journal of Wind Engineering and Industrial Aerodynamics 46-47, 145-153.) proposed a set of boundary conditions which result in horizontally homogeneous profiles. The drawback of this method is that it assumes a constant profile of turbulence kinetic energy, which is not always consistent with field or wind tunnel measurements. Therefore, a method was developed which allows the modelling of a horizontally homogeneous turbulence kinetic energy profile that is varying with height. By comparing simulations performed with the proposed method to simulations performed with the boundary conditions described by Richards and Hoxey (1993. Appropriate boundary conditions for computational wind engineering models using the k-ɛ turbulence model. Journal of Wind Engineering and Industrial Aerodynamics 46-47, 145-153.), the influence of the turbulence kinetic energy on the dispersion of small particles over flat terrain is quantified.

  20. Controlling drug delivery kinetics from mesoporous titania thin films by pore size and surface energy.

    PubMed

    Karlsson, Johan; Atefyekta, Saba; Andersson, Martin

    2015-01-01

    The osseointegration capacity of bone-anchoring implants can be improved by the use of drugs that are administrated by an inbuilt drug delivery system. However, to attain superior control of drug delivery and to have the ability to administer drugs of varying size, including proteins, further material development of drug carriers is needed. Mesoporous materials have shown great potential in drug delivery applications to provide and maintain a drug concentration within the therapeutic window for the desired period of time. Moreover, drug delivery from coatings consisting of mesoporous titania has shown to be promising to improve healing of bone-anchoring implants. Here we report on how the delivery of an osteoporosis drug, alendronate, can be controlled by altering pore size and surface energy of mesoporous titania thin films. The pore size was varied from 3.4 nm to 7.2 nm by the use of different structure-directing templates and addition of a swelling agent. The surface energy was also altered by grafting dimethylsilane to the pore walls. The drug uptake and release profiles were monitored in situ using quartz crystal microbalance with dissipation (QCM-D) and it was shown that both pore size and surface energy had a profound effect on both the adsorption and release kinetics of alendronate. The QCM-D data provided evidence that the drug delivery from mesoporous titania films is controlled by a binding-diffusion mechanism. The yielded knowledge of release kinetics is crucial in order to improve the in vivo tissue response associated to therapeutic treatments.

  1. Controlling drug delivery kinetics from mesoporous titania thin films by pore size and surface energy

    PubMed Central

    Karlsson, Johan; Atefyekta, Saba; Andersson, Martin

    2015-01-01

    The osseointegration capacity of bone-anchoring implants can be improved by the use of drugs that are administrated by an inbuilt drug delivery system. However, to attain superior control of drug delivery and to have the ability to administer drugs of varying size, including proteins, further material development of drug carriers is needed. Mesoporous materials have shown great potential in drug delivery applications to provide and maintain a drug concentration within the therapeutic window for the desired period of time. Moreover, drug delivery from coatings consisting of mesoporous titania has shown to be promising to improve healing of bone-anchoring implants. Here we report on how the delivery of an osteoporosis drug, alendronate, can be controlled by altering pore size and surface energy of mesoporous titania thin films. The pore size was varied from 3.4 nm to 7.2 nm by the use of different structure-directing templates and addition of a swelling agent. The surface energy was also altered by grafting dimethylsilane to the pore walls. The drug uptake and release profiles were monitored in situ using quartz crystal microbalance with dissipation (QCM-D) and it was shown that both pore size and surface energy had a profound effect on both the adsorption and release kinetics of alendronate. The QCM-D data provided evidence that the drug delivery from mesoporous titania films is controlled by a binding–diffusion mechanism. The yielded knowledge of release kinetics is crucial in order to improve the in vivo tissue response associated to therapeutic treatments. PMID:26185444

  2. High-energy cosmic ray interactions

    SciTech Connect

    Engel, Ralph; Orellana, Mariana; Reynoso, Matias M.; Vila, Gabriela S.

    2009-04-30

    Research into hadronic interactions and high-energy cosmic rays are closely related. On one hand--due to the indirect observation of cosmic rays through air showers--the understanding of hadronic multiparticle production is needed for deriving the flux and composition of cosmic rays at high energy. On the other hand the highest energy particles from the universe allow us to study the characteristics of hadronic interactions at energies far beyond the reach of terrestrial accelerators. This is the summary of three introductory lectures on our current understanding of hadronic interactions of cosmic rays.

  3. Global Λ polarization in high energy collisions

    NASA Astrophysics Data System (ADS)

    Xie, Yilong; Wang, Dujuan; Csernai, László P.

    2017-03-01

    With a Yang-Mills flux-tube initial state and a high-resolution (3+1)D particle-in-cell relativistic (PICR) hydrodynamics simulation, we calculate the Λ polarization for different energies. The origination of polarization in high energy collisions is discussed, and we find linear impact parameter dependence of the global Λ polarization. Furthermore, the global Λ polarization in our model decreases very quickly in the low energy domain, and the decline curve fits well the recent results of Beam Energy Scan (BES) program launched by the STAR Collaboration at the Relativistic Heavy Ion Collider (RHIC). The time evolution of polarization is also discussed.

  4. High energy collimating fine grids

    NASA Astrophysics Data System (ADS)

    Arrieta, Victor M.; Tuffias, Robert H.; Laferla, Raffaele

    1995-02-01

    The objective of this project was to demonstrate the fabrication of extremely tight tolerance collimating grids using a high-Z material, specifically tungsten. The approach taken was to fabricate grids by a replication method involving the coating of a silicon grid substrate with tungsten by chemical vapor deposition (CVD). A negative of the desired grid structure was fabricated in silicon using highly wafering techniques developed for the semiconductor industry and capable of producing the required tolerances. Using diamond wafering blades, a network of accurately spaced slots was machined into a single-crystal silicon surface. These slots were then filled with tungsten by CVD, via the hydrogen reduction of tungsten hexafluoride. Following tungsten deposition, the silicon negative was etched away to leave the tungsten collimating grid structure. The project was divided into five tasks: (1) identify materials of construction for the replica and final collimating grid structures; (2) identify and implement a micromachining technique for manufacturing the negative collimator replicas (performed by NASA/JPL); (3) develop a CVD technique and processing parameters suitable for the complete tungsten densification of the collimator replicas; (4) develop a chemical etching technique for the removal of the collimator replicas after the tungsten deposition process; and (5) fabricate and deliver tungsten collimating grid specimens.

  5. High energy collimating fine grids

    NASA Technical Reports Server (NTRS)

    Arrieta, Victor M.; Tuffias, Robert H.; Laferla, Raffaele

    1995-01-01

    The objective of this project was to demonstrate the fabrication of extremely tight tolerance collimating grids using a high-Z material, specifically tungsten. The approach taken was to fabricate grids by a replication method involving the coating of a silicon grid substrate with tungsten by chemical vapor deposition (CVD). A negative of the desired grid structure was fabricated in silicon using highly wafering techniques developed for the semiconductor industry and capable of producing the required tolerances. Using diamond wafering blades, a network of accurately spaced slots was machined into a single-crystal silicon surface. These slots were then filled with tungsten by CVD, via the hydrogen reduction of tungsten hexafluoride. Following tungsten deposition, the silicon negative was etched away to leave the tungsten collimating grid structure. The project was divided into five tasks: (1) identify materials of construction for the replica and final collimating grid structures; (2) identify and implement a micromachining technique for manufacturing the negative collimator replicas (performed by NASA/JPL); (3) develop a CVD technique and processing parameters suitable for the complete tungsten densification of the collimator replicas; (4) develop a chemical etching technique for the removal of the collimator replicas after the tungsten deposition process; and (5) fabricate and deliver tungsten collimating grid specimens.

  6. Kinetic model for the vibrational energy exchange in flowing molecular gas mixtures. Ph.D. Thesis

    NASA Technical Reports Server (NTRS)

    Offenhaeuser, F.

