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Sample records for high-resolution infrared study

  1. Slit-Jet Discharge Studies of Polyacetylenic Molecules: Synthesis and High Resolution Infrared Spectroscopy of Diacetylene

    NASA Astrophysics Data System (ADS)

    Chang, Chih-Hsuan; Roberts, Melanie A.; Nesbitt, David J.

    2013-06-01

    Polyacetylenic molecules play an important role in both combustion chemistry as well as chemistry of the interstellar medium. This talk presents first high resolution infrared spectroscopic efforts on the simplest jet-cooled polyacetylene, namely diacetylene (C_4H_2). Specifically, the fundamental anti-symmetric C-H stretching mode (near 3333 cm^{-1}) and several hot combination bands of diacetylene have been investigated under sub-Doppler, jet cooled conditions in a pulsed supersonic slit discharge. Local Coriolis perturbations in the fundamental anti-symmetric C-H stretch manifold are observed and analyzed. Six hot bands are observed, including the H-C-C bending mode (v_8) not observed in previous room temperature studies. The observation of these hot bands under rotationally jet cooled conditions (T_{rot}=15.7(4) K) indicate the presence of highly non-equilibrium relaxation processes between vibration and rotation. G. Guelachvili, A. M. Craig, and D. A. Ramsay, J. Mol. Spectrosc. 105, 156 (1984)

  2. High-Resolution Infrared and Electron-Diffraction Studies of Trimethylenecyclopropane ([3]-Radialene)

    SciTech Connect

    Wright, Corey; Holmes, Joshua; Nibler, Joseph W.; Hedberg, Kenneth; White, James D.; Hedberg, Lise; Weber, Alfons; Blake, Thomas A.

    2013-05-16

    Combined high-resolution spectroscopic, electron-diffraction, and quantum theoretical methods are particularly advantageous for small molecules of high symmetry and can yield accurate structures that reveal subtle effects of electron delocalization on molecular bonds. The smallest of the radialene compounds, trimethylenecyclopropane, [3]-radialene, has been synthesized and examined in the gas phase by these methods. The first high-resolution infrared spectra have been obtained for this molecule of D3h symmetry, leading to an accurate B0 rotational constant value of 0.1378629(8) cm-1, within 0.5% of the value obtained from electronic structure calculations (density functional theory (DFT) B3LYP/cc-pVTZ). This result is employed in an analysis of electron-diffraction data to obtain the rz bond lengths (in Å): C-H = 1.072 (17), C-C = 1.437 (4), and C=C = 1.330 (4). The analysis does not lead to an accurate value of the HCH angle; however, from comparisons of theoretical and experimental angles for similar compounds, the theoretical prediction of 117.5° is believed to be reliable to within 2°. The effect of electron delocalization in radialene is to reduce the single C-C bond length by 0.07 Å compared to that in cyclopropane.

  3. A high-resolution study of near-infrared diffuse interstellar bands

    SciTech Connect

    Rawlings, M. G.; Adamson, A. J.; Kerr, T. H. E-mail: aadamson@gemini.edu

    2014-11-20

    We present high-resolution echelle spectroscopic observations of the two near-infrared (NIR) diffuse interstellar bands (DIBs) at 13175 Å and 11797.5 Å. The DIBs have been observed in a number of diffuse interstellar medium sightlines that exhibit a wide range of visual extinctions. Band profiles are similar to those seen in narrow DIBs, clearly asymmetric and can be closely fitted in most cases using two simple Gaussian components. Gaussian fits were generally found to be more successful than fits based on a multiple-cloud model using a template DIB profile. For a sample of nine objects in which both bands are observed, the strength of both NIR DIBs generally increases with A(V), and we report a correlation between the two observed bands over a large A(V) range and widely separated lines of sight. The strength of the two bands is also compared against those of two visual DIBs and the diffuse ISM aliphatic dust absorption feature at 3.4 μm previously detected in the same sightlines. We find that the NIR DIBs do not exhibit notable (anti)correlations with either. Implications of these observations on possible DIB carrier species are discussed.

  4. Laboratory studies at high resolution of the infrared absorption spectra of a number of gases found in planetary atmospheres

    NASA Technical Reports Server (NTRS)

    Hunt, R. H.

    1983-01-01

    The infrared absorption spectra of a number of gases found in planetary atmospheres were studied at high resolution. Absorption line measurements which can be of value for the interpretation of planetary spectra in terms of molecular abundances and conditions in the planetary atmospheres were provided. The high resolution spectra have yielded measurements of individual vibration rotation line parameters including positions, strengths, pressure broadened widths and, where assignments were unknown, the temperature sensitivity of the strengths. Such information allows the determinations of the absorption of a given molecular gas under planetary conditions of temperature and pressure and at the same time it provides the data necessary if the spectra are to be understood in terms of basic molecular theory. Thus this work has included spectral analysis in the form of line assignments as well as fitting of the data to Hamiltonian models. Such fitting is very useful in that it helps to confirm and extend the assignments.

  5. High-Resolution Submillimeter and Near-Infrared Studies of the Transition Disk Around Sz 91

    NASA Technical Reports Server (NTRS)

    Tsukagoshi, Takashi; Momose, Munetake; Abe, Lyu; Akiyama, Eiji; Brandner, Wolfgang; Brandt, Timothy D.; Carson, Joseph; Currie, Thayne; Egner, Sebastian E.; Goto, Miwa; Grady, Carol; Guyon, Olivier; Hashimoto, Jun; Hayano, Yutaka; Hayashi, Masahiko; Hayashi, Saeko; Henning, Thomas; Hodapp, Klaus W.; Ishii, Miki; Iye, Masanori; Janson, Markus; Kandori, Ryo; Knapp, Gillian R.; Kudo, Tomoyuki; Kusakabe, Nobuhiko; Kuzuhara, Masayuki; Kwon, Jungmi; McElwain, Mike; Matsuo, Taro; Mayama, Satoshi; Miyama, Shoken; Morino, Jun-ichi; Moro-Martin, Amaya; Nishimura, Tetsuro; Andrews, Sean; Pyo, Tae-Soo; Serabyn, Eugene; Suenaga, Takuya; Suto, Hiroshi; Suzuki, Ryuji; Takahashi, Yasuhiro; Takami, Hideki; Takami, Michihiro; Takato, Naruhisa; Terada, Hiroshi; Saito, Masao; Thalmann, Christian; Tomono, Daigo; Turner, Edwin L.; Usuda, Tomonori; Watanabe, Makoto; Wisniewski, John P.; Yamada, Toru; Tamura, Motohide; Kitamura, Yoshimi; Ohashi, Nagayoshi; Wilner, David; Kawabe, Ryohei

    2014-01-01

    To reveal the structures of a transition disk around a young stellar object in Lupus, Sz 91, we have performed aperture synthesis 345 GHz continuum and CO(3--2) observations with the Submillimeter Array (approximately 1" - 3" resolution), and high-resolution imaging of polarized intensity at the K(sub s) -band by using the HiCIAO instrument on the Subaru Telescope (0.25" resolution). Our observations successfully resolved the inner and outer radii of the dust disk to be 65 AU and 170 AU, respectively, which indicates that Sz 91 is a transition disk source with one of the largest known inner holes. The model fitting analysis of the spectral energy distribution reveals an H 2 mass of 2.4×10(exp -3) M(solar mass) in the cold (T less than 30 K) outer part at 65 less than r less than 170 AU by assuming a canonical gas-to-dust mass ratio of 100, although a small amount (greater than 3×10(exp -9) M(solar mass)) of hot (T approximately 180 K) dust possibly remains inside the inner hole of the disk. The structure of the hot component could be interpreted as either an unresolved self-luminous companion body (not directly detected in our observations) or a narrow ring inside the inner hole. Significant CO(3--2) emission with a velocity gradient along the major axis of the dust disk is concentrated on the Sz 91 position, suggesting a rotating gas disk with a radius of 420 AU. The Sz 91 disk is possibly a rare disk in an evolutionary stage immediately after the formation of protoplanets because of the large inner hole and the lower disk mass than other transition disks studied thus far.

  6. High-Resolution Submillimeter and Near-Infrared Studies of the Transition Disk around Sz 91

    NASA Technical Reports Server (NTRS)

    Tsukagoshi, Takashi; Momose, Munetake; Hashimoto, Jun; Kudo, Tomoyuki; Andrews, Sean; Saito, Masao; Kitamura, Yoshimi; Ohashi, Nagayoshi; Wilner, David; Kawabe, Ryohei; Abe, Lyu; Akiyama, Eiji; Brandner, Wolfgang; Brandt, Timothy D.; Carson, Joseph; Currie, Thayne; Enger, Sebastian E.; Goto, Miwa; Grady, Carol A.; Guyon, Olivier; Hayano, Yutaka; Hayashi, Masahiko; Henning, Thomas; Hodapp, Klaus W.; Ishii, Miki; Iye, Masanori; Janson, Markus; Kandori, Ryo; Knapp, Gillian R.; Kusakabe, Nobuhiko; Kuzuhara, Masayuki; Kwon, Jungmi; McElwain, Michael W.; Matsuo, Taro; Mayama, Satoshi

    2014-01-01

    To reveal the structures of a transition disk around a young stellar object in Lupus, Sz 91, we have performed aperture synthesis 345 GHz continuum and CO(32) observations with the Submillimeter Array ( 13 resolution), and high-resolution imaging of polarized intensity at the Ks-band by using the Hi-CIAO instrument on the Subaru Telescope (0.25 resolution). Our observations successfully resolved the inner and outer radii of the dust disk to be 65 and 170AU, respectively, which indicates that Sz 91 is a transition disk source with one of the largest known inner holes. The model fitting analysis of the spectral energy distribution reveals an H2 mass of 2.4 103 M in the cold (T 30 K) outer part at 65 r 170 AU by assuming a canonical gas-to-dust mass ratio of 100, although a small amount ( 3109 M) of hot (T 180 K) dust possibly remains inside the inner hole of the disk. The structure of the hot component could be interpreted as either an unresolved self-luminous companion body (not directly detected in our observations) or a narrow ring inside the inner hole. Significant CO(32) emission with a velocity gradient along the major axis of the dust disk is concentrated on the Sz 91 position, suggesting a rotating gas disk with a radius of 420 AU. The Sz 91 disk is possibly a rare disk in an evolutionary stage immediately after the formation of protoplanets because of the large inner hole and the lower disk mass than other transition disks studied thus far.

  7. High-resolution Submillimeter and Near-infrared Studies of the Transition Disk around Sz 91

    NASA Astrophysics Data System (ADS)

    Tsukagoshi, Takashi; Momose, Munetake; Hashimoto, Jun; Kudo, Tomoyuki; Andrews, Sean; Saito, Masao; Kitamura, Yoshimi; Ohashi, Nagayoshi; Wilner, David; Kawabe, Ryohei; Abe, Lyu; Akiyama, Eiji; Brandner, Wolfgang; Brandt, Timothy D.; Carson, Joseph; Currie, Thayne; Egner, Sebastian E.; Goto, Miwa; Grady, Carol; Guyon, Olivier; Hayano, Yutaka; Hayashi, Masahiko; Hayashi, Saeko; Henning, Thomas; Hodapp, Klaus W.; Ishii, Miki; Iye, Masanori; Janson, Markus; Kandori, Ryo; Knapp, Gillian R.; Kusakabe, Nobuhiko; Kuzuhara, Masayuki; Kwon, Jungmi; McElwain, Mike; Matsuo, Taro; Mayama, Satoshi; Miyama, Shoken; Morino, Jun-ichi; Moro-Martín, Amaya; Nishimura, Tetsuro; Pyo, Tae-Soo; Serabyn, Eugene; Suenaga, Takuya; Suto, Hiroshi; Suzuki, Ryuji; Takahashi, Yasuhiro; Takami, Hideki; Takami, Michihiro; Takato, Naruhisa; Terada, Hiroshi; Thalmann, Christian; Tomono, Daigo; Turner, Edwin L.; Usuda, Tomonori; Watanabe, Makoto; Wisniewski, John P.; Yamada, Toru; Tamura, Motohide

    2014-03-01

    To reveal the structures of a transition disk around a young stellar object in Lupus, Sz 91 , we have performed aperture synthesis 345 GHz continuum and CO(3-2) observations with the Submillimeter Array (~1''-3'' resolution) and high-resolution imaging of polarized intensity at the Ks -band using the HiCIAO instrument on the Subaru Telescope (0.''25 resolution). Our observations successfully resolved the inner and outer radii of the dust disk to be 65 and 170 AU, respectively, which indicates that Sz 91 is a transition disk source with one of the largest known inner holes. The model fitting analysis of the spectral energy distribution reveals an H2 mass of 2.4 × 10-3 M ⊙ in the cold (T < 30 K) outer part at 65 AU 3 × 10-9 M ⊙) of hot (T ~ 180 K) dust possibly remains inside the inner hole of the disk. The structure of the hot component could be interpreted as either an unresolved self-luminous companion body (not directly detected in our observations) or a narrow ring inside the inner hole. Significant CO(3-2) emission with a velocity gradient along the major axis of the dust disk is concentrated on the Sz 91 position, suggesting a rotating gas disk with a radius of 420 AU. The Sz 91 disk is possibly a rare disk in an evolutionary stage immediately after the formation of protoplanets because of the large inner hole and the lower disk mass than other transition disks studied thus far.

  8. High-resolution submillimeter and near-infrared studies of the transition disk around Sz 91

    SciTech Connect

    Tsukagoshi, Takashi; Momose, Munetake; Hashimoto, Jun; Kudo, Tomoyuki; Saito, Masao; Ohashi, Nagayoshi; Kawabe, Ryohei; Akiyama, Eiji; Andrews, Sean; Wilner, David; Kitamura, Yoshimi; Abe, Lyu; Brandner, Wolfgang; Brandt, Timothy D.; Carson, Joseph; Currie, Thayne; Egner, Sebastian E.; Guyon, Olivier; Goto, Miwa; Grady, Carol; and others

    2014-03-10

    To reveal the structures of a transition disk around a young stellar object in Lupus, Sz 91 , we have performed aperture synthesis 345 GHz continuum and CO(3-2) observations with the Submillimeter Array (∼1''-3'' resolution) and high-resolution imaging of polarized intensity at the K{sub s} -band using the HiCIAO instrument on the Subaru Telescope (0.''25 resolution). Our observations successfully resolved the inner and outer radii of the dust disk to be 65 and 170 AU, respectively, which indicates that Sz 91 is a transition disk source with one of the largest known inner holes. The model fitting analysis of the spectral energy distribution reveals an H{sub 2} mass of 2.4 × 10{sup –3} M {sub ☉} in the cold (T < 30 K) outer part at 65 AU 3 × 10{sup –9} M {sub ☉}) of hot (T ∼ 180 K) dust possibly remains inside the inner hole of the disk. The structure of the hot component could be interpreted as either an unresolved self-luminous companion body (not directly detected in our observations) or a narrow ring inside the inner hole. Significant CO(3-2) emission with a velocity gradient along the major axis of the dust disk is concentrated on the Sz 91 position, suggesting a rotating gas disk with a radius of 420 AU. The Sz 91 disk is possibly a rare disk in an evolutionary stage immediately after the formation of protoplanets because of the large inner hole and the lower disk mass than other transition disks studied thus far.

  9. High-resolution infrared studies of perdeutero-spiropentane, C5D8

    NASA Astrophysics Data System (ADS)

    Erickson, B. A.; Ju, X.; Nibler, J. W.; Beaudry, C. M.; Blake, T. A.

    2016-07-01

    Perdeutero-spiropentane (C5D8) has been synthesized, and infrared and Raman spectra are reported for the first time. Wavenumber assignments are made for most of the fundamental vibrational states. Gas phase infrared spectra were recorded at a resolution (0.002 cm-1) sufficient to resolve individual rovibrational lines and show evidence of strong Coriolis and/or Fermi resonance interactions for most bands. However a detailed rovibrational analysis of the fundamental ν15 (b2) parallel band proved possible, and a fit of more than 1600 lines yielded a band origin of 1053.84465(10) cm-1 and ground state constants (in units of cm-1): B0 = 0.1120700(9), DJ = 1.51(3) × 10-8, DJK = 3.42(15) × 10-8. We note that the B0 value is significantly less than a value of Ba = 0.1140 cm-1 calculated using structural parameters from an earlier electron diffraction (ED) study, whereas one expects Ba to be lower than B0 because of thermal averaging over higher vibrational levels. A similar discrepancy was noted in an earlier study of C5H8 (Price et al., 2011). The structural and spectroscopic results are in good accord with values computed at the anharmonic level using the B3LYP density functional method with a cc-pVTZ basis set.

  10. Collaborative Study of Analysis of High Resolution Infrared Atmospheric Spectra Between NASA Langley Research Center and the University of Denver

    NASA Technical Reports Server (NTRS)

    Goldman, Aaron

    1999-01-01

    The Langley-D.U. collaboration on the analysis of high resolution infrared atmospheric spectra covered a number of important studies of trace gases identification and quantification from field spectra, and spectral line parameters analysis. The collaborative work included: Quantification and monitoring of trace gases from ground-based spectra available from various locations and seasons and from balloon flights. Studies toward identification and quantification of isotopic species, mostly oxygen and Sulfur isotopes. Search for new species on the available spectra. Update of spectroscopic line parameters, by combining laboratory and atmospheric spectra with theoretical spectroscopy methods. Study of trends of atmosphere trace constituents. Algorithms developments, retrievals intercomparisons and automatization of the analysis of NDSC spectra, for both column amounts and vertical profiles.

  11. High Resolution Near Infrared Spectrometer to Study the Zodiacal Light Spectrum

    NASA Technical Reports Server (NTRS)

    Kutyrev, Alexander; Arendt, Richard G.; Dwek, Eli; Moseley, Samuel H.; Silverberg, Robert F.; Rapchun, David

    2008-01-01

    We are developing a near infrared spectrometer for measuring solar absorption lines in the zodiacal light in the near infrared region. R. Reynolds at el. (2004, ApJ 612, 1206) demonstrated that observing single Fraunhofer line can be a powerful tool for extracting zodiacal light parameters based on their measurements of the profile of the Mg I line at 5184 A. We are extending this technique to the near infrared with the primary goal of measuring the absolute intensity of the zodiacal light. This measurement will provide the crucial information needed to accurately subtract zodiacal emission from the DIRBE measurements to get a much higher quality measurement of the extragalactic IR background. The instrument design is based on a dual Fabry-Perot interferometer with a narrow band filter. Its double etalon design allows to achieve high spectral contrast to reject the bright out of band telluric OH emission. High spectral contrast is absolutely necessary to achieve detection limits needed to accurately measure the intensity of the absorption line. We present the design, estimated performance of the instrument with the expected results of the observing program.

  12. Near micron-sized cirrus cloud particles in high-resolution infrared spectra: An orographic case study

    NASA Astrophysics Data System (ADS)

    Kahn, Brian H.; Eldering, Annmarie; Clough, Shepard A.; Fetzer, Eric J.; Fishbein, Evan; Gunson, Michael R.; Lee, Sung-Yung; Lester, Peter F.; Realmuto, Vincent J.

    2003-04-01

    The high-resolution spectra of the Atmospheric Infrared Sounder (AIRS) provide a global view of small- particle-dominated cirrus clouds, and they exist over much larger spatial extents than seen in previous aircraft campaigns. As shown by simulations using a plane-parallel scattering radiative transfer (RT) model and realistic ice particle shapes, the shape of the radiance spectra in the atmospheric windows is uniquely influenced by small ice crystals. Minima in the brightness temperature (BT) spectra between 800 to 850 cm-1 are seen for ice particles smaller than 3 μm in the RT simulations and AIRS spectra. A case study of an orographic cirrus cloud observed on October 2, 2002, over the central Andes of South America is presented with spectral BT differences up to 63K between 998 and 811 cm-1.

  13. The use of high-resolution infrared thermography (HRIT) for the study of ice nucleation and ice propagation in plants.

    PubMed

    Wisniewski, Michael; Neuner, Gilbert; Gusta, Lawrence V

    2015-05-08

    Freezing events that occur when plants are actively growing can be a lethal event, particularly if the plant has no freezing tolerance. Such frost events often have devastating effects on agricultural production and can also play an important role in shaping community structure in natural populations of plants, especially in alpine, sub-arctic, and arctic ecosystems. Therefore, a better understanding of the freezing process in plants can play an important role in the development of methods of frost protection and understanding mechanisms of freeze avoidance. Here, we describe a protocol to visualize the freezing process in plants using high-resolution infrared thermography (HRIT). The use of this technology allows one to determine the primary sites of ice formation in plants, how ice propagates, and the presence of ice barriers. Furthermore, it allows one to examine the role of extrinsic and intrinsic nucleators in determining the temperature at which plants freeze and evaluate the ability of various compounds to either affect the freezing process or increase freezing tolerance. The use of HRIT allows one to visualize the many adaptations that have evolved in plants, which directly or indirectly impact the freezing process and ultimately enables plants to survive frost events.

  14. The use of high-resolution infrared thermography (HRIT) for the study of ice nucleation and ice propagation in plants.

    PubMed

    Wisniewski, Michael; Neuner, Gilbert; Gusta, Lawrence V

    2015-01-01

    Freezing events that occur when plants are actively growing can be a lethal event, particularly if the plant has no freezing tolerance. Such frost events often have devastating effects on agricultural production and can also play an important role in shaping community structure in natural populations of plants, especially in alpine, sub-arctic, and arctic ecosystems. Therefore, a better understanding of the freezing process in plants can play an important role in the development of methods of frost protection and understanding mechanisms of freeze avoidance. Here, we describe a protocol to visualize the freezing process in plants using high-resolution infrared thermography (HRIT). The use of this technology allows one to determine the primary sites of ice formation in plants, how ice propagates, and the presence of ice barriers. Furthermore, it allows one to examine the role of extrinsic and intrinsic nucleators in determining the temperature at which plants freeze and evaluate the ability of various compounds to either affect the freezing process or increase freezing tolerance. The use of HRIT allows one to visualize the many adaptations that have evolved in plants, which directly or indirectly impact the freezing process and ultimately enables plants to survive frost events. PMID:25992743

  15. High Resolution Far Infrared Study of Antiferromagnetic Resonance Transitions in α-Fe2O3 (hematite)

    NASA Astrophysics Data System (ADS)

    Chou, Shin Grace; Plusquellic, David F.; Stutzman, Paul E.; Wang, Shuangzhen; Garboczi, Edward J.; Egelhoff, William F.

    2012-02-01

    In this study, we report high resolution optical measurements of the temperature dependence of the antiferromagnetic (AFM) transition in α-Fe2O3 (hematite) between (0.5 and 10) cm-1. The absorption peak position, over a large temperature range, is found to be in agreement with a modified spin-wave model at both the high and low temperature phases, where the temperature is above and below the Morin transition temperature, respectively. The high spectral resolution optical measurements as demonstrated in this study allow unprecedented zero-field spectral analysis of the zone center AFM magnon in a previously challenging spectral region, giving insights into the role of temperature and strain on the exchange and anisotropy interactions in the system. The results also suggest that the frequency-resolved measurement platform could be extended for room-temperature non-destructive examination and imaging applications for antiferromagnetic materials and devices.

  16. Metallicity determination of M dwarfs. High-resolution infrared spectroscopy

    NASA Astrophysics Data System (ADS)

    Lindgren, Sara; Heiter, Ulrike; Seifahrt, Andreas

    2016-02-01

    Context. Several new techniques to determine the metallicity of M dwarfs with better precision have been developed over the last decades. However, most of these studies were based on empirical methods. In order to enable detailed abundance analysis, standard methods established for warmer solar-like stars, i.e. model-dependent methods using fitting of synthetic spectra, still need to be used. Aims: In this work we continue the reliability confirmation and development of metallicity determinations of M dwarfs using high-resolution infrared spectra. The reliability was confirmed through analysis of M dwarfs in four binary systems with FGK dwarf companions and by comparison with previous optical studies of the FGK dwarfs. Methods: The metallicity determination was based on spectra taken in the J band (1.1-1.4 μm) with the CRIRES spectrograph. In this part of the infrared, the density of stellar molecular lines is limited, reducing the amount of blends with atomic lines enabling an accurate continuum placement. Lines of several atomic species were used to determine the stellar metallicity. Results: All binaries show excellent agreement between the derived metallicity of the M dwarf and its binary companion. Our results are also in good agreement with values found in the literature. Furthermore, we propose an alternative way to determine the effective temperature of M dwarfs of spectral types later than M2 through synthetic spectral fitting of the FeH lines in our observed spectra. Conclusions: We have confirmed that a reliable metallicity determination of M dwarfs can be achieved using high-resolution infrared spectroscopy. We also note that metallicites obtained with photometric metallicity calibrations available for M dwarfs only partly agree with the results we obtain from high-resolution spectroscopy. Based on data obtained at ESO-VLT, Paranal Observatory, Chile, Program ID 082.D-0838(A) and 084.D-1042(A).

  17. Design and implementation of spaceborne high resolution infrared touch screen

    NASA Astrophysics Data System (ADS)

    Li, Tai-guo; Li, Wen-xin; Dong, Yi-peng; Ma, Wen; Xia, Jia-gao

    2015-10-01

    For the consideration of the special application environment of the electronic products used in aerospace and to further more improve the human-computer interaction of the manned aerospace area. The research is based on the design and implementation way of the high resolution spaceborne infrared touch screen on the basis of FPGA and DSP frame structure. Beside the introduction of the whole structure for the high resolution spaceborne infrared touch screen system, this essay also gives the detail information about design of hardware for the high resolution spaceborne infrared touch screen system, FPGA design, GUI design and DSP algorithm design based on Lagrange interpolation. What is more, the easy makes a comprehensive research of the reliability design for the high resolution spaceborne infrared touch screen for the special purpose of it. Besides, the system test is done after installation of spaceborne infrared touch screen. The test result shows that the system is simple and reliable enough, which has a stable running environment and high resolution, which certainly can meet the special requirement of the manned aerospace instrument products.

  18. Infrared-vacuum Ultraviolet-pulsed Field Ionization-photoelectron Study of CH₃I⁺ Using a High-resolution Infrared Laser

    SciTech Connect

    Xing, Xi; Reed, Beth; Bahng, Mi-Kyung; Baek, Sun-Jong; Wang, Peng; Ng, Cheuk-Yiu

    2008-03-12

    The research described in this product was performed in part in the Environmental Molecular Sciences Laboratory, a national scientific user facility sponsored by the Department of Energy's Office of Biological and Environmental Research and located at Pacific Northwest National Laboratory. By using a high-resolution single mode infrared-optical parametric oscillator laser to prepare CH₃I in single (J,K) rotational levels of the v1 (symmetric C–H stretching) =1 vibrational state, we have obtained rovibrationally resolved infrared–vacuum ultraviolet–pulsed field ionization–photoelectron (IR-VUV-PFI-PE) spectra of the CH₃I⁺X˜ 2E3/2 ;v1 +=1;J+ ,P+) band, where (J,K) and (J+ ,P+) represent the respective rotational quantum numbers of CH₃I and CH₃I⁺. The IR-VUV-PFI-PE spectra observed for K=0 and 1 are found to have nearly identical structures. The IR-VUV-PFI-PE spectra for (J,K)=(5,0) and (7, 0) are also consistent with the previous J-selected IR-VUV-PFI-PE measurements. The analysis of these spectra indicates that the photoionization cross section of CH₃I depends strongly on |ΔJ⁺|=|J⁺-J| but not on J and K. This observation lends strong support for the major assumption adopted for the semiempirical simulation scheme, which has been used for the simulation of the origin bands observed in VUV-PFI-PE study of polyatomic molecules. Using the state-to-state photoionization cross sections determined in this IR-VUV study, we have obtained excellent simulation of the VUV-PFI-PE origin band of CH₃I+(X˜ 2E3/2), yielding more precise IE(CH₃I)=76 930.7±0.5 cm-1 and v1 +=2937.8±0.2 cm-1.

  19. Collaborative Study for Analysis of High Resolution Infrared Atmospheric Spectra Between NASA Langley Research Center and the University of Denver

    NASA Technical Reports Server (NTRS)

    Goldman, A.

    2002-01-01

    The Langley-D.U. collaboration on the analysis of high resolultion infrared atmospheric spectra covered a number of important studies of trace gases identification and quantification from field spectra, and spectral line parameters analysis. The collaborative work included: 1) Quantification and monitoring of trace gases from ground-based spectra available from various locations and seasons and from balloon flights; 2) Identification and preliminary quantification of several isotopic species, including oxygen and Sulfur isotopes; 3) Search for new species on the available spectra, including the use of selective coadding of ground-based spectra for high signal to noise; 4) Update of spectroscopic line parameters, by combining laboratory and atmospheric spectra with theoretical spectroscopy methods; 5) Study of trends and correlations of atmosphere trace constituents; and 6) Algorithms developments, retrievals intercomparisons and automatization of the analysis of NDSC spectra, for both column amounts and vertical profiles.

  20. High-Resolution Infrared Spectroscopy of Ge_2C_3

    NASA Astrophysics Data System (ADS)

    Thorwirth, S.; Lutter, V.; Schlemmer, S.; Giesen, T. F.; Gauss, J.

    2013-06-01

    Carbon-rich systems are of great importance in diverse areas of research like material science as well as astro- and structural chemistry. Despite this relevance, our knowledge of smaller cluster units is still fragmentary, particularly with respect to investigations at high-spectral resolution in the gas phase. Unequivocal assignment of spectral features to their molecular carriers is critically dependent on predictions from high-level quantum-chemical calculations. In turn, high-resolution studies provide useful information to assess the predictive power of quantum-chemical methods. This is particularly interesting for cluster systems harboring heavy elements for which so far relatively little is known from experiment. With this contribution, we would like to present a recent gas-phase study of a polyatomic germanium-carbon cluster, linear Ge_2C_3 (Ge=C=C=C=Ge), which was previously studied in an Ar matrix. The cluster was produced through laser ablation of germanium-graphite sample rods and observed in a free jet at wavelengths around 5μm. Additionally, quantum-chemical calculations of Ge_2C_3 were performed at the CCSD(T) level of theory. The production and observation of Ge_2C_3 suggests that many more binary clusters should be amenable to high-resolution spectroscopic techniques not only in the infrared but also in the microwave region. D. L. Robbins, C. M. L. Rittby, and W. R. M. Graham, J. Chem. Phys. 114, 3570 (2001).

  1. The vibrational spectrum and rotational constants of difluoroethyne FC 3/4 CF. Matrix and high resolution infrared studies and ab initio calculations

    NASA Astrophysics Data System (ADS)

    Bürger, H.; Schneider, W.; Sommer, S.; Thiel, W.; Willner, H.

    1991-10-01

    Infrared spectra of the short-lived difluoroethyne molecule have been recorded in neon and argon matrices between 200 and 5000 cm-1. Fourier transform infrared spectra with a resolution of 0.004 cm-1 have been measured in the gas phase around 1350 cm-1 (ν3, ν2+ν4+ν5, hot bands) and 2150 cm-1 (ν2+ν3, ν1-ν5, hot bands). The high resolution study yields rotational parameters of the ground and all singly excited vibrational states. The interpretation of the experimental data has been guided by ab initio calculations at the SCF (self-consistent-field) level and the correlated MP2 level (Moller-Plesset second order perturbation theory) employing three different large basis sets. The theoretical calculations provide the SCF and MP2 harmonic fields as well as the SCF anharmonic force field of FCCF. The agreement between the available theoretical and experimental results is generally quite good, with the exception of the spectroscopic constants involving the trans-bending mode ν4 where more theoretical work is required. The combined use of theoretical and experimental information leads to an estimate of the equilibrium structure [D∞h, re(CC)=1.1865 Å, re(CF)=1.2832 Å] and to recommended ``best'' values for the wave numbers of all fundamental vibrations based on the matrix and high resolution infrared data and some ab initio anharmonicity constants. The present study demonstrates the advantages of a combined theoretical and experimental approach to the spectroscopy of short-lived molecules.

  2. The infrared spectrum of isothiazole in the range 600-1500 cm-1, including a high-resolution study of the ν studies of the full spectrum

    NASA Astrophysics Data System (ADS)

    Hegelund, F.; Wugt Larsen, R.; Aitken, R. A.; Kraus, H.; Nicolaisen, F. M.; Palmer, M. H.

    The gas-phase high-resolution infrared spectrum of isothiazole in the range 600-1500 cm-1 has been recorded, and revised band centres obtained for a number of vibrations. An analysis of the ν11(A') band at 818 cm-1 and the ν16(A'') band at 727 cm-1 has been performed, using the Watson Hamiltonian, A-reduction, IIIr representation. These were combined with previous microwave spectral data to provide combined analyses for rotational constants and quartic centrifugal distortion constants ΔJ, ΔJK, ΔK, δJ and δK. These extend the knowledge derived from previous microwave and IR spectral studies. The equilibrium structures and the derived harmonic frequencies were calculated by ab initio methods, using a variety of basis sets with MP2, MP4 and CCSD(T) methods, and a comparison of these with experimental data is discussed. At a pragmatic level, the closest correlation of the rotational constants with experiment is not obtained with the most sophisticated methodology. Similarly, the vibration frequencies and intensities also vary strongly with the procedure. In particular, we found that the cc-pVTZ+MP2 results probably provide the best numerical comparison with experimental IR data for this molecule.

  3. Measurement of stratospheric HBr using high resolution far infrared spectroscopy

    NASA Astrophysics Data System (ADS)

    Carlotti, M.; Ade, P. A. R.; Carli, B.; Ciarpallini, P.; Cortesi, U.; Griffin, M. J.; Lepri, G.; Mencaraglia, F.; Murray, A. G.; Nolt, I. G.; Park, J. H.; Radostitz, J. V.

    Far infrared spectral features of HBr have been observed in the stratospheric emission spectrum using a balloon borne high resolution Fourier transform spectrometer equipped with a high sensitivity detector specially designed for this purpose. The value of 1.6±0.6 parts per trillion in volume for the HBr mixing ratio has been retrieved, from the global-fit analysis of 121 spectra, in the 25-36.5 km altitude range. The result is briefly compared with models and previous assessments.

  4. High resolution infrared datasets useful for validating stratospheric models

    NASA Technical Reports Server (NTRS)

    Rinsland, Curtis P.

    1992-01-01

    An important objective of the High Speed Research Program (HSRP) is to support research in the atmospheric sciences that will improve the basic understanding of the circulation and chemistry of the stratosphere and lead to an interim assessment of the impact of a projected fleet of High Speed Civil Transports (HSCT's) on the stratosphere. As part of this work, critical comparisons between models and existing high quality measurements are planned. These comparisons will be used to test the reliability of current atmospheric chemistry models. Two suitable sets of high resolution infrared measurements are discussed.

  5. High resolution infrared acquisitions droning over the LUSI mud eruption.

    NASA Astrophysics Data System (ADS)

    Di Felice, Fabio; Romeo, Giovanni; Di Stefano, Giuseppe; Mazzini, Adriano

    2016-04-01

    The use of low-cost hand-held infrared (IR) thermal cameras based on uncooled micro-bolometer detector arrays became more widespread during the recent years. Thermal cameras have the ability to estimate temperature values without contact and therefore can be used in circumstances where objects are difficult or dangerous to reach such as volcanic eruptions. Since May 2006 the Indonesian LUSI mud eruption continues to spew boiling mud, water, aqueous vapor, CO2, CH4 and covers a surface of nearly 7 km2. At this locality we performed surveys over the unreachable erupting crater. In the framework of the LUSI Lab project (ERC grant n° 308126), in 2014 and 2015, we acquired high resolution infrared images using a specifically equipped remote-controlled drone flying at an altitude of m 100. The drone is equipped with GPS and an autopilot system that allows pre-programming the flying path or designing grids. The mounted thermal camera has peak spectral sensitivity in LW wavelength (μm 10) that is characterized by low water vapor and CO2 absorption. The low distance (high resolution) acquisitions have a temperature detail every cm 40, therefore it is possible to detect and observe physical phenomena such as thermodynamic behavior, hot mud and fluids emissions locations and their time shifts. Despite the harsh logistics and the continuously varying gas concentrations we managed to collect thermal images to estimate the crater zone spatial thermal variations. We applied atmosphere corrections to calculate infrared absorption by high concentration of water vapor. Thousands of images have been stitched together to obtain a mosaic of the crater zone. Regular monitoring with heat variation measurements collected, e.g. every six months, could give important information about the volcano activity estimating its evolution. A future data base of infrared high resolution and visible images stored in a web server could be a useful monitoring tool. An interesting development will be

  6. IRAS high resolution studies and modeling of closely interacting galaxies. Galaxy collisions: Infrared observations and analysis of numerical models. UV spectroscopy of massive young stellar populations in interacting galaxies

    NASA Technical Reports Server (NTRS)

    Lamb, Susan A.

    1993-01-01

    The Final Technical Report covering the period from 15 Aug. 1989 to 14 Aug. 1991 is presented. Areas of research included Infrared Astronomy Satellite (IRAS) high resolution studies and modeling of closely interacting galaxies; galaxy collisions: infrared observations and analysis of numerical models; and UV spectroscopy of massive young stellar populations in interacting galaxies. Both observational studies and theoretical modelling of interacting galaxies are covered. As a consequence the report is divided into two parts, one on each aspect of the overall project.

  7. Infrared-Vacuum Ultraviolet Pulsed Field Ionization-Photoelectron Study of C₂H₄ + Using a High-Resolution Infrared Laser

    SciTech Connect

    Xing, Xi; Reed, Beth; Bahng, Mi-Kyung; Ng, Cheuk-Yiu

    2008-02-20

    The research described in this product was performed in part in the Environmental Molecular Sciences Laboratory, a national scientific user facility sponsored by the Department of Energy's Office of Biological and Environmental Research and located at Pacific Northwest National Laboratory. The infrared (IR)-vacuum ultraviolet (VUV)-pulsed field ionization-photoelectron (IR-VUV-PFI-PE) spectrum for C₂H₄(X 1Ag, V11 = 1, N'Ka'Kc'=3₀₃) in the VUV range of 83 000-84 800 cm-1 obtained using a single mode infrared laser revealed 24 rotationally resolved vibrational bands for the ion C₂H₄ +(X 2B3u) ground state. The frequencies and symmetry of the vibrational bands thus determined, together with the anharmonic frequency predictions calculated at the CCSD(T)/aug-cc-pVQZ level, have allowed the unambiguous assignment of these vibrational bands. These bands are mostly combination bands. The measured frequencies of these bands yield the fundamental frequencies for V8 + ) 1103± ( 10 cm-1 and V10 + ) 813 ( 10 cm-1 of C₂H₄ +(X 2B3u), which have not been determined previously. The present IR-VUV-PFI-PE study also provides truly rovibrationally selected and resolved state-to-state cross sections for the photoionization transitions C₂H₄(X~1Ag; V11, N'Ka'Kc') → C₂H₄ +(X~ 2B3u; Vi +, N+ Ka +Kc +), where N'Ka'Kc' denotes the rotational level of C₂H₄(X~ 1Ag; V11), and Vi + and N+ Ka +Kc + represent the vibrational and rotational states of the cation.

  8. High-Resolution Mars Camera Test Image of Moon (Infrared)

    NASA Technical Reports Server (NTRS)

    2005-01-01

    This crescent view of Earth's Moon in infrared wavelengths comes from a camera test by NASA's Mars Reconnaissance Orbiter spacecraft on its way to Mars. The mission's High Resolution Imaging Science Experiment camera took the image on Sept. 8, 2005, while at a distance of about 10 million kilometers (6 million miles) from the Moon. The dark feature on the right is Mare Crisium. From that distance, the Moon would appear as a star-like point of light to the unaided eye. The test verified the camera's focusing capability and provided an opportunity for calibration. The spacecraft's Context Camera and Optical Navigation Camera also performed as expected during the test.

    The Mars Reconnaissance Orbiter, launched on Aug. 12, 2005, is on course to reach Mars on March 10, 2006. After gradually adjusting the shape of its orbit for half a year, it will begin its primary science phase in November 2006. From the mission's planned science orbit about 300 kilometers (186 miles) above the surface of Mars, the high resolution camera will be able to discern features as small as one meter or yard across.

  9. The TIROS-N high resolution infrared radiation sounder

    NASA Technical Reports Server (NTRS)

    Koenig, E. W.

    1979-01-01

    The high-resolution infrared radiation sounder (HIRS/2) was developed and flown on the Television and Infrared Observation Satellite, N Series (TIROS-N) as one means of obtaining atmospheric vertical profile information. The HIRS/2 receives visible and infrared spectrum radiation through a single telescope and selects 20 narrow spectral channels by means of a rotating filter wheel. A passive radiant cooler provides an operating temperature of 106.7K for the HgCdTe and InSb detectors while the visible detector operates at instrument frame temperature. Low noise amplifiers and digital processing provide 13 bit data for spacecraft data multiplexing and transmission. The qualities of system performance that determine sounding capability are the dynamic range of data collection, the noise equivalent radiance of the system, the registration of the air columns sampled in each channel, and the ability to upgrade the calibration of the instrument to maintain the performance standard throughout life. The basic performance of the instrument in test is described. Early orbital information from the TIROS-N launched on October 13, 1978 are given and some observations on system quality are made.

  10. Mid-infrared high resolution spectrometer for SOFIA

    NASA Astrophysics Data System (ADS)

    Kutyrev, Alexander; Moseley, Samuel H.; Bergin, Edwin A.; Bjoraker, Gordon; Melnick, Gary J.; Neufeld, David A.; Pontoppidan, Klaus; Roberge, Aki; Stacey, Gordon J.; Watson, Dan M.; Wollack, Edward

    2016-01-01

    Mid-infrared spectral range between 20 µm and 120 µm has a number of diagnostic atomic and molecular lines that can probe physical conditions in a variety of objects. In particular, protoplanetary disk clouds, YSO, planetary atmospheres would benefit from a high resolution spectroscopy in that wavelength range. Through its high spectral resolution the instrument would allow to obtain both physical and dynamical information on the clouds. Comprehensive observations of the various phases of gas in the protoplanetary disks with the instrument would allow to advance the knowledge of the processes leading to the formation of planetary systems. Such an instrument with high spectral resolving power and sensitivity would be a powerful addition to the current SOFIA instruments.

  11. High-resolution near-infrared spectroscopy of water dimer

    NASA Technical Reports Server (NTRS)

    Huang, Z. S.; Miller, R. E.

    1989-01-01

    High-resolution near-infrared spectra are reported for all of the O-H stretch vibrational bands of the water dimer. The four O-H vibrations are characterized as essentially independent proton-donor or proton-acceptor motions. In addition to the rotational and vibrational information contained in these spectra, details are obtained concerning the internal tunneling dynamics in both the ground and excited vibrational states. These results show that, for tunneling motions which involve the interchange of the proton donor and acceptor molecules, the associated frequencies decrease substantially due to vibrational excitation. The predissociation lifetimes for the various states of the dimer are determined from linewidth measurements. These results clearly show that the predissociation dynamics is strongly dependent on the tunneling states, as well as the Ka quantum number, indicating that the internal tunneling dynamics plays an important role in determining the dissociation rate in this complex.

  12. Design of the WIYN High Resolution Infrared Camera (WHIRC)

    NASA Astrophysics Data System (ADS)

    Smee, S. A.; Barkhouser, R. H.; Scharfstein, G. A.; Meixner, M.; Orndorff, J. D.; Miller, T.

    2011-01-01

    The WIYN High Resolution Infrared Camera (WHIRC) is a high-resolution near-infrared imager (0.8-2.5 μm) designed to produce superb images over a moderate (3.3' × 3.4') field of view on the WIYN 3.5 m telescope at Kitt Peak National Observatory. It takes scientific advantage of the excellent image quality produced by the telescope and its image stabilization subsystem, the WIYN Tip-Tilt Module (WTTM), which is located on one of two Nasmyth ports. WHIRC mounts to WTTM and reimages the WTTM focal plane to a plate scale of 0.1'' pixel-1 at the WHIRC detector. Its straight-through optical path makes for a compact, very low mass, instrument—a necessity, given the stringent moment-loading requirement at the WTTM interface. The WHIRC optical path consists of a vacuum window, a five-element collimator, a dual filter wheel, a five-element achromatic camera, and a 2k2 Raytheon VIRGO mercury cadmium telluride (HgCdTe) detector. A novel all-aluminum lens cell design is used to achieve 13 μm lens centering tolerances between ambient and the 77 K operating temperature. A suite of 13 filters facilitates broadband (J, H, and Ks) imaging, as well as narrowband imaging tailored to a variety of astronomical investigations. The imaging performance of WHIRC is excellent. Irrespective of seeing, the telescope, and WTTM, WHIRC delivers 0.13'', 0.11'', and 0.08'' FWHM images in J, H, and Ks, respectively. On sky, the imaging is equally impressive yielding images as good as ~0.25 FWHM in Ks. In this article we describe the WHIRC design in detail and present the predicted and measured instrument performance.

  13. A Combined Synchrotron-Based High Resolution FTIR and Diode Laser Jet Infrared Spectroscopy Study of the Chiral Molecule CDBrClF

    NASA Astrophysics Data System (ADS)

    Albert, S.; Albert, K. Keppler; Quack, M.; Lerch, Ph.; Boudon, V.

    2013-06-01

    The experimental detection of molecular parity violation Δ_{PV}E is of great interest because of its importance in the understanding of fundamental aspects of molecular dynamics and symmetries. One possible method for this is measuring rovibrational or rotational frequency shifts in the infrared or microwave spectra of enantiomers. For that reason we have measured and analysed the rotationally resolved infrared spectrum of CDBrClF as a prototype spectrum for a chiral molecule using three different techniques. The spectrum has been recorded at room temperature with the Zurich Bruker IFS spectrometer ZP 2001 and with the Bruker interferometer 2009 connected to the Swiss synchrotron using a resolution of 0.0007 cm^{-1}. In addition, the IR spectrum of CDBrClF has been measured at low temperature with our diode laser jet setup in the ν_5 region. The spectra of the two major isotopomers CD^{81}Br^{35}ClF and CD^{79}Br^{35}ClF have been analysed within the ν_5 (CCl-stretch), ν_4 (CF-stretch) and ν_3 (CDF-bend) regions. A detailed rovibrational analysis of these bands is presented. The role for possible experiments in the experimental detection of molecular parity violation shall be discussed. M. Quack, Fundamental symmetries and symmetry violations in Handbook of High Resolution Spectroscopy, Vol. 1(Eds. M. Quack and F. Merkt), Wiley, Chichester, New York 2011, 659-722, M. Quack, J. Stohner and M. Willeke, Annu. Rev. Phys. Chem. 2008, 59, 741, A. Bakasov, T.K. Ha, and M. Quack, J. Chem. Phys. 1998, 109, 7263, R. Berger and M. Quack, J. Chem. Phys, 2000, 112, 3148. M. Quack and J. Stohner, Phys. Rev. Lett. 2000, 84, 3807, M. Quack and J. Stohner. J. Chem. Phys., 2003, 119, 11228. S. Albert, K. Keppler Albert and M. Quack, High Resolution Fourier Transform Infrared Spectroscopy in Handbook of High Resolution Spectroscopy, Vol. 2 (Eds. M. Quack and F. Merkt), Wiley, Chichester, New York 2011, 965-1019, S. Albert and M. Quack, ChemPhysChem, 2007, 8, 1271-1281. S. Albert

  14. High Resolution Infrared Spectroscopy of [1.1.1] Propellane

    SciTech Connect

    Kirkpatrick, Robynne W.; Masiello, Tony; Jariyasopit, Narumol; Weber, Alfons; Nibler, Joseph W.; Maki, Arthur; Blake, Thomas A.; Hubler, Timothy L.

    2008-01-08

    The infrared spectrum of [1.1.1]propellane has been recorded at high resolution (0.002 cm-1) with individual rovibrational lines resolved for the first time. This initial report presents the ground state constants for this molecule determined from the analysis of five of the eight infrared-allowed fundamentals v9(e'), v10(e'), v12(e'), v14(a2''), v15(a2''), as well as of several combination bands. In nearly all cases it was found that the upper states of the transitions exhibit some degree of perturbation but, by use of the combination difference method, the assigned frequencies provided over 4000 consistent ground state difference values. Analysis of these gave for the parameters of the ground state the following values, in cm-1: B0 = 0.28755833(14), DJ = 1.1313(5)x10-7, DJK = -1.2633(7)x10-7, HJ = 0.72(4)x10-13, HJK = -2.24(13)x10-13, and HKJ = 2.25(15)x10-13, where the numbers in parentheses indicate twice the uncertainties in the last quoted digit(s) of the parameters. Gaussian ab initio calculations, especially with the computed anharmonic corrections to some of the spectroscopic parameters, assisted in the assignments of the bands and also provided information on the electron distribution in the bridge-head carbon-carbon bond.

  15. Non-destructive testing for combined stresses using high-resolution thermal infrared remote sensing and ''three-temperature model'': A case study on mangrove plant Kandelia obovata

    NASA Astrophysics Data System (ADS)

    Shen, X.; LI, R.; Li, Y. H.; Chai, M. W.; Qiu, G. Y.

    2015-12-01

    Mangrove forests are currently facing serious heavy metal pollution and eutrophication problems. Remote sensing of vegetation is a non-invasive methodology to monitor physiological characteristics of plants. The potential of high-resolution thermal infrared remote sensing and the three-temperature model (3T model) for monitoring the effects of combined stresses on mangrove plant Kandelia obovata was assessed. The experiment consists of four levels of CdCl2 stress (0, 1, 5 and 10 mg·L-1) in each of four NH4Cl stress levels: 0, 10, 50 and 100 mg·L-1, respectively. The non-destructive testing indices, including plant transpiration transfer coefficient (hat) and estimated instant transpiration rate, were calculated from thermal images and the 3T model. The photosynthetic rate (Pn), stomatal conductance (Gs) and transpiration rate (Tr) were also tested to validate the results of non-destructive testing. The results showed that: (1) The plant transpiration transfer coefficients (hat) were changed from 0.246 to 0.928 and the estimated instant transpiration rates ranged from 0.590 to 6.119 mmol H2O m-2s-1 among different combined stresses. With increasing stress, there were significant decreases for estimated instant transpiration rate and increases for hat (P < 0.05). (2) The photosynthetic characteristics, including Pn, Gs and Tr, were significantly decreased with the increasing combined stresses (P < 0.05). (3) The effects of Cd, N, and their interaction on non-destructive indices and photosynthetic parameters were significant (P < 0.05). (4) The hat was significantly negatively correlated with photosynthetic parameters and the T-3T was significantly positively correlated with photosynthetic parameters (P < 0.05). Therefore, the transpiration transfer coefficient (hat) andestimated instant transpiration rate detecting by infrared thermography device could be indicators to reflect the stress conditions. Based on high-resolution thermal infrared remote sensing, we

  16. Immersion Gratings for Infrared High-resolution Spectroscopy

    NASA Astrophysics Data System (ADS)

    Sarugaku, Yuki; Ikeda, Yuji; Kobayashi, Naoto; Kaji, Sayumi; Sukegawa, Takashi; Sugiyama, Shigeru; Nakagawa, Takao; Arasaki, Takayuki; Kondo, Sohei; Nakanishi, Kenshi; Yasui, Chikako; Kawakita, Hideyo

    2016-10-01

    High-resolution spectroscopy in the infrared wavelength range is essential for observations of minor isotopologues, such as HDO for water, and prebiotic organic molecules like hydrocarbons/P-bearing molecules because numerous vibrational molecular bands (including non-polar molecules) are located in this wavelength range. High spectral resolution enables us to detect weak lines without spectral line confusion. This technique has been widely used in planetary sciences, e.g., cometary coma (H2O, CO, and organic molecules), the martian atmosphere (CH4, CO2, H2O and HDO), and the upper atmosphere of gas giants (H3+ and organic molecules such as C2H6). Spectrographs with higher resolution (and higher sensitivity) still have a potential to provide a plenty of findings. However, because the size of spectrographs scales with the spectral resolution, it is difficult to realize it.Immersion grating (IG), which is a diffraction grating wherein the diffraction surface is immersed in a material with a high refractive index (n > 2), provides n times higher spectral resolution compared to a reflective grating of the same size. Because IG reduces the size of spectrograph to 1/n compared to the spectrograph with the same spectral resolution using a conventional reflective grating, it is widely acknowledged as a key optical device to realize compact spectrographs with high spectral resolution.Recently, we succeeded in fabricating a CdZnTe immersion grating with the theoretically predicted diffraction efficiency by machining process using an ultrahigh-precision five-axis processing machine developed by Canon Inc. Using the same technique, we completed a practical germanium (Ge) immersion grating with both a reflection coating on the grating surface and the an AR coating on the entrance surface. It is noteworthy that the wide wavelength range from 2 to 20 um can be covered by the two immersion gratings.In this paper, we present the performances and the applications of the immersion

  17. High-Resolution Scintimammography: A Pilot Study

    SciTech Connect

    Rachel F. Brem; Joelle M. Schoonjans; Douglas A. Kieper; Stan Majewski; Steven Goodman; Cahid Civelek

    2002-07-01

    This study evaluated a novel high-resolution breast-specific gamma camera (HRBGC) for the detection of suggestive breast lesions. Methods: Fifty patients (with 58 breast lesions) for whom a scintimammogram was clinically indicated were prospectively evaluated with a general-purpose gamma camera and a novel HRBGC prototype. The results of conventional and high-resolution nuclear studies were prospectively classified as negative (normal or benign) or positive (suggestive or malignant) by 2 radiologists who were unaware of the mammographic and histologic results. All of the included lesions were confirmed by pathology. Results: There were 30 benign and 28 malignant lesions. The sensitivity for detection of breast cancer was 64.3% (18/28) with the conventional camera and 78.6% (22/28) with the HRBGC. The specificity with both systems was 93.3% (28/30). For the 18 nonpalpable lesions, sensitivity was 55.5% (10/18) and 72.2% (13/18) with the general-purpose camera and the HRBGC, respectively. For lesions 1 cm, 7 of 15 were detected with the general-purpose camera and 10 of 15 with the HRBGC. Four lesions (median size, 8.5 mm) were detected only with the HRBGC and were missed by the conventional camera. Conclusion: Evaluation of indeterminate breast lesions with an HRBGC results in improved sensitivity for the detection of cancer, with greater improvement shown for nonpalpable and 1-cm lesions.

  18. High resolution infrared synchrotron study of CH2D81Br: ground state constants and analysis of the ν5, ν6 and ν9 fundamentals

    NASA Astrophysics Data System (ADS)

    Baldacci, A.; Stoppa, P.; Visinoni, R.; Wugt Larsen, R.

    2012-09-01

    The high resolution infrared absorption spectrum of CH2D81Br has been recorded by Fourier transform spectroscopy in the range 550-1075 cm-1, with an unapodized resolution of 0.0025 cm-1, employing a synchrotron radiation source. This spectral region is characterized by the ν6 (593.872 cm-1), ν5 (768.710 cm-1) and ν9 (930.295 cm-1) fundamental bands. The ground state constants up to sextic centrifugal distortion terms have been obtained for the first time by ground-state combination differences from the three bands and subsequently employed for the evaluation of the excited state parameters. Watson's A-reduced Hamiltonian in the Ir representation has been used in the calculations. The ν 6 = 1 level is essentially free from perturbation whereas the ν 5 = 1 and ν 9 = 1 states are mutually interacting through a-type Coriolis coupling. Accurate spectroscopic parameters of the three excited vibrational states and a high-order coupling constant which takes into account the interaction between ν5 and ν9 have been determined.

  19. High Resolution Near-Infrared Imaging with Tip - Adaptive Optics.

    NASA Astrophysics Data System (ADS)

    Close, Laird Miller

    1995-01-01

    The development and design of the first operational tip-tilt Cassegrain secondary mirror are presented. This system, FASTTRAC, samples image motion at up to 50 Hz by tracking either infrared (m_{k } <=q 11) or visible (mR <=q 16) guide stars up to 30" and 90" away from the science target respectively. The Steward Observatory 2.3m or 1.5m telescope secondaries act as rapid tip-tilt mirrors to stabilize image motion (<=q0.1" rms;~5 Hz -3 dB frequency) based on the motion of the guide star. FASTTRAC obtains nearly diffraction-limited resolutions in seeing conditions where D/r_circ < 4 in agreement with theoretical expectations. FASTTRAC's unique ability to guide on infrared stars has allowed the first adaptively corrected images of the heavily extincted Galactic Center to be obtained. Over a hundred excellent (0.28" < FWHM < 0.6") images have been obtained of this region. These images do not detect any long term variations in the massive black hole candidate Sgr A*'s luminosity from June 1993 to September 1995. The average infrared magnitudes observed are K = 12.1 +/- 0.3, H = 13.7 +/- 0.3 and J = 16.6 +/- 0.4 integrated over 0.5" at the position of Sgr A*. No significant rapid periodicities were observed from Sgr A* for amplitudes >=q50% of the mean flux in the period range of 3-30 minutes. It is confirmed in the latest 0.28" FWHM image that there is 0.5" "bar" of emission running East-West at the position of Sgr A* as was earlier seen by Eckart et al. 1993. The observed fluxes are consistent with an inclined accretion disk around a ~1 times 10^6 M _odot black hole. However, they are also explained by a line of hot luminous (integrated luminosity of ~10^{3.5 -4.6}L_odot) central cluster stars positionally coincident with Sgr A* naturally explaining the observed 0.5" "bar". High-resolution images with FASTTRAC guiding on a faint (R = 16) visible guide star, combined with spectra from the MMT, have shown that IRAS FSC 10214 + 4724 (z = 2.28) gains its uniquely large

  20. High resolution solar X-ray studies

    NASA Technical Reports Server (NTRS)

    Blake, R. L.

    1974-01-01

    Two high resolution solar X-ray payloads and their launches on Aerobee rockets with pointing system are described. The payloads included 5 to 25A X-ray spectrometers, multiaperture X-ray cameras, and command box attitude control inflight by means of a television image radioed to ground. Spatial resolution ranged from five arc minutes to ten arc seconds and spectral resolution ranged from 500 to 3000. Several laboratory tasks were completed in order to achieve the desired resolution. These included (1) development of techniques to align grid collimators, (2) studies of the spectrometric properties of crystals, (3) measurements of the absorption coefficients of various materials used in X-ray spectrometers, (4) evaluation of the performance of multiaperture cameras, and (5) development of facilities.

  1. Determination of atmospheric moisture structure and infrared cooling rates from high resolution MAMS radiance data

    NASA Technical Reports Server (NTRS)

    Menzel, W. Paul; Moeller, Christopher C.; Smith, William L.

    1991-01-01

    This program has applied Multispectral Atmospheric Mapping Sensor (MAMS) high resolution data to the problem of monitoring atmospheric quantities of moisture and radiative flux at small spatial scales. MAMS, with 100-m horizontal resolution in its four infrared channels, was developed to study small scale atmospheric moisture and surface thermal variability, especially as related to the development of clouds, precipitation, and severe storms. High-resolution Interferometer Sounder (HIS) data has been used to develop a high spectral resolution retrieval algorithm for producing vertical profiles of atmospheric temperature and moisture. The results of this program are summarized and a list of publications resulting from this contract is presented. Selected publications are attached as an appendix.

  2. An infrared high resolution silicon immersion grating spectrometer for airborne and space missions

    NASA Astrophysics Data System (ADS)

    Ge, Jian; Zhao, Bo; Powell, Scott; Jiang, Peng; Uzakbaiuly, Berik; Tanner, David

    2014-08-01

    Broad-band infrared (IR) spectroscopy, especially at high spectral resolution, is a largely unexplored area for the far IR (FIR) and submm wavelength region due to the lack of proper grating technology to produce high resolution within the very constrained volume and weight required for space mission instruments. High resolution FIR spectroscopy is an essential tool to resolve many atomic and molecular lines to measure physical and chemical conditions and processes in the environments where galaxy, star and planets form. A silicon immersion grating (SIG), due to its over three times high dispersion over a traditional reflective grating, offers a compact and low cost design of new generation IR high resolution spectrographs for space missions. A prototype SIG high resolution spectrograph, called Florida IR Silicon immersion grating spectromeTer (FIRST), has been developed at UF and was commissioned at a 2 meter robotic telescope at Fairborn Observatory in Arizona. The SIG with 54.74 degree blaze angle, 16.1 l/mm groove density, and 50x86 mm2 grating area has produced R=50,000 in FIRST. The 1.4-1.8 um wavelength region is completely covered in a single exposure with a 2kx2k H2RG IR array. The on-sky performance meets the science requirements for ground-based high resolution spectroscopy. Further studies show that this kind of SIG spectrometer with an airborne 2m class telescope such as SOFIA can offer highly sensitive spectroscopy with R~20,000-30,000 at 20 to 55 microns. Details about the on-sky measurement performance of the FIRST prototype SIG spectrometer and its predicted performance with the SOFIA 2.4m telescope are introduced.

  3. A high-resolution Fourier-transform infrared spectrometer.

    NASA Technical Reports Server (NTRS)

    Johnson, H. L.; Forbes, F. F.; Thompson, R. I.; Steinmetz , D. L.; Harris, O.

    1973-01-01

    We have developed a Fourier-transform infrared spectrometer having a resolution of 0.5/cm over the range of wavelength from 1 to 5.5 microns. It has been used to observe the sun over this wavelength range from a Lear Jet flying at an altitude of 14 km, and to observe a number of stars from the ground, using the 229-cm telescope of the Steward Observatory and the 152-cm aluminum-mirror telescope at the Observatorio Astronomico Nacional in the Sierra de San Pedro Martir, Baja California, Mexico. The solar spectrum is given here, while the ground-based spectra are being published separately.

  4. The Volatile Chemistry Of Jupiter-family Comets Determined From High-resolution Infrared Spectroscopy

    NASA Astrophysics Data System (ADS)

    Dello Russo, Neil; Vervack, R.; Weaver, H.; Kobayashi, H.; Kawakita, H.; Biver, N.; Bockelée-Morvan, D.; Crovisier, J.

    2009-09-01

    The chemistry of Jupiter-family comets (JFCs) has been extensively studied at optical wavelengths using spectroscopic and photometric techniques. However, the coma species detected at optical wavelengths are daughter and granddaughter photodissociation products that are often not easily related to species present in the nucleus. Because JFCs are generally of moderate productivity, studies of their parent volatile chemistries have lagged owing to sensitivity issues. Recently, studies at radio and infrared wavelengths have revealed the parent volatile chemistry in a small group of JFCs. Here, we report and compare recent results on the chemistry of JFCs using high-resolution infrared spectroscopy. The main goals of this research are to: (1) chemically characterize JFCs using high-resolution infrared spectroscopy in order to build a taxonomy based on parent volatile composition, (2) determine if the parent volatile chemistry of JFCs is consistent with formation conditions or evolutionary processing history, and (3) compare abundances of daughter fragments (e.g., C2, CN, NH, NH2) and their suspected parents (e.g., C2H2, C2H6, HCN, NH3) in JFCs whose chemistries were measured at both infrared and optical wavelengths. Understanding the parent sources of daughter fragments in comets not only provides information on the common infrared/optical database but may also give clues to the parent volatile chemistry in the large number of comets observed only at optical wavelengths. Because JFCs are the most practical mission targets, chemical composition can be one discriminator in determining desirable future targets. Furthermore, determining the range of chemical diversity within the JFC population can help put results of previous missions (e.g. Deep Impact, Stardust) in better context. This work was supported by the NASA Planetary Astronomy and Planetary Atmospheres Programs.

  5. Early Doppler Performance from New Generation High Resolution Optical and near Infrared Planet-hunting Spectrographs

    NASA Astrophysics Data System (ADS)

    Ge, Jian; Varosi, F.; Powell, S.; Zhao, B.; Schofield, S.; Liu, J.; Warner, C.; Sithajan, S.; Li, R.; Muterspaugh, M. W.; Williamson, M. W.; Avner, L.; Jakeman, H.

    2014-01-01

    The next generation of radial velocity (RV) planet surveys require high precision (sub m/s for optical and 1-3 m/s for near infrared (NIR)) and high cadence 100 RV measurements per star) to systematically reach low mass planet populations, including habitable Earth-like planets, around FGKM dwarfs and study their properties. These require new sensitive optical and NIR high resolution spectrographs. At UF, we have developed two new generation optical and NIR high resolution spectrographs for high precision RV low mass planet surveys. The optical high resolution spectrograph called EXtremely high Precision ExtrasolaR planet Tracker (EXPERT) III (EXPERT-III), was commissioned at the Automatic Spectroscopic Telescope (AST), a robotic telescope at Fairborn Observatory in Arizona in July 2013 and has produced a spectral resolution of about 100,000 and a simultaneous wavelength coverage of 0.38-0.9 mm with a 4kx4k back-illuminated Fairchild CCD detector. The early RV measurements show that this instrument has reached ~0.7 m/s RV precision and daily instrument stability is better than 5m/s. The near IR spectrograph, called the Florida IR Silicon immersion grating spectromeTer (FIRST), has produced 60,000 at 0.8-1.8 microns with a 2kx2k H2RG IR array. FIRST is the first high resolution NIR spectrograph taking full advantage of an innovative silicon immersion grating to achieve high spectral resolution (3.4 times higher than a commercially available echelle grating of the equal size and blaze angle) in an extremely compact design. FIRST is schedule to be commissioned at AST in October 2013. Here we report on-sky RV performance and early science results from the AST robotic observations.

  6. Intercomparison of three microwave/infrared high resolution line-by-line radiative transfer codes

    NASA Astrophysics Data System (ADS)

    Schreier, F.; Garcia, S. Gimeno; Milz, M.; Kottayil, A.; Höpfner, M.; von Clarmann, T.; Stiller, G.

    2013-05-01

    An intercomparison of three line-by-line (lbl) codes developed independently for atmospheric sounding - ARTS, GARLIC, and KOPRA - has been performed for a thermal infrared nadir sounding application assuming a HIRS-like (High resolution Infrared Radiation Sounder) setup. Radiances for the HIRS infrared channels and a set of 42 atmospheric profiles from the "Garand dataset" have been computed. Results of this intercomparison and a discussion of reasons of the observed differences are presented.

  7. High Resolution Infrared and Microwave Spectra of NH3-HCCH and NH3-OCS Complexes: Studies of Weak C-H\\cdotsN Hydrogen Bond and Electric Multipole Interactions

    NASA Astrophysics Data System (ADS)

    Liu, Xunchen; Xu, Yunjie

    2011-06-01

    C-H\\cdotsN weak hydrogen bond is of much current interest. We report the first high resolution infrared spectroscopic study of a prototypical C-H\\cdotsN bonded system, i.e. NH3-HCCH, at the vicinity of the ν4 band of NH3. The spectrum has been recorded using an infrared spectrometer equipped with an astigmatic multipass cell aligned for 366 passes and a room temperature external cavity quantum cascade laser at the 6 μm region. The perpendicular band spectrum of symmetric top rotor observed is consistent with the previous microwave and infrared studies at 3 μm. We also extended the previous microwave measurement to higher J and K. For the related NH3-OCS complex, microwave spectrum of J up to 6 and infrared spectrum at the vicinity of the ν4 band of NH3 have been recorded and analyzed for the first time. Comparison has been made with the previously studied isoelectronic complexes such as NH3-N2O and NH3-CO2. The source of the difference will be discussed with the aid of ab initio calculations. G.T. Fraser, K.R. Leopold, and W. Klemperer, J. Chem. Phys. 80(4), 1423, (1984) G. Hilpert, G.T. Fraser, and A.S. Pine, J. Chem. Phys. 105(15), 6183, (1996) G.T. Fraser, D.D. Nelson, JR., G.J. Gerfen, and W. Klemperer, J. Chem. Phys. 83(11), 5442, (1985) G.T. Fraser, K.R. Leopold, and W. Klemperer, J. Chem. Phys. 81(6), 2577, (1984)

  8. High Resolution Infrared Studies of the v2, v4 Bands of 34S16O3, Including Both Intensity and Wavenumber Perturbations

    SciTech Connect

    Barber, Jeffrey B.; Masiello, Tony; Chrysostom, Engelene; Nibler, Joseph W.; Maki, Arthur; Weber, Alfons; Blake, Thomas A.; Sams, Robert L.

    2003-06-15

    The infrared spectrum of the v2, v4 bending mode region of 34S-substituted sulfur trioxide, 34S16O3, has been recorded at a resolution of 0.0025 cm-1. The v2 and v4 levels are coupled by a Coriolis interaction, yielding significant spectral shifts that have been successfully analyzed to obtain rovibrational constants for the ground state and both fundamentals. Comparisons are made with 32S16O3 parameters and the Bo rotational constant is found to be 0.348 556 04(28) cm-1, only very slightly larger than the corresponding value of 0.348 543 33(5) cm-1 for 32S16O3. Coriolis and l-type resonance interactions between the v2 and v4 levels produce frequency shifts and strong intensity perturbations in the spectra that are considered for both 34S16O3 and 32S16O3. The resulting analysis yields an average value of+0.62(8) for the dipole derivative ratio (?x/?Q4x) (?z/?Q2) and a positive sign for the product of this ratio with the?y2,4 Coriolis constant, for which experiment gives+0.5940(15) . Ab initio calculations indicate that the signs of?x/?Q4x and?z/?Q2 are both positive and hence?y2,4 is also positive, in agreement with earlier calculations. These signs indicate that the effective charge movement in the xz plane has the same sense of rotation as Q2, Q4x atom motion in this plane that produces a py vibrational angular momentum component, correlated motion that is confirmed by ab initio calculations.

  9. HIGH RESOLUTION PHOTOEMISSION STUDIES OF COMPLEX MATERIALS.

    SciTech Connect

    JOHNSON,P.D.; VALLA,T.; FEDOROV,A.; REISFELD,G.; HULBERT,S.L.

    1999-10-13

    Recent instrumentation developments in photoemission are providing new insights into the physics of complex materials. With increased energy and momentum resolution, it has become possible to examine in detail different contributions to the self-energy or inverse lifetime of the photohole created in the photoexcitation process. Employing momentum distribution and energy distribution curves, a detailed study of the optimally doped cuprate, Bi{sub 2}Sr{sub 2}CaCu{sub 2}O{sub 8+{delta}}, shows that the material behaves like a non-Fermi liquid with no evidence for the quasi-particles characteristic of a Fermi liquid.

  10. High Resolution Infrared Radiation Sounder (HIRS) for the Nimbus F Spacecraft

    NASA Technical Reports Server (NTRS)

    Koenig, E. W.

    1975-01-01

    Flown on Nimbus F in June 1975, the high resolution infrared radiation sounder (HIRS) scans with a geographical resolution of 23KM and samples radiance in seventeen selected spectral channels from visible (.7 micron) to far IR (15 micron). Vertical temperature profiles and atmospheric moisture content can be inferred from the output. System operation and test results are described.

  11. Measuring stellar magnetic fields from high resolution spectroscopy of near-infrared lines

    NASA Astrophysics Data System (ADS)

    Leone, F.; Vacca, W. D.; Stift, M. J.

    2003-10-01

    Zeeman splitting of otherwise degenerate levels provides a straight-forward method of measuring stellar magnetic fields. In the optical, the relative displacements of the Zeeman components are quite small compared to the rotational line broadening, and therefore observations of Zeeman splitting are usually possible only for rather strong magnetic fields in very slowly rotating stars. However, the magnitude of the Zeeman splitting is proportional to the square of the wavelength, whereas rotational line broadening mechanisms are linear in wavelength; therefore, there is a clear advantage in using near-infrared spectral lines to measure surface stellar magnetic fields. We have obtained high resolution (R >= 25 000) spectra in the 15 625-15 665 Å region for two magnetic chemically peculiar stars, viz. HD 176232 and HD 201601, and for the suspected magnetic chemically peculiar star HD 180583, as part of a pilot study aimed at determining the accuracy with which we can measure stellar magnetic fields using the Zeeman splitting of near-infrared lines. We confirm that in principle the magnetic field strength can be estimated from the magnetic intensification of spectral lines, i.e. the increase in equivalent width of a line over the zero-field value. However, due to line blending as well as the dependence of this intensification on abundance and field geometry, accurate estimates of the magnetic field strengths can be obtained only by modelling the line profiles by means of spectral synthesis techniques. Using this approach, we find a 1.4 kG magnetic field modulus in HD 176132 and an upper limit of 0.2 kG in HD 180583. The very weak infrared lines in the spectrum of HD 201601 are consistent with a 3.9 kG field modulus estimated from the splitting of the Fe II 6149.258 Å line seen in an optical spectrum. Finally, we would like to draw attention to the fact that there are no sufficiently detailed and reliable atomic line lists available for the near-infrared region that

  12. High-resolution study of luminous infrared galaxies. I - The composite nature of the Seyfert 1 galaxy IRAS 20044-6114 (NGC 6860)

    NASA Technical Reports Server (NTRS)

    Lipari, Sebastian; Tsvetanov, Zlatan; Macchetto, F.

    1993-01-01

    The physical conditions in the ionized gas, the stellar population, and the kinematics of the Seyfert 1 galaxy IRAS 20044-6114 (NGC 6860) are studied by high spatial resolution optical imaging and optical and near-IR spectroscopy of this luminous IR source. The broadband images show a compact nucleus, two weak spiral arms, a bar, a bulge, an inner ring, and a possible outer ring. The I-alpha image reveals bright emission-line regions associated with the Seyfert nucleus and an inner ring of intense star formation. The forbidden O III 5007-A image shows that the high-excitation gas is elongated perpendicularly to the direction of the bar, and reveals a bright compact object at about 40 arcsec NE of the nucleus which is undetectable in the broadband images. This object is interpreted as a dwarf young H II galaxy. The optical, near-IR, and FIR results show clear evidence that the nuclear and circumnuclear regions have composite and complex structure: a variable Seyfert 1 nucleus embedded in an intense and dusty star formation. environment.

  13. High Resolution Rovibrational Spectroscopy of Large Molecules Using Infrared Frequency Combs and Buffer Gas Cooling

    NASA Astrophysics Data System (ADS)

    Changala, Bryan; Spaun, Ben; Patterson, David; Bjork, Bryce J.; Heckl, Oliver H.; Doyle, John M.; Ye, Jun

    2016-06-01

    We have recently demonstrated the integration of cavity-enhanced direct frequency comb spectroscopy with buffer gas cooling to acquire high resolution infrared spectra of translationally and rotationally cold (˜10 K) gas-phase molecules. Here, we extend this method to significantly larger systems, including naphthalene (C10H_8), a prototypical polyaromatic hydrocarbon, and adamantane (C10H_{16}), the fundamental building block of diamonoids. To the authors' knowledge, the latter molecule represents the largest system for which rotationally resolved spectra in the CH stretch region (3 μm) have been obtained. In addition to the measured spectra, we present several details of our experimental methods. These include introducing non-volatile species into the cold buffer gas cell and obtaining broadband spectra with single comb mode resolution. We also discuss recent modifications to the apparatus to improve its absorption sensitivity and time resolution, which facilitate the study of both larger molecular systems and cold chemical dynamics. B. Spaun, et al. Probing buffer-gas cooled molecules with direct frequency comb spectroscopy in the mid-infrared, WF02, 70th International Symposium on Molecular Spectroscopy, Champaign-Urbana, IL, 2015.

  14. Estimating evapotranspiration of riparian vegetation using high resolution multispectral, thermal infrared and lidar data

    NASA Astrophysics Data System (ADS)

    Neale, Christopher M. U.; Geli, Hatim; Taghvaeian, Saleh; Masih, Ashish; Pack, Robert T.; Simms, Ronald D.; Baker, Michael; Milliken, Jeff A.; O'Meara, Scott; Witherall, Amy J.

    2011-11-01

    High resolution airborne multispectral and thermal infrared imagery was acquired over the Mojave River, California with the Utah State University airborne remote sensing system integrated with the LASSI imaging Lidar also built and operated at USU. The data were acquired in pre-established mapping blocks over a 2 day period covering approximately 144 Km of the Mojave River floodplain and riparian zone, approximately 1500 meters in width. The multispectral imagery (green, red and near-infrared bands) was ortho-rectified using the Lidar point cloud data through a direct geo-referencing technique. Thermal Infrared imagery was rectified to the multispectral ortho-mosaics. The lidar point cloud data was classified to separate ground surface returns from vegetation returns as well as structures such as buildings, bridges etc. One-meter DEM's were produced from the surface returns along with vegetation canopy height also at 1-meter grids. Two surface energy balance models that use remote sensing inputs were applied to the high resolution imagery, namely the SEBAL and the Two Source Model. The model parameterizations were slightly modified to accept high resolution imagery (1-meter) as well as the lidar-based vegetation height product, which was used to estimate the aerodynamic roughness length. Both models produced very similar results in terms of latent heat fluxes (LE). Instantaneous LE values were extrapolated to daily evapotranspiration rates (ET) using the reference ET fraction, with data obtained from a local weather station. Seasonal rates were obtained by extrapolating the reference ET fraction according to the seasonal growth habits of the different species. Vegetation species distribution and area were obtained from classification of the multispectral imagery. Results indicate that cottonwood and salt cedar (tamarisk) had the highest evapotranspiration rates followed by mesophytes, arundo, mesquite and desert shrubs. This research showed that high-resolution

  15. High-resolution seismic studies applied to injected geothermal fluids

    SciTech Connect

    Smith, A.T.; Kasameyer, P.

    1985-01-01

    The application of high-resolution microseismicity studies to the problem of monitoring injected fluids is one component of the Geothermal Injection Monitoring Project at LLNL. The evaluation of microseismicity includes the development of field techniques, and the acquisition and processing of events during the initial development of a geothermal field. To achieve a specific detection threshold and location precision, design criteria are presented for seismic networks. An analysis of a small swarm near Mammoth Lakes, California, demonstrates these relationships and the usefulness of high-resolution seismic studies. A small network is currently monitoring the Mammoth-Pacific geothermal power plant at Casa Diablo as it begins production.

  16. Applications of High Resolution Mid-Infrared Spectroscopy for Atmospheric and Environmental Measurements

    NASA Astrophysics Data System (ADS)

    Roscioli, Joseph R.; McManus, J. Barry; Nelson, David; Zahniser, Mark; Herndon, Scott C.; Shorter, Joanne; Yacovitch, Tara I.; Jervis, Dylan; Dyroff, Christoph; Kolb, Charles E.

    2016-06-01

    For the past 20 years, high resolution infrared spectroscopy has served as a valuable tool to measure gas-phase concentrations of ambient gas samples. We review recent advances in atmospheric sampling using direct absorption high resolution mid-infrared spectroscopy from the perspective of light sources, detectors, and optical designs. Developments in diode, quantum cascade and interband cascade laser technology have led to thermoelectrically-cooled single-mode laser sources capable of operation between 800 wn and 3100 wn, with <10 MHz resolution and >10 mW power. Advances in detector and preamplifier technology have yielded thermoelectriocally-cooled sensors capable of room-temperature operation with extremely high detectivities. Finally, novel spectrometer optical designs have led to robust multipass absorption cells capable of >400 m effective pathlength in a compact package. In combination with accurate spectroscopic databases, these developments have afforded dramatic improvements in measurement sensitivity, accuracy, precision, and selectivity. We will present several examples of the applications of high resolution mid-IR spectrometers in real-world field measurements at sampling towers and aboard mobile platforms such as vehicles and airplanes.

  17. High Resolution Infrared Spectroscopy of Molecules of Terrestrial and Planetary Interest

    NASA Technical Reports Server (NTRS)

    Freedman, Richard S.

    2001-01-01

    In collaboration with the laboratory spectroscopy group of the Ames Atmospheric Physics Research Branch (SGP), high resolution infrared spectra of molecules that are of importance for the dynamics of the earth's and other planets' atmospheres were acquired using the SGP high resolution Fourier transform spectrometer and gas handling apparatus. That data, along with data acquired using similar instrumentation at the Kitt Peak National Observatory was analyzed to determine the spectral parameters for each of the rotationally resolved transitions for each molecule. Those parameters were incorporated into existing international databases (e.g. HITRANS and GEISA) so that field measurements could be converted into quantitative information regarding the physical and chemical structures of earth and planetary atmospheres.

  18. TOWARD UNDERSTANDING THE ENVIRONMENT OF R MONOCEROTIS FROM HIGH-RESOLUTION NEAR-INFRARED POLARIMETRIC OBSERVATIONS

    SciTech Connect

    Jolin, M.-A.; Bastien, P.; Denni, F.; Lafreniere, D.; Doyon, R.; Voyer, P.

    2010-10-01

    High-resolution H-band imaging polarimetric observations of R Mon obtained at the Canada-France-Hawaii telescope are presented. These data show a centrosymmetric pattern with elongated intensity contours mostly due to the presence of the companion R Mon B. We also consider published R-band data, which show an extended right-angle conical reflection nebula with an offset in the optical peak. We study the circumstellar environment of R Mon with a radiative transfer Monte Carlo code. The best-fitting model obtained succeeds in reproducing the characteristics seen in the data in the two bands simultaneously. The model indicates the presence of relatively small astronomical silicate grains ranging from 0.04 {mu}m to 0.15 {mu}m distributed into three structures: a small disk, an inner envelope, and an outer envelope. The cavity is modeled by a conical structure with a constant low density and we include a 'throat' to produce the offset of the optical peak. Our model predicts a polarization reversal by 90{sup 0} between the R and H bands. Observations show that position angles parallel, perpendicular, and also at other angles to the disk can occur over time in the near-infrared.

  19. High-Resolution Near-Infrared Spectroscopy of CH2+ and Its Deuterated Isotopologues

    NASA Astrophysics Data System (ADS)

    Wang, Haiming; Neese, Christopher F.; Morong, Christopher P.; Kleshcheva, Maria; Oka, Takeshi

    2013-10-01

    Aiming to provide approximate rotational constants for millimeter wave spectroscopists to identify the corresponding species in space, we have recorded the near-infrared spectra of the methylene cation CH2+ and its deuterated isotopologues, CD2+ and CHD+, using a high resolution and high sensitivity spectrometer. Detection of CH2+ in space will shed light on interstellar chemistry as it is the intermediate between the abundant CH+ and yet to be observed CH3+, which is important in the formation of larger organic molecules. CH2+ and its deuterated isotopologues are also of special interest for theoretical studies because of their unique intramolecular dynamics, i.e., the Renner-Teller interaction and quasi-linearity. This paper will discuss several new bands of CH2+, the -(0,5[11],0)0 - X-(0,0[0],0)1 and -(0,4[11],0)2 - X-(0,0[0],0)1 bands of CD2+, which have been identified and analyzed, and the candidate lines for the -(0,4[10],0)1 - X-(0,0[1],0)0 band of CHD+, in comparison with the theoretical predictions by Bunker and colleagues.

  20. High-resolution near-infrared spectroscopy of CH2(+) and its deuterated isotopologues.

    PubMed

    Wang, Haiming; Neese, Christopher F; Morong, Christopher P; Kleshcheva, Maria; Oka, Takeshi

    2013-10-01

    Aiming to provide approximate rotational constants for millimeter wave spectroscopists to identify the corresponding species in space, we have recorded the near-infrared spectra of the methylene cation CH2(+) and its deuterated isotopologues, CD2(+) and CHD+, using a high resolution and high sensitivity spectrometer. Detection of CH2(+) in space will shed light on interstellar chemistry as it is the intermediate between the abundant CH+ and yet to be observed CH3(+), which is important in the formation of larger organic molecules. CH2(+) and its deuterated isotopologues are also of special interest for theoretical studies because of their unique intramolecular dynamics, i.e., the Renner–Teller interaction and quasi-linearity. This paper will discuss several new bands of CH2(+), the Ã(0,5[11],0)0 ← X̃(0,0[0],0)1 and Ã(0,4[11],0)2 ← X̃(0,0[0],0)1 bands of CD2(+), which have been identified and analyzed, and the candidate lines for the Ã(0,4[10],0)1 ← X̃(0,0[1],0)0 band of CHD+, in comparison with the theoretical predictions by Bunker and colleagues.

