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Sample records for hysteresis curve shows

  1. Hysteresis and uncertainty in soil water-retention curve parameters

    USGS Publications Warehouse

    Likos, William J.; Lu, Ning; Godt, Jonathan W.

    2014-01-01

    Accurate estimates of soil hydraulic parameters representing wetting and drying paths are required for predicting hydraulic and mechanical responses in a large number of applications. A comprehensive suite of laboratory experiments was conducted to measure hysteretic soil-water characteristic curves (SWCCs) representing a wide range of soil types. Results were used to quantitatively assess differences and uncertainty in three simplifications frequently adopted to estimate wetting-path SWCC parameters from more easily measured drying curves. They are the following: (1) αw=2αd, (2) nw=nd, and (3) θws=θds, where α, n, and θs are fitting parameters entering van Genuchten’s commonly adopted SWCC model, and the superscripts w and d indicate wetting and drying paths, respectively. The average ratio αw/αd for the data set was 2.24±1.25. Nominally cohesive soils had a lower αw/αd ratio (1.73±0.94) than nominally cohesionless soils (3.14±1.27). The average nw/nd ratio was 1.01±0.11 with no significant dependency on soil type, thus confirming the nw=nd simplification for a wider range of soil types than previously available. Water content at zero suction during wetting (θws) was consistently less than during drying (θds) owing to air entrapment. The θws/θds ratio averaged 0.85±0.10 and was comparable for nominally cohesive (0.87±0.11) and cohesionless (0.81±0.08) soils. Regression statistics are provided to quantitatively account for uncertainty in estimating hysteretic retention curves. Practical consequences are demonstrated for two case studies.

  2. Hysteresis Phenomenon in Heat-Voltage Curves of Polypyrrole-Coated Electrospun Nanofibrous and Regular Fibrous Mats

    NASA Astrophysics Data System (ADS)

    Oroumei, Azam; Tavanai, Hossein; Morshed, Mohammad

    2015-07-01

    This article verifies the hysteresis phenomenon in heat-voltage curves of polypyrrole-coated electrospun nanofibrous and regular fibrous mats. A third-order polynomial model fits the heat-voltage data better than a second-order polynomial model. It was also observed that the hysteresis loop area of nanofibrous and regular fibrous mats increases with decreasing fiber diameter. Moreover, the curvature of the hysteresis loops is significantly affected by the fiber diameter. In fact, the slope of the curvatures increases with decreasing fiber diameter.

  3. Control over hysteresis curves and thresholds of optical bistability in different semiconductor double quantum wells

    NASA Astrophysics Data System (ADS)

    H, R. Hamedi; M, R. Mehmannavaz; Hadi, Afshari

    2015-08-01

    The effects of optical field on the phenomenon of optical bistability (OB) are investigated in a K-type semiconductor double quantum well (SDQW) under various parametric conditions. It is shown that the OB threshold can be manipulated by increasing the intensity of coupling field. The dependence of the shift of OB hysteresis curve on probe wavelength detuning is then explored. In order to demonstrate controllability of the OB in this SDQW, we compare the OB features of three different configurations which could arise in this SDQW scheme, i.e., K-type, Y-type, and inverted Y-type systems. The controllability of this semiconductor nanostructure medium makes the presented OB scheme more valuable for applications in all-optical switches, information storage, and logic circuits of all optical information processing. Project supported by the Lithuanian Research Council (Grant No. VP1-3.1-ŠM-01-V-03-001).

  4. 25. VIEW TO EAST; SHOWS CURVE IN SOUTH RETAINING WALL ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    25. VIEW TO EAST; SHOWS CURVE IN SOUTH RETAINING WALL AND SIDEWALK ELECTROLIER ON ALISO STREET (Asano) - Los Angeles Union Passenger Terminal, Mail, Baggage, & Express Building, 800 North Alameda Street, Los Angeles, Los Angeles County, CA

  5. Hydrophobic/superhydrophobic oxidized metal surfaces showing negligible contact angle hysteresis.

    PubMed

    Hozumi, Atsushi; Cheng, Dalton F; Yagihashi, Makoto

    2011-01-15

    Dynamic wettability of oxidized metal (aluminum and titanium) surfaces could be tuned by chemical vapor deposition (CVD) of 1,3,5,7-tetramethylcyclotetrasiloxane (D(4)(H)). This facile CVD method produces not only monomeric layers but also particulate films by changing the CVD temperature, resulting in a marked difference in the final wetting properties. In the samples prepared at 80°C for ~3 days, D(4)(H) layers with thicknesses of ~0.5 nm were formed on the surfaces without discernible change in surface morphology, as evidenced by X-ray photoelectron spectroscopy and atomic force microscopy. After this D(4)(H) monomeric layer formation, the hydrophilic oxidized aluminum and titanium surfaces became hydrophobic (advancing/receding water contact angles (θ(A)/θ(R))=102-104°/99-102°) showing essentially negligible contact angle hysteresis. Performing CVD of D(4)(H) at 180°C for ~1 day produced opaque film with particulate morphologies with diameters in the range of 500 nm to 4 μm observed on the surfaces. This geometric morphology enhanced the surface hydrophobicity (θ(A)/θ(R)=163°/160-161°). Droplets on these negligible-hysteresis surfaces moved very easily without "pinning".

  6. Modeling hysteresis curves of anisotropic SmCoFeCuZr magnets

    NASA Astrophysics Data System (ADS)

    Sampaio da Silva, Fernanda A.; Castro, Nicolau A.; de Campos, Marcos F.

    2013-02-01

    The hysteresis curves at room temperature and at 630 K of an anisotropic magnet were successfully modeled with the Stoner-Wohlfarth Callen-Liu-Cullen (SW-CLC) model. This implies that coherent rotation of domains is the reversal mechanism in this magnet. The chemical composition of the evaluated magnet is Sm(CobalFe0.06Cu0.108Zr0.03)7.2. The anisotropy field HA was estimated with the model, resulting μ0HA=7.1 T at the room temperature, and 2.9 T at 630 K. For this sample, the CLC interaction parameter (1/d) is very low (near zero) and, thus, the nanocrystalline 2:17 grains are well "magnetically decoupled". The texture analysis using Schulz Pole figure data indicated Mr/Ms ratio=0.96, and this means that the magnet is very well aligned. The excellent alignment of the grains is one of the reasons for the high coercivity of this sample (˜4 T at room temperature).

  7. 14. VIEW FROM TUNDRA CURVES (ON TRAIL RIDGE ROAD) SHOWING ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    14. VIEW FROM TUNDRA CURVES (ON TRAIL RIDGE ROAD) SHOWING FALL RIVER ROAD RISING FROM BENEATH CHAPIN PASS (AT EXTREME RIGHT) TO FALL RIVER PASS (FAR LEFT). - Fall River Road, Between Estes Park & Fall River Pass, Estes Park, Larimer County, CO

  8. Interior detail, building 810, view to north showing curved chord ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    Interior detail, building 810, view to north showing curved chord sections of roof trusses, 90mm lens plus electronic flash fill lighting. - Travis Air Force Base, B-36 Hangar, Between Woodskill Avenue & Ellis, adjacent to Taxiway V & W, Fairfield, Solano County, CA

  9. A measurement of the hysteresis loop in force-spectroscopy curves using a tuning-fork atomic force microscope

    PubMed Central

    van Vörden, Dennis; Möller, Rolf

    2012-01-01

    Summary Measurements of the frequency shift versus distance in noncontact atomic force microscopy (NC-AFM) allow measurements of the force gradient between the oscillating tip and a surface (force-spectroscopy measurements). When nonconservative forces act between the tip apex and the surface the oscillation amplitude is damped. The dissipation is caused by bistabilities in the potential energy surface of the tip–sample system, and the process can be understood as a hysteresis of forces between approach and retraction of the tip. In this paper, we present the direct measurement of the whole hysteresis loop in force-spectroscopy curves at 77 K on the PTCDA/Ag/Si(111) √3 × √3 surface by means of a tuning-fork-based NC-AFM with an oscillation amplitude smaller than the distance range of the hysteresis loop. The hysteresis effect is caused by the making and breaking of a bond between PTCDA molecules on the surface and a PTCDA molecule at the tip. The corresponding energy loss was determined to be 0.57 eV by evaluation of the force–distance curves upon approach and retraction. Furthermore, a second dissipation process was identified through the damping of the oscillation while the molecule on the tip is in contact with the surface. This dissipation process occurs mainly during the retraction of the tip. It reaches a maximum value of about 0.22 eV/cycle. PMID:22496993

  10. A measurement of the hysteresis loop in force-spectroscopy curves using a tuning-fork atomic force microscope.

    PubMed

    Lange, Manfred; van Vörden, Dennis; Möller, Rolf

    2012-01-01

    Measurements of the frequency shift versus distance in noncontact atomic force microscopy (NC-AFM) allow measurements of the force gradient between the oscillating tip and a surface (force-spectroscopy measurements). When nonconservative forces act between the tip apex and the surface the oscillation amplitude is damped. The dissipation is caused by bistabilities in the potential energy surface of the tip-sample system, and the process can be understood as a hysteresis of forces between approach and retraction of the tip. In this paper, we present the direct measurement of the whole hysteresis loop in force-spectroscopy curves at 77 K on the PTCDA/Ag/Si(111) √3 × √3 surface by means of a tuning-fork-based NC-AFM with an oscillation amplitude smaller than the distance range of the hysteresis loop. The hysteresis effect is caused by the making and breaking of a bond between PTCDA molecules on the surface and a PTCDA molecule at the tip. The corresponding energy loss was determined to be 0.57 eV by evaluation of the force-distance curves upon approach and retraction. Furthermore, a second dissipation process was identified through the damping of the oscillation while the molecule on the tip is in contact with the surface. This dissipation process occurs mainly during the retraction of the tip. It reaches a maximum value of about 0.22 eV/cycle.

  11. Organic matter turnover in a tropical floodplain shows hysteresis during a flood cycle

    NASA Astrophysics Data System (ADS)

    Zuijdgeest, Alissa; Baumgartner, Simon; Wehrli, Bernhard

    2016-04-01

    Tropical inland waters are increasingly recognized for their role in the global carbon cycle, but uncertainty about the effects of such systems on the transported organic matter remains. The seasonal interactions between river, floodplain, and vegetation result in highly dynamic systems, which can exhibit markedly different biogeochemical patterns throughout a flood cycle. In this study, we investigated patterns and rates of organic matter turnover, and determined responsible processes. Multi-probes upstream and downstream of the Barotse Plains, a pristine floodplain in the Upper Zambezi (Zambia), provided a high-resolution data set over the course of a hydrological cycle. Concentrations of oxygen, carbon dioxide, dissolved organic carbon, and suspended particulate matter in water column of the main channel showed clear hysteresis trends relative to hydrological parameters. Considering that the respiration rate in the river water remained rather low and stable throughout the year, these patterns indicated that degradation of the terrestrial organic matter was mainly occurring on the floodplain. We suggest that the main location of terrestrially-derived organic matter degradation in river-floodplain systems shifts during a flood cycle from the water of the main channel, to the soil-water interface on the floodplain when the water spends more time on the floodplain.

  12. Kinetic effects on double hysteresis in spin crossover molecular magnets analyzed with first order reversal curve diagram technique

    SciTech Connect

    Stan, Raluca-Maria; Gaina, Roxana; Enachescu, Cristian E-mail: radu.tanasa@uaic.ro; Stancu, Alexandru; Tanasa, Radu E-mail: radu.tanasa@uaic.ro; Bronisz, Robert

    2015-05-07

    In this paper, we analyze two types of hysteresis in spin crossover molecular magnets compounds in the framework of the First Order Reversal Curve (FORC) method. The switching between the two stable states in these compounds is accompanied by hysteresis phenomena if the intermolecular interactions are higher than a threshold. We have measured the static thermal hysteresis (TH) and the kinetic light induced thermal hysteresis (LITH) major loops and FORCs for the polycrystalline Fe(II) spin crossover compound [Fe{sub 1−x}Zn{sub x}(bbtr){sub 3}](ClO{sub 4}){sub 2} (bbtr = 1,4-di(1,2,3-triazol-1-yl)butane), either in a pure state (x = 0) or doped with Zn ions (x = 0.33) considering different sweeping rates. Here, we use this method not only to infer the domains distribution but also to disentangle between kinetic and static components of the LITH and to estimate the changes in the intermolecular interactions introduced by dopants. We also determined the qualitative relationship between FORC distributions measured for TH and LITH.

  13. Analysis of first order reversal curves in the thermal hysteresis of spin-crossover nanoparticles within the mechanoelastic model

    SciTech Connect

    Stoleriu, Laurentiu E-mail: cristian.enachescu@uaic.ro; Stancu, Alexandru; Enachescu, Cristian E-mail: cristian.enachescu@uaic.ro; Chakraborty, Pradip; Hauser, Andreas

    2015-05-07

    The recently obtained spin-crossover nanoparticles are possible candidates for applications in the recording media industry as materials for data storage, or as pressure and temperature sensors. For these applications, the intermolecular interactions and interactions between spin-crossover nanoparticles are extremely important, as they may be essential factors in triggering the transition between the two stable phases: the high-spin and low-spin ones. In order to find correlations between the distributions in size and interactions and the transition temperatures distribution, we apply the FORC (First Order Reversal Curves) method, using simulations based on a mechanoelastic model applied to 2D triangular lattices composed of molecules linked by springs and embedded in a surfactant. We consider two Gaussian distributions: one is the size of the nanoparticles and another is the elastic interactions between edge spin-crossover molecules and the surfactant molecules. In order to disentangle the kinetic and non-kinetic parts of the FORC distributions, we compare the results obtained for different temperature sweeping rates. We also show that the presence of few larger particles in a distribution centered around much smaller particles dramatically increases the hysteresis width.

  14. Interacting Stoner-Wohlfarth behavior in hysteresis curves of Sm(CoFeCuZr) z magnets

    NASA Astrophysics Data System (ADS)

    Romero, S. A.; de Campos, M. F.; Rechenberg, H. R.; Missell, F. P.

    Several magnets with different Zr contents were studied: Sm(Co balFe 0.2Cu 0.1Zr x) 8 (bal=balance; x=0, 0.02, 0.04, 0.06 and 0.08). The microstructure of the magnets includes three main phases, all crystallographically coherent: the cell phase Sm 2(Co,Fe) 17, the cell boundary phase Sm(Co,Cu) 5 and a lamellar Zr-rich phase, rhombohedral (ZrSm) 1Co 3. The hysteresis curves were compared with the Callen, Liu and Cullen (CLC) modification of the Stoner-Wohlfarth model for an isotropic distribution of interacting single-domain particles. Choosing reasonable values for the saturation magnetization Ms, the anisotropy field Ha, and the mean-field interactions of the CLC model, we were able to reproduce the main features of the hysteresis curves for the x=0.02 and 0.04 samples. For higher x values, X-ray diffraction Rietveld analysis revealed the presence of other "impurity" phases, among them cubic Zr 6(Co,Fe) 23, rhombohedral (SmZr) 5(CoFeCu) 19 and rhombohedral (SmZr) 2(CoFeCu) 7.

  15. Influence of the applied elastic tensile and compressive stress on the hysteresis curves of Fe-3%Si non-oriented steel

    NASA Astrophysics Data System (ADS)

    Perevertov, O.

    2017-04-01

    The influence of applied elastic tensile stress up to 120 MPa and compressive stress up to 35 MPa on the magnetic hysteresis curves of non-oriented Fe-3%Si steel is studied. In two tensile stress ranges the hysteresis loop changed monotonously - low stress below 10 MPa facilitated the magnetization process, while above 15 MPa tension deteriorated magnetic properties. This difference in behavior corresponds to two different mechanisms - 1) favoring by tensile stress magnetic easy axes closest to the filed direction and 2) appearance of large demagnetizing fields at grain boundaries and the sample surface. Compression continuously deteriorated magnetic properties and made the hysteresis loop constricted above a few MPa. The effective field as a product of two functions - of the magnetization and of the stress gave excellent agreement with experimental curves for both tensile stress ranges and for compression. The sensitivity of magnetization to compression was approximately five times larger than to tension. The complex hysteresis loop behavior under tension and compression was explained on the basis of our previous results on stressed grain-oriented steel of the same composition, in which the magnetic domains were also studied.

  16. Zero-dipole molecular organic cations in mixed organic-inorganic halide perovskites: possible chemical solution for the reported anomalous hysteresis in the current-voltage curve measurements.

    PubMed

    Giorgi, Giacomo; Yamashita, Koichi

    2015-11-06

    Starting from a brief description of the main architectures characterizing the novel solar technology of perovskite-based solar cells, we focus our attention on the anomalous hysteresis experimentally found to affect the measurement of the current-voltage curve of such devices. This detrimental effect, associated with slow dynamic reorganization processes, depends on several parameters; among them, the scan rate of the measurements, the architecture of the cell, and the perovskite deposition rate are crucial. Even if a conclusive explanation of the origin of the hysteresis has not been provided so far, several experimental findings ascribe its origin to ionic migration at an applied bias and dielectric polarization that occurs in the perovskite layer. Consistently, a dipole-moment-reduced cation such as formamidinium ion is experimentally reported to quantitatively reduce the hysteresis from perovskite-based devices. By means of a density-functional theory-based set of calculations, we have predicted and characterized guanidinium ion (GA = (+)[C(NH2)3], a zero-dipole moment cation by symmetry)-based organic-inorganic halide perovskite's structural and electronic properties, speculating that such a cation and the alloys it may form with other organic cations can represent a possible chemical solution for the puzzling issue of the hysteresis.

  17. The Transcriptional Heat Shock Response of Salmonella Typhimurium Shows Hysteresis and Heated Cells Show Increased Resistance to Heat and Acid Stress

    PubMed Central

    Pin, Carmen; Hansen, Trine; Muñoz-Cuevas, Marina; de Jonge, Rob; Rosenkrantz, Jesper T.; Löfström, Charlotta; Aarts, Henk; Olsen, John E.

    2012-01-01

    We investigated if the transcriptional response of Salmonella Typhimurium to temperature and acid variations was hysteretic, i.e. whether the transcriptional regulation caused by environmental stimuli showed memory and remained after the stimuli ceased. The transcriptional activity of non-replicating stationary phase cells of S. Typhimurium caused by the exposure to 45°C and to pH 5 for 30 min was monitored by microarray hybridizations at the end of the treatment period as well as immediately and 30 minutes after conditions were set back to their initial values, 25°C and pH 7. One hundred and two out of 120 up-regulated genes during the heat shock remained up-regulated 30 minutes after the temperature was set back to 25°C, while only 86 out of 293 down regulated genes remained down regulated 30 minutes after the heat shock ceased. Thus, the majority of the induced genes exhibited hysteresis, i.e., they remained up-regulated after the environmental stress ceased. At 25°C the transcriptional regulation of genes encoding for heat shock proteins was determined by the previous environment. Gene networks constructed with up-regulated genes were significantly more modular than those of down-regulated genes, implying that down-regulation was significantly less synchronized than up-regulation. The hysteretic transcriptional response to heat shock was accompanied by higher resistance to inactivation at 50°C as well as cross-resistance to inactivation at pH 3; however, growth rates and lag times at 43°C and at pH 4.5 were not affected. The exposure to pH 5 only caused up-regulation of 12 genes and this response was neither hysteretic nor accompanied of increased resistance to inactivation conditions. Cellular memory at the transcriptional level may represent a mechanism of adaptation to the environment and a deterministic source of variability in gene regulation. PMID:23236453

  18. Effect of applied tensile stress on the hysteresis curve and magnetic domain structure of grain-oriented transverse Fe-3%Si steel

    NASA Astrophysics Data System (ADS)

    Perevertov, O.; Thielsch, J.; Schäfer, R.

    2015-07-01

    The effect of an elastic applied tensile stress on the quasistatic hysteresis curve and domain structure in conventional (110) [001] Fe-3%Si steel, cut transversely to the rolling direction, is studied. The magnetic domains and magnetization processes were observed by longitudinal Kerr microscopy at different levels of stress. It is shown that above 8 MPa the bulk hysteresis loop can be described with a good accuracy by the action of an effective field, which is the product of the stress and a function of magnetization. Domain observation reveals that the reasons for the effective field are demagnetizing fields due to the disappearance of supplementary domains at low applied field and the formation of different domain systems in different grains at low and moderate fields. The latter are caused by differences in grain sensitivity to stress depending on the degree of misorientation and grain boundary orientation. A decrease of the effective field above 1 T is connected with a transformation of all grains into the same domain system - the column pattern. The hysteresis loop behavior is qualitatively the same as for strips cut in rolling direction and for non-oriented strips.

  19. Hysteresis in Muscle

    NASA Astrophysics Data System (ADS)

    Ramos, Jorgelina; Lynch, Stephen; Jones, David; Degens, Hans

    This paper presents examples of hysteresis from a broad range of scientific disciplines and demonstrates a variety of forms including clockwise, counterclockwise, butterfly, pinched and kiss-and-go, respectively. These examples include mechanical systems made up of springs and dampers which have been the main components of muscle models for nearly one hundred years. For the first time, as far as the authors are aware, hysteresis is demonstrated in single fibre muscle when subjected to both lengthening and shortening periodic contractions. The hysteresis observed in the experiments is of two forms. Without any relaxation at the end of lengthening or shortening, the hysteresis loop is a convex clockwise loop, whereas a concave clockwise hysteresis loop (labeled as kiss-and-go) is formed when the muscle is relaxed at the end of lengthening and shortening. This paper also presents a mathematical model which reproduces the hysteresis curves in the same form as the experimental data.

  20. Hysteresis in single and polycrystalline iron thin films: Major and minor loops, first order reversal curves, and Preisach modeling

    NASA Astrophysics Data System (ADS)

    Cao, Yue; Xu, Ke; Jiang, Weilin; Droubay, Timothy; Ramuhalli, Pradeep; Edwards, Danny; Johnson, Bradley R.; McCloy, John

    2015-12-01

    Hysteretic behavior was studied in a series of Fe thin films, grown by molecular beam epitaxy, having different grain sizes and grown on different substrates. Major and minor loops and first order reversal curves (FORCs) were collected to investigate magnetization mechanisms and domain behavior under different magnetic histories. The minor loop coefficient and major loop coercivity increase with decreasing grain size due to higher defect concentration resisting domain wall movement. First order reversal curves allowed estimation of the contribution of irreversible and reversible susceptibilities and switching field distribution. The differences in shape of the major loops and first order reversal curves are described using a classical Preisach model with distributions of hysterons of different switching fields, providing a powerful visualization tool to help understand the magnetization switching behavior of Fe films as manifested in various experimental magnetization measurements.

  1. Modeling of sharp change in magnetic hysteresis behavior of electrical steel at small plastic deformation

    SciTech Connect

    Sablik, M.J.; Rios, S.; Landgraf, F.J.G.; Yonamine, T.; Campos, M.F. de

    2005-05-15

    In 2.2% Si electrical steel, the magnetic hysteresis behavior is sharply sheared by a rather small plastic deformation (0.5%). A modification to the Jiles-Atherton hysteresis model makes it possible to model magnetic effects of plastic deformation. In this paper, with this model, it is shown how a narrow hysteresis with an almost steplike hysteresis curve for an undeformed specimen is sharply sheared by plastic deformation. Computed coercivity and hysteresis loss show a sharp step to higher values at small strain due to an n=1/2 power law dependence on residual strain. The step is seen experimentally.

  2. Adsorption hysteresis, capillary condensation, and melting in multilayer methane films on graphite foam

    SciTech Connect

    Lysek, M.J.; LaMadrid, M.; Day, P.; Goodstein, D. )

    1992-03-01

    We have studied adsorption hysteresis in the system multilayer methane adsorbed on graphite foam by measuring heat capacities on each branch of the hysteresis curve. We are able to show that, on the stable branch, capillary condensation begins, surprisingly, at 1.1 layers. These observations call into question previous conclusions about this and other multilayer adsorbed systems. 27 refs., 3 figs.

  3. Light saturation curves show competence of the water splitting complex in inactive Photosystem II reaction centers.

    PubMed

    Nedbal, L; Gibas, C; Whitmarsh, J

    1991-12-01

    Photosystem II complexes of higher plants are structurally and functionally heterogeneous. While the only clearly defined structural difference is that Photosystem II reaction centers are served by two distinct antenna sizes, several types of functional heterogeneity have been demonstrated. Among these is the observation that in dark-adapted leaves of spinach and pea, over 30% of the Photosystem II reaction centers are unable to reduce plastoquinone to plastoquinol at physiologically meaningful rates. Several lines of evidence show that the impaired reaction centers are effectively inactive, because the rate of oxidation of the primary quinone acceptor, QA, is 1000 times slower than in normally active reaction centers. However, there are conflicting opinions and data over whether inactive Photosystem II complexes are capable of oxidizing water in the presence of certain artificial electron acceptors. In the present study we investigated whether inactive Photosystem II complexes have a functional water oxidizing system in spinach thylakoid membranes by measuring the flash yield of water oxidation products as a function of flash intensity. At low flash energies (less that 10% saturation), selected to minimize double turnovers of reaction centers, we found that in the presence of the artificial quinone acceptor, dichlorobenzoquinone (DCBQ), the yield of proton release was enhanced 20±2% over that observed in the presence of dimethylbenzoquinone (DMBQ). We argue that the extra proton release is from the normally inactive Photosystem II reaction centers that have been activated in the presence of DCBQ, demonstrating their capacity to oxidize water in repetitive flashes, as concluded by Graan and Ort (Biochim Biophys Acta (1986) 852: 320-330). The light saturation curves indicate that the effective antenna size of inactive reaction centers is 55±12% the size of active Photosystem II centers. Comparison of the light saturation dependence of steady state oxygen evolution

  4. Anomalous Hysteresis in Perovskite Solar Cells.

    PubMed

    Snaith, Henry J; Abate, Antonio; Ball, James M; Eperon, Giles E; Leijtens, Tomas; Noel, Nakita K; Stranks, Samuel D; Wang, Jacob Tse-Wei; Wojciechowski, Konrad; Zhang, Wei

    2014-05-01

    Perovskite solar cells have rapidly risen to the forefront of emerging photovoltaic technologies, exhibiting rapidly rising efficiencies. This is likely to continue to rise, but in the development of these solar cells there are unusual characteristics that have arisen, specifically an anomalous hysteresis in the current-voltage curves. We identify this phenomenon and show some examples of factors that make the hysteresis more or less extreme. We also demonstrate stabilized power output under working conditions and suggest that this is a useful parameter to present, alongside the current-voltage scan derived power conversion efficiency. We hypothesize three possible origins of the effect and discuss its implications on device efficiency and future research directions. Understanding and resolving the hysteresis is essential for further progress and is likely to lead to a further step improvement in performance.

  5. Plant Photosynthesis-Irradiance Curve Responses to Pollution Show Non-Competitive Inhibited Michaelis Kinetics

    PubMed Central

    Lin, Maozi; Wang, Zhiwei; He, Lingchao; Xu, Kang; Cheng, Dongliang; Wang, Genxuan

    2015-01-01

    Photosynthesis-irradiance (PI) curves are extensively used in field and laboratory research to evaluate the photon-use efficiency of plants. However, most existing models for PI curves focus on the relationship between the photosynthetic rate (Pn) and photosynthetically active radiation (PAR), and do not take account of the influence of environmental factors on the curve. In the present study, we used a new non-competitive inhibited Michaelis-Menten model (NIMM) to predict the co-variation of Pn, PAR, and the relative pollution index (I). We then evaluated the model with published data and our own experimental data. The results indicate that the Pn of plants decreased with increasing I in the environment and, as predicted, were all fitted well by the NIMM model. Therefore, our model provides a robust basis to evaluate and understand the influence of environmental pollution on plant photosynthesis. PMID:26561863

  6. Plant Photosynthesis-Irradiance Curve Responses to Pollution Show Non-Competitive Inhibited Michaelis Kinetics.

    PubMed

    Lin, Maozi; Wang, Zhiwei; He, Lingchao; Xu, Kang; Cheng, Dongliang; Wang, Genxuan

    2015-01-01

    Photosynthesis-irradiance (PI) curves are extensively used in field and laboratory research to evaluate the photon-use efficiency of plants. However, most existing models for PI curves focus on the relationship between the photosynthetic rate (Pn) and photosynthetically active radiation (PAR), and do not take account of the influence of environmental factors on the curve. In the present study, we used a new non-competitive inhibited Michaelis-Menten model (NIMM) to predict the co-variation of Pn, PAR, and the relative pollution index (I). We then evaluated the model with published data and our own experimental data. The results indicate that the Pn of plants decreased with increasing I in the environment and, as predicted, were all fitted well by the NIMM model. Therefore, our model provides a robust basis to evaluate and understand the influence of environmental pollution on plant photosynthesis.

  7. Quantification of hysteresis effects on a soil subjected to drying and wetting cycles

    NASA Astrophysics Data System (ADS)

    Rafraf, Samia; Guellouz, Lamia; Guiras, Houda; Bouhlila, Rachida

    2016-10-01

    A quantitative description of soil hysteretic response during drying-wetting cycles is required to improve prediction of the soil water retention model. The objective of the study is to quantify the degree of hysteresis, which is helpful to evaluate the precision of soil water flow calculation. A new procedure to quantify the degree of hysteresis is presented. The Arya-Paris model allows assessment of hysteresis effects from initial drying curves, dynamic contact angles, degree of hysteresis value, and maximum difference value between drying and subsequent wetting curves. The experimental results show that the degree of hysteresis varies with the particle size, bulk density, void ratio, initial water content, and contact angle of the soil. The new findings can be very useful in modelling soil water flows.

  8. Hysteresis and Fatigue

    NASA Astrophysics Data System (ADS)

    Erber, T.; Guralnick, S. A.; Michels, S. C.

    1993-06-01

    Fatigue in materials is the result of cumulative damage processes that are usually induced be repeated loading cycles. Since the energy dissipation associated with damage is irreversible, and the loading cycles are accompanied by the evolution of heat, the corresponding relation between stress and strain is not single-valued; but rather exhibits a memory dependence, or hysteresis. Conversely, sustained hysteresis is a necessary condition for fatigue and is related to the rate of damage accumulation. Engineering design and safety standards for estimating fatigue life are based in part on the Manson-Coffin relations between the width of stress-strain hysteresis loops and the number of loading cycles required to produce failure in test pieces. Experimental and theoretical results show that this relation can be extended into a simple phenomenological description of fatigue that directly links total hysteresis energy dissipation, the cumulation of material damage, and the average number of loading cycles leading to failure. Detailed features of the hysteresis can be understood with the help of analogies between the incremental collapse of structures and the inception and organization of damage in materials. In particular, scanning tunneling microscope measurements of the threshold of mechanical irreversibility and acoustic emission patterns may be used to check on the evolution of hysteresis at the microscopic level.

  9. A magnetic hysteresis model

    NASA Technical Reports Server (NTRS)

    Flatley, Thomas W.; Henretty, Debra A.

    1995-01-01

    The Passive Aerodynamically Stabilized Magnetically Damped Satellite (PAMS) will be deployed from the Space Shuttle and used as a target for a Shuttle-mounted laser. It will be a cylindrical satellite with several corner cube reflectors on the ends. The center of mass of the cylinder will be near one end, and aerodynamic torques will tend to align the axis of the cylinder with the spacecraft velocity vector. Magnetic hysteresis rods will be used to provide passive despin and oscillation-damping torques on the cylinder. The behavior of the hysteresis rods depends critically on the 'B/H' curves for the combination of materials and rod length-to-diameter ratio ('l-over-d'). These curves are qualitatively described in most Physics textbooks in terms of major and minor 'hysteresis loops'. Mathematical modeling of the functional relationship between B and H is very difficult. In this paper, the physics involved is not addressed, but an algorithm is developed which provides a close approximation to empirically determined data with a few simple equations suitable for use in computer simulations.

  10. Adsorption hysteresis in nanopores

    PubMed

    Neimark; Ravikovitch; Vishnyakov

    2000-08-01

    Capillary condensation hysteresis in nanopores is studied by Monte Carlo simulations and the nonlocal density functional theory. Comparing the theoretical results with the experimental data on low temperature sorption of nitrogen and argon in cylindrical channels of mesoporous siliceous molecular sieves of MCM-41 type, we have revealed four qualitatively different sorption regimes depending on the temperature and pore size. As the pore size increases at a given temperature, or as the temperature decreases at a given pore size, the following regimes are consequently observed: volume filling without phase separation, reversible stepwise capillary condensation, irreversible capillary condensation with developing hysteresis, and capillary condensation with developed hysteresis. We show that, in the regime of developed hysteresis (pores wider than 5 nm in the case of nitrogen sorption at 77 K), condensation occurs spontaneously at the vaporlike spinodal while desorption takes place at the equilibrium. A quantitative agreement is found between the modeling results and the experimental hysteresis loops formed by the adsorption-desorption isotherms. The results obtained provide a better understanding of the general behavior of confined fluids and the specifics of sorption and phase transitions in nanomaterials.

  11. Conditions necessary for capillary hysteresis in porous media: Tests of grain size and surface tension influences

    NASA Astrophysics Data System (ADS)

    Tokunaga, Tetsu K.; Olson, Keith R.; Wan, Jiamin

    2004-05-01

    Hysteresis in the relation between water saturation and matric potential is generally regarded as a basic aspect of unsaturated porous media. However, the nature of an upper length scale limit for saturation hysteresis has not been previously addressed. Since hysteresis depends on whether or not capillary rise occurs at the grain scale, this criterion was used to predict required combinations of grain size, surface tension, fluid-fluid density differences, and acceleration in monodisperse systems. The Haines number (Ha), composed of the aforementioned variables, is proposed as a dimensionless number useful for separating hysteretic (Ha < 15) versus nonhysteretic (Ha > 15) behavior. Vanishing of hysteresis was predicted to occur for grain sizes greater than 10.4 ± 0.5 mm, for water-air systems under the acceleration of ordinary gravity, based on Miller-Miller scaling and Haines' original model for hysteresis. Disappearance of hysteresis was tested through measurements of drainage and wetting curves of sands and gravels and occurs between grain sizes of 10 and 14 mm (standard conditions). The influence of surface tension was tested through measurements of moisture retention in 7 mm gravel, without and with a surfactant (sodium dodecylbenzenesulfonate (SDBS)). The ordinary water system (Ha = 7) exhibited hysteresis, while the SDBS system (Ha = 18) did not. The experiments completed in this study indicate that hysteresis in moisture retention relations has an upper limit at Ha = 16 ± 2 and show that hysteresis is not a fundamental feature of unsaturated porous media.

  12. Characterization of Corneal Indentation Hysteresis.

    PubMed

    Ko, Match W L; Dongming Wei; Leung, Christopher K S

    2015-01-01

    Corneal indentation is adapted for the design and development of a characterization method for corneal hysteresis behavior - Corneal Indentation Hysteresis (CIH). Fourteen porcine eyes were tested using the corneal indentation method. The CIH measured in enucleated porcine eyes showed indentation rate and intraocular pressure (IOP) dependences. The CIH increased with indentation rate at lower IOP (<; 25 mmHg) and decreased with indentation rate at higher IOP (> 25 mmHg). The CIH was linear proportional to the IOP within an individual eye. The CIH was positively correlated with the IOP, corneal in-plane tensile stress and corneal tangent modulus (E). A new method based on corneal indentation for the measurement of Corneal Indentation Hysteresis in vivo is developed. To our knowledge, this is the first study to introduce the corneal indentation hysteresis and correlate the corneal indentation hysteresis and corneal tangent modulus.

  13. [Mathematical models of hysteresis

    SciTech Connect

    Mayergoyz, I.D.

    1991-01-01

    The research described in this proposal is currently being supported by the US Department of Energy under the contract Mathematical Models of Hysteresis''. Thus, before discussing the proposed research in detail, it is worthwhile to describe and summarize the main results achieved in the course of our work under the above contract. Our ongoing research has largely been focused on the development of mathematical models of hysteretic nonlinearities with nonlocal memories''. The distinct feature of these nonlinearities is that their current states depend on past histories of input variations. It turns out that memories of hysteretic nonlinearities are quite selective. Indeed, experiments show that only some past input extrema leave their marks upon future states of hysteretic nonlinearities. Thus special mathematical tools are needed in order to describe nonlocal selective memories of hysteretic nonlinearities. Our research has been primarily concerned with Preisach-type models of hysteresis. All these models have a common generic feature; they are constructed as superpositions of simplest hysteretic nonlinearities-rectangular loops. Our study has by and large been centered around the following topics: various generalizations and extensions of the classical Preisach model, finding of necessary and sufficient conditions for the representation of actual hysteretic nonlinearities by various Preisach type models, solution of identification problems for these models, numerical implementation and experimental testing of Preisach type models. Although the study of Preisach type models has constituted the main direction of the research, some effort has also been made to establish some interesting connections between these models and such topics as: the critical state model for superconducting hysteresis, the classical Stoner-Wohlfarth model of vector magnetic hysteresis, thermal activation type models for viscosity, magnetostrictive hysteresis and neural networks.

  14. Hysteresis in the Sky

    NASA Astrophysics Data System (ADS)

    Choudhury, Sayantan; Banerjee, Shreya

    2016-07-01

    Hysteresis is a phenomenon occurring naturally in several magnetic and electric materials in condensed matter physics. When applied to cosmology, aka cosmological hysteresis, has interesting and vivid implications in the scenario of a cyclic bouncy universe. Most importantly, this physical prescription can be treated as an alternative proposal to inflationary paradigm. Cosmological hysteresis is caused by the asymmetry in the equation of state parameter during expansion and contraction phase of the universe, due to the presence of a single scalar field. This process is purely thermodynamical in nature, results in a non-vanishing hysteresis loop integral (∮pdV) in cosmology. When applied to variants of modified gravity models 1) Dvali-Gabadadze-Porrati (DGP) brane world gravity, 2) Cosmological constant dominated Einstein gravity, 3) Loop Quantum Gravity (LQG), 4) Einstein-Gauss-Bonnet brane world gravity and 5) Randall Sundrum single brane world gravity (RSII), under certain circumstances, this phenomenon leads to the increase in amplitude of the consecutive cycles and to a universe with older and larger successive cycles, provided we have physical mechanisms to make the universe bounce and turnaround. This inculcates an arrow of time in a dissipationless cosmology. Remarkably, this phenomenon appears to be widespread in several cosmological potentials in variants of modified gravity background, which we explicitly study for i) Hilltop, ii) Natural and iii) Coleman-Weinberg potentials, in this paper. Semi-analytical analysis of these models, for different potentials with minimum/minima, show that the conditions which creates a universe with an ever increasing expansion, depend on the signature of the hysteresis loop integral (∮pdV) as well as on the variants of model parameters.

  15. The magnetization process: Hysteresis

    NASA Technical Reports Server (NTRS)

    Balsamel, Richard

    1990-01-01

    The magnetization process, hysteresis (the difference in the path of magnetization for an increasing and decreasing magnetic field), hysteresis loops, and hard magnetic materials are discussed. The fabrication of classroom projects for demonstrating hysteresis and the hysteresis of common magnetic materials is described in detail.

  16. Conditions necessary for capillary hysteresis in porous media: Tests of grain-size and surface tension influences

    SciTech Connect

    Tokunaga, Tetsu K.; Olson, Keith R.; Wan, Jiamin

    2004-03-12

    Hysteresis in the relation between water saturation and matric potential is generally regarded as a basic aspect of unsaturated porous media. However, the nature of an upper length scale limit for saturation hysteresis has not been previously addressed. Since hysteresis depends on whether or not capillary rise occurs at the grain scale, this criterion was used to predict required combinations of grain size, surface tension, fluid-fluid density differences, and acceleration in monodisperse systems. The Haines number (Ha), composed of the aforementioned variables, is proposed as a dimensionless number useful for separating hysteretic (Ha < 15) versus nonhysteretic (Ha > 15) behavior. Vanishing of hysteresis was predicted to occur for grain sizes greater than 10.4 +- 0.5 mm, for water-air systems under the acceleration of ordinary gravity, based on Miller-Miller scaling and Haines' original model for hysteresis. Disappearance of hysteresis was tested through measurements of drainage and wetting curves of sands and gravels and occurs between grain sizes of 10 and 14 mm (standard conditions). The influence of surface tension was tested through measurements of moisture retention in 7 mm gravel, without and with a surfactant (sodium dodecylbenzenesulfonate (SDBS)). The ordinary water system (Ha = 7) exhibited hysteresis, while the SDBS system (Ha = 18) did not. The experiments completed in this study indicate that hysteresis in moisture retention relations has an upper limit at Ha = 16 +- 2 and show that hysteresis is not a fundamental feature of unsaturated porous media.

  17. New approach to the calculation of pistachio powder hysteresis

    NASA Astrophysics Data System (ADS)

    Tavakolipour, Hamid; Mokhtarian, Mohsen

    2016-04-01

    Moisture sorption isotherms for pistachio powder were determined by gravimetric method at temperatures of 15, 25, 35 and 40°C. A selected mathematical models were tested to determine the best suitable model to predict isotherm curve. The results show that Caurie model had the most satisfactory goodness of fit. Also, another purpose of this research was to introduce a new methodology to determine the amount of hysteresis at different temperatures by using best predictive model of isotherm curve based on definite integration method. The results demonstrated that maximum hysteresis is related to the multi-layer water (in the range of water activity 0.2-0.6) which corresponds to the capillary condensation region and this phenomenon decreases with increasing temperature.

  18. Modeling of hysteresis in gene regulatory networks.

    PubMed

    Hu, J; Qin, K R; Xiang, C; Lee, T H

    2012-08-01

    Hysteresis, observed in many gene regulatory networks, has a pivotal impact on biological systems, which enhances the robustness of cell functions. In this paper, a general model is proposed to describe the hysteretic gene regulatory network by combining the hysteresis component and the transient dynamics. The Bouc-Wen hysteresis model is modified to describe the hysteresis component in the mammalian gene regulatory networks. Rigorous mathematical analysis on the dynamical properties of the model is presented to ensure the bounded-input-bounded-output (BIBO) stability and demonstrates that the original Bouc-Wen model can only generate a clockwise hysteresis loop while the modified model can describe both clockwise and counter clockwise hysteresis loops. Simulation studies have shown that the hysteresis loops from our model are consistent with the experimental observations in three mammalian gene regulatory networks and two E.coli gene regulatory networks, which demonstrate the ability and accuracy of the mathematical model to emulate natural gene expression behavior with hysteresis. A comparison study has also been conducted to show that this model fits the experiment data significantly better than previous ones in the literature. The successful modeling of the hysteresis in all the five hysteretic gene regulatory networks suggests that the new model has the potential to be a unified framework for modeling hysteresis in gene regulatory networks and provide better understanding of the general mechanism that drives the hysteretic function.

  19. Hysteresis responses of evapotranspiration to meteorological factors at a diel timescale: patterns and causes.

    PubMed

    Zheng, Han; Wang, Qiufeng; Zhu, Xianjin; Li, Yingnian; Yu, Guirui

    2014-01-01

    Evapotranspiration (ET) is an important component of the water cycle in terrestrial ecosystems. Understanding the ways in which ET changes with meteorological factors is central to a better understanding of ecological and hydrological processes. In this study, we used eddy covariance measurements of ET from a typical alpine shrubland meadow ecosystem in China to investigate the hysteresis response of ET to environmental variables including air temperature (Ta), vapor pressure deficit (VPD) and net radiation (Rn) at a diel timescale. Meanwhile, the simulated ET by Priestly-Taylor equation was used to interpret the measured ET under well-watered conditions. Pronounced hysteresis was observed in both Ta and VPD response curves of ET. At a similar Ta and VPD, ET was always significantly depressed in the afternoon compared with the morning. But the hysteresis response of ET to Rn was not evident. Similar hysteresis patterns were also observed in the Ta/VPD response curves of simulated ET. The magnitudes of the measured and simulated hysteresis loops showed similar seasonal variation, with relatively smaller values occurring from May to September, which agreed well with the lifetime of plants and the period of rainy season at this site. About 62% and 23% of changes in the strength of measured ET-Ta and ET-VPD loops could be explained by the changes in the strength of simulated loops, respectively. Thus, the time lag between Rn and Ta/VPD is the most important factor generating and modulating the ET-Ta/VPD hysteresis, but plants and water status also contribute to the hysteresis response of ET. Our research confirmed the different hysteresis in the responses of ET to meteorological factors and proved the vital role of Rn in driving the diel course of ET.

  20. Steady state performance, photo-induced performance degradation and their relation to transient hysteresis in perovskite solar cells

    NASA Astrophysics Data System (ADS)

    Jena, Ajay Kumar; Kulkarni, Ashish; Ikegami, Masashi; Miyasaka, Tsutomu

    2016-03-01

    Hysteresis in current-voltage curves of perovskite solar cells is a serious concern as it creates confusions about actual cell performance and raises questions on its reliability. Although a lot of effort has been made to understand the origin of hysteresis, knowing whether hysteresis affects the cell performance while they are in practical use (operated constantly at maximum power point) is not yet examined. In the present study, we investigate steady state performance and performance stability of perovskite solar cells (planar architecture with varying perovskite film thickness and TiO2 mesoscopic structure with different TiO2 compact layer thickness exhibiting hysteresis of different magnitudes) operating across an external load in relation to hysteresis. The planar cells with larger hysteresis exhibit a steady state current that closely matches the value determined on forward voltage scan. Cyclic photocurrent-dark current measurements on cells with hysteresis of different magnitudes reveal that photo-induced electrical instability (not material degradation), which might be originated from ion migration or photo-induced traps formation, is not related to hysteresis. Performance of the cells is recovered partially or fully, depending on the device structure, on storage in dark. TiO2 meso-structure cells tend to show complete recovery while the planar cells recover partially.

  1. Application of geometry based hysteresis modelling in compensation of hysteresis of piezo bender actuator

    NASA Astrophysics Data System (ADS)

    Milecki, Andrzej; Pelic, Marcin

    2016-10-01

    This paper presents results of studies of an application of a new method of piezo bender actuators modelling. A special hysteresis simulation model was developed and is presented. The model is based on a geometrical deformation of main hysteresis loop. The piezoelectric effect is described and the history of the hysteresis modelling is briefly reviewed. Firstly, a simple model for main loop modelling is proposed. Then, a geometrical description of the non-saturated hysteresis is presented and its modelling method is introduced. The modelling makes use of the function describing the geometrical shape of the two hysteresis main curves, which can be defined theoretically or obtained by measurement. These main curves are stored in the memory and transformed geometrically in order to obtain the minor curves. Such model was prepared in the Matlab-Simulink software, but can be easily implemented using any programming language and applied in an on-line controller. In comparison to the other known simulation methods, the one presented in the paper is easy to understand, and uses simple arithmetical equations, allowing to quickly obtain the inversed model of hysteresis. The inversed model was further used for compensation of a non-saturated hysteresis of the piezo bender actuator and results have also been presented in the paper.

  2. HD 240121 - An ACV variable showing anti-phase variations of the B and V light curves

    NASA Astrophysics Data System (ADS)

    Gröbel, Rainer; Hümmerich, Stefan; Paunzen, Ernst; Bernhard, Klaus

    2017-01-01

    The variability of HD 240121 = BD+59 2602 was first suspected by Särg and Wramdemark (1970) and later confirmed by Gröbel R. (1992a,b). Because of the observed anti-phase variations of the B and V light curves, the latter author tentatively suggested an ACV type. Apart from its inclusion in the catalog of New Suspected Variables (NSV 25977), no further investigations of the star have been published. HD 240121 was included into our target list of ACV candidates and investigated in order to determine the reason for the observed brightness variations. All available information on HD 240121 were collected via an exhaustive data mining procedure. Data from Gröbel (1992a,b) were re-analysed and photometric observations from the NSVS and Hipparcos archives were procured and investigated. Line-of-sight reddening and stellar parameters were calculated from archival photometric data. HD 240121 is a young, late B-type CP2 star of the silicon subgroup. The observed period, amplitude of light variations and variability pattern (anti-phase variations) are typical of ACV variables. The occurrence of anti-phase variations of the B and V light curves is rarely observed and points to the existence of a null wavelength in the visual spectrum. We therefore strongly encourage further multi-colour photometric observations of this star.

  3. Contact angle hysteresis on fluoropolymer surfaces.

    PubMed

    Tavana, H; Jehnichen, D; Grundke, K; Hair, M L; Neumann, A W

    2007-10-31

    Contact angle hysteresis of liquids with different molecular and geometrical properties on high quality films of four fluoropolymers was studied. A number of different causes are identified for hysteresis. With n-alkanes as probe liquids, contact angle hysteresis is found to be strongly related to the configuration of polymer chains. The largest hysteresis is obtained with amorphous polymers whereas the smallest hysteresis occurs for polymers with ordered molecular chains. This is explained in terms of sorption of liquid by the solid and penetration of liquid into the polymer film. Correlation of contact angle hysteresis with the size of n-alkane molecules supports this conclusion. On the films of two amorphous fluoropolymers with different molecular configurations, contact angle hysteresis of one and the same liquid with "bulky" molecules is shown to be quite different. On the surfaces of Teflon AF 1600, with stiff molecular chains, the receding angles of the probe liquids are independent of contact time between solid and liquid and similar hysteresis is obtained for all the liquids. Retention of liquid molecules on the solid surface is proposed as the most likely cause of hysteresis in these systems. On the other hand, with EGC-1700 films that consist of flexible chains, the receding angles are strongly time-dependent and the hysteresis is large. Contact angle hysteresis increases even further when liquids with strong dipolar intermolecular forces are used. In this case, major reorganization of EGC-1700 chains due to contact with the test liquids is suggested as the cause. The effect of rate of motion of the three-phase line on the advancing and receding contact angles, and therefore contact angle hysteresis, is investigated. For low viscous liquids, contact angles are independent of the drop front velocity up to approximately 10 mm/min. This agrees with the results of an earlier study that showed that the rate-dependence of the contact angles is an issue only

  4. A simple model of hysteresis behavior using spreadsheet analysis

    NASA Astrophysics Data System (ADS)

    Ehrmann, A.; Blachowicz, T.

    2015-01-01

    Hysteresis loops occur in many scientific and technical problems, especially as field dependent magnetization of ferromagnetic materials, but also as stress-strain-curves of materials measured by tensile tests including thermal effects, liquid-solid phase transitions, in cell biology or economics. While several mathematical models exist which aim to calculate hysteresis energies and other parameters, here we offer a simple model for a general hysteretic system, showing different hysteresis loops depending on the defined parameters. The calculation which is based on basic spreadsheet analysis plus an easy macro code can be used by students to understand how these systems work and how the parameters influence the reactions of the system on an external field. Importantly, in the step-by-step mode, each change of the system state, compared to the last step, becomes visible. The simple program can be developed further by several changes and additions, enabling the building of a tool which is capable of answering real physical questions in the broad field of magnetism as well as in other scientific areas, in which similar hysteresis loops occur.

  5. Contact angle hysteresis explained.

    PubMed

    Gao, Lichao; McCarthy, Thomas J

    2006-07-04

    A view of contact angle hysteresis from the perspectives of the three-phase contact line and of the kinetics of contact line motion is given. Arguments are made that advancing and receding are discrete events that have different activation energies. That hysteresis can be quantified as an activation energy by the changes in interfacial area is argued. That this is an appropriate way of viewing hysteresis is demonstrated with examples.

  6. Dynamic hysteresis modelling of entangled cross-linked fibres in shear

    NASA Astrophysics Data System (ADS)

    Piollet, Elsa; Poquillon, Dominique; Michon, Guilhem

    2016-11-01

    The objective of this paper is to characterize and model the vibration behaviour of entangled carbon fibres cross-linked with epoxy resin. The material is tested in shear, in a double lap configuration. Experimental testing is carried out for frequencies varying from 1 Hz to 80 Hz and for shear strain amplitudes ranging from 5 ·10-4 to 1 ·10-2. Measured shear stress-strain hysteresis loops show a nonlinear behaviour with a low frequency dependency. The hysteresis loops are decomposed in a linear part and three nonlinear parts: a dry friction hysteresis, a stiffening term and a stiction-like overshoot term. The Generalized Dahl Model is used in conjunction with other hysteresis models to develop an appropriate description of the measured hysteresis loops, based on the three nonlinear parts. In particular, a new one-state formulation of the Bliman-Sorine model is developed. A new identification procedure is also introduced for the Dahl model, based on the so-called backbone curve. The model is shown to capture well the complex shapes of the measured hysteresis loops at all amplitudes.

  7. Hysteresis and feedback of ice sheet response

    NASA Astrophysics Data System (ADS)

    Abe-Ouchi, A.; Saito, F.; Takahashi, K.

    2014-12-01

    Investigating the response of ice sheets to climatic forcings in the past by climate-ice sheet modelling is important for understanding the ice sheets' change. The 100-kyr cycle of the large Northern Hemisphere ice sheets and fast termination of the glacial cycle are the prominent pattern known from paleoclimate records. We simulate the past glacial cycles with an ice sheet model, IcIES in combination with a general circulation model, MIROC, using the time series of insolation and atmospheric CO2. Feedback processes between ice sheet and atmosphere such as the ice albedo feedback, the elevation-mass balance feedback, desertification effect and stationary wave feedback are analyzed. We show that the threshold of termination of the glacial cycles can be explained by the pattern of the hysteresis of ice sheet change, i.e. multiple steady states of the ice sheets under climatic forcings. We find that slope of the upper branch of the multiple equilibria curve for Laurentide ice volumes is fundamental for the observed glacial patterns. Finally, we discuss the similarity and difference between the hysteresis structure of ice sheets variation for Northern Hemisphere ice sheets, Antarctica and Greenland.

  8. Efficient Computational Model of Hysteresis

    NASA Technical Reports Server (NTRS)

    Shields, Joel

    2005-01-01

    A recently developed mathematical model of the output (displacement) versus the input (applied voltage) of a piezoelectric transducer accounts for hysteresis. For the sake of computational speed, the model is kept simple by neglecting the dynamic behavior of the transducer. Hence, the model applies to static and quasistatic displacements only. A piezoelectric transducer of the type to which the model applies is used as an actuator in a computer-based control system to effect fine position adjustments. Because the response time of the rest of such a system is usually much greater than that of a piezoelectric transducer, the model remains an acceptably close approximation for the purpose of control computations, even though the dynamics are neglected. The model (see Figure 1) represents an electrically parallel, mechanically series combination of backlash elements, each having a unique deadband width and output gain. The zeroth element in the parallel combination has zero deadband width and, hence, represents a linear component of the input/output relationship. The other elements, which have nonzero deadband widths, are used to model the nonlinear components of the hysteresis loop. The deadband widths and output gains of the elements are computed from experimental displacement-versus-voltage data. The hysteresis curve calculated by use of this model is piecewise linear beyond deadband limits.

  9. Hysteresis in Metal Hydrides.

    ERIC Educational Resources Information Center

    Flanagan, Ted B., And Others

    1987-01-01

    This paper describes a reproducible process where the irreversibility can be readily evaluated and provides a thermodynamic description of the important phenomenon of hysteresis. A metal hydride is used because hysteresis is observed during the formation and decomposition of the hydride phase. (RH)

  10. Hysteresis in a quantized superfluid 'atomtronic' circuit.

    PubMed

    Eckel, Stephen; Lee, Jeffrey G; Jendrzejewski, Fred; Murray, Noel; Clark, Charles W; Lobb, Christopher J; Phillips, William D; Edwards, Mark; Campbell, Gretchen K

    2014-02-13

    Atomtronics is an emerging interdisciplinary field that seeks to develop new functional methods by creating devices and circuits where ultracold atoms, often superfluids, have a role analogous to that of electrons in electronics. Hysteresis is widely used in electronic circuits-it is routinely observed in superconducting circuits and is essential in radio-frequency superconducting quantum interference devices. Furthermore, it is as fundamental to superfluidity (and superconductivity) as quantized persistent currents, critical velocity and Josephson effects. Nevertheless, despite multiple theoretical predictions, hysteresis has not been previously observed in any superfluid, atomic-gas Bose-Einstein condensate. Here we directly detect hysteresis between quantized circulation states in an atomtronic circuit formed from a ring of superfluid Bose-Einstein condensate obstructed by a rotating weak link (a region of low atomic density). This contrasts with previous experiments on superfluid liquid helium where hysteresis was observed directly in systems in which the quantization of flow could not be observed, and indirectly in systems that showed quantized flow. Our techniques allow us to tune the size of the hysteresis loop and to consider the fundamental excitations that accompany hysteresis. The results suggest that the relevant excitations involved in hysteresis are vortices, and indicate that dissipation has an important role in the dynamics. Controlled hysteresis in atomtronic circuits may prove to be a crucial feature for the development of practical devices, just as it has in electronic circuits such as memories, digital noise filters (for example Schmitt triggers) and magnetometers (for example superconducting quantum interference devices).

  11. Hysteresis in a quantized superfluid `atomtronic' circuit

    NASA Astrophysics Data System (ADS)

    Eckel, Stephen; Lee, Jeffrey G.; Jendrzejewski, Fred; Murray, Noel; Clark, Charles W.; Lobb, Christopher J.; Phillips, William D.; Edwards, Mark; Campbell, Gretchen K.

    2014-02-01

    Atomtronics is an emerging interdisciplinary field that seeks to develop new functional methods by creating devices and circuits where ultracold atoms, often superfluids, have a role analogous to that of electrons in electronics. Hysteresis is widely used in electronic circuits--it is routinely observed in superconducting circuits and is essential in radio-frequency superconducting quantum interference devices. Furthermore, it is as fundamental to superfluidity (and superconductivity) as quantized persistent currents, critical velocity and Josephson effects. Nevertheless, despite multiple theoretical predictions, hysteresis has not been previously observed in any superfluid, atomic-gas Bose-Einstein condensate. Here we directly detect hysteresis between quantized circulation states in an atomtronic circuit formed from a ring of superfluid Bose-Einstein condensate obstructed by a rotating weak link (a region of low atomic density). This contrasts with previous experiments on superfluid liquid helium where hysteresis was observed directly in systems in which the quantization of flow could not be observed, and indirectly in systems that showed quantized flow. Our techniques allow us to tune the size of the hysteresis loop and to consider the fundamental excitations that accompany hysteresis. The results suggest that the relevant excitations involved in hysteresis are vortices, and indicate that dissipation has an important role in the dynamics. Controlled hysteresis in atomtronic circuits may prove to be a crucial feature for the development of practical devices, just as it has in electronic circuits such as memories, digital noise filters (for example Schmitt triggers) and magnetometers (for example superconducting quantum interference devices).

  12. Surface Polarization Model for the Dynamic Hysteresis of Perovskite Solar Cells.

    PubMed

    Ravishankar, Sandheep; Almora, Osbel; Echeverría-Arrondo, Carlos; Ghahremanirad, Elnaz; Aranda, Clara; Guerrero, Antonio; Fabregat-Santiago, Francisco; Zaban, Arie; Garcia-Belmonte, Germà; Bisquert, Juan

    2017-02-10

    The dynamic hysteresis of perovskite solar cells consists of the occurrence of significant deviations of the current density-voltage curve shapes depending on the specific conditions of measurement such as starting voltage, waiting time, scan rate, and other factors. Dynamic hysteresis is a serious impediment to stabilized and reliable measurement and operation of the perovskite solar cells. In this Letter, we formulate a model for the dynamic hysteresis based on the idea that the cell accumulates a huge quantity of surface electronic charge at forward bias that is released on voltage sweeping, causing extra current over the normal response. The charge shows a retarded dynamics due to the slow relaxation of the accompanying ionic charge, that produces variable shapes depending on scan rate or poling value and time. We show that the quantitative model provides a consistent description of experimental results and allows us to determine significant parameters of the perovskite solar cell for both the transient and steady-state performance.

  13. Hysteresis effects in suspended sediment concentration of an allogenic river channel in a very arid environment

    NASA Astrophysics Data System (ADS)

    Yu, Guo-An; Disse, Markus; Yu, Yang

    2016-04-01

    Suspended sediment dynamics of the Tarim River, an allogenic and perennial river flowing in a very arid environment in China, are analyzed to examine the hysteresis effects based on data of flow discharge (Q) and suspended sediment concentration (SSC) from two hydrologic gauging stations in the river in the last five decades (1960-2011). Strong hysteresis effects existed in the sediment rating curves of the Tarim River. Under similar flow conditions, the first flood event in a year quite often causes higher suspended sediment concentration (SSC value), and form a rating curve visibly different from later flood processes. The successive flood events often form rating curves gradually from left to right progressively with time on the SSC-Q plot, indicating that higher flow intensity is needed for later flood events to reach the same SSC value of the earlier flood events. Three hysteresis loop forms, i.e., clockwise, anti-clockwise and Figure-eight existed with occurrence frequency of 57%, 27.3% and 15.6% respectively, showing that clockwise loop is the major hysteresis form and sediment load is generally derived from the channel bed. The very weak banks due to composition of quite homogeneous noncohesive particles (fine sand, silt and almost no clay content) often induce bank failure, which complicates suspended sediment dynamics and causes to shape different hysteresis loops. Somehow random but occurrence of bank collapse with higher possibility near the peak and at the falling limb of a flood hydrograph is probably the major reason causing anti-clockwise and figure-eight hysteresis loops.

  14. Decreased Photosystem II Core Phosphorylation in a Yellow-Green Mutant of Wheat Showing Monophasic Fluorescence Induction Curve.

    PubMed Central

    Giardi, M. T.; Kucera, T.; Briantais, J. M.; Hodges, M.

    1995-01-01

    In the present work we study the regulation of the distribution of the phosphorylated photosystem II (PSII) core populations present in grana regions of the thylakoids from several plant species. The heterogeneous nature of PSII core phosphorylation has previously been reported (M.T. Giardi, F. Rigoni, R. Barbato [1992] Plant Physiol 100: 1948-1954; M.T. Giardi [1993] Planta 190: 107-113). The pattern of four phosphorylated PSII core populations in the grana regions appears to be ubiquitous in higher plants. In the dark, at least two phosphorylated PSII core populations are always detected. A mutant of wheat (Triticum durum) that shows monophasic room-temperature photoreduction of the primary quinone electron acceptor of PSII as measured by chlorophyll fluorescence increase in the presence and absence of 3-(3,4-dichlorophenyl)-1,1-dimethylurea and by fluorescence upon flash illumination in intact leaves also lacks the usual distribution of phosphorylated PSII core populations. In this mutant, the whole PSII core population pattern is changed, probably due to altered threonine kinase activity, which leads to the absence of light-induced phosphorylation of CP43 and D2 proteins. The results, correlated to previous experiments in vivo, support the idea that the functional heterogeneity observed by fluorescence is correlated in part to the PSII protein phosphorylation in the grana. PMID:12228652

  15. Hysteresis of magnetostructural transitions: Repeatable and non-repeatable processes

    NASA Astrophysics Data System (ADS)

    Provenzano, Virgil; Della Torre, Edward; Bennett, Lawrence H.; ElBidweihy, Hatem

    2014-02-01

    The Gd5Ge2Si2 alloy and the off-stoichiometric Ni50Mn35In15 Heusler alloy belong to a special class of metallic materials that exhibit first-order magnetostructural transitions near room temperature. The magnetic properties of this class of materials have been extensively studied due to their interesting magnetic behavior and their potential for a number of technological applications such as refrigerants for near-room-temperature magnetic refrigeration. The thermally driven first-order transitions in these materials can be field-induced in the reverse order by applying a strong enough field. The field-induced transitions are typically accompanied by the presence of large magnetic hysteresis, the characteristics of which are a complicated function of temperature, field, and magneto-thermal history. In this study we show that the virgin curve, the major loop, and sequentially measured MH loops are the results of both repeatable and non-repeatable processes, in which the starting magnetostructural state, prior to the cycling of field, plays a major role. Using the Gd5Ge2Si2 and Ni50Mn35In15 alloys, as model materials, we show that a starting single phase state results in fully repeatable processes and large magnetic hysteresis, whereas a mixed phase starting state results in non-repeatable processes and smaller hysteresis.

  16. Corneal hysteresis and its relevance to glaucoma

    PubMed Central

    Deol, Madhvi; Taylor, David A.; Radcliffe, Nathan M.

    2015-01-01

    Purpose of review Glaucoma is a leading cause of irreversible blindness worldwide. It is estimated that roughly 60.5 million people had glaucoma in 2010 and that this number is increasing. Many patients continue to lose vision despite apparent disease control according to traditional risk factors. The purpose of this review is to discuss the recent findings with regard to corneal hysteresis, a variable that is thought to be associated with the risk and progression of glaucoma. Recent findings Low corneal hysteresis is associated with optic nerve and visual field damage in glaucoma and the risk of structural and functional glaucoma progression. In addition, hysteresis may enhance intraocular pressure (IOP) interpretation: low corneal hysteresis is associated with a larger magnitude of IOP reduction following various glaucoma therapies. Corneal hysteresis is dynamic and may increase in eyes after IOP-lowering interventions are implemented. Summary It is widely accepted that central corneal thickness is a predictive factor for the risk of glaucoma progression. Recent evidence shows that corneal hysteresis also provides valuable information for several aspects of glaucoma management. In fact, corneal hysteresis may be more strongly associated with glaucoma presence, risk of progression, and effectiveness of glaucoma treatments than central corneal thickness. PMID:25611166

  17. Hysteresis and fatigue

    SciTech Connect

    Erber, T. ); Guralnick, S.A.; Michels, S.C. )

    1993-06-01

    Energy dissipation associated with damage of materials is irreversible and loading cycles are accompanied by the evolution of heat. The relation between energy dissipation and loading therefore exhibits a memory dependence or hysteresis. Conversely, sustained hysteresis is a necessary condition for fatigue and is related to the rate of damage accumulation. Standards for estimating fatigue life are partially based on the Manson-Coffin relations between the width of stress strain hysteresis loops and the number of loading cycles required to produce failure in test pieces. In the present study, experimental and theoretical results demonstrate that this relation can be extended into a simple phenomenological description of fatigue that directly links total hysteresis energy dissipation, the cumulation of material damage, and the average number of loading cycles leading to failure. Analogies between the incremental collapse of structures and the inception and organization of damage in materials are used to aid understanding of the detailed features of hysteresis. Scanning tunneling microscope measurements of the threshold of mechanical irreversibility and acoustic emission patterns are used to detect the evolution of hysteresis at the microscopic level. 61 refs., 14 figs., 1 tab.

  18. Hysteresis heating based induction bonding of composite materials

    NASA Astrophysics Data System (ADS)

    Suwanwatana, Witchuda

    The viability of using magnetic particulate susceptor materials for induction heating during bonding of polymer matrix composites is well established in this work. The unique ability to offer localized heating, geometric flexibility, and self-controlled temperature is the major advantage of this technique. Hysteresis heating is tailored through careful design of the microstructure of nickel particulate polymer films (Ni/PSU). An excellent heating rate can be attained in the frequency range of 1 to 10 MHz for particle volume fraction below percolation of 0.26. The diameter of nickel particle should be kept between 65 nm to 10 mum to ensure multi-domain heating, Curie temperature control, negligible shielding effect, minimum eddy current, and slight particle oxidation. The hysteresis heating behavior of the Ni/PSU films is found to be volumetric in nature and proportional to the cube of applied magnetic field. On the other hand, heat generation is inversely proportional to the size of the multi-domain particles. The frequency effect; however, provide maximum heat generation at the domain wall resonance frequency. Curie temperature control is observed when sufficiently high magnetic fields (˜138 Oe) are applied. The master curves of AC heat generation in Ni/PSU films are established and show a strong particle size effect. Hysteresis fusion bonding of glass/polyphenylene sulfide thermoplastic composites using a magnetic film as the thermoplastic adhesive shows that the bond strength of hysteresis-welded materials is comparable to that of autoclave-welded materials while offering an order of magnitude reduction in cycle time. The relative contribution of the intimate contact and healing mechanisms to the fusion bonding process indicates that hysteresis bonding is controlled by intimate contact. The macroscopic failure modes vary from mostly adhesive composite/film (low bond strength) to a combination of adhesive composite/film, cohesive film, cohesive composite and

  19. Structural hysteresis model of transmitting mechanical systems

    NASA Astrophysics Data System (ADS)

    Ruderman, M.; Bertram, T.

    2015-02-01

    We present a structural hysteresis model which describes the dynamic behavior of transmitting mechanical systems with a hysteretic spring and damped bedstop element, both connected in series. From the application point view this approach can be used for predicting the transmitted mechanical force based only on the known kinematic excitation. Using the case study of an elastic gear transmission we show and identify a hysteresis response which multivariate behavior depends on an internal state of the bedstop motion.

  20. Understanding rheological hysteresis in soft glassy materials.

    PubMed

    Radhakrishnan, Rangarajan; Divoux, Thibaut; Manneville, Sébastien; Fielding, Suzanne M

    2017-03-01

    Motivated by recent experimental studies of rheological hysteresis in soft glassy materials, we study numerically strain rate sweeps in simple yield stress fluids and viscosity bifurcating yield stress fluids. Our simulations of downward followed by upward strain rate sweeps, performed within fluidity models and the soft glassy rheology model, successfully capture the experimentally observed monotonic decrease of the area of the rheological hysteresis loop with sweep time in simple yield stress fluids, and the bell shaped dependence of hysteresis loop area on sweep time in viscosity bifurcating fluids. We provide arguments explaining these two different functional forms in terms of differing tendencies of simple and viscosity bifurcating fluids to form shear bands during the sweeps, and show that the banding behaviour captured by our simulations indeed agrees with that reported experimentally. We also discuss the difference in hysteresis behaviour between inelastic and viscoelastic fluids. Our simulations qualitatively agree with the experimental data discussed here for four different soft glassy materials.

