Petroleum exploration and the Atlantic OCS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Edson, G.; Adinolfi, F.; Gray, F.

1993-08-01

The largest Atlantic outer continental shelf (OCS) lease sale was the first one, Sale 40 in 1976. Ninety-three Baltimore Canyon Trough petroleum leases were issued, and industry's winning bids total $1.1 billion. The highest bonus bids were for leases overlying the Schlee Dome, then called Great Stone Dome, a large structure with a very large fetch area. By 1981, seven dry wells on the dome moderated this initial flush of optimism. However, subeconomic quantities of gas and light oil were discovered on the nearby Hudson Canyon Block 598-642 structure. Now after 9 lease sales, 410 lease awards, and 46 explorationmore » wells, United States Atlantic petroleum exploration activity is in a hiatus. Fifty-three leases remain active under suspensions of operation. Twenty-one lease blocks, about 50 mi offshore from Cape Hatteras, have been combined as the Manteo Exploration Unit. Mobil and partners submitted an exploration plant for the unit in 1989. The Atlantic OCS has petroleum potential, especially for gas. With only 46 exploration wells, entire basins and plays remain untested. During the present exploration inactivity, some petroleum evaluation of the Atlantic OCS continues by the Minerals Management Service and others. Similarities and differences are being documented between United States basins and the Canadian Scotian Basin, which contains oil and gas in commercial quantities. Other initiatives include geochemical, thermal history, seismic stratigraphic, and petroleum system modeling studies. The gas-prone Atlantic OCS eventually may make an energy contribution, especially to nearby East Coast markets.« less

Induced bioelectrochemical metabolism for bioremediation of petroleum refinery wastewater: Optimization of applied potential and flow of wastewater.

PubMed

Mohanakrishna, Gunda; Al-Raoush, Riyadh I; Abu-Reesh, Ibrahim M

2018-07-01

Hybrid based bioelectrochemical system (BES) configured with embedded anode and cathode electrodes in soil was tested for the bioelectrochemical degradation of petroleum refinery wastewater (PRW). Four applied potentials were studied to optimize under batch mode operation, among which 2 V resulted in higher COD degradation (69.2%) and power density (725 mW/m 2 ) during 7 days of operation. Further studies with continuous mode of operation at optimized potential (2 V) showed that hydraulic retention time (HRT) of 19 h achieved the highest COD removal (37%) and highest power density (561 mW/m 2 ). BES function with respect to treatment efficiencies of other pollutants of PRW was also identified with respect to oil and grease (batch mode, 91%; continuous mode, 34%), total dissolved salts (batch mode, 53%; continuous mode, 24%) and sulfates (batch mode, 59%; continuous mode, 42%). Soil microenvironment in association with BES forms complex processes, providing suitable conditions for efficient treatment of PRW. Copyright © 2018 Elsevier Ltd. All rights reserved.

Japan Country Analysis Brief

EIA Publications

2017-01-01

Japan is the world's largest liquefied natural gas importer and ranks in the top four countries for the highest coal imports, net imports of petroleum and other liquids, and consumption of crude oil and petroleum products.

Toxicity testing of crude oil and related compounds using early life stages of the crimson-spotted rainbowfish (Melanotaenia fluviatilis).

PubMed

Pollino, Carmel A; Holdway, Douglas A

2002-07-01

The toxicity of petroleum hydrocarbons to marine aquatic organisms has been widely investigated; however, the effects on freshwater environments have largely been ignored. In the Australian freshwater environment, the potential impacts of petroleum hydrocarbons are virtually unknown. The toxicity of crude oil and related compounds were measured in the sensitive early life stages of the crimson-spotted rainbowfish (Melanotaenia fluviatilis). Waterborne petroleum hydrocarbons crossed the chorion of embryonic rainbowfish, reducing survival and hatchability. Acute exposures resulted in developmental abnormalities at and above 0.5 mg/L total petroleum hydrocarbons (TPH). Deformities included pericardial edema, disturbed axis formation, and abnormal jaw development. When assessing the acute toxicities of the water-accommodated fraction (WAF) of crude oil, dispersants, dispersant-oil mixtures, and naphthalene to larval rainbowfish, the lowest to highest 96-h median lethal concentrations for day of hatch larvae were naphthalene (0.51 mg/L), dispersed crude oil WAF (DCWAF)-9527 (0.74 mg/L TPH), WAF (1.28 mg/L TPH), DCWAF-9500 (1.37 mg/L TPH), Corexit 9500 (14.5 mg/L TPH), and Corexit 9527 (20.1 mg/L). Using naphthalene as a reference toxicant, no differences were found between the sensitivities of larval rainbowfish collected from adults exposed to petroleum hydrocarbons during embryonic development and those collected from unexposed adults.

Phase 2 Site Investigations Report. Volume 1 of 3: General Annex-Wide Information

DTIC Science & Technology

1994-09-01

completeness PCB Polychlorinated Biphenyl PCE Tetrachloroethene or Perchloroethene PHC Petroleum hydrocarbons PID Photoionization Detector POLs Petroleum , Oil...TEPS Total Environmental Program Support TIC Tentatively Identified Compound TOC Total Organic Carbon TPHC Total Petroleum Hydrocarbons TRC Technical... hydrocarbons were identified within some soil and sediment samples near the detection limit. These could result from urban runoff. No petroleum

Total petroleum systems of the Grand Erg/Ahnet Province, Algeria and Morocco; the Tanezzuft-Timimoun, Tanezzuft-Ahnet, Tanezzuft-Sbaa, Tanezzuft Mouydir, Tanezzuft-Benoud, and Tanezzuft-Bechar/Abadla

USGS Publications Warehouse

Klett, T.R.

2000-01-01

Undiscovered, conventional oil and gas resources were assessed within total petroleum systems of the Grand Erg/Ahnet Province (2058) as part of the U.S. Geological Survey World Petroleum Assessment 2000. The majority of the Grand Erg/ Ahnet Province is in western Algeria; a very small portion extends into Morocco. The province includes the Timimoun Basin, Ahnet Basin, Sbaa Basin, Mouydir Basin, Benoud Trough, Bechar/Abadla Basin(s), and part of the Oued Mya Basin. Although several petroleum systems may exist within each of these basins, only seven ?composite? total petroleum systems were identified. Each total petroleum system occurs in a separate basin, and each comprises a single assessment unit. The main source rocks are the Silurian Tanezzuft Formation (or lateral equivalents) and Middle to Upper Devonian mudstone. Maturation history and the major migration pathways from source to reservoir are unique to each basin. The total petroleum systems were named after the oldest major source rock and the basin in which it resides. The estimated means of the undiscovered conventional petroleum volumes in total petroleum systems of the Grand Erg/ Ahnet Province are as follows: [MMBO, million barrels of oil; BCFG, billion cubic feet of gas; MMBNGL, million barrels of natural gas liquids] Total Petroleum System MMBO BCFG MMBNGL Tanezzuft-Timimoun 31 1,128 56 Tanezzuft-Ahnet 34 2,973 149 Tanezzuft-Sbaa 162 645 11 Tanezzuft-Mouydir 12 292 14 Tanezzuft-Benoud 72 2,541 125 Tanezzuft-Bechar/Abadla 16 441 22

Cultivation of a bacterial consortium with the potential to degrade total petroleum hydrocarbon using waste activated sludge.

PubMed

Sivakumar, S; Song, Y C; Kim, S H; Jang, S H

2015-11-01

Waste activated sludge was aerobically treated to demonstrate multiple uses such as cultivating an oil degrading bacterial consortium; studying the influence of a bulking agent (peat moss) and total petroleum hydrocarbon concentration on bacterial growth and producing a soil conditioner using waste activated sludge. After 30 days of incubation, the concentration of oil-degrading bacteria was 4.3 x 10(8) CFU g(-1) and 4.5 x 10(8) CFU g(-1) for 5 and 10 g of total petroleum hydrocarbon, respectively, in a mixture of waste activated sludge (1 kg) and peat moss (0.1 kg). This accounts for approximately 88.4 and 91.1%, respectively, of the total heterotrophic bacteria (total-HB). The addition of bulking agent enhanced total-HB population and total petroleum hydrocarbon-degrading bacterial population. Over 90% of total petroleum hydrocarbon degradation was achieved by the mixture of waste activated sludge, bulking agent and total petroleum hydrocarbon. The results of physico-chemical parameters of the compost (waste activated sludge with and without added peat moss compost) and a substantial reduction in E. coli showed that the use of this final product did not exhibit risk when used as soil conditioner. Finally, the present study demonstrated that cultivation of total petroleum hydrocarbon-degrading bacterial consortium and production of compost from waste activated sludge by aerobic treatment was feasible.

San Francisco Deep Ocean Dredged Material Disposal Site (SF-DODS) Monitoring Program. Physical, Chemical, and Benthic Community Monitoring

DTIC Science & Technology

2003-08-29

analyzed for total volatile solids, total organic carbon, oil and grease/total petroleum hydrocarbons , grain size distribution, metals, polycyclic...TBT Tri-Butyltin TOC Total Organic Carbon TPCB Total Polychlorinated Biphenyls TPH Total Petroleum Hydrocarbons USACE U.S. Army Corps of Engineers U.S...Health PQL Practical Quantitation Limit RCRA Resource Conservation and Recovery Act SIM Selected Ion Monitoring TPH Total Petroleum Hydrocarbons tr Trace

Antioxidative Activities and Active Compounds of Extracts from Catalpa Plant Leaves

PubMed Central

Xu, Hongyu; Hu, Gege; Dong, Juane; Wei, Qin; Shao, Hongbo; Lei, Ming

2014-01-01

In order to screen the Catalpa plant with high antioxidant activity and confirm the corresponding active fractions from Catalpa ovata G. Don, C. fargesii Bur., and C. bungei C. A. Mey., total flavonoid contents and antioxidant activities of the extracts/fractions of Catalpa plant leaves were determined. The determined total flavonoid content and antioxidant activity were used as assessment criteria. Those compounds with antioxidant activity were isolated with silica gel column chromatography and ODS column chromatography. Our results showed that the total flavonoid content in C. bungei C. A. Mey. (30.07 mg/g·DW) was the highest, followed by those in C. fargesii Bur. (25.55 mg/g·DW) and C. ovata G. Don (24.96 mg/g·DW). According to the determination results of total flavonoid content and antioxidant activity in 3 clones of leaves of C. bungei C. A. Mey., the total flavonoid content and antioxidant activity in crude extracts from C. bungei C. A. Mey. 6 (CA6) leaves were the highest. Moreover, the results showed that the total flavonoid content and antioxidant activities of ethyl acetate (EA) fraction in ethanol crude extracts in CA6 leaves were the highest, followed by n-butanol, petroleum ether (PE), and water fractions. Two flavonoid compounds with antioxidant activity were firstly isolated based on EA fraction. The two compounds were luteolin (1) and apigenin (2), respectively. PMID:25431795

Antioxidative activities and active compounds of extracts from Catalpa plant leaves.

PubMed

Xu, Hongyu; Hu, Gege; Dong, Juane; Wei, Qin; Shao, Hongbo; Lei, Ming

2014-01-01

In order to screen the Catalpa plant with high antioxidant activity and confirm the corresponding active fractions from Catalpa ovata G. Don, C. fargesii Bur., and C. bungei C. A. Mey., total flavonoid contents and antioxidant activities of the extracts/fractions of Catalpa plant leaves were determined. The determined total flavonoid content and antioxidant activity were used as assessment criteria. Those compounds with antioxidant activity were isolated with silica gel column chromatography and ODS column chromatography. Our results showed that the total flavonoid content in C. bungei C. A. Mey. (30.07 mg/g · DW) was the highest, followed by those in C. fargesii Bur. (25.55 mg/g · DW) and C. ovata G. Don (24.96 mg/g · DW). According to the determination results of total flavonoid content and antioxidant activity in 3 clones of leaves of C. bungei C. A. Mey., the total flavonoid content and antioxidant activity in crude extracts from C. bungei C. A. Mey. 6 (CA6) leaves were the highest. Moreover, the results showed that the total flavonoid content and antioxidant activities of ethyl acetate (EA) fraction in ethanol crude extracts in CA6 leaves were the highest, followed by n-butanol, petroleum ether (PE), and water fractions. Two flavonoid compounds with antioxidant activity were firstly isolated based on EA fraction. The two compounds were luteolin (1) and apigenin (2), respectively.

Seasonal distribution and contamination levels of total PHCs, PAHs and heavy metals in coastal waters of the Alang-Sosiya ship scrapping yard, Gulf of Cambay, India.

PubMed

Srinivasa Reddy, M; Basha, Shaik; Joshi, H V; Ramachandraiah, G

2005-12-01

Alang-Sosiya situated on the Gulf of Cambay is one of the largest ship breaking yard in the world. The seasonal distribution and contamination levels of dissolved and/or dispersed total petroleum hydrocarbons (PHCs), total polycyclic aromatic hydrocarbons (PAHs) and heavy metals in seawater during high tide are investigated. The concentrations of petroleum hydrocarbons and heavy metals are higher in the winter than in the monsoon and summer. The concentrations of total PHCs and PAHs are about three times higher in the winter and two times in the monsoon or summer at Along-Sosiya and about twice in all seasons at two stations one on either side 5 km away from it as compared to the reference station at Mahuva, 60 km away towards the south. Further, the levels of PHCs are correlated with salinity and compared with those of other regions. The concentration of all metals is the highest in the winter season followed by the monsoon and summer. We carried out the quantitative analysis of the possible relationships among 13 variables such as Al, Fe, Pb, Mn, Cu, Zn, Cd, Cr, Co, pH, NO3-, NO2 and PO4(3-).

Evaluation of ethyl lactate as solvent in Fenton oxidation for the remediation of total petroleum hydrocarbon (TPH)-contaminated soil.

PubMed

Jalilian Ahmadkalaei, Seyedeh Pegah; Gan, Suyin; Ng, Hoon Kiat; Abdul Talib, Suhaimi

2017-07-01

Due to the health and environmental risks posed by the presence of petroleum-contaminated areas around the world, remediation of petroleum-contaminated soil has drawn much attention from researchers. Combining Fenton reaction with a solvent has been proposed as a novel way to remediate contaminated soils. In this study, a green solvent, ethyl lactate (EL), has been used in conjunction with Fenton's reagents for the remediation of diesel-contaminated soil. The main aim of this research is to determine how the addition of EL affects Fenton reaction for the destruction of total petroleum hydrocarbons (TPHs) within the diesel range. Specifically, the effects of different parameters, including liquid phase volume-to-soil weight (L/S) ratio, hydrogen peroxide (H 2 O 2 ) concentration and EL% on the removal efficiency, have been studied in batch experiments. The results showed that an increase in H 2 O 2 resulted in an increase in removal efficiency of TPH from 68.41% at H 2 O 2  = 0.1 M to 90.21% at H 2 O 2  = 2 M. The lowest L/S, i.e. L/S = 1, had the highest TPH removal efficiency of 85.77%. An increase in EL% up to 10% increased the removal efficiency to 96.74% for TPH, and with further increase in EL%, the removal efficiency of TPH decreased to 89.6%. EL with an optimum value of 10% was found to be best for TPH removal in EL-based Fenton reaction. The power law and pseudo-first order equations fitted well to the experimental kinetic data of Fenton reactions.

INNOVATIVE TECHNOLOGY VERIFICATION REPORT "FIELD MEASUREMENT TECHNOLOGIES FOR TOTAL PETROLEUM HYDROCARBONS IN SOIL" CHEMETRICS, INC., AND AZUR ENVIRONMENTAL LTD REMEDIAID TOTAL PETROLEUM HYDROCARBON STARTER KIT

EPA Science Inventory

The RemediAidTm Total Petroleum Hydrocarbon Starter Kit (RemediAidTm kit) developed by CHEMetries, Inc. (CHEMetrics), and AZUR Environmental Ltd was demonstrated under the U.S. Environmental Protection Agency Superfund Innovative Technology Evaluation Program in June 2000 at the ...

Thai plants with high antioxidant levels, free radical scavenging activity, anti-tyrosinase and anti-collagenase activity.

PubMed

Chatatikun, Moragot; Chiabchalard, Anchalee

2017-11-09

Ultraviolet radiation from sunlight induces overproduction of reactive oxygen species (ROS) resulting in skin photoaging and hyperpigmentation disorders. Novel whitening and anti-wrinkle compounds from natural products have recently become of increasing interest. The purpose of this study was to find products that reduce ROS in 14 Thai plant extracts. To determine total phenolic and flavonoid content, antioxidant activity, anti-tyrosinase activity and anti-collagenase activity, we compared extracts of 14 Thai plants prepared using different solvents (petroleum ether, dichloromethane and ethanol). Antioxidant activities were determined by DPPH and ABTS assays. Total phenolic content of the 14 Thai plants extracts was found at the highest levels in ethanol followed by dichloromethane and petroleum ether extracts, respectively, while flavonoid content was normally found in the dichloromethane fraction. Scavenging activity ranged from 7 to 99% scavenging as assessed by DPPH and ABTS assays. The ethanol leaf extract of Ardisia elliptica Thunb. had the highest phenolic content, antioxidant activity and collagenase inhibition, while Cassia alata (L.) Roxb. extract had the richest flavonoid content. Interestingly, three plants extracts, which were the ethanolic fractions of Annona squamosa L., Ardisia elliptica Thunb. and Senna alata (L.) Roxb., had high antioxidant content and activity, and significantly inhibited both tyrosinase and collagenase. Our finding show that the ethanol fractions of Annona squamosa L., Ardisia elliptica Thunb. and Senna alata (L.) Roxb. show promise as potential ingredients for cosmetic products such as anti-wrinkle agents and skin whitening products.

Biomass burning contributed most to the human cancer risk exposed to the soil-bound PAHs from Chengdu Economic Region, western China.

PubMed

Zheng, Huang; Xing, Xinli; Hu, Tianpeng; Zhang, Yuan; Zhang, Jiaquan; Zhu, Gehao; Li, Ying; Qi, Shihua

2018-05-03

The purpose of this study was to assess the human cancer risk due to the exposure to the soil-bound polycyclic aromatic hydrocarbons (PAHs) from Chengdu Economic Region (CER), western China with the main concern on cancer risk source apportionment. The total concentrations of sixteen PAHs ranged from 12.5 to 75431 ng g -1 , with a mean value of 3106 ng g -1 , which suggested that the most areas of CER were contaminated. Source apportionment of PAHs was conducted by the positive matrix factorization (PMF) model and the biomass burning contributed most (63.6%) to the total PAHs, followed by petroleum combustion (16.0%), coke source (11.3%), and petrogenic source (9.2%). Results from incremental lifetime cancer risk (ILCR) calculation showed that soil ingestion exerted the highest cancer risk (accounted for 98.1 - 99.3% of the total cancer risk) on human health among three different exposure pathways, followed by dermal contact (0.66 - 1.83%) and inhalation (0.03 - 0.04%). Among different age groups, adult suffered the highest cancer risk via any exposure pathways. Based on PMF and ILCR methods, the cancer risk source apportionment was conducted and the biomass burning showed moderate cancer risk. The petrogenic, coke, and petroleum sources showed low cancer risks to human. To analyze the sensitivity of the parameters used in ILCR calculation, Monte Carlo simulation was employed. The results indicated that the contribution of each source and exposure duration (ED) were the influential parameters on human health associated with soil-bound PAHs. Therefore, much attentions should be paid to biomass burning to avoid cumulative cancer risk. Copyright © 2018 Elsevier Inc. All rights reserved.

Zero-sulfur diesel fuel from non-petroleum resources : the key to reducing U.S. oil imports.

DOT National Transportation Integrated Search

2012-09-01

Zero-sulfur diesel fuel of the highest quality, the fuel used in this project, can be made by Fischer-Tropsch (FT) synthesis from many non-petroleum resources, including natural gas, which is increasingly abundant in the United States. Zero-sulfur FT...

Natural attenuation of petroleum hydrocarbons-a study of biodegradation effects in groundwater (Vitanovac, Serbia).

PubMed

Marić, Nenad; Matić, Ivan; Papić, Petar; Beškoski, Vladimir P; Ilić, Mila; Gojgić-Cvijović, Gordana; Miletić, Srđan; Nikić, Zoran; Vrvić, Miroslav M

2018-01-20

The role of natural attenuation processes in groundwater contamination by petroleum hydrocarbons is of intense scientific and practical interest. This study provides insight into the biodegradation effects in groundwater at a site contaminated by kerosene (jet fuel) in 1993 (Vitanovac, Serbia). Total petroleum hydrocarbons (TPH), hydrochemical indicators (O 2 , NO 3 - , Mn, Fe, SO 4 2- , HCO 3 - ), δ 13 C of dissolved inorganic carbon (DIC), and other parameters were measured to demonstrate biodegradation effects in groundwater at the contaminated site. Due to different biodegradation mechanisms, the zone of the lowest concentrations of electron acceptors and the zone of the highest concentrations of metabolic products of biodegradation overlap. Based on the analysis of redox-sensitive compounds in groundwater samples, redox processes ranged from strictly anoxic (methanogenesis) to oxic (oxygen reduction) within a short distance. The dependence of groundwater redox conditions on the distance from the source of contamination was observed. δ 13 C values of DIC ranged from - 15.83 to - 2.75‰, and the most positive values correspond to the zone under anaerobic and methanogenic conditions. Overall, results obtained provide clear evidence on the effects of natural attenuation processes-the activity of biodegradation mechanisms in field conditions.

Reconnaissance investigations of potential ground-water and sediment contamination at three former underground storage tank locations, Fort Jackson, South Carolina, 1994

USGS Publications Warehouse

Robertson, J.F.; Nagle, Douglas D.; Rhodes, Liesl C.

1994-01-01

Investigations to provide initial qualitative delineation of petroleum hydrocarbon contamination at three former underground storage tank locations at Fort Jackson, South Carolina, were made during March 1994. Ground-water and sediment samples were collected using direct-push technology and analyzed on-site with a gas chromatograph, which provided real-time, semi-quantitative data. In addition, ground-water and sediment samples were collected at selected sites for laboratory analyses to provide a confirmation of the on-site data. These analyses provided qualitative data on the lateral distri- bution of petroleum hydrocarbons. Petroleum hydrocarbons were detected by on-site analysis in ground-water samples from nine locations at Site 1062, suggesting the presence of a contaminant plume. Concentrations ranged from less than the minimum detection limit to 4,511 mg/L (micrograms per liter) for benzene, 15,594 mg/L for toluene, 16,501 mg/L for ethylbenzene, and 19,391 mg/L for total xylenes. Concentrations of Total Petroleum Hydrocarbons-Gasoline Range Organics ranged from 323 mg/L to 3,364 mg/L; Total Petroleum Hydrocarbons-Diesel Range Organics were not detected. Three samples from this site were analyzed for benzene, toluene, ethylbenzene, and total xylenes at a laboratory and results showed concentrations ranging from less than the minimum detection limit to 1,070 mg/L for benzene, 7,930 mg/L for toluene, 6,890 mg/L for ethylbenzene, and 1,524 mg/L for total xylenes. Petroleum hydro- carbons were detected by on-site analysis in only one sample at Site 2438. A concentration of 131,000 micrograms per kilogram Total Petroleum Hydrocarbons-Diesel Range Organics was detected in sample number GP-2-4-13.5. Petroleum hydrocarbons were detected by on-site analysis in only one ground-water sample from Site 2444. A concentration of 3,145 mg/L Total Petroleum Hydrocarbons-Gasoline Range Organics was detected at sampling location GP-3-2.

Total Petroleum Systems of the North Carpathian Province of Poland, Ukraine, Czech Republic, and Austria

USGS Publications Warehouse

Pawlewicz, Mark

2006-01-01

Three total petroleum systems were identified in the North Carpathian Province (4047) that includes parts of Poland, Ukraine, Austria, and the Czech Republic. They are the Isotopically Light Gas Total Petroleum System, the Mesozoic-Paleogene Composite Total Petroleum System, and the Paleozoic Composite Total Petroleum System. The Foreland Basin Assessment Unit of the Isotopically Light Gas Total Petroleum System is wholly contained within the shallow sedimentary rocks of Neogene molasse in the Carpathian foredeep. The biogenic gas is generated locally as the result of bacterial activity on dispersed organic matter. Migration is also believed to be local, and gas is believed to be trapped in shallow stratigraphic traps. The Mesozoic-Paleogene Composite Total Petroleum System, which includes the Deformed Belt Assessment Unit, is structurally complex, and source rocks, reservoirs, and seals are juxtaposed in such a way that a single stratigraphic section is insufficient to describe the geology. The Menilite Shale, an organic-rich rock widespread throughout the Carpathian region, is the main hydrocarbon source rock. Other Jurassic to Cretaceous formations also contribute to oil and gas in the overthrust zone in Poland and Ukraine but in smaller amounts, because those formations are more localized than the Menilite Shale. The Paleozoic Composite Total Petroleum System is defined on the basis of the suspected source rock for two oil or gas fields in western Poland. The Paleozoic Reservoirs Assessment Unit encompasses Devonian organic-rich shale believed to be a source of deep gas within the total petroleum system. East of this field is a Paleozoic oil accumulation whose source is uncertain; however, it possesses geochemical similarities to oil generated by Upper Carboniferous coals. The undiscovered resources in the North Carpathian Province are, at the mean, 4.61 trillion cubic feet of gas and 359 million barrels of oil. Many favorable parts of the province have been extensively explored for oil and gas. The lateral and vertical variability of the structure, the distribution and complex geologic nature of source rocks, and the depths of potential exploration targets, as well as the high degree of exploration, all indicate that future discoveries in this province are likely to be numerous but in small fields.

Antigenotoxic and free radical scavenging activities of extracts from Moricandia arvensis.

PubMed

Skandrani, I; Sghaier, M Ben; Neffati, A; Boubaker, J; Bouhlel, I; Kilani, S; Mahmoud, A; Ghedira, K; Chekir-Ghedira, L

2007-01-01

This study evaluates genotoxic and antigenotoxic effects of extracts from leaves of Moricandia arvensis, which are used in traditional cooking and medicines. Extracts showed no genotoxicity when tested with the SOS Chromotest using E. coli PQ37 and PQ35 strains, except for the total oligomers flavonoids enriched extract. Petroleum ether and methanol extracts are the most active in reducing nitrofurantoin genotoxicity, whereas methanol and total oligomers flavonoids enriched extracts showed the most important inhibitory effect of H2O2 genotoxicity. In addition, these two extracts showed important free radical scavenging activity toward the DPPH. radical, whereas the chloroform extract exhibited the highest value of TEAC against ABTS+. radical.

Total phenolic, antioxidant, antimicrobial activities and toxicity study of Gynotroches axillaris blume (Rhizophoraceae)

PubMed Central

Abed, Salam Ahmed; Sirat, Hasnah Mohd; Taher, Muhammad

2013-01-01

The antioxidant activity and the total phenolic content, as well as the influence of petroleum ether, chloroform and methanol extracts from the leaves of Gynotroches axillaris, on microorganisms were studied. The total phenolic contents were evaluated by using Folin-Ciocalteu reagent and the obtained values ranged from 70.0 to 620 mg GAE/g. The efficiency of antioxidation, which was identified through the scavenging of free radical DPPH, exhibited that the highest IC50 was in the methanolic extract (44.7 µg/mL) as compared to the standard ascorbic acid (25.83 µg/mL) and to standard BHT (17.2 µg/mL). In vitro antimicrobial activity of extracts was tested against Gram-negative bacteria, Gram-positive bacteria and fungi. Methanol extract showed activity in the range (225-900 μg/mL) with both types, while petroleum ether and chloroform extracts were only active with Bacillus subtilis. The three extracts strongly inhibited all fungi with activity 225-450 μg/mL. The toxicity test against brine shrimps indicated that all extracts were non-toxic with LC50 value more than 1000 µg/mL. The finding of this study supports the safety of these extracts to be used in medical treatments. PMID:26600731

Pannonian Basin Province, Central Europe (Province 4808) -Petroleum Geology, Total Petroleum Systems, and Petroleum Resource Assessment

USGS Publications Warehouse

Dolton, Gordon L.

2006-01-01

This report deals with the Pannonian Basin Province of Central Europe and summarizes the petroleum geology, which was the basis for assessment, and presents results of that assessment. The Pannonian Basin Province consists of a large compound extensional basin of Neogene age overlying Paleogene basins and interior elements of the greater Alpine foldbelt. Within it, six total petroleum systems (TPS) are defined and six assessment units established for estimation of undiscovered oil and gas resources. Other speculative TPSs were identified but not included for quantitative assessment within this study.

Geology and total petroleum systems of the West-Central Coastal province (7203), West Africa

USGS Publications Warehouse

Brownfield, Michael E.; Charpentier, Ronald R.

2006-01-01

The West-Central Coastal Province of the Sub-Saharan Africa Region consists of the coastal and offshore areas of Cameroon, Equatorial Guinea, Gabon, Democratic Republic of the Congo, Republic of the Congo, Angola (including the disputed Cabinda Province), and Namibia. The area stretches from the east edge of the Niger Delta south to the Walvis Ridge. The West-Central Coastal Province includes the Douala, Kribi-Campo, Rio Muni, Gabon, Congo, Kwanza, Benguela, and Namibe Basins, which together form the Aptian salt basin of equatorial west Africa. The area has had significant exploration for petroleum; more than 295 oil fields have been discovered since 1954. Since 1995, several giant oil fields have been discovered, especially in the deep-water area of the Congo Basin. Although many total petroleum systems may exist in the West-Central Coastal Province, only four major total petroleum systems have been defined. The area of the province north of the Congo Basin contains two total petroleum systems: the Melania-Gamba Total Petroleum System, consisting of Lower Cretaceous source and reservoir rocks, and the Azile-Senonian Total Petroleum System, consisting of Albian to Turonian source rocks and Cretaceous reservoir rocks. Two assessment units are defined in the West-Central Coastal Province north of the Congo Basin: the Gabon Subsalt and the Gabon Suprasalt Assessment Units. The Congo Basin contains the Congo Delta Composite Total Petroleum System, consisting of Lower Cretaceous to Tertiary source and reservoir rocks. The Central Congo Delta and Carbonate Platform and the Central Congo Turbidites Assessment Units are defined in the Congo Delta Composite Total Petroleum System. The area south of the Congo Basin contains the Cuanza Composite Total Petroleum System, consisting of Lower Cretaceous to Tertiary source and reservoir rocks. The Cuanza-Namibe Assessment Unit is defined in the Cuanza Composite Total Petroleum System. The U.S. Geological Survey (USGS) assessed the potential for undiscovered conventional oil and gas resources in this province as part of its World Petroleum Assessment 2000. The USGS estimated a mean of 29.7 billion barrels of undiscovered conventional oil, 88.0 trillion cubic feet of gas, and 4.2 billion barrels of natural gas liquids. Most of the hydrocarbon potential remains in the offshore waters of the province in the Central Congo Turbidites Assessment Unit. Large areas of the offshore parts of the Kwanza, Douala, Kribi-Campo, and Rio Muni Basins are underexplored, considering their size, and current exploration activity suggests that the basins have hydrocarbon potential. Since about 1995, the offshore part of the Congo Basin has become a major area for new field discoveries and for hydrocarbon exploration, and many deeper water areas in the basin have excellent hydrocarbon potential. Gas resources may be significant and accessible in areas where the zone of oil generation is relatively shallow.

Evaluation of a cleanser for petroleum-contaminated skin.

PubMed

Phieffer, Laura S; Banks, David M; Bosse, Michael J; Meyer, Martha H; Meyer, Ralph A; Smith, Kevin

2003-12-01

Extremity injuries contaminated with petroleum products pose clinical dilemmas. This project was designed to evaluate the efficacy of a dioctyl sulfosuccinate (DS) solution for cleansing petroleum-contaminated skin. One hundred Sprague-Dawley rats were subjected to a contamination protocol followed by a cleansing procedure. Four petroleum contaminants and five cleansing solutions were selected. The protocol consisted of shaving, initial punch biopsy, contamination, precleansing punch biopsy, standardized scrub protocol, and postcleansing punch biopsy. Biopsy samples were analyzed for petroleum residue using fluorometry. The 10% DS solution had the highest reduction of crude oil, grease, and tar: 99.6 +/- 0.4% (mean +/- SD) contaminant reduction for crude oil, 99.8 +/- 0.2% for grease, and 99.8 +/- 0.2% for tar. The other cleansers showed less efficacy (p < 0.05). Concentrated DS appears to be significantly more effective at cleaning petroleum products from skin than the commonly chosen surgical and commercial cleansers.

Bioaccumulation Potential of Contaminants from Bedded and Suspended Oakland Harbor Deepening Project Sediments to San Francisco Bay Flatfish and Bivalve Mollusks

DTIC Science & Technology

1994-08-01

Descriptive Statistics of Sediment Conventional Parameters and Statistical Comparisons of Oil and Grease and Total Petroleum Hydrocarbon Concentrations in...7000 Series, USEPA 1986, Bloom and Crecelius 1987). Oil and grease, total petroleum hydrocarbons . BPNL. Oil and grease were determined accord- ing to...infrared spectrometer. Total petroleum hydrocarbons were determined according to Method 418.1 (USEPA 1983). Sediment samples were extracted with freon

Assessment of Undiscovered Oil and Gas Resources of the Uinta-Piceance Province of Colorado and Utah, 2002

USGS Publications Warehouse

,

2002-01-01

The U.S. Geological Survey (USGS) recently completed an assessment of the undiscovered oil and gas potential of the UintaPiceance Province of northwestern Colorado and northeastern Utah (fig. 1). The assessment of the Uinta-Piceance Province is geology based and uses the Total Petroleum System concept. The geologic elements of Total Petroleum Systems include hydrocarbon source rocks (source rock maturation, hydrocarbon generation and migration), reservoir rocks (sequence stratigraphy, petrophysical properties), and hydrocarbon traps (trap formation and timing). Using this geologic framework, the USGS defined five Total Petroleum Systems and 20 Assessment Units within these Total Petroleum Systems, and quantitatively estimated the undiscovered oil and gas resources within each Assessment Unit (table 1).

Critical assessment of various techniques for the extraction of carotenoids and co-enzyme Q10 from the Thraustochytrid strain ONC-T18.

PubMed

Armenta, Roberto E; Burja, Adam; Radianingtyas, Helia; Barrow, Colin J

2006-12-27

A variety of techniques for extracting carotenoids from the marine Thraustochytrium sp. ONC-T18 was compared. Specifically, the organic solvents acetone, ethyl acetate, and petroleum ether were tested, along with direct and indirect ultrasonic assisted extraction (probe vs bath) methods. Techniques that used petroleum ether/acetone/water (15:75:10, v/v/v) with 3 h of agitation, or 5 min in an ultrasonic bath, produced the highest extraction yields of total carotenoids (29-30.5 microg g-1). Concentrations up to 11.5 microg g-1 of canthaxanthin and 17.5 microg g-1 of beta;-carotene were detected in extracts stored for 6 weeks. Astaxanthin and echinenone were also detected as minor compounds. Extracts with and without antioxidants showed similar carotenoid concentration profiles. However, total carotenoid concentrations were approximately 8% higher when antioxidants were used. Finally, an easy-to-perform and inexpensive method to detect co-enzymes in ONC-T18 was also developed using silica gel TLC plates. Five percent methanol in toluene as a mobile phase consistently eluted co-enzyme Q10 standards and could separate the co-enzyme fractions present in ONC-T18.

Total petroleum hydrocarbons and heavy metals in the surface sediments of Bohai Bay, China: long-term variations in pollution status and adverse biological risk.

PubMed

Zhou, Ran; Qin, Xuebo; Peng, Shitao; Deng, Shihuai

2014-06-15

Surface sediments collected from 2001 to 2011 were analyzed for total petroleum hydrocarbons (TPH) and five heavy metals. The sediment concentration ranges of TPH, Zn, Cu, Pb, Cd and Hg were 6.3-535 μg/g, 58-332 μg/g, 7.2-63 μg/g, 4.3-138 μg/g, 0-0.98μg/g, and 0.10-0.68 μg/g, respectively. These results met the highest marine sediment quality standards in China, indicating that the sediment was fairly clean. However, based on the effects range-median (ERM) quotient method, the calculated values for all of the sampling sites were higher than 0.10, suggesting that there was a potential adverse biological risk in Bohai Bay. According to the calculated results, the biological risk decreased from 2001 to 2007 and increased afterwards. High-risk sites were mainly distributed along the coast. This study suggests that anthropogenic influences might be responsible for the potential risk of adverse biological effects from TPH and heavy metals in Bohai Bay. Copyright © 2014 Elsevier Ltd. All rights reserved.

Hematologic values of the endangered San Joaquin kit fox, Vulpes macrotis mutica

DOE Office of Scientific and Technical Information (OSTI.GOV)

McCue, P.M.; O'Farrell, T.P.

1986-01-01

Between 1981 and 1982 a total of 102 blood samples was collected from 91 San Joaquin kit foxes, Vulpes macrotis mutica, won the US Department of Energy's Naval Petroleum Reserve No. 1 (Elk Hills), in western Kern County, California. The goal of the study was to establish normal blood parameters for this endangered species and to determine whether changes in them could be used to assess the possible effects of petroleum developments on foxes. Adult foxes had the following average hematological characteristics: RBC, 8.4 x 10/sup 6/ cells/..mu..l; Hb, 14.9 g/dl; PCV, 46.9%; MCV, 56.4 fl; MCH, 18.2 pg; MCHC,more » 32.0 g/dl; and WBC, 6900/..mu..l. None of the parameters differed significantly between the sexes. RBC, Hb, PCV, MCV, and MCHC varied as a function of age for puppies between three and six months of age. The highest values of MCV and MCH were obtained in summer, 1982, and the highest value of MCHC was obtained in winter, 1981-1982. These were the only parameters that appeared to change with season. None of the blood parameters appeared to be affected by petroleum developments. Hematological data for kit foxes, coyotes, and wolves confirmed a previously published observation that within mammalian families RBC is inversely correlated with body weight, and that MCV is directly correlated with body weight. It was speculated that it was an adaptive advantage for kit foxes having a high weight-specific metabolic rate to have evolved a high RBC and low MCV, allowing increased oxygen transport and exchange, while PCV was maintained relatively constant, avoiding hemoconcentration and increased viscosity of blood. 33 refs., 1 fig., 6 tabs.« less

QUANTIFICATION AND INTERPRETATION OF TOTAL PETROLEUM HYDROCARBONS IN SEDIMENT SAMPLES BY A GC/MS METHOD AND COMPARISON WITH EPA 418.1 AND A RAPID FIELD METHOD

EPA Science Inventory

ABSTRACT: Total Petroleum hydrocarbons (TPH) as a lumped parameter can be easily and rapidly measured or monitored. Despite interpretational problems, it has become an accepted regulatory benchmark used widely to evaluate the extent of petroleum product contamination. Three cu...

Preparation of activated petroleum coke for removal of naphthenic acids model compounds: Box-Behnken design optimization of KOH activation process.

PubMed

Niasar, Hojatallah Seyedy; Li, Hanning; Das, Sreejon; Kasanneni, Tirumala Venkateswara Rao; Ray, Madhumita B; Xu, Chunbao Charles

2018-04-01

This study employed Box-Behnken design and response surface methodology to optimize activation parameters for the production of activated petroleum coke (APC) adsorbent from petroleum coke (PC) to achieve highest adsorption capacity for three model naphthenic acids. Activated petroleum coke (APC) adsorbent with a BET surface area of 1726 m 2 /g and total pore volume of 0.85 cc/g was produced at the optimum activation conditions (KOH/coke mass ratio) of 3.0, activation temperature 790 °C, and activation time 3.47 h). Effects of the activation parameters on the adsorption pefromances (adsortion capaciy and kinetics) were investigated. With the APC obtained at the optimum activation condition, the maximum adsorption capacity of 451, 362, and 320 (mg/g) was achieved for 2-naphthoic acid, diphenylacetic acid and cyclohexanepentanoic acid (CP), respectively. Although, generally APC adsorbents with a higher specific surface area and pore volume provide better adsorption capacity, the textural properties (surface areas and pore volume) are not the only parameters determining the APC adsorbents' adsorption capacity. Other parameters such as surface functionalities play effective roles on the adsorption capacity of the produced APC adsorbents for NAs. The KOH activation process, in particular the acid washing step, distinctly reduced the sulfur and metals contents in the raw PC, decreasing the leaching potential of metals from APC adsorbents during adsorption. Copyright © 2018 Elsevier Ltd. All rights reserved.

Chapter 5. Assessment of undiscovered conventional oil and gas resources-Lower Cretaceous Travis Peak and Hosston formations, Jurassic Smackover interior salt basins total petroleum system, in the East Texas basin and Louisiana-Mississippi salt basins provinces.

USGS Publications Warehouse

Dyman, T.S.; Condon, S.M.

2006-01-01

The petroleum assessment of the Travis Peak and Hosston Formations was conducted by using a total petroleum system model. A total petroleum system includes all of the important elements of a hydrocarbon fluid system needed to develop oil and gas accumulations, including source and reservoir rocks, hydrocarbon generation, migration, traps and seals, and undiscovered accumulations. A total petroleum system is mappable and may include one or more assessment units. For each assessment unit, reservoir rocks contain similar geology, exploration characteristics, and risk. The Jurassic Smackover Interior Salt Basins Total Petroleum System is defined for this assessment to include (1) Upper Jurassic Smackover carbonates and calcareous shales and organic-rich shales of the Upper Jurassic Bossier Shale of the Cotton Valley Group and (2) Lower Cretaceous Travis Peak and Hosston Formations. The Jurassic Smackover Interior Salt Basins Total Petroleum System includes three conventional Travis Peak-Hosston assessment units: Travis Peak-Hosston Gas and Oil (AU 50490205), Travis Peak-Hosston Updip Oil (AU 50490206), and Travis Peak-Hosston Hypothetical Updip Oil (AU 50490207). A fourth assessment unit, the Hosston Hypothetical Slope-Basin Gas Assessment Unit, was named and numbered (AU 50490208) but not geologically defined or quantitatively assessed owing to a lack of data. Together, assessment units 50490205 to 50490207 are estimated to contain a mean undiscovered conventional resource of 29 million barrels of oil, 1,136 billion cubic feet of gas, and 22 million barrels of natural gas liquids.

Undiscovered oil and gas resources of Lower Silurian Qusaiba-Paleozoic total petroleum systems, Arabian Peninsula

USGS Publications Warehouse

Ahlbrandt, T.S.; Pollastro, R.M.; Schenk, C.J.

2002-01-01

The U.S. Geological Survey (USGS) recently completed an assessment of the undiscovered conventional oil and gas potential of 128 of the world’s petroleum provinces (U.S. Geological Survey World Energy Assessment Team, 2000). In each province, the USGS defined Total Petroleum Systems, and Assessment Units in each Total Petroleum System, and then quantitatively estimated the undiscovered conventional oil and gas resources. Of the eight global regions studied by the USGS, the Arabian Peninsula portion of the Middle East region was estimated to contain the greatest volumes of undiscovered oil and gas. The Lower Silurian Qusaiba Member of the Qalibah Formation is the source rock for some of the most important Total Petroleum Systems of the Middle East region. For example, the sources of the gas in the supergiant North field of Qatar and Iran and recent giant light oil discoveries in central Saudi Arabia were largely organic-rich, Qusaiba marine mudstones.

Saudi Arabia Country Analysis Brief

EIA Publications

2014-01-01

Saudi Arabia is the world's largest holder of crude oil proved reserves and was the largest exporter of total petroleum liquids in 2013. In 2013, Saudi Arabia was the world's second-largest petroleum liquids producer behind the United States and was the world's second-largest crude oil producer behind Russia. Saudi Arabia's economy remains heavily dependent on petroleum. Petroleum exports accounted for 85% of total Saudi export revenues in 2013, according to the Organization of the Petroleum Exporting Countries (OPEC)'s Annual Statistical Bulletin 2014. With the largest oil projects nearing completion, Saudi Arabia is expanding its natural gas, refining, petrochemicals, and electric power industries. Saudi Arabia's oil and natural gas operations are dominated by Saudi Aramco, the national oil and gas company and the world's largest oil company in terms of production. Saudi Arabia's Ministry of Petroleum and Mineral Resources and the Supreme Council for Petroleum and Minerals have oversight of the oil and natural gas sector and Saudi Aramco.

Concentration, composition and sources of PAHs in the coastal sediments of the exclusive economic zone (EEZ) of Qatar, Arabian Gulf.

PubMed

Soliman, Y S; Al Ansari, E M S; Wade, T L

2014-08-30

Surface sediments were collected from sixteen locations in order to assess levels and sources of polycyclic aromatic hydrocarbons (PAHs) in sediments of Qatar exclusive economic zone (EEZ). Samples were analyzed for 16 parent PAHs, 18 alkyl homologs and for dibenzothiophenes. Total PAHs concentration (∑PAHs) ranged from 2.6 ng g(-1) to 1025 ng g(-1). The highest PAHs concentrations were in sediments in and adjacent to harbors. Alkylated PAHs predominated most of the sampling locations reaching up to 80% in offshore locations. Parent PAHs and parent high molecular weight PAHs dominated location adjacent to industrial activities and urban areas. The origin of PAHs sources to the sediments was elucidated using ternary plot, indices, and molecular ratios of specific compounds such as (Ant/Phe+Ant), (Flt/Flt+Pyr). PAHs inputs to most coastal sites consisted of mixture of petroleum and combustion derived sources. However, inputs to the offshore sediments were mainly of petroleum origin. Copyright © 2014 Elsevier Ltd. All rights reserved.

Biological treatment process for removing petroleum hydrocarbons from oil field produced waters

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tellez, G.; Khandan, N.

1995-12-31

The feasibility of removing petroleum hydrocarbons from oil fields produced waters using biological treatment was evaluated under laboratory and field conditions. Based on previous laboratory studies, a field-scale prototype system was designed and operated over a period of four months. Two different sources of produced waters were tested in this field study under various continuous flow rates ranging from 375 1/D to 1,800 1/D. One source of produced water was an open storage pit; the other, a closed storage tank. The TDS concentrations of these sources exceeded 50,000 mg/l; total n-alkanes exceeded 100 mg/l; total petroleum hydrocarbons exceeded 125 mg/l;more » and total BTEX exceeded 3 mg/l. Removals of total n-alkanes, total petroleum hydrocarbons, and BTEX remained consistently high over 99%. During these tests, the energy costs averaged $0.20/bbl at 12 bbl/D.« less

Phase 1 remediation of jet fuel contaminated soil and groundwater at JFK International Airport using dual phase extraction and bioventing

DOE Office of Scientific and Technical Information (OSTI.GOV)

Roth, R.; Bianco, P. Rizzo, M.; Pressly, N.

1995-12-31

Soil and groundwater contaminated with jet fuel at Terminal One of the JFK International Airport in New York have been remediated using dual phase extraction (DPE) and bioventing. Two areas were remediated using 51 DPE wells and 20 air sparging/air injection wells. The total area remediated by the DPE wells is estimated to be 4.8 acres. Groundwater was extracted to recover nonaqueous phase and aqueous phase jet fuel from the shallow aquifer and treated above ground by the following processes; oil/water separation, iron-oxidation, flocculation, sedimentation, filtration, air stripping and liquid-phase granular activated carbon (LPGAC) adsorption. The extracted vapors were treatedmore » by vapor-phase granular activated carbon (VPGAC) adsorption in one area, and catalytic oxidation and VPGAC adsorption in another area. After 6 months of remediation, approximately 5,490 lbs. of volatile organic compounds (VOCs) were removed by soil vapor extraction (SVE), 109,650 lbs. of petroleum hydrocarbons were removed from the extracted groundwater, and 60,550 lbs. of petroleum hydrocarbons were biologically oxidized by subsurface microorganisms. Of these three mechanisms, the rate of petroleum hydrocarbon removal was the highest for biological oxidation in one area and by groundwater extraction in another area.« less

Surfactants selectively reallocated the bacterial distribution in soil bioelectrochemical remediation of petroleum hydrocarbons.

PubMed

Li, Xiaojing; Zhao, Qian; Wang, Xin; Li, Yongtao; Zhou, Qixing

2018-02-15

Soil contaminated by aged petroleum hydrocarbons is faced with scarcity of electron acceptors, low activity of functional microbes and inefficient electron transfer, which hinder the bioremediation application. The soil microbial fuel cell (MFC) simultaneously solves these problems with bioelectricity production. In this study, five types of surfactants were introduced to enhance the bioavailability of aged petroleum hydrocarbon in soils. The ampholytic surfactant (lecithos) was optimal due to the highest bioelectricity generation (0.321Cd -1 g -1 ) and promoted hydrocarbon degradation (328%), while the nonionic (glyceryl monostearate) and cationic (cetyltrimethylammonium bromide) surfactants were inefficient. The surfactants induced a special microbial enrichment affiliated with Proteobacteria, Firmicutes, Bacteroidetes, Actinobacteria, Chloroflexi, Planctomycetes and Acidobacteria (93%-99% of total) in soil MFCs. The anionic surfactant (sodium dodecyl sulfate) exhibited the strongest selectivity, and α-proteobacteria and γ-proteobacteria abundances decreased while Clostridia increased, much like the result obtained with the biosurfactant β-cyclodextrin. Furthermore, Bacillus abundance was increased in connected soil MFCs, except addition of lecithos in which Clostridium increased to 14.88% from 3.61% in the control. The high correlations among Bacillus, Phenylobacterium, Solibacillus (0.9162-0.9577) and among Alcaligenes, Dysgonomonas, Sedimentibacter (0.9538-0.9966) indicated a metabolic network of microorganisms in the soil bioelectrochemical remediation system. Copyright © 2017 Elsevier B.V. All rights reserved.

Jurassic-Cretaceous Composite Total Petroleum System and Geologic Assessment of Oil and Gas Resources of the North Cuba Basin, Cuba

USGS Publications Warehouse

,

2008-01-01

The purpose of the U.S. Geological Survey's (USGS) World Oil and Gas Assessment is to develop geologically based hypotheses regarding the potential for additions to oil and gas reserves in priority areas of the world. The U.S. Geological Survey (USGS) completed an assessment of the undiscovered oil and gas potential of the North Cuba Basin. The assessment is based on the geologic elements of the total petroleum system (TPS) defined in the province, including petroleum source rocks (source-rock maturation, generation, and migration), reservoir rocks (sequence stratigraphy and petrophysical properties), and petroleum traps (Trap formation and timing). Using this geologic framework, the USGS defined a Jurassic-Cretaceous Total Petroleum System in the North Cuba Basin Province. Within this TPS, three assessment units were defined and assessed for undiscovered oil and gas resources.

Study of variation grain size in desulfurization process of calcined petroleum coke

NASA Astrophysics Data System (ADS)

Pintowantoro, Sungging; Setiawan, Muhammad Arif; Abdul, Fakhreza

2018-04-01

Indonesia is a country with abundant natural resources, such as mineral mining and petroleum. In petroleum processing, crude oil can be processed into a source of fuel energy such as gasoline, diesel, oil, petroleum coke, and others. One of crude oil potentials in Indonesia is petroleum coke. Petroleum coke is a product from oil refining process. Sulfur reducing process in calcined petroleum cokes can be done by desulfurization process. The industries which have potential to become petroleum coke processing consumers are industries of aluminum smelting (anode, graphite block, carbon mortar), iron riser, calcined coke, foundry coke, etc. Sulfur reducing process in calcined petroleum coke can be done by thermal desulfurization process with alkaline substance NaOH. Desulfurization of petroleum coke process can be done in two ways, which are thermal desulfurization and hydrodesulphurization. This study aims to determine the effect of various grain size on sulfur, carbon, and chemical bond which contained by calcined petroleum coke. The raw material use calcined petroleum coke with 0.653% sulfur content. The grain size that used in this research is 50 mesh, then varied to 20 mesh and 100 mesh for each desulfurization process. Desulfurization are tested by ICP, UV-VIS, and FTIR to determine levels of sulfur, carbon, chemical bonding and sulfur dissolved water which contained in the residual washing of calcined petroleum coke. From various grain size that mentioned before, the optimal value is on 100 mesh grain size, where the sulfur content in petroleum coke is 0.24% and carbon content reaches the highest level of 97.8%. Meanwhile for grain size 100 mesh in the desulfurization process is enough to break the chemical bonds of organic sulfur in petroleum coke.

Antibacterial substances from marine algae isolated from Jeddah coast of Red sea, Saudi Arabia

PubMed Central

Al-Saif, Sarah Saleh Abdu-llah; Abdel-Raouf, Nevein; El-Wazanani, Hend A.; Aref, Ibrahim A.

2013-01-01

Marine algae are known to produce a wide variety of bioactive secondary metabolites and several compounds have been derived from them for prospective development of novel drugs by the pharmaceutical industries. However algae of the Red sea have not been adequately explored for their potential as a source of bioactive substances. In this context Ulva reticulata, Caulerpa occidentalis, Cladophora socialis, Dictyota ciliolata, and Gracilaria dendroides isolated from Red sea coastal waters of Jeddah, Saudi Arabia, were evaluated for their potential for bioactivity. Extracts of the algae selected for the study were prepared using ethanol, chloroform, petroleum ether and water, and assayed for antibacterial activity against Escherichia coli ATCC 25322, Pseudomonas aeruginosa ATCC 27853, Stapylococcus aureus ATCC 29213, and Enterococcus faecalis ATCC 29212. It was found that chloroform was most effective followed by ethanol, petroleum ether and water for the preparation of algal extract with significant antibacterial activities, respectively. Results also indicated that the extracts of red alga G. dendroides were more efficient against the tested bacterial strains followed by green alga U. reticulata, and brown algae D. ciliolata. Chemical analyses showed that G. dendroides recorded the highest percentages of the total fats and total proteins, followed by U. reticulata, and D. ciliolate. Among the bioflavonoids determined Rutin, Quercetin and Kaempherol were present in high percentages in G. dendroides, U. reticulata, and D. ciliolate. Estimation of saturated and unsaturated fatty acids revealed that palmitic acid was present in highest percentage in all the algal species analyzed. Amino acid analyses indicated the presence of free amino acids in moderate contents in all the species of algae. The results indicated scope for utilizing these algae as a source of antibacterial substances. PMID:24596500

Dynamic monitoring of water petroleum substance using HJ-1/CCD remote sensing data

NASA Astrophysics Data System (ADS)

Huang, Miaofen; Xing, Xufeng; Zhao, Zulong; Li, Zhanqiang

2014-03-01

The experiment data used in this paper include CDOM(Chromophoric dissolved organic matter) absorption coefficient, water apparent optical properties and petroleum pollution concentration, which were obtained in May 2008, August 2009 and June 2010 respectively at Liaohe Oilfield in Panjin city, Liaoning province of China. A model between CDOM absorption coefficient and petroleum pollution concentration was developed, and then was applied to eight HJ-1CCD remote sense images obtained from 2009 to 2011, to produce multi-period temporal and spatial distribution maps of petroleum concentration in costal waters. Based on these thematic maps, the dynamic monitoring of petroleum pollution concentration distribution was done. The results showed that (1)There was a decreasing trend of petroleum concentration from costal waters to open sea, which manifest itself as an approximately zonal distribution;(2) due to low precipitation in May and June every year, the concentration of petroleum keeps in a relatively high value state; (3) in September, the concentration of petroleum decreases dramatically as pre increases, most of the area below 0.29 mg/L; (4) compared with that in the same period, the concentration of petroleum in April 2010 is apparently higher than in April 2011, and among the images in September from 2009 to 2011,the highest concentration of petroleum appears in 2010, and the lowest in 2009.

Identifying the Optimal Water-Occluding Earplugs: A Scientific Simulation Study.

PubMed

Kovoor, Joshua; Al Hussaini, Ali; Backhouse, Steven

2016-12-01

Numerous types of water-occluding earplugs are available as a means of preventing infection in patients with external and middle ear disease. However, little is known about the comparative efficacies of these earplugs with prolonged water exposure. In this study, we assessed the water impermeability of various earplug materials to prolonged water exposure. Nine earplugs were tested: cotton wool mixed with petroleum jelly, cotton wool externally coated with petroleum jelly, Blu-Tack, foam earplugs, silicone putty, silicone earplugs, flanged earplugs, and hard and soft silicone custom-moulds. Precision-engineered cups were filled with 30 mL water and sealed with lids that contained a 10 mm diameter hole to simulate the ear canal. The aperture was occluded with different earplugs, and the cup was inverted. Computer software was used to record the water loss to the nearest 10 milligrams 720 times over a three-hour period. The test was repeated five times for each material. The water permeability onset, rate, and total amount of water loss varied markedly between the materials; cotton wool mixed with petroleum jelly demonstrated the fastest onset of leak and the highest rate of water loss (p < 0.00001), as well as the largest amount of cumulative water loss (p = 0.00213). The soft silicone custom-mould plugs, hard silicone custom-mould plugs, foam plugs, and silicone putty demonstrated no leaks. This study demonstrates a wide range of water permeabilities of commonly used ear-occluding materials during prolonged water exposure. We found that the generally suggested regimen of cotton wool mixed with petroleum jelly may be inefficacious for substantial periods of water exposure.

The use of sensory perception indicators for improving the characterization and modelling of total petroleum hydrocarbon (TPH) grade in soils.

PubMed

Roxo, Sónia; de Almeida, José António; Matias, Filipa Vieira; Mata-Lima, Herlander; Barbosa, Sofia

2016-03-01

This paper proposes a multistep approach for creating a 3D stochastic model of total petroleum hydrocarbon (TPH) grade in potentially polluted soils of a deactivated oil storage site by using chemical analysis results as primary or hard data and classes of sensory perception variables as secondary or soft data. First, the statistical relationship between the sensory perception variables (e.g. colour, odour and oil-water reaction) and TPH grade is analysed, after which the sensory perception variable exhibiting the highest correlation is selected (oil-water reaction in this case study). The probabilities of cells belonging to classes of oil-water reaction are then estimated for the entire soil volume using indicator kriging. Next, local histograms of TPH grade for each grid cell are computed, combining the probabilities of belonging to a specific sensory perception indicator class and conditional to the simulated values of TPH grade. Finally, simulated images of TPH grade are generated by using the P-field simulation algorithm, utilising the local histograms of TPH grade for each grid cell. The set of simulated TPH values allows several calculations to be performed, such as average values, local uncertainties and the probability of the TPH grade of the soil exceeding a specific threshold value.

Carboniferous-Rotliegend total petroleum system; description and assessment results summary

USGS Publications Warehouse

Gautier, Donald L.

2003-01-01

The Anglo-Dutch Basin and the Northwest German Basin are two of the 76 priority basins assessed by the U.S. Geological Survey World Energy Project. The basins were assessed together because most of the resources occur within a single petroleum system (the Carboniferous-Rotliegend Total Petroleum System) that transcends the combined Anglo-Dutch Basin and Northwest German Basin boundary. The juxtaposition of thermally mature coals and carbonaceous shales of the Carboniferous Coal Measures (source rock), sandstones of the Rotliegend sedimentary systems (reservoir rock), and the Zechstein evaporites (seal) define the total petroleum system (TPS). Three assessment units were defined, based upon technological and geographic (rather than geological) criteria, that subdivide the Carboniferous-Rotliegend Total Petroleum System. These assessment units are (1) the Southern Permian Basin-Offshore Europe Assessment Unit, (2) the Southern Permian Basin Onshore Europe Assessment Unit, and (3) the Southern Permian Basin Onshore United Kingdom Assessment Unit. Although the Carboniferous-Rotliegend Total Petroleum System is one of the most intensely explored volumes of rock in the world, potential remains for undiscovered resources. Undiscovered conventional resources associated with the TPS range from 22 to 184 million barrels of oil, and from 3.6 to 14.9 trillion cubic feet of natural gas. Of these amounts, approximately 62 million barrels of oil and 13 trillion cubic feet of gas are expected in offshore areas, and 26 million barrels of oil and 1.9 trillion cubic feet of gas are predicted in onshore areas.

Solubility of crude oil in methane as a function of pressure and temperature

USGS Publications Warehouse

Price, L.C.; Wenger, L.M.; Ging, T.; Blount, C.W.

1983-01-01

The solubility of a 44?? API (0.806 sp. gr.) whole crude oil has been measured in methane with water present at temperatures of 50 to 250??C and pressures of 740 to 14,852 psi, as have the solubilities of two high molecular weight petroleum distillation fractions at temperatures of 50 to 250??C and pressures of 4482 to 25,266 psi. Both increases in pressure and temperature increase the solubility of crude oil and petroleum distillation fractions in methane, the effect of pressure being greater than that of temperature. Unexpectedly high solubility levels (0.5-1.5 grams of oil per liter of methane-at laboratory temperature and pressure) were measured at moderate conditions (50-200??C and 5076-14504 psi). Similar results were found for the petroleum distillation fractions, one of which was the highest molecular weight material of petroleum (material boiling above 266??C at 6 microns pressure). Unexpectedly mild conditions (100??C and 15,200 psi; 200??C and 7513 psi) resulted in cosolubility of crude oil and methane. Under these conditions, samples of the gas-rich phase gave solubility values of 4 to 5 g/l, or greater. Qualitative analyses of the crude-oil solute samples showed that at low pressure and temperature equilibration conditions, the solute condensate would be enriched in C5-C15 range hydrocarbons and in saturated hydrocarbons in the C15+ fraction. With increases in temperature and especially pressure, these tendencies were reversed, and the solute condensate became identical to the starting crude oil. The data of this study, compared to that of previous studies, shows that methane, with water present, has a much greater carrying capacity for crude oil than in dry systems. The presence of water also drastically lowers the temperature and pressure conditions required for cosolubility. The data of this and/or previous studies demonstrate that the addition of carbon dioxide, ethane, propane, or butane to methane also has a strong positive effect on crude oil solubility, as does the presence of fine grained rocks. The n-paraffin distributions (as well as the overall composition) of the solute condensates are controlled by the temperature and pressure of solution and exsolution, as well as by the composition of the original starting material. It appears quite possible that primary migration by gaseous solution could 'strip' a source rock of crude-oil like components leaving behind a bitumen totally unlike the migrated crude oil. The data of this study demonstrate previous criticisms of primary petroleum migration by gas solution are invalid; that primary migration by gaseous solution cannot occur because methane cannot dissolve sufficient volumes of crude oil or cannot dissolve the highest molecular weight components of petroleum (tars and asphaltenes). ?? 1983.

Total Petroleum Systems and Geologic Assessment of Oil and Gas Resources in the Powder River Basin Province, Wyoming and Montana

USGS Publications Warehouse

Anna, L.O.

2009-01-01

The U.S. Geological Survey completed an assessment of the undiscovered oil and gas potential of the Powder River Basin in 2006. The assessment of undiscovered oil and gas used the total petroleum system concept, which includes mapping the distribution of potential source rocks and known petroleum accumulations and determining the timing of petroleum generation and migration. Geologically based, it focuses on source and reservoir rock stratigraphy, timing of tectonic events and the configuration of resulting structures, formation of traps and seals, and burial history modeling. The total petroleum system is subdivided into assessment units based on similar geologic characteristics and accumulation and petroleum type. In chapter 1 of this report, five total petroleum systems, eight conventional assessment units, and three continuous assessment units were defined and the undiscovered oil and gas resources within each assessment unit quantitatively estimated. Chapter 2 describes data used in support of the process being applied by the U.S. Geological Survey (USGS) National Oil and Gas Assessment (NOGA) project. Digital tabular data used in this report and archival data that permit the user to perform further analyses are available elsewhere on this CD-ROM. Computers and software may import the data without transcription from the Portable Document Format files (.pdf files) of the text by the reader. Because of the number and variety of platforms and software available, graphical images are provided as .pdf files and tabular data are provided in a raw form as tab-delimited text files (.tab files).

Ambient PM2.5-bound polycyclic aromatic hydrocarbons (PAHs) in Changhua County, central Taiwan: Seasonal variation, source apportionment and cancer risk assessment.

PubMed

Chen, Yu-Cheng; Chiang, Hung-Che; Hsu, Chin-Yu; Yang, Tzu-Ting; Lin, Tzu-Yu; Chen, Mu-Jean; Chen, Nai-Tzu; Wu, Yuh-Shen

2016-11-01

This study investigates PM 2.5 -bound PAHs for rural sites (Dacheng and Fangyuan) positioned close to heavy air-polluting industries in Changhua County, central Taiwan. A total of 113 PM 2.5 samples with 22 PAHs collected from 2014 to 2015 were analyzed, and Positive Matrix Factorization (PMF) and diagnostic ratios of PAHs were applied to quantify potential PAH sources. The influences of local and regional sources were also explored using the conditional probability function (CPF) and potential source contribution function (PSCF) with PMF-modeled results, respectively. Annual mean concentrations of total PAHs were 2.91 ± 1.34 and 3.04 ± 1.40 ng/m 3 for Dacheng and Fangyuan, respectively, and their corresponding BaP eq were measured at 0.534 ± 0.255 and 0.563 ± 0.273 ng/m 3 in concentration. Seasonal variations with higher PAHs found for the winter than for the spring and summer were observed for both sites. The lifetime excess cancer risk (ECR) from inhalation exposure to PAHs was recorded as 4.7 × 10 -5 overall. Potential sources of PM 2.5 -bound PAHs include unburned petroleum and traffic emissions (42%), steel industry and coal combustion (31%), and petroleum and oil burning (27%), and unburned petroleum and traffic emission could contribute the highest ECR (2.4 × 10 -5 ). The CPF results show that directional apportionment patterns were consistent with the actual locations of local PAH sources. The PSCF results indicate that mainly northeastern regions of China have contributed elevated PM 2.5 -bound PAHs from long-range transports. Copyright © 2016 Elsevier Ltd. All rights reserved.

Discrimination of petroleum fluorescence spectra.

PubMed

Stelmaszewski, Adam

2007-01-01

This paper presents studies of the total spectra (fluorescence-excitation matrix) of petroleum with regard to the utilization of fluorescence for determining petroleum pollutants. Thorough testing of one group, comprising almost forty lubricating oils in the form of their hexane solutions, points out their discrimination.

Proceedings of a Seminar on Attaining Water Quality Goals through Water Management Procedures, 17-18 February 1982, Dallas, Texas,

DTIC Science & Technology

1982-02-01

slightly above the level of detection. In both projects low-level accumulation of petroleum hydrocarbons was observed. Because of the complex nature of... petroleum hydrocarbons , PCB, total DDT, Cd and lig in test and control organisms surviving a 10-day, solid phlase bioassay for project A. Organisms...of petroleum hydrocarbons , PCB, total DDT, Cd and Hig in test and control organisms surviving a 10-day solid phase bioassay for project B. Organisms

Lessons Learned Using Fractions to Assess Risk at Petroleum Release Sites

DTIC Science & Technology

2004-04-01

Jet Fuel Bioavailability Hydrocarbon fractions Total Petroleum Hydrocarbons Weathered petroleum Sequestration 16. SECURITY CLASSIFICATION OF: 17...requirements at sites that were contaminated with petroleum products such as gasoline, diesel fuel , jet fuel , heating oil, lubricants and used motor oils...December 2002. Four of the demonstration sites were contaminated with jet fuel (i.e., JP-4, JP-5 or JP-8). The Misawa Air Base site was contaminated with

40 CFR 60.111a - Definitions.

Code of Federal Regulations, 2011 CFR

2011-07-01

... PERFORMANCE FOR NEW STATIONARY SOURCES Standards of Performance for Storage Vessels for Petroleum Liquids for..., reservoir, or container used for the storage of petroleum liquids, but does not include: (1) Pressure... tanks if the total volume of petroleum liquids added to and taken from a tank annually does not exceed...

40 CFR 60.111a - Definitions.

Code of Federal Regulations, 2014 CFR

2014-07-01

... PERFORMANCE FOR NEW STATIONARY SOURCES Standards of Performance for Storage Vessels for Petroleum Liquids for..., reservoir, or container used for the storage of petroleum liquids, but does not include: (1) Pressure... tanks if the total volume of petroleum liquids added to and taken from a tank annually does not exceed...

40 CFR 60.111a - Definitions.

Code of Federal Regulations, 2012 CFR

2012-07-01

... PERFORMANCE FOR NEW STATIONARY SOURCES Standards of Performance for Storage Vessels for Petroleum Liquids for..., reservoir, or container used for the storage of petroleum liquids, but does not include: (1) Pressure... tanks if the total volume of petroleum liquids added to and taken from a tank annually does not exceed...

40 CFR 60.111a - Definitions.

Code of Federal Regulations, 2013 CFR

2013-07-01

... PERFORMANCE FOR NEW STATIONARY SOURCES Standards of Performance for Storage Vessels for Petroleum Liquids for..., reservoir, or container used for the storage of petroleum liquids, but does not include: (1) Pressure... tanks if the total volume of petroleum liquids added to and taken from a tank annually does not exceed...

40 CFR 60.111a - Definitions.

Code of Federal Regulations, 2010 CFR

2010-07-01

... PERFORMANCE FOR NEW STATIONARY SOURCES Standards of Performance for Storage Vessels for Petroleum Liquids for..., reservoir, or container used for the storage of petroleum liquids, but does not include: (1) Pressure... tanks if the total volume of petroleum liquids added to and taken from a tank annually does not exceed...

Assessment of undiscovered conventional oil and gas resources of the Western Canada Sedimentary Basin, Canada, 2012

USGS Publications Warehouse

Higley, Debra K.

2013-01-01

The U.S. Geological Survey recently completed a geoscience-based assessment of undiscovered oil and gas resources of provinces within the Western Canada Sedimentary Basin. The Western Canada Sedimentary Basin primarily comprises the (1) Alberta Basin Province of Alberta, eastern British Columbia, and the southwestern Northwest Territories; (2) the Williston Basin Province of Saskatchewan, southeastern Alberta, and southern Manitoba; and (3) the Rocky Mountain Deformed Belt Province of western Alberta and eastern British Columbia. This report is part of the U.S. Geological Survey World Petroleum Resources Project assessment of priority geologic provinces of the world. The assessment was based on geoscience elements that define a total petroleum system (TPS) and associated assessment unit(s). These elements include petroleum source rocks (geochemical properties and petroleum generation, migration, and accumulation), reservoir description (reservoir presence, type, and quality), and petroleum traps (trap and seal types, and timing of trap and seal formation relative to petroleum migration). Using this framework, the Elk Point-Woodbend Composite TPS, Exshaw-Fernie-Mannville Composite TPS, and Middle through Upper Cretaceous Composite TPS were defined, and four conventional assessment units within the total petroleum systems were quantitatively assessed for undiscovered resources in the Western Canada Sedimentary Basin.

Public offerings of securities by petroleum industry: methods and costs of raising capital

DOE Office of Scientific and Technical Information (OSTI.GOV)

Siemon, D.

1978-01-01

This study examines public securities offerings by the petroleum industry and the flotation costs associated with raising capital through offerings to the public. Descriptive material is presented on an aggregate basis for the industry and also by selected company characteristics. Data were obtained from the Securities and Exchange Commission's records of registration statements for public offerings and include all public offerings registered with the SEC during the period January 1970 through October 1975. The petroleum industry issued 101 debt offerings and 1058 equity offerings during the time period. The total number of offerings for all industries was estimated to bemore » 20,000, so the petroleum industry accounted for roughly 5% of the total volume.« less

An assessment of oil pollution in the coastal zone of patagonia, Argentina.

PubMed

Commendatore, Marta Graciela; Esteves, José Luis

2007-11-01

The Patagonian coast is considered a relatively pristine environment. However, studies conducted along coastal Patagonia have showed hydrocarbon pollution mostly concentrated at ports that have fishing, oil loading, general merchant, and/or tourist activities. A high value of total aliphatic hydrocarbons (TAH) was found at the Rawson fishing port (741 microg/g dw). In other ports with and without petroleum-related activities, hydrocarbon values were approximately 100 microg/g dw. The highest values for TAH and total aromatic hydrocarbons (TArH) were found in Faro Aristizábal, north of San Jorge gulf (1304 and 737 microg/g dw, respectively). This is very likely the result of petroleum-related activities at the Comodoro Rivadavia, Caleta Cordova, and Caleta Olivia ports located within this gulf. In other coastal areas away from potential anthropogenic sources, hydrocarbon values were less than 2 and 3 microg/g dw for TAH and TArH, respectively. This review of published and unpublished information suggests that ports are important oil pollution sources in the Patagonian coast. More detailed studies are needed to evaluate the area affected by port activities, to understand the mechanisms of hydrocarbon distribution in surrounding environments, and to assess bioaccumulation in marine organisms. Despite that some regulations exist to control oil pollution derived from port and docked vessel activities, new and stricter management guidelines should be implemented.

Total Petroleum Systems of the Carpathian - Balkanian Basin Province of Romania and Bulgaria

USGS Publications Warehouse

Pawlewicz, Mark

2007-01-01

The U.S. Geological Survey defined the Moesian Platform Composite Total Petroleum System and the Dysodile Schist-Tertiary Total Petroleum System, which contain three assessment units, in the Carpathian-Balkanian Basin Province of Romania and Bulgaria. The Moesian Platform Assessment Unit, contained within the Moesian Platform Composite Total Petroleum System, is composed of Mesozoic and Cenozoic rocks within the Moesian platform region of southern Romania and northern Bulgaria and also within the Birlad depression in the northeastern platform area. In Romania, hydrocarbon sources are identified as carbonate rocks and bituminous claystones within the Middle Devonian, Middle Jurassic, Lower Cretaceous, and Neogene stratigraphic sequences. In the Birlad depression, Neogene pelitic strata have the best potential for generating hydrocarbons. In Bulgaria, Middle and Upper Jurassic shales are the most probable hydrocarbon sources. The Romania Flysch Zone Assessment Unit in the Dysodile Schist-Tertiary Total Petroleum System encompasses three structural and paleogeographic subunits within the Pre-Carpathian Mountains region: (1) the Getic depression, a segment of the Carpathian foredeep; (2) the flysch zone of the eastern Carpathian Mountains (also called the Marginal Fold nappe); and (3) the Miocene zone (also called the Sub-Carpathian nappe). Source rocks are interpreted to be Oligocene dysodile schist and black claystone, along with Miocene black claystone and marls. Also part of the Dysodile Schist-Tertiary Total Petroleum System is the Romania Ploiesti Zone Assessment Unit, which includes a zone of diapir folds. This zone lies between the Rimnicu Sarat and Dinibovita valleys and between the folds of the inner Carpathian Mountains and the external flanks of the Carpathian foredeep. The Oligocene Dysodile Schist is considered the main hydrocarbon source rock and Neogene black marls and claystones are likely secondary sources; all are thought to be at their maximum thermal maturation. Undiscovered resources in the Carpathian-Balkanian Basin Province are estimated, at the mean, to be 2,076 billion cubic feet of gas, 1,013 million barrels of oil, and 116 million barrels of natural gas liquids.

Seeds of Peganum Harmala L. chemical analysis, antimalarial and antioxidant activities, and cytotoxicity against human breast cancer cells.

PubMed

Chabir, Naziha; Ibrahim, Hany; Romdhane, Hany; Valentin, Alexis; Moukarzel, Beatrice; Mars, Mohamed; Bouajila, Jalloul

2014-01-01

The present study evaluated the levels of total phenolics, flavonoids, tannins and anthocyanins from Peganum harmala L. seeds and determined their antioxidant, antiplasmodial and anticancer potentials. Antioxidant activity was determined by DPPH and ABTS assays. Extracts of P. harmala seeds from Oudref and Djerba (two places in Tunisia) were obtained by successive extraction solvents: petroleum ether, chloroform, ethyl acetate, ethanol and water. Their composition was evaluated for phenolics (gallic acid equivalent 2.48 to 72.52 g/kg), tannins (catechin equivalent 0 to 25.27 g/kg), anthocyanins (cyanidin equivalent 0 to 20.56 mg/kg) and flavonoids (quercetin equivalent 0 to 3.12 g/kg). Ethanolic extract exerted the highest activities against a chloroquine-resistant strain of Plasmodium falciparum (IC₅₀=23 mg/L), against human breast cancer cells MCF7 (IC₅₀=32 mg/L) and against free radical (IC₅₀=19.09±3.07 mg/L). Correlations were studied between each chemical family and the three activities. Total phenolics content exhibited the highest correlation with antiplasmodial activity (R²=0.92) and with anticancer activity (R²=0.86), respectively.

Analyzing tree cores to detect petroleum hydrocarbon-contaminated groundwater at a former landfill site in the community of Happy Valley-Goose Bay, eastern Canadian subarctic.

PubMed

Fonkwe, Merline L D; Trapp, Stefan

2016-08-01

This research examines the feasibility of analyzing tree cores to detect benzene, toluene, ethylbenzene, and m, p, o-xylene (BTEX) compounds and methyl tertiary-butyl ether (MTBE) in groundwater in eastern Canada subarctic environments, using a former landfill site in the remote community of Happy Valley-Goose Bay, Labrador. Petroleum hydrocarbon contamination at the landfill site is the result of environmentally unsound pre-1990s disposal of households and industrial solid wastes. Tree cores were taken from trembling aspen, black spruce, and white birch and analyzed by headspace-gas chromatography-mass spectrometry. BTEX compounds were detected in tree cores, corroborating known groundwater contamination. A zone of anomalously high concentrations of total BTEX constituents was identified and recommended for monitoring by groundwater wells. Tree cores collected outside the landfill site at a local control area suggest the migration of contaminants off-site. Tree species exhibit different concentrations of BTEX constituents, indicating selective uptake and accumulation. Toluene in wood exhibited the highest concentrations, which may also be due to endogenous production. Meanwhile, MTBE was not found in the tree cores and is considered to be absent in the groundwater. The results demonstrate that tree-core analysis can be useful for detecting anomalous concentrations of petroleum hydrocarbons, such as BTEX compounds, in subarctic sites with shallow unconfined aquifers and permeable soils. This method can therefore aid in the proper management of contamination during landfill operations and after site closures.

Assessment of the photoenhanced toxicity of a weathered oil to the tidewater silverside

USGS Publications Warehouse

Little, Edward E.; Cleveland, Laverne; Calfee, Robin D.; Barron, Mace G.

2000-01-01

Studies were conducted to determine the interactive toxicity of a water-accommodated fraction (WAF) of a weathered middle distillate petroleum and solar radiation to an estuarine organism, the tidewater silverside (Menidia beryllina). Juvenile silversides were monitored for survival and growth during a 7-d static renewal exposure to dilutions of WAFs of an environmentally weathered oil collected in the vicinity of an abandoned oil field in California. Ultraviolet (UV) treatments were based on incident sunlight intensity and spectra measured at this site. Exposure to UV alone was not lethal to the fish, and WAF in the absence of UV was toxic at the highest total petroleum hydrocarbon (TPH) concentration (3.03 mg/L) after 96 h of exposure. Water-accommodated fractions toxicity increased significantly with increasing UV irradiance and duration of exposure. The 7-d LC50 concentrations for the control, low, medium, and high irradiance were 2.84, 1.27, 0.93, and 0.51 mg/L TPH, respectively. Significant mortality occurred among fish previously exposed to WAF in the absence of irradiance, whereas WAF toxicity was unaffected by UV exposure prior to the toxicity test. Thus, the mode of action is a photosensitization of the accumulated petroleum residue rather than a photoactivation of WAF. Chemical analysis indicates that the WAF contains limited amounts of polycyclic aromatic hydrocarbons (PAHs) known to be photoenhanced, suggesting that other constituents may be responsible for the observed photoenhanced toxicity.

Petroleum Systems and Geologic Assessment of Undiscovered Oil and Gas, Navarro and Taylor Groups, Western Gulf Province, Texas

USGS Publications Warehouse

,

2006-01-01

The purpose of the U.S. Geological Survey's (USGS) National Oil and Gas Assessment is to develop geologically based hypotheses regarding the potential for additions to oil and gas reserves in priority areas of the United States. The USGS recently completed an assessment of undiscovered oil and gas potential of the Late Cretaceous Navarro and Taylor Groups in the Western Gulf Province in Texas (USGS Province 5047). The Navarro and Taylor Groups have moderate potential for undiscovered oil resources and good potential for undiscovered gas resources. This assessment is based on geologic principles and uses the total petroleum system concept. The geologic elements of a total petroleum system include hydrocarbon source rocks (source rock maturation, hydrocarbon generation and migration), reservoir rocks (sequence stratigraphy and petrophysical properties), and hydrocarbon traps (trap formation and timing). The USGS used this geologic framework to define one total petroleum system and five assessment units. Five assessment units were quantitatively assessed for undiscovered oil and gas resources.

National Assessment of Oil and Gas Project: petroleum systems and geologic assessment of oil and gas in the Southwestern Wyoming Province, Wyoming, Colorado and Utah

USGS Publications Warehouse

,

2005-01-01

The U.S. Geological Survey (USGS) completed an assessment of the undiscovered oil and gas potential of the Southwestern Wyoming Province of southwestern Wyoming, northwestern Colorado, and northeastern Utah (fig. 1). The USGS Southwestern Wyoming Province for this assessment included the Green River Basin, Moxa arch, Hoback Basin, Sandy Bend arch, Rock Springs uplift, Great Divide Basin, Wamsutter arch, Washakie Basin, Cherokee ridge, and the Sand Wash Basin. The assessment of the Southwestern Wyoming Province is based on geologic principles and uses the total petroleum system concept. The geologic elements of a total petroleum system include hydrocarbon source rocks (source rock maturation, hydrocarbon generation, and migration), reservoir rocks (sequence stratigraphy, petrophysical properties), and hydrocarbon traps (trap types, formation, and timing). Using this geologic framework, the USGS defined 9 total petroleum systems (TPS) and 23 assessment units (AU) within these TPSs, and quantitatively estimated the undiscovered oil and gas resources within 21 of the 23 AUs.