    1987-01-01

    The present study is concerned with the development of a computational model for the description of the vibrational energy exchange in flowing gas mixtures, taking into account a given number of energy levels for each vibrational degree of freedom. It is possible to select an arbitrary number of energy levels. The presented model uses values in the range from 10 to approximately 40. The distribution of energy with respect to these levels can differ from the equilibrium distribution. The kinetic model developed can be employed for arbitrary gaseous mixtures with an arbitrary number of vibrational degrees of freedom for each type of gas. The application of the model to CO2-H2ON2-O2-He mixtures is discussed. The obtained relations can be utilized in a study of the suitability of radiation-related transitional processes, involving the CO2 molecule, for laser applications. It is found that the computational results provided by the model agree very well with experimental data obtained for a CO2 laser. Possibilities for the activation of a 16-micron and 14-micron laser are considered.

  7. Proton transfer pathways, energy landscape, and kinetics in creatine-water systems.

    PubMed

    Ivchenko, Olga; Whittleston, Chris S; Carr, Joanne M; Imhof, Petra; Goerke, Steffen; Bachert, Peter; Wales, David J

    2014-02-27

    We study the exchange processes of the metabolite creatine, which is present in both tumorous and normal tissues and has NH2 and NH groups that can transfer protons to water. Creatine produces chemical exchange saturation transfer (CEST) contrast in magnetic resonance imaging (MRI). The proton transfer pathway from zwitterionic creatine to water is examined using a kinetic transition network constructed from the discrete path sampling approach and an approximate quantum-chemical energy function, employing the self-consistent-charge density-functional tight-binding (SCC-DFTB) method. The resulting potential energy surface is visualized by constructing disconnectivity graphs. The energy landscape consists of two distinct regions corresponding to the zwitterionic creatine structures and deprotonated creatine. The activation energy that characterizes the proton transfer from the creatine NH2 group to water was determined from an Arrhenius fit of rate constants as a function of temperature, obtained from harmonic transition state theory. The result is in reasonable agreement with values obtained in water exchange spectroscopy (WEX) experiments.

  8. Turbulent Flame Speeds and NOx Kinetics of HHC Fuels with Contaminants and High Dilution Levels

    SciTech Connect

    Petersen, Eric; Krejci, Michael; Mathieu, Olivier; Vissotski, Andrew; Ravi, Sankar; Sikes, Travis; Levacque, Anthony; Aul, Christopher; Peterson, Eric

    2011-09-30

    This progress report documents the first year of the project, from October 1, 2010 through September 30, 2011. Laminar flame speeds and ignition delay times have been measured for hydrogen and various compositions of H2/CO (syngas) at elevated pressures and elevated temperatures. Two constant-volume cylindrical vessels were used to visualize the spherical growth of the flame through the use of a schlieren optical setup to measure the laminar flame speed of the mixture. Hydrogen experiments were performed at initial pressures up to 10 atm and initial temperatures up to 443 K. A syngas composition of 50/50 was chosen to demonstrate the effect of carbon monoxide on H2-O2 chemical kinetics at standard temperature and pressures up to 10 atm. All atmospheric mixtures were diluted with standard air, while all elevated-pressure experiments were diluted with a He:O2 of 7:1 to minimize hydrodynamic instabilities. The laminar flame speed measurements of hydrogen and syngas are compared to available literature data over a wide range of equivalence ratios where good agreement can be seen with several data sets. Additionally, an improved chemical kinetics model is shown for all conditions within the current study. The model and the data presented herein agree well, which demonstrates the continual, improved accuracy of the chemical kinetics model. A high-pressure shock tube was used to measure ignition delay times for several baseline compositions of syngas at three pressures across a wide range of temperatures. The compositions of syngas (H2/CO) presented in this study include 80/20, 50/50, 40/60, 20/80, and 10/90, all of which are compared to previously published ignition delay times from a hydrogen-oxygen mixture to demonstrate the effect of carbon monoxide addition. Generally, an increase in carbon monoxide increases the ignition delay time, but there does seem to be a pressure dependency. At low temperatures and

  9. Covalent bonds are created by the drive of electron waves to lower their kinetic energy through expansion

    PubMed Central

    Schmidt, Michael W.; Ivanic, Joseph; Ruedenberg, Klaus

    2014-01-01

    An analysis based on the variation principle shows that in the molecules H2+, H2, B2, C2, N2, O2, F2, covalent bonding is driven by the attenuation of the kinetic energy that results from the delocalization of the electronic wave function. For molecular geometries around the equilibrium distance, two features of the wave function contribute to this delocalization: (i) Superposition of atomic orbitals extends the electronic wave function from one atom to two or more atoms; (ii) intra-atomic contraction of the atomic orbitals further increases the inter-atomic delocalization. The inter-atomic kinetic energy lowering that (perhaps counter-intuitively) is a consequence of the intra-atomic contractions drives these contractions (which per se would increase the energy). Since the contractions necessarily encompass both, the intra-atomic kinetic and potential energy changes (which add to a positive total), the fact that the intra-atomic potential energy change renders the total potential binding energy negative does not alter the fact that it is the kinetic delocalization energy that drives the bond formation. PMID:24880263

  10. Covalent bonds are created by the drive of electron waves to lower their kinetic energy through expansion.

    PubMed

    Schmidt, Michael W; Ivanic, Joseph; Ruedenberg, Klaus

    2014-05-28

    An analysis based on the variation principle shows that in the molecules H2 (+), H2, B2, C2, N2, O2, F2, covalent bonding is driven by the attenuation of the kinetic energy that results from the delocalization of the electronic wave function. For molecular geometries around the equilibrium distance, two features of the wave function contribute to this delocalization: (i) Superposition of atomic orbitals extends the electronic wave function from one atom to two or more atoms; (ii) intra-atomic contraction of the atomic orbitals further increases the inter-atomic delocalization. The inter-atomic kinetic energy lowering that (perhaps counter-intuitively) is a consequence of the intra-atomic contractions drives these contractions (which per se would increase the energy). Since the contractions necessarily encompass both, the intra-atomic kinetic and potential energy changes (which add to a positive total), the fact that the intra-atomic potential energy change renders the total potential binding energy negative does not alter the fact that it is the kinetic delocalization energy that drives the bond formation.

  11. Covalent bonds are created by the drive of electron waves to lower their kinetic energy through expansion

    SciTech Connect

    Schmidt, Michael W; Ivanic, Joseph; Ruedenberg, Klaus

    2014-05-28

    An analysis based on the variation principle shows that in the molecules H2 +, H2, B2, C2, N2, O2, F2, covalent bonding is driven by the attenuation of the kinetic energy that results from the delocalization of the electronic wave function. For molecular geometries around the equilibrium distance, two features of the wave function contribute to this delocalization: (i) Superposition of atomic orbitals extends the electronic wave function from one atom to two or more atoms; (ii) intra-atomic contraction of the atomic orbitals further increases the inter-atomic delocalization. The inter-atomic kinetic energy lowering that (perhaps counter-intuitively) is a consequence of the intra-atomic contractions drives these contractions (which per se would increase the energy). Since the contractions necessarily encompass both, the intra-atomic kinetic and potential energy changes (which add to a positive total), the fact that the intra-atomic potential energy change renders the total potential binding energy negative does not alter the fact that it is the kinetic delocalization energy that drives the bond formation.

  12. Covalent bonds are created by the drive of electron waves to lower their kinetic energy through expansion

    SciTech Connect

    Schmidt, Michael W.; Ruedenberg, Klaus; Ivanic, Joseph

    2014-05-28

    An analysis based on the variation principle shows that in the molecules H{sub 2}{sup +}, H{sub 2}, B{sub 2}, C{sub 2}, N{sub 2}, O{sub 2}, F{sub 2}, covalent bonding is driven by the attenuation of the kinetic energy that results from the delocalization of the electronic wave function. For molecular geometries around the equilibrium distance, two features of the wave function contribute to this delocalization: (i) Superposition of atomic orbitals extends the electronic wave function from one atom to two or more atoms; (ii) intra-atomic contraction of the atomic orbitals further increases the inter-atomic delocalization. The inter-atomic kinetic energy lowering that (perhaps counter-intuitively) is a consequence of the intra-atomic contractions drives these contractions (which per se would increase the energy). Since the contractions necessarily encompass both, the intra-atomic kinetic and potential energy changes (which add to a positive total), the fact that the intra-atomic potential energy change renders the total potential binding energy negative does not alter the fact that it is the kinetic delocalization energy that drives the bond formation.