  1. Resistive hysteresis and nonlinear I-V characteristics at the first-order melting of the Abrikosov vortex lattice

    NASA Astrophysics Data System (ADS)

    Domínguez, Daniel; Grønbech-Jensen, Niels; Bishop, A. R.

    1995-12-01

    We study a three-dimensional network of Josephson junctions in a magnetic field, which undergoes a first-order melting transition of the triangular vortex lattice. We perform a Langevin dynamics calculation of the resistance and current-voltage (I-V) characteristics. We find hysteresis in the resistance as a function of temperature as measured in untwinned YBa2Cu3O7. Close to the melting temperature the I-V curves are S shaped with hysteresis and show a melting transition when increasing the current, driven by the blowing out of current nucleated vortex loops.

  2. Role of reversible susceptibility in ferromagnetic hysteresis

    NASA Astrophysics Data System (ADS)

    Schneider, Carl S.

    2002-05-01

    An equation of state based upon saturation magnetization, Ms, coercive field, Hc, and the reversible susceptibility function of magnetization is proposed for ferromagnetic hysteresis. Reversible susceptibility divided by the initial susceptibility is the anisotropy function of magnetization, χr, ranging from one in the demagnetized state to zero at saturation, and varying with magnetic history. Its dependence on scaled magnetization, m=M/Ms on the interval (-1,1) varies with material, allowing characterization of anisotropy classes. Precise measurements have been made of reversible susceptibility, initial and saturate magnetization curves, and loops for Orthonol™, annealed 3% nickel steel and as-received 1018 steel, representing crystals, isotropic polycrystals and composite ferromagnets, respectively. Magnetization change is the product of the reversible susceptibility, change in the applied field and the cooperative function due to domain interactions. This function is 1+βm for the virgin curve with half this slope from any reversal, where β=Ms/XiHc is the hysteresis coefficient. Variation of β for 1018 steel is due to distributed coercivities, and causes sigmoid B(H) curves. In the scaled field representation, where h=H/Hc, the cooperative function is 1/(1-hχr), a hyperbolic field dependence smeared by the anisotropy function. Constant anisotropy causes closed hysteresis loops, while variable anisotropy causes creeping of cycled asymmetric loops. In ferromagnetism, 1/χ=1/χr-h, normal scaled reluctivity is reduced from its reversible value by the scaled field.

  3. Magnetic hysteresis measurements of thin films under isotropic stress.

    NASA Astrophysics Data System (ADS)

    Holland, Patrick; Dubey, Archana; Geerts, Wilhelmus

    2000-10-01

    Nowadays, ferromagnetic thin films are widely applied in devices for information technology (credit cards, video recorder tapes, floppies, hard disks) and sensors (air bags, anti-breaking systems, navigation systems). Thus, with the increase in the use of magnetic media continued investigation of magnetic properties of materials is necessary to help in determining the useful properties of materials for new or improved applications. We are currently interested in studying the effect of applied external stress on Kerr hysteresis curves of thin magnetic films. The Ni and NiFe films were grown using DC magnetron sputtering with Ar as the sputter gas (pAr=4 mTorr; Tsub=55-190 C). Seed and cap layers of Ti were used on all films for adhesion and oxidation protection, respectively. A brass membrane pressure cell was designed to apply in-plane isotropic stress to thin films. In this pressure cell, gas pressure is used to deform a flexible substrate onto which a thin magnetic film has been sputtered. The curvature of the samples could be controlled by changing the gas pressure to the cell. Magneto-Optical in-plane hysteresis curves at different values of strain were measured. The results obtained show that the stress sensitivity is dependent on the film thickness. For the 500nm NiFe films, the coercivity strongly decreased as a function of the applied stress.

  4. Transport, hysteresis and avalanches in artificial spin ice systems

    SciTech Connect

    Reichhardt, Charles; Reichhardt, Cynthia J; Libal, A

    2010-01-01

    We examine the hopping dynamics of an artificial spin ice system constructed from colloids on a kagome optical trap array where each trap has two possible states. By applying an external drive from an electric field which is analogous to a biasing applied magnetic field for real spin systems, we can create polarized states that obey the spin-ice rules of two spins in and one spin out at each vertex. We demonstrate that when we sweep the external drive and measure the fraction of the system that has been polarized, we can generate a hysteresis loop analogous to the hysteretic magnetization versus external magnetic field curves for real spin systems. The disorder in our system can be readily controlled by changing the barrier that must be overcome before a colloid can hop from one side of a trap to the other. For systems with no disorder, the effective spins all flip simultaneously as the biasing field is changed, while for strong disorder the hysteresis curves show a series of discontinuous jumps or avalanches similar to Barkhausen noise.

  5. Hysteresis phenomena of the intelligent driver model for traffic flow.

    PubMed

    Dahui, Wang; Ziqiang, Wei; Ying, Fan

    2007-07-01

    We present hysteresis phenomena of the intelligent driver model for traffic flow in a circular one-lane roadway. We show that the microscopic structure of traffic flow is dependent on its initial state by plotting the fraction of congested vehicles over the density, which shows a typical hysteresis loop, and by investigating the trajectories of vehicles on the velocity-over-headway plane. We find that the trajectories of vehicles on the velocity-over-headway plane, which usually show a hysteresis loop, include multiple loops. We also point out the relations between these hysteresis loops and the congested jams or high-density clusters in traffic flow.

  6. The hysteresis behavior of an Ising nanowire with core/shell morphology: Monte Carlo treatment

    NASA Astrophysics Data System (ADS)

    Boughazi, B.; Boughrara, M.; Kerouad, M.

    2014-08-01

    We have used Monte Carlo Simulations (MCS) to study the hysteresis behavior of the magnetic nanowire with core/shell morphology described by the spin {1}/{2} Ising particles in the core and the spin {3}/{2} Ising particles in the surface shell. The hysteresis curves are obtained for different temperatures. We find that the hysteresis loop areas decrease when the temperature increases and the hysteresis loops disappear at certain temperatures. Barkhausen jumps are observed for the ferromagnetic nanowire system. An unusual form of triple hysteresis behaviors is observed for the ferrimagnetic nanowire system. The thermal behaviors of the coercivity and the remanent magnetization are also investigated.

  7. Hysteresis in structural dynamics

    NASA Astrophysics Data System (ADS)

    Ivanyi, A.; Ivanyi, P.; Ivanyi, M. M.; Ivanyi, M.

    2012-05-01

    In this paper the Preisach hysteresis model is applied to determine the dynamic behavior of a steel column with mass on the top and loaded by an impulse force. The column is considered as a rigid element, while the fixed end of the column is modeled with a rotational spring of hysterestic characteristic. In the solution of the non-linear dynamical equation of motion the fix-point technique is inserted to the time marching iteration. In the investigation the non-linearity of the rotation spring is modeled with the Preisach hysteresis model. The variation of amplitude and the action time interval of force are changing. The results are plotted in figures.

  8. Hysteresis of ionization waves

    SciTech Connect

    Dinklage, A.; Bruhn, B.; Testrich, H.; Wilke, C.

    2008-06-15

    A quasi-logistic, nonlinear model for ionization wave modes is introduced. Modes are due to finite size of the discharge and current feedback. The model consists of competing coupled modes and it incorporates spatial wave amplitude saturation. The hysteresis of wave mode transitions under current variation is reproduced. Sidebands are predicted by the model and found in experimental data. The ad hoc model is equivalent to a general--so-called universal--approach from bifurcation theory.

  9. Real-time inverse hysteresis compensation of piezoelectric actuators with a modified Prandtl-Ishlinskii model.

    PubMed

    Gu, Guo-Ying; Yang, Mei-Ju; Zhu, Li-Min

    2012-06-01

    This paper presents a novel real-time inverse hysteresis compensation method for piezoelectric actuators exhibiting asymmetric hysteresis effect. The proposed method directly utilizes a modified Prandtl-Ishlinskii hysteresis model to characterize the inverse hysteresis effect of piezoelectric actuators. The hysteresis model is then cascaded in the feedforward path for hysteresis cancellation. It avoids the complex and difficult mathematical procedure for constructing an inversion of the hysteresis model. For the purpose of validation, an experimental platform is established. To identify the model parameters, an adaptive particle swarm optimization algorithm is adopted. Based on the identified model parameters, a real-time feedforward controller is implemented for fast hysteresis compensation. Finally, tests are conducted with various kinds of trajectories. The experimental results show that the tracking errors caused by the hysteresis effect are reduced by about 90%, which clearly demonstrates the effectiveness of the proposed inverse compensation method with the modified Prandtl-Ishlinskii model.

  10. Contact angle hysteresis, adhesion, and marine biofouling.

    PubMed

    Schmidt, Donald L; Brady, Robert F; Lam, Karen; Schmidt, Dale C; Chaudhury, Manoj K

    2004-03-30

    Adhesive and marine biofouling release properties of coatings containing surface-oriented perfluoroalkyl groups were investigated. These coatings were prepared by cross-linking a copolymer of 1H,1H,2H,2H-heptadecafluorodecyl acrylate and acrylic acid with a copolymer of poly(2-isopropenyl-2-oxazoline) and methyl methacrylate at different molar ratios. The relationships between contact angle, contact angle hysteresis, adhesion, and marine biofouling were studied. Adhesion was determined by peel tests using pressure-sensitive adhesives. The chemical nature of the surfaces was studied by using X-ray photoelectron spectroscopy. Resistance to marine biofouling of an optimized coating was studied by immersion in seawater and compared to previous, less optimized coatings. The adhesive release properties of the coatings did not correlate well with the surface energies of the coatings estimated from the static and advancing contact angles nor with the amount of fluorine present on the surface. The adhesive properties of the surfaces, however, show a correlation with water receding contact angles and contact angle hysteresis (or wetting hysteresis) resulting from surface penetration and surface reconstruction. Coatings having the best release properties had both the highest cross-link density and the lowest contact angle hysteresis. An optimized coating exhibited unprecedented resistance to marine biofouling. Water contact angle hysteresis appears to correlate with marine biofouling resistance.

  11. Mesoscopic magnetomechanical hysteresis in a magnetorheological elastomer.

    PubMed

    Biller, A M; Stolbov, O V; Raikher, Yu L

    2015-08-01

    Field-induced magnetostatic interaction in a pair of identical particles made of a magnetically soft ferromagnet is studied. It is shown that due to saturation of the ferromagnet magnetization, this case differs significantly from the (super)paramagnetic one. A numerical solution is given, discussed, and compared with that provided by a simpler model (nonlinear mutual dipoles). We show that for multidomain ferromagnetic particles embedded in an elastomer matrix, as for paramagnetic ones in the same environment, pair clusters may form or break by a hysteresis scenario. However, the magnetization saturation brings in important features to this effect. First, the bistability state and the hysteresis take place only in a limited region of the material parameters of the system. Second, along with the hysteresis jumps occurring under the sole influence of the field, the "latent" hysteresis is possible which realizes only if the action of the field is combined with some additional (nonmagnetic) external factor. The obtained conditions, when used to assess the possibility of clustering in real magnetorheological polymers, infer an important role of mesoscopic magnetomechanical hysteresis for the macroscopic properties of these composites.

  12. Allele specific-PCR and melting curve analysis showed relatively high frequency of β-casein gene A1 allele in Iranian Holstein, Simmental and native cows.

    PubMed

    Gholami, M; Hafezian, S H; Rahimi, G; Farhadi, A; Rahimi, Z; Kahrizi, D; Kiani, S; Karim, H; Vaziri, S; Muhammadi, S; Veisi, F; Ghadiri, K; Shetabi, H; Zargooshi, J

    2016-10-31

    There are two allelic forms of A1 and A2 of β-casein gene in dairy cattle. Proteolytic digestion of bovine β-casein A1 type produces bioactive peptide of β-casomorphin-7 known as milk devil. β-casomorphin-7 causes many diseases, including type 1 diabetes, cardiovascular disease syndrome, sudden death and madness. The aim of the present study was to determine the different allelic forms of β-casein gene in Iranian Holstein, Simmental and native cattle in order to identify A1 and A2 variants. The blood samples were collected randomly and DNA was extracted using modified salting out method. An 854 bp fragment including part of exon 7 and part of intron 6 of β-casein gene was amplified by allele specific polymerase chain reaction (AS-PCR). Also, the accuracy of AS-PCR genotyping has been confirmed by melting temperature curve analysis using Real-time PCR machinery. The comparison of observed allele and genotype frequency among the studied breeds was performed using the Fisher exact and Chi-squared test, respectively by SAS program. Obtained results showed the A1 allele frequencies of 50, 51.57, 54.5, 49.4 and 46.6% in Holstein, Simmental, Sistani, Taleshi and Mazandarani cattle populations, respectively. The chi-square test was shown that no any populations were in Hardy-Weinberg equilibrium for studied marker locus. Comparison and analysis of the test results for allelic frequency showed no any significant differences between breeds (P>0.05). The frequency of observed genotypes only differs significantly between Holstein and Taleshi breeds but no any statistically significant differences were found for other breeds (P>0.05). A relatively high frequency of β-casein A1 allele was observed in Iranian native cattle. Therefore, determine the genotypes and preference alleles A2 in these native and commercial cattle is recommended.

  13. Hysteresis, thermomagnetic, and low-temperature magnetic properties of Southwestern U.S. obsidians

    NASA Astrophysics Data System (ADS)

    Sternberg, R. S.; Jackson, M. J.; Shackley, M. S.

    2011-12-01

    Geochemical signatures of Southwestern U.S. obsidians have been intensively studied, in part to use as a provenance method for archaeological obsidians (Shackley, 2005). We reported (Sternberg et al. 2010) examined magnetic properties of 50 unoriented samples from 10 geologic obsidian sources in Arizona, Nevada, and New Mexico; here we provide additional results measured at the Institute for Rock magnetism. Room-temperature hysteresis curves were measured using a vibrating sample magnetometer on 58 specimens from all 50 samples. The Quantum Designs Magnetic Properties Measurement System was used to measure low temperature cycling of the natural remanence and/or of a room-temperature saturation isothermal remanence for 10 specimens, and frequency dependence of susceptibility for 7 specimens. A Princeton VSM was used to measure hysteresis curves and thermomagnetic curves for 19 specimens from 17 samples. Eleven of the thermomagnetic curves show Curie temperatures close to that for magnetite, and most of them are almost perfectly reversible. Many of the specimens also show a less well-defined Curie point around 150-200°C; for a few specimens the thermomagnetic behavior is dominated by paramagnetic iron and no ferromagnetic phases can be identified. The low-temperature remanence and susceptibility measurements show the magnetite Verwey transition in almost all specimens, and a significant superparamagnetic presence in only a few cases. Hysteresis parameters plot mainly in the lower half of the PSD domain on a Day plot, and saturation magnetization values indicate magnetite concentrations of about 0.2% to 0.5% for most specimens. The coercivity of remanence decreased considerably for one specimen after surface cleaning, although for 5 other comparisons there was no change.

  14. Electroosmotic flow hysteresis for dissimilar ionic solutions

    PubMed Central

    Lim, An Eng; Lam, Yee Cheong

    2015-01-01

    Electroosmotic flow (EOF) with two or more fluids is commonly encountered in various microfluidics applications. However, no investigation has hitherto been conducted to investigate the hysteretic or flow direction-dependent behavior during the displacement flow of solutions with dissimilar ionic species. In this investigation, electroosmotic displacement flow involving dissimilar ionic solutions was studied experimentally through a current monitoring method and numerically through finite element simulations. The flow hysteresis can be characterized by the turning and displacement times; turning time refers to the abrupt gradient change of current-time curve while displacement time is the time for one solution to completely displace the other solution. Both experimental and simulation results illustrate that the turning and displacement times for a particular solution pair can be directional-dependent, indicating that the flow conditions in the microchannel are not the same in the two different flow directions. The mechanics of EOF hysteresis was elucidated through the theoretical model which includes the ionic mobility of each species, a major governing parameter. Two distinct mechanics have been identified as the causes for the EOF hysteresis involving dissimilar ionic solutions: the widening/sharpening effect of interfacial region between the two solutions and the difference in ion concentration distributions (and thus average zeta potentials) in different flow directions. The outcome of this investigation contributes to the fundamental understanding of flow behavior in microfluidic systems involving solution pair with dissimilar ionic species. PMID:25945139

  15. Thermal hysteresis proteins.

    PubMed

    Barrett, J

    2001-02-01

    Extreme environments present a wealth of biochemical adaptations. Thermal hysteresis proteins (THPs) have been found in vertebrates, invertebrates, plants, bacteria and fungi and are able to depress the freezing point of water (in the presence of ice crystals) in a non-colligative manner by binding to the surface of nascent ice crystals. The THPs comprise a disparate group of proteins with a variety of tertiary structures and often no common sequence similarities or structural motifs. Different THPs bind to different faces of the ice crystal, and no single mechanism has been proposed to account for THP ice binding affinity and specificity. Experimentally THPs have been used in the cryopreservation of tissues and cells and to induce cold tolerance in freeze susceptible organisms. THPs represent a remarkable example of parallel and convergent evolution with different proteins being adapted for an anti-freeze role.

  16. Vortex flow hysteresis

    NASA Technical Reports Server (NTRS)

    Cunningham, A. M., Jr.

    1986-01-01

    An experimental study was conducted to quantify the hysteresis associated with various vortex flow transition points and to determine the effect of planform geometry. The transition points observed consisted of the appearance (or disappearance) of trailing edge vortex burst and the transition to (or from) flat plate or totally separated flows. Flow visualization with smoke injected into the vortices was used to identify the transitions on a series of semi-span models tested in a low speed tunnel. The planforms tested included simple deltas (55 deg to 80 deg sweep), cranked wings with varying tip panel sweep and dihedral, and a straked wing. High speed movies at 1000 frames per second were made of the vortex flow visualization in order to better understand the dynamics of vortex flow, burst and transition.

  17. The significance of observed rotational magnetic hysteresis in lunar samples

    NASA Technical Reports Server (NTRS)

    Wasilewski, P.

    1974-01-01

    Rotational magnetic hysteresis curves for lunar soils 10084, 12070, and 14259, and rock 14053 have been published. There is no adequate explanation to date for the observed large hysteresis at high fields. Lunar rock magnetism researchers consider fine particle iron to be the primary source of stable magnetic remanence in lunar samples. Iron has cubic anisotropy with added shape anisotropy for extreme particle shapes. The observed high-field hysteresis must have its source in uniaxial or unidirectional anisotropy. This implies the existence of minerals with uniaxial anisotropy or exchange-coupled spin states. Therefore, the source of this observed high-field hysteresis must be identified and understood before serious paleointensity studies are made. It is probable that the exchange-coupled spin states and/or the source of uniaxial anisotropy responsible for the high-field hysteresis might be influenced by the lunar surface diurnal temperature cycling. The possible sources of high-field hysteresis in lunar samples are presented and considered.

  18. Conductance hysteresis in the voltage-dependent anion channel.

    PubMed

    Rappaport, Shay M; Teijido, Oscar; Hoogerheide, David P; Rostovtseva, Tatiana K; Berezhkovskii, Alexander M; Bezrukov, Sergey M

    2015-09-01

    Hysteresis in the conductance of voltage-sensitive ion channels is observed when the transmembrane voltage is periodically varied with time. Although this phenomenon has been used in studies of gating of the voltage-dependent anion channel, VDAC, from the outer mitochondrial membrane for nearly four decades, full hysteresis curves have never been reported, because the focus was solely on the channel opening branches of the hysteresis loops. We studied the hysteretic response of a multichannel VDAC system to a triangular voltage ramp the frequency of which was varied over three orders of magnitude, from 0.5 mHz to 0.2 Hz. We found that in this wide frequency range the area encircled by the hysteresis curves changes by less than a factor of three, suggesting broad distribution of the characteristic times and strongly non-equilibrium behavior. At the same time, quasi-equilibrium two-state behavior is observed for hysteresis branches corresponding to VDAC opening. This enables calculation of the usual equilibrium gating parameters, gating charge and voltage of equipartitioning, which were found to be almost insensitive to the ramp frequency. To rationalize this peculiarity, we hypothesize that during voltage-induced closure and opening the system explores different regions of the complex free energy landscape, and, in the opening branch, follows quasi-equilibrium paths.

  19. Macroscopic theory for capillary-pressure hysteresis.

    PubMed

    Athukorallage, Bhagya; Aulisa, Eugenio; Iyer, Ram; Zhang, Larry

    2015-03-03

    In this article, we present a theory of macroscopic contact angle hysteresis by considering the minimization of the Helmholtz free energy of a solid-liquid-gas system over a convex set, subject to a constant volume constraint. The liquid and solid surfaces in contact are assumed to adhere weakly to each other, causing the interfacial energy to be set-valued. A simple calculus of variations argument for the minimization of the Helmholtz energy leads to the Young-Laplace equation for the drop surface in contact with the gas and a variational inequality that yields contact angle hysteresis for advancing/receding flow. We also show that the Young-Laplace equation with a Dirichlet boundary condition together with the variational inequality yields a basic hysteresis operator that describes the relationship between capillary pressure and volume. We validate the theory using results from the experiment for a sessile macroscopic drop. Although the capillary effect is a complex phenomenon even for a droplet as various points along the contact line might be pinned, the capillary pressure and volume of the drop are scalar variables that encapsulate the global quasistatic energy information for the entire droplet. Studying the capillary pressure versus volume relationship greatly simplifies the understanding and modeling of the phenomenon just as scalar magnetic hysteresis graphs greatly aided the modeling of devices with magnetic materials.

  20. Ac magnetorestriction hysteresis and magnetization direction in grain oriented silicon steels

    SciTech Connect

    Mogi, Hisashi; Matsuo, Yukio; Kumano, Tomoji

    1999-09-01

    A hysteresis curve of ac magnetostriction was measured, magnetizing a grain oriented silicon steel in the direction deviated from rolling direction of a sample. The ac magnetostriction ({lambda} ac) curves were analyzed as harmonics in the interest of noise spectrum of such as a power transformer. The domain structure model in this magnetostriction process was proposed. The hysteresis was large in the magnetization direction inclined at 30 and 90{degree} from the rolling direction.

  1. Numerical hysteresis model for intermittent studies in unsaturated soils

    NASA Astrophysics Data System (ADS)

    Banerjee, M.

    1986-07-01

    In the present study, the use of one of the recent dependent domain models of capillary hysteresis in the numerical analysis of intermittent infiltration and redistribution of water in two types of soils (a sand and Rubicon Sandy Loam) has been shown. The numerical results for both the soils have been presented in terms of pressure head depth, moisture content depth and the pressure head-moisture content relationships. The capillary hysteresis model has been found to be very useful for the prediction of both wetting and drying scanning curves of various orders.

  2. Hysteresis of boiling for different tunnel-pore surfaces

    NASA Astrophysics Data System (ADS)

    Pastuszko, Robert; Piasecka, Magdalena

    2015-05-01

    Analysis of boiling hysteresis on structured surfaces covered with perforated foil is proposed. Hysteresis is an adverse phenomenon, preventing high heat flux systems from thermal stabilization, characterized by a boiling curve variation at an increase and decrease of heat flux density. Experimental data were discussed for three kinds of enhanced surfaces: tunnel structures (TS), narrow tunnel structures (NTS) and mini-fins covered with the copper wire net (NTS-L). The experiments were carried out with water, R-123 and FC-72 at atmospheric pressure. A detailed analysis of the measurement results identified several cases of type I, II and III for TS, NTS and NTS-L surfaces.

  3. Effect of Hysteresis on Measurements of Thin-Film Cell Performance

    SciTech Connect

    Albin, D.; del Cueto, J.

    2011-03-01

    Transient or hysteresis effects in polycrystalline thin film CdS/CdTe cells are a function of pre-measurement voltage bias and whether Cu is introduced as an intentional dopant during back contact fabrication. When Cu is added, the current-density (J) vs. voltage (V) measurements performed in a reverse-to-forward voltage direction will yield higher open-circuit voltage (Voc), up to 10 mV, and smaller short-circuit current density (Jsc), by up to 2 mA/cm2, relative to scanning voltage in a forward-to-reverse direction. The variation at the maximum power point, Pmax, is however small. The resulting variation in FF can be as large as 3%. When Cu is not added, hysteresis in both Voc and Jsc is negligible however Pmax hysteresis is considerably greater. This behavior corroborates observed changes in depletion width, Wd, derived from capacitance (C) vs voltage (V) scans. Measured values of Wd are always smaller in reverse-to-forward voltage scans, and conversely, larger in the forward-to-reverse voltage direction. Transient ion drift (TID) measurements performed on Cu-containing cells do not show ionic behavior suggesting that capacitance transients are more likely due to electronic capture-emission processes. J-V curve simulation using Pspice shows that increased transient capacitance during light-soak stress at 100 degrees C correlates with increased space-charge recombination. Voltage-dependent collection however was not observed to increase with stress in these cells.

  4. Effect of hysteresis on measurements of thin-film cell performance

    NASA Astrophysics Data System (ADS)

    Albin, D. S.; del Cueto, J. A.

    2010-08-01

    Transient or hysteresis effects in polycrystalline thin film CdS/CdTe cells are a function of pre-measurement voltage bias and whether Cu is introduced as an intentional dopant during back contact fabrication. When Cu is added, the current-density (J) vs. voltage (V) measurements performed in a reverse-to-forward voltage direction will yield higher open-circuit voltage (Voc), up to 10 mV, and smaller short-circuit current density (Jsc), by up to 2 mA/cm2, relative to scanning voltage in a forward-to-reverse direction. The variation at the maximum power point, Pmax, is however small. The resulting variation in FF can be as large as 3%. When Cu is not added, hysteresis in both Voc and Jsc is negligible however Pmax hysteresis is considerably greater. This behavior corroborates observed changes in depletion width, Wd, derived from capacitance (C) vs voltage (V) scans. Measured values of Wd are always smaller in reverse-to-forward voltage scans, and conversely, larger in the forward-to-reverse voltage direction. Transient ion drift (TID) measurements performed on Cu-containing cells do not show ionic behavior suggesting that capacitance transients are more likely due to electronic capture-emission processes. J-V curve simulation using Pspice shows that increased transient capacitance during light-soak stress at 100 °C correlates with increased space-charge recombination. Voltagedependent collection however was not observed to increase with stress in these cells.

  5. Mach, methodology, hysteresis and economics

    NASA Astrophysics Data System (ADS)

    Cross, R.

    2008-11-01

    This methodological note examines the epistemological foundations of hysteresis with particular reference to applications to economic systems. The economy principles of Ernst Mach are advocated and used in this assessment.

  6. Two-phase equilibrium states in individual Cu-Ni nanoparticles: size, depletion and hysteresis effects.

    PubMed

    Shirinyan, Aram S

    2015-01-01

    In isolated bimetallic nanoscale systems the limit amount of matter and surface-induced size effects can change the thermodynamics of first-order phase transformation. In this paper we present theoretical modification of Gibbs free energy concept describing first-order phase transformation of binary alloyed nanoparticles taking into account size effects as well as depletion and hysteresis effects. In such a way the hysteresis in a form of nonsymmetry for forth and back transforming paths takes place; compositional splitting and the loops-like splitted path on the size dependent temperature-composition phase diagram occur. Our calculations for individual Cu-Ni nanoparticle show that one must differentiate the solubility curves and the equilibrium loops (discussed here in term of solidification and melting loops). For the first time we have calculated and present here on the temperature-composition phase diagram the nanomelting loop at the size of 80 nm and the nanosolidification loop at the size of 25 nm for an individual Cu-Ni nanoparticle. So we observe the difference between the size-dependent phase diagram and solubility diagram, between two-phase equilibrium curves and solubility curves; also intersection of nanoliquidus and nanosolidus is available. These findings lead to the necessity to reconsider such basic concepts in materials science as phase diagram and solubility diagram.

  7. High contact angle hysteresis of superhydrophobic surfaces: Hydrophobic defects

    NASA Astrophysics Data System (ADS)

    Chang, Feng-Ming; Hong, Siang-Jie; Sheng, Yu-Jane; Tsao, Heng-Kwong

    2009-08-01

    A typical superhydrophobic surface is essentially nonadhesive and exhibits very low water contact angle (CA) hysteresis, so-called Lotus effect. However, leaves of some plants such as scallion and garlic with an advancing angle exceeding 150° show very serious CA hysteresis. Although surface roughness and epicuticular wax can explain the very high advancing CA, our analysis indicates that the unusual hydrophobic defect, diallyl disulfide, is the key element responsible for contact line pinning on allium leaves. After smearing diallyl disulfide on an extended polytetrafluoroethylene (PTFE) film, which is originally absent of CA hysteresis, the surface remains superhydrophobic but becomes highly adhesive.

  8. Hysteresis phenomena in hydraulic measurement

    NASA Astrophysics Data System (ADS)

    Ran, H. J.; Luo, X. W.; Chen, Y. L.; Xu, H. Y.; Farhat, M.

    2012-11-01

    Hysteresis phenomena demonstrate the lag between the generation and the removal of some physical phenomena. This paper studies the hysteresis phenomena of the head-drop in a scaled model pump turbine using experiment test and CFD methods. These lag is induced by complicated flow patterns, which influenced the reliability of rotating machine. Keeping the same measurement procedure is concluded for the hydraulic machine measurement.

  9. Mastering hysteresis in magnetocaloric materials.

    PubMed

    Gutfleisch, O; Gottschall, T; Fries, M; Benke, D; Radulov, I; Skokov, K P; Wende, H; Gruner, M; Acet, M; Entel, P; Farle, M

    2016-08-13

    Hysteresis is more than just an interesting oddity that occurs in materials with a first-order transition. It is a real obstacle on the path from existing laboratory-scale prototypes of magnetic refrigerators towards commercialization of this potentially disruptive cooling technology. Indeed, the reversibility of the magnetocaloric effect, being essential for magnetic heat pumps, strongly depends on the width of the thermal hysteresis and, therefore, it is necessary to understand the mechanisms causing hysteresis and to find solutions to minimize losses associated with thermal hysteresis in order to maximize the efficiency of magnetic cooling devices. In this work, we discuss the fundamental aspects that can contribute to thermal hysteresis and the strategies that we are developing to at least partially overcome the hysteresis problem in some selected classes of magnetocaloric materials with large application potential. In doing so, we refer to the most relevant classes of magnetic refrigerants La-Fe-Si-, Heusler- and Fe2P-type compounds.This article is part of the themed issue 'Taking the temperature of phase transitions in cool materials'.

  10. Hysteresis modeling in ballistic carbon nanotube field-effect transistors

    PubMed Central

    Liu, Yian; Moura, Mateus S; Costa, Ademir J; de Almeida, Luiz Alberto L; Paranjape, Makarand; Fontana, Marcio

    2014-01-01

    Theoretical models are adapted to describe the hysteresis effects seen in the electrical characteristics of carbon nanotube field-effect transistors. The ballistic transport model describes the contributions of conduction energy sub-bands over carbon nanotube field-effect transistor drain current as a function of drain-source and gate-source voltages as well as other physical parameters of the device. The limiting-loop proximity model, originally developed to understand magnetic hysteresis, is also utilized in this work. The curves obtained from our developed model corroborate well with the experimentally derived hysteretic behavior of the transistors. Modeling the hysteresis behavior will enable designers to reliably use these effects in both analog and memory applications. PMID:25187698

  11. The intrinsic origin of hysteresis in MoS2 field effect transistors

    NASA Astrophysics Data System (ADS)

    Shu, Jiapei; Wu, Gongtao; Guo, Yao; Liu, Bo; Wei, Xianlong; Chen, Qing

    2016-01-01

    We investigate the hysteresis and gate voltage stress effect in MoS2 field effect transistors (FETs). We observe that both the suspended and the SiO2-supported FETs have large hysteresis in their transfer curves under vacuum which cannot be attributed to the traps at the interface between the MoS2 and the SiO2 or in the SiO2 substrate or the gas adsorption/desorption effect. Our findings indicate that the hysteresis we observe comes from the MoS2 itself, revealing an intrinsic origin of the hysteresis besides some extrinsic factors. The fact that the FETs based on thinner MoS2 have larger hysteresis than that with thicker MoS2 suggests that the surface of MoS2 plays a key role in the hysteresis. The gate voltage sweep range, sweep direction, sweep time and loading history all affect the hysteresis observed in the transfer curves.We investigate the hysteresis and gate voltage stress effect in MoS2 field effect transistors (FETs). We observe that both the suspended and the SiO2-supported FETs have large hysteresis in their transfer curves under vacuum which cannot be attributed to the traps at the interface between the MoS2 and the SiO2 or in the SiO2 substrate or the gas adsorption/desorption effect. Our findings indicate that the hysteresis we observe comes from the MoS2 itself, revealing an intrinsic origin of the hysteresis besides some extrinsic factors. The fact that the FETs based on thinner MoS2 have larger hysteresis than that with thicker MoS2 suggests that the surface of MoS2 plays a key role in the hysteresis. The gate voltage sweep range, sweep direction, sweep time and loading history all affect the hysteresis observed in the transfer curves. Electronic supplementary information (ESI) available. See DOI: 10.1039/c5nr07336g

  12. Light regulated I-V hysteresis loop of Ag/BiFeO3/FTO thin film

    NASA Astrophysics Data System (ADS)

    Wei, Lujun; Sun, Bai; Zhao, Wenxi; Li, Hongwei; Chen, Peng

    2017-01-01

    A hysteresis loop of current-voltage characteristics based multiferroic BiFeO3 nanoribbons memory device is observed. Moreover, the white-light can greatly regulate both the current-voltage hysteresis loop and the ferroelectric hysteresis loop. The stored space charges within the electrodes/BiFeO3 interface can lead to hysteresis-type I-V characteristics of Ag/BiFeO3/FTO devices. The white-light controlled I-V loop and ferroelectric loop result from photon-generated carries. Since the I-V hysteresis loop and ferroelectric hysteresis loop have a potential application prospect to the memory devices, these two white-light controlled the hysteresis loops curves are likely to provide promising opportunity for developing the multi-functional memory devices.

  13. Hysteresis Analysis Based on the Ferroelectric Effect in Hybrid Perovskite Solar Cells.

    PubMed

    Wei, Jing; Zhao, Yicheng; Li, Heng; Li, Guobao; Pan, Jinlong; Xu, Dongsheng; Zhao, Qing; Yu, Dapeng

    2014-11-06

    The power conversion efficiency (PCE) of CH3NH3PbX3 (X = I, Br, Cl) perovskite solar cells has been developed rapidly from 6.5 to 18% within 3 years. However, the anomalous hysteresis found in I-V measurements can cause an inaccurate estimation of the efficiency. We attribute the phenomena to the ferroelectric effect and build a model based on the ferroelectric diode to explain it. The ferroelectric effect of CH3NH3PbI3-xClx is strongly suggested by characterization methods and the E-P (electrical field-polarization) loop. The hysteresis in I-V curves is found to greatly depend on the scan range as well as the velocity, which is well explained by the ferroelectric diode model. We also find that the current signals show exponential decay in ∼10 s under prolonged stepwise measurements, and the anomalous hysteresis disappears using these stabilized current values. The experimental results accord well with the model based on ferroelectric properties and prove that prolonged stepwise measurement is an effective way to evaluate the real efficiency of perovskite solar cells. Most importantly, this work provides a meaningful perspective that the ferroelectric effect (if it really exists) should be paid special attention in the optimization of perovskite solar cells.

  14. Hydrograph Asymmetry Drives Bedload Transport Hysteresis: Evidence from Fluvial Seismology

    NASA Astrophysics Data System (ADS)

    Finnegan, N. J.; Roth, D. L.; Brodsky, E. E.; Hsu, L.

    2015-12-01

    Bedload transport rates are frequently different for an equivalent stage or discharge on the rising and falling limbs of a hydrograph. This asymmetry in transport results in hysteresis in sediment rating curves, which although widely documented, is not well understood mechanistically. A major factor contributing to the uncertain origins of hysteresis is the difficulty associated with making continuous bedload transport measurements in large rivers during floods. However, recent work demonstrates that seismic signals from rivers can provide quantitative constraints on the evolution of bedload transport during storms on large rivers, when direct measurements would otherwise be impossible. Here, we analyze patterns in the amplitude of seismic shaking along the Cho-Shui River in Taiwan and along the Erlenbach Stream in Switzerland during a total of 10 storm events. The storms exhibit varying amounts of hysteresis in the amplitude of seismic shaking as a function of flood discharge (as measured from nearby gages). However, the amount of hysteresis, which we quantify with a non-dimensional metric, correlates strongly with the degree of asymmetry in the flood hydrograph. Specifically, the degree of hysteresis observed during an event scales inversely with the ratio of the rising limb time to the recessional limb time. Flume experiments and field observations indicate that vertical sorting and, hence, armor formation in gravel-bedded river channels is more pronounced during longer storms. Although we lack direct constraints on the bed surface during the observed events, our results support the possibility that differential gravel sorting on the rising and falling limbs is responsible for the observed hysteresis. Specifically, our results imply that for a given stage, armor will be better developed on a slow recessional limb, resulting in lower gravel transport rates and a pattern of clockwise hysteresis.

  15. Hysteresis loop of nonperiodic outbreaks of recurrent epidemics.

    PubMed

    Liu, Hengcong; Zheng, Muhua; Wu, Dayu; Wang, Zhenhua; Liu, Jinming; Liu, Zonghua

    2016-12-01

    Most of the studies on epidemics so far have focused on the growing phase, such as how an epidemic spreads and what are the conditions for an epidemic to break out in a variety of cases. However, we discover from real data that on a large scale, the spread of an epidemic is in fact a recurrent event with distinctive growing and recovering phases, i.e., a hysteresis loop. We show here that the hysteresis loop can be reproduced in epidemic models provided that the infectious rate is adiabatically increased or decreased before the system reaches its stationary state. Two ways to the hysteresis loop are revealed, which is helpful in understanding the mechanics of infections in real evolution. Moreover, a theoretical analysis is presented to explain the mechanism of the hysteresis loop.

  16. Hysteresis loop of nonperiodic outbreaks of recurrent epidemics

    NASA Astrophysics Data System (ADS)

    Liu, Hengcong; Zheng, Muhua; Wu, Dayu; Wang, Zhenhua; Liu, Jinming; Liu, Zonghua

    2016-12-01

    Most of the studies on epidemics so far have focused on the growing phase, such as how an epidemic spreads and what are the conditions for an epidemic to break out in a variety of cases. However, we discover from real data that on a large scale, the spread of an epidemic is in fact a recurrent event with distinctive growing and recovering phases, i.e., a hysteresis loop. We show here that the hysteresis loop can be reproduced in epidemic models provided that the infectious rate is adiabatically increased or decreased before the system reaches its stationary state. Two ways to the hysteresis loop are revealed, which is helpful in understanding the mechanics of infections in real evolution. Moreover, a theoretical analysis is presented to explain the mechanism of the hysteresis loop.

  17. A New Model Based on Adaptation of the External Loop to Compensate the Hysteresis of Tactile Sensors

    PubMed Central

    Sánchez-Durán, José A.; Vidal-Verdú, Fernando; Oballe-Peinado, Óscar; Castellanos-Ramos, Julián; Hidalgo-López, José A.

    2015-01-01

    This paper presents a novel method to compensate for hysteresis nonlinearities observed in the response of a tactile sensor. The External Loop Adaptation Method (ELAM) performs a piecewise linear mapping of the experimentally measured external curves of the hysteresis loop to obtain all possible internal cycles. The optimal division of the input interval where the curve is approximated is provided by the error minimization algorithm. This process is carried out off line and provides parameters to compute the split point in real time. A different linear transformation is then performed at the left and right of this point and a more precise fitting is achieved. The models obtained with the ELAM method are compared with those obtained from three other approaches. The results show that the ELAM method achieves a more accurate fitting. Moreover, the involved mathematical operations are simpler and therefore easier to implement in devices such as Field Programmable Gate Array (FPGAs) for real time applications. Furthermore, the method needs to identify fewer parameters and requires no previous selection process of operators or functions. Finally, the method can be applied to other sensors or actuators with complex hysteresis loop shapes. PMID:26501279

  18. A new model based on adaptation of the external loop to compensate the hysteresis of tactile sensors.

    PubMed

    Sánchez-Durán, José A; Vidal-Verdú, Fernando; Oballe-Peinado, Óscar; Castellanos-Ramos, Julián; Hidalgo-López, José A

    2015-10-15

    This paper presents a novel method to compensate for hysteresis nonlinearities observed in the response of a tactile sensor. The External Loop Adaptation Method (ELAM) performs a piecewise linear mapping of the experimentally measured external curves of the hysteresis loop to obtain all possible internal cycles. The optimal division of the input interval where the curve is approximated is provided by the error minimization algorithm. This process is carried out off line and provides parameters to compute the split point in real time. A different linear transformation is then performed at the left and right of this point and a more precise fitting is achieved. The models obtained with the ELAM method are compared with those obtained from three other approaches. The results show that the ELAM method achieves a more accurate fitting. Moreover, the involved mathematical operations are simpler and therefore easier to implement in devices such as Field Programmable Gate Array (FPGAs) for real time applications. Furthermore, the method needs to identify fewer parameters and requires no previous selection process of operators or functions. Finally, the method can be applied to other sensors or actuators with complex hysteresis loop shapes.

  19. Dynamic Hysteresis in Compacted Magnetic Nanoparticles

    NASA Astrophysics Data System (ADS)

    Chowdary, Krishna M.

    The frequency and temperature dependent magnetic response of a bulk soft magnetic nanocomposite made by compacting Fe10Co 90 nanoparticles was measured and modeled. Electron microscopy and x-ray diffraction were used to characterize the size, composition, and structure of the nanoparticles and nanocomposite. Polyol synthesis was used to produce 200 nm particles with average grain size 20 nm and large superparamagnetic fraction. The nanoparticles were consolidated to 90% theoretical density by plasma pressure compaction. The compacted nanoparticles retained the 20 nm average grain size and large superparamagnetic fraction. The nanocomposite resistivity was more than three times that of the bulk alloy. Vibrating sample and SQUID-MPMS magnetometers were used for low frequency magnetic measurements of the nanoparticles and nanocomposite. Compaction reduced the coercivity from 175 Oe to 8 Oe and the effective anisotropy from 124 x 10 3 ergs/cc to 7.9 x 103 ergs/cc. These reductions were caused by increased exchange coupling between surface nanograins, consistent with predictions from the Random Anisotropy model. Varying degrees of exchange coupling existed within the nanocomposite, contributing to a distribution of energy barriers. A permeameter was used for frequency dependent magnetic measurements on a toroid cut from the nanocomposite. Complex permeability, coercivity, and power loss were extracted from dynamic minor hysteresis loops measured over a range of temperatures (77 K - 873 K) and frequencies (0.1 kHz - 100 kHz). The real and imaginary parts of the complex permeability spectrum showed asymmetries consistent with a distribution of energy barriers and high damping. When the complex permeability, power loss, and coercivity were scaled relative to the peak frequency of the imaginary permeability, all fell on universal curves. Various microscopic and macroscopic models for the complex permeability were investigated. The complex permeability was successfully fit

  20. Hysteresis in Analytical Solutions for Three-phase Flow

    NASA Astrophysics Data System (ADS)

    Lambers, J. V.; LaForce, T.

    2011-12-01

    Hysteresis in relative permeability is a widely-recognized phenomenon that impacts oil recovery in water and gas (WAG) injection. Several authors (1-3) have constructed analytical solutions for two-phase oil/water or gas/water flow in enhanced oil recovery however, analytical solutions have not previously been constructed for the three-phase flow problem for immiscible water, oil and gas including hysteresis. In this work analytical solutions are constructed for water and gas floods in a previously water-flooded oil reservoir with and without hysteresis. A simplified model is used in the analysis that qualitatively captures the behavior of oil-phase hysteresis for repeated water imbibition and drainage cycles. Many of the displacements considered have a reversal of flow direction within the displacement, requiring a matching condition to be enforced between the imbibition and drainage relative permeability curves at the point of flow reversal. A suitable matching criterion for the hysteretic curves is presented. A single water/gas injection mixture is considered, with varying initial oil and water volumes present in the reservoir. When hysteresis occurs in a displacement the entire saturation path depends on the initial volumes of oil and water present at the onset of WAG flooding. When hysteresis is ignored most of the displacement is identical for a large range of initial oil and water mixtures, with only the velocity of the leading shock changing. For the displacements which only encounter drainage of the water phase, solutions with and without hysteresis are identical. 1) K. M. Furati, ``Effects of Relative Permeability History Dependence on Two-Phase Flow in Porous Media,'' Transport in Porous Media 28: 181-203, 1997. 2) B. Plohr, D. Marchesin, P. Bedrikovetsky and P. Krause, ``Modeling hysteresis in porous media flow via relaxation,'' Computational Geosciences 5: 225-256, 2001. 3) F. M. Van Kats and C. J. Van Duijn, ``A Mathematical Model for Hysteretic Two

  1. Constitutive modeling of contact angle hysteresis.

    PubMed

    Vedantam, Srikanth; Panchagnula, Mahesh V

    2008-05-15

    We introduce a phase field model of wetting of surfaces by sessile drops. The theory uses a two-dimensional non-conserved phase field variable to parametrize the Gibbs free energy of the three-dimensional system. Contact line tension and contact angle hysteresis arise from the gradient term in the free energy and the kinetic coefficient respectively. A significant advantage of this approach is in the constitutive specification of hysteresis. The advancing and receding angles of a surface, the liquid-vapor interfacial energy and three-phase line tension are the only required constitutive inputs to the model. We first simulate hysteresis on a smooth chemically homogeneous surface using this theory. Next we show that it is possible to study heterogeneous surfaces whose component surfaces are themselves hysteretic. We use this theory to examine the wetting of a surface containing a circular heterogeneous island. The contact angle for this case is found to be determined solely by the material properties at the contact line in accord with recent experimental data.

  2. Bradford Curves.

    ERIC Educational Resources Information Center

    Rousseau, Ronald

    1994-01-01

    Discussion of informetric distributions shows that generalized Leimkuhler functions give proper fits to a large variety of Bradford curves, including those exhibiting a Groos droop or a rising tail. The Kolmogorov-Smirnov test is used to test goodness of fit, and least-square fits are compared with Egghe's method. (Contains 53 references.) (LRW)

  3. Perceptual hysteresis in the judgment of auditory pitch shift.

    PubMed

    Chambers, Claire; Pressnitzer, Daniel

    2014-07-01

    Perceptual hysteresis can be defined as the enduring influence of the recent past on current perception. Here, hysteresis was investigated in a basic auditory task: pitch comparisons between successive tones. On each trial, listeners were presented with pairs of tones and asked to report the direction of subjective pitch shift, as either "up" or "down." All tones were complexes known as Shepard tones (Shepard, 1964), which comprise several frequency components at octave multiples of a base frequency. The results showed that perceptual judgments were determined both by stimulus-related factors (the interval ratio between the base frequencies within a pair) and by recent context (the intervals in the two previous trials). When tones were presented in ordered sequences, for which the frequency interval between tones was varied in a progressive manner, strong hysteresis was found. In particular, ambiguous stimuli that led to equal probabilities of "up" and "down" responses within a randomized context were almost fully determined within an ordered context. Moreover, hysteresis did not act on the direction of the reported pitch shift, but rather on the perceptual representation of each tone. Thus, hysteresis could be observed within sequences in which listeners varied between "up" and "down" responses, enabling us to largely rule out confounds related to response bias. The strength of the perceptual hysteresis observed suggests that the ongoing context may have a substantial influence on fundamental aspects of auditory perception, such as how we perceive the changes in pitch between successive sounds.

  4. Calculations on Hard Ferroelectric PbZr1-xTixO3 Dynamic Hysteresis

    NASA Astrophysics Data System (ADS)

    Hamad, Mahmoud A.

    2017-02-01

    A phenomenological model was modified for dynamic hysteresis loops of hard ferroelectric PbZr1-xTixO3 (PZT). The comparison with experimental results showed that the modified model can reproduce polarization versus an electric field. A predicted hysteresis loss of hard ferroelectric PZT was formulated and estimated. The calculations showed an increase in hysteresis loss with a decrease of frequency at a 40-kV/cm electric field amplitude.

  5. The intrinsic origin of hysteresis in MoS2 field effect transistors.

    PubMed

    Shu, Jiapei; Wu, Gongtao; Guo, Yao; Liu, Bo; Wei, Xianlong; Chen, Qing

    2016-02-07

    We investigate the hysteresis and gate voltage stress effect in MoS2 field effect transistors (FETs). We observe that both the suspended and the SiO2-supported FETs have large hysteresis in their transfer curves under vacuum which cannot be attributed to the traps at the interface between the MoS2 and the SiO2 or in the SiO2 substrate or the gas adsorption/desorption effect. Our findings indicate that the hysteresis we observe comes from the MoS2 itself, revealing an intrinsic origin of the hysteresis besides some extrinsic factors. The fact that the FETs based on thinner MoS2 have larger hysteresis than that with thicker MoS2 suggests that the surface of MoS2 plays a key role in the hysteresis. The gate voltage sweep range, sweep direction, sweep time and loading history all affect the hysteresis observed in the transfer curves.

  6. Nonlinear diffusion and superconducting hysteresis

    SciTech Connect

    Mayergoyz, I.D.

    1996-12-31

    Nonlinear diffusion of electromagnetic fields in superconductors with ideal and gradual resistive transitions is studied. Analytical results obtained for linear and nonlinear polarizations of electromagnetic fields are reported. These results lead to various extensions of the critical state model for superconducting hysteresis.

  7. Evidence for ion migration in hybrid perovskite solar cells with minimal hysteresis.

    PubMed

    Calado, Philip; Telford, Andrew M; Bryant, Daniel; Li, Xiaoe; Nelson, Jenny; O'Regan, Brian C; Barnes, Piers R F

    2016-12-22

    Ion migration has been proposed as a possible cause of photovoltaic current-voltage hysteresis in hybrid perovskite solar cells. A major objection to this hypothesis is that hysteresis can be reduced by changing the interfacial contact materials; however, this is unlikely to significantly influence the behaviour of mobile ionic charge within the perovskite phase. Here, we show that the primary effects of ion migration can be observed regardless of whether the contacts were changed to give devices with or without significant hysteresis. Transient optoelectronic measurements combined with device simulations indicate that electric-field screening, consistent with ion migration, is similar in both high and low hysteresis CH3NH3PbI3 cells. Simulation of the photovoltage and photocurrent transients shows that hysteresis requires the combination of both mobile ionic charge and recombination near the perovskite-contact interfaces. Passivating contact recombination results in higher photogenerated charge concentrations at forward bias which screen the ionic charge, reducing hysteresis.

  8. Impact of back-gate bias on the hysteresis effect in partially depleted SOI MOSFETs

    NASA Astrophysics Data System (ADS)

    Luo, Jie-Xin; Chen, Jing; Zhou, Jian-Hua; Wu, Qing-Qing; Chai, Zhan; Yu, Tao; Wang, Xi

    2012-05-01

    The hysteresis effect in the output characteristics, originating from the floating body effect, has been measured in partially depleted (PD) silicon-on-insulator (SOI) MOSFETs at different back-gate biases. ID hysteresis has been developed to clarify the hysteresis characteristics. The fabricated devices show the positive and negative peaks in the ID hysteresis. The experimental results show that the ID hysteresis is sensitive to the back gate bias in 0.13-μm PD SOI MOSFETs and does not vary monotonously with the back-gate bias. Based on the steady-state Shockley-Read-Hall (SRH) recombination theory, we have successfully interpreted the impact of the back-gate bias on the hysteresis effect in PD SOI MOSFETs.

  9. Evidence for ion migration in hybrid perovskite solar cells with minimal hysteresis

    NASA Astrophysics Data System (ADS)

    Calado, Philip; Telford, Andrew M.; Bryant, Daniel; Li, Xiaoe; Nelson, Jenny; O'Regan, Brian C.; Barnes, Piers R. F.

    2016-12-01

    Ion migration has been proposed as a possible cause of photovoltaic current-voltage hysteresis in hybrid perovskite solar cells. A major objection to this hypothesis is that hysteresis can be reduced by changing the interfacial contact materials; however, this is unlikely to significantly influence the behaviour of mobile ionic charge within the perovskite phase. Here, we show that the primary effects of ion migration can be observed regardless of whether the contacts were changed to give devices with or without significant hysteresis. Transient optoelectronic measurements combined with device simulations indicate that electric-field screening, consistent with ion migration, is similar in both high and low hysteresis CH3NH3PbI3 cells. Simulation of the photovoltage and photocurrent transients shows that hysteresis requires the combination of both mobile ionic charge and recombination near the perovskite-contact interfaces. Passivating contact recombination results in higher photogenerated charge concentrations at forward bias which screen the ionic charge, reducing hysteresis.

  10. Micromagnetic simulation of hysteresis loop of elliptic permalloy nanorings

    NASA Astrophysics Data System (ADS)

    Mishra, Amaresh Chandra

    2016-09-01

    Magnetic hysteresis behavior of isotropic permalloy elliptic nanorings of outer semi-major axis length (aout) 100 nm and thickness (t) 20 nm were studied with respect to the variation of two parameters: outer semiminor axis length (bout) and the difference between outer and inner dimensions (r). The outer semiminor axis length (bout) varied from 90 nm to 20 nm which covers from nearly circular nanoring to elliptic nanoring of high aspect ratio. The value of r varied in steps of 10 nm. Micromagnetic simulation of in-plane hysteresis curve of these nanorings revealed that the remanent state of all of these elliptic rings are onion states if the magnetic field is applied along the longer side of the elliptic rings. If the magnetic field is applied along the shorter side, then the remanent states turn out to be vortex state. The hysteresis loss indicated by area of the hysteresis loop was found to be decreasing gradually with the increment of either r or bout. On the other hand, the remanent magnetization increased with increment of r but decreased with the increment of bout. The changes were attributed to three parameters mainly: inner curvature, exchange energy and demagnetization energy. The changes in loop area were discussed in light of variation of these three parameters.

  11. Hysteresis in Pressure-Driven DNA Denaturation

    PubMed Central

    Hernández-Lemus, Enrique; Nicasio-Collazo, Luz Adriana; Castañeda-Priego, Ramón

    2012-01-01

    In the past, a great deal of attention has been drawn to thermal driven denaturation processes. In recent years, however, the discovery of stress-induced denaturation, observed at the one-molecule level, has revealed new insights into the complex phenomena involved in the thermo-mechanics of DNA function. Understanding the effect of local pressure variations in DNA stability is thus an appealing topic. Such processes as cellular stress, dehydration, and changes in the ionic strength of the medium could explain local pressure changes that will affect the molecular mechanics of DNA and hence its stability. In this work, a theory that accounts for hysteresis in pressure-driven DNA denaturation is proposed. We here combine an irreversible thermodynamic approach with an equation of state based on the Poisson-Boltzmann cell model. The latter one provides a good description of the osmotic pressure over a wide range of DNA concentrations. The resulting theoretical framework predicts, in general, the process of denaturation and, in particular, hysteresis curves for a DNA sequence in terms of system parameters such as salt concentration, density of DNA molecules and temperature in addition to structural and configurational states of DNA. Furthermore, this formalism can be naturally extended to more complex situations, for example, in cases where the host medium is made up of asymmetric salts or in the description of the (helical-like) charge distribution along the DNA molecule. Moreover, since this study incorporates the effect of pressure through a thermodynamic analysis, much of what is known from temperature-driven experiments will shed light on the pressure-induced melting issue. PMID:22496765

  12. Hysteresis modelling and experimental verification of a Fe–Ga alloy magnetostrictive actuator

    NASA Astrophysics Data System (ADS)

    Wei, Zhu; Lei Xiang, Bian; Gangli, Chen; Shuxin, Liu; Qinbo, Zhou; Xiaoting, Rui

    2017-03-01

    In order to accurately describe the asymmetric rate-bias-dependent hysteresis of a Fe–Ga alloy magnetostrictive actuator, a comprehensive model, which is composed of a phenomenon model, describing hysteresis by the modified Bouc–Wen hysteresis operator, and a theoretical model, representing the dynamics characteristics, is put forward. The experimental system is setup to verify the performance of the comprehensive model. Results show that the modified Bouc–Wen model can effectively describe the dynamics and hysteresis characteristics of the Fe–Ga alloy magnetostrictive actuator. The results highlight significantly improved accuracy in the modelling of the magnetostrictive actuator.

  13. Ocean and atmosphere feedbacks affecting AMOC hysteresis in a GCM

    NASA Astrophysics Data System (ADS)

    Jackson, L. C.; Smith, R. S.; Wood, R. A.

    2016-10-01

    Theories suggest that the Atlantic Meridional Overturning Circulation (AMOC) can exhibit a hysteresis where, for a given input of fresh water into the north Atlantic, there are two possible states: one with a strong overturning in the north Atlantic (on) and the other with a reverse Atlantic cell (off). A previous study showed hysteresis of the AMOC for the first time in a coupled general circulation model (Hawkins et al. in Geophys Res Lett. doi: 10.1029/2011GL047208, 2011). In this study we show that the hysteresis found by Hawkins et al. (2011) is sensitive to the method with which the fresh water input is compensated. If this compensation is applied throughout the volume of the global ocean, rather than at the surface, the region of hysteresis is narrower and the off states are very different: when the compensation is applied at the surface, a strong Pacific overturning cell and a strong Atlantic reverse cell develops; when the compensation is applied throughout the volume there is little change in the Pacific and only a weak Atlantic reverse cell develops. We investigate the mechanisms behind the transitions between the on and off states in the two experiments, and find that the difference in hysteresis is due to the different off states. We find that the development of the Pacific overturning cell results in greater atmospheric moisture transport into the North Atlantic, and also is likely responsible for a stronger Atlantic reverse cell. These both act to stabilize the off state of the Atlantic overturning.

  14. Hysteresis and avalanches in two-dimensional foam rheology simulations

    NASA Astrophysics Data System (ADS)

    Jiang, Yi; Swart, Pieter J.; Saxena, Avadh; Asipauskas, Marius; Glazier, James A.

    1999-05-01

    Foams have unique rheological properties that range from solidlike to fluidlike. We study two-dimensional noncoarsening foams of different disorder under shear in a Monte Carlo simulation, using a driven large-Q Potts model. Simulations of periodic shear on an ordered foam show several different response regimes. At small strain amplitudes, bubbles deform and recover their shapes elastically, and the macroscopic response is that of a linear elastic cellular material. For increasing strain amplitude, the energy-strain curve starts to exhibit hysteresis before any topological rearrangements occur, indicating a macroscopic viscoelastic response. When the applied strain amplitude exceeds a critical value, the yield strain, topological rearrangements occur, the foam starts to flow, and we observe macroscopic irreversibility. We find that the dynamics of topological rearrangements depend sensitively on the structural disorder. Structural disorder decreases the yield strain; sufficiently high disorder changes the macroscopic response of a foam from a viscoelastic solid to a viscoelastic fluid. This wide-ranging dynamical response and the associated history effects of foams result from avalanchelike rearrangement events. The spatiotemporal statistics of rearrangement events do not display long-range correlations for ordered foams or at low shear rates, consistent with experimental observations. As the shear rate or structural disorder increases, the topological events become more correlated and their power spectra change from that of white noise toward 1/f noise. Intriguingly, the power spectra of the total stored energy also exhibit this 1/f trend.

  15. Wetting hysteresis induced by nanodefects.

    PubMed

    Giacomello, Alberto; Schimmele, Lothar; Dietrich, Siegfried

    2016-01-19

    Wetting of actual surfaces involves diverse hysteretic phenomena stemming from ever-present imperfections. Here, we clarify the origin of wetting hysteresis for a liquid front advancing or receding across an isolated defect of nanometric size. Various kinds of chemical and topographical nanodefects, which represent salient features of actual heterogeneous surfaces, are investigated. The most probable wetting path across surface heterogeneities is identified by combining, within an innovative approach, microscopic classical density functional theory and the string method devised for the study of rare events. The computed rugged free-energy landscape demonstrates that hysteresis emerges as a consequence of metastable pinning of the liquid front at the defects; the barriers for thermally activated defect crossing, the pinning force, and hysteresis are quantified and related to the geometry and chemistry of the defects allowing for the occurrence of nanoscopic effects. The main result of our calculations is that even weak nanoscale defects, which are difficult to characterize in generic microfluidic experiments, can be the source of a plethora of hysteretical phenomena, including the pinning of nanobubbles.

  16. Wetting hysteresis induced by nanodefects

    PubMed Central

    Giacomello, Alberto; Schimmele, Lothar; Dietrich, Siegfried

    2016-01-01

    Wetting of actual surfaces involves diverse hysteretic phenomena stemming from ever-present imperfections. Here, we clarify the origin of wetting hysteresis for a liquid front advancing or receding across an isolated defect of nanometric size. Various kinds of chemical and topographical nanodefects, which represent salient features of actual heterogeneous surfaces, are investigated. The most probable wetting path across surface heterogeneities is identified by combining, within an innovative approach, microscopic classical density functional theory and the string method devised for the study of rare events. The computed rugged free-energy landscape demonstrates that hysteresis emerges as a consequence of metastable pinning of the liquid front at the defects; the barriers for thermally activated defect crossing, the pinning force, and hysteresis are quantified and related to the geometry and chemistry of the defects allowing for the occurrence of nanoscopic effects. The main result of our calculations is that even weak nanoscale defects, which are difficult to characterize in generic microfluidic experiments, can be the source of a plethora of hysteretical phenomena, including the pinning of nanobubbles. PMID:26721395

  17. Magnetic hysteresis based on dipolar interactions in granular magnetic systems

    NASA Astrophysics Data System (ADS)

    Allia, Paolo; Coisson, Marco; Knobel, Marcelo; Tiberto, Paola; Vinai, Franco

    1999-11-01

    The magnetic hysteresis of granular magnetic systems is investigated in the high-temperature limit (T>> blocking temperature of magnetic nanoparticles). Measurements of magnetization curves have been performed at room temperature on various samples of granular bimetallic alloys of the family Cu100-xCox (x=5-20 at. %) obtained in ribbon form by planar flow casting in a controlled atmosphere, and submitted to different thermal treatments. The loop amplitude and shape, which are functions of sample composition and thermal history, are studied taking advantage of a novel method of graphical representation, particularly apt to emphasize the features of thin, elongated loops. The hysteresis is explained in terms of the effect of magnetic interactions of the dipolar type among magnetic-metal particles, acting to hinder the response of the system of moments to isothermal changes of the applied field. Such a property is accounted for in a mean-field scheme, by introducing a memory term in the argument of the Langevin function which describes the anhysteretic behavior of an assembly of noninteracting superparamagnetic particles. The rms field arising from the cumulative effect of dipolar interactions is linked by the theory to a measurable quantity, the reduced remanence of a major symmetric hysteresis loop. The theory's self-consistence and adequacy have been properly tested at room temperature on all examined systems. The agreement with experimental results is always striking, indicating that at high temperatures the magnetic hysteresis of granular systems is dominated by interparticle, rather than single-particle, effects. Dipolar interactions seem to fully determine the magnetic hysteresis in the high-temperature limit for low Co content (x<=10). For higher concentrations of magnetic metal, the experimental results indicate that additional hysteretic mechanisms have to be introduced.

  18. Simulation of current-voltage curves for inverted planar structure perovskite solar cells using equivalent circuit model with inductance

    NASA Astrophysics Data System (ADS)

    Cojocaru, Ludmila; Uchida, Satoshi; Jayaweera, Piyankarage V. V.; Kaneko, Shoji; Toyoshima, Yasutake; Nakazaki, Jotaro; Kubo, Takaya; Segawa, Hiroshi

    2017-02-01

    Physical modeling of hysteretic behavior in current-voltage (I-V) curves of perovskite solar cells (PSCs) is necessary for further improving their power conversion efficiencies (PCEs). The reduction of hysteresis in inverted planar structure PSCs (p-PSCs) has been achieved by using a [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) layer. In the cases, the opposite trend of the I-V hysteresis has been observed where the forward scan shows slightly higher efficiency than the reverse scan. In this paper, an equivalent circuit model with inductance is proposed. This model consists of a Schottky diode involving a parasitic inductance focusing PCBM/Al(Ca) interface and accurately represents the opposite trend of the I-V hysteresis of the p-PSC with an inverted structure.

  19. Double hysteresis loop induced by defect dipoles in ferroelectric Pb(Zr{sub 0.8}Ti{sub 0.2})O{sub 3} thin films

    SciTech Connect

    Pu Yunti; Zhu Jiliang; Zhu Xiaohong; Luo Yuansheng; Wang Mingsong; Li Xuhai; Liu Jing; Zhu Jianguo; Xiao Dingquan

    2011-02-15

    Pb(Zr{sub 0.8}Ti{sub 0.2})O{sub 3} (PZT80/20) thin films were deposited on the Pt(111)/Ti/SiO{sub 2}/Si(100) substrates by RF magnetron sputtering. Mainly perovskite crystalline phase with highly (202)-preferred orientation, determined by x-ray diffraction, was formed in the lead zirconate titanate (PZT)(80/20) thin films. Polarization measurements of the unannealed and aged films showed a clear double hysteresis loop. However, the double hysteresis loop phenomenon was greatly suppressed in the PZT thin films annealed under pure oxygen, and thus they exhibited larger remnant polarization (P{sub r} = 6.3 {mu}C/cm{sup 2}). The related mechanism for the appearance of constricted and double hysteresis loops was investigated to be associated with the realignment and disassociation of defect dipoles via oxygen octahedral rotations or oxygen vacancy diffusion. The butterfly-shaped C-V characteristic curve with a valley gave further evidence for double hysteresis loop characteristic in the unannealed and aged PZT thin films.

  20. Thermal hysteresis kinetic effects of spin crossover nanoparticulated systems studied by FORC diagram method on an Ising-like model

    NASA Astrophysics Data System (ADS)

    Atitoaie, Alexandru; Stoleriu, Laurentiu; Tanasa, Radu; Stancu, Alexandru; Enachescu, Cristian

    2016-04-01

    The scientific community is manifesting a high research interest on spin crossover compounds and their recently synthesized nanoparticles, due to their various appealing properties, such as the bistability between a diamagnetic low spin state and a paramagnetic high spin state (HS), inter-switchable by temperature or pressure changes, light irradiation or magnetic field. The utility of these compounds showing hysteresis covers a broad area of applications, from the development of more efficient designs of temperature and pressure sensors to automotive and aeronautic industries and even a new type of molecular actuators. We are proposing in this work a study regarding the kinetic effects and the distribution of reversible and irreversible components on the thermal hysteresis of spin crossover nanoparticulated systems. We are considering here tridimensional systems with different sizes and also systems of nanoparticles with a Gaussian size distribution. The correlations between the kinetics of the thermal hysteresis, the distributions of sizes and intermolecular interactions and the transition temperature distributions were established by using the FORC (First Order Reversal Curves) method using a Monte Carlo technique within an Ising-like system.

  1. Cryotherapy-Induced Persistent Vasoconstriction After Cutaneous Cooling: Hysteresis Between Skin Temperature and Blood Perfusion.

    PubMed

    Khoshnevis, Sepideh; Craik, Natalie K; Matthew Brothers, R; Diller, Kenneth R

    2016-03-01

    The goal of this study was to investigate the persistence of cold-induced vasoconstriction following cessation of active skin-surface cooling. This study demonstrates a hysteresis effect that develops between skin temperature and blood perfusion during the cooling and subsequent rewarming period. An Arctic Ice cryotherapy unit (CTU) was applied to the knee region of six healthy subjects for 60 min of active cooling followed by 120 min of passive rewarming. Multiple laser Doppler flowmetry perfusion probes were used to measure skin blood flow (expressed as cutaneous vascular conductance (CVC)). Skin surface cooling produced a significant reduction in CVC (P < 0.001) that persisted throughout the duration of the rewarming period. In addition, there was a hysteresis effect between CVC and skin temperature during the cooling and subsequent rewarming cycle (P < 0.01). Mixed model regression (MMR) showed a significant difference in the slopes of the CVC-skin temperature curves during cooling and rewarming (P < 0.001). Piecewise regression was used to investigate the temperature thresholds for acceleration of CVC during the cooling and rewarming periods. The two thresholds were shown to be significantly different (P = 0.003). The results show that localized cooling causes significant vasoconstriction that continues beyond the active cooling period despite skin temperatures returning toward baseline values. The significant and persistent reduction in skin perfusion may contribute to nonfreezing cold injury (NFCI) associated with cryotherapy.

  2. Cryotherapy-Induced Persistent Vasoconstriction After Cutaneous Cooling: Hysteresis Between Skin Temperature and Blood Perfusion

    PubMed Central

    Khoshnevis, Sepideh; Craik, Natalie K.; Matthew Brothers, R.; Diller, Kenneth R.