  1. Analysis of High-Resolution Infrared and CARS Spectra of ³⁴S¹⁸O₃

    SciTech Connect

    Masiello, Tony; Vulpanovici, Nicolae; Barber, Jeffrey B.; Chrysostom, Engelene; Nibler, Joseph W.; Maki, Arthur; Blake, Thomas A.; Sams, Robert L.; Weber, Alfons

    2004-09-11

    As part of a series of investigations of isotopic forms of sulfur trioxide, high-resolution infrared and coherent anti-Stokes Raman spectroscopies were used to study the fundamental modes and several hot bands of 32S18O3. Hot bands originating from the v2 and v4 bending mode levels have been found to couple strongly to the IR-inactive v1 symmetric stretching mode through indirect Coriolis interactions and Fermi resonances. Coriolis coupling effects are particularly noticeable in 32S18O3 due to the close proximity of the v2 and v4 fundamental vibrations, whose deperturbed wavenumber values are 486.488 13(4) and 504.284 77(4) cm-1. The uncertainties in the last digits are shown in parentheses and are two standard deviations. From the infrared transitions, accurate rovibrational constants are deduced for all of the mixed states, leading to deperturbed values for v1, and of 1004.68(2), 0.000 713(2), and 0.000 348(2) cm-1, respectively. The Be value is found to be 0.310 820(2) cm-1, yielding an equilibrium bond length re of 141.7333(4) pm that is, within experimental error, identical to the value of 141.7339(3) pm reported previously for 34S18O3. With this work, precise and accurate spectroscopic constants have now been determined in a systematic and consistent manner for all the fundamental vibrational modes of the sulfur trioxide D3h isotopomeric forms 32S16O3, 34S16O3, 32S18O3, and 34S18O3.

  2. High Resolution Observations of Magnetic Elements in the Visible and the Infrared

    NASA Astrophysics Data System (ADS)

    Rimmele, T.; Lin, H.

    1997-05-01

    High resolution observations of magnetic elements in the visible and infrared. We report on multi-wavelength observations of plage regions obtained at the Vacuum Tower Telescope at NSO/Sac-Peak . The data set includes high resolution images in the G-band (0.43 mu ), the visible (0.69 mu ) continuum and the infrared (1.6 mu ) continuum. In addition, deep integration full Stokes vector measurements in the FeI 1.56 mu lines, as well as, Ca-K slit jaw images were obtained. G-band bright points, which are observed mostly in supergranular lanes, are also visible as bright points in the visible continuum. Although the infrared observations are limited in spatial resolution to about 0."4 (the diffraction limit of the VTT/SP), the data indicates that G-band bright points are also bright in the infrared (1.6 mu ). We also discuss and compare properties of magnetic knots and small pores. Magnetic knots, which recently also have been referred to as azimuth centers (Lites et al. 1994), by definition show no darkening in individual continuum images. However, in the time-averaged imaging data, and in particular in the infrared, azimuth centers appear as dark features, which are clearly distinguishable from the quiet sun background. In the infrared most azimuth centers are visible as dark features even in individual snapshots. Many azimuth centers as well as some small pores are surrounded by a highly structured bright ring, which becomes more apparent with increasing height of formation. Results of the polarization analysis in the FeI 1.56 mu lines, including measurements of weak fields, are presented as well.

  3. High-resolution infrared detector and its electronic unit for space application

    NASA Astrophysics Data System (ADS)

    Meftah, M.; Montmessin, F.; Korablev, O.; Trokhimovsky, A.; Poiet, G.; Bel, J.-B.

    2015-05-01

    High-resolution infrared detector is used extensively for military and civilian purposes. Military applications include target acquisition, surveillance, night vision, and tracking. Civilian applications include, among others, scientific observations. For our space systems, we want to use the products developed by SOFRADIR Company. Thus, we have developed a space electronic unit that is used to control the high-resolution SCORPIO-MW infrared detector, which has a format of 640×512 pixels with 15μm×15μm pixel pitch. The detector within microelectronics based on infrared mid-wave (MW) complementary metal oxide semiconductors (CMOS) uses a micro-cooler in order to keep its temperature around 100 K. The standard wavelength range (3 to 5μm) is adapted to the 2.2 to 4.3μm wavelength range thanks to adaptation of the optical interface of the detector and with an antireflection coating. With our electronic system, we can acquire 3 images per second. To increase the signal to noise ratio, we have the opportunity to make a summation of 15 frames per image. Through this article, we will describe the space electronic system that we have developed in order to achieve space observations (e.g. Atmospheric Chemistry Suite package for ExoMars Trace Gas Orbiter).

  4. Understanding AGB evolution in Galactic bulge stars from high-resolution infrared spectroscopy

    NASA Astrophysics Data System (ADS)

    Uttenthaler, S.; Blommaert, J. A. D. L.; Wood, P. R.; Lebzelter, T.; Aringer, B.; Schultheis, M.; Ryde, N.

    2015-08-01

    An analysis of high-resolution near-infrared spectra of a sample of 45 asymptotic giant branch (AGB) stars towards the Galactic bulge is presented. The sample consists of two subsamples, a larger one in the inner and intermediate bulge, and a smaller one in the outer bulge. The data are analysed with the help of hydrostatic model atmospheres and spectral synthesis. We derive the radial velocity of all stars, and the atmospheric chemical mix ([Fe/H], C/O, 12C/13C, Al, Si, Ti, and Y) where possible. Our ability to model the spectra is mainly limited by the (in)completeness of atomic and molecular line lists, at least for temperatures down to Teff ≈ 3100 K. We find that the subsample in the inner and intermediate bulge is quite homogeneous, with a slightly subsolar mean metallicity and only few stars with supersolar metallicity, in agreement with previous studies of non-variable M-type giants in the bulge. All sample stars are oxygen-rich, C/O < 1.0. The C/O and carbon isotopic ratios suggest that third dredge-up (3DUP) is absent among the sample stars, except for two stars in the outer bulge that are known to contain technetium. These stars are also more metal-poor than the stars in the intermediate or inner bulge. Current stellar masses are determined from linear pulsation models. The masses, metallicities and 3DUP behaviour are compared to AGB evolutionary models. We conclude that these models are partly in conflict with our observations. Furthermore, we conclude that the stars in the inner and intermediate bulge belong to a more metal-rich population that follows bar-like kinematics, whereas the stars in the outer bulge belong to the metal-poor, spheroidal bulge population.

  5. A High Resolution Microprobe Study of EETA79001 Lithology C

    NASA Technical Reports Server (NTRS)

    Schrader, Christian M.; Cohen, B. A.; Donovan, J. J.; Vicenzi, E. P.

    2010-01-01

    Antarctic meteorite EETA79001 has received substantial attention for possibly containing a component of Martian soil in its impact glass (Lithology C) [1]. The composition of Martian soil can illuminate near-surface processes such as impact gardening [2] and hydrothermal and volcanic activity [3,4]. Impact melts in meteorites represent our most direct samples of Martian regolith. We present the initial findings from a high-resolution electron microprobe study of Lithology C from Martian meteorite EETA79001. As this study develops we aim to extract details of a potential soil composition and to examine Martian surface processes using elemental ratios and correlations.

  6. Mitigating atmospheric effects in high-resolution infra-red surveillance imagery with bispectral speckle imaging

    SciTech Connect

    Carrano, C J

    2006-05-30

    Obtaining a high-resolution image of an object or scene from a long distance away can be very problematic, even with the best optical system. This is because atmospheric blurring and distortion will limit the resolution and contrast of high-resolution imaging systems with substantial sized apertures over horizontal and slant paths. Much of the horizontal and slant-path surveillance imagery we have previously collected and successfully enhanced has been collected at visible wavelengths where atmospheric effects are the strongest. Imaging at longer wavelengths has the benefit of seeing through obscurants or even at night, but even though the atmospheric effects are noticeably reduced, they are nevertheless present, especially near the ground. This paper will describe our recent work on enhanced infrared (IR) surveillance using bispectral speckle imaging. Bispectral speckle imaging in this context is an image postprocessing algorithm that aims to solve the atmospheric blurring and distortion problem of imaging through horizontal or slant path turbulence. A review of the algorithm as well as descriptions of the IR camera and optical systems used in our data collections will be given. Examples of horizontal and slant-path imagery before and after speckle processing will also be presented to demonstrate the resolution improvement gained by the processing. Comparisons of IR imagery to visible wavelength imagery of the same target under the same conditions will be shown to demonstrate the tradeoffs of going to longer wavelengths.

  7. Fusing electro-optic and infrared signals for high resolution night images

    NASA Astrophysics Data System (ADS)

    Huang, Xiaopeng; Netravali, Ravi; Man, Hong; Lawrence, Victor

    2012-03-01

    Electro-optic (EO) images exhibit the properties of high resolution and low noise level, while it is a challenge to distinguish objects at night through infrared (IR) images, especially for objects with a similar temperature. Therefore, we will propose a novel framework of IR image enhancement based on the information (e.g., edge) from EO images, which will result in high resolution IR images and help us distinguish objects at night. Superimposing the detected edge of the EO image onto the corresponding transformed IR image is our principal idea for the proposed framework. In this framework, we will adopt the theoretical point spread function (PSF) proposed by Russell C. Hardie et al. for our IR image system, which is contributed by the modulation transfer function (MTF) of a uniform detector array and the incoherent optical transfer function (OTF) of diffraction-limited optics. In addition, we will design an inverse filter in terms of the proposed PSF to conduct the IR image transformation. The framework requires four main steps, which are inverse filter-based IR image transformation, EO image edge detection, registration and superimposing of the obtained image pair. Simulation results will show the superimposed IR images.

  8. WAHRSIS: A low-cost high-resolution whole sky imager with near-infrared capabilities

    NASA Astrophysics Data System (ADS)

    Dev, Soumyabrata; Savoy, Florian M.; Lee, Yee Hui; Winkler, Stefan

    2014-05-01

    Cloud imaging using ground-based whole sky imagers is essential for a fine-grained understanding of cloud formations, which can be useful in many applications. Some such imagers are available commercially, but their cost is relatively high, and their flexibility is limited. Therefore, we built a new daytime Whole Sky Imager (WSI) called Wide Angle High-Resolution Sky Imaging System (WAHRSIS). The strengths of our new design are its simplicity, low manufacturing cost, and high image resolution. Our imager captures the entire hemisphere in a single picture using a digital camera with a Fish-eye lens. The camera was modified to capture light across the visible and near-infrared spectral ranges. This paper describes the design of the device as well as the geometric and radiometric calibration of the imaging system.

  9. High-resolution synchrotron far infrared spectroscopy of thionyl chloride: Analysis of the ν3 and ν6 fundamental bands

    NASA Astrophysics Data System (ADS)

    Martin-Drumel, Marie-Aline; Mouret, Gaël; Pirali, Olivier; Cuisset, Arnaud

    2015-09-01

    Thionyl chloride (SOCl2) is a volatile inorganic compounds used extensively in industry. Its monitoring in gas phase is critical both for environmental and defense concerns. Previous high-resolution gas phase spectroscopic studies were focused on the microwave region (below 40 GHz) and no rotationally-resolved study of the IR spectrum has been reported to date. We present in this article a rovibrational analysis of the two lowest frequency infrared active bending modes ν3 and ν6 of SOCl2. By means of synchrotron based Fourier-Transform far-infrared spectroscopy on the AILES beamline of the SOLEIL facility, the spectra of the symmetric ν3 (346 cm-1) and asymmetric ν6 (283 cm-1) fundamental bands have been rotationally resolved and analyzed.

  10. New High Resolution Spectroscopy Studies of Methyl Nitrite CH_3ONO

    NASA Astrophysics Data System (ADS)

    Sironneau, V.; Chelin, P.; Tchana, F. Kwabia; Kleiner, I.; Orphal, J.; Pirali, O.; Guillemin, J.-C.; Margules, L.; Motiyenko, R.; Cooke, S.; Youngblood, W. J.; Agnew, A.; Dewberry, C. T.

    2010-06-01

    Methyl nitrite CH3ONO is an important species in atmospheric chemistry involved in photochemical oxidation of volatile organic compounds. The cis conformer (more stable by about 298 cm-1) has a high internal rotation potential barrier for the methyl group (731 cm-1) whereas for the trans conformer the barrier to internal rotation is extremely low (10 cm-1), leading to large internal rotation splittings. Only one high resolution infrared study was performed prior to this study. For the first time, high-resolution spectrum of CH3ONO was recorded in the far infrared region (30-500 cm-1) using the synchrotron SOLEIL far-infrared beamline (AILES) and a Fourier transform (FT) spectrometer. Some 987 lines were assigned for the cis isomer up to J=65 and combined with 66 previously recorded microwave lines. In addition, high-resolution spectrum of the ν9 band of the cis isomer around 627.9 cm-1 was also recorded using the FT spectrometer at LISA. New microwave data is currently recorded to improve the knowledge of both the cis and trans ground state parameters. P. N. Gosh, A. Bauder and Hs. H. Gunthard, Chem. Phys. 53, 39-60 (1980) P. H. Turner, M. J. Corkill, and A. P. Cox, J. Chem. Phys. 83, 1473-1482 1979) L. M. Goss, C. D. Mortensen and T. A. Blake, J. Mol. Spectrosc., 225, 182-188 (2004)

  11. Surface Temperature Mapping of the University of Northern Iowa Campus Using High Resolution Thermal Infrared Aerial Imageries

    PubMed Central

    Savelyev, Alexander; Sugumaran, Ramanathan

    2008-01-01

    The goal of this project was to map the surface temperature of the University of Northern Iowa campus using high-resolution thermal infrared aerial imageries. A thermal camera with a spectral bandwidth of 3.0-5.0 μm was flown at the average altitude of 600 m, achieving ground resolution of 29 cm. Ground control data was used to construct the pixel- to-temperature conversion model, which was later used to produce temperature maps of the entire campus and also for validation of the model. The temperature map then was used to assess the building rooftop conditions and steam line faults in the study area. Assessment of the temperature map revealed a number of building structures that may be subject to insulation improvement due to their high surface temperatures leaks. Several hot spots were also identified on the campus for steam pipelines faults. High-resolution thermal infrared imagery proved highly effective tool for precise heat anomaly detection on the campus, and it can be used by university facility services for effective future maintenance of buildings and grounds.

  12. Synchrotron-based rotationally resolved high-resolution FTIR spectroscopy of azulene and the unidentified infrared bands of astronomy.

    PubMed

    Albert, Sieghard; Lerch, Philippe; Quack, Martin

    2013-10-01

    Chasing the unidentified IR bands: The first rotationally resolved high-resolution infrared spectrum of azulene is reported using synchrotron Fourier transform infrared spectroscopy including a rovibrational analysis of the out-of-plane fundamental ν44. Comparison of azulene, naphthalene, indole, and biphenyl infrared bands leads to coincidences with UIR bands at 12.8 μm with naphthalene and at 13.55 and 14.6 μm with biphenyl bands, but excluding azulene as a strong absorber.

  13. Performance of the HIRS/2 instrument on TIROS-N. [High Resolution Infrared Radiation Sounder

    NASA Technical Reports Server (NTRS)

    Koenig, E. W.

    1980-01-01

    The High Resolution Infrared Radiation Sounder (HIRS/2) was developed and flown on the TIROS-N satellite as one means of obtaining atmospheric vertical profile information. The HIRS/2 receives visible and infrared spectrum radiation through a single telescope and selects 20 narrow radiation channels by means of a rotating filter wheel. A passive radiant cooler provides an operating temperature of 106.7 K for the HgCdTe and InSb detectors while the visible detector operates at instrument frame temperature. Low noise amplifiers and digital processing provide 13 bit data for spacecraft data multiplexing and transmission. The qualities of system performance that determine sounding capability are the dynamic range of data collection, the noise equivalent radiance of the system, the registration of the air columns sampled in each channel and the ability to upgrade the calibration of the instrument to maintain the performance standard throughout life. The basic features, operating characteristics and performance of the instrument in test are described. Early orbital information from the TIROS-N launched on October 13, 1978 is given and some observations on system quality are made.

  14. High resolution spectroscopic study of Be10Lambda;

    NASA Astrophysics Data System (ADS)

    Gogami, T.; Chen, C.; Kawama, D.; Achenbach, P.; Ahmidouch, A.; Albayrak, I.; Androic, D.; Asaturyan, A.; Asaturyan, R.; Ates, O.; Baturin, P.; Badui, R.; Boeglin, W.; Bono, J.; Brash, E.; Carter, P.; Chiba, A.; Christy, E.; Danagoulian, S.; de Leo, R.; Doi, D.; Elaasar, M.; Ent, R.; Fujii, Y.; Fujita, M.; Furic, M.; Gabrielyan, M.; Gan, L.; Garibaldi, F.; Gaskell, D.; Gasparian, A.; Han, Y.; Hashimoto, O.; Horn, T.; Hu, B.; Hungerford, Ed. V.; Jones, M.; Kanda, H.; Kaneta, M.; Kato, S.; Kawai, M.; Khanal, H.; Kohl, M.; Liyanage, A.; Luo, W.; Maeda, K.; Margaryan, A.; Markowitz, P.; Maruta, T.; Matsumura, A.; Maxwell, V.; Mkrtchyan, A.; Mkrtchyan, H.; Nagao, S.; Nakamura, S. N.; Narayan, A.; Neville, C.; Niculescu, G.; Niculescu, M. I.; Nunez, A.; Nuruzzaman, Okayasu, Y.; Petkovic, T.; Pochodzalla, J.; Qiu, X.; Reinhold, J.; Rodriguez, V. M.; Samanta, C.; Sawatzky, B.; Seva, T.; Shichijo, A.; Tadevosyan, V.; Tang, L.; Taniya, N.; Tsukada, K.; Veilleux, M.; Vulcan, W.; Wesselmann, F. R.; Wood, S. A.; Yamamoto, T.; Ya, L.; Ye, Z.; Yokota, K.; Yuan, L.; Zhamkochyan, S.; Zhu, L.; Hksjlab E05-115 Collaboration

    2016-03-01

    Spectroscopy of a Be10Lambda; hypernucleus was carried out at JLab Hall C using the (e ,e'K+) reaction. A new magnetic spectrometer system (SPL+HES+HKS), specifically designed for high resolution hypernuclear spectroscopy, was used to obtain an energy spectrum with a resolution of ˜0.78 MeV (FWHM). The well-calibrated spectrometer system of the present experiment using p (e ,e'K+)Λ ,Σ0 reactions allowed us to determine the energy levels; and the binding energy of the ground-state peak (mixture of 1- and 2- states) was found to be BΛ=8.55 ±0.07 (stat . ) ±0.11 (sys . ) MeV. The result indicates that the ground-state energy is shallower than that of an emulsion study by about 0.5 MeV which provides valuable experimental information on the charge symmetry breaking effect in the Λ N interaction.

  15. High resolution surface wave dispersion studies in China

    SciTech Connect

    Jones, L.E.; Patton, H.J.

    1997-11-01

    The Los Alamos National Laboratory regional calibration project is actively assembling a database of surface-wave dispersion information for China and surrounding areas. As part of the effort to characterize surface wave dispersion in China, we integrate prior long period results from the University of Colorado with our shorter period dispersion measurements in a high resolution survey of key monitoring areas. Focusing on western China initially, we employ broadband data recorded on CDSN stations, and regional events (m{sub b} 4 and above). Our approach is twofold, employing path specific calibration of key stations and well-recorded reference events, and tomographic inference to provide group velocity curves for regions with sparse station distribution and little seismic activity. Initial dispersion studies at Chinese stations WMQ and LZH show substantial azimuthal variation in dispersion, reinforcing the need for careful determination of source regions for path-specific calibration.

  16. HIGH-RESOLUTION, DIFFERENTIAL, NEAR-INFRARED TRANSMISSION SPECTROSCOPY OF GJ 1214b

    SciTech Connect

    Crossfield, I. J. M.; Hansen, Brad M. S.; Barman, Travis

    2011-08-01

    The nearby star GJ 1214 hosts a planet intermediate in radius and mass between Earth and Neptune, resulting in some uncertainty as to its nature. We have observed this planet, GJ 1214b, during transit with the high-resolution, near-infrared NIRSPEC spectrograph on the Keck II telescope, in order to characterize the planet's atmosphere. By cross-correlating the spectral changes through transit with a suite of theoretical atmosphere models, we search for variations associated with absorption in the planet atmosphere. Our observations are sufficient to rule out tested model atmospheres with wavelength-dependent transit depth variations {approx}> 5 x 10{sup -4} over the wavelength range 2.1-2.4 {mu}m. Our sensitivity is limited by variable slit loss and telluric transmission effects. We find no positive signatures but successfully rule out a number of plausible atmospheric models, including the default assumption of a gaseous, H-dominated atmosphere in chemical equilibrium. Such an atmosphere can be made consistent if the absorption due to methane is reduced. Clouds can also render such an atmosphere consistent with our observations, but only if they lie higher in the atmosphere than indicated by recent optical and infrared measurements. When taken in concert with other observational constraints, our results support a model in which the atmosphere of GJ 1214b contains significant H and He, but where CH{sub 4} is depleted. If this depletion is the result of photochemical processes, it may also produce a haze that suppresses spectral features in the optical.

  17. Multi-Sensor Fusion of Infrared and Electro-Optic Signals for High Resolution Night Images

    PubMed Central

    Huang, Xiaopeng; Netravali, Ravi; Man, Hong; Lawrence, Victor

    2012-01-01

    Electro-optic (EO) image sensors exhibit the properties of high resolution and low noise level at daytime, but they do not work in dark environments. Infrared (IR) image sensors exhibit poor resolution and cannot separate objects with similar temperature. Therefore, we propose a novel framework of IR image enhancement based on the information (e.g., edge) from EO images, which improves the resolution of IR images and helps us distinguish objects at night. Our framework superimposing/blending the edges of the EO image onto the corresponding transformed IR image improves their resolution. In this framework, we adopt the theoretical point spread function (PSF) proposed by Hardie et al. for the IR image, which has the modulation transfer function (MTF) of a uniform detector array and the incoherent optical transfer function (OTF) of diffraction-limited optics. In addition, we design an inverse filter for the proposed PSF and use it for the IR image transformation. The framework requires four main steps: (1) inverse filter-based IR image transformation; (2) EO image edge detection; (3) registration; and (4) blending/superimposing of the obtained image pair. Simulation results show both blended and superimposed IR images, and demonstrate that blended IR images have better quality over the superimposed images. Additionally, based on the same steps, simulation result shows a blended IR image of better quality when only the original IR image is available. PMID:23112602

  18. Estimation of Venus wind velocities from high-resolution infrared spectra. Ph.D. Thesis

    NASA Technical Reports Server (NTRS)

    Smith, M. A. H.

    1978-01-01

    Zonal velocity profiles in the Venus atmosphere above the clouds were estimated from measured asymmetries of HCl and HF infrared absorption lines in high-resolution Fourier interferometer spectra of the planet. These asymmetries are caused by both pressure-induced shifts in the positions of the hydrogen-halide lines perturbed by CO2 and Doppler shifts due to atmospheric motions. Particularly in the case of the HCl 2-0 band, the effects of the two types of line shifts can be easily isolated, making it possible to estimate a profile of average Venus equatorial zonal velocity as a function of pressure in the region roughly 60 to 70 km above the surface of the planet. The mean profiles obtained show strong vertical shear in the Venus zonal winds near the cloud-top level, and both the magnitude and direction of winds at all levels in this region appear to vary greatly with longitude relative to the sub-solar point.

  19. Infrared High-resolution Integrated Light Spectral Analyses of M31 Globular Clusters from APOGEE

    NASA Astrophysics Data System (ADS)

    Sakari, Charli M.; Shetrone, Matthew D.; Schiavon, Ricardo P.; Bizyaev, Dmitry; Allende Prieto, Carlos; Beers, Timothy C.; Caldwell, Nelson; García-Hernández, D. A.; Lucatello, Sara; Majewski, Steven; O'Connell, Robert W.; Pan, Kaike; Strader, Jay

    2016-10-01

    Chemical abundances are presented for 25 M31 globular clusters (GCs), based on moderately high resolution (R = 22,500) H-band integrated light (IL) spectra from the Apache Point Observatory Galactic Evolution Experiment (APOGEE). Infrared (IR) spectra offer lines from new elements, lines of different strengths, and lines at higher excitation potentials compared to the optical. Integrated abundances of C, N, and O are derived from CO, CN, and OH molecular features, while Fe, Na, Mg, Al, Si, K, Ca, and Ti abundances are derived from atomic features. These abundances are compared to previous results from the optical, demonstrating the validity and value of IR IL analyses. The CNO abundances are consistent with typical tip of the red giant branch stellar abundances but are systematically offset from optical Lick index abundances. With a few exceptions, the other abundances agree between the optical and the IR within the 1σ uncertainties. The first integrated K abundances are also presented and demonstrate that K tracks the α elements. The combination of IR and optical abundances allows better determinations of GC properties and enables probes of the multiple populations in extragalactic GCs. In particular, the integrated effects of the Na/O anticorrelation can be directly examined for the first time.

  20. Improved fusing infrared and electro-optic signals for high-resolution night images

    NASA Astrophysics Data System (ADS)

    Huang, Xiaopeng; Netravali, Ravi; Man, Hong; Lawrence, Victor

    2012-06-01

    Electro-optic (EO) images exhibit the properties of high resolution and low noise level, while it is a challenge to distinguish objects with infrared (IR), especially for objects with similar temperatures. In earlier work, we proposed a novel framework for IR image enhancement based on the information (e.g., edge) from EO images. Our framework superimposed the detected edges of the EO image with the corresponding transformed IR image. Obviously, this framework resulted in better resolution IR images that help distinguish objects at night. For our IR image system, we used the theoretical point spread function (PSF) proposed by Russell C. Hardie et al., which is composed of the modulation transfer function (MTF) of a uniform detector array and the incoherent optical transfer function (OTF) of diffraction-limited optics. In addition, we designed an inverse filter based on the proposed PSF to transform the IR image. In this paper, blending the detected edge of the EO image with the corresponding transformed IR image and the original IR image is the principal idea for improving the previous framework. This improved framework requires four main steps: (1) inverse filter-based IR image transformation, (2) image edge detection, (3) images registration, and (4) blending of the corresponding images. Simulation results show that blended IR images have better quality over the superimposed images that were generated under the previous framework. Based on the same steps, the simulation result shows a blended IR image of better quality when only the original IR image is available.

  1. Multi-sensor fusion of infrared and electro-optic signals for high resolution night images.

    PubMed

    Huang, Xiaopeng; Netravali, Ravi; Man, Hong; Lawrence, Victor

    2012-01-01

    Electro-optic (EO) image sensors exhibit the properties of high resolution and low noise level at daytime, but they do not work in dark environments. Infrared (IR) image sensors exhibit poor resolution and cannot separate objects with similar temperature. Therefore, we propose a novel framework of IR image enhancement based on the information (e.g., edge) from EO images, which improves the resolution of IR images and helps us distinguish objects at night. Our framework superimposing/blending the edges of the EO image onto the corresponding transformed IR image improves their resolution. In this framework, we adopt the theoretical point spread function (PSF) proposed by Hardie et al. for the IR image, which has the modulation transfer function (MTF) of a uniform detector array and the incoherent optical transfer function (OTF) of diffraction-limited optics. In addition, we design an inverse filter for the proposed PSF and use it for the IR image transformation. The framework requires four main steps: (1) inverse filter-based IR image transformation; (2) EO image edge detection; (3) registration; and (4) blending/superimposing of the obtained image pair. Simulation results show both blended and superimposed IR images, and demonstrate that blended IR images have better quality over the superimposed images. Additionally, based on the same steps, simulation result shows a blended IR image of better quality when only the original IR image is available.

  2. High-Resolution NMR Studies of Human Tissue Factor

    PubMed Central

    Nuzzio, Kristin M.; Watt, Eric D.; Boettcher, John M.; Gajsiewicz, Joshua M.; Morrissey, James H.; Rienstra, Chad M.

    2016-01-01

    In normal hemostasis, the blood clotting cascade is initiated when factor VIIa (fVIIa, other clotting factors are named similarly) binds to the integral membrane protein, human tissue factor (TF). The TF/fVIIa complex in turn activates fX and fIX, eventually concluding with clot formation. Several X-ray crystal structures of the soluble extracellular domain of TF (sTF) exist; however, these structures are missing electron density in functionally relevant regions of the protein. In this context, NMR can provide complementary structural information as well as dynamic insights into enzyme activity. The resolution and sensitivity for NMR studies are greatly enhanced by the ability to prepare multiple milligrams of protein with various isotopic labeling patterns. Here, we demonstrate high-yield production of several isotopically labeled forms of recombinant sTF, allowing for high-resolution NMR studies both in the solid and solution state. We also report solution NMR spectra at sub-mM concentrations of sTF, ensuring the presence of dispersed monomer, as well as the first solid-state NMR spectra of sTF. Our improved sample preparation and precipitation conditions have enabled the acquisition of multidimensional NMR data sets for TF chemical shift assignment and provide a benchmark for TF structure elucidation. PMID:27657719

  3. Preliminary design study of a high resolution meteor radar

    NASA Technical Reports Server (NTRS)

    Lee, W.; Geller, M. A.

    1973-01-01

    A design study for a high resolution meteor radar system is carried out with the objective of measuring upper atmospheric winds and particularly studying short period atmospheric waves in the 80 to 120 km altitude region. The transmitter that is to be used emits a peak power of 4 Mw. The system is designed to measure the wind velocity and height of a meteor trail very accurately. This is achieved using a specially developed digital reduction procedure to determine wind velocity and range together with an interferometer for measuring both the azimuth and elevation angles of the region with a long baseline vernier measurement being used to refine the elevation angle measurement. The resultant accuracies are calculated to be + or - 0.9 m/s for the wind, + or - 230 m for the range and + or - 0.12 deg for the elevation angle, giving a height accuracy of + or - 375 m. The prospects for further development of this system are also discussed.

  4. New design studies for TRIUMF's ARIEL High Resolution Separator

    NASA Astrophysics Data System (ADS)

    Maloney, J. A.; Baartman, R.; Marchetto, M.

    2016-06-01

    As part of its new Advanced Rare IsotopE Laboratory (ARIEL), TRIUMF is designing a novel High Resolution Separator (HRS) (Maloney et al., 2015) to separate rare isotopes. The HRS has a 180° bend, separated into two 90° magnetic dipoles, bend radius 1.2 m, with an electrostatic multipole corrector between them. Second order correction comes mainly from the dipole edge curvatures, but is intended to be fine-tuned with a sextupole component and a small octupole component in the multipole. This combination is designed to achieve 1:20,000 resolution for a 3 μm (horizontal) and 6 μm (vertical) emittance. A design for the HRS dipole magnets achieves both radial and integral flatness goals of <10-5. A review of the optical design for the HRS is presented, including the study of limiting factors affecting separation, matching and aberration correction. Field simulations from the OPERA-3D (OPERA) [2] models of the dipole magnets are used in COSY Infinity (COSY) (Berz and Makino, 2005) [3] to find and optimize the transfer maps to 3rd order and study residual nonlinearities to 8th order.

  5. High resolution spectroscopic study of BeΛ10

    DOE PAGES

    Gogami, T.; Chen, C.; Kawama, D.; Achenbach, P.; Ahmidouch, A.; Albayrak, I.; Androic, D.; Asaturyan, A.; Asaturyan, R.; Ates, O.; et al

    2016-03-10

    Spectroscopy of amore » $$^{10}_{\\Lambda}$$Be hypernucleus was carried out at JLab Hall C using the $$(e,e^{\\prime}K^{+})$$ reaction. A new magnetic spectrometer system (SPL+HES+HKS), specifically designed for high resolution hypernuclear spectroscopy, was used to obtain an energy spectrum with a resolution of 0.78 MeV (FWHM). The well-calibrated spectrometer system of the present experiment using the $$p(e,e^{\\prime}K^{+})\\Lambda,\\Sigma^{0}$$ reactions allowed us to determine the energy levels, and the binding energy of the ground state peak (mixture of 1$$^{-}$$ and 2$$^{-}$$ states) was obtained to be B$$_{\\Lambda}$$=8.55$$\\pm$$0.07(stat.)$$\\pm$$0.11(sys.) MeV. Furthermore, the result indicates that the ground state energy is shallower than that of an emulsion study by about 0.5 MeV which provides valuable experimental information on charge symmetry breaking effect in the $$\\Lambda N$$ interaction.« less

  6. High Resolution Studies of Electron Attachment to Molecules

    SciTech Connect

    Braun, M.; Ruf, M.-W.; Hotop, H.; Fabrikant, I. I.

    2009-05-02

    In this paper, we survey recent progress in studies of anion formation via (dissociative) electron attachment (DEA) to simple molecules, as measured with the laser photoelectron attachment (LPA) method at high resolution. The limiting (E{yields}0) threshold behavior of the cross sections is elucidated for s-wave and p-wave attachment. Cusps at onsets for vibrational excitation (VE), due to interaction of the DEA channnel with the VE channel, are clearly detected, and vibrational Feshbach resonances just below vibrational onsets are observed for molecules with sufficiently strong long-range attraction between the electron and the molecule. From the LPA anion yields, absolute DEA cross sections (energy range typically E = 0.001-2 eV) are determined with reference to rate coefficients for thermal electron attachment at the appropriate gas temperature (normally T{sub G} = 300 K). The experimental data are compared with theoretical cross sections, calculated within the framework of an R-matrix or an Effective Range theory approach.

  7. High-Resolution Infrared Spectroscopy of Carbon-Sulfur Chains: II. C_5S and SC_5S

    NASA Astrophysics Data System (ADS)

    Thorwirth, Sven; Salomon, Thomas; Dudek, John B.

    2016-06-01

    Unbiased high-resolution infrared survey scans of the ablation products from carbon-sulfur targets in the 2100 to 2150 cm-1 regime reveal two bands previously not observed in the gas phase. On the basis of comparison against laboratory matrix-isolation work and new high-level quantum-chemical calculations these bands are attributed to the linear C_5S and SC_5S clusters. While polar C_5S was studied earlier using Fourier-transform microwave techniques, the present work marks the first gas-phase spectroscopic detection of SC_5S. H. Wang, J. Szczepanski, P. Brucat, and M. Vala 2005, Int. J. Quant. Chem. 102, 795 Y. Kasai, K. Obi, Y. Ohshima, Y. Hirahara, Y. Endo, K. Kawaguchi, and A. Murakami 1993, ApJ 410, L45 V. D. Gordon, M. C. McCarthy, A. J. Apponi, and P. Thaddeus 2001, ApJS 134, 311

  8. Water ingress detection in honeycomb sandwich panels by passive infrared thermography using a high-resolution thermal imaging camera

    NASA Astrophysics Data System (ADS)

    Ibarra-Castanedo, C.; Brault, L.; Marcotte, F.; Genest, M.; Farley, V.; Maldague, X.

    2012-06-01

    Water ingress in honeycomb structures is of great concern for the civil and military aerospace industries. Pressure and temperature variations during take-off and landing produce considerable stress on aircraft structures, promoting moisture ingress (by diffusion through fibers or by direct ingress through voids, cracks or unsealed joints) into the core. The presence of water (or other fluids such as kerosene, hydraulic fluid and de-icing agents) in any of its forms (gas vapor, liquid or ice) promotes corrosion, cell breakage, and induce composite layer delaminations and skin disbonds. In this study, testing specimens were produced from unserviceable parts from military aircraft. In order to simulate atmospheric conditions during landing, selected core areas were filled with measured quantities of water and then frozen in a cold chamber. The specimens were then removed from the chamber and monitored for over 20 minutes as they warm up using a cooled high-resolution infrared camera. Results have shown that detection and quantification of water ingress on honeycomb sandwich structures by passive infrared thermography is possible using a HD mid-wave infrared cameras for volumes of water as low as 0.2 ml and from a distance as far as 20 m from the target.

  9. Far Infrared High Resolution Synchrotron FTIR Spectroscopy of the Low Frequency Bending Modes of Dmso

    NASA Astrophysics Data System (ADS)

    Cuisset, Arnaud; Smirnova, Irina; Bocquet, Robin; Hindle, Francis; Mouret, Gael; Sadovskii, Dmitrii A.; Pirali, Olivier; Roy, Pascale

    2010-06-01

    In addition to its importance for industrial and environmental studies, the monitoring of DiMethylSulfOxyde (DMSO, (CH_3)_2SO) concentrations is of considerable interest for civil protection. The existing high resolution gas phase spectroscopic data of DMSO only concerned the pure rotational transitions in the ground state. In the Far-IR domain, the low-frequency rovibrational transitions have never previously resolved. The high brightness of the AILES beamline of the synchrotron SOLEIL and the instrumental sensitivity provided by the multipass cell allowed to measure for the first time these transitions. 1581 A-type and C-type transitions in the ν11 band have been assigned and 25 molecular constants of Watson's s-form hamiltonian developed to degree 8 have been fitted within the experimental accuracy. The use of then synchrotron radiation has opened many possibilities for new spectroscopic studies. Together with several other recent studies, our successful measurement and analysis of DMSO convincingly demonstrates the potential of the AILES beamline for high resolution FIR spectroscopy. Thus our present work is just at the beginning of unraveling the rovibrational structure of low frequency bending and torsional vibrational states of DMSO and yielding important comprehensive structural and spectroscopic information on this molecule. L. Margules, R. A. Motienko, E. A. Alekseev, J. Demaison, J. Molec. Spectrosc., 260(23),2009 V. Typke, M. Dakkouri, J. Molec. Struct., 599(177),2001 A. Cuisset, L. Nanobashvili, I. Smirnova, R. Bocquet, F. Hindle, G. Mouret, O. Pirali, P. Roy, D. Sadovskii, Chem. Phys. Lett., accepted for publication

  10. Human enamel structure studied by high resolution electron microscopy

    SciTech Connect

    Wen, S.L. )

    1989-01-01

    Human enamel structural features are characterized by high resolution electron microscopy. The human enamel consists of polycrystals with a structure similar to Ca10(PO4)6(OH)2. This article describes the structural features of human enamel crystal at atomic and nanometer level. Besides the structural description, a great number of high resolution images are included. Research into the carious process in human enamel is very important for human beings. This article firstly describes the initiation of caries in enamel crystal at atomic and unit-cell level and secondly describes the further steps of caries with structural and chemical demineralization. The demineralization in fact, is the origin of caries in human enamel. The remineralization of carious areas in human enamel has drawn more and more attention as its potential application is realized. This process has been revealed by high resolution electron microscopy in detail in this article. On the other hand, the radiation effects on the structure of human enamel are also characterized by high resolution electron microscopy. In order to reveal this phenomenon clearly, a great number of electron micrographs have been shown, and a physical mechanism is proposed. 26 references.

  11. Analysis of several high-resolution infrared bands of spiropentane, C5H8

    SciTech Connect

    Maki, Arthur G.; Price, Joseph E.; Harzan, J.; Nibler, Joseph W.; Weber, Alfons; Masiello, Tony; Blake, Thomas A.

    2015-06-01

    he high-resolution infrared absorption spectrum of spiropentane (C5H8) has been measured from 200 to 4000 cm 1, and a detailed analysis is presented for eight bands in the region from 700 to 2200 cm 1. Two fundamental perpendicular bands were analyzed, m22 and m24 near 1050 and 780 cm 1, respectively, along with two fundamental parallel bands, m14 and m16 near 1540 and 990 cm1, respectively. Two other fundamentals, m17 and m23, are seen as intense overlapping bands near 880 cm*1 and are Coriolis-coupled, producing a complex mixture in which only P-branch transitions could be tentatively assigned for m17. In addition, three binary combination bands were fit at about 1570, 2082, and 2098 cm*1 which are assigned as either 2m24 or m5 + m16 in the first case, m4 + m22 in the second case, and 2m22 in the latter case. The two l-type resonance constants, q+ and q*, were determined for each of the two perpendicular fundamentals m22 and m24. Those two constants were also responsible for splittings observed in the K = 3 levels of m24. For the ground state the order of the split K = 2 B1/B2 levels has been reversed from that reported previously, based on the measurements and assignments for the m24 band. Rovibrational parameters deduced from the analyses are compared with those obtained from density functional Gaussian calculations at the anharmonic level.

  12. Data Reduction Pipeline for the WIYN High-resolution Infrared Camera

    NASA Astrophysics Data System (ADS)

    Ferguson, Brian A.; Beck, T.

    2010-05-01

    Recently, in November 2008 the WIYN High-resolution InfraRed Camera (WHIRC), mounted on the WIYN 3.5m telescope, was accepted as a general-use instrument supported by the Kitt Peak National Observatory and the WIYN collaboration. WHIRC provides near-IR coverage from 0.9-2.5 microns, resting on the WIYN Tip-Tilt Module (WTTM) port, boasting a strategic field of view (3.3'×3.3') covering most of the WTTM corrected field. Currently, the list of supported near-IR filters include three broad band filters: J, H, Ks, and 10 narrow bands: Low Airglow, He I, Pa β, Pa β ( 4500 km/s), [Fe II], [Fe II] ( 4500 km/s), H2 S(1), Br γ, Br γ ( 4500 km/s), CO. WHIRC has frequently demonstrated seeing-limited performance of approximately 0.5-0.6" FWHM, and as good as 0.3" during exceptional nights. With the full tip-tilt first-order corrections possible with WTTM, WHIRC should typically deliver images with approximately 0.3" FWHM and near-diffraction-limited images (0.20"). An easy to use operational interface has been implemented with the installation of the camera; yet, until now no consistent data reduction scheme has been universally available. We present the first ever stand-alone WHIRC data reduction pipeline written in the publicly available STScI Python (2.5). The pipeline as presented here carries out on-the-fly calibrations, sky-subtraction, flat-fielding, and filter-dependent distortion corrections. An additional alignment algorithm can be implemented for the mosaic combination of dithered images if the user chooses to do so. This pipeline corrects and replaces previous calibration software for the WHIRC instrument: namely the header and WCS correction device, "wprep.cl".

  13. Emerging Trends on the Volatile Chemistry in Comets as Measured with High-Resolution Infrared Spectroscopy

    NASA Astrophysics Data System (ADS)

    Dello Russo, Neil; Kawakita, Hideyo; Vervack, Ronald J., Jr.; Weaver, Harold A.

    2016-10-01

    A systematic analysis of the mixing ratios with respect to H2O for eight species (CH3OH, HCN, NH3, H2CO, C2H2, C2H6, CH4, and CO) measured with high-resolution infrared spectroscopy is presented. Some trends are beginning to emerge when mixing ratios in individual comets are compared to average mixing ratios obtained for all species within the population. The variation in mixing ratios for all measured species is at least an order of magnitude. Overall, Jupiter-family comets are depleted in volatile species with respect to H2O compared to long-period Oort cloud comets, with the most volatile species showing the greatest relative depletion. There is a high positive correlation between the mixing ratios of HCN, C2H6, and CH4, whereas NH3, H2CO, and C2H2 are moderately correlated with each other but generally uncorrelated or show only weak correlation with other species. CO is generally uncorrelated with the other measured species possibly because it has the highest volatility and is therefore more susceptible to thermal evolutionary effects. Molecular mixing ratios for CH3OH, HCN, C2H6, and CH4 show an expected behavior with heliocentric distance suggesting a dominant ice source, whereas there is emerging evidence that the mixing ratios of NH3, H2CO, and C2H2 may increase at small heliocentric distances, suggesting the possibility of additional sources related to the thermal decomposition of organic dust. Although this provides information on the composition of the most volatile grains in comets, it presents an additional difficulty in classifying comet chemistry because most comets within this dataset were only observed over a limited range of heliocentric distance. Optical and infrared comparisons indicate that mixing ratios of daughter species and potential parents from cometary ices are sometimes but not always consistent with one another. This suggests that in many comets there are significant sources of C2 and/or CN from grains, and that the importance of these

  14. High-resolution infrared studies of the v10, v11, v14, and v18 levels of [1.1.1]propellane

    SciTech Connect

    Kirkpatrick, Robynne W.; Masiello, Tony; Martin, Matthew A.; Nibler, Joseph W.; Maki, Arthur; Weber, Alfons; Blake, Thomas A.

    2012-11-15

    This paper is a continuation of earlier work for which the high resolution infrared spectrum of [1.1.1]propellane was measured and its k and l structure resolved for the first time. Here we present results from an analysis of more than 16,000 transitions involving three fundamental bands v10 (E'-A1'), v11 (E'-A1'), v14 (A2''-A1') and two difference bands (v10- v18) (E'-E'') and (v11-v18) (E'-E"). Additional information about v18 was also obtained from the difference band (v15+v18)-v18 (E'-E") and the binary combination band (v15+v18) (E'-A1'). Through the use of the ground state constants reported in an earlier paper [1], rovibrational constants have been determined for all the vibrational states involved in these bands. The rovibrational parameters for the v18(E'') state were obtained from combination-differences and showed no need to include interactions with other states. The v10(E') state analysis was also straight-forward, with only a weak Coriolis interaction with the levels of the v14(A2'') state. The latter levels are much more affected by a strong Coriolis interaction with the levels of the nearby v11(E') state and also by a small but significant interaction with another state, presumably the v16(E'') state, that is not directly observed. Gaussian calculations (B3LYP/cc-pVTZ) computed at the anharmonic level aided the analyses by providing initial values for many of the parameters. These theoretical results generally compare favorably with the final parameter values deduced from the spectral analyses. Finally, evidence was obtained for several level crossings between the rotational levels of the v11 and v14 states and, using a weak coupling term corresponding to a Δk = ±5, Δl = ∓1 matrix element, it was possible to find transitions from the ground state

  15. High-Resolution Infrared Spectrum of the ν_3+ν_8 Combination Band of Jet-Cooled Propyne

    NASA Astrophysics Data System (ADS)

    Zhao, Dongfeng; Linnartz, Harold

    2014-06-01

    Propyne (CH3-C≡CH) is an important molecule in astrophysics and planetary atmospheres, and an important constituent of fuels. Spectroscopic investigation of propyne is also of fundamental interest in intramolecular vibrational redistribution (IVR) dynamics of hydrocarbons. Although extensive spectroscopic studies on this simple organic molecule have been performed, the ν_3+ν_8 band has not been reported before. In this presentation, the high-resolution infrared spectrum of the ν_3+ν_8 combination band of propyne is presented. Continuous-wave cavity ring-down spectroscopy is used to measure this weak infrared band in the 3175 cm-1 region using a supersonic free jet. The rotational analysis of the experimental spectrum results in accurate spectroscopic parameters for the ν_3+ν_8 combination vibrational state. Severe perturbations are found for K = 3 and 4 rotational levels, and are likely due to near-resonant or non-resonant interactions between the ν_3+ν_8 and other vibrational states. Moreover, three parallel-transition type subbands are observed and their analysis is presented as well. D. Zhao, H. Linnartz, Chem. Phys. Lett. (2014), DOI: 10.1016/j.cplett.2014.02.016.

  16. High-resolution satellite imagery for mesoscale meteorological studies

    NASA Technical Reports Server (NTRS)

    Johnson, David B.; Flament, Pierre; Bernstein, Robert L.

    1994-01-01

    In this article high-resolution satellite imagery from a variety of meteorological and environmental satellites is compared. Digital datasets from Geostationary Operational Environmental Satellite (GOES), National Oceanic and Atmospheric Administration (NOAA), Defense Meteorological Satellite Program (DMSP), Landsat, and Satellite Pour l'Observation de la Terre (SPOT) satellites were archived as part of the 1990 Hawaiian Rainband Project (HaRP) and form the basis of the comparisons. During HaRP, GOES geostationary satellite coverage was marginal, so the main emphasis is on the polar-orbiting satellites.

  17. Phase closure retrieval in an infrared-to-visible upconversion interferometer for high resolution astronomical imaging.

    PubMed

    Ceus, Damien; Tonello, Alessandro; Grossard, Ludovic; Delage, Laurent; Reynaud, François; Herrmann, Harald; Sohler, Wolfgang

    2011-04-25

    This paper demonstrates the use of a nonlinear upconversion process to observe an infrared source through a telescope array detecting the interferometric signal in the visible domain. We experimentally demonstrate the possibility to retrieve information on the phase of the object spectrum of an infrared source by using a three-arm upconversion interferometer. We focus our study on the acquisition of phase information of the complex visibility by means of the phase closure technique. In our experimental demonstration, a laboratory binary star with an adjustable photometric ratio is used as a test source. A real time comparison between a standard three-arm interferometer and our new concept using upconversion by sum-frequency generation demonstrates the preservation of phase information which is essential for image reconstruction.

  18. High resolution infrared spectra of H2-Kr and D2-Kr van der Waals complexes.

    PubMed

    McKellar, A R W

    2005-02-22

    Infrared spectra of weakly bound hydrogen-krypton complexes have been studied at high spectral resolution (0.04 cm(-1)) using a long-path (154 m) low temperature (100 K) absorption cell and a Fourier transform spectrometer. In addition to spectra from the regions of the H(2) and D(2) fundamental vibrational bands in the midinfrared, the results also include the region of the pure rotational S(0)(0) transition of H(2) in the far infrared. A total of 219 measured line positions from these spectra have been fully assigned to specific quantum transitions and form the basis for determining a greatly improved semiempirical three-dimensional intermolecular potential energy surface for hydrogen-krypton in an accompanying paper.

  19. Application of High-Resolution Thermal Infrared Remote Sensing and GIS to Assess the Urban Heat Island Effect

    NASA Technical Reports Server (NTRS)

    Lo, C. P.; Quattrochi, D. A.; Luvall, J. C.

    1997-01-01

    Day and night airborne thermal infrared image data at 5 m spatial resolution acquired with the 15-channel (0.45 micron - 12.2 micron) Advanced Thermal and Land Applications Sensor (ATLAS) over Alabama, Huntsville on 7 September, 1994 were used to study changes in the thermal signatures of urban land cover types between day and night. Thermal channel number 13 (9.6 micron - 10.2 micron) data with the best noise-equivalent temperature change (NEAT) of 0.25 C after atmospheric corrections and temperature calibration were selected for use in this analysis. This research also examined the relation between land cover irradiance and vegetation amount, using the Normalized Difference Vegetation Index (NDVI), obtained by ratioing the difference and the sum of the red (channel number 3: 0.60-0.63 micron) and reflected infrared (channel number 6: 0.76-0.90 micron) ATLAS data. Based on the mean radiance values, standard deviations, and NDVI extracted from 351 pairs of polygons of day and night channel number 13 images for the city of Huntsville, a spatial model of warming and cooling characteristics of commercial, residential, agricultural, vegetation, and water features was developed using a GIS approach. There is a strong negative correlation between NDVI and irradiance of residential, agricultural, and vacant/transitional land cover types, indicating that the irradiance of a land cover type is greatly influenced by the amount of vegetation present. The predominance of forests, agricultural, and residential uses associated with varying degrees of tree cover showed great contrasts with commercial and services land cover types in the center of the city, and favors the development of urban heat islands. The high-resolution thermal infrared images match the complexity of the urban environment, and are capable of characterizing accurately the urban land cover types for the spatial modeling of the urban heat island effect using a GIS approach.

  20. A high-resolution fringe printer for studying synthetic holograms

    NASA Astrophysics Data System (ADS)

    Matsushima, K.; Kobayashi, S.; Miyauchi, H.

    2006-02-01

    A high resolution fringe printer developed for driving the research in computer-generated holograms is presented. This fringe printer consists of a rotation drum and a laser diode and is capable of printing elliptical dots of 1.5 times 3.0 microns in diameter on photosensitive films. These dot sizes are approximately converted into resolutions of 17,000dpi × 8,500dpi. The horizontal and vertical angles of viewing-zone of holograms printed by the printer reach 24 and 12 degrees, respectively. The designed maximum scan speed is more than 200mm/s, and at current stage of development, a hologram of approximately 50 mm square can be printed in approximately 2 hours.

  1. High-resolution photoemission study of MgB2.

    PubMed

    Takahashi, T; Sato, T; Souma, S; Muranaka, T; Akimitsu, J

    2001-05-21

    We have performed high-resolution photoemission spectroscopy on MgB2 and observed opening of a superconducting gap with a narrow coherent peak. We found that the superconducting gap is s like with the gap value ( Delta) of 4.5+/-0.3 meV at 15 K. The temperature dependence (15-40 K) of the gap value follows well the BCS form, suggesting that 2Delta/k(B)T(c) at T = 0 is about 3. No pseudogap behavior is observed in the normal state. The present results strongly suggest that MgB2 is categorized into a phonon-mediated BCS superconductor in the weak-coupling regime.

  2. River pollution remediation monitored by optical and infrared high-resolution satellite images.

    PubMed

    Trivero, Paolo; Borasi, Maria; Biamino, Walter; Cavagnero, Marco; Rinaudo, Caterina; Bonansea, Matias; Lanfri, Sofia

    2013-09-01

    The Bormida River Basin, located in the northwestern region of Italy, has been strongly contaminated by the ACNA chemical factory. This factory was in operation from 1892 to 1998, and contamination from the factory has had deleterious consequences on the water quality, agriculture, natural ecosystems and human health. Attempts have been made to remediate the site. The aims of this study were to use high-resolution satellite images combined with a classical remote sensing methodology to monitor vegetation conditions along the Bormida River, both upstream and downstream of the ACNA chemical factory site, and to compare the results obtained at different times before and after the remediation process. The trends of the Normalised Difference Vegetation Index (NDVI) and the Enhanced Vegetation Index (EVI) along the riverbanks are used to assess the effect of water pollution on vegetation. NDVI and EVI values show that the contamination produced by the ACNA factory had less severe effects in the year 2007, when most of the remediation activities were concluded, than in 2006 and 2003. In 2007, the contamination effects were noticeable up to 6 km downstream of the factory, whereas in 2003 and 2006 the influence range was up to about 12 km downstream of the factory. The results of this study show the effectiveness of remediation activities that have been taking place in this area. In addition, the comparison between NDVI and EVI shows that the EVI is more suitable to characterise the vegetation health and can be considered an additional tool to assess vegetation health and to monitor restoration activities. PMID:23456221

  3. River pollution remediation monitored by optical and infrared high-resolution satellite images.

    PubMed

    Trivero, Paolo; Borasi, Maria; Biamino, Walter; Cavagnero, Marco; Rinaudo, Caterina; Bonansea, Matias; Lanfri, Sofia

    2013-09-01

    The Bormida River Basin, located in the northwestern region of Italy, has been strongly contaminated by the ACNA chemical factory. This factory was in operation from 1892 to 1998, and contamination from the factory has had deleterious consequences on the water quality, agriculture, natural ecosystems and human health. Attempts have been made to remediate the site. The aims of this study were to use high-resolution satellite images combined with a classical remote sensing methodology to monitor vegetation conditions along the Bormida River, both upstream and downstream of the ACNA chemical factory site, and to compare the results obtained at different times before and after the remediation process. The trends of the Normalised Difference Vegetation Index (NDVI) and the Enhanced Vegetation Index (EVI) along the riverbanks are used to assess the effect of water pollution on vegetation. NDVI and EVI values show that the contamination produced by the ACNA factory had less severe effects in the year 2007, when most of the remediation activities were concluded, than in 2006 and 2003. In 2007, the contamination effects were noticeable up to 6 km downstream of the factory, whereas in 2003 and 2006 the influence range was up to about 12 km downstream of the factory. The results of this study show the effectiveness of remediation activities that have been taking place in this area. In addition, the comparison between NDVI and EVI shows that the EVI is more suitable to characterise the vegetation health and can be considered an additional tool to assess vegetation health and to monitor restoration activities.

  4. HIGH-RESOLUTION FOURIER TRANSFORM SPECTROSCOPY OF Nb i IN THE NEAR-INFRARED

    SciTech Connect

    Er, A.; Güzelçimen, F.; Başar, Gö.; Öztürk, I. K.; Tamanis, M.; Ferber, R.; Kröger, S. E-mail: sophie.kroeger@htw-berlin.de

    2015-11-15

    In this study, a Fourier Transform spectrum of Niobium (Nb) is investigated in the near-infrared spectral range from 6000 to 12,000 cm{sup −1} (830–1660 nm). The Nb spectrum is produced using a hollow cathode discharge lamp in an argon atmosphere. Both Nb and Ar spectral lines are visible in the spectrum. A total of 110 spectral lines are assigned to the element Nb. Of these lines, 90 could be classified as transitions between known levels of atomic Nb. From these classified Nb i transitions, 27 have not been listed in literature previously. Additionally, 8 lines are classified for the first time.

  5. High resolution spectroscopy of six SOCl2 isotopologues from the microwave to the far-infrared

    NASA Astrophysics Data System (ADS)

    Martin-Drumel, M. A.; Roucou, A.; Brown, G. G.; Thorwirth, S.; Pirali, O.; Mouret, G.; Hindle, F.; McCarthy, M. C.; Cuisset, A.

    2016-02-01

    Despite its potential role as an atmospheric pollutant, thionyl chloride, SOCl2, remains poorly characterized in the gas phase. In this study, the pure rotational and ro-vibrational spectra of six isotopologues of this molecule, all detected in natural abundance, have been extensively studied from the cm-wave band to the far-infrared region by means of three complementary techniques: chirped-pulse Fourier transform microwave spectroscopy, sub-millimeter-wave spectroscopy using frequency multiplier chain, and synchrotron-based far-infrared spectroscopy. Owing to the complex line pattern which results from two nuclei with non-zero spins, new, high-level quantum-chemical calculations of the hyperfine structure played a crucial role in the spectroscopic analysis. From the combined experimental and theoretical work, an accurate semi-experimental equilibrium structure (reSE) of SOCl2 has been derived. With the present data, spectroscopy-based methods can now be applied with confidence to detect and monitor this species, either by remote sensing or in situ.

  6. High-Resolution Near-Infrared Spectroscopy of Deuterated CH_2^+

    NASA Astrophysics Data System (ADS)

    Wang, Haiming; Kleshcheva, Maria; Morong, Christopher P.; Oka, Takeshi

    2009-06-01

    Laboratory spectroscopy of deuterated molecular ions is essential in understanding deuterium ion chemistry-a significant area in astrochemistry since the discovery of many extraordinarily abundant deuterated species in prestellar cores and protostars in recent years. Aiming at providing approximate rotational constants for millimeter wave spectroscopists to identify the corresponding species in space, we are measuring the near-infrared spectrum of deuterated CH_2^+. CH_2^+ is the intermediate between the abundant CH^+ and yet to be observed but very important CH_3^+ in interstellar chemistry. Its abundance is expected in diffuse clouds although our search for interstellar CH_2^+ based on our infrared and near-infrared laboratory spectra has not been successful yet. CH_2^+ and its deuterated species are also of special interest for theoretical studies because of their unique intramolecular dynamics, i.e., the Renner-Teller interaction and quasi-linearity. Using He-dominated liquid-N_2 cooled plasmas (˜10 Torr) containing a small amount (˜0.1 Torr) of CD_4, we have measured the spectra of CD_2^+ in the near-infrared from 11,000 cm^{-1} to 12,500 cm^{-1} with our Ti:sapphire laser spectrometer that combines velocity modulation and phase modulation with heterodyne detection for near shot-noise-limited sensitivity. The tilde{A}(0,5,0)^1 ← tilde{X}(0,0,0)^0, tilde{A}(0,5,0)^0 ← tilde{X}(0,0,0)^1 and tilde{A}(0,4,0)^2 ← tilde{X}(0,0,0)^1 bands of CD_2^+ have been identified and analyzed so far Currently a scan for CHD^+ using CH_2D_2 gas is underway. The spectrum will be discussed in comparison with the theoretical predictions by Bunker and colleagues. M. Rösslein, C. M. Gabrys, M.-F. Jagod, and T. Oka, J. Mol. Spectrosc. 153, 738 (1992). J. L. Gottfried and T. Oka, J. Chem. Phys. 121, 11527 (2004). H.-M. Wang, C. P. Morong, and T. Oka, 62nd, 63rd OSU International Symposium on Molecular Spectroscopy, MJ02 (2007) and WG04 (2008). P. R. Bunker, private

  7. High resolution deuterium NMR studies of bacterial metabolism

    SciTech Connect

    Aguayo, J.B.; Gamcsik, M.P.; Dick, J.D.

    1988-12-25

    High resolution deuterium NMR spectra were obtained from suspensions of five bacterial strains: Escherichia coli, Clostridium perfringens, Klebsiella pneumoniae, Proteus mirabilis, and Staphylococcus aureus. Deuterium-labeled D-glucose at C-1, C-2, and C-6 was used to monitor dynamically anaerobic metabolism. The flux of glucose through the various bacterial metabolic pathways could be determined by following the disappearance of glucose and the appearance of the major end products in the 2H NMR spectrum. The presence of both labeled and unlabeled metabolites could be detected using 1H NMR spectroscopy since the proton resonances in the labeled species are shifted upfield due to an isotopic chemical shift effect. The 1H-1H scalar coupling observed in both the 2H and 1H NMR spectra was used to assign definitively the resonances of labeled species. An increase in the intensity of natural abundance deuterium signal of water can be used to monitor pathways in which a deuteron is lost from the labeled metabolite. The steps in which label loss can occur are outlined, and the influence these processes have on the ability of 2H NMR spectroscopy to monitor metabolism are assessed.

  8. High-Resolution Multiple Sulfur Isotope Studies of Martian Meteorites

    NASA Technical Reports Server (NTRS)

    Mojzsis, S. J.

    2000-01-01

    Sensitive, high resolution measurements of S-32, S-31, and S-34 in individual pyrite grains in martian meteorite ALH84001 by an in situ ion microprobe multi-collection technique reveal mass-independent anomalies in Delta.S-33 (Delta.S-33 = delta.S-33 - 0.516delta.S-34) in addition to the lowest 634S found in an extraterrestrial material. Low delta.S-34 values in two pyrite grains intimately associated with carbonate in ALH84001 can be explained by the sensitivity of sulfur to fractionations in the geologic environment. Anomalies in Delta.S-33 recorded in ALH84001 pyrites probably formed by gas-phase reactions in the early martian atmosphere (>4 Ga). The discovery of clearly resolvable Delta-S33 anomalies in 2 of 12 ALH84001 pyrites analyzed in their petrographic context in thin section, is considered strong evidence for crust-atmosphere exchange and the global cycling of volatile sulfur species on early Mars. These results corroborate previous measurements by Farquhar and co-workers who used a different technique that measures that bulk Delta.S-33 values of martian meteorites. These independent techniques, and their results, suggest that sulfur affected by mass-independent fractionation is common on Mars.

  9. High-resolution infrared spectroscopy of HCN-Agn (n = 1-4) complexes solvated in superfluid helium droplets.

    PubMed

    Stiles, Paul L; Miller, Roger E

    2007-08-01

    High-resolution infrared spectroscopy has been used to determine the structures, C-H stretching frequencies, and dipole moments of the HCN-Agn (n = 1-3) complexes formed in superfluid helium droplets. The HCN-Ag4 cluster was tentatively assigned based upon pick-up cell pressure dependencies and harmonic vibrational shift calculations. Ab initio and density functional theory calculations were used in conjunction with the high-resolution spectra to analyze the bonding nature of each cluster. All monoligated species reported here are bound through the nitrogen end of the HCN molecule. The HCN-Agn complexes are structurally similar to the previously reported HCN-Cun clusters, with the exception of the HCN-Ag binary complex. Although the interaction between the HCN and the Agn clusters follows the same trends as the HCN-Cun clusters, the more diffuse nature of the electrons surrounding the silver atoms results in a much weaker interaction.

  10. High-resolution mid-infrared imaging and astrometry of the nucleus of the Seyfert galaxy NGC 1068

    NASA Technical Reports Server (NTRS)

    Braatz, J. A.; Wilson, A. S.; Gezari, D. Y.; Varosi, F.; Beichman, C. A.

    1993-01-01

    The Goddard Infrared Array Camera was used to obtain a high resolution image of the nucleus of NGC 1068 at 12.4 microns. In addition, the peak emission at 12.4 microns relative to the peak of the optical continuum was determined. The distribution of the 12.4 micron emission relates to both the forbidden O III 5007A 'ionization cone' and the optical continuum emission imaged by HST. This distribution is also found to have an alignment perpendicular to the plane of a putative molecular torus. It is suggested that the extended mid-infrared emission is thermal radiation from dust in circumnuclear clouds heated by the collimated optical/UV AGN source. A portion of the unresolved 12.4 micron emission possibly originates from the torus. The infrared emission peak is found to coincide with the apex of the ionization cone, which is presumed to be the location of the torus.

  11. High-Resolution Optical and Near-Infrared Imaging of Young Circumstellar Disks

    NASA Technical Reports Server (NTRS)

    McCaughrean, Mark; Stapelfeldt, Karl; Close, Laird

    2000-01-01

    In the past five years, observations at optical and near-infrared wavelengths obtained with the Hubble Space Telescope and ground-based adaptive optics have provided the first well-resolved images of young circumstellar disks which may form planetary systems. We review these two observational techniques and highlight their results by presenting prototype examples of disks imaged in the Taurus-Auriga and Orion star-forming regions. As appropriate, we discuss the disk parameters that may be typically derived from the observations, as well as the implications that the observations may have on our understanding of, for example, the role of the ambient environment in shaping the disk evolution. We end with a brief summary of the prospects for future improvements in space- and ground-based optical/IR imaging techniques, and how they may impact disk studies.

  12. High resolution infrared spectroscopy of planetary molecules using diode lasers and Fourier transform spectrometers

    NASA Technical Reports Server (NTRS)

    Jennings, Donald E.

    1990-01-01

    Modern observations of infrared molecular lines in planets are performed at spectral resolutions which are as high as those available in the laboratory. Analysis of such data requires laboratory measurements at the highest possible resolution, which also yield accurate line positions and intensities. For planetary purposes the spectrometer must be coupled to sample cells which can be reduced in temperature and varied in pressure. An approach which produces the full range of required molecular line parameters uses a combination of tunable diode lasers and Fourier transform spectrometers (FTS). The FTS provides board spectral coverage and good calibration accuracy, while the diode laser can be used to study those regions which are not resolved by the FTS.

  13. High resolution infrared astronomy satellite observations of a selected spiral galaxy

    NASA Technical Reports Server (NTRS)

    Kulkarni, S. R.

    1991-01-01

    The H I, infrared, CO, H alpha and H beta band observations of M51, the prototypical grand-design spiral galaxy, are used to study the consequences of star formation for the distribution of H I and dust. Using the new Very Large Array (VLA) map of 21 cm emission, the Owens Valley Radio Observatory CO mosaic map, and an H alpha imate, new tests were performed with the idea of Tilanus and Allen that the H I is largely a photodissociation product in star-forming regions. It is confirmed that the H I spiral arms are generally coincident with the H II region arms, and offset downstream from the CO arms. The radial distributions of total gas, H alpha and H I surface density have a simple explanation in the dissociation picture. The distributions also demonstrate how the surface density of H I might be related to the star formation efficiency in molecule-rich galaxies. The large width of the H I regions along the arms compared to that of the giant H II regions can be understood in terms of a simple calculation of the expected size of an H I region associated with a typical giant H II region. The longer lifetime of the stars producing dissociating radiation vs. those producing ionizing radiation and the relatively long molecular formation timescale will also contribute to the greater width of the H I arms if stars are continuously forming on the arms. The lack of detailed coincidence of the H I and H II regions along the inner arms has a variety of possible explanations. Two simple tests were performed to probe the origins of the IRAS emission in M51. First, it was found that the infrared excess (IFE) of M51 is 24, suggesting that a substantial fraction of the infrared emission arises from dust heated by photons which do not originate in massive star-formaing regions. Second, radial cuts through the IRAS bands show that at 12, 25, and 60 microns, the arm-interarm contrast of the IRAS emission is substantially less than that of the H alpha emission, providing further

  14. Analysis of High-Resolution Infrared and CARS Spectra of ³⁴S¹⁸O₃

    SciTech Connect

    Masiello, Tony; Barber, Jeffrey B.; Chrysostom, Engelene; Nibler, Joseph W.; Maki, Arthur; Weber, Alfons; Blake, Thomas A.; Sams, Robert L.

    2004-01-01

    Three fundamental modes and several hot bands of 34S18O3 have been investigated using both infrared spectroscopy and coherent anti-Stokes Raman scattering spectroscopy (CARS). Coriolis coupling effects are particularly noticeable in 34S18O3 due to the close proximity of the v2 and v4 fundamental vibrations, whose wavenumber values are 477.508 64(5) and 502.055 65(4) cm-1. The uncertainties in the last digits are shown in parentheses and are two standard deviations. Hot band transitions from v2, v4 levels give access to infrared inactive v2, v4 combination/overtone levels which interact strongly with levels of the Raman-active v1 symmetric stretching mode due to indirect Coriolis couplings, l-resonances, and Fermi resonances. The result is a complex v1 CARS Q- branch spectrum that is the most perturbed of the four SO3 isotopomers we have studied. The relative importance of these interaction terms on the v1 CARS spectrum is examined in some detail and accurate rovibrational constants are determined for all of the mixed states, leading to deperturbed values of 1004.662(24), 0.000 350 3(9), and 0.000 706 6(12) cm-1 for v1, α1B, and α1C, respectively. The B e value is found to be 0.310 817(12) cm-1, which gives an equilibrium bond length re of 141.7339(3) pm, in excellent agreement with values of 141.7340(1) and 141.7347(7) pm reported earlier for 32S16O3 and 34S16O3.

  15. High resolution TE&TM near infrared compact spectrometer based on waveguide grating structures

    NASA Astrophysics Data System (ADS)

    Martin, G.; Thomas, F.; Heidmann, S.; de Mengin, M.; Courjal, N.; Ulliac, G.; Morand, A.; Benech, P.; Kern, P.; Le Coarer, E...

    2015-05-01

    Integrated optics spectrometers can be essentially classified into two main families: based on Fourier transform or dispersed modes. In the first case, an interferogram generated inside an optical waveguide is sampled using nanodetectors, these scatter light into the detector that is in contact with the waveguide. A dedicated FFT processing is needed in order to recover the spectrum with high resolution but limited spectral range. Another way is to extract the optical signal confined in a waveguide using a surface grating and directly obtain the spectrum by means of a relay optics that generates the spectrum on the Fourier plane of the lens, where the detector is placed. Following this second approach, we present a high-resolution compact dispersive spectrometer (δλ =1.5nm at λ=1050nm) based on guided optics technology. The propagating signal is dispersed out of a waveguide thanks to a surface grating that lays along it. Focused Ion Beam technique is used to etch nano-grooves that act as individual scattering centers and constitute the surface grating along the waveguide. The waveguide is realized using X-cut, Ypropagating Lithium Niobate substrate, where the effective index for TE and TM guided modes is different. This results in a strong angular separation of TE and TM diffracted modes, allowing simultaneous detection of spectra for both polarizations. A simple relay optics, with limited optical aberrations, reimages the diffracted signal on the focal plane array, leading to a robust, easy to align instrument.

  16. High Resolution Infrared Spectroscopy of Propargyl Alcohol-Water Complex Embedded in Helium Nanodroplets

    NASA Astrophysics Data System (ADS)

    Mani, Devendra; Pal, Nitish; Kaufmann, Matin; Schwaab, Gerhard; Havenith, Martina

    2016-06-01

    Propargyl alcohol (hereafter abbreviated as PA) is a molecule of astrophysical interest and has been probed extensively using microwave spectroscopy.1,2 It is a multifunctional molecule and offers multiple sites for hydrogen bonding interactions. Therefore, it has also attracted the attention of groups interested in weak intermolecular interactions. Recently, the Ar…PA complex3 and PA-dimer4 have been studied using microwave spectroscopy. More recently, there have been matrix-isolation infrared spectroscopic studies on PA-water5 and PA-acetylene6 complexes. In the present work, clusters of PA and water were formed in the helium nanodroplets and probed using a combination of infrared spectroscopy and mass spectrometry. Using ab-initio quantum mechanical calculations, PA-water clusters were optimised and five minimum structures were found on the potential energy hypersurface, which were used as a guidance to the experiments. We used D2O for the experiments since our laser sources at Bochum do not cover the IR spectral region of H2O. IR spectra of PA-D2O complex were recorded in the region of symmetric and antisymmetric stretches of the bound D2O. Multiple signals were found in these regions which were dependent on the concentration of PA as well as D2O. Using pickup curves most of these signals could be assigned to 1:1 PA:D2O clusters. The ab-initio calculations helped in a definitive assignment of the spectra to the different conformers of PA-D2O complex. The details will be presented in the talk. References: 1. E. Hirota, J. Mol. Spec. 26, 335 (1968). 2. J.C. Pearson and B.J. Drouin, J. Mol. Spectrosc. 234, 149 (2005). 3. D. Mani and E. Arunan, ChemPhysChem 14, 754 (2013). 4. D. Mani and E. Arunan, J. Chem. Phys. 141, 164311 (2014). 5. J. Saini, K.S. Vishwanathan, J. Mol. Struct. 1118, 147 (2016). 6. K. Sundararajan et al., J. Mol. Struct. 1121, 26 (2016).

  17. High-resolution subtyping of Staphylococcus aureus strains by means of Fourier-transform infrared spectroscopy.

    PubMed

    Johler, Sophia; Stephan, Roger; Althaus, Denise; Ehling-Schulz, Monika; Grunert, Tom

    2016-05-01

    Staphylococcus aureus causes a variety of serious illnesses in humans and animals. Subtyping of S. aureus isolates plays a crucial role in epidemiological investigations. Metabolic fingerprinting by Fourier-transform infrared (FTIR) spectroscopy is commonly used to identify microbes at species as well as subspecies level. In this study, we aimed to assess the suitability of FTIR spectroscopy as a tool for S. aureus subtyping. To this end, we compared the subtyping performance of FTIR spectroscopy to other subtyping methods such as pulsed field gel electrophoresis (PFGE) and spa typing in a blinded experimental setup and investigated the ability of FTIR spectroscopy for identifying S. aureus clonal complexes (CC). A total of 70 S. aureus strains from human, animal, and food sources were selected, for which clonal complexes and a unique virulence and resistance gene pattern had been determined by DNA microarray analysis. FTIR spectral analysis resulted in high discriminatory power similar as obtained by spa typing and PFGE. High directional concordance was found between FTIR spectroscopy based subtypes and capsular polysaccharide expression detected by FTIR spectroscopy and the cap specific locus, reflecting strain specific expression of capsular polysaccharides and/or other surface glycopolymers, such as wall teichoic acid, peptidoglycane, and lipoteichoic acid. Supervised chemometrics showed only limited possibilities for differentiation of S. aureus CC by FTIR spectroscopy with the exception of CC45 and CC705. In conclusion, FTIR spectroscopy represents a valuable tool for S. aureus subtyping, which complements current molecular and proteomic strain typing. PMID:27021524

  18. High Resolution Far Infrared Spectroscopy of HFC-134a at Cold Temperatures

    NASA Astrophysics Data System (ADS)

    Wong, Andy; Medcraft, Chris; Thompson, Christopher; Robertson, Evan Gary; Appadoo, Dominique; McNaughton, Don

    2016-06-01

    Since the signing of the Montreal protocol, long-lived chlorofluorocarbons have been banned due to their high ozone depleting potential. In order to minimise the effect of such molecules, hydrofluorocarbons (HFCs) were synthesized as replacement molecules to be used as refrigerants and foam blowing agents. HFC-134a, or 1,1,1,2-tetrafluoroethane, is one of these molecules. Although HFCs do not cause ozone depletion, they are typically strong absorbers within the 10 micron atmospheric window, which lead to high global warming potentials. A high resolution FT-IR analysis of the νb{8} band (near 665 wn) of HFC-134a has been performed to help understand the intermode coupling between the νb{8} vibrational state and unobserved dark states.

  19. High-resolution infrared spectrum of propyne: The 30 μm region

    NASA Astrophysics Data System (ADS)

    Graner, Georges; Wagner, Georg

    1990-12-01

    A high-resolution (0.002 cm -1) spectrum of propyne in the region of 30 μm has been used to improve the constants of ν10 and to analyze its hot bands. For ν10, it was found necessary to use ηJJ, ηJK, ηKK, and even ηKKK and ηKKKK constants to fit the high K series correctly. A standard deviation of 0.00021 cm -1 was obtained. The assignments were more challenging for the hot bands. Finally, more than 2000 transitions were assigned in the 2 ν10±2- ν10+1 band and more than 1500 in 2 ν100- ν10±1. The final fit, also including ν9, and microwave data will be presented in a future paper.

  20. Design inputs for a high-performance high-resolution near-infrared spectrograph

    NASA Astrophysics Data System (ADS)

    Hinkle, Kenneth H.; Joyce, Richard R.; Najita, Joan R.

    2010-07-01

    The combination of immersion grating and infrared array detector technologies allows the construction of highresolution spectrographs in the near-infrared that have capabilities similar to those of optical spectrographs. It is possible, for instance, to design multi-object spectrographs with very large wavelength coverage and high throughput. We explored the science and functional drivers for these spectrograph designs. Several key inputs into the design are reviewed including risk, mechanical-optical trades, and operations. We discuss a design for a fixed configuration spectrograph with either 1.1 - 2.5 or 3 - 5 μm simultaneous wavelength coverage.

  1. Coriolis analysis of several high-resolution infrared bands of bicyclo[111]pentane-d0 and -d1

    SciTech Connect

    Perry, A.; Martin, M. A.; Nibler, J. W.; Maki, A.; Weber, A.; Blake, T. A.

    2012-06-01

    High resolution infrared absorption spectra have been analyzed for two bicyclo[1.1.1]pentane isotopologues, C5H8 (-d0) and C5H7D (-d1), where in the latter the D-atom replaces a hydrogen on the C3 symmetry axis such that the molecular symmetry is reduced from D3h to C3v. Two (a2") parallel bands, ν17 and ν18, of bicyclopentane-d0 were studied and the former was found to be profoundly affected by Coriolis coupling with the nearby (e') perpendicular band, ν11. Weaker coupling was observed between the ν18 band and the nearby ν13(e') band, for which fewer transitions could be assigned. For bicyclopentane-d1, the ν5 parallel band was also studied along with the nearby ν15(e') band to which it is coupled through a similar type of Coriolis resonance. For both isotopologues, quantum calculations (B3LYP/cc-pVTZ) done at the anharmonic level were very helpful in unraveling the complexities caused by the Coriolis interactions, provided that care is taken in identifying the effect of any Coriolis resonances in the theoretical values of aB and q rovibrational parameters. The ground state B0 constants were found to be 0.2399412(2) and 0.2267506(11) cm-1 for the -d0 and -d1 isotopologues. The difference yields an Rs substitution value of 2.0309(2) Å for the position of the axial H atom relative to the -d0 center of mass, a result in good accord with a corresponding Ra value of 2.044(6) Å from electron diffraction data. For both isotopologues, the theoretical results from the quantum calculations are in good agreement with all corresponding values determined from the spectra.

  2. High-resolution ground target infrared signature modeling for combat target identification training

    NASA Astrophysics Data System (ADS)

    Sanders, Jeffrey S.

    2003-09-01

    Recent world events have accelerated the evolution of the US military from monolithic formations arrayed against a known enemy, to a force that must respond to rapidly changing world events. New technologies are part of the Army's evolution and thermal imaging sensors are becoming more and more prevalent on the modern battlefield. These sensors are integrated into advanced weapon systems or commonly used for battlefield surveillance. Thermal imaging systems give the soldier the ability to deliver deadly force onto an enemy at long ranges at any time of day or night. The ability to differentiate friendly and threat forces in this situation is critical for the avoidance of friendly fire incidents and for the proper use of battlefield resources. The ability to foresee the location of the Army's next battlefield is becoming more difficult, and we don't know where the next battlefield will be from year to year. Infrared target recognition training tools need to be flexible, adaptable, and be based on not only the latest intelligence data but have geographically specific training available to the soldier. To address this training issue, personnel of the Measurement and Signatures Division at the National Ground Intelligence Center have created the Simulated Infrared Earth Environment Lab (SIREEL) web site. The SIREEL web site contains extensive infrared signature data on numerous threat and friendly vehicles and the site is designed to provide country-specific vehicle identification training in support of US military deployments. The bulk of the content currently on the site consists of infrared signature data collected over a decade of intelligence gathering. The site also employs state of the art infrared signature modeling capabilities to provide the soldier in training the most flexible training possible. If measured data on a vehicle is not available, the website developers have the capability to calculate the infrared signature of ground vehicles in any location

  3. Near-Infrared high resolution spectral survey of comets with GIANO/TNG: The CN red-system at 1.1 μm

    NASA Astrophysics Data System (ADS)

    Faggi, Sara; Villanueva, Geronimo Luis; Mumma, Michael J.; Tozzi, Gian-Paolo; Brucato, John Robert

    2016-10-01

    High-resolution spectroscopy in the near-infrared spectral range is a powerful tool to investigate chemical composition and isotopic fractionation.Comets are the best preserved relic of the enfant stages of the solar system. By targeting biologically relevant species in cometary comae and retrieving isotopic (e.g. D/H) and spin isomeric (e.g., ortho- and para- water) ratios, we can study the formation and evolution of solar system matter, address the origin of Earth's oceans and characterize the delivery of organic matter that was essential for the appearance of life on early Earth. We initiated the first high resolution spectral survey of comets ever conducted in the 0.9-2.5 μm range, targeting C/2014 Q2 (Lovejoy), C/2013 US10 (Catalina) and C/2013 X1 (Panstarrs) with GIANO - the near-IR high resolution spectrograph on Telescopio Nazionale Galileo (TNG). In comet Lovejoy, we detected eight ro-vibrational bands of H2O (Faggi et al., 2016, ApJ in press), emission from the red-system of CN, and many other emission lines whose precursors are now being identified. In this talk we will present a new quantum mechanical solar fluorescence model for the CN red system and the retrievals obtained with it from our cometary spectra. These observations open new pathways for cometary science in the near-infrared spectral range (0.9-2.5 μm) and establish the feasibility of astrobiology-related scientific investigations with future high resolution IR spectrographs on 30-m class telescopes, e.g., the HIRES spectrograph on the E-ELT telescope. This work is part of Sara Faggi's Ph.D. thesis project. NASA's Planetary Astronomy Program supported GLV and MJM through funding awarded under proposal 11-PAST11-0045 (M. J. Mumma, PI ).