Total petroleum hydrocarbons in sediments from the coastline and mangroves of the northern Persian Gulf.

PubMed

Mohebbi-Nozar, Seyedeh Laili; Zakaria, Mohamad Pauzi; Ismail, Wan Ruslan; Mortazawi, Mohammad Seddiq; Salimizadeh, Maryam; Momeni, Mohammad; Akbarzadeh, Gholamali

2015-06-15

To provide baseline information for the marine ecosystem of Hormozgan province, the distribution of petroleum hydrocarbons was evaluated in 52 stations involved in the mangrove and coastline ecosystem. Coastline sampling sites included areas facing harbor, river, domestic and industrial discharge. Sediment samples were analyzed based on ultraviolet fluorescence spectroscopy. Petroleum hydrocarbons showed narrow variations ranging from non-detectable (ND) to 1.71 and from 0.2 to 0.63μg/g dry weight for coastline and mangrove sediments, respectively. The detected concentrations for total petroleum hydrocarbons were lower than guideline values for ecological risk. Furthermore, the minimum environmental risk was confirmed by background levels for the Persian Gulf, the Sea of Oman, and detected values for reference areas. The results were regarded as background data in the studied area, and, considering the rapid expansion of activities related to the petroleum industry in Hormozgan province, the continuous monitoring of pollutants is recommended. Copyright © 2015 Elsevier Ltd. All rights reserved.

Assessment of organic pollutants in the offshore sediments of Dubai, United Arab Emirates

NASA Astrophysics Data System (ADS)

Darwish, H. A. Al; El-Gawad, E. A. Abd; Mohammed, F. H.; Lotfy, M. M.

2005-08-01

Fifteen stations (st) were selected along Dubai coastal region to delineate the distribution and the source of total petroleum hydrocarbon (TPH), total organic carbon (TOC), total Kjeldhal nitrogen (TKN), polycyclic aromatic hydrocarbon (PAHs) and polychlorinated biphenyls. The concentrations of TPH fluctuated between 2 μg g -1 and 48018 μg g -1 and the values of TOC were in the range of 0.16-5.9 wt%, while TPAHs ranged from 0.09 μg g -1 to 161.72 μg g -1. On the other hand, TPCBs showed values between 0.8 μg kg-1 and 93.3 μg kg-1 and TKN values varied from 218 μg g-1 to 2457 μg g -1. Distribution of oil and organic compounds in Dubai sediments are safe compared with previous studies except for limited areas at the northeastern offshore. These readings are probably due to: (1) presence of commercial or industrial ports, dry docks and fishing harbours and (2) population centers mainly concentrated at the northern part of the study area. Results indicate that TOC can be used as indicator of oil pollution only in heavily oiled sediments. The highest values of TOC, TPH, TPAHs and TPCBs corresponded to the stations covered with fine sand, due to adsorption properties and larger surface area. The evaporation of low boiling point compounds from surface layers led to enrichment of sediments with the thick residual. Al-Hamriya St 3 exhibited the highest values of TPH, TOC, TPAHs and TPCBs and the second highest value of TKN.

Madbi Amran/Qishn total petroleum system of the Ma'Rib-Al Jawf/Shabwah, and Masila-Jeza basins, Yemen

USGS Publications Warehouse

Ahlbrandt, Thomas S.

2002-01-01

Since the first discovery of petroleum in Yemen in 1984, several recent advances have been made in the understanding of that countrys geologic history and petroleum systems. The total petroleum resource endowment for the combined petroleum provinces within Yemen, as estimated in the recent U.S. Geological Survey world assessment, ranks 51st in the world, exclusive of the United States, at 9.8 BBOE, which includes cumulative production and remaining reserves, as well as a mean estimate of undiscovered resources. Such undiscovered petroleum resources are about 2.7 billion barrels of oil, 17 trillion cubic feet (2.8 billion barrels of oil equivalent) of natural gas and 1 billion barrels of natural gas liquids. A single total petroleum system, the Jurassic Madbi Amran/Qishn, dominates petroleum generation and production; it was formed in response to a Late Jurassic rifting event related to the separation of the Arabian Peninsula from the Gondwana supercontinent. This rifting resulted in the development of two petroleum-bearing sedimentary basins: (1) the western MaRibAl Jawf / Shabwah basin, and (2) the eastern Masila-Jeza basin. In both basins, petroleum source rocks of the Jurassic (Kimmeridgian) Madbi Formation generated hydrocarbons during Late Cretaceous time that migrated, mostly vertically, into Jurassic and Cretaceous reservoirs. In the western MaRibAl Jawf / Shabwah basin, the petroleum system is largely confined to syn-rift deposits, with reservoirs ranging from deep-water turbidites to continental clastics buried beneath a thick Upper Jurassic (Tithonian) salt. The salt initially deformed in Early Cretaceous time, and continued halokinesis resulted in salt diapirism and associated salt withdrawal during extension. The eastern Masila-Jeza basin contained similar early syn-rift deposits but received less clastic sediment during the Jurassic; however, no salt formed because the basin remained open to ocean circulation in the Late Jurassic. Thus, Madbi Formation-sourced hydrocarbons migrated vertically into Lower Cretaceous estuarine, fluvial, and tidal sandstones of the Qishn Formation and were trapped by overlying impermeable carbonates of the same formation. Both basins were formed by extensional forces during Jurassic rifting; how-ever, another rifting event that formed the Red Sea and Gulf of Aden during Oligocene and Miocene time had a strong effect on the eastern Masila-Jeza basin. Recurrent movement of basement blocks, particularly during the Tertiary, rather than halokinesis, was critical to the formation of traps.

Assessment of Appalachian basin oil and gas resources: Devonian gas shales of the Devonian Shale-Middle and Upper Paleozoic Total Petroleum System: Chapter G.9 in Coal and petroleum resources in the Appalachian basin: distribution, geologic framework, and geochemical character

USGS Publications Warehouse

Milici, Robert C.; Swezey, Christopher S.; Ruppert, Leslie F.; Ryder, Robert T.

2014-01-01

This report presents the results of a U.S. Geological Survey (USGS) assessment of the technically recoverable undiscovered natural gas resources in Devonian shale in the Appalachian Basin Petroleum Province of the eastern United States. These results are part of the USGS assessment in 2002 of the technically recoverable undiscovered oil and gas resources of the province. This report does not use the results of a 2011 USGS assessment of the Devonian Marcellus Shale because the area considered in the 2011 assessment is much greater than the area of the Marcellus Shale described in this report. The USGS assessment in 2002 was based on the identification of six total petroleum systems, which include strata that range in age from Cambrian to Pennsylvanian. The Devonian gas shales described in this report are within the Devonian Shale-Middle and Upper Paleozoic Total Petroleum System, which extends generally from New York to Tennessee. This total petroleum system is divided into ten assessment units (plays), four of which are classified as conventional and six as continuous. The Devonian shales described in this report make up four of these continuous assessment units. The assessment results are reported as fully risked fractiles (F95, F50, F5, and the mean); the fractiles indicate the probability of recovery of the assessment amount. The products reported are oil, gas, and natural gas liquids. The mean estimates for technically recoverable undiscovered hydrocarbons in the four gas shale assessment units are 12,195.53 billion cubic feet (12.20 trillion cubic feet) of gas and 158.91 million barrels of natural gas liquids

Updated estimation of energy efficiencies of U.S. petroleum refineries.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Palou-Rivera, I.; Wang, M. Q.

2010-12-08

Evaluation of life-cycle (or well-to-wheels, WTW) energy and emission impacts of vehicle/fuel systems requires energy use (or energy efficiencies) of energy processing or conversion activities. In most such studies, petroleum fuels are included. Thus, determination of energy efficiencies of petroleum refineries becomes a necessary step for life-cycle analyses of vehicle/fuel systems. Petroleum refinery energy efficiencies can then be used to determine the total amount of process energy use for refinery operation. Furthermore, since refineries produce multiple products, allocation of energy use and emissions associated with petroleum refineries to various petroleum products is needed for WTW analysis of individual fuels suchmore » as gasoline and diesel. In particular, GREET, the life-cycle model developed at Argonne National Laboratory with DOE sponsorship, compares energy use and emissions of various transportation fuels including gasoline and diesel. Energy use in petroleum refineries is key components of well-to-pump (WTP) energy use and emissions of gasoline and diesel. In GREET, petroleum refinery overall energy efficiencies are used to determine petroleum product specific energy efficiencies. Argonne has developed petroleum refining efficiencies from LP simulations of petroleum refineries and EIA survey data of petroleum refineries up to 2006 (see Wang, 2008). This memo documents Argonne's most recent update of petroleum refining efficiencies.« less

Geologic Assessment of Undiscovered Gas Resources of the Eastern Oregon and Washington Province

USGS Publications Warehouse

U.S. Geological Survey Eastern Oregon and Washington Province Assessment Team, (compiler)

2008-01-01

The purpose of the U.S. Geological Survey's (USGS) National Oil and Gas Assessment is to develop geology-based hypotheses regarding the potential for additions to oil and gas reserves in priority areas of the United States, focusing on the distribution, quantity, and availability of oil and natural gas resources. The USGS has completed an assessment of the undiscovered oil and gas potential of the Eastern Oregon and Washington Province of Oregon and Washington (USGS Province 5005). The province is a priority Energy Policy and Conservation Act (EPCA) province for the National Assessment because of its potential for oil and gas resources. The assessment of this province is based on geologic principles and uses the total petroleum system concept. The geologic elements of a total petroleum system include hydrocarbon source rocks (source rock maturation, hydrocarbon generation and migration), reservoir rocks (stratigraphy, sedimentology, petrophysical properties), and hydrocarbon traps (trap formation and timing). In the Eastern Oregon and Washington Province, the USGS used this geologic framework to define one total petroleum system and two assessment units within the total petroleum system, and quantitatively estimated the undiscovered gas resources within each assessment unit.

Scale up of diesel oil biodegradation in a baffled roller bioreactor.

PubMed

Nikakhtari, Hossein; Song, Wanning; Kumar, Pardeep; Nemati, Mehdi; Hill, Gordon A

2010-05-01

Diesel oil is a suitable substance to represent petroleum contamination from accidental spills in operating and transportation facilities. Using a microbial culture enriched from a petroleum contaminated soil, biodegradation of diesel oil was carried out in 2.2, 55, and 220 L roller baffled bioreactors. The effects of bioreactor rotation speed (from 5 to 45 rpm) and liquid loading (from 18% to 73% of total volume) on the biodegradation of diesel oil were studied. In the small scale bioreactor (2.2L), the maximum rotation speed of 45 rpm resulted in the highest biodegradation rate with a first order biodegradation kinetic constant of 0.095 d(-1). In the larger scale bioreactors, rotation speed did not affect the biodegradation rate. Liquid loadings higher than 64% resulted in reduced biodegradation rates in the small scale bioreactor; however, in the larger roller bioreactors liquid loading did not affect the biodegradation rate. Biodegradation of diesel oil at 5 rpm and 73% loading is recommended for operating large scale roller baffled bioreactors. Under these conditions, high diesel oil concentrations up to 50 gL(-1) can be bioremediated at a rate of 1.61 gL(-1)d(-1). Copyright 2010 Elsevier Ltd. All rights reserved.

Petroleum Systems and Assessment of Undiscovered Oil and Gas in the Raton Basin - Sierra Grande Uplift Province, Colorado and New Mexico - USGS Province 41

USGS Publications Warehouse

Higley, Debra K.

2007-01-01

Introduction The purpose of the U.S. Geological Survey's (USGS) National Oil and Gas Assessment is to develop geologically based hypotheses regarding the potential for additions to oil and gas reserves in priority areas of the United States. The USGS recently completed an assessment of undiscovered oil and gas resources of the Raton Basin-Sierra Grande Uplift Province of southeastern Colorado and northeastern New Mexico (USGS Province 41). The Cretaceous Vermejo Formation and Cretaceous-Tertiary Raton Formation have production and undiscovered resources of coalbed methane. Other formations in the province exhibit potential for gas resources and limited production. This assessment is based on geologic principles and uses the total petroleum system concept. The geologic elements of a total petroleum system include hydrocarbon source rocks (source rock maturation, hydrocarbon generation and migration), reservoir rocks (sequence stratigraphy and petrophysical properties), and hydrocarbon traps (trap formation and timing). The USGS used this geologic framework to define two total petroleum systems and five assessment units. All five assessment units were quantitatively assessed for undiscovered gas resources. Oil resources were not assessed because of the limited potential due to levels of thermal maturity of petroleum source rocks.

National Assessment of Oil and Gas Project: Petroleum systems and assessment of undiscovered oil and gas in the Denver Basin Province, Colorado, Kansas, Nebraska, South Dakota, and Wyoming - USGS Province 39

USGS Publications Warehouse

Higley, Debra K.

2007-01-01

The purpose of the U.S. Geological Survey's (USGS) National Oil and Gas Assessment is to develop geologically based hypotheses regarding the potential for additions to oil and gas reserves in priority areas of the United States. The USGS recently completed an assessment of undiscovered oil and gas resources of the Denver Basin Province (USGS Province 39), Colorado, Kansas, Nebraska, South Dakota, and Wyoming. Petroleum is produced in the province from sandstone, shale, and limestone reservoirs that range from Pennsylvanian to Upper Cretaceous in age. This assessment is based on geologic principles and uses the total petroleum system concept. The geologic elements of a total petroleum system include hydrocarbon source rocks (source rock maturation, hydrocarbon generation and migration), reservoir rocks (sequence stratigraphy and petrophysical properties), and hydrocarbon traps (trap formation and timing). The USGS used this geologic framework to define seven total petroleum systems and twelve assessment units. Nine of these assessment units were quantitatively assessed for undiscovered oil and gas resources. Gas was not assessed for two coal bed methane assessment units due to lack of information and limited potential; oil resources were not assessed for the Fractured Pierre Shale Assessment Unit due to its mature development status.

[Determination of β-sitosterol and total sterols content and antioxidant activity of oil in acai (Euterpe oleracea)].

PubMed

He, Cheng; Li, Wei; Zhang, Jian-Jun; Qu, Sheng-Sheng; Li, Jia-Jing; Wang, Lin-Yuan

2014-12-01

In order to establish a method for the determination of the sterols of the oil in the freeze-dried acai (Euterpe oleracea Mart.) and to evaluate its antioxidant activities, a saponification/extraction procedure and high performance liquid chromatography (HPLC) analysis method were developed and validated for the analysis of phytosterols in PEE (Petroleum ether extract). Separation was achieved on a Purosper STAR LP C18 column with a binary, gradient solvent system of acetonitrile and isopropanol. Evaporative light scattering detection (ELSD) was used to quantify β-sitosterol and the total sterols. Peak identification was verified by retention times and spikes with external standards. Standard curves were constructed (r = 0.999 2) to allow for sample quantification. Recovery of the saponification and extraction was demonstrated via analysis of spiked samples. The highest content of total sterols is β-sitosterol. The antioxidant activities of the extracts were evaluated using the total oxyradical scavenging capacity assay (TOSC assay). The result showed that the PEE exhibited significant antioxidant properties, sample concentration and the antioxidant capacity had a certain relevance.

Tidal river sediments in the Washington, D.C. area. 11. Distribution and sources of organic containmants

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wade, T.L.; Velinsky, D.J.; Reinharz, E.

1994-06-01

Concentrations of aliphatic, aromatic, and chlorinated hydrocarbons were determined from 33 surface-sediment samples taken from the Tidal Basin, Washington Ship Channel, and the Anacostia and Potomac rivers in Washington, D.C. In conjunction with these samples, selected storm sewers and outfalls also were sampled to help elucidate general sources of contamination to the area. All of the sediments contained detectable concentrations of aliphatic and aromatic hydrocarbons, DDT (total dichlorodiphenytrichloroethande), DDE (dichlorodiphenyldichloroethene), DDD (dichlorodiphenyldichloroethane), PCBx (total polychlorinated biphenyls) and total chlordanes (oxy-, {alpha}-, and {gamma}-chlordane and cis + trans-nonachlor). Sediment concentrations of most contaminants were highest in the Anacostia River just downstreammore » of the Washington Navy Yard, except for total chlordane, which appeared to have upstream sources in addition to storm and combined sewer runoff. This area has the highest number of storm and combined sewer outfalls in the river. Potomac River stations had lower concentrations than other stations. Polycyclic aromatic hydrocarbons, saturated hydrocarbons, and the unresolved complex mixture (UCM) distributions reflect mixtures of combustion products and direct discharges of petroleum products. Sources of PCBs appear to be related to specific outfalls, while hydrocarbon inputs, especially PAHs, are diffuse, and may be related to street runoff. This study indicates that in large urban areas, nonpoint sources deliver substantial amounts of contaminants to ecosystems through storm and combined sewer systems, and control of these inputs must be addressed. 33 refs., 6 figs., 3 tabs.« less

Water and Proppant Requirements and Water Production Associated with Undiscovered Petroleum in the Bakken and Three Forks Formations, North Dakota and Montana, USA

NASA Astrophysics Data System (ADS)

Haines, S. S.; Varela, B. A.; Thamke, J.; Hawkins, S. J.; Gianoutsos, N. J.; Tennyson, M. E.

2017-12-01

Water is used for several stages of oil and gas production, in particular for hydraulic fracturing that is typically used during production of petroleum from low-permeability shales and other rock types (referred to as "continuous" petroleum accumulations). Proppant, often sand, is also consumed during hydraulic fracturing. Water is then produced from the reservoir along with the oil and gas, representing either a disposal consideration or a possible source of water for further petroleum development or other purposes. The U.S. Geological Survey (USGS) has developed an approach for regional-scale estimation of these water and proppant quantities in order to provide an improved understanding of possible impacts and to help with planning and decision-making. Using the new methodology, the USGS has conducted a quantitative assessment of water and proppant requirements, and water production volumes, associated with associated with possible future production of undiscovered petroleum resources in the Bakken and Three Forks Formations, Williston Basin, USA. This water and proppant assessment builds directly from the 2013 USGS petroleum assessment for the Bakken and Three Forks Formations. USGS petroleum assessments incorporate all available geologic and petroleum production information, and include the definition of assessment units (AUs) that specify the geographic regions and geologic formations for the assessment. The 2013 petroleum assessment included 5 continuous AUs for the Bakken Formation and one continuous AU for the Three Forks Formation. The assessment inputs are defined probabilistically, and a Monte Carlo approach provides outputs that include uncertainty bounds. We can summarize the assessment outputs with the mean values of the associated distributions. The mean estimated total volume of water for well drilling and cement for all six continuous AUs is 5.9 billion gallons, and the mean estimated volume of water for hydraulic fracturing for all AUs is 164.3 billion gallons. The mean estimated quantity of proppant for hydraulic fracturing is 101.3 million tons. Summing over all of the AUs, the mean estimated total flowback water volume is 9.9 billion gallons and the mean estimated total produced water is 414.5 billion gallons.

[Effects and Biological Response on Bioremediation of Petroleum Contaminated Soil].

PubMed

Yang, Qian; Wu, Man-li; Nie, Mai-qian; Wang, Ting-ting; Zhang, Ming-hui

2015-05-01

Bioaugmentation and biostimulation were used to remediate petroleum-contaminated soil which were collected from Zichang city in North of Shaanxi. The optimal bioremediation method was obtained by determining the total petroleum hydrocarbon(TPH) using the infrared spectroscopy. During the bioremediation, number of degrading strains, TPH catabolic genes, and soil microbial community diversity were determined by Most Probable Number (MPN), polymerase chain reaction (PCR) combined agarose electrophoresis, and PCR-denaturing gradient electrophoresis (DGGE). The results in different treatments showed different biodegradation effects towards total petroleum hydrocarbon (TPH). Biostimulation by adding N and P to soils achieved the best degradation effects towards TPH, and the bioaugmentation was achieved by inoculating strain SZ-1 to soils. Further analysis indicated the positive correlation between catabolic genes and TPH removal efficiency. During the bioremediation, the number of TPH and alkanes degrading strains was higher than the number of aromatic degrading strains. The results of PCR-DGGE showed microbial inoculums could enhance microbial community functional diversity. These results contribute to understand the ecologically microbial effects during the bioremediation of petroleum-polluted soil.

Development of a hybrid proximal sensing method for rapid identification of petroleum contaminated soils.

PubMed

Chakraborty, Somsubhra; Weindorf, David C; Li, Bin; Ali Aldabaa, Abdalsamad Abdalsatar; Ghosh, Rakesh Kumar; Paul, Sathi; Nasim Ali, Md

2015-05-01

Using 108 petroleum contaminated soil samples, this pilot study proposed a new analytical approach of combining visible near-infrared diffuse reflectance spectroscopy (VisNIR DRS) and portable X-ray fluorescence spectrometry (PXRF) for rapid and improved quantification of soil petroleum contamination. Results indicated that an advanced fused model where VisNIR DRS spectra-based penalized spline regression (PSR) was used to predict total petroleum hydrocarbon followed by PXRF elemental data-based random forest regression was used to model the PSR residuals, it outperformed (R(2)=0.78, residual prediction deviation (RPD)=2.19) all other models tested, even producing better generalization than using VisNIR DRS alone (RPD's of 1.64, 1.86, and 1.96 for random forest, penalized spline regression, and partial least squares regression, respectively). Additionally, unsupervised principal component analysis using the PXRF+VisNIR DRS system qualitatively separated contaminated soils from control samples. Fusion of PXRF elemental data and VisNIR derivative spectra produced an optimized model for total petroleum hydrocarbon quantification in soils. Copyright © 2015 Elsevier B.V. All rights reserved.

Acaricidal activity of extracts of neem (Azadirachta indica) oil against the larvae of the rabbit mite Sarcoptes scabiei var. cuniculi in vitro.

PubMed

Du, Yong-Hua; Jia, Ren-Yong; Yin, Zhong-Qiong; Pu, Zhong-Hui; Chen, Jiao; Yang, Fan; Zhang, Yu-Qun; Lu, Yang

2008-10-20

The acaricidal activity of the petroleum ether extract, the chloroform extract and the acetic ether extract of neem (Azadirachta indica) oil against Sarcoptes scabiei var. cuniculi larvae was tested in vitro. A complementary log-log (CLL) model was used to analyze the data of the toxicity tests. The results showed that at all test time points, the petroleum ether extract demonstrated the highest activity against the larvae of S. scabiei var. cuniculi, while the activities of the chloroform extract and the acetic ether extract were similar. The activities of both the petroleum ether extract and the chloroform extract against the larvae showed the relation of time and concentration dependent. The median lethal concentration (LC50) of the petroleum ether extract (1.3 microL/mL) was about three times that of the chloroform extract (4.1 microL/mL) at 24 h post-treatment. At the concentrations of 500.0 microL/mL, the median lethal time (LT50) of the petroleum ether extract and the chloroform extract was 8.4 and 9.6 h, respectively.

Chemical signatures of the Anthropocene in the Clyde estuary, UK: sediment-hosted Pb, (207/206)Pb, total petroleum hydrocarbon, polyaromatic hydrocarbon and polychlorinated biphenyl pollution records.

PubMed

Vane, C H; Chenery, S R; Harrison, I; Kim, A W; Moss-Hayes, V; Jones, D G

2011-03-13

The sediment concentrations of total petroleum hydrocarbons (TPHs), polyaromatic hydrocarbons (PAHs), polychlorinated biphenyls (PCBs), Pb and (207/206)Pb isotope ratios were measured in seven cores from the middle Clyde estuary (Scotland, UK) with an aim of tracking the late Anthropocene. Concentrations of TPHs ranged from 34 to 4386 mg kg(-1), total PAHs from 19 to 16,163 μg kg(-1) and total PCBs between less than 4.3 to 1217 μg kg(-1). Inventories, distributions and isomeric ratios of the organic pollutants were used to reconstruct pollutant histories. Pre-Industrial Revolution and modern non-polluted sediments were characterized by low TPH and PAH values as well as high relative abundance of biogenic-sourced phenanthrene and naphthalene. The increasing industrialization of the Clyde gave rise to elevated PAH concentrations and PAH isomeric ratios characteristic of both grass/wood/coal and petroleum and combustion (specifically petroleum combustion). Overall, PAHs had the longest history of any of the organic contaminants. Increasing TPH concentrations and a concomitant decline in PAHs mirrored the lessening of coal use and increasing reliance on petroleum fuels from about the 1950s. Thereafter, declining hydrocarbon pollution was followed by the onset (1950s), peak (1965-1977) and decline (post-1980s) in total PCB concentrations. Lead concentrations ranged from 6 to 631 mg kg(-1), while (207/206)Pb isotope ratios spanned 0.838-0.876, indicative of various proportions of 'background', British ore/coal and Broken Hill type petrol/industrial lead. A chronology was established using published Pb isotope data for aerosol-derived Pb and applied to the cores.

Management of Bottom Sediments Containing Toxic Substances: Proceedings of the U.S./Japan Experts Meeting (10th) Held at Kyoto, Japan on 30-31 October 1984.

DTIC Science & Technology

1985-10-01

potential for bioaccumulation of cadmium, chromium, copper, mercury, silver, pesticides, PCBs, petroleum hydrocarbons , and organotins. The concentration...the dredging projects indicated environmentally significant mortality poten- tial to benthic life. Bioaccumulation analyses for petroleum hydrocarbons ...ocean disposal, bioaccumulation analysis is conducted for total petroleum hydrocarbons (PHC), polychlorinated biphenyls (PCB), DDT, mercury (Hg), and

Comparative bioremediation of heavy metals and petroleum hydrocarbons co-contaminated soil by natural attenuation, phytoremediation, bioaugmentation and bioaugmentation-assisted phytoremediation.

PubMed

Agnello, A C; Bagard, M; van Hullebusch, E D; Esposito, G; Huguenot, D

2016-09-01

Biological remediation technologies are an environmentally friendly approach for the treatment of polluted soils. This study evaluated through a pot experiment four bioremediation strategies: a) natural attenuation, b) phytoremediation with alfalfa (Medicago sativa L.), c) bioaugmentation with Pseudomonas aeruginosa and d) bioaugmentation-assisted phytoremediation, for the treatment of a co-contaminated soil presenting moderate levels of heavy metals (Cu, Pb and Zn at 87, 100 and 110mgkg(-1) DW, respectively) and petroleum hydrocarbons (3800mgkg(-1) DW). As demonstrated by plant biomass and selected physiological parameters alfalfa plants were able to tolerate and grow in the co-contaminated soil, especially when soil was inoculated with P. aeruginosa, which promoted plant growth (56% and 105% increase for shoots and roots, respectively) and appeared to alleviate plant stress. The content of heavy metals in alfalfa plants was limited and followed the order: Zn>Cu>Pb. Heavy metals were mainly concentrated in plant roots and were poorly translocated, favouring their stabilization in the root zone. Bioaugmentation of planted soil with P. aeruginosa generally led to a decrease of plant metal concentration and translocation. The highest degree of total petroleum hydrocarbon removal was obtained for bioaugmentation-assisted phytoremediation treatment (68%), followed by bioaugmentation (59%), phytoremediation (47%) and natural attenuation (37%). The results of this study demonstrated that the combined use of plant and bacteria was the most advantageous option for the treatment of the present co-contaminated soil, as compared to natural attenuation, bioaugmentation or phytoremediation applied alone. Copyright © 2015 Elsevier B.V. All rights reserved.

The new international certification and design principles

DOE Office of Scientific and Technical Information (OSTI.GOV)

Heijnen, W.H.P.M.; Heineman, H.

1995-12-01

ISO/TC 67 deals with standardization of Equipment for the Petroleum and Natural Gas Industries at a global level. The paper will provide the reader with insight in the Certification system as well as its link with Design. It will explain how the total process fits in the business structure of the Petroleum and Natural Gas Industry, with the focus on the emerging concepts such as partnering, turn key contracts, the developments in the EC and the need to reduce costs at a global basis. The paper will also address the topic of Design Principles based on the results of themore » study performed for ISO/TC 67. The paper will provide a framework that can be used by the industry in how to deal with issues such as, there shall the activity of the Operator be focused on when ordering equipment or services and how the manufacturer or service provider should prepare himself to become an equal partner with regard to the required equipment, service and its associated technology now and in the future. In the changing world with ever increasing focus on Health, Safety and Environment (HSE), the topic efficiency, technology, equipment performance and functionality should not be overlooked or been given less attention. The Certification and Design principles, implemented in standards, aim predominantly at Fitness for Purpose of equipment and/or services to regain the balance. A further aim is to limit consequential costs due to deficiencies in the broadest sense, allowing the Petroleum and Natural Gas Industry to produce oil and gas in a cost effective manner with the highest possible HSE targets.« less

In search of a Silurian total petroleum system in the Appalachian basin of New York, Ohio, Pennsylvania, and West Virginia: Chapter G.11 in Coal and petroleum resources in the Appalachian basin: distribution, geologic framework, and geochemical character

USGS Publications Warehouse

Ryder, Robert T.; Swezey, Christopher S.; Trippi, Michael H.; Lentz, Erika E.; Avary, K. Lee; Harper, John A.; Kappel, William M.; Rea, Ronald G.; Ruppert, Leslie F.; Ryder, Robert T.

2014-01-01

Although the TOC analyses in this study indicate that good to very good source rocks are present in the Salina Group and Wills Creek Formation of southwestern Pennsylvania and northern West Virginia, data are insufficient to propose a new Silurian total petroleum system in the Appalachian basin. However, the analytical results of this investigation are encouraging enough to undertake more systematic studies of the source rock potential of the Salina Group, Wills Creek Formation, and perhaps the Tonoloway Formation (Limestone) and McKenzie Limestone (or Member).

Efficiency of Opuntia ficus in the phytoremediation of a soil contaminated with used motor oil and lead, compared to that of Lolium perenne and Aloe barbadensis.

PubMed

Escobar-Alvarado, Luisa F; Vaca-Mier, Mabel; López-Callejas, Raymundo; Rojas-Valencia, Ma Neftalí

2018-01-28

Industrial pollutants such as heavy metals and hydrocarbons in soils represent a serious concern due to their persistence and negative effects on the environment, affecting cellular processes in living organisms and even causing mutations and cancer. The main objectives of this work were to evaluate the efficiency of Opuntia ficus in the phytoremediation of a soil polluted with used motor oil. Two other species, one with different and one with similar characteristics, relatively, were used for comparison purposes: Lolium perenne and Aloe barbadensis. The effect of the plants on lead solubility and bioaccumulation, the biomass production of each specie and the microbial counts and bacterial identification for each experiment was studied. Total petroleum hydrocarbons (TPH) were measured every 5 weeks throughout the 20-week phytoremediation experiment. At the end of the experiment soluble Pb, Pb extracted by the plant species, microbiological counts, total biomass and bacterial species in soil were analyzed. Even though Lolium perenne showed the highest TPH removal (47%), Opuntia ficus produced the highest biomass and similar removal (46%). Since Opuntia ficus requires low amounts of water and grows fast, it would be a suitable option in the remediation of soils polluted with hydrocarbons and/or heavy metals.

CITGO Petroleum Corporation and PDV Midwest Refining, LLC Settlement

EPA Pesticide Factsheets

CITGO Petroleum Corporation and PDV Midwest Refining, LLC (collectively, CITGO) have agreed to pay a $1,955,000 civil penalty, perform environmental projects totaling more than $2 million, and spend an estimated $42 million in injunctive relief to resolve.

Environmental hazard and risk characterisation of petroleum substances: a guided "walking tour" of petroleum hydrocarbons.

PubMed

Bierkens, Johan; Geerts, Lieve

2014-05-01

Petroleum substances are used in large quantities, primarily as fuels. They are complex mixtures whose major constituents are hydrocarbons derived from crude oil by distillation and fractionation. Determining the complete molecular composition of petroleum and its refined products is not feasible with current analytical techniques because of the huge number of molecular components. This complex nature of petroleum products, with their varied number of constituents, all of them exhibiting different fate and effect characteristics, merits a dedicated hazard and risk assessment approach. From a regulatory perspective they pose a great challenge in a number of REACH processes, in particular in the context of dossier and substance evaluation but also for priority setting activities. In order to facilitate the performance of hazard and risk assessment for petroleum substances the European oil company association, CONCAWE, has developed the PETROTOX and PETRORISK spreadsheet models. Since the exact composition of many petroleum products is not known, an underlying assumption of the PETROTOX and PETRORISK tools is that the behaviour and fate of a total petroleum substance can be simulated based on the physical-chemical properties of representative structures mapped to hydrocarbon blocks (HBs) and on the relative share of each HB in the total mass of the product. To assess how differing chemical compositions affect the simulated chemical fate and toxicity of hydrocarbon mixtures, a series of model simulations were run using an artificial petroleum substance, containing 386 (PETROTOX) or 160 (PETRORISK) HBs belonging to different chemical classes and molecular weight ranges, but with equal mass assigned to each of them. To this artificial petroleum substance a guided series of subsequent modifications in mass allocation to a delineated number of HBs belonging to different chemical classes and carbon ranges was performed, in what we perceived as a guided "walking tour" through the chemical space of petroleum substances. We show that the PETROTOX and PETRORISK predictions reflect changes in mass distribution introduced to selected HBs by affecting hazard and risk estimates in correspondence with what is expected based on physical-chemical properties of individual constituents in the corresponding HBs. Copyright © 2014 Elsevier Ltd. All rights reserved.

Assessment of undiscovered hydrocarbon resources of sub-Saharan Africa

USGS Publications Warehouse

Brownfield, Michael E.

2016-01-01

The assessment was geology-based and used the total petroleum system (TPS) concept. The geologic elements of a TPS are hydrocarbon source rocks (source rock maturation and hydrocarbon generation and migration), reservoir rocks (quality and distribution), and traps where hydrocarbon accumulates. Using these geologic criteria, 16 conventional total petroleum systems and 18 assessment units in the 13 provinces were defined. The undiscovered, technically recoverable oil and gas resources were assessed for all assessment units.

Petroleum systems and geologic assessment of undiscovered oil and gas, Cotton Valley group and Travis Peak-Hosston formations, East Texas basin and Louisiana-Mississippi salt basins provinces of the northern Gulf Coast region. Chapters 1-7.

USGS Publications Warehouse

,

2006-01-01

The purpose of the U.S. Geological Survey's (USGS) National Oil and Gas Assessment is to develop geologically based hypotheses regarding the potential for additions to oil and gas reserves in priority areas of the United States. The USGS recently completed an assessment of undiscovered oil and gas potential of the Cotton Valley Group and Travis Peak and Hosston Formations in the East Texas Basin and Louisiana-Mississippi Salt Basins Provinces in the Gulf Coast Region (USGS Provinces 5048 and 5049). The Cotton Valley Group and Travis Peak and Hosston Formations are important because of their potential for natural gas resources. This assessment is based on geologic principles and uses the total petroleum system concept. The geologic elements of a total petroleum system include hydrocarbon source rocks (source rock maturation, hydrocarbon generation and migration), reservoir rocks (sequence stratigraphy and petrophysical properties), and hydrocarbon traps (trap formation and timing). The USGS used this geologic framework to define one total petroleum system and eight assessment units. Seven assessment units were quantitatively assessed for undiscovered oil and gas resources.

Mapping the petroleum system - An investigative technique to explore the hydrocarbon fluid system

USGS Publications Warehouse

Magoon, L.B.; Dow, W.G.

2000-01-01

Creating a petroleum system map includes a series of logical steps that require specific information to explain the origin in time and space of discovered hydrocarbon occurrences. If used creatively, this map provides a basis on which to develop complementary plays and prospects. The logical steps include the characterization of a petroleum system (that is, to identify, map, and name the hydrocarbon fluid system) and the summary of these results on a folio sheet. A petroleum system map is based on the understanding that there are several levels of certainty from "guessing" to "knowing" that specific oil and gas accumulations emanated from a particular pod of active source rock. Levels of certainty start with the close geographic proximity of two or more accumulations, continues with the close stratigraphic proximity, followed by the similarities in bulk properties, and then detailed geochemical properties. The highest level of certainty includes the positive geochemical correlation of the hydrocarbon fluid in the accumulations to the extract of the active source rock. A petroleum system map is created when the following logic is implemented. Implementation starts when the oil and gas accumulations of a petroleum province are grouped stratigraphically and geographically. Bulk and geochemical properties are used to further refine the groups through the determination of genetically related oil and gas types. To this basic map, surface seeps and well shows are added. Similarly, the active source rock responsible for these hydrocarbon occurrences are mapped to further define the extent of the system. A folio sheet constructed for a hypothetical case study of the Deer-Boar(.) petroleum system illustrates this methodology.

Monthly Energy Review

EIA Publications

2017-01-01

The Monthly Energy Review (MER) is the U.S. Energy Information Administration's primary report of recent energy statistics. Included are total energy production, consumption, and trade; energy prices; overviews of petroleum, natural gas, coal, electricity, nuclear energy, renewable energy, and international petroleum; carbon dioxide emissions; and data unit conversions.

Combination of biochar amendment and phytoremediation for hydrocarbon removal in petroleum-contaminated soil.

PubMed

Han, Tao; Zhao, Zhipeng; Bartlam, Mark; Wang, Yingying

2016-11-01

Remediation of soils contaminated with petroleum is a challenging task. Four different bioremediation strategies, including natural attenuation, biochar amendment, phytoremediation with ryegrass, and a combination of biochar and ryegrass, were investigated with greenhouse pot experiments over a 90-day period. The results showed that planting ryegrass in soil can significantly improve the removal rate of total petroleum hydrocarbons (TPHs) and the number of microorganisms. Within TPHs, the removal rate of total n-alkanes (45.83 %) was higher than that of polycyclic aromatic hydrocarbons (30.34 %). The amendment of biochar did not result in significant improvement of TPH removal. In contrast, it showed a clear negative impact on the growth of ryegrass and the removal of TPHs by ryegrass. The removal rate of TPHs was significantly lower after the amendment of biochar. The results indicated that planting ryegrass is an effective remediation strategy, while the amendment of biochar may not be suitable for the phytoremediation of soil contaminated with petroleum hydrocarbons.

The Red Sea Basin Province: Sudr-Nubia(!) and Maqna(!) Petroleum Systems

USGS Publications Warehouse

Lindquist, Sandra J.

1999-01-01

The Sudr-Nubia(!) oil-prone total petroleum system dominates the densely explored Gulf of Suez part of the rifted Red Sea Basin Province. Upper Cretaceous to Eocene source rocks, primarily the Senonian Sudr Formation, are organic-rich, areally uniform marine carbonates that have generated known ultimate recoverable reserves exceeding 11 BBOE. The name Nubia is used for sandstone reservoirs with a wide range of poorly constrained, pre-rift geologic ages ranging from Early Paleozoic to Early Cretaceous. Syn- and post-rift Tertiary reservoirs, especially the Kareem Formation, also contain significant reserves. Partly overlapping Sudr-Nubia(!) is the areally larger and geochemically distinct, oil-and-gas-prone Maqna(!) total petroleum system within the southern Gulf of Suez basin and the sparsely explored remaining Red Sea basin. Known ultimate recoverable reserves are 50-100 MMBOE and more than 900 MMBOE, respectively, in those areas. Both the source and reservoir rocks in this petroleum system are Tertiary, dominantly Miocene, in age. Maqna(!) has the greater potential for future resource development.

USGS World Petroleum Assessment 2000: New Conventional Provinces

USGS Publications Warehouse

Ahlbrandt, T.S.; Klett, T.R.

2000-01-01

The USGS has completed a new assessment of the undiscovered oil and gas resources of the world. One hundred and five geologic provinces were analyzed for assessment. Assessment units (AU) that comprise Total Petroleum Systems (TPS) were identified and described for each of these provinces. The AU served as the basis for assessing undiscovered petroleum within these provinces, 157 TPS and 270 AU were assessed. Some of data included in the assessment include the cumulative percent of world known petroleum volume by ranked oil and gas provinces; undiscovered NGL; reserve growth of the worlds largest oil and gas fields; and world potential reserve growth for oil/gas/NGL.

Vanadium Geochemistry of Oil Sands Fluid Petroleum Coke.

PubMed

Nesbitt, Jake A; Lindsay, Matthew B J

2017-03-07

Vanadium has previously been linked to elevated toxicity of leachates derived from oil sands petroleum coke. However, geochemical controls on V mobility within coke deposits remain poorly constrained. Detailed examinations of porewater and solid-phase V geochemistry were therefore performed on oil sands fluid petroleum coke deposits in Alberta, Canada. Sample collection focused on both active and reclaimed deposits, which contained more than 3 × 10 7 m 3 of fluid petroleum coke. Dissolved V concentrations were highest (up to 3.0 mg L -1 ) immediately below the water table but decreased rapidly with increasing depth. This trend corresponded to a transition from mildly acidic (pH 6-7) and oxic conditions to mildly alkaline (pH 7-8.5) and anoxic conditions. Scanning electron microscopy (SEM), electron microprobe analysis (EMPA), and micro-X-ray fluorescence (μXRF) mapping revealed coke particles exhibited an internal structure characterized by successive concentric layers. The outer margins of these layers were characterized by elevated V, Fe, Si, and Al concentrations, indicating the presence of inorganic phases. Micro-X-ray absorption near-edge structure (μXANES) spectroscopy revealed that V speciation was dominated by V(IV) porphyrins except at outer margins of layers, where octahedrally coordinated V(III) was a major component. Minor to trace V(V) was also detected within fluid petroleum coke particles.

State of energy consumption and CO2 emission in Bangladesh.

PubMed

Azad, Abul K; Nashreen, S W; Sultana, J

2006-03-01

Carbon dioxide (CO2) is one of the most important gases in the atmosphere, and is necessary for sustaining life on Earth. It is also considered to be a major greenhouse gas contributing to global warming and climate change. In this article, energy consumption in Bangladesh is analyzed and estimates are made of CO2 emission from combustion of fossil fuel (coal, gas, petroleum products) for the period 1977 to 1995. International Panel for Climate Change guidelines for national greenhouse gas inventories were used in estimating CO2 emission. An analysis of energy data shows that the consumption of fossil fuels in Bangladesh is growing by more than 5% per year. The proportion of natural gas in total energy consumption is increasing, while that of petroleum products and coal is decreasing. The estimated total CO2 release from all primary fossil fuels used in Bangladesh amounted to 5072 Gigagram (Gg) in 1977, and 14 423 Gg in 1995. The total amounts of CO2 released from petroleum products, natural gas, and coal in the period 1977-1995 were 83 026 Gg (50% of CO2 emission), 72 541 Gg (44% of CO2 emission), and 9545 Gg (6% CO2 emission), respectively. A trend in CO2 emission with projections to 2070 is generated. In 2070, total estimated CO2 emission will be 293 260 Gg with a current growth rate of 6.34% y . CO2 emission from fossil fuels is increasing. Petroleum products contribute the majority of CO2 emission load, and although the use of natural gas is increasing rapidly, its contribution to CO2 emission is less than that of petroleum products. The use of coal as well as CO2 emission from coal is expected to gradually decrease.

Effect of plant growth-promoting bacteria (PGPR) and arbuscular mycorrhizal fungi (AMF) inoculation on oats in saline-alkali soil contaminated by petroleum to enhance phytoremediation.

PubMed

Xun, Feifei; Xie, Baoming; Liu, Shasha; Guo, Changhong

2015-01-01

To investigate the effect of plant growth-promoting bacteria (PGPR) and arbuscular mycorrhizal fungi (AMF) on phytoremediation in saline-alkali soil contaminated by petroleum, saline-alkali soil samples were artificially mixed with different amount of oil, 5 and 10 g/kg, respectively. Pot experiments with oat plants (Avena sativa) were conducted under greenhouse condition for 60 days. Plant biomass, physiological parameters in leaves, soil enzymes, and degradation rate of total petroleum hydrocarbon were measured. The result demonstrated that petroleum inhibited the growth of the plant; however, inoculation with PGPR in combination with AMF resulted in an increase in dry weight and stem height compared with noninoculated controls. Petroleum stress increased the accumulation of malondialdehyde (MDA) and free proline and the activities of the antioxidant enzyme such as superoxide dismutase, catalase, and peroxidase. Application of PGPR and AMF augmented the activities of three enzymes compared to their respective uninoculated controls, but decreased the MDA and free proline contents, indicating that PGPR and AMF could make the plants more tolerant to harmful hydrocarbon contaminants. It also improved the soil quality by increasing the activities of soil enzyme such as urease, sucrase, and dehydrogenase. In addition, the degradation rate of total petroleum hydrocarbon during treatment with PGPR and AMF in moderately contaminated soil reached a maximum of 49.73%. Therefore, we concluded the plants treated with a combination of PGPR and AMF had a high potential to contribute to remediation of saline-alkali soil contaminated with petroleum.

Comparative study on conventional, ultrasonication and microwave assisted extraction of γ-oryzanol from rice bran.

PubMed

Kumar, Pramod; Yadav, Devbrat; Kumar, Pradyuman; Panesar, Paramjeet Singh; Bunkar, Durga Shankar; Mishra, Diwaker; Chopra, H K

2016-04-01

In present study, conventional, ultrasonic and microwave assisted extraction methods were compared with the aim of optimizing best fitting solvent and method, solvent concentration and digestion time for high yield of γ-oryzanol from rice bran. Petroleum ether, hexane and methanol were used to prepare extracts. Extraction yield were evaluated for giving high crude oil yield, total phenolic content (TPC) and γ-oryzanol content. Gas chromatography-mass spectrophotometry was used for the determination of γ-oryzanol concentration. The highest concentration of γ-oryzanol was detected in methanolic extracts of microwave treatment (85.0 ppm) followed by ultrasonication (82.0 ppm) and conventional extraction method (73.5 ppm). Concentration of γ-oryzanol present in the extracts was found to be directly proportional to the total phenolic content. A combination of 80 % methanolic concentration and 55 minutes digestion time of microwave treatment yielded the best extraction method for TPC and thus γ-oryzanol (105 ppm).

Antioxidant and antigenotoxic activities in Acacia salicina extracts and its protective role against DNA strand scission induced by hydroxyl radical.

PubMed

Chatti, Ines Bouhlel; Boubaker, Jihed; Skandrani, Ines; Bhouri, Wissem; Ghedira, Kamel; Chekir Ghedira, Leila

2011-08-01

The antioxidant potency of Acacia salicina extracts was investigated. Total antioxidant capacity was determined using an ABTS(+) assay. Superoxide radical scavenging was measured using riboflavin-light-nitro blue tetrazolium (NBT) assay. In addition, the content of phenols, total flavonoids and sterols were measured in the tested extracts. The petroleum ether exhibited a potent scavenging activity toward ABTS radical cations. Whereas, chloroform extract showed the highest activity against superoxides radicals and was also able to protect pKS plasmid DNA against hydroxyl radicals induced DNA damages. The antimutagenicity of these extracts was assayed using the Ames assay against Salmonella typhimurium TA98 and S. typhimurium TA 1535 tester strains at different concentrations. These extracts decreased significantly the mutagenecity induced by sodium azide (SA) and 4-nitro-o-phenylenediamine (NOP). The antioxidant and antimutagenecity activities exhibited by A. salicina depended on the chemical composition of the tested extracts. Copyright © 2011 Elsevier Ltd. All rights reserved.

Influence of fertilizer levels on phytoremediation of crude oil-contaminated soils with the tropical pasture grass Brachiaria brizantha (hochst. ex a. rich.) stapf.

PubMed

Merkl, Nicole; Schultze-Kraft, Rainer; Arias, Marianela

2005-01-01

Determination of fertilizer levels in phytoremediation of petroleum hydrocarbons is a complex issue, since nutrient demands of the plant and of degrading microorganisms in the rhizosphere have to be considered In the present work, three fertilizer levels were tested in a greenhouse experiment with the aim of optimizing growth of the tropical pasture grass Brachiaria brizantha and enhance microbial degradation of heavy crude oil in soil Fertilizer was applied twice in a concentration of 200, 300, and 400 mg each of N, P, and K per kg soil before and after the first sampling (14 wk). The medium fertilizer concentration resulted in best root growth and highest absolute oil dissipation (18.4%) after 22 wk The highest concentration produced best shoot growth and highest relative oil dissipation after 14 wk (10.5% less than unplanted control). In general, degradation of total oil and grease was higher in planted than in unplanted soil, but differences diminished toward the end of the experiment. Next to fertiizer quantity, its composition is an important factor to be further studied, including the form of available nitrogen (N-NO3- vs. N-NH4+). Field trials are considered indispensable for further phytoremediation studies, since greenhouse experiments produce particular water and nutrient conditions.

Emissions of particulate matter and associated polycyclic aromatic hydrocarbons from agricultural diesel engine fueled with degummed, deacidified mixed crude palm oil blends.

PubMed

Phoungthong, Khamphe; Tekasakul, Surajit; Tekasakul, Perapong; Prateepchaikul, Gumpon; Jindapetch, Naret; Furuuchi, Masami; Hata, Mitsuhiko

2013-04-01

Mixed crude palm oil (MCPO), the mixture of palm fiber oil and palm kernel oil, has become of great interest as a renewable energy source. It can be easily extracted from whole dried palm fruits. In the present work, the degummed, deacidified MCPO was blended in petroleum diesel at portions of 30% and 40% by volume and then tested in agricultural diesel engines for long-term usage. The particulates from the exhaust of the engines were collected every 500 hr using a four-stage cascade air sampler. The 50% cut-off aerodynamic diameters for the first three stages were 10, 2.5 and 1 microm, while the last stage collected all particles smaller than 1 microm. Sixteen particle bounded polycyclic aromatic hydrocarbons (PAHs) were analyzed using a high performance liquid chromatography. The results indicated that the size distribution of particulate matter was in the accumulation mode and the pattern of total PAHs associated with fine-particles (< 1 microm) showed a dominance of larger molecular weight PAHs (4-6 aromatic rings), especially pyrene. The mass median diameter, PM and total PAH concentrations decreased when increasing the palm oil content, but increased when the running hours of the engine were increased. In addition, Commercial petroleum diesel (PB0) gave the highest value of carcinogenic potency equivalent (BaP(eq)) for all particle size ranges. As the palm oil was increased, the BaP(eq) decreased gradually. Therefore the degummed-deacidified MCPO blends are recommended for diesel substitute.

The acute toxicity of chemically and physically dispersed crude oil to key arctic species under arctic conditions during the open water season

PubMed Central

Gardiner, William W; Word, Jack Q; Word, Jack D; Perkins, Robert A; McFarlin, Kelly M; Hester, Brian W; Word, Lucinda S; Ray, Collin M

2013-01-01

The acute toxicity of physically and chemically dispersed crude oil and the dispersant Corexit 9500 were evaluated for key Arctic species. The copepod Calanus glacialis, juvenile Arctic cod (Boreogadus saida), and larval sculpin (Myoxocephalus sp.) were tested under conditions representative of the Beaufort and Chukchi Seas during the ice-free season. The toxicity of 3 water-accommodated fractions (WAF) of Alaska North Slope crude oil was examined with spiked, declining exposures. A dispersant-only test was conducted with the copepod C. glacialis. Each preparation with oil (WAF, breaking wave WAF [BWWAF], and chemically enhanced WAF [CEWAF]) produced distinct suites of hydrocarbon constituents; the total concentrations of oil were lowest in WAF and highest in CEWAF preparations. The relative sensitivity for the different species and age classes was similar within each WAF type. Median lethal concentration values based on total petroleum hydrocarbons ranged from 1.6 mg/L to 4.0 mg/L for WAF and BWWAF treatments and from 22 mg/L to 62 mg/L for CEWAF. For Corexit 9500 exposures, median lethal concentration values ranged from 17 mg/L to 50 mg/L. The differences in the relative toxicity among the accommodated fractions indicated that the majority of petroleum hydrocarbons in the CEWAF are in less acutely toxic forms than the components that dominate the WAF or BWWAF. Further evaluation showed that the parent polycyclic aromatic hydrocarbon compounds, specifically naphthalene, were highly correlated to acute toxicity. Environ Toxicol Chem 2013;32:2284–2300. PMID:23765555

Do your extractable TPH concentrations represent dissolved petroleum? An update on applied research

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zemo, D.A.

1997-12-31

Elevated concentrations of {open_quotes}dissolved-phase{close_quotes} extractable total petroleum hydrocarbons (TPH) in groundwater samples can be a significant impediment to site closure in states that regulate groundwater using TPH criteria. These analytical results are inconsistent with petroleum chemistry because of the relatively low water solubility of petroleum products. This paper presents an update of our research into the source of medium- to high-boiling TPH detections in groundwater samples and application of the results to multiple projects. This work follows from a 1995 publication in which positive interferences to the Method 8015M (GC-FID) TPH measurement by soluble, non-petroleum hydrocarbons resulting from intrinsic bioremediationmore » or non-dissolved petroleum adhered to particulates was described. The 1995 paper was largely theoretical and focused on one case study. Since 1995, we have evaluated the source of TPH detections in groundwater at numerous petroleum sites and have demonstrated the significance of interferences to the Method 8015M measurement to the California regulatory community. Our work has shown conclusively that elevated concentrations of extractable TPH are not representative of dissolved petroleum constituents. We have shown that a sample cleanup prior to analysis using silica gel cleanup (to remove polar non-petroleum hydrocarbons) and/or laboratory filtration (to reduce petroleum-affected particulates) is required to overcome the false positives caused by interferences to the Method 8015M measurement.« less

Material-balance assessment of the New Albany-Chesterian petroleum system of the Illinois basin

USGS Publications Warehouse

Lewan, M.D.; Henry, M.E.; Higley, D.K.; Pitman, Janet K.

2002-01-01

The New Albany-Chesterian petroleum system of the Illinois basin is a well-constrained system from which petroleum charges and losses were quantified through a material-balance assessment. This petroleum system has nearly 90,000 wells penetrating the Chesterian section, a single New Albany Shale source rock accounting for more than 99% of the produced oil, well-established stratigraphic and structural frameworks, and accessible source rock samples at various maturity levels. A hydrogen index (HI) map based on Rock-Eval analyses of source rock samples of New Albany Shale defines the pod of active source rock and extent of oil generation. Based on a buoyancy-drive model, the system was divided into seven secondary-migration catchments. Each catchment contains a part of the active pod of source rock from which it derives a petroleum charge, and this charge is confined to carrier beds and reservoirs within these catchments as accountable petroleum, petroleum losses, or undiscovered petroleum. A well-constrained catchment with no apparent erosional or leakage losses is used to determine an actual petroleum charge from accountable petroleum and residual migration losses. This actual petroleum charge is used to calibrate the other catchments in which erosional petroleum losses have occurred. Petroleum charges determined by laboratory pyrolysis are exaggerated relative to the actual petroleum charge. Rock-Eval charges are exaggerated by a factor of 4-14, and hydrouspyrolysis charges are exaggerated by a factor of 1.7. The actual petroleum charge provides a more meaningful material balance and more realistic estimates of petroleum losses and remaining undiscovered petroleum. The total petroleum charge determined for the New Albany-Chesterian system is 78 billion bbl, of which 11.4 billion bbl occur as a accountable in place petroleum, 9 billion bbl occur as residual migration losses, and 57.6 billion bbl occur as erosional losses. Of the erosional losses, 40 billion bbl were lost from two catchments that have highly faulted and extensively eroded sections. Anomalies in the relationship between erosional losses and degree of erosion suggest there is potential for undiscovered petroleum in one of the catchments. These results demonstrate that a material-balance assessment of migration catchments provides a useful means to evaluate and rank areas within a petroleum system. The article provides methodologies for obtaining more realistic petroleum charges and losses that can be applied to less data-rich petroleum systems.

The effect of soil type on the bioremediation of petroleum contaminated soils.

PubMed

Haghollahi, Ali; Fazaelipoor, Mohammad Hassan; Schaffie, Mahin

2016-09-15

In this research the bioremediation of four different types of contaminated soils was monitored as a function of time and moisture content. The soils were categorized as sandy soil containing 100% sand (type I), clay soil containing more than 95% clay (type II), coarse grained soil containing 68% gravel and 32% sand (type III), and coarse grained with high clay content containing 40% gravel, 20% sand, and 40% clay (type IV). The initially clean soils were contaminated with gasoil to the concentration of 100 g/kg, and left on the floor for the evaporation of light hydrocarbons. A full factorial experimental design with soil type (four levels), and moisture content (10 and 20%) as the factors was employed. The soils were inoculated with petroleum degrading microorganisms. Soil samples were taken on days 90, 180, and 270, and the residual total petroleum hydrocarbon (TPH) was extracted using soxhlet apparatus. The moisture content of the soils was kept almost constant during the process by intermittent addition of water. The results showed that the efficiency of bioremediation was affected significantly by the soil type (Pvalue < 0.05). The removal percentage was the highest (70%) for the sandy soil with the initial TPH content of 69.62 g/kg, and the lowest for the clay soil (23.5%) with the initial TPH content of 69.70 g/kg. The effect of moisture content on bioremediation was not statistically significant for the investigated levels. The removal percentage in the clay soil was improved to 57% (within a month) in a separate experiment by more frequent mixing of the soil, indicating low availability of oxygen as a reason for low degradation of hydrocarbons in the clay soil. Copyright © 2016 Elsevier Ltd. All rights reserved.

Comparison of the relative sensitivity of Arctic species to dispersed oil using total petroleum and PAH measures of toxicity

EPA Science Inventory

Extended periods of open water have expanded the potential opportunities for petroleum and gas exploration and production in the Arctic, increasing the focus on understanding the potential impacts of released oil on aquatic organisms. However, information regarding the toxicity o...

Occurrence, source and ecological assessment of baseline hydrocarbons in the intertidal marine sediments along the shoreline of Douglas Channel to Hecate Strait in British Columbia.

PubMed

Yang, Zeyu; Hollebone, Bruce P; Laforest, Sonia; Lambert, Patrick; Brown, Carl E; Yang, Chun; Shah, Keval; Landriault, Mike; Goldthorp, Michael

2017-09-15

The occurrence, source and ecological assessment of baseline hydrocarbons in the intertidal zone along the northern British shoreline were evaluated based on analyzing total petroleum hydrocarbons (TPH), n-alkanes, petroleum related biomarkers such as terpanes and steranes, and polycyclic aromatic hydrocarbons (PAHs) including non-alkylated and alkylated homologues (APAHs). The TPH levels, n-alkanes, petroleum biomarkers and PAHs in all the sampling sites, except for Masset Harbor/York Point at Gil Island were low, without obvious unresolved complex mixture (UCM) and petroleum contamination input. Specifically, n-alkanes showed a major terrestrial plants input; PAHs with abundant non-alkylated PAHs but minor APAHs showed a major pyrogenic input. However, obvious petroleum-derived hydrocarbons have impacted Masset Harbor. A historical petroleum input was found in York Point at Gil Island, due to the presence of the low level of petroleum biomarkers. Ecological assessment of 13 non-alkylated PAHs in Masset Harbor indicated no potential toxicity to the benthic organisms. Copyright © 2017 Elsevier Ltd. All rights reserved.

Role of nutrients and illuminance in predicting the fate of fungal mediated petroleum hydrocarbon degradation and biomass production.

PubMed

Ali Khan, Aqib Hassan; Tanveer, Sundus; Anees, Mariam; Muhammad, Yousaf Shad; Iqbal, Mazhar; Yousaf, Sohail

2016-07-01

Biodegradation and biomass production are affected by numerous environmental factors including pH, oxygen availability and presence of pollutants. The present study, for the first time, elucidated the effects of nutrients and light on mycodegradation of petroleum hydrocarbons in diesel oil. Seven fungal strains (Aspergillus terreus FA3, Aspergillus niger FA5, Aspergillus terreus FA6, Penicillium chrysogenum FP4, Aspergillus terreus FP6, Aspergillus flavus FP10, and Candida sp. FG1) were used for hydrocarbon degradation under static conditions, in four combinations of nutrient media and illuminance for 45 days. Highest degradation was achieved by Aspergillus terreus FA6 and Candida sp. FG1 under both conditions of light and dark, with nutrient deprived HAF (Hydrocarbon adopted fungi) broth. Under HAF/Dark diesel oil degradation by FA6 and FG1 was 87.3% and 84.3% respectively, while under HAF/Light both FA6 and FG1 performed 84.3% biodegradation. The highest biomass was produced by Aspergillus flavus FP10 in PDB (Potato dextrose broth)/Dark (109.3 mg). Fungal degradation of petroleum hydrocarbons was negatively affected by the presence of other simpler-to-degrade carbon sources in the medium. The biomass production was enhanced by improved nutrient availability and diminished by illuminance. Copyright © 2016 Elsevier Ltd. All rights reserved.

Mesozoic non-marine petroleum source rocks determined by palynomorphs in the Tarim Basin, Xinjiang, northwestern China

USGS Publications Warehouse

Jiang, D.-X.; Wang, Y.-D.; Robbins, E.I.; Wei, J.; Tian, N.

2008-01-01

The Tarim Basin in Northwest China hosts petroleum reservoirs of Cambrian, Ordovician, Carboniferous, Triassic, Jurassic, Cretaceous and Tertiary ages. The sedimentary thickness in the basin reaches about 15 km and with an area of 560000 km2, the basin is expected to contain giant oil and gas fields. It is therefore important to determine the ages and depositional environments of the petroleum source rocks. For prospective evaluation and exploration of petroleum, palynological investigations were carried out on 38 crude oil samples collected from 22 petroleum reservoirs in the Tarim Basin and on additionally 56 potential source rock samples from the same basin. In total, 173 species of spores and pollen referred to 80 genera, and 27 species of algae and fungi referred to 16 genera were identified from the non-marine Mesozoic sources. By correlating the palynormorph assemblages in the crude oil samples with those in the potential source rocks, the Triassic and Jurassic petroleum source rocks were identified. Furthermore, the palynofloras in the petroleum provide evidence for interpretation of the depositional environments of the petroleum source rocks. The affinity of the miospores indicates that the petroleum source rocks were formed in swamps in brackish to lacustrine depositional environments under warm and humid climatic conditions. The palynomorphs in the crude oils provide further information about passage and route of petroleum migration, which is significant for interpreting petroleum migration mechanisms. Additionally, the thermal alternation index (TAI) based on miospores indicates that the Triassic and Jurassic deposits in the Tarim Basin are mature petroleum source rocks. ?? Cambridge University Press 2008.

Antioxidant, antibacterial, cytotoxic, and apoptotic activity of stem bark extracts of Cephalotaxus griffithii Hook. f.

PubMed

Moirangthem, Dinesh Singh; Talukdar, Narayan Chandra; Kasoju, Naresh; Bora, Utpal

2012-04-03

Cephalotaxus spp. are known to possess various therapeutic potentials. Cephalotaxus griffithii, however, has not been evaluated for its biological potential. The reason may be the remoteness and inaccessibility of the habitat where it is distributed. The main aim of this study was to: (1) evaluate multiple biological potentials of stem bark of C. griffithii, and (2) identify solvent extract of stem bark of C. griffithii to find the one with the highest specific biological activity. Dried powder of stem bark of C. griffithii was exhaustively extracted serially by soaking in petroleum ether, acetone and methanol to fractionate the chemical constituents into individual fractions or extracts. The extracts were tested for total phenolic and flavonoid content, antioxidant (DPPH radical scavenging, superoxide radical scavenging, and reducing power models), antibacterial (disc diffusion assay on six bacterial strains), cytotoxic (MTT assay on HeLa cells), and apoptotic activity (fluorescence microscopy, DNA fragmentation assay, and flow cytometry on HeLa cells). Among the three extracts of stem bark of C. griffithii, the acetone extract contained the highest amount of total phenolics and flavonoids and showed maximum antioxidant, antibacterial, cytotoxic (IC50 of 35.5 ± 0.6 μg/ml; P < 0.05), and apoptotic (46.3 ± 3.6% sub-G0/G1 population; P < 0.05) activity, followed by the methanol and petroleum ether extracts. However, there was no significant difference observed in IC50 values (DPPH scavenging assay) of the acetone and methanol extracts and the positive control (ascorbic acid). In contrast, superoxide radical scavenging assay-based antioxidant activity (IC50) of the acetone and methanol extracts was significantly lower than the positive control (P < 0.05). Correlation analysis suggested that phenolic and flavonoid content present in stem bark of C. griffithii extracts was responsible for the high antioxidant, cytotoxic, and apoptotic activity (P < 0.05). Stem bark of C. griffithii has multiple biological effects. These results call for further chemical characterization of acetone extract of stem bark of C. griffithii for specific bioactivity.

In-vitro alpha amylase inhibitory activity of the leaf extracts of Adenanthera pavonina.

PubMed

Wickramaratne, M Nirmali; Punchihewa, J C; Wickramaratne, D B M

2016-11-15

Diabetes has caused a major burden to the health sector in the developing countries and has shown an increasing trend among the urban population. It is estimated that most patients are with type II diabetes which could be easily treated with dietary changes, exercise, and medication. Sri Lanka carries a long history ayurvedic medicine where it uses the plant for treating many diseases. Therefore it is important to screen medicinal plants scientifically so they could be used safely and effectively in the traditional medical system and also be used for further investigations. Adenanthera pavonina is a plant used in the Ayurvedic medical system in Sri Lanka for treating many diseases including diabetics. We evaluated the anti-diabetic properties and the antioxidant properties of Adenanthera pavonina leaves. The methanol extract of the leaves was sequentially extracted with petroleum ether and thereafter was partitioned between EtOAc, and water. The α-amylase inhibition assay was performed using the 3,5- dinitrosalicylic acid method. The antioxidant activities were measured using the DPPH free radical scavenging activity and the total phenolic content using Folin-Ciocalteu's reagent. The cytotoxicity of the extract was evaluated using the Brine shrimp bioassay. The IC 50 values of α amylase inhibitory activity of MeOH, EtOAc, petroleum ether, and water were 16.16 ± 2.23, 59.93 ± 0.25, 145.49 ± 4.86 and 214.85 ± 9.72 μg/ml respectively and was similar to that of Acarbose (18.63 ± 1.21 (μg/ml). Antioxidant activities were also determined and the EtOAc fraction showed the highest total phenolic content (34. 62 ± 1.14 mg/g extract) and the highest DPPH scavenging activity with an IC 50 of 249.92 ± 3.35 μg/ml. The leaf extracts of Adenanthera pavonina exhibit remarkable α-amylase inhibitory activity in the crude methanolic extract. Hence leaves of Adenanthera pavonina has a potential to be used as a regular green vegetable and also be investigated further in isolating pure compounds with anti-diabetic activity.

Geologic Assessment of Undiscovered, Technically Recoverable Coalbed-Gas Resources in Cretaceous and Tertiary Rocks, North Slope and Adjacent State Waters, Alaska

USGS Publications Warehouse

Roberts, Stephen B.

2008-01-01

The purpose of the U.S. Geological Survey's (USGS) National Oil and Gas Assessment is to develop geology-based hypotheses regarding the potential for additions to oil and gas reserves in priority areas of the United States, focusing on the distribution, quantity, and availability of oil and natural gas resources. The USGS has completed an assessment of the undiscovered, technically recoverable coalbed-gas resources in Cretaceous and Tertiary rocks underlying the North Slope and adjacent State waters of Alaska (USGS Northern Alaska Province 5001). The province is a priority Energy Policy and Conservation Act (EPCA) province for the National Assessment because of its potential for oil and gas resources. The assessment of this province is based on geologic principles and uses the total petroleum system concept. The geologic elements of a total petroleum system include hydrocarbon source rocks (source rock maturation, hydrocarbon generation and migration), reservoir rocks (stratigraphy, sedimentology, petrophysical properties), and hydrocarbon traps (trap formation and timing). In the Northern Alaska Province, the USGS used this geologic framework to define one composite coalbed gas total petroleum system and three coalbed gas assessment units within the petroleum system, and quantitatively estimated the undiscovered coalbed-gas resources within each assessment unit.

Ecotoxicity monitoring and bioindicator screening of oil-contaminated soil during bioremediation.

PubMed

Shen, Weihang; Zhu, Nengwu; Cui, Jiaying; Wang, Huajin; Dang, Zhi; Wu, Pingxiao; Luo, Yidan; Shi, Chaohong

2016-02-01

A series of toxicity bioassays was conducted to monitor the ecotoxicity of soils in the different phases of bioremediation. Artificially oil-contaminated soil was inoculated with a petroleum hydrocarbon-degrading bacterial consortium containing Burkholderia cepacia GS3C, Sphingomonas GY2B and Pandoraea pnomenusa GP3B strains adapted to crude oil. Soil ecotoxicity in different phases of bioremediation was examined by monitoring total petroleum hydrocarbons, soil enzyme activities, phytotoxicity (inhibition of seed germination and plant growth), malonaldehyde content, superoxide dismutase activity and bacterial luminescence. Although the total petroleum hydrocarbon (TPH) concentration in soil was reduced by 64.4%, forty days after bioremediation, the phytotoxicity and Photobacterium phosphoreum ecotoxicity test results indicated an initial increase in ecotoxicity, suggesting the formation of intermediate metabolites characterized by high toxicity and low bioavailability during bioremediation. The ecotoxicity values are a more valid indicator for evaluating the effectiveness of bioremediation techniques compared with only using the total petroleum hydrocarbon concentrations. Among all of the potential indicators that could be used to evaluate the effectiveness of bioremediation techniques, soil enzyme activities, phytotoxicity (inhibition of plant height, shoot weight and root fresh weight), malonaldehyde content, superoxide dismutase activity and luminescence of P. phosphoreum were the most sensitive. Copyright © 2015 Elsevier Inc. All rights reserved.

Health Effects of Cut Gas Lines and Other Petroleum Product Release Incidents - Seven States, 2010-2012.

PubMed

Anderson, Ayana R

2015-06-12

Large mass casualty gas explosions and catastrophic oil spills are widely reported and receive considerable regulatory attention. Smaller, less catastrophic petroleum product releases are less likely to receive publicity, although study of these incidents might help focus and prioritize prevention efforts. To describe the causes and health impacts of petroleum product release incidents (including gas explosions and oil spills), the Agency for Toxic Substances and Disease Registry (ATSDR) analyzed 2010-2012 data from the National Toxic Substance Incidents Program (NTSIP). A total of 1,369 petroleum product release incidents were reported from seven states, resulting in 512 injuries and 36 deaths. Approximately one fourth of the incidents were associated with utilities, and approximately one fifth were associated with private vehicles or residences. Approximately 10% of petroleum product releases resulted from inadvertent damage to utility lines. Understanding the characteristics of acute petroleum product releases can aid the public and utility workers in the development of preventive strategies and reduce the morbidity and mortality associated with such releases.

Risk-Based Evaluation of Total Petroleum Hydrocarbons in Vapor Intrusion Studies

PubMed Central

Brewer, Roger; Nagashima, Josh; Kelley, Michael; Heskett, Marvin; Rigby, Mark

2013-01-01

This paper presents a quantitative method for the risk-based evaluation of Total Petroleum Hydrocarbons (TPH) in vapor intrusion investigations. Vapors from petroleum fuels are characterized by a complex mixture of aliphatic and, to a lesser extent, aromatic compounds. These compounds can be measured and described in terms of TPH carbon ranges. Toxicity factors published by USEPA and other parties allow development of risk-based, air and soil vapor screening levels for each carbon range in the same manner as done for individual compounds such as benzene. The relative, carbon range makeup of petroleum vapors can be used to develop weighted, site-specific or generic screening levels for TPH. At some critical ratio of TPH to a targeted, individual compound, the overwhelming proportion of TPH will drive vapor intrusion risk over the individual compound. This is particularly true for vapors associated with diesel and other middle distillate fuels, but can also be the case for low-benzene gasolines or even for high-benzene gasolines if an adequately conservative, target risk is not applied to individually targeted chemicals. This necessitates a re-evaluation of the reliance on benzene and other individual compounds as a stand-alone tool to evaluate vapor intrusion risk associated with petroleum. PMID:23765191

Assessment of three approaches of bioremediation (Natural Attenuation, Landfarming and Bioagumentation - Assistited Landfarming) for a petroleum hydrocarbons contaminated soil.

PubMed

Guarino, C; Spada, V; Sciarrillo, R

2017-03-01

Contamination with total petroleum hydrocarbons (TPH) subsequent to refining activities, is currently one of the major environmental problems. Among the biological remediation approaches, landfarming and in situ bioremediation strategies are of great interest. Purpose of this study was to verify the feasibility of a remediation process wholly based on biological degradation applied to contaminated soils from a decommissioned refinery. This study evaluated through a pot experiment three bioremediation strategies: a) Natural Attenuation (NA), b) Landfarming (L), c) Bioaugmentation-assisted Landfarming (LB) for the treatment of a contaminated soil with petroleum hydrocarbons (TPHs). After a 90-days trial, Bioagumentation - assistited Landfarming approach produced the best results and the greatest evident effect was shown with the most polluted samples reaching a reduction of about 86% of total petroleum hydrocarbons (TPH), followed by Landfarming (70%), and Natural Attenuation (57%). The results of this study demonstrated that the combined use of bioremediation strategies was the most advantageous option for the treatment of contaminated soil with petroleum hydrocarbons, as compared to natural attenuation, bioaugmentation or landfarming applied alone. Besides, our results indicate that incubation with an autochthonous bacterial consortium may be a promising method for bioremediation of TPH-contaminated soils. Copyright © 2016 Elsevier Ltd. All rights reserved.

Characteristics of petroleum contaminants and their distribution in Lake Taihu, China.

PubMed

Guo, Jixiang; Fang, Jia; Cao, Jingjing

2012-08-31

Taihu Lake is a typical plain eutrophic shallow lake. With rapidly economic development of the lake area, the petroleum products and oil wastewater produced in various processes have been inevitably discharged into Taihu Lake. As the major fresh water resource in the economically developed region of Yangtze River Delta, the water quality and environmental condition of Taihu Lake have the direct bearing on the natural environment and sustainable development of economy in this region. For this reason we carried out the study to explore the composition, distribution characteristics and sources of petroleum contaminants in Taihu Lake. The aim of this study was to provide the basis for standard management and pollution control of the Taihu Lake environment. The result showed that water samples from near industrial locations were of relatively higher petroleum contaminants concentrations. The oil pollutants concentrations in different areas of Lake Taihu ranged from 0.106 mg/L to 1.168 mg/L, and the sequence of total contents distribution characteristics of petroleum pollutants from high to low in different regions of Taihu Lake was: "Dapu", "Xiaomeikou", "Zhushan Bay", "Lake center", "Qidu". The results showed that total concentrations of n-alkanes and PAHs ranged from 0.045 to 0.281 mg/L and from 0.011 to 0.034 mg/L respectively. In the same region, the concentrations of hydrocarbon pollutants in the surface and bottom of the lake were higher than that in the middle. This paper reached a conclusion that the petroleum contaminants in Taihu Lake mainly derived from petroleum pollution caused by human activities as indicated by OEP, bimodal distribution, CPI, Pr/Ph ratio, the LMW/HMW ratio and other evaluation indices for sources of n-alkanes and polycyclic aromatic hydrocarbons (PAHs).

National Assessment of Oil and Gas Project: Geologic Assessment of Undiscovered Oil and Gas Resources of the Eastern Great Basin Province, Nevada, Utah, Idaho, and Arizona

USGS Publications Warehouse

,

2007-01-01

Introduction The purpose of the U.S. Geological Survey's (USGS) National Oil and Gas Assessment is to develop geologically based hypotheses regarding the potential for additions to oil and gas reserves in priority areas of the United States. The U.S. Geological Survey (USGS) recently completed an assessment of the undiscovered oil and gas potential of the Eastern Great Basin Province of eastern Nevada, western Utah, southeastern Idaho, and northwestern Arizona. This assessment is based on geologic principles and uses the total petroleum system concept. The geologic elements of a total petroleum system include hydrocarbon source rocks (source rock maturation, hydrocarbon generation and migration), reservoir rocks (sequence stratigraphy and petrophysical properties), and hydrocarbon traps (trap formation and timing). The USGS used this geologic framework to define one total petroleum system and three assessment units. All three assessment units were quantitatively assessed for undiscovered oil and gas resources.

Biodegradation of total organic carbons (TOC) in Jordanian petroleum sludge.

PubMed

Mrayyan, Bassam; Battikhi, Mohammed N

2005-04-11

Biodegradation is cost-effective, environmentally friendly treatment for oily contaminated sites by the use of microorganisms. In this study, laboratory experiments were conducted to establish the performance of bacterial isolates in degradation of organic compounds contained in oily sludge from the Jordanian Oil Refinery plant. As a result of the laboratory screening, three natural bacterial consortia capable of degrading total organic carbons (TOC) were prepared from isolates enriched from the oil sludge. Experiments were conducted in Erlenmeyer flasks under aerobic conditions, with TOC removal percentage varied from 0.3 to 28% depending on consortia type and concentration. Consortia 7B and 13B exhibited the highest TOC removal percentage of 28 and 22%, respectively, before nutrient addition. TOC removal rate was enhanced after addition of nutrients to incubated flasks. The highest TOC reduction (43%) was estimated after addition of combination of nitrogen, phosphorus and sulphur to consortia 7B. A significant variation (P<0.005) was observed between the effect of consortia type and concentration on TOC% reduction. No significant variation was observed between incubation at 10 and 18 days in TOC% reduction. This is the first report concerning biological treatment of TOC by bacteria isolated from the oil refinery plants, where it lays the ground for full integrated studies recommended for the degradation of organic compounds that assist in solving sludge problems.

Larvicidal Activity of Centaurea bruguierana ssp. belangerana Against Anopheles stephensi Larvae.

PubMed

Khanavi, Mahnaz; Rajabi, Afsaneh; Behzad, Masoud; Hadjiakhoondi, Abbas; Vatandoost, Hassan; Abaee, Mohammad Reza

2011-01-01

In this study, the total 80% of MeOH extract and also petroleum ether, CHCl3, EtOAc, n-BuOH, and the remaining MeOH fractions obtained by solvent-solvent fractionation of the whole flowering samples of Centaurea bruguierana (DC.) Hand.-Mzt. ssp. belangerana (DC.) Bornm. (Asteraceae), namely "Baad-Avard", collected from Borazjan in Bushehr Province (Bushehr, Iran) were investigated for larvicidal activity against malaria vector, Anopheles stephensi Liston, according to WHO methods. The mortality rate of total extract and petroleum ether fraction in concentration of 40 ppm were 28% and 86% respectively and the other fractions were inactive. The probit regression analysis for the dose-response to petroleum ether fraction treatment of larvae exhibited the LC50 and LC90 values of 15.7 ppm and 48.3 ppm, respectively. As results showed, the larvicidal activity of the petroleum ether fraction would be due to the nonpolar compounds in the plant which further isolation and purification would obtain the more active compounds in lower concentrations useful for preparation of biological insecticides.

Larvicidal Activity of Centaurea bruguierana ssp. belangerana Against Anopheles stephensi Larvae

PubMed Central

Khanavi, Mahnaz; Rajabi, Afsaneh; Behzad, Masoud; Hadjiakhoondi, Abbas; Vatandoost, Hassan; Abaee, Mohammad Reza

2011-01-01

In this study, the total 80% of MeOH extract and also petroleum ether, CHCl3, EtOAc, n-BuOH, and the remaining MeOH fractions obtained by solvent-solvent fractionation of the whole flowering samples of Centaurea bruguierana (DC.) Hand.-Mzt. ssp. belangerana (DC.) Bornm. (Asteraceae), namely “Baad-Avard”, collected from Borazjan in Bushehr Province (Bushehr, Iran) were investigated for larvicidal activity against malaria vector, Anopheles stephensi Liston, according to WHO methods. The mortality rate of total extract and petroleum ether fraction in concentration of 40 ppm were 28% and 86% respectively and the other fractions were inactive. The probit regression analysis for the dose-response to petroleum ether fraction treatment of larvae exhibited the LC50 and LC90 values of 15.7 ppm and 48.3 ppm, respectively. As results showed, the larvicidal activity of the petroleum ether fraction would be due to the nonpolar compounds in the plant which further isolation and purification would obtain the more active compounds in lower concentrations useful for preparation of biological insecticides. PMID:24250419

Study utilization of extractable petroleum hydrocarbons biodegradation waste as the main material for making solid fuels

NASA Astrophysics Data System (ADS)

Hendrianie, Nuniek; Juliastuti, Sri Rachmania; Ar-rosyidah, Fanny Husna; Rochman, Hilal Abdur

2017-05-01

Nowadays the existence of energy sources of oil and was limited. Therefore, it was important to searching for new innovations of renewable energy sources by utilizing the waste into a source of energy. On the other hand, the process of extractable petroleum hydrocarbons biodegradation generated sludge that had calorific value and untapped. Because of the need for alternative sources of energy innovation with the concept of zero waste and the fuel potential from extractable petroleum hydrocarbons biodegradation waste, so it was necessary to study the use of extractable petroleum hydrocarbons biodegradation waste as the main material for making solid fuel. In addition, sawdust is a waste that had a great quantities and also had a high calorific value to be mixed with extractable petroleum hydrocarbons biodegradation waste. The purpose of this study was to determine the characteristics of the extractable petroleum hydrocarbons biodegradation waste and to determine the potential and a combination of a mixture of extractable petroleum hydrocarbons biodegradation waste and sawdust which has the best calorific value. The variables of this study was the composition of the waste and sawdust as follows 1:1; 1:3; and 3:1 (mass of sawdust : mass of waste) and time of sawdust carbonization was 10, 15 and 20 minutes. Sawdust was carbonized to get the high heating value. The characteristic of main material and fuel analysis performed with proximate analysis. While the calorific value analysis was performed with a bomb calorimeter. From the research, it was known that extractable petroleum hydrocarbons biodegradation waste had a moisture content of 3.06%; volatile matter 19.98%; ash content of 0.56%; fixed carbon content of 76.4% and a calorific value of 717 cal/gram. And a mixture that had the highest calorific value (4286.5 cal/gram) achieved in comparison sawdust : waste (3:1) by carbonization of sawdust for 20 minutes.

