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Sample records for imperfect hexagonal lattice

  1. Stimulation of vapor nucleation on perfect and imperfect hexagonal lattice surfaces

    NASA Astrophysics Data System (ADS)

    Shevkunov, S. V.

    2008-12-01

    Monte Carlo simulations of water vapor nucleation on a perfect crystal surface and on a surface with defects are performed. Mass exchange with the vapor phase is modeled by using an open ensemble. Cluster-substrate interaction is described in terms of conventional atom-atom potentials. The Hamiltonian of the system includes expressions for electrostatic, polarization, exchange, and dispersion interactions. The Gibbs free energy and work of adsorption are calculated by Monte Carlo simulation in the bicanoĭnical ensemble. The microscopic structure of nuclei is analyzed in terms of pair correlation functions. Periodic boundary conditions are used to simulate an infinite substrate surface. Molecule-substrate and molecule-molecule long-range electrostatic interactions are calculated by summing the Fourier harmonics of the electrostatic potential. Dispersion interactions are calculated by direct summation over layers of unit cells. Nucleation on a surface with matching structure follows a layer-by-layer mechanism. The work of adsorption per molecule of a monolayer on the substrate surface has a maximum as a function of nucleus size. The steady rate of nucleation of islands of supercritical size is evaluated. The work of adsorption per molecule for layer-by-layer film growth is an oscillating function of cluster size. As a function of layer number, it has a minimum depending on the vapor pressure. The electric field generated by a microscopic surface protrusion destroys the layered structure of the condensate and eliminates free-energy nucleation barriers. However, point lattice defects do not stimulate explosive nucleation.

  2. Discrete breathers in hexagonal dusty plasma lattices

    SciTech Connect

    Koukouloyannis, V.; Kourakis, I.

    2009-08-15

    The occurrence of single-site or multisite localized vibrational modes, also called discrete breathers, in two-dimensional hexagonal dusty plasma lattices is investigated. The system is described by a Klein-Gordon hexagonal lattice characterized by a negative coupling parameter epsilon in account of its inverse dispersive behavior. A theoretical analysis is performed in order to establish the possibility of existence of single as well as three-site discrete breathers in such systems. The study is complemented by a numerical investigation based on experimentally provided potential forms. This investigation shows that a dusty plasma lattice can support single-site discrete breathers, while three-site in phase breathers could exist if specific conditions, about the intergrain interaction strength, would hold. On the other hand, out of phase and vortex three-site breathers cannot be supported since they are highly unstable.

  3. Ultracold Quantum Gases in Hexagonal Optical Lattices

    NASA Astrophysics Data System (ADS)

    Sengstock, Klaus

    2010-03-01

    Hexagonal structures occur in a vast variety of systems, ranging from honeycombs of bees in life sciences to carbon nanotubes in material sciences. The latter, in particular its unfolded two-dimensional layer -- Graphene -- has rapidly grown to one of the most discussed topics in condensed-matter physics. Not only does it show proximity to various carbon-based materials but also exceptional properties owing to its unusual energy spectrum. In quantum optics, ultracold quantum gases confined in periodic light fields have shown to be very general and versatile instruments to mimic solid state systems. However, so far nearly all experiments were performed in cubic lattice geometries only. Here we report on the first experimental realization of ultracold quantum gases in a state-dependent, two-dimensional, Graphene-like optical lattice with hexagonal symmetry. The lattice is realized via a spin-dependent optical lattice structure with alternating σ^+ and σ^- -sites and thus constitutes a so called `magnetic'-lattice with `antiferromagnetic'-structure. Atoms with different spin orientation can be loaded to specific lattice sites or -- depending on the parameters -- to the whole lattice. As a consequence e.g. superpositions of a superfluid spin component with a different spin component in the Mott-insulating phase can be realized as well as spin-dependent transport properties, disorder etc. After preparing an antiferromagnetically ordered state we e.g. measure sustainable changes of the transport properties of the atoms. This manifests in a significant reduction of the tunneling as compared to a single-component system. We attribute this observation to a partial tunneling blockade for one spin component induced by population in another spin component localized at alternating lattice sites. Within a Gutzwiller-Ansatz we calculate the phase diagrams for the mixed spin-states and find very good agreement with our experimental results. Moreover, by state-resolved recording

  4. Instability of vibrational modes in hexagonal lattice

    NASA Astrophysics Data System (ADS)

    Korznikova, Elena A.; Bachurin, Dmitry V.; Fomin, Sergey Yu.; Chetverikov, Alexander P.; Dmitriev, Sergey V.

    2017-02-01

    The phenomenon of modulational instability is investigated for all four delocalized short-wave vibrational modes recently found for the two-dimensional hexagonal lattice with the help of a group-theoretic approach. The polynomial pair potential with hard-type quartic nonlinearity ( β-FPU potential with β > 0) is used to describe interactions between atoms. As expected for the hard-type anharmonic interactions, for all four modes the frequency is found to increase with the amplitude. Frequency of the modes I and III bifurcates from the upper edge of the phonon spectrum, while that of the modes II and IV increases from inside the spectrum. It is also shown that the considered model supports spatially localized vibrational mode called discrete breather (DB) or intrinsic localized mode. DB frequency increases with the amplitude above the phonon spectrum. Two different scenarios of the mode decay were revealed. In the first scenario (for modes I and III), development of the modulational instability leads to a formation of long-lived DBs that radiate their energy slowly until thermal equilibrium is reached. In the second scenario (for modes II and IV) a transition to thermal oscillations of atoms is observed with no formation of DBs.

  5. Multilayer DNA Origami Packed on Hexagonal and Hybrid Lattices

    PubMed Central

    Ke, Yonggang; Voigt, Niels V.; Gothelf, Kurt V.; Shih, William M.

    2012-01-01

    “Scaffolded DNA origami” has been proven to be a powerful and efficient approach to construct two-dimensional or three-dimensional objects with great complexity. Multilayer DNA origami has been demonstrated with helices packing along either honeycomb-lattice geometry or square-lattice geometry. Here we report successful folding of multilayer DNA origami with helices arranged on a close-packed hexagonal lattice. This arrangement yields a higher density of helical packing and therefore higher resolution of spatial addressing than has been shown previously. We also demonstrate hybrid multilayer DNA origami with honeycomb-lattice, square-lattice, and hexagonal lattice packing of helices all in one design. The availability of hexagonal close packing of helices extends our ability to build complex structures using DNA nanotechnology. PMID:22187940

  6. sd(2) Graphene: Kagome band in a hexagonal lattice.

    PubMed

    Zhou, Miao; Liu, Zheng; Ming, Wenmei; Wang, Zhengfei; Liu, Feng

    2014-12-05

    Graphene, made of sp^{2} hybridized carbon, is characterized with a Dirac band, representative of its underlying 2D hexagonal lattice. The fundamental understanding of graphene has recently spurred a surge in the search for 2D topological quantum phases in solid-state materials. Here, we propose a new form of 2D material, consisting of sd^{2} hybridized transition metal atoms in hexagonal lattice, called sd^{2} "graphene." The sd^{2} graphene is characterized by bond-centered electronic hopping, which transforms the apparent atomic hexagonal lattice into the physics of a kagome lattice that may exhibit a wide range of topological quantum phases. Based on first-principles calculations, room-temperature quantum anomalous Hall states with an energy gap of ∼0.1  eV are demonstrated for one such lattice made of W, which can be epitaxially grown on a semiconductor surface of 1/3 monolayer Cl-covered Si(111), with high thermodynamic and kinetic stability.

  7. Epitaxy on Substrates with Hexagonal Lattice Symmetry.

    NASA Astrophysics Data System (ADS)

    Braun, Max Willi Hermann

    A general description of epitaxy between thin films and substrates of general symmetry was developed from a model with rigid substrate and overgrowth and extended to include strain of the overgrowth. The overgrowth-substrate interaction was described by Fourier series, usually truncated, defined on the reciprocal lattice of the interface surfaces of the crystals. Energy considerations lead directly to a criterion that epitaxial configurations occur when a pair of surface reciprocal lattice vectors of the substrate and overgrowth coincide, equivalent to atomic row matching. This is analogous to the von Laue criterion and Bragg equations of diffraction theory, with a geometrical realization related to the Ewald construction. When generalized, misfit strain, the spacing, line sense and Burgers vectors of misfit dislocations and misfit verniers are obtained from the reciprocal lattices of crystals with any symmetry and misfit. The most general structures can be described with convenient unit cells by using structure factors. Homogeneous misfit strain, the interfacial atom positions after local relaxation and misfit and elastic (harmonic approximation) strain energies were obtained by direct minimization of the total interfacial energy of a large (1105 atoms), but finite, system. The local relaxation was calculated with a Finite Element formulation. Systems with fcc {111 } or bcc{ 110} overgrowths on fcc {111} or hcp{0001} substrates were studied with respect to substrate symmetry, overgrowth size and anisotropy of the overgrowth elastic constants. Configurations such as Kurdjumov-Sachs (KS), Nishiyama-Wassermann (NW) and a pseudomorphic phase (2DC) were explained, while several other higher order configurations were predicted. The inherent difference in nature between the KS and NW and their relationship to the 2DC were emphasized. Deviations from the ideal orientation of KS linked to anisotropy for systems undergoing misfit strain were discovered. Deviations were also

  8. Lattice-Polarity-Driven Epitaxy of Hexagonal Semiconductor Nanowires.

    PubMed

    Wang, Ping; Yuan, Ying; Zhao, Chao; Wang, Xinqiang; Zheng, Xiantong; Rong, Xin; Wang, Tao; Sheng, Bowen; Wang, Qingxiao; Zhang, Yongqiang; Bian, Lifeng; Yang, Xuelin; Xu, Fujun; Qin, Zhixin; Li, Xinzheng; Zhang, Xixiang; Shen, Bo

    2016-02-10

    Lattice-polarity-driven epitaxy of hexagonal semiconductor nanowires (NWs) is demonstrated on InN NWs. In-polarity InN NWs form typical hexagonal structure with pyramidal growth front, whereas N-polarity InN NWs slowly turn to the shape of hexagonal pyramid and then convert to an inverted pyramid growth, forming diagonal pyramids with flat surfaces and finally coalescence with each other. This contrary growth behavior driven by lattice-polarity is most likely due to the relatively lower growth rate of the (0001̅) plane, which results from the fact that the diffusion barriers of In and N adatoms on the (0001) plane (0.18 and 1.0 eV, respectively) are about 2-fold larger in magnitude than those on the (0001̅) plane (0.07 and 0.52 eV), as calculated by first-principles density functional theory (DFT). The formation of diagonal pyramids for the N-polarity hexagonal NWs affords a novel way to locate quantum dot in the kink position, suggesting a new recipe for the fabrication of dot-based devices.

  9. Quantum interference and decoherence in hexagonal antidot lattices

    NASA Astrophysics Data System (ADS)

    Iye, Yasuhiro; Ueki, Masaaki; Endo, Akira; Katsumoto, Shingo

    2003-09-01

    The Altshuler-Aronov-Spivak (AAS) oscillations and the Aharonov-Bohm (AB) type oscillations both at low and high magnetic fields were observed in hexagonal antidot lattices fabricated from a GaAs/AlGaAs two-dimensional electron gas sample. The periodicities in the magnetic field and in the gate bias voltage, of the high field AB oscillation furnish information on the edge states localized around the antidots. The temperature dependences of these quantum oscillations are studied.

  10. Colorings of odd or even chirality on hexagonal lattices

    NASA Astrophysics Data System (ADS)

    Cépas, O.

    2017-02-01

    We define two classes of colorings that have odd or even chirality on hexagonal lattices. This parity is an invariant in the dynamics of all loops, and explains why standard Monte Carlo algorithms are nonergodic. We argue that adding the motion of "stranded" loops allows for parity changes. By implementing this algorithm, we show that the even and odd classes have the same entropy. In general, they do not have the same number of states, except for the special geometry of long strips, where a Z2 symmetry between even and odd states occurs in the thermodynamic limit.

  11. Classical Heisenberg spins on a hexagonal lattice with Kitaev couplings.

    PubMed

    Chandra, Samarth; Ramola, Kabir; Dhar, Deepak

    2010-09-01

    We analyze the low temperature properties of a system of classical Heisenberg spins on a hexagonal lattice with Kitaev couplings. For a lattice of 2N sites with periodic boundary conditions, the ground states form an (N+1) dimensional manifold. We show that the ensemble of ground states is equivalent to that of a solid-on-solid model with continuously variable heights and nearest neighbor interactions, at a finite temperature. For temperature T tending to zero, all ground states have equal weight, and there is no order by disorder in this model. We argue that the bond-energy bond-energy correlations at distance R decay as 1/R2 at zero temperature. This is verified by Monte Carlo simulations. We also discuss the relation to the quantum spin- S Kitaev model for large S, and obtain lower and upper bounds on the ground-state energy of the quantum model.

  12. Proposal for generating synthetic magnetic fields in hexagonal optical lattices

    NASA Astrophysics Data System (ADS)

    Tian, Binbin; Endres, Manuel; Pekker, David

    2015-05-01

    We propose a new approach to generating synthetic magnetic fields in ultra cold atom systems that does not rely on either Raman transitions nor periodic drive. Instead, we consider a hexagonal optical lattice produced by the intersection of three laser beams at 120 degree angles, where the intensity of one or more of the beams is spatially non-uniform. The resulting optical lattice remains hexagonal, but has spatially varying hopping matrix elements. For atoms near the Dirac points, these spatial variations appear as a gauge field, similar to the fictitious gauge field that is induced for for electrons in strained graphene. We suggest that a robust way to generate a gauge field that corresponds to a uniform flux is to aligning three gaussian beams to intersect in an equilateral triangle. Using realistic experimental parameters, we show how the proposed setup can be used to observe cyclotron motion of an atom cloud - the conventional Hall effect and distinct Landau levels - the integer quantum Hall effect.

  13. Internal structure of hexagonal skyrmion lattices in cubic helimagnets

    NASA Astrophysics Data System (ADS)

    McGrouther, D.; Lamb, R. J.; Krajnak, M.; McFadzean, S.; McVitie, S.; Stamps, R. L.; Leonov, A. O.; Bogdanov, A. N.; Togawa, Y.

    2016-09-01

    We report the most precise observations to date concerning the spin structure of magnetic skyrmions in a nanowedge specimen of cubic B20 structured FeGe. Enabled by our development of advanced differential phase contrast (DPC) imaging (in a scanning transmission electron microscope (STEM)) we have obtained high spatial resolution quantitative measurements of skyrmion internal spin profile. For hexagonal skyrmion lattice cells, stabilised by an out-plane applied magnetic field, mapping of the in-plane component of magnetic induction has revealed precise spin profiles and that the internal structure possesses intrinsic six-fold symmetry. With increasing field strength, the diameter of skyrmion cores was measured to decrease and accompanied by a nonlinear variation of the lattice periodicity. Variations in structure for individual skyrmions across an area of the lattice were also studied utilising a new increased sensitivity DPC detection scheme and a variety of symmetry lowering distortions were observed. To provide insight into fundamental energetics we have constructed a phenomenological model, with which our experimental observations of spin profiles and field induced core diameter variation are in good agreement with predicted structure in the middle of the nanowedge crystal. In the vicinity of the crystal surfaces, our model predicts the existence of in-plane twisting distortions which our current experimental observations were not sensitive to. As an alternative to the requirement for as yet unidentified sources of magnetic anisotropy, we demonstrate that surface states could provide the energetic stabilisation needed for predomination over the conical magnetic phase.

  14. Discrete solitons and vortices in anisotropic hexagonal and honeycomb lattices

    NASA Astrophysics Data System (ADS)

    Hoq, Q. E.; Kevrekidis, P. G.; Bishop, A. R.

    2016-02-01

    In the present work, we consider the self-focusing discrete nonlinear Schrödinger equation on hexagonal and honeycomb lattice geometries. Our emphasis is on the study of the effects of anisotropy, motivated by the tunability afforded in recent optical and atomic physics experiments. We find that multi-soliton and discrete vortex states undergo destabilizing bifurcations as the relevant anisotropy control parameter is varied. We quantify these bifurcations by means of explicit analytical calculations of the solutions, as well as of their spectral linearization eigenvalues. Finally, we corroborate the relevant stability picture through direct numerical computations. In the latter, we observe the prototypical manifestation of these instabilities to be the spontaneous rearrangement of the solution, for larger values of the coupling, into localized waveforms typically centered over fewer sites than the original unstable structure. For weak coupling, the instability appears to result in a robust breathing of the relevant waveforms.

  15. Discrete solitons and vortices in anisotropic hexagonal and honeycomb lattices

    DOE PAGES

    Hoq, Q. E.; Kevrekidis, P. G.; Bishop, A. R.

    2016-01-14

    We consider the self-focusing discrete nonlinear Schrödinger equation on hexagonal and honeycomb lattice geometries. Our emphasis is on the study of the effects of anisotropy, motivated by the tunability afforded in recent optical and atomic physics experiments. We find that multi-soliton and discrete vortex states undergo destabilizing bifurcations as the relevant anisotropy control parameter is varied. Furthermore, we quantify these bifurcations by means of explicit analytical calculations of the solutions, as well as of their spectral linearization eigenvalues. Finally, we corroborate the relevant stability picture through direct numerical computations. In the latter, we observe the prototypical manifestation of these instabilitiesmore » to be the spontaneous rearrangement of the solution, for larger values of the coupling, into localized waveforms typically centered over fewer sites than the original unstable structure. In weak coupling, the instability appears to result in a robust breathing of the relevant waveforms.« less

  16. Discrete solitons and vortices in anisotropic hexagonal and honeycomb lattices

    SciTech Connect

    Hoq, Q. E.; Kevrekidis, P. G.; Bishop, A. R.

    2016-01-14

    We consider the self-focusing discrete nonlinear Schrödinger equation on hexagonal and honeycomb lattice geometries. Our emphasis is on the study of the effects of anisotropy, motivated by the tunability afforded in recent optical and atomic physics experiments. We find that multi-soliton and discrete vortex states undergo destabilizing bifurcations as the relevant anisotropy control parameter is varied. Furthermore, we quantify these bifurcations by means of explicit analytical calculations of the solutions, as well as of their spectral linearization eigenvalues. Finally, we corroborate the relevant stability picture through direct numerical computations. In the latter, we observe the prototypical manifestation of these instabilities to be the spontaneous rearrangement of the solution, for larger values of the coupling, into localized waveforms typically centered over fewer sites than the original unstable structure. In weak coupling, the instability appears to result in a robust breathing of the relevant waveforms.

  17. Visualization of the hexagonal lattice in the erythrocyte membrane skeleton.

    PubMed

    Liu, S C; Derick, L H; Palek, J

    1987-03-01

    The isolated membrane skeleton of human erythrocytes was studied by high resolution negative staining electron microscopy. When the skeletal meshwork is spread onto a thin carbon film, clear images of a primarily hexagonal lattice of junctional F-actin complexes crosslinked by spectrin filaments are obtained. The regularly ordered network extends over the entire membrane skeleton. Some of the junctional complexes are arranged in the form of pentagons and septagons, approximately 3 and 8%, respectively. At least five forms of spectrin crosslinks are detected in the spread skeleton including a single spectrin tetramer linking two junctional complexes, three-armed Y-shaped spectrin molecules linking three junctional complexes, three-armed spectrin molecules connecting two junctional complexes with two arms bound to one complex and the third arm bound to the adjacent complex, double spectrin filaments linking two junctional complexes, and four-armed spectrin molecules linking two junctional complexes. Of these, the crosslinks of single spectrin tetramers and three-armed molecules are the most abundant and represent 84 and 11% of the total crosslinks, respectively. These observations are compatible with the presence of spectrin tetramers and oligomers in the erythrocyte membrane skeleton. Globular structures (9-12 nm in diameter) are attached to the majority of the spectrin tetramers or higher order oligomer-like molecules, approximately 80 nm from the distal ends of the spectrin tetramers. These globular structures are ankyrinor ankyrin/band 3-containing complexes, since they are absent when ankyrin and residual band 3 are extracted from the skeleton under hypertonic conditions.

  18. One-dimensional lattices topologically equivalent to two-dimensional lattices within the context of the lattice gas model, III. The hexagonal lattice

    NASA Astrophysics Data System (ADS)

    Costanza, E. F.; Costanza, G.

    2017-02-01

    Continuum partial differential equations are obtained from a set of discrete stochastic evolution equations of both non-Markovian and Markovian processes and applied to the diffusion within the context of the lattice gas model. A procedure allowing to construct one-dimensional lattices that are topologically equivalent to two-dimensional lattices is described in detail in the case of a hexagonal lattice which has the particular feature that need four types of dynamical variables. This example shows additional features to the general procedure and some extensions are also suggested in order to provide a wider insight in the present approach.

  19. Self-Assembly of Cubes into 2D Hexagonal and Honeycomb Lattices by Hexapolar Capillary Interactions

    NASA Astrophysics Data System (ADS)

    Soligno, Giuseppe; Dijkstra, Marjolein; van Roij, René

    2016-06-01

    Particles adsorbed at a fluid-fluid interface induce capillary deformations that determine their orientations and generate mutual capillary interactions which drive them to assemble into 2D ordered structures. We numerically calculate, by energy minimization, the capillary deformations induced by adsorbed cubes for various Young's contact angles. First, we show that capillarity is crucial not only for quantitative, but also for qualitative predictions of equilibrium configurations of a single cube. For a Young's contact angle close to 90°, we show that a single-adsorbed cube generates a hexapolar interface deformation with three rises and three depressions. Thanks to the threefold symmetry of this hexapole, strongly directional capillary interactions drive the cubes to self-assemble into hexagonal or graphenelike honeycomb lattices. By a simple free-energy model, we predict a density-temperature phase diagram in which both the honeycomb and hexagonal lattice phases are present as stable states.

  20. Dust Lattice Waves in Two-Dimensional Hexagonal Dust Crystals with an External Magnetic Field

    SciTech Connect

    Farokhi, B.; Shahmansouri, M.

    2008-09-07

    The influence of a constant magnetic field on the propagation of dust-lattice (DL) modes in a two-dimensional hexagonal strongly coupled plasma crystal formed by paramagnetic particles is considered. The expression for the wave dispersion relation clearly shows that high-frequency and low-frequency branches exist as a result of the coupling of longitudinal and transverse modes due to the Lorentz force acting on the dust particles.

  1. Phase Diagram of an Extended Quantum Dimer Model on the Hexagonal Lattice

    NASA Astrophysics Data System (ADS)

    Schlittler, Thiago; Barthel, Thomas; Misguich, Grégoire; Vidal, Julien; Mosseri, Rémy

    2015-11-01

    We introduce a quantum dimer model on the hexagonal lattice that, in addition to the standard three-dimer kinetic and potential terms, includes a competing potential part counting dimer-free hexagons. The zero-temperature phase diagram is studied by means of quantum Monte Carlo simulations, supplemented by variational arguments. It reveals some new crystalline phases and a cascade of transitions with rapidly changing flux (tilt in the height language). We analyze perturbatively the vicinity of the Rokhsar-Kivelson point, showing that this model has the microscopic ingredients needed for the "devil's staircase" scenario [Eduardo Fradkin et al. Phys. Rev. B 69, 224415 (2004)], and is therefore expected to produce fractal variations of the ground-state flux.

  2. Devil's staircase in a quantum dimer model on the hexagonal lattice

    NASA Astrophysics Data System (ADS)

    Barthel, Thomas; Misguich, Grégoire; Schlittler, Thiago M.; Vidal, Julien; Mosseri, Rémy

    Quantum dimer models appear in different contexts when describing dynamics in constrained low-energy manifolds, such as for frustrated Ising models in weak transverse fields. In this talk, I address a particularly interesting case, where a quantum dimer model on the hexagonal lattice, in addition to the standard Rokhsar-Kivelson Hamiltonian, includes a competing potential term, counting dimer-free hexagons. It has a rich zero-temperature phase diagram that comprises a cascade of rapidly changing flux quantum numbers (tilt in the height language). This cascade is partially of fractal nature and the model provides, in particular, a microscopic realization of the ``devil's staircase'' scenario [E. Fradkin et al. Phys. Rev. B 69, 224415 (2004)]. We have studied the system by means of quantum Monte-Carlo simulations and the results can be explained using perturbation theory, RG, and variational arguments.References: arXiv:1507.04643, arXiv:1501.02242.

  3. Discrete solitons and vortices in hexagonal and honeycomb lattices: existence, stability, and dynamics.

    PubMed

    Law, K J H; Kevrekidis, P G; Koukouloyannis, V; Kourakis, I; Frantzeskakis, D J; Bishop, A R

    2008-12-01

    We consider a prototypical dynamical lattice model, namely, the discrete nonlinear Schrödinger equation on nonsquare lattice geometries. We present a systematic classification of the solutions that arise in principal six-lattice-site and three-lattice-site contours in the form of both discrete multipole solitons and discrete vortices. Additionally to identifying the possible states, we analytically track their linear stability both qualitatively and quantitatively. We find that among the six-site configurations, the "hexapole" of alternating phases (0-pi) , as well as the vortex of topological charge S=2 have intervals of stability; among three-site states, only the vortex of topological charge S=1 may be stable in the case of focusing nonlinearity. These conclusions are confirmed both for hexagonal and for honeycomb lattices by means of detailed numerical bifurcation analysis of the stationary states from the anticontinuum limit, and by direct simulations to monitor the dynamical instabilities, when the latter arise. The dynamics reveal a wealth of nonlinear behavior resulting not only in single-site solitary wave forms, but also in robust multisite breathing structures.

  4. Conical wave propagation and diffraction in two-dimensional hexagonally packed granular lattices

    SciTech Connect

    Chong, C.; Kevrekidis, P. G.; Ablowitz, M. J.; Ma, Yi-Ping

    2016-01-25

    We explore linear and nonlinear mechanisms for conical wave propagation in two-dimensional lattices in the realm of phononic crystals. As a prototypical example, a statically compressed granular lattice of spherical particles arranged in a hexagonal packing configuration is analyzed. Upon identifying the dispersion relation of the underlying linear problem, the resulting diffraction properties are considered. Analysis both via a heuristic argument for the linear propagation of a wave packet and via asymptotic analysis leading to the derivation of a Dirac system suggests the occurrence of conical diffraction. This analysis is valid for strong precompression, i.e., near the linear regime. For weak precompression, conical wave propagation is still possible, but the resulting expanding circular wave front is of a nonoscillatory nature, resulting from the complex interplay among the discreteness, nonlinearity, and geometry of the packing. Lastly, the transition between these two types of propagation is explored.

  5. Conical wave propagation and diffraction in two-dimensional hexagonally packed granular lattices

    DOE PAGES

    Chong, C.; Kevrekidis, P. G.; Ablowitz, M. J.; ...

    2016-01-25

    We explore linear and nonlinear mechanisms for conical wave propagation in two-dimensional lattices in the realm of phononic crystals. As a prototypical example, a statically compressed granular lattice of spherical particles arranged in a hexagonal packing configuration is analyzed. Upon identifying the dispersion relation of the underlying linear problem, the resulting diffraction properties are considered. Analysis both via a heuristic argument for the linear propagation of a wave packet and via asymptotic analysis leading to the derivation of a Dirac system suggests the occurrence of conical diffraction. This analysis is valid for strong precompression, i.e., near the linear regime. Formore » weak precompression, conical wave propagation is still possible, but the resulting expanding circular wave front is of a nonoscillatory nature, resulting from the complex interplay among the discreteness, nonlinearity, and geometry of the packing. Lastly, the transition between these two types of propagation is explored.« less

  6. Dirac cones in two-dimensional systems: from hexagonal to square lattices.

    PubMed

    Liu, Zhirong; Wang, Jinying; Li, Jianlong

    2013-11-21

    The influence of lattice symmetry on the existence of Dirac cones was investigated for two distinct systems: a general two-dimensional (2D) atomic crystal containing two atoms in each unit cell and a 2D electron gas (2DEG) under a periodic muffin-tin potential. A criterion was derived under a tight-binding approximation for the existence of Dirac cones in the atomic crystal. When the transfer hoppings are assumed to be single functions of the distance between atoms, it was shown that the probability of observing Dirac cones in the atomic crystal gradually decreases before being reduced to zero when the lattice changes from hexagonal to square. For a 2DEG with full square symmetry, a Dirac point exists at the Brillouin zone corners, where the energy dispersion is parabolic not linear. These results suggest that conventional Dirac fermions (such as those in graphene) are difficult to achieve in a square lattice with full symmetry (wallpaper group p4mm).

  7. High Sensitivity Refractive Index Sensor Based on Dual-Core Photonic Crystal Fiber with Hexagonal Lattice.

    PubMed

    Wang, Haiyang; Yan, Xin; Li, Shuguang; An, Guowen; Zhang, Xuenan

    2016-10-08

    A refractive index sensor based on dual-core photonic crystal fiber (PCF) with hexagonal lattice is proposed. The effects of geometrical parameters of the PCF on performances of the sensor are investigated by using the finite element method (FEM). Two fiber cores are separated by two air holes filled with the analyte whose refractive index is in the range of 1.33-1.41. Numerical simulation results show that the highest sensitivity can be up to 22,983 nm/RIU(refractive index unit) when the analyte refractive index is 1.41. The lowest sensitivity can reach to 21,679 nm/RIU when the analyte refractive index is 1.33. The sensor we proposed has significant advantages in the field of biomolecule detection as it provides a wide-range of detection with high sensitivity.

  8. High Sensitivity Refractive Index Sensor Based on Dual-Core Photonic Crystal Fiber with Hexagonal Lattice

    PubMed Central

    Wang, Haiyang; Yan, Xin; Li, Shuguang; An, Guowen; Zhang, Xuenan

    2016-01-01

    A refractive index sensor based on dual-core photonic crystal fiber (PCF) with hexagonal lattice is proposed. The effects of geometrical parameters of the PCF on performances of the sensor are investigated by using the finite element method (FEM). Two fiber cores are separated by two air holes filled with the analyte whose refractive index is in the range of 1.33–1.41. Numerical simulation results show that the highest sensitivity can be up to 22,983 nm/RIU(refractive index unit) when the analyte refractive index is 1.41. The lowest sensitivity can reach to 21,679 nm/RIU when the analyte refractive index is 1.33. The sensor we proposed has significant advantages in the field of biomolecule detection as it provides a wide-range of detection with high sensitivity. PMID:27740607

  9. Enhanced optical spin current injection in the hexagonal lattice with intrinsic and Rashba spin-orbit interactions

    NASA Astrophysics Data System (ADS)

    Zou, Jianfei; Tang, Chunmei; Zhang, Aimei

    2017-04-01

    We study the photo-induced spin current injection in a hexagonal lattice with both intrinsic and Rashba spin-orbit interactions which is irradiated by a polarized light beam. It is found that the spin current injection rate could be enhanced as the graphene lattice is in the topological insulator state. Furthermore, the spin current injection rate could be remarkably modulated by the degree of polarization of light and its frequency.

  10. The Calculation of the Band Structure in 3D Phononic Crystal with Hexagonal Lattice

    NASA Astrophysics Data System (ADS)

    Aryadoust, Mahrokh; Salehi, H.

    2015-12-01

    In this article, the propagation of acoustic waves in the phononic crystals (PCs) of three dimensions with the hexagonal (HEX) lattice is studied theoretically. The PCs are constituted of nickel (Ni) spheres embedded in epoxy. The calculations of the band structure and the density of states are performed using the plane wave expansion (PWE) method in the irreducible part of the Brillouin zone (BZ). In this study, we analyse the dependence of the band structures inside (the complete band gap width) on c/a and filling fraction in the irreducible part of the first BZ. Also, we have analysed the band structure of the ALHA and MLHKM planes. The results show that the maximum width of absolute elastic band gap (AEBG) (0.045) in the irreducible part of the BZ of HEX lattice is formed for c/a=6 and filling fraction equal to 0.01. In addition, the maximum of the first and second AEBG widths are 0.0884 and 0.0474, respectively, in the MLHKM plane, and the maximum of the first and second AEBG widths are 0.0851 and 0.0431, respectively, in the ALHA plane.

  11. Direct x-ray observation of a single hexagonal myofilament lattice in native myofibrils of striated muscle.

    PubMed Central

    Iwamoto, Hiroyuki; Nishikawa, Yukihiro; Wakayama, Jun'ichi; Fujisawa, Tetsuro

    2002-01-01

    A striated muscle fiber consists of thousands of myofibrils with crystalline hexagonal myofilament lattices. Because the lattices are randomly oriented, the fiber gives rise to an equatorial x-ray diffraction pattern, which is essentially a rotary-averaged "powder diffraction," carrying only information about the distance between the lattice planes. We were able to record an x-ray diffraction pattern from a single myofilament lattice, very likely originating from a single myofibril from the flight muscle of a bumblebee, by orienting the incident x-ray microbeam along the myofibrillar axis (end-on diffraction). The pattern consisted of a number of hexagonally symmetrical diffraction spots whose originating lattice planes were readily identified. This also held true for some of the weak higher order reflections. The spot-like appearance of reflections implies that the lattice order is extremely well maintained for a distance of millimeters, covering up to a thousand of approximately 2.5-microm-long sarcomeres connected in series. The results open the possibility of applying the x-ray microdiffraction technique to study many other micrometer-sized assemblies of functional biomolecules in the cell. PMID:12124287

  12. Study on hexagonal super-lattice pattern with surface discharges in dielectric barrier discharge

    NASA Astrophysics Data System (ADS)

    Liu, Ying; Dong, Lifang; Niu, Xuejiao; Gao, Yenan; Zhang, Chao

    2015-10-01

    The hexagonal super-lattice pattern with surface discharges (SDs) in dielectric barrier discharge is investigated by intensified charge-coupled device. The pattern is composed of the bright spot and the dim spot which is located at the centroid of surrounding other three bright spots. The phase diagram of the pattern as a function of the gas pressure and the argon concentration is given. The instantaneous images indicate that the bright spot emerging at the front of the current pulse is formed by the volume discharge (VD), and dim spot occurring at the tail of the current pulse is formed by the SD. The above result shows that the SD is induced by the VD. The simulation of the electric fields of wall charges accumulated by VDs confirms that the dim spot is formed by the confluences of the SDs of surrounding other three bright spots. By using optical emission spectrum method, both the molecule vibration temperature and electron density of the SD are larger than that of the VD.

  13. Study on hexagonal super-lattice pattern with surface discharges in dielectric barrier discharge

    SciTech Connect

    Liu, Ying; Dong, Lifang Niu, Xuejiao; Gao, Yenan; Zhang, Chao

    2015-10-15

    The hexagonal super-lattice pattern with surface discharges (SDs) in dielectric barrier discharge is investigated by intensified charge-coupled device. The pattern is composed of the bright spot and the dim spot which is located at the centroid of surrounding other three bright spots. The phase diagram of the pattern as a function of the gas pressure and the argon concentration is given. The instantaneous images indicate that the bright spot emerging at the front of the current pulse is formed by the volume discharge (VD), and dim spot occurring at the tail of the current pulse is formed by the SD. The above result shows that the SD is induced by the VD. The simulation of the electric fields of wall charges accumulated by VDs confirms that the dim spot is formed by the confluences of the SDs of surrounding other three bright spots. By using optical emission spectrum method, both the molecule vibration temperature and electron density of the SD are larger than that of the VD.

  14. Hofstadter butterfly and quantum transport in graphene on hexagonal boron nitride from multiscale lattice simulations

    NASA Astrophysics Data System (ADS)

    Leconte, Nicolas; Martinez-Gordillo, Rafael; MacDonald, Allan; Jung, Jeil

    Clear signatures of the Hofstadter butterfly have been experimentally observed in graphene on hexagonal boron nitride (G/BN), thanks to an appropriate balance between the length scale and the quality of the moiré superlattices. During this talk, I will present a methodology to map the continuum moiré pattern of incommensurable G/BN crystals obtained from ab initio calculations onto supercell lattice tight-binding Hamiltonians. Using efficient Lanczos recursion techniques for simulating large scale systems containing millions of atoms, the density of states and the dc conductivity are obtained as a function of energy or carrier density and magnetic field. The calculated Hofstadter butterflies and Landau fan diagrams show that the site potential variations, the mass, and substantial virtual strain contributions that appear even in the absence of real strains in the band Hamiltonian sensitively affect the electron-hole asymmetry, the gaps at the secondary Dirac points, as well as the tertiary features that appear at high-carrier densities.

  15. An exact solution for the steady state phase distribution in an array of oscillators coupled on a hexagonal lattice

    NASA Technical Reports Server (NTRS)

    Pogorzelski, Ronald J.

    2004-01-01

    When electronic oscillators are coupled to nearest neighbors to form an array on a hexagonal lattice, the planar phase distributions desired for excitation of a phased array antenna are not steady state solutions of the governing non-linear equations describing the system. Thus the steady state phase distribution deviates from planar. It is shown to be possible to obtain an exact solution for the steady state phase distribution and thus determine the deviation from the desired planar distribution as a function of beam steering angle.

  16. Optical properties, lattice dynamics, and structural phase transition in hexagonal 2 H -BaMn O3 single crystals

    NASA Astrophysics Data System (ADS)

    Stanislavchuk, T. N.; Litvinchuk, A. P.; Hu, Rongwei; Jeon, Young Hun; Ji, Sung Dae; Cheong, S.-W.; Sirenko, A. A.

    2015-10-01

    Optical properties and lattice dynamics of hexagonal 2 H -BaMn O3 single crystals are studied experimentally in a wide temperature range by means of rotating analyzer ellipsometry and Raman scattering. The magnitude of the direct electronic band gap is found to be Eg=3.2 eV . At room temperature the far-infrared (IR) ellipsometry spectra reveal six IR-active phonons; two of them are polarized along the c axis and four are polarized within the a-b plane. Seven phonon modes are identified in the Raman scattering experiments. Group theoretical mode analysis and complementary density functional theory lattice dynamics calculations are consistent with the 2 H -BaMn O3 structure belonging to the polar P 63m c space group at room temperature. All observed vibrational modes are assigned to specific eigenmodes of the lattice. The neutron diffraction measurements reveal a structural phase transition upon cooling below TC=130 ±5 K , which is accompanied by a lattice symmetry change from P 63m c to P 63c m . Simultaneously, at temperatures below TC several additional IR- and Raman-active modes are detected in experimental spectra. This confirms the occurrence of a structural transition, which is possibly associated with the appearance of electrical polarization along the c axis and a previously known tripling of the primitive cell volume at low temperatures.

  17. Lattice dynamics, electronic structure, and optical properties of LiBeSb: A hexagonal ABC-type hyperferroelectrics

    NASA Astrophysics Data System (ADS)

    Dai, Jian-Qing; Zhu, Jian-Hui; Xu, Jie-Wang

    2016-07-01

    The recently discovered hexagonal ABC-type hyperferroelectrics, in which the polarization persists in the presence of the depolarization filed, exhibit a variety of intriguing and potentially useful properties [Garrity et al., Phys. Rev. Lett. 112, 127601 (2014)]. For the existing prototype of LiBeSb, we present detailed first-principles calculations concerning the lattice dynamics, electronic structure, and optical properties. An unstable longitudinal optic mode in the high-symmetry structure and a large polarization of 0.5 C/m2 in the polar phase are reported, including the remarkable dependence of Born effective charges on structural distortion. Using the HSE06 hybrid functional, we predict that LiBeSb has a small band-gap of 1.5 eV and shows dominant asymmetric covalent bonding character. Importantly, we find that there are remarkable absorptions in the whole visible spectrum. These features, combined with the enhanced carrier mobility, make LiBeSb as well as the whole family of hexagonal ABC-type hyperferroelectrics as promising candidates for ferroelectric photovoltaic materials with large bulk photovoltaic effect in the visible spectrum.

  18. Interband resonant transitions in two-dimensional hexagonal lattices: Rabi oscillations, Zener tunnelling, and tunnelling of phase dislocations.

    PubMed

    Shchesnovich, Valery S; Desyatnikov, Anton S; Kivshar, Yuri S

    2008-09-01

    We study, analytically and numerically, the dynamics of interband transitions in two-dimensional hexagonal periodic photonic lattices. We develop an analytical approach employing the Bragg resonances of different types and derive the effective multi-level models of the Landau-Zener-Majorana type. For two-dimensional periodic potentials without a tilt, we demonstrate the possibility of the Rabi oscillations between the resonant Fourier amplitudes. In a biased lattice, i.e., for a two-dimensional periodic potential with an additional linear tilt, we identify three basic types of the interband transitions or Zener tunnelling. First, this is a quasi-one-dimensional tunnelling that involves only two Bloch bands and occurs when the Bloch index crosses the Bragg planes away from one of the high-symmetry points. In contrast, at the high-symmetry points (i.e., at the M and Gamma points), the Zener tunnelling is essentially two-dimensional, and it involves either three or six Bloch bands being described by the corresponding multi-level Landau-Zener-Majorana systems. We verify our analytical results by numerical simulations and observe an excellent agreement. Finally, we show that phase dislocations, or optical vortices, can tunnel between the spectral bands preserving their topological charge. Our theory describes the propagation of light beams in fabricated or optically-induced two-dimensional photonic lattices, but it can also be applied to the physics of cold atoms and Bose-Einstein condensates tunnelling in tilted two-dimensional optical potentials and other types of resonant wave propagation in periodic media.

  19. Evolution of lattice dynamics in ferroelectric hexagonal REInO3 (RE = Ho, Dy, Tb, Gd, Eu, Sm) perovskites

    NASA Astrophysics Data System (ADS)

    Paul, Barnita; Chatterjee, Swastika; Gop, Sumana; Roy, Anushree; Grover, Vinita; Shukla, Rakesh; Tyagi, A. K.

    2016-07-01

    Rare-earth indates emerge as one of the efficient geometric ferroelectric materials, in which the spontaneous polarization can be tuned by varying their crystal structure along the 4f rare-earth series. We report a systematic study of structural changes in hexagonal REInO3 perovskite (RE = Ho3+, Dy3+, Tb3+, Gd3+, Eu3+, Sm3+) and YInO3 of P63 cm space group by powder x-ray diffraction (XRD) and Raman scattering measurements. The crystal structure of these materials could be investigated by the Rietveld refinement of their XRD patterns. We have calculated density of states of phonons using density functional theory and examined the atomic displacements corresponding to observed Raman modes. The evolution of lattice dynamics of REInO3 has been probed by correlating various Raman modes with the structural distortion of the unit cell and the characteristics of the rare-earth ions. We report the appearance of the coupled mode in the phonon spectra. We have estimated spontaneous polarization from the structural distortion in this system and shown that it can be modulated by varying RE3+ ions in REInO3. We also report the appearance of a ferroelectric soft Raman mode, a unique characteristic of these materials.

  20. Photonic band gap in an imperfect atomic diamond lattice: Penetration depth and effects of finite size and vacancies

    NASA Astrophysics Data System (ADS)

    Antezza, Mauro; Castin, Yvan

    2013-09-01

    We study the effects of finite size and of vacancies on the photonic band gap recently predicted for an atomic diamond lattice. Close to a Jg=0→Je=1 atomic transition, and for atomic lattices containing up to N≈3×104 atoms, we show how the density of states can be affected by both the shape of the system and the possible presence of a fraction of unoccupied lattice sites. We numerically predict and theoretically explain the presence of shape-induced border states and of vacancy-induced localized states appearing in the gap. We also investigate the penetration depth of the electromagnetic field which we compare to the case of an infinite system.

  1. Phase stability and magnetic behavior of hexagonal phase of N2-O2 system with kagome lattice under high pressure and low temperature

    NASA Astrophysics Data System (ADS)

    Akahama, Y.; Ishihara, D.; Yamashita, H.; Fujihisa, H.; Hirao, N.; Ohishi, Y.

    2016-08-01

    The pressure-temperature (P -T ) phase diagram of N2-O2 mixture with a composition of N2-48 mol % O2 has been investigated using x-ray diffraction and the phase stability of a hexagonal phase (space group: P 6 /mmm), with the kagome lattice examined under high-pressure and low-temperature conditions. While the phase appears as a low-temperature phase of the cubic phase (P m 3 n ) with the structure of γ -O2 or δ -N2 and is stable in a wide range of pressures and temperatures, it transforms to lower symmetry monoclinic or orthorhombic phases at lower temperature, accompanied with a distortion of the kagome lattice. Based on Rietveld refinements, the monoclinic and orthorhombic phases are found to be in the P 21/a and Cmmm space groups, respectively. In magnetization measurements, a magnetic transition is observed with a relatively large drop of magnetization, corresponding to the cubic-to-hexagonal phase transition. This suggests that the hexagonal phase has a certain magnetic ordered state that arises from the molecular magnetic moment of O2.

  2. Persistent current and Drude weight of one-dimensional interacting fermions on imperfect ring from current lattice density functional theory

    NASA Astrophysics Data System (ADS)

    Akande, Akinlolu; Sanvito, Stefano

    2016-11-01

    We perform a numerical study of interacting one-dimensional Hubbard rings with a single impurity potential and pierced by a magnetic flux. Our calculations are carried out at the level of current lattice density functional theory (CLDFT) for the Hubbard model and compared to known results obtained in the thermodynamical limit from the Bethe ansatz. In particular, we investigate the effects of disorder and Coulomb interaction on the persistent current (PC) and the Drude weight. It is found that CLDFT is able to accurately describe qualitative and quantitative features of these ground state properties in the presence of disorder and electronic interaction. When the impurity potential is switched off, the CLDFT approach describes well the velocity of the Luttinger liquid excitations as a function of both interaction strength and electron filling. Then, when the impurity scattering potential is finite, we find the PC to vanish as {{L}-{{α\\text{B}}-1}} for large L and independent on the strength of the scattering potential, in good agreement with Luttinger liquid theory.

  3. The Influence of Lattice Imperfections on the Chemical Reactivity of Solids. The Growth, Perfection and Defect Properties of PETN (Pentaerythritol Tetranitrate) and RDX (Cyclotrimethylene Trinitramine) Single Crystals. Part 2.

    DTIC Science & Technology

    1984-02-01

    RD-A1i~ 272 THE INFLUENCE OF LATTICE IMPERFECTIONS ON THE CHEMICAL i REACTIVITY OF SOI (U) UNIVERSITY OF STRATHCLYDE GLASGOW (SCOTLAND) DEPT OF PURE...M251 11111 MICROCOPY RESOLUTION TEST CHART NATIONAL BUREAU OF STANDARDS 1963-A THE INFLUENCE O ATC MEFCIN ON THE CHEMICAL REACTIVITY OF SOLIDS o. THE...on the Chemical Reactivity of Solids. FINAL TECHNICAL ". PERFORMING ORG. REPORT NUMBER 7. AUTHOR(.) S. CONTRACT OR GRANT NUMUER(i,) J. N. Sherwood

  4. Graphene as a hexagonal 2-lattice: Evaluation of the in-plane material constants for the linear theory. A multiscale approach

    SciTech Connect

    Sfyris, D. E-mail: dsfyris@sfyris.net; Koukaras, E. N.; Pugno, N.; Galiotis, C.

    2015-08-21

    Continuum modeling of free-standing graphene monolayer, viewed as a two dimensional 2-lattice, requires specification of the components of the shift vector that acts as an auxiliary variable. If only in-plane motions are considered, the energy depends on an in-plane strain measure and the shift vector. The assumption of geometrical and material linearity leads to quadratic energy terms with respect to the shift vector, the strain tensor, and their combinations. Graphene's hexagonal symmetry reduces the number of independent moduli then to four. We evaluate these four material parameters using molecular calculations and the adaptive intermolecular reactive empirical bond order potential and compare them with standard linear elastic constitutive modeling. The results of our calculations show that the predicted values are in reasonable agreement with those obtained solely from our molecular calculations as well as those from the literature. To the best of our knowledge, this is the first attempt to measure mechanical properties when graphene is modeled as a hexagonal 2-lattice. This work targets at the continuum scale when the insight measurements come from finer scales using atomistic simulations.

  5. An sd(2) hybridized transition-metal monolayer with a hexagonal lattice: reconstruction between the Dirac and kagome bands.

    PubMed

    Zhou, Baozeng; Dong, Shengjie; Wang, Xiaocha; Zhang, Kailiang; Mi, Wenbo

    2017-03-15

    Graphene-like two-dimensional materials have garnered tremendous interest as emerging device materials due to their remarkable properties. However, their applications in spintronics have been limited by the lack of intrinsic magnetism. Here, we perform an ab initio simulation on the structural and electronic properties of several transition-metal (TM) monolayers (TM = Cr, Mo and W) with a honeycomb lattice on a 1/3 monolayer Cl-covered Si(111) surface. Due to the template effect from the halogenated Si substrate, the TM-layers will be maintained in an expanded lattice which is nearly 60% larger than that of the freestanding case. All these isolated TM-layers exhibit ferromagnetic coupling with kagome band structures related to sd(2) hybridization and a strong interfacial interaction may destroy the topological bands. Interestingly, the W-monolayer on the Cl-covered Si substrate shows a half-metallic behavior. A Dirac point formed at the K point in the spin-down channel is located exactly at the Fermi level which is crucial for the realization of a quantum spin Hall state. Moreover, the reconstruction process between the Dirac and kagome bands is discussed in detail, providing an interesting platform to study the interplay between massless Dirac fermions and heavy fermions.

  6. Unconventional Transport of Spin Bipolarons on an Antiferromagnetic buckled hexagonal lattice of half-filled d-band Mn2+ ions

    NASA Astrophysics Data System (ADS)

    Thorsmolle, Verner; Ignatov, Alexander; Pezzoli, Maria; Haule, Kristjan; Kolchmeyer, David; Lee, Alexander; Simonson, Jack; Aronson, Meigan; Blumberg, Girsh

    2013-03-01

    CaMn2Sb2 presents a magnetic system with a buckled hexagonal lattice of half-filled d-band Mn2+ ions. AC resistivity and susceptibility exhibit non-monotonic temperature dependence at 85-210 K. Below 85 K it has an antiferromagnetic (AF) phase with an activation energy of 28 meV, and above 210 K a paramagnetic phase. Using Raman spectroscopy we find a mode at 32 meV which develops below the AF transition. We attribute this excitation to the activation energy associated with the motion of spin bipolarons. Here, hybridization between Sb and Mn results in extra electrons for the Mn 3 d-shells. It is energetically favorable for these extra carriers to form spin-singlets. These spin-bipolarons cover two Mn sites with a binding energy of ~80 meV and conduction proceed via photo-assisted hopping with an activation energy of ~32 meV. This spin bipolaron model explains the spectroscopic features providing a self-consistent picture of this conductivity mechanism that also clarifies reported unusual temperature-dependent magnetic and transport data. VKT, AI, DK, AL and GB acknowledge support by NSF DMR-1104884 and by U.S. DOE, Office of BES, Award DE-SC0005463. MEP and JWS acknowledge support by NSSEFF, administrative by the AFOSR.

  7. AN INVESTIGATION OF CRYSTAL IMPERFECTIONS BY X-RAY DIFFRACTION.

    DTIC Science & Technology

    Lattice imperfections studied include dislocations, inclusions, precipitates, impurity layers, and fault surfaces such as stacking faults and twin ... boundaries . Both the direction and sense of dislocation Burgers vectors can be determined. Studies performed on natural diamond include the origin of

  8. Localization oscillation in antidot lattices

    NASA Astrophysics Data System (ADS)

    Uryu, S.; Ando, T.

    1998-06-01

    The Anderson localization in square and hexagonal antidot lattices is numerically studied with the use of a Thouless number method. It is revealed that localization is very sensitive to the aspect ratio between the antidot diameter and the lattice constant. In a hexagonal lattice, both the Thouless number and the localization length oscillate with the period equal to the Al’tshuler-Aronov-Spivak oscillation. The oscillation is quite weak in a square lattice.

  9. Imperfection Insensitive Thin Shells

    NASA Astrophysics Data System (ADS)

    Ning, Xin

    The buckling of axially compressed cylindrical shells and externally pressurized spherical shells is extremely sensitive to even very small geometric imperfections. In practice this issue is addressed by either using overly conservative knockdown factors, while keeping perfect axial or spherical symmetry, or adding closely and equally spaced stiffeners on shell surface. The influence of imperfection-sensitivity is mitigated, but the shells designed from these approaches are either too heavy or very expensive and are still sensitive to imperfections. Despite their drawbacks, these approaches have been used for more than half a century. This thesis proposes a novel method to design imperfection-insensitive cylindrical shells subject to axial compression. Instead of following the classical paths, focused on axially symmetric or high-order rotationally symmetric cross-sections, the method in this thesis adopts optimal symmetry-breaking wavy cross-sections (wavy shells). The avoidance of imperfection sensitivity is achieved by searching with an evolutionary algorithm for smooth cross-sectional shapes that maximize the minimum among the buckling loads of geometrically perfect and imperfect wavy shells. It is found that the shells designed through this approach can achieve higher critical stresses and knockdown factors than any previously known monocoque cylindrical shells. It is also found that these shells have superior mass efficiency to almost all previously reported stiffened shells. Experimental studies on a design of composite wavy shell obtained through the proposed method are presented in this thesis. A method of making composite wavy shells and a photogrametry technique of measuring full-field geometric imperfections have been developed. Numerical predictions based on the measured geometric imperfections match remarkably well with the experiments. Experimental results confirm that the wavy shells are not sensitive to imperfections and can carry axial compression

  10. Hexagonal tessellations in image algebra

    NASA Astrophysics Data System (ADS)

    Eberly, David H.; Wenzel, Dennis J.; Longbotham, Harold G.

    1990-11-01

    In image algebra '' the concept of a coordinate set X is general in that such a set is simply a subset of ndimensional Euclidean space . The standard applications in 2-dimensional image processing use coordinate sets which are rectangular arrays X 72 x ZZm. However some applications may require other geometries for the coordinate set. We look at three such related applications in the context of image algebra. The first application is the modeling of photoreceptors in primate retinas. These receptors are inhomogeneously distributed on the retina. The largest receptor density occurs in the center of the fovea and decreases radially outwards. One can construct a hexagonal tessellation of the retina such that each hexagon contains approximately the same number of receptors. The resulting tessellation called a sunflower heart2 consists of concentric rings of hexagons whose sizes increase as the radius of the ring increases. The second application is the modeling of the primary visual . The neurons are assumed to be uniformly distributed as a regular hexagonal lattice. Cortical neural image coding is modeled by a recursive convolution of the retinal neural image using a special set of filters. The third application involves analysis of a hexagonally-tessellated image where the pixel resolution is variable .

  11. An orthogonal oriented quadrature hexagonal image pyramid

    NASA Technical Reports Server (NTRS)

    Watson, Andrew B.; Ahumada, Albert J., Jr.

    1987-01-01

    An image pyramid has been developed with basis functions that are orthogonal, self-similar, and localized in space, spatial frequency, orientation, and phase. The pyramid operates on a hexagonal sample lattice. The set of seven basis functions consist of three even high-pass kernels, three odd high-pass kernels, and one low-pass kernel. The three even kernels are identified when rotated by 60 or 120 deg, and likewise for the odd. The seven basis functions occupy a point and a hexagon of six nearest neighbors on a hexagonal sample lattice. At the lowest level of the pyramid, the input lattice is the image sample lattice. At each higher level, the input lattice is provided by the low-pass coefficients computed at the previous level. At each level, the output is subsampled in such a way as to yield a new hexagonal lattice with a spacing sq rt 7 larger than the previous level, so that the number of coefficients is reduced by a factor of 7 at each level. The relationship between this image code and the processing architecture of the primate visual cortex is discussed.

  12. Learning with imperfectly labeled patterns

    NASA Technical Reports Server (NTRS)

    Chittineni, C. B.

    1979-01-01

    The problem of learning in pattern recognition using imperfectly labeled patterns is considered. The performance of the Bayes and nearest neighbor classifiers with imperfect labels is discussed using a probabilistic model for the mislabeling of the training patterns. Schemes for training the classifier using both parametric and non parametric techniques are presented. Methods for the correction of imperfect labels were developed. To gain an understanding of the learning process, expressions are derived for success probability as a function of training time for a one dimensional increment error correction classifier with imperfect labels. Feature selection with imperfectly labeled patterns is described.

  13. Imperfect Dark Matter

    SciTech Connect

    Mirzagholi, Leila; Vikman, Alexander E-mail: alexander.vikman@lmu.de

    2015-06-01

    We consider cosmology of the recently introduced mimetic matter with higher derivatives (HD). Without HD this system describes irrotational dust—Dark Matter (DM) as we see it on cosmologically large scales. DM particles correspond to the shift-charges—Noether charges of the shifts in the field space. Higher derivative corrections usually describe a deviation from the thermodynamical equilibrium in the relativistic hydrodynamics. Thus we show that mimetic matter with HD corresponds to an imperfect DM which: i) renormalises the Newton's constant in the Friedmann equations, ii) has zero pressure when there is no extra matter in the universe, iii) survives the inflationary expansion which puts the system on a dynamical attractor with a vanishing shift-charge, iv) perfectly tracks any external matter on this attractor, v) can become the main (and possibly the only) source of DM, provided the shift-symmetry in the HD terms is broken during some small time interval in the radiation domination époque. In the second part of the paper we present a hydrodynamical description of general anisotropic and inhomogeneous configurations of the system. This imperfect mimetic fluid has an energy flow in the field's rest frame. We find that in the Eckart and in the Landau-Lifshitz frames the mimetic fluid possesses nonvanishing vorticity appearing already at the first order in the HD. Thus, the structure formation and gravitational collapse should proceed in a rather different fashion from the simple irrotational DM models.

  14. Hexagons of the Heart

    ERIC Educational Resources Information Center

    Burkhauser, Beth; Porter, Dave

    2010-01-01

    This article discusses the international interdependence Hexagon Project for Haiti which invites students, ages five through eighteen, to create an image within a hexagonal template and respond to big questions surrounding a global culture of interdependence. The hexagon is a visual metaphor for interdependence, with its potential to infinitely…

  15. Study of lattice defect vibration

    NASA Technical Reports Server (NTRS)

    Elliott, R. J.

    1969-01-01

    Report on the vibrations of defects in crystals relates how defects, well localized in a crystal but interacting strongly with the other atoms, change the properties of a perfect crystal. The methods used to solve defect problems relate the properties of an imperfect lattice to the properties of a perfect lattice.

  16. Insertion of lattice strains into ordered LiNi0.5Mn1.5O4 spinel by mechanical stress: A comparison of perfect versus imperfect structures as a cathode for Li-ion batteries

    NASA Astrophysics Data System (ADS)

    Kozawa, Takahiro; Murakami, Takeshi; Naito, Makio

    2016-07-01

    The Ni-doped lithium manganese oxide, LiNi0.5Mn1.5O4, has received much attention as a cathode active material in high-energy lithium-ion batteries (LIBs). This active material has two different spinel structures depending on the ordering state of the Ni and Mn ions. The ordered LiNi0.5Mn1.5O4 spinel has an inferior cathode performance than the disordered phase because of its poor electronic conductivity. However, the ordered LiNi0.5Mn1.5O4 spinel possesses the potential advantage of avoiding dissolution of the Mn ion, which is an issue for the disordered spinel. The improvement of cathode performance is important for future applications. Here, we report a unique approach to improve the cathode performance of the ordered LiNi0.5Mn1.5O4 spinel. The mechanical treatment using an attrition-type mill successfully inserted lattice strains into the ordered LiNi0.5Mn1.5O4 spinel structure without a phase transformation to the disordered phase. The insertion of lattice strains by mechanical stresses provided an increased discharge capacity and a decreased charge transfer resistance. This limited crystal structure modification improved the cathode performance. The present work has the potential for application of the mechanically treated ordered LiNi0.5Mn1.5O4 spinel as a cathode for high-energy LIBs.

  17. A new hexagonal carbon nitride synthesized at high pressure and high temperature

    NASA Astrophysics Data System (ADS)

    Sougawa, Masaya; Shima, Yuta; Hirai, Masaaki; Takarabe, Kenichi; Okada, Taku; InstituteSolid State Physics, University of Tokyo Collaboration

    2013-06-01

    A new hexagonal carbon nitride has been synthesized by subjecting the C3N4Hxprecursor to high pressure and high temperature. The XRD pattern of the new hexagonal carbon nitride is indexed as the hexagonal unit cell with the lattice parameters; a = b = 2.83 Å, c = 9.82 Å (V = 68.10 Å3) . The unit cell of this new hexagonal carbon nitride differs from the several hexagonal carbon nitrides reported so far by the theoretical and experimental studies. Hart et al. proposed the hexagonal CN structure with 1:1 stoichiometry is based on the known GaSe layer with the unit cell parameters of the hexagonal unit a = b = 2.37 Å, c = 11.38 Å (V = 55.36 Å3) , respectively, and the space group is P63/mmc. Bojdys et al. synthesized the graphitic-C3N4 (g-C3N4) with the hexagonal unit cell with the lattice parameters; a = b = 8.43 Å, c = 6.72 Å (V = 414.09 Å3) , and the space group is P63cm. These reported hexagonal lattice constants disagree with the new hexagonal carbon nitrides synthesized in this report. We will report the full analysis of the crystal structure of the new hexagonal carbon nitride at the conference.

  18. Hexagon solar power panel

    DOEpatents

    Rubin, Irwin

    1978-01-01

    A solar energy panel comprises a support upon which silicon cells are arrayed. The cells are wafer thin and of two geometrical types, both of the same area and electrical rating, namely hexagon cells and hourglass cells. The hourglass cells are composites of half hexagons. A near perfect nesting relationship of the cells achieves a high density packing whereby optimum energy production per panel area is achieved.

  19. Hexagon solar power panel

    NASA Technical Reports Server (NTRS)

    Rubin, I. (Inventor)

    1978-01-01

    A solar energy panel support is described upon which silicon cells are arrayed. The cells are wafer thin and of two geometrical types, both of the same area and electrical rating, namely hexagon cells and hourglass cells. The hourglass cells are composites of half hexagons. A near perfect nesting relationship of the cells achieves a high density packing whereby optimum energy production per panel area is achieved.

  20. Macromolecular diffractive imaging using imperfect crystals

    PubMed Central

    Ayyer, Kartik; Yefanov, Oleksandr; Oberthür, Dominik; Roy-Chowdhury, Shatabdi; Galli, Lorenzo; Mariani, Valerio; Basu, Shibom; Coe, Jesse; Conrad, Chelsie E.; Fromme, Raimund; Schaffer, Alexander; Dörner, Katerina; James, Daniel; Kupitz, Christopher; Metz, Markus; Nelson, Garrett; Lourdu Xavier, Paulraj; Beyerlein, Kenneth R.; Schmidt, Marius; Sarrou, Iosifina; Spence, John C. H.; Weierstall, Uwe; White, Thomas A.; Yang, Jay-How; Zhao, Yun; Liang, Mengning; Aquila, Andrew; Hunter, Mark S.; Robinson, Joseph S.; Koglin, Jason E.; Boutet, Sébastien; Fromme, Petra; Barty, Anton; Chapman, Henry N.