    2016-01-01

    The goal of this study was to investigate the persistence of cold-induced vasoconstriction following cessation of active skin-surface cooling. This study demonstrates a hysteresis effect that develops between skin temperature and blood perfusion during the cooling and subsequent rewarming period. An Arctic Ice cryotherapy unit (CTU) was applied to the knee region of six healthy subjects for 60 min of active cooling followed by 120 min of passive rewarming. Multiple laser Doppler flowmetry perfusion probes were used to measure skin blood flow (expressed as cutaneous vascular conductance (CVC)). Skin surface cooling produced a significant reduction in CVC (P < 0.001) that persisted throughout the duration of the rewarming period. In addition, there was a hysteresis effect between CVC and skin temperature during the cooling and subsequent rewarming cycle (P < 0.01). Mixed model regression (MMR) showed a significant difference in the slopes of the CVC–skin temperature curves during cooling and rewarming (P < 0.001). Piecewise regression was used to investigate the temperature thresholds for acceleration of CVC during the cooling and rewarming periods. The two thresholds were shown to be significantly different (P = 0.003). The results show that localized cooling causes significant vasoconstriction that continues beyond the active cooling period despite skin temperatures returning toward baseline values. The significant and persistent reduction in skin perfusion may contribute to nonfreezing cold injury (NFCI) associated with cryotherapy. PMID:26632263

  3. Hysteresis and compensation behaviors of spin-3/2 cylindrical Ising nanotube system

    SciTech Connect

    Kocakaplan, Yusuf; Keskin, Mustafa

    2014-09-07

    The hysteresis and compensation behaviors of the spin-3/2 cylindrical Ising nanotube system are studied within the framework of the effective-field theory with correlations. The effects of the Hamiltonian parameters are investigated on the magnetic and thermodynamic quantities, such as the total magnetization, hysteresis curves, and compensation behaviors of the system. Depending on the Hamiltonian parameters, some characteristic hysteresis behaviors are found, such as the existence of double and triple hysteresis loops. According to Néel classification nomenclature, the system displays Q-, R-, P-, N-, M-, and S- types of compensation behaviors for the appropriate values of the system parameters. We also compare our results with some recently published theoretical and experimental works and find a qualitatively good agreement.

  4. Modeling contact angle hysteresis on chemically patterned and superhydrophobic surfaces.

    PubMed

    Kusumaatmaja, H; Yeomans, J M

    2007-05-22

    We investigate contact angle hysteresis on chemically patterned and superhydrophobic surfaces, as the drop volume is quasistatically increased and decreased. We consider both two (cylindrical drops) and three (spherical drops) dimensions using analytical and numerical approaches to minimize the free energy of the drop. In two dimensions, we find, in agreement with other authors, a slip, jump, stick motion of the contact line. In three dimensions, this behavior persists, but the position and magnitude of the contact line jumps are sensitive to the details of the surface patterning. In two dimensions, we identify analytically the advancing and receding contact angles on the different surfaces, and we use numerical insights to argue that these provide bounds for the three-dimensional cases. We present explicit simulations to show that a simple average over the disorder is not sufficient to predict the details of the contact angle hysteresis and to support an explanation for the low contact angle hysteresis of suspended drops on superhydrophobic surfaces.

  5. Completely inverted hysteresis loops: Inhomogeneity effects or experimental artifacts

    SciTech Connect

    Song, C. Cui, B.; Pan, F.; Yu, H. Y.

    2013-11-14

    Completely inverted hysteresis loops (IHL) are obtained by the superconducting quantum interference device with large cooling fields (>10 kOe) in (La,Sr)MnO{sub 3} films with self-assembled LaSrMnO{sub 4}, an antiferromagnetic interface. Although the behaviours of measured loops show many features characteristic to the IHL, its origin, however, is not due to the exchange coupling between (La,Sr)MnO{sub 3}/LaSrMnO{sub 4}, an often accepted view on IHL. Instead, we demonstrate that the negative remanence arises from the hysteresis of superconducting coils, which drops abruptly when lower cooling fields are utilized. Hence the completely inverted hysteresis loops are experimental artifacts rather than previously proposed inhomogeneity effects in complicated materials.

  6. Persistent hysteresis in graphene-mica van der Waals heterostructures.

    PubMed

    Mohrmann, Jens; Watanabe, Kenji; Taniguchi, Takashi; Danneau, Romain

    2015-01-09

    We report the study of electronic transport in graphene-mica van der Waals heterostructures. We have designed various graphene field-effect devices in which mica is utilized as a substrate and/or gate dielectric. When mica is used as a gate dielectric we observe a very strong positive gate voltage hysteresis of the resistance, which persists in samples that were prepared in a controlled atmosphere down to even millikelvin temperatures. In a double-gated mica-graphene-hBN van der Waals heterostructure, we found that while a strong hysteresis occurred when mica was used as a substrate/gate dielectric, the same graphene sheet on mica substrate no longer showed hysteresis when the charge carrier density was tuned through a second gate with the hBN dielectric. While this hysteretic behavior could be useful for memory devices, our findings confirm that the environment during sample preparation has to be controlled strictly.

  7. HYSTERESIS BETWEEN DISTINCT MODES OF TURBULENT DYNAMOS

    SciTech Connect

    Karak, Bidya Binay; Brandenburg, Axel; Kitchatinov, Leonid L.

    2015-04-20

    Nonlinear mean-field models of the solar dynamo show long-term variability, which may be relevant to different states of activity inferred from long-term radiocarbon data. This paper is aimed at probing the dynamo hysteresis predicted by the recent mean-field models of Kitchatinov and Olemskoy with direct numerical simulations. We perform three-dimensional (3D) simulations of large-scale dynamos in a shearing box with helically forced turbulence. As an initial condition, we either take a weak random magnetic field or we start from a snapshot of an earlier simulation. Two quasi-stable states are found to coexist in a certain range of parameters close to the onset of the large-scale dynamo. The simulations converge to one of these states depending on the initial conditions. When either the fractional helicity or the magnetic Prandtl number is increased between successive runs above the critical value for onset of the dynamo, the field strength jumps to a finite value. However, when the fractional helicity or the magnetic Prandtl number is then decreased again, the field strength stays at a similar value (strong field branch) even below the original onset. We also observe intermittent decaying phases away from the strong field branch close to the point where large-scale dynamo action is just possible. The dynamo hysteresis seen previously in mean-field models is thus reproduced by 3D simulations. Its possible relation to distinct modes of solar activity such as grand minima is discussed.

  8. Modeling Anomalous Hysteresis in Perovskite Solar Cells.

    PubMed

    van Reenen, Stephan; Kemerink, Martijn; Snaith, Henry J

    2015-10-01

    Organic-inorganic lead halide perovskites are distinct from most other semiconductors because they exhibit characteristics of both electronic and ionic motion. Accurate understanding of the optoelectronic impact of such properties is important to fully optimize devices and be aware of any limitations of perovskite solar cells and broader optoelectronic devices. Here we use a numerical drift-diffusion model to describe device operation of perovskite solar cells. To achieve hysteresis in the modeled current-voltage characteristics, we must include both ion migration and electronic charge traps, serving as recombination centers. Trapped electronic charges recombine with oppositely charged free electronic carriers, of which the density depends on the bias-dependent ion distribution in the perovskite. Our results therefore show that reduction of either the density of mobile ionic species or carrier trapping at the perovskite interface will remove the adverse hysteresis in perovskite solar cells. This gives a clear target for ongoing research effort and unifies previously conflicting experimental observations and theories.

  9. Hysteresis and the Dynamic Elasticity of Consolidated Granular Materials

    SciTech Connect

    Guyer, R.A.; TenCate, J.; Johnson, P.

    1999-04-01

    Quasistatic elasticity measurements on rocks show them to be strikingly nonlinear and to have elastic hysteresis with end point memory. When the model for this quasistatic elasticity is extended to the description of nonlinear dynamic elasticity the elastic elements responsible for the hysteresis dominate the behavior. Consequently, in a resonant bar, driven to nonlinearity, the frequency shift and the attenuation are predicted to be nonanalytic functions of the strain field. A resonant bar experiment yielding results in substantial qualitative and quantitative accord with these predictions is reported. {copyright} {ital 1999} {ital The American Physical Society }

  10. Semiempirical model of soil water hysteresis

    USGS Publications Warehouse

    Nimmo, J.R.

    1992-01-01

    In order to represent hysteretic soil water retention curves accurately using as few measurements as possible, a new semiempirical model has been developed. It has two postulates related to physical characteristics of the medium, and two parameters, each with a definite physical interpretation, whose values are determined empirically for a given porous medium. Tests of the model show that it provides high-quality optimized fits to measured water content vs. matric pressure wetting curves for a wide variety of media. A practical use of this model is to provide a complete simulated main wetting curve for a medium where only a main drying curve and two points on the wetting curve have been measured. -from Author

  11. Correlation between piezoresponse nonlinearity and hysteresis in ferroelectric crystals at nanoscale

    SciTech Connect

    Kalinin, Sergei V.; Jesse, Stephen; Yang, Yaodong; Li, Linglong; Liu, Zhengchun; Vasudevan, Rama K.

    2016-04-27

    Here, the nonlinear response of a ferroic to external fields has been studied for decades, garnering interest for both understanding fundamental physics, as well as technological applications such as memory devices. Yet, the behavior of ferroelectrics at mesoscopic regimes remains poorly understood, and the scale limits of theories developed for macroscopic regimes are not well tested experimentally. Here, we test the link between piezo-nonlinearity and local piezoelectric strain hysteresis, via AC-field dependent measurements in conjunction with first order reversal curve (FORC) measurements on (K,Na)NbO3 crystals with band-excitation piezoelectric force microscopy. The correlation coefficient between nonlinearity amplitude and the FORC of the polarization switching shows a clear decrease in correlation with increasing AC bias, suggesting the impact of domain wall clamping on the DC measurement case. Further, correlation of polynomial fitting terms from the nonlinear measurements with the hysteresis loop area reveals that the largest correlations are reserved for the quadratic terms, which is expected for irreversible domain wall motion contributions that impact both piezoelectric behavior as well as minor loop formation. These confirm the link between local piezoelectric nonlinearity, domain wall motion and minor loop formation, and suggest that existing theories (such as Preisach) are applicable at these length scales, with associated implications for future nanoscale devices.

  12. Correlation between piezoresponse nonlinearity and hysteresis in ferroelectric crystals at nanoscale

    DOE PAGES

    Kalinin, Sergei V.; Jesse, Stephen; Yang, Yaodong; ...

    2016-04-27

    Here, the nonlinear response of a ferroic to external fields has been studied for decades, garnering interest for both understanding fundamental physics, as well as technological applications such as memory devices. Yet, the behavior of ferroelectrics at mesoscopic regimes remains poorly understood, and the scale limits of theories developed for macroscopic regimes are not well tested experimentally. Here, we test the link between piezo-nonlinearity and local piezoelectric strain hysteresis, via AC-field dependent measurements in conjunction with first order reversal curve (FORC) measurements on (K,Na)NbO3 crystals with band-excitation piezoelectric force microscopy. The correlation coefficient between nonlinearity amplitude and the FORC ofmore » the polarization switching shows a clear decrease in correlation with increasing AC bias, suggesting the impact of domain wall clamping on the DC measurement case. Further, correlation of polynomial fitting terms from the nonlinear measurements with the hysteresis loop area reveals that the largest correlations are reserved for the quadratic terms, which is expected for irreversible domain wall motion contributions that impact both piezoelectric behavior as well as minor loop formation. These confirm the link between local piezoelectric nonlinearity, domain wall motion and minor loop formation, and suggest that existing theories (such as Preisach) are applicable at these length scales, with associated implications for future nanoscale devices.« less

  13. Hydrophobic drying and hysteresis at different length scales by molecular dynamics simulations.

    PubMed

    Lei, Yajie; Leng, Yongsheng

    2012-02-14

    We performed molecular dynamics simulations to investigate hydrophobic interactions between two parallel hydrophobic plates immersed in water. The two plates are separated by a distance D ranging from contact to a few nanometers. To mimic the attractive hydrophobic force measurement in a surface force experiment, a driving spring is used to measure the hydrophobic force between two hydrophobic plates. The force-distance curves, in particular the force variations from spontaneous drying to hydrophobic collapse are obtained. These details are usually not accessible in the surface force measurement due to the unstable jump into contact. The length-scale effect on the hydrophobic drying during normal approach and the hydrophobic hysteresis during retraction has been studied. We find that the critical distance at which a spontaneous drying occurs is determined by the shorter characteristic dimension of the plate, whereas the hydrophobic hysteresis is determined by the longer characteristic dimension of the plate. The variations of the potential of mean force versus separation during approach and retraction are also calculated. The results show that water confined between two parallel hydrophobic plates is in a thermodynamic metastable state. This comparably high energy state leads to the spontaneous drying at some critical distance.

  14. Applications of a theory of ferromagnetic hysteresis

    SciTech Connect

    Hodgdon, M.L.

    1988-01-01

    The differential equation B = ..cap alpha../vertical/ bar H /vertical bar/(f(H) - B) + Hg(H) and a set of restrictions on the material functions f and g yield a theory of rate independent hyseresis for isoperm ferromagnetic materials. A modification based on exchanging the positions of B and H in the differential equation and on allowing for the dependence of the material functions on H extends the theory to rate dependent, nonisoperm materials. The theory and its extension exhibit all of the important features of ferromagnetic hysteresis, including the existence and stability of minor loops. Both are well suited for use in numerical field solving codes. Examples in which the material functions are simple combinations of analytic functions are presented here for MnZn ferrite, NiZn ferrite, NiFe tape, and CoCr thin film. Also presented is a procedure for constructing a two dimensional vector model that yields bell-shaped and M-shaped curves for graphs of the angular variation of the coercive field.

  15. Hidden hysteresis – population dynamics can obscure gene network dynamics

    PubMed Central

    2013-01-01

    Background Positive feedback is a common motif in gene regulatory networks. It can be used in synthetic networks as an amplifier to increase the level of gene expression, as well as a nonlinear module to create bistable gene networks that display hysteresis in response to a given stimulus. Using a synthetic positive feedback-based tetracycline sensor in E. coli, we show that the population dynamics of a cell culture has a profound effect on the observed hysteretic response of a population of cells with this synthetic gene circuit. Results The amount of observable hysteresis in a cell culture harboring the gene circuit depended on the initial concentration of cells within the culture. The magnitude of the hysteresis observed was inversely related to the dilution procedure used to inoculate the subcultures; the higher the dilution of the cell culture, lower was the observed hysteresis of that culture at steady state. Although the behavior of the gene circuit in individual cells did not change significantly in the different subcultures, the proportion of cells exhibiting high levels of steady-state gene expression did change. Although the interrelated kinetics of gene expression and cell growth are unpredictable at first sight, we were able to resolve the surprising dilution-dependent hysteresis as a result of two interrelated phenomena - the stochastic switching between the ON and OFF phenotypes that led to the cumulative failure of the gene circuit over time, and the nonlinear, logistic growth of the cell in the batch culture. Conclusions These findings reinforce the fact that population dynamics cannot be ignored in analyzing the dynamics of gene networks. Indeed population dynamics may play a significant role in the manifestation of bistability and hysteresis, and is an important consideration when designing synthetic gene circuits intended for long-term application. PMID:23800122

  16. Longitudinal data analysis of polymorphisms in the κ-casein and β-lactoglobulin genes shows differential effects along the trajectory of the lactation curve in tropical dairy goats.

    PubMed

    Cardona, Samir Julián Calvo; Cadavid, Henry Cardona; Corrales, Juan David; Munilla, Sebastián; Cantet, Rodolfo J C; Rogberg-Muñoz, Andrés

    2016-09-01

    The κ-casein (CSN-3) and β-lactoglobulin (BLG) genes are extensively polymorphic in ruminants. Several association studies have estimated the effects of polymorphisms in these genes on milk yield, milk composition, and cheese-manufacturing properties. Usually, these results are based on production integrated over the lactation curve or on cross-sectional studies at specific days in milk (DIM). However, as differential expression of milk protein genes occurs over lactation, the effect of the polymorphisms may change over time. In this study, we fitted a mixed-effects regression model to test-day records of milk yield and milk quality traits (fat, protein, and total solids yields) from Colombian tropical dairy goats. We used the well-characterized A/B polymorphisms in the CSN-3 and BLG genes. We argued that this approach provided more efficient estimators than cross-sectional designs, given the same number and pattern of observations, and allowed exclusion of between-subject variation from model error. The BLG genotype AA showed a greater performance than the BB genotype for all traits along the whole lactation curve, whereas the heterozygote showed an intermediate performance. We observed no such constant pattern for the CSN-3 gene between the AA homozygote and the heterozygote (the BB genotype was absent from the sample). The differences among the genotypic effects of the BLG and the CSN-3 polymorphisms were statistically significant during peak and mid lactation (around 40-160 DIM) for the BLG gene and only for mid lactation (80-145 DIM) for the CSN-3 gene. We also estimated the additive and dominant effects of the BLG locus. The locus showed a statistically significant additive behavior along the whole lactation trajectory for all quality traits, whereas for milk yield the effect was not significant at later stages. In turn, we detected a statistically significant dominance effect only for fat yield in the early and peak stages of lactation (at about 1-45 DIM

  17. Hysteresis in the phase transition of chocolate

    NASA Astrophysics Data System (ADS)

    Ren, Ruilong; Lu, Qunfeng; Lin, Sihua; Dong, Xiaoyan; Fu, Hao; Wu, Shaoyi; Wu, Minghe; Teng, Baohua

    2016-01-01

    We designed an experiment to reproduce the hysteresis phenomenon of chocolate appearing in the heating and cooling process, and then established a model to relate the solidification degree to the order parameter. Based on the Landau-Devonshire theory, our model gave a description of the hysteresis phenomenon in chocolate, which lays the foundations for the study of the phase transition behavior of chocolate.

  18. Hysteresis rarefaction in the Riemann problem

    NASA Astrophysics Data System (ADS)

    Krejčí, P.

    2008-11-01

    We consider the wave equation with Preisach hysteresis and Riemann initial data as a model for wave propagation in hysteretic (e.g. elastoplastic) media. The main result consists in proving that in the convex hysteresis loop domain, there exists a unique self-similar locally Lipschitz continuous solution. In other words, smooth rarefaction waves propagate in both directions from the initial jump discontinuity.

  19. High-speed tracking control of piezoelectric actuators using an ellipse-based hysteresis model.

    PubMed

    Gu, Guoying; Zhu, Limin

    2010-08-01

    In this paper, an ellipse-based mathematic model is developed to characterize the rate-dependent hysteresis in piezoelectric actuators. Based on the proposed model, an expanded input space is constructed to describe the multivalued hysteresis function H[u](t) by a multiple input single output (MISO) mapping Gamma:R(2)-->R. Subsequently, the inverse MISO mapping Gamma(-1)(H[u](t),H[u](t);u(t)) is proposed for real-time hysteresis compensation. In controller design, a hybrid control strategy combining a model-based feedforward controller and a proportional integral differential (PID) feedback loop is used for high-accuracy and high-speed tracking control of piezoelectric actuators. The real-time feedforward controller is developed to cancel the rate-dependent hysteresis based on the inverse hysteresis model, while the PID controller is used to compensate for the creep, modeling errors, and parameter uncertainties. Finally, experiments with and without hysteresis compensation are conducted and the experimental results are compared. The experimental results show that the hysteresis compensation in the feedforward path can reduce the hysteresis-caused error by up to 88% and the tracking performance of the hybrid controller is greatly improved in high-speed tracking control applications, e.g., the root-mean-square tracking error is reduced to only 0.34% of the displacement range under the input frequency of 100 Hz.

  20. Three-Phase Capillary Pressure, Hysteresis and Trapping in a Porous Glass-Bead Column

    NASA Astrophysics Data System (ADS)

    Andersson, L.; Schlüter, S.; Li, T.; Brown, K. I.; Helland, J. O.; Wildenschild, D.

    2015-12-01

    Enhanced oil recovery (EOR) strategies employing water-alternate-gas (WAG) injections may improve oil mobility and production recovery. WAG injections for EOR create regions in the reservoir with simultaneous flow of oil, water and air dominated by capillary and gravity forces. As a result of the dynamics in the transition zones, the invading fluid may snap off compartments of the displaced fluid which could then be trapped in the pore space, contributing to the hysteresis of the three-phase capillary pressure curves. Three-phase capillary pressure curves are needed to model the three-phase transition zone movements in the reservoir. In reservoir simulation models, the common practice has been to implement three-phase capillary pressure curves based on two-phase gas-oil and oil-water capillary pressure data. However, experimental and modelling studies of three-phase fluid distributions at the pore scale have shown that this procedure is not always valid; three-phase capillary pressure curves exhibit hysteresis and depend on the saturation history of the three phases which cannot be derived from two-phase capillary pressure curves. We have developed three-phase experiments that provide capillary pressures and 3D-image data of fluid distributions in the entire saturation space of oil, water and air in water-wet porous glass-bead columns; a time-consuming and technically challenging exercise. The 3D data with a resolution of 6.38 μm were derived from high-resolution synchrotron x-ray computed micro-tomography (CMT), collected at the GSECARS beam line 13-BM-D at the Advanced Photon Source, Argonne National Laboratory. In particular, we discuss how three-phase pore-scale mechanisms, such as oil layer existence and multiple displacement events, affect the mobility and trapping of oil in the porous medium. We also show that wettability-alterations of the porous medium in contact with the three-phase fluid system and exposure to x-rays can be avoided by using iodine

  1. Inducing vortex formation in multilayered circular dots using remanent curves

    NASA Astrophysics Data System (ADS)

    Kim, Dong-Ok; Ryeol Lee, Dong; Choi, Yongseong; Metlushko, Vitali; Park, Jihwey; Kim, Jae-Young; Bong Lee, Ki

    2012-11-01

    We report field manipulation of magnetic vortex states in Co(30 nm)/Cu(3 nm)/Ni80Fe20 (20 nm)-multilayer dot arrays via remanent curve. The element-resolved resonant x-ray magnetic measurements, combined with micromagnetic simulations, show vortex formation in the Co layer but not in the NiFe layer along the major hysteresis loop. Although the two magnetic layers are not directly coupled due to the presence of the Cu interlayer, the NiFe layer is strongly influenced by the dipolar field from uncompensated magnetic poles in the Co layer. Using remanent curves, we demonstrate that the single vortex state can be induced simultaneously in both layers.

  2. Mathematical modelling of frequency-dependent hysteresis and energy loss of FeBSiC amorphous alloy

    NASA Astrophysics Data System (ADS)

    Koprivica, Branko; Milovanovic, Alenka; Mitrovic, Nebojsa

    2017-01-01

    The aim of this paper is to present a novel mathematical model of frequency-dependent magnetic hysteresis. The major hysteresis loop in this model is represented by the ascending and descending curve over an arctangent function. The parameters of the hysteresis model have been calculated from a measured hysteresis loop of the FeBSiC amorphous alloy sample. A number of measurements have been performed with this sample at different frequencies of the sinusoidal excitation magnetic field. A variation of the coercive magnetic field with the frequency has been observed and used in the modelling of frequency-dependent hysteresis with the proposed model. A comparison between measured and modelled hysteresis loops has been presented. Additionally, the areas of the obtained hysteresis loops, representing the energy loss per unit volume, have been calculated and the dependence of the energy loss on the frequency is shown. Furthermore, two models of the frequency dependence of the coercivity and two models of the energy loss separation have been used for fitting the experimental and simulation results. The relations between these models and their parameters have been observed and analysed. Also, the relations between parameters of the hysteresis model and the parameters of the energy loss separation models have been analysed and discussed.

  3. Assessing temporal variations in connectivity through suspended sediment hysteresis analysis

    NASA Astrophysics Data System (ADS)

    Sherriff, Sophie; Rowan, John; Fenton, Owen; Jordan, Phil; Melland, Alice; Mellander, Per-Erik; hUallacháin, Daire Ó.

    2016-04-01

    Connectivity provides a valuable concept for understanding catchment-scale sediment dynamics. In intensive agricultural catchments, land management through tillage, high livestock densities and extensive land drainage practices significantly change hydromorphological behaviour and alter sediment supply and downstream delivery. Analysis of suspended sediment-discharge hysteresis has offered insights into sediment dynamics but typically on a limited selection of events. Greater availability of continuous high-resolution discharge and turbidity data and qualitative hysteresis metrics enables assessment of sediment dynamics during more events and over time. This paper assesses the utility of this approach to explore seasonal variations in connectivity. Data were collected from three small (c. 10 km2) intensive agricultural catchments in Ireland with contrasting morphologies, soil types, land use patterns and management practices, and are broadly defined as low-permeability supporting grassland, moderate-permeability supporting arable and high-permeability supporting arable. Suspended sediment concentration (using calibrated turbidity measurements) and discharge data were collected at 10-min resolution from each catchment outlet and precipitation data were collected from a weather station within each catchment. Event databases (67-90 events per catchment) collated information on sediment export metrics, hysteresis category (e.g., clockwise, anti-clockwise, no hysteresis), numeric hysteresis index, and potential hydro-meteorological controls on sediment transport including precipitation amount, duration, intensity, stream flow and antecedent soil moisture and rainfall. Statistical analysis of potential controls on sediment export was undertaken using Pearson's correlation coefficient on separate hysteresis categories in each catchment. Sediment hysteresis fluctuations through time were subsequently assessed using the hysteresis index. Results showed the numeric

  4. Direct hysteresis measurements on ferroelectret films by means of a modified Sawyer-Tower circuit

    NASA Astrophysics Data System (ADS)

    Qiu, Xunlin; Holländer, Lars; Wirges, Werner; Gerhard, Reimund; Cury Basso, Heitor

    2013-06-01

    Ferro- and piezo-electrets are non-polar polymer foams or film systems with internally charged cavities. Since their invention more than two decades ago, ferroelectrets have become a welcome addition to the range of piezo-, pyro-, and ferro-electric materials available for device applications. A polarization-versus-electric-field hysteresis is an essential feature of a ferroelectric material and may also be used for determining some of its main properties. Here, a modified Sawyer-Tower circuit and a combination of unipolar and bipolar voltage waveforms are employed to record hysteresis curves on cellular-foam polypropylene ferroelectret films and on tubular-channel fluoroethylenepropylene copolymer ferroelectret film systems. Internal dielectric barrier discharges (DBDs) are required for depositing the internal charges in ferroelectrets. The true amount of charge transferred during the internal DBDs is obtained from voltage measurements on a standard capacitor connected in series with the sample, but with a much larger capacitance than the sample. Another standard capacitor with a much smaller capacitance—which is, however, still considerably larger than the sample capacitance—is also connected in series as a high-voltage divider protecting the electrometer against destructive breakdown. It is shown how the DBDs inside the polymer cavities lead to phenomenological hysteresis curves that cannot be distinguished from the hysteresis loops found on other ferroic materials. The physical mechanisms behind the hysteresis behavior are described and discussed.

  5. Limestones distinguished by magnetic hysteresis in three-dimensional projections

    NASA Astrophysics Data System (ADS)

    Borradaile, G. J.; Hamilton, Tom

    2003-09-01

    Magnetic hysteresis data determine the suitability of rocks for paleomagnetic work, provide clues to paleo-environment and paleo-climate and they may characterize depositional environments for limestones. However, the variables chosen for conventional two-dimensional hysteresis plots, such as that of Day et al. [1977], are not always suitable to discriminate between samples. Distinguishing samples by their regression surfaces in 3D hysteresis space may be more successful in some cases [Borradaile and Lagroix, 2000] but a 2D projection with a less arbitrary viewing axis is preferable for routine reporting. We show that limestone samples are simply discriminated in a new 2D projection produced by projecting hysteresis data from three dimensions (x, y, z = Mr/Ms, Bcr, Bc) onto a plane containing the Mr/Ms axis. The orientation of the plane is controlled by its x-axis that is defined by a suitably selected Bcr/Bc ratio, most often in the magnetite PSD range, 2< (Bcr/Bc) < 4.

  6. Contact angle hysteresis on superhydrophobic stripes.

    PubMed

    Dubov, Alexander L; Mourran, Ahmed; Möller, Martin; Vinogradova, Olga I

    2014-08-21

    We study experimentally and discuss quantitatively the contact angle hysteresis on striped superhydrophobic surfaces as a function of a solid fraction, ϕS. It is shown that the receding regime is determined by a longitudinal sliding motion of the deformed contact line. Despite an anisotropy of the texture the receding contact angle remains isotropic, i.e., is practically the same in the longitudinal and transverse directions. The cosine of the receding angle grows nonlinearly with ϕS. To interpret this we develop a theoretical model, which shows that the value of the receding angle depends both on weak defects at smooth solid areas and on the strong defects due to the elastic energy of the deformed contact line, which scales as ϕS(2)lnϕS. The advancing contact angle was found to be anisotropic, except in a dilute regime, and its value is shown to be determined by the rolling motion of the drop. The cosine of the longitudinal advancing angle depends linearly on ϕS, but a satisfactory fit to the data can only be provided if we generalize the Cassie equation to account for weak defects. The cosine of the transverse advancing angle is much smaller and is maximized at ϕS ≃ 0.5. An explanation of its value can be obtained if we invoke an additional energy due to strong defects in this direction, which is shown to be caused by the adhesion of the drop on solid sectors and is proportional to ϕS(2). Finally, the contact angle hysteresis is found to be quite large and generally anisotropic, but it becomes isotropic when ϕS ≤ 0.2.

  7. Hysteresis of unsaturated hydromechanical properties of a silty soil

    USGS Publications Warehouse

    Lu, Ning; Kaya, Murat; Collins, Brian D.; Godt, Jonathan W.

    2013-01-01

    Laboratory tests to examine hysteresis in the hydrologic and mechanical properties of partially saturated soils were conducted on six intact specimens collected from a landslide-prone area of Alameda County, California. The results reveal that the pore-size distribution parameter remains statistically unchanged between the wetting and drying paths; however, the wetting or drying state has a pronounced influence on the water-entry pressure, the water-filled porosity at zero suction, and the saturated hydraulic conductivity. The suction stress values obtained from the shear-strength tests under both natural moisture and resaturated conditions were mostly bounded by the suction stress characteristic curves (SSCCs) obtained from the hydrologic tests. This finding experimentally confirms that the soil-water retention curve, hydraulic conductivity function, and SSCC are intrinsically related.

  8. The capillary hysteresis model HYSTR: User`s guide

    SciTech Connect

    Niemi, A.; Bodvarsson, G.S.

    1991-11-01

    The potential disposal of nuclear waste in the unsaturated zone at Yucca Mountain, Nevada, has generated increased interest in the study of fluid flow through unsaturated media. In the near future, large-scale field tests will be conducted at the Yucca Mountain site, and work is now being done to design and analyze these tests. As part of these efforts a capillary hysteresis model has been developed. A computer program to calculate the hysteretic relationship between capillary pressure {phi} and liquid saturation (S{sub 1}) has been written that is designed to be easily incorporated into any numerical unsaturated flow simulator that computes capillary pressure as a function of liquid saturation. This report gives a detailed description of the model along with information on how it can be interfaced with a transport code. Although the model was developed specifically for calculations related to nuclear waste disposal, it should be applicable to any capillary hysteresis problem for which the secondary and higher order scanning curves can be approximated from the first order scanning curves. HYSTR is a set of subroutines to calculate capillary pressure for a given liquid saturation under hysteretic conditions.

  9. Synthesis and characterization of 1D iron(II) spin crossover coordination polymers with hysteresis.

    PubMed

    Bauer, Wolfgang; Lochenie, Charles; Weber, Birgit

    2014-02-07

    Purposeful ligand design was used for the synthesis of eight new 1D iron(II) spin crossover coordination polymers aiming for cooperative spin transitions with hysteresis. The results from magnetic measurements and X-ray structure analysis show that the combination of rigid linkers and a hydrogen bond network between the 1D chains is a promising tool to reach this goal. Five of the eight new samples show a cooperative spin transition with hysteresis with up to 43 K wide hysteresis loops.

  10. A connectivity-based modeling approach for representing hysteresis in macroscopic two-phase flow properties

    SciTech Connect

    Cihan, Abdullah; Birkholzer, Jens; Trevisan, Luca; Bianchi, Marco; Zhou, Quanlin; Illangasekare, Tissa

    2014-12-31

    During CO2 injection and storage in deep reservoirs, the injected CO2 enters into an initially brine saturated porous medium, and after the injection stops, natural groundwater flow eventually displaces the injected mobile-phase CO2, leaving behind residual non-wetting fluid. Accurate modeling of two-phase flow processes are needed for predicting fate and transport of injected CO2, evaluating environmental risks and designing more effective storage schemes. The entrapped non-wetting fluid saturation is typically a function of the spatially varying maximum saturation at the end of injection. At the pore-scale, distribution of void sizes and connectivity of void space play a major role for the macroscopic hysteresis behavior and capillary entrapment of wetting and non-wetting fluids. This paper presents development of an approach based on the connectivity of void space for modeling hysteretic capillary pressure-saturation-relative permeability relationships. The new approach uses void-size distribution and a measure of void space connectivity to compute the hysteretic constitutive functions and to predict entrapped fluid phase saturations. Two functions, the drainage connectivity function and the wetting connectivity function, are introduced to characterize connectivity of fluids in void space during drainage and wetting processes. These functions can be estimated through pore-scale simulations in computer-generated porous media or from traditional experimental measurements of primary drainage and main wetting curves. The hysteresis model for saturation-capillary pressure is tested successfully by comparing the model-predicted residual saturation and scanning curves with actual data sets obtained from column experiments found in the literature. A numerical two-phase model simulator with the new hysteresis functions is tested against laboratory experiments conducted in a quasi-two-dimensional flow cell (91.4cm×5.6cm×61cm

  11. A connectivity-based modeling approach for representing hysteresis in macroscopic two-phase flow properties

    DOE PAGES

    Cihan, Abdullah; Birkholzer, Jens; Trevisan, Luca; ...

    2014-12-31

    During CO2 injection and storage in deep reservoirs, the injected CO2 enters into an initially brine saturated porous medium, and after the injection stops, natural groundwater flow eventually displaces the injected mobile-phase CO2, leaving behind residual non-wetting fluid. Accurate modeling of two-phase flow processes are needed for predicting fate and transport of injected CO2, evaluating environmental risks and designing more effective storage schemes. The entrapped non-wetting fluid saturation is typically a function of the spatially varying maximum saturation at the end of injection. At the pore-scale, distribution of void sizes and connectivity of void space play a major role formore » the macroscopic hysteresis behavior and capillary entrapment of wetting and non-wetting fluids. This paper presents development of an approach based on the connectivity of void space for modeling hysteretic capillary pressure-saturation-relative permeability relationships. The new approach uses void-size distribution and a measure of void space connectivity to compute the hysteretic constitutive functions and to predict entrapped fluid phase saturations. Two functions, the drainage connectivity function and the wetting connectivity function, are introduced to characterize connectivity of fluids in void space during drainage and wetting processes. These functions can be estimated through pore-scale simulations in computer-generated porous media or from traditional experimental measurements of primary drainage and main wetting curves. The hysteresis model for saturation-capillary pressure is tested successfully by comparing the model-predicted residual saturation and scanning curves with actual data sets obtained from column experiments found in the literature. A numerical two-phase model simulator with the new hysteresis functions is tested against laboratory experiments conducted in a quasi-two-dimensional flow cell (91.4cm×5.6cm×61cm), packed with homogeneous and

  12. Allowing for hysteresis in the calculation of fields in the elements of accelerator magnetic systems

    NASA Astrophysics Data System (ADS)

    Vinokurov, N. A.; Shevchenko, O. A.; Serednyakov, S. S.; Shcheglov, M. A.; Royak, M. E.; Stupakov, I. M.; Kondratyeva, N. S.

    2016-07-01

    Iron magnetic circuit residual magnetization may contribute as much as several Gs to the magnetic field in charged-particle accelerators. This contribution depends on the magnetization "history." It is not taken into account in most of the existing software that uses the main magnetization curve. Therefore, an error in field calculations usually exceeds 1%, which is unacceptable for accelerators. In this article, a simple phenomenological magnetic-hysteresis model that is suitable for numerical computations is suggested. Approximations based on the proposed model are compared to the results of measurements on partial hysteresis cycles in a steel ring.

  13. Evaluation technique for plasma-induced SiOC dielectric damage by capacitance-voltage hysteresis monitoring

    NASA Astrophysics Data System (ADS)

    Nishida, Kentaro; Okada, Yukimasa; Takao, Yoshinori; Eriguchi, Koji; Ono, Kouichi

    2016-06-01

    We propose an electrical method, named capacitance-voltage (C-V) monitoring, for quantifying plasma-induced damage (PID) to interlayer dielectrics. By this method, we measure the C-V hysteresis loops to assign carrier trap sites created by PID, and simultaneously obtain the change in the dielectric constant and thickness. We optimized the bias-sweep configuration for measuring the hysteresis curves. It is found that the C-V curve shifted in the negative direction during the optimized voltage sweep from accumulation to inversion in a pseudo-metal-oxide-semiconductor (MOS) structure. This implies the appearance of net positively charged sites owing to PID, presumably near the surface of the SiOC film. We estimate the density of defects created near the surface by monitoring the obtained C-V hysteresis curve shift. Since the degradation of interlayer dielectrics affects the circuit performance, the proposed quantitative method should be used for plasma process designs.

  14. Hysteresis during contact angles measurement.

    PubMed

    Diaz, M Elena; Fuentes, Javier; Cerro, Ramon L; Savage, Michael D

    2010-03-15

    A theory, based on the presence of an adsorbed film in the vicinity of the triple contact line, provides a molecular interpretation of intrinsic hysteresis during the measurement of static contact angles. Static contact angles are measured by placing a sessile drop on top of a flat solid surface. If the solid surface has not been previously in contact with a vapor phase saturated with the molecules of the liquid phase, the solid surface is free of adsorbed liquid molecules. In the absence of an adsorbed film, molecular forces configure an advancing contact angle larger than the static contact angle. After some time, due to an evaporation/adsorption process, the interface of the drop coexists with an adsorbed film of liquid molecules as part of the equilibrium configuration, denoted as the static contact angle. This equilibrium configuration is metastable because the droplet has a larger vapor pressure than the surrounding flat film. As the drop evaporates, the vapor/liquid interface contracts and the apparent contact line moves towards the center of the drop. During this process, the film left behind is thicker than the adsorbed film and molecular attraction results in a receding contact angle, smaller than the equilibrium contact angle.

  15. Implementation and analysis of an innovative digital charge amplifier for hysteresis reduction in piezoelectric stack actuators

    SciTech Connect

    Bazghaleh, Mohsen Grainger, Steven; Cazzolato, Ben; Lu, Tien-Fu; Oskouei, Reza

    2014-04-15

    Smart actuators are the key components in a variety of nanopositioning applications, such as scanning probe microscopes and atomic force microscopes. Piezoelectric actuators are the most common smart actuators due to their high resolution, low power consumption, and wide operating frequency but they suffer hysteresis which affects linearity. In this paper, an innovative digital charge amplifier is presented to reduce hysteresis in piezoelectric stack actuators. Compared to traditional analog charge drives, experimental results show that the piezoelectric stack actuator driven by the digital charge amplifier has less hysteresis. It is also shown that the voltage drop of the digital charge amplifier is significantly less than the voltage drop of conventional analog charge amplifiers.

  16. Sufficient conditions for rate-independent hysteresis in autoregressive identified models

    NASA Astrophysics Data System (ADS)

    Martins, Samir Angelo Milani; Aguirre, Luis Antonio

    2016-06-01

    This paper shows how hysteresis can be described using polynomial models and what are the sufficient conditions to be met by the model in order to have hysteresis. Such conditions are related to the model equilibria, to the forcing function and to certain term clusters in the polynomial models. The main results of the paper are used in the identification and analysis of nonlinear models estimated from data produced by a magneto-rheological damper (MRD) model with Bouc-Wen rate-independent hysteresis. A striking feature of the identified model is its simplicity and this could turn out to be a key factor in controller design.

  17. Equivalent Circuit Modeling of Hysteresis Motors

    SciTech Connect

    Nitao, J J; Scharlemann, E T; Kirkendall, B A

    2009-08-31

    We performed a literature review and found that many equivalent circuit models of hysteresis motors in use today are incorrect. The model by Miyairi and Kataoka (1965) is the correct one. We extended the model by transforming it to quadrature coordinates, amenable to circuit or digital simulation. 'Hunting' is an oscillatory phenomenon often observed in hysteresis motors. While several works have attempted to model the phenomenon with some partial success, we present a new complete model that predicts hunting from first principles.

  18. Contact angle hysteresis at the nanometer scale.

    PubMed

    Delmas, Mathieu; Monthioux, Marc; Ondarçuhu, Thierry

    2011-04-01

    Using atomic force microscopy with nonconventional carbon tips, the pinning of a liquid contact line on individual nanometric defects was studied. This mechanism is responsible for the occurrence of the contact angle hysteresis. The presence of weak defects which do not contribute to the hysteresis is evidenced for the first time. The dissipated energy associated with strong defects is also measured down to values in the range of kT, which correspond to defect sizes in the order of 1 nm.

  19. Spatial versus time hysteresis in damping mechanisms

    NASA Technical Reports Server (NTRS)

    Banks, H. T.; Fabiano, R. H.; Wang, Y.; Inman, D. J.; Cudney, H., Jr.

    1988-01-01

    A description is given of continuing investigations on the task of estimating internal damping mechanisms in flexible structures. Specifically, two models for internal damping in Euler-Bernoulli beams are considered: spatial hysteresis and time hysteresis. A theoretically sound computational algorithm for estimation is described, and experimental results are discussed. It is concluded that both models perform well in the sense that they accurately predict response for the experiments conducted.

  20. Flexible, low-voltage, and low-hysteresis PbSe nanowire field-effect transistors.

    PubMed

    Kim, David K; Lai, Yuming; Vemulkar, Tarun R; Kagan, Cherie R

    2011-12-27

    We report low-hysteresis, ambipolar bottom gold contact, colloidal PbSe nanowire (NW) field-effect transistors (FETs) by chemically modifying the silicon dioxide (SiO(2)) gate dielectric surface to overcome carrier trapping at the NW-gate dielectric interface. While water bound to silanol groups at the SiO(2) surface are believed to give rise to hysteresis in FETs of a wide range of nanoscale materials, we show that dehydration and silanization are insufficient in reducing PbSe NW FET hysteresis. Encapsulating PbSe NW FETs in cured poly(methyl) methacrylate (PMMA), dehydrates and uniquely passivates the SiO(2) surface, to form low-hysteresis FETs. Annealing predominantly p-type ambipolar PbSe NW FETs switches the FET behavior to predominantly n-type ambipolar, both with and without PMMA passivation. Heating the PbSe NW devices desorbs surface bound oxygen, even present in the atmosphere of an inert glovebox. Upon cooling, overtime oxygen readsorption switches the FET polarity to predominantly p-type ambipolar behavior, but PMMA encapsulation maintains low hysteresis. Unfortunately PMMA is sensitive to most solvents and heat treatments and therefore its application for nanostructured material deposition and doping is limited. Seeking a robust, general platform for low-hysteresis FETs we explored a variety of hydroxyl-free substrate surfaces, including silicon nitride, polyimide, and parylene, which show reduced electron trapping, but still large hysteresis. We identified a robust dielectric stack by assembling octadecylphosphonic acid (ODPA) on aluminum oxide (Al(2)O(3)) to form low-hysteresis FETs. We further integrated the ODPA/Al(2)O(3) gate dielectric stack on flexible substrates to demonstrate low-hysteresis, low-voltage FETs, and the promise of these nanostructured materials in flexible, electronic circuitry.

  1. VIIRS day-night band (DNB) electronic hysteresis: characterization and correction

    NASA Astrophysics Data System (ADS)

    Mills, Stephen

    2016-09-01

    The VIIRS Day-Night Band (DNB) offers measurements over a dynamic range from full daylight to the dimmest nighttime. This makes radiometric calibration difficult because effects that are otherwise negligible become significant for the DNB. One of these effects is electronic hysteresis and this paper evaluates this effect and its impact on calibration. It also considers possible correction algorithms. The cause of this hysteresis is uncertain, but since the DNB uses a charge-coupled device (CCD) detector array, it is likely the result of residual charge or charge depletion. The effects of hysteresis are evident in DNB imagery. Steaks are visible in the cross-track direction around very bright objects such as gas flares. Dark streaks are also visible after lightning flashes. Each VIIRS scan is a sequence of 4 sectors: space view (SV); Earth-view (EV); blackbody (BB) view; and solar diffuser (SD) view. There are differences among these sectors in offset that can only be explained as being the result of hysteresis from one sector to the next. The most dramatic hysteresis effect is when the sun illuminates the SD and hysteresis is then observed in the SV and EV. Previously this was hypothesized to be due to stray light leaking from the SD chamber, but more careful evaluation shows that this can only be the result of hysteresis. There is a stray light correction algorithm that treats this as stray light, but there are problems with this that could be remedied by instead using the characterization presented here.

  2. Load-Dependent Friction Hysteresis on Graphene.

    PubMed

    Ye, Zhijiang; Egberts, Philip; Han, Gang Hee; Johnson, A T Charlie; Carpick, Robert W; Martini, Ashlie

    2016-05-24

    Nanoscale friction often exhibits hysteresis when load is increased (loading) and then decreased (unloading) and is manifested as larger friction measured during unloading compared to loading for a given load. In this work, the origins of load-dependent friction hysteresis were explored through atomic force microscopy (AFM) experiments of a silicon tip sliding on chemical vapor deposited graphene in air, and molecular dynamics simulations of a model AFM tip on graphene, mimicking both vacuum and humid air environmental conditions. It was found that only simulations with water at the tip-graphene contact reproduced the experimentally observed hysteresis. The mechanisms underlying this friction hysteresis were then investigated in the simulations by varying the graphene-water interaction strength. The size of the water-graphene interface exhibited hysteresis trends consistent with the friction, while measures of other previously proposed mechanisms, such as out-of-plane deformation of the graphene film and irreversible reorganization of the water molecules at the shearing interface, were less correlated to the friction hysteresis. The relationship between the size of the sliding interface and friction observed in the simulations was explained in terms of the varying contact angles in front of and behind the sliding tip, which were larger during loading than unloading.

  3. Oscillating hysteresis in the q-neighbor Ising model.

    PubMed

    Jȩdrzejewski, Arkadiusz; Chmiel, Anna; Sznajd-Weron, Katarzyna

    2015-11-01

    We modify the kinetic Ising model with Metropolis dynamics, allowing each spin to interact only with q spins randomly chosen from the whole system, which corresponds to the topology of a complete graph. We show that the model with q≥3 exhibits a phase transition between ferromagnetic and paramagnetic phases at temperature T*, which linearly increases with q. Moreover, we show that for q=3 the phase transition is continuous and that it is discontinuous for larger values of q. For q>3, the hysteresis exhibits oscillatory behavior-expanding for even values of q and shrinking for odd values of q. Due to the mean-field-like nature of the model, we are able to derive the analytical form of transition probabilities and, therefore, calculate not only the probability density function of the order parameter but also precisely determine the hysteresis and the effective potential showing stable, unstable, and metastable steady states. Our results show that a seemingly small modification of the kinetic Ising model leads not only to the switch from a continuous to a discontinuous phase transition, but also to an unexpected oscillating behavior of the hysteresis and a puzzling phenomenon for q=5, which might be taken as evidence for the so-called mixed-order phase transition.

  4. Magnetic hysteresis properties and 57Fe Mössbauer spectroscopy of iron and stony-iron meteorites: Implications for mineralogy and thermal history

    NASA Astrophysics Data System (ADS)

    Dos Santos, E.; Gattacceca, J.; Rochette, P.; Scorzelli, R. B.; Fillion, G.

    2015-05-01

    Since the solid matter in our solar system began to assemble 4.57 billion years ago, meteorites have recorded a large range of processes, including metamorphism, melting, irradiation and hypervelocity impacts. These processes as well as solar system magnetic fields can be accessed through the investigation of magnetic properties of meteorites. In this work, we present magnetic hysteresis properties, isothermal remanent magnetization acquisition curves and 57Fe Mössbauer spectra for nineteen iron and eleven stony-iron meteorites. These data will be the background for a discussion about the thermal and shock history of these meteorites. Although Mössbauer spectroscopy and hysteresis measurements are not able to provide cooling rates like the conventional metallographic method does, we show that the combination of the ordering degree of taenite phase measured by Mössbauer spectroscopy and hysteresis properties are useful for constraining the thermal and shock history of meteorites. In particular, strong shock and the associated thermal event that result in disordering of tetrataenite can be easily identified.

  5. Tornado-Shaped Curves

    ERIC Educational Resources Information Center

    Martínez, Sol Sáez; de la Rosa, Félix Martínez; Rojas, Sergio

    2017-01-01

    In Advanced Calculus, our students wonder if it is possible to graphically represent a tornado by means of a three-dimensional curve. In this paper, we show it is possible by providing the parametric equations of such tornado-shaped curves.

  6. Hysteresis Compensation of Piezoresistive Carbon Nanotube/Polydimethylsiloxane Composite-Based Force Sensors

    PubMed Central

    Kim, Ji-Sik; Kim, Gi-Woo

    2017-01-01

    This paper provides a preliminary study on the hysteresis compensation of a piezoresistive silicon-based polymer composite, poly(dimethylsiloxane) dispersed with carbon nanotubes (CNTs), to demonstrate its feasibility as a conductive composite (i.e., a force-sensitive resistor) for force sensors. In this study, the potential use of the nanotube/polydimethylsiloxane (CNT/PDMS) as a force sensor is evaluated for the first time. The experimental results show that the electrical resistance of the CNT/PDMS composite changes in response to sinusoidal loading and static compressive load. The compensated output based on the Duhem hysteresis model shows a linear relationship. This simple hysteresis model can compensate for the nonlinear frequency-dependent hysteresis phenomenon when a dynamic sinusoidal force input is applied. PMID:28125046

  7. Hysteresis Compensation of Piezoresistive Carbon Nanotube/Polydimethylsiloxane Composite-Based Force Sensors.

    PubMed

    Kim, Ji-Sik; Kim, Gi-Woo

    2017-01-24

    This paper provides a preliminary study on the hysteresis compensation of a piezoresistive silicon-based polymer composite, poly(dimethylsiloxane) dispersed with carbon nanotubes (CNTs), to demonstrate its feasibility as a conductive composite (i.e., a force-sensitive resistor) for force sensors. In this study, the potential use of the nanotube/polydimethylsiloxane (CNT/PDMS) as a force sensor is evaluated for the first time. The experimental results show that the electrical resistance of the CNT/PDMS composite changes in response to sinusoidal loading and static compressive load. The compensated output based on the Duhem hysteresis model shows a linear relationship. This simple hysteresis model can compensate for the nonlinear frequency-dependent hysteresis phenomenon when a dynamic sinusoidal force input is applied.

  8. Material Data Representation of Hysteresis Loops for Hastelloy X Using Artificial Neural Networks

    NASA Technical Reports Server (NTRS)

    Alam, Javed; Berke, Laszlo; Murthy, Pappu L. N.

    1993-01-01

    The artificial neural network (ANN) model proposed by Rumelhart, Hinton, and Williams is applied to develop a functional approximation of material data in the form of hysteresis loops from a nickel-base superalloy, Hastelloy X. Several different ANN configurations are used to model hysteresis loops at different cycles for this alloy. The ANN models were successful in reproducing the hysteresis loops used for its training. However, because of sharp bends at the two ends of hysteresis loops, a drift occurs at the corners of the loops where loading changes to unloading and vice versa (the sharp bends occurred when the stress-strain curves were reproduced by adding stress increments to the preceding values of the stresses). Therefore, it is possible only to reproduce half of the loading path. The generalization capability of the network was tested by using additional data for two other hysteresis loops at different cycles. The results were in good agreement. Also, the use of ANN led to a data compression ratio of approximately 22:1.

  9. Hysteresis model and statistical interpretation of energy losses in non-oriented steels

    NASA Astrophysics Data System (ADS)

    Mănescu (Păltânea), Veronica; Păltânea, Gheorghe; Gavrilă, Horia

    2016-04-01

    In this paper the hysteresis energy losses in two non-oriented industrial steels (M400-65A and M800-65A) were determined, by means of an efficient classical Preisach model, which is based on the Pescetti-Biorci method for the identification of the Preisach density. The excess and the total energy losses were also determined, using a statistical framework, based on magnetic object theory. The hysteresis energy losses, in a non-oriented steel alloy, depend on the peak magnetic polarization and they can be computed using a Preisach model, due to the fact that in these materials there is a direct link between the elementary rectangular loops and the discontinuous character of the magnetization process (Barkhausen jumps). To determine the Preisach density it was necessary to measure the normal magnetization curve and the saturation hysteresis cycle. A system of equations was deduced and the Preisach density was calculated for a magnetic polarization of 1.5 T; then the hysteresis cycle was reconstructed. Using the same pattern for the Preisach distribution, it was computed the hysteresis cycle for 1 T. The classical losses were calculated using a well known formula and the excess energy losses were determined by means of the magnetic object theory. The total energy losses were mathematically reconstructed and compared with those, measured experimentally.

  10. Contact angle hysteresis on textured surfaces with nanowire clusters.

    PubMed

    Liao, Ying-Chih; Chiang, Cheng-Kun; Lu, Yen-Wen

    2013-04-01

    Nanowire arrays with various agglomeration patterns were synthesized by adjusting the solvent evaporation rates. Nanowires with 200 nm diameter and 2-25 microm in length were fabricated from an anodic aluminum oxide (AAO) porous template. Various drying treatments were applied to develop nanostructured surfaces with topological differences. Due to surface tension forces, copper nanowires after thermal and evaporative drying treatments agglomerated into clusters, while supercritical drying technique provided excellent bundled-free and vertically-standing nanowire arrays. Although all dried surfaces exhibited hydrophobic nature, the contact angle hysteresis, or the difference between advancing and receding angles, was found to be larger on those surfaces with bundled nanowire clusters. To explain the difference, the wetted solid fraction on each surface was calculated using the Cassie-Baxter model to show that the hysteresis was contributed by liquid/solid contact area on the textured surfaces.

  11. Contact angle hysteresis generated by strong dilute defects.

    PubMed

    Reyssat, Mathilde; Quéré, David

    2009-03-26

    Water on solid decorated with hydrophobic defects (such as micropillars) often stays at the top of the defects in a so-called fakir state, which explains the superhydrophobicity observed in such case, provided that the density of defects is small enough. Here we show that this situation provides an ideal frame for studying the contact angle hysteresis; the phase below the liquid is "perfect" and slippery (it is air), contrasting with pillars' tops whose edges form strong pining sites for the contact line. This model system thus allows us to study the hysteresis as a function of the density of defects and to compare it to the classical theory by Joanny and de Gennes, which is based on very similar hypothesis.

  12. Hysteresis Behaviors of Poly (Naphthalene Quinone) Radical Electrorheological Fluid

    NASA Astrophysics Data System (ADS)

    Choi, Hyoung J.; Cho, Min S.; Jhon, Myung S.

    As a potential electrorheological(ER) material, poly(naphthalene quinone) radical (PNQR) ER fluid was prepared, and its rheological behavior and hysteresis phenomenon were investigated. PNQR was synthesized by Friedel-Crafts acylation between naphthalene and phthalic anhydride, using zinc chloride as a catalyst at 256°C. A Physica rheometer equipped with a high voltage generator was used to measure the rheological properties of the ER fluids, which were prepared by dispersing PNQR in silicone oil at several particle concentrations. Shear stresses were observed to decrease as shear rate increased in the region of slow deformation rate. It was further found that ER fluid showed different hysteresis behaviors according to the shear rate ranges; thixotropy was observed in the low shear rate region (0.007-0.51/s) and anti-thixotropy in the high shear rate region (0.5-10001/s). Controlled shear stress mode was also applied to observe similar behaviors.

  13. Hysteresis and multiple stable configurations in a magnetic fluid system.

    PubMed

    Jackson, D P

    2008-05-21

    A magnetic liquid in a horizontal Hele-Shaw cell is subjected to a vertical magnetic field. The width of the magnetic fluid finger is measured as a function of applied field and compared to a theoretical model. The theoretical model uses an energy minimization procedure and predicts a double energy minimum, hysteresis, and discontinuous transitions between a circle and a finger. The experimental data set agrees very well with the theory for a well-defined magnetic fluid finger. Near the transitions, the experiments show hysteresis and support for a double energy minimum; however, the agreement is not quite so good. The discrepancy between theory and experiment near the transition region is likely due to the simplified finger model used in the theory.

  14. Titration and hysteresis in epigenetic chromatin silencing

    NASA Astrophysics Data System (ADS)

    Dayarian, Adel; Sengupta, Anirvan M.

    2013-06-01

    Epigenetic mechanisms of silencing via heritable chromatin modifications play a major role in gene regulation and cell fate specification. We consider a model of epigenetic chromatin silencing in budding yeast and study the bifurcation diagram and characterize the bistable and the monostable regimes. The main focus of this paper is to examine how the perturbations altering the activity of histone modifying enzymes affect the epigenetic states. We analyze the implications of having the total number of silencing proteins, given by the sum of proteins bound to the nucleosomes and the ones available in the ambient, to be constant. This constraint couples different regions of chromatin through the shared reservoir of ambient silencing proteins. We show that the response of the system to perturbations depends dramatically on the titration effect caused by the above constraint. In particular, for a certain range of overall abundance of silencing proteins, the hysteresis loop changes qualitatively with certain jump replaced by continuous merger of different states. In addition, we find a nonmonotonic dependence of gene expression on the rate of histone deacetylation activity of Sir2. We discuss how these qualitative predictions of our model could be compared with experimental studies of the yeast system under anti-silencing drugs.

  15. Deformation Hysteresis of Electrohydrodynamic Patterning on a Thin Polymer Film.

    PubMed

    Yang, Qingzhen; Li, Ben Q; Tian, Hongmiao; Li, Xiangming; Shao, Jinyou; Chen, Xiaoliang; Xu, Feng

    2016-07-13

    Electrohydrodynamic patterning is a technique that enables micro/nanostructures via imposing an external voltage on thin polymer films. In this investigation, we studied the electrohydrodynamic patterning theoretically and experimentally, with special interest focused on the equilibrium state. It is found that the equilibrium structure height increases with the voltage. In addition, we have observed, and believe it to be the first time, a hysteresis phenomenon exists in the relationship between the voltage and structure height. With an increase in the voltage, a critical value (the first critical voltage) is noticed, above which the polymer film would increase dramatically until it comes into contact with the template. However, with a decrease in the voltage, a smaller voltage (the second critical voltage) is needed to detach the polymer from the template. The mismatch of the first and second critical voltages distorts the voltage-structure height curve into an "S" shape. Such a phenomenon is verified for three representative templates and also by experiments. Furthermore, the effects of some parameters (e.g., polymer film thickness and dielectric constant) on this hysteresis phenomenon are also discussed.

  16. Flow-duration curves

    USGS Publications Warehouse

    Searcy, James Kincheon

    1959-01-01

    The flow-duration curve is a cumulative frequency curve that shows the percent of time specified discharges were equaled or exceeded during a given period. It combines in one curve the flow characteristics of a stream throughout the range of discharge, without regard to the sequence of occurrence. If the period upon which the curve is based represents the long-term flow of a stream, the curve may be used to predict the distribution of future flows for water- power, water-supply, and pollution studies. This report shows that differences in geology affect the low-flow ends of flow-duration curves of streams in adjacent basins. Thus, duration curves are useful in appraising the geologic characteristics of drainage basins. A method for adjusting flow-duration curves of short periods to represent long-term conditions is presented. The adjustment is made by correlating the records of a short-term station with those of a long-term station.

  17. Transforming Curves into Curves with the Same Shape.

    ERIC Educational Resources Information Center

    Levine, Michael V.

    Curves are considered to have the same shape when they are related by a similarity transformation of a certain kind. This paper extends earlier work on parallel curves to curves with the same shape. Some examples are given more or less explicitly. A generalization is used to show that the theory is ordinal and to show how the theory may be applied…

  18. Motion of liquid drops on surfaces induced by asymmetric vibration: role of contact angle hysteresis.

    PubMed

    Mettu, Srinivas; Chaudhury, Manoj K

    2011-08-16

    Hysteresis of wetting, like the Coulombic friction at solid/solid interface, impedes the motion of a liquid drop on a surface when subjected to an external field. Here, we present a counterintuitive example, where some amount of hysteresis enables a drop to move on a surface when it is subjected to a periodic but asymmetric vibration. Experiments show that a surface either with a negligible or high hysteresis is not conducive to any drop motion. Some finite hysteresis of contact angle is needed to break the periodic symmetry of the forcing function for the drift to occur. These experimental results are consistent with simulations, in which a drop is approximated as a linear harmonic oscillator. The experiment also sheds light on the effect of the drop size on flow reversal, where drops of different sizes move in opposite directions due to the difference in the phase of the oscillation of their center of mass.

  19. Modeling of the interleaved hysteresis loop in the measurements of rotational core losses

    NASA Astrophysics Data System (ADS)

    Alatawneh, Natheer; Pillay, Pragasen

    2016-01-01

    The measurement of core losses in machine laminations reveals a fundamental difference between rotational and pulsating types. Rotational core losses under rotating fields decrease at high flux density, while pulsating losses keep increasing steadily. Experimental analyses of loss components Px and Py in x and y directions with rotating fields show that the loss decreases in one loss component and sometimes attains negative values. Tracking the evolution of hysteresis loops along this loss component discloses a peculiar behavior of magnetic hysteresis, where the loop changes its path from counterclockwise to clockwise within a cycle of magnetization process, the so called interleaved hysteresis loop. This paper highlights a successful procedure for modeling the interleaved hysteresis loop in the measurement of rotational core losses in electrical machine laminations using the generalized Prandtl-Ishlinskii (PI) model. The efficiency of the proposed model is compared to Preisach model. Results and conclusion of this work are of importance toward building an accurate model of rotational core losses.

  20. Origins and Mechanisms of Hysteresis in Organometal Halide Perovskites.

    PubMed

    Li, Cheng; Guerrero, Antonio; Zhong, Yu; Huettner, Sven

    2017-02-23

    Inorganic-organic organometal halide perovskites, such as CH3NH3PbI3 or CsPbI3, etc., are an unprecedented rising star in the field of photovoltaics since 2009, owing to its exceptionally high power conversion efficiency (PCE) and simple fabrication processability. Despite its relatively short history of development, intensive investigations have been concentrating on this material, ranging from crystal structure analysis and photophysical characterization, to performance optimization and device integration, etc. Yet, applied in photovoltaic devices, this material is suffering from hysteresis, that is, the difference of the current-voltage (I-V) curve during sweeping in two directions (from short-circuit towards open-circuit and vice versa). This behavior may significantly impede the large-scale commercial application. This Review will focus on the recent theoretical and experimental efforts to reveal the origin and mechanism of hysteresis. The proposed origins include (1) ferroelectric polarization, (2) charge trapping/detrapping and (3) ion migration. Among them, recent evidences consistently support that ion migration plays a key role for the hysteretic behavior in perovskite solar cells (PSC). Hence, this Review will summarize the recent results on ion migration, such as the migrating ion species, activation energy measurement, capacitive characterization and internal electrical field modulation, etc. In addition, this Review will also present the devices with alleviation/elimination of hysteresis by incorporating either large size grains or phenyl-C61-butyric acid methyl ester (PCBM) molecules. In a different application, the hysteretic property has been utilized in photovoltaic and memristive switching devices. In sum, by examining above three possible mechanisms, it is concluded that the origin of hysteresis of PSCs is associated with a combination of effects, both ion/defect migration and charge trapping

  1. Hysteresis and Wavenumber Vacillation in Unstable Baroclinic Flows

    NASA Technical Reports Server (NTRS)

    Chou, Shih-Hung; Goodman, H. Michael (Technical Monitor)

    2001-01-01

    Hysteresis and wavenumber vacillation are studied numerically in a weakly stratified quasigeostrophic model. In general, the amplitude of the most unstable wave increases, as the flow becomes more unstable. When the wave becomes saturated, the next longer wave will grow at the expanse of the most unstable wave and becomes the dominant wave. However, once the longwave state is established, it may remain in that regime even as the instability is decreased beyond the threshold where it first developed, thus constituting a hysteresis loop. In a highly unstable case, the flow may not show a preference for any single wave. Instead, the dominant wave aperiodically varies among several long waves. This phenomenon is known as wavenumber vacillation. Hysteresis is further examined in terms of eddy heat flux. It is shown that total eddy heat flux increases as the flow becomes more unstable, but displays a sharp drop when transition to a longer wave occurs. However, in a longwave state, the heat flux always decreases with decreasing instability even pass the threshold when wave transition first occurs.

  2. Evidence for ion migration in hybrid perovskite solar cells with minimal hysteresis

    PubMed Central

    Calado, Philip; Telford, Andrew M.; Bryant, Daniel; Li, Xiaoe; Nelson, Jenny; O'Regan, Brian C.; Barnes, Piers R.F.

    2016-01-01

    Ion migration has been proposed as a possible cause of photovoltaic current–voltage hysteresis in hybrid perovskite solar cells. A major objection to this hypothesis is that hysteresis can be reduced by changing the interfacial contact materials; however, this is unlikely to significantly influence the behaviour of mobile ionic charge within the perovskite phase. Here, we show that the primary effects of ion migration can be observed regardless of whether the contacts were changed to give devices with or without significant hysteresis. Transient optoelectronic measurements combined with device simulations indicate that electric-field screening, consistent with ion migration, is similar in both high and low hysteresis CH3NH3PbI3 cells. Simulation of the photovoltage and photocurrent transients shows that hysteresis requires the combination of both mobile ionic charge and recombination near the perovskite-contact interfaces. Passivating contact recombination results in higher photogenerated charge concentrations at forward bias which screen the ionic charge, reducing hysteresis. PMID:28004653

  3. Hysteresis from Multiscale Porosity: Modeling Water Sorption and Shrinkage in Cement Paste

    NASA Astrophysics Data System (ADS)

    Pinson, Matthew B.; Masoero, Enrico; Bonnaud, Patrick A.; Manzano, Hegoi; Ji, Qing; Yip, Sidney; Thomas, Jeffrey J.; Bazant, Martin Z.; Van Vliet, Krystyn J.; Jennings, Hamlin M.

    2015-06-01

    Cement paste has a complex distribution of pores and molecular-scale spaces. This distribution controls the hysteresis of water sorption isotherms and associated bulk dimensional changes (shrinkage). We focus on two locations of evaporable water within the fine structure of pastes, each having unique properties, and we present applied physics models that capture the hysteresis by dividing drying and rewetting into two related regimes based on relative humidity (RH). We show that a continuum model, incorporating a pore-blocking mechanism for desorption and equilibrium thermodynamics for adsorption, explains well the sorption hysteresis for a paste that remains above approximately 20% RH. In addition, we show with molecular models and experiments that water in spaces of ≲1 nm width evaporates below approximately 20% RH but reenters throughout the entire RH range. This water is responsible for a drying shrinkage hysteresis similar to that of clays but opposite in direction to typical mesoporous glass. Combining the models of these two regimes allows the entire drying and rewetting hysteresis to be reproduced accurately and provides parameters to predict the corresponding dimensional changes. The resulting model can improve the engineering predictions of long-term drying shrinkage accounting also for the history dependence of strain induced by hysteresis. Alternative strategies for quantitative analyses of the microstructure of cement paste based on this mesoscale physical model of water content within porous spaces are discussed.

  4. Magnetomechanical damping and magnetoelastic hysteresis in permalloy

    NASA Astrophysics Data System (ADS)

    Ercuta, A.; Mihalca, I.

    2002-11-01

    The inverse Wiedemann effect (IWE) consisting in longitudinal magnetization reversals was detected with a cylindrical permalloy layer subjected to circular DC magnetic fields while performing low frequency (~1 Hz) free torsion oscillations. Hysteresis occurring in the magnetization vs elastic strain dependence (the `magnetoelastic hysteresis') suggested irreversible processes activated mechanically. Joint vibration and magnetization time records were carried out by means of an experimental set-up including inverted pendulum and conventional integrating fluxmeter, in order to compare the relative energy losses ascribed to the magnetomechanical damping (MMD) and to the magnetoelastic hysteresis, respectively. The experimental results clearly pointed out a close connection between IWE and MMD providing evidence that, when simultaneously examined, both effects reflect the same basic phenomenon: the irreversible magnetization changes induced by the elastic strain.

  5. Effect of relative humidity on crystal growth, device performance and hysteresis in planar heterojunction perovskite solar cells

    NASA Astrophysics Data System (ADS)

    Gangishetty, Mahesh K.; Scott, Robert W. J.; Kelly, Timothy L.

    2016-03-01

    Due to the hygroscopic nature of organolead halide perovskites, humidity is one of the most important factors affecting the efficiency and longevity of perovskite solar cells. Although humidity has a long term detrimental effect on device performance, it also plays a key role during the initial growth of perovskite crystals. Here we demonstrate that atmospheric relative humidity (RH) plays a key role during the formation of perovskite thin films via the sequential deposition technique. Our results indicate that the RH has a substantial impact on the crystallization process, and hence on device performance. SEM and pXRD analysis show an increase in crystallite size with increasing humidity. At low RH, the formation of small cubic crystallites with large gaps between them is observed. The presence of these voids adversely affects device performance and leads to substantial hysteresis in the device. At higher RH, the perovskite crystals are larger in size, with better connectivity between the crystallites. This produced efficient planar heterojunction solar cells with low hysteresis. By careful control of the RH during the cell fabrication process, efficiencies of up to 12.2% are reached using P3HT as the hole-transport material.Due to the hygroscopic nature of organolead halide perovskites, humidity is one of the most important factors affecting the efficiency and longevity of perovskite solar cells. Although humidity has a long term detrimental effect on device performance, it also plays a key role during the initial growth of perovskite crystals. Here we demonstrate that atmospheric relative humidity (RH) plays a key role during the formation of perovskite thin films via the sequential deposition technique. Our results indicate that the RH has a substantial impact on the crystallization process, and hence on device performance. SEM and pXRD analysis show an increase in crystallite size with increasing humidity. At low RH, the formation of small cubic crystallites

  6. Hysteresis modeling in graphene field effect transistors

    SciTech Connect

    Winters, M.; Rorsman, N.; Sveinbjörnsson, E. Ö.