Biodegradable and Petroleum-Based Microplastics Do Not Differ in Their Ingestion and Excretion but in Their Biological Effects in a Freshwater Invertebrate Gammarus fossarum

PubMed Central

Straub, Sandrine; Hirsch, Philipp E.; Burkhardt-Holm, Patricia

2017-01-01

Research on the uptake and effects of bioplastics by aquatic organisms is still in its infancy. Here, we aim to advance the field by comparing uptake and effects of microplastic particles (MPP) of a biodegradable bioMPP (polyhydroxybutyrate (PHB)) and petroleum-based MPP (polymethylmethacrylate (PMMA)) in the freshwater amphipod Gammarus fossarum. Ingestion of both MPP in different particle sizes (32–250 µm) occurred after 24 h, with highest ingestion of particles in the range 32–63 µm and almost complete egestion after 64 h. A four-week effect-experiment showed a significant decrease of the assimilation efficiency in amphipods exposed to the petroleum-based MPP from week two onwards. The petroleum-based PMMA affected assimilation efficiency significantly in contrast to the biodegradable PHB, but overall differences in direct comparison of MPP types were small. Both MPP types led to a significantly lower wet weight gain relative to the control treatments. After four weeks, differences between both MPP types and silica, used as a natural particle control, were detected. In summary, these results suggest that both MPP types provoke digestive constraints on the amphipods, which go beyond those of natural non-palatable particles. This highlights the need for more detailed research comparing environmental effects of biodegradable and petroleum-based MPP and testing those against naturally occurring particle loads. PMID:28703776

Bioremediation and reclamation of soil contaminated with petroleum oil hydrocarbons by exogenously seeded bacterial consortium: a pilot-scale study.

PubMed

Mukherjee, Ashis K; Bordoloi, Naba K

2011-03-01

Spillage of petroleum hydrocarbons causes significant environmental pollution. Bioremediation is an effective process to remediate petroleum oil contaminant from the ecosystem. The aim of the present study was to reclaim a petroleum oil-contaminated soil which was unsuitable for the cultivation of crop plants by using petroleum oil hydrocarbon-degrading microbial consortium. Bacterial consortium consisting of Bacillus subtilis DM-04 and Pseudomonas aeruginosa M and NM strains were seeded to 20% (v/w) petroleum oil-contaminated soil, and bioremediation experiment was carried out for 180 days under laboratory condition. The kinetics of hydrocarbon degradation was analyzed using biochemical and gas chromatographic (GC) techniques. The ecotoxicity of the elutriates obtained from petroleum oil-contaminated soil before and post-treatment with microbial consortium was tested on germination and growth of Bengal gram (Cicer aretinum) and green gram (Phaseolus mungo) seeds. Bacterial consortium showed a significant reduction in total petroleum hydrocarbon level in contaminated soil (76% degradation) as compared to the control soil (3.6% degradation) 180 days post-inoculation. The GC analysis confirmed that bacterial consortium was more effective in degrading the alkane fraction compared to aromatic fraction of crude petroleum oil hydrocarbons in soil. The nitrogen, sulfur, and oxygen compounds fraction was least degraded. The reclaimed soil supported the germination and growth of crop plants (C. aretinum and P. mungo). In contrast, seeds could not be germinated in petroleum oil-contaminated soil. The present study reinforces the application of bacterial consortium rather than individual bacterium for the effective bioremediation and reclamation of soil contaminated with petroleum oil.

Estimating usable resources from historical industry data.

USGS Publications Warehouse

Cargill, S.M.; Root, D.H.; Bailey, E.H.

1981-01-01

The commodities considered are mercury, copper and its byproducts gold and silver, and petroleum; the production and discovery data are for the US. The results indicate that the cumulative return per unit of effort, herein measured as grade of metal ores and discovery rate of recoverable petroleum, is proportional to a negative power of total effort expended, herein measured as total ore mined and total exploratory wells or footage drilled. This power relationship can be extended to some limiting point (a lower ore grade or a maximum number of exploratory wells or footage), and the apparent quantity of available remaining resource at that limit can be calculated. -from Authors

Ghaba salt basin province and Fahud salt basin province, Oman; geological overview and total petroleum systems

USGS Publications Warehouse

Pollastro, R.M.

1999-01-01

Three Total Petroleum Systems each consisting of one assessment unit have been identified in the Ghaba and Fahud Salt Basin Provinces of north-central Oman. One Total Petroleum System and corresponding assessment unit, the North Oman Huqf/`Q'? Haushi(!) Total Petroleum System (201401) and Ghaba-Makarem Combined Structural Assessment Unit (20140101), were identified for the Ghaba Salt Basin Province (2014). In the Fahud Salt Basin Province, however, two overlapping Total Petroleum Systems (TPS) were recognized: 1) the North Oman Huqf ? Shu'aiba(!) TPS (201601); Fahud-Huqf Combined Structural Assessment Unit (20160101), and 2) the Middle Cretaceous Natih(!) TPS (201602); Natih-Fiqa Structural/Stratigraphic Assessment Unit (20160201). The boundary for each Total Petroleum System also defines the boundary of the corresponding assessment unit and includes all trap styles and hydrocarbon producing reservoirs within the petroleum system. In both the Ghaba and Fahud Salt Basin Provinces, hydrocarbons were generated from several deeply-buried source rocks within the Infracambrian Huqf Supergroup. One general `North Oman Huqf' type oil is dominant in the Fahud Salt Basin. Oils in the Ghaba Salt Basin are linked to at least two distinct Huqf source-rock units based on oil geochemistry: a general North Oman Huqf-type oil source and a more dominant `questionable unidentified-source' or `Q'-type Huqf oil source. These two Huqf-sourced oils are commonly found as admixtures in reservoirs throughout north-central Oman. Hydrocarbons generated from Huqf sources are produced from a variety of reservoir types and ages ranging from Precambrian to Cretaceous in both the Ghaba and Fahud Salt Basin Provinces. Clastic reservoirs of the Gharif and Al Khlata Formations, Haushi Group (M. Carboniferous to L. Permian), dominate oil production in the Ghaba Salt Basin Province and form the basis for the Huqf/`Q' ? Haushi(!) TPS. In contrast, the Lower Cretaceous Shu'aiba and Middle Cretaceous Natih limestones account for most of the production in the Fahud Salt Basin with about 50 percent of the basin's production from porous, fractured Shu'aiba limestones in Yibal field, thus the name North Oman Huqf ? Shu'aiba(!) TPS. Deep gas is produced mainly from Middle Cambrian to Lower Ordovician clastic reservoirs of the Haima Supergroup. Traps in nearly all hydrocarbon accumulations of these petroleum systems are mainly structural and were formed by one or more mechanisms. These trap-forming mechanisms were mainly periodic halokinesis of the thick Cambrian Ara Salt and consequent folding and faulting from basin loading, rifting, or other major tectonic events, particularly those events forming the Oman Mountains and associated foreland-basin system during the Late Cretaceous and Late Tertiary. Many of the future new-field targets will likely be low-relief, subtle structures, as many of the large structures have been drilled. Oman's recent interest and commitments to liquid natural gas export make deep gas a primary objective in the two North Oman Huqf petroleum systems. New-field exploration of deep gas and exploring deeper targets for gas in existing fields will likely identify a significant gas resource in the next thirty years. Moreover, salt-diapir flank traps in these two North Oman Huqf petroleum systems and salt basin provinces have gone essentially untested and will likely be targeted in the near-future. The Middle Cretaceous Natih(!) TPS is a small efficient system of the Fahud Salt Basin. Natih source rocks are only mature in the Late Cretaceous/Tertiary foredeep and production is primarily from Natih reservoirs; minor production from the Shu'aiba limestone is documented along fault-dip structures. Most traps are structural and are related to development of the foreland basin and formation of the Oman Mountains. Future targets of the Natih TPS will be less obvious than those of Fahud and Natih fields and likely includ

Ghaba salt basin province and Fahud salt basin province, Oman; geological overview and total petroleum systems

USGS Publications Warehouse

Pollastro, Richard M.

1999-01-01

Three Total Petroleum Systems each consisting of one assessment unit have been identified in the Ghaba and Fahud Salt Basin Provinces of north-central Oman. One Total Petroleum System and corresponding assessment unit, the North Oman Huqf/?Q??Haushi(!) Total Petroleum System (201401) and Ghaba- Makarem Combined Structural Assessment Unit (20140101), were identified for the Ghaba Salt Basin Province (2014). In the Fahud Salt Basin Province, however, two overlapping Total Petroleum Systems (TPS) were recognized: (1) the North Oman Huqf?Shu?aiba(!) TPS (201601); Fahud-Huqf Combined Structural Assessment Unit (20160101), and (2) the middle Cretaceous Natih(!) TPS (201602); Natih-Fiqa Structural/Stratigraphic Assessment Unit (20160201). The boundary for each Total Petroleum System also defines the boundary of the corresponding assessment unit and includes all trap styles and hydrocarbon-producing reservoirs within the petroleum system. In both the Ghaba and Fahud Salt Basin Provinces, hydrocarbons were generated from several deeply buried source rocks within the Infracambrian Huqf Supergroup. One general ?North Oman Huqf? type oil is dominant in the Fahud Salt Basin. Oils in the Ghaba Salt Basin are linked to at least two distinct Huqf source-rock units based on oil geochemistry: a general North Oman Huqf-type oil source and a more dominant ?questionable unidentified source? or ?Q?-type Huqf oil source. These two Huqf-sourced oils are commonly found as admixtures in reservoirs throughout northcentral Oman. Hydrocarbons generated from Huqf sources are produced from a variety of reservoir types and ages ranging from Precambrian to Cretaceous in both the Ghaba and Fahud Salt Basin Provinces. Clastic reservoirs of the Gharif and Al Khlata Formations, Haushi Group (middle Carboniferous to Lower Permian), dominate oil production in the Ghaba Salt Basin Province and form the basis for the Huqf/?Q??Haushi(!) TPS. In contrast, the Lower Cretaceous Shu?aiba and middle Cretaceous Natih limestones account for most of the production in the Fahud Salt Basin with about 50 percent of the basin?s production from porous, fractured Shu?aiba limestones in Yibal field, thus the name North Oman Huqf? Shu?aiba(!) TPS. Deep gas is produced mainly from Middle Cambrian to Lower Ordovician clastic reservoirs of the Haima Supergroup. Traps in nearly all hydrocarbon accumulations of these petroleum systems are mainly structural and were formed by one or more 3 mechanisms. These trap-forming mechanisms were mainly periodic halokinesis of the thick Cambrian Ara Salt and consequent folding and faulting from basin loading, rifting, or other major tectonic events, particularly those events forming the Oman Mountains and associated foreland-basin system during the Late Cretaceous and late Tertiary. Many of the future new-field targets will likely be low-relief, subtle structures, as many of the large structures have been drilled. Oman?s recent interest and commitments to liquid natural gas export make deep gas a primary objective in the two North Oman Huqf petroleum systems. New-field exploration of deep gas and exploring deeper targets for gas in existing fields will likely identify a significant gas resource in the next 30 years. Moreover, salt-diapir flank traps in these two North Oman Huqf petroleum systems and salt basin provinces have gone essentially untested and will likely be targeted in the near future. The middle Cretaceous Natih(!) TPS is a small efficient system of the Fahud Salt Basin. Natih source rocks are only mature in the Late Cretaceous/Tertiary foredeep and production is primarily from Natih reservoirs; minor production from the Shu?aiba limestone is documented along fault-dip structures. Most traps are structural and are related to development of the foreland basin and formation of the Oman Mountains. Future targets of the Natih TPS will be less obvious

Bioremediation of petroleum-contaminated soil using aged refuse from landfills.

PubMed

Liu, Qingmei; Li, Qibin; Wang, Ning; Liu, Dan; Zan, Li; Chang, Le; Gou, Xuemei; Wang, Peijin

2018-05-10

This study explored the effects and mechanisms of petroleum-contaminated soil bioremediation using aged refuse (AR) from landfills. Three treatments of petroleum-contaminated soil (47.28 mg·g -1 ) amended with AR, sterilized aged refuse (SAR) and petroleum-contaminated soil only (as a control) were tested. During 98 days of incubation, changes in soil physicochemical properties, residual total petroleum hydrocarbon (TPH), biodegradation kinetics, enzyme activities and the microbial community were investigated. The results demonstrated that AR was an effective soil conditioner and biostimulation agent that could comprehensively improve the quality of petroleum-contaminated soil and promote microbial growth, with an 74.64% TPH removal rate, 22.36 day half-life for SAR treatment, compared with the control (half-life: 138.63 days; TPH removal rate: 22.40%). In addition, the petroleum-degrading bacteria isolation results demonstrated that AR was also a petroleum-degrading microbial agent containing abundant microorganisms. AR addition significantly improved both the biotic and abiotic conditions of petroleum-contaminated soil without other additives. The cooperation of conditioner addition, biostimulation and bioaugmentation in AR treatment led to better bioremediation effects (half-life: 13.86 days; TPH removal rate: 89.83%). In conclusion, AR amendment is a cost-effective, easy-to-use method facilitating in situ large-scale application while simultaneously recycling huge amounts of AR from landfills. Copyright © 2018 Elsevier Ltd. All rights reserved.

Dermal uptake of petroleum substances.

PubMed

Jakasa, Ivone; Kezic, Sanja; Boogaard, Peter J

2015-06-01

Petroleum products are complex substances comprising varying amounts of linear and branched alkanes, alkenes, cycloalkanes, and aromatics which may penetrate the skin at different rates. For proper interpretation of toxic hazard data, understanding their percutaneous absorption is of paramount importance. The extent and significance of dermal absorption of eight petroleum substances, representing different classes of hydrocarbons, was evaluated. Literature data on the steady-state flux and permeability coefficient of these substances were evaluated and compared to those predicted by mathematical models. Reported results spanned over 5-6 orders of magnitude and were largely dependent on experimental conditions in particular on the type of the vehicle used. In general, aromatic hydrocarbons showed higher dermal absorption than more lipophilic aliphatics with similar molecular weight. The results showed high variation and were largely influenced by experimental conditions emphasizing the need of performing the experiments under "in use" scenario. The predictive models overestimated experimental absorption. The overall conclusion is that, based on the observed percutaneous penetration data, dermal exposure to petroleum hydrocarbons, even of aromatics with highest dermal absorption is limited and highly unlikely to be associated with health risks under real use scenarios. Copyright © 2015 Elsevier Ireland Ltd. All rights reserved.

Phytotoxic activity and chemical composition of Cassia absus seeds and aerial parts.

PubMed

Zribi, I; Sbai, H; Ghezal, N; Richard, G; Trisman, D; Fauconnier, M L; Haouala, R

2017-12-01

The present study was conducted to assess the phytotoxic potential and the phytochemical composition of Cassia absus. Aqueous extracts caused significant reduction in root growth of Lactuca sativa. Seed extract was more effective than aerial part extract. Successive extractions of this plant were performed using solvents with increasing polarities. The methanolic seed extract exerted strong phytotoxic effect on seedling growth, followed by petroleum ether extract of the aerial part. The phytochemical investigation showed that among the organic extracts, methanol extracts of seeds and aerial parts contained the highest amounts of total phenolics and proanthocyanidins. Seeds were rich in linoleic acid followed by palmitic acids. Palmitic, stearic and arachidic acids were the major fatty acids in aerial parts. HPLC-DAD analysis of the methanolic extracts revealed the presence of luteolin in C. absus aerial parts.

Interference of avian guano in analyses of fuel-contaminated soils

DOE Office of Scientific and Technical Information (OSTI.GOV)

James, D.E.; Johnson, T.E.; Kreamer, D.K.

1996-01-01

Site characterization on Johnston Island, Johnston Atoll, Pacific Ocean, has yielded preliminary data that seabird guano can be an interference in three common petroleum hydrocarbon quantification methods. Volatiles from seabird guano were measured on a hydrocarbon-specific handheld vapor meter (catalytic detector) in concentrations as high as 256 ppm by volume total hydrocarbon. Analysis of guano solids produced measurable concentrations of total petroleum hydrocarbon (TPH) as diesel using both an immunoassay test and the EPA 8015 Modified Method. The testing was conducted on one surface sample of guano collected from a seabird roosting and nesting area. Source species were not identified.more » Positive hydrocarbon test results for guano raise concerns regarding the effectiveness of standard methods of petroleum-contaminated site characterization for Johnston island, other Pacific islands, and coastal areas with historic or contemporary seabird populations.« less

Plant-microbial association in petroleum and gas exploration sites in the state of Assam, north-east India-significance for bioremediation.

PubMed

Sarma, Hemen; Islam, N F; Prasad, M N V

2017-03-01

The state of Assam in north-east India gained popularity in Asia because of discovery of oil. Pollution due to petroleum and gas exploration is a serious problem in Assam. Oil and gas exploration by various agencies in Assam resulted in soil pollution due to hydrocarbons (HCs) and heavy metals (HMs). Bioremediation gained considerable significance in addressing petroleum hydrocarbon polluted sites in various parts of the world. In this investigation, we have observed 15 species of plants belonging to grass growing on the contaminated soils. Among 15 species of grasses, 10 species with high important value index (IVI) were found to be better adapted. The highest IVI is exhibited by Axonopus compressus (21.41), and this grass can be identified as key ecological tool in the rehabilitation of the degraded site. But no definite correlation between the IVI and the biomass of the various grass existed in the study sites. Chemical study of rhizosphere (RS) and non-rhizosphere (NRS) soil of these grasses revealed both aromatic and aliphatic compounds (M.W. 178-456). Four-ring pyrene was detected in NRS soil but not in RS soil. Microbiological study of RS and NRS soil showed high colony-forming unit (CFU) of HC-degrading microbes in RS compared to NRS. The increased microbial catabolism in RS soil established the fact that pyrene is transformed to aliphatic compounds. Metals in RS soil ranged from (in mg kg -1 ) 222.6 to 267.3 (Cr), 854 to 956 (Pb) and 180 to 247 (Ni), but despite the very high total metal concentration in RS and NRS soil, the CaCl 2 -extracted metals were relatively low in RS soil (1.04 for Cr, 0.56 for Pb, 0.35 for Ni). Plants with the highest uptake of metals were Leersia hexandra (36.43 mg Cr kg -1 ) and Kyllinga brevifolia (67.73 mg Pb kg -1 and 40.24 mg Ni kg -1 ). These plant species could be potentially exploited for biomonitoring and bioremediation. Out of 15 plant species, 8 of them have high percentages of cellulose, crude fibres, lignin and holocellulose (14-16%). The explored species thus qualify as energy crops since they have high bioproductivity and are more resilient and adaptable in HM/HC-contaminated sites.

Characterization of contamination, source and degradation of petroleum between upland and paddy fields based on geochemical characteristics and phospholipid fatty acids.

PubMed

Zhang, Juan; Wang, Renqing; Du, Xiaoming; Li, Fasheng; Dai, Jiulan

2012-01-01

To evaluate contamination caused by petroleum, surface soil samples were collected from both upland and paddy fields along the irrigation canals in the Hunpu wastewater irrigation region in northeast China. N-alkanes, terpanes, steranes, and phospholipid fatty acids (PLFA) in the surface soil samples were analyzed. The aliphatic hydrocarbon concentration was highest in the samples obtained from the upland field near an operational oil well; it was lowest at I-3P where wastewater irrigation promoted the downward movement of hydrocarbons. The Hunpu region was found contaminated by heavy petroleum from oxic lacustrine fresh water or marine deltaic source rocks. Geochemical parameters also indicated significantly heavier contamination and degradation in the upland fields compared with the paddy fields. Principal component analysis based on PLFA showed various microbial communities between petroleum contaminated upland and paddy fields. Gram-negative bacteria indicated by 15:0, 3OH 12:0, and 16:1(9) were significantly higher in the paddy fields, whereas Gram-positive bacteria indicated by i16:0 and 18:1(9)c were significantly higher in the upland fields (p < 0.05). These PLFAs were related to petroleum contamination. Poly-unsaturated PLFA (18:2omega6, 9; indicative of hydrocarbon-degrading bacteria and fungi) was also significantly elevated in the upland fields. This paper recommends more sensitive indicators of contamination and degradation of petroleum in soil. The results also provide guidelines on soil pollution control and remediation in the Hunpu region and other similar regions.

Opioidergic mechanisms underlying the actions of Vitex agnus-castus L

PubMed Central

Webster, Donna E.; He, Ying; Chen, Shao.-Nong; Pauli, Guido F.; Farnsworth, Norman R.; Wang, Zaijie Jim

2010-01-01

Vitex agnus-castus (VAC) has been used since ancient Greek times and has been shown clinically to be effective for the treatment of pre-menstrual syndrome. However, its mechanism of action has only been partially determined. Compounds, fractions, and extracts isolated from VAC were used in this study to thoroughly investigate possible opioidergic activity. First, an extract of VAC was found to bind and activate μ- and δ-, but not κ- opioid receptor subtypes (MOR, DOR, and KOR respectively). The extract was then resuspended in 10% methanol and partitioned sequentially with petroleum ether, CHCl3, and EtOAc to form four fractions including a water fraction. The highest affinity for MOR was concentrated in the CHCl3 fraction, whereas the highest affinity for DOR was found in the CHCl3 and EtOAc fractions. However, the petroleum ether fraction had the highest agonist activity at MOR and DOR. Several flavonoids from VAC were found to bind to both MOR and DOR in a dose-dependent manner; however only casticin, a marker compound for genus Vitex, was found to have agonist activity selective for DOR at high concentrations. These results suggest VAC may exert its therapeutic effects through the activation of MOR, DOR, but not KOR. PMID:20854795

Opioidergic mechanisms underlying the actions of Vitex agnus-castus L.

PubMed

Webster, Donna E; He, Ying; Chen, Shao-Nong; Pauli, Guido F; Farnsworth, Norman R; Wang, Zaijie Jim

2011-01-01

Vitex agnus-castus (VAC) has been used since ancient Greek times and has been shown clinically to be effective for the treatment of pre-menstrual syndrome. However, its mechanism of action has only been partially determined. Compounds, fractions, and extracts isolated from VAC were used in this study to thoroughly investigate possible opioidergic activity. First, an extract of VAC was found to bind and activate μ- and δ-, but not κ-opioid receptor subtypes (MOR, DOR, and KOR respectively). The extract was then resuspended in 10% methanol and partitioned sequentially with petroleum ether, CHCl(3), and EtOAc to form four fractions including a water fraction. The highest affinity for MOR was concentrated in the CHCl(3) fraction, whereas the highest affinity for DOR was found in the CHCl(3) and EtOAc fractions. The petroleum ether fraction had the highest agonist activity at MOR and DOR. Several flavonoids from VAC were found to bind to both MOR and DOR in a dose-dependent manner; however only casticin, a marker compound for genus Vitex, was found to have agonist activity selective for DOR at high concentrations. These results suggest VAC may exert its therapeutic effects through the activation of MOR, DOR, but not KOR. Copyright © 2010 Elsevier Inc. All rights reserved.

Assessment of undiscovered oil and gas resources of the Cretaceous-Tertiary Composite Total Petroleum System, Taranaki Basin Assessment Unit, New Zealand

USGS Publications Warehouse

Wandrey, Craig J.; Schenk, Christopher J.; Klett, Timothy R.; Brownfield, Michael E.; Charpentier, Ronald R.; Cook, Troy A.; Pollastro, Richard M.; Tennyson, Marilyn E.

2013-01-01

The Cretaceous-Tertiary Composite Total Petroleum System coincident Taranaki Basin Assessment Unit was recently assessed for undiscovered technically recoverable oil, natural gas, and natural gas liquids resources as part of the U.S. Geological Survey (USGS) World Energy Resources Project, World Oil and Gas Assessment. Using a geology-based assessment methodology, the USGS estimated mean volumes of 487 million barrels of oil, 9.8 trillion cubic feet of gas, and 408 million barrels of natural gas liquids.

Effects of mild cold stress on the survival of seawater-adapted mallard ducks (Anas platyrhynchos) maintained on food contaminated with petroleum

USGS Publications Warehouse

Holmes, W.N.; Gorsline, J.; Cronshaw, J.

1979-01-01

(1) Seawater-adapted Mallard ducks maintained in the laboratory will freely consume food that has been contaminated with either any one of a variety of crude oils or a petroleum derivative such as No. 2 fuel oil. (2) During a 100-day experimental period total masses of petroleum equivalent to 50% of the mean body weight were consumed by some birds and many showed no apparent symptoms of distress. (3) The consumption of petroleum-contaminated food was frequently accompanied by a persistent hyperphagia but no clear patterns of change in body weight were associated with this condition. (4) Among those birds that survived the 100-day experimental period only small changes in mean body weight were observed between successive weighings and in most instances these represented less than 10% of the previously recorded weight. (5) In all groups, including those maintained on uncontaminated food, most of the mortality occurred following exposure to continuous mild cold stress. The total number of deaths in the groups given petroleum-contaminated food, however, was always higher than that among birds given uncontaminated food. (6) The spate of mortality that occurred in groups given petroleum-contaminated food usually occurred earlier, lasted longer, and involved more birds than it did among groups fed uncontaminated food. (7) The pattern of each episode of mortality was sometimes quantitatively related to the concentration of petroleum in the food and a striking range of relative toxicities were observed among the crude oils from different geographic regions. (8) Throughout the experiment, the mean body weight of the birds that died was always significantly less than that of the survivors in the same group; in all instances most of the loss in weight occurred during the 2 weeks preceding death. (9) Autopsy revealed that adrenal hypertrophy and lymphoepithelial involution were characteristic in all of the birds that died, suggesting that a high level of adrenocortical stimulation preceded death. Such high levels of adrenocortical stimulation, therefore, probably occurred sooner in birds consuming petroleum-contaminated food than in birds given uncontaminated food. (10) The consumption of petroleum-contaminated food seemed to constitute a nonspecific stressor and among birds already exposed to stresses, such as hyperosmotic drinking water (seawater) and persistent cold, the ingestion of petroleum seemed to render them more vulnerable to adrenocortical exhaustion, and death frequently ensued.

Airborne concentrations of metals and total dust during solid catalyst loading and unloading operations at a petroleum refinery.

PubMed

Lewis, Ryan C; Gaffney, Shannon H; Le, Matthew H; Unice, Ken M; Paustenbach, Dennis J

2012-09-01

Workers handle catalysts extensively at petroleum refineries throughout the world each year; however, little information is available regarding the airborne concentrations and plausible exposures during this type of work. In this paper, we evaluated the airborne concentrations of 15 metals and total dust generated during solid catalyst loading and unloading operations at one of the largest petroleum refineries in the world using historical industrial hygiene samples collected between 1989 and 2006. The total dust and metals, which included aluminum, cadmium, chromium, cobalt, copper, iron, lead, manganese, molybdenum, nickel, platinum, silicon, silver, vanadium, and zinc, were evaluated in relation to the handling of four different types of solid catalysts associated with three major types of catalytic processes. Consideration was given to the known components of the solid catalysts and any metals that were likely deposited onto them during use. A total of 180 analytical results were included in this analysis, representing 13 personal and 54 area samples. Of the long-term personal samples, airborne concentrations of metals ranged from <0.001 to 2.9mg/m(3), and, in all but one case, resulted in concentrations below the current U.S. Occupational Safety and Health Administration's Permissible Exposure Limits and the American Conference of Governmental Industrial Hygienists' Threshold Limit Values. The arithmetic mean total dust concentration resulting from long-term personal samples was 0.31mg/m(3). The data presented here are the most complete set of its kind in the open literature, and are useful for understanding the potential exposures during solid catalyst handling activities at this petroleum refinery and perhaps other modern refineries during the timeframe examined. Copyright © 2011 Elsevier GmbH. All rights reserved.

10 CFR 503.38 - Permanent exemption for certain fuel mixtures containing natural gas or petroleum.

Code of Federal Regulations, 2011 CFR

2011-01-01

... mixture of solar energy (including wind, tide, and other intermittent sources) and petroleum or natural gas, where: (1) Solar energy will account for at least 20 percent of the total annual Btu heat input... 10 Energy 4 2011-01-01 2011-01-01 false Permanent exemption for certain fuel mixtures containing...

10 CFR 503.38 - Permanent exemption for certain fuel mixtures containing natural gas or petroleum.

Code of Federal Regulations, 2012 CFR

2012-01-01

... mixture of solar energy (including wind, tide, and other intermittent sources) and petroleum or natural gas, where: (1) Solar energy will account for at least 20 percent of the total annual Btu heat input... 10 Energy 4 2012-01-01 2012-01-01 false Permanent exemption for certain fuel mixtures containing...

10 CFR 503.38 - Permanent exemption for certain fuel mixtures containing natural gas or petroleum.

Code of Federal Regulations, 2013 CFR

2013-01-01

... mixture of solar energy (including wind, tide, and other intermittent sources) and petroleum or natural gas, where: (1) Solar energy will account for at least 20 percent of the total annual Btu heat input... 10 Energy 4 2013-01-01 2013-01-01 false Permanent exemption for certain fuel mixtures containing...

10 CFR 503.38 - Permanent exemption for certain fuel mixtures containing natural gas or petroleum.

Code of Federal Regulations, 2014 CFR

2014-01-01

... mixture of solar energy (including wind, tide, and other intermittent sources) and petroleum or natural gas, where: (1) Solar energy will account for at least 20 percent of the total annual Btu heat input... 10 Energy 4 2014-01-01 2014-01-01 false Permanent exemption for certain fuel mixtures containing...

Environmental impact assessment using a GSR tool for a landfarming case in South Korea.

PubMed

Lim, Hyeongseok; Kwon, Ip-Sae; Lee, Hanuk; Park, Jae-Woo

2016-04-01

An environmental impact assessment of a landfarming process, which was performed at an actual petroleum-contaminated site, was conducted using a green and sustainable remediation (GSR) tool in this study. The landfarming process was divided into four stages: site preparation, installation, system operation, and system dismantling/waste disposal. The environmental footprints of greenhouse gas (GHG) emissions, water consumption, total energy usage, and air pollutants (SOx, NOx, and PM10) were analyzed. GHG emissions and water consumption were approximately 276 metric tons and 7.90E + 05 gal, respectively, in stage III, where they were the highest due to the consumables and equipment use in the system operation. Total energy usage had the highest value of 1.54E + 03 MMBTU in stage II due to material production. The SOx and NOx emissions primarily occurred in stages I and II due to energy usage. The PM10 was mostly emitted in stages I and III and was associated with heavy use of equipment. To reduce the environmental footprints, biodiesel and sunlight were suggested as alternatives in this study. The GHG and SOx emissions decreased to 1.7 and 4.4E-04 metric tons, respectively, on the basis of total emissions with a 1 % increase in biodiesel content, but the NOx emissions increased to 5.6E-03 metric tons. If sunlight was used instead of electricity, the GHG and NOx emissions could be reduced by as much as 79 and 84 %, respectively, and the SOx emissions could also be reduced.

Petroleum pipeline explosions in sub-Saharan Africa: a comprehensive systematic review of the academic and lay literature.

PubMed

Carlson, Lucas C; Rogers, Tom T; Kamara, Thaim B; Rybarczyk, Megan M; Leow, Jeffrey J; Kirsch, Thomas D; Kushner, Adam L

2015-05-01

Experience indicates that the frequency and impact of petroleum pipeline fires and explosions in sub-Saharan Africa (SSA) is presently under-represented in the academic literature. Using adapted PRISMA guidelines, the authors reviewed both PubMed and the LexisNexis Academic news database, which includes periodicals, news transcripts and online reports. Country-by-country searches were conducted for petroleum pipeline fires and explosions in SSA occurring between June 1, 2004 and May 31, 2014. Initial search yielded 5730 articles from LexisNexis Academic and 3 from PubMed. On further review, a total of 28 separate petroleum pipeline-related incidents causing injuries and/or deaths were identified, 16 of which had not been previously reported in the academic literature. The events occurred in Nigeria (23), Kenya (2), Ghana (1), Sierra Leone (1), and Tanzania (1). A total of 1756 deaths were reported across all events. The most common cause of the original leak was intentional, either from theft or vandalism (13/20, 65%), or by militia activity (2/20, 10%). Fire disasters related to scavenging fuel from petroleum pipelines are common in SSA and cause significant morbidity and mortality. These events require better reporting tools and intervention strategies overall. Furthermore, our study demonstrates that non-academic sources can effectively supplement gaps in the academic literature. Copyright © 2014 Elsevier Ltd and ISBI. All rights reserved.

[Analysis of fluorescence spectrum of petroleum-polluted water].

PubMed

Huang, Miao-Fen; Song, Qing-Jun; Xing, Xu-Feng; Jian, Wei-Jun; Liu, Yuan; Zhao, Zu-Long

2014-09-01

In four ratio experiments, natural waters, sampled from the mountain reservoir and the sea water around Dalian city, were mixed with the sewage from petroleum refinery and petroleum exploitation plants. The fluorescence spectra of water samples containing only chromophoric dissolved organic matters(CDOM), samples containing only petroleum, and samples containing a mixture of petroleum and CDOM were analyzed, respectively. The purpose of this analysis is to provide a basis for determining the contribution of petroleum substances and CDOM to the total absorption coefficient of the petroleum-contaminated water by using fluorescence technique. The results showed that firstly, CDOM in seawater had three main fluorescence peaks at Ex: 225-230 nm/Em: 320-330 nm, Ex: 280 nm/Em: 340 nm and Ex: 225-240 nm/Em: 430-470 nm, respectively, and these may arise from the oceanic chlorophyll. CDOM in natural reservoir water had two main fluorescence peaks at EX: 240- 260 nm/Em: 420-450 nm and Ex: 310~350 nm/Em: 420--440 nm, respectively, and these may arise from the terrestrial sources; secondly, the water samples containing only petroleum extracted with n-hexane had one to three fluorescence spectral peaksat Ex: 220-240 nm/Em: 320-340 nm, Ex: 270-290 nm/Em: 310-340 nm and Ex: 220-235 nm/Em: 280-310 nm, respectively, caused by their hydrocarbon component; finally, the water samples containing both petroleum and CDOM showed a very strong fluorescence peak at Ex: 230-250 nm/Em: 320-370 nm, caused by the combined effect of CDOM and petroleum hydrocarbons.

Biodegradation of total petroleum hydrocarbons from acidic sludge produced by re-refinery industries of waste oil using in-vessel composting.

PubMed

Asgari, Alireza; Nabizadeh, Ramin; Mahvi, Amir Hossein; Nasseri, Simin; Dehghani, Mohammad Hadi; Nazmara, Shahrokh; Yaghmaeian, Kamyar

2017-01-01

In Iran, re-refinery industry has been developed many years ago based on the acid-clay treatment. Acidic sludge with high concentration of total petroleum hydrocarbon (TPH) is the final products of some facilities. In this study removal of TPH by aerated in-vessel composting was investigated. In order to microorganisms seeding and nutrient providing, urban immature compost was added as an amendment to acidic sludge. The ratios of acidic sludge (AS) to compost were, 1:0 (as control), 1:5, 1:8, 1:10, 1:15, 1:20, 1:30, 1:40, 1:50, 1:75 and 1:100 (as dry basis) at a C: N: P ratio of 100:5:1 and 45-65% moisture content for 70 days. The removal efficiency in all reactors was more than 48%. The highest and lowest TPH removal was observed in 1:5 (71.56%) and 1:100 (48.53%) mixing ratios, respectively. The results of the control reactors showed that biological treatment was the main mechanism for TPH removal. Experimental data was fitted second order kinetic model ( R 2  > 0.8006). Degradation of TPH in 1:5 mixing ratio (k 2  = 0.0038 gmg -1 d -1 ; half-life = 3.08d) was nearly three times faster than 1:100 mixing ratio (k 2  = 0.0238; half-life = 8.96d). The results of the control reactors showed that biological treatment was the main mechanism for TPH removal. The results of this study revealed in-vessel composting with immature urban compost as the amendment maybe recommended as an effective method for TPH remediation.

Degradation of Total Petroleum Hydrocarbon (TPH) in Contaminated Soil Using Bacillus pumilus MVSV3.

PubMed

Varma, Surendra Sheeba; Lakshmi, Mahalingam Brinda; Rajagopal, Perumalsam; Velan, Manickam

2017-01-01

　A study on bioremediation of soil contaminated with petroleum sludge was performed using Bacillus pumilus/MVSV3 (Accession number JN089707). In this study, 5 kg of agricultural soil was mixed well with 5% oil sludge and fertilizers containing nitrogen, phosphorus and potassium (N:P:K). The treatment resulted in 97% removal of total petroleum hydrocarbon (TPH) in 122 d in bacteria mixed contaminated soil when compared to 12% removal of TPH in uninoculated contaminated soil. The population of the microorganism remained stable after introduced into the oil environment. The physical and chemical parameters of the soil mixed with sludge showed variation indicating improvement and the pH level decreased during the experiment period. Elemental analysis and Gas Chromatography-Mass Spectroscopy (GC-MS) analysis revealed the bacterial ability to degrade oil sludge components. Growth experiments with Trigonellafoenumgraecum (Fenugreek) showed the applicability of bioremediated soil for the production.

Executive Summary -- assessment of undiscovered oil and gas resources of the San Joaquin Basin Province of California, 2003: Chapter 1 in Petroleum systems and geologic assessment of oil and gas in the San Joaquin Basin Province, California

USGS Publications Warehouse

Gautier, Donald L.; Scheirer, Allegra Hosford; Tennyson, Marilyn E.; Peters, Kenneth E.; Magoon, Leslie B.; Lillis, Paul G.; Charpentier, Ronald R.; Cook, Troy A.; French, Christopher D.; Klett, Timothy R.; Pollastro, Richard M.; Schenk, Christopher J.

2007-01-01

In 2003, the U.S. Geological Survey (USGS) completed an assessment of the oil and gas resource potential of the San Joaquin Basin Province of California (fig. 1.1). The assessment is based on the geologic elements of each Total Petroleum System defined in the province, including hydrocarbon source rocks (source-rock type and maturation and hydrocarbon generation and migration), reservoir rocks (sequence stratigraphy and petrophysical properties), and hydrocarbon traps (trap formation and timing). Using this geologic framework, the USGS defined five total petroleum systems and ten assessment units within these systems. Undiscovered oil and gas resources were quantitatively estimated for the ten assessment units (table 1.1). In addition, the potential was estimated for further growth of reserves in existing oil fields of the San Joaquin Basin.

Studies on crude oil removal from pebbles by the application of biodiesel.

PubMed

Xia, Wen-xiang; Xia, Yan; Li, Jin-cheng; Zhang, Dan-feng; Zhou, Qing; Wang, Xin-ping

2015-02-15

Oil residues along shorelines are hard to remove after an oil spill. The effect of biodiesel to eliminate crude oil from pebbles alone and in combination with petroleum degrading bacteria was investigated in simulated systems. Adding biodiesel made oil detach from pebbles and formed oil-biodiesel mixtures, most of which remained on top of seawater. The total petroleum hydrocarbon (TPH) removal efficiency increased with biodiesel quantities but the magnitude of augment decreased gradually. When used with petroleum degrading bacteria, the addition of biodiesel (BD), nutrients (NUT) and BD+NUT increased the dehydrogenase activity and decreased the biodegradation half lives. When BD and NUT were replenished at the same time, the TPH removal efficiency was 7.4% higher compared to the total improvement of efficiency when BD and NUT was added separately, indicating an additive effect of biodiesel and nutrients on oil biodegradation. Copyright © 2014 Elsevier Ltd. All rights reserved.

The North Sakhalin Neogene total petroleum system of eastern Russia

USGS Publications Warehouse

Lindquist, S.J.

2000-01-01

The North Sakhalin Basin Province of eastern Russia contains one Total Petroleum System (TPS) ? North Sakhalin Neogene ? with more than 6 BBOE known, ultimately recoverable petroleum (61% gas, 36% oil, 3% condensate). Tertiary rocks in the basin were deposited by the prograding paleo-Amur River system. Marine to continental, Middle to Upper Miocene shale to coaly shale source rocks charged marine to continental Middle Miocene to Pliocene sandstone reservoir rocks in Late Miocene to Pliocene time. Fractured, self-sourced, Upper Oligocene to Lower Miocene siliceous shales also produce hydrocarbons. Geologic history is that of a Mesozoic Asian passive continental margin that was transformed into an active accretionary Tertiary margin and Cenozoic fold belt by the collision of India with Eurasia and by the subduction of Pacific Ocean crustal plates under the Asian continent. The area is characterized by extensional, compressional and wrench structural features that comprise most known traps.

Petroleum-degrading microbial numbers in rhizosphere and non-rhizosphere crude oil-contaminated soil.

PubMed

Kirkpatrick, W D; White, P M; Wolf, D C; Thoma, G J; Reynolds, C M

2008-01-01

Phytoremediation can be a cost-effective and environmentally acceptable method to clean up crude oil-contaminated soils in situ. Our research objective was to determine the effects of nitrogen (N) additions and plant growth on the number of total hydrocarbon (TH)-, alkane-, and polycyclic aromatic hydrocarbon (PAH)-degrading microorganisms in weathered crude oil-contaminated soil. A warm-season grass, sudangrass (Sorghum sudanense (Piper) Stapf), was grown for 7 wk in soil with a total petroleum hydrocarbon (TPH) level of 16.6 g TPH/kg soil. Nitrogen was added based upon TPH-C:added total N (TPH-C:TN) ratios ranging from 44:1 to 11:1. Unvegetated and unamended controls were also evaluated. The TH-, alkane-, and PAH-degrading microbial numbers per gram of dry soil were enumerated from rhizosphere and non-rhizosphere soil for vegetated pots and non-rhizosphere soil populations were enumerated from non-vegetated pots. Total petroleum-degrading microbial numbers were also calculated for each pot. The TH-, alkane-, and PAH-degrading microbial numbers per gram of dry soil in the sudangrass rhizosphere were 3.4, 2.6, and 4.8 times larger, respectively, than those in non-rhizosphere soil across all N rates. The presence of sudangrass resulted in significantly more TH-degrading microorganisms per pot when grown in soil with a TPH-C:TN ratio of 11:1 as compared to the control. Increased plant root growth in a crude oil-contaminated soil and a concomitant increase in petroleum-degrading microbial numbers in the rhizosphere have the potential to enhance phytoremediation.

Petroleum hydrocarbon pollution of urban topsoil in Ibadan city, Nigeria

DOE Office of Scientific and Technical Information (OSTI.GOV)

Onianwa, P.C.

The distribution of total petroleum hydrocarbon in topsoils from various parts of Ibadan city, Nigeria, was studied. Samples were selected from around the following zones: (a) railway tracks, (b) petrol stations, (c) refuse dumps, (d) residential areas, (e) high traffic density areas, (f) mechanical workshops, and (g) control zones. Contamination of the topsoil with hydrocarbons was significant only around petrol stations and mechanical workshops where the factors of accumulation were 10.1 and 4.72, respectively. The general trend in hydrocarbon levels was petrol station > mechanical workshop > refuse dumps > high traffic areas {ge} rail tracks > control residential areas.more » The results highlight the need to monitor urban environments that are remote from petroleum exploration activities for petroleum hydrocarbon contamination. 19 refs., 3 tabs.« less

Chapter 1: An overview of the petroleum geology of the Arctic

USGS Publications Warehouse

Spencer, A.M.; Embry, A.F.; Gautier, D.L.; Stoupakova, A.V.; Sorensen, K.

2011-01-01

Nine main petroleum provinces containing recoverable resources totalling 61 Bbbl liquids + 269 Bbbloe of gas are known in the Arctic. The three best known major provinces are: West Siberia-South Kara, Arctic Alaska and Timan-Pechora. They have been sourced principally from, respectively, Upper Jurassic, Triassic and Devonian marine source rocks and their hydrocarbons are reservoired principally in Cretaceous sandstones, Triassic sandstones and Palaeozoic carbonates. The remaining six provinces except for the Upper Cretaceous-Palaeogene petroleum system in the Mackenzie Delta have predominantly Mesozoic sources and Jurassic reservoirs. There are discoveries in 15% of the total area of sedimentary basins (c. 8 ?? 106 km2), dry wells in 10% of the area, seismic but no wells in 50% and no seismic in 25%. The United States Geological Survey estimate yet-to-find resources to total 90 Bbbl liquids + 279 Bbbloe gas, with four regions - South Kara Sea, Alaska, East Barents Sea, East Greenland - dominating. Russian estimates of South Kara Sea and East Barents Sea are equally positive. The large potential reflects primarily the large undrilled areas, thick basins and widespread source rocks. ?? 2011 The Geological Society of London.

Petroleum contaminated soil in Oman: evaluation of bioremediation treatment and potential for reuse in hot asphalt mix concrete.

PubMed

Jamrah, Ahmad; Al-Futaisi, Ahmed; Hassan, Hossam; Al-Oraimi, Salem

2007-01-01

This paper presents a study that aims at evaluating the leaching characteristics of petroleum contaminated soils as well as their application in hot mix asphalt concrete. Soil samples are environmentally characterized in terms of their total heavy metals and hydrocarbon compounds and leachability. The total petroleum hydrocarbon (TPH) present in the PCS before and after treatment was determined to be 6.8% and 5.3% by dry weight, indicating a reduction of 1% in the TPH of PCS due to the current treatment employed. Results of the total heavy metal analysis on soils indicate that the concentrations of heavy metals are lower when extraction of the soil samples is carried out using hexane in comparison to TCE. The results show that the clean soils present in the vicinity of contaminated sites contain heavy metals in the following decreasing order: nickel (Ni), followed by chromium (Cr), zinc (Zn), copper (Cu), lead (Pb), and vanadium (V). The current treatment practice employed for remediation of the contaminated soil reduces the concentrations of nickel and chromium, but increases the concentrations of all remaining heavy metals.

Stratigraphy of the Upper Cretaceous Mancos Shale (upper part) and Mesaverde Group in the southern part of the Uinta and Piceance basins, Utah and Colorado

USGS Publications Warehouse

Hettinger, R.D.; Kirschbaum, M.A.

2002-01-01

Cross section A–A' was constructed in support of the oil and gas assessments of the Mesaverde and Mancos/Mowry Total Petroleum Systems in the Uinta and Piceance Basins of Utah and Colorado (fig. 1) (U.S. Geological Survey Uinta-Piceance Province Assessment Team, in press). This citation is referred to henceforth as simply “USGS, in press.” The Mesaverde Total Petroleum System contains continuous gas derived primarily from carbonaceous shale and coal in the Mesaverde Group [chapter by Johnson and Roberts in USGS (in press)]. The Mancos/Mowry Total Petroleum System contains continuous gas derived primarily from marine source rocks in the Mancos and Mowry Shales [chapter by Kirschbaum in USGS (in press)]. Cross section A–A' illustrates the stratigraphy of these Upper Cretaceous rocks, emphasizing the fluvial, coal-bearing coastal plain, nearshore marine, and offshore marine strata. The cross section is presented as a hard copy in this report and as a chapter by Hettinger and Kirschbaum (USGS, in press).

Phytoremediation of fuel oil and lead co-contaminated soil by Chromolaena odorata in association with Micrococcus luteus.

PubMed

Jampasri, Kongkeat; Pokethitiyook, Prayad; Kruatrachue, Maleeya; Ounjai, Puey; Kumsopa, Acharaporn

2016-10-02

Phytoremediation is widely promoted as a cost-effective technology for treating heavy metal and total petroleum hydrocarbon (TPH) co-contaminated soil. This study investigated the concurrent removal of TPHs and Pb in co-contaminated soil (27,000 mg kg(-1) TPHs, 780 mg kg(-1) Pb) by growing Siam weed (Chromolaena odorata) in a pot experiment for 90 days. There were four treatments: co-contaminated soil; co-contaminated soil with C. odorata only; co-contaminated soil with C. odorata and Micrococcus luteus inoculum; and co-contaminated soil with M. luteus only. C. odorata survived and grew well in the co-contaminated soil. C. odorata with M. luteus showed the highest Pb accumulation (513.7 mg kg(-1)) and uptake (7.7 mg plant(-1)), and the highest reduction percentage of TPHs (52.2%). The higher TPH degradation in vegetated soils indicated the interaction between the rhizosphere microorganisms and plants. The results suggested that C. odorata together with M. luteus and other rhizosphere microorganisms is a promising candidate for the removal of Pb and TPHs in co-contaminated soils.

Assessment of soil-gas contamination at three former fuel-dispensing sites, Fort Gordon, Georgia, 2010—2011

USGS Publications Warehouse

Caldwell, Andral W.; Falls, W. Fred; Guimaraes, Wladmir B.; Ratliff, W. Hagan; Wellborn, John B.; Landmeyer, James E.

2012-01-01

Soil gas was assessed for contaminants at three former fuel-dispensing sites at Fort Gordon, Georgia, from October 2010 to September 2011. The assessment included delineation of organic contaminants using soil-gas samplers collected from the former fuel-dispensing sites at 8th Street, Chamberlain Avenue, and 12th Street. This assessment was conducted to provide environmental contamination data to Fort Gordon personnel pursuant to requirements for the Resource Conservation and Recovery Act Part B Hazardous Waste Permit process. Soil-gas samplers installed and retrieved during June and August 2011 at the 8th Street site had detections above the method detection level (MDL) for the mass of total petroleum hydrocarbons (TPH), benzene, toluene, ortho-xylene, undecane, tridecane, pentadecane, and chloroform. Total petroleum hydrocarbons soil-gas mass exceeded the MDL of 0.02 microgram in 54 of the 55 soil-gas samplers. The highest detection of TPH soil-gas mass was 146.10 micrograms, located in the central part of the site. Benzene mass exceeded the MDL of 0.01 microgram in 23 soil-gas samplers, whereas toluene was detected in only 10 soil-gas samplers. Ortho-xylene was detected above the MDL in only one soil-gas sampler. The highest soil-gas mass detected for undecane, tridecane, and pentadecane was located in the northeastern corner of the 8th Street site. Chloroform mass greater than the MDL of 0.01 microgram was detected in less than one-third of the soil-gas samplers. Soil-gas masses above the MDL were identified for TPH, gasoline-related compounds, diesel-range alkanes, trimethylbenzenes, naphthalene, 2-methyl-napthalene, octane, and tetrachloroethylene for the July 2011 soil-gas survey at the Chamberlain Avenue site. All 30 of the soil-gas samplers contained TPH mass above the MDL. The highest detection of TPH mass, 426.36 micrograms, was for a soil-gas sampler located near the northern boundary of the site. Gasoline-related compounds and diesel-range alkanes were detected in multiple soil-gas samplers, and the highest detections of these compounds were located near the central part of the site near existing, nonoperational, fuel-dispensing pumps. Trimethylbenzenes were detected in less than half of the soil-gas samplers. Naphthalene soil-gas mass was detected above the MDL in 10 soil-gas samplers, whereas 2-methyl-napthalene was detected above the MDL in half of the soil-gas samplers. Octane mass was detected above the MDL in one soil-gas sampler located near the central part of the site. Tetrachloroethylene soil-gas mass was detected above the MDL in more than half of the soil-gas samplers, and the highest tetrachloroethylene soil-gas mass of 0.90 microgram was located in the northeastern part of the site. Soil-gas samplers collected at the 12th Street site during July 2011 contained soil-gas mass above the MDL for TPH, toluene, undecane, tridecane, and pentadecane (diesel-range alkanes), trichloroethylene, 1,4-dichlorobenzene, chloroform, and 1,2,4-trimethylbenzene. The highest detected TPH mass was 24.37 micrograms in a soil-gas sampler located in the northern part of the site. The highest detection of toluene soil-gas mass was from a soil-gas sampler located near the southern boundary of the site. The diesel-range alkanes were detected above the MDL in five soil-gas samplers; the highest detection of soil-gas diesel mass, 0.65 microgram, was located in the southern part of the site. Trichloroethylene and 1,4-dichlorobenzene were detected above the MDL in the northern part of the site in one soil-gas sampler that also had one of the highest detections of TPH. Chloroform was detected above the MDL in three soil-gas samplers, whereas 1,2,4-trimethylbenzene soil-gas mass was detected above the MDL in two soil-gas samplers.

Glossary: Chapter 29 in Petroleum systems and geologic assessment of oil and gas in the San Joaquin Basin Province, California

USGS Publications Warehouse

Klett, T.R.; Schmoker, James W.; Charpentier, Ronald R.; Ahlbrandt, Thomas S.; Ulmishek, Gregory F.

2007-01-01

Selected terms of particular importance to the U.S. Geological Survey assessment of undiscovered resources in total petroleum systems are defined here. The definitions are intended to be generally explanatory rather than strictly technical. No attempt has been made to include a detailed listing of common industry definitions.

Oman shows vision in leading Middle Eastern drilling

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ahmed-al Shanfari, S.B.

1989-12-01

Oman produced more than 600,000 bopd for the first time in 1988. The country led the Middle East in total wells drilled for the third consecutive year. This article presents an interview with H.E. Said bin Ahmed al-Shanfari, Oman's Minister of Petroleum and Minerals. Topics discussed include Oman's future production plans, Opec, future exploratory areas, and petroleum export levels.

Isolation, biomass estimation and characterization of the biofuel potential of diatom Navicula Sphaerophora

NASA Astrophysics Data System (ADS)

Papu, Nabam Hina; Lingfa, Pradip

2018-04-01

Navicula Sphaerophora was isolated from a fresh water reservoir in Arunachal Pradesh, India. N. Sphaerophora was grown on two different culture media, chu13 medium and Miracle Gro-medium. The maximum yield was obtained by using culture medium chu13(5.08 g/100ml of culture media). Microalgae crude oil was extracted using soxhlation method with three different solvents n-hexane, iso-propanol and hexane/ iso-propanol mixture. The maximum crude oil was obtained using n-hexane as a solvent (13.8% of dry weight biomass). The crude oil was converted into biodiesel using single stage transesterification process with sodium hydroxide (NaOH) as a base catalyst. Fuel properties of algae biodiesel satisfied biodiesel standard ASTM D6751 and use of this fuel should be comparable with petroleum diesel. Further short term engine test was conducted on single cylinder direct injection diesel engine at four different load (25%,50%,75% and 100%). Three different petroleum diesel and Microalgae Biodiesel blends (10%, 20% and 30%) were prepared. The influence of biodiesel blends on BSFC (brake specific fuel consumption), BTE (brake thermal efficiency), oxides of nitrogen (NOx), UBHC (unburnt hydrocarbons), carbonmonoxide (CO) and smoke opacity was studied and compared with petroleum diesel. Microalgae methyl ester 50% blend (B50) had lowest brake thermal efficiency (BTE) and highest Brake specific fuel consumption (BSFC) as compared to diesel; this may be due to Lower calorific value. HC, CO emission and smoke opacity reduces significantly with microalgae methyl ester. However, the NOx emission increases with all blends when compared to petroleum diesel. 10% microalgae blend with petroleum diesel showed the closet performance to petroleum diesel. Results obtained from present investigation confirmed the biofuel potentiality of Navicula Sphaerophora.

A four-dimensional petroleum systems model for the San Joaquin Basin Province, California: Chapter 12 in Petroleum systems and geologic assessment of oil and gas in the San Joaquin Basin Province, California

USGS Publications Warehouse

Peters, Kenneth E.; Magoon, Leslie B.; Lampe, Carolyn; Scheirer, Allegra Hosford; Lillis, Paul G.; Gautier, Donald L.

2008-01-01

A calibrated numerical model depicts the geometry and three-dimensional (3-D) evolution of petroleum systems through time (4-D) in a 249 x 309 km (155 x 192 mi) area covering all of the San Joaquin Basin Province of California. Model input includes 3-D structural and stratigraphic data for key horizons and maps of unit thickness, lithology, paleobathymetry, heat flow, original total organic carbon, and original Rock-Eval pyrolysis hydrogen index for each source rock. The four principal petroleum source rocks in the basin are the Miocene Antelope shale of Graham and Williams (1985; hereafter referred to as Antelope shale), the Eocene Kreyenhagen Formation, the Eocene Tumey formation of Atwill (1935; hereafter referred to as Tumey formation), and the Cretaceous to Paleocene Moreno Formation. Due to limited Rock-Eval/total organic carbon data, the Tumey formation was modeled using constant values of original total organic carbon and original hydrogen index. Maps of original total organic carbon and original hydrogen index were created for the other three source rocks. The Antelope shale was modeled using Type IIS kerogen kinetics, whereas Type II kinetics were used for the other source rocks. Four-dimensional modeling and geologic field evidence indicate that maximum burial of the three principal Cenozoic source rocks occurred in latest Pliocene to Holocene time. For example, a 1-D extraction of burial history from the 4-D model in the Tejon depocenter shows that the bottom of the Antelope shale source rock began expulsion (10 percent transformation ratio) about 4.6 Ma and reached peak expulsion (50 percent transformation ratio) about 3.6 Ma. Except on the west flank of the basin, where steep dips in outcrop and seismic data indicate substantial uplift, little or no section has been eroded. Most petroleum migration occurred during late Cenozoic time in distinct stratigraphic intervals along east-west pathways from pods of active petroleum source rock in the Tejon and Buttonwillow depocenters to updip sandstone reservoirs. Satisfactory runs of the model required about 18 hours of computation time for each simulation using parallel processing on a Linux-based cluster.

Polycyclic Aromatic Hydrocarbons in Coastal Sediment of Klang Strait, Malaysia: Distribution Pattern, Risk Assessment and Sources

PubMed Central

Tavakoly Sany, Seyedeh Belin; Hashim, Rosli; Salleh, Aishah; Rezayi, Majid; Mehdinia, Ali; Safari, Omid

2014-01-01

Concentration, source, and ecological risk of polycyclic aromatic hydrocarbons (PAHs) were investigated in 22 stations from surface sediments in the areas of anthropogenic pollution in the Klang Strait (Malaysia). The total PAH level in the Klang Strait sediment was 994.02±918.1 µg/kg dw. The highest concentration was observed in stations near the coastline and mouth of the Klang River. These locations were dominated by high molecular weight PAHs. The results showed both pyrogenic and petrogenic sources are main sources of PAHs. Further analyses indicated that PAHs primarily originated from pyrogenic sources (coal combustion and vehicular emissions), with significant contribution from petroleum inputs. Regarding ecological risk estimation, only station 13 was moderately polluted, the rest of the stations suffered rare or slight adverse biological effects with PAH exposure in surface sediment, suggesting that PAHs are not considered as contaminants of concern in the Klang Strait. PMID:24747349

Personal Breathing Zone Exposures among Hot-Mix Asphalt Paving Workers; Preliminary Analysis for Trends and Analysis of Work Practices That Resulted in the Highest Exposure Concentrations

PubMed Central

Osborn, Linda V.; Snawder, John E.; Kriech, Anthony J.; Cavallari, Jennifer M.; McClean, Michael D.; Herrick, Robert F.; Blackburn, Gary R.; Olsen, Larry D.

2015-01-01

An exposure assessment of hot-mix asphalt (HMA) paving workers was conducted to determine which of four exposure scenarios impacted worker exposure and dose. Goals of this report are to present the personal-breathing zone (PBZ) data, discuss the impact of substituting the releasing/cleaning agent, and discuss work practices that resulted in the highest exposure concentration for each analyte. One-hundred-seven PBZ samples were collected from HMA paving workers on days when diesel oil was used as a releasing/cleaning agent. An additional 36 PBZ samples were collected on days when B-100 (100% biodiesel, containing no petroleum-derived products) was used as a substitute releasing/cleaning agent. Twenty-four PBZ samples were collected from a reference group of concrete workers, who also worked in outdoor construction but had no exposure to asphalt emissions. Background and field blank samples were also collected daily. Total particulates and the benzene soluble fraction were determined gravimetrically. Total organic matter was determined using gas chromatography (GC) with flame ionization detection and provided qualitative information about other exposure sources contributing to worker exposure besides asphalt emissions. Thirty-three individual polycyclic aromatic compounds (PACs) were determined using GC with time-offlight mass spectrometry; results were presented as either the concentration of an individual PAC or a summation of the individual PACs containing either 2- to 3-rings or 4- to 6-rings. Samples were also screened for PACs containing 4- to 6-rings using fluorescence spectroscopy. Arithmetic means, medians, and box plots of the PBZ data were used to evaluate trends in the data. Box plots illustrating the diesel oil results were more variable than the B-100. Also, the highest diesel oil results were much higher in concentration than the highest B-100 results. An analysis of the highest exposure results and field notes revealed a probable association between these exposures and the use of diesel oil, use of a diesel-powered screed, elevated HMA paving application temperatures, lubricating and working on broken-down equipment, and operation of a broom machine. PMID:24195533

Personal breathing zone exposures among hot-mix asphalt paving workers; preliminary analysis for trends and analysis of work practices that resulted in the highest exposure concentrations.

PubMed

Osborn, Linda V; Snawder, John E; Kriech, Anthony J; Cavallari, Jennifer M; McClean, Michael D; Herrick, Robert F; Blackburn, Gary R; Olsen, Larry D

2013-01-01

An exposure assessment of hot-mix asphalt (HMA) paving workers was conducted to determine which of four exposure scenarios impacted worker exposure and dose. Goals of this report are to present the personal-breathing zone (PBZ) data, discuss the impact of substituting the releasing/cleaning agent, and discuss work practices that resulted in the highest exposure concentration for each analyte. One-hundred-seven PBZ samples were collected from HMA paving workers on days when diesel oil was used as a releasing/cleaning agent. An additional 36 PBZ samples were collected on days when B-100 (100% biodiesel, containing no petroleum-derived products) was used as a substitute releasing/cleaning agent. Twenty-four PBZ samples were collected from a reference group of concrete workers, who also worked in outdoor construction but had no exposure to asphalt emissions. Background and field blank samples were also collected daily. Total particulates and the benzene soluble fraction were determined gravimetrically. Total organic matter was determined using gas chromatography (GC) with flame ionization detection and provided qualitative information about other exposure sources contributing to worker exposure besides asphalt emissions. Thirty-three individual polycyclic aromatic compounds (PACs) were determined using GC with time-of-flight mass spectrometry; results were presented as either the concentration of an individual PAC or a summation of the individual PACs containing either 2- to 3-rings or 4- to 6-rings. Samples were also screened for PACs containing 4- to 6-rings using fluorescence spectroscopy. Arithmetic means, medians, and box plots of the PBZ data were used to evaluate trends in the data. Box plots illustrating the diesel oil results were more variable than the B-100. Also, the highest diesel oil results were much higher in concentration than the highest B-100 results. An analysis of the highest exposure results and field notes revealed a probable association between these exposures and the use of diesel oil, use of a diesel-powered screed, elevated HMA paving application temperatures, lubricating and working on broken-down equipment, and operation of a broom machine.

Risk assessment of petroleum-contaminated soil using soil enzyme activities and genotoxicity to Vicia faba.

PubMed

Ma, Jun; Shen, Jinglong; Liu, Qingxing; Fang, Fang; Cai, Hongsheng; Guo, Changhong

2014-05-01

Pollution caused by petroleum is one of the most serious problems worldwide. To better understand the toxic effects of petroleum-contaminated soil on the microflora and phytocommunity, we conducted a comprehensive field study on toxic effects of petroleum contaminated soil collected from the city of Daqing, an oil producing region of China. Urease, protease, invertase, and dehydrogenase activity were significantly reduced in microflora exposed to contaminated soils compared to the controls, whereas polyphenol oxidase activity was significantly increased (P < 0.05). Soil pH, electrical conductivity, and organic matter content were correlated with total petroleum hydrocarbons (TPHs) and a correlation (P < 0.01) existed between the C/N ratio and TPHs. Protease, invertase and catalase were correlated with TPHs. The Vicia faba micronucleus (MN) test, chromosome aberrant (CA) analyses, and the mitotic index (MI) were used to detect genotoxicity of water extracts of the soil. Petroleum-contaminated samples indicated serious genotoxicity to plants, including decreased index level of MI, increased frequency of MN and CA. The combination of enzyme activities and genotoxicity test via Vicia faba can be used as an important indicator for assessing the impact of TPH on soil ecosystem.

Microbial Community Response to Simulated Petroleum Seepage in Caspian Sea Sediments

PubMed Central

Stagars, Marion H.; Mishra, Sonakshi; Treude, Tina; Amann, Rudolf; Knittel, Katrin

2017-01-01

Anaerobic microbial hydrocarbon degradation is a major biogeochemical process at marine seeps. Here we studied the response of the microbial community to petroleum seepage simulated for 190 days in a sediment core from the Caspian Sea using a sediment-oil-flow-through (SOFT) system. Untreated (without simulated petroleum seepage) and SOFT sediment microbial communities shared 43% bacterial genus-level 16S rRNA-based operational taxonomic units (OTU0.945) but shared only 23% archaeal OTU0.945. The community differed significantly between sediment layers. The detection of fourfold higher deltaproteobacterial cell numbers in SOFT than in untreated sediment at depths characterized by highest sulfate reduction rates and strongest decrease of gaseous and mid-chain alkane concentrations indicated a specific response of hydrocarbon-degrading Deltaproteobacteria. Based on an increase in specific CARD-FISH cell numbers, we suggest the following groups of sulfate-reducing bacteria to be likely responsible for the observed decrease in aliphatic and aromatic hydrocarbon concentration in SOFT sediments: clade SCA1 for propane and butane degradation, clade LCA2 for mid- to long-chain alkane degradation, clade Cyhx for cycloalkanes, pentane and hexane degradation, and relatives of Desulfobacula for toluene degradation. Highest numbers of archaea of the genus Methanosarcina were found in the methanogenic zone of the SOFT core where we detected preferential degradation of long-chain hydrocarbons. Sequencing of masD, a marker gene for alkane degradation encoding (1-methylalkyl)succinate synthase, revealed a low diversity in SOFT sediment with two abundant species-level MasD OTU0.96. PMID:28503173

Responses of meiofauna and nematode communities to crude oil contamination in a laboratory microcosm experiment

NASA Astrophysics Data System (ADS)

Kang, Teawook; Oh, Je Hyeok; Hong, Jae-Sang; Kim, Dongsung

2016-09-01

We examined the effects of crude oil contamination on community assemblages of meiofauna and nematodes after exposure to total petroleum hydrocarbons in the laboratory. We administered a seawater solution that had been contaminated with total petroleum hydrocarbons to seven treatment groups at different concentrations, while the control group received uncontaminated filtered seawater. The average density of total meiofauna in the experimental microcosms diluted with 0.5%, 1%, 2%, and 4% contaminated seawater was higher than the density in the control. The average density of total meiofauna in the 8%, 15%, and 20% microcosms was lower than the density in the control. The density of nematodes was similar to that of the total meiofauna. Cluster analysis divided the microcosms into group 1 (control, 0.5%, 1%, 2%, and 4% microcosms) and group 2 (8%, 15%, and 20% microcosms). However, SIMPROF analysis showed no significant difference between the two groups ( p > 0.05). Bolbolaimus spp. (37.1%) were dominant among the nematodes. Cluster analysis showed similar results for nematode and meiofaunal communities. The total meiofaunal density, nematode density, and number of Bolbolaimus spp. individuals were significantly negatively associated with the concentration of total petroleum hydrocarbons (Spearman correlation coefficients, p < 0.05). Within the nematodes, epistrate feeders (group 2A: 46%) were the most abundant trophic group. Among the treatment groups, the abundance of group 2A increased in low-concentration microcosms and decreased in high-concentration microcosms. Thus, our findings provide information on the effects of oil pollution on meiofauna in the intertidal zones of sandy beaches.

Protoscolicidal and immunomodulatory activity of Ziziphora tenuior extract and its fractions.

PubMed

Shahnazi, Mojtaba; Azadmehr, Abbas; Andalibian, Ammar; Hajiaghaee, Reza; Saraei, Mehrzad; Alipour, Mahmood

2016-11-01

To evaluate the scolicidal and immunomodulatory effect of the Ziziphora tenuior (Z. tenuior) extract and its fractions. Protoscolices were treated with six concentrations (3, 5, 10, 25, 50, and 100 mg/mL) of Z. tenuior extract and its fractions (ethanol, petroleum ether, ethyl acetate and chloroform) in periods of 10, 20, 30, 40, 50 and 60 min, and viability of protoscolices was evaluated using the 1.0% eosin. To examine the immunomodulatory effects of Ziziphora and its fractions on macrophage cells, the non-toxic concentration of extract and different fractions determined by MTT assay, and the Griess reaction was used to measure the level of nitrite as an indicator of nitric oxide by the macrophage cells in 10, 100 and 200 μg/mL in 24 h at 37 °C. In this study, the Z. tenuior extract at 10 mg/mL concentration was able to kill all protoscolices during 20 min. By increasing the concentration to 25 mg/mL, the scolicidal time reduced to 10 min. Regarding the effect of different fractions of Z. tenuior, the ethanolic fraction showed the highest scolicidal activity. The extract demonstrated an inhibitory effect on the activity of macrophages and reduced nitric oxide production. Although the petroleum ether and ethanolic fractions of the extract reduced nitric oxide production, nevertheless, this effect was only significant at 10 and 100 μg/mL concentrations (P < 0.05). The Z. tenuior extract and its fractions were effective against protoscolices yet the effect of total extract was considerable. Our findings indicates that the extract and its ethanolic and petroleum ether fractions could have anti-inflammatory properties. Copyright © 2016 Hainan Medical University. Production and hosting by Elsevier B.V. All rights reserved.

Concentrations and sources of polycyclic aromatic hydrocarbons in surface coastal sediments of the northern Gulf of Mexico

PubMed Central

2014-01-01

Background Coastal sediments in the northern Gulf of Mexico have a high potential of being contaminated by petroleum hydrocarbons, such as polycyclic aromatic hydrocarbons (PAHs), due to extensive petroleum exploration and transportation activities. In this study we evaluated the spatial distribution and contamination sources of PAHs, as well as the bioavailable fraction in the bulk PAH pool, in surface marsh and shelf sediments (top 5 cm) of the northern Gulf of Mexico. Results PAH concentrations in this region ranged from 100 to 856 ng g−1, with the highest concentrations in Mississippi River mouth sediments followed by marsh sediments and then the lowest concentrations in shelf sediments. The PAH concentrations correlated positively with atomic C/N ratios of sedimentary organic matter (OM), suggesting that terrestrial OM preferentially sorbs PAHs relative to marine OM. PAHs with 2 rings were more abundant than those with 5–6 rings in continental shelf sediments, while the opposite was found in marsh sediments. This distribution pattern suggests different contamination sources between shelf and marsh sediments. Based on diagnostic ratios of PAH isomers and principal component analysis, shelf sediment PAHs were petrogenic and those from marsh sediments were pyrogenic. The proportions of bioavailable PAHs in total PAHs were low, ranging from 0.02% to 0.06%, with higher fractions found in marsh than shelf sediments. Conclusion PAH distribution and composition differences between marsh and shelf sediments were influenced by grain size, contamination sources, and the types of organic matter associated with PAHs. Concentrations of PAHs in the study area were below effects low-range, suggesting a low risk to organisms and limited transfer of PAHs into food web. From the source analysis, PAHs in shelf sediments mainly originated from direct petroleum contamination, while those in marsh sediments were from combustion of fossil fuels. PMID:24641695

Polycyclic aromatic hydrocarbons (PAHs) in wetland soils under different land uses in a coastal estuary: toxic levels, sources and relationships with soil organic matter and water-stable aggregates.

PubMed

Xiao, Rong; Bai, Junhong; Wang, Junjing; Lu, Qiongqiong; Zhao, Qingqing; Cui, Baoshan; Liu, Xinhui

2014-09-01

The concentrations of 16 polycyclic aromatic hydrocarbons (PAHs) were determined in the soils from industrial, wharf, cropland, milldam and natural wetland sites to characterize their distributions, toxic levels and possible sources in the Pearl River Estuary and identify their relationships with soil organic matter (SOM) and water-stable aggregates (WSAs). Our results indicate that the average concentration of total PAHs in this region reached a moderate pollution level, which was higher than that in other larger estuaries in Asia. The average level of total PAHs in industrial soils was 1.2, 1.5, 1.6 and 2.3 times higher than those in soils from wharf, cropland, milldam and natural wetland sites, respectively. Greater accumulation of PAHs occurred in the middle and/or bottom soil layers where 3-ring PAHs were dominant. Industrial soils also exhibited the highest toxic levels with the highest toxic equivalent concentrations of PAHs, followed by wharf and milldam soils, and the cropland and wetland soils had the lowest toxicity. The diagnostic ratios suggested that PAHs primarily originated from biomass and coal combustion at industrial and milldam sites, and petroleum combustion was determined to be the primary source of PAHs at the wharf, cropland and wetland sites. Both 3-ring and 4-ring PAHs in the milldam and wharf soils were significantly positively correlated with the SOM, whereas the 4,5,6-ring PAHs and total PAHs in industrial soils and the 2-ring PAHs in cropland soils were significantly negatively correlated with the SOM. In addition, large WSAs also exhibited a significant positive correlation with PAHs. Copyright © 2014 Elsevier Ltd. All rights reserved.

Characterization of Crude Oil Degrading Bacteria Isolated from Contaminated Soils Surrounding Gas Stations.

PubMed

Abou-Shanab, Reda A I; Eraky, Mohamed; Haddad, Ahmed M; Abdel-Gaffar, Abdel-Rahman B; Salem, Ahmed M

2016-11-01

A total of twenty bacterial cultures were isolated from hydrocarbon contaminated soil. Of the 20 isolates, RAM03, RAM06, RAM13, and RAM17 were specifically chosen based on their relatively higher growth on salt medium amended with 4 % crude oil, emulsion index, surface tension, and degradation percentage. These bacterial cultures had 16S rRNA gene sequences that were most similar to Ochrobactrum cytisi (RAM03), Ochrobactrum anthropi (RAM06 and RAM17), and Sinorhizobium meliloti (RAM13) with 96 %, 100 % and 99 %, and 99 % similarity. The tested strains revealed a promising potential for bioremediation of petroleum oil contamination as they could degrade >93 % and 54 % of total petroleum hydrocarbons (TPHs) in a liquid medium and soil amended with 4 % crude oil, respectively, after 30 day incubation. These bacteria could effectively remove both aliphatic and aromatic petroleum hydrocarbons. In conclusion, these strains could be considered as good prospects for their application in bioremediation of hydrocarbon contaminated environment.

GC-MS analysis of the antioxidant active fractions of Micromeria juliana with anticholinesterase activity.

PubMed

Oztürk, Mehmet; Kolak, Ufuk; Duru, Mehmet Emin; Harmandar, Mansur

2009-09-01

The aerial parts of Micromeria juliana (L.) Bentham ex Reichb. were extracted with light petroleum, acetone and methanol, successively. The antioxidant activity of different concentrations of the extracts was evaluated using different antioxidant tests, namely total antioxidant (lipid peroxidation inhibition activity), DPPH (1,1-diphenyl-2-picrylhydrazyl) radical scavenging, ferric reducing power, and metal chelating. Total antioxidant activity was determined using the beta-carotene-linoleic acid assay. Unexpectedly, the light petroleum extract exhibited strong lipid peroxidation inhibition activity. The extract was fractionated on a silica gel column and the antioxidant activity of the fractions was determined by the beta-carotene-linoleic assay at 25 microg/mL concentration. The fractions that exhibited more than 50% inhibition activity were analysed by GC and GC/MS; thus, the structure of fourteen compounds were elucidated. In addition, acetyl- and butyryl-cholinesterase inhibitory activities of the extracts were also determined in vitro. The light petroleum and acetone extracts were found to have mild butyrylcholinesterase inhibitory activity.

Controls on the distribution of alkylphenols and BTEX in oilfield waters

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dale, J.D.; Aplin, A.C.; Larter, S.R.

1996-10-01

Controls on the abundance of alkylphenols and BTEX in oilfield waters are poorly understood, but are important because these species are the main dissolved pollutants in produced waters and may also be used as indicators of both the proximity and migration range of petroleum. Using (1) measurements of alkyl phenols and BTEX in oilfield waters and associated petroleums, and (b) oil/water partition coefficients under subsurface conditions we conclude that: (1) The distribution of alkylphenols and BTEX in formation waters are controlled by partition equilibrium with petroleum. Phenol and benzene typically account for 50% of total phenols and total BTEX respectively.more » (2) The concentrations of alkylphenols and BTEX in produced waters equilibriated with oil in reservoirs or in separator systems vary predictably as a function of pressure, temperature and salinity. This suggests that oil/water partition is the primary control influencing the distribution of alkylphenols and BTEX in oilfield waters and that other processes such as hydrolysis processes at the oil-water contact are secondary.« less

Distribution of petroleum degrading genes and factor analysis of petroleum contaminated soil from the Dagang Oilfield, China

PubMed Central

Liu, Qinglong; Tang, Jingchun; Bai, Zhihui; Hecker, Markus; Giesy, John P.

2015-01-01

Genes that encode for enzymes that can degrade petroleum hydrocarbons (PHs) are critical for the ability of microorganisms to bioremediate soils contaminated with PHs. Distributions of two petroleum-degrading genes AlkB and Nah in soils collected from three zones of the Dagang Oilfield, Tianjin, China were investigated. Numbers of copies of AlkB ranged between 9.1 × 105 and 1.9 × 107 copies/g dry mass (dm) soil, and were positively correlated with total concentrations of PHs (TPH) (R2 = 0.573, p = 0.032) and alkanes (C33 ~ C40) (R2 = 0.914, p < 0.01). The Nah gene was distributed relatively evenly among sampling zones, ranging between 1.9 × 107 and 1.1 × 108 copies/g dm soil, and was negatively correlated with concentrations of total aromatic hydrocarbons (TAH) (R2 = −0.567, p = 0.035) and ∑16 PAHs (R2 = −0.599, p = 0.023). Results of a factor analysis showed that individual samples of soils were not ordinated as a function of the zones. PMID:26086670

Modeling of gas generation from the Barnett Shale, Fort Worth Basin, Texas

USGS Publications Warehouse

Hill, R.J.; Zhang, E.; Katz, B.J.; Tang, Y.

2007-01-01

The generative gas potential of the Mississippian Barnett Shale in the Fort Worth Basin, Texas, was quantitatively evaluated by sealed gold-tube pyrolysis. Kinetic parameters for gas generation and vitrinite reflectance (Ro) changes were calculated from pyrolysis data and the results used to estimate the amount of gas generated from the Barnett Shale at geologic heating rates. Using derived kinetics for Ro evolution and gas generation, quantities of hydrocarbon gas generated at Ro ??? 1.1% are about 230 L/t (7.4 scf/t) and increase to more that 5800 L/t (186 scf/t) at Ro ??? 2.0% for a sample with an initial total organic carbon content of 5.5% and Ro = 0.44%. The volume of shale gas generated will depend on the organic richness, thickness, and thermal maturity of the shale and also the amount of petroleum that is retained in the shale during migration. Gas that is reservoired in shales appears to be generated from the cracking of kerogen and petroleum that is retained in shales, and that cracking of the retained petroleum starts by Ro ??? 1.1%. This result suggests that the cracking of petroleum retained in source rocks occurs at rates that are faster than what is predicted for conventional siliciclastic and carbonate reservoirs, and that contact of retained petroleum with kerogen and shale mineralogy may be a critical factor in shale-gas generation. Shale-gas systems, together with overburden, can be considered complete petroleum systems, although the processes of petroleum migration, accumulation, and trap formation are different from what is defined for conventional petroleum systems. Copyright ?? 2007. The American Association of Petroleum Geologists. All rights reserved.

Antifungal activity from polar and non-polar extracts of some Chenopodiaceae wild species growing in Tunisia.