    2016-01-01

    The three-dimensional structures of macromolecules and their complexes are predominantly elucidated by X-ray protein crystallography. A major limitation is access to high-quality crystals, to ensure X-ray diffraction extends to sufficiently large scattering angles and hence yields sufficiently high-resolution information that the crystal structure can be solved. The observation that crystals with shrunken unit-cell volumes and tighter macromolecular packing often produce higher-resolution Bragg peaks1,2 hints that crystallographic resolution for some macromolecules may be limited not by their heterogeneity but rather by a deviation of strict positional ordering of the crystalline lattice. Such displacements of molecules from the ideal lattice give rise to a continuous diffraction pattern, equal to the incoherent sum of diffraction from rigid single molecular complexes aligned along several discrete crystallographic orientations and hence with an increased information content3. Although such continuous diffraction patterns have long been observed—and are of interest as a source of information about the dynamics of proteins4 —they have not been used for structure determination. Here we show for crystals of the integral membrane protein complex photosystem II that lattice disorder increases the information content and the resolution of the diffraction pattern well beyond the 4.5 Å limit of measurable Bragg peaks, which allows us to directly phase5 the pattern. With the molecular envelope conventionally determined at 4.5 Å as a constraint, we then obtain a static image of the photosystem II dimer at 3.5 Å resolution. This result shows that continuous diffraction can be used to overcome long-supposed resolution limits of macromolecular crystallography, with a method that puts great value in commonly encountered imperfect crystals and opens up the possibility for model-free phasing6,7. PMID:26863980

  1. Macromolecular diffractive imaging using imperfect crystals

    NASA Astrophysics Data System (ADS)

    Ayyer, Kartik; Yefanov, Oleksandr M.; Oberthür, Dominik; Roy-Chowdhury, Shatabdi; Galli, Lorenzo; Mariani, Valerio; Basu, Shibom; Coe, Jesse; Conrad, Chelsie E.; Fromme, Raimund; Schaffer, Alexander; Dörner, Katerina; James, Daniel; Kupitz, Christopher; Metz, Markus; Nelson, Garrett; Xavier, Paulraj Lourdu; Beyerlein, Kenneth R.; Schmidt, Marius; Sarrou, Iosifina; Spence, John C. H.; Weierstall, Uwe; White, Thomas A.; Yang, Jay-How; Zhao, Yun; Liang, Mengning; Aquila, Andrew; Hunter, Mark S.; Robinson, Joseph S.; Koglin, Jason E.; Boutet, Sébastien; Fromme, Petra; Barty, Anton; Chapman, Henry N.

    2016-02-01

    The three-dimensional structures of macromolecules and their complexes are mainly elucidated by X-ray protein crystallography. A major limitation of this method is access to high-quality crystals, which is necessary to ensure X-ray diffraction extends to sufficiently large scattering angles and hence yields information of sufficiently high resolution with which to solve the crystal structure. The observation that crystals with reduced unit-cell volumes and tighter macromolecular packing often produce higher-resolution Bragg peaks suggests that crystallographic resolution for some macromolecules may be limited not by their heterogeneity, but by a deviation of strict positional ordering of the crystalline lattice. Such displacements of molecules from the ideal lattice give rise to a continuous diffraction pattern that is equal to the incoherent sum of diffraction from rigid individual molecular complexes aligned along several discrete crystallographic orientations and that, consequently, contains more information than Bragg peaks alone. Although such continuous diffraction patterns have long been observed—and are of interest as a source of information about the dynamics of proteins—they have not been used for structure determination. Here we show for crystals of the integral membrane protein complex photosystem II that lattice disorder increases the information content and the resolution of the diffraction pattern well beyond the 4.5-ångström limit of measurable Bragg peaks, which allows us to phase the pattern directly. Using the molecular envelope conventionally determined at 4.5 ångströms as a constraint, we obtain a static image of the photosystem II dimer at a resolution of 3.5 ångströms. This result shows that continuous diffraction can be used to overcome what have long been supposed to be the resolution limits of macromolecular crystallography, using a method that exploits commonly encountered imperfect crystals and enables model-free phasing.

  2. Why Hexagonal Basalt Columns?

    PubMed

    Hofmann, Martin; Anderssohn, Robert; Bahr, Hans-Achim; Weiß, Hans-Jürgen; Nellesen, Jens

    2015-10-09

    Basalt columns with their preferably hexagonal cross sections are a fascinating example of pattern formation by crack propagation. Junctions of three propagating crack faces rearrange such that the initial right angles between them tend to approach 120°, which enables the cracks to form a pattern of regular hexagons. To promote understanding of the path on which the ideal configuration can be reached, two periodically repeatable models are presented here involving linear elastic fracture mechanics and applying the principle of maximum energy release rate. They describe the evolution of the crack pattern as a transition from rectangular start configuration to the hexagonal pattern. This is done analytically and by means of three-dimensional finite element simulation. The latter technique reproduces the curved crack path involved in this transition.

  3. Comparison of microfabricated hexagonal and lamellar post arrays for DNA electrophoresis

    PubMed Central

    Chen, Zhen; Dorfman, Kevin D.

    2014-01-01

    We used Brownian dynamics simulations to compare DNA separations in microfabricated post arrays containing either hexagonal or lamellar lattices. Contrary to intuition, dense hexagonal arrays with frequent DNA-post collisions do not yield the optimal separation. Rather, hexagonal arrays with pore sizes commensurate with the radius of gyration of the DNA lead to increased separation resolution due to a molecular-weight dependent collision probability that increases with molecular weight. However, when the hexagonal array is too sparse, this advantage is lost due to the low number of collisions. Lamellar lattices, such as the DNA nanofence, appear to be superior to a hexagonal array at the same post density, since the lamellar lattice combines regions for DNA relaxation with locally dense post regions for collisions. The relative advantages of different post array designs are explained in terms of the statistics for the number of collisions and the holdup time, providing guidelines for designing post arrays for separating long DNA. PMID:24132597

  4. Two-dimensional electrostatic lattices for indirect excitons

    NASA Astrophysics Data System (ADS)

    Remeika, M.; Fogler, M. M.; Butov, L. V.; Hanson, M.; Gossard, A. C.

    2012-02-01

    We report on a method for the realization of two-dimensional electrostatic lattices for excitons using patterned interdigitated electrodes. Lattice structure is set by the electrode pattern and depth of the lattice potential is controlled by applied voltages. We demonstrate square, hexagonal, and honeycomb lattices created by this method.

  5. Hexagonal quartz resonator

    DOEpatents

    Peters, Roswell D. M.

    1982-01-01

    A generally flat, relatively thin AT-cut piezoelectric resonator element structured to minimize the force-frequency effect when mounted and energized in a housing. The resonator is in the form of an equilateral hexagon with the X crystallographic axis of the crystal passing through one set of opposing corners with mounting being effected at an adjacent set of corners respectively .+-.60.degree. away from the X axis which thereby results in a substantially zero frequency shift of the operating frequency.

  6. Dynamics of wet granular hexagons

    NASA Astrophysics Data System (ADS)

    Baur, Manuel; Huang, Kai

    2017-03-01

    The collective behavior of vibrated hexagonal disks confined in a monolayer is investigated experimentally. Due to the broken circular symmetry, hexagons prefer to rotate upon sufficiently strong driving. Due to the formation of liquid bridges, short-ranged cohesive interactions are introduced upon wetting. Consequently, a nonequilibrium stationary state with the rotating disks self-organized in a hexagonal structure arises. The bond length of the hexagonal structure is slightly smaller than the circumdiameter of a hexagon, indicating geometric frustration. This investigation provides an example where the collective behavior of granular matter is tuned by the shape of individual particles.

  7. Hexagonalization of correlation functions

    NASA Astrophysics Data System (ADS)

    Fleury, Thiago; Komatsu, Shota

    2017-01-01

    We propose a nonperturbative framework to study general correlation functions of single-trace operators in N = 4 supersymmetric Yang-Mills theory at large N . The basic strategy is to decompose them into fundamental building blocks called the hexagon form factors, which were introduced earlier to study structure constants using integrability. The decomposition is akin to a triangulation of a Riemann surface, and we thus call it hexagonalization. We propose a set of rules to glue the hexagons together based on symmetry, which naturally incorporate the dependence on the conformal and the R-symmetry cross ratios. Our method is conceptually different from the conventional operator product expansion and automatically takes into account multi-trace operators exchanged in OPE channels. To illustrate the idea in simple set-ups, we compute four-point functions of BPS operators of arbitrary lengths and correlation functions of one Konishi operator and three short BPS operators, all at one loop. In all cases, the results are in perfect agreement with the perturbative data. We also suggest that our method can be a useful tool to study conformal integrals, and show it explicitly for the case of ladder integrals.

  8. Mechanism of the body-centered cubic--hexagonal close-packed phase transition in iron.

    PubMed

    Bassett, W A; Huang, E

    1987-11-06

    The transition from body-centered cubic to hexagonal close-packed phase in iron has been studied in a diamond anvil cell with synchrotron radiation. The hexagonal close-packed phase, when it first appears, has a ratio of lattice parameters that is significantly larger than normal. This is attributed to a displacive mechanism that causes a distortion of the hexagonal close-packed structure in a body-centered cubic matrix. The hexagonal close-packed phase adjacent to a boundary with the body-centered cubic phase is stretched in the c direction and compressed in the a direction when it first forms.

  9. A developmental perspective on the Imperfective Paradox.

    PubMed

    Kazanina, Nina; Phillips, Colin

    2007-10-01

    Imperfective or progressive verb morphology makes it possible to use the name of a whole event to refer to an activity that is clearly not a complete instance of that event, leading to what is known as the Imperfective Paradox. For example, a sentence like 'John was building a house' does not entail that a house ever got built. The Imperfective Paradox has received a number of different treatments in the philosophical and linguistic literature, but has received less attention from the perspective of language acquisition. This article presents developmental evidence on the nature of the Imperfective Paradox, based on a series of four experiments conducted with Russian-speaking 3 to 6 year olds. Despite the fact that Russian is a language in which the morphological form of imperfectives is highly salient and used appropriately at a very young age, younger children show a clearly non-adultlike pattern of comprehension in our experiments. The results from Experiments 1 and 2 suggest that Russian-speaking children incorrectly ascribe completion entailments to imperfectives. However, Experiments 3 and 4 indicate that the children recognize that imperfectives can describe incomplete events, and that their problem instead concerns their inability to find a suitable temporal interval against which to evaluate imperfective statements. Specifically, children are only willing to accept an imperfective predicate as a description of a past incomplete event when the sentence contains an explicit temporal modifier that highlights a time interval that ends before the failure point of the event. These findings are taken as support for an account of the imperfective that makes use of temporal perspectives in solving the Imperfective Paradox.

  10. Hexagonal quartz resonator

    DOEpatents

    Peters, R.D.M.

    1982-11-02

    A generally flat, relatively thin AT-cut piezoelectric resonator element structured to minimize the force-frequency effect when mounted and energized in a housing. The resonator is in the form of an equilateral hexagon with the X crystallographic axis of the crystal passing through one set of opposing corners with mounting being effected at an adjacent set of corners respectively [+-]60[degree] away from the X axis which thereby results in a substantially zero frequency shift of the operating frequency. 3 figs.

  11. Buckling of conical shell with local imperfections

    NASA Technical Reports Server (NTRS)

    Cooper, P. A.; Dexter, C. B.

    1974-01-01

    Small geometric imperfections in thin-walled shell structures can cause large reductions in buckling strength. Most imperfections found in structures are neither axisymmetric nor have the shape of buckling modes but rather occur locally. This report presents the results of a study of the effect of local imperfections on the critical buckling load of a specific axially compressed thin-walled conical shell. The buckling calculations were performed by using a two-dimensional shell analysis program referred to as the STAGS (Structural Analysis of General Shells) computer code, which has no axisymmetry restrictions. Results show that the buckling load found from a bifurcation buckling analysis is highly dependent on the circumferential arc length of the imperfection type studied. As the circumferential arc length of the imperfection is increased, a reduction of up to 50 percent of the critical load of the perfect shell can occur. The buckling load of the cone with an axisymmetric imperfections is nearly equal to the buckling load of imperfections which extended 60 deg or more around the circumference, but would give a highly conservative estimate of the buckling load of a shell with an imperfection of a more local nature.

  12. A Developmental Perspective on the Imperfective Paradox

    ERIC Educational Resources Information Center

    Kazanina, Nina; Phillips, Colin

    2007-01-01

    Imperfective or progressive verb morphology makes it possible to use the name of a whole event to refer to an activity that is clearly not a complete instance of that event, leading to what is known as the Imperfective Paradox. For example, a sentence like "John was building a house" does not entail that a house ever got built. The Imperfective…

  13. The Discrete Fourier Transform on hexagonal remote sensing image

    NASA Astrophysics Data System (ADS)

    Li, Yalu; Ben, Jin; Wang, Rui; Du, Lingyu

    2016-11-01

    Global discrete grid system will subdivide the earth recursively to form a multi-resolution grid hierarchy with no Overlap and seamless which help build global uniform spatial reference datum and multi-source data processing mode which takes the position as the object and in the aspect of data structure supports the organization, process and analysis of the remote sensing big data. This paper adopts the base transform to realize the mutual transformation of square pixel and hexagonal pixel. This paper designs the corresponding discrete Fourier transform algorithm for any lattice. Finally, the paper show the result of the DFT of the remote sensing image of the hexagonal pixel.

  14. Shape-induced frustration of hexagonal order in polyhedral colloids.

    PubMed

    Dullens, Roel P A; Mourad, Maurice C D; Aarts, Dirk G A L; Hoogenboom, Jacob P; Kegel, Willem K

    2006-01-20

    The effect of a nonspherical particle shape and shape polydispersity on the structure of densely packed hard colloidal particles was studied in real space by confocal microscopy. We show that the first layer at the wall of concentrated size-monodisperse but shape-polydisperse polyhedral colloids exhibits significant deviations from a hexagonal lattice. These deviations are identified as bond-orientational fluctuations which lead to percolating "mismatch lines." While the shape-induced geometrical frustration of the hexagonal symmetry suppresses translational order, bond-orientational order is clearly retained, indicating a hexaticlike structure of the polyhedral colloids.

  15. Numerical study of localization in antidot lattices

    NASA Astrophysics Data System (ADS)

    Uryu, Seiji; Ando, Tsuneya

    1998-10-01

    Localization effects in antidot lattices in weak magnetic fields are numerically studied with the use of a Thouless-number method. In hexagonal antidot lattices, both conductance and inverse localization length oscillate as a function of a magnetic flux with the same period as an Al'tshuler-Aronov-Spivak oscillation, in qualitative agreement with recent experiments.

  16. Hexagonal Mirror Array

    NASA Technical Reports Server (NTRS)

    1999-01-01

    NASA's Space Optics Manufacturing Technology Center has been working to expand our view of the universe via sophisticated new telescopes. The Optics Center's goal is to develop low-cost, advanced space optics technologies for the NASA program in the 21st century, including the long-term goal of imaging Earth-like planets in distant solar systems. A segmented array of mirrors was designed by the Space Optics Manufacturing Technology Center for solar the concentrator test stand at the Marshall Space Flight Center (MSFC) for powering solar thermal propulsion engines. Each hexagon mirror has a spherical surface to approximate a parabolic concentrator when combined into the entire 18-foot diameter array. The aluminum mirrors were polished with a diamond turning machine, that creates a glass-like reflective finish on metal. The precision fabrication machinery at the Space Optics Manufacturing Technology Center at MSFC can polish specialized optical elements to a world class quality of smoothness. This image shows optics physicist, Vince Huegele, examining one of the 144-segment hexagonal mirrors of the 18-foot diameter array at the MSFC solar concentrator test stand.

  17. Hexagonal Mirror Array

    NASA Technical Reports Server (NTRS)

    1999-01-01

    NASA's Space Optics Manufacturing Technology Center has been working to expand our view of the universe via sophisticated new telescopes. The Optics Center's goal is to develop low-cost, advanced space optics technologies for the NASA program in the 21st century, including the long-term goal of imaging Earth-like planets in distant solar systems. A segmented array of mirrors was designed by the Space Optics Manufacturing Technology Center for the solar concentrator test stand at the Marshall Space Flight Center (MSFC) for powering solar thermal propulsion engines. Each hexagon mirror has a spherical surface to approximate a parabolic concentrator when combined into the entire 18-foot diameter array. The aluminum mirrors were polished with a diamond turning machine that creates a glass-like reflective finish on metal. The precision fabrication machinery at the Space Optics Manufacturing Technology Center at MSFC can polish specialized optical elements to a world class quality of smoothness. This image shows optics physicist, Vince Huegele, examining one of the 144-segment hexagonal mirrors of the 18-foot diameter array at the MSFC solar concentrator test stand.

  18. Enhanced physics design with hexagonal repeated structure tools using Monte Carlo methods

    SciTech Connect

    Carter, L L; Lan, J S; Schwarz, R A

    1991-01-01

    This report discusses proposed new missions for the Fast Flux Test Facility (FFTF) reactor which involve the use of target assemblies containing local hydrogenous moderation within this otherwise fast reactor. Parametric physics design studies with Monte Carlo methods are routinely utilized to analyze the rapidly changing neutron spectrum. An extensive utilization of the hexagonal lattice within lattice capabilities of the Monte Carlo Neutron Photon (MCNP) continuous energy Monte Carlo computer code is applied here to solving such problems. Simpler examples that use the lattice capability to describe fuel pins within a brute force'' description of the hexagonal assemblies are also given.

  19. Initial conditions for imperfect dark matter

    SciTech Connect

    Ramazanov, Sabir

    2015-12-01

    We discuss initial conditions for the recently proposed Imperfect Dark Matter (Modified Dust). We show that they are adiabatic under fairly moderate assumptions about the cosmological evolution of the Universe at the relevant times.

  20. Understanding Your Vision: The "Imperfect Eye"

    MedlinePlus

    ... Issues Feature: Vision Understanding Your Vision: The "Imperfect Eye" Past Issues / Summer 2008 Table of Contents For ... including an implanted set of lenses. "Keeping your eyes healthy means learning about them and the conditions ...

  1. Surface plasmon dispersion in hexagonal, honeycomb and kagome plasmonic crystals.

    PubMed

    Tenner, V T; de Dood, M J A; van Exter, M P

    2016-12-26

    We present a systematic experimental study on the optical properties of plasmonic crystals (PlC) with hexagonal symmetry. We compare the dispersion and avoided crossings of surface plasmon modes around the Γ-point of Au-metal hole arrays with a hexagonal, honeycomb and kagome lattice. Symmetry arguments and group theory are used to label the six modes and understand their radiative and dispersive properties. Plasmon-plasmon interaction are accurately described by a coupled mode model, that contains effective scattering amplitudes of surface plasmons on a lattice of air holes under 60°, 120°, and 180°. We determine these rates in the experiment and find that they are dominated by the hole-density and not on the complexity of the unit-cell. Our analysis shows that the observed angle-dependent scattering can be explained by a single-hole model based on electric and magnetic dipoles.

  2. Epitaxial Growth of Cubic Crystalline Semiconductor Alloys on Basal Plane of Trigonal or Hexagonal Crystal

    NASA Technical Reports Server (NTRS)

    Park, Yeonjoon (Inventor); Choi, Sang H. (Inventor); King, Glen C. (Inventor)

    2011-01-01

    Hetero-epitaxial semiconductor materials comprising cubic crystalline semiconductor alloys grown on the basal plane of trigonal and hexagonal substrates, in which misfit dislocations are reduced by approximate lattice matching of the cubic crystal structure to underlying trigonal or hexagonal substrate structure, enabling the development of alloyed semiconductor layers of greater thickness, resulting in a new class of semiconductor materials and corresponding devices, including improved hetero-bipolar and high-electron mobility transistors, and high-mobility thermoelectric devices.

  3. An Explanation for Saturn's Hexagon

    NASA Astrophysics Data System (ADS)

    Kohler, Susanna

    2015-08-01

    For over three decades, weve been gathering observations of the mysterious hexagonal cloud pattern encircling Saturns north pole. Now, researchers believe they have a model that can better explain its formation.Fascinating GeometrySaturns northern Hexagon is a cloud band circling Saturns north pole at 78 N, first observed by the Voyager flybys in 198081. This remarkable pattern has now persisted for more than a Saturn year (29.5 Earth years).Eight frames demonstrating the motion within Saturns Hexagon. Click to watch the animation! The view is from a reference frame rotating with Saturn. [NASA/JPL-Caltech/SSI/Hampton University]Observations by Voyager and, more recently, Cassini have helped to identify many key characteristics of this bizarre structure. Two interesting things weve learned are:The Hexagon is associated with an eastward zonal jet moving at more than 200 mph.The cause of the Hexagon is believed to be a jet stream, similar to the ones that we experience on Earth. The path of the jet itself appears to follow the hexagons outline.The Hexagon rotates at roughly the same rate as Saturns overall rotation.While we observe individual storms and cloud patterns moving at different speeds within the Hexagon, the vertices of the Hexagon move at almost exactly the same rotational speed as that of Saturn itself.Attempts to model the formation of the Hexagon with a jet stream have yet to fully reproduce all of the observed features and behavior. But now, a team led by Ral Morales-Juberas of the New Mexico Institute of Mining and Technology believes they have created a model that better matches what we see.Simulating a Meandering JetThe team ran a series of simulations of an eastward, Gaussian-profile jet around Saturns pole. They introduced small perturbations to the jet and demonstrated that, as a result of the perturbations, the jet can meander into a hexagonal shape. With the initial conditions of the teams model, the meandering jet is able to settle into a

  4. Gravitational focusing of imperfect dark matter

    NASA Astrophysics Data System (ADS)

    Babichev, Eugeny; Ramazanov, Sabir

    2017-01-01

    Motivated by the projectable Horava-Lifshitz model/mimetic matter scenario, we consider a particular modification of standard gravity, which manifests as an imperfect low pressure fluid. While practically indistinguishable from a collection of nonrelativistic weakly interacting particles on cosmological scales, it leaves drastically different signatures in the Solar system. The main effect stems from gravitational focusing of the flow of imperfect dark matter passing near the Sun. This entails strong amplification of imperfect dark matter energy density compared to its average value in the surrounding halo. The enhancement is many orders of magnitude larger than in the case of cold dark matter, provoking deviations of the metric in the second order in the Newtonian potential. Effects of gravitational focusing are prominent enough to substantially affect the planetary dynamics. Using the existing bound on the post-Newtonian parameter βPPN, we deduce a stringent constraint on the unique constant of the model.

  5. Predator cognition permits imperfect coral snake mimicry.

    PubMed

    Kikuchi, David W; Pfennig, David W

    2010-12-01

    Batesian mimicry is often imprecise. An underexplored explanation for imperfect mimicry is that predators might not be able to use all dimensions of prey phenotype to distinguish mimics from models and thus permit imperfect mimicry to persist. We conducted a field experiment to test whether or not predators can distinguish deadly coral snakes (Micrurus fulvius) from nonvenomous scarlet kingsnakes (Lampropeltis elapsoides). Although the two species closely resemble one another, the order of colored rings that encircle their bodies differs. Despite this imprecise mimicry, we found that L. elapsoides that match coral snakes in other respects are not under selection to match the ring order of their model. We suggest that L. elapsoides have evolved only those signals necessary to deceive predators. Generally, imperfect mimicry might suffice if it exploits limitations in predator cognitive abilities.

  6. Generic substitution, financial interests, and imperfect agency.

    PubMed

    Rischatsch, Maurus; Trottmann, Maria; Zweifel, Peter

    2013-06-01

    Policy makers around the world seek to encourage generic substitution. In this paper, the importance of prescribing physicians' imperfect agency is tested using the fact that some Swiss jurisdictions allow physicians to dispense drugs on their own account (physician dispensing, PD) while others disallow it. We estimate a model of physician drug choice with the help of drug claim data, finding a significant positive association between PD and the use of generics. While this points to imperfect agency, generics are prescribed more often to patients with high copayments or low incomes.

  7. Imperfect wetting of hydrogen in zeolite

    SciTech Connect

    Sullivan, N.S.; Rall, M.

    1995-11-01

    We have considered the theoretical dependencies of the amount of supercooling of liquid hydrogen as a function of pore size for constrained geometries in order to compare the different mechanisms for supercooling that can be observed: notably the inhibition of nucleation in small geometries and the use of surfaces for which there is imperfect wetting. Analysis of the dependence of the observed supercooling reported elsewhere for molecular hydrogen and hydrogen deuteride on the pore size in zeolites supports the view that imperfect wetting occurs for small pores that have rough surfaces and dimension less than approximately 10{angstrom}.

  8. Incentives for Cheating Given Imperfect Detection

    SciTech Connect

    Canavan, G.H.

    1998-10-01

    The incentives for cheating given imperfect detection can be discussed within the context of first strike stability. The cost reduction due to is balanced against the sanctions that would be imposed if cheating was detected. For small political sanctions, the optimum level is at high levels of cheating. For large sanctions, the optimum is at quite low levels, which discourages cheating.

  9. Liquid phase deposition synthesis of hexagonal molybdenum trioxide thin films

    SciTech Connect

    Deki, Shigehito; Beleke, Alexis Bienvenu; Kotani, Yuki; Mizuhata, Minoru

    2009-09-15

    Hexagonal molybdenum trioxide thin films with good crystallinity and high purity have been fabricated by the liquid phase deposition (LPD) technique using molybdic acid (H{sub 2}MoO{sub 4}) dissolved in 2.82% hydrofluoric acid (HF) and H{sub 3}BO{sub 3} as precursors. The crystal was found to belong to a hexagonal hydrate system MoO{sub 3}.nH{sub 2}O (napprox0.56). The unit cell lattice parameters are a=10.651 A, c=3.725 A and V=365.997 A{sup 3}. Scanning electron microscope (SEM) images of the as-deposited samples showed well-shaped hexagonal rods nuclei that grew and where the amount increased with increase in reaction time. X-ray photon electron spectroscopy (XPS) spectra showed a Gaussian shape of the doublet of Mo 3d core level, indicating the presence of Mo{sup 6+} oxidation state in the deposited films. The deposited films exhibited an electrochromic behavior by lithium intercalation and deintercalation, which resulted in coloration and bleaching of the film. Upon dehydration at about 450 deg. C, the hexagonal MoO{sub 3}.nH{sub 2}O was transformed into the thermodynamically stable orthorhombic phase. - Abstract: SEM photograph of typical h-MoO{sub 3}.nH{sub 2}O thin film nuclei obtained after 36 h at 40 deg. C by the LPD method. Display Omitted

  10. On the Structure of a New Superhard Hexagonal Carbon Phase

    NASA Astrophysics Data System (ADS)

    Zhang, Bin; Liang, Yongcheng; Guo, Zaoyang; Bordas, Stéphane

    2010-05-01

    Molecular dynamics simulations show that graphite will transform into a superhard phase under cold compression. Recent experiments show that there is a sp3-rich hexagonal carbon polymorph (a0 = 2.496 Å, c0 = 4.123 Å) with a bulk modulus of 447 GPa and average density about 3.6 g/cm3, restricted to the space group of P-62c (No. 190), but the detailed atomic structure was not obtained [Wang et al., P. Natl. Acad. Sci. 101(38), 13699]. Here we set carbon atoms occupying P-62c 4f Wyckoff positions of P-62c, and calculate the total energy of the different structures changing the internal parameter z by first-principles calculations using geometry optimisation algorithm in CASTEP code, which shows that the stable structures in energy (at local minimum points) are hexagonal carbon (z = 1/4) and hexagonal diamond (z = 1/16). The calculated mechanical properties and lattice parameters of the structure P-62c 4f (z = 1/4) are in good agreement with those of the new hexagonal carbon proposed by Wang et al., which indicates that the atomic structure is a possible candidate.

  11. Microcrystalline hexagonal tungsten bronze. 2. Dehydration dynamics.

    PubMed

    Luca, Vittorio; Griffith, Christopher S; Hanna, John V

    2009-07-06

    Low-temperature (25-600 degrees C) thermal transformations have been studied for hydrothermally prepared, microcrystalline hexagonal tungsten bronze (HTB) phases A(x)WO(3+x/2).zH(2)O as a function of temperature, where A is an exchangeable cation (in this case Na(+) or Cs(+)) located in hexagonal structural tunnels. Thermal treatment of the as-prepared sodium- and cesium-exchanged phases in air were monitored using a conventional laboratory-based X-ray diffractometer, while thermal transformations in vacuum were studied using synchrotron X-ray and neutron diffraction. Concurrent thermogravimetric, diffuse reflectance infrared (DRIFT), and (23)Na and (133)Cs magic angle spinning (MAS) NMR spectroscopic studies have also been undertaken. For the cesium variant, cell volume contraction occurred from room temperature to about 350 degrees C, the regime in which water was "squeezed" out of tunnel sites. This was followed by a lattice expansion in the 350-600 degrees C temperature range. Over the entire temperature range, a net thermal contraction was observed, and this was the result of an anisotropic change in the cell dimensions which included a shortening of the A-O2 bond length. These changes explain why Cs(+) ions are locked into tunnel positions at temperatures as low as 400 degrees C, subsequently inducing a significant reduction in Cs(+) extractability under low pH (nitric acid) conditions. The changing Cs(+) speciation as detected by (133)Cs MAS NMR showed a condensation from multiple Cs sites, presumably associated with differing modes of Cs(+) hydration in the tunnels, to a single Cs(+) environment upon thermal transformation and water removal. While similar lattice contraction was observed for the as-prepared sodium variant, the smaller radius of Na(+) caused it to be relatively easily removed with acid in comparison to the Cs(+) variant. From (23)Na MAS NMR studies of the parent material, complex Na(+) speciation was observed with dehydrated and various

  12. Imperfect chimera states for coupled pendula

    PubMed Central

    Kapitaniak, Tomasz; Kuzma, Patrycja; Wojewoda, Jerzy; Czolczynski, Krzysztof; Maistrenko, Yuri

    2014-01-01

    The phenomenon of chimera states in the systems of coupled, identical oscillators has attracted a great deal of recent theoretical and experimental interest. In such a state, different groups of oscillators can exhibit coexisting synchronous and incoherent behaviors despite homogeneous coupling. Here, considering the coupled pendula, we find another pattern, the so-called imperfect chimera state, which is characterized by a certain number of oscillators which escape from the synchronized chimera's cluster or behave differently than most of uncorrelated pendula. The escaped elements oscillate with different average frequencies (Poincare rotation number). We show that imperfect chimera can be realized in simple experiments with mechanical oscillators, namely Huygens clock. The mathematical model of our experiment shows that the observed chimera states are controlled by elementary dynamical equations derived from Newton's laws that are ubiquitous in many physical and engineering systems. PMID:25223296

  13. Observing Altshuler--Aronov--Spivak Oscillation in a Hexagonal Antidot Array of Monolayer Graphene

    NASA Astrophysics Data System (ADS)

    Yagi, Ryuta; Shimomura, Midori; Tahara, Fumiya; Kobara, Hiroaki; Fukada, Seiya

    2012-06-01

    We show that hexagonal antidot lattices of monolayer graphene exhibited the Altshuler--Aronov--Spivak (AAS) effect in low field magnetoresistance. In higher magnetic fields, Aharonov--Bohm-type oscillations were visible. The phase of AAS oscillation indicated that the chirality effect of graphene is suppressed because of inter-valley scattering due to boundary scatterings.

  14. Consistent perturbations in an imperfect fluid

    SciTech Connect

    Sawicki, Ignacy; Amendola, Luca; Saltas, Ippocratis D.; Kunz, Martin E-mail: i.saltas@sussex.ac.uk E-mail: martin.kunz@unige.ch

    2013-01-01

    We present a new prescription for analysing cosmological perturbations in a more-general class of scalar-field dark-energy models where the energy-momentum tensor has an imperfect-fluid form. This class includes Brans-Dicke models, f(R) gravity, theories with kinetic gravity braiding and generalised galileons. We employ the intuitive language of fluids, allowing us to explicitly maintain a dependence on physical and potentially measurable properties. We demonstrate that hydrodynamics is not always a valid description for describing cosmological perturbations in general scalar-field theories and present a consistent alternative that nonetheless utilises the fluid language. We apply this approach explicitly to a worked example: k-essence non-minimally coupled to gravity. This is the simplest case which captures the essential new features of these imperfect-fluid models. We demonstrate the generic existence of a new scale separating regimes where the fluid is perfect and imperfect. We obtain the equations for the evolution of dark-energy density perturbations in both these regimes. The model also features two other known scales: the Compton scale related to the breaking of shift symmetry and the Jeans scale which we show is determined by the speed of propagation of small scalar-field perturbations, i.e. causality, as opposed to the frequently used definition of the ratio of the pressure and energy-density perturbations.

  15. Status of the ATF2 Lattices

    SciTech Connect

    Marin, E.; Tomas, R.; Bambade, P.; Okugi, T.; Tauchi, T.; Terunuma, N.; Urakawa, J.; Seryi, A.; White, G.; Woodley, M.; /SLAC

    2011-12-09

    The current status for the ATF2 Nominal and Ultra-low {beta}* lattices are presented in this paper. New lattice designs have been obtained in order to minimise the impact of the last interpretation of multipole measurements that have been included into the model. However, the new ATF2 Ultra-low design is not able to recover the expected vertical beam size at the IP with the current magnet distribution. Therefore, different quadrupole sorting have been studied. A significant gain is evident for the ATF2 Ultra-low lattice when sorting the magnets according to the skew-sextupolar components. The ATF2 Nominal lattice is also expected to benefit from the new sorting. Tuning results of the new ATF2 Ultra-low lattice under realistic imperfections are also reported.

  16. Microstructural and crystallographic imperfections of MgB{sub 2} superconducting wire and their correlation with the critical current density

    SciTech Connect

    Shahabuddin, Mohammed; Alzayed, Nasser S.; Oh, Sangjun; Choi, Seyong; Maeda, Minoru; Hata, Satoshi; Shimada, Yusuke; Hossain, Md Shahriar Al; Kim, Jung Ho

    2014-01-15

    A comprehensive study of the effects of structural imperfections in MgB{sub 2} superconducting wire has been conducted. As the sintering temperature becomes lower, the structural imperfections of the MgB{sub 2} material are increased, as reflected by detailed X-ray refinement and the normal state resistivity. The crystalline imperfections, caused by lattice disorder, directly affect the impurity scattering between the π and σ bands of MgB{sub 2}, resulting in a larger upper critical field. In addition, low sintering temperature keeps the grain size small, which leads to a strong enhancement of pinning, and thereby, enhanced critical current density. Owing to both the impurity scattering and the grain boundary pinning, the critical current density, irreversibility field, and upper critical field are enhanced. Residual voids or porosities obviously remain in the MgB{sub 2}, however, even at low sintering temperature, and thus block current transport paths.

  17. Thermal stability of hexagonal OsB{sub 2}

    SciTech Connect

    Xie, Zhilin; Blair, Richard G.; Orlovskaya, Nina; Cullen, David A.; Andrew Payzant, E.

    2014-11-15

    The synthesis of novel hexagonal ReB{sub 2}-type OsB{sub 2} ceramic powder was performed by high energy ball milling of elemental Os and B powders. Two different sources of B powder have been used for this mechanochemical synthesis. One B powder consisted of a mixture of amorphous and crystalline phases and a mixture of {sup 10}B and {sup 11}B isotopes with a fine particle size, while another B powder was a purely crystalline (rhombohedral) material consisting of enriched {sup 11}B isotope with coarse particle size. The same Os powder was used for the synthesis in both cases. It was established that, in the first case, the hexagonal OsB{sub 2} phase was the main product of synthesis with a small quantity of Os{sub 2}B{sub 3} phase present after synthesis as an intermediate product. In the second case, where coarse crystalline {sup 11}B powder was used as a raw material, only Os{sub 2}B{sub 3} boride was synthesized mechanochemically. The thermal stability of hexagonal OsB{sub 2} powder was studied by heating under argon up to 876 °C and cooling in vacuo down to −225 °C. During the heating, the sacrificial reaction 2OsB{sub 2}+3O{sub 2}→2Os+2B{sub 2}O{sub 3} took place due to presence of O{sub 2}/water vapor molecules in the heating chamber, resulting in the oxidation of B atoms and formation of B{sub 2}O{sub 3} and precipitation of Os metal out of the OsB{sub 2} lattice. As a result of such phase changes during heating, the lattice parameters of hexagonal OsB{sub 2} changed significantly. The shrinkage of the a lattice parameter was recorded in 276–426 °C temperature range upon heating, which was attributed to the removal of B atoms from the OsB{sub 2} lattice due to oxidation followed by the precipitation of Os atoms and formation of Os metal. While significant structural changes occurred upon heating due to presence of O{sub 2}, the hexagonal OsB{sub 2} ceramic demonstrated good phase stability upon cooling in vacuo with linear shrinkage of the lattice

  18. Shell Buckling Design Criteria Based on Manufacturing Imperfection Signatures

    NASA Technical Reports Server (NTRS)

    Hilburger, Mark W.; Nemeth, Michael P.; Starnes, James H., Jr.

    2004-01-01

    An analysis-based approach .for developing shell-buckling design criteria for laminated-composite cylindrical shells that accurately accounts for the effects of initial geometric imperfections is presented. With this approach, measured initial geometric imperfection data from six graphite-epoxy shells are used to determine a manufacturing-process-specific imperfection signature for these shells. This imperfection signature is then used as input into nonlinear finite-element analyses. The imperfection signature represents a "first-approximation" mean imperfection shape that is suitable for developing preliminary-design data. Comparisons of test data and analytical results obtained by using several different imperfection shapes are presented for selected shells. Overall, the results indicate that the analysis-based approach presented for developing reliable preliminary-design criteria has the potential to provide improved, less conservative buckling-load estimates, and to reduce the weight and cost of developing buckling-resistant shell structures.

  19. Graphene on hexagonal boron nitride

    NASA Astrophysics Data System (ADS)

    Yankowitz, Matthew; Xue, Jiamin; LeRoy, B. J.

    2014-07-01

    The field of graphene research has developed rapidly since its first isolation by mechanical exfoliation in 2004. Due to the relativistic Dirac nature of its charge carriers, graphene is both a promising material for next-generation electronic devices and a convenient low-energy testbed for intrinsically high-energy physical phenomena. Both of these research branches require the facile fabrication of clean graphene devices so as not to obscure its intrinsic physical properties. Hexagonal boron nitride has emerged as a promising substrate for graphene devices as it is insulating, atomically flat and provides a clean charge environment for the graphene. Additionally, the interaction between graphene and boron nitride provides a path for the study of new physical phenomena not present in bare graphene devices. This review focuses on recent advancements in the study of graphene on hexagonal boron nitride devices from the perspective of scanning tunneling microscopy with highlights of some important results from electrical transport measurements.

  20. Epitaxial Garnets and Hexagonal Ferrites.

    DTIC Science & Technology

    1983-12-01

    Ferrites Lithium Ferrite Magnetostatic Wave Garnets Epitaxy Yttrium Iron Garnet Liquid Phase Epitaxy Hexagonal Ferrite Microwave Signal Processing...epitaxial ferrit ( materials for use in microwave and millirreter-wave signal processing devices. The major emphasis has been on multiple layer...overall objective of this research is to develop epitaxial single crystal ferrite films suitable for microwave and millimeter-wave signal processing at

  1. Epitaxial Garnets and Hexagonal Ferrites.

    DTIC Science & Technology

    1982-04-20

    Iron Garnet Liquid Phase Epitaxy Hexagonal Ferrite microwave Signal Processing Millimeter-Wave 20. ABSTRACT (Continue ani revee arde if necoeermy and...le.’uIfy by block rns.) e objective of this research is to develop new and improved epitauial ferrite materials for use in microwave and millimeter... ferrite films suitable for microwave and millimeter-wave signal processing at frequencies above 1 GHz. The specific tasks are: a. Analyze and develop

  2. A hexagonal orthogonal-oriented pyramid as a model of image representation in visual cortex

    NASA Technical Reports Server (NTRS)

    Watson, Andrew B.; Ahumada, Albert J., Jr.

    1989-01-01

    Retinal ganglion cells represent the visual image with a spatial code, in which each cell conveys information about a small region in the image. In contrast, cells of the primary visual cortex use a hybrid space-frequency code in which each cell conveys information about a region that is local in space, spatial frequency, and orientation. A mathematical model for this transformation is described. The hexagonal orthogonal-oriented quadrature pyramid (HOP) transform, which operates on a hexagonal input lattice, uses basis functions that are orthogonal, self-similar, and localized in space, spatial frequency, orientation, and phase. The basis functions, which are generated from seven basic types through a recursive process, form an image code of the pyramid type. The seven basis functions, six bandpass and one low-pass, occupy a point and a hexagon of six nearest neighbors on a hexagonal lattice. The six bandpass basis functions consist of three with even symmetry, and three with odd symmetry. At the lowest level, the inputs are image samples. At each higher level, the input lattice is provided by the low-pass coefficients computed at the previous level. At each level, the output is subsampled in such a way as to yield a new hexagonal lattice with a spacing square root of 7 larger than the previous level, so that the number of coefficients is reduced by a factor of seven at each level. In the biological model, the input lattice is the retinal ganglion cell array. The resulting scheme provides a compact, efficient code of the image and generates receptive fields that resemble those of the primary visual cortex.

  3. Bimaterial lattices as thermal adapters and actuators

    NASA Astrophysics Data System (ADS)

    Toropova, Marina M.; Steeves, Craig A.

    2016-11-01

    The goal of this paper is to demonstrate how anisotropic biomaterial lattices can be used in thermal actuation. Compared to other lattices with tailored thermal expansion, the anisotropy of these bimaterial lattices makes them uniquely suitable for use as thermal actuators. Each individual cell, and hence lattices consisting of such cells, can be designed with widely different predetermined coefficients of thermal expansion (CTE) in different directions, enabling complex shape changes appropriate for actuation with either passive or active control. The lattices are composed of planar non-identical cells that each consist of a skewed hexagon surrounding an irregular triangle. The cells and all members of any cell are connected to each other by pins so that they have no rotational constraints and are able to expand or contract freely. In this case, the skew angles of the hexagon and the ratio of the CTEs of the two component materials determine the overall performance of the lattice. At its boundaries, the lattice is connected to substrates by pins and configured such that the CTE between two neighboring lattice vertices coincides with the CTE of the adjacent substrate. Provided the boundary behavior of the lattice is matched to the thermal properties of the substrates, temperature changes in the structure produce thermal strains without producing any corresponding stresses. Such lattices can be used in three different ways: as adaptive elements for stress-free connection of components with different CTEs; for fine tuning of structures; and as thermally driven actuators. In this paper, we demonstrate some concepts for lattice configurations that produce thermally-driven displacements that enable several actuators: a switch, a valve and tweezers.

  4. Trend estimation in populations with imperfect detection

    USGS Publications Warehouse

    Kery, Marc; Dorazio, Robert M.; Soldaat, Leo; Van Strien, Arco; Zuiderwijk, Annie; Royle, J. Andrew

    2009-01-01

    1. Trends of animal populations are of great interest in ecology but cannot be directly observed owing to imperfect detection. Binomial mixture models use replicated counts to estimate abundance, corrected for detection, in demographically closed populations. Here, we extend these models to open populations and illustrate them using sand lizard Lacerta agilis counts from the national Dutch reptile monitoring scheme. 2. Our model requires replicated counts from multiple sites in each of several periods, within which population closure is assumed. Counts are described by a hierarchical generalized linear model, where the state model deals with spatio-temporal patterns in true abundance and the observation model with imperfect counts, given that true state. We used WinBUGS to fit the model to lizard counts from 208 transects with 1–10 (mean 3) replicate surveys during each spring 1994–2005. 3. Our state model for abundance contained two independent log-linear Poisson regressions on year for coastal and inland sites, and random site effects to account for unexplained heterogeneity. The observation model for detection of an individual lizard contained effects of region, survey date, temperature, observer experience and random survey effects. 4. Lizard populations increased in both regions but more steeply on the coast. Detectability increased over the first few years of the study, was greater on the coast and for the most experienced observers, and highest around 1 June. Interestingly, the population increase inland was not detectable when the observed counts were analysed without account of detectability. The proportional increase between 1994 and 2005 in total lizard abundance across all sites was estimated at 86% (95% CRI 35–151). 5. Synthesis and applications. Open-population binomial mixture models are attractive for studying true population dynamics while explicitly accounting for the observation process, i.e. imperfect detection. We emphasize the important

  5. Implicit bias, awareness and imperfect cognitions.

    PubMed

    Holroyd, Jules

    2015-05-01

    Are individuals responsible for behaviour that is implicitly biased? Implicitly biased actions are those which manifest the distorting influence of implicit associations. That they express these 'implicit' features of our cognitive and motivational make up has been appealed to in support of the claim that, because individuals lack the relevant awareness of their morally problematic discriminatory behaviour, they are not responsible for behaving in ways that manifest implicit bias. However, the claim that such influences are implicit is, in fact, not straightforwardly related to the claim that individuals lack awareness of the morally problematic dimensions of their behaviour. Nor is it clear that lack of awareness does absolve from responsibility. This may depend on whether individuals culpably fail to know something that they should know. I propose that an answer to this question, in turn, depends on whether other imperfect cognitions are implicated in any lack of the relevant kind of awareness. In this paper I clarify our understanding of 'implicitly biased actions' and then argue that there are three different dimensions of awareness that might be at issue in the claim that individuals lack awareness of implicit bias. Having identified the relevant sense of awareness I argue that only one of these senses is defensibly incorporated into a condition for responsibility, rejecting recent arguments from Washington & Kelly for an 'externalist' epistemic condition. Having identified what individuals should - and can - know about their implicitly biased actions, I turn to the question of whether failures to know this are culpable. This brings us to consider the role of implicit biases in relation to other imperfect cognitions. I conclude that responsibility for implicitly biased actions may depend on answers to further questions about their relationship to other imperfect cognitions.

  6. Imperfect relativistic mirrors in the quantum regime

    SciTech Connect

    Mendonça, J. T.; Serbeto, A.; Galvão, R. M. O.

    2014-05-15

    The collective backscattering of intense laser radiation by energetic electron beams is considered in the relativistic quantum regime. Exact solutions for the radiation field are obtained, for arbitrary electron pulse shapes and laser intensities. The electron beams act as imperfect nonlinear mirrors on the incident laser radiation. This collective backscattering process can lead to the development of new sources of ultra-short pulse radiation in the gamma-ray domain. Numerical examples show that, for plausible experimental conditions, intense pulses of gamma-rays, due to the double Doppler shift of the harmonics of the incident laser radiation, can be produced using the available technology, with durations less than 1 as.

  7. Imperfection, practice and humility in clinical ethics.

    PubMed

    Garchar, Kim

    2012-10-01

    In this essay, I provide a description of the discipline of ethics using the philosophies of Aristotle and the American pragmatist John Dewey. Specifically, I argue that ethics is an active undertaking that is ambiguous and pluralistic. I then normatively prescribe the way in which clinical ethicists ought to approach their work in medicine. Rather than endeavouring to become, or behaving as if they are, experts, clinical ethicists must be humble. They must practise ethics. That is, they must admit ethics is the study and pursuit of the good life but that this study and pursuit occurs imperfectly in the face of problematic situations.

  8. Learning receptor positions from imperfectly known motions

    NASA Astrophysics Data System (ADS)

    Ahumada, Albert J., Jr.; Mulligan, Jeffrey B.

    1990-10-01

    An algorithm is described for learning image interpolation functions for sensor arrays whose sensor positions are somewhat disordered. The learning is based on failures of translation invariance, so it does not require knowledge of the images being presented to the visual system. Previously reported implementations of the method assumed the visual system to have precise knowledge of the translations. We demonstrate here that translation estimates computed from the imperfectly interpolated images can have enough accuracy to allow the learning process to converge to a correct interpolation.

  9. Method for correcting imperfections on a surface

    DOEpatents

    Sweatt, William C.; Weed, John W.

    1999-09-07

    A process for producing near perfect optical surfaces. A previously polished optical surface is measured to determine its deviations from the desired perfect surface. A multi-aperture mask is designed based on this measurement and fabricated such that deposition through the mask will correct the deviations in the surface to an acceptable level. Various mask geometries can be used: variable individual aperture sizes using a fixed grid for the apertures or fixed aperture sizes using a variable aperture spacing. The imperfections are filled in using a vacuum deposition process with a very thin thickness of material such as silicon monoxide to produce an amorphous surface that bonds well to a glass substrate.

  10. Chaos in an imperfectly premixed model combustor

    SciTech Connect

    Kabiraj, Lipika Saurabh, Aditya; Paschereit, Christian O.; Karimi, Nader; Sailor, Anna; Mastorakos, Epaminondas; Dowling, Ann P.

    2015-02-15

    This article reports nonlinear bifurcations observed in a laboratory scale, turbulent combustor operating under imperfectly premixed mode with global equivalence ratio as the control parameter. The results indicate that the dynamics of thermoacoustic instability correspond to quasi-periodic bifurcation to low-dimensional, deterministic chaos, a route that is common to a variety of dissipative nonlinear systems. The results support the recent identification of bifurcation scenarios in a laminar premixed flame combustor (Kabiraj et al., Chaos: Interdiscip. J. Nonlinear Sci. 22, 023129 (2012)) and extend the observation to a practically relevant combustor configuration.

  11. Physical Vapor Deposition of Hexagonal and Tetragonal CuIn5Se8 Thin Films

    NASA Astrophysics Data System (ADS)

    Kohara, Naoki; Nishiawaki, Shiro; Negami, Takayuki; Wada, Takahiro

    2000-11-01

    Hexagonal and tetragonal CuIn5Se8 thin films have been successfully prepared by physical vapor deposition. A hexagonal CuIn5Se8 thin film was obtained via the reaction of (Cu+Se) and (In+Se) layers. This hexagonal film had a layered structure with a lattice spacing of approximately 16 Å, corresponding to fivefold close-packed stacking of Se. With an alternative deposition process using (CuInSe2) and (In2Se3) layers, a tetragonal CuIn5Se8 thin film was obtained. The tetragonal film had a columnar structure with a lattice spacing of 3.3 Å, corresponding to the cubic close-packed stacking of Se. As evident from examination of the Cu2Se-In2Se3 pseudo-binary system phase diagram, hexagonal CuIn5Se8 is a stable phase and tetragonal CuIn5Se8 is metastable. The growth mechanism of the hexagonal and tetragonal phase CuIn5Se8 thin films is discussed from a crystallographic point of view.

  12. Thermal conductivity of ultra-thin chemical vapor deposited hexagonal boron nitride films

    SciTech Connect

    Alam, M. T.; Haque, M. A.; Bresnehan, M. S.; Robinson, J. A.

    2014-01-06

    Thermal conductivity of freestanding 10 nm and 20 nm thick chemical vapor deposited hexagonal boron nitride films was measured using both steady state and transient techniques. The measured value for both thicknesses, about 100 ± 10 W m{sup −1} K{sup −1}, is lower than the bulk basal plane value (390 W m{sup −1} K{sup −1}) due to the imperfections in the specimen microstructure. Impressively, this value is still 100 times higher than conventional dielectrics. Considering scalability and ease of integration, hexagonal boron nitride grown over large area is an excellent candidate for thermal management in two dimensional materials-based nanoelectronics.

  13. Imperfect twinning: a clinical and ethical dilemma

    PubMed Central

    Denardin, Daniela; Telles, Jorge Alberto B.; Betat, Rosilene da Silveira; Fell, Paulo Renato K.; da Cunha, André Campos; Targa, Luciano Vieira; Zen, Paulo Ricardo G.; Rosa, Rafael Fabiano M.

    2013-01-01

    OBJECTIVE To review the history, epidemiology, etiology, gestational aspects, diagnosis and prognosis of imperfect twinning. DATA SOURCES Scientific articles were searched in PubMed, SciELO and Lilacs databases, using the descriptors "conjoined twins", "multiple pregnancy", "ultrasound", "magnetic resonance imaging" and "prognosis". The research was not delimited to a specific period of time and was supplemented with bibliographic data from books. DATA SYNTHESIS: The description of conjoined twins is legendary. The estimated frequency is 1/45,000-200,000 births. These twins are monozygotic, monochorionic and usually monoamniotic. They can be classified by the most prominent fusion site, by the symmetry between the conjoined twins or by the sharing structure. The diagnosis can be performed in the prenatal period or after birth by different techniques, such as ultrasound, magnetic resonance imaging and echocardiography. These tests are of paramount importance for understanding the anatomy of both fetuses/children, as well as for prognosis and surgical plan determination. CONCLUSIONS Although imperfect twinning is a rare condition, the prenatal diagnosis is very important in order to evaluate the fusion site and its complexity. Hence, the evaluation of these children should be multidisciplinary, involving mainly obstetricians, pediatricians and pediatric surgeons. However, some decisions may constitute real ethical dilemmas, in which different points should be discussed and analyzed with the health team and the family. PMID:24142323

  14. Modeling Being "Lost": Imperfect Situation Awareness

    NASA Technical Reports Server (NTRS)

    Middleton, Victor E.

    2011-01-01

    Being "lost" is an exemplar of imperfect Situation Awareness/Situation Understanding (SA/SU) -- information/knowledge that is uncertain, incomplete, and/or just wrong. Being "lost" may be a geo-spatial condition - not knowing/being wrong about where to go or how to get there. More broadly, being "lost" can serve as a metaphor for uncertainty and/or inaccuracy - not knowing/being wrong about how one fits into a larger world view, what one wants to do, or how to do it. This paper discusses using agent based modeling (ABM) to explore imperfect SA/SU, simulating geo-spatially "lost" intelligent agents trying to navigate in a virtual world. Each agent has a unique "mental map" -- its idiosyncratic view of its geo-spatial environment. Its decisions are based on this idiosyncratic view, but behavior outcomes are based on ground truth. Consequently, the rate and degree to which an agent's expectations diverge from ground truth provide measures of that agent's SA/SU.

  15. Relations and interactions between twinning and grain boundaries in hexagonal close-packed structures

    NASA Astrophysics Data System (ADS)

    Barrett, Christopher Duncan

    Improving the formability and crashworthiness of wrought magnesium alloys are the two biggest challenges in current magnesium technology. Magnesium is the best material candidate for enabling required improvements in fuel economy of combustion engines and increases in ranges of electric vehicles. In hexagonal closed-packed (HCP) structures, effects of grain size/morphology and crystallographic texture are particularly important. Prior research has established a general understanding of the dependences of strength and strain anisotropy on grain morphology and texture. Unfortunately, deformation, recrystallization, and grain growth strategies that control the microstructures and textures of cubic metals and alloys have not generally worked for HCPs. For example, in Magnesium, the deformation texture induced by primary forming operations (rolling, extrusion, etc.) is not randomized by recrystallization and may strengthen during grain growth. A strong texture reduces formability during secondary forming (stamping, bending, hemming etc.) Thus, the inability to randomize texture has impeded the implementation of magnesium alloys in engineering applications. When rare earth solutes are added to magnesium alloys, distinct new textures are derived. However, `rare earth texture' derivation remains insufficiently explained. Currently, it is hypothesized that unknown mechanisms of alloy processing are at work, arising from the effects of grain boundary intrinsic defect structures on microstructural evolution. This dissertation is a comprehensive attempt to identify formal methodologies of analyzing the behavior of grain boundaries in magnesium. We focus particularly on twin boundaries and asymmetric tilt grain boundaries using molecular dynamics. We begin by exploring twin nucleation in magnesium single crystals, elucidating effects of heterogeneities on twin nucleation and their relationships with concurrent slip. These efforts highlighted the necessity of imperfections to

  16. Equivalence of deterministic walks on regular lattices on the plane

    NASA Astrophysics Data System (ADS)

    Rechtman, Ana; Rechtman, Raúl

    2017-01-01

    We consider deterministic walks on square, triangular and hexagonal two dimensional lattices. In each case, there is a scatterer at every lattice site that can be in one of two states that forces the walker to turn either to his/her immediate right or left. After the walker is scattered, the scatterer changes state. A lattice with an arrangement of scatterers is an environment. We show that there are only two environments for which the scattering rules are injective, mirrors or rotators, on the three lattices. On hexagonal lattices Webb and Cohen (2014), proved that if a walker with a given initial position and velocity moves through an environment of mirrors (rotators) then there is an environment of rotators (mirrors) through which the walker would move with the same trajectory. We refer to these trajectories on mirror and rotator environments as equivalent walks. We prove the equivalence of walks on square and triangular lattices and include a proof of the equivalence of walks on hexagonal lattices. The proofs are based both on the geometry of the lattice and the structure of the scattering rule.

  17. Statistical analysis of imperfection effect on cylindrical buckling response

    NASA Astrophysics Data System (ADS)

    Ismail, M. S.; Purbolaksono, J.; Muhammad, N.; Andriyana, A.; Liew, H. L.

    2015-12-01

    It is widely reported that no efficient guidelines for modelling imperfections in composite structures are available. In response, this work evaluates the imperfection factors of axially compressed Carbon Fibre Reinforced Polymer (CFRP) cylinder with different ply angles through finite element (FE) analysis. The sensitivity of imperfection factors were analysed using design of experiment: factorial design approach. From the analysis it identified three critical factors that sensitively reacted towards buckling load. Furthermore empirical equation is proposed according to each type of cylinder. Eventually, critical buckling loads estimated by empirical equation showed good agreements with FE analysis. The design of experiment methodology is useful in identifying parameters that lead to structures imperfection tolerance.

  18. Method for correcting imperfections on a surface

    SciTech Connect

    Sweatt, W.C.; Weed, J.W.

    1999-09-07

    A process for producing near perfect optical surfaces is disclosed. A previously polished optical surface is measured to determine its deviations from the desired perfect surface. A multi-aperture mask is designed based on this measurement and fabricated such that deposition through the mask will correct the deviations in the surface to an acceptable level. Various mask geometries can be used: variable individual aperture sizes using a fixed grid for the apertures or fixed aperture sizes using a variable aperture spacing. The imperfections are filled in using a vacuum deposition process with a very thin thickness of material such as silicon monoxide to produce an amorphous surface that bonds well to a glass substrate.

  19. Imperfect mimicry and the limits of natural selection.

    PubMed

    Kikuchi, David W; Pfennig, David W

    2013-12-01

    Mimicry--when one organism (the mimic) evolves a phenotypic resemblance to another (the model) due to selective benefits--is widely used to illustrate natural selection's power to generate adaptations. However, many putative mimics resemble their models imprecisely, and such imperfect mimicry represents a specific challenge to mimicry theory and a general one to evolutionary theory. Here, we discuss 11 nonmutually exclusive hypotheses for imperfect mimicry. We group these hypotheses according to whether imperfect mimicry reflects: an artifact of human perception, which is not shared by any naturally occurring predators and therefore is not truly an instance of imperfect mimicry; genetic, developmental or time-lag constraints, which (temporarily) prevent a response to selection for perfect mimicry; relaxed selection, where imperfect mimicry is as adaptive as perfect mimicry; or tradeoffs, where imperfect mimicry is (locally) more adaptive than perfect mimicry. We find that the relaxed selection hypothesis has garnered the most support. However, because only a few study systems have thus far been comprehensively evaluated, the relative contributions of the various hypotheses toward explaining the evolution of imperfect mimicry remain unclear. Ultimately, clarifying why imperfect mimicry exists should provide critical insights into the limits of natural selection in producing complex adaptations.

  20. Imperfection sensitivity of pressured buckling of biopolymer spherical shells

    NASA Astrophysics Data System (ADS)

    Zhang, Lei; Ru, C. Q.

    2016-06-01

    Imperfection sensitivity is essential for mechanical behavior of biopolymer shells [such as ultrasound contrast agents (UCAs) and spherical viruses] characterized by high geometric heterogeneity. In this work, an imperfection sensitivity analysis is conducted based on a refined shell model recently developed for spherical biopolymer shells of high structural heterogeneity and thickness nonuniformity. The influence of related parameters (including the ratio of radius to average shell thickness, the ratio of transverse shear modulus to in-plane shear modulus, and the ratio of effective bending thickness to average shell thickness) on imperfection sensitivity is examined for pressured buckling. Our results show that the ratio of effective bending thickness to average shell thickness has a major effect on the imperfection sensitivity, while the effect of the ratio of transverse shear modulus to in-plane shear modulus is usually negligible. For example, with physically realistic parameters for typical imperfect spherical biopolymer shells, the present model predicts that actual maximum external pressure could be reduced to as low as 60% of that of a perfect UCA spherical shell or 55%-65% of that of a perfect spherical virus shell, respectively. The moderate imperfection sensitivity of spherical biopolymer shells with physically realistic imperfection is largely attributed to the fact that biopolymer shells are relatively thicker (defined by smaller radius-to-thickness ratio) and therefore practically realistic imperfection amplitude normalized by thickness is very small as compared to that of classical elastic thin shells which have much larger radius-to-thickness ratio.

  1. Imperfection sensitivity of pressured buckling of biopolymer spherical shells.

    PubMed

    Zhang, Lei; Ru, C Q

    2016-06-01

    Imperfection sensitivity is essential for mechanical behavior of biopolymer shells [such as ultrasound contrast agents (UCAs) and spherical viruses] characterized by high geometric heterogeneity. In this work, an imperfection sensitivity analysis is conducted based on a refined shell model recently developed for spherical biopolymer shells of high structural heterogeneity and thickness nonuniformity. The influence of related parameters (including the ratio of radius to average shell thickness, the ratio of transverse shear modulus to in-plane shear modulus, and the ratio of effective bending thickness to average shell thickness) on imperfection sensitivity is examined for pressured buckling. Our results show that the ratio of effective bending thickness to average shell thickness has a major effect on the imperfection sensitivity, while the effect of the ratio of transverse shear modulus to in-plane shear modulus is usually negligible. For example, with physically realistic parameters for typical imperfect spherical biopolymer shells, the present model predicts that actual maximum external pressure could be reduced to as low as 60% of that of a perfect UCA spherical shell or 55%-65% of that of a perfect spherical virus shell, respectively. The moderate imperfection sensitivity of spherical biopolymer shells with physically realistic imperfection is largely attributed to the fact that biopolymer shells are relatively thicker (defined by smaller radius-to-thickness ratio) and therefore practically realistic imperfection amplitude normalized by thickness is very small as compared to that of classical elastic thin shells which have much larger radius-to-thickness ratio.