    2015-02-21

    Graphene field effect transistors with an Al{sub 2}O{sub 3} gate dielectric are fabricated on H-intercalated bilayer graphene grown on semi-insulating 4H-SiC by chemical vapour deposition. DC measurements of the gate voltage v{sub g} versus the drain current i{sub d} reveal a severe hysteresis of clockwise orientation. A capacitive model is used to derive the relationship between the applied gate voltage and the Fermi energy. The electron transport equations are then used to calculate the drain current for a given applied gate voltage. The hysteresis in measured data is then modeled via a modified Preisach kernel.

  7. Influence of hydraulic hysteresis on the mechanical behavior of unsaturated soils and interfaces

    NASA Astrophysics Data System (ADS)

    Khoury, Charbel N.

    Unsaturated soils are commonly widespread around the world, especially at shallow depths from the surface. The mechanical behavior of this near surface soil is influenced by the seasonal variations such as rainfall or drought, which in turn may have a detrimental effect on many structures (e.g. retaining walls, shallow foundations, mechanically stabilized earth walls, soil slopes, and pavements) in contact with it. Thus, in order to better understand this behavior, it is crucial to study the complex relationship between soil moisture content and matric suction (a stress state variable defined as pore air pressure minus pore water pressure) known as the Soil Water Characteristic Curve (SWCC). In addition, the influence of hydraulic hysteresis on the behavior of unsaturated soils, soil-structure interaction (i.e. rough and smooth steel interfaces, soil-geotextile interfaces) and pavement subgrade (depicted herein mainly by resilient modulus, Mr) was also studied. To this end, suction-controlled direct shear tests were performed on soils, rough and smooth steel interfaces and geotextile interface under drying (D) and wetting after drying (DW). The shearing behavior is examined in terms of the two stress state variables, matric suction and net normal stress. Results along the D and DW paths indicated that peak shear strength increased with suction and net normal stress; while in general, the post peak shear strength was not influenced by suction for rough interfaces and no consistent trend was observed for soils and soil-geotextiles interfaces. Contrary to saturated soils, results during shearing at higher suction values (i.e. 25 kPa and above) showed a decrease in water content eventhough the sample exhibited dilation. A behavior postulated to be related to disruption of menisci and/or non-uniformity of pore size which results in an increase in localized pore water pressures. Interestingly, wetting after drying (DW) test results showed higher peak and post peak shear

  8. Thermally induced all-optical inverter and dynamic hysteresis loops in graphene oxide dispersions.

    PubMed

    Melle, Sonia; Calderón, Oscar G; Egatz-Gómez, Ana; Cabrera-Granado, E; Carreño, F; Antón, M A

    2015-11-01

    We experimentally study the temporal dynamics of amplitude-modulated laser beams propagating through a water dispersion of graphene oxide sheets in a fiber-to-fiber U-bench. Nonlinear refraction induced in the sample by thermal effects leads to both phase reversing of the transmitted signals and dynamic hysteresis in the input-output power curves. A theoretical model including beam propagation and thermal lensing dynamics reproduces the experimental findings.

  9. High-Precision Hysteresis Sensing of the Quartz Crystal Inductance-to-Frequency Converter.

    PubMed

    Matko, Vojko; Milanović, Miro

    2016-06-28

    A new method for the automated measurement of the hysteresis of the temperature-compensated inductance-to-frequency converter with a single quartz crystal is proposed. The new idea behind this method is a converter with two programmable analog switches enabling the automated measurement of the converter hysteresis, as well as the temperature compensation of the quartz crystal and any other circuit element. Also used is the programmable timing control device that allows the selection of different oscillating frequencies. In the proposed programmable method two different inductances connected in series to the quartz crystal are switched in a short time sequence, compensating the crystal's natural temperature characteristics (in the temperature range between 0 and 50 °C). The procedure allows for the measurement of the converter hysteresis at various values of capacitance connected in parallel with the quartz crystal for the converter sensitivity setting at selected inductance. It, furthermore, enables the measurement of hysteresis at various values of inductance at selected parallel capacitance (sensitivity) connected to the quartz crystal. The article shows that the proposed hysteresis measurement of the converter, which converts the inductance in the range between 95 and 100 μH to a frequency in the range between 1 and 200 kHz, has only 7 × 10(-13) frequency instability (during the temperature change between 0 and 50 °C) with a maximum 1 × 10(-11) hysteresis frequency difference.

  10. High-Precision Hysteresis Sensing of the Quartz Crystal Inductance-to-Frequency Converter

    PubMed Central

    Matko, Vojko; Milanović, Miro

    2016-01-01

    A new method for the automated measurement of the hysteresis of the temperature-compensated inductance-to-frequency converter with a single quartz crystal is proposed. The new idea behind this method is a converter with two programmable analog switches enabling the automated measurement of the converter hysteresis, as well as the temperature compensation of the quartz crystal and any other circuit element. Also used is the programmable timing control device that allows the selection of different oscillating frequencies. In the proposed programmable method two different inductances connected in series to the quartz crystal are switched in a short time sequence, compensating the crystal’s natural temperature characteristics (in the temperature range between 0 and 50 °C). The procedure allows for the measurement of the converter hysteresis at various values of capacitance connected in parallel with the quartz crystal for the converter sensitivity setting at selected inductance. It, furthermore, enables the measurement of hysteresis at various values of inductance at selected parallel capacitance (sensitivity) connected to the quartz crystal. The article shows that the proposed hysteresis measurement of the converter, which converts the inductance in the range between 95 and 100 μH to a frequency in the range between 1 and 200 kHz, has only 7 × 10−13 frequency instability (during the temperature change between 0 and 50 °C) with a maximum 1 × 10−11 hysteresis frequency difference. PMID:27367688

  11. Negative hysteresis effect observed during calibration of the US Bureau of Mines borehole deformation gauge

    SciTech Connect

    Ganow, H.C.

    1985-08-01

    The US Bureau of Mines borehole deformation gauge (BMG) was designed in the early 1960`s to allow rock stress measurements by the overcoring method. Since that time it has become a de facto standard against which the performance of other borehole deformation gauges is often judged. However, during recent in situ stress studies in the Climax Stock at the Nevada Test Site a strange "negative hysteresis" in the order of 300 to 500 microstrains was observed in standard calibration data. Here, the relaxation curve lies below the indentation (compression) curves as if the system were to somehow respond with an energy release. Therefore, a precision micro-indentation apparatus has been designed and used to perform a series of tests allowing a better understanding of the BMG button to cantilever interaction. Results indicate that the hysteresis effect is caused by differential motion between the button base and the cantilever resulting from the geometric motion inherent in the cantilever. The very large apparent hysteresis is mainly caused by cycling opposing cantilevers through the instrument`s entire dynamic range, and the fundamental imprecision inherent in use of the standard micrometers to calibrate the BMG. Laboratory mean hysteresis magnitudes for a polished cantilever typically range from 3 to 25 microstrain for 100 and 1000 microstrain relaxations on 1000 microstrain deflection loops intended to simulate typical field data. The error percentage is thought to remain fairly constant with deformation loop size, and is sufficiently small such that it can be safely ignored. The hysteresis effect can probably be reduced, and instrument stability improved by machining a small 90 degree cone in the cantilever in which a slightly larger mating cone on the base of the indentation button would reside. 5 refs. 26 figs., 1 tab.

  12. Wetting hysteresis of nanodrops on nanorough surfaces

    NASA Astrophysics Data System (ADS)

    Chang, Cheng-Chung; Sheng, Yu-Jane; Tsao, Heng-Kwong

    2016-10-01

    Nanodrops on smooth or patterned rough surfaces are explored by many-body dissipative particle dynamics to demonstrate the influence of surface roughness on droplet wetting. On a smooth surface, nanodrops exhibit the random motion and contact angle hysteresis is absent. The diffusivity decays as the intrinsic contact angle (θY) decreases. On a rough surface, the contact line is pinned and the most stable contact angle (θY') is acquired. The extent of contact angle hysteresis (Δ θ ) is determined by two approaches, which resemble the inflation-deflation method and inclined plane method for experiments. The hysteresis loop is acquired and both approaches yield consistent results. The influences of wettability and surface roughness on θY' and Δ θ are examined. θY' deviates from that estimated by the Wenzel or Cassie-Baxter models. This consequence can be explained by the extent of impregnation, which varies with the groove position and wettability. Moreover, contact angle hysteresis depends more on the groove width than the depth.

  13. Wetting hysteresis of nanodrops on nanorough surfaces.

    PubMed

    Chang, Cheng-Chung; Sheng, Yu-Jane; Tsao, Heng-Kwong

    2016-10-01

    Nanodrops on smooth or patterned rough surfaces are explored by many-body dissipative particle dynamics to demonstrate the influence of surface roughness on droplet wetting. On a smooth surface, nanodrops exhibit the random motion and contact angle hysteresis is absent. The diffusivity decays as the intrinsic contact angle (θ_{Y}) decreases. On a rough surface, the contact line is pinned and the most stable contact angle (θ_{Y}^{'}) is acquired. The extent of contact angle hysteresis (Δθ) is determined by two approaches, which resemble the inflation-deflation method and inclined plane method for experiments. The hysteresis loop is acquired and both approaches yield consistent results. The influences of wettability and surface roughness on θ_{Y}^{'} and Δθ are examined. θ_{Y}^{'} deviates from that estimated by the Wenzel or Cassie-Baxter models. This consequence can be explained by the extent of impregnation, which varies with the groove position and wettability. Moreover, contact angle hysteresis depends more on the groove width than the depth.

  14. Role of hysteresis in stomatal aperture dynamics

    NASA Astrophysics Data System (ADS)

    Ramos, Antônio M. T.; Prado, Carmen P. C.

    2013-01-01

    Stomata are pores responsible for gas exchange in leaves. Several experiments indicate that stomata synchronize into clusters or patches. The patches’ coordination may produce oscillations in stomatal conductance. Previous studies claim to reproduce some experimental results. However, none was able to explain the variety of behavior observed in the stomatal dynamics. Recently, Ferraz and Prado suggested a realistic geometry of vein distribution. Although it reproduces the patches, no oscillation was observed and the patches remain static. Without exploring significant details, the authors stated that hysteresis in stomatal aperture could explain several experimental features. In this paper, the hysteresis hypothesis is further explored through the concept of hysteretic operators. We have shown that the hysteresis assumption is sufficient to obtain dynamical patches and oscillations in stomatal conductance. The robustness of this hypothesis is tested by using different hysteresis operators. The model analysis reveals a dependence between the period of oscillation in stomatal conductance and the water deficit between the leaf and the environment. This underlying feature of the model might inspire further experiments to test this hypothesis.

  15. Managing Hysteresis: Three Cornerstones to Fiscal Stability

    ERIC Educational Resources Information Center

    Weeks, Richard

    2012-01-01

    The effects of the Great Recession of 2007-2009 continue to challenge school business officials (SBOs) and other education leaders as they strive to prepare students for the global workforce. Economists have borrowed a word from chemistry to describe this state of affairs: hysteresis--the lingering effects of the past on the present. Today's SBOs…

  16. Circuit increases capability of hysteresis synchronous motor

    NASA Technical Reports Server (NTRS)

    Markowitz, I. N.

    1967-01-01

    Frequency and phase detector circuit enables a hysteresis synchronous motor to drive a load of given torque value at a precise speed determined by a stable reference. This technique permits driving larger torque loads with smaller motors and lower power drain.

  17. CO2 Trapping in Reservoirs with Fluvial Architecture: Sensitivity to Heterogeneity and Hysteresis in Characteristic Relationships for Different Rock Types

    NASA Astrophysics Data System (ADS)

    Gershenzon, N. I.; Ritzi, R. W., Jr.; Dominic, D. F.; Mehnert, E.; Okwen, R. T.

    2015-12-01

    Naum I. Gershenzona, Robert W. Ritzi Jr.a, David F. Dominica, Edward Mehnertb, and Roland T. OkwenbaDepartment of Earth and Environmental Sciences, Wright State University, 3640 Col. Glenn Hwy., Dayton, OH 45435, USAbIllinois State Geological Survey, Prairie Research Institute, University of Illinois at Urbana-Champaign, 615 East Peabody Drive, Champaign, IL 61820, USA A number of important candidate CO2 reservoirs exhibit sedimentary architecture reflecting fluvial deposition. Recent studies have led to new conceptual and quantitative models for sedimentary architecture in fluvial deposits over a range of scales that are relevant to CO2 injection and storage, led to new geocellular modelling approaches for representing this architecture, and led to new computational studies of CO2 plume dynamics during and after injection. The processes of CO2 trapping depend upon a complex system of non-linear and hysteretic characteristic relationships including how relative permeability and capillary pressure vary with brine and CO2 saturation. New computational studies of capillary trapping in conglomeratic reservoirs strongly suggest that representing small-scale (decimeter to meter) textural facies among different rock types, including their organization within a hierarchy of larger-scale stratification, representing differences in characteristic relationships between rock types, and representing hysteresis in characteristic curves can all be critical to understanding trapping processes. In this context, CO2trapping was evaluated in conglomeratic reservoirs with fluvial architecture including different rock types with different and hysteretic characteristic curves and with capillary pressure defined for each rock type using two different conventional approaches, i.e. Brooks-Corey and van Genuchten. The results show that in these reservoirs the capillary trapping rates are quite sensitive to differences between the Brooks-Corey and van Genuchten approaches, and that

  18. Contact angle hysteresis: a different view and a trivial recipe for low hysteresis hydrophobic surfaces.

    PubMed

    Krumpfer, Joseph W; McCarthy, Thomas J

    2010-01-01

    Contact angle hysteresis is addressed from two perspectives. The first is an analysis of the events that occur during motion of droplets on superhydrophobic surfaces. Hysteresis is discussed in terms of receding contact line pinning and the tensile failure of capillary bridges. The sign of the curvature of the solid surface is implicated as playing a key role. The second is the report of a new method to prepare smooth low hysteresis surfaces. The thermal treatment of oxygen plasma-cleaned silicon wafers with trimethylsilyl-terminated linear poly(dimethylsiloxane) (PDMS - commercial silicone oils) in disposable glass vessels is described. This treatment renders silicon/silica surfaces that contain covalently attached PDMS chains. The grafted layers of nanometre scale thickness are liquid-like (rotationally dynamic at room temperature), decrease activation barriers for contact line motion and minimize water contact angle hysteresis. This simple method requires neither sophisticated techniques nor substantial laboratory skills to perform.

  19. Fatigue and hysteresis modeling of ferroelectric materials

    NASA Astrophysics Data System (ADS)

    Yoo, In. K.; Desu, Seshu B.

    1993-10-01

    Due to their nonlinear properties, ferroelectric materials are ideal candidates for smart materials. Degradation properties such as low voltage breakdown, fatigue, and aging have been major problems in commercial applications of these materials. Such degradations affect the lifetime of ferroelectric materials. Therefore, it is important to understand degradation for reliability improvement. In this article, recent studies on fatigue and hysteresis of ferroelectric ceramics such as Lead Zirconate Titanate (PZT) thin films is reviewed. A new fatigue model is discussed in detail which is based on effective one-directional movement of defects by internal field difference, defect entrapment at the ferroelectrics-electrode interface, and resultant polarization loss at the interface. A fatigue equation derived from this model is presented. Fatigue parameters such as initial polarization, piling constant, and decay constant are defined from the fatigue equation and voltage and temperature dependence of fatigue parameters are discussed. The jump distance of defect calculated from voltage dependence of the decay constant is close to the lattice constant of ferroelectric materials, which implies that oxygen or lead vacancies migrate either parallel or antiparallel to the polarization direction. From the temperature dependence of the decay constant, it is shown that the activation energy for domain wall movement plays an important role in fatigue. The hysteresis model of ferroelectrics is shown using polarization reversal. The hysteresis loop is made by four polarization stages: nucleation, growth, merging, and shrinkage of domains. The hysteresis equation confirms that dielectric viscosity controls hysteresis properties, and temperature dependence of the coefficient of dielectric viscosity is also discussed in conjunction with fatigue mechanism.

  20. Torque meter aids study of hysteresis motor rings

    NASA Technical Reports Server (NTRS)

    Cole, M.

    1967-01-01

    Torque meter, simulating hysteresis motor operation, allows rotor ring performance characteristics to be analyzed. The meter determines hysteresis motor torque and actual stresses of the ring due to its mechanical situation and rotation, aids in the study of asymmetries or defects in motor rings, and measures rotational hysteresis.

  1. Effect of contact angle hysteresis on breakage of a liquid bridge

    NASA Astrophysics Data System (ADS)

    Chen, H.; Tang, T.; Amirfazli, A.

    2015-03-01

    In this paper, the importance of considering contact angle hysteresis (CAH) during the process of stretching and breaking a liquid bridge between two solid surfaces is addressed. We clearly show that due to the pinning of contact line at the end of the stretching stage, the contact angle between liquid bridge and surfaces cannot be simply assumed to have a constant value (e.g. receding contact angle, θ r ). Simulation results for stretching a liquid bridge with and without CAH, showed that the contact line pinning can lead to breakage at a larger surface separation and smaller value of pull-off force ( F p ). A systematic study about the effect of CAH and contact line pinning on the value of F p is provided. It is found that when one of the surfaces has a θ r larger than 90∘, F p decreases with the increase of θ r on either surface delimiting the bridge. For the cases where θ r of both surfaces are smaller than 90∘, significantly smaller F p is seen when contact line pinning occurs on both surfaces, as compared to F p when contact line pinning occurs only on one surface. This smaller F p is caused by more curved profile and later breakage of liquid bridge.

  2. Hysteresis phenomena in perovskite solar cells: the many and varied effects of ionic accumulation.

    PubMed

    Jacobs, Daniel A; Wu, Yiliang; Shen, Heping; Barugkin, Chog; Beck, Fiona J; White, Thomas P; Weber, Klaus; Catchpole, Kylie R

    2017-01-25

    The issue of hysteresis in perovskite solar cells has now been convincingly linked to the presence of mobile ions within the perovskite layer. Here we test the limits of the ionic theory by attempting to account for a number of exotic characterization results using a detailed numerical device model that incorporates ionic charge accumulation at the perovskite interfaces. Our experimental observations include a temporary enhancement in open-circuit voltage following prolonged periods of negative bias, dramatically S-shaped current-voltage sweeps, decreased current extraction following positive biasing or "inverted hysteresis", and non-monotonic transient behaviours in the dark and the light. Each one of these phenomena can be reproduced and ultimately explained by our models, providing further evidence for the ionic theory of hysteresis as well as valuable physical insight into the factors that coincide to bring these phenomena about. In particular we find that both interfacial recombination and carrier injection from the selective contacts are heavily affected by ionic accumulation, and are essential to explaining the non-monotonic voltage transients and S-shaped J-V curves. Inverted hysteresis is attributed to the occurrence of "positive" ionic accumulation, which may also be responsible for enhancing the stabilized open-circuit voltage in some perovskite cells.

  3. Highly Stretchable, Hysteresis-Free Ionic Liquid-Based Strain Sensor for Precise Human Motion Monitoring.

    PubMed

    Choi, Dong Yun; Kim, Min Hyeong; Oh, Yong Suk; Jung, Soo-Ho; Jung, Jae Hee; Sung, Hyung Jin; Lee, Hyung Woo; Lee, Hye Moon

    2017-01-18

    A highly stretchable, low-cost strain sensor was successfully prepared using an extremely cost-effective ionic liquid of ethylene glycol/sodium chloride. The hysteresis performance of the ionic-liquid-based sensor was able to be improved by introducing a wavy-shaped fluidic channel diminishing the hysteresis by the viscoelastic relaxation of elastomers. From the simulations on visco-hyperelastic behavior of the elastomeric channel, we demonstrated that the wavy structure can offer lower energy dissipation compared to a flat structure under a given deformation. The resistance response of the ionic-liquid-based wavy (ILBW) sensor was fairly deterministic with no hysteresis, and it was well-matched to the theoretically estimated curves. The ILBW sensors exhibited a low degree of hysteresis (0.15% at 250%), low overshoot (1.7% at 150% strain), and outstanding durability (3000 cycles at 300% strain). The ILBW sensor has excellent potential for use in precise and quantitative strain detections in various areas, such as human motion monitoring, healthcare, virtual reality, and smart clothes.

  4. Modeling of micromagnetic Barkhausen activity using a stochastic process extension to the theory of hysteresis

    SciTech Connect

    Jiles, D.C. ); Sipahi, L.B. ); Williams, G. )

    1993-05-15

    Recent work by Bertotti [IEEE Trans. Magn. [bold MAG]-[bold 24], 621 (1988)] and others has shown that it is possible to model the micromagnetic Barkhausen discontinuities at the coercive point using a two-parameter stochastic model. However, the present formulation of the model is restricted to limited regions of the hysteresis curve over which [ital dM]/[ital dH] is approximately constant and when [ital dH]/[ital dt] is held at a constant rate. A natural extension of this model is to take the basic result, in which the level of Barkhausen activity in one time period is related to the activity in the previous time period, and increment it by a small amount which is dependent on the differential permeability. The extension of the model proposed here uses the theory of ferromagnetic hysteresis to determine the differential permeability at any point of the hysteresis loop. The Barkhausen activity is then assumed to vary in proportion to the differential permeability. The resulting model allows the Barkhausen sum of discontinuous changes in magnetization to be modelled around the entire hysteresis loop, leading to an important generalization of the basic model.

  5. In-plane hysteresis of permalloy nanorings: a study of micromagnetic simulation

    NASA Astrophysics Data System (ADS)

    Mishra, A. C.

    2015-09-01

    Magnetic hysteresis of isotropic permalloy nanorings with outer diameter 200 nm and thickness 20 nm has been studied. The inner diameter is varied from 0 to 190 nm to accommodate wide range of samples from nanodisk to thin nanorings. Micromagnetic simulation of in-plane hysteresis curve of these nanorings reveals that the magnetic properties change gradually with the change of inner diameter. The hysteresis loss indicated by the area of the hysteresis loop, increases gradually with the increase in inner radius up to d in = 174 nm. For inner diameter of 176 nm, the loop area decreases drastically and remains so for up to d in = 180 nm. After that, a small increment of d in results in a large increment of loop area. The remanent states are found to be vortex states for d in = 0-180 nm and onion states for d in > 180 nm. The changes are attributed to two parameters mainly: exchange energy and demagnetization energy. These two parameters depend on inner curvature of the ring, which is treated as a variable in this simulation work. The changes in loop area have been discussed in light of variation of these parameters.

  6. Lift hysteresis at stall as an unsteady boundary-layer phenomenon

    NASA Technical Reports Server (NTRS)

    Moore, Franklin K

    1956-01-01

    Analysis of rotating stall of compressor blade rows requires specification of a dynamic lift curve for the airfoil section at or near stall, presumably including the effect of lift hysteresis. Consideration of the magnus lift of a rotating cylinder suggests performing an unsteady boundary-layer calculation to find the movement of the separation points of an airfoil fixed in a stream of variable incidence. The consideration of the shedding of vorticity into the wake should yield an estimate of lift increment proportional to time rate of change of angle of attack. This increment is the amplitude of the hysteresis loop. An approximate analysis is carried out according to the foregoing ideas for a 6:1 elliptic airfoil at the angle of attack for maximum lift. The assumptions of small perturbations from maximum lift are made, permitting neglect of distributed vorticity in the wake. The calculated hysteresis loop is counterclockwise. Finally, a discussion of the forms of hysteresis loops is presented; and, for small reduced frequency of oscillation, it is concluded that the concept of a viscous "time lag" is appropriate only for harmonic variations of angle of attack with time at mean conditions other than maximum lift.

  7. Hysteresis and calcium set-point for the calcium parathyroid hormone relationship in healthy horses.

    PubMed

    Toribio, Ramiro E; Kohn, Catherine W; Sams, Richard A; Capen, Charles C; Rosol, Thomas J

    2003-02-15

    Abnormalities in calcium (Ca(2+)) homeostasis are reported in horses with several pathological conditions; however, there is little information on Ca(2+) regulation in horses. The objectives of the present study were to determine the Ca(2+) set-point in healthy horses, to determine whether the Ca(2+)/parathyroid hormone (PTH) response curves were characterized by hysteresis, and to determine if the order of experimentally induced hypocalcemia or hypercalcemia had an effect on PTH secretion. The Ca(2+) set-point and hysteresis were determined in 12 healthy horses by infusing Na(2)EDTA and calcium gluconate. The Ca(2+) set-point was 1.37 +/- 0.05 mmol/L, which is higher than values reported for humans and dogs (1.0-1.2 mmol/L). Hysteresis was present during hypocalcemia and hypercalcemia. Horses in which hypocalcemia was followed by hypercalcemia secreted more PTH (7440 +/- 740 pmol min/L) than horses in which hypercalcemia was followed by hypocalcemia (5990 +/- 570 pmol min/L). This study has demonstrated that the Ca(2+) set-point in the horse is higher than in other domestic animals and man. We have shown that the Ca(2+)/PTH relationship in horses is sigmoidal and displays hysteresis during both hypocalcemia and hypercalcemia, and that extracellular Ca(2+) concentrations may affect the response of the parathyroid gland to hypocalcemia.

  8. On the hysteresis of argon adsorption in a uniform closed end slit pore.

    PubMed

    Fan, Chunyan; Do, D D; Nicholson, D

    2013-09-01

    We present a molecular simulation study of adsorption and desorption in slit mesopores of uniform width with one end closed and explore the effects of pore dimensions (width and length), temperature and surface affinity on the hysteresis loop: its position, lower and upper closure points, area and shape. Our results show that the metastability, brought about by structural change in the adsorbate, is the reason for the existence of hysteresis, and contrast with reports suggesting that reversibility invariably prevails for adsorption in closed end pores. The shape, area and position of the hysteresis loop are complex functions of pore width, length and temperature. We establish a parametric map of the boundary separating reversible and hysteretic regions. Our simulation results also show a number of interesting observations that have not been previously reported or generally recognised: (1) the fluid within the core of the pore behaves like a bulk liquid as the pore is progressively filled, via the movement of the meniscus from the closed end to the pore mouth, but as the pore fills, the fluid in the core becomes structured, (2) the shape of the meniscus changes as adsorption progresses but is constant during desorption because of the constant thickness of the adsorbed layer in the two-phase region, (3) the hysteresis loop is larger for a longer pore, (4) the area of the hysteresis loop increases with pore width up to a certain width, beyond which it decreases and finally disappears, (5) as temperature approaches the critical hysteresis temperature, the hysteresis loop area decreases, but it retains its Type H1 character.

  9. Power laws in the dynamic hysteresis of quantum nonlinear photonic resonators

    NASA Astrophysics Data System (ADS)

    Casteels, W.; Storme, F.; Le Boité, A.; Ciuti, C.

    2016-03-01

    We explore theoretically the physics of dynamic hysteresis for driven-dissipative nonlinear photonic resonators. In the regime where the semiclassical mean-field theory predicts bistability, the exact steady-state density matrix is known to be unique, being a statistical mixture of two states; in particular, no static hysteresis cycle of the excited population occurs as a function of the driving intensity. Here, we predict that in the quantum regime a dynamic hysteresis with a rich phenomenology does appear when sweeping the driving amplitude in a finite time. The hysteresis area as a function of the sweep time reveals a double power-law decay, with a behavior qualitatively different from the mean-field predictions. The dynamic hysteresis power-law in the slow sweep limit defines a characteristic time, which depends dramatically on the size of the nonlinearity and on the frequency detuning between the driving and the resonator. In the strong nonlinearity regime, the characteristic time oscillates as a function of the intrinsic system parameters due to multiphotonic resonances. We show that the dynamic hysteresis for the considered class of driven-dissipative systems is due to a nonadiabatic response region with connections to the Kibble-Zurek mechanism for quenched phase transitions. We also consider the case of two coupled driven-dissipative nonlinear resonators, showing that dynamic hysteresis and power-law behavior occur also in the presence of correlations between resonators. Our theoretical predictions can be explored in a broad variety of physical systems, e.g., circuit QED superconducting resonators and semiconductor optical microcavities.

  10. Study of contact angle hysteresis using the Cellular Potts Model.

    PubMed

    Mortazavi, Vahid; D'Souza, Roshan M; Nosonovsky, Michael

    2013-02-28

    We use the Cellular Potts Model (CPM) to study the contact angle (CA) hysteresis in multiphase (solid-liquid-vapour) systems. We simulate a droplet over the tilted patterned surface, and a bubble placed under the surface immersed in liquid. The difference between bubbles and droplets was discussed through their CA hysteresis. Dependency of CA hysteresis on the surface structure and other parameters was also investigated. This analysis allows decoupling of the 1D (pinning of the triple line) and 2D (adhesion hysteresis in the contact area) effects and provides new insight into the nature of CA hysteresis.

  11. Origin of hysteresis in bed form response to unsteady flows

    NASA Astrophysics Data System (ADS)

    Martin, Raleigh L.; Jerolmack, Douglas J.

    2013-03-01

    Field and laboratory studies indicate that changes in riverbed morphology often lag changes in water discharge. This lagged response produces hysteresis in the relationship between water discharge and bed form geometry. To understand these phenomena, we performed flume experiments to observe the response of a sand bed to step increases and decreases in water discharge. For an abrupt rise in discharge, we observed that bed forms grew rapidly by collision and merger of bed forms migrating with different celerities. Growth rate slowed as bed forms approached equilibrium with the higher discharge regime. After an abrupt discharge drop, bed form decay occurred through formation of smaller secondary bed forms, in equilibrium with the lower discharge, which cannibalized the original, relict features. We present a simple model framework to quantitatively predict time scales of bed form adjustment to flow changes, based on equilibrium bed form heights, lengths, and celerities at low and high flows. For rising discharge, the model assumes that all bed form collisions result in irreversible merger, due to a dispersion of initial celerities. For falling discharge, we derive a diffusion model for the decay of relict high-stage features. Our models predict the form and time scale of experimental bed form adjustments. Additional experiments applying slow and fast triangular flood waves show that bed form hysteresis occurs only when the time scale of flow change is faster than the modeled (and measured) bed form adjustment time. We show that our predicted adjustment time scales can also be used to predict the occurrence of bed form hysteresis in natural floods.

  12. Two phase flow of liquids in a narrow gap: Phase interference and hysteresis

    NASA Astrophysics Data System (ADS)

    Raza, Salim; Hejazi, S. Hossein; Gates, Ian D.

    2016-07-01

    Co-current flow of two immiscible liquids, such as oil and water in a planar fracture, exhibits nonlinear structures which become important in many natural and engineering systems such as subsurface flows, multiphase flows in lubrication joints, and coating flows. In this context, co-current flow of oil and water with variable rates is experimentally studied in a Hele-Shaw cell, various flow regimes are classified, and relative permeabilities for the phases are analysed thoroughly. Similar to multiphase pipe flows, multiphase flow in planar gaps shows various flow regimes, each having different flow rate/pressure gradient behaviour. As well as recovering the known results in the immiscible displacements in Hele-Shaw cell where the fluid-fluid interface remains stable/unstable for favorable/adverse viscosity ratios, it is found that the co-current flow of two fluids with different viscosities results in three distinct flow regimes. Before breakthrough of non-wetting phase, i.e, water, a "linear displacement" flow regime initially establishes at very low water injection rates. This stable movement turns into a "fingering advancement" flow regime at high water flow rates and Saffman-Taylor instability develops normal to the direction of the flow. After the breakthrough, a "droplet formation" flow regime is identified where the droplets of wetting phase, oil, are trapped in the water phase. For subsurface flow applications, we quantify these regimes through relative permeability curves. It is reported that as the water flow rate increases, the relative permeabilities and flow channels become smooth and regular. This behaviour of relative permeability and saturations shows dominance of capillary forces at low flow rates and viscous forces at higher flow rates. Variable injection rates provide the interface structures for both drainage and imbibition process, where the wetting phase saturation decreases and increases respectively. It is shown that relative permeability

  13. Wetting Hysteresis at the Molecular Scale

    NASA Technical Reports Server (NTRS)

    Jin, Wei; Koplik, Joel; Banavar, Jayanth R.

    1996-01-01

    The motion of a fluid-fluid-solid contact line on a rough surface is well known to display hysteresis in the contact angle vs. velocity relationship. In order to understand the phenomenon at a fundamental microscopic level, we have conducted molecular dynamics computer simulations of a Wilhelmy plate experiment in which a solid surface is dipped into a liquid bath, and the force-velocity characteristics are measured. We directly observe a systematic variation of force and contact angle with velocity, which is single-valued for the case of an atomically smooth solid surface. In the microscopically rough case, however, we find (as intuitively expected) an open hysteresis loop. Further characterization of the interface dynamics is in progress.

  14. Magnetic hysteresis of limestones: facies control?

    NASA Astrophysics Data System (ADS)

    Borradaile, Graham J.; Chow, Nancy; Werner, Tomasz

    1993-03-01

    The hysteresis properties of 116 non-red, marine limestones from 92 localities indicate that remanence is carried by magnetite of pseudo-single-domain (PSD) and small multidomain (MD) size. Pelagic limestones have paramagnetic matrices and hysteresis properties compatible with larger PSD or MD grain sizes of magnetite, probably associated with detrital clay minerals introduced by pelagic rain-out. Thus they may be less suitable recorders of stable remanence. Other limestone facies (excepting dolomitized examples) have diamagnetic matrices. They include shallow—subtidal limestones which tend to have smaller PSD sizes of magnetite, as do backreef—lagoonal, undifferentiated-shelf and reef facies. It is believed that the wide geographical and temporal range of samples minimizes effects related to post-compaction groundwater flow (late diagenesis) and that the associations recognized should be tested in future studies.

  15. Highly curved microchannel plates

    NASA Technical Reports Server (NTRS)

    Siegmund, O. H. W.; Cully, S.; Warren, J.; Gaines, G. A.; Priedhorsky, W.; Bloch, J.

    1990-01-01

    Several spherically curved microchannel plate (MCP) stack configurations were studied as part of an ongoing astrophysical detector development program, and as part of the development of the ALEXIS satellite payload. MCP pairs with surface radii of curvature as small as 7 cm, and diameters up to 46 mm have been evaluated. The experiments show that the gain (greater than 1.5 x 10 exp 7) and background characteristics (about 0.5 events/sq cm per sec) of highly curved MCP stacks are in general equivalent to the performance achieved with flat MCP stacks of similar configuration. However, gain variations across the curved MCP's due to variations in the channel length to diameter ratio are observed. The overall pulse height distribution of a highly curved surface MCP stack (greater than 50 percent FWHM) is thus broader than its flat counterpart (less than 30 percent). Preconditioning of curved MCP stacks gives comparable results to flat MCP stacks, but it also decreases the overall gain variations. Flat fields of curved MCP stacks have the same general characteristics as flat MCP stacks.

  16. The hysteresis response of soil respiration and soil CO2 concentration to soil temperature

    NASA Astrophysics Data System (ADS)

    Zhang, Q., Sr.; Katul, G. G.; Oren, R.; Daly, E.; Manzoni, S.; Yang, D.

    2015-12-01

    Diurnal hysteresis between soil temperature (Ts) and both CO2 concentration ([CO2]) and soil respiration rate (Rs) were reported across different field experiments. However, the causes of these hysteresis patterns remain a subject of debate, with biotic and abiotic factors both invoked as explanations. To address these issues, a CO2 gas transport model is developed by combining layer-wise mass conservation for subsurface gas-phase CO2, Fickian diffusion for gas transfer, and a CO2 source term that depends on soil temperature, moisture, and photosynthetic rate. Using this model, a hierarchy of numerical experiments were employed to disentangle the causes of the hysteretic [CO2]-Ts and CO2 flux-Ts (i.e., F -Ts) relations. Model results show that gas transport alone can introduce both [CO2]-Ts and F-Ts hysteresis, and also confirm prior findings that heat flow in soils lead to [CO2] and F(z) being out of phase with Ts, thereby providing another reason for the occurrence of both hysteresis. The area (Ahys) of the [CO2]-Ts hysteresis near the surface increases, while the Ahys of the Rs-Ts hysteresis decreases as soils become wetter. Moreover, a time-lagged carbon input from photosynthesis deformed the [CO2]-Ts and Rs-Ts patterns, causing a change in the loop direction from counterclockwise to clockwise with decreasing time lag. An asymmetric 8-shaped pattern emerged as the transition state between the two loop directions. Tracing the pattern and direction of the hysteretic [CO2]-Ts and Rs-Ts relations can provide new ways to fingerprint the effects of photosynthesis stimulation on soil microbial activity and detect the corresponding time lags. Key words: Hysteresis; Photosynthesis; Soil CO2 concentration; Soil respiration; Soil temperature; Soil moisture

  17. Modulating contact angle hysteresis to direct fluid droplets along a homogenous surface.

    PubMed

    Luo, Mingxiang; Gupta, Rohini; Frechette, Joelle

    2012-02-01

    The shape and motion of drops on surfaces is governed by the balance between the driving and the pinning forces. Here we demonstrate control over the motion of droplets on an inclined surface by exerting control over the contact angle hysteresis. The external modulation of contact angle hysteresis is achieved through a voltage-induced local molecular reorganization within the surface film at the solid-liquid interface. We show that tuning contact angle hysteresis alone is sufficient to direct and deform drops when subjected to a constant external driving force, here gravity, in the absence of a pre-defined surface energy gradient or pattern. We also show that the observed stretching and contraction of the drops mimic the motion of an inchworm. Such reversible manipulation of the pinning forces could be an attractive means to direct drops, especially with the dominance of surface forces at micro-/nanoscale.

  18. "The Show"

    ERIC Educational Resources Information Center

    Gehring, John

    2004-01-01

    For the past 16 years, the blue-collar city of Huntington, West Virginia, has rolled out the red carpet to welcome young wrestlers and their families as old friends. They have come to town chasing the same dream for a spot in what many of them call "The Show". For three days, under the lights of an arena packed with 5,000 fans, the…

  19. Interactive effect of hysteresis and surface chemistry on gated silicon nanowire gas sensors.

    PubMed

    Paska, Yair; Haick, Hossam

    2012-05-01

    Gated silicon nanowire gas sensors have emerged as promising devices for chemical and biological sensing applications. Nevertheless, the performance of these devices is usually accompanied by a "hysteresis" phenomenon that limits their performance under real-world conditions. In this paper, we use a series of systematically changed trichlorosilane-based organic monolayers to study the interactive effect of hysteresis and surface chemistry on gated silicon nanowire gas sensors. The results show that the density of the exposed or unpassivated Si-OH groups (trap states) on the silicon nanowire surface play by far a crucial effect on the hysteresis characteristics of the gated silicon nanowire sensors, relative to the effect of hydrophobicity or molecular density of the organic monolayer. Based on these findings, we provide a tentative model-based understanding of (i) the relation between the adsorbed organic molecules, the hysteresis, and the related fundamental parameters of gated silicon nanowire characteristics and of (ii) the relation between the hysteresis drift and possible screening effect on gated silicon nanowire gas sensors upon exposure to different analytes at real-world conditions. The findings reported in this paper could be considered as a launching pad for extending the use of the gated silicon nanowire gas sensors for discriminations between polar and nonpolar analytes in complex, real-world gas mixtures.

  20. Comparison of contact angle hysteresis of different probe liquids on the same solid surface.

    PubMed

    Chibowski, Emil; Jurak, Malgorzata

    2013-02-01

    Advancing and receding contact angles of water, formamide and diiodomethane were measured on 1,2-dipalmitoyl-sn-glycero-3-phosphocholine (DPPC) layers deposited on three different solid supports-glass, mica and poly(methyl methacrylate). Up to five statistical monolayers were deposited on the surfaces by spreading DPPC solution. It was found that even on five statistical DPPC monolayers, the hysteresis of a given liquid depends on the kind of solid support. Also on the same solid support the contact angle hysteresis is different for each probe liquid used. The AFM images show that the heights of roughness of the DPPC films cannot be the primary cause of the observed hysteresis because the heights are too small to cause the observed hystereses. It is believed that the hysteresis is due to the liquid film present right behind the three-phase solid surface/liquid drop/gas (vapour) contact line and the presence of Derjaguin pressure. The value of contact angle hysteresis depends on both the solid surface and liquid properties as well as on intermolecular interactions between them.

  1. CURVES: curve evolution for vessel segmentation.

    PubMed

    Lorigo, L M; Faugeras, O D; Grimson, W E; Keriven, R; Kikinis, R; Nabavi, A; Westin, C F

    2001-09-01

    The vasculature is of utmost importance in neurosurgery. Direct visualization of images acquired with current imaging modalities, however, cannot provide a spatial representation of small vessels. These vessels, and their branches which show considerable variations, are most important in planning and performing neurosurgical procedures. In planning they provide information on where the lesion draws its blood supply and where it drains. During surgery the vessels serve as landmarks and guidelines to the lesion. The more minute the information is, the more precise the navigation and localization of computer guided procedures. Beyond neurosurgery and neurological study, vascular information is also crucial in cardiovascular surgery, diagnosis, and research. This paper addresses the problem of automatic segmentation of complicated curvilinear structures in three-dimensional imagery, with the primary application of segmenting vasculature in magnetic resonance angiography (MRA) images. The method presented is based on recent curve and surface evolution work in the computer vision community which models the object boundary as a manifold that evolves iteratively to minimize an energy criterion. This energy criterion is based both on intensity values in the image and on local smoothness properties of the object boundary, which is the vessel wall in this application. In particular, the method handles curves evolving in 3D, in contrast with previous work that has dealt with curves in 2D and surfaces in 3D. Results are presented on cerebral and aortic MRA data as well as lung computed tomography (CT) data.

  2. A supply-based concentration rating curve to predict total phosphorus concentrations in the Rhine River

    NASA Astrophysics Data System (ADS)

    Van der Perk, M.; Vogels, M. F. A.

    2012-04-01

    Concentration rating curves are useful for the analysis of the response of sediment or solute concentrations to changes in stream discharge or for the interpolation of infrequent concentration measurements in time with discharge as auxiliary variable, for example to estimate annual sediment or solute loads. A known limitation of rating curves is that their performance is generally poor, which can be partly attributed to the fact that rating curve methods neglect the hysteresis effects in the concentration response to changes in discharge. To enhance the performance of rating curve models, they should account for these hysteresis effects. Here, we present a supply-based concentration rating curve for total phosphorus concentrations in the Rhine River, the Netherlands, which does account for the above hysteresis effects. The supply-based concentration rating curve has four components: 1) The traditional power law rating curve of the form C = a Qb where C is the phosphorus concentration [M L-3], Qis the river discharge [L T-1], and a and b are constants [-]; 2) A long-term linear trend; 3) A seasonal trend of the form C(t) = Acos [2π(t - Tk)/T] where A is the concentration amplitude [M L-3], t is the time (T), Tk is the phase shift (T), and T is the period [T] (365.25 d). 4) A discharge dependent supply or loss term of the form C = -ΔS/(QΔt), where S is the phosphorus stock [M]. The phosphorus stock was assumed to increase linearly during periods of deposition, i.e. the discharge is below a critical discharge. If the discharge is greater than the critical discharge during a sufficiently long period (> 16 days), the decrease in phosphorus stock was assumed to be proportional to the excess discharge above the critical discharge. For model parameterization and calibration, we used the daily Aqualarm data of total phosphorus concentrations and the Waterbase data of water discharge measured daily by Rijkswaterstaat (Dutch Ministry of Infrastructure and the Environment

  3. Apparent contact angle and contact angle hysteresis on liquid infused surfaces

    NASA Astrophysics Data System (ADS)

    Semprebon, Ciro; McHale, Glen; Kusumaatmaja, Halim

    We theoretically investigate the apparent contact angle and contact angle hysteresis of a droplet placed on a liquid infused surface. We show that the apparent contact angle is not uniquely defined by material parameters, but also has a strong dependence on the relative size between the droplet and its surrounding wetting ridge formed by the infusing liquid. We derive a closed form expression for the contact angle in the limit of vanishing wetting ridge, and compute the correction for small but finite ridge, which corresponds to an effective line tension term. We also predict contact angle hysteresis on liquid infused surfaces generated by the pinning of the contact lines by the surface corrugations. Our analytical expressions for both the apparent contact angle and contact angle hysteresis can be interpreted as `weighted sums' between the contact angles of the infusing liquid relative to the droplet and surrounding gas phases, where the weighting coefficients are given by ratios of the fluid surface tensions.

  4. Apparent contact angle and contact angle hysteresis on liquid infused surfaces.

    PubMed

    Semprebon, Ciro; McHale, Glen; Kusumaatmaja, Halim

    2016-12-21

    We theoretically investigate the apparent contact angle and contact angle hysteresis of a droplet placed on a liquid infused surface. We show that the apparent contact angle is not uniquely defined by material parameters, but also has a dependence on the relative size between the droplet and its surrounding wetting ridge formed by the infusing liquid. We derive a closed form expression for the contact angle in the limit of vanishing wetting ridge, and compute the correction for small but finite ridge, which corresponds to an effective line tension term. We also predict contact angle hysteresis on liquid infused surfaces generated by the pinning of the contact lines by the surface corrugations. Our analytical expressions for both the apparent contact angle and contact angle hysteresis can be interpreted as 'weighted sums' between the contact angles of the infusing liquid relative to the droplet and surrounding gas phases, where the weighting coefficients are given by ratios of the fluid surface tensions.

  5. Magnetostrictive and Kinematic Model Considering the Dynamic Hysteresis and Energy Loss for GMA

    NASA Astrophysics Data System (ADS)

    LIU, Huifang; SUN, Xingwei; GAO, Yifei; WANG, Hanyu; GAO, Zijin

    2017-03-01

    Due to the influence of magnetic hysteresis and energy loss inherent in giant magnetostrictive materials (GMM), output displacement accuracy of giant magnetostrictive actuator (GMA) can not meet the precision and ultra precision machining. Using a GMM rod as the core driving element, a GMA which may be used in the field of precision and ultra precision drive engineering is designed through modular design method. Based on the Armstrong theory and elastic Gibbs free energy theory, a nonlinear magnetostriction model which considers magnetic hysteresis and energy loss characteristics is established. Moreover, the mechanical system differential equation model for GMA is established by utilizing D'Alembert's principle. Experimental results show that the model can preferably predict magnetization property, magnetic potential orientation, energy loss for GMM. It is also able to describe magnetostrictive elongation and output displacement of GMA. Research results will provide a theoretical basis for solving the dynamic magnetic hysteresis, energy loss and working precision for GMA fundamentally.

  6. Magnetic hysteresis, compensation behaviors, and phase diagrams of bilayer honeycomb lattices

    NASA Astrophysics Data System (ADS)

    Ersin, Kantar

    2015-10-01

    Magnetic behaviors of the Ising system with bilayer honeycomb lattice (BHL) structure are studied by using the effective-field theory (EFT) with correlations. The effects of the interaction parameters on the magnetic properties of the system such as the hysteresis and compensation behaviors as well as phase diagrams are investigated. Moreover, when the hysteresis behaviors of the system are examined, single and double hysteresis loops are observed for various values of the interaction parameters. We obtain the L-, Q-, P-, and S-type compensation behaviors in the system. We also observe that the phase diagrams only exhibit the second-order phase transition. Hence, the system does not show the tricritical point (TCP).

  7. Dissipative particle dynamics simulation of contact angle hysteresis on a patterned solid/air composite surface.

    PubMed

    Kong, Bin; Yang, Xiaozhen

    2006-02-28

    We have studied two types of topological substrates--the continuous solid substrates (CSS) and the discontinuous solid substrates (DSS)--by using the dissipative particle dynamics (DPD) method for a better understanding of the contact angle hysteresis on two such substrates. After the validation of DPD in the system, we found that DSS has a different distribution of the metastable states from that of CSS and that DSS has relatively larger contact angle hysteresis at lower temperature. Obtained results also show that CSS is more suitable for making an ultrahydrophobic or ultralyophobic surface than DSS from the point of view of dynamic wettability.

  8. Simulation of magnetic hysteresis loops and magnetic Barkhausen noise of α-iron containing nonmagnetic particles

    SciTech Connect

    Li, Yi; Xu, Ben; Hu, Shenyang Y.; Li, Yulan; Li, Qiulin; Liu, Wei

    2015-09-25

    Hysteresis loops and Magnetic Barkhausen Noise in a single crystal α-iron containing a nonmagnetic particle were simulated based on the Laudau-Lifshitz-Gilbert equation. The analyses of domain morphologies and hysteresis loops show that reversal magnetization process is control by nucleation of reversed domains at nonmagnetic particle when the particle size reaches a particle value. In such a situation, the value of nucleation field is determined by the size of nonmagnetic particles, and moreover, coercive field and Magnetic Barkhausen Noise signal are strongly affected by the nucleation field of reversed domains.

  9. Extension of hysteresis operators of Preisach-type to real, Lebesgue measurable functions

    NASA Astrophysics Data System (ADS)

    Iyer, R.; Ekanayake, D.

    2008-02-01

    Functions in Llocp[0,∞) where 1⩽p⩽∞ can be considered as inputs to linear systems. However, hysteresis operators of Preisach type have only been defined on much smaller space of regulated (or Baire) functions. In this paper, we re-define Play operators so that they are well defined for real valued measurable functions. We show that this definition coincides with the older definition for continuous and regulated functions on an interval. Domain extension of hysteresis operators of Preisach type to real, Lebesgue measurable functions is then obtained in the standard manner using the re-defined Play operators.

  10. Research on transient hysteresis current control strategy of DC-DC converter

    NASA Astrophysics Data System (ADS)

    Zhang, Ting; Wang, Zu-liang; Zhao, Yu-kai

    2017-01-01

    In order to improve the dynamic performance of DC-DC converter, transient hysteresis current control strategy is proposed which is based on parallel computing and combinational logic. By making a comparison between the real-time inductor current and the threshold inductor current, the switch is controlled more accurately. Under the Matlab/Simulink environment, the process of the Buck-Boost converter was simulated. The simulation results show that the transient hysteresis current control strategy can effectively overcome the disadvantages when load changes or input voltage disturbance occurs, it posses high load regulation and short dynamic response time, and it verifies the feasibility of the proposed strategy.

  11. Conformational Electroresistance and Hysteresis in Nanoclusters

    DOE PAGES

    Li, Xiangguo; Zhang, Xiaoguang; Cheng, Hai-Ping

    2014-07-02

    Among many mechanisms proposed for electroresistance, ones involving structural changes are the least understood because of challenges of controllability and repeatability. Yet structural changes can cause dramatic changes in electronic properties, leading to multiple ways in which conduction paths can be opened and closed, not limited to filament movement or variation in molecular conductance. Here we show at least another way: conformational dependence of the Coulomb charging energy of a nanocluster, where charging induced conformational distortion changes the blockade voltage, which in turn leads to a giant electroresistance. This intricate interplay between charging and conformation change is demonstrated in amore » nanocluster Zn3O4 by combining a first-principles calculation with a temperature dependent transport model. The predicted hysteretic Coulomb blockade staircase in the current-voltage curve adds another dimension to the rich phenomenon of tunneling electroresistance. The new mechanism also provides a better controlled and repeatable platform to study conformational electroresistance.« less

  12. Conformational Electroresistance and Hysteresis in Nanoclusters

    SciTech Connect

    Li, Xiangguo; Zhang, Xiaoguang; Cheng, Hai-Ping

    2014-07-02

    Among many mechanisms proposed for electroresistance, ones involving structural changes are the least understood because of challenges of controllability and repeatability. Yet structural changes can cause dramatic changes in electronic properties, leading to multiple ways in which conduction paths can be opened and closed, not limited to filament movement or variation in molecular conductance. Here we show at least another way: conformational dependence of the Coulomb charging energy of a nanocluster, where charging induced conformational distortion changes the blockade voltage, which in turn leads to a giant electroresistance. This intricate interplay between charging and conformation change is demonstrated in a nanocluster Zn3O4 by combining a first-principles calculation with a temperature dependent transport model. The predicted hysteretic Coulomb blockade staircase in the current-voltage curve adds another dimension to the rich phenomenon of tunneling electroresistance. The new mechanism also provides a better controlled and repeatable platform to study conformational electroresistance.

  13. Hysteresis in voltage-gated channels.

    PubMed

    Villalba-Galea, Carlos A

    2016-09-30

    Ion channels constitute a superfamily of membrane proteins found in all living creatures. Their activity allows fast translocation of ions across the plasma membrane down the ion's transmembrane electrochemical gradient, resulting in a difference in electrical potential across the plasma membrane, known as the membrane potential. A group within this superfamily, namely voltage-gated channels, displays activity that is sensitive to the membrane potential. The activity of voltage-gated channels is controlled by the membrane potential, while the membrane potential is changed by these channels' activity. This interplay produces variations in the membrane potential that have evolved into electrical signals in many organisms. These signals are essential for numerous biological processes, including neuronal activity, insulin release, muscle contraction, fertilization and many others. In recent years, the activity of the voltage-gated channels has been observed not to follow a simple relationship with the membrane potential. Instead, it has been shown that the activity of voltage-gated channel displays hysteresis. In fact, a growing number of evidence have demonstrated that the voltage dependence of channel activity is dynamically modulated by activity itself. In spite of the great impact that this property can have on electrical signaling, hysteresis in voltage-gated channels is often overlooked. Addressing this issue, this review provides examples of voltage-gated ion channels displaying hysteretic behavior. Further, this review will discuss how Dynamic Voltage Dependence in voltage-gated channels can have a physiological role in electrical signaling. Furthermore, this review will elaborate on the current thoughts on the mechanism underlying hysteresis in voltage-gated channels.

  14. Influence of hysteresis on groundwater wave dynamics in an unconfined aquifer with a sloping boundary

    NASA Astrophysics Data System (ADS)

    Shoushtari, Seyed Mohammad Hossein Jazayeri; Cartwright, Nick; Perrochet, Pierre; Nielsen, Peter

    2015-12-01

    In this paper, the influence of hysteresis on water table dynamics in an unconfined aquifer was examined using a numerical model to solve Richards' unsaturated flow equation. The model was subject to simple harmonic forcing across a sloping boundary with a seepage face boundary condition. Time series from both hysteretic and non-hysteretic models were subject to harmonic analysis to extract the amplitude and phase profiles for comparison with existing sand flume data (Cartwright et al., 2004). The results from both model types show good agreement with the data indicating no influence of hysteresis at the oscillation period examined (T = 348 s). The models were then used to perform a parametric study to examine the relationship between oscillation period and hysteresis effects with periods ranging from 3 min to 180 min. At short oscillation periods, (T ≈ 180 s) the effects of hysteresis were negligible with both models providing similar results. As the oscillation period increased, the hysteretic model showed less amplitude damping than the non-hysteretic model. For periods greater than T = 60 min, the phase lag in the non-hysteretic model is greater than for the hysteretic one. For periods less than T = 60 min this trend is reversed and the hysteretic model produced a greater phase lag than the non-hysteretic model. These findings suggest that consideration of hysteresis dynamics in Richards' equation models has no influence on water table wave dispersion for short period forcing such as waves (T ≈ 10 s) whereas for long period forcing such as tides (T ≈ 12.25 h) or storm surges (T ≈ days) hysteresis dynamics should be taken into account.

  15. Archimedes Curves

    ERIC Educational Resources Information Center

    Swain, Gordon A.

    2013-01-01

    We show that inside every triangle the locus of points satisfying a natural proportionality relationship is a parabola and go on to describe how this triangle-parabola relationship was used by Archimedes to find the area between a line and a parabola.

  16. Hysteresis prediction inside magnetic shields and application

    SciTech Connect

    Morić, Igor; De Graeve, Charles-Marie; Grosjean, Olivier; Laurent, Philippe

    2014-07-15

    We have developed a simple model that is able to describe and predict hysteresis behavior inside Mumetal magnetic shields, when the shields are submitted to ultra-low frequency (<0.01 Hz) magnetic perturbations with amplitudes lower than 60 μT. This predictive model has been implemented in a software to perform an active compensation system. With this compensation the attenuation of longitudinal magnetic fields is increased by two orders of magnitude. The system is now integrated in the cold atom space clock called PHARAO. The clock will fly onboard the International Space Station in the frame of the ACES space mission.

  17. Hysteresis prediction inside magnetic shields and application.

    PubMed

    Morić, Igor; De Graeve, Charles-Marie; Grosjean, Olivier; Laurent, Philippe

    2014-07-01

    We have developed a simple model that is able to describe and predict hysteresis behavior inside Mumetal magnetic shields, when the shields are submitted to ultra-low frequency (<0.01 Hz) magnetic perturbations with amplitudes lower than 60 μT. This predictive model has been implemented in a software to perform an active compensation system. With this compensation the attenuation of longitudinal magnetic fields is increased by two orders of magnitude. The system is now integrated in the cold atom space clock called PHARAO. The clock will fly onboard the International Space Station in the frame of the ACES space mission.

  18. Fingerprint image enhancement by differential hysteresis processing.

    PubMed

    Blotta, Eduardo; Moler, Emilce

    2004-05-10

    A new method to enhance defective fingerprints images through image digital processing tools is presented in this work. When the fingerprints have been taken without any care, blurred and in some cases mostly illegible, as in the case presented here, their classification and comparison becomes nearly impossible. A combination of spatial domain filters, including a technique called differential hysteresis processing (DHP), is applied to improve these kind of images. This set of filtering methods proved to be satisfactory in a wide range of cases by uncovering hidden details that helped to identify persons. Dactyloscopy experts from Policia Federal Argentina and the EAAF have validated these results.

  19. Mechano-electric optoisolator transducer with hysteresis

    NASA Astrophysics Data System (ADS)

    Ciuruş, I. M.; Dimian, M.; Graur, A.

    2011-01-01

    This article presents a theoretical and experimental study of designing a mechano-electric optoisolator transducer with hysteresis. Our research is centred upon designing transducers on the basis of optical sensors, as photoelectric conversions eliminate the influence of electromagnetic disturbances. Conversion of the rotation/translation motions into electric signals is performed with the help of a LED-photoresistor Polaroid optocoupler. The driver of the optocoupler's transmitter module is an independent current source. The signal conditioning circuit is a Schmitt trigger circuit. The device is designed to be applied in the field of automation and mechatronics.

  20. Contact angle hysteresis on randomly rough surfaces: a computational study.

    PubMed

    David, Robert; Neumann, A Wilhelm

    2013-04-09

    Wetting is important in many applications, and the solid surfaces being wet invariably feature some amount of surface roughness. A free energy-based computational simulation is used to study the effect of roughness on wetting and especially contact angle hysteresis. On randomly rough, self-affine surfaces, it is found that hysteresis depends primarily on the value of the Wenzel roughness parameter r, increasing in proportion with r - 1. Micrometer-level roughness causes hysteresis of a few degrees.

  1. Method and apparatus for sub-hysteresis discrimination

    DOEpatents

    De Geronimo, Gianluigi

    2015-12-29

    Embodiments of comparator circuits are disclosed. A comparator circuit may include a differential input circuit, an output circuit, a positive feedback circuit operably coupled between the differential input circuit and the output circuit, and a hysteresis control circuit operably coupled with the positive feedback circuit. The hysteresis control circuit includes a switching device and a transistor. The comparator circuit provides sub-hysteresis discrimination and high speed discrimination.

  2. THE EFFECT OF LIQUID STRUCTURE ON CONTACT ANGLE HYSTERESIS

    DTIC Science & Technology

    Contact angle hysteresis was measured for a variety of liquids on condensed monolayers of 17-(perfluoroheptyl)-heptadecanoic acid adsorbed on...into the porous monolayer. However, contact angle hysteresis was negligible when the average diameter of the liquid molecules was larger than the...monolayers by contact angle hysteresis measurements on a series of liquids having gradations in molecular volume. The results of this investigation

  3. On the rationale for hysteresis in economic decisions

    NASA Astrophysics Data System (ADS)

    Rios, Luis A.; Rachinskii, Dmitrii; Cross, Rod

    2017-02-01

    In the social sciences there are plausible reasons to postulate that hysteresis effects are important. The available evidence, however, is predominantly at the macro level. In this paper we review the evidence regarding hysteresis in the neural processes underlying human behavior. We argue that there is a need for experimental and neuroimaging studies to fill the gap in knowledge about hysteresis processes at the micro level in the social sciences.

  4. Dynamic hysteresis modeling including skin effect using diffusion equation model

    NASA Astrophysics Data System (ADS)

    Hamada, Souad; Louai, Fatima Zohra; Nait-Said, Nasreddine; Benabou, Abdelkader

    2016-07-01

    An improved dynamic hysteresis model is proposed for the prediction of hysteresis loop of electrical steel up to mean frequencies, taking into account the skin effect. In previous works, the analytical solution of the diffusion equation for low frequency (DELF) was coupled with the inverse static Jiles-Atherton (JA) model in order to represent the hysteresis behavior for a lamination. In the present paper, this approach is improved to ensure the reproducibility of measured hysteresis loops at mean frequency. The results of simulation are compared with the experimental ones. The selected results for frequencies 50 Hz, 100 Hz, 200 Hz and 400 Hz are presented and discussed.

  5. Correct Determination of Hysteresis of Nonlinear Current-Voltage Characteristics of Spin Valves, Magnetic Tunnel Junctions, or Memristors

    NASA Astrophysics Data System (ADS)

    Demidov, E. S.

    2016-11-01

    Until now, significant progress has been made in synthesizing the current-switched structure of spin valves and magnetic tunnel junctions with hysteresis dependences of the resistance on the current. These structures are of interest for creation of small-size electronic memory. However, hysteresis of resistance, which is usually presented in publications, does not correspond to physical principles. In this paper, we show how the hysteresis dependence of the resistance on the current, or the conductance on the voltage, which does not contradict the energy conservation law, and the corresponding current-voltage characteristic should look like. As an example, we present the experimental current-voltage characteristic of the CO2MnSi/MgO/Co2MnSi magnetic tunnel junction, which agrees with the model hysteresis dependences.

  6. Digital signaling and hysteresis characterize Ras activation in lymphoid cells

    PubMed Central

    Das, Jayajit; Ho, Mary; Zikherman, Julie; Govern, Christopher; Yang, Ming; Weiss, Arthur; Chakraborty, Arup K.; Roose, Jeroen P.

    2009-01-01

    Activation of Ras proteins underlies functional decisions in diverse cell types. Two molecules, RasGRP and SOS, catalyze Ras activation in lymphocytes. Binding of active Ras to SOS′ allosteric pocket markedly increases SOS′ activity establishing a positive feedback loop for SOS-mediated Ras activation. Integrating in silico and in vitro studies, we demonstrate that digital signaling in lymphocytes (cells are “on” or “off”) is predicated upon feedback regulation of SOS. SOS′ feedback loop leads to hysteresis in the dose-response curve, which can enable a capacity to sustain Ras activation as stimuli are withdrawn and exhibit “memory” of past encounters with antigen. Ras activation via RasGRP alone is analog (graded increase in amplitude with stimulus). We describe how complementary analog (RasGRP) and digital (SOS) pathways act on Ras to efficiently convert analog input to digital output. Numerous predictions regarding the impact of our findings on lymphocyte function and development are noted. PMID:19167334

  7. Towards the establishment of an archeointensity master curve for Mesoamerica

    NASA Astrophysics Data System (ADS)

    Morales, J.; Gogichaisvili, A.; Acosta, G.; Gonzales, T.

    2007-05-01

    We present new rock-magnetic and archaeointensity results of some pre-Columbian potteries found at archaeological caves in Chiapas, Southeast Mexico. The ceramics studied consist mostly of tiles of different archaeological artifacts. Their archeological ages cover mainly two ranges: from 550-250 BC and from 100-500 AD. `Rock-magnetic' experiments which included susceptibility vs. temperature and hysteresis measurements were used to select magnetically stable and suitable material for Thellier absolute intensity determinations. Six out of thirteen archaeological tiles, which showed no evidence of strong secondary components and presenting almost reversible susceptibility curves, were selected for archeointensity studies. Each of these tiles were further divided into at least seven fragments and then set in salt (NaCl) pellets in order to treat them as standard paleomagnetic cores. Magnetization per unit volume of `blank' pellets is negligible with respect to that of ceramic samples. Archeointensity experiments were carried out using the Coe version of the Thellier method. Cooling rate and anisotropy effects were investigated on each sample. Thellier experiments yielded unusually high success rate and data obtained are of excellent technical quality, attested by reasonably high Coe's factors. This pioneering study proves the usefulness of Mesoamerican ceramics for archeointensity studies and opens new perspectives towards the establishment of a reference intensity variation curve for the region.

  8. Hysteresis and the length dependence of calcium sensitivity in chemically skinned rat cardiac muscle.

    PubMed Central

    Harrison, S M; Lamont, C; Miller, D J

    1988-01-01

    1. The relationship between pCa (-log10[Ca2+]) and steady-state isometric tension has been investigated in saponin- or Triton-treated (chemically 'skinned') cardiac muscle of rat. 2. Hysteresis exists in the relationship such that the muscle is less sensitive to Ca2+ during increasing activation (as [Ca2+] is stepped upward) than during reducing activation (as [Ca2+] is stepped downward). 3. The extent of the hysteresis is insensitive to interventions that increase overall calcium sensitivity by chemical means, such as caffeine, carnosine or increased pH. 4. The extent of the hysteresis is sensitive to sarcomere length. The phenomenon is virtually absent above sarcomere lengths of about 2.2-2.3 microns but becomes progressively greater at shorter sarcomere lengths. 5. The effect of sarcomere length on calcium sensitivity is restricted to the upward-going (increasing activation) part of the pCa-tension loop below 2.2 microns. The downward-going (decreasing activation) part of the hysteretic relationship is virtually unaffected by sarcomere length up to 2.2 microns. 6. Significant alterations in sarcomere length do not occur during tension development in the experiments described here: the phenomenon is not attributable to experimental artifacts of this kind. 7. Hysteresis develops sufficiently rapidly to be consistent with a physiological relevance during the normal heart beat. 8. The effects of sarcomere length show that the phenomenon is not due to force per se since, for example, greater peak force produces less hysteresis as sarcomere length is increased towards 2.2 microns. 9. Tonicity increase (by high-molecular-weight dextran), which shrinks the myofilament lattice, increases calcium sensitivity but reduces the effect of sarcomere length on calcium sensitivity. 10. The results suggest that lattice shrinkage is the mechanism which accounts for hysteresis in, and the sarcomere length dependence of, calcium sensitivity in cardiac muscle. Images Fig. 1 Fig. 11

  9. Molecular hysteresis: residual effects of hormones and glucose on genes during aging.

    PubMed

    Mobbs, C V

    1994-01-01

    The basic concept of molecular hysteresis may be succintly summarized as follows in the following Limerick:. Hormones behave like Don Juan: They show up, do their thing, then they're gone. But when genes have been kissed Some effects may persist, And the melody still lingers on.

  10. Statistical analysis of Contact Angle Hysteresis

    NASA Astrophysics Data System (ADS)

    Janardan, Nachiketa; Panchagnula, Mahesh

    2015-11-01

    We present the results of a new statistical approach to determining Contact Angle Hysteresis (CAH) by studying the nature of the triple line. A statistical distribution of local contact angles on a random three-dimensional drop is used as the basis for this approach. Drops with randomly shaped triple lines but of fixed volumes were deposited on a substrate and their triple line shapes were extracted by imaging. Using a solution developed by Prabhala et al. (Langmuir, 2010), the complete three dimensional shape of the sessile drop was generated. A distribution of the local contact angles for several such drops but of the same liquid-substrate pairs is generated. This distribution is a result of several microscopic advancing and receding processes along the triple line. This distribution is used to yield an approximation of the CAH associated with the substrate. This is then compared with measurements of CAH by means of a liquid infusion-withdrawal experiment. Static measurements are shown to be sufficient to measure quasistatic contact angle hysteresis of a substrate. The approach also points towards the relationship between microscopic triple line contortions and CAH.

  11. Percolation and hysteresis in macroscopic capillarity

    NASA Astrophysics Data System (ADS)

    Hilfer, Rudolf

    2010-05-01

    The concepts of relative permeability and capillary pressure are crucial for the accepted traditional theory of two phase flow in porous media. Recently a theoretical approach was introduced that does not require these concepts as input [1][2][3]. Instead it was based on the concept of hydraulic percolation of fluid phases. The presentation will describe this novel approach. It allows to simulate processes with simultaneous occurence of drainage and imbibition. Furthermore, it predicts residual saturations and their spatiotemporal changes during two phase immiscible displacement [1][2][3][4][5]. [1] R. Hilfer. Capillary Pressure, Hysteresis and Residual Saturation in Porous Media, Physica A, vol. 359, pp. 119, 2006. [2] R. Hilfer. Macroscopic Capillarity and Hysteresis for Flow in Porous Media, Physical Review E, vol. 73, pp. 016307, 2006. [3] R. Hilfer. Macroscopic capillarity without a constitutive capillary pressure function, Physica A, vol. 371, pp. 209, 2006. [4] R. Hilfer. Modeling and Simulation of Macrocapillarity, in: P. Garrido et al. (eds.) Modeling and Simulation of Materials vol. CP1091, pp. 141, American Institute of Physcis, New York, 2009. [5] R. Hilfer and F. Doster. Percolation as a basic concept for macroscopic capillarity, Transport in Porous Media, DOI 10.1007/s11242-009-9395-0, in print, 2009.