PubMed

Boughalleb, N; Trabelsi, L; Harzallah-Skhiri, F

2009-01-01

Nine plants belonging to Chenopodiaceae family were collected around salt marshes near Monastir, located in the east Mediterranean coast of Tunisia. They were tested for their antifungal activities against six plant pathogenic fungi: Botrytis cinerea, Fusarium oxysporum f. sp. niveum, F. solani f. sp. cucurbitae, Phytophthora cactorum, Rhizoctonia solani and Nattrassia mangiferae. Data of this study showed that the highest inhibition of Botrytis cinerea growth was observed with the petroleum ether extract of Atriplex inflata fruits (F) (24.5 mm). The in vitro growth of F. oxysporum f. sp. niveum was reduced only with A. inflata whole plant (WP) petroleum ether extract (32.3 mm). The most important inhibition zones were obtained against F. solani f. sp. cucurbitae with Atriplex semibaccata methanol and acetone extracts (34.7 and 31.0 mm, respectively). This work revealed that fungitoxic compounds were probably present in the petroleum ether extract obtained from A. portulacoides (WP), since it has suppressed the growth of F. s. cucurbitae. Our investigation proved that many Chenopodiaceae species adapted to saline soils may contain phytochemical compounds with fungicidal properties.

Assessing soil and groundwater contamination in a metropolitan redevelopment project.

PubMed

Yun, Junki; Lee, Ju Young; Khim, Jeehyeong; Ji, Won Hyun

2013-08-01

The purpose of this study was to assess contaminated soil and groundwater for the urban redevelopment of a rapid transit railway and a new mega-shopping area. Contaminated soil and groundwater may interfere with the progress of this project, and residents and shoppers may be exposed to human health risks. The study area has been remediated after application of first remediation technologies. Of the entire area, several sites were still contaminated by waste materials and petroleum. For zinc (Zn) contamination, high Zn concentrations were detected because waste materials were disposed in the entire area. For petroleum contamination, high total petroleum hydrocarbon (TPH) and hydrocarbon degrading microbe concentrations were observed at the depth of 7 m because the underground petroleum storage tank had previously been located at this site. Correlation results suggest that TPH (soil) concentration is still related with TPH (groundwater) concentration. The relationship is taken into account in the Spearman coefficient (α).

The effect of plants on the degradation and toxicity of petroleum contaminants in soil: a field assessment.

PubMed

Banks, M K; Schwab, P; Liu, B; Kulakow, P A; Smith, J S; Kim, R

2003-01-01

A field project located at the US Naval Base at Port Hueneme, California was designed to evaluate changes in contaminant concentrations and toxicity during phytoremediation. Vegetated plots were established in petroleum (diesel and heavy oil) contaminated soil and were evaluated over a two-year period. Plant species were chosen based on initial germination studies and included native California grasses. The toxicity of the impacted soil in vegetated and unvegetated plots was evaluated using Microtox, earthworm, and seed germination assays. The reduction of toxicity was affected more by contaminant aging than the establishment of plants. However, total petroleum hydrocarbon concentrations were lower by the end of the study in the vegetated plots when compared to the unvegetated soil. Although phytoremediation is an effective approach for cleaning-up of petroleum contaminated soil, a long-term management plan is required for significant reductions in contaminant concentrations.

Health status among urban residents living in proximity to petroleum coke storage: a first examination.

PubMed

Hendryx, Michael; Entwhistle, Jennifer; Kenny, Emily; Illyn, Peter

2016-01-01

We conducted an in-person survey in neighborhoods in south Chicago to examine whether residence near outdoor petroleum coke storage piles was associated with poorer health status and illness symptoms. A total of 223 adults (≥18) completed the surveys in English or Spanish, including 136 from a neighborhood exposed to the petroleum coke and 87 from a nearby comparison neighborhood. Exposure was defined based on prevailing winds and distance. We conducted a propensity score regression analysis, and found that residents in the exposed neighborhood were significantly more likely to report poor self-rated health, more unhealthy physical and mental health days, more illness symptoms including in particular respiratory and neurological symptoms, and worse perceived environmental conditions. The survey is limited by the small sample and the self-report nature of the data, but provides initial quantitative evidence that residence near outdoor petroleum coke storage piles may pose a public health risk.

Modified sequential extraction for biochar and petroleum coke: Metal release potential and its environmental implications.

PubMed

von Gunten, Konstantin; Alam, Md Samrat; Hubmann, Magdalena; Ok, Yong Sik; Konhauser, Kurt O; Alessi, Daniel S

2017-07-01

A modified Community Bureau of Reference (CBR) sequential extraction method was tested to assess the composition of untreated pyrogenic carbon (biochar) and oil sands petroleum coke. Wood biochar samples were found to contain lower concentrations of metals, but had higher fractions of easily mobilized alkaline earth and transition metals. Sewage sludge biochar was determined to be less recalcitrant and had higher total metal concentrations, with most of the metals found in the more resilient extraction fractions (oxidizable, residual). Petroleum coke was the most stable material, with a similar metal distribution pattern as the sewage sludge biochar. The applied sequential extraction method represents a suitable technique to recover metals from these materials, and is a valuable tool in understanding the metal retaining and leaching capability of various biochar types and carbonaceous petroleum coke samples. Copyright © 2017 Elsevier Ltd. All rights reserved.

Petroleum Sludge as gypsum replacement in cement plants: Its Impact on Cement Strength

NASA Astrophysics Data System (ADS)

Benlamoudi, Ali; Kadir, Aeslina Abdul; Khodja, Mohamed

2017-08-01

Due to high cost of cement manufacturing and the huge amount of resources exhaustion, companies are trying to incorporate alternative raw materials or by-products into cement production so as to produce alternative sustainable cement. Petroleum sludge is a dangerous waste that poses serious imparts on soil and groundwater. Given that this sludge contains a high percentage of anhydrite (CaSO4), which is the main component of gypsum (CaSO4.2H2O), it may play the same gypsum role in strength development. In this research, a total replacement of gypsum (100%) has been substituted by petroleum sludge in cement production and has led to an increase of 28.8% in UCS values after 28 curing days. Nevertheless, the burning of this waste has emitted a considerable amount of carbon monoxide (CO) gas that needs to be carefully considered prior to use petroleum sludge within cement plants.

Numerical taxonomy and ecology of petroleum-degrading bacteria.

PubMed Central

Austin, B; Calomiris, J J; Walker, J D; Colwell, R R

1977-01-01

A total of 99 strains of petroleum-degrading bacteria isolated from Chesapeake Bay water and sediment were identified by using numerical taxonomy procedures. The isolates, together with 33 reference cultures, were examined for 48 biochemical, cultural, morphological, and physiological characters. The data were analyzed by computer, using both the simple matching and the Jaccard coefficients. Clustering was achieved by the unweighted average linkage method. From the sorted similarity matrix and dendrogram, 14 phenetic groups, comprising 85 of the petroleum-degrading bacteria, were defined at the 80 to 85% similarity level. These groups were identified as actinomycetes (mycelial forms, four clusters), coryneforms, Enterobacteriaceae, Klebsiella aerogenes, Micrococcus spp. (two clusters), Nocardia species (two clusters), Pseudomonas spp. (two clusters), and Sphaerotilus natans. It is concluded that the degradation of petroleum is accomplished by a diverse range of bacterial taxa, some of which were isolated only at given sampling stations and, more specifically, from sediment collected at a given station. PMID:889329

Assessment of the undiscovered oil and gas of the Senegal province, Mauritania, Senegal, the Gambia, and Guinea-Bissau, northwest Africa

USGS Publications Warehouse

Brownfield, Michael E.; Charpentier, Ronald R.

2003-01-01

Undiscovered, conventional oil and gas resources were assessed in the Senegal Province as part of the U.S. Geological Survey World Petroleum Assessment 2000 (U.S. Geological Survey World Energy Assessment Team, 2000). Although several total petroleum systems may exist in the province, only one composite total petroleum system, the Cretaceous-Tertiary Composite Total Petroleum System, was defined with one assessment unit, the Coastal Plain and Offshore Assessment Unit, having sufficient data to allow quantitative assessment. The primary source rocks for the Cretaceous-Tertiary Composite Total Petroleum System are the Cenomanian-Turonian marine shales. The Turonian shales can be as much as 150 meters thick and contain Type II organic carbon ranging from 3 to 10 weight percent. In the Senegal Province, source rocks are mature even when situated at depths relatively shallow for continental passive margin basins. Reservoir rocks consist of Upper Cretaceous sandstones and lower Tertiary clastic and carbonate rocks. The Lower Cretaceous platform carbonate rocks (sealed by Cenomanian shales) have porosities ranging from 10 to 23 percent. Oligocene carbonate rock reservoirs exist, such as the Dome Flore field, which contains as much as 1 billion barrels of heavy oil (10? API, 1.6 percent sulfur) in place. The traps are a combination of structural closures and stratigraphic pinch-outs. Hydrocarbon production in the Senegal Province to date has been limited to several small oil and gas fields around Cape Verde (also known as the Dakar Peninsula) from Upper Cretaceous sandstone reservoirs bounded by normal faults, of which three fields (two gas and one oil) exceed the minimum size assessed in this study (1 MMBO; 6 BCFG). Discovered known oil resources in the Senegal Province are 10 MMBO, with known gas resources of 49 BCFG (Petroconsultants, 1996). This study estimates that 10 percent of the total number of potential oil and gas fields (both discovered and undiscovered) of at least the minimum size have been discovered. The estimated mean size and number of assessed, undiscovered oil fields are 13 MMBO and 13 fields, respectively, whereas the mean size and number of undiscovered gas fields are estimated to be 50 BCFG and 11 fields. The mean estimates for undiscovered conventional petroleum resources are 157 MMBO, 856 BCFG, and 43 MMBNGL (table 2). The mean sizes of the largest anticipated undiscovered oil and gas fields are 66 MMBO and 208 BCFG, respectively. The Senegal Province is underexplored considering its large size. The province has hydrocarbon potential in both the offshore and onshore, and undiscovered gas resources may be significant and accessible in areas where the zone of oil generation is relatively shallow.

Nutrient and suspended solids removal from petrochemical wastewater via microalgal biofilm cultivation.

PubMed

Hodges, Alan; Fica, Zachary; Wanlass, Jordan; VanDarlin, Jessica; Sims, Ronald

2017-05-01

Wastewater derived from petroleum refining currently accounts for 33.6 million barrels per day globally. Few wastewater treatment strategies exist to produce value-added products from petroleum refining wastewater. In this study, mixed culture microalgal biofilm-based treatment of petroleum refining wastewater using rotating algae biofilm reactors (RABRs) was compared with suspended-growth open pond lagoon reactors for removal of nutrients and suspended solids. Triplicate reactors were operated for 12 weeks and were continuously fed with petroleum refining wastewater. Effluent wastewater was monitored for nitrogen, phosphorus, total suspended solids (TSS), and chemical oxygen demand (COD). RABR treatment demonstrated a statistically significant increase in removal of nutrients and suspended solids, and increase in biomass productivity, compared to the open pond lagoon treatment. These trends translate to a greater potential for the production of biomass-based fuels, feed, and fertilizer as value-added products. This study is the first demonstration of the cultivation of mixed culture biofilm microalgae on petroleum refining wastewater for the dual purposes of treatment and biomass production. Copyright © 2017 Elsevier Ltd. All rights reserved.

Development of a cost-effective CO2 adsorbent from petroleum coke via KOH activation

NASA Astrophysics Data System (ADS)

Jang, Eunji; Choi, Seung Wan; Hong, Seok-Min; Shin, Sangcheol; Lee, Ki Bong

2018-01-01

The capture of CO2 via adsorption is considered an effective technology for decreasing global warming issues; hence, adsorbents for CO2 capture have been actively developed. Taking into account cost-effectiveness and environmental concerns, the development of CO2 adsorbents from waste materials is attracting considerable attention. In this study, petroleum coke (PC), which is the carbon residue remaining after heavy oil upgrading, was used to produce high-value-added porous carbon for CO2 capture. Porous carbon materials were prepared by KOH activation using different weight ratios of KOH/PC (1:1, 2:1, 3:1, and 4:1) and activation temperatures (600, 700, and 800 °C). The specific surface area and total pore volume of resulting porous carbon materials increased with KOH amount, reaching up to 2433 m2/g and 1.11 cm3/g, respectively. The sample prepared under moderate conditions with a KOH/PC weight ratio of 2:1 and activation temperature of 700 °C exhibited the highest CO2 adsorption uptake of 3.68 mmol/g at 25 °C and 1 bar. Interestingly, CO2 adsorption uptake was linearly correlated with the volume of micropores less than 0.8 nm, indicating that narrow micropore volume is crucial for CO2 adsorption. The prepared porous carbon materials also exhibited good selectivity for CO2 over N2, rapid adsorption, facile regeneration, and stable adsorption-desorption cyclic performance, demonstrating potential as a candidate for CO2 capture.

Publications - GMC 13 | Alaska Division of Geological & Geophysical Surveys

Science.gov Websites

DGGS GMC 13 Publication Details Title: Total organic carbon, rock-eval pyrolysis and vitrinite information. Bibliographic Reference Phillips Petroleum Company, 1983, Total organic carbon, rock-eval K) Keywords Pyrolysis; Rock-Eval Pyrolysis; Total Organic Carbon; Vitrinite Reflectance Top of Page

Chapter 5: Geologic Assessment of Undiscovered Petroleum Resources in the Waltman Shale Total Petroleum System,Wind River Basin Province, Wyoming

USGS Publications Warehouse

Roberts, Steve B.; Roberts, Laura N.R.; Cook, Troy

2007-01-01

The Waltman Shale Total Petroleum System encompasses about 3,400 square miles in the Wind River Basin Province, Wyoming, and includes accumulations of oil and associated gas that were generated and expelled from oil-prone, lacustrine shale source rocks in the Waltman Shale Member of the Paleocene Fort Union Formation. Much of the petroleum migrated and accumulated in marginal lacustrine (deltaic) and fluvial sandstone reservoirs in the Shotgun Member of the Fort Union, which overlies and intertongues with the Waltman Shale Member. Additional petroleum accumulations derived from Waltman source rocks are present in fluvial deposits in the Eocene Wind River Formation overlying the Shotgun Member, and also might be present within fan-delta deposits included in the Waltman Shale Member, and in fluvial sandstone reservoirs in the uppermost part of the lower member of the Fort Union Formation immediately underlying the Waltman. To date, cumulative production from 53 wells producing Waltman-sourced petroleum exceeds 2.8 million barrels of oil and 5.8 billion cubic feet of gas. Productive horizons range from about 1,770 feet to 5,800 feet in depth, and average about 3,400 to 3,500 feet in depth. Formations in the Waltman Shale Total Petroleum System (Fort Union and Wind River Formations) reflect synorogenic deposition closely related to Laramide structural development of the Wind River Basin. In much of the basin, the Fort Union Formation is divided into three members (ascending order): the lower unnamed member, the Waltman Shale Member, and the Shotgun Member. These members record the transition from deposition in dominantly fluvial, floodplain, and mire environments in the early Paleocene (lower member) to a depositional setting characterized by substantial lacustrine development (Waltman Shale Member) and contemporaneous fluvial, and marginal lacustrine (deltaic) deposition (Shotgun Member) during the middle and late Paleocene. Waltman Shale Member source rocks have total organic carbon values ranging from 0.93 to 6.21 weight percent, averaging about 2.71 weight percent. The hydrocarbon generative potential of the source rocks typically exceeds 2.5 milligrams of hydrocarbon per gram of rock and numerous samples had generative potentials exceeding 6.0 milligrams of hydrocarbon per gram of rock. Waltman source rocks are oil prone, and contain a mix of Type-II and Type-III kerogen, indicating organic input from a mix of algal and terrestrial plant matter, or a mix of algal and reworked or recycled material. Thermal maturity at the base of the Waltman Shale Member ranges from a vitrinite reflectance value of less than 0.60 percent along the south basin margin to projected values exceeding 1.10 percent in the deep basin west of Madden anticline. Burial history reconstructions for three wells in the northern part of the Wind River Basin indicate that the Waltman Shale Member was well within the oil window (Ro equal to or greater than 0.65 percent) by the time of maximum burial about 15 million years ago; maximum burial depths exceeded 10,000 feet. Onset of oil generation calculated for the base of the Waltman Shale member took place from about 49 million years ago to about 20 million years ago. Peak oil generation occurred from about 31 million years ago to 26 million years ago in the deep basin west of Madden anticline. Two assessment units were defined in the Waltman Shale Total Petroleum System: the Upper Fort Union Sandstones Conventional Oil and Gas Assessment Unit (50350301) and the Waltman Fractured Shale Continuous Oil Assessment Unit (50350361). The conventional assessment unit primarily relates to the potential for undiscovered petroleum accumulations that are derived from source rocks in the Waltman Shale Member and trapped within sandstone reservoirs in the Shotgun Member (Fort Union Formation) and in the lower part of the overlying Wind River Formation. The potential for Waltman-sourced oil accumulations in fan-delta depos

Geographical coincidence of high heat flow, high seismicity, and upwelling, with hydrocarbon deposits, phosphorites, evaporites, and uranium ores.

PubMed

Libby, L M; Libby, W F

1974-10-01

Oil deposits occur in deep sediments, and appear to be organic matter that has been transformed through the action of geothermal heat and pressure. Deep sediments, rich in biological remains, are created by ocean upwelling, caused in part by high geothermal heat flow through the sea bottom. Such regions correlate with enhanced seismic activity. We look for correlations of seismicity, high heat flux, petroleum, uranium, phosphates, and salts, deposited from abundant plant life. These may be useful in discovering more petroleum and coal. We estimate that the known world reserves of petroleum and coal are about 10(-4) of the total of buried biogenic carbon.

Geographical Coincidence of High Heat Flow, High Seismicity, and Upwelling, with Hydrocarbon Deposits, Phosphorites, Evaporites, and Uranium Ores

PubMed Central

Libby, L. M.; Libby, W. F.

1974-01-01

Oil deposits occur in deep sediments, and appear to be organic matter that has been transformed through the action of geothermal heat and pressure. Deep sediments, rich in biological remains, are created by ocean upwelling, caused in part by high geothermal heat flow through the sea bottom. Such regions correlate with enhanced seismic activity. We look for correlations of seismicity, high heat flux, petroleum, uranium, phosphates, and salts, deposited from abundant plant life. These may be useful in discovering more petroleum and coal. We estimate that the known world reserves of petroleum and coal are about 10-4 of the total of buried biogenic carbon. Images PMID:16592185

Transylvanian Composite Total Petroleum System of the Transylvanian Basin Province, Romania, Eastern Europe

USGS Publications Warehouse

Pawlewicz, Mark

2005-01-01

The Transylvanian Composite Total Petroleum System and the Transylvanian Neogene Suprasalt Gas Assessment Unit were identified in the Transylvanian Basin Province (4057), which lies entirely within the country of Romania. The assessment unit is composed of middle Miocene (Badenian) to Pliocene strata. Gas from the assessment unit is biogenic and originated from bacterial activity on dispersed organic matter in shales and siltstones. Gas migration is believed to be minimal, both vertically and laterally, with gases trapped in local stratigraphic traps and in structural traps (most likely domes and anticlinal folds created by salt diapirism) in the central part of the basin. For this reason, the gas fields also are concentrated in the central part of the basin. Reservoirs are isolated and composed of vertically stacked sandstones and siltstones sealed by shales and possibly by evaporite layers. Traps result from stratigraphic and facies changes within the entire assessment unit stratigraphic section. Some gas fields contain as much or more than a trillion cubic feet, but in most, the estimated resources are between 6 billion and 96 billion cubic feet. Petroleum exploration in the province is in the mature stage, which, combined with the geologic complexity of the region, is considered to limit future discoveries to a relatively few small fields. The undiscovered resources for the Transylvanian Basin Neogene Suprasalt Composite AU in the Transylvanian Hybrid Total Petroleum System (4057) are, at the mean, 2.083 trillion cubic feet of gas. No oil is produced in the basin. Rocks underlying the salt layers were not assessed for hydrocarbon potential.

Bioremediation of hydrocarbon degradation in a petroleum-contaminated soil and microbial population and activity determination.

PubMed

Wu, Manli; Li, Wei; Dick, Warren A; Ye, Xiqiong; Chen, Kaili; Kost, David; Chen, Liming

2017-02-01

Bioremediation of hydrocarbon degradation in petroleum-polluted soil is carried out by various microorganisms. However, little information is available for the relationships between hydrocarbon degradation rates in petroleum-contaminated soil and microbial population and activity in laboratory assay. In a microcosm study, degradation rate and efficiency of total petroleum hydrocarbons (TPH), alkanes, and polycyclic aromatic hydrocarbons (PAH) in a petroleum-contaminated soil were determined using an infrared photometer oil content analyzer and a gas chromatography mass spectrometry (GC-MS). Also, the populations of TPH, alkane, and PAH degraders were enumerated by a modified most probable number (MPN) procedure, and the hydrocarbon degrading activities of these degraders were determined by the Biolog (MT2) MicroPlates assay. Results showed linear correlations between the TPH and alkane degradation rates and the population and activity increases of TPH and alkane degraders, but no correlation was observed between the PAH degradation rates and the PAH population and activity increases. Petroleum hydrocarbon degrading microbial population measured by MPN was significantly correlated with metabolic activity in the Biolog assay. The results suggest that the MPN procedure and the Biolog assay are efficient methods for assessing the rates of TPH and alkane, but not PAH, bioremediation in oil-contaminated soil in laboratory. Copyright © 2016 Elsevier Ltd. All rights reserved.

Reuse of solid petroleum waste in the manufacture of porcelain stoneware tile.

PubMed

Pinheiro, B C A; Holanda, J N F

2013-03-30

This study investigates the incorporation of solid petroleum waste as raw material into a porcelain stoneware tile body, in replacement to natural kaolin material by up to 5 wt.%. Tile formulations containing solid petroleum waste were pressed and fired at 1240 °C by using a fast-firing cycle. The tile pieces were tested to determine their properties (linear shrinkage, water absorption, apparent density, and flexural strength), sintered microstructure, and leaching toxicity. The results therefore indicated that the growing addition of solid petroleum waste into tile formulations leads to a decrease of linear shrinkage, apparent density, and flexural strength, and to an increase of water absorption of the produced tile materials. It was also found that the replacement of kaolin with solid petroleum waste, in the range up to 2.5 wt.%, allows the production of porcelain stoneware tile (group BIa, ISO 13006 standard). All concentrations of Ag, As, Ba, Cd, Cr (total), Hg, and Pb of the fired porcelain stoneware tile pieces in the leachate comply with the current regulatory limits. These results indicate that the solid petroleum waste could be used for high-quality porcelain stoneware tile production, thus giving rise to a new possibility for an environmentally friendly management of this abundant waste. Copyright © 2013 Elsevier Ltd. All rights reserved.

Analysis of heavy oils: Method development and application to Cerro Negro heavy petroleum: Topical report. [Metal content in Cerro Negro heavy petroleum

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pearson, C.D.; Green, J.A.; Green, J.B.

1988-01-01

Nickel, vanadium, and iron were determined in distilled and chromatographically separated fractions from Cerro Negro heavy petroleum. Corresponding data were also obtained on two samples of Wilmington, California, heavy crude and one Mayan, Mexico, heavy oil for comparison. For the Cerro Negro crude, the ratio of porphyrinic to nonporphyrinic forms of metals was also determined on selected fractions using visible spectroscopy. In all four heavy petroleums, significant levels of metals were found only in the highest boiling distillate available, ca. 550-700/sup 0/C (1000-1300/sup 0/F), and the residue. Typically, the distillation residue contained >95 percent of a given metal. All crudesmore » contained metalloorganics of the following types: strongly acidic, weakly acidic, strongly basic, weakly basic, and neutral, but the relative distribution of metals among each class was crude dependent. Generally, nickel and vanadium distributions for a given crude followed one another very closely, while those for iron were often inconclusive because of poor mass balances for that element. Attempts to concentrate metalloorganics through liquid chromatographic separation methods largely unsuccessful. The wide variety of types of metal-containing compounds in the crudes examined precluded the use of a single approach for their isolation or preconcentration. 21 refs., 1 fig., 12 tabs.« less

Antioxidant properties of the red alga Asparagopsis taxiformis collected on the North West Algerian coast

PubMed Central

Mellouk, Zoheir; Benammar, Ilhem; Krouf, Djamil; Goudjil, Makhlouf; Okbi, Meriem; Malaisse, Willy

2017-01-01

The aim of the present study was to evaluate the total phenolic and lipid content, fatty acids profiles and in vitro antioxidant activities of aqueous and solvent extracts of the red seaweed Asparagopsis taxiformis, through six different investigations. The present study demonstrated that phenol contents (mg gallic acid/g dry weight) were highest in the aqueous and methanolic extracts, followed by the ethanolic, hydroethanolic and hydromethanolic extracts. The lowest phenol contents were identified in the three remaining extracts: Butanolic, petroleum ether and acetone extracts. Furthermore, the total lipid content of the algae powder amounted to 2.85% of dry weight. The fatty acid methyl ester profiles analysed by gas-liquid chromatography represented indicated that fatty acids comprised 91.0±0.3% of total algae lipids. The saturated to unsaturated fatty acid contents amounted to 23.2±0.1 and 67.9±0.4% respectively. C13:0 (tridecanoate), C15:0 (pentadecanoate) and C17:0 (heptadecanoate) represented 47.4% of the total saturated fatty acids. Notably, the two most abundant unsaturated fatty acids, C15:1 (pentadecenoate) and C18:2 (octadecadienoate) represented 13.4 and 11.4% respectively, of the total unsaturated fatty acid content. Furthermore, the results of the antioxidant screening performed at 1.0 mg/ml, revealed that aqueous and methanolic extracts exhibited higher inhibition against superoxide and nitric oxide radicals and excellent radical scavenging activity [with half maximal inhibitory concentration (IC50) values 5.1 and 15.0 µg/ml, respectively], demonstrating improved antioxidant behavior when compared with standard ascorbic acid (which has an IC50 value of 3.7 µg/ml). Scavenging activity of the aqueous and methanolic extracts exhibited a strong peroxidation inhibition against linoleic acid emulsion system at a concentration of 300 µg/ml in comparison to the butylated hydroxyltoluene. Although all the studied extracts exhibited ferric reducing power, the aqueous and methanolic extracts had greater hydrogen donating ability. By contrast, hydromethanolic, ethanolic, hydroethanolic, butanolic, acetone and petroleum ether extracts exhibited weak antioxidant behavior. The antioxidant activity of potent seaweed species identified in the current study means that as well as being used as a functional food, they may be developed as novel pharmaceutical compounds and may be used as anti-ageing agents. PMID:28587401

The future of the chemical industries

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shinnar, R.

1991-01-01

As Lincoln, we first must ask where we are before we ask whither. I'd therefore like to define where our industry is and how it got there before we look at the challenges facing us. If we view the chemical and petroleum industries through the glass of macroeconomics, they look very healthy. Let's start with size. Table 1 shows that these two industries each provide about 10% of the total U.S. manufacturing output. This paper shows the fraction of the total GNP contributed by the chemical industry and by the petroleum industry and compares them with total manufacturing. The authorsmore » note that total manufacturing grew more slowly than the total GNP, whereas over the last 40 years, the chemical industry grew close to the rate of the GNP. For a large industry, this is the best we can hope for. The chemical industry is one of the very few major industries that has consistently maintained a positive trade balance.« less

Technical basis for using passive sampling as a biomimetic extraction procedure to assess bioavailability and predict toxicity of petroleum substances.

PubMed

Redman, A D; Butler, J D; Letinski, D J; Di Toro, D M; Leon Paumen, M; Parkerton, T F

2018-05-01

Solid-phase microextraction fibers coated with polydimethylsiloxane (PDMS) provide a convenient passive sampling format to characterize bioavailability of petroleum substances. Hydrocarbons absorb onto PDMS in proportion to both freely dissolved concentrations and partitioning properties of the individual constituents, which parallels the mechanistic basis used to predict aquatic toxicity in the PETROTOX model. When deployed in a non-depletive manner, combining SPME with thermal desorption and quantification using gas chromatography-flame ionization creates a biomimetic extraction (BE) procedure that has the potential to simplify aquatic hazard assessments of petroleum substances since the total moles of all hydrocarbons sorbed to the fiber can be related to toxic thresholds in target lipid of aquatic organisms. The objective of this work is to describe the technical basis for applying BE measurements to predict toxicity of petroleum substances. Critical BE-based PDMS concentrations corresponding to adverse effects were empirically derived from toxicity tests on different petroleum substances with multiple test species. The resulting species sensitivity distribution (SSD) of PDMS effect concentrations was then compared and found consistent with the previously reported target lipid-based SSD. Further, BE data collected on samples of aqueous media dosed with a wide range of petroleum substances were highly correlated to predicted toxic units derived using the PETROTOX model. These findings provide justification for applying BE in environmental hazard and risk evaluations of petroleum substances and related mixtures. Copyright © 2018 Elsevier Ltd. All rights reserved.

Isolation and Characterization of Surface and Subsurface Bacteria in Seawater of Mantanani Island, Kota Belud, Sabah by Direct and Enrichment Techniques

NASA Astrophysics Data System (ADS)

Benard, L. D.; Tuah, P. M.; Suadin, E. G.; Jamian, N.

2015-04-01

The distribution of hydrocarbon-utilizing bacterial may vary between surface and subsurface of the seawater. One of the identified contributors is the Total Petroleum Hydrocarbon. The isolation and characterization of bacteria using Direct and Enrichment techniques helps in identifying dominant bacterial populations in seawater of Mantanani Island, Kota Belud, Sabah, potential of further investigation as hydrocarbon degrader. Crude oil (5% v/v) was added as the carbon source for bacteria in Enrichment technique. For surface seawater, the highest population of bacteria identified for both Direct and Enrichment technique were 2.60 × 107 CFU/mL and 3.84 × 106 CFU/mL respectively. Meanwhile, for subsurface seawater, the highest population of bacteria identified for both Direct and Enrichment technique were 5.21 × 106 CFU/mL and 8.99 × 107 CFU/mL respectively. Dominant species in surface seawater were characterized as Marinobacter hydrocarbonoclasticus-RMSF-C1 and RMSF-C2 and Alcanivorax borkumensis-RMSF-C3, RMSF-C4 and RMSF-C5. As for subsurface seawater, dominant species were characterized as Pseudomonas luteola-SSBR-W1, Burkholderia cepacia-SSBR-C1, Rhizobium radiobacter- SSBR-C3 and Leuconostoc-cremois -SSBR-C4.

Sediment quantity and quality in three impoundments in Massachusetts

USGS Publications Warehouse

Zimmerman, Marc James; Breault, Robert F.

2003-01-01

As part of a study with an overriding goal of providing information that would assist State and Federal agencies in developing screening protocols for managing sediments impounded behind dams that are potential candidates for removal, the U.S Geological Survey determined sediment quantity and quality at three locations: one on the French River and two on Yokum Brook, a tributary to the west branch of the Westfield River. Data collected with a global positioning system, a geographic information system, and sediment-thickness data aided in the creation of sediment maps and the calculation of sediment volumes at Perryville Pond on the French River in Webster, Massachusetts, and at the Silk Mill and Ballou Dams on Yokum Brook in Becket, Massachusetts. From these data the following sediment volumes were determined: Perryville Pond, 71,000 cubic yards, Silk Mill, 1,600 cubic yards, and Ballou, 800 cubic yards. Sediment characteristics were assessed in terms of grain size and concentrations of potentially hazardous organic compounds and metals. Assessment of the approaches and methods used at study sites indicated that ground-penetrating radar produced data that were extremely difficult and time-consuming to interpret for the three study sites. Because of these difficulties, a steel probe was ultimately used to determine sediment depth and extent for inclusion in the sediment maps. Use of these methods showed that, where sampling sites were accessible, a machine-driven coring device would be preferable to the physically exhausting, manual sediment-coring methods used in this investigation. Enzyme-linked immunosorbent assays were an effective tool for screening large numbers of samples for a range of organic contaminant compounds. An example calculation of the number of samples needed to characterize mean concentrations of contaminants indicated that the number of samples collected for most analytes was adequate; however, additional analyses for lead, copper, silver, arsenic, total petroleum hydrocarbons, and chlordane are needed to meet the criteria determined from the calculations. Particle-size analysis did not reveal a clear spatial distribution pattern at Perryville Pond. On average, less than 65 percent of each sample was greater in size than very fine sand. The sample with the highest percentage of clay-sized particles (24.3 percent) was collected just upstream from the dam and generally had the highest concentrations of contaminants determined here. In contrast, more than 90 percent of the sediment samples in the Becket impoundments had grain sizes larger than very fine sand; as determined by direct observation, rocks, cobbles, and boulders constituted a substantial amount of the material impounded at Becket. In general, the highest percentages of the finest particles, clays, occurred in association with the highest concentrations of contaminants. Enzyme-linked immunosorbent assays of the Perryville samples showed the widespread presence of petroleum hydrocarbons (16 out of 26 samples), polycyclic aromatic hydrocarbons (23 out of 26 samples), and chlordane (18 out of 26 samples); polychlorinated biphenyls were detected in five samples from four locations. Neither petroleum hydrocarbons nor polychlorinated biphenyls were detected at Becket, and chlordane was detected in only one sample. All 14 Becket samples contained polycyclic aromatic hydrocarbons. Replicate quality-control analyses revealed consistent results between paired samples. Samples from throughout Perryville Pond contained a number of metals at potentially toxic concentrations. These metals included arsenic, cadmium, copper, lead, nickel, and zinc. At Becket, no metals were found in elevated concentrations. In general, most of the concentrations of organic compounds and metals detected in Perryville Pond exceeded standards for benthic organisms, but only rarely exceeded standards for human contact. The most highly contaminated samples were

Source apportionment of VOCs and the contribution to photochemical ozone formation during summer in the typical industrial area in the Yangtze River Delta, China

NASA Astrophysics Data System (ADS)

Shao, Ping; An, Junlin; Xin, Jinyuan; Wu, Fangkun; Wang, Junxiu; Ji, Dongsheng; Wang, Yuesi

2016-07-01

Volatile organic compounds (VOCs) were continuously observated in a northern suburb of Nanjing, a typical industrial area in the Yangtze River Delta, in a summer observation period from 15th May to 31st August 2013. The average concentration of total VOCs was (34.40 ± 25.20) ppbv, including alkanes (14.98 ± 12.72) ppbv, alkenes (7.35 ± 5.93) ppbv, aromatics (9.06 ± 6.64) ppbv and alkynes (3.02 ± 2.01) ppbv, respectively. Source apportionment via Positive Matrix Factorization was conducted, and six major sources of VOCs were identified. The industry-related sources, including industrial emissions and industrial solvent usage, occupied the highest proportion, accounting for about 51.26% of the VOCs. Vehicular emissions occupied the second highest proportion, accounting for about 34.08%. The rest accounted for about 14.66%, including vegetation emission and liquefied petroleum gas/natural gas usage. Contributions of VOCs to photochemical O3 formation were evaluated by the application of a detailed chemical mechanism model (NCAR MM). Alkenes were the dominant contributors to the O3 photochemical production, followed by aromatics and alkanes. Alkynes had a very small impact on photochemical O3 formation. Based on the outcomes of the source apportionment, a sensitivity analysis of relative O3 reduction efficiency (RORE), under different source removal regimes such as using the reduction of VOCs from 10% to 100% as input, was conducted. The RORE was the highest (~ 20%-40%) when the VOCs from solvent-related sources decreased by 40%. The highest RORE values for vegetation emissions, industrial emissions, vehicle exhaust, and LPG/NG usage were presented in the scenarios of 50%, 80%, 40% and 40%, respectively.

Myelodysplastic Syndrome and Benzene Exposure Among Petroleum Workers: An International Pooled Analysis

PubMed Central

2012-01-01

Background Benzene at high concentrations is known to cause acute myeloid leukemia (AML), but its relationship with other lymphohematopoietic (LH) cancers remains uncertain, particularly at low concentrations. In this pooled analysis, we examined the risk of five LH cancers relative to lower levels of benzene exposure in petroleum workers. Methods We updated three nested case–control studies from Australia, Canada, and the United Kingdom with new incident LH cancers among petroleum distribution workers through December 31, 2006, and pooled 370 potential case subjects and 1587 matched LH cancer-free control subjects. Quantitative benzene exposure in parts per million (ppm) was blindly reconstructed using historical monitoring data, and exposure certainty was scored as high, medium, or low. Two hematopathologists assigned diagnoses and scored the certainty of diagnosis as high, medium, or low. Dose–response relationships were examined for five LH cancers, including the three most common leukemia cell-types (AML, chronic myeloid leukemia [CML], and chronic lymphoid leukemia [CLL]) and two myeloid tumors (myelodysplastic syndrome [MDS] and myeloproliferative disease [MPD]). Odds ratios (ORs) and 95% confidence intervals (CIs) were calculated using conditional logistic regression, controlling for age, sex, and time period. Results Cumulative benzene exposure showed a monotonic dose–response relationship with MDS (highest vs lowest tertile, >2.93 vs ≤0.348 ppm-years, OR = 4.33, 95% CI = 1.31 to 14.3). For peak benezene exposures (>3 ppm), the risk of MDS was increased in high and medium certainty diagnoses (peak exposure vs no peak exposure, OR = 6.32, 95% CI = 1.32 to 30.2) and in workers having the highest exposure certainty (peak exposure vs no peak exposure, OR = 5.74, 95% CI = 1.05 to 31.2). There was little evidence of dose–response relationships for AML, CLL, CML, or MPD. Conclusions Relatively low-level exposure to benzene experienced by petroleum distribution workers was associated with an increased risk of MDS, but not AML, suggesting that MDS may be the more relevant health risk for lower exposures. PMID:23111193

Evaluation of microbial population and functional genes during the bioremediation of petroleum-contaminated soil as an effective monitoring approach.

PubMed

Shahi, Aiyoub; Aydin, Sevcan; Ince, Bahar; Ince, Orhan

2016-03-01

This study investigated the abundance and diversity of soil n-alkane and polycyclic aromatic hydrocarbon (PAH)-degrading bacterial communities. It also investigated the quantity of the functional genes, the occurrence of horizontal gene transfer (HGT) in the identified bacterial communities and the effect that such HGT can have on biostimulation process. Illumina sequencing was used to detect the microbial diversity of petroleum-polluted soil prior to the biostimulation process, and quantitative real-time PCR was used to determine changes in the bacterial community and functional genes (alkB, phnAc and nah) expressions throughout the biostimulation of petroleum-contaminated soil. The illumine results revealed that γ-proteobacteria, Chloroflexi, Firmicutes, and δ-proteobacteria were the most dominant bacterial phyla in the contaminated site, and that most of the strains were Gram-negative. The results of the gene expression results revealed that gram-negative bacteria and alkB are critical to successful bioremediation. Failure to maintain the stability of hydrocarbon-degrading bacteria and functional gene will reduce the extend to which alkanes and PAHs are degraded. According to the results of the study, the application of a C:N:P ratio of was 100:15:1 in the biodegradation experiment resulted in the highest rate at which petroleum hydrocarbons were biodegraded. The diversity of pollutant-degrading bacteria and the effective transfer of degrading genes among resident microorganisms are essential factors for the successful biostimulation of petroleum hydrocarbons. As such, screening these factors throughout the biostimulation process represents an effective monitoring approach by which the success of the biostimulation can be assessed. Copyright © 2015 Elsevier Inc. All rights reserved.

Best Technical Approach for the Petroleum Quality Analysis (PQA) System

DTIC Science & Technology

1994-08-01

two test methods for determination of water content in a fuel. The Karl Fischer titration method (ASTM D 1744) measures for total water, both...difficult to automate. ASTM D 664, "Standard Test Method for Acid Number of Petroleum Products by Potentiometric Titration," is simple to automate...release. distribution unlimnied 13. ABSTRACT (Maximum 2C3 words) Recent U.S. militar-y operations have identified a need for improved methods of fuel and

Assessment of Appalachian basin oil and gas resources:Devonian shale - Middle and Upper Paleozoic Total Petroleum System

USGS Publications Warehouse

Milici, Robert C.; Swezey, Christopher S.

2006-01-01

The U.S. Geological Survey (USGS) recently completed an assessment of the technically recoverable undiscovered hydrocarbon resources of the Appalachian Basin Province. The assessment province includes parts of New York, Pennsylvania, Ohio, Maryland, West Virginia, Virginia, Kentucky, Tennessee, Georgia and Alabama. The assessment was based on six major petroleum systems, which include strata that range in age from Cambrian to Pennsylvanian. The Devonian Shale-Middle and Upper Paleozoic Total Petroleum System (TPS) extends generally from New York to Tennessee. This petroleum system has produced a large proportion of the oil and natural gas that has been discovered in the Appalachian basin since the drilling of the Drake well in Pennsylvania in 1859. For assessment purposes, the TPS was divided into 10 assessment units (plays), 4 of which were classified as conventional and 6 as continuous. The results were reported as fully risked fractiles (F95, F50, F5 and the Mean), with the fractiles indicating the probability of recovery of the assessment amount. Products reported were oil (millions of barrels of oil, MMBO), gas (billions of cubic feet of gas, BCFG), and natural gas liquids (millions of barrels of natural gas liquids, MMBNGL). The mean estimates for technically recoverable undiscovered hydrocarbons in the TPS are: 7.53 MMBO, 31,418.88 BCFG (31.42 trillion cubic feet) of gas, and 562.07 MMBNGL.

Biodegradation of petroleum hydrocarbons in estuarine sediments: metal influence.

PubMed

Almeida, Raquel; Mucha, Ana P; Teixeira, Catarina; Bordalo, Adriano A; Almeida, C Marisa R

2013-02-01

In this work, the potential effect of metals, such as Cd, Cu and Pb, on the biodegradation of petroleum hydrocarbons in estuarine sediments was investigated under laboratory conditions. Sandy and muddy non-vegetated sediments were collected in the Lima River estuary (NW Portugal) and spiked with crude oil and each of the metals. Spiked sediments were left in the dark under constant shaking for 15 days, after which crude oil biodegradation was evaluated. To estimate microbial abundance, total cell counts were obtained by DAPI staining and microbial community structure was characterized by ARISA. Culturable hydrocarbon degraders were determined using a modified most probable number protocol. Total petroleum hydrocarbons concentrations were analysed by Fourier Transform Infrared Spectroscopy after their extraction by sonication, and metal contents were determined by atomic absorption spectrometry. The results obtained showed that microbial communities had the potential to degrade petroleum hydrocarbons, with a maximum of 32 % degradation obtained for sandy sediments. Both crude oil and metals changed the microbial community structure, being the higher effect observed for Cu. Also, among the studied metals, only Cu displayed measurable deleterious effect on the hydrocarbons degradation process, as shown by a decrease in the hydrocarbon degrading microorganisms abundance and in the hydrocarbon degradation rates. Both degradation potential and metal influence varied with sediment characteristics probably due to differences in contaminant bioavailability, a feature that should be taken into account in developing bioremediation strategies for co-contaminated estuarine sites.

Distribution and sources of the polycyclic aromatic hydrocarbons in the sediments of the Pearl River estuary, China.

PubMed

Zhang, Jian-Dong; Wang, You-Shao; Cheng, Hao; Jiang, Zhao-Yu; Sun, Cui-Ci; Wu, Mei-Lin

2015-10-01

The Pearl River delta, one of the most prosperous economically region in China, has experienced significant contaminant inputs. However, the dynamics of pollutants in the Pearl River estuary and the adjacent coastal areas are still unclear at present. In the paper, distribution and sources of polycyclic aromatic hydrocarbons (PAHs) were investigated in the surface sediments of the Pearl River estuary. The total PAHs concentrations ranged from 126.08 to 3828.58 ng/g with a mean value of 563.52 ng/g, whereas the highest PAHs were observed in Guangzhou channel. Among the U.S. Environmental Protection Agency's 16 priority PAHs, PAHs with 3-4 rings exhibited relative higher levels. A positive relationship was found between PAHs and total organic carbon. The source analysis further showed that the major sources of PAHs in the Pearl River estuary were originated from the pyrolytic inputs, reflecting a mixed energy structure such as wood, coal and petroleum combustion. In summary, although PAHs in Lingding Bay and the adjacent coastal areas of the Pearl River estuary exhibited a relatively low pollution level, the relatively high pollution level of PAHs in Guangzhou channel will be attended.

Total petroleum hydrocarbon degradation by hybrid electrobiochemical reactor in oilfield produced water.

PubMed

Mousa, Ibrahim E

2016-08-15

The crude oil drilling and extraction operations are aimed to maximize the production may be counterbalanced by the huge production of contaminated produced water (PW). PW is conventionally treated through different physical, chemical, and biological technologies. The efficiency of suggested hybrid electrobiochemical (EBC) methods for the simultaneous removal of total petroleum hydrocarbon (TPH) and sulfate from PW generated by petroleum industry is studied. Also, the factors that affect the stability of PW quality are investigated. The results indicated that the effect of biological treatment is very important to keep control of the electrochemical by-products and more TPH removal in the EBC system. The maximum TPH and sulfate removal efficiency was achieved 75% and 25.3%, respectively when the detention time was about 5.1min and the energy consumption was 32.6mA/cm(2). However, a slight increasing in total bacterial count was observed when the EBC compact unit worked at a flow rate of average 20L/h. Pseudo steady state was achieved after 30min of current application in the solution. Also, the results of the study indicate that when the current intensity was increased above optimum level, no significant results occurred due to the release of gases. Copyright © 2016 Elsevier Ltd. All rights reserved.

Bioaccumulation of trace metals and total petroleum and genotoxicity responses in an edible fish population as indicators of marine pollution.

PubMed

D'Costa, Avelyno; Shyama, S K; Praveen Kumar, M K

2017-08-01

The present study reports the genetic damage and the concentrations of trace metals and total petroleum hydrocarbons prevailing in natural populations of an edible fish, Arius arius in different seasons along the coast of Goa, India as an indicator of the pollution status of coastal water. Fish were collected from a suspected polluted site and a reference site in the pre-monsoon, monsoon and post-monsoon seasons. Physico-chemical parameters as well as the concentrations of total petroleum hydrocarbons (TPH) and trace metals in the water and sediment as well as the tissues of fish collected from these sites were recorded. The genotoxicity status of the fish was assessed employing the micronucleus test and comet assay. A positive correlation (p<0.001) was observed between the tail DNA and micronuclei in all the fish collected. Multiple regression analysis revealed that tissue and environmental pollutant concentrations and genotoxicity were positively associated and higher in the tissues of the fish collected from the polluted site. Pollution indicators and genotoxicity tests, combined with other physiological or biochemical parameters represent an essential integrated approach for efficient monitoring of aquatic ecosystems in Goa. Copyright © 2017 Elsevier Inc. All rights reserved.

The use of poultry litter as co-substrate and source of inorganic nutrients and microorganisms for the ex situ biodegradation of petroleum compounds.

PubMed

Williams, C M; Grimes, J L; Mikkelsen, R L

1999-07-01

The purpose of this investigation was to determine the feasibility of utilizing poultry litter as a source of microorganisms, C co-substrate, N, and P to enhance the biodegradation of petroleum compounds in contaminated soil. An initial laboratory-scale study utilized soil contaminated with approximately 3,000 mg/kg (ppm) total petroleum hydrocarbons (TPHC) as diesel fuel. Biotreatment units, each containing 10 L of contaminated soil, were supplemented (0, 1, 10, and 20%, total weight basis) with broiler litter containing 3.65% N and 1.89% P. Petroleum-degrading microorganisms previously enriched from broiler and turkey litter were also inoculated into the litter-treated units. A significant first order rate of TPHC biodegradation was measured for all treatment units containing broiler litter (P < 0.05). Based on these results, a subsequent study was conducted at the site of a commercial facility permitted to treat soil (ex situ) contaminated with hazardous compounds. Soil treatment plots, each containing approximately 1 ton of soil contaminated with approximately 1,200 to 1,600 mg/kg diesel fuel were established. Each plot was replicated four times and the experiment was conducted for 35 d. Treatments were as follows: control, soil only; soil + commercial blend of bioremediation nutrients; soil + commercial fertilizer; soil + poultry litter (1% by volume); soil + poultry litter (10% by volume); soil + pelleted poultry litter (10% by volume). The results showed that the remediation of soil contaminated with petroleum compounds is significantly (P < 0.05) enhanced when supplemented with poultry litter (pelleted or nonpelleted) in concentrations of 10% soil volume. These results demonstrate the potential for a specialized market for the use of poultry litter.

Engineering a Synthetic Microbial Consortium for Comprehensive Conversion of Algae Biomass into Terpenes for Advanced Biofuels and Bioproducts

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wu, Weihua; Wu, Benjamin Chiau-Pin; Davis, Ryan Wesley

Recent strategies for algae-based biofuels have primarily focused on biodiesel production by exploiting high algal lipid yields under nutrient stress conditions. However, under conditions supporting robust algal biomass accumulation, carbohydrate and proteins typically comprise up to ~80% of the ash-free dry weight of algae biomass. Therefore, comprehensive utilization of algal biomass for production of multipurpose intermediate- to high-value bio-based products will promote scale-up of algae production and processing to commodity volumes. Terpenes are hydrocarbon and hydrocarbon-like (C:O>10:1) compounds with high energy density, and are therefore potentially promising candidates for the next generation of value added bio-based chemicals and “drop-in” replacementsmore » for petroleum-based fuels. In this study, we demonstrated the feasibility of bioconversion of proteins into sesquiterpene compounds as well as comprehensive bioconversion of algal carbohydrates and proteins into biofuels. To achieve this, the mevalonate pathway was reconstructed into an E. coli chassis with six different terpene synthases (TSs). Strains containing the various TSs produced a spectrum of sesquiterpene compounds in minimal medium containing amino acids as the sole carbon source. The sesquiterpene production was optimized through three different regulation strategies using chamigrene synthase as an example. The highest total terpene titer reached 166 mg/L, and was achieved by applying a strategy to minimize mevalonate accumulation in vivo. The highest yields of total terpene were produced under reduced IPTG induction levels (0.25 mM), reduced induction temperature (25°C), and elevated substrate concentration (20 g/L amino acid mixture). A synthetic bioconversion consortium consisting of two engineering E. coli strains (DH1-TS and YH40-TS) with reconstructed terpene biosynthetic pathways was designed for comprehensive single-pot conversion of algal carbohydrates and proteins to sesquiterpenes. The consortium yielded the highest total terpene yields (187 mg/L) at an inoculum ratio 2:1 of strain YH40-TS: DH1-TS, corresponding to 31 mg fuel/g algae biomass ash free dry weight. This study therefore demonstrates a feasible process for comprehensive algal biofuel production.« less

Bioremediation of soil contaminated crude oil by Agaricomycetes.

PubMed

Mohammadi-Sichani, M Maryam; Assadi, M Mazaheri; Farazmand, A; Kianirad, M; Ahadi, A M; Ghahderijani, H Hadian

2017-01-01

One of the most important environmental problems is the decontamination of petroleum hydrocarbons polluted soil, particularly in the oil-rich country. Bioremediation is the most effective way to remove these pollutants in the soil. Spent mushroom compost has great ability to decompose lignin-like pollution. The purpose of this study was the bioremediation of soil contaminated with crude oil by an Agaricomycetes . Soil sample amended with spent mushroom compost into 3%, 5% and 10% (w/w) with or without fertilizer. Ecotoxicity germination test was conducted with Lipidium sativa . The amplified fragment (18 s rDNA) sequence of this mushroom confirmed that the strain belonged to Pleurotus ostreatus species with complete homology (100% identity). All tests experiment sets were effective at supporting the degradation of petroleum hydrocarbons contaminated soil after three months. Petroleum contaminated soil amended with Spent mushroom compost 10% and fertilizer removed 64.7% of total petroleum hydrocarbons compared control. The germination index (%) in ecotoxicity tests ranged from 60.4 to 93.8%. This showed that the petroleum hydrocarbons contaminated soil amended with 10% Spent mushroom compost had higher bioremediation ability and reduced soil toxicity in less than three months.

Measurement of total acid number (TAN) and TAN boiling point distribution in petroleum products by electrospray ionization mass spectrometry.

PubMed

Qian, Kuangnan; Edwards, Kathleen E; Dechert, Gary J; Jaffe, Stephen B; Green, Larry A; Olmstead, William N

2008-02-01

We report a new method for rapid measurement of total acid number (TAN) and TAN boiling point (BP) distribution for petroleum crude and products. The technology is based on negative ion electrospray ionization mass spectrometry (ESI-MS) for selective ionization of petroleum acid and quantification of acid structures and molecular weight distributions. A chip-based nanoelectrospray system enables microscale (<200 mg) and higher throughput (20 samples/h) measurement. Naphthenic acid structures were assigned based on nominal masses of a set of predefined acid structures. Stearic acid is used as an internal standard to calibrate ESI-MS response factors for quantification purposes. With the use of structure-property correlations, boiling point distributions of TAN values can be calculated from the composition. The rapid measurement of TAN BP distributions by ESI is demonstrated for a series of high-TAN crudes and distillation cuts. TAN values determined by the technique agree well with those by the titration method. The distributed properties compare favorably with those measured by distillation and measurement of TAN of corresponding cuts.

FORSPAN Model Users Guide

USGS Publications Warehouse

Klett, T.R.; Charpentier, Ronald R.

2003-01-01

The USGS FORSPAN model is designed for the assessment of continuous accumulations of crude oil, natural gas, and natural gas liquids (collectively called petroleum). Continuous (also called ?unconventional?) accumulations have large spatial dimensions and lack well defined down-dip petroleum/water contacts. Oil and natural gas therefore are not localized by buoyancy in water in these accumulations. Continuous accumulations include ?tight gas reservoirs,? coalbed gas, oil and gas in shale, oil and gas in chalk, and shallow biogenic gas. The FORSPAN model treats a continuous accumulation as a collection of petroleumcontaining cells for assessment purposes. Each cell is capable of producing oil or gas, but the cells may vary significantly from one another in their production (and thus economic) characteristics. The potential additions to reserves from continuous petroleum resources are calculated by statistically combining probability distributions of the estimated number of untested cells having the potential for additions to reserves with the estimated volume of oil and natural gas that each of the untested cells may potentially produce (total recovery). One such statistical method for combination of number of cells with total recovery, used by the USGS, is called ACCESS.

Comparison of landfarming amendments to improve bioremediation of petroleum hydrocarbons in Niger Delta soils.

PubMed

Brown, David M; Okoro, Samson; van Gils, Juami; van Spanning, Rob; Bonte, Matthijs; Hutchings, Tony; Linden, Olof; Egbuche, Uzoamaka; Bruun, Kim Bye; Smith, Jonathan W N

2017-10-15

Large scale landfarming experiments, using an extensive range of treatments, were conducted in the Niger-Delta, Nigeria to study the degradation of oil in contaminated soils. In this work the effect of nutrient addition, biosurfactant, Eisenia fetida (earthworm) enzyme extract, bulking and sorption agents and soil neutralization were tested. It was found that these treatments were successful in removing up to 53% of the total petroleum hydrocarbon in the soil within 16 weeks. A comparison between treatments demonstrated that most were no more effective than agricultural fertilizer addition alone. One strategy that did show better performance was a combination of nutrients, biochar and biosurfactant, which was found to remove 23% more Total Petroleum Hydrocarbons (TPH) than fertilizer alone. However, when performance normalized costs were considered, this treatment became less attractive as a remedial option. Based on this same analysis it was concluded that fertilizer only was the most cost effective treatment. As a consequence, it is recommended that fertilizer is used to enhance the landfarming of hydrocarbon contaminated soils in the Niger Delta. The attenuation rates of both bulk TPH and Total Petroleum Hydrocarbon Criteria Working Group (TPHCWG) fractions are also provided. These values represent one of the first large scale and scientifically tested datasets for treatment of contaminated soil in the Niger Delta region. An inverse correlation between attenuation rates and hydrocarbon molecular weight was observed with heavy fractions showing much slower degradation rates than lighter fractions. Despite this difference, the bioremediation process resulted in significant removal of all TPH compounds independent of carbon number. Copyright © 2017 The Authors. Published by Elsevier B.V. All rights reserved.

Numerical taxonomy and ecology of petroleum-degrading bacteria

DOE Office of Scientific and Technical Information (OSTI.GOV)

Austin, B.; Calomiris, J.J.; Walker, J.D.

1977-07-01

A total of 99 strains of petroleum-degrading bacteria isolated from Chesapeake Bay water and sediment were identified by using numerical taxonomy procedures. The isolates, together with 33 reference cultures, were examined for 48 biochemical, cultural, morphological, and physiological characters. The data were analyzed by computer, using both the simple matching and the Jaccard coefficients. Clustering was achieved by the unweighted average linkage method. From the sorted similarity matrix and dendrogram, 14 phenetic groups, comprising 85 of the petroleum-degrading bacteria, were defined at the 80 to 85% similarity level. These groups were identified as actinomycetes (mycelial forms, four clusters), coryneforms, Enterobacteriaceae,more » Klebsiella aerogenes, Micrococcus spp. (two clusters), Nocardia species (two clusters), Pseudomonas spp. (two clusters), and Sphaerotilus natans. It is concluded that the degradation of petroleum is accomplished by a diverse range of bacterial taxa, some of which were isolated only at given sampling stations and, more specifically, from sediment collected at a given station.« less

U.S. Geological Survey Assessment of Undiscovered Petroleum Resources of the Hamra Basin, Libya, 2006

USGS Publications Warehouse

,

2007-01-01

The Hamra Basin Province encompasses approximately 244,100 square kilometers (94,250 square miles) and is entirely within Libya. One composite total petroleum system (TPS) was defined for this assessment; it extends from Libya westward into adjacent parts of Algeria and southern Tunisia. The Hamra Basin part of the TPS was subdivided into four assessment units for the purpose of resource assessment. The assessment units cover only 172,390 square kilometers of the Hamra Basin Province; the remaining area has little potential for undiscovered petroleum resources because of the absence of petroleum source rocks. Using a geology-based assessment methodology, the U.S. Geological Survey estimated mean volumes of 784 million barrels of crude oil, 4,748 billion cubic feet of natural gas, and 381 million barrels of natural gas liquids in the Hamra Basin of northwestern Libya. Most of the undiscovered crude oil and natural gas are interpreted to be in deeper parts of the Hamra Basin.

A novel bioremediation strategy for petroleum hydrocarbon pollutants using salt tolerant Corynebacterium variabile HRJ4 and biochar.

PubMed

Zhang, Hairong; Tang, Jingchun; Wang, Lin; Liu, Juncheng; Gurav, Ranjit Gajanan; Sun, Kejing

2016-09-01

The present work aimed to develop a novel strategy to bioremediate the petroleum hydrocarbon contaminants in the environment. Salt tolerant bacterium was isolated from Dagang oilfield, China and identified as Corynebacterium variabile HRJ4 based on 16S rRNA gene sequence analysis. The bacterium had a high salt tolerant capability and biochar was developed as carrier for the bacterium. The bacteria with biochar were most effective in degradation of n-alkanes (C16, C18, C19, C26, C28) and polycyclic aromatic hydrocarbons (NAP, PYR) mixture. The result demonstrated that immobilization of C. variabile HRJ4 with biochar showed higher degradation of total petroleum hydrocarbons (THPs) up to 78.9% after 7-day of incubation as compared to the free leaving bacteria. The approach of this study will be helpful in clean-up of petroleum-contamination in the environments through bioremediation process using eco-friendly and cost effective materials like biochar. Copyright © 2016. Published by Elsevier B.V.

Assessment of undiscovered petroleum resources of the Arctic Alaska Petroleum Province

USGS Publications Warehouse

Houseknecht, David W.; Bird, Kenneth J.; Garrity, Christopher P.

2012-01-01

The Arctic Alaska Petroleum Province encompasses all lands and adjacent continental shelf areas north of the Brooks Range-Herald arch tectonic belts and south of the northern (outboard) margin of the Alaska rift shoulder. Even though only a small part is thoroughly explored, it is one of the most prolific petroleum provinces in North America, with total known resources (cumulative production plus proved reserves) of about 28 billion barrels of oil equivalent. For assessment purposes, the province is divided into a platform assessment unit, comprising the Alaska rift shoulder and its relatively undeformed flanks, and a fold-and-thrust belt assessment unit, comprising the deformed area north of the Brooks Range and Herald arch tectonic belts. Mean estimates of undiscovered, technically recoverable resources include nearly 28 billion barrels of oil and 122 trillion cubic feet of nonassociated gas in the platform assessment unit and 2 billion barrels of oil and 59 trillion cubic feet of nonassociated gas in the fold-and-thrust belt assessment unit.

Hydrocarbons in the sediments of the Bermuda region lagoonal to abyssal depths

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sletter, T.D.; Butler, J.N.; Barbash, J.E.

1980-01-01

Gas chromatographic analyses of the pentane fraction derived from surface sediments collected from 20 stations (50 cores) around Bermuda from the subtidal zone to 40 m depth and one deep-water sediment sample from 1400 m depth showed that outside the protective boiler reef, the total aliphatic (pentane-extractable) hydrocarbon content was less than inside the reef (3-10 jg/g dry weight outside vs. 10-65 jg/g inside). Samples from the 1400 m depth showed < 1.0 jg/g aliphatic hydrocarbon content. The chromatograms from the shipping channels showed fresh petroleum source concentrations of 8-31 jg/g; harbors yielded chromatograms typical of chronic petroleum contamination, withmore » 30-110 jg/g concentrations. Several biogenic compounds (including C15 and C17 n-alkanes and most probably derived from marine algae) were observed, in addition to the petroleum-derived hydrocarbons. The criteria adopted for distinguishing biogenic and petroleum hydrocarbons are given.« less

Removal of petroleum hydrocarbons from contaminated groundwater by the combined technique of adsorption onto perlite followed by the O3/H2O2 process.

PubMed

Moussavi, Gholamreza; Bagheri, Amir

2012-09-01

Groundwater contaminated with petroleum hydrocarbons was treated using a combined system of adsorption onto powdered expanded perlite (PEP) followed by the O3/H2O2 process. The pretreatment investigations indicated a high capacity for PEP to remove petroleum hydrocarbons from the contaminated water. An experimental total petroleum hydrocarbon (TPH) adsorption capacity of 275 mg/g PEP was obtained at the natural pH of water. The experimental data fit best with the Freundlich isotherm model and pseudo-second-order adsorption model. The second phase of the experiment evaluated the performance of the O3/H2O2 process in the removal of residual TPH from pretreated water and compared the results with that of raw water. The O3/H202 process attained a maximum TPH removal rate for the pretreated water after 70 min, when 93% of the residual TPH in the effluent of the adsorption system was removed. Overall, the combination of adsorption onto PEP for 100 min and the subsequent treatment with the O3/H2O2 process for 70min eliminated over 99% of the TPH of highly petroleum-contaminated groundwater, with initial values of 162 mg/L. Therefore, we can conclude that the developed treatment system is an appropriate method of remediation for petroleum-contaminated waters.

Soil TPH Concentration Estimation Using Vegetation Indices in an Oil Polluted Area of Eastern China

PubMed Central

Zhu, Linhai; Zhao, Xuechun; Lai, Liming; Wang, Jianjian; Jiang, Lianhe; Ding, Jinzhi; Liu, Nanxi; Yu, Yunjiang; Li, Junsheng; Xiao, Nengwen; Zheng, Yuanrun; Rimmington, Glyn M.

2013-01-01

Assessing oil pollution using traditional field-based methods over large areas is difficult and expensive. Remote sensing technologies with good spatial and temporal coverage might provide an alternative for monitoring oil pollution by recording the spectral signals of plants growing in polluted soils. Total petroleum hydrocarbon concentrations of soils and the hyperspectral canopy reflectance were measured in wetlands dominated by reeds (Phragmites australis) around oil wells that have been producing oil for approximately 10 years in the Yellow River Delta, eastern China to evaluate the potential of vegetation indices and red edge parameters to estimate soil oil pollution. The detrimental effect of oil pollution on reed communities was confirmed by the evidence that the aboveground biomass decreased from 1076.5 g m−2 to 5.3 g m−2 with increasing total petroleum hydrocarbon concentrations ranging from 9.45 mg kg−1 to 652 mg kg−1. The modified chlorophyll absorption ratio index (MCARI) best estimated soil TPH concentration among 20 vegetation indices. The linear model involving MCARI had the highest coefficient of determination (R 2 = 0.73) and accuracy of prediction (RMSE = 104.2 mg kg−1). For other vegetation indices and red edge parameters, the R2 and RMSE values ranged from 0.64 to 0.71 and from 120.2 mg kg−1 to 106.8 mg kg−1 respectively. The traditional broadband normalized difference vegetation index (NDVI), one of the broadband multispectral vegetation indices (BMVIs), produced a prediction (R 2 = 0.70 and RMSE = 110.1 mg kg−1) similar to that of MCARI. These results corroborated the potential of remote sensing for assessing soil oil pollution in large areas. Traditional BMVIs are still of great value in monitoring soil oil pollution when hyperspectral data are unavailable. PMID:23342066

Cytogenetic and viability effects of petroleum aromatic and PCB hydrocarbons, temperature and salinity, on early development of the American oyster, Crassostrea virginica Gmelin

DOE Office of Scientific and Technical Information (OSTI.GOV)

Stiles-Jewell, S.

1994-01-01

Fertilized eggs were exposed to 0.1, 10 and 100 mg/l of benzene, naphthalene and Aroclor 1254 individually and in combination in seawater at temperatures and salinities of 20 and 25. Toxicity was measured as frequencies of: (1) meiotic and mitotic abnormalities in 3-hour embryos; (2) total development to the 48-hour straight-hinge larval stage; (3) mortality and abnormality at the 48-hour larval stage; (4) mean size of larvae at 48 hours; and (5) cytogenetic and cytological abnormalities in 48-hour larvae. Dose-dependent responses were observed. Overall, naphthalene and aroclor at 100 mg/l had few embryos that survived to the stage where theymore » could be examined and scored for cytogenetic and cytological abnormality even by 3-hours post-fertilization. Abnormality of the few embryos available for examination was somewhat higher for aroclor but was significantly higher for naphthalene than for control embryos and those exposed to 0.1 mg/l. At the highest concentration of 100 mg/l, mortality was 100% by the larval stage for naphthalene and aroclor. Though total development and survival of embryos to the larval stage at the 10 mg/l dose were high, many of the larvae were dead or abnormal in the aroclor-exposed cultures. This mean incidence was significantly higher than for all other groups. Larvae developing in these cultures with 10 mg/l were also significantly smaller and cytological condition of the larvae was significantly worse. Higher temperature appeared to increase the frequency of deleterious effects, particularly for naphthalene and aroclor. Results with salinity were more variable. Overall, results showed that petroleum aromatic hydrocarbons and PCBs can have toxic effects on the development and survival of early life stages of oysters, as well as sublethal effects on growth and cytological condition, depending on dose and interactions with other compound and with environmental variables.« less

Petroleum hydrocarbon concentrations in marine sediments along Chennai Coast, Bay of Bengal, India.

PubMed

Venkatachalapathy, R; Veerasingam, S; Ramkumar, T

2010-10-01

The spatial and temporal distribution of petroleum hydrocarbons (PHC) in marine sediments along the Chennai coast, Bay of Bengal was quantified by Ultra-Violet Fluorescence (UVF) Spectroscopy. The concentration of PHC in surface sediments varied from 1.88 to 39.76 ppm. The highest values obtained in the northern part of the study area, where shipping activities and land-based waste waters disposed into sea through the rivers like Kuvam and Adayar. The Adayar (7.26-16.83 ppm) and Kuvam (5.5-39.72 ppm) cores reveal a clear horizon of increase in PHC above 50 and 35 cm respectively. PHC values showed a decreasing pattern with depth in all sediment cores suggesting the excess anthropogenic loading occurring in the recent past. The present study revealed that the PHC values of Chennai coastal sediments are lower than the values reported from selected costal areas including the sediment of the Mumbai coast (7.6-42.8 ppm), Arabian Sea. The results will be useful for pollution monitoring program along the coastal region and also to check the level of petroleum hydrocarbons in marine sediments.

The Militarily Useful Clean Product Tanker: Sealift Component of the DoD Petroleum Distribution System.

DTIC Science & Technology

1983-12-01

dentlfIr by block numbher) Clean product tanker Defense Fuel Supply Center (DFSC) Handy Size Tanker (HST) Petroleum, Lubricants, and Oils (POL) Military...ccnsumer representing approximately 81 percent of tha " total. The majority of DOD energy is in the form of petro- leum, oil and lubricants (POL) with...annual consumption equating to 250 million barrels of oil . it h over five percent of *he DOD budget devoted to energy expnadiu::es, it is reasonable to

Hydrocarbons in sediments along a tropical estuary-shelf transition area: Sources and spatial distribution.

PubMed

Maciel, Daniele Claudino; de Souza, José Roberto Botelho; Taniguchi, Satie; Bícego, Márcia Caruso; Schettini, Carlos Augusto França; Zanardi-Lamardo, Eliete

2016-12-15

Estuaries generally act as sediment traps and may retain a range of contaminants associated to this matrix. Aliphatic hydrocarbons (AHs) were investigated in Capibaribe Estuarine System and adjacent shelf, Northeast of Brazil, to evaluate the contamination and to better understand its functionality related to the coast. Fourteen sediment samples were analyzed, using gas chromatography with flame ionization detection. Total AHs concentrations ranged from 7.5 to 190.3μgg -1 and n-alkanes ranged from below detection limit (

The generalized 20/80 law using probabilistic fractals applied to petroleum field size

USGS Publications Warehouse

Crovelli, R.A.

1995-01-01

Fractal properties of the Pareto probability distribution are used to generalize "the 20/80 law." The 20/80 law is a heuristic law that has evolved over the years into the following rule of thumb for many populations: 20 percent of the population accounts for 80 percent of the total value. The general p100/q100 law in probabilistic form is defined with q as a function of p, where p is the population proportion and q is the proportion of total value. Using the Pareto distribution, the p100/q100 law in fractal form is derived with the parameter q being a fractal, where q unexpectedly possesses the scale invariance property. The 20/80 law is a special case of the p100/q100 law in fractal form. The p100/q100 law in fractal form is applied to petroleum fieldsize data to obtain p and q such that p100% of the oil fields greater than any specified scale or size in a geologic play account for q100% of the total oil of the fields. The theoretical percentages of total resources of oil using the fractal q are extremely close to the empirical percentages from the data using the statistic q. Also, the empirical scale invariance property of the statistic q for the petroleum fieldsize data is in excellent agreement with the theoretical scale invariance property of the fractal q. ?? 1995 Oxford University Press.

Antimicrobial activities of the rhizome extract of Zingiber zerumbet Linn.

PubMed

Kader, Golam; Nikkon, Farjana; Rashid, Mohammad Abdur; Yeasmin, Tanzima

2011-10-01

To investigate antimicrobial effects of ethanolic extract of Zingiber zerumbet (Z. zerumbet) (L.) Smith and its chloroform and petroleum ether soluble fractions against pathogenic bacteria and fungi. The fresh rhizomes of Zingiber zerumbet were extracted in cold with ethanol (4.0 L) after concentration. The crude ethanol extract was fractionated by petroleum ether and chloroform to form a suspension of ethanol extract (15.0 g), petroleum ether fraction (6.6 g) and chloroform soluble fraction (5.0 g). The crude ethanol extract and its petroleum ether and chloroform fractions were evaluated for antibacterial and antifungal activity against thirteen pathogenic bacteria and three fungi by the disc diffusion method. Commercially available kanamycin (30 µg/disc) was used as standard disc and blank discs impregnated with the respective solvents were used as negative control. At a concentration of 400 µg/disc, all the samples showed mild to moderate antibacterial and antifungal activity and produced the zone of inhibition ranging from 6 mm to 10 mm. Among the tested samples, the crude ethanol extract showed the highest activity against Vibrio parahemolyticus (V. parahemolyticus). The minimum inhibitory concentration (MIC) of the crude ethanol extract and its fractions were within the value of 128-256 µg/mL against two Gram positive and four Gram negative bacteria and all the samples showed the lowest MIC value against V. parahemolyticus (128 µg/mL). It can be concluded that, potent antibacterial and antifungal phytochemicals are present in ethanol extract of Z. zerumbet (L).

Thermal Decomposition of Methyl Esters in Biodiesel Fuel: Kinetics, Mechanisms and Products

NASA Astrophysics Data System (ADS)

Chai, Ming

Biodiesel continues to enjoy increasing popularity. However, recent studies on carbonyl compounds emissions from biodiesel fuel are inconclusive. Emissions of carbonyl compounds from petroleum diesel fuels were compared to emissions from pure biodiesel fuels and petroleum-biodiesel blends used in a non-road diesel generator. The concentration of total carbonyl compounds was the highest when the engine was idling. The carbonyl emissions, as well as ozone formation potential, from biodiesel fuel blends were higher than those emitted from petroleum diesel fuel. The sulfur content of diesel fuel and the source of biodiesel fuel were not found to have a significant impact on emissions of carbonyl compounds. Mechanism parameters of the thermal decomposition of biodiesel-range methyl esters were obtained from the results of thermal gravimetric analysis (TGA). The overall reaction orders are between 0.49 and 0.71 and the energies of activation are between 59.9 and 101.3 kJ/mole. Methyl esters in air have lower activation energies than those in nitrogen. Methyl linoleate has the lowest activation energy, followed by methyl oleate, and methyl stearate. The pyrolysis and oxidation of the three methyl esters were investigated using a semi-isothermal tubular flow reactor. The profiles of major products versus reaction temperature are presented. In the pyrolysis of methyl stearate, the primary reaction pathway is the decarboxylic reaction at the methyl ester functional group. Methyl oleate's products indicate more reactions on its carbon-carbon double bond. Methyl linoleate shows highest reactivity among the three methyl esters, and 87 products were detected. The oxidation of three methyl esters resulted in more products in all compound classes, and 55, 114, and 127 products were detected, respectively. The oxidation of methyl esters includes decarboxylation on ester group. The methyl ester's carbon chain could be oxidized as a hydrocarbon compound and form oxidized esters and unsaturated esters, which have been observed in methyl ester's oxidation products. The oxidation of methyl stearate, methyl oleate and methyl linoleate produces 16, 28 and 34 types of carbonyl compounds, respectively. The unsaturated methyl ester forms more carbonyl compounds compared to the saturated methyl ester, which indicates the formation of carbonyl compounds might be more related to the unsaturated carbon bond rather than the methyl ester group. Good agreement between results for total carbon (TC) generally has been found, but the organic and elemental carbon (OC and EC) fractions determined by different methods often disagree. Lack of reference materials has impeded progress on method standardization and understanding method biases. As part of this dissertation, uniform carbon distribution for the filter sets is prepared by using a simply aerosol generation and collection method. The relative standard deviations for the mean TC, OC, and EC results reported by the seven laboratories were below 10%, 11% and 12% (respectively). The method of filter generation is generally applicable and reproducible. Depending on the application, different filter loadings and types of OC materials can be employed. Matched filter sets prepared by this approach can be used for determining the accuracy of various OC-EC methods and thereby contribute to method standardization.

[A socio-economic profile of exposed populations to petroleum exploration residues].

PubMed

Corrêa, Gyselle Guimarães; Malhão, Thainá Alves; Asmus, Carmen Ildes Rodrigues Fróes; Coeli, Cláudia Medina

2011-09-01

Environmental Macro-Area Five (EMA-5) is located in Rio de Janeiro. Their municipalities are suffering the consequences of rapid urbanization, especially after the discovery of large reserves of petroleum and natural gas (PNG) in the Campos Basin. To describe the socio-economic profile of the region and compare their indicators in space and time. This is an ecological study, which made comparisons between the 11 municipalities of EMA-5. It is based on the behavior of the indicators before and after the increase in royalties and special participatioms (RPE) and the division of the production areas of PNG (main production area - MPA - and the border zone of MPA, BZMPA). The period of analysis of the indicators ranged from 1991 to 2005. Higher values of gross domestic product per capita were found in the municipalities of MPA, especially Macaé. The same occurred in the RPE per capita, especially Rio das Ostras (higher value) and Nova Friburgo (lower value). In 2004, more than 50% of total revenues of municipalities were dependent on the funds derived from royalties. In 2000, Nova Friburgo had the best Human Development Index. The highest value of the Quality Index of Municipalities Potential for Development was found in Macaé. The major indexes of Social Exclusion was found in Macaé, Nova Friburgo and Rio das Ostras. It was found, in the municipalities of MPA, economic growth with great exclusive reliance on royalties. It should invest in alternative economic activities for which there is no damage to the population with the completion of these resources.

Chemical composition, antioxidant and antimicrobial effects of Tunisian Limoniastrum guyonianum Durieu ex Boiss extracts.

PubMed

Bouzidi, Amel; Benzarti, Anissa; Arem, Amira El; Mahfoudhi, Adel; Hammami, Saoussen; Gorcii, Mohamed; Mastouri, Maha; Hellal, Ahmed Noureddine; Mighri, Zine

2016-07-01

In the present investigation, extracts obtained from L. guyonianum Durieu ex Boiss. aerial parts were used to evaluate total phenolic, flavonoid and tannin contents. A study of antioxidant activities of the prepared samples was carried out on the basis of 1,1-Diphenyl-2-picrylhydrazyl (DPPH), 2-2'-azino-bis-(3-ethylbenz-thiazoline-6-sulfonic acid) (ABTS+.) and ferric reducing antioxidant power (FRAP) assays. Moreover, the efficiency of methanolic, chloroformic and petroleum ether extracts and the deriving fractions from the methanolic extract was tested against human bacterial and fungal pathogenic strains using micro dilution method in 96 multiwell microtiter plate. Furthermore, leaves and stems extracts were subjected to RP-HPLC for phenolic compounds identification. Results showed that polyphenolic contents and antioxidant activities varied considerably as function of solvent polarity. Moreover, antiradical capacities against DPPH, ABTS(+.) and reducing power were maxima in methanol aerial parts extract which showed the highest polyphenol contents (134mg CE/g DW). The antimicrobial activities showed that methanolic, chloroformic and petroleum ether extracts were found to be most potent against Pseudomonas aeruginosa and Staphylococcus aureus with MIC values of 23 and 46μ.mL(-1), respectively. The fractions F(13) and F(16) have a great antifungal potential against Candida glabrata, Candida krusei and Candida parapsilesis (MIC=39μ.mL(-1)). The RP-HPLC analysis lead the identification of gallic, procatechuic and trans-cinnamic acids, methyl-4-hydroxybenzoate, n-propyl-3,4,5-trihydroxybenzoate, epicatechin, naringin and myricetin in L. guyonianum Durieu ex Boiss. leaves and stems extracts.

Environmental issues of petroleum exploration and production: Introduction

USGS Publications Warehouse

Kharaka, Yousif K.; Dorsey, Nancy S.

2005-01-01

Energy is the lifeblood of our planet Earth, an essential commod- ity that powers the expanding global economy. Starting in the 1950s, oil and natural gas became the main sources of primary energy for the increasing world population, and this dominance is expected to continue for several more decades (Edwards, 1997; Energy Information Administration (EIA), 2004). In the United States, petroleum production started in 1859 when Drake's well was drilled near Titusville, Pennsylvania, and oil and natural gas currently supply approximately 63% of the energy consumption; forecasts indicate that by 2025, their use will increase by about 40% to 28.3 million bbl/day and to 31.4 tcf/yr (EIA, 2004). The clear benefits of petroleum consumption, however, can carry major environmental impacts that may be regional or global in scale, in- cluding air pollution, global climate change, and oil spills. This vol- ume of Environmental Geosciences, covering environmental impacts of petroleum exploration and production, does not address these major impacts directly because air pollution and global warming are issues related primarily to petroleum and coal uses, and major oil spills are generally attributed to marine petroleum transportation, such as the Exxon Valdez's 1989 spill of 260,000 bbl of oil into Prince William Sound, Alaska. Exploration for and production of petroleum, however, have caused local detrimental impacts to soils, surface and groundwa- ters, and ecosystems in the 36 producing states in the United States (Richter and Kreitler, 1993; Kharaka and Hanor, 2003). These im- pacts arose primarily from the improper disposal of some of the large volumes (presently estimated at 20 billion bbl/yr total pro- duced) of saline water produced with oil and gas, from accidental hydrocarbon and produced-water releases, and from abandoned oil wells that were orphaned or not correctly plugged (Kharaka et al., 1995; Veil et al., 2004). Impacts and ground-surface disturbances, in the order of several acres per well, can also arise from related activities such as site clearance, construction of roads, tank bat- teries, brine pits and pipelines, and other land modifications nec- essary for the drilling of exploration and production wells and construction of production facilities. The cumulative impacts from these operations are high, because a total of about 3.5 million oil. 