  2. Fourier-transform infrared spectroscopy (FTIR) analysis of triclinic and hexagonal birnessites.

    PubMed

    Ling, Florence T; Post, Jeffrey E; Heaney, Peter J; Kubicki, James D; Santelli, Cara M

    2017-05-05

    The characterization of birnessite structures is particularly challenging for poorly crystalline materials of biogenic origin, and a determination of the relative concentrations of triclinic and hexagonal birnessite in a mixed assemblage has typically required synchrotron-based spectroscopy and diffraction approaches. In this study, Fourier-transform infrared spectroscopy (FTIR) is demonstrated to be capable of differentiating synthetic triclinic Na-birnessite and synthetic hexagonal H-birnessite. Furthermore, IR spectral deconvolution of peaks resulting from MnO lattice vibrations between 400 and 750cm(-1) yield results comparable to those obtained by linear combination fitting of synchrotron X-ray absorption fine structure (EXAFS) data when applied to known mixtures of triclinic and hexagonal birnessites. Density functional theory (DFT) calculations suggest that an infrared absorbance peak at ~1628cm(-1) may be related to OH vibrations near vacancy sites. The integrated intensity of this peak may show sensitivity to vacancy concentrations in the Mn octahedral sheet for different birnessites.

  3. A planar carbon allotrope with linear bipentagon-octagon and hexagon arrangement

    NASA Astrophysics Data System (ADS)

    Zheng, Guohui; Jia, Yalei; Gao, Song; Ke, San-Huang

    2017-03-01

    A two-dimensional (2D) metallic carbon allotrope is proposed, which consists of linearly aligned bipentagon-octagon and hexagon rings in a planar sheet. The relatively high percentage of hexagon and the regular arrangement of the polygons make it energetically more favorable than most of other predicted 2D carbon allotropes. Phonon dispersions without negative frequencies also indicate its stability. Electronic structure calculations show that its metallic nature is mainly due to the atoms shared by the pentagon, hexagon and octagon. Its lattice thermal conductivity is only about one fifth of that of graphene. Armchair- and zigzag-edged nanoribbons of this structure are also studied. The former is metallic while the latter has a small band gap due to the spin-polarized edge states. The appropriate band gap and the significantly reduced thermal conductivity suggest potential applications in thermoelectricity.

  4. Oxygen interaction with hexagonal OsB2 at high temperature

    DOE PAGES

    Xie, Zhilin; Blair, Richard G.; Orlovskaya, Nina; ...

    2016-08-10

    The stability of ReB2-type hexagonal OsB2 powder at high temperature with oxygen presence has been studied by thermogravimetric analysis, differential scanning calorimetry, SEM, EDS, and high-temperature scanning transmission electron microscopy and XRD. Results of the study revealed that OsB2 ceramics interact readily with oxygen present in reducing atmosphere, especially at high temperature and produces boric acid, which decomposes on the surface of the powder resulting in the formation of boron vacancies in the hexagonal OsB2 lattice as well as changes in the stoichiometry of the compound. It was also found that under low oxygen partial pressure, sintering of OsB2 powdersmore » occurred at a relatively low temperature (900°C). Finally, hexagonal OsB2 ceramic is prone to oxidation and it is very sensitive to oxygen partial pressures, especially at high temperatures.« less

  5. Electrodeposited Silver Nanoparticles Patterned Hexagonally for SERS

    SciTech Connect

    Gu, Geun Hoi; Lee, Sue Yeone; Suh, Jung Sang

    2010-08-06

    We have fabricated hexagonally patterned silver nanoparticles for surface-enhanced Raman scattering (SERS) by electrodepositing silver on the surface of an aluminum plate prepared by completely removing the oxide from anodic aluminum oxide (AAO) templates. Even after completely removing the oxide, well-ordered hexagonal patterns, similar to the shape of graphene, remained on the surface of the aluminum plate. The borders of the hexagonal pattern protruded up to form sorts of nano-mountains at both the sides and apexes of the hexagon, with the apexes protruding even more significantly than the sides. The aluminum plate prepared by completely removing the oxide has been used in the preparation of SERS substrates by sputter-coating of gold or silver on it. Instead of sputter-coating, here we have electro-deposited silver on the aluminum plate. When silver was electro-deposited on the plate, silver nanoparticles were made along the hexagonal margins.

  6. Ballistic Transport in Graphene Antidot Lattices.

    PubMed

    Sandner, Andreas; Preis, Tobias; Schell, Christian; Giudici, Paula; Watanabe, Kenji; Taniguchi, Takashi; Weiss, Dieter; Eroms, Jonathan

    2015-12-09

    The bulk carrier mobility in graphene was shown to be enhanced in graphene-boron nitride heterostructures. However, nanopatterning graphene can add extra damage and drastically degrade the intrinsic properties by edge disorder. Here we show that graphene embedded into a heterostructure with hexagonal boron nitride (hBN) on both sides is protected during a nanopatterning step. In this way, we can prepare graphene-based antidot lattices where the high mobility is preserved. We report magnetotransport experiments in those antidot lattices with lattice periods down to 50 nm. We observe pronounced commensurability features stemming from ballistic orbits around one or several antidots. Due to the short lattice period in our samples, we can also explore the boundary between the classical and the quantum transport regime, as the Fermi wavelength of the electrons approaches the smallest length scale of the artificial potential.

  7. Perfect crystals grown from imperfect interfaces.

    PubMed

    Falub, Claudiu V; Meduňa, Mojmír; Chrastina, Daniel; Isa, Fabio; Marzegalli, Anna; Kreiliger, Thomas; Taboada, Alfonso G; Isella, Giovanni; Miglio, Leo; Dommann, Alex; von Känel, Hans

    2013-01-01

    The fabrication of advanced devices increasingly requires materials with different properties to be combined in the form of monolithic heterostructures. In practice this means growing epitaxial semiconductor layers on substrates often greatly differing in lattice parameters and thermal expansion coefficients. With increasing layer thickness the relaxation of misfit and thermal strains may cause dislocations, substrate bowing and even layer cracking. Minimizing these drawbacks is therefore essential for heterostructures based on thick layers to be of any use for device fabrication. Here we prove by scanning X-ray nanodiffraction that mismatched Ge crystals epitaxially grown on deeply patterned Si substrates evolve into perfect structures away from the heavily dislocated interface. We show that relaxing thermal and misfit strains result just in lattice bending and tiny crystal tilts. We may thus expect a new concept in which continuous layers are replaced by quasi-continuous crystal arrays to lead to dramatically improved physical properties.

  8. Perfect crystals grown from imperfect interfaces

    PubMed Central

    Falub, Claudiu V.; Meduňa, Mojmír; Chrastina, Daniel; Isa, Fabio; Marzegalli, Anna; Kreiliger, Thomas; Taboada, Alfonso G.; Isella, Giovanni; Miglio, Leo; Dommann, Alex; von Känel, Hans

    2013-01-01

    The fabrication of advanced devices increasingly requires materials with different properties to be combined in the form of monolithic heterostructures. In practice this means growing epitaxial semiconductor layers on substrates often greatly differing in lattice parameters and thermal expansion coefficients. With increasing layer thickness the relaxation of misfit and thermal strains may cause dislocations, substrate bowing and even layer cracking. Minimizing these drawbacks is therefore essential for heterostructures based on thick layers to be of any use for device fabrication. Here we prove by scanning X-ray nanodiffraction that mismatched Ge crystals epitaxially grown on deeply patterned Si substrates evolve into perfect structures away from the heavily dislocated interface. We show that relaxing thermal and misfit strains result just in lattice bending and tiny crystal tilts. We may thus expect a new concept in which continuous layers are replaced by quasi-continuous crystal arrays to lead to dramatically improved physical properties. PMID:23880632

  9. Investigation of Hexagonal Ferrite Film Growth Techniques for Millimeter-Wave Systems Applications.

    DTIC Science & Technology

    1987-03-15

    hexagonal ferrite compounds. The approach was twofold: to synthesize lattice-matched substrate materials and to explore epitaxial growth methods which...poly-crystal garnet or spinel ferrites find widespread use as tunable microwave filters and resonators in applica- tions ranging from test equipment...REFERENCES 1. W. H. von Aulock, ed., Handbook of Microwave Ferrite Materials, Academic Press, NY. 2. R. 0. Savage et al., J. App1. Phys., 36: 873 (1965

  10. Ionizing and Non-ionizing Radiation Effects in Thin Layer Hexagonal Boron Nitride

    DTIC Science & Technology

    2015-03-01

    M-099 Abstract The radiation response of 14nm h-BN/Si metal insulator semiconductor (MIS) devices was investigated using current-voltage and... insulator and passivation layers to maintain performance, but options are limited. Hexagonal boron nitride (h-BN) is one candidate for use with...graphene-based electronic systems because it has the same lattice structure as graphene, is an insulator , and is known to form on graphene surfaces. h

  11. Templated Growth of Hexagonal Nickel Carbide Nanocrystals on Vertically Aligned Carbon Nanotubes (PREPRINT)

    DTIC Science & Technology

    2010-01-01

    centered cubic ( FCC ) structure . Interestingly, there have been reports in the literature related to the stabilization of a non-equilibrium hexagonal...crystallite size (~ 4 nm) and changes to the equilibrium FCC structure for larger crystallite sizes [9-10]. Nickel does not form a carbide under equilibrium...a single weak ring corresponding to the face-centered cubic ( FCC ) structure of Ni. The lattice parameter of the HCP phase was determined to be a

  12. Thermal conductance of graphene/hexagonal boron nitride heterostructures

    NASA Astrophysics Data System (ADS)

    Lu, Simon; McGaughey, Alan J. H.

    2017-03-01

    The lattice-based scattering boundary method is applied to compute the phonon mode-resolved transmission coefficients and thermal conductances of in-plane heterostructures built from graphene and hexagonal boron nitride (hBN). The thermal conductance of all structures is dominated by acoustic phonon modes near the Brillouin zone center that have high group velocity, population, and transmission coefficient. Out-of-plane modes make their most significant contributions at low frequencies, whereas in-plane modes contribute across the frequency spectrum. Finite-length superlattice junctions between graphene and hBN leads have a lower thermal conductance than comparable junctions between two graphene leads due to lack of transmission in the hBN phonon bandgap. The thermal conductances of bilayer systems differ by less than 10% from their single-layer counterparts on a per area basis, in contrast to the strong thermal conductivity reduction when moving from single- to multi-layer graphene.

  13. Activated chemoreceptor arrays remain intact and hexagonally packed

    PubMed Central

    Briegel, Ariane; Beeby, Morgan; Thanbichler, Martin; Jensen, Grant J.

    2013-01-01

    Summary Bacterial chemoreceptors cluster into exquisitively sensitive, tunable, highly ordered, polar arrays. While these arrays serve as paradigms of cell signalling in general, it remains unclear what conformational changes transduce signals from the periplasmic tips, where attractants and repellents bind, to the cytoplasmic signalling domains. Conflicting reports support and contest the hypothesis that activation causes large changes in the packing arrangement of the arrays, up to and including their complete disassembly. Using electron cryotomography, here we show that in Caulobacter crescentus, chemoreceptor arrays in cells grown in different media and immediately after exposure to the attractant galactose all exhibit the same 12 nm hexagonal packing arrangement, array size and other structural parameters. ΔcheB and ΔcheR mutants mimicking attractant- or repellent-bound states prior to adaptation also show the same lattice structure. We conclude that signal transduction and amplification must be accomplished through only small, nanoscale conformational changes. PMID:21992450

  14. Electronic structure of spontaneously strained graphene on hexagonal boron nitride

    NASA Astrophysics Data System (ADS)

    San-Jose, Pablo; Gutiérrez-Rubio, A.; Sturla, Mauricio; Guinea, Francisco

    2014-09-01

    Hexagonal boron nitride substrates have been shown to dramatically improve the electric properties of graphene. Recently, it has been observed that when the two honeycomb crystals are close to perfect alignment, strong lattice distortions develop in graphene due to the moiré adhesion landscape. Simultaneously, a gap opens at the Dirac point. Here, we derive a simple low-energy electronic model for graphene aligned with the substrate, taking into account spontaneous strains at equilibrium and pseudogauge fields. We carry out a detailed characterization of the modified band structure, gap, local and global density of states, and band topology in terms of physical parameters. We show that the overall electronic structure is strongly modified by the spontaneous strains.

  15. Columnar epitaxy of hexagonal and orthorhombic silicides on Si(111)

    NASA Technical Reports Server (NTRS)

    Fathauer, R. W.; Nieh, C. W.; Xiao, Q. F.; Hashimoto, Shin

    1990-01-01

    Columnar grains of PtSi and CrSi2 surrounded by high-quality epitaxial silicon are obtained by ultrahigh vacuum codeposition of Si and metal in an approximately 10:1 ratio on Si(111) substrates heated to 610-840 C. This result is similar to that found previously for CoSi2 (a nearly-lattice-matched cubic-fluorite crystal) on Si(111), in spite of the respective orthorhombic and hexagonal structures of PtSi and CrSi2. The PtSi grains are epitaxial and have one of three variants of the relation defined by PtSi(010)/Si(111), with PtSi 001 line/Si 110 line type.

  16. Influence of imperfections on effective properties of cellular solids

    SciTech Connect

    Grenestedt, J.L.

    1998-12-31

    The mechanical properties of cellular solids, or solid foams, is affected by imperfections such as wavy distortions of cell walls, variations in cell wall thickness, non-uniform cell shape, etc. The present paper is focused mainly on elastic stiffnesses of closed cell cellular solids. A perfect model is first discussed and shown to predict the behavior of PVC foams well. However, this model over-estimates the stiffnesses of aluminum foams. The relatively poor properties of the aluminum foam are believed to be caused by imperfections in the cells. The main body of the paper focuses on modeling different kinds of imperfections, and analyzing their impact on foam properties.

  17. Spatial anisotropy of topological domain structure in hexagonal manganites

    NASA Astrophysics Data System (ADS)

    Yang, K. L.; Zhang, Y.; Zheng, S. H.; Lin, L.; Yan, Z. B.; Liu, J.-M.; Cheong, S.-W.

    2017-01-01

    The domain structure of hexagonal manganites is simulated based on the phenomenological Ginzburg-Landau theory, and special attention is paid to the evolution of a topological vortex-antivortex pattern with the varying out-of-plane anisotropies of two stiffness parameters for the in-plane (x y -plane) trimerization amplitude Q and out-of-plane (z -axis) polarization P . It is revealed that the topological domain structure can be remarkably modulated by the stiffness anisotropies. A larger stiffness for Q along the z axis causes the trajectory lines of the vortex nodes and antivortex nodes to be seriously stretched along the z axis, eventually leading to the topological stripelike domain pattern. The larger stiffness for either Q or P along the z axis makes the domain walls perpendicular to the z axis wider, while the domain walls parallel to the z axis remain less affected. The present work suggests that the topological domain structure may be controlled by some approaches (e.g., lattice strain) which can change the trimerization stiffness and polarization stiffness in hexagonal manganites.

  18. Novel high pressure hexagonal OsB{sub 2} by mechanochemistry

    SciTech Connect

    Xie, Zhilin; Graule, Moritz; Orlovskaya, Nina; Andrew Payzant, E.; Cullen, David A.; Blair, Richard G.

    2014-07-01

    Hexagonal OsB{sub 2}, a theoretically predicted high-pressure phase, has been synthesized for the first time by a mechanochemical method, i.e., high energy ball milling. X-ray diffraction indicated that formation of hexagonal OsB{sub 2} begins after 2.5 h of milling, and the reaction reaches equilibrium after 18 h of milling. Rietveld refinement of the powder data indicated that hexagonal OsB{sub 2} crystallizes in the P63/mmc space group (No. 194) with lattice parameters of a=2.916 Å and c=7.376 Å. Transmission electron microscopy confirmed the appearance of the hexagonal OsB{sub 2} phase after high energy ball milling. in situ X-ray diffraction experiments showed that the phase is stable from −225 °C to 1050 °C. The hexagonal OsB{sub 2} powder was annealed at 1050 °C for 6 days in vacuo to improve crystallinity and remove strain induced during the mechanochemical synthesis. The structure partially converted to the orthorhombic phase (20 wt%) after fast current assisted sintering of hexagonal OsB{sub 2} at 1500 °C for 5 min. Mechanochemical approaches to the synthesis of hard boride materials allow new phases to be produced that cannot be prepared using conventional methods. - Graphical abstract: High resolution transmission electron micrograph of hexagonal OsB{sub 2} nanocrystallite with corresponding fast Fourier transform and simulated diffraction pattern. - Highlights: • Hexagonal OsB{sub 2} has been synthesized for the first time by mechanochemical method. • Hexagonal OsB{sub 2} crystallizes in P63/mmc space group (No. 194), a=2.916 Å and c=7.376 Å. • The hexagonal structure was confirmed by a transmission electron microscope. • No phase transformation was observed after being annealed at 1050 °C for 6 days. • 20 wt% of h-OsB{sub 2} was transformed to o-OsB{sub 2} after being sintered at 1500 °C for 5 min.

  19. Lattice overview

    SciTech Connect

    Creutz, M.

    1984-01-01

    After reviewing some recent developments in supercomputer access, the author discusses a few areas where perturbation theory and lattice gauge simulations make contact. The author concludes with a brief discussion of a deterministic dynamics for the Ising model. This may be useful for numerical studies of nonequilibrium phenomena. 13 references.

  20. Precision Astronomy with Imperfect Deep Depletion CCDs

    NASA Astrophysics Data System (ADS)

    Stubbs, Christopher; LSST Sensor Team; PanSTARRS Team

    2014-01-01

    While thick CCDs do provide definite advantages in terms of increased quantum efficiency at wavelengths 700 nm<λ < 1.1 microns and reduced fringing from atmospheric emission lines, these devices also exhibit undesirable features that pose a challenge to precision determination of the positions, fluxes, and shapes of astronomical objects, and for the precision extraction of features in astronomical spectra. For example, the assumptions of a perfectly rectilinear pixel grid and of an intensity-independent point spread function become increasingly invalid as we push to higher precision measurements. Many of the effects seen in these devices arise from lateral electrical fields within the detector, that produce charge transport anomalies that have been previously misinterpreted as quantum efficiency variations. Performing simplistic flat-fielding therefore introduces systematic errors in the image processing pipeline. One measurement challenge we face is devising a combination of calibration methods and algorithms that can distinguish genuine quantum efficiency variations from charge transport effects. These device imperfections also confront spectroscopic applications, such as line centroid determination for precision radial velocity studies. Given the scientific benefits of improving both the precision and accuracy of astronomical measurements, we need to identify, characterize, and overcome these various detector artifacts. In retrospect, many of the detector features first identified in thick CCDs also afflict measurements made with more traditional CCD detectors, albeit often at a reduced level since the photocharge is subject to the perturbing influence of lateral electric fields for a shorter time interval. I provide a qualitative overview of the physical effects we think are responsible for the observed device properties, and provide some perspective for the work that lies ahead.

  1. Buckling Imperfection Sensitivity of Axially Compressed Orthotropic Cylinders

    NASA Technical Reports Server (NTRS)

    Schultz, Marc R.; Nemeth, Michael P.

    2010-01-01

    Structural stability is a major consideration in the design of lightweight shell structures. However, the theoretical predictions of geometrically perfect structures often considerably over predict the buckling loads of inherently imperfect real structures. It is reasonably well understood how the shell geometry affects the imperfection sensitivity of axially compressed cylindrical shells; however, the effects of shell anisotropy on the imperfection sensitivity is less well understood. In the present paper, the development of an analytical model for assessing the imperfection sensitivity of axially compressed orthotropic cylinders is discussed. Results from the analytical model for four shell designs are compared with those from a general-purpose finite-element code, and good qualitative agreement is found. Reasons for discrepancies are discussed, and potential design implications of this line of research are discussed.

  2. Quantification of the Forgiveness of Drugs to Imperfect Adherence.

    PubMed

    Assawasuwannakit, P; Braund, R; Duffull, S B

    2015-03-01

    The circumstance of how sensitive therapeutic success is under imperfect adherence is driven by the property known as forgiveness. To date, no studies have considered variability in the pharmacokinetic-pharmacodynamic process in conjunction with imperfect adherence patterns in order to develop a comparative criterion to determine the forgiveness of a drug. In this study, we have proposed a criterion to quantify forgiveness; illustrated the criterion for a theoretical example and evaluated the forgiveness of a motivating example, namely warfarin. A forgiveness criterion, relative forgiveness, is defined as the number of times more likely that a target is successfully attained under perfect adherence compared to imperfect adherence; or when comparing two drugs under a standard setting of imperfect adherence. The relative forgiveness criterion may have important implications for both drug development and clinical practice since the choice of drug can account for the likely influence of its forgiveness.

  3. Method and Apparatus for Evaluating Multilayer Objects for Imperfections

    NASA Technical Reports Server (NTRS)

    Heyman, Joseph S. (Inventor); Abedin, Nurul (Inventor); Sun, Kuen J. (Inventor)

    1999-01-01

    A multilayer object having multiple layers arranged in a stacking direction is evaluated for imperfections such as voids, delaminations and microcracks. First. an acoustic wave is transmitted into the object in the stacking direction via an appropriate transducer/waveguide combination. The wave propagates through the multilayer object and is received by another transducer/waveguide combination preferably located on the same surface as the transmitting combination. The received acoustic wave is correlated with the presence or absence of imperfections by, e.g., generating pulse echo signals indicative of the received acoustic wave. wherein the successive signals form distinct groups over time. The respective peak amplitudes of each group are sampled and curve fit to an exponential curve. wherein a substantial fit of approximately 80-90% indicates an absence of imperfections and a significant deviation indicates the presence of imperfections. Alternatively, the time interval between distinct groups can be measured. wherein equal intervals indicate the absence of imperfections and unequal intervals indicate the presence of imperfections.

  4. Attenuation characterization of multiple combinations of imperfect polarizers.

    PubMed

    Huang, Chong; Zhao, Shuang; Chen, Haiqing; Liao, Zhaoshu

    2010-05-01

    Malus's law, when used to calculate the attenuation ratio of the combination of two imperfect polarizers (two-CIP), will introduce an error, especially near the crossed-axis orientation. In this paper, first, the Jones matrix of the imperfect polarizer is deduced and an exact algorithm of the attenuation ratio of the two-CIP is proposed as well as its monotonic attenuation interval. Experimental results confirm that our deduced expression is more accurate than Malus's law. Then based on this algorithm, an attenuation-ratio expression of the combination of three imperfect polarizers (three-CIP) is presented. In this three-CIP model, it is found that when the electric field amplitude ratio of the imperfect polarizer is epsilon, the attenuation ratio can change from 1 to epsilon(4) monotonically in a general model when P(1) and P(3) are rotated and P(2) is fixed, which is proved by experiment. Finally, it is deduced that the combination of n imperfect polarizers (n-CIP) can obtain a minimum attenuation ratio of epsilon(2(n-1)), which indicates the number of imperfect polarizers needed to achieve the required attenuation ratio.

  5. Lattice fermions

    NASA Technical Reports Server (NTRS)

    Wilczek, Frank

    1987-01-01

    A simple heuristic proof of the Nielsen-Ninomaya theorem is given. A method is proposed whereby the multiplication of fermion species on a lattice is reduced to the minimal doubling, in any dimension, with retention of appropriate chiral symmetries. Also, it is suggested that use of spatially thinned fermion fields is likely to be a useful and appropriate approximation in QCD - in any case, it is a self-checking one.

  6. Fabrication of colloidal photonic crystal heterostructures free of interface imperfection based on solvent vapor annealing.

    PubMed

    Liu, Xiaomiao; Zhao, Duobiao; Geng, Chong; Zhang, Lijing; Tan, Tianya; Hu, Mingzhe; Yan, Qingfeng

    2014-11-15

    We describe the transformation of a colloidal photonic crystal into a photonic crystal heterostructure. It was achieved by annealing a polystyrene multilayer colloidal photonic crystal partially immersed in water using a solvent vapor. The floating polystyrene colloidal photonic crystal was divided into two parts by the liquid level, which can be manipulated by the addition of ethanol into the water. The top part protruding out of the water experienced a uniform lattice stretching upon exposure to the solvent vapor. The bottom part that stayed immersed in the water remained unaffected due to the protection by the water. The inconsistent behaviors of the two parts resulted in the formation of a colloidal photonic crystal heterostructure. Such a heterostructure was free of interface imperfection since it was a direct descendant of the original colloidal crystal. Meanwhile, optical measurements demonstrated the presence of a wider photonic band gap along the crystallographic [111] direction in these photonic crystal heterostructures compared with the original colloidal photonic crystals.

  7. Critical phenomena in the majority voter model on two-dimensional regular lattices.

    PubMed

    Acuña-Lara, Ana L; Sastre, Francisco; Vargas-Arriola, José Raúl

    2014-05-01

    In this work we studied the critical behavior of the critical point as a function of the number of nearest neighbors on two-dimensional regular lattices. We performed numerical simulations on triangular, hexagonal, and bilayer square lattices. Using standard finite-size scaling theory we found that all cases fall in the two-dimensional Ising model universality class, but that the critical point value for the bilayer lattice does not follow the regular tendency that the Ising model shows.

  8. Arbitrary lattice symmetries via block copolymer nanomeshes

    PubMed Central

    Majewski, Pawel W.; Rahman, Atikur; Black, Charles T.; Yager, Kevin G.

    2015-01-01

    Self-assembly of block copolymers is a powerful motif for spontaneously forming well-defined nanostructures over macroscopic areas. Yet, the inherent energy minimization criteria of self-assembly give rise to a limited library of structures; diblock copolymers naturally form spheres on a cubic lattice, hexagonally packed cylinders and alternating lamellae. Here, we demonstrate multicomponent nanomeshes with any desired lattice symmetry. We exploit photothermal annealing to rapidly order and align block copolymer phases over macroscopic areas, combined with conversion of the self-assembled organic phase into inorganic replicas. Repeated photothermal processing independently aligns successive layers, providing full control of the size, symmetry and composition of the nanoscale unit cell. We construct a variety of symmetries, most of which are not natively formed by block copolymers, including squares, rhombuses, rectangles and triangles. In fact, we demonstrate all possible two-dimensional Bravais lattices. Finally, we elucidate the influence of nanostructure on the electrical and optical properties of nanomeshes. PMID:26100566

  9. Lattice Strain Defects in a Ceria Nanolayer

    PubMed Central

    2016-01-01

    An ultrathin two-dimensional CeO2 (ceria) phase on a Cu(110) surface has been fabricated and fully characterized by high-resolution scanning tunneling microscopy, photoelectron spectroscopy, and density functional theory. The atomic lattice structure of the ceria/Cu(110) system is revealed as a hexagonal CeO2(111)-type monolayer separated from the Cu(110) surface by a partly disordered Cu–O intercalated buffer layer. The epitaxial coupling of the two-dimensional ceria overlayer to the Cu(110)-O surface leads to a nanoscopic stripe pattern, which creates defect regions of quasi-periodic lattice distortions. The symmetry and lattice mismatch at the interface is clarified to be responsible for the topographic stripe geometry and the related anisotropic strain defect regions at the ceria surface. This ceria monolayer is in a fully oxidized and thermodynamically stable state. PMID:26988695

  10. Lattice Strain Defects in a Ceria Nanolayer.

    PubMed

    Ma, Liying; Doudin, Nassar; Surnev, Svetlozar; Barcaro, Giovanni; Sementa, Luca; Fortunelli, Alessandro; Netzer, Falko P

    2016-04-07

    An ultrathin two-dimensional CeO2 (ceria) phase on a Cu(110) surface has been fabricated and fully characterized by high-resolution scanning tunneling microscopy, photoelectron spectroscopy, and density functional theory. The atomic lattice structure of the ceria/Cu(110) system is revealed as a hexagonal CeO2(111)-type monolayer separated from the Cu(110) surface by a partly disordered Cu-O intercalated buffer layer. The epitaxial coupling of the two-dimensional ceria overlayer to the Cu(110)-O surface leads to a nanoscopic stripe pattern, which creates defect regions of quasi-periodic lattice distortions. The symmetry and lattice mismatch at the interface is clarified to be responsible for the topographic stripe geometry and the related anisotropic strain defect regions at the ceria surface. This ceria monolayer is in a fully oxidized and thermodynamically stable state.

  11. Crystal lattice imaging of the silica and alumina faces of kaolinite using atomic force microscopy.

    PubMed

    Gupta, Vishal; Hampton, Marc A; Nguyen, Anh V; Miller, Jan D

    2010-12-01

    The crystal lattice images of the two faces of kaolinite (the silica face and the alumina face) have been obtained using contact-mode atomic force microscopy (AFM) under ambient conditions. Lattice resolution images reveal the hexagonal surface lattice of these two faces of kaolinite. Analysis of the silica face of kaolinite showed that the hexagonal surface lattice ring of oxygen atoms had a periodicity of 0.50±0.04nm between neighboring oxygen atoms, which is in good agreement with the surface lattice structure of the mica basal plane. The center of the hexagonal ring of oxygen atoms is vacant. Analysis of the alumina face of kaolinite showed that the hexagonal surface lattice ring of hydroxyls surround a hydroxyl in the center of the ring. The atomic spacing between neighboring hydroxyls was determined as 0.36±0.04nm. Ordering of the kaolinite particles for examination of the silica and alumina surfaces was accomplished using different substrates, a procedure previously established. Crystal lattice imaging supports previous results and independently confirms that the two faces of kaolinite have been properly identified.

  12. Imperfection Insensitivity Analyses of Advanced Composite Tow-Steered Shells

    NASA Technical Reports Server (NTRS)

    Wu, K. Chauncey; Farrokh, Babak; Stanford, Bret K.; Weaver, Paul M.

    2016-01-01

    Two advanced composite tow-steered shells, one with tow overlaps and another without overlaps, were previously designed, fabricated and tested in end compression, both without cutouts, and with small and large cutouts. In each case, good agreement was observed between experimental buckling loads and supporting linear bifurcation buckling analyses. However, previous buckling tests and analyses have shown historically poor correlation, perhaps due to the presence of geometric imperfections that serve as failure initiators. For the tow-steered shells, their circumferential variation in axial stiffness may have suppressed this sensitivity to imperfections, leading to the agreement noted between tests and analyses. To investigate this further, a numerical investigation was performed in this study using geometric imperfections measured from both shells. Finite element models of both shells were analyzed first without, and then, with measured imperfections that were then, superposed in different orientations around the shell longitudinal axis. Small variations in both the axial prebuckling stiffness and global buckling load were observed for the range of imperfections studied here, which suggests that the tow steering, and resulting circumferentially varying axial stiffness, may result in the test-analysis correlation observed for these shells.

  13. Pin-wheel hexagons: a model for anthraquinone ordering on Cu(111).

    PubMed

    Simenas, M; Tornau, E E

    2013-10-21

    The 4-state model of anthraquinone molecules ordering in a pin-wheel large-pore honeycomb phase on Cu(111) is proposed and solved by Monte Carlo simulation. The model is defined on a rescaled triangular lattice with the lattice constant a being equal to intermolecular distance in the honeycomb phase. The pin-wheel triangle formations are obtained taking into account the elongated shape of the molecules and anisotropic interactions for main two attractive short range (double and single dimeric) H-bond interactions. The long-range intermolecular interactions, corresponding to repulsive dipole-dipole forces, are assumed to be isotropic. Also, a very small (compared to short-range forces) isotropic attractive long-range interaction at the "characteristic" distance of a pore diameter is employed, and its effect carefully studied. This interaction is crucial for a formation of closed porous ordered systems, pin-wheel hexagons in particular. If each side of a pin-wheel hexagon is formed of n parallel molecules, the distance of this characteristic interaction is a√(3n(2)+1). The phase diagrams including different pin-wheel hexagon phases and a variety of other ordered structures are obtained. By changing the distance of characteristic interaction, different ordering routes into the experimental pin-wheel honeycomb phase are explored. The results obtained imply that classical explanation of the origin of the pin-wheel honeycomb phase in terms of some balance of attractive and repulsive forces cannot be totally discounted yet.

  14. Micropolar dissipative models for the analysis of 2D dispersive waves in periodic lattices

    NASA Astrophysics Data System (ADS)

    Reda, H.; Ganghoffer, J. F.; Lakiss, H.

    2017-03-01

    The computation of the dispersion relations for dissipative periodic lattices having the attributes of metamaterials is an actual research topic raising the interest of researchers in the field of acoustics and wave propagation phenomena. We analyze in this contribution the impact of wave damping on the dispersion features of periodic lattices, which are modeled as beam-lattices. The band diagram structure and damping ratio are computed for different repetitive lattices, based on the homogenized continuum response of the initially discrete lattice architecture, modeled as Kelvin-Voigt viscoelastic beams. Three of these lattices (reentrant hexagonal, chiral diamond, hexachiral lattice) are auxetic metamaterials, since they show negative Poisson's ratio. The effective viscoelastic anisotropic continuum behavior of the lattices is first computed in terms of the homogenized stiffness and viscosity matrices, based on the discrete homogenization technique. The dynamical equations of motion are obtained for an equivalent homogenized micropolar continuum evaluated based on the homogenized properties, and the dispersion relation and damping ratio are obtained by inserting an harmonic plane waves Ansatz into these equations. The comparison of the acoustic properties obtained in the low frequency range for the four considered lattices shows that auxetic lattices attenuate waves at lower frequencies compared to the classical hexagonal lattice. The diamond chiral lattice shows the best attenuation properties of harmonic waves over the entire Brillouin zone, and the hexachiral lattice presents better acoustic properties than the reentrant hexagonal lattice. The range of validity of the effective continuum obtained by the discrete homogenization has been assessed by comparing the frequency band structure of this continuum with that obtained by a Floquet-Bloch analysis.

  15. Formation of hexagonal and cubic ice during low-temperature growth.

    PubMed

    Thürmer, Konrad; Nie, Shu

    2013-07-16

    From our daily life we are familiar with hexagonal ice, but at very low temperature ice can exist in a different structure--that of cubic ice. Seeking to unravel the enigmatic relationship between these two low-pressure phases, we examined their formation on a Pt(111) substrate at low temperatures with scanning tunneling microscopy and atomic force microscopy. After completion of the one-molecule-thick wetting layer, 3D clusters of hexagonal ice grow via layer nucleation. The coalescence of these clusters creates a rich scenario of domain-boundary and screw-dislocation formation. We discovered that during subsequent growth, domain boundaries are replaced by growth spirals around screw dislocations, and that the nature of these spirals determines whether ice adopts the cubic or the hexagonal structure. Initially, most of these spirals are single, i.e., they host a screw dislocation with a Burgers vector connecting neighboring molecular planes, and produce cubic ice. Films thicker than ~20 nm, however, are dominated by double spirals. Their abundance is surprising because they require a Burgers vector spanning two molecular-layer spacings, distorting the crystal lattice to a larger extent. We propose that these double spirals grow at the expense of the initially more common single spirals for an energetic reason: they produce hexagonal ice.

  16. B27-: Appearance of the smallest planar boron cluster containing a hexagonal vacancy

    NASA Astrophysics Data System (ADS)

    Li, Wei-Li; Pal, Rhitankar; Piazza, Zachary A.; Zeng, Xiao Cheng; Wang, Lai-Sheng

    2015-05-01

    Photoelectron spectroscopy and ab initio calculations have been carried out to probe the structures and chemical bonding of the B27- cluster. Comparison between the experimental spectrum and the theoretical results reveals a two-dimensional (2D) global minimum with a triangular lattice containing a tetragonal defect (I) and two low-lying 2D isomers (II and III), each with a hexagonal vacancy. All three 2D isomers have 16 peripheral boron atoms and 11 inner boron atoms. Isomer I is shown to be mainly responsible for the observed photoelectron spectrum with isomers II and III as minor contributors. Chemical bonding analyses of these three isomers show that they all feature 16 localized peripheral B-B σ-bonds. Additionally, isomer I possesses 16 delocalized σ bonds and nine delocalized π bonds, while isomers II and III each contain 17 delocalized σ bonds and eight delocalized π bonds. It is found that the hexagonal vacancy is associated generally with an increase of delocalized σ bonds at the expense of delocalized π bonds in 2D boron clusters. The hexagonal vacancy, characteristic of borophenes, is found to be a general structural feature for mid-sized boron clusters. The current study shows that B27- is the first boron cluster, where a hexagonal vacancy appears among the low-lying isomers accessible experimentally.

  17. Disclinations in square and hexagonal patterns.

    PubMed

    Golovin, A A; Nepomnyashchy, A A

    2003-05-01

    We report the observation of defects with fractional topological charges (disclinations) in square and hexagonal patterns as numerical solutions of several generic equations describing many pattern-forming systems: Swift-Hohenberg equation, damped Kuramoto-Sivashinsky equation, as well as nonlinear evolution equations describing large-scale Rayleigh-Benard and Marangoni convection in systems with thermally nearly insulated boundaries. It is found that disclinations in square and hexagonal patterns can be stable when nucleated from special initial conditions. The structure of the disclinations is analyzed by means of generalized Cross-Newell equations.

  18. Localization and delocalization of ultracold bosonic atoms in finite optical lattices

    SciTech Connect

    Luehmann, Dirk-Soeren; Pfannkuche, Daniela; Bongs, Kai; Sengstock, Klaus

    2008-02-15

    We study bosonic atoms in small optical lattices by exact diagonalization and observe a striking similarity to the superfluid to Mott insulator transition in macroscopic systems. The momentum distribution, the formation of an energy gap, and the pair correlation function show only a weak size dependence. For noncommensurate filling we reveal in deep lattices a mixture of localized and delocalized particles, which is sensitive to lattice imperfections. Breaking the lattice symmetry causes a Bose-glass-like behavior. We discuss the nature of excited states and orbital effects by using an exact diagonalization technique that includes higher bands.

  19. Multiwave diffraction, phase problem, and extinction in imperfect crystals

    SciTech Connect

    Dmitrienko, V. E.

    2009-11-15

    The extinction effects of multiwave diffraction in imperfect crystals have been investigated. It is shown that the presence of extinction in the direct diffraction channel may lead to errors in determining the relative phases of structural amplitudes by the multiwave diffraction method (i.e., by interference with indirect excitation). The reason is that the dependence of the reflection intensity on the structural amplitude in imperfect crystals is generally nonquadratic (as in the kinematic theory), nonlinear (as in the dynamic theory), and is not even somewhat intermediate. These effects open up new possibilities for using multiwave diffraction for the direct study of the extinction and, therefore, quantitatively characterize the imperfection of crystal structures with known values and phases of structural amplitudes.

  20. Topological Properties of Electrons in Honeycomb Lattice with Detuned Hopping Energy

    PubMed Central

    Wu, Long-Hua; Hu, Xiao

    2016-01-01

    Honeycomb lattice can support electronic states exhibiting Dirac energy dispersion, with graphene as the icon. We propose to derive nontrivial topology by grouping six neighboring sites of honeycomb lattice into hexagons and enhancing the inter-hexagon hopping energies over the intra-hexagon ones. We reveal that this manipulation opens a gap in the energy dispersion and drives the system into a topological state. The nontrivial topology is characterized by the index associated with a pseudo time-reversal symmetry emerging from the C6 symmetry of the hopping texture, where the angular momentum of orbitals accommodated on the hexagonal “artificial atoms” behaves as the pseudospin. The size of topological gap is proportional to the hopping-energy difference, which can be larger than typical spin-orbit couplings by orders of magnitude and potentially renders topological electronic transports available at high temperatures. PMID:27076196

  1. Hexagonal Boron Nitride Tunnel Barriers Grown on Graphite by High Temperature Molecular Beam Epitaxy.

    PubMed

    Cho, Yong-Jin; Summerfield, Alex; Davies, Andrew; Cheng, Tin S; Smith, Emily F; Mellor, Christopher J; Khlobystov, Andrei N; Foxon, C Thomas; Eaves, Laurence; Beton, Peter H; Novikov, Sergei V

    2016-09-29

    We demonstrate direct epitaxial growth of high-quality hexagonal boron nitride (hBN) layers on graphite using high-temperature plasma-assisted molecular beam epitaxy. Atomic force microscopy reveals mono- and few-layer island growth, while conducting atomic force microscopy shows that the grown hBN has a resistance which increases exponentially with the number of layers, and has electrical properties comparable to exfoliated hBN. X-ray photoelectron spectroscopy, Raman microscopy and spectroscopic ellipsometry measurements on hBN confirm the formation of sp(2)-bonded hBN and a band gap of 5.9 ± 0.1 eV with no chemical intermixing with graphite. We also observe hexagonal moiré patterns with a period of 15 nm, consistent with the alignment of the hBN lattice and the graphite substrate.

  2. Synthesis of hexagonal lanthanum germanate apatites through site selective isovalent doping with yttrium

    SciTech Connect

    Kendrick, E.; Slater, P.R.

    2008-08-04

    Apatite-type lanthanum silicates/germanates have been attracting considerable interest as a new class of oxide ion conductors, whose conductivity is mediated by oxide ion interstitials. For the germanates, it has been shown that, depending on composition, the cell can be either hexagonal or triclinic, with evidence for reduced low-temperature conductivities for the latter, attributed to increased defect trapping in this lower symmetry cell. In this paper we show that site selective doping of Y into the triclinic apatite-type oxide ion conductors, La{sub 9.33+z}(GeO{sub 4}){sub 6}O{sub 2+3z/2} (0.33 {<=} z {<=} 0.67) results in a hexagonal lattice for the complete series with correspondingly enhanced low-temperature conductivity.

  3. Hexagonal Boron Nitride Tunnel Barriers Grown on Graphite by High Temperature Molecular Beam Epitaxy

    NASA Astrophysics Data System (ADS)

    Cho, Yong-Jin; Summerfield, Alex; Davies, Andrew; Cheng, Tin S.; Smith, Emily F.; Mellor, Christopher J.; Khlobystov, Andrei N.; Foxon, C. Thomas; Eaves, Laurence; Beton, Peter H.; Novikov, Sergei V.

    2016-09-01

    We demonstrate direct epitaxial growth of high-quality hexagonal boron nitride (hBN) layers on graphite using high-temperature plasma-assisted molecular beam epitaxy. Atomic force microscopy reveals mono- and few-layer island growth, while conducting atomic force microscopy shows that the grown hBN has a resistance which increases exponentially with the number of layers, and has electrical properties comparable to exfoliated hBN. X-ray photoelectron spectroscopy, Raman microscopy and spectroscopic ellipsometry measurements on hBN confirm the formation of sp2-bonded hBN and a band gap of 5.9 ± 0.1 eV with no chemical intermixing with graphite. We also observe hexagonal moiré patterns with a period of 15 nm, consistent with the alignment of the hBN lattice and the graphite substrate.

  4. Hexagonal Boron Nitride Tunnel Barriers Grown on Graphite by High Temperature Molecular Beam Epitaxy

    PubMed Central

    Cho, Yong-Jin; Summerfield, Alex; Davies, Andrew; Cheng, Tin S.; Smith, Emily F.; Mellor, Christopher J.; Khlobystov, Andrei N.; Foxon, C. Thomas; Eaves, Laurence; Beton, Peter H.; Novikov, Sergei V.

    2016-01-01

    We demonstrate direct epitaxial growth of high-quality hexagonal boron nitride (hBN) layers on graphite using high-temperature plasma-assisted molecular beam epitaxy. Atomic force microscopy reveals mono- and few-layer island growth, while conducting atomic force microscopy shows that the grown hBN has a resistance which increases exponentially with the number of layers, and has electrical properties comparable to exfoliated hBN. X-ray photoelectron spectroscopy, Raman microscopy and spectroscopic ellipsometry measurements on hBN confirm the formation of sp2-bonded hBN and a band gap of 5.9 ± 0.1 eV with no chemical intermixing with graphite. We also observe hexagonal moiré patterns with a period of 15 nm, consistent with the alignment of the hBN lattice and the graphite substrate. PMID:27681943

  5. A composite nodal finite element for hexagons

    SciTech Connect

    Hennart, J.P.; Mund, E.H. |; Valle, E. Del

    1997-10-01

    A nodal algorithm for the solution of the multigroup diffusion equations in hexagonal arrays is analyzed. Basically, the method consists of dividing each hexagon into four quarters and mapping the hexagon quarters onto squares. The resulting boundary value problem on a quadrangular domain is solved in primal weak formulation. Nodal finite element methods like the Raviart-Thomas RTk schemes provide accurate analytical expansions of the solution in the hexagons. Transverse integration cannot be performed on the equations in the quadrangular domain as simply as it is usually done on squares because these equations have essentially variable coefficients. However, by considering an auxiliary problem with constant coefficients (on the same quadrangular domain) and by using a preconditioning approach, transverse integration can be performed as for rectangular geometry. A description of the algorithm is given for a one-group diffusion equation. Numerical results are presented for a simple model problem with a known analytical solution and for k{sub eff} evaluations of some benchmark problems proposed in the literature. For the analytical problem, the results indicate that the theoretical convergence orders of RTk schemes (k = 0,1) are obtained, yielding accurate solutions at the expense of a few preconditioning iterations.

  6. Hexagonal and Pentagonal Fractal Multiband Antennas

    NASA Technical Reports Server (NTRS)

    Tang, Philip W.; Wahid, Parveen

    2005-01-01

    Multiband dipole antennas based on hexagonal and pentagonal fractals have been analyzed by computational simulations and functionally demonstrated in experiments on prototypes. These antennas are capable of multiband or wide-band operation because they are subdivided into progressively smaller substructures that resonate at progressively higher frequencies by virtue of their smaller dimensions. The novelty of the present antennas lies in their specific hexagonal and pentagonal fractal configurations and the resonant frequencies associated with them. These antennas are potentially applicable to a variety of multiband and wide-band commercial wireless-communication products operating at different frequencies, including personal digital assistants, cellular telephones, pagers, satellite radios, Global Positioning System receivers, and products that combine two or more of the aforementioned functions. Perhaps the best-known prior multiband antenna based on fractal geometry is the Sierpinski triangle antenna (also known as the Sierpinski gasket), shown in the top part of the figure. In this antenna, the scale length at each iteration of the fractal is half the scale length of the preceding iteration, yielding successive resonant frequencies related by a ratio of about 2. The middle and bottom parts of the figure depict the first three iterations of the hexagonal and pentagonal fractals along with typical dipole-antenna configuration based on the second iteration. Successive resonant frequencies of the hexagonal fractal antenna have been found to be related by a ratio of about 3, and those of the pentagonal fractal antenna by a ratio of about 2.59.

  7. Intrinsic ferromagnetism in hexagonal boron nitride nanosheets

    SciTech Connect

    Si, M. S.; Gao, Daqiang E-mail: xueds@lzu.edu.cn; Yang, Dezheng; Peng, Yong; Zhang, Z. Y.; Xue, Desheng E-mail: xueds@lzu.edu.cn; Liu, Yushen; Deng, Xiaohui; Zhang, G. P.

    2014-05-28

    Understanding the mechanism of ferromagnetism in hexagonal boron nitride nanosheets, which possess only s and p electrons in comparison with normal ferromagnets based on localized d or f electrons, is a current challenge. In this work, we report an experimental finding that the ferromagnetic coupling is an intrinsic property of hexagonal boron nitride nanosheets, which has never been reported before. Moreover, we further confirm it from ab initio calculations. We show that the measured ferromagnetism should be attributed to the localized π states at edges, where the electron-electron interaction plays the role in this ferromagnetic ordering. More importantly, we demonstrate such edge-induced ferromagnetism causes a high Curie temperature well above room temperature. Our systematical work, including experimental measurements and theoretical confirmation, proves that such unusual room temperature ferromagnetism in hexagonal boron nitride nanosheets is edge-dependent, similar to widely reported graphene-based materials. It is believed that this work will open new perspectives for hexagonal boron nitride spintronic devices.

  8. Intrinsic ferromagnetism in hexagonal boron nitride nanosheets.

    PubMed

    Si, M S; Gao, Daqiang; Yang, Dezheng; Peng, Yong; Zhang, Z Y; Xue, Desheng; Liu, Yushen; Deng, Xiaohui; Zhang, G P

    2014-05-28

    Understanding the mechanism of ferromagnetism in hexagonal boron nitride nanosheets, which possess only s and p electrons in comparison with normal ferromagnets based on localized d or f electrons, is a current challenge. In this work, we report an experimental finding that the ferromagnetic coupling is an intrinsic property of hexagonal boron nitride nanosheets, which has never been reported before. Moreover, we further confirm it from ab initio calculations. We show that the measured ferromagnetism should be attributed to the localized π states at edges, where the electron-electron interaction plays the role in this ferromagnetic ordering. More importantly, we demonstrate such edge-induced ferromagnetism causes a high Curie temperature well above room temperature. Our systematical work, including experimental measurements and theoretical confirmation, proves that such unusual room temperature ferromagnetism in hexagonal boron nitride nanosheets is edge-dependent, similar to widely reported graphene-based materials. It is believed that this work will open new perspectives for hexagonal boron nitride spintronic devices.

  9. Intrinsic ferromagnetism in hexagonal boron nitride nanosheets

    NASA Astrophysics Data System (ADS)

    Si, M. S.; Gao, Daqiang; Yang, Dezheng; Peng, Yong; Zhang, Z. Y.; Xue, Desheng; Liu, Yushen; Deng, Xiaohui; Zhang, G. P.

    2014-05-01

    Understanding the mechanism of ferromagnetism in hexagonal boron nitride nanosheets, which possess only s and p electrons in comparison with normal ferromagnets based on localized d or f electrons, is a current challenge. In this work, we report an experimental finding that the ferromagnetic coupling is an intrinsic property of hexagonal boron nitride nanosheets, which has never been reported before. Moreover, we further confirm it from ab initio calculations. We show that the measured ferromagnetism should be attributed to the localized π states at edges, where the electron-electron interaction plays the role in this ferromagnetic ordering. More importantly, we demonstrate such edge-induced ferromagnetism causes a high Curie temperature well above room temperature. Our systematical work, including experimental measurements and theoretical confirmation, proves that such unusual room temperature ferromagnetism in hexagonal boron nitride nanosheets is edge-dependent, similar to widely reported graphene-based materials. It is believed that this work will open new perspectives for hexagonal boron nitride spintronic devices.

  10. Powdered Hexagonal Boron Nitride Reducing Nanoscale Wear

    NASA Astrophysics Data System (ADS)

    Chkhartishvili, L.; Matcharashvili, T.; Esiava, R.; Tsagareishvili, O.; Gabunia, D.; Margiev, B.; Gachechiladze, A.

    2013-05-01

    A morphology model is suggested for nano-powdered hexagonal boron nitride that can serve as an effective solid additive to liquid lubricants. It allows to estimate the specific surface, that is a hard-to-measure parameter, based on average size of powder particles. The model can be used also to control nanoscale wear processes.

  11. Hexagonal ferrites for millimeter wave applications

    NASA Astrophysics Data System (ADS)

    Polk, Donald E.; Hathaway, Kristl B.

    1993-01-01

    A review of the work accomplished on this contract is presented. A review of the physics of hexagonal ferrite materials and the effective linewidth concept and the detailed overall research plan are contained in the original proposal document. The focus of the program was on the effective linewidth in millimeter wave materials, including planar hexagonal ferrite Y-type materials, uniaxial M-type materials, and thin ferromagnetic transition metal and alloy films. The key idea in the original proposal was that the ferromagnetic resonance (FMR) linewidth in hexagonal ferrites is dominated by inhomogeneous and two-magnon scattering losses and that off-resonance measurements of the effective linewidth would (1) show that the FMR losses do not represent the intrinsic losses, and (2) that the intrinsic losses are significantly lower. This basic idea was verified. Results were obtained on the off-resonance far-field effective linewidth in planar Zn-Y hexagonal ferrite single crystal platelets, single crystal spheres of Ba- and Sr-hexaferrite materials, and permalloy thin films. Three papers on these results were published.

  12. Evaluation Strategies in Financial Education: Evaluation with Imperfect Instruments

    ERIC Educational Resources Information Center

    Robinson, Lauren; Dudensing, Rebekka; Granovsky, Nancy L.

    2016-01-01

    Program evaluation often suffers due to time constraints, imperfect instruments, incomplete data, and the need to report standardized metrics. This article about the evaluation process for the Wi$eUp financial education program showcases the difficulties inherent in evaluation and suggests best practices for assessing program effectiveness. We…

  13. Imperfect two-dimensional topological insulator field-effect transistors

    NASA Astrophysics Data System (ADS)

    Vandenberghe, William G.; Fischetti, Massimo V.

    2017-01-01

    To overcome the challenge of using two-dimensional materials for nanoelectronic devices, we propose two-dimensional topological insulator field-effect transistors that switch based on the modulation of scattering. We model transistors made of two-dimensional topological insulator ribbons accounting for scattering with phonons and imperfections. In the on-state, the Fermi level lies in the bulk bandgap and the electrons travel ballistically through the topologically protected edge states even in the presence of imperfections. In the off-state the Fermi level moves into the bandgap and electrons suffer from severe back-scattering. An off-current more than two-orders below the on-current is demonstrated and a high on-current is maintained even in the presence of imperfections. At low drain-source bias, the output characteristics are like those of conventional field-effect transistors, at large drain-source bias negative differential resistance is revealed. Complementary n- and p-type devices can be made enabling high-performance and low-power electronic circuits using imperfect two-dimensional topological insulators.

  14. Imperfect two-dimensional topological insulator field-effect transistors.

    PubMed

    Vandenberghe, William G; Fischetti, Massimo V

    2017-01-20

    To overcome the challenge of using two-dimensional materials for nanoelectronic devices, we propose two-dimensional topological insulator field-effect transistors that switch based on the modulation of scattering. We model transistors made of two-dimensional topological insulator ribbons accounting for scattering with phonons and imperfections. In the on-state, the Fermi level lies in the bulk bandgap and the electrons travel ballistically through the topologically protected edge states even in the presence of imperfections. In the off-state the Fermi level moves into the bandgap and electrons suffer from severe back-scattering. An off-current more than two-orders below the on-current is demonstrated and a high on-current is maintained even in the presence of imperfections. At low drain-source bias, the output characteristics are like those of conventional field-effect transistors, at large drain-source bias negative differential resistance is revealed. Complementary n- and p-type devices can be made enabling high-performance and low-power electronic circuits using imperfect two-dimensional topological insulators.

  15. Imperfect two-dimensional topological insulator field-effect transistors

    PubMed Central

    Vandenberghe, William G.; Fischetti, Massimo V.

    2017-01-01

    To overcome the challenge of using two-dimensional materials for nanoelectronic devices, we propose two-dimensional topological insulator field-effect transistors that switch based on the modulation of scattering. We model transistors made of two-dimensional topological insulator ribbons accounting for scattering with phonons and imperfections. In the on-state, the Fermi level lies in the bulk bandgap and the electrons travel ballistically through the topologically protected edge states even in the presence of imperfections. In the off-state the Fermi level moves into the bandgap and electrons suffer from severe back-scattering. An off-current more than two-orders below the on-current is demonstrated and a high on-current is maintained even in the presence of imperfections. At low drain-source bias, the output characteristics are like those of conventional field-effect transistors, at large drain-source bias negative differential resistance is revealed. Complementary n- and p-type devices can be made enabling high-performance and low-power electronic circuits using imperfect two-dimensional topological insulators. PMID:28106059

  16. Stability of the laminar boundary layer for an imperfect gas

    NASA Astrophysics Data System (ADS)

    Gasperas, G.

    The linear perturbation equations are derived for the general case of a compressible imperfect gas characterized by an equation of state utilizing a compressibility factor. The specific case of the Beattie-Bridgeman gas is chosen for calculation. Amplification curves calculated using the Beattie-Bridgeman equation of state for two representative flat plate boundary layers are presented.

  17. Coherent detection of multiamplitude MSK under imperfect phase synchronisation

    NASA Astrophysics Data System (ADS)

    Goncalves, V.; Gusmao, A.; Esteves, N.

    1991-04-01

    Simple formulas for the BER performance achieved through coherent detection of MAMSK signals, under a carrier phase error, are presented. It is shown that MAMSK schemes are much less sensitive to imperfect carrier recovery than the corresponding QAM schemes, this advantage being especially clear when serial detection is employed. Possible applications to future TDMA satellite systems are emphasized.

  18. Electron Distributions in Hexagonal Selenium and Tellurium and Monoclinic Selenium with Dilute Impurities and Associated Nuclear Quadrupole Interactions*.

    NASA Astrophysics Data System (ADS)

    Maharjan, N. B.; Paudyal, D. D.; Mishra, D. R.; Byahut, S.; Aryal, M. M.; Cho, Hwa-Suck; Scheicher, R. H.; Chow, Lee; Jeong, Junho; Das, T. P.

    2006-03-01

    The electron structures of Selenium chains and rings with Te impurities in hexagonal and monoclinic structures respectively and Se impurities in Te chains in hexagonal lattice have been studied using Hartree-Fock cluster model including many-body effects, including lattice relaxation effects. The calculated electronic wave-functions are utilized to obtain ^77Se and ^125Te nuclear quadrupole coupling constants e^2qQ and asymmetry parameters η and compared with available experimental data from Mossbauer and perturbed angular correlation measurements. From our results, the expected nature of nuclear quadrupole interactions associated with Sb impurities will be discussed. *Supported by NSF US-Nepal Program and UGC Nepal **Also at UCF, Orlando

  19. Complex magnetism of Ho-Dy-Y-Gd-Tb hexagonal high-entropy alloy

    NASA Astrophysics Data System (ADS)

    Lužnik, J.; Koželj, P.; Vrtnik, S.; Jelen, A.; Jagličić, Z.; Meden, A.; Feuerbacher, M.; Dolinšek, J.

    2015-12-01

    Rare earth based equimolar Ho-Dy-Y-Gd-Tb hexagonal high-entropy alloy (HEA) is a prototype of an ideal HEA, stabilized by the entropy of mixing at any temperature with random mixing of elements on the hexagonal close-packed lattice. In order to determine intrinsic properties of an ideal HEA characterized by the enormous chemical (substitutional) disorder on a weakly distorted simple lattice, we have performed measurements of its magnetic and electrical response and the specific heat. The results show that the Ho-Dy-Y-Gd-Tb hexagonal HEA exhibits a rich and complex magnetic field-temperature (H ,T ) phase diagram, as a result of competition among the periodic potential arising from the electronic band structure that favors periodic magnetic ordering, the disorder-induced local random potential that favors spin glass-type spin freezing in random directions, the Zeeman interaction with the external field that favors spin alignment along the field direction, and the thermal agitation that opposes any spin ordering. Three characteristic temperature regions were identified in the (H ,T ) phase diagram between room temperature and 2 K. Within the upper temperature region I (roughly between 300 and 75 K), thermal fluctuations average out the effect of local random pinning potential and the spin system behaves as a pure system of compositionally averaged spins, undergoing a thermodynamic phase transition to a long-range ordered helical antiferromagnetic state at the Néel temperature TN=180 K that is a compositional average of the Néel temperatures of pure Tb, Dy, and Ho metals. Region II (between 75 and 20 K) is an intermediate region where the long-range periodic spin order "melts" and the random ordering of spins in the local random potential starts to prevail. Within the low-temperature region III (below 20 K), the spins gradually freeze in a spin glass configuration. The spin glass phase appears to be specific to the rare earths containing hexagonal HEAs, sharing

  20. An X-ray scattering study of flow-aligned samples of a lyotropic liquid-crystalline hexagonal phase

    NASA Astrophysics Data System (ADS)

    Impéror-Clerc, M.; Davidson, P.

    Large flow-aligned samples of the hexagonal mesophase of the (sodium dodecylsulfate, pentanol, water) ternary system were produced by merely sucking the material into flat glass capillaries. These samples were examined by polarized light microscopy and X-ray scattering. In the plane of the hexagonal lattice, the `` -mosaic'' is only because the dense (10) hexagonal planes lie parallel to the flat glass plates of the capillaries. In contrast, the `` -mosaic'' of the C6 axis reaches 5-10 because the samples undergo a thermomechanical instability of the columns already investigated by Oswald et al. in detail on the (C12EO6, H2O) system. Anisotropic thermal diffuse scattering is observed around the Bragg peaks and its description in the frame of an elastic continuum model provides estimates of the elastic constants. On heating the samples, we observed a clear splitting of four of the (10) hexagonal lattice reflections. This splitting is the defining signature of the thermomechanical instability by which the columns form zig-zags. The fact that two of the (10) reflections are not affected by the instability demonstrates that it is confined to the plane of the capillary. The influence of temperature on the thermomechanical instability was also studied in detail.

  1. Temperature and field dependence of the flux-line-lattice symmetry in V{sub 3}Si

    SciTech Connect

    Yethiraj, M.; Christen, D.K.; Gapud, A.A.; Paul, D. McK.; Crowe, S.J.; Dewhurst, C.D.; Cubitt, R.; Porcar, L.; Gurevich, A.

    2005-08-01

    In V{sub 3}Si, a first-order structural phase transition from hexagonal to square flux-line lattice occurs at approximately 1 T with H parallel to the a axis. In this paper, we demonstrate the reentrant structural transition in the flux-line lattice, which reverts to hexagonal symmetry as the magnetic field approached H{sub c2}(T). This behavior is described very well by a nonlocal London theory with thermal fluctuations. The phase diagram of the flux lattice topology is mapped out for this geometry.

  2. Lysozyme entrapped within reverse hexagonal mesophases: physical properties and structural behavior.

    PubMed

    Mishraki, Tehila; Libster, Dima; Aserin, Abraham; Garti, Nissim

    2010-01-01

    A model protein (lysozyme) was incorporated into monoolein-based reverse hexagonal (H(II)) mesophase and its structure effects were characterized by small angle X-ray scattering, ATR-FTIR spectroscopy, and rheological measurements. Modifications in molecular organization of the H(II) mesophases as well as the conformational stability of lysozyme (LSZ) as a function of pH and denaturating agent (urea) were clarified. Up to 3 wt.% LSZ can be solubilized into the H(II). The vibration FTIR analysis revealed that LSZ interacted with OH groups of glycerol monooleate (GMO) in the outer interface region, resulting in strong hydrogen bonding between the surfactant and its environment. Simultaneously, the decrease in the hydrogen-bonded carbonyl population of GMO was monitored, indicating dehydration of the monoolein carbonyls. These molecular interactions yielded a minor decrease in the lattice parameter of the systems, as detected by small angle X-ray scattering. Furthermore, LSZ was crystallized within the medium of the hexagonal structures in a single crystal form. The alpha-helix conformation of lysozyme was stabilized at high pH conditions, demonstrating greater helical structure content, compared to D(2)O solution. Moreover, the hexagonal phase decreased the unfavorable alpha-->beta transition in lysozyme, thereby increasing the stability of the protein under chemical denaturation. The rheological behavior of the hexagonal structures varied with the incorporation of LSZ, reflected in stronger elastic properties and pronounced solid-like response of the systems. The hydrogen bonding enhancement in the interface region of the structures was most likely responsible for these phenomena. The results of this study provided valuable information on the use of hexagonal systems as a carrier for incorporation and stabilization of proteins for various applications.