  4. Vertical profiling of methane and carbon dioxide using high resolution near-infrared heterodyne spectroscopic observations

    NASA Astrophysics Data System (ADS)

    Rodin, Alexander; Klimchuk, Artem; Churbanov, Dmitry; Pereslavtseva, Anastasia; Spiridonov, Maxim; Nadezhdinskyi, Alexander

    2014-05-01

    We present new method of monitoring greenhouse gases using spectroscopic observations of solar radiation passed through the atmosphere with spectral resolution ΛvδΛ up to 108. Such a high resolution is achieved by heterodyne technique and allows to retrieve full information about spectral line shape which, in turn, is used to distinguish contribution of different atmospheric layers to the resulting absorption. Weak absorption line at 6056.5 cm-1 was selected for CO2 measurements and a quartet of lines centered at 6057 cm-1for CH4. The instrument setup includes Sun tracker with a microtelescope and chopper, diode DFB laser used as a local oscillator, a bundle of single mode optical fibers that provides medium for radiation transfer and beam coupling, reference cell with depressurized methane for LO frequency stabilization, and Fabry-Perot etalon for LO frequency calibration. A commercial p-i-n diode with squared detector replaces a mixer and IF spectrometer, providing measurement of heterodyne beating within a bandpass of few MHz, which determines the effective spectral resolution of the instrument. Spectral coverage within narrow range (about 1 cm-1) is provided by ramping the LO frequency based on feedback from the reference channel. Observations of Sun in the Moscow region have resulted for the first time in measurements of the atmospheric transmission near 1.65 μm with sub-Doppler spectral resolution. In order to retrieve vertical profiles of methane and carbon dioxide we developed the inversion algorithm implementing Tikhonov regularization approach. With measured transmission having S/N ratio of 100 or higher, the uncertainty of CH4 profile is about 10 ppb, with the uncertainty of CO2 profile at 1 ppm. This techniques is promising an affordable opportunity or widespread monitoring of greenhouse gases and may be implemented on existing ground-based stations. This work has been supported by the grant of Russian Ministry of education and science #11.G34.31.0074

  5. HIGH-RESOLUTION FOURIER TRANSFORM SPECTROSCOPY OF LANTHANUM IN Ar DISCHARGE IN THE NEAR-INFRARED

    SciTech Connect

    Güzelçimen, F.; Başar, Gö.; Tamanis, M.; Kruzins, A.; Ferber, R.; Windholz, L.; Kröger, S. E-mail: sophie.kroeger@htw-berlin.de

    2013-10-01

    A high-resolution spectrum of lanthanum has been recorded by a Fourier Transform spectrometer in the wavelength range from 833 nm to 1666 nm (6000 cm{sup –1} to 12,000 cm{sup –1}) using as light source a hollow cathode lamp operated with argon as the discharge carrier gas. In total, 2386 spectral lines were detected in this region, of which 555 lines could be classified as La I transitions and 10 lines as La II transitions. All La II transitions and 534 of these La I transitions were classified for the first time, and 6 of the La II transitions and 433 of the classified La I transitions appear to be new lines, which could not be found in the literature. The corresponding energy level data of classified lines are given. Additionally, 430 lines are assigned as Ar I lines and 394 as Ar II lines, of which 179 and 77, respectively, were classified for the first time. All 77 classified Ar II transitions as well as 159 of the classified Ar I transitions are new lines. Furthermore, the wavenumbers of 997 unclassified spectral lines were determined, 235 of which could be assigned as La lines, because of their hyperfine pattern. The remaining 762 lines may be either unclassified Ar lines or unresolved and unclassified La lines with only one symmetrical peak with an FWHM in the same order of magnitude as the Ar lines. The accuracy of the wavenumber for the classified lines with signal-to-noise-ratio higher than four is better than 0.006 cm{sup –1} which corresponds to an accuracy of 0.0004 nm at 830 nm and 0.0017 nm at 1660 nm, respectively.

  6. Study of radar pulse compression for high resolution satellite altimetry

    NASA Technical Reports Server (NTRS)

    Dooley, R. P.; Nathanson, F. E.; Brooks, L. W.

    1974-01-01

    Pulse compression techniques are studied which are applicable to a satellite altimeter having a topographic resolution of + 10 cm. A systematic design procedure is used to determine the system parameters. The performance of an optimum, maximum likelihood processor is analysed, which provides the basis for modifying the standard split-gate tracker to achieve improved performance. Bandwidth considerations lead to the recommendation of a full deramp STRETCH pulse compression technique followed by an analog filter bank to separate range returns. The implementation of the recommended technique is examined.

  7. High resolution studies of sunspots and flux tubes

    NASA Astrophysics Data System (ADS)

    Title, Alan

    This contract is for a three-year research study of sunspots and magnetic flux tubes in the solar atmosphere, using tunable filter images collected with a CCD camera during observing runs at the Canary Islands observatories in Spain. The best observations are analyzed and compared with theoretical models, to study the structure and dynamics of sunspots, their connections with surrounding magnetic fields, and the properties and evolution of smaller flux tubes in plage and quiet sun. Scientific results are reported at conferences and published in the appropriate journals. The contract is being performed by the Solar and Astrophysics Laboratory, part of the Lockheed Palo Alto Research Laboratory (LPARL) of the Research and Development Division (RDD) of Lockheed Missiles and Space Co., Inc. (LMSC). The principal investigator is Dr. Alan Title, and the research is done by him and other scientific staff at LPARL and Solar Physics Research Corporation (SPRC), often in collaboration with visiting scientists and students from other institutions. Highlights during this reporting period include completing the final version of a paper on the Evershed effect, writing a paper on magnetic diffusion, continuing work on contrast of small flux tubes, and work on the development of new models to interpret our sunspots observations.

  8. High resolution studies of sunspots and flux tubes

    NASA Technical Reports Server (NTRS)

    Title, Alan

    1994-01-01

    This contract is for a three-year research study of sunspots and magnetic flux tubes in the solar atmosphere, using tunable filter images collected with a CCD camera during observing runs at the Canary Islands observatories in Spain. The best observations are analyzed and compared with theoretical models, to study the structure and dynamics of sunspots, their connections with surrounding magnetic fields, and the properties and evolution of smaller flux tubes in plage and quiet sun. Scientific results are reported at conferences and published in the appropriate journals. The contract is being performed by the Solar and Astrophysics Laboratory, part of the Lockheed Palo Alto Research Laboratory (LPARL) of the Research and Development Division (RDD) of Lockheed Missiles and Space Co., Inc. (LMSC). The principal investigator is Dr. Alan Title, and the research is done by him and other scientific staff at LPARL and Solar Physics Research Corporation (SPRC), often in collaboration with visiting scientists and students from other institutions. Highlights during this reporting period include completing the final version of a paper on the Evershed effect, writing a paper on magnetic diffusion, continuing work on contrast of small flux tubes, and work on the development of new models to interpret our sunspots observations.

  9. High resolution infrared spectrum of the CD2 wagging band of methanol-D2 (CHD2OH) for the lowest lying torsional vibrational state (e0)

    NASA Astrophysics Data System (ADS)

    Mukhopadhyay, Indra

    2016-07-01

    This paper reports the analysis of the high resolution (0.0019 cm-1) Fourier transform infrared (FTIR) spectrum for asymmetrically deuterated methanol CHD2OH (methanol-D2) at a low temperature for the CD2 wagging band for the lowest lying trans-species (e0). In spite of the complexity and perturbation in the spectra, assignments were possible for the CD2 wagging band for a maximum K value of 10. In total, about 500 spectral lines have been assigned. Analysis of the spectral lines has been performed in terms of state dependent molecular parameters, Q-branch origins and asymmetry splitting. Assignments have been thoroughly confirmed using combination relations (see text). The catalogue of the assigned transition wavenumbers will help identification and prediction of far infrared (FIR) optically pumped CO2 lasers. The absorption lines close to the several 10R and 10P CO2 laser lines have also been identified. These should help experimentalists to optimize the power of the emission FIR laser lines and to predict new lines and should prove valuable as a laboratory support for interstellar detection in "Radio Astronomy". To our knowledge this is the first time such vibrational infrared (IR) high resolution study in CHD2OH is being performed.

  10. New very high resolution radar studies of the Moon

    NASA Technical Reports Server (NTRS)

    Mouginis-Mark, Peter J.; Campbell, Bruce

    1987-01-01

    As part of an effort to further understand the geologic utility of radar studies of the terrestrial planets, investigators at the Hawaii Institute of Geophysics are collaborating with NEROC Haystack Observatory, MIT and the Jet Propulsion Laboratory in the analysis of existing 3.8 and 70 cm radar images of the Moon, and in the acquisition of new data for selected lunar targets. The intent is to obtain multi-polarization radar images at resolutions approaching 75 meters (3.8 cm wavelength) and 400 meters (70 cm wavelength) for the Apollo landing sites (thereby exploiting available ground truth) or regions covered by the metric camera and geochemical experiments onboard the command modules of Apollos 15, 16 and 17. These data were collected in both like- and cross-polarizations, and, in the case of the 70 cm data, permit the phase records to be used to assess the scattering properties of the surface. The distribution of surface units on the Moon that show a mismatch between the surface implied by like- and cross-polarized scattering data is being analyzed, based on the scattering models of Evans and Hagfors.

  11. High Resolution Studies of Sunspots and Flux Tubes

    NASA Technical Reports Server (NTRS)

    1997-01-01

    This contract started as a three-year research study of sunspots and magnetic flux tubes in the solar atmosphere, using tunable filter images collected with a CCD camera during observing runs at the Canary Islands observatories in Spain. Scientific results are reported at conferences and published in the appropriate journals. The contract is being performed by the Solar and Astrophysics Laboratory (S&AL), part of the Lockheed Palo Alto Advanced Technology Center (ATC) of Lockheed Martin Missiles and Space (LMMS). The principal investigator is Dr. Alan Title, and the research is done by him and other scientific staff at S&AL, often in collaboration with visiting scientists and students from other institutions. An extension to the contract has been awarded for developing the Solar Lite technology demonstration telescope, a 1-meter solar telescope with silicon carbide optics made at the Vavilov Optical Institute in St. Petersburg, Russia. The highlights during this reporting period included the continuation of the fabrication efforts on the Solar Lite optical components at Vavilov State Optical Institute, including the completion of the Gregorian telescope field stop. A visit was made to the Vavilov Institute to review the progress and inspect the optical components.

  12. Fiber-coupled high resolution infrared array spectrometer for the Kuiper Airborne Observatory

    NASA Technical Reports Server (NTRS)

    Glenar, D. A.; Reuter, D.; Mumma, M. J.; Chin, G.; Wiedemann, G.; Jennings, D.

    1990-01-01

    A novel cryogenic grating spectrometer (FCAS) is being designed for observations of volatiles in cometary and planetary atmospheres, and in newly forming planetary systems. The instrument features two-dimensional detector arrays coupled to a high-dispersion echelle by infrared fibers, and will achieve a spectral resolving power of about 40,000. The primary observational platform for this instrument will be the Kuiper Airborne Observatory, but it will also be configured for use at ground-based observatories. Initially, the spectrometer will use a 58 x 62, 1- to 5-micron InSb array. Larger-format IR arrays and arrays of different composition, will later be incorporated as they become available. The instrument will be used in two modes. The first uses a large format IR array in the spectral image plane for the customary one-dimensional spectral-one-dimensional spatial coverage. In the second mode, a massive, coherent bundle of infrared transmitting ZrF4 fibers will be installed after the dispersive element, to reformat the two-dimensional array into an elongated one-dimensional array for wide spectral coverage, allowing multiple lines to be measured in a single integration with high sensitivity. The overall instrument design is discussed, and the system sensitivity is estimated.

  13. Packet based serial link realized in FPGA dedicated for high resolution infrared image transmission

    NASA Astrophysics Data System (ADS)

    Bieszczad, Grzegorz

    2015-05-01

    In article the external digital interface specially designed for thermographic camera built in Military University of Technology is described. The aim of article is to illustrate challenges encountered during design process of thermal vision camera especially related to infrared data processing and transmission. Article explains main requirements for interface to transfer Infra-Red or Video digital data and describes the solution which we elaborated based on Low Voltage Differential Signaling (LVDS) physical layer and signaling scheme. Elaborated link for image transmission is built using FPGA integrated circuit with built-in high speed serial transceivers achieving up to 2500Gbps throughput. Image transmission is realized using proprietary packet protocol. Transmission protocol engine was described in VHDL language and tested in FPGA hardware. The link is able to transmit 1280x1024@60Hz 24bit video data using one signal pair. Link was tested to transmit thermal-vision camera picture to remote monitor. Construction of dedicated video link allows to reduce power consumption compared to solutions with ASIC based encoders and decoders realizing video links like DVI or packed based Display Port, with simultaneous reduction of wires needed to establish link to one pair. Article describes functions of modules integrated in FPGA design realizing several functions like: synchronization to video source, video stream packeting, interfacing transceiver module and dynamic clock generation for video standard conversion.

  14. High-Resolution Observations of the Infrared Spectrum of Neutral Neon

    PubMed Central

    Sansonetti, Craig J.; Blackwell, Marion M.; Saloman, E. B.

    2004-01-01

    We have observed the spectrum of neutral neon (Ne I) emitted by a microwave-excited electrodeless discharge lamp with the National Institute of Standards and Technology 2 m Fourier transform spectrometer. The spectra cover the regions 6929 Å to 11 000 Å with a resolution of 0.01 cm−1 and 11 000 Å to 47 589 Å with a resolution of 0.007 cm−1. We present a line list that includes more than 650 classified lines and provides an accurate and comprehensive description of the infrared spectrum. The response of the Fourier transform spectrometer was determined by using a radiometrically calibrated tungsten strip lamp, providing relative intensities that for moderate to strong lines are accurate to approximately 10 % over the entire range of the observations. The identities of many lines that were previously multiply classified are unambiguously resolved. PMID:27366619

  15. High-Resolution Infrared Space Observatory Spectroscopy of the Unidentified 21 Micron Feature

    NASA Technical Reports Server (NTRS)

    Volk, Kevin; Kwok, Sun; Hrivnak, Bruce

    1999-01-01

    We present Infrared Space Observatory SWS06 mode observations of the 21 micron feature in eight sources, including a first "detection of the feature in IRAS Z02229+6208. The observed feature peak-to-continuum ratios range from 0.13 in IRAS Z02229+6208 to 1.30 in IRAS 07134+1005. The normalized spectra, obtained by the removal of the underlying continua and by scaling the features to the same peak flux value. show that all features have the same intrinsic profile and peak wavelength. There is no evidence for any discrete substructure due to molecular bands in the observed spectra, suggesting that the 21 micron feature is due to either a solid substance or a mixture of many similarly structured large molecules.

  16. On-chip near-infrared spectroscopy of CO2 using high resolution plasmonic filter array

    NASA Astrophysics Data System (ADS)

    Chong, Xinyuan; Li, Erwen; Squire, Kenneth; Wang, Alan X.

    2016-05-01

    We report an ultra-compact, cost-effective on-chip near-infrared spectroscopy system for CO2 sensing using narrow-band optical filter array based on plasmonic gratings with a waveguide layer. By varying the periodicity of the gratings, the transmission spectra of the filters can be continuously tuned to cover the 2.0 μm sensing window with high spectral resolution around 10 nm. Our experimental results show that the on-chip spectroscopy system can resolve the two symmetric vibrational bands of CO2 at 2.0 μm wavelength, which proves its potential to replace the expensive commercial IR spectroscopy system for on-site gas sensing.

  17. High-resolution infrared spectra of bicyclo[1.1.1]pentane

    SciTech Connect

    Martin, M. A.; Perry, A.; Masiello, T.; Schwartz, K. D.; Nibler, J. W.; Weber, A.; Maki, A.; Blake, T. A.

    2010-07-01

    Infrared spectra of bicyclo[1.1.1]pentane (C5H8) have been recorded at a resolution (0.0015 cm-1) sufficient to resolve for the first time individual rovibrational lines. This initial report presents the ground state constants for this molecule determined from the detailed analysis of three of the ten infrared-allowed bands, v14(e') at 540 cm-1, v17(a2'') at 1220 cm-1, v18(a2'') at 832 cm-1, and a partial analysis of the v11(e') band at 1237 cm-1. The upper states of transitions involving the lowest frequency mode, v14(e'), show no evidence of rovibrational perturbations but those for the v17 and v18 (a2'') modes give clear indication of Coriolis coupling to nearby e' levels. Accordingly, ground state constants were determined by use of the combination-difference method for all three bands. The assigned frequencies provided over 3300 consistent ground state difference values, yielding the following constants for the ground state (in units of cm-1): B0 = 0.2399412(2), DJ = 6.024(6) x 10-8, DJK = -1.930(21) x 10-8. For the unperturbed v14(e') fundamental, more than 3500 transitions were analyzed and the band origin was found to be at 540.34225(2) cm-1. The numbers in parentheses are the uncertainties (two standard deviations) in the values of the constants. The results are compared with those obtained previously for [1.1.1]propellane and with those computed at the ab initio anharmonic level using the B3LYP density functional method with a cc-pVTZ basis set.

  18. Multi-sensor fusion of electro-optic and infrared signals for high resolution visible images: part I

    NASA Astrophysics Data System (ADS)

    Huang, Xiaopeng; Netravali, Ravi; Man, Hong; Lawrence, Victor

    2013-06-01

    Electro-Optic (EO) image sensors exhibit the properties of high resolution and low noise level, but they cannot reflect information about the temperature of objects and do not work in dark environments. On the other hand, infrared (IR) image sensors exhibit the properties of low resolution and high noise level, but IR images can reflect information about the temperature of objects all the time. Therefore, in this paper, we propose a novel framework to enhance the resolution of EO images using the information (e.g., temperature) from IR images, which helps distinguish temperature variation of objects in the daytime via high-resolution EO images. The proposed novel framework involves four main steps: (1) select target objects with temperature variation in original IR images; (2) fuse original RGB color (EO) images and IR images based on image fusion algorithms; (3) blend the fused images of target objects in proportion with original gray-scale EO images; (4) superimpose the target objects' temperature information, onto original EO images via the modified NTSC color space transformation. Therein, the image fusion step will be conducted by qualitative (frame pipeline) approach. Revealing temperature information in EO images for the first time is the most significant contribution of this paper. Simulation results will show the transformed EO images with the targets' temperature information.

  19. High-resolution satellite and airborne thermal infrared imaging of precursory unrest and 2009 eruption of Redoubt Volcano, Alaska

    USGS Publications Warehouse

    Wessels, Rick L.; Vaughan, R. Greg; Patrick, Matthew R.; Coombs, Michelle L.

    2013-01-01

    A combination of satellite and airborne high-resolution visible and thermal infrared (TIR) image data detected and measured changes at Redoubt Volcano during the 2008–2009 unrest and eruption. The TIR sensors detected persistent elevated temperatures at summit ice-melt holes as seismicity and gas emissions increased in late 2008 to March 2009. A phreatic explosion on 15 March was followed by more than 19 magmatic explosive events from 23 March to 4 April that produced high-altitude ash clouds and large lahars. Two (or three) lava domes extruded and were destroyed between 23 March and 4 April. After 4 April, the eruption extruded a large lava dome that continued to grow until at least early July 2009.

  20. High-Resolution Infrared Spectra of Spiropentane, C5H8

    SciTech Connect

    Price, Joseph E.; Coulterpark, K. A.; Masiello, Tony; Nibler, Joseph W.; Weber, Alfons; Maki, Arthur G.; Blake, Thomas A.

    2011-09-01

    Infrared spectra of spiropentane (C{sub 5}H{sub 8}) have been recorded at a resolution (0.002 cm{sup -1}) sufficient to resolve for the first time individual rovibrational lines. This initial report presents the ground state constants for this molecule determined from the detailed analysis of the {nu}16 (b2) parallel band at 993 cm{sup -1}. In addition, the determination included more than 2000 ground state combination-differences deduced from partial analyses of four other infrared-allowed bands, the {nu}24(e) perpendicular band at 780 cm{sup -1} and three (b2) parallel bands at 1540 cm{sup -1} ({nu}14), 1568 cm{sup -1} ({nu}5+{nu}16), and 2098 cm{sup -1} ({nu}5+{nu}14). In each of the latter four cases, the spectra show complications; in the case of {nu}24, these complications are due to rotational l-type doublings, and in the case of the parallel bands, the spectral complexities are due to Fermi resonance and Coriolis interactions of the upper states with nearby levels. The unraveling of these is underway but the assignment of many of these transitions permit the confident use of the ground state differences in determining the following constants for the ground state (in units of cm{sup -1}): B0 = 0.1394736(2), DJ = 2.458(1) x 10{sup -8}, DJK = 8.28(3) x 10{sup -8}. For the unperturbed {nu}16 fundamental, more than 3000 transitions were fit and the band origin was found to be at 992.53793(2) cm{sup -1}. The numbers in parentheses are the uncertainties (two standard deviations) in the value of the last digit of the constants. Surprisingly, the very accurate B0 value measured here is lower than the value (0.1418 cm{sup -1}) calculated from an electron diffraction structure, instead of being higher, as expected. Where possible, the rovibrational results are compared with those computed at the anharmonic level using the B3LYP density functional method with a cc-pVTZ basis set. These too suggest that the electron diffraction results are in question.

  1. High-Resolution Infrared Imaging and Spectroscopy of the Pistol Nebula: Evidence for Ejection

    NASA Astrophysics Data System (ADS)

    Figer, Donald F.; Morris, Mark; Geballe, T. R.; Rich, R. Michael; Serabyn, Eugene; McLean, Ian S.; Puetter, R. C.; Yahil, Amos

    1999-11-01

    We present new infrared images, obtained with the Hubble Space Telescope (HST) Near-Infrared Camera and Multiobject Spectrometer (NICMOS), and Brα (4.05 μm) spectroscopy, obtained using CGS4 on UKIRT, of the Pistol Star and its associated nebula. We find strong evidence to support the hypothesis that the Pistol Nebula was ejected from the Pistol Star. The Paα (1.87 μm) NICMOS image shows that the nebula completely surrounds the Pistol Star, although the line intensity is much stronger on its northern and western edges. The Brα CGS4 spectra show the classical ringlike signature of quasi-spherical expansion. The blueshifted emission (Vmax~-60 km s-1) is much weaker than the redshifted emission (Vmax~+10 km s-1), where the velocities are with respect to the velocity of the Pistol Star; further, the redshifted emission spans a very narrow range of velocities, i.e., it appears ``flattened'' in the position-velocity diagram. These data suggest that the nebula was ejected from the star several thousand years ago, with a velocity between the current terminal velocity of the stellar wind (95 km s-1) and the present expansion velocity of gas in the outer shell of the nebula (60 km s-1). The Paα image reveals several emission-line stars in the region, including two newly identified emission-line stars north of the Pistol Star, both of which are likely to be the hottest known stars in the Galactic center with spectral types earlier than WC8 and Teff>50,000 K). The presence of these stars, the morphology of the Paα emission, and the velocity field in the gas suggest that the side of the nebula farthest from us is approaching, and being ionized by, the hot stars of the Quintuplet and that the highest velocity redshifted gas has been decelerated by winds from the Quintuplet stars. We also discuss the possibility that the nebular gas might be magnetically confined by the ambient magnetic field delineated by the nearby nonthermal filaments. Based on observations with the

  2. Spartan infrared camera: high-resolution imaging for the SOAR Telescope

    NASA Astrophysics Data System (ADS)

    Loh, Edwin D.; Biel, Jason D.; Chen, Jian-Jun; Davis, Michael; Laporte, Rene; Loh, Owen Y.

    2004-09-01

    The Spartan Infrared Camera provides tip-tilt corrected imaging for the SOAR Telescope in the 1-2.5μm spectral range with four 2048x2048 HAWAII2 detectors. The median image size is expected to be less than 0.25 arcsec (FWHM), and in the H and K bands a significant amount of the light is expected to be in a core having the diffraction-limited width. The camera has two plate scales: 0.04 arcsec/pixel (f/21) for diffraction-limited sampling in the H and K bands and 0.07 arcsec/pixel (f/12) to cover a 5×5 arcmin2 field, over which tip-tilt correction is substantial. Except for CaF2 field-flattening lenses, the optics is all reflective to achieve the large field size and achromaticity, and all aluminum to match thermally the aluminum cryogenic-optical box in which the optics mount. The Strehl ratio of the camera itself is 0.95-1.00 for the f/21 channel. The optics (including the off-axis aspherical mirrors) will be aligned with precise metrology rather than adjusted using interferometry.

  3. High-Resolution Near-Infrared Polarimetry of a Circumstellar Disk around UX Tau A

    NASA Astrophysics Data System (ADS)

    Tanii, Ryoko; Itoh, Yoichi; Kudo, Tomoyuki; Hioki, Tomonori; Oasa, Yumiko; Gupta, Ranjan; Sen, Asoke K.; Wisniewski, John P.; Muto, Takayuki; Grady, Carol A.; Hashimoto, Jun; Fukagawa, Misato; Mayama, Satoshi; Hornbeck, Jeremy; Sitko, Michael L.; Russell, Ray W.; Werren, Chelsea; Curé, Michel; Currie, Thayne; Ohashi, Nagayoshi; Okamoto, Yoshiko; Momose, Munetake; Honda, Mitsuhiko; Inutsuka, Shu-ichi; Takeuchi, Taku; Dong, Ruobing; Abe, Lyu; Brandner, Wolfgang; Brandt, Timothy D.; Carson, Joseph; Egner, Sebastian E.; Feldt, Markus; Fukue, Tsubasa; Goto, Miwa; Guyon, Olivier; Hayano, Yutaka; Hayashi, Masahiko; Hayashi, Saeko S.; Henning, Thomas; Hodapp, Klaus W.; Ishii, Miki; Iye, Masanori; Janson, Markus; Kandori, Ryo; Knapp, Gillian R.; Kusakabe, Nobuhiko; Kuzuhara, Masayuki; Matsuo, Taro; McElwain, Michael W.; Miyama, Shoken; Morino, Jun-ichi; Moro-Martín, Amaya; Nishimura, Tetsuro; Pyo, Tae-Soo; Serabyn, Eugene; Suto, Hiroshi; Suzuki, Ryuji; Takami, Michihiro; Takato, Naruhisa; Terada, Hiroshi; Thalmann, Christian; Tomono, Daigo; Turner, Edwin L.; Watanabe, Makoto; Yamada, Toru; Takami, Hideki; Usuda, Tomonori; Tamura, Motohide

    2012-12-01

    We present H-band polarimetric imagery of UX Tau A taken with HiCIAO/AO188 on the Subaru Telescope. UX Tau A has been classified as a pre-transitional disk object, with a gap structure separating its inner and outer disks. Our imagery taken with the 0.''15 (21 AU) radius coronagraphic mask has revealed a strongly polarized circumstellar disk surrounding UX Tau A, which extends to 120 AU, at a spatial resolution of 0.''1 (14 AU). It is inclined by 46° ± 2°, since the west side is nearest. Although SED modeling and sub-millimeter imagery have suggested the presence of a gap in the disk, with the inner edge of the outer disk estimated to be located at 25-30 AU, we detect no evidence of a gap at the limit of our inner working angle (23 AU) at the near-infrared wavelength. We attribute the observed strong polarization (up to 66%) to light scattering by dust grains in the disk. However, neither polarization models of the circumstellar disk based on Rayleigh-scattering nor Mie-scattering approximations were consistent with the observed azimuthal profile of the polarization degrees of the disk. Instead, a geometric optics model of the disk with nonspherical grains with radii of 30μm is consistent with the observed profile. We suggest that the dust grains have experienced frequent collisional coagulations, and have grown in the circumstellar disk of UX Tau A.

  4. High-Resolution Near-Infrared Polarimetry of a Circumstellar Disk around UX Tau A

    NASA Technical Reports Server (NTRS)

    Serabyn, G.; Grady, C. A.; Currie, T.

    2012-01-01

    We present H-band polarimetric imagery of UX Tau A taken with HiCIAO/AO188 on the Subaru Telescope. UX Tau A has been classified as a pre-transitional disk object, with a gap structure separating its inner and outer disks. Our imagery taken with the 0.15" (21 AU) radius coronagraphic mask has revealed a strongly polarized circumstellar disk surrounding UX Tau A which extends to 120 AU, at a spatial resolution of 0.1" (14 AU). It is inclined by 46 degrees plus or minus 2 degrees as the west side is nearest. Although SED modeling and sub-millimeter imagery suggested the presence of a gap in the disk, with the inner edge of the outer disk estimated to be located at 25 - 30 AU, we detect no evidence of a gap at the limit of our inner working angle (23AU) at the near-infrared wavelength. We attribute the observed strong polarization (up to 66 %) to light scattering by dust grains in the disk. However, neither polarization models of the circumstellar disk based on Rayleigh scattering nor Mie scattering approximations were consistent with the observed azimuthal profile of the polarization degrees of the disk. Instead, a geometric optics model of the disk with nonspherical grains with the radii of 30 micrometers is consistent with the observed profile. We suggest that the dust grains have experienced frequent collisional coagulations and have grown in the circumstellar disk of UX Tau A.

  5. Retrieval of Precise Radial Velocities from High Resolution Near-Infrared Spectra of M Dwarfs

    NASA Astrophysics Data System (ADS)

    Gao, Peter; Plavchan, Peter; Gagne, Jonathan; Furlan, Elise; Bottom, Michael; Anglada-Escudé, Guillem; White, Russel J.; Davison, Cassy; Mills, Sean; Beichman, Charles A.; Brinkworth, Carolyn; Johnson, John; Ciardi, David R.; Wallace, J. Kent; Mennesson, Bertrand; von Braun, Kaspar; Vasisht, Gautam; Prato, Lisa A.; Kane, Stephen R.; Tanner, Angelle M.; Walp, Bernie; Crawford, Sam; Lin, Sean

    2015-01-01

    We present a data analysis pipeline focused on obtaining precision radial velocities (RV) of M Dwarfs from spectra taken between 2.309 and 2.316 microns by the CSHELL spectrograph (R~46,000) at NASA's Infrared Telescope Facility with the aid of a methane isotopologue gas cell (see poster by Plavchan et al. at this meeting). The pipeline compares the observed spectra with a forward model defined by parameters that are optimized using a simplex amoeba algorithm. The stellar template is optimized simultaneously with the fit parameters in an iterative process. The pipeline accounts for temporal variations in the spectral wavelength solution, line spread function, and interference fringes due to instrumental effects. We apply our pipeline to the M Dwarfs GJ 15 A and GJ 876 and the M Giant SV Peg. For GJ 15 A, we are able to obtain 30 m/s RV precision. For the planet host GJ 876, the two most massive planets are easily retrievable from our RV curve. For SV Peg, the single night RV precision can be as low as 15 m/s, with < 5 m/s obtainable through data stacking.

  6. High resolution far-infrared observations of the evolved H II region M16

    SciTech Connect

    McBreen, B.; Fazio, G.G.; Jaffe, D.T.

    1982-03-01

    M16 is an evolved, extremely density bounded H II region, which now consists only of a series of ionization fronts at molecular cloud boundaries. The source of ionization is the OB star cluster (NGC 6611) which is about 5 x 10/sup 6/ years old. We used the CFA/UA 102 cm balloon-borne telescope to map this region and detected three far-infrared (far-IR) sources embedded in an extended ridge of emission. Source I is an unresolved far-IR source embedded in a molecular cloud near a sharp ionization front. An H/sub 2/O maser is associated with this source, but no radio continuum emission has been observed. The other two far-IR sources (II and III) are associated with ionized gas-molecular cloud interfaces, with the far-IR radiation arising from dust at the boundary heated by the OB cluster. Source II is located at the southern prominent neutral intrusion with its associated bright rims and dark ''elephant trunk'' globules that delineate the current progress of the ionization front into the neutral material, and Source III arises at the interface of the northern molecular cloud fragment.

  7. Calibration of high resolution remote sensing instruments in the visible and near infrared

    NASA Astrophysics Data System (ADS)

    Schüller, L.; Fischer, J.; Armbruster, W.; Bartsch, B.

    1997-05-01

    Measurements of the reflected solar radiation with high spectral resolution airborne instruments are usually used to develop new remote sensing techniques. The observed spectral features in the signals provide the possibility to define useful band settings for future satellite instruments. A precise wavelength and radiometric calibration is a prerequisite for such tasks. In this paper, a calibration procedure for the airborne spectrometer OVID is presented. The Optical Visible and near Infrared Detector consists of two similar detector systems, (600 - 1100 nm = VIS and 900 - 1700 nm = NIR). The spectral resolution is ~1.7 nm for the VIS-system and ~6 nm for the IR-system. This instrument is applied for the retrieval of water vapour content, aerosol and cloud properties. Besides the spectral and intensity calibration, also corrections for the dark current signals and for defective pixels have been performed. An indirect verification of the calibration procedure by the comparison of OVID measurements in cloudy and cloud free atmospheres with radiative transfer simulations is discussed in this paper. The used radiation transfer model MOMO is based on the matrix operator method.

  8. High-resolution infrared spectroscopy of atomic bromine in solid parahydrogen and orthodeuterium

    NASA Astrophysics Data System (ADS)

    Raston, Paul L.; Kettwich, Sharon C.; Anderson, David T.

    2013-10-01

    This work extends our earlier investigation of the near-infrared absorption spectroscopy of atomic bromine (Br) trapped in solid parahydrogen (pH2) and orthodeuterium (oD2) [S. C. Kettwich, L. O. Paulson, P. L. Raston, and D. T. Anderson, J. Phys. Chem. A 112, 11153 (2008)]. We report new spectroscopic observations on a series of double transitions involving excitation of the weak Br-atom spin-orbit (SO) transition (2P1/2 ← 2P3/2) in concert with phonon, rotational, vibrational, and rovibrational excitation of the solid molecular hydrogen host. Further, we utilize the rapid vapor deposition technique to produce pH2 crystals with a non-equilibrium mixture of face centered cubic (fcc) and hexagonal closed packed (hcp) crystal domains in the freshly deposited solid. Gentle annealing (T = 4.3 K) of the pH2 sample irreversibly converts the higher energy fcc crystal domains to the slightly more stable hcp structure. We follow the extent of this conversion process using the intensity of the U1(0) transition of solid pH2 and correlate crystal structure changes with changes in the integrated intensity of Br-atom absorption features. Annealing the pH2 solid causes the integrated intensity of the zero-phonon Br SO transition to increase approximately 45% to a value that is 8 times larger than the gas phase value. We show that the magnitude of the increase is strongly correlated to the fraction of hcp crystal domains within the solid. Theoretical calculations presented in Paper II show that these intensity differences are caused by the different symmetries of single substitution sites for these two crystal structures. For fully annealed Br-atom doped pH2 solids, where the crystal structure is nearly pure hcp, the Br-atom SO transition sharpens considerably and shows evidence for resolved hyperfine structure.

  9. Mid-Infrared OPO for High Resolution Measurements of Trace Gases in the Mars Atmosphere

    NASA Technical Reports Server (NTRS)

    Yu, Anthony W.; Numata,Kenji; Riris, haris; Abshire, James B.; Allan, Graham; Sun, Xiaoli; Krainak, Michael A.

    2008-01-01

    The Martian atmosphere is composed primarily (>95%) of CO2 and N2 gas, with CO, O2, CH4, and inert gases such as argon comprising most of the remainder. It is surprisingly dynamic with various processes driving changes in the distribution of CO2, dust, haze, clouds and water vapor on global scales in the meteorology of Mars atmosphere [I]. The trace gases and isotopic ratios in the atmosphere offer important but subtle clues as to the origins of the planet's atmosphere, hydrology, geology, and potential for biology. In the search for life on Mars, an important process is the ability of bacteria to metabolize inorganic substrates (H2, CO2 and rock) to derive energy and produce methane as a by-product of anaerobic metabolism. Trace gases have been measured in the Mars atmosphere from Earth, Mars orbit, and from the Mars surface. The concentration of water vapor and various carbon-based trace gases are observed in variable concentrations. Within the past decade multiple groups have reported detection of CH4, with concentrations in the 10's of ppb, using spectroscopic observations from Earth [2]. Passive spectrometers in the mid-infrared (MIR) are restricted to the sunlit side of the planet, generally in the mid latitudes, and have limited spectral and spatial resolution. To accurately map the global distribution and to locate areas of possibly higher concentrations of these gases such as plumes or vents requires an instrument with high sensitivity and fine spatial resolution that also has global coverage and can measure during both day and night. Our development goal is a new MIR lidar capable of measuring, on global scales, with sensitivity, resolution and precision needed to characterize the trace gases and isotopic ratios of the Martian atmosphere. An optical parametric oscillator operating in the MIR is well suited for this instrument. The sufficient wavelength tuning range of the OPO can extend the measurements to other organic molecules, CO2, atmospheric water

  10. High resolution infrared spectroscopy from space: A preliminary report on the results of the Atmospheric Trace Molecule Spectroscopy (ATMOS) experiment on Spacelab 3

    NASA Technical Reports Server (NTRS)

    Farmer, Crofton B.; Raper, Odell F.

    1987-01-01

    The ATMOS (Atmospheric Trace Molecule Spectroscopy) experiment has the broad purpose of investigating the physical structure, chemistry, and dynamics of the upper atmosphere through the study of the distributions of the neutral minor and trace constituents and their seasonal and long-term variations. The technique used is high-resolution infrared absorption spectroscopy using the Sun as the radiation source, observing the changes in the transmission of the atmosphere as the line-of-sight from the Sun to the spacecraft penetrates the atmosphere close to the Earth's limb at sunrise and sunset. During these periods, interferograms are generated at the rate of one each second which yield, when transformed, high resolution spectra covering the 2.2 to 16 micron region of the infrared. Twenty such occultations were recorded during the Spacelab 3 flight, which have produced concentration profiles for a large number of minor and trace upper atmospheric species in both the Northern and Southern Hemispheres. Several of these species have not previously been observed in spectroscopic data. The data reduction and analysis procedures used following the flight are discussed; a number of examples of the spectra obtained are shown, and a bar graph of the species detected thus far in the analysis is given which shows the altitude ranges for which concentration profiles were retrieved.

  11. A High Resolution, Unobscured View of the Active Regions in (Ultra) Luminous Infrared Galaxies from a VLA 33 GHz Survey

    NASA Astrophysics Data System (ADS)

    Barcos-Muñoz, Loreto; Leroy, Adam K.; Evans, Aaron S.; Armus, Lee; Condon, James J.; Mazzarella, Joseph M.; Meier, David S.; Momjian, Emmanuel; Murphy, Eric J.; Ott, Juergen; Privon, George C.; Reichardt, Ashley; Sakamoto, Kazushi; Sanders, David B.; Schinnerer, Eva; Stierwalt, Sabrina; Surace, Jason A.; Thompson, Todd A.; Walter, Fabian

    2016-01-01

    I will present a new survey of 33 GHz radio continuum emission from local U/LIRGs carried out using the Karl G. Jansky Very Large Array (VLA). This is the first such survey and it combines high resolution, good sensitivity, and multi-configuration observations that should have sensitivity to emission on all spatial scales. (Ultra) luminous infrared galaxies host some of the most extreme star-forming environments in the local universe, with large reservoirs of molecular gas and dust concentrated in the central few kpc. Our VLA observations allow us to see through the dust in these systems and to resolve the sizes of their active regions, which is essential to understand the surface and volume densities of star formation and gas in these extreme systems. I will present the best size measurements to date of the active regions for our 22 targets. I will show what these sizes imply about gas volume and surface density and infrared luminosity surface densities. I will also lay out the physical implications of these values for the strength of star formation and feedback (especially radiative feedback) in extreme environments.

  12. A High Resolution, Unobscured View of the Active Regions in (Ultra) Luminous Infrared Galaxies from a VLA 33 GHz Survey

    NASA Astrophysics Data System (ADS)

    Barcos-Muñoz, L.; Leroy, A.; Evans, A.; et al.

    2016-06-01

    I will present a new survey of 33 GHz radio continuum emission from local U/LIRGs carried out using the Karl G. Jansky Very Large Array (VLA). This is the first such survey and it combines high resolution, good sensitivity, and multi-configuration observations that should have sensitivity to emission on all spatial scales. (Ultra) luminous infrared galaxies host some of the most extreme star-forming environments in the local universe, with large reservoirs of molecular gas and dust concentrated in the central few kpc. Our VLA observations allow us to see through the dust in these systems to resolve the sizes of their active regions, which is essential to understand the surface and volume densities of star formation and gas in these extreme systems. I will present the best size measurements to date of the active regions for our 22 targets. I will show what these sizes imply about gas volume and surface density and infrared luminosity surface densities. I will also lay out the physical implications of these values for the strength of star formation and feedback (especially radiative feedback) in extreme environments.

  13. Updating Object for GIS Database Information Using High Resolution Satellite Images: a Case Study Zonguldak

    NASA Astrophysics Data System (ADS)

    Alkan, M.; Arca, D.; Bayik, Ç.; Marangoz, A. M.

    2011-09-01

    Nowadays Geographic Information Systems (GIS) uses Remote Sensing (RS) data for a lot of applications. One of the application areas is the updating of the GIS database using high resolution imagery. In this context high resolution satellite imagery data is very important for many applications areas today's and future. And also, high resolution satellite imagery data will be used in many applications for different purposes. Information systems needs to high resolution imagery data for updating. Updating is very important component for the any of the GIS systems. One of this area will be updated and kept alive GIS database information. High resolution satellite imagery is used with different data base which serve map information via internet and different aims of information systems applications in future topographic and cartographic information systems will very important in our country in this sense use of the satellite images will be unavoidable. In this study explain to how is acquired to satellite images and how is use this images in information systems for object and roads. Firstly, pan-sharpened two of the IKONOS's images have been produced by fusion of high resolution PAN and MS images using PCI Geomatica v9.1 software package. Automatic object extraction has been made using eCognition v4.0.6. On the other hand, these objects have been manually digitized from high resolution images using ArcGIS v9.3. software package. Application section of in this study, satellite images data will be compared each other and GIS objects and road database. It is also determined which data is useful in Geographic Information Systems. Finally, this article explains that integration of remote sensing technology and GIS applications.

  14. A high-resolution near-infrared extraterrestrial solar spectrum derived from ground-based Fourier transform spectrometer measurements

    NASA Astrophysics Data System (ADS)

    Menang, Kaah P.; Coleman, Marc D.; Gardiner, Tom D.; Ptashnik, Igor V.; Shine, Keith P.

    2013-06-01

    A detailed spectrally resolved extraterrestrial solar spectrum (ESS) is important for line-by-line radiative transfer modeling in the near-IR. Very few observationally based high-resolution ESS are available in this spectral region. Consequently, the theoretically calculated ESS by Kurucz has been widely adopted. We present the CAVIAR (Continuum Absorption at Visible and Infrared Wavelengths and its Atmospheric Relevance) ESS, which is derived using the Langley technique applied to calibrated observations using a ground-based high-resolution Fourier transform spectrometer (FTS) in atmospheric windows from 2000 to 10,000 cm-1 (1-5 µm). There is good agreement between the strengths and positions of solar lines between the CAVIAR and the satellite-based Atmospheric Chemistry Experiment-FTS ESS, in the spectral region where they overlap, and good agreement with other ground-based FTS measurements in two near-IR windows. However, there are significant differences in the structure between the CAVIAR ESS and spectra from semiempirical models. In addition, we found a difference of up to 8% in the absolute (and hence the wavelength-integrated) irradiance between the CAVIAR ESS and that of Thuillier et al., which was based on measurements from the Atmospheric Laboratory for Applications and Science satellite and other sources. In many spectral regions, this difference is significant, because the coverage factor k = 2 (or 95% confidence limit) uncertainties in the two sets of observations do not overlap. Because the total solar irradiance is relatively well constrained, if the CAVIAR ESS is correct, then this would indicate an integrated "loss" of solar irradiance of about 30 W m-2 in the near-IR that would have to be compensated by an increase at other wavelengths.

  15. First High-Resolution Infrared Spectroscopic Measurements of Comet 2P/Encke: Unusual Organic Composition and Low Rotational Temperatures

    NASA Astrophysics Data System (ADS)

    Radeva, Yana L.; Mumma, M. J.; Villanueva, G. L.; Bonev, B. P.; DiSanti, M. A.; A'Hearn, M. F.; Dello Russo, N.

    2012-10-01

    We present the first high-resolution infrared spectra of the ecliptic comet 2P/Encke, acquired on UT 4 - 6 Nov. 2003, with the Near Infrared Echelle Spectrograph (NIRSPEC) on the Keck II telescope. 2P/Encke is a dynamical end-member among comets. Its very short period of 3.3 years (with perihelion at 0.34 AU and aphelion at 4.09 AU) exposes the nucleus to unusually high insolation throughout its orbit, raising the prospect that native ices may have experienced significant fractionation over time. Here, we present flux-calibrated spectra, production rates, and mixing ratios for H2O, CH3OH, HCN, H2CO, C2H2, C2H6, CH4 and CO, and compare the abundance ratios with the “organics-normal” population. We also extracted very low rotational temperatures (20 - 30 K) for H2O, HCN, and CH3OH in the near-nucleus coma, which correlate with one of the lowest cometary gas production rates ( 1027 molecules s-1) measured thus far in the infrared. We determined that 2P/Encke is enriched in CH3OH, but depleted in C2H6, C2H2, HCN, CH4, H2CO and CO. We compared mixing ratios of these organic species measured on separate dates, and found no evidence of macroscopic chemical heterogeneity in this cometary nucleus, however, we are limited by sparse temporal sampling of our observations. The depleted abundances of most measured species but retention of the high temperature volatiles (H2O, CH3OH) are consistent with fractionation of 2P/Encke’s native ices by thermal processing while in its current orbit. 2P/Encke is unique in terms of its short period, unusual organic composition, low rotational temperatures and low production rates. The discovery of its unusual organic composition is an important contribution to the emerging chemical taxonomy of comets.

  16. High-Resolution Infrared Spectrscopy of the Hydroxymethyl Radical in Solid Parahydrogen

    NASA Astrophysics Data System (ADS)

    Balabanoff, Morgan E.; Anderson, David T.

    2016-06-01

    Interest in the hydroxymethyl radical, CH2OH, stems primarily from its importance as a reaction intermediate. However, this radical is also of interest from a spectroscopic point of view with large amplitude COH torsional tunneling and out of plane CH2 wagging motions. The first IR detection of CH2OH was accomplished via matrix isolation spectroscopy over 40 years ago by Jacox. Reisler and co-workers detected CH2OH in the gas-phase using the sensitivity of double resonance ionization detected IR spectroscopy to probe the OH stretch, asymmetric CH stretch, and symmetric CH stretch vibrational modes with partial rotational resolution (0.4 wn). Most recently, the Nesbitt group published the first fully rotationally resolved IR spectrum of CH2OH via the Ka=0←0 band of the symmetric CH stretch. These researchers were able to unambiguously assign the identified transitions to a Watson A-reduced symmetric top Hamiltonian thereby producing improved values for the symmetric CH stretch rotational constants and vibrational band origin. However, in this same work the authors point out a number of remaining unresolved issues. Motivated by these gas-phase observations, we decided to return to the matrix isolation studies of CH2OH, however utilizing solid parahydrogen as a matrix host to improve upon the sensitivity and resolution of the previous matrix isolation studies. Based on our measurements, while the end-over-end rotation of the CH2OH radical is quenched, rotational motion around the a-axis is nearly free permitting both A-type and B-type transitions to be resolved. In the case of the OH stretch mode, both A-type and B-type transitions are observed with an energy difference that makes sense based on the gas-phase CH2OH rotational constants. However, for the symmetric CH stretch mode, the same mode recently assigned by Nesbitt and co-workers, two absorption features are also observed but the energy difference and intensities of the two features do not match predictions

  17. Jet-Cooled High Resolution Infrared Spectroscopy of Small Van Der Waals SF_6 Clusters

    NASA Astrophysics Data System (ADS)

    Asselin, Pierre; Boudon, Vincent; Potapov, Alexey; Bruel, Laurent; Gaveau, Marc-André; Mons, Michel

    2016-06-01

    Using a pulsed slit nozzle multipass absorption spectrometer with a tunable quantum cascade laser we investigated van der Waals clusters involving sulfur hexafluoride in the spectral range near the νb{3} stretching vibration. Different sized homo-complexes were generated in a planar supersonic expansion with typically 0,5 % SF_6 diluted in 6 bar He. Firstly, several rotationally resolved parallel and perpendicular bands of (SF_6)_2, at 934,0 and 956,1 wn (#1 structure) in agreement with Takami et al. but also one band at 933,6 wn (#2 structure) never observed previously, were analyzed in light of a recent theoretical study predicting three nearly isoenergetic isomers of D2d, C2h and C_2 symmetry for the dimer. Furthermore, some broader bands were detected around 938 and 964 wn and assigned to (SF_6)_3 and (SF_6)_4 clusters on the grounds of concentration effects and/or ab initio calculations. Lastly, with 0,5 % rare gas Rg (Rg = Ne, Ar, Kr and Xe) added to the SF_6:He gas mixture, a series of van der Waals (SF_6)_2-Rg hetero-trimers were observed, which display a remarkable linear dependence of the vibrational shift with the polarizability of the rare gas atom provided that the initial SF_6 dimer structure is #2 . In the same time no transitions belonging to the binary complexes SF_6-Rg were found near the νb{3} monomer band. This result suggests a complex thermodynamics within the pulsed supersonic expansion leading to the preponderance of (SF_6)_2-Rg clusters over SF_6-Rg binary systems. R. D. Urban and M. Takami, J. Chem. Phys. 103, 9132 (1995). T. Vazhappily, A. Marjolin and K. D. Jordan, J. Phys. Chem. B, DOI: 10.1021/acs.jpcb.5b09419 (2015).

  18. A high-resolution three-dimensional far-infrared thermal and true-color imaging system for medical applications.

    PubMed

    Cheng, Victor S; Bai, Jinfen; Chen, Yazhu

    2009-11-01

    As the needs for various kinds of body surface information are wide-ranging, we developed an imaging-sensor integrated system that can synchronously acquire high-resolution three-dimensional (3D) far-infrared (FIR) thermal and true-color images of the body surface. The proposed system integrates one FIR camera and one color camera with a 3D structured light binocular profilometer. To eliminate the emotion disturbance of the inspector caused by the intensive light projection directly into the eye from the LCD projector, we have developed a gray encoding strategy based on the optimum fringe projection layout. A self-heated checkerboard has been employed to perform the calibration of different types of cameras. Then, we have calibrated the structured light emitted by the LCD projector, which is based on the stereo-vision idea and the least-squares quadric surface-fitting algorithm. Afterwards, the precise 3D surface can fuse with undistorted thermal and color images. To enhance medical applications, the region-of-interest (ROI) in the temperature or color image representing the surface area of clinical interest can be located in the corresponding position in the other images through coordinate system transformation. System evaluation demonstrated a mapping error between FIR and visual images of three pixels or less. Experiments show that this work is significantly useful in certain disease diagnoses. PMID:19782632

  19. The Apache Point Observatory Galactic Evolution Experiment (APOGEE) high-resolution near-infrared multi-object fiber spectrograph

    NASA Astrophysics Data System (ADS)

    Wilson, John C.; Hearty, Fred; Skrutskie, Michael F.; Majewski, Steven; Schiavon, Ricardo; Eisenstein, Daniel; Gunn, Jim; Blank, Basil; Henderson, Chuck; Smee, Stephen; Barkhouser, Robert; Harding, Al; Fitzgerald, Greg; Stolberg, Todd; Arns, Jim; Nelson, Matt; Brunner, Sophia; Burton, Adam; Walker, Eric; Lam, Charles; Maseman, Paul; Barr, Jim; Leger, French; Carey, Larry; MacDonald, Nick; Horne, Todd; Young, Erick; Rieke, George; Rieke, Marcia; O'Brien, Tom; Hope, Steve; Krakula, John; Crane, Jeff; Zhao, Bo; Carr, Mike; Harrison, Craig; Stoll, Robert; Vernieri, Mary A.; Holtzman, Jon; Shetrone, Matt; Allende-Prieto, Carlos; Johnson, Jennifer; Frinchaboy, Peter; Zasowski, Gail; Bizyaev, Dmitry; Gillespie, Bruce; Weinberg, David

    2010-07-01

    The Apache Point Observatory Galactic Evolution Experiment (APOGEE) will use a dedicated 300-fiber, narrow-band (1.5-1.7 micron), high resolution (R~30,000), near-infrared spectrograph to survey approximately 100,000 giant stars across the Milky Way. This survey, conducted as part of the Sloan Digital Sky Survey III (SDSS III), will revolutionize our understanding of kinematical and chemical enrichment histories of all Galactic stellar populations. The instrument, currently in fabrication, will be housed in a separate building adjacent to the 2.5 m SDSS telescope and fed light via approximately 45-meter fiber runs from the telescope. The instrument design includes numerous technological challenges and innovations including a gang connector that allows simultaneous connection of all fibers with a single plug to a telescope cartridge that positions the fibers on the sky, numerous places in the fiber train in which focal ratio degradation must be minimized, a large (290 mm x 475 mm elliptically-shaped recorded area) mosaic-VPH, an f/1.4 sixelement refractive camera featuring silicon and fused silica elements with diameters as large as 393 mm, three near-within a custom, LN2-cooled, stainless steel vacuum cryostat with dimensions 1.4 m x 2.3 m x 1.3 m.

  20. Calibration of the Visible and Near-Infrared Channels of the Advanced Very High Resolution Radiometer (AVHRR) After Launch

    NASA Technical Reports Server (NTRS)

    Rao, C. R. Nagaraja; Chen, Jianhua

    1993-01-01

    The relative degradation in time of the visible(channel 1: approx.0.58-0.6 microns) and near-infrared(channel 2: approx. O.72-1.1 microns) channels of the Advanced Very High Resolution Radiometer(AVHRR), onboard the NOAA Polar-orbiting Operational Environmental Satellites(POES), has been determined, using the southeastern Libyan desert(21-23 deg N latitude; 28- 29 deg E longitude) as a time-invariant calibration target. A statistical procedure was used on the reflectance data for the two channels from the B3 data of the International Satellite Cloud Climatology Project(ISCCP) to obtain the degradation rates for the AVERRs on NOAA-7, -9, and -11 spacecraft. The degradation rates per year for channels 1 and 2 are respectively: 3.6% and 4.3%(NOAA-7); 5.9% and 3.5%(NOAA-9); and 1.2% and 2.0%(NOAA-11). The use of the degradation rates thus determined, in conjunction with 'absolute' calibrations obtained from congruent aircraft and satellite measurements, in the development of correction algorithms is illustrated with the AVHRR on the NOAA-9 spacecraft.

  1. Wavelet-based decomposition of high resolution surface plasmon microscopy V(Z) curves at visible and near infrared wavelengths.

    PubMed

    Boyer-Provera, E; Rossi, A; Oriol, L; Dumontet, C; Plesa, A; Berguiga, L; Elezgaray, J; Arneodo, A; Argoul, F

    2013-03-25

    Surface plasmon resonance is conventionally conducted in the visible range and, during the past decades, it has proved its efficiency in probing molecular scale interactions. Here we elaborate on the first implementation of a high resolution surface plasmon microscope that operates at near infrared (IR) wavelength for the specific purpose of living matter imaging. We analyze the characteristic angular and spatial frequencies of plasmon resonance in visible and near IR lights and how these combined quantities contribute to the V(Z) response of a scanning surface plasmon microscope (SSPM). Using a space-frequency wavelet decomposition, we show that the V(Z) response of the SSPM for red (632.8 nm) and near IR (1550 nm) lights includes the frequential response of plasmon resonance together with additional parasitic frequencies induced by the objective pupil. Because the objective lens pupil profile is often unknown, this space-frequency decomposition turns out to be very useful to decipher the characteristic frequencies of the experimental V(Z) curves. Comparing the visible and near IR light responses of the SSPM, we show that our objective lens, primarily designed for visible light microscopy, is still operating very efficiently in near IR light. Actually, despite their loss in resolution, the SSPM images obtained with near IR light remain contrasted for a wider range of defocus values from negative to positive Z values. We illustrate our theoretical modeling with a preliminary experimental application to blood cell imaging.

  2. HIGH-RESOLUTION MID-INFRARED SPECTROSCOPY OF NGC 7538 IRS 1: PROBING CHEMISTRY IN A MASSIVE YOUNG STELLAR OBJECT

    SciTech Connect

    Knez, Claudia; Lacy, John H.; Evans, Neal J.; Van Dishoeck, Ewine F.; Richter, Matthew J.

    2009-05-01

    We present high-resolution (R = 75,000-100,000) mid-infrared spectra of the high-mass embedded young star IRS 1 in the NGC 7538 star-forming region. Absorption lines from many rotational states of C{sub 2}H{sub 2}, {sup 13}C{sup 12}CH{sub 2}, CH{sub 3}, CH{sub 4}, NH{sub 3}, HCN, HNCO, and CS are seen. The gas temperature, column density, covering factor, line width, and Doppler shift for each molecule are derived. All molecules were fit with two velocity components between -54 and -63 km s{sup -1}. We find high column densities ({approx}10{sup 16} cm{sup -2}) for all the observed molecules compared to values previously reported and present new results for CH{sub 3} and HNCO. Several physical and chemical models are considered. The favored model involves a nearly edge-on disk around a massive star. Radiation from dust in the inner disk passes through the disk atmosphere, where large molecular column densities can produce the observed absorption line spectrum.

  3. High-resolution infrared spectroscopic measurements of Comet 2P/Encke: Unusual organic composition and low rotational temperatures

    NASA Astrophysics Data System (ADS)

    Radeva, Yana L.; Mumma, Michael J.; Villanueva, Geronimo L.; Bonev, Boncho P.; DiSanti, Michael A.; A'Hearn, Michael F.; Dello Russo, Neil

    2013-03-01

    We present high-resolution infrared spectroscopic measurements of the ecliptic Comet 2P/Encke, observed on 4-6 November 2003 during its close approach to the Earth, using the Near Infrared Echelle Spectrograph on the Keck II telescope. We present flux-calibrated spectra, production rates, and mixing ratios for H2O, CH3OH, HCN, H2CO, C2H2, C2H6, CH4 and CO. Comet 2P/Encke is a dynamical end-member among comets because of its short period of 3.3 years. Relative to “organics-normal” comets, we determined that 2P/Encke is depleted in HCN, H2CO, C2H2, C2H6, CH4 and CO, but it is enriched in CH3OH. We compared mixing ratios of these organic species measured on separate dates, and we see no evidence of macroscopic chemical heterogeneity in the nucleus of 2P/Encke, however, this conclusion is limited by sparse temporal sampling. The depleted abundances of most measured species suggest that 2P/Encke may have formed closer to the young Sun, before its insertion to the Kuiper belt, compared with “organics-normal” comets - as was previously suggested for other depleted comets (e.g. C/1999 S4 (LINEAR)). We measured very low rotational temperatures of 20-30 K for H2O, CH3OH and HCN in the near nucleus region of 2P/Encke, which correlate with one of the lowest cometary gas production rates (∼2.6 × 1027 molecules s-1) measured thus far in the infrared. This suggests that we are seeing the effects of more efficient radiative cooling, insufficient collisional excitation, and/or inefficient heating by fast H-atoms (and icy grains) in the observed region of the coma. Its extremely short orbital period, very low gas production rate, and classification as an ecliptic comet, make 2P/Encke an important addition to our growing database, and contribute significantly to the establishment of a chemical taxonomy of comets.

  4. High-Resolution Infrared Spectroscopic Measurements of Comet 2PlEncke: Unusual Organic Composition and Low Rotational Temperatures

    NASA Technical Reports Server (NTRS)

    Radeva, Yana L.; Mumma, Michael J.; Villanueva, Geronimo L.; Bonev, Boncho P.; DiSanti, Michael A.; A'Hearn, Michael F.; Dello Russo, Neil

    2013-01-01

    We present high-resolution infrared spectroscopic measurements of the ecliptic comet 2P/Encke, observed on 4-6 Nov. 2003 during its close approach to the Earth, using the Near Infrared Echelle Spectrograph on the Keck II telescope. We present flux-calibrated spectra, production rates, and mixing ratios for H2O, CH3OH, HCN, H2CO, C2H2, C2H6, CH4 and CO. Comet 2P/Encke is a dynamical end-member among comets because of its short period of 3.3 years. Relative to "organics-normal" comets, we determined that 2PlEncke is depleted in HCN, H2CO, C2H2, C2H6, CH4 and CO, but it is enriched in CH3OH. We compared mixing ratios of these organic species measured on separate dates, and we see no evidence of macroscopic chemical heterogeneity in the nucleus of 2P/Encke, however, this conclusion is limited by sparse temporal sampling. The depleted abundances of most measured species suggest that 2P/Encke may have formed closer to the young Sun, before its insertion to the Kuiper belt, compared with "organics-normal" comets - as was previously suggested for other depleted comets (e.g. C/1999 S4 (LINEAR)). We measured very low rotational temperatures of 20 - 30 K for H2O, CH3OH and HCN in the near nucleus region of 2P/Encke, which correlate with one of the lowest cometary gas production rates (approx. 2.6 x 10(exp 27) molecules/s) measured thus far in the infrared. This suggests that we are seeing the effects of more efficient radiative cooling, insufficient collisional excitation, and/or inefficient heating by fast H-atoms (and icy grains) in the observed region of the coma. Its extremely short orbital period, very low gas production rate, and classification as an ecliptic comet, make 2PlEncke an important addition to our growing database, and contribute significantly to the establishment of a chemical taxonomy of comets.

  5. Study of fish response using particle image velocimetry and high-speed, high-resolution imaging

    SciTech Connect

    Deng, Z.; Richmond, M. C.; Mueller, R. P.; Gruensch, G. R.

    2004-10-01

    Fish swimming has fascinated both engineers and fish biologists for decades. Digital particle image velocimetry (DPIV) and high-speed, high-resolution digital imaging are recently developed analysis tools that can help engineers and biologists better understand how fish respond to turbulent environments. This report details studies to evaluate DPIV. The studies included a review of existing literature on DPIV, preliminary studies to test the feasibility of using DPIV conducted at our Flow Biology Laboratory in Richland, Washington September through December 2003, and applications of high-speed, high-resolution digital imaging with advanced motion analysis to investigations of fish injury mechanisms in turbulent shear flows and bead trajectories in laboratory physical models. Several conclusions were drawn based on these studies, which are summarized as recommendations for proposed research at the end of this report.

  6. A high resolution EEG study of dynamic brain activity during video game play.

    PubMed

    Sheikholeslami, C; Yuan, H; He, E J; Bai, X; Yang, L; He, B

    2007-01-01

    A high resolution EEG study was conducted on healthy human subjects during video game play. Throughout the game playing experiment short time segments of spontaneous activity were recorded. Spectral analysis was performed on these segments for the theta-wave (4-8 Hz) and alpha-wave (8-13 Hz) bands to investigate the modulatory effects of long-lasting game play and the dynamic changes of spectral contribution in range of alpha-and theta-wave. The present results revealed that a) the frontal midline theta-wave activity increased over time relative to the eye open resting condition and b) the parietal alpha-wave activity initially decreased relative to the resting condition, then followed by a slow increase. These experimental results indicate the high resolution EEG provides a useful quantitative analysis tool for studying dynamic brain activity.

  7. High Resolution Imager (HRI) for the Roentgen Satellite (ROSAT) definition study

    NASA Technical Reports Server (NTRS)

    1983-01-01

    The design of the high resolution imager (HRI) on HEAO 2 was modified for use in the instrument complement of the Roentgen Satellite (ROSAT). Mechanical models of the front end assembly, central electronics assembly, and detector assembly were used to accurately represent the HRI envelope for both fit checks and focal plane configuration studies. The mechanical and electrical interfaces were defined and the requirements for electrical ground support equipment were established. A summary description of the ROSAT telescope and mission is included.

  8. Spartan Infrared Camera, a High-Resolution Imager for the SOAR Telescope: Design, Tests, and On-Telescope Performance

    NASA Astrophysics Data System (ADS)

    Loh, Edwin D.; Biel, Jason D.; Davis, Michael W.; Laporte, René; Loh, Owen Y.; Verhanovitz, Nathan J.

    2012-04-01

    The Spartan Infrared Camera provides tip-tilt corrected imaging for the SOAR Telescope in the 900-2500 nm spectral range with four 2048 × 2048 HAWAII-2 detectors. The camera has two plate scales: high-resolution (40 mas pixel-1) for future diffraction-limited sampling in the H and K bands and wide-field (66 mas pixel-1) to cover a 5' × 5' field, over which tip-tilt correction is substantial. The design is described in detail. Except for CaF2 field-flattening lenses, the optics are aluminum mirrors to thermally match the aluminum cryogenic-optical box in which the optics mount. The design minimizes the tilt of the optics as the instrument rotates on the Nasmyth port of the telescope. Two components of the gravitational torque on an optic are eliminated by symmetry, and the third component is minimized by balancing the optic. The optics (including the off-axis aspherical mirrors) were aligned with precise metrology. For the detector assembly, Henein pivots are used to provide frictionless, thermally compliant, lubricant-free, and thermally conducting rotation of the detectors. The heat load is 14 W for an ambient temperature of 10°C. Cooling down takes 40 hr. An activated-charcoal getter controls permeation through the large Viton O-ring for at least nine months. We present maps of the image distortion, which amount to tens of pixels at the greatest. The wavelength of the narrowband filters shift with position in the sky. The measured Strehl ratio of the camera itself is 0.81-0.84 at λ1650 nm. The width of the best K-band image was 260 mas in unexceptional seeing measured after tuning the telescope and before moving the telescope. Since images are normally taken after pointing the telescope to a different field, this supports the idea that the image quality could be improved by better control of the focus and the shape of the primary mirror. The instrument has proved to be capable of producing images that can be stitched together to measure faint, extended

  9. Characterization of REE-Bearing Minerals and Synthetic Materials Using High Resolution Ultraviolet to Near-Infrared Reflectance Spectroscopy

    NASA Astrophysics Data System (ADS)

    Hoefen, T. M.; Livo, K. E.; Giles, S. A.; Lowers, H. A.; Swayze, G. A.; Taylor, C. D.; Verplanck, P. L.; Emsbo, P.; Koenig, A.; Mccafferty, A. E.

    2014-12-01

    Diagnostic crystal field 4fn-4fn transition features in the ultraviolet (UV) to near-infrared (NIR) region of the electromagnetic spectrum have been observed in many common rare earth element (REE)-bearing minerals. The partial filling of the 4f electron shell combined with a shielding effect caused by the fully filled 5s25p6-electron shells, which weaken any effects from external magnetic or electric fields on the electrons, makes rare earth ions unique. The narrow absorption features occur as a result of parity forbidden transitions and crystal field splitting of the trivalent REEs, and since they are well shielded, only subtle wavelengths shifts are seen in their spectral features. Synthetic single REE phosphates, carbonates, oxides, hydroxides and glasses have been measured in the lab to help identify absorption band positions that are characteristic of each REE as they occur in different minerals. Because spectral resolution is critical to identifying shifts in the absorption band positions, these materials have been measured on several different high resolution spectrometers. Using a combination of Ocean Optics USB 2000+ UV-VIS, USB2000+ VIS-NIR and ASD FS 4 spectrometers we have characterized REE-bearing materials from 0.2 to 2.5 microns with a spectral resolution of ~2 nm between 0.2 and 1.0 microns and 11 to 12 nm between 1.0 and 2.5 microns. Results to date suggest that wavelength shifts and variations in the degree of crystal field splitting allow spectral differentiation between REE-bearing minerals. To support these results, a comprehensive suite of marine phosphates, paleo-beach placers, IOCG deposits, alkaline to peralkaline igneous complexes, pegmatites associated with alkaline magmas and carbonatite intrusives, have been measured and included in our database. Core, rock chips, billets, sediment samples and grab samples were manually scanned to identify the most intense or spectrally different REE features. While REE-bearing minerals have been

  10. Revisit of Contessa Quarry (gubbio): High Resolution Study In Chron 11

    NASA Astrophysics Data System (ADS)

    Touchard, Y.; Sagnotti, L.; Rochette, P.; Montanari, A.

    With the purpose of wordlwide correlation of marine sections synchronous with the Ethiopian traps emplacement, a high resolution study of Lowrie et al. (1982) Contessa quarry section was conducted for Mid-Oligocene, with a sampling interval of 5 cm (5 ka), on a ca.12 m (ca. 1.33 Ma) height. Original magnetostratigraphy was reproduced within one meter of the measured stratigraphic height relative to the Oligo-Miocene boundary, although the new quarry is on the other side of the valley. Thanks to the presence of a major Ethiopian tephra layer at the end of C11n1r subchron it is fea- sible to locate within 20 cm this potential layer in any section with high resolution magnetostratigraphy. This tephra was identified in the Southern Indian and Atlantic Ocean but not in Gubbio, suggesting negligible fallout (<1 cm) in this site, distant by 3500 km from Ethiopia. On the other hand the good time control and constant depo- sitional rate allows the analysis of the high resolution rock magnetic record in terms of orbital cycles. Magnetic mineralogy is fairly constant (PSD magnetite) so that rock magnetic variations are mainly concentration dependent. Power spectra of the ARM and IRM time series reveal a prominent peak near ca. 400 ka and a minor one near 41 ka. The same periodicities were recognized in high-resolution Oligo-Miocene ben- thic foraminifera O18 and C13 records from Equatorial Atlantic. We conclude that the amount of magnetite in the Scaglia Cinerea Fm. of the Apennines was climatically controlled.

  11. Drone with thermal infrared camera provides high resolution georeferenced imagery of the Waikite geothermal area, New Zealand

    NASA Astrophysics Data System (ADS)

    Harvey, M. C.; Rowland, J. V.; Luketina, K. M.

    2016-10-01

    Drones are now routinely used for collecting aerial imagery and creating digital elevation models (DEM). Lightweight thermal sensors provide another payload option for generation of very high-resolution aerial thermal orthophotos. This technology allows for the rapid and safe survey of thermal areas, often present in inaccessible or dangerous terrain. Here we present a 2.2 km2 georeferenced, temperature-calibrated thermal orthophoto of the Waikite geothermal area, New Zealand. The image represents a mosaic of nearly 6000 thermal images captured by drone over a period of about 2 weeks. This is thought by the authors to be the first such image published of a significant geothermal area produced by a drone equipped with a thermal camera. Temperature calibration of the image allowed calculation of heat loss (43 ± 12 MW) from thermal lakes and streams in the survey area (loss from evaporation, conduction and radiation). An RGB (visible spectrum) orthomosaic photo and digital elevation model was also produced for this area, with ground resolution and horizontal position error comparable to commercially produced LiDAR and aerial imagery obtained from crewed aircraft. Our results show that thermal imagery collected by drones has the potential to become a key tool in geothermal science, including geological, geochemical and geophysical surveys, environmental baseline and monitoring studies, geotechnical studies and civil works.

  12. MISTiC Winds, a Micro-Satellite Constellation Approach to High Resolution Observations of the Atmosphere using Infrared Sounding and 3D Winds Measurements

    NASA Astrophysics Data System (ADS)

    Maschhoff, K. R.; Polizotti, J. J.; Susskind, J.; Aumann, H. H.

    2015-12-01

    MISTiCTM Winds is an approach to improve short-term weather forecasting based on a miniature high resolution, wide field, thermal emission spectrometry instrument that will provide global tropospheric vertical profiles of atmospheric temperature and humidity at high (3-4 km) horizontal and vertical ( 1 km) spatial resolution. MISTiC's extraordinarily small size, payload mass of less than 15 kg, and minimal cooling requirements can be accommodated aboard a 27U-class CubeSat or an ESPA-Class micro-satellite. Low fabrication and launch costs enable a LEO sun-synchronous sounding constellation that would collectively provide frequent IR vertical profiles and vertically resolved atmospheric motion vector wind observations in the troposphere. These observations are highly complementary to present and emerging environmental observing systems, and would provide a combination of high vertical and horizontal resolution not provided by any other environmental observing system currently in operation. The spectral measurements that would be provided by MISTiC Winds are similar to those of NASA's Atmospheric Infrared Sounder that was built by BAE Systems and operates aboard the AQUA satellite. These new observations, when assimilated into high resolution numerical weather models, would revolutionize short-term and severe weather forecasting, save lives, and support key economic decisions in the energy, air transport, and agriculture arenas-at much lower cost than providing these observations from geostationary orbit. In addition, this observation capability would be a critical tool for the study of transport processes for water vapor, clouds, pollution, and aerosols. Key technical risks are being reduced through laboratory and airborne testing under NASA's Instrument Incubator Program.

  13. Developmental and morphological studies in Japanese medaka with ultra-high resolution optical coherence tomography

    PubMed Central

    Gladys, Fanny Moses; Matsuda, Masaru; Lim, Yiheng; Jackin, Boaz Jessie; Imai, Takuto; Otani, Yukitoshi; Yatagai, Toyohiko; Cense, Barry

    2015-01-01

    We propose ultra-high resolution optical coherence tomography to study the morphological development of internal organs in medaka fish in the post-embryonic stages at micrometer resolution. Different stages of Japanese medaka were imaged after hatching in vivo with an axial resolution of 2.8 µm in tissue. Various morphological structures and organs identified in the OCT images were then compared with the histology. Due to the medaka’s close resemblance to vertebrates, including humans, these morphological features play an important role in morphogenesis and can be used to study diseases that also occur in humans. PMID:25780725

  14. Mini-Sosie high-resolution seismic method aids hazards studies

    USGS Publications Warehouse

    Stephenson, W.J.; Odum, J.; Shedlock, K.M.; Pratt, T.L.; Williams, R.A.

    1992-01-01

    The Mini-Sosie high-resolution seismic method has been effective in imaging shallow-structure and stratigraphic features that aid in seismic-hazard and neotectonic studies. The method is not an alternative to Vibroseis acquisition for large-scale studies. However, it has two major advantages over Vibroseis as it is being used by the USGS in its seismic-hazards program. First, the sources are extremely portable and can be used in both rural and urban environments. Second, the shifting-and-summation process during acquisition improves the signal-to-noise ratio and cancels out seismic noise sources such as cars and pedestrians. -from Authors

  15. Thermal signatures of urban land cover types: High-resolution thermal infrared remote sensing of urban heat island in Huntsville, AL

    NASA Technical Reports Server (NTRS)

    Lo, Chor Pang

    1996-01-01

    The main objective of this research is to apply airborne high-resolution thermal infrared imagery for urban heat island studies, using Huntsville, AL, a medium-sized American city, as the study area. The occurrence of urban heat islands represents human-induced urban/rural contrast, which is caused by deforestation and the replacement of the land surface by non-evaporating and non-porous materials such as asphalt and concrete. The result is reduced evapotranspiration and more rapid runoff of rain water. The urban landscape forms a canopy acting as a transitional zone between the atmosphere and the land surface. The composition and structure of this canopy have a significant impact on the thermal behavior of the urban environment. Research on the trends of surface temperature at rapidly growing urban sites in the United States during the last 30 to 50 years suggests that significant urban heat island effects have caused the temperatures at these sites to rise by 1 to 2 C. Urban heat islands have caused changes in urban precipitation and temperature that are at least similar to, if not greater than, those predicted to develop over the next 100 years by global change models. Satellite remote sensing, particularly NOAA AVHRR thermal data, has been used in the study of urban heat islands. Because of the low spatial resolution (1.1 km at nadir) of the AVHRR data, these studies can only examine and map the phenomenon at the macro-level. The present research provides the rare opportunity to utilize 5-meter thermal infrared data acquired from an airplane to characterize more accurately the thermal responses of different land cover types in the urban landscape as input to urban heat island studies.

  16. Machine Learning Approaches for High-resolution Urban Land Cover Classification: A Comparative Study

    SciTech Connect

    Vatsavai, Raju; Chandola, Varun; Cheriyadat, Anil M; Bright, Eddie A; Bhaduri, Budhendra L; Graesser, Jordan B

    2011-01-01

    The proliferation of several machine learning approaches makes it difficult to identify a suitable classification technique for analyzing high-resolution remote sensing images. In this study, ten classification techniques were compared from five broad machine learning categories. Surprisingly, the performance of simple statistical classification schemes like maximum likelihood and Logistic regression over complex and recent techniques is very close. Given that these two classifiers require little input from the user, they should still be considered for most classification tasks. Multiple classifier systems is a good choice if the resources permit.

  17. Physical and Chemical Properties of Jupiter's Polar Vortices and Regions of Auroral Influence Revealed Through High-Resolution Infrared Imaging

    NASA Astrophysics Data System (ADS)

    Fernandes, Josh; Orton, Glenn S.; Sinclair, James; Kasaba, Yasumasa; Sato, Takao M.; Fujiyoshi, Takuya; Momary, Thomas W.; Yanamandra-Fisher, Padma A.

    2016-10-01

    We report characterization of the physical and chemical properties of Jupiter's polar regions derived from mid-infrared imaging of Jupiter covering all longitudes at unprecedented spatial resolution using the COMICS instrument at the Subaru Telescope on the nights of January 24 and 25, 2016 (UT). Because of Jupiter's slight axial tilt of 3°, the low angular resolution and incomplete longitudinal coverage of previous mid-infrared observations, the physical and chemical properties of Jupiter's polar regions have been poorly characterized. In advance of the Juno mission's exploration of the polar regions, this study focuses on mapping the 3-dimensional structure of Jupiter's polar regions, specifically to characterize the polar vortices and compact regions of auroral influence. Using mid-infrared images taken in the 7.8 - 24.2 µm range, we determined the 3-dimensional temperature field, mapped the para-H2 fraction and aerosol opacity at 700 mbar and lower pressures, and constrained the distribution of gaseous NH3 in Jupiter's northern and southern polar regions. Retrievals of these atmospheric parameters was performed using NEMESIS, a radiative transfer forward model and retrieval code. Preliminary results indicate that there are vortices at both poles, each with very distinct low-latitude boundaries approximately 60° (planetocentric) from the equator, which can be defined by sharp thermal gradients extending at least from the upper troposphere (500 mbar) and into the stratosphere (0.1 mbar). These polar regions are characterized by lower temperatures, lower aerosol number densities, and lower NH3 volume mixing ratios, compared with the regions immediately outside the vortex boundaries. These images also provided the highest resolution of prominent auroral-related stratospheric heating to date, revealing a teardrop-shaped morphology in the north and a sharp-edged oval shape in the south. Both appear to be contained inside the locus of H3+ auroral emission detected

  18. High-resolution neutron crystallographic studies of the hydration of the coenzyme cob(II)alamin

    SciTech Connect

    Jogl, Gerwald; Wang, Xiaoping; Mason, Sax A.; Kovalevsky, Andrey; Mustyakimov, Marat; Fisher, Zöe; Hoffman, Christina; Kratky, Christoph; Langan, Paul

    2011-06-01

    High-resolution crystallographic studies of the hydration of the coenzyme cob(II)alamin have provided hydrogen-bond parameters of unprecedented accuracy for a biomacromolecule. The hydration of the coenzyme cob(II)alamin has been studied using high-resolution monochromatic neutron crystallographic data collected at room temperature to a resolution of 0.92 Å on the original D19 diffractometer with a prototype 4° × 64° detector at the high-flux reactor neutron source run by the Institute Laue–Langevin. The resulting structure provides hydrogen-bonding parameters for the hydration of biomacromolecules to unprecedented accuracy. These experimental parameters will be used to define more accurate force fields for biomacromolecular structure refinement. The presence of a hydrophobic bowl motif surrounded by flexible side chains with terminal functional groups may be significant for the efficient scavenging of ligands. The feasibility of extending the resolution of this structure to ultrahigh resolution was investigated by collecting time-of-flight neutron crystallographic data during commissioning of the TOPAZ diffractometer with a prototype array of 14 modular 2° × 21° detectors at the Spallation Neutron Source run by Oak Ridge National Laboratory.

  19. High resolution neutron crystallographic studies of the hydration of coenzyme cob(II)alamin

    SciTech Connect

    Jogl, Gerwald; Wang, Xiaoping; Mason, Sax; Kovalevsky, Andrey; Mustyakimov, Marat; Fisher, Zoe; Hoffmann, Christina; Kratky, Christoph; Langan, Paul

    2011-01-01

    The hydration of coenzyme cob(II)alamin has been studied using high resolution monochromatic neutron crystallographic data collected at room temperature to a resolution of surrounded by flexible side chains with terminal functional groups may be significant for 0.92 on the original diffractometer D19 with a prototype 4o x 64o detector at the high-flux reactor neutron source run by the Institute Laue Langevin. The resulting structure provides H bonding parameters for the hydration of biomacromolecules to unprecedented accuracy. These experimental parameters will be used to define more accurate force-fields for biomacromolecular structure refinement. The presence of a hydrophobic bowl motif efficient scavenging of ligands. The feasibility of extending the resolution of this structure to ultra high resolution was investigated by collecting time-of-flight neutron crystallographic data on diffractometer TOPAZ with a prototype array of 14 modular 21o x 21o detectors at the Spallation Neutron Source run by Oak Ridge National Laboratory.

  20. A digitally configurable measurement platform using audio cards for high-resolution electronic transport studies

    NASA Astrophysics Data System (ADS)

    Gopman, D. B.; Bedau, D.; Kent, A. D.

    2012-05-01

    We report on a software-defined digitally configurable measurement platform for determining electronic transport properties in nanostructures with small readout signals. By using a high-resolution audio analog-to-digital/digital-to-analog converter in a digitally compensated bridge configuration we significantly increase the measurement speed compared to established techniques and simultaneously acquire large and small signal characteristics. We characterize the performance (16 bit resolution, 100 dB dynamic range at 192 kS/s) and demonstrate the application of this measurement platform for studying the transport properties of spin-valve nanopillars, a two-terminal device that exhibits giant magnetoresistance and whose resistance can be switched between two levels by applied magnetic fields and by currents applied by the audio card. The high resolution and fast sampling capability permits rapid acquisition of deep statistics on the switching of a spin-valve nanopillar and reduces the time to acquire the basic properties of the device - a state-diagram showing the magnetic configurations as function of applied current and magnetic field - by orders of magnitude.

  1. [Study on the Advanced Czerny-Turner Imaging Spectrometer with High Resolution in Broadband].

    PubMed

    Yan, Ling-wei

    2015-06-01

    This paper studies the Czerny-Turner optical structure which is used for the application in imaging spectrometers. To obtain the perfect astigmatism-corrected condition, the Czerny-Turner system has been analyzed and advanced. The basic structure of optical system is still as the traditional form which is composed by the spherical collimating mirror, the plane grating and the spherical focusing mirror. However, an off-the-shelf cylindrical lens is added after the focusing mirror to remove astigmatism differences between the tangential direction and the sagittaI direction. It makes the advanced optical system presents high resolution over the full bandwidth and decreases the cost. An example of the imaging spectrum system in the waveband of 380-760 nm has been designed to prove our theory. A system owns that NA equals to 0.05, and the modulation transfer functions (MTF) of all fields of view are more than 0.59 over the broadband under the required Nyquist frequency (20 lp x mm(-1)). It certificates that the optical system theory can be applied to the small scale imaging spectrometer with high resolution in spectral broadband.

  2. a Detailed Study about Digital Surface Model Generation Using High Resolution Satellite Stereo Imagery

    NASA Astrophysics Data System (ADS)

    Gong, K.; Fritsch, D.

    2016-06-01

    Photogrammetry is currently in a process of renaissance, caused by the development of dense stereo matching algorithms to provide very dense Digital Surface Models (DSMs). Moreover, satellite sensors have improved to provide sub-meter or even better Ground Sampling Distances (GSD) in recent years. Therefore, the generation of DSM from spaceborne stereo imagery becomes a vivid research area. This paper presents a comprehensive study about the DSM generation of high resolution satellite data and proposes several methods to implement the approach. The bias-compensated Rational Polynomial Coefficients (RPCs) Bundle Block Adjustment is applied to image orientation and the rectification of stereo scenes is realized based on the Project-Trajectory-Based Epipolarity (PTE) Model. Very dense DSMs are generated from WorldView-2 satellite stereo imagery using the dense image matching module of the C/C++ library LibTsgm. We carry out various tests to evaluate the quality of generated DSMs regarding robustness and precision. The results have verified that the presented pipeline of DSM generation from high resolution satellite imagery is applicable, reliable and very promising.

