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Sample records for high-temperature superconducting films

  1. Use of high-temperature superconducting films in superconducting bearings.

    SciTech Connect

    Cansiz, A.

    1999-07-14

    We have investigated the effect of high-temperature superconductor (HTS) films deposited on substrates that are placed above bulk HTSs in an attempt to reduce rotational drag in superconducting bearings composed of a permanent magnet levitated above the film/bulk HTS combination. According to the critical state model, hysteresis energy loss is inversely proportional to critical current density, J{sub c}, and because HTS films typically have much higher J{sub c} than that of bulk HTS, the film/bulk combination was expected to reduce rotational losses by at least one order of magnitude in the coefficient of fiction, which in turn is a measure of the hysteresis losses. We measured rotational losses of a superconducting bearing in a vacuum chamber and compared the losses with and without a film present. The experimental results showed that contrary to expectation, the rotational losses are increased by the film. These results are discussed in terms of flux drag through the film, as well as of the critical state model.

  2. High-Temperature Superconductivity

    NASA Astrophysics Data System (ADS)

    Tanaka, Shoji

    2006-12-01

    A general review on high-temperature superconductivity was made. After prehistoric view and the process of discovery were stated, the special features of high-temperature superconductors were explained from the materials side and the physical properties side. The present status on applications of high-temperature superconductors were explained on superconducting tapes, electric power cables, magnets for maglev trains, electric motors, superconducting quantum interference device (SQUID) and single flux quantum (SFQ) devices and circuits.

  3. Use of thin films in high-temperature superconducting bearings.

    SciTech Connect

    Hull, J. R.; Cansiz, A.

    1999-09-30

    In a PM/HTS bearing, locating a thin-film HTS above a bulk HTS was expected to maintain the large levitation force provided by the bulk with a lower rotational drag provided by the very high current density of the film. For low drag to be achieved, the thin film must shield the bulk from inhomogeneous magnetic fields. Measurement of rotational drag of a PM/HTS bearing that used a combination of bulk and film HTS showed that the thin film is not effective in reducing the rotational drag. Subsequent experiments, in which an AC coil was placed above the thin-film HTS and the magnetic field on the other side of the film was measured, showed that the thin film provides good shielding when the coil axis is perpendicular to the film surface but poor shielding when the coil axis is parallel to the surface. This is consistent with the lack of reduction in rotational drag being due to a horizontal magnetic moment of the permanent magnet. The poor shielding with the coil axis parallel to the film surface is attributed to the aspect ratio of the film and the three-dimensional nature of the current flow in the film for this coil orientation.

  4. High-temperature superconductivity in potassium-coated multilayer FeSe thin films.

    PubMed

    Miyata, Y; Nakayama, K; Sugawara, K; Sato, T; Takahashi, T

    2015-08-01

    The recent discovery of possible high-temperature (T(c)) superconductivity over 65 K in a monolayer FeSe film on SrTiO3 (refs 1-6) triggered a fierce debate on how superconductivity evolves from bulk to film, because bulk FeSe crystal exhibits a T(c) of no higher than 10 K (ref. 7). However, the difficulty in controlling the carrier density and the number of FeSe layers has hindered elucidation of this problem. Here, we demonstrate that deposition of potassium onto FeSe films markedly expands the accessible doping range towards the heavily electron-doped region. Intriguingly, we have succeeded in converting non-superconducting films with various thicknesses into superconductors with T(c) as high as 48 K. We also found a marked increase in the magnitude of the superconducting gap on decreasing the FeSe film thickness, indicating that the interface plays a crucial role in realizing the high-temperature superconductivity. The results presented provide a new strategy to enhance and optimize T(c) in ultrathin films of iron-based superconductors.

  5. High-temperature superconductivity in potassium-coated multilayer FeSe thin films

    NASA Astrophysics Data System (ADS)

    Miyata, Y.; Nakayama, K.; Sugawara, K.; Sato, T.; Takahashi, T.

    2015-08-01

    The recent discovery of possible high-temperature (Tc) superconductivity over 65 K in a monolayer FeSe film on SrTiO3 (refs , , , , , ) triggered a fierce debate on how superconductivity evolves from bulk to film, because bulk FeSe crystal exhibits a Tc of no higher than 10 K (ref. ). However, the difficulty in controlling the carrier density and the number of FeSe layers has hindered elucidation of this problem. Here, we demonstrate that deposition of potassium onto FeSe films markedly expands the accessible doping range towards the heavily electron-doped region. Intriguingly, we have succeeded in converting non-superconducting films with various thicknesses into superconductors with Tc as high as 48 K. We also found a marked increase in the magnitude of the superconducting gap on decreasing the FeSe film thickness, indicating that the interface plays a crucial role in realizing the high-temperature superconductivity. The results presented provide a new strategy to enhance and optimize Tc in ultrathin films of iron-based superconductors.

  6. A review of basic phenomena and techniques for sputter-deposition of high temperature superconducting films

    SciTech Connect

    Auciello, O. North Carolina State Univ., Raleigh, NC . Dept. of Materials Science and Engineering); Ameen, M.S.; Kingon, A.I.; Lichtenwalner, D.J. . Dept. of Materials Science and Engineering); Krauss, A.R. )

    1990-01-01

    The processes involved in plasma and ion beam sputter-deposition of high temperature superconducting thin films are critically reviewed. Recent advances in the development of these techniques are discussed in relation to basic physical phenomena, specific to each technique, which must be understood before high quality films can be produced. Control of film composition is a major issue in sputter-deposition of multicomponent materials. Low temperature processing of films is a common goal for each technique, particularly in relation to integrating high temperature superconducting films with the current microelectronics technology. It has been understood for some time that for Y{sub 1}Ba{sub 2}Cu{sub 3}O{sub 7} deposition, the most intensely studied high-{Tc} compound, incorporation of sufficient oxygen into the film during deposition is necessary to produce as-deposited superconducting films at relatively substrate temperatures. Recent results have shown that with the use of suitable buffer layers, high quality Y{sub 1}Ba{sub 2}Cu{sub 3}O{sub 7} sputtered films can be obtained on Si substrates without the need for post-deposition anneal processing. This review is mainly focussed on issues related to sputter-deposition of Y{sub 1}Ba{sub 2}Cu{sub 3}O{sub 7} thin films, although representative results concerning the bismuth and thallium based compounds are included. 143 refs., 11 figs.

  7. Properties of cathodic arc deposited high-temperature superconducting composite thin films on Ag substrates

    NASA Astrophysics Data System (ADS)

    Chae, M. S.; Simnad, M. T.; Maple, M. B.; Anders, S.; Anders, A.; Brown, I. G.

    1996-02-01

    High temperature superconducting composite thin films on Ag substrates were prepared by cathodic arc deposition of alloy precursors. The deposition technique employed a cathode comprised of a precursor alloy for the vacuum arc plasma source. The precursor alloy was prepared by multiple arc-melting of mixed metallic constituents of the high-temperature superconducting material Bi 2Sr 2CaCu 2O y (Bi2212) and 50 wt.% of Ag. The presence of silver in the precursor alloy film was expected to allow accommodation of the lattice and thermal expansion mismatch between the oxidized film and the silver substrate. The as-deposited film could be formed to practically any desirable shape before being subjected to heat treatments. Following deposition, controlled oxidation of the precursor alloy thin film on the Ag substrate was performed to produce the superconducting composite on the silver substrate. After the heat treatment, the composite film consisted of Bi2212 highly c-axis oriented normal to the Ag substrate.

  8. High Temperature Superconducting Materials Database

    National Institute of Standards and Technology Data Gateway

    SRD 149 NIST High Temperature Superconducting Materials Database (Web, free access)   The NIST High Temperature Superconducting Materials Database (WebHTS) provides evaluated thermal, mechanical, and superconducting property data for oxides and other nonconventional superconductors.

  9. Lanthanum gallate substrates for epitaxial high-temperature superconducting thin films

    SciTech Connect

    Sandstrom, R.L.; Giess, E.A.; Gallagher, W.J.; Segmueller, A.; Cooper, E.I.; Chisholm, M.F.; Gupta, A.; Shinde, S.; Laibowitz, R.B.

    1988-11-07

    We demonstrate that lanthanum gallate (LaGaO/sub 3/) has considerable potential as an electronic substrate material for high-temperature superconducting films. It provides a good lattice and thermal expansion match to YBa/sub 2/Cu/sub 3/O/sub 7-//sub x/, can be grown in large crystal sizes, is compatible with high-temperature film processing, and has a reasonably low dielectric constant (epsilonapprox. =25) and low dielectric losses. Epitaxial YBa/sub 2/Cu/sub 3/O/sub 7-//sub x/ films grown on LaGaO/sub 3/ single-crystal substrates by three techniques have zero resistance between 87 and 91 K.

  10. Strain and high temperature superconductivity: unexpected results from direct electronic structure measurements in thin films.

    PubMed

    Abrecht, M; Ariosa, D; Cloetta, D; Mitrovic, S; Onellion, M; Xi, X X; Margaritondo, G; Pavuna, D

    2003-08-01

    Angle-resolved photoemission spectroscopy reveals very surprising strain-induced effects on the electronic band dispersion of epitaxial La(2-x)Sr(x)CuO(4-delta) thin films. In strained films we measure a band that crosses the Fermi level (E(F)) well before the Brillouin zone boundary. This is in contrast to the flat band reported in unstrained single crystals and in our unstrained films, as well as in contrast to the band flattening predicted by band structure calculations for in-plane compressive strain. In spite of the density of states reduction near E(F), the critical temperature increases in strained films with respect to unstrained samples. These results require a radical departure from commonly accepted notions about strain effects on high temperature superconductors, with possible general repercussions on superconductivity theory.

  11. Strain and High Temperature Superconductivity: Unexpected Results from Direct Electronic Structure Measurements in Thin Films

    NASA Astrophysics Data System (ADS)

    Abrecht, M.; Ariosa, D.; Cloetta, D.; Mitrovic, S.; Onellion, M.; Xi, X.; Margaritondo, G.; Pavuna, D.

    2003-07-01

    Angle-resolved photoemission spectroscopy reveals very surprising strain-induced effects on the electronic band dispersion of epitaxial La2-xSrxCuO4-δ thin films. In strained films we measure a band that crosses the Fermi level (EF) well before the Brillouin zone boundary. This is in contrast to the flat band reported in unstrained single crystals and in our unstrained films, as well as in contrast to the band flattening predicted by band structure calculations for in-plane compressive strain. In spite of the density of states reduction near EF, the critical temperature increases in strained films with respect to unstrained samples. These results require a radical departure from commonly accepted notions about strain effects on high temperature superconductors, with possible general repercussions on superconductivity theory.

  12. High temperature interfacial superconductivity

    SciTech Connect

    Bozovic, Ivan; Logvenov, Gennady; Gozar, Adrian Mihai

    2012-06-19

    High-temperature superconductivity confined to nanometer-scale interfaces has been a long standing goal because of potential applications in electronic devices. The spontaneous formation of a superconducting interface in bilayers consisting of an insulator (La.sub.2CuO.sub.4) and a metal (La.sub.1-xSr.sub.xCuO.sub.4), neither of which is superconducting per se, is described. Depending upon the layering sequence of the bilayers, T.sub.c may be either .about.15 K or .about.30 K. This highly robust phenomenon is confined to within 2-3 nm around the interface. After exposing the bilayer to ozone, T.sub.c exceeds 50 K and this enhanced superconductivity is also shown to originate from a 1 to 2 unit cell thick interfacial layer. The results demonstrate that engineering artificial heterostructures provides a novel, unconventional way to fabricate stable, quasi two-dimensional high T.sub.c phases and to significantly enhance superconducting properties in other superconductors. The superconducting interface may be implemented, for example, in SIS tunnel junctions or a SuFET.

  13. Deposition of High-Temperature Superconducting Thin Films on Metallic and Nometallic Substrates by Laser Ablation.

    NASA Astrophysics Data System (ADS)

    Wu, Anqi

    This dissertation covers my research in four steps: basic understanding of the theory of superconductors, development of the experimental setup, deposition of high temperature superconducting thin films (HTSTF) on metallic and nonmetallic substrates by laser ablation, and characterization HTSTFs on metallic and nonmetallic substrates. High quality HTSTFs have been grown on metallic and nonmetallic substrates, including SrTiO_3 , MgO, YSZ, Cu, Ag, Ni, and Stainless Steel. Of particular note, there have been no other successful reports of a superconducting YBa_2Cu _3O_{rm 7-x} (YBCO) film on Cu. Cu is a unique candidate for a YBCO substrate material. My investigation shows that it is possible, using laser ablation, to make good YBCO films on Cu substrates, possessing a natural oxide layer interface. The films on Cu exhibit a metallic normal state, and a resistive transition width of 6 K to zero resistance (R ~ 0) at 84 K. We determined the critical current density, J_{rm c}, to be 1,300 A/cm^2 at 13 K by the 4-probe transport method. The Naval Research Laboratory found J_{rm c} of another film to be about 3,880 A/cm ^2 at 4.2 K using the contactless single coil method. Analysis of the film compositions and structures have been made using XRD, EDAX, SEM, and AFM. STM, AFM, and high-magnification SEM images of the YBCO films on Cu show random orientation and rough surface relative to similar films on SrTiO_3, MgO, and YSZ. Due to the formation of a natural, irregular Cu oxide layer between the film and Cu substrate, the gaps between grains of YBCO on polycrystalline Cu are definitely larger than those of films deposited on single crystal such as SrTiO_3 (J_{ rm c} = 1.4 times 10^6 A/cm^2 at 77 K). This may explain the differences in J _{rm c}. The Cu-oxide layer significantly affects the quality of YBCO film on Cu because of larger lattice mismatches and thermal expansion differences between the Cu-oxide and YBCO film compared to Cu and YBCO. Applying an electric field

  14. High temperature interface superconductivity

    DOE PAGES

    Gozar, A.; Bozovic, I.

    2016-01-20

    High-Tc superconductivity at interfaces has a history of more than a couple of decades. In this review we focus our attention on copper-oxide based heterostructures and multi-layers. We first discuss the technique, atomic layer-by-layer molecular beam epitaxy (ALL-MBE) engineering, that enabled High-Tc Interface Superconductivity (HT-IS), and the challenges associated with the realization of high quality interfaces. Then we turn our attention to the experiments which shed light on the structure and properties of interfacial layers, allowing comparison to those of single-phase films and bulk crystals. Both ‘passive’ hetero-structures as well as surface-induced effects by external gating are discussed. Here, wemore » conclude by comparing HT-IS in cuprates and in other classes of materials, especially Fe-based superconductors, and by examining the grand challenges currently laying ahead for the field.« less

  15. High temperature interface superconductivity

    NASA Astrophysics Data System (ADS)

    Gozar, A.; Bozovic, I.

    2016-02-01

    High-Tc superconductivity at interfaces has a history of more than a couple of decades. In this review we focus our attention on copper-oxide based heterostructures and multi-layers. We first discuss the technique, atomic layer-by-layer molecular beam epitaxy (ALL-MBE) engineering, that enabled High-Tc Interface Superconductivity (HT-IS), and the challenges associated with the realization of high quality interfaces. Then we turn our attention to the experiments which shed light on the structure and properties of interfacial layers, allowing comparison to those of single-phase films and bulk crystals. Both 'passive' hetero-structures as well as surface-induced effects by external gating are discussed. We conclude by comparing HT-IS in cuprates and in other classes of materials, especially Fe-based superconductors, and by examining the grand challenges currently laying ahead for the field.

  16. Application of high-temperature superconducting thin-film devices to electro-optical and electronic warfare systems

    NASA Astrophysics Data System (ADS)

    Boone, B. G.

    1990-02-01

    This report gives an assessment of the impact of high-temperature superconductivity on applications in electro-optical and electronic warfare. Prior art in low-temperature superconductivity provides many examples of potential applications. It is essential that the feasibility of developing and using specific high-temperature superconducting devices, such as radiation detectors and passive microwave components, be determined before significant systems investment occurs. Research and development activities at The Johns Hopkins University Applied Physics Laboratory aimed at implementing such thin-film devices are underway.

  17. High-temperature superconductivity: A conventional conundrum

    DOE PAGES

    Božović, Ivan

    2016-01-07

    High-temperature superconductivity in ultrathin films of iron selenide deposited on strontium titanate has been attributed to various exotic mechanisms, and new experiments indicate that it may be conventional, with broader implications.

  18. Protection of high temperature superconducting thin-films in a semiconductor processing environment

    SciTech Connect

    Xu, Yizi; Fiske, R.; Sanders, S.C.; Ekin, J.W.

    1996-12-31

    Annealing studies have been carried out for high temperature superconductor YBaCuO{sub 7{minus}{delta}} in a reducing ambient, in order to identify insulator layer(s) that will effectively protect the superconducting film in the hostile environment. While a layer of magnesium oxide (MgO) sputter deposited directly on YBaCuO{sub 7{minus}{delta}} film provides some degree of protection, the authors found that a composite structure of YBCO/SrTiO{sub 3}/MgO, where the SrTiO{sub 3} was grown by laser ablation immediately following YBCO deposition (in-situ process), was much more effective. They also address the need for a buffer layer between YBCO and aluminum (Al) during annealing. Al is most commenly used for semiconductor metalization, but is known to react readily with YBCO at elevated temperatures. The authors found that the most effective buffer layers are platinum (Pt) and gold/platinum (Au/Pt).

  19. High-Temperature Superconductivity

    SciTech Connect

    Peter Johnson

    2008-11-05

    Like astronomers tweaking images to gain a more detailed glimpse of distant stars, physicists at Brookhaven National Laboratory have found ways to sharpen images of the energy spectra in high-temperature superconductors — materials that carry electrical c

  20. High-Temperature Superconductivity

    ScienceCinema

    Peter Johnson

    2016-07-12

    Like astronomers tweaking images to gain a more detailed glimpse of distant stars, physicists at Brookhaven National Laboratory have found ways to sharpen images of the energy spectra in high-temperature superconductors — materials that carry electrical c

  1. High temperature superconducting FeSe films on SrTiO3 substrates

    PubMed Central

    Sun, Yi; Zhang, Wenhao; Xing, Ying; Li, Fangsen; Zhao, Yanfei; Xia, Zhengcai; Wang, Lili; Ma, Xucun; Xue, Qi-Kun; Wang, Jian

    2014-01-01

    Interface enhanced superconductivity at two dimensional limit has become one of most intriguing research directions in condensed matter physics. Here, we report the superconducting properties of ultra-thin FeSe films with the thickness of one unit cell (1-UC) grown on conductive and insulating SrTiO3 (STO) substrates. For the 1-UC FeSe on conductive STO substrate (Nb-STO), the magnetization versus temperature (M-T) measurement shows a drop crossover around 85 K. For the FeSe films on insulating STO substrate, systematic transport measurements were carried out and the sheet resistance of FeSe films exhibits Arrhenius TAFF behavior with a crossover from a single-vortex pinning region to a collective creep region. More intriguing, sign reversal of Hall resistance with temperature is observed, demonstrating a crossover from hole conduction to electron conduction above TC in 1-UC FeSe films. PMID:25113391

  2. High temperature superconducting thin film microwave circuits: Fabrication, characterization, and applications

    NASA Technical Reports Server (NTRS)

    Bhasin, K. B.; Warner, J. D.; Romanofsky, R. R.; Heinen, V. O.; Chorey, C. M.

    1990-01-01

    Epitaxial YBa2Cu3O7 films were grown on several microwave substrates. Surface resistance and penetration depth measurements were performed to determine the quality of these films. Here the properties of these films on key microwave substrates are described. The fabrication and characterization of a microwave ring resonator circuit to determine transmission line losses are presented. Lower losses than those observed in gold resonator circuits were observed at temperatures lower than critical transition temperature. Based on these results, potential applications of microwave superconducting circuits such as filters, resonators, oscillators, phase shifters, and antenna elements in space communication systems are identified.

  3. Microwave applications and characterization of the microwave properties of high temperature superconducting films

    NASA Technical Reports Server (NTRS)

    Strayer, D. M.; Bautista, J. J.; Riley, A. L.; Dick, G. J.; Housley, R. L.

    1990-01-01

    The development by NASA JPL of high-temperature superconductors (HTSs) for use in microwave circuit elements is discussed. The synthesis of HTS films and characterization of their microwave absorption are reviewed. Applications to cryogenic low-noise receivers, spacecraft microwave systems, and low-noise oscillators are considered.

  4. Large oscillations of the magnetoresistance in nanopatterned high-temperature superconducting films.

    PubMed

    Sochnikov, Ilya; Shaulov, Avner; Yeshurun, Yosef; Logvenov, Gennady; Bozović, Ivan

    2010-07-01

    Measurements on nanoscale structures constructed from high-temperature superconductors are expected to shed light on the origin of superconductivity in these materials. To date, loops made from these compounds have had sizes of the order of hundreds of nanometres(8-11). Here, we report the results of measurements on loops of La(1.84)Sr(0.16)CuO(4), a high-temperature superconductor that loses its resistance to electric currents when cooled below approximately 38 K, with dimensions down to tens of nanometres. We observe oscillations in the resistance of the loops as a function of the magnetic flux through the loops. The oscillations have a period of h/2e, and their amplitude is much larger than the amplitude of the resistance oscillations expected from the Little-Parks effect. Moreover, unlike Little-Parks oscillations, which are caused by periodic changes in the superconducting transition temperature, the oscillations we observe are caused by periodic changes in the interaction between thermally excited moving vortices and the oscillating persistent current induced in the loops. However, despite the enhanced amplitude of these oscillations, we have not detected oscillations with a period of h/e, as recently predicted for nanoscale loops of superconductors with d-wave symmetry, or with a period of h/4e, as predicted for superconductors that exhibit stripes. PMID:20543834

  5. Superconducting properties of very high quality NbN thin films grown by high temperature chemical vapor deposition

    NASA Astrophysics Data System (ADS)

    Hazra, D.; Tsavdaris, N.; Jebari, S.; Grimm, A.; Blanchet, F.; Mercier, F.; Blanquet, E.; Chapelier, C.; Hofheinz, M.

    2016-10-01

    Niobium nitride (NbN) is widely used in high-frequency superconducting electronics circuits because it has one of the highest superconducting transition temperatures ({T}{{c}}˜ 16.5 {{K}}) and largest gap among conventional superconductors. In its thin-film form, the T c of NbN is very sensitive to growth conditions and it still remains a challenge to grow NbN thin films (below 50 nm) with high T c. Here, we report on the superconducting properties of NbN thin films grown by high-temperature chemical vapor deposition (HTCVD). Transport measurements reveal significantly lower disorder than previously reported, characterized by a Ioffe-Regel parameter ({k}{{F}}{\\ell }) ˜ 12. Accordingly we observe {T}{{c}}˜ 17.06 {{K}} (point of 50% of normal state resistance), the highest value reported so far for films of thickness 50 nm or less, indicating that HTCVD could be particularly useful for growing high quality NbN thin films.

  6. Electronic properties of high-temperature superconducting thin films grown by pulsed laser deposition

    NASA Astrophysics Data System (ADS)

    Abrecht, M.; Ariosa, Daniel; Cloetta, D.; Margaritondo, Giorgio; Pavuna, Davor

    2002-11-01

    We use a pulsed laser deposition (PLD) setup to grow ultra-thin films of high temperature superconductors (HTSC) and transfer them in-situ into a photoemission chamber. Photoemission measurements on such films allow us to study non-cleavable materials, but can also give insights into aspects never measured before, like the influence of strain on the low energy electronic structure. Systematic studies of many different materials grown as films showed that Bi2Sr2CaCu2O8+x, Bi2Sr2Cu1O6+x, Bi2Sr2Ca2Cu3O10+x and La2-xSrxCuO4 films exhibit a conductor-like Fermi edge, but materials containing chains (such as YBa2Cu3O7-x) are prone to very rapid surface degradation, possibly related to critical oxygen loss at the surface. Among HTSC materials, La2-xSrxCuO4 is extremely interesting because of its rather simple structure and the fact that its critical temperature Tc can be enhanced by epitaxial strain. Here we present our first high resolution angular resolved photoemission spectroscopy (ARPES) results on 8 unit-cell thin La2-xSrxCuO4 films on SrLaAlO4 [001] substrates. Due to the lattice mismatch, such films are compressed in the copper oxygen planes and expanded in the c-axis direction. Results show a surprisingly modified Fermi surface compared to the one of non-strained samples.

  7. Development of Energy-Efficient Cryogenic Leads with High Temperature Superconducting Films on Ceramic Substrates

    NASA Astrophysics Data System (ADS)

    Pan, A. V.; Fedoseev, S. A.; Shcherbakova, O. V.; Golovchanskiy, I. A.; Zhou, S.; Dou, S. X.; Webber, R. J.; Mukhanov, O. A.; Yamashita, T.; Taylor, R.

    High temperature superconductor (HTS) material can be used for the implementation of high-speed low-heat conduction data links to transport digital data from 4 K superconductor integrated circuits to higher-temperature parts of computing systems. In this work, we present a conceptual design of energy efficient interface and results in fabricating such HTS leads. Initial calculations have shown that the microstrip line cable geometry for typical materials employed in production of HTS thin films can be a two-layered film for which the two layers of about 10 cm long are separated by an insulation layer with as low permittivity as possible. With this architecture in mind, the pulsed laser deposition process has been designed in a 45 cm diameter vacuum chamber to incorporate an oscillating sample holder with homogeneous substrate heating up to 900°C, while the laser plume is fixed. This design has allowed us to produce 200 nm to 500 nm thick, 7 cm to 10 cm long YBa2Cu3O7 thin films with the homogeneous critical temperature (Tc) of about 90 K. The critical current density (Jc) of the short samples obtained from the long sample is of (2 ± 1) × 1010 A/m2. Lines of 3-100 μm wide have been successfully patterned along the length of the samples in order to directly measure the Tc and Jc values over the entire length of the samples, as well as to attempt the structuring of multichannel data lead prototype.

  8. High Temperature Superconducting Underground Cable

    SciTech Connect

    Farrell, Roger, A.

    2010-02-28

    The purpose of this Project was to design, build, install and demonstrate the technical feasibility of an underground high temperature superconducting (HTS) power cable installed between two utility substations. In the first phase two HTS cables, 320 m and 30 m in length, were constructed using 1st generation BSCCO wire. The two 34.5 kV, 800 Arms, 48 MVA sections were connected together using a superconducting joint in an underground vault. In the second phase the 30 m BSCCO cable was replaced by one constructed with 2nd generation YBCO wire. 2nd generation wire is needed for commercialization because of inherent cost and performance benefits. Primary objectives of the Project were to build and operate an HTS cable system which demonstrates significant progress towards commercial progress and addresses real world utility concerns such as installation, maintenance, reliability and compatibility with the existing grid. Four key technical areas addressed were the HTS cable and terminations (where the cable connects to the grid), cryogenic refrigeration system, underground cable-to-cable joint (needed for replacement of cable sections) and cost-effective 2nd generation HTS wire. This was the world’s first installation and operation of an HTS cable underground, between two utility substations as well as the first to demonstrate a cable-to-cable joint, remote monitoring system and 2nd generation HTS.

  9. Perspectives on high temperature superconducting electronics

    NASA Technical Reports Server (NTRS)

    Venkatesan, T.

    1990-01-01

    The major challenges in making high temperature superconducting (HTSC) electronics viable are predominantly materials problems. Unlike their predecessors the metal oxide-based superconductors are integratable with other advanced technologies such as opto-electronics and micro-electronics. The materials problems to be addressed relate to the epitaxial growth of high quality films, highly oriented films on non-lattice matched substrates, heterostructures with atomically sharp interfaces of junctions and other novel devices, and the processing of these films with negligible deterioration of the superconducting properties. These issues are illustrated with results based on films prepared in-situ by a pulsed laser deposition process. Films with zero-transition temperatures of 90 K and critical current densities of 5 x 10(exp 6) A/sq cm at 77 K have been prepared by this technique. Ultra-thin films, less than 100 A show T(sub c) is greater than 80 K, supporting the idea of two-dimensional transport in these materials. By the use of appropriate buffer layers, films with T(sub c) of 87 K and J(sub c) of 6 x 10(exp 4) A/sq cm were fabricated on silicon substrates. Submicron structures with J(sub c) is greater than 2 x 10(exp 7) at 10 K were fabricated. Results on nonlinear switching elements, IR detectors, and microwave studies will be briefly summarized.

  10. Perspectives on high temperature superconducting electronics

    NASA Technical Reports Server (NTRS)

    Venkatesan, T.

    1991-01-01

    The major challenges in making high temperature superconducting (HTSC) electronics viable are predominantly materials problems. Unlike their predecessors, the metal oxide-based superconductors are integratable with other advanced technologies such as opto-electronics and micro-electronics. The materials problems to be addressed relate to the epitaxial growth of high quality films, highly oriented films on non-lattice matched substrates, heterostructures with atomically sharp interfaces of junctions and other novel devices, and the processing of these films with negligible deterioration of the superconducting properties. These issues are illustrated with results based on films prepared in-situ by a pulsed laser deposition process. Films with zero-transition temperatures of 90 K and critical current densities of 5 x 10(exp 6) A/sq cm at 77 K have been prepared by this technique. Ultra-thin films, less than 100 A show T(sub c) is greater than 80 K, supporting the idea of two-dimensional transport in these materials. By the use of appropriate buffer layers, films with T(sub c) of 87 K and J(sub c) of 6 x 10(exp 4) A/sq cm were fabricated on silicon substrates. Submicron structures with J(sub c) is greater than 2 x 10(exp 7) at 10 K were fabricated. Results on nonlinear switching elements, IR detectors, and microwave studies will be briefly summarized.

  11. The NASA high temperature superconductivity program

    NASA Technical Reports Server (NTRS)

    Sokoloski, Martin M.; Romanofsky, Robert R.

    1990-01-01

    It has been recognized from the onset that high temperature superconductivity held great promise for major advances across a broad range of NASA interests. The current effort is organized around four key areas: communications and data, sensors and cryogenics, propulsion and power, and space materials technology. Recently, laser ablated YBa2Cu3O(7-x) films on LaAIO produced far superior RF characteristics when compared to metallic films on the same substrate. This achievement has enabled a number of unique microwave device applications, such as low insertion loss phase shifters and high Q filters. Melt texturing and melt quenched techniques are being used to produce bulk materials with optimized magnetic properties. These yttrium enriched materials possess enhanced flux pinning characteristics and will lead to prototype cryocooler bearings. Significant progress has also occurred in bolometer and current lead technology. Studies are being conducted to evaluate the effect of high temperature superconducting materials on the performance and life of high power magneto-plasma-dynamic thrusters. Extended studies were also performed to evaluate the benefit of superconducting magnetic energy storage for LEO space station, lunar and Mars mission applications. The project direction and level of effort of the program are also described.

  12. High-Temperature Superconductivity in Single-Unit-Cell FeSe Films on Anatase TiO_{2}(001).

    PubMed

    Ding, Hao; Lv, Yan-Feng; Zhao, Kun; Wang, Wen-Lin; Wang, Lili; Song, Can-Li; Chen, Xi; Ma, Xu-Cun; Xue, Qi-Kun

    2016-08-01

    We report on the observation of high-temperature (T_{c}) superconductivity and magnetic vortices in single-unit-cell FeSe films on anatase TiO_{2}(001) substrate by using scanning tunneling microscopy. A systematic study and engineering of interfacial properties has clarified the essential roles of substrate in realizing the high-T_{c} superconductivity, probably via interface-induced electron-phonon coupling enhancement and charge transfer. By visualizing and tuning the oxygen vacancies at the interface, we find their very limited effect on the superconductivity, which excludes interfacial oxygen vacancies as the primary source for charge transfer between the substrate and FeSe films. Our findings have placed severe constraints on any microscopic model for the high-T_{c} superconductivity in FeSe-related heterostructures.

  13. High-Temperature Superconductivity in Single-Unit-Cell FeSe Films on Anatase TiO_{2}(001).

    PubMed

    Ding, Hao; Lv, Yan-Feng; Zhao, Kun; Wang, Wen-Lin; Wang, Lili; Song, Can-Li; Chen, Xi; Ma, Xu-Cun; Xue, Qi-Kun

    2016-08-01

    We report on the observation of high-temperature (T_{c}) superconductivity and magnetic vortices in single-unit-cell FeSe films on anatase TiO_{2}(001) substrate by using scanning tunneling microscopy. A systematic study and engineering of interfacial properties has clarified the essential roles of substrate in realizing the high-T_{c} superconductivity, probably via interface-induced electron-phonon coupling enhancement and charge transfer. By visualizing and tuning the oxygen vacancies at the interface, we find their very limited effect on the superconductivity, which excludes interfacial oxygen vacancies as the primary source for charge transfer between the substrate and FeSe films. Our findings have placed severe constraints on any microscopic model for the high-T_{c} superconductivity in FeSe-related heterostructures. PMID:27541474

  14. High-Temperature Superconductivity in Single-Unit-Cell FeSe Films on Anatase TiO2(001 )

    NASA Astrophysics Data System (ADS)

    Ding, Hao; Lv, Yan-Feng; Zhao, Kun; Wang, Wen-Lin; Wang, Lili; Song, Can-Li; Chen, Xi; Ma, Xu-Cun; Xue, Qi-Kun

    2016-08-01

    We report on the observation of high-temperature (Tc) superconductivity and magnetic vortices in single-unit-cell FeSe films on anatase TiO2(001 ) substrate by using scanning tunneling microscopy. A systematic study and engineering of interfacial properties has clarified the essential roles of substrate in realizing the high-Tc superconductivity, probably via interface-induced electron-phonon coupling enhancement and charge transfer. By visualizing and tuning the oxygen vacancies at the interface, we find their very limited effect on the superconductivity, which excludes interfacial oxygen vacancies as the primary source for charge transfer between the substrate and FeSe films. Our findings have placed severe constraints on any microscopic model for the high-Tc superconductivity in FeSe-related heterostructures.

  15. Dimensionality of high temperature superconductivity in oxides

    NASA Technical Reports Server (NTRS)

    Chu, C. W.

    1989-01-01

    Many models have been proposed to account for the high temperature superconductivity observed in oxide systems. Almost all of these models proposed are based on the uncoupled low dimensional carrier Cu-O layers of the oxides. Results of several experiments are presented and discussed. They suggest that the high temperature superconductivity observed cannot be strictly two- or one-dimensional, and that the environment between the Cu-O layers and the interlayer coupling play an important role in the occurrence of such high temperature superconductivity. A comment on the very short coherence length reported is also made.

  16. Phase diagram and electronic indication of high-temperature superconductivity at 65 K in single-layer FeSe films.

    PubMed

    He, Shaolong; He, Junfeng; Zhang, Wenhao; Zhao, Lin; Liu, Defa; Liu, Xu; Mou, Daixiang; Ou, Yun-Bo; Wang, Qing-Yan; Li, Zhi; Wang, Lili; Peng, Yingying; Liu, Yan; Chen, Chaoyu; Yu, Li; Liu, Guodong; Dong, Xiaoli; Zhang, Jun; Chen, Chuangtian; Xu, Zuyan; Chen, Xi; Ma, Xucun; Xue, Qikun; Zhou, X J

    2013-07-01

    The recent discovery of possible high-temperature superconductivity in single-layer FeSe films has generated significant experimental and theoretical interest. In both the cuprate and the iron-based high-temperature superconductors, superconductivity is induced by doping charge carriers into the parent compound to suppress the antiferromagnetic state. It is therefore important to establish whether the superconductivity observed in the single-layer sheets of FeSe--the essential building blocks of the Fe-based superconductors--is realized by undergoing a similar transition. Here we report the phase diagram for an FeSe monolayer grown on a SrTiO3 substrate, by tuning the charge carrier concentration over a wide range through an extensive annealing procedure. We identify two distinct phases that compete during the annealing process: the electronic structure of the phase at low doping (N phase) bears a clear resemblance to the antiferromagnetic parent compound of the Fe-based superconductors, whereas the superconducting phase (S phase) emerges with the increase in doping and the suppression of the N phase. By optimizing the carrier concentration, we observe strong indications of superconductivity with a transition temperature of 65±5 K. The wide tunability of the system across different phases makes the FeSe monolayer ideal for investigating not only the physics of superconductivity, but also for studying novel quantum phenomena more generally.

  17. High temperature superconducting fault current limiter

    DOEpatents

    Hull, John R.

    1997-01-01

    A fault current limiter (10) for an electrical circuit (14). The fault current limiter (10) includes a high temperature superconductor (12) in the electrical circuit (14). The high temperature superconductor (12) is cooled below its critical temperature to maintain the superconducting electrical properties during operation as the fault current limiter (10).

  18. High temperature superconducting fault current limiter

    DOEpatents

    Hull, J.R.

    1997-02-04

    A fault current limiter for an electrical circuit is disclosed. The fault current limiter includes a high temperature superconductor in the electrical circuit. The high temperature superconductor is cooled below its critical temperature to maintain the superconducting electrical properties during operation as the fault current limiter. 15 figs.

  19. Introduction to high-temperature superconductivity

    SciTech Connect

    Sheahen, T.P.

    1994-12-31

    The Electric Power Research Institute, as part of its program to develop high-temperature superconductivity applications for the power industry, has endevoured to educate utility engineers and executives on superconductivity. This book is a series of tutorials prepared by the Argonne National Laboratory. Part one is at an introductory level, asking and answering the question `What is superconductivity?` Part 2 is an exposition of the basic properties of the new materials - structure, phase equilibria, effects of doping, etc. with consideration of theoretical issues. Part 3 covers potential practical uses of high temperature superconductors.

  20. The high temperature superconductivity space experiment

    NASA Technical Reports Server (NTRS)

    Webb, Denis C.; Nisenoff, M.

    1991-01-01

    The history and the current status of the high temperature superconductivity space experiment (HTSSE) initiated in 1988 are briefly reviewed. The goal of the HTSSE program is to demonstrate the feasibility of incorporating high temperature superconductivity (HTS) technology into space systems. The anticipated payoffs include the development of high temperature superconductor devices for space systems; preparation and space qualification of a cryogenically cooled experimental package containing HTS devices and components; and acquisition of data for future space experiments using more complex HTS devices and subsystems. The principal HTSSE systems and devices are described.

  1. A high temperature superconductivity communications flight experiment

    NASA Technical Reports Server (NTRS)

    Ngo, P.; Krishen, K.; Arndt, D.; Raffoul, G.; Karasack, V.; Bhasin, K.; Leonard, R.

    1992-01-01

    The proposed high temperature superconductivity (HTSC) millimeter-wave communications flight experiment from the payload bay of the Space Shuttle Orbiter to the Advanced Communications Technology Satellite (ACTS) in geosynchronous orbit is described. The experiment will use a Ka-band HTSC phased array antenna and front-end electronics to receive a downlink communications signal from the ACTS. The discussion covers the system configuration, a description of the ground equipment, the spacecraft receiver, link performance, thermal loading, and the superconducting antenna array.

  2. Space applications of high temperature superconductivity technology

    NASA Technical Reports Server (NTRS)

    Connolly, D. J.; Aron, P. R.; Leonard, R. F.; Wintucky, E. G.

    1991-01-01

    A review is presented of the present status of high temperature superconductivity (HTS) technology and related areas of potential space application. Attention is given to areas of application that include microwave communications, cryogenic systems, remote sensing, and space propulsion and power. Consideration is given to HTS phase shifters, miniaturization of microwave filters, far-IR bolometers, and magnetic refrigeration using flux compression.

  3. High-Temperature-Superconductor Films In Microwave Circuits

    NASA Technical Reports Server (NTRS)

    Bhasin, K. B.; Warner, J. D.; Romanofsky, R. R.; Heinen, V. O.; Chorey, C. M.

    1993-01-01

    Report discusses recent developments in continuing research on fabrication and characterization of thin films of high-temperature superconducting material and incorporation of such films into microwave circuits. Research motivated by prospect of exploiting superconductivity to reduce electrical losses and thereby enhancing performance of such critical microwave components as ring resonators, filters, transmission lines, phase shifters, and feed lines in phased-array antennas.

  4. Magnetic suspension using high temperature superconducting cores

    NASA Technical Reports Server (NTRS)

    Scurlock, R. G.

    1992-01-01

    The development of YBCO high temperature superconductors, in wire and tape forms, is rapidly approaching the point where the bulk transport current density j vs magnetic field H characteristics with liquid nitrogen cooling will enable its use in model cores. On the other hand, BSCCO high temperature superconductor in wire form has poor j-H characteristics at 77 K today, although with liquid helium or hydrogen cooling, it appears to be superior to NbTi superconductor. Since liquid nitrogen cooling is approx. 100 times cheaper than liquid helium cooling, the use of YBCO is very attractive for use in magnetic suspension. The design is discussed of a model core to accommodate lift and drag loads up to 6000 and 3000 N respectively. A comparison is made between the design performance of a liquid helium cooled NbTi (or BSCCO) superconducting core and a liquid nitrogen cooled YBCO superconducting core.

  5. Aerospace applications of high temperature superconductivity

    NASA Technical Reports Server (NTRS)

    Heinen, V. O.; Connolly, D. J.

    1991-01-01

    Space application of high temperature superconducting (HTS) materials may occur before most terrestrial applications because of the passive cooling possibilities in space and because of the economic feasibility of introducing an expensive new technology which has a significant system benefit in space. NASA Lewis Research Center has an ongoing program to develop space technology capitalizing on the potential benefit of HTS materials. The applications being pursued include space communications, power and propulsion systems, and magnetic bearings. In addition, NASA Lewis is pursuing materials research to improve the performance of HTS materials for space applications.

  6. Parameters of high-temperature superconducting transformers

    NASA Astrophysics Data System (ADS)

    Volkov, E. P.; Dzhafarov, E. A.

    2015-12-01

    Parameters of the high-temperature superconducting (HTSC) transformer with a core-type magnetic circuit and with coaxial and symmetrical interleaved windings made of the first-generation HTSC wire with a localized magnetic field are considered. The parameters of the most widespread core-type transformer with a coaxial HTSC winding are compared with those of a conventional transformer with a copper wire winding. Advantages of the HTSC transformers, such as reduction in the leakage inductive reactance and the HTSC winding's cross section, volume, and mass, as compared with the same parameters of conventional transformers with a copper wire winding are demonstrated. The efficiency of the HTSC transformers has proven to be determined predominantly by the core loss. In order to increase the efficiency of the HTSC transformer, it is proposed to use the amorphous electrical steel as the material of its magnetic circuit.

  7. Aerospace applications of high temperature superconductivity

    NASA Technical Reports Server (NTRS)

    Connolly, D. J.; Heinen, V. O.; Aron, P. R.; Lazar, J.; Romanofsky, Robert R.

    1990-01-01

    A review is presented of all the applications that are part of the NASA program to develop space technology capitalizing on the potential benefit of high temperature superconducting materials. The applications in three major areas are being pursued: sensors and cryogenic systems, space communications, and propulsion and power systems. This review places emphasis on space communications applications and the propulsion and power applications. It is concluded that the power and propulsion applications will eventually be limited by structural considerations rather than by the availability of suitable superconductors. A cursory examination of structural limitations implied by the virial theorem suggested that there is an upper limit to the size of high field magnetic systems that are feasible in space.

  8. High temperature superconductivity space experiment (HTSSE)

    NASA Technical Reports Server (NTRS)

    Ritter, J. C.; Nisenoff, M.; Price, G.; Wolf, S. A.

    1991-01-01

    An experiment dealing with high-temperature superconducting devices and components in space is discussed. A variety of devices (primarily passive microwave and millimeter-wave components) has been procured and will be integrated with a cryogenic refrigerating and data acquisition system to form the space package, which will be launched in late 1992. This space experiment is expected to demonstrate that this technology is sufficiently robust to survive the space environment and that the technology has the potential to improve the operation of space systems significantly. The devices for the initial launch have been evaluated electrically, thermally, and mechanically, and will be integrated into the final space package early in 1991. The performance of the devices is summarized, and some potential applications of this technology in space systems are outlined.

  9. Polaron models of high-temperature superconductivity

    NASA Astrophysics Data System (ADS)

    Mott, N. F.

    1993-01-01

    A review is given of theories of high-temperature superconductors in which the current is carried by bipolarons, which form a condensed Bose gas below Tc and a non-degenerate gas above it. Such theories were first proposed by Schafroth, Alexandrov, Ranninger and de Jongh; the present author has, for the copper oxide materials, proposed spin bipolarons. Experimental work has, however, shown no magnetic moments in the superconducting and “spin glass” ranges of composition; a modification of the spin bipolaron model is proposed to take account of these observations. Other aspects of the model are discussed, particularly heat conduction and the effect of disorder. A comparison is made with the cubic bismuth materials.

  10. High Temperature Superconductivity and Cold Fusion

    NASA Astrophysics Data System (ADS)

    Rabinowitz, Mario

    There are numerous historical and scientific parallels between high temperature superconductivity (HTSC) and the newly emerging field of cold fusion (CF). Just as the charge carrier effective mass plays an important role in SC, the deuteron effective mass may play a vital role in CF. A new theory including effects of proximity, electron shielding, and decreased effective mass of the fusing nuclei can account for the reported CF results. A quantum-gas model that covers the range from low temperature to superhigh temperature SC indicates an increased Tc with reduced dimensionality. A reduced dimensionality effect may also enhance CF. A relation is shown between CF and the significant cluster-impact fusion experiments.

  11. Model for the Vaporization of Mixed Organometallic Compounds in the Metalorganic Chemical Vapor Deposition of High Temperature Superconducting Films

    NASA Technical Reports Server (NTRS)

    Meng, Guangyao; Zhou, Gang; Schneider, Roger L.; Sarma, Bimal K.; Levy, Moises

    1993-01-01

    A model of the vaporization and mass transport of mixed organometallics from a single source for thin film metalorganic chemical vapor deposition is presented. A stoichiometric gas phase can be obtained from a mixture of the organometallics in the desired mole ratios, in spite of differences in the volatilities of the individual compounds. Proper film composition and growth rates are obtained by controlling the velocity of a carriage containing the organometallics through the heating zone of a vaporizer.

  12. JETC (Japanese Technology Evaluation Center) Panel Report on High Temperature Superconductivity in Japan

    NASA Technical Reports Server (NTRS)

    Shelton, Duane; Gamota, George

    1989-01-01

    The Japanese regard success in R and D in high temperature superconductivity as an important national objective. The results of a detailed evaluation of the current state of Japanese high temperature superconductivity development are provided. The analysis was performed by a panel of technical experts drawn from U.S. industry and academia, and is based on reviews of the relevant literature and visits to Japanese government, academic and industrial laboratories. Detailed appraisals are presented on the following: Basic research; superconducting materials; large scale applications; processing of superconducting materials; superconducting electronics and thin films. In all cases, comparisons are made with the corresponding state-of-the-art in the United States.

  13. High Temperature Superconducting Thick Films

    DOEpatents

    Arendt, Paul N.; Foltyn, Stephen R.; Groves, James R.; Holesinger, Terry G.; Jia, Quanxi

    2005-08-23

    An article including a substrate, a layer of an inert oxide material upon the surface of the substrate, (generally the inert oxide material layer has a smooth surface, i.e., a RMS roughness of less than about 2 nm), a layer of an amorphous oxide or oxynitride material upon the inert oxide material layer, a layer of an oriented cubic oxide material having a rock-salt-like structure upon the amorphous oxide material layer is provided together with additional layers such as at least one layer of a buffer material upon the oriented cubic oxide material layer or a HTS top-layer of YBCO directly upon the oriented cubic oxide material layer. With a HTS top-layer of YBCO upon at least one layer of a buffer material in such an article, Jc's of 1.4×106 A/cm2 have been demonstrated with projected Ic's of 210 Amperes across a sample 1 cm wide.

  14. High temperature superconducting magnetic energy storage for future NASA missions

    NASA Technical Reports Server (NTRS)

    Faymon, Karl A.; Rudnick, Stanley J.

    1988-01-01

    Several NASA sponsored studies based on 'conventional' liquid helium temperature level superconductivity technology have concluded that superconducting magnetic energy storage has considerable potential for space applications. The advent of high temperature superconductivity (HTSC) may provide additional benefits over conventional superconductivity technology, making magnetic energy storage even more attractive. The proposed NASA space station is a possible candidate for the application of HTSC energy storage. Alternative energy storage technologies for this and other low Earth orbit missions are compared.

  15. High-temperature superconductivity: Electron mirages in an iron salt

    NASA Astrophysics Data System (ADS)

    Zaanen, Jan

    2014-11-01

    The detection of unusual 'mirage' energy bands in photoemission spectra of single-atom layers of iron selenide reveals the probable cause of high-temperature superconductivity in these artificial structures. See Letter p.245

  16. High-Temperature Superconductivity in the Yttrium Barium-Copper System: Thin Film Growth, Grain Boundary Effects and Interlayer Coupling Mechanisms

    NASA Astrophysics Data System (ADS)

    Chen, Ling

    The present work addresses key scientific and technical issues pertaining to the establishment of an improved understanding of the physical mechanisms of superconductivity and the development of a technologically useful process for the growth of YBCO films. The first section describes the successful development of a technologically useful CVD process for the growth of high quality YBCO ultrathin and multilayered structures on metallic and insulating substrates for energy-related, microwave, and microelectronic applications. In particular, the process was employed to deposit epitaxial YBCO films on single-crystal dielectric substrates, such as LaAlO _3 and SrTiO_3 at growth rates >700 A/min. Films above 500 A on SrTiO_3 exhibited a T _{rm c} of 92 K, a J _{rm c} of 2times10 ^6 A/cm^2 (77K, B = 0), no weak-link behavior in magnetic field up to 1 Tesla, and a surface resistance R_{rm s} of 309 muOmega (10 GHz, 77 K), which is comparable to the best PVD YBCO films. Corresponding investigations of the mechanisms of early film nucleation and growth led to the identification of appropriate growth modes and the successful production of high quality superconducting ultrathin YBCO layers down to 60 A. In particular, it is shown that the nature of YBCO growth is greatly influenced by substrate morphology, chemical condition and lattice mismatch, with the early stages of growth on LaAlO_3 and MgO following, respectively, the Frank-van der Merwe and Volmer Weber modes. Additionally, the improved quality of YBCO films on silver substrates was partially explained by the key role of the substrate processing temperature in not only affecting YBCO nucleation and growth but also in the recrystallization of silver substrates, which in turn greatly influenced film growth. In addition, experimental observations concerning the existence of a T_{rm c} ~ 30 K in a unit-cell thick YBCO layer and the effects on T_{rm c} of composition and dimensions of multilayered superconductor structures

  17. High temperature superconductive flux gate magnetometer

    SciTech Connect

    Gershenson, M. )

    1991-03-01

    This paper proposes a different type of HTS superconducting magnetometer based on the non-linear magnetic behavior of bulk HTS materials. The device design is based on the generation of second harmonics which arise as a result of non-linear magnetization observed in Type-II superconductors. Even harmonics are generated from the non-linear interaction of an ac excitation signal with an external DC magnetic field which acts as a bias signal.

  18. The characteristic electronic structure needed for high-temperature superconductivity

    NASA Astrophysics Data System (ADS)

    Pyper, N. C.; Edwards, P. P.

    1991-01-01

    It is shown that the magnon mechanism proposed by Goddard and co-workers to explain high-temperature superconductivity in oxidized cuprates can also account for such superconductivity in both oxidized barium bismuthate and the electron superconductors based on neodynium cuprate. The specific and characteristic electronic structure required for the operation of the magnon mechanism naturally accounts for why only a small number of basic types of high-temperature superconductors are currently known. This mechanism can readily explain the effects of doping cuprate superconductors with both magnetic and non-magnetic ions.

  19. Damping in high-temperature superconducting levitation systems

    DOEpatents

    Hull, John R.

    2009-12-15

    Methods and apparatuses for improved damping in high-temperature superconducting levitation systems are disclosed. A superconducting element (e.g., a stator) generating a magnetic field and a magnet (e.g. a rotor) supported by the magnetic field are provided such that the superconducting element is supported relative to a ground state with damped motion substantially perpendicular to the support of the magnetic field on the magnet. Applying this, a cryostat housing the superconducting bearing may be coupled to the ground state with high damping but low radial stiffness, such that its resonant frequency is less than that of the superconducting bearing. The damping of the cryostat may be substantially transferred to the levitated magnetic rotor, thus, providing damping without affecting the rotational loss, as can be derived applying coupled harmonic oscillator theory in rotor dynamics. Thus, damping can be provided to a levitated object, without substantially affecting the rotational loss.

  20. High-Temperature Capacitor Polymer Films

    NASA Astrophysics Data System (ADS)

    Tan, Daniel; Zhang, Lili; Chen, Qin; Irwin, Patricia

    2014-12-01

    Film capacitor technology has been under development for over half a century to meet various applications such as direct-current link capacitors for transportation, converters/inverters for power electronics, controls for deep well drilling of oil and gas, direct energy weapons for military use, and high-frequency coupling circuitry. The biaxially oriented polypropylene film capacitor remains the state-of-the-art technology; however, it is not able to meet increasing demand for high-temperature (>125°C) applications. A number of dielectric materials capable of operating at high temperatures (>140°C) have attracted investigation, and their modifications are being pursued to achieve higher volumetric efficiency as well. This paper highlights the status of polymer dielectric film development and its feasibility for capacitor applications. High-temperature polymers such as polyetherimide (PEI), polyimide, and polyetheretherketone were the focus of our studies. PEI film was found to be the preferred choice for high-temperature film capacitor development due to its thermal stability, dielectric properties, and scalability.

  1. Plasma synthesis of high temperature ceramic films

    SciTech Connect

    Brown, I.G.; Monteiro, O.R.

    1998-11-01

    Thin films of alumina, chromia, mullite, yttria and zirconia have been synthesized using a plasma-based method called metal plasma immersion ion implantation and deposition (Mepiiid)--a highly versatile plasma deposition technique with ion energy control. Monolithic films (a single ceramic component) and multilayer films (individual layers of different ceramic materials) were formed. The films were characterized for their composition and structure in a number of different ways, and the high temperature performance of the films was explored, particularly for their ability to maintain their integrity and adhesion when subjected to repetitive high temperature thermal cycling up 1100 C. We found that the films retain their adhesion and quality without any apparent degradation with time, even after a large number of cycles; (the tests were extended out to a total of 40 cycles each of 24 hours duration). After repetitive high temperature thermal cycling, the film-substrate adhesion was greater than {approx}70 Mpa, the instrumental limit of measurement, and the interface toughness was approximately 0.8 MPa m{sup 1/2}.

  2. Miniaturized high-temperature superconducting multiplexer with cascaded quadruplet structure

    NASA Astrophysics Data System (ADS)

    Xu, Zhang; Jingping, Liu; Shaolin, Yan; Lan, Fang; Bo, Zhang; Xinjie, Zhao

    2015-06-01

    In this paper, compact high temperature superconducting (HTS) multiplexers are presented for satellite communication applications. The first multiplexer consists of an input coupling node and three high-order bandpass filters, which is named triplexer. The node is realized by a loop microstrip line instead of conventional T-junction to eliminate the redundant susceptance due to combination of three filters. There are two eight-pole band-pass filters and one ten-pole band-pass filter with cascaded quadruplet structure for realizing high isolation. Moreover, the triplexer is extended to a multiplexer with six channels so as to verify the expansibility of the suggested approach. The triplexer is fabricated using double-sided YBa2Cu3O7 thin films on a 38 × 25 mm2 LaAlO3 substrate. The experimental results, when compared with those ones from the T-junction multiplexer, show that our multiplexer has lower insertion loss, smaller sizes and higher isolation between any two channels. Also, good agreement has been achieved between simulations and measurements, which illustrate the effectiveness of our methods for the design of high performance HTS multiplexers.

  3. High temperature superconductive microwave technology for space applications

    NASA Technical Reports Server (NTRS)

    Leonard, R. F.; Connolly, D. J.; Bhasin, K. B.; Warner, J. D.; Alterovitz, S. A.

    1991-01-01

    Progress being made on space application technology research on film fabrication, passive microwave circuits, and semiconductor devices for cryogenic circuits is reviewed. Achievements in YBCO and TCBCO films are addressed along with circuit evaluations of microstrip resonators, phase shifters, microstrip filters, dielectric resonator filters, and superconducting antennas.

  4. A Snapshot View of High Temperature Superconductivity 2002

    SciTech Connect

    Schuller, Ivan K.; Bansil, Arun; Basov, Dimitri N.

    2002-04-05

    This report outlines the conclusions of a workshop on High Temperature Superconductivity held April 5-8, 2002 in San Diego. The purpose of this report is to outline and highlight some outstanding and interesting issues in the field of High Temperature Superconductivity. The range of activities and new ideas that arose within the context of High Temperature Superconductors is so vast and extensive that it is impossible to summarize it in a brief document. Thus this report does not pretend to be all-inclusive and cover all areas of activity. It is a restricted snapshot and it only presents a few viewpoints. The complexity and difficulties with high temperature superconductivity is well illustrated by the Buddhist parable of the blind men trying to describe “experimentally” an elephant. These very same facts clearly illustrate that this is an extremely active field, with many unanswered questions, and with a great future potential for discoveries and progress in many (sometimes unpredictable) directions. It is very important to stress that independently of any current or future applications, this is a very important area of basic research.

  5. Spin-bag mechanism of high-temperature superconductivity

    NASA Technical Reports Server (NTRS)

    Schrieffer, J. R.; Wen, X.-G.; Zhang, S.-C.

    1988-01-01

    A new approach to the theory of high-temperature superconductivity is proposed, based on the two-dimensional antiferromagnetic spin correlations observed in these materials over distances large compared to the lattice spacing. The spin ordering produces an electronic pseudogap which is locally suppressed by the addition of a hole. This suppression forms a bag inside which the hole is self-consistently trapped. Two holes are attracted by sharing a common bag. The resulting pairing interaction leads to a superconducting energy gap which is nodeless over the Femri surface.

  6. Fabrication of Large Bulk High Temperature Superconducting Articles

    NASA Technical Reports Server (NTRS)

    Koczor, Ronald (Inventor); Hiser, Robert A. (Inventor)

    2003-01-01

    A method of fabricating large bulk high temperature superconducting articles which comprises the steps of selecting predetermined sizes of crystalline superconducting materials and mixing these specific sizes of particles into a homogeneous mixture which is then poured into a die. The die is placed in a press and pressurized to predetermined pressure for a predetermined time and is heat treated in the furnace at predetermined temperatures for a predetermined time. The article is left in the furnace to soak at predetermined temperatures for a predetermined period of time and is oxygenated by an oxygen source during the soaking period.

  7. The high temperature superconductivity space experiment (HTSSE-II) design

    SciTech Connect

    Kawecki, T.G.; Golba, G.A.; Price, G.E.; Rose, V.S.; Meyers, W.J.

    1996-07-01

    The high temperature superconductivity space experiment (HTSSE) program, initiated by the Naval Research Laboratory (NRL) in 1988, is described. The HTSSE program focuses high temperature superconductor (HTS) technology applications on space systems. The program phases, goals, and objectives are discussed. The devices developed for the HTSSE-II phase of the program and their suppliers are enumerated. Eight space-qualified components were integrated as a cryogenic experimental payload on DOD`s ARGOS spacecraft. The payload was designed and built using a unique NRL/industry partnership and was integrated and space-qualified at NRL.

  8. Vitaly Ginzburg and high temperature superconductivity: Personal reminiscences

    NASA Astrophysics Data System (ADS)

    Mazin, Igor I.

    2008-01-01

    This article is an attempt to give Western readers, as well as young researchers in Russia, a glance at the atmosphere in one of the leading physics institutions in the USSR from 1977-1988, through the eye of a graduate student and later a posdoc in the theory group led by Vitaly Ginzburg, arguably the most enthusiatic proponent of high-temperature superconductivity before the discovery of Bednorz and Muller. This is a very personal narration, wherein the events of my own life and career are inevitably intertwined with scientific events and with my reminiscences of great Russian physicists whom I had the pleasure to meet with while working in the “High-Temperature Superconductivity Section” at the Lebedev Institute within the aforementioned 12 years.

  9. Space applications for high temperature superconductivity - Brief review

    NASA Technical Reports Server (NTRS)

    Krishen, Kumar

    1990-01-01

    An overview is presented of materials and devices based on high-temperature superconductivity (HTS) that could have useful space-oriented applications. Of specific interest are applications of HTS technologies to mm and microwave systems, spaceborne and planet-surface sensors, and to magnetic subsystems for robotic, rescue, and docking maneuvers. HTS technologies can be used in optoelectronics, magnetic-field detectors, antennae, transmission/delay lines, and launch/payload coils.

  10. Optical studies of high-temperature superconducting cuprates.

    PubMed

    Tajima, Setsuko

    2016-09-01

    The optical studies of high-temperature superconducting cuprates (HTSC) are reviewed. From the doping dependence of room temperature spectra, a dramatic change of the electronic state from a Mott (charge transfer) insulator to a Fermi liquid has been revealed. Additionally, the unusual 2D nature of the electronic state has been found. The temperature dependence of the optical spectra provided a rich source of information on the pseudogap, superconducting gap, Josephson plasmon, transverse Josephson plasma mode and precursory superconductivity. Among these issues, Josephson plasmons and transverse Josephson plasma mode were experimentally discovered by optical measurements, and thus are unique to HTSC. The effect of the spin/charge stripe order is also unique to HTSC, reflecting the conducting nature of the stripe order in this system. The pair-breaking due to the stripe order seems stronger in the out-of-plane direction than in the in-plane one. PMID:27472654

  11. Multistable current states in high-temperature superconducting composites

    NASA Astrophysics Data System (ADS)

    Romanovskii, V. R.

    2016-09-01

    Conditions for current instabilities that arise in high-temperature superconducting composites with essentially nonlinear dependences of the critical current densities and resistivity on the temperature and magnetic induction have been studied. The analysis has been conducted in terms of zero-dimensional models, which has made it possible to formulate general physical mechanisms behind the formation of currents states in superconducting composites according to the external magnetic field induction, cooling conditions, and the properties of the superconductor and cladding. The possible existence of current and temperature stable steps, as well as stable steps of the electric field strength, in the absence of the superconducting-normal transition, has been demonstrated. Reasons for instabilities under multistable current states have been discussed.

  12. Optical studies of high-temperature superconducting cuprates

    NASA Astrophysics Data System (ADS)

    Tajima, Setsuko

    2016-09-01

    The optical studies of high-temperature superconducting cuprates (HTSC) are reviewed. From the doping dependence of room temperature spectra, a dramatic change of the electronic state from a Mott (charge transfer) insulator to a Fermi liquid has been revealed. Additionally, the unusual 2D nature of the electronic state has been found. The temperature dependence of the optical spectra provided a rich source of information on the pseudogap, superconducting gap, Josephson plasmon, transverse Josephson plasma mode and precursory superconductivity. Among these issues, Josephson plasmons and transverse Josephson plasma mode were experimentally discovered by optical measurements, and thus are unique to HTSC. The effect of the spin/charge stripe order is also unique to HTSC, reflecting the conducting nature of the stripe order in this system. The pair-breaking due to the stripe order seems stronger in the out-of-plane direction than in the in-plane one.

  13. Insights from the study of high-temperature interface superconductivity.

    PubMed

    Pereiro, J; Bollinger, A T; Logvenov, G; Gozar, A; Panagopoulos, C; Bozović, I

    2012-10-28

    A brief overview is given of the studies of high-temperature interface superconductivity based on atomic-layer-by-layer molecular beam epitaxy (ALL-MBE). A number of difficult materials science and physics questions have been tackled, frequently at the expense of some technical tour de force, and sometimes even by introducing new techniques. ALL-MBE is especially suitable to address questions related to surface and interface physics. Using this technique, it has been demonstrated that high-temperature superconductivity can occur in a single copper oxide layer-the thinnest superconductor known. It has been shown that interface superconductivity in cuprates is a genuine electronic effect-it arises from charge transfer (electron depletion and accumulation) across the interface driven by the difference in chemical potentials rather than from cation diffusion and mixing. We have also understood the nature of the superconductor-insulator phase transition as a function of doping. However, a few important questions, such as the mechanism of interfacial enhancement of the critical temperature, are still outstanding. PMID:22987034

  14. Spontaneous quenches of a high temperature superconducting pancake coil

    SciTech Connect

    Lue, J.W.; Lubell, M.S.; Aized, D.; Campbell, J.M.; Schwall, R.E.

    1995-09-01

    A double-pancake coil made of Bi-2223/Ag high temperature superconducting (HTS) tape was constructed with an embedded heater and graded conductors to study the stability and quench propagation in HTS coils. The experiments were performed with liquid nitrogen and gaseous helium cooling in temperatures ranging from 5 to 77 K. The coil was very stable, and no ``normal`` zone was sustained or propagated with local pulsed heating. However, spontaneous quenches of the cod were experienced. This was found to be the result of having the coil current higher than that of the lower I{sub c} sections of the coil for a long time. This quench process took minutes to develop--much longer than would be expected in a low temperature superconducting coil. The quench behaved more like a spreading and continuous heating of an increasingly larger partially resistive section of the coil than like a sequential ``normal`` front propagation.

  15. Conductor requirements for high-temperature superconducting utility power transformers

    SciTech Connect

    Pleva, E. F.; Mehrotra, V.; Schwenterly, S W

    2010-01-01

    High-temperature superconducting (HTS) coated conductors in utility power transformers must satisfy a set of operating requirements that are driven by two major considerations-HTS transformers must be economically competitive with conventional units, and the conductor must be robust enough to be used in a commercial manufacturing environment. The transformer design and manufacturing process will be described in order to highlight the various requirements that it imposes on the HTS conductor. Spreadsheet estimates of HTS transformer costs allow estimates of the conductor cost required for an HTS transformer to be competitive with a similarly performing conventional unit.

  16. Can Laser Physics Notions Explain High Temperature Superconductivity?

    NASA Astrophysics Data System (ADS)

    James, John C.

    2003-03-01

    Thinking of large excitations in superconductivity (SC) in terms of population inversions would seem to allow for phonon laser amplification while simultaneously refrigerating the environment (an obvious impossibility). Fortunately, fluctuation of the SC ground state, when the population is inverted (ns < n_e), prevents second law violation by disallowing directional control of the spontaneous coherent phonon bursts. The bursts are therefore allowed to prevent the complete collapse of the SC state by driving the excited electrons back down into the SC state. Stabilization of the SC state by spontaneous, real coherent phonon deexcitation of the population inversion circumvents the instability problems in strong coupling theories bound together through virtual exchange of phonons. EXTERNAL (REAL PHONON) STABILIZATION OF STRONG COUPLED SC EXPLAINS HIGH TEMPERATURE SC ITSELF. Allowing the use of laser physics notions in high temperature SC theory dramatically simplifies understanding of an enormous number of experiments.

  17. Nuclear Magnetic Resonance Study of High Temperature Superconductivity

    NASA Astrophysics Data System (ADS)

    Mounce, Andrew M.

    The high temperature superconductors HgBa2CuO 4+delta (Hg1201) and Bi2SrCa2Cu2O 8+delta (Bi2212) have been treated with 17O for both nuclear magnetic resonance (NMR) sensitivity and various electronic properties. Subsequently, NMR experiments were performed on Hg1201 and Bi2212 to reveal the nature of the pseudogap, in the normal state, and vortex phases, in the superconducting state. NMR has been performed on 17O in an underdoped Hg1201 crystal with a superconducting transition transition temperature of 74 K to look for circulating orbital currents proposed theoretically and inferred from neutron scattering. The measurements reveal narrow spectra which preclude static local fields in the pseudogap phase at the apical site, suggesting that the moments observed with neutrons are fluctuating or the orbital current ordering is not the correct model for the neutron scattering observation. The fine detail of the NMR frequency shifts at the apical oxygen site are consistent with a dipolar field from the Cu+2 site and diamagnetism below the superconducting transition. It has been predicted that superconducting vortices should be electrically charged and that this effect is particularly enhanced for high temperature superconductors. Here it is shown that the Abrikosov vortex lattice, characteristic of the mixed state of superconductors, will become unstable at sufficiently high magnetic field if there is charge trapped on the vortex core for highly anisotropic superconductors. NMR measurements of the magnetic fields generated by vortices in Bi2212 single crystals provide evidence for an electro-statically driven vortex lattice reconstruction with the magnitude of charge on each vortex pancake of 2x10-3e, depending on doping, in line with theoretical estimates. Competition with magnetism is at the heart of high temperature superconductivity, most intensely felt near a vortex core. To investigate vortex magnetism spatially resolved NMR has been used, finding a strongly non

  18. Developing a high-temperature superconducting bulk magnet for the maglev train of the future

    NASA Astrophysics Data System (ADS)

    Fujimoto, Hiroyuki

    1998-10-01

    The major applications of high-temperature superconductors have mostly been confined to products in the form of wires and thin films. However, recent developments show that rare-earth REBa2Cu3O7-x and light rare-earth LREBa2Cu3O7-3 superconductors prepared by melt processes have a high critical-current density at 77 K and high magnetic fields. These superconductors will promote the application of bulk high-temperature superconductors in high magnetic fields; the superconducting bulk magnet for the Maglev train is one possible application.