  3. Chain hexagonal cacti with the extremal eccentric distance sum.

    PubMed

    Qu, Hui; Yu, Guihai

    2014-01-01

    Eccentric distance sum (EDS), which can predict biological and physical properties, is a topological index based on the eccentricity of a graph. In this paper we characterize the chain hexagonal cactus with the minimal and the maximal eccentric distance sum among all chain hexagonal cacti of length n, respectively. Moreover, we present exact formulas for EDS of two types of hexagonal cacti.

  4. Chain Hexagonal Cacti with the Extremal Eccentric Distance Sum

    PubMed Central

    Qu, Hui

    2014-01-01

    Eccentric distance sum (EDS), which can predict biological and physical properties, is a topological index based on the eccentricity of a graph. In this paper we characterize the chain hexagonal cactus with the minimal and the maximal eccentric distance sum among all chain hexagonal cacti of length n, respectively. Moreover, we present exact formulas for EDS of two types of hexagonal cacti. PMID:24741365

  5. Nodal equivalence theory for hexagonal geometry, thermal reactor analysis

    SciTech Connect

    Zika, M.; Downar, T. )

    1992-01-01

    An important aspect of advanced nodal methods is the determination of equivalent few-group parameters for the relatively large homogenized regions used in the nodal flux solution. The theoretical foundation for light water reactor (LWR) assembly homogenization methods has been clearly established, and during the last several years, its successes have secured its position in the stable of dependable LWR analysis methods. Groupwise discontinuity factors that correct for assembly homogenization errors are routinely generated along with the group constants during lattice physics analysis. During the last several years, there has been interest in applying equivalence theory to other reactor types and other geometries. A notable effort has been the work at Argonne National Laboratory to incorporate nodal equivalence theory (NET) for hexagonal lattices into the nodal diffusion option of the DIF3D code. This work was originally intended to improve the neutronics methods used for the analysis of the Experimental Breeder Reactor II (EBR-II), and Ref. 4 discusses the success of that application. More recently, however, attempts were made to apply NET to advanced, thermal reactor designs such as the modular high-temperature gas reactor (MHTGR) and the new production heavy water reactor (NPR/HWR). The same methods that were successful for EBR-II have encountered problems for these reactors. Our preliminary analysis indicates that the sharp global flux gradients in these cores requires large discontinuity factors (greater than 4 or 5) to reproduce the reference solution. This disrupts the convergence of the iterative methods used to solve for the node-wise flux moments and partial currents. Several attempts to remedy the problem have been made over the last few years, including bounding the discontinuity factors and providing improved initial guesses for the flux solution, but nothing has been satisfactory.

  6. Formation of Hexagonal-Close Packed (HCP) Rhodium as a Size Effect.

    PubMed

    Huang, Jing Lu; Li, Zhi; Duan, Hao Hong; Cheng, Zhi Ying; Li, Ya Dong; Zhu, Jing; Yu, Rong

    2017-01-18

    Previous studies on the structural and functional properties of rhodium are based on the face-centered-cubic (fcc) structure in the bulk form. Here we report the first discovery of the hexagonal-close packed (hcp) rhodium in the nanoparticle form. The hcp Rh can be directly synthesized by solvothermal reaction or by electron-beam induced decomposition of Rh monolayers. The hcp Rh nanoparticles are stable under electron beam irradiation. Compared with the fcc structure, the hcp Rh nanoparticles show a large lattice expansion (6% larger atomic volume). The first-principles calculations suggest that the lower surface energy of hcp Rh leads to the size effect in the crystal structure.

  7. Graphene-hexagonal boron nitride resonant tunneling diodes as high-frequency oscillators

    SciTech Connect

    Gaskell, J.; Fromhold, T. M.; Greenaway, M. T.; Eaves, L.; Novoselov, K. S.; Mishchenko, A.; Geim, A. K.

    2015-09-07

    We assess the potential of two-terminal graphene-hexagonal boron nitride-graphene resonant tunneling diodes as high-frequency oscillators, using self-consistent quantum transport and electrostatic simulations to determine the time-dependent response of the diodes in a resonant circuit. We quantify how the frequency and power of the current oscillations depend on the diode and circuit parameters including the doping of the graphene electrodes, device geometry, alignment of the graphene lattices, and the circuit impedances. Our results indicate that current oscillations with frequencies of up to several hundred GHz should be achievable.

  8. First Brillouin Polytope and Band Structure of Diamond Lattice in Four Dimensions

    NASA Astrophysics Data System (ADS)

    Kato, Yuichi; Yamanaka, Masanori

    2017-03-01

    We study the diamond lattice in four dimensions — a descendant of the three-dimensional diamond lattice. As a four-dimensional polytope, we determine the first Brillouin zone and draw the band structure of the corresponding tight-binding model on two-dimensional paper in the usual manner. In the polyhedral decomposition, we find the zone boundary of the first Brillouin zone in four dimensions to be the omnitruncated 5-cell, which comprises ten truncated octahedra glued to 20 hexagonal prisms. We find Dirac line nodes inside the hexagonal prisms.

  9. Synthesis of silicon carbide hexagonal nanoprisms

    NASA Astrophysics Data System (ADS)

    Wu, R. B.; Yang, G. Y.; Pan, Y.; Chen, J. J.

    2007-02-01

    SiC hexagonal nanoprisms have been prepared by a reaction of multiwall carbon nanotubes and Si vapor in an Astro furnace at 1450 °C for 3 h. The polytype, morphology, crystal structure of the nanoprisms were studied by X-ray powder diffraction, scanning electron microscopy and high resolution transmission electron microscopy, showing their hexagonal nanoprism shapes with a 3C-SiC single crystal structure with a diameter of about 100 nm and 2 μm in length. The photoluminescence spectrum of the nanoprisms exhibits a significant blue-shift relative to bulk 3C-SiC and other nanostructured SiC. The possible growth mechanism that controls the nanostructure formation is also analysed.

  10. Multilayer hexagonal silicon forming in slit nanopore.

    PubMed

    He, Yezeng; Li, Hui; Sui, Yanwei; Qi, Jiqiu; Wang, Yanqing; Chen, Zheng; Dong, Jichen; Li, Xiongying

    2015-10-05

    The solidification of two-dimensional liquid silicon confined to a slit nanopore has been studied using molecular dynamics simulations. The results clearly show that the system undergoes an obvious transition from liquid to multilayer hexagonal film with the decrease of temperature, accompanied by dramatic change in potential energy, atomic volume, coordination number and lateral radial distribution function. During the cooling process, some hexagonal islands randomly appear in the liquid first, then grow up to grain nuclei, and finally connect together to form a complete polycrystalline film. Moreover, it is found that the quenching rate and slit size are of vital importance to the freezing structure of silicon film. The results also indicate that the slit nanopore induces the layering of liquid silicon, which further induces the slit size dependent solidification behavior of silicon film with different electrical properties.

  11. Hexagonal Ferrites for Millimeter Wave Applications

    DTIC Science & Technology

    1993-01-07

    single crystal platelets, single crystal spheres of Ba- and Sr- hexaferrite materials, and permalloy thin films. Three papers on these results have been...effective linewidth in planar Zn-Y hexagonal ferrite single crystal platelets, single crystal spheres of Ba- and Sr- hexaferrite materials, and...basic thesis of the original proposal - that the measured linewidth in single crystal hexaferrites (1) may contain significant contributions related to

  12. Exfoliation of Hexagonal Boron Nitride via Ferric Chloride Intercalation

    NASA Technical Reports Server (NTRS)

    Hung, Ching-cheh; Hurst, Janet; Santiago, Diana; Rogers, Richard B.

    2014-01-01

    Sodium fluoride (NaF) was used as an activation agent to successfully intercalate ferric chloride (FeCl3) into hexagonal boron nitride (hBN). This reaction caused the hBN mass to increase by approx.100 percent, the lattice parameter c to decrease from 6.6585 to between 6.6565 and 6.6569 ?, the x-ray diffraction (XRD) (002) peak to widen from 0.01deg to 0.05deg of the full width half maximum value, the Fourier transform infrared (FTIR) spectrum's broad band (1277/cm peak) to change shape, and new FTIR bands to emerge at 3700 to 2700 and 1600/cm. This indicates hBN's structural and chemical properties are significantly changed. The intercalated product was hygroscopic and interacted with moisture in the air to cause further structural and chemical changes (from XRD and FTIR). During a 24-h hold at room temperature in air with 100 percent relative humidity, the mass increased another 141 percent. The intercalated product, hydrated or not, can be heated to 750 C in air to cause exfoliation. Exfoliation becomes significant after two intercalation-air heating cycles, when 20-nm nanosheets are commonly found. Structural and chemical changes indicated by XRD and FTIR data were nearly reversed after the product was placed in hydrochloric acid (HCl), resulting in purified, exfoliated, thin hBN products.

  13. Tilted hexagonal post arrays: DNA electrophoresis in anisotropic media.

    PubMed

    Chen, Zhen; Dorfman, Kevin D

    2014-02-01

    Using Brownian dynamics simulations, we show that DNA electrophoresis in a hexagonal array of micron-sized posts changes qualitatively when the applied electric field vector is not coincident with the lattice vectors of the array. DNA electrophoresis in such "tilted" post arrays is superior to the standard "un-tilted" approach; while the time required to achieve a resolution of unity in a tilted post array is similar to an un-tilted array at a low-electric field strengths, this time (i) decreases exponentially with electric field strength in a tilted array and (ii) increases exponentially with electric field strength in an un-tilted array. Although the DNA dynamics in a post array are complicated, the electrophoretic mobility results indicate that the "free path," i.e. the average distance of ballistic trajectories of point-sized particles launched from random positions in the unit cell until they intersect the next post, is a useful proxy for the detailed DNA trajectories. The analysis of the free path reveals a fundamental connection between anisotropy of the medium and DNA transport therein that goes beyond simply improving the separation device.

  14. Lattice and off-lattice side chain models of protein folding: Linear time structure prediction better than 86% of optimal

    SciTech Connect

    Hart, W.E.; Istrail, S.

    1996-08-09

    This paper considers the protein structure prediction problem for lattice and off-lattice protein folding models that explicitly represent side chains. Lattice models of proteins have proven extremely useful tools for reasoning about protein folding in unrestricted continuous space through analogy. This paper provides the first illustration of how rigorous algorithmic analyses of lattice models can lead to rigorous algorithmic analyses of off-lattice models. The authors consider two side chain models: a lattice model that generalizes the HP model (Dill 85) to explicitly represent side chains on the cubic lattice, and a new off-lattice model, the HP Tangent Spheres Side Chain model (HP-TSSC), that generalizes this model further by representing the backbone and side chains of proteins with tangent spheres. They describe algorithms for both of these models with mathematically guaranteed error bounds. In particular, the authors describe a linear time performance guaranteed approximation algorithm for the HP side chain model that constructs conformations whose energy is better than 865 of optimal in a face centered cubic lattice, and they demonstrate how this provides a 70% performance guarantee for the HP-TSSC model. This is the first algorithm in the literature for off-lattice protein structure prediction that has a rigorous performance guarantee. The analysis of the HP-TSSC model builds off of the work of Dancik and Hannenhalli who have developed a 16/30 approximation algorithm for the HP model on the hexagonal close packed lattice. Further, the analysis provides a mathematical methodology for transferring performance guarantees on lattices to off-lattice models. These results partially answer the open question of Karplus et al. concerning the complexity of protein folding models that include side chains.

  15. A Discourse Analysis of the Periphrastic Imperfect in the Greek New Testament Writings of Luke

    ERIC Educational Resources Information Center

    Johnson, Carl E.

    2010-01-01

    Motivated by Bloomfield's belief that linguistic variation is not without motivation, this paper seeks to determine the distinction between the morphological imperfect and periphrastic imperfect of Koine Greek within the New Testament writings of Luke. This study suggests that: (1) The periphrastic imperfect occurs only within narrative…

  16. Stress Wave Propagation in Two-dimensional Buckyball Lattice

    NASA Astrophysics Data System (ADS)

    Xu, Jun; Zheng, Bowen

    2016-11-01

    Orderly arrayed granular crystals exhibit extraordinary capability to tune stress wave propagation. Granular system of higher dimension renders many more stress wave patterns, showing its great potential for physical and engineering applications. At nanoscale, one-dimensionally arranged buckyball (C60) system has shown the ability to support solitary wave. In this paper, stress wave behaviors of two-dimensional buckyball (C60) lattice are investigated based on square close packing and hexagonal close packing. We show that the square close packed system supports highly directional Nesterenko solitary waves along initially excited chains and hexagonal close packed system tends to distribute the impulse and dissipates impact exponentially. Results of numerical calculations based on a two-dimensional nonlinear spring model are in a good agreement with the results of molecular dynamics simulations. This work enhances the understanding of wave properties and allows manipulations of nanoscale lattice and novel design of shock mitigation and nanoscale energy harvesting devices.

  17. Thermodynamic properties of the magnetized Coulomb crystal lattices

    NASA Astrophysics Data System (ADS)

    Kozhberov, A. A.

    2016-08-01

    It is thought that Coulomb crystals of ions with hexagonal close-packed lattice may form in the crust of strongly-magnetized neutron stars (magnetars). In this work we are trying to verify this prediction assuming that the direction of the magnetic field corresponds to the minimum of the zero-point energy. We also continue a detailed study of vibration modes and thermodynamic properties of magnetized Coulomb crystals in a wide range of temperatures and magnetic fields. It is demonstrated that the total Helmholtz free energy of the body-centered cubic Coulomb crystal is always lower than that of the Coulomb crystal with hexagonal close-packed or face-centered cubic lattice, which casts doubt on the hypothesis above.

  18. Stress Wave Propagation in Two-dimensional Buckyball Lattice

    PubMed Central

    Xu, Jun; Zheng, Bowen

    2016-01-01

    Orderly arrayed granular crystals exhibit extraordinary capability to tune stress wave propagation. Granular system of higher dimension renders many more stress wave patterns, showing its great potential for physical and engineering applications. At nanoscale, one-dimensionally arranged buckyball (C60) system has shown the ability to support solitary wave. In this paper, stress wave behaviors of two-dimensional buckyball (C60) lattice are investigated based on square close packing and hexagonal close packing. We show that the square close packed system supports highly directional Nesterenko solitary waves along initially excited chains and hexagonal close packed system tends to distribute the impulse and dissipates impact exponentially. Results of numerical calculations based on a two-dimensional nonlinear spring model are in a good agreement with the results of molecular dynamics simulations. This work enhances the understanding of wave properties and allows manipulations of nanoscale lattice and novel design of shock mitigation and nanoscale energy harvesting devices. PMID:27892963

  19. Non-abelian gauge fields and topological insulators in shaken optical lattices.

    PubMed

    Hauke, Philipp; Tieleman, Olivier; Celi, Alessio; Olschläger, Christoph; Simonet, Juliette; Struck, Julian; Weinberg, Malte; Windpassinger, Patrick; Sengstock, Klaus; Lewenstein, Maciej; Eckardt, André

    2012-10-05

    Time-periodic driving like lattice shaking offers a low-demanding method to generate artificial gauge fields in optical lattices. We identify the relevant symmetries that have to be broken by the driving function for that purpose and demonstrate the power of this method by making concrete proposals for its application to two-dimensional lattice systems: We show how to tune frustration and how to create and control band touching points like Dirac cones in the shaken kagome lattice. We propose the realization of a topological and a quantum spin Hall insulator in a shaken spin-dependent hexagonal lattice. We describe how strong artificial magnetic fields can be achieved for example in a square lattice by employing superlattice modulation. Finally, exemplified on a shaken spin-dependent square lattice, we develop a method to create strong non-abelian gauge fields.

  20. Parametric Multi-Level Tiling of Imperfectly Nested Loops

    SciTech Connect

    Hartono, Albert; Baskaran, Muthu M.; Bastoul, Cedric; Cohen, Albert; Krishnamoorthy, Sriram; Norris, Boyana; Ramanujam, J.; Sadayappan, Ponnuswamy

    2009-05-18

    Tiling is a critical loop transformation for generating high-performance code on modern architectures. Efficient generation of multilevel tiled code is essential to exploit several levels of parallelism and/or to maximize data reuse in deep memory hierarchies. Tiled loops with parameterized tile sizes (not compile time constants) facilitate runtime feedback and dynamic optimizations used in iterative compilation and automatic tuning. The existing parametric multilevel tiling approach has focused on transformation for perfectly nested loops, where all assignment statements are contained inside the innermost loop of a loop nest. Previous solutions to tiling for imperfect loop nests are limited to the case where tile sizes are fixed. In this paper, we present an approach to parameterized multilevel tiling for imperfectly nested loops. Our tiling algorithm generates loops that iterate over full rectangular tiles that are amenable for potential compiler optimizations such as register tiling. Experimental results using a number of computational benchmarks demonstrate the effectiveness of our tiling approach.

  1. Evidences of global bifurcations of an imperfect circular plate

    NASA Astrophysics Data System (ADS)

    Yeo, M. H.; Lee, W. K.

    2006-05-01

    The global bifurcations in modal interactions of an imperfect circular plate with one-to-one internal resonance are investigated. The case of the third-order subharmonic resonance, in which an excitation frequency is near triple natural frequencies, is considered. The equations governing nonlinear oscillations of an imperfect circular plate are reduced to a system of non-autonomous ordinary differential equations via Galerkin's procedure. The method of multiple scales is used to obtain a system of autonomous ordinary differential equations, and then Kovačič and Wiggins' method is used to investigate the global dynamics of the plate. Having found a sufficient condition under which Silnikov-type homoclinic orbit can exist, we failed to observe any numerical evidences of global bifurcation.

  2. Stability, vibration and passive damping of partially restrained imperfect columns

    NASA Technical Reports Server (NTRS)

    Razzaq, Z.; Voland, R. T.; Bush, H. G.; Mikulas, M. M., Jr.

    1983-01-01

    A theoretical and experimental study of slender tubular columns for possible use in space structures is conducted in the presence of partial rotational end restraints. Explicit formulas are derived for computing the buckling load and the lowest natural frequency of perfectly straight uniform elastic members with rotational end restraints possessing linear moment-rotation characteristics. An exact solution in the form of a transcendental equation, and a numerical solution using second-order finite-differences are also presented. The presence of an initial imperfection is also incorporated into the numerical procedure. Vibration tests are conducted on an imperfect tubular steel member in the absence of an axial load. A damping concept consisting of a string-mass assembly is explored. Three passive damping configurations involving combinations of three lead shots were investigated. The three lead shot configurations provided considerably greater damping than the single lead shot.

  3. Interplay of imperfections and surface states in topological crystalline insulators

    NASA Astrophysics Data System (ADS)

    Plekhanov, Evgeny; Weber, Cedric

    The conducting states, recently discovered at the surface of a special class of insulators - topological insulators - are distinguished for their insensitivity to local and non-magnetic surface defects. Their behavior in the presence of magnetic impurities and macroscopic imperfections of the surface is puzzling and hard to analyze quantitatively. Here, we present a systematic study of the imperfections (magnetic impurities and deviations from perfect surface cleavage) in topological crystalline insulators of the tin telluride family by using realistic first-principles-derived tight-binding models. The theoretical framework proposed is quite general and easily permits the extensions to other TI families and impurity types. The influence of the strong local correlations of the impurity atoms on the topological states stability is also discussed within the frame of the Dynamical Mean Field Theory.

  4. Noncontacting thermoelectric detection of material imperfections in metals

    SciTech Connect

    Peter B. Nagy; Adnan H. Nayfeh; Waseem I. Faidi; Hector Carreon; Balachander Lakshminaraya; Feng Yu; Bassam Abu-Nabah

    2005-06-17

    This project was aimed at developing a new noncontacting thermoelectric method for nondestructive detection of material imperfections in metals. The method is based on magnetic sensing of local thermoelectric currents around imperfections when a temperature gradient is established throughout a conducting specimen by external heating and cooling. The surrounding intact material serves as the reference electrode therefore the detection sensitivity could be very high if a sufficiently sensitive magnetometer is used in the measurements. This self-referencing, noncontacting, nondestructive inspection technique offers the following distinct advantages over conventional methods: high sensitivity to subtle variations in material properties, unique insensitivity to the size, shape, and other geometrical features of the specimen, noncontacting nature with a substantial stand-off distance, and the ability to probe relatively deep into the material. The potential applications of this method cover a very wide range from detection metallic inclusions and segregations, inhomogeneities, and tight cracks to characterization of hardening, embrittlement, fatigue, texture, and residual stresses.

  5. Effects of instrument imperfections on quantitative scanning transmission electron microscopy.

    PubMed

    Krause, Florian F; Schowalter, Marco; Grieb, Tim; Müller-Caspary, Knut; Mehrtens, Thorsten; Rosenauer, Andreas

    2016-02-01

    Several instrumental imperfections of transmission electron microscopes are characterized and their effects on the results of quantitative scanning electron microscopy (STEM) are investigated and quantified using simulations. Methods to either avoid influences of these imperfections during acquisition or to include them in reference calculations are proposed. Particularly, distortions inflicted on the diffraction pattern by an image-aberration corrector can cause severe errors of more than 20% if not accounted for. A procedure for their measurement is proposed here. Furthermore, afterglow phenomena and nonlinear behavior of the detector itself can lead to incorrect normalization of measured intensities. Single electrons accidentally impinging on the detector are another source of error but can also be exploited for threshold-less calibration of STEM images to absolute dose, incident beam current determination and measurement of the detector sensitivity.

  6. Distribution of radiative crystal imperfections through a silicon ingot

    SciTech Connect

    Flø, A. Burud, I.; Kvaal, K.; Olsen, E.; Søndenå, R.

    2013-11-15

    Crystal imperfections limit the efficiency of multicrystalline silicon solar cells. Recombination through traps is more prominent in areas with high density of crystal imperfections. A method to visualize the distribution of radiative emission from Shockley Read Hall recombination in silicon is demonstrated. We use hyperspectral photoluminescence, a fast non-destructive method, to image radiatively active recombination processes on a set of 50 wafers through a silicon block. The defect related emission lines D1 and D2 may be detected together or alone. The D3 and D4 seem to be correlated if we assume that an emission at the similar energy as D3 (VID3) is caused by a separate mechanism. The content of interstitial iron (Fe{sub i}) correlates with D4. This method yields a spectral map of the inter band gap transitions, which opens up for a new way to characterize mechanisms related to loss of efficiency for solar cells processed from the block.

  7. Buckling of structures with uncertain imperfections - Personal perspective

    NASA Technical Reports Server (NTRS)

    Elishakoff, Isaac

    1998-01-01

    The previous review on stochastic buckling of structures was written by Amazigo in 1976. This review summarizes some of the developments which took place in recent two decades. A brief overview is given of the effect on uncertainty in the initial geometric imperfections, elastic moduli, applied forces, and thickness variation. For the benefit of the thinking reader, the review has a critical nature. It should be noted that this manuscript has yet to be completed.

  8. Resonant Zener tunneling in two-dimensional periodic photonic lattices.

    PubMed

    Desyatnikov, Anton S; Kivshar, Yuri S; Shchesnovich, Valery S; Cavalcanti, Solange B; Hickmann, Jandir M

    2007-02-15

    We study Zener tunneling in two-dimensional photonic lattices and derive, for the case of hexagonal symmetry, the generalized Landau-Zener-Majorana model describing resonant interaction between high-symmetry points of the photonic spectral bands. We demonstrate that this effect can be employed for the generation of Floquet-Bloch modes and verify the model by direct numerical simulations of the tunneling effect.

  9. Symbiosis lost: imperfect vertical transmission of fungal endophytes in grasses.

    PubMed

    Afkhami, Michelle E; Rudgers, Jennifer A

    2008-09-01

    Vertically transmitted symbionts associate with some of the most ecologically dominant species on Earth, and their fixation has led to major evolutionary transitions (e.g., the development of mitochondria). Theory predicts that exclusive vertical transmission should favor mutualism and generate high frequencies of symbiosis in host populations. However, host populations often support lower-than-expected symbiont frequencies. Imperfect transmission (i.e., symbiont is not transmitted to all offspring) can reduce symbiont frequency, but for most beneficial symbionts it is unknown whether vertical transmission can be imperfect or during which life-history stage the symbiont is lost. Using quantitative natural history surveys of fungal endophytes in grasses, we show that transmission was imperfect in at least one stage for all seven host species examined. Endophytes were lost at all possible stages: within adult plants, from adult tillers to seeds, and from seeds to seedlings. Despite this loss, uninfected seeds failed to germinate in some species, resulting in perfect transmission to seedlings. The type and degree of loss differed among host populations and species and between endophyte genera. Populations with lower endophyte frequencies had higher rates of loss. Our results indicate new directions for understanding cooperation and conflict in symbioses and suggest mechanisms for host sanctions against costly symbionts.

  10. Accounting for hardware imperfections in EIT image reconstruction algorithms.

    PubMed

    Hartinger, Alzbeta E; Gagnon, Hervé; Guardo, Robert

    2007-07-01

    Electrical impedance tomography (EIT) is a non-invasive technique for imaging the conductivity distribution of a body section. Different types of EIT images can be reconstructed: absolute, time difference and frequency difference. Reconstruction algorithms are sensitive to many errors which translate into image artefacts. These errors generally result from incorrect modelling or inaccurate measurements. Every reconstruction algorithm incorporates a model of the physical set-up which must be as accurate as possible since any discrepancy with the actual set-up will cause image artefacts. Several methods have been proposed in the literature to improve the model realism, such as creating anatomical-shaped meshes, adding a complete electrode model and tracking changes in electrode contact impedances and positions. Absolute and frequency difference reconstruction algorithms are particularly sensitive to measurement errors and generally assume that measurements are made with an ideal EIT system. Real EIT systems have hardware imperfections that cause measurement errors. These errors translate into image artefacts since the reconstruction algorithm cannot properly discriminate genuine measurement variations produced by the medium under study from those caused by hardware imperfections. We therefore propose a method for eliminating these artefacts by integrating a model of the system hardware imperfections into the reconstruction algorithms. The effectiveness of the method has been evaluated by reconstructing absolute, time difference and frequency difference images with and without the hardware model from data acquired on a resistor mesh phantom. Results have shown that artefacts are smaller for images reconstructed with the model, especially for frequency difference imaging.

  11. Oxygen interaction with hexagonal OsB2 at high temperature

    SciTech Connect

    Xie, Zhilin; Blair, Richard G.; Orlovskaya, Nina; Cullen, David A.; Kata, Dariusz; Rutkowski, Pawel; Lis, Jerzy; Qin, Nan; T-Raissi, Ali

    2016-08-10

    The stability of ReB2-type hexagonal OsB2 powder at high temperature with oxygen presence has been studied by thermogravimetric analysis, differential scanning calorimetry, SEM, EDS, and high-temperature scanning transmission electron microscopy and XRD. Results of the study revealed that OsB2 ceramics interact readily with oxygen present in reducing atmosphere, especially at high temperature and produces boric acid, which decomposes on the surface of the powder resulting in the formation of boron vacancies in the hexagonal OsB2 lattice as well as changes in the stoichiometry of the compound. It was also found that under low oxygen partial pressure, sintering of OsB2 powders occurred at a relatively low temperature (900°C). Finally, hexagonal OsB2 ceramic is prone to oxidation and it is very sensitive to oxygen partial pressures, especially at high temperatures.

  12. Clusters in irregular areas and lattices.

    PubMed

    Wieczorek, William F; Delmerico, Alan M; Rogerson, Peter A; Wong, David W S

    2012-01-01

    Geographic areas of different sizes and shapes of polygons that represent counts or rate data are often encountered in social, economic, health, and other information. Often political or census boundaries are used to define these areas because the information is available only for those geographies. Therefore, these types of boundaries are frequently used to define neighborhoods in spatial analyses using geographic information systems and related approaches such as multilevel models. When point data can be geocoded, it is possible to examine the impact of polygon shape on spatial statistical properties, such as clustering. We utilized point data (alcohol outlets) to examine the issue of polygon shape and size on visualization and statistical properties. The point data were allocated to regular lattices (hexagons and squares) and census areas for zip-code tabulation areas and tracts. The number of units in the lattices was set to be similar to the number of tract and zip-code areas. A spatial clustering statistic and visualization were used to assess the impact of polygon shape for zip- and tract-sized units. Results showed substantial similarities and notable differences across shape and size. The specific circumstances of a spatial analysis that aggregates points to polygons will determine the size and shape of the areal units to be used. The irregular polygons of census units may reflect underlying characteristics that could be missed by large regular lattices. Future research to examine the potential for using a combination of irregular polygons and regular lattices would be useful.

  13. Hexagonal OsB2 reduction upon heating in H2 containing environment

    DOE PAGES

    Xie, Zhilin; Blair, Richard G.; Orlovskaya, Nina; ...

    2014-10-23

    The stability of hexagonal ReB2 type OsB2 powder upon heating under reforming gas was investigated. Pure Os metal particles were detected by powder X-ray diffraction starting at 375⁰ C and complete transformation of OsB2 to metallic Os was observed at 725⁰ C. The mechanisms of precipitation of metallic Os is proposed and changes in the lattice parameters of OsB2 upon heating are analysed in terms of the presence of oxygen or water vapour in the heating chamber. Previous studies suggested that Os atoms possess (0) valence, while B atoms possess both (+3) and ( 3) valences in the alternating boron/osmiummore » sheet structure of hexagonal (P63/mmc, No. 194) OsB2; if controllable method for Os removal from the lattice could be found, the opportunity would arise to form two-dimensional (2D) layers consisting of pure B atoms.« less

  14. Epitaxial chemical vapour deposition growth of monolayer hexagonal boron nitride on a Cu(111)/sapphire substrate.

    PubMed

    Uchida, Yuki; Iwaizako, Tasuku; Mizuno, Seigi; Tsuji, Masaharu; Ago, Hiroki

    2017-03-22

    Hexagonal boron nitride (h-BN), an atomically thin insulating material, shows a large band gap, mechanical flexibility, and optical transparency. It can be stacked with other two-dimensional (2D) materials through van der Waals interactions to form layered heterostructures. These properties promise its application as an insulating layer of novel 2D electronic devices due to its atomically smooth surface with a large band gap. Herein, we demonstrated the ambient-pressure chemical vapour deposition (CVD) growth of high-quality, large-area monolayer h-BN on a Cu(111) thin film deposited on a c-plane sapphire using ammonia borane (BH3NH3) as the feedstock. Highly oriented triangular h-BN grains grow on Cu(111), which finally coalescence to cover the entire Cu surface. Low-energy electron diffraction (LEED) measurements indicated that the hexagonal lattice of the monolayer h-BN is well-oriented along the underlying Cu(111) lattice, thus implying the epitaxial growth of h-BN, which can be applied in various 2D electronic devices.

  15. Wargaming in Both Rectilinear and Hexagonal Spaces

    NASA Technical Reports Server (NTRS)

    Hoover, Alex

    2012-01-01

    There are two main approaches to managing wargame entity interactions (movement, line of sight, area of effect, etc) freespace and gridded In the freespace approach, the units exist as entities in a continuous volume of (usually) Cartesian 3D space. They move in any direction (based on interaction with "terrain" that occupies the same space) and interact with each other based on references and displacements from their position in that space. In the gridded approach, space is broken up into (usually regular) shaped pieces. Units are considered to occupy the entire volume of one of these pieces, movement, line of sight, and other interactions are based on the relationships among the spaces rather than the absolute positions of the units themselves. Both approaches have advantages and drawbacks. The general issue that this discussion has addressed is that there is no "perfect" approach to implementing a wargaming battlespace. Each of them (and this extends to others not discussed) has different sets of advantages and disadvantages. Nothing will change that basic nature of the various approaches, nor would it be desirable to do so. Along with the advantages, the challenges define the feel of the game and focus the thinking of the players on certain aspects and away from others. The proposed approach to combining square and hexagonal approaches, which we will call the rhombus interface, leverages rhombuses constructed from equilateral triangles into which the hexagon can be decomposed to bridge the gap between the approaches, maintain relative consistency between the two as much as possible, and provide most of the feel of the hexagonal approach.

  16. Solubilization of nutraceuticals into reverse hexagonal mesophases.

    PubMed

    Amar-Yuli, Idit; Aserin, Abraham; Garti, Nissim

    2008-08-21

    The solubilization of four bioactive molecules with different polarities, in three reverse hexagonal (HII) systems has been investigated. The three HII systems were a typical reverse hexagonal composed of glycerol monooleate (GMO)/tricaprylin/water and two fluid hexagonal systems containing either 2.75 wt % Transcutol or ethanol as a fourth component. The phase behavior of the liquid crystalline phases in the presence of ascorbic acid, ascorbyl palmitate, D-alpha-tocopherol and D-alpha-tocopherol acetate were determined by small-angle X-ray scattering (SAXS) and optical microscopy. Differential scanning calorimetry (DSC) and Fourier-transform infrared (FT-IR) techniques were utilized to follow modifications in the thermal behavior and in the vibrations of different functional groups upon solubilizing the bioactive molecules. The nature of each guest molecule (in both geometry and polarity) together with the different HII structures (typical and fluids) determined the corresponding phase behavior, swelling or structural transformations and its location in the HII structures. Ascorbic acid was found to act as a chaotropic guest molecule, localized in the water-rich core and at the interface. The AP was also a chaotropic guest molecule with its head located in the vicinity of the GMO headgroup while its tail embedded close to the surfactant tail. D-alpha-tocopherol and D-alpha-tocopherol acetate were incorporated between the GMO tails; however, the D-alpha-tocopherol was located closer to the interface. Once Transcutol or ethanol was present and upon guest molecule incorporation, partial migration was detected.

  17. Method for exfoliation of hexagonal boron nitride

    NASA Technical Reports Server (NTRS)

    Lin, Yi (Inventor); Connell, John W. (Inventor)

    2012-01-01

    A new method is disclosed for the exfoliation of hexagonal boron nitride into mono- and few-layered nanosheets (or nanoplatelets, nanomesh, nanoribbons). The method does not necessarily require high temperature or vacuum, but uses commercially available h-BN powders (or those derived from these materials, bulk crystals) and only requires wet chemical processing. The method is facile, cost efficient, and scalable. The resultant exfoliated h-BN is dispersible in an organic solvent or water thus amenable for solution processing for unique microelectronic or composite applications.

  18. Solution of an associating lattice-gas model with density anomaly on a Husimi lattice

    NASA Astrophysics Data System (ADS)

    Oliveira, Tiago J.; Stilck, Jürgen F.; Barbosa, Marco Aurélio A.

    2010-11-01

    We study a model of a lattice gas with orientational degrees of freedom which resemble the formation of hydrogen bonds between the molecules. In this model, which is the simplified version of the Henriques-Barbosa model, no distinction is made between donors and acceptors in the bonding arms. We solve the model in the grand-canonical ensemble on a Husimi lattice built with hexagonal plaquettes with a central site. The ground state of the model, which was originally defined on the triangular lattice, is exactly reproduced by the solution on this Husimi lattice. In the phase diagram, one gas and two liquid [high density liquid (HDL) and low density liquid (LDL)] phases are present. All phase transitions (GAS-LDL, GAS-HDL, and LDL-HDL) are discontinuous, and the three phases coexist at a triple point. A line of temperatures of maximum density in the isobars is found in the metastable GAS phase, as well as another line of temperatures of minimum density appears in the LDL phase, part of it in the stable region and another in the metastable region of this phase. These findings are at variance with simulational results for the same model on the triangular lattice, which suggested a phase diagram with two critical points. However, our results show very good quantitative agreement with the simulations, both for the coexistence loci and the densities of particles and of hydrogen bonds. We discuss the comparison of the simulations with our results.

  19. High Precision Calculations of the Lennard-Jones Lattice Constants for Five Lattices

    NASA Astrophysics Data System (ADS)

    Stein, Matthew

    2017-01-01

    The total potential energy of a crystal as described by the Lennard-Jones (L-J) potential depends in part upon the calculation of lattice constants. Knowing these constants to high precision is useful for prediction of the lattice type and simulation of crystals such as rare-gas solids or germanium detectors, but reaching higher precision is computationally costly and challenging. Presented here is the extension of the precision of the lattice constants, Lp, up to 32 decimal digits, and in some cases corrections from previous publication. The Lp terms are given for 4 <= p <= 30 in the simple cubic, face-centered cubic, body-centered cubic, hexagonal-close-pack, and diamond lattices. This precision was obtained through the use of careful parallelization technique, exploitation of the symmetries of each lattice, and the ``onionization'' of the simulated crystal. The results of this computation, along with the tools and algorithm strategies to make this computation possible, are explained in detail graphically.

  20. Solution of an associating lattice-gas model with density anomaly on a Husimi lattice.

    PubMed

    Oliveira, Tiago J; Stilck, Jürgen F; Barbosa, Marco Aurélio A

    2010-11-01

    We study a model of a lattice gas with orientational degrees of freedom which resemble the formation of hydrogen bonds between the molecules. In this model, which is the simplified version of the Henriques-Barbosa model, no distinction is made between donors and acceptors in the bonding arms. We solve the model in the grand-canonical ensemble on a Husimi lattice built with hexagonal plaquettes with a central site. The ground state of the model, which was originally defined on the triangular lattice, is exactly reproduced by the solution on this Husimi lattice. In the phase diagram, one gas and two liquid [high density liquid (HDL) and low density liquid (LDL)] phases are present. All phase transitions (GAS-LDL, GAS-HDL, and LDL-HDL) are discontinuous, and the three phases coexist at a triple point. A line of temperatures of maximum density in the isobars is found in the metastable GAS phase, as well as another line of temperatures of minimum density appears in the LDL phase, part of it in the stable region and another in the metastable region of this phase. These findings are at variance with simulational results for the same model on the triangular lattice, which suggested a phase diagram with two critical points. However, our results show very good quantitative agreement with the simulations, both for the coexistence loci and the densities of particles and of hydrogen bonds. We discuss the comparison of the simulations with our results.

  1. Gravitational waves from inspiralling compact binaries: Hexagonal template placement and its efficiency in detecting physical signals

    NASA Astrophysics Data System (ADS)

    Cokelaer, T.

    2007-11-01

    Matched filtering is used to search for gravitational waves emitted by inspiralling compact binaries in data from the ground-based interferometers. One of the key aspects of the detection process is the design of a template bank that covers the astrophysically pertinent parameter space. In an earlier paper, we described a template bank that is based on a square lattice. Although robust, we showed that the square placement is overefficient, with the implication that it is computationally more demanding than required. In this paper, we present a template bank based on an hexagonal lattice, which size is reduced by 40% with respect to the proposed square placement. We describe the practical aspects of the hexagonal template bank implementation, its size, and computational cost. We have also performed exhaustive simulations to characterize its efficiency and safeness. We show that the bank is adequate to search for a wide variety of binary systems (primordial black holes, neutron stars, and stellar-mass black holes) and in data from both current detectors (initial LIGO, Virgo and GEO600) as well as future detectors (advanced LIGO and EGO). Remarkably, although our template bank placement uses a metric arising from a particular template family, namely, stationary phase approximation, we show that it can be used successfully with other template families (e.g., Padé resummation and effective one-body approximation). This quality of being effective for different template families makes the proposed bank suitable for a search that would use several of them in parallel (e.g., in a binary black hole search). The hexagonal template bank described in this paper is currently used to search for nonspinning inspiralling compact binaries in data from the Laser Interferometer Gravitational-Wave Observatory (LIGO).

  2. Theoretical and numerical investigation of HF elastic wave propagation in two-dimensional periodic beam lattices

    NASA Astrophysics Data System (ADS)

    Tie, B.; Tian, B. Y.; Aubry, D.

    2013-12-01

    The elastic wave propagation phenomena in two-dimensional periodic beam lattices are studied by using the Bloch wave transform. The numerical modeling is applied to the hexagonal and the rectangular beam lattices, in which, both the in-plane (with respect to the lattice plane) and out-of-plane waves are considered. The dispersion relations are obtained by calculating the Bloch eigenfrequencies and eigenmodes. The frequency bandgaps are observed and the influence of the elastic and geometric properties of the primitive cell on the bandgaps is studied. By analyzing the phase and the group velocities of the Bloch wave modes, the anisotropic behaviors and the dispersive characteristics of the hexagonal beam lattice with respect to the wave propagation are highlighted in high frequency domains. One important result presented herein is the comparison between the first Bloch wave modes to the membrane and bending/transverse shear wave modes of the classical equivalent homogenized orthotropic plate model of the hexagonal beam lattice. It is shown that, in low frequency ranges, the homogenized plate model can correctly represent both the in-plane and out-of-plane dynamic behaviors of the beam lattice, its frequency validity domain can be precisely evaluated thanks to the Bloch modal analysis. As another important and original result, we have highlighted the existence of the retropropagating Bloch wave modes with a negative group velocity, and of the corresponding "retro-propagating" frequency bands.

  3. Realignment of the flux-line lattice by a change in the symmetry of superconductivity in UPt3

    PubMed

    Huxley; Rodiere; Paul; van Dijk N; Cubitt; Flouquet

    2000-07-13

    In 1957, Abrikosov described how quanta of magnetic flux enter the interior of a bulk type II superconductor. It was subsequently predicted that, in an isotropic superconductor, the repulsive forces between the flux lines would cause them to order in two dimensions, forming a hexagonal lattice. Flux-line lattices with different geometry can also be found in conventional (type II) superconductors; however, the ideal hexagonal lattice structure should always occur when the magnetic field is applied along a hexagonal crystal direction. Here we report measurements of the orientation of the flux-line lattice in the heavy-fermion superconductor UPt3, for this special case. As the temperature is increased, the hexagonal lattice, which is initially aligned along the crystal symmetry directions, realigns itself with the anisotropic superconducting gap. The superconductivity in UPt3 is unusual (even compared to unconventional oxide superconductors) because the superconducting gap has a lower rotational symmetry than the crystal structure. This special feature enables our data to demonstrate clearly the link between the microscopic symmetry of the superconductivity and the mesoscopic physics of the flux-line lattice. Moreover, our observations provide a stringent test of the theoretical description of the unconventional superconductivity in UPt3.

  4. Nylon flocked swab severely reduces Hexagon Obti sensibility.

    PubMed

    Frippiat, Christophe; De Roy, Gilbert; Fontaine, Louis-Marie; Dognaux, Sophie; Noel, Fabrice; Heudt, Laeticia; Lepot, Laurent

    2015-02-01

    Hexagon Obti immunological blood test and flocked swab are widely used in forensic laboratories. Nevertheless, up to now, no compatibility tests have been published between sampling with the ethylene oxide treated flocked swab and the Hexagon Obti blood detection strip. In this study, we investigated this compatibility. Our work shows that sampling with ethylene oxide treated flocked swab reduces by a factor of at least 100 the detection threshold of blood using the Hexagon Obti immunological test.

  5. Two-dimensional hexagonal semiconductors beyond graphene

    NASA Astrophysics Data System (ADS)

    Nguyen, Bich Ha; Hieu Nguyen, Van

    2016-12-01

    The rapid and successful development of the research on graphene and graphene-based nanostructures has been substantially enlarged to include many other two-dimensional hexagonal semiconductors (THS): phosphorene, silicene, germanene, hexagonal boron nitride (h-BN) and transition metal dichalcogenides (TMDCs) such as MoS2, MoSe2, WS2, WSe2 as well as the van der Waals heterostructures of various THSs (including graphene). The present article is a review of recent works on THSs beyond graphene and van der Waals heterostructures composed of different pairs of all THSs. One among the priorities of new THSs compared to graphene is the presence of a non-vanishing energy bandgap which opened up the ability to fabricate a large number of electronic, optoelectronic and photonic devices on the basis of these new materials and their van der Waals heterostructures. Moreover, a significant progress in the research on TMDCs was the discovery of valley degree of freedom. The results of research on valley degree of freedom and the development of a new technology based on valley degree of freedom-valleytronics are also presented. Thus the scientific contents of the basic research and practical applications os THSs are very rich and extremely promising.

  6. Nanocrystalline hexagonal diamond formed from glassy carbon

    DOE PAGES

    Shiell, Thomas. B.; McCulloch, Dougal G.; Bradby, Jodie E.; ...

    2016-11-29

    Carbon exhibits a large number of allotropes and its phase behaviour is still subject to signifcant uncertainty and intensive research. The hexagonal form of diamond, also known as lonsdaleite, was discovered in the Canyon Diablo meteorite where its formation was attributed to the extreme conditions experienced during the impact. However, it has recently been claimed that lonsdaleite does not exist as a well-defned material but is instead defective cubic diamond formed under high pressure and high temperature conditions. Here we report the synthesis of almost pure lonsdaleite in a diamond anvil cell at 100GPa and 400 C. The nanocrystalline materialmore » was recovered at ambient and analysed using difraction and high resolution electron microscopy. We propose that the transformation is the result of intense radial plastic fow under compression in the diamond anvil cell, which lowers the energy barrier by locking in favourable stackings of graphene sheets. This strain induced transformation of the graphitic planes of the precursor to hexagonal diamond is supported by frst principles calculations of transformation pathways and explains why the new phase is found in an annular region. Furthermore, our findings establish that high purity lonsdaleite is readily formed under strain and hence does not require meteoritic impacts.« less

  7. Nanocrystalline hexagonal diamond formed from glassy carbon

    SciTech Connect

    Shiell, Thomas. B.; McCulloch, Dougal G.; Bradby, Jodie E.; Haberl, Bianca; Boehler, Reinhard; McKenzie, David. R.

    2016-11-29

    Carbon exhibits a large number of allotropes and its phase behaviour is still subject to signifcant uncertainty and intensive research. The hexagonal form of diamond, also known as lonsdaleite, was discovered in the Canyon Diablo meteorite where its formation was attributed to the extreme conditions experienced during the impact. However, it has recently been claimed that lonsdaleite does not exist as a well-defned material but is instead defective cubic diamond formed under high pressure and high temperature conditions. Here we report the synthesis of almost pure lonsdaleite in a diamond anvil cell at 100GPa and 400 C. The nanocrystalline material was recovered at ambient and analysed using difraction and high resolution electron microscopy. We propose that the transformation is the result of intense radial plastic fow under compression in the diamond anvil cell, which lowers the energy barrier by locking in favourable stackings of graphene sheets. This strain induced transformation of the graphitic planes of the precursor to hexagonal diamond is supported by frst principles calculations of transformation pathways and explains why the new phase is found in an annular region. Furthermore, our findings establish that high purity lonsdaleite is readily formed under strain and hence does not require meteoritic impacts.

  8. Nanocrystalline hexagonal diamond formed from glassy carbon

    NASA Astrophysics Data System (ADS)

    Shiell, Thomas. B.; McCulloch, Dougal G.; Bradby, Jodie E.; Haberl, Bianca; Boehler, Reinhard; McKenzie, David. R.

    2016-11-01

    Carbon exhibits a large number of allotropes and its phase behaviour is still subject to significant uncertainty and intensive research. The hexagonal form of diamond, also known as lonsdaleite, was discovered in the Canyon Diablo meteorite where its formation was attributed to the extreme conditions experienced during the impact. However, it has recently been claimed that lonsdaleite does not exist as a well-defined material but is instead defective cubic diamond formed under high pressure and high temperature conditions. Here we report the synthesis of almost pure lonsdaleite in a diamond anvil cell at 100 GPa and 400 °C. The nanocrystalline material was recovered at ambient and analysed using diffraction and high resolution electron microscopy. We propose that the transformation is the result of intense radial plastic flow under compression in the diamond anvil cell, which lowers the energy barrier by “locking in” favourable stackings of graphene sheets. This strain induced transformation of the graphitic planes of the precursor to hexagonal diamond is supported by first principles calculations of transformation pathways and explains why the new phase is found in an annular region. Our findings establish that high purity lonsdaleite is readily formed under strain and hence does not require meteoritic impacts.

  9. Nanocrystalline hexagonal diamond formed from glassy carbon

    PubMed Central

    Shiell, Thomas. B.; McCulloch, Dougal G.; Bradby, Jodie E.; Haberl, Bianca; Boehler, Reinhard; McKenzie, David. R.

    2016-01-01

    Carbon exhibits a large number of allotropes and its phase behaviour is still subject to significant uncertainty and intensive research. The hexagonal form of diamond, also known as lonsdaleite, was discovered in the Canyon Diablo meteorite where its formation was attributed to the extreme conditions experienced during the impact. However, it has recently been claimed that lonsdaleite does not exist as a well-defined material but is instead defective cubic diamond formed under high pressure and high temperature conditions. Here we report the synthesis of almost pure lonsdaleite in a diamond anvil cell at 100 GPa and 400 °C. The nanocrystalline material was recovered at ambient and analysed using diffraction and high resolution electron microscopy. We propose that the transformation is the result of intense radial plastic flow under compression in the diamond anvil cell, which lowers the energy barrier by “locking in” favourable stackings of graphene sheets. This strain induced transformation of the graphitic planes of the precursor to hexagonal diamond is supported by first principles calculations of transformation pathways and explains why the new phase is found in an annular region. Our findings establish that high purity lonsdaleite is readily formed under strain and hence does not require meteoritic impacts. PMID:27897174

  10. Nanocrystalline hexagonal diamond formed from glassy carbon.

    PubMed

    Shiell, Thomas B; McCulloch, Dougal G; Bradby, Jodie E; Haberl, Bianca; Boehler, Reinhard; McKenzie, David R

    2016-11-29

    Carbon exhibits a large number of allotropes and its phase behaviour is still subject to significant uncertainty and intensive research. The hexagonal form of diamond, also known as lonsdaleite, was discovered in the Canyon Diablo meteorite where its formation was attributed to the extreme conditions experienced during the impact. However, it has recently been claimed that lonsdaleite does not exist as a well-defined material but is instead defective cubic diamond formed under high pressure and high temperature conditions. Here we report the synthesis of almost pure lonsdaleite in a diamond anvil cell at 100 GPa and 400 °C. The nanocrystalline material was recovered at ambient and analysed using diffraction and high resolution electron microscopy. We propose that the transformation is the result of intense radial plastic flow under compression in the diamond anvil cell, which lowers the energy barrier by "locking in" favourable stackings of graphene sheets. This strain induced transformation of the graphitic planes of the precursor to hexagonal diamond is supported by first principles calculations of transformation pathways and explains why the new phase is found in an annular region. Our findings establish that high purity lonsdaleite is readily formed under strain and hence does not require meteoritic impacts.

  11. Exotic damping ring lattices

    SciTech Connect

    Palmer, R.B.

    1987-05-01

    This paper looks at, and compares three types of damping ring lattices: conventional, wiggler lattice with finite ..cap alpha.., wiggler lattice with ..cap alpha.. = 0, and observes the attainable equilibrium emittances for the three cases assuming a constraint on the attainable longitudinal impedance of 0.2 ohms. The emittance obtained are roughly in the ratio 4:2:1 for these cases.

  12. Characterizing the curvature and its first derivative for imperfect fluids

    NASA Astrophysics Data System (ADS)

    Machado Ramos, Maria da Piedade

    2017-04-01

    The curvature tensor and its derivatives up to any order can be covariantly characterized by a minimal set of spinor quantities. On the other hand it might be useful, particularly in cosmology, to describe the geometry of a spacetime in a (1+3) formalism, based on an invariantly defined fluid velocity. In this work, we consider an imperfect fluid possessing both isotropic and anisotropic pressure. For these fluids, we determine the (1+3) matter terms of the curvature as well as the parts of the first order covariant derivative of the curvature (\

  13. Postdeposition annealing induced transition from hexagonal Pr{sub 2}O{sub 3} to cubic PrO{sub 2} films on Si(111)

    SciTech Connect

    Weisemoeller, T.; Bertram, F.; Gevers, S.; Greuling, A.; Deiter, C.; Tobergte, H.; Neumann, M.; Wollschlaeger, J.; Giussani, A.; Schroeder, T.

    2009-06-15

    Films of hexagonal praseodymium sesquioxide (h-Pr{sub 2}O{sub 3}) were deposited on Si(111) by molecular beam epitaxy and thereafter annealed in 1 atm oxygen at different temperatures, ranging from 100 to 700 deg. C. The films of the samples annealed at 300 deg. C or more were transformed to PrO{sub 2} with B-oriented Fm3m structure, while films annealed at lower temperatures kept the hexagonal structure. The films are composed of PrO{sub 2} and PrO{sub 2-d}elta species, which coexist laterally and are tetragonally distorted due to the interaction at the interface between oxide film and Si substrate. Compared to PrO{sub 2}, PrO{sub 2-d}elta has the same cubic structure but with oxygen vacancies. The oxygen vacancies are partly ordered and increase the vertical lattice constant of the film, whereas the lateral lattice constant is almost identical for both species and on all samples. The latter lattice constant matches the lattice constant of the originally crystallized hexagonal praseodymium sesquioxide. That means that no long range reordering of the praseodymium atoms takes place during the phase transformation.

  14. Elasto-static micropolar behavior of a chiral auxetic lattice

    NASA Astrophysics Data System (ADS)

    Spadoni, A.; Ruzzene, M.

    2012-01-01

    Auxetic materials expand when stretched, and shrink when compressed. This is the result of a negative Poisson's ratio ν. Isotropic configurations with ν≈-1 have been designed and are expected to provide increased shear stiffness G. This assumes that Young's modulus and ν can be engineered independently. In this article, a micropolar-continuum model is employed to describe the behavior of a representative auxetic structural network, the chiral lattice, in an attempt to remove the indeterminacy in its constitutive law resulting from ν=-1. While this indeterminacy is successfully removed, it is found that the shear modulus is an independent parameter and, for certain configurations, it is equal to that of the triangular lattice. This is remarkable as the chiral lattice is subject to bending deformation of its internal members, and thus is more compliant than the triangular lattice which is stretch dominated. The derived micropolar model also indicates that this unique lattice has the highest characteristic length scale lc of all known lattice topologies, as well as a negative first Lamé constant without violating bounds required for thermodynamic stability. We also find that hexagonal arrangements of deformable rings have a coupling number N=1. This is the first lattice reported in the literature for which couple-stress or Mindlin theory is necessary rather than being adopted a priori.

  15. Large-area monolayer hexagonal boron nitride on Pt foil.

    PubMed

    Park, Ji-Hoon; Park, Jin Cheol; Yun, Seok Joon; Kim, Hyun; Luong, Dinh Hoa; Kim, Soo Min; Choi, Soo Ho; Yang, Woochul; Kong, Jing; Kim, Ki Kang; Lee, Young Hee

    2014-08-26

    Hexagonal boron nitride (h-BN) has recently been in the spotlight due to its numerous applications including its being an ideal substrate for two-dimensional electronics, a tunneling material for vertical tunneling devices, and a growth template for heterostructures. However, to obtain a large area of h-BN film while maintaining uniform thickness is still challenging and has not been realized. Here, we report the systematical study of h-BN growth on Pt foil by using low pressure chemical vapor deposition with a borazine source. The monolayer h-BN film was obtained over the whole Pt foil (2 × 5 cm(2)) under <100 mTorr, where the size is limited only by the Pt foil size. A borazine source was catalytically decomposed on the Pt surface, leading to the self-limiting growth of the monolayer without the associating precipitation, which is very similar to the growth of graphene on Cu. The orientation of the h-BN domains was largely confined by the Pt domain, which is confirmed by polarizing optical microscopy (POM) assisted by the nematic liquid crystal (LC) film. The total pressure and orientation of the Pt lattice plane are crucial parameters for thickness control. At high pressure (∼0.5 Torr), thick film was grown on Pt (111), and in contrast, thin film was grown on Pt (001). Our advances in monolayer h-BN growth will play an important role to further develop a high quality h-BN film that can be used for vertical tunneling, optoelectronic devices and growth templates for a variety of heterostructures.

  16. Graphene on hexagonal boron nitride as a tunable hyperbolic metamaterial.

    PubMed

    Dai, S; Ma, Q; Liu, M K; Andersen, T; Fei, Z; Goldflam, M D; Wagner, M; Watanabe, K; Taniguchi, T; Thiemens, M; Keilmann, F; Janssen, G C A M; Zhu, S-E; Jarillo-Herrero, P; Fogler, M M; Basov, D N

    2015-08-01

    Hexagonal boron nitride (h-BN) is a natural hyperbolic material, in which the dielectric constants are the same in the basal plane (ε(t) ≡ ε(x) = ε(y)) but have opposite signs (ε(t)ε(z) < 0) in the normal plane (ε(z)). Owing to this property, finite-thickness slabs of h-BN act as multimode waveguides for the propagation of hyperbolic phonon polaritons--collective modes that originate from the coupling between photons and electric dipoles in phonons. However, control of these hyperbolic phonon polaritons modes has remained challenging, mostly because their electrodynamic properties are dictated by the crystal lattice of h-BN. Here we show, by direct nano-infrared imaging, that these hyperbolic polaritons can be effectively modulated in a van der Waals heterostructure composed of monolayer graphene on h-BN. Tunability originates from the hybridization of surface plasmon polaritons in graphene with hyperbolic phonon polaritons in h-BN, so that the eigenmodes of the graphene/h-BN heterostructure are hyperbolic plasmon-phonon polaritons. The hyperbolic plasmon-phonon polaritons in graphene/h-BN suffer little from ohmic losses, making their propagation length 1.5-2.0 times greater than that of hyperbolic phonon polaritons in h-BN. The hyperbolic plasmon-phonon polaritons possess the combined virtues of surface plasmon polaritons in graphene and hyperbolic phonon polaritons in h-BN. Therefore, graphene/h-BN can be classified as an electromagnetic metamaterial as the resulting properties of these devices are not present in its constituent elements alone.

  17. Graphene on hexagonal boron nitride as a tunable hyperbolic metamaterial

    NASA Astrophysics Data System (ADS)

    Dai, S.; Ma, Q.; Liu, M. K.; Andersen, T.; Fei, Z.; Goldflam, M. D.; Wagner, M.; Watanabe, K.; Taniguchi, T.; Thiemens, M.; Keilmann, F.; Janssen, G. C. A. M.; Zhu, S.-E.; Jarillo-Herrero, P.; Fogler, M. M.; Basov, D. N.

    2015-08-01

    Hexagonal boron nitride (h-BN) is a natural hyperbolic material, in which the dielectric constants are the same in the basal plane (ɛt ≡ ɛx = ɛy) but have opposite signs (ɛtɛz < 0) in the normal plane (ɛz). Owing to this property, finite-thickness slabs of h-BN act as multimode waveguides for the propagation of hyperbolic phonon polaritons—collective modes that originate from the coupling between photons and electric dipoles in phonons. However, control of these hyperbolic phonon polaritons modes has remained challenging, mostly because their electrodynamic properties are dictated by the crystal lattice of h-BN. Here we show, by direct nano-infrared imaging, that these hyperbolic polaritons can be effectively modulated in a van der Waals heterostructure composed of monolayer graphene on h-BN. Tunability originates from the hybridization of surface plasmon polaritons in graphene with hyperbolic phonon polaritons in h-BN, so that the eigenmodes of the graphene/h-BN heterostructure are hyperbolic plasmon-phonon polaritons. The hyperbolic plasmon-phonon polaritons in graphene/h-BN suffer little from ohmic losses, making their propagation length 1.5-2.0 times greater than that of hyperbolic phonon polaritons in h-BN. The hyperbolic plasmon-phonon polaritons possess the combined virtues of surface plasmon polaritons in graphene and hyperbolic phonon polaritons in h-BN. Therefore, graphene/h-BN can be classified as an electromagnetic metamaterial as the resulting properties of these devices are not present in its constituent elements alone.

  18. Microstructural characterization and optical properties of green emitting hexagonal and monoclinic CePO4:Tb3+ nanocrystals

    NASA Astrophysics Data System (ADS)

    Sisira, S.; Alexander, Dinu; Thomas, Kukku; Vimal, G.; Mani, Kamal P.; Biju, P. R.; Unnikrishnan, N. V.; Joseph, Cyriac

    2017-02-01

    Green emitting CePO4:Tb3+ nanocrystals with hexagonal and monoclinic structures were successfully synthesized through microwave assisted sol gel method. The variation observed in the powder XRD pattern from that of bulk is explained using HRTEM analysis in relation with the preferential growth in distinct directions to form nanorods. The results obtained from the microstructural characterization of the hexagonal and monoclinic CePO4:Tb3+nanocrystals are successfully correlated with the single crystal data of CePO4 for the first time in accordance with the single crystal growth theory. FTIR spectrum of the CePO4 nanocrystals evidenced the splitting of fundamental vibrations of phosphate group in the nine fold coordination of lanthanide atoms and confirmed the low symmetry of monoclinic structure than the hexagonal system. The diminishing intensity of terbium emission in the hexagonal structure than the monoclinic structured CePO4:Tb3+ nanocrystals is explained in relation with the lattice symmetry. The high intensity green emission due to the strong 5D4–7F5 transition in monoclinic CePO4:Tb3+ nanocrystals make it as a potential candidate for optoelectronic applications.

  19. B{sub 27}{sup −}: Appearance of the smallest planar boron cluster containing a hexagonal vacancy

    SciTech Connect

    Li, Wei-Li; Piazza, Zachary A.; Wang, Lai-Sheng; Pal, Rhitankar; Zeng, Xiao Cheng

    2015-05-28

    Photoelectron spectroscopy and ab initio calculations have been carried out to probe the structures and chemical bonding of the B{sub 27}{sup −} cluster. Comparison between the experimental spectrum and the theoretical results reveals a two-dimensional (2D) global minimum with a triangular lattice containing a tetragonal defect (I) and two low-lying 2D isomers (II and III), each with a hexagonal vacancy. All three 2D isomers have 16 peripheral boron atoms and 11 inner boron atoms. Isomer I is shown to be mainly responsible for the observed photoelectron spectrum with isomers II and III as minor contributors. Chemical bonding analyses of these three isomers show that they all feature 16 localized peripheral B–B σ-bonds. Additionally, isomer I possesses 16 delocalized σ bonds and nine delocalized π bonds, while isomers II and III each contain 17 delocalized σ bonds and eight delocalized π bonds. It is found that the hexagonal vacancy is associated generally with an increase of delocalized σ bonds at the expense of delocalized π bonds in 2D boron clusters. The hexagonal vacancy, characteristic of borophenes, is found to be a general structural feature for mid-sized boron clusters. The current study shows that B{sub 27}{sup −} is the first boron cluster, where a hexagonal vacancy appears among the low-lying isomers accessible experimentally.