  13. Intercomparison of high energy neutron personnel dosimeters

    SciTech Connect

    McDonald, J.C.; Akabani, G.; Loesch, R.M.

    1993-03-01

    An intercomparison of high-energy neutron personnel dosimeters was performed to evaluate the uniformity of the response characteristics of typical neutron dosimeters presently in use at US Department of Energy (DOE) accelerator facilities. It was necessary to perform an intercomparison because there are no national or international standards for high-energy neutron dosimetry. The testing that is presently under way for the Department of Energy Laboratory Accreditation Program (DOELAP) is limited to the use of neutron sources that range in energy from about 1 keV to 2 MeV. Therefore, the high-energy neutron dosimeters presently in use at DOE accelerator facilities are not being tested effectively. This intercomparison employed neutrons produced by the {sup 9}Be(p,n){sup 9}B interaction at the University of Washington cyclotron, using 50-MeV protons. The resulting neutron energy spectrum extended to a maximum of approximately 50-MeV, with a mean energy of about 20-MeV. Intercomparison results for currently used dosimeters, including Nuclear Type A (NTA) film, thermoluminescent dosimeter (TLD)-albedo, and track-etch dosimeters (TEDs), indicated a wide variation in response to identical doses of high-energy neutrons. Results of this study will be discussed along with a description of plans for future work.

  14. Shape-memory transformations of NiTi: Minimum-energy pathways between austenite, martensites, and kinetically limited intermediate states

    DOE PAGES

    Zarkevich, N. A.; Johnson, D. D.

    2014-12-24

    NiTi is the most used shape-memory alloy, nonetheless, a lack of understanding remains regarding the associated structures and transitions, including their barriers. Using a generalized solid-state nudge elastic band (GSSNEB) method implemented via density-functional theory, we detail the structural transformations in NiTi relevant to shape memory: those between body-centered orthorhombic (BCO) groundstate and a newly identified stable austenite (“glassy” B2-like) structure, including energy barriers (hysteresis) and intermediate structures (observed as a kinetically limited R-phase), and between martensite variants (BCO orientations). All results are in good agreement with available experiment. We contrast the austenite results to those from the often-assumed, butmore » unstable B2. Furthermore, these high- and low-temperature structures and structural transformations provide much needed atomic-scale detail for transitions responsible for NiTi shape-memory effects.« less

  15. Shape-memory transformations of NiTi: Minimum-energy pathways between austenite, martensites, and kinetically limited intermediate states

    SciTech Connect

    Zarkevich, N. A.; Johnson, D. D.

    2014-12-24

    NiTi is the most used shape-memory alloy, nonetheless, a lack of understanding remains regarding the associated structures and transitions, including their barriers. Using a generalized solid-state nudge elastic band (GSSNEB) method implemented via density-functional theory, we detail the structural transformations in NiTi relevant to shape memory: those between body-centered orthorhombic (BCO) groundstate and a newly identified stable austenite (“glassy” B2-like) structure, including energy barriers (hysteresis) and intermediate structures (observed as a kinetically limited R-phase), and between martensite variants (BCO orientations). All results are in good agreement with available experiment. We contrast the austenite results to those from the often-assumed, but unstable B2. Furthermore, these high- and low-temperature structures and structural transformations provide much needed atomic-scale detail for transitions responsible for NiTi shape-memory effects.

  16. Shape-memory transformations of NiTi: minimum-energy pathways between austenite, martensites, and kinetically limited intermediate states.

    PubMed

    Zarkevich, N A; Johnson, D D

    2014-12-31

    NiTi is the most used shape-memory alloy; nonetheless, a lack of understanding remains regarding the associated structures and transitions, including their barriers. Using a generalized solid-state nudged elastic band method implemented via density-functional theory, we detail the structural transformations in NiTi relevant to shape memory: those between a body-centered orthorhombic (bco) ground state and a newly identified stable austenite ("glassy" B2-like) structure, including energy barriers (hysteresis) and intermediate structures (observed as a kinetically limited R phase), and between martensite variants (bco orientations). All results are in good agreement with available experiment. We contrast the austenite results to those from the often-assumed, but unstable B2. These high- and low-temperature structures and structural transformations provide much needed atomic-scale detail for transitions responsible for NiTi shape-memory effects.

  17. Estimation of Rainfall Kinetic Energy by Rain Intensity and/or Radar Reflectivity Factor

    NASA Astrophysics Data System (ADS)

    Yu, N.; Delrieu, G.; Boudevillain, B.; Hazenberg, P.; Uijlenhoet, R.

    2011-12-01

    This study presents an approach to estimate the rainfall kinetic energy (KE) by rain intensity (R) and radar reflectivity factor (Z) separately, or jointly, on the basis of a one- or two-moment scaled formulation. This formulation considers the raindrop size distribution (DSD) as a combination of bulk rainfall variable(s) (R or/and Z) and an intrinsic distribution g(x), which is in function of the scaled raindrop diameter x. Results from previous studies showed that g(x) remains more or less constant, hence the variability of DSD is mainly explained by the bulk rainfall variable(s). In this study, the Gamma probability density function (pdf) with two parameters is used to model the g(x). Considered the self-consistent relationships between parameters, a robust method is proposed to estimate three climatological g(x), in R-, Z- and RZ-scaled formulation respectively, with a 28-month DSD dataset collected in the Cevennes-Vivarais region, France. Three relationships (KE-R, KE-Z and KE-(R,Z)), which link the observations (R and/or Z) to rainfall kinetic energy (KE), are established based on three climatological g(x). As expected, the combination of R and Z yields a significant improvement of the estimation of KE compared to the single-moment formulations. And Z yields a better performance in KE estimating compared to the KE-R relationship. In terms of the application of these relationships based on real radar reflectivity factors and/or rain gauge measurements, the combination of R and Z yields also the best performance in estimation of KE among the three relationships. Different from the application of the disdrometer data, the performance of the real KE-Z relationship degrades compared to the real KE-R relationship, which is probably due to the sampling error of radar. However, KE estimated by radar possess the advantages in spatialization of kinetic energy over that based on rain gauge stations. This study was supported financially by the HYDRATE project of the

  18. Internal calibration Förster resonance energy transfer assay: a real-time approach for determining protease kinetics.

    PubMed

    Jiang, Ling; Liu, Yan; Song, Yang; Saavedra, Amanda N; Pan, Songqin; Xiang, Wensheng; Liao, Jiayu

    2013-04-08

    Förster resonance energy transfer (FRET) technology has been widely used in biological and biomedical research. This powerful tool can elucidate protein interactions in either a dynamic or steady state. We recently developed a series of FRET-based technologies to determine protein interaction dissociation constant and for use in high-throughput screening assays of SUMOylation. SUMO (small ubiquitin-like modifier) is conjugated to substrates through an enzymatic cascade. This important posttranslational protein modification is critical for multiple biological processes. Sentrin/SUMO-specific proteases (SENPs) act as endopeptidases to process the pre-SUMO or as isopeptidases to deconjugate SUMO from its substrate. Here, we describe a novel quantitative FRET-based protease assay for determining the kinetics of SENP1. Our strategy is based on the quantitative analysis and differentiation of fluorescent emission signals at the FRET acceptor emission wavelengths. Those fluorescent emission signals consist of three components: the FRET signal and the fluorescent emissions of donor (CyPet) and acceptor (YPet). Unlike our previous method in which donor and acceptor direct emissions were excluded by standard curves, the three fluorescent emissions were determined quantitatively during the SENP digestion process from onesample. New mathematical algorithms were developed to determine digested substrate concentrations directly from the FRET signal and donor/acceptor direct emissions. The kinetic parameters, kcat, KM, and catalytic efficiency (kcat/KM) of SENP1 catalytic domain for pre-SUMO1/2/3 were derived. Importantly, the general principles of this new quantitative methodology of FRET-based protease kinetic determinations can be applied to other proteases in a robust and systems biology approach.