  19. High temperature superconducting composite conductor and method for manufacturing the same

    DOEpatents

    Holesinger, Terry G.; Bingert, John F.

    2002-01-01

    A high temperature superconducting composite conductor is provided including a high temperature superconducting material surrounded by a noble metal layer, the high temperature superconducting composite conductor characterized as having a fill factor of greater than about 40. Additionally, the conductor can be further characterized as containing multiple cores of high temperature superconducting material surrounded by a noble metal layer, said multiple cores characterized as having substantially uniform geometry in the cross-sectional dimensions. Processes of forming such a high temperature superconducting composite conductor are also provided.

  20. Double-sided Tl{sub 2}Ba{sub 2}Ca{sub 2}Cu{sub 3}O{sub 10} thin films based high temperature superconducting filter operating above 100 K

    SciTech Connect

    Xie, Wei; Wang, Pei; He, Ming Qiao, Ren; Du, Jia-Nan; Gao, Xiao-Xin; Liu, Xin; Zhang, Xu; Ji, Lu; Chen, Hai-Hua; Zhao, Xin-Jie

    2014-09-01

    A high temperature superconducting (HTS) filter on double-sided Tl{sub 2}Ba{sub 2}Ca{sub 2}Cu{sub 3}O{sub 10} (Tl-2223) thin films is designed in this letter. High-quality double-sided Tl-2223 thin films are prepared on 10 × 10 × 0.5 mm{sup 3} LaAlO{sub 3} (001) substrate. The critical temperatures T{sub c} of the films are 120 ± 1 K and the critical current densities J{sub c} are 3–4 MA/cm{sup 2} at 77 K for both sides. X-ray diffraction θ-2θ scans and rotational ϕ-scans prove that the films are strongly textured with the c axis perpendicular to the substrate surface. A 3-pole band-pass filter is then fabricated on the Tl-2223 thin films with 4% relative bandwidth and a center frequency of 4.0 GHz. At 77 K, 100 K, and 102 K, the insertion loss in the passband is 0.088 dB, 0.21 dB, and 0.27 dB, respectively. These performances show that the proposed HTS filter is satisfying even when the operating temperature is above 100 K, which makes it possible to work in outer space without cryogenic systems.

  1. Materials science challenges for high-temperature superconducting wire.

    PubMed

    Foltyn, S R; Civale, L; Macmanus-Driscoll, J L; Jia, Q X; Maiorov, B; Wang, H; Maley, M

    2007-09-01

    Twenty years ago in a series of amazing discoveries it was found that a large family of ceramic cuprate materials exhibited superconductivity at temperatures above, and in some cases well above, that of liquid nitrogen. Imaginations were energized by the thought of applications for zero-resistance conductors cooled with an inexpensive and readily available cryogen. Early optimism, however, was soon tempered by the hard realities of these new materials: brittle ceramics are not easily formed into long flexible conductors; high current levels require near-perfect crystallinity; and--the downside of high transition temperature--performance drops rapidly in a magnetic field. Despite these formidable obstacles, thousands of kilometres of high-temperature superconducting wire have now been manufactured for demonstrations of transmission cables, motors and other electrical power components. The question is whether the advantages of superconducting wire, such as efficiency and compactness, can outweigh the disadvantage: cost. The remaining task for materials scientists is to return to the fundamentals and squeeze as much performance as possible from these wonderful and difficult materials.

  2. Shock-induced synthesis of high temperature superconducting materials

    DOEpatents

    Ginley, D.S.; Graham, R.A.; Morosin, B.; Venturini, E.L.

    1987-06-18

    It has now been determined that the unique features of the high pressure shock method, especially the shock-induced chemical synthesis technique, are fully applicable to high temperature superconducting materials. Extraordinarily high yields are achievable in accordance with this invention, e.g., generally in the range from about 20% to about 99%, often in the range from about 50% to about 90%, lower and higher yields, of course, also being possible. The method of this invention involves the application of a controlled high pressure shock compression pulse which can be produced in any conventional manner, e.g., by detonation of a high explosive material, the impact of a high speed projectile or the effect of intense pulsed radiation sources such as lasers or electron beams. Examples and a discussion are presented.

  3. Plaquette valence bond theory of high-temperature superconductivity

    NASA Astrophysics Data System (ADS)

    Harland, Malte; Katsnelson, Mikhail I.; Lichtenstein, Alexander I.

    2016-09-01

    We present a strong-coupling approach to the theory of high-temperature superconductivity based on the observation of a quantum critical point in the plaquette within the t ,t' Hubbard model. The crossing of ground-state energies in the N =2 -4 sectors occurs for parameters close to the optimal doping. The theory predicts the maximum of the dx2-y2-wave order parameter at the border between localized and itinerant electron behaviors and gives a natural explanation for the pseudogap formation via the soft-fermion mode related to local singlet states of the plaquette in the environment. Our approach follows the general line of resonating valence-bond theory stressing a crucial role of singlets in the physics of high-Tc superconductors but focuses on the formation of local singlets, similar to phenomena observed in frustrated one-dimensional quantum spin models.

  4. The fabrication and characterization of high temperature superconducting magnetic shields

    SciTech Connect

    Purpura, J.W.; Clem, T.R.

    1989-03-01

    Tubes fabricated of polycrystalline YBa/sub 2/Cu/sub 3/O/sub 7-x/ are characterized and details of the fabrication procedure are discussed. The microstructure of the tubes determined by scanning electron microscopy and x-ray diffractometry is described. Resistive measurements of T/sub c/ and /Delta/T/sub c/ have been made. The tubes have also been characterized by means of SQUID magnetometry. The temperature dependence of magnetic fields trapped axially in the tubes has been measured and estimates of penetration depth are given. Moreover, measurements of transverse shielding effectiveness of the tubes have been made and are compared with theoretical predictions. Studies on flux penetration into the tubes are described. Findings from the microstructure studies are correlated with the observed superconductivity properties. The results on the high temperature materials are compared to results obtained previously on tubes made from conventional superconductors.

  5. High Temperature Superconducting Reciprocating Magnetic Separator Final Report

    SciTech Connect

    James F. Maguire

    2008-06-05

    In 2001, under DOE's Superconductivity Partnership Initiative (SPI), E. I. du Pont de Nemours & Co. (Dupont) was awarded a cost-share contract to build a fully functional full-scale model high temperature superconducting reciprocating magnet unit specifically designed for the koalin clay industry. After competitive bidding, American Superconductor (AMSC) was selected to provide the coil for the magnet. Dupont performed the statement of work until September 2004, when it stopped work, with the concurrence of DOE, due to lack of federal funds. DOE had paid all invoices to that point, and Dupont had provided all cost share. At this same time, Dupont determined that this program did not fit with its corporate strategies and notified DOE that it was not interesting in resuming the program when funding became available. AMSC expressed interest in assuming performance of the Agreement to Dupont and DOE, and in March 2005, this project was transferred to AMSC by DOE amendment to the original contract and Novation Agreement between AMSC and Dupont. Design drawings and some hardware components and subassemblies were transferred to AMSC. However, no funding was obligated by DOE and AMSC never performed work on the project. This report contains a summary of the work performed by Dupont up to the September 04 timeframe.

  6. Progress in high-temperature superconducting transistors and other devices II; Proceedings of the Meeting, San Jose, CA, Sept. 12, 13, 1991

    NASA Astrophysics Data System (ADS)

    Singh, Rajendra; Nisenoff, Martin; Pavuna, Davor

    The present conference on high-temperature superconducting transistors and related devices encompasses applications of superconducting thin films, the deposition, patterning, and characterization of thin films, superconducting digital technology, two- and three-terminal devices, and superconducting devices and programs. Specific issues addressed include the application of HTSC films in hybrid optoelectronic devices, the growth and control of epitaxial Ba2YCu3O(7-delta) thin films, atomic layer epitaxy of YBaCuO for optoelectronic applications, single-flux quantum logic, and all-YBaCu3O(7-x) edge-geometry weak links. Also addressed are inverted cylindrical magnetron sputtering for HTSC thin film growth, HTSC films for novel optronic devices, large-area ion-beam-sputtered YBA2Cu3O(7-delta) films for novel device structures, and the High-temperature Superconductivity Space Experiment.

  7. Rotor instrumentation study for high-temperature superconducting generators

    SciTech Connect

    Schwenterly, S.W.; Wilson, C.T.

    1996-06-01

    In FY 9195, ORNL carried out work on rotor instrumentation systems in support of the General Electric (GE) Superconductivity Partnership Initiative (SPI) on Superconducting Generator Development. The objective was to develop a system for tramsitting data from sensors in the spinning rotor to a stationary data acquisition system. Previous work at ORNL had investigated an optical method of cryogenic temperature measurement using laser-induced fluorescence in certain phosphors. Later follow-up discussions with experts in the ORNL Engineering Technology Division indicated that this method could also be extended to measure strain and magnetic field. Another optical alternative using standard fiber optic transmission modules was also investigated. The equipment is very inexpensive, but needs to be adapted for operation in a high-g-force rotating environment. An optical analog of a commutator or slip ring also needs to be developed to couple the light signals from the rotor to the stationary frame. Sealed mercury-film rotary contacts are manufactured by Meridian Laboratory. Unlike conventional slipring assemblies, these offer low noise and long lifetime, with low costs per channel. Standard units may need some upgrading for 3600-rpm or high-voltage operation. A commercial electronic telemetry system offered by Wireless Data Corporation (WDC) was identified as a viable candidate, and information on this system was presented to GE. GE has since ordered two of these systems from WDC for temperature measurements in their rotating test cryostat.

  8. Thermal response of large area high temperature superconducting YBaCuO infrared bolometer

    NASA Technical Reports Server (NTRS)

    Khalil, Ali E.

    1990-01-01

    Thermal analysis of large area high temperature superconducting infrared detector operating in the equilibrium mode (bolometer) was performed. An expression for the temperature coefficient beta=1/R(dR/dT) in terms of the thermal conductance and the thermal time constant of the detector were derived. A superconducting transition edge bolometer is a thermistor consisting of a thin film superconducting YBaCuO evaporated into a suitable thermally isolated substrate. The operating temperature of the bolometer is maintained close to the midpoint of the superconducting transition region where the resistance R has a maximum dynamic range. A detector with a strip configuration was analyzed and an expression for the temperature rise (delta T) above the ambient due to a uniform illumination with a source of power density P(sub i) was calculated. An expression for the thermal responsivity of the detector was derived using the thermal diffusion analysis with appropriate boundary conditions. It was found that the thermal responsibility depends upon the spatial modulation frequency and the angular frequency of the incoming radiation. The problem of the thermal cross talk between different detector elements was addressed. In the case of monolithic HTS detector array with a row of square elements of dimensions 2a and CCD or CID readout electronics the thermal spread function was derived for different spacing between elements. This analysis can be critical for future design and applications of large area focal plane arrays as broad band optical detectors made of granular thin films HTS YBaCuO.

  9. A 3M high temperature dielectric film

    NASA Technical Reports Server (NTRS)

    Hampl, Edward, Jr.

    1994-01-01

    The performance characteristics of a dielectric film are summarized. Additionally, the film's environmental and chemical properties are listed: low shrinkage to 300 C; moisture insensitive; low outgassing under vacuum; excellent surface qualities--easy metallization of film; flame retardant; and low smoke generation. A series of graphs that display the performance characteristics of the film are also presented.

  10. High temperature superconductivity technology for advanced space power systems

    NASA Technical Reports Server (NTRS)

    Faymon, Karl A.; Myers, Ira T.; Connolly, Denis J.

    1990-01-01

    In 1987, the Lewis Research center of the NASA and the Argonne National Laboratory of the Department of Energy joined in a cooperative program to identify and assess high payoff space and aeronautical applications of high temperature superconductivity (HTSC). The initial emphasis of this effort was limited, and those space power related applications which were considered included microwave power transmission and magnetic energy storage. The results of these initial studies were encouraging and indicated the need of further studies. A continuing collaborative program with Argonne National Laboratory has been formulated and the Lewis Research Center is presently structuring a program to further evaluate HTSC, identify applications and define the requisite technology development programs for space power systems. This paper discusses some preliminary results of the previous evaluations in the area of space power applications of HTSC which were carried out under the joint NASA-DOE program, the future NASA-Lewis proposed program, its thrusts, and its intended outputs and give general insights on the anticipated impact of HTSC for space power applications of the future.

  11. High temperature superconducting axial field magnetic coupler: realization and test

    NASA Astrophysics Data System (ADS)

    Belguerras, L.; Mezani, S.; Lubin, T.; Lévêque, J.; Rezzoug, A.

    2015-09-01

    Contactless torque transmission through a large airgap is required in some industrial applications in which hermetic isolation is necessary. This torque transmission usually uses magnetic couplers, whose dimension strongly depends on the airgap flux density. The use of high temperature superconducting (HTS) coils to create a strong magnetic field may constitute a solution to reduce the size of the coupler. It is also possible to use this coupler to replace a torque tube in transmitting the torque produced by a HTS motor to its load. This paper presents the detailed construction and tests of an axial field HTS magnetic coupler. Pancake coils have been manufactured from BSCCO tape and used in one rotor of the coupler. The second rotor is mainly composed of NdFeB permanent magnets. Several tests have been carried out showing that the constructed coupler is working properly. A 3D finite element (FE) model of the studied coupler has been developed. Airgap magnetic field and torque measurements have been carried out and compared to the FE results. It has been shown that the measured and the computed quantities are in satisfactory agreement.

  12. Transient analysis and burnout of high temperature superconducting current leads

    NASA Astrophysics Data System (ADS)

    Seol, S. Y.; Hull, J. R.

    The transient behaviour of high-temperature superconductor (HTS) current leads operated between liquid helium and liquid nitrogen temperatures is analysed for burnout conditions upon transition of the HTS into the normal state. Leads composed of HTS only and of HTS sheathed by pure silver or silver alloy are investigated numerically for temperature-dependent properties and analytically for temperature-independent properties. For lower values of shape factor (current density times length), the lead can be operated indefinitely without burnout. At higher values of shape factor, the lead reaches burnout in a finite time. With high current densities, the leads heat adiabatically. For a fixed shape factor, low current densities are desired to achieve long burnout times. To achieve a low helium boil-off rate in the superconducting state without danger of burnout, there is a preferred temperature dependence for thermal conductivity, and silver alloy sheaths are preferred to pure silver sheaths. However, for a given current density, pure silver sheaths take longer to burn out.

  13. Apparatus for continuous manufacture of high temperature superconducting wires from molten superconducting oxides

    SciTech Connect

    Hed, A.Z.

    1991-09-10

    This patent describes an apparatus for making a composite high-temperature superconducting wire, comprising a refractory core having a melting point above a melt temperature of a superconducting oxide ceramic having a critical temperature T{sub c} above 23{degrees} K and a layer of the superconducting oxide ceramic on the core. It comprises means forming a controlled-atmosphere chamber; a vessel received in the chamber and formed with an opening at a bottom thereof, the vessel receiving an annular mass of the superconducting oxide ceramic in solid form surrounding a passage traversing the mass and extending upwardly from the opening; means for forming a melt of the superconductive oxide ceramic in a small pool in the mass above the passage and at a temperature slightly above a melting point of the superconducting oxide ceramic; means for drawing the refractory core through the opening, the passage and the melt in succession and depositing the melt on the core, the pool being in contact only with the mass, the core and the atmosphere; means in the chamber above the pool for cooling the melt deposited on the core by radiation and convection.

  14. Thermal response of large area high temperature superconducting YBaCuO infrared bolometers

    NASA Technical Reports Server (NTRS)

    Khalil, Ali E.

    1991-01-01

    Thermal analysis of large area high temperature superconducting infrared detector operating in the equilibrium mode (bolometer) was performed. An expression for the temperature coefficient beta = 1/R(dR/dT) in terms of the thermal conductance and the thermal time constant of the detector were derived. A superconducting transition edge bolometer is a thermistor consisting of a thin film superconducting YBaCuO evaporated into a suitable thermally isolated substrate. The operating temperature of the bolometer is maintained close to the midpoint of the superconducting transition region where the resistance R has a maximum dynamic range. A detector with a strip configuration was analyzed and an expression for the temperature rise (delta T) above the ambient due to a uniform illumination with a source of power density was calculated. An expression for the thermal responsibility depends upon the spatial modulation frequency and the angular frequency of the incoming radiation. The problem of the thermal cross talk between different detector elements was addressed. In the case of monolithic HTS detector array with a row of square elements of dimensions 2a and CCD or CID readout electronics the thermal spread function was derived for different spacing between elements.

  15. Damping and support in high-temperature superconducting levitation systems

    DOEpatents

    Hull, John R.; McIver, Carl R.; Mittleider, John A.

    2009-12-15

    Methods and apparatuses to provide improved auxiliary damping for superconducting bearings in superconducting levitation systems are disclosed. In a superconducting bearing, a cryostat housing the superconductors is connected to a ground state with a combination of a damping strip of material, a set of linkage arms to provide vertical support, and spring washers to provide stiffness. Alternately, the superconducting bearing may be supported by a cryostat connected to a ground state by posts constructed from a mesh of fibers, with the damping and stiffness controlled by the fiber composition, size, and mesh geometry.

  16. Application of a high-temperature superconducting detector to terahertz imaging

    NASA Astrophysics Data System (ADS)

    Hellicar, Andrew D.; Du, Jia; Hanham, Stephen M.; Li, Li

    2009-05-01

    The performance of a high temperature superconducting junction detector is evaluated. The detector has been built to explore applications of terahertz imaging. The detector device is a high-temperature superconductor (HTS) Josephson junction, which is integrated with a thin-film ring-slot antenna. The ring-slot antenna is patterned on a magnesium oxide (MgO) substrate which is compatible with the detector's YBCO superconducting material lattice. A hyper-hemispherical lens made from high resistivity float zone silicon (HRFZ-Si) is mounted on the rear side of the substrate. The lens couples energy from an imaging system onto the antenna which couples the energy into the device. An existing terahertz imaging system is used in conjunction with the detector to allow for the exploration of relevant applications. The imaging system is based on a conventional quasi-optical design with a backward-wave oscillator as the source and raster scans samples for image acquisition. The imaging capability of the system has been assessed by trialing a range of applications in both transmission and reflection modes. Applications explored include imaging concealed weapons in packaging, non-destructive testing of materials, and imaging devices through plastic structures. The results generated by the imaging system demonstrate its capability for these applications.

  17. The spin bag mechanism of high temperature superconductivity

    NASA Technical Reports Server (NTRS)

    Schrieffer, J. R.; Wen, X.-G.; Zhang, S.-C.

    1989-01-01

    In oxide superconductors the local suppression of antiferromagnetic correlations in the vicinity of a hole lowers the energy of the system. This quasi two-dimensional bag of weakened spin order follows the hole in its motion. In addition, holes prefer to share a bag, leading to a strong pairing attraction and a high Tc superconductivity. There are many experimental consequences of this mechanism for both the superconducting and normal phases.

  18. Engineering nanocolumnar defect configurations for optimized vortex pinning in high temperature superconducting nanocomposite wires

    PubMed Central

    Wee, Sung Hun; Zuev, Yuri L.; Cantoni, Claudia; Goyal, Amit

    2013-01-01

    We report microstructural design via control of BaZrO3 (BZO) defect density in high temperature superconducting (HTS) wires based on epitaxial YBa2Cu3O7-δ (YBCO) films to achieve the highest critical current density, Jc, at different fields, H. We find the occurrence of Jc(H) cross-over between the films with 1–4 vol% BZO, indicating that optimal BZO doping is strongly field-dependent. The matching fields, Bφ, estimated by the number density of BZO nanocolumns are matched to the field ranges for which 1–4 vol% BZO-doped films exhibit the highest Jc(H). With incorporation of BZO defects with the controlled density, we fabricate 4-μm-thick single layer, YBCO + BZO nanocomposite film having the critical current (Ic) of ~1000 A cm−1 at 77 K, self-field and the record minimum Ic, Ic(min), of 455 A cm−1 at 65 K and 3 T for all field angles. This Ic(min) is the largest value ever reported from HTS films fabricated on metallic templates. PMID:23939231

  19. Engineering nanocolumnar defect configurations for optimized vortex pinning in high temperature superconducting nanocomposite wires

    NASA Astrophysics Data System (ADS)

    Wee, Sung Hun; Zuev, Yuri L.; Cantoni, Claudia; Goyal, Amit

    2013-08-01

    We report microstructural design via control of BaZrO3 (BZO) defect density in high temperature superconducting (HTS) wires based on epitaxial YBa2Cu3O7-δ (YBCO) films to achieve the highest critical current density, Jc, at different fields, H. We find the occurrence of Jc(H) cross-over between the films with 1-4 vol% BZO, indicating that optimal BZO doping is strongly field-dependent. The matching fields, Bφ, estimated by the number density of BZO nanocolumns are matched to the field ranges for which 1-4 vol% BZO-doped films exhibit the highest Jc(H). With incorporation of BZO defects with the controlled density, we fabricate 4-μm-thick single layer, YBCO + BZO nanocomposite film having the critical current (Ic) of ~1000 A cm-1 at 77 K, self-field and the record minimum Ic, Ic(min), of 455 A cm-1 at 65 K and 3 T for all field angles. This Ic(min) is the largest value ever reported from HTS films fabricated on metallic templates.

  20. Electronic properties of rocksalt copper monoxide: a proxy structure for high temperature superconductivity

    NASA Astrophysics Data System (ADS)

    Grant, Paul M.

    2008-10-01

    Cubic rocksalt copper monoxide, in contrast to its lighter transition metal neighbours, does not exist in nature nor has it yet been successfully synthesized. Nonetheless, its numerical study as a structurally much simpler proxy for the layered cuprate perovskites may prove useful in probing the source of high temperature superconductivity in the latter family of compounds. Here we report such a study employing density functional theory (DFT) abetted by the local density approximation including cation on-site Hubbard interactions (LDA+U). Rather surprisingly, we find that unlike oxides of the light transition metals, cubic CuO remains metallic for all physically reasonable values of U and does not result in a Mott- Hubbard induced charge transfer insulator as might be expected, and, in fact, displays a Fermi surface with clearly nesting tendencies. Preliminary calculations of the net dimensionless electron-phonon coupling constant, λ, yield values in the range 0.6 - 0.7 similar to those found for the superconducting fullerenes and magnesium diboride. On the other hand, we do find as we gradually introduce a tetragonal distortion away from pure cubic symmetry that a charge- transfer insulator emerges for values of U thicksim 5 eV and c/a thicksim 1.3 in agreement with recent experimental data on forced-epitaxial growth of 2-4 ML thick films of tetragonal rocksalt CuO. We preliminarily conclude from these computational studies that high temperature superconductivity in the copper oxide compounds is at least initially mediated by Jahn-Teller driven electron-phonon coupling as originally suggested by Bednorz and Mueller.

  1. Compact design of high-temperature superconducting duplexer and triplexer for satellite communications

    NASA Astrophysics Data System (ADS)

    Zhang, Xu; He, Ming; Ji, Lu; Zhao, Xinjie; Fang, Lan; Yan, Shaolin

    2012-10-01

    This paper presents a compact C-band high-temperature superconducting (HTS) input module duplexer, which can be scaled to a triplexer. The duplexer includes a common node as the input port, which is an extensible and effective structure for integrating a HTS multiplexer on a single superconducting film. The input node is realized by an open-loop microstrip line, which resonates at the frequency in the guard band between the two channels. In addition two four-pole bandpass filters consisting of rectangular spiral line resonators are used as output channels of the device. The duplexer is designed at 3995 MHz with a bandwidth of 226 MHz. The frequency ranges of the two channels are 3882-3942 MHz and 4048-4108 MHz, respectively. It is fabricated using double-sided Y Ba2Cu3O7 (YBCO) thin films on a piece of 30× 10 mm 2 MgO substrate. The experimental results show that the insertion loss is less than 0.1 dB for both channel filters and the isolation between the two channels is higher than 40 dB. Good agreement has been achieved between simulations and measurements to illustrate the effectiveness of the proposed approach. Moreover, the triplexer is also designed and measured and the scalability is verified by simulation and experiments.

  2. Preisach-type modeling of high-temperature superconducting hysteresis

    NASA Astrophysics Data System (ADS)

    ElBidweihy, Hatem

    2016-05-01

    Even though Isaak Mayergoyz described it as: "much more accurate for the description of superconducting hysteresis than for the description of hysteresis of magnetic materials", Preisach modeling of superconducting hysteresis is not a popular investigative tool. This might be due to the complexity of identifying the Preisach distribution function or due to lack of convincing physical reasoning behind pure phenomenological versions. In this paper, a two-component Preisach-type model is presented which is computationally-efficient and physically-sound. The change in the slope of the minor hysteresis loops is incorporated in the model and is attributed to reversible fluxoid motion. The model presented is clearly capable of simulating various shapes of superconducting hysteresis loops and could be easily coupled with finite element method (FEM) numerical software.

  3. Hidden Fermionic Excitation Boosting High-Temperature Superconductivity in Cuprates.

    PubMed

    Sakai, Shiro; Civelli, Marcello; Imada, Masatoshi

    2016-02-01

    The dynamics of a microscopic cuprate model, namely, the two-dimensional Hubbard model, is studied with a cluster extension of the dynamical mean-field theory. We find a nontrivial structure of the frequency-dependent self-energies, which describes an unprecedented interplay between the pseudogap and superconductivity. We show that these properties are well described by quasiparticles hybridizing with (hidden) fermionic excitations, emergent from the strong electronic correlations. The hidden fermion enhances superconductivity via a mechanism distinct from a conventional boson-mediated pairing, and originates the normal-state pseudogap. Though the hidden fermion is elusive in experiments, it can solve many experimental puzzles.

  4. High-temperature superconductivity in compressed solid silane.

    PubMed

    Zhang, Huadi; Jin, Xilian; Lv, Yunzhou; Zhuang, Quan; Liu, Yunxian; Lv, Qianqian; Bao, Kuo; Li, Da; Liu, Bingbing; Cui, Tian

    2015-01-01

    Crystal structures of silane have been extensively investigated using ab initio evolutionary simulation methods at high pressures. Two metallic structures with P2₁/c and C2/m symmetries are found stable above 383 GPa. The superconductivities of metallic phases are fully explored under BCS theory, including the reported C2/c one. Perturbative linear-response calculations for C2/m silane at 610 GPa reveal a high superconducting critical temperature that beyond the order of 10(2) K.

  5. Hidden Fermionic Excitation Boosting High-Temperature Superconductivity in Cuprates.

    PubMed

    Sakai, Shiro; Civelli, Marcello; Imada, Masatoshi

    2016-02-01

    The dynamics of a microscopic cuprate model, namely, the two-dimensional Hubbard model, is studied with a cluster extension of the dynamical mean-field theory. We find a nontrivial structure of the frequency-dependent self-energies, which describes an unprecedented interplay between the pseudogap and superconductivity. We show that these properties are well described by quasiparticles hybridizing with (hidden) fermionic excitations, emergent from the strong electronic correlations. The hidden fermion enhances superconductivity via a mechanism distinct from a conventional boson-mediated pairing, and originates the normal-state pseudogap. Though the hidden fermion is elusive in experiments, it can solve many experimental puzzles. PMID:26894730

  6. Engineering Nanocolumnar Defect Configurations for Optimized Vortex Pinning in High Temperature Superconducting Nanocomposite Wires

    SciTech Connect

    Wee, Sung Hun; Zuev, Yuri L; Cantoni, Claudia; Goyal, Amit; Ahuja, Raj; Abiade, J.

    2013-01-01

    High temperature superconducting (HTS), coated conductor wires based on nanocomposite films containing self-assembled, insulating BaZrO3 (BZO) nanocolumnar defects have previously been reported to exhibit enhanced vortex pinning. Here, we report on microstructural design via control of BZO nanocolumns density in YBa2Cu3O7- (YBCO)+BZO nancomposite films to achieve the highest critical current density, Jc(H, ,T). X-ray diffraction and microstructural examination shows increasing number density of epitaxial BZO nanocolumns in the highly cube-textured YBCO matrix with increasing nominal BZO additions. Transport property measurement reveals that an increase in BZO content upto 4 vol% is required to sustain the highest pinning and Jc performance as the magnetic field increases. By growing thicker, single-layer nanocomposite films (~4 m) with controlled density of BZO columnar defects, the critical current (Ic) of ~1000 A/cm at 77 K, self-field and the minimum Ic of 455 A/cm at 65 K and 3 T for all magnetic field orientations were obtained. This is the highest Ic reported to date for films on metallic templates which are the basis for the 2nd generation, coated conductor-based HTS wires.

  7. Superconducting properties of copper oxide high-temperature superconductors

    PubMed Central

    Chen, Guanhua; Langlois, Jean-Marc; Guo, Yuejin; Goddard, William A.

    1989-01-01

    The equations for the magnon pairing theory of high-temperature copper-oxide-based superconductors are solved and used to calculate several properties, leading to results for specific heat and critical magnetic fields consistent with experimental results. In addition, the theory suggests an explanation of why there are two sets of transition temperatures (Tc ≈ 90 K and Tc ≈ 55 K) for the Y1Ba2Cu3O6+x class of superconductors. It also provides an explanation of why La2-xSrxCuO4 is a superconductor for only a small range of x (and suggests an experiment to independently test the theory). These results provide support for the magnon pairing theory of high-temperature superconductors. On the basis of the theory, some suggestions are made for improving these materials. PMID:16594038

  8. A novel excitonic mechanism for high temperature superconductivity

    SciTech Connect

    Tesanovic, Z.; Bishop, A.R.; Martin, R.L.

    1988-01-01

    We propose a novel mechanism for superconductivity, based on intra and interband Cu/longleftrightarrow/O charge transfer excitations in oxide superconductors. The dynamic polarizability of the environment surrounding CuO/sup 2/ planes plays an important role in enhancing T/sub c/. The ''sandwich'' structure in which CuO/sub 2/ planes are separated by a highly polarizable medium is ideally suited for this mechanism. Our proposal is consistent with a variety of available data, and suggests several new experimental directions. 9 refs., 2 figs.

  9. Narrowband high temperature superconducting receiver for low frequency radio waves

    DOEpatents

    Reagor, David W.

    2001-01-01

    An underground communicating device has a low-noise SQUID using high temperature superconductor components connected to detect a modulated external magnetic flux for outputting a voltage signal spectrum that is related to the varying magnetic flux. A narrow bandwidth filter may be used to select a portion of the voltage signal spectrum that is relatively free of power line noise to output a relatively low noise output signal when operating in a portion of the electromagnetic spectra where such power line noise exists. A demodulator outputs a communication signal, which may be an FM signal, indicative of a modulation on the modulated external magnetic flux.

  10. Recent Developments in High-Temperature Shape Memory Thin Films

    NASA Astrophysics Data System (ADS)

    Motemani, Y.; Buenconsejo, P. J. S.; Ludwig, A.

    2015-11-01

    High-temperature shape memory alloy (HTSMA) thin films are candidates for development of microactuators with operating temperatures exceeding 100 °C. This article reviews recent advances and developments in the field of HTSMA thin films during the past decade, with focus on the systems Ti-Ni-X (X = Hf, Zr, Pd, Pt and Au), Ti-Ta, and Au-Cu-Al. These actuator films offer a wide range of transformation temperatures, thermal hysteresis, and recoverable strains suitable for high-temperature applications. Promising alloy compositions in the systems Ti-Ni-Hf, Ti-Ni-Pd, Ti-Ni-Au, and Au-Cu-Al are highlighted for further upscaling and development. The remaining challenges as well as prospects for development of HTSMA thin films are also discussed.

  11. High Temperature Superconducting Bearings for Lunar Telescope Mounts

    NASA Technical Reports Server (NTRS)

    Lamb, Mark; BuiMa, Ki; Cooley, Rodger; Mackey, Daniel; Meng, Ruling; Chu, Ching Wu; Chu, Wei Kan; Chen, Peter C.; Wilson, Thomas

    1995-01-01

    A telescope to be installed on the lunar surface in the near future must work in a cold and dusty vacuum environment for long periods without on site human maintenance. To track stars, the drive mechanism must be capable of exceedingly fine steps and repeatability. Further, the use of lightweight telescopes for obvious economic benefits burdens the requirement for stable support and rotation. Conventional contact bearings and gear drives have numerous failure modes under such a restrictive and harsh environment. However, hybrid superconducting magnetic bearings (HSMB) fit in naturally. These bearings are stable, light, passive, and essentially frictionless, allowing high precision electronic positioning control. By passive levitation, the HSMB does not wear out and requires neither maintenance nor power. A prototype illustrating the feasibility of this application is presented.

  12. Active superconducting devices formed of thin films

    DOEpatents

    Martens, Jon S.; Beyer, James B.; Nordman, James E.; Hohenwarter, Gert K. G.

    1991-05-28

    Active superconducting devices are formed of thin films of superconductor which include a main conduction channel which has an active weak link region. The weak link region is composed of an array of links of thin film superconductor spaced from one another by voids and selected in size and thickness such that magnetic flux can propagate across the weak link region when it is superconducting. Magnetic flux applied to the weak link region will propagate across the array of links causing localized loss of superconductivity in the links and changing the effective resistance across the links. The magnetic flux can be applied from a control line formed of a superconducting film deposited coplanar with the main conduction channel and weak link region on a substrate. The devices can be formed of any type to superconductor but are particularly well suited to the high temperature superconductors since the devices can be entirely formed from coplanar films with no overlying regions. The devices can be utilized for a variety of electrical components, including switching circuits, amplifiers, oscillators and modulators, and are well suited to microwave frequency applications.

  13. Microwave properties of high transition temperature superconducting thin films

    NASA Technical Reports Server (NTRS)

    Gordon, W. L.

    1991-01-01

    Extensive studies of the interaction of microwaves with YBa2Cu3O(7-delta), Bi-based, and Tl-based superconducting thin films deposited in several microwave substrates were performed. The data were obtained by measuring the microwave power transmitted through the film in the normal and the superconducting state and by resonant cavity techniques. The main motives were to qualify and understand the physical parameters such as the magnetic penetration depth, the complex conductivity, and the surface impedance, of high temperature superconducting (HTS) materials at microwave frequencies. Based on these parameters, the suitability of these HTS thin films is discussed for microwave applications.

  14. Contribution of ion beam analysis methods to the development of 2nd generation high temperature superconducting (HTS) wires

    SciTech Connect

    Usov, Igor O; Arendt, Paul N; Stan, Liliana; Holesinger, Terry G; Foltyn, Steven R; Depaula, Raymond F

    2009-01-01

    One of the crucial steps in the second generation high temperature superconducting wire program was development of the buffer layer architecture. The architecture designed at the Superconductivity Technology Center at Los Alamos National Laboratory consists of several oxide layers wherein each layer plays a specific role, namely: nucleation layer, diffusion barrier, biaxially textured template, and an intermediate layer with a good match to the lattice parameter of superconducting Y{sub 1}Ba{sub 2}Cu{sub 3}O{sub 7} (YBCO) compound. This report demonstrates how a wide range of ion beam analysis techniques (SIMS, RBS, channeling, PIXE, PIGE, NRA, ERD) was employed for analysis of each buffer layer and the YBCO films. These results assisted in understanding of a variety of physical processes occurring during the buffet layer fabrication and helped to optimize the buffer layer architecture as a whole.

  15. High Temperature Superconducting Terahertz Emitters with Various Mesa Structures

    NASA Astrophysics Data System (ADS)

    Delfanazari, Kaveh; Tsujimoto, M.; Kashiwagi, T.; Asai, H.; Kitamura, T.; Yamamoto, T.; Sawamura, M.; Ishida, K.; Watanabe, C.; Sekimoto, S.; Minami, H.; Tachiki, M.; Hattori, T.; Klemm, R. A.; Kadowaki, K.

    2013-03-01

    In 2007, the first observation of the coherent terahertz (THz) electromagnetic (EM) waves from a mesa structures of intrinsic Josephson junctions (IJJs) in high temperature superconductor Bi2Sr2CaCu2O8+δ (Bi-2212) is reported. The ac-Josephson effect as well as the cavity resonance conditions is considered as the principle mechanism of the THz radiation. In order to understand the cavity effect in THz radiation from IJJ mesas more clearly, we studied mesas with various geometries; various kinds of triangles, and pentagonal mesas with various sizes and thicknesses. The focused ion beam (FIB) milling technique is used in all mesa fabrications. In this talk, we discuss our recent progress in THz emission observation in pentagonal mesas. This work has been supported in part by CREST-JST (Japan Science and Technology Agency), WPI-MANA project (NIMS).

  16. Spacecraft design project: High temperature superconducting infrared imaging satellite

    NASA Technical Reports Server (NTRS)

    1991-01-01

    The High Temperature Superconductor Infrared Imaging Satellite (HTSCIRIS) is designed to perform the space based infrared imaging and surveillance mission. The design of the satellite follows the black box approach. The payload is a stand alone unit, with the spacecraft bus designed to meet the requirements of the payload as listed in the statement of work. Specifications influencing the design of the spacecraft bus were originated by the Naval Research Lab. A description of the following systems is included: spacecraft configuration, orbital dynamics, radio frequency communication subsystem, electrical power system, propulsion, attitude control system, thermal control, and structural design. The issues of testing and cost analysis are also addressed. This design project was part of the course Advanced Spacecraft Design taught at the Naval Postgraduate School.

  17. The 20 GHz circularly polarized, high temperature superconducting microstrip antenna array

    NASA Technical Reports Server (NTRS)

    Morrow, Jarrett D.; Williams, Jeffery T.; Long, Stuart A.; Wolfe, John C.

    1994-01-01

    The primary goal was to design and characterize a four-element, 20 GHz, circularly polarized microstrip patch antenna fabricated from YBa2Cu3O(x) superconductor. The purpose is to support a high temperature superconductivity flight communications experiment between the space shuttle orbiter and the ACTS satellite. This study is intended to provide information into the design, construction, and feasibility of a circularly polarized superconducting 20 GHz downlink or cross-link antenna. We have demonstrated that significant gain improvements can be realized by using superconducting materials for large corporate fed array antennas. In addition, we have shown that when constructed from superconducting materials, the efficiency, and therefore the gain, of microstrip patches increases if the substrate is not so thick that the dominant loss mechanism for the patch is radiation into the surface waves of the conductor-backed substrate. We have considered two design configurations for a superconducting 20 GHz four-element circularly polarized microstrip antenna array. The first is the Huang array that uses properly oriented and phased linearly polarized microstrip patch elements to realize a circularly polarized pattern. The second is a gap-coupled array of circularly polarized elements. In this study we determined that although the Huang array operates well on low dielectric constant substrates, its performance becomes extremely sensitive to mismatches, interelement coupling, and design imperfections for substrates with high dielectric constants. For the gap-coupled microstrip array, we were able to fabricate and test circularly polarized elements and four-element arrays on LaAlO3 using sputtered copper films. These antennas were found to perform well, with relatively good circular polarization. In addition, we realized a four-element YBa2Cu3O(x) array of the same design and measured its pattern and gain relative to a room temperature copper array. The patterns were

  18. An overview of recent developments in high-temperature superconductivity

    NASA Astrophysics Data System (ADS)

    Falicov, L. M.

    1987-10-01

    The BCS theory, in all probability, will explain the properties of new superconducting oxide materials. However, a detailed account of why they have such an unusually high transition temperature will require much more work. The key to the answer to the theoretical questions may be found in the fact that all these materials are ceramics, i.e., bad conductors in their normal phase. In fact, they are 'almost insulators', with strange and varied magnetic properties. And although the lattice polarization will certainly play a role (as shown by the isotope effect), the detailed motion of the electrons and the short-range Coulomb repulsion may give the unusual characteristics which result in high transition temperatures. From the point of view of practical applications and their implications in our everyday life, much can be speculated: transmission lines without any power losses, levitated trains, super-super-computers, new and not-yet-invented devices. But all these innovations will require the solution of complicated (and expensive to solve) materials problems (brittle, hard to handle ceramics; unstable phases; low critical currents) as well as a cool-headed economic analysis which this author is unable to provide.

  19. Development of Thin Film Ceramic Thermocouples for High Temperature Environments

    NASA Technical Reports Server (NTRS)

    Wrbanek, John D.; Fralick, Gustave C.; Farmer, Serene C.; Sayir, Ali; Blaha, Charles A.; Gonzalez, Jose M.

    2004-01-01

    The maximum use temperature of noble metal thin film thermocouples of 1100 C (2000 F) may not be adequate for use on components in the increasingly harsh conditions of advanced aircraft and next generation launch technology. Ceramic-based thermocouples are known for their high stability and robustness at temperatures exceeding 1500 C, but are typically found in the form of rods or probes. NASA Glenn Research Center is investigating the feasibility of ceramics as thin film thermocouples for extremely high temperature applications to take advantage of the stability and robustness of ceramics and the non-intrusiveness of thin films. This paper will discuss the current state of development in this effort.

  20. Performance evaluation of high-temperature superconducting current leads for micro-SMES systems

    SciTech Connect

    Niemann, R.C.; Cha, Y.S.; Hull, J.R.; Buckles, W.E.; Weber, B.R.; Yang, S.T.

    1995-08-01

    As part of the US Department of Energy`s Superconductivity Technology Program, Argonne National Laboratory and Superconductivity, Inc., are developing high-temperature superconductor (HTS) current leads for application to micro-superconducting magnetic energy storage systems. Two 1500-A HTS leads have been designed and constructed. The performance of the current lead assemblies is being evaluated in a zero-magnetic-field test program that includes assembly procedures, tooling, and quality assurance; thermal and electrical performance; and flow and mechanical characteristics. Results of evaluations performed to data are presented.

  1. Thin Film Ceramic Strain Sensor Development for High Temperature Environments

    NASA Technical Reports Server (NTRS)

    Wrbanek, John D.; Fralick, Gustave C.; Gonzalez, Jose M.; Laster, Kimala L.

    2008-01-01

    The need for sensors to operate in harsh environments is illustrated by the need for measurements in the turbine engine hot section. The degradation and damage that develops over time in hot section components can lead to catastrophic failure. At present, the degradation processes that occur in the harsh hot section environment are poorly characterized, which hinders development of more durable components, and since it is so difficult to model turbine blade temperatures, strains, etc, actual measurements are needed. The need to consider ceramic sensing elements is brought about by the temperature limits of metal thin film sensors in harsh environments. The effort at the NASA Glenn Research Center (GRC) to develop high temperature thin film ceramic static strain gauges for application in turbine engines is described, first in the fan and compressor modules, and then in the hot section. The near-term goal of this research effort was to identify candidate thin film ceramic sensor materials and provide a list of possible thin film ceramic sensor materials and corresponding properties to test for viability. A thorough literature search was conducted for ceramics that have the potential for application as high temperature thin film strain gauges chemically and physically compatible with the NASA GRCs microfabrication procedures and substrate materials. Test results are given for tantalum, titanium and zirconium-based nitride and oxynitride ceramic films.

  2. Recovery time of high temperature superconducting tapes exposed in liquid nitrogen

    NASA Astrophysics Data System (ADS)

    Sheng, Jie; Zeng, Weina; Yao, Zhihao; Zhao, Anfeng; Hu, Daoyu; Hong, Zhiyong

    2016-08-01

    The recovery time is a crucial parameter to high temperature superconducting tapes, especially in power applications. The cooperation between the reclosing device and the superconducting facilities mostly relies on the recovery time of the superconducting tapes. In this paper, a novel method is presented to measure the recovery time of several different superconducting samples. In this method criterion used to judge whether the sample has recovered is the liquid nitrogen temperature, instead of the critical temperature. An interesting phenomenon is observed during the testing of superconducting samples exposed in the liquid nitrogen. Theoretical explanations of this phenomenon are presented from the aspect of heat transfer. Optimization strategy of recovery characteristics based on this phenomenon is also briefly discussed.

  3. Superconductivity in CVD Diamond Films

    NASA Astrophysics Data System (ADS)

    Takano, Yoshihiko

    2005-03-01

    The recent news of superconductivity 2.3K in heavily boron-doped diamond synthesized by high pressure sintering was received with considerable surprise (1). Opening up new possibilities for diamond-based electrical devices, a systematic investigation of these phenomena clearly needs to be achieved. Application of diamond to actual devices requires it to be made into the form of wafers or thin films. We show unambiguous evidence for superconductivity in a heavily boron-doped diamond thin film deposited by the microwave plasma assisted chemical vapor deposition (MPCVD) method (2). An advantage of the MPCVD deposited diamond is that it can control boron concentration in its wider range, particularly in (111) oriented films. The temperature dependence of resistivity for (111) and (100) homoepitaxial thin films were measured under several magnetic fields. Superconducting transition temperatures of (111) homoepitaxial film are determined to be 11.4K for Tc onset and 7.2K for zero resistivity. And the upper critical field is estimated to be about 8T. These values are 2-3 times higher than these ever reported (1,3). On other hand, for (100) homoepitaxial film, Tc onset and Tc zero resistivity were estimated to be 6.3 and 3.2K respectively. The superconductivity in (100) film was strongly suppressed even at the same boron concentration. These differences of superconductivity in film orientation will be discussed. These findings established the superconductivity as a universal property of boron-doped diamond, demonstrating that device application is indeed a feasible challenge. 1. E. A. Ekimov et al. Nature, 428, 542 (2004). 2. Y. Takano et al., Appl. Phys. Lett. 85, 2851 (2004). 3. E. Bustarret et al., ond-mat 0408517.

  4. Characterization of polybenzimidazole (PBI) film at high temperatures

    NASA Technical Reports Server (NTRS)

    Hammoud, Ahmad N.; Suthar, J. L.

    1992-01-01

    Polybenzimidazole, a linear thermoplastic polymer with excellent thermal stability and strength retention over a wide range of temperatures, was evaluated for its potential use as the main dielectric in high temperature capacitors. The film was characterized in terms of its dielectric properties in a frequency range of 50 Hz to 100 kilo-Hz. These properties, which include the dielectric constant and dielectric loss, were also obtained in a temperature range from 20 C to 300 C with an electrical stress of 60 Hz, 50 V/mil present. The alternating and direct current breakdown voltages of silicone oil impregnated films as a function of temperature were also determined. The results obtained indicate that while the film remained relatively stable up to 200 C, it exhibited an increase in its dielectric properties as the temperature was raised to 300 C. It was also found that conditioning of the film by heat treatment at 60 C for six hours tended to improve its dielectric and breakdown properties. The results are discussed and conclusions made concerning the suitability of the film as a high temperature capacitor dielectric.

  5. Phase Diagram and High-Temperature Superconductivity of Compressed Selenium Hydrides

    NASA Astrophysics Data System (ADS)

    Zhang, Shoutao; Wang, Yanchao; Zhang, Jurong; Liu, Hanyu; Zhong, Xin; Song, Hai-Feng; Yang, Guochun; Zhang, Lijun; Ma, Yanming

    2015-10-01

    Recent discovery of high-temperature superconductivity (Tc = 190 K) in sulfur hydrides at megabar pressures breaks the traditional belief on the Tc limit of 40 K for conventional superconductors, and opens up the doors in searching new high-temperature superconductors in compounds made up of light elements. Selenium is a sister and isoelectronic element of sulfur, with a larger atomic core and a weaker electronegativity. Whether selenium hydrides share similar high-temperature superconductivity remains elusive, but it is a subject of considerable interest. First-principles swarm structure predictions are performed in an effort to seek for energetically stable and metallic selenium hydrides at high pressures. We find the phase diagram of selenium hydrides is rather different from its sulfur analogy, which is indicated by the emergence of new phases and the change of relative stabilities. Three stable and metallic species with stoichiometries of HSe2, HSe and H3Se are identified above ~120 GPa and they all exhibit superconductive behaviors, of which the hydrogen-rich HSe and H3Se phases show high Tc in the range of 40-110 K. Our simulations established the high-temperature superconductive nature of selenium hydrides and provided useful route for experimental verification.

  6. Phase Diagram and High-Temperature Superconductivity of Compressed Selenium Hydrides

    PubMed Central

    Zhang, Shoutao; Wang, Yanchao; Zhang, Jurong; Liu, Hanyu; Zhong, Xin; Song, Hai-Feng; Yang, Guochun; Zhang, Lijun; Ma, Yanming

    2015-01-01

    Recent discovery of high-temperature superconductivity (Tc = 190 K) in sulfur hydrides at megabar pressures breaks the traditional belief on the Tc limit of 40 K for conventional superconductors, and opens up the doors in searching new high-temperature superconductors in compounds made up of light elements. Selenium is a sister and isoelectronic element of sulfur, with a larger atomic core and a weaker electronegativity. Whether selenium hydrides share similar high-temperature superconductivity remains elusive, but it is a subject of considerable interest. First-principles swarm structure predictions are performed in an effort to seek for energetically stable and metallic selenium hydrides at high pressures. We find the phase diagram of selenium hydrides is rather different from its sulfur analogy, which is indicated by the emergence of new phases and the change of relative stabilities. Three stable and metallic species with stoichiometries of HSe2, HSe and H3Se are identified above ~120 GPa and they all exhibit superconductive behaviors, of which the hydrogen-rich HSe and H3Se phases show high Tc in the range of 40–110 K. Our simulations established the high-temperature superconductive nature of selenium hydrides and provided useful route for experimental verification. PMID:26490223

  7. Phase Diagram and High-Temperature Superconductivity of Compressed Selenium Hydrides.

    PubMed

    Zhang, Shoutao; Wang, Yanchao; Zhang, Jurong; Liu, Hanyu; Zhong, Xin; Song, Hai-Feng; Yang, Guochun; Zhang, Lijun; Ma, Yanming

    2015-01-01

    Recent discovery of high-temperature superconductivity (Tc = 190 K) in sulfur hydrides at megabar pressures breaks the traditional belief on the Tc limit of 40 K for conventional superconductors, and opens up the doors in searching new high-temperature superconductors in compounds made up of light elements. Selenium is a sister and isoelectronic element of sulfur, with a larger atomic core and a weaker electronegativity. Whether selenium hydrides share similar high-temperature superconductivity remains elusive, but it is a subject of considerable interest. First-principles swarm structure predictions are performed in an effort to seek for energetically stable and metallic selenium hydrides at high pressures. We find the phase diagram of selenium hydrides is rather different from its sulfur analogy, which is indicated by the emergence of new phases and the change of relative stabilities. Three stable and metallic species with stoichiometries of HSe2, HSe and H3Se are identified above ~120 GPa and they all exhibit superconductive behaviors, of which the hydrogen-rich HSe and H3Se phases show high Tc in the range of 40-110 K. Our simulations established the high-temperature superconductive nature of selenium hydrides and provided useful route for experimental verification. PMID:26490223

  8. High-frequency applications of high-temperature superconductor thin films

    NASA Astrophysics Data System (ADS)

    Klein, N.

    2002-10-01

    High-temperature superconducting thin films offer unique properties which can be utilized for a variety of high-frequency device applications in many areas related to the strongly progressing market of information technology. One important property is an exceptionally low level of microwave absorption at temperatures attainable with low power cryocoolers. This unique property has initiated the development of various novel type of microwave devices and commercialized subsystems with special emphasis on application in advanced microwave communication systems. The second important achievement related to efforts in oxide thin and multilayer technology was the reproducible fabrication of low-noise Josephson junctions in high-temperature superconducting thin films. As a consequence of this achievement, several novel nonlinear high-frequency devices, most of them exploiting the unique features of the ac Josephson effect, have been developed and found to exhibit challenging properties to be utilized in basic metrology and Terahertz technology. On the longer timescale, the achievements in integrated high-temperature superconductor circuit technology may offer a strong potential for the development of digital devices with possible clock frequencies in the range of 100 GHz.

  9. Electronic origin of high-temperature superconductivity in single-layer FeSe superconductor.

    PubMed

    Liu, Defa; Zhang, Wenhao; Mou, Daixiang; He, Junfeng; Ou, Yun-Bo; Wang, Qing-Yan; Li, Zhi; Wang, Lili; Zhao, Lin; He, Shaolong; Peng, Yingying; Liu, Xu; Chen, Chaoyu; Yu, Li; Liu, Guodong; Dong, Xiaoli; Zhang, Jun; Chen, Chuangtian; Xu, Zuyan; Hu, Jiangping; Chen, Xi; Ma, Xucun; Xue, Qikun; Zhou, X J

    2012-07-03

    The recent discovery of high-temperature superconductivity in iron-based compounds has attracted much attention. How to further increase the superconducting transition temperature (T(c)) and how to understand the superconductivity mechanism are two prominent issues facing the current study of iron-based superconductors. The latest report of high-T(c) superconductivity in a single-layer FeSe is therefore both surprising and significant. Here we present investigations of the electronic structure and superconducting gap of the single-layer FeSe superconductor. Its Fermi surface is distinct from other iron-based superconductors, consisting only of electron-like pockets near the zone corner without indication of any Fermi surface around the zone centre. Nearly isotropic superconducting gap is observed in this strictly two-dimensional system. The temperature dependence of the superconducting gap gives a transition temperature T(c)~ 55 K. These results have established a clear case that such a simple electronic structure is compatible with high-T(c) superconductivity in iron-based superconductors.

  10. Deposition of YBCO films by high temperature spray pyrolysis

    NASA Astrophysics Data System (ADS)

    Shields, T. C.; Abell, J. S.; Button, T. W.; Chakalov, R. A.; Chakalova, R. I.; Cai, C.; Haessler, W.; Eickemeyer, J.; de Boer, B.

    2002-08-01

    The fabrication of YBCO coated conductors on flexible textured metallic substrates requires the deposition of biaxially textured buffer layers and superconducting films. In this study we have prepared YBCO thin films on single crystal SrTiO 3 substrates and cube textured Ni substrates by spray pyrolysis. The Ni substrates have been pre-buffered with CeO 2/YSZ/CeO 2, layers deposited by pulsed laser deposition. Spray pyrolysis of nitrate solutions has been performed directly on heated substrates at temperatures between 800 and 900 °C without need for a subsequent annealing step. YBCO films deposited on both types of substrate are biaxially textured. Full width half maximum values determined from φ-scans are 8° and 20° for films on SrTiO 3 and buffered Ni substrates respectively. A transport Jc value of 1.2×10 5 A/cm 2 at 77 K and zero field has been achieved on SrTiO 3 ( T c onset=91 K, ΔTc=6 K). χ ac susceptibility measurements of films on buffered Ni substrates show Tc onsets of 88 K with ΔTc=18 K.

  11. Determination of the Cu(I) content in high temperature superconducting materials using neocuproine

    NASA Astrophysics Data System (ADS)

    Bondarenko, G. P.; Karaseva, L. G.

    1993-11-01

    The method of the direct spectrophotometric determination of the Cu + content in oxide Y, Bi and Tl-containing high temperature superconducting (HTSC) ceramics with neocuproine (sensitivity 2.5×10 -5% mas. and error of measurement ±0.85% P=0.95, n=7) has been developed. The method allows the dependence between the ratio {Cu +}/{Cu 2+} and superconducting properties (determined according to the magnetic response and the value of the low-field ESR signal) of copper-containing HTSC materials to be found.

  12. From quantum matter to high-temperature superconductivity in copper oxides.

    PubMed

    Keimer, B; Kivelson, S A; Norman, M R; Uchida, S; Zaanen, J

    2015-02-12

    The discovery of high-temperature superconductivity in the copper oxides in 1986 triggered a huge amount of innovative scientific inquiry. In the almost three decades since, much has been learned about the novel forms of quantum matter that are exhibited in these strongly correlated electron systems. A qualitative understanding of the nature of the superconducting state itself has been achieved. However, unresolved issues include the astonishing complexity of the phase diagram, the unprecedented prominence of various forms of collective fluctuations, and the simplicity and insensitivity to material details of the 'normal' state at elevated temperatures. PMID:25673411

  13. Performance of a four-element Ka-band high-temperature superconducting microstrip antenna

    NASA Technical Reports Server (NTRS)

    Richard, M. A.; Bhasin, K. B.; Gilbert, C.; Metzler, S.; Koepf, G.; Claspy, P. C.

    1992-01-01

    Superconducting four-element microstrip array antennas operating at 30 GHz have been designed and fabricated on a lanthanum aluminate (LaAlO3) substrates. The experimental performance of these thin film Y-Ba-Cu-O superconducting antennas is compared with that of identical antenna patterned with evaporated gold. Efficiency measurements of these antennas show an improvement of 2 dB at 70 K and as much as 3.5 dB at 40 K in the superconducting antenna over the gold antenna.

  14. High-Temperature, Thin-Film Ceramic Thermocouples Developed

    NASA Technical Reports Server (NTRS)

    Sayir, Ali; Blaha, Charles A.; Gonzalez, Jose M.

    2005-01-01

    To enable long-duration, more distant human and robotic missions for the Vision for Space Exploration, as well as safer, lighter, quieter, and more fuel efficient vehicles for aeronautics and space transportation, NASA is developing instrumentation and material technologies. The high-temperature capabilities of thin-film ceramic thermocouples are being explored at the NASA Glenn Research Center by the Sensors and Electronics Branch and the Ceramics Branch in partnership with Case Western Reserve University (CWRU). Glenn s Sensors and Electronics Branch is developing thin-film sensors for surface measurement of strain, temperature, heat flux, and surface flow in propulsion system research. Glenn s Ceramics Branch, in conjunction with CWRU, is developing structural and functional ceramic technology for aeropropulsion and space propulsion.

  15. Quantitative non-destructive evaluation of high-temperature superconducting materials

    SciTech Connect

    Achenbach, J.D.

    1990-09-15

    Even though the currently intensive research efforts on high-temperature superconducting materials have not yet converged on a well specified material, the strong indications are that such a material will be brittle, anisotropic, and may contain many flaws such as microcracks and voids at grain boundaries. Consequently, practical applications of high temperature superconducting materials will require a very careful strength analysis based on fracture mechanics considerations. Because of the high sensitivity of the strength of such materials to the presence of defects, methods of quantitative non-destructive evaluation may be expected to play an important role in strength determinations. This proposal is concerned with the use of ultrasonic methods to detect and characterize isolated cracks, clusters of microcracks and microcracks distributed throughout the material. Particular attention will be devoted to relating ultrasonic results directly to deterministic and statistical linear elastic fracture mechanics considerations.

  16. Doping dependence of spin excitations and its correlations with high-temperature superconductivity in iron pnictides.

    PubMed

    Wang, Meng; Zhang, Chenglin; Lu, Xingye; Tan, Guotai; Luo, Huiqian; Song, Yu; Wang, Miaoyin; Zhang, Xiaotian; Goremychkin, E A; Perring, T G; Maier, T A; Yin, Zhiping; Haule, Kristjan; Kotliar, Gabriel; Dai, Pengcheng

    2013-01-01

    High-temperature superconductivity in iron pnictides occurs when electrons and holes are doped into their antiferromagnetic parent compounds. Since spin excitations may be responsible for electron pairing and superconductivity, it is important to determine their electron/hole-doping evolution and connection with superconductivity. Here we use inelastic neutron scattering to show that while electron doping to the antiferromagnetic BaFe₂As₂ parent compound modifies the low-energy spin excitations and their correlation with superconductivity (<50 meV) without affecting the high-energy spin excitations (>100 meV), hole-doping suppresses the high-energy spin excitations and shifts the magnetic spectral weight to low-energies. In addition, our absolute spin susceptibility measurements for the optimally hole-doped iron pnictide reveal that the change in magnetic exchange energy below and above T(c) can account for the superconducting condensation energy. These results suggest that high-T(c) superconductivity in iron pnictides is associated with both the presence of high-energy spin excitations and a coupling between low-energy spin excitations and itinerant electrons.

  17. High-temperature superconductivity in a single copper-oxygen plane.

    PubMed

    Logvenov, G; Gozar, A; Bozovic, I

    2009-10-30

    The question of how thin cuprate layers can be while still retaining high-temperature superconductivity (HTS) has been challenging to address, in part because experimental studies require the synthesis of near-perfect ultrathin HTS layers and ways to profile the superconducting properties such as the critical temperature and the superfluid density across interfaces with atomic resolution. We used atomic-layer molecular beam epitaxy to synthesize bilayers of a cuprate metal (La(1.65)Sr(0.45)CuO4) and a cuprate insulator (La2CuO4) in which each layer is just three unit cells thick. We selectively doped layers with isovalent Zn atoms, which suppress superconductivity and act as markers, to show that this interface HTS occurs within a single CuO2 plane. This approach may also be useful in fabricating HTS devices. PMID:19900926

  18. Evaluation of a strengthening and insulation system for high temperature BSCCO-2223 superconducting tape

    SciTech Connect

    King, C.; Mantone, A.; Herd, K.; Laskaris, T.

    1995-12-31

    Recent advances in BSCCO-2223 superconducting tape quality and length have led to demonstration programs for coil performance. The conductors in these coils need to be insulated without damage to the superconducting properties. A paper insulation process developed at the General Electric Company (GE) for low temperature superconducting Nb{sub 3}Sn tape has been modified to provide the same insulation system to high temperature (HTS) superconducting tapes, such as BSCCO-2223. In this paper, we report on the insulation process and its effect on the tape performance. Several long lengths of conductor have been tested, unwound, insulated and retested to examine any degradation issues. Additionally, it is known that HTS materials are inherently weak in relation to the winding and handling stresses in a manufacturing environment. A system to provide mechanical stabilization to Nb{sub 3}Sn tape through a lamination process has been successfully applied to high temperature superconductors as a method to build a strong, windable composite. The system is described and mechanical and electrical properties of the strengthened tapes are discussed.

  19. Evaluation of high temperature superconductive thermal bridges for space borne cryogenic detectors

    NASA Technical Reports Server (NTRS)

    Scott, Elaine P.

    1996-01-01

    Infrared sensor satellites are used to monitor the conditions in the earth's upper atmosphere. In these systems, the electronic links connecting the cryogenically cooled infrared detectors to the significantly warmer amplification electronics act as thermal bridges and, consequently, the mission lifetimes of the satellites are limited due to cryogenic evaporation. High-temperature superconductor (HTS) materials have been proposed by researchers at the National Aeronautics and Space Administration Langley's Research Center (NASA-LaRC) as an alternative to the currently used manganin wires for electrical connection. The potential for using HTS films as thermal bridges has provided the motivation for the design and the analysis of a spaceflight experiment to evaluate the performance of this superconductive technology in the space environment. The initial efforts were focused on the preliminary design of the experimental system which allows for the quantitative comparison of superconductive leads with manganin leads, and on the thermal conduction modeling of the proposed system. Most of the HTS materials were indicated to be potential replacements for the manganin wires. In the continuation of this multi-year research, the objectives of this study were to evaluate the sources of heat transfer on the thermal bridges that have been neglected in the preliminary conductive model and then to develop a methodology for the estimation of the thermal conductivities of the HTS thermal bridges in space. The Joule heating created by the electrical current through the manganin wires was incorporated as a volumetric heat source into the manganin conductive model. The radiative heat source on the HTS thermal bridges was determined by performing a separate radiant interchange analysis within a high-T(sub c) superconductor housing area. Both heat sources indicated no significant contribution on the cryogenic heat load, which validates the results obtained in the preliminary conduction

  20. High temperature superconductivity in sulfur hydride under ultrahigh pressure: A complex superconducting phase beyond conventional BCS

    NASA Astrophysics Data System (ADS)

    Bussmann-Holder, Annette; Köhler, Jürgen; Whangbo, M.-H.; Bianconi, Antonio; Simon, Arndt

    2016-05-01

    The recent report of superconductivity under high pressure at the record transition temperature of Tc =203 K in pressurized H2S has been identified as conventional in view of the observation of an isotope effect upon deuteration. Here it is demonstrated that conventional theories of superconductivity in the sense of BCS or Eliashberg formalisms cannot account for the pressure dependence of the isotope coefficient. The only way out of the dilemma is a multi-band approach of superconductivity where already small interband coupling suffices to achieve the high values of Tc together with the anomalous pressure dependent isotope coefficient. In addition, it is shown that anharmonicity of the hydrogen bonds vanishes under pressure whereas anharmonic phonon modes related to sulfur are still active.

  1. Method and apparatus for measuring gravitational acceleration utilizing a high temperature superconducting bearing

    SciTech Connect

    Hull, J.R.

    2000-06-27

    Gravitational acceleration is measured in all spatial dimensions with improved sensitivity by utilizing a high temperature superconducting (HTS) gravimeter. The HTS gravimeter is comprised of a permanent magnet suspended in a spaced relationship from a high temperature superconductor, and a cantilever having a mass at its free end is connected to the permanent magnet at its fixed end. The permanent magnet and superconductor combine to form a bearing platform with extremely low frictional losses, and the rotational displacement of the mass is measured to determine gravitational acceleration. Employing a high temperature superconductor component has the significant advantage of having an operating temperature at or below 77 K, whereby cooling may be accomplished with liquid nitrogen.

  2. Method and Apparatus for measuring Gravitational Acceleration Utilizing a high Temperature Superconducting Bearing

    SciTech Connect

    Hull, John R.

    1998-11-06

    Gravitational acceleration is measured in all spatial dimensions with improved sensitivity by utilizing a high temperature superconducting (HTS) gravimeter. The HTS gravimeter is comprised of a permanent magnet suspended in a spaced relationship from a high temperature superconductor, and a cantilever having a mass at its free end is connected to the permanent magnet at its fixed end. The permanent magnet and superconductor combine to form a bearing platform with extremely low frictional losses, and the rotational displacement of the mass is measured to determine gravitational acceleration. Employing a high temperature superconductor component has the significant advantage of having an operative temperature at or below 77K, whereby cooling maybe accomplished with liquid nitrogen.

  3. Method and apparatus for measuring gravitational acceleration utilizing a high temperature superconducting bearing

    DOEpatents

    Hull, John R.

    2000-01-01

    Gravitational acceleration is measured in all spatial dimensions with improved sensitivity by utilizing a high temperature superconducting (HTS) gravimeter. The HTS gravimeter is comprised of a permanent magnet suspended in a spaced relationship from a high temperature superconductor, and a cantilever having a mass at its free end is connected to the permanent magnet at its fixed end. The permanent magnet and superconductor combine to form a bearing platform with extremely low frictional losses, and the rotational displacement of the mass is measured to determine gravitational acceleration. Employing a high temperature superconductor component has the significant advantage of having an operating temperature at or below 77K, whereby cooling may be accomplished with liquid nitrogen.

  4. High temperature superconductivity in sulfur and selenium hydrides at high pressure

    NASA Astrophysics Data System (ADS)

    Flores-Livas, José A.; Sanna, Antonio; Gross, E. K. U.

    2016-03-01

    Due to its low atomic mass, hydrogen is the most promising element to search for high-temperature phononic superconductors. However, metallic phases of hydrogen are only expected at extreme pressures (400 GPa or higher). The measurement of the record superconducting critical temperature of 203 K in a hydrogen-sulfur compound at 160 GPa of pressure [A.P. Drozdov, M.I. Eremets, I.A. Troyan, arXiv:1412.0460; [cond-mat.supr-con] (2014); A.P. Drozdov, M.I. Eremets, I.A. Troyan, V. Ksenofontov, S.I. Shylin, Nature 525, 73 (2015)], shows that metallization of hydrogen can be reached at significantly lower pressure by inserting it in the matrix of other elements. In this work we investigate the phase diagram and the superconducting properties of the H-S systems by means of minima hopping method for structure prediction and density functional theory for superconductors. We also show that Se-H has a similar phase diagram as its sulfur counterpart as well as high superconducting critical temperature. We predict H3Se to exceed 120 K superconductivity at 100 GPa. We show that both H3Se and H3S, due to the critical temperature and peculiar electronic structure, present rather unusual superconducting properties. Supplementary material in the form of one pdf file available from the Journal web page at: http://dx.doi.org/10.1140/epjb/e2016-70020-0

  5. Modeling of electrical properties in the fabrication of layered superconducting thin films

    NASA Astrophysics Data System (ADS)

    Din, Fasih Ud; Shaari, Abdul Halim; Kien, Chen Soo; Yar, Asfand; Talib, Zainal Abidin; Pah, Lim Kean

    2015-05-01

    The Pulse laser deposition (PLD) is a sole tool that is used to develop fine quality superconducting (YBCO) epitaxial films. The description and devices application aspect of the PLD on high temperature superconducting epitaxial films have an important role in the field of superconductivity. In the present study, thin films fabrication by PLD, buffer layers and electrical properties have been probed numerically with computer simulations. The electrical transport properties are discussed in term of thermally-activated flux motion model. The present study concludes that the plume dynamics is important in fabricating high quality epitaxial films thus improving the superconducting electrical transport properties.