  20. Robust light transport in non-Hermitian photonic lattices

    PubMed Central

    Longhi, Stefano; Gatti, Davide; Valle, Giuseppe Della

    2015-01-01

    Combating the effects of disorder on light transport in micro- and nano-integrated photonic devices is of major importance from both fundamental and applied viewpoints. In ordinary waveguides, imperfections and disorder cause unwanted back-reflections, which hinder large-scale optical integration. Topological photonic structures, a new class of optical systems inspired by quantum Hall effect and topological insulators, can realize robust transport via topologically-protected unidirectional edge modes. Such waveguides are realized by the introduction of synthetic gauge fields for photons in a two-dimensional structure, which break time reversal symmetry and enable one-way guiding at the edge of the medium. Here we suggest a different route toward robust transport of light in lower-dimensional (1D) photonic lattices, in which time reversal symmetry is broken because of the non-Hermitian nature of transport. While a forward propagating mode in the lattice is amplified, the corresponding backward propagating mode is damped, thus resulting in an asymmetric transport insensitive to disorder or imperfections in the structure. Non-Hermitian asymmetric transport can occur in tight-binding lattices with an imaginary gauge field via a non-Hermitian delocalization transition, and in periodically-driven superlattices. The possibility to observe non-Hermitian delocalization is suggested using an engineered coupled-resonator optical waveguide (CROW) structure. PMID:26314932

  1. Quantum emission from hexagonal boron nitride monolayers

    NASA Astrophysics Data System (ADS)

    Tran, Toan Trong; Bray, Kerem; Ford, Michael J.; Toth, Milos; Aharonovich, Igor

    2016-01-01

    Artificial atomic systems in solids are widely considered the leading physical system for a variety of quantum technologies, including quantum communications, computing and metrology. To date, however, room-temperature quantum emitters have only been observed in wide-bandgap semiconductors such as diamond and silicon carbide, nanocrystal quantum dots, and most recently in carbon nanotubes. Single-photon emission from two-dimensional materials has been reported, but only at cryogenic temperatures. Here, we demonstrate room-temperature, polarized and ultrabright single-photon emission from a colour centre in two-dimensional hexagonal boron nitride. Density functional theory calculations indicate that vacancy-related defects are a probable source of the emission. Our results demonstrate the unprecedented potential of van der Waals crystals for large-scale nanophotonics and quantum information processing.

  2. Quantum emission from hexagonal boron nitride monolayers

    NASA Astrophysics Data System (ADS)

    Aharonovich, Igor; Tran, Toantrong; Bray, Kerem; Ford, Michael J.; Toth, Milos; MTEE Collaboration

    Artificial atomic systems in solids are widely considered the leading physical system for a variety of quantum technologies, including quantum communications, computing and metrology. To date, however, room-temperature quantum emitters have only been observed in wide-bandgap semiconductors such as diamond and silicon carbide, nanocrystal quantum dots, and most recently in carbon nanotubes. Here, we demonstrate room-temperature, polarized single-photon emission from a colour centre in two-dimensional hexagonal boron nitride. The emitters emit at the red and the near infrared spectral range and exhibit narrowband ultra bright emission (~full width at half maximum of below 10 nm with more than three million counts/s). Density functional theory calculations indicate that vacancy-related defects are a probable source of the emission. Our results demonstrate the unprecedented potential of van der Waals crystals for large-scale nanophotonics and quantum information processing.

  3. The hexagon hypothesis: Six disruptive scenarios.

    PubMed

    Burtles, Jim

    2015-01-01

    This paper aims to bring a simple but effective and comprehensive approach to the development, delivery and monitoring of business continuity solutions. To ensure that the arguments and principles apply across the board, the paper sticks to basic underlying concepts rather than sophisticated interpretations. First, the paper explores what exactly people are defending themselves against. Secondly, the paper looks at how defences should be set up. Disruptive events tend to unfold in phases, each of which invites a particular style of protection, ranging from risk management through to business continuity to insurance cover. Their impact upon any business operation will fall into one of six basic scenarios. The hexagon hypothesis suggests that everyone should be prepared to deal with each of these six disruptive scenarios and it provides them with a useful benchmark for business continuity.

  4. Hexagonal boron nitride and water interaction parameters

    NASA Astrophysics Data System (ADS)

    Wu, Yanbin; Wagner, Lucas K.; Aluru, Narayana R.

    2016-04-01

    The study of hexagonal boron nitride (hBN) in microfluidic and nanofluidic applications at the atomic level requires accurate force field parameters to describe the water-hBN interaction. In this work, we begin with benchmark quality first principles quantum Monte Carlo calculations on the interaction energy between water and hBN, which are used to validate random phase approximation (RPA) calculations. We then proceed with RPA to derive force field parameters, which are used to simulate water contact angle on bulk hBN, attaining a value within the experimental uncertainties. This paper demonstrates that end-to-end multiscale modeling, starting at detailed many-body quantum mechanics and ending with macroscopic properties, with the approximations controlled along the way, is feasible for these systems.

  5. Hexagonal boron nitride and water interaction parameters.

    PubMed

    Wu, Yanbin; Wagner, Lucas K; Aluru, Narayana R

    2016-04-28

    The study of hexagonal boron nitride (hBN) in microfluidic and nanofluidic applications at the atomic level requires accurate force field parameters to describe the water-hBN interaction. In this work, we begin with benchmark quality first principles quantum Monte Carlo calculations on the interaction energy between water and hBN, which are used to validate random phase approximation (RPA) calculations. We then proceed with RPA to derive force field parameters, which are used to simulate water contact angle on bulk hBN, attaining a value within the experimental uncertainties. This paper demonstrates that end-to-end multiscale modeling, starting at detailed many-body quantum mechanics and ending with macroscopic properties, with the approximations controlled along the way, is feasible for these systems.

  6. Adjustment of Design Limited Imperfections for Transportation Vehicles

    NASA Astrophysics Data System (ADS)

    Voges-Schwieger, Kathrin; Hübner, Sven; Behrens, Bernd-Arno

    2011-05-01

    The realization of light weight-construction without loss of passive safety in transportation vehicles is a big challenge for the next years. Considering the requirements on an automobile from consumer view a modern car should combine a high quality of comfort and standard with low operating expenses and a high safety standard. The use of lightweight design enables reductions in fuel consumption and CO2 emissions which are leading to a decrease of operating costs. The increase in passive safety is mainly characterized by an increase in strength and weight due to a concerted material selection, an enhancement of sheet metal thickness and additional compensating elements, e.g. patches. Especially for limited imperfections like cataphoretic drain holes or accesses for joining operations the strength adjustment without additional compensating elements and increasing weight possesses very much potential. The presented research investigate the possibility to reinforce local imperfections considering the material TRIP780 by combining different approaches on light-weight design. The reinforcements are realized by additional forming elements and enhance the moment of inertia. Different investigations were carried out to assess the placement and arrangement of the reinforcements in the deep drawing parts

  7. One-dimensional flows of an imperfect diatomic gas

    NASA Technical Reports Server (NTRS)

    1959-01-01

    With the assumptions that Berthelot's equation of state accounts for molecular size and intermolecular force effects, and that changes in the vibrational heat capacities are given by a Planck term, expressions are developed for analyzing one-dimensional flows of a diatomic gas. The special cases of flow through normal and oblique shocks in free air at sea level are investigated. It is found that up to a Mach number 10 pressure ratio across a normal shock differs by less than 6 percent from its ideal gas value; whereas at Mach numbers above 4 the temperature rise is considerable below and hence the density rise is well above that predicted assuming ideal gas behavior. It is further shown that only the caloric imperfection in air has an appreciable effect on the pressures developed in the shock process considered. The effects of gaseous imperfections on oblique shock-flows are studied from the standpoint of their influence on the life and pressure drag of a flat plate operating at Mach numbers of 10 and 20. The influence is found to be small. (author)

  8. Structural domain walls in polar hexagonal manganites

    NASA Astrophysics Data System (ADS)

    Kumagai, Yu

    2014-03-01

    The domain structure in the multiferroic hexagonal manganites is currently intensely investigated, motivated by the observation of intriguing sixfold topological defects at their meeting points [Choi, T. et al,. Nature Mater. 9, 253 (2010).] and nanoscale electrical conductivity at the domain walls [Wu, W. et al., Phys. Rev. Lett. 108, 077203 (2012).; Meier, D. et al., Nature Mater. 11, 284 (2012).], as well as reports of coupling between ferroelectricity, magnetism and structural antiphase domains [Geng, Y. et al., Nano Lett. 12, 6055 (2012).]. The detailed structure of the domain walls, as well as the origin of such couplings, however, was previously not fully understood. In the present study, we have used first-principles density functional theory to calculate the structure and properties of the low-energy structural domain walls in the hexagonal manganites [Kumagai, Y. and Spaldin, N. A., Nature Commun. 4, 1540 (2013).]. We find that the lowest energy domain walls are atomically sharp, with {210}orientation, explaining the orientation of recently observed stripe domains and suggesting their topological protection [Chae, S. C. et al., Phys. Rev. Lett. 108, 167603 (2012).]. We also explain why ferroelectric domain walls are always simultaneously antiphase walls, propose a mechanism for ferroelectric switching through domain-wall motion, and suggest an atomistic structure for the cores of the sixfold topological defects. This work was supported by ETH Zurich, the European Research Council FP7 Advanced Grants program me (grant number 291151), the JSPS Postdoctoral Fellowships for Research Abroad, and the MEXT Elements Strategy Initiative to Form Core Research Center TIES.

  9. Supersymmetric correspondence in spectra on a graph and its line graph: From circuit theory to spoof plasmons on metallic lattices

    NASA Astrophysics Data System (ADS)

    Nakata, Yosuke; Urade, Yoshiro; Nakanishi, Toshihiro; Miyamaru, Fumiaki; Takeda, Mitsuo Wada; Kitano, Masao

    2016-04-01

    We investigate the supersymmetry (SUSY) structures for inductor-capacitor circuit networks on a simple regular graph and its line graph. We show that their eigenspectra must coincide (except, possibly, for the highest eigenfrequency) due to SUSY, which is derived from the topological nature of the circuits. To observe this spectra correspondence in the high-frequency range, we study spoof plasmons on metallic hexagonal and kagomé lattices. The band correspondence between them is predicted by a simulation. Using terahertz time-domain spectroscopy, we demonstrate the band correspondence of fabricated metallic hexagonal and kagomé lattices.

  10. Pull-in instability tuning in imperfect nonlinear circular microplates under electrostatic actuation

    NASA Astrophysics Data System (ADS)

    Jallouli, A.; Kacem, N.; Bourbon, G.; Le Moal, P.; Walter, V.; Lardies, J.

    2016-12-01

    Dynamic range improvement based on geometric nonlinearity and initial deflection is demonstrated with imperfect circular microplates under electrostatic actuation. Depending on design parameters, we prove how the von Kármán nonlinearity and the plate imperfections lead to a significant delay in pull-in occurrence. These promising results open the way towards an accurate identification of static parameters of circular microplates and the development of a predictive model for the nonlinear dynamics of imperfect capacitive micromachined ultrasonic transducers.

  11. Topological triple-vortex lattice stabilized by mixed frustration in expanded honeycomb Kitaev-Heisenberg model

    PubMed Central

    Yao, Xiaoyan; Dong, Shuai

    2016-01-01

    The expanded classical Kitaev-Heisenberg model on a honeycomb lattice is investigated with the next-nearest-neighboring Heisenberg interaction considered. The simulation shows a rich phase diagram with periodic behavior in a wide parameter range. Beside the double 120° ordered phase, an inhomogeneous phase is uncovered to exhibit a topological triple-vortex lattice, corresponding to the hexagonal domain structure of vector chirality, which is stabilized by the mixed frustration of two sources: the geometrical frustration arising from the lattice structure as well as the frustration from the Kitaev couplings. PMID:27229486

  12. Thermodynamic functions of the hcp Coulomb crystal lattice

    NASA Astrophysics Data System (ADS)

    Kozhberov, A. A.; Baiko, D. A.

    2015-10-01

    One-component Coulomb crystals of ions with hexagonal close-packed (hcp) lattice likely form in the crust of strongly-magnetized neutron stars (magnetars). In this work we present a detailed study of vibration modes and thermodynamic properties of such crystals in a wide range of temperatures at zero magnetic field. In contrast to typically considered lattices, the phonon spectrum of the system exhibits a peculiar crossing of the acoustic modes near the Brillouin zone center in certain directions of the wavevector. It is demonstrated that in the field-free regime the Helmholtz free energy of the hcp Coulomb crystal is always higher than those of the Coulomb crystals with body-centered cubic and face-centered cubic lattices. The results of our numerical calculations are fitted by simple analytic expressions.

  13. Detecting the BCS pairing amplitude via a sudden lattice ramp in a honeycomb lattice

    NASA Astrophysics Data System (ADS)

    Tiesinga, Eite; Nuske, Marlon; Mathey, Ludwig

    2016-05-01

    We determine the exact time evolution of an initial Bardeen-Cooper-Schrieffer (BCS) state of ultra-cold atoms in a hexagonal optical lattice. The dynamical evolution is triggered by ramping the lattice potential up, such that the interaction strength Uf is much larger than the hopping amplitude Jf. The quench initiates collective oscillations with frequency | Uf | /(2 π) in the momentum occupation numbers and imprints an oscillating phase with the same frequency on the order parameter Δ. The latter is not reproduced by treating the time evolution in mean-field theory. The momentum density-density or noise correlation functions oscillate at frequency | Uf | /(2 π) as well as its second harmonic. For a very deep lattice, with negligible tunneling energy, the oscillations of momentum occupation numbers are undamped. Non-zero tunneling after the quench leads to dephasing of the different momentum modes and a subsequent damping of the oscillations. This occurs even for a finite-temperature initial BCS state, but not for a non-interacting Fermi gas. We therefore propose to use this dephasing to detect a BCS state. Finally, we predict that the noise correlation functions in a honeycomb lattice will develop strong anti-correlations near the Dirac point. We acknowledge funding from the National Science Foundation.

  14. Interaction of multiferroic properties and interfaces in hexagonal LuMnO3 ceramics

    NASA Astrophysics Data System (ADS)

    Baghizadeh, A.; Vieira, J. M.; Stroppa, D. G.; Mirzadeh Vaghefi, P.; Graça, M. P.; Amaral, J. S.; Willinger, M.-G.; Amaral, V. S.

    2017-02-01

    A study on the underlying interaction mechanisms between lattice constants, magnetic and dielectric properties with inhomogeneities or internal interfaces in hexagonal, off-stoichiometric LuMnO3 oxide is presented. By increasing Mn content the a-axis constant and volume of the unit cell, the antiferromagnetic (AFM) Néel temperature, T N, and frustration factor of the frustrated Mn3+ trimmers in basal plane show decreasing trends. It was found that increasing the annealing time improves the properties of the lattices and progressively eliminates secondary phases for compositions within the solid solution stability limits. A magnetic contribution below T N is observed for all samples. Two regimes of magnetization below and above 45 K were observed in the AFM state. The magnetic contribution below T N is assigned to either the secondary phase or internal interfaces like ferroelectric (FE) domain walls. Magneto-dielectric coupling at T N is preserved in off-stoichiometric ceramics. The presence of a low temperature anomaly of the dielectric constant is correlated to the composition of the solid solution in off-stoichiometric ceramics. Large FE domains are observed in piezoresponse force microscopy (PFM) images of doped and un-doped ceramics, whereas atomic structure analysis indicates the parallel formation of nano-sized FE domains. A combination of measured properties and microscopy images of micron- and nano-sized domains ascertain the role of lattice distortion and stability of solid solution on multiferroic properties.

  15. Electron compound nature in a surface atomic layer of a two-dimensional hexagonal lattice

    NASA Astrophysics Data System (ADS)

    Matsuda, Iwao; Nakamura, Fumitaka; Kubo, Keisuke; Hirahara, Toru; Yamazaki, Shiro; Choi, Won Hoon; Yeom, Han Woong; Narita, Hisashi; Fukaya, Yuki; Hashimoto, Mie; Kawasuso, Atsuo; Ono, Masanori; Hasegawa, Yukio; Hasegawa, Shuji; Kobayashi, Katsuyoshi

    2010-10-01

    The two-dimensional (2D) ordered phase of monovalent metal alloy, 21×21 , is formed on the Si(111) surface with the constant electron/atom ratio, indicating electron compound nature. Two conventional theories of the Hume-Rothery compounds, Jones model (nearly-free-electron model), and pseudopotential model (interionic interaction model), were applied to examine stability of the 2D phase. We found breakdown of the former and confirmation of the latter approaches with importance of medium-range interatomic interaction, mediated by the 2D surface-state electrons, in the latter approach.

  16. On the Wiener Polarity Index of Lattice Networks

    PubMed Central

    Chen, Lin; Li, Tao; Liu, Jinfeng; Shi, Yongtang; Wang, Hua

    2016-01-01

    Network structures are everywhere, including but not limited to applications in biological, physical and social sciences, information technology, and optimization. Network robustness is of crucial importance in all such applications. Research on this topic relies on finding a suitable measure and use this measure to quantify network robustness. A number of distance-based graph invariants, also known as topological indices, have recently been incorporated as descriptors of complex networks. Among them the Wiener type indices are the most well known and commonly used such descriptors. As one of the fundamental variants of the original Wiener index, the Wiener polarity index has been introduced for a long time and known to be related to the cluster coefficient of networks. In this paper, we consider the value of the Wiener polarity index of lattice networks, a common network structure known for its simplicity and symmetric structure. We first present a simple general formula for computing the Wiener polarity index of any graph. Using this formula, together with the symmetric and recursive topology of lattice networks, we provide explicit formulas of the Wiener polarity index of the square lattices, the hexagonal lattices, the triangular lattices, and the 33 ⋅ 42 lattices. We also comment on potential future research topics. PMID:27930705

  17. How to Introduce the Imperfection Sensitivity Concept into Design 2

    NASA Technical Reports Server (NTRS)

    Elishakoff, Isaac

    1998-01-01

    The previous review on stochastic buckling of structures was written by Amazigo in 1976. The present review summarizes some of the developments which took place in recent two decades. A brief overview is given of the effect on uncertainty in the initial geometric imperfections, elastic moduli, applied forces, and thickness variation. For the benefit of the thinking reader, the review has a critical nature. Present essay should be viewed as a direct continuation of our previous paper (1983) with the same title. In order not to repeat what was covered there, it appears instructive to read it although not necessarily prior to dwelling on this article. Accordingly the title is appended with the serial number. It is not promised that the third review will follow since the university science, both fortunately and unfortunately, stands on three things: relevance, interest, and grants.

  18. Plastic buckling. [post-bifurcation and imperfection sensitivity

    NASA Technical Reports Server (NTRS)

    Hutchinson, J. W.

    1974-01-01

    The present article is concerned mainly with the post-bifurcation and imperfection-sensitivity aspects of plastic buckling. A simple two-degree-of-freedom model is used to introduce post-bifurcation behavior and a second model illustrates features of the behavior of continuous solids and structures. Hill's bifurcation criterion for a class of three-dimensional solids is applied to the Donnell-Mushtari-Vlasov (DMV) theory of plates and shells. A general treatment of the initial post-bifurcation behavior of plates and shells is given within the context of the DMV theory. This is illustrated by problems involving columns and circular plates under radial compression. Numerical results are given for a column under axial compression, a circular plate under radial compression, and spherical and cylindrical shells.

  19. Transport properties of multigrained nanocomposites with imperfect interfaces

    NASA Astrophysics Data System (ADS)

    Palla, Pier Luca; Giordano, Stefano

    2016-11-01

    Multigrained or polycrystalline composite materials have attracted a considerable attention due to their potential applications as advanced materials with outstanding thermal, mechanical, and electromagnetic properties. When the grains' morphology is displayed at the nanoscopic scale, the presence of imperfect interfaces plays a central role in determining the effective transport properties. Therefore, we develop here a self-consistent effective medium theory able to evaluate the influence of real contacts between the different phases of multigrained composite materials. This approach takes into account the classical interface schemes that have been introduced in literature, namely, the low and the high conducting interface models. The theoretical results have been compared with numerical and experimental data concerning the thermal conductivity of ( 1 - x ) Si : x Ge mixtures and the electrical conductivity of ( 1 - x ) Li 2 O : x B 2 O 3 composites.

  20. Imperfect Batesian mimicry and the conspicuousness costs of mimetic resemblance.

    PubMed

    Speed, Michael P; Ruxton, Graeme D

    2010-07-01

    We apply signal detection methodology to make predictions about the evolution of Batesian mimicry. Our approach is novel in three ways. First, we applied a deterministic evolutionary modeling system that allows a large number of alternative mimetic morphs to coexist and compete. Second, we considered that there may be natural boundaries to phenotypic expression. Finally, we allowed increasing conspicuousness to impose an increasing detection cost on mimics. In some instances, the model predicts widespread variation in mimetic forms at evolutionary stability. In other situations, rather than a polymorphism the model predicts dimorphisms in which some prey were maximally cryptic and had minimal resemblance to the model, whereas many others were more conspicuous than the model. The biological implications of these results, particularly for our understanding of imperfect mimicry, are discussed.

  1. Long-distance quantum key distribution with imperfect devices

    SciTech Connect

    Lo Piparo, Nicoló; Razavi, Mohsen

    2014-12-04

    Quantum key distribution over probabilistic quantum repeaters is addressed. We compare, under practical assumptions, two such schemes in terms of their secure key generation rate per memory, R{sub QKD}. The two schemes under investigation are the one proposed by Duan et al. in [Nat. 414, 413 (2001)] and that of Sangouard et al. proposed in [Phys. Rev. A 76, 050301 (2007)]. We consider various sources of imperfections in the latter protocol, such as a nonzero double-photon probability for the source, dark count per pulse, channel loss and inefficiencies in photodetectors and memories, to find the rate for different nesting levels. We determine the maximum value of the double-photon probability beyond which it is not possible to share a secret key anymore. We find the crossover distance for up to three nesting levels. We finally compare the two protocols.

  2. Loss-tolerant quantum cryptography with imperfect sources

    NASA Astrophysics Data System (ADS)

    Tamaki, Kiyoshi; Curty, Marcos; Kato, Go; Lo, Hoi-Kwong; Azuma, Koji

    2014-11-01

    In principle, quantum key distribution (QKD) offers unconditional security based on the laws of physics. Unfortunately, all previous QKD experiments assume perfect state preparation in their security analysis. Therefore, the generated key is not proven to be secure in the presence of unavoidable modulation errors. The key reason that modulation errors are not considered in previous QKD experiments lies in a crucial weakness of the standard Gottesman-Lo-Lütkenhaus-Preskill (GLLP) model, namely, it is not loss tolerant and Eve may in principle enhance imperfections through losses. Here, we propose a QKD protocol that is loss tolerant to state preparation flaws. Importantly, we show conclusively that the state preparation process in QKD can be much less precise than initially thought. Our method can also be applied to other quantum cryptographic protocols.

  3. Modeling Steady Acoustic Fields Bounded in Cavities with Geometrical Imperfections

    NASA Astrophysics Data System (ADS)

    Albo, P. A. Giuliano; Gavioso, R. M.; Benedetto, G.

    2010-07-01

    A mathematical method is derived within the framework of classical Lagrangian field theory, which is suitable for the determination of the eigenstates of acoustic resonators of nearly spherical shape. The method is based on the expansion of the Helmholtz differential operator and the boundary condition in a power series of a small geometrical perturbation parameter {ɛ} . The method extends to orders higher than {ɛ^2} the calculation of the perturbed acoustic eigenvalues, which was previously limited by the use of variational formalism and the methods of Morse and Ingard. A specific example is worked out for radial modes of a prolate spheroid, with the frequency perturbation calculated to order {ɛ^3} . A possible strategy to tackle the problem of calculating the acoustic eigenvalues for cavities presenting non-smooth geometrical imperfections is also described.

  4. Imperfect traveling chimera states induced by local synaptic gradient coupling

    NASA Astrophysics Data System (ADS)

    Bera, Bidesh K.; Ghosh, Dibakar; Banerjee, Tanmoy

    2016-07-01

    In this paper, we report the occurrence of chimera patterns in a network of neuronal oscillators, which are coupled through local, synaptic gradient coupling. We discover a new chimera pattern, namely the imperfect traveling chimera state, where the incoherent traveling domain spreads into the coherent domain of the network. Remarkably, we also find that chimera states arise even for one-way local coupling, which is in contrast to the earlier belief that only nonlocal, global, or nearest-neighbor local coupling can give rise to chimera state; this find further relaxes the essential connectivity requirement of getting a chimera state. We choose a network of identical bursting Hindmarsh-Rose neuronal oscillators, and we show that depending upon the relative strength of the synaptic and gradient coupling, several chimera patterns emerge. We map all the spatiotemporal behaviors in parameter space and identify the transitions among several chimera patterns, an in-phase synchronized state, and a global amplitude death state.

  5. Imperfect traveling chimera states induced by local synaptic gradient coupling.

    PubMed

    Bera, Bidesh K; Ghosh, Dibakar; Banerjee, Tanmoy

    2016-07-01

    In this paper, we report the occurrence of chimera patterns in a network of neuronal oscillators, which are coupled through local, synaptic gradient coupling. We discover a new chimera pattern, namely the imperfect traveling chimera state, where the incoherent traveling domain spreads into the coherent domain of the network. Remarkably, we also find that chimera states arise even for one-way local coupling, which is in contrast to the earlier belief that only nonlocal, global, or nearest-neighbor local coupling can give rise to chimera state; this find further relaxes the essential connectivity requirement of getting a chimera state. We choose a network of identical bursting Hindmarsh-Rose neuronal oscillators, and we show that depending upon the relative strength of the synaptic and gradient coupling, several chimera patterns emerge. We map all the spatiotemporal behaviors in parameter space and identify the transitions among several chimera patterns, an in-phase synchronized state, and a global amplitude death state.

  6. Magnetic field effects in electron systems with imperfect nesting

    NASA Astrophysics Data System (ADS)

    Sboychakov, A. O.; Rakhmanov, A. L.; Kugel, K. I.; Rozhkov, A. V.; Nori, Franco

    2017-01-01

    We analyze the effects of an applied magnetic field on the phase diagram of a weakly correlated electron system with imperfect nesting. The Hamiltonian under study describes two bands: electron and hole ones. Both bands have spherical Fermi surfaces, whose radii are slightly mismatched due to doping. These types of models are often used in the analysis of magnetic states in chromium and its alloys, superconducting iron pnictides, AA-type bilayer graphene, borides, etc. At zero magnetic field, the uniform ground state of the system turns out to be unstable against electronic phase separation. The applied magnetic field affects the phase diagram in several ways. In particular, the Zeeman term stabilizes new antiferromagnetic phases. It also significantly shifts the boundaries of inhomogeneous (phase-separated) states. At sufficiently high fields, the Landau quantization gives rise to oscillations of the order parameters and of the Néel temperature as a function of the magnetic field.

  7. Long-distance quantum key distribution with imperfect devices

    NASA Astrophysics Data System (ADS)

    Lo Piparo, Nicoló; Razavi, Mohsen

    2014-12-01

    Quantum key distribution over probabilistic quantum repeaters is addressed. We compare, under practical assumptions, two such schemes in terms of their secure key generation rate per memory, RQKD. The two schemes under investigation are the one proposed by Duan et al. in [Nat. 414, 413 (2001)] and that of Sangouard et al. proposed in [Phys. Rev. A 76, 050301 (2007)]. We consider various sources of imperfections in the latter protocol, such as a nonzero double-photon probability for the source, dark count per pulse, channel loss and inefficiencies in photodetectors and memories, to find the rate for different nesting levels. We determine the maximum value of the double-photon probability beyond which it is not possible to share a secret key anymore. We find the crossover distance for up to three nesting levels. We finally compare the two protocols.

  8. Collectives for the Optimal Combination of Imperfect Objects

    NASA Technical Reports Server (NTRS)

    Tumer, Kagan; Wolpert, David

    2003-01-01

    In this letter we summarize some recent theoretical work on the design of collectives, i.e., of systems containing many agents, each of which can be viewed as trying to maximize an associated private utility, where there is also a world utility rating the behavior of that overall system that the designer of the collective wishes to optimize. We then apply algorithms based on that work on a recently suggested testbed for such optimization problems. This is the problem of finding the combination of imperfect nano-scale objects that results in the best aggregate object. We present experimental results showing that these algorithms outperform conventional methods by more than an order of magnitude in this domain.

  9. Improving aquatic warbler population assessments by accounting for imperfect detection.

    PubMed

    Oppel, Steffen; Marczakiewicz, Piotr; Lachmann, Lars; Grzywaczewski, Grzegorz

    2014-01-01

    Monitoring programs designed to assess changes in population size over time need to account for imperfect detection and provide estimates of precision around annual abundance estimates. Especially for species dependent on conservation management, robust monitoring is essential to evaluate the effectiveness of management. Many bird species of temperate grasslands depend on specific conservation management to maintain suitable breeding habitat. One such species is the Aquatic Warbler (Acrocephalus paludicola), which breeds in open fen mires in Central Europe. Aquatic Warbler populations have so far been assessed using a complete survey that aims to enumerate all singing males over a large area. Because this approach provides no estimate of precision and does not account for observation error, detecting moderate population changes is challenging. From 2011 to 2013 we trialled a new line transect sampling monitoring design in the Biebrza valley, Poland, to estimate abundance of singing male Aquatic Warblers. We surveyed Aquatic Warblers repeatedly along 50 randomly placed 1-km transects, and used binomial mixture models to estimate abundances per transect. The repeated line transect sampling required 150 observer days, and thus less effort than the traditional 'full count' approach (175 observer days). Aquatic Warbler abundance was highest at intermediate water levels, and detection probability varied between years and was influenced by vegetation height. A power analysis indicated that our line transect sampling design had a power of 68% to detect a 20% population change over 10 years, whereas raw count data had a 9% power to detect the same trend. Thus, by accounting for imperfect detection we increased the power to detect population changes. We recommend to adopt the repeated line transect sampling approach for monitoring Aquatic Warblers in Poland and in other important breeding areas to monitor changes in population size and the effects of habitat management.

  10. Improving Aquatic Warbler Population Assessments by Accounting for Imperfect Detection

    PubMed Central

    Oppel, Steffen; Marczakiewicz, Piotr; Lachmann, Lars; Grzywaczewski, Grzegorz

    2014-01-01

    Monitoring programs designed to assess changes in population size over time need to account for imperfect detection and provide estimates of precision around annual abundance estimates. Especially for species dependent on conservation management, robust monitoring is essential to evaluate the effectiveness of management. Many bird species of temperate grasslands depend on specific conservation management to maintain suitable breeding habitat. One such species is the Aquatic Warbler (Acrocephalus paludicola), which breeds in open fen mires in Central Europe. Aquatic Warbler populations have so far been assessed using a complete survey that aims to enumerate all singing males over a large area. Because this approach provides no estimate of precision and does not account for observation error, detecting moderate population changes is challenging. From 2011 to 2013 we trialled a new line transect sampling monitoring design in the Biebrza valley, Poland, to estimate abundance of singing male Aquatic Warblers. We surveyed Aquatic Warblers repeatedly along 50 randomly placed 1-km transects, and used binomial mixture models to estimate abundances per transect. The repeated line transect sampling required 150 observer days, and thus less effort than the traditional ‘full count’ approach (175 observer days). Aquatic Warbler abundance was highest at intermediate water levels, and detection probability varied between years and was influenced by vegetation height. A power analysis indicated that our line transect sampling design had a power of 68% to detect a 20% population change over 10 years, whereas raw count data had a 9% power to detect the same trend. Thus, by accounting for imperfect detection we increased the power to detect population changes. We recommend to adopt the repeated line transect sampling approach for monitoring Aquatic Warblers in Poland and in other important breeding areas to monitor changes in population size and the effects of habitat management

  11. Correcting length-frequency distributions for imperfect detection

    USGS Publications Warehouse

    Breton, André R.; Hawkins, John A.; Winkelman, Dana L.

    2013-01-01

    Sampling gear selects for specific sizes of fish, which may bias length-frequency distributions that are commonly used to assess population size structure, recruitment patterns, growth, and survival. To properly correct for sampling biases caused by gear and other sources, length-frequency distributions need to be corrected for imperfect detection. We describe a method for adjusting length-frequency distributions when capture and recapture probabilities are a function of fish length, temporal variation, and capture history. The method is applied to a study involving the removal of Smallmouth Bass Micropterus dolomieu by boat electrofishing from a 38.6-km reach on the Yampa River, Colorado. Smallmouth Bass longer than 100 mm were marked and released alive from 2005 to 2010 on one or more electrofishing passes and removed on all other passes from the population. Using the Huggins mark–recapture model, we detected a significant effect of fish total length, previous capture history (behavior), year, pass, year×behavior, and year×pass on capture and recapture probabilities. We demonstrate how to partition the Huggins estimate of abundance into length frequencies to correct for these effects. Uncorrected length frequencies of fish removed from Little Yampa Canyon were negatively biased in every year by as much as 88% relative to mark–recapture estimates for the smallest length-class in our analysis (100–110 mm). Bias declined but remained high even for adult length-classes (≥200 mm). The pattern of bias across length-classes was variable across years. The percentage of unadjusted counts that were below the lower 95% confidence interval from our adjusted length-frequency estimates were 95, 89, 84, 78, 81, and 92% from 2005 to 2010, respectively. Length-frequency distributions are widely used in fisheries science and management. Our simple method for correcting length-frequency estimates for imperfect detection could be widely applied when mark–recapture data

  12. Dust grain oscillations in two-dimensional hexagonal dusty plasma crystals in the presence of a magnetic field

    SciTech Connect

    Farokhi, B.; Shahmansouri, M.; Shukla, P. K.

    2009-06-15

    The influence of a constant magnetic field on the propagation of dust-lattice waves in a two-dimensional hexagonal strongly coupled dusty plasma crystal is considered. The expression for the wave dispersion relation clearly shows that high- and low-frequency dust lattice vibrations exist as a result of the coupling between the longitudinal and transverse dust lattice modes due to the Lorentz force acting on the charged dust particles. It is found that in an external magnetic field the damping rate of the high-frequency (low-frequency) dust lattice wave is increased (decreased). For special values of the wave number and the direction of the wave propagation, the imaginary part of low-frequency is zero and the imaginary part of high-frequency attains a maximum value. The present investigation indicates that the damping rates depend on direction of the external magnetic field. The polarization of dust lattice wave modes is found for different magnetic field strengths and for different directions.

  13. Electronic properties of hexagonal tungsten monocarbide ( h-WC) with 3 d impurities from first-principles calculations

    NASA Astrophysics Data System (ADS)

    Suetin, D. V.; Shein, I. R.; Ivanovskii, A. L.

    2009-07-01

    First-principles FLAPW-GGA calculations have been performed to predict the structural, electronic, cohesive and magnetic properties for hexagonal tungsten monocarbide ( h-WC) doped with all 3 d metals. The optimized lattice parameters, density of states, cohesive and formation energies have been obtained and analyzed for ternary solid solutions with nominal compositions W 0.875M 0.125C (where M=Sc, Ti…Ni, Cu). In addition, the magnetic properties of these solid solutions have been examined, and magnetization has been established for W 0.875Co 0.125C.

  14. A 4-fold-symmetry hexagonal ruthenium for magnetic heterostructures exhibiting enhanced perpendicular magnetic anisotropy and tunnel magnetoresistance.

    PubMed

    Wen, Zhenchao; Sukegawa, Hiroaki; Furubayashi, Takao; Koo, Jungwoo; Inomata, Koichiro; Mitani, Seiji; Hadorn, Jason Paul; Ohkubo, Tadakatsu; Hono, Kazuhiro

    2014-10-08

    A 4-fold-symmetry hexagonal Ru emerging in epitaxial MgO/Ru/Co2 FeAl/MgO heterostructures is reported, in which an approximately Ru(022¯3) growth attributes to the lattice matching between MgO, Ru, and Co2 FeAl. Perpendicular magnetic anisotropy of the Co2 FeAl/MgO interface is substantially enhanced. The magnetic tunnel junctions (MTJs) incorporating this structure give rise to the largest tunnel magnetoresistance for perpendicular MTJs using low damping Heusler alloys.

  15. Hyperbolic phonon polaritons in hexagonal boron nitride

    NASA Astrophysics Data System (ADS)

    Dai, Siyuan

    2015-03-01

    Uniaxial materials whose axial and tangential permittivities have opposite signs are referred to as indefinite or hyperbolic media. While hyperbolic responses are normally achieved with metamaterials, hexagonal boron nitride (hBN) naturally possesses this property due to the anisotropic phonons in the mid-infrared. Using scattering-type scanning near-field optical microscopy, we studied polaritonic phenomena in hBN. We performed infrared nano-imaging of highly confined and low-loss hyperbolic phonon polaritons in hBN. The polariton wavelength was shown to be governed by the hBN thickness according to a linear law persisting down to few atomic layers [Science, 343, 1125-1129 (2014)]. Additionally, we carried out the modification of hyperbolic response in heterostructures comprised of a mononlayer graphene deposited on hBN. Electrostatic gating of the top graphene layer allows for the modification of wavelength and intensity of hyperbolic phonon polaritons in bulk hBN. The physics of the modification originates from the plasmon-phonon coupling in the hyperbolic medium. Furthermore, we demonstrated the ``hyperlens'' for subdiffractional imaging and focusing using a slab of hBN.

  16. Bootstrapping the Three-Loop Hexagon

    SciTech Connect

    Dixon, Lance J.; Drummond, James M.; Henn, Johannes M.; /Humboldt U., Berlin /Santa Barbara, KITP

    2011-11-08

    We consider the hexagonal Wilson loop dual to the six-point MHV amplitude in planar N = 4 super Yang-Mills theory. We apply constraints from the operator product expansion in the near-collinear limit to the symbol of the remainder function at three loops. Using these constraints, and assuming a natural ansatz for the symbol's entries, we determine the symbol up to just two undetermined constants. In the multi-Regge limit, both constants drop out from the symbol, enabling us to make a non-trivial confirmation of the BFKL prediction for the leading-log approximation. This result provides a strong consistency check of both our ansatz for the symbol and the duality between Wilson loops and MHV amplitudes. Furthermore, we predict the form of the full three-loop remainder function in the multi-Regge limit, beyond the leading-log approximation, up to a few constants representing terms not detected by the symbol. Our results confirm an all-loop prediction for the real part of the remainder function in multi-Regge 3 {yields} 3 scattering. In the multi-Regge limit, our result for the remainder function can be expressed entirely in terms of classical polylogarithms. For generic six-point kinematics other functions are required.

  17. Hexagonal boron-nitride nanomesh magnets

    NASA Astrophysics Data System (ADS)

    Ohata, C.; Tagami, R.; Nakanishi, Y.; Iwaki, R.; Nomura, K.; Haruyama, J.

    2016-09-01

    The formation of magnetic and spintronic devices using two-dimensional (2D) atom-thin layers has attracted attention. Ferromagnetisms (FMs) arising from zigzag-type atomic structure of edges of 2D atom-thin materials have been experimentally observed in graphene nanoribbons, hydrogen (H)-terminated graphene nanomeshes (NMs), and few-layer oxygen (O)-terminated black phosphorus NMs. Herein, we report room-temperature edge FM in few-layer hexagonal boron-nitride (hBN) NMs. O-terminated hBNNMs annealed at 500 °C show the largest FM, while it completely disappears in H-terminated hBNNMs. When hBNNMs are annealed at other temperatures, amplitude of the FM significantly decreases. These are highly in contrast to the case of graphene NMs but similar to the cases of black phosphorus NM and suggest that the hybridization of the O atoms with B(N) dangling bonds of zigzag pore edges, formed at the 500 °C annealing, strongly contribute to this edge FM. Room-temperature FM realizable only by exposing hBNNMs into air opens the way for high-efficiency 2D flexible magnetic and spintronic devices without the use of rare magnetic elements.

  18. Ab-initio study of hexagonal apatites

    NASA Astrophysics Data System (ADS)

    Calderin, Lazaro; Stott, Malcom J.

    2001-03-01

    A silicon stabilized mixture of calcium phosphate phases has been recognized as playing an important role in actively resorbable coatings and in ceramics as bone materials. The nature of this material is being investigated using a variety of techniques including a combination of crystallographic analysis of measured x-ray diffraction spectra, and ab initio quantum mechanics simulations. We have used all-electron, density functional based calculations to investigate a group of hexagonal apatites. The fully relaxed crystallographic structures of hydroxyapatite, and related apatites have been obtained. We will present the results and discuss the nature of the bonding in these materials. The x-ray diffraction pattern and the infra-red spectra have also been obtained and will be compared with experiment. Acknowledgments:This work is part of a collaboration with the Applied Ceramics group of M.Sayer, and with Millenium Biologix Inc. Support of the NSERC of Canada through the award of a Co-operative R & D grant to the collaboration is acknowledged.

  19. Tunable spin wave spectra in two-dimensional Ni{sub 80}Fe{sub 20} antidot lattices with varying lattice symmetry

    SciTech Connect

    Mandal, R.; Barman, S.; Saha, S.; Barman, A.; Otani, Y.

    2015-08-07

    Ferromagnetic antidot lattices are important systems for magnetic data storage and magnonic devices, and understanding their magnetization dynamics by varying their structural parameters is an important problems in magnetism. Here, we investigate the variation in spin wave spectrum in two-dimensional nanoscale Ni{sub 80}Fe{sub 20} antidot lattices with lattice symmetry. By varying the bias magnetic field values in a broadband ferromagnetic resonance spectrometer, we observed a stark variation in the spin wave spectrum with the variation of lattice symmetry. The simulated mode profiles showed further difference in the spatial nature of the modes between different lattices. While for square and rectangular lattices extended modes are observed in addition to standing spin wave modes, all modes in the hexagonal, honeycomb, and octagonal lattices are either localized or standing waves. In addition, the honeycomb and octagonal lattices showed two different types of modes confined within the honeycomb (octagonal) units and between two such consecutive units. Simulated internal magnetic fields confirm the origin of such a wide variation in the frequency and spatial nature of the spin wave modes. The tunability of spin waves with the variation of lattice symmetry is important for the design of future magnetic data storage and magnonic devices.

  20. Synthesis and oxygen content dependent properties of hexagonal DyMnO[subscript 3+delta

    SciTech Connect

    Remsen, S.; Dabrowski, B.; Chmaissem, O.; Mais, J.; Szewczyk, A.

    2011-10-28

    Oxygen deficient polycrystalline samples of hexagonal P6{sub 3}cm (space group No.185) DyMnO{sub 3+{delta}} ({delta} < 0) were synthesized in Ar by intentional decomposition of its perovskite phase obtained in air. The relative stability of these phases is in accord with our previous studies of the temperature and oxygen vacancy dependent tolerance factor. Thermogravimetric measurements have shown that hexagonal samples of DyMnO{sub 3+{delta}} (0 {le} {delta} {le} 0.4) exhibit unusually large excess oxygen content, which readily incorporates on heating near 300 C in various partial-pressures of oxygen atmospheres. Neutron and synchrotron diffraction data show the presence of two new structural phases at {delta} {approx} 0.25 (Hex{sub 2}) and {delta} {approx} 0.40 (Hex{sub 3}). Rietveld refinements of the Hex{sub 2} phase strongly suggest it is well modeled by the R3 space group (No.146). These phases were observed to transform back to P6{sub 3}cm above {approx} 350 C when material becomes stoichiometric in oxygen content ({delta} = 0). Chemical expansion of the crystal lattice corresponding to these large changes of oxygen was found to be 3.48 x 10{sup -2} mol{sup -1}. Thermal expansion of stoichiometric phases were determined to be 11.6 x 10{sup -6} and 2.1 x 10{sup -6} K{sup -1} for the P6{sub 3}cm and Hex{sub 2} phases, respectively. Our measurements also indicate that the oxygen non-stoichiometry of hexagonal RMnO{sub 3+{delta}} materials may have important influence on their multiferroic properties.

  1. Hexagonal plaquette spin-spin interactions and quantum magnetism in a two-dimensional ion crystal

    NASA Astrophysics Data System (ADS)

    Nath, R.; Dalmonte, M.; Glaetzle, A. W.; Zoller, P.; Schmidt-Kaler, F.; Gerritsma, R.

    2015-06-01

    We propose a trapped ion scheme en route to realize spin Hamiltonians on a Kagome lattice which, at low energies, are described by emergent {{{Z}}}2 gauge fields, and support a topological quantum spin liquid ground state. The enabling element in our scheme is the hexagonal plaquette spin-spin interactions in a two-dimensional ion crystal. For this, the phonon-mode spectrum of the crystal is engineered by standing-wave optical potentials or by using Rydberg excited ions, thus generating localized phonon-modes around a hexagon of ions selected out of the entire two-dimensional crystal. These tailored modes can mediate spin-spin interactions between ion-qubits on a hexagonal plaquette when subject to state-dependent optical dipole forces. We discuss how these interactions can be employed to emulate a generalized Balents-Fisher-Girvin model in minimal instances of one and two plaquettes. This model is an archetypical Hamiltonian in which gauge fields are the emergent degrees of freedom on top of the classical ground state manifold. Under realistic situations, we show the emergence of a discrete Gauss’s law as well as the dynamics of a deconfined charge excitation on a gauge-invariant background using the two-plaquettes trapped ions spin-system. The proposed scheme in principle allows further scaling in a future trapped ion quantum simulator, and we conclude that our work will pave the way towards the simulation of emergent gauge theories and quantum spin liquids in trapped ion systems.

  2. Pyramidal Image-Processing Code For Hexagonal Grid

    NASA Technical Reports Server (NTRS)

    Watson, Andrew B.; Ahumada, Albert J., Jr.

    1990-01-01

    Algorithm based on processing of information on intensities of picture elements arranged in regular hexagonal grid. Called "image pyramid" because image information at each processing level arranged in hexagonal grid having one-seventh number of picture elements of next lower processing level, each picture element derived from hexagonal set of seven nearest-neighbor picture elements in next lower level. At lowest level, fine-resolution of elements of original image. Designed to have some properties of image-coding scheme of primate visual cortex.

  3. Effects of the Interfering Harmonics Caused by Imperfect Data Streams on BPSK and QPSK Receivers

    NASA Technical Reports Server (NTRS)

    Nguyen, T. M.; Yeh, H-G.

    1994-01-01

    One of the most pernicious cause for spurious emission and performance degradation in space telemetry systems is the imperfect data stream at the input of the modulator. The imperfection of the data stream can be caused by impalance between -1s and +1s (unbalanced data) and/or by data asymmetry.

  4. 49 CFR 192.713 - Transmission lines: Permanent field repair of imperfections and damages.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 49 Transportation 3 2013-10-01 2013-10-01 false Transmission lines: Permanent field repair of imperfections and damages. 192.713 Section 192.713 Transportation Other Regulations Relating to Transportation... Maintenance § 192.713 Transmission lines: Permanent field repair of imperfections and damages. (a)...

  5. 49 CFR 192.713 - Transmission lines: Permanent field repair of imperfections and damages.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 49 Transportation 3 2010-10-01 2010-10-01 false Transmission lines: Permanent field repair of imperfections and damages. 192.713 Section 192.713 Transportation Other Regulations Relating to Transportation... Maintenance § 192.713 Transmission lines: Permanent field repair of imperfections and damages. (a)...

  6. 49 CFR 192.713 - Transmission lines: Permanent field repair of imperfections and damages.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 49 Transportation 3 2012-10-01 2012-10-01 false Transmission lines: Permanent field repair of imperfections and damages. 192.713 Section 192.713 Transportation Other Regulations Relating to Transportation... Maintenance § 192.713 Transmission lines: Permanent field repair of imperfections and damages. (a)...

  7. Negative index optical chiral metamaterial based on asymmetric hexagonal arrays of metallic triangular nanoprisms

    NASA Astrophysics Data System (ADS)

    Giloan, M.; Astilean, S.

    2014-03-01

    Nanostructures made of two layers of metallic triangular nanoprisms arranged in hexagonal lattice separated by a dielectric layer are theoretically analyzed as chiral metamaterial slabs. Transmitted and reflected electromagnetic field of normally incident circular polarized plane waves are computed using a tri-dimensional (3D) finite-difference time domain (FDTD) algorithm. Chirality and effective constitutive parameters are calculated using the modified S-parameter retrieval method for chiral metamaterials. Different hybridized plasmon modes are induced by the left and right circularly polarized light leading to a chiral behavior of the asymmetric type metamaterials. Negative refractive index due to chirality is obtained in the near infrared range of the spectrum for either left or right polarization.

  8. Van der Waals epitaxy and characterization of hexagonal boron nitride nanosheets on graphene

    NASA Astrophysics Data System (ADS)

    Song, Yangxi; Zhang, Changrui; Li, Bin; Ding, Guqiao; Jiang, Da; Wang, Haomin; Xie, Xiaoming

    2014-07-01

    Graphene is highly sensitive to environmental influences, and thus, it is worthwhile to deposit protective layers on graphene without impairing its excellent properties. Hexagonal boron nitride (h-BN), a well-known dielectric material, may afford the necessary protection. In this research, we demonstrated the van der Waals epitaxy of h-BN nanosheets on mechanically exfoliated graphene by chemical vapor deposition, using borazine as the precursor to h-BN. The h-BN nanosheets had a triangular morphology on a narrow graphene belt but a polygonal morphology on a larger graphene film. The h-BN nanosheets on graphene were highly crystalline, except for various in-plane lattice orientations. Interestingly, the h-BN nanosheets preferred to grow on graphene than on SiO2/Si under the chosen experimental conditions, and this selective growth spoke of potential promise for application to the preparation of graphene/h-BN superlattice structures fabricated on SiO2/Si.

  9. Van der Waals epitaxy and characterization of hexagonal boron nitride nanosheets on graphene.

    PubMed

    Song, Yangxi; Zhang, Changrui; Li, Bin; Ding, Guqiao; Jiang, Da; Wang, Haomin; Xie, Xiaoming

    2014-01-01

    Graphene is highly sensitive to environmental influences, and thus, it is worthwhile to deposit protective layers on graphene without impairing its excellent properties. Hexagonal boron nitride (h-BN), a well-known dielectric material, may afford the necessary protection. In this research, we demonstrated the van der Waals epitaxy of h-BN nanosheets on mechanically exfoliated graphene by chemical vapor deposition, using borazine as the precursor to h-BN. The h-BN nanosheets had a triangular morphology on a narrow graphene belt but a polygonal morphology on a larger graphene film. The h-BN nanosheets on graphene were highly crystalline, except for various in-plane lattice orientations. Interestingly, the h-BN nanosheets preferred to grow on graphene than on SiO2/Si under the chosen experimental conditions, and this selective growth spoke of potential promise for application to the preparation of graphene/h-BN superlattice structures fabricated on SiO2/Si.

  10. A study of the magnetic after-effect in w-hexagonal compounds

    SciTech Connect

    Francisco, C. de; Munoz, J.M.; Torres, R. . Dept. Electricidad y Electronica); Torres, L.; Iniguez, J.; Zazo, M. . Dept. Fisica Aplicada)

    1993-11-01

    The relaxation of the initial permeability is measured in barium ferrite samples with W-hexagonal structure. In the temperature range between 80 and 420 K three clear relaxation processes are found which features are Influenced by sintering temperature and atmosphere. Peak C (370 K) seems to arise from long range cation diffusion processes via vacancies, with activation energies around 1.1 eV. Peak B (300 K) can be attributed to local rearrangements of ferrous cations in octahedral position via lattice vacancies and can be fitted by the superposition of two Debye processes with activation energies close to 0.80 and 0.84 eV. Peak A exhibits the characteristics of a single Debye process with activation energy of the order of 0.48 eV and its origin is not yet clear.

  11. Effect of hexagonal patterned arrays and defect geometry on the critical current of superconducting films

    NASA Astrophysics Data System (ADS)

    Sadovskyy, I. A.; Wang, Y. L.; Xiao, Z.-L.; Kwok, W.-K.; Glatz, A.

    2017-02-01

    Understanding the effect of pinning on the vortex dynamics in superconductors is a key factor towards controlling critical current values. Large-scale simulations of vortex dynamics can provide a rational approach to achieve this goal. Here, we use the time-dependent Ginzburg-Landau equations to study thin superconducting films with artificially created pinning centers arranged periodically in hexagonal lattices. We calculate the critical current density for various geometries of the pinning centers—varying their size, strength, and density. Furthermore, we shed light upon the influence of pattern distortion on the magnetic-field-dependent critical current. We compare our result directly with available experimental measurements on patterned molybdenum-germanium films, obtaining good agreement. Our results give important systematic insights into the mechanisms of pinning in these artificial pinning landscapes and open a path for tailoring superconducting films with desired critical current behavior.

  12. Edge Dislocations Triggered Surface Instability in Tensile Epitaxial Hexagonal Nitride Semiconductor.

    PubMed

    Cheng, Jianpeng; Yang, Xuelin; Zhang, Jie; Hu, Anqi; Ji, Panfeng; Feng, Yuxia; Guo, Lei; He, Chenguang; Zhang, Lisheng; Xu, Fujun; Tang, Ning; Wang, Xinqiang; Shen, Bo

    2016-12-14

    Understanding the semiconductor surface and its properties including surface stability, atomic morphologies, and even electronic states is of great importance not only for understanding surface growth kinetics but also for evaluating the degree to which they affect the devices' performance. Here, we report studies on the nanoscale fissures related surface instability in AlGaN/GaN heterostructures. Experimental results reveal that edge dislocations are actually the root cause of the surface instability. The nanoscale fissures are initially triggered by the edge dislocations, and the subsequent evolution is associated with tensile lattice-mismatch stress and hydrogen etching. Our findings resolve a long-standing problem on the surface instability in AlGaN/GaN heterostructures and will also lead to new understandings of surface growth kinetics in other hexagonal semiconductor systems.

  13. Fabrication of hexagonal ZnO nanorods on porous carbon matrix by microwave irradiation.

    PubMed

    Suresh, P; Vijaya, J Judith; Kennedy, L John

    2013-04-01

    The hexagonal ZnO nanorods supported activated carbon (ZSAC) was successfully prepared using zinc nitrate hexahydrate and urea through microwave irradiation. The method of preparation is simple and cost effective. The activated carbon (AC) with high surface area (446.44 m2/g), pore volume (00.21 cm3/g) and average pore diameter (01.89 nm) was employed as a matrix support for the growth of ZnO nanorods. The XRD results affirm the formation of wurtzite ZnO nanostructures. The FT-IR studies disclose the presence of varied functional groups present in ZSAC. The HR-SEM images reveal the pore morphology of AC and hexagonal shape of ZnO nanorods formed. The E(g) value obtained from Kubelka-Munk transformed reflectance spectra is about 3.43 eV. The photoluminescence emissions reveal the defects in the crystal lattice. The ZSAC thus prepared would perform substantial role in the area of catalysis.

  14. Stanene: Atomically Thick Free-standing Layer of 2D Hexagonal Tin

    PubMed Central

    Saxena, Sumit; Chaudhary, Raghvendra Pratap; Shukla, Shobha

    2016-01-01

    Stanene is one of most important of 2D materials due to its potential to demonstrate room temperature topological effects due to opening of spin-orbit gap. In this pursuit we report synthesis and investigation of optical properties of stanene up to few layers, a two-dimensional hexagonal structural analogue of graphene. Atomic scale morphological and elemental characterization using HRTEM equipped with SAED and EDAX detectors confirm the presence of hexagonal lattice of Sn atoms. The position of Raman peak along with the inter-planar ‘d’ spacing obtained from SAED for prepared samples are in good agreement with that obtained from first principles calculations and confirm that the sheets are not (111) α-Sn sheets. Further, the optical signature calculated using density functional theory at ~191 nm and ~233 nm for low buckled stanene are in qualitative agreement with the measured UV-Vis absorption spectrum. AFM measurements suggest interlayer spacing of ~0.33 nm in good agreement with that reported for epitaxial stanene sheets. No traces of oxygen were observed in the EDAX spectrum suggesting the absence of any oxidized phases. This is also confirmed by Raman measurements by comparing with oxidized stanene sheets. PMID:27492139

  15. Overtones of interlayer shear modes in the phonon-assisted emission spectrum of hexagonal boron nitride

    NASA Astrophysics Data System (ADS)

    Vuong, T. Q. P.; Cassabois, G.; Valvin, P.; Jacques, V.; Cuscó, R.; Artús, L.; Gil, B.

    2017-01-01

    We address the intrinsic optical properties of hexagonal boron nitride in deep ultraviolet. We show that the fine structure of the phonon replicas arises from overtones involving up to six low-energy interlayer shear modes. These lattice vibrations are specific to layered compounds since they correspond to the shear rigid motion between adjacent layers, with a characteristic energy of about 6-7 meV. We obtain a quantitative interpretation of the multiplet observed in each phonon replica under the assumption of a cumulative Gaussian broadening as a function of the overtone index, and with a phenomenological line broadening taken identical for all phonon types. We show from our quantitative interpretation of the full emission spectrum above 5.7 eV that the energy of the involved phonon mode is 6.8 ±0.5 meV, in excellent agreement with temperature-dependent Raman measurements of the low-energy interlayer shear mode in hexagonal boron nitride. We highlight the unusual properties of this material where the optical response is tailored by the phonon group velocities in the middle of the Brillouin zone.

  16. Factors controlling phase formation of novel Sr-based Y-type hexagonal ferrite nanoparticles

    NASA Astrophysics Data System (ADS)

    Tholkappiyan, R.; Vishista, K.; Hamed, Fathalla

    2017-02-01

    New Sr-based Y-type nanocrystalline hexagonal ferrites with a nominal chemical composition of Sr 2Mg 2Fe 12 O 22 (Sr 2Y) were prepared by autocombustion from mixtures of Sr(NO 3) 2, Mg(NO 3) 2ṡ6H 2O and Fe(NO 3) 3ṡ9H 2O. The newly prepared Sr 2Y nanocrystalline particles were characterized by powder X-ray diffraction (XRD). A well crystalline phase of Sr 2Y with hexagonal crystal structure was observed. Fourier transform infrared spectroscopy (FTIR) studies revealed the information about the positions of the ions and their bonds within the lattice structure of the Sr 2Y. The chemical elements and their oxidation states in the Sr 2Y hexaferrites were determined using X-ray photoelectron spectroscopy (XPS). The XRD, FTIR and XPS studies confirmed the formation of Sr 2Mg 2Fe 12 O 22 hexaferrites. The morphology and porosity of the prepared Sr 2Y nanocrystalline Sr 2Y hexaferrite particles were studied by field emission scanning electron microscopy. The magnetic properties of Sr 2Y hexaferrites showed dependence on the methods of preparation conditions and calcination treatments. The values of coercivity, saturation magnetization and retentivity were in the range of 21.33-19.66 kA m -1, 42.44- 38.72 emu g -1 and 10.05-13.19 emu g -1 respectively.

  17. Parametric Study on the Response of Compression-Loaded Composite Shells With Geometric and Material Imperfections

    NASA Technical Reports Server (NTRS)

    Hilburger, Mark W.; Starnes, James H., Jr.

    2004-01-01

    The results of a parametric study of the effects of initial imperfections on the buckling and postbuckling response of three unstiffened thinwalled compression-loaded graphite-epoxy cylindrical shells with different orthotropic and quasi-isotropic shell-wall laminates are presented. The imperfections considered include initial geometric shell-wall midsurface imperfections, shell-wall thickness variations, local shell-wall ply-gaps associated with the fabrication process, shell-end geometric imperfections, nonuniform applied end loads, and variations in the boundary conditions including the effects of elastic boundary conditions. A high-fidelity nonlinear shell analysis procedure that accurately accounts for the effects of these imperfections on the nonlinear responses and buckling loads of the shells is described. The analysis procedure includes a nonlinear static analysis that predicts stable response characteristics of the shells and a nonlinear transient analysis that predicts unstable response characteristics.

  18. Analytical and numerical modeling of non-collinear shear wave mixing at an imperfect interface

    NASA Astrophysics Data System (ADS)

    Zhang, Ziyin; Nagy, Peter B.; Hassan, Waled

    2016-02-01

    Non-collinear shear wave mixing at an imperfect interface between two solids can be exploited for nonlinear ultrasonic assessment of bond quality. In this study we developed two analytical models for nonlinear imperfect interfaces. The first model uses a finite nonlinear interfacial stiffness representation of an imperfect interface of vanishing thickness, while the second model relies on a thin nonlinear interphase layer to represent an imperfect interface region. The second model is actually a derivative of the first model obtained by calculating the equivalent interfacial stiffness of a thin isotropic nonlinear interphase layer in the quasi-static approximation. The predictions of both analytical models were numerically verified by comparison to COMSOL finite element simulations. These models can accurately predict the excess nonlinearity caused by interface imperfections based on the strength of the reflected and transmitted mixed longitudinal waves produced by them under non-collinear shear wave interrogation.

  19. Analysis of magnetic aftereffects in strontium hexagonal ferrites with W-type stoichiometry

    NASA Astrophysics Data System (ADS)

    Hernández-Gómez, P.; Torres, C.; de Francisco, C.; Muñoz, J. M.; Hisatake, K.

    2003-05-01

    The relaxation of the initial permeability has been measured in polycrystalline Sr hexaferrites with the initial composition of W phase (SrOṡ9Fe2O3). The samples have been prepared by means of standard ceramic techniques at different temperatures in the 1250 °Clattice vacancies within the octahedral sites in spinel-like S blocks whereas D peak is associated with a similar process in face-sharing octahedral sites located in the hexagonal R blocks of the lattice. Regarding the corresponding isochronal spectra of barium W-type ferrites, we can observe that the C process centered at 240 K does not appear in Sr hexaferrites. This suggests that the relaxation processes which take place in the hexagonal R blocks are not favorable in Sr hexaferrites, probably due to the smaller size of the Sr ion.