  3. Fragmentation and conformation study of ephedrine by low- and high-resolution mass selective UV spectroscopy

    NASA Astrophysics Data System (ADS)

    Chervenkov, S.; Wang, P. Q.; Braun, J. E.; Neusser, H. J.

    2004-10-01

    The neurotransmitter molecule, ephedrine, has been studied by mass-selective low- and high-resolution UV resonance enhanced two-photon ionization spectroscopy. Under all experimental conditions we observed an efficient fragmentation upon ionization. The detected vibronic peaks in the spectrum are classified according to the efficiency of the fragmentation, which leads to the conclusion that there exist three different species in the molecular beam: ephedrine-water cluster and two distinct conformers. The two-color two-photon ionization experiment with a decreased energy of the second photon leads to an upper limit of 8.3 eV for the ionization energy of ephedrine. The high-resolution (70 MHz) spectrum of the strongest vibronic peak in the spectrum measured at the fragment (m/z=58) mass channel displays a pronounced and rich rotational structure. Its analysis by the use of a specially designed computer-aided rotational fit process yields accurate rotational constants for the S0 and S1 states and the transition moment ratio, providing information on the respective conformational structure.

  4. [Study on the Advanced Czerny-Turner Imaging Spectrometer with High Resolution in Broadband].

    PubMed

    Yan, Ling-wei

    2015-06-01

    This paper studies the Czerny-Turner optical structure which is used for the application in imaging spectrometers. To obtain the perfect astigmatism-corrected condition, the Czerny-Turner system has been analyzed and advanced. The basic structure of optical system is still as the traditional form which is composed by the spherical collimating mirror, the plane grating and the spherical focusing mirror. However, an off-the-shelf cylindrical lens is added after the focusing mirror to remove astigmatism differences between the tangential direction and the sagittaI direction. It makes the advanced optical system presents high resolution over the full bandwidth and decreases the cost. An example of the imaging spectrum system in the waveband of 380-760 nm has been designed to prove our theory. A system owns that NA equals to 0.05, and the modulation transfer functions (MTF) of all fields of view are more than 0.59 over the broadband under the required Nyquist frequency (20 lp x mm(-1)). It certificates that the optical system theory can be applied to the small scale imaging spectrometer with high resolution in spectral broadband. PMID:26601404

  5. High Resolution Studies of the Origins of Polyatomic Ions in Inductively Coupled Plasma-Mass Spectrometry

    SciTech Connect

    Ferguson, Jill Wisnewski

    2006-01-01

    The inductively coupled plasma (ICP) is an atmospheric pressure ionization source. Traditionally, the plasma is sampled via a sampler cone. A supersonic jet develops behind the sampler, and this region is pumped down to a pressure of approximately one Torr. A skimmer cone is located inside this zone of silence to transmit ions into the mass spectrometer. The position of the sampler and skimmer cones relative to the initial radiation and normal analytical zones of the plasma is key to optimizing the useful analytical signal [1]. The ICP both atomizes and ionizes the sample. Polyatomic ions form through ion-molecule interactions either in the ICP or during ion extraction [l]. Common polyatomic ions that inhibit analysis include metal oxides (MO+), adducts with argon, the gas most commonly used to make up the plasma, and hydride species. While high resolution devices can separate many analytes from common interferences, this is done at great cost in ion transmission efficiency--a loss of 99% when using high versus low resolution on the same instrument [2]. Simple quadrupole devices, which make up the bulk of ICP-MS instruments in existence, do not present this option. Therefore, if the source of polyatomic interferences can be determined and then manipulated, this could potentially improve the figures of merit on all ICP-MS devices, not just the high resolution devices often utilized to study polyatomic interferences.

  6. A digitally configurable measurement platform using audio cards for high-resolution electronic transport studies.

    PubMed

    Gopman, D B; Bedau, D; Kent, A D

    2012-05-01

    We report on a software-defined digitally configurable measurement platform for determining electronic transport properties in nanostructures with small readout signals. By using a high-resolution audio analog-to-digital/digital-to-analog converter in a digitally compensated bridge configuration we significantly increase the measurement speed compared to established techniques and simultaneously acquire large and small signal characteristics. We characterize the performance (16 bit resolution, 100 dB dynamic range at 192 kS/s) and demonstrate the application of this measurement platform for studying the transport properties of spin-valve nanopillars, a two-terminal device that exhibits giant magnetoresistance and whose resistance can be switched between two levels by applied magnetic fields and by currents applied by the audio card. The high resolution and fast sampling capability permits rapid acquisition of deep statistics on the switching of a spin-valve nanopillar and reduces the time to acquire the basic properties of the device - a state-diagram showing the magnetic configurations as function of applied current and magnetic field - by orders of magnitude. PMID:22667635

  7. High Resolution Infrared Study of the 2v9 and v4 Bands of 10BF2OH and 11BF2OH: Evidence of Large Amplitude Effects for the OH- Torsion and OH-Bending Modes in the 9(2) and 4(1) and Excited States

    SciTech Connect

    Perrin, Annette M.; Bertseva, E.; Flaud, Jean-marie; Collett, Derron R.; Burger, H.; Masiello, Tony; Blake, Thomas A.

    2007-07-21

    High resolution (2-3x10-3cm-1) Fourier transform infrared spectra of gas phase 10B and 11B enriched and natural samples of BF2OH (difluoroboric acid) were recorded at Wuppertal and Richland. Starting from the results of previous studies [A.Perrin, M.Carvajal-Zaera, Z.Dutkiewicz, J.-M.Flaud, D.Collet, H.Bürger, J.Demaison, F.Willaert, H.Mäder, and N.W.Larsen, Mol. Phys. 102 , 1641 (2004); J. Breidung, J. Demaison, J.-F. D’Eu, L. Margulès, D. Collet, E.B. Mkadmi, A. Perrin and W. Thiel, J. Mol. Spectrosc. 228, 7, (2004)], it was possible to perform the first rovibrational analysis of the 2ν9 (first overtone of ν9, the OH torsion) and ν4 (BOH bending) bands located at about 1043.9 and 961.7 cm-1 and 1042.9 and 961.5 cm-1 for the 10BF2OH and 11BF2OH isotopic species respectively. Numerous “classic” perturbations were observed in the analysis of the 2ν9 and ν4 bands. The energy levels of the 92 bright state are indeed involved in a B- type Coriolis resonance with those of the 6191 dark state. The 41 levels are perturbed by a B-type Coriolis resonance and by an anharmonic resonance with the levels of the 7191 and the 6171 dark states respectively. In addition large amplitude effects were observed for the 2ν9 and also, more surprisingly, the ν4 bands. This results in splittings of the energy levels of about 0.005 and 0.0035 cm-1 for the 92 and 41 states respectively which are easily observable in the P and R branches for both bands. The theoretical model used to reproduce the experimental levels accounts for the classic vibration –rotation resonances. Also the large amplitude torsional (or bending) effects are accounted for within the frame of the IAM (Internal Axis Method) -like approach. The Coriolis resonances between the two torsional (or bending) substates are taken into account by {Jx,Jz} non orthorhombic terms in the v-diagonal blocks. This means that the zquantification axis deviates from the a inertial axis by an axis switching effect of ~35

  8. High-resolution synchrotron infrared spectroscopy of acrolein: The vibrational levels between 700 and 820 cm-1

    NASA Astrophysics Data System (ADS)

    McKellar, A. R. W.; Billinghurst, B. E.

    2015-09-01

    The weak combination bands ν12 + ν18 and ν17 + ν18 of trans-acrolein in the 700-760 cm-1 region are observed at high resolution (<0.001 cm-1) using spectra obtained at the Canadian Light Source synchrotron radiation facility. A detailed rotational analysis of the 121181 and 171181 upper states is made which includes the nearby perturbing states 185, 132181, and 131183. Taking the results of this 5-state fit, together with earlier results on lower lying vibrations, we now have experimental characterization for all 15 excited vibrational states of acrolein lying below 820 cm-1.

  9. Study of Ga incorporation in glassy arsenic selenides by high-resolution XPS and EXAFS.

    PubMed

    Golovchak, R; Shpotyuk, Ya; Nazabal, V; Boussard-Pledel, C; Bureau, B; Cebulski, J; Jain, H

    2015-05-14

    Effect of Ga addition on the structure of vitreous As2Se3 is studied using high-resolution X-ray photoelectron spectroscopy and extended X-ray absorption fine structure techniques. The "8-N" rule is shown to be violated for Ga atoms and, possibly, for certain number of As atoms. On the contrary, Se keeps its 2-fold coordination according to "8-N" rule in the amorphous phase throughout all the compositions. Crystalline inclusions appear in the amorphous structure of the investigated glasses at Ga concentrations greater than 3 at. %. These inclusions are presumably associated with Ga2Se3 crystallites and transition phases/defects formed at the boundaries of these crystallites and host amorphous matrix. The existence of Ga-As and Se-Se bonds in the samples with higher Ga content is supported by present studies.

  10. Study of Ga incorporation in glassy arsenic selenides by high-resolution XPS and EXAFS

    SciTech Connect

    Golovchak, R.; Shpotyuk, Ya.; Nazabal, V.; Boussard-Pledel, C.; Bureau, B.; Cebulski, J.; Jain, H.

    2015-05-14

    Effect of Ga addition on the structure of vitreous As{sub 2}Se{sub 3} is studied using high-resolution X-ray photoelectron spectroscopy and extended X-ray absorption fine structure techniques. The “8-N” rule is shown to be violated for Ga atoms and, possibly, for certain number of As atoms. On the contrary, Se keeps its 2-fold coordination according to “8-N” rule in the amorphous phase throughout all the compositions. Crystalline inclusions appear in the amorphous structure of the investigated glasses at Ga concentrations greater than 3 at. %. These inclusions are presumably associated with Ga{sub 2}Se{sub 3} crystallites and transition phases/defects formed at the boundaries of these crystallites and host amorphous matrix. The existence of Ga–As and Se–Se bonds in the samples with higher Ga content is supported by present studies.

  11. Study of Ga incorporation in glassy arsenic selenides by high-resolution XPS and EXAFS

    NASA Astrophysics Data System (ADS)

    Golovchak, R.; Shpotyuk, Ya.; Nazabal, V.; Boussard-Pledel, C.; Bureau, B.; Cebulski, J.; Jain, H.

    2015-05-01

    Effect of Ga addition on the structure of vitreous As2Se3 is studied using high-resolution X-ray photoelectron spectroscopy and extended X-ray absorption fine structure techniques. The "8-N" rule is shown to be violated for Ga atoms and, possibly, for certain number of As atoms. On the contrary, Se keeps its 2-fold coordination according to "8-N" rule in the amorphous phase throughout all the compositions. Crystalline inclusions appear in the amorphous structure of the investigated glasses at Ga concentrations greater than 3 at. %. These inclusions are presumably associated with Ga2Se3 crystallites and transition phases/defects formed at the boundaries of these crystallites and host amorphous matrix. The existence of Ga-As and Se-Se bonds in the samples with higher Ga content is supported by present studies.

  12. A high-resolution infrared spectral survey of 103P/Hartley 2 on the night of the EPOXI closest approach

    NASA Astrophysics Data System (ADS)

    Dello Russo, Neil; Vervack, Ronald J.; Weaver, Harold A.; Lisse, Carey M.; Kawakita, Hideyo; Kobayashi, Hitomi; Cochran, Anita L.; Harris, Walter M.; Bockelée-Morvan, Dominique; Biver, Nicolas; Crovisier, Jacques; McKay, Adam J.

    2013-02-01

    We obtained high-resolution (λ/Δλ ˜ 28,000) infrared spectra of Comet 103P/Hartley 2 on UT 2010 November 4.6 using the NIRSPEC spectrometer at the W.M. Keck Observatory. Here we present spectra of Hartley 2 between 2.832 and 3.639 μm (3531-2748 cm-1), representing the most complete high-resolution infrared survey of a Jupiter-family comet to date in this wavelength region. We have tabulated rest frequencies, line fluxes, line signal-to-noise ratios and line widths for all detected emissions. Fluorescence models, published line lists and laboratory spectra were used to obtain molecular assignments for detected emissions. Multiple lines of the following species were detected in Hartley 2: H2O, OH, CH3OH, C2H6, HCN, C2H2, H2CO, NH3 and NH2. All identified species seen in this survey have been previously detected in comets. There were 364 distinct emission features present in these spectra, of which 36 were unidentified. We compare the spectrum of Hartley 2 to chemically different Jupiter-family Comets 73P/Schwassmann-Wachmann 3-B and 17P/Holmes in order to obtain additional information on the characteristics of unknown lines through the comparison of relative line fluxes for corresponding emissions in these comets. For the strongest unidentified emissions, additional information was also obtained through a comparison of their spatial distributions in the coma to that of known emission features in Hartley 2. This spectral survey of Hartley 2 provides detailed information about its overall volatile chemistry, provides a comparison to past and future high-resolution infrared datasets, and further characterizes the most promising spectral regions for future molecular searches in comets.

  13. HIGH-RESOLUTION INFRARED IMAGING AND SPECTROSCOPY OF THE Z CANIS MAJORIS SYSTEM DURING QUIESCENCE AND OUTBURST

    SciTech Connect

    Hinkley, Sasha; Hillenbrand, Lynne; Crepp, Justin R.; Oppenheimer, Ben R.; Zimmerman, Neil; Brenner, Douglas; Rice, Emily L.; Pueyo, Laurent; Vasisht, Gautam; Roberts, Jennifer E.; Roberts, Lewis C. Jr.; Burruss, Rick; Wallace, J. Kent; Cady, Eric; Zhai, Chengxing; Kraus, Adam L.; Ireland, Michael J.; Beichman, Charles; Dekany, Richard; Parry, Ian R.; and others

    2013-01-20

    We present adaptive optics photometry and spectra in the JHKL bands along with high spectral resolution K-band spectroscopy for each component of the Z Canis Majoris system. Our high angular resolution photometry of this very young ({approx}<1 Myr) binary, comprised of an FU Ori object and a Herbig Ae/Be star, was gathered shortly after the 2008 outburst while our high-resolution spectroscopy was gathered during a quiescent phase. Our photometry conclusively determines that the outburst was due solely to the embedded Herbig Ae/Be member, supporting results from earlier works, and that the optically visible FU Ori component decreased slightly ({approx}30%) in luminosity during the same period, consistent with previous works on the variability of FU Ori type systems. Further, our high-resolution K-band spectra definitively demonstrate that the 2.294 {mu}m CO absorption feature seen in composite spectra of the system is due solely to the FU Ori component, while a prominent CO emission feature at the same wavelength, long suspected to be associated with the innermost regions of a circumstellar accretion disk, can be assigned to the Herbig Ae/Be member. These findings clarify previous analyses of the origin of the CO emission in this complex system.

  14. High-Resolution Infrared Fourier-Transform Spectroscopy and Rotational Constants of the ν 4Band of BrNO 2

    NASA Astrophysics Data System (ADS)

    Orphal, J.; Frenzel, A.; Grothe, H.; Redlich, B.; Scheffler, D.; Willner, H.; Zetzsch, C.

    1998-09-01

    For the first time, high-resolution infrared gas-phase absorption spectra of the BrNO2molecule were recorded using a Fourier-transform spectrometer. In this paper, the ν4bands of the79BrNO2and81BrNO2isotopomers around 1670 cm-1are investigated. Although the spectra are highly congested, rotational and centrifugal distortion constants for the ground andv4= 1 states of79BrNO2and81BrNO2were determined. The results show that BrNO2is a planar molecule ofC2νsymmetry and confirm predictions from a recentab initiostudy.

  15. A Cryogenic, Insulating Suspension System for the High Resolution Airborne Wideband Camera (HAWC)and Submillemeter And Far Infrared Experiment (SAFIRE) Adiabatic Demagnetization Refrigerators (ADRs)

    NASA Technical Reports Server (NTRS)

    Voellmer, George M.; Jackson, Michael L.; Shirron, Peter J.; Tuttle, James G.

    2002-01-01

    The High Resolution Airborne Wideband Camera (HAWC) and the Submillimeter And Far Infrared Experiment (SAFIRE) will use identical Adiabatic Demagnetization Refrigerators (ADR) to cool their detectors to 200mK and 100mK, respectively. In order to minimize thermal loads on the salt pill, a Kevlar suspension system is used to hold it in place. An innovative, kinematic suspension system is presented. The suspension system is unique in that it consists of two parts that can be assembled and tensioned offline, and later bolted onto the salt pill.

  16. Complex Organization of Human Primary Motor Cortex: A High-Resolution fMRI Study

    PubMed Central

    Meier, Jeffrey D.; Aflalo, Tyson N.; Kastner, Sabine; Graziano, Michael S. A.

    2008-01-01

    A traditional view of the human motor cortex is that it contains an overlapping sequence of body part representations from the tongue in a ventral location to the foot in a dorsal location. In this study, high-resolution functional MRI (1.5 × 1.5 × 2 mm) was used to examine the somatotopic map in the lateral motor cortex of humans, to determine whether it followed the traditional somatotopic order or whether it contained any violations of that somatotopic order. The arm and hand representation had a complex organization in which the arm was relatively emphasized in two areas: one dorsal and the other ventral to a region that emphasized the fingers. This violation of a traditional somatotopic order suggests that the motor cortex is not merely a map of the body but is topographically shaped by other influences, perhaps including correlations in the use of body parts in the motor repertoire. PMID:18684903

  17. Oxidation of diamond films by atomic oxygen: High resolution electron energy loss spectroscopy studies

    NASA Astrophysics Data System (ADS)

    Shpilman, Z.; Gouzman, I.; Grossman, E.; Akhvlediani, R.; Hoffman, A.

    2007-12-01

    Diamond surface oxidation by atomic oxygen, annealing up to ˜700°C, and in situ exposure to thermally activated hydrogen were studied by high resolution electron energy loss spectroscopy (HREELS). After atomic oxygen (AO) exposure, HREELS revealed peaks associated with CHx groups, carbonyl, ether, and peroxide-type species and strong quenching of the diamond optical phonon and its overtones. Upon annealing of the oxidized surfaces, the diamond optical phonon overtones at 300 and 450meV emerge and carbonyl and peroxide species gradually desorb. The diamond surface was not completely regenerated after annealing to ˜700°C and in situ exposure to thermally activated hydrogen, probably due to the irreversible deterioration of the surface by AO.

  18. High resolution digital holographic microscopy for the study of aggregated natural cellulose nanowhisker fibers

    NASA Astrophysics Data System (ADS)

    Wahba, H. H.; Sjödahl, M.; Gren, P.; Olsson, E.

    2015-10-01

    In this paper, digital holographic (DH) microscopy demonstrates its ability to perform a full characterization of nanofibers. The high resolution and magnification of the presented method to study the nanofibers are tested using standard MIL-STD-150A 1951 USAF resolution test target. In this investigation, aggregated natural cellulose nanowhisker fibers are positioned in the front of the microscopic objective using a 3D translation stage in the object arm of DH setup. The recorded off-axis holograms are refocused using the angular spectrum method. The reconstructed complex field is used to calculate optical phase and intensity distributions of the object at different reconstruction depths. A simple algorithm is used to define the focused image with suitable accuracy. The dimensions and orientation of the fibers can be evaluated from the optical field at different depths. Then, the shape and textures along the aggregated natural cellulose nanowhisker fiber can be presented in a 3D space.

  19. Characterization Studies of Radioactive Waste Drums Using High Resolution Gamma Spectrometric Systems

    SciTech Connect

    Toma, M.; Cristache, C.; Done, L.; Dragolici, F.; Sima, O.

    2010-01-21

    The problem of radioactive waste has become a critical issue in the country and worldwide. The radioactive waste containers, containing different radioactive materials, have to be characterized before their final disposal. Destructive methods, although being the most precise, are also the most expensive and not the easiest ones from the radioprotection point of view. In this situation, high resolution gamma spectrometry proved to be a reliable method for the non destructive assay method. However, the non-homogenous composition of the radioactive waste inside the drum makes the quantitative characterization of the radioactive waste drum a difficult task. Experimental studies and computed results, combined with Monte Carlo simulations using GESPECOR, are presented in this paper as a possibility to achieve this task.

  20. Alkyl-terminated Si(111) surfaces: A high-resolution, core level photoelectron spectroscopy study

    SciTech Connect

    Terry, J.; Linford, M.R.; Wigren, C.; Cao, R.; Pianetta, P.; Chidsey, C.E.

    1999-01-01

    The bonding of alkyl monolayers to Si(111) surfaces has been studied with high-resolution core level photoelectron spectroscopy (PES). Two very different wet-chemical methods have been used to prepare the alkyl monolayers: (i) Olefin insertion into the H{endash}Si bond of the H{endash}Si(111) surface, and (ii) replacement of Cl on the Cl{endash}Si(111) surface by an alkyl group from an alkyllithium reagent. In both cases, PES has revealed a C 1s component shifted to lower binding energy and a Si 2p component shifted to higher binding energy. Both components are attributed to the presence of a C{endash}Si bond at the interface. Along with photoelectron diffraction data [Appl. Phys. Lett. {bold 71}, 1056, (1997)], these data are used to show that these two synthetic methods can be used to functionalize the Si(111) surface. {copyright} {ital 1999 American Institute of Physics.}

  1. A High-Resolution Study of Quasiperiodic Radio Emissions Observed by the Galileo Plasma Wave Instrument

    NASA Technical Reports Server (NTRS)

    Menietti, J. D.; Christopher, I.; Granroth, L. J.

    2001-01-01

    We have conducted a study of quasiperiodic emission observed by the plasma wave instrument on board the Galileo spacecraft. These emissions appear as broadband bursts with dominant periods ranging from 10 min to over 40 min. For these emissions we have explicitly analyzed the high-resolution (waveform) data to determine the presence of impulsive, solitary signatures. Our investigations have indicated that the broadband bursts, as well as the background more narrowband continuum emission, are composed of a highly turbulent spectrum. Within the broadband burst, however, there are higher-frequency components present, but no impulsive electrostatic signatures. Also significantly, the broadband bursts show no low-frequency dispersion. We conclude that the bursts are consistent with a distant, electromagnetic source, probably in the near-Jupiter vicinity.

  2. Study of Stent Deployment Mechanics Using a High-Resolution X-ray Imaging Detector

    PubMed Central

    Wang, Weiyuan; Ionita, Ciprian N; Bednarek, Daniel R; Rudin, Stephen

    2011-01-01

    To treat or prevent some of the 795,000 annual strokes in the U.S., self-expanding endo-vascular stents deployed under fluoroscopic image guidance are often used. Neuro-interventionalists need to know the deployment behavior of each stent in order to place them in the correct position. Using the Micro-Angiographic Fluoroscope (MAF) which has about 3 times higher resolution than commercially available flat panel detectors (FPD) we studied the deployment mechanics of two of the most important commercially available nitinol stents: the Pipeline embolization device (EV3), and the Enterprise stent (Codman). The Pipeline stent's length extends to about 3 times that of its deployed length when it is contained inside a catheter. From the high-resolution images with the MAF we found that upon the sudden release of the distal end of the Pipeline from a helical wire cap, the stent expands radially but retracts to about 30% (larger than for patient deployments) of its length. When released from the catheter proximally, it retracts additionally about 50% contributing to large uncertainty in the final deployed location. In contrast, the MAF images clearly show that the Enterprise stent self expands with minimal length retraction during deployment from its catheter and can be retrieved and repositioned until the proximal markers are released from clasping structures on its guide-wire thus enabling more accurate placement at the center of an aneurysm or stenosis. The high-resolution imaging demonstrated in this study should help neurointerventionalists understand and control endovascular stent deployment mechanisms and hence perform more precise treatments. PMID:21804747

  3. High-resolution air quality monitoring from space: a fast retrieval scheme for CO from hyperspectral infrared measurements

    NASA Astrophysics Data System (ADS)

    Smith, N.; Huang, H.-L.; Weisz, E.; Annegarn, H. J.; Pierce, R. B.

    2011-06-01

    The first results of the Fast Linear Inversion Trace gas System (FLITS) retrieval scheme are presented here for CO from IASI (Infrared Atmospheric Sounding Interferometer) measurements using RAQMS (Real time Air Quality Modelling System) as atmospheric background. FLITS is a simple linear inversion scheme with a stable performance that retrieves total column CO concentrations (molec cm-2) at single field-of-view (FOV) irrespective of cloud cover. A case study is presented here for a biomass burning plume over the Pacific on 29 March 2010. For each FOV a single tropospheric CO density, vertically integrated over 200-800 hPa, is retrieved with 12 channels in the spectral range 2050-2225 cm-1. Despite variations in cloud cover and temperature, the degrees of freedom for signal (DFS) of the solution ranges between 0.8 and 0.95. In addition, the retrieval error is at least half the background error of 10 %, with dominant contribution from uncertainty in the measurement and temperature. With its stability and processing speed, FLITS meet two of the key requirements for operational processing. We conclude that the linear combination of space-borne measurements with a chemical transport model in the FLITS retrieval scheme holds potential for real-time air quality monitoring and evaluation of pollutant transport at high spatial resolution.

  4. Analysis of High Resolution Infrared Spectra of 1,1-DICHLOROETHYLENE in the 500 - 1000 wn Range

    NASA Astrophysics Data System (ADS)

    Peebles, Rebecca A.; Peebles, Sean A.; Obenchain, Daniel A.

    2012-06-01

    The far infrared beamline of the Canadian Light Source synchrotron facility has been used to record three rotationally resolved vibrational bands of 1,1-dichloroethylene in the 500-1000 cm-1 range, at 0.00096 cm-1 resolution. These correspond, for the H_2C=C35Cl_2 isotopologue, to an a-type band (CCl_2 antisymmetric stretch) at 796.0 cm-1, a b-type band (CCl_2 symmetric stretch) at 603.0 cm-1, and a c-type band (CH_2 wag) at 868.6 cm-1. Anharmonic frequency calculations at the MP2/6-311++G(2d,2p) level, combined with rotational and centrifugal distortion constants from a millimeter wave study of the ground state, were an invaluable aid in facilitating the spectroscopic assignment for this asymmetric top ({κ} = -0.58). Analysis of the 796 cm-1 band is nearly complete, giving well determined excited state rotational and centrifugal distortion constants. Results of this analysis and progress with analysis of the other two bands will be presented. Z. Kisiel, L. Pszczolkowski, Z. Naturforsch, 50a, (1995), 347-351.

  5. A High Resolution Geophysical Study of the Offshore Western Gulf of Corinth Rift

    NASA Astrophysics Data System (ADS)

    McNeill, L.; Cotterill, C.; Stefatos, A.; Henstock, T.; Bull, J.; Collier, R.; Papatheodorou, G.; Georgiopoulou, A.; Ferentinos, G.

    2003-12-01

    The western Gulf of Corinth has generated recent debate in terms of distribution of extensional strain, interactions between active faults and fault geometry. Onshore data suggest that faults do not accommodate extensional strain of the magnitude suggested by geodetic measurements. Recently acquired high resolution geophysical data in the western Gulf of Corinth, including Reson Seabat 8160 50 kHz multibeam bathymetry (with sidescan collected simultaneously) and sparker and boomer seismic profiles, will allow a detailed study of faulting relationships, fault propagation history and associated sedimentological processes. Multibeam data indicate the complex axial and tributary channel pattern of the gulf as well as revealing the surface expression of active faults on both margins and within the basin centre. Several fault tips are evident, including the Aigion fault which has been surveyed in great detail with boomer lines spaced between 25-100 m. The fault tip is complex with multiple synthetic and antithetic splays. The post-lowstand transgressive surface is clearly imaged and therefore fault growth rates can be established. Gas-related features are common, including pockmarks and mud volcanoes. To the east, displacement on the eastern tip of the Eliki fault decreases rapidly offshore and a splay of the Derveni fault is observed. A major S-dipping antithetic fault opposite the Eastern Eliki fault has clear bathymetric expression and is locally associated with a prominent basement ridge. This fault may make a significant contribution to extensional strain in this part of the rift. In the centre of the basin, sediments are deformed by multiple minor faults with seafloor displacement. Ultimately, high resolution offshore interpretations can be integrated with regional datasets and existing data (e.g., geomorphic, paleoseismological and sedimentological) onshore and used to better assess rift deformation models, rift evolution and local seismic hazards.

  6. A high resolution study of a hurricane storm surge and inundation in Veracruz, Mexico

    NASA Astrophysics Data System (ADS)

    Díaz García, Ovel; Zavala Hidalgo, Jorge; Douillet, Pascal

    2014-05-01

    Veracruz is the most populated city along the Mexican shoreline of the Gulf of Mexico and also is the country's largest commercial port. In recent years the city has been affected by hurricanes of medium intensity that have provoked human casualties, property damaged and economic loss. Two of the most recent events were hurricane Karl (2010), which caused a storm surge and severe flooding, and hurricane Ernesto (2012). The purpose of this work is to study, based on high-resolution numerical simulations, scenarios of storm surge flooding using state-of-the-art open source numerical models: the Weather, Research and Forecasting (WRF), and the coupled models ADvanced CIRCulation (ADCIRC) and Simulating WAves Nearshore (SWAN) for weather and storm surge hindcast, respectively. We also use topography high resolution data from LIDAR and bathymetry from GEBCO 30", the Mexican Navy and nautical charts from Electrical Federal Commission. We present the validation of the models evaluating several statistical parameters against measurements from Acoustic Data Current Profilers, pressure sensors, tide gauge and meteorological stations for these events. In the case of hurricane Karl, it made landfall 15 km north of Veracruz City, reducing the maximum surge along the city shoreline. The hurricane Ernesto made landfall 200 km southeast of the city, too far to have a significant impact. We did some numerical experiments slightly changing the trajectory, reported by the best track data, for these two hurricanes with the purpose of evaluating storm surge scenarios. The results shows that the worst storm surge cases were when the tracks of this hurricanes made landfall south of the city in the range of 30 to 60 km.

  7. Using High Resolution Vegetation Images to study Ecogeomorphologic Thresholds in Semiarid Australia

    NASA Astrophysics Data System (ADS)

    Azadi, Samira; Saco, Patricia; Moreno-de las Heras, Mariano; Willgoose, Garry

    2016-04-01

    Arid and Semiarid sites are very sensitive to climatic or anthropogenic pressures. Several previous studies argue that ecosystem function in these areas tends to display critical degradation thresholds which make rehabilitation efforts considerably difficult. This threshold behaviour is linked to coevolving eco-geomorphic processes triggered by climatic or anthropogenic disturbances. A common trigger is the removal of vegetation (by grazing or harvesting activities) which increases landscape hydrological connectivity and can induce a substantial loss of water and soil affecting ecosystem function (e.g. decreasing the rainfall-use efficiency of the landscape). Here we present results exploring the impact of degradation processes induced by grazing pressure on rainfall-use efficiency along a precipitation gradient (250 mm to 490 mm annual average rainfall). The sites were carefully selected in the mulga lands bioregion (New South Wales, Queensland) and in sites of the Northern Territory in Australia, and display similar vegetation characteristics and good quality rainfall information. Vegetation patterns and percentage cover are derived from high resolution remote sensing images (IKONOS, QuickBird and complement this information with high resolution images obtained from Google Earth). We compute rainfall use efficiency and precipitation marginal response using local precipitation data and MODIS vegetation indices. The analysis of the NDVI MODIS data shows the presence of a clear critical degradation threshold, associated with loss of vegetation cover in the drier sites. Below this threshold we found what we call "functional landscapes" with high vegetation cover that display high rainfall use efficiency. Above this threshold, we found "dysfunctional landscapes" with much lower rainfall use efficiency. We compare the different behaviours for several sites along the precipitation gradient, and find that the wetter sites do not tend to display this threshold behaviour

  8. High-resolution Fourier-transform infrared spectroscopy of the Coriolis coupled ground state and ν7 mode of ketenimine.

    PubMed

    Bane, Michael K; Robertson, Evan G; Thompson, Christopher D; Medcraft, Chris; Appadoo, Dominique R T; McNaughton, Don

    2011-06-21

    High resolution FTIR spectra of the short lived species ketenimine have been recorded in the regions 390-1300 cm(-1) and 20-110 cm(-1) using synchrotron radiation. Two thousand six hundred sixty transitions of the ν(7) band centered at 693 cm(-1) and 126 far-IR rotational transitions have been assigned. Rotational and centrifugal distortion parameters for the ν(7) mode were determined and local Fermi and b-axis Coriolis interactions with 2ν(12) are treated. A further refinement of the ground state, ν(12) and ν(8) parameters was also achieved, including the treatment of previously unrecognized ac-axis and ab-axis second order perturbations to the ground state.

  9. Improved method for calibrating the visible and near-infrared channels of the National Oceanic and Atmospheric Administration Advanced Very High Resolution Radiometer.

    PubMed

    Che, N; Price, J C

    1993-12-20

    Two procedures are used to establish calibration of the visible and near-infrared channels of the National Oceanic and Atmospheric Administration-11 (NOAA-II) Advanced Very High Resolution Radiometer (AVHRR). The first procedure for visible spectra, uses satellite data, ground measurements of atmospheric conditions during satellite overpass, and historical surface reflectance values at White Sands Missile Range (WSMR) in New Mexico. The second procedure, for the near-infrared, uses knowledge of the reflective properties at the WSMR and of a low-reflectance area, as determined from the first method, that yields satellite-gain values without a requirement for ground measurements of atmospheric conditions. The accuracy of gain values is estimated at ±7% for the two methods. The WSMR combines accessibility, a wide range of surface reflectances, and generally good observing conditions, making it a desirable location for satellite calibration.

  10. HIGH-RESOLUTION FOURIER TRANSFORM INFRARED SPECTRUM OF THE ν2 + ν12 BAND OF ETHYLENE (12C2H4)

    NASA Astrophysics Data System (ADS)

    Lebron, G. B.; Tan, T. L.

    2013-09-01

    The high-resolution Fourier transform infrared absorption spectrum of the ν2 + ν12 combination band of normal ethylene (12C2H4) in the 3050-3105 cm-1 region was recorded at a resolution of 0.0063 cm-1 and at an ambient temperature of 296 K. Upper state rovibrational analysis was carried out using a standard Watson's Hamiltonian in asymmetric reduction in Ir representation. The band center, rotational constants and centrifugal distortion constants up to quartic terms of the upper ν2 + ν12 = 1 state were determined from the final fit that included 102 infrared transitions. The root-mean-square deviation of the fit was 0.000729 cm-1.

  11. Effects of atmosphere and view and illumination geometry on visible and near infrared radiance data from the advanced very high resolution radiometer (AVHR)

    NASA Technical Reports Server (NTRS)

    Holben, B. N.; Fraser, R. S.

    1984-01-01

    The use of Dave's models to evaluate satellite off-nadir remote sensing of green vegetation cover types by simulating the visible and near-infrared advanced very high resolution radiometer (AVHRR) NOAA-6 and NOAA-7 radiances for three green-leaf biomass levels and bare soil. Ground measurements of surface reflectances were used. The simulations were done along a scan line at 30 deg latitude during the summer solstice, equinox, and winter solstice. The simulation models are described and the effect of atmosphere over moderately vegetated surfaces is discussed. The results show that sensor response to atmospheric path length can be substantial for the AVHRR visible and near-infrared channels and normalized difference values, but they can be minimized by high sun and clear atmospheric viewing. The results indicate that AVHRR data would be most useful for monitoring low green leaf biomas canopies.

  12. HIGH-RESOLUTION MID-INFRARED IMAGING OF THE CIRCUMSTELLAR DISKS OF HERBIG Ae/Be STARS

    SciTech Connect

    Marinas, N.; Telesco, C. M.; Packham, C.; Fisher, R. S.

    2011-08-20

    We have imaged the circumstellar environments of 17 Herbig Ae/Be stars at 12 and 18 {mu}m using MICHELLE on Gemini North and T-ReCS on Gemini South. Our sample contained eight Group I sources, those having large rising near- to far-infrared (IR) fluxes, and nine Group II sources, those having more modest mid-IR fluxes relative to their near-IR flux (in the classification of Meeus et al.). We have resolved extended emission from all Group I sources in our target list. The majority of these sources have radially symmetric mid-IR emission extending from a radius of 10 AU to hundreds of AU. Only one of the nine Group II sources is resolved at the FWHM level, with another two Group II sources resolved at fainter levels. Models by Dullemond et al. explain the observed spectral energy distribution of Group II sources using self-shadowed cold disks. If this is the case for all the Group II sources, we do not expect to detect extended emission with this study, since the IR emission measured should arise from a region only a few AU in size, which is smaller than our resolution. The fact that we do resolve some of the Group II sources implies that their disks are not completely flat, and might represent an intermediate stage. We also find that none of the more massive (>3 M{sub sun}) Herbig Ae/Be stars in our sample belongs to Group I, which may point to a relationship between stellar mass and circumstellar dust evolution. Disks around more massive stars might evolve faster so that stars are surrounded by a more evolved flat disk by the time they become optically visible, or they might follow a different evolutionary path altogether.

  13. A high resolution study of the Martian water cycle with a global climate model

    NASA Astrophysics Data System (ADS)

    Pottier, A.; Montmessin, F.; Forget, F.; Navarro, T.; Millour, E.; Madeleine, J.-B.; Spiga, A.

    2015-10-01

    The martian water cycle's main source is the northern polar cap. Running high resolution models, up to 360° per 180°, help better resolve this ice cap, and better mimic the gradual retreat of the seasonal cap. Atmospheric circulation is also better resolved. Water vapor advection and the subsequent formation of clouds quite differ when we compare these brand new high resolution simulations and the usual lower resolution ones at 64 per 48 grid points.

  14. A high-resolution infrared spectrum of IRC +10216. [carbon star immersed in expanding gas/dust shell

    NASA Technical Reports Server (NTRS)

    Barnes, T. G.; Hinkle, K. H.; Lambert, D. L.; Beer, R.

    1977-01-01

    The IR-emitting core and shell of IRC +10216 are investigated using a high-resolution spectrum covering the wavelength interval between 3 and 5 microns. Line identifications made or confirmed include those due to (C-12)(O-16), (C-13)(O-16), (C-12)(O-17), and (C-12)(O-18). A mean heliocentric velocity of about -32 km/s is obtained from the 42 least blended (C-12)O and (C-13)O lines, and the following isotopic abundance ratios are derived by comparing equivalent widths of the observed lines: C-12/C-13, C-12/C-14, O-16/O-17, and O-17/O-18. The structure of the expanding gas shell is examined, an explanation is offered for the lack of P Cygni profiles in the spectrum, and an unsuccessful search for other molecules is briefly discussed. It is concluded that a low C-12/C-13 ratio is not necessarily a signature of a carbon star.

  15. Imaging magnetographs for high-resolution solar observations in the visible and near-infrared wavelength region

    NASA Astrophysics Data System (ADS)

    Denker, C.; Didkovsky, L.; Ma, J.; Shumko, S.; Varsik, J.; Wang, J.; Wang, H.; Goode, P. R.

    The Coudé feed of the vacuum telescope (aperture D=65 cm) at the Big Bear Solar Observatory (BBSO) is currently completely remodelled to accommodate a correlation tracker and a high-order Adaptive Optics (AO) system. The AO system serves two imaging magnetograph systems located at a new optical laboratory on the observatory's 2nd floor. The InfraRed Imaging Magnetograph (IRIM) is an innovative magnetograph system for near-infrared (NIR) observations in the wavelength region from 1.0 mu m to 1.6 mu m. The Visible-light Imaging Magnetograph (VIM) is basically a twin of IRIM for observations in the wavelength range from 550 nm to 700 nm. Both instruments were designed for high spatial and high temporal observations of the solar photosphere and chromosphere. Real-time data processing is an integral part of the instruments and will enhance BBSO's capabilities in monitoring solar activity and predicting and forecasting space weather.

  16. High-resolution pulsed-field ionization photoelectron study of O{sub 2}

    SciTech Connect

    Hsu, C.W.; Evans, M.; Stimson, S.

    1997-04-01

    There have been numerous photoionization studies of O{sub 2} over the past 10 years. Using the pulsed field ionization (PFI) photoelectron spectroscopy (PES) technique, the electronic ground state of O{sub 2}{sup +} (X{sup 2}{Pi}{sub g}{sup {minus}}) has been well studied on the rotationally resolved level by several groups. However, due to the difficulty of producing photon energies above 18 eV using the tunable lasers, the electronic excited states of O{sub 2}{sup +} have been mostly studied on the vibrationally resolved level using the threshold photoelectron spectroscopy (TPES) and the synchrotron radiation. Recently, the authors developed a new technique for performing the PFI-PE experiments using multi-bunch synchrotron radiation at the Chemical Dynamics Beamline of the Advanced Light Source (ALS). Using the high resolution VUV light from the ALS, they have obtained the PFI-PE spectra of O{sub 2} between 12 and 24 eV. In this abstract, the authors report for the first time the rotationally resolved spectra of O{sub 2}{sup +} (b{sup 4}{Sigma}{sub g}{sup {minus}}, v{sup +}=0).

  17. A feasibility study of PETiPIX: an ultra high resolution small animal PET scanner

    NASA Astrophysics Data System (ADS)

    Li, K.; Safavi-Naeini, M.; Franklin, D. R.; Petasecca, M.; Guatelli, S.; Rosenfeld, A. B.; Hutton, B. F.; Lerch, M. L. F.

    2013-12-01

    PETiPIX is an ultra high spatial resolution positron emission tomography (PET) scanner designed for imaging mice brains. Four Timepix pixellated silicon detector modules are placed in an edge-on configuration to form a scanner with a field of view (FoV) 15 mm in diameter. Each detector module consists of 256 × 256 pixels with dimensions of 55 × 55 × 300 μm3. Monte Carlo simulations using GEANT4 Application for Tomographic Emission (GATE) were performed to evaluate the feasibility of the PETiPIX design, including estimation of system sensitivity, angular dependence, spatial resolution (point source, hot and cold phantom studies) and evaluation of potential detector shield designs. Initial experimental work also established that scattered photons and recoil electrons could be detected using a single edge-on Timepix detector with a positron source. Simulation results estimate a spatial resolution of 0.26 mm full width at half maximum (FWHM) at the centre of FoV and 0.29 mm FWHM overall spatial resolution with sensitivity of 0.01%, and indicate that a 1.5 mm thick tungsten shield parallel to the detectors will absorb the majority of non-coplanar annihilation photons, significantly reducing the rates of randoms. Results from the simulated phantom studies demonstrate that PETiPIX is a promising design for studies demanding high resolution images of mice brains.

  18. Cassini UVIS Solar Zenith Angle Studies of Titan Dayglow Based on N2 High Resolution Spectroscopy

    NASA Astrophysics Data System (ADS)

    Ajello, Joseph; West, Robert; Holsclaw, Greg; Royer, Emilie; Heays, Alan; Bradley, Todd; Stevens, Michael

    2014-11-01

    The Cassini Ultraviolet Imaging Spectrograph (UVIS) observed photon emissions of Titan’s day and night limb-airglow on multiple occasions, including during an eclipse observation. On one occasion the UVIS made a Solar Zenith Angle (SZA) study of the Titan limb dayglow (2011 DOY 171) from about 70 to 95 degrees SZA. The UV intensity variation observations of the N2 photoelectron excited spectral features from the EUV (563-118.2 nm) and FUV (111.5-191.2nm) sub-systems followed a Chapman function. For other observations at night on the limb, the emission features are much weaker in intensity. Beyond 120 deg SZA, when the upper atmosphere of Titan below 1200 km is in total XUV darkness, there is an indication of weak and sporadic night side UV airglow emission excited by magnetosphere plasma collisions with ambient thermosphere gas, with similar N2 excited features as above in the daylight or twilight glow over an extended altitude range. We have analyzed the UVIS airglow spectra with models based on high resolution laboratory electron impact induced fluorescence spectra. We have measured high-resolution (FWHM = 0.2 Å) extreme-ultraviolet (EUV, 800-1350 Å) laboratory emission spectra of molecular nitrogen excited by electron impact at 20 and 100 eV. Molecular emission was observed to vibrationally-excited ground state levels as high as v''=17, from the a 1Πg , b 1Πu, and b‧ 1Σu+ excited valence states and the Rydberg series c‧n+1 1Σu+, cn 1Πu and o 1Πu for n between 3 and 9. A total of 491 emission features were observed from N2 electronic-vibrational transitions and atomic N I and N II multiplets. Their emission cross sections were measured.The blended molecular emission bands were disentangled with the aid of a model which solves the coupled-Schroedinger equation

  19. High Resolution Tsunami Modeling and Assessment of Harbor Resilience; Case Study in Istanbul

    NASA Astrophysics Data System (ADS)

    Cevdet Yalciner, Ahmet; Aytore, Betul; Gokhan Guler, Hasan; Kanoglu, Utku; Duzgun, Sebnem; Zaytsev, Andrey; Arikawa, Taro; Tomita, Takashi; Ozer Sozdinler, Ceren; Necmioglu, Ocal; Meral Ozel, Nurcan

    2014-05-01

    Ports and harbors are the major vulnerable coastal structures under tsunami attack. Resilient harbors against tsunami impacts are essential for proper, efficient and successful rescue operations and reduction of the loss of life and property by tsunami disasters. There are several critical coastal structures as such in the Marmara Sea. Haydarpasa and Yenikapi ports are located in the Marmara Sea coast of Istanbul. These two ports are selected as the sites of numerical experiments to test their resilience under tsunami impact. Cargo, container and ro-ro handlings, and short/long distance passenger transfers are the common services in both ports. Haydarpasa port has two breakwaters with the length of three kilometers in total. Yenikapi port has one kilometer long breakwater. The accurate resilience analysis needs high resolution tsunami modeling and careful assessment of the site. Therefore, building data with accurate coordinates of their foot prints and elevations are obtained. The high resolution bathymetry and topography database with less than 5m grid size is developed for modeling. The metadata of the several types of structures and infrastructure of the ports and environs are processed. Different resistances for the structures/buildings/infrastructures are controlled by assigning different friction coefficients in a friction matrix. Two different tsunami conditions - high expected and moderate expected - are selected for numerical modeling. The hybrid tsunami simulation and visualization codes NAMI DANCE, STOC-CADMAS System are utilized to solve all necessary tsunami parameters and obtain the spatial and temporal distributions of flow depth, current velocity, inundation distance and maximum water level in the study domain. Finally, the computed critical values of tsunami parameters are evaluated and structural performance of the port components are discussed in regard to a better resilience. ACKNOWLEDGEMENTS: Support by EU 603839 ASTARTE Project, UDAP-Ç-12

  20. High-resolution x-ray absorption spectroscopy studies of metal compounds in neurodegenerative brain tissue

    SciTech Connect

    Collingwood, J.F.; Mikhaylova, A.; Davidson, M.R.; Batich, C.; Streit, W.J.; Eskin, T.; Terry, J.; Barrea, R.; Underhill, R.S.; Dobson, J.

    2008-06-16

    Fluorescence mapping and microfocus X-ray absorption spectroscopy are used to detect, locate and identify iron biominerals and other inorganic metal accumulations in neurodegenerative brain tissue at sub-cellular resolution (< 5 microns). Recent progress in developing the technique is reviewed. Synchrotron X-rays are used to map tissue sections for metals of interest, and XANES and XAFS are used to characterize anomalous concentrations of the metals in-situ so that they can be correlated with tissue structures and disease pathology. Iron anomalies associated with biogenic magnetite, ferritin and haemoglobin are located and identified in an avian tissue model with a pixel resolution {approx} 5 microns. Subsequent studies include brain tissue sections from transgenic Huntington's mice, and the first high-resolution mapping and identification of iron biominerals in human Alzheimer's and control autopsy brain tissue. Technical developments include use of microfocus diffraction to obtain structural information about biominerals in-situ, and depositing sample location grids by lithography for the location of anomalies by conventional microscopy. The combined techniques provide a breakthrough in the study of both intra- and extra-cellular iron compounds and related metals in tissue. The information to be gained from this approach has implications for future diagnosis and treatment of neurodegeneration, and for our understanding of the mechanisms involved.

  1. High-resolution x-ray absorption spectroscopy studies of metal compounds in neurodegenerative brain tissue

    NASA Astrophysics Data System (ADS)

    Collingwood, J. F.; Mikhaylova, A.; Davidson, M. R.; Batich, C.; Streit, W. J.; Eskin, T.; Terry, J.; Barrea, R.; Underhill, R. S.; Dobson, J.

    2005-01-01

    Fluorescence mapping and microfocus X-ray absorption spectroscopy are used to detect, locate and identify iron biominerals and other inorganic metal accumulations in neurodegenerative brain tissue at sub-cellular resolution (<5 microns). Recent progress in developing the technique is reviewed. Synchrotron X-rays are used to map tissue sections for metals of interest, and XANES and XAFS are used to characterise anomalous concentrations of the metals in-situ so that they can be correlated with tissue structures and disease pathology. Iron anomalies associated with biogenic magnetite, ferritin and haemoglobin are located and identified in an avian tissue model with a pixel resolution ~5 microns. Subsequent studies include brain tissue sections from transgenic Huntington's mice, and the first high-resolution mapping and identification of iron biominerals in human Alzheimer's and control autopsy brain tissue. Technical developments include use of microfocus diffraction to obtain structural information about biominerals in-situ, and depositing sample location grids by lithography for the location of anomalies by conventional microscopy. The combined techniques provide a breakthrough in the study of both intra- and extra-cellular iron compounds and related metals in tissue. The information to be gained from this approach has implications for future diagnosis and treatment of neurodegeneration, and for our understanding of the mechanisms involved.

  2. Internal pressure gradient errors in σ-coordinate ocean models in high resolution fjord studies

    NASA Astrophysics Data System (ADS)

    Berntsen, Jarle; Thiem, Øyvind; Avlesen, Helge

    2015-08-01

    Terrain following ocean models are today applied in coastal areas and fjords where the topography may be very steep. Recent advances in high performance computing facilitate model studies with very high spatial resolution. In general, numerical discretization errors tend to zero with the grid size. However, in fjords and near the coast the slopes may be very steep, and the internal pressure gradient errors associated with σ-models may be significant even in high resolution studies. The internal pressure gradient errors are due to errors when estimating the density gradients in σ-models, and these errors are investigated for two idealized test cases and for the Hardanger fjord in Norway. The methods considered are the standard second order method and a recently proposed method that is balanced such that the density gradients are zero for the case ρ = ρ(z) where ρ is the density and z is the vertical coordinate. The results show that by using the balanced method, the errors may be reduced considerably also for slope parameters larger than the maximum suggested value of 0.2. For the Hardanger fjord case initialized with ρ = ρ(z) , the errors in the results produced with the balanced method are orders of magnitude smaller than the corresponding errors in the results produced with the second order method.

  3. Regional climate change predictions from the Goddard Institute for Space Studies high resolution GCM

    NASA Technical Reports Server (NTRS)

    Crane, Robert G.; Hewitson, Bruce

    1990-01-01

    Model simulations of global climate change are seen as an essential component of any program aimed at understanding human impact on the global environment. A major weakness of current general circulation models (GCMs), however, is their inability to predict reliably the regional consequences of a global scale change, and it is these regional scale predictions that are necessary for studies of human/environmental response. This research is directed toward the development of a methodology for the validation of the synoptic scale climatology of GCMs. This is developed with regard to the Goddard Institute for Space Studies (GISS) GCM Model 2, with the specific objective of using the synoptic circulation form a doubles CO2 simulation to estimate regional climate change over North America, south of Hudson Bay. This progress report is specifically concerned with validating the synoptic climatology of the GISS GCM, and developing the transfer function to derive grid-point temperatures from the synoptic circulation. Principal Components Analysis is used to characterize the primary modes of the spatial and temporal variability in the observed and simulated climate, and the model validation is based on correlations between component loadings, and power spectral analysis of the component scores. The results show that the high resolution GISS model does an excellent job of simulating the synoptic circulation over the U.S., and that grid-point temperatures can be predicted with reasonable accuracy from the circulation patterns.

  4. High Resolution STEM-EELS Study of Silver Nanoparticles Exposed to Light and Humic Substances.

    PubMed

    Römer, Isabella; Wang, Zhi Wei; Merrifield, Ruth C; Palmer, Richard E; Lead, Jamie

    2016-03-01

    Nanoparticles (NPs) are defined as particles with at least one dimension between 1 and 100 nm or with properties that differ from their bulk material, which possess unique properties. The extensive use of NPs means that discharge to the environment is likely increasing, but fate, behavior, and effects under environmentally relevant conditions are insufficiently studied. This paper focuses on the transformations of silver nanoparticles (AgNPs) under simulated but realistic environmental conditions. High resolution aberration-corrected scanning transmission electron microscopy (HAADF STEM) coupled with electron energy loss spectroscopy (EELS) and UV-vis were used within a multimethod approach to study morphology, surface chemistry transformations, and corona formation. Although loss, most likely by dissolution, was observed, there was no direct evidence of oxidation from the STEM-EELS. However, in the presence of fulvic acid (FA), a 1.3 nm oxygen-containing corona was observed around the AgNPs in water; modeled data based on the HAADF signal at near atomic resolution suggest this was an FA corona was formed and was not silver oxide, which was coherent (i.e., fully coated in FA), where observed. The corona further colloidally stabilized the NPs for periods of weeks to months, dependent on the solution conditions. PMID:26792384

  5. High resolution model studies of transport of sedimentary material in the south-western Baltic

    NASA Astrophysics Data System (ADS)

    Seifert, Torsten; Fennel, Wolfgang; Kuhrts, Christiane

    2009-02-01

    The paper presents high resolution model simulations of transport, deposition and resuspension of sedimentary material in the south-western Baltic, based on an upgrade of the sediment transport model described in the work of Kuhrts et al. [Kuhrts, C., Fennel, W., Seifert, T., 2004. Model studies of transport of sedimentary material in the Western Baltic. Journal of Marine Systems 52, 167.]. In the western Baltic, a grid spacing of at least 1 nautical mile is required to resolve the shallow and narrow bathymetry and the associated current patterns. A series of experimental model simulations is carried out with forcing data for the year 1993, which include a sequence of storms in January. Compared to earlier model versions, a more detailed description of potential deposition areas can be provided. The study quantifies the influence of enhanced bottom roughness caused by biological structures, like mussels and worm holes, provides estimates of the regional erosion risks for fine grained sediments, and analyses scenarios of the settling and spreading of material at dumping sites. Although the effects of changed bottom roughness, as derived from more detailed, re-classified sea floor data, are relatively small, the sediment transport and deposition patterns are clearly affected by the variation of the sea bed properties.

  6. Monitoring Disease Trends using Hospital Traffic Data from High Resolution Satellite Imagery: A Feasibility Study

    PubMed Central

    Nsoesie, Elaine O.; Butler, Patrick; Ramakrishnan, Naren; Mekaru, Sumiko R.; Brownstein, John S.

    2015-01-01

    Challenges with alternative data sources for disease surveillance include differentiating the signal from the noise, and obtaining information from data constrained settings. For the latter, events such as increases in hospital traffic could serve as early indicators of social disruption resulting from disease. In this study, we evaluate the feasibility of using hospital parking lot traffic data extracted from high-resolution satellite imagery to augment public health disease surveillance in Chile, Argentina and Mexico. We used archived satellite imagery collected from January 2010 to May 2013 and data on the incidence of respiratory virus illnesses from the Pan American Health Organization as a reference. We developed dynamical Elastic Net multivariable linear regression models to estimate the incidence of respiratory virus illnesses using hospital traffic and assessed how to minimize the effects of noise on the models. We noted that predictions based on models fitted using a sample of observations were better. The results were consistent across countries with selected models having reasonably low normalized root-mean-squared errors and high correlations for both the fits and predictions. The observations from this study suggest that if properly procured and combined with other information, this data source could be useful for monitoring disease trends. PMID:25765943

  7. Monitoring disease trends using hospital traffic data from high resolution satellite imagery: a feasibility study.

    PubMed

    Nsoesie, Elaine O; Butler, Patrick; Ramakrishnan, Naren; Mekaru, Sumiko R; Brownstein, John S

    2015-03-13

    Challenges with alternative data sources for disease surveillance include differentiating the signal from the noise, and obtaining information from data constrained settings. For the latter, events such as increases in hospital traffic could serve as early indicators of social disruption resulting from disease. In this study, we evaluate the feasibility of using hospital parking lot traffic data extracted from high-resolution satellite imagery to augment public health disease surveillance in Chile, Argentina and Mexico. We used archived satellite imagery collected from January 2010 to May 2013 and data on the incidence of respiratory virus illnesses from the Pan American Health Organization as a reference. We developed dynamical Elastic Net multivariable linear regression models to estimate the incidence of respiratory virus illnesses using hospital traffic and assessed how to minimize the effects of noise on the models. We noted that predictions based on models fitted using a sample of observations were better. The results were consistent across countries with selected models having reasonably low normalized root-mean-squared errors and high correlations for both the fits and predictions. The observations from this study suggest that if properly procured and combined with other information, this data source could be useful for monitoring disease trends.

  8. MID-INFRARED PROPERTIES OF OH MEGAMASER HOST GALAXIES. I. SPITZER IRS LOW- AND HIGH-RESOLUTION SPECTROSCOPY

    SciTech Connect

    Willett, Kyle W.; Darling, Jeremy; Spoon, Henrik W. W.; Charmandaris, Vassilis; Armus, Lee

    2011-03-15

    We present mid-infrared spectra and photometry from the Infrared Spectrograph on the Spitzer Space Telescope for 51 OH megamasers (OHMs), along with 15 galaxies confirmed to have no megamaser emission above L {sub OH} = 10{sup 2.3} L {sub sun}. The majority of galaxies display moderate-to-deep 9.7 {mu}m amorphous silicate absorption, with OHM galaxies showing stronger average absorption and steeper 20-30 {mu}m continuum emission than non-masing galaxies. Emission from multiple polycyclic aromatic hydrocarbons (PAHs), especially at 6.2, 7.7, and 11.3 {mu}m, is detected in almost all systems. Fine-structure atomic emission (including [Ne II], [Ne III], [S III], and [S IV]) and multiple H{sub 2} rotational transitions are observed in more than 90% of the sample. A subset of galaxies show emission from rarer atomic lines, such as [Ne V], [O IV], and [Fe II]. Fifty percent of the OHMs show absorption from water ice and hydrogenated amorphous carbon grains, while absorption features from CO{sub 2}, HCN, C{sub 2}H{sub 2}, and crystalline silicates are also seen in several OHMs. Column densities of OH derived from 34.6 {mu}m OH absorption are similar to those derived from 1667 MHz OH absorption in non-masing galaxies, indicating that the abundance of masing molecules is similar for both samples. This data paper presents full mid-infrared spectra for each galaxy, along with measurements of line fluxes and equivalent widths, absorption feature depths, and spectral indices.

  9. High-resolution neutron crystallographic studies of the hydration of the coenzyme cob(II)alamin.

    PubMed

    Jogl, Gerwald; Wang, Xiaoping; Mason, Sax A; Kovalevsky, Andrey; Mustyakimov, Marat; Fisher, Zöe; Hoffman, Christina; Kratky, Christoph; Langan, Paul

    2011-06-01

    The hydration of the coenzyme cob(II)alamin has been studied using high-resolution monochromatic neutron crystallographic data collected at room temperature to a resolution of 0.92 Å on the original D19 diffractometer with a prototype 4° × 64° detector at the high-flux reactor neutron source run by the Institute Laue-Langevin. The resulting structure provides hydrogen-bonding parameters for the hydration of biomacromolecules to unprecedented accuracy. These experimental parameters will be used to define more accurate force fields for biomacromolecular structure refinement. The presence of a hydrophobic bowl motif surrounded by flexible side chains with terminal functional groups may be significant for the efficient scavenging of ligands. The feasibility of extending the resolution of this structure to ultrahigh resolution was investigated by collecting time-of-flight neutron crystallographic data during commissioning of the TOPAZ diffractometer with a prototype array of 14 modular 2° × 21° detectors at the Spallation Neutron Source run by Oak Ridge National Laboratory.

  10. A study of equivalent source techniques for high-resolution EEG imaging.

    PubMed

    Yao, D; Zhou, Y; Zeng, M; Fan, S; Lian, J; Wu, D; Ao, X; Chen, L; He, B

    2001-08-01

    High-resolution EEG imaging has been an important topic in recent EEG research, and much work has been done on the two equivalent source imaging techniques: the equivalent distributed dipole-layer source imaging technique (EST) and the equivalent multipole source imaging technique (SAT). In this paper we first develop a forward density formula for a spherical equivalent distributed dipole layer of an arbitrary dipole in a three-concentric-sphere head model. It is clarified using the derived forward formula that the equivalent dipole-layer source and equivalent multipole source are interrelated in theory. Finally, simulation comparisons are conducted, the results of which suggest that EST has a higher spatial resolution than SAT when both of them are implemented by a truncated singular value decomposition algorithm. This is due to the different singularities of the inversion equations involved in the two techniques. An empirical VEP data study also shows that EST is better than SAT in providing higher spatial resolution EEG imaging.

  11. High-resolution He-scattering apparatus for gas-surface interaction studies

    NASA Astrophysics Data System (ADS)

    David, Rudolf; Kern, Klaus; Zeppenfeld, Peter; Comsa, George

    1986-11-01

    A high-resolution apparatus designed for the study of elastic and inelastic scattering of thermal helium atoms from crystal surfaces is presented. The highly expanded He nozzle beam has an energy spread ΔE/E of about 1.4% and is collimated to 0.2°. The angle subtended by the detector opening as seen from the sample is also 0.2°. Beam intensities as low as 10-6 of the specular beam intensity from a low-temperature clean Pt(111) surface are detectable. Pseudorandom chopping with a resolution of 2.5 μs (flight path 790 mm) is used for time-of-flight (TOF) analysis of the scattered helium. The base pressure in the sample chamber is in the low 10-11 mbar. The capabilities of the apparatus are demonstrated for physisorbed Xe adlayers on Pt(111). The results presented are obtained by using He scattering in various modes: coherent inelastic, coherent elastic, and incoherent (diffuse) elastic. This technique allows for a nondestructive nearly exhaustive characterization of the thermodynamics, structure, and dynamics of physisorbed adlayers on arbitrary substrates.

  12. High resolution radio imaging study of the Pulsar Wind Nebula MSH 15-52

    NASA Astrophysics Data System (ADS)

    Leung, W.-Y.; Ng, C.-Y.

    2016-06-01

    We present a new high-resolution radio imaging study of the pulsar wind nebula (PWN) MSH 15-52, also dubbed as "the hand of God", with the Australia Telescope Compact Array observations. The system is powered by a young and energetic radio pulsar B1509-58 with high spin down luminosity of E(dot) = 2 x 10^37 erg/s. Previous X-ray images have shown that the PWN has a complex hand-shape morphology extending over 10 pc with features like jets, arc, filaments and enhanced emission knots in the HII region RCW 89. The new 6cm and 3cm radio images show different morphology than the X-ray counterpart. No radio counterpart of the X-ray jet is detected, instead we found enhanced emission in a sheath surrounding the jet. Additional small-scale features including a polarized linear filament next to the pulsar have also been discovered. Our polarisation measurements show that the intrinsic orientation of magnetic field aligns with the sheath. Finally, spectral analysis results indicate a steep spectrum for the system, which is rather unusual among PWNe. Implications of these findings will be discussed. The Australia Telescope Compact Array is part of the Australia Telescope National Facility which is funded by the Commonwealth of Australia for operation as a National Facility managed by CSIRO. This work is supported by an ECS grant under HKU 709713P.

  13. [Study on the advanced Schwarzschild imaging spectrometer with high resolution in broadband].

    PubMed

    Liu, Jian-Fang

    2013-08-01

    The Schwarzschild optical structure was studied for the application of imaging spectrometer. The perfect astigmatism-corrected condition was obtained based on the analysis of the astigmatism of the Schwarzschild structure. The structure was advanced in the paper. The Schwarzschild imaging spectrum system is composed of two Schwarzschild structures, which are the collimating mirror-convex mirror and the convex mirror-focusing mirror. The calculation was given to present the parameters of the imaging spectrum system. An example of the imaging spectrum system in the waveband of 340-500 nm was designed and proved our design theory. The solution of the initial optimum structure was designed by our theory and simulated. A system with NA 1.25, of which the modulation transfer functions (MTF) of all fields of view are more than 0.58 in the waveband in the required Nyquist frequency (20 lp x mm(-1)), is presented in the paper. The form of the design structure can be changed as C-T system, Ebert-Fastie system and Offner system. The result also certificated that the optical system theory can be applied to the small scale imaging spectrometer with high resolution and spectral broadband.

  14. [Study on an optical system of small ultraviolet imaging spectrometer with high resolution in broadband].

    PubMed

    Cong, Hai-Fang; Wang, Chun-Hui; Wang, Yu

    2013-02-01

    An ultraviolet imaging spectrometer was studied based on the principle of the small scale ultraviolet spectral instrument. The scheme composed of an off-axis parabolic mirror telescope and a single toroidal grating spectral imaging system was designed. The optimization of the optical system is the optimum processing for the parameters of the toroidal grating. The optical path function and the aberration equations of the grating were analyzed. The perfect anastigmatism conditions and imaging conditions of the single toroidal grating system were obtained. These two conditions that cannot be satisfied by the algebra calculation method limit the field of view and waveband of the spectrometer. The genetic algorithm was introduced to solve the problem. A solar-blind ultraviolet imaging spectrometer for 200-280 nm was designed to verify the design method. The optimum initial configuration was calculated and simulated. A system with F/# 5.7, focal length 102 mm and high spatial resolution was designed. The modulation transfer functions (MTF) of all fields of view are more than 0.65 in the waveband in the required Nyquist frequency (20 1p x mm(-1)). The design results indicate that the optical system theory can be applied to the small scale ultraviolet imaging spectrometer with high resolution and spectral broadband.

  15. Study of a high-resolution, 3-D positioning cadmium zinc telluride detector for PET

    PubMed Central

    Gu, Y; Matteson, J L; Skelton, R T; Deal, A C; Stephan, E A; Duttweiler, F; Gasaway, T M; Levin, C S

    2011-01-01

    This paper investigates the performance of 1 mm resolution Cadmium Zinc Telluride (CZT) detectors for positron emission tomography (PET) capable of positioning the 3-D coordinates of individual 511 keV photon interactions. The detectors comprise 40 mm × 40 mm × 5 mm monolithic CZT crystals that employ a novel cross-strip readout with interspersed steering electrodes to obtain high spatial and energy resolution. The study found a single anode FWHM energy resolution of 3.06±0.39% at 511 keV throughout most the detector volume. Improved resolution is expected with properly shielded front-end electronics. Measurements made using a collimated beam established the efficacy of the steering electrodes in facilitating enhanced charge collection across anodes, as well as a spatial resolution of 0.44±0.07 mm in the direction orthogonal to the electrode planes. Finally, measurements based on coincidence electronic collimation yielded a point spread function with 0.78±0.10 mm FWHM, demonstrating 1 mm spatial resolution capability transverse to the anodes – as expected from the 1 mm anode pitch. These findings indicate that the CZT-based detector concept has excellent performance and shows great promise for a high-resolution PET system. PMID:21335649

  16. Hunting the parent of the Orphan stream. II. The first high-resolution spectroscopic study

    SciTech Connect

    Casey, Andrew R.; Keller, Stefan C.; Da Costa, Gary; Maunder, Elizabeth; Frebel, Anna

    2014-03-20

    We present the first high-resolution spectroscopic study on the Orphan stream for five stream candidates, observed with the Magellan Inamori Kyocera Echelle spectrograph on the Magellan Clay telescope. The targets were selected from the low-resolution catalog of Casey et al.: three high-probability members, one medium, and one low-probability stream candidate were observed. Our analysis indicates that the low- and medium-probability targets are metal-rich field stars. The remaining three high-probability targets range over ∼1 dex in metallicity, and are chemically distinct compared to the other two targets and all standard stars: low [α/Fe] abundance ratios are observed, and lower limits are ascertained for [Ba/Y], which sit well above the Milky Way trend. These chemical signatures demonstrate that the undiscovered parent system is unequivocally a dwarf spheroidal galaxy, consistent with dynamical constraints inferred from the stream width and arc. As such, we firmly exclude the proposed association between NGC 2419 and the Orphan stream. A wide range in metallicities adds to the similarities between the Orphan stream and Segue 1, although the low [α/Fe] abundance ratios in the Orphan stream are in tension with the high [α/Fe] values observed in Segue 1. Open questions remain before Segue 1 could possibly be claimed as the 'parent' of the Orphan stream. The parent system could well remain undiscovered in the southern sky.

  17. Modelling high resolution Echelle spectrographs for calibrations: Hanle Echelle spectrograph, a case study

    NASA Astrophysics Data System (ADS)

    Chanumolu, Anantha; Jones, Damien; Thirupathi, Sivarani

    2015-06-01

    We present a modelling scheme that predicts the centroids of spectral line features for a high resolution Echelle spectrograph to a high accuracy. Towards this, a computing scheme is used, whereby any astronomical spectrograph can be modelled and controlled without recourse to a ray tracing program. The computations are based on paraxial ray trace and exact corrections added for certain surface types and Buchdahl aberration coefficients for complex modules. The resultant chain of paraxial ray traces and corrections for all relevant components is used to calculate the location of any spectral line on the detector under all normal operating conditions with a high degree of certainty. This will allow a semi-autonomous control using simple in-house, programming modules. The scheme is simple enough to be implemented even in a spreadsheet or in any scripting language. Such a model along with an optimization routine can represent the real time behaviour of the instrument. We present here a case study for Hanle Echelle Spectrograph. We show that our results match well with a popular commercial ray tracing software. The model is further optimized using Thorium Argon calibration lamp exposures taken during the preliminary alignment of the instrument. The model predictions matched the calibration frames at a level of 0.08 pixel. Monte Carlo simulations were performed to show the photon noise effect on the model predictions.

  18. IONIZED GAS KINEMATICS AT HIGH RESOLUTION. II. DISCOVERY OF A DOUBLE INFRARED CLUSTER IN II Zw 40

    SciTech Connect

    Beck, Sara; Lahad, Ohr; Turner, Jean; Lacy, John; Greathouse, Thomas

    2013-04-10

    The nearby dwarf galaxy II Zw 40 hosts an intense starburst. At the center of the starburst is a bright compact radio and infrared source, thought to be a giant dense H II region containing Almost-Equal-To 14, 000 O stars. Radio continuum images suggest that the compact source is actually a collection of several smaller emission regions. We accordingly use the kinematics of the ionized gas to probe the structure of the radio-infrared emission region. With TEXES on the NASA-IRTF we measured the 10.5 {mu}m [S IV] emission line with effective spectral resolutions, including thermal broadening, of {approx}25 and {approx}3 km s{sup -1} and spatial resolution {approx}1''. The line profile shows two distinct, spatially coextensive, emission features. The stronger feature is at galactic velocity and has FWHM 47 km s{sup -1}. The second feature is {approx}44 km s{sup -1} redward of the first and has FWHM 32 km s{sup -1}. We argue that these are two giant embedded clusters, and estimate their masses to be Almost-Equal-To 3 Multiplication-Sign 10{sup 5} M{sub Sun} and Almost-Equal-To 1.5 Multiplication-Sign 10{sup 5} M{sub Sun }. The velocity shift is unexpectedly large for such a small spatial offset. We suggest that it may arise in a previously undetected kinematic feature remaining from the violent merger that formed the galaxy.

  19. High resolution infrared spectroscopy of [1.1.1]propellane: The region of the ν9 band

    SciTech Connect

    Maki, Arthur; Weber, Alfons; Nibler, Joseph W.; Masiello, Tony; Blake, Thomas A.; Kirkpatrick, Robynne

    2010-11-01

    The region of the infrared-active band of the ν9 CH2 bending mode [1.1.1]propellane has been recorded at a resolution (0.0025 cm-1) sufficient to distinguish individual rovibrational lines. This region includes the partially overlapping bands ν9 (e') = 1459 cm-1, 2ν18 (l = 2, E') = 1430 cm-1, ν6 + ν12 (E') = 1489 cm-1, and ν4 + ν15 (A2") = 1518 cm-1. In addition, the difference band ν4 - ν15 (A2") was observed in the far infrared near 295 cm-1 and analyzed to give good constants for the upper ν4 levels. The close proximities of the four bands in the ν9 region suggest that Coriolis and Fermi resonance couplings could be significant and theoretical band parameters obtained from Gaussian ab initio calculations were helpful in guiding the band analyses. The analyses of all four bands were accomplished, based on our earlier report of ground state constants determined from combination differences involving more than 4000 pairs of transitions from five fundamental and four combination bands. This paper presents the analyses and the determination of the upper state constants of all four bands in the region of the ν9 band. Complications were most evident in the 2ν18 (l = 2, E') band, which showed significant perturbations due to mixing with the nearby 2ν18 (l = 0, A1') and ν4 + ν12 (E') levels which are either infrared inactive as transitions from the ground state, or, in the latter case, too weak to observe. Finally, these complications are discussed and a comparison of all molecular constants with those available from the ab initio calculations at the anharmonic level is presented.

  20. Retrieval of Precise Radial Velocities from Near-infrared High-resolution Spectra of Low-mass Stars

    NASA Astrophysics Data System (ADS)

    Gao, Peter; Plavchan, P.; Gagné, J.; Furlan, E.; Bottom, M.; Anglada-Escudé, G.; White, R.; Davison, C. L.; Beichman, C.; Brinkworth, C.; Johnson, J.; Ciardi, D.; Wallace, K.; Mennesson, B.; von Braun, K.; Vasisht, G.; Prato, L.; Kane, S. R.; Tanner, A.; Crawford, T. J.; Latham, D.; Rougeot, R.; Geneser, C. S.; Catanzarite, J.

    2016-10-01

    Given that low-mass stars have intrinsically low luminosities at optical wavelengths and a propensity for stellar activity, it is advantageous for radial velocity (RV) surveys of these objects to use near-infrared (NIR) wavelengths. In this work, we describe and test a novel RV extraction pipeline dedicated to retrieving RVs from low-mass stars using NIR spectra taken by the CSHELL spectrograph at the NASA Infrared Telescope Facility, where a methane isotopologue gas cell is used for wavelength calibration. The pipeline minimizes the residuals between the observations and a spectral model composed of templates for the target star, the gas cell, and atmospheric telluric absorption; models of the line-spread function, continuum curvature, and sinusoidal fringing; and a parameterization of the wavelength solution. The stellar template is derived iteratively from the science observations themselves without a need for separate observations dedicated to retrieving it. Despite limitations from CSHELL’s narrow wavelength range and instrumental systematics, we are able to (1) obtain an RV precision of 35 m s-1 for the RV standard star GJ 15 A over a time baseline of 817 days, reaching the photon noise limit for our attained signal-to-noise ratio; (2) achieve ˜3 m s-1 RV precision for the M giant SV Peg over a baseline of several days and confirm its long-term RV trend due to stellar pulsations, as well as obtain nightly noise floors of ˜2-6 m s-1 and (3) show that our data are consistent with the known masses, periods, and orbital eccentricities of the two most massive planets orbiting GJ 876. Future applications of our pipeline to RV surveys using the next generation of NIR spectrographs, such as iSHELL, will enable the potential detection of super-Earths and mini-Neptunes in the habitable zones of M dwarfs.

  1. The Claustrum and Insula in Microcebus murinus: A High Resolution Diffusion Imaging Study

    PubMed Central

    Park, Soyoung; Tyszka, J. Michael; Allman, John M.

    2012-01-01

    The claustrum and the insula are closely juxtaposed in the brain of the prosimian primate, the gray mouse lemur (Microcebus murinus). Whether the claustrum has closer affinities with the cortex or the striatum has been debated for many decades. Our observation of histological sections from primate brains and genomic data in the mouse suggest former. Given this, the present study compares the connections of the two structures in Microcebus using high angular resolution diffusion imaging (HARDI, with 72 directions), with a very small voxel size (90 micra), and probabilistic fiber tractography. High angular and spatial resolution diffusion imaging is non-destructive, requires no surgical interventions, and the connection of each and every voxel can be mapped, whereas in conventional tract tracer studies only a few specific injection sites can be assayed. Our data indicate that despite the high genetic and spatial affinities between the two structures, their connectivity patterns are very different. The claustrum connects with many cortical areas and the olfactory bulb; its strongest probabilistic connections are with the entorhinal cortex, suggesting that the claustrum may have a role in spatial memory and navigation. By contrast, the insula connects with many subcortical areas, including the brainstem and thalamic structures involved in taste and visceral feelings. Overall, the connections of the Microcebus claustrum and insula are similar to those of the rodents, cat, macaque, and human, validating our results. The insula in the Microcebus connects with the dorsolateral frontal cortex in contrast to the mouse insula, which has stronger connections with the ventromedial frontal lobe, yet this is consistent with the dorsolateral expansion of the frontal cortex in primates. In addition to revealing the connectivity patterns of the Microcebus brain, our study demonstrates that HARDI, at high resolutions, can be a valuable tool for mapping fiber pathways for multiple

  2. Old high resolution satellite images for landscape archaeology: case studies from Turkey and Iraq

    NASA Astrophysics Data System (ADS)

    Scardozzi, Giuseppe

    2008-10-01

    The paper concerns the contribution for Landscape Archaeology from satellite images of 1960s and 1970s, very useful when old aerial photographs are scarce. Particularly, the study concerns the panchromatic photos taken by USA reconnaissance satellites from 1963 to 1972, declassified for civil use in 1995 and 2002, that in the last years are very used in the archaeological research; in fact, a lot of these images have an high geometric resolution, about between 2.74 and 1.83 m (Corona KH-4A and KH-4B), and some have a ground resolution about between 1.20 and 0.60 m (Gambit KH-7). These satellite images allow to examine very in detail ancient urban areas and territories that later are changed or partially destroyed; so, it is possible to detect and examine ancient structures, palaeo-environmental elements and archaeological traces of buried features now not visible. The paper presents some exemplificative cases study in Turkey and Iraq, in which the analysis of these images has made a fundamental contribution to the archaeological researches: particularly, for the reconstruction of the urban layout of the ancient city of Hierapolis of Phrygia and for the surveys in its territory, and for the study of the ancient topography of some archaeological sites of Iraq. In this second case, the research is gained in the context of the Iraq Virtual Museum Project; the comparison with recent high resolution satellite images (Ikonos-2, QuickBird-2, WorldView-1) also provide a fundamental tool for monitoring archaeological areas and for an evaluation of the situation after the first and the second Gulf War.

  3. HIRS-AMTS satellite sounding system test - Theoretical and empirical vertical resolving power. [High resolution Infrared Radiation Sounder - Advanced Moisture and Temperature Sounder

    NASA Technical Reports Server (NTRS)

    Thompson, O. E.

    1982-01-01

    The present investigation is concerned with the vertical resolving power of satellite-borne temperature sounding instruments. Information is presented on the capabilities of the High Resolution Infrared Radiation Sounder (HIRS) and a proposed sounding instrument called the Advanced Moisture and Temperature Sounder (AMTS). Two quite different methods for assessing the vertical resolving power of satellite sounders are discussed. The first is the theoretical method of Conrath (1972) which was patterned after the work of Backus and Gilbert (1968) The Backus-Gilbert-Conrath (BGC) approach includes a formalism for deriving a retrieval algorithm for optimizing the vertical resolving power. However, a retrieval algorithm constructed in the BGC optimal fashion is not necessarily optimal as far as actual temperature retrievals are concerned. Thus, an independent criterion for vertical resolving power is discussed. The criterion is based on actual retrievals of signal structure in the temperature field.

  4. Seasonal differences of urban organic aerosol composition - an ultra-high resolution mass spectrometry study

    NASA Astrophysics Data System (ADS)

    Rincon, A. G.; Calvo, A. I.; Dietzel, M.; Kalberer, M.

    2012-04-01

    The understanding of the chemical composition of atmospheric aerosols, their properties and reactivity are important for assessing aerosol effects upon both global climate change and human health. The composition of organic aerosols is poorly understood mainly due to their highly complex chemical composition with several thousand compounds. In the present study the water-soluble organic fraction of ambient particles collected at an urban site in Cambridge, UK, during different seasons were analysed with ultra-high resolution mass spectrometry. For several thousand peaks in the mass specta (between 3000-6000) an elemental composition could be assigned and summer samples generally contained more components than winter samples. Up to 80% of the peaks in the mass spectra contain nitrogen and/or sulphur functional groups and only about 20% of the compounds contain only C, H and O atoms. In summer the fraction of compounds with oxidized nitrogen and sulphur groups increases compared to winter indicating a photo-chemical formation route of these multifunctional compounds. In addition to oxidized nitrogen compounds a large number of highly unsaturated reduced nitrogen-containing compounds were detected, corresponding likely to cyclic amines. A significant number of oxidized PAHs have been detected in summer samples, which were not present in winter, indicating again photo-chemical aging processes. Both, amines and long-chain aliphatic acids (also frequently observed in these urban samples) are likely signatures of biomass burning and primary biological sources. Potential biomass burning markers are discussed. Particle-phase oligomerisation reactions have only been observed to a very limited degree. Compounds larger than m/z 350 almost exclusively contained N and/or S functional groups indicating that the high molecular weight compounds in these organic aerosol extracts might be mainly due to particle-phase heterogeneous reactions of organic compounds with inorganic

  5. Molecular composition of organic aerosols in central Amazonia: an ultra-high-resolution mass spectrometry study

    NASA Astrophysics Data System (ADS)

    Kourtchev, Ivan; Godoi, Ricardo H. M.; Connors, Sarah; Levine, James G.; Archibald, Alex T.; Godoi, Ana F. L.; Paralovo, Sarah L.; Barbosa, Cybelli G. G.; Souza, Rodrigo A. F.; Manzi, Antonio O.; Seco, Roger; Sjostedt, Steve; Park, Jeong-Hoo; Guenther, Alex; Kim, Saewung; Smith, James; Martin, Scot T.; Kalberer, Markus

    2016-09-01

    The Amazon Basin plays key role in atmospheric chemistry, biodiversity and climate change. In this study we applied nanoelectrospray (nanoESI) ultra-high-resolution mass spectrometry (UHRMS) for the analysis of the organic fraction of PM2.5 aerosol samples collected during dry and wet seasons at a site in central Amazonia receiving background air masses, biomass burning and urban pollution. Comprehensive mass spectral data evaluation methods (e.g. Kendrick mass defect, Van Krevelen diagrams, carbon oxidation state and aromaticity equivalent) were used to identify compound classes and mass distributions of the detected species. Nitrogen- and/or sulfur-containing organic species contributed up to 60 % of the total identified number of formulae. A large number of molecular formulae in organic aerosol (OA) were attributed to later-generation nitrogen- and sulfur-containing oxidation products, suggesting that OA composition is affected by biomass burning and other, potentially anthropogenic, sources. Isoprene-derived organosulfate (IEPOX-OS) was found to be the most dominant ion in most of the analysed samples and strongly followed the concentration trends of the gas-phase anthropogenic tracers confirming its mixed anthropogenic-biogenic origin. The presence of oxidised aromatic and nitro-aromatic compounds in the samples suggested a strong influence from biomass burning especially during the dry period. Aerosol samples from the dry period and under enhanced biomass burning conditions contained a large number of molecules with high carbon oxidation state and an increased number of aromatic compounds compared to that from the wet period. The results of this work demonstrate that the studied site is influenced not only by biogenic emissions from the forest but also by biomass burning and potentially other anthropogenic emissions from the neighbouring urban environments.