  6. Preparation of high temperature superconducting coated wires by dipping and post annealing

    SciTech Connect

    Provenzano, V.; Singh, A.K.; Imam, M.A.; Tritt, T.M.

    1992-04-14

    This patent describes a process for coating a film on a wire substrate, it comprises: melting a superconducting metal oxide mixture in a crucible to form a melt; coating the substrate with a diffusion barrier; dipping the coated wire substrate into the melt; cooling the coated wire substrate at a rate sufficiently slow to avoid thermal shock and hot cracking; and post-annealing the cooled, coated wire substrate to relieve thermal stresses in the coating, whereupon the superconducting metal-oxide mixture forms a perovskite coating upon the wire substrate.

  7. DC characterization and 3D modelling of a triangular, epoxy-impregnated high temperature superconducting coil

    NASA Astrophysics Data System (ADS)

    Hu, D.; Ainslie, M. D.; Rush, J. P.; Durrell, J. H.; Zou, J.; Raine, M. J.; Hampshire, D. P.

    2015-06-01

    The direct current (dc) characterization of high temperature superconducting (HTS) coils is important for applications, such as electric machines, superconducting magnetic energy storage and transformers. In this paper, the dc characterization of a triangular-shaped, epoxy-impregnated HTS coil wound with YBCO coated conductor intended for use in an axial-flux HTS motor is presented. Voltage was measured at several points along the coil to provide detailed information of its dc characteristics. The coil is modelled based on the H -formulation using a new three-dimensional (3D) technique that utilizes the real superconducting layer thickness, and this model allows simulation of the actual geometrical layout of the HTS coil structure. Detailed information on the critical current density’s dependence on the magnitude and orientation of the magnetic flux density, Jc(B,θ), determined from experimental measurement of a short sample of the coated conductor comprising the coil is included directly in the numerical model by a two-variable direct interpolation to avoid developing complicated equations for data fitting and greatly improve the computational speed. Issues related to meshing the finite elements of the real thickness 3D model are also discussed in detail. Based on a comparison of the measurement and simulation results, it is found that non-uniformity along the length exists in the coil, which implies imperfect superconducting properties in the coated conductor, and hence, coil. By evaluating the current-voltage (I-V) curves using the experimental data, and after taking into account a more practical n value and critical current for the non-uniform region, the modelling results show good agreement with the experimental results, validating this model as an appropriate tool to estimate the dc I-V relationship of a superconducting coil. This work provides a further step towards effective and efficient 3D modelling of superconducting devices for large

  8. Possible light-induced superconductivity in K3C60 at high temperature.

    PubMed

    Mitrano, M; Cantaluppi, A; Nicoletti, D; Kaiser, S; Perucchi, A; Lupi, S; Di Pietro, P; Pontiroli, D; Riccò, M; Clark, S R; Jaksch, D; Cavalleri, A

    2016-02-25

    The non-equilibrium control of emergent phenomena in solids is an important research frontier, encompassing effects such as the optical enhancement of superconductivity. Nonlinear excitation of certain phonons in bilayer copper oxides was recently shown to induce superconducting-like optical properties at temperatures far greater than the superconducting transition temperature, Tc (refs 4-6). This effect was accompanied by the disruption of competing charge-density-wave correlations, which explained some but not all of the experimental results. Here we report a similar phenomenon in a very different compound, K3C60. By exciting metallic K3C60 with mid-infrared optical pulses, we induce a large increase in carrier mobility, accompanied by the opening of a gap in the optical conductivity. These same signatures are observed at equilibrium when cooling metallic K3C60 below Tc (20 kelvin). Although optical techniques alone cannot unequivocally identify non-equilibrium high-temperature superconductivity, we propose this as a possible explanation of our results.

  9. Possible light-induced superconductivity in K3C60 at high temperature.

    PubMed

    Mitrano, M; Cantaluppi, A; Nicoletti, D; Kaiser, S; Perucchi, A; Lupi, S; Di Pietro, P; Pontiroli, D; Riccò, M; Clark, S R; Jaksch, D; Cavalleri, A

    2016-02-25

    The non-equilibrium control of emergent phenomena in solids is an important research frontier, encompassing effects such as the optical enhancement of superconductivity. Nonlinear excitation of certain phonons in bilayer copper oxides was recently shown to induce superconducting-like optical properties at temperatures far greater than the superconducting transition temperature, Tc (refs 4-6). This effect was accompanied by the disruption of competing charge-density-wave correlations, which explained some but not all of the experimental results. Here we report a similar phenomenon in a very different compound, K3C60. By exciting metallic K3C60 with mid-infrared optical pulses, we induce a large increase in carrier mobility, accompanied by the opening of a gap in the optical conductivity. These same signatures are observed at equilibrium when cooling metallic K3C60 below Tc (20 kelvin). Although optical techniques alone cannot unequivocally identify non-equilibrium high-temperature superconductivity, we propose this as a possible explanation of our results. PMID:26855424

  10. Ultra-Low Heat-Leak, High-Temperature Superconducting Current Leads for Space Applications

    NASA Technical Reports Server (NTRS)

    Rey, Christopher M.

    2013-01-01

    NASA Goddard Space Flight Center has a need for current leads used in an adiabatic demagnetization refrigerator (ADR) for space applications. These leads must comply with stringent requirements such as a heat leak of approximately 100 W or less while conducting up to 10 A of electric current, from more than 90 K down to 10 K. Additionally, a length constraint of < 300 mm length and < 50 mm diameter is to be maintained. The need for these current leads was addressed by developing a superconducting hybrid lead. This hybrid lead comprises two different high-temperature superconducting (HTS) conductors bonded together at a thermally and electrically determined optimum point along the length of the current lead. By taking advantage of material properties of each conductor type, employing advanced fabrication techniques, and taking advantage of novel insulation materials, the company was able to develop and fabricate the lightweight, low heat-leak leads currently to NASA's specs.

  11. High temperature superconducting current lead test facility with heat pipe intercepts

    SciTech Connect

    Blumenfeld, P.E.; Prenger, C.; Roth, E.W.; Stewart, J.A.

    1998-12-31

    A high temperature superconducting (HTS) current lead test facility using heat pipe thermal intercepts is under development at the Superconducting Technology Center at Los Alamos National Laboratory. The facility can be configured for tests at currents up to 1,000 A. Mechanical cryocoolers provide refrigeration to the leads. Electrical isolation is maintained by intercepting thermal energy from the leads through cryogenic heat pipes. HST lead warm end temperature is variable from 65 K to over 90 K by controlling heat pipe evaporator temperature. Cold end temperature is variable up to 30 K. Performance predictions in terms of heat pipe evaporator temperature as a function of lead current are presented for the initial facility configuration, which supports testing up to 200 A. Measurements are to include temperature and voltage gradient in the conventional and HTS lead sections, temperature and heat transfer rate in the heat pipes. as well as optimum and off-optimum performance of the conventional lead sections.

  12. Evaluation of high temperature superconductive thermal bridges for space-borne cryogenic infrared detectors

    NASA Technical Reports Server (NTRS)

    Scott, Elaine P.

    1993-01-01

    The focus of this research is on the reduction of the refrigeration requirements for infrared sensors operating in space through the use of high temperature superconductive (HTS) materials as electronic leads between the cooled sensors and the relatively warmer data acquisition components. Specifically, this initial study was directed towards the design of an experiment to quantify the thermal performance of these materials in the space environment. First, an intensive review of relevant literature was undertaken, and then, design requirements were formulated. From this background information, a preliminary experimental design was developed. Additional studies will involve a thermal analysis of the experiment and further modifications of the experimental design.

  13. Application of high-temperature superconducting wires to magnetostrictive transducers for underwater sonar

    SciTech Connect

    Voccio, J.P.; Joshi, C.H.; Lindberg, J.F.

    1994-07-01

    Recently discovered cryogenic magnetostrictive materials show maximum strains greater than any room temperature materials. These cryogenic magnetostrictors can be combined with high-temperature superconducting (HTS) coils to create a sonar transducer with high efficiency and high acoustic power density. A prototype low-frequency (< 1,000 Hz) magnetostrictive transducer is described. This transducer uses a terbium-dysprosium (TbDy) magnetostrictor rod with HTS coils cooled to 50--80 K using a single-stage cryocooler. The device is designed for operation at water depths of 100 m and is believed to be the first fully integrated prototype demonstration of HTS.

  14. Soldered joints—an essential component of demountable high temperature superconducting fusion magnets

    NASA Astrophysics Data System (ADS)

    Tsui, Yeekin; Surrey, Elizabeth; Hampshire, Damian

    2016-07-01

    Demountable superconducting magnet coils would offer significant benefits to commercial nuclear fusion power plants. Whether large pressed joints or large soldered joints provide the solution for demountable fusion magnets, a critical component or building block for both will be the many, smaller-scale joints that enable the supercurrent to leave the superconducting layer, cross the superconducting tape and pass into the solder that lies between the tape and the conductor that eventually provides one of the demountable surfaces. This paper considers the electrical and thermal properties of this essential component part of demountable high temperature superconducting (HTS) joints by considering the fabrication and properties of jointed HTSs consisting of a thin layer of solder (In52Sn48 or Pb38Sn62) sandwiched between two rare-earth-Ba2Cu3O7 (REBCO) second generation HTS coated conductors (CCs). The HTS joints are analysed using numerical modelling, critical current and resistivity measurements on the joints from 300 to 4.2 K in applied magnetic fields up to 12 T, as well as scanning electron microscopy studies. Our results show that the copper/silver layers significantly reduce the heating in the joints to less than a few hundred mK. When the REBCO alone is superconducting, the joint resistivity (R J) predominantly has two sources, the solder layer and an interfacial resistivity at the REBCO/silver interface (∼25 nΩ cm2) in the as-supplied CCs which together have a very weak magnetoresistance in fields up to 12 T. We achieved excellent reproducibility in the R J of the In52Sn48 soldered joints of better than 10% at temperatures below T c of the REBCO layer which can be compared to variations of more than two orders of magnitude in the literature. We also show that demountable joints in fusion energy magnets are viable and need only add a few percent to the total cryogenic cost for a fusion tokamak.

  15. A Cryogenic Magnetostrictive Actuator Using a Persistent High Temperature Superconducting Magnet. Part 1; Concept and Design

    NASA Technical Reports Server (NTRS)

    Horner, Garnett; Bromberg, Leslie; Teter, J. P.

    2000-01-01

    Cryogenic magnetostrictive materials, such as rare earth zinc crystals, offer high strains and high forces with minimally applied magnetic fields, making the material ideally suited for deformable optics applications. For cryogenic temperature applications the use of superconducting magnets offer the possibility of a persistent mode of operation, i.e., the magnetostrictive material will maintain a strain field without power. High temperature superconductors (HTS) are attractive options if the temperature of operation is higher than 10 degrees Kelvin (K) and below 77 K. However, HTS wires have constraints that limit the minimum radius of winding, and even if good wires can be produced, the technology for joining superconducting wires does not exist. In this paper, the design and capabilities of a rare earth zinc magnetostrictive actuator using bulk HTS is described. Bulk superconductors can be fabricated in the sizes required with excellent superconducting properties. Equivalent permanent magnets, made with this inexpensive material, are persistent, do not require a persistent switch as in HTS wires, and can be made very small. These devices are charged using a technique which is similar to the one used for charging permanent magnets, e.g., by driving them into saturation. A small normal conducting coil can be used for charging or discharging. Because of the magnetic field capability of the superconductor material, a very small amount of superconducting magnet material is needed to actuate the rare earth zinc. In this paper, several designs of actuators using YBCO and BSCCO 2212 superconducting materials are presented. Designs that include magnetic shielding to prevent interaction between adjacent actuators will also be described. Preliminary experimental results and comparison with theory for BSCCO 2212 with a magnetostrictive element will be discussed.

  16. The creation of high-temperature superconducting cables of megawatt range in Russia

    NASA Astrophysics Data System (ADS)

    Sytnikov, V. E.; Bemert, S. E.; Krivetsky, I. V.; Romashov, M. A.; Popov, D. A.; Fedotov, E. V.; Komandenko, O. V.

    2015-12-01

    Urgent problems of the power industry in the 21st century require the creation of smart energy systems, providing a high effectiveness of generation, transmission, and consumption of electric power. Simultaneously, the requirements for controllability of power systems and ecological and resource-saving characteristics at all stages of production and distribution of electric power are increased. One of the decision methods of many problems of the power industry is the development of new high-efficiency electrical equipment for smart power systems based on superconducting technologies to ensure a qualitatively new level of functioning of the electric power industry. The intensive research and development of new types of electrical devices based on superconductors are being carried out in many industrialized advanced countries. Interest in such developments has especially increased in recent years owing to the discovery of so-called high-temperature superconductors (HTS) that do not require complicated and expensive cooling devices. Such devices can operate at cooling by inexpensive and easily accessible liquid nitrogen. Taking into account the obvious advantages of superconducting cable lines for the transmission of large power flows through an electrical network, as compared with conventional cables, the Federal Grid Company of Unified Energy System (JSC FGC UES) initiated a research and development program including the creation of superconducting HTS AC and DC cable lines. Two cable lines for the transmitted power of 50 MVA/MW at 20 kV were manufactured and tested within the framework of the program.

  17. The creation of high-temperature superconducting cables of megawatt range in Russia

    SciTech Connect

    Sytnikov, V. E. Bemert, S. E.; Krivetsky, I. V.; Romashov, M. A.; Popov, D. A.; Fedotov, E. V.; Komandenko, O. V.

    2015-12-15

    Urgent problems of the power industry in the 21st century require the creation of smart energy systems, providing a high effectiveness of generation, transmission, and consumption of electric power. Simultaneously, the requirements for controllability of power systems and ecological and resource-saving characteristics at all stages of production and distribution of electric power are increased. One of the decision methods of many problems of the power industry is the development of new high-efficiency electrical equipment for smart power systems based on superconducting technologies to ensure a qualitatively new level of functioning of the electric power industry. The intensive research and development of new types of electrical devices based on superconductors are being carried out in many industrialized advanced countries. Interest in such developments has especially increased in recent years owing to the discovery of so-called high-temperature superconductors (HTS) that do not require complicated and expensive cooling devices. Such devices can operate at cooling by inexpensive and easily accessible liquid nitrogen. Taking into account the obvious advantages of superconducting cable lines for the transmission of large power flows through an electrical network, as compared with conventional cables, the Federal Grid Company of Unified Energy System (JSC FGC UES) initiated a research and development program including the creation of superconducting HTS AC and DC cable lines. Two cable lines for the transmitted power of 50 MVA/MW at 20 kV were manufactured and tested within the framework of the program.

  18. Design analysis of a solid nitrogen cooled ''permanent'' high-temperature superconducting magnet system

    NASA Astrophysics Data System (ADS)

    Haid, Benjamin J.; Lee, Haigun; Iwasa, Yukikazu; Oh, Sang-Soo; Kwon, Young-Kil; Ryu, Kang-Sik

    2002-10-01

    Potential performance advantages of a solid nitrogen cooled "permanent" high-temperature superconducting (SN2/HTS) magnet system over a liquid helium cooled low-temperature superconducting (LHe/LTS) system are explored. The SN2/HTS system design includes a second solid heat capacitor that cools a radiation shield. Recooling of the heat capacitors is performed with a demountable cryocooler. The SN2/HTS system offers both enhanced stability and improved portability over a LHe/LTS system. Design codes are constructed to compare the SN2/HTS system design with a LHe/LTS design for a general permanent superconducting magnet system employing a room temperature bore. The codes predict the system volume and mass that should be expected for a given set of design requirements, i.e. field strength and bore size, and a given set of conductor properties. The results indicate that present HTS conductor critical current and index are not yet sufficient for producing SN2/HTS systems of a size that is comparable with that expected for a LHe/LTS system; however, the conductor properties of Bi2223/Ag have been consistently improving, and new HTS conductors are expected to be developed in the near future. The codes are used to determine the minimum Bi2223/Ag conductor performance required for a SN2/HTS system to be competitive with a LHe/LTS system.

  19. TOPICAL REVIEW: The physics behind high-temperature superconducting cuprates: the 'plain vanilla' version of RVB

    NASA Astrophysics Data System (ADS)

    Anderson, P. W.; Lee, P. A.; Randeria, M.; Rice, T. M.; Trivedi, N.; Zhang, F. C.

    2004-06-01

    One of the first theoretical proposals for understanding high-temperature superconductivity in the cuprates was Anderson's RVB theory using a Gutzwiller projected BCS wavefunction as an approximate ground state. Recent work by Paramekanti et al has shown that this variational approach gives a semi-quantitative understanding of the doping dependences of a variety of experimental observables in the superconducting state of the cuprates. In this paper we revisit these issues using the 'renormalized mean field theory' of Zhang et al based on the Gutzwiller approximation in which the kinetic and superexchange energies are renormalized by different doping-dependent factors gt and gS respectively. We point out a number of consequences of this early mean field theory for experimental measurements which were not available when it was first explored, and observe that it is able to explain the existence of the pseudogap, properties of nodal quasiparticles and approximate spin-charge separation, the latter leading to large renormalizations of the Drude weight and superfluid density. We use the Lee-Wen theory of the phase transition as caused by thermal excitation of nodal quasiparticles, and also obtain a number of further experimental confirmations. Finally, we remark that superexchange, and not phonons, is responsible for d-wave superconductivity in the cuprates.

  20. The US market for high-temperature superconducting wire in transmission cable applications

    SciTech Connect

    Forbes, D

    1996-04-01

    Telephone interviews were conducted with 23 utility engineers concerning the future prospects for high-temperature superconducting (HTS) transmission cables. All have direct responsibility for transmission in their utility, most of them in a management capacity. The engineers represented their utilities as members of the Electric Power Research Institute`s Underground Transmission Task Force (which has since been disbanded). In that capacity, they followed the superconducting transmission cable program and are aware of the cryogenic implications. Nineteen of the 23 engineers stated the market for underground transmission would grow during the next decade. Twelve of those specified an annual growth rate; the average of these responses was 5.6%. Adjusting that figure downward to incorporate the remaining responses, this study assumes an average growth rate of 3.4%. Factors driving the growth rate include the difficulty in securing rights-of-way for overhead lines, new construction techniques that reduce the costs of underground transmission, deregulation, and the possibility that public utility commissions will allow utilities to include overhead costs in their rate base. Utilities have few plans to replace existing cable as preventive maintenance, even though much of the existing cable has exceeded its 40-year lifetime. Ten of the respondents said the availability of a superconducting cable with the same life-cycle costs as a conventional cable and twice the ampacity would induce them to consider retrofits. The respondents said a cable with those characteristics would capture 73% of their cable retrofits.

  1. High-temperature superconducting superconductor/normal metal/superconducting devices

    NASA Technical Reports Server (NTRS)

    Foote, M. C.; Hunt, B. D.; Bajuk, L. J.

    1991-01-01

    We describe the fabrication and characterization of superconductor/normal metal/superconductor (SNS) devices made with the high-temperature superconductor (HTS) YBa2Cu3O(7-x). Structures of YBa2Cu3O(7-x)/Au/Nb on c-axis-oriented YBa2Cu3O(7-x) were made in both sandwich and edge geometries in order to sample the HTS material both along and perpendicular to the conducting a-b planes. These devices display fairly ideal Josephson properties at 4.2 K. In addition, devices consisting of YBa2Cu3O(7-x)/YBa2Cu3O(y)/YBa2Cu3O(7-x), with a 'normal metal' layer of reduced transition temperature YBa2Cu3O(7-x) were fabricated and show a great deal of promise for applications near 77 K. Current-voltage characteristics like those of the Resistively-Shunted Junction model are observed, with strong response to 10 GHz radiation above 60 K.

  2. Superconducting thin films on potassium tantalate substrates

    DOEpatents

    Feenstra, Roeland; Boatner, Lynn A.

    1992-01-01

    A superconductive system for the lossless transmission of electrical current comprising a thin film of superconducting material Y.sub.1 Ba.sub.2 Cu.sub.3 O.sub.7-x epitaxially deposited upon a KTaO.sub.3 substrate. The KTaO.sub.3 is an improved substrate over those of the prior art since the it exhibits small lattice constant mismatch and does not chemically react with the superconducting film.

  3. Cryogenics Vision Workshop for High-Temperature Superconducting Electric Power Systems Proceedings

    SciTech Connect

    Energetics, Inc.

    2000-01-01

    The US Department of Energy's Superconductivity Program for Electric Systems sponsored the Cryogenics Vision Workshop, which was held on July 27, 1999 in Washington, D.C. This workshop was held in conjunction with the Program's Annual Peer Review meeting. Of the 175 people attending the peer review meeting, 31 were selected in advance to participate in the Cryogenics Vision Workshops discussions. The participants represented cryogenic equipment manufactures, industrial gas manufacturers and distributors, component suppliers, electric power equipment manufacturers (Superconductivity Partnership Initiative participants), electric utilities, federal agencies, national laboratories, and consulting firms. Critical factors were discussed that need to be considered in describing the successful future commercialization of cryogenic systems. Such systems will enable the widespread deployment of high-temperature superconducting (HTS) electric power equipment. Potential research, development, and demonstration (RD and D) activities and partnership opportunities for advancing suitable cryogenic systems were also discussed. The workshop agenda can be found in the following section of this report. Facilitated sessions were held to discuss the following specific focus topics: identifying Critical Factors that need to be included in a Cryogenics Vision for HTS Electric Power Systems (From the HTS equipment end-user perspective) identifying R and D Needs and Partnership Roles (From the cryogenic industry perspective) The findings of the facilitated Cryogenics Vision Workshop were then presented in a plenary session of the Annual Peer Review Meeting. Approximately 120 attendees participated in the afternoon plenary session. This large group heard summary reports from the workshop session leaders and then held a wrap-up session to discuss the findings, cross-cutting themes, and next steps. These summary reports are presented in this document. The ideas and suggestions raised during

  4. High-temperature adhesives for bonding polyimide film. [bonding Kapton film for solar sails

    NASA Technical Reports Server (NTRS)

    St.clair, A. K.; Slemp, W. S.; St.clair, T. L.

    1980-01-01

    Experimental polyimide resins were developed and evaluated as potential high temperature adhesives for bonding Kapton polyimide film. Lap shear strengths of Kapton/Kapton bonds were obtained as a function of test temperature, adherend thickness, and long term aging at 575 K (575 F) in vacuum. Glass transition temperatures of the polyimide/"Kapton" bondlines were monitored by thermomechanical analysis.

  5. High-temperature superconductivity in two-band materials with interband pairing

    SciTech Connect

    Mazur, E. A. Dubovik, V. M.

    2015-07-15

    The Eliashberg theory generalized using peculiar properties of two-band electron–phonon (EP) systems is employed for studying T{sub c} in two-band materials (in particular, pnictides). In view of probably strong EP coupling, we take into account pairing within the entire width of the electron band, not only in a narrow layer at the Fermi surface. It is found that the effect of pairing of electrons belonging to different bands is a decisive factor for manifestation of the effect of high T{sub c} in these materials. It is shown that in materials analogous to pnictides, high T{sub c} values are reproduced by the two-band spectral function of electron–phonon interaction. The existence of one more family of two-band high-temperature materials with a superconducting transition temperature T{sub c} comparable to that in cuprates is predicted.

  6. Studying the force characteristics of a high temperature superconducting linear synchronous motor

    NASA Astrophysics Data System (ADS)

    Zheng, Luhai; Jin, Jianxun

    2011-08-01

    A single-sided high temperature superconducting (HTS) linear synchronous motor (HTSLSM) with an HTS bulk magnet array as its secondary has been developed. A field-cooled magnetization system has also been developed to obtain the magnet array with alternate magnetic poles. In order to identify the performance and force characteristics of the HTSLSM, an equivalent 3D finite element analysis (FEA) model has been built up to analyze its field distributions and cogging force characteristics, and an experimental system has been constructed to measure its thrust and normal force characteristics. The traits of the thrust and the normal force have been extracted by comprehensive experiments, including the trends versus different exciting currents, different air gap lengths and variable magnetic poles. The analysis and experimental results are fundamental to the electromagnetic optimum design and control scheme evaluation for the HTSLSM.

  7. The present status of the high temperature superconducting Maglev vehicle in China

    NASA Astrophysics Data System (ADS)

    Wang, J. S.; Wang, S. Y.; Zeng, Y. W.; Deng, C. Y.; Ren, Z. Y.; Wang, X. R.; Song, H. H.; Wang, X. Z.; Zheng, J.; Zhao, Y.

    2005-02-01

    Since the first successful running of the people-carrying high temperature superconducting (HTS) Maglev test vehicle on 31 December 2000, about 27 000 people have taken it, and the accumulated running distance is about 400 km. The levitation force of the onboard HTS equipment is measured periodically, and new experimental results measured on 5 March 2003 show that the performance of the onboard HTS Maglev equipment is almost the same as that of two years ago. Experimental results indicate that the long-term stability of the HTS Maglev vehicle is good. This further proves the feasibility of the HTS Maglev vehicle for practical transportation. It is worth mentioning that all the results are measured at a low speed; however, investigations of the dynamic performance of the HTS Maglev vehicle at high speed are necessary for practical application. Research on the dynamic performance of the HTS Maglev vehicle is ongoing.

  8. Triple-band high-temperature superconducting microstrip filter based on multimode split ring resonator

    NASA Astrophysics Data System (ADS)

    Liu, Hai-Wen; Wang, Yan; Fan, Yi-Chao; Guan, Xue-Hui; He, Yusheng

    2013-09-01

    A compact triple-band high-temperature superconducting (HTS) YBa2Cu3Oy microstrip bandpass filter using multimode split ring resonator (SRR) is presented in this letter. Also, its properties and equivalent circuit models are investigated by even- and odd-mode analysis. Moreover, design method of the proposed triple-band HTS filter for the applications of global positioning system at 1.57 GHz, worldwide interoperability for microwave access at 3.5 GHz, and wireless local area networks at 5.8 GHz is discussed. The centre frequencies and the bandwidths of the three passbands can be allocated properly choosing the dimension parameters of the multimode SRR. In addition, four transmission zeros are produced to improve the selectivity of this filter.

  9. Performance improvement of a high-temperature superconducting coil by separating and grading the coil edge

    NASA Astrophysics Data System (ADS)

    Ishiguri, Shinichi; Funamoto, Taisuke

    2011-06-01

    In this paper, we establish a model to analyze the transport current performance of a high-temperature superconducting (HTS) coil, considering the dependencies of critical current and n-value of an HTS tape on magnetic field and magnetic field angles. This analysis shows that relatively large electric fields appear at the coil’s edges, preventing improvement in the transport current performance of the coil. To solve this problem, in this paper, we propose a graded coil in which several coil edges of different heights are separated and graded. Analysis of its performance shows that the coil’s critical current increases, thus confirming that there exists an optimum coil cross section at which the stored energy and central magnetic field improve 2.1 times and 45%, respectively, compared with a typical rectangular coil that employs the same total length of the HTS tape. It is recommended that these results of the coil should be applied to SMES.

  10. Towards material-specific simulations of high-temperature superconducting cuprates

    NASA Astrophysics Data System (ADS)

    Schulthess, Thomas

    2006-03-01

    Simulations of high-temperature superconducting (HTSC) cuprates have typically fallen into two categories: (1) studies of generic models such as the two-dimensional (2D) Hubbard model, that are believed to capture the essential physics necessary to describe the superconducting state, and, (2) first principles electronic structure calculations that are based on the local density approximation (LDA) to density functional theory (DFT) and lead to materials specific models. With advent of massibely parallel vector supercomputers, such as the Cray X1E at ORNL, and cluster algorithms such as the Dynamical Cluster Approximation (DCA), it is now possible to systematically solve the 2D Hubbard model with Quantum Monte Carol (QMC) simulations and to establish that the model indeed describes d-wave superconductivity [1]. Furthermore, studies of a multi-band model with input parameters generated from LDA calculations demonstrate that the existence of a superconducting transition is very sensitive to the underlying band structure [2]. Application of the LDA to transition metal oxides is, however, hampered by spurious self-interactions that particularly affects localized orbitals. Here we apply the self-interaction corrected local spin-density method (SIC-LSD) to describe the electronic structure of the cuprates. It was recently applied with success to generate input parameters for simple models of Mn doped III-V semiconductors [3] and is known to properly describe the antiferromagnetic insulating ground state of the parent compounds of the HTSC cuprates. We will discus the models for HTSC cuprates derived from the SIC-LSD study and how the differences to the well-known LDA results impact the QMC-DCA simulations of the magnetic and superconducting properties. [1] T. A. Maier, M. Jarrell, T. C. Schulthess, P. R. C. Kent, and J. B. White, Phys. Rev. Lett. 95, 237001 (2005). [2] P. Kent, A. Macridin, M. Jarrell, T. Schulthess, O. Andersen, T. Dasgupta, and O. Jepsen, Bulletin of

  11. High-temperature superconductivity in heavily N- or B-doped graphene

    NASA Astrophysics Data System (ADS)

    Zhou, Jian; Sun, Qiang; Wang, Qian; Jena, Puru

    2015-08-01

    A two-dimensional honeycomb lattice of graphene, if heavily doped with electrons or holes, has been predicted to possess a wealth of fascinating properties including high-temperature superconductivity. Although such a material is possible with high concentration of N or B substitution, its experimental realization has been hindered due to its dynamic instability. Using density functional theory combined with a global structural search and phonon dispersion calculations, we show that an ordered 50 % N- or B-doped graphene can be made energetically and dynamically stable by simultaneous doping carriers and applying biaxial tensile strain; carrier doping moves the system toward aromaticity while tensile strain reduces adverse effects associated with electrostatic interaction. Electron-phonon coupling calculations show that the N- or B-doped graphene is superconducting with critical temperature reaching above the melting point of nitrogen in the case of 50 % N-doped graphene. In addition, the ideal strength of N-doped graphene is even higher than that of pure graphene.

  12. The high temperature superconductivity in cuprates: physics of the pseudogap region

    NASA Astrophysics Data System (ADS)

    Cea, Paolo

    2016-08-01

    We discuss the physics of the high temperature superconductivity in hole doped copper oxide ceramics in the pseudogap region. Starting from an effective reduced Hamiltonian relevant to the dynamics of holes injected into the copper oxide layers proposed in a previous paper, we determine the superconductive condensate wavefunction. We show that the low-lying elementary condensate excitations are analogous to the rotons in superfluid 4He. We argue that the rotons-like excitations account for the specific heat anomaly at the critical temperature. We discuss and compare with experimental observations the London penetration length, the Abrikosov vortices, the upper and lower critical magnetic fields, and the critical current density. We give arguments to explain the origin of the Fermi arcs and Fermi pockets. We investigate the nodal gap in the cuprate superconductors and discuss both the doping and temperature dependence of the nodal gap. We suggest that the nodal gap is responsible for the doping dependence of the so-called nodal Fermi velocity detected in angle resolved photoemission spectroscopy studies. We discuss the thermodynamics of the nodal quasielectron liquid and their role in the low temperature specific heat. We propose that the ubiquitous presence of charge density wave in hole doped cuprate superconductors in the pseudogap region originates from instabilities of the nodal quasielectrons driven by the interaction with the planar CuO2 lattice. We investigate the doping dependence of the charge density wave gap and the competition between charge order and superconductivity. We discuss the effects of external magnetic fields on the charge density wave gap and elucidate the interplay between charge density wave and Abrikosov vortices. Finally, we examine the physics underlying quantum oscillations in the pseudogap region.

  13. Ultra-High Performance, High-Temperature Superconducting Wires via Cost-effective, Scalable, Co-evaporation Process

    SciTech Connect

    Kim, Dr. Hosup; Oh, Sang-Soo; Ha, HS; Youm, D; Moon, SH; Kim, JH; Heo, YU; Dou, SX; Wee, Sung Hun; Goyal, Amit

    2014-01-01

    Long-length, high-temperature superconducting (HTS) wires capable of carrying high critical current, Ic, are required for a wide range of applications. Here, we report extremely high performance HTS wires based on 5 m thick SmBa2Cu3O7- (SmBCO) single layer films on textured metallic templates. SmBCO layer wires over 20 meters long were deposited by a cost-effective, scalable co-evaporation process using a batch-type drum in a dual chamber. All deposition parameters influencing the composition, phase, and texture of the films were optimized via a unique combinatorial method that is broadly applicable for co-evaporation of other promising complex materials containing several cations. Thick SmBCO layers deposited under optimized conditions exhibit excellent cube-on-cube epitaxy. Such excellent structural epitaxy over the entire thickness results in exceptionally high Ic performance, with average Ic over 1000 A/cm for the entire 22 meter long wire and maximum Ic over 1,500 A/cm for a short 12 cm long tape. The Ic values reported in this work are the highest values ever reported from any lengths of cuprate-based HTS wire or conductor.

  14. Ultra-High Performance, High-Temperature Superconducting Wires via Cost-effective, Scalable, Co-evaporation Process

    NASA Astrophysics Data System (ADS)

    Kim, Ho-Sup; Oh, Sang-Soo; Ha, Hong-Soo; Youm, Dojun; Moon, Seung-Hyun; Kim, Jung Ho; Dou, Shi Xue; Heo, Yoon-Uk; Wee, Sung-Hun; Goyal, Amit

    2014-04-01

    Long-length, high-temperature superconducting (HTS) wires capable of carrying high critical current, Ic, are required for a wide range of applications. Here, we report extremely high performance HTS wires based on 5 μm thick SmBa2Cu3O7 - δ (SmBCO) single layer films on textured metallic templates. SmBCO layer wires over 20 meters long were deposited by a cost-effective, scalable co-evaporation process using a batch-type drum in a dual chamber. All deposition parameters influencing the composition, phase, and texture of the films were optimized via a unique combinatorial method that is broadly applicable for co-evaporation of other promising complex materials containing several cations. Thick SmBCO layers deposited under optimized conditions exhibit excellent cube-on-cube epitaxy. Such excellent structural epitaxy over the entire thickness results in exceptionally high Ic performance, with average Ic over 1,000 A/cm-width for the entire 22 meter long wire and maximum Ic over 1,500 A/cm-width for a short 12 cm long tape. The Ic values reported in this work are the highest values ever reported from any lengths of cuprate-based HTS wire or conductor.

  15. Thermodynamic Critical Field and Superconducting Fluctuation of Vortices for High Temperature Cuprate Superconductor: La-214

    SciTech Connect

    Yung Moo Huh

    2001-05-01

    Thermodynamics has been studied systematically for the high temperature cuprate superconductor La{sub 2-x}Sr{sub x}CuO{sub 4-{delta}}, La-214, in the entire superconductive region from strongly underdoped to strongly overdoped regimes. Magnetization studies with H{parallel}c have been made in order to investigate the changes in free energy of the system as the number of carriers is reduced. Above the superconducting transition temperature, the normal-state magnetization exhibits a two-dimensional Heisenberg antiferromagnetic behavior. Below T{sub c}, magnetization data are thermodynamically reversible over large portions of the H-T plane, so the free energy is well defined in these regions. As the Sr concentration is varied over the wide range from 0.060 (strongly underdoped) to 0.234 (strongly overdoped), the free energy change goes through a maximum at the optimum doped in a manner similar to the T{sub c0} vs. x curve. The density of states, N(0), remains nearly constant in the overdoped and optimum doped regimes, taking a broad maximum around x = 0.188, and then drops abruptly towards zero in the underdoped regime. The La{sub 2-x}Sr{sub x}CuO{sub 4} (La-214) system displays the fluctuating vortex behavior with the characteristic of either 2D or 3D fluctuations as indicated by clearly identifiable crossing points T* close to T{sub c}. The dimensional character of the fluctuations depends on both applied magnetic fields and the density of charge carriers. The dimensional crossover from 2D to 3D occurs in the strongly underdoped regime when the c-axis coherence distance {zeta}{sub c} becomes comparable to the spacing between adjacent CuO{sub 2} layers s at sufficiently high magnetic fields near H{sub c2}.

  16. Quantitative determination of pairing interactions for high-temperature superconductivity in cuprates.

    PubMed

    Bok, Jin Mo; Bae, Jong Ju; Choi, Han-Yong; Varma, Chandra M; Zhang, Wentao; He, Junfeng; Zhang, Yuxiao; Yu, Li; Zhou, X J

    2016-03-01

    A profound problem in modern condensed matter physics is discovering and understanding the nature of fluctuations and their coupling to fermions in cuprates, which lead to high-temperature superconductivity and the invariably associated strange metal state. We report the quantitative determination of normal and pairing self-energies, made possible by laser-based angle-resolved photoemission measurements of unprecedented accuracy and stability. Through a precise inversion procedure, both the effective interactions in the attractive d-wave symmetry and the repulsive part in the full symmetry are determined. The latter is nearly angle-independent. Near T c, both interactions are nearly independent of frequency and have almost the same magnitude over the complete energy range of up to about 0.4 eV, except for a low-energy feature at around 50 meV that is present only in the repulsive part, which has less than 10% of the total spectral weight. Well below T c, they both change similarly, with superconductivity-induced features at low energies. Besides finding the pairing self-energy and the attractive interactions for the first time, these results expose the central paradox of the problem of high T c: how the same frequency-independent fluctuations can dominantly scatter at angles ±π/2 in the attractive channel to give d-wave pairing and lead to angle-independent repulsive scattering. The experimental results are compared with available theoretical calculations based on antiferromagnetic fluctuations, the Hubbard model, and quantum-critical fluctuations of the loop-current order.

  17. Quantitative determination of pairing interactions for high-temperature superconductivity in cuprates.

    PubMed

    Bok, Jin Mo; Bae, Jong Ju; Choi, Han-Yong; Varma, Chandra M; Zhang, Wentao; He, Junfeng; Zhang, Yuxiao; Yu, Li; Zhou, X J

    2016-03-01

    A profound problem in modern condensed matter physics is discovering and understanding the nature of fluctuations and their coupling to fermions in cuprates, which lead to high-temperature superconductivity and the invariably associated strange metal state. We report the quantitative determination of normal and pairing self-energies, made possible by laser-based angle-resolved photoemission measurements of unprecedented accuracy and stability. Through a precise inversion procedure, both the effective interactions in the attractive d-wave symmetry and the repulsive part in the full symmetry are determined. The latter is nearly angle-independent. Near T c, both interactions are nearly independent of frequency and have almost the same magnitude over the complete energy range of up to about 0.4 eV, except for a low-energy feature at around 50 meV that is present only in the repulsive part, which has less than 10% of the total spectral weight. Well below T c, they both change similarly, with superconductivity-induced features at low energies. Besides finding the pairing self-energy and the attractive interactions for the first time, these results expose the central paradox of the problem of high T c: how the same frequency-independent fluctuations can dominantly scatter at angles ±π/2 in the attractive channel to give d-wave pairing and lead to angle-independent repulsive scattering. The experimental results are compared with available theoretical calculations based on antiferromagnetic fluctuations, the Hubbard model, and quantum-critical fluctuations of the loop-current order. PMID:26973872

  18. Quantitative determination of pairing interactions for high-temperature superconductivity in cuprates

    PubMed Central

    Bok, Jin Mo; Bae, Jong Ju; Choi, Han-Yong; Varma, Chandra M.; Zhang, Wentao; He, Junfeng; Zhang, Yuxiao; Yu, Li; Zhou, X. J.

    2016-01-01

    A profound problem in modern condensed matter physics is discovering and understanding the nature of fluctuations and their coupling to fermions in cuprates, which lead to high-temperature superconductivity and the invariably associated strange metal state. We report the quantitative determination of normal and pairing self-energies, made possible by laser-based angle-resolved photoemission measurements of unprecedented accuracy and stability. Through a precise inversion procedure, both the effective interactions in the attractive d-wave symmetry and the repulsive part in the full symmetry are determined. The latter is nearly angle-independent. Near Tc, both interactions are nearly independent of frequency and have almost the same magnitude over the complete energy range of up to about 0.4 eV, except for a low-energy feature at around 50 meV that is present only in the repulsive part, which has less than 10% of the total spectral weight. Well below Tc, they both change similarly, with superconductivity-induced features at low energies. Besides finding the pairing self-energy and the attractive interactions for the first time, these results expose the central paradox of the problem of high Tc: how the same frequency-independent fluctuations can dominantly scatter at angles ±π/2 in the attractive channel to give d-wave pairing and lead to angle-independent repulsive scattering. The experimental results are compared with available theoretical calculations based on antiferromagnetic fluctuations, the Hubbard model, and quantum-critical fluctuations of the loop-current order. PMID:26973872

  19. Thin film thermocouples for high temperature measurement on ceramic materials

    NASA Technical Reports Server (NTRS)

    Holanda, Raymond

    1992-01-01

    Thin film thermocouples have been developed for use on metal parts in jet engines to 1000 C. However, advanced propulsion systems are being developed that will use ceramic materials and reach higher temperatures. The purpose of this work is to develop thin film thermocouples for use on ceramic materials. The thin film thermocouples are Pt13Rh/Pt fabricated by the sputtering process. Lead wires are attached using the parallel-gap welding process. The ceramic materials are silicon nitride, silicon carbide, aluminum oxide, and mullite. Both steady state and thermal cycling furnace tests were performed in the temperature range to 1500 C. High-heating-rate tests were performed in an arc lamp heat-flux-calibration facility. The fabrication of the thin film thermocouples is described. The thin film thermocouple output was compared to a reference wire thermocouple. Drift of the thin film thermocouples was determined, and causes of drift are discussed. The results of high-heating-rate tests up to 2500 C/sec are presented. The stability of the ceramic materials is examined. It is concluded that Pt13Rh/Pt thin film thermocouples are capable of meeting lifetime goals of 50 hours or more up to temperatures of 1500 C depending on the stability of the particular ceramic substrate.

  20. Pulsed Laser Deposition of High Temperature Protonic Films

    NASA Technical Reports Server (NTRS)

    Dynys, Fred W.; Berger, M. H.; Sayir, Ali

    2006-01-01

    Pulsed laser deposition has been used to fabricate nanostructured BaCe(0.85)Y(0.15)O3- sigma) films. Protonic conduction of fabricated BaCe(0.85)Y(0.15)O(3-sigma) films was compared to sintered BaCe(0.85)Y(0.15)O(3-sigma). Sintered samples and laser targets were prepared by sintering BaCe(0.85)Y(0.15)O(3-sigma) powders derived by solid state synthesis. Films 1 to 8 micron thick were deposited by KrF excimer laser on porous Al2O3 substrates. Thin films were fabricated at deposition temperatures of 700 to 950 C at O2 pressures up to 200 mTorr using laser pulse energies of 0.45 - 0.95 J. Fabricated films were characterized by X-ray diffraction, electron microscopy and electrical impedance spectroscopy. Single phase BaCe(0.85)Y(0.15)O(3-sigma) films with a columnar growth morphology are observed with preferred crystal growth along the [100] or [001] direction. Results indicate [100] growth dependence upon laser pulse energy. Electrical conductivity of bulk samples produced by solid state sintering and thin film samples were measured over a temperature range of 100 C to 900 C. Electrical conduction behavior was dependent upon film deposition temperature. Maximum conductivity occurs at deposition temperature of 900 oC; the electrical conductivity exceeds the sintered specimen. All other deposited films exhibit a lower electrical conductivity than the sintered specimen. Activation energy for electrical conduction showed dependence upon deposition temperature, it varied

  1. YBCO High-Temperature Superconducting Filters on M-Plane Sapphire Substrates

    NASA Technical Reports Server (NTRS)

    Sabataitis, J. C.; Mueller, C. H.; Miranda, F. A.; Warner, J.; Bhasin, K. B.

    1996-01-01

    Since the discovery of High Temperature Superconductors (HTS) in 1986, microwave circuits have been demonstrated using HTS films on various substrates. These HTS-based circuits have proven to operate with less power loss than their metallic film counterparts at 77 K. This translates into smaller and lighter microwave circuits for space communication systems such as multiplexer filter banks. High quality HTS films have conventionally been deposited on lanthanum aluminate (LaAlO3) substrates. However, LaAlO3 has a relative dielectric constant (epsilon(sub r)) of 24. With a epsilon(sub r) approx. 9.4-11.6, sapphire (Al2O3) would be a preferable substrate for the fabrication of HTS-based components since the lower dielectric constant would permit wider microstrip lines to be used in filter design, since the lower dielectric constant would permit wider microstrip lines to be used for a given characteristic impedance (Z(sub 0)), thus lowering the insertion losses and increasing the power handling capabilities of the devices. We report on the fabrication and characterization of YBa2Cu3O(7-delta) (YBCO) on M-plane sapphire bandpass filters at 4.0 GHz. For a YBCO 'hairpin' filter, a minimum insertion loss of 0.5 dB was measured at 77 K as compared with 1.4 dB for its gold counterpart. In an 'edge-coupled' configuration, the insertion loss went down from 0.9 dB for the gold film to 0.8 dB for the YBCO film at the same temperature.

  2. Superconductivity of Iron Selenide Thin Films

    NASA Astrophysics Data System (ADS)

    Nie, Yuefeng; Brahimi, Erind; Budnick, Joseph; Hines, William; Jain, Menka; Wells, Barrett

    2009-03-01

    Near stoichiometry FeSe films were successfully grown on MgO, SrTiO3, and LaAlO3 single crystal substrates using pulsed laser deposition (PLD). X-ray diffraction analysis showed that the FeSe films have a tetragonal structure on SrTiO3 and LaAlO3 substrates. A mixture of tetragonal and hexagonal structures was observed on MgO substrates due to the larger lattice constant misfit. The superconductivity of films exhibited a strong dependence on epitaxial strain and thickness. Thicker films (˜ 100 nm and ˜ 200 nm) are fully relaxed and have a clear superconducting transition near that of the bulk FeSe. Thinner films (˜ 50 nm) are strained. Films on nearly lattice-matched LaAlO3 are superconducting, while films under tension on SrTiO3 or MgO are metallic but not superconducting down to 5K. The onset temperature for superconductivity have a near linear magnetic field dependence with dH/dT = - 2.8 T/K for fields up to 9T.

  3. Effect of Discontinuities and Penetrations on the Shielding Efficacy of High Temperature Superconducting Magnetic Shields

    NASA Astrophysics Data System (ADS)

    Hatwar, R.; Kvitkovic, J.; Herman, C.; Pamidi, S.

    2015-12-01

    High Temperature Superconducting (HTS) materials have been demonstrated to be suitable for applications in shielding of both DC and AC magnetic fields. Magnetic shielding is required for protecting sensitive instrumentation from external magnetic fields and for preventing the stray magnetic fields produced by high power density equipment from affecting neighbouring devices. HTS shields have high current densities at relatively high operating temperatures (40-77 K) and can be easily fabricated using commercial HTS conductor. High current densities in HTS materials allow design and fabrication of magnetic shields that are lighter and can be incorporated into the body and skin of high power density devices. HTS shields are particularly attractive for HTS devices because a single cryogenic system can be used for cooling the device and the associated shield. Typical power devices need penetrations for power and signal cabling and the penetrations create discontinuities in HTS shields. Hence it is important to assess the effect of the necessary discontinuities on the efficacy of the shields and the design modifications necessary to accommodate the penetrations.

  4. Dynamic response characteristics of the high-temperature superconducting maglev system under lateral eccentric distance

    NASA Astrophysics Data System (ADS)

    Wang, Bo; Zheng, Jun; Si, Shuaishuai; Qian, Nan; Li, Haitao; Li, Jipeng; Deng, Zigang

    2016-07-01

    Off-centre operation of high-temperature superconducting (HTS) maglev systems caused by inevitable conditions such as the misregistration of vehicle, crosswind and curve negotiation, may change the distribution of the trapped flux in the HTS bulks and the magnetic interaction between HTS bulks and the PMG. It impacts on the performance of HTS maglev, and more seriously makes the maglev vehicle overturned. Therefore, understanding the performance of the HTS maglev in off-center operation is very important. In this paper, the dynamic response characteristics of a cryostat with twenty-four onboard YBaCuO superconductor bulks were experimentally investigated at different eccentric distances under loads before the initial FC process. Parameters such as vibration accelerations, displacement, natural frequency and dynamic stiffness were acquired and analyzed via the B&K vibration analyzer and laser displacement sensors. Results suggest that the natural frequency and dynamic stiffness of the maglev vehicle would be obviously reduced with the eccentric distance, posing negative effects on the stability of HTS maglev.

  5. Operating experience with the southwire 30-meter high-temperature superconducting power cable

    NASA Astrophysics Data System (ADS)

    Stovall, J. P.; Lue, J. W.; Demko, J. A.; Fisher, P. W.; Gouge, M. J.; Hawsey, R. A.; Armstrong, J. W.; Hughey, R. L.; Lindsay, D. T.; Roden, M. L.; Sinha, U. K.; Tolbert, J. C.

    2002-05-01

    Southwire Company is operating a high-temperature superconducting (HTS) cable system at its corporate headquarters. The 30-m long, 3-phase cable system is powering three Southwire manufacturing plants and is rated at 12.4-kV, 1250-A, 60-Hz. Cooling is provided by a pressurized liquid nitrogen system operating at 70-80 K. The cables were energized on January 5, 2000 for on-line testing and operation and in April 2000 were placed into extended service. As of June 1, 2001, the HTS cables have provided 100% of the customer load for 8000 hours. The cryogenic system has been in continuous operation since November 1999. The HTS cable system has not been the cause of any power outages to the average 20 MW industrial load served by the cable. The cable has been exposed to short-circuit currents caused by load-side faults without damage. Based upon field measurements described herein, the cable critical current-a key performance parameter-remains the same and has not been affected by the hours of real-world operation, further proving the viability of this promising technology.

  6. Development of high-efficiency Stirling cryocoolers for high temperature superconducting motors

    NASA Astrophysics Data System (ADS)

    Nakano, K.; Yumoto, K.; Hiratsuka, Y.

    2015-12-01

    For wide spread high-temperature superconductor (HTS) devices, a cryocooler having COP of >0.1, with a compact size, light weight, high efficiency and high reliability is required. For practical use of superconductive devices, Sumitomo Heavy Industries, Ltd. (SHI) developed a high-efficiency Stirling type pulse tube cryocooler (STPC). The STPC had high reliability and low vibration. However, its efficiency was not enough to meet the demands of an HTS motor. To further improve the efficiency, we reconsidered the expander of cryocooler and developed a Stirling cryocooler (STC). Two prototype units of a compact, high-efficiency split Stirling cryocooler were designed, built and tested. With the second prototype unit, a cooling capacity of 151 W at 70 K and a minimum temperature of 33 K have been achieved with a compressor input power of 2.15 kW. Accordingly, COP of about 0.07 has been achieved. The detailed design of the prototype units and the experimental results will be reported in this paper.

  7. A high-temperature superconducting millimeter wave detecting system based on pulse tube cryocooler

    NASA Astrophysics Data System (ADS)

    Chen, Jian; Wu, Peiheng; Nakajima, Kensuke; Yamashita, Tsutomu

    2004-10-01

    A millimeter (mm) wave broadband video detecting system using high temperature superconducting (HTS) junction and compact pulse tube cryocooler (PTC) has been studied. The lowest attainable temperature of the PTC is 42K and the operating temperature (T) can be adjusted by changing the pressure difference in the compressor. By measuring the linewidth of the Josephson oscillation as well as the dynamic range of the Josephson detector, it is found that the PTC has no excess noise compared with other kinds of cryostats such as liquid helium cryostats, and is very suitable for the applications in the mm wave detecting system. Furthermore, to improve the sensitivity of the system, the coupling efficiency of the system has been studied in detail. It is found that the coupling efficiency increases with the increase of RN linearly, and is better than 1% for RN of 1.7 Ohm. A sensitivity of about 318V/W has been obtained for the system based on the PTC and a junction with RN=1.7 Ohm and ICRN =1mV.

  8. Quench Detection and Protection for High Temperature Superconducting Transformers by Using the Active Power Method

    NASA Astrophysics Data System (ADS)

    Nanato, N.; Kobayashi, Y.

    AC high temperature superconducting (HTS) coils have been developed for transformers, motors and so on. Quench detection and protection system are essential for safety operations of the AC HTS facilities. The balance voltage method is universally used for the quench detection and protection, however especially for AC operations, the method has risks in terms of high voltage sparks. Because the method needs a voltage tap soldered to a midpoint of the coil winding and the AC HTS facilities generally operate at high voltages and therefore high voltage sparks may occur at the midpoint with no insulation. We have proposed the active power method for the quench detection and protection. The method requires no voltage tap on the midpoint of the coil winding and therefore it has in-built effectiveness for the AC HTS facilities. In this paper, we show that the method can detect the quench in an HTS transformer and moreover our proposed quench protection circuits which consist of thyristors are simple and useful for the AC HTS facilities.

  9. Development of practical high temperature superconducting wire for electric power application

    NASA Technical Reports Server (NTRS)

    Hawsey, Robert A.; Sokolowski, Robert S.; Haldar, Pradeep; Motowidlo, Leszek R.

    1995-01-01

    The technology of high temperature superconductivity has gone from beyond mere scientific curiousity into the manufacturing environment. Single lengths of multifilamentary wire are now produced that are over 200 meters long and that carry over 13 amperes at 77 K. Short-sample critical current densities approach 5 x 104 A/sq cm at 77 K. Conductor requirements such as high critical current density in a magnetic field, strain-tolerant sheathing materials, and other engineering properties are addressed. A new process for fabricating round BSCCO-2212 wire has produced wires with critical current densities as high as 165,000 A/sq cm at 4.2 K and 53,000 A/sq cm at 40 K. This process eliminates the costly, multiple pressing and rolling steps that are commonly used to develop texture in the wires. New multifilamentary wires with strengthened sheathing materials have shown improved yield strengths up to a factor of five better than those made with pure silver. Many electric power devices require the wire to be formed into coils for production of strong magnetic fields. Requirements for coils and magnets for electric power applications are described.

  10. High Temperature Superconducting Magnets with Active Control for Attraction Levitation Transport Applications

    NASA Technical Reports Server (NTRS)

    Jones, Harry; Jenkins, Richard G.; Goodall, Roger M.; Macleod, Colin; ElAbbar, Abdallah A.; Campbell, Archie M.

    1996-01-01

    A research program, involving 3 British universities, directed at quantifying the controllability of High Temperature Superconducting (HTS) magnets for use in attraction levitation transport systems will be described. The work includes measurement of loss mechanisms for iron cored HTS magnets which need to produce a flux density of approx. 1 tesla in the airgap between the magnet poles and a ferromagnetic rail. This flux density needs to be maintained and this is done by introducing small variations of the magnet current using a feedback loop, at frequencies up to 10 Hz to compensate for load changes, track variation etc. The test magnet assemblies constructed so far will be described and the studies and modelling of designs for a practical levitation demonstrator (using commercially obtained HTS tape) will be discussed with particular emphasis on how the field distribution and its components, e.g., the component vector normal to the broad face of the tape, can radically affect design philosophy compared to the classical electrical engineering approach. Although specifically aimed at levitation transport the controllability data obtained have implications for a much wider range of applications.

  11. Comparative Assessment of Direct Drive High Temperature Superconducting Generators in Multi-Megawatt Class Wind Turbines

    SciTech Connect

    Maples, B.; Hand, M.; Musial, W.

    2010-10-01

    This paper summarizes the work completed under the CRADA between NREL and American Superconductor (AMSC). The CRADA combined NREL and AMSC resources to benchmark high temperature superconducting direct drive (HTSDD) generator technology by integrating the technologies into a conceptual wind turbine design, and comparing the design to geared drive and permanent magnet direct drive (PMDD) wind turbine configurations. Analysis was accomplished by upgrading the NREL Wind Turbine Design Cost and Scaling Model to represent geared and PMDD turbines at machine ratings up to 10 MW and then comparing cost and mass figures of AMSC's HTSDD wind turbine designs to theoretical geared and PMDD turbine designs at 3.1, 6, and 10 MW sizes. Based on the cost and performance data supplied by AMSC, HTSDD technology has good potential to compete successfully as an alternative technology to PMDD and geared technology turbines in the multi megawatt classes. In addition, data suggests the economics of HTSDD turbines improve with increasing size, although several uncertainties remain for all machines in the 6 to 10 MW class.

  12. Van Hove singularities and spectral smearing in high-temperature superconducting H3S

    NASA Astrophysics Data System (ADS)

    Quan, Yundi; Pickett, Warren E.

    2016-03-01

    The superconducting phase of hydrogen sulfide at Tc=200 K observed by Drozdov and collaborators at pressures around 200 GPa is simple bcc I m 3 ¯m H3S from a combination of theoretical and experimental confirmation. The various "extremes" that are involved—high pressure implying extreme reduction of volume, extremely high H phonon energy scale around 1400 K, extremely high temperature for a superconductor—necessitates a close look at new issues raised by these characteristics in relation to high Tc itself. First principles methods are applied to analyze the H3S electronic structure, beginning with the effect of sulfur and then focusing on the origin and implications of the two van Hove singularities (vHs) providing an impressive peak in the density of states near the Fermi energy. Implications arising from strong coupling Migdal-Eliashberg theory are studied. It becomes evident that electron spectral density smearing due to virtual phonon emission and absorption must be accounted for in a correct understanding of this unusual material and to obtain accurate theoretical predictions. Means for increasing Tc in H3S -like materials are noted.

  13. van Hove Singularities and Spectral Smearing in High Temperature Superconducting H3S

    NASA Astrophysics Data System (ADS)

    Quan, Yundi; Pickett, Warren E.

    The superconducting phase of hydrogen sulfide at Tc=200 K observed by Drozdov and collaborators at pressures around 200 GPa is simple bcc Im 3 m H3S reopens questions about what is achievable in high Tc. The various ''extremes'' that are involved - pressure, implying extreme reduction of volume, extremely high H phonon energy scale around 1400K, extremely high temperature for a superconductor - necessitate a close look at new issues raised by these characteristics in relation to high Tc. We have applied first principles methods to analyze the H3S electronic structure, particularly the van Hove singularities (vHs) and the effect of sulfur. Focusing on the two closely spaced vHs near the Fermi level that give rise to the impressively sharp peak in the density of states, the implications of strong coupling Migdal-Eliashberg theory are assessed. The electron spectral density smearing due to virtual phonon emission and absorption, as done in earlier days for A15 superconductors, must be included explicitly to obtain accurate theoretical predictions and a correct understanding. Means for increasing Tc in H3S-like materials will be mentioned. NSF DMR Grant 1207622.

  14. Application Study of a High Temperature Superconducting Fault Current Limiter for Electric Power System

    NASA Astrophysics Data System (ADS)

    Naito, Yuji; Shimizu, Iwao; Yamaguchi, Iwao; Kaiho, Katsuyuki; Yanabu, Satoru

    Using high temperature superconductor, a Superconducting Fault Current Limiter (SFCL) was made and tested. Superconductor and vacuum interrupter as commutation switch are connected in parallel with bypass coil. When a fault occurs and the excessive current flows, superconductor is first quenched and the current is transferred to bypass coil because on voltage drop of superconductor. At the same time, since magnetic field is generated by current which flows in bypass coil, commutation switch is immediately driven by electromagnetic repulsion plate connected to driving rod of vacuum interrupter, and superconductor is separated from this circuit. Using the testing model, we could separate the superconductor from a circuit due to movement of vacuum interrupter within half-cycle current and transfer all current to bypass coil. Since operation of a commutation switch is included in current limiting operation of this testing model, it is one of helpful circuit of development of SFCL in the future. Moreover, since it can make the consumed energy of superconductor small during fault state due to realization of high-speed switch with simple composition, the burden of superconductor is reduced compared with conventional resistive type SFCL and it is considered that the flexibility of a SFCL design increases. Cooperation with a circuit breaker was also considered, the trial calculation of a parameter and energy of operation is conducted and discussion in the case of installing the SFCL to electric power system is made.

  15. Calculating AC Losses in High-temperature Superconducting Cables Comprising Coated Conductors

    NASA Astrophysics Data System (ADS)

    Noji, Hideki; Kawano, Shouta; Akaki, Yoji; Hamada, Tsugio

    In this study, we present a new calculation model of AC loss in a high-temperature superconducting (HTS) cable comprising coated conductors. AC loss is calculated by an electric circuit (EC) model. A previous EC model had three circuit elements: resistance as a function of the layer current, inductances related to the circumferential and axial fields. The new EC model has only inductances, and resistance is eliminated. In both models, AC loss of the coated conductor in each layer of an HTS cable is calculated on the basis of the Norris equation for a thin strip. The differences between measurement and calculations using the previous and new models are 12% and 14%, respectively, when transporting 1 kArms, which indicates that the new model is applicable for the calculation of AC loss in an HTS cable. These results indicate that layer current is dependent on inductances and not on resistance. The elimination of resistance simplifies AC loss calculation because it does not require repeated calculations for the convergence of the layer current. The calculation time was 1/20th of that of the previous model. In the new model, the Norris equation can be replaced with the calculation result obtained by the two-dimensional finite element method to obtain more accurate AC loss.

  16. Fermi-surface reconstruction and the origin of high-temperature superconductivity.

    SciTech Connect

    Norman, M. R.; Materials Science Division

    2010-01-01

    lattice into a d{sup 9} configuration, with one localized hole in the 3d shell per copper site. Given the localized nature of this state, it was questioned whether a momentum-space picture was an appropriate description of the physics of the cuprates. In fact, this question relates to a long-standing debate in the physics community: Since the parent state is also an antiferromagnet, one can, in principle, map the Mott insulator to a band insulator with magnetic order. In this 'Slater' picture, Mott physics is less relevant than the magnetism itself. It is therefore unclear which of the two, magnetism or Mott physics, is more fundamentally tied to superconductivity in the cuprates. After twenty years of effort, definitive quantum oscillations that could be used to map the Fermi surface were finally observed in a high-temperature cuprate superconductor in 2007. This and subsequent studies reveal a profound rearrangement of the Fermi surface in underdoped cuprates. The cause of the reconstruction, and its implication for the origin of high-temperature superconductivity, is a subject of active debate.

  17. Method and apparatus for connecting high voltage leads to a high temperature super-conducting transformer

    DOEpatents

    Golner, Thomas M.; Mehta, Shirish P.

    2005-07-26

    A method and apparatus for connecting high voltage leads to a super-conducting transformer is provided that includes a first super-conducting coil set, a second super-conducting coil set, and a third super-conducting coil set. The first, second and third super-conducting coil sets are connected via an insulated interconnect system that includes insulated conductors and insulated connectors that are utilized to connect the first, second, and third super-conducting coil sets to the high voltage leads.

  18. Magnetic and levitation characteristics of bulk high-temperature superconducting magnets above a permanent magnet guideway

    NASA Astrophysics Data System (ADS)

    Zheng, Jun; Zheng, Botian; He, Dabo; Sun, Ruixue; Deng, Zigang; Xu, Xun; Dou, Shixue

    2016-09-01

    Due to the large levitation force or the large guidance force of bulk high-temperature superconducting magnets (BHTSMs) above a permanent magnet guideway (PMG), it is reasonable to employ pre-magnetized BHTSMs to replace applied-magnetic-field-cooled superconductors in a maglev system. There are two combination modes between the BHTSM and the PMG, distinguished by the different directions of the magnetization. One is the S-S pole mode, and the other is the S-N pole mode combined with a unimodal PMG segment. A multi-point magnetic field measurement platform was employed to acquire the magnetic field signals of the BHTSM surface in real time during the pre-magnetization process and the re-magnetization process. Subsequently, three experimental aspects of levitation, including the vertical movement due to the levitation force, the lateral movement due to the guidance force, and the force relaxation with time, were explored above the PMG segment. Moreover, finite element modeling by COMSOL Multiphysics has been performed to simulate the different induced currents and the potentially different temperature rises with different modes inside the BHTSM. It was found that the S-S pole mode produced higher induced current density and a higher temperature rise inside the BHTSM, which might escalate its lateral instability above the PMG. The S-N pole mode exhibits the opposite characteristics. In general, this work is instructive for understanding and connecting the magnetic flux, the inner current density, the levitation behavior, and the temperature rise of BHTSMs employed in a maglev system.

  19. High-Temperature, Thin-Film Strain Gages Improved

    NASA Technical Reports Server (NTRS)

    2005-01-01

    Conventional resistance strain gage technology uses "bonded" strain gages. These foil or wire gages are bonded onto the surface of the test article with glue, ceramic cements, or flame-sprayed ceramics. These bonding agents can, in some instances, limit both the degree of strain transmission from the test structure to the gage and the maximum working temperature of the gage. Also, the bulky, bonded gage normally disrupts aerodynamic gas flow on the surface of the test structure because of its intrusive character. To respond to the urgent needs in aeronautic and aerospace research where stress and temperature gradients are high, aerodynamic effects need to be minimized, and higher operational temperatures are required, the NASA Lewis Research Center developed a thin film strain gage. This gage, a vacuum-deposited thin film formed directly on the surface of a test structure, operates at much higher temperatures than commercially available gages do and with minimal disruption of the aerodynamic flow. The gage uses an alloy, palladium-13 wt % chromium (hereafter, PdCr), which was developed by United Technologies Research Center under a NASA contract. PdCr is structurally stable and oxidation resistant up to at least 1100 C (2000 F); its temperature-induced resistance change is linear, repeatable, and not sensitive to the rates of heating and cooling. An early strain gage, which was made of 25-micrometer-diameter PdCr wire and demonstrated to be useable to 800 C, won an R&D 100 award in 1991. By further improving the purity of the material and by developing gage fabrication techniques that use sputter-deposition, photolithography patterning, and chemical etching, we have made an 8- to 10-m PdCr thin-film strain gage that can measure dynamic and static strain to at least 1100 C. For static strain measurements, a 5-m-thick Pt element serves as a temperature compensator to further minimize the temperature effect of the gage. These thin-film gages provide the advantage of

  20. High temperature polymer dielectric film-wire insulation

    NASA Technical Reports Server (NTRS)

    Nairus, John G.

    1994-01-01

    The highlights of the program are outlined including two major accomplishments. TRW identified and demonstrated the potential of two aromatic/heterocyclic polymers to have an outstanding and superior combination of electrical, thermal, and chemical resistance properties versus state-of-the-art Kapton for spacecraft and/or aircraft dielectric insulation applications. (Supporting data is provided in tables.) Feasibility was demonstrated for supporting/enabling technologies such as ceramic coatings, continuous film casting, and conductor wire wrapping, which are designed to accelerate qualification and deployment of the new wire insulation materials for USAF systems applications during the mid- to late-1990's.

  1. Techniques for Connecting Superconducting Thin Films

    NASA Technical Reports Server (NTRS)

    Mester, John; Gwo, Dz-Hung

    2006-01-01

    Several improved techniques for connecting superconducting thin films on substrates have been developed. The techniques afford some versatility for tailoring the electronic and mechanical characteristics of junctions between superconductors in experimental electronic devices. The techniques are particularly useful for making superconducting or alternatively normally conductive junctions (e.g., Josephson junctions) between patterned superconducting thin films in order to exploit electron quantum-tunneling effects. The techniques are applicable to both low-Tc and high-Tc superconductors (where Tc represents the superconducting- transition temperature of a given material), offering different advantages for each. Most low-Tc superconductors are metallic, and heretofore, connections among them have been made by spot welding. Most high-Tc superconductors are nonmetallic and cannot be spot welded. These techniques offer alternatives to spot welding of most low-Tc superconductors and additional solutions to problems of connecting most high-Tc superconductors.

  2. High temperature Hall measurement setup for thin film characterization

    NASA Astrophysics Data System (ADS)

    Adnane, L.; Gokirmak, A.; Silva, H.

    2016-07-01

    Hall measurement using the van der Pauw technique is a common characterization approach that does not require patterning of contacts. Measurements of the Hall voltage and electrical resistivity lead to the product of carrier mobility and carrier concentration (Hall coefficient) which can be decoupled through transport models. Based on the van der Paw method, we have developed an automated setup for Hall measurements from room temperature to ˜500 °C of semiconducting thin films of a wide resistivity range. The resistivity of the film and Hall coefficient is obtained from multiple current-voltage (I-V) measurements performed using a semiconductor parameter analyzer under applied constant "up," zero, and "down" magnetic field generated with two neodymium permanent magnets. The use of slopes obtained from multiple I-Vs for the three magnetic field conditions offer improved accuracy. Samples are preferred in square shape geometry and can range from 2 mm to 25 mm side length. Example measurements of single-crystal silicon with known doping concentration show the accuracy and reliability of the measurement.