  20. Dirac plasmons in bipartite lattices of metallic nanoparticles

    NASA Astrophysics Data System (ADS)

    Jebb Sturges, Thomas; Woollacott, Claire; Weick, Guillaume; Mariani, Eros

    2015-03-01

    We study theoretically ‘graphene-like’ plasmonic metamaterials constituted by two-dimensional arrays of metallic nanoparticles, including perfect honeycomb structures with and without inversion symmetry, as well as generic bipartite lattices. The dipolar interactions between localized surface plasmons (LSPs) in different nanoparticles gives rise to collective plasmons (CPs) that extend over the whole lattice. We study the band structure of CPs and unveil its tunability with the orientation of the dipole moments associated with the LSPs. Depending on the dipole orientation, we identify a phase diagram of gapless or gapped phases in the CP dispersion. We show that the gapless phases in the phase diagram are characterized by CPs behaving as massless chiral Dirac particles, in analogy with electrons in graphene. When the inversion symmetry of the honeycomb structure is broken, CPs are described as gapped chiral Dirac modes with an energy-dependent Berry phase. We further relax the geometric symmetry of the honeycomb structure by analysing generic bipartite hexagonal lattices. In this case we study the evolution of the phase diagram and unveil the emergence of a sequence of topological phase transitions when one hexagonal sublattice is progressively shifted with respect to the other.

  1. Dissipative photonic lattice solitons.

    PubMed

    Ultanir, Erdem A; Stegeman, George I; Christodoulides, Demetrios N

    2004-04-15

    We show that discrete dissipative optical lattice solitons are possible in waveguide array configurations that involve periodically patterned semiconductor optical amplifiers and saturable absorbers. The characteristics of these low-power soliton states are investigated, and their propagation constant eigenvalues are mapped on Floquet-Bloch band diagrams. The prospect of observing such low-power dissipative lattice solitons is discussed in detail.

  2. 14. DETAIL OF ROOF SUPPORT BEAMS BRACED AGAINST HEXAGONAL WOODEN ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    14. DETAIL OF ROOF SUPPORT BEAMS BRACED AGAINST HEXAGONAL WOODEN COMPRESSION RING AT TOP OF CENTRAL ROOF TRUSS. - Saratoga Gas Light Company, Gasholder No. 2, Niagara Mohawk Power Corporation Substation Facility, intersection of Excelsior & East Avenues, Saratoga Springs, NY

  3. Hydrogen bonding in the hexagonal ice surface.

    PubMed

    Barnett, Irene Li; Groenzin, Henning; Shultz, Mary Jane

    2011-06-16

    A recently developed technique in sum frequency generation spectroscopy, polarization angle null (or PAN-SFG), is applied to two orientations of the prism face of hexagonal ice. It is found that the vibrational modes of the surface are similar in different faces. As in the basal face, the prism face of ice contains five dominant resonances: 3096, 3146, 3205, 3253, and 3386 cm(-1). On the basal face, the reddest resonance occurs at 3098 cm(-1); within the bandwidth, the same as the prism face. On both the prism and basal faces, this mode contains a significant quadrupole component and is assigned to the bilayer stitching hydrogen bonds. The bluest of the resonances, 3386 cm(-1), occurs slightly blue-shifted at 3393 cm(-1) in the basal face. The prism face has two orientations: one with the optic or c axis in the input plane (the plane formed by the surface normal and the interrogating beam propagation) and one with the c axis perpendicular to the input plane. The 3386 cm(-1) mode has significant intensity only with the c axis in the input plane. On the basis of these orientation characteristics, the 3386 cm(-1) mode is assigned to double-donor molecules in either the top half bilayer or in the lower half bilayer. On the basis of frequency considerations, it is assigned to double-donor molecules in the top half bilayer. These are water molecules containing a nonbonded lone pair. In addition to identification of the components of the broad hydrogen-bonded region, PAN-SFG measures the tangential vs longitudinal content of the vibrational modes. In accord with previous suggestions, the lower frequency modes are predominantly tangential, whereas the higher frequency modes are mainly longitudinal. On the prism face, the 3386 cm(-1) mode is entirely longitudinal.

  4. ScGaN alloy growth by molecular beam epitaxy: Evidence for a metastable layered hexagonal phase

    SciTech Connect

    Constantin, Costel; Al-Brithen, Hamad; Haider, Muhammad B.; Ingram, David; Smith, Arthur R.

    2004-11-15

    Alloy formation in ScGaN is explored using rf molecular beam epitaxy over the Sc fraction range x=0-100%. Optical and structural analysis show separate regimes of growth, namely (I) wurtzitelike but having local lattice distortions in the vicinity of the Sc{sub Ga} substitutions for small x (x{<=}0.17) (II) a transitional regime for intermediate x, and (III) cubic, rocksaltlike for large x(x{>=}0.54). In regimes I and III, the direct optical transition decreases approximately linearly with increasing x but with an offset over region II. Importantly, it is found that for regime I, an anisotropic lattice expansion occurs with increasing x in which a increases much more than c. These observations support the prediction of Farrer and Bellaiche [Phys. Rev. B 66, 201203-1 (2002)] of a metastable layered hexagonal phase of ScN, denoted h-ScN.

  5. Solar concentrating properties of truncated hexagonal, pyramidal and circular cones

    NASA Technical Reports Server (NTRS)

    Burkhard, D. G.; Strobel, G. L.; Shealy, D. L.

    1978-01-01

    The solar concentrating properties of specularly reflecting truncated pyramidal, hexagonal, and circular cones are evaluated. Pyramidal and hexagonal configurations are discussed with reference to the concentration factor as a function of half apex angle and the length of the side over the width, and to the irradiance distribution. Expressions are derived for the concentration factor and the irradiance at the base of a circular cone when the sunlight is incident normal to the aperture and for oblique incidence.

  6. Epitaxial Hexagonal Ferrites for Millimeter Wave Tunable Filters.

    DTIC Science & Technology

    1982-12-13

    anisotropy fields which, in effect, provide built-in biasing. The result is that ferrite components, similar to those used in microwave systems, can operate... method for growing hexagonal ferrites in the form of single crystal layers on non-magnetic, trAnsparmat subsrates - . The LPE method circumvents... method , single crystal hexagonal ferrites which are superior in quality to those grown by conventional methods . In order to have a more specific goal

  7. Synthesis and Characterization of Hexagonal Boron Nitride (h- BN) Films

    DTIC Science & Technology

    2014-01-09

    Synthesis 1. Diborane- ammonia (B2H6-NH3- gases): Early results with these precursors were published in 2012. 5 Briefly, LPCVD growth of h-BN in a hot-wall...Approved for public release; distribution is unlimited. Synthesis and Characterization of Hexagonal Boron Nitride (h- BN) Films. The views, opinions and...1 ABSTRACT Number of Papers published in peer-reviewed journals: Synthesis and Characterization of Hexagonal Boron Nitride (h-BN) Films. Report Title

  8. Electrical contact to carbon nanotubes encapsulated in hexagonal boron nitride

    NASA Astrophysics Data System (ADS)

    Huang, Jhao-Wun; Pan, Cheng; Tran, Son; Taniguchi, Takashi; Bockrath, Marc; Lau, Jeanie

    2015-03-01

    Hexagonal boron nitride has been an excellent platform for low dimensional materials. We have fabricated ultra clean single-walled carbon nanotube(SWNT) devices encapsulated in hexagonal boron nitride by a dry transfer technique. Contacts to the SWNTs were made by reactive ion etching to expose the ends of SWNTs, followed by metal deposition. Ohmic contacts to SWNTs were achieved. We will discuss the quality of the contacts using different combinations of metals and present latest transport data.

  9. Percolation in spatial evolutionary prisoner's dilemma game on two-dimensional lattices.

    PubMed

    Choi, Woosik; Yook, Soon-Hyung; Kim, Yup

    2015-11-01

    We study the spatial evolutionary prisoner's dilemma game with updates of imitation max on triangular, hexagonal, and square lattices. We use the weak prisoner's dilemma game with a single parameter b. Due to the competition between the temptation value b and the coordination number z of the base lattice, a greater variety of percolation properties is expected to occur on the lattice with the larger z. From the numerical analysis, we find six different regimes on the triangular lattice (z=6). Regardless of the initial densities of cooperators and defectors, cooperators always percolate in the steady state in two regimes for small b. In these two regimes, defectors do not percolate. In two regimes for the intermediate value of b, both cooperators and defectors undergo percolation transitions. The defector always percolates in two regimes for large b. On the hexagonal lattice (z=3), there exist two distinctive regimes. For small b, both the cooperators and the defectors undergo percolation transitions while only defectors always percolate for large b. On the square lattice (z=4), there exist three regimes. Combining with the finite-size scaling analyses, we show that all the observed percolation transitions belong to the universality class of the random percolation. We also show how the detailed growth mechanism of cooperator and defector clusters decides each regime.

  10. Percolation in spatial evolutionary prisoner's dilemma game on two-dimensional lattices

    NASA Astrophysics Data System (ADS)

    Choi, Woosik; Yook, Soon-Hyung; Kim, Yup

    2015-11-01

    We study the spatial evolutionary prisoner's dilemma game with updates of imitation max on triangular, hexagonal, and square lattices. We use the weak prisoner's dilemma game with a single parameter b . Due to the competition between the temptation value b and the coordination number z of the base lattice, a greater variety of percolation properties is expected to occur on the lattice with the larger z . From the numerical analysis, we find six different regimes on the triangular lattice (z =6 ). Regardless of the initial densities of cooperators and defectors, cooperators always percolate in the steady state in two regimes for small b . In these two regimes, defectors do not percolate. In two regimes for the intermediate value of b , both cooperators and defectors undergo percolation transitions. The defector always percolates in two regimes for large b . On the hexagonal lattice (z =3 ), there exist two distinctive regimes. For small b , both the cooperators and the defectors undergo percolation transitions while only defectors always percolate for large b . On the square lattice (z =4 ), there exist three regimes. Combining with the finite-size scaling analyses, we show that all the observed percolation transitions belong to the universality class of the random percolation. We also show how the detailed growth mechanism of cooperator and defector clusters decides each regime.

  11. A realistic lattice example

    SciTech Connect

    Courant, E.D.; Garren, A.A.

    1985-10-01

    A realistic, distributed interaction region (IR) lattice has been designed that includes new components discussed in the June 1985 lattice workshop. Unlike the test lattices, the lattice presented here includes utility straights and the mechanism for crossing the beams in the experimental straights. Moreover, both the phase trombones and the dispersion suppressors contain the same bending as the normal cells. Vertically separated beams and 6 Tesla, 1-in-1 magnets are assumed. Since the cells are 200 meters long, and have 60 degree phase advance, this lattice has been named RLD1, in analogy with the corresponding test lattice, TLD1. The quadrupole gradient is 136 tesla/meter in the cells, and has similar values in other quadrupoles except in those in the IR`s, where the maximum gradient is 245 tesla/meter. RLD1 has distributed IR`s; however, clustered realistic lattices can easily be assembled from the same components, as was recently done in a version that utilizes the same type of experimental and utility straights as those of RLD1.

  12. Superalloy Lattice Block Structures

    NASA Technical Reports Server (NTRS)

    Whittenberger, J. D.; Nathal, M. V.; Hebsur, M. G.; Kraus, D. L.

    2003-01-01

    In their simplest form, lattice block panels are produced by direct casting and result in lightweight, fully triangulated truss-like configurations which provide strength and stiffness [2]. The earliest realizations of lattice block were made from A1 and steels, primarily under funding from the US Navy [3]. This work also showed that the mechanical efficiency (eg., specific stiffness) of lattice block structures approached that of honeycomb structures [2]. The lattice architectures are also less anisotropic, and the investment casting route should provide a large advantage in cost and temperature capability over honeycombs which are limited to alloys that can be processed into foils. Based on this early work, a program was initiated to determine the feasibility of extending the high temperature superalloy lattice block [3]. The objective of this effort was to provide an alternative to intermetallics and composites in achieving a lightweight high temperature structure without sacrificing the damage tolerance and moderate cost inherent in superalloys. To establish the feasibility of the superalloy lattice block concept, work was performed in conjunction with JAMCORP, Inc. Billerica, MA, to produce a number of lattice block panels from both IN71 8 and Mar-M247.

  13. Quasicrystallography from Bn lattices

    NASA Astrophysics Data System (ADS)

    Koca, M.; Koca, N. O.; Al-Mukhaini, A.; Al-Qanabi, A.

    2014-11-01

    We present a group theoretical analysis of the hypercubic lattice described by the affine Coxeter-Weyl group Wa (Bn). An h-fold symmetric quasicrystal structure follows from the hyperqubic lattice whose point group is described by the Coxeter-Weyl group W (Bn) with the Coxeter number h=2n. Higher dimensional cubic lattices are explicitly constructed for n = 4,5,6 by identifying their rank-3 Coxeter subgroups and maximal dihedral subgroups. Decomposition of their Voronoi cells under the respective rank-3 subgroups W (A3), W (H2)×W (A1) and W (H3)lead to the rhombic dodecahedron, rhombic icosahedron and rhombic triacontahedron respectively. Projection of the lattice B4 describes a quasicrystal structure with 8-fold symmetry. The B5 lattice leads to quasicrystals with both 5fold and 10 fold symmetries. The lattice B6 projects on a 12-fold symmetric quasicrystal as well as a 3D icosahedral quasicrystal depending on the choice of subspace of projections. The projected sets of lattice points are compatible with the available experimental data.

  14. Many-body localization in imperfectly isolated quantum systems.

    PubMed

    Johri, Sonika; Nandkishore, Rahul; Bhatt, R N

    2015-03-20

    We use numerical exact diagonalization to analyze which aspects of the many-body localization phenomenon survive in an imperfectly isolated setting, when the system of interest is weakly coupled to a thermalizing environment. We show that widely used diagnostics (such as many-body level statistics and expectation values in exact eigenstates) cease to show signatures of many-body localization above a critical coupling that is exponentially small in the size of the environment. However, we also identify alternative diagnostics for many-body localization, in the spectral functions of local operators. Diagnostics include a discrete spectrum and a hierarchy of energy gaps, including a universal gap at zero frequency. These alternative diagnostics are shown to be robust, and continue to show signatures of many-body localization as long as the coupling to the bath is weaker than the characteristic energy scales in the system. We also examine how these signatures disappear when the coupling to the environment becomes larger than the characteristic energy scales of the system.

  15. Modeling species occurrence dynamics with multiple states and imperfect detection

    USGS Publications Warehouse

    MacKenzie, D.I.; Nichols, J.D.; Seamans, M.E.; Gutierrez, R.J.

    2009-01-01

    Recent extensions of occupancy modeling have focused not only on the distribution of species over space, but also on additional state variables (e.g., reproducing or not, with or without disease organisms, relative abundance categories) that provide extra information about occupied sites. These biologist-driven extensions are characterized by ambiguity in both species presence and correct state classification, caused by imperfect detection. We first show the relationships between independently published approaches to the modeling of multistate occupancy. We then extend the pattern-based modeling to the case of sampling over multiple seasons or years in order to estimate state transition probabilities associated with system dynamics. The methodology and its potential for addressing relevant ecological questions are demonstrated using both maximum likelihood (occupancy and successful reproduction dynamics of California Spotted Owl) and Markov chain Monte Carlo estimation approaches (changes in relative abundance of green frogs in Maryland). Just as multistate capture-recapture modeling has revolutionized the study of individual marked animals, we believe that multistate occupancy modeling will dramatically increase our ability to address interesting questions about ecological processes underlying population-level dynamics. ?? 2009 by the Ecological Society of America.

  16. A comparative analysis of the evolution of imperfect mimicry.

    PubMed

    Penney, Heather D; Hassall, Christopher; Skevington, Jeffrey H; Abbott, Kevin R; Sherratt, Thomas N

    2012-03-21

    Although exceptional examples of adaptation are frequently celebrated, some outcomes of natural selection seem far from perfect. For example, many hoverflies (Diptera: Syrphidae) are harmless (Batesian) mimics of stinging Hymenoptera. However, although some hoverfly species are considered excellent mimics, other species bear only a superficial resemblance to their models and it is unclear why this is so. To evaluate hypotheses that have been put forward to explain interspecific variation in the mimetic fidelity of Palearctic Syrphidae we use a comparative approach. We show that the most plausible explanation is that predators impose less selection for mimetic fidelity on smaller hoverfly species because they are less profitable prey items. In particular, our findings, in combination with previous results, allow us to reject several key hypotheses for imperfect mimicry: first, human ratings of mimetic fidelity are positively correlated with both morphometric measures and avian rankings, indicating that variation in mimetic fidelity is not simply an illusion based on human perception; second, no species of syrphid maps out in multidimensional space as being intermediate in appearance between several different hymenopteran model species, as the multimodel hypothesis requires; and third, we find no evidence for a negative relationship between mimetic fidelity and abundance, which calls into question the kin-selection hypothesis. By contrast, a strong positive relationship between mimetic fidelity and body size supports the relaxed-selection hypothesis, suggesting that reduced predation pressure on less profitable prey species limits the selection for mimetic perfection.

  17. Effect of Surface Imperfections and Excrescences on the Crossflow Instability

    NASA Astrophysics Data System (ADS)

    Tufts, Matthew; Duncan, Glen, Jr.; Crawford, Brian; Reed, Helen; Saric, William

    2012-11-01

    Presented is analysis of the planned SWIFTER experiment to be flown on Texas A&M University's O-2A aircraft. Simultaneous control of the crossflow and streamwise boundary-layer instabilities is a challenge for laminar flow control on swept wings. Solving this problem is an active area of research, with a specific need to quantify the effect of surface imperfections and outer mold line excrescences on crossflow instabilities. The SWIFTER test article is a modification of a prior-tested flight model, with the additional capability of creating controlled excrescences in flight. Using a finite-element Navier-Stokes solution and a spectrally accurate boundary-layer solver, coupled with linear and nonlinear stability analyses, we show that the flow field over the test article is well suited to this study. Results are compared with flight data. The work is supported by the Air Force Research Laboratory through General Dynamics Information Technology, Inc. under sub Agreement No USAF-3446-11-50-SC-01 and the Texas A&M Supercomputing Facility.

  18. Is imperfection becoming easier to live with for doctors?

    PubMed Central

    Aasland, Olaf G

    2017-01-01

    Objective Being involved in serious patient injury is devastating for most doctors. During the last two decades, several efforts have been launched to improve Norwegian doctors’ coping with adverse events and complaints. Methods The method involved survey to a representative sample of 1792 Norwegian doctors in 2012. The questions on adverse events and its effects were previously asked in 2000. Results Response rate was 71%. More doctors reported to have been involved in episodes with serious patient harm in 2012 (35%) than in 2000 (28%), and more of the episodes were reported as required by law. Doctors below age 50 report better support from colleagues, more collegial retrospective discussion on the event and less patient/family blame. In all, 27% of the doctors had been reported to the Norwegian Board of Health Supervision; 79% of these complaints were rejected; 73% of the doctors who had received a reaction from the health authorities found the reaction reasonable, but almost one out of five practiced more testing and referrals after a complaint and 25% claimed that the complaint had made them into a more fearful doctor. Conclusion Our results indicate that adverse events are being met more openly in 2012 than in 2000, and that coping with imperfection and patient complaints is less devastating for new generations of doctors.

  19. Imperfect supercritical bifurcation in a three-dimensional turbulent wake.

    PubMed

    Cadot, Olivier; Evrard, Antoine; Pastur, Luc

    2015-06-01

    The turbulent wake of a square-back body exhibits a strong bimodal behavior. The wake randomly undergoes symmetry-breaking reversals between two mirror asymmetric steady modes [reflectional symmetry-breaking (RSB) modes]. The characteristic time for reversals is about 2 or 3 orders of magnitude larger than the natural time for vortex shedding. Studying the effects of the proximity of a ground wall together with the Reynolds number, it is shown that the bimodal behavior is the result of an imperfect pitchfork bifurcation. The RSB modes correspond to the two stable bifurcated branches resulting from an instability of the stable symmetric wake. An attempt to stabilize the unstable symmetric wake is investigated using a passive control technique. Although the controlled wake still exhibits strong fluctuations, the bimodal behavior is suppressed and the drag reduced. This promising experiment indicates the possible existence of an unstable solution branch corresponding to a reflectional symmetry preserved (RSP) mode. This work is encouraging to develop a control strategy based on a stabilization of this RSP mode to reduce mean drag and lateral force fluctuations.

  20. Graphene antidot lattices as potential electrode materials for supercapacitors

    NASA Astrophysics Data System (ADS)

    Liu, Lizhao; Yue, Xin; Zhao, Jijun; Cheng, Qian; Tang, Jie

    2015-05-01

    Thermodynamic stabilities and electronic properties of graphene antidot lattices with hexagonal holes were examined using density functional theory calculations and several crucial factors related to the applications of supercapacitors were discussed. For the graphene antidot lattices with different hole sizes, the formation energy per edge length is about 0.50∼0.60 eV/nm, which is comparable to that of graphene nanoribbon edges. Within a hole density of 10%, the graphene antidot lattices can maintain the excellent electronic properties of perfect graphene due to negligible intervalley scattering. Further increasing the hole density will open a band gap. Taking the potassium chloride (KCl) electrolyte as an example, we further investigated the diffusion behaviors of potassium (K) and chlorine (Cl) atoms through the graphene antidot lattices. It was shown that K and Cl atoms can go through the holes with nearly no barrier at an appropriate hole size of 0.54 nm, which gives an optimum pore diameter of ∼0.86 nm. Therefore, the excellent graphene-like electronic properties and good penetrability for ions suggest promising applications of graphene antidot lattices in the field of supercapacitors.

  1. Effects of Imperfections on the Buckling Response of Compression-Loaded Composite Shells

    NASA Technical Reports Server (NTRS)

    Hilburger, Mark W.; Starnes, James H., Jr.

    2002-01-01

    The results of an experimental and analytical study of the effects of initial imperfections on the buckling and postbuckling response of three unstiffened thin-walled compression-loaded graphite-epoxy cylindrical shells with different orthotropic and quasi-isotropic shell-wall laminates are presented. The results identify the effects of traditional and non-traditional initial imperfections on the non-linear response and buckling loads of the shells. The traditional imperfections include the geometric shell-wall mid-surface imperfect ions that are commonly discussed in the literature on thin shell buckling. The non-traditional imperfections include shell-wall thickness variations local shell-wall ply-gaps associated with the fabrication process, sheltered geometric imperfections, non-uniform applied end loads, and variations in the boundary conditions including the effects of elastic boundary conditions. A high-fidelity non-linear shell analysis procedure that accurately accounts for the effects of these traditional and non-traditional imperfections on the nonlinear response, and buckling loads of the shells is described. The analysis procedure includes a non-linear static analysis that predicts stable response characteristics of the shells and a non-linear transient analysis that predicts unstable response characteristics.

  2. Jammed lattice sphere packings

    NASA Astrophysics Data System (ADS)

    Kallus, Yoav; Marcotte, Étienne; Torquato, Salvatore

    2013-12-01

    We generate and study an ensemble of isostatic jammed hard-sphere lattices. These lattices are obtained by compression of a periodic system with an adaptive unit cell containing a single sphere until the point of mechanical stability. We present detailed numerical data about the densities, pair correlations, force distributions, and structure factors of such lattices. We show that this model retains many of the crucial structural features of the classical hard-sphere model and propose it as a model for the jamming and glass transitions that enables exploration of much higher dimensions than are usually accessible.

  3. The extended family of hexagonal molybdenum oxide

    SciTech Connect

    Hartl, Monika; Daemen, Luke; Lunk, J H; Hartl, H; Frisk, A T; Shendervich, I; Mauder, D; Feist, M; Eckelt, R

    2009-01-01

    Over the last 40 years, a large number of isostructural compounds in the system MoO{sub 3}-NH{sub 3}-H{sub 2}O have been published. The reported molecular formulae of 'hexagonal molybdenum oxide' (HEMO) varied from MoO{sub 3}, MoO{sub 3} {center_dot} 0.33NH{sub 3}, MoO{sub 3} {center_dot} nH{sub 2}O (0.09 {le} n {le} 0.69) to MoO{sub 3} {center_dot} mNH{sub 3} {center_dot} nH{sub 2}O (0.09 {le} m {le} 0.20; 0.18 {le} n {le} 0.60). Samples, prepared by the acidification route, were investigated using thermal analysis coupled on-line to a mass spectrometer for evolved gas analysis; X-ray powder diffraction; Fourier Transform Infrared, Raman and Magic-Angle-Spinning {sup 1}H-NMR spectroscopy; Incoherent Inelastic Neutron Scattering. The X-ray study of a selected monocrystal confirmed the presence of the well-known framework of edge-sharing MoO{sub 6} octahedra: Space group P6{sub 3}/m, a = 10.527(1), c =3.7245(7) {angstrom}, {gamma} = 120{sup o}. The structure of the synthesized samples can best be described by the structural formula (NH{sub 4})[Mo{sub x}{open_square}{sub 1/2+p/2}(O{sub 3x + 1/2-p/2})(OH){sub p}] {center_dot} yH{sub 2}O (x 5.9-7.1; p {approx} 0.1; y = 1.2-2.6), which is consistent with the existence of one vacancy for 12-15 molybdenum sites. The 'chimie douce' reaction of MoO{sub 3} {center_dot} 0.155NH{sub 3} {center_dot} 0.440H{sub 2}O with a 1:1 mixture of NO/NO{sub 2} at 100 C resulted in the synthesis of MoO{sub 3} {center_dot} 0.539H{sub 2}O. Tailored nano-sized molybdenum powders can be produced using HEMO as precursor.

  4. Role of electronic correlation in high-low temperature phase transition of hexagonal nickel sulfide: a comparative density functional theory study with and without correction for on-site Coulomb interaction.

    PubMed

    Zhang, Wei-Bing; Li, Jie; Tang, Bi-Yu

    2013-06-28

    The structural, electronic, magnetic, and elastic properties of hexagonal nickel sulfide (NiS) have been investigated comparatively by Density Functional theory (DFT) and DFT plus correction for on-site Coulomb interaction (DFT+U), in which two different exchange correlation functionals local density approximations (LDA) and general gradient approximations (GGA) in the form of Perdew-Burke-Ernzerhof (PBE) are used. Our results indicate LDA and PBE methods predict hexagonal NiS to be a paramagnetic metal whereas LDA(PBE)+U calculations with reasonable on-site Coulomb interaction energy give the antiferromagnetic insulating state of low temperature hexagonal NiS successfully. Meanwhile, compared with LDA(PBE) results, LDA(PBE)+U methods give larger lattice parameters, crystal volume, and shear constant c44, consistent with the experimental picture during high-low temperature phase transition of hexagonal NiS, in which an increase of the shear constant c44 and lattice parameters were found in the low-temperature antiferromagnetic phase. The present DFT and DFT+U calculations provide a reasonable description for the properties of high temperature and low temperature hexagonal NiS respectively, which indicates that electronic correlation is responsible for this high-low temperature phase transition.

  5. Buckling and postbuckling behaviour of imperfect laminated shallow spherical shells under external pressure

    NASA Astrophysics Data System (ADS)

    Muc, A.

    The paper deals with the static buckling and postbuckling behavior of clamped elastic imperfect laminated shallow spherical shells subjected to uniform external pressure. Three types of initial geometrical imperfections are analyzed: two local described by a convex or a concave curve, and one global in the form of the Legendre polynomial. Applying the Rayleigh-Ritz procedure to Marguerre's equations combined with the precise prebuckling numerical analysis, reasonably accurate solutions are obtained for upper and lower buckling pressures. The effects of fiber orientations on pre- and postbuckling behavior, imperfection sensitivity, buckling loads, and modes are considered. The results for composite shells are compared with those calculated for quasi-isotropic ones.

  6. Analysis and testing of axial compression in imperfect slender truss struts

    NASA Technical Reports Server (NTRS)

    Lake, Mark S.; Georgiadis, Nicholas

    1990-01-01

    The axial compression of imperfect slender struts for large space structures is addressed. The load-shortening behavior of struts with initially imperfect shapes and eccentric compressive end loading is analyzed using linear beam-column theory and results are compared with geometrically nonlinear solutions to determine the applicability of linear analysis. A set of developmental aluminum clad graphite/epoxy struts sized for application to the Space Station Freedom truss are measured to determine their initial imperfection magnitude, load eccentricity, and cross sectional area and moment of inertia. Load-shortening curves are determined from axial compression tests of these specimens and are correlated with theoretical curves generated using linear analysis.

  7. Hexagonal OsB2 reduction upon heating in H2 containing environment

    SciTech Connect

    Xie, Zhilin; Blair, Richard G.; Orlovskaya, Nina; Payzant, E. Andrew

    2014-10-23

    The stability of hexagonal ReB2 type OsB2 powder upon heating under reforming gas was investigated. Pure Os metal particles were detected by powder X-ray diffraction starting at 375⁰ C and complete transformation of OsB2 to metallic Os was observed at 725⁰ C. The mechanisms of precipitation of metallic Os is proposed and changes in the lattice parameters of OsB2 upon heating are analysed in terms of the presence of oxygen or water vapour in the heating chamber. Previous studies suggested that Os atoms possess (0) valence, while B atoms possess both (+3) and ( 3) valences in the alternating boron/osmium sheet structure of hexagonal (P63/mmc, No. 194) OsB2; if controllable method for Os removal from the lattice could be found, the opportunity would arise to form two-dimensional (2D) layers consisting of pure B atoms.

  8. Optical selection rules for excitonic Rydberg series in the massive Dirac cones of hexagonal two-dimensional materials

    NASA Astrophysics Data System (ADS)

    Gong, Pu; Yu, Hongyi; Wang, Yong; Yao, Wang

    2017-03-01

    We investigate the optical transition selection rules for excitonic Rydberg series formed in massive Dirac cones. The entanglement of the exciton envelop function with the pseudospin texture leads to anomalous selection rules for one-photon generation of excitons, where d orbitals can be excited with the opposite helicity selection rule from the s orbitals in a given valley. The trigonal warping effects in realistic hexagonal lattices further renders more excited states bright, where p orbitals can also be accessed by one-photon excitation with the opposite valley selection rules to the s orbitals. The one-photon generation of exciton in the various states and the intraexcitonic transition between these states are both dictated by the discrete in-plane rotational symmetry of the lattices, and our results show that in hexagonal 2D materials the symmetry allowed transitions are enabled when trigonal warping effects are included in the massive Dirac fermion model. In monolayer transition metal dichalcogenides where excitons can be generated by visible light and intraexcitonic transitions can be induced by infrared light, we give the strength of these optical transitions, estimated using modified hydrogenlike envelope functions combined with the optical transition matrix elements between the Bloch states calculated at various k points.

  9. Superalloy Lattice Block Structures

    NASA Technical Reports Server (NTRS)

    Nathal, M. V.; Whittenberger, J. D.; Hebsur, M. G.; Kantzos, P. T.; Krause, D. L.

    2004-01-01

    Initial investigations of investment cast superalloy lattice block suggest that this technology will yield a low cost approach to utilize the high temperature strength and environmental resistance of superalloys in lightweight, damage tolerant structural configurations. Work to date has demonstrated that relatively large superalloy lattice block panels can be successfully investment cast from both IN-718 and Mar-M247. These castings exhibited mechanical properties consistent with the strength of the same superalloys measured from more conventional castings. The lattice block structure also accommodates significant deformation without failure, and is defect tolerant in fatigue. The potential of lattice block structures opens new opportunities for the use of superalloys in future generations of aircraft applications that demand strength and environmental resistance at elevated temperatures along with low weight.

  10. Root lattices and quasicrystals

    NASA Astrophysics Data System (ADS)

    Baake, M.; Joseph, D.; Kramer, P.; Schlottmann, M.

    1990-10-01

    It is shown that root lattices and their reciprocals might serve as the right pool for the construction of quasicrystalline structure models. All noncrystallographic symmetries observed so far are covered in minimal embedding with maximal symmetry.

  11. Root lattices and quasicrystals

    NASA Astrophysics Data System (ADS)

    Baake, M.; Joseph, D.; Kramer, P.; Schlottmann, M.

    1990-10-01

    It is shown how root lattices and their reciprocals might serve as the right pool for the construction of quasicrystalline structure models. All non-periodic symmetries observed so far are covered in minimal embedding with maximal symmetry.

  12. SPIN ON THE LATTICE.

    SciTech Connect

    ORGINOS,K.

    2003-01-07

    I review the current status of hadronic structure computations on the lattice. I describe the basic lattice techniques and difficulties and present some of the latest lattice results; in particular recent results of the RBC group using domain wall fermions are also discussed. In conclusion, lattice computations can play an important role in understanding the hadronic structure and the fundamental properties of Quantum Chromodynamics (QCD). Although some difficulties still exist, several significant steps have been made. Advances in computer technology are expected to play a significant role in pushing these computations closer to the chiral limit and in including dynamical fermions. RBC has already begun preliminary dynamical domain wall fermion computations [49] which we expect to be pushed forward with the arrival of QCD0C. In the near future, we also expect to complete the non-perturbative renormalization of the relevant derivative operators in quenched QCD.

  13. Shaken lattice interferometry

    NASA Astrophysics Data System (ADS)

    Weidner, Carrie; Yu, Hoon; Anderson, Dana

    2016-05-01

    In this work, we report on progress towards performing interferometry using atoms trapped in an optical lattice. That is, we start with atoms in the ground state of an optical lattice potential V(x) =V0cos [ 2 kx + ϕ(t) ] , and by a prescribed phase function ϕ(t) , transform from one atomic wavefunction to another. In this way, we implement the standard interferometric sequence of beam splitting, propagation, reflection, reverse propagation, and recombination. Through the use of optimal control techniques, we have computationally demonstrated a scalable accelerometer that provides information on the sign of the applied acceleration. Extension of this idea to a two-dimensional shaken-lattice-based gyroscope is discussed. In addition, we report on the experimental implementation of the shaken lattice system.

  14. Automated Lattice Perturbation Theory

    SciTech Connect

    Monahan, Christopher

    2014-11-01

    I review recent developments in automated lattice perturbation theory. Starting with an overview of lattice perturbation theory, I focus on the three automation packages currently "on the market": HiPPy/HPsrc, Pastor and PhySyCAl. I highlight some recent applications of these methods, particularly in B physics. In the final section I briefly discuss the related, but distinct, approach of numerical stochastic perturbation theory.

  15. Additive lattice kirigami.

    PubMed

    Castle, Toen; Sussman, Daniel M; Tanis, Michael; Kamien, Randall D

    2016-09-01

    Kirigami uses bending, folding, cutting, and pasting to create complex three-dimensional (3D) structures from a flat sheet. In the case of lattice kirigami, this cutting and rejoining introduces defects into an underlying 2D lattice in the form of points of nonzero Gaussian curvature. A set of simple rules was previously used to generate a wide variety of stepped structures; we now pare back these rules to their minimum. This allows us to describe a set of techniques that unify a wide variety of cut-and-paste actions under the rubric of lattice kirigami, including adding new material and rejoining material across arbitrary cuts in the sheet. We also explore the use of more complex lattices and the different structures that consequently arise. Regardless of the choice of lattice, creating complex structures may require multiple overlapping kirigami cuts, where subsequent cuts are not performed on a locally flat lattice. Our additive kirigami method describes such cuts, providing a simple methodology and a set of techniques to build a huge variety of complex 3D shapes.

  16. Additive lattice kirigami

    PubMed Central

    Castle, Toen; Sussman, Daniel M.; Tanis, Michael; Kamien, Randall D.

    2016-01-01

    Kirigami uses bending, folding, cutting, and pasting to create complex three-dimensional (3D) structures from a flat sheet. In the case of lattice kirigami, this cutting and rejoining introduces defects into an underlying 2D lattice in the form of points of nonzero Gaussian curvature. A set of simple rules was previously used to generate a wide variety of stepped structures; we now pare back these rules to their minimum. This allows us to describe a set of techniques that unify a wide variety of cut-and-paste actions under the rubric of lattice kirigami, including adding new material and rejoining material across arbitrary cuts in the sheet. We also explore the use of more complex lattices and the different structures that consequently arise. Regardless of the choice of lattice, creating complex structures may require multiple overlapping kirigami cuts, where subsequent cuts are not performed on a locally flat lattice. Our additive kirigami method describes such cuts, providing a simple methodology and a set of techniques to build a huge variety of complex 3D shapes. PMID:27679822

  17. Spontaneous Symmetry-Breaking Vortex Lattice Transitions in Pure Niobium

    SciTech Connect

    Laver, M.; Forgan, E.M.; Brown, S.P.; Bowell, C.; Ramos, S.; Lycett, R.J.; Charalambous, D.; Fort, D.; Christen, D.K.; Kohlbrecher, J.; Dewhurst, C.D.; Cubitt, R.

    2006-04-28

    We report an extensive investigation of magnetic vortex lattice (VL) structures in single crystals of pure niobium with the magnetic field applied parallel to a fourfold symmetry axis, so as to induce frustration between the cubic crystal symmetry and hexagonal VL coordination expected in an isotropic situation. We observe new VL structures and phase transitions; all the VL phases observed (including those with an exactly square unit cell) spontaneously break some crystal symmetry. One phase even has the lowest possible symmetry of a two-dimensional Bravais lattice. This is quite unlike the situation in high-T{sub c} or borocarbide superconductors, where VL structures orient along particular directions of high crystal symmetry. The causes of this behavior are discussed.

  18. Enhancement of hydrogen storage capacity in hydrate lattices

    NASA Astrophysics Data System (ADS)

    Willow, Soohaeng Yoo; Xantheas, Sotiris S.

    2012-02-01

    First principles electronic structure calculations of the pentagonal dodecahedron (H2O)20 (D-cage) and tetrakaidecahedron (H2O)24 (T-cage), building blocks of structure I (sI) hydrate lattice, suggest that these can accommodate up to a maximum of 5 and 7 guest hydrogen molecules, respectively. For the pure hydrogen hydrate, Born-Oppenheimer molecular dynamics (BOMD) simulations of periodic (sI) hydrate lattices indicate that the guest molecules are released into the vapor phase via the hexagonal faces of the larger T-cages. The presence of methane in the larger T-cages was found to block this release, therefore suggesting possible scenarios for the stabilization of these coated clathrate hydrates and the potential enhancement of their hydrogen storage capacity.

  19. Monitoring programs need to take into account imperfect species detectability

    USGS Publications Warehouse

    Kery, M.; Schmid, Hans

    2004-01-01

    Biodiversiry monitoring is important to identify biological units in need of conservation and to check the effectiveness of conservation actions. Programs generally monitor species richness and its changes (trend). Usually, no correction is made for imperfect species detectability. Instead, it is assumed that each species present has the same probability of being recorded and that there is no difference in this detectability across space and time, e.g. among observers and habitats. Consequently, species richness is determined by enumeration as the sum of species recorded. In Switzerland, the federal government has recently launched a comprehensive program that aims at detecting changes in biodiversity at all levels of biological integration. Birds are an important part of that program. Since 1999, 23 visits per breeding season are made to each of >250 1 km2 squares to map the territories of all detected breeding bird species. Here, we analyse data from three squares to illustrate the use of capture-recapture models in monitoring to obtain detectability-corrected estimates of species richness and trend. Species detectability averaged only 85%. Hence an estimated 15% of species present remained overlooked even after three visits. Within a square, changes in detectability for different years were of the same magnitude when surveys were conducted by the same observer as when they were by different observers. Estimates of trend were usually biased and community turnover was overestimated when based on enumeration. Here we use bird data as an illustration of methods. However, species detectability for any taxon is unlikely ever to be perfect or even constant across categories to be compared. Therefore, monitoring programs should correct for species detectability.

  20. Quantum state tomography with noninstantaneous measurements, imperfections, and decoherence

    NASA Astrophysics Data System (ADS)

    Six, P.; Campagne-Ibarcq, Ph.; Dotsenko, I.; Sarlette, A.; Huard, B.; Rouchon, P.

    2016-01-01

    Tomography of a quantum state is usually based on a positive-operator-valued measure (POVM) and on their experimental statistics. Among the available reconstructions, the maximum-likelihood (MaxLike) technique is an efficient one. We propose an extension of this technique when the measurement process cannot be simply described by an instantaneous POVM. Instead, the tomography relies on a set of quantum trajectories and their measurement records. This model includes the fact that, in practice, each measurement could be corrupted by imperfections and decoherence, and could also be associated with the record of continuous-time signals over a finite amount of time. The goal is then to retrieve the quantum state that was present at the start of this measurement process. The proposed extension relies on an explicit expression of the likelihood function via the effective matrices appearing in quantum smoothing and solutions of the adjoint quantum filter. It allows us to retrieve the initial quantum state as in standard MaxLike tomography, but where the traditional POVM operators are replaced by more general ones that depend on the measurement record of each trajectory. It also provides, aside from the MaxLike estimate of the quantum state, confidence intervals for any observable. Such confidence intervals are derived, as the MaxLike estimate, from an asymptotic expansion of multidimensional Laplace integrals appearing in Bayesian mean estimation. A validation is performed on two sets of experimental data: photon(s) trapped in a microwave cavity subject to quantum nondemolition measurements relying on Rydberg atoms, and heterodyne fluorescence measurements of a superconducting qubit.

  1. Cytoskeletal Signaling: Is Memory Encoded in Microtubule Lattices by CaMKII Phosphorylation?

    PubMed Central

    Craddock, Travis J. A.; Tuszynski, Jack A.; Hameroff, Stuart

    2012-01-01

    Memory is attributed to strengthened synaptic connections among particular brain neurons, yet synaptic membrane components are transient, whereas memories can endure. This suggests synaptic information is encoded and ‘hard-wired’ elsewhere, e.g. at molecular levels within the post-synaptic neuron. In long-term potentiation (LTP), a cellular and molecular model for memory, post-synaptic calcium ion (Ca2+) flux activates the hexagonal Ca2+-calmodulin dependent kinase II (CaMKII), a dodacameric holoenzyme containing 2 hexagonal sets of 6 kinase domains. Each kinase domain can either phosphorylate substrate proteins, or not (i.e. encoding one bit). Thus each set of extended CaMKII kinases can potentially encode synaptic Ca2+ information via phosphorylation as ordered arrays of binary ‘bits’. Candidate sites for CaMKII phosphorylation-encoded molecular memory include microtubules (MTs), cylindrical organelles whose surfaces represent a regular lattice with a pattern of hexagonal polymers of the protein tubulin. Using molecular mechanics modeling and electrostatic profiling, we find that spatial dimensions and geometry of the extended CaMKII kinase domains precisely match those of MT hexagonal lattices. This suggests sets of six CaMKII kinase domains phosphorylate hexagonal MT lattice neighborhoods collectively, e.g. conveying synaptic information as ordered arrays of six “bits”, and thus “bytes”, with 64 to 5,281 possible bit states per CaMKII-MT byte. Signaling and encoding in MTs and other cytoskeletal structures offer rapid, robust solid-state information processing which may reflect a general code for MT-based memory and information processing within neurons and other eukaryotic cells. PMID:22412364

  2. Buckling and Failure of Compression-Loaded Composite Cylindrical Shells With Geometric and Material Imperfections

    NASA Technical Reports Server (NTRS)

    Hilburger, Mark W.; Starnes, James H., Jr.

    2004-01-01

    The results of an experimental and numerical study of the effects of initial imperfections on the buckling response and failure of unstiffened thin-walled compression-loaded graphite-epoxy cylindrical shells are presented. The shells considered in the study have six different orthotropic or quasi-isotropic shell-wall laminates and two different shell-radius-to-thickness ratios. The numerical results include the effects of geometric shell-wall mid-surface imperfections, shell-wall thickness variations, local shell-wall ply-gaps associated with the fabrication process, shell-end geometric imperfections, nonuniform end loads, and the effects of elastic boundary conditions. Selected cylinder parameter uncertainties were also considered. Results that illustrate the effects of imperfections and uncertainties on the nonlinear response characteristics, buckling loads and failure the shells are presented. In addition, a common failure analysis is used to predict material failures in the shells.

  3. Understanding Your Vision: The “Imperfect Eye” | NIH MedlinePlus the Magazine

    MedlinePlus

    ... of this page please turn Javascript on. Feature: Vision Understanding Your Vision: The “Imperfect Eye” Past Issues / Winter 2012 Table ... are different and so are the types of vision that we have. Understanding how some of us ...

  4. Unveiling the physics of the doped phase of the t - J model on the kagome lattice.

    PubMed

    Guertler, Siegfried; Monien, Hartmut

    2013-08-30

    We investigate the ground state properties of the kagome lattice t - J model at low doping by variational Monte Carlo calculations. The resulting state possesses an interesting balance of spin exchange and kinetic exchange through the building blocks of stars which are linked by triangles and their internal hexagons. While the spin exchange is taking place mainly on the stars, hopping is favored on the hexagons. There is a density modulation, resulting in the holes having an effective static contribution. From this observation, how holes lead to dimerization in this model and why a particular valence bond crystal pattern is formed can be understood. Furthermore, we argue the optimal doping for this state. We discuss our result in connection with static impurities, and show the likely relevance to the diluted kagome lattice Heisenberg model, describing actual compounds.

  5. The Influence of Hollow Imperfections of Adhesive on Performances of Interface of RC Beams Strengthened with HFRP

    NASA Astrophysics Data System (ADS)

    Yongchang, Guo; Lijuan, Li; Jun, Deng; Genquan, Zhong

    2010-05-01

    The mechanical characteristics of the interface with hollow imperfections for reinforced concrete (RC) beams strengthened with Carbon-Glass fiber sheet is discussed, which is a new hybrid strengthening method. By establishing the constitutive equations of different materials, three interfacial models including imperfection dimension, imperfection location and imperfection amount are simulated using nonlinear finite element method. The shear stress and normal stress of glue layer, the first principal stress of concrete at the end of the interface and the stress distributions of different strengthening modes are analyzed. The results show that the shear stress of glue layer is sensitive for imperfection dimension and significantly increases with the imperfection dimension. However, the first principal stress of the concrete at the end of the interface marginally decreases with the imperfection dimension.

  6. The Influence of Hollow Imperfections of Adhesive on Performances of Interface of RC Beams Strengthened with HFRP

    SciTech Connect

    Guo Yongchang; Li Lijuan; Deng Jun; Zhong Genquan

    2010-05-21

    The mechanical characteristics of the interface with hollow imperfections for reinforced concrete (RC) beams strengthened with Carbon-Glass fiber sheet is discussed, which is a new hybrid strengthening method. By establishing the constitutive equations of different materials, three interfacial models including imperfection dimension, imperfection location and imperfection amount are simulated using nonlinear finite element method. The shear stress and normal stress of glue layer, the first principal stress of concrete at the end of the interface and the stress distributions of different strengthening modes are analyzed. The results show that the shear stress of glue layer is sensitive for imperfection dimension and significantly increases with the imperfection dimension. However, the first principal stress of the concrete at the end of the interface marginally decreases with the imperfection dimension.

  7. Effect of joint imperfections on static control of adaptive structures as space cranes

    NASA Technical Reports Server (NTRS)

    Ramesh, A. V.; Utku, Senol; Wada, B. K.; Chen, G. S.

    1990-01-01

    Effect of imperfections in the joints of an adaptive structure on its slow (no inertia forces) motion along a prescribed trajectory as a space crane is studied. Two mathematical models to predict the effect of joint imperfections are proposed. The two models are used to obtain estimates of the deviations of the node of the space crane to which the end-effector is attached, from its prescribed trajectory. An application of the models to a two-section space crane is given.

  8. Ab initio engineering of materials with stacked hexagonal tin frameworks

    PubMed Central

    Shao, Junping; Beaufils, Clément; Kolmogorov, Aleksey N.

    2016-01-01

    The group-IV tin has been hypothesized to possess intriguing electronic properties in an atom-thick hexagonal form. An attractive pathway of producing sizable 2D crystallites of tin is based on deintercalation of bulk compounds with suitable tin frameworks. Here, we have identified a new synthesizable metal distannide, NaSn2, with a 3D stacking of flat hexagonal layers and examined a known compound, BaSn2, with buckled hexagonal layers. Our ab initio results illustrate that despite being an exception to the 8-electron rule, NaSn2 should form under pressures easily achievable in multi-anvil cells and remain (meta)stable under ambient conditions. Based on calculated Z2 invariants, the predicted NaSn2 may display topologically non-trivial behavior and the known BaSn2 could be a strong topological insulator. PMID:27387140

  9. Stabilization of 4H hexagonal phase in gold nanoribbons

    PubMed Central

    Fan, Zhanxi; Bosman, Michel; Huang, Xiao; Huang, Ding; Yu, Yi; Ong, Khuong P.; Akimov, Yuriy A.; Wu, Lin; Li, Bing; Wu, Jumiati; Huang, Ying; Liu, Qing; Eng Png, Ching; Lip Gan, Chee; Yang, Peidong; Zhang, Hua

    2015-01-01

    Gold, silver, platinum and palladium typically crystallize with the face-centred cubic structure. Here we report the high-yield solution synthesis of gold nanoribbons in the 4H hexagonal polytype, a previously unreported metastable phase of gold. These gold nanoribbons undergo a phase transition from the original 4H hexagonal to face-centred cubic structure on ligand exchange under ambient conditions. Using monochromated electron energy-loss spectroscopy, the strong infrared plasmon absorption of single 4H gold nanoribbons is observed. Furthermore, the 4H hexagonal phases of silver, palladium and platinum can be readily stabilized through direct epitaxial growth of these metals on the 4H gold nanoribbon surface. Our findings may open up new strategies for the crystal phase-controlled synthesis of advanced noble metal nanomaterials. PMID:26216712

  10. Ab initio engineering of materials with stacked hexagonal tin frameworks

    NASA Astrophysics Data System (ADS)

    Shao, Junping; Beaufils, Clément; Kolmogorov, Aleksey N.

    2016-07-01

    The group-IV tin has been hypothesized to possess intriguing electronic properties in an atom-thick hexagonal form. An attractive pathway of producing sizable 2D crystallites of tin is based on deintercalation of bulk compounds with suitable tin frameworks. Here, we have identified a new synthesizable metal distannide, NaSn2, with a 3D stacking of flat hexagonal layers and examined a known compound, BaSn2, with buckled hexagonal layers. Our ab initio results illustrate that despite being an exception to the 8-electron rule, NaSn2 should form under pressures easily achievable in multi-anvil cells and remain (meta)stable under ambient conditions. Based on calculated Z2 invariants, the predicted NaSn2 may display topologically non-trivial behavior and the known BaSn2 could be a strong topological insulator.

  11. New approach for direct chemical synthesis of hexagonal Co nanoparticles

    NASA Astrophysics Data System (ADS)

    Abel, Frank M.; Tzitzios, Vasilis; Hadjipanayis, George C.

    2016-02-01

    In this paper, we explore the possibility of producing hexagonal Cobalt nanoparticles, with high saturation magnetization by direct chemical synthesis. The nanoparticles were synthesized by reduction of anhydrous cobalt (II) chloride by NaBH4 in tetraglyme at temperatures in the range of 200-270 °C under a nitrogen-hydrogen atmosphere. The reactions were done at high temperatures to allow for the formation of as-made hexagonal cobalt. The size of the particles was controlled by the addition of different surfactants. The best magnetic properties so far were obtained on spherical hexagonal Co nanoparticles with an average size of 45 nm, a saturation magnetization of 143 emu/g and coercivity of 500 Oe. the saturation magnetization and coercivity were further improved by annealing the Co nanoparticles leading to saturation magnetization of 160 emu/g and coercivity of 540 Oe.

  12. Density functional theory study of hexagonal carbon phases.

    PubMed

    Wang, Zhibin; Gao, Faming; Li, Na; Qu, Nianrui; Gou, Huiyang; Hao, Xianfeng

    2009-06-10

    It is reported frequently that the new carbon phases may be harder than diamond (Wang et al 2004 Proc. Natl Acad. Sci. 101 13699 and Mao et al 2003 Science 302 425). However, the mechanism is still unclear. In this paper we systematically investigate the structural, electronic, and mechanical properties of the diamond polytypes using first-principles density functional calculations. The results show that the bulk modulus and shear modulus for the hexagonal form of diamond approach those of diamond, suggesting they might be hard and low compressibility materials. According to the semiempirical method for hardness based on the Mulliken overlap population, the hardnesses for hexagonal forms have been evaluated and compared to diamond. The results indicate that these phases are superhard. More importantly, the bonds in some specific directions of the hexagonal phases are harder than those in diamond, which may lead to the noticeable indentation marks on the diamond anvils observed in experiments.

  13. HEXAGONAL ARRAY STRUCTURE FOR 2D NDE APPLICATIONS

    SciTech Connect

    Dziewierz, J.; Ramadas, S. N.; Gachagan, A.; O'Leary, R. L.

    2010-02-22

    This paper describes a combination of simulation and experimentation to evaluate the advantages offered by utilizing a hexagonal shaped array element in a 2D NDE array structure. The active material is a 1-3 connectivity piezoelectric composite structure incorporating triangular shaped pillars--each hexagonal array element comprising six triangular pillars. A combination of PZFlex, COMSOL and Matlab has been used to simulate the behavior of this device microstructure, for operation around 2.25 MHz, with unimodal behavior and low levels of mechanical cross-coupling predicted. Furthermore, the application of hexagonal array elements enables the array aperture to increase by approximately 30%, compared to a conventional orthogonal array matrix and hence will provide enhanced volumetric coverage and SNR. Prototype array configurations demonstrate good corroboration of the theoretically predicted mechanical cross-coupling between adjacent array elements (approx23 dB).

  14. Spin-orbital short-range order on a honeycomb-based lattice.

    PubMed

    Nakatsuji, S; Kuga, K; Kimura, K; Satake, R; Katayama, N; Nishibori, E; Sawa, H; Ishii, R; Hagiwara, M; Bridges, F; Ito, T U; Higemoto, W; Karaki, Y; Halim, M; Nugroho, A A; Rodriguez-Rivera, J A; Green, M A; Broholm, C

    2012-05-04

    Frustrated magnetic materials, in which local conditions for energy minimization are incompatible because of the lattice structure, can remain disordered to the lowest temperatures. Such is the case for Ba(3)CuSb(2)O(9), which is magnetically anisotropic at the atomic scale but curiously isotropic on mesoscopic length and time scales. We find that the frustration of Wannier's Ising model on the triangular lattice is imprinted in a nanostructured honeycomb lattice of Cu(2+) ions that resists a coherent static Jahn-Teller distortion. The resulting two-dimensional random-bond spin-1/2 system on the honeycomb lattice has a broad spectrum of spin-dimer-like excitations and low-energy spin degrees of freedom that retain overall hexagonal symmetry.

  15. Impact of surface imperfections on the Casimir force for lenses of centimeter-size curvature radii

    SciTech Connect

    Bezerra, V. B.; Romero, C.; Klimchitskaya, G. L.; Mohideen, U.; Mostepanenko, V. M.

    2011-02-15

    The impact of imperfections, which are always present on surfaces of lenses with centimeter-size curvature radii, on the Casimir force in the lens-plate geometry is investigated. It is shown that the commonly used formulation of the proximity force approximation is inapplicable for spherical lenses with surface imperfections, such as bubbles and pits. More general expressions for the Casimir force are derived that take surface imperfections into account. Using these expressions, we show that surface imperfections can both increase and decrease the magnitude of the Casimir force up to a few tens percent when compared with the case of a perfectly spherical lens. We demonstrate that the Casimir force between a perfectly spherical lens and a plate described by the Drude model can be made approximately equal to the force between a sphere with some surface imperfection and a plate described by the plasma model, and vice versa. In the case of a metallic sphere and a semiconductor plate, approximately the same Casimir forces are obtained for four different descriptions of charge carriers in the semiconductor if appropriate surface imperfections on the lens surface are present. The conclusion is made that there is a fundamental problem in the interpretation of measurement data for the Casimir force using spherical lenses of centimeter-size radii.

  16. Explicit solutions for the buckling of an imperfect strut on a nonlinear foundation

    NASA Astrophysics Data System (ADS)

    Lagrange, Romain; Averbuch, Daniel; Ifpen Team

    2013-03-01

    We perform a theoretical and numerical study of the buckling of an imperfect finite strut on a nonlinear elastic Winkler type foundation. The imperfection is introduced by considering an initially deformed shape which is a sine function with an half wavelength. The length of the strut is chosen such that the first buckling mode is excited and the restoring force is either a bi-linear or an exponential profile. Considering these two profiles, we show (exact piecewise solution theory, explicit Galerkin method, numerical resolution) that the system is subcritical, imperfection sensitive and the deflection is an amplification of the default. For small imperfection sizes, the equilibrium paths hit a limit point which is asymptotic to the Euler load for a critical imperfection amplitude. This critical amplitude is determined analytically and does not depend on the choice of the restoring force. The decrease of the maximum value of the axial force supported by the beam as a function of the imperfection magnitude is determined. We show that the leading term of the development has a different exponent than in subcritical buckling of elastic systems, and that the exponent values depend on the regularization.

  17. Ecological and evolutionary processes drive the origin and maintenance of imperfect mimicry.

    PubMed

    Wilson, Joseph S; Jahner, Joshua P; Williams, Kevin A; Forister, Matthew L

    2013-01-01

    Although the forces behind the evolution of imperfect mimicry remain poorly studied, recent hypotheses suggest that relaxed selection on small-bodied individuals leads to imperfect mimicry. While evolutionary history undoubtedly affects the development of imperfect mimicry, ecological community context has largely been ignored and may be an important driver of imperfect mimicry. Here we investigate how evolutionary and ecological contexts might influence mimetic fidelity in Müllerian and Batesian mimicry systems. In Batesian hoverfly systems we find that body size is not a strong predictor of mimetic fidelity. However, in Müllerian velvet ants we find a weak positive relationship between body size and mimetic fidelity when evolutionary context is controlled for and a much stronger relationship between community diversity and mimetic fidelity. These results suggest that reduced selection on small-bodied individuals may not be a major driver of the evolution of imperfect mimicry and that other factors, such as ecological community context, should be considered when studying the evolution of imperfect mimicry.

  18. Metasurfaces inner symmetries: from square lattices to quasicrystalline layouts (presentation video)

    NASA Astrophysics Data System (ADS)

    Kruk, Sergey S.; Poddubny, Alexander; Helgert, Christian; Decker, Manuel; Staude, Isabelle; Menzel, Christoph; Etrich, Christoph; Rockstuhl, Carsten; Powell, David A.; Pertsch, Thomas; Neshev, Dragomir N.; Kivshar, Yuri S.

    2014-09-01

    We systematically study both experimentally and theoretically the links between the lattice symmetries of metasurfaces and their optical properties at both normal and oblique illumination. We attribute different symmetry elements to number of polarization phenomena. In particular, we predict analytically and verify experimentally the influence of rotational axes, mirror planes and inversion centres on optical activity, circular dichroism and asymmetric transmission. We fabricate and test nanostructured optical metasurfaces with four different inner structures: square and hexagonal lattices, quasicrystalline layout, and amorphous arrangement. We demonstrate the ability to enhance/suppress particular optical response by appropriate choice of the metasurface's symmetry.

  19. Direct observation of Σ7 domain boundary core structure in magnetic skyrmion lattice

    PubMed Central

    Matsumoto, Takao; So, Yeong-Gi; Kohno, Yuji; Sawada, Hidetaka; Ikuhara, Yuichi; Shibata, Naoya

    2016-01-01

    Skyrmions are topologically protected nanoscale magnetic spin entities in helical magnets. They behave like particles and tend to form hexagonal close-packed lattices, like atoms, as their stable structure. Domain boundaries in skyrmion lattices are considered to be important as they affect the dynamic properties of magnetic skyrmions. However, little is known about the fine structure of such skyrmion domain boundaries. We use differential phase contrast scanning transmission electron microscopy to directly visualize skyrmion domain boundaries in FeGe1−xSix induced by the influence of an “edge” of a crystal grain. Similar to hexagonal close-packed atomic lattices, we find the formation of skyrmion “Σ7” domain boundary, whose orientation relationship is predicted by the coincidence site lattice theory to be geometrically stable. On the contrary, the skyrmion domain boundary core structure shows a very different structure relaxation mode. Individual skyrmions can flexibly change their size and shape to accommodate local coordination changes and free volumes formed at the domain boundary cores. Although atomic rearrangement is a common structural relaxation mode in crystalline grain boundaries, skyrmions show very unique and thus different responses to such local lattice disorders. PMID:26933690

  20. Phononic band gap design in honeycomb lattice with combinations of auxetic and conventional core

    NASA Astrophysics Data System (ADS)

    Mukherjee, Sushovan; Scarpa, Fabrizio; Gopalakrishnan, S.

    2016-05-01

    We present a novel design of a honeycomb lattice geometry that uses a seamless combination of conventional and auxetic cores, i.e. elements showing positive and negative Poisson’s ratio. The design is aimed at tuning and improving the band structure of periodic cellular structures. The proposed cellular configurations show a significantly wide band gap at much lower frequencies compared to their pure counterparts, while still retaining their major dynamic features. Different topologies involving both auxetic inclusions in a conventional lattice and conversely hexagonal cellular inclusions in auxetic butterfly lattices are presented. For all these cases the impact of the varying degree of auxeticity on the band structure is evaluated. The proposed cellular designs may offer significant advantages in tuning high-frequency bandgap behaviour, which is relevant to phononics applications. The configurations shown in this paper may be made iso-volumetric and iso-weight to a given regular hexagonal topology, making possible to adapt the hybrid lattices to existing sandwich structures with fixed dimensions and weights. This work also features a comparative study of the wave speeds corresponding to different configurations vis-a vis those of a regular honeycomb to highlight the superior behaviour of the combined hybrid lattice.

  1. Measuring on Lattices

    NASA Astrophysics Data System (ADS)

    Knuth, Kevin H.

    2009-12-01

    Previous derivations of the sum and product rules of probability theory relied on the algebraic properties of Boolean logic. Here they are derived within a more general framework based on lattice theory. The result is a new foundation of probability theory that encompasses and generalizes both the Cox and Kolmogorov formulations. In this picture probability is a bi-valuation defined on a lattice of statements that quantifies the degree to which one statement implies another. The sum rule is a constraint equation that ensures that valuations are assigned so as to not violate associativity of the lattice join and meet. The product rule is much more interesting in that there are actually two product rules: one is a constraint equation arises from associativity of the direct products of lattices, and the other a constraint equation derived from associativity of changes of context. The generality of this formalism enables one to derive the traditionally assumed condition of additivity in measure theory, as well introduce a general notion of product. To illustrate the generic utility of this novel lattice-theoretic foundation of measure, the sum and product rules are applied to number theory. Further application of these concepts to understand the foundation of quantum mechanics is described in a joint paper in this proceedings.