  12. Magnetic vortex chirality determination via local hysteresis loops measurements with magnetic force microscopy.

    PubMed

    Coïsson, Marco; Barrera, Gabriele; Celegato, Federica; Manzin, Alessandra; Vinai, Franco; Tiberto, Paola

    2016-07-18

    Magnetic vortex chirality in patterned square dots has been investigated by means of a field-dependent magnetic force microscopy technique that allows to measure local hysteresis loops. The chirality affects the two loop branches independently, giving rise to curves that have different shapes and symmetries as a function of the details of the magnetisation reversal process in the square dot, that is studied both experimentally and through micromagnetic simulations. The tip-sample interaction is taken into account numerically, and exploited experimentally, to influence the side of the square where nucleation of the vortex preferably occurs, therefore providing a way to both measure and drive chirality with the present technique.

  13. Magnetic vortex chirality determination via local hysteresis loops measurements with magnetic force microscopy

    PubMed Central

    Coïsson, Marco; Barrera, Gabriele; Celegato, Federica; Manzin, Alessandra; Vinai, Franco; Tiberto, Paola

    2016-01-01

    Magnetic vortex chirality in patterned square dots has been investigated by means of a field-dependent magnetic force microscopy technique that allows to measure local hysteresis loops. The chirality affects the two loop branches independently, giving rise to curves that have different shapes and symmetries as a function of the details of the magnetisation reversal process in the square dot, that is studied both experimentally and through micromagnetic simulations. The tip-sample interaction is taken into account numerically, and exploited experimentally, to influence the side of the square where nucleation of the vortex preferably occurs, therefore providing a way to both measure and drive chirality with the present technique. PMID:27426442

  14. Scanning of Adsorption Hysteresis In Situ with Small Angle X-Ray Scattering

    PubMed Central

    Mitropoulos, Athanasios Ch.; Favvas, Evangelos P.; Stefanopoulos, Konstantinos L.; Vansant, Etienne F.

    2016-01-01

    Everett’s theorem-6 of the domain theory was examined by conducting adsorption in situ with small angle x-ray scattering (SAXS) supplemented by the contrast matching technique. The study focuses on the spectrum differences of a point to which the system arrives from different scanning paths. It is noted that according to this theorem at a common point the system has similar macroscopic properties. Furthermore it was examined the memory string of the system. We concluded that opposite to theorem-6: a) at a common point the system can reach in a finite (not an infinite) number of ways, b) a correction for the thickness of the adsorbed film prior to capillary condensation is necessary, and c) the scattering curves although at high-Q values coincide, at low-Q values are different indicating different microscopic states. That is, at a common point the system holds different metastable states sustained by hysteresis effects. These metastable states are the ones which highlight the way of a system back to a return point memory (RPM). Entering the hysteresis loop from different RPMs different histories are implanted to the paths toward the common point. Although in general the memory points refer to relaxation phenomena, they also constitute a characteristic feature of capillary condensation. Analogies of the no-passing rule and the adiabaticity assumption in the frame of adsorption hysteresis are discussed. PMID:27741263

  15. Environmental Effects on Hysteresis of Transfer Characteristics in Molybdenum Disulfide Field-Effect Transistors

    NASA Astrophysics Data System (ADS)

    Shimazu, Yoshihiro; Tashiro, Mitsuki; Sonobe, Satoshi; Takahashi, Masaki

    2016-07-01

    Molybdenum disulfide (MoS2) has recently received much attention for nanoscale electronic and photonic applications. To explore the intrinsic properties and enhance the performance of MoS2-based field-effect transistors, thorough understanding of extrinsic effects such as environmental gas and contact resistance of the electrodes is required. Here, we report the effects of environmental gases on the transport properties of back-gated multilayered MoS2 field-effect transistors. Comparisons between different gases (oxygen, nitrogen, and air and nitrogen with varying relative humidities) revealed that water molecules acting as charge-trapping centers are the main cause of hysteresis in the transfer characteristics. While the hysteresis persisted even after pumping out the environmental gas for longer than 10 h at room temperature, it disappeared when the device was cooled to 240 K, suggesting a considerable increase in the time constant of the charge trapping/detrapping at these modestly low temperatures. The suppression of the hysteresis or instability in the easily attainable temperature range without surface passivation is highly advantageous for the device application of this system. The humidity dependence of the threshold voltages in the transfer curves indicates that the water molecules dominantly act as hole-trapping centers. A strong dependence of the on-state current on oxygen pressure was also observed.

  16. Non-linear control of a hydraulic piezo-valve using a generalised Prandtl-Ishlinskii hysteresis model

    NASA Astrophysics Data System (ADS)

    Stefanski, Frederik; Minorowicz, Bartosz; Persson, Johan; Plummer, Andrew; Bowen, Chris

    2017-01-01

    The potential to actuate proportional flow control valves using piezoelectric ceramics or other smart materials has been investigated for a number of years. Although performance advantages compared to electromagnetic actuation have been demonstrated, a major obstacle has proven to be ferroelectric hysteresis, which is typically 20% for a piezoelectric actuator. In this paper, a detailed study of valve control methods incorporating hysteresis compensation is made for the first time. Experimental results are obtained from a novel spool valve actuated by a multi-layer piezoelectric ring bender. A generalised Prandtl-Ishlinskii model, fitted to experimental training data from the prototype valve, is used to model hysteresis empirically. This form of model is analytically invertible and is used to compensate for hysteresis in the prototype valve both open loop, and in several configurations of closed loop real time control system. The closed loop control configurations use PID (Proportional Integral Derivative) control with either the inverse hysteresis model in the forward path or in a command feedforward path. Performance is compared to both open and closed loop control without hysteresis compensation via step and frequency response results. Results show a significant improvement in accuracy and dynamic performance using hysteresis compensation in open loop, but where valve position feedback is available for closed loop control the improvements are smaller, and so conventional PID control may well be sufficient. It is concluded that the ability to combine state-of-the-art multi-layer piezoelectric bending actuators with either sophisticated hysteresis compensation or closed loop control provides a route for the creation of a new generation of high performance piezoelectric valves.

  17. Investigating the mechanism of hysteresis effect in graphene electrical field device fabricated on SiO₂ substrates using Raman spectroscopy.

    PubMed

    Xu, Hua; Chen, Yabin; Zhang, Jin; Zhang, Haoli

    2012-09-24

    The hysteresis effect is a common problem in graphene field-effect transistors (FETs). Usually, the external doping to graphene is considered to be responsible for the hysteresis behavior, but is not yet clearly understood. By monitoring the doping of graphene and the hysteresis in graphene FETs under different atmospheres using in situ Raman spectroscopy, it is confirmed that the electrochemical doping of O(2) /H(2) O redox couple to graphene is responsible for the hysteresis effect. In addition, Raman spectra of graphene on SiO(2) substrate show stronger doping than that suspended, which indicates that SiO(2) substrate plays an important role in the doping of graphene. Herein it is proposed that the doping species (H(2) O and O(2) ) are bounded at the interface of graphene/SiO(2) substrate by hydrogen-bonds with the silanol groups on SiO(2) substrate. The dynamic equilibrium process of the charge-transfer between H(2) O/O(2) redox couple and graphene under electrical field modulation is carefully analyzed using Marcus-Gerischer theory. This work provides a clear view to the mechanism of the hysteresis effect, and is of benefit to a reliable design to suppress the hysteresis in graphene FETs.

  18. Fatigue, Hysteresis and Acoustic Emission. Parts 1 and 2

    DTIC Science & Technology

    1992-05-15

    Strain Controlled Fatigue Experiment in Progress ............ 47 25. Typical Hysteresis Loop Displayed with Data Points ..................... 48 26...88 52. Typical Hysteresis Loops from a Staircase Load Program ................. 89 53. Typical Strain Controlled Fatigue Experiment Displaying Strain ...area is difficult, if not impossible. Hence, the shift from stress controlled to strain controlled experiments. During this period, separating the total

  19. Hysteresis compensation of the piezoelectric ceramic actuators-based tip/tilt mirror with a neural network method in adaptive optics

    NASA Astrophysics Data System (ADS)

    Wang, Chongchong; Wang, Yukun; Hu, Lifa; Wang, Shaoxin; Cao, Zhaoliang; Mu, Quanquan; Li, Dayu; Yang, Chengliang; Xuan, Li

    2016-05-01

    The intrinsic hysteresis nonlinearity of the piezo-actuators can severely degrade the positioning accuracy of a tip-tilt mirror (TTM) in an adaptive optics system. This paper focuses on compensating this hysteresis nonlinearity by feed-forward linearization with an inverse hysteresis model. This inverse hysteresis model is based on the classical Presiach model, and the neural network (NN) is used to describe the hysteresis loop. In order to apply it in the real-time adaptive correction, an analytical nonlinear function derived from the NN is introduced to compute the inverse hysteresis model output instead of the time-consuming NN simulation process. Experimental results show that the proposed method effectively linearized the TTM behavior with the static hysteresis nonlinearity of TTM reducing from 15.6% to 1.4%. In addition, the tip-tilt tracking experiments using the integrator with and without hysteresis compensation are conducted. The wavefront tip-tilt aberration rejection ability of the TTM control system is significantly improved with the -3 dB error rejection bandwidth increasing from 46 to 62 Hz.

  20. Predicted Disappearance of Saturation Hysteresis in Coarse Granular Media Based on Capillary and Gravity Scaling, and Experimental Tests

    NASA Astrophysics Data System (ADS)

    Tokunaga, T. K.; Olson, K. R.; Wan, J.

    2002-12-01

    Since the classic work of W. B. Haines (1930), hysteresis in the relation between matric (capillary) potential versus water content has been recognized as a basic aspect of interactions between water and variably saturated porous media. This lack of unique correspondence between potential and saturation has well-recognized consequences for equilibrium, flow, and transport. Although hysteresis in moisture characteristic relations has several causes, the existence of different pore-sizes within porous media (the "ink bottle" effect) is primary. This capillarity-dependent phenomenon has a grain-size limit imposed by the influence of gravity, and more generally by the relations between surface and body forces, and length scales. Above this limit, capillary hysteresis vanishes. The grain-size associated with vanishing of capillary hysteresis was predicted in two ways; first with a simple pore-size model, and second by Miller-Miller scaling. Both methods predict that hysteresis vanishes when characteristic grain-sizes exceed about 8 mm, when the water-air surface tension is 72 mN/m, and when the body force is due to ordinary gravity. More generally, capillary hysteresis is predicted to disappear when the Haines Number (dependent on grain-size, surface tension, the body force, density difference between immiscible fluids) exceeds 8. The predicted critical grain-size was experimentally supported through measurements of drainage and wetting curves of sands and gravels, with grain-sizes ranging from 0.2 up to 11 mm. We also consider effects of interfacial tension variation (surfactants), variation of the body force (centrifugal field), and capillarity associated with grain-surface roughness.

  1. ST/HR hysteresis: exercise and recovery phase ST depression/heart rate analysis of the exercise ECG.

    PubMed

    Lehtinen, R

    1999-01-01

    ST segment depression/heart rate (ST/HR) hysteresis is a recently introduced novel computer method for integrating the exercise and recovery phase ST/HR analysis for improved detection of coronary artery disease (CAD). It is a continuous diagnostic variable that extracts the prevailing direction and average magnitude of the hysteresis in ST depression against HR during the first 3 consecutive minutes of postexercise recovery. This article reviews the development and evaluation of this new method in a clinical population of 347 patients referred for a routine bicycle exercise electrocardiographic (ECG) test at Tampere University Hospital, Finland. Of these patients, 127 had angiographically proven CAD, whereas 13 had no CAD according to angiography, 18 had no perfusion defect according to Tc-99m-sestamibi myocardial imaging and single photon emission computed tomography, and 189 were clinically normal with respect to cardiac diseases. For each patient, the values for ST/HR hysteresis, ST/HR index, end-exercise ST depression, and recovery ST depression were determined for each lead of the Mason-Likar modification of the standard 12-lead exercise ECG and maximum value from the lead system (aVL, aVR, and V1 excluded). The area under the receiver operating characteristics curve (ie, the discriminative capacity) of the ST/HR hysteresis was 89%, which was significantly larger than that of the end-exercise ST depression (76%, P < .0001), recovery ST depression (84%, P = .0063) or ST/HR index (83%, P = .0023), indicating the best diagnostic performance of the ST/HR hysteresis in detection of CAD regardless of the partition value selection. Furthermore, the superior diagnostic performance of the method was relatively insensitive to the ST segment measurement point or to the ECG lead selection. These results suggest that the ST/HR hysteresis improves the clinical utility of the exercise ECG test in detection of CAD.

  2. Monte Carlo simulation of the hysteresis phenomena on ferromagnetic nanotubes.

    PubMed

    Salazar-Enríquez, C D; Restrepo, J; Restrepo-Parra, E

    2012-06-01

    In this work the hysteretic properties of single wall ferromagnetic nanotubes were studied. Hysteresis loops were computed on the basis of a classical Heisenberg model involving nearest neighbor interactions and using a Monte Carlo method implemented with a single spin movement Metropolis dynamics. Nanotubes with square and hexagonal unit cells were studied varying their diameter, temperature and magneto-crystalline anisotropy. Effects of the diameter were found stronger in the square unit cell magnetic nanotubes (SMNTs) than in the hexagonal unit cell magnetic nanotubes (HMNTs). The ferromagnetic behavior was observed in SMNTs at higher temperature than in HMNTs. Moreover in both cases, SMNTs and HMNTs, the magneto-crystalline anisotropy in the longitudinal direction showed a linear correspondence with the coercive field.

  3. Ambipolar organic field-effect transistor using gate insulator hysteresis

    NASA Astrophysics Data System (ADS)

    Mizuno, Eriko; Taniguchi, Masateru; Kawai, Tomoji

    2005-04-01

    An organic field-effect transistor based on a copper-phthalocyanine and cyanoethylpullulan gate insulator showed ambipolar operation using gate insulator hysteresis, which appeared at less than 1mHz. The gate insulator possesses spontaneous polarization of 1.6μC/cm2 and a coercive electric field of 50kV/cm. After poling in an effort to obtain a large amount of accumulated charge, the field-effect mobilities of the hole and electron were 4.1×10-3 and 3.5×10-6cm2/Vs, respectively. The on/off ratio at VSG=±10V was 6×104 for the p type and 70 for the n type.

  4. Reversibility and hysteresis of the sharp yielding transition of a colloidal glass under oscillatory shear.

    PubMed

    Dang, M T; Denisov, D; Struth, B; Zaccone, A; Schall, P

    2016-04-01

    The mechanical response of glasses remains challenging to understand. Recent results indicate that the oscillatory rheology of soft glasses is accompanied by a sharp non-equilibrium transition in the microscopic dynamics. Here, we use simultaneous x-ray scattering and rheology to investigate the reversibility and hysteresis of the sharp symmetry change from anisotropic solid to isotropic liquid dynamics observed in the oscillatory shear of colloidal glasses (D. Denisov, M.T. Dang, B. Struth, A. Zaccone, P. Schall, Sci. Rep. 5 14359 (2015)). We use strain sweeps with increasing and decreasing strain amplitude to show that, in analogy with equilibrium transitions, this sharp symmetry change is reversible and exhibits systematic frequency-dependent hysteresis. Using the non-affine response formalism of amorphous solids, we show that these hysteresis effects arise from frequency-dependent non-affine structural cage rearrangements at large strain. These results consolidate the first-order-like nature of the oscillatory shear transition and quantify related hysteresis effects both via measurements and theoretical modelling.

  5. Coexistence of negative photoconductivity and hysteresis in semiconducting graphene

    NASA Astrophysics Data System (ADS)

    Zhuang, Shendong; Chen, Yan; Xia, Yidong; Tang, Nujiang; Xu, Xiaoyong; Hu, Jingguo; Chen, Zhuo

    2016-04-01

    Solution-processed graphene quantum dots (GQDs) possess a moderate bandgap, which make them a promising candidate for optoelectronics devices. However, negative photoconductivity (NPC) and hysteresis that happen in the photoelectric conversion process could be harmful to performance of the GQDs-based devices. So far, their origins and relations have remained elusive. Here, we investigate experimentally the origins of the NPC and hysteresis in GQDs. By comparing the hysteresis and photoconductance of GQDs under different relative humidity conditions, we are able to demonstrate that NPC and hysteresis coexist in GQDs and both are attributed to the carrier trapping effect of surface adsorbed moisture. We also demonstrate that GQDs could exhibit positive photoconductivity with three-order-of-magnitude reduction of hysteresis after a drying process and a subsequent encapsulation. Considering the pervasive moisture adsorption, our results may pave the way for a commercialization of semiconducting graphene-based and diverse solution-based optoelectronic devices.

  6. A Hysteresis Model for Piezoceramic Materials

    NASA Technical Reports Server (NTRS)

    Smith, Ralph C.; Ounaies, Zoubeida

    1999-01-01

    This paper addresses the modeling of nonlinear constitutive relations and hysteresis inherent to piezoceramic materials at moderate to high drive levels. Such models are, necessary to realize the, full potential of the materials in high performance control applications, and a necessary prerequisite is the development of techniques which permit control implementation. The approach employed here is based on the qualification of reversible and irreversible domain wall motion in response to applied electric fields. A comparison with experimental data illustrates that because the resulting ODE model is physics-based, it can be employed for both characterization and prediction of polarization levels throughout the range of actuator operation. Finally, the ODE formulation is amenable to inversion which facilitates the development of an inverse compensator for linear control design.

  7. Modified Davidenkov hysteresis and the propagation of sawtooth waves in polycrystals with hysteresis loss saturation

    NASA Astrophysics Data System (ADS)

    Nazarov, V. E.; Kiyashko, S. B.

    2016-08-01

    A modified Davidenkov hysteresis equation of the state has been proposed for describing the saturation of the effects of amplitude-dependent internal friction in polycrystalline metals and other solids, which possess imperfect elasticity. Using this equation, an exact analytical solution of the problem of the propagation of a periodic sawtooth wave in media characterized by quadratic hysteresis with nonlinear loss saturation has been obtained. Regularities of variations in the characteristics of a sawtooth wave, such as nonlinear loss, the change in the velocity of the propagation of the wave, and the amplitudes of the higher harmonics of the wave, have been determined. A graphical analysis of the evolution of the shape and the spectral components of the wave has been carried out.

  8. Mechanism of Wettability Hysteresis in Natural Soils

    NASA Astrophysics Data System (ADS)

    Ryder, J. L.; Demond, A. H.

    2006-12-01

    Because models of subsurface flow and transport depend on the contact angles made by the air/water and waste liquid/water interfaces with soil and rock surfaces, accurate knowledge of the wettability of subsurface systems is necessary. Sessile drop contact angles were measured on dry rock surfaces and on the same rock surfaces immersed in a second fluid. Quartz slides and cut rock faces that had been leveled and polished served as representative surfaces for silica sand, talc, kerogen containing shales, bituminous coal, and mineralized carbon. For several carbon-containing materials, contact angles are reversed from near 170 degrees when water is the receding fluid to less than 70 degrees if water is the advancing fluid. However, some mineral soils do not display wetting reversal. This work seeks to explain the mechanisms of the wetting order hysteresis. Utilizing an aqueous 0.01 M NaCl solution, glycerol, 1-bromonapthalene, and diidomethane as probe fluids, contact angle values are assessed with the method of van Oss et al. (1988) to determine the surface energy components of each type of soil. The quartz mineral surface energy has a large polar component and the calculated quartz surface energy does not depend on the wetting history of the slide. However, the magnitudes of the surface energy components of the carbon-containing materials change depending on the wetting history, indicating that the nature of the surface is altered by the surrounding fluid. The presence of wetting order hysteresis may contribute to the heterogeneous fluid distributions found at many waste liquid sites. When soil is known to contain carbon, some knowledge of the wetting history is necessary to predict the contact angle and thus the transport behavior.

  9. An undulation theory for condensation in open end slit pores: critical hysteresis temperature & critical hysteresis pore size.

    PubMed

    Fan, Chunyan; Zeng, Yonghong; Do, D D; Nicholson, D

    2014-06-28

    A new theory of condensation in an open end slit pore, based on the concept of temperature dependent undulation, at the interface separating the adsorbed phase and the gas-like region, is presented. The theory, describes, for the first time, the microscopic origin of the critical hysteresis temperature and the critical hysteresis pore size, properties which are not accessible to any classical theories.

  10. Magnetocaloric effect with low magnetic hysteresis loss in ferromagnetic Ni-Mn-Sb-Si alloys

    NASA Astrophysics Data System (ADS)

    Zhang, Ruochen; Qian, Mingfang; Zhang, Xuexi; Qin, Faxiang; Wei, Longsha; Xing, Dawei; Cui, Xiping; Sun, Jianfei; Geng, Lin; Peng, Huaxin

    2017-04-01

    Giant magnetocaloric effect in Ni-Mn-X (X=In, Sn, Sb) Heusler alloys has been revealed due to the significant shift of the martensite transformation temperatures under a bias magnetic field. However, the magnetic hysteresis during the magnetization and demagnetization cycles creates a large hysteresis loss and reduces the refrigeration capacity. Here we demonstrated that the magnetic hysteresis loss in Ni-Mn-Sb alloys was effectively reduced by Si-doping. The quaternary Ni49.0Mn38.4Sb11.7Si0.9 alloy exhibited martensite and magnetic transitions around room temperature. Maximum magnetic entropy change ΔSm 9.4 J/kg K and working temperature interval 7.0 K were achieved attributed to the martensite transformation under a magnetic field of 5 T. Meanwhile, the average magnetic hysteresis loss for Ni49.0Mn38.4Sb11.7Si0.9 alloy was 2.1 J/kg, much smaller than that for Ni49.0Mn38.5Sb12.5 alloy, 11.4 J/kg. As a result, a refrigeration capacity of 50.2 J/kg was obtained in the Ni49.0Mn38.4Sb11.7Si0.9 alloy. This result shows that Si-doped Ni-Mn-Sb alloys may act as a potential material system for magnetic refrigeration.

  11. Correlation between piezoresponse nonlinearity and hysteresis in ferroelectric crystals at the nanoscale

    NASA Astrophysics Data System (ADS)

    Li, Linglong; Yang, Yaodong; Liu, Zhengchun; Jesse, Stephen; Kalinin, Sergei V.; Vasudevan, Rama K.

    2016-04-01

    The nonlinear response of a ferroic to external fields has been studied for decades, garnering interest for both understanding fundamental physics, as well as technological applications such as memory devices. Yet, the behavior of ferroelectrics at mesoscopic regimes remains poorly understood, and the scale limits of theories developed for macroscopic regimes are not well tested experimentally. Here, we test the link between piezo-nonlinearity and local piezoelectric strain hysteresis, via AC-field dependent measurements in conjunction with hysteresis measurements with varying voltage windows on (K,Na)NbO3 crystals with band-excitation piezoelectric force microscopy. The correlation coefficient between nonlinearity amplitude and the amplitude during hysteresis loop acquisition shows a clear decrease with increasing AC bias. Further, correlation of polynomial fitting terms from the nonlinear measurements with the hysteresis loop area reveals that the largest correlations are reserved for the quadratic terms, which is expected for irreversible domain wall motion contributions that impact both piezoelectric behavior as well as minor loop formation. This study suggests applicability at local length scales of fundamental principles of Rayleigh behavior, with associated implications for future nanoscale ferroic devices.

  12. Hysteresis of Current in Noninteracting Atomic Fermi Gases in Optical Ring Potentials

    NASA Astrophysics Data System (ADS)

    Metcalf, Mekena; Chien, Chih-Chun; Lai, Chen-Yen

    Hysteresis is a ubiquitous phenomenon, which can be found in magnets, superfluids, and other many-body systems. Although interactions are present in most systems exhibiting hysteresis, here we show the current of a non-interacting Fermi gas in an optical ring potential produces hysteresis behavior when driven by a time-dependent artificial gauge field and subject to dissipation. Fermions in a ring potential threaded with flux can exhibit a persistent current when the system is in thermal equilibrium, but cold-atoms are clean and dissipation for reaching thermal equilibrium may be introduced by an external, thermal bath. We use the standard relaxation approximation to model the dynamics of cold-atoms driven periodically by an artificial gauge field. A competition of the driven time and the relaxation time leads to hysteresis of the mass current, and work done on the system, as a function of the relaxation time, exhibits similar behavior as Kramers transition rate in chemical reaction and one-dimensional thermal transport.

  13. Performance Calculation of High Temperature Superconducting Hysteresis Motor Using Finite Element Method

    NASA Astrophysics Data System (ADS)

    Konar, G.; Chakraborty, N.; Das, J.

    Hysteresis motors being capable of producing a steady torque at low speeds and providing good starting properties at loaded condition became popular among different fractional horse power electrical motors. High temperature superconducting materials being intrinsically hysteretic are suitable for this type of motor. In the present work, performance study of a 2-pole, 50 Hz HTS hysteresis motor with conventional stator and HTS rotor has been carried out numerically using finite element method. The simulation results confirm the ability of the segmented HTS rotor with glued circular sectors to trap the magnetic field as high as possible compared to the ferromagnetic rotor. Also the magnetization loops in the HTS hysteresis motor are obtained and the corresponding torque and AC losses are calculated. The motor torque thus obtained is linearly proportional to the current which is the common feature of any hysteresis motor. Calculations of torques, current densities etc are done using MATLAB program developed in-house and validated using COMSOL Multiphysics software. The simulation result shows reasonable agreement with the published results.

  14. Hysteresis and precession of a swirling jet normal to a wall.

    PubMed

    Shtern, V; Mi, J

    2004-01-01

    Interaction of a swirling jet with a no-slip surface has striking features of fundamental and practical interest. Different flow states and transitions among them occur at the same conditions in combustors, vortex tubes, and tornadoes. The jet axis can undergo precession and bending in combustors; this precession enhances large-scale mixing and reduces emissions of NOx. To explore the mechanisms of these phenomena, we address conically similar swirling jets normal to a wall. In addition to the Serrin model of tornadolike flows, a new model is developed where the flow is singularity free on the axis. New analytical and numerical solutions of the Navier-Stokes equations explain occurrence of multiple states and show that hysteresis is a common feature of wall-normal vortices or swirling jets no matter where sources of motion are located. Then we study the jet stability with the aid of a new approach accounting for deceleration and nonparallelism of the base flow. An appropriate transformation of variables reduces the stability problem for this strongly nonparallel flow to a set of ordinary differential equations. A particular flow whose stability is studied in detail is a half-line vortex normal to a rigid plane-a model of a tornado and of a swirling jet issuing from a nozzle in a combustor. Helical counter-rotating disturbances appear to be first growing as Reynolds number increases. Disturbance frequency changes its sign along the neutral curve while the wave number remains positive. Short disturbance waves propagate downstream and long waves propagate upstream. This helical instability causes bending of the vortex axis and its precession-the effects observed in technological flows and in tornadoes.

  15. First order reversal curves (FORC) analysis of individual magnetic nanostructures using micro-Hall magnetometry

    NASA Astrophysics Data System (ADS)

    Pohlit, Merlin; Eibisch, Paul; Akbari, Maryam; Porrati, Fabrizio; Huth, Michael; Müller, Jens

    2016-11-01

    Alongside the development of artificially created magnetic nanostructures, micro-Hall magnetometry has proven to be a versatile tool to obtain high-resolution hysteresis loop data and access dynamical properties. Here we explore the application of First Order Reversal Curves (FORC)—a technique well-established in the field of paleomagnetism for studying grain-size and interaction effects in magnetic rocks—to individual and dipolar-coupled arrays of magnetic nanostructures using micro-Hall sensors. A proof-of-principle experiment performed on a macroscopic piece of a floppy disk as a reference sample well known in the literature demonstrates that the FORC diagrams obtained by magnetic stray field measurements using home-built magnetometers are in good agreement with magnetization data obtained by a commercial vibrating sample magnetometer. We discuss in detail the FORC diagrams and their interpretation of three different representative magnetic systems, prepared by the direct-write Focused Electron Beam Induced Deposition (FEBID) technique: (1) an isolated Co-nanoisland showing a simple square-shaped hysteresis loop, (2) a more complex CoFe-alloy nanoisland exhibiting a wasp-waist-type hysteresis, and (3) a cluster of interacting Co-nanoislands. Our findings reveal that the combination of FORC and micro-Hall magnetometry is a promising tool to investigate complex magnetization reversal processes within individual or small ensembles of nanomagnets grown by FEBID or other fabrication methods. The method provides sub-μm spatial resolution and bridges the gap of FORC analysis, commonly used for studying macroscopic samples and rather large arrays, to studies of small ensembles of interacting nanoparticles with the high moment sensitivity inherent to micro-Hall magnetometry.

  16. First order reversal curves (FORC) analysis of individual magnetic nanostructures using micro-Hall magnetometry.

    PubMed

    Pohlit, Merlin; Eibisch, Paul; Akbari, Maryam; Porrati, Fabrizio; Huth, Michael; Müller, Jens

    2016-11-01

    Alongside the development of artificially created magnetic nanostructures, micro-Hall magnetometry has proven to be a versatile tool to obtain high-resolution hysteresis loop data and access dynamical properties. Here we explore the application of First Order Reversal Curves (FORC)-a technique well-established in the field of paleomagnetism for studying grain-size and interaction effects in magnetic rocks-to individual and dipolar-coupled arrays of magnetic nanostructures using micro-Hall sensors. A proof-of-principle experiment performed on a macroscopic piece of a floppy disk as a reference sample well known in the literature demonstrates that the FORC diagrams obtained by magnetic stray field measurements using home-built magnetometers are in good agreement with magnetization data obtained by a commercial vibrating sample magnetometer. We discuss in detail the FORC diagrams and their interpretation of three different representative magnetic systems, prepared by the direct-write Focused Electron Beam Induced Deposition (FEBID) technique: (1) an isolated Co-nanoisland showing a simple square-shaped hysteresis loop, (2) a more complex CoFe-alloy nanoisland exhibiting a wasp-waist-type hysteresis, and (3) a cluster of interacting Co-nanoislands. Our findings reveal that the combination of FORC and micro-Hall magnetometry is a promising tool to investigate complex magnetization reversal processes within individual or small ensembles of nanomagnets grown by FEBID or other fabrication methods. The method provides sub-μm spatial resolution and bridges the gap of FORC analysis, commonly used for studying macroscopic samples and rather large arrays, to studies of small ensembles of interacting nanoparticles with the high moment sensitivity inherent to micro-Hall magnetometry.

  17. Understanding the Hysteresis Loop Conundrum in Pharmacokinetic / Pharmacodynamic Relationships

    PubMed Central

    Louizos, Christopher; Yáñez, Jaime A.; Forrest, Laird; Davies, Neal M.

    2015-01-01

    Hysteresis loops are phenomena that sometimes are encountered in the analysis of pharmacokinetic and pharmacodynamic relationships spanning from pre-clinical to clinical studies. When hysteresis occurs it provides insight into the complexity of drug action and disposition that can be encountered. Hysteresis loops suggest that the relationship between drug concentration and the effect being measured is not a simple direct relationship, but may have an inherent time delay and disequilibrium, which may be the result of metabolites, the consequence of changes in pharmacodynamics or the use of a non-specific assay or may involve an indirect relationship. Counter-clockwise hysteresis has been generally defined as the process in which effect can increase with time for a given drug concentration, while in the case of clockwise hysteresis the measured effect decreases with time for a given drug concentration. Hysteresis loops can occur as a consequence of a number of different pharmacokinetic and pharmacodynamic mechanisms including tolerance, distributional delay, feedback regulation, input and output rate changes, agonistic or antagonistic active metabolites, uptake into active site, slow receptor kinetics, delayed or modified activity, time-dependent protein binding and the use of racemic drugs among other factors. In this review, each of these various causes of hysteresis loops are discussed, with incorporation of relevant examples of drugs demonstrating these relationships for illustrative purposes. Furthermore, the effect that pharmaceutical formulation has on the occurrence and potential change in direction of the hysteresis loop, and the major pharmacokinetic / pharmacodynamic modeling approaches utilized to collapse and model hysteresis are detailed. PMID:24735761

  18. Understanding the hysteresis loop conundrum in pharmacokinetic/pharmacodynamic relationships.

    PubMed

    Louizos, Christopher; Yáñez, Jaime A; Forrest, M Laird; Davies, Neal M

    2014-01-01

    Hysteresis loops are phenomena that sometimes are encountered in the analysis of pharmacokinetic and pharmacodynamic relationships spanning from pre-clinical to clinical studies. When hysteresis occurs it provides insight into the complexity of drug action and disposition that can be encountered. Hysteresis loops suggest that the relationship between drug concentration and the effect being measured is not a simple direct relationship, but may have an inherent time delay and disequilibrium, which may be the result of metabolites, the consequence of changes in pharmacodynamics or the use of a non-specific assay or may involve an indirect relationship. Counter-clockwise hysteresis has been generally defined as the process in which effect can increase with time for a given drug concentration, while in the case of clockwise hysteresis the measured effect decreases with time for a given drug concentration. Hysteresis loops can occur as a consequence of a number of different pharmacokinetic and pharmacodynamic mechanisms including tolerance, distributional delay, feedback regulation, input and output rate changes, agonistic or antagonistic active metabolites, uptake into active site, slow receptor kinetics, delayed or modified activity, time-dependent protein binding and the use of racemic drugs among other factors. In this review, each of these various causes of hysteresis loops are discussed, with incorporation of relevant examples of drugs demonstrating these relationships for illustrative purposes. Furthermore, the effect that pharmaceutical formulation has on the occurrence and potential change in direction of the hysteresis loop, and the major pharmacokinetic / pharmacodynamic modeling approaches utilized to collapse and model hysteresis are detailed.

  19. An application of the time-step topological model for three-phase transformer no-load current calculation considering hysteresis

    NASA Astrophysics Data System (ADS)

    Carrander, Claes; Mousavi, Seyed Ali; Engdahl, G. öran

    2017-02-01

    In many transformer applications, it is necessary to have a core magnetization model that takes into account both magnetic and electrical effects. This becomes particularly important in three-phase transformers, where the zero-sequence impedance is generally high, and therefore affects the magnetization very strongly. In this paper, we demonstrate a time-step topological simulation method that uses a lumped-element approach to accurately model both the electrical and magnetic circuits. The simulation method is independent of the used hysteresis model. In this paper, a hysteresis model based on the first-order reversal-curve has been used.

  20. Static measurements of slender delta wing rolling moment hysteresis

    NASA Technical Reports Server (NTRS)

    Katz, Joseph; Levin, Daniel

    1991-01-01

    Slender delta wing planforms are susceptible to self-induced roll oscillations due to aerodynamic hysteresis during the limit cycle roll oscillation. Test results are presented which clearly establish that the static rolling moment hysteresis has a damping character; hysteresis tends to be greater when, due to either wing roll or side slip, the vortex burst moves back and forth over the wing trailing edge. These data are an indirect indication of the damping role of the vortex burst during limit cycle roll oscillations.

  1. [Mathematical models of hysteresis]. Progress report No. 4, [January 1, 1991--December 31, 1991

    SciTech Connect

    Mayergoyz, I.D.

    1991-12-31

    The research described in this proposal is currently being supported by the US Department of Energy under the contract ``Mathematical Models of Hysteresis``. Thus, before discussing the proposed research in detail, it is worthwhile to describe and summarize the main results achieved in the course of our work under the above contract. Our ongoing research has largely been focused on the development of mathematical models of hysteretic nonlinearities with ``nonlocal memories``. The distinct feature of these nonlinearities is that their current states depend on past histories of input variations. It turns out that memories of hysteretic nonlinearities are quite selective. Indeed, experiments show that only some past input extrema leave their marks upon future states of hysteretic nonlinearities. Thus special mathematical tools are needed in order to describe nonlocal selective memories of hysteretic nonlinearities. Our research has been primarily concerned with Preisach-type models of hysteresis. All these models have a common generic feature; they are constructed as superpositions of simplest hysteretic nonlinearities-rectangular loops. Our study has by and large been centered around the following topics: various generalizations and extensions of the classical Preisach model, finding of necessary and sufficient conditions for the representation of actual hysteretic nonlinearities by various Preisach type models, solution of identification problems for these models, numerical implementation and experimental testing of Preisach type models. Although the study of Preisach type models has constituted the main direction of the research, some effort has also been made to establish some interesting connections between these models and such topics as: the critical state model for superconducting hysteresis, the classical Stoner-Wohlfarth model of vector magnetic hysteresis, thermal activation type models for viscosity, magnetostrictive hysteresis and neural networks.

  2. Electrodynamic soil plate oscillator: Modeling nonlinear mesoscopic elastic behavior and hysteresis in nonlinear acoustic landmine detection

    NASA Astrophysics Data System (ADS)

    Korman, M. S.; Duong, D. V.; Kalsbeck, A. E.

    2015-10-01

    An apparatus (SPO), designed to study flexural vibrations of a soil loaded plate, consists of a thin circular elastic clamped plate (and cylindrical wall) supporting a vertical soil column. A small magnet attached to the center of the plate is driven by a rigid AC coil (located coaxially below the plate) to complete the electrodynamic soil plate oscillator SPO design. The frequency dependent mechanical impedance Zmech (force / particle velocity, at the plate's center) is inversely proportional to the electrical motional impedance Zmot. Measurements of Zmot are made using the complex output to input response of a Wheatstone bridge that has an identical coil element in one of its legs. Near resonance, measurements of Zmot (with no soil) before and after a slight point mass loading at the center help determine effective mass, spring, damping and coupling constant parameters of the system. "Tuning curve" behavior of real{ Zmot } and imaginary{ Zmot } at successively higher vibration amplitudes of dry sifted masonry sand are measured. They exhibit a decrease "softening" in resonance frequency along with a decrease in the quality Q factor. In soil surface vibration measurements a bilinear hysteresis model predicts the tuning curve shape for this nonlinear mesoscopic elastic SPO behavior - which also models the soil vibration over an actual plastic "inert" VS 1.6 buried landmine. Experiments are performed where a buried 1m cube concrete block supports a 12 inch deep by 30 inch by 30 inch concrete soil box for burying a VS 1.6 in dry sifted masonry sand for on-the-mine and off-the-mine soil vibration experiments. The backbone curve (a plot of the peak amplitude vs. corresponding resonant frequency from a family of tuning curves) exhibits mostly linear behavior for "on target" soil surface vibration measurements of the buried VS 1.6 or drum-like mine simulants for relatively low particle velocities of the soil. Backbone curves for "on target" measurements exhibit

  3. Permeation hysteresis in PdCu membranes.

    PubMed

    Yuan, Lixiang; Goldbach, Andreas; Xu, Hengyong

    2008-10-09

    H 2 permeation hysteresis has been observed during cycling of a 3 mum thick supported PdCu membrane with approximately 50 atom % Pd through the fcc/bcc (face-centered cubic/body-centered cubic) miscibility gap between 723 and 873 K. Structural investigations after annealing of membrane fragments under H 2 at 823 K reveal retardation of the fcc(H) --> bcc(H) transition, which is attributed to the occurrence of metastable hydrogenated fcc PdCu(H) phases. The H(2) flux at 0.1 MPa H(2) pressure difference in the well-annealed bcc single phase regime below 723 K can be described by J(H2) = (1.3 +/- 0.2) mol.m (-2).s (-1) exp[(-11.1 +/- 0.6) kJ.mol (-1)/( RT)] and that in the fcc single phase regime above 873 K by J(H2) = (7 +/- 2) mol.m (-2).s (-1) exp[(-30.3 +/- 2.5) kJ.mol (-1)/( RT)].

  4. HYSTERESIS OF BACKFLOW IMPRINTED IN COLLIMATED JETS

    SciTech Connect

    Mizuta, Akira; Kino, Motoki; Nagakura, Hiroki

    2010-01-20

    We report two different types of backflow from jets by performing two-dimensional special relativistic hydrodynamical simulations. One is anti-parallel and quasi-straight to the main jet (quasi-straight backflow), and the other is a bent path of the backflow (bent backflow). We find that the former appears when the head advance speed is comparable to or higher than the local sound speed at the hotspot, while the latter appears when the head advance speed is slower than the sound speed at the hotspot. Bent backflow collides with the unshocked jet and laterally squeezes the jet. At the same time, a pair of new oblique shocks is formed at the tip of the jet and new bent fast backflows are generated via these oblique shocks. The hysteresis of backflow collisions is thus imprinted in the jet as a node and anti-node structure. This process also promotes broadening of the jet cross-sectional area and also causes a decrease in the head advance velocity. This hydrodynamic process may be tested by observations of compact young jets.

  5. Hysteresis and nonlinear elasticity in rocks

    SciTech Connect

    McCall, K.R.; Guyer, R.A.

    1993-12-01

    The purpose of this paper is to describe a theory of the propagation of elastic waves in hysteretic nonlinear elastic materials, e.g., rock. In the next section, we introduce the Priesach-Mayergoyz (P-M) model [6,7] of hysteretic systems and adapt it to describe the hysteretic mesoscopic elastic units (HMEU) determining the elastic properties of a rock. We combine the P-M model with effective medium theory (EMT) [8] to find the elastic response of a rock that has experienced a specified pressure history. Next, we consider elastic wave propagation in a hysteretic nonlinear elastic system governed by a history dependent equation of state. We consider one-dimensional propagation of compressional waves. The equation of motion for the longitudinal displacement field contains the same hysteretic nonlinear interactions that characterize the equation of state. We solve the equation of motion using the Green function technique developed by McCall [9]. This solution lets us identify the qualitative features in harmonic generation that are signatures of nonlinearity and hysteresis.

  6. The presence of long spinal muscles increases stiffness and hysteresis of the caprine spine in-vitro.

    PubMed

    Valentin, S; Grösel, M; Licka, T

    2012-10-11

    Long muscle-tendon-units are known to contribute to spinal stiffness and hysteresis in-vivo, yet their contribution as a passive structure in-vitro is less well defined. Twelve full length caprine spines including the head, pelvis and all spinal muscles were tested during displacement in Flexion-Extension (FE) and coupled Lateral and Rotational (LR) motion in a material testing machine. Hysteresis and modified stiffness (modST), i.e. mean force divided by the total displacement, were calculated. This was repeated following removal of dorsal muscles (longissimus dorsi and gluteus) and ventral muscles (iliopsoas), in a random order. ModST and hysteresis in the different dissection stages were identified. Correlations between modST, hysteresis, body mass, spine length and longissimus muscle thickness were calculated. Removal of dorsal musculature reduced extension modST significantly by 23%, and flexion modST by 40%. Ventral muscle removal reduced extension modST by 1% and flexion modSt by 13%. Hysteresis was reduced by 27% after dorsal and 2% after ventral muscle removal in FE hysteresis. Out of 105 correlation coefficients, five values were significantly correlated (p<0.05, range r(2): 0.61-0.71) and 10 values were highly significantly correlated (p<0.01, range r(2): 0.75-0.97). Strongest correlations were between hysteresis and modST for the same movement direction and dissection state. The results of this study demonstrate that the presence of muscles stiffens the spine with dorsal muscles showing more effect. This supports the concept that muscle volume even in a non-contractile state provides a stabilising function to the spine.

  7. Perovskite-Fullerene Hybrid Materials Eliminate Hysteresis In Planar Diodes

    SciTech Connect

    Xu, Jixian; Buin, Andrei; Ip, Alexander H.; Li, Wei; Voznyy, Oleksandr; Comin, Riccardo; Yuan, Mingjian; Jeon, Seokmin; Ning, Zhijun; McDowell, Jeffrey; Kanjanaboos, Pongsakorn; Sun, Jon-Paul; Lan, Xinzheng; Quan, Li Na; Kim, Dong Ha; Hill, Ian; Maksymovych, Petro; Sargent, Edward H.

    2015-03-31

    Solution-processed planar perovskite devices are highly desirable in a wide variety of optoelectronic applications; however, they are prone to hysteresis and current instabilities. Here we report the first perovskite–PCBM hybrid solid with significantly reduced hysteresis and recombination loss achieved in a single step. This new material displays an efficient electrically coupled microstructure: PCBM is homogeneously distributed throughout the film at perovskite grain boundaries. The PCBM passivates the key PbI3 antisite defects during the perovskite self-assembly, as revealed by theory and experiment. Photoluminescence transient spectroscopy proves that the PCBM phase promotes electron extraction. We showcase this mixed material in planar solar cells that feature low hysteresis and enhanced photovoltage. Using conductive AFM studies, we reveal the memristive properties of perovskite films. We close by positing that PCBM, by tying up both halide-rich antisites and unincorporated halides, reduces electric field-induced anion migration that may give rise to hysteresis and unstable diode behaviour.

  8. Could linear hysteresis contribute to shear wave losses in tissues?

    PubMed

    Parker, Kevin J

    2015-04-01

    For nearly 100 y in the study of cyclical motion in materials, a particular phenomenon called "linear hysteresis" or "ideal hysteretic damping" has been widely observed. More recently in the field of shear wave elastography, the basic mechanisms underlying shear wave losses in soft tissues are in question. Could linear hysteresis play a role? An underlying theoretical question must be answered: Is there a real and causal physical model that is capable of producing linear hysteresis over a band of shear wave frequencies used in diagnostic imaging schemes? One model that can approximately produce classic linear hysteresis behavior, by examining a generalized Maxwell model with a specific power law relaxation spectrum, is described here. This provides a theoretical plausibility for the phenomenon as a candidate for models of tissue behavior.

  9. Low-Hysteresis Flow-Through Wind-Tunnel Balance

    NASA Technical Reports Server (NTRS)

    Kunz, N.; Luna, P. M.; Roberts, A. C.; Smith, R. C.; Horne, W. L.; Smith, K. M.

    1992-01-01

    Improved flow-through wind-tunnel balance includes features minimizing both spurious force readings caused by internal pressurized flow and mechanical hysteresis. Symmetrical forces caused by internal flow cancelled.

  10. Hysteresis as a Marker for Complex, Overlapping Landscapes in Proteins

    PubMed Central

    Andrews, Benjamin T.; Capraro, Dominique T.; Sulkowska, Joanna I.; Onuchic, José N.; Jennings, Patricia A.

    2013-01-01

    Topologically complex proteins fold by multiple routes as a result of hard-to-fold regions of the proteins. Oftentimes these regions are introduced into the protein scaffold for function and increase frustration in the otherwise smooth-funneled landscape. Interestingly, while functional regions add complexity to folding landscapes, they may also contribute to a unique behavior referred to as hysteresis. While hysteresis is predicted to be rare, it is observed in various proteins, including proteins containing a unique peptide cyclization to form a fluorescent chromophore as well as proteins containing a knotted topology in their native fold. Here, hysteresis is demonstrated to be a consequence of the decoupling of unfolding events from the isomerization or hula-twist of a chromophore in one protein and the untying of the knot in a second protein system. The question now is- can hysteresis be a marker for the interplay of landscapes where complex folding and functional regions overlap? PMID:23525263

  11. Perovskite-fullerene hybrid materials suppress hysteresis in planar diodes.

    PubMed

    Xu, Jixian; Buin, Andrei; Ip, Alexander H; Li, Wei; Voznyy, Oleksandr; Comin, Riccardo; Yuan, Mingjian; Jeon, Seokmin; Ning, Zhijun; McDowell, Jeffrey J; Kanjanaboos, Pongsakorn; Sun, Jon-Paul; Lan, Xinzheng; Quan, Li Na; Kim, Dong Ha; Hill, Ian G; Maksymovych, Peter; Sargent, Edward H

    2015-05-08

    Solution-processed planar perovskite devices are highly desirable in a wide variety of optoelectronic applications; however, they are prone to hysteresis and current instabilities. Here we report the first perovskite-PCBM hybrid solid with significantly reduced hysteresis and recombination loss achieved in a single step. This new material displays an efficient electrically coupled microstructure: PCBM is homogeneously distributed throughout the film at perovskite grain boundaries. The PCBM passivates the key PbI3(-) antisite defects during the perovskite self-assembly, as revealed by theory and experiment. Photoluminescence transient spectroscopy proves that the PCBM phase promotes electron extraction. We showcase this mixed material in planar solar cells that feature low hysteresis and enhanced photovoltage. Using conductive AFM studies, we reveal the memristive properties of perovskite films. We close by positing that PCBM, by tying up both halide-rich antisites and unincorporated halides, reduces electric field-induced anion migration that may give rise to hysteresis and unstable diode behaviour.

  12. A nonlinear state-space approach to hysteresis identification

    NASA Astrophysics Data System (ADS)

    Noël, J. P.; Esfahani, A. F.; Kerschen, G.; Schoukens, J.

    2017-02-01

    Most studies tackling hysteresis identification in the technical literature follow white-box approaches, i.e. they rely on the assumption that measured data obey a specific hysteretic model. Such an assumption may be a hard requirement to handle in real applications, since hysteresis is a highly individualistic nonlinear behaviour. The present paper adopts a black-box approach based on nonlinear state-space models to identify hysteresis dynamics. This approach is shown to provide a general framework to hysteresis identification, featuring flexibility and parsimony of representation. Nonlinear model terms are constructed as a multivariate polynomial in the state variables, and parameter estimation is performed by minimising weighted least-squares cost functions. Technical issues, including the selection of the model order and the polynomial degree, are discussed, and model validation is achieved in both broadband and sine conditions. The study is carried out numerically by exploiting synthetic data generated via the Bouc-Wen equations.

  13. Aileron roll hysteresis effects on entry of space shuttle orbiter

    NASA Technical Reports Server (NTRS)

    Powell, R. W.

    1977-01-01

    Six-degree-of-freedom simulations of the space shuttle orbiter entry with control hysteresis were conducted on the NASA Langley Research Center interactive simulator known as the automatic reentry flight dynamics simulator. These simulations revealed that the vehicle can tolerate control hysteresis producing a + or - 50 percent change in the nominal aileron roll characteristics and an offset in the nominal characteristics equivalent to a + or - 5 deg aileron deflection with little increase in the reaction control system's fuel consumption.

  14. Hysteresis as an implicit prior in tactile spatial decision making.

    PubMed

    Thiel, Sabrina D; Bitzer, Sebastian; Nierhaus, Till; Kalberlah, Christian; Preusser, Sven; Neumann, Jane; Nikulin, Vadim V; van der Meer, Elke; Villringer, Arno; Pleger, Burkhard

    2014-01-01

    Perceptual decisions not only depend on the incoming information from sensory systems but constitute a combination of current sensory evidence and internally accumulated information from past encounters. Although recent evidence emphasizes the fundamental role of prior knowledge for perceptual decision making, only few studies have quantified the relevance of such priors on perceptual decisions and examined their interplay with other decision-relevant factors, such as the stimulus properties. In the present study we asked whether hysteresis, describing the stability of a percept despite a change in stimulus property and known to occur at perceptual thresholds, also acts as a form of an implicit prior in tactile spatial decision making, supporting the stability of a decision across successively presented random stimuli (i.e., decision hysteresis). We applied a variant of the classical 2-point discrimination task and found that hysteresis influenced perceptual decision making: Participants were more likely to decide 'same' rather than 'different' on successively presented pin distances. In a direct comparison between the influence of applied pin distances (explicit stimulus property) and hysteresis, we found that on average, stimulus property explained significantly more variance of participants' decisions than hysteresis. However, when focusing on pin distances at threshold, we found a trend for hysteresis to explain more variance. Furthermore, the less variance was explained by the pin distance on a given decision, the more variance was explained by hysteresis, and vice versa. Our findings suggest that hysteresis acts as an implicit prior in tactile spatial decision making that becomes increasingly important when explicit stimulus properties provide decreasing evidence.

  15. Stabilization of supercooled fluids by thermal hysteresis proteins.

    PubMed Central

    Wilson, P W; Leader, J P

    1995-01-01

    It has been reported that thermal hysteresis proteins found in many cold-hardy, freeze-avoiding arthropods stabilize their supercooled body fluids. We give evidence that fish antifreeze proteins, which also produce thermal hysteresis, bind to and reduce the efficiency of heterogenous nucleation sites, rather than binding to embryonic ice nuclei. We discuss both possible mechanisms for stabilization of supercooled body fluids and also describe a new method for measuring and defining the supercooling point of small volumes of liquid. PMID:7612853

  16. A MHO-based magnetic hysteresis model for amorphous materials

    NASA Astrophysics Data System (ADS)

    Ma, Lianwei; Shen, Yu; Li, Jinrong; Zhao, Xinlong

    2014-12-01

    A magnetic hysteretic operator (MHO) is proposed in this paper. Based on the constructed MHO, the input space of neural networks is expanded from one-dimension to two-dimension using the expanded space method so that the one-to-multiple mapping of magnetic hysteresis is transformed into one-to-one mapping. Based on the expanded input space, a neural network is employed to identify magnetic hysteresis. The result of an experimental example suggests the proposed approach is effective.

  17. Optical bistability and hysteresis of a hybrid metal-semiconductor nanodimer

    NASA Astrophysics Data System (ADS)

    Malyshev, A. V.; Malyshev, V. A.

    2011-07-01

    Optical response of an artificial composite nanodimer comprising a semiconductor quantum dot and a metal nanosphere is analyzed theoretically. We show that internal degrees of freedom of the system can manifest bistability and optical hysteresis as functions of the incident field intensity. We argue that these effects can be observed for real-world systems, such as a CdSe quantum dot and an Au nanoparticle hybrid. These properties can be revealed by measuring the optical hysteresis of Rayleigh scattering. We also show that the total dipole moment of the system can be switched abruptly between its two stable states by small changes in the excitation intensity. The latter promises various applications in the field of all-optical processing at the nanoscale, the most basic of them being the volatile optical memory.

  18. Effect of Tabor parameter on hysteresis losses during adhesive contact

    NASA Astrophysics Data System (ADS)

    Ciavarella, M.; Greenwood, J. A.; Barber, J. R.

    2017-01-01

    The Tabor parameter μ is conventionally assumed to determine the range of applicability of the classical 'JKR' solution for adhesive elastic contact of a sphere and a plane, with the variation of the contact area and approach with load, and in particular the maximum tensile force (the pull-off force) being well predicted for μ > 5 . Here we show that the hysteretic energy loss during a contact separation cycle is significantly overestimated by the JKR theory, even at quite large values of μ. This stems from the absence of long-range tensile forces in the JKR theory, which implies that jump into contact is delayed until the separation α = 0 . We develop an approximate solution based on the use of Wu's solution with van der Waals interactions for jump-in, and the JKR theory for jump out of contact, and show that for μ > 5 , the predicted hysteresis loss is then close to that found by direct numerical solutions using the Lennard-Jones force law. We also show how the same method can be adapted to allow for contact between bodies with finite support stiffness.

  19. Hysteresis modelling of GO laminations for arbitrary in-plane directions taking into account the dynamics of orthogonal domain walls

    NASA Astrophysics Data System (ADS)

    Baghel, A. P. S.; Sai Ram, B.; Chwastek, K.; Daniel, L.; Kulkarni, S. V.

    2016-11-01

    The anisotropy of magnetic properties in grain-oriented steels is related to their microstructure. It results from the anisotropy of the single crystal properties combined to crystallographic texture. The magnetization process along arbitrary directions can be explained using phase equilibrium for domain patterns, which can be described using Neel's phase theory. According to the theory the fractions of 180° and 90° domain walls depend on the direction of magnetization. This paper presents an approach to model hysteresis loops of grain-oriented steels along arbitrary in-plane directions. The considered description is based on a modification of the Jiles-Atherton model. It includes a modified expression for the anhysteretic magnetization which takes into account contributions of two types of domain walls. The computed hysteresis curves for different directions are in good agreement with experimental results.

  20. Theory of hysteresis during electron heating of electromagnetic wave scattering by self-organized dust structures in complex plasmas

    SciTech Connect

    Tsytovich, Vadim; Gusein-zade, Namik; Ignatov, Alexander

    2015-07-15

    Dust structuring is a natural and universal process in complex plasmas. The scattering of electromagnetic waves by dust structures is governed by the factor of coherency, i.e., the total number of coherent electrons in a single structure. In the present paper, we consider how the factor of coherency changes due to additional pulse electron heating and show that it obeys a hysteresis. After the end of the pulse heating, the scattering intensity differs substantially from that before heating. There are three necessary conditions for scattering hysteresis: first, the radiation wavelength should be larger than the pattern (structure) size; second, the total number of coherent electrons confined by the structure should be large; and third, the heating pulse duration should be shorter than the characteristic time of dust structure formation. We present the results of numerical calculations using existing models of self-consistent dust structures with either positively or negatively charged dust grains. It is shown that, depending on the grain charge and the ionization rate, two types of hysteresis are possible: one with a final increase of the scattering and the other with a final decrease of the scattering. It is suggested that the hysteresis of coherent scattering can be used as a tool in laboratory experiments and that it can be a basic mechanism explaining the observed hysteresis in radar scattering by noctilucent clouds during active experiments on electron heating in mesosphere.

  1. Suspended-sediment rating curve response to urbanization and wildfire, Santa Ana River, California

    USGS Publications Warehouse

    Warrick, J.A.; Rubin, D.M.

    2007-01-01

    River suspended-sediment concentrations provide insights to the erosion and transport of materials from a landscape, and changes in concentrations with time may result from landscape processes or human disturbance. Here we show that suspended-sediment concentrations in the Santa Ana River, California, decreased 20-fold with respect to discharge during a 34-year period (1968−2001). These decreases cannot be attributed to changes in sampling technique or timing, nor to event or seasonal hysteresis. Annual peak and total discharge, however, reveal sixfold increases over the 34-year record, which largely explain the decreases in sediment concentration by a nonlinear dilution process. The hydrological changes were related to the widespread urbanization of the watershed, which resulted in increases in storm water discharge without detectable alteration of sediment discharge, thus reducing suspended-sediment concentrations. Periodic upland wildfire significantly increased water discharge, sediment discharge, and suspended-sediment concentrations and thus further altered the rating curve with time. Our results suggest that previous inventories of southern California sediment flux, which assume time-constant rating curves and extend these curves beyond the sampling history, may have substantially overestimated loads during the most recent decades.

  2. Entropy Production and the Pressure-Volume Curve of the Lung.

    PubMed

    Oliveira, Cláudio L N; Araújo, Ascânio D; Bates, Jason H T; Andrade, José S; Suki, Béla

    2016-01-01

    We investigate analytically the production of entropy during a breathing cycle in healthy and diseased lungs. First, we calculate entropy production in healthy lungs by applying the laws of thermodynamics to the well-known transpulmonary pressure-volume (P-V) curves of the lung under the assumption that lung tissue behaves as an entropic spring similar to rubber. The bulk modulus, B, of the lung is also derived from these calculations. Second, we extend this approach to elastic recoil disorders of the lung such as occur in pulmonary fibrosis and emphysema. These diseases are characterized by particular alterations in the P-V relationship. For example, in fibrotic lungs B increases monotonically with disease progression, while in emphysema the opposite occurs. These diseases can thus be mimicked simply by making appropriate adjustments to the parameters of the P-V curve. Using Clausius's formalism, we show that entropy production, ΔS, is related to the hysteresis area, ΔA, enclosed by the P-V curve during a breathing cycle, namely, ΔS=ΔA∕T, where T is the body temperature. Although ΔA is highly dependent on the disease, such formula applies to healthy as well as diseased lungs, regardless of the disease stage. Finally, we use an ansatz to predict analytically the entropy produced by the fibrotic and emphysematous lungs.

  3. Entropy Production and the Pressure–Volume Curve of the Lung

    PubMed Central

    Oliveira, Cláudio L. N.; Araújo, Ascânio D.; Bates, Jason H. T.; Andrade, José S.; Suki, Béla

    2016-01-01

    We investigate analytically the production of entropy during a breathing cycle in healthy and diseased lungs. First, we calculate entropy production in healthy lungs by applying the laws of thermodynamics to the well-known transpulmonary pressure–volume (P–V) curves of the lung under the assumption that lung tissue behaves as an entropic spring similar to rubber. The bulk modulus, B, of the lung is also derived from these calculations. Second, we extend this approach to elastic recoil disorders of the lung such as occur in pulmonary fibrosis and emphysema. These diseases are characterized by particular alterations in the P–V relationship. For example, in fibrotic lungs B increases monotonically with disease progression, while in emphysema the opposite occurs. These diseases can thus be mimicked simply by making appropriate adjustments to the parameters of the P–V curve. Using Clausius's formalism, we show that entropy production, ΔS, is related to the hysteresis area, ΔA, enclosed by the P–V curve during a breathing cycle, namely, ΔS=ΔA∕T, where T is the body temperature. Although ΔA is highly dependent on the disease, such formula applies to healthy as well as diseased lungs, regardless of the disease stage. Finally, we use an ansatz to predict analytically the entropy produced by the fibrotic and emphysematous lungs. PMID:26973540

  4. Quantum relative Lorenz curves

    NASA Astrophysics Data System (ADS)

    Buscemi, Francesco; Gour, Gilad

    2017-01-01

    The theory of majorization and its variants, including thermomajorization, have been found to play a central role in the formulation of many physical resource theories, ranging from entanglement theory to quantum thermodynamics. Here we formulate the framework of quantum relative Lorenz curves, and show how it is able to unify majorization, thermomajorization, and their noncommutative analogs. In doing so, we define the family of Hilbert α divergences and show how it relates with other divergences used in quantum information theory. We then apply these tools to the problem of deciding the existence of a suitable transformation from an initial pair of quantum states to a final one, focusing in particular on applications to the resource theory of athermality, a precursor of quantum thermodynamics.

  5. Alkali Metal Halide Salts as Interface Additives to Fabricate Hysteresis-Free Hybrid Perovskite-Based Photovoltaic Devices.

    PubMed

    Wang, Lili; Moghe, Dhanashree; Hafezian, Soroush; Chen, Pei; Young, Margaret; Elinski, Mark; Martinu, Ludvik; Kéna-Cohen, Stéphane; Lunt, Richard R

    2016-09-07

    A new method was developed for doping and fabricating hysteresis-free hybrid perovskite-based photovoltaic devices by using alkali metal halide salts as interface layer additives. Such salt layers introduced at the perovskite interface can provide excessive halide ions to fill vacancies formed during the deposition and annealing process. A range of solution-processed halide salts were investigated. The highest performance of methylammonium lead mixed-halide perovskite device was achieved with a NaI interlayer and showed a power conversion efficiency of 12.6% and a hysteresis of less than 2%. This represents a 90% improvement compared to control devices without this salt layer. Through depth-resolved mass spectrometry, optical modeling, and photoluminescence spectroscopy, this enhancement is attributed to the reduction of iodide vacancies, passivation of grain boundaries, and improved hole extraction. Our approach ultimately provides an alternative and facile route to high-performance and hysteresis-free perovskite solar cells.

  6. Magnetic hysteresis of p(+) and He-3(2+) irradiated melt-textured YBa2Cu3O(7-delta)

    NASA Technical Reports Server (NTRS)

    Song, S. N.; Liu, J.; Chen, I. G.; Weinstein, Roy

    1992-01-01

    We have measured the magnetic hysteresis loops and temperature dependent trapped fields in melt-textured YBa2Cu3O(7-delta) samples before and after p(+) and He-3(2+) irradiation using a Hall effect magnetometer (HEM) as well as a commercial vibrating sample magnetometer (VSM). For proper He-3(2+) fluence, the critical current density may be enhanced by a factor of 10. Calculations based on various critical state models show that before the irradiation, the hysteresis loops can be well accounted for by a critical current density of a modified power law field dependence. After the irradiation, the best fit has been achieved by using an exponential form. Jc and its field dependence deduced from HEM hysteresis loops are in good agreement with those deduced from the VSM loops, suggesting that the Hall effect magnetometer can be conveniently used to characterize bulk high Tc oxide superconductors.

  7. Hysteresis in the tearing mode locking/unlocking due to resonant magnetic perturbations in EXTRAP T2R

    NASA Astrophysics Data System (ADS)

    Fridström, R.; Frassinetti, L.; Brunsell, P. R.

    2015-10-01

    The physical mechanisms behind the hysteresis in the tearing mode locking and unlocking to a resonant magnetic perturbation (RMP) are experimentally studied in EXTRAP T2R reversed-field pinch. The experiments show that the electromagnetic and the viscous torque increase with increasing perturbation amplitude until the mode locks to the wall. At the wall-locking, the plasma velocity reduction profile is peaked at the radius where the RMP is resonant. Thereafter, the viscous torque drops due to the relaxation of the velocity in the central plasma. This is the main reason for the hysteresis in the RMP locking and unlocking amplitude. The increased amplitude of the locked tearing mode produces further deepening of the hysteresis. Both experimental results are in qualitative agreement with the model in Fitzpatrick et al (2001 Phys. Plasmas 8 4489)

  8. Simulated Contact Angle Hysteresis of a Three-Dimensional Drop on a Chemically Heterogeneous Surface: A Numerical Example

    PubMed

    Brandon; Wachs; Marmur

    1997-07-01

    A public domain software package is employed in the quasi-steady-state simulation of contact angle hysteresis. Three-dimensional sessile drops in equilibrium with a model chemically heterogeneous smooth solid surface are considered; evolving drop shapes, as a function of incremental changes in their volume, are investigated. Results are presented for a model system in which the intrinsic contact angle is assumed to vary along the surface in a periodic manner. Throughout the simulation, calculated contact angles show reasonable agreement with the local intrinsic contact angle values, and the computed drop shapes are found to be constant mean curvature surfaces. Significant hysteresis in the liquid-fluid interface curvature and average contact angle is found; a complete hysteresis loop is simulated. Advancing and receding contact angles exhibit the "stick-slip" behavior observed in experiments as well as in previous 2-D simulations.

  9. An improved Prandtl-Ishlinskii model for compensating rate-dependent hysteresis in fast steering mirror system

    NASA Astrophysics Data System (ADS)

    Wang, Wan-ting; Guo, Jin; Fang, Chu; Jiang, Zhen-hua; Wang, Ting-feng

    2016-11-01

    To solve the rate-dependent hysteresis compensation problem in fast steering mirror (FSM) systems, an improved Prandtl-Ishlinskii (P-I) model is proposed in this paper. The proposed model is formulated by employing a linear density function into the STOP operator. By this way, the proposed model has a relatively simple mathematic format, which can be applied to compensate the rate-dependent hysteresis directly. Adaptive differential evolution algorithm is utilized to obtain the accurate parameters of the proposed model. A fast steering mirror control system is established to demonstrate the validity and feasibility of the improved P-I model. Comparative experiments with different input signals are performed and analyzed, and the results show that the proposed model not only suppresses the rate-dependent hysteresis effectively, but also obtains high tracking precision.

  10. Elastic hysteresis in human eyes is age dependent value.

    PubMed

    Ishii, Kotaro; Saito, Kei; Kameda, Toshihiro; Oshika, Tetsuro

    2012-06-19

    Background:  The elastic hysteresis phenomenon is observed when cyclic loading is applied to a viscoelastic system. The purpose of this study was to quantitatively evaluate elastic hysteresis in living human eyes against an external force. Design:  Prospective case series. Participants:  Twenty-four eyes of 24 normal human subjects (mean age: 41.5 ± 10.6 years) were recruited. Methods:  A non-contact tonometry process was recorded with a high-speed camera. Central corneal thickness (CCT), corneal thickness at 4 mm from the center, corneal curvature, and anterior chamber depth (ACD) were measured. Intraocular pressure (IOP) was also measured using Goldmann applanation tonometry (GAT) and dynamic contour tonometer (DCT). Main Outcome Measures:  Energy loss due to elastic hysteresis was calculated and graphed. Results:  The mean CCT was 552.5 ± 36.1 µm, corneal curvature was 7.84 ± 0.26 mm, and ACD was 2.83 ± 0.29 mm. The mean GAT-IOP was 14.2 ± 2.7 mmHg and DCT-IOP was 16.3 ± 3.5 mmHg. The mean energy loss due to elastic hysteresis was 3.90 × 10(-6) ± 2.49 × 10(-6) Nm. Energy loss due to elastic hysteresis correlated significantly with age (Pearson correlation coefficient = 0.596, p = 0.0016). There were no significant correlations between energy loss due to elastic hysteresis and other measurements. Conclusion:  Energy loss due to elastic hysteresis in the eyes of subjects was found to positively correlate with age, independent of anterior eye structure or IOP. Therefore, it is believed that the viscosity of the eye increases with age. © 2010 The Authors. Clinical and Experimental Ophthalmology © 2010 Royal Australian and New Zealand College of Ophthalmologists.

  11. Effect of contact angle hysteresis on the measurement of capillary forces.

    PubMed

    De Souza, E J; Gao, L; McCarthy, T J; Arzt, E; Crosby, A J

    2008-02-19

    We conduct experimental investigations of macroscopic capillary forces between two flat rigid substrates characterized by their advancing and receding contact angles with water. Our results exhibit excellent agreement with theoretical predictions obtained by the numerical solution of the capillary equation. On the basis of this comparison, we use the measurements of the capillary force to investigate the phenomenon of contact angle hysteresis. We present examples of force measurements for surfaces that display low, moderate, and high contact angle hysteresis and compare results for a larger variety of substrates. Finally, we show that for the case of water, the role of viscosity is insignificant within the range of force and velocity measured in the present work.