A comparative study of the elemental composition of the exhaust emissions of cars powered by liquefied petroleum gas and unleaded petrol

NASA Astrophysics Data System (ADS)

Lim, McKenzie C. H.; Ayoko, Godwin A.; Morawska, Lidia; Ristovski, Zoran D.; Jayaratne, E. Rohan; Kokot, Serge

Elements emitted from the exhausts of new Ford Falcon Forte cars powered by unleaded petrol (ULP) and liquefied petroleum gas (LPG) were measured on a chassis dynamometer. The measurements were carried out in February, June and August 2001, and at two steady state driving conditions (60 and 80 km h -1). Thirty seven elements were quantified in the exhaust samples by inductively coupled plasma mass spectrometry (ICPMS). The total emission factors of the elements from the exhausts of ULP cars were higher than those of LPG cars at both engine speeds even though high variability in the exhaust emissions from different cars was noted. The effect of the operating conditions such as mileage of the cars, engine speed, fuel and lubricating oil compositions on the emissions was studied. To investigate the effects of these conditions, multivariate data analysis methods were employed including exploratory principal component analysis (PCA), and the multi-criteria decision making methods (MCDM), preference ranking organization method for enrichment evaluation (PROMETHEE) and geometrical analysis for interactive aid (GAIA), for ranking the cars on the basis of the emission factors of the elements. PCA biplot of the complete data matrix showed a clear discrimination of the February, June and August emission test results. In addition, (i) platinum group elements (PGE) emissions were separated from each other in the three different clusters viz. Pt with February, Pd with June and Rh with August; (ii) the motor oil related elements, Zn and P, were particularly associated with the June and August tests (these vectors were also grouped with V, Al and Cu); and (iii) highest emissions of most major elements were associated with the August test after the cars have recorded their highest mileage. Extensive analysis with the aid of the MCDM ranking methods demonstrated clearly that cars powered by LPG outperform those powered by ULP. In general, cars tested in June perform better than those tested in August, which suggested that mileage was the key criterion of car performance on the basis of elemental emission factors.

Revisions to the original extent of the Devonian Shale-Middle and Upper Paleozoic Total Petroleum System

USGS Publications Warehouse

Enomoto, Catherine B.; Rouse, William A.; Trippi, Michael H.; Higley, Debra K.

2016-04-11

Technically recoverable undiscovered hydrocarbon resources in continuous accumulations are present in Upper Devonian and Lower Mississippian strata in the Appalachian Basin Petroleum Province. The province includes parts of New York, Pennsylvania, Ohio, Maryland, West Virginia, Virginia, Kentucky, Tennessee, Georgia, and Alabama. The Upper Devonian and Lower Mississippian strata are part of the previously defined Devonian Shale-Middle and Upper Paleozoic Total Petroleum System (TPS) that extends from New York to Tennessee. This publication presents a revision to the extent of the Devonian Shale-Middle and Upper Paleozoic TPS. The most significant modification to the maximum extent of the Devonian Shale-Middle and Upper Paleozoic TPS is to the south and southwest, adding areas in Tennessee, Georgia, Alabama, and Mississippi where Devonian strata, including potential petroleum source rocks, are present in the subsurface up to the outcrop. The Middle to Upper Devonian Chattanooga Shale extends from southeastern Kentucky to Alabama and eastern Mississippi. Production from Devonian shale has been established in the Appalachian fold and thrust belt of northeastern Alabama. Exploratory drilling has encountered Middle to Upper Devonian strata containing organic-rich shale in west-central Alabama. The areas added to the TPS are located in the Valley and Ridge, Interior Low Plateaus, and Appalachian Plateaus physiographic provinces, including the portion of the Appalachian fold and thrust belt buried beneath Cretaceous and younger sediments that were deposited on the U.S. Gulf Coastal Plain.

Prevention of renal dysfunction by nutraceuticals prepared from oil rich plant foods

PubMed Central

Al-Okbi, Sahar Y.; Mohamed, Doha A.; Hamed, Thanaa E.; Esmail, Reham SH.; Donya, Souria M.

2014-01-01

Objective To investigate the protective effect of extracts prepared from avocado, walnut, flaxseed and Eruca sativa seeds in a rat model of kidney dysfunction induced by intraperitoneal cisplatin. Methods Ethanol and petroleum ether extracts mixture was prepared from each plant. Six groups of rats were conducted; control healthy, cisplatin group and four test groups where rats were given daily oral dose of each extract mixture before cisplatin injection. Different biochemical and cytogenetic parameters and kidney histopathology were determined. Acute toxicity was tested for the nutraceuticals. Total phenolic contents, fatty acids (FA) and unsaponifiable matter were assessed in the extracts. Results Walnut ethanol extract showed the highest content of total phenolic. FA analysis revealed that all the studied plants were rich in unsaturated FA. Gas-liquid chromatographic investigation of the unsaponifiable matter showed the presence of campesterol, stigmasterol and β-sitosterol in all the studied plants. Cisplatin treatment induced significant increase in plasma urea, creatinine and malondialdehyde along with significant reduction of plasma albumin, total protein, catalase and total antioxidant as well as reduction in creatinine clearance. Histopathological examination proved the induction of kidney dysfunction. Some sorts of chromosomal aberration and sperm-shape abnormalities were noticed after cisplatin treatment. Administration of extracts mixtures produced improvements in biochemical, histopathological and cytogenetic parameters. Conclusions Administration of the studied nutraceuticals proved to possess protective role against cisplatin-induced nephrotoxicity, chromosomal aberration and abnormal sperms. All studied nutraceuticals showed complete safety. PMID:25183331

United Kingdom Country Analysis Brief

EIA Publications

2016-01-01

The United Kingdom (UK) is the fifth-largest economy in the world in terms of gross domestic product. Following years as a net exporter of crude oil and natural gas, the UK became a net importer of both fuels in 2004 and 2005, respectively. Production from UK oil and natural gas fields peaked in the late 1990s and has generally declined over the past several years as the discovery of new reserves and new production has not kept pace with the maturation of existing fields. Production of petroleum and other liquids increased in 2015, as investments made when oil prices were high came to fruition, but the UK remains a net importer. Renewable energy use, particularly in the electric power sector, has more than doubled over the past decade (2005-14). However, petroleum and natural gas continue to account for most of UK's energy consumption. In 2014, petroleum and natural gas accounted for 36% and 33%, respectively, of total energy consumption (Figure 2).1 Coal also continues to be a significant part of total energy consumption (16% in 2014). Energy use per unit of gross domestic product (GDP) in the UK is one of the lowest among western economies. The UK has seen total primary energy consumption decline by almost 20% over the past decade (2005-14). This decline resulted from smaller contribution of energy-intensive industry to the economy, economic contraction, and improvements in energy efficiency.

Alternative designs for petroleum product storage tanks for groundwater protection.

PubMed

Oke Adeleke, Samson

In developing countries, there are numerous occurrences of petroleum product spillage in groundwater. The current practice of burying storage tanks beneath the surface without adequate safety devices facilitates this phenomenon. Underground tanks rust and leak, and spilled petroleum products migrate downward. The movement of the oil in the soil depends on its viscosity and quantity, the permeability of the soil/rock, and the presence of fractures within the rock. The oil spreads laterally in the form of a thin pancake due to its lower specific gravity, and soluble components dissolve in water. The pollution plume of petroleum products and dissolved phases moves in the direction of groundwater flow in the aquifer within the pores of soil and sediments or along fractures in basement complex areas. Most communities reply heavily on groundwater for potable and industrial supplies. However, the sustainability of this resource is under threat in areas where there are filling stations as a result of significant groundwater contamination from petroleum product spillage. Drinking water becomes unpalatable when it contains petroleum products in low concentrations, and small quantities may contaminate large volumes of water. Considering the losses incurred from spillage, the cost of cleaning the aquifer, and the fact that total cleansing and attenuation is impossible, the need to prevent spillage and if it happens to prevent it from getting into the groundwater system is of paramount importance. This paper proposes alternative design procedures with a view to achieving these objectives.

Rapid identification of oil-contaminated soils using visible near-infrared diffuse reflectance spectroscopy.

PubMed

Chakraborty, Somsubhra; Weindorf, David C; Morgan, Cristine L S; Ge, Yufeng; Galbraith, John M; Li, Bin; Kahlon, Charanjit S

2010-01-01

In the United States, petroleum extraction, refinement, and transportation present countless opportunities for spillage mishaps. A method for rapid field appraisal and mapping of petroleum hydrocarbon-contaminated soils for environmental cleanup purposes would be useful. Visible near-infrared (VisNIR, 350-2500 nm) diffuse reflectance spectroscopy (DRS) is a rapid, nondestructive, proximal-sensing technique that has proven adept at quantifying soil properties in situ. The objective of this study was to determine the prediction accuracy of VisNIR DRS in quantifying petroleum hydrocarbons in contaminated soils. Forty-six soil samples (including both contaminated and reference samples) were collected from six different parishes in Louisiana. Each soil sample was scanned using VisNIR DRS at three combinations of moisture content and pretreatment: (i) field-moist intact aggregates, (ii) air-dried intact aggregates, (iii) and air-dried ground soil (sieved through a 2-mm sieve). The VisNIR spectra of soil samples were used to predict total petroleum hydrocarbon (TPH) content in the soil using partial least squares (PLS) regression and boosted regression tree (BRT) models. Each model was validated with 30% of the samples that were randomly selected and not used in the calibration model. The field-moist intact scan proved best for predicting TPH content with a validation r2 of 0.64 and relative percent difference (RPD) of 1.70. Because VisNIR DRS was promising for rapidly predicting soil petroleum hydrocarbon content, future research is warranted to evaluate the methodology for identifying petroleum contaminated soils.

Petroleum reserves and undiscovered resources in the total petroleum systems of Iraq: Reserve growth and production implications

USGS Publications Warehouse

Verma, M.K.; Ahlbrandt, T.S.; Al-Gailani, M.

2004-01-01

Iraq is one of the world's most petroleum-rich countries and, in the future, it could become one of the main producers. Iraq's petroleum resources are estimated to be 184 billion barrels, which include oil and natural gas reserves, and undiscovered resources. With its proved (or remaining) reserves of 113 billion barrels of oil (BBO) as of January 2003, Iraq ranks second to Saudi Arabia with 259 BBO in the Middle East. Iraq's proved reserves of 110 trillion cubic feet of gas (TCFG) rank tenth in the world. In addition to known reserves, the combined undiscovered hydrocarbon potential for the three Total Petroleum Systems (Paleozoic, Jurassic, and Cretaceous/Tertiary) in Iraq is estimated to range from 14 to 84 BBO (45 BBO at the mean), and 37 to 227 TCFG (120 TCFG at the mean). Additionally, of the 526 known prospective structures, some 370 remain undrilled. Petroleum migration models and associated geological and geochemical studies were used to constrain the undiscovered resource estimates of Iraq. Based on a criterion of recoverable reserves of between 1 and 5 BBO for a giant field, and more than 5 BBO for a super-giant, Iraq has 6 super-giant and 11 giant fields, accounting for 88% of its recoverable reserves, which include proved reserves and cumulative production. Of the 28 producing fields, 22 have recovery factors that range from 15 to 42% with an overall average of less than 30%. The recovery factor can be increased with water injection, improved and enhanced oil recovery methods (IOR and EOR) in various reservoirs, thus potentially increasing Iraq's reserves by an additional 50 to 70 BBO. Reserve growth is a significant factor that has been observed, to some extent, in nearly all Iraqi oil fields. Historically, producing fields have shown an average growth of 1.6 fold (or 60%) in their recoverable reserves over a 20-year period (1981-2001). With periodic assessments of reservoirs, application of available technology, and an upgrading of facilities, increases in reserves are expected in the future.

Identification of refined petroleum products in contaminated soils using an identification index for GC chromatograms.

PubMed

Kwon, Dongwook; Ko, Myoung-Soo; Yang, Jung-Seok; Kwon, Man Jae; Lee, Seung-Woo; Lee, Seunghak

2015-08-01

Hydrocarbons found in the environment are typically characterized by gas chromatography (GC). The shape of the GC chromatogram has been used to identify the source of petroleum contamination. However, the conventional practice of simply comparing the peak patterns of source products to those of environmental samples is dependent on the subjective decisions of individual analysts. We have developed and verified a quantitative analytical method for interpreting GC chromatograms to distinguish refined petroleum products in contaminated soils. We found that chromatograms for gasoline, kerosene, and diesel could be divided into three ranges with boundaries at C6, C8, C16, and C26. In addition, the relative peak area (RPA(GC)) of each range, a dimensionless ratio of the peak area within each range to that of the total range (C6-C26), had a unique value for each petroleum product. An identification index for GC chromatograms (ID(GC)), defined as the ratio of RPA(GC) of C8-C16 to that of C16-C26, was able to identify diesel and kerosene sources in samples extracted from artificially contaminated soils even after weathering. Thus, the ID(GC) can be used to effectively distinguish between refined petroleum products in contaminated soils.

Sedimentary organic biomarkers suggest detrimental effects of PAHs on estuarine microbial biomass during the 20th century in San Francisco Bay, CA, USA

USGS Publications Warehouse

Nilsen, Elena B.; Rosenbauer, Robert J.; Fuller, Christopher C.; Jaffe, Bruce E.

2014-01-01

Hydrocarbon contaminants are ubiquitous in urban aquatic ecosystems, and the ability of some microbial strains to degrade certain polycyclic aromatic hydrocarbons (PAHs) is well established. However, detrimental effects of petroleum hydrocarbon contamination on nondegrader microbial populations and photosynthetic organisms have not often been considered. In the current study, fatty acid methyl ester (FAME) biomarkers in the sediment record were used to assess historical impacts of petroleum contamination on microbial and/or algal biomass in South San Francisco Bay, CA, USA. Profiles of saturated, branched, and monounsaturated fatty acids had similar concentrations and patterns downcore. Total PAHs in a sediment core were on average greater than 20× higher above ∼200 cm than below, which corresponds roughly to the year 1900. Isomer ratios were consistent with a predominant petroleum combustion source for PAHs. Several individual PAHs exceeded sediment quality screening values. Negative correlations between petroleum contaminants and microbial and algal biomarkers – along with high trans/cis ratios of unsaturated FA, and principle component analysis of the PAH and fatty acid records – suggest a negative impacts of petroleum contamination, appearing early in the 20th century, on microbial and/or algal ecology at the site.

Impact of refined petroleum spills on water quality, macro-invertebrate and microbial communities of a tropical aquatic environment.

PubMed

Chukwu, L O; Nwachukwu, S C U

2005-07-01

Water quality characteristics, benthic macro-invertebrates and microbial communities of three first order streams in South West Nigeria were investigated to assess the effects of refined petroleum five months after spillage. All physical and chemical conditions except temperature and pH were significantly different (P<0.01) at the upstream control stations and impacted stations reflecting the perturbational stress. The benthic macro-invertebrate fauna were dominated by arthropods, but the faunal spectrum was dissimilar at all the stations studied. Sampling stations at the epicentre of the spill showed considerable reduction in faunal compositions and relative abundance. Generally, the microbial density and diversity were highest in both soil and water samples from impacted sites than in control sites. There was a significantly higher proportion (P < 0.05) of hydrocarbon utilizers in soil than in water samples in all stations except in samples from stations (P<0.05).

Liberian energy consumption and sectoral distribution for 1981

DOE Office of Scientific and Technical Information (OSTI.GOV)

Samuels, G.

1985-02-01

This report is one of a series of project papers providing background information for an assessment of energy options for Liberia, West Africa; it summarizes 1981 Liberian energy consumption data collected during 1982. Total Liberian primary energy consumption in 1981 was equivalent to 11,400,000 barrels of crude oil (BCOE) - 64% from wood, 31% from petroleum, and 5% from hydro. About 71% (8,100,000 BCOE) entered the domestic market. The difference represents exports (400,000 BCOE), refining losses (200,000 BCOE), and losses in converting wood to charcoal (2,600,000 BCOE). Of the 8,100,000 BCOE entering the domestic market, 58% was in the formmore » of wood and charcoal, 35% petroleum products, and 7% hydro. Excluding wood and charcoal, electricity generation consumed 59% of the energy entering the domestic market. The three iron ore mining companies accounted for 60% of all electricity production; the Liberia Electricity Corporation for 35%, and private organizations and individuals for 5%. The mining operations (including electricity generation and transportation uses) consumed about 60% of all petroleum products. The transportation sector consumed 30% of all petroleum of which 85% was for road transport, 12% for the railroads owned and operated by the mining companies, and 3% for sea and air transport. Nontransportation energy use in the industrial, commercial, government, and agriculture and forestry sectors is small. Together, these sectors account for less than 10% of the petroleum products consumed. Wood and charcoal were used almost entirely by the residential sector, which also consumed an additional 530,000 BCOE of other fuels. Over 90% of the 530,000 BCOE was for electricity and 290,000 (56%) was from petroleum. Over half of the petroleum (150,000 BCOE) was for generation at the mines for their associated communities. 8 references, 10 tables.« less

Mutations That Alter the Bacterial Cell Envelope Increase Lipid Production.

PubMed

Lemmer, Kimberly C; Zhang, Weiping; Langer, Samantha J; Dohnalkova, Alice C; Hu, Dehong; Lemke, Rachelle A; Piotrowski, Jeff S; Orr, Galya; Noguera, Daniel R; Donohue, Timothy J

2017-05-23

Lipids from microbes offer a promising source of renewable alternatives to petroleum-derived compounds. In particular, oleaginous microbes are of interest because they accumulate a large fraction of their biomass as lipids. In this study, we analyzed genetic changes that alter lipid accumulation in Rhodobacter sphaeroides By screening an R. sphaeroides Tn 5 mutant library for insertions that increased fatty acid content, we identified 10 high-lipid (HL) mutants for further characterization. These HL mutants exhibited increased sensitivity to drugs that target the bacterial cell envelope and changes in shape, and some had the ability to secrete lipids, with two HL mutants accumulating ~60% of their total lipids extracellularly. When one of the highest-lipid-secreting strains was grown in a fed-batch bioreactor, its lipid content was comparable to that of oleaginous microbes, with the majority of the lipids secreted into the medium. Based on the properties of these HL mutants, we conclude that alterations of the cell envelope are a previously unreported approach to increase microbial lipid production. We also propose that this approach may be combined with knowledge about biosynthetic pathways, in this or other microbes, to increase production of lipids and other chemicals. IMPORTANCE This paper reports on experiments to understand how to increase microbial lipid production. Microbial lipids are often cited as one renewable replacement for petroleum-based fuels and chemicals, but strategies to increase the yield of these compounds are needed to achieve this goal. While lipid biosynthesis is often well understood, increasing yields of these compounds to industrially relevant levels is a challenge, especially since genetic, synthetic biology, or engineering approaches are not feasible in many microbes. We show that altering the bacterial cell envelope can be used to increase microbial lipid production. We also find that the utility of some of these alterations can be enhanced by growing cells in bioreactor configurations that can be used industrially. We propose that our findings can inform current and future efforts to increase production of microbial lipids, other fuels, or chemicals that are currently derived from petroleum. Copyright © 2017 Lemmer et al.

Growth of four tropical tree species in petroleum-contaminated soil and effects of crude oil contamination.

PubMed

Pérez-Hernández, I; Ochoa-Gaona, S; Adams, R H; Rivera-Cruz, M C; Pérez-Hernández, V; Jarquín-Sánchez, A; Geissen, V; Martínez-Zurimendi, P

2017-01-01

Under greenhouse conditions, we evaluated establishment of four tree species and their capacity to degrade crude oil recently incorporated into the soil; the species were as follows: Cedrela odorata (tropical cedar), Haematoxylum campechianum (tinto bush), Swietenia macrophylla (mahogany), and Tabebuia rosea (macuilis). Three-month-old plants were planted in soil with three treatments of heavy petroleum and a control (C0 0 mg kg -1 ; C1 18,000 mg kg -1 ; C2 31,700 mg kg -1 ; C3 47,100 mg kg -1 ) with four repetitions per treatment and species; the experiment was carried out for 245 days. Height and biomass of all species significantly diminished as petroleum concentration increased, although plant survival was not affected. The quantity of colony-forming units (CFU) of rhizospheric bacteria varied among tree species and treatments; petroleum stimulated bacterial CFU for S. macrophylla. The number of fungi CFU for S. macrophylla and T. rosea was significantly greater in C0 than in soil with petroleum, but among species and among different concentrations, no significant differences were found. The greatest percentage of total petroleum hydrocarbon (TPH) degradation was found in C1 for soil without plants (45 %). Differences from the remaining treatments (petroleum concentrations in soil and plant species) were not significant (P < 0.05). Among all trees, H. campechianum had the greatest TPH degradation (32.5 % in C2). T. rosea (C1) and H. campechianum (C2) resulted in petroleum degradation at levels ranging from 20.5 to 32.5 %. On the basis of this experiment, the tree species used did not improve TPH degradation. However, all of them showed high rates of survival and vigor. So, as tree species provide goods and services, experiments with inoculation of hydrocarbonclastic microorganisms, addition of fertilizers, and mixture of tree and grasses are recommended.

Petroleum potential of wilderness lands in the Western United States

USGS Publications Warehouse

Miller, Betty M.

1983-01-01

In 1982-83, the U.S. Geological Survey (USGS) conducted an investigation of the oil and gas potential of the designated and proposed Wilderness Lands in the Western United States. The scope of this study was limited to the assessment of conventional recoverable petroleum resources occurring in the designated and proposed Wilderness Lands of the Western United States that are administered under four Federal agencies: Bureau of Land Management (BLM), U.S. Forest Service (USFS), National Park Service (NPS), and Fish and Wildlife Service (FWS). The total area of the study included approximately 74 million acres of Wilderness Lands in these 11 Western States: Arizona, California, Colorado, Idaho, Montana, Nevada, New Mexico, Oregon, Utah, Washington, and Wyoming. The 74 million acres represent 31 percent of the total Federal lands within these 11 Western States. Approximately 49 percent of all the lands in these States are federally owned. The objective of this study was to assemble through various means all the available pertinent information that could be brought together within the USGS and integrate these data into a computer-based digital cartographic data system that was focused upon the single issue of reviewing the known geological and geophysical data to determine the geologic characteristics favorable or unfavorable for the occurrence of petroleum resources in these Wilderness Lands. In a joint effort in the USGS between the Geologic Division (GD) and the National Mapping Division (NMD) all of the mappable information used in this study was prepared and processed by using digital cartographic techniques. These include digitizing the location and boundaries of the Wilderness Lands; acreage calculations; the boundaries of the USGS petroleum provinces; and the geologic and tectonic boundaries within each petroleum province and State. In addition, searches were conducted on well data files which provided the locations and geologic information on over 5,000 wells drilled within or immediately adjacent to the Wilderness Lands. An analysis of all the geologic characteristics favorable or unfavorable for petroleum occurrence in conjunction with the geologic settings for the Wilderness Lands scattered within the framework of the petroleum provinces was performed by a team of geologists on each of the wilderness tracts. The geologic characteristics reviewed for each tract included the presence or absence of the following: adequate source beds and reservoir rocks; adequate trapping mechanisms; favorable thermal and maturation histories; presence of petroleum seeps or adjacent wells with shows or production; and the presence of favorable sedimentary rock sections underlying volcanic terrane or faulted and overthrust areas. A description of the geology and geologic framework is provided for each State along with an explanation of the interpretative geology and evaluation of the petroleum potential within the locale of each of the wilderness tracts. The assessment of the petroleum resources on the Wilderness Lands was completed in two separate stages. In the first stage the geologists evaluated the geological characteristics for the favorability or lack of favorability for the occurrence of oil and natural gas within each wilderness tract and assigned a qualitative rating for each tract's potential for the occurrence of recoverable oil and gas resources. In the second stage in evaluating the petroleum potential for the wilderness tracts, an effort was made to arrive at a quantitative assessment within the framework of the USGS's latest published resource estimates which are made on a province basis. The geologic characteristics evaluated for the favorability of petroleum occurrence within each of the clusters of wilderness tracts were the determining factors for the subjective assessments of the petroleum potential for each wilderness tract occurring within the respective basin or province. The quantitative resource

Appalachian basin oil and natural gas: stratigraphic framework, total petroleum systems, and estimated ultimate recovery: Chapter C.1 in Coal and petroleum resources in the Appalachian basin: distribution, geologic framework, and geochemical character

USGS Publications Warehouse

Ryder, Robert T.; Milici, Robert C.; Swezey, Christopher S.; Trippi, Michael H.; Ruppert, Leslie F.; Ryder, Robert T.

2014-01-01

The most recent U.S. Geological Survey (USGS) assessment of undiscovered oil and gas resources of the Appalachian basin was completed in 2002 (Milici and others, 2003). This assessment was based on the total petroleum system (TPS), a concept introduced by Magoon and Dow (1994) and developed during subsequent studies such as those by the U.S. Geological Survey World Energy Assessment Team (2000) and by Biteau and others (2003a,b). Each TPS is based on specific geologic elements that include source rocks, traps and seals, reservoir rocks, and the generation and migration of hydrocarbons. This chapter identifies the TPSs defined in the 2002 Appalachian basin oil and gas assessment and places them in the context of the stratigraphic framework associated with regional geologic cross sections D–D′ (Ryder and others, 2009, which was re-released in this volume, chap. E.4.1) and E–E′ (Ryder and others, 2008, which was re-released in this volume, chap. E.4.2). Furthermore, the chapter presents a recent estimate of the ultimate recoverable oil and natural gas in the basin.

Assessment of Undiscovered Technically Recoverable Oil and Gas Resources of the Bakken Formation, Williston Basin, Montana and North Dakota, 2008

USGS Publications Warehouse

Pollastro, R.M.; Roberts, L.N.R.; Cook, T.A.; Lewan, M.D.

2008-01-01

The U.S. Geological Survey (USGS) has completed an assessment of the undiscovered oil and associated gas resources of the Upper Devonian to Lower Mississippian Bakken Formation in the U.S. portion of the Williston Basin of Montana and North Dakota and within the Williston Basin Province. The assessment is based on geologic elements of a total petroleum system (TPS), which include (1) source-rock distribution, thickness, organic richness, maturation, petroleum generation, and migration; (2) reservoir-rock type (conventional or continuous), distribution, and quality; and (3) character of traps and time of formation with respect to petroleum generation and migration. Framework studies in stratigraphy and structural geology and modeling of petroleum geochemistry, combined with historical exploration and production analyses, were used to estimate the undiscovered, technically recoverable oil resource of the Bakken Formation. Using this framework, the USGS defined a Bakken-Lodgepole TPS and seven assessment units (AU) within the system. For the Bakken Formation, the undiscovered oil and associated gas resources were quantitatively estimated for six of these AUs.

Non-targeted analysis of petroleum metabolites in groundwater using GC×GC-TOFMS.

PubMed

Mohler, Rachel E; O'Reilly, Kirk T; Zemo, Dawn A; Tiwary, Asheesh K; Magaw, Renae I; Synowiec, Karen A

2013-09-17

Groundwater at fuel release sites often contains nonpolar hydrocarbons that originate from both the fuel release and other environmental sources, as well as polar metabolites of petroleum biodegradation. These compounds, along with other polar artifacts, can be quantified as "total petroleum hydrocarbons" using USEPA Methods 3510/8015B, unless a silica gel cleanup step is used to separate nonpolar hydrocarbons from polar compounds prior to analysis. Only a limited number of these metabolites have been identified by traditional GC-MS methods, because they are difficult to resolve using single-column configurations. Additionally, the targeted use of derivatization limits the detection of many potential metabolites of interest. The objective of this research was to develop a nontargeted GC×GC-TOFMS approach to characterize petroleum metabolites in environmental samples gathered from fuel release sites. The method tentatively identified more than 760 unique polar compounds, including acids/esters, alcohols, phenols, ketones, and aldehydes, from 22 groundwater samples collected at five sites. Standards for 28 polar compounds indicate that effective limits of quantitation for most of these compounds in the groundwater samples range from 1 to 11 μg/L.

A field trial for an ex-situ bioremediation of a drilling mud-polluted site.

PubMed

Rojas-Avelizapa, N G; Roldán-Carrillo, T; Zegarra-Martínez, H; Muñoz-Colunga, A M; Fernández-Linares, L C

2007-01-01

The remediation of drilling mud-polluted sites in the Southeast of Mexico is a top priority for Mexican oil industry. The objective of this work was to find a technology to remediate these sites. A field trial was performed by composting in biopiles, where four 1ton soil-biopiles were established, one treatment in triplicate and one unamended biopile. Amended biopiles were added with nutrients to get a C/N/P ratio of 100/3/0.5 plus a bulking agent (straw) at a soil/straw ratio of 97/3. Moisture content was maintained around 30-35%. Results showed that, after 180 d, total petroleum hydrocarbon (TPH) concentrations decreased from 99300+/-23000mgTPHkg(-1) soil to 5500+/-770mgTPHkg(-1) for amended biopiles and to 22900+/-7800mgTPHkg(-1) for unamended biopile. An undisturbed soil control showed no change in TPH concentrations. Gas chromatographic analysis showed residual alkyl dibenzothiophene type compounds. Highest bacterial counts were observed during the first 30 d which correlated with highest TPH removal, whereas fungal count increased at the end of the experimentation period. Results suggested an important role of the straw, nutrient addition and water content in stimulating aerobic microbial activity and thus hydrocarbon removal. This finding opens an opportunity to remediate old polluted sites with recalcitrant and high TPH concentration.

North Slope, Alaska: Source rock distribution, richness, thermal maturity, and petroleum charge

USGS Publications Warehouse

Peters, K.E.; Magoon, L.B.; Bird, K.J.; Valin, Z.C.; Keller, M.A.

2006-01-01

Four key marine petroleum source rock units were identified, characterized, and mapped in the subsurface to better understand the origin and distribution of petroleum on the North Slope of Alaska. These marine source rocks, from oldest to youngest, include four intervals: (1) Middle-Upper Triassic Shublik Formation, (2) basal condensed section in the Jurassic-Lower Cretaceous Kingak Shale, (3) Cretaceous pebble shale unit, and (4) Cretaceous Hue Shale. Well logs for more than 60 wells and total organic carbon (TOC) and Rock-Eval pyrolysis analyses for 1183 samples in 125 well penetrations of the source rocks were used to map the present-day thickness of each source rock and the quantity (TOC), quality (hydrogen index), and thermal maturity (Tmax) of the organic matter. Based on assumptions related to carbon mass balance and regional distributions of TOC, the present-day source rock quantity and quality maps were used to determine the extent of fractional conversion of the kerogen to petroleum and to map the original TOC (TOCo) and the original hydrogen index (HIo) prior to thermal maturation. The quantity and quality of oil-prone organic matter in Shublik Formation source rock generally exceeded that of the other units prior to thermal maturation (commonly TOCo > 4 wt.% and HIo > 600 mg hydrocarbon/g TOC), although all are likely sources for at least some petroleum on the North Slope. We used Rock-Eval and hydrous pyrolysis methods to calculate expulsion factors and petroleum charge for each of the four source rocks in the study area. Without attempting to identify the correct methods, we conclude that calculations based on Rock-Eval pyrolysis overestimate expulsion factors and petroleum charge because low pressure and rapid removal of thermally cracked products by the carrier gas retards cross-linking and pyrobitumen formation that is otherwise favored by natural burial maturation. Expulsion factors and petroleum charge based on hydrous pyrolysis may also be high compared to nature for a similar reason. Copyright ?? 2006. The American Association of Petroleum Geologists. All rights reserved.

Characterization of Athabasca lean oil sands and mixed surficial materials: Comparison of capillary electrophoresis/low-resolution mass spectrometry and high-resolution mass spectrometry.

PubMed

MacLennan, Matthew S; Peru, Kerry M; Swyngedouw, Chris; Fleming, Ian; Chen, David D Y; Headley, John V

2018-05-15

Oil sands mining in Alberta, Canada, requires removal and stockpiling of considerable volumes of near-surface overburden material. This overburden includes lean oil sands (LOS) which cannot be processed economically but contain sparingly soluble petroleum hydrocarbons and naphthenic acids, which can leach into environmental waters. In order to measure and track the leaching of dissolved constituents and distinguish industrially derived organics from naturally occurring organics in local waters, practical methods were developed for characterizing multiple sources of contaminated water leakage. Capillary electrophoresis/positive-ion electrospray ionization low-resolution time-of-flight mass spectrometry (CE/LRMS), high-resolution negative-ion electrospray ionization Orbitrap mass spectrometry (HRMS) and conventional gas chromatography/flame ionization detection (GC/FID) were used to characterize porewater samples collected from within Athabasca LOS and mixed surficial materials. GC/FID was used to measure total petroleum hydrocarbon and HRMS was used to measure total naphthenic acid fraction components (NAFCs). HRMS and CE/LRMS were used to characterize samples according to source. The amounts of total petroleum hydrocarbon in each sample as measured by GC/FID ranged from 0.1 to 15.1 mg/L while the amounts of NAFCs as measured by HRMS ranged from 5.3 to 82.3 mg/L. Factors analysis (FA) on HRMS data visually demonstrated clustering according to sample source and was correlated to molecular formula. LRMS coupled to capillary electrophoresis separation (CE/LRMS) provides important information on NAFC isomers by adding analyte migration time data to m/z and peak intensity. Differences in measured amounts of total petroleum hydrocarbons by GC/FID and NAFCs by HRMS indicate that the two methods provide complementary information about the nature of dissolved organic species in a soil or water leachate samples. NAFC molecule class O x S y is a possible tracer for LOS seepage. CE/LRMS provides complementary information and is a feasible and practical option for source evaluation of NAFCs in water. Copyright © 2018 John Wiley & Sons, Ltd.

77 FR 959 - National Emission Standards for Hazardous Air Pollutants From Petroleum Refineries; National...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-01-06

... million by volume (ppmv) total strippable hydrocarbons (as methane) in the stripping gas collected via the... methane) collected via the Modified El Paso Method. We are also proposing to include alternative leak.... The delay of repair action level would be either 62 ppmv total strippable hydrocarbons (as methane...

Ocean Pollution as a Result of Onshore Offshore Petroleum Activities in the African Gulf of Guinea Region

NASA Astrophysics Data System (ADS)

Abubakar, B.

2007-05-01

The Gulf of Guinea region is located on the Atlantic side of Africa; the sub region has a total population of approximately 190million people. It comprises of five different countries and their territorial waters, which are as follows: Nigeria, Sao Tome & Principe, Equatorial Guinea, Gabon and Cameroon. The sub region is blessed with so many types of natural resources ranging from petroleum, Natural gas, Bitumen, Uranium Diamond and Gold to mention but a few. However the region since the last two decades started attracting the World's attention as a result of the continuous increasing discoveries of new oil fields on both its on shores and off shores. In view of this extra ordinary increasing discoveries of new oil fields in the region, the Gulf of Guinea has become a "Gold rush" to the oil companies and it has so far attracted almost all the top oil firms in the world including; Exxon Mobil, Shell, Total, Texaco, Agip, Chevron, Slumberger, Stat Oil and Conoco Phillips among many other oil giants. In the more recent time even the U.S. Marine Corp have stationed their War Ship in the territorial waters of the Gulf in the name of providing protection to the "Liquid Gold" (Petroleum) underlying the beneath of the region. OIL ACTIVITIES AND ITS ASSOCIATED PROBLEMS IN THE GULF OF GUINEA As a result of the geometrically increasing oil activities in the region ranging from Drilling, Gas flaring, Bunkering and Exploration activities, there was increase in the general pollution of the region. For example recent reports released in June, 2005 by the internationally renown nongovernmental organization on environmental pollution the Netherlands based Climate Justice programme and the Nigeria's Environmental Rights Action, Under the aegis of friends of the Earth, had it that the region is ranked top on the world's total flare with Nigeria along accounting for 16 percent of the world's total flare. Another example is the increasing cases of oil spillages leading to the increasing cases of pollution of farmlands, rivers, wells and the environment in general. Apart from all these, what is even becoming more worrisome is that none of all these oil firms operating in the region is able to account on how it disposes its industrial toxic waste generated as a result of its industrial activities within the region. Finally Geological strata are adversely destroyed by seismographic activities, Sea creatures are destroyed by oil pollution and Means of livelihood of revering dwellers are often threatened by pollution. RECOMMENDATIONS After identifying how the pollution in the Gulf of Guinea region is increasing in relation to the increasing petroleum activities, I have come up with the following suggestions/recommendations. 1. AFRICAN UNION RESOLUTION The Organization of the Petroleum Exporting Countries (OPEC) in conjunction with the International Atomic Energy Agency (IAEA) should use their capacity to be able to influence the African Union (AU) to pass a resolution banning the illegal dumping of radioactive waste, Gas flaring and Costal bunkering in this part of the world. 2. RESEARCH AND INVESTIGATION The Organization of the Petroleum Exporting Countries, in conjunction with the United Nations Environmental Agency, the International Atomic Energy Agency and with the corporation of the African Union should send team of researchers to come and investigate this trend on petroleum pollution in the Gulf of Guinea region and proffer possible solutions in checking the menace.

Treatment of petroleum drill cuttings using bioaugmentation and biostimulation supplemented with phytoremediation.

PubMed

Kogbara, Reginald B; Ogar, Innocent; Okparanma, Reuben N; Ayotamuno, Josiah M

2016-07-28

This study sought to compare the effectiveness of bioaugmentation and biostimulation, as well as the combination of both techniques, supplemented with phytoremediation, in the decontamination of petroleum drill cuttings. Drill cuttings with relatively low concentration of total petroleum hydrocarbons (TPH) and metals were mixed with soil in the ratio 5:1 and treated with three different combinations of the bioremediation options. Option A entailed bioaugmentation supplemented with phytoremediation. Option B had the combination of biostimulation and bioaugmentation supplemented with phytoremediation. While biostimulation supplemented with phytoremediation was deployed in option C. Option O containing the drill cuttings-soil mixture without treatment served as untreated control. Fertilizer application, tillage and watering were used for biostimulation treatment, while spent mushroom substrate (Pleurotus ostreatus) and elephant grass (Pennisetum purpureum) were employed for bioaugmentation and phytoremediation treatment, respectively. The drill cuttings-soil mixtures were monitored for TPH, organic carbon, total nitrogen, pH, metal concentrations, and fungal counts, over time. After 56 days of treatment, there was a decline in the initial TPH concentration of 4,114 mg kg(-1) by 5.5%, 68.3%, 75.6% and 48% in options O, A, B and C, respectively. Generally, higher TPH loss resulted from the phytoremediation treatment stage. The treated options also showed slight reductions in metal concentrations ranging from 0% to 16% of the initial low concentrations. The results highlight the effectiveness of bioaugmentation supplemented with phytoremediation. The combination of bioaugmentation and biostimulation supplemented with phytoremediation, however, may prove better in decontaminating petroleum drill cuttings to environmentally benign levels.

Bacterial Community Response to Petroleum Hydrocarbon Amendments in Freshwater, Marine, and Hypersaline Water-Containing Microcosms

PubMed Central

Jurelevicius, Diogo; Alvarez, Vanessa Marques; Marques, Joana Montezano; de Sousa Lima, Laryssa Ribeiro Fonseca; Dias, Felipe de Almeida

2013-01-01

Hydrocarbon-degrading bacterial communities from freshwater, marine, and hypersaline Brazilian aquatic ecosystems (with water salinities corresponding to 0.2%, 4%, and 5%, respectively) were enriched with different hydrocarbons (heptadecane, naphthalene, or crude oil). Changes within the different microcosms of bacterial communities were analyzed using cultivation approaches and molecular methods (DNA and RNA extraction, followed by genetic fingerprinting and analyses of clone libraries based on the 16S rRNA-coding gene). A redundancy analysis (RDA) of the genetic fingerprint data and a principal component analysis (PCA) of the clone libraries revealed hydrocarbon-enriched bacterial communities specific for each ecosystem studied. However, within the same ecosystem, different bacterial communities were selected according to the petroleum hydrocarbon used. In general, the results demonstrated that Acinetobacter and Cloacibacterium were the dominant genera in freshwater microcosms; the Oceanospirillales order and the Marinobacter, Pseudomonas, and Cycloclasticus genera predominated in marine microcosms; and the Oceanospirillales order and the Marinobacter genus were selected in the different hydrocarbon-containing microcosms in hypersaline water. Determination of total petroleum hydrocarbons (TPHs) in all microcosms after 32 days of incubation showed a decrease in the hydrocarbon concentration compared to that for the controls. A total of 50 (41.3%) isolates from the different hydrocarbon-contaminated microcosms were associated with the dominant operational taxonomic units (OTUs) obtained from the clone libraries, and their growth in the hydrocarbon contaminating the microcosm from which they were isolated as the sole carbon source was observed. These data provide insight into the general response of bacterial communities from freshwater, marine, and hypersaline aquatic ecosystems to petroleum hydrocarbon contamination. PMID:23872573

Naphthenic acids speciation and removal during petroleum-coke adsorption and ozonation of oil sands process-affected water.

PubMed

Gamal El-Din, Mohamed; Fu, Hongjing; Wang, Nan; Chelme-Ayala, Pamela; Pérez-Estrada, Leonidas; Drzewicz, Przemysław; Martin, Jonathan W; Zubot, Warren; Smith, Daniel W

2011-11-01

The Athabasca Oil Sands industry produces large volumes of oil sands process-affected water (OSPW) as a result of bitumen extraction and upgrading processes. Constituents of OSPW include chloride, naphthenic acids (NAs), aromatic hydrocarbons, and trace heavy metals, among other inorganic and organic compounds. To address the environmental issues associated with the recycling and/or safe return of OSPW into the environment, water treatment technologies are required. This study examined, for the first time, the impacts of pretreatment steps, including filtration and petroleum-coke adsorption, on ozonation requirements and performance. The effect of the initial OSPW pH on treatment performance, and the evolution of ozonation and its impact on OSPW toxicity and biodegradability were also examined. The degradation of more than 76% of total acid-extractable organics was achieved using a semi-batch ozonation system at a utilized ozone dose of 150 mg/L. With a utilized ozone dose of 100 mg/L, the treated OSPW became more biodegradable and showed no toxicity towards Vibrio fischeri. Changes in the NA profiles in terms of carbon number and number of rings were observed after ozonation. The filtration of the OSPW did not improve the ozonation performance. Petroleum-coke adsorption was found to be effective in reducing total acid-extractable organics by a 91%, NA content by an 84%, and OSPW toxicity from 4.3 to 1.1 toxicity units. The results of this study indicate that the combination of petroleum-coke adsorption and ozonation is a promising treatment approach to treat OSPW. Copyright © 2011 Elsevier B.V. All rights reserved.

Exposure assessment of particulates of diesel and natural gas fuelled buses in silico.

PubMed

Pietikäinen, Mari; Oravisjärvi, Kati; Rautio, Arja; Voutilainen, Arto; Ruuskanen, Juhani; Keiski, Riitta L

2009-12-15

Lung deposition estimates of particulate emissions of diesel and natural gas (CNG) fuelled vehicles were studied by using in silico methodology. Particulate emissions and particulate number size distributions of two Euro 2 petroleum based diesel buses and one Euro 3 gas bus were measured. One of the petroleum based diesel buses used in the study was equipped with an oxidation catalyst on the vehicle (DI-OC) while the second had a partial-DPF catalyst (DI-pDPF). The third bus used was the gas bus with an oxidation catalyst on the vehicle (CNG-OC). The measurements were done using a transient chassis dynamometer test cycle (Braunschweig cycle) and an Electric Low Pressure Impactor (ELPI) with formed particulates in the size range of 7 nm to 10 microm. The total amounts of the emitted diesel particulates were 88-fold for DI-OC and 57-fold for DI-pDPF compared to the total amount of emitted CNG particulates. Estimates for the deposited particulates were computed with a lung deposition model ICRP 66 using in-house MATLAB scripts. The results were given as particulate numbers and percentages deposited in five different regions of the respiratory system. The percentages of particulates deposited in the respiratory system were 56% for DI-OC, 51% for DI-pDPF and 77% for CNG-OC of all the inhaled particulates. The result shows that under similar conditions the total lung dose of particulates originating from petroleum diesel fuelled engines DI-OC and DI-pDPF was more than 60-fold and 35-fold, respectively, compared to the lung dose of particulates originating from the CNG fuelled engine. The results also indicate that a majority (35-50%) of the inhaled particulates emitted from the tested petroleum diesel and CNG engines penetrate deep into the unciliated regions of the lung where gas-exchange occurs.

Geology and total petroleum systems of the Gulf of Guinea province of West Africa

USGS Publications Warehouse

Brownfield, Michael E.; Charpentier, Ronald R.

2006-01-01

The Gulf of Guinea Province as defined by the U.S. Geological Survey (USGS) consists of the coastal and offshore areas of Cote d'Ivoire, Ghana, Togo, and Benin, and the western part of the coast of Nigeria, from the Liberian border east to the west edge of the Niger Delta. The province includes the Ivory Coast, Tano, Central, Saltpond, Keta, and Benin Basins and the Dahomey Embayment. The area has had relatively little hydrocarbon exploration since 1968, with only 33 small to moderate-sized oil and gas fields having been discovered prior to the USGS assessment. Most discoveries to 1995 have been located in water depths less than 500 m. Since 1995, only eight new offshore discoveries have been made, with four of the discoveries in the deep-water area of the province. Although as many as five total petroleum systems exist in the Gulf of Guinea Province, only one, the Cretaceous Composite Total Petroleum System, and its assessment unit, the Coastal Plain and Offshore Assessment Unit, had sufficient data to allow assessment. The province shows two important differences compared to the passive-margin basins south of the Niger Delta: (1) the influence of transform tectonics, and (2) the absence of evaporites and salt deformation. The province also lacks long-lived, large deltaic systems that typically result in rapid source rock burial and abundant high-quality hydrocarbon reservoirs. The USGS assessed the potential for undiscovered conventional oil and gas resources in the Gulf of Guinea Province as part of its World Petroleum Assessment 2000, estimating a mean of 1,004 million barrels of conventional undiscovered oil, 10,071 billion cubic feet of gas, and 282 million barrels of natural gas liquids. Most of the hydrocarbon potential is postulated to be in the offshore, deeper waters of the province. Gas resources may be large, as well as accessible, in areas where the zone of hydrocarbon generation is relatively shallow.

Petroleum contamination of soil and water, and their effects on vegetables by statistically analyzing entire data set.

PubMed

Zhang, Juan; Fan, Shu-kai; Yang, Jun-cheng; Du, Xiao-ming; Li, Fa-sheng; Hou, Hong

2014-04-01

Aliphatic hydrocarbons have been used to assess total oil concentrations, petroleum sources, and petroleum degradation. In this study, surface soil, groundwater, surface water, and vegetables were collected from the outskirts of Xi'an, the largest city in northwestern China, and the samples were analyzed for aliphatic hydrocarbon contents. The concentrations of n-alkanes were 1.06-4.01 μg/g in the soil. The concentrations and the geochemical characteristics of n-alkanes showed that the low carbon number hydrocarbons were mainly from petroleum sources, whereas the high carbon number hydrocarbons received more hydrocarbons from herbaceous plants. The concentrations of n-alkanes were 9.20-93.44 μg/L and 23.74-118.27 μg/L in the groundwater and the surface water, respectively. The water had characteristics of petroleum and submerged/floating macrophytes and was found in concentrations that would cause chronic disruption of sensitive organisms. The concentrations and geochemical characteristics of n-alkanes in Brassica chinensis L. and Apium graveolens were different, but both were contaminated by petroleum hydrocarbons. The results from principal component analysis (PCA) indicated that the sorption of n-alkanes to soil particles could not be described by linear models. The distributions of n-alkanes in vegetables were positively correlated with those in soil, and the correlation coefficient was up to 0.9310 using the constructed vectors. Therefore, the researchers should pay close attention to the effect of soil contamination on vegetables. Copyright © 2014 Elsevier B.V. All rights reserved.

The Talara Basin province of northwestern Peru: cretaceous-tertiary total petroleum system

USGS Publications Warehouse

Higley, Debra K.

2004-01-01

More than 1.68 billion barrels of oil (BBO) and 340 billion cubic feet of gas (BCFG) have been produced from the Cretaceous-Tertiary Total Petroleum System in the Talara Basin province, northwestern Peru. Oil and minor gas fields are concentrated in the onshore northern third of the province. Current production is primarily oil, but there is excellent potential for offshore gas resources, which is a mostly untapped resource because of the limited local market for gas and because there are few pipelines. Estimated mean recoverable resources from undiscovered fields in the basin are 1.71 billion barrels of oil (BBO), 4.79 trillion cubic feet of gas (TCFG), and 255 million barrels of natural gas liquids (NGL). Of this total resource, 15 percent has been allocated to onshore and 85 percent to offshore; volumes are 0.26 BBO and 0.72 TCFG onshore, and 1.45 BBO and 4.08 TCFG offshore. The mean estimate of numbers of undiscovered oil and gas fields is 83 and 27, respectively. Minimum size of fields that were used in this analysis is 1 million barrels of oil equivalent and (or) 6 BCFG. The Paleocene Talara forearc basin is superimposed on a larger, Mesozoic and pre-Mesozoic basin. Producing formations, ranging in age from Pennsylvanian to Oligocene, are mainly Upper Cretaceous through Oligocene sandstones of fluvial, deltaic, and nearshore to deep-marine depositional origins. The primary reservoirs and greatest potential for future development are Eocene sandstones that include turbidites of the Talara and Salinas Groups. Additional production and undiscovered resources exist within Upper Cretaceous, Paleocene, and Oligocene formations. Pennsylvanian Amotape quartzites may be productive where fractured. Trap types in this block-faulted basin are mainly structural or a combination of structure and stratigraphy. Primary reservoir seals are interbedded and overlying marine shales. Most fields produce from multiple reservoirs, and production is reported commingled. For this reason, and also because geochemical data on oils and source rocks is very limited, Tertiary and Cretaceous production is grouped into one total petroleum system. The most likely source rocks are Tertiary marine shales, but some of the Cretaceous marine shales are also probable source rocks, and these would represent separate total petroleum systems. Geochemical data on one oil sample from Pennsylvanian rock indicates that it was probably also sourced from Tertiary shales.

Effects of contaminated soil on the growth performance of young Salix (Salix schwerinii E. L. Wolf) and the potential for phytoremediation of heavy metals.

PubMed

Salam, Mir Md Abdus; Kaipiainen, Erik; Mohsin, Muhammad; Villa, Aki; Kuittinen, Suvi; Pulkkinen, Pertti; Pelkonen, Paavo; Mehtätalo, Lauri; Pappinen, Ari

2016-12-01

Salix schwerinii was tested in a pot experiment to assess plant growth performance i.e., relative height and dry biomass and the potential for heavy metal uptake in soils polluted with chromium, zinc, copper, nickel and total petroleum hydrocarbons. The soil used in the pot experiment was collected from a landfill area in Finland. Peat soil was added at different quantities to the polluted soil to stimulate plant growth. The plants were irrigated with tap water or processed water (municipal waste water) to further investigate the effects of nutrient loading on plant biomass growth. The soil was treated at two pH levels (4 and 6). The results showed that the addition of 40-70% peat soil at pH 6 to a polluted soil, and irrigation with processed water accelerated plant growth and phytoextraction efficiency. In the pot experiment, Salix grown in chromium, zinc, copper, nickel and total petroleum hydrocarbons -contaminated field soil for 141 days were unaffected by the contaminated soil and took up excess nutrients from the soil and water. Total mean chromium concentration in the plant organs ranged from 17.05 to 250.45 mg kg -1 , mean zinc concentration ranged from 142.32 to 1616.59 mg kg -1 , mean copper concentration ranged from 12.11 to 223.74 mg kg -1 and mean nickel concentration ranged from 10.11 to 75.90 mg kg -1 . Mean chromium concentration in the plant organs ranged from 46 to 94%, mean zinc concentration ranged from 44 to 76%, mean copper concentration ranged from 19 to 54% and mean nickel concentration ranged from 8 to 21% across all treatments. Under the different treatments, chromium was taken up by Salix in the largest quantities, followed by zinc, copper and nickel respectively. Salix also produced a moderate reduction in total petroleum total petroleum hydrocarbons in the polluted soil. The results from the pot experiment suggest that Salix schwerinii has the potential to accumulate significant amounts of chromium, zinc, copper and nickel. However, long term research is needed to verify the phytoextraction abilities of Salix observed in the pot experiment. Copyright © 2016 Elsevier Ltd. All rights reserved.

The Timan-Pechora Basin province of northwest Arctic Russia; Domanik, Paleozoic total petroleum system

USGS Publications Warehouse

Lindquist, Sandra J.

1999-01-01

The Domanik-Paleozoic oil-prone total petroleum system covers most of the Timan-Pechora Basin Province of northwestern Arctic Russia. It contains nearly 20 BBOE ultimate recoverable reserves (66% oil). West of the province is the early Precambrian Eastern European craton margin. The province itself was the site of periodic Paleozoic tectonic events, culminating with the Hercynian Uralian orogeny along its eastern border. The stratigraphic record is dominated by Paleozoic platform and shelf-edge carbonates succeeded by Upper Permian to Triassic molasse siliciclastics that are locally present in depressions. Upper Devonian (Frasnian), deep marine shale and limestone source rocks ? with typically 5 wt % total organic carbon ? by middle Mesozoic time had generated hydrocarbons that migrated into reservoirs ranging in age from Ordovician to Triassic but most focused in Devonian and Permian rocks. Carboniferous structural inversions of old aulacogen borders, and Hercynian (Permian) to Early Cimmerian (Late Triassic to Early Jurassic) orogenic compression not only impacted depositional patterns, but also created and subsequently modified numerous structural traps within the province.

Zeatin and Thidiazuron Induced Embryogenic Calli From In Vitro Leaf and Stem of Jojoba (Simmondsia chinensis).

PubMed

El-Ashry, Amal Abd El-Latif; Gabr, Ahmed Mohamed Magdy; Bekheet, Shawky Abd El-Hamid

2017-01-01

Jojoba is a promising industrial plant, which recommended with pharmaceutical benefits. The present study was conducted to stimulate embryogenic calli formation from jojoba using zeatin and thidiazuron (TDZ), as well as determination of the antioxidant activity of proliferated calli. For callus induction, leaf and stem explants derived from in vitro grown shootlets, were cultured on Murashige and Skoog (MS) medium with different combinations of 0.5 mg L-1 benzyl adenine (BA) or kinetin with 2,4-Dichlorophenoxyacetic acid (2,4-D), Naphthalene acetic acid (NAA) and picloram at 0.5 or 1mg L-1. To stimulate embryogenic calli, friable callus were transferred to woody plant medium (WPM) supplemented with different concentrations of zeatin or TDZ. Antioxidant activity of different treatments was determined using hexane or petroleum ether extraction. Data was analyzed as mean±standard deviation (SD). The MS medium supplemented with 0.5 mg L-1 BA+0.5 or 1 mg L-1 picloram was the best treatment to obtain friable calli from both explants types. WPM medium supplemented with 2 mg L-1 zeatin gave the highest percentage of embryogenic calli derived from leaf explants. While the highest percentage of embryogenic calli derived from stem explants was registered using 1 or 4 mg L-1 TDZ containing medium. Embryogenic calli originated from leaves explants on 1.5 mg L-1 zeatin showed promising activity of antioxidant with hexane extraction. However, embryogenic calli originated from stem explants on 1 mg L-1 TDZ showed the highest antioxidant activity with petroleum ether extraction. TDZ has promising effect on embryogenic callus induction from stem explants. While, zeatin has promising effect on embryogenic callus induction from leaf explants.

Occurrences and behaviors of naphthenic acids in a petroleum refinery wastewater treatment plant.

PubMed

Wang, Beili; Wan, Yi; Gao, Yingxin; Zheng, Guomao; Yang, Min; Wu, Song; Hu, Jianying

2015-05-05

Naphthenic acids (NAs) are one class of compounds in wastewaters from petroleum industries that are known to cause toxic effects, and their removal from oilfield wastewater is an important challenge for remediation of large volumes of petrochemical effluents. The present study investigated occurrences and behaviors of total NAs and aromatic NAs in a refinery wastewater treatment plant, located in north China, which combined physicochemical and biological processes. Concentrations of total NAs were semiquantified to be 113-392 μg/L in wastewater from all the treatment units, and the percentages of aromatic NAs in total NAs was estimated to be 2.1-8.8%. The mass reduction for total NAs and aromatic NAs was 15±16% and 7.5±24% after the physicochemical treatment, respectively. Great mass reduction (total NAs: 65±11%, aromatic NAs: 86±5%) was observed in the biological treatment units, and antiestrogenic activities observed in wastewater from physicochemical treatment units disappeared in the effluent of the activated sludge system. The distributions of mass fractions of NAs demonstrated that biodegradation via activated sludge was the major mechanism for removing alicyclic NAs, aromatic NAs, and related toxicities in the plant, and the polycyclic NA congener classes were relatively recalcitrant to biodegradation, which is a complete contrast to the preferential adsorption of NAs with higher cyclicity (low Z value). Removal efficiencies of total NAs were 73±17% in summer, which were higher than those in winter (53±15%), and the seasonal variation was possibly due to the relatively high microbial biotransformation activities in the activated sludge system in summer (indexed by O3-NAs/NAs). The results of the investigations indicated that biotransformation of NA mixtures by the activated sludge system were largely affected by temperature, and employing an efficient adsorbent together with biodegradation processes would help cost-effectively remove NAs in petroleum effluents.

Petroleum contamination and bioaugmentation in bacterial rhizosphere communities from Avicennia schaueriana.

PubMed

Dealtry, Simone; Ghizelini, Angela Michelato; Mendonça-Hagler, Leda C S; Chaloub, Ricardo Moreira; Reinert, Fernanda; Campos, Tácio M P de; Gomes, Newton C M; Smalla, Kornelia

2018-06-01

Anthropogenic activity, such as accidental oil spills, are typical sources of urban mangrove pollution that may affect mangrove bacterial communities as well as their mobile genetic elements. To evaluate remediation strategies, we followed over the time the effects of a petroleum hydrocarbon degrading consortium inoculated on mangrove tree Avicennia schaueriana against artificial petroleum contamination in a phytoremediation greenhouse experiment. Interestingly, despite plant protection due to the inoculation, denaturing gradient gel electrophoresis of the bacterial 16S rRNA gene fragments amplified from the total community DNA indicated that the different treatments did not significantly affect the bacterial community composition. However, while the bacterial community was rather stable, pronounced shifts were observed in the abundance of bacteria carrying plasmids. A PCR-Southern blot hybridization analysis indicated an increase in the abundance of IncP-9 catabolic plasmids. Denaturing gradient gel electrophoresis of naphthalene dioxygenase (ndo) genes amplified from cDNA (RNA) indicated the dominance of a specific ndo gene in the inoculated petroleum amendment treatment. The petroleum hydrocarbon degrading consortium characterization indicated the prevalence of bacteria assigned to Pseudomonas spp., Comamonas spp. and Ochrobactrum spp. IncP-9 plasmids were detected for the first time in Comamonas sp. and Ochrobactrum spp., which is a novelty of this study. Copyright © 2018 Sociedade Brasileira de Microbiologia. Published by Elsevier Editora Ltda. All rights reserved.

TPH detection in groundwater: Identification and elimination of positive interferences

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zemo, D.A.; Synowiec, K.A.

1996-01-01

Groundwater assessment programs frequently require total petroleum hydrocarbon (TPH) analyses (Methods 8015M and 418.1). TPH analyses are often unreliable indicators of water quality because these methods are not constituent-specific and are vulnerable to significant sources of positive interferences. These positive interferences include: (a) non-dissolved petroleum constituents; (b) soluble, non-petroleum hydrocarbons (e.g., biodegradation products); and (c) turbidity, commonly introduced into water samples during sample collection. In this paper, we show that the portion of a TPH concentration not directly the result of water-soluble petroleum constituents can be attributed solely to these positive interferences. To demonstrate the impact of these interferences, wemore » conducted a field experiment at a site affected by degraded crude oil. Although TPH was consistently detected in groundwater samples, BTEX was not detected. PNAs were not detected, except for very low concentrations of fluorene (<5 ug/1). Filtering and silica gel cleanup steps were added to sampling and analyses to remove particulates and biogenic by-products. Results showed that filtering lowered the Method 8015M concentrations and reduced the Method 418.1 concentrations to non-detectable. Silica gel cleanup reduced the Method 8015M concentrations to non-detectable. We conclude from this study that the TPH results from groundwater samples are artifacts of positive interferences caused by both particulates and biogenic materials and do not represent dissolved-phase petroleum constituents.« less

TPH detection in groundwater: Identification and elimination of positive interferences

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zemo, D.A.; Synowiec, K.A.

1996-12-31

Groundwater assessment programs frequently require total petroleum hydrocarbon (TPH) analyses (Methods 8015M and 418.1). TPH analyses are often unreliable indicators of water quality because these methods are not constituent-specific and are vulnerable to significant sources of positive interferences. These positive interferences include: (a) non-dissolved petroleum constituents; (b) soluble, non-petroleum hydrocarbons (e.g., biodegradation products); and (c) turbidity, commonly introduced into water samples during sample collection. In this paper, we show that the portion of a TPH concentration not directly the result of water-soluble petroleum constituents can be attributed solely to these positive interferences. To demonstrate the impact of these interferences, wemore » conducted a field experiment at a site affected by degraded crude oil. Although TPH was consistently detected in groundwater samples, BTEX was not detected. PNAs were not detected, except for very low concentrations of fluorene (<5 ug/1). Filtering and silica gel cleanup steps were added to sampling and analyses to remove particulates and biogenic by-products. Results showed that filtering lowered the Method 8015M concentrations and reduced the Method 418.1 concentrations to non-detectable. Silica gel cleanup reduced the Method 8015M concentrations to non-detectable. We conclude from this study that the TPH results from groundwater samples are artifacts of positive interferences caused by both particulates and biogenic materials and do not represent dissolved-phase petroleum constituents.« less

7 CFR 3201.65 - Concrete and asphalt cleaners.

Code of Federal Regulations, 2014 CFR

2014-01-01

... concrete etching as well as to remove petroleum-based soils, lubricants, paints, mastics, organic soils... product as a percent of the weight (mass) of the total organic carbon in the finished product. (c...

7 CFR 3201.65 - Concrete and asphalt cleaners.

Code of Federal Regulations, 2012 CFR

2012-01-01

... concrete etching as well as to remove petroleum-based soils, lubricants, paints, mastics, organic soils... product as a percent of the weight (mass) of the total organic carbon in the finished product. (c...

7 CFR 3201.65 - Concrete and asphalt cleaners.

Code of Federal Regulations, 2013 CFR

2013-01-01

... concrete etching as well as to remove petroleum-based soils, lubricants, paints, mastics, organic soils... product as a percent of the weight (mass) of the total organic carbon in the finished product. (c...

Issues in International Energy Consumption Analysis: Chinese Transportation Fuel Demand

EIA Publications

2014-01-01

Since the 1990s, China has experienced tremendous growth in its transportation sector. By the end of 2010, China's road infrastructure had emerged as the second-largest transportation system in the world after the United States. Passenger vehicle sales are dramatically increasing from a little more than half a million in 2000, to 3.7 million in 2005, to 13.8 million in 2010. This represents a twenty-fold increase from 2000 to 2010. The unprecedented motorization development in China led to a significant increase in oil demand, which requires China to import progressively more petroleum from other countries, with its share of petroleum imports exceeding 50% of total petroleum demand since 2009. In response to growing oil import dependency, the Chinese government is adopting a broad range of policies, including promotion of fuel-efficient vehicles, fuel conservation, increasing investments in oil resources around the world, and many others.

USGS world petroleum assessment 2000; new estimates of undiscovered oil and natural gas, including reserve growth, outside the United States

USGS Publications Warehouse

,

2000-01-01

Oil and natural gas account for approximately 63 percent of the world’s total energy consumption. The U.S. Geological Survey periodically estimates the amount of oil and gas remaining to be found in the world. Since 1981, each of the last four of these assessments has shown a slight increase in the combined volume of identified reserves and undiscovered resources. The latest assessment estimates the volume of technically recoverable conventional oil and gas that may be added to the world's reserves, exclusive of the United States, in the next 30 years. The USGS World Petroleum Assessment 2000 reports an increase in global petroleum resources, including a 20-percent increase in undiscovered oil and a 14-percent decrease in undiscovered natural gas compared to the previous assessment (table 1). These results have important implications for energy prices, policy, security, and the global resource balance.

Anoxic biodegradation of petroleum hydrocarbons in saline media using denitrifier biogranules.

PubMed

Moussavi, Gholamreza; Shekoohiyan, Sakine; Naddafi, Kazem

2016-07-01

The total petroleum hydrocarbons (TPH) biodegradation was examined using biogranules at different initial TPH concentration and contact time under anoxic condition in saline media. The circular compact biogranules having the average diameter between 2 and 3mm were composed of a dense population of Bacillus spp. capable of biodegrading TPH under anoxic condition in saline media were formed in first step of the study. The biogranules could biodegrade over 99% of the TPH at initial concentration up to 2g/L at the contact time of 22h under anoxic condition in saline media. The maximum TPH biodegradation rate of 2.6 gTPH/gbiomass.d could be obtained at initial TPH concentration of 10g/L. Accordingly, the anoxic biogranulation is a possible and promising technique for high-rate biodegradation of petroleum hydrocarbons in saline media. Copyright © 2016 Elsevier Inc. All rights reserved.

Tolerance of adult mallards to subacute ingestion of crude petroleum oil

USGS Publications Warehouse

Rattner, B.A.

1981-01-01

Adult male mallards were fed untreated mash or mash containing 1.5% Prudhoe Bay crude oil for 7 days ad lib. During the initial 24 h of exposure to crude petroleum oil, ducks consumed less mash (P less than 0.05) and lost approx. 3.5% of their initial body weight (P less than 0.05), however, neither intake nor body weight differ between groups on days 2-7. Plasma samples collected between 09.00 and 10.00 h on days 0, 1, 3, or 7 indicated that corticosterone, glucose, thyroxine, total protein, and uric acid concentrations, and the activities of aspartate aminotransferase (AST), alanine aminotransferase (ALT), and butyrylcholinesterase (BCHE) were not affected by treatment. These findings suggest that adult mallards may be able to tolerate large quantities of crude petroleum oil mixed in their diet (approx. 25 ml over a 7-day period) without overt or biochemical indications of distress.

Experimental study of the combined calcination and hydrodesulfurization of high-sulfur green petroleum coke

NASA Astrophysics Data System (ADS)

Kilic, Saliha Meltem

The primary production of aluminum is done by means of the Hall-Heroult process where large amounts of carbon anodes are required and consumed. The quality of carbon anodes used in electrolysis is one of the most important parameters affecting the production of primary aluminum. The anode quality widely depends on the raw materials, one of which is the petroleum coke. Green petroleum coke is produced from the heavy residual fractions of petroleum. Petroleum cokes produced from sour crude oil sources contain high quantity of sulfur. A certain level of sulfur is needed to reduce the anode reactivities; however, the demand for anode-grade coke with acceptable sulfur content is increasing faster than the available supply. High sulfur levels in carbon anodes would have an adverse effect on environment; hence, the desulfurization of high sulfur green petroleum cokes is necessary. There are different ways of desulfurizing green petroleum cokes: solvent extraction, thermal desulfurization, and hydrodesulfurization. Coke produced by solvent extraction is prone to contamination. The thermal approach requires greater energy consumption and causes an increase in coke porosity. The global objective of this master project is to find an alternative solution for desulfurization that will produce quality calcined coke with minimum impact on environment. Hydrodesulfurization seems to be a viable option and was investigated in this study. Water was used for the hydrodesulfurization of commercially available high sulfur green petroleum coke. Different experimental systems were tried during the hydrodesulfurization experiments. A systematic approach was used to investigate the influence of hydrodesulfurization parameters including water injection temperature, duration, and water flow rate as well as coke particle size on the hydrodesulfurization of green petroleum coke. In addition to hydrodesulfurization, a number of thermal desulfurization experiments were carried out with the same green petroleum coke in this study. Sulfur removal as well as weight loss results which were obtained from the two methods were compared. The petroleum coke sulfur content as well as its structure were characterized using C-S analysis equipment, SEM-EDX, XPS, FT-IR, XRD, and helium pycnometer prior to the experiments. Hydrodesulfurized cokes which gave maximum sulfur removal were compared with thermally desulfurized cokes in terms of the degree of desulfurization and coke structure by using the above characterization techniques. This study has indicated that different parameters affect the rate of desulfurization to different extents. Maximum sulfur removal was obtained when the water was injected to coke surface at 1 ml/min flow rate for 60 min at 650°C and 850°C resulting in the removal of 22.87% and 22.60% sulfur, respectively. Weight loss percentages were 26.07% and 24.34%, respectively, under these conditions. Hydrodesulfurization involves the loss of a small quantity of carbon due to gasification of coke by water. The characterization of hydrodesulfurized coke with the highest desulfurization rate showed similar structure with its counterpart which was thermally desulfurized to the same maximum temperature. This result, thus, reveals that the hydrodesulfurization does not create a more porous calcined coke compared to that of thermal desulfurization. Therefore, it seems to be a promising method to produce anode-grade calcined coke with lower sulfur content and suitable structure for carbon anode production.

Field-to-Fuel Performance Testing of Lignocellulosic Feedstocks for Fast Pyrolysis and Upgrading: Techno-economic Analysis and Greenhouse Gas Life Cycle Analysis

DOE Office of Scientific and Technical Information (OSTI.GOV)

Meyer, Pimphan A.; Snowden-Swan, Lesley J.; Rappé, Kenneth G.

This work shows preliminary results from techno-economic analysis and life cycle greenhouse gas analysis of the conversion of seven (7) biomass feedstocks to produce liquid transportation fuels via fast pyrolysis and upgrading via hydrodeoxygenation. The biomass consists of five (5) pure feeds (pine, tulip poplar, hybrid poplar, switchgrass, corn stover) and two blends. Blend 1 consists of equal weights of pine, tulip poplar and switchgrass, and blend 2 is 67% pine and 33% hybrid poplar. Upgraded oil product yield is one of the most significant parameters affecting the process economics, and is a function of both fast pyrolysis oil yieldmore » and hydrotreating oil yield. Pure pine produced the highest overall yield, while switchgrass produced the lowest. Interestingly, herbaceous materials blended with woody biomass performed nearly as well as pure woody feedstock, suggesting a non-trivial relationship between feedstock attributes and production yield. Production costs are also highly dependent upon hydrotreating catalyst-related costs. The catalysts contribute an average of ~15% to the total fuel cost, which can be reduced through research and development focused on achieving performance at increased space velocity (e.g., reduced catalyst loading) and prolonging catalyst lifetime. Green-house-gas reduction does not necessarily align with favorable economics. From the greenhouse gas analysis, processing tulip poplar achieves the largest GHG emission reduction relative to petroleum (~70%) because of its lower hydrogen consumption in the upgrading stage that results in a lower natural gas requirement for hydrogen production. Conversely, processing blend 1 results in the smallest GHG emission reduction from petroleum (~58%) because of high natural gas demand for hydrogen production.« less

Exposure of Trucking Company Workers to Particulate Matter during the Winter

PubMed Central

Lee, Byeong-Kyu; Smith, Thomas J.; Garshick, Eric; Natkin, Jonathan; Reaser, Paul; Lane, Kevin; Lee, Haengah Kim

2006-01-01

This study analyzed the workplace area concentrations and the personal exposure concentrations to fine particulate (PM2.5), elemental carbon (EC), and organic carbon (OC) measured during the winter period in trucking companies. The averaged personal exposure concentrations at breathing zones of workers are much greater than those of the microenvironment concentrations. The highest difference between the area (microenvironment) and personal exposure concentrations was in the PM2.5 concentrations followed by the OC concentrations. The area concentrations of PM2.5, EC, and OC at a large terminal were higher than those at a small one. The highest area concentrations of PM2.5, EC, and OC were observed in the shop areas followed by pick-up and delivery (P&D) areas. The area concentrations and personal exposure to PM2.5, EC, and OC in the shop and P&D areas which are highly affected by diesel engine exhaust emissions were much higher than those in the docks which are significantly affected by liquefied petroleum gas (LPG) engine exhaust emissions. The highest EC fraction to the total carbon (EC + OC) concentrations was observed in the shops, while the lowest one was identified in the offices. The personal exposure of the smoking workers to PM2.5 and OC was much higher than that of the non-smoking workers. However, the smoking might not significantly contribute to the personal exposure to EC. There were significant correlations between the PM2.5 and OC concentrations in both the area and personal exposure concentrations. However, significant correlations between the PM2.5 and EC concentrations and between the OC and EC concentrations were not identified. PMID:15913707

Petroleum developments in Middle East countries in 1967

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mason, J.F.; Moore, Q.M.

1968-08-01

Petroleum production in Middle East countries in 1967 totaled 3,679,506,000 bbl at an average rate of 10,080,838 bpd. This compares with 3,407,666,000 bbl or 9,336,071 bpd in 1966. The principal production increases were in Iran, Kuwait, Saudi Arabia, Qatar offshore, Abu Dhabi, and Oman (first production). New fields were found in offshore Iran, Neutral Zone, and Saudi Arabia. There were no exploration activities in Iraq, Aden, Kamaran Islands, Yeman, Hadramaut, and Cyprus. The main areas of exploratory work were in Iran, Saudi Arabia, Neutral Zone, and the southern Gulf (both onshore and offshore).

United Arab Emirates Country Analysis Brief

EIA Publications

2017-01-01

The United Arab Emirates (UAE) is among the world's 10 largest oil producers and is a member of the Organization of the Petroleum Exporting Countries (OPEC) and the Gas Exporting Countries Forum (GECF). The UAE is currently the seventh-largest petroleum producer in the world, and hydrocarbon export revenues are projected to account for $65 billion in 2017, roughly 20% of all export revenue. The share of hydrocarbon export revenues, which amounted to $129 billion (35% of total export revenue), has fallen since 2013 according to the International Monetary Fund (IMF) as a result of the decline in oil prices

Water-Quality Data for Selected National Park Units within the Southern Colorado Plateau Network, Arizona, Utah, Colorado, and New Mexico, Water Years 2005 and 2006

USGS Publications Warehouse

Macy, Jamie P.; Monroe, Stephen A.

2006-01-01

The National Park Service initiated a Level 1 Water-Quality Inventory program to provide water-quality data to park managers so informed natural resource management decisions could be made. Level 1 water-quality data were collected by the U.S. Geological Survey Arizona Water Science Center at 57 sites in 13 National Park units located in the Southern Colorado Plateau Inventory and Monitoring network in water years 2005 and 2006. These data describe the current water-quality at selected sites within the park units and provide information for monitoring future trends. Water samples were collected three times at each type of site including wells, springs, seeps, tinajas, rivers, a lake, and an irrigation ditch. Field measurements were taken at each site and they included pH, specific conductance, temperature, barometric pressure, dissolved oxygen, alkalinity, turbidity, and discharge rates where applicable. Water samples collected were sent to the U.S. Geological Survey National Water Quality Laboratory and analyzed for major ions, trace elements, and nutrients. The National Water Quality Laboratory also analyzed selected samples for mercury and petroleum hydrocarbons. Additional samples at selected sites were collected and analyzed for cyanide, radiochemistry, and suspended sediment by U.S. Geological Survey contract labs. Fecal-indicator bacteria (Escherichia coli) were sampled for at selected sites as another indicator of water quality. Quality control for this study was achieved through proper training of field personnel, use of standard U.S. Geological Survey field and laboratory protocols, collection of sample blanks and replicates, and a thorough review of the water-quality analyses. Measured field pH ranged from 6.0 to 8.8, within normal range for springs and rivers, at most sites. Concentrations of dissolved solids ranged from 48 to 8,680 mg/L and the majority of samples had concentrations of dissolved solids below 900 mg/L. Trace-element concentrations at most sites were at or near the laboratory reporting levels. The highest overall trace-element concentrations were found at U.S. Highway 160 Spring near Park Entrance to Mesa Verde National Park. Concentrations of uranium in samples at all sites ranged from below the detection limit to 55.7 ?g/L. Water samples from selected sites were analyzed for total petroleum hydrocarbons and concentrations of total petroleum hydrocarbons were at or above the laboratory detection limit in samples at six National Park units. Ten sites were sampled for Escherichia coli and positive counts were found at 9 out of the ten sites, the highest colony counts were found at Chinle Creek at Chinle, AZ in Canyon de Chelly National Monument. Measured concentrations of dissolved ammonia, nitrite, and nitrate were at or near laboratory reporting levels at most sites; nitrate concentrations ranged from below the reporting limit (0.047 mg/L) to 9.77 mg/L. Samples that were analyzed for mercury had concentrations below or at the laboratory reporting level. Concentrations of cyanide were less than the laboratory reporting level for all samples except two, Spruce Tree House Spring in Mesa Verde National Park and Pine Tree Canyon Tinaja in Canyon de Chelly National Monument, which had average concentrations of .042 and .011 ?g/L respectively. Gross alpha/beta radioactivity counts were below the U.S. Environmental Protection Agency maximum contaminant level except for samples from Casa Chiquita Well Middle at Chaco Culture National Historical Park which averaged 35 pCi/L. Suspended-sediment concentrations were variable and ranged from 10 to 150,000 mg/L.

Total Petroleum Hydrocarbons (TPH): ToxFAQs

MedlinePlus

... Favorites Del.icio.us Digg Facebook Google Bookmarks Yahoo MyWeb Page last reviewed: February 4, 2014 Page ... Favorites Del.icio.us Digg Facebook Google Bookmarks Yahoo MyWeb Contact Us: Agency for Toxic Substances and ...

Petroleum system modeling capabilities for use in oil and gas resource assessments

USGS Publications Warehouse

Higley, Debra K.; Lewan, Michael; Roberts, Laura N.R.; Henry, Mitchell E.

2006-01-01

Summary: Petroleum resource assessments are among the most highly visible and frequently cited scientific products of the U.S. Geological Survey. The assessments integrate diverse and extensive information on the geologic, geochemical, and petroleum production histories of provinces and regions of the United States and the World. Petroleum systems modeling incorporates these geoscience data in ways that strengthen the assessment process and results are presented visually and numerically. The purpose of this report is to outline the requirements, advantages, and limitations of one-dimensional (1-D), two-dimensional (2-D), and three-dimensional (3-D) petroleum systems modeling that can be applied to the assessment of oil and gas resources. Primary focus is on the application of the Integrated Exploration Systems (IES) PetroMod? software because of familiarity with that program as well as the emphasis by the USGS Energy Program on standardizing to one modeling application. The Western Canada Sedimentary Basin (WCSB) is used to demonstrate the use of the PetroMod? software. Petroleum systems modeling quantitatively extends the 'total petroleum systems' (TPS) concept (Magoon and Dow, 1994; Magoon and Schmoker, 2000) that is employed in USGS resource assessments. Modeling allows integration of state-of-the-art analysis techniques, and provides the means to test and refine understanding of oil and gas generation, migration, and accumulation. Results of modeling are presented visually, numerically, and statistically, which enhances interpretation of the processes that affect TPSs through time. Modeling also provides a framework for the input and processing of many kinds of data essential in resource assessment, including (1) petroleum system elements such as reservoir, seal, and source rock intervals; (2) timing of depositional, hiatus, and erosional events and their influences on petroleum systems; (3) incorporation of vertical and lateral distribution and lithologies of strata that compose the petroleum systems; and (4) calculations of pressure-volume-temperature (PVT) histories. As digital data on petroleum systems continue to expand, the models can integrate these data into USGS resource assessments by building and displaying, through time, areas of petroleum generation, migration pathways, accumulations, and relative contributions of source rocks to the hydrocarbon components. IES PetroMod? 1-D, 2-D, and 3-D models are integrated such that each uses the same variables for petroleum systems modeling. 1-D burial history models are point locations, mainly wells. Maps and cross-sections model geologic information in two dimensions and can incorporate direct input of 2-D seismic data and interpretations using various formats. Both 1-D and 2-D models use data essential for assessments and, following data compilation, they can be completed in hours and retested in minutes. Such models should be built early in the geologic assessment process, inasmuch as they incorporate the petroleum system elements of reservoir, source, and seal rock intervals with associated lithologies and depositional and erosional ages. The models can be used to delineate the petroleum systems. A number of 1-D and 2-D models can be constructed across a geologic province and used by the assessment geologists as a 3-D framework of processes that control petroleum generation, migration, and accumulation. The primary limitation of these models is that they only represent generation, migration, and accumulation in two dimensions. 3-D models are generally built at reservoir to basin scales. They provide a much more detailed and realistic representation of petroleum systems than 1-D or 2-D models because they portray more fully the temporal and physical relations among (1) burial history; (2) lithologies and associated changes through burial in porosity, permeability, and compaction; (3) hydrodynamic effects; and (4) other parameters that influence petroleum gen

Petroleum system of Northwest Java basin based on gravity data analysis

NASA Astrophysics Data System (ADS)

Widianto, E.

2018-01-01

Energy management in the upstream oil and gas sector becomes very important for the country’s energy security. The renewal of energy resources and reserves becomes necessary and is a must. In the oil and gas industry, gravity data is usually used only for regional surveys, but with the development of instrumentation technology and gravity software development, this method can be used for assessing oil and gas survey stages from exploration to production. This study was conducted to evaluate aspects of petroleum system and exploration play concept in the part of Northwest Java Basin, covering source rock deposition regions (source kitchen area, migration direction), development of reservoirs, structural and stratigraphic trap, based on gravity data. This study uses data from Bouguer gravity anomaly map by filtering process to produce a residual map depicting sedimentation basin configuration. The mapping generated 20 sedimentary basins in Java Island with the total hydrocarbon resources of 113 BBOE (Billion Barrel of Oil Equivalent). The petroleum system analysis was conducted in the Northwest Basin section. The final map produced illustrates the condition of petroleum system and play concept that can be used as exploration direction, expectedly reducing the risk of drilling failure.