  19. Growth kinetics of forsterite reaction rims at high-pressure

    NASA Astrophysics Data System (ADS)

    Nishihara, Yu; Maruyama, Genta; Nishi, Masayuki

    2016-08-01

    Growth kinetics of forsterite (Fo) reaction rims between periclase (Per) and enstatite (En) were studied experimentally at pressure (P) and temperature (T) conditions of 3.0-11.1 GPa and 1473-1873 K, respectively. Pt markers originally placed at the Per-En interface were always observed at the Per-Fo interface, which indicates that Mg and O are the diffusing species in Fo rim growth (Mg-O coupled diffusion). The presence of some En inclusions in Fo grains and the growth rate of the Fo rim suggests that grain boundary diffusion is dominant rather than lattice diffusion. Considering the very fast grain boundary diffusion of O in olivine, the Mg-O coupled grain boundary diffusion in Fo is deduced to be rate-limited by the diffusivity of Mg. Based on an analysis of data collected under dry conditions, the product of the Mg grain boundary diffusion coefficient (Dgb) and the effective grain boundary width (δ) was determined to be δDgb = δDgb,0exp[-(E∗ + PV∗)/RT] with δDgb,0 = 10-9.68 ± 1.51 m3/s, E∗ = 379 ± 44 kJ/mol and V∗ = -1.9 ± 1.4 cm3/mol. Our results, combined with previously reported data on Mg lattice diffusion in Fo, suggest that for Mg, the significance of grain boundary diffusion increases with depth in the Earth's upper mantle, although lattice diffusion is still dominant for typical mantle grain sizes of 1-10 mm.

  20. A subsynoptic-scale kinetic energy study of the Red River Valley tornado outbreak (AVE-SESAME 1)

    NASA Technical Reports Server (NTRS)

    Jedlovec, G. J.; Fuelberg, H. E.

    1981-01-01

    The subsynoptis-scale kinetic energy balance during the Red River Valley tornado outbreak is presented in order to diagnose storm environment interactions. Area-time averaged energetics indicate that horizontal flux convergence provides the major energy source to the region, while cross contour flow provides the greatest sink. Maximum energy variability is found in the upper levels in association with jet stream activity. Area averaged energetics at individual observation times show that the energy balance near times of maximum storm activity differs considerably from that of the remaining periods. The local kinetic energy balance over Oklahoma during the formation of a limited jet streak receives special attention. Cross contour production of energy is the dominant local source for jet development. Intense convection producing the Red River Valley tornadoes may have contributed to this local development by modifying the surrounding environment.

  1. High Energy Electron Detection with ATIC

    NASA Technical Reports Server (NTRS)

    Chang, J.; Schmidt, W. K. H.; Adams, James H., Jr.; Ahn, H.; Ampe, J.; Whitaker, Ann F. (Technical Monitor)

    2001-01-01

    The ATIC (Advanced Thin Ionization Calorimeter) balloon-borne ionization calorimeter is well suited to record and identify high energy cosmic ray electrons. The instrument was exposed to high-energy beams at CERN H2 bean-dine in September of 1999. We have simulated the performance of the instrument, and compare the simulations with actual high energy electron exposures at the CERN accelerator. Simulations and measurements do not compare exactly, in detail, but overall the simulations have predicted actual measured behavior quite well.

  2. On the Future High Energy Colliders

    SciTech Connect

    Shiltsev, Vladimir

    2015-09-28

    High energy particle colliders have been in the forefront of particle physics for more than three decades. At present the near term US, European and international strategies of the particle physics community are centered on full exploitation of the physics potential of the Large Hadron Collider (LHC) through its high-luminosity upgrade (HL-LHC). A number of the next generation collider facilities have been proposed and are currently under consideration for the medium and far-future of accelerator-based high energy physics. In this paper we offer a uniform approach to evaluation of various accelerators based on the feasibility of their energy reach, performance potential and cost range.

  3. Practical neutron dosimetry at high energies

    SciTech Connect

    McCaslin, J.B.; Thomas, R.H.

    1980-10-01

    Dosimetry at high energy particle accelerators is discussed with emphasis on physical measurements which define the radiation environment and provide an immutable basis for the derivation of any quantities subsequently required for risk evaluation. Results of inter-laboratory dosimetric comparisons are reviewed and it is concluded that a well-supported systematic program is needed which would make possible detailed evaluations and inter-comparisons of instruments and techniques in well characterized high energy radiation fields. High-energy dosimetry is so coupled with radiation transport that it is clear their study should proceed concurrently.

  4. Computing in high-energy physics

    DOE PAGES

    Mount, Richard P.

    2016-05-31

    I present a very personalized journey through more than three decades of computing for experimental high-energy physics, pointing out the enduring lessons that I learned. This is followed by a vision of how the computing environment will evolve in the coming ten years and the technical challenges that this will bring. I then address the scale and cost of high-energy physics software and examine the many current and future challenges, particularly those of management, funding and software-lifecycle management. Lastly, I describe recent developments aimed at improving the overall coherence of high-energy physics software.

  5. High Energy Physics Research at Louisiana Tech

    SciTech Connect

    Sawyer, Lee; Greenwood, Zeno; Wobisch, Marcus

    2013-06-28

    The goal of this project was to create, maintain, and strengthen a world-class, nationally and internationally recognized experimental high energy physics group at Louisiana Tech University, focusing on research at the energy frontier of collider-based particle physics, first on the DØ experiment and then with the ATLAS experiment, and providing leadership within the US high energy physics community in the areas of jet physics, top quark and charged Higgs decays involving tau leptons, as well as developing leadership in high performance computing.

  6. New accelerators in high-energy physics

    SciTech Connect

    Blewett, J.P.

    1982-01-01

    First, I should like to mention a few new ideas that have appeared during the last few years in the accelerator field. A couple are of importance in the design of injectors, usually linear accelerators, for high-energy machines. Then I shall review some of the somewhat sensational accelerator projects, now in operation, under construction or just being proposed. Finally, I propose to mention a few applications of high-energy accelerators in fields other than high-energy physics. I realize that this is a digression from my title but I hope that you will find it interesting.

  7. High-energy facility development plan

    NASA Technical Reports Server (NTRS)

    Walker, Arthur B. C., Jr.; Roberts, W. T.; Dabbs, J. R.

    1988-01-01

    Approaches to the deployment of instruments for the study of high-energy solar emissions alone or in conjunction with other solar instruments are considered. The Space Station has been identified as the preferred mode for the deployment of the Advanced Solar Observatory, and it is suggested that a proposed High-Energy Facility could be on a coorbiting platform. The implementation plan for the High-Energy Facility involves the definition of the interface structures required to mount the facility instruments to the Space Station and the development of hard X-ray and gamma-ray imaging, spectroscopic, and polarimetric instruments.

  8. Inversion vibration of PH3+(X~ 2A2'') studied by zero kinetic energy photoelectron spectroscopy

    NASA Astrophysics Data System (ADS)

    Yang, Jie; Li, Juan; Hao, Yusong; Zhou, Chang; Mo, Yuxiang

    2006-08-01

    We report the first rotationally resolved spectroscopic studies on PH3+(X˜A2″2) using zero kinetic energy photoelectron spectroscopy and coherent VUV radiation. The spectra about 8000cm-1 above the ground vibrational state of PH3+(X˜A2″2) have been recorded. We observed the vibrational energy level splittings of PH3+(X˜A2″2) due to the tunneling effect in the inversion (symmetric bending) vibration (ν2+). The energy splitting for the first inversion vibrational state (0+/0-) is 5.8cm-1. The inversion vibrational energy levels, rotational constants, and adiabatic ionization energies (IEs) for ν2+=0-16 have been determined. The bond angles between the neighboring P-H bonds and the P-H bond lengths are also obtained using the experimentally determined rotational constants. With the increasing of the inversion vibrational excitations (ν2+), the bond lengths (P-H) increase a little and the bond angles (H-P-H) decrease a lot. The inversion vibrational energy levels have also been calculated by using one dimensional potential model and the results are in good agreement with the experimental data for the first several vibrational levels. In addition to inversion vibration, we also observed firstly the other two vibrational modes: the symmetric P-H stretching vibration (ν1+) and the degenerate bending vibration (ν4+). The fundamental frequencies for ν1+ and ν4+ are 2461.6 (±2) and 1043.9 (±2)cm-1, respectively. The first IE for PH3 was determined as 79670.9 (±1)cm-1.