  12. Magnetic Study of Martensitic Transformation in Austenitic Stainless Steel by Low Field Hysteresis Loops Analysis

    SciTech Connect

    Zhang Lefu; Takahashi, Seiki; Kamada, Yasuhiro; Kikuchi, Hiroaki; Mumtaz, Khalid; Ara, Katsuyuki; Sato, Masaya

    2005-04-09

    Magnetic method has been used to evaluate the volume percentage of {alpha}' martensitic phase in austenitic stainless steels by measuring saturation magnetization, and it is said to be a candidate NDE method. However, nondestructive detection of saturation magnetization without high magnetic field is difficult. In the current work, we present a NDE method for evaluating the magnetic properties of strain induced {alpha}' martensitic phase. Low field hysteresis loops of an austenitic stainless steels type SUS 304 after cold rolling were measured by using a yoke sensor. The results show that the initial permeability {mu}i and the relative coercive field Hcl calculated by low field hysteresis loop analysis keep monotonic relation with saturation magnetization and coercive force measured by VSM, respectively. By this method, it is possible to characterize the volume content and particle properties of {alpha}' martensitic phase in stainless steels.

  13. Demonstration of the "conditioning effect" in soil organic matter in support of a pore deformation mechanism for sorption hysteresis.

    PubMed

    Lu, Yuefeng; Pignatello, Joseph J

    2002-11-01

    Hysteresis, or isotherm nonsingularity, is a confounding issue in sorption research that undermines the commonplace assumption of reversibility in environmental fate and effects models for organic compounds in soil media. Until now, a molecular-level mechanism for true hysteresis when the sorbate is retrievable, structurally intact, has not been forthcoming. We show here that two organic soils exhibit the "conditioning effect", which refers to the enhancement in sorption of a compound following brief exposure of the sorbent to high concentrations of the same or a similar compound. The conditioning effect has been used in support of a pore deformation mechanism for hysteresis in glassy polymers. By this mechanism, the sorbate causes irreversible changes in the structure of internal nanopores (holes) in the organic matrix upon its sorption. Trichloromethane was the test solute for dichloromethane-conditioned Pahokee soil (44.6% organic carbon), and chlorobenzene and 1,2,4-trichlorobenzene were the test solutes for benzene-conditioned Mount Pleasant silt loam (4.5% organic carbon). In each case, the isotherm of the test solute in the conditioned soil was shifted upward of, and was less linear than, the corresponding isotherm in the nonconditioned control. Application of the polymer-based Dual-Mode (partitioning-hole filling) Model shows an expansion of the hole domain as a result of conditioning. The memory of the conditioning effect persists for longer than 96 days at 21 degrees C but is lost upon heating the sample at 100 degrees C. A three-step (sorption-desorption-resorption) experiment demonstrated hysteresis followed by enhanced resorption, implying a mechanistic relationship between hysteresis and the conditioning effect. The results indicate that irreversible pore deformation is a mechanism for hysteresis in natural organic matter materials and suggest that slow matrix relaxation may contribute to the often-observed long-term resistance of some contaminants to

  14. Thin three-dimensional droplets on an oscillating substrate with contact angle hysteresis

    NASA Astrophysics Data System (ADS)

    Bradshaw, J.; Billingham, J.

    2016-01-01

    Recent experiments [P. Brunet, J. Eggers, and R. D. Deegan, Phys. Rev. Lett. 99, 144501 (2007), 10.1103/PhysRevLett.99.144501] have shown that a liquid droplet on an inclined plane can be made to move uphill by sufficiently strong, vertical oscillations. In order to investigate this counterintuitive phenomenon we use a model in which liquid inertia and viscosity are assumed negligible so that the motion of the droplet is dominated by the applied acceleration due to the oscillation of the plate, gravity, and surface tension. We explain how the leading order motion of the droplet can be separated into a spreading mode and a swaying mode. For a linear contact line law, the maximum rise velocity occurs when these modes are in phase. We show that, both with and without contact angle hysteresis, the droplet can climb uphill and also that, for certain contact line laws, the motion of the droplet can produce footprints similar to experimental results. We show that if the two modes are out of phase when there is no contact angle hysteresis, the inclusion of hysteresis can force them into phase. This in turn increases the rise velocity of the droplet and can, in some cases, cause a sliding droplet to climb.

  15. Thin three-dimensional droplets on an oscillating substrate with contact angle hysteresis.

    PubMed

    Bradshaw, J; Billingham, J

    2016-01-01

    Recent experiments [P. Brunet, J. Eggers, and R. D. Deegan, Phys. Rev. Lett. 99, 144501 (2007)10.1103/PhysRevLett.99.144501] have shown that a liquid droplet on an inclined plane can be made to move uphill by sufficiently strong, vertical oscillations. In order to investigate this counterintuitive phenomenon we use a model in which liquid inertia and viscosity are assumed negligible so that the motion of the droplet is dominated by the applied acceleration due to the oscillation of the plate, gravity, and surface tension. We explain how the leading order motion of the droplet can be separated into a spreading mode and a swaying mode. For a linear contact line law, the maximum rise velocity occurs when these modes are in phase. We show that, both with and without contact angle hysteresis, the droplet can climb uphill and also that, for certain contact line laws, the motion of the droplet can produce footprints similar to experimental results. We show that if the two modes are out of phase when there is no contact angle hysteresis, the inclusion of hysteresis can force them into phase. This in turn increases the rise velocity of the droplet and can, in some cases, cause a sliding droplet to climb.

  16. Dynamic characterization of hysteresis elements in mechanical systems. I. Theoretical analysis

    NASA Astrophysics Data System (ADS)

    Al-Bender, F.; Symens, W.

    2005-03-01

    The pre-sliding-pre-rolling phase of friction behavior is dominated by rate-independent hysteresis. Many machine elements in common engineering use exhibit, therefore, the characteristic of "hysteresis springs," for small displacements at least. Plain and rolling element bearings that are widely used in motion guidance of machine tools are typical examples. While the presence of a hysteresis element may mark the character of the resulting dynamics, little is to be found about this topic in the literature. The study of the nonlinear dynamics caused by such elements becomes imperative if we wish to achieve accurate control of such machines. In this Part I of the investigation, we examine a single-degree-of-freedom mass-hysteresis-spring system and show that, while the free response case is amenable to an exact solution, the more important case of forced response has no closed form solution and requires other methods of treatment. We consider harmonic-balance analysis methods (which are common analysis tools in engineering) suitable for frequency-domain treatment, in particular the approximate describing function (DF) method, and compare those results with "exact" numerical simulations. The DF method yields basically a linear equation with amplitude-dependent modal parameters. We find that agreement in the frequency response function, between DF and exact solution, is good for small excitation amplitudes and for very large amplitudes. Intermediate values, however, show high sensitivity to amplitude variations and, consequently, no regular solution is obtainable by either approach. This appears to be an inherent property of the system pointing to the need for developing further analysis methods. Experimental verification of the analysis outlined in this Part I is given in Part II of the paper.

  17. Quantum Phase Transitions with Parity-Symmetry Breaking and Hysteresis.

    PubMed

    Trenkwalder, A; Spagnolli, G; Semeghini, G; Coop, S; Landini, M; Castilho, P; Pezzè, L; Modugno, G; Inguscio, M; Smerzi, A; Fattori, M

    2016-09-01

    Symmetry-breaking quantum phase transitions play a key role in several condensed matter, cosmology and nuclear physics theoretical models1-3. Its observation in real systems is often hampered by finite temperatures and limited control of the system parameters. In this work we report for the first time the experimental observation of the full quantum phase diagram across a transition where the spatial parity symmetry is broken. Our system is made of an ultra-cold gas with tunable attractive interactions trapped in a spatially symmetric double-well potential. At a critical value of the interaction strength, we observe a continuous quantum phase transition where the gas spontaneously localizes in one well or the other, thus breaking the underlying symmetry of the system. Furthermore, we show the robustness of the asymmetric state against controlled energy mismatch between the two wells. This is the result of hysteresis associated with an additional discontinuous quantum phase transition that we fully characterize. Our results pave the way to the study of quantum critical phenomena at finite temperature4, the investigation of macroscopic quantum tunneling of the order parameter in the hysteretic regime and the production of strongly quantum entangled states at critical points5.

  18. Quantum Phase Transitions with Parity-Symmetry Breaking and Hysteresis

    PubMed Central

    Trenkwalder, A.; Spagnolli, G.; Semeghini, G.; Coop, S.; Landini, M.; Castilho, P.; Pezzè, L.; Modugno, G.; Inguscio, M.; Smerzi, A.; Fattori, M.

    2016-01-01

    Symmetry-breaking quantum phase transitions play a key role in several condensed matter, cosmology and nuclear physics theoretical models1–3. Its observation in real systems is often hampered by finite temperatures and limited control of the system parameters. In this work we report for the first time the experimental observation of the full quantum phase diagram across a transition where the spatial parity symmetry is broken. Our system is made of an ultra-cold gas with tunable attractive interactions trapped in a spatially symmetric double-well potential. At a critical value of the interaction strength, we observe a continuous quantum phase transition where the gas spontaneously localizes in one well or the other, thus breaking the underlying symmetry of the system. Furthermore, we show the robustness of the asymmetric state against controlled energy mismatch between the two wells. This is the result of hysteresis associated with an additional discontinuous quantum phase transition that we fully characterize. Our results pave the way to the study of quantum critical phenomena at finite temperature4, the investigation of macroscopic quantum tunneling of the order parameter in the hysteretic regime and the production of strongly quantum entangled states at critical points5. PMID:27610189

  19. On the flow structures and hysteresis of laminar swirling jets

    NASA Astrophysics Data System (ADS)

    Ogus, G.; Baelmans, M.; Vanierschot, M.

    2016-12-01

    In this paper different flow patterns of an annular jet with a stepped-conical nozzle as well as the transition between these patterns are numerically investigated as a function of the swirl number S which is the ratio of tangential momentum flux to axial momentum flux. The Reynolds number of the jet based on the axial velocity and the nozzle hydraulic diameter is 180. The 3D Navier Stokes equations are solved using the direct numerical simulation. Four different flow patterns are identified and their associated flow structures are discussed. Starting from an annular jet at zero swirl, spinning vortices around the central axis originate with increasing swirl. As the swirl is further increased, the onset of vortex breakdown occurs, followed by jet attachment to the nozzle. Decreasing the swirl number back from this flow pattern, the Coanda effect near the nozzle outlet creates a wall jet. This wall jet remains till the decreasing swirl number equals to zero, showing hysteresis in flow patterns between an increase and a subsequent decrease in swirl. The determined flow states are experimentally validated. Potential applications related to these flow patterns and their hysteretic behavior are also briefly discussed.

  20. Hysteresis of ligand binding in CNGA2 ion channels

    PubMed Central

    Nache, Vasilica; Eick, Thomas; Schulz, Eckhard; Schmauder, Ralf; Benndorf, Klaus

    2013-01-01

    Tetrameric cyclic nucleotide-gated (CNG) channels mediate receptor potentials in olfaction and vision. The channels are activated by the binding of cyclic nucleotides to a binding domain embedded in the C terminus of each subunit. Here using a fluorescent cGMP derivative (fcGMP), we show for homotetrameric CNGA2 channels that ligand unbinding is ~50 times faster at saturating than at subsaturating fcGMP. Analysis with complex Markovian models reveals two pathways for ligand unbinding; the partially liganded open channel unbinds its ligands from closed states only, whereas the fully liganded channel reaches a different open state from which it unbinds all four ligands rapidly. Consequently, the transition pathways for ligand binding and activation of a fully liganded CNGA2 channel differ from that of ligand unbinding and deactivation, resulting in pronounced hysteresis of the gating mechanism. This concentration-dependent gating mechanism allows the channels to respond to changes in the cyclic nucleotide concentration with different kinetics. PMID:24287615

  1. Multilevel non-volatile data storage utilizing common current hysteresis of networked single walled carbon nanotubes.

    PubMed

    Hwang, Ihn; Wang, Wei; Hwang, Sun Kak; Cho, Sung Hwan; Kim, Kang Lib; Jeong, Beomjin; Huh, June; Park, Cheolmin

    2016-05-21

    The characteristic source-drain current hysteresis frequently observed in field-effect transistors with networked single walled carbon-nanotube (NSWNT) channels is problematic for the reliable switching and sensing performance of devices. But the two distinct current states of the hysteresis curve at a zero gate voltage can be useful for memory applications. In this work, we demonstrate a novel non-volatile transistor memory with solution-processed NSWNTs which are suitable for multilevel data programming and reading. A polymer passivation layer with a small amount of water employed on the top of the NSWNT channel serves as an efficient gate voltage dependent charge trapping and de-trapping site. A systematic investigation evidences that the water mixed in a polymer passivation solution is critical for reliable non-volatile memory operation. The optimized device is air-stable and temperature-resistive up to 80 °C and exhibits excellent non-volatile memory performance with an on/off current ratio greater than 10(4), a switching time less than 100 ms, data retention longer than 4000 s, and write/read endurance over 100 cycles. Furthermore, the gate voltage dependent charge injection mediated by water in the passivation layer allowed for multilevel operation of our memory in which 4 distinct current states were programmed repetitively and preserved over a long time period.

  2. Weak hysteresis in a simplified model of the L-H transition

    SciTech Connect

    Malkov, M. A.; Diamond, P. H.

    2009-01-15

    A simple one-field L-H transition model is studied in detail, analytically and numerically. The dynamical system consists of three equations coupling the drift wave turbulence level, zonal flow speed, and the pressure gradient. The fourth component, i.e., the mean shear velocity, is slaved to the pressure gradient. Bursting behavior, characteristic for predator-prey models of the drift wave - zonal flow interaction, is recovered near the transition to the quiescent H-mode (QH) and occurs as strongly nonlinear relaxation oscillations. The latter, in turn, arise as a result of Hopf bifurcation (limit cycle) of an intermediate fixed point (between the L- and H-modes). The system is shown to remain at the QH-mode fixed point even after the heating rate is decreased below the bifurcation point (i.e., hysteresis, subcritical bifurcation), but the basin of attraction of the QH-mode shrinks rapidly with decreasing power. This suggests that the hysteresis in the H-L transition may be less than that expected from S-curve models. Nevertheless, it is demonstrated that by shaping the heating rate temporal profile, one can reduce the average power required for the transition to the QH-mode.

  3. Performance Analysis of SISFCL with the Variation of Circuit Parameters using Jiles Atherton Hysteresis Model

    NASA Astrophysics Data System (ADS)

    Sarkar, Debraj; Roy, Debabrata; Choudhury, Amalendu Bikash; Yamada, Sotoshi

    2016-08-01

    In modern day power systems, fault current limiters (FCL) are used to provide protection from high fault currents in the event of electrical faults and thus help to deliver uninterrupted electric supply to the consumers. Several technologies of FCLs are available for practical usage. However, the saturated iron-core superconducting fault current limiter (SISFCL) has gained a lot of attention in recent years in view of its ability to offer very low impedance during normal operation and high impedance during faulted condition. Previous mathematical models defining the performance of the device employs a simple BH curve. But as the change in mathematical state of saturation and unsaturation is important for the operation of the device, the paper investigates the responses considering the effects of magnetic hysteresis utilising the Jiles Atherton hysteresis model. Further the performance of the device is analysed with the variations of different parameters viz., the fault resistance magnitude, DC bias current, number of turns of the AC winding and number of turns of the DC winding that portray the effectiveness of the parameters encouraging an optimal design of the limiter.

  4. Parameter analysis of PEM fuel cell hysteresis effects for transient load use

    NASA Astrophysics Data System (ADS)

    Talj, R.; Azib, T.; Béthoux, O.; Remy, G.; Marchand, C.; Berthelot, E.

    2011-05-01

    This paper focuses on the hysteresis effect of the polarization characteristics of a polymer electrolyte membrane fuel cell (PEMFC), mainly due to the compressor-air supply system dynamics. Indeed in PEMFC/ultracapacitor hybrid vehicles, fuel cells can be used to supply the low frequencies of the power demand only. First, the different parts of a FC system are described and modeled in order to analyze the transient stack performance decrease and to identify its main influential factors for automotive applications. Then, apart from humidity and temperature variations, each phenomenon is dynamically described, leading to a complete mathematical model based on macroscopic component parameters. Thus, an analytical model based on this set of equations enables us to draw the static voltage versus current FC characteristics. Furthermore, the hysteresis effect on the V-I curve, which still occurs during low dynamic responses, is shown while temperature and humidity are kept constant. Finally, dynamic responses of the Ballard PEMFC Nexa 1200 W generator are analyzed, and detailed experimentation and simulation are carried out for a large magnitude sinusoidal waveform at different frequencies.

  5. Modulated self-reversed magnetic hysteresis in iron oxides

    PubMed Central

    Ma, Ji; Chen, Kezheng

    2017-01-01

    The steadfast rule of a ferromagnetic hysteresis loop claims its saturation positioned within the first and third quadrants, whereas its saturation positioned in the second and fourth quadrants (named as self-reversed magnetic hysteresis) is usually taken as an experimental artifact and is always intentionally ignored. In this report, a new insight in this unique hysteresis phenomenon and its modulation were discussed in depth. Different iron oxides (magnetite, maghemite and hematite) with varying dimensions were soaked in FeCl3 aqueous solution and absorbed Fe3+ cations due to their negative enough surface zeta potentials. These iron oxides@Fe3+ core-shell products exhibit well pronounced self-reversed magnetic hysteresis which concurrently have typical diamagnetic characteristics and essential ferromagnetic features. The presence of pre-magnetized Fe3+ shell and its negatively magnetic exchange coupling with post-magnetized iron-oxide core is the root cause for the observed phenomena. More strikingly, this self-reversed magnetic hysteresis can be readily modulated by changing the core size or by simply controlling Fe3+ concentration in aqueous solution. It is anticipated that this work will shed new light on the development of spintronics, magnetic recording and other magnetically-relevant fields. PMID:28220793

  6. Surface free energy of a solid from contact angle hysteresis.

    PubMed

    Chibowski, Emil

    2003-04-25

    Nature of contact angle hysteresis is discussed basing on the literature data (Colloids Surf. A 189 (2001) 265) of dynamic advancing and receding contact angles of n-alkanes and n-alcohols on a very smooth surface of 1,1,2,-trichloro-1,2,2,-trifluoroethane (FC-732) film deposited on a silicon plate. The authors considered the liquid absorption and/or retention (swelling) processes responsible for the observed hysteresis. In this paper hysteresis is considered to be due to the liquid film left behind the drop during retreating of its contact line. Using the contact angle hysteresis an approach is suggested for evaluation of the solid surface free energy. Molecular spacing and the film structure are discussed to explain the difference in n-alkanes and n-alcohols behaviour as well as to explain the difference between dispersion free energy gamma(s)(d) and total surface free energy gamma(s)(tot) of FC-732, as determined from the advancing contact angles and the hysteresis, respectively.

  7. Modulated self-reversed magnetic hysteresis in iron oxides.

    PubMed

    Ma, Ji; Chen, Kezheng

    2017-02-21

    The steadfast rule of a ferromagnetic hysteresis loop claims its saturation positioned within the first and third quadrants, whereas its saturation positioned in the second and fourth quadrants (named as self-reversed magnetic hysteresis) is usually taken as an experimental artifact and is always intentionally ignored. In this report, a new insight in this unique hysteresis phenomenon and its modulation were discussed in depth. Different iron oxides (magnetite, maghemite and hematite) with varying dimensions were soaked in FeCl3 aqueous solution and absorbed Fe(3+) cations due to their negative enough surface zeta potentials. These iron oxides@Fe(3+) core-shell products exhibit well pronounced self-reversed magnetic hysteresis which concurrently have typical diamagnetic characteristics and essential ferromagnetic features. The presence of pre-magnetized Fe(3+) shell and its negatively magnetic exchange coupling with post-magnetized iron-oxide core is the root cause for the observed phenomena. More strikingly, this self-reversed magnetic hysteresis can be readily modulated by changing the core size or by simply controlling Fe(3+) concentration in aqueous solution. It is anticipated that this work will shed new light on the development of spintronics, magnetic recording and other magnetically-relevant fields.

  8. Modulated self-reversed magnetic hysteresis in iron oxides

    NASA Astrophysics Data System (ADS)

    Ma, Ji; Chen, Kezheng

    2017-02-01

    The steadfast rule of a ferromagnetic hysteresis loop claims its saturation positioned within the first and third quadrants, whereas its saturation positioned in the second and fourth quadrants (named as self-reversed magnetic hysteresis) is usually taken as an experimental artifact and is always intentionally ignored. In this report, a new insight in this unique hysteresis phenomenon and its modulation were discussed in depth. Different iron oxides (magnetite, maghemite and hematite) with varying dimensions were soaked in FeCl3 aqueous solution and absorbed Fe3+ cations due to their negative enough surface zeta potentials. These iron oxides@Fe3+ core-shell products exhibit well pronounced self-reversed magnetic hysteresis which concurrently have typical diamagnetic characteristics and essential ferromagnetic features. The presence of pre-magnetized Fe3+ shell and its negatively magnetic exchange coupling with post-magnetized iron-oxide core is the root cause for the observed phenomena. More strikingly, this self-reversed magnetic hysteresis can be readily modulated by changing the core size or by simply controlling Fe3+ concentration in aqueous solution. It is anticipated that this work will shed new light on the development of spintronics, magnetic recording and other magnetically-relevant fields.

  9. Hysteresis in Transport Critical-Current Measurements of Oxide Superconductors.

    PubMed

    Goodrich, L F; Stauffer, T C

    2001-01-01

    We have investigated magnetic hysteresis in transport critical-current (I c) measurements of Ag-matrix (Bi,Pb)2Sr2Ca2Cu3O10- x (Bi-2223) and AgMg-matrix Bi2Sr2CaCu2O8+ x (Bi-2212) tapes. The effect of magnetic hysteresis on the measured critical current of high temperature superconductors is a very important consideration for every measurement procedure that involves more than one sweep of magnetic field, changes in field angle, or changes in temperature at a given field. The existence of this hysteresis is well known; however, the implications for a measurement standard or interlaboratory comparisons are often ignored and the measurements are often made in the most expedient way. A key finding is that I c at a given angle, determined by sweeping the angles in a given magnetic field, can be 17 % different from the I c determined after the angle was fixed in zero field and the magnet then ramped to the given field. Which value is correct is addressed in the context that the proper sequence of measurement conditions reflects the application conditions. The hysteresis in angle-sweep and temperature-sweep data is related to the hysteresis observed when the field is swept up and down at constant angle and temperature. The necessity of heating a specimen to near its transition temperature to reset it to an initial state between measurements at different angles and temperatures is discussed.

  10. Hysteresis in the production of force by larval Dipteran muscle.

    PubMed

    Paterson, Bethany A; Anikin, Ilya Marko; Krans, Jacob L

    2010-07-15

    We describe neuromuscular hysteresis - the dependence of muscle force on recent motoneuron activity - in the body wall muscles of larval Sarcophaga bullata and Drosophila melanogaster. In semi-intact preparations, isometric force produced by a train of nerve impulses at a constant rate was significantly less than that produced by the same train of stimuli with a brief (200 ms) high-frequency burst of impulses interspersed. Elevated force did not decay back to predicted values after the burst but instead remained high throughout the duration of the stimulus train. The increased force was not due to a change in excitatory junction potentials (EJPs); EJP voltage and time course before and after the high-frequency burst were not statistically different. Single muscle and semi-intact preparations exhibited hysteresis similarly, suggesting that connective tissues of the origin or insertion are not crucial to the mechanism of hysteresis. Hysteresis was greatest at low motoneuron rates - yielding a approximately 100% increase over predicted values based on constant-rate stimulation alone - and decreased as impulse rate increased. We modulated motoneuron frequency rhythmically across rates and cycle periods similar to those observed during kinematic analysis of larval crawling. Positive force hysteresis was also evident within these more physiological activation parameters.

  11. Dual-domain mass-transfer parameters from electrical hysteresis: theory and analytical approach applied to laboratory, synthetic streambed, and groundwater experiments

    USGS Publications Warehouse

    Briggs, Martin; Day-Lewis, Frederick D.; Ong, John B.; Harvey, Judson W.; Lane, Jr., John W.

    2014-01-01

    Models of dual-domain mass transfer (DDMT) are used to explain anomalous aquifer transport behavior such as the slow release of contamination and solute tracer tailing. Traditional tracer experiments to characterize DDMT are performed at the flow path scale (meters), which inherently incorporates heterogeneous exchange processes; hence, estimated “effective” parameters are sensitive to experimental design (i.e., duration and injection velocity). Recently, electrical geophysical methods have been used to aid in the inference of DDMT parameters because, unlike traditional fluid sampling, electrical methods can directly sense less-mobile solute dynamics and can target specific points along subsurface flow paths. Here we propose an analytical framework for graphical parameter inference based on a simple petrophysical model explaining the hysteretic relation between measurements of bulk and fluid conductivity arising in the presence of DDMT at the local scale. Analysis is graphical and involves visual inspection of hysteresis patterns to (1) determine the size of paired mobile and less-mobile porosities and (2) identify the exchange rate coefficient through simple curve fitting. We demonstrate the approach using laboratory column experimental data, synthetic streambed experimental data, and field tracer-test data. Results from the analytical approach compare favorably with results from calibration of numerical models and also independent measurements of mobile and less-mobile porosity. We show that localized electrical hysteresis patterns resulting from diffusive exchange are independent of injection velocity, indicating that repeatable parameters can be extracted under varied experimental designs, and these parameters represent the true intrinsic properties of specific volumes of porous media of aquifers and hyporheic zones.

  12. Thin films of spin-crossover coordination polymers with large thermal hysteresis loops prepared by nanoparticle spin coating.

    PubMed

    Tanaka, Daisuke; Aketa, Naoki; Tanaka, Hirofumi; Tamaki, Takashi; Inose, Tomoko; Akai, Tomoki; Toyama, Hirotaka; Sakata, Osami; Tajiri, Hiroo; Ogawa, Takuji

    2014-09-11

    This communication describes the synthesis of spin-crossover nanoparticles, which can disperse in various organic solvents without an excess amount of surfactants. The nanoparticles form homogeneous thin films on substrates by spin coating. The films show abrupt spin transitions with large thermal hysteresis loops.

  13. Wetting hysteresis induced by temperature changes: Supercooled water on hydrophobic surfaces.

    PubMed

    Heydari, Golrokh; Sedighi Moghaddam, Maziar; Tuominen, Mikko; Fielden, Matthew; Haapanen, Janne; Mäkelä, Jyrki M; Claesson, Per M

    2016-04-15

    The state and stability of supercooled water on (super)hydrophobic surfaces is crucial for low temperature applications and it will affect anti-icing and de-icing properties. Surface characteristics such as topography and chemistry are expected to affect wetting hysteresis during temperature cycling experiments, and also the freezing delay of supercooled water. We utilized stochastically rough wood surfaces that were further modified to render them hydrophobic or superhydrophobic. Liquid flame spraying (LFS) was utilized to create a multi-scale roughness by depositing titanium dioxide nanoparticles. The coating was subsequently made non-polar by applying a thin plasma polymer layer. As flat reference samples modified silica surfaces with similar chemistries were utilized. With these substrates we test the hypothesis that superhydrophobic surfaces also should retard ice formation. Wetting hysteresis was evaluated using contact angle measurements during a freeze-thaw cycle from room temperature to freezing occurrence at -7°C, and then back to room temperature. Further, the delay in freezing of supercooled water droplets was studied at temperatures of -4°C and -7°C. The hysteresis in contact angle observed during a cooling-heating cycle is found to be small on flat hydrophobic surfaces. However, significant changes in contact angles during a cooling-heating cycle are observed on the rough surfaces, with a higher contact angle observed on cooling compared to during the subsequent heating. Condensation and subsequent frost formation at sub-zero temperatures induce the hysteresis. The freezing delay data show that the flat surface is more efficient in enhancing the freezing delay than the rougher surfaces, which can be rationalized considering heterogeneous nucleation theory. Thus, our data suggests that molecular flat surfaces, rather than rough superhydrophobic surfaces, are beneficial for retarding ice formation under conditions that allow condensation and frost

  14. The hysteresis response of soil CO2 concentration and soil respiration to soil temperature

    NASA Astrophysics Data System (ADS)

    Zhang, Quan; Katul, Gabriel G.; Oren, Ram; Daly, Edoardo; Manzoni, Stefano; Yang, Dawen

    2015-08-01

    Diurnal hysteresis between soil temperature (Ts) and both CO2 concentration ([CO2]) and soil respiration rate (Rs) were reported across different field experiments. However, the causes of these hysteresis patterns remain a subject of debate, with biotic and abiotic factors both invoked as explanations. To address these issues, a CO2 gas transport model is developed by combining a layer-wise mass conservation equation for subsurface gas phase CO2, Fickian diffusion for gas transfer, and a CO2 source term that depends on soil temperature, moisture, and photosynthetic rate. Using this model, a hierarchy of numerical experiments were employed to disentangle the causes of the hysteretic [CO2]-Ts and CO2 flux Ts (i.e., F-Ts) relations. Model results show that gas transport alone can introduce both [CO2]-Ts and F-Ts hystereses and also confirm prior findings that heat flow in soils lead to [CO2] and F being out of phase with Ts, thereby providing another reason for the occurrence of both hystereses. The area (Ahys) of the [CO2]-Ts hysteresis near the surface increases, while the Ahys of the Rs-Ts hysteresis decreases as soils become wetter. Moreover, a time-lagged carbon input from photosynthesis deformed the [CO2]-Ts and Rs-Ts patterns, causing a change in the loop direction from counterclockwise to clockwise with decreasing time lag. An asymmetric 8-shaped pattern emerged as the transition state between the two loop directions. Tracing the pattern and direction of the hysteretic [CO2]-Ts and Rs-Ts relations can provide new ways to fingerprint the effects of photosynthesis stimulation on soil microbial activity and detect time lags between rhizospheric respiration and photosynthesis.

  15. Observations of hysteresis in solar cycle variations among seven solar activity indicators

    NASA Technical Reports Server (NTRS)

    Bachmann, Kurt T.; White, Oran R.

    1994-01-01

    We show that smoothed time series of 7 indices of solar activity exhibit significant solar cycle dependent differences in their relative variations during the past 20 years. In some cases these observed hysteresis patterns start to repeat over more than one solar cycle, giving evidence that this is a normal feature of solar variability. Among the indices we study, we find that the hysteresis effects are approximately simple phase shifts, and we quantify these phase shifts in terms of lag times behind the leading index, the International Sunspot Number. Our measured lag times range from less than one month to greater than four months and can be much larger than lag times estimated from short-term variations of these same activity indices during the emergence and decay of major active regions. We argue that hysteresis represents a real delay in the onset and decline of solar activity and is an important clue in the search for physical processes responsible for changing solar emission at various wavelengths.

  16. Modeling of galfenol bending actuator considering nonlinear hysteresis and dynamic real-time control strategy

    NASA Astrophysics Data System (ADS)

    Shu, Liang; Wu, Guichu; Chen, Dingfang; Dapino, Marcelo J.

    2016-03-01

    On active bending structures, the actuation direction and the excitation field direction are not the same. Simple lumped parameter models are inadequate to describe the relationship between output displacement and input field. In this paper, a dynamic distributed parameter model is presented to describe the system dynamics of a galfenol bending actuator. To consider nonlinearities and hysteresis in bending, a nonlinear magnetomechanical model is developed to characterize the hysteretic magnetostriction generated by the galfenol layer. A dynamic real-time control strategy is proposed to compensate for hysteresis. A nonlinear inverse filter is constructed to linearize the hysteresis based on the proposed distributed parameter model. In order to increase the calculation efficiency, a new iteration method is proposed to calculate the filter. The iteration stepsize of the input field can be adaptively updated according to the inverting error. Simulation results show that significant enhancement of convergence efficiency can be achieved by using the proposed method compared with the existing fixed step size method. Experiments have been conducted to verify the real-time control strategy.

  17. Inkjet printing of precisely defined features using contact-angle hysteresis.

    PubMed

    Soltman, Dan; Smith, Ben; Morris, S J S; Subramanian, Vivek

    2013-06-15

    Motivated by the process of inkjet printing of electronics, we study experimentally and theoretically the processes limiting the printing of sharply defined, equilibrium corners. Using a non-volatile ionic liquid, we inkjet print squares with rounded corners on a substrate of roughened, display-grade glass. We show experimentally that with increasing roughness, corner radius decreases, allowing more precisely defined features to be printed. To interpret these results in terms of contact-angle hysteresis (difference between the advancing and retreating contact angles θA and θR), we implement the following model with the Surface Evolver program. With drop volume fixed, we minimize drop surface energy subject to a prescribed contact line. We identify θA and θR as the minimum and maximum contact angles around the drop perimeter. We find that with decreasing corner fidelity, contact-angle hysteresis also decreases. We are thus able to infer θR from the corner radius of printed features. We conclude that increasing contact-angle hysteresis allows the printing of more precisely defined features.

  18. Mode transition and hysteresis in inductively coupled radio frequency argon discharge

    NASA Astrophysics Data System (ADS)

    Wegner, Th.; Küllig, C.; Meichsner, J.

    2016-02-01

    This contribution presents experimental results about the mode transition of an inductively coupled radio frequency (RF) (13.56 MHz) argon discharge at different total gas pressures. In particular, the positive ion saturation current and the line integrated electron density are measured by Langmuir probe and 160 GHz microwave interferometer, respectively. The mode transition strongly depends on the total gas pressure and can appear stepwise or continuously. The space resolved positive ion saturation current is separately shown for the E- and H-mode at different total gas pressures. Therewith, the pressure dependency of the RF sheath thickness indicates a collisional sheath. The hysteresis phenomenon during the E-H and the inverse H-E transition is discussed within the framework of the matching situation for different total gas pressures. The hysteresis width is analyzed using the absorbed power as well as the coil voltage and current. As a result, the width strongly increases with pressure regarding the power and the coil voltage in the E-mode and remains constant in the H-mode. In addition, the phase shift between the coil voltage and current shows a hysteresis effect, too.

  19. Temperature-Salinity Oscillations, Sudden Transitions, and Hysteresis in Laboratory Experiments and Layered Models

    NASA Astrophysics Data System (ADS)

    Whitehead, J. A.; Te Raa, L.; Tozuka, T.

    2002-12-01

    Simplified box models of the cooling of a salt-stratified ocean have been constructed in the laboratory. A large isothermal basin of water has two layers with differing salinity. Beside this is a small basin connected to the large basin by horizontal tubes at the top, middle and bottom. Calculations indicate that there is a sudden transition and hysteresis between a shallow and a deep convection state if there is a relaxation temperature boundary condition and also if one tube has large flow resistance. Our laboratory studies to date do not clearly show hysteresis but have relatively sudden changes in properties for some parameters. The shallow state is frequently found as an oscillation, and the deep convection state is steady, although thermals produce small rapid fluctuations. Numerical models of the experiments produce qualitative agreement, but quantitative differences are large. In contrast, experiments with a cavity at the bottom of a fresh water reservoir, subjected to steady heating from below and steady salt-water inflow has two distinct states, and exhibits a hysteresis range. Oscillations and transitions like those seen in these experiments may exist in natural bodies with a layer of fresh water cooled from above such as fjords, polar bays, or larger polar regions. The oscillation periods are much greater than either the fresh water or the thermal time scale, making the oscillation mechanism a candidate for climate oscillations. (Much of this work was done at the GFD summer program).

  20. Hysteresis Analysis and Positioning Control for a Magnetic Shape Memory Actuator

    PubMed Central

    Lin, Jhih-Hong; Chiang, Mao-Hsiung

    2015-01-01

    Magnetic shape memory alloys (MSM alloys), a new kind of smart materials, have become a potential candidate in many engineering fields. MSMs have the advantage of bearing a huge strain, much larger than other materials. In addition, they also have fast response. These characteristics make MSM a good choice in micro engineering. However, MSMs display the obvious hysteresis phenomenon of nonlinear behavior. Thus the difficulty in using the MSM element as a positioning actuator is increased due to the hysteresis. In this paper, the hysteresis phenomenon of the MSM actuator is analyzed, and the closed-loop positioning control is also implemented experimentally. For that, a modified fuzzy sliding mode control (MFSMC) is proposed. The MFSMC and the PID control are used to design the controllers for realizing the positioning control. The experimental results are compared under different experimental conditions, such as different frequency, amplitude, and loading. The experimental results show that the precise positioning control of MFSMC can be achieved satisfactorily. PMID:25853405

  1. Magnetic hysteresis and Barkhausen noise emission analysis of magnetic materials and composites

    NASA Astrophysics Data System (ADS)

    Prabhu Gaunkar, Neelam

    specialchapt{ABSTRACT}. Barkhausen emission studies have been used to analyze the effect of residual stresses in ferromagnetic materials. The stresses generated due to mechanical wear and tear, abrasion and prolonged use can also lead to phase changes within the material. These phase changes can cause damage to the structural parts and should be prevented. In this study we analyze the magnetic hysteresis and Barkhausen noise profile of materials with more than one ferromagnetic phase. The correlation between the hysteresis and Barkhausen noise profiles for such materials is studied. Secondary Barkhausen emission peaks can be simulated for such materials. Experimental observations are compared with simulation measurements. Drawing a correlation between the secondary emergent peaks and the composition of each secondary phase should lead to an improved technique for non-destructive characterization of ferromagnetic materials. . Improved sensor-to-specimen coupling is also essential for conducting Barkhausen noise measurements of multiphase materials which may also have different surface geometries. A finite element study was conducted to optimize the design parameters of the magnetizing core in a Barkhausen noise sensor. Several sensor parameters inclusive of core material, core-tip curvature, core length and pole spacing were studied. A procedure for developing a high sensitivity Barkhausen noise sensor by design optimization based on finite element simulations has been demonstrated. The study also shows the applicability of Barkhausen emission and magnetic hysteresis analysis as advanced tools of non-destructive characterization of ferromagnetic materials.

  2. A GCMC simulation and experimental study of krypton adsorption/desorption hysteresis on a graphite surface.

    PubMed

    Prasetyo, Luisa; Horikawa, Toshihide; Phadungbut, Poomiwat; Johnathan Tan, Shiliang; Do, D D; Nicholson, D

    2016-09-15

    Adsorption isotherms and isosteric heats of krypton on a highly graphitized carbon black, Carbopack F, have been studied with a combination of Monte Carlo simulation and high-resolution experiments at 77K and 87K. Our investigation sheds light on the microscopic origin of the experimentally observed, horizontal hysteresis loop in the first layer, and the vertical hysteresis-loop in the second layer, and is found to be in agreement with our recent Monte Carlo simulation study (Diao et al., 2015). From detailed analysis of the adsorption isotherm, the latter is attributed to the compression of an imperfect solid-like state in the first layer, to form a hexagonally packed, solid-like state, immediately following the first order condensation of the second layer. To ensure that capillary condensation in the confined spaces between microcrystallites of Carbopack F does not interfere with these hysteresis loops, we carried out simulations of krypton adsorption in the confined space of a wedge-shaped pore that mimics the interstices between particles. These simulations show that, up to the third layer, any such interference is negligible.

  3. Nonequilibrium hysteresis and Wien effect water dissociation at a bipolar membrane

    NASA Astrophysics Data System (ADS)

    Conroy, D. T.; Craster, R. V.; Matar, O. K.; Cheng, L.-J.; Chang, H.-C.

    2012-11-01

    As in electrochemical cyclic voltammetry, time-periodic reverse voltage bias across a bipolar membrane is shown to exhibit hysteresis due to transient effects. This is due to the incomplete depletion of mobile ions, at the junction between the membranes, within two adjoining polarized layers; the layer thickness depends on the applied voltage and the surface charge densities. Experiments show that the hysteresis consists of an Ohmic linear rise in the total current with respect to the voltage, followed by a decay of the current. A limiting current is established for a long period when all the mobile ions are depleted from the polarized layer. If the resulting high field within the two polarized layers is sufficiently large, water dissociation occurs to produce proton and hydroxyl traveling wave fronts which contribute to another large jump in the current. We use numerical simulation and asymptotic analysis to interpret the experimental results and to estimate the amplitude of the transient hysteresis and the water-dissociation current.

  4. The antifreeze potential of the spruce budworm thermal hysteresis protein.

    PubMed

    Tyshenko, M G; Doucet, D; Davies, P L; Walker, V K

    1997-09-01

    Antifreeze proteins (AFP) inhibit ice growth by surface adsorption that results in a depression of the freezing point below the melting point. The maximum level of this thermal hysteresis shown by the four structurally unrelated fish AFP is approximately 1.5 degrees C. In contrast, hemolymph and crude extracts from insects can have 5 degrees to 10 degrees C of thermal hysteresis. Based on the isolation, cloning, and expression of a thermal hysteresis protein (THP) from spruce budworm (Choristoneura fumiferana), the vastly greater activity is attributable to a 9 kDa protein. This novel, threonine- and cysteine-rich THP has striking effects on ice crystal morphology, both before and during freezing. It is also 10 to 30 times more active than any known fish AFP, offering the prospect of superior antifreeze properties in cryoprotective applications.

  5. Sinusoidal input describing function for hysteresis followed by elementary backlash

    NASA Technical Reports Server (NTRS)

    Ringland, R. F.

    1976-01-01

    The author proposes a new sinusoidal input describing function which accounts for the serial combination of hysteresis followed by elementary backlash in a single nonlinear element. The output of the hysteresis element drives the elementary backlash element. Various analytical forms of the describing function are given, depending on the a/A ratio, where a is the half width of the hysteresis band or backlash gap, and A is the amplitude of the assumed input sinusoid, and on the value of the parameter representing the fraction of a attributed to the backlash characteristic. The negative inverse describing function is plotted on a gain-phase plot, and it is seen that a relatively small amount of backlash leads to domination of the backlash character in the describing function. The extent of the region of the gain-phase plane covered by the describing function is such as to guarantee some form of limit cycle behavior in most closed-loop systems.

  6. Hysteresis Modeling in Magnetostrictive Materials Via Preisach Operators

    NASA Technical Reports Server (NTRS)

    Smith, R. C.

    1997-01-01

    A phenomenological characterization of hysteresis in magnetostrictive materials is presented. Such hysteresis is due to both the driving magnetic fields and stress relations within the material and is significant throughout, most of the drive range of magnetostrictive transducers. An accurate characterization of the hysteresis and material nonlinearities is necessary, to fully utilize the actuator/sensor capabilities of the magnetostrictive materials. Such a characterization is made here in the context of generalized Preisach operators. This yields a framework amenable to proving the well-posedness of structural models that incorporate the magnetostrictive transducers. It also provides a natural setting in which to develop practical approximation techniques. An example illustrating this framework in the context of a Timoshenko beam model is presented.

  7. An Energy-Based Hysteresis Model for Magnetostrictive Transducers

    NASA Technical Reports Server (NTRS)

    Calkins, F. T.; Smith, R. C.; Flatau, A. B.

    1997-01-01

    This paper addresses the modeling of hysteresis in magnetostrictive transducers. This is considered in the context of control applications which require an accurate characterization of the relation between input currents and strains output by the transducer. This relation typically exhibits significant nonlinearities and hysteresis due to inherent properties of magnetostrictive materials. The characterization considered here is based upon the Jiles-Atherton mean field model for ferromagnetic hysteresis in combination with a quadratic moment rotation model for magnetostriction. As demonstrated through comparison with experimental data, the magnetization model very adequately quantifies both major and minor loops under various operating conditions. The combined model can then be used to accurately characterize output strains at moderate drive levels. The advantages to this model lie in the small number (six) of required parameters and the flexibility it exhibits in a variety of operating conditions.

  8. Contact Hysteresis and Friction of Alkanethiol SAMs on Au

    SciTech Connect

    Houston, J.E.; Kiely, J.D.

    1998-10-14

    Nanoindentation has been combhed with nanometer-scale friction measurements to identi~ dissipative mechanisms responsible for friction in hexadecanethiol self-assembled monolayer on Au. We have demonstrated that friction is primarily due to viscoelastic relaxations within the films, which give rise to contact hysteresis when deformation rates are within the ranges of 5 and 200 k. We observe that this contact hysteresis increases with exposure to air such that the friction coefficient increases from 0.004 to 0.075 when films are exposed to air for 40 days. Both hysteresis and friction increase with probe speed, and we present a model of friction that characterizes this speed dependence and which also predicts a linear dependence of friction on normal force in thin organic films. Finally, we identify several short-term wear regimes and identify that wear changes dramatically when fdms age.

  9. A modified Prandtl-Ishlinskii modeling method for hysteresis

    NASA Astrophysics Data System (ADS)

    Dong, Ruili; Tan, Yonghong

    2009-05-01

    A modified Prandtl-Ishlinskii modeling method for rate-independent hysteresis in piezoelectric actuators is proposed in this paper. In this method, a generalized backlash operator (GBO) regarded as the elementary operator is introduced into the model so as to be more flexible for modeling of complex hysteresis. Moreover, the Levenberg-Marquardt algorithm is used to estimate the parameters of the model. Thus, all the parameters of the modified PI model can be determined automatically. From this way, it avoids the tedious procedure for the selection of the operator parameters by trial and error. Then, a group of proper Clarke subgradients of the GBO outputs with respect to their parameters at a non-smooth point is obtained based on the bundle method. Finally, the experimental results of applying the proposed method to the modeling of hysteresis in a piezoelectric actuator and an ultrasonic motor (USM) are illustrated, respectively.

  10. Direct recursive identification of the Preisach hysteresis density function

    NASA Astrophysics Data System (ADS)

    Ruderman, Michael

    2013-12-01

    In this paper, a novel direct method of recursive identification of the Preisach hysteresis density function is proposed. Using the discrete dynamic Preisach model, which is a state-space realization of the classical scalar Preisach model, the method is designed based on the output increment error. After giving the general formulation, the identification scheme implemented for a discretized Preisach plane is introduced and evaluated through the use of numerical simulations. Two cases of Gaussian mixtures are considered for mapping the hysteresis system to be identified. The parameter convergence is shown for a low-pass filtered white-noise input. Further, the proposed identification method is applied to a magnetism-related application example, where the flux linkage hysteresis of a proportional solenoid is assumed from the measurements, and then the inverse of a standard demagnetization procedure is utilized as the identification sequence.

  11. Origin of J-V Hysteresis in Perovskite Solar Cells.

    PubMed

    Chen, Bo; Yang, Mengjin; Priya, Shashank; Zhu, Kai

    2016-03-03

    High-performance perovskite solar cells (PSCs) based on organometal halide perovskite have emerged in the past five years as excellent devices for harvesting solar energy. Some remaining challenges should be resolved to continue the momentum in their development. The photocurrent density-voltage (J-V) responses of the PSCs demonstrate anomalous dependence on the voltage scan direction/rate/range, voltage conditioning history, and device configuration. The hysteretic J-V behavior presents a challenge for determining the accurate power conversion efficiency of the PSCs. Here, we review the recent progress on the investigation of the origin(s) of J-V hysteresis behavior in PSCs. We discuss the impact of slow transient capacitive current, trapping and detrapping process, ion migrations, and ferroelectric polarization on the hysteresis behavior. The remaining issues and future research required toward the understanding of J-V hysteresis in PSCs will also be discussed.

  12. A survey on hysteresis modeling, identification and control

    NASA Astrophysics Data System (ADS)

    Hassani, Vahid; Tjahjowidodo, Tegoeh; Do, Thanh Nho

    2014-12-01

    The various mathematical models for hysteresis such as Preisach, Krasnosel'skii-Pokrovskii (KP), Prandtl-Ishlinskii (PI), Maxwell-Slip, Bouc-Wen and Duhem are surveyed in terms of their applications in modeling, control and identification of dynamical systems. In the first step, the classical formalisms of the models are presented to the reader, and more broadly, the utilization of the classical models is considered for development of more comprehensive models and appropriate controllers for corresponding systems. In addition, the authors attempt to encourage the reader to follow the existing mathematical models of hysteresis to resolve the open problems.

  13. Large-scale separation and hysteresis in cascades

    NASA Technical Reports Server (NTRS)

    Rothmayer, A. P.; Smith, F. T.

    1985-01-01

    An approach using a two-dimensional thin aerofoil, allied with the theory of viscous bluff-body separation, is used to study the initial cross-over from massive separation to an attached flow in a single-row unstaggered cascade. Analytic solutions are developed for the limit of small cascade-spacing. From the analytic solutions several interesting features of the cascade are examined, including multiple-solution branches and multiple regions of hysteresis. In addition, numerical results are presented for several selected aerofoils. Some of the aerofoils are found to contain markedly enlarged regions of hysteresis for certain critical cascade spacings.

  14. Modeling of Switching and Hysteresis in Molecular Transport

    NASA Technical Reports Server (NTRS)

    Samanta, Manoj P.; Partridge, Harry (Technical Monitor)

    2002-01-01

    The conventional way of modeling current transport in two and three terminal molecular devices could be inadequate for certain cases involving switching and hysteresis. Here we present an alternate approach. Contrary to the regular way where applied bias directly modulates the conducting energy levels of the molecule, our method introduces a nonlinear potential energy surface varying with the applied bias as a control parameter. A time-dynamics is also introduced properly accounting for switching and hysteresis behavior. Although the model is phenomenological at this stage, we believe any detailed model would contain similar descriptions at its core.

  15. Low hysteresis FeMn-based top spin valve.

    PubMed

    Ustinov, V V; Krinitsina, T P; Milyaev, M A; Naumova, L I; Proglyado, V V

    2012-09-01

    FeMn-based top spin valves Ta/[FeNi/CoFe]/Cu/CoFe/FeMn/Ta with different Cu and FeMn layers thicknesses were prepared by DC magnetron sputtering at room temperature. It was shown that low field hysteresis due to free layer magnetization reversal can be reduced down to (0.1 divided by 0.2) Oe keeping the GMR ratio higher 8% by using both layers thicknesses optimization and non-collinear geometry of magnetoresistance measurements. Dependence of low field hysteresis and GMR ratio on the angle between applied magnetic field and pinning direction are presented.

  16. Nonlinear space charge dynamics in mixed ionic-electronic conductors: Resistive switching and ferroelectric-like hysteresis of electromechanical response

    SciTech Connect

    Morozovska, Anna N.; Morozovsky, Nicholas V.; Eliseev, Eugene A.; Varenyk, Olexandr V.; Kim, Yunseok; Strelcov, Evgheni; Tselev, Alexander; Kalinin, Sergei V.

    2014-08-14

    We performed self-consistent modelling of nonlinear electrotransport and electromechanical response of thin films of mixed ionic-electronic conductors (MIEC) allowing for steric effects of mobile charged defects (ions, protons, or vacancies), electron degeneration, and Vegard stresses. We establish correlations between the features of the nonlinear space-charge dynamics, current-voltage, and bending-voltage curves for different types of the film electrodes. A pronounced ferroelectric-like hysteresis of the bending-voltage loops and current maxima on the double hysteresis current-voltage loops appear for the electron-transport electrodes. The double hysteresis loop with pronounced humps indicates a memristor-type resistive switching. The switching occurs due to the strong nonlinear coupling between the electronic and ionic subsystems. A sharp meta-stable maximum of the electron density appears near one open electrode and moves to another one during the periodic change of applied voltage. Our results can explain the nonlinear nature and correlation of electrical and mechanical memory effects in thin MIEC films. The analytical expression proving that the electrically induced bending of MIEC films can be detected by interferometric methods is derived.

  17. A complete soil hydraulic model accounting for capillary and adsorptive water retention, capillary and film conductivity, and hysteresis

    NASA Astrophysics Data System (ADS)

    Rudiyanto; Sakai, Masaru; van Genuchten, Martinus Th.; Alazba, A. A.; Setiawan, Budi Indra; Minasny, Budiman

    2015-11-01

    A soil hydraulic model that considers capillary hysteretic and adsorptive water retention as well as capillary and film conductivity covering the complete soil moisture range is presented. The model was obtained by incorporating the capillary hysteresis model of Parker and Lenhard into the hydraulic model of Peters-Durner-Iden (PDI) as formulated for the van Genuchten (VG) retention equation. The formulation includes the following processes: capillary hysteresis accounting for air entrapment, closed scanning curves, nonhysteretic sorption of water retention onto mineral surfaces, a hysteretic function for the capillary conductivity, a nonhysteretic function for the film conductivity, and a nearly nonhysteretic function of the conductivity as a function of water content (θ) for the entire range of water contents. The proposed model only requires two additional parameters to describe hysteresis. The model was found to accurately describe observed hysteretic water retention and conductivity data for a dune sand. Using a range of published data sets, relationships could be established between the capillary water retention and film conductivity parameters. Including vapor conductivity improved conductivity descriptions in the very dry range. The resulting model allows predictions of the hydraulic conductivity from saturation until complete dryness using water retention parameters.

  18. Evaluation of the potential for hysteresis in index-velocity ratings for the Chicago Sanitary and Ship Canal near Lemont, Illinois

    USGS Publications Warehouse

    Jackson, P. Ryan; Sinha, Sumit; Dutta, Som; Johnson, Kevin K.; Duncker, James J.; Garcia, Marcelo H.

    2013-01-01

    The U.S. Geological Survey (USGS) is responsible for monitoring flows in the Chicago Sanitary and Ship Canal (CSSC) near Lemont, Illinois, as a part of the Lake Michigan Diversion Accounting overseen by the U.S. Army Corps of Engineers, Chicago District. Lake Michigan Diversion Accounting is mandated by a U.S. Supreme Court decree in order to monitor, and limit, the State of Illinois’ annual diversion of Great Lakes water through the manmade CSSC. Every 5 years, a technical review committee consisting of practicing engineers and academics reviews USGS streamgaging practices in the CSSC near Lemont, Illinois. The sixth technical review committee expressed concern that the index-velocity rating—the method used to estimate mean cross-sectional velocity from a measured index velocity—may be subject to hysteresis at this site because of the unique, unsteady hydraulics of the canal. Hysteresis in index-velocity ratings can occur at sites where the flow distribution in the channel varies significantly between the rising and falling limbs of the hydrograph for the same discharge. Presently, hysteresis in index-velocity ratings has been documented only in tidally affected sites. This report investigates whether hysteresis can occur at this nontidal site, and the conditions under which it is likely to occur, by using both a theoretical approach and a three-dimensional hydrodynamic model. The theoretical analysis investigated the conditions required for hysteresis in the index-velocity rating, and the modeling analysis focused on the effect of the timing of the inflows from the CSSC and the Cal-Sag Channel on the potential for hysteresis and whether highly resolved simulations of actual high-flow events show any evidence of hysteresis. Based on both a theoretical analysis using observed historical data and an analysis using a three-dimensional hydrodynamic model, there is no conclusive evidence for the existence of hysteresis in the index-velocity rating at the USGS

  19. Shock detachment from curved wedges

    NASA Astrophysics Data System (ADS)

    Mölder, S.

    2017-03-01

    Curved shock theory is used to show that the flow behind attached shocks on doubly curved wedges can have either positive or negative post-shock pressure gradients depending on the freestream Mach number, the wedge angle and the two wedge curvatures. Given enough wedge length, the flow near the leading edge can choke to force the shock to detach from the wedge. This local choking can preempt both the maximum deflection and the sonic criteria for shock detachment. Analytical predictions for detachment by local choking are supported by CFD results.

  20. Interaction of bipolaron with the H2O/O2 redox couple causes current hysteresis in organic thin-film transistors.

    PubMed

    Qu, Minni; Li, Hui; Liu, Ran; Zhang, Shi-Li; Qiu, Zhi-Jun

    2014-01-01

    Hysteresis in the current-voltage characteristics is one of the major obstacles to the implementation of organic thin-film transistors in large-area integrated circuits. The hysteresis has been correlated either extrinsically to various charge-trapping/transfer mechanisms arising from gate dielectrics or surrounding ambience or intrinsically to the polaron-bipolaron reaction in low-mobility conjugated polymer thin-film transistors. However, a comprehensive understanding essential for developing viable solutions to eliminate hysteresis is yet to be established. By embedding carbon nanotubes in the polymer-based conduction channel of various lengths, here we show that the bipolaron formation/recombination combined with the H2O/O2 electrochemical reaction is responsible for the hysteresis in organic thin-film transistors. The bipolaron-induced hysteresis is a thermally activated process with an apparent activation energy of 0.29 eV for the bipolaron dissociation. This finding leads to a hysteresis model that is generally valid for thin-film transistors with both band transport and hopping conduction in semiconducting thin films.

  1. The Skipping Rope Curve

    ERIC Educational Resources Information Center

    Nordmark, Arne; Essen, Hanno

    2007-01-01

    The equilibrium of a flexible inextensible string, or chain, in the centrifugal force field of a rotating reference frame is investigated. It is assumed that the end points are fixed on the rotation axis. The shape of the curve, the skipping rope curve or "troposkien", is given by the Jacobi elliptic function sn. (Contains 3 figures.)

  2. Anodic Polarization Curves Revisited

    ERIC Educational Resources Information Center

    Liu, Yue; Drew, Michael G. B.; Liu, Ying; Liu, Lin

    2013-01-01

    An experiment published in this "Journal" has been revisited and it is found that the curve pattern of the anodic polarization curve for iron repeats itself successively when the potential scan is repeated. It is surprising that this observation has not been reported previously in the literature because it immediately brings into…

  3. Simulating Supernova Light Curves

    SciTech Connect

    Even, Wesley Paul; Dolence, Joshua C.

    2016-05-05

    This report discusses supernova light simulations. A brief review of supernovae, basics of supernova light curves, simulation tools used at LANL, and supernova results are included. Further, it happens that many of the same methods used to generate simulated supernova light curves can also be used to model the emission from fireballs generated by explosions in the earth’s atmosphere.

  4. Phase nucleation in curved space

    NASA Astrophysics Data System (ADS)

    Gómez, Leopoldo; García, Nicolás; Vitelli, Vincenzo; Lorenzana, José; Daniel, Vega

    Nucleation and growth is the dominant relaxation mechanism driving first-order phase transitions. In two-dimensional flat systems, nucleation has been applied to a wide range of problems in physics, chemistry and biology. Here we study nucleation and growth of two-dimensional phases lying on curved surfaces and show that curvature modifies both critical sizes of nuclei and paths towards the equilibrium phase. In curved space, nucleation and growth becomes inherently inhomogeneous and critical nuclei form faster on regions of positive Gaussian curvature. Substrates of varying shape display complex energy landscapes with several geometry-induced local minima, where initially propagating nuclei become stabilized and trapped by the underlying curvature (Gómez, L. R. et al. Phase nucleation in curved space. Nat. Commun. 6:6856 doi: 10.1038/ncomms7856 (2015).).

  5. Monte-Carlo multiscale simulation study of argon adsorption/desorption hysteresis in mesoporous heterogeneous tubular pores like MCM-41 or oxidized porous silicon.

    PubMed

    Puibasset, Joël

    2009-01-20

    In a recent paper [J. Chem. Phys. 2007, 127, 154701] a multiscale approach was introduced which allowed calculation of adsorption/desorption hysteresis for fluid confined in a single mesoporous, heterogeneous tubular pore. The main interest in using such an approach is that it allows one to reconcile a molecular simulation approach generally limited to the nanometer scale (atomistic description of the confined fluid and pore roughness) with the much larger scale (micrometer) relevant to understand the complexity of adsorption/desorption hysteresis (the numerous metastable states in the hysteresis loop are a consequence of the large-scale disorder in the porous material). In this paper, this multiscale approach is used to study adsorption phenomena in mesoporous models made of a collection of disordered, noninterconnected tubular pores, as MCM-41 or porous silicon. A double distribution is introduced: one to characterize the disorder in a given pore, and the other to characterize the disorder between the pores. We consider two distribution shapes: Gaussian and uniform truncated and two cases of pores open at one or both ends. These models are expected to cover a wide variety of real materials made of independent pores, as MCM-41 and oxidized porous silicon. A large variety of hysteresis shapes is obtained, ranging from almost parallel adsorption/desorption branches typical of MCM-41 adsorption to triangular hysteresis typical of porous silicon. The structure of the metastable states inside the hysteresis (scanning adsorption/desorption curves) is also examined. The results are expected to be useful to experimentalists who want to infer pore structure and level of disorder from experimental adsorption/desorption experiments.

  6. Mixture Modeling of Individual Learning Curves

    ERIC Educational Resources Information Center

    Streeter, Matthew

    2015-01-01

    We show that student learning can be accurately modeled using a mixture of learning curves, each of which specifies error probability as a function of time. This approach generalizes Knowledge Tracing [7], which can be viewed as a mixture model in which the learning curves are step functions. We show that this generality yields order-of-magnitude…

  7. Perovskite-Fullerene Hybrid Materials Eliminate Hysteresis In Planar Diodes

    DOE PAGES

    Xu, Jixian; Buin, Andrei; Ip, Alexander H.; ...

    2015-03-31

    Solution-processed planar perovskite devices are highly desirable in a wide variety of optoelectronic applications; however, they are prone to hysteresis and current instabilities. Here we report the first perovskite–PCBM hybrid solid with significantly reduced hysteresis and recombination loss achieved in a single step. This new material displays an efficient electrically coupled microstructure: PCBM is homogeneously distributed throughout the film at perovskite grain boundaries. The PCBM passivates the key PbI3 antisite defects during the perovskite self-assembly, as revealed by theory and experiment. Photoluminescence transient spectroscopy proves that the PCBM phase promotes electron extraction. We showcase this mixed material in planar solarmore » cells that feature low hysteresis and enhanced photovoltage. Using conductive AFM studies, we reveal the memristive properties of perovskite films. We close by positing that PCBM, by tying up both halide-rich antisites and unincorporated halides, reduces electric field-induced anion migration that may give rise to hysteresis and unstable diode behaviour.« less

  8. Hierarchically structured superoleophobic surfaces with ultralow contact angle hysteresis.

    PubMed

    Kota, Arun K; Li, Yongxin; Mabry, Joseph M; Tuteja, Anish

    2012-11-14

    Hierarchically structured, superoleophobic surfaces are demonstrated that display one of the lowest contact angle hysteresis values ever reported - even with extremely low-surface-tension liquids such as n-heptane. Consequently, these surfaces allow, for the first time, even ≈2 μL n-heptane droplets to bounce and roll-off at tilt angles. ≤ 2°.

  9. Contact angle hysteresis on regular pillar-like hydrophobic surfaces.

    PubMed

    Yeh, Kuan-Yu; Chen, Li-Jen; Chang, Jeng-Yang

    2008-01-01

    A series of pillar-like patterned silicon wafers with different pillar sizes and spacing are fabricated by photolithography and further modified by a self-assembled fluorosilanated monolayer. The dynamic contact angles of water on these surfaces are carefully measured and found to be consistent with the theoretical predictions of the Cassie model and the Wenzel model. When a water drop is at the Wenzel state, its contact angle hysteresis increases along with an increase in the surface roughness. While the surface roughness is further raised beyond its transition roughness (from the Wenzel state to the Cassie state), the contact angle hysteresis (or receding contact angle) discontinuously drops (or jumps) to a lower (or higher) value. When a water drop is at the Cassie state, its contact angle hysteresis strongly depends on the solid fraction and has nothing to do with the surface roughness. Even for a superhydrophobic surface, the contact angle hysteresis may still exhibit a value as high as 41 degrees for the solid fraction of 0.563.

  10. Dynamic contact angles and hysteresis under electrowetting-on-dielectric.

    PubMed

    Nelson, Wyatt C; Sen, Prosenjit; Kim, Chang-Jin C J

    2011-08-16

    By designing and implementing a new experimental method, we have measured the dynamic advancing and receding contact angles and the resulting hysteresis of droplets under electrowetting-on-dielectric (EWOD). Measurements were obtained over wide ranges of applied EWOD voltages, or electrowetting numbers (0 ≤ Ew ≤ 0.9), and droplet sliding speeds, or capillary numbers (1.4 × 10(-5) ≤ Ca ≤ 6.9 × 10(-3)). If Ew or Ca is low, dynamic contact angle hysteresis is not affected much by the EWOD voltage or the sliding speed; that is, the hysteresis increases by less than 50% with a 2 order-of-magnitude increase in sliding speed when Ca < 10(-3). If both Ew and Ca are high, however, the hysteresis increases with either the EWOD voltage or the sliding speed. Stick-slip oscillations were observed at Ew > 0.4. Data are interpreted with simplified hydrodynamic (Cox-Voinov) and molecular-kinetic theory (MKT) models; the Cox-Voinov model captures the trend of the data, but it yields unreasonable fitting parameters. MKT fitting parameters associated with the advancing contact line are reasonable, but a lack of symmetry indicates that a more intricate model is required.

  11. Hysteresis, Stability, and Ion Migration in Lead Halide Perovskite Photovoltaics.

    PubMed

    Miyano, Kenjiro; Yanagida, Masatoshi; Tripathi, Neeti; Shirai, Yasuhiro

    2016-06-16

    Ion migration has been suspected as the origin of various irreproducible and unstable properties, most notably the hysteresis, of lead halide perovskite photovoltaic (PV) cells since the early stage of the research. Although many evidence of ionic movement have been presented both numerically and experimentally, a coherent and quantitative picture that accounts for the observed irreproducible phenomena is still lacking. At the same time, however, it has been noticed that in certain types of PV cells, the hysteresis is absent or at least within the measurement reproducibility. We have previously shown that the electronic properties of hysteresis-free cells are well represented in terms of the conventional inorganic semiconductors. The reproducibility of these measurements was confirmed typically within tens of minutes under the biasing field of -1 V to +1.5 V. In order to probe the effect of ionic motion in the hysteresis-free cells, we extended the time scale and the biasing rage in the electronic measurements, from which we conclude the following: (1) From various evidence, it appears that ion migration is inevitable. However, it does not cause detrimental effects to the PV operation. (2) We propose, based on the quantitative characterization, that the degradation is more likely due to the chemical change at the interfaces between the carrier selective layers and perovskite rather than the compositional change of the lead iodide perovskite bulk. Together, they give much hope in the use of the lead iodide perovskite in the use of actual application.

  12. Small hysteresis and high energy storage power of antiferroelectric ceramics

    NASA Astrophysics Data System (ADS)

    Wang, Jinfei; Yang, Tongqing; Chen, Shengchen; Yao, Xi

    2014-09-01

    In this paper, modified Pb(Zr,Ti)O3(PZT) antiferroelectric (AFE) ceramics system was investigated by traditional solid state method. It was observed that the effect of different contents of Zr/Sn, Zr/Ti on modified PZT antiferroelectrics. With increasing Zr/Sn content, the EAFE (electric field of AFE phase to ferroelectric (FE) phase) value was enlarged. The phase switch field was reduced from FE to AFE (EFA). The hysteresis loops were changed from "slanted" to "square"-types. With increasing Zr/Ti concentrate, the EAFE value, and also the EFA was enlarged, while the hysteresis switch ΔE was reduced. The hysteresis loops was from "square" to "slanted"-types. The samples with square hysteresis loops are suitable for energy storage capacitor applications, the composition of ceramics was Pb0.97La0.02(Zr0.90Sn0.05Ti0.05)O3, which have the largest energy storage density 4.426J/cm3 at 227 kV/cm, and ΔE was 80 kV/cm, energy efficient η was about 0.612.

  13. Causes and implications of colloid and microorganism retention hysteresis

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Experiments were designed to better understand the causes and implications of colloid and microorganism retention hysteresis with transients in solution ionic strength (IS). Saturated packed column experiments were conducted using two sizes of carboxyl modified latex (CML) microspheres (0.1 and 1.1...

  14. Hysteresis loops revisited: An efficient method to analyze ferroic materials

    NASA Astrophysics Data System (ADS)

    Corbellini, Luca; Plathier, Julien; Lacroix, Christian; Harnagea, Catalin; Ménard, David; Pignolet, Alain

    2016-09-01

    Hysteresis loops characterize a wide variety of behaviors in fields ranging from physics and chemistry to economics and sociology. In particular, they represent the main characteristic of ferroic materials such as ferromagnetic and ferroelectric, which, in recent years, have attracted much interest due to their multifunctional properties. Although measuring such loops may not be experimentally complicated, extracting the intrinsic values of the characteristic parameters of the loop may prove difficult due to the different contributions to the measured hysteresis. In this paper, a simple technique is proposed to analyze hysteresis loops and to extract solely the contribution of the ferromagnetic or ferroelectric material. Such method consists in differentiating the measured loop, deconvoluting the different contributions and selectively integrating only the signals belonging to the ferroic response. A discussion of the limitations of the method is presented. Different measured ferromagnetic and ferroelectric hysteresis loops were also used to validate the technique. Comparison between experimental and reconstructed data demonstrated the precision and reliability of the technique. Moreover, application of such method allowed us to highlight properties of a Bi2FeCrO6 room temperature multiferroic thin film that were not previously observed.

  15. Intrinsic Hysteresis Loops Calculation of BZT Thin Films

    NASA Astrophysics Data System (ADS)

    Hikam, M.; Adnan, S. R.