Bioconversion of petroleum hydrocarbons in soil using apple filter cake

PubMed Central

Medaura, M. Cecilia; Ércoli, Eduardo C.

2008-01-01

The aim of this study was to investigate the feasibility of using apple filter cake, a fruit-processing waste to enhance the bioremediation of petroleum contaminated soil. A rotating barrel system was used to study the bioconversion of the xenobiotic compound by natural occurring microbial population. The soil had been accidentally polluted with a total petroleum hydrocarbon concentration of 41,000 ppm. Although this global value was maintained during the process, microbial intervention was evidenced through transformation of the petroleum fractions. Thus, fractions that represent a risk for the environment (GRO, Gasoline Range Organics i.e., C6 to C10–12; DRO, Diesel Range Organics i.e., C8–12 to C24–26 and RRO, Residual Range Organics i.e., C25 to C35) were significantly reduced, from 2.95% to 1.39%. On the contrary, heavier weight fraction from C35 plus other organics increased in value from 1.15% to 3.00%. The noticeable diminution of low molecular weight hydrocarbons content and hence environmental risk by the process plus the improvement of the physical characteristics of the soil, are promising results with regard to future application at large scale. PMID:24031241

Geology and assessment of the undiscovered, technically recoverable petroleum resources of Armenia, 2013

USGS Publications Warehouse

Klett, T.R.

2016-02-23

The U.S. Geological Survey (USGS) assessed the undiscovered, technically recoverable oil and gas resources of Armenia in 2013. A Paleozoic and a Cenozoic total petroleum system (TPS) were identified within the country of Armenia. The postulated petroleum system elements are uncertain, resulting in low geologic probabilities for significant oil an gas resources. Two assessment units (AU) were delineated in each TPS—a Paleozoic-Sourced Conventional Reservoirs AU and a Permian Shale Gas AU in the Paleozoic Composite TPS and a Paleogene-Sourced Conventional Reservoirs AU and a Cenozoic Coalbed Gas AU in the Cenozoic Composite TPS. The TPS elements are largely uncertain and risked, and so only the Paleogene-Sourced Conventional Reservoirs AU was quantitatively assessed because the geologic probability is more than the threshold of 10 percent (that is, the probability of at least one conventional oil or gas accumulation of 5 million barrels of oil equivalent or greater based on postulated petroleum-system elements). The USGS estimated fully risked mean volumes of about 1 million barrels of oil (MMBO), about 6 billion cubic feet of natural gas (BCFG), and less than 1 million barrels of natural gas liquids (MMBNGL).

Alaska: A twenty-first-century petroleum province

USGS Publications Warehouse

Bird, K.J.

2001-01-01

Alaska, the least explored of all United States regions, is estimated to contain approximately 40% of total U.S. undiscovered, technically recoverable oil and natural-gas resources, based on the most recent U.S. Department of the Interior (U.S. Geological Survey and Minerals Management Service) estimates. Northern Alaska, including the North Slope and adjacent Beaufort and Chukchi continental shelves, holds the lion's share of the total Alaskan endowment of more than 30 billion barrels (4.8 billion m3) of oil and natural-gas liquids plus nearly 200 trillion cubic feet (5.7 trillion m3) of natural gas. This geologically complex region includes prospective strata within passive-margin, rift, and foreland-basin sequences. Multiple source-rock zones have charged several regionally extensive petroleum systems. Extensional and compressional structures provide ample structural objectives. In addition, recent emphasis on stratigraphic traps has demonstrated significant resource potential in shelf and turbidite systems in Jurassic to Tertiary strata. Despite robust potential, northern Alaska remains a risky exploration frontier - a nexus of geologic complexity, harsh economic conditions, and volatile policy issues. Its role as a major petroleum province in this century will depend on continued technological innovations, not only in exploration and drilling operations, but also in development of huge, currently unmarketable natural-gas resources. Ultimately, policy decisions will determine whether exploration of arctic Alaska will proceed.

Microbial community dynamics during assays of harbour oil spill bioremediation: a microscale simulation study.

PubMed

Cappello, S; Caruso, G; Zampino, D; Monticelli, L S; Maimone, G; Denaro, R; Tripodo, B; Troussellier, M; Yakimov, M; Giuliano, L

2007-01-01

Microcosm experiments simulating an oil spill event were performed to evaluate the response of the natural microbial community structure of Messina harbour seawater following the accidental load of petroleum. An experimental harbour seawater microcosm, supplemented with nutrients and crude oil, was monitored above 15 days in comparison with unpolluted ones (control microcosms). Bacterial cells were counted with a Live/Dead BacLight viability kit; leucine aminopeptidase, beta-glucosidase, alkaline phosphatase, lipase and esterase enzymes were measured using fluorogenic substrates. The microbial community dynamic was monitored by isolation of total RNA, RT-PCR amplification of 16S rRNA, cloning and sequencing. Oil addition stimulated an increase of the total bacterial abundance, leucine aminopeptidase and phosphatase activity rates, as well as a change in the community structure. This suggested a prompt response of micro-organisms to the load of petroleum hydrocarbons. The present study on the viability, specific composition and metabolic characteristics of the microbial community allows a more precise assessment of oil pollution. Both structural and functional parameters offer interesting perspectives as indicators to monitor changes caused by petroleum hydrocarbons. A better knowledge of microbial structural successions at oil-polluted sites is essential for environmental bioremediation. Data obtained in microcosm studies improve our understanding of natural processes occurring during oil spills.

Petroleum Source Rock Maturation Data Constrain Predictions of Natural Hydrocarbon Seepage into the Atmosphere

NASA Astrophysics Data System (ADS)

Mansfield, M. L.

2013-12-01

Natural seepage of methane from the lithosphere to the atmosphere occurs in regions with large natural gas deposits. According to some authors, it accounts for roughly 5% of the global methane budget. I explore a new approach to estimate methane fluxes based on the maturation of kerogen, which is the hydrocarbon polymer present in petroleum source rocks, and whose pyrolysis leads to the formation of oil and natural gas. The temporal change in the atomic H/C ratio of kerogen lets us estimate the total carbon mass released by it in the form of oil and natural gas. Then the time interval of active kerogen pyrolysis lets us estimate the average annual formation rate of oil and natural gas in any given petroleum system. Obviously, this is an upper bound to the average annual rate at which natural gas seeps into the atmosphere. After adjusting for bio-oxidation of natural gas, I conclude that the average annual seepage rate in the Uinta Basin of eastern Utah is not greater than (3100 × 900) tonne/y. This is (0.5 × 0.15)% of the total flux of methane into the atmosphere over the Basin, as measured during aircraft flights. I speculate about the difference between the regional 0.5% and the global 5% estimates.

Hydrocarbon Degradation and Lead Solubility in a Soil Polluted with Lead and Used Motor Oil Treated by Composting and Phytoremediation.

PubMed

Escobar-Alvarado, L F; Vaca-Mier, M; López, R; Rojas-Valencia, M N

2018-02-01

Used lubricant oils and metals can be common soil pollutants in abandoned sites. When soil is contaminated with various hazardous wastes, the efficiency of biological treatments could be affected. The purpose of this work was to investigate the effect of combining phytoremediation and composting on the efficiency of hydrocarbon degradation and lead solubility in a soil contaminated with 31,823 mg/kg of total petroleum hydrocarbon (TPH) from used motor oil and 8260 mg/kg of lead. Mexican cactus (Opuntia ficus indica) and yard trimmings were added in the composting process, and lucerne (Medicago sativa) was used in the phytoremediation process. After a 9 week composting process, only 13% of the initial TPH concentration was removed. The following 20 week phytoremediation process removed 48% of TPH. The highest TPH degradation percentage (66%), was observed in the experiment with phytoremediation only. This work demonstrates sustainable technologies, such as biological treatments, represent low-cost options for remediation; however, they are not frequently used because they require long periods of time for success.

In vitro efficacies of oils, silicas and plant preparations against the poultry red mite Dermanyssus gallinae.

PubMed

Maurer, Veronika; Perler, Erika; Heckendorn, Felix

2009-06-01

The aim of this study was to test the effectiveness of physically acting substances (oils and silicas) and plant preparations for the control of the poultry red mite Dermanyssus gallinae (De Geer 1778). Reproduction and survival of fed D. gallinae females were evaluated in vitro for a total of 168 h using the "area under the survival curve" (AUC) to compare survival of the mites between treatments. Four oils (two plant oils, one petroleum spray oil and diesel), one soap, three silicas (one synthetic amorphous silica, one diatomaceous earth (DE) and one DE with 2% pyrethrum extract) and seven plant preparations (derived from Chrysanthemum cineariaefolium, Allium sativum, Tanacetum vulgare, Yucca schidigera, Quillaja saponaria, Dryopteris filix-mas, and Thuja occidentalis) were tested at various concentrations. All the oils, diesel and soap significantly reduced D. gallinae survival. All silicas tested inhibited reproduction. DE significantly reduced mite survival, but amorphous silica was less effective in vitro. Except for pure A. sativum juice and the highest concentration of C. cineariaefolium extract, the plant preparations tested resulted in statistically insignificant control of D. gallinae.

Chapter 32: Geology and petroleum potential of the Arctic Alaska petroleum province

USGS Publications Warehouse

Bird, K.J.; Houseknecht, D.W.

2011-01-01

The Arctic Alaska petroleum province encompasses all lands and adjacent continental shelf areas north of the Brooks Range-Herald Arch orogenic belt and south of the northern (outboard) margin of the Beaufort Rift shoulder. Even though only a small part is thoroughly explored, it is one of the most prolific petroleum provinces in North America with total known resources (cumulative production plus proved reserves) of c. 28 BBOE. The province constitutes a significant part of a displaced continental fragment, the Arctic Alaska microplate, that was probably rifted from the Canadian Arctic margin during formation of the Canada Basin. Petroleum prospective rocks in the province, mostly Mississippian and younger, record a sequential geological evolution through passive margin, rift and foreland basin tectonic stages. Significant petroleum source and reservoir rocks were formed during each tectonic stage but it was the foreland basin stage that provided the necessary burial heating to generate petroleum from the source rocks. The lion's share of known petroleum resources in the province occur in combination structural-stratigraphic traps formed as a consequence of rifting and located along the rift shoulder. Since the discovery of the super-giant Prudhoe Bay accumulation in one of these traps in the late 1960s, exploration activity preferentially focused on these types of traps. More recent activity, however, has emphasized the potential for stratigraphic traps and the prospect of a natural gas pipeline in this region has spurred renewed interest in structural traps. For assessment purposes, the province is divided into a Platform assessment unit (AU), comprising the Beaufort Rift shoulder and its relatively undeformed flanks, and a Fold-and-Thrust Belt AU, comprising the deformed area north of the Brooks Range and Herald Arch tectonic belt. Mean estimates of undiscovered, technically recoverable resources include nearly 28 billion barrels of oil (BBO) and 122 trillion cubic feet (TCF) of nonassociated gas in the Platform AU and 2 BBO and 59 TCF of nonassociated gas in the Fold-and-Thrust Belt AU. ?? 2011 The Geological Society of London.

[Humus composition of petroleum hydrocarbon-contaminated soil].

PubMed

Feng, Jun; Tang, Li-Na; Zhang, Jin-Jing; Dou, Sen

2008-05-01

An abandoned petroleum well which had been exploited for about twenty years in Songyuan city of Jilin Province, China, was selected to study the compositions and characteristics of soil humus using revised humus composition method and Simon-Kumada method. Soil samples were collected at 0.5, 1.5, 2.5, 3.5, 4.5, 5.5, 6.5, 7.5 and 10.5 m apart from the well head. Results show that the petroleum contents increase from 0.08 g/kg (10.5 m to the well head) to 153.3 g/kg (0.5 m to the well head). With the increase in petroleum content, the contents of soil organic carbon and water soluble organic carbon increase; for total soil humus, the contents of extractable humus (HE) and humic acid (HA) decrease whereas that of humin (HM) increase; the percentage of HA/HE (PQ 72.0%-8.05%) decrease and HM/HE ratio (31.4-76.7) increase; for different combined humus, the contents of loosely combined humus (HI) and stably combined humus (HII) have a decrease tendency while that of tightly combined humus (HIII) increase; the HI/HII ratio (0.19-0.39) shows an increase tendency, whereas HI/HIII ratio (0.032-0.003) and HII/HIII ratio (0.096-0.009) decrease; the PQs of HI (3.21%-1.42%) and HIII (58.1%-35.5%) also decrease, and the range of PQ change is less in HI than in HII; the color coefficient (deltalogk) of water soluble organic matter (WSOM) decreases, whereas no obvious change for HA. The above results indicate that petroleum hydrocarbon promotes the formation of HM but not HA. The decrease in HA is mainly due to the restraining effect of petroleum hydrocarbon on the formation of stably combined HA. Petroleum hydrocarbon leads molecular structure of WSOM more complex but no effect on molecular structure of HA.

Antifungal potential of Avicennia schaueriana Stapf & Leech. (Acanthaceae) against Cladosporium and Colletotrichum species.

PubMed

Fardin, K M; Young, M C M

2015-07-01

There is significant interest in research to develop plant extracts with fungicidal activities that are less harmful to the environment and human health than synthetic fungicides. This study aimed to evaluate the antifungal activity of the extracts of Avicennia schaueriana against Colletotrichum and Cladosporium species and to identify the compounds responsible for the activity. Leaves and stems of A. schaueriana were extracted with ethanol and partitioned with petroleum ether, chloroform and ethyl acetate. The antifungal activity of such extracts was tested by bioautography against Cladosporium sphaerospermum, Cladosporium cladosporioides and Colletotrichum lagenarium. Ethanolic extracts, petroleum ether and chloroform fractions of stems had the highest antifungal activity with several active bands (Rf = 0·72 and Rf = 0·55). In the agar dilution assay, ethanolic extract, petroleum ether and chloroform fractions of stems were the most efficacious, presenting 85, 62 and 63% growth inhibition of Colletotrichum gloeopsporioides and minimum inhibitory concentration values between 1 and 1·5 mg ml(-1) , respectively. Analysis carried out using gas chromatography coupled to a mass spectrometry of petroleum ether and chloroform fractions allowed the identification of fatty acids methyl esters, lupeol and naphthoquinones such as lapachol, α-lapachone, naphtho[2,3-b]furan-4,9-dione, 2-isopropyl- and avicenol-C. We may infer that the antifungal activity of A. schaueriana is due to the abundance of these compounds. This study shows that Avicennia schaueriana extracts have a high potential for the growth inhibition of Colletotrichum and Cladosporium ssp. and will provide a starting point for discovering new natural products with antifungal activity. Their development is of particular interest to organic production systems where synthetic fungicides cannot be used. © 2015 The Society for Applied Microbiology.

Corrosion-Related Consequences of Biodiesel in Contact with Natural Seawater

DTIC Science & Technology

2010-03-01

petroleum diesel, biodiesel contains no sulfur. In the U.S. the term “biodiesel” is standardized as fatty acid methyl ester ( FAME ). Biodiesel content is...Form 298 (Rev. 8-98) Prescribed by ANSI Std Z39-18 to methyl (or ethyl) esters with a process known as transesterification.4 The transesterification...biodegradation of the vegetable methyl esters in agitated San Francisco Bay water was less than 4 days at 17 °C.4,22 The highest corrosion rates

Quantification of petroleum-type hydrocarbons in avian tissue

USGS Publications Warehouse

Gay, M.L.; Belisle, A.A.; Patton, J.F.

1980-01-01

Methods were developed for the analysis of 16 hydrocarbons in avian tissue. Mechanical extraction with pentane was followed by clean-up on Florisil and Silicar. Residues were determined by gas—liquid chromatography and gas—liquid, chromatography—mass spectrometry. The method was applied to the analysis of liver, kidney, fat, and brain tissue of mallard ducks (Anas platyrhynchos) fed a mixture of hydrocarbons. Measurable concentrations of all compounds analyzed were present in all tissues except brain. Highest concentrations were in fat.

GC/GCMS analysis of the petroleum ether and dichloromethane extracts of Moringa oleifera roots

PubMed Central

Faizi, Shaheen; Sumbul, Saima; Versiani, Muhammed Ali; Saleem, Rubeena; Sana, Aisha; Siddiqui, Hira

2014-01-01

Objective To explore the phytochemical constituents from petroleum ether and dichloromethane extracts of Moringa oleifera (M. oleifera) roots using GC/GC-MS. Methods A total of 5.11 kg fresh and undried crushed root of M. oleifera were cut into small pieces and extracted with petroleum ether and dichloromethane (20 L each) at room temperature for 2 d. The concentrated extracts were subjected to their GC-MS analysis. Results The GC-MS analysis of the petroleum ether and dichloromethane extracts of M. oleifera roots, which showed promising biological activities, has resulted in the identification 102 compounds. These constituents belong to 15 classes of compounds including hydrocarbons, fatty acids, esters, alcohols, isothiocyanate, thiocyanate, pyrazine, aromatics, alkamides, cyanides, steroids, halocompounds, urea and N-hydroxyimine derivatives, unsaturated alkenamides, alkyne and indole. GC/GC-MS studies on petroleum ether extract of the roots revealed that it contained 39 compounds, belonging to nine classes. Cyclooctasulfur S8 has been isolated as a pure compound from the extract. The major compounds identified from petroleum ether extract were trans-13-docosene (37.9%), nonacosane (32.6%), cycloartenol (28.6%) nonadecanoic acid (13.9%) and cyclooctasulfur S8 (13.9%). Dichloromethane extract of the roots was composed of 63 compounds of which nasimizinol (58.8%) along with oleic acid (46.5%), N-benzyl-N-(7-cyanato heptanamide (38.3%), N-benzyl-N-(1-chlorononyl) amide (30.3%), bis [3-benzyl prop-2-ene]-1-one (19.5%) and N, N-dibenzyl-2-ene pent 1, 5-diamide (11.6%) were the main constituents. Conclusions This study helps to predict the formula and structure of active molecules which can be used as drugs. This result also enhances the traditional usage of M. oleifera which possesses a number of bioactive compounds. PMID:25183335

Petroleum generation and migration in the Mesopotamian Basin and Zagros fold belt of Iraq: Results from a basin-modeling study

USGS Publications Warehouse

Pitman, Janet K.; Steinshouer, D.; Lewan, M.D.

2004-01-01

A regional 3-D total petroleum-system model was developed to evaluate petroleum generation and migration histories in the Mesopotamian Basin and Zagros fold belt in Iraq. The modeling was undertaken in conjunction with Middle East petroleum assessment studies conducted by the USGS. Regional structure maps, isopach and facies maps, and thermal maturity data were used as input to the model. The oil-generation potential of Jurassic source-rocks, the principal known source of the petroleum in Jurassic, Cretaceous, and Tertiary reservoirs in these regions, was modeled using hydrous pyrolysis (Type II-S) kerogen kinetics. Results showed that oil generation in source rocks commenced in the Late Cretaceous in intrashelf basins, peak expulsion took place in the late Miocene and Pliocene when these depocenters had expanded along the Zagros foredeep trend, and generation ended in the Holocene when deposition in the foredeep ceased. The model indicates that, at present, the majority of Jurassic source rocks in Iraq have reached or exceeded peak oil generation and most rocks have completed oil generation and expulsion. Flow-path simulations demonstrate that virtually all oil and gas fields in the Mesopotamian Basin and Zagros fold belt overlie mature Jurassic source rocks (vertical migration dominated) and are situated on, or close to, modeled migration pathways. Fields closest to modeled pathways associated with source rocks in local intrashelf basins were charged earliest from Late Cretaceous through the middle Miocene, and other fields filled later when compression-related traps were being formed. Model results confirm petroleum migration along major, northwest-trending folds and faults, and oil migration loss at the surface.

Temperature and petroleum generation history of the Wilcox Formation, Louisiana

USGS Publications Warehouse

Pitman, Janet K.; Rowan, Elisabeth Rowan

2012-01-01

A one-dimensional petroleum system modeling study of Paleogene source rocks in Louisiana was undertaken in order to characterize their thermal history and to establish the timing and extent of petroleum generation. The focus of the modeling study was the Paleocene and Eocene Wilcox Formation, which contains the youngest source rock interval in the Gulf Coast Province. Stratigraphic input to the models included thicknesses and ages of deposition, lithologies, amounts and ages of erosion, and ages for periods of nondeposition. Oil-generation potential of the Wilcox Formation was modeled using an initial total organic carbon of 2 weight percent and an initial hydrogen index of 261 milligrams of hydrocarbon per grams of total organic carbon. Isothermal, hydrous-pyrolysis kinetics determined experimentally was used to simulate oil generation from coal, which is the primary source of oil in Eocene rocks. Model simulations indicate that generation of oil commenced in the Wilcox Formation during a fairly wide age range, from 37 million years ago to the present day. Differences in maturity with respect to oil generation occur across the Lower Cretaceous shelf edge. Source rocks that are thermally immature and have not generated oil (depths less than about 5,000 feet) lie updip and north of the shelf edge; source rocks that have generated all of their oil and are overmature (depths greater than about 13,000 feet) are present downdip and south of the shelf edge. High rates of sediment deposition coupled with increased accommodation space at the Cretaceous shelf margin led to deep burial of Cretaceous and Tertiary source rocks and, in turn, rapid generation of petroleum and, ultimately, cracking of oil to gas.

Petroleum source potential of the Lower Cretaceous mudstone succession of the NPRA and Colville Delta area, North Slope Alaska, based on sonic and resistivity logs

USGS Publications Warehouse

Keller, Margaret A.; Bird, Kenneth J.

2003-01-01

Resource assessment of the North Slope of Alaska by the U. S. Geological Survey includes evaluation of the petroleum source potential of Mesozoic and Cenozoic rocks using the delta log R technique (Passey and others, 1990). Porosity and resistivity logs are used in combination with thermal maturity data to produce a continuous profile of total organic carbon content in weight % (TOC). From the pattern and amount of TOC in the profile produced, the depositional setting and thus the petroleum source-rock potential (kerogen type) of the organic matter can be inferred and compared to interpretations from other data such as Rock-Eval pyrolysis. TOC profiles determined by this technique for the contiguous interval of pebble shale unit, Hue Shale (including the Gamma Ray Zone or GRZ), and lower part of the Torok Formation indicate important potential for petroleum generation in the Tunalik 1, Inigok 1, N. Inigok 1, Kuyanak 1, Texaco Colville Delta 1, Nechelik 1, and Bergschrund 1 wells of the western North Slope region. TOC profiles suggest that this interval contains both type II and III kerogens – consistent with proposed depositional models -- and is predominantly greater than 2 wt. % TOC (cut-off used for effective source potential). Average TOC for the total effective section of the pebble shale unit + Hue Shale ranges from 2.6 to 4.1 wt % TOC (values predominantly 2-8% TOC) over 192-352 ft. Source potential for the lower Torok Formation, which also has interbedded sandstone and lean mudstone, is good to negligible in these 7 wells.

Size distribution and sources of 37 toxic species of particulate polycyclic aromatic hydrocarbons during summer and winter in Baoshan suburban area of Shanghai, China.

PubMed

Wang, Qingyue; Kobayashi, Keisuke; Wang, Weiqian; Ruan, Jie; Nakajima, Daisuke; Yagishita, Mayuko; Lu, Senlin; Zhang, Wenchao; Suzuki, Miho; Saitou, Tomoya; Sekiguchi, Kazuhiko; Sankoda, Kenshi; Takao, Yuji; Nagae, Masaki; Terasaki, Masanori

2016-10-01

The objectives of this study were to assess the size-segregated distribution and sources of 37 different species of particulate polycyclic aromatic hydrocarbons (PAHs) in a suburban area of Shanghai metropolitan City, China. The ambient particulate sampling was carried out on the rooftop of a five-stories building in Baoshan campus of Shanghai University. An Andersen high-volume air sampler was employed to collect ambient size-segregated particulate matter during summer of August to September and winter of November to December 2015. The high toxic PAHs were determined by a gas chromatography mass spectrometry. The concentrations of total PAHs in suspended particulate matter (SPM) and PM1.1 (suspended particulate matter below 1.1μm in diameter) in the suburban area of Shanghai were 4.58-14.5ng/m(3) and 1.82-8.56ng/m(3), respectively in summer, and 43.6-160ng/m(3) and 23.2-121ng/m(3), separately in winter. 1,8-Naphthalic anhydride (1,8-NA) showed the highest concentration among 37 different species of PAHs in the suburban area of Shanghai. The concentrations of high molecular PAHs (e.g. 5-6 ring PAHs) followed a nearly unimodal size distribution with the highest peaks in PM1.1. The diagnostic ration qualitatively indicated that PAHs in SPM of Shanghai were mainly derived from motor-vehicle or petroleum combustion in summer and from coal and biomass combustion in winter. According to the calculated toxicity equivalency factors based on the methods of Nisbet and Lagoy and the potency equivalency factors (PEF) recommended by U.S. EPA, the highest contributors in the total carcinogenicity of the PAHs in SPM and PM1.1 were dibenzo[a,h]pyrene (46.2% and 45.0% in summer), benzo[a]pyrene (44.4% and 43.8% in winter) and benz[j]aceanthrylene (80.2% and 83.1% in summer and 83.1% and 84.0% in winter), respectively. Therefore, benzo[a]pyrene seemed to be a lower contributor than other carcinogenic PAHs. Copyright © 2016 Elsevier B.V. All rights reserved.

Advances of two-stage riser catalytic cracking of heavy oil for maximizing propylene yield (TMP) process.

PubMed

Chaohe, Yang; Xiaobo, Chen; Jinhong, Zhang; Chunyi, Li; Honghong, Shan

Two-stage riser catalytic cracking of heavy oil for maximizing propylene yield (TMP) process proposed by State Key Laboratory of Heavy oil Processing, China University of Petroleum, can remarkably enhance the propylene yield and minimize the dry gas and coke yields, and obtain high-quality light oils (gasoline and diesel). It has been commercialized since 2006. Up to now, three TMP commercial units have been put into production and other four commercial units are under design and construction. The commercial data showed that taking paraffinic based Daqing (China) atmospheric residue as the feedstock, the propylene yield reached 20.31 wt%, the liquid products yield (the total yield of liquefied petroleum gas, gasoline, and diesel) was 82.66 wt%, and the total yield of dry gas and coke was 14.28 wt%. Moreover, the research octane number of gasoline could be up to 96.

Optimization of ultrasonic-assisted extraction of pomegranate (Punica granatum L.) seed oil.

PubMed

Tian, Yuting; Xu, Zhenbo; Zheng, Baodong; Martin Lo, Y

2013-01-01

The effectiveness of ultrasonic-assisted extraction (UAE) of pomegranate seed oil (PSO) was evaluated using a variety of solvents. Petroleum ether was the most effective for oil extraction, followed by n-hexane, ethyl acetate, diethyl ether, acetone, and isopropanol. Several variables, such as ultrasonic power, extraction temperature, extraction time, and the ratio of solvent volume and seed weight (S/S ratio) were studied for optimization using response surface methodology (RSM). The highest oil yield, 25.11% (w/w), was obtained using petroleum ether under optimal conditions for ultrasonic power, extraction temperature, extraction time, and S/S ratio at 140 W, 40 °C, 36 min, and 10 ml/g, respectively. The PSO yield extracted by UAE was significantly higher than by using Soxhlet extraction (SE; 20.50%) and supercriti cal fluid extraction (SFE; 15.72%). The fatty acid compositions were significantly different among the PSO extracted by Soxhlet extraction, SFE, and UAE, with punicic acid (>65%) being the most dominant using UAE. Copyright © 2012 Elsevier B.V. All rights reserved.

Spatial distribution and historical trends of heavy metals in the sediments of petroleum producing regions of the Beibu Gulf, China.

PubMed

Yang, Jichao; Wang, Weiguo; Zhao, Mengwei; Chen, Bin; Dada, Olusegun A; Chu, Zhihui

2015-02-15

The concentrations of As, Sb, Hg, Pb, Cd, and Ba in the surface and core sediments of the oil and gas producing region of the Beibu Gulf were measured by Inductively Coupled Plasma Optical Emission Spectrometry (ICP-OES), Inductively Coupled Plasma Mass Spectrometry (ICP-MS) and Atomic Fluorescence Spectrometry (AFS), and the spatial distribution and historical trends of these elements are discussed. The results show that the concentrations of these elements are highest near the platforms. The results of Enrichment Factor (EF) and Potential Ecological Risk Index (PERI) also reveal significantly higher enrichment around the platforms, which imply that the offshore petroleum production was the cause of the unusual distribution and severe enrichment of these elements in the study area. The environment around the platforms was highly laden with toxic elements, thereby representing a very high ecological risk to the environment of the study area. Copyright © 2014 Elsevier Ltd. All rights reserved.

Self-cementitious properties of fly ashes from CFBC boilers co-firing coal and high-sulphur petroleum coke

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sheng Guanghong; Li Qin; Zhai Jianping

2007-06-15

Self-cementitious properties of fly ash from circulating fluidized bed combustion boiler co-firing coal and high-sulphur petroleum coke (CPFA) were investigated. CPFA was self-cementitious which was affected by its fineness and chemical compositions, especially the contents of SO{sub 3} and free lime (f-CaO). Higher contents of SO{sub 3} and f-CaO were beneficial to self-cementitious strength; the self-cementitious strength increases with a decrease of its 45 {mu}m sieve residue. The expansive ratio of CPFA hardened paste was high because of generation of ettringite (AFt), which was influenced by its water to binder ratio (W/A), curing style and grinding of the ash. Themore » paste cured in water had the highest expansive ratio, and grinding of CPFA was beneficial to its volume stability. The hydration products of CPFA detected by X-ray diffraction (XRD) and scanning electron microscopy (SEM) were portlandite, gypsum, AFt and hydrated calcium silicate (C-S-H)« less

Petroleum oil removal by immobilized bacterial cells on polyurethane foam under different temperature conditions.

PubMed

Alessandrello, Mauricio J; Juárez Tomás, María S; Raimondo, Enzo E; Vullo, Diana L; Ferrero, Marcela A

2017-09-15

In this work, a mixed biofilm composed by Pseudomonas monteilii P26 and Gordonia sp. H19 was formed using polyurethane foam (PUF) as immobilization support, for crude oil removal from artificial sea water. Fresh immobilized cells and immobilized cells that were stored at 4°C for two months before use were assessed. The oil removal assays were carried out at microcosm scale at 4, 15 and 30°C. A viability loss of P. monteilii P26 was observed after the storage. The highest removal value (75%) was obtained at 30°C after 7days using fresh immobilized cells on PUF. Enhanced oil bioremoval was obtained at 4°C and 15°C with the previously stored immobilized cells compared to the fresh immobilized cells. Crude oil sorption on the different systems was responsible for the removal of 22-33% oil at the different temperatures. In conclusion, an economic tool for petroleum bioremediation is proposed. Copyright © 2017 Elsevier Ltd. All rights reserved.

Kinetic modeling of liquefied petroleum gas (LPG) reduction of titania in MATLAB

NASA Astrophysics Data System (ADS)

Yin, Tan Wei; Ramakrishnan, Sivakumar; Rezan, Sheikh Abdul; Noor, Ahmad Fauzi Mohd; Izah Shoparwe, Noor; Alizadeh, Reza; Roohi, Parham

2017-04-01

In the present study, reduction of Titania (TiO2) by liquefied petroleum gas (LPG)-hydrogen-argon gas mixture was investigated by experimental and kinetic modelling in MATLAB. The reduction experiments were carried out in the temperature range of 1100-1200°C with a reduction time from 1-3 hours and 10-20 minutes of LPG flowing time. A shrinking core model (SCM) was employed for the kinetic modelling in order to determine the rate and extent of reduction. The highest experimental extent of reduction of 38% occurred at a temperature of 1200°C with 3 hours reduction time and 20 minutes of LPG flowing time. The SCM gave a predicted extent of reduction of 82.1% due to assumptions made in the model. The deviation between SCM and experimental data was attributed to porosity, thermodynamic properties and minute thermal fluctuations within the sample. In general, the reduction rates increased with increasing reduction temperature and LPG flowing time.

Studies on the origin and transformation of selenium and its chemical species along the process of petroleum refining

NASA Astrophysics Data System (ADS)

Stivanin de Almeida, Cibele M.; Ribeiro, Anderson S.; Saint'Pierre, Tatiana D.; Miekeley, Norbert

2009-06-01

Inductively coupled plasma optical emission spectrometry and mass spectrometry (ICPMS), the latter hyphenated to flow injection hydride generation, electrothermal vaporization or ion chromatography, have been applied to the chemical characterization of crude oil, aqueous process stream samples and wastewaters from a petroleum refinery, in order to get information on the behavior of selenium and its chemical species along effluent generation and treatment. Multielemental characterization of these effluents by ICPMS revealed a complex composition of most of them, with high salinity and potential spectral and non-spectral interferents present. For this reason, a critical re-assessment of the analytical techniques for the determination of total selenium and its species was performed. Methane was employed as gas in dynamic reaction cell ICPMS and cell parameters were optimized for a simulated brine matrix and for diluted aqueous solutions to match the expected process and treated wastewaters samples. The signal-to-background ratios for 78Se and 80Se were used as criteria in optimization, the first isotope resulting in better detection limits for the simulated brine matrix ( 78Se: 0.07 μg L - 1 , 80Se: 0.31 μg L - 1 ). A large variability in the concentration of selenium (from < 10 μg kg - 1 up to 960 μg kg - 1 ) was observed in 16 of the most frequently processed crude oil samples in the refinery here investigated, which may explain the pronounced concentrations changes of this element measured in aqueous process stream and wastewater samples. Highest concentrations of total selenium were analyzed in samples from the hydrotreater (up to about 1800 μg L - 1 ). The predominance of selenocyanate (SeCN -) was observed in most of the wastewaters so far investigated, but also other species were detected with retention times different from Se(IV), Se(VI) and SeCN -. Colloidal selenium (Se 0) was the only Se-species observed in samples from the atmospheric distillation unit, but was also identified in other samples, most probably formed by the decomposition of SeCN - or other unstable species.

Naphthalene and benzene degradation under Fe(III)-reducing conditions in petroleum-contaminated aquifers

USGS Publications Warehouse

Anderson, Robert T.; Lovely, Derek R.

1999-01-01

Naphthalene was oxidized anaerobically to CO2 in sediments collected from a petroleum-contaminated aquifer in Bemidji, Minnesota in which Fe(III) reduction was the terminal electron-accepting process. Naphthalene was not oxidized in sediments from the methanogenic zone at Bemidji or in sediments from the Fe(III)-reducing zone of other petroleum-contaminated aquifers studied. In a profile across the Fe(III)-reducing zone of the Bemidji aquifer, rates of naphthalene oxidation were fastest in sediments with the highest proportion of Fe(III), which was also the zone of the most rapid degradation of benzene, toluene, and acetate. The comparative studies attempted to elucidate factors that might account for the fact that unsubstituted aromatic hydrocarbons such as benzene and naphthalene were degraded under Fe(III)-reducing conditions at Bemidji, but not at the other aquifers examined. These studies indicated that the ability of Fe(III)-reducing microorganisms to degrade benzene and naphthalene at the Bemidji site cannot be attributed to groundwater components that make Fe(III) more available for reduction or other potential factors that were evaluated. However, unlike the other aquifers evaluated, uncontaminated sediments at the Bemidji site could be adapted for anaerobic benzene degradation merely with the addition of benzene. These findings indicate that Bemidji sediments naturally contain Fe(III) reducers capable of degradation of unsubstituted aromatic hydrocarbons.

[Procedure for Latrodectus reproduction in the laboratory setting and the preparation of the first Russian matrix from its venom to manufacture homeopathic remedies with antiparasitic activity].

PubMed

Streliaeva, A V; Gasparian, E R; Polzikov, V V; Sagieva, A T; Lazareva, N B; Kurilov, D V; Chebyshev, N V; Sadykov, V M; Zuev, S S; Shcheglova, T A

2012-01-01

The investigation was undertaken to study the biology and ecology of Latrodectus, the possibilities of its importation to Russia from other countries, to breed Latrodectus in the laboratory setting, and to design the first homeopathic matrix of Latrodectus to manufacture homeopathic remedies. The authors were the first to devise a method for Latrodectus breeding in the laboratory setting of Moscow and its vicinities. The Latrodectus bred in the laboratory is suitable to manufacture drugs and in captivity they do not lose its biological activity. The authors were the first to prepare a homeopathic Latrodectus matrix for homeopathic medicines, by using the new Russian extragent petroleum. Chromatography mass spectrometry was used to identify more than a hundred chemical compounds in the Russian petroleum. The biological activity of the petroleum Latrodectus matrix for the manufacture of homeopathic remedies was highly competitive with that of the traditional Latrodectus venom matrix made using ethyl alcohol. The homeopathic Latrodectus matrix made using glycerol lost its biological activity because of glycerol. The biological activity of homeopathic matrixes made from Latrodectus inhabiting the USA, Uzbekistan, and the south of Russia and from that bred in the laboratory was studied. The homeopathic matrix made from the Latrodectus living in the Samarkand Region, Republic of Uzbekistan, has the highest biological activity.

Decontamination of soil washing wastewater using solar driven advanced oxidation processes.

PubMed

Bandala, Erick R; Velasco, Yuridia; Torres, Luis G

2008-12-30

Decontamination of soil washing wastewater was performed using two different solar driven advanced oxidation processes (AOPs): the photo-Fenton reaction and the cobalt/peroxymonosulfate/ultraviolet (Co/PMS/UV) process. Complete sodium dodecyl sulphate (SDS), the surfactant agent used to enhance soil washing process, degradation was achieved when the Co/PMS/UV process was used. In the case of photo-Fenton reaction, almost complete SDS degradation was achieved after the use of almost four times the actual energy amount required by the Co/PMS/UV process. Initial reaction rate in the first 15min (IR15) was determined for each process in order to compare them. Highest IR15 value was determined for the Co/PMS/UV process (0.011mmol/min) followed by the photo-Fenton reaction (0.0072mmol/min) and the dark Co/PMS and Fenton processes (IR15=0.002mmol/min in both cases). Organic matter depletion in the wastewater, as the sum of surfactant and total petroleum hydrocarbons present (measured as chemical oxygen demand, COD), was also determined for both solar driven processes. It was found that, for the case of COD, the highest removal (69%) was achieved when photo-Fenton reaction was used whereas Co/PMS/UV process yielded a slightly lower removal (51%). In both cases, organic matter removal achieved was over 50%, which can be consider proper for the coupling of the tested AOPs with conventional wastewater treatment processes such as biodegradation.

31 CFR 576.308 - Iraqi petroleum and petroleum products.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 31 Money and Finance:Treasury 3 2011-07-01 2011-07-01 false Iraqi petroleum and petroleum products... SANCTIONS REGULATIONS General Definitions § 576.308 Iraqi petroleum and petroleum products. The term Iraqi petroleum and petroleum products means any petroleum, petroleum products, or natural gas originating in Iraq...

Protein-based composites and biomaterials

USDA-ARS?s Scientific Manuscript database

World industrialization has generated substantial quantities of petroleum-based plastics over many years, which are not biodegradable or compostable, and are permanently residing on land, in landfills, or in the oceans, as environmental pollution. Recently, total or partially degradable materials ha...

Petroleum developments in Middle East countries in 1969

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mason, J.F.; Moore, Q.M.

1970-08-01

Petroleum production in Middle East countries in 1969 totaled 4,525,475,000 bbl at an average rate of 12,398,561 bpd, compared with 4,113,838,000 bbl or 11,239,995 bpd in 1968. The principal production increases were in Iran, Kuwait, Saudi Arabia, Abu Dhabi, and Oman. New fields were found in Iraq, Iran, and Abu Dhabi. There were no exploratory activities in Bahrain, Qatar, Sharjah, Ajman, Umm al Qawain, Dhofar, Hadhramaut, Aden-Kamaran islands, Yemen, or Lebanon. The main areas of exploratory work were in Iran, Iraq, Saudi Arabia-Red Sea, and the S. Gulf (both on shore and off shore). (67 refs.)

Method 1664: N-hexane extractable material (hem) and silica gel treated n-hexane extractable material (SGT-HEM) by extraction and gravimetry (oil and grease and total petroleum hydrocarbons), April 1995

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

Method 1664 was developed by the United States Environmental Protection Agency Office of Science and Technology to replace previously used gravimetric procedures that employed Freon-113, a Class I CFC, as the extraction solvent for the determination of oil and grease and petroleum hydrocarbons. Method 1664 is a performance-based method applicable to aqueous matrices that requires the use of n-hexane as the extraction solvent and gravimetry as the determinative technique. In addition, QC procedures designed to monitor precision and accuracy have been incorporated into Method 1664.

Sembar Goru/Ghazij Composite Total Petroleum System, Indus and Sulaiman-Kirthar Geologic Provinces, Pakistan and India

USGS Publications Warehouse

Wandrey, C.J.; Law, B.E.; Shah, Haider Ali

2004-01-01

Geochemical analyses of rock samples and produced oil and gas in the Indus Basin have shown that the bulk of the hydrocarbons produced in the Indus Basin are derived from the Lower Cretaceous Sembar Formation and equivalent rocks. The source rocks of the Sembar are composed of shales that were deposited in shallow marine environments, are of mixed type-II and type-III kerogen, with total organic carbon (TOC) content ranging from less than 0.5 percent to more than 3.5 percent; the average TOC of the Sembar is about 1.4 percent. Vitrinite reflectance (Ro) values range from immature (1.35 percent Ro). Thermal generation of hydrocarbons in the Sembar Formation began 65 to 40 million years ago, (Mya) during Paleocene to Oligocene time. Hydrocarbon expulsion, migration, and entrapment are interpreted to have occurred mainly 50 to 15 Mya, during Eocene to Miocene time, prior to and contemporaneously with the development of structural traps in Upper Cretaceous and Tertiary reservoirs. The principal reservoirs in the Sembar-Goru/Ghazij Composite Total Petroleum System are Upper Cretaceous through Eocene sandstones and limestones.

A Preliminary Estimate of Total Petroleum Hydrocarbons in Water and Some Commercially Important Fish Species in the Amba Estuary, West Coast of India.

PubMed

Nageswar Rao, M; Ram, Anirudh; Rokade, M A; Raja, P; Rakesh, P S; Chemburkar, Parul; Gajbhiye, S N

2016-07-01

Amba Estuary, which receives effluent from several industries including a petrochemical complex, opens to the southern limits of the Mumbai Harbor. The study was conducted to find out the level of Total Petroleum Hydrocarbons (TPHs) in water and their bioconcentration in ten commercially important fishes from Amba Estuary during different months. In water high concentration of TPHs (39.7 μg/L) was obtained during December (middle of estuary) and minimum value (7.2 μg/L) was observed in September (lower estuarine). The maximum concentration of TPHs was found to be in Trichiurus savala (3.2 µg/g) during December and minimum in Boleophthalmus sp (0.4 µg/g) during May. Irrespective of the monthly variations, TPHs accumulation in all the species was considerably lower than hazardous levels. Although there was no statistical significance between TPHs and total length/weight, the T. savala recording maximum concentration during all months and it can be used as indicator of hydrocarbon pollution in this region.

[Use of Leersia hexandra (Poaceae) for soil phytoremediation in soils contaminated with fresh and weathered oil].

PubMed

Arias-Trinidad, Alfredo; Rivera-Cruz, María del Carmen; Roldán-Garrigós, Antonio; Aceves-Navarro, Lorenzo Armando; Quintero-Lizaola, Roberto; Hernández-Guzmán, Javier

2017-03-01

The oil industry has generated chronic oil spills and their accumulation in wetlands of the state of Tabasco, in Southeastern Mexico. Waterlogging is a factor that limits the use of remediation technologies because of its high cost and low levels of oil degradation. However, Leersia hexandra is a grass that grows in these contaminated areas with weathered oil. The aim of the study was to evaluate the bacteria density, plant biomass production and phytoremediation of L. hexandra in contaminated soil. For this, two experiments in plastic tunnel were performed with fresh (E1) and weathered petroleum (E2) under waterlogging experimental conditions. The E1 was based on eight doses: 6 000, 10 000, 30 000, 60 000, 90 000, 120 000, 150 000 and 180 000 mg.kg-1 dry basis (d. b.) of total petroleum hydrocarbons fresh (TPH-F), and the E2, that evaluated five doses: 14 173, 28 400, 50 598, 75 492 and 112 142 mg. kg-1 d. b. of total petroleum hydrocarbons weathered (TPH-W); a control treatment with 2 607 mg.kg-1 d. b. was used. Each experiment, with eight replicates per treatment, evaluated after three and six months: a) microbial density of total free-living nitrogen-fixing bacteria (NFB) of Azospirillum (AZP) and Azotobacter group (AZT), for viable count in serial plate; b) dry matter production (DMP), quantified gravimetrically as dry weight of L. hexandra; and c) the decontamination percentage of hydrocarbons (PDH) by Soxhlet extraction. In soil with TPH-F, the NFB, AZP y AZT populations were stimulated five times more than the control both at the three and six months; however, concentrations of 150 000 and 180 000 mg.kg-1 d. b. inhibited the bacterial density between 70 and 89 %. Likewise, in soil with TPH-W, the FNB, AZP and AZT inhibitions were 90 %, with the exception of the 14 173 mg.kg-1 d. b. treatment, which stimulated the NFB and AZT in 2 and 0.10 times more than the control, respectively. The DMP was continued at the six months in the experiments, with values of 63 and 89 g in fresh and weathered petroleum, respectively; had no significant differences with the control (p≤0.05). The PDH reached values of 66 to 87 % both TPH-F and TPH-W at six months, respectively. These results demonstrated the ability the L. hexandra rhizosphere to stimulate the high NFB density, vegetal biomass production and phytoremediation of contaminated soils (with fresh and weathered petroleum), in a tropical waterlogging environment.

Strategic petroleum reserve: reprogramming of funds. Hearing before the Subcommittee on Energy and Power of the Committee on Interstate and Foreign Commerce, House of Representatives, Ninety-Fifth Congress, Second Session, December 18, 1978

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1979-01-01

The Subcommittee on Energy and Power met December 18, 1978 to investigate the cost overrun of the strategic petroleum reserve. More particularly, the subject is the candor of the DOE officials in Washington who run the strategic petroleum reserve program and how they deal with Congress and particularly with the subcommittee. In May 1977, the subcommittee was told that the total cost of putting 500 million barrels in storage would be $835 million. In May of 1978, Secretary Schlesinger also advised Congress that the DOE intended to double the size of the reserve. The committee also heard testimony on themore » correct information on the filling schedule. Many representatives from DOE presented statements and Ernest A. Fitzgerald from the Department of Defense presented a statement. Additional material was submitted for the record by DOE. (MCW)« less

Optimization of the omega-3 extraction as a functional food from flaxseed.

PubMed

Hassan-Zadeh, A; Sahari, M A; Barzegar, M

2008-09-01

The fatty acid content, total lipid, refractive index, peroxide, iodine, acid and saponification values of Iranian linseed oil (Linum usitatissimum) were studied. For optimization of extraction conditions, this oil was extracted by solvents (petroleum benzene and methanol-water-petroleum benzene) in 1:2, 1:3 and 1:4 ratios at 2, 5 and 8 h. Then its fatty acid content, omega-3 content and extraction yield were determined. According to the statistical analysis, petroleum benzene in a ratio of 1:3 at 5 h was chosen for the higher fatty acid, extraction yield, and economical feasibility. For preservation of omega-3 ingredients, oil with specified characters containing 46.8% omega-3 was kept under a nitrogen atmosphere at -30 degrees C during 0, 7, 30, 60 and 90 days and its peroxide value was determined. Statistical analysis showed a significant difference in the average amount of peroxide value only on the first 7 days of storage, and its increase (8.30%) conformed to the international standard.

Assessment of Appalachian basin oil and gas resources: Carboniferous Coal-bed Gas Total Petroleum System: Chapter G.1 in Coal and petroleum resources in the Appalachian basin: distribution, geologic framework, and geochemical character

USGS Publications Warehouse

Milici, Robert C.; Ruppert, Leslie F.; Ryder, Robert T.

2014-01-01

Trap formation began with the deposition of the peat deposits during the Mississippian and continued into the Late Pennsylvanian and Permian, when strata of the Appalachian Plateaus were deformed during the Alleghanian orogeny. The seals are the connate waters that occupy fractures and larger pore spaces within the coal beds, as well as the fine-grained, siliciclastic sedimentary strata that are intercalated with the coal. The critical moment for the petroleum system occurred during the Alleghanian orogeny, when deformation resulted in the geologic structures in the eastern part of the Appalachian basin that enhanced fracture porosity within the coal beds. In places, burial by thrust sheets (thrust loading) in the Valley and Ridge physiographic province may have resulted in the additional generation of thermogenic coalbed methane in the Pennsylvania Anthracite region and in the semianthracite deposits of Virginia and West Virginia, although other explanations have been offered.

Evaluation of undiscovered natural gas in the Upper Cretaceous Ferron Coal/Wasatch Plateau Total Petroleum System, Wasatch Plateau and Castle Valley, Utah

USGS Publications Warehouse

Henry, M.E.; Finn, T.M.

2003-01-01

The Total Petroleum System approach was used to estimate undiscovered gas potential of the Wasatch Plateau and Castle Valley, central Utah. The Ferron Coal/Wasatch Plateau Total Petroleum System was geologically defined and subdivided into seven assessment units, six of which were formally evaluated. Geologic data considered in defining the assessment unit boundaries included thermal maturity, coal presence and thickness, overburden thickness, and faulting intensity. Historical production data were also used to estimate volumes of gas from undrilled areas. The one conventional assessment unit includes almost the entire area of the petroleum system and is characterized by known accumulations that occur in structural or combination traps in sandstone reservoirs. The estimated undiscovered conventional producible gas that may be added to reserves of this unit ranges from a low (F95) of 14.8 billion cubic feet (BCFG) [419 million cubic meters (Mm3)] of gas to a high (F5) of 82 BCFG [2321 Mm3] and a mean value of 39.9 BCFG [1130 Mm3]. Continuous gas accumulations are those in which the entire assessment unit is considered to be gas-charged. Within these assessment units, there may be wells drilled that are not economic successes but all are expected to contain gas. Coalbed gas is in this continuous category. Mean estimates of undiscovered gas for the five continuous assessment units are: (1) Northern Coal Fairway/Drunkards Wash-752.3 BCFG [21,323 Mm3]; (2) Central Coal Fairway/Buzzard Bench-536.7 BCFG [15,194 Mm3]; (3) Southern Coal Fairway-152.6 BCFG [4320 Mm3]; (4) Deep (6000 feet plus) Coal and Sandstone-59.1 BCFG [1673 Mm3]; (5) Southern Coal Outcrop-10.6 BCFG [300 Mm3]; and Joes Valley and Musinia Grabens-not assessed.The mean estimate of undiscovered gas for the entire TPS is 1551.2 BCFG [43,914 Mm3]. There is a 95% chance that at least 855.7 BCFG [24,225 Mm3] and a 5% chance that at least 2504 BCFG [70,888 Mm3] of undiscovered producible gas remain in the TPS. ?? 2003 Published by Elsevier B.V.

Petroleum systems of the San Joaquin Basin Province -- geochemical characteristics of gas types: Chapter 10 in Petroleum systems and geologic assessment of oil and gas in the San Joaquin Basin Province, California

USGS Publications Warehouse

Lillis, Paul G.; Warden, Augusta; Claypool, George E.; Magoon, Leslie B.

2008-01-01

The San Joaquin Basin Province is a petroliferous basin filled with predominantly Late Cretaceous to Pliocene-aged sediments, with organic-rich marine rocks of Late Cretaceous, Eocene, and Miocene age providing the source of most of the oil and gas. Previous geochemical studies have focused on the origin of the oil in the province, but the origin of the natural gas has received little attention. To identify and characterize natural gas types in the San Joaquin Basin, 66 gas samples were analyzed and combined with analyses of 15 gas samples from previous studies. For the purpose of this resource assessment, each gas type was assigned to the most likely petroleum system. Three general gas types are identified on the basis of bulk and stable carbon isotopic composition—thermogenic dry (TD), thermogenic wet (TW) and biogenic (B). The thermogenic gas types are further subdivided on the basis of the δ13C values of methane and ethane and nitrogen content into TD-1, TD-2, TD-Mixed, TW-1, TW-2, and TW-Mixed. Gas types TD-1 and TD-Mixed, a mixture of biogenic and TD-1 gases, are produced from gas fields in the northern San Joaquin Basin. Type TD-1 gas most likely originated from the Late Cretaceous to Paleocene Moreno Formation, a gas-prone source rock. The biogenic component of the TD-Mixed gas existed in the trap prior to the influx of thermogenic gas. For the assessment, these gas types were assigned to the Winters- Domengine Total Petroleum System, but subsequent to the assessment were reclassified as part of the Moreno-Nortonville gas system. Dry thermogenic gas produced from oil fields in the southern San Joaquin Basin (TD-2 gas) most likely originated from the oil-prone source rock of Miocene age. These samples have low wetness values due to migration fractionation or biodegradation. The thermogenic wet gas types (TW-1, TW-2, TW-Mixed) are predominantly associated gas produced from oil fields in the southern and central San Joaquin Basin. Type TW-1 gas most likely originates from source rocks within the Eocene Kreyenhagen Formation or the Eocene Tumey formation of Atwill (1935). Type TW-2 gas most likely originates from the Miocene Monterey Formation and equivalents. TW-Mixed gas is likely a mixture of biogenic and wet thermogenic gas (TW-1 or TW-2) derived from source rocks mentioned above. The thermogenic wet gas types are included in the corresponding Eocene or Miocene total petroleum systems. Type B gas is a dry, nonassociated gas produced from the Pliocene San Joaquin Formation in the central and southern San Joaquin Basin. This gas type most likely originated from Pliocene marine source rocks as a product of methanogenesis, and defines the Neogene Nonassociated Gas Total Petroleum System.

Hydro and geothermal electricity as an alternative for industrial petroleum consumption in Costa Rica

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mendis, M.; Park, W.; Sabadell, A.

This report assesses the potential for substitution of electricity for petroleum in the industrial/agro-industrial sector of Costa Rica. The study includes a preliminary estimate of the process energy needs in this sector, a survey of the principal petroleum consuming industries in Costa Rica, an assessment of the electrical technologies appropriate for substitution, and an analysis of the cost trade offs of alternative fuels and technologies. The report summarizes the total substitution potential both by technical feasibility and by cost effectiveness under varying fuel price scenarios and identifies major institutional constraints to the introduction of electric based technologies. Recommendations to themore » Government of Costa Rica are presented. The key to the success of a Costa Rican program for substitution of electricity for petroleum in industry rests in energy pricing policy. The report shows that if Costa Rica Bunker C prices are increased to compare equitably with Caribbean Bunker C prices, and increase at 3 percent per annum relative to a special industrial electricity rate structure, the entire substitution program, including both industrial and national electric investment, would be cost effective. The definition of these pricing structures and their potential impacts need to be assessed in depth.« less

Phytoremediation of petroleum hydrocarbon-contaminated saline-alkali soil by wild ornamental Iridaceae species.

PubMed

Cheng, Lijuan; Wang, Yanan; Cai, Zhang; Liu, Jie; Yu, Binbin; Zhou, Qixing

2017-03-04

As a green remediation technology, phytoremediation is becoming one of the most promising methods for treating petroleum hydrocarbons (PHCs)-contaminated soil. Pot culture experiments were conducted in this study to investigate phytoremediation potential of two representative Iridaceae species (Iris dichotoma Pall. and Iris lactea Pall.) in remediation of petroleum hydrocarbon-contaminated saline-alkali soil from the Dagang Oilfield in Tianjin, China. The results showed that I. lactea was more endurable to extremely high concentration of PHCs (about 40,000 mg/kg), with a relatively high degradation rate of 20.68%.The degradation rate of total petroleum hydrocarbons (TPHs) in soils contaminated with 10,000 and 20,000 mg/kg of PHCs was 30.79% and 19.36% by I. dichotoma, and 25.02% and 19.35% by I. lactea, respectively, which improved by 10-60% than the unplanted controls. The presence of I. dichotoma and I. lactea promoted degradation of PHCs fractions, among which saturates were more biodegradable than aromatics. Adaptive specialization was observed within the bacterial community. In conclusion, phytoremediation by I. dichotoma should be limited to soils contaminated with ≤20,000 mg/kg of PHCs, while I. lactea could be effectively applied to phytoremediation of contaminated soils by PHCs with at least 40,000 mg/kg.

Characteristics of petroleum-contaminated groundwater during natural attenuation: a case study in northeast China.

PubMed

Qian, Hong; Zhang, Yuling; Wang, Jiali; Si, Chaoqun; Chen, Zaixing

2018-01-13

The objective of this study was to investigate a petroleum-contaminated groundwater site in northeast China. We determined the physicochemical properties of groundwater that contained total petroleum hydrocarbons (TPH) with a view to developing a scientifically robust strategy for controlling and remediating pollution of groundwater already contaminated with petroleum. Samples were collected at regular intervals and were analyzed for dissolved oxygen (DO), iron (Fe 3+ ), sulfate (SO 4 2- ), electrical conductivity (Eh), pH, hydrogen carbonate (HCO 3 - ), and enzyme activities of catalase (CAT), peroxidase (HRP), catechol 1,2-dioxygenase (C12O), and catechol 2,3-dioxygenase (C23O). We used factor analysis in SPSS to determine the main environmental characteristics of the groundwater samples. The results confirmed that the study site was slightly contaminated and that TPH levels were decreasing slightly. Some of the physicochemical variables showed regular fluctuations; DO, Fe 3+ , and SO 4 2- contents decreased gradually, while the concentrations of one of the microbial degradation products, HCO 3 - , increased. Microorganism enzyme activities decreased gradually. The microbiological community deteriorated noticeably during the natural attenuation process, so microbiological degradation of pollutants receded gradually. The HCO 3 - content increased and the pH and Eh decreased gradually. The groundwater environment tended to be reducing.

Potential for Electrified Vehicles to Contribute to U.S. Petroleum and Climate Goals and Implications for Advanced Biofuels.

PubMed

Meier, Paul J; Cronin, Keith R; Frost, Ethan A; Runge, Troy M; Dale, Bruce E; Reinemann, Douglas J; Detlor, Jennifer

2015-07-21

To examine the national fuel and emissions impacts from increasingly electrified light-duty transportation, we reconstructed the vehicle technology portfolios from two national vehicle studies. Using these vehicle portfolios, we normalized assumptions and examined sensitivity around the rates of electrified vehicle penetration, travel demand growth, and electricity decarbonization. We further examined the impact of substituting low-carbon advanced cellulosic biofuels in place of petroleum. Twenty-seven scenarios were benchmarked against a 50% petroleum-reduction target and an 80% GHG-reduction target. We found that with high rates of electrification (40% of miles traveled) the petroleum-reduction benchmark could be satisfied, even with high travel demand growth. The same highly electrified scenarios, however, could not satisfy 80% GHG-reduction targets, even assuming 80% decarbonized electricity and no growth in travel demand. Regardless of precise consumer vehicle preferences, emissions are a function of the total reliance on electricity versus liquid fuels and the corresponding greenhouse gas intensities of both. We found that at a relatively high rate of electrification (40% of miles and 26% by fuel), an 80% GHG reduction could only be achieved with significant quantities of low-carbon liquid fuel in cases with low or moderate travel demand growth.

Potential of vetiver (vetiveria zizanioides (L.) Nash) for phytoremediation of petroleum hydrocarbon-contaminated soils in Venezuela.

PubMed

Brandt, Regine; Merkl, Nicole; Schultze-Kraft, Rainer; Infante, Carmen; Broll, Gabriele

2006-01-01

Venezuela is one of the largest oil producers in the world. For the rehabilitation of oil-contaminated sites, phytoremediation represents a promising technology whereby plants are used to enhance biodegradation processes in soil. A greenhouse study was conducted to determine the tolerance of vetiver (Vetiveria zizanioides (L.) Nash) to a Venezuelan heavy crude oil in soil. Additionally, the plant's potential for stimulating the biodegradation processes of petroleum hydrocarbons was tested under the application of two fertilizer levels. In the presence of contaminants, biomass and plant height were significantly reduced. As for fertilization, the lower fertilizer level led to higher biomass production. The specific root surface area was reduced under the effects of petroleum. However, vetiver was found to tolerate crude-oil contamination in a concentration of 5% (w/w). Concerning total oil and grease content in soil, no significant decrease under the influence of vetiver was detected when compared to the unplanted control. Thus, there was no evidence of vetiver enhancing the biodegradation of crude oil in soil under the conditions of this trial. However, uses of vetiver grass in relation to petroleum-contaminated soils are promising for amelioration of slightly polluted sites, to allow other species to get established and for erosion control.

Effect of Piriformospora indica inoculation on root development and distribution of maize (Zea mays L.) in the presence of petroleum contaminated soil

NASA Astrophysics Data System (ADS)

Zamani, Javad; Hajabbasi, Mohammad Ali; Alaie, Ebrahim

2014-05-01

The root systems of most terrestrial plants are confronted to various abiotic and biotic stresses. One of these abiotic stresses is contamination of soil with petroleum hydrocarbon, which the efficiency of phytoremediation of petroleum hydrocarbons in soils is dependent on the ability of plant roots to development into the contaminated soils. Piriformospora indica represents a recently discovered fungus that transfers considerable beneficial impact to its host plants. A rhizotron experiment was conducted to study the effects of P. Indica inoculation on root distribution and root and shoot development of maize (Zea mays L.) in the presence of three patterns of petroleum contamination in the soil (subsurface contamination, continuous contamination and without contamination (control)). Root distribution and root and shoot development were monitored over time. The final root and shoot biomass and the final TPH concentration in the rhizosphere were determined. Analysis of digitized images which were prepared of the tracing of the appeared roots along the front rhizotrons showed the depth and total length of root network in the contamination treatments were significantly decreased. Although the degradation of TPH in the rhizosphere of maize was significant, but there were no significant differences between degradation of TPH in the rhizosphere of +P. indica plants in comparison to -P. indica plants.

QATAR offshore oil

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

The Qatar Petroleum Producing Authority is presently operating three offshore fields - Idd al-Shargi, Maydan Mahzam and Bul Hanine. The Idd al-Shargi field consists of 14 naturally flowing wells and three suspended wells. Individual flow rates of the producing wells range from 250 to 3000 barrels per day (b/d). The Maydan Mahzam field produces from 11 naturally flowing wells. Reservoir energy in the field is maintained by water injection. Each of the wells produce oil at rates ranging from 2500 to 20,000 b/d. The Bul Hanine field comprises 10 producing wells supported by 9 dumpflooders. Production rates of the individualmore » wells reach 29,000 b/d, making them among the world's highest. In 1978 the completion of a major acceleration project for the Bul Hanine Arab IV reservoir added more than 40,000 b/d to the production potential of the field. Total Qatari oil exports in 1978 were 91,708,000 barrels, equivalent to an average export rate of 25,000 b/d. Total production in Qatar in 1979 was 100,641,394 barrels (offshore) and 84,130,917 (onshore), an increase of 11% and a decrease of 3%, respectively, over 1978. Halal Island provides offshore storage for oil and gas berthing and loading operations. A natural gas liquids offshore complex, including a fractionation plant, is nearing completion at Umm Said. (SAC)« less

CHARACTERISTICS OF NON-PETROLEUM UNDERGROUND STORAGE TANKS

EPA Science Inventory

It is generally acknowledged that a small fraction of the total underground storage tank population is used to store chemicals. The detailed characteristics of these tanks, however, are not well understood. Additional information is required if competent decisions are to be made ...

14 CFR 152.605 - Definitions.

Code of Federal Regulations, 2010 CFR

2010-01-01

... subpart— Building construction means construction of any building which receives Federal assistance under... total energy requirements of a building, which, within the scope of the proposed construction activity...— (1) Consideration of opportunities for using fuels other than petroleum and natural gas, and (2...

Large scale treatment of total petroleum-hydrocarbon contaminated groundwater using bioaugmentation.

PubMed

Poi, Gregory; Shahsavari, Esmaeil; Aburto-Medina, Arturo; Mok, Puah Chum; Ball, Andrew S

2018-05-15

Bioaugmentation or the addition of microbes to contaminated sites has been widely used to treat contaminated soil or water; however this approach is often limited to laboratory based studies. In the present study, large scale bioaugmentation has been applied to total petroleum hydrocarbons (TPH)-contaminated groundwater at a petroleum facility. Initial TPH concentrations of 1564 mg L -1 in the field were reduced to 89 mg L -1 over 32 days. This reduction was accompanied by improved ecotoxicity, as shown by Brassica rapa germination numbers that increased from 52 at day 0 to 82% by the end of the treatment. Metagenomic analysis indicated that there was a shift in the microbial community when compared to the beginning of the treatment. The microbial community was dominated by Proteobacteria and Bacteroidetes from day 0 to day 32, although differences at the genus level were observed. The predominant genera at the beginning of the treatment (day 0 just after inoculation) were Cloacibacterium, Sediminibacterium and Brevundimonas while at the end of the treatment members of Flavobacterium dominated, reaching almost half the population (41%), followed by Pseudomonas (6%) and Limnobacter (5.8%). To the author's knowledge, this is among the first studies to report the successful large scale biodegradation of TPH-contaminated groundwater (18,000 L per treatment session) at an offshore petrochemical facility. Copyright © 2018 Elsevier Ltd. All rights reserved.

Total to withdraw from Qatar methanol - MTBE?

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

Total is rumored to be withdrawing from the $700-million methanol and methyl tert-butyl ether (MTBE) Qatar Fuel Additives Co., (Qafac) project. The French company has a 12.5% stake in the project. Similar equity is held by three other foreign investors: Canada`s International Octane, Taiwan`s Chinese Petroleum Corp., and Lee Change Yung Chemical Industrial Corp. Total is said to want Qafac to concentrate on methanol only. The project involves plant unit sizes of 610,000 m.t./year of MTBE and 825,000 m.t./year of methanol. Total declines to comment.

The New Albany Shale Petroleum System, Illinois Basin - Data and Map Image Archive from the Material-Balance Assessment

USGS Publications Warehouse

Higley, Debra K.; Henry, M.E.; Lewan, M.D.; Pitman, Janet K.

2003-01-01

The data files and explanations presented in this report were used to generate published material-balance approach estimates of amounts of petroleum 1) expelled from a source rock, and the sum of 2) petroleum discovered in-place plus that lost due to 3) secondary migration within, or leakage or erosion from a petroleum system. This study includes assessment of cumulative production, known petroleum volume, and original oil in place for hydrocarbons that were generated from the New Albany Shale source rocks.More than 4.00 billion barrels of oil (BBO) have been produced from Pennsylvanian-, Mississippian-, Devonian-, and Silurian-age reservoirs in the New Albany Shale petroleum system. Known petroleum volume is 4.16 BBO; the average recovery factor is 103.9% of the current cumulative production. Known petroleum volume of oil is 36.22% of the total original oil in place of 11.45 BBO. More than 140.4 BBO have been generated from the Upper Devonian and Lower Mississippian New Albany Shale in the Illinois Basin. Approximately 86.29 billion barrels of oil that was trapped south of the Cottage Grove fault system were lost by erosion of reservoir intervals. The remaining 54.15 BBO are 21% of the hydrocarbons that were generated in the basin and are accounted for using production data. Included in this publication are 2D maps that show the distribution of production for different formations versus the Rock-Eval pyrolysis hydrogen-indices (HI) contours, and 3D images that show the close association between burial depth and HI values.The primary vertical migration pathway of oil and gas was through faults and fractures into overlying reservoir strata. About 66% of the produced oil is located within the generative basin, which is outlined by an HI contour of 400. The remaining production is concentrated within 30 miles (50 km) outside the 400 HI contour. The generative basin is subdivided by contours of progressively lower hydrogen indices that represent increased levels of thermal maturity and generative capacity of New Albany Shale source rocks. The generative basin was also divided into seven oil-migration catchments. The catchments were determined using a surface-flow hydrologic model with contoured HI values as input to the model.

Comparison of methods used to estimate conventional undiscovered petroleum resources: World examples

USGS Publications Warehouse

Ahlbrandt, T.S.; Klett, T.R.

2005-01-01

Various methods for assessing undiscovered oil, natural gas, and natural gas liquid resources were compared in support of the USGS World Petroleum Assessment 2000. Discovery process, linear fractal, parabolic fractal, engineering estimates, PETRIMES, Delphi, and the USGS 2000 methods were compared. Three comparisons of these methods were made in: (1) the Neuquen Basin province, Argentina (different assessors, same input data); (2) provinces in North Africa, Oman, and Yemen (same assessors, different methods); and (3) the Arabian Peninsula, Arabian (Persian) Gulf, and North Sea (different assessors, different methods). A fourth comparison (same assessors, same assessment methods but different geologic models), between results from structural and stratigraphic assessment units in the North Sea used only the USGS 2000 method, and hence compared the type of assessment unit rather than the method. In comparing methods, differences arise from inherent differences in assumptions regarding: (1) the underlying distribution of the parent field population (all fields, discovered and undiscovered), (2) the population of fields being estimated; that is, the entire parent distribution or the undiscovered resource distribution, (3) inclusion or exclusion of large outlier fields; (4) inclusion or exclusion of field (reserve) growth, (5) deterministic or probabilistic models, (6) data requirements, and (7) scale and time frame of the assessment. Discovery process, Delphi subjective consensus, and the USGS 2000 method yield comparable results because similar procedures are employed. In mature areas such as the Neuquen Basin province in Argentina, the linear and parabolic fractal and engineering methods were conservative compared to the other five methods and relative to new reserve additions there since 1995. The PETRIMES method gave the most optimistic estimates in the Neuquen Basin. In less mature areas, the linear fractal method yielded larger estimates relative to other methods. A geologically based model, such as one using the total petroleum system approach, is preferred in that it combines the elements of petroleum source, reservoir, trap and seal with the tectono-stratigraphic history of basin evolution with petroleum resource potential. Care must be taken to demonstrate that homogeneous populations in terms of geology, geologic risk, exploration, and discovery processes are used in the assessment process. The USGS 2000 method (7th Approximation Model, EMC computational program) is robust; that is, it can be used in both mature and immature areas, and provides comparable results when using different geologic models (e.g. stratigraphic or structural) with differing amounts of subdivisions, assessment units, within the total petroleum system. ?? 2005 International Association for Mathematical Geology.

Interfacial sciences in unconventional petroleum production: from fundamentals to applications.

PubMed

He, Lin; Lin, Feng; Li, Xingang; Sui, Hong; Xu, Zhenghe

2015-08-07

With the ever increasing demand for energy to meet the needs of growth in population and improvement in the living standards in particular in developing countries, the abundant unconventional oil reserves (about 70% of total world oil), such as heavy oil, oil/tar sands and shale oil, are playing an increasingly important role in securing global energy supply. Compared with the conventional reserves unconventional oil reserves are characterized by extremely high viscosity and density, combined with complex chemistry. As a result, petroleum production from unconventional oil reserves is much more difficult and costly with more serious environmental impacts. As a key underpinning science, understanding the interfacial phenomena involved in unconventional petroleum production, such as oil liberation from host rocks, oil-water emulsions and demulsification, is critical for developing novel processes to improve oil production while reducing GHG emission and other environmental impacts at a lower operating cost. In the past decade, significant efforts and advances have been made in applying the principles of interfacial sciences to better understand complex unconventional oil-systems, while many environmental and production challenges remain. In this critical review, the recent research findings and progress in the interfacial sciences related to unconventional petroleum production are critically reviewed. In particular, the chemistry of unconventional oils, liberation mechanisms of oil from host rocks and mechanisms of emulsion stability and destabilization in unconventional oil production systems are discussed in detail. This review also seeks to summarize the current state-of-the-art characterization techniques and brings forward the challenges and opportunities for future research in this important field of physical chemistry and petroleum.

Application of electrochemical technology for removing petroleum hydrocarbons from produced water using lead dioxide and boron-doped diamond electrodes.

PubMed

Gargouri, Boutheina; Gargouri, Olfa Dridi; Gargouri, Bochra; Trabelsi, Souhel Kallel; Abdelhedi, Ridha; Bouaziz, Mohamed

2014-12-01

Although diverse methods exist for treating polluted water, the most promising and innovating technology is the electrochemical remediation process. This paper presents the anodic oxidation of real produced water (PW), generated by the petroleum exploration of the Petrobras plant-Tunisia. Experiments were conducted at different current densities (30, 50 and 100 mA cm(-2)) using the lead dioxide supported on tantalum (Ta/PbO2) and boron-doped diamond (BDD) anodes in an electrolytic batch cell. The electrolytic process was monitored by the chemical oxygen demand (COD) and the residual total petroleum hydrocarbon [TPH] in order to know the feasibility of electrochemical treatment. The characterization and quantification of petroleum wastewater components were performed by gas chromatography mass spectrometry. The COD removal was approximately 85% and 96% using PbO2 and BDD reached after 11 and 7h, respectively. Compared with PbO2, the BDD anode showed a better performance to remove petroleum hydrocarbons compounds from produced water. It provided a higher oxidation rate and it consumed lower energy. However, the energy consumption and process time make useless anodic oxidation for the complete elimination of pollutants from PW. Cytotoxicity has shown that electrochemical oxidation using BDD could be efficiently used to reduce more than 90% of hydrocarbons compounds. All results suggest that electrochemical oxidation could be an effective approach to treat highly concentrated organic pollutants present in the industrial petrochemical wastewater and significantly reduce the cost and time of treatment. Copyright © 2014 Elsevier Ltd. All rights reserved.

40 CFR 70.2 - Definitions.

Code of Federal Regulations, 2012 CFR

2012-07-01

...: (i) Coal cleaning plants (with thermal dryers); (ii) Kraft pulp mills; (iii) Portland cement plants... plants; (xii) Phosphate rock processing plants; (xiii) Coke oven batteries; (xiv) Sulfur recovery plants...) totaling more than 250 million British thermal units per hour heat input; (xxii) Petroleum storage and...

40 CFR 71.2 - Definitions.

Code of Federal Regulations, 2012 CFR

2012-07-01

...: (i) Coal cleaning plants (with thermal dryers); (ii) Kraft pulp mills; (iii) Portland cement plants... plants; (xii) Phosphate rock processing plants; (xiii) Coke oven batteries; (xiv) Sulfur recovery plants...) totaling more than 250 million British thermal units per hour heat input; (xxii) Petroleum storage and...

The response of maize (Zea mays L.) plant assisted with bacterial consortium and fertilizer under oily sludge.

PubMed

Shahzad, Asim; Saddiqui, Samina; Bano, Asghari

2016-01-01

The objective of this study was to evaluate the role of PGPR consortium and fertilizer alone and in combination on the physiology of maize grown under oily sludge stress environment as well on the soil nutrient status. Consortium was prepared from Bacillus cereus (Acc KR232400), Bacillus altitudinis (Acc KF859970), Comamonas (Delftia) belonging to family Comamonadacea (Acc KF859971) and Stenotrophomonasmaltophilia (Acc KF859973). The experiment was conducted in pots with complete randomized design with four replicates and kept in field. Oily sludge was mixed in ml and Ammonium nitrate and Diammonium phosphate (DAP) were added at 70 ug/g and 7 ug/g at sowing. The plant was harvested at 21 d for estimation of protein, proline and antioxidant enzymes superoxide dismutase (SOD) and peroxidase (POD). To study the degradation, total petroleum hydrocarbon was extracted by soxhelt extraction and extract was analyzed by GC-FID at different period after incubation. Combined application of consortium and fertilizer enhanced the germination %, protein and, proline content by 90,130 and 99% higher than untreated maize plants. Bioavailability of macro and micro nutrient was also enhanced with consortium and fertilizer in oily sludge. The consortium and fertilizer in combined treatment decreased the superoxide dismutase (SOD), peroxidase dismutase (POD) of the maize leaves grown in oily sludge. Degradation of total petroleum hydrocarbon (TPHs) was 59% higher in combined application of consortium and fertilizer than untreated maize at 3 d. The bacterial consortium can enhanced the maize tolerance to oily sludge and enhanced degradation of total petroleum hydrocarbon (TPHs). The maize can be considered as tolerant plant species to remediate oily sludge contaminated soils.

Estimating usable resources from historical industry data

USGS Publications Warehouse

Cargill, S.M.; Root, D.H.; Bailey, E.H.

1981-01-01

Historical production statistics are used to predict the quantity of remaining usable resources. The commodities considered are mercury, copper and its byproducts gold and silver, and petroleum; the production and discovery data are for the United States. The results of the study indicate that the cumulative return per unit of effort, herein measured as grade of metal ores and discovery rate of recoverable petroleum, is proportional to a negative power of total effort expended, herein measured as total ore mined and total exploratory wells or footage drilled. This power relationship can be extended to some limiting point (a lower ore grade or a maximum number of exploratory wells or footage), and the apparent quantity of available remaining resource at that limit can be calculated. For mercury ore of grades at and above 0.1 percent, the remaining usable resource in the United States is calculated to be 54 million kg (1,567,000 flasks). For copper ore of grades at and above 0.2 percent, the remaining usable copper resource is calculated to be 270 million metric tons (298 million short tons); remaining resources of its by-products gold and silver are calculated to be 3,656 metric tons (118 million troy ounces) and 64,676 metric tons (2,079 million troy ounces), respectively. The undiscovered recoverable crude oil resource in the conterminous United States, at 3 billion feet of additional exploratory drilling, is calculated to be nearly 37.6 billion barrels; the undiscovered recoverable petroleum resource in the Permian basin of western Texas and southeastern New Mexico, at 300 million feet of additional exploratory drilling or 50,000 additional exploratory wells, is calculated to be about 6.2 billion BOE (barrels of oil equivalent).

Response of microbial community and catabolic genes to simulated petroleum hydrocarbon spills in soils/sediments from different geographic locations.

PubMed

Liu, Q; Tang, J; Liu, X; Song, B; Zhen, M; Ashbolt, N J

2017-10-01

Study the response of microbial communities and selected petroleum hydrocarbon (PH)-degrading genes on simulated PH spills in soils/sediments from different geographic locations. A microcosm experiment was conducted by spiking mixtures of petroleum hydrocarbons (PHs) to soils/sediments collected from four different regions of China, including the Dagang Oilfield (DG), Sand of Bohai Sea (SS), Northeast China (NE) and Xiamen (XM). Changes in bacterial community and the abundance of PH-degrading genes (alkB, nah and phe) were analysed by denaturing gradient electrophoresis (DGGE) and qPCR, respectively. Degradation of alkanes and PAHs in SS and NE materials were greater (P < 0·05) than those in DG and XM. Clay content was negatively correlated with the degradation of total alkanes by 112 days and PAHs by 56 days, while total organic carbon content was negatively correlated with initial degradation of total alkanes as well as PAHs. Abundances of alkB, nah and phe genes increased 10- to 100-fold and varied by soil type over the incubation period. DGGE fingerprints identified the dominance of α-, β- and γ-Proteobacteria (Gram -ve) and Actinobacteria (Gram +ve) bacteria associated with degradation of PHs in the materials studied. The geographic divergence resulting from the heterogeneity of physicochemical properties of soils/sediments appeared to influence the abundance of metabolic genes and community structure of microbes capable of degrading PHs. When developing practical in-situ bioremediation approaches for PHs contamination of soils/sediment, appropriate microbial community structures and the abundance of PH-degrading genes appear to be influenced by geographic location. © 2017 The Society for Applied Microbiology.

Geology, sequence stratigraphy, and oil and gas assessment of the Lewis Shale Total Petroleum System, San Juan Basin, New Mexico and Colorado: Chapter 5 in Total petroleum systems and geologic assessment of undiscovered oil and gas resources in the San Juan Basin Province, exclusive of Paleozoic rocks, New Mexico and Colorado

USGS Publications Warehouse

Dubiel, R.F.

2013-01-01

The Lewis Shale Total Petroleum System (TPS) in the San Juan Basin Province contains a continuous gas accumulation in three distinct stratigraphic units deposited in genetically related depositional environments: offshore-marine shales, mudstones, siltstones, and sandstones of the Lewis Shale, and marginal-marine shoreface sandstones and siltstones of both the La Ventana Tongue and the Chacra Tongue of the Cliff House Sandstone. The Lewis Shale was not a completion target in the San Juan Basin (SJB) in early drilling from about the 1950s through 1990. During that time, only 16 wells were completed in the Lewis from natural fracture systems encountered while drilling for deeper reservoir objectives. In 1991, existing wells that penetrated the Lewis Shale were re-entered by petroleum industry operators in order to fracture-stimulate the Lewis and to add Lewis gas production onto preexisting, and presumably often declining, Mesaverde Group production stratigraphically lower in the section. By 1997, approximately 101 Lewis completions had been made, both as re-entries into existing wells and as add-ons to Mesaverde production in new wells. Based on recent industry drilling and completion practices leading to successful gas production from the Lewis and because new geologic models indicate that the Lewis Shale contains both source rocks and reservoir rocks, the Lewis Shale TPS was defined and evaluated as part of this U.S. Geological Survey oil and gas assessment of the San Juan Basin. Gas in the Lewis Shale Total Petroleum System is produced from shoreface sandstones and siltstones in the La Ventana and Chacra Tongues and from distal facies of these prograding clastic units that extend into marine rocks of the Lewis Shale in the central part of the San Juan Basin. Reservoirs are in shoreface sandstone parasequences of the La Ventana and Chacra and their correlative distal parasequences in the Lewis Shale where both natural and artificially enhanced fractures produce gas. The Lewis Continuous Gas Assessment Unit (AU 50220261) is thought to be self-sourced from and self-sealed by marine shales and mudstones deposited within the Lewis Shale that enclose clastic parasequences in the La Ventana and Chacra Tongues. The gas resource is thought to be a continuous accumulation sourced from the Lewis Shale throughout the depositional basin. In the Lewis Continuous Gas Assessment Unit (AU 50220261), for continuous gas resources, there is an F95 of 8,315.22 billion cubic feet of gas (BCFG) and an F5 of 12,282.31 BCFG, with a mean value of 10,177.24 BCFG. There is an F95 of 18.08 million barrels of natural gas liquids (MMBNGL) and an F5 of 47.32 MMBNGL, with a mean of 30.53 MMBNGL.