  3. High temperature Hall measurement setup for thin film characterization.

    PubMed

    Adnane, L; Gokirmak, A; Silva, H

    2016-07-01

    Hall measurement using the van der Pauw technique is a common characterization approach that does not require patterning of contacts. Measurements of the Hall voltage and electrical resistivity lead to the product of carrier mobility and carrier concentration (Hall coefficient) which can be decoupled through transport models. Based on the van der Paw method, we have developed an automated setup for Hall measurements from room temperature to ∼500 °C of semiconducting thin films of a wide resistivity range. The resistivity of the film and Hall coefficient is obtained from multiple current-voltage (I-V) measurements performed using a semiconductor parameter analyzer under applied constant "up," zero, and "down" magnetic field generated with two neodymium permanent magnets. The use of slopes obtained from multiple I-Vs for the three magnetic field conditions offer improved accuracy. Samples are preferred in square shape geometry and can range from 2 mm to 25 mm side length. Example measurements of single-crystal silicon with known doping concentration show the accuracy and reliability of the measurement. PMID:27475605

  4. Optimization of Multilayer Laminated Film and Absorbent of Vacuum Insulation Panel for Use at High Temperature

    NASA Astrophysics Data System (ADS)

    Araki, Kuninari; Echigoya, Wataru; Tsuruga, Toshimitsu; Kamoto, Daigorou; Matsuoka, Shin-Ichi

    For the energy saving regulation and larger capacity, Vacuum Insulation Panel (VIP) has been used in refrigerators with urethane foam in recent years. VIP for low temperature is constructed by laminated plastic film, using heat welding of each neighboring part for keeping vacuum, so that the performance decrement is very large under high temperature. But recently high efficiency insulation material is desired for high temperature water holding devices (automatic vending machine, heat pump water heater, electric hot-water pot water, etc.), and we especially focused on cost and ability of the laminated plastic film and absorbent for high temperature VIP. We measured the heatproof temperature of plastic films and checked the amount of water vapor and out coming gas on temperature-programmed adsorption in absorbent. These results suggest the suitable laminated film and absorbent system for VIP use at high temperature, and the long-term reliability was evaluated by measuring thermal conductivity of high temperature. As a result it was found that high-retort pouch of CPP (cast polypropylene film) and adding of aluminum coating are the most suitable materials for use in the welded layers of high-temperature VIPs (105°C).

  5. Silicon carbide thin films for high temperature microelectromechanical systems

    NASA Astrophysics Data System (ADS)

    Fleischman, Aaron Judah

    Silicon Carbide (SiC) was studied for use as a material in microelectromechanical systems (MEMS). An APCVD reactor was built to deposit SiC on 100-mm diameter substrates. 3C-SiC films were grown heteroepitaxially atop 100-mm Si wafers. SiC was deposited atop suitable sacrificial layers of polysilicon and thermal oxide. The reactor gas flow was modeled using finite element techniques. The gas flow formed a recirculating pattern, with fresh reactant gases injected at the top of the reactor, traveling down the inside sidewalls and introduced at the bottom of the wafer, forming a plume of heated gases rising to the top of the reactor. This recirculation pattern explains the gradually decreasing growth rate from the wafer's bottom to its top as reactant gases are gradually depleted as they rise. Intentional doping of 3C-SiC films was studied, using diborane and phosphine dopant sources. SIMS indicated that B and P could be incorporated into 3C-SiC films, however B doped films were electrically compensated due to trace amounts of nitrogen in the diborane. Boron concentrations above 3C-SiC's solid solubility caused the SiC to become polycrystalline. Phosphorus incorporation was less predictable and did not vary linearly with phosphine flow rates. A reactive ion etch (REE) process was developed to etch 3C-SiC. Addition of He to the plasma chemistry enhanced the etch rates and etch anisotropy of the 3C-SiC. The etch recipe also produced similar results for polycrystalline SiC on polysilicon and thermal oxide. A maximum SiC etch rate of 1,267 A/min with a selectivity of 1.4 to Si was obtained. Using the above methods, SiC resonant devices were fabricated using polysilicon and thermal oxide as sacrificial layers. Polysilicon resonant devices were fabricated for comparison. The devices were tested by measuring their resonant frequency at room and elevated temperatures to 900°C to determine Young's modulus and its temperature dependence. All devices showed resonant frequency

  6. Advanced high temperature superconductor film-based process using RABiTS

    SciTech Connect

    Goyal, A.; Hawsey, R.A.; Hack, J.; Moon, D.

    2000-01-01

    The purpose of this Cooperative Research and Development Agreement (CRADA) between Lockheed Martin Energy Research Corporation (Contractor), Managing contractor for Oak Ridge National Laboratory (ORNL) and Midwest Superconductivity, Inc. (MSI) and Westinghouse Science and Electric Company (WEC) was to develop the basis for a commercial process for the manufacturing of superconducting tape based on the RABiTS technology developed at ORNL. The chosen method for deposition of YBCO films on RABiTS was Metal Organic chemical Vapor Deposition (MOCVD).

  7. Quantitative non-destructive evaluation of high-temperature superconducting materials. Technical progress report, September 1, 1989--August 30, 1990

    SciTech Connect

    Achenbach, J.D.

    1990-09-15

    Even though the currently intensive research efforts on high-temperature superconducting materials have not yet converged on a well specified material, the strong indications are that such a material will be brittle, anisotropic, and may contain many flaws such as microcracks and voids at grain boundaries. Consequently, practical applications of high temperature superconducting materials will require a very careful strength analysis based on fracture mechanics considerations. Because of the high sensitivity of the strength of such materials to the presence of defects, methods of quantitative non-destructive evaluation may be expected to play an important role in strength determinations. This proposal is concerned with the use of ultrasonic methods to detect and characterize isolated cracks, clusters of microcracks and microcracks distributed throughout the material. Particular attention will be devoted to relating ultrasonic results directly to deterministic and statistical linear elastic fracture mechanics considerations.

  8. A visualization instrument to investigate the mechanical-electro properties of high temperature superconducting tapes under multi-fields

    NASA Astrophysics Data System (ADS)

    Liu, Wei; Zhang, Xingyi; Liu, Cong; Zhang, Wentao; Zhou, Jun; Zhou, YouHe

    2016-07-01

    We construct a visible instrument to study the mechanical-electro behaviors of high temperature superconducting tape as a function of magnetic field, strain, and temperature. This apparatus is directly cooled by a commercial Gifford-McMahon cryocooler. The minimum temperature of sample can be 8.75 K. A proportion integration differentiation temperature control is used, which is capable of producing continuous variation of specimen temperature from 8.75 K to 300 K with an optional temperature sweep rate. We use an external loading device to stretch the superconducting tape quasi-statically with the maximum tension strain of 20%. A superconducting magnet manufactured by the NbTi strand is applied to provide magnetic field up to 5 T with a homogeneous range of 110 mm. The maximum fluctuation of the magnetic field is less than 1%. We design a kind of superconducting lead composed of YBa2Cu3O7-x coated conductor and beryllium copper alloy (BeCu) to transfer DC to the superconducting sample with the maximum value of 600 A. Most notably, this apparatus allows in situ observation of the electromagnetic property of superconducting tape using the classical magnetic-optical imaging.

  9. A visualization instrument to investigate the mechanical-electro properties of high temperature superconducting tapes under multi-fields.

    PubMed

    Liu, Wei; Zhang, Xingyi; Liu, Cong; Zhang, Wentao; Zhou, Jun; Zhou, YouHe

    2016-07-01

    We construct a visible instrument to study the mechanical-electro behaviors of high temperature superconducting tape as a function of magnetic field, strain, and temperature. This apparatus is directly cooled by a commercial Gifford-McMahon cryocooler. The minimum temperature of sample can be 8.75 K. A proportion integration differentiation temperature control is used, which is capable of producing continuous variation of specimen temperature from 8.75 K to 300 K with an optional temperature sweep rate. We use an external loading device to stretch the superconducting tape quasi-statically with the maximum tension strain of 20%. A superconducting magnet manufactured by the NbTi strand is applied to provide magnetic field up to 5 T with a homogeneous range of 110 mm. The maximum fluctuation of the magnetic field is less than 1%. We design a kind of superconducting lead composed of YBa2Cu3O7-x coated conductor and beryllium copper alloy (BeCu) to transfer DC to the superconducting sample with the maximum value of 600 A. Most notably, this apparatus allows in situ observation of the electromagnetic property of superconducting tape using the classical magnetic-optical imaging.

  10. A visualization instrument to investigate the mechanical-electro properties of high temperature superconducting tapes under multi-fields.

    PubMed

    Liu, Wei; Zhang, Xingyi; Liu, Cong; Zhang, Wentao; Zhou, Jun; Zhou, YouHe

    2016-07-01

    We construct a visible instrument to study the mechanical-electro behaviors of high temperature superconducting tape as a function of magnetic field, strain, and temperature. This apparatus is directly cooled by a commercial Gifford-McMahon cryocooler. The minimum temperature of sample can be 8.75 K. A proportion integration differentiation temperature control is used, which is capable of producing continuous variation of specimen temperature from 8.75 K to 300 K with an optional temperature sweep rate. We use an external loading device to stretch the superconducting tape quasi-statically with the maximum tension strain of 20%. A superconducting magnet manufactured by the NbTi strand is applied to provide magnetic field up to 5 T with a homogeneous range of 110 mm. The maximum fluctuation of the magnetic field is less than 1%. We design a kind of superconducting lead composed of YBa2Cu3O7-x coated conductor and beryllium copper alloy (BeCu) to transfer DC to the superconducting sample with the maximum value of 600 A. Most notably, this apparatus allows in situ observation of the electromagnetic property of superconducting tape using the classical magnetic-optical imaging. PMID:27475594

  11. CaFeAs2: A staggered intercalation of quantum spin Hall and high-temperature superconductivity

    NASA Astrophysics Data System (ADS)

    Wu, Xianxin; Qin, Shengshan; Liang, Yi; Le, Congcong; Fan, Heng; Hu, Jiangping

    2015-02-01

    We predict that CaFeAs2, a newly discovered iron-based high-temperature (Tc) superconductor, is a staggered intercalation compound that integrates topological quantum spin Hall (QSH) and superconductivity (SC). CaFeAs2 has a structure with staggered CaAs and FeAs layers. While the FeAs layers are known to be responsible for high Tc superconductivity, we show that with spin orbital coupling each CaAs layer is a Z2 topologically nontrivial two-dimensional QSH insulator and the bulk is a three-dimensional weak topological insulator. In the superconducting state, the edge states in the CaAs layer are natural one-dimensional topological superconductors. The staggered intercalation of QSH and SC provides us a unique opportunity to realize and explore physics, such as Majorana modes and Majorana fermion chains.

  12. The design and fabrication of a reverse Brayton cycle cryocooler system for the high temperature superconductivity cable cooling

    NASA Astrophysics Data System (ADS)

    Park, Jae Hong; Kwon, Yong Ha; Kim, Young Soo

    2005-01-01

    A high temperature superconductivity cable must be cooled below the nitrogen liquefaction temperature to apply the cable to power generation and transmission systems under superconducting state. To maintain the superconducting state, a reliable cryocooler system is also required. The design and fabrication of a cryocooler system have been performed with a reverse Brayton cycle using neon gas as a refrigerant. The system consists of a compressor, a recuperator, a cold-box, and control valves. The design of the system is made to have 1 kW cooling capacity. The heat loss through multilayer insulators is calculated. Conduction heat loss is about 7 W through valves and access ports and radiation heat loss is about 18 W on the surface of a cryocooler. The design factors are discussed in detail.

  13. Local structural studies of oriented high-temperature superconducting cuprates by polarized XAFS spectroscopy

    NASA Astrophysics Data System (ADS)

    Haskel, Daniel

    1998-07-01

    Doping (Sr,Ba) in Lasb{2-x}(Sr,Ba)sb{x}CuOsb4 induces high Tsb{c} superconductivity in addition to profound changes in structural, magnetic and normal state electronic properties. The purpose of this thesis is to investigate the structural characteristics accompanying this doping by performing orientation dependent x-ray absorption fine structure (XAFS) measurements on magnetically aligned powders. This type of measurements allowed obtaining critical information at the La/(Sr,Ba) site previously unavailable, as detailed below. The measurements show that hole carriers introduced with Sr are polaronic in nature as evident from the two site configuration found for the O(2) apical neighboring Sr and the lack of temperature dependence in the O(2) distribution, which indicates that the hole states associated with each site are not discrete but rather broader than ksb{B}T up to T = 300K. There is a good theoretical argument suggesting each O(2) site is associated with holes being doped into O(1) 2psb{x,y}-Cu 3dsb{xsp2-ysp2} in-plane and O(2) 2psb{z}-Cu 3dsb{3zsp2-rsp2} out-of-plane electronic bands resulting in two different Jahn-Teller distortions of the CuOsb6 octahedra neighboring Sr, where the doped holes are peaked. Based on this argument, the predominance of out-of-plane character for the doped holes, as evidenced from the concentration dependence of the relative population of O(2) sites, would imply that theories of high Tsb{c} relying only on in-plane character of the doped holes are not complete in describing the properties of these cuprates. Our measurements showed that all structural phase transitions in Lasb{2-x}(Sr,Ba)sb{x}CuOsb4 have a significant order-disorder component, as opposed to the purely displacive models found in crystallographic studies. The CuOsb6 octahedra are locally tilted in the high-doping, high-temperature phases but fail to order over long range resulting in the average structures of the crystallographic studies. A critical parameter in

  14. Structure, electrical characteristics, and high-temperature stability of aerosol jet printed silver nanoparticle films

    NASA Astrophysics Data System (ADS)

    Rahman, Md Taibur; McCloy, John; Ramana, C. V.; Panat, Rahul

    2016-08-01

    Printed electronics has emerged as a versatile eco-friendly fabrication technique to create sintered nanoparticle (NP) films on arbitrary surfaces with an excellent control over the film microstructure. While applicability of such films for high-temperature applications is not explored previously, herein we report the high-temperature electrical stability of silver (Ag) metal NP films fabricated using an Aerosol Jet based printing technique and demonstrate that this behavior is dictated by changes in the film microstructure. In-situ high temperature (24-500 °C) impedance spectroscopy measurements show that the real part of the impedance increases with increasing temperature up to 150 °C, at which point a decreasing trend prevails until 300 °C, followed again by an increase in impedance. The electrical behavior is correlated with the in-situ grain growth of the Ag NP films, as observed afterwards by scanning electron microscopy and X-ray diffraction (XRD), and could be tailored by controlling the initial microstructure through sintering conditions. Using combined diffraction and spectroscopic analytical methods, it is demonstrated the Aerosol Jet printed Ag NP films exhibit enhanced thermal stability and oxidation resistance. In addition to establishing the conditions for stability of Ag NP films, the results provide a fundamental understanding of the effect of grain growth and reduction in grain boundary area on the electrical stability of sintered NP films.

  15. Superconducting NbTiN thin films for superconducting radio frequency accelerator cavity applications

    DOE PAGES

    Burton, Matthew C.; Beebe, Melissa R.; Yang, Kaida; Lukaszew, Rosa A.; Valente-Feliciano, Anne -Marie; Reece, Charles

    2016-02-12

    Current superconducting radio frequency technology, used in various particle accelerator facilities across the world, is reliant upon bulk niobium superconducting cavities. Due to technological advancements in the processing of bulk Nb cavities, the facilities have reached accelerating fields very close to a material-dependent limit, which is close to 50 MV/m for bulk Nb. One possible solution to improve upon this fundamental limitation was proposed a few years ago by Gurevich [Appl. Phys. Lett. 88, 012511 (2006)], consisting of the deposition of alternating thin layers of superconducting and insulating materials on the interior surface of the cavities. The use of type-IImore » superconductors with Tc > TcNb and Hc > HcNb, (e.g., Nb3Sn, NbN, or NbTiN) could potentially greatly reduce the surface resistance (Rs) and enhance the accelerating field, if the onset of vortex penetration is increased above HcNb, thus enabling higher field gradients. Although Nb3Sn may prove superior, it is not clear that it can be grown as a suitable thin film for the proposed multilayer approach, since very high temperature is typically required for its growth, hindering achieving smooth interfaces and/or surfaces. On the other hand, since NbTiN has a smaller lower critical field (Hc1) and higher critical temperature (Tc) than Nb and increased conductivity compared to NbN, it is a promising candidate material for this new scheme. Here, the authors present experimental results correlating filmmicrostructure with superconducting properties on NbTiN thin film coupon samples while also comparing filmsgrown with targets of different stoichiometry. In conclusion, it is worth mentioning that the authors have achieved thin films with bulk-like lattice parameter and transition temperature while also achieving Hc1 values larger than bulk for films thinner than their London penetration depths.« less

  16. An experimental investigation of high temperature superconducting microstrip antennas at K- and Ka-band frequencies. Ph.D. Thesis Final Report

    NASA Technical Reports Server (NTRS)

    Richard, Mark A.

    1993-01-01

    The recent discovery of high temperature superconductors (HTS) has generated a substantial amount of interest in microstrip antenna applications. However, the high permittivity of substrates compatible with HTS results in narrow bandwidths and high patch edge impedances of such antennas. To investigate the performance of superconducting microstrip antennas, three antenna architectures at K and Ka-band frequencies are examined. Superconducting microstrip antennas that are directly coupled, gap coupled, and electromagnetically coupled to a microstrip transmission line were designed and fabricated on lanthanum aluminate substrates using YBa2Cu3O7 superconducting thin films. For each architecture, a single patch antenna and a four element array were fabricated. Measurements from these antennas, including input impedance, bandwidth, patterns, efficiency, and gain are presented. The measured results show usable antennas can be constructed using any of the architectures. All architectures show excellent gain characteristics, with less than 2 dB of total loss in the four element arrays. Although the direct and gap coupled antennas are the simplest antennas to design and fabricate, they suffer from narrow bandwidths. The electromagnetically coupled antenna, on the other hand, allows the flexibility of using a low permittivity substrate for the patch radiator, while using HTS for the feed network, thus increasing the bandwidth while effectively utilizing the low loss properties of HTS. Each antenna investigated in this research is the first of its kind reported.

  17. High-temperature superconductivity in Y-Ba-Cu-O: identification of a copper-rich superconducting phase

    SciTech Connect

    Stacy, A.M.; Badding, J.V.; Geselbracht, M.J.; Ham, W.K.; Holland, G.F.; Hoskins, R.L.; Keller, S.W.; Millikan, C.F.; zur Loye, H.C.

    1987-01-01

    For the past 15 years, advances in superconductivity have come about only slowly and even a 0.5 K increase in transition temperature was noteworthy. Until April 1986, the highest transition temperatures were near 23 K. At that time, Bednorz and Mueller reported superconductivity in La-Ba-Cu-O compounds above 30 K. The authors report here the composition and properties of a superconducting phase containing Y, Ba, Cu, and O which is copper-rich compared with Y/sub 1.2/Ba/sub 0.8/CuO/sub 4/. This phase show 10-20% Meissner effect, with T/sub 0/ = 90 K. Further the most exciting aspect of this phase is that it is near a low melting (below 1200 /sup 0/C) eutectic; if the phase metals congruently it will be possible to fashion wires.

  18. Amorphous molybdenum silicon superconducting thin films

    SciTech Connect

    Bosworth, D. Sahonta, S.-L.; Barber, Z. H.; Hadfield, R. H.

    2015-08-15

    Amorphous superconductors have become attractive candidate materials for superconducting nanowire single-photon detectors due to their ease of growth, homogeneity and competitive superconducting properties. To date the majority of devices have been fabricated using W{sub x}Si{sub 1−x}, though other amorphous superconductors such as molybdenum silicide (Mo{sub x}Si{sub 1−x}) offer increased transition temperature. This study focuses on the properties of MoSi thin films grown by magnetron sputtering. We examine how the composition and growth conditions affect film properties. For 100 nm film thickness, we report that the superconducting transition temperature (Tc) reaches a maximum of 7.6 K at a composition of Mo{sub 83}Si{sub 17}. The transition temperature and amorphous character can be improved by cooling of the substrate during growth which inhibits formation of a crystalline phase. X-ray diffraction and transmission electron microscopy studies confirm the absence of long range order. We observe that for a range of 6 common substrates (silicon, thermally oxidized silicon, R- and C-plane sapphire, x-plane lithium niobate and quartz), there is no variation in superconducting transition temperature, making MoSi an excellent candidate material for SNSPDs.

  19. Amorphous molybdenum silicon superconducting thin films

    NASA Astrophysics Data System (ADS)

    Bosworth, D.; Sahonta, S.-L.; Hadfield, R. H.; Barber, Z. H.

    2015-08-01

    Amorphous superconductors have become attractive candidate materials for superconducting nanowire single-photon detectors due to their ease of growth, homogeneity and competitive superconducting properties. To date the majority of devices have been fabricated using WxSi1-x, though other amorphous superconductors such as molybdenum silicide (MoxSi1-x) offer increased transition temperature. This study focuses on the properties of MoSi thin films grown by magnetron sputtering. We examine how the composition and growth conditions affect film properties. For 100 nm film thickness, we report that the superconducting transition temperature (Tc) reaches a maximum of 7.6 K at a composition of Mo83Si17. The transition temperature and amorphous character can be improved by cooling of the substrate during growth which inhibits formation of a crystalline phase. X-ray diffraction and transmission electron microscopy studies confirm the absence of long range order. We observe that for a range of 6 common substrates (silicon, thermally oxidized silicon, R- and C-plane sapphire, x-plane lithium niobate and quartz), there is no variation in superconducting transition temperature, making MoSi an excellent candidate material for SNSPDs.

  20. Force-free coil principles applied to high-temperature superconducting materials

    SciTech Connect

    Furth, H.P.; Jardin, S.C.; Montgomery, D.B.

    1987-11-01

    Force-free magnetic-field configurations, where the current flows parallel to the magnetic field vector, have the potential to raise the critical magnetic field and current-density limits for high-temperature superconductors. 10 refs., 3 figs.

  1. Magnetic levitation using high temperature superconducting pancake coils as composite bulk cylinders

    NASA Astrophysics Data System (ADS)

    Patel, A.; Hopkins, S. C.; Baskys, A.; Kalitka, V.; Molodyk, A.; Glowacki, B. A.

    2015-11-01

    Stacks of superconducting tape can be used as composite bulk superconductors for both trapped field magnets and for magnetic levitation. Little previous work has been done on quantifying the levitation force behavior between stacks of tape and permanent magnets. This paper reports the axial levitation force properties of superconducting tape wound into pancake coils to act as a composite bulk cylinder, showing that similar stable forces to those expected from a uniform bulk cylinder are possible. Force creep was also measured and simulated for the system. The geometry tested is a possible candidate for a rotary superconducting bearing. Detailed finite element modeling in COMSOL Multiphysics was also performed including a full critical state model for induced currents, with temperature and field dependent properties and 3D levitation force models. This work represents one of the most complete levitation force modeling frameworks yet reported using the H-formulation and helps explain why the coil-like stacks of tape are able to sustain levitation forces. The flexibility of geometry and consistency of superconducting properties offered by stacks of tapes, make them attractive for superconducting levitation applications.

  2. High-temperature interface superconductivity between metallic and insulating copper oxides.

    PubMed

    Gozar, A; Logvenov, G; Kourkoutis, L Fitting; Bollinger, A T; Giannuzzi, L A; Muller, D A; Bozovic, I

    2008-10-01

    The realization of high-transition-temperature (high-T(c)) superconductivity confined to nanometre-sized interfaces has been a long-standing goal because of potential applications and the opportunity to study quantum phenomena in reduced dimensions. This has been, however, a challenging target: in conventional metals, the high electron density restricts interface effects (such as carrier depletion or accumulation) to a region much narrower than the coherence length, which is the scale necessary for superconductivity to occur. By contrast, in copper oxides the carrier density is low whereas T(c) is high and the coherence length very short, which provides an opportunity-but at a price: the interface must be atomically perfect. Here we report superconductivity in bilayers consisting of an insulator (La(2)CuO(4)) and a metal (La(1.55)Sr(0.45)CuO(4)), neither of which is superconducting in isolation. In these bilayers, T(c) is either approximately 15 K or approximately 30 K, depending on the layering sequence. This highly robust phenomenon is confined within 2-3 nm of the interface. If such a bilayer is exposed to ozone, T(c) exceeds 50 K, and this enhanced superconductivity is also shown to originate from an interface layer about 1-2 unit cells thick. Enhancement of T(c) in bilayer systems was observed previously but the essential role of the interface was not recognized at the time. PMID:18843365

  3. High-temperature interface superconductivity between metallic and insulating copper oxides.

    PubMed

    Gozar, A; Logvenov, G; Kourkoutis, L Fitting; Bollinger, A T; Giannuzzi, L A; Muller, D A; Bozovic, I

    2008-10-01

    The realization of high-transition-temperature (high-T(c)) superconductivity confined to nanometre-sized interfaces has been a long-standing goal because of potential applications and the opportunity to study quantum phenomena in reduced dimensions. This has been, however, a challenging target: in conventional metals, the high electron density restricts interface effects (such as carrier depletion or accumulation) to a region much narrower than the coherence length, which is the scale necessary for superconductivity to occur. By contrast, in copper oxides the carrier density is low whereas T(c) is high and the coherence length very short, which provides an opportunity-but at a price: the interface must be atomically perfect. Here we report superconductivity in bilayers consisting of an insulator (La(2)CuO(4)) and a metal (La(1.55)Sr(0.45)CuO(4)), neither of which is superconducting in isolation. In these bilayers, T(c) is either approximately 15 K or approximately 30 K, depending on the layering sequence. This highly robust phenomenon is confined within 2-3 nm of the interface. If such a bilayer is exposed to ozone, T(c) exceeds 50 K, and this enhanced superconductivity is also shown to originate from an interface layer about 1-2 unit cells thick. Enhancement of T(c) in bilayer systems was observed previously but the essential role of the interface was not recognized at the time.

  4. A Mobile and Space-saving High-temperature Superconducting Multichannel Magnetocardiograph in a Vertical Magnetically Shielded Cylinder

    NASA Astrophysics Data System (ADS)

    Suzuki, Daisuke; Tsukamoto, Akira; Yokosawa, Koichi; Kandori, Akihiko; Ogata, Kuniomi; Tsukada, Keiji

    2004-01-01

    A high-temperature superconducting (HTS) magnetocardiographic system composed of 16-channels HTS-Superconducting Quantum Interference Device (SQUID) magnetometers and a vertical magnetically shielded cylinder has been developed. The cylinder is designed to save space and provide mobility for the entire system, including the magnetically shielded cylinder. It consists of two fixed semicircular shells and a sliding semicircular door, all of which are made from sheets of a flexible nanocrystalline soft-magnetic material. The cardiomagnetic field from a subject seated in the vertical magnetically shielded cylinder is measured by multichannel HTS-SQUID magnetometers that are sensitive to field strengths weaker than 100 fT/(Hz)1/2. The high signal-to-noise ratio of the magnetometer signals makes beat-to-beat measurement of the cardiomagnetic field possible. This HTS-based multichannel MCG system is being applied to medical applications such as the detection of arrhythmias and ischemic heart disease.

  5. SSTAC/ARTS review of the draft Integrated Technology Plan (ITP). Volume 8: Aerothermodynamics Automation and Robotics (A/R) systems sensors, high-temperature superconductivity

    NASA Technical Reports Server (NTRS)

    1991-01-01

    Viewgraphs of briefings presented at the SSTAC/ARTS review of the draft Integrated Technology Plan (ITP) on aerothermodynamics, automation and robotics systems, sensors, and high-temperature superconductivity are included. Topics covered include: aerothermodynamics; aerobraking; aeroassist flight experiment; entry technology for probes and penetrators; automation and robotics; artificial intelligence; NASA telerobotics program; planetary rover program; science sensor technology; direct detector; submillimeter sensors; laser sensors; passive microwave sensing; active microwave sensing; sensor electronics; sensor optics; coolers and cryogenics; and high temperature superconductivity.

  6. Electrochemical Na-intercalation-induced high-temperature superconductivity in FeSe

    NASA Astrophysics Data System (ADS)

    Kajita, Tetsuya; Kawamata, Takayuki; Noji, Takashi; Hatakeda, Takehiro; Kato, Masatsune; Koike, Yoji; Itoh, Takashi

    2015-12-01

    Iron-chalcogenide-based superconductors have attracted much attention due to their relatively high superconducting transition temperatures (Tc) and their simple layered crystal structures. We have performed electrochemical co-intercalation of Na and propylene carbonate (PC) into FeSe, and successfully synthesized a new superconductor, Nax(PC)yFe2Se2, with Tc = 43 K. The type and amount of intercalated metal, and the electrolyte used in the intercalation affected the superconductivity. Our electrochemical intercalation method should be a useful tool for discovering new superconductors by controlling the intercalation conditions.

  7. Crystallization and high temperature functional properties in CoFeB films

    NASA Astrophysics Data System (ADS)

    Wang, Ke; Huang, Ya; Xu, Zhan; Hu, Yiyang; Dong, Shuo

    2016-05-01

    CoFeB alloy films have been attracting much research interest for the applications in magnetoelectronic devices. In this study, crystallization and high temperature functional properties in the sputtered CoFeB alloy films were investigated. The as-deposited alloy films were amorphous and a nanocrystalline structure was formed after annealing, confirmed by X-ray measurements. Large variation in saturation magnetization with temperature was observed in thermomagnetic measurements, reflecting the interplay between crystallization and temperature dependent magnetization in the ferromagnetic alloy film. Pronounced changes in electrical resistivity and optical reflectance with temperature were observed in the alloy film, in accompany with the structural change. The activation barrier for crystallization was determined to be 1.32 eV from the electrical measurements, showing a good thermal stability of the alloy film.

  8. Experimental setup for precise measurement of losses in high-temperature superconducting transformer

    NASA Astrophysics Data System (ADS)

    Janu, Z.; Wild, J.; Repa, P.; Jelinek, Z.; Zizek, F.; Peksa, L.; Soukup, F.; Tichy, R.

    2006-10-01

    A simple cryogenic system for testing of the superconducting power transformer was constructed. Thermal shielding is provided by additional liquid nitrogen bath instead of super-insulation. The system, together with use of a precise nitrogen liquid level meter, permitted calorimetric measurements of losses of the 8 kVA HTS transformer with a resolution of the order of 0.1 W.

  9. Preparation and Analysis of Platinum Thin Films for High Temperature Sensor Applications

    NASA Technical Reports Server (NTRS)

    Wrbanek, John D.; Laster, Kimala L. H.

    2005-01-01

    A study has been made of platinum thin films for application as high temperature resistive sensors. To support NASA Glenn Research Center s high temperature thin film sensor effort, a magnetron sputtering system was installed recently in the GRC Microsystems Fabrication Clean Room Facility. Several samples of platinum films were prepared using various system parameters to establish run conditions. These films were characterized with the intended application of being used as resistive sensing elements, either for temperature or strain measurement. The resistances of several patterned sensors were monitored to document the effect of changes in parameters of deposition and annealing. The parameters were optimized for uniformity and intrinsic strain. The evaporation of platinum via oxidation during annealing over 900 C was documented, and a model for the process developed. The film adhesion was explored on films annealed to 1000 C with various bondcoats on fused quartz and alumina. From this compiled data, a list of optimal parameters and characteristics determined for patterned platinum thin films is given.

  10. High temperature performance of sputter-deposited piezoelectric aluminum nitride thin films

    NASA Astrophysics Data System (ADS)

    Gillinger, M.; Schneider, M.; Bittner, A.; Nicolay, P.; Schmid, U.

    2015-05-01

    Aluminum nitride (AlN) is a promising material for sensor applications in harsh environments such as turbine exhausts or thermal power plants due to its piezoelectric properties, good thermal match to silicon and high temperature stability. Typically, the usage of piezoelectric materials in high temperature is limited by the Curie-temperature, the increase of the leakage current as well as by enhanced diffusion effects in the materials. In order to exploit the high temperature potential of AlN thin films, post deposition annealing experiments up to 1000°C in both oxygen and nitrogen gas atmospheres for 2 h were performed. X-ray diffraction measurements indicate that the thin films are chemically stable in a pure oxygen atmosphere for 2 h at annealing temperatures of up to 900°C. After a 2 h annealing step at 1000°C in pure oxygen. However, a 100 nm thin AlN film is completely oxidized. In contrast, the layer is stable up to 1000°C in pure nitrogen atmosphere. The surface topology changes significantly at annealing temperatures above 800°C independent of annealing atmosphere. The surface roughness is increased by about one order of magnitude compared to the "as deposited" state. This is predominantly attributed to recrystallization processes occurring during high temperature loading. Up to an annealing temperature of 700°C, a Poole-Frenkel conduction mechanism dominates the leakage current characteristics. Above, a mixture of different leakage current mechanisms is observed.

  11. Electrodynamic stabilization conditions for high-temperature superconducting composites with different types of current-voltage characteristic nonlinearity

    NASA Astrophysics Data System (ADS)

    Arkharov, A. M.; Lavrov, N. A.; Romanovskii, V. R.

    2014-06-01

    The current instability is studied in high-temperature superconducting current-carrying elements with I- V characteristics described by power or exponential equations. Stability analysis of the macroscopic states is carried out in terms of a stationary zero-dimensional model. In linear temperature approximation criteria are derived that allow one to find the maximum allowable values of the induced current, induced electric field intensity, and overheating of the superconductor. A condition is formulated for the complete thermal stabilization of the superconducting composite with regard to the nonlinearity of its I- V characteristic. It is shown that both subcritical and supercritical stable states may arise. In the latter case, the current and electric field intensity are higher than the preset critical parameters of the superconductor. Conditions for these states depending on the properties of the matrix, superconductor's critical current, fill factor, and nonlinearity of the I- V characteristic are discussed. The obtained results considerably augment the class of allowable states for high-temperature superconductors: it is demonstrated that there exist stable resistive conditions from which superconductors cannot pass to the normal state even if the parameters of these conditions are supercritical.

  12. SO(5) as a critical dynamical symmetry in the SU(4) model of high-temperature superconductivity

    NASA Astrophysics Data System (ADS)

    Wu, Lian-Ao; Guidry, Mike; Sun, Yang; Wu, Cheng-Li

    2003-01-01

    An SU(4) model of high-temperature superconductivity and antiferromagnetism has recently been proposed. The SO(5) group employed by Zhang [Science 275, 1089 (1997)] is embedded in this SU(4) as a subgroup, suggesting a connection between our SU(4) model and the Zhang SO(5) model. In order to understand the relationship between the the two models, we have used generalized coherent states to analyze the nature of the SO(5) subgroup. By constructing coherent-state energy surfaces, we demonstrate explicitly that the SU(4)⊃SO(5) symmetry can be interpreted as a critical dynamical symmetry interpolating between superconducting and antiferromagnetic phases, and that this critical dynamical symmetry has many similarities to critical dynamical symmetries identified previously in other fields of physics. More generally, we demonstrate with this example that the mathematical techniques associated with generalized coherent states may have powerful applications in condensed-matter physics because they provide a clear connection between microscopic many-body theories and their broken-symmetry approximate solutions. In addition, these methods may be interpreted as defining the most general Bogoliubov transformation subject to a Lie group symmetry constraint, thus providing a mathematical connection between algebraic formulations and the language of quasiparticle theory. Finally, we suggest that the identification of the SO(5) symmetry as a critical dynamical symmetry implies deep algebraic connections between high-temperature superconductors and seemingly unrelated phenomena in other field of physics.

  13. Characterization of Thick and Thin Film SiCN for Pressure Sensing at High Temperatures

    PubMed Central

    Leo, Alfin; Andronenko, Sergey; Stiharu, Ion; Bhat, Rama B.

    2010-01-01

    Pressure measurement in high temperature environments is important in many applications to provide valuable information for performance studies. Information on pressure patterns is highly desirable for improving performance, condition monitoring and accurate prediction of the remaining life of systems that operate in extremely high temperature environments, such as gas turbine engines. A number of technologies have been recently investigated, however these technologies target specific applications and they are limited by the maximum operating temperature. Thick and thin films of SiCN can withstand high temperatures. SiCN is a polymer-derived ceramic with liquid phase polymer as its starting material. This provides the advantage that it can be molded to any shape. CERASET™ also yields itself for photolithography, with the addition of photo initiator 2, 2-Dimethoxy-2-phenyl-acetophenone (DMPA), thereby enabling photolithographical patterning of the pre-ceramic polymer using UV lithography. SiCN fabrication includes thermosetting, crosslinking and pyrolysis. The technology is still under investigation for stability and improved performance. This work presents the preparation of SiCN films to be used as the body of a sensor for pressure measurements in high temperature environments. The sensor employs the phenomenon of drag effect. The pressure sensor consists of a slender sensitive element and a thick blocking element. The dimensions and thickness of the films depend on the intended application of the sensors. Fabrication methods of SiCN ceramics both as thin (about 40–60 μm) and thick (about 2–3 mm) films for high temperature applications are discussed. In addition, the influence of thermosetting and annealing processes on mechanical properties is investigated. PMID:22205871

  14. Electrodeposited Ag-Stabilization Layer for High Temperature Superconducting Coated Conductors: Preprint

    SciTech Connect

    Bhattacharya, R. N.; Mann, J.; Qiao, Y.; Zhang, Y.; Selvamanickam, V.

    2010-11-01

    We developed a non-aqueous based electrodepostion process of Ag-stabilization layer on YBCO superconductor tapes. The non-aqueous electroplating solution is non-reactive to the HTS layer thus does not detoriate the critical current capability of the superconductor layer when plated directly on the HTS tape. The superconducting current capabilities of these tapes were measured by non-contact magnetic measurements.

  15. High-temperature superconductivity from fine-tuning of Fermi-surface singularities in iron oxypnictides

    PubMed Central

    Charnukha, A.; Evtushinsky, D. V.; Matt, C. E.; Xu, N.; Shi, M.; Büchner, B.; Zhigadlo, N. D.; Batlogg, B.; Borisenko, S. V.

    2015-01-01

    In the family of the iron-based superconductors, the REFeAsO-type compounds (with RE being a rare-earth metal) exhibit the highest bulk superconducting transition temperatures (Tc) up to 55 K and thus hold the key to the elusive pairing mechanism. Recently, it has been demonstrated that the intrinsic electronic structure of SmFe0.92Co0.08AsO (Tc = 18 K) is highly nontrivial and consists of multiple band-edge singularities in close proximity to the Fermi level. However, it remains unclear whether these singularities are generic to the REFeAsO-type materials and if so, whether their exact topology is responsible for the aforementioned record Tc. In this work, we use angle-resolved photoemission spectroscopy (ARPES) to investigate the inherent electronic structure of the NdFeAsO0.6F0.4 compound with a twice higher Tc = 38 K. We find a similarly singular Fermi surface and further demonstrate that the dramatic enhancement of superconductivity in this compound correlates closely with the fine-tuning of one of the band-edge singularities to within a fraction of the superconducting energy gap Δ below the Fermi level. Our results provide compelling evidence that the band-structure singularities near the Fermi level in the iron-based superconductors must be explicitly accounted for in any attempt to understand the mechanism of superconducting pairing in these materials. PMID:26678565

  16. Effects of interlayer coupling on the magnetic and transport properties of superconducting multilayers and high-temperature superconductors

    SciTech Connect

    Gray, K.E.; Hettinger, J.D.; Kim, D.H.

    1994-06-01

    The effect of interlayer coupling on the transport properties and dissipation in a magnetic field is reviewed for superconducting multilayers including highly-anisotropic high-temperature superconductors (HTS). For the applied field parallel to the superconducting layers the absence of any Lorentz-force dependence of the dissipation leads to an explanation other than flux motion. This is consistent with a Josephson junction dissipation which dominates flux motion of the insulating regions between layers. However, in is seen to cross over from phase slips at Josephson junctions to depinning of vortices from the external field at high fields and temperatures. For fields perpendicular to the superconducting layers the much greater resistive broadening in HTS is due to dissipation by thermally-activated flux motion, consistent with a lack of intrinsic pinning. We show experimental evidence that the associated flux motion occurs as a result of a crossover from three dimensional (3D) vortex lines to 2D independent pancake-like vortices, residing in the Cu-O layers. This 3D to 2D crossover occurs after k{sub B}T exceeds the Josephson coupling energy.

  17. Performance of a High-Temperature Superconducting Resonator for High-Field Imaging

    NASA Astrophysics Data System (ADS)

    Black, R. D.; Early, T. A.; Johnson, G. A.

    The practicalities involved with the use of a superconducting microimaging probe are outlined so that the power and problems associated with this technology can be assessed. The nonlinearity of the transmission characteristics of this class of probe, the intrinsic limits on bandwidth, the long ring-down times, the potential for spin damping, and the difficulties of suppressing Johnson noise are all discussed. Recent refinements that have delivered a factor of 30 gain in SNR (signal-to-noise ratio) relative to copper coils at room temperature are presented. Further reductions in noise sources should yield a gain of a factor of 60 in SNR.

  18. High Temperature Annealing Studies on the Piezoelectric Properties of Thin Aluminum Nitride Films

    SciTech Connect

    R. Farrell; V. R. Pagan; A. Kabulski; Sridhar Kuchibhatl; J. Harman; K. R. Kasarla; L. E. Rodak; P. Famouri; J. Peter Hensel; D. Korakakis

    2008-05-01

    A Rapid Thermal Annealing (RTA) system was used to anneal sputtered and MOVPE grown Aluminum Nitride (AlN) thin films at temperatures up to 1000°C in ambient and controlled environments. According to Energy Dispersive X-Ray Analysis (EDAX), the films annealed in an ambient environment rapidly oxidize after five minutes at 1000°C. Below 1000°C the films oxidized linearly as a function of annealing temperature which is consistent with what has been reported in literature [1]. Laser Doppler Vibrometry (LDV) was used to measure the piezoelectric coefficient, d33, of these films. Films annealed in an ambient environment had a weak piezoelectric response indicating that oxidation on the surface of the film reduces the value of d33. A high temperature furnace has been built that is capable of taking in-situ measurements of the piezoelectric response of AlN films. In-situ d33 measurements are recorded up to 300°C for both sputtered and MOVPE-grown AlN thin films. The measured piezoelectric response appears to increase with temperature up to 300°C possibly due to stress in the film.

  19. High Temperature Annealing Studies on the Piezoelectric Properties of Thin Aluminum Nitride Films

    SciTech Connect

    Farrell, R.; Pagan, V.R.; Kabulski, A.; Kuchibhatla, S.; Harman, J.; Kasarla, K.R.; Rodak, L.E.; Hensel, J.P.; Famouri, P.; Korakakis, D.

    2008-01-01

    A Rapid Thermal Annealing (RTA) system was used to anneal sputtered and MOVPE-grown Aluminum Nitride (AlN) thin films at temperatures up to 1000°C in ambient and controlled environments. According to Energy Dispersive X-Ray Analysis (EDAX), the films annealed in an ambient environment rapidly oxidize after five minutes at 1000°C. Below 1000°C the films oxidized linearly as a function of annealing temperature which is consistent with what has been reported in literature [1]. Laser Doppler Vibrometry (LDV) was used to measure the piezoelectric coefficient, d33, of these films. Films annealed in an ambient environment had a weak piezoelectric response indicating that oxidation on the surface of the film reduces the value of d33. A high temperature furnace has been built that is capable of taking in-situ measurements of the piezoelectric response of AlN films. In-situ d33 measurements are recorded up to 300°C for both sputtered and MOVPE-grown AlN thin films. The measured piezoelectric response appears to increase with temperature up to 300°C possibly due to stress in the film.

  20. Space-deployed, thin-walled enclosure for a cryogenically-cooled high temperature superconducting coil

    NASA Astrophysics Data System (ADS)

    Porter, Allison K.

    The interaction of magnetic fields generated by large superconducting coils has multiple applications in space, including actuation of spacecraft or spacecraft components, wireless power transfer, and shielding of spacecraft from radiation and high energy particles. These applications require coils with major diameters as large as 20 meters and a thermal management system to maintain the superconducting material of the coil below its critical temperature. Since a rigid thermal management system, such as a heat pipe, is unsuitable for compact stowage inside a 5 meter payload fairing, a thin-walled thermal enclosure is proposed. A 1.85 meter diameter test article consisting of a bladder layer for containing chilled nitrogen vapor, a restraint layer, and multilayer insulation was tested in a custom toroidal vacuum chamber. The material properties found during laboratory testing are used to predict the performance of the test article in low Earth orbit. Deployment motion of the same test article was measured using a motion capture system and the results are used to predict the deployment in space. A 20 meter major diameter and coil current of 6.7 MA is selected as a point design case. This design point represents a single coil in a high energy particle shielding system. Sizing of the thermal and structural components of the enclosure is completed. The thermal and deployment performance is predicted.

  1. Influence of rapid thermal vacuum annealing and high temperature treatment on the properties of PSG films

    NASA Astrophysics Data System (ADS)

    Beschkov, G.; Bakardjieva, V.; Alexieva, Z.

    2008-05-01

    The effect is presented of rapid thermal annealing (RTA) in vacuum and thermal annealing in water vapor at 850 °C on the properties of phosphosilicate glass (PSG) films deposited in PECVD and μPCVD reactors. The films were characterized by etch rates and XPS and AES analyses. The RTA was carried out at 800 - 1400 °C at annealing times varying from 15 to 180 sec. The RTA caused a significant decrease in the etch rate, which is indicative of structural changes. The XPS and AES analyses showed that the PECVD PSG films contain excess Si due to the lower oxidation activity of N2O. The excess Si can be oxidized in water vapor at high temperatures. The excess Si leads to a decrease in the etching rate of the PECVD PSG layers as compared to that of the μPCVD films.

  2. Grain boundary studies of high temperature superconducting materials using electron backscatter Kikuchi diffraction

    SciTech Connect

    Goyal, A.; Specht, E.D.; Wang, Z.L.; Kroeger, D.M.

    1996-12-31

    Grain Orientation and gain boundary misorientation distributions in high critical current density, high temperature superconductors were determined using electron backscatter Kikuchi diffraction. It is found that depending on the type of superconductor and the processing method used to fabricate it, there exist different scales of biaxial texture from no biaxial texture, local biaxial texture, to complete biaxial texture. Experimentally obtained grain boundary misorientation distributions (GBMDs) were found to be skewed significantly to low angles in comparison to what is expected on the basis of macroscopic texture alone, suggesting that minimization of energy may be a driving force during the processing of high critical current density materials. In addition, a higher than expected fraction of coincident-site lattice boundaries is observed. Examination of maps of grain boundary misorientations in spatially correlated gains, i.e. the grain boundary mesotexture, suggests the presence percolative paths of high critical current density. A combination of orientation measurements, theoretical modeling of GBMDs and modeling of percolative current flow through an assemblage of gain boundaries is performed to gain an insight into the important microstructural features dictating the transport properties of high temperature superconductors. It is found that maximization of low energy, in particular, low angle boundaries is essential for higher critical currents. The combination of experimental and analytical techniques employed are applicable to other materials where physical properties are dominated by interganular characteristics.

  3. Assessment of High Temperature Superconducting (HTS) electric motors for rotorcraft propulsion

    NASA Technical Reports Server (NTRS)

    Doernbach, Jay

    1990-01-01

    The successful development of high temperature superconductors (HTS) could have a major impact on future aeronautical propulsion and aeronautical flight vehicle systems. Applications of high temperature superconductors have been envisioned for several classes of aeronautical systems, including subsonic and supersonic transports, hypersonic aircraft, V/STOL aircraft, rotorcraft and solar powered aircraft. The potential of HTS electric motors and generators for providing primary shaft power for rotorcraft propulsion is examined. Three different sized production helicopters were investigated; namely, the Bell Jet Ranger, the Sikorsky Black Hawk and the Sikorsky Super Stallion. These rotorcraft have nominal horsepower ratings of 500, 3600, and 13400 respectively. Preliminary results indicated that an all-electric HTS drive system produces an improvement in rotorcraft Takeoff Gross Weight (TOGW) for those rotorcraft with power ratings above 2000 horsepower. The predicted TOGW improvements are up to 9 percent for the medium-sized Sikorsky Black Hawk and up to 20 percent for the large-sized Sikorsky Super Stallion. The small-sized Bell Jet Ranger, however, experienced a penalty in TOGW with the all-electric HTS drive system.

  4. Advances in Thin Film Thermocouple Durability Under High Temperature and Pressure Testing Conditions

    NASA Technical Reports Server (NTRS)

    Martin, Lisa C.; Fralick, Gustave C.; Taylor, Keith F.

    1999-01-01

    Thin film thermocouples for measuring material surface temperature have been previously demonstrated on several material systems and in various hostile test environments. A well-developed thin film fabrication procedure utilizing shadow masking for patterning the sensors elements had produced thin films with sufficient durability for applications in high temperature and pressure environments that exist in air-breathing and hydrogen-fueled burner rig and engine test facilities. However, while shadow masking had been a reliable method for specimens with flat and gently curved surfaces, it had not been consistently reliable for use on test components with sharp contours. This work reports on the feasibility of utilizing photolithography processing for patterning thin film thermocouples. Because this patterning process required changes in the thin film deposition process from that developed for shadow masking, the effect of these changes on thin film adherence during burner rig testing was evaluated. In addition to the results of changing the patterning method, the effects on thin film adherence of other processes used in the thin film fabrication procedure is also presented.

  5. Research On Bi-Based High-Temperature Superconductors

    NASA Technical Reports Server (NTRS)

    Banks, Curtis; Doane, George B., III; Golben, John

    1993-01-01

    Brief report describes effects of melt sintering on Bi-based high-temperature superconductor system, as well as use of vibrating-sample magnetometer to determine hysteresis curves at 77 K for partially melt-sintered samples. Also discussed is production of high-temperature superconducting thin films by laser ablation: such films potentially useful in detection of signals of very low power.

  6. Evolution of High-Temperature Superconductivity from a Low-T_{c} Phase Tuned by Carrier Concentration in FeSe Thin Flakes.

    PubMed

    Lei, B; Cui, J H; Xiang, Z J; Shang, C; Wang, N Z; Ye, G J; Luo, X G; Wu, T; Sun, Z; Chen, X H

    2016-02-19

    We report the evolution of superconductivity in an FeSe thin flake with systematically regulated carrier concentrations by the liquid-gating technique. With electron doping tuned by the gate voltage, high-temperature superconductivity with an onset at 48 K can be achieved in an FeSe thin flake with T_{c} less than 10 K. This is the first time such high temperature superconductivity in FeSe is achieved without either an epitaxial interface or external pressure, and it definitely proves that the simple electron-doping process is able to induce high-temperature superconductivity with T_{c}^{onset} as high as 48 K in bulk FeSe. Intriguingly, our data also indicate that the superconductivity is suddenly changed from a low-T_{c} phase to a high-T_{c} phase with a Lifshitz transition at a certain carrier concentration. These results help to build a unified picture to understand the high-temperature superconductivity among all FeSe-derived superconductors and shed light on the further pursuit of a higher T_{c} in these materials.

  7. High-temperature processing of cuprate oxide superconductors

    NASA Technical Reports Server (NTRS)

    Wu, M. K.; Ashburn, J. R.; Higgins, C. A.; Fellows, C. W.; Loo, B. H.; Burns, D. H.; Ibrahim, A.; Rolin, T. D.; Peters, P. N.; Sisk, R. C.

    1988-01-01

    Superconducting Y1Ba2Cu3O7 ('123') films were fabricated on the Y2BaCuO5 ('211') phase substrate. The superconducting characteristics of these films, in terms of superconducting transition temperature (Tc) and width, are better than those using other oxide compounds as substrates. In addition, using high-temperature processing, the bulk 211 phase was converted into the 123 phase. A new high Tc copper oxide material with non-rare-earth elements (Bi-Sr-Cu-O) was prepared using similar high-temperature processing. High-temperature processing presents an alternative synthetic route in the search of new high Tc superconductors.

  8. Serial and parallel power equipment with high-temperature superconducting elements

    NASA Technical Reports Server (NTRS)

    Bencze, Laszlo; Goebl, Nandor; Palotas, Bela; Vajda, Istvan

    1995-01-01

    One of the prospective, practical applications of high-temperature superconductors is the fault-current limitation in electrical energy networks. The development and testing of experimental HTSC serial current limiters have been reported in the literature. A Hungarian electric power company has proposed the development of a parallel equipment for arc suppressing both in the industrial and customers' networks. On the basis of the company's proposal the authors have outlined the scheme of a compound circuit that can be applied both for current limitation and arc suppressing. In this paper the design principles and methods of the shunt equipment are presented. These principles involve the electrical, mechanical and cryogenic aspects with the special view on the electrical and mechanical connection between the HTSC material and the current lead. Preliminary experiments and tests have been carried out to demonstrate the validity of the design principles developed. The results of the experiments and of the technological investigations are presented.

  9. Levitation characteristics of a high-temperature superconducting Maglev system for launching space vehicles

    NASA Astrophysics Data System (ADS)

    Yang, Wenjiang; Liu, Yu; Chen, Xiaodong; Wen, Zheng; Duan, Yi; Qiu, Ming

    2007-05-01

    Maglev launch assist is viewed as an effective method to reduce the cost of space launch. The primary aerodynamic characteristics of the Maglev launch vehicle and the space vehicle are discussed by analyzing their aerodynamic shapes and testing a scale mode in a standard wind tunnel. After analyzing several popular Maglev systems, we present a no-controlling Maglev system with bulk YBaCuO high-temperature superconductors (HTSs). We tested a HTS Maglev system unit, and obtained the levitation force density of 3.3 N/cm2 and the lateral force density of 2.0 N/cm2. We also fabricated a freely levitated test platform to investigate the levitation characteristics of the HTS Maglev system in load changing processes. We found that the HTS system could provide the strong self-stable levitation performance due to the magnetic flux trapped in superconductors. The HTS Maglev system provided feasibility for application in the launch vehicle.

  10. Some problems in the competition of high-temperature superconductivity research during the late 1980s

    NASA Astrophysics Data System (ADS)

    Liu, Bing

    2014-03-01

    After A. Müller and J.G. Bednorz found that Oxide Ba-La-Cu-O could have Tc for 30K in 1986, a special competition in High Temperature superconductors research began in the world, especially among American, Japanese and Chinese scientists in late 1980's. By investigating that competition in history, some interesting problems were found. There are strategy used by scientists in different country which differ from normal science period; Question about the peer review and competition in that special period; ``Matthew's Effect'' in that competition; some question about the disclosure of the secret information and competition; and, finally what methodology was used by Chinese scientists. All that problems are not only historically, but also have some sociological and philosophical meaning. Based on historical re-investigation, all those problems were discussed in the paper.

  11. No-insulation multi-width winding technique for high temperature superconducting magnet

    PubMed Central

    Hahn, Seungyong; Kim, Youngjae; Keun Park, Dong; Kim, Kwangmin; Voccio, John P.; Bascuñán, Juan; Iwasa, Yukikazu

    2013-01-01

    We present a No-Insulation (NI) Multi-Width (MW) winding technique for an HTS (high temperature superconductor) magnet consisting of double-pancake (DP) coils. The NI enables an HTS magnet self-protecting and the MW minimizes the detrimental anisotropy in current-carrying capacity of HTS tape by assigning tapes of multiple widths to DP coils within a stack, widest tape to the top and bottom sections and the narrowest in the midplane section. This paper presents fabrication and test results of an NI-MW HTS magnet and demonstrates the unique features of the NI-MW technique: self-protecting and enhanced field performance, unattainable with the conventional technique. PMID:24255549

  12. Feasibility study for reduction of the screening current induced field in a 2G high temperature superconducting coil

    NASA Astrophysics Data System (ADS)

    Hwang, Y. J.; Jang, J. Y.; Ahn, M. C.; Park, Y. G.; Lee, S. G.

    2016-10-01

    This paper reports the effects of thermal energy on reducing the overshoot of the current sweep cycle method to reduce the screening current-induced field (SCF) in a 2G high temperature superconducting (HTS) coil. A disadvantage of the current sweep cycle method is the necessity for large overshoot in the coil current. For a 2G HTS coil, excessive overshooting of the coil current is undesirable (Yanagisawa et al 2012 AIP Conf. Proc. 1434 1373-8). In an effort to circumvent this overshooting problem, the thermal energy effect was investigated in combination with the current sweep cycle method based on experiments in this study. The experimental results show that greater SCF reduction in the HTS coil was obtained upon increasing thermal energy by heater current.

  13. Study on the effect of transition curve to the dynamic characteristics of high-temperature superconducting maglev

    NASA Astrophysics Data System (ADS)

    Qian, Nan; Zheng, Botian; Gou, Yanfeng; Chen, Ping; Zheng, Jun; Deng, Zigang

    2015-12-01

    High temperature superconducting (HTS) maglev technology is becoming more and more mature, and many key technologies have been deeply studied. However, the transition curve plays a key role in HTS maglev system, and related studies have not been carried out. In this paper series of simulations were conducted to test the lateral and vertical vibration of HTS maglev when passing through curves. Two magnetic guideways, of which one has transition curves but the other does not, are designed to test the vibration characteristics of a mini HTS maglev model running though curves. Results show that after adding transition curves between straight line and circular curve the vibration of HTS maglev model in lateral and vertical directions are all weakened in different degrees. It proves that adding transition curve into HTS maglev system is favorable and necessary.

  14. High Temperature Superconducting Degaussing-Cooling Two Hts Coils with One Cryocooler for the Littoral Combat Ship

    NASA Astrophysics Data System (ADS)

    Fitzpatrick, B. K.; Golda, E. M.; Kephart, J. T.

    2008-03-01

    The concept of creating a high temperature superconducting degaussing system has previously been studied by the Navy and shown to provide significant weight savings over conventional copper based degaussing systems. Modeling efforts have shown that in a HTS Degaussing System (HTSDG) for the Littoral Combat Ship, the dominant costs are cryocoolers. In an effort to minimize the number of cryocoolers, a two coil demonstrator cooled by one cryocooler has been constructed at NSWCCD Philadelphia. The demonstration consists of two 22 m long sections of flexible cryostat that are electrically isolated but connected in series through two junction boxes for serial gas flow. Within each cryostat section, 12 turns of HTS represent a vertical and horizontal degaussing coil. Use of Helium as the working fluid reduces safety impacts and allows higher current density in the HTS conductor due to lower temperature operation. Design, testing results, and lessons learned from the installation and operation of this cable are presented in this paper.

  15. Minimizing wafer defectivity during high-temperature baking of organic films in 193nm lithography

    NASA Astrophysics Data System (ADS)

    Randall, Mai; Longstaff, Christopher; Ueda, Kenichi; Nicholson, Jim; Winter, Thomas

    2006-03-01

    Demands for continued defect reduction in 300mm IC manufacturing is driving process engineers to examine all aspects of the apply process for improvement. Process engineers, and their respective tool sets, are required to process films at temperatures above the boiling point of the casting solvents. This can potentially lead to the sublimation of the film chemical components. The current methods used to minimize wafer defectivity due to bake residues include frequent cleaning of bake plate modules and surrounding equipment, process optimization, and hardware improvements until more robust chemistries are available. IBM has evaluated the Tokyo Electron CLEAN TRACK TM ACT TM 12 high exhaust high temperature hotplate (HHP) lid to minimize wafer level contamination due to the outgasing of a bottom anti-reflective coating (BARC) films during the high temperature bake process. Goal was to minimize airborne contamination (particles in free space), reduce hotplate contamination build up, and ultimately reduce defects on the wafer. This evaluation was performed on a 193nm BARC material. Evaluation data included visual hardware inspections, airborne particle counting, relative thickness build up measurements on hotplate lids, wafer level defect measurements, and electrical open fail rate. Film coat thickness mean and uniformity were also checked to compare the high exhaust HHP with the standard HHP lid. Chemical analysis of the HHP module residue was performed to identify the source material. The work will quantify potential cost savings achieved by reducing added wafer defects during processing and extending PM frequency for equipment cleaning.

  16. Nanostructures of Boron, Carbon and Magnesium Diboride for High Temperature Superconductivity

    SciTech Connect

    Pfefferle, Lisa; Fang, Fang; Iyyamperumal, Eswarmoorthi; Keskar, Gayatri

    2013-12-23

    Direct fabrication of MgxBy nanostructures is achieved by employing metal (Ni,Mg) incorporated MCM-41 in the Hybrid Physical-Chemical Vapor Deposition (HPCVD) reaction. Different reaction conditions are tested to optimize the fabrication process. TEM analysis shows the fabrication of MgxBy nanostructures starting at the reaction temperature of 600oC, with the yield of the nanostructures increasing with increasing reaction temperature. The as-synthesized MgxBy nanostructures have the diameters in the range of 3-5nm, which do not increase with the reaction temperature consistent with templated synthesis. EELS analysis of the template removed nanostructures confirms the existence of B and Mg with possible contamination of Si and O. NEXAFS and Raman spectroscopy analysis suggested a concentric layer-by-layer MgxBy nanowire/nanotube growth model for our as-synthesized nanostructures. Ni k-edge XAS indicates that the formation of MgNi alloy particles is important for the Vapor-Liquid-Solid (VLS) growth of MgxBy nanostructures with fine diameters, and the presence of Mg vapor not just Mg in the catalyst is crucial for the formation of Ni-Mg clusters. Physical templating by the MCM-41 pores was shown to confine the diameter of the nanostructures. DC magnetization measurements indicate possible superconductive behaviors in the as-synthesized samples.

  17. Revealing the high-energy electronic excitations underlying the onset of high-temperature superconductivity in cuprates

    PubMed Central

    Giannetti, Claudio; Cilento, Federico; Conte, Stefano Dal; Coslovich, Giacomo; Ferrini, Gabriele; Molegraaf, Hajo; Raichle, Markus; Liang, Ruixing; Eisaki, Hiroshi; Greven, Martin; Damascelli, Andrea; van der Marel, Dirk; Parmigiani, Fulvio

    2011-01-01

    In strongly correlated systems the electronic properties at the Fermi energy (EF) are intertwined with those at high-energy scales. One of the pivotal challenges in the field of high-temperature superconductivity (HTSC) is to understand whether and how the high-energy scale physics associated with Mott-like excitations (|E−EF|>1 eV) is involved in the condensate formation. Here, we report the interplay between the many-body high-energy CuO2 excitations at 1.5 and 2 eV, and the onset of HTSC. This is revealed by a novel optical pump-supercontinuum-probe technique that provides access to the dynamics of the dielectric function in Bi2Sr2Ca0.92Y0.08Cu2O8+δ over an extended energy range, after the photoinduced suppression of the superconducting pairing. These results unveil an unconventional mechanism at the base of HTSC both below and above the optimal hole concentration required to attain the maximum critical temperature (Tc). PMID:21673674

  18. The Progress on Low-Cost, High-Quality, High-Temperature Superconducting Tapes Deposited by the Combustion Chemical Vapor Deposition Process

    SciTech Connect

    Shoup, S.S.; White, M.K.; Krebs, S.L.; Darnell, N.; King, A.C.; Mattox, D.S.; Campbell, I.H.; Marken, K.R.; Hong, S.; Czabaj, B.; Paranthaman, M.; Christen, H.M.; Zhai, H.-Y. Specht, E.

    2008-06-24

    The innovative Combustion Chemical Vapor Deposition (CCVD) process is a non-vacuum technique that is being investigated to enable next generation products in several application areas including high-temperature superconductors (HTS). In combination with the Rolling Assisted Biaxially Textured Substrate (RABiTS) technology, the CCVD process has significant promise to provide low-cost, high-quality lengths of YBCO coated conductor. Over 100 meter lengths of both Ni and Ni-W (3 at. Wt.%) substrates with a surface roughness of 12-18 nm were produced. The CCVD technology has been used to deposit both buffer layer coatings as well as YBCO superconducting layers. Buffer layer architecture of strontium titanate (SrTiO{sub 3}) and ceria (CeO{sub 2}) have been deposited by CCVD on textured nickel substrates and optimized to appropriate thicknesses and microstructures to provide templates for growing PLD YBCO with a J{sub c} of 1.1 MA/cm{sup 2} at 77 K and self-field. The CCVD buffer layers have been scaled to meter plus lengths with good epitaxial uniformity along the length. A short sample cut from one of the lengths enabled high critical current density PLD YBCO. Films of CCVD YBCO superconductors have been grown on single crystal substrates with critical current densities over 1 MA/cm{sup 2}. In addition, superconducting YBCO films with an I{sub c} of 60 A/cm-width (J{sub c} = 1.5 MA/cm{sup 2}) were grown on ORNL RABiTS (CeO{sub 2}/YSZ/Y{sub 2}O{sub 3}/Ni/Ni-3W) using CCVD process.

  19. Substrates suitable for deposition of superconducting thin films

    DOEpatents

    Feenstra, Roeland; Boatner, Lynn A.

    1993-01-01

    A superconducting system for the lossless transmission of electrical current comprising a thin film of superconducting material Y.sub.1 Ba.sub.2 Cu.sub.3 O.sub.7-x epitaxially deposited upon a KTaO.sub.3 substrate. The KTaO.sub.3 is an improved substrate over those of the prior art since the it exhibits small lattice constant mismatch and does not chemically react with the superconducting film.

  20. Rhombohedral AlPt films formed by self-propagating, high temperature synthesis.

    SciTech Connect

    Adams, David Price; Rodriguez, Mark Andrew; Kotula, Paul Gabriel

    2005-11-01

    High-purity AlPt thin films prepared by self-propagating, high temperature combustion synthesis show evidence for a new rhombohedral phase. Sputter deposited Al/Pt multilayers of various designs are reacted at different rates in air and in vacuum, and each form a new trigonal/hexagonal aluminide phase with unit cell parameters a = 15.571(8) {angstrom}, c = 5.304(1) {angstrom}, space group R-3 (148), and Z, the number of formula units within a unit cell, = 39. The lattice is isostructural to that of the AlPd R-3 lattice as reported by Matkovic and Schubert (Matkovic, 1977). Reacted films have a random in-plane crystallographic texture, a modest out-of-plane (001) texture, and equiaxed grains with dimensions on the order of film thickness.

  1. High Temperature Dielectric Behavior of Polycarbonate/Poly(vinylidene fluoride) Multilayer Films

    NASA Astrophysics Data System (ADS)

    Lewis, Craig; Tseng, Jung-Kai; Mackey, Mathew; Baer, Eric; Zhu, Lei; Lei Zhu Group Team

    2013-03-01

    Because of significant dielectric and resistivity constants for polycarbonate (PC) and poly(vinylidene fluoride) (PVDF), the Maxwell-Wagner-Sillars interfacial polarization is observed in PC/PVDF multilayer films and is able to increase the overall electric displacement. However, based on the dielectric displacement-electric field (D-E) loop study, the PC/PVDF 50/50 32 layer film has higher dielectric constant calculated from the slope of D-E loop as compared to the 256 layer film. In other words, the maximum D decreases with decreasing the PC layer thickness. Since the electron tunneling is significant for thinner PC layers (i.e., internal conduction), the interfacial polarization is decreased. This study elucidates the relationship between the maximum D and the PC layer thickness, as well as the dielectric behavior at high temperatures.

  2. High temperature superconductor micro-superconducting-quantum-interference-device magnetometer for magnetization measurement of a microscale magnet

    SciTech Connect

    Takeda, Keiji; Mori, Hatsumi; Yamaguchi, Akira; Ishimoto, Hidehiko; Nakamura, Takayoshi; Kuriki, Shinya; Hozumi, Toshiya; Ohkoshi, Shin-ichi

    2008-03-15

    We have developed a high temperature superconductor (HTS) micrometer-sized dc superconducting quantum interference device (SQUID) magnetometer for high field and high temperature operation. It was fabricated from YBa{sub 2}Cu{sub 3}O{sub 7-{delta}} of 92 nm in thickness with photolithography techniques to have a hole of 4x9 {mu}m{sup 2} and 2 {mu}m wide grain boundary Josephson junctions. Combined with a three dimensional magnetic field coil system, the modulation patterns of critical current I{sub c} were observed for three different field directions. They were successfully used to measure the magnetic properties of a molecular ferrimagnetic microcrystal (23x17x13 {mu}m{sup 3}), [Mn{sub 2}(H{sub 2}O){sub 2}(CH{sub 3}COO)][W(CN){sub 8}]{center_dot}2H{sub 2}O. The magnetization curve was obtained in magnetic field up to 0.12 T between 30 and 70 K. This is the first to measure the anisotropy of hysteresis curve in the field above 0.1 T with an accuracy of 10{sup -12} J T{sup -1} (10{sup -9} emu) with a HTS micro-SQUID magnetometer.