    2014-04-01

    The Landau Devonshire (LK) simulation is utilized to calculate the intrinsic hysteresis properties of Barium Zirconium Titanate (BZT) doped by Indium and Lanthanum. A Delphi program run on Windows platform is used to facilitate the calculation. The simulation is very useful to calculate and understand the Gibbs free energy and the relationship between spontaneous polarization and electric field.

  16. Hysteresis Can Grant Fitness in Stochastically Varying Environment

    PubMed Central

    Friedman, Gary; McCarthy, Stephen; Rachinskii, Dmitrii

    2014-01-01

    Although the existence of multiple stable phenotypes of living organisms enables random switching between phenotypes as well as non-random history dependent switching called hysteresis, only random switching has been considered in prior experimental and theoretical models of adaptation to variable environments. This work considers the possibility that hysteresis may also evolve together with random phenotype switching to maximize population growth. In addition to allowing the possibility that switching rates between different phenotypes may depend not only on a continuous environmental input variable, but also on the phenotype itself, the present work considers an opportunity cost of the switching events. This opportunity cost arises as a result of a lag phase experimentally observed after phenotype switching and stochastic behavior of the environmental input. It is shown that stochastic environmental variation results in maximal asymptotic growth rate when organisms display hysteresis for sufficiently slowly varying environmental input. At the same time, sinusoidal input does not cause evolution of memory suggesting that the connection between the lag phase, stochastic environmental variation and evolution of hysteresis is a result of a stochastic resonance type phenomenon. PMID:25068284

  17. Anhysteretic and biased first magnetization curves for Finemet-type toroidal samples

    NASA Astrophysics Data System (ADS)

    Varga, L. K.; Kovács, Gy.; Takács, J.

    The anhysteretic and a set of biased first magnetization (BFMC) curves together with a set of first-order reversal curves (FORC) were measured and modeled by the hyperbolic T( x) model for a Finemet-type nanocrystalline toroidal sample with a round hysteresis loop. Similar to the FORC diagram, a "fingerprint"-like distribution has been obtained from a set of BFMC curves using the mixed second-derivate method of Pike. It is concluded that while the FORC diagram gives the distribution of coercive fields (or Preisach distribution), the BFMC diagram gives the distribution of the critical field where the domain wall magnetization become unstable and split up.

  18. Hysteresis in the dynamic perception of scenes and objects.

    PubMed

    Poltoratski, Sonia; Tong, Frank

    2014-10-01

    Scenes and objects are effortlessly processed and integrated by the human visual system. Given the distinct neural and behavioral substrates of scene and object processing, it is likely that individuals sometimes preferentially rely on one process or the other when viewing canonical "scene" or "object" stimuli. This would allow the visual system to maximize the specific benefits of these 2 types of processing. It is less obvious which of these modes of perception would be invoked during naturalistic visual transition between a focused view of a single object and an expansive view of an entire scene, particularly at intermediate views that may not be assigned readily to either stimulus category. In the current study, we asked observers to report their online perception of such dynamic image sequences, which zoomed and panned between a canonical view of a single object and an entire scene. We found a large and consistent effect of prior perception, or hysteresis, on the classification of the sequence: observers classified the sequence as an object for several seconds longer if the trial started at the object view and zoomed out, whereas scenes were perceived for longer on trials beginning with a scene view. This hysteresis effect resisted several manipulations of the movie stimulus and of the task performed, but hinged on the perceptual history built by unidirectional progression through the image sequence. Multiple experiments confirmed that this hysteresis effect was not purely decisional and was more prominent for transitions between corresponding objects and scenes than between other high-level stimulus classes. This finding suggests that the competitive mechanisms underlying hysteresis may be especially prominent in the perception of objects and scenes. We propose that hysteresis aids in disambiguating perception during naturalistic visual transitions, which may facilitate a dynamic balance between scene and object processing to enhance processing efficiency.

  19. Mechanics of Curved Folds

    NASA Astrophysics Data System (ADS)

    Dias, Marcelo A.; Santangelo, Christian D.

    2011-03-01

    Despite an almost two thousand year history, origami, the art of folding paper, remains a challenge both artistically and scientifically. Traditionally, origami is practiced by folding along straight creases. A whole new set of shapes can be explored, however, if, instead of straight creases, one folds along arbitrary curves. We present a mechanical model for curved fold origami in which the energy of a plastically-deformed crease is balanced by the bending energy of developable regions on either side of the crease. Though geometry requires that a sheet buckle when folded along a closed curve, its shape depends on the elasticity of the sheet. NSF DMR-0846582.

  20. Characterizing dynamic hysteresis and fractal statistics of chaotic two-phase flow and application to fuel cells

    NASA Astrophysics Data System (ADS)

    Burkholder, Michael B.; Litster, Shawn

    2016-05-01

    In this study, we analyze the stability of two-phase flow regimes and their transitions using chaotic and fractal statistics, and we report new measurements of dynamic two-phase pressure drop hysteresis that is related to flow regime stability and channel water content. Two-phase flow dynamics are relevant to a variety of real-world systems, and quantifying transient two-phase flow phenomena is important for efficient design. We recorded two-phase (air and water) pressure drops and flow images in a microchannel under both steady and transient conditions. Using Lyapunov exponents and Hurst exponents to characterize the steady-state pressure fluctuations, we develop a new, measurable regime identification criteria based on the dynamic stability of the two-phase pressure signal. We also applied a new experimental technique by continuously cycling the air flow rate to study dynamic hysteresis in two-phase pressure drops, which is separate from steady-state hysteresis and can be used to understand two-phase flow development time scales. Using recorded images of the two-phase flow, we show that the capacitive dynamic hysteresis is related to channel water content and flow regime stability. The mixed-wettability microchannel and in-channel water introduction used in this study simulate a polymer electrolyte fuel cell cathode air flow channel.

  1. Local Condensation Curve from Dropwise to Glacial Region on Large Vertical Surface

    NASA Astrophysics Data System (ADS)

    Haraguchi, Tadao; Shimada, Ryohachi; Takeyama, Toshiro

    The existence of several regimes of condensation heat transfer is well known. Regimes are given academic names as dropwise, transition, film and glacial condensation along the condensation curve showing the relationship between heat flux and surface subcooling. In case of comparatively large vertical surface, the lower part on the gravitational direction is affected by condensate from the upper part, and will be covered by water stream like a rivulet. It has no longer an existence as dropwise condition, and it is absolutely impossible that heat transfer problems under constant temperature or constant heat flux take place. The reason is why as follows, heat transfer of film condensation is some orders of magnitude less than dropwise condensation, and various regimes exist together simultaneously. In the present paper we shall try to observe the coexisting appearance of regimes in steam condensation at atmospheric pressure and make researches in the local condensation curve from top to bottom on the same surface, that is divided into eight parts in the rear side. The main results are shown as follows (1) Enhancement of heat transfer by wiping of drops appears toward somewhat lower position from top. (2) Frazil ice is observed in the supercooled liquid film flowing down on glacial condensation. (3) The regime of glacial condensation describes a thermal hysteresis loop.

  2. Insolation-driven 100,000-year glacial cycles and hysteresis of ice-sheet volume.

    PubMed

    Abe-Ouchi, Ayako; Saito, Fuyuki; Kawamura, Kenji; Raymo, Maureen E; Okuno, Jun'ichi; Takahashi, Kunio; Blatter, Heinz

    2013-08-08

    The growth and reduction of Northern Hemisphere ice sheets over the past million years is dominated by an approximately 100,000-year periodicity and a sawtooth pattern (gradual growth and fast termination). Milankovitch theory proposes that summer insolation at high northern latitudes drives the glacial cycles, and statistical tests have demonstrated that the glacial cycles are indeed linked to eccentricity, obliquity and precession cycles. Yet insolation alone cannot explain the strong 100,000-year cycle, suggesting that internal climatic feedbacks may also be at work. Earlier conceptual models, for example, showed that glacial terminations are associated with the build-up of Northern Hemisphere 'excess ice', but the physical mechanisms underpinning the 100,000-year cycle remain unclear. Here we show, using comprehensive climate and ice-sheet models, that insolation and internal feedbacks between the climate, the ice sheets and the lithosphere-asthenosphere system explain the 100,000-year periodicity. The responses of equilibrium states of ice sheets to summer insolation show hysteresis, with the shape and position of the hysteresis loop playing a key part in determining the periodicities of glacial cycles. The hysteresis loop of the North American ice sheet is such that after inception of the ice sheet, its mass balance remains mostly positive through several precession cycles, whose amplitudes decrease towards an eccentricity minimum. The larger the ice sheet grows and extends towards lower latitudes, the smaller is the insolation required to make the mass balance negative. Therefore, once a large ice sheet is established, a moderate increase in insolation is sufficient to trigger a negative mass balance, leading to an almost complete retreat of the ice sheet within several thousand years. This fast retreat is governed mainly by rapid ablation due to the lowered surface elevation resulting from delayed isostatic rebound, which is the lithosphere

  3. Dissociative Recombination without a Curve Crossing

    NASA Technical Reports Server (NTRS)

    Guberman, Steven L.

    1994-01-01

    Ab initio calculations show that a curve crossing is not always needed for a high dissociative- recombination cross section. For HeH(+), in which no neutral states cross the ion potential curve, dissociative recombination is driven by the nuclear kinetic-energy operator on adiabatic potential curves. The kinetic-energy derivative operator allows for capture into repulsive curves that are outside of the classical turning points for the nuclear motion. The dominant dissociative route is the C (2)Sigma(+) state leading to H(n = 2) atoms. An analogous mechanism is proposed for the dissociative recombination of H3(+).

  4. A kill curve for Phanerozoic marine species

    NASA Technical Reports Server (NTRS)

    Raup, D. M.

    1991-01-01

    A kill curve for Phanerozoic species is developed from an analysis of the stratigraphic ranges of 17,621 genera, as compiled by Sepkoski. The kill curve shows that a typical species' risk of extinction varies greatly, with most time intervals being characterized by very low risk. The mean extinction rate of 0.25/m.y. is thus a mixture of long periods of negligible extinction and occasional pulses of much higher rate. Because the kill curve is merely a description of the fossil record, it does not speak directly to the causes of extinction. The kill curve may be useful, however, to li inverted question markmit choices of extinction mechanisms.

  5. Finite transformers for construction of fractal curves

    SciTech Connect

    Lisovik, L.P.

    1995-01-01

    In this paper we continue the study of infinite R{sup n}-transformers that can be used to define real functions and three-dimensional curves. An R{sup n}-transformer A generates an output n-tuple A(x) = (Y{sub 1},...,Y{sub n}), consisting of output binary representations. We have previously shown that finite R{sup n}-transformers with n = 1, 2 can be used to define a continuous, nowhere differentiable function and a Peano curve. Curves of this kind are objects of fractal geometry. Here we show that some other fractal curves, which are analogs of the Koch curve and the Sierpinski napkin, can be defined by finite R{sup 2}-transformers. R{sup n}-transformers (and also finite R{sup n}-transformers) thus provide a convenient tool for definition of fractal curves.

  6. On-board capacity estimation of lithium iron phosphate batteries by means of half-cell curves

    NASA Astrophysics Data System (ADS)

    Marongiu, Andrea; Nlandi, Nsombo; Rong, Yao; Sauer, Dirk Uwe

    2016-08-01

    This paper presents a novel methodology for the on-board estimation of the actual battery capacity of lithium iron phosphate batteries. The approach is based on the detection of the actual degradation mechanisms by collecting plateau information. The tracked degradation modes are employed to change the characteristics of the fresh electrode voltage curves (mutual position and dimension), to reconstruct the full voltage curve and therefore to obtain the total capacity. The work presents a model which describes the relation between the single degradation modes and the electrode voltage curves characteristics. The model is then implemented in a novel battery management system structure for aging tracking and on-board capacity estimation. The working principle of the new algorithm is validated with data obtained from lithium iron phosphate cells aged in different operating conditions. The results show that both during charge and discharge the algorithm is able to correctly track the actual battery capacity with an error of approx. 1%. The use of the obtained results for the recalibration of a hysteresis model present in the battery management system is eventually presented, demonstrating the benefit of the tracked aging information for additional scopes.

  7. Enhancement of the transversal magnetic optic Kerr effect: Lock-in vs. hysteresis method.

    PubMed

    Hayek, Jorge Nicolás; Herreño-Fierro, César A; Patiño, Edgar J

    2016-10-01

    The lock-in amplifier is often used to study the enhancement of the magneto-optical Kerr effect (MOKE) in the presence of plasmon resonances. In the present work we show that it is possible to investigate such effect replacing the lock-in amplifier by a compensator, filter, and differential amplifier. This allows us to extract the full hysteresis loop in and out of the resonance without the need of a lock-in amplifier. Our results demonstrate these two setups are equivalent to study the enhancement of the transversal MOKE (T-MOKE) in magnetoplasmonic systems.

  8. Enhancement of the transversal magnetic optic Kerr effect: Lock-in vs. hysteresis method

    NASA Astrophysics Data System (ADS)

    Hayek, Jorge Nicolás; Herreño-Fierro, César A.; Patiño, Edgar J.

    2016-10-01

    The lock-in amplifier is often used to study the enhancement of the magneto-optical Kerr effect (MOKE) in the presence of plasmon resonances. In the present work we show that it is possible to investigate such effect replacing the lock-in amplifier by a compensator, filter, and differential amplifier. This allows us to extract the full hysteresis loop in and out of the resonance without the need of a lock-in amplifier. Our results demonstrate these two setups are equivalent to study the enhancement of the transversal MOKE (T-MOKE) in magnetoplasmonic systems.

  9. Breakpoint chlorination curves of greywater.

    PubMed

    March, J G; Gual, M

    2007-08-01

    A study on chlorination of raw greywater with hypochlorite is reported in this paper. Samples were chlorinated in a variety of conditions, and residual chlorine (Cl2) was measured spectrophotometrically. For each sample, the chlorination curve (chlorine residuals versus chlorine dose) was obtained. Curves showed the typical hump-and-dip profile attributable to the formation and destruction of chloramines. It was observed that, after reactions with strong reductants and chloramines-forming compounds, the remaining organic matter exerted a certain demand of chlorine. The evolution of chlorination curves with addition of ammonia and dodecylbencene sulfonate sodium salt and with dilution of the greywater sample were studied. In addition, chlorination curves at several contact times have been obtained, resulting in slower chlorine decay in the hump zone than in the dip zone. In addition, the decay of coliforms in chlorinated samples was also investigated. It was found that, for a chlorination dosage corresponding to the maximum of the hump zone (average 8.9 mg Cl2/ L), samples were negative in coliforms after 10 to 30 minutes of contact time. After-growth was not observed within 3 days after chlorination. Implications in chlorination treatments of raw greywater can be derived from these results.

  10. Measuring Model Rocket Engine Thrust Curves

    ERIC Educational Resources Information Center

    Penn, Kim; Slaton, William V.

    2010-01-01

    This paper describes a method and setup to quickly and easily measure a model rocket engine's thrust curve using a computer data logger and force probe. Horst describes using Vernier's LabPro and force probe to measure the rocket engine's thrust curve; however, the method of attaching the rocket to the force probe is not discussed. We show how a…

  11. Charge state hysteresis in semiconductor quantum dots

    SciTech Connect

    Yang, C. H.; Rossi, A. Lai, N. S.; Leon, R.; Lim, W. H.; Dzurak, A. S.

    2014-11-03

    Semiconductor quantum dots provide a two-dimensional analogy for real atoms and show promise for the implementation of scalable quantum computers. Here, we investigate the charge configurations in a silicon metal-oxide-semiconductor double quantum dot tunnel coupled to a single reservoir of electrons. By operating the system in the few-electron regime, the stability diagram shows hysteretic tunnelling events that depend on the history of the dots charge occupancy. We present a model which accounts for the observed hysteretic behaviour by extending the established description for transport in double dots coupled to two reservoirs. We demonstrate that this type of device operates like a single-electron memory latch.

  12. Multilevel non-volatile data storage utilizing common current hysteresis of networked single walled carbon nanotubes

    NASA Astrophysics Data System (ADS)

    Hwang, Ihn; Wang, Wei; Hwang, Sun Kak; Cho, Sung Hwan; Kim, Kang Lib; Jeong, Beomjin; Huh, June; Park, Cheolmin

    2016-05-01

    The characteristic source-drain current hysteresis frequently observed in field-effect transistors with networked single walled carbon-nanotube (NSWNT) channels is problematic for the reliable switching and sensing performance of devices. But the two distinct current states of the hysteresis curve at a zero gate voltage can be useful for memory applications. In this work, we demonstrate a novel non-volatile transistor memory with solution-processed NSWNTs which are suitable for multilevel data programming and reading. A polymer passivation layer with a small amount of water employed on the top of the NSWNT channel serves as an efficient gate voltage dependent charge trapping and de-trapping site. A systematic investigation evidences that the water mixed in a polymer passivation solution is critical for reliable non-volatile memory operation. The optimized device is air-stable and temperature-resistive up to 80 °C and exhibits excellent non-volatile memory performance with an on/off current ratio greater than 104, a switching time less than 100 ms, data retention longer than 4000 s, and write/read endurance over 100 cycles. Furthermore, the gate voltage dependent charge injection mediated by water in the passivation layer allowed for multilevel operation of our memory in which 4 distinct current states were programmed repetitively and preserved over a long time period.The characteristic source-drain current hysteresis frequently observed in field-effect transistors with networked single walled carbon-nanotube (NSWNT) channels is problematic for the reliable switching and sensing performance of devices. But the two distinct current states of the hysteresis curve at a zero gate voltage can be useful for memory applications. In this work, we demonstrate a novel non-volatile transistor memory with solution-processed NSWNTs which are suitable for multilevel data programming and reading. A polymer passivation layer with a small amount of water employed on the top of the

  13. PREFACE: International Workshop on Multi-Rate Processes and Hysteresis

    NASA Astrophysics Data System (ADS)

    Mortell, Michael P.; O'Malley, Robert E.; Pokrovskii, Alexei; Rachinskii, Dmitrii; Sobolev, Vladimir A.

    2008-07-01

    We are interested in singular perturbation problems and hysteresis as common strongly nonlinear phenomena that occur in many industrial, physical and economic systems. The wording `strongly nonlinear' means that linearization will not encapsulate the observed phenomena. Often these two types of phenomena are manifested for different stages of the same or similar processes. A number of fundamental hysteresis models can be considered as limit cases of time relaxation processes, or admit an approximation by a differential equation which is singular with respect to a particular parameter. However, the amount of interaction between practitioners of theories of systems with time relaxation and systems with hysteresis (and between the `relaxation' and `hysteresis' research communities) is still low, and cross-fertilization is small. In recent years Ireland has become a home for a series of prestigious International Workshops in Singular Perturbations and Hysteresis: International Workshop on Multi-rate Processes and Hysteresis (University College Cork, Ireland, 3-8 April 2006). Proceedings are published in Journal of Physics: Conference Series, volume 55. See further information at http://euclid.ucc.ie/murphys2008.htm International Workshop on Hysteresis and Multi-scale Asymptotics (University College Cork, Ireland, 17-21 March 2004). Proceedings are published in Journal of Physics: Conference Series, volume 22. See further information at http://euclid.ucc.ie/murphys2006.htm International Workshop on Relaxation Oscillations and Hysteresis (University College Cork, Ireland, 1-6 April 2002). The related collection of invited lectures, was published as a volume Singular Perturbations and Hysteresis, SIAM, Philadelphia, 2005. See further information at http://euclid.ucc.ie/hamsa2004.htm International Workshop on Geometrical Methods of Nonlinear Analysis and Semiconductor Laser Dynamics (University College Cork, Ireland, 5-5 April 2001). A collection of invited papers has been

  14. Hysteresis effects in the formation of a neutralizing beam plasma at low ion energy

    NASA Astrophysics Data System (ADS)

    Rafalskyi, Dmytro; Aanesland, Ane

    2013-11-01

    In this paper, the PEGASES II thruster prototype is used as an ion source generating low-energy (<300\\ \\text{eV}) positive Ar ion beam, extracted without an external neutralizer. The ions are extracted and accelerated from the source using a two-grid system. The extracted positive ion beam current is measured on a large beam target that can be translated along the acceleration axis. The ion beam current shows a stepwise transition from a low-current to a high-current extraction regime with hysteresis. The hysteresis region depends strongly upon the beam target position. Langmuir probe measurements in the plume show high plasma potentials and low plasma densities in the low-current mode, while the plasma potential drops and the density increases in the high-current mode. The ion energy distribution functions of the beam are measured for different regimes of ion extraction. The ion beam extracted in the high-current mode is indicated by the presence of an additional low-energy peak corresponding to ions from an ion-beam plasma created in the downstream chamber, as well as 10-20 times higher intensity of the primary ion beam peak. The hysteresis behavior is explained by the formation of a downstream neutralizing beam plasma, that depends on the target position and pressure in agreement with a Paschen-like breakdown by secondary electrons. The obtained results are of high relevance for further development of the PEGASES thruster, as well as for improving existing neutralizer-free concepts of the broad-beam ion sources.

  15. Hysteresis in suspended sediment to turbidity relations due to changing particle size distributions

    USGS Publications Warehouse

    Landers, Mark N.; Sturm, Terry W.

    2013-01-01

    Turbidity (T) is the most ubiquitous of surrogate technologies used to estimate suspended-sediment concentration (SSC). The effects of sediment size on turbidity are well documented; however, effects from changes in particle size distributions (PSD) are rarely evaluated. Hysteresis in relations of SSC-to-turbidity (SSC~T) for single stormflow events was observed and quantified for a data set of 195 concurrent measurements of SSC, turbidity, discharge, velocity, and volumetric PSD collected during five stormflows in 2009–2010 on Yellow River at Gees Mill Road in metropolitan Atlanta, Georgia. Regressions of SSC-normalized turbidity (T/SSC) on concurrently measured PSD percentiles show an inverse, exponential influence of particle size on turbidity that is not constant across the size range of the PSD. The majority of the influence of PSD on T/SSC is from particles of fine-silt and smaller sizes (finer than 16 microns). This study shows that small changes in the often assumed stability of the PSD are significant to SSC~T relations. Changes of only 5 microns in the fine silt and smaller size fractions of suspended sediment PSD can produce hysteresis in the SSC~T rating that can increase error and produce bias. Observed SSC~T hysteresis may be an indicator of changes in sediment properties during stormflows and of potential changes in sediment sources. Trends in the PSD time series indicate that sediment transport is capacity-limited for sand-sized sediment in the channel and supply-limited for fine silt and smaller sediment from the hillslope.

  16. Hysteresis in suspended sediment to turbidity relations due to changing particle size distributions

    NASA Astrophysics Data System (ADS)

    Landers, Mark N.; Sturm, Terry W.

    2013-09-01

    Turbidity (T) is the most ubiquitous of surrogate technologies used to estimate suspended-sediment concentration (SSC). The effects of sediment size on turbidity are well documented; however, effects from changes in particle size distributions (PSD) are rarely evaluated. Hysteresis in relations of SSC-to-turbidity (SSC˜T) for single stormflow events was observed and quantified for a dataset of 195 concurrent measurements of SSC, turbidity, discharge, velocity, and volumetric PSD collected during five stormflows in 2009-2010 on Yellow River at Gees Mill Road in metropolitan Atlanta, Georgia. Regressions of SSC-normalized turbidity (T/SSC) on concurrently measured PSD percentiles show an inverse, exponential influence of particle size on turbidity that is not constant across the size range of the PSD. The majority of the influence of PSD on T/SSC is from particles of fine silt and smaller sizes (finer than 16 µm). This study shows that small changes in the often assumed stability of the PSD are significant to SSC˜T relations. Changes of only 5 µm in the fine silt and smaller size fractions of suspended sediment PSD can produce hysteresis in the SSC˜T rating that can increase error and produce bias. Observed SSC˜T hysteresis may be an indicator of changes in sediment properties during stormflows and of potential changes in sediment sources. Trends in the PSD time series indicate that sediment transport is capacity limited for sand-sized sediment in the channel and supply limited for fine silt and smaller sediment from the hillslope.

  17. Are driving and overtaking on right curves more dangerous than on left curves?

    PubMed

    Othman, Sarbaz; Thomson, Robert; Lannér, Gunnar

    2010-01-01

    It is well known that crashes on horizontal curves are a cause for concern in all countries due to the frequency and severity of crashes at curves compared to road tangents. A recent study of crashes in western Sweden reported a higher rate of crashes in right curves than left curves. To further understand this result, this paper reports the results of novel analyses of the responses of vehicles and drivers during negotiating and overtaking maneuvers on curves for right hand traffic. The overall objectives of the study were to find road parameters for curves that affect vehicle dynamic responses, to analyze these responses during overtaking maneuvers on curves, and to link the results with driver behavior for different curve directions. The studied road features were speed, super-elevation, radius and friction including their interactions, while the analyzed vehicle dynamic factors were lateral acceleration and yaw angular velocity. A simulation program, PC-Crash, has been used to simulate road parameters and vehicle response interaction in curves. Overtaking maneuvers have been simulated for all road feature combinations in a total of 108 runs. Analysis of variances (ANOVA) was performed, using two sided randomized block design, to find differences in vehicle responses for the curve parameters. To study driver response, a field test using an instrumented vehicle and 32 participants was reviewed as it contained longitudinal speed and acceleration data for analysis. The simulation results showed that road features affect overtaking performance in right and left curves differently. Overtaking on right curves was sensitive to radius and the interaction of radius with road condition; while overtaking on left curves was more sensitive to super-elevation. Comparisons of lateral acceleration and yaw angular velocity during these maneuvers showed different vehicle response configurations depending on curve direction and maneuver path. The field test experiments also showed

  18. Hysteresis and Kinetic Effects During Liquid-Solid Transitions

    SciTech Connect

    Streitz, F H; Chau, R

    2009-02-17

    We address the fundamental issue of phase transition kinetics in dynamically compressed materials. Focusing on solid bismuth (Bi) as a prototype material, we used a variety of time-resolved experiments including electrical conductivity and velocimetry to study the phase transition kinetics of the solid-solid phase transitions. Simple single shock experiments performed on several low-lying high pressure phases of Bi, revealed surprisingly complex behavior and slow dynamics. Strong hysteresis effects were observed in the transition behavior in experiments where the compressed Bi was allowed to release back across a phase line. These experiments represent the first reported simultaneous use of resistivity and velocimetry in a shock compression experiment, and the first observation of hysteresis effects occurring during dynamic compression and release.

  19. Linear Stepper Actuation Driving Drop Resonance and Modifying Hysteresis.

    PubMed

    Katariya, Mayur; Huynh, So Hung; McMorran, Darren; Lau, Chun Yat; Muradoglu, Murat; Ng, Tuck Wah

    2016-08-23

    In this work, 2 μL water drops are placed on substrates that are created to have a circular hydrophilic region bounded by superhydrophobicity so that they exhibit high contact angles. When the substrate is translated by a linear stepper actuator, the random force components present in the actuator are shown to cause the drop to rock resonantly. When the substrate is translated downward at inclination angles of up to 6° with respect to the horizontal, the contact angle hysteresis increases progressively to a limiting condition. When the substrate is moved up at inclined angles, alternatively, the contact angle hysteresis increases initially to the limiting condition before it is progressively restored to its static state. These behaviors are accounted for by the reversible micro-Cassie to Wenzel wetting state transformations that are made possible by the hierarchical microscale and nanoscale structures present in the superhydrophobic regions.

  20. Method of thermal strain hysteresis reduction in metal matrix composites

    NASA Technical Reports Server (NTRS)

    Dries, Gregory A. (Inventor); Tompkins, Stephen S. (Inventor)

    1987-01-01

    A method is disclosed for treating graphite reinforced metal matrix composites so as to eliminate thermal strain hysteresis and impart dimensional stability through a large thermal cycle. The method is applied to the composite post fabrication and is effective on metal matrix materials using graphite fibers manufactured by both the hot roll bonding and diffusion bonding techniques. The method consists of first heat treating the material in a solution anneal oven followed by a water quench and then subjecting the material to a cryogenic treatment in a cryogenic oven. This heat treatment and cryogenic stress reflief is effective in imparting a dimensional stability and reduced thermal strain hysteresis in the material over a -250.degree. F. to +250.degree. F. thermal cycle.

  1. Microscopic Origin of Hysteresis in Water Sorption on Protein Matrices.

    PubMed

    Kim, Sang Beom; Sparano, Evan M; Singh, Rakesh S; Debenedetti, Pablo G

    2017-02-28

    Despite the importance of water sorption isotherms for a fundamental understanding of protein-water interactions, the microscopic origin of hysteresis between the adsorption and desorption branches is not well understood. Using our recently developed simulation technique, we compute the water sorption isotherms of two proteins, lysozyme and Trp-cage, a miniprotein. We explicitly compare protein-water interactions in adsorption and desorption processes, by analyzing local hydration in terms of hydrogen bonding, water density, and solvent-accessible surface area. We find that significant differences in hydration behavior between adsorption and desorption manifest themselves at the individual amino acid level, in particular around polar or charged residues. We confirm this observation by demonstrating that Trp-cage's hysteresis can be significantly reduced by mutating charged residues to alanine, a neutral and nonpolar amino acid.

  2. Charge metastability and hysteresis in the quantum Hall regime

    NASA Astrophysics Data System (ADS)

    Pollanen, J.; Eisenstein, J. P.; Pfeiffer, L. N.; West, K. W.

    2016-12-01

    We report simultaneous quasi-dc magnetotransport and high-frequency surface acoustic wave measurements on bilayer two-dimensional electron systems in GaAs. Near strong integer quantized Hall states, a strong magnetic-field-sweep hysteresis in the velocity of the acoustic waves is observed at low temperatures. This hysteresis indicates the presence of a metastable state with anomalously high conductivity in the interior of the sample. This nonequilibrium state is not revealed by conventional low-frequency transport measurements which are dominated by dissipationless transport at the edge of the two-dimensional system. We find that a field-cooling technique allows the equilibrium charge configuration within the interior of the sample to be established. A simple model for this behavior is discussed.

  3. Hysteresis in modeling of poroelastic systems: quasistatic equilibrium.

    PubMed

    Guyer, R A; Kim, H Alicia; Derome, Dominique; Carmeliet, Jan; TenCate, J

    2011-06-01

    The behavior of hysteretic, coupled elastic and fluid systems is modeled. The emphasis is on quasistatic equilibrium in response to prescribed chemical potential (μ) protocols and prescribed stress (σ) protocols. Hysteresis arises in these models either from the presence of hysterons or from the presence of self-trapping internal fields. This latter mechanism is modeled in finite element calculations which serve to illustrate the creation of hysteresis in a range of circumstances that go from conventionally hysteretic systems, a sandstone, to systems like a wood fiber. An essential ingredient in the behavior of these systems, the interaction between the mechanical variables and the fluid variables, is accorded special attention. The proper venue for the exploration of these systems is (μ,σ) space and appropriate μ protocols, σ protocols, and combined μ-σ protocols.

  4. Effect of Electron Energy Distribution on the Hysteresis of Plasma Discharge: Theory, Experiment, and Modeling

    NASA Astrophysics Data System (ADS)

    Lee, Hyo-Chang; Chung, Chin-Wook

    2015-10-01

    Hysteresis, which is the history dependence of physical systems, is one of the most important topics in physics. Interestingly, bi-stability of plasma with a huge hysteresis loop has been observed in inductive plasma discharges. Despite long plasma research, how this plasma hysteresis occurs remains an unresolved question in plasma physics. Here, we report theory, experiment, and modeling of the hysteresis. It was found experimentally and theoretically that evolution of the electron energy distribution (EED) makes a strong plasma hysteresis. In Ramsauer and non-Ramsauer gas experiments, it was revealed that the plasma hysteresis is observed only at high pressure Ramsauer gas where the EED deviates considerably from a Maxwellian shape. This hysteresis was presented in the plasma balance model where the EED is considered. Because electrons in plasmas are usually not in a thermal equilibrium, this EED-effect can be regarded as a universal phenomenon in plasma physics.

  5. Effect of Electron Energy Distribution on the Hysteresis of Plasma Discharge: Theory, Experiment, and Modeling.

    PubMed

    Lee, Hyo-Chang; Chung, Chin-Wook

    2015-10-20

    Hysteresis, which is the history dependence of physical systems, is one of the most important topics in physics. Interestingly, bi-stability of plasma with a huge hysteresis loop has been observed in inductive plasma discharges. Despite long plasma research, how this plasma hysteresis occurs remains an unresolved question in plasma physics. Here, we report theory, experiment, and modeling of the hysteresis. It was found experimentally and theoretically that evolution of the electron energy distribution (EED) makes a strong plasma hysteresis. In Ramsauer and non-Ramsauer gas experiments, it was revealed that the plasma hysteresis is observed only at high pressure Ramsauer gas where the EED deviates considerably from a Maxwellian shape. This hysteresis was presented in the plasma balance model where the EED is considered. Because electrons in plasmas are usually not in a thermal equilibrium, this EED-effect can be regarded as a universal phenomenon in plasma physics.

  6. Effect of Electron Energy Distribution on the Hysteresis of Plasma Discharge: Theory, Experiment, and Modeling

    PubMed Central

    Lee, Hyo-Chang; Chung, Chin-Wook

    2015-01-01

    Hysteresis, which is the history dependence of physical systems, is one of the most important topics in physics. Interestingly, bi-stability of plasma with a huge hysteresis loop has been observed in inductive plasma discharges. Despite long plasma research, how this plasma hysteresis occurs remains an unresolved question in plasma physics. Here, we report theory, experiment, and modeling of the hysteresis. It was found experimentally and theoretically that evolution of the electron energy distribution (EED) makes a strong plasma hysteresis. In Ramsauer and non-Ramsauer gas experiments, it was revealed that the plasma hysteresis is observed only at high pressure Ramsauer gas where the EED deviates considerably from a Maxwellian shape. This hysteresis was presented in the plasma balance model where the EED is considered. Because electrons in plasmas are usually not in a thermal equilibrium, this EED-effect can be regarded as a universal phenomenon in plasma physics. PMID:26482650

  7. Measurement of contact-angle hysteresis for droplets on nanopillared surface and in the Cassie and Wenzel states: a molecular dynamics simulation study.

    PubMed

    Koishi, Takahiro; Yasuoka, Kenji; Fujikawa, Shigenori; Zeng, Xiao Cheng

    2011-09-27

    We perform large-scale molecular dynamics simulations to measure the contact-angle hysteresis for a nanodroplet of water placed on a nanopillared surface. The water droplet can be in either the Cassie state (droplet being on top of the nanopillared surface) or the Wenzel state (droplet being in contact with the bottom of nanopillar grooves). To measure the contact-angle hysteresis in a quantitative fashion, the molecular dynamics simulation is designed such that the number of water molecules in the droplets can be systematically varied, but the number of base nanopillars that are in direct contact with the droplets is fixed. We find that the contact-angle hysteresis for the droplet in the Cassie state is weaker than that in the Wenzel state. This conclusion is consistent with the experimental observation. We also test a different definition of the contact-angle hysteresis, which can be extended to estimate hysteresis between the Cassie and Wenzel state. The idea is motivated from the appearance of the hysteresis loop typically seen in computer simulation of the first-order phase transition, which stems from the metastability of a system in different thermodynamic states. Since the initial shape of the droplet can be controlled arbitrarily in the computer simulation, the number of base nanopillars that are in contact with the droplet can be controlled as well. We show that the measured contact-angle hysteresis according to the second definition is indeed very sensitive to the initial shape of the droplet. Nevertheless, the contact-angle hystereses measured based on the conventional and new definition seem converging in the large droplet limit.

  8. Degradation and capacitance: voltage hysteresis in CdTe devices

    NASA Astrophysics Data System (ADS)

    Albin, D. S.; Dhere, R. G.; Glynn, S. C.; del Cueto, J. A.; Metzger, W. K.

    2009-08-01

    CdS/CdTe photovoltaic solar cells were made on two different transparent conducting oxide (TCO) structures in order to identify differences in fabrication, performance, and reliability. In one set of cells, chemical vapor deposition (CVD) was used to deposit a bi-layer TCO on Corning 7059 borosilicate glass consisting of a F-doped, conductive tin-oxide (cSnO2) layer capped by an insulating (undoped), buffer (iSnO2) layer. In the other set, a more advanced bi-layer structure consisting of sputtered cadmium stannate (Cd2SnO4; CTO) as the conducting layer and zinc stannate (Zn2SnO4; ZTO) as the buffer layer was used. CTO/ZTO substrates yielded higher performance devices however performance uniformity was worse due to possible strain effects associated with TCO layer fabrication. Cells using the SnO2-based structure were only slightly lower in performance, but exhibited considerably greater performance uniformity. When subjected to accelerated lifetime testing (ALT) at 85 - 100 °C under 1-sun illumination and open-circuit bias, more degradation was observed in CdTe cells deposited on the CTO/ZTO substrates. Considerable C-V hysteresis, defined as the depletion width difference between reverse and forward direction scans, was observed in all Cu-doped CdTe cells. These same effects can also be observed in thin-film modules. Hysteresis was observed to increase with increasing stress and degradation. The mechanism for hysteresis is discussed in terms of both an ionic-drift model and one involving majority carrier emission in the space-charge region (SCR). The increased generation of hysteresis observed in CdTe cells deposited on CTO/ZTO substrates suggests potential decomposition of these latter oxides when subjected to stress testing.

  9. Domain-wall motion in random potential and hysteresis modeling

    SciTech Connect

    Pasquale, M.; Basso, V.; Bertotti, G.; Jiles, D.C.; Bi, Y.

    1998-06-01

    Two different approaches to hysteresis modeling are compared using a common ground based on energy relations, defined in terms of dissipated and stored energy. Using the Preisach model and assuming that magnetization is mainly due to domain-wall motion, one can derive the expression of magnetization along a major loop typical of the Jiles{endash}Atherton model and then extend its validity to cases where mean-field effects and reversible contributions are present. {copyright} {ital 1998 American Institute of Physics.}

  10. Novel thermal hysteresis proteins from low temperature basidiomycete, Coprinus psychromorbidus.

    PubMed

    Hoshino, T; Kiriaki, M; Nakajima, T

    2003-01-01

    The low temperature basidiomycete, Coprinus psychromorbidus, produced three kinds of thermal hysteresis proteins (THPs) in the extracellular space. Molecular mass of purified fungal THPs were approximately 23 kDa, respectively, however those fungal THPs had different N-terminal amino acid sequences. Those fungal THPs formed ice crystals resembling "stone Age arrow head". These observations indicate that fungal THPs did not form hexagonal ice crystals to inhibit its growth.

  11. Energy Barriers and Hysteresis in Martensitic Phase Transformations

    DTIC Science & Technology

    2008-08-01

    I) ∂F2 (Gλ,Gλ) + ω(|λGλ|)|Gλ|2 ] Jλdt1dt2 (93) Since Gλ is bounded uniformly in L2(Ω`) and ω(|λGλ|)→ 0 uniformly, then the error term can be...small hysteresis width. Nature Materials 5 (2006), 286-290. [9] E. De Giorgi and T. Franzoni, Su un tipo di convergenza variazionale. Atti Accad. Naz

  12. Robust homoclinic orbits in planar systems with Preisach hysteresis operator

    NASA Astrophysics Data System (ADS)

    Pimenov, Alexander; Rachinskii, Dmitrii

    2016-06-01

    We construct examples of robust homoclinic orbits for systems of ordinary differential equations coupled with the Preisach hysteresis operator. Existence of such orbits is demonstrated for the first time. We discuss a generic mechanism that creates robust homoclinic orbits and a method for finding them. An example of a homoclinic orbit in a population dynamics model with hysteretic response of the prey to variations of the predator is studied numerically.

  13. Vector magnetic hysteresis modeling of stress annealed galfenol

    NASA Astrophysics Data System (ADS)

    Adly, A. A.; Davino, D.; Giustiniani, A.; Visone, C.

    2013-05-01

    In the past years, utilization of magnetostrictive materials has been increasing in different applications including actuation, sensing, and energy harvesting. Special interest has been recently directed to galfenol (iron-gallium alloy). This paper experimentally investigates the vector hysteresis properties of stress-annealed galfenol as well as to test the capability of recently proposed models to mimic those properties. Details of the measurements, model identification, and experimental testing of the model accuracy are reported in the paper.

  14. Barkhausen discontinuities and hysteresis of ferromagnetics: New stochastic approach

    SciTech Connect

    Vengrinovich, Valeriy

    2014-02-18

    The magnetization of ferromagnetic material is considered as periodically inhomogeneous Markov process. The theory assumes both statistically independent and correlated Barkhausen discontinuities. The model, based on the chain evolution-type process theory, assumes that the domain structure of a ferromagnet passes successively the steps of: linear growing, exponential acceleration and domains annihilation to zero density at magnetic saturation. The solution of stochastic differential Kolmogorov equation enables the hysteresis loop calculus.

  15. A Hydrodynamic Model of Dynamic Contact Angle Hysteresis.

    DTIC Science & Technology

    contact angle hysteresis is developed in terms of the interaction of capillary, viscous, and...used to obtain the equations which describe the contact angle region and thereby to define the dynamic contact angle . The analysis is limited to...velocity dependence of the receding contact angle and of the thickness of the deposited film of the receding interface of a wetting liquid are determined as functions of the capillary, viscous, and disjoining forces.

  16. Understanding contact angle hysteresis on an ambient solid surface.

    PubMed

    Wang, Yong Jian; Guo, Shuo; Chen, Hsuan-Yi; Tong, Penger

    2016-05-01

    We report a systematic study of contact angle hysteresis (CAH) with direct measurement of the capillary force acting on a contact line formed on the surface of a long glass fiber intersecting a liquid-air interface. The glass fiber of diameter 1-2μm and length 100-200μm is glued onto the front end of a rectangular cantilever beam, which is used for atomic force microscopy. From the measured hysteresis loop of the capillary force for 28 different liquids with varying surface tensions and contact angles, we find a universal behavior of the unbalanced capillary force in the advancing and receding directions and the spring constant of a stretched meniscus by the glass fiber. Measurements of the capillary force and its fluctuations suggest that CAH on an ambient solid surface is caused primarily by two types of coexisting and spatially intertwined defects with opposite natures. The contact line is primarily pinned by the relatively nonwetting (repulsive) defects in the advancing direction and by the relatively wetting (attractive) defects in the receding direction. Based on the experimental observations, we propose a "composite model" of CAH and relevant scaling laws, which explain the basic features of the measured hysteresis force loops.

  17. Tuning size and thermal hysteresis in bistable spin crossover nanoparticles.

    PubMed

    Galán-Mascarós, José Ramón; Coronado, Eugenio; Forment-Aliaga, Alicia; Monrabal-Capilla, María; Pinilla-Cienfuegos, Elena; Ceolin, Marcelo

    2010-06-21

    Nanoparticles of iron(II) triazole salts have been prepared from water-organic microemulsions. The mean size of the nanoparticles can be tuned down to 6 nm in diameter, with a narrow size distribution. A sharp spin transition from the low spin (LS) to the high spin (HS) state is observed above room temperature, with a 30-40-K-wide thermal hysteresis. The same preparation can yield second generation nanoparticles containing molecular alloys by mixing triazole with triazole derivatives, or from metallic mixtures of iron(II) and zinc(II). In these nanoparticles of 10-15 nm, the spin transition "moves" towards lower temperatures, reaching a 316 K limit for the cooling down transition and maintaining a thermal hysteresis over 15-20-K-wide. The nanoparticles were characterized by dynamic light scattering, TEM, and AFM, after deposition on gold or silicon surfaces. The spin transition was characterized by magnetic susceptibility measurements and EXAFS (in solid samples after solvent removal) and also by the color change between the LS (violet) and HS (colorless) states in an organic solvent suspension. The discovery of bistable magnetic nanoparticles of 6 nm with a wide thermal hysteresis above room temperature showcases the actual possibilities of spin crossover materials for nanotechnological applications.

  18. Does adsorption in a single nanogroove exhibit hysteresis?

    NASA Astrophysics Data System (ADS)

    Malijevský, Alexandr

    2012-12-01

    A simple fluid, in a microscopic capillary capped at one end, is studied by means of fundamental measure density functional. The model represents a single, infinitely long nanogroove with long-range wall-fluid attractive (dispersion) forces. It is shown that the presence or absence of hysteresis in adsorption isotherms is determined by wetting properties of the wall as follows: Above wetting temperature, Tw, appropriate to a single wall of the groove, the adsorption is a continuous process corresponding to a rise of a meniscus from the capped to the open end of the groove. For a sufficiently deep capillary, the meniscus rise is shown to be a steep, yet continuous process taking place near the capillary condensation of a corresponding slit. However, for temperatures lower than Tw the condensation exhibits a first-order transition accompanied by hysteresis of the adsorption isotherm. Finally, it is shown that hysteresis may occur even for T > Tw as a consequence of prewetting on the side and bottom walls of the groove.

  19. Understanding contact angle hysteresis on an ambient solid surface

    NASA Astrophysics Data System (ADS)

    Wang, Yong Jian; Guo, Shuo; Chen, Hsuan-Yi; Tong, Penger

    2016-05-01

    We report a systematic study of contact angle hysteresis (CAH) with direct measurement of the capillary force acting on a contact line formed on the surface of a long glass fiber intersecting a liquid-air interface. The glass fiber of diameter 1 -2 μ m and length 100 -200 μ m is glued onto the front end of a rectangular cantilever beam, which is used for atomic force microscopy. From the measured hysteresis loop of the capillary force for 28 different liquids with varying surface tensions and contact angles, we find a universal behavior of the unbalanced capillary force in the advancing and receding directions and the spring constant of a stretched meniscus by the glass fiber. Measurements of the capillary force and its fluctuations suggest that CAH on an ambient solid surface is caused primarily by two types of coexisting and spatially intertwined defects with opposite natures. The contact line is primarily pinned by the relatively nonwetting (repulsive) defects in the advancing direction and by the relatively wetting (attractive) defects in the receding direction. Based on the experimental observations, we propose a "composite model" of CAH and relevant scaling laws, which explain the basic features of the measured hysteresis force loops.

  20. The sales learning curve.

    PubMed

    Leslie, Mark; Holloway, Charles A

    2006-01-01

    When a company launches a new product into a new market, the temptation is to immediately ramp up sales force capacity to gain customers as quickly as possible. But hiring a full sales force too early just causes the firm to burn through cash and fail to meet revenue expectations. Before it can sell an innovative product efficiently, the entire organization needs to learn how customers will acquire and use it, a process the authors call the sales learning curve. The concept of a learning curve is well understood in manufacturing. Employees transfer knowledge and experience back and forth between the production line and purchasing, manufacturing, engineering, planning, and operations. The sales learning curve unfolds similarly through the give-and-take between the company--marketing, sales, product support, and product development--and its customers. As customers adopt the product, the firm modifies both the offering and the processes associated with making and selling it. Progress along the manufacturing curve is measured by tracking cost per unit: The more a firm learns about the manufacturing process, the more efficient it becomes, and the lower the unit cost goes. Progress along the sales learning curve is measured in an analogous way: The more a company learns about the sales process, the more efficient it becomes at selling, and the higher the sales yield. As the sales yield increases, the sales learning process unfolds in three distinct phases--initiation, transition, and execution. Each phase requires a different size--and kind--of sales force and represents a different stage in a company's production, marketing, and sales strategies. Adjusting those strategies as the firm progresses along the sales learning curve allows managers to plan resource allocation more accurately, set appropriate expectations, avoid disastrous cash shortfalls, and reduce both the time and money required to turn a profit.

  1. Dynamics of curved interfaces

    SciTech Connect

    Escudero, Carlos

    2009-08-15

    Stochastic growth phenomena on curved interfaces are studied by means of stochastic partial differential equations. These are derived as counterparts of linear planar equations on a curved geometry after a reparametrization invariance principle has been applied. We examine differences and similarities with the classical planar equations. Some characteristic features are the loss of correlation through time and a particular behavior of the average fluctuations. Dependence on the metric is also explored. The diffusive model that propagates correlations ballistically in the planar situation is particularly interesting, as this propagation becomes nonuniversal in the new regime.

  2. Naturally Produced Co/CoO Nanocrystalline Magnetic Multilayers: Structure and Inverted Hysteresis.

    PubMed

    Santarossa, Francesca; Pappas, Spiridon D; Delimitis, Andreas; Sousanis, Andreas; Poulopoulos, Panagiotis

    2016-05-01

    Cobalt-based multilayers with excellent sequencing are grown via radiofrequency magnetron sputtering with the use of one Co target and natural oxidation. The Co layers are continuous, fully textured {111} and have the face centered cubic structure. At the end of deposition of each Co layer air is let to flow into the vacuum chamber via a fine (leak) valve. The top of Co is oxidized. The oxidized layers consist of cubic CoO crystallites. Near the film surface hexagonal Co(OH)2 is also detected. Magneto-optical Kerr effect hysteresis loops show in-plane magnetized films. The magnetic saturation field in the out-of-plane measurements is large exceeding 12 kOe. This observation supports indirectly the fact that Co is face centered cubic; if it was c-axis textured hexagonal the magnetocrystalline anisotropy would be large resulting in smaller values of the saturation field. As the Co-layer thickness decreases the in-plane loops show reduced remanence, slow approach to magnetic saturation and the out-of-plane loops show inverted hysteresis and/or crossing loop features with sizeable remanence. The effects are discussed with respect to the enhanced orbital magnetic moment of Co and the antiferromagnetic coupling between Co spins at the Co/CoO interface.

  3. The design, hysteresis modeling and control of a novel SMA-fishing-line actuator

    NASA Astrophysics Data System (ADS)

    Xiang, Chaoqun; Yang, Hui; Sun, Zhiyong; Xue, Bangcan; Hao, Lina; Asadur Rahoman, M. D.; Davis, Steve

    2017-03-01

    Fishing line can be combined with shape memory alloy (SMA) to form novel artificial muscle actuators which have low cost, are lightweight and soft. They can be applied in bionic, wearable and rehabilitation robots, and can reduce system weight and cost, increase power-to-weight ratio and offer safer physical human-robot interaction. However, these actuators possess several disadvantages, for example fishing line based actuators possess low strength and are complex to drive, and SMA possesses a low percentage contraction and has high hysteresis. This paper presents a novel artificial actuator (known as an SMA-fishing-line) made of fishing line and SMA twisted then coiled together, which can be driven directly by an electrical voltage. Its output force can reach 2.65 N at 7.4 V drive voltage, and the percentage contraction at 4 V driven voltage with a 3 N load is 7.53%. An antagonistic bionic joint driven by the novel SMA-fishing-line actuators is presented, and based on an extended unparallel Prandtl-Ishlinskii (EUPI) model, its hysteresis behavior is established, and the error ratio of the EUPI model is determined to be 6.3%. A Joule heat model of the SMA-fishing-line is also presented, and the maximum error of the established model is 0.510 mm. Based on this accurate hysteresis model, a composite PID controller consisting of PID and an integral inverse (I-I) compensator is proposed and its performance is compared with a traditional PID controller through simulations and experimentation. These results show that the composite PID controller possesses higher control precision than basic PID, and is feasible for implementation in an SMA-fishing-line driven antagonistic bionic joint.

  4. Application of magnetomechanical hysteresis modeling to magnetic techniques for monitoring neutron embrittlement and biaxial stress

    SciTech Connect

    Sablik, M.J.; Kwun, H.; Rollwitz, W.L.; Cadena, D.

    1992-01-01

    The objective is to investigate experimentally and theoretically the effects of neutron embrittlement and biaxial stress on magnetic properties in steels, using various magnetic measurement techniques. Interaction between experiment and modeling should suggest efficient magnetic measurement procedures for determining neutron embrittlement biaxial stress. This should ultimately assist in safety monitoring of nuclear power plants and of gas and oil pipelines. In the first six months of this first year study, magnetic measurements were made on steel surveillance specimens from the Indian Point 2 and D.C. Cook 2 reactors. The specimens previously had been characterized by Charpy tests after specified neutron fluences. Measurements now included: (1) hysteresis loop measurement of coercive force, permeability and remanence, (2) Barkhausen noise amplitude; and (3) higher order nonlinear harmonic analysis of a 1 Hz magnetic excitation. Very good correlation of magnetic parameters with fluence and embrittlement was found for specimens from the Indian Point 2 reactor. The D.C. Cook 2 specimens, however showed poor correlation. Possible contributing factors to this are: (1) metallurgical differences between D.C. Cook 2 and Indian Point 2 specimens; (2) statistical variations in embrittlement parameters for individual samples away from the stated men values; and (3) conversion of the D.C. Cook 2 reactor to a low leakage core configuration in the middle of the period of surveillance. Modeling using a magnetomechanical hysteresis model has begun. The modeling will first focus on why Barkhausen noise and nonlinear harmonic amplitudes appear to be better indicators of embrittlement than the hysteresis loop parameters.

  5. Utilizing dynamic tensiometry to quantify contact angle hysteresis and wetting state transitions on nonwetting surfaces.

    PubMed

    Kleingartner, Justin A; Srinivasan, Siddarth; Mabry, Joseph M; Cohen, Robert E; McKinley, Gareth H

    2013-11-05

    Goniometric techniques traditionally quantify two parameters, the advancing and receding contact angles, that are useful for characterizing the wetting properties of a solid surface; however, dynamic tensiometry, which measures changes in the net force on a surface during the repeated immersion and emersion of a solid into a probe liquid, can provide further insight into the wetting properties of a surface. We detail a framework for analyzing tensiometric results that allows for the determination of wetting hysteresis, wetting state transitions, and characteristic topographical length scales on textured, nonwetting surfaces, in addition to the more traditional measurement of apparent advancing and receding contact angles. Fluorodecyl POSS, a low-surface-energy material, was blended with commercially available poly(methyl methacrylate) (PMMA) and then dip- or spray-coated onto glass substrates. These surfaces were probed with a variety of liquids to illustrate the effects of probe liquid surface tension, solid surface chemistry, and surface texture on the apparent contact angles and wetting hysteresis of nonwetting surfaces. Woven meshes were then used as model structured substrates to add a second, larger length scale for the surface texture. When immersed into a probe liquid, these spray-coated mesh surfaces can form a metastable, solid-liquid-air interface on the largest length scale of surface texture. The increasing hydrostatic pressure associated with progressively greater immersion depths disrupts this metastable, composite interface and forces penetration of the probe liquid into the mesh structure. This transition is marked by a sudden change in the wetting hysteresis, which can be systematically probed using spray-coated, woven meshes of varying wire radius and spacing. We also show that dynamic tensiometry can accurately and quantitatively characterize topographical length scales that are present on microtextured surfaces.

  6. Climate Hysteresis for Planets Orbiting Stars of Different Spectral Type

    NASA Astrophysics Data System (ADS)

    Shields, Aomawa; Meadows, V.; Bitz, C.; Pierrehumbert, R.; Joshi, M.; Robinson, T.; Planetary Laboratory, Virtual

    2013-10-01

    Planetary climate can be affected by the interaction of the host star spectral energy distribution with the wavelength-dependent reflectivity of ice and snow. We have explored this effect with a hierarchy of models. Results from both one-dimensional (1-D) radiative transfer and energy balance models and a three-dimensional (3-D) general circulation model indicate that terrestrial planets orbiting stars with higher near-UV radiation exhibit a stronger ice-albedo feedback. We found that ice extent is much greater on a planet orbiting an F-dwarf star than on a planet orbiting a G- or M-dwarf star at an equivalent flux distance, assuming fixed CO2 (present atmospheric level on Earth). The surface ice-albedo feedback effect becomes less important at the outer edge of the habitable zone for main-sequence stars, where the maintenance of surface liquid water requires high atmospheric CO2 concentrations. We show that ˜3-10 bar of CO2 will entirely mask the climatic effect of ice and snow, leaving the outer limits of the habitable zone unaffected by the spectral dependence of water ice and snow albedo. However, less CO2 is needed to maintain open water for a planet orbiting an M-dwarf star than would be the case for hotter main-sequence stars. Both entrance into and exit out of a snowball state are sensitive to host star spectral energy distribution. Our simulations indicate a smaller climate hysteresis on M-dwarf planets, as measured by the range of instellation that permits multiple stable ice line latitudes. While M-dwarf planets appear less susceptible to snowball episodes than G- or F-dwarf planets over the course of their evolution, any snowball planets that are found orbiting M-dwarf stars may more easily melt out of these states as stellar luminosity increases over time. This effect is due to the lower-albedo ice on M-dwarf planets which, compounded with near-IR absorption by atmospheric gases, reduces the amount of increased stellar insolation, or

  7. A suite of user-friendly global climate models: Hysteresis experiments

    NASA Astrophysics Data System (ADS)

    Fraedrich, K.

    2012-05-01

    A hierarchy of global spectral circulation models is introduced ranging from the shallow-water system via the primitive-equation dynamical core of the atmosphere to the Planet Simulator as a Global Climate Model (GCM) of Intermediate Complexity (MIC) which can be used to run climate and paleo-climate simulations for time scales up to ten thousand years or more in an acceptable real time. The priorities in development are set to speed, easy handling and portability with a modular structure suitable for problem-dependent configuration. Adaptions exist for the planetary atmospheres of Mars and of Saturn's moon Titan and are being extended. Common coupling interfaces enable the addition of ocean, ice, vegetation models and more. An interactive mode with a Model Starter and a Graphical User Interface (GUI) is available to select a configuration from the available model suite, to set its parameters and inspect atmospheric fields while changing the models' parameters on the fly. This is especially useful for teaching, debugging and tuning of parameterizations. An updated overview of the model suite's features is presented based on the Earth-like climate model Planet Simulator with mixed-layer ocean introducing static and memory hysteresis in terms of a parameter sweep of the solar constant and CO2 concentrations. The static hysteresis experiment demonstrates that the solar constant varying by 20% reveals warm and snowball Earth climate regimes depending on the history of the system. This hysteresis subjected to a thermodynamic analysis shows the following features: i) Both climate regimes are characterized by global mean surface temperature and entropy growing with increasing solar constant. ii) The climate system's efficiency decreases (increases) with increasing solar constant in present-day warm (snowball) climate conditions. iii) Climate transitions near bifurcation points are characterized by high efficiency associated with the system's large distance from the stable

  8. Analysis of Magnetic Minor Hysteresis Loops in Thermally Aged and Cold-rolled Fe-Cu Alloys

    NASA Astrophysics Data System (ADS)

    Takahashi, F.; Kobayashi, S.; Murakami, T.; Takahashi, S.; Kamada, Y.; Kikuchi, H.

    2011-01-01

    Neutron irradiation causes the formation of Cu precipitate in reactor pressure vessel steel and makes the steel susceptible to rupture. In the present study, we have examined magnetic minor hysteresis loops of Fe-1wt%Cu alloy after thermally ageing at 753 K and subsequent cold rolling to elucidate the effects of Cu precipitation on magnetic properties. Minor-loop coefficients, obtained from scaling power laws between field-dependent parameters of minor hysteresis loops, decrease with ageing time and show a local maximum around 200 min, reflecting the growth of Cu precipitates with ageing. For the alloy cold-rolled after ageing, the minor-loop properties linearly increase with reduction and show a good relationship with mechanical properties such as DBTT and hardness. These observations indicate that the analysis method using magnetic minor loops can be an useful technique of nondestructive evaluation of irradiation embrittlement and subsequent deformation hardening in reactor pressure vessel steels.

  9. Graphing Polar Curves

    ERIC Educational Resources Information Center

    Lawes, Jonathan F.

    2013-01-01

    Graphing polar curves typically involves a combination of three traditional techniques, all of which can be time-consuming and tedious. However, an alternative method--graphing the polar function on a rectangular plane--simplifies graphing, increases student understanding of the polar coordinate system, and reinforces graphing techniques learned…

  10. Textbook Factor Demand Curves.

    ERIC Educational Resources Information Center

    Davis, Joe C.

    1994-01-01

    Maintains that teachers and textbook graphics follow the same basic pattern in illustrating changes in demand curves when product prices increase. Asserts that the use of computer graphics will enable teachers to be more precise in their graphic presentation of price elasticity. (CFR)

  11. Curve Fit Challenge

    ERIC Educational Resources Information Center

    Harper, Suzanne R.; Driskell, Shannon

    2005-01-01

    Graphic tips for using the Geometer's Sketchpad (GSP) are described. The methods to import an image into GSP, define a coordinate system, plot points and curve fit the function using a graphical calculator are demonstrated where the graphic features of GSP allow teachers to expand the use of the technology application beyond the classroom.

  12. The Bacterial Growth Curve.

    ERIC Educational Resources Information Center

    Paulton, Richard J. L.

    1991-01-01

    A procedure that allows students to view an entire bacterial growth curve during a two- to three-hour student laboratory period is described. Observations of the lag phase, logarithmic phase, maximum stationary phase, and phase of decline are possible. A nonpathogenic, marine bacterium is used in the investigation. (KR)

  13. Contact Angle Hysteresis on Graphene Surfaces and Hysteresis-free Behavior on Oil-infused Graphite Surfaces

    NASA Astrophysics Data System (ADS)

    Wu, Cyuan-Jhang; Li, Yueh-Feng; Woon, Wei-Yen; Sheng, Yu-Jane; Tsao, Heng-Kwong

    2016-11-01

    Contact angle hysteresis (CAH) on graphitic surfaces, including chemical vapor deposition (CVD) graphene, reduced electrophoretic deposition (EPD) graphene, highly oriented pyrolytic graphite (HOPG), and polished graphite sheet, has been investigated. The hysteresis loops of water drops on the first three samples are similar but the receding contact angle is particularly small for the polished graphite sheet.The significant CAH observed on CVD graphene and HOPG associated with atom-scale roughness has to be attributed mainly to adhesion hysteresis (surface relaxation), instead of roughness or defects.The difference of the wetting behavior among those four graphitic samples has been further demonstrated by hexadecane drops. On the surface of HOPG or CVD graphene,the contact line expands continuously with time, indicating total wetting for which the contact angle does not exist and contact line pinning disappears. In contrast, on the surface of reduced EPD graphene, spontaneous spreading is halted by spikes on it and partial wetting with small contact angle (θ≈4°) is obtained. On the surface of polished graphite sheet, the superlipophilicity and porous structure are demonstrated by imbibition and capillary rise of hexadecane. Consequently, an oil-infused graphite surface can be fabricated and the ultralow CAH of water (∆θ≈2°) is achieved.

  14. Remote sensing used for power curves

    NASA Astrophysics Data System (ADS)

    Wagner, R.; Jørgensen, H. E.; Paulsen, U. S.; Larsen, T. J.; Antoniou, I.; Thesbjerg, L.

    2008-05-01

    : Power curve measurement for large wind turbines requires taking into account more parameters than only the wind speed at hub height. Based on results from aerodynamic simulations, an equivalent wind speed taking the wind shear into account was defined and found to reduce the power standard deviation in the power curve significantly. Two LiDARs and a SoDAR are used to measure the wind profile in front of a wind turbine. These profiles are used to calculate the equivalent wind speed. The comparison of the power curves obtained with the three instruments to the traditional power curve, obtained using a cup anemometer measurement, confirms the results obtained from the simulations. Using LiDAR profiles reduces the error in power curve measurement, when these are used as relative instrument together with a cup anemometer. Results from the SoDAR do not show such promising results, probably because of noisy measurements resulting in distorted profiles.

  15. Crystal structure and polarization hysteresis properties of ferroelectric BaTiO3 thin-film capacitors on (Ba,Sr)TiO3-buffered substrates

    NASA Astrophysics Data System (ADS)

    Maki, Hisashi; Noguchi, Yuji; Kutsuna, Kazutoshi; Matsuo, Hiroki; Kitanaka, Yuuki; Miyayama, Masaru

    2016-10-01

    Ferroelectric BaTiO3 (BT) thin-film capacitors with a buffer layer of (Ba1- x Sr x )TiO3 (BST) have been fabricated on (001) SrTiO3 (STO) single-crystal substrates by a pulsed laser deposition method, and the crystal structure and polarization hysteresis properties have been investigated. X-ray diffraction reciprocal space mapping shows that the BST buffer effectively reduces the misfit strain relaxation of the BT films on SrRuO3 (SRO) electrodes. The BT capacitor with the SRO electrodes on the BST (x = 0.3) buffer exhibits a well-saturated hysteresis loop with a remanent polarization of 29 µC/cm2. The hysteresis loop displays a shift toward a specific field direction, which is suggested to stem from the flexoelectric coupling between the out-of-plane polarization and the strain gradient adjacent to the bottom interface.

  16. Trishear for curved faults

    NASA Astrophysics Data System (ADS)

    Brandenburg, J. P.

    2013-08-01

    Fault-propagation folds form an important trapping element in both onshore and offshore fold-thrust belts, and as such benefit from reliable interpretation. Building an accurate geologic interpretation of such structures requires palinspastic restorations, which are made more challenging by the interplay between folding and faulting. Trishear (Erslev, 1991; Allmendinger, 1998) is a useful tool to unravel this relationship kinematically, but is limited by a restriction to planar fault geometries, or at least planar fault segments. Here, new methods are presented for trishear along continuously curved reverse faults defining a flat-ramp transition. In these methods, rotation of the hanging wall above a curved fault is coupled to translation along a horizontal detachment. Including hanging wall rotation allows for investigation of structures with progressive backlimb rotation. Application of the new algorithms are shown for two fault-propagation fold structures: the Turner Valley Anticline in Southwestern Alberta, and the Alpha Structure in the Niger Delta.

  17. Atlas of fatigue curves

    SciTech Connect

    Boyer, H.E.

    1986-01-01

    This Atlas was developed to serve engineers who are looking for fatigue data on a particular metal or alloy. Having these curves compiled in a single book will also facilitate the computerization of the involved data. It is pointed out that plans are under way to make the data in this book available in ASCII files for analysis by computer programs. S-N curves which typify effects of major variables are considered along with low-carbon steels, medium-carbon steels, alloy steels, HSLA steels, high-strength alloy steels, heat-resisting steels, stainless steels, maraging steels, cast irons, and heat-resisting alloys. Attention is also given to aluminum alloys, copper alloys, magnesium alloys, molybdenum, tin alloys, titanium and titanium alloys, zirconium, steel castings, closed-die forgings, powder metallurgy parts, composites, effects of surface treatments, and test results for component parts.

  18. Mouse Curve Biometrics

    SciTech Connect

    Schulz, Douglas A.

    2007-10-08

    A biometric system suitable for validating user identity using only mouse movements and no specialized equipment is presented. Mouse curves (mouse movements with little or no pause between them) are individually classied and used to develop classication histograms, which are representative of an individual's typical mouse use. These classication histograms can then be compared to validate identity. This classication approach is suitable for providing continuous identity validation during an entire user session.

  19. NOISE AND HYSTERESIS IN CHARGED STRIPE, CHECKERBOARD, AND CLUMP FORMING SYSTEMS

    SciTech Connect

    Reichhardt, Charles; Reichhardt, Cynthia J.; Bishop, Alan R.

    2007-05-07

    We numerically examine noise fluctuations and hysteresis phenomena in charged systems that form stripe, labyrinth or clump patterns. It is believed that charge inhomogeneities of this type arise in two-dimensional (2D) quantum hall systems and in electron crystal structures in high temperature superconductors, while related patterns appear in manganites and type-I superconductors. Recent noise and transport experiments in twodimensional electron gases and high temperature superconducting samples revealed both 1/ fα. noise signatures and hysteretic phenomena. Using numerical simulations we show that 1/ fα. noise fluctuations and hysteresis are generic features that occur in charge systems which undergo a type of phase separation that results in stripes, clumps, checkerboards, or other inhomogeneous patterns. We find that these systems exhibit 1/ fα. fluctuations with 1.2 < α < 1.8, rather than simple 1/ f or 1/ f 2 fluctuations. We also propose that the 2D metal insulator transition may be associated with a clump electron glass phase rather than a Wigner glass phase.

  20. Ferroelectric-like hysteresis loop originated from non-ferroelectric effects

    SciTech Connect

    Kim, Bora; Seol, Daehee; Lee, Shinbuhm; Lee, Ho Nyung; Kim, Yunseok

    2016-09-06

    Piezoresponse force microscopy (PFM) has provided advanced nanoscale understanding and analysis of ferroelectric and piezoelectric properties. In PFM-based studies, electromechanical strain induced by the converse piezoelectric effect is probed and analyzed as a PFM response. However, electromechanical strain can also arise from several non-piezoelectric origins that may lead to a misinterpretation of the observed response. Among them, electrostatic interaction can significantly affect the PFM response. Nonetheless, previous studies explored solely the influence of electrostatic interaction on the PFM response under the situation accompanied with polarization switching. Here, we show the influence of the electrostatic interaction in the absence of polarization switching by using unipolar voltage sweep. The obtained results reveal that the electromechanical neutralization between piezoresponse of polarization and electrostatic interaction plays a crucial role in the observed ferroelectric-like hysteresis loop despite the absence of polarization switching. Furthermore, our work can provide a basic guideline for the correct interpretation of the hysteresis loop in PFM-based studies.

  1. Ferroelectric-like hysteresis loop originated from non-ferroelectric effects

    DOE PAGES

    Kim, Bora; Seol, Daehee; Lee, Shinbuhm; ...