Petroleum developments in Middle East countries in 1968

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mason, J.F.; Moore, Q.M.

1969-08-01

Petroleum production in Middle East countries in 1968 totaled 4,113,838,000 bbl at an average rate of 11,239,995 bpd. This compares with 3,679,506,000 bbl or 10,080,838 bpd in 1967. The principal production increases were in Iraq, Iran, Saudi Arabia, Abu Dhabi, and Oman. New fields were found in offshore Iran, offshore and onshore Saudi Arabia, and Turkey. There were no exploratory activities in Bahrain, Qatar, Sharjah-Ajman-Umm al Qawain, Dhofar, Hadhramaut, Aden-Kamaran Islands, Yemen, Lebanon, and Cyprus The main areas of exploratory work were in Iran, Saudi Arabia, Neutral Zone, and the S. Gulf (both on shore and off shore). (30 refs.)

Evaluation of the Total Petroleum Hydrocarbon Standard for Cleanup of Petroleum Contaminated Sites

DTIC Science & Technology

1993-09-01

100-500 20-100 Hawaii .05-1.7 10-21 1.4-7 Idaho 40-200 Illinois 11.705 0.005 Indiana X 20 Iowa 100 Kansas 100 1.4 XXX Kentucky 1 Louisiana X * * Maine...100 Hawaii 0.5-1.7 10-20 1.4-7 XXX Idaho 100 llinois 11.705 0.005 XXX Indiana X 20 Iowa 100 Kansas 100 1.4 XXX Kentucky XXX Louisiana X Maine X FIELD...Alaska X X Arizona X X Arkansas X X California X X X Colorado X X Connecticut (I) Delaware X X lorida X Georstia, X IX I Hawaii X X Idaho X X illinois X X

Driving an Industry: Medium and Heavy Duty Fuel Cell Electric Truck Component Sizing

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kast, James; Marcinkoski, Jason; Vijayagopal, Ram

Medium and heavy duty (MD and HD respectively) vehicles are responsible for 26 percent of the total U.S. transportation petroleum consumption [1]. Hydrogen fuel cells have demonstrated value as part of a portfolio of strategies for reducing petroleum use and emissions from MD and HD vehicles. [2] [3], but their performance and range capabilities, and associated component sizing remain less clear when compared to other powertrains. This paper examines the suitability of converting a representative sample of MD and HD diesel trucks into Fuel Cell Electric Trucks (FCETs), while ensuring the same truck performance, in terms of range, payload, acceleration,more » speed, gradeability and fuel economy.« less

The worldwide search for petroleum offshore; a status report for the quarter century, 1947-72

USGS Publications Warehouse

Berryhill, Henry L.

1974-01-01

At the end of 1972, offshore petroleum exploration was in progress on the submerged continental margins of 80 countries. Some 780 oil and gas fields had been discovered. Estimated worldwide volume of oil discovered offshore as of January 1, 1973, is 172.8 billion barrels of oil, or about 26 percent of the world total, and 168.4 trillion ft3 of natural gas. Present reserves of oil are 135.5 billion barrels, of which 70 percent is in the Persian Gulf. Some 90 percent of the oil discovered offshore has been found in 60 giant fields having reserves of 500 million or more barrels each.

31 CFR 576.206 - Protection granted to the Development Fund for Iraq, Iraqi Petroleum and Petroleum Products, and...

Code of Federal Regulations, 2011 CFR

2011-07-01

... Fund for Iraq, Iraqi Petroleum and Petroleum Products, and the Central Bank of Iraq. 576.206 Section... Prohibitions § 576.206 Protection granted to the Development Fund for Iraq, Iraqi Petroleum and Petroleum... petroleum and petroleum products, and interests therein, but only until title passes to the initial...

19 CFR 151.47 - Optional entry of net quantity of petroleum or petroleum products.

Code of Federal Regulations, 2011 CFR

2011-04-01

... 19 Customs Duties 2 2011-04-01 2011-04-01 false Optional entry of net quantity of petroleum or petroleum products. 151.47 Section 151.47 Customs Duties U.S. CUSTOMS AND BORDER PROTECTION, DEPARTMENT OF... Petroleum and Petroleum Products § 151.47 Optional entry of net quantity of petroleum or petroleum products...

19 CFR 151.47 - Optional entry of net quantity of petroleum or petroleum products.

Code of Federal Regulations, 2010 CFR

2010-04-01

... 19 Customs Duties 2 2010-04-01 2010-04-01 false Optional entry of net quantity of petroleum or petroleum products. 151.47 Section 151.47 Customs Duties U.S. CUSTOMS AND BORDER PROTECTION, DEPARTMENT OF... Petroleum and Petroleum Products § 151.47 Optional entry of net quantity of petroleum or petroleum products...

Biodegradation of spilled diesel fuel in agricultural soil: effect of humates, zeolite, and bioaugmentation.

PubMed

Kuráň, Pavel; Trögl, Josef; Nováková, Jana; Pilařová, Věra; Dáňová, Petra; Pavlorková, Jana; Kozler, Josef; Novák, František; Popelka, Jan

2014-01-01

Possible enhancement of biodegradation of petroleum hydrocarbons in agricultural soil after tank truck accident (~5000 mg/kg dry soil initial concentration) by bioaugmentation of diesel degrading Pseudomonas fluorescens strain and addition of abiotic additives (humates, zeolite) was studied in a 9-month pot experiment. The biodegradation process was followed by means of analytical parameters (hydrocarbon index expressed as content of C10-C40 aliphatic hydrocarbons, ratio pristane/C17, and total organic carbon content) and characterization of soil microbial community (content of phospholipid fatty acids (PLFA) as an indicator of living microbial biomass, respiration, and dehydrogenase activity). The concentration of petroleum hydrocarbons (C10-C40) was successfully reduced by ~60% in all 15 experiment variants. The bioaugmentation resulted in faster hydrocarbon elimination. On the contrary, the addition of humates and zeolite caused only a negligible increase in the degradation rate. These factors, however, affected significantly the amount of PLFA. The humates caused significantly faster increase of the total PLFA suggesting improvement of the soil microenvironment. Zeolite caused significantly slower increase of the total PLFA; nevertheless it aided in homogenization of the soil. Comparison of microbial activities and total PLFA revealed that only a small fraction of autochthonous microbes took part in the biodegradation which confirms that bioaugmentation was the most important treatment.

Impacts of petroleum production on ground and surface waters: Results from the Osage-Skiatook Petroleum Environmental Research A site, Osage County Oklahoma

USGS Publications Warehouse

Kharaka, Y.K.; Thordsen, J.J.; Kakouros, E.; Herkelrath, W.N.

2005-01-01

As part of a multidisciplinary group of about 20 scientists, we are investigating the transport, fate, natural attenuation, and ecosystem impacts of inorganic salts and organic compounds present in releases of produced water and associated hydrocarbons at the Osage-Skiatook Petroleum Environmental Research (OSPER) sites, located in Osage County, Oklahoma. Geochemical data collected from nearby oil wells show that the produced water source is a Na-Ca-Cl brine (???150,000 mg/L total dissolved solids [TDS]), with relatively high concentrations of Mg, Sr, and NH4, but low SO4 and H2S. Results from the depleted OSPER A site show that the salts continue to be removed from the soil and surficial rocks, but degraded oil persists on the contaminated surface. Eventually, the bulk of inorganic salts and dissolved organics in the brine will reach the adjacent Skiatook Lake, a 4250-ha (10,501-ac) potable water reservoir. Repeated sampling of 44 wells show a plume of high-salinity water (2000-30,000 mg/L TDS) at intermediate depths that intersects Skiatook Lake and extends beyond the visibly impacted areas. No liquid petroleum was observed in this plume, but organic acid anions, benzene, toluene, ethylbenzene, and xylene (BTEX), and other volatile organic carbon (VOC) are present. The chemical composition of released brine is modified by sorption, mineral precipitation and dissolution, evapotranspiration, volatilization, and bacterially mediated oxidation-reduction reactions, in addition to mixing with percolating precipitation water, lake water, and pristine groundwater. Results show that only minor amounts of salt are removed by runoff, supporting the conclusion that significant amounts of salts from produced water and petroleum releases still remain in the soils and rocks of the impacted area after more than 65 yr of natural attenuation. Copyright ?? 2005. The American Association of Petroleum Geologists/Division of Environmental Geosciences. All rights reserved.

Determination of microbial carbon sources and cycling during remediation of petroleum hydrocarbon impacted soil using natural abundance (14)C analysis of PLFA.

PubMed

Cowie, Benjamin R; Greenberg, Bruce M; Slater, Gregory F

2010-04-01

In a petroleum impacted land-farm soil in Sarnia, Ontario, compound-specific natural abundance radiocarbon analysis identified biodegradation by the soil microbial community as a major pathway for hydrocarbon removal in a novel remediation system. During remediation of contaminated soils by a plant growth promoting rhizobacteria enhanced phytoremediation system (PEPS), the measured Delta(14)C of phospholipid fatty acid (PLFA) biomarkers ranged from -793 per thousand to -897 per thousand, directly demonstrating microbial uptake and utilization of petroleum hydrocarbons (Delta(14)C(PHC) = -1000 per thousand). Isotopic mass balance indicated that more than 80% of microbial PLFA carbon was derived from petroleum hydrocarbons (PHC) and a maximum of 20% was obtained from metabolism of more modern carbon sources. These PLFA from the contaminated soils were the most (14)C-depleted biomarkers ever measured for an in situ environmental system, and this study demonstrated that the microbial community in this soil was subsisting primarily on petroleum hydrocarbons. In contrast, the microbial community in a nearby uncontaminated control soil maintained a more modern Delta(14)C signature than total organic carbon (Delta(14)C(PLFA) = +36 per thousand to -147 per thousand, Delta(14)C(TOC) = -148 per thousand), indicating preferential consumption of the most modern plant-derived fraction of soil organic carbon. Measurements of delta(13)C and Delta(14)C of soil CO(2) additionally demonstrated that mineralization of PHC contributed to soil CO(2) at the contaminated site. The CO(2) in the uncontaminated control soil exhibited substantially more modern Delta(14)C values, and lower soil CO(2) concentrations than the contaminated soils, suggesting increased rates of soil respiration in the contaminated soils. In combination, these results demonstrated that biodegradation in the soil microbial community was a primary pathway of petroleum hydrocarbon removal in the PEPS system. This study highlights the power of natural abundance radiocarbon for determining microbial carbon sources and identifying biodegradation pathways in complex remediation systems.

Hydrocarbon seeps in petroliferous basins in China: A first inventory

NASA Astrophysics Data System (ADS)

Zheng, Guodong; Xu, Wang; Etiope, Giuseppe; Ma, Xiangxian; Liang, Shouyun; Fan, Qiaohui; Sajjad, Wasim; Li, Yang

2018-01-01

Natural hydrocarbon seepage is a widespread phenomenon in sedimentary basins, with important implications in petroleum exploration and emission of greenhouse gases to the atmosphere. China has vast petroleum (oil and gas) bearing sedimentary basins, but hydrocarbon seepage has rarely been the object of systematic studies and measurements. Based on the available Chinese literature, we report a first inventory of 932 hydrocarbon seeps or seepage zones (710 onshore seeps and 222 offshore seeps), including 81 mud volcanoes, 449 oil seeps, 215 gas seeps, and 187 solid seeps (bitumen outcrops). The seeps are located within the main 20 Mesozoic-Cenozoic petroliferous sedimentary basins, especially along the marginal, regional and local faults. The type of manifestations (oil, gas or mud volcano) reflects the type and maturity of the subsurface petroleum system and the sedimentary conditions of the basin. Oil seeps are particularly abundant in the Junggar Basin. Gas seeps mostly developed in the Lunpola Basin, in smaller basins of the eastern Guizhou and Yunnan provinces, onshore Taiwan and in the offshore Yinggehai Basin. Mud volcanoes developed in basins (Junggar, Qaidam, Qiangtang, onshore and offshore Taiwan) that experienced rapid sedimentation, which induced gravitative instability of shales and diapirism. In comparison to available global onshore seep data-bases, China results to be the country with the highest number of seeps in the world. The massive gas seepage in China could represent a considerable natural source of methane to the atmosphere, and a key process that may drive future hydrocarbon exploration.

The toxicological properties of petroleum gases.

PubMed

McKee, Richard H; Herron, Deborah; Saperstein, Mark; Podhasky, Paula; Hoffman, Gary M; Roberts, Linda

2014-01-01

To characterize the toxicological hazards of petroleum gases, 90-day inhalation toxicity (Organization for Economic Cooperation and Development [OECD] 413) and developmental toxicity (OECD 414) tests were conducted with liquefied propane gas (LPG) at concentrations of 1000, 5000, or 10,000 ppm. A micronucleus test (OECD 474) of LPG was also conducted. No systemic or developmental effects were observed; the overall no observed adverse effect concentration (NOAEC) was 10,000 ppm. Further, there was no effect of LPG exposure at levels up to 10,000 ppm on micronucleus induction and no evidence of bone marrow toxicity. Other alkane gases (ethane, propane, n-butane, and isobutane) were then evaluated in combined repeated exposure studies with reproduction/development toxicity screening tests (OECD 422). There were no toxicologically important changes in parameters relating to systemic toxicity or neurotoxicity for any of these gases at concentrations ranging from 9000 to 16,000 ppm. There was no evidence of effects on developmental or reproductive toxicity in the studies of ethane, propane, or n-butane at the highest concentrations tested. However, there was a reduction in mating in the high-exposure group (9000 ppm) of the isobutane study, which although not significantly different was outside the range previously observed in the testing laboratory. Assuming the reduction in mating to have been toxicologically significant, the NOAEC for the isobutane reproductive toxicity screening test was 3000 ppm (7125 mg/m(3)). A method is proposed by which the toxicity of any of the 106 complex petroleum gas streams can be estimated from its composition.

Field Evidence for Magnetite Formation by a Methanogenic Microbial Community

NASA Astrophysics Data System (ADS)

Rossbach, S.; Beaver, C. L.; Williams, A.; Atekwana, E. A.; Slater, L. D.; Ntarlagiannis, D.; Lund, A.

2015-12-01

The aged, subsurface petroleum spill in Bemidji, Minnesota, has been surveyed with magnetic susceptibility (MS) measurements. High MS values were found in the free-product phase around the fluctuating water table. Although we had hypothesized that high MS values are related to the occurrence of the mineral magnetite resulting from the activity of iron-reducing bacteria, our microbial analysis pointed to the presence of a methanogenic microbial community at the locations and depths of the highest MS values. Here, we report on a more detailed microbial analysis based on high-throughput sequencing of the 16S rRNA gene of sediment samples from four consecutive years. In addition, we provide geochemical data (FeII/FeIII concentrations) to refine our conceptual model of methanogenic hydrocarbon degradation at aged petroleum spills and demonstrate that the microbial induced changes of sediment properties can be monitored with MS. The methanogenic microbial community at the Bemidji site consisted mainly of the syntrophic, hydrocarbon-degrading Smithella and the hydrogenotrophic, methane-generating Methanoregula. There is growing evidence in the literature that not only Bacteria, but also some methanogenic Archaea are able to reduce iron. In fact, a recent study reported that the methanogen Methanosarcina thermophila produced magnetite during the reduction of ferrihydrite in a laboratory experiment when hydrogen was present. Therefore, our finding of high MS values and the presence of magnetite in the methanogenic zone of an aged, subsurface petroleum spill could very well be the first field evidence for magnetite formation during methanogenic hydrocarbon degradation.

Morocco Country Analysis Brief

EIA Publications

2014-01-01

Morocco is a net hydrocarbon importer. The country produces marginal amounts of oil, natural gas, and refined petroleum products, which is mainly consumed domestically. Morocco has two refineries with a total crude oil distillation capacity of about 155,000 barrels per day (bbl/d), according to Oil & Gas Journal.

Biodegradation of Diesel, Crude Oil and Spent Lubricating Oil by Soil Isolates of Bacillus spp.

PubMed

Raju, Maddela Naga; Leo, Rodriguez; Herminia, Sanaguano Salguero; Morán, Ricardo Ernesto Burgos; Venkateswarlu, Kadiyala; Laura, Scalvenzi

2017-05-01

Two species of Bacillus, B. thuringiensis B3 and B. cereus B6, isolated from crude oil-contaminated sites in Ecuador, were tested for their capability in degrading polycyclic aromatic hydrocarbons (PAHs) in diesel (shake-flask), and to remove total petroleum hydrocarbons (TPHs) from crude oil- or spent lubricating oil-polluted soils (plot-scale). TPHs and PAHs were analyzed by Gas chromatography-Flame ionization detector (GC-FID) and High performance liquid chromatography (HPLC), respectively. Degradation percentages of PAHs by strain B6 were in the range of 11-83 after 30 days. A mixed culture of both the strains removed 84% and 28% of TPHs from crude oil- and spent lubricating oil-polluted soils, respectively. Reduction in the abundance of total n-alkane fractions (C 8 -C 40 ) of spent lubricating oil was 94%, which was 18% higher than the control. Our results clearly indicate that the selected strains have great potential in degrading petroleum hydrocarbons at both laboratory- and field-scales.

Phytoremediation in mangrove sediments impacted by persistent total petroleum hydrocarbons (TPH's) using Avicennia schaueriana.

PubMed

Moreira, Icaro T A; Oliveira, Olivia M C; Triguis, Jorge A; Queiroz, Antonio F S; Ferreira, Sergio L C; Martins, Cintia M S; Silva, Ana C M; Falcão, Brunno A

2013-02-15

This study evaluated the efficiency of Avicennia schaueriana in the implementation of phytoremediation compared with intrinsic bioremediation in mangrove sediments contaminated by total petroleum hydrocarbons (TPHs). The experiment was conducted for 3months at a pilot scale under conditions similar to a mangrove: the dynamics of the tides were simulated, and physical, chemical, microbiological and biogeochemical parameters were monitored. After the 90 days, it was found that the phytoremediation was more efficient in the degradation of the TPHs compared to bioremediation, reducing the initial concentration of 32.2-4.2 mg/g. A. schaueriana was also more efficient in mediating the degradation of different fractions of hydrocarbons, achieving a removal efficiency of 87%. The microbiological results consisted of a higher growth in the model with the plants, demonstrating the phytostimulation ability of the plants. Finally, the experiment showed that phytoremediation is a promising alternative in mangrove impacted by oil. Copyright © 2012 Elsevier Ltd. All rights reserved.

Hydrocarbon pollution in the sediment from the Jarzouna-Bizerte coastal area of Tunisia (Mediterranean Sea).

PubMed

Zrafi-Nouira, I; Khedir-Ghenim, Z; Zrafi, F; Bahri, R; Cheraeif, I; Rouabhia, M; Saidane-Mosbahi, D

2008-06-01

This study investigated the presence and origin of hydrocarbon pollution in industrial waste water sediments found near the Jarzouna (Bizerte, Tunisia) oil refinery. Analyses of surface sediments (layer 1) and deep sediments (layer 2) showed that Total Hydrocarbon (TH) concentrations ranged from 602 +/- 7.638 microg/g in layer-1 to 1270 +/- 2.176 microg/g in layer-2. The results suggest that the deeper the sediment, the higher the level of total hydrocarbon found. The sedimentary Non Aromatic Hydrocarbon (NAH) and Aromatic Hydrocarbon (AH) concentrations ranged from 66.22 +/- 1.516 to 211.82 +/- 10.670 microg/g for NAH, and from 13.84 +/- 0.180 to 115.60 +/- 2.479 microg/g for AH. The high variability of these concentrations was associated with the location of the sediment collection sites. Aliphatic biomarker analysis revealed petroleum contamination close to the refinery rejection site, and biogenic sources further away. Petroleum contamination may be associated with increased industrial activity in the area of Jarzouna-Bizerte in the Mediterranean Sea.

Total petroleum systems of the Bonaparte Gulf Basin area, Australia; Jurassic, Early Cretaceous-Mesozoic; Keyling, Hyland Bay-Permian; Milligans-Carboniferous, Permian

USGS Publications Warehouse

Bishop, M.G.

1999-01-01

The Bonaparte Gulf Basin Province (USGS #3910) of northern Australia contains three important hydrocarbon source-rock intervals. The oldest source-rock interval and associated reservoir rocks is the Milligans-Carboniferous, Permian petroleum system. This petroleum system is located at the southern end of Joseph Bonaparte Gulf and includes both onshore and offshore areas within a northwest to southeast trending Paleozoic rift that was initiated in the Devonian. The Milligans Formation is a Carboniferous marine shale that sources accumulations of both oil and gas in Carboniferous and Permian deltaic, marine shelf carbonate, and shallow to deep marine sandstones. The second petroleum system in the Paleozoic rift is the Keyling, Hyland Bay-Permian. Source rocks include Lower Permian Keyling Formation delta-plain coals and marginal marine shales combined with Upper Permian Hyland Bay Formation prodelta shales. These source-rock intervals provide gas and condensate for fluvial, deltaic, and shallow marine sandstone reservoirs primarily within several members of the Hyland Bay Formation. The Keyling, Hyland Bay-Permian petroleum system is located in the Joseph Bonaparte Gulf, north of the Milligans-Carboniferous, Permian petroleum system, and may extend northwest under the Vulcan graben sub-basin. The third and youngest petroleum system is the Jurassic, Early Cretaceous-Mesozoic system that is located seaward of Joseph Bonaparte Gulf on the Australian continental shelf, and trends southwest-northeast. Source-rock intervals in the Vulcan graben sub-basin include deltaic mudstones of the Middle Jurassic Plover Formation and organic-rich marine shales of the Upper Jurassic Vulcan Formation and Lower Cretaceous Echuca Shoals Formation. These intervals produce gas, oil, and condensate that accumulates in, shallow- to deep-marine sandstone reservoirs of the Challis and Vulcan Formations of Jurassic to Cretaceous age. Organic-rich, marginal marine claystones and coals of the Plover Formation (Lower to Upper Jurassic), combined with marine claystones of the Flamingo Group and Darwin Formation (Upper Jurassic to Lower Cretaceous) comprise the source rocks for the remaining area of the system. These claystones and coals source oil, gas, and condensate accumulations in reservoirs of continental to marine sandstones of the Plover Formation and Flamingo Group. Shales of the regionally distributed Lower Cretaceous Bathurst Island Group and intraformational shales act as seals for hydrocarbons trapped in anticlines and fault blocks, which are the major traps of the province. Production in the Bonaparte Gulf Basin Province began in 1986 using floating production facilities, and had been limited to three offshore fields located in the Vulcan graben sub-basin. Cumulative production from these fields totaled more than 124 million barrels of oil before the facilities were removed after production fell substantially in 1995. Production began in 1998 from three offshore wells in the Zone of Cooperation through floating production facilities. After forty years of exploration, a new infrastructure of pipelines and facilities are planned to tap already discovered offshore reserves and to support additional development.

Studies on effects of Andrographis paniculata (Burm.f.) and Andrographis lineata nees (Family: Acanthaceae) extracts against two mosquitoes Culex quinquefasciatus (Say.) and Aedes aegypti (Linn.).

PubMed

Renugadevi, G; Ramanathan, T; Shanmuga, priya R; Thirunavukkarasu, P

2013-03-01

To investigate the studies on effects of Andrographis paniculata (A. paniculata) (Burm.f.) and Andrographis lineata (A. lineata) nees (Family: Acanthaceae) extracts against two mosquitoes Culex quinquefasciatus (Cx. quinquefasciatus) (Say.) and Aedes aegypti (Ae. aegypti) (Linn.). The aqueous and petroleum ether extracts of two plant species, A. paniculata and A. lineate were examined against the larvae of A. aegypti (L.) and Cx. quinquefasciatus with gradually increasing concentration ie. from 50 to 200 ppm of solvent extracts and to test their activity in combination with each other. In a 24 h bioassay experiment with plant extracts, highest mortalities were recorded at 200 ppm of concentrations for leaves of A. lineta and A. paniculata individually. For combination effect, only 150 ppm of the mixture of solvent extracts of petroleum ether: aqueous (1:1) extracts showed 100% mortality after 24 h of exposure. The results show that, insecticides of plant combination is ecofriend and has better larvicidal activity compared to individual extracts. Copyright © 2013 Hainan Medical College. Published by Elsevier B.V. All rights reserved.

Petroleum hydrocarbons, fluorescent aromatic compounds in fish bile and organochlorine pesticides from areas surrounding the spill of the Kab121 well, in the Southern Gulf of Mexico: a case study.

PubMed

Gold-Bouchot, G; Ceja-Moreno, V; Chan-Cocom, E; Zapata-Perez, O

2014-01-01

In October 2007, a light crude oil spill took place in the off shore Kab121 oil well, 32 km north of the mouth of the Grijalva River, Tabasco, Mexico. In order to estimate the possible effects of oil spill on the biota in the area surrounding the spilled well, the level of different fractions of petroleum hydrocarbons were measured in fish, as well as the concentration of some chlorinated hydrocarbons and PCBs. The organisms examined were cat fish (Ariopsis felis), in addition fluorescent aromatic compounds in bile, the contaminants above mentioned and their relationship with cyotochrome P-450 and Ethoxyresorufin-O-deethylase, Glutathion-S-Transferase and catalase activities in liver were determined. The concentration of most pollutants were low, except PAHs. Spatial distribution of these compounds, as well as most biomarkers, reflected the highest exposure of fish to pollutants in the area adjacent to well, as well as in the proximity of rivers. The profile of exposure to this environment was chronic in nature and not temporary.

Ecofriendly demulsification of water in oil emulsions by an efficient biodemulsifier producing bacterium isolated from oil contaminated environment.

PubMed

Sabati, Hoda; Motamedi, Hossein

2018-05-15

Water in oil emulsions increase oil processing costs and cause damage to refinery equipment which necessitates demulsification. Since chemical demulsifiers cause environmental pollution, biodemulsifiers have been paid more attention. This study aims to identify biodemulsifier-producing bacteria from petroleum contaminated environments. As a result, several biodemulsifier producing strains were found that Stenotrophomonas sp. strain HS7 (accession number: MF445088) which produced a cell associated biodemulsifier showed the highest demulsifying ratio, 98.57% for water in kerosene and 66.28% for water in crude oil emulsion after 48 h. 35 °C, pH 7, 48 h incubation and ammonium nitrate as nitrogen source were optimum conditions for biodemulsifier production. Furthermore, it was found that hydrophobic carbon sources like as liquid paraffin is not preferred as the sole carbon source while a combination of various carbon sources including liquid paraffin will increase demulsification efficiency of the biodemulsifier. The appropriate potential of this biodemulsifier strengthens the possibility of its application in industries especially petroleum industry.

Total phenolic, total flavonoid content, and antioxidant capacity of the leaves of Meyna spinosa Roxb., an Indian medicinal plant.

PubMed

Sen, Saikat; De, Biplab; Devanna, N; Chakraborty, Raja

2013-03-01

The objective of the present study was to determine the total phenolic and total flavonoid contents, and to evaluate the antioxidant potential of different leaf extracts of Meyna spinosa Roxb. ex Link, a traditional medicinal plant of India. Free radical scavenging and antioxidant potential of the methanol, ethyl acetate, and petroleum ether extracts of Meyna spinosa leaves were investigated using several in vitro and ex vivo assays, including the 2, 2-diphenyl-picrylhydrazyl radical scavenging, superoxide anion scavenging, hydroxyl radical scavenging, nitric oxide radical scavenging, hydrogen peroxide scavenging activity, metal chelating assay, and reducing power ability method. Total antioxidant activity of the extracts was estimated by the ferric thiocyanate method. Inhibition assay of lipid peroxidation and oxidative hemolysis were also performed to confirm the protective effect of the extracts. Total phenolic and total flavonoid contents of the extracts were estimated using standard chemical assay procedures. Methanol extracts showed the highest polyphenolic content and possessed the better antioxidant activity than the other two extracts. Total phenolic and total flavonoid contents in the methanol extract were (90.08 ± 0.44) mg gallic acid equivalents/g and (58.50 ± 0.09) mg quercetin equivalents/g, respectively. The IC50 of the methanol extract in the DPPH(·), superoxide anion, hydroxyl radical, nitric oxide radical, hydrogen peroxide scavenging activity and metal chelating assays were (16.4 ± 0.41), (35.9 ± 0.19), (24.1 ± 0.33), (23.7 ± 0.09), (126.8 ± 2.92), and (117.2 ± 1.01) μg·mL(-1), respectively. The methanol extract showed potent reducing power ability, total antioxidant activity, and significantly inhibit lipid peroxidation and oxidative hemolysis which was similar to that of standards. The results indicated a direct correlation between the antioxidant activity and the polyphenolic content of the extracts, which may the foremost contributors to the antioxidant activity of the plant. The present study confirmed that the methanol extract of Meyna spinosa leaves is a potential source of natural antioxidants. Copyright © 2013 China Pharmaceutical University. Published by Elsevier B.V. All rights reserved.

Towards greener environment: Energy efficient pathways for the transportation sector in Malaysia

NASA Astrophysics Data System (ADS)

Indati, M. S.; Ghate, A. T.; Leong, Y. P.

2013-06-01

Transportation sector is the second most energy consuming sector after industrial sector, accounting for 40% of total energy consumption in Malaysia. The transportation sector is one of the most energy intensive sectors in the country and relies primarily on petroleum products, which in total account for nearly 98% of the total consumption in the sector. Since it is heavily reliant on petroleum based fuels, the sector contributes significantly to the greenhouse gas (GHG) emissions. The need to reduce the greenhouse gas emission is paramount as Malaysia at Conference of the Parties (COP15) pledged to reduce its carbon intensity by 40% by 2020 from 2005 level subject to availability of technology and finance. Transport sector will be among the first sectors that need to be addressed to achieve this goal, as two-thirds of the emissions come from fuel combustion in transport sector. This paper will analyse the factors influencing the transport sector's growth and energy consumption trends and discuss the key issues and challenges for greener environment and sustainable transportation in Malaysia. The paper will also discuss the policy and strategic options aimed towards energy efficient pathways in Malaysia.

Remediation of aged diesel contaminated soil by alkaline activated persulfate.

PubMed

Lominchar, M A; Santos, A; de Miguel, E; Romero, A

2018-05-01

The present work studies the efficiency of alkaline activated persulfate (PS) to remediate an aged diesel fuel contaminated soil from a train maintenance facility. The Total Petroleum Hydrocarbon (TPH) concentration in soil was approximately 5000mgkg -1 with a ratio of aliphatic:aromatic compounds of 70:30. Aromatic compounds were mainly naphtalenes and phenanthrenes. The experiments were performed in batch mode where different initial concentrations of persulfate (105mM, 210mM and 420mM) and activator:persulfate ratios (2 and 4) were evaluated, with NaOH used as activator. Runs were carried out during 56days. Complete TPH conversion was obtained with the highest concentration of PS and activator, whereas in the other runs the elimination of fuel ranged between 60 and 77%. Besides, the abatement of napthalenes and phenantrenes was faster than aliphatic reduction (i. e. after 4days of treatment, the conversions of the aromatic compounds were around 0.8 meanwhile the aliphatic abatements were 0.55) and no aromatic oxidation intermediates from naphtalenes or phenantrenes were detected. These results show that this technology is effective for the remediation of aged diesel in soil with alkaline pH. Copyright © 2017 Elsevier B.V. All rights reserved.

Analysis of the Global Warming Potential of Biogenic CO2 Emission in Life Cycle Assessments

NASA Astrophysics Data System (ADS)

Liu, Weiguo; Zhang, Zhonghui; Xie, Xinfeng; Yu, Zhen; von Gadow, Klaus; Xu, Junming; Zhao, Shanshan; Yang, Yuchun

2017-01-01

Biomass is generally believed to be carbon neutral. However, recent studies have challenged the carbon neutrality hypothesis by introducing metric indicators to assess the global warming potential of biogenic CO2 (GWPbio). In this study we calculated the GWPbio factors using a forest growth model and radiative forcing effects with a time horizon of 100 years and applied the factors to five life cycle assessment (LCA) case studies of bioproducts. The forest carbon change was also accounted for in the LCA studies. GWPbio factors ranged from 0.13-0.32, indicating that biomass could be an attractive energy resource when compared with fossil fuels. As expected, short rotation and fast-growing biomass plantations produced low GWPbio. Long-lived wood products also allowed more regrowth of biomass to be accounted as absorption of the CO2 emission from biomass combustion. The LCA case studies showed that the total life cycle GHG emissions were closely related to GWPbio and energy conversion efficiency. By considering the GWPbio factors and the forest carbon change, the production of ethanol and bio-power appeared to have higher GHG emissions than petroleum-derived diesel at the highest GWPbio.

Analysis of the Global Warming Potential of Biogenic CO2 Emission in Life Cycle Assessments

PubMed Central

Liu, Weiguo; Zhang, Zhonghui; Xie, Xinfeng; Yu, Zhen; von Gadow, Klaus; Xu, Junming; Zhao, Shanshan; Yang, Yuchun

2017-01-01

Biomass is generally believed to be carbon neutral. However, recent studies have challenged the carbon neutrality hypothesis by introducing metric indicators to assess the global warming potential of biogenic CO2 (GWPbio). In this study we calculated the GWPbio factors using a forest growth model and radiative forcing effects with a time horizon of 100 years and applied the factors to five life cycle assessment (LCA) case studies of bioproducts. The forest carbon change was also accounted for in the LCA studies. GWPbio factors ranged from 0.13–0.32, indicating that biomass could be an attractive energy resource when compared with fossil fuels. As expected, short rotation and fast-growing biomass plantations produced low GWPbio. Long-lived wood products also allowed more regrowth of biomass to be accounted as absorption of the CO2 emission from biomass combustion. The LCA case studies showed that the total life cycle GHG emissions were closely related to GWPbio and energy conversion efficiency. By considering the GWPbio factors and the forest carbon change, the production of ethanol and bio-power appeared to have higher GHG emissions than petroleum-derived diesel at the highest GWPbio. PMID:28045111

Analysis of the Global Warming Potential of Biogenic CO2 Emission in Life Cycle Assessments.

PubMed

Liu, Weiguo; Zhang, Zhonghui; Xie, Xinfeng; Yu, Zhen; von Gadow, Klaus; Xu, Junming; Zhao, Shanshan; Yang, Yuchun

2017-01-03

Biomass is generally believed to be carbon neutral. However, recent studies have challenged the carbon neutrality hypothesis by introducing metric indicators to assess the global warming potential of biogenic CO 2 (GWP bio ). In this study we calculated the GWP bio factors using a forest growth model and radiative forcing effects with a time horizon of 100 years and applied the factors to five life cycle assessment (LCA) case studies of bioproducts. The forest carbon change was also accounted for in the LCA studies. GWP bio factors ranged from 0.13-0.32, indicating that biomass could be an attractive energy resource when compared with fossil fuels. As expected, short rotation and fast-growing biomass plantations produced low GWP bio . Long-lived wood products also allowed more regrowth of biomass to be accounted as absorption of the CO 2 emission from biomass combustion. The LCA case studies showed that the total life cycle GHG emissions were closely related to GWP bio and energy conversion efficiency. By considering the GWP bio factors and the forest carbon change, the production of ethanol and bio-power appeared to have higher GHG emissions than petroleum-derived diesel at the highest GWP bio .

Modulation of microbial consortia enriched from different polluted environments during petroleum biodegradation.

PubMed

Omrani, Rahma; Spini, Giulia; Puglisi, Edoardo; Saidane, Dalila

2018-04-01

Environmental microbial communities are key players in the bioremediation of hydrocarbon pollutants. Here we assessed changes in bacterial abundance and diversity during the degradation of Tunisian Zarzatine oil by four indigenous bacterial consortia enriched from a petroleum station soil, a refinery reservoir soil, a harbor sediment and seawater. The four consortia were found to efficiently degrade up to 92.0% of total petroleum hydrocarbons after 2 months of incubation. Illumina 16S rRNA gene sequencing revealed that the consortia enriched from soil and sediments were dominated by species belonging to Pseudomonas and Acinetobacter genera, while in the seawater-derived consortia Dietzia, Fusobacterium and Mycoplana emerged as dominant genera. We identified a number of species whose relative abundances bloomed from small to high percentages: Dietzia daqingensis in the seawater microcosms, and three OTUs classified as Acinetobacter venetianus in all two soils and sediment derived microcosms. Functional analyses on degrading genes were conducted by comparing PCR results of the degrading genes alkB, ndoB, cat23, xylA and nidA1 with inferences obtained by PICRUSt analysis of 16S amplicon data: the two data sets were partly in agreement and suggest a relationship between the catabolic genes detected and the rate of biodegradation obtained. The work provides detailed insights about the modulation of bacterial communities involved in petroleum biodegradation and can provide useful information for in situ bioremediation of oil-related pollution.

Comparison of gaseous exhaust indices of the F109 turbofan using three different blends of petroleum-based Jet-A and camelina-based Jet-A

NASA Astrophysics Data System (ADS)

Kozak, Brian John

This research project focused on the collection and comparison of gaseous exhaust emissions of the F109 turbofan engine using petroleum-based Jet-A and two different blends of camelina-based Jet-A. Simulated landing and takeoff cycles were used to collect gaseous exhaust emissions. Unburned hydrocarbon (HC), nitrogen oxide (NOx), and carbon moNOxide (CO) exhaust indices (EIm) were calculated using ICAO Annex 16 Volume II formulae. Statistical analyses were performed on the Elm data. There was no significant difference in HC EIm and CO EI m among the three fuels at takeoff thrust. There were significant differences among the fuels for NOx EIm. 50% Jet-A 50% camelina produced the highest NOx EIm, then 75% Jet-A 25% camelina and finally Jet-A. At climb thrust, both blends of camelina fuel produced higher NOx EIm but no difference in CO EIm and HC EIm as Jet-A. At approach thrust, both blends of camelina fuel produced higher NOx EIm, lower CO EIm, and no difference in HC EIm as Jet-A. At idle thrust, there was no significant difference among the fuels for NOx EIm. There were significant differences among the fuels for HC EIm. Jet-A and 50% Jet-A 50% both produced higher HC EIm as 75% Jet-A 25% camelina. There were significant differences among the fuels for CO EI m. Jet-A produced the highest CO EIm, then 75% Jet-A 25% camelina and finally 50% Jet-A 50% camelina.

Modeling oil generation with time-temperature index graphs based on the Arrhenius equation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hunt, J.M.; Lewan, M.D.; Hennet, R.J.C.

1991-04-01

The time and depth of oil generation from petroleum source rocks containing type II kerogens can be determined using time-temperature index (TTI) graphs based on the Arrhenius equation. Activation energies (E) and frequency factors (A) used in the Arrhenius equation were obtained from hydrous pyrolysis experiments on rock samples in which the kerogens represent the range of type II kerogen compositions encountered in most petroleum basins. The E and A values obtained were used to construct graphs that define the beginning and end of oil generation for most type II kerogens having chemical compositions in the range of these standards.more » Activation energies of these standard kerogens vary inversely with their sulfur content. The kerogen with the highest sulfur content had the lowest E value and was the fastest in generating oil, whereas the kerogen with the lowest sulfur content had the highest E value and was the slowest in generating oil. These standard kerogens were designated as types IIA, B, C, and D on the basis of decreasing sulfur content and corresponding increasing time-temperature requirements for generating oil. The {Sigma}TTI{sub ARR} values determined graphically with these type II kerogen standards in two basin models were compared with a computer calculation using 2,000 increments. The graphical method came within {plus minus} 3% of the computer calculation. As type II kerogens are the major oil generators in the world, these graphs should have wide application in making preliminary evaluations of the depth of the oil window in exploration areas.« less

Appraisal of levels and patterns of occupational exposure to 1,3-butadiene.

PubMed

Scarselli, Alberto; Corfiati, Marisa; Di Marzi, Davide; Iavicoli, Sergio

2017-09-01

Objectives 1,3-butadiene is classified as carcinogenic to human by inhalation and the association with leukemia has been observed in several epidemiological studies. The aim of this study was to evaluate data about occupational exposure levels to 1,3-butadiene in the Italian working force. Methods Airborne concentrations of 1,3-butadiene were extracted from the Italian database on occupational exposure to carcinogens in the period 1996-2015. Descriptive statistics were calculated for exposure-related variables. An analysis through linear mixed model was performed to determine factors influencing the exposure level. The probability of exceeding the exposure limit was predicted using a mixed-effects logistic model. Concurrent exposures with other occupational carcinogens were investigated using the two-step cluster analysis. Results The total number of exposure measurements selected was 23 885, with an overall arithmetic mean of 0.12 mg/m3. The economic sector with the highest number of measurements was manufacturing of chemicals (18 744). The most predictive variables of the exposure level resulted to be the occupational group and its interaction with the measurement year. The highest likelihood of exceeding the exposure limit was found in the manufacture of coke and refined petroleum products. Concurrent exposures were frequently detected, mainly with benzene, acrylonitrile and ethylene dichloride, and three main clusters were identified. Conclusions Exposure to 1,3-butadiene occurs in a wide variety of activity sectors and occupational groups. The use of several statistical analysis methods applied to occupational exposure databases can help to identify exposure situations at high risk for workers' health and better target preventive interventions and research projects.

Polycyclic Aromatic Hydrocarbons in Fine Particulate Matter ...

EPA Pesticide Factsheets

This study measured polycyclic aromatic hydrocarbon (PAH) composition in particulate matter emissions from residential cookstoves. A variety of fuel and cookstove combinations were examined, including: (i) liquid petroleum gas (LPG), (ii) kerosene in a wick stove, (iii) wood (10% and 30% moisture content on a wet basis) in a forced-draft fan stove, and (iv) wood in a natural-draft rocket cookstove. LPG combustion had the highest thermal efficiency (~57%) and the lowest PAH emissions per unit fuel energy, resulting in the lowest PAH emissions per useful energy delivered (MJd). The average benzo[a]pyrene (B[a]P) emission factor for LPG was 0.842 µg/MJd; the emission rate was 0.043 µg/min. The highest PAH emissions were from wood burning in the natural-draft stove (209-700 µg B[a]P/MJd). PAH emissions from kerosene were significantly lower than those from the wood burning in the natural-draft cookstove, but higher than those from LPG. It is expected that in rural regions where LPG and kerosene are unavailable or unaffordable, the forced-draft fan stove may be an alternative because its emission factor (5.17-8.07 µg B[a]P/MJd) and emission rate (0.52-0.57 µg/min) are similar to kerosene (5.36 µg B[a]P/MJd and 0.45 µg/min). Compared with wood combustion emissions, LPG stoves emit less total PAH emissions and less fractions of high molecular weight PAHs. Relatively large variations in PAH emissions from LPG call for additional future tests to identify the major

INNOVATIVE TECHNOLOGY VERIFICATION REPORT "FIELD MEASUREMENT TECHNOLOGIES FOR TOTAL PETROLEUM HYDROCARBONS IN SOIL" ENVIRONMENTAL SYSTEMS CORPORATION SYNCHRONOUS SCANNING LUMINOSCOPE

EPA Science Inventory

The Synchronous Scanning Luminoscope (Luminoscope) developed by the Oak Ridge National Laboratory in collaboration with Environmental Systems Corporation (ESC) was demonstrated under the U.S. Environmental Protection Agency Superfund Innovative Technology Evaluation Program i...

IMPACT OF OIL PRODUCTION RELEASES ON SOME SOIL CHEMICAL PROPERTIES AT THE OSPER SITES

EPA Science Inventory

Surface and soil core samples were collected at two field sites in an old oil production area near Skiatook Lake in Oklahoma. The soil samples were analyzed for nitrates, organic matter, total petroleum hydrocarbons, conductivity, chlorides and dehydrogenase activity. Low level...

Characterization Of Contaminant Migration Potential In The Vicinity Of An In-Place Sand Cap

EPA Science Inventory

This study characterized the chemical transport potential of polycyclic aromatic hydrocarbons (PAHs) and total petroleum hydrocarbons (TPHs) in the vicinity of a sand cap placed in the nearshore zone of a tidal marine embayment. Groundwater seepage was investigated along the per...

Alternative Fuels Data Center

Science.gov Websites

Liquefied Petroleum Gas (Propane) Vehicle and Equipment Incentive - Propane Council of Texas fleets. New dedicated propane vehicles and aftermarket conversions are eligible for an incentive equal to the incremental cost, up to $7,500. Each fleet is limited to $20,000 in total incentive awards

40 CFR 80.92 - Baseline auditor requirements.

Code of Federal Regulations, 2014 CFR

2014-07-01

... total of more than 10 percent of its net worth with the refiner or importer; nor (iii) Receive... determination. It shall have personnel familiar with petroleum refining processes, including associated... worked at least five (5) years in either refinery operations or as a consultant for the refining industry...

40 CFR 80.92 - Baseline auditor requirements.

Code of Federal Regulations, 2011 CFR

2011-07-01

... total of more than 10 percent of its net worth with the refiner or importer; nor (iii) Receive... determination. It shall have personnel familiar with petroleum refining processes, including associated... worked at least five (5) years in either refinery operations or as a consultant for the refining industry...

40 CFR 80.92 - Baseline auditor requirements.

Code of Federal Regulations, 2013 CFR

2013-07-01

... total of more than 10 percent of its net worth with the refiner or importer; nor (iii) Receive... determination. It shall have personnel familiar with petroleum refining processes, including associated... worked at least five (5) years in either refinery operations or as a consultant for the refining industry...

Total petroleum system assessment of undiscovered resources in the giant Barnett Shale continuous (unconventional) gas accumulation, Fort Worth Basin, Texas

USGS Publications Warehouse

Pollastro, R.M.

2007-01-01

Undiscovered natural gas having potential for additions to reserves in the Mississippian Barnett Shale of the Fort Worth Basin, north-central Texas, was assessed using the total petroleum system assessment unit concept and a cell-based methodology for continuous-type (Unconventional) resources. The Barnett-Paleozoic total petroleum system is defined in the Bend arch-Fort Worth Basin as encompassing the area in which the organic-rich Barnett is the primary source rock for oil and gas produced from Paleozoic carbonate and clastic reservoirs. Exploration, technology, and drilling in the Barnett Shale play have rapidly evolved in recent years, with about 3500 vertical and 1000 horizontal wells completed in the Barnett through 2005 and more than 85% of the them completed since 1999. Using framework geology and historical production data, assessment of the Barnett Shale was performed by the U.S. Geological Survey using vertical wells at the peak of vertical well completions and before a transition to completions with horizontal wells. The assessment was performed after (1) mapping critical geological and geochemical parameters to define assessment unit areas with future potential, (2) defining distributions of drainage area (cell size) and estimating ultimate recovery per cell, and (3) estimating future success rates. Two assessment units are defined and assessed for the Barnett Shale continuous gas accumulation, resulting in a total mean undiscovered volume having potential for additions to reserves of 26.2 TCFG. The greater Newark East fracture-barrier continuous Barnett Shale gas assessment unit represents a core-producing area where thick, organic-rich, siliceous Barnett Shale is within the thermal window for gas generation (Ro ??? 1.1%) and is overlain and underlain by impermeable limestone barriers (Pennsylvanian Marble Falls Limestone and Ordovician Viola Limestone, respectively) that serve to confine induced fractures during well completion to maximize gas recovery. The extended continuous Barnett Shale gas assessment unit, which had been less explored, defines a geographic area where Barnett Shale is (1) within the thermal window for gas generation, (2) greater than 100 ft (30 m) thick, and (3) where at least one impermeable limestone barrier is absent. Mean undiscovered gas having potential for additions to reserves in the greater Newark East assessment unit is estimated at 14.6 tcf, and in the less tested extended assessment unit, a mean resource is estimated at 11.6 TCFG. A third hypothetical basin-arch Barnett Shale oil assessment unit was defined but not assessed because of a lack of production data. Copyright ?? 2007. The American Association of Petroleum Geologists. All rights reserved.

Mass Burns Disaster in Abule-egba, Lagos, Nigeria from a Petroleum Pipeline Explosion Fire

PubMed Central

Fadeyibi, I.O.; Omosebi, D.T.; Jewo, P.I.; Ademiluyi, S.A.

2009-01-01

Summary The aim of this paper is to review the basic principles of triage in mass burns disasters and discuss the experience of the Lagos State University Teaching Hospital (LASUTH), Ikeja, Nigeria, in the December 2006 disaster at Abule-Egba, Lagos, Nigeria. It is hoped that the experience gained will help in the planning for and management of similar disasters in the developing countries with limited facilities. Burn injury has been described as the severest form of trauma and its management is very challenging as it is often accompanied by numerous pathophysiological changes. Successful management requires expert management by well-trained personnel in equipped and dedicated centres. In mass disasters the total number of victims may exceed the capability of the facility and its staff and a system for sorting out the patients and caring for those that will benefit from the facilities available needs to be developed. Other patients will either be sent to other medical facilities for further treatment or discharged after initial care for future follow-up. Documented experiences in the management of mass burns disasters from petroleum pipeline explosions from developing countries are rare. However, petroleum pipeline explosions, especially in the Lagos area of Nigeria, are relatively common. These cases have been associated with a variety of factors. The resulting morbidity and mortality have been high. LASUTH has a dedicated burns centre, which has received and managed many burn patients. Triage is the medical process of screening patients according to their need of treatment and the resources available. The aims and objectives of triage are discussed, its various levels described, and the final goals elaborated. All the burn victims involved in the 2006 disaster were studied, together with the triage carried out at different levels and the consequent sorting of the patients. Standard burns management was carried out. A total of 385 patients sustained burns of various degrees from the fire resulting from the explosion. On site, emergency department (ED) and intra-hospital triage were carried out. Ninety patients were brought to the LASUTH ED. Of these, 51 patients (56.67%) received first-aid treatment and were either discharged for out-patient follow-up or referred to secondary health care facilities. Twenty-eight (31.11%) out of the remaining 39 patients with burns in more than 70% total body surface area (TBSA) were categorized as unsalvageable and 11 (12.22%) with less than 70% TBSA as salvageable. All the patients in the unsalvageable group died (i.e. 100% mortality), while one patient died in the salvageable group (mortality rate, 9.09%). The mortality rate for the ruptured petroleum product pipeline incident was 84.16%; the fatality rate for all patients seen at LASUTH was 32.22%. The need for caution in the handling of petroleum products is discussed and the effectiveness of the triage system used is highlighted. In conclusion, burns from flammable petroleum products can be very dangerous and proper triage should therefore be carried out, with salvageable patients being managed by experts in dedicated burns centres. PMID:21991163

Geologic Assessment of Undiscovered Oil and Gas Resources of the North Cuba Basin, Cuba

USGS Publications Warehouse

Schenk, Christopher J.

2010-01-01

Petroleum generation in the North Cuba Basin is primarily the result of thrust loading of Jurassic and Cretaceous source rocks during formation of the North Cuba fold and thrust belt in the Late Cretaceous to Paleogene. The fold and thrust belt formed as Cuban arc-forearc rocks along the leading edge of the Caribbean plate translated northward during the opening of the Yucatan Basin and collided with the passive margin of southern North America in the Paleogene. Petroleum fluids generated during thrust loading migrated vertically into complex structures in the fold and thrust belt, into structures in the foreland basin, and possibly into carbonate reservoirs along the margins of the Yucatan and Bahama carbonate platforms. The U.S. Geological Survey (USGS) defined a Jurassic-Cretaceous Composite Total Petroleum System (TPS) and three assessment units (AU)-North Cuba Fold and Thrust Belt AU, North Cuba Foreland Basin AU, and the North Cuba Platform Margin Carbonate AU-within this TPS based mainly on structure and reservoir type (fig. 1). There is considerable geologic uncertainty as to the extent of petroleum migration that might have occurred within this TPS to form potential petroleum accumulations. Taking this geologic uncertainty into account, especially in the offshore area, the mean volumes of undiscovered resources in the composite TPS of the North Cuba Basin are estimated at (1) 4.6 billion barrels of oil (BBO), with means ranging from an F95 probability of 1 BBO to an F5 probability of 9 BBO; and (2) 8.6 trillion cubic feet of of gas (TCFG), of which 8.6 TCFG is associated with oil fields, and about 1.2 TCFG is in nonassociated gas fields in the North Cuba Foreland Basin AU.

Petroleum Hydrocarbon Profiles of Water and Sediment of Algoa Bay, Eastern Cape, South Africa

PubMed Central

Adeniji, Abiodun O.; Okoh, Omobola O.

2017-01-01

Petroleum hydrocarbon profiles of water and sediment samples of Algoa Bay in the Eastern Cape Province of South Africa were assessed using standard analytical procedures. Water (from surface and bottom levels) and sediment samples were collected from five locations in the bay from February to June 2016. Extraction of the petroleum hydrocarbons from the water and sediment samples collected was achieved using liquid-liquid and Soxhlet extraction techniques, respectively, followed by column clean up. Target compounds were analytically determined with gas chromatography–flame ionization detector (GC-FID) and quantified by integrating the areas of both the resolved and unresolved components. Physicochemical properties of the water samples were also determined on site using a SeaBird 19plusV2 CTD SBE 55 device. Estimated limit of detection, limit of quantitation and relative standard deviation for the 35 n-alkane standards ranged from 0.06 to 0.13 μg/L, 0.30 to 0.69 μg/L and 3.61 to 8.32%, respectively. Results showed that total petroleum hydrocarbon (TPH) varied from 45.07 to 307 μg/L in the water and 0.72 to 27.03 mg/kg in the sediments. The mean concentrations of TPH in both the water and sediment samples from Algoa Bay revealed a slight level of pollution. The diagnostic indices used showed that the hydrocarbons in the area were from both biogenic and anthropogenic sources. Hence, there is need for adequate regulation and control of all activities contributing to the levels of petroleum hydrocarbon in the marine environment for the safety of human, aquatic and wild lives in the area. PMID:29053634

Geology and hydrocarbon potential of the Hartford-Deerfield Basin, Connecticut and Massachusetts

USGS Publications Warehouse

Coleman, James

2016-01-01

The Hartford-Deerfield basin, a Late Triassic to Early Jurassic rift basin located in central Connecticut and Massachusetts, is the northernmost basin of the onshore Mesozoic rift basins in the eastern United States. The presence of asphaltic petroleum in outcrops indicates that at least one active petroleum system has existed within the basin. However, to-date oil and gas wells have not been drilled in the basin to test any type of petroleum trap. There are good to excellent quality source rocks (up to 3.8% present day total organic carbon) within the Jurassic East Berlin and Portland formations. While these source rock intervals are fairly extensive and at peak oil to peak gas stages of maturity, individual source rock beds are relatively thin (typically less than 1 m) based solely on outcrop observations. Potential reservoir rocks within the Hartford-Deerfield basin are arkosic conglomerates, pebbly sandstones, and finer grained sandstones, shales, siltstones, and fractured igneous rocks of the Triassic New Haven and Jurassic East Berlin and Portland formations (and possibly other units). Sandstone porosity data from 75 samples range from less than 1% to 21%, with a mean of 5%. Permeability is equally low, except around joints, fractures, and faults. Seals are likely to be unfractured intra-formational shales and tight igneous bodies. Maturation, generation, and expulsion likely occurred during the late synrift period (Early Jurassic) accentuated by an increase in local geothermal gradient, igneous intrusions, and hydrothermal fluid circulation. Migration pathways were likely along syn- and postrift faults and fracture zones. Petroleum resources, if present, are probably unconventional (continuous) accumulations as conventionally accumulated petroleum is likely not present in significant volumes.

Petroleum Hydrocarbon Profiles of Water and Sediment of Algoa Bay, Eastern Cape, South Africa.

PubMed

Adeniji, Abiodun O; Okoh, Omobola O; Okoh, Anthony I

2017-10-20

Petroleum hydrocarbon profiles of water and sediment samples of Algoa Bay in the Eastern Cape Province of South Africa were assessed using standard analytical procedures. Water (from surface and bottom levels) and sediment samples were collected from five locations in the bay from February to June 2016. Extraction of the petroleum hydrocarbons from the water and sediment samples collected was achieved using liquid-liquid and Soxhlet extraction techniques, respectively, followed by column clean up. Target compounds were analytically determined with gas chromatography-flame ionization detector (GC-FID) and quantified by integrating the areas of both the resolved and unresolved components. Physicochemical properties of the water samples were also determined on site using a SeaBird 19plusV2 CTD SBE 55 device. Estimated limit of detection, limit of quantitation and relative standard deviation for the 35 n -alkane standards ranged from 0.06 to 0.13 μg/L, 0.30 to 0.69 μg/L and 3.61 to 8.32%, respectively. Results showed that total petroleum hydrocarbon (TPH) varied from 45.07 to 307 μg/L in the water and 0.72 to 27.03 mg/kg in the sediments. The mean concentrations of TPH in both the water and sediment samples from Algoa Bay revealed a slight level of pollution. The diagnostic indices used showed that the hydrocarbons in the area were from both biogenic and anthropogenic sources. Hence, there is need for adequate regulation and control of all activities contributing to the levels of petroleum hydrocarbon in the marine environment for the safety of human, aquatic and wild lives in the area.

Membrane Lipids as Indicators for Viable Bacterial Communities Inhabiting Petroleum Systems.

PubMed

Gruner, Andrea; Mangelsdorf, Kai; Vieth-Hillebrand, Andrea; Horsfield, Brian; van der Kraan, Geert M; Köhler, Thomas; Janka, Christoph; Morris, Brandon E L; Wilkes, Heinz

2017-08-01

Microbial activity in petroleum reservoirs has been implicated in a suite of detrimental effects including deterioration of petroleum quality, increases in oil sulfur content, biofouling of steel pipelines and other infrastructures, and well plugging. Here, we present a biogeochemical approach, using phospholipid fatty acids (PLFAs), for detecting viable bacteria in petroleum systems. Variations within the bacterial community along water flow paths (producing well, topside facilities, and injection well) can be elucidated in the field using the same technique, as shown here within oil production plants in the Molasse Basin of Upper Austria. The abundance of PLFAs is compared to total cellular numbers, as detected by qPCR of the 16S rDNA gene, to give an overall comparison between the resolutions of both methods in a true field setting. Additionally, the influence of biocide applications on lipid- and DNA-based quantification was investigated. The first oil field, Trattnach, showed significant PLFA abundances and cell numbers within the reservoir and topside facilities. In contrast, the second field (Engenfeld) showed very low PLFA levels overall, likely due to continuous treatment of the topside facilities with a glutaraldehyde-based antimicrobial. In comparison, Trattnach is dosed once per week in a batch fashion. Changes within PLFA compositions across the flow path, throughout the petroleum production plants, point to cellular adaptation within the system and may be linked to shifts in the dominance of certain bacterial types in oil reservoirs versus topside facilities. Overall, PLFA-based monitoring provides a useful tool to assess the abundance and high-level taxonomic diversity of viable microbial populations in oil production wells, topside infrastructure, pipelines, and other related facilities.

Effect of petroleum products inhalation on some haematological indices of fuel attendants in Calabar metropolis, Nigeria.

PubMed

Okoro, A M; Ani, E J; Ibu, J O; Akpogomeh, B A

2006-01-01

The Haematotoxic implications of exposure to petroleum fumes through inhalation in human subjects were investigated. A total of 400 subjects (200 males and 200 females) aged between 18-30 years participated. Each gender was further categorized into two groups of 100 each for control and test, respectively. The test group was again subdivided into test 1 (T1) and test 2 (T2) in both sexes. T1 subjects were exposed to petroleum fumes for two years and below while T2 subjects were exposed for more than two years. Samples of blood were collected daily and subjected to haematological analysis. The results obtained showed that in males and females, red blood cell counts (10(6) /mm3) was significantly [P < 0.001] decreased in T1 (4.4 +/- 0.13) and T2 (3.85 +/- 0.07) compared to control (4.76 +/- 0.01). White blood cell counts, haematocrit, haemoglobin concentration and mean corpusclular haemoglobin concentration (MCHC) were significantly [P < 0.01] decreased in both sexes of test groups when compared with control. There was also a significant [P < 0.001] decrease in mean corpuscular haemoglobin (MCH) and mean corpuscular volume (MCV) in test 2 males compared with control. Most subjects exposed for longer than two years (T2) had significantly [P < 0.001] lower values of red blood cell count, haemoglobin concentration and haematocrit than those exposed for less than two years. The odds/odds ratio that a subject would become anaemic progressively rose from less than 1 in the control to greater than 1 or infinity on exposure to petroleum fumes. These results indicate that the petroleum fumes cause a reduction in haematological indices which worsens with prolonged exposure.

Evaluation of gastrointestinal solubilization of petroleum hydrocarbon residues in soil using an in vitro physiologically based model.

PubMed

Holman, Hoi-Ying N; Goth-Goldstein, Regine; Aston, David; Yun, Mao; Kengsoontra, Jenny

2002-03-15

Petroleum hydrocarbon residues in weathered soils may pose risks to humans through the ingestion pathway. To understand the factors controlling their gastrointestinal (GI) absorption, a newly developed experimental extraction protocol was used to model the GI solubility of total petroleum hydrocarbon (TPH) residues in highly weathered soils from different sites. The GI solubility of TPH residues was significantly higher for soil contaminated with diesel than with crude oil. Compared to the solubility of TPH residues during fasted state,the solubility of TPH residues during fat digestion was much greater. Diesel solubility increased from an average of 8% during the "gallbladder empty" phase of fasting (and less than 0.2% during the otherfasting phase) to an average of 16% during fat digestion. For crude oil, the solubility increased from an average of 1.2% during the gallbladder empty phase of fasting (and undetectable during the other fasting phase) to an average of 4.5% during fat digestion. Increasing the concentration of bile salts also increased GI solubility. GI solubility was reduced by soil organic carbon but enhanced by the TPH content.

Biosurfactant-assisted phytoremediation of multi-contaminated industrial soil using sunflower (Helianthus annuus L.).

PubMed

Liduino, Vitor S; Servulo, Eliana F C; Oliveira, Fernando J S

2018-06-07

This study evaluated the use of commercial rhamnolipid biosurfactant supplementation in the phytoremediation of a soil via sunflower (Helianthus annuus L.) cultivation. The soil, obtained from an industrial area, was co-contaminated with heavy metals and petroleum hydrocarbons. The remediation tests were monitored for 90 days. The best results for removal of contaminants were obtained from the tests in which the sunflower plants were cultivated in soil with 4 mg kg -1 of the rhamnolipid. Under these conditions, reductions of 58% and 48% were obtained in the total petroleum hydrocarbon (TPH) and polycyclic aromatic hydrocarbon (PAH) concentrations, respectively; reductions in the concentrations of the following metals were also achieved: Ni (41%), Cr (30%), Pb (29%), and Zn (20%). The PCR-DGGE analysis of soil samples collected before and after the treatments verified that the plant cultivation and biosurfactants supplementation had little effect on the structure of the dominant bacterial community in the soil. The results indicated that sunflower cultivation with the addition of a biosurfactant is a viable and efficient technology to treat soils co-contaminated with heavy metals and petroleum hydrocarbons.

Sensitivity of the Endogeic Tropical Earthworm Pontoscolex corethrurus to the Presence of Heavy Crude Oil.

PubMed

Del Carmen Cuevas-Díaz, María; Vázquez-Luna, Dinora; Martínez-Hernández, Sergio; Guzmán-López, Oswaldo; Ortíz-Ceballos, Angel I

2017-08-01

Contamination of soil with petroleum is common in oil-producing areas across the tropical regions of the world. There is limited knowledge on the sensitivity of endogeic tropical earthworms to the contamination of soil with total petroleum hydrocarbons (TPH) present in crude oil. Pontoscolex corethrurus is a dominant species in tropical agroecosystems around oil-processing facilities. The sensitivity of P. corethrurus to soil artificially contaminated with "Maya" Mexican heavy crude oil was investigated through avoidance and acute ecotoxicity tests, using the following measured concentrations: 0 (reference soil), 551, 969, 4845, 9991 and 14,869 mg/kg. The avoidance test showed that P. corethrurus displayed a significant avoidance behavior to heavy crude oil at a concentration of 9991 mg/kg or higher. In contrast, acute toxicity tests indicate that the median lethal concentration (LC 50 ) was 3067.32 mg/kg; however, growth (weight loss) was more sensitive than mortality. Our study revealed that P. corethrurus is sensitive to TPH, thus highlighting the importance of P. corethrurus for petroleum ecotoxicological tests.

PAH, PCB, TPH and mercury in surface sediments of the Delaware River Estuary and Delmarva Peninsula, USA.

PubMed

Kim, A W; Vane, C H; Moss-Hayes, V; Engelhart, S E; Kemp, A C

2018-04-01

Surface sediment concentrations of polycyclic aromatic hydrocarbons (PAH) and polychlorinated biphenyls (PCB), total petroleum hydrocarbons (TPH) and mercury, were compared from two areas with contrasting land use history, the industrial Delaware Estuary and the rural Delmarva Peninsula (USA). TPH in the Delaware (38-616mg/kg) and saturate/aromatic fractions suggested petroleum/industrial sources compared to biogenic sources in the Delmarva coastal control (<34-159mg/kg). Within the Delaware the ∑PAH18 ranged from 3749 to 22,324μg/kg with isomeric ratios indicative of petroleum combustion source/s, conversely, those in the Delmarva (5-2139μg/kg) also yielded relatively higher perylene that were consistent with natural background levels derived from vegetation/coal combustion source/s. ∑PCB(tri-hepta) concentrations in the Delmarva (0.6-6.5μg/kg) were less than the threshold effect concentration (TEC), whereas the Delaware had received much higher PCB loading (18.1-136.8μg/kg) as evidenced by a significantly higher amounts in some samples (>TEC). Copyright © 2017 Elsevier Ltd. All rights reserved.

Data sources and compilation: Chapter 27 in Petroleum systems and geologic assessment of oil and gas in the San Joaquin Basin Province, California

USGS Publications Warehouse

Klett, T.R.; Schmoker, James W.

2007-01-01

Geologic, production, and exploration/discovery-history data are used by the U.S. Geological Survey to aid in the assessment of petroleum resources. These data, as well as the broad knowledge and experience of the assessing geologists, are synthesized to provide, for each assessment unit, geologic and exploration models upon which estimates are made of the number and sizes of undiscovered accumulations for conventional assessment units or number and total recoverable volumes of untested cells for continuous assessment units (input data for resource calculations). Quantified geologic information and trends in production and exploration/discovery-history data with respect to time and exploration effort provide guides for the estimating parameters of variables recorded on the input-data forms (input data) used to calculate petroleum resources. An Assessment Review Team reviews proposed geologic and exploration models and input data for each assessment unit in formal assessment meetings. The Assessment Review Team maintains the accuracy and consistency of the assessment procedure during the formal assessment meetings.

Bio-electrochemical remediation of real field petroleum sludge as an electron donor with simultaneous power generation facilitates biotransformation of PAH: effect of substrate concentration.

PubMed

Chandrasekhar, K; Venkata Mohan, S

2012-04-01

Remediation of real-field petroleum sludge was studied under self-induced electrogenic microenvironment with the function of variable organic loads (OLs) in bio-electrochemical treatment (BET) systems. Operation under various OLs documented marked influence on both electrogenic activity and remediation efficiency. Both total petroleum hydrocarbons (TPH) and its aromatic fraction documented higher removal with OL4 operation followed by OL3, OL2, OL1 and control. Self-induced biopotential and associated multiple bio-electrocatalytic reactions during BET operation facilitated biotransformation of higher ring aromatics (5-6) to lower ring aromatic (2-3) compounds. Asphaltenes and NSO fractions showed negligible removal during BET operation. Higher electrogenic activity was recorded at OL1 (343mV; 53.11mW/m(2), 100Ω) compared to other three OLs operation. Bioaugmentation to anodic microflora with anaerobic culture documented enhanced electrogenic activity at OL4 operation. Voltammetric profiles, Tafel analysis and VFA generation were in agreement with the observed power generation and degradation efficiency. Copyright © 2012 Elsevier Ltd. All rights reserved.

Assessment of undiscovered technically recoverable conventional petroleum resources of northern Afghanistan

USGS Publications Warehouse

Klett, T.R.; Ulmishek, G.F.; Wandrey, C.J.; Agena, Warren F.; Steinshouer, Douglas

2006-01-01

Using a geology-based assessment methodology, the U.S. Geological Survey - Afghanistan Ministry of Mines and Industry Joint Oil and Gas Resource Assessment Team estimated mean volumes of undiscovered petroleum in northern Afghanistan; the resulting estimates are 1.6 billion barrels (0.2 billion metric tons) of crude oil, 16 trillion cubic feet (0.4 trillion cubic meters) of natural gas, and 0.5 billion barrels (0.8 billion metric tons) of natural gas liquids. Most of the undiscovered crude oil is in the Afghan-Tajik Basin and most of the undiscovered natural gas is in the Amu Darya Basin. Four total petroleum systems were identified, and these were subdivided into eight assessment units for the purpose of this resource assessment. The area with the greatest potential for undiscovered natural gas accumulations is in Upper Jurassic carbonate and reef reservoirs beneath an impermeable salt layer in relatively unexplored parts of northern Afghanistan. The Afghan-Tajik Basin has the greatest potential for undiscovered crude oil accumulations, and these are potentially in Cretaceous to Paleogene carbonate reservoir rocks associated with thrust faulting and folding.

Coprocessing of plastics with coal and petroleum resid

DOE Office of Scientific and Technical Information (OSTI.GOV)

Joo, H.; Curtis, C.W.

1995-12-31

Waste plastics have become an increasing problem in the United States since land filling is no longer considered a feasible disposal method. Since plastics are petroleum-derived materials, coprocessing then with coal to produce transportation fuels is a feasible alternative. In this study, catalytic coprocessing reactions were performed using Blind Canyon bituminous coal, Manji petroleum resid, and waste plastics. Model polymers including polystyrene, low density polyethylene (LDPE) and polyethylene tereplithalare (PET) were selected because they represent a substantial portion of the waste plastics generated in the United States. Coprocessing reactions of coal, resid, and polymer as well as reactions of individualmore » components and combinations of two components were performed at 430{degrees}C for one hour with an initial H{sub 2} pressure of 8.5 MPa introduced at ambient temperature with presulfided NiMo/Al{sub 2}O{sub 3} as catalyst. Coprocessing all three materials resulted in a substantial improvement in the total conversion compared to the coal plus polymer reaction and slightly less conversion than the resid plus polymer combinations.« less

Potential biodegradation of crude petroleum oil by newly isolated halotolerant microbial strains from polluted Red Sea area.

PubMed

Shetaia, Yousseria M H; El Khalik, Wafaa A A; Mohamed, Tarek M; Farahat, Laila A; ElMekawy, Ahmed

2016-10-15

Two microbial isolates from oil polluted Red Sea water in Egypt, designated as RS-Y1 and RS-F3, were found capable of degrading Belayim mix (BX) crude oil. Strains RS-Y1 and RS-F3 were assigned to the genera Lipomyces tetrasporus and Paecilomyces variotii based on their morphological and physiological characteristics. Both isolates were compared for the biodegradation of crude petroleum-oil hydrocarbons in basal salt medium supplemented with 5% (w/v) of BX-crude oil. Gas chromatography profile showed that the biodegradation of total petroleum hydrocarbons (TPHs) inoculated with L. tetrasporus (68.3%) and P. variotii (58.15%) along with their consortium (66%) significantly reduced TPHs levels as compared to the control after 30days. L. tetrasporus (44.5%) was more effective than P. variotii strain (32.89%) in reducing the unresolved complex mixtures (UCM) content from the medium. Both isolates exhibited a strong growth over a wide range of salinity (5-45g/L NaCl). Copyright © 2016 Elsevier Ltd. All rights reserved.

Microbiological characteristics of multi-media PRB reactor in the bioremediation of groundwater contaminated by petroleum hydrocarbons.

PubMed

Liu, Hong; Zhang, Lanying; Deng, Haijing; Liu, Na; Liu, Cuizhu

2011-10-01

A multi-media bio-PRB reactor was designed to treat groundwater contaminated with petroleum hydrocarbons. After a 208-day bioremediation, combined with the total petroleum hydrocarbons content in the groundwater flowed through the reactor, microbiological characteristics of the PRB reactor including microbes immobilized and its dehydrogenase activity were investigated. TPH was significantly reduced by as much as 65% in the back of the second media layer, whereas in the third layer, the TPH content reached lower than 1 mg l⁻¹. For microbes immobilized on the media, the variations with depth in different media were significantly the same and the regularity was obvious in the forepart of the media, which increased with depth at first and then reduced gradually, while in the back-end, the microbes almost did not have any variations with depth but decreased with the distance. The dehydrogenase activity varied from 2.98 to 16.16 mg TF L⁻¹ h⁻¹ and its distribution illustrated a similar trend with numbers of microbial cell, therefore, the noticeable correlation was found between them.

Comparison of trees and grasses for rhizoremediation of petroleum hydrocarbons.

PubMed

Cook, Rachel L; Hesterberg, Dean

2013-01-01

Rhizoremediation of petroleum contaminants is a phytoremediation process that depends on interactions among plants, microbes, and soils. Trees and grasses are commonly used for phytoremediation, with trees typically being chosen for remediation of BTEX while grasses are more commonly used for remediation of PAHs and total petroleum hydrocarbons. The objective of this review was to compare the effectiveness of trees and grasses for rhizoremediation of hydrocarbons and address the advantages of each vegetation type. Grasses were more heavily represented in the literature and therefore demonstrated a wider range of effectiveness. However, the greater biomass and depth of tree roots may have greater potential for promoting environmental conditions that can improve rhizoremediation, such as increased metabolizable organic carbon, oxygen, and water. Overall, we found little difference between grasses and trees with respect to average reduction of hydrocarbons for studies that compared planted treatments with a control. Additional detailed investigations into plant attributes that most influence hydrocarbon degradation rates should provide data needed to determine the potential for rhizoremediation with trees or grasses for a given site and identify which plant characteristics are most important.

Petroleum systems of the Po Basin Province of northern Italy and the northern Adriatic Sea; Porto Garibaldi (biogenic), Meride/Riva di Solto (thermal), and Marnoso Arenacea (thermal)

USGS Publications Warehouse

Lindquist, Sandra J.

1999-01-01

The Porto Garibaldi total petroleum system dominates the Po Basin Province of onshore northern Italy and offshore Italy and Croatia in the northern Adriatic Sea. Porto Garibaldi contains Pliocene (primarily) and Pleistocene (secondarily) biogenic gas ? approximately 16 TCF (2.66 BBOE) ultimately recoverable ? accumulated in co-eval siliciclastic reservoirs. This area was the northwestern edge of the Gondwanan (African) continental plate in pre-Hercynian time until the assembly of Pangea, a dominantly carbonate passive continental margin during the Mesozoic breakup of Pangea, and a Cenozoic collision zone with siliciclastic foredeep and foreland regions surrounded by thrust belts. At least two other petroleum systems, with Triassic (Meride / Riva di Solto) and Miocene (Marnoso Arenacea) source rocks, contribute oil and thermal gas reserves (nearly 1 BBOE) to the province. The major time of hydrocarbon expulsion of the thermal systems was Late Neogene during the Alpine and Apennine orogenies. Local Mesozoic oil expulsion from Triassic rocks also occurred, but those oils either were not trapped or were leaked from faulty traps through time.

The application of petroleum hydrocarbon fingerprint characterization in site investigation and remediation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zemo, D.A.; Bruya, J.E.; Graf, T.E.

1995-07-01

Tremendous resources have been and continue to be spent investigating and remediating petroleum hydrocarbon compounds (PHCs) in soil and ground water. Investigating and planning a remedial strategy for sites affected by PHCs is often a challenging task because of the complex chemical nature of the PHCs, the complex regulatory environment related to PHC cleanup, and the use of analytical methods that provide quantitation but not identification f PHCs. From a technical standpoint, the PHC impacting soil and/or ground water is frequently inadequately characterized, both in identification as well as in its general properties (solubility, toxicity). From a regulatory standpoint, promulgatedmore » or recommended total petroleum hydrocarbon (TPH) cleanup levels generally relate to assumed properties of specific unweathered products and are inconsistent among different agencies and regions. Accurately identifying the PHC and its nature, a process known as fingerprint characterization, is critical to the determination of appropriate regulatory goals and design of cost-effective remedial approaches. This paper presents several case studies in which fingerprint characterization made a significant difference in the project outcome.« less

31 CFR 576.308 - Iraqi petroleum and petroleum products.

Code of Federal Regulations, 2013 CFR

2013-07-01

... (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY IRAQ STABILIZATION AND INSURGENCY... petroleum and petroleum products means any petroleum, petroleum products, or natural gas originating in Iraq, including any Iraqi-origin oil inventories, wherever located. ...

31 CFR 576.308 - Iraqi petroleum and petroleum products.

Code of Federal Regulations, 2014 CFR

2014-07-01

... (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY IRAQ STABILIZATION AND INSURGENCY... petroleum and petroleum products means any petroleum, petroleum products, or natural gas originating in Iraq, including any Iraqi-origin oil inventories, wherever located. ...

31 CFR 576.308 - Iraqi petroleum and petroleum products.

Code of Federal Regulations, 2012 CFR

2012-07-01

... (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY IRAQ STABILIZATION AND INSURGENCY... petroleum and petroleum products means any petroleum, petroleum products, or natural gas originating in Iraq, including any Iraqi-origin oil inventories, wherever located. ...

The change of CO2 emission on manufacturing sectors in Indonesia: An input-output analysis

NASA Astrophysics Data System (ADS)

Putranti, Titi Muswati; Imansyah, Muhammad Handry

2017-12-01

The objective of this paper is to evaluate the change of CO2 emission on manufacturing sectors in Indonesia using input-output analysis. The method used supply perspective can measure the impact of an increase in the value added of different productive on manufacturing sectors on total CO2 emission and can identify the productive sectors responsible for the increase in CO2 emission when there is an increase in the value added of the economy. The data used are based on Input-Output Energy Table 1990, 1995 and 2010. The method applied the elasticity of CO2 emission to value added. Using the elasticity approach, one can identify the highest elasticity on manufacturing sector as the change of value added provides high response to CO2 emission. Therefore, policy maker can concentrate on manufacturing sectors with the high response of CO2 emission due to the increase of value added. The approach shows the contribution of the various sectors that deserve more consideration for mitigation policy. Five of highest elasticity of manufacturing sectors of CO2 emission are Spinning & Weaving, Other foods, Tobacco, Wearing apparel, and other fabricated textiles products in 1990. Meanwhile, the most sensitive sectors Petroleum refinery products, Other chemical products, Timber & Wooden Products, Iron & Steel Products and Other non-metallic mineral products in 1995. Two sectors of the 1990 were still in the big ten, i.e. Spinning & weaving and Other foods in 1995 for the most sensitive sectors. The six sectors of 1995 in the ten highest elasticity of CO2 emission on manufacturing which were Plastic products, Other chemical products,Other fabricated metal products, Cement, Iron & steel products, Iron & steel, still existed in 2010 condition. The result of this research shows that there is a change in the most elastic CO2 emission of manufacturing sectors which tends from simple and light manufacturing to be a more complex and heavier manufacturing. Consequently, CO2 emission jumped significantly.

Effect of initial oil concentration and dispersant on crude oil biodegradation in contaminated seawater.

PubMed

Zahed, Mohammad Ali; Aziz, Hamidi Abdul; Isa, Mohamed Hasnain; Mohajeri, Leila

2010-04-01

The effects of initial oil concentration and the Corexit 9500 dispersant on the rate of bioremediation of petroleum hydrocarbons were investigated with a series of ex-situ seawater samples. With initial oil concentrations of 100, 500, 1,000 and 2,000 mg/L, removal of total petroleum hydrocarbons (TPHs) with dispersant were 67.3%, 62.5%, 56.5% and 44.7%, respectively, and were 64.2%, 55.7%, 48.8% and 37.6% without dispersant. The results clearly indicate that the presence of dispersant enhanced crude oil biodegradation. Lower concentrations of crude oil demonstrated more efficient hydrocarbon removal. Based on these findings, bioremediation is not recommended for crude oil concentrations of 2,000 mg/L or higher.

Diatoms: a fossil fuel of the future.