  3. Development of a 13C-optimized 1.5-mm high temperature superconducting NMR probe

    NASA Astrophysics Data System (ADS)

    Ramaswamy, Vijaykumar; Hooker, Jerris W.; Withers, Richard S.; Nast, Robert E.; Brey, William W.; Edison, Arthur S.

    2013-10-01

    We report a 1.5-mm NMR probe based on high temperature superconductors operating at 14.1 T optimized for 13C detection. The probe has a total sample volume of about 35 microliters (μL) with an active volume of 20 μL and provides exceptional mass sensitivity for 13C detection. The probe also has excellent 1H sensitivity and employs a 2H lock; 15N irradiation capability can be added in the future. The coils are cooled to about 20 K using a standard Agilent cryogenic refrigeration system, and the sample temperature is regulated near room temperature. The coil design considerations are discussed in detail. This probe is ideal for directly detected 13C NMR experiments for natural products chemistry and metabolomics applications, for which 35 μL is an optimal sample volume. The outstanding 13C sensitivity of this probe allowed us to directly determine the 13C connectivity on 1.1 mg of natural abundance histidine using an INADEQUATE experiment. We demonstrated the utility of this probe for 13C-based metabolomics using a synthetic mixture of common natural abundance metabolites whose concentrations ranged from 1 to 5 mM (40-200 nmol).

  4. High-Temperature Superconductive Cabling Investigated for Space Solar Power Satellites

    NASA Technical Reports Server (NTRS)

    Tew, Roy C.; Juhasz, Albert J.

    2000-01-01

    NASA has been directed by Congress to take a fresh look at the Space Solar Power (SSP) concept that was studied by the Department of Energy and NASA about 20 years ago. To summarize, the concept involves (1) collecting solar energy and converting it to electrical energy via photovoltaic arrays on satellites in Earth orbit, (2) conducting the electricity to the microwave transmitting portion of the satellite, and (3) transmitting the power via microwave transmitters (or possibly via lasers) to ground power station antennas located on the surface of the Earth. One Sun Tower SSP satellite concept is illustrated here. This figure shows many photovoltaic arrays attached to a "backbone" that conducts electricity down to a wireless transmitter, which is pointed toward the Earth. Other variations on this concept use multiple backbones to reduce the overall length of the satellite structure. In addition, non-Sun-Tower concepts are being considered. The objective of the work reported here was to determine the benefits to the SSP concept of using high-temperature superconductors (HTS) to conduct the electricity from the photovoltaic arrays to the wireless power transmitters. Possible benefits are, for example, reduced mass, improved efficiency, and improved reliability. Dr. James Powell of Plus Ultra Technologies, Inc., of Stony Brook, New York, is conducting the study, and it is being managed by the NASA Glenn Research Center at Lewis Field via a task-order contract through Scientific Applications International Corp. (SAIC).

  5. Growth, structure, and high temperature stability of zirconium diboride thin films

    SciTech Connect

    Stewart, David M.; Frankel, David J.; Lad, Robert J.

    2015-05-15

    Morphologically stable, electrically conductive thin films are required for emerging harsh environment sensors that can operate at temperatures above 1000 °C. Zirconium diboride (ZrB{sub 2}) is an ultrahigh temperature ceramic with a melting temperature greater than 3200 °C and in bulk form has an electrical conductivity of ∼10{sup 7 }S/m. Thin films of varying Zr:B ratio have been deposited on sapphire substrates by electron beam coevaporation from elemental sources. An appropriate ratio of the elemental fluxes was determined to produce nearly stoichiometric ZrB{sub 2} thin films. Films deposited at ambient substrate temperatures are amorphous as measured by x-ray diffraction, while films grown at 600 °C show textured ZrB{sub 2} nanocrystallites in an amorphous matrix, regardless of composition. When annealed in ultrahigh vacuum at 800 and 1000 °C for 1 h, nanocrystalline films show further grain growth with a 〈101{sup ¯}0〉 ZrB{sub 2} preferred orientation normal to the substrate, while the low nucleation rate in the amorphous films inhibits the formation of any substantial grains. Film conductivity ranges between 0.13 and 6.3 × 10{sup 5 }S/m, increasing with zirconium content and crystallite grain size. Besides grain growth, no micron-scale structural or morphological changes were observed with annealing, suggesting that ZrB{sub 2} films can act as stable electrodes in high temperature environments.

  6. High Temperature - Thin Film Strain Gages Based on Alloys of Indium Tin Oxide

    NASA Technical Reports Server (NTRS)

    Gregory, Otto J.; Cooke, James D.; Bienkiewicz, Joseph M.

    1998-01-01

    A stable, high temperature strain gage based on reactively sputtered indium tin oxide (ITO) was demonstrated at temperatures up to 1050 C. These strain sensors exhibited relatively large, negative gage factors at room temperature and their piezoresistive response was both linear and reproducible when strained up to 700 micro-in/in. When cycled between compression and tension, these sensors also showed very little hysteresis, indicating excellent mechanical stability. Thin film strain gages based on selected ITO alloys withstood more than 50,000 strain cycles of +/- 500 micro-in/in during 180 hours of testing in air at 1000 C, with minimal drift at temperature. Drift rates as low as 0.0009%/hr at 1000 C were observed for ITO films that were annealed in nitrogen at 700 C prior to strain testing. These results compare favorably with state of the art 10 micro-m thick PdCr films deposited by NASA, where drift rates of 0.047%/hr at 1050 C were observed. Nitrogen annealing not only produced the lowest drift rates to date, but also produce the largest dynamic gage factors (G = 23.5). These wide bandgap, semiconductor strain sensors also exhibited moderately low temperature coefficients of resistance (TCR) at temperatures up to 1100 C, when tested in a nitrogen ambient. A TCR of +230 ppm/C over the temperature range 200 C < T < 500 C and a TCR of -469 ppm/C over the temperature range 600 C < T < 1100 C was observed for the films tested in nitrogen. However, the resistivity behavior changed considerably when the same films were tested in oxygen ambients. A TCR of -1560 ppm/C was obtained over the temperature range of 200 C < T < 1100 C. When similar films were protected with an overcoat or when ITO films were prepared with higher oxygen contents in the plasma, two distinct TCR's were observed. At T < 800 C, a linear TCR of -210 ppm/C was observed and at T > 800 C, a linear TCR of -2170 DDm/C was observed. The combination of a moderately low TCR and a relatively large gage

  7. A deployable high temperature superconducting coil (DHTSC) - A novel concept for producing magnetic shields against both solar flare and Galactic radiation during manned interplanetary missions

    NASA Technical Reports Server (NTRS)

    Cocks, F. Hadley

    1991-01-01

    The discovery of materials which are superconducting above 100 K makes possible the use of superconducting coils deployed beyong the hull of an interplanetary spacecraft to produce a magnetic shield capable of giving protection not only against solar flare radiation, but also even against Galactic radiation. Such deployed coils can be of very large size and can thus achieve the great magnetic moments required using only relatively low currents. Deployable high-temperature-superconducting coil magnetic shields appear to offer very substantial reductions in mass and energy compared to other concepts and could readily provide the radiation protection needed for a Mars mission or space colonies.

  8. High temperature thermocouple and heat flux gauge using a unique thin film-hardware hot juncture

    NASA Technical Reports Server (NTRS)

    Liebert, C. H.; Holanda, R.; Hippensteele, S. A.; Andracchio, C. A.

    1984-01-01

    A special thin film-hardware material thermocouple (TC) and heat flux gauge concept for a reasonably high temperature and high flux flat plate heat transfer experiment was fabricated and tested to gauge temperatures of 911 K. This concept was developed for minimal disturbance of boundary layer temperature and flow over the plates and minimal disturbance of heat flux through the plates. Comparison of special heat flux gauge Stanton number output at steady-state conditions with benchmark literature data was good and agreement was within a calculated uncertainty of the measurement system. Also, good agreement of special TC and standard TC outputs was obtained and the results are encouraging. Oxidation of thin film thermoelements was a primary failure mode after about 5 of operation.

  9. Characterization of high temperature deposited Ti-containing hydrogenated carbon thin films

    NASA Astrophysics Data System (ADS)

    Shi, B.; Meng, W. J.; Evans, R. D.

    2004-12-01

    A detailed structural and mechanical characterization was performed on Ti-containing hydrogenated amorphous carbon (Ti-C:H) thin films deposited at ˜600°C by plasma assisted hybrid chemical/physical vapor deposition. The structural and mechanical characteristics of these specimens were compared to those deposited at the lower temperature of ˜250°C. The results indicated that Ti-C :H consisted of a nanocrystalline TiC phase and a hydrogenated amorphous carbon (a-C:H) phase, and that Ti atoms were incorporated into Ti-C :H predominantly as B1-TiC. Deposition at ˜600°C promoted TiC precipitation, resulting in little Ti dissolution within the a-C :H matrix. High temperature deposited Ti-C :H specimens were found to possess lower modulus and hardness values as compared to low temperature deposited specimens, especially at low Ti compositions. This is rationalized by electron microscopy evidence of increased short and medium range graphitic order within the a-C :H matrix of high temperature deposited Ti-C :H, and supported by additional Raman spectroscopic observations. Heat treatments at 600 °C combined with Raman scattering measurements showed that the a-C :H matrix in high temperature deposited Ti-C :H specimens appears to be less structurally sensitive to additional annealing.

  10. Analytical approximations for thermophysical properties of supercritical nitrogen (SCN) to be used in futuristic high temperature superconducting (HTS) cables

    NASA Astrophysics Data System (ADS)

    Dondapati, Raja Sekhar; Ravula, Jeswanth; Thadela, S.; Usurumarti, Preeti Rao

    2015-12-01

    Future power transmission applications demand higher efficiency due to the limited resources of energy. In order to meet such demand, a novel method of transmission is being developed using High Temperature Superconducting (HTS) cables. However, these HTS cables need to be cooled below the critical temperature of superconductors used in constructing the cable to retain the superconductivity. With the advent of new superconductors whose critical temperatures having reached up to 134 K (Hg based), a need arises to find a suitable coolant which can accommodate the heating loads on the superconductors. The present work proposes, Supercritical Nitrogen (SCN) to be a feasible coolant to achieve the required cooling. Further, the feasibility of proposed coolant to be used in futuristic HTS cables is investigated by studying the thermophysical properties such as density, viscosity, specific heat and thermal conductivity with respect to temperature (TC + 10 K) and pressure (PC + 10 bar). In addition, few temperature dependent analytical functions are developed for thermophysical properties of SCN which are useful in predicting thermohydraulic performance (pressure drop, pumping power and cooling capacity) using numerical or computational techniques. Also, the developed analytical functions are used to calculate the pumping power and the temperature difference between inlet and outlet of HTS cable. These results are compared with those of liquid nitrogen (LN2) and found that the circulating pumping power required to pump SCN is significantly smaller than that to pump LN2. Further, it is found that the temperature difference between the inlet and outlet is smaller as compared to that when LN2 is used, SCN can be preferred to cool long length Hg based HTS cables.

  11. High Energy Density and High Temperature Multilayer Capacitor Films for Electric Vehicle Applications

    NASA Astrophysics Data System (ADS)

    Treufeld, Imre; Song, Michelle; Zhu, Lei; Baer, Eric; Snyder, Joe; Langhe, Deepak

    2015-03-01

    Multilayer films (MLFs) with high energy density and high temperature capability (>120 °C) have been developed at Case Western Reserve University. Such films offer a potential solution for electric car DC-link capacitors, where high ripple currents and high temperature tolerance are required. The current state-of-the-art capacitors used in electric cars for converting DC to AC use biaxially oriented polypropylene (BOPP), which can only operate at temperatures up to 85 °C requiring an external cooling system. The polycarbonate (PC)/poly(vinylidene fluoride) (PVDF) MLFs have a higher permittivity compared to that of BOPP (2.3), leading to higher energy density. They have good mechanical stability and reasonably low dielectric losses at 120 °C. Nonetheless, our preliminary dielectric measurements show that the MLFs exhibit appreciable dielectric losses (20%) at 120 °C, which would, despite all the other advantages, make them not suitable for practical applications. Our preliminary data showed that dielectric losses of the MLFs at 120 °C up to 400 MV/m and 1000 Hz originate mostly from impurity ionic conduction. This work is supported by the NSF PFI/BIC Program (IIP-1237708).

  12. Chemical fabrication of superconducting Y-Ba-Cu oxide films

    NASA Astrophysics Data System (ADS)

    Hussain, A. A.; Sayer, M.

    1992-02-01

    High-Tc superconducting films of Y-Ba-Cu oxide were prepared on 100-plane MgO substrates by a sol-gel method. A procedure is described for preparing a superconducting film using acetate compounds dissolved in salicylic or lactic acids in the presence of ethylene glycol. This solution has superior qualities in terms of homogeneity, viscosity, and stability against atmospheric hydration. The results indicate that the nature of the solvent influences the microstructure and superconducting properties of Y-Ba-Cu-O films. X-ray diffraction analysis reveals that the annealed films are textured and had orthorhombic orientation. A correlation between the crystal structure and the superconducting properties of the Y-Ba-Cu-O films is presented.

  13. In situ epitaxial MgB2 thin films for superconducting electronics.

    PubMed

    Zeng, Xianghui; Pogrebnyakov, Alexej V; Kotcharov, Armen; Jones, James E; Xi, X X; Lysczek, Eric M; Redwing, Joan M; Xu, Shengyong; Li, Qi; Lettieri, James; Schlom, Darrell G; Tian, Wei; Pan, Xiaoqing; Liu, Zi-Kui

    2002-09-01

    The newly discovered 39-K superconductor MgB2 holds great promise for superconducting electronics. Like the conventional superconductor Nb, MgB2 is a phonon-mediated superconductor, with a relatively long coherence length. These properties make the prospect of fabricating reproducible uniform Josephson junctions, the fundamental element of superconducting circuits, much more favourable for MgB2 than for high-temperature superconductors. The higher transition temperature and larger energy gap of MgB2 promise higher operating temperatures and potentially higher speeds than Nb-based integrated circuits. However, success in MgB2 Josephson junctions has been limited because of the lack of an adequate thin-film technology. Because a superconducting integrated circuit uses a multilayer of superconducting, insulating and resistive films, an in situ process in which MgB2 is formed directly on the substrate is desirable. Here we show that this can be achieved by hybrid physical-chemical vapour deposition. The epitaxially grown MgB2 films show a high transition temperature and low resistivity, comparable to the best bulk samples, and their surfaces are smooth. This advance removes a major barrier for superconducting electronics using MgB2.

  14. PREFACE: Superconductivity in ultrathin films and nanoscale systems Superconductivity in ultrathin films and nanoscale systems

    NASA Astrophysics Data System (ADS)

    Bianconi, Antonio; Bose, Sangita; Garcia-Garcia, Antonio Miguel

    2012-12-01

    The recent technological developments in the synthesis and characterization of high-quality nanostructures and developments in the theoretical techniques needed to model these materials, have motivated this focus section of Superconductor Science and Technology. Another motivation is the compelling evidence that all new superconducting materials, such as iron pnictides and chalcogenides, diborides (doped MgB2) and fullerides (alkali-doped C60 compounds), are heterostrucures at the atomic limit, such as the cuprates made of stacks of nanoscale superconducting layers intercalated by different atomic layers with nanoscale periodicity. Recently a great amount of interest has been shown in the role of lattice nano-architecture in controlling the fine details of Fermi surface topology. The experimental and theoretical study of superconductivity in the nanoscale started in the early 1960s, shortly after the discovery of the BCS theory. Thereafter there has been rapid progress both in experiments and the theoretical understanding of nanoscale superconductors. Experimentally, thin films, granular films, nanowires, nanotubes and single nanoparticles have all been explored. New quantum effects appear in the nanoscale related to multi-component condensates. Advances in the understanding of shape resonances or Fano resonances close to 2.5 Lifshitz transitions near a band edge in nanowires, 2D films and superlattices [1, 2] of these nanosized modules, provide the possibility of manipulating new quantum electronic states. Parity effects and shell effects in single, isolated nanoparticles have been reported by several groups. Theoretically, newer techniques based on solving Richardson's equation (an exact theory incorporating finite size effects to the BCS theory) numerically by path integral methods or solving the entire Bogoliubov-de Gennes equation in these limits have been attempted, which has improved our understanding of the mechanism of superconductivity in these confined

  15. Superconductivity of YBCO Thick Films Prepared by Spark Plasma Sintering

    NASA Astrophysics Data System (ADS)

    Kim, Youngha; Lee, Kyong H.; Sung, Tae-Hyun; Han, Sang-Chul; Han, Young-Hee; Jeong, Nyeon-Ho; No, Kwangsoo

    2007-10-01

    YBa2Cu3O x (YBCO) superconducting thick films have been fabricated on Cu substrates, using a simple screen-printing method from Cu-free powders (Y2O3 and BaCO3). However, such films have poor superconducting properties such as critical current density ( J c) due to the low film density. In this work, we investigate the effect of uniaxial c-axis pressure on the superconducting properties of these YBCO films using a spark plasma sintering (SPS) technique. The film screen-printed on Cu substrates was heat-treated at 850°C for 5 min in vacuum varying the pressure (15, 30, and 45 MPa). To form a superconducting YBCO phase, the film was reheat-treated at 930°C for 30 s in air followed by oxygen annealing at 450°C for 1 h. For heat-treatments performed under pressure, lower film porosity was obtained, and a higher crack density was also observed compared to films prepared without pressure. The densification of the YBCO thick films using the SPS technique was very effective in improving the superconducting properties of the films.

  16. Superconductivity in epitaxial thin films of NaxCoO2•yD2O

    NASA Astrophysics Data System (ADS)

    Krockenberger, Y.; Fritsch, I.; Christiani, G.; Habermeier, H.-U.; Yu, Li; Bernhard, C.; Keimer, B.; Alff, L.

    2006-04-01

    The observation of superconductivity in the layered transition metal oxide NaxCoO2•yH2O [K. Takada et al., Nature (London) 422, 53 (2003)] has caused a tremendous upsurge of scientific interest due to its similarities and its differences to the copper based high-temperature superconductors. Two years after the discovery, we report the fabrication of single-phase superconducting epitaxial thin films of Na0.3CoO2•1.3D2O grown by pulsed laser deposition technique. This opens additional roads for experimental research exploring the superconducting state and the phase diagram of this unconventional material.

  17. Dynamic response characteristics of high temperature superconducting maglev systems: Comparison between Halbach-type and normal permanent magnet guideways

    NASA Astrophysics Data System (ADS)

    Wang, B.; Zheng, J.; Che, T.; Zheng, B. T.; Si, S. S.; Deng, Z. G.

    2015-12-01

    The permanent magnet guideway (PMG) is very important for the performance of the high temperature superconducting (HTS) system in terms of electromagnetic force and operational stability. The dynamic response characteristics of a HTS maglev model levitating on two types of PMG, which are the normal PMG with iron flux concentration and Halbach-type PMG, were investigated by experiments. The dynamic signals for different field-cooling heights (FCHs) and loading/unloading processes were acquired and analyzed by a vibration analyzer and laser displacement sensors. The resonant frequency, stiffness and levitation height of the model were discussed. It was found that the maglev model on the Halbach-type PMG has higher resonant frequency and higher vertical stiffness compared with the normal PMG. However, the low lateral stiffness of the model on the Halbach-type PMG indicates poor lateral stability. Besides, the Halbach-type PMG has better loading capacity than the normal PMG. These results are helpful to design a suitable PMG for the HTS system in practical applications.

  18. A Temperature-Stable Cryo-System for High-Temperature Superconducting MR In-Vivo Imaging

    PubMed Central

    Lin, In-Tsang; Yang, Hong-Chang; Chen, Jyh-Horng

    2013-01-01

    To perform a rat experiment using a high-temperature superconducting (HTS) surface resonator, a cryostat is essential to maintain the rat's temperature. In this work, a compact temperature-stable HTS cryo-system, keeping animal rectal temperature at 37.4°C for more than 3 hours, was successfully developed. With this HTS cryo-system, a 40-mm-diameter Bi2Sr2Ca2Cu3Ox (Bi-2223) surface resonator at 77 K was demonstrated in a 3-Tesla MRI system. The proton resonant frequency (PRF) method was employed to monitor the rat's temperature. Moreover, the capacity of MR thermometry in the HTS experiments was evaluated by correlating with data from independent fiber-optic sensor temperature measurements. The PRF thermal coefficient was derived as 0.03 rad/°C and the temperature-monitoring architecture can be implemented to upgrade the quality and safety in HTS experiments. The signal-to-noise ratio (SNR) of the HTS surface resonator at 77 K was higher than that of a professionally made copper surface resonator at 300 K, which has the same geometry, by a 3.79-fold SNR gain. Furthermore, the temperature-stable HTS cryo-system we developed can obtain stable SNR gain in every scan. A temperature-stable HTS cryo-system with an external air-blowing circulation system is demonstrated. PMID:23637936

  19. Study on the performance improvement of the high temperature superconducting coil with several separated coils at the edges

    NASA Astrophysics Data System (ADS)

    Ishiguri, S.; Oka, T.; Fukui, S.; Ogawa, J.; Sato, T.

    2008-09-01

    In designing high temperature superconducting (HTS) coils, it is important to secure large magnetic fields and stored energy using shorter tape length. Thus, it is necessary to improve the transport current performance of the coils. The critical current and n-value of an HTS tape depend on magnetic fields and flux angles under constant temperature. Considering these dependencies, we established a model to analyze coil critical current. This model clarifies that relatively large electric fields are generated at the coil edges. This adversely affects the transport current performance. In this study, the coil edge is separated into several coils, keeping the total tape length constant. This increases the coil critical current, stored energy, central magnetic field, and also the coil volume, which contains vacancies created by the separation. To estimate coil performance, we calculated the stored energy density, whose denominator is the increased coil volume. This stored energy density reaches its maximum value when the number of the separated coils is eight. At this optimum separation, the central magnetic field increases by 13%, and the stored energy improves by 43%, compared to a rectangular coil wound with the same tape length.

  20. Design and preliminary results from a high temperature superconducting SQUID milliscope used for non-destructive evaluation

    SciTech Connect

    Espy, M.A.; Atencio, L.; Flynn, E.R.; Kraus, R.H. Jr.; Matlashov, A.

    1998-12-31

    The authors present the design and preliminary results from a SQUID milliscope. The device was designed for nondestructive evaluation (NDE) as part of the Enhanced Surveillance Program at Los Alamos National Laboratory and uses a high temperature superconducting (HTS) SQUID sensor to map magnetic fields induced in the sample. Eddy currents are induced in the conducting sample by a wire coil designed to produce minimal magnetic field at the SQUID when no sample is present. The features of interest are characterized by anomalies in the induced magnetic field. The goal of the instrument is sensitivity to small features generally buried under several intervening layers ({approximately}1--10 mm) of conducting and/or non-conducting materials and robustness of design (i.e., the ability to operate in a noisy, unshielded environment). The device has primarily focused on specific NDE problems such as the ability to detect buried seams in conducting materials and quantify the width of these seams. The authors present the design of the instrument, and some data to demonstrate its capabilities.

  1. PREFACE: Superconductivity in ultrathin films and nanoscale systems Superconductivity in ultrathin films and nanoscale systems

    NASA Astrophysics Data System (ADS)

    Bianconi, Antonio; Bose, Sangita; Garcia-Garcia, Antonio Miguel

    2012-12-01

    The recent technological developments in the synthesis and characterization of high-quality nanostructures and developments in the theoretical techniques needed to model these materials, have motivated this focus section of Superconductor Science and Technology. Another motivation is the compelling evidence that all new superconducting materials, such as iron pnictides and chalcogenides, diborides (doped MgB2) and fullerides (alkali-doped C60 compounds), are heterostrucures at the atomic limit, such as the cuprates made of stacks of nanoscale superconducting layers intercalated by different atomic layers with nanoscale periodicity. Recently a great amount of interest has been shown in the role of lattice nano-architecture in controlling the fine details of Fermi surface topology. The experimental and theoretical study of superconductivity in the nanoscale started in the early 1960s, shortly after the discovery of the BCS theory. Thereafter there has been rapid progress both in experiments and the theoretical understanding of nanoscale superconductors. Experimentally, thin films, granular films, nanowires, nanotubes and single nanoparticles have all been explored. New quantum effects appear in the nanoscale related to multi-component condensates. Advances in the understanding of shape resonances or Fano resonances close to 2.5 Lifshitz transitions near a band edge in nanowires, 2D films and superlattices [1, 2] of these nanosized modules, provide the possibility of manipulating new quantum electronic states. Parity effects and shell effects in single, isolated nanoparticles have been reported by several groups. Theoretically, newer techniques based on solving Richardson's equation (an exact theory incorporating finite size effects to the BCS theory) numerically by path integral methods or solving the entire Bogoliubov-de Gennes equation in these limits have been attempted, which has improved our understanding of the mechanism of superconductivity in these confined

  2. Suppression of superconductivity in epitaxial MgB2 ultrathin films

    NASA Astrophysics Data System (ADS)

    Zhang, Chen; Wang, Yue; Wang, Da; Zhang, Yan; Liu, Zheng-Hao; Feng, Qing-Rong; Gan, Zi-Zhao

    2013-07-01

    MgB2 ultrathin films have potential to make sensitive superconducting devices such as superconducting single-photon detectors working at relatively high temperatures. We have grown epitaxial MgB2 films in thicknesses ranging from about 40 nm to 6 nm by using the hybrid physical-chemical vapor deposition method and performed electrical transport measurements to study the thickness dependence of the superconducting critical temperature Tc. With reducing film thickness d, although a weak depression of the Tc has been observed, which could be attributed to an increase of disorder (interband impurity scattering) in the film, the Tc retains close to the bulk value of MgB2 (39 K), being about 35 K in the film of 6 nm thick. We show that this result, beneficial to the application of MgB2 ultrathin films and in accordance with recent theoretical calculations, is in contrast to previous findings in MgB2 films prepared by other methods such as co-evaporation and molecular-beam epitaxy, where a severe Tc suppression has been observed with Tc about one third of the bulk value in films of ˜5 nm thick. We discuss this apparent discrepancy in experiments and suggest that, towards the ultrathin limit, the different degrees of Tc suppression displayed in currently obtained MgB2 films by various techniques may arise from the different levels of disorder present in the film or different extents of proximity effect at the film surface or film-substrate interface.

  3. Superconducting detector of IR single-photons based on thin WSi films

    NASA Astrophysics Data System (ADS)

    Seleznev, V. A.; Divochiy, A. V.; Vakhtomin, Yu B.; Morozov, P. V.; Zolotov, P. I.; Vasil'ev, D. D.; Moiseev, K. M.; Malevannaya, E. I.; Smirnov, K. V.

    2016-08-01

    We have developed the deposition technology of WSi thin films 4 to 9 nm thick with high temperature values of superconducting transition (Tc~4 K). Based on deposed films there were produced nanostructures with indicative planar sizes ~100 nm, and the research revealed that even on nanoscale the films possess of high critical temperature values of the superconducting transition (Tc~3.3-3.7 K) which certifies high quality and homogeneity of the films created. The first experiments on creating superconducting single-photon detectors showed that the detectors’ SDE (system detection efficiency) with increasing bias current (I b) reaches a constant value of ~30% (for X=1.55 micron) defined by infrared radiation absorption by the superconducting structure. To enhance radiation absorption by the superconductor there were created detectors with cavity structures which demonstrated a practically constant value of quantum efficiency >65% for bias currents Ib>0.6-Ic. The minimal dark counts level (DC) made 1 s-1 limited with background noise. Hence WSi is the most promising material for creating single-photon detectors with record SDE/DC ratio and noise equivalent power (NEP).

  4. Co-sputtered MoRe thin films for carbon nanotube growth-compatible superconducting coplanar resonators

    NASA Astrophysics Data System (ADS)

    Götz, K. J. G.; Blien, S.; Stiller, P. L.; Vavra, O.; Mayer, T.; Huber, T.; Meier, T. N. G.; Kronseder, M.; Strunk, Ch; Hüttel, A. K.

    2016-04-01

    Molybdenum rhenium alloy thin films can exhibit superconductivity up to critical temperatures of {T}{{c}}=15 {{K}}. At the same time, the films are highly stable in the high-temperature methane/hydrogen atmosphere typically required to grow single wall carbon nanotubes. We characterize molybdenum rhenium alloy films deposited via simultaneous sputtering from two sources, with respect to their composition as function of sputter parameters and their electronic dc as well as GHz properties at low temperature. Specific emphasis is placed on the effect of the carbon nanotube growth conditions on the film. Superconducting coplanar waveguide resonators are defined lithographically; we demonstrate that the resonators remain functional when undergoing nanotube growth conditions, and characterize their properties as function of temperature. This paves the way for ultra-clean nanotube devices grown in situ onto superconducting coplanar waveguide circuit elements.

  5. Co-sputtered MoRe thin films for carbon nanotube growth-compatible superconducting coplanar resonators.

    PubMed

    Götz, K J G; Blien, S; Stiller, P L; Vavra, O; Mayer, T; Huber, T; Meier, T N G; Kronseder, M; Strunk, Ch; Hüttel, A K

    2016-04-01

    Molybdenum rhenium alloy thin films can exhibit superconductivity up to critical temperatures of T(c)=15K. At the same time, the films are highly stable in the high-temperature methane/hydrogen atmosphere typically required to grow single wall carbon nanotubes. We characterize molybdenum rhenium alloy films deposited via simultaneous sputtering from two sources, with respect to their composition as function of sputter parameters and their electronic dc as well as GHz properties at low temperature. Specific emphasis is placed on the effect of the carbon nanotube growth conditions on the film. Superconducting coplanar waveguide resonators are defined lithographically; we demonstrate that the resonators remain functional when undergoing nanotube growth conditions, and characterize their properties as function of temperature. This paves the way for ultra-clean nanotube devices grown in situ onto superconducting coplanar waveguide circuit elements. PMID:26901846

  6. In situ electrical transport measurementof superconductive ultrathin films

    NASA Astrophysics Data System (ADS)

    Liu, Can-Hua; Jia, Jin-Feng

    2015-11-01

    The discovery of an extraordinarily superconductive large energy gap in SrTiO3 supported single-layer FeSe films has recently initiated a great deal of research interests in surface-enhanced superconductivity and superconductive ultrathin films fabricated on crystal surfaces. On account of the instability of ultra-thin films in air, it is desirable to perform electrical transport measurement in ultra-high vaccum (UHV). Here we review the experimental techniques of in situ electrical transport measurement and their applications on superconductive ultrathin films. The work in SJTU was supported by the National Basic Research Program of China (Grant Nos. 2013CB921902 and 2011CB922200) and the National Natural Science Foundation of China (Grant Nos. 11227404, 11274228, 11521404, 11174199, and 11134008).

  7. High temperature nitrogen oxides sensing enabled by indium oxide thin films

    NASA Astrophysics Data System (ADS)

    Kannan, Srinivasan

    Generation of power using fossil fuel combustion invariably results in formation of undesirable gas species (NOx, SOx, CO, CO2, etc.) at high-temperatures which are harmful to the environment. Thus, there is a continual need to develop sensitive, responsive, stable, selective, robust and low-cost sensor systems and sensor materials for combustion monitoring. This work investigates the viability of microfabricated NO x sensors based on sputtered indium oxide (In2O3) utilizing microhotplate structures. The material becomes resistive when exposed to oxidizing gases like NOx, with its conductivity dependent upon the temperature, partial pressure of the test gas and morphological structure. We believe this device would help increase efficiency and decrease emissions through improved combustion process control, leading to a comparably economic and responsive sensor. In this work, more than 600 sensors were fabricated and tested, including RF and pulsed-DC sputtered films. About 50 unique sensor conditions were characterized and related to the gas sensor response. The sensor conditions included deposition parameters (power, pressure, time, etc.) and postdeposition processes (anneals, promoter layers, etc.). In2O3 thin films were RF sputter deposited on microhotplate structures with different thickness (40 to 300 nm) in pure Ar. Additionally, a combination of reactive and RF sputtering of In2O3 material was-deposited in Ar and O2 (10% and 25%) mixture. In2O3 films without promoter layers and with gold or TiOx promoter layers (~ 3 nm) were investigated for NOx sensing. Selectivity, stability and repeatability of indium oxide (In2O3) thin film sensor to detect NOx (25 ppm) in presence of other exhaust gas pollutants including H2, NH3 and CO2 at high operating temperatures (greater than 350 °C) was investigated in N2 carrier gas. In2O 3 films (150nm thick) deposited in Ar and O2 (25% O 2) presented the highest response (S ~ 50) to 25 ppm NOx at 500 °C when compared to films

  8. High temperature superconductor materials and applications

    NASA Technical Reports Server (NTRS)

    Doane, George B., III.; Banks, Curtis; Golben, John

    1990-01-01

    Research on processing methods leading to a significant enhancement in the critical current densities (Jc) and the critical temperature (Tc) of high temperature superconducting in thin bulk and thin film forms. The fabrication of important devices for NASA unique applications (sensors) is investigated.

  9. Effect of surface condition on the formation of solid lubricating films at high temperatures

    NASA Technical Reports Server (NTRS)

    Hanyaloglu, Bengi; Graham, E. E.

    1992-01-01

    Solid films were produced on active metal or ceramic surfaces using lubricants (such as tricresyl phosphate) delivered as a vapor at high temperatures, and the lubricity of these deposits under different dynamic wear conditions was investigated. A method is described for chemically activating ceramic surfaces resulting in a surface that could promote the formation of lubricating polymeric derivative of TCP. Experiments were carried out to evaluate the wear characteristics of unlubricated cast iron and of Sialon ceramic at 25 and 280 C, and lubricated with a vapor of TCP at 280 C. It is shown that continuous vapor phase lubrication of chemically treated Sialon reduced its coefficient of friction from 0.7 to less than 0.1.

  10. SiC Nanowire Film Photodetectors: A Promising Candidate Toward High Temperature Photodetectors.

    PubMed

    Chong, Haining; Yang, Huijun; Yang, Weiyou; Zheng, Jinju; Shang, Minghui; Yang, Zuobao; Wei, Guodong; Gao, Fengmei

    2016-04-01

    In this study, UV photodetectors (PDs) based on SiC nanowire films have been successfully prepared by a simple and low-cost drip-coating method followed by sintering at 500 °C. The corresponding electrical characterizations clearly demonstrate that the SiC nanowire based PD devices can be regarded as a promising candidate for UV PDs. The PDs can exhibit the excellent performances of fast, high sensitivity, linearity, and stable response, which can thus achieve on-line monitoring of weak UV light. Furthermore, the SiC nanowire-based PDs enable us to fabricate detectors working under high temperature as high as 150 °C. The high photosensitivity and rapid photoresponse for the PDs can be attributed to the superior single crystalline quality of SiC nanowires and the ohmic contact between the electrodes and nanowires. PMID:27451712

  11. Studies to Enhance Superconductivity in Thin Film Carbon

    NASA Astrophysics Data System (ADS)

    Pierce, Benjamin; Brunke, Lyle; Burke, Jack; Vier, David; Steckl, Andrew; Haugan, Timothy

    2012-02-01

    With research in the area of superconductivity growing, it is no surprise that new efforts are being made to induce superconductivity or increase transition temperatures (Tc) in carbon given its many allotropic forms. Promising results have been published for boron doping in diamond films, and phosphorus doping in highly oriented pyrolytic graphite (HOPG) films show hints of superconductivity.. Following these examples in the literature, we have begun studies to explore superconductivity in thin film carbon samples doped with different elements. Carbon thin films are prepared by pulsed laser deposition (PLD) on amorphous SiO2/Si and single-crystal substrates. Doping is achieved by depositing from (C1-xMx) single-targets with M = B4C and BN, and also by ion implantation into pure-carbon films. Previous research had indicated that Boron in HOPG did not elicit superconducting properties, but we aim to explore that also in thin film carbon and see if there needs to be a higher doping in the sample if trends were able to be seen in diamond films. Higher onset temperatures, Tc , and current densities, Jc, are hoped to be achieved with doping of the thin film carbon with different elements.

  12. Common electronic origin of superconductivity in (Li,Fe)OHFeSe bulk superconductor and single-layer FeSe/SrTiO3 films.

    PubMed

    Zhao, Lin; Liang, Aiji; Yuan, Dongna; Hu, Yong; Liu, Defa; Huang, Jianwei; He, Shaolong; Shen, Bing; Xu, Yu; Liu, Xu; Yu, Li; Liu, Guodong; Zhou, Huaxue; Huang, Yulong; Dong, Xiaoli; Zhou, Fang; Liu, Kai; Lu, Zhongyi; Zhao, Zhongxian; Chen, Chuangtian; Xu, Zuyan; Zhou, X J

    2016-02-08

    The mechanism of high-temperature superconductivity in the iron-based superconductors remains an outstanding issue in condensed matter physics. The electronic structure plays an essential role in dictating superconductivity. Recent revelation of distinct electronic structure and high-temperature superconductivity in the single-layer FeSe/SrTiO3 films provides key information on the role of Fermi surface topology and interface in inducing or enhancing superconductivity. Here we report high-resolution angle-resolved photoemission measurements on the electronic structure and superconducting gap of an FeSe-based superconductor, (Li0.84Fe0.16)OHFe0.98Se, with a Tc at 41 K. We find that this single-phase bulk superconductor shows remarkably similar electronic behaviours to that of the superconducting single-layer FeSe/SrTiO3 films in terms of Fermi surface topology, band structure and the gap symmetry. These observations provide new insights in understanding high-temperature superconductivity in the single-layer FeSe/SrTiO3 films and the mechanism of superconductivity in the bulk iron-based superconductors.

  13. Common electronic origin of superconductivity in (Li,Fe)OHFeSe bulk superconductor and single-layer FeSe/SrTiO3 films

    PubMed Central

    Zhao, Lin; Liang, Aiji; Yuan, Dongna; Hu, Yong; Liu, Defa; Huang, Jianwei; He, Shaolong; Shen, Bing; Xu, Yu; Liu, Xu; Yu, Li; Liu, Guodong; Zhou, Huaxue; Huang, Yulong; Dong, Xiaoli; Zhou, Fang; Liu, Kai; Lu, Zhongyi; Zhao, Zhongxian; Chen, Chuangtian; Xu, Zuyan; Zhou, X. J.

    2016-01-01

    The mechanism of high-temperature superconductivity in the iron-based superconductors remains an outstanding issue in condensed matter physics. The electronic structure plays an essential role in dictating superconductivity. Recent revelation of distinct electronic structure and high-temperature superconductivity in the single-layer FeSe/SrTiO3 films provides key information on the role of Fermi surface topology and interface in inducing or enhancing superconductivity. Here we report high-resolution angle-resolved photoemission measurements on the electronic structure and superconducting gap of an FeSe-based superconductor, (Li0.84Fe0.16)OHFe0.98Se, with a Tc at 41 K. We find that this single-phase bulk superconductor shows remarkably similar electronic behaviours to that of the superconducting single-layer FeSe/SrTiO3 films in terms of Fermi surface topology, band structure and the gap symmetry. These observations provide new insights in understanding high-temperature superconductivity in the single-layer FeSe/SrTiO3 films and the mechanism of superconductivity in the bulk iron-based superconductors. PMID:26853801

  14. Low-loss substrate for epitaxial growth of high-temperature superconductor thin films

    SciTech Connect

    Simon, R.W.; Platt, C.E.; Lee, A.E.; Lee, G.S.; Daly, K.P.; Wire, M.S.; Luine, J.A.; Urbanik, M.

    1988-12-26

    A perovskite-like single-crystal substrate material has been investigated that simultaneously permits epitaxial growth of 1-2-3 superconductor films and possesses desirable rf properties of low dielectric constant and loss tangent. The lattice constant of 3.792 A provides a lattice match to within 1% of the a axis of 1-2-3. Sputtered films of erbium-barium-copper-oxide have been produced on (100) LaAlO/sub 3/ substrates that exhibit sharp resistive transitions at 90 K (..delta..T = 1K), bulk superconductivity as determined by ac susceptibility measurements, and nearly single-crystal growth as evidenced by x-ray diffraction and high-resolution scanning electron microscopy. The high-frequency dielectric properties of LaAlO/sub 3/ were experimentally investigated at several temperatures. The low-frequency dielectric constant was measured to be 15 and the microwave loss tangent ranged from 6 x 10/sup -4/ at room temperature to 5 x 10/sup -6/ at 4 K.

  15. Characterization of a high-temperature superconducting conductor on round core cables in magnetic fields up to 20 T

    SciTech Connect

    van der Laan, D. C.; Noyes, P. D.; Miller, G. E.; Weijers, H. W.; Willering, G. P.

    2013-02-13

    The next generation of high-ï¬eld magnets that will operate at magnetic ï¬elds substantially above 20 T, or at temperatures substantially above 4.2 K, requires high-temperature superconductors (HTS). Conductor on round core (CORC) cables, in which RE-Ba{sub 2}Cu{sub 3}O{sub 7-{delta}} (RE = rare earth) (REBCO) coated conductors are wound in a helical fashion on a flexible core, are a practical and versatile HTS cable option for low-inductance, high-field magnets. We performed the first tests of CORC magnet cables in liquid helium in magnetic fields of up to 20 T. A record critical current I{sub c} of 5021 A was measured at 4.2 K and 19 T. In a cable with an outer diameter of 7.5 mm, this value corresponds to an engineering current density J{sub e} of 114 A mm{sup -2} , the highest J{sub e} ever reported for a superconducting cable at such high magnetic fields. Additionally, the first magnet wound from an HTS cable was constructed from a 6 m-long CORC cable. The 12-turn, double-layer magnet had an inner diameter of 9 cm and was tested in a magnetic field of 20 T, at which it had an I{sub c} of 1966 A. The cables were quenched repetitively without degradation during the measurements, demonstrating the feasibility of HTS CORC cables for use in high-field magnet applications.

  16. Thermal Cycling Behavior of Zinc Antimonide Thin Films for High Temperature Thermoelectric Power Generation Applications.

    PubMed

    Shim, Hyung Cheoul; Woo, Chang-Su; Han, Seungwoo

    2015-08-19

    The zinc antimonide compound ZnxSby is one of the most efficient thermoelectric materials known at high temperatures due to its exceptional low thermal conductivity. For this reason, it continues to be the focus of active research, especially regarding its glass-like atomic structure. However, before practical use in actual surroundings, such as near a vehicle manifold, it is imperative to analyze the thermal reliability of these materials. Herein, we present the thermal cycling behavior of ZnxSby thin films in nitrogen (N2) purged or ambient atmosphere. ZnxSby thin films were prepared by cosputtering and reached a power factor of 1.39 mW m(-1) K(-2) at 321 °C. We found maximum power factor values gradually decreased in N2 atmosphere due to increasing resistivity with repeated cycling, whereas the specimen in air kept its performance. X-ray diffraction and electron microscopy observations revealed that fluidity of Zn atoms leads to nanoprecipitates, porous morphologies, and even growth of a coating layer or fiber structures on the surface of ZnxSby after repetitive heating and cooling cycles. With this in mind, our results indicate that proper encapsulation of the ZnxSby surface would reduce these unwanted side reactions and the resulting degradation of thermoelectric performance.

  17. Synthesis and characterization of novel piezoelectric nitrile copolyimide films for high temperature sensor applications

    NASA Astrophysics Data System (ADS)

    Maceiras, A.; Martins, P.; San Sebastián, M.; Lasheras, A.; Silva, M.; Laza, J. M.; Vilas, J. L.; Gutierrez, J.; Lanceros-Mendez, S.; Barandiarán, J. M.; León, L. M.

    2014-10-01

    A series of amorphous polyimides and copolyimides that contained nitrile were obtained by a two-step procedure. The first step consisted of a polycondensation reaction of 4,4’-oxydiphtalic anhydride (ODPA) with one or two aromatic diamines, namely 1,3-Bis-2-cyano-3-(3-aminophenoxy)phenoxybenzene (diamine 2CN) and 1,3-Bis(3-aminophenoxy)benzene (diamine 0CN). In the second step, a thermal cyclodehydration converted each poly(amic acid) or copoly(amic acid) into their corresponding polyimide films. The piezoelectric response was improved after corona poling of the films. A maximum d33 modulus value of 16 pC N-1 was obtained for the polymide with two cyano groups (poly 2CN). The polarization also showed time and thermal stability up to 160 °C. Additionally, the thermal stability of the amorphous polyimides, (β-CN)APB/ODPA, was studied by determining the glass transition temperature (T g ) and thermal decomposition through differential scanning calorimetry (DSC) and thermogravimetric analysis (TG), respectively. The high piezoelectric response (1-16 pC N-1), T g (160-180 °C) and degradation temperature (315-450 °C) make such polyamides excellent candidates for use as high temperature sensors.

  18. Process for preparing superconducting film having substantially uniform phase development

    SciTech Connect

    Bharacharya, R.; Parilla, P.A.; Blaugher, R.D.

    1995-12-19

    A process is disclosed for preparing a superconducting film, such as a thallium-barium-calcium-copper oxide superconducting film, having substantially uniform phase development. The process comprises providing an electrodeposition bath having one or more soluble salts of one or more respective potentially superconducting metals in respective amounts adequate to yield a superconducting film upon subsequent appropriate treatment. Should all of the metals required for producing a superconducting film not be made available in the bath, such metals can be a part of the ambient during a subsequent annealing process. A soluble silver salt in an amount between about 0.1% and about 4.0% by weight of the provided other salts is also provided to the bath, and the bath is electrically energized to thereby form a plated film. The film is annealed in ambient conditions suitable to cause formation of a superconductor film. Doping with silver reduces the temperature at which the liquid phase appears during the annealing step, initiates a liquid phase throughout the entire volume of deposited material, and influences the nucleation and growth of the deposited material. 3 figs.

  19. Process for preparing superconducting film having substantially uniform phase development

    SciTech Connect

    Bharacharya, Raghuthan; Parilla, Philip A.; Blaugher, Richard D.

    1995-01-01

    A process for preparing a superconducting film, such as a thallium-barium-calcium-copper oxide superconducting film, having substantially uniform phase development. The process comprises providing an electrodeposition bath having one or more soluble salts of one or more respective potentially superconducting metals in respective amounts adequate to yield a superconducting film upon subsequent appropriate treatment. Should all of the metals required for producing a superconducting film not be made available in the bath, such metals can be a part of the ambient during a subsequent annealing process. A soluble silver salt in an amount between about 0.1% and about 4.0% by weight of the provided other salts is also provided to the bath, and the bath is electrically energized to thereby form a plated film. The film is annealed in ambient conditions suitable to cause formation of a superconductor film. Doping with silver reduces the temperature at which the liquid phase appears during the annealing step, initiates a liquid phase throughout the entire volume of deposited material, and influences the nucleation and growth of the deposited material.

  20. High-Tc Superconducting Thin- and Thick-Film-Based Coated Conductors for Energy Applications

    SciTech Connect

    Cantoni, Claudia; Goyal, Amit

    2010-01-01

    Although the first epitaxial films of YBCO with high Tc were grown nearly 20 years ago, the understanding and control of the nanostructures responsible for the dissipation-free electrical current transport in high temperature superconductors (HTS) is quite recent. In the last six to seven years, major advances have occurred in the fundamental investigation of low angle grain boundaries, flux-pinning phenomena, growth mode, and atomic-level defect structures of HTS epitaxial films. As a consequence, it has been possible to map and even engineer to some extent the performance of HTS coatings in large regions of the operating H, T, J phase space. With such progress, the future of high temperature superconducting wires looks increasingly promising despite the tremendous challenges offered by these brittle and anisotropic materials. Nevertheless, further performance improvements are necessary for the superconducting technology to become cost-competitive against copper wires and ultimately succeed in revolutionizing the transmission of electricity. This can be achieved by further diminishing the gap between theoretical and experimental values of the critical current density Jc, and/or increasing the thickness of the superconductive layer as much as possible without degrading performance. In addition, further progress in controlling extrinsic and/or intrinsic nano-sized defects within the films is necessary to significantly reduce the anisotropic response of HTS and obtain a nearly constant dependence of the critical current on the magnetic field orientation, which is considered crucial for power applications. This chapter is a review of the challenges still present in the area of superconducting film processing for HTS wires and the approaches currently employed to address them.

  1. In-situ integrated processing and characterization of thin films of high temperature superconductors, dielectrics and semiconductors by MOCVD

    NASA Technical Reports Server (NTRS)

    Singh, R.; Sinha, S.; Hsu, N. J.; Thakur, R. P. S.; Chou, P.; Kumar, A.; Narayan, J.

    1991-01-01

    In this strategy of depositing the basic building blocks of superconductors, semiconductors, and dielectrics having common elements, researchers deposited superconducting films of Y-Ba-Cu-O, semiconductor films of Cu2O, and dielectric films of BaF2 and Y2O3 by metal oxide chemical vapor deposition (MOCVD). By switching source materials entering the chamber, and by using direct writing capability, complex device structures like three terminal hybrid semiconductor/superconductor transistors can be fabricated. The Y-Ba-Cu-O superconducting thin films on BaF2/YSZ substrates show a T(sub c) of 80 K and are textured with most of the grains having their c-axis or a-axis perpendicular to the substrate. Electrical characteristics as well as structural characteristics of superconductors and related materials obtained by x-ray deffraction, electron microscopy, and energy dispersive x-ray analysis are discussed.

  2. Physical and Material Properties of Yttrium Barium Copper Oxide High Critical Temperature Superconducting Thin Films.

    NASA Astrophysics Data System (ADS)

    Ma, Qiyuan

    1990-01-01

    A simple method of using layered structures and rapid thermal annealing to produce Y_1 Ba_2 Cu_3 O_{7-x} (YBCO) superconducting thin films is presented. Material properties of the films depend strongly on the processing conditions, the film stoichiometry, and the substrates. The films with critical temperature (T_{ rm c}) higher than liquid nitrogen temperature (77 K) have been made on various substrates including magnesium oxide, sapphire, and silicon. The best film was obtained on a MgO substrate with T_{rm c} of 84 K. Silicon diffusion and reaction with oxygen during a high temperature anneal degrade the superconductivity of the film on a Si substrate. Using a buffer layer of gold, the Si-YBCO interaction is greatly reduced. Typical resistivity of the film shows a linear temperature dependence which may be attributed to an electron -phonon interaction. Anisotropic resistance behavior has been observed due to the layered structures. Different metal contacts to the YBCO films have been used to study the chemical and electrical properties of metal-YBCO film interfaces. Gold has been found nonreactive to YBCO film, thus, it has the lowest contact resistivity. Near the T_{rm c}, the contact resistivity of a Au-YBCO contact approaches zero. This may be due to the proximity effect. Other metals such as Pt, Pd, Sn and Ti, react with the YBCO film and form thin oxide layers at the interfaces. The oxide layer acts as an insulating barrier which forbids the proximity effect and causes a large contact resistivity. The structural and electrical properties of the Si-YBCO intermixed film have been studied for different thicknesses of the silicon layers. A novel patterning technique of using Si-YBCO intermixing has been developed for fabricating the YBCO superconducting device structures. A superconductor sample has a critical current value I _{rm c}. Below the I _{rm c} the material is superconducting, and above I_{rm c} the sample has a finite resistance. Based on this effect

  3. Neutron scattering studies of spin-phonon hybridization and superconducting spin gaps in the high temperature superconductor La2-x(Sr;Ba)xCuO4

    DOE PAGES

    Wagman, J. J.; Carlo, Jeremy P.; Gaudet, J.; Van Gastel, G. J.; Abernathy, Douglas L.; Stone, Matthew B.; Granroth, Garrett E.; Kolesnikov, Alexander I.; Savici, Andrei T.; Kim, Young -June; et al

    2016-03-14

    We present time-of-flight neutron-scattering measurements on single crystals of La2-xBaxCuO4 (LBCO) with 0 ≤ x ≤ 0.095 and La2-xSrxCuO4 (LSCO) with x = 0.08 and 0.11. This range of dopings spans much of the phase diagram relevant to high temperature cuprate superconductivity, ranging from insulating, three dimensional commensurate long range antiferromagnetic order for x ≤ 0.02 to two dimensional (2D) incommensurate antiferromagnetism co-existing with superconductivity for x ≥ 0.05. Previous work on lightly doped LBCO with x = 0.035 showed a clear resonant enhancement of the inelastic scattering coincident with the low energy crossings of the highly dispersive spin excitationsmore » and quasi-2D optic phonons. The present work extends these measurements across the phase diagram and shows this enhancement to be a common feature to this family of layered quantum magnets. Furthermore we show that the low temperature, low energy magnetic spectral weight is substantially larger for samples with non-superconducting ground states relative to any of the samples with superconducting ground states. Lastly spin gaps, suppression of low energy magnetic spectral weight, are observed in both superconducting LBCO and LSCO samples, consistent with previous observations for superconducting LSCO« less

  4. Superconductive thin film makes convenient liquid helium level sensor

    NASA Technical Reports Server (NTRS)

    Becker, H. H.

    1968-01-01

    Sensor consisting of superconductive film mounted on a dipstick measures the level of liquid helium in a Dewar flask. The sensor is made by depositing a thin film of niobium metal to a thickness of 2000 angstroms on a quartz substrate, which is then mounted on a graduated dipstick.

  5. Plasmonic-Based High Temperature Chemical Sensing Using Gold Nanoparticles Embedded in Metal Oxide Thin Films

    NASA Astrophysics Data System (ADS)

    Joy, Nicholas

    Thin metal oxide films embedded with Au nanoparticles (AuNPs) have been investigated as high temperature localized surface plasmon resonance (LSPR) based sensing materials to monitor H2, CO, and NO2 at a temperature of 500°C. Applications for this technology include turbine engines as well as other combustion environments where it is important to monitor emission gases for both regulatory purposes as well as combustion control. These high temperature applications, which may be oxidizing or reducing in nature, present challenges to sensor reliability and selectivity, and have therefore necessitated the development of novel sensing devices. While there has been work on developing semiconductor-based electrical sensing methods, this work examines the optical response of AuNPs in yttria-stabilized zirconia (YSZ), TiO2, and CeO2. The main challenge with this technique is to achieve a selective response to the target gases. As a means of addressing this issue, both materials and data analysis techniques have been investigated. From the materials aspect, a sensor array was developed for a direct comparison of Au-YSZ, Au-TiO2, and Au-CeO2. In order to analyze the data, the multivariate method of principle component analysis was applied. The result of this analysis showed that a unique response was seen for each of the three target gases during separate exposures, which is an initial step towards selective detection in a gas mixture. Additional material control has also been achieved with the use of electron beam lithography to pattern Au nanoparticles for size and shape control. A particular emphasis has been placed on the nanorod geometry due to its tunable longitudinal LSPR peak; however, thermal stability of this geometry has been a challenge. Encapsulating the Au nanorods with YSZ was shown to help stabilize the nanorods for sensing tests performed at 500°C. Apart from material control, a kinetics analysis has also been performed for H2 reactions with Au-YSZ in an

  6. Effects of high-temperature thermal annealing on the electronic properties of In-Ga-Zn oxide thin films

    SciTech Connect

    Li, Qin; Song, Zhong Xiao; Ma, Fei E-mail: liyhemail@gmail.com; Li, Yan Huai E-mail: liyhemail@gmail.com; Xu, Ke Wei

    2015-03-15

    Indium gallium zinc oxide (IGZO) thin films were deposited by radio-frequency magnetron sputtering at room-temperature. Then, thermal annealing was conducted to improve the structural ordering. X-ray diffraction and high-resolution transmission electron microscopy demonstrated that the as-deposited IGZO thin films were amorphous and crystallization occurred at 800 and 950 °C. As a result of crystallization at high temperature, the carrier concentration and the Hall mobility of IGZO thin films were sharply increased, which could be ascribed to the increased oxygen vacancies and improved structural ordering of the thin films.

  7. Neutral wetting brush layers for block copolymer thin films using homopolymer blends processed at high temperatures.

    PubMed

    Ceresoli, M; Palermo, M; Ferrarese Lupi, F; Seguini, G; Perego, M; Zuccheri, G; Phadatare, S D; Antonioli, D; Gianotti, V; Sparnacci, K; Laus, M

    2015-10-16

    Binary homopolymer blends of two hydroxyl-terminated polystyrene (PS-OH) and polymethylmethacrylate (PMMA-OH) homopolymers (Mn ∼ 16000 g mol(-1)) were grafted on SiO2 substrates by high-temperature (T > 150 °C), short-time (t < 600 s) thermal treatments. The resulting brush layer was tested to screen preferential interactions of the SiO2 substrate with the different symmetric and asymmetric PS-b-PMMA block copolymers deposited on top of the grafted molecules. By properly adjusting the blend composition and the processing parameters, an efficient surface neutralization path was identified, enabling the formation, in the block copolymer film, of homogeneous textures of lamellae or cylinders perpendicularly oriented with respect to the substrate. A critical interplay between the phase segregation of the homopolymer blends and their grafting process on the SiO2 was observed. In fact, the polar SiO2 is preferential for the PMMA-rich phase that forms a homogeneous layer on the substrate, while the PS-rich phase is located at the polymer-air interface. During the thermal treatment, phase segregation and grafting proceed simultaneously. Complete wetting of the PS rich phase on the PMMA rich phase leads to the formation of a PS/PMMA bilayer. In this case, the progressive diffusion of PS chains toward the polymer-SiO2 interface during the thermal treatment allows tuning of the brush layer composition.

  8. Resistance of Spores of Bacillus subtilis var. niger on Kapton and Teflon Film to High Temperature and Dry Heat

    PubMed Central

    Bruch, Mary K.; Smith, Frederick W.

    1968-01-01

    To determine parameters that would assure sterility of a sealed seam of film for application in “split-seam entry,” spores of Bacillus subtilis var. niger were sprayed onto pieces of Kapton and Teflon film. Short-time, high-temperature (200 to 270 C) exposures were made with film pieces between aluminum blocks in a hot-air oven, and the D and z values were determined after subculture of surviving spores. The use of Kapton film allowed the study of high temperatures, since it is not heat sealable and could be used to make thin packages for heat treatment. Spores on Teflon were dry-heat treated in a package designed to simulate an actual seam to be sealed. The z values of 29.1 C (52.4 F) for spores on Kapton and 139 C (250.4 F) for spores on Teflon were calculated. Images Fig. 1 Fig. 2 Fig. 3 PMID:4973071

  9. Dissipation in thin superconducting current biased films due to vortex motion

    SciTech Connect

    Bulaevskii, Lev N

    2009-01-01

    Recently, the problem of dissipation in thin superconducting films with thickness d on the order of the coherence length {zeta}, and width {omega} much narrower than the Pearl length, {Lambda} >> {omega} >> {zeta}, was discussed as the main cause for the behavior of I-V characteristics observed in thin high-temperature superconducting films. In thin and narrow films or strips with width w >> {zeta} the barrier for phase slips by creation of temporary normal regions across the entire film width is too big, thus phase slips become highly improbable. Instead, we consider a vortex crossing the strip from one edge to the other, perpendicular to the bias current, as the dominant mechanism for generalized phase slips resulting in detectable voltage pulses. We derive the rate of vortex crossings using the general theory of transition rates between metastable states. In mean field theory, the saddle point solution of the rate equation gives the vortex position inside the strip, where the kinetic energy of supercurrents is maximum. However, the free energy barrier derived in such an approach is strongly renormalized by superconducting fluctuations and this effect was not accounted for previously. They drastically reduce the rate of vortex crossings and, consequently, dissipation. We present results for the amplitude and duration of voltage pulses induced by vortex motion and their consequences on I-V characteristics, when heating due to vortex crossings is negligible. We found ohmic behavior at low bias currents, power law behavior at intermediate currents and exponential I-V characteristics at currents close to the critical one. The impact of vortex motion in superconducting strips on the observation of so-called dark counts (voltage pulses) in superconducting nanowire single-photon detectors is discussed.

  10. Buffer layers for deposition of superconducting YBaCuO thin film on polycrystalline diamond

    NASA Astrophysics Data System (ADS)

    Beetz, Charles P.; Cui, G. J.; Lincoln, B. A.; Kirlin, Peter S.

    1992-09-01

    In an attempt to combine the properties of high temperature superconductors with the high thermal conductivity and low specific heat of diamond, we have explored the deposition of in- situ YBa(subscript 2)Cu(subscript 3)O(subscript 7-(delta) ) (YBCO) superconducting films on polycrystalline diamond thin films. We demonstrate for the first time superconducting YBCO films on diamond employing multiple layer buffer layer systems. Three different composite buffer layer systems were explored for this purpose: (1) Diamond/Zr/YSZ/YBCO, (2) Diamond/Si(subscript 3)N(subscript 4)/YSZ/YBCO, and (3) Diamond/SiO(subscript 2)/YSZ/YBCO. Adherent thin Zr films were deposited by dc sputtering on the diamond films at 450 to 820 degree(s)C. The yttria stabilized zirconia (YSZ) was deposited by reactive RF sputtering at 680 to 750 degree(s)C. The Si(subscript 3)N(subscript 4) and SiO(subscript 2) were also deposited by on-axis RF sputtering at 400 to 700 degree(s)C. YBCO films were grown on the buffer layers by off-axis RF sputtering at substrate temperatures between 690 degree(s)C and 750 degree(s)C. In all cases, the as-deposited YBCO films were superconducting above 77 K. This demonstration enables the fabrication of low heat capacity, fast response time bolometric far IR detectors and paves the way for the use of HTSC as a high frequency interconnect metallization on thick diamond film based multichip modules.

  11. Optical and electrical properties of thin superconducting films

    NASA Technical Reports Server (NTRS)

    Covington, Billy C.; Jing, Feng Chen

    1990-01-01

    Infrared spectroscopic techniques can provide a vital probe of the superconducting energy gap which is one of the most fundamental physical properties of superconductors. Currently, the central questions regarding the optical properties of superconductors are how the energy gap can be measured by infrared techniques and at which frequency the gap exists. An effective infrared spectroscopic method to investigate the superconducting energy gap, Eg, was developed by using the Bomem DA 3.01 Fourier Transformation Spectrophotometer. The reflectivity of a superconducting thin film of YBaCuO deposited on SrTiO3 was measured. A shoulder was observed in the superconducting state reflectance R(sub S) at 480/cm. This gives a value of Eg/kT(sub c) = 7.83, where k is the Boltzmann constant and T(sub c) is the superconducting transition temperature, from which, it is suggested that YBaCuO is a very strong coupling superconductor.

  12. Jet Propulsion Laboratory/NASA Lewis Research Center space qualified hybrid high temperature superconducting/semiconducting 7.4 GHz low-noise downconverter for NRL HTSSE-II program

    SciTech Connect

    Javadi, H.H.S.; Bowen, J.G.; Rascoe, D.L.; Romanofsky, R.R.; Bhasin, K.B.; Chorey, C.M.

    1996-07-01

    A deep space satellite downconverter receiver was proposed by Jet Propulsion Laboratory (JPL) and NASA Lewis Research Center (LeRC) for the Naval Research Laboratory`s (NRL) high temperature superconductivity space experiment, phase-II (HTSSE-II) program. Space qualified low-noise cryogenic downconverter receivers utilizing thin-film high temperature superconducting (HTS) passive circuitry and semiconductor active devices were developed and delivered to NRL. The downconverter consists of an HTS preselect filter, a cryogenic low-noise amplifier, a cryogenic mixer, and a cryogenic oscillator with an HTS resonator. HTS components were inserted as the front-end filter and the local oscillator resonator for their superior 77 K performance over the conventional components. The semiconducting low noise amplifier also benefited from cooling to 77 K. The mixer was designed specifically for cryogenic applications and provided low conversion loss and low power consumption. In addition to an engineering model, two space qualified units (qualification, flight) were built and delivered to NRL. Manufacturing, integration and test of the space qualified downconverters adhered to the requirements of JPL class-D space instruments and partially to MIL-STD-883D specifications. The qualification unit has {approximately}50 K system noise temperature which is a factor of three better than a conventional downconverter at room temperature.

  13. Superconductivity of very thin films: The superconductor-insulator transition

    NASA Astrophysics Data System (ADS)

    Lin, Yen-Hsiang; Nelson, J.; Goldman, A. M.

    2015-07-01

    The study of thin superconducting films has been an important component of the science of superconductivity for more than six decades. It played a major role in the development of currently accepted views of the macroscopic and microscopic nature of the superconducting state. In recent years the focus of research in the field has shifted to the study of ultrathin films and surface and interface layers. This has permitted the exploration of one of the important topics of condensed matter physics, the superconductor-insulator transition. This review will discuss this phenomenon as realized in the study of metallic films, cuprates, and metallic interfaces. These are in effect model systems for behaviors that may be found in more complex systems of contemporary interest.

  14. Study of critical current density in superconducting magnesium diboride films grown by ex situ annealing of CVD boron films

    NASA Astrophysics Data System (ADS)

    Hanna, Mina

    MgB2 films have been processed by different techniques, the most successful of which include the hybrid physical-chemical vapor deposition (HPCVD) as well as the ex situ high temperature annealing of boron films in Mg vapor. The advantage of the ex situ method is that it allows the coating of MgB2 on large and complex surfaces, such as superconducting radio frequency (RF) cavities. However, it has always been realized that HPCVD films can carry higher J c than the ex situ annealed films. In this research, we succeeded in fabricating high quality MgB2 films by the ex situ annealing technique that produced a Jc value as high as 1.8 x 106 A/cm 2 for 1 mum thick film at 20 K and self-field. This high Jc value is, however, considerably reduced at higher thicknesses similar to that observed in YBCO coated conductors. In order to understand the mechanisms responsible for J c decrease with increasing film thickness, we studied the Jc behavior as a function of thickness in MgB2 films fabricated by ex situ annealing at 840°C of boron films, grown by chemical vapor deposition, in Mg vapor. The film thickness ranged between 300 nm and 10 mum. The values of Jc for these films ranged from 1.2 x 107 A/cm2 for 300 nm to 1.9 x 105 A/cm2 for 10 mum film thickness at 20 K and self-field. In addition, the results show that critical current (Ic) reaches a maximum value of 728 A/cm width at ˜1 mum thick MgB2 film at 20 K and self-field. These results of Jc and Ic behaviors with higher thickness are interpreted in terms of impurity diffusion during annealing and microstructural degradation for thicker films.

  15. Tribological properties at 25 C of seven polyimide films bonded to 440 C high-temperature stainless steel

    NASA Technical Reports Server (NTRS)

    Fusaro, R. L.

    1982-01-01

    The tribological properties of seven polyimide films applied to 440 C high temperature stainless steel substrates were studied at 25 C with a pin-on-disk type of friction and were apparatus. The polyimides fell into two groups according to friction and wear properties. Group I polyimides had slightly lower friction but much higher wear than group II polyimides. The wear mechanism was predominately adhesion, but the wear particles were larger for group I polyimides. For most of the polyimides the transfer films consisted of clumps of compacted wear particles. One polyimide composition produced a very thin transfer film that sheared plastically in the contact area.

  16. Large magnetoresistance of insulating silicon films with superconducting nanoprecipitates

    NASA Astrophysics Data System (ADS)

    Heera, V.; Fiedler, J.; Skorupa, W.

    2016-10-01

    We report on large negative and positive magnetoresistance in inhomogeneous, insulating Si:Ga films below a critical temperature of about 7 K. The magnetoresistance effect exceeds 300 % at temperatures below 3 K and fields of 8 T. The comparison of the transport properties of superconducting samples with that of insulating ones reveals that the large magnetoresistance is associated with the appearance of local superconductivity. A simple phenomenological model based on localized Cooper pairs and hopping quasiparticles is able to describe the temperature and magnetic field dependence of the sheet resistance of such films.

  17. First-principles prediction of MgB2-like NaBC: A more promising high-temperature superconducting material than LiBC

    NASA Astrophysics Data System (ADS)

    Miao, Rende; Huang, Guiqin; Yang, Jun

    2016-05-01

    Crystal structure, lattice dynamics, and superconducting properties for sodium borocarbides NaB1+xC1-x are investigated with first-principles calculations. Based on crystal structure analysis by particle swarm optimization methodology, NaBC is predicted to crystallize in the layered P63 / mmc crystal structure as LiBC. However, it is different from LiBC, in that Na atoms are effectively ionized, with no longitudinal covalence exist between Na and B-C layers, just as in the case of MgB2. Therefore, Na1-xBC is more similar to MgB2 than Li1-xBC as a potential high-temperature superconductor. Further more, we suggest that the slight hole doping of NaBC through partial substitution of C by B atoms can also produce cause superconductivity. The phonon spectra for NaBC and NaB1.1C0.9 are obtained within the virtual-crystal approximation treatment. There is a remarkable softening of the in-plane B-C bond-stretching modes for NaB1.1C0.9 in certain regions of the Brillouin zone, while other phonon bands show no obvious softening behavior. This conspicuous softening of the in-plane B-C bond-stretching modes indicates a strong electron-phonon coupling for them. The obtained total electron-phonon coupling strength λ for NaB1.1C0.9 is 0.73, and superconducting transition temperature TC is predicted to be 35 K (μ* = 0.1). This indicates that NaB1+xC1-x is potentially high-temperature superconducting and hole doping of NaBC could produce high-temperature superconductivity. In addition, we conjecture that, to design a MgB2-like high TC superconducting material, the longitudinal covalent bonds between the metal cations and graphite-like layers need be excluded.