    2016-09-06

    Piezoresponse force microscopy (PFM) has provided advanced nanoscale understanding and analysis of ferroelectric and piezoelectric properties. In PFM-based studies, electromechanical strain induced by the converse piezoelectric effect is probed and analyzed as a PFM response. However, electromechanical strain can also arise from several non-piezoelectric origins that may lead to a misinterpretation of the observed response. Among them, electrostatic interaction can significantly affect the PFM response. Nonetheless, previous studies explored solely the influence of electrostatic interaction on the PFM response under the situation accompanied with polarization switching. Here, we show the influence of the electrostatic interaction in the absence of polarizationmore » switching by using unipolar voltage sweep. The obtained results reveal that the electromechanical neutralization between piezoresponse of polarization and electrostatic interaction plays a crucial role in the observed ferroelectric-like hysteresis loop despite the absence of polarization switching. Furthermore, our work can provide a basic guideline for the correct interpretation of the hysteresis loop in PFM-based studies.« less

  2. Efficient and Hysteresis-Free Field Effect Modulation of Ambipolarly Doped Vanadium Dioxide Nanowires

    NASA Astrophysics Data System (ADS)

    Peng, Xingyue; Yang, Yiming; Hou, Yasen; Travaglini, Henry C.; Hellwig, Luke; Hihath, Sahar; van Benthem, Klaus; Lee, Kathleen; Liu, Weifeng; Yu, Dong

    2016-05-01

    The subpicosecond metal-insulator phase transition in vanadium dioxide (VO2 ) has attracted extensive attention with potential applications in ultrafast Mott transistors, which are based on electric-field-induced phase transition. However, the development of VO2 -based transistors lags behind, owing to inefficient and hysteretic gate modulation. Here we report ambipolar doping and strong field effects free of hysteresis in single-crystal VO2 nanowires synthesized via catalyst-free chemical vapor deposition. The ambipolarly doped VO2 nanowires are achieved by controlling the oxygen vacancy density during the synthesis and show strong gate effects because of their relatively low doping level. Both the doping type of the nanowires and the band-bending direction at the metal-insulator domain walls are reversibly switched by electrochemical gating, as revealed by scanning photocurrent microscopy. Furthermore, we eliminate the hysteresis in gate sweep via a hybrid gating method, which combines the merits of liquid-ionic and solid gating. The capability of efficient field effect modulation of ambipolar conduction and band alignment offers opportunities on understanding the phase transition mechanism and enables electronic applications based on VO2 .

  3. Inverted hysteresis loops in magnetically coupled bilayers with uniaxial competing anisotropies: Theory and experiments

    NASA Astrophysics Data System (ADS)

    Valvidares, S. M.; Álvarez-Prado, L. M.; Martín, J. I.; Alameda, J. M.

    2001-10-01

    The magnetization reversal processes in magnetic bilayers with individual uniaxial anisotropies have been studied, both theoretically and experimentally, to analyze the possible existence of inverted hysteresis loops, that is, with negative remanent magnetization (Mr). Kerr effect measurements in amorphous YCo2/YCo2 bilayers and alternating gradient magnetometry in polycrystalline FeNi/FeNi samples reveal that Mr<0 can be observed for certain directions of the applied magnetic field in the sample plane. This property has also been found in CoNbZr films annealed under an applied field. Our theoretical approach shows that the behavior of these magnetic heterogeneous systems with two coupled uniaxial anisotropies can be understood in terms of two competing effective anisotropies, one biaxial (with Kbiax) and one uniaxial (with Kuniax). In particular, a phase diagram has been deduced for the conditions on Kbiax and Kuniax that can produce negative remanence. This description indicates that, under those anisotropy conditions, inverted hysteresis loops can be observed for an applied field close to the hard axis of the effective uniaxial anisotropy, when magnetization reversal is driven by rotations and not by domain nucleation and wall movement. To consider the real situation in a YCo2/YCo2 bilayer sample, the predictions of this phenomenological model have been further improved by micromagnetic calculations, which are in very good agreement with the magneto-optical measurements.

  4. Memory-efficient architecture for hysteresis thresholding and object feature extraction.

    PubMed

    Najjar, Mayssaa A; Karlapudi, Swetha; Bayoumi, Magdy A

    2011-12-01

    Hysteresis thresholding is a method that offers enhanced object detection. Due to its recursive nature, it is time consuming and requires a lot of memory resources. This makes it avoided in streaming processors with limited memory. We propose two versions of a memory-efficient and fast architecture for hysteresis thresholding: a high-accuracy pixel-based architecture and a faster block-based one at the expense of some loss in the accuracy. Both designs couple thresholding with connected component analysis and feature extraction in a single pass over the image. Unlike queue-based techniques, the proposed scheme treats candidate pixels almost as foreground until objects complete; a decision is then made to keep or discard these pixels. This allows processing on the fly, thus avoiding additional passes for handling candidate pixels and extracting object features. Moreover, labels are reused so only one row of compact labels is buffered. Both architectures are implemented in MATLAB and VHDL. Simulation results on a set of real and synthetic images show that the execution speed can attain an average increase up to 24× for the pixel-based and 52× for the block-based when compared to state-of-the-art techniques. The memory requirements are also drastically reduced by about 99%.

  5. A hysteresis model for dynamic behaviour of magnetorheological elastomer base isolator

    NASA Astrophysics Data System (ADS)

    Yu, Yang; Li, Yancheng; Li, Jianchun; Gu, Xiaoyu

    2016-05-01

    In recent years, an adaptively tuned magnetorheological elastomer (MRE) isolator for a base isolation system has been designed and tested with the benefits of low power cost, fail safe manner and fast responses. To make full use of this striking device for design of smart structures, a highly precise model should be developed to effectively and accurately forecast the shear force of the device in real-time so as to adopt a proper control strategy to improve the responses of the protected structures. In this work, a novel mechanical model is presented to characterize this nonlinear hysteresis for its implementation in structural vibration control. This model employs the displacement and velocity of the device as well as the applied current as the inputs and just has the limited constant parameters to be identified compared with some classical hysteretic models such as Bouc-Wen, improved Dahl and LuGre models. Performance evaluation of this novel hysteresis model has been conducted based on the testing data from an MRE base isolator. The results show that the proposed model has high modelling accuracy and is able to perfectly portray the unique and complicated behaviours of the device with various excitations.

  6. Organo-Mineral Interaction on the Adsorption Hysteresis, Transport and Vulnerability of Soil Organic Carbon

    NASA Astrophysics Data System (ADS)

    Gu, B.; Wullschleger, S. D.; Liang, L.

    2011-12-01

    Interactions between natural soil organic matter and mineral surfaces are of primary importance in determining the partitioning, transport, and preservation or storage of soil organic matter (SOM) in the natural environment. SOM is a complex mixture of a variety of polyfunctional organic moieties with a range of chemical and structural properties, such as pKa values, functional groups, aromaticities, and molecular sizes. These organic compounds exhibit varying affinities and capacities during interactions with mineral surfaces, resulting in sorption-desorption hysteresis, fractionation and competitive reactions, and degrative transformation during transport over time and depth. In this study, fractionation reactions, sorption mechanisms, and competitive reactions were investigated using advanced spectroscopic techniques and microcosm flow experiments. We show that strongly-binding organic moieties of SOM can competitively interact with minerals such as iron oxide and displace those weakly-bound organics during the reaction. These reactions lead to the adsorption and desorption hysteresis of SOM on minerals and kinetically limited exchange among different organic moieties during the transport of SOM under a controlled column flow system. Those strong-binding organic moieties of SOM are generally characterized by high molecular weight and poly-condensed, conjugated aromatics, which are sorbed onto iron oxide minerals primarily through surface complexation or ligand exchange processes. These observations highlight the importance of soil organo-mineral interactions on transformation, mobilization and decomposition of SOM and their controls on soil carbon balance, cycling, and vulnerability to climate change.

  7. Resisting and pinning of a nanodrop by trenches on a hysteresis-free surface

    NASA Astrophysics Data System (ADS)

    Chang, Cheng-Chung; Wu, Cyuan-Jhang; Sheng, Yu-Jane; Tsao, Heng-Kwong

    2016-10-01

    The encounter of a nanodrop with a trench on a hysteresis-free surface is explored by many-body dissipative particle dynamics to show the effect of surface roughness on droplet wetting. A free nanodrop exhibits Brownian motion and the diffusivity decays exponentially with the liquid-solid contact area. In contrast, as the nanodrop sits on a trench, its random motion is constrained. Work must be done to overcome the energy barriers for the transition between free and trapped states. The potential energy landscape is thus constructed based on the force-displacement plot. It is shown that the trench acts as a hydrophobic blemish for capture but like a hydrophilic blemish for escape. A drop always breaks up after detachment from a hydrophilic trench. Therefore, the drop tends to bypass a small trench when it meets one. The macroscopic experiments are performed by fabricating liquid-infused surfaces with extremely low contact angle hysteresis. The experimental observations agree qualitatively with simulation outcomes.

  8. Double hysteresis loops and large negative and positive electrocaloric effects in tetragonal ferroelectrics.

    PubMed

    Wu, Hong-Hui; Zhu, Jiaming; Zhang, Tong-Yi

    2015-10-07

    Phase field modelling and thermodynamic analysis are employed to investigate depolarization and compression induced large negative and positive electrocaloric effects (ECEs) in ferroelectric tetragonal crystalline nanoparticles. The results show that double-hysteresis loops of polarization versus electric field dominate at temperatures below the Curie temperature of the ferroelectric material, when the mechanical compression exceeds a critical value. In addition to the mechanism of pseudo-first-order phase transition (PFOPT), the double-hysteresis loops are also caused by the abrupt rise of macroscopic polarization from the abc phase to the c phase or the sudden fall of macroscopic polarization from the c phase to the abc phase when the temperature increases. This phenomenon is called the electric-field-induced-pseudo-phase transition (EFIPPT) in the present study. Similar to the two types of PFOPTs, the two types of EFIPPTs cause large negative and positive ECEs, respectively, and give the maximum absolute values of negative and positive adiabatic temperature change (ATC ΔT). The temperature associated with the maximum absolute value of negative ATC ΔT is lower than that associated with the maximum positive ATC ΔT. Both maximum absolute values of ATC ΔTs change with the variation in the magnitude of an applied electric field and depend greatly on the compression intensity.

  9. Critical energy barrier for capillary condensation in mesopores: Hysteresis and reversibility

    NASA Astrophysics Data System (ADS)

    Hiratsuka, Tatsumasa; Tanaka, Hideki; Miyahara, Minoru T.

    2016-04-01

    Capillary condensation in the regime of developing hysteresis occurs at a vapor pressure, Pcond, that is less than that of the vapor-like spinodal. This is because the energy barrier for the vapor-liquid transition from a metastable state at Pcond becomes equal to the energy fluctuation of the system; however, a detailed mechanism of the spontaneous transition has not been acquired even through extensive experimental and simulation studies. We therefore construct accurate atomistic silica mesopore models for MCM-41 and perform molecular simulations (gauge cell Monte Carlo and grand canonical Monte Carlo) for argon adsorption on the models at subcritical temperatures. A careful comparison between the simulation and experiment reveals that the energy barrier for the capillary condensation has a critical dimensionless value, Wc* = 0.175, which corresponds to the thermal fluctuation of the system and depends neither on the mesopore size nor on the temperature. We show that the critical energy barrier Wc* controls the capillary condensation pressure Pcond and also determines a boundary between the reversible condensation/evaporation regime and the developing hysteresis regime.

  10. Critical energy barrier for capillary condensation in mesopores: Hysteresis and reversibility.

    PubMed

    Hiratsuka, Tatsumasa; Tanaka, Hideki; Miyahara, Minoru T

    2016-04-28

    Capillary condensation in the regime of developing hysteresis occurs at a vapor pressure, Pcond, that is less than that of the vapor-like spinodal. This is because the energy barrier for the vapor-liquid transition from a metastable state at Pcond becomes equal to the energy fluctuation of the system; however, a detailed mechanism of the spontaneous transition has not been acquired even through extensive experimental and simulation studies. We therefore construct accurate atomistic silica mesopore models for MCM-41 and perform molecular simulations (gauge cell Monte Carlo and grand canonical Monte Carlo) for argon adsorption on the models at subcritical temperatures. A careful comparison between the simulation and experiment reveals that the energy barrier for the capillary condensation has a critical dimensionless value, Wc (*) = 0.175, which corresponds to the thermal fluctuation of the system and depends neither on the mesopore size nor on the temperature. We show that the critical energy barrier Wc (*) controls the capillary condensation pressure Pcond and also determines a boundary between the reversible condensation/evaporation regime and the developing hysteresis regime.

  11. Abnormal Current–Voltage Hysteresis Induced by Reverse Bias in Organic–Inorganic Hybrid Perovskite Photovoltaics

    SciTech Connect

    Rajagopal, Adharsh; Williams, Spencer T.; Chueh, Chu-Chen; Jen, Alex K. -Y.

    2016-02-29

    In this study, reverse bias (RB)-induced abnormal hysteresis is investigated in perovskite solar cells (PVSCs) with nickel oxide (NiOx)/methylammonium lead iodide (CH3NH3PbI3) interfaces. Through comprehensive current-voltage (I-V) characterization and bias-dependent external quantum efficiency (EQE) measurements, we demonstrate that this phenomenon is caused by the interfacial ion accumulation intrinsic to CH3NH3PbI3. Subsequently, via systematic analysis we discover that the abnormal I-V behavior is remarkably similar to tunnel diode I-V characteristics and is due to the formation of a transient tunnel junction at NiOx/CH3NH3PbI3 interfaces under RB. The detailed analysis navigating the complexities of I-V behavior in CH3NH3PbI3-based solar cells provided here ultimately illuminates possibilities in modulating ion motion and hysteresis via interfacial engineering in PVSCs. Moreover, this work shows that RB can alter how CH3NH3PbI3 contributes to the functional nature of devices and provides the first steps toward approaching functional perovskite interfaces in new ways for metrology and analysis of complex transient processes.

  12. Abnormal Current–Voltage Hysteresis Induced by Reverse Bias in Organic–Inorganic Hybrid Perovskite Photovoltaics

    DOE PAGES

    Rajagopal, Adharsh; Williams, Spencer T.; Chueh, Chu-Chen; ...

    2016-02-29

    In this study, reverse bias (RB)-induced abnormal hysteresis is investigated in perovskite solar cells (PVSCs) with nickel oxide (NiOx)/methylammonium lead iodide (CH3NH3PbI3) interfaces. Through comprehensive current-voltage (I-V) characterization and bias-dependent external quantum efficiency (EQE) measurements, we demonstrate that this phenomenon is caused by the interfacial ion accumulation intrinsic to CH3NH3PbI3. Subsequently, via systematic analysis we discover that the abnormal I-V behavior is remarkably similar to tunnel diode I-V characteristics and is due to the formation of a transient tunnel junction at NiOx/CH3NH3PbI3 interfaces under RB. The detailed analysis navigating the complexities of I-V behavior in CH3NH3PbI3-based solar cells provided heremore » ultimately illuminates possibilities in modulating ion motion and hysteresis via interfacial engineering in PVSCs. Moreover, this work shows that RB can alter how CH3NH3PbI3 contributes to the functional nature of devices and provides the first steps toward approaching functional perovskite interfaces in new ways for metrology and analysis of complex transient processes.« less

  13. Asymmetric and speed-dependent contact angle hysteresis and relaxation of a suddenly stopped moving contact line

    NASA Astrophysics Data System (ADS)

    Guan, Dongshi; Wang, Yong Jian; Charlaix, Elisabeth; Tong, Penger

    We report direct atomic-force-microscope measurements of capillary force hysteresis and relaxation of a circular moving contact line (CL) formed on a long micron-sized hydrophobic fiber intersecting a water-air interface. The measured capillary force hysteresis and CL relaxation show a strong asymmetric speed dependence in the advancing and receding directions. A unified model based on force-assisted barrier-crossing is utilized to find the underlying energy barrier Eb and size λ associated with the defects on the fiber surface. The experiment demonstrates that the pinning (relaxation) and depinning dynamics of the CL can be described by a common microscopic frame-work, and the advancing and receding CLs are influenced by two different sets of relatively wetting and non-wetting defects on the fiber surface. Work supported in part by the Research Grants Council of Hong Kong SAR.

  14. Light-induced hysteresis and recovery behaviors in photochemically activated solution-processed metal-oxide thin-film transistors

    SciTech Connect

    Jo, Jeong-Wan; Park, Sung Kyu E-mail: skpark@cau.ac.kr; Kim, Yong-Hoon E-mail: skpark@cau.ac.kr

    2014-07-28

    In this report, photo-induced hysteresis, threshold voltage (V{sub T}) shift, and recovery behaviors in photochemically activated solution-processed indium-gallium-zinc oxide (IGZO) thin-film transistors (TFTs) are investigated. It was observed that a white light illumination caused negative V{sub T} shift along with creation of clockwise hysteresis in electrical characteristics which can be attributed to photo-generated doubly ionized oxygen vacancies at the semiconductor/gate dielectric interface. More importantly, the photochemically activated IGZO TFTs showed much reduced overall V{sub T} shift compared to thermally annealed TFTs. Reduced number of donor-like interface states creation under light illumination and more facile neutralization of ionized oxygen vacancies by electron capture under positive gate potential are claimed to be the origin of the less V{sub T} shift in photochemically activated TFTs.

  15. Dipole spring ferroelectrics in superlattice SrTiO3/BaTiO3 thin films exhibiting constricted hysteresis loops

    SciTech Connect

    Wu, Pingping; Ma, Xingqiao; Li, Yulan; Gopalan, Venkatraman; Chen , L.Q.

    2012-03-01

    Ferroelectric superlattice heterostructures have recently been explored for potential applications in electronic devices. In this letter we employed the phase-field approach to simulate the domain structure and switching of a (BaTiO3)8/(SrTiO3)3 superlattice film constrained by a GdScO3 substrate. A constricted ferroelectric hysteresis loop was observed with a high saturation polarization but a small coercive field. The shape of the hysteresis loop is understood by analyzing the ferroelectric polarization distributions during switching. It is demonstrated that the constricted loop show a similar mechanism to the exchange coupling effect in magnetic multilayers.

  16. Quantization on Curves

    NASA Astrophysics Data System (ADS)

    Frønsdal, Christian; Kontsevich, Maxim

    2007-02-01

    Deformation quantization on varieties with singularities offers perspectives that are not found on manifolds. The Harrison component of Hochschild cohomology, vanishing on smooth manifolds, reflects information about singularities. The Harrison 2-cochains are symmetric and are interpreted in terms of abelian *-products. This paper begins a study of abelian quantization on plane curves over mathbb{C}, being algebraic varieties of the form {mathbb{C}}^2/R, where R is a polynomial in two variables; that is, abelian deformations of the coordinate algebra mathbb{C}[x,y]/(R). To understand the connection between the singularities of a variety and cohomology we determine the algebraic Hochschild (co)homology and its Barr Gerstenhaber Schack decomposition. Homology is the same for all plane curves mathbb{C}[x,y]/R, but the cohomology depends on the local algebra of the singularity of R at the origin. The Appendix, by Maxim Kontsevich, explains in modern mathematical language a way to calculate Hochschild and Harrison cohomology groups for algebras of functions on singular planar curves etc. based on Koszul resolutions.

  17. Analysis of the Hysteresis Behavior of Perovskite Solar Cells with Interfacial Fullerene Self-Assembled Monolayers.

    PubMed

    Valles-Pelarda, Marta; Hames, Bruno Clasen; García-Benito, Inés; Almora, Osbel; Molina-Ontoria, Agustin; Sánchez, Rafael S; Garcia-Belmonte, Germà; Martín, Nazario; Mora-Sero, Ivan

    2016-11-17

    The use of self-assembled monolayers (SAMs) of fullerene derivatives reduces the hysteresis of perovskite solar cells (PSCs). We have investigated three different fullerene derivatives observing a decrease on hysteresis for all the cases. Several processes can contribute to the hysteresis behavior on PSCs. We have determined that the reduced hysteresis observed for devices with SAMs is produced by a decrease of the capacitive hysteresis. In addition, with an appropriated functionalization, SAMs can increase photocurrent even when no electron selective contact (ESC) is present and a SAM is deposited just on top of the transparent conductive oxide. Appropriated functionalization of the fullerene derivative, as introducing -CN groups, can enhance cell performance and reduce hysteresis. This work paves the way for a future enhancement of PSCs by a tailored design of the fullerene molecules that could actuate as an ESC by themselves.

  18. Tuning the hysteresis voltage in 2D multilayer MoS2 FETs

    NASA Astrophysics Data System (ADS)

    Jiang, Jie; Zheng, Zhouming; Guo, Junjie

    2016-10-01

    The hysteresis tuning is of great significance before the two-dimensional (2D) molybdenum disulfide (MoS2) field-effect transistors (FETs) can be practically used in the next-generation nanoelectronic devices. In this paper, a simple and effective annealing method was developed to tune the hysteresis voltage in 2D MoS2 transistors. It was found that high temperature (175 °C) annealing in air could increase the hysteresis voltage from 8.0 V (original device) to 28.4 V, while a next vacuum annealing would reduce the hysteresis voltage to be only 2.0 V. An energyband diagram model based on electron trapping/detrapping due to oxygen adsorption is proposed to understand the hysteresis mechanism in multilayer MoS2 FET. This simple method for tuning the hysteresis voltage of MoS2 FET can make a significant step toward 2D nanoelectronic device applications.

  19. Hysteresis and charge trapping in graphene quantum dots

    NASA Astrophysics Data System (ADS)

    Kalita, Hemen; V, Harikrishnan; Shinde, Dhanraj B.; Pillai, Vijayamohanan K.; Aslam, M.

    2013-04-01

    We report current hysteresis in response to applied voltage in graphene quantum dots of average diameter 4.5 ± 0.55 nm, synthesized electrochemically using multiwalled carbon nanotubes. In response to step voltages, transient current decay, characteristic of deep and shallow level charge traps with time constants 186 ms and 6 s, is observed. Discharging current transients indicate charge storage of the order of 100 μC. Trap states are believed to arise due to the fast physisorption of external adsorbates, which are found to have a significant effect on charge transport and changes the resistance of the prepared device by an order of 3.

  20. Effect of contact angle hysteresis on moving liquid film integrity.

    NASA Technical Reports Server (NTRS)

    Simon, F. F.; Hsu, Y. Y.

    1972-01-01

    A study was made of the formation and breakdown of a water film moving over solid surfaces (teflon, lucite, stainless steel, and copper). The flow rate associated with film formation was found to be higher than the flow rate at which film breakdown occurred. The difference in the flow rates for film formation and film breakdown was attributed to contact angle hysteresis. Analysis and experiment, which are in good agreement, indicated that film formation and film breakdown are functions of the advancing and receding angles, respectively.

  1. Effect of contact angle hysteresis on moving liquid film integrity

    NASA Technical Reports Server (NTRS)

    Simon, F. F.; Hsu, Y. Y.

    1972-01-01

    A study was made of the formation and breakdown of a water film moving over solid surfaces (teflon, lucite, stainless steel, and copper). The flow rate associated with film formation was found to be higher than the flow rate at which film breakdown occurred. The difference in the flow rates for film formation and film breakdown was attributed to contact angle hysteresis. Analysis and experiment, which are in good agreement, indicated that film formation and film breakdown are functions of the advancing and receding angles, respectively.

  2. Internal hysteresis experienced on a high pressure syn gas compressor

    NASA Technical Reports Server (NTRS)

    Zeidan, F. Y.

    1984-01-01

    A vibration instability phenomenon experienced in operating high pressure syn gas centrifugal compressors in two ammonia plants is described. The compressors were monitored by orbit and spectrum analysis for changes from baseline readings. It is found that internal hysteresis was the major destabilizing force; however, the problem was further complicated by seal lockup at the suction end of the compressor. A coupling lockup problem and a coupling fit problem, which frettage of the shaft, are also considered as contributors to the self excited vibrations.

  3. Role of measurement voltage on hysteresis loop shape in Piezoresponse Force Microscopy

    SciTech Connect

    Kim, Yunseok; Yang, J.-C.; Chu, Ying Hao; Yu, Pu; Lu, X.; Jesse, Stephen; Kalinin, Sergei V

    2012-01-01

    The dependence of on-field and off-field hysteresis loop shape in Piezoresponse Force Microscopy (PFM) on driving voltage, Vac, is explored. A nontrivial dependence of hysteresis loop parameters on measurement conditions is observed. The strategies to distinguish between paraelectric and ferroelectric states with small coercive bias and separate reversible hysteretic and non-hysteretic behaviors are suggested. Generally, measurement of loop evolution with Vac is a necessary step to establish the veracity of PFM hysteresis measurements.

  4. Hysteresis zone or locus - Aerodynamic of bulbous based bodies at low speeds

    NASA Technical Reports Server (NTRS)

    Covert, E. E.

    1979-01-01

    Experimental data are presented which seem to suggest that a well-defined hysteresis locus on bulbous based bodies at low speeds does not exist. Instead, if the experiment is repeated several times, the entire hysteresis region seems to fill with data rather than trace out a specific hysteresis locus. Data obtained on an oscillating model even at low reduced frequencies may be well defined but when applied to arbitrary motion lead to less accurate results than desired.

  5. Role of measurement voltage on hysteresis loop shape in Piezoresponse Force Microscopy

    NASA Astrophysics Data System (ADS)

    Strelcov, E.; Kim, Y.; Yang, J. C.; Chu, Y. H.; Yu, P.; Lu, X.; Jesse, S.; Kalinin, S. V.

    2012-11-01

    The dependence of field-on and field-off hysteresis loop shape in Piezoresponse Force Microscopy (PFM) on driving voltage, Vac, is explored. A nontrivial dependence of hysteresis loop parameters on measurement conditions is observed. The strategies to distinguish between paraelectric and ferroelectric states with small coercive bias and separate reversible hysteretic and non-hysteretic behaviors are suggested. Generally, measurement of loop evolution with Vac is a necessary step to establish the veracity of PFM hysteresis measurements.

  6. Curved microchannels and bacterial streamers

    NASA Astrophysics Data System (ADS)

    Rusconi, Roberto; Lecuyer, Sigolene; Guglielmini, Laura; Stone, Howard

    2010-03-01

    Bacterial biofilms are commonly identified as microbial communities attached to a surface and encased in a self-secreted extracellular matrix. Due to their increased resistance to antimicrobial agents, biofilms have an enormous impact on health and medicine (e.g., wound healing, implant-associated infections, disease transmission). On the other hand, they constitute a major component of the stream ecosystem by increasing transport of nutrients and retention of suspended particles. In this talk, we present an experimental study of bacterial biofilm development in a microfluidic device. In particular, we show the formation of filamentous structures, or streamers, in curved channels and how these suspended biofilms are linked to the underlying hydrodynamics.

  7. Fabrication of surfaces with extremely high contact angle hysteresis from polyelectrolyte multilayer.

    PubMed

    Wang, Liming; Wei, Jingjing; Su, Zhaohui

    2011-12-20

    High contact angle hysteresis on polyelectrolyte multilayers (PEMs) ion-paired with hydrophobic perfluorooctanoate anions is reported. Both the bilayer number of PEMs and the ionic strength of deposition solutions have significant influence on contact angle hysteresis: higher ionic strength and greater bilayer number cause increased contact angle hysteresis values. The hysteresis values of ~100° were observed on smooth PEMs and pinning of the receding contact line on hydrophilic defects is implicated as the cause of hysteresis. Surface roughness can be used to further tune the contact angle hysteresis on the PEMs. A surface with extremely high contact angle hysteresis of 156° was fabricated when a PEM was deposited on a rough substrate coated with submicrometer scale silica spheres. It was demonstrated that this extremely high value of contact angle hysteresis resulted from the penetration of water into the rough asperities on the substrate. The same substrate hydrophobized by chemical vapor deposition of 1H,1H,2H,2H-perfluorooctyltriethoxysilane exhibits high advancing contact angle and low hysteresis.

  8. Effect of Electron Energy Distribution on the Hysteresis of Plasma Discharge: Theory, Experiment, and Modeling

    NASA Astrophysics Data System (ADS)

    Lee, Hyo-Chang; Chung, Chin-Wook

    2016-09-01

    Hysteresis, which is the history dependence of physical systems, indicates that there are more-than-two stable points in a given condition, and it has been considered to one of the most important topics in fundamental physics. Recently, the hysteresis of plasma has become a focus of research because stable plasma operation is very important for fusion reactors, bio-medical plasmas, and industrial plasmas for nano-device fabrication process. Interestingly, the bi-stability characteristics of plasma with a huge hysteresis loop have been observed in inductive discharge plasmas Because hysteresis study in such plasmas can provide a universal understanding of plasma physics, many researchers have attempted experimental and theoretical studies. Despite long plasma research, how this plasma hysteresis occurs remains an unresolved question in plasma physics. Here, we report theory, experiment, and modeling of the hysteresis. It was found experimentally and theoretically that evolution of the electron energy distribution (EED) makes a strong plasma hysteresis. In Ramsauer and non-Ramsauer gas experiments, it was revealed that the plasma hysteresis is observed only at high pressure Ramsauer gas where the EED deviates considerably from a Maxwellian shape. This hysteresis was presented in the plasma balance model where the EED is considered. Because electrons in plasmas are usually not in a thermal equilibrium, this EED-effect can be regarded as a universal phenomenon in plasma physics. This research was partially supported by Korea Research Institute of Standard and Science.

  9. Equivalent circuit representation of hysteresis in solar cells that considers interface charge accumulation: Potential cause of hysteresis in perovskite solar cells

    NASA Astrophysics Data System (ADS)

    Seki, Kazuhiko

    2016-07-01

    If charge carriers accumulate in the charge transport layer of a solar cell, then the transient response of the electric field that originates from these accumulated charges results in hysteresis in the current-voltage (J-V) characteristics. While this mechanism was previously known, a theoretical model to explain these J-V characteristics has not been considered to date. We derived an equivalent circuit from the proposed hysteresis mechanism. By solving the equivalent circuit model, we were able to reproduce some of the features of hysteresis in perovskite solar cells.

  10. Rotation Curves of Galaxies

    NASA Astrophysics Data System (ADS)

    Kalnajs, Agris J.

    One can obtain a fairly good understanding of the relation between axially symmetric mass distributions and the rotation curves they produce without resorting to calculations. However it does require a break with tradition. The first step consists of replacing quantities such as surface density, volume density, and circular velocity with the mass in a ring, mass in a spherical shell, and the square of the circular velocity, or more precisely with 2 pi G r mu(r), 4 pi G r^2 rho(r), and Vc^2 (r). These three quantities all have the same dimensions, and are related to each other by scale-free linear operators. The second step consists of introducing ln(r) as the coordinate. On the log scale the scale-free operators becomes the more familiar convolution operations. Convolutions are easily handled by Fourier techniques and a surface density can be converted into a rotation curve or volume density in a small fraction of a second. A simple plot of 2 pi G r mu(r) as a function of ln(r) reveals the relative contributions of different radii to Vc^2(r). Such a plot also constitutes a sanity test for the fitting of various laws to photometric data. There are numerous examples in the literature of excellent fits to the tails that lack data or are poor fits around the maximum of 2 pi G r mu(r). I will discuss some exact relations between the above three quantities as well as some empirical observations such as the near equality of the maxima of 2 pi G r mu(r) and Vc^2 (r) curves for flat mass distributions.

  11. Curved PVDF airborne transducer.

    PubMed

    Wang, H; Toda, M

    1999-01-01

    In the application of airborne ultrasonic ranging measurement, a partially cylindrical (curved) PVDF transducer can effectively couple ultrasound into the air and generate strong sound pressure. Because of its geometrical features, the ultrasound beam angles of a curved PVDF transducer can be unsymmetrical (i.e., broad horizontally and narrow vertically). This feature is desired in some applications. In this work, a curved PVDF air transducer is investigated both theoretically and experimentally. Two resonances were observed in this transducer. They are length extensional mode and flexural bending mode. Surface vibration profiles of these two modes were measured by a laser vibrometer. It was found from the experiment that the surface vibration was not uniform along the curvature direction for both vibration modes. Theoretical calculations based on a model developed in this work confirmed the experimental results. Two displacement peaks were found in the piezoelectric active direction of PVDF film for the length extensional mode; three peaks were found for the flexural bending mode. The observed peak positions were in good agreement with the calculation results. Transient surface displacement measurements revealed that vibration peaks were in phase for the length extensional mode and out of phase for the flexural bending mode. Therefore, the length extensional mode can generate a stronger ultrasound wave than the flexural bending mode. The resonance frequencies and vibration amplitudes of the two modes strongly depend on the structure parameters as well as the material properties. For the transducer design, the theoretical model developed in this work can be used to optimize the ultrasound performance.

  12. Magnetism in curved geometries

    NASA Astrophysics Data System (ADS)

    Streubel, Robert; Fischer, Peter; Kronast, Florian; Kravchuk, Volodymyr P.; Sheka, Denis D.; Gaididei, Yuri; Schmidt, Oliver G.; Makarov, Denys

    2016-09-01

    Extending planar two-dimensional structures into the three-dimensional space has become a general trend in multiple disciplines, including electronics, photonics, plasmonics and magnetics. This approach provides means to modify conventional or to launch novel functionalities by tailoring the geometry of an object, e.g. its local curvature. In a generic electronic system, curvature results in the appearance of scalar and vector geometric potentials inducing anisotropic and chiral effects. In the specific case of magnetism, even in the simplest case of a curved anisotropic Heisenberg magnet, the curvilinear geometry manifests two exchange-driven interactions, namely effective anisotropy and antisymmetric exchange, i.e. Dzyaloshinskii-Moriya-like interaction. As a consequence, a family of novel curvature-driven effects emerges, which includes magnetochiral effects and topologically induced magnetization patterning, resulting in theoretically predicted unlimited domain wall velocities, chirality symmetry breaking and Cherenkov-like effects for magnons. The broad range of altered physical properties makes these curved architectures appealing in view of fundamental research on e.g. skyrmionic systems, magnonic crystals or exotic spin configurations. In addition to these rich physics, the application potential of three-dimensionally shaped objects is currently being explored as magnetic field sensorics for magnetofluidic applications, spin-wave filters, advanced magneto-encephalography devices for diagnosis of epilepsy or for energy-efficient racetrack memory devices. These recent developments ranging from theoretical predictions over fabrication of three-dimensionally curved magnetic thin films, hollow cylinders or wires, to their characterization using integral means as well as the development of advanced tomography approaches are in the focus of this review.

  13. Magnetism in curved geometries

    SciTech Connect

    Streubel, Robert; Fischer, Peter; Kronast, Florian; Kravchuk, Volodymyr P.; Sheka, Denis D.; Gaididei, Yuri; Schmidt, Oliver G.; Makarov, Denys

    2016-08-17

    Extending planar two-dimensional structures into the three-dimensional space has become a general trend in multiple disciplines, including electronics, photonics, plasmonics and magnetics. This approach provides means to modify conventional or to launch novel functionalities by tailoring the geometry of an object, e.g. its local curvature. In a generic electronic system, curvature results in the appearance of scalar and vector geometric potentials inducing anisotropic and chiral effects. In the specific case of magnetism, even in the simplest case of a curved anisotropic Heisenberg magnet, the curvilinear geometry manifests two exchange-driven interactions, namely effective anisotropy and antisymmetric exchange, i.e. Dzyaloshinskii–Moriya-like interaction. As a consequence, a family of novel curvature-driven effects emerges, which includes magnetochiral effects and topologically induced magnetization patterning, resulting in theoretically predicted unlimited domain wall velocities, chirality symmetry breaking and Cherenkov-like effects for magnons. The broad range of altered physical properties makes these curved architectures appealing in view of fundamental research on e.g. skyrmionic systems, magnonic crystals or exotic spin configurations. In addition to these rich physics, the application potential of three-dimensionally shaped objects is currently being explored as magnetic field sensorics for magnetofluidic applications, spin-wave filters, advanced magneto-encephalography devices for diagnosis of epilepsy or for energy-efficient racetrack memory devices. Finally, these recent developments ranging from theoretical predictions over fabrication of three-dimensionally curved magnetic thin films, hollow cylinders or wires, to their characterization using integral means as well as the development of advanced tomography approaches are in the focus of this review.

  14. Magnetism in curved geometries

    DOE PAGES

    Streubel, Robert; Fischer, Peter; Kronast, Florian; ...

    2016-08-17

    Extending planar two-dimensional structures into the three-dimensional space has become a general trend in multiple disciplines, including electronics, photonics, plasmonics and magnetics. This approach provides means to modify conventional or to launch novel functionalities by tailoring the geometry of an object, e.g. its local curvature. In a generic electronic system, curvature results in the appearance of scalar and vector geometric potentials inducing anisotropic and chiral effects. In the specific case of magnetism, even in the simplest case of a curved anisotropic Heisenberg magnet, the curvilinear geometry manifests two exchange-driven interactions, namely effective anisotropy and antisymmetric exchange, i.e. Dzyaloshinskii–Moriya-like interaction. Asmore » a consequence, a family of novel curvature-driven effects emerges, which includes magnetochiral effects and topologically induced magnetization patterning, resulting in theoretically predicted unlimited domain wall velocities, chirality symmetry breaking and Cherenkov-like effects for magnons. The broad range of altered physical properties makes these curved architectures appealing in view of fundamental research on e.g. skyrmionic systems, magnonic crystals or exotic spin configurations. In addition to these rich physics, the application potential of three-dimensionally shaped objects is currently being explored as magnetic field sensorics for magnetofluidic applications, spin-wave filters, advanced magneto-encephalography devices for diagnosis of epilepsy or for energy-efficient racetrack memory devices. Finally, these recent developments ranging from theoretical predictions over fabrication of three-dimensionally curved magnetic thin films, hollow cylinders or wires, to their characterization using integral means as well as the development of advanced tomography approaches are in the focus of this review.« less

  15. Effect of stress and plastic deformation on hysteresis and anhysteretic magnetization of Fe-Ni alloys

    NASA Astrophysics Data System (ADS)

    Finkel, Peter; Lofland, Sam

    2004-03-01

    We report on the low-field magnetic properties of thin FeNi alloys films and ribbons under tensile stress. The magnetization was measured using a conventional vibrating sample magnetometer using a special designed fixture allowing applying forces as large as 250 N providing sizable uniaxial stresses on thin film and wires. Anhysteretic permeability was extracted from the anhysteretic B-H curves constructed by degaussing the sample at given longitudinal (parallel to the stresses) dc field. We discuss results of the measurements of steel and invar samples of FeNi samples leads to higher susceptibility and lower coercivity for low tensile stress. The magnetostriction contribution to dc magnetization under elastic stress and the effect of the plastic strain on the hysteresis loops were characterized. Larger stresses result in plastic strain of the sample which induces an increase in dislocation density and subsequently domain wall pinning. This causes an increase in coercivity and decrease in anhysteretic permeability at the highest stresses. We also discuss the effect of composition and processing on these results.

  16. A two-dimensional adsorption kinetic model for thermal hysteresis activity in antifreeze proteins

    NASA Astrophysics Data System (ADS)

    Li, Q. Z.; Yeh, Y.; Liu, J. J.; Feeney, R. E.; Krishnan, V. V.

    2006-05-01

    Antifreeze proteins (AFPs) and antifreeze glycoproteins (AFGPs), collectively abbreviated as AF(G)Ps, are synthesized by various organisms to enable their cells to survive in subzero environments. Although the AF(G)Ps are markedly diverse in structure, they all function by adsorbing to the surface of embryonic ice crystals to inhibit their growth. This adsorption results in a freezing temperature depression without an appreciable change in the melting temperature. The difference between the melting and freezing temperatures, termed thermal hysteresis (TH), is used to detect and quantify the antifreeze activity. Insights from crystallographic structures of a number of AFPs have led to a good understanding of the ice-protein interaction features. Computational studies have focused either on verifying a specific model of AFP-ice interaction or on understanding the protein-induced changes in the ice crystal morphology. In order to explain the origin of TH, we propose a novel two-dimensional adsorption kinetic model between AFPs and ice crystal surfaces. The validity of the model has been demonstrated by reproducing the TH curve on two different β-helical AFPs upon increasing the protein concentration. In particular, this model is able to accommodate the change in the TH behavior observed experimentally when the size of the AFPs is increased systematically. Our results suggest that in addition to the specificity of the AFPs for the ice, the coverage of the AFPs on the ice surface is an equally necessary condition for their TH activity.

  17. Study of spin crossover nanoparticles thermal hysteresis using FORC diagrams on an Ising-like model

    NASA Astrophysics Data System (ADS)

    Atitoaie, Alexandru; Tanasa, Radu; Stancu, Alexandru; Enachescu, Cristian

    2014-11-01

    Recent developments in the synthesis and characterization of spin crossover (SCO) nanoparticles and their prospects of switching at molecular level turned these bistable compounds into possible candidates for replacing the materials used in recording media industry for development of solid state pressure and temperature sensors or for bringing contributions in engineering. Compared to bulk samples with the same chemical structure, SCO nanoparticles display different characteristics of the hysteretic and relaxation properties like the shift of the transition temperature towards lower values along with decrease of the hysteresis width with nanoparticles size. Using an Ising-like model with specific boundary conditions within a Monte Carlo procedure, we here reproduce most of the hysteretic properties of SCO nanoparticles by considering the interaction between spin crossover edge molecules and embedding surfactant molecules and we propose a complex analysis concerning the effect of the interactions and sizes during the thermal transition in systems of SCO nanoparticles by using the First Order Reversal Curves diagram method and by comparison with similar effects in mixed crystal systems.

  18. Resonant frequency and hysteresis of a stack actuator made of single crystal (PMN-29PT) layers

    NASA Astrophysics Data System (ADS)

    Tran, K. S.; Lee, H. Y.; Kim, Y.; Park, H. C.

    2016-12-01

    In this study, we have presented the dynamic behavior of a piezoelectric stack actuator made of forty layers of single-crystal (PMN-29PT) with an area of 10 × 10 mm2 and thickness of 1 mm. To conduct a dynamic test of the actuator, we built a test apparatus with dummy weights that was placed over the top of the actuator to measure the actuation displacement. The resonant frequencies of the actuator with and without the dummy weight were determined as the excitation frequencies where a significant increase in the actuation displacement could be observed. We also proposed an analytical multi-degree-of-freedom (MDOF) model of the actuator to analytically predict the resonant frequency. Finite element analyses were conducted to validate the analytically predicted and measured resonant frequencies. With no dummy weight, the resonant frequency of the actuator was measured at 730.00 Hz, which was 0.70% higher than the one calculated by the MDOF model and 0.10% smaller than that of the finite element model. With a dummy weight, the measured resonant frequency was lower than 730.00 Hz and close enough to those computed by the MDOF model and the finite element model. The hysteresis curves of the actuator at various frequencies indicated that the actuator might incur a small energy loss.

  19. Complementary Curves of Descent

    DTIC Science & Technology

    2012-11-16

    provision of law , no person shall be subject to a penalty for failing to comply with a collection of information if it does not display a currently valid...curves of descent 5a. CONTRACT NUMBER 5b. GRANT NUMBER 5c. PROGRAM ELEMENT NUMBER 6. AUTHOR( S ) 5d. PROJECT NUMBER 5e. TASK NUMBER 5f. WORK UNIT...NUMBER 7. PERFORMING ORGANIZATION NAME( S ) AND ADDRESS(ES) US Naval Academy,Physics Department,Annapolis,MD,21402-1363 8. PERFORMING ORGANIZATION

  20. Curved cap corrugated sheet

    NASA Technical Reports Server (NTRS)

    Davis, R. C.; Bales, T. T.; Royster, D. M.; Jackson, L. R. (Inventor)

    1984-01-01

    The report describes a structure for a strong, lightweight corrugated sheet. The sheet is planar or curved and includes a plurality of corrugation segments, each segment being comprised of a generally U-shaped corrugation with a part-cylindrical crown and cap strip, and straight side walls and with secondary corrugations oriented at right angles to said side walls. The cap strip is bonded to the crown and the longitudinal edge of said cap strip extends beyond edge at the intersection between said crown and said side walls. The high strength relative to weight of the structure makes it desirable for use in aircraft or spacecraft.

  1. Substrate engineering by hexagonal boron nitride/SiO2 for hysteresis-free graphene FETs and large-scale graphene p-n junctions.

    PubMed

    Xu, Hua; Wu, Juanxia; Chen, Yabin; Zhang, Haoli; Zhang, Jin

    2013-10-01

    We have explored an approach for the fabrication of intrinsic and hysteresis-free graphene field-effect transistors (FETs) and for the construction of graphene p-n junctions based on substrate engineering by hexagonal boron nitride (h-BN)/SiO2. The effect of various interfaces on the performance of the graphene FETs was systematically studied by constructing four types of graphene devices (graphene/SiO2 FETs, graphene/h-BN FETs, h-BN/graphene/SiO2 FETs, and h-BN/graphene/h-BN FETs). Graphene/SiO2 FETs and h-BN/graphene/SiO2 FETs always exhibit large hysteresis before and after annealing, whereas graphene/h-BN FETs and h-BN/graphene/h-BN FETs show intrinsic properties after annealing. Raman measurements also indicate that graphene on a SiO2 substrate contains large amounts of p-doping, whereas that on a h-BN substrate is intrinsic. Thus, the graphene/h-BN interface gives intrinsic and hysteresis-free graphene FETs, whilst the graphene/SiO2 interface affords p-doping and a hysteresis effect in the graphene FETs. This result is because h-BN serves as an insulation layer, which prevents charge trapping between the graphene and the charge traps at the graphene/SiO2 interface, which cause the hysteresis. In addition, the negligible electrostatic doping of h-BN into graphene also ensures the intrinsic and hysteresis-free properties of graphene/BN/SiO2 FETs. Moreover, benefitting from the p-doped and intrinsic features of graphene on SiO2 and h-BN substrates, respectively, large-scale graphene p-n junction superlattices with great potential difference are constructed and integrated into photodetector arrays by substrate engineering with h-BN/SiO2. Efficient hot carrier-assisted photocurrent was generated by laser excitation at the junction under ambient conditions.

  2. Contact-angle hysteresis on super-hydrophobic surfaces.

    PubMed

    McHale, G; Shirtcliffe, N J; Newton, M I

    2004-11-09

    The relationship between perturbations to contact angles on a rough or textured surface and the super-hydrophobic enhancement of the equilibrium contact angle is discussed theoretically. Two models are considered. In the first (Wenzel) case, the super-hydrophobic surface has a very high contact angle and the droplet completely contacts the surface upon which it rests. In the second (Cassie-Baxter) case, the super-hydrophobic surface has a very high contact angle, but the droplet bridges across surface protrusions. The theoretical treatment emphasizes the concept of contact-angle amplification or attenuation and distinguishes between the increases in contact angles due to roughening or texturing surfaces and perturbations to the resulting contact angles. The theory is applied to predicting contact-angle hysteresis on rough surfaces from the hysteresis observable on smooth surfaces and is therefore relevant to predicting roll-off angles for droplets on tilted surfaces. The theory quantitatively predicts a "sticky" surface for Wenzel-type surfaces and a "slippy" surface for Cassie-Baxter-type surfaces.

  3. Contact angle hysteresis and pinning at periodic defects in statics.

    PubMed

    Iliev, Stanimir; Pesheva, Nina; Nikolayev, Vadim S

    2014-07-01

    This article deals with the theoretical prediction of the wetting hysteresis on nonideal solid surfaces in terms of the surface heterogeneity parameters. The spatially periodical chemical heterogeneity is considered. We propose precise definitions for both the advancing and the receding contact angles for the Wilhelmy plate geometry. It is well known that in such a system, a multitude of metastable states of the liquid meniscus occurs for each different relative position of the defect pattern on the plate with respect to the liquid level. As usual, the static advancing and receding angles are assumed to be a consequence of the preceding contact line motion in the respective direction. It is shown how to select the appropriate states among all metastable states. Their selection is discussed. The proposed definitions are applicable to both the static and the dynamic contact angles on heterogeneous surfaces. The static advancing and receding angles are calculated for two examples of periodic heterogeneity patterns with sharp borders: the horizontal alternating stripes of a different wettability (studied analytically) and the doubly periodic pattern of circular defects on a homogeneous base (studied numerically). The wetting hysteresis is determined as a function of the defect density and the spatial period. A comparison with the existing results is carried out.

  4. Ionic Origin of Electro-osmotic Flow Hysteresis

    NASA Astrophysics Data System (ADS)

    Lim, Chun Yee; Lim, An Eng; Lam, Yee Cheong

    2016-02-01

    Electro-osmotic flow, the driving of fluid at nano- or micro- scales with electric field, has found numerous applications, ranging from pumping to chemical and biomedical analyses in micro-devices. Electro-osmotic flow exhibits a puzzling hysteretic behavior when two fluids with different concentrations displace one another. The flow rate is faster when a higher concentration solution displaces a lower concentration one as compared to the flow in the reverse direction. Although electro-osmotic flow is a surface phenomenon, rather counter intuitively we demonstrate that electro-osmotic flow hysteresis originates from the accumulation or depletion of pH-governing minority ions in the bulk of the fluid, due to the imbalance of electric-field-induced ion flux. The pH and flow velocity are changed, depending on the flow direction. The understanding of electro-osmotic flow hysteresis is critical for accurate fluid flow control in microfluidic devices, and maintaining of constant pH in chemical and biological systems under an electric field.

  5. Hysteresis in myo-inositol utilization by Salmonella Typhimurium.

    PubMed

    Hellinckx, Jessica; Fuchs, Thilo M

    2016-12-27

    Growth of Salmonella enterica serovar Typhimurium strain 14028 with myo-inositol (MI) as the sole carbon and energy source is characterized by a bistable phenotype that manifests in a growth phenotype with an extraordinarily long and length-variable lag phase. However, in the presence of hydrogen carbonate, in the absence of IolR that represses the MI degradation pathway, or if cells are already adapted to minimal medium (MM) with MI, the lag phase is drastically shortened, and the bistable phenotype is abolished. We hypothesized that memory development or hysteresis is a further characteristic of MI degradation by S. Typhimurium; therefore, we investigated the transition from a short to a long lag phase in more detail. Growth experiments demonstrated that memory on the population level is successively lost within approximately 8 hr after cells, which had been adapted to MI utilization, were transferred to lysogeny broth (LB) medium. Flow cytometry (FC) analysis using a chromosomal fusion to PiolE , a promoter controlling the expression of the enzymatic genes iolE and iolG involved in MI degradation, indicated a gradual reversion within a few hours from a population in the "ON" status with respect to iolE transcription to one that is mainly in the "OFF" status. Growth and FC experiments revealed that IolR does not affect hysteresis.

  6. Wavenumber selection and hysteresis in nonlinear baroclinic flow

    NASA Technical Reports Server (NTRS)

    Chou, Shih-Hung

    1995-01-01

    Wavenumber transition and hysteresis in a highly unstable baroclinic flow are investigated using a high-resolution spectral numerical model. As the flow becomes more supercritical, the dominant wave gradually shifts from the most unstable wave predicted by the linear theory to a longer wave with a larger time-averaged amplitude, while the rectified mean flow attains a stronger shear at the center of the channel. The numerical results display a complex hysteresis behavior, which occurs not only between the states of different dominant wavenumbers, but also between the states of identical dominant wavenumber but of different dynamic characteristics. In a certain parameter range three stable states, each with different dominant wavenumber, are possible, and in another parameter range four stable states are possible, among them three stable states with an identical dominant wave. The numerical results suggest that a multiple weather regime exists even without external forcing in which the flow aperiodically varies between two distinct behaviors. The effects of stable higher harmonics are assessed and it is found that their presence contributes not only to the better approximation of the model solutions but also to the selection of the final equilibrium state, due to the chaotic nature of the initial transient period.

  7. Computational micromagnetic study of particulate media hysteresis and recording

    NASA Astrophysics Data System (ADS)

    Seberino, Christian

    2000-11-01

    A description of the micromagnetic theory, algorithms, computer software and computer hardware built and used to study particulate media particles, hysteresis and recording is first provided. This includes a derivation and analysis of the modified version of the Fast Multipole Method used in this dissertation. Results will then be presented on particulate media particle nucleation field dependence on particle shape, particle aspect ratio, ferromagnetic exchange energy and external magnetic field angle. Results on the discretization necessary to accurately model a particle will also be provided. The reversal mode of a particle will be simulated and analyzed. Simulated longitudinal and transverse hysteresis loops will be presented. Results will also be presented on particulate media coercivity and squareness dependence on volumetric packing fraction. Simulated recorded transition results will be given as well as total power spectra results for AC and DC erased particulate media. Numerical results will be compared to experimental data and analytical theories. Advice is provided on how to build a personal supercomputer like the one used in the numerical experiments of this dissertation.

  8. Ionic Origin of Electro-osmotic Flow Hysteresis

    PubMed Central

    Lim, Chun Yee; Lim, An Eng; Lam, Yee Cheong

    2016-01-01

    Electro-osmotic flow, the driving of fluid at nano- or micro- scales with electric field, has found numerous applications, ranging from pumping to chemical and biomedical analyses in micro-devices. Electro-osmotic flow exhibits a puzzling hysteretic behavior when two fluids with different concentrations displace one another. The flow rate is faster when a higher concentration solution displaces a lower concentration one as compared to the flow in the reverse direction. Although electro-osmotic flow is a surface phenomenon, rather counter intuitively we demonstrate that electro-osmotic flow hysteresis originates from the accumulation or depletion of pH-governing minority ions in the bulk of the fluid, due to the imbalance of electric-field-induced ion flux. The pH and flow velocity are changed, depending on the flow direction. The understanding of electro-osmotic flow hysteresis is critical for accurate fluid flow control in microfluidic devices, and maintaining of constant pH in chemical and biological systems under an electric field. PMID:26923197

  9. Modeling of hysteresis loops by Monte Carlo simulation

    NASA Astrophysics Data System (ADS)

    Nehme, Z.; Labaye, Y.; Sayed Hassan, R.; Yaacoub, N.; Greneche, J. M.

    2015-12-01

    Recent advances in MC simulations of magnetic properties are rather devoted to non-interacting systems or ultrafast phenomena, while the modeling of quasi-static hysteresis loops of an assembly of spins with strong internal exchange interactions remains limited to specific cases. In the case of any assembly of magnetic moments, we propose MC simulations on the basis of a three dimensional classical Heisenberg model applied to an isolated magnetic slab involving first nearest neighbors exchange interactions and uniaxial anisotropy. Three different algorithms were successively implemented in order to simulate hysteresis loops: the classical free algorithm, the cone algorithm and a mixed one consisting of adding some global rotations. We focus particularly our study on the impact of varying the anisotropic constant parameter on the coercive field for different temperatures and algorithms. A study of the angular acceptation move distribution allows the dynamics of our simulations to be characterized. The results reveal that the coercive field is linearly related to the anisotropy providing that the algorithm and the numeric conditions are carefully chosen. In a general tendency, it is found that the efficiency of the simulation can be greatly enhanced by using the mixed algorithm that mimic the physics of collective behavior. Consequently, this study lead as to better quantified coercive fields measurements resulting from physical phenomena of complex magnetic (nano)architectures with different anisotropy contributions.

  10. Hysteresis in magnetic shape memory composites: Modeling and simulation

    NASA Astrophysics Data System (ADS)

    Conti, Sergio; Lenz, Martin; Rumpf, Martin

    2016-04-01

    Magnetic shape memory alloys are characterized by the coupling between the reorientation of structural variants and the rearrangement of magnetic domains. This permits to control the shape change via an external magnetic field, at least in single crystals. Composite materials with single-crystalline particles embedded in a softer matrix have been proposed as a way to overcome the blocking of the reorientation at grain boundaries. We investigate hysteresis phenomena for small NiMnGa single crystals embedded in a polymer matrix for slowly varying magnetic fields. The evolution of the microstructure is studied within the rate-independent variational framework proposed by Mielke and Theil (1999). The underlying variational model incorporates linearized elasticity, micromagnetism, stray field and a dissipation term proportional to the volume swept by the twin boundary. The time discretization is based on an incremental minimization of the sum of energy and dissipation. A backtracking approach is employed to approximately ensure the global minimality condition. We illustrate and discuss the influence of the particle geometry (volume fraction, shape, arrangement) and the polymer elastic parameters on the observed hysteresis and compare with recent experimental results.

  11. Contact angle hysteresis and pinning at periodic defects in statics

    NASA Astrophysics Data System (ADS)

    Iliev, Stanimir; Pesheva, Nina; Nikolayev, Vadim S.

    2014-07-01

    This article deals with the theoretical prediction of the wetting hysteresis on nonideal solid surfaces in terms of the surface heterogeneity parameters. The spatially periodical chemical heterogeneity is considered. We propose precise definitions for both the advancing and the receding contact angles for the Wilhelmy plate geometry. It is well known that in such a system, a multitude of metastable states of the liquid meniscus occurs for each different relative position of the defect pattern on the plate with respect to the liquid level. As usual, the static advancing and receding angles are assumed to be a consequence of the preceding contact line motion in the respective direction. It is shown how to select the appropriate states among all metastable states. Their selection is discussed. The proposed definitions are applicable to both the static and the dynamic contact angles on heterogeneous surfaces. The static advancing and receding angles are calculated for two examples of periodic heterogeneity patterns with sharp borders: the horizontal alternating stripes of a different wettability (studied analytically) and the doubly periodic pattern of circular defects on a homogeneous base (studied numerically). The wetting hysteresis is determined as a function of the defect density and the spatial period. A comparison with the existing results is carried out.

  12. The role of hysteresis in modeling root water uptake, both for single root and root system models.

    NASA Astrophysics Data System (ADS)

    de Willigen, P.; Heinen, M.

    2009-04-01

    The water retention curve obtained by progressive extraction of water from an initially saturated soil (desorption) differs from that obtained by gradual addition of water to air-dry soil (absorption). This phenomenon is called hysteresis (Koorevaar et al., 1983). Common as its occurrence is, it is often neglected in the modeling of root water uptake. We will present here a model for the transport of water to a single root. The model solves Richard's equation in cylindrical coordinates where the water uptake rate is a function of the root water potential. The occurrence of hysteresis is accounted for by application of the modified dependent domain model developed by Mualem (1984) and used by Kool and Parker (1987). We will discuss the differences in results due to the inclusion of the hysteresis subroutine, when alternate wetting and drying cycles occur. The influence of soil type and transpiration reduction function will be discussed. The findings obtained for the single root model were used to upscale root water uptake to a root system. This is a part of the FUSSIM2 model of Heinen and de Willigen (1998) and Heinen (2001), where water transport in a soil profile is calculated. We will use an example for a soil profile where the root length density decreases exponentially with depth, and where again wetting and drying cycles alternate. References Heinen M., 2001. FUSSIM2: brief description of the simulation model and application to fertigation scenarios. Agronomie 21: 285-296. Heinen, M., and P. de Willigen, 1998. FUSSIM2 A two-dimensional simulation model for water flow, solute transport and root uptake of water and nutrients in partly unsaturated porous media, QASA No. 20, AB-DLO, Wageningen, The Netherlands, 140 p. Kool J.B. and J.C. Parker, 1987. Development and evaluation of closed form expressions for hysteretic soil hydraulic properties. Water Resour. Res. 23: 105 114. Koorevaar P., G. Menelik and C. Dirksen, 1983. Elements of soil physics. Elsevier

  13. Laboratory and Field Investigations of Dynamic Effects in Soil Water Retention Curve

    NASA Astrophysics Data System (ADS)

    Chiu, Yung-Chia; Tseng, Yen-Huiang; Ye, Jiun-Yan

    2015-04-01

    The unsaturated soil is a multi-phase system and the embedded physical mechanisms and chemical reactions are very complicated. The characteristics of groundwater flow and mechanisms of mass transport are still ambiguous so far. In order to fully understand the flow and transport in the unsaturated zone, the soil water retention curve plays an important role in description of water flow. However, the measurements and calculations of soil water retention curve are usually obtained under the static condition or steady state (equilibrium), in which the dynamic effects (non-equilibrium) are not considered, and the obtained relationship between capillary pressure and saturation is skeptical. Therefore, the sandbox experiments and field tests will be conducted to discuss the dynamic effects in the soil water retention curve and hysteresis effect in this study. In the laboratory, the relations between capillary pressure, saturation, the rate of change of water content, and dynamic constant are evaluated through different setting of boundary conditions and different sizes of particles. In the field, the tests are conducted to describe the soil water retention curve through the rain simulator and artificial evaporation. Besides, the dynamic dewpoint potentiameter is used to analyze the hysteresis effect of soil samples, and its results are compared with the results obtained from sandbox and field experiments. Finally, through a series of experiments, the relationship between capillary pressure and saturation under the dynamic effects is established, and the associated theories and mechanisms are discussed. The works developed in this study can provide as reference tools for the hydrogeological investigation and contaminated site remediation in the future. Keywords: capillary pressure, saturation, soil water retention curve, hysteresis, sandbox experiment, field test

  14. Unstable Reaction Intermediates and Hysteresis during the Catalytic Cycle of 5-Aminolevulinate Synthase

    PubMed Central

    Stojanovski, Bosko M.; Hunter, Gregory A.; Jahn, Martina; Jahn, Dieter; Ferreira, Gloria C.

    2014-01-01

    5-Aminolevulinate (ALA), an essential metabolite in all heme-synthesizing organisms, results from the pyridoxal 5′-phosphate (PLP)-dependent enzymatic condensation of glycine with succinyl-CoA in non-plant eukaryotes and α-proteobacteria. The predicted chemical mechanism of this ALA synthase (ALAS)-catalyzed reaction includes a short-lived glycine quinonoid intermediate and an unstable 2-amino-3-ketoadipate intermediate. Using liquid chromatography coupled with tandem mass spectrometry to analyze the products from the reaction of murine erythroid ALAS (mALAS2) with O-methylglycine and succinyl-CoA, we directly identified the chemical nature of the inherently unstable 2-amino-3-ketoadipate intermediate, which predicates the glycine quinonoid species as its precursor. With stopped-flow absorption spectroscopy, we detected and confirmed the formation of the quinonoid intermediate upon reacting glycine with ALAS. Significantly, in the absence of the succinyl-CoA substrate, the external aldimine predominates over the glycine quinonoid intermediate. When instead of glycine, l-serine was reacted with ALAS, a lag phase was observed in the progress curve for the l-serine external aldimine formation, indicating a hysteretic behavior in ALAS. Hysteresis was not detected in the T148A-catalyzed l-serine external aldimine formation. These results with T148A, a mALAS2 variant, which, in contrast to wild-type mALAS2, is active with l-serine, suggest that active site Thr-148 modulates ALAS strict amino acid substrate specificity. The rate of ALA release is also controlled by a hysteretic kinetic mechanism (observed as a lag in the ALA external aldimine formation progress curve), consistent with conformational changes governing the dissociation of ALA from ALAS. PMID:24920668

  15. Hysteresis and drift of spiral waves near heterogeneities: From chemical experiments to cardiac simulations.

    PubMed

    Nakouzi, Elias; Totz, Jan Frederik; Zhang, Zhihui; Steinbock, Oliver; Engel, Harald

    2016-02-01

    Dissipative patterns in excitable reaction-diffusion systems can be strongly affected by spatial heterogeneities. Using the photosensitive Belousov-Zhabotinsky reaction, we show a hysteresis effect in the transition between free and pinned spiral rotation. The latter state involves the rotation around a disk-shaped obstacle with an impermeable and inert boundary. The transition is controlled by changes in light intensity. For permeable heterogeneities of higher excitability, we observe spiral drift along both linear and circular boundaries. Our results confirm recent theoretical predictions and, in the case of spiral drift, are further reproduced by numerical simulations with a modified Oregonator model. Additional simulations with a cardiac model show that orbital motion can also exist in anisotropic and three-dimensional systems.

  16. A N2(3-) radical-bridged terbium complex exhibiting magnetic hysteresis at 14 K.

    PubMed

    Rinehart, Jeffrey D; Fang, Ming; Evans, William J; Long, Jeffrey R

    2011-09-14

    The synthesis and magnetic properties of three new N(2)(3-) radical-bridged dilanthanide complexes, {[(Me(3)Si)(2)N](2)(THF)Ln}(2)(μ-η(2):η(2)-N(2))(-) (Ln = Tb, Ho, Er), are reported. All three display signatures of single-molecule-magnet behavior, with the terbium congener exhibiting magnetic hysteresis at 14 K and a 100 s blocking temperature of 13.9 K. The results show how synergizing the strong magnetic anisotropy of terbium(III) with the effective exchange-coupling ability of the N(2)(3-) radical can create the hardest molecular magnet discovered to date. Through comparisons with non-radical-bridged ac magnetic susceptibility measurements, we show that the magnetic exchange coupling hinders zero-field fast relaxation pathways, forcing thermally activated relaxation behavior over a much broader temperature range.

  17. Three-Dimensionally Mesostructured Fe2O3 Electrodes with Good Rate Performance and Reduced Voltage Hysteresi

    DOE PAGES

    Wang, Junjie; Braun, Paul V.; Zhou, Hui; ...

    2015-03-26

    Ni scaffolded mesostructured 3D Fe2O3 electrodes were fabricated by colloidal templating and pulsed elec-trodeposition. The scaffold provided short pathways for both lithium ions and electrons in the active phase, enabling fast kinetics and thus a high power density. The scaffold also resulted in a reduced voltage hysteresis. The electrode showed a reversible capacity of ~1000 mA h g-1 at 0.2 A g-1 (~0.2 C) for about 20 cycles, and at a current density of 20 A g-1 (~20 C) the deliverable capacity was about 450 mA h g-1. The room temperature voltage hysteresis at 0.1 A g-1 (~0.1 C) wasmore » 0.62 V, which is significantly smaller than that normally reported in the literature. And it could be further reduced to 0.42 V when cycling at 45 ºC. Potentiostatic electrochemical impedance spectroscopy (PEIS) studies indicated the small voltage hysteresis may be due to a reduction in the Li2O/Fe interfacial area in the electrode during cycling relative to convention-al conversion systems.« less

  18. Transient multi-physics analysis of a magnetorheological shock absorber with the inverse Jiles-Atherton hysteresis model

    NASA Astrophysics Data System (ADS)

    Zheng, Jiajia; Li, Yancheng; Li, Zhaochun; Wang, Jiong

    2015-10-01

    This paper presents multi-physics modeling of an MR absorber considering the magnetic hysteresis to capture the nonlinear relationship between the applied current and the generated force under impact loading. The magnetic field, temperature field, and fluid dynamics are represented by the Maxwell equations, conjugate heat transfer equations, and Navier-Stokes equations. These fields are coupled through the apparent viscosity and the magnetic force, both of which in turn depend on the magnetic flux density and the temperature. Based on a parametric study, an inverse Jiles-Atherton hysteresis model is used and implemented for the magnetic field simulation. The temperature rise of the MR fluid in the annular gap caused by core loss (i.e. eddy current loss and hysteresis loss) and fluid motion is computed to investigate the current-force behavior. A group of impulsive tests was performed for the manufactured MR absorber with step exciting currents. The numerical and experimental results showed good agreement, which validates the effectiveness of the proposed multi-physics FEA model.

  19. Three-body choreographies in given curves

    NASA Astrophysics Data System (ADS)

    Ozaki, Hiroshi; Fukuda, Hiroshi; Fujiwara, Toshiaki

    2009-10-01

    As shown by Johannes Kepler in 1609, in the two-body problem, the shape of the orbit, a given ellipse, and a given non-vanishing constant angular momentum determine the motion of the planet completely. Even in the three-body problem, in some cases, the shape of the orbit, conservation of the center of mass and a constant of motion (the angular momentum or the total energy) determine the motion of the three bodies. We show, by a geometrical method, that choreographic motions, in which equal mass three bodies chase each other around the same curve, will be uniquely determined for the following two cases. (i) Convex curves that have point symmetry and non-vanishing angular momentum are given. (ii) Eight-shaped curves which are similar to the curve for the figure-eight solution and the energy constant are given. The reality of the motion should be tested whether the motion satisfies an equation of motion or not. Extensions of the method for generic curves are shown. The extended methods are applicable to generic curves which do not have point symmetry. Each body may have its own curve and its own non-vanishing masses.

  20. Generating artificial light curves: revisited and updated

    NASA Astrophysics Data System (ADS)

    Emmanoulopoulos, D.; McHardy, I. M.; Papadakis, I. E.

    2013-08-01

    The production of artificial light curves with known statistical and variability properties is of great importance in astrophysics. Consolidating the confidence levels during cross-correlation studies, understanding the artefacts induced by sampling irregularities, establishing detection limits for future observatories are just some of the applications of simulated data sets. Currently, the widely used methodology of amplitude and phase randomization is able to produce artificial light curves which have a given underlying power spectral density (PSD) but which are strictly Gaussian distributed. This restriction is a significant limitation, since the majority of the light curves, e.g. active galactic nuclei, X-ray binaries, gamma-ray bursts, show strong deviations from Gaussianity exhibiting `burst-like' events in their light curves yielding long-tailed probability density functions (PDFs). In this study, we propose a simple method which is able to precisely reproduce light curves which match both the PSD and the PDF of either an observed light curve or a theoretical model. The PDF can be representative of either the parent distribution or the actual distribution of the observed data, depending on the study to be conducted for a given source. The final artificial light curves contain all of the statistical and variability properties of the observed source or theoretical model, i.e. the same PDF and PSD, respectively. Within the framework of Reproducible Research, the code and the illustrative example used in this paper are both made publicly available in the form of an interactive MATHEMATICA notebook.