  9. Characterization of the relation between energy landscape and the time evolution of complex materials using kinetic ART

    NASA Astrophysics Data System (ADS)

    N'tsouaglo, Kokou; Joly, Jean-Francois; Beland, Laurent; Brommer, Peter; Mousseau, Normand

    2013-03-01

    In the last two decades, there has been a considerable interest in the development of accelerated numerical methods for sampling the energy landscape of complex materials. Many of these methods are based on the kinetic Monte Carlo (KMC) algorithm introduced 40 years ago. This is the case of kinetic ART, for example, which uses a very efficient transition-state searching method, ART nouveau, coupled with a topological tool, NAUTY, to offer an off-lattice KMC method with on-the-fly catalog building to study complex systems, such as ion-bombarded and amorphous materials, on timescales of a second or more. Looking at two systems, vacancy aggregation in Fe and energy relaxation in ion-bombarded c-Si, we characterize the changes in the energy landscape and the relation to its time evolution with kinetic ART and its correspondence with the well-known Bell-Evans-Polanyi principle used in chemistry.

  10. Note: Proton microbeam formation with continuously variable kinetic energy using a compact system for three-dimensional proton beam writing

    SciTech Connect

    Ohkubo, T. Ishii, Y.

    2015-03-15

    A compact focused gaseous ion beam system has been developed to form proton microbeams of a few hundreds of keV with a penetration depth of micrometer range in 3-dimensional proton beam writing. Proton microbeams with kinetic energies of 100-140 keV were experimentally formed on the same point at a constant ratio of the kinetic energy of the object side to that of the image side. The experimental results indicate that the beam diameters were measured to be almost constant at approximately 6 μm at the same point with the kinetic energy range. These characteristics of the system were experimentally and numerically demonstrated to be maintained as long as the ratio was constant.

  11. The effects of divergent and nondivergent winds on the kinetic energy budget of a mid-latitude cyclone - A case study

    NASA Technical Reports Server (NTRS)

    Chen, T.-C.; Alpert, J. C.; Schlatter, T. W.

    1978-01-01

    The magnitude of the divergent component of the wind is relatively small compared to that of the nondivergent component in large-scale atmospheric flows; nevertheless, it plays an important role in the case of explosive cyclogenesis examined here. The kinetic energy budget for the life cycle of an intense, developing cyclone over North America is calculated. The principal kinetic energy source is the net horizontal transport across the boundaries of the region enclosing the cyclone. By investigating the relative importance of the divergent and nondivergent wind components in the kinetic energy budget, it was found, as expected, that neglecting the divergent wind component in calculating the magnitude of the kinetic energy is of little consequence, but that the horizontal flux convergence and generation of kinetic energy depend crucially upon the divergent component. Modification of the divergent wind component can result in significant changes in the kinetic energy budget of the synoptic system.

  12. High Energy Flywheel Containment Evaluation

    NASA Technical Reports Server (NTRS)

    Colozza, Anthony J.; Trase, Larry (Technical Monitor)

    2000-01-01

    A flywheel testing facility is being constructed at the NASA Glenn Research Center. This facility is to be used for life cycle testing of various flywheel rotors. The lifecycle testing consists of spinning a rotor from a low rpm (approx. 20,000 ) to a high rpm (approx. 60,000) and then back to the low rpm. This spin cycle will model that which the rotor will see during use. To simulate the lifetime of the rotor, the spin cycle will be performed tens of thousands of times. A typical life cycle spin test is expected to last six months. During this time the rotor will be spun through a cycle every five minutes. The test will run continuously for the six month period barring a flywheel failure. Since it is not reasonable to have the surrounding area evacuated of personnel for the duration of the testing, the flywheel facility has to be designed to withstand a flywheel rotor failure and insure that there is no danger to any personnel in the adjacent buildings or surrounding areas. In order to determine if the facility can safely contain a flywheel rotor failure an analysis of the facility in conjunction with possible flywheel failure modes was performed. This analysis is intended as a worst case evaluation of the burst liner and vacuum tank's ability to contain a failure. The test chamber consists of a cylindrical stainless steel vacuum tank, two outer steel containment rings, and a stainless steel burst liner. The stainless steel used is annealed 302, which has an ultimate strength of 620 MPa (90,000 psi). A diagram of the vacuum tank configuration is shown. The vacuum tank and air turbine will be located below ground in a pit. The tank is secured in the pit with 0.3 m (12 in.) of cement along the base and the remaining portion of the tank is surrounded by gravel up to the access ports. A 590 kg (1300 lb.) bulkhead is placed on top of the pit during operation and the complete facility is housed within a concrete structure which has 7.5 cm (3 in.) thick walls. A cutaway

  13. Precision Crystal Calorimeters in High Energy Physics

    ScienceCinema

    Ren-Yuan Zhu

    2016-07-12

    Precision crystal calorimeters traditionally play an important role in high energy physics experiments. In the last two decades, it faces a challenge to maintain its precision in a hostile radiation environment. This paper reviews the performance of crystal calorimeters constructed for high energy physics experiments and the progress achieved in understanding crystal’s radiation damage as well as in developing high quality scintillating crystals for particle physics. Potential applications of new generation scintillating crystals of high density and high light yield, such as LSO and LYSO, in particle physics experiments is also discussed.

  14. Energy resolution and efficiency of phonon-mediated kinetic inductance detectors for light detection

    NASA Astrophysics Data System (ADS)

    Cardani, L.; Colantoni, I.; Cruciani, A.; Di Domizio, S.; Vignati, M.; Bellini, F.; Casali, N.; Castellano, M. G.; Coppolecchia, A.; Cosmelli, C.; Tomei, C.

    2015-08-01

    The development of sensitive cryogenic light detectors is of primary interest for bolometric experiments searching for rare events like dark matter interactions or neutrino-less double beta decay. Thanks to their good energy resolution and the natural multiplexed read-out, Kinetic Inductance Detectors (KIDs) are particularly suitable for this purpose. To efficiently couple KIDs-based light detectors to the large crystals used by the most advanced bolometric detectors, active surfaces of several cm2 are needed. For this reason, we are developing phonon-mediated detectors. In this paper, we present the results obtained with a prototype consisting of four 40 nm thick aluminum resonators patterned on a 2 × 2 cm2 silicon chip, and calibrated with optical pulses and X-rays. The detector features a noise resolution σE = 154 ± 7 eV and an (18 ± 2)% efficiency.

  15. Aspects of the Eckart frame ro-vibrational kinetic energy operator

    NASA Astrophysics Data System (ADS)

    Szalay, Viktor

    2015-08-01

    A most decisive part of developing the Eckart frame ro-vibrational kinetic energy operator (KEO) in terms of curvilinear internal coordinates is the introduction of vibrational displacements obeying the Eckart conditions. It is examined here, how such displacements may be constructed by orthogonal and nonorthogonal transformations, and how they can be employed in developing the KEO. In particular, it is shown analytically, by term by term comparison, that the Eckart KEOs obtained by employing Pickett's method and the gateway Hamiltonian method are equivalent. That is, although it may appear in the form of very different expressions, the general, exact ro-vibrational Eckart frame KEO is unique. As side result, it has been shown that the simple formula of the pseudo-potential derived by Watson for the exact KEO given in normal coordinates applies to any Eckart frame KEO, irrespective of the choice of the vibrational coordinates.