  2. Hexagonal Pixels and Indexing Scheme for Binary Images

    NASA Technical Reports Server (NTRS)

    Johnson, Gordon G.

    2004-01-01

    A scheme for resampling binaryimage data from a rectangular grid to a regular hexagonal grid and an associated tree-structured pixel-indexing scheme keyed to the level of resolution have been devised. This scheme could be utilized in conjunction with appropriate image-data-processing algorithms to enable automated retrieval and/or recognition of images. For some purposes, this scheme is superior to a prior scheme that relies on rectangular pixels: one example of such a purpose is recognition of fingerprints, which can be approximated more closely by use of line segments along hexagonal axes than by line segments along rectangular axes. This scheme could also be combined with algorithms for query-image-based retrieval of images via the Internet. A binary image on a rectangular grid is generated by raster scanning or by sampling on a stationary grid of rectangular pixels. In either case, each pixel (each cell in the rectangular grid) is denoted as either bright or dark, depending on whether the light level in the pixel is above or below a prescribed threshold. The binary data on such an image are stored in a matrix form that lends itself readily to searches of line segments aligned with either or both of the perpendicular coordinate axes. The first step in resampling onto a regular hexagonal grid is to make the resolution of the hexagonal grid fine enough to capture all the binaryimage detail from the rectangular grid. In practice, this amounts to choosing a hexagonal-cell width equal to or less than a third of the rectangular- cell width. Once the data have been resampled onto the hexagonal grid, the image can readily be checked for line segments aligned with the hexagonal coordinate axes, which typically lie at angles of 30deg, 90deg, and 150deg with respect to say, the horizontal rectangular coordinate axis. Optionally, one can then rotate the rectangular image by 90deg, then again sample onto the hexagonal grid and check for line segments at angles of 0deg, 60deg

  3. Communication: Water on hexagonal boron nitride from diffusion Monte Carlo

    SciTech Connect

    Al-Hamdani, Yasmine S.; Ma, Ming; Michaelides, Angelos; Alfè, Dario; Lilienfeld, O. Anatole von

    2015-05-14

    Despite a recent flurry of experimental and simulation studies, an accurate estimate of the interaction strength of water molecules with hexagonal boron nitride is lacking. Here, we report quantum Monte Carlo results for the adsorption of a water monomer on a periodic hexagonal boron nitride sheet, which yield a water monomer interaction energy of −84 ± 5 meV. We use the results to evaluate the performance of several widely used density functional theory (DFT) exchange correlation functionals and find that they all deviate substantially. Differences in interaction energies between different adsorption sites are however better reproduced by DFT.

  4. Backscattering by hexagonal ice crystals of cirrus clouds.

    PubMed

    Borovoi, Anatoli; Konoshonkin, Alexander; Kustova, Natalia

    2013-08-01

    Light backscattering by randomly oriented hexagonal ice crystals of cirrus clouds is considered within the framework of the physical-optics approximation. The fine angular structure of all elements of the Mueller matrix in the vicinity of the exact backward direction is first calculated and discussed. In particular, an approximate equation for the differential scattering cross section is obtained. Its simple spectral dependence is discussed. Also, a hollow of the linear depolarization ratio around the exact backward direction inherent to the long hexagonal columns is revealed.

  5. Frustrated honeycomb-lattice bilayer quantum antiferromagnet in a magnetic field: Unconventional phase transitions in a two-dimensional isotropic Heisenberg model

    NASA Astrophysics Data System (ADS)

    Krokhmalskii, Taras; Baliha, Vasyl; Derzhko, Oleg; Schulenburg, Jörg; Richter, Johannes

    2017-03-01

    We consider the spin-1/2 antiferromagnetic Heisenberg model on a bilayer honeycomb lattice including interlayer frustration in the presence of an external magnetic field. In the vicinity of the saturation field, we map the low-energy states of this quantum system onto the spatial configurations of hard hexagons on a honeycomb lattice. As a result, we can construct effective classical models (lattice-gas as well as Ising models) on the honeycomb lattice to calculate the properties of the frustrated quantum Heisenberg spin system in the low-temperature regime. We perform classical Monte Carlo simulations for a hard-hexagon model and adopt known results for an Ising model to discuss the finite-temperature order-disorder phase transition that is driven by a magnetic field at low temperatures. We also discuss an effective-model description around the ideal frustration case and find indications for a spin-flop-like transition in the considered isotropic spin model.

  6. Security issues of quantum cryptographic systems with imperfect detectors

    NASA Astrophysics Data System (ADS)

    Burenkov, Viacheslav

    The laws of quantum physics can be used to secure communications between two distant parties in a scheme called quantum key distribution (QKD), even against a technologically unlimited eavesdropper. While the theoretical security of QKD has been proved rigorously, current implementations of QKD are generally insecure. In particular, mathematical models of devices, such as detectors, do not accurately describe their real-life behaviour. Such seemingly insignificant discrepancies can compromise the security of the entire scheme, especially as novel detector technologies are being developed with little regard for potential vulnerabilities. In this thesis, we study how detector imperfections can impact the security of QKD and how to overcome such technological limitations. We first analyze the security of a high-speed QKD system with finite detector dead time tau. We show that the previously reported sifting approaches are not guaranteed to be secure in this regime. More specifically, Eve can induce a basis-dependent detection efficiency at the receiver's end. Modified key sifting schemes that are basis-independent, and thus secure in the presence of dead time and an active eavesdropper, are discussed and compared. It is shown that the maximum key generation rate is 1/(2tau) for passive basis selection, and 1/tau for active basis selection. The security analysis is also extended to the decoy state BB84 protocol. We then study a relatively new type of single-photon detector called the superconducting nanowire single-photon detector (SNSPD), and discover some unexpected behaviour. We report an afterpulsing effect present when the SNSPD is operated in the high bias current regime. In our standard set-up, the afterpulsing is most likely to occur at around 180 ns following a detection event, for both real counts and dark counts. We characterize the afterpulsing behaviour and speculate that it is not due to the SNSPD itself but rather the associated read-out circuit. We also

  7. Crossing on hyperbolic lattices

    NASA Astrophysics Data System (ADS)

    Gu, Hang; Ziff, Robert M.

    2012-05-01

    We divide the circular boundary of a hyperbolic lattice into four equal intervals and study the probability of a percolation crossing between an opposite pair as a function of the bond occupation probability p. We consider the {7,3} (heptagonal), enhanced or extended binary tree (EBT), the EBT-dual, and the {5,5} (pentagonal) lattices. We find that the crossing probability increases gradually from 0 to 1 as p increases from the lower pl to the upper pu critical values. We find bounds and estimates for the values of pl and pu for these lattices and identify the self-duality point p* corresponding to where the crossing probability equals 1/2. Comparison is made with recent numerical and theoretical results.

  8. Lattice gauge theories

    NASA Astrophysics Data System (ADS)

    Weisz, Peter; Majumdar, Pushan

    2012-03-01

    Lattice gauge theory is a formulation of quantum field theory with gauge symmetries on a space-time lattice. This formulation is particularly suitable for describing hadronic phenomena. In this article we review the present status of lattice QCD. We outline some of the computational methods, discuss some phenomenological applications and a variety of non-perturbative topics. The list of references is severely incomplete, the ones we have included are text books or reviews and a few subjectively selected papers. Kronfeld and Quigg (2010) supply a reasonably comprehensive set of QCD references. We apologize for the fact that have not covered many important topics such as QCD at finite density and heavy quark effective theory adequately, and mention some of them only in the last section "In Brief". These topics should be considered in further Scholarpedia articles.

  9. Lattice studies of baryons

    SciTech Connect

    David Richards

    2004-10-01

    This talk describes progress at understanding the properties of the nucleon and its excitations from lattice QCD. I begin with a review of recent lattice results for the lowest-lying states of the excited baryon spectrum. The need to approach physical values of the light quark masses is emphasized, enabling the effects of the pion cloud to be revealed. I then outline the development of techniques that will enable the extraction of the masses of the higher resonances, and describe how such calculations provide insight into the structure of the hadrons. Finally, I discuss direct probes of the quark and gluon structure of baryons through the lattice measurement of the moments of quark distributions and of Generalized Parton Distributions.

  10. Structural and electrical studies of sol-gel synthesized nanocrystalline hexagonal yttrium iron manganite ceramics

    NASA Astrophysics Data System (ADS)

    Touthang, Jangkhohao; Maisnam, Mamata

    2017-03-01

    Hexagonal yttrium manganites, YMnO3, are interesting materials for their multiferroic behavior. Substituting suitable cations either at the Y-site or Mn-site offers great opportunities to produce a variety of manganites and tune their properties. Nanocrystalline yttrium iron manganites with the compositional formula Y1‑xFexMnO3, x = 0.0, 0.10, 0.15, 0.20 and 0.25, were synthesized by sol-gel autocombustion method. The prepared samples were heated at 1100∘C for 1 h. Another set of samples with compositional formula YFexMn1‑xO3, x = 0.0, 0.10, 0.15, 0.20 and 0.25, were also synthesized by the same method and heated at 1100∘C for 1 h. Various characterizations were done on these manganite systems synthesized by substituting iron at different sites. X-ray diffraction (XRD) technique studied the structure of the samples and analysis of XRD patterns confirmed the formation of hexagonal phase in the samples. Structural parameters such as lattice constants, crystallite size, theoretical density, etc. were determined using the XRD data. The unit cell dimensions have been found to agree with the standard data and the Debye-Scherrer crystallite size obtained from XRD data ranges from 42 nm to 77 nm. The room temperature frequency variations of electrical properties such as dielectric constant, dielectric loss and AC conductivity were measured in the range of 100 Hz-2 MHz and the variations showed a dispersive behavior for all the samples. The various measurements and the results obtained were studied and discussed in the paper.

  11. Exact Lattice Supersymmetry

    SciTech Connect

    Catterall, Simon; Kaplan, David B.; Unsal, Mithat

    2009-03-31

    We provide an introduction to recent lattice formulations of supersymmetric theories which are invariant under one or more real supersymmetries at nonzero lattice spacing. These include the especially interesting case of N = 4 SYM in four dimensions. We discuss approaches based both on twisted supersymmetry and orbifold-deconstruction techniques and show their equivalence in the case of gauge theories. The presence of an exact supersymmetry reduces and in some cases eliminates the need for fine tuning to achieve a continuum limit invariant under the full supersymmetry of the target theory. We discuss open problems.

  12. Optical Lattice Clocks

    NASA Astrophysics Data System (ADS)

    Oates, Chris

    2012-06-01

    Since they were first proposed in 2003 [1], optical lattice clocks have become one of the leading technologies for the next generation of atomic clocks, which will be used for advanced timing applications and in tests of fundamental physics [2]. These clocks are based on stabilized lasers whose frequency is ultimately referenced to an ultra-narrow neutral atom transition (natural linewidths << 1 Hz). To suppress the effects of atomic motion/recoil, the atoms in the sample (˜10^4 atoms) are confined tightly in the potential wells of an optical standing wave (lattice). The wavelength of the lattice light is tuned to its ``magic'' value so as to yield a vanishing net AC Stark shift for the clock transition. As a result lattice clocks have demonstrated the capability of generating high stability clock signals with small absolute uncertainties (˜ 1 part in 10^16). In this presentation I will first give an overview of the field, which now includes three different atomic species. I will then use experiments with Yb performed in our laboratory to illustrate the key features of a lattice clock. Our research has included the development of state-of-the-art optical cavities enabling ultra-high-resolution optical spectroscopy (1 Hz linewidth). Together with the large atom number in the optical lattice, we are able to achieve very low clock instability (< 0.3 Hz in 1 s) [3]. Furthermore, I will show results from some of our recent investigations of key shifts for the Yb lattice clock, including high precision measurements of ultracold atom-atom interactions in the lattice and the dc Stark effect for the Yb clock transition (necessary for the evaluation of blackbody radiation shifts). [4pt] [1] H. Katori, M. Takamoto, V. G. Pal'chikov, and V. D. Ovsiannikov, Phys. Rev. Lett. 91, 173005 (2003). [0pt] [2] Andrei Derevianko and Hidetoshi Katori, Rev. Mod. Phys. 83, 331 (2011). [0pt] [3] Y. Y. Jiang, A. D. Ludlow, N. D. Lemke, R. W. Fox, J. A. Sherman, L.-S. Ma, and C. W. Oates

  13. Nonlinear analysis of wiggler-imperfections in free-electron lasers

    SciTech Connect

    Freund, H.P.; Yu, L.H.

    1995-12-31

    We present an analysis of the effect of wiggler imperfections in FELs using a variety of techniques. Our basic intention is to compare wiggler averaged nonlinear simulations to determine the effect of various approximations on the estimates of gain degradation due to wiggler imperfections. The fundamental assumption in the wiggler-averaged formulations is that the electrons are described by a random walk model, and an analytic representation of the orbits is made. This is fundamentally different from the approach taken for the non-wiggler-averaged formulation in which the wiggler imperfections are specified at the outset, and the orbits are integrated using a field model that is consistent with the Maxwell equations. It has been conjectured on the basis of prior studies using the non-wiggler-averaged formalism that electrons follow a {open_quotes}meander line{close_quotes} through the wiggler governed by the specific imperfections; hence, the electrons behave more as a ball-in-groove than as a random walk. This conjecture is tested by comparison of the wiggler-averaged and non-wiggler-averaged simulations. In addition, two different wiggler models are employed in the non-wiggler-averaged simulation: one based upon a parabolic pole face wiggler which is not curl and divergence free in the presence of wiggler imperfections, and a second model in which the divergence and z-component of the curl vanish identically. This will gauge the effect of inconsistencies in the wiggler model on the estimation of the effect of the imperfections. Preliminary results indicate that the inconsistency introduced by the non-vanishing curl and divergence result in an overestimation of the effect of wiggler imperfections on the orbit. The wiggler-averaged simulation is based upon the TDA code, and the non-wiggler-averaged simulation is a variant of the ARACHNE and WIGGLIN codes called MEDUSA developed to treat short-wavelength Gauss-Hermite modes.

  14. Robust half-metallicity of hexagonal SrNiO{sub 3}

    SciTech Connect

    Chen, Gao-Yuan; Ma, Chun-Lan; Chen, Da; Zhu, Yan

    2016-01-15

    In the rich panorama of the electronic and magnetic properties of 3d transition metal oxides SrMO{sub 3} (M=Ti, V, Cr, Mn, Fe, Co, Ni, Cu), one member (SrNiO{sub 3}) is missing. In this paper we use GGA+U method based on density functional theory to examine its properties. It is found that SrNiO{sub 3} is a ferromagnetic half-metal. The charge density map shows a high degree of ionic bonding between Sr and other atoms. Meanwhile, a covalent-bonding Ni–O–Ni–O–Ni chain is observed. The spin density contour of SrNiO{sub 3} further indicates that the magnetic interaction between Ni atoms mediated by O is semicovalent exchange. The density of states are examined to explore the unusual indirect magnetic-exchange mechanism. Corresponding to the total energies results, a robust half-metallic character is observed, suggesting a promising giant magneto-optical Kerr property of the material. The partial density of states are further examined to explore the origin of ferromagnetic half-metallicity. The O atoms are observed to have larger contribution at fermi level than Ni atoms to the spin-polarized states, demonstrating that O atoms play a critical role in ferromagnetic half-metallicity of SrNiO{sub 3}. Hydrostatic pressure effect is examined to evaluate how robust the half-metallic ferromagnetism is. - Graphical abstract: (a) The total energy as a function of the lattice constant a for hexagonal SrNiO3 with various magnetic phases. (b) The total electronic density of states for hexagonal SrNiO{sub 3} with FM configuration from GGA+U calculations. (c) Total electron-density distribution in the (110) plane. The colors gradually change from cyan (through pink) to yellow corresponding to charge density value from 0 to 4.0. (d) The magnetization density map in the (110) plane. The colors range from blue (through green) to red corresponding to magnetization density value from −0.15 to 0.45. Black and white contours stand for positive and negative values, respectively

  15. Synthesis and photocatalytic activity of porous bismuth oxychloride hexagonal prisms.

    PubMed

    Ding, Liyong; Chen, Huan; Wang, Qingqian; Zhou, Tengfei; Jiang, Qingqing; Yuan, Yuhong; Li, Jinlin; Hu, Juncheng

    2016-01-18

    Porous BiOCl hexagonal prisms have been successfully prepared through a simple solvothermal route. These novel BiOCl HPs with porous structures are assembled from nanoparticles and exhibit high activity and selectivity toward the photocatalytic aerobic oxidation of benzyl alcohol to benzaldehyde and degradation of methyl orange.

  16. A low cost route to hexagonal mesostructured carbon molecular sieves.

    PubMed

    Kim, S S; Pinnavaia, T J

    2001-12-07

    A mesoporous carbon molecular sieve with a hexagonal framework structure (denoted C-MSU-H) has been prepared using a MSU-H silica template that can be assembled from a low cost soluble silicate precursor at near-neutral pH conditions.

  17. Microwave Loss Properties of Hexagonal Ferrites for Millimeter Wave Applications.

    DTIC Science & Technology

    1986-03-15

    concerns the magnetic loss. Previous ferromagnetic resonance (FMR) linewidth data indicated that these losses were too large for efficient device... magnetic and dielectric materials measurement facility at Colorado State University and one to extend the measurements reported herein to the actual...reprint of the article, "Off Resonance Relaxation in Hexagonal Ferrites", which was presented at the International Conference on Magnetics , San

  18. TOILET ROOM IN THE PROJECTION BOOTH. NOTE THE HEXAGONAL FLOOR ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    TOILET ROOM IN THE PROJECTION BOOTH. NOTE THE HEXAGONAL FLOOR TILES WITH ACCENTED BORDER AND GLAZED WALL TILES, ALL OF WHICH WERE ORIGINAL/ TYPICAL IN TOILET ROOMS IN THIS FACILITY VIEW FACING NORTHWEST - U.S. Naval Base, Pearl Harbor, Theater, Hornet Avenue between Enterprise & Pokomoke Streets, Pearl City, Honolulu County, HI

  19. Characterization of the secondary flow in hexagonal ducts

    NASA Astrophysics Data System (ADS)

    Marin, O.; Vinuesa, R.; Obabko, A. V.; Schlatter, P.

    2016-12-01

    In this work we report the results of DNSs and LESs of the turbulent flow through hexagonal ducts at friction Reynolds numbers based on centerplane wall shear and duct half-height Reτ,c ≃ 180, 360, and 550. The evolution of the Fanning friction factor f with Re is in very good agreement with experimental measurements. A significant disagreement between the DNS and previous RANS simulations was found in the prediction of the in-plane velocity, and is explained through the inability of the RANS model to properly reproduce the secondary flow present in the hexagon. The kinetic energy of the secondary flow integrated over the cross-sectional area yz decreases with Re in the hexagon, whereas it remains constant with Re in square ducts at comparable Reynolds numbers. Close connection between the values of Reynolds stress u w ¯ on the horizontal wall close to the corner and the interaction of bursting events between the horizontal and inclined walls is found. This interaction leads to the formation of the secondary flow, and is less frequent in the hexagon as Re increases due to the 120∘ aperture of its vertex, whereas in the square duct the 90∘ corner leads to the same level of interaction with increasing Re. Analysis of turbulence statistics at the centerplane and the azimuthal variance of the mean flow and the fluctuations shows a close connection between hexagonal ducts and pipe flows, since the hexagon exhibits near-axisymmetric conditions up to a distance of around 0.15DH measured from its center. Spanwise distributions of wall-shear stress show that in square ducts the 90∘ corner sets the location of a high-speed streak at a distance zv+≃50 from it, whereas in hexagons the 120∘ aperture leads to a shorter distance of zv+≃38 . At these locations the root mean square of the wall-shear stresses exhibits an inflection point, which further shows the connections between the near-wall structures and the large-scale motions in the outer flow.

  20. Fractional scaling of quantum walks on percolation lattices

    NASA Astrophysics Data System (ADS)

    Kendon, Viv; Leung, Godfrey; Bailey, Joe; Knott, Paul

    2011-03-01

    Quantum walks can be used to model processes such as transport in spin chains and bio-molecules. The enhanced spreading and mixing properties of quantum walks compared with their classical counterparts have been well-studied on regular structures and also shown to be sensitive to defects and imperfections. Using numerical simulation, we study the spreading properties of quantum walks on percolation lattices for both bond and site percolation. The randomly missing edges or sites provide a controlled amount of disorder in the regular Cartesian lattice. In one dimension (the line) we introduce a simple model of quantum tunneling to allow the walk to proceed past the missing edges or sites. This allows the quantum walk to spread faster than a classical random walk for short times, but at longer times the disorder localises the quantum walk. In two dimensions, we observe fractional scaling of the spreading with the number of steps of the walk. For percolation above the 85% level, we obtain faster spreading than classical random walks on the full lattice.

  1. Moving embedded lattice solitons.

    PubMed

    Malomed, B A; Fujioka, J; Espinosa-Cerón, A; Rodríguez, R F; González, S

    2006-03-01

    It was recently proved that solitons embedded in the spectrum of linear waves may exist in discrete systems, and explicit solutions for isolated unstable embedded lattice solitons (ELS) of a differential-difference version of a higher-order nonlinear Schrodinger equation were found [Gonzalez-Perez-Sandi, Fujioka, and Malomed, Physica D 197, 86 (2004)]. The discovery of these ELS gives rise to relevant questions such as the following: (1) Are there continuous families of ELS? (2) Can ELS be stable? (3) Is it possible for ELS to move along the lattice? (4) How do ELS interact? The present work addresses these questions by showing that a novel equation (a discrete version of a complex modified Korteweg-de Vries equation that includes next-nearest-neighbor couplings) has a two-parameter continuous family of exact ELS. These solitons can move with arbitrary velocities across the lattice, and the numerical simulations demonstrate that these ELS are completely stable. Moreover, the numerical tests show that these ELS are robust enough to withstand collisions, and the result of a collision is only a shift in the positions of the solitons. The model may apply to the description of a Bose-Einstein condensate with dipole-dipole interactions between the atoms, trapped in a deep optical-lattice potential.

  2. Generalizing Word Lattice Translation

    DTIC Science & Technology

    2008-02-01

    demonstrate substantial gains for Chinese -English and Arabic -English translation. Keywords: word lattice translation, phrase-based and hierarchical...introduce in reordering models. Our experiments evaluating the approach demonstrate substantial gains for Chinese -English and Arabic -English translation. 15...Section 4 presents two applications of the noisier channel paradigm, demonstrating substantial performance gains in Arabic -English and Chinese -English

  3. Supersymmetry on the Lattice

    NASA Astrophysics Data System (ADS)

    Schaich, David

    2016-03-01

    Lattice field theory provides a non-perturbative regularization of strongly interacting systems, which has proven crucial to the study of quantum chromodynamics among many other theories. Supersymmetry plays prominent roles in the study of physics beyond the standard model, both as an ingredient in model building and as a tool to improve our understanding of quantum field theory. Attempts to apply lattice techniques to supersymmetric field theories have a long history, but until recently these efforts have generally encountered insurmountable difficulties related to the interplay of supersymmetry with the lattice discretization of spacetime. In recent years these difficulties have been overcome for a class of theories that includes the particularly interesting case of maximally supersymmetric Yang-Mills (N = 4 SYM) in four dimensions, which is a cornerstone of AdS/CFT duality. In combination with computational advances this progress enables practical numerical investigations of N = 4 SYM on the lattice, which can address questions that are difficult or impossible to handle through perturbation theory, AdS/CFT duality, or the conformal bootstrap program. I will briefly review some of the new ideas underlying this recent progress, and present some results from ongoing large-scale numerical calculations, including comparisons with analytic predictions.

  4. Random lattice superstrings

    SciTech Connect

    Feng Haidong; Siegel, Warren

    2006-08-15

    We propose some new simplifying ingredients for Feynman diagrams that seem necessary for random lattice formulations of superstrings. In particular, half the fermionic variables appear only in particle loops (similarly to loop momenta), reducing the supersymmetry of the constituents of the type IIB superstring to N=1, as expected from their interpretation in the 1/N expansion as super Yang-Mills.

  5. Progress in lattice QCD

    SciTech Connect

    Andreas S. Kronfeld

    2002-09-30

    After reviewing some of the mathematical foundations and numerical difficulties facing lattice QCD, I review the status of several calculations relevant to experimental high-energy physics. The topics considered are moments of structure functions, which may prove relevant to search for new phenomena at the LHC, and several aspects of flavor physics, which are relevant to understanding CP and flavor violation.

  6. Phenomenology Using Lattice QCD

    NASA Astrophysics Data System (ADS)

    Gupta, R.

    2005-08-01

    This talk provides a brief summary of the status of lattice QCD calculations of the light quark masses and the kaon bag parameter BK. Precise estimates of these four fundamental parameters of the standard model, i.e., mu, md, ms and the CP violating parameter η, help constrain grand unified models and could provide a window to new physics.

  7. Phenomenology Using Lattice QCD

    NASA Astrophysics Data System (ADS)

    Gupta, R.

    This talk provides a brief summary of the status of lattice QCD calculations of the light quark masses and the kaon bag parameter BK. Precise estimates of these four fundamental parameters of the standard model, i.e., mu, md, ms and the CP violating parameter η, help constrain grand unified models and could provide a window to new physics.

  8. Rigidity of lattice domes

    NASA Technical Reports Server (NTRS)

    Savelyev, V. A.

    1979-01-01

    The means of ensuring total rigidity of lattice domes, using comparison with solid shells of 1-3 layers are discussed. Irregularities of manufacture, processing, and other factors are considered, as they relate to diminution of rigidity. The discussion uses the concepts of upper and lower critical loads on the structure in question.

  9. Production inventory policies for defective items with inspection errors, sales return, imperfect rework process and backorders

    NASA Astrophysics Data System (ADS)

    Jaggi, Chandra K.; Khanna, Aditi; Kishore, Aakanksha

    2016-03-01

    In order to sustain the challenges of maintaining good quality and perfect screening process, rework process becomes a rescue to compensate for the imperfections present in the production system. The proposed model attempts to explore the existing real-life situation with a more practical approach by incorporating the concept of imperfect rework as this occurs as an unavoidable problem to the firm due to irreparable disorders even in the reworked items. Hence, a production inventory model is formulated here to study the combined effect of imperfect quality items, faulty inspection process and imperfect rework process on the optimal production quantity and optimal backorder level. An analytical method is employed to maximize the expected total profit per unit time. Moreover, the results of several previous research articles namely Chiu et al (2006), Chiu et al (2005), Salameh and Hayek (2001), and classical EPQ with shortages are deduced as special cases. To demonstrate the applicability of the model, and to observe the effects of key parameters on the optimal replenishment policy, a numerical example along with a comprehensive sensitivity analysis has been presented. The pertinence of the model can be found in most of the manufacturing industries like textile, electronics, furniture, footwear, plastics etc. A production lot size model has been explored for defectives items with inspection errors and an imperfect rework process.

  10. Effects of Imperfections on the Buckling Response of Compression-Loaded Composite Shells

    NASA Technical Reports Server (NTRS)

    Hilburger, Mark W.; Starnes, James H., Jr.

    2000-01-01

    The results of an experimental and numerical study of the effects of imperfections on the buckling response of unstiffened thin-walled composite cylindrical shells are presented. Results that identify the individual and combined effects of traditional initial geometric shell-wall imperfections and non-traditional shell-wall thickness variations, shell-end geometric imperfections and variations in loads applied to the ends of the shells on the shell buckling response are included. In addition, results illustrating the effects of manufacturing flaws in the form of gaps between adjacent pieces of graphite-epoxy tape in some of the laminate plies are presented in detail. The shells have been analyzed with a nonlinear finite-element analysis code that accurately accounts for these effects on the buckling and nonlinear responses of the shells. The numerical results indicate that traditional and nontraditional initial imperfections can cause a significant reduction in the buckling load of a compression-loaded composite shell. Furthermore, the results indicate that the imperfections couple in a nonlinear manner. The numerical results correlate well with the experimental results. The nonlinear analysis results are also compared to the results from a traditional linear bifurcation buckling analysis. The results suggest that the nonlinear analysis procedure can be used for determining accurate, high-fidelity design knockdown factors for shell buckling and collapse. The results can also be used to determine the effects of manufacturing tolerances on the buckling response of composite shells.

  11. Thermo-electro-mechanical postbuckling of piezoelectric FG-CNTRC beams with geometric imperfections

    NASA Astrophysics Data System (ADS)

    Wu, Helong; Kitipornchai, Sritawat; Yang, Jie

    2016-09-01

    This paper presents thermo-electro-mechanical postbuckling analysis of geometrically imperfect functionally graded carbon nanotube-reinforced composite (FG-CNTRC) hybrid beams that are integrated with surface-bonded piezoelectric actuators. The material properties of FG-CNTRCs are assumed to be temperature-dependent and graded in the thickness direction. By using a generic imperfection function, various possible imperfections with different shapes and locations in the beam are considered. The theoretical formulations are based on the first-order shear deformation beam theory with von-Kármán nonlinearity. A differential quadrature approximation based iteration process is employed to obtain the postbuckling equilibrium path of piezoelectric FG-CNTRC hybrid beams under thermo-electro-mechanical loading. Parametric studies are conducted to examine the effect of geometric imperfection, distribution pattern and volume fraction of carbon nanotubes, temperature rise, actuator voltage, beam geometry and boundary conditions on the thermo-electro-mechanical postbuckling behaviour. The results show that the thermo-electro-mechanical postbuckling is considerably affected by the imperfection mode, half-wave number, location and amplitude, as well as the temperature rise and boundary conditions. The effect of applied actuator voltage is much less pronounced but tends to be relatively more noticeable as the slenderness ratio increases.

  12. Relaxation of Lattice Inperfections as Studied by Chlorine NQR

    NASA Astrophysics Data System (ADS)

    Hashimoto, Masao; Adachi, Masahiro; Mano, Koichi

    1986-02-01

    The intensities, linewidths, and frequencies of 35Cl NQR signals in 6-nitro-2,4-bis(trichlorom ethyl)-benzo[1,3]dioxine were found to vary remarkably depending on the crystallization methods and annealing. This finding was correlated to the degree of crystal disorder. For a sample obtained by slow crystallization from an ethanolic solution of the compound, the growth of the height of the NQR absorption signal due to annealing was measured as a function of the isothermal annealing time. A kinetic analysis of the growth process gave an activation energy of approx. 110 kJ/mole for the relaxation process of the imperfection dominating the NQR signals. The dimorphism of the compound and the magnitude of the activation energy suggest the presence of misoriented molecules accompanied by vacancies in the crystal lattice of the stable phase.

  13. Ab initio density functional theory investigation of the structural, electronic and optical properties of Ca{sub 3}Sb{sub 2} in hexagonal and cubic phases

    SciTech Connect

    Arghavani Nia, Borhan; Sedighi, Matin; Shahrokhi, Masoud; Moradian, Rostam

    2013-11-15

    A density functional theory study of structural, electronical and optical properties of Ca{sub 3}Sb{sub 2} compound in hexagonal and cubic phases is presented. In the exchange–correlation potential, generalized gradient approximation (PBE-GGA) has been used to calculate lattice parameters, bulk modulus, cohesive energy, dielectric function and energy loss spectra. The electronic band structure of this compound has been calculated using the above two approximations as well as another form of PBE-GGA, proposed by Engle and Vosko (EV-GGA). It is found that the hexagonal phase of Ca{sub 3}Sb{sub 2} has an indirect gap in the Γ→N direction; while in the cubic phase there is a direct-gap at the Γ point in the PBE-GGA and EV-GGA. Effects of applying pressure on the band structure of the system studied and optical properties of these systems were calculated. - Graphical abstract: A density functional theory study of structural, electronic and optical properties of Ca{sub 3}Sb{sub 2} compound in hexagonal and cubic phases is presented. Display Omitted - Highlights: • Physical properties of Ca{sub 3}Sb{sub 2} in hexagonal and cubic phases are investigated. • It is found that the hexagonal phase is an indirect gap semiconductor. • Ca{sub 3}Sb{sub 2} is a direct-gap semiconductor at the Γ point in the cubic phase. • By increasing pressure the semiconducting band gap and anti-symmetry gap are decreased.

  14. Propagation of SH waves in a piezoelectric/piezomagnetic plate: Effects of interfacial imperfection couplings and the related physical mechanisms

    NASA Astrophysics Data System (ADS)

    Wei, Hong-Xing; Li, Yong-Dong; Xiong, Tao; Guan, Yong

    2016-09-01

    The problem of dispersive SH wave in a piezoelectric/piezomagnetic plate that contains an imperfect interface is considered in the present work. An imperfection coupling model is adopted to describe the magnetic, electric and mechanical imperfections on the interface. A transcendental dispersion equation is derived and numerically solved to get the phase velocity. The validity of the numerical procedure is verified in a degenerated case. The effects of the coupled interfacial imperfections on the dispersion behavior of SH waves are discussed in detail and the related underlying physical mechanisms are explained.

  15. Synthesis, characterization, shape evolution, and optical properties of copper sulfide hexagonal bifrustum nanocrystals

    NASA Astrophysics Data System (ADS)

    Jia, Baorui; Qin, Mingli; Jiang, Xuezhi; Zhang, Zili; Zhang, Lin; Liu, Ye; Qu, Xuanhui

    2013-03-01

    The hexagonal bifrustum-shaped copper sulfide (CuS) nanocrystals were selectively and facilely synthesized by a hydrothermal method for the first time at 120 °C. The products were characterized by X-ray diffraction, field emission scanning electron microscopy, energy dispersive X-ray spectroscopy, transmission electron microscopy, ultraviolet-visible (UV-Vis) spectroscopy, and photoluminescence spectroscopy. The results showed that the CuS hexagonal bifrustum nanocrystal was bounded by two top hexagons with edge length of about 50-70 nm and twelve lateral trapezoids with a base of about 100 nm and that the length of each hexagonal bifrustum was about 250 nm. Tetradecylamine (TDA), as an effective capping agent, was found to be critical for this special shape. Using different amounts of TDA, two kinds of CuS hexagonal bifrustum nanocrystals were obtained: "lender hexagonal bifrustum" and "pancake hexagonal bifrustum." Furthermore, we studied the formation mechanism of hexagonal bifrustum, which is related to the intrinsic crystalline structure of CuS and Ostwald ripening. And, the results revealed that the CuS nanocrystal evolved from hexagonal plate to hexagonal bifrustum and finally to hexagonal bipyramid as the heating time increased. The UV-Vis absorption spectrum showed that these CuS hexagonal bifrustum nanocrystals exhibited strong absorption in the near-infrared region and had a potential application for photothermal therapy and photocatalysis.

  16. Homogenized Finite Element Analysis on Effective Elastoplastic Mechanical Behaviors of Composite with Imperfect Interfaces

    PubMed Central

    Jiang, Wu-Gui; Zhong, Ren-Zhi; Qin, Qing H.; Tong, Yong-Gang

    2014-01-01

    A three-dimensional (3D) representative volume element (RVE) model was developed for analyzing effective mechanical behavior of fiber-reinforced ceramic matrix composites with imperfect interfaces. In the model, the fiber is assumed to be perfectly elastic until its tensile strength, and the ceramic material is modeled by an elasto-plastic Drucker-Prager constitutive law. The RVE model is then used to study the elastic properties and the tensile strength of composites with imperfect interfaces and validated through experiments. The imperfect interfaces between the fiber and the matrix are taken into account by introducing some cohesive contact surfaces. The influences of the interface on the elastic constants and the tensile strengths are examined through these interface models. PMID:25522170

  17. Adaptive beamforming with imperfect arrays: Pattern effects and their partial correction

    NASA Astrophysics Data System (ADS)

    Pettersson, Lars E.

    1992-12-01

    The effects of various types of imperfections on the radiation pattern of adaptive antenna arrays, using the Applebaum and Frost algorithms, are investigated. The imperfections considered are nonuniform noise figures in the channels, gain and phase shift error, IQ imbalance, DC offset, finite number of samples when forming the covariance matrix, quantization of the signals, and the weights and saturation of the signals. In particular the effects on the resulting sidelobe level, null depth, and gain are studied, and simulated results and analytical expressions for the expected pattern parameters are given. The effects of some methods to partly correct for the imperfections are also investigated. A method to obtain low sidelobe pattern when using the Frost algorithm is also discussed.

  18. Homogenized finite element analysis on effective elastoplastic mechanical behaviors of composite with imperfect interfaces.

    PubMed

    Jiang, Wu-Gui; Zhong, Ren-Zhi; Qin, Qing H; Tong, Yong-Gang

    2014-12-16

    A three-dimensional (3D) representative volume element (RVE) model was developed for analyzing effective mechanical behavior of fiber-reinforced ceramic matrix composites with imperfect interfaces. In the model, the fiber is assumed to be perfectly elastic until its tensile strength, and the ceramic material is modeled by an elasto-plastic Drucker-Prager constitutive law. The RVE model is then used to study the elastic properties and the tensile strength of composites with imperfect interfaces and validated through experiments. The imperfect interfaces between the fiber and the matrix are taken into account by introducing some cohesive contact surfaces. The influences of the interface on the elastic constants and the tensile strengths are examined through these interface models.

  19. Stochastic analysis of the lateral-torsional buckling resistance of steel beams with random imperfections

    NASA Astrophysics Data System (ADS)

    Kala, Zdeněk

    2013-10-01

    The paper deals with the statistical analysis of resistance of a hot-rolled steel IPE beam under major axis bending. The lateral-torsional buckling stability problem of imperfect beam is described. The influence of bending moments and warping torsion on the ultimate limit state of the IPE beam with random imperfections is analyzed. The resistance is calculated by means of the close form solution. The initial geometrical imperfections of the beam are considered as the formatively identical to the first eigen mode of buckling. Changes of mean values of the resistance, of mean values of internal bending moments, of the variance of resistance and of the variance of internal bending moments were studied in dependence on the beam non-dimensional slenderness. The values of non-dimensional slenderness for which the statistical characteristics of internal moments associated with random resistance are maximal were determined.

  20. Algorithm for the evaluation of imperfections in auto bodywork using profiles from a retroreflective image.

    PubMed

    Barber, Ramon; Zwilling, Valerie; Salichs, Miguel A

    2014-02-05

    Nowadays the automobile industry is becoming more and more demanding as far as quality is concerned. Within the wide variety of processes in which this quality must be ensured, those regarding the squeezing of the auto bodywork are especially important due to the fact that the quality of the resulting product is tested manually by experts, leading to inaccuracies of all types. In this paper, an algorithm is proposed for the automated evaluation of the imperfections in the sheets of the bodywork after the squeezing process. The algorithm processes the profile signals from a retroreflective image and characterizes an imperfection. It is based on a convergence criterion that follows the line of the maximum gradient of the imperfection and gives its geometrical characteristics as a result: maximum gradient, length, width, and area.

  1. Splitter imperfections in annular split-flow thin separation channels: effect on nonspecific crossover.

    PubMed

    Williams, P Stephen; Moore, Lee R; Chalmers, Jeffrey J; Zborowski, Maciej

    2003-03-15

    The separation performance of split-flow thin (SPLITT) separation channels generally falls short of ideal behavior. There are many possible contributing factors to the loss of separation resolution, and these are discussed in the text. The possibility that small imperfections in the splitters play a significant role is examined in this study. Computational fluid dynamics is used to determine the flow pattern within an annular SPLITT channel having small imperfections in the inlet splitter. These results are used to calculate the nonspecific crossover of particles from the inner annular inlet to the outer annular outlet under various flow rate regimes. Nonspecific crossover, obtained through convective transport alone, and not the result of field-induced transport, is often used as a check of channel behavior. The results of a typical experimental determination of nonspecific crossover are included for comparison. It is concluded that geometrical imperfections can indeed play a significant role in the loss of resolution observed for these systems.

  2. Programming Self-Assembly of DNA Origami Honeycomb Two-Dimensional Lattices and Plasmonic Metamaterials.

    PubMed

    Wang, Pengfei; Gaitanaros, Stavros; Lee, Seungwoo; Bathe, Mark; Shih, William M; Ke, Yonggang

    2016-06-22

    Scaffolded DNA origami has proven to be a versatile method for generating functional nanostructures with prescribed sub-100 nm shapes. Programming DNA-origami tiles to form large-scale 2D lattices that span hundreds of nanometers to the micrometer scale could provide an enabling platform for diverse applications ranging from metamaterials to surface-based biophysical assays. Toward this end, here we design a family of hexagonal DNA-origami tiles using computer-aided design and demonstrate successful self-assembly of micrometer-scale 2D honeycomb lattices and tubes by controlling their geometric and mechanical properties including their interconnecting strands. Our results offer insight into programmed self-assembly of low-defect supra-molecular DNA-origami 2D lattices and tubes. In addition, we demonstrate that these DNA-origami hexagon tiles and honeycomb lattices are versatile platforms for assembling optical metamaterials via programmable spatial arrangement of gold nanoparticles (AuNPs) into cluster and superlattice geometries.

  3. Fractional lattice charge transport

    PubMed Central

    Flach, Sergej; Khomeriki, Ramaz

    2017-01-01

    We consider the dynamics of noninteracting quantum particles on a square lattice in the presence of a magnetic flux α and a dc electric field E oriented along the lattice diagonal. In general, the adiabatic dynamics will be characterized by Bloch oscillations in the electrical field direction and dispersive ballistic transport in the perpendicular direction. For rational values of α and a corresponding discrete set of values of E(α) vanishing gaps in the spectrum induce a fractionalization of the charge in the perpendicular direction - while left movers are still performing dispersive ballistic transport, the complementary fraction of right movers is propagating in a dispersionless relativistic manner in the opposite direction. Generalizations and the possible probing of the effect with atomic Bose-Einstein condensates and photonic networks are discussed. Zak phase of respective band associated with gap closing regime has been computed and it is found converging to π/2 value. PMID:28102302

  4. Statistics of lattice animals

    NASA Astrophysics Data System (ADS)

    Hsu, Hsiao-Ping; Nadler, Walder; Grassberger, Peter

    2005-07-01

    The scaling behavior of randomly branched polymers in a good solvent is studied in two to nine dimensions, modeled by lattice animals on simple hypercubic lattices. For the simulations, we use a biased sequential sampling algorithm with re-sampling, similar to the pruned-enriched Rosenbluth method (PERM) used extensively for linear polymers. We obtain high statistics of animals with up to several thousand sites in all dimension 2⩽d⩽9. The partition sum (number of different animals) and gyration radii are estimated. In all dimensions we verify the Parisi-Sourlas prediction, and we verify all exactly known critical exponents in dimensions 2, 3, 4, and ⩾8. In addition, we present the hitherto most precise estimates for growth constants in d⩾3. For clusters with one site attached to an attractive surface, we verify the superuniversality of the cross-over exponent at the adsorption transition predicted by Janssen and Lyssy.

  5. Magnetic and High-Frequency Dielectric Parameters of Divalent Ion-Substituted W-Type Hexagonal Ferrites

    NASA Astrophysics Data System (ADS)

    Ali, Akbar; Grössinger, R.; Imran, Muhammad; Khan, M. Ajmal; Elahi, Asmat; Akhtar, Majid Niaz; Mustafa, Ghulam; Khan, Muhammad Azhar; Ullah, Hafeez; Murtaza, Ghulam; Ahmad, Mukhtar

    2017-02-01

    Polycrystalline W-type hexagonal ferrites with chemical formulae Ba0.5Sr0.5 Co2- x Me x Fe16O27 ( x = 0, 0.5, Me = Mn, Mg, Zn, Ni) have been prepared using sol-gel autocombustion. It has been reported in our earlier published work that all the samples exhibit a single-phase W-type hexagonal structure which was confirmed by x-ray diffraction (XRD) analysis. The values of bulk density lie in the range of 4.64-4.78 g/cm3 for all the samples which are quite high as compared to those for other types of hexaferrites. It was also observed that Zn-substituted ferrite reflects the highest (14.7 × 107 Ω-cm) whereas Mn-substituted ferrite has the lowest (11.3 × 107 Ω-cm) values of direct current (DC) electrical resistivity. The observed values of saturation magnetization ( M s) are found to be in the range of 62.01-68.7 emu/g depending upon the type of cation substitution into the hexagonal lattice. All the samples exhibit a typical soft magnetic character with low values of coercivity ( H c) that are in the range of 26-85 Oe. These ferrites may be promising materials for microwave absorbers due to their higher saturation magnetization and low coercivities. Both the dielectric constant and tangent loss decrease with increasing frequency in the lower frequency region and become constant in the higher frequency region. The much lower dielectric constant obtained in this study makes the investigated ferrites very useful for high-frequency applications, i.e. dielectric resonators and for camouflaging military targets such as ships, tanks and aircrafts, etc.

  6. Nonlinear vibrations of cylindrical shells with initial imperfections in a supersonic flow

    NASA Astrophysics Data System (ADS)

    Kurilov, E. A.; Mikhlin, Yu. V.

    2007-09-01

    The paper studies the dynamics of nonlinear elastic cylindrical shells using the theory of shallow shells. The aerodynamic pressure on the shell in a supersonic flow is found using piston theory. The effect of the flow and initial deflections on the vibrations of the shell is analyzed in the flutter range. The normal modes of both perfect shells in a flow and shells with initial imperfections are studied. In the latter case, the trajectories of normal modes in the configuration space are nearly rectilinear, only one mode determined by the initial imperfections being stable

  7. Effect of Imperfections on the Collapse of Rectangular Plates Using Variational Calculus.

    DTIC Science & Technology

    1979-12-01

    UCLASSIFIEO AFI/AE/AA/79D014 ru oIN280 11 AFIT/GAE/AA/7 9D-l 4 EFFECT OF IMPERFECTIONS ON THE COLLAPSE OF RECTANGULAR KLATES USING VARIATIONAL CALCULUS , THESIS...Imperfections on the Collapse of Rectangular Plates Using Variational Calculus THESIS Presented to the Faculty of the School of Engineering of the Air...PLATES USING VARIATIONAL CALCULUS I. Introduction Background The first problems in elastic instabi. ty were solved over 200 years ago by Euler (1

  8. Synchronizing spatio-temporal chaos with imperfect models: A stochastic surface growth picture

    SciTech Connect

    Pazó, Diego López, Juan M.; Rodríguez, Miguel A.; Gallego, Rafael

    2014-12-01

    We study the synchronization of two spatially extended dynamical systems where the models have imperfections. We show that the synchronization error across space can be visualized as a rough surface governed by the Kardar-Parisi-Zhang equation with both upper and lower bounding walls corresponding to nonlinearities and model discrepancies, respectively. Two types of model imperfections are considered: parameter mismatch and unresolved fast scales, finding in both cases the same qualitative results. The consistency between different setups and systems indicates that the results are generic for a wide family of spatially extended systems.

  9. Postbuckling analysis of shear deformable composite flat panels taking into account geometrical imperfections

    NASA Technical Reports Server (NTRS)

    Librescu, L.; Stein, M.

    1990-01-01

    The effects of initial geometrical imperfections on the postbuckling response of flat laminated composite panels to uniaxial and biaxial compressive loading are investigated analytically. The derivation of the mathematical model on the basis of first-order transverse shear deformation theory is outlined, and numerical results for perfect and imperfect, single-layer and three-layer square plates with free-free, clamped-clamped, or free-clamped edges are presented in graphs and briefly characterized. The present approach is shown to be more accurate than analyses based on the classical Kirchhoff plate model.

  10. Charmonium from Lattice QCD

    SciTech Connect

    Jozef Dudek

    2007-08-05

    Charmonium is an attractive system for the application of lattice QCD methods. While the sub-threshold spectrum has been considered in some detail in previous works, it is only very recently that excited and higher-spin states and further properties such as radiative transitions and two-photon decays have come to be calculated. I report on this recent progress with reference to work done at Jefferson Lab.

  11. Crystallographic Lattice Boltzmann Method

    NASA Astrophysics Data System (ADS)

    Namburi, Manjusha; Krithivasan, Siddharth; Ansumali, Santosh

    2016-06-01

    Current approaches to Direct Numerical Simulation (DNS) are computationally quite expensive for most realistic scientific and engineering applications of Fluid Dynamics such as automobiles or atmospheric flows. The Lattice Boltzmann Method (LBM), with its simplified kinetic descriptions, has emerged as an important tool for simulating hydrodynamics. In a heterogeneous computing environment, it is often preferred due to its flexibility and better parallel scaling. However, direct simulation of realistic applications, without the use of turbulence models, remains a distant dream even with highly efficient methods such as LBM. In LBM, a fictitious lattice with suitable isotropy in the velocity space is considered to recover Navier-Stokes hydrodynamics in macroscopic limit. The same lattice is mapped onto a cartesian grid for spatial discretization of the kinetic equation. In this paper, we present an inverted argument of the LBM, by making spatial discretization as the central theme. We argue that the optimal spatial discretization for LBM is a Body Centered Cubic (BCC) arrangement of grid points. We illustrate an order-of-magnitude gain in efficiency for LBM and thus a significant progress towards feasibility of DNS for realistic flows.

  12. Digital lattice gauge theories

    NASA Astrophysics Data System (ADS)

    Zohar, Erez; Farace, Alessandro; Reznik, Benni; Cirac, J. Ignacio

    2017-02-01

    We propose a general scheme for a digital construction of lattice gauge theories with dynamical fermions. In this method, the four-body interactions arising in models with 2 +1 dimensions and higher are obtained stroboscopically, through a sequence of two-body interactions with ancillary degrees of freedom. This yields stronger interactions than the ones obtained through perturbative methods, as typically done in previous proposals, and removes an important bottleneck in the road towards experimental realizations. The scheme applies to generic gauge theories with Lie or finite symmetry groups, both Abelian and non-Abelian. As a concrete example, we present the construction of a digital quantum simulator for a Z3 lattice gauge theory with dynamical fermionic matter in 2 +1 dimensions, using ultracold atoms in optical lattices, involving three atomic species, representing the matter, gauge, and auxiliary degrees of freedom, that are separated in three different layers. By moving the ancilla atoms with a proper sequence of steps, we show how we can obtain the desired evolution in a clean, controlled way.

  13. Crystallographic Lattice Boltzmann Method

    PubMed Central

    Namburi, Manjusha; Krithivasan, Siddharth; Ansumali, Santosh

    2016-01-01

    Current approaches to Direct Numerical Simulation (DNS) are computationally quite expensive for most realistic scientific and engineering applications of Fluid Dynamics such as automobiles or atmospheric flows. The Lattice Boltzmann Method (LBM), with its simplified kinetic descriptions, has emerged as an important tool for simulating hydrodynamics. In a heterogeneous computing environment, it is often preferred due to its flexibility and better parallel scaling. However, direct simulation of realistic applications, without the use of turbulence models, remains a distant dream even with highly efficient methods such as LBM. In LBM, a fictitious lattice with suitable isotropy in the velocity space is considered to recover Navier-Stokes hydrodynamics in macroscopic limit. The same lattice is mapped onto a cartesian grid for spatial discretization of the kinetic equation. In this paper, we present an inverted argument of the LBM, by making spatial discretization as the central theme. We argue that the optimal spatial discretization for LBM is a Body Centered Cubic (BCC) arrangement of grid points. We illustrate an order-of-magnitude gain in efficiency for LBM and thus a significant progress towards feasibility of DNS for realistic flows. PMID:27251098

  14. Topological lattice actions

    NASA Astrophysics Data System (ADS)

    Bietenholz, W.; Gerber, U.; Pepe, M.; Wiese, U.-J.

    2010-12-01

    We consider lattice field theories with topological actions, which are invariant against small deformations of the fields. Some of these actions have infinite barriers separating different topological sectors. Topological actions do not have the correct classical continuum limit and they cannot be treated using perturbation theory, but they still yield the correct quantum continuum limit. To show this, we present analytic studies of the 1-d O(2) and O(3) model, as well as Monte Carlo simulations of the 2-d O(3) model using topological lattice actions. Some topological actions obey and others violate a lattice Schwarz inequality between the action and the topological charge Q. Irrespective of this, in the 2-d O(3) model the topological susceptibility {χ_t} = {{{left< {{Q^2}} rightrangle }} left/ {V} right.} is logarithmically divergent in the continuum limit. Still, at non-zero distance the correlator of the topological charge density has a finite continuum limit which is consistent with analytic predictions. Our study shows explicitly that some classically important features of an action are irrelevant for reaching the correct quantum continuum limit.

  15. Bacterial chemoreceptor arrays are hexagonally packed trimers of receptor dimers networked by rings of kinase and coupling proteins

    PubMed Central

    Briegel, Ariane; Li, Xiaoxiao; Bilwes, Alexandrine M.; Hughes, Kelly T.; Jensen, Grant J.; Crane, Brian R.

    2012-01-01

    Chemoreceptor arrays are supramolecular transmembrane machines of unknown structure that allow bacteria to sense their surroundings and respond by chemotaxis. We have combined X-ray crystallography of purified proteins with electron cryotomography of native arrays inside cells to reveal the arrangement of the component transmembrane receptors, histidine kinases (CheA) and CheW coupling proteins. Trimers of receptor dimers lie at the vertices of a hexagonal lattice in a “two-facing-two” configuration surrounding a ring of alternating CheA regulatory domains (P5) and CheW couplers. Whereas the CheA kinase domains (P4) project downward below the ring, the CheA dimerization domains (P3) link neighboring rings to form an extended, stable array. This highly interconnected protein architecture underlies the remarkable sensitivity and cooperative nature of transmembrane signaling in bacterial chemotaxis. PMID:22355139

  16. A wave-dominated heat transport mechanism for negative differential thermal resistance in graphene/hexagonal boron nitride heterostructures

    NASA Astrophysics Data System (ADS)

    Chen, Xue-Kun; Liu, Jun; Peng, Zhi-Hua; Du, Dan; Chen, Ke-Qiu

    2017-02-01

    Nonlinear thermal transport in graphene/hexagonal boron nitride (h-BN) heterostructure is investigated by the nonequilibrium molecular dynamics method. It is found that negative differential thermal resistance (NDTR) will appear as the applied temperature difference increases. Detailed phonon spectra analysis reveals that the excited out-of-plane acoustic wave plays an important role in the heat transport across such interface. That is, the mechanical wave results in a significant mismatch between the lattice vibrations of graphene and h-BN domains and hinders interfacial thermal transport. In addition, NDTR can be tuned through the temperature parameter. Interestingly, the regime of NDTR becomes smaller and eventually vanishes with increasing the heterostructure length. However, NDTR is insensitive to the variation of system width. The work may be useful for nanoscale thermal managements utilizing the graphene/h-BN heterostructure.

  17. A new interlayer potential for hexagonal boron nitride

    NASA Astrophysics Data System (ADS)

    Akıner, Tolga; Mason, Jeremy K.; Ertürk, Hakan

    2016-09-01

    A new interlayer potential is developed for interlayer interactions of hexagonal boron nitride sheets, and its performance is compared with other potentials in the literature using molecular dynamics simulations. The proposed potential contains Coulombic and Lennard-Jones 6-12 terms, and is calibrated with recent experimental data including the hexagonal boron nitride interlayer distance and elastic constants. The potentials are evaluated by comparing the experimental and simulated values of interlayer distance, density, elastic constants, and thermal conductivity using non-equilibrium molecular dynamics. The proposed potential is found to be in reasonable agreement with experiments, and improves on earlier potentials in several respects. Simulated thermal conductivity values as a function of the number of layers and of temperature suggest that the proposed LJ 6-12 potential has the ability to predict some phonon behaviour during heat transport in the out-of-plane direction.

  18. The Formation and Characterization of GaN Hexagonal Pyramids

    NASA Astrophysics Data System (ADS)

    Zhang, Shi-Ying; Xiu, Xiang-Qian; Lin, Zeng-Qin; Hua, Xue-Mei; Xie, Zi-Li; Zhang, Rong; Zheng, You-Dou

    2013-05-01

    GaN with hexagonal pyramids is fabricated using the photo-assisted electroless chemical etching method. Defective areas of the GaN substrate are selectively etched in a mixed solution of KOH and K2S2O8 under ultraviolet illumination, producing submicron-sized pyramids. Hexagonal pyramids on the etched GaN with well-defined {101¯1¯} facets and very sharp tips are formed. High-resolution x-ray diffraction shows that etched GaN with pyramids has a higher crystal quality, and micro-Raman spectra reveal a tensile stress relaxation in GaN with pyramids compared with normal GaN. The cathodoluminescence intensity of GaN after etching is significantly increased by three times, which is attributed to the reduction in the internal reflection, high-quality GaN with pyramids and the Bragg effect.

  19. Zonal wavefront estimation using an array of hexagonal grating patterns

    SciTech Connect

    Pathak, Biswajit E-mail: brboruah@iitg.ernet.in; Boruah, Bosanta R. E-mail: brboruah@iitg.ernet.in

    2014-10-15

    Accuracy of Shack-Hartmann type wavefront sensors depends on the shape and layout of the lenslet array that samples the incoming wavefront. It has been shown that an array of gratings followed by a focusing lens provide a substitution for the lensslet array. Taking advantage of the computer generated holography technique, any arbitrary diffraction grating aperture shape, size or pattern can be designed with little penalty for complexity. In the present work, such a holographic technique is implemented to design regular hexagonal grating array to have zero dead space between grating patterns, eliminating the possibility of leakage of wavefront during the estimation of the wavefront. Tessellation of regular hexagonal shape, unlike other commonly used shapes, also reduces the estimation error by incorporating more number of neighboring slope values at an equal separation.

  20. Melting of hexagonal skyrmion states in chiral magnets

    NASA Astrophysics Data System (ADS)

    Ambrose, M. C.; Stamps, R. L.

    2013-05-01

    Skyrmions are spiral structures observed in thin films of certain magnetic materials (Uchida et al 2006 Science 311 359-61). Of the phases allowed by the crystalline symmetries of these materials (Yi et al 2009 Phys. Rev. B 80 054416), only the hexagonally packed phases (SCh) have been observed. Here the melting of the SCh phase is investigated using Monte Carlo simulations. In addition to the usual measure of skyrmion density, chiral charge, a morphological measure is considered. In doing so it is shown that the low-temperature reduction in chiral charge is associated with a change in skyrmion profiles rather than skyrmion destruction. At higher temperatures, the loss of six-fold symmetry is associated with the appearance of elongated skyrmions that disrupt the hexagonal packing.

  1. Chemical and Bandgap Engineering in Monolayer Hexagonal Boron Nitride.

    PubMed

    Ba, Kun; Jiang, Wei; Cheng, Jingxin; Bao, Jingxian; Xuan, Ningning; Sun, Yangye; Liu, Bing; Xie, Aozhen; Wu, Shiwei; Sun, Zhengzong

    2017-04-03

    Monolayer hexagonal boron nitride (h-BN) possesses a wide bandgap of ~6 eV. Trimming down the bandgap is technically attractive, yet poses remarkable challenges in chemistry. One strategy is to topological reform the h-BN's hexagonal structure, which involves defects or grain boundaries (GBs) engineering in the basal plane. The other way is to invite foreign atoms, such as carbon, to forge bizarre hybrid structures like hetero-junctions or semiconducting h-BNC materials. Here we successfully developed a general chemical method to synthesize these different h-BN derivatives, showcasing how the chemical structure can be manipulated with or without a graphene precursor, and the bandgap be tuned to ~2 eV, only one third of the pristine one's.

  2. Thickness-dependent bending modulus of hexagonal boron nitride nanosheets.

    PubMed

    Li, Chun; Bando, Yoshio; Zhi, Chunyi; Huang, Yang; Golberg, Dmitri

    2009-09-23

    Bending modulus of exfoliation-made single-crystalline hexagonal boron nitride nanosheets (BNNSs) with thicknesses of 25-300 nm and sizes of 1.2-3.0 microm were measured using three-point bending tests in an atomic force microscope. BNNSs suspended on an SiO(2) trench were clamped by a metal film via microfabrication based on electron beam lithography. Calculated by the plate theory of a doubly clamped plate under a concentrated load, the bending modulus of BNNSs was found to increase with the decrease of sheet thickness and approach the theoretical C(33) value of a hexagonal BN single crystal in thinner sheets (thickness<50 nm). The thickness-dependent bending modulus was suggested to be due to the layer distribution of stacking faults which were also thought to be responsible for the layer-by-layer BNNS exfoliation.

  3. Oriented graphene nanoribbons embedded in hexagonal boron nitride trenches

    NASA Astrophysics Data System (ADS)

    Chen, Lingxiu; He, Li; Wang, Hui Shan; Wang, Haomin; Tang, Shujie; Cong, Chunxiao; Xie, Hong; Li, Lei; Xia, Hui; Li, Tianxin; Wu, Tianru; Zhang, Daoli; Deng, Lianwen; Yu, Ting; Xie, Xiaoming; Jiang, Mianheng

    2017-03-01

    Graphene nanoribbons (GNRs) are ultra-narrow strips of graphene that have the potential to be used in high-performance graphene-based semiconductor electronics. However, controlled growth of GNRs on dielectric substrates remains a challenge. Here, we report the successful growth of GNRs directly on hexagonal boron nitride substrates with smooth edges and controllable widths using chemical vapour deposition. The approach is based on a type of template growth that allows for the in-plane epitaxy of mono-layered GNRs in nano-trenches on hexagonal boron nitride with edges following a zigzag direction. The embedded GNR channels show excellent electronic properties, even at room temperature. Such in-plane hetero-integration of GNRs, which is compatible with integrated circuit processing, creates a gapped channel with a width of a few benzene rings, enabling the development of digital integrated circuitry based on GNRs.

  4. Thickness-dependent bending modulus of hexagonal boron nitride nanosheets

    NASA Astrophysics Data System (ADS)

    Li, Chun; Bando, Yoshio; Zhi, Chunyi; Huang, Yang; Golberg, Dmitri

    2009-09-01

    Bending modulus of exfoliation-made single-crystalline hexagonal boron nitride nanosheets (BNNSs) with thicknesses of 25-300 nm and sizes of 1.2-3.0 µm were measured using three-point bending tests in an atomic force microscope. BNNSs suspended on an SiO2 trench were clamped by a metal film via microfabrication based on electron beam lithography. Calculated by the plate theory of a doubly clamped plate under a concentrated load, the bending modulus of BNNSs was found to increase with the decrease of sheet thickness and approach the theoretical C33 value of a hexagonal BN single crystal in thinner sheets (thickness<50 nm). The thickness-dependent bending modulus was suggested to be due to the layer distribution of stacking faults which were also thought to be responsible for the layer-by-layer BNNS exfoliation.