  18. Microwave study of superconducting Sn films above and below percolation

    NASA Astrophysics Data System (ADS)

    Beutel, Manfred H.; Ebensperger, Nikolaj G.; Thiemann, Markus; Untereiner, Gabriele; Fritz, Vincent; Javaheri, Mojtaba; Nägele, Jonathan; Rösslhuber, Roland; Dressel, Martin; Scheffler, Marc

    2016-08-01

    The electronic properties of superconducting Sn films ({T}{{c}}≈ 3.8 {{K}}) change significantly when reducing the film thickness down to a few {nm}, in particular close to the percolation threshold. The low-energy electrodynamics of such Sn samples can be probed via microwave spectroscopy, e.g. with superconducting stripline resonators. Here we study Sn thin films, deposited via thermal evaporation—ranging in thickness between 38 and 842 {nm}—which encompasses the percolation transition. We use superconducting Pb stripline resonators to probe the microwave response of these Sn films in a frequency range between 4 and 20 {GHz} at temperatures from 7.2 down to 1.5 {{K}}. The measured quality factor of the resonators decreases with rising temperature due to enhanced losses. As a function of the sample thickness we observe three regimes with significantly different properties: samples below percolation, i.e. ensembles of disconnected superconducting islands, exhibit dielectric properties with negligible losses, demonstrating that macroscopic current paths are required for appreciable dynamical conductivity of Sn at GHz frequencies. Thick Sn films, as the other limit, lead to low-loss resonances both above and below T c of Sn, as expected for bulk conductors. But in an intermediate thickness regime, just above percolation and with labyrinth-like morphology of the Sn, we observe a quite different behavior: the superconducting state has a microwave response similar to the thicker, completely covering films with low microwave losses; but the metallic state of these Sn films is so lossy that resonator operation is suppressed completely.

  19. High-temperature superconductivity in space-charge regions of lanthanum cuprate induced by two-dimensional doping.

    PubMed

    Baiutti, F; Logvenov, G; Gregori, G; Cristiani, G; Wang, Y; Sigle, W; van Aken, P A; Maier, J

    2015-10-20

    The exploitation of interface effects turned out to be a powerful tool for generating exciting material properties. Such properties include magnetism, electronic and ionic transport and even superconductivity. Here, instead of using conventional homogeneous doping to enhance the hole concentration in lanthanum cuprate and achieve superconductivity, we replace single LaO planes with SrO dopant planes using atomic-layer-by-layer molecular beam epitaxy (two-dimensional doping). Electron spectroscopy and microscopy, conductivity measurements and zinc tomography reveal such negatively charged interfaces to induce layer-dependent superconductivity (Tc up to 35 K) in the space-charge zone at the side of the planes facing the substrate, where the strontium (Sr) profile is abrupt. Owing to the growth conditions, the other side exhibits instead a Sr redistribution resulting in superconductivity due to conventional doping. The present study represents a successful example of two-dimensional doping of superconducting oxide systems and demonstrates its power in this field.

  20. High-temperature superconductivity in space-charge regions of lanthanum cuprate induced by two-dimensional doping

    PubMed Central

    Baiutti, F.; Logvenov, G.; Gregori, G.; Cristiani, G.; Wang, Y.; Sigle, W.; van Aken, P. A.; Maier, J.

    2015-01-01

    The exploitation of interface effects turned out to be a powerful tool for generating exciting material properties. Such properties include magnetism, electronic and ionic transport and even superconductivity. Here, instead of using conventional homogeneous doping to enhance the hole concentration in lanthanum cuprate and achieve superconductivity, we replace single LaO planes with SrO dopant planes using atomic-layer-by-layer molecular beam epitaxy (two-dimensional doping). Electron spectroscopy and microscopy, conductivity measurements and zinc tomography reveal such negatively charged interfaces to induce layer-dependent superconductivity (Tc up to 35 K) in the space-charge zone at the side of the planes facing the substrate, where the strontium (Sr) profile is abrupt. Owing to the growth conditions, the other side exhibits instead a Sr redistribution resulting in superconductivity due to conventional doping. The present study represents a successful example of two-dimensional doping of superconducting oxide systems and demonstrates its power in this field. PMID:26481902

  1. Enhanced localized superconductivity in Sr2RuO4 thin film by pulsed laser deposition

    NASA Astrophysics Data System (ADS)

    Cao, J.; Massarotti, D.; Vickers, M. E.; Kursumovic, A.; Di Bernardo, A.; Robinson, J. W. A.; Tafuri, F.; MacManus-Driscoll, J. L.; Blamire, M. G.

    2016-09-01

    Superconducting c-axis-oriented Sr2RuO4 thin film has been fabricated using pulsed laser deposition. Although the superconductivity is localized, the onset critical temperature is enhanced over the bulk value. X-ray microstructural analysis of Sr2RuO4 superconducting and non-superconducting thin films suggests the existence of the localized stacking faults and an overall c-axis lattice expansion which may account for the locally enhanced superconductivity.

  2. Photoemission, Correlation and Superconductivity:

    NASA Astrophysics Data System (ADS)

    Abrecht, M.; Ariosa, D.; Cloëtta, D.; Pavuna, D.; Perfetti, L.; Grioni, M.; Margaritondo, G.

    We review some of the problems still affecting photoemission as a probe of high-temperature superconductivity, as well as important recent results concerning their solution. We show, in particular, some of the first important results on thin epitaxial films grown by laser ablation, which break the monopoly of cleaved BCSCO in this type of experiments. Such results, obtained on thin LSCO, may have general implications on the theory of high-temperature superconductivity.

  3. Passivation of high temperature superconductors

    NASA Technical Reports Server (NTRS)

    Vasquez, Richard P. (Inventor)

    1991-01-01

    The surface of high temperature superconductors such as YBa2Cu3O(7-x) are passivated by reacting the native Y, Ba and Cu metal ions with an anion such as sulfate or oxalate to form a surface film that is impervious to water and has a solubility in water of no more than 10(exp -3) M. The passivating treatment is preferably conducted by immersing the surface in dilute aqueous acid solution since more soluble species dissolve into the solution. The treatment does not degrade the superconducting properties of the bulk material.

  4. Berezinskii-Kosterlitz-Thouless transition in homogeneously disordered superconducting films

    NASA Astrophysics Data System (ADS)

    König, E. J.; Levchenko, A.; Protopopov, I. V.; Gornyi, I. V.; Burmistrov, I. S.; Mirlin, A. D.

    2015-12-01

    We develop a theory for the vortex-unbinding transition in homogeneously disordered superconducting films. This theory incorporates the effects of quantum, mesoscopic, and thermal fluctuations stemming from length scales ranging from the superconducting coherence length down to the Fermi wavelength. In particular, we extend the renormalization group treatment of the diffusive nonlinear sigma model to the superconducting side of the transition. Furthermore, we explore the mesoscopic fluctuations of parameters in the Ginzburg-Landau functional. Using the developed theory, we determine the dependence of essential observables (including the vortex-unbinding temperature, the superconducting density, as well as the temperature-dependent resistivity and thermal conductivity) on microscopic characteristics such as the disorder-induced scattering rate and bare interaction couplings.

  5. Controllable injector for local flux entry into superconducting films

    NASA Astrophysics Data System (ADS)

    Carmo, D.; Colauto, F.; de Andrade, A. M. H.; Oliveira, A. A. M.; Ortiz, W. A.; Johansen, T. H.

    2016-09-01

    A superconducting flux injector (SFI) has been designed to allow for controlled injections of magnetic flux into a superconducting film from a predefined location along the edge. The SFI is activated by an external current pulse, here chosen to be 200 ms long, and it is demonstrated on films of Nb that the amount of injected flux is controlled by the pulse height. Examples of injections at two different temperatures where the flux enters by stimulated flux-flow and by triggered thermomagnetic avalanches are presented. The boundary between the two types of injection is determined and discussed. The SFI opens up for active use of phenomena which up to now have been considered hazardous for a safe operation of superconducting devices.

  6. Thickness dependence of superconductivity and superconductor-insulator transition in ultrathin FeSe films on SrTiO3(001) substrate

    NASA Astrophysics Data System (ADS)

    Wang, Qingyan; Zhang, Wenhao; Zhang, Zuocheng; Sun, Yi; Xing, Ying; Wang, Yayu; Wang, Lili; Ma, Xucun; Xue, Qi-Kun; Wang, Jian

    2015-12-01

    Interface-enhanced high-temperature superconductivity in a one-unit-cell (UC) FeSe film on SrTiO3(001) (STO) substrate has recently attracted much attention in condensed matter physics and material science. Here, using ex situ transport measurements, we report on the superconductivity in FeSe ultrathin films with different thicknesses on STO substrate. We find that the onset superconducting transition temperature (T c) decreases with increasing film thickness of FeSe, which is opposite to the behavior usually observed in traditional superconductor films. By systematic post-annealing of 5 UC FeSe films, we observe an insulator-superconductor transition, which is accompanied by a sign change of the dominant charge carriers from holes to electrons at low temperatures according to the corresponding Hall measurement.

  7. Preparation, structure and superconductivity of high T(c) compounds: Research of high temperature superconductors in Hungary

    NASA Technical Reports Server (NTRS)

    Kirschner, I.

    1995-01-01

    In this paper the main directions, methods and results of the investigation of high-T(c) superconductors in Hungary are briefly summarized. The fundamental idea of this research is to study the effect of starting conditions on the microstructure of samples and the influence of the latter one on their superconducting parameters. The investigation concerning technical development is also mentioned.

  8. Effects of high-temperature hydrogenation treatment on sliding friction and wear behavior of carbide-derived carbon films.

    SciTech Connect

    Erdemir, A.; Kovalchenko, A.; McNallan, M. J.; Welz, S.; Lee, A.; Gogotsi, Y.; Carroll, B.; Energy Technology; Univ. of Illinois; Drexel Univ.

    2004-01-01

    In this study, we investigated the effects of a high-temperature hydrogenation treatment on the sliding friction and wear behavior of nanostructured carbide-derived carbon (CDC) films in dry nitrogen and humid air environments. These films are produced on the surfaces of silicon carbide substrates by reacting the carbide phase with chlorine or chlorine-hydrogen gas mixtures at 1000 to 1100 C in a sealed tube furnace. The typical friction coefficients of CDC films in open air are in the range of 0.2 to 0.25, but in dry nitrogen, the friction coefficients are 0.15. In an effort to achieve lower friction on CDC films, we developed and used a special hydrogenation process that was proven to be very effective in lowering friction of CDC films produced on SiC substrates. Specifically, the films that were post-hydrogen-treated exhibited friction coefficients as low as 0.03 in dry nitrogen, while the friction coefficients in humid air were 0.2. The wear of Si{sub 3}N{sub 4} counterface balls was hard to measure after the tests, while shallow wear tracks had formed on CDC films on SiC disks. Detailed mechanical and structural characterizations of the CDC films and sliding contact surfaces were done using a series of analytical techniques and these findings were correlated with the friction and wear behaviors of as-produced and hydrogen-treated CDC films.

  9. Signs of high-temperature superconductivity in frustrated manganites La1 - y Sm y MnO3 + δ ( y = 0.85, 1)

    NASA Astrophysics Data System (ADS)

    Bukhanko, F. N.; Bukhanko, A. F.

    2016-03-01

    The characteristics signs of the coexistence of nanoscale superconductivity and fluctuating antiferromagnetic state of the spin-liquid type have been revealed for the first time in frustrated manganites La1‒ y Sm y MnO3 + δ (δ ~ 0.1, y = 0.85, 1.0) in the form of macroscopic quantization of magnetic properties in weak magnetic fields. A sharp decrease and oscillations of close-in-magnitude critical temperatures of transitions to fluctuating antiferromagnetic ( T A) and superconducting ( T c0) states with an increase in the external magnetic field strength have been found. Quantum oscillations of the magnetization and magnetic susceptibility near the critical temperatures of fluctuating antiferromagnetic phase transitions of the A- and CE-types have been discovered and investigated in detail. It has been shown that the studied samples exhibit properties of a multicomponent composite in which at temperatures T < 60 K in weak magnetic fields, there coexist fluctuating charge and antiferromagnetic correlations of the A- and CE-types with properties of the spin-liquid state and a small fraction of the superconducting phase in the form of individual and Josephsontunnel- junction-coupled superconducting loops with low critical currents. It has been assumed that, in samples with samarium concentrations y ≥ 0.8 at temperatures below 60 K, there is a new inhomogeneous state of doped manganites of the magneto-electronic liquid crystal type with strong quantum fluctuations of the magnetic and electronic order parameters, which are similar to electronic liquid crystals in lightly doped high-temperature superconducting cuprates.

  10. A Cryogenic Magnetostrictive Actuator using a Persistent High Temperature Superconducting Magnet, Part 1: Concept and Design. Part 1; Concept and Design

    NASA Technical Reports Server (NTRS)

    Horner, Garnett C.; Bromberg, Leslie; Teter, J. P.

    2001-01-01

    Cryogenic magnetostrictive materials, such as rare earth zinc crystals, offer high strains and high forces with minimally applied magnetic fields, making the material ideally suited for deformable optics applications. For cryogenic temperature applications, such as Next Generation Space Telescope (NGST), the use of superconducting magnets offer the possibility of a persistent mode of operation, i.e., the magnetostrictive material will maintain a strain field without power. High temperature superconductors (HTS) are attractive options if the temperature of operation is higher than 10 degrees Kelvin (K) and below 77 K. However, HTS wires have constraints that limit the minimum radius of winding, and even if good wires can be produced, the technology for joining superconducting wires does not exist. In this paper, the design and capabilities of a rare earth zinc magnetostrictive actuator using bulk HTS is described. Bulk superconductors can be fabricated in the sizes required with excellent superconducting properties. Equivalent permanent magnets, made with this inexpensive material, are persistent, do not require a persistent switch as in HTS wires, and can be made very small. These devices are charged using a technique which is similar to the one used for charging permanent magnets, e.g., by driving them into saturation. A small normal conducting coil can be used for charging or discharging. Very fast charging and discharging of HTS tubes, as short as 100 microseconds, has been demonstrated. Because of the magnetic field capability of the superconductor material, a very small amount of superconducting magnet material is needed to actuate the rare earth zinc. In this paper, several designs of actuators using YBCO and BSCCO 2212 superconducting materials are presented. Designs that include magnetic shielding to prevent interaction between adjacent actuators will also be described. Preliminary experimental results and comparison with theory for BSSCO 2212 with a

  11. High-temperature stability of thermoelectric Ca{sub 3}Co{sub 4}O{sub 9} thin films

    SciTech Connect

    Brinks, P.; Rijnders, G.; Huijben, M.; Van Nong, N.; Pryds, N.

    2015-04-06

    An enhanced thermal stability in thermoelectric Ca{sub 3}Co{sub 4}O{sub 9} thin films up to 550 °C in an oxygen rich environment was demonstrated by high-temperature electrical and X-ray diffraction measurements. In contrast to generally performed heating in helium gas, it is shown that an oxygen/helium mixture provides sufficient thermal contact, while preventing the previously disregarded formation of oxygen vacancies. Combining thermal cycling with electrical measurements proves to be a powerful tool to study the real intrinsic thermoelectric behaviour of oxide thin films at elevated temperatures.

  12. Optimization of the Processing Parameters of High Temperature Superconducting Glass-Ceramics: Center Director's Discretionary Fund Final Report

    NASA Technical Reports Server (NTRS)

    Ethridge, E. C.; Kaukler, W. F.

    1993-01-01

    A number of promising glass forming compositions of high Tc superconducting Ba-Sr-Ca-Cu-O (BSCCO) materials were evaluated for their glass-ceramic crystallization ability. The BSCCO ceramics belonging to the class of superconductors in the Ba-Sr-Ca-Cu-O system were the focus of this study. By first forming the superconducting material as a glass, subsequent devitrification into the crystalline (glass-ceramic) superconductor can be performed by thermal processing of the glass preform body. Glass formability and phase formation were determined by a variety of methods in another related study. This study focused on the nucleation and crystallization of the materials. Thermal analysis during rapid cooling aids in the evaluation of nucleation and crystallization behavior. Melt viscosity is used to predict glass formation ability.

  13. Dome-shaped magnetic order competing with high-temperature superconductivity at high pressures in FeSe.

    PubMed

    Sun, J P; Matsuura, K; Ye, G Z; Mizukami, Y; Shimozawa, M; Matsubayashi, K; Yamashita, M; Watashige, T; Kasahara, S; Matsuda, Y; Yan, J-Q; Sales, B C; Uwatoko, Y; Cheng, J-G; Shibauchi, T

    2016-01-01

    The coexistence and competition between superconductivity and electronic orders, such as spin or charge density waves, have been a central issue in high transition-temperature (Tc) superconductors. Unlike other iron-based superconductors, FeSe exhibits nematic ordering without magnetism whose relationship with its superconductivity remains unclear. Moreover, a pressure-induced fourfold increase of Tc has been reported, which poses a profound mystery. Here we report high-pressure magnetotransport measurements in FeSe up to ∼15 GPa, which uncover the dome shape of magnetic phase superseding the nematic order. Above ∼6 GPa the sudden enhancement of superconductivity (Tc≤38.3 K) accompanies a suppression of magnetic order, demonstrating their competing nature with very similar energy scales. Above the magnetic dome, we find anomalous transport properties suggesting a possible pseudogap formation, whereas linear-in-temperature resistivity is observed in the normal states of the high-Tc phase above 6 GPa. The obtained phase diagram highlights unique features of FeSe among iron-based superconductors, but bears some resemblance to that of high-Tc cuprates. PMID:27431724

  14. Dome-shaped magnetic order competing with high-temperature superconductivity at high pressures in FeSe.

    PubMed

    Sun, J P; Matsuura, K; Ye, G Z; Mizukami, Y; Shimozawa, M; Matsubayashi, K; Yamashita, M; Watashige, T; Kasahara, S; Matsuda, Y; Yan, J-Q; Sales, B C; Uwatoko, Y; Cheng, J-G; Shibauchi, T

    2016-07-19

    The coexistence and competition between superconductivity and electronic orders, such as spin or charge density waves, have been a central issue in high transition-temperature (Tc) superconductors. Unlike other iron-based superconductors, FeSe exhibits nematic ordering without magnetism whose relationship with its superconductivity remains unclear. Moreover, a pressure-induced fourfold increase of Tc has been reported, which poses a profound mystery. Here we report high-pressure magnetotransport measurements in FeSe up to ∼15 GPa, which uncover the dome shape of magnetic phase superseding the nematic order. Above ∼6 GPa the sudden enhancement of superconductivity (Tc≤38.3 K) accompanies a suppression of magnetic order, demonstrating their competing nature with very similar energy scales. Above the magnetic dome, we find anomalous transport properties suggesting a possible pseudogap formation, whereas linear-in-temperature resistivity is observed in the normal states of the high-Tc phase above 6 GPa. The obtained phase diagram highlights unique features of FeSe among iron-based superconductors, but bears some resemblance to that of high-Tc cuprates.

  15. Dome-shaped magnetic order competing with high-temperature superconductivity at high pressures in FeSe

    NASA Astrophysics Data System (ADS)

    Sun, J. P.; Matsuura, K.; Ye, G. Z.; Mizukami, Y.; Shimozawa, M.; Matsubayashi, K.; Yamashita, M.; Watashige, T.; Kasahara, S.; Matsuda, Y.; Yan, J.-Q.; Sales, B. C.; Uwatoko, Y.; Cheng, J.-G.; Shibauchi, T.

    2016-07-01

    The coexistence and competition between superconductivity and electronic orders, such as spin or charge density waves, have been a central issue in high transition-temperature (Tc) superconductors. Unlike other iron-based superconductors, FeSe exhibits nematic ordering without magnetism whose relationship with its superconductivity remains unclear. Moreover, a pressure-induced fourfold increase of Tc has been reported, which poses a profound mystery. Here we report high-pressure magnetotransport measurements in FeSe up to ~15 GPa, which uncover the dome shape of magnetic phase superseding the nematic order. Above ~6 GPa the sudden enhancement of superconductivity (Tc<=38.3 K) accompanies a suppression of magnetic order, demonstrating their competing nature with very similar energy scales. Above the magnetic dome, we find anomalous transport properties suggesting a possible pseudogap formation, whereas linear-in-temperature resistivity is observed in the normal states of the high-Tc phase above 6 GPa. The obtained phase diagram highlights unique features of FeSe among iron-based superconductors, but bears some resemblance to that of high-Tc cuprates.

  16. Dome-shaped magnetic order competing with high-temperature superconductivity at high pressures in FeSe

    PubMed Central

    Sun, J. P.; Matsuura, K.; Ye, G. Z.; Mizukami, Y.; Shimozawa, M.; Matsubayashi, K.; Yamashita, M.; Watashige, T.; Kasahara, S.; Matsuda, Y.; Yan, J. -Q.; Sales, B. C.; Uwatoko, Y.; Cheng, J. -G.; Shibauchi, T.

    2016-01-01

    The coexistence and competition between superconductivity and electronic orders, such as spin or charge density waves, have been a central issue in high transition-temperature (Tc) superconductors. Unlike other iron-based superconductors, FeSe exhibits nematic ordering without magnetism whose relationship with its superconductivity remains unclear. Moreover, a pressure-induced fourfold increase of Tc has been reported, which poses a profound mystery. Here we report high-pressure magnetotransport measurements in FeSe up to ∼15 GPa, which uncover the dome shape of magnetic phase superseding the nematic order. Above ∼6 GPa the sudden enhancement of superconductivity (Tc≤38.3 K) accompanies a suppression of magnetic order, demonstrating their competing nature with very similar energy scales. Above the magnetic dome, we find anomalous transport properties suggesting a possible pseudogap formation, whereas linear-in-temperature resistivity is observed in the normal states of the high-Tc phase above 6 GPa. The obtained phase diagram highlights unique features of FeSe among iron-based superconductors, but bears some resemblance to that of high-Tc cuprates. PMID:27431724

  17. Dome-shaped magnetic order competing with high-temperature superconductivity at high pressures in FeSe

    DOE PAGES

    Sun, J. P.; Matsuura, K.; Ye, G. Z.; Mizukami, Y.; Shimozawa, M.; Matsubayashi, K.; Yamashita, M.; Watashige, T.; Kasahara, S.; Matsuda, Y.; et al

    2016-07-19

    The coexistence and competition between superconductivity and electronic orders, such as spin or charge density waves, have been a central issue in high transition-temperature (Tc) superconductors. Unlike other iron-based superconductors, FeSe exhibits nematic ordering without magnetism whose relationship with its superconductivity remains unclear. Moreover, a pressure-induced fourfold increase of Tc has been reported, which poses a profound mystery. Here we report high-pressure magnetotransport measurements in FeSe up to ~15 GPa, which uncover the dome shape of magnetic phase superseding the nematic order. Above ~6 GPa the sudden enhancement of superconductivity (Tc ≤ 38.3 K) accompanies a suppression of magnetic order,more » demonstrating their competing nature with very similar energy scales. Above the magnetic dome, we find anomalous transport properties suggesting a possible pseudogap formation, whereas linear-in-temperature resistivity is observed in the normal states of the high-Tc phase above 6 GPa. In conclusion, the obtained phase diagram highlights unique features of FeSe among iron-based superconductors, but bears some resemblance to that of high-Tc cuprates.« less

  18. Superconducting films made by spin-coating of acetate solutions

    SciTech Connect

    Balachandran, U.; Poeppel, R.B. ); dos Santos, D.I.; Carvalho, C.L.; da Silva, R.R.; Aegerter, M.A. . Inst. de Fisica e Quimica)

    1990-12-01

    Metallic silver substrates were spin-coated with several layers of mixed acetate solutions containing bismuth, lead, strontium, calcium, and copper. The viscosities of the cation solutions were modified by the addition of polyvinyl alcohol. The films were heat treated at various temperatures in air, O{sub 2}, and 1% O{sub 2} (balance N{sub 2}) atmospheres. Bismuth cuprate films with transport critical current densities {approx}500 A/cm{sup 2} were obtained in this work. New conditions of coating and sintering have been tried to produce superconducting films.

  19. Low temperature phase formation of Tl-based superconducting thin films in reduced oxygen atmosphere

    NASA Technical Reports Server (NTRS)

    Wu, C. Y.; Foong, F.; Liou, S. H.; Ho, J. C.

    1993-01-01

    Tl-Ba-Cu-Cu-O superconducting thin films were prepared by magnetron sputtering with postannealing in a reduced oxygen atmosphere. Single-phase Tl2Ba2Ca2Cu3O(x) can form on the MgO substrate at 800 C under P(O2) about 0.1 atm. However the phase formation temperature can be affected by the starting composition of the film. Tl1Ba2Ca2Cu3O(x) phase can be formed by simply lowering the Tl2O pressure. The thermal stability of Tl1Ba2Ca2Cu3O(x) phase was studied by resistivity measurements at high temperatures.

  20. A novel no-insulation winding technique of high temperature-superconducting racetrack coil for rotating applications: A progress report in Korea university

    NASA Astrophysics Data System (ADS)

    Choi, Y. H.; Song, J. B.; Yang, D. G.; Kim, Y. G.; Hahn, S.; Lee, H. G.

    2016-10-01

    This paper presents our recent progress on core technology development for a megawatt-class superconducting wind turbine generator supported by the international collaborative R&D program of the Korea Institute of Energy Technology Evaluation and Planning. To outperform the current high-temperature-superconducting (HTS) magnet technology in the wind turbine industry, a novel no-insulation winding technique was first proposed to develop the second-generation HTS racetrack coil for rotating applications. Here, we briefly report our recent studies on no-insulation (NI) winding technique for GdBCO coated conductor racetrack coils in the following areas: (1) Charging-discharging characteristics of no-insulation GdBCO racetrack coils with respect to external pressures applied to straight sections; (2) thermal and electrical stabilities of no-insulation GdBCO racetrack coils encapsulated with various impregnating materials; (3) quench behaviors of no-insulation racetrack coils wound with GdBCO conductor possessing various lamination layers; (4) electromagnetic characteristics of no-insulation GdBCO racetrack coils under time-varying field conditions. Test results confirmed that this novel NI winding technique was highly promising. It could provide development of a compact, mechanically dense, and self-protecting GdBCO magnet for use in real-world superconducting wind turbine generators.

  1. X-ray diffraction characterization of thin superconductive films

    SciTech Connect

    Kozaczek, K.J.; Watkins, T.R.; Book, G.W.; Carter, W.B.

    1995-12-31

    The physical and mechanical properties of thin films are often different from the properties of bulk material and are dictated by the film/substrate orientation relationship, crystal anisotropy and crystalgraphic texture of the film. X-ray diffraction texture analysis provides information about preferential film growth and can be used for optimization of deposition parameters and prediction of properties of thin films. An x-ray back reflection technique using the Braga-Brentano geometry with experimental corrections for absorption and defocusing was used to study thin ceramic films deposited by combustion chemical vapor deposition (CCVD). The film/substrate orientation relationships of YBa{sub 2}Cu{sub 3}O{sub x} (YBCO) superconducting thin films deposited via CCVD on single crystal MgO and polycrystalline silver substrates were studied. The as-deposited films on single crystal (100) MgO substrates showed strong preferential growth with the basal plane parallel to the substrate surface (c-axis up growth). Texture analysis showed two in-plane alignment orientations of the film with respect to the substrate, with YBCO [100] and [110] aligned with the [100] MgO substrate. YBCO films deposited on cold-rolled polycrystalline silver displayed c-axis up growth indicating that the orientation of the polycrystalline substrate (brass type texture) did not induce detectable in-plane preferential growth of the YBCO.

  2. High temperature passive film on the surface of Co-Cr-Mo alloy and its tribological properties

    NASA Astrophysics Data System (ADS)

    Guo, Feifei; Dong, Guangneng; Dong, Lishe

    2014-09-01

    For the artificial hip joints, passive film formed on the Co-Cr-Mo alloy acted as a highly protective barrier in the body fluid. But its stability, composition and structure always influenced the protection. In this work, passive film was obtained by high temperature treatment. The effect of passivation environment on the properties of the passive film was investigated. The film's surface roughness, micro-hardness and structure were analyzed. In order to study the tribological behavior of the passive film, pin-on-disk tribotest was carried out under bovine serum albumin (BSA) and saline solution. Results indicated the sample passivated in vacuum had friction coefficient of 0.18 under BSA solution and 0.53 under saline solution; the sample passivated in air had friction coefficient of 0.14 under BSA solution and 0.56 under saline solution. In addition, the reference sample without passivation was tested under the same condition. It showed friction of 0.22 under BSA solution and 0.45 under solution. The lubricating mechanism was attributed to BSA tribo-film absorption on the surface and high hardness passive film.

  3. High-Temperature Characterization of Silicon Dioxide Films with Wafer Curvature

    NASA Astrophysics Data System (ADS)

    Bigl, S.; Heinz, W.; Kahn, M.; Schoenherr, H.; Cordill, M. J.

    2015-12-01

    Amorphous silicon dioxide films used as dielectric layers in microelectronic devices are deposited using plasma-enhanced chemical vapor deposition. Because of the presence of hydrogen and nitrogen species in the precursor gases, incorporation of such species in the films can lead to crack formation during subsequent annealing processes up to 1000°C. In this study, the role of film chemistry on the thermo-mechanical behavior of silicon dioxide films is studied with in situ film stress measurements using wafer curvature to maximum temperatures of 1000°C. This is a significant advance because normal wafer curvature can only reach maximum temperatures of around 500°C. The increased temperature range allows for the stress evolution and film chemistry to be examined for the relevant processing conditions. It was found that at temperatures higher than 550°C, hydrogen bond cleavage led to a large stress increase and film chemistry change due to new bonding arrangements between nitrogen and silicon as well as subsequent film densification causing cracking of films. These changes could only be identified with wafer curvature measurements up to 1000°C.

  4. Different variation behaviors of resistivity for high-temperature-grown and low-temperature-grown p-GaN films

    NASA Astrophysics Data System (ADS)

    Jing, Yang; De-Gang, Zhao; De-Sheng, Jiang; Ping, Chen; Zong-Shun, Liu; Jian-Jun, Zhu; Ling-Cong, Le; Xiao-Jing, Li; Xiao-Guang, He; Li-Qun, Zhang; Hui, Yang

    2016-02-01

    Two series of p-GaN films grown at different temperatures are obtained by metal organic chemical vapor deposition (MOCVD). And the different variation behaviors of resistivity with growth condition for high- temperature(HT)-grown and low-temperature(LT)-grown p-GaN films are investigated. It is found that the resistivity of HT-grown p-GaN film is nearly unchanged when the NH3 flow rate or reactor pressure increases. However, it decreases largely for LT-grown p-GaN film. These different variations may be attributed to the fact that carbon impurities are easy to incorporate into p-GaN film when the growth temperature is low. It results in a relatively high carbon concentration in LT-grown p-GaN film compared with HT-grown one. Therefore, carbon concentration is more sensitive to the growth condition in these samples, ultimately, leading to the different variation behaviors of resistivity for HT- and LT-grown ones. Project supported by the National Natural Science Foundation of China (Grant Nos. 61474110, 61377020, 61376089, 61223005, and 61176126), the National Natural Science Fund for Distinguished Young Scholars, China (Grant No. 60925017), the One Hundred Person Project of the Chinese Academy of Sciences, and the Basic Research Project of Jiangsu Province, China (Grant No. BK20130362).

  5. Method of preparing high-temperature-stable thin-film resistors

    DOEpatents

    Raymond, Leonard S.

    1983-01-01

    A chemical vapor deposition method for manufacturing tungsten-silicide thin-film resistors of predetermined bulk resistivity and temperature coefficient of resistance (TCR). Gaseous compounds of tungsten and silicon are decomposed on a hot substrate to deposit a thin-film of tungsten-silicide. The TCR of the film is determined by the crystallinity of the grain structure, which is controlled by the temperature of deposition and the tungsten to silicon ratio. The bulk resistivity is determined by the tungsten to silicon ratio. Manipulation of the fabrication parameters allows for sensitive control of the properties of the resistor.

  6. Method of preparing high-temperature-stable thin-film resistors

    DOEpatents

    Raymond, L.S.

    1980-11-12

    A chemical vapor deposition method for manufacturing tungsten-silicide thin-film resistors of predetermined bulk resistivity and temperature coefficient of resistance (TCR) is disclosed. Gaseous compounds of tungsten and silicon are decomposed on a hot substrate to deposit a thin-film of tungsten-silicide. The TCR of the film is determined by the crystallinity of the grain structure, which is controlled by the temperature of deposition and the tungsten to silicon ratio. The bulk resistivity is determined by the tungsten to silicon ratio. Manipulation of the fabrication parameters allows for sensitive control of the properties of the resistor.

  7. Superconducting Gap Anisotropy in Monolayer FeSe Thin Film.

    PubMed

    Zhang, Y; Lee, J J; Moore, R G; Li, W; Yi, M; Hashimoto, M; Lu, D H; Devereaux, T P; Lee, D-H; Shen, Z-X

    2016-09-01

    Superconductivity originates from pairing of electrons near the Fermi energy. The Fermi surface topology and pairing symmetry are thus two pivotal characteristics of a superconductor. Superconductivity in one monolayer (1 ML) FeSe thin film has attracted great interest recently due to its intriguing interfacial properties and possibly high superconducting transition temperature over 65 K. Here, we report high-resolution measurements of the Fermi surface and superconducting gaps in 1 ML FeSe using angle-resolved photoemission spectroscopy. Two ellipselike electron pockets are clearly resolved overlapping with each other at the Brillouin zone corner. The superconducting gap is nodeless but moderately anisotropic, which puts strong constraint on determining the pairing symmetry. The gap maxima locate on the d_{xy} bands along the major axis of the ellipse and four gap minima are observed at the intersections of electron pockets. The gap maximum location combined with the Fermi surface geometry deviate from a single d-wave, extended s-wave or s_{±} gap function, suggesting an important role of the multiorbital nature of Fermi surface and orbital-dependent pairing in 1 ML FeSe. The gap minima location may be explained by a sign change on the electron pockets, or a competition between intra- and interorbital pairing. PMID:27661715

  8. Superconducting Gap Anisotropy in Monolayer FeSe Thin Film

    NASA Astrophysics Data System (ADS)

    Zhang, Y.; Lee, J. J.; Moore, R. G.; Li, W.; Yi, M.; Hashimoto, M.; Lu, D. H.; Devereaux, T. P.; Lee, D.-H.; Shen, Z.-X.

    2016-09-01

    Superconductivity originates from pairing of electrons near the Fermi energy. The Fermi surface topology and pairing symmetry are thus two pivotal characteristics of a superconductor. Superconductivity in one monolayer (1 ML) FeSe thin film has attracted great interest recently due to its intriguing interfacial properties and possibly high superconducting transition temperature over 65 K. Here, we report high-resolution measurements of the Fermi surface and superconducting gaps in 1 ML FeSe using angle-resolved photoemission spectroscopy. Two ellipselike electron pockets are clearly resolved overlapping with each other at the Brillouin zone corner. The superconducting gap is nodeless but moderately anisotropic, which puts strong constraint on determining the pairing symmetry. The gap maxima locate on the dx y bands along the major axis of the ellipse and four gap minima are observed at the intersections of electron pockets. The gap maximum location combined with the Fermi surface geometry deviate from a single d -wave, extended s -wave or s± gap function, suggesting an important role of the multiorbital nature of Fermi surface and orbital-dependent pairing in 1 ML FeSe. The gap minima location may be explained by a sign change on the electron pockets, or a competition between intra- and interorbital pairing.

  9. In-situ deposition of YBCO high-Tc superconducting thin films by MOCVD and PE-MOCVD

    NASA Technical Reports Server (NTRS)

    Zhao, J.; Noh, D. W.; Chern, C.; Li, Y. Q.; Norris, P. E.; Kear, B.; Gallois, B.

    1991-01-01

    Metal-Organic Chemical Vapor Deposition (MOCVD) offers the advantages of a high degree of compositional control, adaptability for large scale production, and the potential for low temperature fabrication. The capability of operating at high oxygen partial pressure is particularly suitable for in situ formation of high temperature superconducting (HTSC) films. Yttrium barium copper oxide (YBCO) thin films having a sharp zero-resistance transition with T(sub c) greater than 90 K and J(sub c) of approximately 10(exp 4) A on YSZ have been prepared, in situ, at a substrate temperature of about 800 C. Moreover, the ability to form oxide films at low temperature is very desirable for device applications of HTSC materials. Such a process would permit the deposition of high quality HTSC films with a smooth surface on a variety of substrates. Highly c-axis oriented, dense, scratch resistant, superconducting YBCO thin films with mirror-like surfaces have been prepared, in situ, at a reduced substrate temperature as low as 570 C by a remote microwave-plasma enhanced metal-organic chemical vapor deposition (PE-MOCVD) process. Nitrous oxide was used as a reactant gas to generate active oxidizing species. This process, for the first time, allows the formation of YBCO thin films with the orthorhombic superconducting phase in the as-deposited state. The as-deposited films grown by PE-MOCVD show attainment of zero resistance at 72 K with a transition width of about 5 K. MOCVD was carried out in a commercial production scale reactor with the capability of uniform deposition over 100 sq cm per growth run. Preliminary results indicate that PE-MOCVD is a very attractive thin film deposition process for superconducting device technology.

  10. In Situ deposition of YBCO high-T(sub c) superconducting thin films by MOCVD and PE-MOCVD

    NASA Technical Reports Server (NTRS)

    Zhao, J.; Noh, D. W.; Chern, C.; Li, Y. Q.; Norris, P.; Gallois, B.; Kear, B.

    1990-01-01

    Metalorganic Chemical Vapor Deposition (MOCVD) offers the advantages of a high degree of compositional control, adaptability for large scale production, and the potential for low temperature fabrication. The capability of operating at high oxygen partial pressure is particularly suitable for in situ formation of high temperature superconducting (HTSC) films. Yttrium barium copper oxide (YBCO) thin films having a sharp zero-resistance transition with T( sub c) greater than 90 K and Jc approx. 10 to the 4th power A on YSZ have been prepared, in situ, at a substrate temperature of about 800 C. Moreover, the ability to form oxide films at low temperature is very desirable for device applications of HTSC materials. Such a process would permit the deposition of high quality HTSC films with a smooth surface on a variety of substrates. Highly c-axis oriented, dense, scratch resistant, superconducting YBCO thin films with mirror-like surfaces have been prepared, in situ, at a reduced substrate temperature as low as 570 C by a remote microwave-plasma enhanced metalorganic chemical vapor deposition (PE-MOCVD) process. Nitrous oxide was used as a reactant gas to generate active oxidizing species. This process, for the first time, allows the formation of YBCO thin films with the orthorhombic superconducting phase in the as-deposited state. The as-deposited films grown by PE-MOCVD show attainment of zero resistance at 72 K with a transition width of about 5 K. MOCVD was carried out in a commercial production scale reactor with the capability of uniform deposition over 100 sq cm per growth run. Preliminary results indicate that PE-MOCVD is a very attractive thin film deposition process for superconducting device technology.

  11. Nucleation of stable superconductivity in YBCO-films

    NASA Astrophysics Data System (ADS)

    Kötzler, J.

    By means of the linear dynamic conductivity, inductively measured on epitaxial films between 30mHz and 30 MHz, the transition line T g (B) to generic superconductivity is studied in fields between B=0 and 19T. It follows closely the melting line T m (B) described recently in terms of a blowout of thermal vortex loops in clean materials. The critical exponents of the correlation length and time near T g (B), however, enem to be dominated by some intrinsic disorder. Columnar defects produced by heavy-ion irradiation up to field-equivalent-doses of B ϕ =10T lead to adisappointing reduction of T g (B→0) while for B>B ϕ the generic line of the pristine film is recovered. These novel results are also discussed in terms of a loop-driven destruction of generic superconductivity.

  12. Weakly superconducting, thin-film structures as radiation detectors.

    NASA Technical Reports Server (NTRS)

    Kirschman, R. K.

    1972-01-01

    Measurements were taken with weakly superconducting quantum structures of the Notarys-Mercereau type, representing a thin superconductor film with a short region that is weakened in the sense that its transition temperature is lower than in the remaining portion of the film. The structure acts as a superconducting relaxation oscillator in which the supercurrent increases with time until the critical current of the weakened section is attained, at which moment the supercurrent decays and the cycle repeats. Under applied radiation, a series of constant-voltage steps appears in the current-voltage curve, and the size of the steps varies periodically with the amplitude of applied radiation. Measurements of the response characteristics were made in the frequency range of 10 to 450 MHz.

  13. Solid state thin film battery having a high temperature lithium alloy anode

    DOEpatents

    Hobson, David O.

    1998-01-01

    An improved rechargeable thin-film lithium battery involves the provision of a higher melting temperature lithium anode. Lithium is alloyed with a suitable solute element to elevate the melting point of the anode to withstand moderately elevated temperatures.

  14. Method of producing high T(subc) superconducting NBN films

    NASA Technical Reports Server (NTRS)

    Thakoor, Sarita (Inventor); Lamb, James L. (Inventor); Thakoor, Anilkumar P. (Inventor); Khanna, Satish K. (Inventor)

    1988-01-01

    Thin films of niobium nitride with high superconducting temperature (T sub c) of 15.7 K are deposited on substrates held at room temperature (approx 90 C) by heat sink throughout the sputtering process. Films deposited at P sub Ar 12.9 + or - 0.2 mTorr exhibit higher T sub c with increasing P sub N2,I with the highest T sub c achieved at P sub n2,I= 3.7 + or - 0.2 mTorr and total sputtering pressure P sub tot = 16.6 + or - 0.4. Further increase of N2 injection starts decreasing T sub c.

  15. On excess conductivity of wide superconducting films with phase slippage

    SciTech Connect

    Kulikovsky, A.; Erganokov, Kh.; Bielska-Lewandowska, H.

    1997-02-01

    Properties of wide superconducting tin films in the resistive current state with phase slippage have been studied experimentally. The authors have observed a region of excess conductivity on the current-voltage characteristics of the samples. Experimental results were discussed in view of the theory establishing the relationship between an interference term of the total current and excess current in weak superconductors. They derived the equation to evaluate the inelastic scattering time of superconductor {tau}{sub E} using the excess current of wide films with phase slippage. Their {tau}{sub E} values are in a good agreement with those obtained by other methods.

  16. Dynamic magneto-optical imaging of superconducting thin films

    NASA Astrophysics Data System (ADS)

    Wells, Frederick S.; Pan, Alexey V.; Wilson, Stephen; Golovchanskiy, Igor A.; Fedoseev, Sergey A.; Rozenfeld, Anatoly

    2016-03-01

    We present a novel method for analysis of superconducting thin films using dynamic magneto-optical imaging, revealing hallmarks of flux penetration with temporal resolution around 1 ms (in the present work) or better. This method involves investigation of transient field and dynamic current distributions, which are calculated by an inversion procedure on the Biot-Savart Law, which we show to be valid under dynamic conditions. We compare and discuss the flux front penetration speed and evolution of current distribution in high quality YBa2Cu3O{}7-δ thin films with that of samples deliberately damaged in such a way as to reduce critical current density without causing macroscopic damage.

  17. Phase transformation of oxide film in zirconium alloy in high temperature hydrogenated water

    SciTech Connect

    Kim, Taeho; Kim, Jongjin; Choi, Kyoung Joon; Yoo, Seung Chang; Kim, Seung Hyun; Kim, Ji Hyun

    2015-07-23

    The effect of the variation of the dissolved hydrogen concentration on the oxide phase transformation under high-temperature hydrogenated water conditions was investigated using in situ Raman spectroscopy. The Raman spectrum in 50 cm(3)/kg of dissolved hydrogen concentration indicated the formation of monoclinic and tetragonal zirconium oxide at the water-substrate interface. As the dissolved hydrogen concentration decreased to 30 cm(3)/kg, the Raman peaks corresponding to the zirconium oxide phase changed, indicating an oxide phase transformation. And, the results of SEM and TEM analyses were compared with those of in situ analyses obtained for the oxide structure formed on the zirconium alloy.

  18. Electrical transport in the superconducting and normal states in Y2Ba5Cu7Ox high-temperature superconductor

    NASA Astrophysics Data System (ADS)

    Mazaheri, M.; Jamasb, S.

    2016-05-01

    The resistivity of a recently reported Y2Ba5Cu7Ox (Y257) polycrystalline, high-temperature superconductor has been characterized over temperature in the presence of magnetic field intensities in the 0-15 kOe range. The magnetoresistive behavior of Y257 has been analyzed to determine the functional dependence of the pinning energy, U, associated with the resistive transition. Within the temperature range of 0.60 < T /Tc < 0.95 the Y257 resistivity data are consistent with the thermally activated flux creep model with the pinning energy following the temperature and magnetic field according to (1 - T /Tc) 2H-1. The pinning energy in this temperature range was determined to be in the 0.0125-0.8151 eV range. Furthermore, application of the Mott variable range hopping model to account for the normal-state behavior of resistivity in Y257 is critically assessed.

  19. Study - Radiation Shielding Effectiveness of the Prototyped High Temperature Superconductivity (HTS) 'Artificial' Magnetosphere for Deep Space Missions

    NASA Technical Reports Server (NTRS)

    Denkins, Pamela

    2010-01-01

    The high temperature superconductor (HTS) is being used to develop the magnets for the Variable Specific Impulse Magneto-plasma Rocket (VASIMR ) propulsion system and may provide lightweight magnetic radiation shielding to protect spacecraft crews from radiation caused by GCR and SPEs on missions to Mars. A study is being planned to assess the radiation shielding effectiveness of the artificial magnetosphere produced by the HTS magnet. VASIMR is an advanced technology propulsion engine which is being touted as enabling one way transit to Mars in 90 days or less. This is extremely important to NASA. This technology would enable a significant reduction in the number of days in transit to and from Mars and significantly reduce the astronauts exposure to a major threat - high energy particles from solar storms and GCR during long term deep space missions. This paper summarizes the plans for the study and the subsequent testing of the VASIMR technology onboard the ISS slated for 2013.

  20. Superconductivity above 100 K in single-layer FeSe films on doped SrTiO3.

    PubMed

    Ge, Jian-Feng; Liu, Zhi-Long; Liu, Canhua; Gao, Chun-Lei; Qian, Dong; Xue, Qi-Kun; Liu, Ying; Jia, Jin-Feng

    2015-03-01

    Recent experiments on FeSe films grown on SrTiO3 (STO) suggest that interface effects can be used as a means to reach superconducting critical temperatures (Tc) of up to 80 K (ref. ). This is nearly ten times the Tc of bulk FeSe and higher than the record value of 56 K for known bulk Fe-based superconductors. Together with recent studies of superconductivity at oxide heterostructure interfaces, these results rekindle the long-standing idea that electron pairing at interfaces between two different materials can be tailored to achieve high-temperature superconductivity. Subsequent angle-resolved photoemission spectroscopy measurements of the FeSe/STO system revealed an electronic structure distinct from bulk FeSe (refs , ), with an energy gap vanishing at around 65 K. However, ex situ electrical transport measurements have so far detected zero resistance-the key experimental signature of superconductivity-only below 30 K. Here, we report the observation of superconductivity with Tc above 100 K in the FeSe/STO system by means of in situ four-point probe electrical transport measurements. This finding confirms FeSe/STO as an ideal material for studying high-Tc superconductivity.

  1. Emergence of a High-Temperature Superconductivity in Hydrogen Cycled pd Compounds as AN Evidence for Superstoihiometric H/d Sites

    NASA Astrophysics Data System (ADS)

    Lipson, Andrei; Castano, Carlos; Miley, George; Lipson, Andrei; Lyakhov, Boris; Mitin, Alexander

    2006-02-01

    Transport and magnetic properties of hydrogen cycled PdHx and Pd/PdO:Hx (x ~ (4/6) × 10-4) nano-composite consisting of a Pd matrix with hydrogen trapped inside dislocation cores have been studied. The results suggest emergence of a high-temperature superconductivity state of a condensed hydrogen phase confined inside deep dislocation cores in the Pd matrix. The possible role of hydrogen/deuterium filled dislocation nano-tubes is discussed. These dislocation cores could be considered as active centers of LENR triggering due to (i) short D-D separation distance (~Bohr radius); (ii) high-local D-loading in the Pd and the corresponding effective lattice compression; (iii) a large optic phonon energy resulting in a most effective lattice-nuclei energy transfer.

  2. Convective Heat Transfer with and without Film Cooling in High Temperature, Fuel Rich and Lean Environments

    NASA Astrophysics Data System (ADS)

    Greiner, Nathan J.

    Modern turbine engines require high turbine inlet temperatures and pressures to maximize thermal efficiency. Increasing the turbine inlet temperature drives higher heat loads on the turbine surfaces. In addition, increasing pressure ratio increases the turbine coolant temperature such that the ability to remove heat decreases. As a result, highly effective external film cooling is required to reduce the heat transfer to turbine surfaces. Testing of film cooling on engine hardware at engine temperatures and pressures can be exceedingly difficult and expensive. Thus, modern studies of film cooling are often performed at near ambient conditions. However, these studies are missing an important aspect in their characterization of film cooling effectiveness. Namely, they do not model effect of thermal property variations that occur within the boundary and film cooling layers at engine conditions. Also, turbine surfaces can experience significant radiative heat transfer that is not trivial to estimate analytically. The present research first computationally examines the effect of large temperature variations on a turbulent boundary layer. Subsequently, a method to model the effect of large temperature variations within a turbulent boundary layer in an environment coupled with significant radiative heat transfer is proposed and experimentally validated. Next, a method to scale turbine cooling from ambient to engine conditions via non-dimensional matching is developed computationally and the experimentally validated at combustion temperatures. Increasing engine efficiency and thrust to weight ratio demands have driven increased combustor fuel-air ratios. Increased fuel-air ratios increase the possibility of unburned fuel species entering the turbine. Alternatively, advanced ultra-compact combustor designs have been proposed to decrease combustor length, increase thrust, or generate power for directed energy weapons. However, the ultra-compact combustor design requires a

  3. Probing transport mechanisms of BaFe₂As₂ superconducting films and grain boundary junctions by noise spectroscopy.

    PubMed

    Barone, C; Romeo, F; Pagano, S; Adamo, M; Nappi, C; Sarnelli, E; Kurth, F; Iida, K

    2014-01-01

    An important step forward for the understanding of high-temperature superconductivity has been the discovery of iron-based superconductors. Among these compounds, iron pnictides could be used for high-field magnet applications, resulting more advantageous over conventional superconductors, due to a high upper critical field as well as its low anisotropy at low temperatures. However, the principal obstacle in fabricating high quality superconducting wires and tapes is given by grain boundaries. In order to study these effects, the dc transport and voltage-noise properties of Co-doped BaFe₂As₂ superconducting films with artificial grain boundary junctions have been investigated. A specific procedure allows the separation of the film noise from that of the junction. While the former shows a standard 1/f behaviour, the latter is characterized by an unconventional temperature-dependent multi-Lorentzian voltage-spectral density. Moreover, below the film superconducting critical temperature, a peculiar noise spectrum is found for the grain boundary junction. Possible theoretical interpretation of these phenomena is proposed. PMID:25145385

  4. Effect of niobium interlayer on high-temperature sliding friction and wear of silver films on alumina

    SciTech Connect

    Erdemir, A.; Erck, R.A.

    1994-03-01

    We investigated the effect of a thin Nb bond layer (15--20 mn thick) on the high-temperature sliding friction and wear of silver films ({approx}1.5 {mu}m thick) produced on {alpha}-alumina (Al{sub 2}O{sub 3}) substrates by ion-beam assisted deposition. The friction coefficients of test pairs without an Ag film fluctuated between 0.8 to 1.1, whereas the friction coefficients of pairs with an Ag film were 0.32 to 0.5. The wear of uncoated Al{sub 2}O{sub 3} balls sliding against the Ag-coated flats was reduced by factors of 25 to {approx}2000, depending on test temperature and the presence or absence of an Nb bond layer. The wear of silver-coated flats was virtually unmeasurable after tests at temperatures up to 400C. At much higher temperatures (e.g., 600C), Ag films without an Nb bond layer delaminated from the sliding surfaces and lost their effectiveness; however, Ag films with an Nb bond layer remained intact on the sliding surfaces of the Al{sub 2}O{sub 3} substrates even at 600C and continued to impart low friction and low wear.

  5. RuAl thin films on high-temperature piezoelectric substrates

    NASA Astrophysics Data System (ADS)

    Seifert, M.; Menzel, S. B.; Rane, G. K.; Hoffmann, M.; Gemming, T.

    2015-08-01

    The phase formation, structural and electrical properties of thin Ru-Al alloy films prepared on LGS (La3Ga5SiO14) and CTGS (Ca3TaGa3Si2O14) as well as on Si/SiO2(reference) substrates are analyzed for samples prepared at room temperature and after annealing for 10 h in high vacuum at 600 °C and 800 °C. The physical characterization reveals a strong dependence of the film quality on the chosen substrate. While the RuAl phase is clearly formed on the Si/SiO2 reference substrate, the phase is not stable on LGS and only weakly formed on CTGS due to a substrate decomposition effect and related Ga and O diffusion into the RuAl film.

  6. High-temperature superconducting radiofrequency probe for magnetic resonance imaging applications operated below ambient pressure in a simple liquid-nitrogen cryostat

    NASA Astrophysics Data System (ADS)

    Lambert, Simon; Ginefri, Jean-Christophe; Poirier-Quinot, Marie; Darrasse, Luc

    2013-05-01

    The present work investigates the joined effects of temperature and static magnetic field on the electrical properties of a 64 MHz planar high-temperature superconducting (HTS) coil, in order to enhance the signal-to-noise ratio (SNR) in nuclear magnetic resonance (NMR) applications with a moderate decrease of the HTS coil temperature (THTS). Temperature control is provided with accuracy better than 0.1 K from 80 to 66 K by regulating the pressure of the liquid nitrogen bath of a dedicated cryostat. The actual temperature of the HTS coil is obtained using a straightforward wireless method that eliminates the risks of coupling electromagnetic interference to the HTS coil and of disturbing the static magnetic field by DC currents near the region of interest. The resonance frequency ( f0) and the quality factor (Q) of the HTS coil are measured as a function of temperature in the 0-4.7 T field range with parallel and orthogonal orientations relative to the coil plane. The intrinsic HTS coil sensitivity and the detuning effect are then analyzed from the Q and f0 data. In the presence of the static magnetic field, the initial value of f0 in Earth's field could be entirely recovered by decreasing THTS, except for the orthogonal orientation above 1 T. The improvement of Q by lowering THTS was substantial. From 80 to 66 K, Q was multiplied by a factor of 6 at 1.5 T in orthogonal orientation. In parallel orientation, the maximum measured improvement of Q from 80 K to 66 K was a factor of 2. From 80 to 66 K, the improvement of the RF sensitivity relative to the initial value at the Earth's field and ambient pressure was up to 4.4 dB in parallel orientation. It was even more important in orthogonal orientation and continued to increase, up to 8.4 dB, at the maximum explored field of 1.5 T. Assuming that the noise contributions from the RF receiver are negligible, the SNR improvement using enhanced HTS coil cooling in NMR experiments was extracted from Q measurements either

  7. In situ high temperature crystallization study of sputter deposited amorphous W-Fe-C films

    SciTech Connect

    Trindade, B.; Vieira, M.T. . Dept. de Engenharia Mecanica); Grosse, E.B. . Lab. de Sciences et Genie des Surfaces)

    1995-01-01

    The structural behavior of amorphous W[sub 46]Fe[sub 13]C[sub 41] and W[sub 36]Fe[sub 31]C[sub 33] films produced by sputtering have been studied in situ during annealing up to [approximately] 950 C by means of hot stage transmission electron microscopy. Differential thermal analysis and X-ray diffraction were used as complementary experimental techniques. The results are presented and correlated with the equilibrium phases anticipated from the W-Fe-C ternary phase diagram and with previous studied on similar films deposited and annealed onto substrates.

  8. High Temperature Superconductivity in Praseodymium Doped (0%, 2%, 4%) in Melt-Textured Y(1-x)Pr(x)Ba2Cu3O(7-delta) Systems

    NASA Technical Reports Server (NTRS)

    James, Claudell

    1995-01-01

    A study of the magnetic and structural properties of the alloy Y(1-x)Pr(x)Ba2Cu3O(7-delta) of 0%, 2%, and 4% doping of praseodymium is presented. The resulting oxides of the alloy series are a high-temperature superconductor Y-Ba-Cu-O, which has an orthorhombic superconducting crystal-lattice. Magnetic relaxation studies have been performed on the Y-Pr-Ba-CuO bulk samples for field orientation parallel to the c-axis, using a vibrating sample magnetometer. Relaxation was measured at several temperatures to obtain the irreversible magnetization curves used for the Bean model. Magnetization current densities were derived from the relaxation data. Field and temperature dependence of the logarithmic flux-creep relaxation was measured in critical state. The data indicates that the effective activation energy U(eff) increases with increasing T between 77 K and 86 K. Also, the data shows that U(eff)(T) and superconducting transition temperature, Tc, decreased as the lattice parameters increased with increasing Pr ion concentration, x, for the corresponding Y(1-x)Pr(x)Ba(x)Cu3O(7-delta) oxides. One contribution to Tc decrease in this sampling is suspected to be due to the larger ionic radius of the Pr(3+) ion. The upper critical field (H(sub c2)) was measured in the presence of magnetic field parallel to the c axis. A linear temperature dependence with H(sub c2) was obtained.

  9. Thermal diffusivity measurements of sub-micron organic dye thin films using a high temperature superconductor bolometer

    NASA Astrophysics Data System (ADS)

    Savoy, Steven M.; Wells, Cyndi A.; McDevitt, John T.; Rhodes, Timothy A.

    1998-12-01

    The thermal diffusivity of a thin organic dye layer deposited atop thin films of the high temperature superconductor YBa2Cu3O7-δ is measured using a pulsed laser flash method. Here, the underlying superconductor acts as a highly sensitive temperature transducer after appropriate conversion of the transient voltage response from 7 ns optical pulses. Film surface temperature decays for several thicknesses of the dye layers were evaluated; these decays exhibited a linear dependence of the time at half temperature maximum versus thickness squared. Three dimensional finite difference modeling was used to study and extract the thermal diffusivity values of the thin organic layers as well as to investigate the transient temperature distributions within the dye and superconductor areas.

  10. Crystallization and segregation in vitreous rutile films annealed at high temperature

    SciTech Connect

    Omari, M.A.; Sorbello, R.S.; Aita, C.R.

    2005-11-15

    Vitreous titania films with rutile short-range order were sputter deposited on unheated fused silica substrates, sequentially annealed at 973 and 1273 K, and examined by Raman microscopy, scanning electron microscopy, and x-ray diffraction. A segregated microstructure developed after the 1273 K anneal. This microstructure consists of supermicron-size craters dispersed in a matrix of submicron rutile crystals. Ti-O short-range order in the craters is characteristic of a mixture of two high pressure phases, m-TiO{sub 2} (monoclinic P2{sub 1}/c space group) and {alpha}-TiO{sub 2} (tetragonal Pbcn space group). We calculated that a high average compressive stress parallel to the substrate must be accommodated in the films at 1273 K, caused by the difference in the thermal expansion coefficients of titania and fused silica. The formation of the segregated microstructure is modeled by considering two processes at work at 1273 K to lower a film's internal energy: crystallization and nonuniform stress relief. The Gibbs-Thomson relation shows that small m-TiO{sub 2} crystallites are able to form directly from vitreous TiO{sub 2} at 1273 K. However, the preferred mechanism for forming {alpha}-TiO{sub 2} is likely to be by epitaxial growth at crystalline rutile twin boundaries (secondary crystallization). Both phases are denser than crystalline rutile and reduce the average thermal stress in the films.

  11. Solid-film lubricant is effective at high temperatures in vacuum

    NASA Technical Reports Server (NTRS)

    Sliney, H. E.

    1966-01-01

    Calcium fluoride with a suitable inorganic binder forms a stable solid-film lubricant when fused to the surface to be lubricated. It is effective in environments at elevated temperatures and gas pressures ranging from atmospheric to high vacuum. It is not stable in reducing atmospheres.

  12. Solid state thin film battery having a high temperature lithium alloy anode

    DOEpatents

    Hobson, D.O.

    1998-01-06

    An improved rechargeable thin-film lithium battery involves the provision of a higher melting temperature lithium anode. Lithium is alloyed with a suitable solute element to elevate the melting point of the anode to withstand moderately elevated temperatures. 2 figs.

  13. Overcoats for the Improved Performance of PdCr High Temperature Thin Film Strain Gages

    NASA Technical Reports Server (NTRS)

    Gregory, Otto J.; Dyer, S. E.; Cooke, James D.

    1998-01-01

    Overcoat protection schemes for thin film devices have typically focused on inhibiting the growth of native oxides formed on the sensor surface, rather than on improving the passivating nature of these native oxides. Here, thin sputtered Cr overcoats and heat treatments in varying oxygen partial pressures enhanced the passivating nature of native Cr203 films formed on PdCr thin film strain gages. Results of strain tests using sensors protected using this approach are presented and the implications are discussed. PdCr gages with sputtered Cr overcoats withstood 12,000 dynamic strain cycles of 1100 micro-epsilon during 100 hours of testing at a temperature of 1000 C in air. Gage factors of 1.3 with drift rates as low as 0.1 Omega/hr were achieved for devices having a nominal resistance of approximately 100 Omega's. TCR's ranging from +550 ppm/C to +798 ppm/C were realized depending on the overcoat and thermal history. Possible mechanisms for an anomaly in the electrical characteristics of these films at 800 C and improvements in stability due to the use of overcoats are presented.

  14. Study of high temperature oxide superconductors

    NASA Astrophysics Data System (ADS)

    Wu, M. K.; Ashburn, J. R.; Higgins, C. A.; Carswell, W. E.; Loo, B. H.; Burns, D. H.; Ibrahim, A.; Rolin, T.; Peters, P. N.; Sisk, R. C.

    1988-01-01

    Experimental studies are reported whose results indicate that proper processing procedures are critical to the formation of high-temperature copper oxide superconductors. Superconducting 123 films can be fabricated using the green 211 phase as a substrate. The transition temperature and transition width characteristics of these films are better than those obtained when other oxide compounds are used as substrates. A compact or single-crystal 211 phase will be desirable as a substrate for high-quality thin films. A new high T(c) copper oxide compound with nonrare earth elements was prepared using high-temperature processing. A YBa2Cu3O7-Ag composite with improved electrical conductivity was also prepared.

  15. Review of high-temperature superconductivity and the effect of chemical modifications on Bi2Sr2CaCu2O8 and Bi2Sr2Ca2Cu3O10. Technical report

    SciTech Connect

    Jones, T.E.; McGinnis, W.C.; Boss, R.D.

    1991-08-01

    Perform chemical modifications to existing materials that may enhance their superconducting properties and provide insight into the mechanisms responsible for high-temperature superconductivity. This report presented a review of high-temperature superconductivity. An overview of superconductivity from its original discovery to the present is also given. Synthesized two sets of samples. One set was based on the structure Bi2Sr2CaCu2O8 and the other on Bi2Sr2Ca2Cu3O10. In both cases, the copper was partially replaced with elements from the first transition row of elements. The replacement was at the level of 5 mol.-% of the transition element for copper. The transition elements used were vanadium (V), manganese (Mn), titanium (Ti), nickel (Ni), zinc (Zn), cobalt (Co), and iron (Fe) and determined the effect of the substitutions on the crystal structure.

  16. A study on the electrical insulation properties of solid nitrogen for cooling of the high temperature superconducting systems

    NASA Astrophysics Data System (ADS)

    Choi, J. H.; Choi, J. W.; Lee, H.; Song, J. B.; Kim, H. J.; Seong, K. C.; Kim, S. H.

    2009-10-01

    Recently, for improvement of the magnetic field of high temperature superconductor (HTS) apparatus, many studies on operating in the temperature range of 20-65 K with liquid helium or the thermal conducting method using cryocooler are actively reviewed. Also, the cooling method of using solid nitrogen as cryogen is currently being suggested. Since nitrogen has a very large specific heat in solid state, it is expected that it can enable long-time operation without a continuous supply of cooling energy. However, there is still insufficient data on the characteristics of solid nitrogen such as thermodynamic properties and liquid-solid phase transition. Especially, there was almost no study done on the electrical insulation properties of solid nitrogen so far. In this study, solid nitrogen to find the electrical characteristics was made by using cryocooler and cryostat, and investigated the flashover discharge and breakdown. The results of this study will be useful as a basic data for electrical insulation design of the HTS system such as SMES using solid nitrogen as cryogen.

  17. Predicted Mechanical Behavior of High-Tc Superconducting Ceramic Films

    NASA Astrophysics Data System (ADS)

    Suhir, Ephraim

    1990-03-01

    In potential applications, the recently discovered high transition temperature (high-Tc) ceramic superconductors (Bednorz and Muller, 1986, Wu et al., 1987, Cava et al., 1987) may experience large mechanical stresses and strains. These can be imposed by magnet fabrication, high magnetic fields, and, in the case of superconducting films, also by thermal contraction mismatch with the substrate material (see, for instance, Baynham, 1988, Severin and de With, 1988). Although mechanical strength of a superconductor may appear to be not as important a property, as, say, high superconducting transition temperature, high upper critical magnetic field or high critical current density, it may play a decisive role, when a superconducting material is used for practical purposes. Since ceramics are brittle materials, and break quite easily when stretched, bent or hit, use of ceramics as practical superconductors requires that they possess high ultimate stress and strain, sufficient fracture toughness and good shock resistance. It is also important that the actual stresses and strains arising in superconducting ceramics at low temperatures can be predicted and, if possible, minimized.

  18. Operation of a 500 MHz high temperature superconducting NMR: towards an NMR spectrometer operating beyond 1 GHz.

    PubMed

    Yanagisawa, Y; Nakagome, H; Tennmei, K; Hamada, M; Yoshikawa, M; Otsuka, A; Hosono, M; Kiyoshi, T; Takahashi, M; Yamazaki, T; Maeda, H

    2010-04-01

    We have begun a project to develop an NMR spectrometer that operates at frequencies beyond 1 GHz (magnetic field strength in excess of 23.5 T) using a high temperature superconductor (HTS) innermost coil. As the first step, we developed a 500 MHz NMR with a Bi-2223 HTS innermost coil, which was operated in external current mode. The temporal magnetic field change of the NMR magnet after the coil charge was dominated by (i) the field fluctuation due to a DC power supply and (ii) relaxation in the screening current in the HTS tape conductor; effect (i) was stabilized by the 2H field-frequency lock system, while effect (ii) decreased with time due to relaxation of the screening current induced in the HTS coil and reached 10(-8)(0.01 ppm)/h on the 20th day after the coil charge, which was as small as the persistent current mode of the NMR magnet. The 1D (1)H NMR spectra obtained by the 500 MHz LTS/HTS magnet were nearly equivalent to those obtained by the LTS NMR magnet. The 2D-NOESY, 3D-HNCO and 3D-HNCACB spectra were achieved for ubiquitin by the 500 MHz LTS/HTS magnet; their quality was closely equivalent to that achieved by a conventional LTS NMR. Based on the results of numerical simulation, the effects of screening current-induced magnetic field changes are predicted to be harmless for the 1.03 GHz NMR magnet system.