  6. Cadastral Resurvey using High Resolution Satellite Ortho Image - challenges: A case study in Odisha, India

    NASA Astrophysics Data System (ADS)

    Parida, P. K.; Sanabada, M. K.; Tripathi, S.

    2014-11-01

    Advancements in satellite sensor technology enabling capturing of geometrically accurate images of earth's surface coupled with DGPS/ETS and GIS technology holds the capability of large scale mapping of land resources at cadastral level. High Resolution Satellite Images depict field bunds distinctly. Thus plot parcels are to be delineated from cloud free ortho-images and obscured/difficult areas are to be surveyed using DGPS and ETS. The vector datasets thus derived through RS/DGPS/ETS survey are to be integrated in GIS environment to generate the base cadastral vector datasets for further settlement/title confirmation activities. The objective of this paper is to illustrate the efficacy of a hybrid methodology employed in Pitambarpur Sasana village under Digapahandi Tahasil of Ganjam district, as a pilot project, particularly in Odisha scenario where the land parcel size is very small. One of the significant observations of the study is matching of Cadastral map area i.e. 315.454 Acres, the image map area i.e. 314.887 Acres and RoR area i.e. 313.815 Acre. It was revealed that 79 % of plots derived by high-tech survey method show acceptable level of accuracy despite the fact that the mode of area measurement by ground and automated method has significant variability. The variations are more in case of Government lands, Temple/Trust lands, Common Property Resources and plots near to river/nalas etc. The study indicates that the adopted technology can be extended to other districts and cadastral resurvey and updating work can be done for larger areas of the country using this methodology.

  7. High resolution direct evaporation tagging in a RCM: A case study for West Africa

    NASA Astrophysics Data System (ADS)

    Kunstmann, Harald; Knoche, Hans Richard

    2014-05-01

    One of the central questions in hydrological research is where and to what extent evaporated water of a region returns as precipitation in another region. This study addresses this question and presents a detailed process-based approach implemented into a high resolution regional climate model. It allows tagging and tracking of the moisture evaporating from a given region into the atmosphere until it returns to the land surface as precipitation. Our approach is fully three-dimensional and enables the detailed consideration of vertical transport mechanisms for tagged water. We present a case study for the region around Lake Volta in West Africa, which is one of the largest man made surface water body in the world. The simulation demonstrates the performance of the regional model and the implemented tagging mechanism. It shows the evolution of the tagged moisture field and reveals details of the transport: Moisture evaporated from Lake Volta is initially transported predominantly to the east and north, lifted by convective processes and then transported in upper layers to the west far away from the source of evaporation. The results indicate that the coupling between boundary layer and higher levels through convective processes can be essential for the fate of tagged water substances. Detailed analysis for a 2 month period in the rainy season 1998 shows that locally up to 6% of precipitating water originates from the Lake Volta region. Less than 2% of the evaporated water is locally recycled as precipitation in the source area. A further 10% precipitates in the rest of the Volta Basin.

  8. Using High-Resolution Airborne Remote Sensing to Study Aerosol Near Clouds

    NASA Technical Reports Server (NTRS)

    Levy, Robert; Munchak, Leigh; Mattoo, Shana; Marshak, Alexander; Wilcox, Eric; Gao, Lan; Yorks, John; Platnick, Steven

    2016-01-01

    The horizontal space in between clear and cloudy air is very complex. This so-called twilight zone includes activated aerosols that are not quite clouds, thin cloud fragments that are not easily observable, and dying clouds that have not quite disappeared. This is a huge challenge for satellite remote sensing, specifically for retrieval of aerosol properties. Identifying what is cloud versus what is not cloud is critically important for attributing radiative effects and forcings to aerosols. At the same time, the radiative interactions between clouds and the surrounding media (molecules, surface and aerosols themselves) will contaminate retrieval of aerosol properties, even in clear skies. Most studies on aerosol cloud interactions are relevant to moderate resolution imagery (e.g. 500 m) from sensors such as MODIS. Since standard aerosol retrieval algorithms tend to keep a distance (e.g. 1 km) from the nearest detected cloud, it is impossible to evaluate what happens closer to the cloud. During Studies of Emissions, Atmospheric Composition, Clouds and Climate Coupling by Regional Surveys (SEAC4RS), the NASA ER-2 flew with the enhanced MODIS Airborne Simulator (eMAS), providing MODIS-like spectral observations at high (50 m) spatial resolution. We have applied MODIS-like aerosol retrieval for the eMAS data, providing new detail to characterization of aerosol near clouds. Interpretation and evaluation of these eMAS aerosol retrievals is aided by independent MODIS-like cloud retrievals, as well as profiles from the co-flying Cloud Physics Lidar (CPL). Understanding aerosolcloud retrieval at high resolution will lead to better characterization and interpretation of long-term, global products from lower resolution (e.g.MODIS) satellite retrievals.

  9. High-resolution spectroscopic studies of ultra metal-poor stars found in the LAMOST survey

    NASA Astrophysics Data System (ADS)

    Li, Haining; Aoki, Wako; Zhao, Gang; Honda, Satoshi; Christlieb, Norbert; Suda, Takuma

    2015-10-01

    We report on the observations of two ultra metal-poor (UMP) stars with [Fe/H] ˜ -4.0, including one new discovery. The two stars are studied in the on-going and quite efficient project to search for extremely metal-poor (EMP) stars with LAMOST and Subaru. Detailed abundances or upper limits of abundances have been derived for 15 elements from Li to Eu based on high-resolution spectra obtained with the High Dispersion Spectrograph (HDS) mounted in the Subaru Telescope. The abundance patterns of both UMP stars are consistent with the "normal population" among the low-metallicity stars. Both of the two program stars show carbon-enhancement without any excess of heavy neutron-capture elements, indicating that they belong to the subclass of (carbon-enhanced metal-poor) CEMP-no stars, as is the case of most UMP stars previously studied. The [Sr/Ba] ratios of both CEMP-no UMP stars are above [Sr/Ba] ˜ -0.4, suggesting the origin of the carbon-excess is not compatible with the mass transfer from an asymptotic giant branch companion where the s-process has operated. Lithium abundance is measured in the newly discovered UMP star LAMOST J125346.09+075343.1, making it the second UMP turnoff star with Li detection. The Li abundance of LAMOST J125346.09+075343.1 is slightly lower than the values obtained for less metal-poor stars with similar temperatures, and provides a unique data point at [Fe/H] ˜ -4.2 to support the "meltdown" of the Li Spite plateau at extremely low metallicity. Comparison with the other two UMP and HMP (hyper metal-poor, with [Fe/H] < -5.0) turnoff stars suggests that the difference in lighter elements such as CNO and Na might cause notable difference in lithium abundances among CEMP-no stars.

  10. High Resolution Infrared Spectroscopy of the CO_2-CO Dimers and (CO_2)_2-CO Trimer

    NASA Astrophysics Data System (ADS)

    Barclay, A. J.; Sheybani-Deloui, S.; Michaelian, K. H.; McKellar, Bob; Moazzen-Ahmadi, Nasser

    2016-06-01

    Infrared spectra in the carbon monoxide CO stretch region (≈2150 cm-1) are assigned to the previously unobserved O-bonded form of the CO_2-CO dimer ("isomer 2"), which has a planar T-shaped structure like that of the previously observed C-bonded form ("isomer 1"). Results will also be reported for both isomers of the 12C18O_2-substituted form of the dimer. In addition, we have observed two combination bands for each isomer yielding the first experimental determinations of intermolecular frequencies for the planar T-shaped structures. Within both of the fundamental bands, weak "satellite bands" are observed. These are tentatively assigned to the trimer He-CO_2-CO. To the higher side of the fundamental for "isomer 1", we have observed a weaker b-type band which we have assigned to (CO_2)_2-CO trimer. This trimer has a "pin wheel" structure with C2 symmetry and the derived experimental structural parameters match well with those obtained from ab initio calculations.

  11. High-resolution, near-infrared CW-CRDS, and ab initio investigations of N2O-HDO

    NASA Astrophysics Data System (ADS)

    Földes, T.; Lauzin, C.; Vanfleteren, T.; Herman, M.; Liévin, J.; Didriche, K.

    2015-03-01

    We have investigated the N2O-HDO molecular complex using ab initio calculations at the CCSD(T)-F12a/aug-cc-pVTZ level of theory and using cavity ring-down spectroscopy to probe an HDO/N2O/Ar supersonic jet around 1.58 μm. A single a-type vibrational band was observed, 13 cm-1 redshifted compared to the OH+OD excited band in HDO, and 173 vibration-rotation lines were assigned (Trot ≈ 20 K). A weighted fit of existing microwave and present near infrared (NIR) data was achieved using a standard Watson's Hamiltonian (σ = 1.26), producing ground and excited states rotational constants. The comparison of the former with those calculated ab initio suggests a planar geometry in which the OD rather than the OH bond in water is almost parallel to NNO. The equilibrium geometry and dissociation energy (De = -11.7 kJ/mol) of the water-nitrous oxide complex were calculated. The calculations further demonstrate and allow characterising another minimum, 404 cm-1 (ΔE0) higher in energy. Harmonic vibrational frequencies and dissociation energies, D0, were calculated for various conformers and isotopic forms of the complex, in both minima. The absence of N2O-D2O from dedicated NIR experiments is reported and discussed.

  12. Source Attribution of Methane Emission from Petroleum Production Operations using High-Resolution Airborne Thermal-Infrared Imaging Spectrometry

    NASA Astrophysics Data System (ADS)

    Tratt, D. M.; Buckland, K. N.; Young, S. J.; Riley, D.; Leifer, I.

    2012-12-01

    High spatio-spectral resolution airborne thermal-infrared (TIR) imaging spectrometry is shown to be effective in detecting and tracking gaseous emissions from petroleum production facilities. The high spatial resolution (1-2 m) of the sensor permits unequivocal trace-back of emission plumes to their source. The high spectral resolution (44 nm across the 7.5-13.5 μm TIR band) enables precise identification and discrimination of primary and subsidiary plume components through the application of spectral matched filtering and adaptive coherence estimation techniques. Operation in the TIR spectral region allows operations to be conducted throughout the diurnal cycle, since the measurement relies on observation of emissive radiation and the intrinsic thermal contrast between the fugitive plume gases and the underlying scene. Methane plumes associated with petroleum production operations and natural emissions have been identified in a variety of environmental settings. The accompanying figure shows a grayscale thermal image of a marine production platform off the California coast. A gas plume (identified as methane) being released from a venting boom is shown superimposed in false color.

  13. High-Resolution Spectroscopic Studies of Complexes Formed by Medium-Size Organic Molecules.

    PubMed

    Becucci, Maurizio; Melandri, Sonia

    2016-05-11

    A wealth of structural and dynamical information has been obtained in the last 30 years from the study of high-resolution spectra of molecular clusters generated in a cold supersonic expansion by means of highly resolved spectroscopic methods. The data obtained, generally lead to determination of the structures of stable conformations. In addition, in the case of weakly bound molecular complexes, it is usual to observe the effects of internal motions due to the shallowness of the potential energy surfaces involved and the flexibility of the systems. In the case of electronic excitation experiments, also the effect of electronic distribution changes on both equilibrium structures and internal motions becomes accessible. The structural and dynamical information that can be obtained by applying suitable theoretical models to the analysis of these unusually complex spectra allows the determination and understanding of the driving forces involved in formation of the molecular complex. In this way, many types of non-covalent interactions have been characterized, from pure van der Waals interactions in complexes of rare gases to moderate-strength and weak hydrogen bonds and to the most recent halogen bonds and n-π interactions. The aim of this review is to underline how the different experimental and theoretical methods converge in giving a detailed picture of weak interactions in small molecular adducts involving medium-size molecules. The conclusions regarding geometries and energies can contribute to understanding of the different driving forces involved in the dynamics of the processes and can be exploited in all fields of chemistry and biochemistry, from design of new materials with novel properties to rational design of drugs. PMID:26986455

  14. A High-Resolution Spectrophotometric Study of the WR Binary System V444 Cygni

    NASA Astrophysics Data System (ADS)

    Underhill, Anne B.

    1984-07-01

    The binary system V444 Cygni (P = 4.212424 day) is an important object for determining the sizes and masses of 0 and WR stars. However, no spectrographic studies of its orbit have been made since 1950. The orbital elements given by Munch (1950) require confirmation, especially the elements describing the motion of the WR star. Spectrophotometric observations from the ground by Kuhi (1968) indicate that the system is enveloped in high-temperature gas which may be streaming between the stars. Review of the four (3 SWP, I LWR) high-resolution spectrograms of this system taken previously by others indicates that absorption lines attributable to the O star occur in the wavelength range from 1700 to 1900A, and that rather sharp absorption components associated with the C II resonance lines and with N IV 1718 occur on some of the spectrograms, but not on others. It is planned to follow V444 Cygni through one orbital cycle obtaining spectra throughout both eclipses and at the elongations. Observations will be made with the SWP camera using the spectrograph in the highresolution mode and with the large aperture. The resulting series of spectra will permit us to confirm and improve the orbital elements of Munch, and to track what, if any, streams of gas occur in the system. Improved orbital elements will allow us to deduce improved sizes and masses for the two stars. Analysis of the blended spectra and comparisons with the spectra of single stars having equivalent spectral types to those of the components of V444 Cygni will allow us to infer information about the physical state of the atmosphere of each star. Appropriate comparison spectra of single stars exist in NSSDC. The P.I. has copies of some of them.

  15. Hunting the Parent of the Orphan Stream. II. The First High-resolution Spectroscopic Study

    NASA Astrophysics Data System (ADS)

    Casey, Andrew R.; Keller, Stefan C.; Da Costa, Gary; Frebel, Anna; Maunder, Elizabeth

    2014-03-01

    We present the first high-resolution spectroscopic study on the Orphan stream for five stream candidates, observed with the Magellan Inamori Kyocera Echelle spectrograph on the Magellan Clay telescope. The targets were selected from the low-resolution catalog of Casey et al.: three high-probability members, one medium, and one low-probability stream candidate were observed. Our analysis indicates that the low- and medium-probability targets are metal-rich field stars. The remaining three high-probability targets range over ~1 dex in metallicity, and are chemically distinct compared to the other two targets and all standard stars: low [α/Fe] abundance ratios are observed, and lower limits are ascertained for [Ba/Y], which sit well above the Milky Way trend. These chemical signatures demonstrate that the undiscovered parent system is unequivocally a dwarf spheroidal galaxy, consistent with dynamical constraints inferred from the stream width and arc. As such, we firmly exclude the proposed association between NGC 2419 and the Orphan stream. A wide range in metallicities adds to the similarities between the Orphan stream and Segue 1, although the low [α/Fe] abundance ratios in the Orphan stream are in tension with the high [α/Fe] values observed in Segue 1. Open questions remain before Segue 1 could possibly be claimed as the "parent" of the Orphan stream. The parent system could well remain undiscovered in the southern sky. This paper includes data gathered with the 6.5 m Magellan Telescopes located at Las Campanas Observatory, Chile.

  16. High-resolution ultrastructural study of the rat glomerular basement membrane in aminonucleoside nephrosis.

    PubMed

    Inoue, S; Bendayan, M

    1996-01-01

    In the initial stages of aminonucleoside nephrosis, functional alterations in the glomerular basement membrane occur, as evidenced by the development of proteinuria. However, it has not been possible to observe important ultrastructural modifications at the level of the basement membrane, probably because the changes are taking place at the molecular level. In this study, by the use of high-resolution electron microscopy, an attempt was made to evaluate such changes in rat glomerular basement membrane during acute aminonucleoside nephrosis. As previously reported, in control animals the glomerular basement membrane is composed of a network of 4-nm-wide irregular anastomosing strands, referred to as "cords," which are known to contain a core filament of type IV collagen surrounded by a "sheath" of other components, such as laminin and heparan sulfate proteoglycan (HSPG). The most conspicuous ultrastructural alteration of the nephrotic glomerular basement membrane, recognizable only at high magnification, is that the cords were denuded leaving only the core filament through the loss of the sheath material. Thus, the cord network was transformed, with the progress of pathological conditions, into a network of fine filaments. On the other hand, abundance and distribution of HSPG molecules known to be present in the form of 4.5- to 5-nm-wide ribbon-like "double tracks," were found to be similar in control and nephrotic tissues. Since HSPG is one of the charge proteins of the basement membrane, the little changes observed for HSPG are difficult to interpret in view of reported decreases in basement membrane anionic sites in nephrosis. In conclusion, the glomerular basement membrane in aminonucleoside nephrosis loses its cord network components and replaces them with a more perforated network, which could be a cause for the increased permeability of this basement membrane. PMID:8883324

  17. The Spectrum of Achalasia: Lessons From Studies of Pathophysiology and High-Resolution Manometry

    PubMed Central

    Kahrilas, Peter J.; Boeckxstaens, Guy

    2013-01-01

    High-resolution manometry and recently described analysis algorithms, summarized in the Chicago Classification, have increased the recognition of achalasia. It has become apparent that the cardinal feature of achalasia, impaired lower esophageal sphincter relaxation, can occur in several disease phenotypes: without peristalsis, with premature (spastic) distal esophageal contractions, with panesophageal pressurization, or with peristalsis. Any of these phenotypes could indicate achalasia; however, without a disease-specific biomarker, no manometric pattern is absolutely specific. Laboratory studies indicate that achalasia is an autoimmune disease in which esophageal myenteric neurons are attacked in a cell-mediated and antibody-mediated immune response against an uncertain antigen. This autoimmune response could be related to infection of genetically predisposed subjects with herpes simplex virus 1, although there is substantial heterogeneity among patients. At one end of the spectrum is complete aganglionosis in patients with end-stage or fulminant disease. At the opposite extreme is type III (spastic) achalasia, which has no demonstrated neuronal loss but only impaired inhibitory postganglionic neuron function; it is often associated with accentuated contractility and could be mediated by cytokine-induced alterations in gene expression. Distinct from these extremes is progressive plexopathy, which likely arises from achalasia with preserved peristalsis and then develops into type II achalasia and then type I achalasia. Variations in its extent and rate of progression are likely related to the intensity of the cytotoxic T-cell assault on the myenteric plexus. Moving forward, we need to integrate the knowledge we have gained into treatment paradigms that are specific for individual phenotypes of achalasia and away from the one-size-fits-all approach. PMID:23973923

  18. Simulation of Urban Climate with High-Resolution WRF Model: A Case Study in Nanjing, China

    SciTech Connect

    Yang, Ben; Zhang, Yaocun; Qian, Yun

    2012-08-05

    In this study, urban climate in Nanjing of eastern China is simulated using 1-km resolution Weather Research and Forecasting (WRF) model coupled with a single-layer Urban Canopy Model. Based on the 10-summer simulation results from 2000 to 2009 we find that the WRF model is capable of capturing the high-resolution features of urban climate over Nanjing area. Although WRF underestimates the total precipitation amount, the model performs well in simulating the surface air temperature, relative humidity, and precipitation frequency, diurnal cycle and inter-annual variability. We find that extremely hot events occur most frequently in urban area, with daily maximum (minimum) temperature exceeding 36ºC (28ºC) in around 40% (32%) of days. Urban Heat Island (UHI) effect at surface is more evident during nighttime than daytime, with 20% of cases the UHI intensity above 2.5ºC at night. However, The UHI affects the vertical structure of Planet Boundary Layer (PBL) more deeply during daytime than nighttime. Net gain for latent heat and net radiation is larger over urban than rural surface during daytime. Correspondingly, net loss of sensible heat and ground heat are larger over urban surface resulting from warmer urban skin. Because of different diurnal characteristics of urban-rural differences in the latent heat, ground heat and other energy fluxes, the near surface UHI intensity exhibits a very complex diurnal feature. UHI effect is stronger in days with less cloud or lower wind speed. Model results reveal a larger precipitation frequency over urban area, mainly contributed by the light rain events (<10 mm day-1). Consistent with satellite dataset, around 10-20% more precipitation occurs in urban than rural area at afternoon induced by more unstable urban PBL, which induces a strong vertical atmospheric mixing and upward moisture transport. A significant enhancement of precipitation is found in the downwind region of urban in our simulations in the afternoon.

  19. Dynamical Studies of the Middle Atmosphere Using High Resolution Doppler Imager Observations

    NASA Technical Reports Server (NTRS)

    Skinner, Wilbert

    2002-01-01

    This report summarizes the activities of NASA grant NAG5-11068, "Dynamicai Studies of the Middle Atmosphere Using High Resolution Doppler Imager Observations." The High Resolution Doppler Imager (HRDI) on the Upper Atmosphere Research Satellite (UARS) has been providing direct measurements of the Earth's horizontal wind field in the stratosphere, mesosphere and lower thermosphere. Mesospheric temperatures, ozone, and O((sup 1) D) densities, and stratospheric aerosol extinctions coefficients, are also retrieved. The goal of HRDI is to measure the vector winds in the stratosphere (10-40 km), mesosphere, and lower thermosphere (approximately 50-120 km) during the day, and the lower thermosphere at night (approximately 95 km) to an accuracy of 5 m/s. The horizontal wind vector is measured by observing the Doppler shift of rotational lines of molecular oxygen along two lines of sight. In addition to winds, temperatures and volume emission rates are determined in the mesosphere and lower thermosphere, from which ozone and O((sup 1) D) concentrations can be derived, and aerosol scattering coefficients are determined in the stratosphere. UARS was launched on September 12, 1991, into a 585-km circular orbit inclined 57 degrees to the equator HRDI was activated September 28, 1991 and following a period of checkout and adjustment of the instrument parameters, scientific observations began November 2, 199 1. HRDI operated nearly continuously from launch until April 1995. At that time the UARS solar array drive failed, forcing the instruments to time-share the available power. From July 1995 to July 1996 HRDI operated approximately 50% of the time. At that point, one of the three spacecraft batteries failed and from then until September 1998 the duty cycle was less than 20% per month, At that time it was determined that HRDI could operate during each daytime pass, which increased the daytime duty cycle to close to l00%, while nighttime operations were limited to about a week

  20. Line Identifications and Preliminary Synthesis of High-resolution Infrared Spectra of CP and Herbig Ae Stars

    NASA Astrophysics Data System (ADS)

    Cowley, Charles R.; Castelli, F.; Hubrig, S.; Wolff, B.; Elkin, V.

    2012-01-01

    We report on surveys of infrared spectra of chemically peculiar and Herbig Ae stars based on CRIRES (Kaufl, et al. SPIE, 5492, 1218 2004). We discuss the magnetic CP stars Gamma Equ and HD 154708, and multiple-phase observations of the Herbig Ae star HD 101412. The Be star HR 4537 and HgMn HR 6620 were also examined. The primary emphasis of the present work is on line identifications primarily in four regions, 1065-1091, 1084-1109,1550-1587, and 2276-2313nm (with order gaps). Observations were reduced with recipes available from the ESO CRIRES data reduction pipeline. Wavelength calibration is determined from daytime ThAr arc lamp exposures. Generally speaking, this is not rich in atomic lines. The strongest features are the Paschen line P6 (1093.81nm), and He I (108.30nm). The latter shows phase variations indicative of a more complex magnetic field than that of a pure dipole. No individual molecular lines were found in these early stars, though CO emission from circumstellar material is likely present in HR 4537 and HD 101412. We used atomic line lists from Kurucz's site (kurucz.harvard.edu) and VALD (http://vald.astro.univie.ac.at/ cf. Kupka et al. 1999, A&AS, 138, 119), supplemented by Outred (J. Phys. Chem. Ref. Data 7, 1, 1978). The following spectra were identified in Gamma Equ: C I, Si I, Ca I, Mg I, II, Cr I, Fe I, Sr II, and Ce III (1584.75nm). The Ap star spectra show broad Zeeman patterns compatible with published models and field strengths. Synthetic calculations used SYNTHE and SYNTHMAG (Piskunov N. E., 1999, in Astrophys. Space Sci. Library Vol. 243, Solar polarization. Kluwer, p 515). The γ Equ model is from Heiter et al. (2002, A&A, 392, 619). and the line list from VALD.

  1. Development of Fiber Fabry-Perot Interferometers as Stable Near-infrared Calibration Sources for High Resolution Spectrographs

    NASA Astrophysics Data System (ADS)

    Halverson, Samuel; Mahadevan, Suvrath; Ramsey, Lawrence; Hearty, Fred; Wilson, John; Holtzman, Jon; Redman, Stephen; Nave, Gillian; Nidever, David; Nelson, Matt; Venditti, Nick; Bizyaev, Dmitry; Fleming, Scott

    2014-05-01

    We discuss the ongoing development of single-mode fiber Fabry-Perot (FFP) Interferometers as precise astrophotonic calibration sources for high precision radial velocity (RV) spectrographs. FFPs are simple, inexpensive, monolithic units that can yield a stable and repeatable output spectrum. An FFP is a unique alternative to a traditional etalon, as the interferometric cavity is made of single-mode fiber rather than an air-gap spacer. This design allows for excellent collimation, high spectral finesse, rigid mechanical stability, insensitivity to vibrations, and no need for vacuum operation. The device we have tested is a commercially available product from Micron Optics.10 Our development path is targeted toward a calibration source for the Habitable-Zone Planet Finder (HPF), a near-infrared spectrograph designed to detect terrestrial-mass planets around low-mass stars, but this reference could also be used in many existing and planned fiber-fed spectrographs as we illustrate using the Apache Point Observatory Galactic Evolution Experiment (APOGEE) instrument. With precise temperature control of the fiber etalon, we achieve a thermal stability of 100 μK and associated velocity uncertainty of 22 cm s-1. We achieve a precision of ≈2 m s-1 in a single APOGEE fiber over 12 hr using this new photonic reference after removal of systematic correlations. This high precision (close to the expected photon-limited floor) is a testament to both the excellent intrinsic wavelength stability of the fiber interferometer and the stability of the APOGEE instrument design. Overall instrument velocity precision is 80 cm s-1 over 12 hr when averaged over all 300 APOGEE fibers and after removal of known trends and pressure correlations, implying the fiber etalon is intrinsically stable to significantly higher precision.

  2. TESTING THE HYPOTHESIS THAT METHANOL MASER RINGS TRACE CIRCUMSTELLAR DISKS: HIGH-RESOLUTION NEAR-INFRARED AND MID-INFRARED IMAGING

    SciTech Connect

    De Buizer, James M.; Bartkiewicz, Anna; Szymczak, Marian

    2012-08-01

    Milliarcsecond very long baseline interferometry maps of regions containing 6.7 GHz methanol maser emission have lead to the recent discovery of ring-like distributions of maser spots and the plausible hypothesis that they may be tracing circumstellar disks around forming high-mass stars. We aimed to test this hypothesis by imaging these regions in the near- and mid-infrared at high spatial resolution and compare the observed emission to the expected infrared morphologies as inferred from the geometries of the maser rings. In the near-infrared we used the Gemini North adaptive optics system of ALTAIR/NIRI, while in the mid-infrared we used the combination of the Gemini South instrument T-ReCS and super-resolution techniques. Resultant images had a resolution of {approx}150 mas in both the near-infrared and mid-infrared. We discuss the expected distribution of circumstellar material around young and massive accreting (proto)stars and what infrared emission geometries would be expected for the different maser ring orientations under the assumption that the masers are coming from within circumstellar disks. Based upon the observed infrared emission geometries for the four targets in our sample and the results of spectral energy distribution modeling of the massive young stellar objects associated with the maser rings, we do not find compelling evidence in support of the hypothesis that methanol masers rings reside in circumstellar disks.

  3. High-resolution airborne magnetometry for hydrocarbon exploration: A case study, Wilson County, Texas

    SciTech Connect

    McConnell, T.J.; Phillips, J.D.

    1994-12-31

    Aeromagnetic anomaly surveying has been used extensively for geophysical exploration since just before World War II. Its primary value in hydrocarbon exploration has been for mapping the strong magnetic anomalies of the crystalline magnetic basement rocks to estimate the regional thickness of overlying, potential oil and gas bearing sediments. These basement responses are typically in the amplitude range of 2--200 nanotesla (nT) or gammas. In contrast, High Resolution Aeromagnetic (HRA) surveys specifically target the sedimentary stack where response amplitudes generated are typically in the range of 0.2-2.0 nT. These low intensity anomalies generated within the sediments are related to changes in the magnetic composition of rocks. This will occur when rocks of differing magnetic intensities are juxtaposed across a fault, or at a stratigraphic truncation. With this objective in mind a new high resolution, high sensitivity aeromagnetic survey was conducted over parts of Wilson and Karnes counties in Texas.

  4. Study of a high-resolution PET system using a silicon detector probe.

    PubMed

    Brzeziński, K; Oliver, J F; Gillam, J; Rafecas, M

    2014-10-21

    A high-resolution silicon detector probe, in coincidence with a conventional PET scanner, is expected to provide images of higher quality than those achievable using the scanner alone. Spatial resolution should improve due to the finer pixelization of the probe detector, while increased sensitivity in the probe vicinity is expected to decrease noise. A PET-probe prototype is being developed utilizing this principle. The system includes a probe consisting of ten layers of silicon detectors, each a 80 × 52 array of 1 × 1 × 1 mm(3) pixels, to be operated in coincidence with a modern clinical PET scanner. Detailed simulation studies of this system have been performed to assess the effect of the additional probe information on the quality of the reconstructed images. A grid of point sources was simulated to study the contribution of the probe to the system resolution at different locations over the field of view (FOV). A resolution phantom was used to demonstrate the effect on image resolution for two probe positions. A homogeneous source distribution with hot and cold regions was used to demonstrate that the localized improvement in resolution does not come at the expense of the overall quality of the image. Since the improvement is constrained to an area close to the probe, breast imaging is proposed as a potential application for the novel geometry. In this sense, a simplified breast phantom, adjacent to heart and torso compartments, was simulated and the effect of the probe on lesion detectability, through measurements of the local contrast recovery coefficient-to-noise ratio (CNR), was observed. The list-mode ML-EM algorithm was used for image reconstruction in all cases. As expected, the point spread function of the PET-probe system was found to be non-isotropic and vary with position, offering improvement in specific regions. Increase in resolution, of factors of up to 2, was observed in the region close to the probe. Images of the resolution phantom

  5. Study of a high-resolution PET system using a Silicon detector probe

    NASA Astrophysics Data System (ADS)

    Brzeziński, K.; Oliver, J. F.; Gillam, J.; Rafecas, M.

    2014-10-01

    A high-resolution silicon detector probe, in coincidence with a conventional PET scanner, is expected to provide images of higher quality than those achievable using the scanner alone. Spatial resolution should improve due to the finer pixelization of the probe detector, while increased sensitivity in the probe vicinity is expected to decrease noise. A PET-probe prototype is being developed utilizing this principle. The system includes a probe consisting of ten layers of silicon detectors, each a 80 × 52 array of 1 × 1 × 1 mm3 pixels, to be operated in coincidence with a modern clinical PET scanner. Detailed simulation studies of this system have been performed to assess the effect of the additional probe information on the quality of the reconstructed images. A grid of point sources was simulated to study the contribution of the probe to the system resolution at different locations over the field of view (FOV). A resolution phantom was used to demonstrate the effect on image resolution for two probe positions. A homogeneous source distribution with hot and cold regions was used to demonstrate that the localized improvement in resolution does not come at the expense of the overall quality of the image. Since the improvement is constrained to an area close to the probe, breast imaging is proposed as a potential application for the novel geometry. In this sense, a simplified breast phantom, adjacent to heart and torso compartments, was simulated and the effect of the probe on lesion detectability, through measurements of the local contrast recovery coefficient-to-noise ratio (CNR), was observed. The list-mode ML-EM algorithm was used for image reconstruction in all cases. As expected, the point spread function of the PET-probe system was found to be non-isotropic and vary with position, offering improvement in specific regions. Increase in resolution, of factors of up to 2, was observed in the region close to the probe. Images of the resolution phantom showed

  6. [Visualization of transcription complexes in spread chromatin from mammalian cells: high resolution autoradiographic study].

    PubMed

    Villard, D; Fakan, S

    1978-03-13

    RNA transcription processes were visualized within chromatin from cultured Mouse cells, spread according to Miller, and Bakken (3), by high resolution autoradiography. The cells were labelled for a short time with 3H-uridine and lysed using the detergent Nonidet P 40. Transcription complexes of both ribosomal ("Christmas tree"-like forms) and non-ribosomal types were revealed and their structure is described.

  7. Advances in high-resolution RIXS for the study of excitation spectra under high pressure

    NASA Astrophysics Data System (ADS)

    Kim, Jungho

    2016-07-01

    Hard X-ray resonant inelastic X-ray scattering (RIXS) is a promising X-ray spectroscopic tool for measuring low-energy excitation spectra from complex materials under high pressure. In the past, these measurements have been stymied by technical difficulties inherent in measuring a tiny sample, held at high pressure, inside a diamond anvil cell. Now, due to substantial advances in X-ray instrumentation, high-resolution (? meV) RIXS spectrometers at third-generation synchrotron radiation sources have started to successfully address these samples in their extreme environment. However, compared to elastic X-ray scattering and X-ray emission spectroscopy, RIXS is a very photon hungry technique and high-resolution RIXS for samples under high pressure is in its infancy. In this review, the fundamentals of the high-resolution RIXS and associated instrumentation are presented, as well as technical details of diamond anvil cells, sample preparation, and the measurement geometry. Experimental data from measurements of 3d- and 5d-transition metal oxides are shown and future improvements of the RIXS technique in the context of high pressure are discussed.

  8. Laser interstitial thermotherapy (LITT) monitoring using high-resolution digital mammography: theory and experimental studies.

    PubMed

    Minhaj, Ahmed M; Mann, Fabrice; Milne, Peter J; Denham, David B; Salas, Nelson; Nose, Izuru; Damgaard-Iversen, Karsten; Parel, Jean-Marie; Robinson, David S

    2002-08-21

    Laser interstitial thermotherapy (LITT) is a minimally-invasive laser hyperthermia procedure for the treatment of localized tumours. Real-time monitoring of LITT is essential to control the extent of tumour destruction and ensure safe and effective treatments. The feasibility of using high-resolution digital x-ray mammography to monitor LITT of breast cancer was evaluated. Tissue phantoms including polyacrylamide hydrogel and cadaver porcine tissue were heated using a 980 nm diode laser delivered through optical fibres with diffusing tips. Digital images of the tissue phantoms were recorded with a high-resolution digital stereotactic breast biopsy system during heating. The recorded images were processed and analysed to detect heat-induced changes. No changes were detected during heating of the hydrogel. Pixel-by-pixel subtraction of the initial image from images taken during laser heating shows observable thermally-induced changes around the fibre during laser irradiation that correlate with the thermal denaturation zone observed by gross anatomy. These experiments demonstrate that high-resolution digital x-ray mammography can be used to detect heat-induced tissue changes during experimental LITT in fibro-fatty tissue.

  9. First far-infrared high resolution analysis of the ν3 band of phosgene 35Cl2CO and 35Cl37ClCO

    NASA Astrophysics Data System (ADS)

    Ndao, M.; Perrin, A.; Kwabia Tchana, F.; Manceron, L.; Flaud, J. M.

    2016-08-01

    The high-resolution absorption spectra of phosgene (Cl2CO) has been recorded at 0.001 cm-1 resolution in the 250-350 cm-1 region by Fourier transform spectroscopy at synchrotron SOLEIL. To reduce the spectral congestion, the spectra have been recorded at low temperature (197 K) using a 93.14 m optical path length cryogenic cell. This enables the first detailed infrared analysis of the ν3 bands of the 35Cl2CO and 35Cl37ClCO isotopologues of phosgene. Using a Watson-type Hamiltonian, it was possible to reproduce the upper state rovibrational infrared energy levels, together with, for 35Cl2CO, the available microwave data in the 31 excited state (Yamamoto et al. 1984) to within their experimental accuracy. In this way, accurate rotational and centrifugal distortion constants together with the following band centers: ν0(ν3, 35Cl2CO) = 301.545622(17) cm-1 and ν0(ν3, 35Cl37ClCO) = 298.199194(81) cm-1, were derived for the ν3 bands of 35Cl2CO and 35Cl37ClCO.

  10. The high-resolution infrared spectrum of DC4H from 450 to 1100 cm-1: Overtone, combination, and hot bands

    NASA Astrophysics Data System (ADS)

    Bizzocchi, L.; Tamassia, F.; Esposti, C. Degli; Dore, L.; Fusina, L.; Villa, M.; Canè, E.

    2013-10-01

    The high-resolution infrared spectrum of monodeuterated diacetylene has been recorded in the 450-1100 cm-1 spectral region by Fourier transform infrared spectroscopy. Seven new bands have been identified: the ν3 fundamental (C-C stretch), and the ν8 + ν9, ν7 + ν8, 2ν7, 2ν8, ν8 + ν9 - ν9, and ν6 + ν9 - ν9 combination, overtone, and hot bands. The assigned transitions, together with those previously reported for the fundamental bands [F. Tamassia, L. Bizzocchi, C. Degli Esposti, L. Dore, M. Di Lauro, L. Fusina, M. Villa, and E. Canè, Astron. Astrophys. 549, A38 (2013)], form a comprehensive data set which comprises more than 2500 ro-vibrational transitions, and involves all singly and most doubly excited vibrational states of DC4H lying below 1000 cm-1. Rotational and vibrational l-type resonance effects among the sub-levels of excited bending states were considered in the analysis, which also included a careful treatment of the various anharmonic interactions coupling many vibrational states lying above 600 cm-1. Reliable and unambiguous spectroscopic parameters were obtained for each investigated state, including the rotational and centrifugal distortion constants Bv and Dv, the l-type doubling parameter qt, the anharmonicity constants xL(89), xL(69), and the vibrational l-type terms r89, r69 for the v8 = v9 = 1 and v6 = v9 = 1 bend-bend combination states.

  11. A high-resolution atlas of the infrared spectrum of the Sun and the Earth atmosphere from space. Volume 3: Key to identification of solar features

    NASA Technical Reports Server (NTRS)

    Geller, Murray

    1992-01-01

    During the period April 29 through May 2, 1985, the Atmospheric Trace Molecule Spectroscopy (ATMOS) experiment was operated as part of the Spacelab-3 (SL-3) payload on the shuttle Challenger. The instrument, a Fourier transform spectrometer, recorded over 2000 infrared solar spectra from an altitude of 360 km. Although the majority of the spectra were taken through the limb of the Earth's atmosphere in order to better understand its composition, several hundred of the 'high-sun' spectra were completely free from telluric absorption. These high-sun spectra recorded from space are, at the present time, the only high-resolution infrared spectra ever taken of the Sun free from absorptions due to constituents in the Earth's atmosphere. Volumes 1 and 2 of this series provide a compilation of these spectra arranged in a format suitable for quick-look reference purposes and are the first record of the continuous high-resolution infrared spectrum of the Sun and the Earth's atmosphere from space. In the Table of Identifications, which constitutes the main body of this volume, each block of eight wavenumbers is given a separate heading and corresponds to a page of two panels in Volume 1 of this series. In addition, three separate blocks of data available from ATMOS from 622-630 cm(exp -1), 630-638 cm(exp -1) and 638-646 cm(exp -1), excluded from Volume 1 because of the low signal-to-noise ratio, have been included due to the certain identification of several OH and NH transitions. In the first column of the table, the corrected frequency is given. The second column identifies the molecular species. The third and fourth columns represent the assigned transition. The fifth column gives the depth of the molecular line in millimeters. Also included in this column is a notation to indicate whether the line is a blend or lies on the shoulder(s) of another line(s). The final column repeats a question mark if the line is unidentified.

  12. Aerosol Composition in the Los Angeles Basin Studied by High Resolution Aerosol Mass Spectrometry

    NASA Astrophysics Data System (ADS)

    Hayes, P. L.; Ortega, A. M.; Cubison, M.; Hu, W.; Toohey, D. W.; Flynn, J. H.; Grossberg, N.; Lefer, B. L.; Alvarez, S. L.; Rappenglueck, B.; Allan, J. D.; Taylor, J.; Holloway, J. S.; Gilman, J. B.; Kuster, W. C.; De Gouw, J. A.; Massoli, P.; Zhang, X.; Weber, R.; Zhao, Y.; Cliff, S. S.; Wexler, A. S.; Isaacman, G. A.; Worton, D. R.; Kreisberg, N. M.; Hering, S. V.; Goldstein, A. H.; Jimenez, J. L.

    2011-12-01

    Atmospheric aerosols impact climate and health, but their sources and composition are poorly understood. To address this knowledge gap, a high-resolution aerosol mass spectrometer (AMS) and complementary instrumentation were deployed during the 2010 CalNex campaign to characterize aerosol composition in the Los Angeles (LA) area. Total mass concentrations as well as the species concentrations measured by the AMS compare well with most other instruments. Nitrate dominates in the mornings, but its concentration is reduced in the afternoon when organic aerosols (OA) increase and dominate. The diurnal variations in concentrations are strongly influenced by emission transport from the source-rich western basin. The average OA to enhanced CO ratio increases with photochemical age from 25 to 80 μg m-3 ppm-1, which indicates significant secondary OA (SOA) production and that a large majority of OA is secondary in aged air. The ratio values are similar to those from Mexico City as well as New England and the Mid-Atlantic States. Positive matrix factorization (PMF) is used to assess the concentrations of different OA components. The major OA classes are oxygenated OA (OOA, a surrogate for total SOA), and hydrocarbon-like OA (HOA, a surrogate for primary combustion OA). Several subclasses of OA are identified as well including diesel-influenced HOA (DI-HOA) and non-diesel HOA. DI-HOA exhibits low concentrations on Sundays consistent with the well-known weekday/weekend effect in LA. PMF analysis finds that OOA is 67% of the total OA concentration. A strong correlation between OOA and Ox (O3 + NO2) concentrations is observed with a slope of 0.15 that suggests the production of fresh SOA in Pasadena. Plotting the OA elemental ratios in a Van Krevelen diagram (H:C vs. O:C) yields a slope of -0.6, which is less steep than that observed in Riverside during the SOAR-2005 campaign. The difference in slopes may be attributed to the highly oxidized HOA present in Pasadena that is

  13. High Resolution Environmental Magnetic Study of a Holocene Sedimentary Record from Zaca Lake, Ca

    NASA Astrophysics Data System (ADS)

    Platzman, E. S.; Lund, S.; Kirby, M. E.; Feakins, S. J.

    2012-12-01

    Magnetic studies of Holocene lake sediments recovered from Zaca lake have yielded a 3000-year high resolution record of environmental variability and paleolimnology. Zaca lake is a small oligomictic lake ~12m deep situated 730 m above sea level in the steep canyons of the San Rafael mountains, NW of Santa Barbara. Throughout much of the year Zaca lake is anaerobic below 7m. Hydrogen sulfide, fed into the lake via runoff and local sulphur springs, is present throughout the hypolimnion with concentrations sometime exceeding 30 mg/ l. During the summer months when the lake is stratified, light colored carbonate rich microlaminae are formed; and often during the winter months when the lake overturns, killing the anaerobic bacteria, black microlamina rich in iron sulfide are deposited on the lake floor, creating a stratigraphy reflecting patterns of environmental variability on annual to millennial scales. Samples for magnetic analysis were obtained from 8.5 m of core recovered from the central region of Zaca lake. Ages, constrained using radiocarbon chronostratigraphy, yielded sedimentation rates of 2-10 mm/yr with an average rate of 3 mm per yr over the 3000 yr interval. Parameters reflecting decadal scale variability in magnetic concentration (susceptibility, ARM, SIRM) and grainsize (ARM/Chi) were measured every 2 cm. Additional rock magnetic tests, including thermal demagnetization of three component IRM, were applied at selected intervals to constrain the magnetic mineralogy. These data were combined with analyses of clastic grain size, % calcium carbonate and % organics to create a multiproxy record of environmental variability. Results show that Zaca lake has had a complex depositional history. Anthropogenic effects associated with European colonization are present in the upper meters. Most notable, however, is a dramatic shift in the magnetic parameters and mineralogy between the upper and lower half of the core (circa 1300 ybp) indicating a shift in regime

  14. The critical need for moderate to high resolution thermal infrared data for volcanic hazard mitigation and process monitoring from the micron to the kilometer scale

    NASA Astrophysics Data System (ADS)

    Ramsey, M. S.

    2006-12-01

    thermally-elevated pixels (max = 25.9 C) clustered near the summit with a lesser anomaly (max = 15.5 C) approximately 650 m to the southwest and down slope from the summit. Such small-scale and low-grade thermal features confirmed the increased activity state of the volcano and were only made possible with the moderate spatial, spectral, and radiometric resolution of ASTER. ASTER continued to collect data for the next 12 weeks tracking the progress of large scale pyroclastic flows, the growth of the lava dome, and the path of ash-rich plumes. Data from these observations were reported world-wide and used for evacuation and hazard planning purposes. With the pending demise of such TIR data from orbit, research is also focused on the use of handheld TIR instruments such as the forward-looking infrared radiometer (FLIR) camera. These instruments provide the highest spatial resolution in-situ TIR data and have been used to observe numerous volcanic phenomena and quantitatively model others (e.g., the rise of the magma body preceding the eruption of Mt. St. Helens Volcano; the changes on the lava dome at Bezymianny Volcano; the behavior of basalt crusts during pahoehoe flow inflation). Studies such as these confirm the utility and importance of future moderate to high resolution TIR data in order to understand volcanic processes and their accompanying hazards.

  15. Applications of very high-resolution imagery in the study and conservation of large predators in the Southern Ocean.

    PubMed

    Larue, Michelle A; Knight, Joseph

    2014-12-01

    The Southern Ocean is one of the most rapidly changing ecosystems on the planet due to the effects of climate change and commercial fishing for ecologically important krill and fish. Because sea ice loss is expected to be accompanied by declines in krill and fish predators, decoupling the effects of climate and anthropogenic changes on these predator populations is crucial for ecosystem-based management of the Southern Ocean. We reviewed research published from 2007 to 2014 that incorporated very high-resolution satellite imagery to assess distribution, abundance, and effects of climate and other anthropogenic changes on populations of predators in polar regions. Very high-resolution imagery has been used to study 7 species of polar animals in 13 papers, many of which provide methods through which further research can be conducted. Use of very high-resolution imagery in the Southern Ocean can provide a broader understanding of climate and anthropogenic forces on populations and inform management and conservation recommendations. We recommend that conservation biologists continue to integrate high-resolution remote sensing into broad-scale biodiversity and population studies in remote areas, where it can provide much needed detail.

  16. Applications of very high-resolution imagery in the study and conservation of large predators in the Southern Ocean.

    PubMed

    Larue, Michelle A; Knight, Joseph

    2014-12-01

    The Southern Ocean is one of the most rapidly changing ecosystems on the planet due to the effects of climate change and commercial fishing for ecologically important krill and fish. Because sea ice loss is expected to be accompanied by declines in krill and fish predators, decoupling the effects of climate and anthropogenic changes on these predator populations is crucial for ecosystem-based management of the Southern Ocean. We reviewed research published from 2007 to 2014 that incorporated very high-resolution satellite imagery to assess distribution, abundance, and effects of climate and other anthropogenic changes on populations of predators in polar regions. Very high-resolution imagery has been used to study 7 species of polar animals in 13 papers, many of which provide methods through which further research can be conducted. Use of very high-resolution imagery in the Southern Ocean can provide a broader understanding of climate and anthropogenic forces on populations and inform management and conservation recommendations. We recommend that conservation biologists continue to integrate high-resolution remote sensing into broad-scale biodiversity and population studies in remote areas, where it can provide much needed detail. PMID:25103277

  17. Deriving the Extinction to Young Stellar Objects using [Fe II] Near-infrared Emission Lines: Prescriptions from GIANO High-resolution Spectra

    NASA Astrophysics Data System (ADS)

    Pecchioli, T.; Sanna, N.; Massi, F.; Oliva, E.

    2016-07-01

    The near-infrared (NIR) emission lines of Fe+ at 1.257, 1.321, and 1.644 μm share the same upper level; their ratios can then be exploited to derive the extinction to a line emitting region once the relevant spontaneous emission coefficients are known. This is commonly done, normally from low-resolution spectra, in observations of shocked gas from jets driven by Young Stellar Objects. In this paper we review this method, provide the relevant equations, and test it by analyzing high-resolution (R ∼ 50,000) NIR spectra of two young stars, namely the Herbig Be star HD 200775 and the Be star V1478 Cyg, which exhibit intense emission lines. The spectra were obtained with the new GIANO echelle spectrograph at the Telescopio Nazionale Galileo. Notably, the high-resolution spectra allowed checking the effects of overlapping telluric absorption lines. A set of various determinations of the Einstein coefficients are compared to show how much the available computations affect extinction derivation. The most recently obtained values are probably good enough to allow reddening determination within 1 visual mag of accuracy. Furthermore, we show that [Fe ii] line ratios from low-resolution pure emission-line spectra in general are likely to be in error due to the impossibility to properly account for telluric absorption lines. If low-resolution spectra are used for reddening determinations, we advice that the ratio 1.644/1.257, rather than 1.644/1.321, should be used, being less affected by the effects of telluric absorption lines.

  18. Nitrosyl iodide, INO: A combined ab initio and high-resolution spectroscopic study

    NASA Astrophysics Data System (ADS)

    Bailleux, S.; Duflot, D.; Aiba, S.; Nakahama, S.; Ozeki, H.

    2016-04-01

    In the nitrosyl halides series (XNO, where X = F, Cl, Br, I), INO is the only chemical species whose rotational spectrum has not been reported. Nitrosyl iodide, together with the nitryl (INO2), nitrite (IONO) and nitrate (IONO2) iodides, is believed to impact tropospheric ozone levels. Guided by our quantum chemical calculations, we report the detection of INO in the gas phase by high-resolution spectroscopy for the first time. INO was generated by mixing continuously I2 and NO. The measurement and least-squares analysis of 173 a-type rotational transitions resulted in the accurate determination of molecular parameters.

  19. High-resolution PET (positron emission tomography) for medical science studies

    SciTech Connect

    Budinger, T.F.; Derenzo, S.E.; Huesman, R.H.; Jagust, W.J.; Valk, P.E. )

    1989-09-01

    One of the unexpected fruits of basic physics research and the computer revolution is the noninvasive imaging power available to today's physician. Technologies that were strictly the province of research scientists only a decade or two ago now serve as the foundations for such standard diagnostic tools as x-ray computer tomography (CT), magnetic resonance imaging (MRI), magnetic resonance spectroscopy (MRS), ultrasound, single photon emission computed tomography (SPECT), and positron emission tomography (PET). Furthermore, prompted by the needs of both the practicing physician and the clinical researcher, efforts to improve these technologies continue. This booklet endeavors to describe the advantages of achieving high resolution in PET imaging. 6 refs., 21 figs.

  20. High-resolution PET [Positron Emission Tomography] for Medical Science Studies

    DOE R&D Accomplishments Database

    Budinger, T. F.; Derenzo, S. E.; Huesman, R. H.; Jagust, W. J.; Valk, P. E.

    1989-09-01

    One of the unexpected fruits of basic physics research and the computer revolution is the noninvasive imaging power available to today's physician. Technologies that were strictly the province of research scientists only a decade or two ago now serve as the foundations for such standard diagnostic tools as x-ray computer tomography (CT), magnetic resonance imaging (MRI), magnetic resonance spectroscopy (MRS), ultrasound, single photon emission computed tomography (SPECT), and positron emission tomography (PET). Furthermore, prompted by the needs of both the practicing physician and the clinical researcher, efforts to improve these technologies continue. This booklet endeavors to describe the advantages of achieving high resolution in PET imaging.

  1. High-resolution synchrotron infrared spectroscopy of acrolein: The vibrational levels between 850 and 1020 cm-1

    NASA Astrophysics Data System (ADS)

    McKellar, A. R. W.; Billinghurst, B. E.; Xu, Li-Hong; Lees, R. M.

    2015-11-01

    Using spectra obtained at the Canadian Light Source synchrotron radiation facility, a previously unobserved out-of-plane vibration of trans-acrolein (propenal) is reliably assigned for the first time. Its origin is at 1002.01 cm-1, which is about 20 cm-1 higher than usually quoted in the past. This mode is thus labelled as v14, leaving the label v15 for the known vibration at 992.66 cm-1. Weak combination bands 171182 ← 182, 171131 ← 131, 121182 ← 181, and 171182 ← 181 are studied for the first time, and assignments in the known v11, v16, and v15 fundamental bands are also extended. The seven excited vibrations involved in these bands are analyzed, together with five more unobserved vibrations in the same region (850-1020 cm-1), in a large 12-state simultaneous fit which accounts for most of the many observed perturbations in the spectra.

  2. Measurement of HO2 and other trace gases in the stratosphere using a high resolution far-infrared spectrometer

    NASA Technical Reports Server (NTRS)

    Traub, Wesley A.; Chance, Kelly V.; Johnson, David G.; Jucks, Kenneth W.; Salawitch, Ross J.; Xue, Jim Changqin; Ciarpallini, Paola

    1995-01-01

    This report covers the time period 1 January 1994 to 31 December 1994. During this reporting period we had our fourth Upper Atmosphere Research Satellite (UARS) correlative balloon flight; the data from this flight have been reduced and submitted to the UARS CDHF. We have spent most of the past year analyzing data from this and past flights. For example, using data from our September 1989 balloon flight we have demonstrated for the first time ever that the rates of production and loss of ozone are in balance in the upper stratosphere. As part of this analysis, we have completed the most detailed study to date of radical partitioning throughout the stratosphere. We have also produced the first measurement of HBr and HOBr mixing ratio profiles over a full diurnal cycle.

  3. Suomi NPP/JPSS Cross-track Infrared Sounder (CrIS): Calibration Validation With The Aircraft Based Scanning High-resolution Interferometer Sounder (S-HIS)

    NASA Astrophysics Data System (ADS)

    Taylor, J. K.; Revercomb, H. E.; Tobin, D.; Knuteson, R. O.; Best, F. A.; Adler, D. A.; Pettersen, C.; Garcia, R. K.; Gero, P.

    2013-12-01

    To better accommodate climate change monitoring and improved weather forecasting, there is an established need for higher accuracy and more refined error characterization of radiance measurements from space and the corresponding geophysical products. This need has led to emphasizing direct tests of on-orbit performance, referred to as validation. Currently, validation typically involves (1) collecting high quality reference data from airborne and/or ground-based instruments during the satellite overpass, and (2) a detailed comparison between the satellite-based radiance measurements and the corresponding high quality reference data. Additionally, for future missions technology advancements at the University of Wisconsin Space Science and Engineering Center (UW-SSEC) have led to the development of an on-orbit absolute radiance reference utilizing miniature phase change cells to provide direct on-orbit traceability to International Standards (SI). The detailed comparison between the satellite-based radiance measurements and the corresponding measurements made from a high-altitude aircraft must account for instrument noise and scene variations, as well as differences in instrument observation altitudes, view angles, spatial footprints, and spectral response. Most importantly, for the calibration validation process to be both accurate and repeatable the reference data instrument must be extremely well characterized and understood, carefully maintained, and accurately calibrated, with traceability to absolute standards. The Scanning High-resolution Interferometer Sounder (S-HIS) meets and exceeds these requirements and has proven to do so on multiple airborne platforms, each with significantly different instrument operating environments. The Cross-track Infrared Sounder (CrIS) on Suomi NPP, launched 28 October 2011, is designed to give scientists more refined information about Earth's atmosphere and improve weather forecasts and our understanding of climate. CrIS is an

  4. A High-Resolution, Multi-Proxy Palaeoclimate Study of the Central Northern Mediterranean

    NASA Astrophysics Data System (ADS)

    Horsfield, T. E.; Rogerson, M.; Henderson, G. M.; Rohling, E. J.; Mihevc, A.; Budja, M.; Prelovsek, M.; Coulthard, T. J.; Greenway, G. M.

    2012-04-01

    Two stalagmites, SLO-1 and SLO-2, collected from Postojna cave, Slovenia show very high growth rates (~0.28mmyr-1), and grew to impressive lengths - SLO-1 measures 2.2m (2200mm) and SLO-2 measures 1.38m (1380mm). This record is constrained by U-Th and α-mass spectrometry dates collected on both stalagmites, indicating growth between 16 and 0.6ka BP. Together, these samples provide a potentially exceptionally complete and high-resolution record of climate in the central northern Mediterranean for the Holocene. Moreover, within these stalagmites, there is an overlapping period between ~4.5 and ~9.1ka which allows cross-validation of two records. Stable isotope data collected to date form a continuous, 1-mm resolved record for the upper 554mm of SLO-2, resulting in a record covering ~1.5ka, from ~0.6ka BP to ~2.1ka BP and a series of "Hendy tests", which indicate that kinetic fractionation has been small. The stable isotope data spans the Medieval Warm Period and Dark Ages Cool Period and shows a marked cyclic variability probably reflecting the balance of winter and summer precipitation. Regionally cooler periods show typically isotopically negative (winter-like) δ18Ocalcite values, whereas regionally warm periods show relatively positive (summer-like) values. High temperature fluctuations between summer and winter in Slovenia result in large (~6) variations in δ18Oprecipitation. Such a dramatic shift between winter and summer precipitation makes changes in winter/summer balance more noticeable in these samples than in other areas. Shorter scale variability is also prevalent, especially when longer term variations have been removed by detrending. This is in spite of the aquifer feeding the stalagmites being well-mixed, which would ordinarily hinder finer resolution records. This may be due to an influence of cave ventilation affecting the fractionation of isotopes once the drip has entered the cave. The climate record is in good agreement with known climate

  5. High Resolution Angle Resolved Photoemission Studies on Quasi-Particle Dynamics in Graphite

    SciTech Connect

    Leem, C.S.

    2010-06-02

    We obtained the spectral function of the graphite H point using high resolution angle resolved photoelectron spectroscopy (ARPES). The extracted width of the spectral function (inverse of the photo-hole lifetime) near the H point is approximately proportional to the energy as expected from the linearly increasing density of states (DOS) near the Fermi energy. This is well accounted by our electron-phonon coupling theory considering the peculiar electronic DOS near the Fermi level. And we also investigated the temperature dependence of the peak widths both experimentally and theoretically. The upper bound for the electron-phonon coupling parameter is 0.23, nearly the same value as previously reported at the K point. Our analysis of temperature dependent ARPES data at K shows that the energy of phonon mode of graphite has much higher energy scale than 125K which is dominant in electron-phonon coupling.

  6. A high resolution spectroscopic study of the oxygen molecule. Ph.D. Thesis Final Report

    NASA Technical Reports Server (NTRS)

    Ritter, K. J.

    1984-01-01

    A high resolution spectrometer which incorporates a narrow line width tunable dye laser was used to make absorption profiles of 57 spectral lines in the Oxygen A-Band at pressures up to one atmosphere in pure O2. The observed line profiles are compared to the Voigt, and a collisionally narrowed, profile using a least squares fitting procedure. The collisionally narrowed profile compares more favorable to the observed profiles. Values of the line strengths and self broadening coeffiencients, determined from the least square fitting process, are presented in tabular form. It is found that the experssion by Watson are in closest agreement with the experimentally determined strengths. The self broadening coefficients are compared with the measurements of several other investigators.

  7. High-resolution studies on late-replicating segments (G + C bands) in mammalian chromosomes.

    PubMed

    Iannuzzi, L; Gustavsson, I; Di Meo, G P; Ferrara, L

    1989-01-01

    High resolution of late-replicating segments (G + C bands) in chromosomes of human, cattle and water buffalo was obtained by using 5-bromodeoxyuridine incorporation early in the cell cycle, simultaneous with methotrexate treatment combined with reduced colcemid treatment and addition of ethidium bromide, which increased the proportion of prometaphase cells. Giemsa counterstaining, following fluorescence microscopy observation and treatment with 2 x SSC, improved the resolution of the banding patterns, particularly in the pericentromeric regions. Acrocentric bovine and water buffalo chromosomes, which were seen to be C-positive by fluorescence microscopy observation and C-negative after counterstaining, showed the presence of subcentromeric G-positive bands within the heterochromatic blocks of several chromosomes.

  8. Performance of the Apache Point Observatory Galactic Evolution Experiment (APOGEE) high-resolution near-infrared multi-object fiber spectrograph

    NASA Astrophysics Data System (ADS)

    Wilson, John C.; Hearty, F.; Skrutskie, M. F.; Majewski, S. R.; Schiavon, R.; Eisenstein, D.; Gunn, J.; Holtzman, J.; Nidever, D.; Gillespie, B.; Weinberg, D.; Blank, B.; Henderson, C.; Smee, S.; Barkhouser, R.; Harding, A.; Hope, S.; Fitzgerald, G.; Stolberg, T.; Arns, J.; Nelson, M.; Brunner, S.; Burton, A.; Walker, E.; Lam, C.; Maseman, P.; Barr, J.; Leger, F.; Carey, L.; MacDonald, N.; Ebelke, G.; Beland, S.; Horne, T.; Young, E.; Rieke, G.; Rieke, M.; O'Brien, T.; Crane, J.; Carr, M.; Harrison, C.; Stoll, R.; Vernieri, M.; Shetrone, M.; Allende-Prieto, C.; Johnson, J.; Frinchaboy, P.; Zasowski, G.; Garcia Perez, A.; Bizyaev, D.; Cunha, K.; Smith, V. V.; Meszaros, Sz.; Zhao, B.; Hayden, M.; Chojnowski, S. D.; Andrews, B.; Loomis, C.; Owen, R.; Klaene, M.; Brinkmann, J.; Stauffer, F.; Long, D.; Jordan, W.; Holder, D.; Cope, F.; Naugle, T.; Pfaffenberger, B.; Schlegel, D.; Blanton, M.; Muna, D.; Weaver, B.; Snedden, S.; Pan, K.; Brewington, H.; Malanushenko, E.; Malanushenko, V.; Simmons, A.; Oravetz, D.; Mahadevan, S.; Halverson, S.

    2012-09-01

    The Apache Point Observatory Galactic Evolution Experiment (APOGEE) uses a dedicated 300-fiber, narrow-band near-infrared (1.51-1.7 μm), high resolution (R~22,500) spectrograph to survey approximately 100,000 giant stars across the Milky Way. This three-year survey, in operation since late-summer 2011 as part of the Sloan Digital Sky Survey III (SDSS III), will revolutionize our understanding of the kinematical and chemical enrichment histories of all Galactic stellar populations. We present the performance of the instrument from its first year in operation. The instrument is housed in a separate building adjacent to the 2.5-m SDSS telescope and fed light via approximately 45-meter fiber runs from the telescope. The instrument design includes numerous innovations including a gang connector that allows simultaneous connection of all fibers with a single plug to a telescope cartridge that positions the fibers on the sky, numerous places in the fiber train in which focal ratio degradation had to be minimized, a large mosaic-VPH (290 mm x 475 mm elliptically-shaped recorded area), an f/1.4 six-element refractive camera featuring silicon and fused silica elements with diameters as large as 393 mm, three near-infrared detectors mounted in a 1 x 3 mosaic with sub-pixel translation capability, and all of these components housed within a custom, LN2-cooled, stainless steel vacuum cryostat with dimensions 1.4-m x 2.3-m x 1.3-m.

  9. Mapping bare soil in South West Wales, UK, using high resolution colour infra-red aerial photography for water quality and flood risk management applications

    NASA Astrophysics Data System (ADS)

    Sykes, Helena; Neale, Simon; Coe, Sarah

    2016-04-01

    Natural Resources Wales is a UK government body responsible for environmental regulation, among other areas. River walks in Water Framework Directive (WFD) priority catchments in South West Wales, UK, identified soil entering water courses due to poaching and bank erosion, leading to deterioration in the water quality and jeopardising the water quality meeting legal minimum standards. Bare soil has also been shown to cause quicker and higher hydrograph peaks in rural catchments than if those areas were vegetated, which can lead to flooding of domestic properties during peak storm flows. The aim was to target farm visits by operational staff to advise on practices likely to improve water quality and to identify areas where soft engineering solutions such as revegetation could alleviate flood risk in rural areas. High resolution colour-infrared aerial photography, 25cm in the three colour bands and 50cm in the near infrared band, was used to map bare soil in seven catchments using supervised classification of a five band stack including the Normalised Difference Vegetation Index (NDVI). Mapping was combined with agricultural land use and field boundary data to filter out arable fields, which are supposed to bare soil for part of their cycle, and was very successful when compared to ground truthing, with the exception of silage fields which contained sparse, no or unproductive vegetation at the time the imagery was acquired leading to spectral similarity to bare soil. A raindrop trace model was used to show the path sediment from bare soil areas would take when moving through the catchment to a watercourse, with hedgerows inserted as barriers following our observations from ground truthing. The findings have been used to help farmers gain funding for improvements such as fencing to keep animals away from vulnerable river banks. These efficient and automated methods can be rolled out to more catchments in Wales and updated using aerial imagery acquired more recently to

  10. Rotational Analysis of Bands in the High-Resolution Infrared Spectra of cis,cis- and trans,trans-1,4-difluorobutadiene-2-d1

    SciTech Connect

    Craig, Norman C.; Easterday, Clay C.; Nemchick, Deacon J.; Williamson, Drew; Sams, Robert L.

    2012-02-01

    Pure samples of cis,cis- and trans,trans-1,4-difluorobutadiene-2-d1 have been synthesized, and high-resolution (0.0015 cm-1) infrared spectra have been recorded for these nonpolar molecules in the gas phase. For the cis,cis isomer, the rotational structure in two C-type bands at 775 and 666 cm-1 and one A-type band at 866 cm-1 has been analyzed to yield a combined set of 2020 ground state combination differences (GSCDs). Ground state rotational constants fit to these GSCDs are A0 = 0.4195790(4), B0 = 0.0536508(8), and C0 = 0.0475802(9) cm-1. For the trans,trans isomer, three Ctype bands at 856, 839, and 709 cm-1 have been investigated to give a combined set of 1624 GSCDs. Resulting ground state rotational constants for this isomer are A0 = 0.9390117(8), B0 = 0.0389225(4), and C0 = 0.0373778(3) cm-1. Small inertial defects confirm the planarity of both isomers in the ground state. Upper state rotational constants have been determined for most of the transitions. The ground state rotational constants for the two isotopologues will contribute to the data set needed for determining semiexperimental equilibrium structures for the nonpolar isomers of 1,4- difluorobutadiene.

  11. Improving surface-subsurface water budgeting for Brownfield study sites using high resolution satellite imagery

    NASA Astrophysics Data System (ADS)

    Dujardin, J.; Boel, S.; Anibas, C.; Batelaan, O.; Canters, F.

    2009-04-01

    Countries around the world have problems with contaminated brownfield sites as resulting from a relatively anarchic economical and industrial development during the 19th and 20th centuries. Since a few decades policy makers and stakeholders have become more aware of the risk posed by these sites because some of these sites present direct public hazards. Water is often the main vector of the mobility of contaminants. In order to propose remediation measures for the contaminated sites, it is required to describe and to quantify as accurately as possible the surface and subsurface water fluxes in the polluted site. In this research a modelling approach with integrated remote sensing analysis has been developed for accurately calculating water and contaminant fluxes on the polluted sites. Groundwater pollution in urban environments is linked to patterns of land use, so to identify the sources of contamination with great accuracy in urban environments it is essential to characterize the land cover in a detailed way. The use of high resolution spatial information is required because of the complexity of the urban land use. An object-oriented classification approach applied on high resolution satellite data has been adopted. Cluster separability analysis and visual interpretation of the image objects belonging to each cluster resulted in the selection of 8 land-cover categories (water, bare soil, meadow, mixed forest, grey urban surfaces, red roofs, bright roofs and shadow).To assign the image objects to one of the 8 selected classes a multiple layer perceptron (MLP) approach was adopted, using the NeuralWorks Predict software. After a post-classification shadow removal and a rule-based classification enhancement a kappa-value of 0.86 was obtained. Once the land cover was characterized, the groundwater recharge has been simulated using the spatially distributed WetSpass model and the subsurface water flow was simulated with GMS 6.0 in order to identify and budget the

  12. A high-resolution coherent transition radiation diagnostic for laser-produced electron transport studies (invited)

    SciTech Connect

    Storm, M.; Begishev, I. A.; Brown, R. J.; Mileham, C.; Myatt, J. F.; Nilson, P. M.; Sangster, T. C.; Stoeckl, C.; Theobald, W.; Zuegel, J. D.; Guo, C.; Meyerhofer, D. D.

    2008-10-15

    High-resolution images of the rear-surface optical emission from high-intensity (I{approx}10{sup 19} W/cm{sup 2}) laser illuminated metal foils have been recorded using coherent transition radiation (CTR). CTR is generated as relativistic electrons, generated in high-intensity laser-plasma interactions, exit the target's rear surface and move into vacuum. A transition radiation diagnostic (TRD) records time-integrated images in a 24 nm bandwidth window around {lambda}=529 nm. The optical transmission at {lambda}=1053 nm, the laser wavelength, is 15 orders of magnitude lower than the transmission at the wavelength of interest, {lambda}=527 nm. The detector is a scientific grade charge-coupled device (CCD) camera that operates with a signal-to-noise ratio of 10{sup 3} and has a dynamic range of 10{sup 4}. The TRD has demonstrated a spatial resolution of 1.4 {mu}m over a 1 mm field of view, limited only by the CCD pixel size.

  13. Advances in high-resolution mass spectrometry based on metabolomics studies for food--a review.

    PubMed

    Rubert, Josep; Zachariasova, Milena; Hajslova, Jana

    2015-01-01

    Food authenticity becomes a necessity for global food policies, since food placed in the market without fail has to be authentic. It has always been a challenge, since in the past minor components, called also markers, have been mainly monitored by chromatographic methods in order to authenticate the food. Nevertheless, nowadays, advanced analytical methods have allowed food fingerprints to be achieved. At the same time they have been also combined with chemometrics, which uses statistical methods in order to verify food and to provide maximum information by analysing chemical data. These sophisticated methods based on different separation techniques or stand alone have been recently coupled to high-resolution mass spectrometry (HRMS) in order to verify the authenticity of food. The new generation of HRMS detectors have experienced significant advances in resolving power, sensitivity, robustness, extended dynamic range, easier mass calibration and tandem mass capabilities, making HRMS more attractive and useful to the food metabolomics community, therefore becoming a reliable tool for food authenticity. The purpose of this review is to summarise and describe the most recent metabolomics approaches in the area of food metabolomics, and to discuss the strengths and drawbacks of the HRMS analytical platforms combined with chemometrics.

  14. Intensity and phase fields behind phase-shifting masks studied with high-resolution interference microscopy

    NASA Astrophysics Data System (ADS)

    Puthankovilakam, Krishnaparvathy; Scharf, Toralf; Kim, Myun Sik; Naqavi, Ali; Herzig, Hans Peter; Weichelt, Tina; Zeitner, Uwe; Vogler, Uwe; Voelkel, Reinhard

    2016-04-01

    We try to find out the details of how light fields behind the structures of photomasks develop in order to determine the best conditions and designs for proximity printing. The parameters that we use approach real situations like structure printing at proximity gaps of 20 to 50 μm and structure sizes down to 2 μm. This is the first time that an experimental analysis of light propagation through a mask is presented in detail, which includes information on intensity and phase. We use high-resolution interference microscopy (HRIM) for the measurement. HRIM is a Mach-Zehnder interferometer, which is capable of recording three-dimensional distributions of intensity and phase with diffraction-limited resolution. Our characterization technique allows plotting the evolution of the desired light field, usually called the aerial image, and therefore gives access to the printable structure until the desired proximity gap. Here, we discuss in detail the evolution of intensity and phase fields of elbow or corner structures at different positions behind a phase mask and interpret the main parameters. Of particular interest are tolerances against proximity gap variation and the theoretical explanation of the resolution in printed structures.

  15. [Design and study of a high resolution vacuum ultraviolet imaging spectrometer carried by satellite].

    PubMed

    Yu, Lei; Lin, Guan-yu; Qu, Yi; Wang, Shu-rong; Wang, Long-qi

    2011-12-01

    A high resolution vacuum ultraviolet imaging spectrometer prototype carried by satellite applied to the atmosphere detection of particles distribution in 115-300 nm was developed for remote sensing. First, based on the analysis of advanced loads, the optical system including an off-axis parabolic mirror as the telescope and Czerny-Turner structure as the imaging spectrometer was chosen Secondly, the 2-D photon counting detector with MCP was adopted for the characteristic that the radiation is weak in vacuum ultraviolet waveband. Then the geometric method and 1st order differential calculation were introduced to improve the disadvantages that aberrations in the traditional structure can not be corrected homogeneously to achieve perfect broadband imaging based on the aberration theory. At last, an advanced example was designed. The simulation and calculation of results demonstrate that the modulation transfer function (MTF) of total field of view is more than 0.6 in the broadband, and the spectral resolution is 1.23 nm. The structure is convenient and predominant. It proves that the design is feasible.

  16. Advances in high-resolution mass spectrometry based on metabolomics studies for food--a review.

    PubMed

    Rubert, Josep; Zachariasova, Milena; Hajslova, Jana

    2015-01-01

    Food authenticity becomes a necessity for global food policies, since food placed in the market without fail has to be authentic. It has always been a challenge, since in the past minor components, called also markers, have been mainly monitored by chromatographic methods in order to authenticate the food. Nevertheless, nowadays, advanced analytical methods have allowed food fingerprints to be achieved. At the same time they have been also combined with chemometrics, which uses statistical methods in order to verify food and to provide maximum information by analysing chemical data. These sophisticated methods based on different separation techniques or stand alone have been recently coupled to high-resolution mass spectrometry (HRMS) in order to verify the authenticity of food. The new generation of HRMS detectors have experienced significant advances in resolving power, sensitivity, robustness, extended dynamic range, easier mass calibration and tandem mass capabilities, making HRMS more attractive and useful to the food metabolomics community, therefore becoming a reliable tool for food authenticity. The purpose of this review is to summarise and describe the most recent metabolomics approaches in the area of food metabolomics, and to discuss the strengths and drawbacks of the HRMS analytical platforms combined with chemometrics. PMID:26365870

  17. High-resolution modeling study of the Kuroshio path variations south of Japan

    NASA Astrophysics Data System (ADS)

    Li, Rui; Zhang, Zuowei; Wu, Lixin

    2014-09-01

    A high-resolution ocean general circulation model (OGCM) is used to investigate the Kuroshio path variations south of Japan. The model reproduces many important features of the Kuroshio system including its interannual bimodal variability south of Japan. A decreasing trend of the spatial averaged relative vorticity is detected when the Kuroshio takes the non-large meander (NLM) path, and during the transition period from the NLM to the large meander (LM), a sudden release of velocity shear corresponds well to the weakening of the Shikoku recirculation gyre (SRG), which plays a key role in modulating the Kuroshio path variations. Analysis of eddy energetics indicates that baroclinic instability is mainly responsible for the formation of the LM. In addition, further analysis shows that the strength of the SRG could be largely influenced by the baroclinic Rossby wave adjustment process, forced by the wind stress curl anomalies in the North Pacific basin, based on the model investigation. It is suggested that the cyclonic disturbances might account for the weakening of the SRG, and act as a remote trigger for the baroclinic instability of the Kuroshio south of Japan.

  18. Component analyses of urinary nanocrystallites of uric acid stone formers by combination of high-resolution transmission electron microscopy, fast Fourier transformation, energy dispersive X-ray spectroscopy, X-ray diffraction and Fourier transform infrared spectroscopy.

    PubMed

    Sun, Xin-Yuan; Xue, Jun-Fa; Xia, Zhi-Yue; Ouyang, Jian-Ming

    2015-06-01

    This study aimed to analyse the components of nanocrystallites in urines of patients with uric acid (UA) stones. X-ray diffraction (XRD), Fourier transform infrared spectroscopy, high-resolution transmission electron microscopy (HRTEM), fast Fourier transformation (FFT) of HRTEM, and energy dispersive X-ray spectroscopy (EDS) were performed to analyse the components of these nanocrystallites. XRD and FFT showed that the main component of urinary nanocrystallites was UA, which contains a small amount of calcium oxalate monohydrate and phosphates. EDS showed the characteristic absorption peaks of C, O, Ca and P. The formation of UA stones was closely related to a large number of UA nanocrystallites in urine. A combination of HRTEM, FFT, EDS and XRD analyses could be performed accurately to analyse the components of urinary nanocrystallites.

  19. [High-resolution magnetoencephalography--studies with a small-volume phantom].

    PubMed

    Hagner, T; Eiselt, M; Giessler, F; Hansen, E; Haueisen, J; Nowak, H

    1999-03-01

    To investigate the spatiotemporal organisation of neuronal processes in an animal model using magnetoencephalography (MEG), a high temporal resolution (ms) and an appropriate spatial resolution of about 1 mm is necessary. With the aim of determining the localization error and the resolution power of high-resolution MEG systems, we developed a phantom capable of simulating the characteristics of animal models. The phantom enables us to variably position at least two magnetic field sources to within 0.1 mm. For source localization on the basis of the magnetic field data, a spatial filtering algorithm was used. The investigation of a 16-channel micro SQUID-MEG system with a current dipole orientated tangentially to the phantom surface produced the following localization data (min ... max, x, y--horizontal plane, z--depth); systematic localization error e(x) = 1.16 ... 1.67 mm, e(y) = -1.01 ... -1.28 mm, e(z) = -5.22 ... -7.64 mm, standard deviation of the individual measurements perpendicular to the dipole axis s(perp) = 0.05 ... 0.22 mm, along this axis s(long) = 0.20 ... 1.73 mm, in the depths sz = 0.17 ... 3.17 mm. The "goodness of fit" was > 95%. Separation of two dipoles was still possible for parallel dipoles at a distance apart of d(parallel) = 0.03 mm and for those oriented perpendicularly to each other at a distance apart of d(perp) = 0.10 mm. On the basis of these results we conclude that the MEG system can achieve a resolution sufficient to permit the investigation of neuronal microstructures. The spatial errors detected were related to sensor position in the cryostatic vessel as well as to external low-frequency noise.

  20. High-resolution Earth-based lunar radar studies: Applications to lunar resource assessment

    NASA Technical Reports Server (NTRS)

    Stacy, N. J. S.; Campbell, D. B.

    1992-01-01

    The lunar regolith will most likely be a primary raw material for lunar base construction and resource extraction. High-resolution radar observations of the Moon provide maps of radar backscatter that have intensity variations generally controlled by the local slope, material, and structural properties of the regolith. The properties that can be measured by the radar system include the dielectric constant, density, loss tangent, and wavelength scale roughness. The radar systems currently in operation at several astronomical observatories provide the ability to image the lunar surface at spatial resolutions approaching 30 m at 3.8 cm and 12.6 cm wavelengths and approximately 500 m at 70 cm wavelength. The radar signal penetrates the lunar regolith to a depth of 10-20 wavelengths so the measured backscatter contains contributions from the vacuum-regolith interface and from wavelength-scale heterogeneities in the electrical properties of the subsurface material. The three wavelengths, which are sensitive to different scale structures and scattering volumes, provide complementary information on the regolith properties. Aims of the previous and future observations include (1) analysis of the scattering properties associated with fresh impact craters, impact crater rays, and mantled deposits; (2) analysis of high-incidence-angle observations of the lunar mare to investigate measurement of the regolith dielectric constant and hence porosity; (3) investigation of interferometric techniques using two time-delayed observations of the same site, observations that require a difference in viewing geometry less than 0.05 deg and, hence, fortuitous alignment of the Earth-Moon system when visible from Arecibo Observatory.

  1. Cranial electrotherapy stimulation and transcranial pulsed current stimulation: a computer based high-resolution modeling study.

    PubMed

    Datta, Abhishek; Dmochowski, Jacek P; Guleyupoglu, Berkan; Bikson, Marom; Fregni, Felipe

    2013-01-15

    The field of non-invasive brain stimulation has developed significantly over the last two decades. Though two techniques of noninvasive brain stimulation--transcranial direct current stimulation (tDCS) and transcranial magnetic stimulation (TMS)--are becoming established tools for research in neuroscience and for some clinical applications, related techniques that also show some promising clinical results have not been developed at the same pace. One of these related techniques is cranial electrotherapy stimulation (CES), a class of transcranial pulsed current stimulation (tPCS). In order to understand further the mechanisms of CES, we aimed to model CES using a magnetic resonance imaging (MRI)-derived finite element head model including cortical and also subcortical structures. Cortical electric field (current density) peak intensities and distributions were analyzed. We evaluated different electrode configurations of CES including in-ear and over-ear montages. Our results confirm that significant amounts of current pass the skull and reach cortical and subcortical structures. In addition, depending on the montage, induced currents at subcortical areas, such as midbrain, pons, thalamus and hypothalamus are of similar magnitude than that of cortical areas. Incremental variations of electrode position on the head surface also influence which cortical regions are modulated. The high-resolution modeling predictions suggest that details of electrode montage influence current flow through superficial and deep structures. Finally we present laptop based methods for tPCS dose design using dominant frequency and spherical models. These modeling predictions and tools are the first step to advance rational and optimized use of tPCS and CES.

  2. Atmospheric chemical transport based on high-resolution model-derived winds: A case study

    NASA Astrophysics Data System (ADS)

    Hannan, John R.; Fuelberg, Henry E.; Thompson, Anne M.; Bieberbach, George; Knabb, Richard D.; Kondo, Yutaka; Anderson, Bruce E.; Browell, Edward V.; Gregory, Gerald L.; Sachse, Glen W.; Singh, Hanwant B.

    2000-02-01

    Flight 10 of NASA's Subsonic Assessment (SASS) Ozone and Nitrogen Oxide Experiment (SONEX) extended southwest of Lajes, Azores. A variety of chemical signatures was encountered. These signatures are examined in detail, relating them to meteorological data from a high-resolution numerical model having a horizontal grid spacing of 30 and 90 km with 26 vertical levels. The meteorological output at hourly intervals is used to create backward trajectories from the locations of the chemical signatures. Four major categories of chemical signatures are discussed: stratospheric, lightning, continental pollution, and a mixed chemical layer. The strong stratospheric signal is encountered just south of the Azores in a region of depressed tropopause height. Three chemical signatures at different altitudes in the upper troposphere are attributed to lightning. Backward trajectories from these signatures extend to locations of cloud-to-ground lightning. Specifically, results show that the trajectories pass over regions of lightning 1-2 days earlier over the eastern Gulf of Mexico and off the southeast coast of the United States. The lowest leg of the flight exhibits a chemical signature consistent with continental pollution. Trajectories from this signature are found to pass over the highly populated Northeast Corridor of the United States. Surface-based pollution apparently is lofted to the altitudes of the trajectories by convective clouds along the East Coast that did not contain lightning. Finally, a mixed layer is described. Its chemical signature is intermediate to those of lightning and continental pollution. Backward trajectories from this layer pass between the trajectories of the lightning and pollution signatures. Thus they likely are impacted by both sources.