  16. Radiation processing with high-energy X-rays

    NASA Astrophysics Data System (ADS)

    Cleland, Marshall R.; Stichelbaut, Frédéric

    2013-03-01

    The radiation processing of materials and commercial products with high-energy X-rays, which are also identified by the German term bremsstrahlung, can produce beneficial changes that are similar to those obtained by irradiation with nuclear gamma rays emitted by cobalt-60 sources. Both X-rays and gamma rays are electromagnetic radiations with short wavelengths and high photon energies that can stimulate chemical reactions by creating ions and free radicals in irradiated materials. Nevertheless, there are some physical differences in these energy sources that can influence the choice for practical applications. The English translation of bremsstrahlung is braking radiatiorn or deceleration radiation. It is produced when energetic electrons are deflected by the strong electric field near an atomic nucleus. The efficiency for producing this kind of electromagnetic energy increases with the kinetic energy of the electrons and the atomic number of the target material. The energy spectrum of the emitted X-ray photons is very broad and extends up to the maximum energy of the incident electrons. In contrast, a cobalt-60 nucleus emits two gamma rays simultaneously, which have well-defined energies. Another significant difference is the angular distribution of the radiation. Nuclear gamma rays are emitted in all directions, but high-energy bremsstrahlung photons are concentrated in the direction of the incident electrons when they strike the target material. This property enables an X-ray processing facility to be more compact than a gamma-ray processing facility with similar throughput capacity, and it increases the penetration and the efficiency for absorbing the emitted X-ray energy in the irradiated material. Recent increases in the electron energy and the electron beam power from modern industrial accelerators have increased the throughput rates in X-ray processing facilities, so that this irradiation method is now economically competitive with large cobalt-60

  17. Design of specially adapted reactive coordinates to economically compute potential and kinetic energy operators including geometry relaxation

    NASA Astrophysics Data System (ADS)

    Thallmair, Sebastian; Roos, Matthias K.; de Vivie-Riedle, Regina

    2016-06-01

    Quantum dynamics simulations require prior knowledge of the potential energy surface as well as the kinetic energy operator. Typically, they are evaluated in a low-dimensional subspace of the full configuration space of the molecule as its dimensionality increases proportional to the number of atoms. This entails the challenge to find the most suitable subspace. We present an approach to design specially adapted reactive coordinates spanning this subspace. In addition to the essential geometric changes, these coordinates take into account the relaxation of the non-reactive coordinates without the necessity of performing geometry optimizations at each grid point. The method is demonstrated for an ultrafast photoinduced bond cleavage in a commonly used organic precursor for the generation of electrophiles. The potential energy surfaces for the reaction as well as the Wilson G-matrix as part of the kinetic energy operator are shown for a complex chemical reaction, both including the relaxation of the non-reactive coordinates on equal footing. A microscopic interpretation of the shape of the G-matrix elements allows to analyze the impact of the non-reactive coordinates on the kinetic energy operator. Additionally, we compare quantum dynamics simulations with and without the relaxation of the non-reactive coordinates included in the kinetic energy operator to demonstrate its influence.

  18. Kinetic and electron-electron energies for convex sums of ground state densities with degeneracies and fractional electron number

    SciTech Connect

    Levy, Mel E-mail: mlevy@tulane.edu; Anderson, James S. M.; Zadeh, Farnaz Heidar; Ayers, Paul W. E-mail: mlevy@tulane.edu

    2014-05-14

    Properties of exact density functionals provide useful constraints for the development of new approximate functionals. This paper focuses on convex sums of ground-level densities. It is observed that the electronic kinetic energy of a convex sum of degenerate ground-level densities is equal to the convex sum of the kinetic energies of the individual degenerate densities. (The same type of relationship holds also for the electron-electron repulsion energy.) This extends a known property of the Levy-Valone Ensemble Constrained-Search and the Lieb Legendre-Transform refomulations of the Hohenberg-Kohn functional to the individual components of the functional. Moreover, we observe that the kinetic and electron-repulsion results also apply to densities with fractional electron number (even if there are no degeneracies), and we close with an analogous point-wise property involving the external potential. Examples where different degenerate states have different kinetic energy and electron-nuclear attraction energy are given; consequently, individual components of the ground state electronic energy can change abruptly when the molecular geometry changes. These discontinuities are predicted to be ubiquitous at conical intersections, complicating the development of universally applicable density-functional approximations.

  19. Design of specially adapted reactive coordinates to economically compute potential and kinetic energy operators including geometry relaxation.

    PubMed

    Thallmair, Sebastian; Roos, Matthias K; de Vivie-Riedle, Regina

    2016-06-21

    Quantum dynamics simulations require prior knowledge of the potential energy surface as well as the kinetic energy operator. Typically, they are evaluated in a low-dimensional subspace of the full configuration space of the molecule as its dimensionality increases proportional to the number of atoms. This entails the challenge to find the most suitable subspace. We present an approach to design specially adapted reactive coordinates spanning this subspace. In addition to the essential geometric changes, these coordinates take into account the relaxation of the non-reactive coordinates without the necessity of performing geometry optimizations at each grid point. The method is demonstrated for an ultrafast photoinduced bond cleavage in a commonly used organic precursor for the generation of electrophiles. The potential energy surfaces for the reaction as well as the Wilson G-matrix as part of the kinetic energy operator are shown for a complex chemical reaction, both including the relaxation of the non-reactive coordinates on equal footing. A microscopic interpretation of the shape of the G-matrix elements allows to analyze the impact of the non-reactive coordinates on the kinetic energy operator. Additionally, we compare quantum dynamics simulations with and without the relaxation of the non-reactive coordinates included in the kinetic energy operator to demonstrate its influence.

  20. Dynamic kinetic energy potential for orbital-free density functional theory.

    PubMed

    Neuhauser, Daniel; Pistinner, Shlomo; Coomar, Arunima; Zhang, Xu; Lu, Gang

    2011-04-14

    A dynamic kinetic energy potential (DKEP) is developed for time-dependent orbital-free (TDOF) density function theory applications. This potential is constructed to affect only the dynamical (ω ≠ 0) response of an orbital-free electronic system. It aims at making the orbital-free simulation respond in the same way as that of a noninteracting homogenous electron gas (HEG), as required by a correct kinetic energy, therefore enabling extension of the success of orbital-free density functional theory in the static case (e.g., for embedding and description of processes in bulk materials) to dynamic processes. The potential is constructed by expansions of terms, each of which necessitates only simple time evolution (concurrent with the TDOF evolution) and a spatial convolution at each time-step. With 14 such terms a good fit is obtained to the response of the HEG at a large range of frequencies, wavevectors, and densities. The method is demonstrated for simple jellium spheres, approximating Na(9)(+) and Na(65)(+) clusters. It is applicable both to small and large (even ultralarge) excitations and the results converge (i.e., do not blow up) as a function of time. An extension to iterative frequency-resolved extraction is briefly outlined, as well as possibly numerically simpler expansions. The approach could also be extended to fit, instead of the HEG susceptibility, either an experimental susceptibility or a theoretically derived one for a non-HEG system. The DKEP potential should be a powerful tool for embedding a dynamical system described by a more accurate method (such as time-dependent density functional theory, TDDFT) in a large background described by TDOF with a DKEP potential. The type of expansions used and envisioned should be useful for other approaches, such as memory functionals in TDDFT. Finally, an appendix details the formal connection between TDOF and TDDFT.

  1. Vertical Kinetic Energy of Internal Gravity Waves and Turbulent Dissipation in the Ocean

    NASA Astrophysics Data System (ADS)

    Thurnherr, Andreas; St. Laurent, Louis; Richards, Kelvin; Toole, John

    2015-04-01

    Internal gravity waves in the ocean are closely associated with turbulence and mixing. The relationship between IGWs and turbulence is usually interpreted in the framework of the Garret-Munk model, a prescription for open-ocean internal-wave energy as a function of several environmental parameters. Here, we evaluate the relationship between internal-wave energy and turbulence directly, using more than 250 joint profiles of turbulent dissipation from microstructure, and vertical velocity from CTD/LADCP measurements. The observations include profiles from a wide variety of dynamical regimes and latitudes between the equator and 60°. In most profiles, finescale vertical kinetic energy (VKE) varies as kz-2, where kz is the vertical wave number. Scaling VKE with dissipation collapses all off-equatorial data-set average spectra to within √2 or better. The dissipation-normalized spectrum can be interpreted as a new single-parameter (dissipation) model for internal-wave VKE, which is considerably simpler and more accurate than the corresponding Garrett-Munk model.

  2. Scale-dependent distribution of kinetic energy from surface drifters in the Gulf of Mexico

    NASA Astrophysics Data System (ADS)

    Balwada, Dhruv; LaCasce, Joseph H.; Speer, Kevin G.