  19. Operation of a 500 MHz high temperature superconducting NMR: towards an NMR spectrometer operating beyond 1 GHz.

    PubMed

    Yanagisawa, Y; Nakagome, H; Tennmei, K; Hamada, M; Yoshikawa, M; Otsuka, A; Hosono, M; Kiyoshi, T; Takahashi, M; Yamazaki, T; Maeda, H

    2010-04-01

    We have begun a project to develop an NMR spectrometer that operates at frequencies beyond 1 GHz (magnetic field strength in excess of 23.5 T) using a high temperature superconductor (HTS) innermost coil. As the first step, we developed a 500 MHz NMR with a Bi-2223 HTS innermost coil, which was operated in external current mode. The temporal magnetic field change of the NMR magnet after the coil charge was dominated by (i) the field fluctuation due to a DC power supply and (ii) relaxation in the screening current in the HTS tape conductor; effect (i) was stabilized by the 2H field-frequency lock system, while effect (ii) decreased with time due to relaxation of the screening current induced in the HTS coil and reached 10(-8)(0.01 ppm)/h on the 20th day after the coil charge, which was as small as the persistent current mode of the NMR magnet. The 1D (1)H NMR spectra obtained by the 500 MHz LTS/HTS magnet were nearly equivalent to those obtained by the LTS NMR magnet. The 2D-NOESY, 3D-HNCO and 3D-HNCACB spectra were achieved for ubiquitin by the 500 MHz LTS/HTS magnet; their quality was closely equivalent to that achieved by a conventional LTS NMR. Based on the results of numerical simulation, the effects of screening current-induced magnetic field changes are predicted to be harmless for the 1.03 GHz NMR magnet system. PMID:20149698

  20. Advanced APCVD-processes for high-temperature grown crystalline silicon thin film solar cells.

    PubMed

    Driessen, Marion; Merkel, Benjamin; Reber, Stefan

    2011-09-01

    Crystalline silicon thin film (cSiTF) solar cells based on the epitaxial wafer-equivalent (EpiWE) concept combine advantages of wafer-based and thin film silicon solar cells. In this paper two processes beyond the standard process sequence for cSiTF cell fabrication are described. The first provides an alternative to wet chemical saw damage removal by chemical vapor etching (CVE) with hydrogen chloride in-situ prior to epitaxial deposition. This application decreases the number of process and handling steps. Solar cells fabricated with different etching processes achieved efficiencies up to 14.7%. 1300 degrees C etching temperature led to better cell results than 1200 degrees C. The second investigated process aims for an improvement of cell efficiency by implementation of a reflecting interlayer between substrate and active solar cell. Some characteristics of epitaxial lateral overgrowth (ELO) of a patterned silicon dioxide film in a lab-type reactor constructed at Fraunhofer ISE are described and first solar cell results are presented.

  1. Enhanced p-type conduction of B-doped nanocrystalline diamond films by high temperature annealing

    SciTech Connect

    Gu, S. S.; Hu, X. J.

    2013-07-14

    We report the enhanced p-type conduction with Hall mobility of 53.3 cm{sup 2} V{sup -1} s{sup -1} in B-doped nanocrystalline diamond (NCD) films by 1000 Degree-Sign C annealing. High resolution transmission electronic microscopy, uv, and visible Raman spectroscopy measurements show that a part of amorphous carbon grain boundaries (GBs) transforms to diamond phase, which increases the opportunity of boron atoms located at the GBs to enter into the nano-diamond grains. This phase transition doping is confirmed by the secondary ion mass spectrum depth profile results that the concentration of B atoms in nano-diamond grains increases after 1000 Degree-Sign C annealing. It is also observed that 1000 Degree-Sign C annealing improves the lattice perfection, reduces the internal stress, decreases the amount of trans-polyacetylene, and increases the number or size of aromatic rings in the sp{sup 2}-bonded carbon cluster in B-doped NCD films. These give the contributions to improve the electrical properties of 1000 Degree-Sign C annealed B-doped NCD films.

  2. Ray optics behavior of flux avalanche propagation in superconducting films

    NASA Astrophysics Data System (ADS)

    Mikheenko, P.; Johansen, T. H.; Chaudhuri, S.; Maasilta, I. J.; Galperin, Y. M.

    2015-02-01

    Experimental evidence of wave properties of dendritic flux avalanches in superconducting films is reported. Using magneto-optical imaging the propagation of dendrites across boundaries between a bare NbN film and areas coated by a Cu layer was visualized, and it was found that the propagation is refracted in full quantitative agreement with Snell's law. For the studied film of 170 nm thickness and a 0.9 μ m thick metal layer, the refractive index was close to n =1.4 . The origin of the refraction is believed to be caused by the dendrites propagating as an electromagnetic shock wave, similar to damped modes considered previously for normal metals. The analogy is justified by the large dissipation during the avalanches raising the local temperature significantly. Additional time-resolved measurements of voltage pulses generated by segments of the dendrites traversing an electrode confirm the consistency of the adopted physical picture.

  3. Nanocomposite thin films for high temperature optical gas sensing of hydrogen

    DOEpatents

    Ohodnicki, Jr., Paul R.; Brown, Thomas D.

    2013-04-02

    The disclosure relates to a plasmon resonance-based method for H.sub.2 sensing in a gas stream at temperatures greater than about 500.degree. C. utilizing a hydrogen sensing material. The hydrogen sensing material is comprised of gold nanoparticles having an average nanoparticle diameter of less than about 100 nanometers dispersed in an inert matrix having a bandgap greater than or equal to 5 eV, and an oxygen ion conductivity less than approximately 10.sup.-7 S/cm at a temperature of 700.degree. C. Exemplary inert matrix materials include SiO.sub.2, Al.sub.2O.sub.3, and Si.sub.3N.sub.4 as well as modifications to modify the effective refractive indices through combinations and/or doping of such materials. At high temperatures, blue shift of the plasmon resonance optical absorption peak indicates the presence of H.sub.2. The method disclosed offers significant advantage over active and reducible matrix materials typically utilized, such as yttria-stabilized zirconia (YSZ) or TiO.sub.2.

  4. Atomic spin decoherence near conducting and superconducting films

    NASA Astrophysics Data System (ADS)

    Scheel, S.; Rekdal, P. K.; Knight, P. L.; Hinds, E. A.

    2005-10-01

    We derive scaling laws for the spin decoherence of neutral atoms trapped near conducting and superconducting plane surfaces. A result for thin films sheds light on the measurement of Y. J. Lin, I. Teper, C. Chin, and V. Vuletić [Phys. Rev. Lett. 92, 050404 (2004)]. Our calculation is based on a quantum-theoretical treatment of electromagnetic radiation near metallic bodies [P. K. Rekdal, S. Scheel, P. L. Knight, and E. A. Hinds, Phys. Rev. A 70, 013811 (2004)]. We show that there is a critical atom-surface distance that maximizes the spin relaxation rate and we show how this depends on the skin depth and thickness of the metal surface. In the light of this impedance-matching effect we discuss the spin relaxation to be expected above a thin superconducting niobium layer.

  5. Solid state microelectronics tolerant to radiation and high temperature. [JFET thick film hybrids

    NASA Technical Reports Server (NTRS)

    Draper, B. L.; Palmer, D. W.

    1981-01-01

    The 300 C electronics technology based on JFET thick film hybrids was tested up to 10 to the 9th power rad gamma (Si) and 10 to the 15th power neutrons/sq cm. Circuits and individual components from this technology all survived this total dose although some devices required 1 hour of annealing at 200 or 300 C to regain functionality. This technology used with real time annealing should function to levels greater than 10 to the 10th power rad gamma and 10 to the 16th power n/sq cm.

  6. Simulation of space radiation effects on polyimide film materials for high temperature applications

    NASA Technical Reports Server (NTRS)

    Fogdall, L. B.; Cannaday, S. S.

    1977-01-01

    Space environment effects on candidate materials for the solar sail film are determined. Polymers, including metallized polyimides that might be suitable solar radiation receivers, were exposed to combined proton and solar electromagnetic radiation. Each test sample was weighted, to simulate the tension on the polymer when it is stretched into near-planar shape while receiving solar radiation. Exposure rates up to 16 times that expected in Earth orbit were employed, to simulate near-sun solar sailing conditions. Sample appearance, elongation, and shrinkage were monitored, noted, and documented in situ. Thermosetting polyimides showed less degradation or visual change in appearance than thermoplastics.

  7. High-temperature large-gap quantum anomalous Hall insulating state in ultrathin double perovskite films

    NASA Astrophysics Data System (ADS)

    Baidya, Santu; Waghmare, Umesh V.; Paramekanti, Arun; Saha-Dasgupta, Tanusri

    2016-10-01

    Towards the goal of realizing topological phases in thin films of correlated oxide and heterostructures, we propose here a quantum anomalous Hall insulator (QAHI) in ultrathin films of double perovskites based on mixed 3 d -5 d or 3 d -4 d transition-metal ions, grown along the [111] direction. Considering the specific case of ultrathin Ba2FeReO6 , we present a theoretical analysis of an effective Hamiltonian derived from first principles. We establish that a strong spin-orbit coupling at the Re site, t2 g symmetry of the low-energy d bands, polarity of its [111] orientation of perovskite structure, and mixed 3 d -5 d chemistry results in room temperature magnetism with a robust QAHI state of Chern number C =1 and a large band gap. We uncover and highlight a nonrelativistic orbital Rashba-type effect in addition to the spin-orbit coupling, that governs this QAHI state. With a band gap of ˜100 meV in electronic structure and magnetic transition temperature Tc˜300 K estimated by Monte Carlo simulations, our finding of the QAHI state in ultrathin Ba2FeReO6 is expected to stimulate experimental verification along with possible practical applications of its dissipationless edge currents.

  8. Upward shift of the vortex solid phase in high-temperature-superconducting wires through high density nanoparticle addition.

    PubMed

    Miura, Masashi; Maiorov, Boris; Balakirev, Fedor F; Kato, Takeharu; Sato, Michio; Takagi, Yuji; Izumi, Teruo; Civale, Leonardo

    2016-02-08

    We show a simple and effective way to improve the vortex irreversibility line up to very high magnetic fields (60T) by increasing the density of second phase BaZrO3 nanoparticles. (Y0.77,Gd0.23)Ba2Cu3Oy films were grown on metal substrates with different concentration of BaZrO3 nanoparticles by the metal organic deposition method. We find that upon increase of the BaZrO3 concentration, the nanoparticle size remains constant but the twin-boundary density increases. Up to the highest nanoparticle concentration (n ~ 1.3 × 10(22)/m(3)), the irreversibility field (Hirr) continues to increase with no sign of saturation up to 60 T, although the vortices vastly outnumber pinning centers. We find extremely high Hirr, namely Hirr = 30 T (H||45°) and 24 T (H||c) at 65 K and 58 T (H||45°) and 45 T (H||c) at 50K. The difference in pinning landscape shifts the vortex solid-liquid transition upwards, increasing the vortex region useful for power applications, while keeping the upper critical field, critical temperature and electronic mass anisotropy unchanged.

  9. Upward shift of the vortex solid phase in high-temperature-superconducting wires through high density nanoparticle addition

    DOE PAGES

    Miura, Masashi; Maiorov, Boris; Balakirev, Fedor F.; Kato, Takeharu; Sato, Michio; Takagi, Yuji; Izumi, Teruo; Civale, Leonardo

    2016-02-08

    Here, we show a simple and effective way to improve the vortex irreversibility line up to very high magnetic fields (60T) by increasing the density of second phase BaZrO3 nanoparticles. (Y0.77,Gd0.23)Ba2Cu3Oy films were grown on metal substrates with different concentration of BaZrO3 nanoparticles by the metal organic deposition method. We find that upon increase of the BaZrO3 concentration, the nanoparticle size remains constant but the twin-boundary density increases. Up to the highest nanoparticle concentration (n ~ 1.3 × 1022/m3), the irreversibility field (Hirr) continues to increase with no sign of saturation up to 60 T, although the vortices vastly outnumbermore » pinning centers. We find extremely high Hirr, namely Hirr = 30 T (H||45°) and 24 T (H||c) at 65 K and 58 T (H||45°) and 45 T (H||c) at 50K. The difference in pinning landscape shifts the vortex solid-liquid transition upwards, increasing the vortex region useful for power applications, while keeping the upper critical field, critical temperature and electronic mass anisotropy unchanged.« less

  10. Upward shift of the vortex solid phase in high-temperature-superconducting wires through high density nanoparticle addition.

    PubMed

    Miura, Masashi; Maiorov, Boris; Balakirev, Fedor F; Kato, Takeharu; Sato, Michio; Takagi, Yuji; Izumi, Teruo; Civale, Leonardo

    2016-01-01

    We show a simple and effective way to improve the vortex irreversibility line up to very high magnetic fields (60T) by increasing the density of second phase BaZrO3 nanoparticles. (Y0.77,Gd0.23)Ba2Cu3Oy films were grown on metal substrates with different concentration of BaZrO3 nanoparticles by the metal organic deposition method. We find that upon increase of the BaZrO3 concentration, the nanoparticle size remains constant but the twin-boundary density increases. Up to the highest nanoparticle concentration (n ~ 1.3 × 10(22)/m(3)), the irreversibility field (Hirr) continues to increase with no sign of saturation up to 60 T, although the vortices vastly outnumber pinning centers. We find extremely high Hirr, namely Hirr = 30 T (H||45°) and 24 T (H||c) at 65 K and 58 T (H||45°) and 45 T (H||c) at 50K. The difference in pinning landscape shifts the vortex solid-liquid transition upwards, increasing the vortex region useful for power applications, while keeping the upper critical field, critical temperature and electronic mass anisotropy unchanged. PMID:26853703

  11. Upward shift of the vortex solid phase in high-temperature-superconducting wires through high density nanoparticle addition

    PubMed Central

    Miura, Masashi; Maiorov, Boris; Balakirev, Fedor F.; Kato, Takeharu; Sato, Michio; Takagi, Yuji; Izumi, Teruo; Civale, Leonardo

    2016-01-01

    We show a simple and effective way to improve the vortex irreversibility line up to very high magnetic fields (60T) by increasing the density of second phase BaZrO3 nanoparticles. (Y0.77,Gd0.23)Ba2Cu3Oy films were grown on metal substrates with different concentration of BaZrO3 nanoparticles by the metal organic deposition method. We find that upon increase of the BaZrO3 concentration, the nanoparticle size remains constant but the twin-boundary density increases. Up to the highest nanoparticle concentration (n ~ 1.3 × 1022/m3), the irreversibility field (Hirr) continues to increase with no sign of saturation up to 60 T, although the vortices vastly outnumber pinning centers. We find extremely high Hirr, namely Hirr = 30 T (H||45°) and 24 T (H||c) at 65 K and 58 T (H||45°) and 45 T (H||c) at 50K. The difference in pinning landscape shifts the vortex solid-liquid transition upwards, increasing the vortex region useful for power applications, while keeping the upper critical field, critical temperature and electronic mass anisotropy unchanged. PMID:26853703

  12. Stability of Tl-Ba-Ca-Cu-O Superconducting Thin Films

    SciTech Connect

    Siegal, M.P.; Overmyer, D.L.; Venturini, E.L.; Padilla, R.R.; Provencio, P.N.

    1999-08-23

    We report the stability of TlBa{sub 2}CaCu{sub 2}O{sub 7} (Tl-1212) and Tl{sub 2}Ba{sub 2}CaCu{sub 2}O{sub 8} (T1-2212) thin films and by inference, the stability of TlBa{sub 2}Ca{sub 2}Cu{sub 3}O{sub 9} (Tl-1223) and Tl{sub 2}Ba{sub 2}Ca{sub 2}Cu{sub 3}O{sub 10} (Tl-2223) thin films, under a variety of conditions. In general, we observe that the stability behavior of the single Tl-O layer materials (Tl-1212 and Tl-1223)are similar and the double Tl-O layer materials (Tl-2212 and Tl-2223) are similar. All films are stable with repeated thermal cycling to cryogenic temperatures. Films are also stable in acetone and methanol. Moisture degrades film quality rapidly, especially in the form of vapor. Tl-1212 is more sensitive to vapor than Tl-2212. These materials are stable to high temperatures in either N{sub 2}, similar to vacuum for the cuprates, and O{sub 2} ambients. While total degradation of properties (superconducting and structural) occur at the same temperatures for all phases, 600 C in N{sub 2} and 700 C in O{sub 2}, the onset of degradation occurs at somewhat lower temperatures for Tl-1212 than for Tl-2212 films. In all cases, sample degradation is associated with Tl depletion from the films.

  13. Interface enhanced superconductivity in single unit-cell FeSe films on SrTiO3(110)

    NASA Astrophysics Data System (ADS)

    Wang, Lili

    The advent of enhanced superconductivity in FeSe/STO(001) has instigated great interests in other interfacial systems both experimentally and theoretically. To figure out the key role of substrate, STO(110) substrate is of great interest because it resembles STO(001) in high density subsurface oxygen vacancies but distinguishes itself by anisotropic in-plane lattice constants and dielectric constant. Here, we investigated molecular beam epitaxy growth of 1-UC FeSe films on STO(110) substrates and studied the superconducting properties by combined in-situ scanning tunneling spectroscopy (STS) and ex-situ transport measurement. By STS we observed a superconducting gap as large as 17 meV. Transport measurements on 1-UC FeSe/STO(110) capped with FeTe layers reveal superconductivity with an onset transition temperature (TC) of 31.6 K and an upper critical magnetic field of 30.2 T. We also find that TC can be further increased by an external electric field, but the effect is weaker than that on STO(001) substrate. Our study highlights the important roles of interface related charge transfer and electron-phonon coupling in the high temperature superconductivity of FeSe/STO. References: [1] Q. Y. Wang, et al., Chin. Phys. Lett., 29, 037402 (2012). [2] J. J. Lee, Nature 515, 245 (2014).

  14. Superconducting properties of evaporated copper molybdenum sulfide films

    NASA Technical Reports Server (NTRS)

    Woollam, J. A.; Chi, K. C.; Dillon, R. O.; Bunshah, R. F.; Alterovitz, S. A.

    1978-01-01

    Films of copper molybdenum sulfide were produced by coevaporation. Those that were superconducting contained only the ternary compound and free molybdenum. The range of copper content in the ternary compound was as large as that in polycrystalline material, that is, it includes either phase alone, or a mixture of the two phases of this material. This is in contrast with sputtered materials where copper concentration has been limited to a narrower range. The upper critical field and the critical current were measured as functions of external magnetic field, and found to be similar to those of sputtered copper molybdenum sulfide, when the comparison was made for samples having the same amount of copper.

  15. Cathodic arc grown niobium films for RF superconducting cavity applications

    NASA Astrophysics Data System (ADS)

    Catani, L.; Cianchi, A.; Lorkiewicz, J.; Tazzari, S.; Langner, J.; Strzyzewski, P.; Sadowski, M.; Andreone, A.; Cifariello, G.; Di Gennaro, E.; Lamura, G.; Russo, R.

    2006-07-01

    Experimental results on the characterization of the linear and non-linear microwave properties of niobium film produced by UHV cathodic arc deposition are presented. Surface impedance Zs as a function of RF field and intermodulation distortion (IMD) measurement have been carried out by using a dielectrically loaded resonant cavity operating at 7 GHz. The experimental data show that these samples have a lower level of intrinsic non-linearities at low temperature and low circulating power in comparison with Nb samples grown by sputtering. These results make UHV cathodic arc deposition a promising technique for the improvement of RF superconducting cavities for particle accelerators.

  16. Superconducting microstrip resonator for pulsed ESR of thin films.

    PubMed

    Benningshof, O W B; Mohebbi, H R; Taminiau, I A J; Miao, G X; Cory, D G

    2013-05-01

    This article describes a superconducting microstrip resonator operating at 9.5 GHz (X-band) that is specially designed for pulsed ESR on thin films. A novel configuration consisting of an array of half-wave length microstrip transmission lines generates a uniform magnetic field over a 2-D region of 100×1000 μm(2) with field homogeneity better than 5×10(-2). Using the device, we demonstrate strong coupling of the resonator to an electron spin ensemble and pulsed ESR on Si:P.

  17. Conversion of microwave signals by superconducting films in the resistive state

    NASA Technical Reports Server (NTRS)

    Yeru, I. I.; Peskovatskiy, S. A.; Sulima, V. S.

    1984-01-01

    The main characteristics of a superconducting thin film microwave mixer, i.e., conversion efficiency and bandwidth are analyzed. The optimum operating regime of the nonlinear element is determined. Results of calculations are compared with the experimental ones. Experimental data on the noise in the superconducting films in a wide frequency range are presented.

  18. Epitaxial Ba-Y-Cu-O ceramic superconducting film on perovskite structure substrate

    SciTech Connect

    Chai, B.H.

    1991-07-09

    This patent describes a superconducting structure. It comprises a crystal substrate having a superconducting film epitaxially deposited thereon, wherein the substrate is a crystal selected from the group consisting of LaAlO{sub 3}, LaGaO{sub 3}, PrGaO{sub 3} and NdGaO{sub 3}, and wherein the superconducting film is a Ba- Y- Cu- O superconductor.

  19. Suppressed gross erosion of high-temperature lithium films under high-flux deuterium bombardment

    NASA Astrophysics Data System (ADS)

    Abrams, Tyler; Jaworski, M. A.; Kaita, R.; Capece, A. M.; Nichols, J. H.; Stotler, D. P.; Roszell, J. P.; de Temmerman, G.; van den Berg, M. A.; van der Meiden, H. J.; Morgan, T. W.

    2014-10-01

    Liquid lithium is an attractive plasma facing component (PFC) for a fusion reactor because it improves confinement and protects the underlying substrate from high heat fluxes. However some previous studies have implied the maximum Li temperature permitted on such devices may be unacceptably low. Recently thin (<1 μm) and thick (~500 μm) Li films on TZM molybdenum substrates were studied in the Magnum-PSI linear plasma device with ion fluxes >1024 m-2 s1 and Li surface temperatures <= 800 °C. Measured Li erosion yields under neon plasma bombardment were similar to previous studies on low-flux devices, but erosion under deuterium bombardment was significantly suppressed. This motivated development of a mixed-material Li-D surface model incorporating D diffusion in Li, preferential sputtering, and LiD chemistry. This model is coupled to the adatom-evaporation equation for thermally-enhanced sputtering and the Langmuir law evaporation equation to obtain realistic predictions of temperature-dependent erosion rates. This model is found to predict the correct functional dependence of the mixed-material Li-D erosion rate vs. temperature in these discharges. Further investigations via molecular dynamics (MD) simulations and surface science experiments will also be presented. This work supported by US DOE Contract DE-AC02-09CH11466.

  20. Stresses evolution at high temperature (200°C) on the interface of thin films in magnetic components

    NASA Astrophysics Data System (ADS)

    Doumit, Nicole; Danoumbé, Bonaventure; Capraro, Stéphane; Chatelon, Jean-Pierre; Nader, Chadi; Habchi, Roland; Piot, Alain; Rousseau, Jean-Jacques

    2014-07-01

    In the field of electronics, the increase of operating temperatures is a major industrial and scientific challenge because it allows reducing mass and volume of components especially in the aeronautic domain. So minimizing our components reduce masses and the use of cooling systems. For that, the behaviours and interface stresses of our components (in particular magnetic inductors and transformers) that are constituted of one magnetic layer (YIG) or an alumina substrate (Al2O3) representing the substrate and a thin copper film are studied at high temperature (200°C). COMSOL Multiphysics is used to simulate our work and to validate our measurements results. In this paper, we will present stresses results according to the geometrical copper parameters necessary for the component fabrication. Results show that stresses increase with temperature and copper's thickness while remaining always lower than 200MPa which is the rupture stress value.

  1. A facile approach to derive binder protective film on high voltage spinel cathode materials against high temperature degradation

    NASA Astrophysics Data System (ADS)

    Chou, Wei-Yu; Jin, Yi-Chun; Duh, Jenq-Gong; Lu, Cheng-Zhang; Liao, Shih-Chieh

    2015-11-01

    The electrochemical performance of spinel LiNi0.5Mn1.5O4 cathode combined with different binders at elevated temperature is firstly investigated. The water soluble binder, such as sodium carboxymethyl cellulose (CMC) and sodium alginate (SA), is compared with the polyvinylidene difluoride (PVdF) binder used in non-aqueous process. The aqueous process can meet the need of Li-ion battery industry due to environmental-friendly and cost effectiveness by replacing toxic organic solvent, such as N-methyl-pyrrolidone (NMP). In this study, a significantly improved high temperature cycling performance is successfully obtained as compared to the traditional PVdF binder. The aqueous binder can serve as a protective film which inhibits the serious Ni and Mn dissolution especially at elevated temperature. Our result demonstrates a facile approach to solve the problem of capacity fading for high voltage spinel cathodes.

  2. Microwave surface resistance of high Tc superconducting films

    NASA Astrophysics Data System (ADS)

    Apte, Prakash R.; Pinto, R.; Kumar, Dhananjay; Vijayaraghavan, R.

    1995-09-01

    The surface resistance, Rs, at microwave frequencies has been an important qualification parameter for high temperature superconductor (HTS) thin films. HTS thin films with low Rs have been realized on many substrates, and many groups have realized Rs values in the range 300 - 400 (mu) (Omega) at 10 GHz at 77 K with YBa2Cu3O7-(delta ) (YBCO) films on <100> LaAlO3 substrates. Both microstrip resonator and parallel plate resonator techniques are being used to measure Rs values of HTS thin films. It has been observed that the value of Rs at given frequency and temperature critically depends upon the epitaxial quality and granularity of the films. For example, YBCO films grown on <100> MgO have been found to be granular and weak link limited with a significant microwave power dependence of Rs. On the other hand, YBCO films insitu grown on <100> LaAlO3 have shown better epitaxy with low Rs. This is obviously due to the much better lattice match of YBCO with <100> LaAlO3 if the targets used for laser deposition are doped with Ag. Extensive work carried out in our laboratory has shown that a Ag-doping level of around 5 wt.% in YBCO is the optimum which results in YBCO films of much improved quality. We have realized Ag-doped YBCO films with Jc values of 6 - 8 X 106 Acm-2 at 77 K and a low Rs value of 210 (mu) (Omega) at 10 GHz at 77 K on <100> LaAlO3. Both these values are the best realized on LaAlO3 to date. What is equally important is the fact that with Ag-doping the reproducibility of the epitaxial quality of the films improves significantly. This has been found to be due to the enhanced oxygenation of films during growth and the surfactant effect of Ag. Experiments have shown that even the optimum temperature for insitu growth in reduced considerably by Ag-doping. It must be mentioned, however, that the only negative aspect of Ag-doping is the higher microwave residual surface resistance, Rres, observed in these films at (very) low temperatures. This is obviously due

  3. High-temperature dc superconducting quantum interference device with deep-submicron YBa sub 2 Cu sub 3 O sub 7 weak links

    SciTech Connect

    Romaine, S.E.; Mankiewich, P.M.; Skocpol, W.J. ); Westerwick, E. )

    1991-11-11

    We have fabricated a YBa{sub 2}Cu{sub 3}O{sub 7} (YBCO) thin-film dc superconducting quantum interference device (SQUID) with lithographically defined deep-submicron weak links. At 77 K the voltage response to dc flux is sinusoidal and nonhysteretic, with maximum peak-to-peak amplitude of 5 {mu}V. The maximum response is 8 {mu}V at 70 K, where 2{ital LI}{sub 0}/{Phi}{sub 0}{approx}1. At lower temperatures, the maximum response oscillates in the range 4--6 {mu}V. Random telegraph noise was observed near 30--40 K. Well-behaved Shapiro steps were observable at all measured temperatures below {ital T}{sub {ital c}}.

  4. Low-loss terahertz metamaterial from superconducting niobium nitride films.

    PubMed

    Zhang, C H; Wu, J B; Jin, B B; Ji, Z M; Kang, L; Xu, W W; Chen, J; Tonouchi, M; Wu, P H

    2012-01-01

    This paper reports a type of low Ohmic loss terahertz (THz) metamaterials made from low-temperature superconducting niobium nitride (NbN) films. Its resonance properties are studied by THz time domain spectroscopy. Our experiments show that its unloaded quality factor reaches as high as 178 at 8 K with the resonance frequency at around 0.58 THz, which is about 24 times that of gold metamaterial at the same temperature. The unloaded quality factor keeps at a high level, above 90, even when the resonance frequency increases to 1.02 THz, which is close to the gap frequency of NbN film. All these experimental observations fit well into the framework of Bardeen-Copper-Schrieffer theory and equivalent circuit model. These new metamaterials offer an efficient way to the design and implementation of high performance THz electronic devices.

  5. Impact of Edge-Barrier Pinning in Superconducting Thin Films

    SciTech Connect

    Jones, W. A.; Barnes, P.N.; Mullins, M. J.; Baca, F. J.; Emergo, R. L. S.; Wu, J.; Haugan, T. J.; Clem, J. R.

    2010-12-30

    It has been suggested that edge-barrier pinning might cause the critical current density (J{sub c}) in bridged superconducting films to increase. Subsequent work indicated that this edge-barrier effect does not impact bridges larger than 1 {micro}m. However, we provide a theoretical assessment with supporting experimental data suggesting edge-barrier pinning can significantly enhance J{sub c} for bridges of a few microns or even tens of microns thus skewing any comparisons among institutions. As such, when reporting flux pinning and superconductor processing improvements for J{sub c} comparisons, the width of the sample has to be taken into consideration as is currently done with film thickness.

  6. Edge tunneling of vortices in superconducting thin films

    SciTech Connect

    Iengo, R. |; Jug, G. |

    1996-11-01

    We investigate the phenomenon of the decay of a supercurrent due to the zero-temperature quantum tunneling of vortices from the edge in a thin superconducting film in the absence of an external magnetic field. An explicit formula is derived for the tunneling rate of vortices, which are subject to the Magnus force induced by the supercurrent, through the Coulomb-like potential barrier binding them to the film{close_quote}s edge. Our approach ensues from the nonrelativistic version of a Schwinger-type calculation for the decay of the two-dimensional vacuum previously employed for describing vortex-antivortex pair nucleation in the bulk of the sample. In the dissipation-dominated limit, our explicit edge-tunneling formula yields numerical estimates which are compared with those obtained for bulk nucleation to show that both mechanisms are possible for the decay of a supercurrent. {copyright} {ital 1996 The American Physical Society.}

  7. Enhancement of the finite-frequency superfluid response in the pseudogap regime of strongly disordered superconducting films

    PubMed Central

    Mondal, Mintu; Kamlapure, Anand; Ganguli, Somesh Chandra; Jesudasan, John; Bagwe, Vivas; Benfatto, Lara; Raychaudhuri, Pratap

    2013-01-01

    The persistence of a soft gap in the density of states above the superconducting transition temperature Tc, the pseudogap, has long been thought to be a hallmark of unconventional high-temperature superconductors. However, in the last few years this paradigm has been strongly revised by increasing experimental evidence for the emergence of a pseudogap state in strongly-disordered conventional superconductors. Nonetheless, the nature of this state, probed primarily through scanning tunneling spectroscopy (STS) measurements, remains partly elusive. Here we show that the dynamic response above Tc, obtained from the complex ac conductivity, is highly modified in the pseudogap regime of strongly disordered NbN films. Below the pseudogap temperature, T*, the superfluid stiffness acquires a strong frequency dependence associated with a marked slowing down of critical fluctuations. When translated into the length-scale of fluctuations, our results suggest a scenario of thermal phase fluctuations between superconducting domains in a strongly disordered s-wave superconductor. PMID:23446946

  8. Analysis of the proximity function in electron-beam lithography on high-? superconducting thin-films

    NASA Astrophysics Data System (ADS)

    Gueorguiev, Y. M.; Vutova, K. G.; Mladenov, G. M.

    1996-07-01

    In this paper we approximate by the combination of double Gaussian and exponential functions the radial distributions of the absorbed electron energy density in a 125 nm PMMA resist layer on 0953-2048/9/7/009/img2 thin-film/substrate targets obtained by means of Monte Carlo simulation for a zero-width 0953-2048/9/7/009/img3-function and the following variables (i) the substrate material (0953-2048/9/7/009/img4 and MgO), (ii) the electron beam energy 0953-2048/9/7/009/img5 (25, 50 and 75 keV) and (iii) the 0953-2048/9/7/009/img2 film thickness d (0, 100, 200 and 300 nm). The values of the parameters of the analytical function are calculated using an original Monte Carlo technique. These values are presented in the form of 3D diagrams which show their dependences on beam energy and on high-temperature superconducting film thickness and can also be used for approximate determination of the parameters at different initial conditions.

  9. Development and testing of a 2.5 kW synchronous generator with a high temperature superconducting stator and permanent magnet rotor

    NASA Astrophysics Data System (ADS)

    Qu, Timing; Song, Peng; Yu, Xiaoyu; Gu, Chen; Li, Longnian; Li, Xiaohang; Wang, Dewen; Hu, Boping; Chen, Duxing; Zeng, Pan; Han, Zhenghe

    2014-04-01

    High temperature superconducting (HTS) armature windings have the potential for increasing the electric loading of a synchronous generator due to their high current transport capacity, which could increase the power density of an HTS rotating machine. In this work, a novel synchronous generator prototype with an HTS stator and permanent magnet rotor has been developed. It has a basic structure of four poles and six slots. The armature winding was constructed from six double-pancake race-track coils with 44 turns each. It was designed to deliver 2.5 kW at 300 rpm. A concentrated winding configuration was proposed, to prevent interference at the ends of adjacent HTS coils. The HTS stator was pressure mounted into a hollow Dewar cooled with liquid nitrogen. The whole stator could be cooled down to around 82 K by conduction cooling. In the preliminary testing, the machine worked properly and could deliver 1.8 kW power when the armature current was 14.4 A. Ic for the HTS coils was found to be suppressed due to the influence of the temperature and the leakage field.

  10. Generalized proximity effect model in superconducting bi- and trilayer films

    SciTech Connect

    Brammertz, G.; Poelaert, A.; Golubov, A. A.; Verhoeve, P.; Peacock, A.; Rogalla, H.

    2001-07-01

    This article presents a general model for calculating the density of states and the Cooper pair potential in proximity-coupled superconducting bi- and trilayer films. It is valid for any kind of bilayer S{sub 1}-S{sub 2}, whatever the quality of the materials S{sub 1} and S{sub 2}, the quality of the S{sub 1}-S{sub 2} interface, and the layer thicknesses. The trilayer model is valid for a thin S{sub 3} layer, whereas the other two layers have arbitrary thicknesses. Although the equations of the dirty limit are used, it is argued that the model stays valid in clean bi-and trilayer films. The typical example of superconducting tunnel junctions is used to show that existing models, which apply to very thin or very thick layers or to perfectly transparent S{sub 1}-S{sub 2} interfaces, are too restrictive to apply to an arbitrary bilayer. The new model is applied to practical junctions, with layer thicknesses intermediate between the {open_quotes}thick{close_quotes} and the {open_quotes}thin{close_quotes} approximation. {copyright} 2001 American Institute of Physics.

  11. Optical detector prepared by high-Tc superconducting thin film

    NASA Astrophysics Data System (ADS)

    Wang, Lingjie; Zhou, Fang Q.; Zhao, Xing R.; Sun, Han D.; Yi, Xin J.

    1991-12-01

    An optical detector prepared by high T(subscript c) superconducting thin film has been discussed. The device has been made from YBaCuO superconducting thin film with zero resistance at more than 80 K on a ZrO(subscript 2) substrate. A pattern of the device with the dimension of the microbridge is formed through photolithographic process. Electrical contacts are made by evaporating gold or silver with thickness of 0.5 - 1 micrometers . The sample is then placed in a dewar with an infrared window and is cooled by liquid nitrogen. A blackbody source at 800 K is used to measure the responsivity of the detector, and the infrared radiation is chopped at frequencies between 6.3 and 2000 Hz. The detector output with the detectivity larger than 10(superscript 9) cmHz(superscript 1/2)/w and a typical responsivity value as large as 10(superscript 3) V/w is observed on both lock-in amplifier and root-mean-square voltmeter. In addition, the mechanism of optical detection and the methods to improve the sensitivity have been described.

  12. Tunneling into thin superconducting films: Interface-induced quasiparticle lifetime reduction

    NASA Astrophysics Data System (ADS)

    Löptien, P.; Zhou, L.; Khajetoorians, A. A.; Wiebe, J.; Wiesendanger, R.

    2016-01-01

    Scanning tunneling spectroscopy measurements of superconducting thin lanthanum films grown on a normal metal tungsten substrate reveal an extraordinarily large broadening of the coherence peaks. The observed broadening corresponds to very short electron-like quasiparticle lifetimes in the tunneling process. A thorough analysis considering the different relaxation processes reveals that the dominant mechanism is an efficient quasiparticle relaxation at the interface between the superconducting film and the underlying substrate. This process is of general relevance to scanning tunneling spectroscopy studies on thin superconducting films and enables measurements of film thicknesses via a spectroscopic method.

  13. High-field magnets using high-critical-temperature superconducting thin films

    DOEpatents

    Mitlitsky, Fred; Hoard, Ronald W.

    1994-01-01

    High-field magnets fabricated from high-critical-temperature superconducting ceramic (HTSC) thin films which can generate fields greater than 4 Tesla. The high-field magnets are made of stackable disk-shaped substrates coated with HTSC thin films, and involves maximizing the critical current density, superconducting film thickness, number of superconducting layers per substrate, substrate diameter, and number of substrates while minimizing substrate thickness. The HTSC thin films are deposited on one or both sides of the substrates in a spiral configuration with variable line widths to increase the field.

  14. High-field magnets using high-critical-temperature superconducting thin films

    DOEpatents

    Mitlitsky, F.; Hoard, R.W.

    1994-05-10

    High-field magnets fabricated from high-critical-temperature superconducting ceramic (HTSC) thin films which can generate fields greater than 4 Tesla are disclosed. The high-field magnets are made of stackable disk-shaped substrates coated with HTSC thin films, and involves maximizing the critical current density, superconducting film thickness, number of superconducting layers per substrate, substrate diameter, and number of substrates while minimizing substrate thickness. The HTSC thin films are deposited on one or both sides of the substrates in a spiral configuration with variable line widths to increase the field. 4 figures.

  15. Microwave response of high transition temperature superconducting thin films

    NASA Technical Reports Server (NTRS)

    Miranda, Felix Antonio

    1991-01-01

    We have studied the microwave response of YBa2Cu3O(7 - delta), Bi-Sr-Ca-Cu-O, and Tl-Ba-Ca-Cu-O high transition temperature superconducting (HTS) thin films by performing power transmission measurements. These measurements were carried out in the temperature range of 300 K to 20 K and at frequencies within the range of 30 to 40 GHz. Through these measurements we have determined the magnetic penetration depth (lambda), the complex conductivity (sigma(sup *) = sigma(sub 1) - j sigma(sub 2)) and the surface resistance (R(sub s)). An estimate of the intrinsic penetration depth (lambda approx. 121 nm) for the YBa2Cu3O(7 - delta) HTS has been obtained from the film thickness dependence of lambda. This value compares favorably with the best values reported so far (approx. 140 nm) in single crystals and high quality c-axis oriented thin films. Furthermore, it was observed that our technique is sensitive to the intrinsic anisotropy of lambda in this superconductor. Values of lambda are also reported for Bi-based and Tl-based thin films. We observed that for the three types of superconductors, both sigma(sub 1) and sigma(sub 2) increased when cooling the films below their transition temperature. The measured R(sub s) are in good agreement with other R(sub S) values obtained using resonant activity techniques if we assume a quadratic frequency dependence. Our analysis shows that, of the three types of HTS films studied, the YBa2Cu3O(7 - delta) thin film, deposited by laser ablation and off-axis magnetron sputtering are the most promising for microwave applications.

  16. Application of indium tin oxide (ITO) thin film as a low emissivity film on Ni-based alloy at high temperature

    NASA Astrophysics Data System (ADS)

    Sun, Kewei; Zhou, Wancheng; Tang, Xiufeng; Luo, Fa

    2016-09-01

    Indium tin oxide (ITO) films as the low emissivity coatings of Ni-based alloy at high temperature were studies. ITO films were deposited on the polished surface of alloy K424 by direct current magnetron sputtering. These ITO-coated samples were heat-treated in air at 600-900 °C for 150 h to explore the effect of high temperature environment on the emissivity. The samples were analyzed by X-ray diffraction (XRD), SEM and EDS. The results show that the surface of sample is integrity after heat processing at 700 °C and below it. A small amount of fine crack is observed on the surface of sample heated at 800 °C and Ti oxide appears. There are lots of fine cracks on the sample annealed at 900 °C and a large number of various oxides are detected. The average infrared emissivities at 3-5 μm and 8-14 μm wavebands were tested by an infrared emissivity measurement instrument. The results show the emissivity of the sample after annealed at 600 and 700 °C is still kept at a low value as the sample before annealed. The ITO film can be used as a low emissivity coating of super alloy K424 up to 700 °C.

  17. Dichotomy of the electronic structure and superconductivity between single-layer and double-layer FeSe/SrTiO3 films.

    PubMed

    Liu, Xu; Liu, Defa; Zhang, Wenhao; He, Junfeng; Zhao, Lin; He, Shaolong; Mou, Daixiang; Li, Fangsen; Tang, Chenjia; Li, Zhi; Wang, Lili; Peng, Yingying; Liu, Yan; Chen, Chaoyu; Yu, Li; Liu, Guodong; Dong, Xiaoli; Zhang, Jun; Chen, Chuangtian; Xu, Zuyan; Chen, Xi; Ma, Xucun; Xue, Qikun; Zhou, X J

    2014-09-23

    The latest discovery of possible high-temperature superconductivity in the single-layer FeSe film grown on a SrTiO3 substrate has generated much attention. Initial work found that, while the single-layer FeSe/SrTiO3 film exhibits a clear signature of superconductivity, the double-layer film shows an insulating behaviour. Such a marked layer-dependent difference is surprising and the underlying origin remains unclear. Here we report a comparative angle-resolved photoemission study between the single-layer and double-layer FeSe/SrTiO3 films annealed in vacuum. We find that, different from the single-layer FeSe/SrTiO3 film, the double-layer FeSe/SrTiO3 film is hard to get doped and remains in the semiconducting/insulating state under an extensive annealing condition. Such a behaviour originates from the much reduced doping efficiency in the bottom FeSe layer of the double-layer FeSe/SrTiO3 film from the FeSe-SrTiO3 interface. These observations provide key insights in understanding the doping mechanism and the origin of superconductivity in the FeSe/SrTiO3 films.

  18. Observation of Double-Dome Superconductivity in Potassium-Doped FeSe Thin Films.

    PubMed

    Song, Can-Li; Zhang, Hui-Min; Zhong, Yong; Hu, Xiao-Peng; Ji, Shuai-Hua; Wang, Lili; He, Ke; Ma, Xu-Cun; Xue, Qi-Kun

    2016-04-15

    We report on the emergence of two disconnected superconducting domes in alkali-metal potassium- (K-)doped FeSe ultrathin films grown on graphitized SiC(0001). The superconductivity exhibits hypersensitivity to K dosage in the lower-T_{c} dome, whereas in the heavily electron-doped higher-T_{c} dome it becomes spatially homogeneous and robust against disorder, supportive of a conventional Cooper-pairing mechanism. Furthermore, the heavily K-doped multilayer FeSe films all reveal a large superconducting gap of ∼14  meV, irrespective of film thickness, verifying the higher-T_{c} superconductivity only in the topmost FeSe layer. The unusual finding of a double-dome superconducting phase is a step towards the mechanistic understanding of superconductivity in FeSe-derived superconductors.

  19. Superconductivity applications for infrared and microwave devices; Proceedings of the Meeting, Orlando, FL, Apr. 19, 20, 1990

    NASA Technical Reports Server (NTRS)

    Bhasin, Kul B. (Editor); Heinen, Vernon O. (Editor)

    1990-01-01

    Various papers on superconductivity applications for IR and microwave devices are presented. The individual topics addressed include: pulsed laser deposition of Tl-Ca-Ba-Cu-O films, patterning of high-Tc superconducting thin films on Si substrates, IR spectra and the energy gap in thin film YBa2Cu3O(7-delta), high-temperature superconducting thin film microwave circuits, novel filter implementation utilizing HTS materials, high-temperature superconductor antenna investigations, high-Tc superconducting IR detectors, high-Tc superconducting IR detectors from Y-Ba-Cu-O thin films, Y-Ba-Cu0-O thin films as high-speed IR detectors, fabrication of a high-Tc superconducting bolometer, transition-edge microbolometer, photoresponse of YBa2Cu3O(7-delta) granular and epitaxial superconducting thin films, fast IR response of YBCO thin films, kinetic inductance effects in high-Tc microstrip circuits at microwave frequencies.

  20. High temperature measurement set-up for the electro-mechanical characterization of robust thin film systems

    NASA Astrophysics Data System (ADS)

    Fricke, S.; Friedberger, A.; Seidel, H.; Schmid, U.

    2014-01-01

    Due to economic and environmental requirements there is a strong need both to increase the efficiency and to monitor the actual status of gas turbines, rocket engines and deep drilling systems. For these applications, micromachined pressure sensors based on a robust substrate material (e.g. sapphire) as well as strain gauges made of platinum for long-term stable operation are regarded as most promising to withstand harsh environments such as high temperature levels, aggressive media and/or high pressure loads. For pre-evaluation purposes, a novel, custom-built measurement set-up is presented allowing the determination of electro-mechanical thin film properties up to 850 °C. Key components of the measurement set-up are the one-sided clamped beam made of Al2O3 ceramics which is deflected by a quartz rod and a high precision encoder-controlled dc motor to drive the quartz rod. The specific arrangement of the infrared halogen heaters in combination with the gold coated quartz half shells ensures a high degree of temperature homogeneity along the beam axis. When exposed to tensile as well as compressive load conditions, the corresponding gauge factor values of 1 µm thick platinum thin films show a good comparison at room temperature and in the temperature range from 600 up to 850 °C where the effects originating from grain boundaries or from the film surfaces are negligible. Between 150 and 600 °C, however, a strong deviation in the gauge factor determination depending on the mechanical load condition is observed, which is attributed to the gliding of adjacent grains.

  1. Superconductivity in Epitaxial Thin Films of Fe1:08Te:Ox

    SciTech Connect

    Gu, G.; Si, W.; Jie, Q.; Wu, L.; Zhou, J.; Johnson, P.D.; Li, Q.

    2010-03-01

    Superconducting thin films of Fe{sub 1.08}Te:O{sub x} have been epitaxially grown on SrTiO{sub 3} substrates by pulsed-laser deposition in controlled oxygen atmosphere. Although the bulk Fe{sub 1.08}Te is not superconducting, thin films with oxygen are superconducting with an onset and a zero resistance transition temperature around 12 and 8 K, respectively. Oxygen was found to be crucial to the superconducting properties of these films, suggesting that the oxygen incorporation can induce superconductivity in FeTe thin films. A metal-insulator transition is found at about 60 K, lower than that of bulk ({approx}70 K). From magnetoresistive measurements, we obtained the irreversibility line and the upper critical field.

  2. Sequentially evaporated thin Y-Ba-Co-O superconducting films on microwave substrates

    NASA Technical Reports Server (NTRS)

    Valco, G. J.; Rohrer, N. J.; Warner, J. D.; Bhasin, K. B.

    1989-01-01

    The development of high T sub c superconducting thin films on various microwave substrates is of major interest in space electronic systems. Thin films of YBa2Cu3O(7-Delta) were formed on SrTiO3, MgO, ZrO2 coated Al2O3, and LaAlO3 substrates by multi-layer sequential evaporation and subsequent annealing in oxygen. The technique allows controlled deposition of Cu, BaF2 and Y layers, as well as the ZrO buffer layers, to achieve reproducibility for microwave circuit fabrication. The three layer structure of Cu/BaF2/Y is repeated a minimum of four times. The films were annealed in an ambient of oxygen bubbled through water at temperatures between 850 C and 900 C followed by slow cooling (-2 C/minute) to 450 C, a low temperature anneal, and slow cooling to room temperature. Annealing times ranged from 15 minutes to 5 hrs. at high temperature and 0 to 6 hr. at 450 C. Silver contacts for four probe electrical measurements were formed by evaporation followed with an anneal at 500 C. The films were characterized by resistance-temperature measurements, energy dispersive X-ray spectroscopy, X-ray diffraction, and scanning electron microscopy. Critical transition temperatures ranged from 30 K to 87 K as a function of the substrate, composition of the film, thicknesses of the layers, and annealing conditions. Microwave ring resonator circuits were also patterned on these MgO and LaAlO3 substrates.

  3. Superconducting YBCO thin film on multicrystalline Ag film evaporated on MgO substrate

    NASA Astrophysics Data System (ADS)

    Azoulay, Jacob; Verdyan, Armen; Lapsker, Igor

    Superconducting YBa 2Cu 3O 7-δ films were grown by resistive evaporation on multicrystalline silver film which was evaporated on MgO substrate. A simple inexpensive vacuum system equipped with resistively heated boat was used for the whole process. Silver film was first evaporated on MgO substrate kept at 400°C during the evaporation after which with no further annealing a precursor mixture of yttrium small grains and Cu and BaF2 in powder form weighed in the atomic proportion to yield stoichiometric YBa 2Cu 3O 7 was evaporated. The films thus obtained were annealed at 740°C under low oxygen partial pressure of about 1Pa for 30 minutes to form the superconducting phase. X-ray diffraction and scanning electron microscopy techniques were used for texture and surface analysis. Electrical properties were determined using a standard dc four-probe for electrical measurements. The physical and electrical properties of the YBCO films are discussed in light of the fact that X-ray diffraction measurements done on the silver film have revealed a multicrystalline structure

  4. Frequency Noise in Superconducting Thin-Film Resonators

    NASA Astrophysics Data System (ADS)

    Kumar, Shwetank; Day, Peter; Leduc, Henry; Mazin, Benjamin; Eckart, Megan; Gao, Jiansong; Zmuidzinas, Jonas

    2006-03-01

    We present the results of low temperature (120 -- 1200 mK) noise measurements performed on thin-film superconducting niobium resonators fabricated on a silicon substrate. The devices studied use coplanar waveguide (CPW) transmission lines and have resonance frequencies of around 4 GHz and quality factors in the range of Q ˜ 10^4 to 10^6. These resonators are similar to those used to make novel photon detectors and read out charge qubits. These resonators show excess frequency noise which varies as approximately f-1/2. This excess noise limits the sensitivity of our photon detectors and likely effects the qubit performance as well. Two level systems (TLS) in amorphous thin-film dielectrics and oxide tunnel barriers have been shown to cause dissipation and decoherence in phase qubits. We suggest that noise in our resonators is also caused by TLS most likely near the surfaces of the substrate and metal films. To test this idea, we have measured the frequency shift, the quality factor and the frequency noise as a function of the device temperature and the microwave readout power. The frequency shift data agrees well with existing weak field TLS theory. We also find that the frequency noise decreases with increasing readout power and temperature and that decreased noise at higher powers is not due to simply device heating.

  5. Study of high [Tc] superconducting thin films grown by MOCVD

    SciTech Connect

    Erbil, A.

    1990-01-01

    Work is described briefly, which was carried out on development of techniques to grow metal-semiconductor superlattices (artificially layered materials) and on the copper oxide based susperconductors (naturally layered materials). The current growth technique utilized is metalorganic chemical vapor deposition (MOCVD). CdTe, PbTe, La, LaTe, and Bi[sub 2]Te[sub 3] were deposited, mostly on GaAs. Several YBa[sub 2]Cu[sub 3]O[sub 7] compounds were obtained with possible superconductivity at temperatures up to 550 K (1 part in 10[sup 4]). YBa[sub 2]Cu[sub 3]O[sub 7[minus]x] and Tl[sub 2]CaBa[sub 2]Cu[sub 2]O[sub y] thin films were deposited by MOCVD on common substrates such as glass.

  6. Highly textured oxypnictide superconducting thin films on metal substrates

    NASA Astrophysics Data System (ADS)

    Iida, Kazumasa; Kurth, Fritz; Chihara, Masashi; Sumiya, Naoki; Grinenko, Vadim; Ichinose, Ataru; Tsukada, Ichiro; Hänisch, Jens; Matias, Vladimir; Hatano, Takafumi; Holzapfel, Bernhard; Ikuta, Hiroshi

    2014-10-01

    Highly textured NdFeAs(O,F) thin films have been grown on ion beam assisted deposition-MgO/Y2O3/Hastelloy substrates by molecular beam epitaxy. The oxypnictide coated conductors showed a superconducting transition temperature (Tc) of 43 K with a self-field critical current density (Jc) of 7.0 × 10 4 A / cm 2 at 5 K, more than 20 times higher than powder-in-tube processed SmFeAs(O,F) wires. Albeit higher Tc as well as better crystalline quality than Co-doped BaFe2As2 coated conductors, in-field Jc of NdFeAs(O,F) was lower than that of Co-doped BaFe2As2. These results suggest that grain boundaries in oxypnictides reduce Jc significantly compared to that in Co-doped BaFe2As2 and, hence biaxial texture is necessary for high Jc.

  7. Micrometer-Scale Ordering of Silicon-Containing Block Copolymer Thin Films via High-Temperature Thermal Treatments.

    PubMed

    Giammaria, Tommaso Jacopo; Ferrarese Lupi, Federico; Seguini, Gabriele; Perego, Michele; Vita, Francesco; Francescangeli, Oriano; Wenning, Brandon; Ober, Christopher K; Sparnacci, Katia; Antonioli, Diego; Gianotti, Valentina; Laus, Michele

    2016-04-20

    Block copolymer (BCP) self-assembly is expected to complement conventional optical lithography for the fabrication of next-generation microelectronic devices. In this regard, silicon-containing BCPs with a high Flory-Huggins interaction parameter (χ) are extremely appealing because they form high-resolution nanostructures with characteristic dimensions below 10 nm. However, due to their slow self-assembly kinetics and low thermal stability, these silicon-containing high-χ BCPs are usually processed by solvent vapor annealing or in solvent-rich ambient at a low annealing temperature, significantly increasing the complexity of the facilities and of the procedures. In this work, the self-assembly of cylinder-forming polystyrene-block-poly(dimethylsiloxane-random-vinylmethylsiloxane) (PS-b-P(DMS-r-VMS)) BCP on flat substrates is promoted by means of a simple thermal treatment at high temperatures. Homogeneous PS-b-P(DMS-r-VMS) thin films covering the entire sample surface are obtained without any evidence of dewetting phenomena. The BCP arranges in a single layer of cylindrical P(DMS-r-VMS) nanostructures parallel-oriented with respect to the substrate. By properly adjusting the surface functionalization, the heating rate, the annealing temperature, and the processing time, one can obtain correlation length values larger than 1 μm in a time scale fully compatible with the stringent requirements of the microelectronic industry. PMID:27020526

  8. Superconducting Thin Films for SRF Cavity Applications: A Route to Higher Field Gradient Linacs

    NASA Astrophysics Data System (ADS)

    Roach, Wiliam Michael

    Many linear accelerator (linac) applications rely on the use of superconducting radio frequency (SRF) cavities. In order to overcome the current field gradient limits imposed by the use of bulk niobium, a model involving the deposition of alternating superconducting-insulating-superconducting (SIS) thin films onto the interior surface of SRF cavities has been proposed. Since SRF performance is a surface phenomenon, the critical surface of these cavities is less than 1 micron thick, thus enabling the use of thin films. Before such approach can successfully be implemented fundamental studies correlating the microstructure and superconducting properties of thin films are needed. To this end the effect of grain boundary density and interfacial strain in thin films has been explored. Thin films with a smaller grain boundary density were found to have better superconducting properties than films with a larger grain boundary density. Interfacial strain due to a lattice mismatch between the film and substrate lead to two regions in films, one strained region near the interface and one relaxed region away from the interface. The presence of two regions in the film resulted in two types of superconducting behavior. Niobium films were deposited onto copper surfaces to help understand why previous attempts of implementing niobium coated copper cavities in order to exploit the better thermal properties of copper had varying degrees of success. It was found that an increased growth temperature produced niobium films with larger grains and correspondingly better superconducting properties. Proof of principle multilayer samples were prepared to test the SIS model. For the first time, multilayers were produced that were capable of shielding an underlying niobium film from vortex penetration beyond the lower critical field of bulk niobium. This result provides evidence supporting the feasibility of the SIS model.

  9. Method of forming superconducting Tl-Ba-Ca-Cu-O films

    DOEpatents

    Wessels, Bruce W.; Marks, Tobin J.; Richeson, Darrin S.; Tonge, Lauren M.; Zhang, Jiming

    1993-01-01

    A method of forming a superconducting Tl-Ba-Ca-Cu-O film is disclosed, which comprises depositing a Ba-Ca-Cu-O film on a substrate by MOCVD, annealing the deposited film and heat-treating the annealed film in a closed circular vessel with TlBa.sub.2 Ca.sub.2 Cu.sub.3 O.sub.x and cooling to form said superconducting film of TlO.sub.m Ba.sub.2 Ca.sub.n-1 Cu.sub.n O.sub.2n+2, wherein m=1,2 and n=1,2,3.

  10. Formation of the 110-K superconducting phase in Pb-doped Bi-Sr-Ca-Cu-O thin films

    SciTech Connect

    Kula, W.; Sobolewski, R.; Gorecka, J.; Lewandowski, S.J. )

    1991-09-15

    Investigation of the 110-K Bi{sub 2}Sr{sub 2}Ca{sub 2}Cu{sub 3}O{sub {ital x}} phase formation in superconducting thin films of Bi-based cuprates is reported. The films were dc magnetron sputtered from single Bi(Pb)-Sr-Ca-Cu-O targets of various stoichiometries, and subsequently annealed in air at high temperatures. The influence of the initial Pb content, annealing conditions, as well as the substrate material on the growth of the 110-K phase was investigated. We found that the films, fully superconducting above 100 K could be reproducibly fabricated on various dielectric substrates from Pb-rich targets by optimizing annealing conditions for each initial Pb/Bi ratio. Heavy Pb doping considerably accelerated formation of the 110-K phase, reducing the film annealing time to less than 1 h. Films containing, according to the x-ray measurement, more than 90% of the 110-K phase were obtained on MgO substrates, after sputtering from the Bi{sub 2}Pb{sub 2.5}Sr{sub 2}Ca{sub 2.15}Cu{sub 3.3}O{sub {ital x}} target and annealing in air for 1 h at 870 {degree}C. The films were {ital c}-axis oriented, with 4.5-K-wide superconducting transition, and zero resistivity at 106 K. Their critical current density was 2 {times} 10{sup 2} A/cm{sup 2} at 90 K, and above 10{sup 4} A/cm{sup 2} below 60 K. The growth of the 110-K phase on epitaxial substrates, such as CaNdAlO{sub 4} and SrTiO{sub 3}, was considerably deteriorated, and the presence of the 80- and 10-K phases was detected. Nevertheless, the best films deposited on these substrates were fully superconducting at 104 K and exhibited critical current densities above 2 {times} 10{sup 5} A/cm{sup 2} below 60 K{minus}one order of magnitude greater than the films deposited on MgO.

  11. Strong vortex matching effects in YBCO films with periodic modulations of the superconducting order parameter fabricated by masked ion irradiation

    NASA Astrophysics Data System (ADS)

    Haag, L. T.; Zechner, G.; Lang, W.; Dosmailov, M.; Bodea, M. A.; Pedarnig, J. D.

    2014-08-01

    We report on measurements of the magnetoresistance and of the critical current in thin films of the high-temperature superconductor YBa2Cu3O7-δ (YBCO). A square array of regions with suppressed superconducting order parameter has been created in these films by introducing point defects via irradiation with He+ ions through a silicon stencil mask. In such a structure distinct peaks of the critical current can be observed at commensurate arrangements of magnetic flux quanta with the artificial defect lattice. Concurrently, the magnetoresistance shows pronounced minima. Both observations demonstrate that the strong intrinsic pinning in YBCO can be overcome by a periodic array of ion-damage columns with 300 nm spacing.

  12. Studies of the Superconducting Transition in the Mo/Au-Bilayer Thin Films

    NASA Technical Reports Server (NTRS)

    Sadleir, John; Smith, Stephen; Iyomoto, naoko; Bandler, Simon; Chervenak, Jay; Brown, Ari; Brekowsky, Regis; Kilbourne, Caroline; Robinson, Ian

    2007-01-01

    At NASA Goddard, microcalorimeter arrays using superconducting transition edge sensor thermometers (TESs) are under development for high energy resolution X-ray astrophysics applications. We report on our studies of the superconducting transition in our Mo/Au-bilayer TES films including: low current measurements of the superconducting bilayer's resistance transition versus temperature on pixels with different normal metal absorber attachment designs and measured temperature scaling of the critical current and critical magnetic field.

  13. Isotope analysis of diamond-surface passivation effect of high-temperature H2O-grown atomic layer deposition-Al2O3 films

    NASA Astrophysics Data System (ADS)

    Hiraiwa, Atsushi; Saito, Tatsuya; Matsumura, Daisuke; Kawarada, Hiroshi

    2015-06-01

    The Al2O3 film formed using an atomic layer deposition (ALD) method with trimethylaluminum as Al precursor and H2O as oxidant at a high temperature (450 °C) effectively passivates the p-type surface conduction (SC) layer specific to a hydrogen-terminated diamond surface, leading to a successful operation of diamond SC field-effect transistors at 400 °C. In order to investigate this excellent passivation effect, we carried out an isotope analysis using D2O instead of H2O in the ALD and found that the Al2O3 film formed at a conventional temperature (100 °C) incorporates 50 times more CH3 groups than the high-temperature film. This CH3 is supposed to dissociate from the film when heated afterwards at a higher temperature (550 °C) and causes peeling patterns on the H-terminated surface. The high-temperature film is free from this problem and has the largest mass density and dielectric constant among those investigated in this study. The isotope analysis also unveiled a relatively active H-exchange reaction between the diamond H-termination and H2O oxidant during the high-temperature ALD, the SC still being kept intact. This dynamic and yet steady H termination is realized by the suppressed oxidation due to the endothermic reaction with H2O. Additionally, we not only observed the kinetic isotope effect in the form of reduced growth rate of D2O-oxidant ALD but found that the mass density and dielectric constant of D2O-grown Al2O3 films are smaller than those of H2O-grown films. This is a new type of isotope effect, which is not caused by the presence of isotopes in the films unlike the traditional isotope effects that originate from the presence of isotopes itself. Hence, the high-temperature ALD is very effective in forming Al2O3 films as a passivation and/or gate-insulation layer of high-temperature-operation diamond SC devices, and the knowledge of the aforementioned new isotope effect will be a basis for further enhancing ALD technologies in general.

  14. Superconducting thin films of (100) and (111) oriented indium doped topological crystalline insulator SnTe

    SciTech Connect

    Si, W.; Zhang, C.; Wu, L.; Ozaki, T.; Gu, G.; Li, Q.

    2015-09-01

    Recent discovery of the topological crystalline insulator SnTe has triggered a search for topological superconductors, which have potential application to topological quantum computing. The present work reports on the superconducting properties of indium doped SnTe thin films. The (100) and (111) oriented thin films were epitaxially grown by pulsed-laser deposition on (100) and (111) BaF2 crystalline substrates respectively. The onset superconducting transition temperatures are about 3.8 K for (100) and 3.6 K for (111) orientations, slightly lower than that of the bulk. Magneto-resistive measurements indicate that these thin films may have upper critical fields higher than that of the bulk. With large surface-to-bulk ratio, superconducting indium doped SnTe thin films provide a rich platform for the study of topological superconductivity and potential device applications based on topological superconductors.

  15. Superconducting thin films of (100) and (111) oriented indium doped topological crystalline insulator SnTe

    DOE PAGES

    Si, W.; Zhang, C.; Wu, L.; Ozaki, T.; Gu, G.; Li, Q.

    2015-09-01

    Recent discovery of the topological crystalline insulator SnTe has triggered a search for topological superconductors, which have potential application to topological quantum computing. The present work reports on the superconducting properties of indium doped SnTe thin films. The (100) and (111) oriented thin films were epitaxially grown by pulsed-laser deposition on (100) and (111) BaF2 crystalline substrates respectively. The onset superconducting transition temperatures are about 3.8 K for (100) and 3.6 K for (111) orientations, slightly lower than that of the bulk. Magneto-resistive measurements indicate that these thin films may have upper critical fields higher than that of the bulk.more » With large surface-to-bulk ratio, superconducting indium doped SnTe thin films provide a rich platform for the study of topological superconductivity and potential device applications based on topological superconductors.« less

  16. Superconducting thin films of (100) and (111) oriented indium doped topological crystalline insulator SnTe

    SciTech Connect

    Si, Weidong E-mail: qiangli@bnl.gov; Zhang, Cheng; Wu, Lijun; Ozaki, Toshinori; Gu, Genda; Li, Qiang E-mail: qiangli@bnl.gov

    2015-08-31

    Recent discovery of the topological crystalline insulator SnTe has triggered a search for topological superconductors, which have potential application to topological quantum computing. The present work reports on the superconducting properties of indium doped SnTe thin films. The (100) and (111) oriented thin films were epitaxially grown by pulsed-laser deposition on (100) and (111) BaF{sub 2} crystalline substrates, respectively. The onset superconducting transition temperatures are about 3.8 K for (100) and 3.6 K for (111) orientations, slightly lower than that of the bulk. Magneto-resistive measurements indicate that these thin films may have upper critical fields higher than that of the bulk. With large surface-to-bulk ratio, superconducting indium doped SnTe thin films provide a rich platform for the study of topological superconductivity and potential device applications based on topological superconductors.

  17. Enhancement of high-TC superconducting thin film devices by nanoscale polishing

    NASA Astrophysics Data System (ADS)

    Michalowski, P.; Shapoval, T.; Meier, D.; Katzer, C.; Schmidl, F.; Schultz, L.; Seidel, P.

    2012-11-01

    The effects of mechanical nanoscale polishing on the superconducting parameters of YBa2Cu3O7-δ (YBCO) thin films and bi-crystal grain boundary Josephson junctions have been investigated. We prepared samples with additional gold nanocrystallites in the YBCO film. As they are distributed throughout the whole YBCO film, they provide a low-resistance ohmic contact even if parts of the film are removed. Polishing was performed either before or after the patterning and did not change the properties of the grain boundary. However, nanopolishing reduces the film roughness in a significant way, which makes it an indispensable tool for the preparation of integrated superconducting circuits. We also succeeded in tuning the IC and RN of the Josephson junctions of direct current superconducting quantum interference devices (dc-SQUIDs) by systematically reducing the film thickness, which opens up new possibilities in the application of magnetic field sensors.

  18. High-[Tc] superconducting magnets based on thick film arrangements

    SciTech Connect

    Kirschner, I.; Zsolt, G.; Karman, T.; Porjesz, T. . Dept. for Low Temperature Physics); Leppaevuori, S.; Uusimaeki, A. . Microelectronics Lab.); Lukacs, P. )

    1993-11-01

    On the basis of the authors' earlier idea on magnetic feeding, high-[Tc] superconducting magnets can be built consisting of Y-Ba-Cu-O or Bi(Pb)-Sr-Ca-Cu-O thick films. Critical current densities of the samples prepared by an oxalate route are between 7,000 and 23,000 A/cm[sup 2] at helium temperatures depending on the details of the preparation. The self-magnetic field of the individual layer rings are 0.5--1.7 mT which can produce field strength of the magnets of 55 178 mT, corresponding to the experimental critical currents. If the specimens of oxide-nitrate reactions can provide critical current densities of 5,000--15,000 A/cm[sup 2] at nitrogen temperatures they lead to the number of ampere-turns of 550--22,500 A/cm and magnetic field intensity of 69 mT--2.82 T. Since the applicable techniques of the film preparation are very flexible concerning the shape and size of the products, magnetic field profiles of different character can be obtained for various purposes.

  19. Theory of dirty Rashba superconductivity in ultrathin Pb films

    NASA Astrophysics Data System (ADS)

    Chen, Hua; Nam, Hyoungdo; Shih, Chih-Kang; MacDonald, Allan

    Pb is a typical s-wave superconductor and also has strong atomic spin-orbit coupling. In Pb thin films inversion symmetry breaking combined with the large atomic spin-orbit coupling will split the otherwise spin-degenerate bands of Pb, an effect which can be roughly accounted for by Rashba spin-orbit coupling. Motivated by a recent experiment, we used a 2D model involving Rashba spin-orbit coupling and s-wave pairing to study the influence of the former on the superfluid density, parallel critical field, and the resistive transition to the superconducting phase. We found that in both the clean and the dirty limits, Rashba spin-orbit coupling has little influence on the superfluid density and the Kosterlitz-Thouless transition temperature. However, in the dirty limit the Rashba spin-orbit coupling can significantly enhance the parallel critical field, making the Clogston-Chandrasekhar limit inapplicable. The strong suppression of the spin pair-breaking effect of a parallel magnetic field by the Rashba spin-orbit coupling and impurity scattering can make the orbital pair-breaking effect dominant again even in ultrathin films. Finally, we propose and examine a number of mechanisms that can lead to a smeared resistive transition under parallel magnetic fields. Supported by ONR-N00014-14-1-0330.