  3. Atmospheric Oxidation of Squalene: Molecular Study Using COBRA Modeling and High-Resolution Mass Spectrometry

    SciTech Connect

    Fooshee, David R.; Aiona, Paige K.; Laskin, Alexander; Laskin, Julia; Nizkorodov, Sergey; Baldi, Pierre

    2015-10-22

    Squalene is a major component of skin and plant surface lipids, and is known to be present at high concentrations in indoor dust. Its high reactivity toward ozone makes it an important ozone sink and a natural protectant against atmospheric oxidizing agents. While the volatile products of squalene ozonolysis are known, the condensed-phase products have not been characterized. We present an analysis of condensed-phase products resulting from an extensive oxidation of squalene by ozone probed by electrospray ionization (ESI) high-resolution mass spectrometry (HR-MS). A complex distribution of nearly 1,300 peaks assignable to molecular formulas is observed in direct infusion positive ion mode ESI mass spectra. The distribution of peaks in the mass spectra suggests that there are extensive cross-coupling reactions between hydroxy-carbonyl products of squalene ozonolysis. To get additional insights into the mechanism, we apply a Computational Brewing Application (COBRA) to simulate the oxidation of squalene in the presence of ozone, and compare predicted results with those observed by the HR-MS experiments. The system predicts over one billion molecular structures between 0-1450 Da, which correspond to about 27,000 distinct elemental formulas. Over 83% of the squalene oxidation products inferred from the mass spectrometry data are matched by the simulation. Simulation indicates a prevalence of peroxy groups, with hydroxyl and ether groups being the second-most important O-containing functional groups formed during squalene oxidation. These highly oxidized products of squalene ozonolysis may accumulate on indoor dust and surfaces, and contribute to their redox capacity.

  4. Atmospheric Oxidation of Squalene: Molecular Study Using COBRA Modeling and High-Resolution Mass Spectrometry.

    PubMed

    Fooshee, David R; Aiona, Paige K; Laskin, Alexander; Laskin, Julia; Nizkorodov, Sergey A; Baldi, Pierre F

    2015-11-17

    Squalene is a major component of skin and plant surface lipids and is known to be present at high concentrations in indoor dust. Its high reactivity toward ozone makes it an important ozone sink and a natural protectant against atmospheric oxidizing agents. While the volatile products of squalene ozonolysis are known, the condensed-phase products have not been characterized. We present an analysis of condensed-phase products resulting from an extensive oxidation of squalene by ozone probed by electrospray ionization (ESI) high-resolution mass spectrometry (HR-MS). A complex distribution of nearly 1300 peaks assignable to molecular formulas is observed in direct infusion positive ion mode ESI mass spectra. The distribution of peaks in the mass spectra suggests that there are extensive cross-coupling reactions between hydroxy-carbonyl products of squalene ozonolysis. To get additional insights into the mechanism, we apply a Computational Brewing Application (COBRA) to simulate the oxidation of squalene in the presence of ozone, and compare predicted results with those observed by the HR-MS experiments. The system predicts over one billion molecular structures between 0 and 1450 Da, which correspond to about 27 000 distinct elemental formulas. Over 83% of the squalene oxidation products inferred from the mass spectrometry data are matched by the simulation. The simulation indicates a prevalence of peroxy groups, with hydroxyl and ether groups being the second-most important O-containing functional groups formed during squalene oxidation. These highly oxidized products of squalene ozonolysis may accumulate on indoor dust and surfaces and contribute to their redox capacity. PMID:26492333

  5. High-resolution soft x-ray photoionization studies of selected molecules

    SciTech Connect

    Hudson, E.A.

    1993-08-01

    Near-edge soft x-ray photoionization spectra were measured for CO, SF{sub 6}, H{sub 2}S, and D{sub 2}S in the gas phase, using the Free University of Berlin plane-grating SX-700-II monochromator at the synchrotron radiation source BESSY. Photoionization spectra of carbon monoxide were measured near the carbon and oxygen K edges. Vibrational spacings and bond lengths are derived for several resonances. Results are consistent with equivalent-core model and indicate the different influences of the carbon and oxygen Is core holes. Corresponding spectra of H{sub 2}CO and D{sub 2}CO were also measured. Assignment of complex vibrational structure in valence-shell and Rydberg resonances is facilitated by comparison of spectra for the two isotopic species. Geometric and vibrational parameters are derived for several carbon 1s core-excited states. Isotopic shifts are observed in the energies and linewidths of some core-excited states. Sulfur hexafluoride photoionization spectra, measured near the sulfur L{sub 2,3} edges, show several series of weak, narrow Rydberg resonances. High resolution and good counting statistics allow a complete assignment of these states. Lineshapes of the broad inner-well resonances are analyzed to establish the magnitudes of vibrational and lifetime broadening in these states. Spectra of the H{sub 2}S and D{sub 2}S molecules were also measured near the sulfur L{sub 2,3} edges. Besides lower-energy transitions to inner-well states, a complex manifold of overlapping Rydberg resonances is observed. The rich fine structure of these states arises mainly from removal of orbital degeneracies in molecular field. Additional structure due to vibrational excitations in the final state is identified by comparison of the spectra for the two isotopic species.

  6. High resolution infrared spectroscopy of CN and NH lines: nitrogen abundance in oxygen-rich giants through K to late M

    NASA Astrophysics Data System (ADS)

    Aoki, W.; Tsuji, T.

    1997-12-01

    The analyses of high resolution infrared spectra have been done for CN lines in oxygen-rich cool evolved stars including 2 K giants, 20 M giants and 1 S-type star. Since CN lines analyzed in the present work are weak and resolved well, they are appropriate for quantitative analyses. CN lines of Delta v=-2 and -1 sequences (red system) which are in the K- and the H-window regions, respectively, give the consistent nitrogen abundance for each star. The analyses of NH lines in the L-window region have been done for 5 late M giants for which CN lines have been also analyzed. Although the triplet structure of NH lines cannot be fully resolved, they are preferable because determination of nitrogen abundance is almost independent of other elemental abundances while nitrogen abundance based on CN depends on carbon abundance. The nitrogen abundances derived from NH for late M giants agree well with those from CN for which we adopt 7.75eV as the dissociation energy in the analysis. The results show that the nitrogen abundances in late M giants are larger than those in early M giants while decrease of the carbon abundance was found in late M giants by our previous work (Tsuji 1991). These variations of abundances can not be explained by the first dredge-up model but require additional processing by the CN cycle and mixing after the first dredge-up. However, there is no obvious evidence of other processes such as the 3alpha -process and subsequent hot bottom burning in our program stars. Such variation of the carbon and nitrogen abundances is not well understood by the present evolutionary models of low-mass and intermediate-mass stars. Table~10 is only available in electronic form at the CDS (Strasbourg) via anonymous ftp to cdsarc.u-strasbg.fr (130.79.128.5) or via http://cdsweb.u-strasbg.fr/Abstract.html

  7. Emerging trends and a comet taxonomy based on the volatile chemistry measured in thirty comets with high-resolution infrared spectroscopy between 1997 and 2013

    NASA Astrophysics Data System (ADS)

    Dello Russo, Neil; Kawakita, Hideyo; Vervack, Ronald J.; Weaver, Harold A.

    2016-11-01

    A systematic analysis of the mixing ratios with respect to H2O for eight species (CH3OH, HCN, NH3, H2CO, C2H2, C2H6, CH4, and CO) measured with high-resolution infrared spectroscopy in thirty comets between 1997 and 2013 is presented. Some trends are beginning to emerge when mixing ratios in individual comets are compared to average mixing ratios obtained for all species within the population. The variation in mixing ratios for all measured species is at least an order of magnitude. Overall, Jupiter-family comets are depleted in volatile species with respect to H2O compared to long-period Oort cloud comets, with the most volatile species showing the greatest relative depletion. There is a high positive correlation between the mixing ratios of HCN, C2H6, and CH4, whereas NH3, H2CO, and C2H2 are moderately correlated with each other but generally uncorrelated or show only weak correlation with other species. CO is generally uncorrelated with the other measured species possibly because it has the highest volatility and is therefore more susceptible to thermal evolutionary effects. Most of these correlations appear to be independent of dynamical class with a few possible exceptions. Molecular mixing ratios for CH3OH, HCN, C2H6, and CH4 show an expected behavior with heliocentric distance suggesting a dominant ice source, whereas there is emerging evidence that the mixing ratios of NH3, H2CO, C2H2, NH2, and CN may increase at small heliocentric distances, suggesting the possibility of additional sources related to the thermal decomposition of organic dust. Although this provides information on the composition of the most volatile grains in comets, it presents an additional difficulty in classifying comet chemistry because most comets within this dataset were only observed over a limited range of heliocentric distance. Although there is remarkable compositional diversity resulting in a unique chemical fingerprint for each comet, a hierarchical tree cluster analysis is

  8. High Resolution Infrared Spectra of Plasma Jet-Cooled - and Triacetylene in the C-H Stretch Region by CW Cavity Ring-Down Spectroscopy

    NASA Astrophysics Data System (ADS)

    Zhao, D.; Guss, J.; Walsh, A.; Doney, K.; Linnartz, H.

    2013-06-01

    Polyacetylenes form an important series of unsaturated hydrocarbons that are of astrophysical interest. Small polyacetylenes have been detected from infrared observations in dense atmosphere of Titan and in a protoplanetary nebula CRL 618. We present here high-resolution mid-infrared spectra of diacetylene (HC_{4}H) and triacetylene (HC_{6}H) that are recorded in a supersonically expanded pulsed planar plasma using an ultra-sensitive detection technique. This method uses an all fiber-laser-based optical parametric oscillator (OPO), in combination with continuous wave cavity ring-down spectroscopy (cw-CRDS) as a direct absorption detection tool. A hardware-based multi-trigger concept is developed to apply cw-CRDS to pulsed plasmas. Vibrationally hot but rotationally cold HC_{4}H and HC_{6}H are produced by discharging a C_{2}H_{2}/He/Ar gas mixture which is supersonically expanded into a vacuum chamber through a slit discharge nozzle. Experimental spectra are recorded at a resolution of ˜100 MHz in the 3305-3340 cm^{-1} region, which is characteristic of the C-H stretch vibrations of HC_{4}H and HC_{6}H. Jet-cooling in our experiment reduces the rotational temperature of both HC_{4}H and HC_{6}H to <20 K. In total, ˜2000 lines are measured. More than fourteen (vibrationally hot) bands for HC_{4}H and four bands for HC_{6}H are assigned based on Loomis-Wood diagrams, and nearly half of these bands are analyzed for the first time. For both molecules improved and new molecular constants of a series of vibrational levels are presented. The accurate molecular data reported here, particularly those for low-lying (bending) vibrational levels may be used to interpret the ro-vibrational transitions in the FIR and submillimeter/THz region. D. Zhao, J. Guss, A. Walsh, H. Linnartz Chem. Phys. Lett., {dx.doi.org/10.1016/j.cplett.2013.02.025}, in press, 2013.

  9. Neural basis for brain responses to TV commercials: a high-resolution EEG study.

    PubMed

    Astolfi, Laura; De Vico Fallani, F; Cincotti, F; Mattia, D; Bianchi, L; Marciani, M G; Salinari, S; Colosimo, A; Tocci, A; Soranzo, R; Babiloni, F

    2008-12-01

    We investigated brain activity during the observation of TV commercials by tracking the cortical activity and the functional connectivity changes in normal subjects. The aim was to elucidate if the TV commercials that were remembered by the subjects several days after their first observation elicited particular brain activity and connectivity compared with those generated during the observation of TV commercials that were quickly forgotten. High-resolution electroencephalogram (EEG) recordings were performed in a group of healthy subjects and the cortical activity during the observation of TV commercials was evaluated in several regions of interest coincident with the Brodmann areas (BAs). The patterns of cortical connectivity were obtained in the four principal frequency bands, Theta (3-7 Hz), Alpha (8-12 Hz), Beta (13-30 Hz), Gamma (30-40 Hz) and the directed influences between any given pair of the estimated cortical signals were evaluated by use of a multivariate spectral technique known as partial directed coherence. The topology of the cortical networks has been identified with tools derived from graph theory. Results suggest that the cortical activity and connectivity elicited by the viewing of the TV commercials that were remembered by the experimental subjects are markedly different from the brain activity elicited during the observation of the TV commercials that were forgotten. In particular, during the observation of the TV commercials that were remembered, the amount of cortical spectral activity from the frontal areas (BA 8 and 9) and from the parietal areas (BA 5, 7, and 40) is higher compared with the activity elicited by the observation of TV commercials that were forgotten. In addition, network analysis suggests a clear role of the parietal areas as a target of the incoming flow of information from all the other parts of the cortex during the observation of TV commercials that have been remembered. The techniques presented here shed new light on

  10. Neural basis for brain responses to TV commercials: a high-resolution EEG study.

    PubMed

    Astolfi, Laura; De Vico Fallani, F; Cincotti, F; Mattia, D; Bianchi, L; Marciani, M G; Salinari, S; Colosimo, A; Tocci, A; Soranzo, R; Babiloni, F

    2008-12-01

    We investigated brain activity during the observation of TV commercials by tracking the cortical activity and the functional connectivity changes in normal subjects. The aim was to elucidate if the TV commercials that were remembered by the subjects several days after their first observation elicited particular brain activity and connectivity compared with those generated during the observation of TV commercials that were quickly forgotten. High-resolution electroencephalogram (EEG) recordings were performed in a group of healthy subjects and the cortical activity during the observation of TV commercials was evaluated in several regions of interest coincident with the Brodmann areas (BAs). The patterns of cortical connectivity were obtained in the four principal frequency bands, Theta (3-7 Hz), Alpha (8-12 Hz), Beta (13-30 Hz), Gamma (30-40 Hz) and the directed influences between any given pair of the estimated cortical signals were evaluated by use of a multivariate spectral technique known as partial directed coherence. The topology of the cortical networks has been identified with tools derived from graph theory. Results suggest that the cortical activity and connectivity elicited by the viewing of the TV commercials that were remembered by the experimental subjects are markedly different from the brain activity elicited during the observation of the TV commercials that were forgotten. In particular, during the observation of the TV commercials that were remembered, the amount of cortical spectral activity from the frontal areas (BA 8 and 9) and from the parietal areas (BA 5, 7, and 40) is higher compared with the activity elicited by the observation of TV commercials that were forgotten. In addition, network analysis suggests a clear role of the parietal areas as a target of the incoming flow of information from all the other parts of the cortex during the observation of TV commercials that have been remembered. The techniques presented here shed new light on

  11. Use of High Resolution 3D Diffusion Tensor Imaging to Study Brain White Matter Development in Live Neonatal Rats

    PubMed Central

    Cai, Yu; McMurray, Matthew S.; Oguz, Ipek; Yuan, Hong; Styner, Martin A.; Lin, Weili; Johns, Josephine M.; An, Hongyu

    2011-01-01

    High resolution diffusion tensor imaging (DTI) can provide important information on brain development, yet it is challenging in live neonatal rats due to the small size of neonatal brain and motion-sensitive nature of DTI. Imaging in live neonatal rats has clear advantages over fixed brain scans, as longitudinal and functional studies would be feasible to understand neuro-developmental abnormalities. In this study, we developed imaging strategies that can be used to obtain high resolution 3D DTI images in live neonatal rats at postnatal day 5 (PND5) and PND14, using only 3 h of imaging acquisition time. An optimized 3D DTI pulse sequence and appropriate animal setup to minimize physiological motion artifacts are the keys to successful high resolution 3D DTI imaging. Thus, a 3D rapid acquisition relaxation enhancement DTI sequence with twin navigator echoes was implemented to accelerate imaging acquisition time and minimize motion artifacts. It has been suggested that neonatal mammals possess a unique ability to tolerate mild-to-moderate hypothermia and hypoxia without long term impact. Thus, we additionally utilized this ability to minimize motion artifacts in magnetic resonance images by carefully suppressing the respiratory rate to around 15/min for PND5 and 30/min for PND14 using mild-to-moderate hypothermia. These imaging strategies have been successfully implemented to study how the effect of cocaine exposure in dams might affect brain development in their rat pups. Image quality resulting from this in vivo DTI study was comparable to ex vivo scans. fractional anisotropy values were also similar between the live and fixed brain scans. The capability of acquiring high quality in vivo DTI imaging offers a valuable opportunity to study many neurological disorders in brain development in an authentic living environment. PMID:22013426

  12. High-resolution imaging of the large non-human primate brain using microPET: a feasibility study

    NASA Astrophysics Data System (ADS)

    Naidoo-Variawa, S.; Hey-Cunningham, A. J.; Lehnert, W.; Kench, P. L.; Kassiou, M.; Banati, R.; Meikle, S. R.

    2007-11-01

    The neuroanatomy and physiology of the baboon brain closely resembles that of the human brain and is well suited for evaluating promising new radioligands in non-human primates by PET and SPECT prior to their use in humans. These studies are commonly performed on clinical scanners with 5 mm spatial resolution at best, resulting in sub-optimal images for quantitative analysis. This study assessed the feasibility of using a microPET animal scanner to image the brains of large non-human primates, i.e. papio hamadryas (baboon) at high resolution. Factors affecting image accuracy, including scatter, attenuation and spatial resolution, were measured under conditions approximating a baboon brain and using different reconstruction strategies. Scatter fraction measured 32% at the centre of a 10 cm diameter phantom. Scatter correction increased image contrast by up to 21% but reduced the signal-to-noise ratio. Volume resolution was superior and more uniform using maximum a posteriori (MAP) reconstructed images (3.2-3.6 mm3 FWHM from centre to 4 cm offset) compared to both 3D ordered subsets expectation maximization (OSEM) (5.6-8.3 mm3) and 3D reprojection (3DRP) (5.9-9.1 mm3). A pilot 18F-2-fluoro-2-deoxy-d-glucose ([18F]FDG) scan was performed on a healthy female adult baboon. The pilot study demonstrated the ability to adequately resolve cortical and sub-cortical grey matter structures in the baboon brain and improved contrast when images were corrected for attenuation and scatter and reconstructed by MAP. We conclude that high resolution imaging of the baboon brain with microPET is feasible with appropriate choices of reconstruction strategy and corrections for degrading physical effects. Further work to develop suitable correction algorithms for high-resolution large primate imaging is warranted.

  13. High-resolution 3D ultrasound jawbone surface imaging for diagnosis of periodontal bony defects: an in vitro study.

    PubMed

    Mahmoud, Ahmed M; Ngan, Peter; Crout, Richard; Mukdadi, Osama M

    2010-11-01

    Although medical specialties have recognized the importance of using ultrasonic imaging, dentistry is only beginning to discover its benefit. This has particularly been important in the field of periodontics which studies infections in the gum and bone tissues that surround the teeth. This study investigates the feasibility of using a custom-designed high-frequency ultrasound imaging system to reconstruct high-resolution (< 50 μm) three-dimensional (3D) surface images of periodontal defects in human jawbone. The system employs single-element focused ultrasound transducers with center frequencies ranging from 30 to 60 MHz. Continuous acquisition using a 1 GHz data acquisition card is synchronized with a high-precision two-dimensional (2D) positioning system of ±1 μm resolution for acquiring accurate measurements of the mandible, in vitro. Signal and image processing algorithms are applied to reconstruct high-resolution ultrasound images and extract the jawbone surface in each frame. Then, all edges are combined and smoothed in order to render a 3D surface image of the jawbone. In vitro experiments were performed to assess the system performance using mandibles with teeth (dentate) or without (nondentate). The system was able to reconstruct 3D images for the mandible's outer surface with superior spatial resolution down to 24 μm, and to perform the whole scanning in < 30 s. Major anatomical landmarks on the images were confirmed with the anatomical structures on the mandibles. All the anatomical landmarks were detected and fully described as 3D images using this novel ultrasound imaging technique, whereas the 2D X-ray radiographic images suffered from poor contrast. These results indicate the great potential of utilizing high-resolution ultrasound as a noninvasive, nonionizing imaging technique for the early diagnosis of the more severe form of periodontal disease.

  14. ASTER Urgent Response to the 2006 Eruption of Augustine Volcano, Alaska: Science and Decision Support Gained From Frequent High-resolution, Satellite Thermal Infrared Imaging of Volcanic Events

    NASA Astrophysics Data System (ADS)

    Wessels, R. L.; Ramsey, M. S.; Schneider, D. S.; Coombs, M.; Dehn, J.; Realmuto, V. J.

    2006-12-01

    Augustine Volcano, Alaska explosively erupted on January 11, 2006 after nearly eight months of increasing seismicity, deformation, gas emission, and small phreatic explosions. The volcano produced a total of 13 explosive eruptions during the last three weeks of January 2006. A new summit lava dome and two short, blocky lava flows grew during February and March 2006. A series of 7 daytime and 15 nighttime Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) scenes were acquired in response to this new activity. This response was facilitated by a new ASTER Urgent Request Protocol system. The ASTER data provided several significant observations as a part of a much larger suite of real-time or near-real-time data from other satellite (AVHRR, MODIS), airborne (FLIR, visual, gas), and ground-based (seismometers, radiometers) sensors used at the Alaska Volcano Observatory (AVO). ASTER is well-suited to volcanic observations because of its 15-m to 90-m spatial resolution, its ability to be scheduled and point off-nadir, and its ability to collect visible-near infrared (VNIR) to thermal infrared (TIR) data during both the day and night. Aided by the volcano's high latitude (59.4°N) ASTER was able to provide frequent repeat imaging as short as one day between scenes with an average 6-day repeat during the height of activity. These data provided a time series of high-resolution VNIR, shortwave infrared (SWIR - detects temperatures from about 200°C to > 600°C averaged over a 30-m pixel), and TIR (detects temperatures up to about 100°C averaged over a 90-m pixel) data of the volcano and its eruptive products. Frequent satellite imaging of volcanoes is necessary to record rapid changes in activity and to avoid recurring cloud cover. Of the 22 ASTER scenes acquired between October 30, 2005 and May 30, 2006, the volcano was clear to partly cloudy in 13 scenes. The most useful pre-eruption ASTER Urgent Request image was acquired on December 20. These data

  15. High-Resolution Distance Dependence Study of Surface-Enhanced Raman Scattering Enabled by Atomic Layer Deposition.

    PubMed

    Masango, Sicelo S; Hackler, Ryan A; Large, Nicolas; Henry, Anne-Isabelle; McAnally, Michael O; Schatz, George C; Stair, Peter C; Van Duyne, Richard P

    2016-07-13

    We present a high-resolution distance dependence study of surface-enhanced Raman scattering (SERS) enabled by atomic layer deposition (ALD) at 55 and 100 °C. ALD is used to deposit monolayers of Al2O3 on bare silver film over nanospheres (AgFONs) and AgFONs functionalized with self-assembled monolayers. Operando SERS is used to measure the intensities of the Al-CH3 and C-H stretches from trimethylaluminum (TMA) as a function of distance from the AgFON surface. This study clearly demonstrates that SERS on AgFON substrates displays both a short- and long-range nanometer scale distance dependence. Excellent agreement is obtained between these experiments and theory that incorporates both short-range and long-range terms. This is a high-resolution operando SERS distance dependence study performed in one integrated experiment using ALD Al2O3 as the spacer layer and Raman label simultaneously. The long-range SERS distance dependence should make it possible to detect chemisorbed surface species located as far as ∼3 nm from the AgFON substrate and will provide new insight into the surface chemistry of ALD and catalytic reactions.

  16. Sensory epithelia of the fish inner ear in 3D: studied with high-resolution contrast enhanced microCT

    PubMed Central

    2013-01-01

    Introduction While a number of studies have illustrated and analyzed 3D models of inner ears in higher vertebrates, inner ears in fishes have rarely been investigated in 3D, especially with regard to the sensory epithelia of the end organs, the maculae. It has been suggested that the 3D curvature of these maculae may also play an important role in hearing abilities in fishes. We therefore set out to develop a fast and reliable approach for detailed 3D visualization of whole inner ears as well as maculae. Results High-resolution microCT imaging of black mollies Poecilia sp. (Poeciliidae, Teleostei) and Steatocranus tinanti (Cichlidae, Teleostei) stained with phosphotungstic acid (PTA) resulted in good tissue contrast, enabling us to perform a reliable 3D reconstruction of all three sensory maculae of the inner ears. Comparison with maculae that have been 3D reconstructed based on histological serial sections and phalloidin-stained maculae showed high congruence in overall shape of the maculae studied here. Conclusions PTA staining and subsequent high-resolution contrast enhanced microCT imaging is a powerful method to obtain 3D models of fish inner ears and maculae in a fast and more reliable manner. Future studies investigating functional morphology, phylogenetic potential of inner ear features, or evolution of hearing and inner ear specialization in fishes may benefit from the use of 3D models of inner ears and maculae. PMID:24160754

  17. High-Resolution Distance Dependence Study of Surface-Enhanced Raman Scattering Enabled by Atomic Layer Deposition.

    PubMed

    Masango, Sicelo S; Hackler, Ryan A; Large, Nicolas; Henry, Anne-Isabelle; McAnally, Michael O; Schatz, George C; Stair, Peter C; Van Duyne, Richard P

    2016-07-13

    We present a high-resolution distance dependence study of surface-enhanced Raman scattering (SERS) enabled by atomic layer deposition (ALD) at 55 and 100 °C. ALD is used to deposit monolayers of Al2O3 on bare silver film over nanospheres (AgFONs) and AgFONs functionalized with self-assembled monolayers. Operando SERS is used to measure the intensities of the Al-CH3 and C-H stretches from trimethylaluminum (TMA) as a function of distance from the AgFON surface. This study clearly demonstrates that SERS on AgFON substrates displays both a short- and long-range nanometer scale distance dependence. Excellent agreement is obtained between these experiments and theory that incorporates both short-range and long-range terms. This is a high-resolution operando SERS distance dependence study performed in one integrated experiment using ALD Al2O3 as the spacer layer and Raman label simultaneously. The long-range SERS distance dependence should make it possible to detect chemisorbed surface species located as far as ∼3 nm from the AgFON substrate and will provide new insight into the surface chemistry of ALD and catalytic reactions. PMID:27243108

  18. High Resolution Spectroscopy to Support Atmospheric Measurements

    NASA Technical Reports Server (NTRS)

    Venkataraman, Malathy Devi

    2003-01-01

    Spectroscopic parameters (such as line position, intensity, broadening and shifting coefficients and their temperature dependences, line mixing coefficients etc.) for various molecular species of atmospheric interest are determined. In order to achieve these results, infrared spectra of several molecular bands are obtained using high-resolution recording instruments such as tunable diode laser spectrometer and Fourier transform spectrometers. Using sophisticated analysis routines (Multispectrum nonlinear least squares technique) these high-resolution infrared spectra are processed to determine the various spectral line parameters that are cited above. Spectra were taken using the McMath-Pierce Fourier transform spectrometer (FTS) at the National Solar Observatory on Kitt Peak, Arizona as well as the Bruker FTS at the Pacific Northwest National Laboratory (PNNL) at Richland, Washington. Most of the spectra are acquired not only at room temperature, but also at several different cold temperatures. This procedure is necessary to study the variation of the spectral line parameters as a function of temperature in order to simulate the Earth's and other planetary atmospheric environments. Depending upon the strength or weakness of the various bands recorded and analyzed, the length(s) of the absorption cells in which the gas samples under study are kept varied from a few centimeters up to several meters and the sample temperatures varied from approximately +30 C to -63 C. Research on several infrared bands of various molecular species and their isotopomers are undertaken. Those studies are briefly described.

  19. Developing a semi/automated protocol to post-process large volume, High-resolution airborne thermal infrared (TIR) imagery for urban waste heat mapping

    NASA Astrophysics Data System (ADS)

    Rahman, Mir Mustafizur

    In collaboration with The City of Calgary 2011 Sustainability Direction and as part of the HEAT (Heat Energy Assessment Technologies) project, the focus of this research is to develop a semi/automated 'protocol' to post-process large volumes of high-resolution (H-res) airborne thermal infrared (TIR) imagery to enable accurate urban waste heat mapping. HEAT is a free GeoWeb service, designed to help Calgary residents improve their home energy efficiency by visualizing the amount and location of waste heat leaving their homes and communities, as easily as clicking on their house in Google Maps. HEAT metrics are derived from 43 flight lines of TABI-1800 (Thermal Airborne Broadband Imager) data acquired on May 13--14, 2012 at night (11:00 pm--5:00 am) over The City of Calgary, Alberta (˜825 km 2) at a 50 cm spatial resolution and 0.05°C thermal resolution. At present, the only way to generate a large area, high-spatial resolution TIR scene is to acquire separate airborne flight lines and mosaic them together. However, the ambient sensed temperature within, and between flight lines naturally changes during acquisition (due to varying atmospheric and local micro-climate conditions), resulting in mosaicked images with different temperatures for the same scene components (e.g. roads, buildings), and mosaic join-lines arbitrarily bisect many thousands of homes. In combination these effects result in reduced utility and classification accuracy including, poorly defined HEAT Metrics, inaccurate hotspot detection and raw imagery that are difficult to interpret. In an effort to minimize these effects, three new semi/automated post-processing algorithms (the protocol) are described, which are then used to generate a 43 flight line mosaic of TABI-1800 data from which accurate Calgary waste heat maps and HEAT metrics can be generated. These algorithms (presented as four peer-reviewed papers)---are: (a) Thermal Urban Road Normalization (TURN)---used to mitigate the microclimatic

  20. Feasibility study of high-resolution coherent diffraction microscopy using synchrotron x rays focused by Kirkpatrick-Baez mirrors

    SciTech Connect

    Takahashi, Yukio; Nishino, Yoshinori; Ishikawa, Tetsuya; Mimura, Hidekazu; Tsutsumi, Ryosuke; Kubo, Hideto; Yamauchi, Kazuto

    2009-04-15

    High-flux coherent x rays are necessary for the improvement of the spatial resolution in coherent x-ray diffraction microscopy (CXDM). In this study, high-resolution CXDM using Kirkpatrick-Baez (KB) mirrors is proposed, and the mirrors are designed for experiments of the transmission scheme at SPring-8. Both the photon density and spatial coherence of synchrotron x rays focused by the KB mirrors are investigated by wave optical simulation. The KB mirrors can produce nearly diffraction-limited two-dimensional focusing x rays of approx1 mum in size at 8 keV. When the sample size is less than approx1 mum, the sample can be illuminated with full coherent x rays by adjusting the cross-slit size set between the source and the mirrors. From the estimated photon density at the sample position, the feasibility of CXDM with a sub-1-nm spatial resolution is suggested. The present ultraprecise figuring process enables us to fabricate mirrors for carrying out high-resolution CXDM experiments.

  1. Laboratory infrared studies of molecules of atmospheric and astrophysical interest

    NASA Technical Reports Server (NTRS)

    Rao, N. N.

    1982-01-01

    Nineteen reprints on the molecular species are compiled. Much of the work was done by using the Doppler-limited resolution provided by diode lasers. The diode laser was used as a source to a grating spectrometer which has been used earlier for high resolution studies. This technique provided many advantages. Wherever possible, the studies have been directed to intensity determinations of infrared bands.

  2. An Overview of MADONA: A Multinational Field Study of High-Resolution Meteorology and Diffusion over Complex Terrain.

    NASA Astrophysics Data System (ADS)

    Cionco, R. M.; Byers, J. H.; Aufm Kampe, W.; van Raden, H.; Weber, H.; Biltoft, C.; Collins, C. G.; Higgs, T. J.; Jones, C. D.; Ride, D. J.; Robson, R.; Hin, A. R. T.; Johansson, P.-E.; Nyrén, K.; Jørgensen, H. E.; Mikkelsen, T.; Santabarbara, J. M.; Thykier-Nielsen, S.; Kimber, J. F.; Streicher, J.

    1999-01-01

    The multination, high-resolution field study of Meteorology And Diffusion Over Non-Uniform Areas (MADONA) was conducted by scientists from the United States, the United Kingdom, Germany, Denmark, Sweden, and the Netherlands at Porton Down, Salisbury, Wiltshire, United Kingdom, during September and October 1992. The host of the field study was the Chemical and Biological Defence Establishment (CBDE, now part of Defence Evaluation and Research Agency) at Porton Down. MADONA was designed and conducted for high-resolution meteorological data collection and diffusion experiments using smoke, sulphurhexaflouride (SF6), and propylene gas during unstable, neutral, and stable atmospheric conditions in an effort to obtain terrain-influenced meteorological fields, dispersion, and concentration fluctuation measurements using specialized sensors and tracer generators. Thirty-one days of meteorological data were collected during the period 7 September-7 October and 27 diffusion experiments were conducted from 14 to 23 September 1992. Puffs and plumes of smoke and SF6 were released simultaneously for most of the experiments to gauge the resultant diffusion and concentration behavior. Some 44 meteorological and aerosol sensors and four source generators were used during each day of the field study. This array of sensors included 14 towers of wind cups and vanes, 10 sonic anemometer/thermometers, one boundary layer sonde, two lidar, one ion sensor, the CBDE Weather Station, and several one-of-a-kind sensors. Simulations of airflow and diffusion over the MADONA topography (a 9 km by 7.5 km area) were made with a variety of models. Wind fields and wind-related parameters were simulated with several high-resolution (microalpha scale) wind flow models. A tally of the various data-gathering activities indicates that the execution of MADONA was highly successful. Preliminary use of the datasets shows the high quality and depth of the MADONA database. This well-documented database is

  3. High-resolution imaging with a real-time synthetic aperture ultrasound system: a phantom study

    NASA Astrophysics Data System (ADS)

    Huang, Lianjie; Labyed, Yassin; Simonetti, Francesco; Williamson, Michael; Rosenberg, Robert; Heintz, Philip; Sandoval, Daniel

    2011-03-01

    It is difficult for ultrasound to image small targets such as breast microcalcifications. Synthetic aperture ultrasound imaging has recently developed as a promising tool to improve the capabilities of medical ultrasound. We use two different tissueequivalent phantoms to study the imaging capabilities of a real-time synthetic aperture ultrasound system for imaging small targets. The InnerVision ultrasound system DAS009 is an investigational system for real-time synthetic aperture ultrasound imaging. We use the system to image the two phantoms, and compare the images with those obtained from clinical scanners Acuson Sequoia 512 and Siemens S2000. Our results show that synthetic aperture ultrasound imaging produces images with higher resolution and less image artifacts than Acuson Sequoia 512 and Siemens S2000. In addition, we study the effects of sound speed on synthetic aperture ultrasound imaging and demonstrate that an accurate sound speed is very important for imaging small targets.

  4. High Resolution RANS NLH Study of Stage 67 Tip Injection Physics

    SciTech Connect

    Matheson, Michael A

    2014-01-01

    Numerical prediction of the Stage 67 transonic fan stage employing wall jet tip injection flow control and study of the physical mechanisms leading to stall suppression and stability enhancement afforded by endwall recirculation/injection is the focus of this paper. Reynolds averaged Navier-Stokes computations were used to perform detailed analysis of the Stage 67 configuration experimentally tested at NASA s Glenn Research Center in 2004. Time varying prediction of the stage plus recirculation and injection flowpath were performed utilizing the Nonlinear Harmonic approach. Significantly higher grid resolution per passage was achieved than what has been generally employed in prior reported numerical studies of spike stall phenomena in transonic compressors. This paper focuses on characterizing the physics of spike stall embryonic stage phenomena and the impact of tip injection, resulting in experimentally and numerically demonstrated stall suppression

  5. Mechanism of cellular secretion studied by high resolution soft-x-ray microscopy

    SciTech Connect

    Loo, Jr., Billy W.; Meyer-Ilse, W; Rothman, S S

    1997-04-01

    The secretion of proteins is a fundamental cellular process. The physical and biochemical mechanisms that underlie this process have been studied with the view that they can serve as a general model for how cells transport many different substances to and through their various compartments and to the external environment. In this work, the authors study the secretion of digestive enzymes by the acinar cell of the mammalian pancreas. This is the classical system for studying such processes. The proteins that digest food are stored in approximately micrometer sized vesicles, zymogen granules, within these cells. There are two explanations for how these proteins are transported from within the granules to the exterior of the cell during the process of secretion. One proposes that whole granules are lost from the cell in discrete events, and the other proposes that partial and gradual emptying of the granules accounts for protein secretion. Of course, both mechanisms may occur. The authors are attempting to assess to what degree each of these mechanisms account for protein secretion by the organ. In order to do so, the authors have been determining whether physical changes in the granules, such as mass loss, occur during secretion as the second model predicts, or if there is a simple reduction in the number of granules as predicted by the first model.

  6. Oliver E. Buckley Condensed Matter Prize Talk: High-resolution Photoemission Studies of the High Tc Superconductors

    NASA Astrophysics Data System (ADS)

    Johnson, Peter

    2011-03-01

    In the last decade, high resolution angle-resolved photoelectron spectroscopy has evolved into one of the most powerful probes of the electronic structure of condensed matter systems. This development reflects new technological advances coupled to the enormous research effort devoted to the study of strongly correlated systems, particularly the high Tc cuprate superconductors. Two decades after their initial discovery the latter still present some of the biggest challenges for materials science. In this talk we review some of the developments in new instrumentation and analysis techniques in photoemission and include discussion of both self-energy effects and Fermi surface studies. In the latter case, the discussion will focus on the pseudogap phase of the underdoped cuprates with particular reference to an observed particle-hole asymmetry and the possibility of hole pockets. Work at Brookhaven is supported by the U.S. Department of Energy.

  7. High Resolution Electron Microscopy Study of Phase Composition of Yttrium Oxide Nanoparticles

    NASA Astrophysics Data System (ADS)

    Mamtsev, D. I.; Murzakaev, A. M.

    2015-10-01

    Phase composition and structural features of the yttrium oxide nanoparticles produced by laser evaporation are studied. Initial and annealed samples were examined. Initial samples contain several phases. The phase composition is found to depend on the particle size. Small crystallites (5-12 nm) possess a FCC lattice (Fm-3m) and larger ones have a BCC lattice (Ia-3). Annealing at temperatures T = 930-1000°C allowed to obtain samples containing only particles with the BCC lattice that may be used for the manufacture of transparent ceramics.

  8. High resolution taxonomic study of the late Eocene (~34 Ma) Florissant palynoflora, Colorado, USA

    NASA Astrophysics Data System (ADS)

    Bouchal, J. M.

    2012-04-01

    The Florissant Fossil Beds National Monument is located in Teller County in central Colorado, at approximate latitude 38°54'N and longitude 105°13'. The lithologies of the Florissant Formation consist of coarse-grained arkosic and volcanoclastic sandstones and conglomerates, finer shale, and tuffaceus mudstone and siltstone. It is divided into six units, mostly of lacustrine and fluvial origin with volcanic sediments interfingering and topping the strata. Volcanic units have been dated using the 40Ar/39Ar single-crystal method, giving an absolute age of ca. 34 Ma for the upper fossiliferous sedimentary unit. This pinpoints the formation of the Florissant sediments at the end of the Eocene, providing fruitful insight into the changing palaeoecosystem of the region at the dawn of the Oligocene. The formation is very well known for its rich fossil insect fauna and well preserved plant macrofossils found in the shale units, and the silicified tree stumps occurring in the lower mudstone unit. The sample used for this study originates from the upper shale unit, the fifth unit from the base of the formation. Previous studies on the plant macrofossils, mesofossils and the palynoflora have shown that during the late Eocene the surroundings of Florissant palaeo-lake were covered by diverse mixed broad-leaved evergreen/deciduous and needle-leafed forests. Until now pollen from the Florissant Formation has mostly been described according to conventional morphological nomenclature, using light microscopy (LM) only. In this study the same individual pollen grains are investigated using both LM and scanning electron microscopy (SEM), by means of single grain technique. This provides best exploitable results concerning a more detailed resolution regarding taxonomy and more accurate identifications. The main goal of this study is to compile a well resolved taxonomic species list based on the palynoflora, to clarify the generic and species diversity of selected families (e

  9. Global change impacts on river ecosystems: A high-resolution watershed study of Ebro river metabolism.

    PubMed

    Val, Jonatan; Chinarro, David; Pino, María Rosa; Navarro, Enrique

    2016-11-01

    Global change is transforming freshwater ecosystems, mainly through changes in basin flow dynamics. This study assessed how the combination of climate change and human management of river flow impacts metabolism of the Ebro River (the largest river basin in Spain, 86,100km(2)), assessed as gross primary production-GPP-and ecosystem respiration-ER. In order to investigate the influence of global change on freshwater ecosystems, an analysis of trends and frequencies from 25 sampling sites of the Ebro river basin was conducted. For this purpose, we examined the effect of anthropogenic flow control on river metabolism with a Granger causality study; simultaneously, took into account the effects of climate change, a period of extraordinary drought (largest in past 140years). We identified periods of sudden flow changes resulting from both human management and global climate effects. From 1998 to 2012, the Ebro River basin was trending toward a more autotrophic condition indicated by P/R ratio. Particularly, the results show that floods that occurred after long periods of low flows had a dramatic impact on the respiration (i.e., mineralization) capacity of the river. This approach allowed for a detailed characterization of the relationships between river metabolism and drought impacts at the watershed level. These findings may allow for a better understanding of the ecological impacts provoked by flow management, thus contributing to maintain the health of freshwater communities and ecosystem services that rely on their integrity. PMID:27392332

  10. Study of hydrogen in coals, polymers, oxides, and muscle water by nuclear magnetic resonance; extension of solid-state high-resolution techniques. [Hydrogen molybdenum bronze

    SciTech Connect

    Ryan, L.M.

    1981-10-01

    Nuclear magnetic resonance (NMR) spectroscopy has been an important analytical and physical research tool for several decades. One area of NMR which has undergone considerable development in recent years is high resolution NMR of solids. In particular, high resolution solid state /sup 13/C NMR spectra exhibiting features similar to those observed in liquids are currently achievable using sophisticated pulse techniques. The work described in this thesis develops analogous methods for high resolution /sup 1/H NMR of rigid solids. Applications include characterization of hydrogen aromaticities in fossil fuels, and studies of hydrogen in oxides and bound water in muscle.

  11. Magnetic dynamics studied by high-resolution electron spectroscopy and time-resolved electron microscopy

    NASA Astrophysics Data System (ADS)

    Jayaraman, Rajeswari

    Future information technology requires an increased magnetically encoded data density and novel electromagnetic modes of data transfer. While to date magnetic properties are observed and characterized mostly statically, the need emerges to monitor and capture their fast dynamics. In this talk, I will focus on the spin dynamics i.e. spin wave excitations and the dynamics of a new topological distribution of spins termed ``skyrmions''. Wave packets of spin waves offer the unique capability to transport a quantum bit, the spin, without the transport of charge or mass. Here, large wave-vector spin waves are of particular interest as they admit spin localization within a few nanometers. By using our recently developed electron energy loss spectrometer, we could study such spin waves in ultrathin films with an unprecedented energy resolution of 4 meV. By virtue of the finite penetration depth of low energy electrons, spin waves localized at interfaces between a substrate and a thin capping layer can be been studied yielding information about the exchange coupling between atoms at the interface. The quantization of spin waves with wave vectors perpendicular to the film gives rise to standing modes to which EELS has likewise access. Such studies when carried out as function of the film thickness again yield information on the layer dependence of the exchange coupling. Magnetic skyrmions are promising candidates as information carriers in logic or storage devices. Currently, little is known about the influence of disorder, defects, or external stimuli on the spatial distribution and temporal evolution of the skyrmion lattice. In this talk, I will describe the dynamical role of disorder in a large and flat thin film of Cu2OSeO3, exhibiting a skyrmion phase in an insulating material. We image up to 70,000 skyrmions by means of cryo-Lorentz Transmission Electron Microscopy as a function of the applied magnetic field. In the skyrmion phase, dislocations are shown to cause the

  12. Study of Fish Response Using Particle Image Velocimetry and High-Speed, High-Resolution Imaging

    SciTech Connect

    Deng, Zhiqun; Richmond, Marshall C.; Guensch, Gregory R.; Mueller, Robert P.

    2004-10-23

    Existing literature of previous particle image velocimetry (PIV) studies of fish swimming has been reviewed. Historically, most of the studies focused on the performance evaluation of freely swimming fish. Technological advances over the last decade, especially the development of digital particle image velocimetry (DPIV) technique, make possible more accurate, quantitative descriptions of the flow patterns adjacent to the fish and in the wake behind the fins and tail, which are imperative to decode the mechanisms of drag reduction and propulsive efficiency. For flows generated by different organisms, the related scales and flow regimes vary significantly. For small Reynolds numbers, viscosity dominates; for very high Reynolds numbers, inertia dominates, and three-dimensional complexity occurs. The majority of previous investigations dealt with the lower end of Reynolds number range. The fish of our interest, such as rainbow trout and spring and fall chinook salmon, fall into the middle range, in which neither viscosity nor inertia is negligible, and three-dimensionality has yet to dominate. Feasibility tests have proven the applicability of PIV to flows around fish. These tests have shown unsteady vortex shedding in the wake, high vorticity region and high stress region, with the highest in the pectoral area. This evident supports the observations by Nietzel et al. (2000) and Deng et al. (2004) that the operculum are most vulnerable to damage from the turbulent shear flow, because they are easily pried open, and the large vorticity and shear stress can lift and tear off scales, rupture or dislodge eyes, and damage gills. In addition, the unsteady behavior of the vortex shedding in the wake implies that injury to fish by the instantaneous flow structures would likely be much higher than the injury level estimated using the average values of the dynamics parameters. Based on existing literature, our technological capability, and relevance and practicability to

  13. High Resolution In Vivo Bioluminescent Imaging for the Study of Bacterial Tumour Targeting

    PubMed Central

    Cronin, Michelle; Akin, Ali R.; Collins, Sara A.; Meganck, Jeff; Kim, Jae-Beom; Baban, Chwanrow K.; Joyce, Susan A.; van Dam, Gooitzen M.; Zhang, Ning; van Sinderen, Douwe; O'Sullivan, Gerald C.; Kasahara, Noriyuki; Gahan, Cormac G.; Francis, Kevin P.; Tangney, Mark

    2012-01-01

    The ability to track microbes in real time in vivo is of enormous value for preclinical investigations in infectious disease or gene therapy research. Bacteria present an attractive class of vector for cancer therapy, possessing a natural ability to grow preferentially within tumours following systemic administration. Bioluminescent Imaging (BLI) represents a powerful tool for use with bacteria engineered to express reporter genes such as lux. BLI is traditionally used as a 2D modality resulting in images that are limited in their ability to anatomically locate cell populations. Use of 3D diffuse optical tomography can localize the signals but still need to be combined with an anatomical imaging modality like micro-Computed Tomography (μCT) for interpretation. In this study, the non-pathogenic commensal bacteria E.coli K-12 MG1655 and Bifidobacterium breve UCC2003, or Salmonella Typhimurium SL7207 each expressing the luxABCDE operon were intravenously (IV) administered to mice bearing subcutaneous (s.c) FLuc-expressing xenograft tumours. Bacterial lux signal was detected specifically in tumours of mice post IV-administration and bioluminescence correlated with the numbers of bacteria recovered from tissue. Through whole body imaging for both lux and FLuc, bacteria and tumour cells were co-localised. 3D BLI and μCT image analysis revealed a pattern of multiple clusters of bacteria within tumours. Investigation of spatial resolution of 3D optical imaging was supported by ex vivo histological analyses. In vivo imaging of orally-administered commensal bacteria in the gastrointestinal tract (GIT) was also achieved using 3D BLI. This study demonstrates for the first time the potential to simultaneously image multiple BLI reporter genes three dimensionally in vivo using approaches that provide unique information on spatial locations. PMID:22295120

  14. Breast cancer survival in the US and Europe: a CONCORD high-resolution study

    PubMed Central

    Allemani, Claudia; Sant, Milena; Weir, Hannah K; Richardson, Lisa C; Baili, Paolo; Storm, Hans; Siesling, Sabine; Torrella-Ramos, Ana; Voogd, Adri C; Aareleid, Tiiu; Ardanaz, Eva; Berrino, Franco; Bielska-Lasota, Magdalena; Bolick, Susan; Cirilli, Claudia; Colonna, Marc; Contiero, Paolo; Cress, Rosemary; Crocetti, Emanuele; Fulton, John P; Grosclaude, Pascale; Hakulinen, Timo; Izarzugaza, M Isabel; Malmström, Per; Peignaux, Karin; Primic-Žakelj, Maja; Rachtan, Jadwiga; Diba, Chakameh Safaei; Sánchez, Maria-José; Schymura, Maria J; Shen, Tiefu; Traina, Adele; Tryggvadottir, Laufey; Tumino, Rosario; Velten, Michel; Vercelli, Marina; Wolf, Holly J; Woronoff, Anne-Sophie; Wu, Xiaocheng; Coleman, Michel P

    2015-01-01

    Breast cancer survival is reportedly higher in the US than in Europe. The first worldwide study (CONCORD) found wide international differences in age-standardised survival. The aim of this study is to explain these survival differences. Population-based data on stage at diagnosis, diagnostic procedures, treatment and follow-up were collected for about 20,000 women diagnosed with breast cancer aged 15–99 years during 1996–98 in 7 US states and 12 European countries. Age-standardised net survival and the excess hazard of death up to five years after diagnosis were estimated by jurisdiction (registry, country, European region), age and stage with flexible parametric models. Breast cancers were generally less advanced in the US than in Europe. Stage also varied less between US states than between European jurisdictions. Early, node-negative tumours were more frequent in the US (39%) than in Europe (32%), while locally advanced tumours were twice as frequent in Europe (8%), and metastatic tumours of similar frequency (5–6%). Net survival in Northern, Western and Southern Europe (82–85%) was similar to that in the US (84%), but lower in Eastern Europe (72%). For the first 3 years after diagnosis the mean excess hazard was higher in Eastern Europe than elsewhere: the difference was most marked for women aged 70–99 years, and mainly confined to women with locally advanced or metastatic tumours. Differences in breast cancer survival between Europe and the US in the late 1990s were mainly explained by lower survival in Eastern Europe, where low healthcare expenditure may have constrained the quality of treatment. PMID:22815141

  15. High Resolution Aerosol Data from MODIS Satellite for Urban Air Quality Studies

    NASA Technical Reports Server (NTRS)

    Chudnovsky, A.; Lyapustin, A.; Wang, Y.; Tang, C.; Schwartz, J.; Koutrakis, P.

    2013-01-01

    The Moderate Resolution Imaging Spectroradiometer (MODIS) provides daily global coverage, but the 10 km resolution of its aerosol optical depth (AOD) product is not suitable for studying spatial variability of aerosols in urban areas. Recently, a new Multi-Angle Implementation of Atmospheric Correction (MAIAC) algorithm was developed for MODIS which provides AOD at 1 km resolution. Using MAIAC data, the relationship between MAIAC AOD and PM(sub 2.5) as measured by the 27 EPA ground monitoring stations was investigated. These results were also compared to conventional MODIS 10 km AOD retrievals (MOD04) for the same days and locations. The coefficients of determination for MOD04 and for MAIAC are R(exp 2) =0.45 and 0.50 respectively, suggested that AOD is a reasonably good proxy for PM(sub 2.5) ground concentrations. Finally, we studied the relationship between PM(sub 2.5) and AOD at the intra-urban scale (10 km) in Boston. The fine resolution results indicated spatial variability in particle concentration at a sub-10 kilometer scale. A local analysis for the Boston area showed that the AOD-PM(sub 2.5) relationship does not depend on relative humidity and air temperatures below approximately 7 C. The correlation improves for temperatures above 7 - 16 C. We found no dependence on the boundary layer height except when the former was in the range 250-500 m. Finally, we apply a mixed effects model approach to MAIAC aerosol optical depth (AOD) retrievals from MODIS to predict PM(sub 2.5) concentrations within the greater Boston area. With this approach we can control for the inherent day-to-day variability in the AOD-PM(sub 2.5) relationship, which depends on time-varying parameters such as particle optical properties, vertical and diurnal concentration profiles and ground surface reflectance. Our results show that the model-predicted PM(sub 2.5) mass concentrations are highly correlated with the actual observations (out-of-sample R(exp 2) of 0.86). Therefore, adjustment

  16. Case study of wave breaking with high-resolution turbulence measurements with LITOS and WRF simulations

    NASA Astrophysics Data System (ADS)

    Schneider, Andreas; Söder, Jens; Gerding, Michael; Wagner, Johannes; Lübken, Franz-Josef

    2016-04-01

    Gravity waves in their final stage produce turbulence and dissipation. In the stratosphere only few studies of this phenomenon exist because the observation is technically challenging. In order to precisely infer energy dissipation rates, the viscous subrange has to be covered, which in the stratosphere lies at scales of centimetres and below. With our balloon-borne instrument LITOS (Leibniz-Institute Turbulence Observations in the Stratosphere), which has a vertical resolution below 1 mm, measurements were performed from Kiruna (68°N, 21°E) as well as from Kühlungsborn (54°N, 12°E). To characterise the atmospheric background conditions, WRF simulations driven by ECMWF reanalysis data were performed for the times of the flights. Averaged dissipation rates observed by LITOS are connected to wave signatures seen in the model. Particularly, larger dissipation rates correlate to larger amplitudes seen in the horizontal divergence or vertical winds in the model and vice versa. For one flight, a very pronounced maximum in dissipation is observed below the tropopause. It is connected to a wind reversal and dynamic instability. In the corresponding WRF simulation, turbulent kinetic energies (TKE) and amplitudes in horizontal divergence are enhanced in this region. For the other flights, no such pronounced maximum in dissipation but also no enhanced values of TKE outside of the boundary layer are observed. That means that low and moderate turbulence is not resolved in WRF, but is observed by LITOS throughout all altitudes.

  17. Mnemonic discrimination relates to perforant path integrity: An ultra-high resolution diffusion tensor imaging study.

    PubMed

    Bennett, Ilana J; Stark, Craig E L

    2016-03-01

    Pattern separation describes the orthogonalization of similar inputs into unique, non-overlapping representations. This computational process is thought to serve memory by reducing interference and to be mediated by the dentate gyrus of the hippocampus. Using ultra-high in-plane resolution diffusion tensor imaging (hrDTI) in older adults, we previously demonstrated that integrity of the perforant path, which provides input to the dentate gyrus from entorhinal cortex, was associated with mnemonic discrimination, a behavioral outcome designed to load on pattern separation. The current hrDTI study assessed the specificity of this perforant path integrity-mnemonic discrimination relationship relative to other cognitive constructs (identified using a factor analysis) and white matter tracts (hippocampal cingulum, fornix, corpus callosum) in 112 healthy adults (20-87 years). Results revealed age-related declines in integrity of the perforant path and other medial temporal lobe (MTL) tracts (hippocampal cingulum, fornix). Controlling for global effects of brain aging, perforant path integrity related only to the factor that captured mnemonic discrimination performance. Comparable integrity-mnemonic discrimination relationships were also observed for the hippocampal cingulum and fornix. Thus, whereas perforant path integrity specifically relates to mnemonic discrimination, mnemonic discrimination may be mediated by a broader MTL network.

  18. High-resolution proton NMR studies of intracellular metabolites in yeast using 13C decoupling

    NASA Astrophysics Data System (ADS)

    Sillerud, Laurel O.; Alger, Jeffry R.; Shulman, Robert G.

    The resolution and specificity of 1H NMR in studies of yeast cellular metabolism were increased by feeding a 13C-labeled substrate and observing 1H difference spectra in the presence and absence of 13C decoupling fields. [2- 13C]Acetate was utilized as a respiratory substrate in an aerobic suspension of Saccharomyces cerevisiae. The broad cellular background proton resonances are removed by the technique, leaving only signals from the protons of the substrate, or its metabolites, that are coupled to 13C. Spectra of the yeast suspension after acetate feeding show the disappearance of label from the acetate pool and the subsequent appearance of 13C in glutamate C 3 and C 4 and in aspartate C 3. These results are in accord with the known fluxes of metabolites. Selective single-frequency 13C decoupling was used to provide assignments for the difference signals. The limitations on single-frequency decoupling coming from finite decoupling fields are investigated. The technique shows a potential for application in a wide variety of systems where the resolution of the 13C spectrum may be combined with the sensitivity for proton detection to observe metabolites that have been previously unobservable.

  19. Activation of cortical areas in music execution and imagining: a high-resolution EEG study.

    PubMed

    Kristeva, Rumyana; Chakarov, Vihren; Schulte-Mönting, Jürgen; Spreer, Joachim

    2003-11-01

    Neuroimaging studies have shown that execution of a musical sequence on an instrument activates bilateral frontal opercular regions, in addition to bilateral sensorimotor and supplementary motor areas. During imagining activation of the same areas without primary sensorimotor areas was shown. We recorded EEG from 58 scalp positions to investigate the temporal sequence and the time course of activation of these areas while violin players prepared to execute, executed, prepared to imagine, or imagined a musical sequence on a violin. During the preparation for the sequence in three of seven musicians investigated the bilateral frontal opercular regions became active earlier than the motor areas and in one of them simultaneously with the motor areas. In two of the musicians a rather variable pattern of activation was observed. The frontal opercular regions were also strongly involved throughout the period of music execution or imagining. The supplementary motor area was involved in both preparation for the sequence and during execution and imagining of the sequence. The left primary sensorimotor area was involved in the preparation and termination of the musical sequence for both execution and imagining. The right sensorimotor area was strongly involved in the preparation for and during the execution of the sequence. We conclude that the bilateral frontal opercular regions are crucial in both preparation for and during music execution and imagining. They may have "mirror neurone" properties that underlie observation or imagining of one's own performance. The motor areas are differentially activated during the preparation and execution or imagining the sequence.

  20. High-resolution electron microscopical study of cyst walls of Entamoeba spp.

    PubMed

    Chávez-Munguía, Bibiana; Martínez-Palomo, Adolfo

    2011-01-01

    Knowledge of the fine structural organization, molecular composition and permeability properties of the cell surface of intestinal protozoan cysts is important to understand the biologic basis of their resistance. Recent studies on the biology of the cyst walls of Entamoeba histolytica and Entamoeba invadens have considerably advanced knowledge on the cellular processes involved in the transport and surface deposition of the main cyst wall components. Using transmission electron microscopy, cytochemistry, scanning electron microscopy and freeze-fracture techniques, we have obtained new information. In mature cysts the permeability of Entamoeba cysts is limited to small molecules not by the cyst wall, but by the plasma membrane, as demonstrated with the use of ruthenium red as an electron-dense tracer. Cell walls of E. histolytica cysts are made up of five to seven layers of unordered fibrils 7-8 nm thick. Alcian blue stains a regular mesh of fibrils approximately 4 nm thick, running perpendicularly to the cyst wall. In addition, abundant ionogenic groups are seen in cyst walls treated with cationized ferritin. In the mature cysts of E. histolytica and E. invadens small cytoplasmic vesicles with granular material were in close contact with the plasma membrane, suggesting a process of fusion and deposition of granular material to the cell wall. The plasma membrane of mature cysts is devoid of intramembrane particles when analyzed with the freeze-fracture technique. When viewed with scanning electron microscopy the surface of E. histolytica cysts clearly differs from that of Entamoeba coli and E. invadens.

  1. [Study and design on Dyson imaging spectrometer in spectral broadband with high resolution].

    PubMed

    Yan, Ling-Wei

    2014-04-01

    The paper designs and improves a telecentric imaging spectrometer, the Dyson imaging spectrometer. The optical structure of the imaging spectrometer is simple and compact, which is only composed of a hemispherical lens and a concave grating. Based on the Rowland circle and refraction theory, the broadband anastigmatic imaging condition of Dyson imaging spectrometer which is the ratio of the grating radius and hemispherical lens radius has been analyzed. By imposing this condition for two different wavelengths, the parameters of the optical system presenting low aberrations and excellent imaging quality are obtained. To make the design spectrometer more suitable for the engineering application, the paper studies the method making the detector not to attach the surface of the hemispherical lens. A design example using optimal conditions was designed to prove our theory. The Dyson imaging spectrometer of which the imaging RMS radii are less than 2.5 microm and the advanced spectrometer of which the imaging RMS radii are less than 8 microm, with NA 0.33, waveband 0.38-1.7 microm and the slit length 15 mm, have been obtained. The design method and results are more feasible and predominant, and can be applied in the areas of the industry and remote sensing.

  2. Study of CT-based positron range correction in high resolution 3D PET imaging

    NASA Astrophysics Data System (ADS)

    Cal-González, J.; Herraiz, J. L.; España, S.; Vicente, E.; Herranz, E.; Desco, M.; Vaquero, J. J.; Udías, J. M.

    2011-08-01

    Positron range limits the spatial resolution of PET images and has a different effect for different isotopes and positron propagation materials. Therefore it is important to consider it during image reconstruction, in order to obtain optimal image quality. Positron range distributions for most common isotopes used in PET in different materials were computed using the Monte Carlo simulations with PeneloPET. The range profiles were introduced into the 3D OSEM image reconstruction software FIRST and employed to blur the image either in the forward projection or in the forward and backward projection. The blurring introduced takes into account the different materials in which the positron propagates. Information on these materials may be obtained, for instance, from a segmentation of a CT image. The results of introducing positron blurring in both forward and backward projection operations was compared to using it only during forward projection. Further, the effect of different shapes of positron range profile in the quality of the reconstructed images with positron range correction was studied. For high positron energy isotopes, the reconstructed images show significant improvement in spatial resolution when positron range is taken into account during reconstruction, compared to reconstructions without positron range modeling.

  3. Photoionization study of doubly-excited helium at ultra-high resolution

    SciTech Connect

    Kaindl, G.; Schulz, K.; Domke, M.

    1997-04-01

    Ever since the pioneering work of Madden & Codling and Cooper, Fano & Prats on doubly-excited helium in the early sixties, this system may be considered as prototypical for the study of electron-electron correlations. More detailed insight into these states could be reached only much later, when improved theoretical calculations of the optically-excited {sup 1}P{sup 0} double-excitation states became available and sufficiently high energy resolution ({delta}E=4.0 meV) was achieved. This allowed a systematic investigation of the double-excitation resonances of He up to excitation energies close to the double-ionization threshold, I{sub infinity}=79.003 eV, which stimulated renewed theoretical interest into these correlated electron states. The authors report here on striking progress in energy resolution in this grazing-incidence photon-energy range of grating monochromators and its application to hitherto unobservable states of doubly-excited He. By monitoring an extremely narrow double-excitation resonance of He, with a theoretical lifetime width of less than or equal to 5 {mu}eV, a resolution of {delta}E=1.0 meV (FWHM) at 64.1 eV could be achieved. This ultra-high spectral resolution, combined with high photon flux, allowed the investigation of new Rydberg resonances below the N=3 ionization threshold, I{sub 3}, as well as a detailed comparison with ab-initio calculations.

  4. Impact of irrigations on simulated convective activity over Central Greece: A high resolution study

    NASA Astrophysics Data System (ADS)

    Kotsopoulos, S.; Tegoulias, I.; Pytharoulis, I.; Kartsios, S.; Bampzelis, D.; Karacostas, T.

    2014-12-01

    The aim of this research is to investigate the impact of irrigations in the characteristics of convective activity simulated by the non-hydrostatic Weather Research and Forecasting model with the Advanced Research dynamic solver (WRF-ARW, version 3.5.1), under different upper air synoptic conditions in central Greece. To this end, 42 cases equally distributed under the six most frequent upper air synoptic conditions, which are associated with convective activity in the region of interest, were utilized considering two different soil moisture scenarios. In the first scenario, the model was initialized with the surface soil moisture of the ECMWF analysis data that usually does not take into account the modification of soil moisture due to agricultural activity in the area of interest. In the second scenario, the soil moisture in the upper soil layers of the study area was modified to the field capacity for the irrigated cropland. Three model domains, covering Europe, the Mediterranean Sea and northern Africa (d01), the wider area of Greece (d02) and central Greece - Thessaly region (d03) are used at horizontal grid-spacings of 15km, 5km and 1km respectively. The model numerical results indicate a strong dependence of convective spatiotemporal characteristics from the soil moisture difference between the two scenarios. Acknowledgements: This research is co-financed by the European Union (European Regional Development Fund) and Greek national funds, through the action "COOPERATION 2011: Partnerships of Production and Research Institutions in Focused Research and Technology Sectors" (contract number 11SYN_8_1088 - DAPHNE) in the framework of the operational programme "Competitiveness and Entrepreneurship" and Regions in Transition (OPC II, NSRF 2007-2013).

  5. A High-Resolution Hubble Space Telescope Study of Apparent Lyman Continuum Leakers at z~3

    NASA Astrophysics Data System (ADS)

    Mostardi, R. E.; Shapley, A. E.; Steidel, C. C.; Trainor, R. F.; Reddy, N. A.; Siana, B.

    2015-09-01

    We present U336V606J125H160 follow-up Hubble Space Telescope (HST) observations of 16 z ˜ 3 candidate Lyman continuum (LyC) emitters in the HS1549+1919 field. With these data, we obtain high spatial-resolution photometric redshifts of all sub-arcsecond components of the LyC candidates in order to eliminate foreground contamination and identify robust candidates for leaking LyC emission. Of the 16 candidates, we find one object with a robust LyC detection that is not due to foreground contamination. This object (MD5) resolves into two components; we refer to the LyC-emitting component as MD5b. MD5b has an observed 1500 Å to 900 Å flux-density ratio of {({F}{UV}/{F}{LyC})}{obs}=4.0+/- 2.0, compatible with predictions from stellar population synthesis models. Assuming minimal IGM absorption, this ratio corresponds to a relative (absolute) escape fraction of {f}{esc,{rel}}{MD5{{b}}} = 75%-100% ({f}{esc,{abs}}{MD5{{b}}} = 14%-19%). The stellar population fit to MD5b indicates an age of ≲50 Myr, which is in the youngest 10% of the HST sample and the youngest third of typical z ˜ 3 Lyman break galaxies, and may be a contributing factor to its LyC detection. We obtain a revised, contamination-free estimate for the comoving specific ionizing emissivity at z = 2.85, indicating (with large uncertainties) that star-forming galaxies provide roughly the same contribution as QSOs to the ionizing background at this redshift. Our results show that foreground contamination prevents ground-based LyC studies from obtaining a full understanding of LyC emission from z ˜ 3 star-forming galaxies. Future progress in direct LyC searches is contingent upon the elimination of foreground contaminants through high spatial-resolution observations, and upon acquisition of sufficiently deep LyC imaging to probe ionizing radiation in high-redshift galaxies.

  6. High-resolution neutron diffraction study of CuNCN: New evidence of structure anomalies at low temperature

    SciTech Connect

    Jacobs, Philipp; Houben, Andreas; Dronskowski, Richard; Tchougréeff, Andrei L.

    2013-12-14

    Copper carbodiimide (CuNCN) is the nitrogen-containing analogue of cupric oxide. Based on high-resolution neutron-diffraction data, CuNCN's lattice parameters are derived as a function of the temperature. In accordance with a recent synchrotron study, a clear trend in the cell parameter a is observed accompanying the changing magnetic behavior. With decreasing temperature, a slowly decreases to a minimum at ∼100 K after which it rises again. The same trend—albeit more pronounced—is observed for the c lattice parameter at ∼35 K. The herein presented neutron powder-diffraction data also support the conjectured sequence of transitions from the high-temperature one-dimensional resonating valence-bond (RVB) state to a transient two-dimensional RVB state and eventually, at lowest temperatures, into another two-dimensional RVB state, presumably the ground state.

  7. High-Resolution Rotational Spectroscopy Study of the Smallest Sugar Dimer: Interplay of Hydrogen Bonds in the Glycolaldehyde Dimer.

    PubMed

    Zinn, Sabrina; Medcraft, Chris; Betz, Thomas; Schnell, Melanie

    2016-05-10

    Molecular recognition of carbohydrates plays an important role in nature. The aggregation of the smallest sugar, glycolaldehyde, was studied in a conformer-selective manner using high-resolution rotational spectroscopy. Two different dimer structures were observed. The most stable conformer reveals C2 -symmetry by forming two intermolecular hydrogen bonds, giving up the strong intramolecular hydrogen bonds of the monomers and thus showing high hydrogen bond selectivity. By analyzing the spectra of the (13) C and (18) O isotopologues of the dimer in natural abundance, we could precisely determine the heavy backbone structure of the dimer. Comparison to the monomer structure and the complex with water provides insight into intermolecular interactions. Despite hydrogen bonding being the dominant interaction, precise predictions from quantum-chemical calculations highly rely on the consideration of dispersion.

  8. High-resolution angle-resolved photoemission study of UN and USb; Dual character of 5f electrons

    NASA Astrophysics Data System (ADS)

    Ito, T.; Kumigashira, H.; Souma, S.; Takahashi, T.; Suzuki, T.

    2001-05-01

    We have performed high-resolution angle-resolved photoemission spectroscopy on UN and USb to study the electronic structure near the Fermi level ( EF) and the nature of U 5f electrons. We found that the pnictogen (N and Sb) p bands are fully occupied in contrast with Ce monopnictides and shows a good qualitative agreement with the band calculation by treating the U 5f states as bands. On the other hand, we have not observed dispersive U 5f bands near EF predicted by the band calculation, instead we found two non-dispersive bands near EF, which are assigned as the 5f 2-final-state multiplet indicative of localized U 5f states. The intensity of multiplet structure is stronger in USb than in UN. These results indicate the dual character of U 5f electrons and its difference between USb and UN.

  9. African Easterly Waves in 30-day High-Resolution Global Simulations: A Case Study During the 2006 NAMMA Period

    NASA Technical Reports Server (NTRS)

    Shen, Bo-Wen; Tao, Wei-Kuo; Wu, Man-Li C.

    2010-01-01

    In this study, extended -range (30 -day) high-resolution simulations with the NASA global mesoscale model are conducted to simulate the initiation and propagation of six consecutive African easterly waves (AEWs) from late August to September 2006 and their association with hurricane formation. It is shown that the statistical characteristics of individual AEWs are realistically simulated with larger errors in the 5th and 6th AEWs. Remarkable simulations of a mean African easterly jet (AEJ) are also obtained. Nine additional 30 -day experiments suggest that although land surface processes might contribute to the predictability of the AEJ and AEWs, the initiation and detailed evolution of AEWs still depend on the accurate representation of dynamic and land surface initial conditions and their time -varying nonlinear interactions. Of interest is the potential to extend the lead time for predicting hurricane formation (e.g., a lead time of up to 22 days) as the 4th AEW is realistically simulated.

  10. High-resolution neutron diffraction study of CuNCN: new evidence of structure anomalies at low temperature.

    PubMed

    Jacobs, Philipp; Houben, Andreas; Tchougréeff, Andrei L; Dronskowski, Richard

    2013-12-14

    Copper carbodiimide (CuNCN) is the nitrogen-containing analogue of cupric oxide. Based on high-resolution neutron-diffraction data, CuNCN's lattice parameters are derived as a function of the temperature. In accordance with a recent synchrotron study, a clear trend in the cell parameter a is observed accompanying the changing magnetic behavior. With decreasing temperature, a slowly decreases to a minimum at ~100 K after which it rises again. The same trend-albeit more pronounced-is observed for the c lattice parameter at ~35 K. The herein presented neutron powder-diffraction data also support the conjectured sequence of transitions from the high-temperature one-dimensional resonating valence-bond (RVB) state to a transient two-dimensional RVB state and eventually, at lowest temperatures, into another two-dimensional RVB state, presumably the ground state.

  11. High-Resolution Rotational Spectroscopy Study of the Smallest Sugar Dimer: Interplay of Hydrogen Bonds in the Glycolaldehyde Dimer.

    PubMed

    Zinn, Sabrina; Medcraft, Chris; Betz, Thomas; Schnell, Melanie

    2016-05-10

    Molecular recognition of carbohydrates plays an important role in nature. The aggregation of the smallest sugar, glycolaldehyde, was studied in a conformer-selective manner using high-resolution rotational spectroscopy. Two different dimer structures were observed. The most stable conformer reveals C2 -symmetry by forming two intermolecular hydrogen bonds, giving up the strong intramolecular hydrogen bonds of the monomers and thus showing high hydrogen bond selectivity. By analyzing the spectra of the (13) C and (18) O isotopologues of the dimer in natural abundance, we could precisely determine the heavy backbone structure of the dimer. Comparison to the monomer structure and the complex with water provides insight into intermolecular interactions. Despite hydrogen bonding being the dominant interaction, precise predictions from quantum-chemical calculations highly rely on the consideration of dispersion. PMID:27060475

  12. Antiphase Modulated Structure of Fe 2O 3(ZnO) 15Studied by High-Resolution Electron Microscopy

    NASA Astrophysics Data System (ADS)

    Li, Chunfei; Bando, Yoshio; Nakamura, Masaki; Kimizuka, Noboru

    1999-01-01

    As one of our systematic studies of the modulated structures of a series of new homologous compoundsRMO3(ZnO)m(R=Sc, In, Y, and La;M=In, Fe Ga, and Al;m=integer), this paper reports the modulated structure of Fe2O3(ZnO)15(R=Fe;M=Fe) studied by high-resolution electron microscopy. It is found that the main and satellite spots in the diffraction patterns can be indexed asha*+kb*+lc*+mq by considering a monoclinic unit cell ofa=0.57 nm,b=0.33 nm,c=4.5 nm, andβ=92° and a modulation wave vector of q=b*/34.8+c*/2. The possible space groups for the basic structure areC2,Cm, andC2/m, and the possible four-dimensional superspace groups for the modulated structure areCC21,CCmoverline1, andCC2/m1overline1. The crystal structure of Fe2O3(ZnO)15consists of Fe-O layers interleaved with 16 Fe/Zn-O layers. In the high-resolution image, the modulated structure appeared as zigzag-shaped contrasts among the Fe/Zn-O layers, where Fe is in high concentration. Compared with those of InMO3(ZnO)m(R=In;M=In, Fe and Ga) reported in our earlier paper, the special features of the present modulated structure are the half-periodicity relative shift of the neighboring zigzag-shaped contrasts and the appearance of modulation within the Fe-O layers.

  13. Local deep convection in a megacity environment: A high-resolution modeling study with a rapid refresh system

    NASA Astrophysics Data System (ADS)

    Wang, Xiaofeng; Xu, Xiaolin; Wang, Ping; Li, Jia; Zhang, Lei; Chen, Baode

    2013-04-01

    Due to a special underlying surface condition over Shanghai, a great deal of deep convection is locally developed. Because of its relatively small spatial scale, fast development and complicated movement, it's hard to monitor and predict such event in real-time by using the traditional observational network and forecast system. To forecast this kind of system, a rapid refresh cycling (1-hour) forecasting system was established based on the Weather Research and Forecasting (WRF) model and the ARPS Data Analysis System (ADAS), in which a 3-km grid size and the warm-start initialization technique are used. In this study, making use of high-resolution observations and the rapid refresh system, a deep convection weather event occurred in the afternoon of July 31, 2011 was simulated and the mechanism of initiation and development of this convective event was investigated. In the morning, due to the urban heat island effects in city, boundary layer jet stream was maintained and weakened gradually, and in the meantime, a large amount of unstable energy was accumulated. By the afternoon, due to strong land-sea breeze near the Yangtze Estuary and Southeast coastal of Shanghai, abundant water vapor was brought into the lower atmosphere over the urban area. The interaction between land-sea breeze and urban heat island effects largely enhanced the boundary layer vertical wind shear, accelerated the accumulation of instability energy and strengthened the updrafts. While the southward intrusion of weaker cold air led to strong westerly wind in the boundary layer of inland, and at the same time, the powerful easterly land-sea breeze occurred, resulting in a meso-scale surface convergence line over the central area of Shanghai, which triggered the unstable energy releasing and deep convection formed. Our study found that a high-resolution and high-frequency rapid refresh cycling system is capable to predict this kind of local deep convective weather event if a proper data

  14. Real-time, high-resolution study of nanocrystallization and fatigue cracking in a cyclically strained metallic glass.

    PubMed

    Wang, Cheng-Cai; Mao, Yun-Wei; Shan, Zhi-Wei; Dao, Ming; Li, Ju; Sun, Jun; Ma, Evan; Suresh, Subra

    2013-12-01

    Metallic glasses (MGs) exhibit greater elastic limit and stronger resistance to plastic deformation than their crystalline metal counterparts. Their capacity to withstand plastic straining is further enhanced at submicrometer length scales. For a range of microelectromechanical applications, the resistance of MGs to damage and cracking from thermal and mechanical stress or strain cycling under partial or complete constraint is of considerable scientific and technological interest. However, to our knowledge, no real-time, high-resolution transmission electron microscopy observations are available of crystallization, damage, and failure from the controlled imposition of cyclic strains or displacements in any metallic glass. Here we present the results of a unique in situ study, inside a high-resolution transmission electron microscope, of glass-to-crystal formation and fatigue of an Al-based MG. We demonstrate that cyclic straining progressively leads to nanoscale surface roughening in the highly deformed region of the starter notch, causing crack nucleation and formation of nanocrystals. The growth of these nanograins during cyclic straining impedes subsequent crack growth by bridging the crack. In distinct contrast to this fatigue behavior, only distributed nucleation of smaller nanocrystals is observed with no surface roughening under monotonic deformation. We further show through molecular dynamics simulation that these findings can be rationalized by the accumulation of strain-induced nonaffine atomic rearrangements that effectively enhances diffusion through random walk during repeated strain cycling. The present results thus provide unique insights into fundamental mechanisms of fatigue of MGs that would help shape strategies for material design and engineering applications. PMID:24255113

  15. High-Resolution Imaging Spectrometer

    NASA Technical Reports Server (NTRS)

    Dozier, Jeff; Goetz, Alexander F. H.

    1990-01-01

    Earth resources observed in greater detail. High-Resolution Imaging Spectrometer, undergoing development for use in NASA's Earth Observing System, measures reflectance of Earth's surface in visible and near-infrared wavelengths. From an orbit around Earth, instrument scans surface of Earth in 200 wavelength bands simultaneously. Produces images enabling identification of minerals in rocks and soils, important algal pigments in oceans and inland waters, changes in spectra associated with biochemistry of plant canopies, compositions of atmospheric aerosols, sizes of grains in snow, and contamination of snow by impurities that absorb visible light.

  16. High Resolution Laboratory Spectroscopy

    NASA Astrophysics Data System (ADS)

    Brünken, S.; Schlemmer, S.

    2016-05-01

    In this short review we will highlight some of the recent advancements in the field of high-resolution laboratory spectroscopy that meet the needs dictated by the advent of highly sensitive and broadband telescopes like ALMA and SOFIA. Among these is the development of broadband techniques for the study of complex organic molecules, like fast scanning conventional absorption spectroscopy based on multiplier chains, chirped pulse instrumentation, or the use of synchrotron facilities. Of similar importance is the extension of the accessible frequency range to THz frequencies, where many light hydrides have their ground state rotational transitions. Another key experimental challenge is the production of sufficiently high number densities of refractory and transient species in the laboratory, where discharges have proven to be efficient sources that can also be coupled to molecular jets. For ionic molecular species sensitive action spectroscopic schemes have recently been developed to overcome some of the limitations of conventional absorption spectroscopy. Throughout this review examples demonstrating the strong interplay between laboratory and observational studies will be given.

  17. High Resolution Doppler Imager

    NASA Technical Reports Server (NTRS)

    Hays, Paul B.

    1999-01-01

    This report summarizes the accomplishments of the High Resolution Doppler Imager (HRDI) on UARS spacecraft during the period 4/l/96 - 3/31/99. During this period, HRDI operation, data processing, and data analysis continued, and there was a high level of vitality in the HRDI project. The HRDI has been collecting data from the stratosphere, mesosphere, and lower thermosphere since instrument activation on October 1, 1991. The HRDI team has stressed three areas since operations commenced: 1) operation of the instrument in a manner which maximizes the quality and versatility of the collected data; 2) algorithm development and validation to produce a high-quality data product; and 3) scientific studies, primarily of the dynamics of the middle atmosphere. There has been no significant degradation in the HRDI instrument since operations began nearly 8 years ago. HRDI operations are fairly routine, although we have continued to look for ways to improve the quality of the scientific product, either by improving existing modes, or by designing new ones. The HRDI instrument has been programmed to collect data for new scientific studies, such as measurements of fluorescence from plants, measuring cloud top heights, and lower atmosphere H2O.

  18. Use of high-resolution measurements for the retrieval of temperature and gas-concentration profiles from outgoing infrared spectra in the presence of cirrus clouds.

    PubMed

    Huang, Xianglei L; Yung, Yuk L; Margolis, Jack S

    2003-04-20

    We explore ways in which high-spectral-resolution measurements can aid in the retrieval of atmospheric temperature and gas-concentration profiles from outgoing infrared spectra when optically thin cirrus clouds are present. Simulated outgoing spectra that contain cirrus are fitted with spectra that do not contain cirrus, and the residuals are examined. For those lines with weighting functions that peak near the same altitude as the thin cirrus, unique features are observed in the residuals. These unique features are highly sensitive to the resolution of the instrumental line shape. For thin cirrus these residual features are narrow (< or = 0.1 cm(-1)), so high spectral resolution is required for unambiguous observation. The magnitudes of these unique features are larger than the noise of modern instruments. The sensitivities of these features to cloud height and cloud optical depth are also discussed. Our sensitivity studies show that, when the errors in the estimation of temperature profiles are not large, the dominant contribution to the residuals is the misinterpretation of cirrus. An analysis that focuses on information content is also presented. An understanding of the magnitude of the effect and of its dependence on spectral resolution as well as on spectral region is important for retrieving spacecraft data and for the design of future infrared instruments for forecasting weather and monitoring greenhouse gases.

  19. High Resolution Camera for Mapping Titan Surface

    NASA Technical Reports Server (NTRS)

    Reinhardt, Bianca

    2011-01-01

    Titan, Saturn's largest moon, has a dense atmosphere and is the only object besides Earth to have stable liquids at its surface. The Cassini/Huygens mission has revealed the extraordinary breadth of geological processes shaping its surface. Further study requires high resolution imaging of the surface, which is restrained by light absorption by methane and scattering from aerosols. The Visual and Infrared Mapping Spectrometer (VIMS) onboard the Cassini spacecraft has demonstrated that Titan's surface can be observed within several windows in the near infrared, allowing us to process several regions in order to create a geological map and to determine the morphology. Specular reflections monitored on the lakes of the North Pole show little scattering at 5 microns, which, combined with the present study of Titan's northern pole area, refutes the paradigm that only radar can achieve high resolution mapping of the surface. The present data allowed us to monitor the evolution of lakes, to identify additional lakes at the Northern Pole, to examine Titan's hypothesis of non-synchronous rotation and to analyze the albedo of the North Pole surface. Future missions to Titan could carry a camera with 5 micron detectors and a carbon fiber radiator for weight reduction.

  20. Evaluation of Advanced Bionics high resolution mode.

    PubMed

    Buechner, Andreas; Frohne-Buechner, Carolin; Gaertner, Lutz; Lesinski-Schiedat, Anke; Battmer, Rolf-Dieter; Lenarz, Thomas

    2006-07-01

    The objective of this paper is to evaluate the advantages of the Advanced Bionic high resolution mode for speech perception, through a retrospective analysis. Forty-five adult subjects were selected who had a minimum experience of three months' standard mode (mean of 10 months) before switching to high resolution mode. Speech perception was tested in standard mode immediately before fitting with high resolution mode, and again after a maximum of six months high resolution mode usage (mean of two months). A significant improvement was found, between 11 and 17%, depending on the test material. The standard mode preference does not give any indication about the improvement when switching to high resolution. Users who are converted within any study achieve a higher performance improvement than those converted in the clinical routine. This analysis proves the significant benefits of high resolution mode for users, and also indicates the need for guidelines for individual optimization of parameter settings in a high resolution mode program.

  1. Parallelization and Algorithmic Enhancements of High Resolution IRAS Image Construction

    NASA Technical Reports Server (NTRS)

    Cao, Yu; Prince, Thomas A.; Tereby, Susan; Beichman, Charles A.