    2016-10-01

    The scale-dependent distribution of kinetic energy is probed at the surface in the Gulf of Mexico using surface drifters from the Grand Lagrangian Deployment (GLAD) experiment. The second-order velocity structure function and its decomposition into rotational and divergent components are examined. The results reveal that the divergent component, compared to the rotational component, dominates at scales below 5 km, and the pattern is reversed at larger scales. The divergent component has a slope near 2/3 below 5 km, similar to an energy cascade range (k-5/3). The third-order velocity structure function at scales below 5 km is negative and implies a forward cascade of energy to smaller scales. The rotational component has a steeper slope, roughly 1.5, from scales of 5 km up to the deformation radius. This is similar to a 2-D enstrophy cascade, although the slope is shallower than the predicted 2. There is a brief 2/3 range from the deformation radius to 200 km, suggestive of a 2-D inverse cascade.

  3. Kinetic theory of binary particles with unequal mean velocities and non-equipartition energies

    NASA Astrophysics Data System (ADS)

    Chen, Yanpei; Mei, Yifeng; Wang, Wei

    2017-03-01

    The hydrodynamic conservation equations and constitutive relations for a binary granular mixture composed of smooth, nearly elastic spheres with non-equipartition energies and different mean velocities are derived. This research is aimed to build three-dimensional kinetic theory to characterize the behaviors of two species of particles suffering different forces. The standard Enskog method is employed assuming a Maxwell velocity distribution for each species of particles. The collision components of the stress tensor and the other parameters are calculated from the zeroth- and first-order approximation. Our results demonstrate that three factors, namely the differences between two granular masses, temperatures and mean velocities all play important roles in the stress-strain relation of the binary mixture, indicating that the assumption of energy equipartition and the same mean velocity may not be acceptable. The collision frequency and the solid viscosity increase monotonously with each granular temperature. The zeroth-order approximation to the energy dissipation varies greatly with the mean velocities of both species of spheres, reaching its peak value at the maximum of their relative velocity.

  4. Correcting the Wingate test for changes in kinetic energy of the ergometer flywheel.

    PubMed

    Bassett, D R

    1989-12-01

    The rotating flywheel of a cycle ergometer possesses kinetic energy (KE) by virtue of its rotation about the center of mass. The energy released as the flywheel velocity (FV) decreases during the course of a Wingate test is used to accomplish mechanical work. The subject should not be "credited" with this work since the energy storage occurred prior to the start of the 30-s test. The total KE (KE-total) in the flywheel of a Monark ergometer was determined using the formula KEtotal = 1/2 I omega 2. The KE available to do work (KEwork) was measured by loading the ergometer with 1 Kp (9.8 N), spinning it at predetermined rates, and observing the number of revolutions completed as it coasted to a stop. The difference between KEtotal and KE-work was attributable to friction. The mechanical power supplied by the flywheel in any 5-s period of the Wingate test was found to be: Flywheel power (W) = .00185 (FVstart2-FVend2)/5s where FV is expressed in rpm. This indicates that Wingate test scores should be corrected by subtracting the flywheel power output from the total power output. The correction lowers peak power (PP), mean power (MP), and fatigue index (% fatigue) by 6.2%, 3.0%, and 6.6% in active male subjects (P less than 0.05).

  5. The energy landscape, folding pathways and the kinetics of a knotted protein.

    PubMed

    Prentiss, Michael C; Wales, David J; Wolynes, Peter G

    2010-07-01

    The folding pathway and rate coefficients of the folding of a knotted protein are calculated for a potential energy function with minimal energetic frustration. A kinetic transition network is constructed using the discrete path sampling approach, and the resulting potential energy surface is visualized by constructing disconnectivity graphs. Owing to topological constraints, the low-lying portion of the landscape consists of three distinct regions, corresponding to the native knotted state and to configurations where either the N or C terminus is not yet folded into the knot. The fastest folding pathways from denatured states exhibit early formation of the N terminus portion of the knot and a rate-determining step where the C terminus is incorporated. The low-lying minima with the N terminus knotted and the C terminus free therefore constitute an off-pathway intermediate for this model. The insertion of both the N and C termini into the knot occurs late in the folding process, creating large energy barriers that are the rate limiting steps in the folding process. When compared to other protein folding proteins of a similar length, this system folds over six orders of magnitude more slowly.

  6. The kinetic and available potential energy budget of a winter extratropical cyclone system

    NASA Technical Reports Server (NTRS)

    Smith, P. J.; Dare, P. M.

    1986-01-01

    The energy budget of an extratropical cyclone system which traversed North America and intensified through the period January 9-11, 1975 is presented. The objectives of the study are: (1) to document the complete energy budget of a significant winter cyclone event, and (2) to comment on the significance of latent heat release (LHR) in the cyclone's evolution. Results reveal an overall increase in both kinetic (K) and available potential energy (A). K increases are accounted for by boundary flux convergence of K, while A increases are due to generation by LHR and K to A conversion. In addition, the general A increase is accompanied by a 24 h oscillation that is explained largely by the flux quantity in the A budget equation and is correlated with a similar fluctuation in the K to A conversion. LHR does not appear to be critical in the development of this cyclone system. Rather, LHR acts to increase the intensity of the event. It is hypothesized that the direct influence that LHR had on the deepening cyclone's reduced mass was augmented by an indirect influence, in which pre-existing dry dynamical forcing was enhanced by diabatic heating, thus leading to accelerated cyclone development at a later time.

  7. The evolution of high energy accelerators

    SciTech Connect

    Courant, E.D.

    1989-10-01

    In this lecture I would like to trace how high energy particle accelerators have grown from tools used for esoteric small-scale experiments to gigantic projects being hotly debated in Congress as well as in the scientific community.

  8. Research in High Energy Physics. Final report

    SciTech Connect

    Conway, John S.

    2013-08-09

    This final report details the work done from January 2010 until April 2013 in the area of experimental and theoretical high energy particle physics and cosmology at the University of California, Davis.

  9. Physics at high energy photon photon colliders

    SciTech Connect

    Chanowitz, M.S.

    1994-06-01

    I review the physic prospects for high energy photon photon colliders, emphasizing results presented at the LBL Gamma Gamma Collider Workshop. Advantages and difficulties are reported for studies of QCD, the electroweak gauge sector, supersymmetry, and electroweak symmetry breaking.

  10. High Energy Astrophysics Research and Programmatic Support

    NASA Technical Reports Server (NTRS)

    Angellini, L.

    1994-01-01

    This report reviews activities performed by members of the USRA contract team during the three months of the reporting period. Activities take place at the Goddard Space Flight Center, within the Laboratory for High Energy Astrophysics.

  11. Junior High Gets Energy Efficient VAV System

    ERIC Educational Resources Information Center

    Modern Schools, 1977

    1977-01-01

    Minnesota's Isanti Junior High, designed with an energy efficient variable air volume system, is an innovative school selected for display at the 1977 Exhibition of School Architecture in Las Vegas. (Author/MLF)

  12. High efficiency flat plate solar energy collector

    SciTech Connect

    Butler, R. F.

    1985-04-30

    A concentrating flat plate collector for the high efficiency collection of solar energy. Through an arrangement of reflector elements, incoming solar radiation, either directly or after reflection from the reflector elements, impinges upon both surfaces of a collector element.

  13. Amplification of a fast wave by extracting both the kinetic energy and electrostatic potential energy of a large-orbit relativistic electron beam in a coaxial electrostatic wiggler

    SciTech Connect

    Zhang Shichang

    2010-05-15

    Nonlinear model and simulation technique of the interaction and energy transfer between a fast wave and a large-orbit relativistic electron beam in a coaxial electrostatic wiggler are presented. Unlike the situations in a magnetostatic-wiggler free-electron laser (MWFEL) and in an electron cyclotron maser (ECM), the electrostatic potential of the electrons plays an important role and participates in the energy exchange between the wave and the electron beam. Compared to MWFEL and ECM, the coaxial electrostatic-wiggler configuration has a distinguishing peculiarity that besides the electron-beam's kinetic energy, its electrostatic potential energy can be effectively transferred to the fast wave. Simulation shows that wave could be amplified with ultrahigh gain by extracting both the kinetic energy and electrostatic potential energy of the electron beam.