PubMed

Levitan, Orly; Dinamarca, Jorge; Hochman, Gal; Falkowski, Paul G

2014-03-01

Long-term global climate change, caused by burning petroleum and other fossil fuels, has motivated an urgent need to develop renewable, carbon-neutral, economically viable alternatives to displace petroleum using existing infrastructure. Algal feedstocks are promising candidate replacements as a 'drop-in' fuel. Here, we focus on a specific algal taxon, diatoms, to become the fossil fuel of the future. We summarize past attempts to obtain suitable diatom strains, propose future directions for their genetic manipulation, and offer biotechnological pathways to improve yield. We calculate that the yields obtained by using diatoms as a production platform are theoretically sufficient to satisfy the total oil consumption of the US, using between 3 and 5% of its land area. Copyright © 2014 Elsevier Ltd. All rights reserved.

Research of Isolation and Degradation Conditions of Petroleum Degrading Marine

NASA Astrophysics Data System (ADS)

Fangrui, Guo

2017-01-01

A novel petroleum-degrading microbial strain was isolated from sediment samples in estuary of Bohai Sea estuary beaches. The strain was primarily identified as Alcanivorax sp. and named Alcanivorax sp. H34. Effect of PH values, temperature, nitrogen and phosphorus concentrations on degradation of H34 were investigated. The paraffinic components average degradation rate of H34 ungrowth cells under optimized conditions was studied. The results showed that the optimal growth conditions of H34 are were temperature of 30°C, initial PH of 7.0, nitrogen concentration of 3g/L, phosphorus concentration of 3g/L, and paraffinic components average degradation rates of H34 ungrowth cells was 41.6%, while total degradation rate was 45.5%.

Response of the microbial community to seasonal groundwater level fluctuations in petroleum hydrocarbon-contaminated groundwater.

PubMed

Zhou, Ai-xia; Zhang, Yu-ling; Dong, Tian-zi; Lin, Xue-yu; Su, Xiao-si

2015-07-01

The effects of seasonal groundwater level fluctuations on the contamination characteristics of total petroleum hydrocarbons (TPH) in soils, groundwater, and the microbial community were investigated at a typical petrochemical site in northern China. The measurements of groundwater and soil at different depths showed that significant TPH residue was present in the soil in this study area, especially in the vicinity of the pollution source, where TPH concentrations were up to 2600 mg kg(-1). The TPH concentration in the groundwater fluctuated seasonally, and the maximum variation was 0.8 mg L(-1). The highest TPH concentrations were detected in the silty clay layer and lied in the groundwater level fluctuation zones. The groundwater could reach previously contaminated areas in the soil, leading to higher groundwater TPH concentrations as TPH leaches into the groundwater. The coincident variation of the electron acceptors and TPH concentration with groundwater-table fluctuations affected the microbial communities in groundwater. The microbial community structure was significantly different between the wet and dry seasons. The canonical correspondence analysis (CCA) results showed that in the wet season, TPH, NO3(-), Fe(2+), TMn, S(2-), and HCO3(-) were the major factors correlating the microbial community. A significant increase in abundance of operational taxonomic unit J1 (97% similar to Dechloromonas aromatica sp.) was also observed in wet season conditions, indicating an intense denitrifying activity in the wet season environment. In the dry season, due to weak groundwater level fluctuations and low temperature of groundwater, the microbial activity was weak. But iron and sulfate-reducing were also detected in dry season at this site. As a whole, groundwater-table fluctuations would affect the distribution, transport, and biodegradation of the contaminants. These results may be valuable for the control and remediation of soil and groundwater pollution at this site and in other petrochemical-contaminated areas. Furthermore, they are probably helpful for reducing health risks to the general public from contaminated groundwater.

Hydrocarbonoclastic bacteria isolated from petroleum contaminated sites in Tunisia: isolation, identification and characterization of the biotechnological potential.

PubMed

Mahjoubi, Mouna; Jaouani, Atef; Guesmi, Amel; Ben Amor, Sonia; Jouini, Ahlem; Cherif, Hanen; Najjari, Afef; Boudabous, Abdellatif; Koubaa, Nedra; Cherif, Ameur

2013-09-25

Petroleum hydrocarbons are important energy resources used by industry and in our daily life, whose production contributes highly to environmental pollution. To control such risk, bioremediation constitutes an environmentally friendly alternative technology that has been established and applied. It constitutes the primary mechanism for the elimination of hydrocarbons from contaminated sites by natural existing populations of microorganisms. In this work, a collection of 125 strains, adapted to grow on minimal medium supplemented with crude oil, was obtained from contaminated sediments and seawater from a refinery harbor of the Bizerte coast in the North of Tunisia. The diversity of the bacterial collection was analyzed by amplification of the internal transcribed spacers between the 16S and the 23S rRNA genes (ITS-PCR) and by 16S rRNA sequencing. A total of 36 distinct ITS haplotypes were detected on agarose matrix. Partial 16S rRNA gene sequencing performed on 50 isolates showed high level of identity with known sequences. Strains were affiliated to Ochrabactrum, Sphingobium, Acinetobacter, Gordonia, Microbacterium, Brevundimonas, Novosphingobium, Stenotrophomonas, Luteibacter, Rhodococcus, Agrobacterium, Achromobacter, Bacilllus, Kocuria and Pseudomonas genera. Acinetobacter and Stenotrophomons were found to be the most abundant species characterized by a marked microdiversity as shown through ITS typing. Culture-independent approach (DGGE) showed high diversity in the microbial community in all the studied samples with a clear correlation with the hydrocarbon pollution rate. Sequencing of the DGGE bands revealed a high proportion of Proteobacteria represented by the Alpha and Gamma subclasses. The predominant bacterial detected by both dependent and independent approaches were the Proteobacteria. The biotechnological potential of the isolates revealed a significant production of biosurfactants with important emulsification activities useful in bioremediation. The highest emulsification activity was detected in Pseudomonas geniculata with 52.77% of emulsification. Our overall results suggest that the obtained bacterial isolates may constitute potential candidates for bioremediation and can be useful for biotechnological applications. Copyright © 2013 Elsevier B.V. All rights reserved.

40 CFR 52.28 - Protection of visibility from sources in nonattainment areas.

Code of Federal Regulations, 2013 CFR

2013-07-01

... categories: (A) Coal cleaning plants (with thermal dryers); (B) Kraft pulp mills; (C) Portland cement plants...) Phosphate rock processing plants; (M) Coke oven batteries; (N) Sulfur recovery plants; (O) Carbon black... thereof) totaling more than 250 million British thermal units per hour heat input; (V) Petroleum storage...

40 CFR 52.28 - Protection of visibility from sources in nonattainment areas.

Code of Federal Regulations, 2010 CFR

2010-07-01

... categories: (A) Coal cleaning plants (with thermal dryers); (B) Kraft pulp mills; (C) Portland cement plants...) Phosphate rock processing plants; (M) Coke oven batteries; (N) Sulfur recovery plants; (O) Carbon black... thereof) totaling more than 250 million British thermal units per hour heat input; (V) Petroleum storage...

40 CFR 52.28 - Protection of visibility from sources in nonattainment areas.

Code of Federal Regulations, 2012 CFR

2012-07-01

... categories: (A) Coal cleaning plants (with thermal dryers); (B) Kraft pulp mills; (C) Portland cement plants...) Phosphate rock processing plants; (M) Coke oven batteries; (N) Sulfur recovery plants; (O) Carbon black... thereof) totaling more than 250 million British thermal units per hour heat input; (V) Petroleum storage...

40 CFR 52.28 - Protection of visibility from sources in nonattainment areas.

Code of Federal Regulations, 2014 CFR

2014-07-01

... categories: (A) Coal cleaning plants (with thermal dryers); (B) Kraft pulp mills; (C) Portland cement plants...) Phosphate rock processing plants; (M) Coke oven batteries; (N) Sulfur recovery plants; (O) Carbon black... thereof) totaling more than 250 million British thermal units per hour heat input; (V) Petroleum storage...

40 CFR 52.28 - Protection of visibility from sources in nonattainment areas.

Code of Federal Regulations, 2011 CFR

2011-07-01

... categories: (A) Coal cleaning plants (with thermal dryers); (B) Kraft pulp mills; (C) Portland cement plants...) Phosphate rock processing plants; (M) Coke oven batteries; (N) Sulfur recovery plants; (O) Carbon black... thereof) totaling more than 250 million British thermal units per hour heat input; (V) Petroleum storage...

EVALUATING THE IMPACTS OF ENVIRONMENTAL ENFORCEMENT: THE CASE OF EFFLUENT DISCHARGES IN THE PETROLEUM REFINING INDUSTRY

EPA Science Inventory

This paper looks at the impact of enforcement activity on facility-level behavior and derives quantitative estimates of the impact. We measure facility-level behavior as the levels of Biological Oxygen Demand (BOD) and Total Suspended Solids (TSS) pollutant discharges generated b...

QUANTITATIVE ELISA OF POLYCHLORINATED BIPHENYLS IN AN OILY SOIL MATRIX USING SUPERCRITICAL FLUID EXTRACTION

EPA Science Inventory

Soil samples from the GenCorp Lawrence Brownfields site were analyzed with a commercial semi-quantitative enzyme-linked immunosorbent assay (ELISA) using a methanol shake extraction. Many of the soil samples were extremely oily, with total petroleum hydrocarbon levels up to 240...

INNOVATIVE TECHNOLOGY VERIFICATION REPORT "FIELD MEASUREMENT TECHNOLOGIES FOR TOTAL PETROLEUM HYDROCARBONS IN SOIL" DEXSIL CORPORATION PETROFLAG SYSTEM

EPA Science Inventory

The PetroFLAGTm System developed by Dexsilo Corporation (Dexsil) was demonstrated under the U.S. Environmental Protection Agency Superfund Innovative Technology Evaluation Program in June 2000 at the Navy Base Ventura County site in Port Hueneme, California. The purpose o...

GREENHOUSE GASES FROM BIOMASS AND FOSSIL FUEL STOVES IN DEVELOPING COUNTRIES: A MANILA PILOT STUDY

EPA Science Inventory

Samples were taken of the combustion gases released by household cookstoves in Manila, Philippines. In a total of 24 samples, 14 cookstoves were tested. These were fueled by liquefied petroleum gas (LPG), kerosene (three kinds of stoves), charcoal, and wood. Ambient samples were ...

Hazardous Waste Cleanup: Industrial Oil Tank Services, Inc. in Verona, New York

EPA Pesticide Factsheets

Industrial Oil Tank Services, Inc. operated as a petroleum recovery facility in the town of Verona in Oneida County from mid-1970’s through 1992. The site stored hazardous wastes in 23 steel tanks of various sizes with a total combined capacity of

Compendium of Arab exploratory wells and petroleum fields, 1985 edition

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1985-01-01

This book provides a compilation of primary and secondary information giving well name and province, operating company, completion date, exploration technique, bottom home formation, total depth, producing formations, lithology, geologic age, drilling results, and geologic, petrophysical, and production data. It covers all the Arab countries in a new format.

Energy resources of the United States

USGS Publications Warehouse

Theobald, P.K.; Schweinfurth, Stanley P.; Duncan, Donald Cave

1972-01-01

Estimates are made of United States resources of coal, petroleum liquids, natural gas, uranium, geothermal energy, and oil from oil shale. The estimates, compiled by specialists of the U.S. Geological Survey, are generally made on geologic projections of favorable rocks and on anticipated frequency of the energy resource in the favorable rocks. Accuracy of the estimates probably ranges from 20 to 50 percent for identified-recoverable resources to about an order of magnitude for undiscovered-submarginal resources. The total coal resource base in the United States is estimated to be about 3,200 billion tons, of which 200-390 billion tons can be considered in the category identified and recoverable. More than 70 percent of current production comes from the Appalachian basin where the resource base, better known than for the United States as a whole, is about 330 billion tons, of which 22 billion tons is identified and recoverable. Coals containing less than 1 percent sulfur are the premium coals. These are abundant in the western coal fields, but in the Appalachian basin the resource base for low-sulfur coal is estimated to be only a little more than 100 billion tons, of which 12 billion tons is identified and recoverable. Of the many estimates of petroleum liquids and natural-gas resources, those of the U.S. Geological Survey are the largest because, in general, our estimates include the largest proportion of favorable ground for exploration. We estimate the total resource base for petroleum liquids to be about 2,900 billion barrels, of which 52 billion barrels is identified and recoverable. Of the total resource base, some 600 billion barrels is in Alaska or offshore from Alaska, 1,500 billion barrels is offshore from the United States, and 1,300 billion barrels is onshore in the conterminous United States. Identified-recoverable resources of petroleum liquids corresponding to these geographic units are 11, 6, and 36 billion barrels, respectively. The total natural-gas resource of the United States is estimated to be about 6,600 trillion cubic feet, of which 290 trillion cubic feet is identified and recoverable. In geographic units comparable to those for petroleum liquids, the resource bases are 1,400, 3,400, and 2,900 trillion cubic feet, and the identified-recoverable resources are 31, 40, and 220 trillion cubic feet, respectively. Uranium resources in conventional deposits, where uranium is the major product, are estimated at 1,600,000 tons of U3O8, of which 250,000 tons is identified and recoverable. A potential byproduct resource of more than 7 million tons of U3O8, is estimated for phosphate rock, but none of this resource is recoverable under present economic conditions. The resources of heat in potential geothermal energy sources are poorly known. The total resource base for the United States is certainly greater than 10 22 calories, of which only 2.5 ? 10 18 calories can be considered identified and recoverable at present. Oil shale is estimated to contain 26 trillion barrels of oil. None of this resource is economic at present, but if prices increase moderately, 160-600 billion barrels of this oil could be shifted into the identified-recoverable category.

Petroleum supply monthly, with data for September 1995

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

1995-11-01

The Petroleum Supply Monthly (PSM) is one of a family of four publications produced by the Petroleum Supply Division within the Energy Information Administration (EIA) reflecting different levels of data timeliness and completeness. The other publications are the Weekly Petroleum Status Report (WPSR), the Winter Fuels Report, and the Petroleum Supply Annual (PSA). Data presented in the PSM describe the supply and disposition of petroleum products in the United States and major U.S. geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products inmore » the United States (50 States and the District of Columbia). The reporting universe includes those petroleum sectors in primary supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated, the data reported by these sectors approximately represent the consumption of petroleum products in the United States.« less

Assessment of Appalachian Basin Oil and Gas Resources: Carboniferous Coal-bed Gas Total Petroleum System

USGS Publications Warehouse

Milici, Robert C.

2004-01-01

The Carboniferous Coal-bed Gas Total Petroleum System, lies within the central and northern parts of the Appalachian coal field. It consists of five assessment units (AU): the Pocahontas Basin in southwestern Virginia, southern West Virginia, and eastern Kentucky, the Central Appalachian Shelf in Tennessee, eastern Kentucky and southern West Virginia, East Dunkard (Folded) in western Pennsylvania and northern West Virginia, West Dunkard (Unfolded) in Ohio and adjacent parts of Pennsylvania and West Virginia, and the Appalachian Anthracite and Semi-Anthracite AU in Pennsylvania and Virginia. Of these, only the Pocahontas Basin and West Dunkard (Folded) AU were assessed quantitatively by the U.S. Geological survey in 2002 as containing about 3.6 and 4.8 Tcf of undiscovered, technically recoverable gas, respectively (Milici and others, 2003). In general, the coal beds of this Total Petroleum System, which are both the source rock and reservoir, were deposited together with their associated sedimentary strata in Mississippian and Pennsylvanian (Carboniferous) time. The generation of biogenic (microbial) gas probably began almost immediately as the peat deposits were first formed. Microbial gas generation is probably occurring at present to some degree throughout the basin, where the coal beds are relatively shallow and wet. With sufficient depth of burial, compaction, and coalification during the late Paleozoic and Early Mesozoic, the coal beds were heated sufficiently to generate thermogenic gas in the eastern part of the Appalachian basin. Trap formation began initially with the deposition of the paleopeat deposits during the Mississippian, and continued into the Late Pennsylvanian and Permian as the Appalachian Plateau strata were deformed during the Alleghanian orogeny. Seals are the connate waters that occupy fractures and larger pore spaces within the coal beds as well as the fine-grained siliciclastic sedimentary strata that are intercalated with the coal. The critical moment for the petroleum system occurred during this orogeny, when deformation created geologic structures in the eastern part of the basin that enhanced fracture porosity within the coal beds. In places, burial by thrust sheets (thrust loading) within the Appalachian fold-and-thrust belt may have resulted in additional generation of thermogenic CBM in the anthracite district of Pennsylvania and in the semianthracite deposits of Virginia and West Virginia.

Antioxidant capacity and phenolic compounds of Lonicerae macranthoides by HPLC-DAD-QTOF-MS/MS.

PubMed

Hu, Xin; Chen, Lin; Shi, Shuyun; Cai, Ping; Liang, Xuejuan; Zhang, Shuihan

2016-05-30

Lonicerae macranthoides with strong antioxidant activity is commonly used in traditional Chinese medicine and folk tea/beverage. However, detailed information about its antioxidant activity and bioactive compounds is limited. Then at first, we comparatively evaluated total phenolic content (TPC), total flavonoid content (TFC) and antioxidant activities of water extract, petroleum ether, ethyl acetate and n-butanol fractions of L. macranthoides. Ethyl acetate fraction exhibited the highest level of TPC (207.38 mg GAE/g DW), TFC (53.06 mg RE/g DW) and the best DPPH scavenge activity and reducing power. n-Butanol fraction showed the best ABTS(+) and O2(-) scavenging activities. Interestingly, water extract, ethyl acetate and n-butanol fractions showed stronger antioxidant activities than positive control, butylated hydroxytoluene (BHT). After that, thirty-one antioxidant phenolic compounds, including twenty-two phenolic acids and nine flavonoids, were screened by DPPH-HPLC experiment and then identified using HPLC-DAD-QTOF-MS/MS. It is noted that twenty-one compounds (1, 3-4, 6-17, 19, 23, 26, 28-29, and 31), as far as was known, were discovered from L. macranthoide for the first time, and eleven of them (3-4, 10-17, and 23) were reported in Lonicera species for the first time. Results indicated that L. macranthoides could serve as promising source of rich antioxidants in foods, beverages and medicines for health promotion. Copyright © 2016 Elsevier B.V. All rights reserved.

Bioremediation of oil-based drill cuttings by a halophilic consortium isolated from oil-contaminated saline soil.

PubMed

Rezaei Somee, Maryam; Shavandi, Mahmoud; Dastgheib, Seyed Mohammad Mehdi; Amoozegar, Mohammad Ali

2018-05-01

Oil-based drill cuttings are hazardous wastes containing complex hydrocarbons, heavy metals, and brine. Their remediation is a crucial step before release to the environment. In this work, we enriched a halophilic consortium, from oil-polluted saline soil, which is capable of degrading diesel as the main pollutant of oil-based drill cuttings. The degradation ability of the consortium was evaluated in microcosms using two different diluting agents (fine sand and biologically active soil). During the bioremediation process, the bacterial community dynamics of the microcosms was surveyed using PCR amplification of a fragment of 16S rRNA gene followed by denaturing gradient gel electrophoresis (DGGE). The diesel degradation rates were monitored by total petroleum hydrocarbon (TPH) measurement and the total count of heterotrophic and diesel-degrading bacteria. After 3 months, the microcosm containing fine sand and drill cuttings with the ratio of 1:1 (initial TPH of 36,000 mg/kg) showed the highest TPH removal (40%) and its dominant bacterial isolates belonged to the genera Dietzia, Arthrobacter , and Halomonas . DGGE results also confirmed the role of these genera in drill cuttings remediation. DGGE analysis of the bacterial diversity showed that Propionibacterium, Salinimicrobium, Marinobacter , and Dietzia are dominant in active soil microcosm; whereas Bacillus, Salinibacillus , and Marinobacter are abundant in sand microcosm. Our results suggest that the bioaugmentation strategy would be more successful if the diluting agent does not contain a complex microbial community.

Bio-treatment of oily sludge: the contribution of amendment material to the content of target contaminants, and the biodegradation dynamics.

PubMed

Kriipsalu, Mait; Marques, Marcia; Nammari, Diauddin R; Hogland, William

2007-09-30

The objective was to investigate the aerobic biodegradation of oily sludge generated by a flotation-flocculation unit (FFU) of an oil refinery wastewater treatment plant. Four 1m(3) pilot bioreactors with controlled air-flow were filled with FFU sludge mixed with one of the following amendments: sand (M1); matured oil compost (M2); kitchen waste compost (M3) and shredded waste wood (M4). The variables monitored were: pH, total petroleum hydrocarbons (TPHs), polycyclic aromatic hydrocarbons (PAHs), total carbon (C(tot)), total nitrogen (N(tot)) and total phosphorus (P(tot)). The reduction of TPH based on mass balance in M1, M2, M3 and M4 after 373 days of treatment was 62, 51, 74 and 49%; the reduction of PAHs was 97%, +13% (increase), 92 and 88%, respectively. The following mechanisms alone or in combination might explain the results: (i) most organics added with amendments biodegrade faster than most petroleum hydrocarbons, resulting in a relative increase in concentration of these recalcitrant contaminants; (ii) some amendments result in increased amounts of TPH and PAHs to be degraded in the mixture; (iii) sorption-desorption mechanisms involving hydrophobic compounds in the organic matrix reduce bioavailability, biodegradability and eventually extractability; (iv) mixture heterogeneity affecting sampling. Total contaminant mass reduction seems to be a better parameter than concentration to assess degradation efficiency in mixtures with high content of biodegradable amendments.

Effects of Oil Spillage on Vegetation, Land and Water Odu-Gboro Sagamu, Ogun State, South-Western Nigeria) Using Remote Sensing and GIS Techniques.

NASA Astrophysics Data System (ADS)

Oseni, O.

2016-12-01

This paper explores the impacts of oil spill on the physical environment with particular attention paid to the NNPC/PPMC pipeline system. It focuses on the environmental impacts of oil pollution in Nigeria, and discusses the increasing environmental contradictions of the area, and its influence on global warming. Nigeria's economy is highly dependent on earnings from the oil sector, which provides 20% of GDP, 95% of foreign exchange earnings, and about 65% of budgetary revenues. Since the discovery of oil in Nigeria in 1956, the country has been suffering the negative environmental consequences of oil exploration and exploitation. Between 1976 and 1996 a total of 4647 incidents resulted in the spill of approximately 2,369,470 barrels of oil into the environment. The study traces the effects of the oil spillage on the environment to determine whether oil spill is a major factor responsible for environmental pollution. By the use of remotely sensed data and other ancillary data, the major causes of oil spill in the region were identified; the presence of total petroleum hydrocarbon (TPH) in the environment, and it also determined the environmental impacts on land and water. Field observation and laboratory analysis of soil and water were used. Gas chromatography was used to determine the TPH concentration in soil extract and water extracts. Liquid-liquid extraction method was used for water and spectro-radiometer which is a very efficient process commonly used to determine spectral signature of various soil, water and plant samples obtained from the study area. Based largely on the GIS analysis, the findings showed that the main cause of oil spill is vandalism along the pipeline right of way; Vandalism which is an act of sabotage had the highest percentage compared to equipment failure, accident from oil tankers and accidental discharge during pipeline repairs. TPH were present at the site with soil samples having the high values, and the environmental impact on soil and water is due to poor resource management and control. Satellite imagery (Ikonos and Landsat series) helped in monitoring oil spill by providing the spill position. The petroleum industries should work with government agencies, universities and research centers to prevent oil spill incidents. Keywords: Environment, Pollution, GIS, TPH, Analysis, Vandalism.

Biodegradation of Spilled Diesel Fuel in Agricultural Soil: Effect of Humates, Zeolite, and Bioaugmentation

PubMed Central

Kuráň, Pavel; Nováková, Jana; Pilařová, Věra; Dáňová, Petra; Pavlorková, Jana; Kozler, Josef; Novák, František

2014-01-01

Possible enhancement of biodegradation of petroleum hydrocarbons in agricultural soil after tank truck accident (~5000 mg/kg dry soil initial concentration) by bioaugmentation of diesel degrading Pseudomonas fluorescens strain and addition of abiotic additives (humates, zeolite) was studied in a 9-month pot experiment. The biodegradation process was followed by means of analytical parameters (hydrocarbon index expressed as content of C10–C40 aliphatic hydrocarbons, ratio pristane/C17, and total organic carbon content) and characterization of soil microbial community (content of phospholipid fatty acids (PLFA) as an indicator of living microbial biomass, respiration, and dehydrogenase activity). The concentration of petroleum hydrocarbons (C10–C40) was successfully reduced by ~60% in all 15 experiment variants. The bioaugmentation resulted in faster hydrocarbon elimination. On the contrary, the addition of humates and zeolite caused only a negligible increase in the degradation rate. These factors, however, affected significantly the amount of PLFA. The humates caused significantly faster increase of the total PLFA suggesting improvement of the soil microenvironment. Zeolite caused significantly slower increase of the total PLFA; nevertheless it aided in homogenization of the soil. Comparison of microbial activities and total PLFA revealed that only a small fraction of autochthonous microbes took part in the biodegradation which confirms that bioaugmentation was the most important treatment. PMID:24672346

Global atmospheric emissions of polycyclic aromatic hydrocarbons from 1960 to 2008 and future predictions.

PubMed

Shen, Huizhong; Huang, Ye; Wang, Rong; Zhu, Dan; Li, Wei; Shen, Guofeng; Wang, Bin; Zhang, Yanyan; Chen, Yuanchen; Lu, Yan; Chen, Han; Li, Tongchao; Sun, Kang; Li, Bengang; Liu, Wenxin; Liu, Junfeng; Tao, Shu

2013-06-18

Global atmospheric emissions of 16 polycyclic aromatic hydrocarbons (PAHs) from 69 major sources were estimated for a period from 1960 to 2030. Regression models and a technology split method were used to estimate country and time specific emission factors, resulting in a new estimate of PAH emission factor variation among different countries and over time. PAH emissions in 2007 were spatially resolved to 0.1° × 0.1° grids based on a newly developed global high-resolution fuel combustion inventory (PKU-FUEL-2007). The global total annual atmospheric emission of 16 PAHs in 2007 was 504 Gg (331-818 Gg, as interquartile range), with residential/commercial biomass burning (60.5%), open-field biomass burning (agricultural waste burning, deforestation, and wildfire, 13.6%), and petroleum consumption by on-road motor vehicles (12.8%) as the major sources. South (87 Gg), East (111 Gg), and Southeast Asia (52 Gg) were the regions with the highest PAH emission densities, contributing half of the global total PAH emissions. Among the global total PAH emissions, 6.19% of the emissions were in the form of high molecular weight carcinogenic compounds and the percentage of the carcinogenic PAHs was higher in developing countries (6.22%) than in developed countries (5.73%), due to the differences in energy structures and the disparities of technology. The potential health impact of the PAH emissions was greatest in the parts of the world with high anthropogenic PAH emissions, because of the overlap of the high emissions and high population densities. Global total PAH emissions peaked at 592 Gg in 1995 and declined gradually to 499 Gg in 2008. Total PAH emissions from developed countries peaked at 122 Gg in the early 1970s and decreased to 38 Gg in 2008. Simulation of PAH emissions from 2009 to 2030 revealed that PAH emissions in developed and developing countries would decrease by 46-71% and 48-64%, respectively, based on the six IPCC SRES scenarios.

Global atmospheric emissions of polycyclic aromatic hydrocarbons from 1960 to 2008 and future predictions

PubMed Central

Shen, Huizhong; Huang, Ye; Wang, Rong; Zhu, Dan; Li, Wei; Shen, Guofeng; Wang, Bin; Zhang, Yanyan; Chen, Yuanchen; Lu, Yan; Chen, Han; Li, Tongchao; Sun, Kang; Li, Bengang; Liu, Wenxin; Liu, Junfeng; Tao, Shu

2013-01-01

Global atmospheric emissions of 16 polycyclic aromatic hydrocarbons (PAHs) from 69 major sources were estimated for a period from 1960 to 2030. Regression models and a technology split method were used to estimate country and time specific emission factors, resulting in a new estimate of PAH emission factor variation among different countries and over time. PAH emissions in 2007 were spatially resolved to 0.1°× 0.1° grids based on a newly developed global high-resolution fuel combustion inventory (PKU-FUEL-2007). The global total annual atmospheric emission of 16 PAHs in 2007 was 504 Gg (331-818 Gg, as interquartile range), with residential/commercial biomass burning (60.5%), open-field biomass burning (agricultural waste burning, deforestation, and wildfire, 13.6%), and petroleum consumption by on-road motor vehicles (12.8%) as the major sources. South (87 Gg), East (111 Gg), and Southeast Asia (52 Gg) were the regions with the highest PAH emission densities, contributing half of the global total PAH emissions. Among the global total PAH emissions, 6.19% of the emissions were in the form of high molecular weight carcinogenic compounds and the percentage of the carcinogenic PAHs was higher in developing countries (6.22%) than in developed countries (5.73%), due to the differences in energy structures and the disparities of technology. The potential health impact of the PAH emissions was greatest in the parts of the world with high anthropogenic PAH emissions, because of the overlap of the high emissions and high population densities. Global total PAH emissions peaked at 592 Gg in 1995 and declined gradually to 499 Gg in 2008. Total PAH emissions from developed countries peaked at 122 Gg in the early 1970s and decreased to 38 Gg in 2008. Simulation of PAH emissions from 2009 to 2030 revealed that PAH emissions in developed and developing countries would decrease by 46-71% and 48-64%, respectively, based on the six IPCC SRES scenarios. PMID:23659377

46 CFR 148.04-15 - Petroleum coke, uncalcined; petroleum coke, uncalcined and calcined (mixture).

Code of Federal Regulations, 2010 CFR

2010-10-01

... 46 Shipping 5 2010-10-01 2010-10-01 false Petroleum coke, uncalcined; petroleum coke, uncalcined and calcined (mixture). 148.04-15 Section 148.04-15 Shipping COAST GUARD, DEPARTMENT OF HOMELAND... Requirements for Certain Material § 148.04-15 Petroleum coke, uncalcined; petroleum coke, uncalcined and...

Petroleum supply monthly, October 1993

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1993-10-26

The Petroleum Supply Monthly (PSM) is one of a family of four publications produced by the Petroleum Supply Division within the Energy Information Administration (EIA) reflecting different levels of data timeliness and completeness. The other publications are the Weekly Petroleum Status Report (WPSR), the Winter Fuels Report, and the Petroleum Supply Annual (PSA). Data presented in the PSM describe the supply and disposition of petroleum products in the United States and major US geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products inmore » the United States (50 States and the District of Columbia). The reporting universe includes those petroleum sectors in primary supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated, the data reported by these sectors approximately represent the consumption of petroleum products in the United States. Data presented in the PSM are divided into two sections: Summary Statistics and Detailed Statistics.« less

Petroleum supply monthly, January 1996

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

The Petroleum Supply Monthly (PSM) is one of a family of four publications produced by the Petroleum Supply Division within the Energy Information Administration (EIA) reflecting different levels of data timeliness and completeness. The other publications are the Weekly Petroleum Status Report (WPSR), the Winter Fuels Report, and the Petroleum Supply Annual (PSA). Data presented in the PSM describe the supply and disposition of petroleum products in the United States and major US geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products inmore » the United States (50 States and the District of Columbia). The reporting universe includes those petroleum sectors in primary supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated, the data reported by these sectors approximately represent the consumption of petroleum products in the United States. Data presented in the PSM are divided into two sections: Summary Statistics and Detailed Statistics.« less

JEDI Petroleum Model | Jobs and Economic Development Impact Models | NREL

Science.gov Websites

Petroleum Model JEDI Petroleum Model The Jobs and Economic Development Impacts (JEDI) Petroleum Model allows users to estimate economic development impacts from petroleum projects and includes default

Antibacterial, antioxidant, anti-cholinesterase potential and flavonol glycosides of Biscutella raphanifolia (Brassicaceae).

PubMed

Boudouda, Houria Berhail; Zeghib, Assia; Karioti, Anastazia; Bilia, Anna Rita; Öztürk, Mehmet; Aouni, Mahjoub; Kabouche, Ahmed; Kabouche, Zahia

2015-01-01

Different extracts of the aerial parts of Biscutella raphanifolia (Brassicaceae), which has not been the subject of any study, were screened for the phytochemical content, anti-microbial, antioxidant and anti-cholinesterase activities. We used four methods to identify the antioxidant activity namely, ABTS(•+), DPPH• scavenging, CUPRAC and ferrous-ions chelating methods. Since there is a relationship between antioxidants and cholinesterase enzyme inhibitors, we used two methods to determine the in vitro anti-cholinesterase activity by the use of the basic enzymes that occur in causing Alzheimer's disease: acetylcholinesterase (AChE) and butyrylcholinesterase (BChE). The extracts were also tested in vitro antimicrobial activity against various bacteria. The phytochemical study of B. raphanifolia afforded four flavonol glycosides; namely, quercetin-3-O-β-D-g1ucoside, quercetin-3-O-[β-D-glucosyl(1→2)-O-β-D-glucoside], quercetin-3-O-[β-D-glucosyl(1→3)-O-β-D-glucoside] and kaempferol-3-O-[β-D-glucosyl(1→2)-[(6'''p-coumaroyl)- β-D-glucoside], being isolated here for the first time from Biscutella raphanifolia and the genus. The ethyl acetate extract showed the highest activity in ABTS(•+), DPPH• and CUPRAC assays, while the petroleum ether extract demonstrated optimum efficiency metal chelating activity. The dicloromethane and petroleum ether extracts showed a mild inhibition against AChE and BChE. However, the petroleum ether extract showed a good antibacterial activity against the pathovars Enteropathogenic E. coli (EPEC), Enterotoxigenic E. coli (ETEC) and Enterococcus feacalis, whereas the Enterohemorrhagic E. coli (EHEC) strain was more sensitive to dichloromethane and n-butanol extracts.

Control of petroleum-hydrocarbon contaminated groundwater by intrinsic and enhanced bioremediation.

PubMed

Chen, Ku-Fan; Kao, Chih-Ming; Chen, Chiu-Wen; Surampalli, Rao Y; Lee, Mu-Sheng

2010-01-01

In the first phase of this study, the effectiveness of intrinsic bioremediation on the containment of petroleum hydrocarbons was evaluated at a gasoline spill site. Evidences of the occurrence of intrinsic bioremediation within the BTEX (benzene, toluene, ethylbenzene, and xylenes) plume included (1) decreased BTEX concentrations; (2) depletion of dissolved oxygen (DO), nitrate, and sulfate; (3) production of dissolved ferrous iron, methane, and CO2; (4) deceased pH and redox potential; and (5) increased methanogens, total heterotrophs, and total anaerobes, especially within the highly contaminated areas. In the second phase of this study, enhanced aerobic bioremediation process was applied at site to enhance the BTEX decay rates. Air was injected into the subsurface near the mid-plume area to biostimulate the naturally occurring microorganisms for BTEX biodegradation. Field results showed that enhanced bioremediation process caused the change of BTEX removal mechanisms from anaerobic biodegradation inside the plume to aerobic biodegradation. This variation could be confirmed by the following field observations inside the plume due to the enhanced aerobic bioremediation process: (1) increased in DO, CO2, redox potential, nitrate, and sulfate, (2) decreased in dissolved ferrous iron, sulfide, and methane, (3) increased total heterotrophs and decreased total anaerobes. Field results also showed that the percentage of total BTEX removal increased from 92% to 99%, and the calculated total BTEX first-order natural attenuation rates increased from 0.0092% to 0.0188% per day, respectively, after the application of enhanced bioremediation system from the spill area to the downgradient area (located approximately 300 m from the source area).

Re-Os geochronology and Os isotope fingerprinting of petroleum sourced from a Type I lacustrine kerogen: Insights from the natural Green River petroleum system in the Uinta Basin and hydrous pyrolysis experiments

NASA Astrophysics Data System (ADS)

Cumming, Vivien M.; Selby, David; Lillis, Paul G.; Lewan, Michael D.

2014-08-01

Rhenium-osmium (Re-Os) geochronology of marine petroleum systems has allowed the determination of the depositional age of source rocks as well as the timing of petroleum generation. In addition, Os isotopes have been applied as a fingerprinting tool to correlate oil to its source unit. To date, only classic marine petroleum systems have been studied. Here we present Re-Os geochronology and Os isotope fingerprinting of different petroleum phases (oils, tar sands and gilsonite) derived from the lacustrine Green River petroleum system in the Uinta Basin, USA. In addition we use an experimental approach, hydrous pyrolysis experiments, to compare to the Re-Os data of naturally generated petroleum in order to further understand the mechanisms of Re and Os transfer to petroleum. The Re-Os geochronology of petroleum from the lacustrine Green River petroleum system (19 ± 14 Ma - all petroleum phases) broadly agrees with previous petroleum generation basin models (∼25 Ma) suggesting that Re-Os geochronology of variable petroleum phases derived from lacustrine Type I kerogen has similar systematics to Type II kerogen (e.g., Selby and Creaser, 2005a,b; Finlay et al., 2010). However, the large uncertainties (over 100% in some cases) produced for the petroleum Re-Os geochronology are a result of multiple generation events occurring through a ∼3000-m thick source unit that creates a mixture of initial Os isotope compositions in the produced petroleum phases. The 187Os/188Os values for the petroleum and source rocks at the time of oil generation vary from 1.4 to 1.9, with the mode at ∼1.6. Oil-to-source correlation using Os isotopes is consistent with previous correlation studies in the Green River petroleum system, and illustrates the potential utility of Os isotopes to characterize the spatial variations within a petroleum system. Hydrous pyrolysis experiments on the Green River Formation source rocks show that Re and Os transfer are mimicking the natural system. This transfer from source to bitumen to oil does not affect source rock Re-Os systematics or Os isotopic compositions. This confirms that Os isotope compositions are transferred intact from source to petroleum during petroleum generation and can be used as a powerful correlation tool. These experiments further confirm that Re-Os systematics in source rocks are not adversely affected by petroleum maturation. Overall this study illustrates that the Re-Os petroleum geochronometer and Os isotope fingerprinting tools can be used on a wide range of petroleum types sourced from variable kerogen types.

Re-Os geochronology and Os isotope fingerprinting of petroleum sourced from a Type I lacustrine kerogen: insights from the natural Green River petroleum system in the Uinta Basin and hydrous pyrolysis experiments

USGS Publications Warehouse

Cumming, Vivien M.; Selby, David; Lillis, Paul G.; Lewan, Michael D.

2014-01-01

Rhenium–osmium (Re–Os) geochronology of marine petroleum systems has allowed the determination of the depositional age of source rocks as well as the timing of petroleum generation. In addition, Os isotopes have been applied as a fingerprinting tool to correlate oil to its source unit. To date, only classic marine petroleum systems have been studied. Here we present Re–Os geochronology and Os isotope fingerprinting of different petroleum phases (oils, tar sands and gilsonite) derived from the lacustrine Green River petroleum system in the Uinta Basin, USA. In addition we use an experimental approach, hydrous pyrolysis experiments, to compare to the Re–Os data of naturally generated petroleum in order to further understand the mechanisms of Re and Os transfer to petroleum. The Re–Os geochronology of petroleum from the lacustrine Green River petroleum system (19 ± 14 Ma – all petroleum phases) broadly agrees with previous petroleum generation basin models (∼25 Ma) suggesting that Re–Os geochronology of variable petroleum phases derived from lacustrine Type I kerogen has similar systematics to Type II kerogen (e.g., Selby and Creaser, 2005a, Selby and Creaser, 2005b and Finlay et al., 2010). However, the large uncertainties (over 100% in some cases) produced for the petroleum Re–Os geochronology are a result of multiple generation events occurring through a ∼3000-m thick source unit that creates a mixture of initial Os isotope compositions in the produced petroleum phases. The 187Os/188Os values for the petroleum and source rocks at the time of oil generation vary from 1.4 to 1.9, with the mode at ∼1.6. Oil-to-source correlation using Os isotopes is consistent with previous correlation studies in the Green River petroleum system, and illustrates the potential utility of Os isotopes to characterize the spatial variations within a petroleum system. Hydrous pyrolysis experiments on the Green River Formation source rocks show that Re and Os transfer are mimicking the natural system. This transfer from source to bitumen to oil does not affect source rock Re–Os systematics or Os isotopic compositions. This confirms that Os isotope compositions are transferred intact from source to petroleum during petroleum generation and can be used as a powerful correlation tool. These experiments further confirm that Re–Os systematics in source rocks are not adversely affected by petroleum maturation. Overall this study illustrates that the Re–Os petroleum geochronometer and Os isotope fingerprinting tools can be used on a wide range of petroleum types sourced from variable kerogen types.

The role of analytical chemistry in Niger Delta petroleum exploration: a review.

PubMed

Akinlua, Akinsehinwa

2012-06-12

Petroleum and organic matter from which the petroleum is derived are composed of organic compounds with some trace elements. These compounds give an insight into the origin, thermal maturity and paleoenvironmental history of petroleum, which are essential elements in petroleum exploration. The main tool to acquire the geochemical data is analytical techniques. Due to progress in the development of new analytical techniques, many hitherto petroleum exploration problems have been resolved. Analytical chemistry has played a significant role in the development of petroleum resources of Niger Delta. Various analytical techniques that have aided the success of petroleum exploration in the Niger Delta are discussed. The analytical techniques that have helped to understand the petroleum system of the basin are also described. Recent and emerging analytical methodologies including green analytical methods as applicable to petroleum exploration particularly Niger Delta petroleum province are discussed in this paper. Analytical chemistry is an invaluable tool in finding the Niger Delta oils. Copyright © 2011 Elsevier B.V. All rights reserved.

Short-Term Energy Outlook Model Documentation: Petroleum Products Supply Module

EIA Publications

2013-01-01

The Petroleum Products Supply Module of the Short-Term Energy Outlook (STEO) model provides forecasts of petroleum refinery inputs (crude oil, unfinished oils, pentanes plus, liquefied petroleum gas, motor gasoline blending components, and aviation gasoline blending components) and refinery outputs (motor gasoline, jet fuel, distillate fuel, residual fuel, liquefied petroleum gas, and other petroleum products).

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kevin C. Galbreath; Donald L. Toman; Christopher J. Zygarlicke

Petroleum coke, a byproduct of the petroleum-refining process, is an attractive primary or supplemental fuel for power production primarily because of a progressive and predictable increase in the production volumes of petroleum coke (1, 2). Petroleum coke is most commonly blended with coal in proportions suitable to meet sulfur emission compliance. Petroleum coke is generally less reactive than coal; therefore, the cofiring of petroleum coke with coal typically improves ignition, flame stability, and carbon loss relative to the combustion of petroleum coke alone. Although petroleum coke is a desirable fuel for producing relatively inexpensive electrical power, concerns about the effectsmore » of petroleum coke blending on combustion and pollution control processes exist in the coal-fired utility industry (3). The Energy & Environmental Research Center (EERC) completed a 2-year technical assessment of petroleum coke as a supplemental fuel. A survey questionnaire was sent to seven electric utility companies that are currently cofiring coal and petroleum coke in an effort to solicit specific suggestions on research needs and fuel selections. An example of the letter and survey questionnaire is presented in Appendix A. Interest was expressed by most utilities in evaluating the effects of petroleum coke blending on grindability, combustion reactivity, fouling, slagging, and fly ash emissions control. Unexpectedly, concern over corrosion was not expressed by the utilities contacted. Although all seven utilities responded to the question, only two utilities, Northern States Power Company (NSP) and Ameren, sent fuels to the EERC for evaluation. Both utilities sent subbituminous coals from the Power River Basin and petroleum shot coke samples. Petroleum shot coke is produced unintentionally during operational upsets in the petroleum refining process. This report evaluates the effects of petroleum shot coke blending on grindability, fuel reactivity, fouling/slagging, and electrostatic precipitator (ESP) fly ash collection efficiency.« less

Cancer incidence of workers in the Swedish petroleum industry.

PubMed Central

Järvholm, B; Mellblom, B; Norrman, R; Nilsson, R; Nordlinder, R

1997-01-01

OBJECTIVES: To estimate the risk of cancer due to occupational exposure to petroleum products in the Swedish transport and refinery industries. METHODS: In a retrospective cohort study the cancer incidence in 4128 men and 191 women, who had worked for at least one year in the petroleum industry, was compared with the incidence in the general population. The job titles and employment times for each person were found in personal files in the industries. The men had on average worked in jobs exposed to petroleum for 11.6 years at the end of the observation period. The cases of cancer were identified by record linkage with the Swedish cancer register. RESULTS: In total there were 146 cases of cancer v 157.6 expected (standardised mortality ratio (SMR) 0.93 90% confidence interval (90% CI) 0.80 to 1.1). Operators at refineries had an increased risk of leukaemia (6 cases v 1.7 expected, 90% CI of relative risk (RR) 1.5 to 7.0). Five of the six cases had started to work at the refineries in the 1950s or later. No other significantly increased risk of cancer was found. Distribution workers had a decreased incidence of lung cancer (no cases, 90% CI of RR 0 to 0.4). CONCLUSIONS: Operators at Swedish refineries had an increased risk of leukaemia. A possible cause is exposure to benzene. There was no increased risk of leukaemia in distribution workers. Distribution workers had a decreased risk of lung cancer. PMID:9423584

Generation and migration of Bitumen and oil from the oil shale interval of the Eocene Green River formation, Uinta Basin, Utah

USGS Publications Warehouse

Johnson, Ronald C.; Birdwell, Justin E.; Mercier, Tracey J.

2016-01-01

The results from the recent U.S. Geological Survey assessment of in-place oil shale resources of the Eocene Green River Formation, based primarily on the Fischer assay method, are applied herein to define areas where the oil shale interval is depleted of some of its petroleum-generating potential along the deep structural trough of the basin and to make: (1) a general estimates of the amount of this depletion, and (2) estimate the total volume of petroleum generated. Oil yields (gallons of oil per ton of rock, GPT) and in-place oil (barrels of oil per acre, BPA) decrease toward the structural trough of the basin, which represents an offshore lacustrine area that is believed to have originally contained greater petroleum-generating potential than is currently indicated by measured Fischer assay oil yields. Although this interval is considered to be largely immature for oil generation based on vitrinite reflectance measurements, the oil shale interval is a likely source for the gilsonite deposits and much of the tar sands in the basin. Early expulsion of petroleum may have occurred due to the very high organic carbon content and oil-prone nature of the Type I kerogen present in Green River oil shale. In order to examine the possible sources and migration pathways for the tar sands and gilsonite deposits, we have created paleogeographic reconstructions of several oil shale zones in the basin as part of this study.

Petroleum Refinery Jobs and Economic Development Impact (JEDI) Model User Reference Guide

DOE Office of Scientific and Technical Information (OSTI.GOV)

Goldberg, Marshall

The Jobs and Economic Development Impact (JEDI) models, developed through the National Renewable Energy Laboratory (NREL), are user-friendly tools utilized to estimate the economic impacts at the local level of constructing and operating fuel and power generation projects for a range of conventional and renewable energy technologies. The JEDI Petroleum Refinery Model User Reference Guide was developed to assist users in employing and understanding the model. This guide provides information on the model's underlying methodology, as well as the parameters and references used to develop the cost data utilized in the model. This guide also provides basic instruction on modelmore » add-in features, operation of the model, and a discussion of how the results should be interpreted. Based on project-specific inputs from the user, the model estimates job creation, earning and output (total economic activity) for a given petroleum refinery. This includes the direct, indirect and induced economic impacts to the local economy associated with the refinery's construction and operation phases. Project cost and job data used in the model are derived from the most current cost estimations available. Local direct and indirect economic impacts are estimated using economic multipliers derived from IMPLAN software. By determining the regional economic impacts and job creation for a proposed refinery, the JEDI Petroleum Refinery model can be used to field questions about the added value refineries may bring to the local community.« less

Evaluation of biodiesel’s impact on real-world occupational and environmental particulate matter exposures at a municipal facility in Keene, NH

PubMed Central

Thelen, Brett Amy; Ingalls, Jaime Kathryn; Treadwell, Melinda Dawn

2016-01-01

Many organizations are interested in biodiesel as a renewable, domestic energy source for use in transportation and heavy-duty equipment. Although numerous biodiesel emission studies exist, biodiesel exposure studies are nearly absent from the literature. This study compared the impact of petroleum diesel fuel and a B20 blend (20% soy-based biodiesel/80% petroleum diesel) on occupational and environmental exposures at a rural municipal facility in Keene, NH. For each fuel type, we measured concentrations of fine particulate matter (PM2.5), elemental carbon (EC), and organic carbon (OC) at multiple locations (in-cabin, work area, and near-field) at a materials recovery facility utilizing non-road equipment. B20 fuel use resulted in significant reductions in PM2.5 mass (56–76%), reductions in EC (5–29%), and increases in OC (294–467%). Concentrations of PM2.5 measured during petroleum diesel use were up to four times higher than PM2.5 concentrations during B20 use. Further analysis of the EC and OC fractions of total carbon also indicated substantial differences between fuels. Our results demonstrate that biodiesel blends significantly reduced PM2.5 exposure compared to petroleum diesel fuel in a workplace utilizing non-road construction-type equipment. While this suggests that biodiesel may reduce health risks associated with exposure to fine particulate matter mass, more exposure research is needed to better understand biodiesel-related changes in particulate matter composition and other exposure metrics.

Petroleum marketing monthly, February 1999 with data for November 1998

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

1999-02-01

The Petroleum Marketing Monthly (PMM) provides information and statistical data on a variety of crude oils and refined petroleum products. The publication presents statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and the refiners` acquisition cost of crude oil. Refined petroleum product sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane. Monthly statistics on purchases of crude oil and sales of petroleum products aremore » presented in the Petroleum Marketing Monthly in six sections: Initial Estimates; Summary Statistics; Crude Oil Prices; Prices of Petroleum Products; Volumes of Petroleum Products; and Prime Supplier Sales Volumes of Petroleum Products for Local Consumption. 7 figs., 50 tabs.« less

Petroleum marketing monthly, March 1999 with data for December 1998

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

1999-03-01

The Petroleum Marketing Monthly (PMM) provides information and statistical data on a variety of crude oils and refined petroleum products. The publication presents statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and the refiners` acquisition cost of crude oil. Refined petroleum product sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane. Monthly statistics on purchases of crude oil and sales of petroleum products aremore » presented in the Petroleum Marketing Monthly in five sections: summary statistics; crude oil prices; prices of petroleum products; volumes of petroleum products; and prime supplier sales volumes of petroleum products for local consumption. 7 figs., 50 tabs.« less

Clean Cities Guide to Alternative Fuel Commercial Lawn Equipment (Brochure)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

Guide explains the different types of alternative fuel commercial mowers and lists the makes and models of the ones available on the market. Turf grass is a fixture of the American landscape and the American economy. It is the nation's largest irrigated crop, covering more than 40 million acres. Legions of lawnmowers care for this expanse during the growing season-up to year-round in the warmest climates. The annual economic impact of the U.S. turf grass industry has been estimated at more than $62 billion. Lawn mowing also contributes to the nation's petroleum consumption and pollutant emissions. Mowers consume 1.2 billionmore » gallons of gasoline annually, about 1% of U.S. motor gasoline consumption. Commercial mowing accounts for about 35% of this total and is the highest-intensity use. Large property owners and mowing companies cut lawns, sports fields, golf courses, parks, roadsides, and other grassy areas for 7 hours per day and consume 900 to 2,000 gallons of fuel annually depending on climate and length of the growing season. In addition to gasoline, commercial mowing consumes more than 100 million gallons of diesel annually. Alternative fuel mowers are one way to reduce the energy and environmental impacts of commercial lawn mowing. They can reduce petroleum use and emissions compared with gasoline- and diesel-fueled mowers. They may also save on fuel and maintenance costs, extend mower life, reduce fuel spillage and fuel theft, and promote a 'green' image. And on ozone alert days, alternative fuel mowers may not be subject to the operational restrictions that gasoline mowers must abide by. To help inform the commercial mowing industry about product options and potential benefits, Clean Cities produced this guide to alternative fuel commercial lawn equipment. Although the guide's focus is on original equipment manufacturer (OEM) mowers, some mowers can be converted to run on alternative fuels. For more information about propane conversions. This guide may be particularly helpful for organizations that are already using alternative fuels in their vehicles and have an alternative fuel supply or electric charging in place (e.g., golf cart charging stations at most golf courses). On the flip side, experiencing the benefits of using alternative fuels in mowing equipment may encourage organizations to try them in on-road vehicles as well. Whatever the case, alternative fuel commercial lawnmowers are a powerful and cost-effective way to reduce U.S. petroleum dependence and help protect the environment.« less

The drama of Puna: For and against the Hawai'i geothermal project

NASA Astrophysics Data System (ADS)

Keyser, William Henry

The geothermal project was conceived in the context of the international oil business and the economic growth of Hawai'i. From the point of view of the State, the geothermal project is necessary because imported petroleum provides Hawai'i with 911/2 percent of its total energy. That petroleum consists of 140,000 b/d of crude (1990) and it comes from Alaska, Indonesia and a few other suppliers. However, the Alaskan North Slope is beginning to run dry and the Southeast Asian suppliers of crude will be exporting less petroleum as time goes on. Increasingly, Hawai'i will become dependent on "unstable Middle Eastern" suppliers of crude. From this worry about the Middle East, the State seeks indigenous energy to reduce its dependence on petroleum and to support economic growth. Hence, the geothermal project was born after the 1973 oil embargo. The major source of geothermal energy is the Kilauea Volcano on the Big Island. Kilauea is characterized by the Kilauea caldera and a crack in the Island which extends easterly from the caldera to Cape Kumukahi in Puna and southwest to Pahala in Ka'u. The eastern part of the crack is approximately 55 kilometers long and 5 kilometers wide. The geothermal plants will sit on this crack. While the State has promoted the geothermal project with the argument of reducing "dependence" on imported petroleum, it hardly mentions its goal of economic growth. The opponents have resisted the project on the grounds of protecting Pele and Hawaiian gathering rights, protecting the rain forest, and stopping the pollution in the geothermal steam. What the opponents do not mention is their support for economic growth. The opposition to the project suggests a new environmental politics is forming in Hawai'i. Is this true? The dissertation will show that the participants in this drama are involved in a strange dance where each side avoids any recognition of their fundamental agreement on economic growth. Hence the creation of a new environmental politics which accounts for the danger inherent in economic growth, the eventual depletion of petroleum and the West's imperative to conquer nature is very problematic.

78 FR 37133 - National Emission Standards for Hazardous Air Pollutants From Petroleum Refineries

Federal Register 2010, 2011, 2012, 2013, 2014

2013-06-20

... systems that would allow owners and operators at existing sources to monitor quarterly using a leak action... option, which requires monitoring monthly at a leak action level defined as a total strippable... monitoring alternative and the modeling indicates that quarterly monitoring at the lower leak action level...

40 CFR 86.410-90 - Emission standards for 1990 and later model year motorcycles.

Code of Federal Regulations, 2010 CFR

2010-07-01

... petroleum gas-fueled motorcycles): (i) Hydrocarbons. 5.0 grams per vehicle kilometer. (ii) Carbon monoxide. 12 grams per vehicle kilometer. (2) Exhaust emissions from 1990 and later model year methanol-fueled motorcycles shall not exceed: (i) Total hydrocarbon equivalent. 5.0 grams per vehicle kilometer. (ii) Carbon...

40 CFR 86.410-90 - Emission standards for 1990 and later model year motorcycles.

Code of Federal Regulations, 2013 CFR

2013-07-01

... petroleum gas-fueled motorcycles): (i) Hydrocarbons. 5.0 grams per vehicle kilometer. (ii) Carbon monoxide. 12 grams per vehicle kilometer. (2) Exhaust emissions from 1990 and later model year methanol-fueled motorcycles shall not exceed: (i) Total hydrocarbon equivalent. 5.0 grams per vehicle kilometer. (ii) Carbon...

40 CFR 86.410-90 - Emission standards for 1990 and later model year motorcycles.

Code of Federal Regulations, 2012 CFR

2012-07-01

... petroleum gas-fueled motorcycles): (i) Hydrocarbons. 5.0 grams per vehicle kilometer. (ii) Carbon monoxide. 12 grams per vehicle kilometer. (2) Exhaust emissions from 1990 and later model year methanol-fueled motorcycles shall not exceed: (i) Total hydrocarbon equivalent. 5.0 grams per vehicle kilometer. (ii) Carbon...

40 CFR 86.410-90 - Emission standards for 1990 and later model year motorcycles.

Code of Federal Regulations, 2014 CFR

2014-07-01

... petroleum gas-fueled motorcycles): (i) Hydrocarbons. 5.0 grams per vehicle kilometer. (ii) Carbon monoxide. 12 grams per vehicle kilometer. (2) Exhaust emissions from 1990 and later model year methanol-fueled motorcycles shall not exceed: (i) Total hydrocarbon equivalent. 5.0 grams per vehicle kilometer. (ii) Carbon...

40 CFR 86.410-90 - Emission standards for 1990 and later model year motorcycles.

Code of Federal Regulations, 2011 CFR

2011-07-01

... petroleum gas-fueled motorcycles): (i) Hydrocarbons. 5.0 grams per vehicle kilometer. (ii) Carbon monoxide. 12 grams per vehicle kilometer. (2) Exhaust emissions from 1990 and later model year methanol-fueled motorcycles shall not exceed: (i) Total hydrocarbon equivalent. 5.0 grams per vehicle kilometer. (ii) Carbon...

Obtaining Representative Field Information for Vapor Intrusion Assessments: What Do You Need to Know? (St. Louis, MO)

EPA Science Inventory

The rate and extent of biodegradation a contaminant of concern (such as benzene) in soil gas is controlled by the supply of molecular oxygen. The supply of oxygen is limited by the competing demands for oxygen to support the biodegradation of methane and total petroleum hydroc...

INNOVATIVE TECHNOLOGY VERIFICATION REPORT "FIELD MEASUREMENT TECHNOLOGIES FOR TOTAL PETROLEUM HYDROCARBONS IN SOIL" WILKS ENTERPRISE, INC. INFRACAL TOG/TPH ANALYZER

EPA Science Inventory

The hifracal' TOG/TPH Analyzer developed by Wilks Enterprise, Inc. (Wilks), was demonstrated under the U.S. Environmental Protection Agency Superfund Innovative Technology Evaluation Program in June 2000 at the Navy Base Ventura County site in Port Hueneme, California. The pu...

INNOVATIVE TECHNOLOGY VERIFICATION REPORT "FIELD MEASUREMENT TECHNOLOGIES FOR TOTAL PETROLEUM HYDROCARBONS IN SOIL" STRATEGIC DIAGNOSTICS INC. ENSYS PETRO TEST SYSTEM

EPA Science Inventory

The EnSys Petro Test System developed by Strategic Diagnostics Inc. (SDI), was demonstrated under the U.S. Environmental Protection Agency Superfund Innovative Technology Evaluation Program in June 2000 at the Navy Base Ventura County site in Port Hueneme, California. The...

INNOVATIVE TECHNOLOGY VERIFICATION REPORT "FIELD MEASUREMENT TECHNOLOGIES FOR TOTAL PETROLEUM HYDROCARBONS IN SOIL" HORIBA INSTRUMENTS INCORPORATED OCMA-350 CONTENT ANALYZER

EPA Science Inventory

The OCMA-350 Oil Content Analyzer(OCMA-350) developed by Horiba Instruments Incorporated (Horiba), was demonstrated under the U.S. Environmental Protection Agency Superfund Innovative Technology Evaluation Program in June 2000 at the Navy Base Ventura County site in Port Huen...

Can Tribes Control Energy Development?

ERIC Educational Resources Information Center

Owens, Nancy J.

1979-01-01

Emphasizing that the Indian future does not have to be bleak if only Indians take greater control over energy development on their lands. Two-thirds of the total Indian population control 33 percent of U.S. low-sulfer, strippable coal; 80 percent of U.S. uranium reserves; and about 10 percent of petroleum and gas reserves. (Author/RTS)

Investigation of ethyl lactate as a green solvent for desorption of total petroleum hydrocarbons (TPH) from contaminated soil.

PubMed

Jalilian Ahmadkalaei, Seyedeh Pegah; Gan, Suyin; Ng, Hoon Kiat; Abdul Talib, Suhaimi

2016-11-01

Treatment of oil-contaminated soil is a major environmental concern worldwide. The aim of this study is to examine the applicability of a green solvent, ethyl lactate (EL), in desorption of diesel aliphatic fraction within total petroleum hydrocarbons (TPH) in contaminated soil and to determine the associated desorption kinetics. Batch desorption experiments were carried out on artificially contaminated soil at different EL solvent percentages (%). In analysing the diesel range of TPH, TPH was divided into three fractions and the effect of solvent extraction on each fraction was examined. The experimental results demonstrated that EL has a high and fast desorbing power. Pseudo-second order rate equation described the experimental desorption kinetics data well with correlation coefficient values, R 2 , between 0.9219 and 0.9999. The effects of EL percentage, initial contamination level of soil and liquid to solid ratio (L/S (v/w)) on initial desorption rate have also been evaluated. The effective desorption performance of ethyl lactate shows its potential as a removal agent for remediation of TPH-contaminated soil worldwide.

Mapping polycyclic aromatic hydrocarbon and total toxicity equivalent soil concentrations by visible and near-infrared spectroscopy.

PubMed

Okparanma, Reuben N; Coulon, Frederic; Mayr, Thomas; Mouazen, Abdul M

2014-09-01

In this study, we used data from spectroscopic models based on visible and near-infrared (vis-NIR; 350-2500 nm) diffuse reflectance spectroscopy to develop soil maps of polycyclic aromatic hydrocarbons (PAHs) and total toxicity equivalent concentrations (TTEC) of the PAH mixture. The TTEC maps were then used for hazard assessment of three petroleum release sites in the Niger Delta province of Nigeria (5.317°N, 6.467°E). As the paired t-test revealed, there were non-significant (p > 0.05) differences between soil maps of PAH and TTEC developed with chemically measured and vis-NIR-predicted data. Comparison maps of PAH showed a slight to moderate agreement between measured and predicted data (Kappa coefficient = 0.19-0.56). Using proposed generic assessment criteria, hazard assessment showed that the degree of action for site-specific risk assessment and/or remediation is similar for both measurement methods. This demonstrates that the vis-NIR method may be useful for monitoring hydrocarbon contamination in a petroleum release site. Copyright © 2014 Elsevier Ltd. All rights reserved.

Microbial degradation of total petroleum hydrocarbons in crude oil: a field-scale study at the low-land rainforest of Ecuador.

PubMed

Maddela, Naga Raju; Scalvenzi, Laura; Venkateswarlu, Kadiyala

2017-10-01

A field-level feasibility study was conducted to determine total petroleum hydrocarbon (TPH)-degrading potential of two bacterial strains, Bacillus thuringiensis B3 and B. cereus B6, and two fungi, Geomyces pannorum HR and Geomyces sp. strain HV, all soil isolates obtained from an oil field located in north-east region of Ecuador. Crude oil-treated soil samples contained in wooden boxes received a mixture of all the four microorganisms and were incubated for 90 days in an open low-land area of Amazon rainforest. The percent removal of TPHs in soil samples that received the mixed microbial inoculum was 87.45, indicating the great potential of the soil isolates in field-scale removal of crude oil. The TPHs-degrading efficiency was verified by determining the toxicity of residues, remained in soil after biodegradation, toward viability of Artemia salina or seed germination and plant growth of cowpea. Our results clearly suggest that the selected soil isolates of bacteria and fungi could be effectively used for large-scale bioremediation of sites contaminated with crude oil.

South Sumatra Basin Province, Indonesia; the Lahat/Talang Akar-Cenozoic total petroleum system

USGS Publications Warehouse

Bishop, Michele G.

2000-01-01

Oil and gas are produced from the onshore South Sumatra Basin Province. The province consists of Tertiary half-graben basins infilled with carbonate and clastic sedimentary rocks unconformably overlying pre-Tertiary metamorphic and igneous rocks. Eocene through lower Oligocene lacustrine shales and Oligocene through lower Miocene lacustrine and deltaic coaly shales are the mature source rocks. Reserves of 4.3 billion barrels of oil equivalent have been discovered in reservoirs that range from pre-Tertiary basement through upper Miocene sandstones and carbonates deposited as synrift strata and as marine shoreline, deltaic-fluvial, and deep-water strata. Carbonate and sandstone reservoirs produce oil and gas primarily from anticlinal traps of Plio-Pleistocene age. Stratigraphic trapping and faulting are important locally. Production is compartmentalized due to numerous intraformational seals. The regional marine shale seal, deposited by a maximum sea level highstand in early middle Miocene time, was faulted during post-depositional folding allowing migration of hydrocarbons to reservoirs above the seal. The province contains the Lahat/Talang Akar-Cenozoic total petroleum system with one assessment unit, South Sumatra.

Chronic autoimmune thyroiditis in industrial areas in Brazil: a 15-year survey.

PubMed

Zaccarelli-Marino, Maria Angela

2012-10-01

To investigate whether there is an increased incidence of chronic autoimmune thyroiditis (CAT) in individuals living in the vicinity of industrial plants that manufacture petroleum byproducts in the state of São Paulo, Brazil. Between 1989 and 2004, 6,306 patients of both sexes, from 5 to 78 years old were divided in two groups according to their home location: Group 1: 3,356 residents living near industrial plants that manufacture petroleum byproducts (Region A), and Group 2: 2,950 residents living far from Region A in an area with predominantly steel industries (Region B). For all patients, we measured the serum levels of antithyroglobulin antibody, antithyroperoxidase antibody, triiodothyronine, thyroxine, free thyroxine and thyrostimulating hormone. Sonographic scans of the thyroid gland were also conducted. The proportion of patients with CAT coming from Region A increased from 2.5 % (5 patients with CAT/200 total patients) in 1992 to 57.6 % (106 patients with CAT/184 total patients) in 2001. This striking increase was highly significant (p < 0.001). Similar findings were not observed in Region B. The difference in the number of patients with CAT between 1989 and 2004 coming from Region A and Region B was highly significant (p < 0.001), with 905 CAT patients (83.95 %) in Region A and 173 CAT patients (16.05 %) in Region B. Our results showed a striking increase in the incidence of CAT in residents in the vicinity of large industrial plants that manufacture petroleum byproducts compared with residents living near steel industries, which opens the field to new areas of research.

Effects of Low Temperature and Freeze-Thaw Cycles on Hydrocarbon Biodegradation in Arctic Tundra Soil

PubMed Central

Eriksson, Mikael; Ka, Jong-Ok; Mohn, William W.

2001-01-01

Degradation of petroleum hydrocarbons was monitored in microcosms with diesel fuel-contaminated Arctic tundra soil incubated for 48 days at low temperatures (−5, 0, and 7°C). An additional treatment was incubation for alternating 24-h periods at 7 and −5°C. Hydrocarbons were biodegraded at or above 0°C, and freeze-thaw cycles may have actually stimulated hydrocarbon biodegradation. Total petroleum hydrocarbon (TPH) removal over 48 days in the 7, 0, and 7 and −5°C treatments, respectively, was 450, 300, and 600 μg/g of soil. No TPH removal was observed at −5°C. Total carbon dioxide production suggested that TPH removal was due to biological mineralization. Bacterial metabolic activity, indicated by RNA/DNA ratios, was higher in the middle of the experiment (day 21) than at the start, in agreement with measured hydrocarbon removal and carbon dioxide production activities. The total numbers of culturable heterotrophs and of hydrocarbon degraders did not change significantly over the 48 days of incubation in any of the treatments. At the end of the experiment, bacterial community structure, evaluated by ribosomal intergenic spacer length analysis, was very similar in all of the treatments but the alternating 7 and −5°C treatment. PMID:11679333

Brine-in-crude-oil emulsions at the Strategic Petroleum Reserve

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nemer, Martin B.; Lord, David L.; MacDonald, Terry L.

2013-10-01

Metastable water-in-crude-oil emulsion formation could occur in a Strategic Petroleum Reserve (SPR) cavern if water were to flow into the crude-oil layer at a sufficient rate. Such a situation could arise during a drawdown from a cavern with a broken-hanging brine string. A high asphaltene content (> 1.5 wt %) of the crude oil provides the strongest predictor of whether a metastable water-in-crude-oil emulsion will form. However there are many crude oils with an asphaltene content > 1.5 wt % that don't form stable emulsions, but few with a low asphaltene content that do form stable emulsions. Most of themore » oils that form stable emulsions are "sour" by SPR standards indicating they contain total sulfur > 0.50 wt %.« less

Mining machinery/equipment/parts/services. Oil and gas field equipment/machinery/parts/supplies (Ecuador). Refinery equipment, parts, and accessories, March 1991. Export trade information

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1991-03-01

The petroleum sector in Ecuador brings in about 65 percent of the country's revenue. Three of the refineries are located in the coastal region. The other two, plus the Liquified Petroleum Gas Plant (LPG), are located in the Oriente region (Amazon jungle). The refineries operate at about 85% of their installation capacity. The Petroindustrial and Petropeninsula investment plan for 1991 comtemplates the expansion of the Esmeraldas refinery to 110,000 barrels a day, and the up-grading of the Shushufindi and Libertad refineries located near the city of Guayaquil. The United States is by far the largest supplier of refinery equipment, partsmore » and accessories, controlling about 90% of the total market.« less

Enhancement of biodegradation of crude petroleum-oil in contaminated water by the addition of nitrogen sources.

PubMed

Mukred, A M; Hamid, A A; Hamzah, A; Yusoff, W M Wan

2008-09-01

Addition of nitrogen sources as supplementary nutrient into MSM medium to enhance biodegradation by stimulating the growth four isolates, Acinetobacter faecalis, Staphylococcus sp., Pseudomonas putida and Neisseria elongata isolated from petroleum contaminated groundwater, wastewater aeration pond and biopond at the oil refinery Terengganu Malaysia was investigated. The organic nitrogen sources tested not only supported growth but also enhances biodegradation of 1% Tapis crude oil. All four isolates showed good growth especially when peptone was employed as the organic nitrogen compared to growth in the basal medium. Gas chromatography showed that more then 91, 93, 94 and 95% degradation of total hydrocarbon was observed after 5 days of incubation by isolates Pseudomonas putida, Neisseria elongate, Acinetobacter faecalis and Staphylococcus sp., respectively.

Development and Dissemination of a Nationwide Helium Database for a National Assessment of Helium Resources.

NASA Astrophysics Data System (ADS)

Brennan, S. T.; East, J. A., II; Garrity, C. P.

2015-12-01

In 2013, Congress passed the Helium Stewardship Act requiring the U.S. Geological Survey (USGS) to undertake a national helium gas resource assessment to determine the nation's helium resources. An important initial component necessary to complete this assessment was the development of a comprehensive database of Helium (He) concentrations from petroleum exploration wells. Because Helium is often used as the carrier gas for compositional analyses for commercial and exploratory oil and gas wells, this limits the available helium concentration data. A literature search in peer-reviewed publications, state geologic survey databases, USGS energy geochemical databases, and the Bureau of Land Management databases provided approximately 16,000 data points from wells that had measurable He concentrations in the gas composition analyses. The data from these wells includes, date of sample collection, American Petroleum Institute well number, formation name, field name, depth of sample collection, and location. The gas compositional analyses, some performed as far back as 1934, do not all have the same level of precision and accuracy, therefore the date of the analysis is critical to the assessment as it indicates the relative amount of uncertainty in the analytical results. Non-proprietary data was used to create a GIS based interactive web interface that allows users to visualize, inspect, interact, and download our most current He data. The user can click on individual locations to see the available data at that location, as well as zoom in and out on a data density map. Concentrations on the map range from .04 mol% (lowest concentration of economic value) to 12% (highest naturally occurring values). This visual interface will allow users to develop a rapid appreciation of the areas with the highest potential for high helium concentrations within oil and gas fields.

Genotoxicity evaluation of buprofezin, petroleum oil and profenofos in somatic and germ cells of male mice.

PubMed

Fahmy, M A; Abdalla, E F

1998-01-01

The two pest control agents, buprofezin and petroleum oil (Super Royal), were tested to evaluate their potential mutagenicity, in comparison with the organophosphorus insecticide profenofos. Chromosomal aberration analysis was used in both somatic and germ cells of male mice. Single oral treatment at three different dose levels (1/16, 1/8 and 1/4 LD50) for each insecticide induced an increase in the percentage of chromosomal aberrations in bone-marrow cells 24 h post-treatment, indicating a dose-dependent relationship. The percentage of chromosomal aberrations reached 23 +/- 0.73, 10.5 +/- 0.64 and 15 +/- 1.4 after treatment with the highest tested dose of profenofos, buprofezin and Super Royal, respectively. Such percentages did not exceed the corresponding value of the positive control, mitomycin C (29.2 +/- 0.69). The percentage of chromosomal aberrations induced by the different doses of profenofos was still highly significant even after excluding gaps. The same trend of results was noticed only at the highest tested dose of buprofezin and Super Royal. With respect to germ cells, profenofos is also a potent inducer of chromosomal aberrations in 1ry spermatocytes, giving percentages of 14 +/- 1.3 and 19 +/- 1.6 at the two higher doses of 4.25 and 8.5 mg kg(-1) body wt., respectively. Buprofezin and Super Royal had no significant effect on mouse spermatocytes at the tested concentrations. The various types of induced aberrations were examined and recorded in both somatic and germ cells. In conclusion, the present investigation indicates that the two pest control agents buprofezin and Super Royal are relatively much safer compounds than the conventional organophosphorus insecticides.

Petroleum Quality Information System 2013 Annual Report

DTIC Science & Technology

2013-01-01

Content: (ppm) 10 0.10 Metals : (ppm) 0.5 total 0.10 Alkali Metals and Metalloids: (ppm) 1 total 0.99 Table 3-12 displays Direct Sugar to ...183 146 189 185 111 143 0 50 100 150 200 250 300 350 400 450 2005 2006 2007 2008 2009 2010 2011 2012 2013 To ta l S am pl es Calendar Year In-Line...Report Documentation Page Form ApprovedOMB No. 0704-0188 Public reporting burden for the collection of information is estimated to average 1 hour

40 CFR 280.92 - Definition of terms.

Code of Federal Regulations, 2010 CFR

2010-07-01

... financial assurances. Petroleum marketing facilities include all facilities at which petroleum is produced... marketers or to the public. Petroleum marketing firms are all firms owning petroleum marketing facilities. Firms owning other types of facilities with USTs as well as petroleum marketing facilities are...

Petroleum and individual polycyclic aromatic hydrocarbons

USGS Publications Warehouse

Albers, Peter H.; Hoffman, David J.; Rattner, Barnett A.; Burton, G. Allen; Cairns, John

1995-01-01

Crude petroleum, refined-petroleum products, and individual polycyclic aromatic hydrocarbons (PAHs) contained within petroleum are found throughout the world. their presence has been detected in living and nonliving components of ecosystems. Petroleum can be an environmental hazard for wild animals and plants. Individual PAHs are also hazardous to wildlife, but they are most commonly associated with human illnesses. Because petroleum is a major environmental source of these PAHs, petroleum and PAHs are jointly presented in this chapter. Composition, sources, environmental fate, and toxic effects on all living components of aquatic and terrestrial environments are addessed.

Chapter 2. Assessment of undiscovered conventional oil and gas resources--Upper Jurassic-Lower Cretaceous Cotton Valley group, Jurassic Smackover interior salt basins total petroleum system, in the East Texas basin and Louisiana-Mississippi salt basins provinces.

USGS Publications Warehouse

Dyman, T.S.; Condon, S.M.

2006-01-01

The Jurassic Smackover Interior Salt Basins Total Petroleum System is defined for this assessment to include (1) Upper Jurassic Smackover Formation carbonates and calcareous shales and (2) Upper Jurassic and Lower Cretaceous Cotton Valley Group organic-rich shales. The Jurassic Smackover Interior Salt Basins Total Petroleum System includes four conventional Cotton Valley assessment units: Cotton Valley Blanket Sandstone Gas (AU 50490201), Cotton Valley Massive Sandstone Gas (AU 50490202), Cotton Valley Updip Oil and Gas (AU 50490203), and Cotton Valley Hypothetical Updip Oil (AU 50490204). Together, these four assessment units are estimated to contain a mean undiscovered conventional resource of 29.81 million barrels of oil, 605.03 billion cubic feet of gas, and 19.00 million barrels of natural gas liquids. The Cotton Valley Group represents the first major influx of clastic sediment into the ancestral Gulf of Mexico. Major depocenters were located in south-central Mississippi, along the Louisiana-Mississippi border, and in northeast Texas. Reservoir properties and production characteristics were used to identify two Cotton Valley Group sandstone trends across northern Louisiana and east Texas: a high-permeability blanket-sandstone trend and a downdip, low-permeability massive-sandstone trend. Pressure gradients throughout most of both trends are normal, which is characteristic of conventional rather than continuous basin-center gas accumulations. Indications that accumulations in this trend are conventional rather than continuous include (1) gas-water contacts in at least seven fields across the blanket-sandstone trend, (2) relatively high reservoir permeabilities, and (3) high gas-production rates without fracture stimulation. Permeability is sufficiently low in the massive-sandstone trend that gas-water transition zones are vertically extensive and gas-water contacts are poorly defined. The interpreted presence of gas-water contacts within the Cotton Valley massive-sandstone trend, however, suggests that accumulations in this trend are also conventional.

Assessment of the Mesaverde Total Petroleum System in Southwestern Wyoming Province: a petroleum system approach to assessing undiscovered oil and gas resources

USGS Publications Warehouse

Johnson, Ronald C.; Finn, Thomas M.

2003-01-01

The U.S. Geological Survey, in a recent assessment of the undiscovered oil and gas resources in the Southwestern Wyoming Province using a Total Petroleum System (TPS) approach, estimated a mean of 84.6 trillion cubic feet of gas (TCFG), 131 million barrels of oil (MMBO) and 2.6 billion barrels of natural gas liquids (BBNGL) that have the potential to be added to reserves over the next 30 years. Only a fraction of this, however, may be economically recoverable . Of the total estimate of 84.6 TCFG, a mean of 25.78 TCFG is in continuous-type reservoirs in the Mesaverde TPS. The Mesaverde TPS is defined as all reservoirs predominantly containing gas derived from the Mesaverde Group east of the pinchout of the Lewis Shale, which acts as a top seal separating the Mesaverde TPS from the overlying Lewis TPS. Continuous-type reservoirs in the Mesaverde TPS were subdivided into the Almond Continuous Gas Assessment Unit (AU) (mean of 13.35 TCFG), Rock Springs-Ericson Continuous Gas AU (mean of 12.18 TCFG), and the Mesaverde Coalbed Gas AU (mean of 0.25 TCFG). Geologic analysis was used to determine the favorable ?sweet spots? for potential gas resources. The Almond AU has been heavily explored at depths less than 11,000 ft, thus additions to reserves will most likely be the result of infill drilling in existing fields and the discovery of sweet spots at depths greater than 11,000 ft. There is much uncertainty in the size of undiscovered resource in the Rock Springs-Ericson AU because potential reservoirs are only sparsely explored. Only a small fraction of in-place coal-bed gas is considered to be recoverable because of low permeability and problems posed by produced water.

GC estimation of organic hydrocarbons that threaten shallow Quaternary sandy aquifer Northwestern Gulf of Suez, Egypt.

PubMed

Zawrah, M F; Ebiad, M A; Rashad, A M; El-Sayed, E; Snousy, Moustafa Gamal; Tantawy, M A

2014-11-01

Soil and groundwater contamination is one of the important environmental problems at petroleum-related sites, which causes critical environmental and health defects. Severe petroleum hydrocarbon contamination from coastal refinery plant was detected in a shallow Quaternary sandy aquifer is bordered by Gulf in the Northwestern Gulf of Suez, Egypt. The overall objective of this investigation is to estimate the organic hydrocarbons in shallow sandy aquifers, released from continuous major point-source of pollution over a long period of time (91 years ago). This oil refinery contamination resulted mainly in the improper disposal of hydrocarbons and produced water releases caused by equipment failures, vandalism, and accidents that caused direct groundwater pollution or discharge into the gulf. In order to determine the fate of hydrocarbons, detailed field investigations were made to provide intensive deep profile information. Eight composite randomly sediment samples from a test plot were selected for demonstration. The tested plot was 50 m long × 50 m wide × 70 cm deep. Sediment samples were collected using an American auger around the point 29° 57' 33″ N and 32° 30' 40″ E in 2012 and covered an area of 2,500 m(2) which represents nearly 1/15 of total plant area (the total area of the plant is approximately 3.250 km(2)). The detected total petroleum hydrocarbons (TPHs) were 2.44, 2.62, 4.54, 4.78, 2.83, 3.22, 2.56, and 3.13 wt%, respectively. TPH was calculated by differences in weight and subjected to gas chromatography (GC). Hydrocarbons were analyzed on Hewlett-Packard (HP-7890 plus) gas chromatograph equipped with a flame ionization detector (FID). The percentage of paraffine of the investigated TPH samples was 7.33, 7.24, 7.58, 8.25, 10.25, 9.89, 14.77, and 17.53 wt%, respectively.