    1996-01-01

    The Infrared Astronomical Satellite caried out a nearly complete survey of the infrared sky, and the survey data are important for the study of many astrophysical phenomena. However, many data sets at other wavelengths have higher resolutions than that of the co-added IRAS maps, and high resolution IRAS images are strongly desired both for their own information content and their usefulness in correlation. The HIRES program was developed by the Infrared Processing and Analysis Center (IPAC) to produce high resolution (approx. 1') images from IRAS data using the Maximum Correlation Method (MCM). We describe the port of HIRES to the Intel Paragon, a massively parallel supercomputer, other software developments for mass production of HIRES images, and the IRAS Galaxy Atlas, a project to map the Galactic plane at 60 and 100(micro)m.

  2. Recollection, familiarity, and content-sensitivity in lateral parietal cortex: a high-resolution fMRI study

    PubMed Central

    Johnson, Jeffrey D.; Suzuki, Maki; Rugg, Michael D.

    2013-01-01

    Numerous studies have identified brain regions where activity is consistently correlated with the retrieval (recollection) of qualitative episodic information. This ‘core recollection network’ can be contrasted with regions where activity differs according to the contents of retrieval. The present study used high-resolution fMRI to investigate whether these putatively-distinct retrieval processes engage common versus dissociable regions. Subjects studied words with two encoding tasks and then performed a memory test in which they distinguished between recollection and different levels of recognition confidence. The fMRI data from study and test revealed several overlapping regions where activity differed according to encoding task, suggesting that content was selectively reinstated during retrieval. The majority of recollection-related regions, though, did not exhibit reinstatement effects, providing support for a core recollection network. Importantly, lateral parietal cortex demonstrated a clear dissociation, whereby recollection effects were localized to angular gyrus and confidence effects were restricted to intraparietal sulcus. Moreover, the latter region exhibited a non-monotonic pattern, consistent with a neural signal reflecting item familiarity rather than a generic form of memory strength. Together, the findings show that episodic retrieval relies on both content-sensitive and core recollective processes, and these can be differentiated from familiarity-based recognition memory. PMID:23734122

  3. High-resolution transmission electron microscopy studies of quantum wire structures grown on submicrometre gratings of V-grooves

    NASA Astrophysics Data System (ADS)

    Gustafsson, A.; Malm, J.-O.; Carlsson, A.; Vermeire, G.

    1996-11-01

    We present an extensive characterization of a quantum wire (QWR) structure using transmission electron microscopy (TEM). The structure consisted of a single GaAs layer in between AlGaAs barriers, grown on a GaAs substrate patterned with a submicrometre grating of V-grooves. For reference we also studied other QWR, as well as, quantum well (QW) samples, fabricated under similar conditions. We used bright field and dark field imaging to study the overall structure, high-resolution TEM to study the layer thickness and the interface quality, and chemical lattice imaging to study the compositional variations across the interfaces. In the QWR sample, there were mainly two distinctly different areas of the QW: on the (100) planes between the V-grooves, the QW was flat, whereas the QW on the near 0268-1242/11/11/018/img5 side walls of the V-grooves had a flat lower interface and a saw-tooth shaped upper interface. The QWRs at the bottom of the V-grooves were crescent shaped. We also observed a fundamental difference in growth of the GaAs and the AlGaAs on the side wall, where the AlGaAs formed straight interfaces, determined by high-index planes, whereas the GaAs tended to form alternating low-index planes giving a saw-tooth appearance of the GaAs QW.

  4. On the Nature of Tintinnid Loricae (Ciliophora: Spirotricha: Tintinnina): a Histochemical, Enzymatic, EDX, and High-resolution TEM Study.

    PubMed

    Agatha, Sabine; Simon, Paul

    2012-06-01

    Tintinnids (Ciliophora: Spirotricha: Tintinnina) are occasionally the dominant ciliates in the marine plankton. The tintinnid loricae are minute artworks fascinating scientists for more than 230 years, but their chemical composition remained unclear, viz., chitinous or proteinaceous substances were discussed. Since sedimenting loricae contribute to the flux of elements and organic compounds in the oceans, knowledge about their nature is necessary in assessing their ecological role. Previous techniques and new methods, e.g. enzymatic digestion and high-resolution transmission electron microscopy, are applied in the present study. A chitinous nature of the loricae is rejected by the Van-Wisselingh test and failure of chitinase digestion. Only proteins might show a resistance against strong hot bases (KOH at 160°C for ~ 40 min. in tintinnid loricae) similar to that of chitin. Actually, the presence of nitrogen in the EDX analyses and the digestion of at least some loricae by proteinase K strongly indicate a proteinaceous nature. Furthermore, the crystal lattice revealed by high-resolution TEM in Eutintinnus loricae is similar to the proteinaceous surface layer (S-layer) of archaea, and the striation recognizable in transverse sections of Eutintinnus loricae has a periodicity resembling that of the crystalline proteins in the extruded trichocysts of Paramecium and Frontonia. The proteolytic resistance of some loricae does not reject the idea of a proteinaceous nature, as proteins in S-layers of some archaea and in most naturally occurring prions show comparable reactions. The data from the present study and the literature indicate proteins in the loricae of thirteen genera. Differences in the proteolytic resistance and staining properties between genera and congeners are probably due to deviations in the protein composition and the additional substances, e.g. lipids, carbohydrates. At the present state of knowledge, correlations between lorica structure, wall texture

  5. On the Nature of Tintinnid Loricae (Ciliophora: Spirotricha: Tintinnina): a Histochemical, Enzymatic, EDX, and High-resolution TEM Study

    PubMed Central

    AGATHA, Sabine; SIMON, Paul

    2012-01-01

    Summary Tintinnids (Ciliophora: Spirotricha: Tintinnina) are occasionally the dominant ciliates in the marine plankton. The tintinnid loricae are minute artworks fascinating scientists for more than 230 years, but their chemical composition remained unclear, viz., chitinous or proteinaceous substances were discussed. Since sedimenting loricae contribute to the flux of elements and organic compounds in the oceans, knowledge about their nature is necessary in assessing their ecological role. Previous techniques and new methods, e.g. enzymatic digestion and high-resolution transmission electron microscopy, are applied in the present study. A chitinous nature of the loricae is rejected by the Van-Wisselingh test and failure of chitinase digestion. Only proteins might show a resistance against strong hot bases (KOH at 160°C for ~ 40 min. in tintinnid loricae) similar to that of chitin. Actually, the presence of nitrogen in the EDX analyses and the digestion of at least some loricae by proteinase K strongly indicate a proteinaceous nature. Furthermore, the crystal lattice revealed by high-resolution TEM in Eutintinnus loricae is similar to the proteinaceous surface layer (S-layer) of archaea, and the striation recognizable in transverse sections of Eutintinnus loricae has a periodicity resembling that of the crystalline proteins in the extruded trichocysts of Paramecium and Frontonia. The proteolytic resistance of some loricae does not reject the idea of a proteinaceous nature, as proteins in S-layers of some archaea and in most naturally occurring prions show comparable reactions. The data from the present study and the literature indicate proteins in the loricae of thirteen genera. Differences in the proteolytic resistance and staining properties between genera and congeners are probably due to deviations in the protein composition and the additional substances, e.g. lipids, carbohydrates. At the present state of knowledge, correlations between lorica structure, wall

  6. Hydrological and vegetational response to the Younger Dryas climatic oscillations: a high resolution case study from Quoyloo Meadow, Orkney, Scotland

    NASA Astrophysics Data System (ADS)

    Maas, David; Abrook, Ashley; Timms, Rhys; Matthews, Ian; Palmer, Adrian; Milner, Alice; Candy, Ian; Sachse, Dirk

    2016-04-01

    The Younger Dryas (Loch Lomond) Stadial is a well defined period of cold climate that in North West Europe punctuated the climatic amelioration during the Last Glacial - Interglacial Transition (LGIT ca. 16-8 ka). A palaeolake record from Quoyloo Meadow, Orkney Islands (N59.067, E-3.309) has been analysed for pollen and stable isotopes on biomarker lipids. n-Alkanes from terrestrial and aquatic sources are present throughout the core. The average chain length (ACL) is relatively low during the interstadial (~28.0) and shows a distinct increase during the Younger Dryas (to 29.0 +), attributed to an increase in grasses and drought resistant shrubs (e.g. Artemisia, Castañeda et al., 2009, Bunting, 1994). At the beginning of the Holocene, the ACL rapidly drops to 28.3 and from thereon gently increases again to ~29.0. There is a continued odd-over-even n-alkane predominance, although even n-alkanes are present in greater quantities in the interstadial, indicating an increasing terrestrial contribution in the Holocene. Ongoing deuterium isotope measurements of the n-alkanes will give independent evidence for palaeohydrological changes and can be compared to the other proxy evidence within the same core. Using a combination of nC29 and nC23 (terrestrial and aquatic end-members, respectively), a change in relative humidity (rH) can be qualified. This is based on the idea that terrestrial vegetation is affected by evapotranspiration processes, whereas aquatic vegetation is not (Rach et al., 2014). This data is supported by a high resolution palynological study; the contiguously sampled record demonstrates ecosystem/environmental responses to millennial-scale climatic change and allows for the possible detection of vegetation shifts at the sub-millennial scale. Vegetation aside, the pollen data can further aid in the interpretation of the recorded n-alkanes and isotopic analyses. This data is placed within a chronological framework derived from a high resolution crypto- and

  7. High-resolution headlamp

    NASA Astrophysics Data System (ADS)

    Gut, Carsten; Cristea, Iulia; Neumann, Cornelius

    2016-04-01

    The following article shall describe how human vision by night can be influenced. At first, front lighting systems that are already available on the market will be described, followed by their analysis with respect to the positive effects on traffic safety. Furthermore, how traffic safety by night can be increased since the introduction of high resolution headlamps shall be discussed.

  8. LDEF (Postflight), AO178 : A High-Resolution Study of Ultra-heavy Cosmic-Ray Nuclei, Tray D05

    NASA Technical Reports Server (NTRS)

    1990-01-01

    LDEF (Postflight), AO178 : A High-Resolution Study of Ultra-heavy Cosmic-Ray Nuclei, Tray D05 EL-1994-00311 LDEF (Postflight), AO178 : A High-Resolution Study of Ultra-heavy Cosmic-Ray Nuclei, Tray D05 The postflight photograph of the Ultra Heavy Cosmic Ray Experiment (UHCRE) was taken in SAEF II at KSC after removal of the experiment tray from the LDEF. The experiment tray flanges appear discolored by a brown stain. Outlines of experiment tray clamp blocks are clearly visible on the upper and lower tray flanges. The experiment tray holding fixture hardware covers the clamp block areas on the end flanges. The UHCRE detectors were contained in 16 peripheral LDEF trays with at least one UHCRE tray located on each row of the LDEF except row 3, row 9 and row 12. Each tray contains three cylindrical aluminum pressure vessels with an integral aluminum support structure. Each cylinder is filled with an Eccofoam insert that houses 4 UHCRE detector stacks. Each stack consist of layers of Lexan polycarbonate sheets (approximately 70) interleaved with several thin sheets of lead. Forty-seven of the 48 pressure vessels were pressurized to 1.0 bar of a dry gas mixture (oxygen, nitrogen and helium) and sealed. One of the units was left unsealed in order to investigate the effects of the vacuum environment on the detector materials. Thermal control was accomplished by attaching an aluminized Kapton thermal cover on the tray bottom (the Kapton facing the LDEF interior), placing the aluminum cylinder support structure on thermal isolators and covering the experiment with a thin (5 mil) silvered TEFLON® thermal cover. The silvered TEFLON® cover was supported by an aluminum frame, an integral part of the experiment structure, and held in place by Velcro pads selectively located on the frame and on the back of the cover. The copper colored strip extending over the trays lower flange is a copper coated pressure sensitive tape used to provide an electrical ground between the

  9. LDEF (Postflight), AO178 : A High-Resolution Study of Ultra-heavy Cosmic-Ray Nuclei, Tray C06

    NASA Technical Reports Server (NTRS)

    1990-01-01

    LDEF (Postflight), AO178 : A High-Resolution Study of Ultra-heavy Cosmic-Ray Nuclei, Tray C06 EL-1994-00206 LDEF (Postflight), AO178 : A High-Resolution Study of Ultra-heavy Cosmic-Ray Nuclei, Tray C06 The postflight photograph of the Ultra Heavy Cosmic Ray Experiment (UHCRE) was taken in SAEF II at KSC after removal of the experiment tray from the LDEF. The experiment tray flanges appear discolored by a light brown stain. Outlines of experiment tray clamp blocks are clearly visible on the lower tray flanges.The experiment tray holding fixture hardware covers the clamp block areas on the end flanges. The UHCRE detectors were contained in 16 peripheral LDEF trays with at least one UHCRE tray located on each row of the LDEF except row 3, row 9 and row 12. Each tray contains three cylindrical aluminum pressure vessels with an integral aluminum support structure. Each cylinder is filled with an Eccofoam insert that houses 4 UHCRE detector stacks. Each stack consist of layers of Lexan polycarbonate sheets (approximately 70) interleaved with several thin sheets of lead. Forty-seven of the 48 pressure vessels were pressurized to 1.0 bar of a dry gas mixture (oxygen, nitrogen and helium) and sealed. One of the units was left unsealed in order to investigate the effects of the vacuum environment on the detector materials. Thermal control was accomplished by attaching an aluminized Kapton thermal cover on the tray bottom (the Kapton facing the LDEF interior), placing the aluminum cylinder support structure on thermal isolators and covering the experiment with a thin (5 mil) silvered TEFLON® thermal cover. The silvered TEFLON® cover was supported by an aluminum frame, an integral part of the experiment structure, and held in place by Velcro pads selectively located on the frame and on the back of the cover. The copper colored strip extending over the trays upper flange is a copper coated pressure sensitive tape used to provide an electrical ground between the experiments

  10. LDEF (Postflight), AO178 : A High-Resolution Study of Ultra-heavy Cosmic-Ray Nuclei, Tray A04

    NASA Technical Reports Server (NTRS)

    1990-01-01

    LDEF (Postflight), AO178 : A High-Resolution Study of Ultra-heavy Cosmic-Ray Nuclei, Tray A04 EL-1994-00391 LDEF (Postflight), AO178 : A High-Resolution Study of Ultra-heavy Cosmic-Ray Nuclei, Tray A04 The postflight photograph of the Ultra Heavy Cosmic Ray Experiment (UHCRE) was taken in SAEF II at KSC prior to removal of the experiment tray from the LDEF. The paint dots on the experiment tray clamp blocks, originally white, appearsDE:to be discolored by a brown stain. The experiment tray flanges also appear to be coated but with a lighter colored stain. The UHCRE detectors were contained in 16 peripheral LDEF trays with at leastDE:one UHCRE tray located on each row of the LDEF except row 3, row 9 and row 12. Each tray contains three cylindrical aluminum pressure vessels with an integral aluminum support structure. Each cylinder is filled with an Eccofoam insert that houses 4 UHCRE detector stacks. Each stack consist of layers of Lexan polycarbonate sheets (approximately 70) interleaved with several thin sheets of lead. Forty-seven of the 48 pressure vessels were pressurized to 1.0 bar of a dry gas mixture (oxygen, nitrogen and helium) and sealed. One of the units was left unsealed in order to investigate the effects of the vacuum environment on the detector materials. Thermal control was accomplished by attaching an aluminized Kapton thermal cover on the tray bottom (the Kapton facing the LDEF interior), placing the aluminum cylinder support structure on thermal isolators and covering the experiment with a thin (5 mil) silvered TEFLON® thermal cover. The silvered TEFLON® cover was supported by an aluminum frame, an integral part of the experiment structure, and held in place by Velcro pads selectively located on the frame and on the back of the cover. The copper colored strip extending over the trays lower flange is a copper coated pressure sensitive tape used to provide an electrical ground between the experiments thermal cover and the LDEF structure. The

  11. LDEF (Postflight), AO178 : A High-Resolution Study of Ultra-heavy Cosmic-Ray Nuclei, Tray E02

    NASA Technical Reports Server (NTRS)

    1990-01-01

    LDEF (Postflight), AO178 : A High-Resolution Study of Ultra-heavy Cosmic-Ray Nuclei, Tray E02 EL-1994-00385 LDEF (Postflight), AO178 : A High-Resolution Study of Ultra-heavy Cosmic-Ray Nuclei, Tray E02 The postflight photograph of the Ultra Heavy Cosmic Ray Experiment (UHCRE) was taken in SAEF II at KSC prior to removal of the experiment tray from the LDEF. The white paint dot on the experiment tray clamp blocks located at the center of the trays lower and left flanges and at the right end of the trays upper flange appear to be discolored by a brown stain. The experiment tray flanges also appear to be coated but with a lighter colored stain. The UHCRE detectors were contained in 16 peripheral LDEF trays with at least one UHCRE tray located on each row of the LDEF except row 3, row 9 and row 12. Each tray contains three cylindrical aluminum pressure vessels with an integral aluminum support structure. Each cylinder is filled with an Eccofoam insert that houses 4 UHCRE detector stacks. Each stack consist of layers of Lexan polycarbonate sheets (approximately 70) interleaved with several thin sheets of lead. Forty-seven of the 48 pressure vessels were pressurized to 1.0 bar of a dry gas mixture (oxygen, nitrogen and helium) and sealed. One of the units was left unsealed in order to investigate the effects of the vacuum environment on the detector materials. Thermal control was accomplished by attaching an aluminized Kapton thermal cover on the tray bottom (the Kapton facing the LDEF interior), placing the aluminum cylinder support structure on thermal isolators and covering the experiment with a thin (5 mil) silvered TEFLON® thermal cover. The silvered TEFLON® cover was supported by an aluminum frame, an integral part of the experiment structure, and held in place by Velcro pads selectively located on the frame and on the back of the cover. The copper colored strip extending over the trays lower flange is a copper coated pressure sensitive tape used to provide an

  12. LDEF (Postflight), AO178 : A High-Resolution Study of Ultra-heavy Cosmic-Ray Nuclei, Tray A02

    NASA Technical Reports Server (NTRS)

    1990-01-01

    LDEF (Postflight), AO178 : A High-Resolution Study of Ultra-heavy Cosmic-Ray Nuclei, Tray A02 EL-1994-00387 LDEF (Postflight), AO178 : A High-Resolution Study of Ultra-heavy Cosmic-Ray Nuclei, Tray A02 The postflight photograph of the Ultra Heavy Cosmic Ray Experiment (UHCRE) was taken in SAEF II at KSC prior to removal of the experiment tray from the LDEF. The white paint dot on the experiment tray clamp blocks located at the center of the trays upper and right flanges and at the left end of the trays lower flange appear to be discolored by a brown stain. The experiment tray flanges also appear to be coated but with a lighter colored stain. The UHCRE detectors were contained in 16 peripheral LDEF trays with at least one UHCRE tray located on each row of the LDEF except row 3, row 9 and row 12. Each tray contains three cylindrical aluminum pressure vessels with an integral aluminum support structure. Each cylinder is filled with an Eccofoam insert that houses 4 UHCRE detector stacks. Each stack consist of layers of Lexan polycarbonate sheets (approximately 70) interleaved with several thin sheets of lead. Forty-seven of the 48 pressure vessels were pressurized to 1.0 bar with a dry gas mixture (oxygen, nitrogen and helium) and sealed. One of the units was left unsealed in order to investigate the effects of the vacuum environment on the detector materials. Thermal control was accomplished by attaching an aluminized Kapton thermal cover on the tray bottom (the Kapton facing the LDEF interior), placing the aluminum cylinder support structure on thermal isolators and covering the experiment with a thin (5 mil) silvered TEFLON® thermal cover. The silvered TEFLON® cover was supported by an aluminum frame, an integral part of the experiment structure, and held in place by Velcro pads selectively located on the frame and on the back of the cover. The copper colored strip extending over the trays lower flange is a copper coated pressure sensitive tape used to provide an

  13. LDEF (Postflight), AO178 : A High-Resolution Study of Ultra-heavy Cosmic-Ray Nuclei, Tray B05

    NASA Technical Reports Server (NTRS)

    1990-01-01

    LDEF (Postflight), AO178 : A High-Resolution Study of Ultra-heavy Cosmic-Ray Nuclei, Tray B05 EL-1994-00184 LDEF (Postflight), AO178 : A High-Resolution Study of Ultra-heavy Cosmic-Ray Nuclei, Tray B05 The postflight photograph of the Ultra Heavy Cosmic Ray Experiment (UHCRE) was taken in SAEF II at KSC prior to removal of the experiment tray from the LDEF. The paint dots on the experiment tray clamp blocks, originally white, appears to be discolored by a brown stain. The experiment tray flanges also appear to be coated but with a lighter colored stain. The UHCRE detectors were contained in 16 peripheral LDEF trays with at least one UHCRE tray located on each row of the LDEF except row 3, row 9 and row 12. Each tray contains three cylindrical aluminum pressure vessels with an integral aluminum support structure. Each cylinder is filled with an Eccofoam insert that houses 4 UHCRE detector stacks. Each stack consist of layers of Lexan polycarbonate sheets (approximately 70) interleaved with several thin sheets of lead. Forty-seven of the 48 pressure vessels were pressurized to 1.0 bar of a dry gas mixture (oxygen, nitrogen and helium) and sealed. One of the units was left unsealed in order to investigate the effects of the vacuum environment on the detector materials. Thermal control was accomplished by attaching an aluminized Kapton thermal cover on the tray bottom (the Kapton facing the LDEF interior), placing the aluminum cylinder support structure on thermal isolators and covering the experiment with a thin (5 mil) silvered TEFLON® thermal cover. The silvered TEFLON® cover was supported by an aluminum frame, an integral part of the experiment structure, and held in place by Velcro pads selectively located on the frame and on the back of the cover. The copper colored strip extending over the trays lower flange is a copper coated pressure sensitive tape used to provide an electrical ground between the experiments thermal cover and the LDEF structure. The UHCRE

  14. LDEF (Postflight), AO178 : A High-Resolution Study of Ultra-heavy Cosmic-Ray Nuclei, Tray C05

    NASA Technical Reports Server (NTRS)

    1990-01-01

    LDEF (Postflight), AO178 : A High-Resolution Study of Ultra-heavy Cosmic-Ray Nuclei, Tray C05 EL-1994-00205 LDEF (Postflight), AO178 : A High-Resolution Study of Ultra-heavy Cosmic-Ray Nuclei, Tray C05 The postflight photograph of the Ultra Heavy Cosmic Ray Experiment (UHCRE) was taken in SAEF II at KSC after removal of the experiment tray from the LDEF. The experiment tray flanges appear discolored by a brown stain that provides outlines of the experiment tray clamp blocks that are clearly visible on the upper and lower tray flanges.The experiment tray holding fixture hardware covers the clamp block areas on the end flanges. The UHCRE detectors were contained in 16 peripheral LDEF trays with at least one UHCRE tray located on each row of the LDEF except row 3, row 9 and row 12. Each tray contains three cylindrical aluminum pressure vessels with an integral aluminum support structure. Each cylinder is filled with an Eccofoam insert that houses 4 UHCRE detector stacks. Each stack consist of layers of Lexan polycarbonate sheets (approximately 70) interleaved with several thin sheets of lead. Forty-seven of the 48 pressure vessels were pressurized to 1.0 bar of a dry gas mixture (oxygen, nitrogen and helium) and sealed. One of the units was left unsealed in order to investigate the effects of the vacuum environment on the detector materials. Thermal control was accomplished by attaching an aluminized Kapton thermal cover on the tray bottom (the Kapton facing the LDEF interior), placing the aluminum cylinder support structure on thermal isolators and covering the experiment with a thin (5 mil) silvered TEFLON® thermal cover. The silvered TEFLON® cover was supported by an aluminum frame, an integral part of the experiment structure, and held in place by Velcro pads selectively located on the frame and on the back of the cover. The copper colored strip extending over the trays lower flange is a copper coated pressure sensitive tape used to provide an electrical ground

  15. LDEF (Flight), AO178 : A High-Resolution Study of Ultra-heavy Cosmic-Ray Nuclei, Tray A04

    NASA Technical Reports Server (NTRS)

    1990-01-01

    LDEF (Flight), AO178 : A High-Resolution Study of Ultra-heavy Cosmic-Ray Nuclei, Tray A04 EL-1994-00089 LDEF (Flight), AO178 : A High-Resolution Study of Ultra-heavy Cosmic-Ray Nuclei, Tray A04 The flight photograph of the Ultra Heavy Cosmic Ray Experiment (UHCRE) was taken while the LDEF was attached to the Orbiter's RMS arm prior to berthing in the Orbiter's cargo bay. The white paint dots on the center clamp blocks of the experiment trays left flange and lower flange appear to be discolored by a dark brown stain. The UHCRE detectors were contained in 16 peripheral LDEF trays with at least one UHCRE tray located on each row of the LDEF except row 3, row 9 and row 12. Each tray contains three cylindrical aluminum pressure vessels with an integral aluminum support structure. Each cylinder is filled with an Eccofoam insert that houses 4 UHCRE detector stacks. Each stack consist of layers of Lexan polycarbonate sheets (approximately 70) interleaved with several thin sheets of lead. Forty-seven of the 48 pressure vessels were pressurized to 1.0 bar of a dry gas mixture (oxygen, nitrogen and helium) and sealed. One of the units was left unsealed in order to investigate the effects of the vacuum environment on the detector materials. Thermal control was accomplished by attaching an aluminized Kapton thermal cover on the tray bottom (the Kapton facing the LDEF interior), placing the aluminum cylinder support structure on thermal isolators and covering the experiment with a thin (5 mil) silvered TEFLON® thermal cover. The silvered TEFLON® cover was supported by an aluminum frame, an integral part of the experiment structure, and held in place by Velcro pads selectively located on the frame and on the back of the cover. The copper colored strip extending over the trays upper flange is a copper coated pressure sensitive tape used to provide an electrical ground between the experiments thermal cover and the LDEF structure. The UHCRE thermal cover appears to be specular and

  16. LDEF (Flight), AO178 : A High-Resolution Study of Ultra-heavy Cosmic-Ray Nuclei, Tray B05

    NASA Technical Reports Server (NTRS)

    1990-01-01

    LDEF (Flight), AO178 : A High-Resolution Study of Ultra-heavy Cosmic-Ray Nuclei, Tray B05 EL-1994-00088 LDEF (Flight), AO178 : A High-Resolution Study of Ultra-heavy Cosmic-Ray Nuclei, Tray B05 The flight photograph of the Ultra Heavy Cosmic Ray Experiment (UHCRE) was taken while the LDEF was attached to the Orbiter's RMS arm prior to berthing in the Orbiter's cargo bay. The white paint dots on the center clamp block of the experiment trays lower flange appears to be discolored by a dark brown stain. The tray flanges also appear to be discolored but with a lighter stain. The UHCRE detectors were contained in 16 peripheral LDEF trays with at least one UHCRE tray located on each row of the LDEF except row 3, row 9 and row 12. Each tray contains three cylindrical aluminum pressure vessels with an integral aluminum support structure. Each cylinder is filled with an Eccofoam insert that houses 4 UHCRE detector stacks. Each stack consist of layers of Lexan polycarbonate sheets (approximately 70) interleaved with several thin sheets of lead. Forty-seven of the 48 pressure vessels were pressurized to 1.0 bar of a dry gas mixture (oxygen, nitrogen and helium) and sealed. One of the units was left unsealed in order to investigate the effects of the vacuum environment on the detector materials. Thermal control was accomplished by attaching an aluminized Kapton thermal cover on the tray bottom (the Kapton facing the LDEF interior), placing the aluminum cylinder support structure on thermal isolators and covering the experiment with a thin (5 mil) silvered TEFLON® thermal cover. The silvered TEFLON® cover was supported by an aluminum frame, an integral part of the experiment structure, and held in place by Velcro pads selectively located on the frame and on the back of the cover. The copper colored strip extending over the trays upper flange is a copper coated pressure sensitive tape used to provide an electrical ground between the experiments thermal cover and the LDEF

  17. LDEF (Flight), AO178 : A High-Resolution Study of Ultra-heavy Cosmic-Ray Nuclei, Tray E10

    NASA Technical Reports Server (NTRS)

    1990-01-01

    LDEF (Flight), AO178 : A High-Resolution Study of Ultra-heavy Cosmic-Ray Nuclei, Tray E10 EL-1994-00019 LDEF (Flight), AO178 : A High-Resolution Study of Ultra-heavy Cosmic-Ray Nuclei, Tray E10 The flight photograph of the Ultra Heavy Cosmic Ray Experiment (UHCRE) was taken while the LDEF was attached to the Orbiter's RMS arm prior to berthing in the Orbiter's cargo bay. The white paint dots on the center clamp blocks of the experiment trays left flange and lower flange appear to be slightly discolored. The UHCRE detectors were contained in 16 peripheral LDEF trays with at least one UHCRE tray located on each row of the LDEF except row 3, row 9 and row 12. Each tray contains three cylindrical aluminum pressure vessels with an integral aluminum support structure. Each cylinder is filled with an Eccofoam insert that houses 4 UHCRE detector stacks. Each stack consist of layers of Lexan polycarbonate sheets (approximately 70) interleaved with several thin sheets of lead. Forty-seven of the 48 pressure vessels were pressurized to 1.0 bar of a dry gas mixture (oxygen, nitrogen and helium) and sealed. One of the units was left unsealed in order to investigate the effects of the vacuum environment on the detector materials. Thermal control was accomplished by attaching an aluminized Kapton thermal cover on the tray bottom (the Kapton facing the LDEF interior), placing the aluminum cylinder support structure on thermal isolators and covering the experiment with a thin (5 mil) silvered TEFLON® thermal cover. The silvered TEFLON® cover was supported by an aluminum frame, an integral part of the experiment structure, and held in place by Velcro pads selectively located on the frame and on the back of the cover. The copper colored strip extending over the trays lower flange is a copper coated pressure sensitive tape used to provide an electrical ground between the experiments thermal cover and the LDEF structure. The UHCRE thermal covers surface appears to have changed from

  18. LDEF (Postflight), AO178 : A High-Resolution Study of Ultra-heavy Cosmic-Ray Nuclei, Tray A04

    NASA Technical Reports Server (NTRS)

    1990-01-01

    LDEF (Postflight), AO178 : A High-Resolution Study of Ultra-heavy Cosmic-Ray Nuclei, Tray A04 EL-1994-00272 LDEF (Postflight), AO178 : A High-Resolution Study of Ultra-heavy Cosmic-Ray Nuclei, Tray A04 The postflight photograph of the Ultra Heavy Cosmic Ray Experiment (UHCRE) was taken in SAEF II at KSC after the experiment tray was removed from the LDEF and the silvered TEFLON® thermal cover removed. The UHCRE detectors were contained in 16 peripheral LDEF trays with at least one UHCRE tray located on each row of the LDEF except row 3, row 9 and row 12. Each tray contains three cylindrical aluminum pressure vessels with an integral aluminum support structure. Each cylinder is filled with an Eccofoam insert that houses 4 UHCRE detector stacks. Each stack consist of layers of Lexan polycarbonate sheets (approximately 70) interleaved with several thin sheets of lead. Forty-seven of the 48 pressure vessels were pressurized to 1.0 bar of a dry gas mixture (oxygen, nitrogen and helium) and sealed. One of the units was left unsealed in order to investigate the effects of the vacuum environment on the detector materials. Thermal control was accomplished by attaching an aluminized Kapton thermal cover on the tray bottom (the Kapton facing the LDEF interior), placing the aluminum cylinder support structure on thermal isolators and covering the experiment with a thin (5 mil) silvered TEFLON® thermal cover. The silvered TEFLON® cover was supported by an aluminum frame, an integral part of the experiment structure, and held in place by Velcro pads selectively located on the frame and on the back of the cover. A copper coated pressure sensitive tape was used to provide an electrical ground strap between the thermal cover and the LDEF structure. All experiment hardware appears to be in prelaunch condition and securely in place. The three cylindrical pressure vessels containing the experiment detectors are shown mounted in the experiment tray with the frame for mounting the

  19. LDEF (Postflight), AO178 : A High-Resolution Study of Ultra-heavy Cosmic-Ray Nuclei, Tray F04

    NASA Technical Reports Server (NTRS)

    1990-01-01

    LDEF (Postflight), AO178 : A High-Resolution Study of Ultra-heavy Cosmic-Ray Nuclei, Tray F04 EL-1994-00171 LDEF (Postflight), AO178 : A High-Resolution Study of Ultra-heavy Cosmic-Ray Nuclei, Tray F04 The postflight photograph was taken in the SAEF II at KSC after the experiment was removed from the LDEF. The UHCRE detectors were contained in 16 peripheral LDEF trays with at least one UHCRE tray located on each row of the LDEF except row 3, row 9 and row 12. Each tray contains three cylindrical aluminum pressure vessels with an integral aluminum support structure. Each cylinder is filled with an Eccofoam insert that houses 4 UHCRE detector stacks. Each stack consist of layers of Lexan polycarbonate sheets (approximately 70) interleaved with several thin sheets of lead. Forty-seven of the 48 pressure vessels were pressurized to 1.0 bar of a dry gas mixture (oxygen, nitrogen and helium) and sealed. One of the units was left unsealed in order to investigate the effects of the vacuum environment on the detector materials. Thermal control was accomplished by attaching an aluminized Kapton thermal cover on the tray bottom (the Kapton facing the LDEF interior), placing the aluminum cylinder support structure on thermal isolators and covering the experiment with a thin (5 mil) silvered TEFLON® thermal cover. The silvered TEFLON® cover was supported by an aluminum frame, an integral part of the experiment structure, and held in place by Velcro pads selectively located on the frame and on the back of the cover. The copper colored strip extending over the trays lower flange is a copper coated pressure sensitive tape used to provide an electrical ground between the experiments thermal cover and the LDEF structure. The UHCRE thermal cover appears to be specular and intact. The circular damaged locations that appeared to to be impact points in the flight photograph are not as apparent in the reflections and is less taut cover. The wrinkled spots on the thermal cover are areas

  20. LDEF (Postflight), AO178 : A High-Resolution Study of Ultra-heavy Cosmic-Ray Nuclei, Tray E10

    NASA Technical Reports Server (NTRS)

    1990-01-01

    LDEF (Postflight), AO178 : A High-Resolution Study of Ultra-heavy Cosmic-Ray Nuclei, Tray E10 EL-1994-00162 LDEF (Postflight), AO178 : A High-Resolution Study of Ultra-heavy Cosmic-Ray Nuclei, Tray E10 The postflight photograph of the Ultra Heavy Cosmic Ray Experiment (UHCRE) was taken in the Orbiter Processing Facility during removal of the LDEF from the Orbiter's payload bay. The UHCRE detectors were contained in 16 peripheral LDEF trays with at least one UHCRE tray located on each row of the LDEF except row 3, row 9 and row 12. Each tray contains three cylindrical aluminum pressure vessels with an integral aluminum support structure. Each cylinder is filled with an Eccofoam insert that houses 4 UHCRE detector stacks. Each stack consist of layers of Lexan polycarbonate sheets (approximately 70) interleaved with several thin sheets of lead. Forty-seven of the 48 pressure vessels were pressurized to 1.0 bar of a dry gas mixture (oxygen, nitrogen and helium) and sealed. One of the units was left unsealed in order to investigate the effects of the vacuum environment on the detector materials. Thermal control was accomplished by attaching an aluminized Kapton thermal cover on the tray bottom (the Kapton facing the LDEF interior), placing the aluminum cylinder support structure on thermal isolators and covering the experiment with a thin (5 mil) silvered TEFLON® thermal cover. The silvered TEFLON® cover was supported by an aluminum frame, an integral part of the experiment structure, and held in place by Velcro pads selectively located on the frame and on the back of the cover. The copper colored strip extending over the trays lower flange is a copper coated pressure sensitive tape used to provide an electrical ground between the experiments thermal cover and the LDEF structure. The UHCRE thermal covers surface appears to have changed from specular to opaque with numerous black dots of various sizes that appear to be impact craters. Many of the craters appear to have

  1. LDEF (Postflight), AO178 : A High-Resolution Study of Ultra-heavy Cosmic-Ray Nuclei, Tray A10

    NASA Technical Reports Server (NTRS)

    1990-01-01

    LDEF (Postflight), AO178 : A High-Resolution Study of Ultra-heavy Cosmic-Ray Nuclei, Tray A10 EL-1994-00122 LDEF (Postflight), AO178 : A High-Resolution Study of Ultra-heavy Cosmic-Ray Nuclei, Tray A10 The postflight photograph of the Ultra Heavy Cosmic Ray Experiment (UHCRE) was taken in the Orbiter Processing Facility (OPF) at KSC during removal of the LDEF from the Orbiters cargo bay. The UHCRE detectors were contained in 16 peripheral LDEF trays with at least one UHCRE tray located on each row of the LDEF except row 3, row 9 and row 12. Each tray contains three cylindrical aluminum pressure vessels with an integral aluminum support structure. Each cylinder is filled with an Eccofoam insert that houses 4 UHCRE detector stacks. Each stack consist of layers of Lexan polycarbonate sheets (approximately 70) interleaved with several thin sheets of lead. Forty-seven of the 48 pressure vessels were pressurized to 1.0 bar of a dry gas mixture (oxygen, nitrogen and helium) and sealed. One of the units was left unsealed in order to investigate the effects of the vacuum environment on the detector materials. Thermal control was accomplished by attaching an aluminized Kapton thermal cover on the tray bottom (the Kapton facing the LDEF interior), placing the aluminum cylinder support structure on thermal isolators and covering the experiment with a thin (5 mil) silvered TEFLON® thermal cover. The silvered TEFLON® cover was supported by an aluminum frame, an integral part of the experiment structure, and held in place by Velcro pads selectively located on the frame and on the back of the cover. The copper colored strip extending over the trays upper flange is a copper coated pressure sensitive tape used to provide an electrical ground between the experiments thermal cover and the LDEF structure. The UHCRE thermal covers surface appears to have changed from specular to opaque (glossy white) with many black dots of various sizes that appear to be impact craters. An impact

  2. High-resolution calorimetric study of the nematic to smectic- A transition in aligned liquid crystal-aerosil gels

    NASA Astrophysics Data System (ADS)

    Cruceanu, F.; Liang, D.; Leheny, R. L.; Garland, C. W.; Iannacchione, G. S.

    2009-01-01

    High-resolution ac calorimetry has been used to study the nematic to smectic- A (N-SmA) phase transition in the liquid crystal octylcyanobiphenyl (8CB) confined in aligned colloidal aerosil gels. A stable and robust nematic alignment was achieved by repeated thermal cycling of the samples in the presence of a strong uniform magnetic field. In some ways (such as transition temperature and integrated enthalpy), the dependence of the specific heat peak associated with the N-SmA transition on the aerosil density for aligned gels is consistent with that observed in unaligned (random) gel samples. However, a power-law analysis reveals that the behavior of the critical exponent α is quite different. For random gels, α varies gradually with aerosil density, whereas we find that α for aligned gels shifts abruptly to an XY -like value for the lowest aerosil density studied and remains essentially constant as the sil density increases. This aerosil density independence of α is consistent with the critical behavior of the smectic correlation lengths obtained from an x-ray scattering study of 8CB in aligned aerosil gels. The combined calorimetric and x-ray results indicate that the role of quenched randomness in aligned gels of 8CB+sils differs significantly from that in random gels.

  3. SR instrumentation for optimized anomalous scattering and high resolution structure studies of proteins and nucleic acids (invited)

    NASA Astrophysics Data System (ADS)

    Deacon, A.; Habash, J.; Harrop, S. J.; Helliwell, J. R.; Hunter, W. N.; Leonard, G. A.; Peterson, M.; Hadener, A.; Kalb Gilboa, A. J.; Allinson, N. M.; Castelli, C.; Moon, K.; McSweeney, S.; Gonzalez, A.; Thompson, A. W.; Ealick, S.; Szebenyi, D. M.; Walter, R.

    1995-02-01

    Crystal structure solution by anomalous dispersion methods has been greatly facilitated using the rapidly tunable station 9.5 at the Daresbury SRS. Both SIROAS and MAD techniques, with IP data, have been used in the phasing of a brominated nucleotide and a seleno deaminase, respectively. The electron density maps in each case are interpretable. Throughput of projects could be improved upon with a better duty cycle detector. Another category of data collection is that at very high resolution. Detailed structure refinement pushes the limits of resolution and data quality. Station 9.5 has been used to collect high resolution (1.4 Å) native data for the protein concanavalin A. This utilized very short wavelengths (0.7 Å), the image plate, and crystal freezing. A total of 155 407 measurements from two crystals benefited from the on-line nature of the IP detector device, but a slow and quick pass are required to capture the full dynamic range of the data. There are data seen to 1.2 Å and beyond for a pure Mn substituted form of the protein, but a higher intensity still is required to actually record these data. By comparison, trials at CHESS, on a multipole wiggler (station A1) with a CCD (without image intensifier) system, yield native concanavalin A data to 0.98 Å and beyond. This demonstrates that the combination of yet higher intensity and the ease of use of a CCD offers worthwhile improvements; in this case an increase in the data by a factor of (1.4/0.98)3, thus at least doubling the data to parameter ratio for protein structure model refinement and potentially opening up direct structure determination of proteins of the size of concanavalin A (25 kDa). Finally, possibilities at ESRF and further detector developments, such as mosaic CCDs and scintillator coatings, offer further impetus for the field. These include more intense rapidly tunable beams for anomalous dispersion-based structure solution and ``ideal'' higher resolution data collection and reactivity

  4. An Elliptical Crystal Spectrometer Suitable for EXAFS Studies of Laser Compressed Materials and for High Resolution X-Ray Spectroscopy.

    PubMed

    Ridgeley, A; Goodman, D; Hall, T A

    1995-01-01

    Using an x-ray spectrometer with an elliptically curved crystal it is possible to study absorption spectra from a target placed at one focus of the ellipse using a backlighting source placed at the other focus. This principle has been used to develop a spectrometer for EXAFS studies of laser compressed materials. The backlighting source is placed at one focus of the ellipse and the laser compressed EXAFS sample at the other. Using this technique a small area of the EXAFS target can be probed, thereby minimizing any spatial variations in the compressed plasma due to nonuniformities in the laser beams. Also, the dispersive nature of the crystal ensures that it acts as a bandpass filter, so that the EXAFS sample is not probed by other x-ray wavelengths which may cause unwanted heating. Another advantage is that compressed and uncompressed EXAFS spectra can be compared on a single shot. The optical properties of the spectrometer are discussed analytically and using a computer ray-tracing program. The development and alignment of the elliptical spectrometer are discussed, and its performance using both x-ray film and a CCD detector is evaluated. The use of the elliptical spectrometer as a high-resolution x-ray instrument is presented. PMID:21307480

  5. Study of Grape Polyphenols by Liquid Chromatography-High-Resolution Mass Spectrometry (UHPLC/QTOF) and Suspect Screening Analysis

    PubMed Central

    Flamini, Riccardo; De Rosso, Mirko; Bavaresco, Luigi

    2015-01-01

    Suspect screening analysis is a targeted metabolomics method in which the identification of compounds relies on specific available information, such as their molecular formula and isotopic pattern. This method, coupled to liquid chromatography-high-resolution mass spectrometry, is effective in the study of grape metabolomics, in particular for characterization of flavonols, stilbene derivatives, and anthocyanins. For identification of compounds expected in the samples, a new database of putative compounds was expressly constructed by using the molecular information on potential metabolites of grape and wine from the literature and other electronic databases. Currently, this database contains around 1,100 compounds. The method allows identification of several hundred grape metabolites with two analyses (positive and negative ionization modes), and performing of data reprocessing using “untargeted” algorithms also provided the identification of some flavonols and resveratrol trimers and tetramers in grape for the first time. This approach can be potentially used in the study of metabolomics of varieties of other plant species. PMID:25734021

  6. Genesis of presolar diamonds: Comparative high-resolution transmission electron microscopy study of meteoritic and terrestrial nano-diamonds

    SciTech Connect

    Daulton, T.L. |; Eisenhour, D.D.; Buseck, P.R.

    1996-12-01

    Nano-diamonds isolated from acid dissolution residues of primitive carbonaceous meteorites (Allende and Murchison) were studied using high-resolution transmission electron microscopy. To discriminate among their most likely formation mechanisms, high-pressure shock-induced metamorphism or low-pressure vapor condensation. the microstructures of presolar diamond crystallites were compared to those of (terrestrial) synthesized nano-diamonds. The synthesized diamonds used for comparison in this study were produced by high-pressure shock waves generated in controlled detonations and by direct nucleation and homoepitaxial growth from the vapor phase in low-pressure chemical vapor deposition (CVD)-type processes. Microstructural features were identified that appear unique to shock metamorphism and to nucleation from the vapor phase, respectively. A comparison of these features to the microstructures found in presolar diamonds indicates that the predominant mechanism for presolar diamond formation is a vapor deposition process, suggesting a circumstellar condensation origin. A new presolar grain component has also been identified in the meteoritic residues, the (2H) hexagonal polytype of diamond (lonsdaleite). 93 refs., 17 figs., 1 tab.

  7. Estimating daily air temperature across the Southeastern United States using high-resolution satellite data: A statistical modeling study.

    PubMed

    Shi, Liuhua; Liu, Pengfei; Kloog, Itai; Lee, Mihye; Kosheleva, Anna; Schwartz, Joel

    2016-04-01

    Accurate estimates of spatio-temporal resolved near-surface air temperature (Ta) are crucial for environmental epidemiological studies. However, values of Ta are conventionally obtained from weather stations, which have limited spatial coverage. Satellite surface temperature (Ts) measurements offer the possibility of local exposure estimates across large domains. The Southeastern United States has different climatic conditions, more small water bodies and wetlands, and greater humidity in contrast to other regions, which add to the challenge of modeling air temperature. In this study, we incorporated satellite Ts to estimate high resolution (1km×1km) daily Ta across the southeastern USA for 2000-2014. We calibrated Ts-Ta measurements using mixed linear models, land use, and separate slopes for each day. A high out-of-sample cross-validated R(2) of 0.952 indicated excellent model performance. When satellite Ts were unavailable, linear regression on nearby monitors and spatio-temporal smoothing was used to estimate Ta. The daily Ta estimations were compared to the NASA's Modern-Era Retrospective Analysis for Research and Applications (MERRA) model. A good agreement with an R(2) of 0.969 and a mean squared prediction error (RMSPE) of 1.376°C was achieved. Our results demonstrate that Ta can be reliably predicted using this Ts-based prediction model, even in a large geographical area with topography and weather patterns varying considerably.

  8. Optimization study for metabolomics analysis of human sweat by liquid chromatography-tandem mass spectrometry in high resolution mode.

    PubMed

    Calderón-Santiago, M; Priego-Capote, F; Jurado-Gámez, B; Luque de Castro, M D

    2014-03-14

    Sweat has recently gained popularity as a potential tool for diagnostics and biomarker monitoring as it is a non-invasive biofluid the composition of which could be modified by certain pathologies, as is the case with cystic fibrosis, which increases chloride levels in sweat. The aim of the present study was to develop an analytical method for analysis of human sweat by liquid chromatography-mass spectrometry (LC-Q-TOF MS/MS) in high resolution mode. Thus, different sample preparation strategies and different chromatographic modes (HILIC and C18 reverse modes) were compared to check their effect on the profile of sweat metabolites. Forty-one compounds were identified by the MS/MS information obtained with a mass tolerance window below 4 ppm. Amino acids, dicarboxylic acids and other interesting metabolites such as inosine, choline, uric acid and tyramine were identified. Among the tested protocols, direct analysis after dilution was a suited option to obtain a representative snapshot of sweat metabolome. In addition, sample clean up by C18 SpinColumn SPE cartridges improved the sensitivity of most identified compounds and reduced the number of interferents. As most of the identified metabolites are involved in key biochemical pathways, this study opens new possibilities to the use of sweat as a source of metabolite biomarkers of specific disorders.

  9. Estimating daily air temperature across the Southeastern United States using high-resolution satellite data: A statistical modeling study.

    PubMed

    Shi, Liuhua; Liu, Pengfei; Kloog, Itai; Lee, Mihye; Kosheleva, Anna; Schwartz, Joel

    2016-04-01

    Accurate estimates of spatio-temporal resolved near-surface air temperature (Ta) are crucial for environmental epidemiological studies. However, values of Ta are conventionally obtained from weather stations, which have limited spatial coverage. Satellite surface temperature (Ts) measurements offer the possibility of local exposure estimates across large domains. The Southeastern United States has different climatic conditions, more small water bodies and wetlands, and greater humidity in contrast to other regions, which add to the challenge of modeling air temperature. In this study, we incorporated satellite Ts to estimate high resolution (1km×1km) daily Ta across the southeastern USA for 2000-2014. We calibrated Ts-Ta measurements using mixed linear models, land use, and separate slopes for each day. A high out-of-sample cross-validated R(2) of 0.952 indicated excellent model performance. When satellite Ts were unavailable, linear regression on nearby monitors and spatio-temporal smoothing was used to estimate Ta. The daily Ta estimations were compared to the NASA's Modern-Era Retrospective Analysis for Research and Applications (MERRA) model. A good agreement with an R(2) of 0.969 and a mean squared prediction error (RMSPE) of 1.376°C was achieved. Our results demonstrate that Ta can be reliably predicted using this Ts-based prediction model, even in a large geographical area with topography and weather patterns varying considerably. PMID:26717080

  10. A quantitative study of Langmuir-Blodgett model systems by high resolution electron energy loss vibrational spectroscopy. Spectral analysis and information depth

    NASA Astrophysics Data System (ADS)

    Weitzsacker, Cara L.; Gardella, Joseph A., Jr.; Gregoire, Chantal; Pireaux, Jean-Jacques

    1995-03-01

    Langmuir Blodgett monolayers of a series of anthroyl substituted alkanoic (fatty) acid derivatives are used as model systems to study the interaction of low energy electrons with organic polymers in high resolution electron energy loss spectrometry. The variation of structure in the series effectively places the anthroyl functionality at various depths from the monolayer vacuum surface. The HREELS analysis of these systems provides a means to probe the depth dependence of vibrational energy losses. Maximum likelihood spectral restoration was used to establish more precise and energies resulting from energy loss, with comparison to infrared and Raman spectroscopic results from the compounds. These band energies were then used as initial values for curve fitting of the original data. The results of curve resolution aided in the estimation of the relative intensity of vibrational bands specific to the functional groups in the anthroyl sidechain and the aliphatic hydrocarbon backbone of the molecules in the films. By comparing vibrational intensities normalized to the elastic peak, it is shown that bands due to CH vibrations from saturated aliphatic structures are more surface sensitive than those due to aromatic structures. The comparison of the series of samples shows how the signals from aromatic structures decrease relative to aliphatic over a range of 15 A from the vacuum surface.

  11. Exploring the Influence of Topographic Correction and SWIR Spectral Information Inclusion on Burnt Scars Detection From High Resolution EO Imagery: A Case Study Using ASTER imagery

    NASA Astrophysics Data System (ADS)

    Said, Yahia A.; Petropoulos, George; Srivastava, Prashant K.

    2014-05-01

    Information on burned area estimates is of key importance in environmental and ecological studies as well as in fire management including damage assessment and planning of post-fire recovery of affected areas. Earth Observation (EO) provides today the most efficient way in obtaining such information in a rapid, consistent and cost-effective manner. The present study aimed at exploring the effect of topographic correction to the burnt area delineation in conditions characteristic of a Mediterranean environment using ASTER high resolution multispectral remotely sensed imagery. A further objective was to investigate the potential added-value of the inclusion of the shortwave infrared (SWIR) bands in improving the retrievals of burned area cartography from the ASTER data. In particular the capability of the Maximum Likelihood (ML), the Support Vector Machines (SVMs) and Object-based Image Analysis (OBIA) classification techniques has been examined herein for the purposes of our study. As a case study is used a typical Mediterranean site on which a fire event occurred in Greece during the summer of 2007, for which post-fire ASTER imagery has been acquired. Our results indicated that the combination of topographic correction (ortho-rectification) with the inclusion of the SWIR bands returned the most accurate results in terms of burnt area mapping. In terms of image processing methods, OBIA showed the best results and found as the most promising approach for burned area mapping with least absolute difference from the validation polygon followed by SVM and ML. All in all, our study provides an important contribution to the understanding of the capability of high resolution imagery such as that from ASTER sensor and corroborates the usefulness particularly of the topographic correction as an image processing step when in delineating the burnt areas from such data. It also provides further evidence that use of EO technology can offer an effective practical tool for the

  12. Point-process high-resolution representations of heartbeat dynamics for multiscale analysis: A CHF survivor prediction study.

    PubMed

    Valenza, G; Wendt, H; Kiyono, K; Hayano, J; Watanabe, E; Yamamoto, Y; Abry, P; Barbieri, R

    2015-08-01

    Multiscale analysis of human heartbeat dynamics has been proved effective in characterizeing cardiovascular control physiology in health and disease. However, estimation of multiscale properties can be affected by the interpolation procedure used to preprocess the unevenly sampled R-R intervals derived from the ECG. To this extent, in this study we propose the estimation of wavelet coefficients and wavelet leaders on the output of inhomogeneous point process models of heartbeat dynamics. The RR interval series is modeled using probability density functions (pdfs) characterizing and predicting the time until the next heartbeat event occurs, as a linear function of the past history. Multiscale analysis is then applied to the pdfs' instantaneous first order moment. The proposed approach is tested on experimental data gathered from 57 congestive heart failure (CHF) patients by evaluating the recognition accuracy in predicting survivor and non-survivor patients, and by comparing performances from the informative point-process based interpolation and non-informative spline-based interpolation. Results demonstrate that multiscale analysis of point-process high-resolution representations achieves the highest prediction accuracy of 65.45%, proving our method as a promising tool to assess risk prediction in CHF patients. PMID:26736666

  13. High-resolution X-ray study of the multiple ionization of Pd atoms by fast oxygen ions

    NASA Astrophysics Data System (ADS)

    Czarnota, M.; Banaś, D.; Berset, M.; Chmielewska, D.; Dousse, J.-Cl.; Hoszowska, J.; Maillard, Y.-P.; Mauron, O.; Pajek, M.; Polasik, M.; Raboud, P. A.; Rzadkiewicz, J.; Słabkowska, K.; Sujkowski, Z.

    2010-04-01

    The multiple ionization of the L- and M-shells of Pd by fast oxygen ions has been studied by measuring with high-resolution the satellite structures of the Lα1,2 X-ray transitions. Relativistic multi-configuration Dirac-Fock (MCDF) calculations were used to interpret the complex X-ray spectrum, allowing to derive the number of L- and M-shell spectator vacancies at the moment of the X-ray emission. After correcting these numbers for the atomic vacancy rearrangement processes that take place prior to the X-ray emission, the ionization probabilities corresponding to the collision time were obtained. The latter were compared to predictions of the semiclassical approximation (SCA) and the geometrical model. The SCA calculations were performed using relativistic hydrogenic and self-consistent Dirac-Hartree-Fock (DHF) electronic wave functions. It was found that the use of the more realistic DHF wave functions in the SCA calculations leads to a much better description of the measured ionization probabilities for both the L- and M-shells.

  14. High resolution 23Na-nuclear magnetic resonance study of stroke-prone spontaneously hypertensive rat erythrocytes.

    PubMed

    Kwan, C Y; Seo, Y; Ito, H; Murakami, M; Watari, H

    1987-06-01

    The intracellular Na+ content of washed erythrocytes from stroke-prone spontaneously hypertensive rats (SHRSP) and Wistar-Kyoto normotensive rats (WKY) was measured by a high resolution 23Na-nuclear magnetic resonance (NMR) technique using a non-permeant aqueous shift reagent, dysprosium triethylenetetramine hexaacetic acid, Dy(TTHA)3-. The initial intracellular Na+ of freshly isolated and washed erythrocytes was very low (approximately 5 mmol/l) and increased progressively with prolonged incubation in isotonic salt solution at 37 degrees C. There was no significant difference in the erythrocyte Na+ concentration between SHRSP and WKY over the entire period of measurement, nor was any difference detected in their osmotic fragility or total cellular volume, although the osmotic fragility decreased with incubation time. The high energy phosphate metabolites were also studied in the same erythrocytes by 31P-NMR. The level of intracellular ATP decreased with incubation at 37 degrees C but showed no difference between the SHRSP and WKY samples. Inclusion of 1 mmol/l ouabain in the incubation medium substantially retarded the breakdown of intracellular ATP and resulted in a concomitant increase in intracellular Na+. However, neither the ouabain-sensitive nor the ouabain-insensitive component of Na+ influx altered in SHRSP erythrocytes compared with WKY erythrocytes in paired experiments. Our results do not support the hypothesis that altered Na+ transport, resulting in an increase in erythrocyte Na+ concentration, is associated with spontaneous hypertension. PMID:3611783

  15. Metabolomics in Lung Inflammation: A High Resolution 1H NMR Study of Mice Exposed to Silica Dust

    PubMed Central

    Hu, Jian Zhi; Rommereim, Donald N.; Minard, Kevin R.; Woodstock, Angie; Harrer, Bruce J.; Wind, Robert A.; Phipps, Richard P.; Sime, Patricia J.

    2010-01-01

    Here we report the first 1H NMR metabolomics studies on excised lungs and bronchoalveolar lavage fluid (BALF) from mice exposed to crystalline silica. High resolution 1H NMR metabolic profiling on intact excised lungs was performed using slow magic angle sample spinning (slow-MAS) 1H PASS (phase altered spinning sidebands) at a sample spinning rate of 80 Hz. Metabolic profiling on BALF was completed using fast magic angle spinning at 2kHz. Major findings are that the relative concentrations of choline, phosphocholine (PC) and glycerophosphocholine(GPC) were statistically significantly increased in silica-exposed mice compared to sham controls, indicating an altered membrane choline phospholipids metabolism (MCPM). The relative concentrations of glycogen/glucose, lactate and creatine were also statistically significantly increased in mice exposed to silica dust, suggesting that cellular energy pathways were affected by silica dust. Elevated levels of glycine, lysine, glutamate, proline and 4-hydroxyproline were also increased in exposed mice, suggesting the activation of a collagen pathway. Furthermore, metabolic profiles in mice exposed to silica dust were found to be spatially heterogeneous, in consistent with regional inflammation revealed by in vivo magnetic resonance imaging (MRI). PMID:20020862

  16. Visualizing impact structures using high-resolution LiDAR-derived DEMs: A case study of two structures in Missouri

    USGS Publications Warehouse

    Finn, Michael P.; Krizanich, Gary W.; Evans, Kevin R.; Cox, Melissa R.; Yamamoto, Kristina H.

    2015-01-01

    Evidence suggests that a crypto-explosive hypothesis and a meteorite impact hypothesis may be partly correct in explaining several anomalous geological features in the middle of the United States. We used a primary geographic information science (GIScience) technique of creating a digital elevation model (DEM) of two of these features that occur in Missouri. The DEMs were derived from airborne light detection and ranging, or LiDAR. Using these DEMs, we characterized the Crooked Creek structure in southern Crawford County and the Weaubleau structure in southeastern St. Clair County, Missouri. The mensuration and study of exposed and buried impact craters implies that the craters may have intrinsic dimensions which could only be produced by collision. The results show elevations varying between 276 and 348 m for Crooked Creek and between 220 and 290 m for Weaubleau structure. These new high- resolution DEMs are accurate enough to allow for precise measurements and better interpretations of geological structures, particularly jointing in the carbonate rocks, and they show greater definition of the central uplift area in the Weaubleau structure than publicly available DEMs.

  17. The effect of substrate topology on smectic liquid crystal alignment: A high-resolution x-ray diffraction study

    SciTech Connect

    Smela, E.

    1992-01-01

    Surface topography is theoretically predicted to affect liquid crystal alignment through mechanical interactions: elastic deformations of the director are energetically unfavorable, causing the molecules to realign to minimize the distortion energy. Octylcyanobiphenyl (8CB), a bilayer smecticA liquid crystal at room temperature, was deposited on gratings, grids, and flat surfaces, and was studied using high resolution x-ray diffraction at shallow angles of incidence. One surface of the film was in contact with air and the other was in contact with a treated glass or silicon substrate. At the air interface, surface tension forces caused the liquid crystal molecules to align perpendicularly with respect to the plane of the substrate. Competing with the LC-air interface, which is a strong aligner, a grating at the LC-substrate interface produced distortions in the smectic layering which resulted in excess elastic energy and favored alignment parallel to the substrate and the grooves. The results show that in films less than approximately 30 [mu]m thick, the homeotropic orientation was maintained throughout the film due to the constraint of perpendicular alignment at the air interface. However, for thicker films on gratings, Bragg scattering from molecules lying parallel to the grooves was observed. The free air surface was thus the strongest aligning force, followed by the surface topology, while surface anchoring was not found to play a role.

  18. The ESA-ANISAP Study: Estimate Of Troospheric Scintillation Along A LEO-LEO Link Through High Resolution Radiosonde Data

    NASA Astrophysics Data System (ADS)

    Martini, Enrica; Freni, Angelo; Facheris, Luca; Cuccoli, Fabrizio

    2013-12-01

    This work describes the procedure developed in the framework of the ESA-ANISAP study to obtain, for a given atmospheric profile, an estimate of scintillation effects in a LEO-LEO link. In this procedure, the refractive-index structure constant profiles describing the intensity of turbulence, are derived by applying the vertical gradient approach to high resolution radiosonde data. The fact that turbulence in the free atmosphere is confined to vertically thin layers is accounted for by identifying the turbulent layers through the analysis of the Richardson number profiles. Then, the derived structure constant profiles are inserted into a parametric scintillation model to create a scintillation disturbance estimate consistent with the considered atmospheric profile. In the parametric model, the troposphere is described as a spherically symmetric turbulent medium. Rytov's first iteration solution for weak fluctuations is used to derive an expression for two quantities of interest to evaluate the performances of the Normalized Differential Spectral Attenuation for the estimate of the total content of water vapour along the propagation path between two LEO satellite, namely: the variance of amplitude fluctuations of the wave and the correlation between the fluctuations at different frequencies. The influence on these quantities of some turbulence characteristics which are not known with confidence, like the outer scale length and the behaviour of the spectrum in the input range, is also investigated.

  19. An attempt to study LiH and Li{sub 2} molecules by high resolution pulsed laser spectroscopy

    SciTech Connect

    Bouloufa, Nadia; Cabaret, Louis; Cacciani, Patrice; Camus, Pierre; Pitcheev, Boris; Vetter, Raymond

    1998-12-16

    As we start a program to study alkali hydrides and dimers, we have developed a two-step photoionisation experiment on Li{sub 2} molecules based on the use of an atomic beam and two pulsed dye lasers. The first resonant step which excites the A {sup 1}{sigma}{sub u}{sup +}-X {sup 1}{sigma}{sub g}{sup +}Li{sub 2} dimer systems is a home-made cw-seeded DCM dye laser with a laser linewidth of 55 MHz (FWHM) and near the Fourier transform limit. The second step is a larger width fixed frequency UV laser which allows the photoionisation of the selectively excited molecules. The three {sup 6}Li{sub 2}, {sup 6}Li {sup 7}Li and {sup 7}Li{sub 2} spectra are recorded simultaneously by the use of a doubly-accelerating time-of-flight ion analyser. Comparison between recorded and calculated absorption spectra using Dunham parameters found in the literature is satisfactory. To develop similar pulsed high-resolution investigations in LiH, we have characterized our molecular beam by using the laser induced fluorescence (LIF) technique with a cw blue dye laser. Two Franck-Condon LiH Doppler-free resonances have been observed.

  20. [Development of a high-resolution pinhole SPECT system using dual-head gamma camera for small animal studies].

    PubMed

    Yokoi, T; Kishi, H

    1998-11-01

    We developed a high-resolution pinhole SPECT system using dual-head gamma camera (PRISM-2000XP) for small animal, and evaluated the performance of this system. Two pinhole-inserts (Pb) were mounted on the same unit, and it was not attached to the detector but the gantry of gamma camera. We designed two kinds of pinhole collimators with different rotating radii, 40 mm (Type-I) and 50 mm (Type-II). The diameter of the pinhole is 1 mm for both types. The field of view (FOV) and magnification were 45.8 mm phi and 4.25 for Type-I, 57.4 mm phi and 3.40 for Type-II, respectively. We measured full width at half maximum (FWHM) of line spread function using a 99mTc line source. Measured FWHM values were 1.65 mm using Type-I and 1.91 mm using Type-II at the center of FOV in the center slice. The volume sensitivity of this system was 8.54 kcps/MBq/ml (Type-I) and 5.68 kcps/MBq/ml (Type-II). We could observed 1.2 mm phi cold spot in the resolution phantom using Type-I. In conclusion, this system is available for SPECT measurement of small animal studies.

  1. A high-resolution cat radiation hybrid and integrated FISH mapping resource for phylogenomic studies across Felidae.

    PubMed

    Davis, Brian W; Raudsepp, Terje; Pearks Wilkerson, Alison J; Agarwala, Richa; Schäffer, Alejandro A; Houck, Marlys; Chowdhary, Bhanu P; Murphy, William J

    2009-04-01

    We describe the construction of a high-resolution radiation hybrid (RH) map of the domestic cat genome, which includes 2662 markers, translating to an estimated average intermarker distance of 939 kilobases (kb). Targeted marker selection utilized the recent feline 1.9x genome assembly, concentrating on regions of low marker density on feline autosomes and the X chromosome, in addition to regions flanking interspecies chromosomal breakpoints. Average gap (breakpoint) size between cat-human ordered conserved segments is less than 900 kb. The map was used for a fine-scale comparison of conserved syntenic blocks with the human and canine genomes. Corroborative fluorescence in situ hybridization (FISH) data were generated using 129 domestic cat BAC clones as probes, providing independent confirmation of the long-range correctness of the map. Cross-species hybridization of BAC probes on divergent felids from the genera Profelis (serval) and Panthera (snow leopard) provides further evidence for karyotypic conservation within felids, and demonstrates the utility of such probes for future studies of chromosome evolution within the cat family and in related carnivores. The integrated map constitutes a comprehensive framework for identifying genes controlling feline phenotypes of interest, and to aid in assembly of a higher coverage feline genome sequence.

  2. Study of Explosive Electron Emission from a Pin Cathode Using High Resolution Point-Projection X-Ray Radiography

    NASA Astrophysics Data System (ADS)

    Pikuz, S. A.; Shelkovenko, T. A.; Hammer, D. A.; Parkevich, E. V.; Tilikin, I. N.; Mingaleev, A. R.; Agafonov, A. V.

    2015-11-01

    Most studies of Explosive Electron Emission (EEE) are based on the idea of cathode flares developing after explosion of metal whiskers (micron scale pins) on the cathode surface. The physical state of the pin material, the spatial structure of the explosion and its origin are still a matter of conjecture. In this work we used high-resolution point projection x-ray radiography to observe micron scale pin explosion in a high-current diode. Pin cathodes made from 10-25 micron Cu or Mo wires were placed in gaps in return current circuits of hybrid X-pinches on the XP and BIN pulsers. Pin lengths were varied over a range 1-4 mm and pin-anode gaps within 0.05-3 mm. The diode current and voltage were measured. In experiments with small pin-anode gap (0.1 - 1 mm) development of an expanded dense core of the pin was observed except the pin tip with length 100-200 microns indicating significant energy deposition in the wire material. In experiments with bigger gaps there was no visible wire core expansion within the spatial resolution of the experimental technique. Work at Cornell was supported by the National Nuclear Security Administration Stewardship Sciences Academic Programs under Department of Energy Cooperative Agreement No. DE-NA0001836 and at the Lebedev Institute by the RSF grant 142200273.

  3. A high-resolution cat radiation hybrid and integrated FISH mapping resource for phylogenomic studies across Felidae.

    PubMed

    Davis, Brian W; Raudsepp, Terje; Pearks Wilkerson, Alison J; Agarwala, Richa; Schäffer, Alejandro A; Houck, Marlys; Chowdhary, Bhanu P; Murphy, William J

    2009-04-01

    We describe the construction of a high-resolution radiation hybrid (RH) map of the domestic cat genome, which includes 2662 markers, translating to an estimated average intermarker distance of 939 kilobases (kb). Targeted marker selection utilized the recent feline 1.9x genome assembly, concentrating on regions of low marker density on feline autosomes and the X chromosome, in addition to regions flanking interspecies chromosomal breakpoints. Average gap (breakpoint) size between cat-human ordered conserved segments is less than 900 kb. The map was used for a fine-scale comparison of conserved syntenic blocks with the human and canine genomes. Corroborative fluorescence in situ hybridization (FISH) data were generated using 129 domestic cat BAC clones as probes, providing independent confirmation of the long-range correctness of the map. Cross-species hybridization of BAC probes on divergent felids from the genera Profelis (serval) and Panthera (snow leopard) provides further evidence for karyotypic conservation within felids, and demonstrates the utility of such probes for future studies of chromosome evolution within the cat family and in related carnivores. The integrated map constitutes a comprehensive framework for identifying genes controlling feline phenotypes of interest, and to aid in assembly of a higher coverage feline genome sequence. PMID:18951970

  4. Metabolic profile modifications in milk after enrofloxacin administration studied by liquid chromatography coupled with high resolution mass spectrometry.

    PubMed

    Junza, A; Saurina, J; Barrón, D; Minguillón, C

    2016-08-19

    High resolution accurate mass spectrometry (HRMS) operating in full scan MS mode was used in the search and identification of metabolites in raw milk from cows medicated with enrofloxacin. Data consisting of m/z features were taken throughout the entire chromatogram of milk samples from medicated animals and were compared with blank samples. Twenty six different compounds were identified. Some of them were attributed to structures related to enrofloxacin while others were dipeptides or tripeptides. Additionally, enrofloxacin was administered in a controlled treatment for three days. Milk was collected daily from the first day of treatment and until four days after in the search for the identified compounds. The obtained data were chemometrically treated by Principal Component Analysis. Samples were classified by this method into three different groups corresponding to days 1-2, day 3 and days 4-7 considering the different concentration profile evolution of metabolites during the days studied. Tentative metabolic pathways were designed to rationalize the presence of the newly identified compounds. PMID:27425761

  5. Study of Regional Volcanic Impact on the Middle East and North Africa using high-resolution global and regional models

    NASA Astrophysics Data System (ADS)

    Osipov, Sergey; Dogar, Mohammad; Stenchikov, Georgiy

    2016-04-01

    High-latitude winter warming after strong equatorial volcanic eruptions caused by circulation changes associated with the anomalously positive phase of Arctic Oscillation is a subject of active research during recent decade. But severe winter cooling in the Middle East observed after the Mt. Pinatubo eruption of 1991, although recognized, was not thoroughly investigated. These severe regional climate perturbations in the Middle East cannot be explained by solely radiative volcanic cooling, which suggests that a contribution of forced circulation changes could be important and significant. To better understand the mechanisms of the Middle East climate response and evaluate the contributions of dynamic and radiative effects we conducted a comparative study using Geophysical Fluid Dynamics Laboratory global High Resolution Atmospheric Model (HiRAM) with the effectively "regional-model-resolution" of 25-km and the regional Weather Research and Forecasting (WRF) model focusing on the eruption of Mount Pinatubo on June 15, 1991 followed by a pronounced positive phase of the Arctic Oscillation. The WRF model has been configured over the Middle East and North Africa (MENA) region. The WRF code has been modified to interactively account for the radiative effect of volcanic aerosols. Both HiRAM and WRF capture the main features of the MENA climate response and show that in winter the dynamic effects in the Middle East prevail the direct radiative cooling from volcanic aerosols.

  6. Local-area-enhanced, high-resolution natural-color and color-infrared satellite-image mosaics of mineral districts in Afghanistan

    USGS Publications Warehouse

    Davis, Philip A.

    2012-01-01

    -reflectance values using the methods described in Davis (2006). Mosaicking the multispectral or panchromatic images started with the image with the highest sun-elevation angle and the least atmospheric scattering, which was treated as the standard image. The band-reflectance values of all other multispectral or panchromatic images within the area were sequentially adjusted to that of the standard image by determining band-reflectance correspondence between overlapping images using linear least-squares analysis. The resolution of the multispectral image mosaic was then increased to that of the panchromatic image mosaic using SPARKLE logic, which is described in Davis (2006). Each of the four-band images within each resolution-enhanced image mosaic was individually subjected to a local-area histogram stretch algorithm (described in Davis, 2007), which stretches each band's picture element based on the digital values of all picture elements within a specified radius that was usually 500 m. The final databases, which are provided in this DS, are three-band, color-composite images of the local-area-enhanced, natural-color data (the blue, green, and red wavelength bands) and color-infrared data (the green, red, and near-infrared wavelength bands). All image data were initially projected and maintained in Universal Transverse Mercator (UTM) map projection using the target area's local zone (either 41 or 42) and the WGS84 datum. Most final image mosaics were subdivided into overlapping tiles or quadrants because of the large size of the target areas. The image tiles (or quadrants) for each area of interest are provided as embedded geotiff images, which can be read and used by most geographic information system (GIS) and image-processing software. The tiff world files (tfw) are provided, even though they are generally not needed for most software to read an embedded geotiff image. Approximately one-half of the study areas have at least one subarea designated for detailed field investigations

  7. High resolution data acquisition

    DOEpatents

    Thornton, Glenn W.; Fuller, Kenneth R.

    1993-01-01

    A high resolution event interval timing system measures short time intervals such as occur in high energy physics or laser ranging. Timing is provided from a clock (38) pulse train (37) and analog circuitry (44) for generating a triangular wave (46) synchronously with the pulse train (37). The triangular wave (46) has an amplitude and slope functionally related to the time elapsed during each clock pulse in the train. A converter (18, 32) forms a first digital value of the amplitude and slope of the triangle wave at the start of the event interval and a second digital value of the amplitude and slope of the triangle wave at the end of the event interval. A counter (26) counts the clock pulse train (37) during the interval to form a gross event interval time. A computer (52) then combines the gross event interval time and the first and second digital values to output a high resolution value for the event interval.

  8. High resolution data acquisition

    DOEpatents

    Thornton, G.W.; Fuller, K.R.

    1993-04-06

    A high resolution event interval timing system measures short time intervals such as occur in high energy physics or laser ranging. Timing is provided from a clock, pulse train, and analog circuitry for generating a triangular wave synchronously with the pulse train (as seen in diagram on patent). The triangular wave has an amplitude and slope functionally related to the time elapsed during each clock pulse in the train. A converter forms a first digital value of the amplitude and slope of the triangle wave at the start of the event interval and a second digital value of the amplitude and slope of the triangle wave at the end of the event interval. A counter counts the clock pulse train during the interval to form a gross event interval time. A computer then combines the gross event interval time and the first and second digital values to output a high resolution value for the event interval.

  9. High-Resolution Autoradiography

    NASA Technical Reports Server (NTRS)

    Towe, George C; Gomberg, Henry J; Freemen, J W

    1955-01-01

    This investigation was made to adapt wet-process autoradiography to metallurgical samples to obtain high resolution of segregated radioactive elements in microstructures. Results are confined to development of the technique, which was perfected to a resolution of less than 10 microns. The radioactive samples included carbon-14 carburized iron and steel, nickel-63 electroplated samples, a powder product containing nickel-63, and tungsten-185 in N-155 alloy.

  10. Ultra high resolution tomography

    SciTech Connect

    Haddad, W.S.

    1994-11-15

    Recent work and results on ultra high resolution three dimensional imaging with soft x-rays will be presented. This work is aimed at determining microscopic three dimensional structure of biological and material specimens. Three dimensional reconstructed images of a microscopic test object will be presented; the reconstruction has a resolution on the order of 1000 A in all three dimensions. Preliminary work with biological samples will also be shown, and the experimental and numerical methods used will be discussed.

  11. High resolution X-ray computed tomography studies of Grasberg porphyry Cu-Au ores, Papua, Indonesia

    NASA Astrophysics Data System (ADS)

    Kyle, J. Richard; Mote, Alison S.; Ketcham, Richard A.

    2008-07-01

    High-resolution X-ray computed tomography (HRXCT) provides unique information of the geological and metallurgical significance for gold and related ore minerals in the supergiant Grasberg porphyry Cu-Au deposit. Digital radiographs have proved to be an effective means of screening samples for the presence of gold for HRXCT studies. Digital radiograph effectiveness is limited by the thickness of samples (typically to ≤2 cm), as well as the associated minerals. Thus, preselecting samples for gold studies using HRXCT is most effective using digital radiographs combined with assay information. Differentiating between metallic mineral grains with relatively small differences in density, e.g., bornite (5.1 g/cm3) from chalcopyrite (4.2 g/cm3), is relatively straightforward for isolated monominerallic grains or composites in a similar lower-density matrix, but difficulties are encountered with the interpretation of typical intergrown ore minerals. X-ray beam-hardening artifacts lead to inconsistency in attenuation determination, both within and among slice images, complicating quantitative processing. However, differentiation of chalcopyrite and bornite has been successful in smaller-diameter (≤22-mm) cores of Grasberg ores. Small-diameter (≤10 mm) cores of the Grasberg stockwork Cu-Au ore were analyzed using HRXCT methods scanned at the minimum spacing currently available (7.5 μm), and data reduction protocols using the Blob3D program were modified to improve the quantification of grain sizes and shapes. Grains as small as 6.5 μm have been identified. All of these grains are in direct contact with chalcopyrite, providing support for gold distribution in porphyry copper systems being a result of exsolution from copper sulfides. HRXCT scanning (±digital radiography) precisely defines the in situ location of mineral grains of interest within a sample, which then can be studied in conventional petrographic sections, and other types of analytical studies conducted, e

  12. High-resolution Fourier-transform infrared spectroscopy of the ν6 and Coriolis perturbation allowed ν10 modes of ketenimine.

    PubMed

    Bane, Michael K; Robertson, Evan G; Thompson, Christopher D; Appadoo, Dominique R T; McNaughton, Don

    2011-12-14

    High-resolution FTIR spectra of the short lived species ketenimine have been recorded in the region 700-1300 cm(-1) and over 1500 transitions of the ν(10) and ν(6) modes have been assigned. Effective rotational and centrifugal distortion parameters for the v(10) = 1 and v(6) = 1 (excluding K(a) = 5) states were determined by co-fitting transitions, and treating strong a- and c-axis Coriolis interactions between them. Other perturbations attributed to interactions with the v(8) = 2 and v(12) = 1 + v(8) = 1 dark-states were also observed and treated. The ν(10) transitions are predicted to be inherently very weak, but are enhanced by an intensity stealing effect with the highly IR active ν(6) mode. A mechanism for this intensity stealing in ketenimine is also detailed.

  13. Urban impact on air quality in RegCM/CAMx couple for MEGAPOLI project - high resolution sensitivity study

    NASA Astrophysics Data System (ADS)

    Halenka, T.; Huszar, P.; Belda, M.

    2010-09-01

    Recent studies show considerable effect of atmospheric chemistry and aerosols on climate on regional and local scale. For the purpose of qualifying and quantifying the magnitude of climate forcing due to atmospheric chemistry/aerosols on regional scale, the development of coupling of regional climate model and chemistry/aerosol model was started on the Department of Meteorology and Environmental Protection, Charles University, Prague, for the EC FP6 Project QUANTIFY and EC FP6 Project CECILIA. For this coupling, existing regional climate model and chemistry transport model have been used at very high resolution of 10km grid. Climate is calculated using RegCM while chemistry is solved by CAMx. The experiments with the couple have been prepared for EC FP7 project MEGAPOLI assessing the impact of the megacities and industrialized areas on climate. Meteorological fields generated by RCM drive CAMx transport, chemistry and a dry/wet deposition. A preprocessor utility was developed for transforming RegCM provided fields to CAMx input fields and format. New domain have been settled for MEGAPOLI purpose in 10km resolution including all the European "megacities" regions, i.e. London metropolitan area, Paris region, industrialized Ruhr area, Po valley etc. There is critical issue of the emission inventories available for 10km resolution including the urban hot-spots, TNO emissions are adopted for this sensitivity study in 10km resolution for comparison of the results with the simulation based on merged TNO emissions, i.e. basically original EMEP emissions at 50 km grid. The sensitivity test to switch on/off Paris area emissions is analysed as well. Preliminary results for year 2005 are presented and discussed to reveal whether the concept of effective emission indices could help to parameterize the urban plume effects in lower resolution models. Interactive coupling is compared to study the potential of possible impact of urban air-pollution to the urban area climate.

  14. High-resolution x-ray diffraction study of the heavy-fermion compound YbBiPt

    SciTech Connect

    Ueland, B. G.; Saunders, S. M.; Bud'ko, S. L.; Schmiedeshoff, G. M.; Canfield, P. C.; Kreyssig, A.; Goldman, A. I.

    2015-11-30

    In this study, YbBiPt is a heavy-fermion compound possessing significant short-range antiferromagnetic correlations below a temperature of T*=0.7K, fragile antiferromagnetic order below TN = 0.4K, a Kondo temperature of TK ≈ 1K, and crystalline-electric-field splitting on the order of E/kB = 1 – 10K. Whereas the compound has a face-centered-cubic lattice at ambient temperature, certain experimental data, particularly those from studies aimed at determining its crystalline-electric-field scheme, suggest that the lattice distorts at lower temperature. Here, we present results from high-resolution, high-energy x-ray diffraction experiments which show that, within our experimental resolution of ≈ 6 – 10 × 10–5 Å, no structural phase transition occurs between T = 1.5 and 50 K. In combination with results from dilatometry measurements, we further show that the compound's thermal expansion has a minimum at ≈ 18 K and a region of negative thermal expansion for 9 ≲ T ≲ 18 K. Despite diffraction patterns taken at 1.6 K which indicate that the lattice is face-centered cubic and that the Yb resides on a crystallographic site with cubic point symmetry, we demonstrate that the linear thermal expansion may be modeled using crystalline-electric-field level schemes appropriate for Yb3+ residing on a site with either cubic or less than cubic point symmetry.

  15. Fine-scale mapping of vector habitats using very high resolution satellite imagery: a liver fluke case-study.

    PubMed

    De Roeck, Els; Van Coillie, Frieke; De Wulf, Robert; Soenen, Karen; Charlier, Johannes; Vercruysse, Jozef; Hantson, Wouter; Ducheyne, Els; Hendrickx, Guy

    2014-01-01

    The visualization of vector occurrence in space and time is an important aspect of studying vector-borne diseases. Detailed maps of possible vector habitats provide valuable information for the prediction of infection risk zones but are currently lacking for most parts of the world. Nonetheless, monitoring vector habitats from the finest scales up to farm level is of key importance to refine currently existing broad-scale infection risk models. Using Fasciola hepatica, a parasite liver fluke, as a case in point, this study illustrates the potential of very high resolution (VHR) optical satellite imagery to efficiently and semi-automatically detect detailed vector habitats. A WorldView2 satellite image capable of <5m resolution was acquired in the spring of 2013 for the area around Bruges, Belgium, a region where dairy farms suffer from liver fluke infections transmitted by freshwater snails. The vector thrives in small water bodies (SWBs), such as ponds, ditches and other humid areas consisting of open water, aquatic vegetation and/or inundated grass. These water bodies can be as small as a few m2 and are most often not present on existing land cover maps because of their small size. We present a classification procedure based on object-based image analysis (OBIA) that proved valuable to detect SWBs at a fine scale in an operational and semi-automated way. The classification results were compared to field and other reference data such as existing broad-scale maps and expert knowledge. Overall, the SWB detection accuracy reached up to 87%. The resulting fine-scale SWB map can be used as input for spatial distribution modelling of the liver fluke snail vector to enable development of improved infection risk mapping and management advice adapted to specific, local farm situations.