  14. Blast Pressures Induced by the Impact of Kinetic Energy Penetrators on Steel Targets in an Enclosed Range.

    DTIC Science & Technology

    1981-02-01

    heat of detonation of pentolite is Sl k.J/g, so the kinetic energy of the tungsten penetrators is equal to the heat of detonation of...the heat of detonation of pentolite, 5.11 kJ/g. Then the scaled distance curves 3 can be used to predict blast pressure at the instrumented position for...kinetic and chemical energy is 11.8 MJ which equals the heat of detonation of 2.3 kg of pentolite. This would produce a reflected blast pressure of

  15. Single-particle kinetic energy in density-functional theory: Harmonic confinement in two and three dimensions

    SciTech Connect

    March, N. H.

    2006-04-15

    Using the known perturbation series for the idempotent Dirac density matrix in powers of a given one-body potential V(r), Stoddart and March (SM) generated a corresponding series for the kinetic energy density. While the general term of the SM series is known, a summation has not been achieved to date. A contribution to solve this problem is made here by exhibiting an explicit form of the above kinetic energy density for Fermions filling an arbitrary number of closed shells, when the confinement is harmonic. This example is of considerable current interest because of ongoing experiments on ultracold atomic gases of Fermions.

  16. Kinetics of charged particles in a high-voltage gas discharge in a nonuniform electrostatic field

    NASA Astrophysics Data System (ADS)

    Kolpakov, V. A.; Krichevskii, S. V.; Markushin, M. A.

    2017-01-01

    A high-voltage gas discharge is of interest as a possible means of generating directed flows of low-temperature plasma in the off-electrode space distinguished by its original features [1-4]. We propose a model for calculating the trajectories of charges particles in a high-voltage gas discharge in nitrogen at a pressure of 0.15 Torr existing in a nonuniform electrostatic field and the strength of this field. Based on the results of our calculations, we supplement and refine the extensive experimental data concerning the investigation of such a discharge published in [1, 2, 5-8]; good agreement between the theory and experiment has been achieved. The discharge burning is initiated and maintained through bulk electron-impact ionization and ion-electron emission. We have determined the sizes of the cathode surface regions responsible for these processes, including the sizes of the axial zone involved in the discharge generation. The main effect determining the kinetics of charged particles consists in a sharp decrease in the strength of the field under consideration outside the interelectrode space, which allows a free motion of charges with specific energies and trajectories to be generated in it. The simulation results confirm that complex electrode systems that allow directed plasma flows to be generated at a discharge current of hundreds or thousands of milliamperes and a voltage on the electrodes of 0.3-1 kV can be implemented in practice [3, 9, 10].

  17. Digitial readout for microwave kinetic inductance detectors and applications in high time resolution astronomy

    NASA Astrophysics Data System (ADS)

    Strader, Matthew James

    This dissertation spans two topics relating to optical to near-infrared astronomical cameras built around Microwave Kinetic Inductance Detectors (MKIDs). The first topic is the development of a digital readout system for 10- to 30-kilopixel arrays of MKIDs. MKIDs are superconducting detectors that can detect individual photons with a wide range of wavelengths with high time resolution (SI{2}{micro s}) and low energy resolution. The advantage of MKIDs over other low temperature detectors with similar capabilities is that it is relatively straightforward to multiplex MKIDs into large arrays. All the complexity of readout is in room temperature electronics. This work discusses the implementation and programming of these electronics. The second part of this work demonstrates the capabilities of the prototype optical and near-infrared MKID instrument with observations of pulsars. Detecting optical pulsations in these objects require high time resolution and low noise. The discovery of a correlation between the brightness of optical pulses from the Crab pulsar and the time of arrival of coincident giant radio pulses is presented. The search for optical pulses from a millisecond pulsar J0337+1715 is discussed along with a new upper limit on the brightness of its optical pulses.

  18. High to ultra-high power electrical energy storage.

    PubMed

    Sherrill, Stefanie A; Banerjee, Parag; Rubloff, Gary W; Lee, Sang Bok

    2011-12-14

    High power electrical energy storage systems are becoming critical devices for advanced energy storage technology. This is true in part due to their high rate capabilities and moderate energy densities which allow them to capture power efficiently from evanescent, renewable energy sources. High power systems include both electrochemical capacitors and electrostatic capacitors. These devices have fast charging and discharging rates, supplying energy within seconds or less. Recent research has focused on increasing power and energy density of the devices using advanced materials and novel architectural design. An increase in understanding of structure-property relationships in nanomaterials and interfaces and the ability to control nanostructures precisely has led to an immense improvement in the performance characteristics of these devices. In this review, we discuss the recent advances for both electrochemical and electrostatic capacitors as high power electrical energy storage systems, and propose directions and challenges for the future. We asses the opportunities in nanostructure-based high power electrical energy storage devices and include electrochemical and electrostatic capacitors for their potential to open the door to a new regime of power energy.

  19. Effect of landing height on frontal plane kinematics, kinetics and energy dissipation at lower extremity joints.

    PubMed

    Yeow, C H; Lee, P V S; Goh, J C H

    2009-08-25

    Lack of the necessary magnitude of energy dissipation by lower extremity joint muscles may be implicated in elevated impact stresses present during landing from greater heights. These increased stresses are experienced by supporting tissues like cartilage, ligaments and bones, thus aggravating injury risk. This study sought to investigate frontal plane kinematics, kinetics and energetics of lower extremity joints during landing from different heights. Eighteen male recreational athletes were instructed to perform drop-landing tasks from 0.3- to 0.6-m heights. Force plates and motion-capture system were used to capture ground reaction force and kinematics data, respectively. Joint moment was calculated using inverse dynamics. Joint power was computed as a product of joint moment and angular velocity. Work was defined as joint power integrated over time. Hip and knee joints delivered significantly greater joint power and eccentric work (p<0.05) than the ankle joint at both landing heights. Substantial increase (p<0.05) in eccentric work was noted at the hip joint in response to increasing landing height. Knee and hip joints acted as key contributors to total energy dissipation in the frontal plane with increase in peak ground reaction force (GRF). The hip joint was the top contributor to energy absorption, which indicated a hip-dominant strategy in the frontal plane in response to peak GRF during landing. Future studies should investigate joint motions that can maximize energy dissipation or reduce the need for energy dissipation in the frontal plane at the various joints, and to evaluate their effects on the attenuation of lower extremity injury risk during landing.

  20. Seasonal eddy kinetic energy modulations along the North Equatorial Countercurrent in the western Pacific

    NASA Astrophysics Data System (ADS)

    Chen, Xiao; Qiu, Bo; Chen, Shuiming; Qi, Yiquan; Du, Yan

    2015-09-01

    Seasonal eddy kinetic energy (EKE) variability and its associated eddy energy conversion processes in the western tropical Pacific are investigated using satellite altimeter observations and a global, eddy-resolving, ocean general circulation model (OGCM). Both the altimeter-observed sea surface height anomalies and the OGCM simulation show an area with enhanced EKE east of the Mindanao Island centered around 133°E and 5°N. This enhanced EKE area corresponds to the location of the quasi-stationary meander of the North Equatorial Countercurrent (NECC) and is bordered to the south by the Halmahera Eddy. The mesoscale EKE in this area exhibits a clear seasonality, strong in summer (July-August) and weak in winter (November-January), and much of this seasonality is confined to the upper 200 m layer. An investigation into the upper ocean eddy energetics based on the OGCM simulation reveals that the areal barotropic eddy energy conversion rate has an annual cycle similar to the EKE variations, while the areal baroclinic eddy energy conversion is found to be much smaller that the barotropic conversion rate and exhibits no clear seasonal changes. This indicates that the EKE variations are largely controlled by barotropic conversion of the seasonally varying regional circulation. By examining the seasonal background circulation changes, we find that the amplification of the barotropic eddy energy conversion rate in July-August is related to the seasonal evolution of the Mindanao Current and the New Guinea Coastal Current that amplifies the curvature and amplitude of the quasi-stationary meander of the NECC and results in an elevated EKE level through increased regional barotropic conversion.