  20. The influence of internal oxidation during decarburization of a grain oriented silicon steel on the morphology of the glass film formed at high temperature annealing

    NASA Astrophysics Data System (ADS)

    Silveira, Carolina Cesconetto; da Cunha, Marco Antônio; Buono, Vicente Tadeu Lopes

    2014-05-01

    Fourier transform infrared spectroscopy (FTIR) was applied to evaluate the amount of fayalite formed during decarburization of a grain-oriented silicon steel, in order to assess its influence on the morphology of the glass film developed at the final high temperature annealing. The decarburization conditions varied within the temperature range of 740-950 °C and pH2O/pH2 from 0.28 to 0.58. The decarburized specimens were then coated with magnesia slurry and submitted to the high temperature annealing at 1200 °C for 15 h. Characterization of the oxide layer and glass film samples was performed by scanning and transmission electron microscopy. The FTIR analysis showed that the amount of fayalite increased as the temperature and the dew point increased during decarburization. The morphology of the glass film obtained after high temperature annealing was related to the amount of fayalite and silica previously formed. A higher amount of subsurface particles in the glass film, which can deteriorate magnetic properties by restraining domain wall movements, was obtained from oxide layers rich in fayalite and thus with a low amount of silica.

  1. Charge storage phenomenon derived from composition redistribution for single Hf0.8Si0.2Ox film after high-temperature treatment

    NASA Astrophysics Data System (ADS)

    Tang, Zhenjie; Li, Rong; Zhang, Xiwei; Hu, Dan

    2016-05-01

    Simple metal-Hf0.8Si0.2Ox-silicon capacitors have been fabricated. It is observed that the capacitor after high-temperature rapid thermal annealing treatment exhibits a significant charge storage phenomenon, with large hysteresis windows of 3.93 V in a ±8 V gate sweeping voltage range, faster operating speed and good data retention characteristics. The occurrence of charge memory should be attributed to the high-temperature treatment, which gives rise to the HfO2 crystallization and elemental composition redistribution in the Hf0.8Si0.2Ox film, forming a typical metal-oxide-high-κ-oxide-silicon memory structure. Therefore, the high-temperature treatment that induced the internal structure transformation is an appealing approach, and provides a guide for future charge-trap memory design.

  2. Two-Dimensional Superconductivity in the Cuprates Revealed by Atomic-Layer-by- Layer Molecular Beam Epitaxy

    DOE PAGES

    A. T. Bollinger; Bozovic, I.

    2016-08-12

    Various electronic phases displayed by cuprates that exhibit high temperature superconductivity continue to attract much interest. We provide a short review of several experiments that we have performed aimed at investigating the superconducting state in these compounds. Measurements on single-phase films, bilayers, and superlattices all point to the conclusion that the high-temperature superconductivity in these materials is an essentially quasi-two dimensional phenomenon. With proper control over the film growth, high-temperature superconductivity can exist in a single copper oxide plane with the critical temperatures as high as that achieved in the bulk samples.

  3. Highly textured oxypnictide superconducting thin films on metal substrates

    SciTech Connect

    Iida, Kazumasa Kurth, Fritz; Grinenko, Vadim; Hänisch, Jens; Chihara, Masashi; Sumiya, Naoki; Hatano, Takafumi; Ikuta, Hiroshi; Ichinose, Ataru; Tsukada, Ichiro; Matias, Vladimir; Holzapfel, Bernhard

    2014-10-27

    Highly textured NdFeAs(O,F) thin films have been grown on ion beam assisted deposition-MgO/Y{sub 2}O{sub 3}/Hastelloy substrates by molecular beam epitaxy. The oxypnictide coated conductors showed a superconducting transition temperature (T{sub c}) of 43 K with a self-field critical current density (J{sub c}) of 7.0×10{sup 4} A/cm{sup 2} at 5 K, more than 20 times higher than powder-in-tube processed SmFeAs(O,F) wires. Albeit higher T{sub c} as well as better crystalline quality than Co-doped BaFe{sub 2}As{sub 2} coated conductors, in-field J{sub c} of NdFeAs(O,F) was lower than that of Co-doped BaFe{sub 2}As{sub 2}. These results suggest that grain boundaries in oxypnictides reduce J{sub c} significantly compared to that in Co-doped BaFe{sub 2}As{sub 2} and, hence biaxial texture is necessary for high J{sub c.}.

  4. The Thermomagnetic Instability in Superconducting Films with Adjacent Metal Layer

    NASA Astrophysics Data System (ADS)

    Vestgården, J. I.; Galperin, Y. M.; Johansen, T. H.

    2013-12-01

    Dendritic flux avalanches is a frequently encountered consequence of the thermomagnetic instability in type-II superconducting films. The avalanches, which are potentially harmful for superconductor-based devices, can be suppressed by an adjacent normal metal layer, even when the two layers are not in thermal contact. The suppression of the avalanches in this case is due to so-called magnetic braking, caused by eddy currents generated in the metal layer by propagating magnetic flux. We develop a theory of magnetic braking by analyzing coupled electrodynamics and heat flow in a superconductor-normal metal bilayer. The equations are solved by linearization and by numerical simulation of the avalanche dynamics. We find that in an uncoated superconductor, even a uniform thermomagnetic instability can develop into a dendritic flux avalanche. The mechanism is that a small non-uniformity caused by the electromagnetic non-locality induces a flux-flow hot spot at a random position. The hot spot quickly develops into a finger, which at high speeds penetrates into the superconductor, forming a branching structure. Magnetic braking slows the avalanches, and if the normal metal conductivity is sufficiently high, it can suppress the formation of the dendritic structure. During avalanches, the braking by the normal metal layer prevents the temperature from exceeding the transition temperature of the superconductor. Analytical criteria for the instability threshold are developed using the linear stability analysis. The criteria are found to match quantitatively the instability onsets obtained in simulations.

  5. High temperature superconductor materials and applications

    NASA Technical Reports Server (NTRS)

    Doane, George B., III. (Editor); Banks, Curtis; Golben, John

    1991-01-01

    One of the areas concerned itself with the investigation of the phenomena involved in formulating and making in the laboratory new and better superconductor material with enhanced values of critical current and temperature. Of special interest were the chemistry, physical processes, and environment required to attain these enhanced desirable characteristics. The other area concerned itself with producing high temperature superconducting thin films by pulsed laser deposition techniques. Such films are potentially very useful in the detection of very low power signals. To perform this research high vacuum is required. In the course of this effort, older vacuum chambers were maintained and used. In addition, a new facility is being brought on line. This latter activity has been replete with the usual problems of bringing a new facility into service. Some of the problems are covered in the main body of this report.

  6. A Model Approach to Flux-Pinning Properties of YBa2Cu 3O7-delta Thin Film Vortex States via Non-Superconducting Impurities

    NASA Astrophysics Data System (ADS)

    Gamble, Ronald S., Jr.

    Thin film YBa2Cu3O7--delta (YBCO) samples with added non-superconducting nanodot defects of CeO 2 and BaSnO2 are the focus of recent high-temperature superconductor studies. These nanodots allow magnetic flux to penetrate at these sites of the superconducting lattice thus creating a magnetic flux vortex state. Examining the structure shows that these quantized magnetic flux vortices arrange themselves in a self-assembled lattice. The nanodots, with non-superconducting properties, serve to present structural properties to restrict motion of these vorticies under a pinning-force and to enhance the critical current density. A formulation of a new model for the system by a variation in the electron pair velocity via the virtual work from the nanodot defects in accordance to the well-known Superconductivity theories is tested. A solution to the expression for the magnetic flux, zero net force and pair velocity will generate a setting for the optimal deposition parameters of number density, growth geometry and mass density of these nanodot structures. With a calculation of pair velocities from a similar work, a comparison is made between experimental and theoretical velocity calculations using growth geometry and chemical potential. This will yield insight into how the current density for a doped high-temperature superconductor will be modified and tuned based on the dynamics and density of the nanodots themselves.

  7. Robustness of s-wave pairing symmetry in iron-based superconductors and its implications for fundamentals of magnetically driven high-temperature superconductivity

    NASA Astrophysics Data System (ADS)

    Hu, Jiangping; Yuan, Jing

    2016-10-01

    Based on the assumption that the superconducting state belongs to a single irreducible representation of lattice symmetry, we propose that the pairing symmetry in all measured iron-based superconductors is generally consistent with the A 1 g s-wave. Robust s-wave pairing throughout the different families of iron-based superconductors at different doping regions signals two fundamental principles behind high- T c superconducting mechanisms: (i) the correspondence principle: the short-range magnetic-exchange interactions and the Fermi surfaces act collaboratively to achieve high- T c superconductivity and determine pairing symmetries; (ii) the magnetic-selection pairing rule: superconductivity is only induced by the magnetic-exchange couplings from the super-exchange mechanism through cation-anion-cation chemical bonding. These principles explain why unconventional high- T c superconductivity appears to be such a rare but robust phenomena, with its strict requirements regarding the electronic environment. The results will help us to identify new electronic structures that can support high- T c superconductivity.

  8. Topological edge states in a high-temperature superconductor FeSe/SrTiO3(001) film.

    PubMed

    Wang, Z F; Zhang, Huimin; Liu, Defa; Liu, Chong; Tang, Chenjia; Song, Canli; Zhong, Yong; Peng, Junping; Li, Fangsen; Nie, Caina; Wang, Lili; Zhou, X J; Ma, Xucun; Xue, Q K; Liu, Feng

    2016-09-01

    Superconducting and topological states are two most intriguing quantum phenomena in solid materials. The entanglement of these two states, the topological superconducting state, will give rise to even more exotic quantum phenomena. While many materials are found to be either a superconductor or a topological insulator, it is very rare that both states exist in one material. Here, we demonstrate by first-principles theory as well as scanning tunnelling spectroscopy and angle-resolved photoemission spectroscopy experiments that the recently discovered 'two-dimensional (2D) superconductor' of single-layer FeSe also exhibits 1D topological edge states within an energy gap of ∼40 meV at the M point below the Fermi level. It is the first 2D material that supports both superconducting and topological states, offering an exciting opportunity to study 2D topological superconductors through the proximity effect. PMID:27376684

  9. Topological edge states in a high-temperature superconductor FeSe/SrTiO3(001) film.

    PubMed

    Wang, Z F; Zhang, Huimin; Liu, Defa; Liu, Chong; Tang, Chenjia; Song, Canli; Zhong, Yong; Peng, Junping; Li, Fangsen; Nie, Caina; Wang, Lili; Zhou, X J; Ma, Xucun; Xue, Q K; Liu, Feng

    2016-09-01

    Superconducting and topological states are two most intriguing quantum phenomena in solid materials. The entanglement of these two states, the topological superconducting state, will give rise to even more exotic quantum phenomena. While many materials are found to be either a superconductor or a topological insulator, it is very rare that both states exist in one material. Here, we demonstrate by first-principles theory as well as scanning tunnelling spectroscopy and angle-resolved photoemission spectroscopy experiments that the recently discovered 'two-dimensional (2D) superconductor' of single-layer FeSe also exhibits 1D topological edge states within an energy gap of ∼40 meV at the M point below the Fermi level. It is the first 2D material that supports both superconducting and topological states, offering an exciting opportunity to study 2D topological superconductors through the proximity effect.

  10. Topological edge states in a high-temperature superconductor FeSe/SrTiO3(001) film

    NASA Astrophysics Data System (ADS)

    Wang, Z. F.; Zhang, Huimin; Liu, Defa; Liu, Chong; Tang, Chenjia; Song, Canli; Zhong, Yong; Peng, Junping; Li, Fangsen; Nie, Caina; Wang, Lili; Zhou, X. J.; Ma, Xucun; Xue, Q. K.; Liu, Feng

    2016-09-01

    Superconducting and topological states are two most intriguing quantum phenomena in solid materials. The entanglement of these two states, the topological superconducting state, will give rise to even more exotic quantum phenomena. While many materials are found to be either a superconductor or a topological insulator, it is very rare that both states exist in one material. Here, we demonstrate by first-principles theory as well as scanning tunnelling spectroscopy and angle-resolved photoemission spectroscopy experiments that the recently discovered `two-dimensional (2D) superconductor' of single-layer FeSe also exhibits 1D topological edge states within an energy gap of ~40 meV at the M point below the Fermi level. It is the first 2D material that supports both superconducting and topological states, offering an exciting opportunity to study 2D topological superconductors through the proximity effect.

  11. Superconducting Yttrium Barium Copper Oxide Thin Films and Thin Film Devices

    NASA Astrophysics Data System (ADS)

    Stamper, Anthony Kendall

    Superconducting thin films of YBa_2 Cu_3O_{7 -delta} (YBCO) have been deposited using rf diode sputtering from a single composite target. These films were deposited on silicon substrates at substrate temperatures up to 600^circC using either 100% argon or a 90% argon and 10% oxygen sputtering gas mixture. Yttria-stabilized ZrO_2 (YSZ) buffer layers were employed both for electrical isolation and to minimize the reaction between the silicon and the superconductor. The YSZ crystal structure was highly dependent on the deposition parameters and films with (111) and (100) cubic texturing were grown on oxidized silicon substrates. The composition and electrical properties of the YBCO films, which were deposited on-axis from 5 cm targets, were approximately constant over most of the 5 cm substrates when oxygen was in the sputtering gas and were reproducible. The effect of the sputtering gas pressure, the presence of 10% oxygen in the sputtering gas, the target composition, and the substrate temperature on the film composition have been studied. We demonstrated that neutral oxygen bombardment was responsible for composition differences between the target and the thin film. YBCO films deposited on in-situ heated substrates had zero-transition temperatures up to 87K with 10% to 90% transition widths of less than 5K and were c-axis oriented. Films deposited on unheated substrates required processing at higher temperatures, had zero-transition temperatures up to 85K, and were randomly oriented. Lithographic processes and contact technologies were developed for device fabrication. Using these processes, we fabricated simple YBCO microstrip structures, YBCO/Au/n-Si Schottky diodes, Pb/Ag/YBCO Josephson junctions, and Au/YSZ/YBCO multi-layer structures. After optimization of the process, we were able to fabricate high quality diodes and ohmic contacts without degrading the electrical properties of the YBCO. Finally, we fabricated flux transformer structures, with winding widths

  12. Effect of Corrosion Film Composition and Structure on the Corrosion Kinetics of Ni-Cr-Fe Alloys in High Temperature Water

    SciTech Connect

    P.M. Rosecrans; N. Lewis; D.J. Duquette

    2002-02-27

    Nickel alloys such as Alloy 600 undergo Stress Corrosion Cracking (SCC) in pure water at temperatures between about 260 C and the critical point. Increasing the level of Cr in Ni-Fe-Cr alloys increases SCC resistance in aerated and deaerated water. The mechanism is not understood. The effect of Cr composition on oxide microstructure and corrosion kinetics of Ni-Fe-Cr alloys was determined experimentally, to evaluate whether the anodic dissolution model for SCC can account for the effect of Cr on SCC. The alloy corrosion rate and corrosion product oxide microstructure is strongly influenced by the Cr composition. Corrosion kinetics are parabolic and influenced by chromium concentration, with the parabolic constant first increasing then decreasing as Cr increases from 5 to 39%. Surface analyses using Analytical Electron microscopy (AEM) and Auger Electron Spectroscopy (AES) show that the corrosion product film that forms initially on all alloys exposed to high purity high temperature water is a nickel rich oxide. With time, the amount of chromium in the oxide film increases and corrosion proceeds toward the formation of the more thermodynamically stable spinel or hexagonal Cr-rich oxides, similar to high temperature gaseous oxidation. Due to the slower diffusion kinetics at the temperatures of water corrosion compared to those in high temperature gaseous oxidation, however, the films remain as a mixture of NiO, mixed Ni, Fe and Cr spinels, NiCrO{sub 3} and FeCrO{sub 3}. As the amount of Cr in the film increases and the nature of the film changes from NiO to spinel or hexagonal oxides, cation diffusion through the films slows, slowing the corrosion rate. These observations are qualitatively consistent with an anodic dissolution SCC mechanism. However, parametric modeling of the SCC growth process, applying available creep, oxide rupture strain and corrosion kinetics data, indicates that the anodic dissolution mechanism accounts for only a fraction of the effect of Cr

  13. Superconductivity in textured Bi clusters/Bi{sub 2}Te{sub 3} films

    SciTech Connect

    Le, Phuoc Huu; Tzeng, Wen-Yen; Chen, Hsueh-Ju; Luo, Chih Wei; Lin, Jiunn-Yuan; Leu, Jihperng

    2014-09-01

    We report superconductivity at an onset critical temperature below 3.1 K in topological insulator ∼200-nm-thick Bi{sub 2}Te{sub 3} thin films grown by pulsed laser deposition. Using energy-dispersive X-ray spectroscopy elemental mapping and Auger electron spectroscopy elemental depth profiling, we clearly identified bismuth (Bi) precipitation and Bi cluster signatures. Superconductivity in the Bi{sub 2}Te{sub 3} films was attributed to the proximity effect of Bi clusters precipitated on the surface of the Bi{sub 2}Te{sub 3} films.

  14. Laser Plasma Vapour Deposition Of Photoconducting And High Tc Superconducting Films

    NASA Astrophysics Data System (ADS)

    Popescu, Mihai A.; Apostol, Ileana; Mihailescu, Ion N.; Botila, T.; Pentia, E.; Ciurea, M. L.; Dinescu, M.; Jaklovsky, J.; Aldica, Gheorghe V.; Miu, L.; Rusu, C.; Hening, Al. A.; Mihai, S.; Constantin, C.; Stoica, Mihaela; Pausescu, P.; Cruceanu, Eugen; Pompe, Wolfgang; Wuensch, R.; Richter, Asta; Scheibe, H. J.

    1989-05-01

    Device quality PbS photoconducting films were obtained by laser plasma vapour deposition on special glass substrates at room temperature and their structure was investigated by X-ray diffraction. High Tc superconducting films of composition Dy0.2Y0.8Ba2Cu3O~7 and YBa2Cu3O~7 were deposited on sapphire substrate. It was shown for laser deposited YBa2Cu3O~7 that a buffer layer of the same composition predeposited by rf sputtering allows for getting high quality superconducting films.

  15. Contribution of heat transfer to turbine blades and vanes for high temperature industrial gas turbines. Part 1: Film cooling.

    PubMed

    Takeishi, K; Aoki, S

    2001-05-01

    This paper deals with the contribution of heat transfer to increase the turbine inlet temperature of industrial gas turbines in order to attain efficient and environmentally benign engines. High efficiency film cooling, in the form of shaped film cooling and full coverage film cooling, is one of the most important cooling technologies. Corresponding heat transfer tests to optimize the film cooling effectiveness are shown and discussed in this first part of the contribution.

  16. Contribution of heat transfer to turbine blades and vanes for high temperature industrial gas turbines. Part 1: Film cooling.

    PubMed

    Takeishi, K; Aoki, S

    2001-05-01

    This paper deals with the contribution of heat transfer to increase the turbine inlet temperature of industrial gas turbines in order to attain efficient and environmentally benign engines. High efficiency film cooling, in the form of shaped film cooling and full coverage film cooling, is one of the most important cooling technologies. Corresponding heat transfer tests to optimize the film cooling effectiveness are shown and discussed in this first part of the contribution. PMID:11460641

  17. Thick REBaCuO superconducting films through single-coating of low-fluorine metallorganic solution

    NASA Astrophysics Data System (ADS)

    Boubeche, M.; Cai, C. B.; Jian, H. B.; Li, M. J.; Yang, W. T.; Liu, Z. Y.; Bai, C. Y.

    2016-10-01

    A high critical current Ic is crucial for the application of high temperature superconductors YBa2Cu3O7-δ in energy efficient power devices and wires. In this paper we report the fabrication of thick (YGd)1.3Ba2Cu3O7-x films on a metal substrate using low-fluorine metal organic deposition method. The effects of the film thickness on the microstructure, texture and superconductivity properties of the films were evaluated. In order to increase the film thicknesses by single coating, the influence of withdrawal speed during the dip coating on resulting thickness are investigated with the other processing parameters fixed. It is revealed that there is a maximum thickness for a certain starting solution. Here we used 3 different solutions, Conventional Low Fluorine solutions with 2 M and 2.5 M, and super low-fluorine solution with 2.5 M. The maximum thicknesses of about 710 nm, 1280 nm and 1460 nm were obtained, respectively.

  18. Effects of Surface Electron Doping and Substrate on the Superconductivity of Epitaxial FeSe Films.

    PubMed

    Zhang, W H; Liu, X; Wen, C H P; Peng, R; Tan, S Y; Xie, B P; Zhang, T; Feng, D L

    2016-03-01

    Superconductivity in FeSe is greatly enhanced in films grown on SrTiO3 substrates, although the mechanism behind remains unclear. Recently, surface potassium (K) doping has also proven able to enhance the superconductivity of FeSe. Here, by using scanning tunneling microscopy, we compare the K doping dependence of the superconductivity in FeSe films grown on two substrates: SrTiO3 (001) and graphitized SiC (0001). For thick films (20 unit cells (UC)), the optimized superconducting (SC) gaps are of similar size (∼9 meV) regardless of the substrate. However, when the thickness is reduced to a few UC, the optimized SC gap is increased up to ∼15 meV for films on SrTiO3, whereas it remains unchanged for films on SiC. This clearly indicates that the FeSe/SrTiO3 interface can further enhance the superconductivity, beyond merely doping electrons. Intriguingly, we found that this interface enhancement decays exponentially as the thickness increases, with a decay length of 2.4 UC, which is much shorter than the length scale for relaxation of the lattice strain, pointing to interfacial electron-phonon coupling as the likely origin.

  19. Superconducting niobium thin film slow-wave structures

    NASA Technical Reports Server (NTRS)

    Bautista, J. J.; Petty, S. M.; Allen, L. H.; Beasley, M. R.; Hammond, R. H.

    1983-01-01

    A superconducting comb structure as a slow-wave element in a traveling-wave maser will significantly improve maser noise temperature and gain by reducing the insertion loss. The results of the insertion loss measurements of superconducting niobium slow-wave structures subjected to maser operating conditions at X-Band frequencies are presented.

  20. Quasi-two-dimensional superconductivity in FeSe0.3Te0.7 thin films and electric-field modulation of superconducting transition.

    PubMed

    Lin, Zhu; Mei, Chenguang; Wei, Linlin; Sun, Zhangao; Wu, Shilong; Huang, Haoliang; Zhang, Shu; Liu, Chang; Feng, Yang; Tian, Huanfang; Yang, Huaixin; Li, Jianqi; Wang, Yayu; Zhang, Guangming; Lu, Yalin; Zhao, Yonggang

    2015-09-18

    We report the structural and superconducting properties of FeSe0.3Te0.7 (FST) thin films with different thicknesses grown on ferroelectric Pb(Mg1/3Nb2/3)0.7Ti0.3O3 substrates. It was shown that the FST films undergo biaxial tensile strains which are fully relaxed for films with thicknesses above 200 nm. Electrical transport measurements reveal that the ultrathin films exhibit an insulating behavior and superconductivity appears for thicker films with Tc saturated above 200 nm. The current-voltage curves around the superconducting transition follow the Berezinskii-Kosterlitz-Thouless (BKT) transition behavior and the resistance-temperature curves can be described by the Halperin-Nelson relation, revealing quasi-two-dimensional phase fluctuation in FST thin films. The Ginzburg number decreases with increasing film thickness indicating the decrease of the strength of thermal fluctuations. Upon applying electric field to the heterostructure, Tc of FST thin film increases due to the reduction of the tensile strain in FST. This work sheds light on the superconductivity, strain effect as well as electric-field modulation of superconductivity in FST films.

  1. Quasi-two-dimensional superconductivity in FeSe0.3Te0.7 thin films and electric-field modulation of superconducting transition.

    PubMed

    Lin, Zhu; Mei, Chenguang; Wei, Linlin; Sun, Zhangao; Wu, Shilong; Huang, Haoliang; Zhang, Shu; Liu, Chang; Feng, Yang; Tian, Huanfang; Yang, Huaixin; Li, Jianqi; Wang, Yayu; Zhang, Guangming; Lu, Yalin; Zhao, Yonggang

    2015-01-01

    We report the structural and superconducting properties of FeSe0.3Te0.7 (FST) thin films with different thicknesses grown on ferroelectric Pb(Mg1/3Nb2/3)0.7Ti0.3O3 substrates. It was shown that the FST films undergo biaxial tensile strains which are fully relaxed for films with thicknesses above 200 nm. Electrical transport measurements reveal that the ultrathin films exhibit an insulating behavior and superconductivity appears for thicker films with Tc saturated above 200 nm. The current-voltage curves around the superconducting transition follow the Berezinskii-Kosterlitz-Thouless (BKT) transition behavior and the resistance-temperature curves can be described by the Halperin-Nelson relation, revealing quasi-two-dimensional phase fluctuation in FST thin films. The Ginzburg number decreases with increasing film thickness indicating the decrease of the strength of thermal fluctuations. Upon applying electric field to the heterostructure, Tc of FST thin film increases due to the reduction of the tensile strain in FST. This work sheds light on the superconductivity, strain effect as well as electric-field modulation of superconductivity in FST films. PMID:26382136

  2. Quasi-two-dimensional superconductivity in FeSe0.3Te0.7 thin films and electric-field modulation of superconducting transition

    PubMed Central

    Lin, Zhu; Mei, Chenguang; Wei, Linlin; Sun, Zhangao; Wu, Shilong; Huang, Haoliang; Zhang, Shu; Liu, Chang; Feng, Yang; Tian, Huanfang; Yang, Huaixin; Li, Jianqi; Wang, Yayu; Zhang, Guangming; Lu, Yalin; Zhao, Yonggang

    2015-01-01

    We report the structural and superconducting properties of FeSe0.3Te0.7 (FST) thin films with different thicknesses grown on ferroelectric Pb(Mg1/3Nb2/3)0.7Ti0.3O3 substrates. It was shown that the FST films undergo biaxial tensile strains which are fully relaxed for films with thicknesses above 200 nm. Electrical transport measurements reveal that the ultrathin films exhibit an insulating behavior and superconductivity appears for thicker films with Tc saturated above 200 nm. The current-voltage curves around the superconducting transition follow the Berezinskii-Kosterlitz-Thouless (BKT) transition behavior and the resistance-temperature curves can be described by the Halperin–Nelson relation, revealing quasi-two-dimensional phase fluctuation in FST thin films. The Ginzburg number decreases with increasing film thickness indicating the decrease of the strength of thermal fluctuations. Upon applying electric field to the heterostructure, Tc of FST thin film increases due to the reduction of the tensile strain in FST. This work sheds light on the superconductivity, strain effect as well as electric-field modulation of superconductivity in FST films. PMID:26382136

  3. Electrical modulation of superconducting critical temperature in liquid-gated thin niobium films

    SciTech Connect

    Choi, Jiman; Pradheesh, R.; Chong, Yonuk Chae, Dong-Hun; Kim, Hyungsang; Im, Hyunsik

    2014-07-07

    We demonstrate that the superconducting critical temperature (T{sub c}) of thin niobium films can be electrically modulated in a liquid-gated geometry device. T{sub c} can be suppressed and enhanced by applying positive and negative gate voltage, respectively, in a reversible manner within a range of about 0.1 K. At a fixed temperature below T{sub c}, we observed that the superconducting critical current can be modulated by gate voltage. This result suggests a possibility of an electrically controlled switching device operating at or above liquid helium temperature, where superconductivity can be turned on or off solely by the applied gate voltage.

  4. Superconductivity induced in iron telluride films by low-temperature oxygen incorporation

    NASA Astrophysics Data System (ADS)

    Nie, Y. F.; Telesca, D.; Budnick, J. I.; Sinkovic, B.; Wells, B. O.

    2010-07-01

    We report superconductivity induced in films of the nonsuperconducting, antiferromagnetic parent material FeTe by low-temperature oxygen incorporation in a reversible manner. X-ray absorption shows that oxygen incorporation changes the nominal Fe valence state from 2+ in the nonsuperconducting state to mainly 3+ in the superconducting state. Thus superconductivity in O-doped FeTe occurs in a quite different charge and strain state than the more common FeTe1-xSex . This work also suggests a convenient path for conducting doping experiments in situ with many measurement techniques.

  5. Controlling flux flow dissipation by changing flux pinning in superconducting films

    SciTech Connect

    Grimaldi, G.; Leo, A.; Nigro, A.; Pace, S.; Silhanek, A. V.; Verellen, N.; Moshchalkov, V. V.; Milosevic, M. V.; Casaburi, A.; Cristiano, R.

    2012-05-14

    We study the flux flow state in superconducting materials characterized by rather strong intrinsic pinning, such as Nb, NbN, and nanostructured Al thin films, in which we drag the superconducting dissipative state into the normal state by current biasing. We modify the vortex pinning strength either by ion irradiation, by tuning the measuring temperature or by including artificial pinning centers. We measure critical flux flow voltages for all materials and the same effect is observed: switching to low flux flow dissipations at low fields for an intermediate pinning regime. This mechanism offers a way to additionally promote the stability of the superconducting state.

  6. Structural and magnetic phase diagram of CeFeAsO(1- x)F(x) and its relation to high-temperature superconductivity.

    PubMed

    Zhao, Jun; Huang, Q; de la Cruz, Clarina; Li, Shiliang; Lynn, J W; Chen, Y; Green, M A; Chen, G F; Li, G; Li, Z; Luo, J L; Wang, N L; Dai, Pengcheng

    2008-12-01

    Recently, high-transition-temperature (high-Tc) superconductivity was discovered in the iron pnictide RFeAsO(1-x)F(x) (R, rare-earth metal) family of materials. We use neutron scattering to study the structural and magnetic phase transitions in CeFeAsO(1-x)F(x) as the system is tuned from a semimetal to a high-Tc superconductor through fluorine (F) doping, x. In the undoped state, CeFeAsO develops a structural lattice distortion followed by a collinear antiferromagnetic order with decreasing temperature. With increasing fluorine doping, the structural phase transition decreases gradually and vanishes within the superconductivity dome near x=0.10, whereas the antiferromagnetic order is suppressed before the appearance of superconductivity for x>0.06, resulting in an electronic phase diagram remarkably similar to that of the high-Tc copper oxides. Comparison of the structural evolution of CeFeAsO(1-x)F(x) with other Fe-based superconductors suggests that the structural perfection of the Fe-As tetrahedron is important for the high-Tc superconductivity in these Fe pnictides.

  7. Advances in pulsed-laser-deposited AIN thin films for high-temperature capping, device passivation, and piezoelectric-based RF MEMS/NEMS resonator applications

    NASA Astrophysics Data System (ADS)

    Hullavarad, S. S.; Vispute, R. D.; Nagaraj, B.; Kulkarni, V. N.; Dhar, S.; Venkatesan, T.; Jones, K. A.; Derenge, M.; Zheleva, T.; Ervin, M. H.; Lelis, A.; Scozzie, C. J.; Habersat, D.; Wickenden, A. E.; Currano, L. J.; Dubey, M.

    2006-04-01

    In this paper we report recent advances in pulsed-laser-deposited AIN thin films for high-temperature capping of SiC, passivation of SiC-based devices, and fabrication of a piezoelectric MEMS/NEMS resonator on Pt-metallized SiO2/Si. The AlN films grown using the reactive laser ablation technique were found to be highly stoichiometric, dense with an optical band gap of 6.2 eV, and with a surface smoothness of less than 1 nm. A low-temperature buffer-layer approach was used to reduce the lattice and thermal mismatch strains. The dependence of the quality of AlN thin films and its characteristics as a function of processing parameters are discussed. Due to high crystallinity, near-perfect stoichiometry, and high packing density, pulsed-laser-deposited AlN thin films show a tendency to withstand high temperatures up to 1600°C, and which enables it to be used as an anneal capping layer for SiC wafers for removing ion-implantation damage and dopant activation. The laser-deposited AlN thin films show conformal coverage on SiC-based devices and exhibit an electrical break-down strength of 1.66 MV/cm up to 350°C when used as an insulator in Ni/AlN/SiC metal-insulator-semiconductor (MIS) devices. Pulsed laser deposition (PLD) AlN films grown on Pt/SiO2/Si (100) substrates for radio-frequency microelectrical and mechanical systems and nanoelectrical and mechanical systems (MEMS and NEMS) demonstrated resonators having high Q values ranging from 8,000 to 17,000 in the frequency range of 2.5-0.45 MHz. AlN thin films were characterized by x-ray diffraction, Rutherford backscattering spectrometry (in normal and oxygen resonance mode), atomic force microscopy, ultraviolet (UV)-visible spectroscopy, and scanning electron microscopy. Applications exploiting characteristics of high bandgap, high bond strength, excellent piezoelectric characteristics, extremely high chemical inertness, high electrical resistivity, high breakdown strength, and high thermal stability of the pulsed

  8. Scaling Laws for Thin Films near the Superconducting-to-Insulating Transition

    PubMed Central

    Tao, Yong

    2016-01-01

    We propose a Lagrangian function, which combines Landau-Ginzburg term and Chern-Simons term, for describing the competition between disorder and superconductivity. To describe the normal-to-superconducting transition in the thin superconducting films, we apply Wilson’s renormalization group methods into this Lagrangian function. Finally, we obtain a scaling law between critical temperature (Tc), film thickness (d), sheet resistance of the film at the normal state (Rs), and number density of the electrons at the normal state (N). Such a scaling law is in agreement with recent experimental investigations [Ivry, Y. et al., Physical Review B 90, 214515 (2014)]. Our finding may have potential benefits for improving transition temperature Tc. PMID:27029338

  9. Characterization of NbN films for superconducting nanowire single photon detectors

    SciTech Connect

    Mcdonald, Ross D; Ayala - Valenzuela, Oscar E; Weisse - Bernstein, Nina R; Williamson, Todd L; Hoffbauer, M. A.; Graf, M. J.; Rabin, M. W.

    2011-01-14

    Nanoscopic superconducting meander patterns offer great promise as a new class of cryogenic radiation sensors capable of single photon detection. To realize this potential, control of the superconducting properties on the nanoscale is imperative. To this end, Superconducting Nanowire Single Photon Detectors (SNSPDs) are under development by means Energetic Neutral Atom Beam Lithography and Epitaxy, or ENABLE. ENABLE can growth highly-crystalline, epitaxial thin-film materials, like NbN, at low temperatures; such wide-ranging control of fabrication parameters is enabling the optimization of film properties for single photon detection. T{sub c}, H{sub c2}, {zeta}{sub GL} and J{sub c} of multiple thin films and devices have been studied as a function of growth conditions. The optimization of which has already produced devices with properties rivaling all reports in the existing literature.

  10. Superconducting and Insulating Phases of Disordered FeSe Thin Films in a Magnetic Field

    NASA Astrophysics Data System (ADS)

    Schneider, R.; Zaitsev, A. G.; Fuchs, D.; von Löhneysen, H.

    2015-01-01

    The temperature-dependent electronic transport on the superconducting and insulating sides of the superconductor-insulator transition in disordered quasi-two-dimensional textured FeSe thin films is reported. The transition is driven by a perpendicular magnetic field applied to a film with its thickness close to the critical thickness of the thickness-, i.e., disorder-induced transition. The resistance in the superconducting phase might be dominated by thermally assisted flux flow, and in the phase diagram a metallic phase might intervene between the superconducting and insulating state at very low temperatures. In the insulating phase, weak insulating behavior is observed that can be described by weak localization theory of bosons, thus supporting the bosonic description of the superconductor-insulator transition in FeSe thin films.

  11. High growth rate homoepitaxial diamond film deposition at high temperatures by microwave plasma-assisted chemical vapor deposition

    NASA Technical Reports Server (NTRS)

    Vohra, Yogesh K. (Inventor); McCauley, Thomas S. (Inventor)

    1997-01-01

    The deposition of high quality diamond films at high linear growth rates and substrate temperatures for microwave-plasma chemical vapor deposition is disclosed. The linear growth rate achieved for this process is generally greater than 50 .mu.m/hr for high quality films, as compared to rates of less than 5 .mu.m/hr generally reported for MPCVD processes.

  12. Microstrip ring resonator technique for measuring microwave attenuation in high-Tc superconducting thin films

    NASA Astrophysics Data System (ADS)

    Takemoto, June H.; Oshita, Floyd K.; Fetterman, Harold R.; Kobrin, Paul; Sovero, Emilio

    1989-10-01

    Microwave attenuation of high-Tc superconducting (HTS) films sputtered on MgO and ZrO2 were measured using a microstrip ring resonator circuit. The results for Y-Ba-Cu-O and Bi-Sr-Ca-Cu-O resonators were compared to those for gold-plated resonators of identical design. The losses of superconducting and gold-plated films were determined from unloaded Q-factor measurements. The attenuation of Y-Ba-Cu-O film on an MgO substrate is approximately 31 percent lower than that of gold films at 6.6 GHz and 33 percent lower at 19.2 GHz for temperatures below 50 K. The approach of using microstrips to characterize microwave losses shows the usefulness of HTS films in integrated circuit technology.

  13. Preparation and transport properties of high-Tc superconducting thick films

    NASA Astrophysics Data System (ADS)

    Aponte, J. M.; Octavio, M.

    1989-08-01

    We have prepared thick films of high Tc superconductors on a variety of substrates: SrTiO3, BeO, Zr(Ca)O2, alumina, and sapphire. The powder of the YBa2Cu3O7-δ compound is mixed with an organic solvent and painted on the substrates. The films are then dried and fired. We have studied the effect of the substrate and of the firing temperature on the superconducting properties of the films. We found an optimum firing temperature of 990 °C. The films prepared are superconducting with Tc (R=0) as high as 82 K. We discuss the shape of the resistance-versus-temperature curves as well as the temperature dependence of the critical currents of these films.

  14. Tuning Superconductivity in FeSe Thin Films via Magnesium Doping.

    PubMed

    Qiu, Wenbin; Ma, Zongqing; Liu, Yongchang; Shahriar Al Hossain, Mohammed; Wang, Xiaolin; Cai, Chuanbing; Dou, Shi Xue

    2016-03-01

    In contrast to its bulk crystal, the FeSe thin film or layer exhibits better superconductivity performance, which recently attracted much interest in its fundamental research as well as in potential applications around the world. In the present work, tuning superconductivity in FeSe thin films was achieved by magnesium-doping technique. Tc is significantly enhanced from 10.7 K in pure FeSe films to 13.4 K in optimized Mg-doped ones, which is approximately 1.5 times higher than that of bulk crystals. This is the first time achieving the enhancement of superconducting transition temperature in FeSe thin films with practical thickness (120 nm) via a simple Mg-doping process. Moreover, these Mg-doped FeSe films are quite stable in atmosphere with Hc2 up to 32.7 T and Tc(zero) up to 12 K, respectively, implying their outstanding potential for practical applications in high magnetic fields. It was found that Mg enters the matrix of FeSe lattice, and does not react with FeSe forming any other secondary phase. Actually, Mg first occupies Fe-vacancies, and then substitutes for some Fe in the FeSe crystal lattices when Fe-vacancies are fully filled. Simultaneously, external Mg-doping introduces sufficient electron doping and induces the variation of electron carrier concentration according to Hall coefficient measurements. This is responsible for the evolution of superconducting performance in FeSe thin films. Our results provide a new strategy to improve the superconductivity of 11 type Fe-based superconductors and will help us to understand the intrinsic mechanism of this unconventional superconducting system.

  15. Plasma-Assisted Laser Deposition of High T(c) Oxide Superconducting Thin Films.

    NASA Astrophysics Data System (ADS)

    Witanachchi, Sarath

    1990-01-01

    Since the discovery of the high T_ {rm c} oxide superconductor YBa _2Cu_3O _7 a great deal of attention has been given to the fabrication of superconducting thin films of this material. Thin films of the new superconductor have an immense importance in scientific research, such as microwave, infrared and critical current studies, and also in applications, such as Josephson junction based digital computer circuits, SQUID (Superconducting Quantum Interference Devices), transmission lines, and interconnectors. Integration of these films with semiconductors and multilayer capabilities are important for future practical uses. For most of these applications, a low temperature in-situ fabrication process is designed to obtain smooth surfaces and sharp interfaces. Less than 500^circC growth temperatures would be compatible with the existing semiconductor technology. At the beginning of this research project, the lowest deposition temperature reported for the fabrication of in-situ superconducting films was about 650^circC. Our goal was to develop a technique that would enable us to fabricate in-situ high T_{ rm c} superconducting films at a substrate temperature lower than 650^circC. By incorporating a weak oxygen plasma in the laser evaporation zone, we have been able to develop a novel plasma assisted laser deposition (PLD) technique to grow YBaCuO films that are superconducting in the as-deposited state. Using this technique, good quality superconducting films with mirror -like surfaces have been grown at substrate temperatures as low as 500^circC. YBaCuO films were deposited on single crystal substrates, SrTiO_3, ZrO _2, MgO, sapphire and Si, and also on flexible stainless steel substrates. Films deposited on SrTiO _3 at 500^circC showed a critical temperature of 86K and a critical current of 10^5 A/cm^2 at 80K and 5 times 10^6 A/cm^2 at 4.3K. The possibility of improving the superconducting properties of the films deposited on sapphire, Si, and stainless steel by

  16. Synthesis and superconducting properties of Tl-Ba-Ca-Cu-O films

    NASA Technical Reports Server (NTRS)

    Liou, S. H.; Chan, V. K.; Foong, F.; Lee, W. Y.; Gou, Y. S.

    1991-01-01

    Tl-Ba-Ca-Cu-O superconducting films were synthesized by sputtering either from a single target or from two oxide targets in a symmetric configuration. Films with zero resistance Tc of up to 122 K were obtained after various postannealing treatments at 870-950 C under an oxygen atmosphere. The composition of the films is not very homogeneous on the submicrometer scale. The critical current of these films at 77 K is in the 1000 A/sq cm to 10,000 A/sq cm range, which is much smaller than that of films prepared on SrTiO3 and LaAlO3 substrates. The low critical current density in these films is probably due to the granularity in the films. The morphology, structure, and magnetic and superconducting properties of the films were studied. Films prepared by two different sputtering techniques have similar results which depend mostly on the film compositions and their annealing conditions. It is found that the induced magnetic flux in the film decreases rapidly with increasing temperature, indicating weak flux pinning.

  17. Attachment of lead wires to thin film thermocouples mounted on high temperature materials using the parallel gap welding process

    NASA Technical Reports Server (NTRS)

    Holanda, Raymond; Kim, Walter S.; Pencil, Eric; Groth, Mary; Danzey, Gerald A.

    1990-01-01

    Parallel gap resistance welding was used to attach lead wires to sputtered thin film sensors. Ranges of optimum welding parameters to produce an acceptable weld were determined. The thin film sensors were Pt13Rh/Pt thermocouples; they were mounted on substrates of MCrAlY-coated superalloys, aluminum oxide, silicon carbide and silicon nitride. The entire sensor system is designed to be used on aircraft engine parts. These sensor systems, including the thin-film-to-lead-wire connectors, were tested to 1000 C.

  18. Powder-in-tube and thick-film methods of fabricating high temperature superconductors having enhanced biaxial texture

    DOEpatents

    Goyal, Amit; Kroeger, Donald M.

    2003-11-11

    A method for forming an electronically active biaxially textured article includes the steps of providing a substrate having a single crystal metal or metal alloy surface, deforming the substrate to form an elongated substrate surface having biaxial texture and depositing an epitaxial electronically active layer on the biaxially textured surface. The method can include at least one annealing step after the deforming step to produce the biaxially textured substrate surface. The invention can be used to form improved biaxially textured articles, such as superconducting wire and tape articles having improved J.sub.c values.

  19. Near-ambient pressure XPS of high-temperature surface chemistry in Sr2Co2O5 thin films

    DOE PAGES

    Hong, Wesley T.; Stoerzinger, Kelsey; Crumlin, Ethan J.; Mutoro, Eva; Jeen, Hyoung Jeen; Lee, Ho Nyung; Shao-Horn, Yang

    2016-02-11

    Transition metal perovskite oxides are promising electrocatalysts for the oxygen reduction reaction (ORR) in fuel cells, but a lack of fundamental understanding of oxide surfaces impedes the rational design of novel catalysts with improved device efficiencies. In particular, understanding the surface chemistry of oxides is essential for controlling both catalytic activity and long-term stability. Thus, elucidating the physical nature of species on perovskite surfaces and their catalytic enhancement would generate new insights in developing oxide electrocatalysts. In this article, we perform near-ambient pressure XPS of model brownmillerite Sr2Co2O5 (SCO) epitaxial thin films with different crystallographic orientations. Detailed analysis of themore » Co 2p spectra suggests that the films lose oxygen as a function of temperature. Moreover, deconvolution of the O 1s spectra shows distinct behavior for (114)-oriented SCO films compared to (001)-oriented SCO films, where an additional bulk oxygen species is observed. These findings indicate a change to a perovskite-like oxygen chemistry that occurs more easily in (114) SCO than (001) SCO, likely due to the orientation of oxygen vacancy channels out-of-plane with respect to the film surface. This difference in surface chemistry is responsible for the anisotropy of the oxygen surface exchange coefficient of SCO and may contribute to the enhanced ORR kinetics of La0.8Sr0.2CoO3-δ thin films by SCO surface particles observed previously.« less

  20. Superconducting transistor

    DOEpatents

    Gray, Kenneth E.

    1979-01-01

    A superconducting transistor is formed by disposing three thin films of superconducting material in a planar parallel arrangement and insulating the films from each other by layers of insulating oxides to form two tunnel junctions. One junction is biased above twice the superconducting energy gap and the other is biased at less than twice the superconducting energy gap. Injection of quasiparticles into the center film by one junction provides a current gain in the second junction.

  1. Superconducting properties and chemical composition of NbTiN thin films with different thickness

    SciTech Connect

    Zhang, L.; Peng, W.; You, L. X.; Wang, Z.

    2015-09-21

    In this research, we systematically investigated the superconducting properties and chemical composition of NbTiN thin films prepared on single-crystal MgO substrates. The NbTiN thin films with different thicknesses (4–100 nm) were deposited by reactive DC magnetron sputtering at ambient temperature. We measured and analyzed the crystal structure and thickness dependence of the chemical composition using X-ray diffraction and X-ray photoelectron spectroscopy depth profiles. The films exhibited excellent superconducting properties, with a high superconducting critical temperature of 10.1 K, low resistivity (ρ{sub 20} = 93 μΩ cm), and residual resistivity ratio of 1.12 achieved for 4-nm-thick ultrathin NbTiN films prepared at the deposition current of 2.4 A. The stoichiometry and electrical properties of the films varied gradually between the initial and upper layers. A minimum ρ{sub 20} of 78 μΩ cm and a maximum residual resistivity ratio of 1.15 were observed for 12-nm-thick films, which significantly differ from the properties of NbN films with the same NaCl structure.

  2. High temperature reactive ion etching of iridium thin films with aluminum mask in CF4/O2/Ar plasma

    NASA Astrophysics Data System (ADS)

    Yeh, Chia-Pin; Lisker, Marco; Kalkofen, Bodo; Burte, Edmund P.

    2016-08-01

    Reactive ion etching (RIE) technology for iridium with CF4/O2/Ar gas mixtures and aluminum mask at high temperatures up to 350 °C was developed. The influence of various process parameters such as gas mixing ratio and substrate temperature on the etch rate was studied in order to find optimal process conditions. The surface of the samples after etching was found to be clean under SEM inspection. It was also shown that the etch rate of iridium could be enhanced at higher process temperature and, at the same time, very high etching selectivity between aluminum etching mask and iridium could be achieved.

  3. Processing, electrical and microwave properties of sputtered Tl-Ca-Ba-Cu-O superconducting thin films

    NASA Technical Reports Server (NTRS)

    Subramanyam, G.; Kapoor, V. J.; Chorey, C. M.; Bhasin, K. B.

    1993-01-01

    A reproducible fabrication process has been established for TlCaBaCuO thin films on LaAlO3 substrates by RF magnetron sputtering and post-deposition processing methods. Electrical transport properties of the thin films were measured on patterned four-probe test devices. Microwave properties of the films were obtained from unloaded Q measurements of all-superconducting ring resonators. This paper describes the processing, electrical and microwave properties of Tl2Ca1Ba2Cu2O(x) 2122-plane phase thin films.

  4. High-temperature performance of MoS{sub 2} thin-film transistors: Direct current and pulse current-voltage characteristics

    SciTech Connect

    Jiang, C.; Samnakay, R.; Balandin, A. A.; Rumyantsev, S. L.; Shur, M. S.

    2015-02-14

    We report on fabrication of MoS{sub 2} thin-film transistors (TFTs) and experimental investigations of their high-temperature current-voltage characteristics. The measurements show that MoS{sub 2} devices remain functional to temperatures of at least as high as 500 K. The temperature increase results in decreased threshold voltage and mobility. The comparison of the direct current (DC) and pulse measurements shows that the direct current sub-linear and super-linear output characteristics of MoS{sub 2} thin-films devices result from the Joule heating and the interplay of the threshold voltage and mobility temperature dependences. At temperatures above 450 K, a kink in the drain current occurs at zero gate voltage irrespective of the threshold voltage value. This intriguing phenomenon, referred to as a “memory step,” was attributed to the slow relaxation processes in thin films similar to those in graphene and electron glasses. The fabricated MoS{sub 2} thin-film transistors demonstrated stable operation after two months of aging. The obtained results suggest new applications for MoS{sub 2} thin-film transistors in extreme-temperature electronics and sensors.

  5. Superconducting MgB{sub 2} films via precursor postprocessing approach

    SciTech Connect

    Paranthaman, M.; Cantoni, C.; Zhai, H. Y.; Christen, H. M.; Aytug, T.; Sathyamurthy, S.; Specht, E. D.; Thompson, J. R.; Lowndes, D. H.; Kerchner, H. R.

    2001-06-04

    Superconducting MgB{sub 2} films with T{sub c}=38.6K were prepared using a precursor-deposition, ex situ postprocessing approach. Precursor films of boron, {similar_to}0.5 {mu}m thick, were deposited onto Al{sub 2}O{sub 3} (102) substrates by electron-beam evaporation; a postanneal at 890{degree}C in the presence of bulk MgB{sub 2} and Mg metal produced highly crystalline MgB{sub 2} films. X-ray diffraction indicated that the films exhibit some degree of c-axis alignment, but are randomly oriented in plane. Transport current measurements of the superconducting properties show high values of the critical current density and yield an irreversibility line that exceeds that determined by magnetic measurements on bulk polycrystalline materials. {copyright} 2001 American Institute of Physics.

  6. Evidence of Superstoichiometric H/d Lenr Active Sites and High-Temperature Superconductivity in a Hydrogen-Cycled Pd/PdO

    NASA Astrophysics Data System (ADS)

    Lipson, A. G.; Castano, C. H.; Miley, G. H.; Lyakhov, B. F.; Tsivadze, A. Yu.; Mitin, A. V.

    Electron transport and magnetic properties have been studied in a 12.5 μm thick Pd foil with a thermally grown oxide and a low-residual concentration of hydrogen. This foil was deformed by cycling across the Pd hydride miscibility gap and the residual hydrogen was trapped at dislocation cores. Anomalies of both resistance and magnetic susceptibility have been observed below 70 K, indicating the appearance of excess conductivity and a diamagnetic response that we interpret in terms of filamentary superconductivity. These anomalies are attributed to a condensed hydrogen-rich phase at dislocation cores. The role of deuterium rich dislocation cores as LENR active sites is discussed.

  7. High Temperature Protonic Conductors

    NASA Technical Reports Server (NTRS)

    Dynys, Fred; Berger, Marie-Helen; Sayir, Ali

    2007-01-01

    High Temperature Protonic Conductors (HTPC) with the perovskite structure are envisioned for electrochemical membrane applications such as H2 separation, H2 sensors and fuel cells. Successive membrane commercialization is dependent upon addressing issues with H2 permeation rate and environmental stability with CO2 and H2O. HTPC membranes are conventionally fabricated by solid-state sintering. Grain boundaries and the presence of intergranular second phases reduce the proton mobility by orders of magnitude than the bulk crystalline grain. To enhanced protonic mobility, alternative processing routes were evaluated. A laser melt modulation (LMM) process was utilized to fabricate bulk samples, while pulsed laser deposition (PLD) was utilized to fabricate thin film membranes . Sr3Ca(1+x)Nb(2-x)O9 and SrCe(1-x)Y(x)O3 bulk samples were fabricated by LMM. Thin film BaCe(0.85)Y(0.15)O3 membranes were fabricated by PLD on porous substrates. Electron microscopy with chemical mapping was done to characterize the resultant microstructures. High temperature protonic conduction was measured by impedance spectroscopy in wet air or H2 environments. The results demonstrate the advantage of thin film membranes to thick membranes but also reveal the negative impact of defects or nanoscale domains on protonic conductivity.

  8. Growth and characterization of superconducting spinel oxide LiTi2O4 thin films

    SciTech Connect

    Chopdekar, R.V.; Wong, F.; Takamura, Y.; Arenholz, E.; Suzuki, Y.

    2009-03-10

    Epitaxial films of LiTi{sub 2}O{sub 4} on single crystalline substrates of MgAl{sub 2}O{sub 4}, MgO, and SrTiO{sub 3} provide model systems to systematically explore the effects of lattice strain and microstructural disorder on the superconducting state. Lattice strain that affects bandwidth gives rise to variations in the superconducting and normal state properties. Microstructural disorder, such as antiphase boundaries that give rise to Ti network disorder, reduces the critical temperature, and Ti network disorder combined with Mg interdiffusion lead to a much more dramatic effect on the superconducting state. Surface sensitive X-ray absorption spectroscopy has identified Ti to retain site symmetry and average valence of the bulk material regardless of film thickness.

  9. Magnetic anisotropy peculiarities of high-temperature ferromagnetic MnxSi1-x (x ≈ 0.5) alloy films

    NASA Astrophysics Data System (ADS)

    Drovosekov, A. B.; Kreines, N. M.; Savitsky, A. O.; Kapelnitsky, S. V.; Rylkov, V. V.; Tugushev, V. V.; Prutskov, G. V.; Novodvorskii, O. A.; Cherebilo, E. A.; Kulatov, E. T.; Wang, Y.; Zhou, S.

    2016-08-01

    Thin films of Mn x Si1-x alloys with different Mn concentration x≈0.44\\text{--}0.63 grown by the pulsed-laser deposition (PLD) method onto the Al2O3 (0001) substrate were investigated in the temperature range 4-300 K using ferromagnetic resonance (FMR) measurements in the wide range of frequencies (f = 7\\text{--}60 \\text{GHz}) and magnetic fields (H = 0\\text{--}30 \\text{kOe}) . For samples with x≈0.52\\text{--}0.55 , FMR data show clear evidence of ferromagnetism (FM) with high Curie temperatures TC ˜ 300 \\text{K} . These samples demonstrate the complex and unusual character of magnetic anisotropy described in the frame of phenomenological model as a combination of the essential second-order easy-plane anisotropy contribution and the additional fourth-order anisotropy contribution with the easy direction normal to the film plane. We explain the obtained results by a polycrystalline (mosaic) structure of the films caused by the film-substrate lattice mismatch.

  10. Buffer layers for REBCO films for use in superconducting devices

    SciTech Connect

    Goyal, Amit; Wee, Sung-Hun

    2014-06-10

    A superconducting article includes a substrate having a biaxially textured surface. A biaxially textured buffer layer, which can be a cap layer, is supported by the substrate. The buffer layer includes a double perovskite of the formula A.sub.2B'B''O.sub.6, where A is rare earth or alkaline earth metal and B' and B'' are different transition metal cations. A biaxially textured superconductor layer is deposited so as to be supported by the buffer layer. A method of making a superconducting article is also disclosed.

  11. Spin dynamics near a putative antiferromagnetic quantum critical point in Cu-substituted BaFe2As2 and its relation to high-temperature superconductivity

    NASA Astrophysics Data System (ADS)

    Kim, M. G.; Wang, M.; Tucker, G. S.; Valdivia, P. N.; Abernathy, D. L.; Chi, Songxue; Christianson, A. D.; Aczel, A. A.; Hong, T.; Heitmann, T. W.; Ran, S.; Canfield, P. C.; Bourret-Courchesne, E. D.; Kreyssig, A.; Lee, D. H.; Goldman, A. I.; McQueeney, R. J.; Birgeneau, R. J.

    2015-12-01

    We present the results of elastic and inelastic neutron scattering measurements on nonsuperconducting Ba (Fe 0.957Cu 0.043) 2As 2 , a composition close to a quantum critical point between antiferromagnetic (AFM) ordered and paramagnetic phases. By comparing these results with the spin fluctuations in the low-Cu composition as well as the parent compound BaFe2As2 and superconducting Ba (Fe1-xNix) 2As2 compounds, we demonstrate that paramagnon-like spin fluctuations are evident in the antiferromagnetically ordered state of Ba (Fe0.957Cu0.043)2As2 , which is distinct from the AFM-like spin fluctuations in the superconducting compounds. Our observations suggest that Cu substitution decouples the interaction between quasiparticles and the spin fluctuations. We also show that the spin-spin correlation length ξ (T ) increases rapidly as the temperature is lowered and find ω /T scaling behavior, the hallmark of quantum criticality, at an antiferromagnetic quantum critical point.

  12. Spin dynamics near a putative antiferromagnetic quantum critical point in Cu-substituted BaFe2As2 and its relation to high-temperature superconductivity

    DOE PAGES

    Kim, M. G.; Wang, M.; Tucker, G. S.; Valdivia, P. N.; Abernathy, D. L.; Chi, Songxue; Christianson, A. D.; Aczel, A. A.; Hong, T.; Heitmann, T. W.; et al

    2015-12-02

    We present the results of elastic and inelastic neutron scattering measurements on nonsuperconducting Ba(Fe0.957Cu0.043)2As2, a composition close to a quantum critical point between antiferromagnetic (AFM) ordered and paramagnetic phases. By comparing these results with the spin fluctuations in the low-Cu composition as well as the parent compound BaFe2As2 and superconducting Ba(Fe1–xNix)2As2 compounds, we demonstrate that paramagnon-like spin fluctuations are evident in the antiferromagnetically ordered state of Ba(Fe0.957Cu0.043)2As2, which is distinct from the AFM-like spin fluctuations in the superconducting compounds. Our observations suggest that Cu substitution decouples the interaction between quasiparticles and the spin fluctuations. In addition, we show that themore » spin-spin correlation length ξ(T) increases rapidly as the temperature is lowered and find ω/T scaling behavior, the hallmark of quantum criticality, at an antiferromagnetic quantum critical point.« less

  13. Quench-condensing superconducting thin films using the Fab on a Chip approach

    NASA Astrophysics Data System (ADS)

    Han, Han; Imboden, Matthias; Del Corro, Pablo; Stark, Thomas; Lally, Richard; Pardo, Flavio; Bolle, Cristian; Bishop, David

    Micro-electromechanical systems (MEMS) being manufactured in a macroscopic fab inspires the idea of getting the process further down to fabricate even smaller structures, namely nano-structures, using MEMS. The Fab on a Chip concept was proposed based on such ideas. By implementing the final-step, additive fabrication approach, manufacturing, characterization and experiments of nano-structures are integrated in-situ. Due to the miniature size of MEMS, the thickness precision is significantly improved while the power consumption is significantly depressed, making the quench-condensation of very thin films well controlled and easily achievable. Among various types of nano-structures, quench-condensed superconducting thin films are of great interest for physicists. Here we present such experiments done on superconducting thin films quench-condensed using the Fab on a Chip. We show that we are able to fabricate very thin films with its thickness precisely controlled, and the base temperature kept under ~3K during the process. The resistivity data demonstrates the high purity and uniformity of the film, as well as the annealing effect when cycling to higher temperatures. Based on the tremendous results obtained from the superconducting thin films, more complex nano-circuits can be fabricated and investigated using the Fab on a Chip, enabling a new approach for novel condensed matter physics experiments. This research is funded by the NSF through their CMMI division. This research is funded by the NSF through their CMMI division.

  14. Emerging applications of high temperature superconductors for space communications

    NASA Technical Reports Server (NTRS)

    Heinen, Vernon O.; Bhasin, Kul B.; Long, Kenwyn J.

    1990-01-01

    Proposed space missions require longevity of communications system components, high input power levels, and high speed digital logic devices. The complexity of these missions calls for a high data bandwidth capacity. Incorporation of high temperature superconducting (HTS) thin films into some of these communications system components may provide a means of meeting these requirements. Space applications of superconducting technology has previously been limited by the requirement of cooling to near liquid helium temperatures. Development of HTS materials with transition temperatures above 77 K along with the natural cooling ability of space suggest that space applications may lead the way in the applications of high temperature superconductivity. In order for HTS materials to be incorporated into microwave and millimeter wave devices, the material properties such as electrical conductivity, current density, surface resistivity and others as a function of temperature and frequency must be well characterized and understood. The millimeter wave conductivity and surface resistivity were well characterized, and at 77 K are better than copper. Basic microwave circuits such as ring resonators were used to determine transmission line losses. Higher Q values than those of gold resonator circuits were observed below the transition temperature. Several key HTS circuits including filters, oscillators, phase shifters and phased array antenna feeds are feasible in the near future. For technology to improve further, good quality, large area films must be reproducibly grown on low dielectric constant, low loss microwave substrates.

  15. Hybrid Cluster Precursors of the LaZrO Insulator for Transistors: Properties of High-Temperature-Processed Films and Structures of Solutions, Gels, and Solids

    PubMed Central

    Li, Jinwang; Zhu, Peixin; Hirose, Daisuke; Kohara, Shinji; Shimoda, Tatsuya

    2016-01-01

    In the solution processing of oxide electronics, the structure of metal–organic precursors in solution and their effect on processability and on the final structure and properties of the oxide have rarely been studied. We have observed that hybrid clusters, having inorganic cores coordinated by organic ligands, are the typical form of metal–organic precursor structures. For insulating ternary LaZrO, improved synthesis of the cluster precursor under solvothermal conditions led to low-temperature deposition of the film at 200 °C, as we will report in another paper. In the current paper, we first briefly show that solvothermal synthesis of the precursor resulted in significantly improved insulating properties (e.g., two orders lower leakage current) of high-temperature-annealed films, and then focus on the structural analysis of the cluster precursors and annealed solids and relate the results to the significant improvement of properties by solvothermal treatment of solutions. A change in the cluster core toward structural unification was brought about by solvothermal treatment, resulting in higher uniformity and higher stability of clusters. The final structure of the material maintained the features of the core structure in solution, even after annealing at high temperatures. These results demonstrate the key role played by designing cluster structure in solution. PMID:27411971

  16. Hybrid Cluster Precursors of the LaZrO Insulator for Transistors: Properties of High-Temperature-Processed Films and Structures of Solutions, Gels, and Solids.

    PubMed

    Li, Jinwang; Zhu, Peixin; Hirose, Daisuke; Kohara, Shinji; Shimoda, Tatsuya

    2016-01-01

    In the solution processing of oxide electronics, the structure of metal-organic precursors in solution and their effect on processability and on the final structure and properties of the oxide have rarely been studied. We have observed that hybrid clusters, having inorganic cores coordinated by organic ligands, are the typical form of metal-organic precursor structures. For insulating ternary LaZrO, improved synthesis of the cluster precursor under solvothermal conditions led to low-temperature deposition of the film at 200 °C, as we will report in another paper. In the current paper, we first briefly show that solvothermal synthesis of the precursor resulted in significantly improved insulating properties (e.g., two orders lower leakage current) of high-temperature-annealed films, and then focus on the structural analysis of the cluster precursors and annealed solids and relate the results to the significant improvement of properties by solvothermal treatment of solutions. A change in the cluster core toward structural unification was brought about by solvothermal treatment, resulting in higher uniformity and higher stability of clusters. The final structure of the material maintained the features of the core structure in solution, even after annealing at high temperatures. These results demonstrate the key role played by designing cluster structure in solution. PMID:27411971

  17. Evolution of the electronic structure of CaO thin films following Mo interdiffusion at high temperature

    NASA Astrophysics Data System (ADS)

    Cui, Yi; Pan, Yi; Pascua, Leandro; Qiu, Hengshan; Stiehler, Christian; Kuhlenbeck, Helmut; Nilius, Niklas; Freund, Hans-Joachim

    2015-01-01

    The electronic structure of CaO films of 10-60 monolayer thickness grown on Mo(001) has been investigated with synchrotron-mediated x-ray photoelectron spectroscopy (XPS) and scanning tunneling microscopy (STM). Upon annealing or reducing the thickness of the film, a rigid shift of the CaO bands to lower energy is revealed. This evolution is explained with a temperature-induced diffusion of Mo ions from the metal substrate to the oxide and their accumulation in the interface region of the film. The Mo substitutes divalent Ca species in the rocksalt lattice and is able to release electrons to the system. The subsequent changes in the Mo oxidation state have been followed with high-resolution XPS measurements. While near-interface Mo transfers extra electrons back to the substrate, generating an interface dipole that gives rise to the observed band shift, near-surface species are able to exchange electrons with adsorbates bound to the oxide surface. For example, exposure of O2 results in the formation of superoxo species on the oxide surface, as revealed from STM measurements. Mo interdiffusion is therefore responsible for the pronounced donor character of the initially inert oxide, and largely modifies its adsorption and reactivity behavior.

  18. Reinforced fluropolymer nanocomposites with high-temperature superconducting Bi{sub 2}Sr{sub 2}CaCu{sub 2}O{sub y}

    SciTech Connect

    Jayasree, T. K.

    2014-10-15

    Bismuth Strontium Calcium Copper Oxide (Bi{sub 2}Sr{sub 2}CaCu{sub 2}O{sub y})/Polyvinylidene fluoride (PVDF) nanocomposite was prepared and their thermal properties were analyzed. The composite consists of the polyvinylidene fluoride (PVDF) as an insulating polymer matrix, and homogenously distributed Bismuth strontium calcium copperoxide (2212) nanoparticles. SEM data shows flaky grains of the superconductor coated and linked by polymer. Differential scanning calorimetry (DSC) results indicated that the melting point was not affected significantly by the addition of BSCCO. However, the addition of superconducting ceramic resulted in an extra melting peak at a lower temperature (145°C). Thermogravimetric analysis of the samples shows that the onset decomposition temperature of the PVDF matrix was decreased by the addition of SC filler.

  19. High temperature strain gages

    NASA Technical Reports Server (NTRS)

    Gregory, Otto J. (Inventor); You, Tao (Inventor)

    2011-01-01

    A ceramic strain gage based on reactively sputtered indium-tin-oxide (ITO) thin films is used to monitor the structural integrity of components employed in aerospace propulsion systems operating at temperatures in excess of 1500.degree. C. A scanning electron microscopy (SEM) of the thick ITO sensors reveals a partially sintered microstructure comprising a contiguous network of submicron ITO particles with well defined necks and isolated nanoporosity. Densification of the ITO particles was retarded during high temperature exposure with nitrogen thus stabilizing the nanoporosity. ITO strain sensors were prepared by reactive sputtering in various nitrogen/oxygen/argon partial pressures to incorporate more nitrogen into the films. Under these conditions, sintering and densification of the ITO particles containing these nitrogen rich grain boundaries was retarded and a contiguous network of nano-sized ITO particles was established.

  20. Spontaneous formation of superconducting NiBi{sub 3} phase in Ni-Bi bilayer films

    SciTech Connect

    Siva, Vantari; Senapati, Kartik Prusty, Sudakshina; Sahoo, Pratap K.; Satpati, Biswarup

    2015-02-28

    We report the spontaneous formation of superconducting NiBi{sub 3} phase in thermally evaporated Ni-Bi bilayer films. High reaction-diffusion coefficient of Bi is believed to drive the formation of NiBi{sub 3} during the deposition of Bi on the Ni film. Cross sectional transmission electron microscopy and glancing incidence X-ray depth profiling confirmed the presence of NiBi{sub 3} throughout the top Bi layer. Superconducting transition at ∼3.9 K, close to the bulk value, was confirmed by transport and magnetization measurements. The bilayers were irradiated with varying fluence of 100 MeV Au ions to study the robustness of superconducting order in presence of large concentration of defects. Superconducting parameters of NiBi{sub 3}, such as transition temperature and upper critical field, remained unchanged upto an ion dose of 1 × 10{sup 14} ions/cm{sup 2}. The diffusive formation of NiBi{sub 3} in Ni opens the possibility of studying superconducting proximity effect at a truly clean superconductor-ferromagnet interface.