  16. Large-scale high-resolution seismic study in the western end of the Nankai seismogenic zone

    NASA Astrophysics Data System (ADS)

    Nakanishi, A.; Kodaira, S.; Fujie, G.; Obana, K.; Takizawa, K.; Kashiwase, K.; Kaneda, Y.

    2009-12-01

    In the Nankai Trough subduction seismogenic zone, M8-class great earthquake area can be divided into three segments; they are source regions of the Nankai, Tonankai and presumed Tokai earthquakes. The Nankai and Tonankai earthquakes had often occurred simultaneously, and caused a great event. Possibility of a megathrust earthquake along the Nankai Trough from Tokai to the Hyuga-nada, east off the Kyushu Island, Japan, is recently pointed out. To understand rupture synchronization and segmentation of the Nankai megathrust earthquake, it is important to know the deep seismic image and activity in the Hyuga-nada, the western end of the Nankai seismogenic zone. To obtain the deep structure related to the rupture synchronization and segmentation in this region, the large-scale high-resolution wide-angle seismic study was conducted in Dec. 2008. In this study, 160 ocean bottom seismographs are deployed with a spacing of 5km along four seismic profiles, 830km in a total length. A tuned airgun system (7800 cu. in.) was shot every 200m along these profiles (Fig. 1). This research is part of ‘Research concerning Interaction Between the Tokai, Tonankai and Nankai Earthquakes’ funded by Ministry of Education, Culture, Sports, Science and Technology, Japan. The subducting plate interface beneath coseismic slip zone of the 1968 event (Mw7.5) is the top of the oceanic crust contacting with the old accreted sediments. The young accretionary sediments (Vp<5km/s) above the subducting Philippine Sea plate reaches a maximum thickness of ~10km, and is widely distributed landward. In the northwestern half of the slip zone of the 1968 event, the young Accretionary sediments become thin abruptly. Figure 1: Location map of seismic survey

  17. High-resolution x-ray diffraction study of the heavy-fermion compound YbBiPt

    DOE PAGES

    Ueland, B. G.; Iowa State Univ., Ames, IA; Saunders, S. M.; Iowa State Univ., Ames, IA; Bud'ko, S. L.; Iowa State Univ., Ames, IA; Schmiedeshoff, G. M.; Canfield, P. C.; Iowa State Univ., Ames, IA; Kreyssig, A.; et al

    2015-11-30

    In this study, YbBiPt is a heavy-fermion compound possessing significant short-range antiferromagnetic correlations below a temperature of T*=0.7K, fragile antiferromagnetic order below TN = 0.4K, a Kondo temperature of TK ≈ 1K, and crystalline-electric-field splitting on the order of E/kB = 1 – 10K. Whereas the compound has a face-centered-cubic lattice at ambient temperature, certain experimental data, particularly those from studies aimed at determining its crystalline-electric-field scheme, suggest that the lattice distorts at lower temperature. Here, we present results from high-resolution, high-energy x-ray diffraction experiments which show that, within our experimental resolution of ≈ 6 – 10 × 10–5 Å,more » no structural phase transition occurs between T = 1.5 and 50 K. In combination with results from dilatometry measurements, we further show that the compound's thermal expansion has a minimum at ≈ 18 K and a region of negative thermal expansion for 9 ≲ T ≲ 18 K. Despite diffraction patterns taken at 1.6 K which indicate that the lattice is face-centered cubic and that the Yb resides on a crystallographic site with cubic point symmetry, we demonstrate that the linear thermal expansion may be modeled using crystalline-electric-field level schemes appropriate for Yb3+ residing on a site with either cubic or less than cubic point symmetry.« less

  18. Detecting environmental change using time series, high resolution imagery and field work - a case study in the Sahel of Mali

    NASA Astrophysics Data System (ADS)

    Brandt, M.; Samimi, C.; Romankiewicz, C.; Spiekermann, R.

    2012-04-01

    Climatic changes and population pressure have caused major environmental change in the Sahel during the last fifty years. Many studies use coarse resolution NDVI time series such as GIMMS to detect environmental trends; however explanations for these trends remain largely unknown. We suggest a five-step methodology for the validation of trends with a case study on the Dogon Plateau, Mali. The first step is to monitor long-term trends with coarse scale time series. Instead of GIMMS, we use a combination of LTDR (derived from AVHRR) and SPOT VGT NDVI data, covering the period from 1982-today with a temporal resolution of 10 days and a spatial resolution of 5.6 km. Areas with significant trends are further analysed in a second step. Here we use a decomposed MODIS time series with a spatial resolution of 250 m. Due to the large scaled MODIS dataset, trends can be identified at a local scale / village level. Using very high resolution imagery (e.g. SPOT, Quickbird) areas of interest can be compared with pre-drought Corona-imagery. This offers a detailed overview of the environmental change at tree-level. Yet many explanations for the changes identified remain unclear. On-site field work provides information on the land use systems, vegetation composition and the current environmental condition. Still many explanations for change can only be speculated and hypothesized. For this reason, interviews with the local population are vital for providing missing details. In this case study, an area near Fiko is introduced and analysed, where significant negative NDVI-trends are observed at a coarse scale. Using the MODIS dataset, the spatial pattern shows areas with both positive and negative trends within the same area. A comparison of high resolution imagery with the Corona images show major land use changes over the past fifty years. What used to be dense bush cover has partially been converted to farmer managed agro-forestry and a significant proportion is now degraded land

  19. High Resolution Formaldehyde Photochemistry

    NASA Astrophysics Data System (ADS)

    Ernest, C. T.; Bauer, D.; Hynes, A. J.

    2010-12-01

    Formaldehyde (HCHO) is the most abundant and most important organic carbonyl compound in the atmosphere. The sources of formaldehyde are the oxidation of methane, isoprene, acetone, and other volatile organic compounds (VOCs); fossil fuel combustion; and biomass burning. The dominant loss mechanism for formaldehyde is photolysis which occurs via two pathways: (R1) HCHO + hv → HCO + H (R2) HCHO + hv → H2 + CO The first pathway (R1) is referred to as the radical channel, while the second pathway (R2) is referred to as the molecular channel. The products of both pathways play a significant role in atmospheric chemistry. The CO that is produced in the molecular channel undergoes further oxidation to produce CO2. Under atmospheric conditions, the H atom and formyl radical that are produced in the radical channel undergo rapid reactions with O2 to produce the hydroperoxyl radical (HO2) via (R3) and (R4). (R3) HCO + O2 → HO2 + CO (R4) H + O2 → HO2 Thus, for every photon absorbed, the photolysis of formaldehyde can contribute one CO2 molecule to the global greenhouse budget or two HO2 radicals to the tropospheric HOx (OH + HO2) cycle. The HO2 radicals produced during formaldehyde photolysis have also been implicated in the formation of photochemical smog. The HO2 radicals act as radical chain carriers and convert NO to NO2, which ultimately results in the catalytic production of O3. Constraining the yield of HO2 produced via HCHO photolysis is essential for improving tropospheric chemistry models. In this study, both the absorption cross section and the quantum yield of the radical channel (R1) were measured at high resolution over the tropospherically relevant wavelength range 304-330 nm. For the cross section measurements a narrow linewidth Nd:YAG pumped dye laser was used with a multi-pass cell. Partial pressures of HCHO were kept below 0.3 torr. Simultaneous measurement of OH LIF in a flame allowed absolute calibration of the wavelength scale. Pressure

  20. LDEF (Postflight), AO178 : A High-Resolution Study of Ultra-heavy Cosmic-Ray Nuclei, Tray C11

    NASA Technical Reports Server (NTRS)

    1990-01-01

    LDEF (Postflight), AO178 : A High-Resolution Study of Ultra-heavy Cosmic-Ray Nuclei, Tray C11 EL-1994-00299 LDEF (Postflight), AO178 : A High-Resolution Study of Ultra-heavy Cosmic-Ray Nuclei, Tray C11 The postflight photograph of the Ultra Heavy Cosmic Ray Experiment (UHCRE) was taken in SAEF II at KSC after removal of the experiment tray from the LDEF. The experiment tray flanges appear discolored by a light brown stain. Outlines of experiment tray clamp blocks are faint but visible on the upper and lower experiment tray flanges.The experiment tray holding fixture hardware covers the clamp block areas on the end flanges. The UHCRE detectors were contained in 16 peripheral LDEF trays with at least one UHCRE tray located on each row of the LDEF except row 3, row 9 and row 12. Each tray contains three cylindrical aluminum pressure vessels with an integral aluminum support structure. Each cylinder is filled with an Eccofoam insert that houses 4 UHCRE detector stacks. Each stack consist of layers of Lexan polycarbonate sheets (approximately 70) interleaved with several thin sheets of lead. Forty-seven of the 48 pressure vessels were pressurized to 1.0 bar of a dry gas mixture (oxygen, nitrogen and helium) and sealed. One of the units was left unsealed in order to investigate the effects of the vacuum environment on the detector materials. Thermal control was accomplished by attaching an aluminized Kapton thermal cover on the tray bottom (the Kapton facing the LDEF interior), placing the aluminum cylinder support structure on thermal isolators and covering the experiment with a thin (5 mil) silvered TEFLON® thermal cover. The silvered TEFLON® cover was supported by an aluminum frame, an integral part of the experiment structure, and held in place by Velcro pads selectively located on the frame and on the back of the cover. The copper colored strip extending over the trays lower flange is a copper coated pressure sensitive tape used to provide an electrical ground

  1. LDEF (Postflight), AO178 : A High-Resolution Study of Ultra-heavy Cosmic-Ray Nuclei, Tray D01

    NASA Technical Reports Server (NTRS)

    1990-01-01

    LDEF (Postflight), AO178 : A High-Resolution Study of Ultra-heavy Cosmic-Ray Nuclei, Tray D01 EL-1994-00188 LDEF (Postflight), AO178 : A High-Resolution Study of Ultra-heavy Cosmic-Ray Nuclei, Tray D01 The postflight photograph of the Ultra Heavy Cosmic Ray Experiment (UHCRE) was taken in SAEF II at KSC prior to removal of the experiment tray from the LDEF. The white paint dot on the experiment tray clamp block located at the center of the trays lower flange appears to be discolored by a brown stain. The experiment trays lower flange also appear to be coated but with a lighter colored stain. The white paint dots on clamp blocks at each end of the trays upper flange appear to be discolored very little. The UHCRE detectors were contained in 16 peripheral LDEF trays with at least one UHCRE tray located on each row of the LDEF except row 3, row 9 and row 12. Each tray contains three cylindrical aluminum pressure vessels with an integral aluminum support structure. Each cylinder is filled with an Eccofoam insert that houses 4 UHCRE detector stacks. Each stack consist of layers of Lexan polycarbonate sheets (approximately 70) interleaved with several thin sheets of lead. Forty-seven of the 48 pressure vessels were pressurized to 1.0 bar of a dry gas mixture (oxygen, nitrogen and helium) and sealed. One of the units was left unsealed in order to investigate the effects of the vacuum environment on the detector materials. Thermal control was accomplished by attaching an aluminized Kapton thermal cover on the tray bottom (the Kapton facing the LDEF interior), placing the aluminum cylinder support structure on thermal isolators and covering the experiment with a thin (5 mil) silvered TEFLON® thermal cover. The silvered TEFLON® cover was supported by an aluminum frame, an integral part of the experiment structure, and held in place by Velcro pads selectively located on the frame and on the back of the cover. The copper colored strip extending over the trays lower flange is

  2. LDEF (Postflight), AO178 : A High-Resolution Study of Ultra-heavy Cosmic-Ray Nuclei, Tray C08

    NASA Technical Reports Server (NTRS)

    1990-01-01

    LDEF (Postflight), AO178 : A High-Resolution Study of Ultra-heavy Cosmic-Ray Nuclei, Tray C08 EL-1994-00212 LDEF (Postflight), AO178 : A High-Resolution Study of Ultra-heavy Cosmic-Ray Nuclei, Tray C08 The postflight photograph of the Ultra Heavy Cosmic Ray Experiment (UHCRE) was taken in SAEF II at KSC after removal of the experiment tray from the LDEF. The experiment tray flanges appear discolored by a brown stain. Outlines of experiment tray clamp blocks are clearly visible on the upper and lower experiment tray flanges.The experiment tray holding fixture hardware covers the clamp block areas on the end flanges. The UHCRE detectors were contained in 16 peripheral LDEF trays with at least one UHCRE tray located on each row of the LDEF except row 3, row 9 and row 12. Each tray contains three cylindrical aluminum pressure vessels with an integral aluminum support structure. Each cylinder is filled with an Eccofoam insert that houses 4 UHCRE detector stacks. Each stack consist of layers of Lexan polycarbonate sheets (approximately 70) interleaved with several thin sheets of lead. Forty-seven of the 48 pressure vessels were pressurized to 1.0 bar of a dry gas mixture (oxygen, nitrogen and helium) and sealed. One of the units was left unsealed in order to investigate the effects of the vacuum environment on the detector materials. Thermal control was accomplished by attaching an aluminized Kapton thermal cover on the tray bottom (the Kapton facing the LDEF interior), placing the aluminum cylinder support structure on thermal isolators and covering the experiment with a thin (5 mil) silvered TEFLON® thermal cover. The silvered TEFLON® cover was supported by an aluminum frame, an integral part of the experiment structure, and held in place by Velcro pads selectively located on the frame and on the back of the cover. The copper colored strip extending over the trays lower flange is a copper coated pressure sensitive tape used to provide an electrical ground between the

  3. LDEF (Postflight), AO178 : A High-Resolution Study of Ultra-heavy Cosmic-Ray Nuclei, Tray D07

    NASA Technical Reports Server (NTRS)

    1990-01-01

    LDEF (Postflight), AO178 : A High-Resolution Study of Ultra-heavy Cosmic-Ray Nuclei, Tray D07 EL-1994-00207 LDEF (Postflight), AO178 : A High-Resolution Study of Ultra-heavy Cosmic-Ray Nuclei, Tray D07 The postflight photograph of the Ultra Heavy Cosmic Ray Experiment (UHCRE) was taken in SAEF II at KSC after removal of the experiment tray from the LDEF. The experiment tray flanges appear to be discolored by a light brown stain. An outline of experiment tray clamp block locations is clearly visible on the experiment trays upper flange and to a lesser extent on its lower flange. The holding fixture hardware covers the clamp block areas on the end flanges. The UHCRE detectors were contained in 16 peripheral LDEF trays with at least one UHCRE tray located on each row of the LDEF except row 3, row 9 and row 12. Each tray contains three cylindrical aluminum pressure vessels with an integral aluminum support structure. Each cylinder is filled with an Eccofoam insert that houses 4 UHCRE detector stacks. Each stack consist of layers of Lexan polycarbonate sheets (approximately 70) interleaved with several thin sheets of lead. Forty-seven of the 48 pressure vessels were pressurized to 1.0 bar of a dry gas mixture (oxygen, nitrogen and helium) and sealed. One of the units was left unsealed in order to investigate the effects of the vacuum environment on the detector materials. Thermal control was accomplished by attaching an aluminized Kapton thermal cover on the tray bottom (the Kapton facing the LDEF interior), placing the aluminum cylinder support structure on thermal isolators and covering the experiment with a thin (5 mil) silvered TEFLON® thermal cover. The silvered TEFLON® cover was supported by an aluminum frame, an integral part of the experiment structure, and held in place by Velcro pads selectively located on the frame and on the back of the cover. The copper colored strip extending over the trays lower flange is a copper coated pressure sensitive tape used to

  4. LDEF (Flight), AO178 : A High-Resolution Study of Ultra-heavy Cosmic-Ray Nuclei, Tray D05

    NASA Technical Reports Server (NTRS)

    1990-01-01

    LDEF (Flight), AO178 : A High-Resolution Study of Ultra-heavy Cosmic-Ray Nuclei, Tray D05 EL-1994-00038 LDEF (Flight), AO178 : A High-Resolution Study of Ultra-heavy Cosmic-Ray Nuclei, Tray D05 The flight photograph of the Ultra Heavy Cosmic Ray Experiment (UHCRE) was taken while the LDEF was attached to the Orbiter's RMS arm prior to berthing in the Orbiter's cargo bay. The white paint dots on the center clamp block of the experiment trays upper flange and on the tray clamp blocks at each end of the trays lower flange appear to be discolored by a brown stain. The experiment tray flanges also appear to be discolored by the stain. The UHCRE detectors were contained in 16 peripheral LDEF trays with at least one UHCRE tray located on each row of the LDEF except row 3, row 9 and row 12. Each tray contains three cylindrical aluminum pressure vessels with an integral aluminum support structure. Each cylinder is filled with an Eccofoam insert that houses 4 UHCRE detector stacks. Each stack consist of layers of Lexan polycarbonate sheets (approximately 70) interleaved with several thin sheets of lead. Forty-seven of the 48 pressure vessels were pressurized to 1.0 bar of a dry gas mixture (oxygen, nitrogen and helium) and sealed. One of the units was left unsealed in order to investigate the effects of the vacuum environment on the detector materials. Thermal control was accomplished by attaching an aluminized Kapton thermal cover on the tray bottom (the Kapton facing the LDEF interior), placing the aluminum cylinder support structure on thermal isolators and covering the experiment with a thin (5 mil) silvered TEFLON® thermal cover. The silvered TEFLON® cover was supported by an aluminum frame, an integral part of the experiment structure, and held in place by Velcro pads selectively located on the frame and on the back of the cover. The copper colored strip extending over the trays lower flange is a copper coated pressure sensitive tape used to provide an electrical

  5. LDEF (Flight), AO178 : A High-Resolution Study of Ultra-heavy Cosmic-Ray Nuclei, Tray B07

    NASA Technical Reports Server (NTRS)

    1990-01-01

    LDEF (Flight), AO178 : A High-Resolution Study of Ultra-heavy Cosmic-Ray Nuclei, Tray B07 EL-1994-00087 LDEF (Flight), AO178 : A High-Resolution Study of Ultra-heavy Cosmic-Ray Nuclei, Tray B07 The flight photograph of the Ultra Heavy Cosmic Ray Experiment (UHCRE) was taken while the LDEF was attached to the Orbiter's RMS arm prior to berthing in the Orbiter's cargo bay. The white paint dots on the center clamp blocks of the experiment trays left flange and lower flange appear to be slightly discolored but the paint dot on the clamp block located at the right end of the upper flange appears to be stained less. The UHCRE detectors were contained in 16 peripheral LDEF trays with at least one UHCRE tray located on each row of the LDEF except row 3, row 9 and row 12. Each tray contains three cylindrical aluminum pressure vessels with an integral aluminum support structure. Each cylinder is filled with an Eccofoam insert that houses 4 UHCRE detector stacks. Each stack consist of layers of Lexan polycarbonate sheets (approximately 70) interleaved with several thin sheets of lead. Forty-seven of the 48 pressure vessels were pressurized to 1.0 bar of a dry gas mixture (oxygen, nitrogen and helium) and sealed. One of the units was left unsealed in order to investigate the effects of the vacuum environment on the detector materials. Thermal control was accomplished by attaching an aluminized Kapton thermal cover on the tray bottom (the Kapton facing the LDEF interior), placing the aluminum cylinder support structure on thermal isolators and covering the experiment with a thin (5 mil) silvered TEFLON® thermal cover. The silvered TEFLON® cover was supported by an aluminum frame, an integral part of the experiment structure, and held in place by Velcro pads selectively located on the frame and on the back of the cover. The copper colored strip extending over the trays lower flange is a copper coated pressure sensitive tape used to provide an electrical ground between the

  6. LDEF (Flight), AO178 : A High-Resolution Study of Ultra-heavy Cosmic-Ray Nuclei, Tray D01

    NASA Technical Reports Server (NTRS)

    1990-01-01

    LDEF (Flight), AO178 : A High-Resolution Study of Ultra-heavy Cosmic-Ray Nuclei, Tray D01 EL-1994-00134 LDEF (Flight), AO178 : A High-Resolution Study of Ultra-heavy Cosmic-Ray Nuclei, Tray D01 The flight photograph of the Ultra Heavy Cosmic Ray Experiment (UHCRE) was taken while the LDEF was attached to the Orbiter's RMS arm prior to berthing in the Orbiter's cargo bay. The paint dot , originally white, on the experiment tray clamp block located at the center of the trays lower flange appears to be discolored by a brown stain. The experiment trays lower flange also appears to be coated but with a much lighter stain. The paint dots on clamp blocks at each end of the trays upper flange appear to be discolored very little. The UHCRE detectors were contained in 16 peripheral LDEF trays with at least one UHCRE tray located on each row of the LDEF except row 3, row 9 and row 12. Each tray contains three cylindrical aluminum pressure vessels with an integral aluminum support structure. Each cylinder is filled with an Eccofoam insert that houses 4 UHCRE detector stacks. Each stack consist of layers of Lexan polycarbonate sheets (approximately 70) interleaved with several thin sheets of lead. Forty-seven of the 48 pressure vessels were pressurized to 1.0 bar of a dry gas mixture (oxygen, nitrogen and helium) and sealed. One of the units was left unsealed in order to investigate the effects of the vacuum environment on the detector materials. Thermal control was accomplished by attaching an aluminized Kapton thermal cover on the tray bottom (the Kapton facing the LDEF interior), placing the aluminum cylinder support structure on thermal isolators and covering the experiment with a thin (5 mil) silvered TEFLON® thermal cover. The silvered TEFLON® cover was supported by an aluminum frame, an integral part of the experiment structure, and held in place by Velcro pads selectively located on the frame and on the back of the cover. The copper colored strip extending over the

  7. LDEF (Flight), AO178 : A High-Resolution Study of Ultra-heavy Cosmic-Ray Nuclei, Tray D07

    NASA Technical Reports Server (NTRS)

    1990-01-01

    LDEF (Flight), AO178 : A High-Resolution Study of Ultra-heavy Cosmic-Ray Nuclei, Tray D07 EL-1994-00062 LDEF (Flight), AO178 : A High-Resolution Study of Ultra-heavy Cosmic-Ray Nuclei, Tray D07 The flight photograph of the Ultra Heavy Cosmic Ray Experiment (UHCRE) was taken while the LDEF was attached to the Orbiter's RMS arm prior to berthing in the Orbiter's cargo bay. The white paint dot on the center clamp block of the experiment trays upper flange appears to be in prelaunch condition but the paint dot on the clamp block located at the right end of the lower flange appears to be slightly discolored. The UHCRE detectors were contained in 16 peripheral LDEF trays with at least one UHCRE tray located on each row of the LDEF except row 3, row 9 and row 12. Each tray contains three cylindrical aluminum pressure vessels with an integral aluminum support structure. Each cylinder is filled with an Eccofoam insert that houses 4 UHCRE detector stacks. Each stack consist of layers of Lexan polycarbonate sheets (approximately 70) interleaved with several thin sheets of lead. Forty-seven of the 48 pressure vessels were pressurized to 1.0 bar of a dry gas mixture (oxygen, nitrogen and helium) and sealed. One of the units was left unsealed in order to investigate the effects of the vacuum environment on the detector materials. Thermal control was accomplished by attaching an aluminized Kapton thermal cover on the tray bottom (the Kapton facing the LDEF interior), placing the aluminum cylinder support structure on thermal isolators and covering the experiment with a thin (5 mil) silvered TEFLON® thermal cover. The silvered TEFLON® cover was supported by an aluminum frame, an integral part of the experiment structure, and held in place by Velcro pads selectively located on the frame and on the back of the cover. The copper colored strip extending over the trays lower flange is a copper coated pressure sensitive tape used to provide an electrical ground between the experiments

  8. LDEF (Flight), AO178 : A High-Resolution Study of Ultra-heavy Cosmic-Ray Nuclei, Tray C11

    NASA Technical Reports Server (NTRS)

    1990-01-01

    LDEF (Flight), AO178 : A High-Resolution Study of Ultra-heavy Cosmic-Ray Nuclei, Tray C11 EL-1994-00010 LDEF (Flight), AO178 : A High-Resolution Study of Ultra-heavy Cosmic-Ray Nuclei, Tray C11 The flight photograph of the Ultra Heavy Cosmic Ray Experiment (UHCRE) was taken while the LDEF was attached to the Orbiter's RMS arm prior to berthing in the Orbiter's cargo bay. The white paint dots on the center clamp block of the experiment trays left flange and on the clamp blocks located at the upper and lower ends of the experiment trays right flange appear to be in near prelaunch condition. The UHCRE detectors were contained in 16 peripheral LDEF trays with at least one UHCRE tray located on each row of the LDEF except row 3, row 9 and row 12. Each tray contains three cylindrical aluminum pressure vessels with an integral aluminum support structure. Each cylinder is filled with an Eccofoam insert that houses 4 UHCRE detector stacks. Each stack consist of layers of Lexan polycarbonate sheets (approximately 70) interleaved with several thin sheets of lead. Forty-seven of the 48 pressure vessels were pressurized to 1.0 bar of a dry gas mixture (oxygen, nitrogen and helium) and sealed. One of the units was left unsealed in order to investigate the effects of the vacuum environment on the detector materials. Thermal control was accomplished by attaching an aluminized Kapton thermal cover on the tray bottom (the Kapton facing the LDEF interior), placing the aluminum cylinder support structure on thermal isolators and covering the experiment with a thin (5 mil) silvered TEFLON® thermal cover. The silvered TEFLON® cover was supported by an aluminum frame, an integral part of the experiment structure, and held in place by Velcro pads selectively located on the frame and on the back of the cover. The copper colored strip extending over the trays lower flange is a copper coated pressure sensitive tape used to provide an electrical ground between the experiments thermal cover

  9. LDEF (Postflight), AO178 : A High-Resolution Study of Ultra-heavy Cosmic-Ray Nuclei, Tray B07

    NASA Technical Reports Server (NTRS)

    1990-01-01

    LDEF (Postflight), AO178 : A High-Resolution Study of Ultra-heavy Cosmic-Ray Nuclei, Tray B07 EL-1994-00312 LDEF (Postflight), AO178 : A High-Resolution Study of Ultra-heavy Cosmic-Ray Nuclei, Tray B07 The postflight photograph of the Ultra Heavy Cosmic Ray Experiment (UHCRE) was taken in SAEF II at KSC after removal of the experiment tray from the LDEF. The outline of the experiment tray clamp blocks is clearly visible on the upper tray flange and to a lesser extent on the lower flange. The holding fixture hardware covers the clamp block areas on the end flanges. The prelaunch photograph of the Ultra Heavy Cosmic Ray Experiment (UHCRE) was taken in SAEF II at KSC prior to installation of the experiment tray on the LDEF. The UHCRE detectors were contained in 16 peripheral LDEF trays with at least one UHCRE tray located on each row of the LDEF except row 3, row 9 and row 12. Each tray contains three cylindrical aluminum pressure vessels with an integral aluminum support structure. Each cylinder is filled with an Eccofoam insert that houses 4 UHCRE detector stacks. Each stack consist of layers of Lexan polycarbonate sheets (approximately 70) interleaved with several thin sheets of lead. Forty-seven of the 48 pressure vessels were pressurized to 1.0 bar of a dry gas mixture (oxygen, nitrogen and helium) and sealed. One of the units was left unsealed in order to investigate the effects of the vacuum environment on the detector materials. Thermal control was accomplished by attaching an aluminized Kapton thermal cover on the tray bottom (the Kapton facing the LDEF interior), placing the aluminum cylinder support structure on thermal isolators and covering the experiment with a thin (5 mil) silvered TEFLON® thermal cover. The silvered TEFLON® cover was supported by an aluminum frame, an integral part of the experiment structure, and held in place by Velcro pads selectively located on the frame and on the back of the cover. The copper colored strip extending over the

  10. Precipitation and microphysical studies with a low cost high resolution X-band radar: an innovative project prospective

    NASA Astrophysics Data System (ADS)

    van Baelen, J.; Pointin, Y.; Wobrock, W.; Flossmann, A.; Peters, G.; Tridon, F.; Planche, C.

    2009-03-01

    This paper describes an innovative project which has just been launched at the "Laboratoire de Météorologie Physique" (LaMP) in Clermont-Ferrand in collaboration with the "Meteorologische Institut" in Hamburg, where a low cost X-band high resolution precipitation radar is combined with supporting measurements and a bin microphysical cloud resolving model in order to develop adapted Z-R relationships for accurate rain rate estimates over a local area such as a small catchment basin, an urban complex or even an agriculture domain. In particular, the use of K-band micro rain radars which can retrieve vertical profiles of drop size distribution and the associated reflectivity will be used to perform direct comparisons with X-band radar volume samples while a network of rain-gauges provides ground truth to which our rain estimates will be compared. Thus, the experimental suite of instrumentation should provide a detailed characterization of the various rain regimes and their associated Z-R relationship. Furthermore, we will make use of the hilly environment of the radar to test the use of novel attenuation methods in order to estimate rainfall rates. A second important aspect of this work is to use the detailed cloud modeling available at LaMP. Simulations of precipitating clouds in highly resolved 3-D dynamics model allow predicting the spectra of rain drops and precipitating ice particles. Radar reflectivity determined from these model studies will be compared with the observations in order to better understand which raindrop size spectrum shape factor should be applied to the radar algorithms as a function of the type of precipitating cloud. Likewise, these comparisons between the modeled and the observed reflectivity will also give us the opportunity to further improve our model microphysics and the parameterizations for meso-scale models.

  11. Catalytic Mechanism of Perosamine N-Acetyltransferase Revealed by High-Resolution X-ray Crystallographic Studies and Kinetic Analyses

    SciTech Connect

    Thoden, James B.; Reinhardt, Laurie A.; Cook, Paul D.; Menden, Patrick; Cleland, W.W.; Holden, Hazel M.

    2012-09-17

    N-Acetylperosamine is an unusual dideoxysugar found in the O-antigens of some Gram-negative bacteria, including the pathogenic Escherichia coli strain O157:H7. The last step in its biosynthesis is catalyzed by PerB, an N-acetyltransferase belonging to the left-handed {beta}-helix superfamily of proteins. Here we describe a combined structural and functional investigation of PerB from Caulobacter crescentus. For this study, three structures were determined to 1.0 {angstrom} resolution or better: the enzyme in complex with CoA and GDP-perosamine, the protein with bound CoA and GDP-N-acetylperosamine, and the enzyme containing a tetrahedral transition state mimic bound in the active site. Each subunit of the trimeric enzyme folds into two distinct regions. The N-terminal domain is globular and dominated by a six-stranded mainly parallel {beta}-sheet. It provides most of the interactions between the protein and GDP-perosamine. The C-terminal domain consists of a left-handed {beta}-helix, which has nearly seven turns. This region provides the scaffold for CoA binding. On the basis of these high-resolution structures, site-directed mutant proteins were constructed to test the roles of His 141 and Asp 142 in the catalytic mechanism. Kinetic data and pH-rate profiles are indicative of His 141 serving as a general base. In addition, the backbone amide group of Gly 159 provides an oxyanion hole for stabilization of the tetrahedral transition state. The pH-rate profiles are also consistent with the GDP-linked amino sugar substrate entering the active site in its unprotonated form. Finally, for this investigation, we show that PerB can accept GDP-3-deoxyperosamine as an alternative substrate, thus representing the production of a novel trideoxysugar.

  12. High resolution study of petroleum source rock variation, Lower Cretaceous (Hauterivian and Barremian) of Mikkelsen Bay, North Slope, Alaska

    USGS Publications Warehouse

    Keller, Margaret A.; Macquaker, Joe H.S.; Lillis, Paul G.

    2001-01-01

    Open File Report 01-480 was designed as a large format poster for the Annual Meeting of the American Association of Petroleum Geologists and the Society for Sedimentary Geology in Denver Colorado in June 2001. It is reproduced here in digital format to make widely available some unique images of mudstones. The images include description, interpretation, and Rock-Eval data that resulted from a high-resolution study of petroleum source rock variation of the Lower Cretaceous succession of the Mobil-Phillips Mikkelsen Bay State #1 well on the North Slope of Alaska. Our mudstone samples with Rock-Eval data plus color images are significant because they come from one of the few continuously cored and complete intervals of the Lower Cretaceous succession on the North Slope. This succession, which is rarely preserved in outcrop and very rarely cored in the subsurface, is considered to include important petroleum source rocks that have not previously been described nor explained Another reason these images are unique is that the lithofacies variability within mudstone dominated successions is relatively poorly known in comparison with that observed in coarser clastic and carbonate successions. They are also among the first published scans of thin sections of mudstone, and are of excellent quality because the sections are well made, cut perpendicular to bedding, and unusually thin, 20 microns. For each of 15 samples, we show a thin section scan (cm scale) and an optical photomicrograph (mm scale) that illustrates the variability present. Several backscattered SEM images are also shown. Rock-Eval data for the samples can be compared with the textures and mineralogy present by correlating sample numbers and core depth.

  13. Giant Impacts on Terrestrial Planets: A High-Resolution 3D Study of Magma Ocean Formation and Atmospheric Blowoff

    NASA Astrophysics Data System (ADS)

    Stewart-Mukhopadhyay, Sarah

    The end stages of terrestrial planet formation are dominated by giant impact events, which may significantly affect the final composition of a planet. The physical changes from giant impacts include formation of magma oceans and atmospheric blowoff. We propose to conduct unique numerical experiments to investigate the physics of giant impacts in order to determine their effect on the thermal state and volatile budget of terrestrial planets (0.1 to 10 Earth masses). Proposed work: High-resolution 3D giant impacts between differentiated silicate-iron and ice-silicate planets will be modeled with both the widely-used CTH shock physics code and a new second-order Godunov finite-volume hydrocode called AREPO. AREPO's powerful arbitrary Lagrangian-Eulerian grid and computational efficiency allows for unprecedented resolution of planetary structure (e.g., crust and ocean). Expected results: (1) We will calculate the amount of melt generated and fraction of atmosphere lost during different classes of giant impacts (merging, graze and merge, hit and run, and erosion/disruption). (2) We will derive general scaling laws to describe these complicated phenomena. (3) We will consider the effect of re-accretion of ejected material at late times on the total thermal input of giant impact events. (4) And we will test the giant impact hypothesis for the high bulk density of Mercury by conducting orbital integrations of ejected debris to determine the amount of re-accreted mantle material for different impact orientations. The science team has an established collaborative body of work in giant impact simulations and hydrocode development. As in previous studies, the simulation results will be generalized into sets of simple equations describing collision outcomes that are suitable for N-body planet formation models. The proposed work supports the goals of the Origins of Solar Systems program by conducting a fundamental theoretical investigation of a key stage of planet formation

  14. High-resolution ultrasound of rotator cuff and biceps reflection pulley in non-elite junior tennis players: anatomical study

    PubMed Central

    2014-01-01

    Background Tennis is believed to be potentially harmful for the shoulder, therefore the purpose of this study is to evaluate the anatomy of the rotator cuff and the coraco-humeral ligament (CHL) in a-symptomatic non-elite junior tennis players with high-resolution ultrasound (US). Methods From August 2009 to September 2010 n = 90 a-symptomatic non-elite junior tennis players (mean age ± standard deviation: 15 ± 3) and a control group of age- and sex- matched subjects were included. Shoulder assessment with a customized standardized protocol was performed. Body mass index, dominant arm, years of practice, weekly hours of training, racket weight, grip (Eastern, Western and semi-Western), kind of strings were recorded. Results Abnormalities were found at ultrasound in 14/90 (15%) players. Two players had supraspinatus tendinosis, two had subacromial impingement and ten had subacromial bursitis. CHL thickness resulted comparable in the dominant and non-dominant arms (11.3 ± 4.4 mm vs. 13 ± 4.2, p > 0.05). Multivariate analysis demonstrated that no association was present among CHL thickness and the variables evaluated. In the control group, abnormalities were found at ultrasound in 6/60 (10%) subjects (sub-acromial bursitis). No statistically significant differences between players and control group were found (p = 0.71). Conclusion In a-symptomatic non-elite junior tennis players only minor shoulder abnormalities were found. PMID:25034864

  15. Characterization of skin abnormalities in a mouse model of osteogenesis imperfecta using high resolution magnetic resonance imaging and Fourier transform infrared imaging spectroscopy.

    PubMed

    Canuto, H C; Fishbein, K W; Huang, A; Doty, S B; Herbert, R A; Peckham, J; Pleshko, N; Spencer, R G

    2012-01-01

    Evaluation of the skin phenotype in osteogenesis imperfecta (OI) typically involves biochemical measurements, such as histologic or biochemical assessment of the collagen produced from biopsy-derived dermal fibroblasts. As an alternative, the current study utilized non-invasive magnetic resonance imaging (MRI) microscopy and optical spectroscopy to define biophysical characteristics of skin in an animal model of OI. MRI of skin harvested from control, homozygous oim/oim and heterozygous oim/+ mice demonstrated several differences in anatomic and biophysical properties. Fourier transform infrared imaging spectroscopy (FT-IRIS) was used to interpret observed MRI signal characteristics in terms of chemical composition. Differences between wild-type and OI mouse skin included the appearance of a collagen-depleted lower dermal layer containing prominent hair follicles in the oim/oim mice, accounting for 55% of skin thickness in these. The MRI magnetization transfer rate was lower by 50% in this layer as compared to the upper dermis, consistent with lower collagen content. The MRI transverse relaxation time, T2, was greater by 30% in the dermis of the oim/oim mice compared to controls, consistent with a more highly hydrated collagen network. Similarly, an FT-IRIS-defined measure of collagen integrity was 30% lower in the oim/oim mice. We conclude that characterization of phenotypic differences between the skin of OI and wild-type mice by MRI and FT-IRIS is feasible, and that these techniques provide powerful complementary approaches for the analysis of the skin phenotype in animal models of disease. PMID:21845737

  16. Characterization of skin abnormalities in a mouse model of osteogenesis imperfecta using high resolution magnetic resonance imaging and Fourier transform infrared imaging spectroscopy.

    PubMed

    Canuto, H C; Fishbein, K W; Huang, A; Doty, S B; Herbert, R A; Peckham, J; Pleshko, N; Spencer, R G

    2012-01-01

    Evaluation of the skin phenotype in osteogenesis imperfecta (OI) typically involves biochemical measurements, such as histologic or biochemical assessment of the collagen produced from biopsy-derived dermal fibroblasts. As an alternative, the current study utilized non-invasive magnetic resonance imaging (MRI) microscopy and optical spectroscopy to define biophysical characteristics of skin in an animal model of OI. MRI of skin harvested from control, homozygous oim/oim and heterozygous oim/+ mice demonstrated several differences in anatomic and biophysical properties. Fourier transform infrared imaging spectroscopy (FT-IRIS) was used to interpret observed MRI signal characteristics in terms of chemical composition. Differences between wild-type and OI mouse skin included the appearance of a collagen-depleted lower dermal layer containing prominent hair follicles in the oim/oim mice, accounting for 55% of skin thickness in these. The MRI magnetization transfer rate was lower by 50% in this layer as compared to the upper dermis, consistent with lower collagen content. The MRI transverse relaxation time, T2, was greater by 30% in the dermis of the oim/oim mice compared to controls, consistent with a more highly hydrated collagen network. Similarly, an FT-IRIS-defined measure of collagen integrity was 30% lower in the oim/oim mice. We conclude that characterization of phenotypic differences between the skin of OI and wild-type mice by MRI and FT-IRIS is feasible, and that these techniques provide powerful complementary approaches for the analysis of the skin phenotype in animal models of disease.

  17. Measurement of HO2 and other trace gases in the stratosphere using a high resolution far-infrared spectrometer at 28 KM

    NASA Technical Reports Server (NTRS)

    Traub, Wesley A.; Chance, Kelly V.

    1988-01-01

    The major events and results to date of the ongoing program of measuring stratospheric composition by the technique of far-infrared Fourier-transform spectroscopy from a balloon-borne platform are reviewed. The highlights of this period were the two balloon flight campaigns which were performed at Palestine, Texas, both of which produced large amounts of scientifically useful data.

  18. Constructing a WISE High Resolution Galaxy Atlas

    NASA Astrophysics Data System (ADS)

    Jarrett, T. H.; Masci, F.; Tsai, C. W.; Petty, S.; Cluver, M.; Assef, Roberto J.; Benford, D.; Blain, A.; Bridge, C.; Donoso, E.; Eisenhardt, P.; Fowler, J.; Koribalski, B.; Lake, S.; Neill, James D.; Seibert, M.; Sheth, K.; Stanford, S.; Wright, E.

    2012-08-01

    After eight months of continuous observations, the Wide-field Infrared Survey Explorer (WISE) mapped the entire sky at 3.4 μm, 4.6 μm, 12 μm, and 22 μm. We have begun a dedicated WISE High Resolution Galaxy Atlas project to fully characterize large, nearby galaxies and produce a legacy image atlas and source catalog. Here we summarize the deconvolution techniques used to significantly improve the spatial resolution of WISE imaging, specifically designed to study the internal anatomy of nearby galaxies. As a case study, we present results for the galaxy NGC 1566, comparing the WISE enhanced-resolution image processing to that of Spitzer, Galaxy Evolution Explorer, and ground-based imaging. This is the first paper in a two-part series; results for a larger sample of nearby galaxies are presented in the second paper.

  19. Constructing a WISE High Resolution Galaxy Atlas

    NASA Technical Reports Server (NTRS)

    Jarrett, T. H.; Masci, F.; Tsai, C. W.; Petty, S.; Cluver, M.; Assef, Roberto J.; Benford, D.; Blain, A.; Bridge, C.; Donoso, E.; Eisenhardt, P.; Fowler, J.; Koribalski, B.; Lake, S.; Neill, James D.; Seibert, M.; Stanford, S.; Wright, E.

    2012-01-01

    After eight months of continuous observations, the Wide-field Infrared Survey Explorer (WISE) mapped the entire sky at 3.4 micron, 4.6 micron, 12 micron, and 22 micron. We have begun a dedicated WISE High Resolution Galaxy Atlas project to fully characterize large, nearby galaxies and produce a legacy image atlas and source catalog. Here we summarize the deconvolution techniques used to significantly improve the spatial resolution of WISE imaging, specifically designed to study the internal anatomy of nearby galaxies. As a case study, we present results for the galaxy NGC 1566, comparing the WISE enhanced-resolution image processing to that of Spitzer, Galaxy Evolution Explorer, and ground-based imaging. This is the first paper in a two-part series; results for a larger sample of nearby galaxies are presented in the second paper.

  20. Feedback in the Antennae Galaxies (NGC 4038/9): I. High-Resolution Infrared Spectroscopy of Winds from Super Star Clusters

    SciTech Connect

    Gilbert, A; Graham, J

    2007-06-05

    We present high-resolution (R {approx} 24,600) near-IR spectroscopy of the youngest super star clusters (SSCs) in the prototypical starburst merger, the Antennae Galaxies. These SSCs are young (3-7 Myr old) and massive (10{sup 5}-10{sup 7} M{sub {circle_dot}} for a Kroupa IMF) and their spectra are characterized by broad, extended Brackett {gamma} emission, so we refer to them as emission-line clusters (ELCs) to distinguish them from older SSCs. The Br {gamma} lines of most ELCs have supersonic widths (60-110 km s{sup -1} FWHM) and non-Gaussian wings whose velocities exceed the clusters escape velocities. This high-velocity unbound gas is flowing out in winds that are powered by the clusters massive O and W-R stars over the course of at least several crossing times. The large sizes of some ELCs relative to those of older SSCs may be due to expansion caused by these outflows; many of the ELCs may not survive as bound stellar systems, but rather dissipate rapidly into the field population. The observed tendency of older ELCs to be more compact than young ones is consistent with the preferential survival of the most concentrated clusters at a given age.

  1. Modeling defect cluster evolution in irradiated structural materials: Focus on comparing to high-resolution experimental characterization studies

    DOE PAGES

    Wirth, Brian D.; Hu, Xunxiang; Kohnert, Aaron; Xu, Donghua

    2015-03-02

    Exposure of metallic structural materials to irradiation environments results in significant microstructural evolution, property changes, and performance degradation, which limits the extended operation of current generation light water reactors and restricts the design of advanced fission and fusion reactors. Further, it is well recognized that these irradiation effects are a classic example of inherently multiscale phenomena and that the mix of radiation-induced features formed and the corresponding property degradation depend on a wide range of material and irradiation variables. This inherently multiscale evolution emphasizes the importance of closely integrating models with high-resolution experimental characterization of the evolving radiation-damaged microstructure. Lastly,more » this article provides a review of recent models of the defect microstructure evolution in irradiated body-centered cubic materials, which provide good agreement with experimental measurements, and presents some outstanding challenges, which will require coordinated high-resolution characterization and modeling to resolve.« less

  2. Modeling defect cluster evolution in irradiated structural materials: Focus on comparing to high-resolution experimental characterization studies

    SciTech Connect

    Wirth, Brian D.; Hu, Xunxiang; Kohnert, Aaron; Xu, Donghua

    2015-03-02

    Exposure of metallic structural materials to irradiation environments results in significant microstructural evolution, property changes, and performance degradation, which limits the extended operation of current generation light water reactors and restricts the design of advanced fission and fusion reactors. Further, it is well recognized that these irradiation effects are a classic example of inherently multiscale phenomena and that the mix of radiation-induced features formed and the corresponding property degradation depend on a wide range of material and irradiation variables. This inherently multiscale evolution emphasizes the importance of closely integrating models with high-resolution experimental characterization of the evolving radiation-damaged microstructure. Lastly, this article provides a review of recent models of the defect microstructure evolution in irradiated body-centered cubic materials, which provide good agreement with experimental measurements, and presents some outstanding challenges, which will require coordinated high-resolution characterization and modeling to resolve.

  3. Study of M1 and E1 excitations by high-resolution proton inelastic scattering measurement at forward angles

    SciTech Connect

    Tamii, A.; Adachi, T.; Hatanaka, K.; Hashimoto, H.; Kaneda, T.; Matsubara, H.; Okamura, H.; Sakemi, Y.; Shimizu, Y.; Tameshige, Y.; Yosoi, M.; Carter, J.; Dozono, M.; Fujita, H.; Fujita, Y.; Itoh, M.; Kawabata, T.; Nakanishi, K.; Sasamoto, Y.; Neumann-Cosel, P. von

    2007-06-13

    Experimental technique for measuring proton inelastic scattering with high-resolution at 295 MeV and at forward angles including zero degrees is described. The method is useful for extracting spin part of the M1 strength via nuclear excitation as well as E1 strength via Coulomb excitation. An excitation energy resolution of 20 keV, good scattering angle resolution, and low background condition have been achieved. The experimental technique was applied for several sd and pf shell nuclei.

  4. A high-resolution study of surfactant partitioning and kinetic limitations for two-component internally mixed aerosols

    NASA Astrophysics Data System (ADS)

    Suda, S. R.; Petters, M. D.

    2013-12-01

    Atmospheric aerosols serve as cloud condensation nuclei (CCN), altering cloud properties and ultimately affecting climate through their effect on the radiative balance. Aerosol CCN activity depends in part on aerosol composition and surfactant compounds are of particular interest because surfactants are enriched at the water/air interface, resulting in a radial concentration gradient within the aqueous droplet. Accurate treatment of the surfactant concentration gradient complicates the otherwise straightforward predictions of CCN activity for aerosols of known composition. To accurately evaluate predictions made by theory, laboratory studies investigating the relationship between critical supersaturation and dry diameter of particles that include surfactants require significant reduction in measurement uncertainty for both water-uptake and CCN measurements. Furthermore, uncertainties remain regarding kinetic limitations to surfactant partitioning that could result in deviation from predictions based on equilibrium thermodynamics. This study attempts to address some of these issues through high-resolution analysis of CCN activity of two-component mixed surfactant/non-surfactant aerosols at different internal mixing ratios performed with and without a water-uptake time delay to ascertain whether or not the observed effects are kinetically limited. We present new data for the aerosols consisting of 1) the ionic surfactant sodium dodecyl sulfate (SDS) with ammonium sulfate, 2) SDS with sodium chloride and 3) the strong non-ionic fluorosurfactant Zonyl with an organic proxy glucose. As a point of reference we also evaluated the mixture of ammonium sulfate with glucose. Aerosol activation diameters were determined using CCN analysis in conjunction with scanning mobility size classification and high sheath-to-aerosol flow ratios. This resulted in CCN-derived kappa values that could be determined within +/-5% relative error. To test whether dynamic surfactant partitioning

  5. A biomarker study of high resolution sedimentary records in the eastern Mediterranean Sea since the last glacial maximum

    NASA Astrophysics Data System (ADS)

    Katsouras, G.; Gogou, A.; Bouloubassi, I.; Emeis, K.-C.; Triantaphyllou, M. V.; Lykousis, V.

    2009-04-01

    Information stored in sedimentary records provides evidence on climate and environmental variability at decadal to centennial time scales. The eastern Mediterranean Sea and the related Aegean Sea exhibit high sedimentation rates in certain areas and are considered as sensitive regions to record paleo-environmental and -climatic changes. The aim of our study is to reconstruct high-frequency paleoclimatic variations and identify associated changes in the physical, chemical and biological environment in selected basins of the eastern Mediterranean Sea, using molecular biogeochemical proxies. Here we present a high-resolution multi-proxy study along two Aegean Sea cores (north (152SL) and southeast (NS-14)) and a Libyan Sea core (HCM2/22). An important time marker and indicator of remarkable climatic and environmental changes is sapropel S1, a sediment layer rich in organic carbon. Depending on the water column depth, the sediment accumulation rates and the proximity to freshwater and water formation sources, S1 deposited between ~9.8 to 6.4 kyr BP, with an apparent interruption in the S1 deposition that occurred from ~8.6 to 7.6 kyr BP. SSTs based on alkenone unsaturation index Uḱ 37, ^15tot, ^13Corg and various marine and terrestrial biomarkers are used to investigate the region's climatic variability, and the modifications in the biogeochemical functioning of the eastern Mediterranean Sea. Uḱ 37 SST distribution in our records reveals significant fluctuations in temperature over the last 20.000 yrs. Organic carbon stable isotopes values span a narrow range over the whole sequence, with values varying to typical marine origin. The distributions of land-plant biomarkers are indicative of variable terrigenous organic matter supply and the concomitant transport of nutrients to surface waters. Furthermore, the distribution patterns and characteristic ratios of marine biomarkers exhibit differences in the paleoproductivity trends and ventilation changes over the last

  6. A HIGH-RESOLUTION PHOTOIONIZATION AND PHOTOELECTRON STUDY OF {sup 58}Ni USING A VACUUM ULTRAVIOLET LASER

    SciTech Connect

    Shi Xiaoyu; Huang Huang; Jacobson, Brian; Chang, Yih-Chung; Ng, C. Y.; Yin Qingzhu

    2012-03-01

    In order to provide high-resolution spectroscopic data of nickel ({sup 58}Ni) and its cation ({sup 58}Ni{sup +}) for the assignment of vacuum ultraviolet (VUV) stellar spectra, we have obtained the photoionization efficiency (PIE) spectra of {sup 58}Ni by using a supersonically cooled laser ablation transition-metal beam source and a broadly tunable VUV laser in the range of 61,100-73,600 cm{sup -1}, covering the photoionization transitions: Ni{sup +} (3d{sup 92} D) <- Ni (3d{sup 8}4s{sup 23} D), Ni{sup +}(3d{sup 92} D) <- Ni(3d{sup 8}4s{sup 23} F), and Ni{sup +} (3d{sup 8}4s{sup 4} F) <- Ni(3d{sup 8}4s{sup 23} F). We have also measured the VUV laser pulsed-field-ionization-photoelectron (PFI-PE) spectra of {sup 58}Ni in these regions. The VUV-PFI-PE measurement has allowed the determination of a precise value of 61,619.89 {+-} 0.8 cm{sup -1} (7.6399 {+-} 0.0001 eV) for the ionization energy (IE) of {sup 58}Ni. Due to the narrow VUV laser optical bandwidth of 0.4 cm{sup -1} used in the present study, many complex autoionizing resonances exhibiting Fano line shape profiles are resolved in the PIE spectra. Four autoionizing Rydberg series originating from two-electron and one-electron excitations from the Ni(3d{sup 8}4s{sup 23} F{sub 4}) ground state to converge to the respective Ni{sup +}({sup 2} D{sub 3/2}) and Ni{sup +}({sup 4} F{sub J} ) (J = 9/2, 7/2, and 5/2) ion states are identified. The Rydberg analysis, along with VUV-PFI-PE measurements, has yielded highly precise IE values for the formation of these excited ionic states from the Ni(3d{sup 8}4s{sup 23} F{sub 4}) ground state. The IE values, relative photoionization cross sections, and autoionizing Rydberg resonances observed in the present study are relevant to astrophysics by enhancing the atomic database of iron group transition metal atoms and for understanding the Ni and Ni{sup +} contribution to the VUV opacity in the solar atmosphere.

  7. A case study of a Ross Ice Shelf Airstream event using high resolution observational data captured by SNOWWEB

    NASA Astrophysics Data System (ADS)

    Jolly, Ben; McDonald, Adrian

    2015-04-01

    The Ross Ice Shelf Airstream (RAS) is the dominant weather pattern over the Ross Ice Shelf in Antarctica. Characterised by a strong southerly flow over the ice shelf, the RAS plays a significant role in the northward transport of cold air from the interior of the continent out into the Ross Sea. As it passes by Ross Island - home to McMurdo Station and Scott Base - and out over the edge of the ice shelf, the RAS also helps to create and maintain the Ross Sea Polynya, the single largest contributor to sea ice growth in the Ross Sea region. Our area of interest is the McMurdo Ice Shelf, situated directly south of Ross Island and adjoining the north-western tip of the much larger Ross Ice Shelf. The terrain of this region is complex, with large mountains, islands, and cliffs dominating local flow. Additionally, severe weather - often experienced during a RAS event - can greatly impact human activity. These two factors make this region particularly interesting to study. During the 2013/14 austral summer season we deployed 14 weather stations on the McMurdo Ice Shelf, creating a dense spatial observational network. In combination with existing automatic weather stations and high resolution model output from the Antarctic Mesoscale Prediction System (AMPS), we present a case study of a three day RAS event observed in November 2013. We find that AMPS represents the RAS well in general, however at the local scale there are some large discrepancies between observed and forecast winds. Predominantly these are a result of errors in timing, with AMPS incorrectly forecasting 'lulls' in the RAS when none were observed and vice-versa. There also appear to be some differences between AMPS and observations regarding the split of the southerly RAS flow around Ross Island. The representation within AMPS of both Hut Point Peninsula - a small yet important orographic feature running south-west from Ross Island that blocks relatively weak flows - and the Windless Bight high pressure

  8. High-Resolution Mid-Infrared Imaging of the Asymptotic Giant Branch Star RV Bootis with the Steward Observatory Adaptive Optics System

    NASA Astrophysics Data System (ADS)

    Biller, B. A.; Close, L. M.; Li, A.; Bieging, J. H.; Hoffmann, W. F.; Hinz, P. M.; Miller, D.; Brusa, G.; Lloyd-Hart, M.; Wildi, F.; Potter, D.; Oppenheimer, B. D.

    2005-02-01

    We present high-resolution (~0.1"), very high Strehl ratio (0.97+/-0.03) mid-IR adaptive optics (AO) images of the asymptotic giant branch (AGB) star RV Boo utilizing the MMT adaptive secondary AO system. RV Boo was observed at a number of wavelengths over two epochs (9.8 μm in 2003 May and 8.8, 9.8, and 11.7 μm in 2004 February) and appeared slightly extended at all wavelengths. While the extension is very slight at 8.8 and 11.7 μm, the extension is somewhat more pronounced at 9.8 μm. With such high Strehl ratios, we can achieve superresolutions of 0.1" by deconvolving RV Boo with a point-spread function (PSF) derived from an unresolved star. We tentatively resolve RV Boo into a 0.16" FWHM extension at a position angle of 120°. At a distance of 390+250-100 pc, this corresponds to a FWHM of 60+40-15 AU. We measure a total flux at 9.8 μm of 145+/-24 Jy for the disk and star. Based on a dust thermal emission model for the observed IR spectral energy distribution and the 9.8 μm AO image, we derive a disk dust mass of 1.6×10-6 Msolar and an inclination of 30°-45° from edge-on. We discuss whether the dust disk observed around RV Boo is an example of the early stages in the formation of asymmetric structure in planetary nebulae.

  9. Comparative study of IDH1 mutations in gliomas by high resolution melting analysis, immunohistochemistry and direct DNA sequencing.

    PubMed

    Li, Juan; Zhang, Haiyan; Wang, Li; Yang, Chuanhong; Lai, Huangwen; Zhang, Wei; Chen, Xiaodong; Wang, Jie

    2015-09-01

    Patients with glioblastomas with a specific mutation in the isocitrate dehydrogenase 1 (IDH1) gene have a better prognosis than those with gliomas with wild‑type IDH1. IDH1 analysis has become part of the standard diagnostic procedure and a promising tool used for stratification in clinical trials. The present study aimed to compare high resolution melting (HRM) analysis, immunohistochemistry (IHC) and direct DNA sequencing for the detection of IDH mutations in gliomas. Fifty‑one formalin‑fixed paraffin‑embedded tumor samples were selected. For the HRM analysis and direct DNA sequencing, DNA was extracted from the tissues. For IHC, sections were stained with an anti‑IDH1‑R132H specific antibody. The HRM analysis method identified 33 cases of IDH1 gene mutations, and all mutations occurred at the R132H site. There were 33 cases of IDH1 gene mutations found by IHC, which was consistent with that identified using the HRM analysis method. However, only 30 IDH1 samples were confirmed by sequencing, in which mutations occurred at the IDH1 exon 4 R132H site. No mutation was detected in the other three of these 33 cases (two grade II oligodendroglioma and one grade II diffuse astrocytoma) by sequencing, while IHC was positive for IDH1‑R132H. The results showed that the mutation detection rate was not identified to be significantly different (P=0.250) when determined by the HRM analysis method or by direct DNA sequencing, as the concordant rate between the two methods was high (κ=0.866). The HRM analysis method in glioma IDH1 gene mutation detection has advantages of high sensitivity, good repeatability, simple operation and accurate results. It provides a novel method for detecting mutations of the IDH1 gene in paraffin embedded tissue samples of clinical glioma. Related to a small amount of sample, there was no evidence showing that HRM analysis method is superior to IHC. Direct DNA sequencing, HRM analysis and IHC results were consistent; however, HRM and

  10. A High-Resolution Study of Hippocampal and Medial Temporal Lobe Correlates of Spatial Context and Prospective Overlapping Route Memory

    PubMed Central

    Brown, Thackery I.; Hasselmo, Michael E.; Stern, Chantal E.

    2015-01-01

    When navigating our world we often first plan or retrieve an ideal route to our goal, avoiding alternative paths that lead to other destinations. The medial temporal lobe (MTL) has been implicated in processing contextual information, sequence memory, and uniquely retrieving routes that overlap or “cross paths.” However, the identity of subregions of the hippocampus and neighboring cortex that support these functions in humans remains unclear. The present study used high-resolution functional magnetic resonance imaging (hr-fMRI) in humans to test whether the CA3/DG hippocampal subfield and para-hippocampal cortex are important for processing spatial context and route retrieval, and whether the CA1 subfield facilitates prospective planning of mazes that must be distinguished from alternative overlapping routes. During hr-fMRI scanning, participants navigated virtual mazes that were well-learned from prior training while also learning new mazes. Some routes learned during scanning shared hallways with those learned during pre-scan training, requiring participants to select between alternative paths. Critically, each maze began with a distinct spatial contextual Cue period. Our analysis targeted activity from the Cue period, during which participants identified the current navigational episode, facilitating retrieval of upcoming route components and distinguishing mazes that overlap. Results demonstrated that multiple MTL regions were predominantly active for the contextual Cue period of the task, with specific regions of CA3/DG, parahippocampal cortex, and perirhinal cortex being consistently recruited across trials for Cue periods of both novel and familiar mazes. During early trials of the task, both CA3/DG and CA1 were more active for overlapping than non-overlapping Cue periods. Trial-by-trial Cue period responses in CA1 tracked subsequent overlapping maze performance across runs. Together, our findings provide novel insight into the contributions of MTL

  11. Determination of total mercury for marine environmental monitoring studies by solid sampling continuum source high resolution atomic absorption spectrometry

    NASA Astrophysics Data System (ADS)

    Mandjukov, Petko; Orani, Anna Maria; Han, Eunmi; Vassileva, Emilia

    2015-01-01

    The most critical step in almost all commonly used analytical procedures for Hg determination is the sample preparation due to its extreme volatility. One of the possible solutions of this problem is the application of methods for direct analysis of solid samples. The possibilities for solid sampling high resolution continuum source atomic absorption spectrometry (HR CS AAS) determination of total mercury in various marine environmental samples e.g. sediments and biota are object of the present study. The instrumental parameters were optimized in order to obtain reproducible and interference free analytical signal. A calibration technique based on the use of solid standard certified reference materials similar to the nature of the analyzed sample was developed and applied to various CRMs and real samples. This technique allows simple and reliable evaluation of the uncertainty of the result and the metrological characteristics of the method. A validation approach in line with the requirements of ISO 17025 standard and Eurachem guidelines was followed. With this in mind, selectivity, working range (0.06 to 25 ng for biota and 0.025 to 4 ng for sediment samples, expressed as total Hg) linearity (confirmed by Student's t-test), bias (1.6-4.3%), repeatability (4-9%), reproducibility (9-11%), and absolute limit of detection (0.025 ng for sediment, 0.096 ng for marine biota) were systematically assessed using solid CRMs. The relative expanded uncertainty was estimated at 15% for sediment sample and 8.5% for marine biota sample (k = 2). Demonstration of traceability of measurement results is also presented. The potential of the proposed analytical procedure, based on solid sampling HR CS AAS technique was demonstrated by direct analysis of sea sediments form the Caribbean region and various CRMs. Overall, the use of solid sampling HR CS AAS permits obtaining significant advantages for the determination of this complex analyte in marine samples, such as straightforward

  12. Interpretation of high resolution aeromagnetic data for lineaments study and occurrence of Banded Iron Formation in Ogbomoso area, Southwestern Nigeria

    NASA Astrophysics Data System (ADS)

    Oladunjoye, Michael Adeyinka; Olayinka, Abel Idowu; Alaba, Mustapha; Adabanija, Moruffdeen Adedapo

    2016-02-01

    The quest for solid mineral resource as an alternative for oil income in Nigeria presents opportunity to diversify the resource base of the country. To fill some information gap on the long abandoned Ajase and Gbede Banded Iron Formations (BIF) in Ogbomoso area, Southwestern Nigeria, high resolution aeromagnetic data of Ogbomoso - Sheet 222 was interpreted; to provide a better understanding of the mode of occurrence of the iron ore and associated structural features and geologic model. These were accomplished by subjecting reduced-to-pole (RTP) residual aeromagnetic intensity map to various data filtering and processing involving total horizontal derivative, vertical derivative, Upward Continuation (UC), Downward Continuation (DC), Euler Deconvolution at different Spectral Indices (SI), and Analytical signal using Geosoft Oasis Montaj 6.4.2 (HJ) data processing and analysis software. The resultants maps were overlain, compared and or plotted on RTP residual aeromagnetic intensity map and or geological map and interpreted in relation to the surface geological map. Positive magnetic anomalies observed on the RTP residual aeromagnetic intensity map ranged from 2.1 to 94.0 nT and associated with contrasting basement rocks, Ajase and Gbede BIF; while negative magnetic anomalies varied between -54.7 nT and -2.8 nT and are associated with intrusive bodies. Interpreted lineaments obtained from total horizontal derivative map were separated into two categories namely ductile and brittle based on their character vis-à-vis magnetic anomalies on RTP intensity map. Whilst the brittle lineaments were interpreted as fracture or faults; the ductile lineaments were interpreted as folds or representing the internal fabric of the rock units. In addition prominent magnetic faults mainly due to offset of similar magnetic domain/gradient were also interpreted. The iron ore mineralization is distributed within the eastern portion of the study area with Ajase BIF at relatively greater

  13. High Resolution Spectroscopy to Support Atmospheric Measurements

    NASA Technical Reports Server (NTRS)

    Venkataraman, Malathy Devi

    2006-01-01

    The major research activities performed during the cooperative agreement enhanced our spectroscopic knowledge of molecules of atmospheric interest such as H2O (water vapor), O3 (ozone), HCN (hydrogen cyanide), CH4 (methane), NO2 (nitrogen dioxide) and CO (carbon monoxide). The data required for the analyses were obtained from two different Fourier Transform Spectrometers (FTS); one of which is located at the National Solar Observatory (NSO) on Kitt Peak, Arizona and the other instrument is located at the Pacific Northwest National Laboratories (PNNL) at Richland, Washington. The data were analyzed using a modified multispectrum nonlinear least squares fitting algorithm developed by Dr. D. Chris Benner of the College of William and Mary. The results from these studies made significant improvements in the line positons and intensities for these molecules. The measurements of pressure broadening and pressure induced line shift coefficients and the temperature dependence of pressure broadening and pressure induced shift coefficients for hundreds of infrared transitions of HCN, CO3 CH4 and H2O were also performed during this period. Results from these studies have been used for retrievals of stratospheric gas concentration profiles from data collected by several Upper Atmospheric Research Satellite (UARS) infrared instruments as well as in the analysis of high resolution atmospheric spectra such as those acquired by space-based, ground-based, and various balloon- and aircraft-borne experiments. Our results made significant contributions in several updates of the HITRAN (HIgh resolution TRANsmission) spectral line parameters database. This database enjoys worldwide recognition in research involving diversified scientific fields. The research conducted during the period 2003-2006 has resulted in publications given in this paper. In addition to Journal publications, several oral and poster presentations were given at various Scientific conferences within the United States

  14. Chemical Synthesis and High Resolution Spectroscopic Characterization of 1-AZA-ADAMANTANE-4-ONE C_9H13NO from the Microwave to the Infrared

    NASA Astrophysics Data System (ADS)

    Pirali, Olivier; Goubet, Manuel; Boudon, Vincent; D'accolti, Lucia; Annese, Cosimo; Fusco, Caterina

    2016-06-01

    We have synthesized 1-aza-adamantane-4-one (C_9H13NO) starting from commercial 1,4-cyclohexanedionemonoethylene acetal and tosylmethylisocianide and following a procedure described in details in the literature. The high degree of sample purity was demonstrated by gas chromatography and mass spectrometric measurements, and its structure evidenced by 1H and 13C NMR spectroscopy. We present a thorough spectroscopic characterization of this molecule by gas phase vibrational and rotational spectroscopy. Accurate vibrational frequencies have been determined by infrared and far-infrared spectra. The pure rotational spectrum of the molecule has been recorded both by cavity-based Fourier-transform microwave spectroscopy in the 2-20 GHz region, by supersonically expanding the vapor pressure of the warm sample, and by room-temperature absorption spectroscopy in the 140-220 GHz range. Quantum-chemical calculations have enabled a fast analysis of the spectra. Accurate sets of rotational and centrifugal distorsion parameters of 1-aza-adamantane-4-one in its ground state and five vibrationally excited states have been derived from these measurements. Black, R. M. Synthesis, 1981, 829

  15. Resolving shocked and UV excited components of H2 emission in planetary nebulae with high-resolution near-infrared spectroscopy

    NASA Astrophysics Data System (ADS)

    Kaplan, Kyle; Dinerstein, Harriet L.; Jaffe, Daniel Thomas

    2016-06-01

    Planetary nebulae (PNe) form when low and intermediate-mass stars eject their outer layers into the ISM at the end of the AGB phase. Many PNe exhibit near-infrared (NIR) emission from molecular hydrogen (H2). This NIR emission arises from radiative decay out of excited rotation-vibration (rovibrational) states. The rovibrational states can be populated by excitation to higher electronic states through absorption of a far-UV photon followed by a radiative cascade to the electronic ground state, or by collisions (e.g., in a hot gas). The two processes populate the rovibrational levels of H2 differently, so the observed emergent emission spectrum provides an effective probe of the mechanisms that excite the H2. Many PNe display line intensity ratios that are intermediate between these two processes (Otsuka et al. 2013). With the advantages of the high spectral resolution (R~40000), broad wavelength coverage (1.45-2.45 μm), and high spatial resolution of the Immersion GRating Infrared Spectrometer (IGRINS, Park et al. 2014), we are able to differentiate components in position-velocity space: we see a slowly expanding UV-excited H2 shell in the PN M 1-11 and two faster moving “bullets” of thermalized H2 that we interpret as shocked gas from a bipolar outflow. We also present observations of several other PNe that exhibit similar morphologies of thermalized and UV-excited H2 components.

  16. New temperature and pressure retrieval algorithm for high-resolution infrared solar occultation spectroscopy: analysis and validation against ACE-FTS and COSMIC

    NASA Astrophysics Data System (ADS)

    Olsen, K. S.; Toon, G. C.; Boone, C. D.; Strong, K.

    2015-10-01

    Motivated by the initial selection of a high-resolution solar occultation Fourier transform spectrometer (FTS) to fly to Mars on the ExoMars Trace Gas Orbiter, we have been developing algorithms for retrieving volume mixing ratio vertical profiles of trace gases, the primary component of which is a new algorithm and software for retrieving vertical profiles of temperature and pressure from the spectra. In contrast to Earth-observing instruments, which can rely on accurate meteorological models, a priori information, and spacecraft position, Mars retrievals require a method with minimal reliance on such data. The temperature and pressure retrieval algorithms developed for this work were evaluated using Earth-observing spectra from the Atmospheric Chemistry Experiment (ACE) FTS, a solar occultation instrument in orbit since 2003, and the basis for the instrument selected for a Mars mission. ACE-FTS makes multiple measurements during an occultation, separated in altitude by 1.5-5 km, and we analyze 10 CO2 vibration-rotation bands at each altitude, each with a different usable altitude range. We describe the algorithms and present results of their application and their comparison to the ACE-FTS data products. The Constellation Observing System for Meteorology, Ionosphere, and Climate (COSMIC) provides vertical profiles of temperature up to 40 km with high vertical resolution. Using six satellites and GPS radio occultation, COSMIC's data product has excellent temporal and spatial coverage, allowing us to find coincident measurements with ACE with very tight criteria: less than 1.5 h and 150 km. We present an inter-comparison of temperature profiles retrieved from ACE-FTS using our algorithm, that of the ACE Science Team (v3.5), and from COSMIC. When our retrievals are compared to ACE-FTS v3.5, we find mean differences between -5 and +2 K, and that our retrieved profiles have no seasonal or zonal biases, but do have a warm bias in the stratosphere and a cold bias in the

  17. New temperature and pressure retrieval algorithm for high-resolution infrared solar occultation spectroscopy: analysis and validation against ACE-FTS and COSMIC

    NASA Astrophysics Data System (ADS)

    Olsen, Kevin S.; Toon, Geoffrey C.; Boone, Chris D.; Strong, Kimberly

    2016-03-01

    Motivated by the initial selection of a high-resolution solar occultation Fourier transform spectrometer (FTS) to fly to Mars on the ExoMars Trace Gas Orbiter, we have been developing algorithms for retrieving volume mixing ratio vertical profiles of trace gases, the primary component of which is a new algorithm and software for retrieving vertical profiles of temperature and pressure from the spectra. In contrast to Earth-observing instruments, which can rely on accurate meteorological models, a priori information, and spacecraft position, Mars retrievals require a method with minimal reliance on such data. The temperature and pressure retrieval algorithms developed for this work were evaluated using Earth-observing spectra from the Atmospheric Chemistry Experiment (ACE) FTS, a solar occultation instrument in orbit since 2003, and the basis for the instrument selected for a Mars mission. ACE-FTS makes multiple measurements during an occultation, separated in altitude by 1.5-5 km, and we analyse 10 CO2 vibration-rotation bands at each altitude, each with a different usable altitude range. We describe the algorithms and present results of their application and their comparison to the ACE-FTS data products. The Constellation Observing System for Meteorology, Ionosphere, and Climate (COSMIC) provides vertical profiles of temperature up to 40 km with high vertical resolution. Using six satellites and GPS radio occultation, COSMIC's data product has excellent temporal and spatial coverage, allowing us to find coincident measurements with ACE with very tight criteria: less than 1.5 h and 150 km. We present an intercomparison of temperature profiles retrieved from ACE-FTS using our algorithm, that of the ACE Science Team (v3.5), and from COSMIC. When our retrievals are compared to ACE-FTS v3.5, we find mean differences between -5 and +2 K and that our retrieved profiles have no seasonal or zonal biases but do have a warm bias in the stratosphere and a cold bias in the

  18. High-resolution surface temperature patterns related to urban morphology in a tropical city: A satellite-based study

    SciTech Connect

    Nichol, J.E.

    1996-01-01

    High-resolution thermal data derived from Landsat`s thematic mapper are evaluated for their correspondence to building geometry and landscape features in Singapore`s high-rise housing estates. The image data are sufficiently detailed to reveal that differences in solar azimuth on images taken at different times of year create different thermal patterns due to building geometry and surface materials. Field measurements of surface and adjacent air temperatures in urban canyons at different orientations and at different elevations above ground demonstrate that for Singapore conditions satellite-derived surface temperature patterns are a good indicator of the daytime urban heat island. 18 refs., 11 figs., 2 tabs.

  19. High-Resolution Study of X-Ray Resonant Raman Scattering at the K Edge of Silicon

    SciTech Connect

    Szlachetko, J.; Dousse, J.-Cl.; Berset, M.; Fennane, K.; Szlachetko, M.; Hoszowska, J.; Barrett, R.; Pajek, M.; Kubala-Kukus, A.

    2006-08-18

    We report on the first high-resolution measurements of the K x-ray resonant Raman scattering (RRS) in Si. The measured x-ray RRS spectra, interpreted using the Kramers-Heisenberg approach, revealed spectral features corresponding to electronic excitations to the conduction and valence bands in silicon. The total cross sections for the x-ray RRS at the 1s absorption edge and the 1s-3p excitation were derived. The Kramers-Heisenberg formalism was found to reproduce quite well the x-ray RRS spectra, which is of prime importance for applications of the total-reflection x-ray fluorescence technique.

  20. The study of oxygen molecules on Pt (111) surface with high resolution x-ray photoemission spectroscopy

    NASA Astrophysics Data System (ADS)

    Kim, Yong Su; Bostwick, Aaron; Rotenberg, Eli; Ross, Philip N.; Hong, Soon Cheol; Mun, Bongjin Simon

    2010-07-01

    By using high resolution x-ray photoelectron spectroscopy, we show that inelastic scattering of photoelectron at low temperature (30-50 K) generates two kinds of oxygen species on Pt (111) surface. Intense synchrotron radiation source dissociates oxygen molecules into chemisorbed atomic oxygen and induces the formation of PtO on the surface. Estimated coverage of dissociated atomic oxygen is 0.5 ML, suggesting possible formation of p(2×1) surface structure, while PtO coverage shows saturation coverage of 0.5 ML. Molecular oxygen dosed at 30 K undergoes thermally activated transition from physisorbed to chemisorbed state at around 40 K.

  1. The study of oxygen molecules on Pt (111) surface with high resolution x-ray photoemission spectroscopy.

    PubMed

    Kim, Yong Su; Bostwick, Aaron; Rotenberg, Eli; Ross, Philip N; Hong, Soon Cheol; Mun, Bongjin Simon

    2010-07-21

    By using high resolution x-ray photoelectron spectroscopy, we show that inelastic scattering of photoelectron at low temperature (30-50 K) generates two kinds of oxygen species on Pt (111) surface. Intense synchrotron radiation source dissociates oxygen molecules into chemisorbed atomic oxygen and induces the formation of PtO on the surface. Estimated coverage of dissociated atomic oxygen is 0.5 ML, suggesting possible formation of p(2 x 1) surface structure, while PtO coverage shows saturation coverage of 0.5 ML. Molecular oxygen dosed at 30 K undergoes thermally activated transition from physisorbed to chemisorbed state at around 40 K. PMID:20649331

  2. High-resolution remote sensing and coupled fire-weather simulation modeling offer unprecedented insight to megafire behavior: The 2014 California King Megafire case study

    NASA Astrophysics Data System (ADS)

    Stavros, E. N.; Coen, J. L.; Sign, H.; Tane, Z.; McGaughey, R. J.; Kane, V. R.; Fites, J. A.; Oliva, P.; Schroeder, W.; Schimel, D.; Ramirez, C.

    2015-12-01

    Megafires, defined by their size, unanticipated fire behavior, and fire severity, are increasing across the western contiguous United States. To date, limited observations have been made during these events. However, in September 2014 the California King Fire, which gained much public attention due to its rapid spread, effects on air quality, damage to infrastructure, and impacts on the Sierra Nevada landscape, burned an area where high resolution remotely sensed data had been acquired. These data include Light Detection and Ranging (LiDAR), hyper spectral visual to shortwave infrared Airborne Visual/Infrared Imaging Spectrometer (AVIRIS), and high spatial resolution multi-band thermal infrared imaging (MASTER) technologies. These technologies were used to image the fire before, during and after the fire providing unprecedented detail describing fuel conditions and availability (AVIRIS and LiDAR), fire behavior (i.e., Land Surface Temperature and Fire Radiative Power from MASTER), and fire severity (AVIRIS). Although AVIRIS and MASTER data cover the full extent of the fire before, during, and after the burn, LiDAR data only covered ~34% of the extent. We used quadratic regression (0.53 < R2 < 0. 86) to extrapolate post-fire LiDAR structural metrics to the full extent of the fire before burning. Using these structural data with dominant vegetation maps generated using weighted multiple endmember spectral mixture analysis (wMEMSA) from AVIRIS, we generated high-resolution fuel model maps. These were used as input to CAWFETM a high spatial and temporal resolution coupled weather-fire simulator. Although other fire models did not represent the King Fire very well, CAWFE did capture the unanticipated surge up the Rubicon Valley and features captured by MASTER resulted from fine-scale mountain airflows and periods of growth apparently driven by fire-induced winds. Results indicate remote sensing tools may be used to optimize data products for fire science and operations.

  3. Investigation of Contaminant Transport and Dispersion in New York Harbor by a High Resolution SF6 Tracer Study

    NASA Astrophysics Data System (ADS)

    Caplow, T.; Schlosser, P.; Ho, D. T.

    2002-12-01

    Sulfur hexafluoride (SF6) has been used successfully as a deliberate tracer for rivers, estuaries, and coastal areas, due to its inert nature, non-toxicity, and extremely low detection limit. An automated, high-resolution SF6 measurement system mounted on a boat was recently developed for several projects on the Hudson River. The system has a sampling interval of two minutes and a detection limit of 1 x 10-14 mol L-1. Real-time data visualization enables revisions of sampling strategy during the experiment. A single injection has allowed observation of advection rates, dispersion processes, and air-water gas exchange for up to two weeks, and longer experiments are possible. This equipment, with minor modifications, was applied to New York Harbor in July 2002. New York Harbor is one of the busiest seaports in the United States, processing nearly \\100 billion in cargo each year. Most of the shipping facilities are located in Newark Bay (approximately 15 km^{2}) or in two adjacent channels: the Kill van Kull (6 km long) and the Arthur Kill (20 km long). Newark Bay, which is mostly saline, is fed by the Hackensack and Passaic Rivers, both of which flow through heavily industrialized areas. Ultimately, these waters drain through the Kills to Raritan Bay and the Atlantic Ocean. Due to a combination of point sources, runoff, wastewater treatment plants, and emissions from the shipping industry, Newark Bay and the Kills receive a large volume and variety of contaminants, including petroleum, heavy metals, PCBs, and dioxins. In addition, much of the area is subject to ongoing and extensive navigational dredging, causing widespread re-suspension of previously deposited contaminants. A small quantity (ca. 2 mols) of SF_{6}$ was injected into northern Newark Bay to investigate the spreading of water throughout the Bay, the Kills, and the tidal portions of the Passaic and Hackensack Rivers. The tracer was successfully monitored across most of this area for 12 consecutive days

  4. High-Resolution Electron Energy Loss Studies of Oxygen, Hydrogen, Nitrogen, Nitric Oxide, and Nitrous Oxide Adsorption on Germanium Surfaces.

    NASA Astrophysics Data System (ADS)

    Entringer, Anthony G.

    The first high resolution electron energy loss spectroscopy (HREELS) studies of the oxidation and nitridation of germanium surfaces are reported. Both single crystal Ge(111) and disordered surfaces were studied. Surfaces were exposed to H, O_2, NO, N _2O, and N, after cleaning in ultra-high vacuum. The Ge surfaces were found to be non-reactive to molecular hydrogen (H_2) at room temperature. Exposure to atomic hydrogen (H) resulted hydrogen adsorption as demonstrated by the presence of Ge-H vibrational modes. The HREEL spectrum of the native oxide of Ge characteristic of nu -GeO_2 was obtained by heating the oxide to 200^circC. Three peaks were observed at 33, 62, and 106 meV for molecular oxygen (O_2) adsorbed on clean Ge(111) at room temperature. These peaks are indicative of dissociative bonding and a dominant Ge-O-Ge bridge structure. Subsequent hydrogen exposure resulted in a shift of the Ge-H stretch from its isolated value of 247 meV to 267 meV, indicative of a dominant +3 oxidation state. A high density of dangling bonds and defects and deeper oxygen penetration at the amorphous Ge surface result in a dilute bridge structure with a predominant +1 oxidation state for similar exposures. Molecules of N_2O decompose at the surfaces to desorbed N_2 molecules and chemisorbed oxygen atoms. In contrast, both oxygen and nitrogen are detected at the surfaces following exposure to NO molecules. Both NO and N_2O appear to dissociate and bond at the top surface layer. Molecular nitrogen (N_2) does not react with the Ge surfaces, however, a precursor Ge nitride is observed at room temperature following exposure to nitrogen atoms and ions. Removal of oxygen by heating of the NO-exposed surface to 550^circC enabled the identification of the Ge-N vibrational modes. These modes show a structure similar to that of germanium nitride. This spectrum is also identical to that of the N-exposed surface heated to 550^circC. Surface phonon modes of the narrow-gap semiconducting

  5. Monitoring the Impacts of Wildfires on Forest Ecosystems and Public Health in the Exo-Urban Environment Using High-Resolution Satellite Aerosol Products from the Visible Infrared Imaging Radiometer Suite (VIIRS).

    PubMed

    Huff, Amy K; Kondragunta, Shobha; Zhang, Hai; Hoff, Raymond M

    2015-01-01

    Increasing development of exo-urban environments and the spread of urbanization into forested areas is making humans and forest ecosystems more susceptible to the risks associated with wildfires. Larger and more damaging wildfires are having a negative impact on forest ecosystem services, and smoke from wildfires adversely affects the public health of people living in exo-urban environments. Satellite aerosol measurements are valuable tools that can track the evolution of wildfires and monitor the transport of smoke plumes. Operational users, such as air quality forecasters and fire management officials, can use satellite observations to complement ground-based and aircraft measurements of wildfire activity. To date, wildfire applications of satellite aerosol products, such as aerosol optical depth (AOD), have been limited by the relatively coarse resolution of available AOD data. However, the new Visible Infrared Imaging Radiometer Suite (VIIRS) instrument on the Suomi National Polar-orbiting Partnership (S-NPP) satellite has high-resolution AOD that is ideally suited to monitoring wildfire impacts on the exo-urban scale. Two AOD products are available from VIIRS: the 750-m × 750-m nadir resolution Intermediate Product (IP) and the 6-km × 6-km resolution Environmental Data Record product, which is aggregated from IP measurements. True color (red, green, and blue [RGB]) imagery and a smoke mask at 750-m × 750-m resolution are also available from VIIRS as decision aids for wildfire applications; they serve as counterparts to AOD meas