  5. Calculation of Accurate Hexagonal Discontinuity Factors for PARCS

    SciTech Connect

    Pounders. J., Bandini, B. R. , Xu, Y, and Downar, T. J.

    2007-11-01

    In this study we derive a methodology for calculating discontinuity factors consistent with the Triangle-based Polynomial Expansion Nodal (TPEN) method implemented in PARCS for hexagonal reactor geometries. The accuracy of coarse-mesh nodal methods is greatly enhanced by permitting flux discontinuities at node boundaries, but the practice of calculating discontinuity factors from infinite-medium (zero-current) single bundle calculations may not be sufficiently accurate for more challenging problems in which there is a large amount of internodal neutron streaming. The authors therefore derive a TPEN-based method for calculating discontinuity factors that are exact with respect to generalized equivalence theory. The method is validated by reproducing the reference solution for a small hexagonal core.

  6. Oriented graphene nanoribbons embedded in hexagonal boron nitride trenches

    PubMed Central

    Chen, Lingxiu; He, Li; Wang, Hui Shan; Wang, Haomin; Tang, Shujie; Cong, Chunxiao; Xie, Hong; Li, Lei; Xia, Hui; Li, Tianxin; Wu, Tianru; Zhang, Daoli; Deng, Lianwen; Yu, Ting; Xie, Xiaoming; Jiang, Mianheng

    2017-01-01

    Graphene nanoribbons (GNRs) are ultra-narrow strips of graphene that have the potential to be used in high-performance graphene-based semiconductor electronics. However, controlled growth of GNRs on dielectric substrates remains a challenge. Here, we report the successful growth of GNRs directly on hexagonal boron nitride substrates with smooth edges and controllable widths using chemical vapour deposition. The approach is based on a type of template growth that allows for the in-plane epitaxy of mono-layered GNRs in nano-trenches on hexagonal boron nitride with edges following a zigzag direction. The embedded GNR channels show excellent electronic properties, even at room temperature. Such in-plane hetero-integration of GNRs, which is compatible with integrated circuit processing, creates a gapped channel with a width of a few benzene rings, enabling the development of digital integrated circuitry based on GNRs. PMID:28276532

  7. Chemical and Bandgap Engineering in Monolayer Hexagonal Boron Nitride

    PubMed Central

    Ba, Kun; Jiang, Wei; Cheng, Jingxin; Bao, Jingxian; Xuan, Ningning; Sun, Yangye; Liu, Bing; Xie, Aozhen; Wu, Shiwei; Sun, Zhengzong

    2017-01-01

    Monolayer hexagonal boron nitride (h-BN) possesses a wide bandgap of ~6 eV. Trimming down the bandgap is technically attractive, yet poses remarkable challenges in chemistry. One strategy is to topological reform the h-BN’s hexagonal structure, which involves defects or grain boundaries (GBs) engineering in the basal plane. The other way is to invite foreign atoms, such as carbon, to forge bizarre hybrid structures like hetero-junctions or semiconducting h-BNC materials. Here we successfully developed a general chemical method to synthesize these different h-BN derivatives, showcasing how the chemical structure can be manipulated with or without a graphene precursor, and the bandgap be tuned to ~2 eV, only one third of the pristine one’s. PMID:28367992

  8. Oriented graphene nanoribbons embedded in hexagonal boron nitride trenches.

    PubMed

    Chen, Lingxiu; He, Li; Wang, Hui Shan; Wang, Haomin; Tang, Shujie; Cong, Chunxiao; Xie, Hong; Li, Lei; Xia, Hui; Li, Tianxin; Wu, Tianru; Zhang, Daoli; Deng, Lianwen; Yu, Ting; Xie, Xiaoming; Jiang, Mianheng

    2017-03-09

    Graphene nanoribbons (GNRs) are ultra-narrow strips of graphene that have the potential to be used in high-performance graphene-based semiconductor electronics. However, controlled growth of GNRs on dielectric substrates remains a challenge. Here, we report the successful growth of GNRs directly on hexagonal boron nitride substrates with smooth edges and controllable widths using chemical vapour deposition. The approach is based on a type of template growth that allows for the in-plane epitaxy of mono-layered GNRs in nano-trenches on hexagonal boron nitride with edges following a zigzag direction. The embedded GNR channels show excellent electronic properties, even at room temperature. Such in-plane hetero-integration of GNRs, which is compatible with integrated circuit processing, creates a gapped channel with a width of a few benzene rings, enabling the development of digital integrated circuitry based on GNRs.

  9. Electrically dependent bandgaps in graphene on hexagonal boron nitride

    SciTech Connect

    Kaplan, D. Swaminathan, V.; Recine, G.

    2014-03-31

    We present first-principles calculations on the bandgap of graphene on a layer of hexagonal boron nitride in three different stacking configurations. Relative stability of the configurations is identified and bandgap tunability is demonstrated through the application of an external, perpendicularly applied electric field. We carefully examine the bandgap's sensitivity to both magnitude of the applied field as well as separation between the graphene and hexagonal boron nitride layers. Features of the band structure are examined and configuration-dependent relationships between the field and bandgap are revealed and elucidated through the atom-projected density of states. These findings suggest the potential for opening and modulating a bandgap in graphene as high as several hundred meV.

  10. Stretching the limits of membrane charge density using Dendrimer Lipids - New Highly Transfecting Hexagonal Phases for Gene Delivery

    NASA Astrophysics Data System (ADS)

    Ewert, Kai; Zidovska, Alexandra; Evans, Heather M.; Safinya, Cyrus R.

    2006-03-01

    Newly designed multivalent lipids ranging in head group charge from 4+ to 16+ have been synthesized and investigated as DNA delivery vectors. These dendritic lipids (DLs) allow a controlled study of the relationship between membrane charge density (σ) and transfection efficiency (TE). An earlier report from our group described that TE of different cationic lipids of charge 1+ to 5+ follows a common, bell shaped curve as a function of membrane charge density [1]. To further probe this universal behavior, the dendritic lipids with higher valence were designed in order to reach higher values of σ. Structural studies using x-ray diffraction reveal new phases, where cylindrical micelles of DLs form a hexagonal lattice which holds together a continuous DNA network, described as HI^C [2]. The new hexagonal phase is highly transfecting in the regime where the TE of lamellar complexes follows a decrease in the bell curve. Small angle x-ray scattering studies have revealed a rich phase diagram of micelles made from DL/DOPC mixtures. Funding provided by NIH GM-59288 and NSF DMR-0503347. [1] A. Ahmad et al., J. Gene Med., 2005, V7:739-748. [2] K. Ewert et al., J. Am. Chem. Soc., (submitted).

  11. Near coincidence site lattice misorientations in monoclinic zirconia

    SciTech Connect

    Gertsman, V.Y. |; Zhilyaev, A.P. |; Szpunar, J.

    1996-12-01

    Zirconium dioxide, ZrO{sub 2}, exists in three crystalline phases: monoclinic, tetragonal, and cubic. Calculations of the coincidence site lattice (CSL) misorientations for the last two lattices and for hexagonal ones using the methods developed represent little difficulty. However, no procedure for the determination of the CSL misorientations in the monoclinic system has been reported so far. Monoclinic zirconia has the crystallographic space group P2{sub 1}/c and the following parameters of the unit cell (e.g., 5, 6): a = 5.1490 {angstrom}, b = 5.2133 {angstrom}, c = 5.3161 {angstrom}, and {beta} = 99.228{degree}. Before discussing possible CSL misorientations in zirconia, consider a simple example based on geometric considerations. In any monoclinic crystal (with any lattice parameters) the two symmetrical boundaries along the (001) and (100) planes must have highly ordered atomic structure. The misorientation of the first boundary is descried as a rotation of either 180{degree} around the [100] direction or 180{degree} around the normal to the (001) plane. The misorientation of the second boundary is 180{degree} [001] or 180{degree} around the normal to the (100) plane. It can be shown that three-dimensional CSLs will exist in both cases if (c/a)cos{beta} is a rational number. This example justifies the following approximation of the unit cell in the monoclinic zirconia: a = b = c and cos{beta} = {minus}1/6 (i.e., {beta} = 99.594{degree}). Consider the following prismatic cell in the monoclinic crystal structure: ([1 0 1], [{bar 1} 0 1], [0 1 0]). With the above approximation, this cell is orthogonal with the ratios of the squares of the edge lengths expressed as 5:7:3. Therefore, one can apply the algorithm for calculations of the CSL misorientations in orthorhombic lattices with rational ratios of squares of the lattice periods, which is based on the general vector-quaternion method of misorientation representation.

  12. Covalently functionalized hexagonal boron nitride nanosheets by nitrene addition.

    PubMed

    Sainsbury, Toby; Satti, Amro; May, Peter; O'Neill, Arlene; Nicolosi, Valeria; Gun'ko, Yurii K; Coleman, Jonathan N

    2012-08-27

    The covalent functionalization of exfoliated hexagonal boron nitride (h-BN) nanosheets by nitrene addition is described. Integration of functionalized h-BN nanosheets within a polycarbonate matrix is demonstrated and was found to afford significant increases in mechanical properties. This integration methodology was further extended by the covalent modification of the h-BN nanosheets with polymer chains of a polycarbonate analogue, and the integration of the polymer modified h-BN within the polymer matrix.

  13. Acetone sensor based on zinc oxide hexagonal tubes

    SciTech Connect

    Hastir, Anita Singh, Onkar Anand, Kanika Singh, Ravi Chand

    2014-04-24

    In this work hexagonal tubes of zinc oxide have been synthesized by co-precipitation method. For structural, morphological, elemental and optical analysis synthesized powders were characterized by using x-ray diffraction, field emission scanning microscope, EDX, UV-visible and FTIR techniques. For acetone sensing thick films of zinc oxide have been deposited on alumina substrate. The fabricated sensors exhibited maximum sensing response towards acetone vapour at an optimum operating temperature of 400°C.

  14. Lambda modes of the neutron diffusion equation in hexagonal geometry

    SciTech Connect

    Barrachina, T.; Ginestar, D.; Verdu, G.

    2006-07-01

    A nodal collocation method is proposed to compute the dominant Lambda modes of nuclear reactor core with a hexagonal geometry. This method is based on a triangular mesh and assumes that the neutronic flux can be approximated as a finite expansion in terms of Dubiner's polynomials. The method transforms the initial differential eigenvalue problem into a generalized algebraic one, from which the dominant modes of the reactor can be computed. The performance of the method is tested with two benchmark problems. (authors)

  15. Energy landscapes for shells assembled from pentagonal and hexagonal pyramids.

    PubMed

    Fejer, Szilard N; James, Tim R; Hernández-Rojas, Javier; Wales, David J

    2009-03-28

    We present new rigid body potentials that should favour efficient self-assembly of pentagonal and hexagonal pyramids into icosahedral shells over a wide range of temperature. By adding an extra repulsive site opposite the existing apex sites of the pyramids considered in a previously published model, frustrated energy landscapes are transformed into systems identified with self-assembling properties. The extra interaction may be considered analogous to a hydrophobic-hydrophilic repulsion, as in micelle formation.

  16. Optical absorption spectrum and electronic structure of multiferroic hexagonal YMnO3 compound

    NASA Astrophysics Data System (ADS)

    Lima, A. F.; Lalic, M. V.

    2017-02-01

    Optical absorption (OA) spectrum and electronic structure of the hexagonal YMnO3 compound have been investigated by employment of the first-principles calculations based on density functional theory. The calculations were performed upon the ferroelectric structure of the YMnO3, by testing various approximations of the exchange-correlation effects between the Mn d-electrons and considering two types of magnetic ordering of the Mn sub-lattice: (1) collinear anti-ferromagnetic order of the G-type and (2) non-collinear antiferromagnetic order that correspond to magnetic space group P63. The results demonstrate that satisfactory agreement between the theoretical and the experimental OA spectrum can be achieved only if both non-collinear anti-ferromagnetic order of the Mn spins and strong correlations between the Mn d-electrons are taken into account. The latter is found to be best described by effective Hubbard parameter Ueff = 2.55 eV. The principal features of the OA spectrum are interpreted in terms of calculated electronic structure. It is found that the most important, threshold 1.6 eV OA peak is generated by electron transitions from strongly hybridized occupied Mn d- and its neighboring in-plane O p-states to unoccupied Mn d-states. It is also concluded that the electronic gap (calculated as ∼1.1 eV) should be smaller than the optical one (∼1.6 eV).

  17. New crystal structures in hexagonal CuInS2 nanocrystals

    NASA Astrophysics Data System (ADS)

    Shen, Xiao; Hernández-Pagan, Emil A.; Zhou, Wu; Puzyrev, Yevgeniy S.; Idrobo, Juan C.; MacDonald, Janet E.; Pennycook, Stephen J.; Pantelides, Sokrates T.

    2013-03-01

    CuInS2 is one of the best candidate materials for solar energy harvesting. Its nanocrystals with a hexagonal lattice structure that is different from the bulk chalcopyrite phase have been synthesized by many groups. The structure of these CuInS2 nanocrystals has been previously identified as the wurtzite structure in which the copper and indium atoms randomly occupy the cation sites. Using first-principles total energy and electronic structure calculations based on density functional theory, UV-vis absorption spectroscopy, X-ray diffraction, and atomic resolution Z-contrast images obtained in an aberration-corrected scanning transmission electron microscope, we show that CuInS2 nanocrystals do not form random wurtzite structure. Instead, the CuInS2 nanocrystals consist of several wurtzite- related crystal structures with ordered cation sublattices, some of which are reported for the first time here. This work is supported by the NSF TN-SCORE (JEM), by NSF (WZ), by ORNL's Shared Research Equipment User Program (JCI) sponsored by DOE BES, by DOE BES Materials Sciences and Engineering Division (SJP, STP), and used resources of the National Energy Research Scientific Computing Center, supported by the DOE Office of Science under Contract No. DE-AC02-05CH11231.

  18. An energy stable, hexagonal finite difference scheme for the 2D phase field crystal amplitude equations

    NASA Astrophysics Data System (ADS)

    Guan, Zhen; Heinonen, Vili; Lowengrub, John; Wang, Cheng; Wise, Steven M.

    2016-09-01

    In this paper we construct an energy stable finite difference scheme for the amplitude expansion equations for the two-dimensional phase field crystal (PFC) model. The equations are formulated in a periodic hexagonal domain with respect to the reciprocal lattice vectors to achieve a provably unconditionally energy stable and solvable scheme. To our knowledge, this is the first such energy stable scheme for the PFC amplitude equations. The convexity of each part in the amplitude equations is analyzed, in both the semi-discrete and fully-discrete cases. Energy stability is based on a careful convexity analysis for the energy (in both the spatially continuous and discrete cases). As a result, unique solvability and unconditional energy stability are available for the resulting scheme. Moreover, we show that the scheme is point-wise stable for any time and space step sizes. An efficient multigrid solver is devised to solve the scheme, and a few numerical experiments are presented, including grain rotation and shrinkage and grain growth studies, as examples of the strength and robustness of the proposed scheme and solver.

  19. Optic phonons and anisotropic thermal conductivity in hexagonal Ge2Sb2Te5

    PubMed Central

    Mukhopadhyay, Saikat; Lindsay, Lucas; Singh, David J.

    2016-01-01

    The lattice thermal conductivity (κ) of hexagonal Ge2Sb2Te5 (h-GST) is studied via direct first-principles calculations. We find significant intrinsic anisotropy (κa/κc~2) of κ in bulk h-GST, with the dominant contribution to κ from optic phonons, ~75%. This is extremely unusual as the acoustic phonon modes are the majority heat carriers in typical semiconductors and insulators. The anisotropy derives from varying bonding along different crystal directions, specifically from weak interlayer bonding along the c-axis, which gives anisotropic phonon dispersions. The phonon spectrum of h-GST has very dispersive optic branches with higher group velocities along the a-axis as compared to flat optic bands along the c-axis. The large optic mode contributions to the thermal conductivity in low-κ h-GST is unusual, and development of fundamental physical understanding of these contributions may be critical to better understanding of thermal conduction in other complex layered materials. PMID:27848985

  20. Scanning tunnelling microscopy and spectroscopy of ultra-flat graphene on hexagonal boron nitride

    NASA Astrophysics Data System (ADS)

    Xue, Jiamin; Sanchez-Yamagishi, Javier; Bulmash, Danny; Jacquod, Philippe; Deshpande, Aparna; Watanabe, K.; Taniguchi, T.; Jarillo-Herrero, Pablo; Leroy, Brian J.

    2011-04-01

    Graphene has demonstrated great promise for future electronics technology as well as fundamental physics applications because of its linear energy-momentum dispersion relations which cross at the Dirac point. However, accessing the physics of the low-density region at the Dirac point has been difficult because of disorder that leaves the graphene with local microscopic electron and hole puddles. Efforts have been made to reduce the disorder by suspending graphene, leading to fabrication challenges and delicate devices which make local spectroscopic measurements difficult. Recently, it has been shown that placing graphene on hexagonal boron nitride (hBN) yields improved device performance. Here we use scanning tunnelling microscopy to show that graphene conforms to hBN, as evidenced by the presence of Moiré patterns. However, contrary to predictions, this conformation does not lead to a sizeable band gap because of the misalignment of the lattices. Moreover, local spectroscopy measurements demonstrate that the electron-hole charge fluctuations are reduced by two orders of magnitude as compared with those on silicon oxide. This leads to charge fluctuations that are as small as in suspended graphene, opening up Dirac point physics to more diverse experiments.

  1. Scanning tunnelling microscopy and spectroscopy of ultra-flat graphene on hexagonal boron nitride.

    PubMed

    Xue, Jiamin; Sanchez-Yamagishi, Javier; Bulmash, Danny; Jacquod, Philippe; Deshpande, Aparna; Watanabe, K; Taniguchi, T; Jarillo-Herrero, Pablo; LeRoy, Brian J

    2011-04-01

    Graphene has demonstrated great promise for future electronics technology as well as fundamental physics applications because of its linear energy-momentum dispersion relations which cross at the Dirac point. However, accessing the physics of the low-density region at the Dirac point has been difficult because of disorder that leaves the graphene with local microscopic electron and hole puddles. Efforts have been made to reduce the disorder by suspending graphene, leading to fabrication challenges and delicate devices which make local spectroscopic measurements difficult. Recently, it has been shown that placing graphene on hexagonal boron nitride (hBN) yields improved device performance. Here we use scanning tunnelling microscopy to show that graphene conforms to hBN, as evidenced by the presence of Moiré patterns. However, contrary to predictions, this conformation does not lead to a sizeable band gap because of the misalignment of the lattices. Moreover, local spectroscopy measurements demonstrate that the electron-hole charge fluctuations are reduced by two orders of magnitude as compared with those on silicon oxide. This leads to charge fluctuations that are as small as in suspended graphene, opening up Dirac point physics to more diverse experiments.

  2. Modulating memristive performance of hexagonal WO3 nanowire by water-oxidized hydrogen ion implantation

    PubMed Central

    Zhou, Yong; Peng, Yuehua; Yin, Yanling; Zhou, Fang; Liu, Chang; Ling, Jing; Lei, Le; Zhou, Weichang; Tang, Dongsheng

    2016-01-01

    In a two-terminal Au/hexagonal WO3 nanowire/Au device, ions drifting or carriers self-trapping under external electrical field will modulate the Schottky barriers between the nanowire and electrodes, and then result in memristive effect. When there are water molecules adsorbed on the surface of WO3 nanowire, hydrogen ions will generate near the positively-charged electrode and transport in the condensed water film, which will enhance the memristive performance characterized by analogic resistive switching remarkably. When the bias voltage is swept repeatedly under high relative humidity level, hydrogen ions will accumulate on the surface and then implant into the lattice of the WO3 nanowire, which leads to a transition from semiconducting WO3 nanowire to metallic HxWO3 nanowire. This insulator-metal transition can be realized more easily after enough electron-hole pairs being excited by laser illumination. The concentration of hydrogen ions in HxWO3 nanowire will decrease when the device is exposed to oxygen atmosphere or the bias voltage is swept in atmosphere with low relative humidity. By modulating the concentration of hydrogen ions, conductive hydrogen tungsten bronze filament might form or rupture near electrodes when the polarity of applied voltage changes, which will endow the device with memristive performance characterized by digital resistive switching. PMID:27600368

  3. Kitaev anisotropy induces mesoscopic Z2 vortex crystals in frustrated hexagonal antiferromagnets

    NASA Astrophysics Data System (ADS)

    Rousochatzakis, Ioannis; Rössler, Ulrich K.; van den Brink, Jeroen; Daghofer, Maria

    2016-03-01

    The triangular-lattice Heisenberg antiferromagnet (HAF) is known to carry topological Z2 vortex excitations which form a gas at finite temperatures. Here we show that the spin-orbit interaction, introduced via a Kitaev term in the exchange Hamiltonian, condenses these vortices into a triangular Z2 vortex crystal at zero temperature. The cores of the Z2 vortices show abrupt, soliton-like magnetization modulations and arise by a special intertwining of three honeycomb superstructures of ferromagnetic domains, one for each of the three sublattices of the 120∘ state of the pure HAF. This is an example of a nucleation transition, analogous to the spontaneous formation of magnetic domains, Abrikosov vortices in type-II superconductors, blue phases in cholesteric liquid crystals, and skyrmions in chiral helimagnets. As the mechanism relies on the interplay of geometric frustration and spin-orbital anisotropies, such vortex mesophases can materialize as a ground state property in spin-orbit coupled correlated systems with nearly hexagonal topology, as in triangular or strongly frustrated honeycomb iridates.

  4. Hexagonal ice stability and growth in the presence of glyoxal and secondary organic aerosols.

    PubMed

    Daskalakis, Vangelis; Hadjicharalambous, Marios

    2014-09-07

    The presence of ice dominates the microphysics of formation of high altitude cirrus and polar stratospheric clouds, as well as the maturity of thunderstorms. We report on the hexagonal (1h) ice stability and growth in binary as well as multi-compound aerosols in atmospherically relevant conformations. The ubiquitous atmospheric trace gas glyoxal along with secondary organic aerosol (SOA) also in the presence of CO2 interacts with large ice 1h crystals of 1300-2000 water molecules. The crystals are subjected to phase transitions under superheating and supercooling conditions by Molecular Dynamics (MD) simulations. Density Functional Theory (DFT) based geometry optimization and vibrational frequency analysis are also employed for a smaller ice 1h cell of 12 water molecules. The interaction of the latter with each organic molecule reveals the extent of the mechanical stress exerted on the ordered ice structure. Full hydration of glyoxal promotes ice 1h stability and growth in wet aerosols, while partial hydration or full oxidation exerts a destabilizing effect on the ice 1h lattice. This behavior is associated with the ability of each organic phase to match the order of the ice 1h crystal. We propose that aqueous chemistry in wet aerosols may also have a strong effect on the microphysics of cloud formation.

  5. Modulating memristive performance of hexagonal WO3 nanowire by water-oxidized hydrogen ion implantation.

    PubMed

    Zhou, Yong; Peng, Yuehua; Yin, Yanling; Zhou, Fang; Liu, Chang; Ling, Jing; Lei, Le; Zhou, Weichang; Tang, Dongsheng

    2016-09-07

    In a two-terminal Au/hexagonal WO3 nanowire/Au device, ions drifting or carriers self-trapping under external electrical field will modulate the Schottky barriers between the nanowire and electrodes, and then result in memristive effect. When there are water molecules adsorbed on the surface of WO3 nanowire, hydrogen ions will generate near the positively-charged electrode and transport in the condensed water film, which will enhance the memristive performance characterized by analogic resistive switching remarkably. When the bias voltage is swept repeatedly under high relative humidity level, hydrogen ions will accumulate on the surface and then implant into the lattice of the WO3 nanowire, which leads to a transition from semiconducting WO3 nanowire to metallic HxWO3 nanowire. This insulator-metal transition can be realized more easily after enough electron-hole pairs being excited by laser illumination. The concentration of hydrogen ions in HxWO3 nanowire will decrease when the device is exposed to oxygen atmosphere or the bias voltage is swept in atmosphere with low relative humidity. By modulating the concentration of hydrogen ions, conductive hydrogen tungsten bronze filament might form or rupture near electrodes when the polarity of applied voltage changes, which will endow the device with memristive performance characterized by digital resistive switching.

  6. Modulating memristive performance of hexagonal WO3 nanowire by water-oxidized hydrogen ion implantation

    NASA Astrophysics Data System (ADS)

    Zhou, Yong; Peng, Yuehua; Yin, Yanling; Zhou, Fang; Liu, Chang; Ling, Jing; Lei, Le; Zhou, Weichang; Tang, Dongsheng

    2016-09-01

    In a two-terminal Au/hexagonal WO3 nanowire/Au device, ions drifting or carriers self-trapping under external electrical field will modulate the Schottky barriers between the nanowire and electrodes, and then result in memristive effect. When there are water molecules adsorbed on the surface of WO3 nanowire, hydrogen ions will generate near the positively-charged electrode and transport in the condensed water film, which will enhance the memristive performance characterized by analogic resistive switching remarkably. When the bias voltage is swept repeatedly under high relative humidity level, hydrogen ions will accumulate on the surface and then implant into the lattice of the WO3 nanowire, which leads to a transition from semiconducting WO3 nanowire to metallic HxWO3 nanowire. This insulator-metal transition can be realized more easily after enough electron-hole pairs being excited by laser illumination. The concentration of hydrogen ions in HxWO3 nanowire will decrease when the device is exposed to oxygen atmosphere or the bias voltage is swept in atmosphere with low relative humidity. By modulating the concentration of hydrogen ions, conductive hydrogen tungsten bronze filament might form or rupture near electrodes when the polarity of applied voltage changes, which will endow the device with memristive performance characterized by digital resistive switching.

  7. Optic phonons and anisotropic thermal conductivity in hexagonal Ge2Sb2Te5

    NASA Astrophysics Data System (ADS)

    Mukhopadhyay, Saikat; Lindsay, Lucas; Singh, David J.

    2016-11-01

    The lattice thermal conductivity (κ) of hexagonal Ge2Sb2Te5 (h-GST) is studied via direct first-principles calculations. We find significant intrinsic anisotropy (κa/κc~2) of κ in bulk h-GST, with the dominant contribution to κ from optic phonons, ~75%. This is extremely unusual as the acoustic phonon modes are the majority heat carriers in typical semiconductors and insulators. The anisotropy derives from varying bonding along different crystal directions, specifically from weak interlayer bonding along the c-axis, which gives anisotropic phonon dispersions. The phonon spectrum of h-GST has very dispersive optic branches with higher group velocities along the a-axis as compared to flat optic bands along the c-axis. The large optic mode contributions to the thermal conductivity in low-κ h-GST is unusual, and development of fundamental physical understanding of these contributions may be critical to better understanding of thermal conduction in other complex layered materials.

  8. Optic phonons and anisotropic thermal conductivity in hexagonal Ge2Sb2Te5

    DOE PAGES

    Mukhopadhyay, Saikat; Lindsay, Lucas R.; Singh, David

    2016-11-16

    The lattice thermal conductivity ($κ$) of hexagonal Ge2Sb2Tesub>5 (h-GST) is studied via direct first-principles calculations. We find significant intrinsic anisotropy of ( $κ$a/$κ$c~2) of $κ$ in bulk h-GST along different transport directions. The dominant contribution to$κ$ is from optic phonons, ~75%. This is extremely unusual as the acoustic phonon modes carry most of the heat in typical semiconductors and insulators with small unit cells. Very recently, Lee et. al. observed anisotropic in GST thin films and attributed this to thermal resistance of amorphous regions near grain boundaries. However, our results suggest an additional strong intrinsic anisotropy for the pure hexagonalmore » phase. This derives from bonding anisotropy along different crystal directions, specifically from weak interlayer coupling, which gives anisotropic phonon dispersions. The phonon spectrum of h-GST has very dispersive optic branches with higher group velocities along the a-axis as compared to flat optic bands along the c-axis. The importance of optic mode contributions for the thermal conductivity in low-$κ$ h-GST is unusual, and development of fundamental physical understanding of these contributions may be critical to better understanding of thermal conduction in other complex layered materials.« less

  9. First-principles study of nanotubes within the tetragonal, hexagonal and dodecagonal cycle structures

    NASA Astrophysics Data System (ADS)

    BabaeiPour, M.; Safari, E. Keshavarz; Shokri, A. A.

    2017-02-01

    A systematic study has been done on the structural and electronic properties of carbon, boron nitride and aluminum nitride nanotubes with structure consisting of periodically distributed tetragonal (T ≡A2X2), hexagonal (H ≡A3X3) and dodecagonal (D ≡A6X6) (AX=C2, BN, AlN) cycles. The method has been performed using first-principles calculations based on density functional theory (DFT). The optimized lattice parameters, density of state (DOS) curves and band structure of THD-NTs are obtained for (3, 0) and (0, 2) types. Our calculation results indicate that carbon nanotubes of these types (THD-CNTs) behave as a metallic, but the boron nitride nanotubes (THD-BNNTs) (with a band gap of around 4 eV) as well as aluminum nitride nanotubes (THD-AlNNTs) (with a band gap of around 2.6 eV) behave as an semiconductor. The inequality in number of atoms in different directions is affected on structures and diameters of nanotubes and their walls curvature.

  10. Dispersion engineering of slow light in hexagonal ring hole photonic crystal waveguide

    NASA Astrophysics Data System (ADS)

    Wu, Min; Li, Changhong; Li, Liucun; Wang, Yumeng

    2016-10-01

    We adopt hexagonal optofluidic ring scatterers to built two-dimensional photonic crystal waveguide (PCW) with triangular lattice. By studying slow light effects of varieties of optical optofluidic rings, the thickness of optofluidic ring in X and Z direction, and the moving distance of the first row of scatterers near central waveguide, some relatively optimism results have been founded. In addition, in the process of research, we adopt PWE method to simulation calculation. When the thickness of optofluidic ring changes, the optimization results which ng equals 47.2120, bandwidth Δλ is 28.5nm and the group velocity dispersion β2 is 43.3418 ps2/mm. When the moving distance changes, the optimization results we could get that ng equals 15.6569, Δλ is 92.9nm and β2 is 7.8202 ps2/mm. This wideband and low dispersion slow light can be used for storage capacity with certain requirements of the optical buffer, optical sensors, etc.

  11. Temperature Dependence of Wavelength Selectable Zero-Phonon Emission from Single Defects in Hexagonal Boron Nitride.

    PubMed

    Jungwirth, Nicholas R; Calderon, Brian; Ji, Yanxin; Spencer, Michael G; Flatté, Michael E; Fuchs, Gregory D

    2016-10-12

    We investigate the distribution and temperature-dependent optical properties of sharp, zero-phonon emission from defect-based single photon sources in multilayer hexagonal boron nitride (h-BN) flakes. We observe sharp emission lines from optically active defects distributed across an energy range that exceeds 500 meV. Spectrally resolved photon-correlation measurements verify single photon emission, even when multiple emission lines are simultaneously excited within the same h-BN flake. We also present a detailed study of the temperature-dependent line width, spectral energy shift, and intensity for two different zero-phonon lines centered at 575 and 682 nm, which reveals a nearly identical temperature dependence despite a large difference in transition energy. Our temperature-dependent results are well described by a lattice vibration model that considers piezoelectric coupling to in-plane phonons. Finally, polarization spectroscopy measurements suggest that whereas the 575 nm emission line is directly excited by 532 nm excitation, the 682 nm line is excited indirectly.

  12. Transitional liquid crystalline phases between the hexagonal and lamellar phases in ternary cesium N-tetradecanoate-water-additive mixtures

    SciTech Connect

    Blackburn, J.C.; Kilpatrick, P.K. )

    1993-04-01

    The effects of added salt (CsOH, CsCl), long-chain carboxylic acid, and long-chain alcohol on the lyotropic liquid crystalline phase behavior in the cesium n-tetradecanoate (CsTD)-water system is reported. The transitional region between the hexagonal (H) and lamellar (L) phases was the compositional range of focus. Three transitional phases were observed: (i) the ribbon (R) phase, a biaxial phase consisting of cylinders of ellipsoidal cross section; (ii) the viscous isotropic (VI) phase, an isotropic phase thought to consist of interconnected rods on an Ia3d lattice; and (iii) the intermediate (Int) phase, a uniaxial anisotropic phase thought to consist of interconnected rods on a planar lattice. The effect of the additives was to decrease the interfacial curvature of the surfactant head group layer by varying head group repulsion and by varying the surfactant tail volume relative to the surfactant head group area. These changes resulted in formation of transitional phases seeming to possess curvature between that of the cylindrical H phase and the planar L phase. The ionic repulsion between carboxylate head groups was reduced by the addition of CsOH or CsCl, and resulted in destabilization of the VI phase and the formation of the anisotropic Int phase. With the addition of cosurfactants, n-tetradecanoic acid (TDA) and 1-tetradecanol (TDOH), no Int phase was observed. With 7 wt% added TDA the R phase was stabilized up to temperatures of 336 K, above the 330 K temperature limit in the binary CsTD-D[sub 2]O system. In all four systems, sufficient additive (5-10 wt%) resulted in a transition to the L phase, which was stable over a large portion of the compositional range. In order of apparently decreasing mean curvature, the phase sequence is: hexagonal, ribbon, viscous isotropic, intermediate, and lamellar.

  13. Femtosecond laser direct writing of monocrystalline hexagonal silver prisms

    SciTech Connect

    Vora, Kevin; Kang, SeungYeon; Moebius, Michael; Mazur, Eric

    2014-10-06

    Bottom-up growth methods and top-down patterning techniques are both used to fabricate metal nanostructures, each with a distinct advantage: One creates crystalline structures and the other offers precise positioning. Here, we present a technique that localizes the growth of metal crystals to the focal volume of a laser beam, combining advantages from both approaches. We report the fabrication of silver nanoprisms—hexagonal nanoscale silver crystals—through irradiation with focused femtosecond laser pulses. The growth of these nanoprisms is due to a nonlinear optical interaction between femtosecond laser pulses and a polyvinylpyrrolidone film doped with silver nitrate. The hexagonal nanoprisms have bases hundreds of nanometers in size and the crystal growth occurs over exposure times of less than 1 ms (8 orders of magnitude faster than traditional chemical techniques). Electron backscatter diffraction analysis shows that the hexagonal nanoprisms are monocrystalline. The fabrication method combines advantages from both wet chemistry and femtosecond laser direct-writing to grow silver crystals in targeted locations. The results presented in this letter offer an approach to directly positioning and growing silver crystals on a substrate, which can be used for plasmonic devices.

  14. Discovery of Superconductivity in Hard Hexagonal ε-NbN.

    PubMed

    Zou, Yongtao; Qi, Xintong; Zhang, Cheng; Ma, Shuailing; Zhang, Wei; Li, Ying; Chen, Ting; Wang, Xuebing; Chen, Zhiqiang; Welch, David; Zhu, Pinwen; Liu, Bingbing; Li, Qiang; Cui, Tian; Li, Baosheng

    2016-02-29

    Since the discovery of superconductivity in boron-doped diamond with a critical temperature (TC) near 4 K, great interest has been attracted in hard superconductors such as transition-metal nitrides and carbides. Here we report the new discovery of superconductivity in polycrystalline hexagonal ε-NbN synthesized at high pressure and high temperature. Direct magnetization and electrical resistivity measurements demonstrate that the superconductivity in bulk polycrystalline hexagonal ε-NbN is below ∼11.6 K, which is significantly higher than that for boron-doped diamond. The nature of superconductivity in hexagonal ε-NbN and the physical mechanism for the relatively lower TC have been addressed by the weaker bonding in the Nb-N network, the co-planarity of Nb-N layer as well as its relatively weaker electron-phonon coupling, as compared with the cubic δ-NbN counterpart. Moreover, the newly discovered ε-NbN superconductor remains stable at pressures up to ∼20 GPa and is significantly harder than cubic δ-NbN; it is as hard as sapphire, ultra-incompressible and has a high shear rigidity of 201 GPa to rival hard/superhard material γ-B (∼227 GPa). This exploration opens a new class of highly desirable materials combining the outstanding mechanical/elastic properties with superconductivity, which may be particularly attractive for its technological and engineering applications in extreme environments.

  15. Femtosecond laser direct writing of monocrystalline hexagonal silver prisms

    NASA Astrophysics Data System (ADS)

    Vora, Kevin; Kang, SeungYeon; Moebius, Michael; Mazur, Eric

    2014-10-01

    Bottom-up growth methods and top-down patterning techniques are both used to fabricate metal nanostructures, each with a distinct advantage: One creates crystalline structures and the other offers precise positioning. Here, we present a technique that localizes the growth of metal crystals to the focal volume of a laser beam, combining advantages from both approaches. We report the fabrication of silver nanoprisms—hexagonal nanoscale silver crystals—through irradiation with focused femtosecond laser pulses. The growth of these nanoprisms is due to a nonlinear optical interaction between femtosecond laser pulses and a polyvinylpyrrolidone film doped with silver nitrate. The hexagonal nanoprisms have bases hundreds of nanometers in size and the crystal growth occurs over exposure times of less than 1 ms (8 orders of magnitude faster than traditional chemical techniques). Electron backscatter diffraction analysis shows that the hexagonal nanoprisms are monocrystalline. The fabrication method combines advantages from both wet chemistry and femtosecond laser direct-writing to grow silver crystals in targeted locations. The results presented in this letter offer an approach to directly positioning and growing silver crystals on a substrate, which can be used for plasmonic devices.

  16. Hexagonal OsB2: Sintering, microstructure and mechanical properties

    DOE PAGES

    Xie, Zhilin; Lugovy, Mykola; Orlovskaya, Nina; ...

    2015-02-07

    In this study, the metastable high pressure ReB2-type hexagonal OsB2 bulk ceramics was produced by spark plasma sintering. The phase composition, microstructure, and mechanical behavior of the sintered OsB2 were studied by X-ray diffraction, optical microscopy, TEM, SEM, EDS, and nanoindentation. The produced ceramics was rather porous and contained a mixture of hexagonal (~80 wt.%) and orthorhombic (~20 wt.%) phases as identified by X-ray diffraction and EBSD analysis. Two boron-rich phases, which do not contain Os, were also identified by TEM and SEM/EDS analysis. Nanoindentation measurements yielded a hardness of 31 ± 9 GPa and Young’s modulus of 574 ±more » 112 GPa, indicating that the material is rather hard and very stiff; but, it is very prone to crack formation and propagation, which is indicative of a very brittle nature of this material. Improvements in the sintering regime are required in order to produce dense, homogeneous and single phase hexagonal OsB2 bulk ceramics.« less

  17. Cubic and Hexagonal Liquid Crystals as Drug Delivery Systems

    PubMed Central

    Chen, Yulin; Ma, Ping; Gui, Shuangying

    2014-01-01

    Lipids have been widely used as main constituents in various drug delivery systems, such as liposomes, solid lipid nanoparticles, nanostructured lipid carriers, and lipid-based lyotropic liquid crystals. Among them, lipid-based lyotropic liquid crystals have highly ordered, thermodynamically stable internal nanostructure, thereby offering the potential as a sustained drug release matrix. The intricate nanostructures of the cubic phase and hexagonal phase have been shown to provide diffusion controlled release of active pharmaceutical ingredients with a wide range of molecular weights and polarities. In addition, the biodegradable and biocompatible nature of lipids demonstrates the minimum toxicity and thus they are used for various routes of administration. Therefore, the research on lipid-based lyotropic liquid crystalline phases has attracted a lot of attention in recent years. This review will provide an overview of the lipids used to prepare cubic phase and hexagonal phase at physiological temperature, as well as the influencing factors on the phase transition of liquid crystals. In particular, the most current research progresses on cubic and hexagonal phases as drug delivery systems will be discussed. PMID:24995330

  18. Design of a solar concentrator with hexagonal facets

    NASA Astrophysics Data System (ADS)

    Herrera Vázquez, Joel; Vázquez y Montiel, Sergio

    2007-09-01

    In this work we present the optical design of a solar concentrator for an High-Flux solar furnace of a solar laboratory, these concentrator is compound for an aspheric mirror surface sectioned in 121 hexagonal facets to simplify the construction process, its total diameter is 6.6 m and a focal length is 3.68 m, also was developed the corresponding algorithm to determine the correct position and orientation of each hexagonal section that compound the arrangement. We present the results of the focused energy of this configuration and we propose a modification on the original position of the mirrors for optimizing the focusing of energy by the sun furnace. These modifications produces an increment on the energy focused on a small area in a remarkable way similar to used a parabolic mirror. The algorithm before mentioned was programmed in MathCAD and it calculates the modification of the original position of each hexagonal mirror giving us a file that ZEMAX can read. This file contains the information of each 121 mirrors from the arrangement and also the correct form, position and direction, simplifying the traditional input process one by one.

  19. Discovery of superconductivity in hard hexagonal ε-NbN

    DOE PAGES

    Zou, Yongtao; Li, Qiang; Qi, Xintong; ...

    2016-02-29

    Since the discovery of superconductivity in boron-doped diamond with a critical temperature (TC) near 4 K, great interest has been attracted in hard superconductors such as transition-metal nitrides and carbides. Here we report the new discovery of superconductivity in polycrystalline hexagonal ε-NbN synthesized at high pressure and high temperature. Direct magnetization and electrical resistivity measurements demonstrate that the superconductivity in bulk polycrystalline hexagonal ε-NbN is below ~11.6 K, which is significantly higher than that for boron-doped diamond. The nature of superconductivity in hexagonal ε-NbN and the physical mechanism for the relatively lower TC have been addressed by the weaker bondingmore » in the Nb-N network, the co-planarity of Nb-N layer as well as its relatively weaker electron-phonon coupling, as compared with the cubic δ-NbN counterpart. Moreover, the newly discovered ε-NbN superconductor remains stable at pressures up to ~20 GPa and is significantly harder than cubic δ-NbN; it is as hard as sapphire, ultra-incompressible and has a high shear rigidity of 201 GPa to rival hard/superhard material γ-B (~227 GPa). Furthermore, this exploration opens a new class of highly desirable materials combining the outstanding mechanical/elastic properties with superconductivity, which may be particularly attractive for its technological and engineering applications in extreme environments.« less

  20. Discovery of superconductivity in hard hexagonal ε-NbN

    SciTech Connect

    Zou, Yongtao; Li, Qiang; Qi, Xintong; Zhang, Cheng; Ma, Shuailing; Zhang, Wei; Li, Ying; Chen, Ting; Wang, Xuebing; Chen, Zhiqiang; Welch, David; Pinwen Zhu; Cui, Tian; Li, Bingbing; Li, Baosheng

    2016-02-29

    Since the discovery of superconductivity in boron-doped diamond with a critical temperature (TC) near 4 K, great interest has been attracted in hard superconductors such as transition-metal nitrides and carbides. Here we report the new discovery of superconductivity in polycrystalline hexagonal ε-NbN synthesized at high pressure and high temperature. Direct magnetization and electrical resistivity measurements demonstrate that the superconductivity in bulk polycrystalline hexagonal ε-NbN is below ~11.6 K, which is significantly higher than that for boron-doped diamond. The nature of superconductivity in hexagonal ε-NbN and the physical mechanism for the relatively lower TC have been addressed by the weaker bonding in the Nb-N network, the co-planarity of Nb-N layer as well as its relatively weaker electron-phonon coupling, as compared with the cubic δ-NbN counterpart. Moreover, the newly discovered ε-NbN superconductor remains stable at pressures up to ~20 GPa and is significantly harder than cubic δ-NbN; it is as hard as sapphire, ultra-incompressible and has a high shear rigidity of 201 GPa to rival hard/superhard material γ-B (~227 GPa). Furthermore, this exploration opens a new class of highly desirable materials combining the outstanding mechanical/elastic properties with superconductivity, which may be particularly attractive for its technological and engineering applications in extreme environments.

  1. Discovery of Superconductivity in Hard Hexagonal ε-NbN

    PubMed Central

    Zou, Yongtao; Qi, Xintong; Zhang, Cheng; Ma, Shuailing; Zhang, Wei; Li, Ying; Chen, Ting; Wang, Xuebing; Chen, Zhiqiang; Welch, David; Zhu, Pinwen; Liu, Bingbing; Li, Qiang; Cui, Tian; Li, Baosheng

    2016-01-01

    Since the discovery of superconductivity in boron-doped diamond with a critical temperature (TC) near 4 K, great interest has been attracted in hard superconductors such as transition-metal nitrides and carbides. Here we report the new discovery of superconductivity in polycrystalline hexagonal ε-NbN synthesized at high pressure and high temperature. Direct magnetization and electrical resistivity measurements demonstrate that the superconductivity in bulk polycrystalline hexagonal ε-NbN is below ∼11.6 K, which is significantly higher than that for boron-doped diamond. The nature of superconductivity in hexagonal ε-NbN and the physical mechanism for the relatively lower TC have been addressed by the weaker bonding in the Nb-N network, the co-planarity of Nb-N layer as well as its relatively weaker electron-phonon coupling, as compared with the cubic δ-NbN counterpart. Moreover, the newly discovered ε-NbN superconductor remains stable at pressures up to ∼20 GPa and is significantly harder than cubic δ-NbN; it is as hard as sapphire, ultra-incompressible and has a high shear rigidity of 201 GPa to rival hard/superhard material γ-B (∼227 GPa). This exploration opens a new class of highly desirable materials combining the outstanding mechanical/elastic properties with superconductivity, which may be particularly attractive for its technological and engineering applications in extreme environments. PMID:26923318

  2. Discovery of Superconductivity in Hard Hexagonal ε-NbN

    NASA Astrophysics Data System (ADS)

    Zou, Yongtao; Qi, Xintong; Zhang, Cheng; Ma, Shuailing; Zhang, Wei; Li, Ying; Chen, Ting; Wang, Xuebing; Chen, Zhiqiang; Welch, David; Zhu, Pinwen; Liu, Bingbing; Li, Qiang; Cui, Tian; Li, Baosheng

    2016-02-01

    Since the discovery of superconductivity in boron-doped diamond with a critical temperature (TC) near 4 K, great interest has been attracted in hard superconductors such as transition-metal nitrides and carbides. Here we report the new discovery of superconductivity in polycrystalline hexagonal ε-NbN synthesized at high pressure and high temperature. Direct magnetization and electrical resistivity measurements demonstrate that the superconductivity in bulk polycrystalline hexagonal ε-NbN is below ∼11.6 K, which is significantly higher than that for boron-doped diamond. The nature of superconductivity in hexagonal ε-NbN and the physical mechanism for the relatively lower TC have been addressed by the weaker bonding in the Nb-N network, the co-planarity of Nb-N layer as well as its relatively weaker electron-phonon coupling, as compared with the cubic δ-NbN counterpart. Moreover, the newly discovered ε-NbN superconductor remains stable at pressures up to ∼20 GPa and is significantly harder than cubic δ-NbN it is as hard as sapphire, ultra-incompressible and has a high shear rigidity of 201 GPa to rival hard/superhard material γ-B (∼227 GPa). This exploration opens a new class of highly desirable materials combining the outstanding mechanical/elastic properties with superconductivity, which may be particularly attractive for its technological and engineering applications in extreme environments.

  3. Influence of lattice defects on the ferromagnetic resonance behaviour of 2D magnonic crystals

    PubMed Central

    Manzin, Alessandra; Barrera, Gabriele; Celegato, Federica; Coïsson, Marco; Tiberto, Paola

    2016-01-01

    This paper studies, from a modelling point of view, the influence of randomly distributed lattice defects (non-patterned areas and variable hole size) on the ferromagnetic resonance behaviour and spin wave mode profiles of 2D magnonic crystals based on Ni80Fe20 antidot arrays with hexagonal lattice. A reference sample is first defined via the comparison of experimental and simulated hysteresis loops and magnetoresistive curves of patterned films, prepared by self-assembly of polystyrene nanospheres. Second, a parametric analysis of the dynamic response is performed, investigating how edge, quasi-uniform and localized modes are affected by alterations of the lattice geometry and bias field amplitude. Finally, some results about the possible use of magnetic antidot arrays in frequency-based sensors for magnetic bead detection are presented, highlighting the need for an accurate control of microstructural features. PMID:26911336

  4. Large area stress distribution in crystalline materials calculated from lattice deformation identified by electron backscatter diffraction.

    PubMed

    Shao, Yongliang; Zhang, Lei; Hao, Xiaopeng; Wu, Yongzhong; Dai, Yuanbin; Tian, Yuan; Huo, Qin

    2014-08-05

    We report a method to obtain the stress of crystalline materials directly from lattice deformation by Hooke's law. The lattice deformation was calculated using the crystallographic orientations obtained from electron backscatter diffraction (EBSD) technology. The stress distribution over a large area was obtained efficiently and accurately using this method. Wurtzite structure gallium nitride (GaN) crystal was used as the example of a hexagonal crystal system. With this method, the stress distribution of a GaN crystal was obtained. Raman spectroscopy was used to verify the stress distribution. The cause of the stress distribution found in the GaN crystal was discussed from theoretical analysis and EBSD data. Other properties related to lattice deformation, such as piezoelectricity, can also be analyzed by this novel approach based on EBSD data.

  5. Phase diagram of interacting spinless fermions on the honeycomb lattice.

    PubMed

    Capponi, Sylvain

    2017-02-01

    Fermions hopping on a hexagonal lattice represent one of the most active research fields in condensed matter since the discovery of graphene in 2004 and its numerous applications. Another exciting aspect of the interplay between geometry and quantum mechanical effects is given by the Haldane model (Haldane 1988 Phys. Rev. Lett. 61 2015), where spinless fermions experiencing a certain flux pattern on the honeycomb lattice leads to the stabilization of a topological phase of matter, distinct from a Mott insulator and nowadays dubbed Chern insulator. In this context, it is crucial to understand the role of interactions and this review will describe recent results that have been obtained for a minimal model, namely spinless fermions with nearest and next-nearest neighbour density-density interactions on the honeycomb lattice at half-filling. Topics addressed include an introduction of the minimal model and a discussion of the possible instabilities of the Dirac semimetal, a presentation of various theoretical and numerical approaches, and a summary of the results with a particular emphasis on the stability or not of some exotic quantum phases such as charge ordered ones (similar to Wigner crystals) and spontaneous Chern insulator phases.

  6. Phase diagram of interacting spinless fermions on the honeycomb lattice

    NASA Astrophysics Data System (ADS)

    Capponi, Sylvain

    2017-02-01

    Fermions hopping on a hexagonal lattice represent one of the most active research fields in condensed matter since the discovery of graphene in 2004 and its numerous applications. Another exciting aspect of the interplay between geometry and quantum mechanical effects is given by the Haldane model (Haldane 1988 Phys. Rev. Lett. 61 2015), where spinless fermions experiencing a certain flux pattern on the honeycomb lattice leads to the stabilization of a topological phase of matter, distinct from a Mott insulator and nowadays dubbed Chern insulator. In this context, it is crucial to understand the role of interactions and this review will describe recent results that have been obtained for a minimal model, namely spinless fermions with nearest and next-nearest neighbour density-density interactions on the honeycomb lattice at half-filling. Topics addressed include an introduction of the minimal model and a discussion of the possible instabilities of the Dirac semimetal, a presentation of various theoretical and numerical approaches, and a summary of the results with a particular emphasis on the stability or not of some exotic quantum phases such as charge ordered ones (similar to Wigner crystals) and spontaneous Chern insulator phases.

  7. Hexagonal sampling in the infrared domain: an introduction to array set addressing

    NASA Astrophysics Data System (ADS)

    Rummelt, Nicholas I.; Barrows, Geoffrey L.; Massie, Mark A.

    2011-06-01

    It has been known since the early 1960s that hexagonal sampling is the optimal sampling approach for isotropically band-limited images, providing a 13.4% improvement in sampling efficiency over rectangular sampling. Despite this fact and other significant advantages of hexagonal sampling, rectangular sampling is still used for virtually all modern digital image processing systems. This is arguably due to the lack of an efficient addressing system for hexagonal grids. Array set addressing (ASA) is a recent advance in addressing hexagonal grids that allows image processing techniques to be performed efficiently on hexagonally sampled images. This paper will describe ASA and discuss its advantages. With ASA, a renewed interest in sensors that sample hexagonally is occurring. We will describe a new visible imager that simultaneously samples both hexagonally and rectangularly. This novel research tool has the ability to provide real imagery that can be used to quantitatively compare the performance of an image processing operation on both hexagonally sampled and rectangularly sampled images. We will also describe current efforts and plans for future visible sensors that sample hexagonally. The advantages of hexagonal sampling are not limited to the visible domain and should be equally realizable in the infrared domain. This paper will discuss considerations for developing infrared sensors that sample hexagonally. On-focal plane array (FPA) processing, readout architectures, detector materials, and bump-bonding are among the topics to be discussed.

  8. An iterative linear method for calculation of spin-lattice relaxation times

    NASA Astrophysics Data System (ADS)

    Crouch, Ronald; Hurlbert, Stuart; Ragouzeos, Aris

    A simple algorithm for the calculation of spin-lattice relaxation times which can be run in a programmable calculator is presented. As was suggested by H. Hanssum et al., an experimentally determined inhomogeneity parameter ( I) can be used with this procedure to compensate for imperfections in the RF field. The effects of variation of pulse width and repetition rate on both I and T1 are investigated with simulated and experimental data sets. The superiority of this approach over three-parameter nonlinear fitting methods is demonstrated by comparisons between data sets generated with different pulse flip angles and sample volumes.

  9. Lattice-induced nonadiabatic frequency shifts in optical lattice clocks

    SciTech Connect

    Beloy, K.

    2010-09-15

    We consider the frequency shift in optical lattice clocks which arises from the coupling of the electronic motion to the atomic motion within the lattice. For the simplest of three-dimensional lattice geometries this coupling is shown to affect only clocks based on blue-detuned lattices. We have estimated the size of this shift for the prospective strontium lattice clock operating at the 390-nm blue-detuned magic wavelength. The resulting fractional frequency shift is found to be on the order of 10{sup -18} and is largely overshadowed by the electric quadrupole shift. For lattice clocks based on more complex geometries or other atomic systems, this shift could potentially be a limiting factor in clock accuracy.

  10. FDTD analysis of 2D triangular-lattice photonic crystals with arbitrary-shape inclusions based on unit cell transformation

    NASA Astrophysics Data System (ADS)

    Ma, Zetao; Ogusu, Kazuhiko

    2009-04-01

    A finite-difference time-domain method based on Yee's orthogonal cell is utilized to calculate the band structures of 2D triangular-lattice-based photonic crystals through a simple modification to properly shifting the boundaries of the original unit cell. A strategy is proposed for transforming the triangular unit cell into an orthogonal one, which can be used to calculate the band structures of 2D PhCs with various shapes of inclusions, such as triangular, quadrangular, and hexagonal shapes, to overcome the shortage of plane-wave expansion method for circular one. The band structures of 2D triangular-lattice-based PhCs with hexagonal air-holes are calculated and discussed for different values of its radius and rotation angle. The obtained results provide an insight to manipulate the band structures of PhCs.

  11. Single identities for lattice theory and for weakly associative lattices

    SciTech Connect

    McCune, W.; Padmanabhan, R.

    1995-03-13

    We present a single identity for the variety of all lattices that is much simpler than those previously known to us. We also show that the variety of weakly associative lattices is one-based, and we present a generalized one-based theorem for subvarieties of weakly associative lattices that can be defined with absorption laws. The automated theorem-proving program OTTER was used in substantial way to obtain the results.

  12. Buckling analysis of imperfect I-section beam-columns with stochastic shell finite elements

    NASA Astrophysics Data System (ADS)

    Schillinger, Dominik; Papadopoulos, Vissarion; Bischoff, Manfred; Papadrakakis, Manolis

    2010-08-01

    Buckling loads of thin-walled I-section beam-columns exhibit a wide stochastic scattering due to the uncertainty of imperfections. The present paper proposes a finite element based methodology for the stochastic buckling simulation of I-sections, which uses random fields to accurately describe the fluctuating size and spatial correlation of imperfections. The stochastic buckling behaviour is evaluated by crude Monte-Carlo simulation, based on a large number of I-section samples, which are generated by spectral representation and subsequently analyzed by non-linear shell finite elements. The application to an example I-section beam-column demonstrates that the simulated buckling response is in good agreement with experiments and follows key concepts of imperfection triggered buckling. The derivation of the buckling load variability and the stochastic interaction curve for combined compression and major axis bending as well as stochastic sensitivity studies for thickness and geometric imperfections illustrate potential benefits of the proposed methodology in buckling related research and applications.

  13. Imperfect or Perfect Dynamic Bipolarity? The Case of Antonymous Affective Judgments

    ERIC Educational Resources Information Center

    Vautier, Stephane; Steyer, Rolf; Jmel, Said; Raufaste, Eric

    2005-01-01

    How is affective change rated with positive adjectives such as good related to change rated with negative adjectives such as bad? Two nested perfect and imperfect forms of dynamic bipolarity are defined using latent change structural equation models based on tetrads of items. Perfect bipolarity means that latent change scores correlate -1.…

  14. A circular inclusion with circumferentially inhomogeneous imperfect interface in harmonic materials

    NASA Astrophysics Data System (ADS)

    McArthur, D. R.; Sudak, L. J.

    2016-03-01

    In the following analysis, we present a rigorous solution for the problem of a circular elastic inclusion surrounded by an infinite elastic matrix in finite plane elastostatics. The inclusion and matrix are separated by a circumferentially inhomogeneous imperfect interface characterized by the linear spring-type imperfect interface model where the interface is such that the same degree of imperfection is realized in both the normal and tangential directions. Through the use of analytic continuation, a set of first-order coupled ordinary differential equations with variable coefficients are developed for two analytic potential functions. The unknown coefficients of the potential functions are determined from their analyticity requirements and some additional problem-specific constraints. An example is then presented for a specific class of interface where the inclusion mean stress is contrasted between the homogeneous interface and inhomogeneous interface models. It is shown that, for circumstances where a homogeneously imperfect interface may not be warranted, the inhomogeneous model has a pronounced effect on the mean stress within the inclusion.

  15. Intrinsic hierarchical structural imperfections in a natural ceramic of bivalve shell with distinctly graded properties

    PubMed Central

    Jiao, Da; Liu, Zengqian; Zhang, Zhenjun; Zhang, Zhefeng

    2015-01-01

    Despite the extensive investigation on the structure of natural biological materials, insufficient attention has been paid to the structural imperfections by which the mechanical properties of synthetic materials are dominated. In this study, the structure of bivalve Saxidomus purpuratus shell has been systematically characterized quantitatively on multiple length scales from millimeter to sub-nanometer. It is revealed that hierarchical imperfections are intrinsically involved in the crossed-lamellar structure of the shell despite its periodically packed platelets. In particular, various favorable characters which are always pursued in synthetic materials, e.g. nanotwins and low-angle misorientations, have been incorporated herein. The possible contributions of these imperfections to mechanical properties are further discussed. It is suggested that the imperfections may serve as structural adaptations, rather than detrimental defects in the real sense, to help improve the mechanical properties of natural biological materials. This study may aid in understanding the optimizing strategies of structure and properties designed by nature, and accordingly, provide inspiration for the design of synthetic materials. PMID:26198844

  16. Imperfection sensitivity due to the elastic moduli in the Roorda-Koiter frame

    NASA Technical Reports Server (NTRS)

    Elishakoff, Isaac; Starnes, J. H., Jr.; Li, Y. W.

    1998-01-01

    In this study, it is demonstrated through a simple example of the Roorda-Koiter frame that the unavoidable dissimilarity in the distribution of elastic moduli may further reduce the load-carrying capacity in addition to the well-recognized effect of initial geometric imperfections.

  17. Surface instability of an imperfectly bonded thin elastic film under surface van der Waals forces

    NASA Astrophysics Data System (ADS)

    Wang, Xu; Jing, Rong

    2017-02-01

    This paper studies surface instability of a thin elastic film imperfectly bonded to a rigid substrate interacting with a rigid contactor through van der Waals forces under plane strain conditions. The film-substrate interface is modeled as a linear spring with vanishing thickness described in terms of the normal and tangential interface parameters. Depending on the ratio of the two imperfect interface parameters, the critical value of the Poisson's ratio for the occurrence of surface wrinkling in the absence of surface energy can be greater than, equal to, or smaller than 0.25, which is the critical Poisson's ratio for a perfect film-substrate interface. The critical surface energy for the inhibition of the surface wrinkling is also obtained. Finally, we propose a very simple and effective method to study the surface instability of a multilayered elastic film with imperfect interfaces interacting with a rigid contactor or with another multilayered elastic film (or a multilayered simply supported plate) with imperfect interfaces.

  18. Free vibration of thermally loaded panels including initial imperfections and post-buckling effects

    NASA Technical Reports Server (NTRS)

    Murphy, K. D.; Virgin, L. N.; Rizzi, S. A.

    1994-01-01

    A combined theoretical and experimental approach is developed to consider the small amplitude free vibration characteristics of fully clamped panels under the influence of uniform heating. Included in this study are the effects of higher modes, in-plane boundary elasticity, initial imperfections, and post-buckling. Comparisons between theory and experiment reveal excellent agreement.

  19. A cellular automaton implementation of a quantum battle of the sexes game with imperfect information

    NASA Astrophysics Data System (ADS)

    Alonso-Sanz, Ramón

    2015-10-01

    The dynamics of a spatial quantum formulation of the iterated battle of the sexes game with imperfect information is studied in this work. The game is played with variable entangling in a cellular automata manner, i.e. with local and synchronous interaction. The effect of spatial structure is assessed in fair and unfair scenarios.

  20. Let Cinderella and Luke Skywalker Help You Teach the Passe Compose and Imperfect.

    ERIC Educational Resources Information Center

    Terry, Robert M.

    Instructional materials for the passe compose and imperfect tenses in French use the technique of presenting familiar stories in the foreign language, written in the present tense, which students must place in the past by changing verb forms. The objective is to avoid the disadvantages of simply translating verb tenses and to allow the student to…

  1. Computer simulations of the X-ray diffraction patterns of imperfect Al/Nb superlattices

    NASA Astrophysics Data System (ADS)

    Baumann, J. R.; Liebemann, E.; Simon, M.; Bucher, E.

    In order to obtain more structural details from X-ray diffraction (XRD) patterns of metallic multilayers we developed a simulation program for XRD patterns of Al/Nb multilayers. We followed the theory of an imperfect one-dimensional superlattice described by Z. Mitura and P. Mikolajczak. Computer simulated patterns are compared with experimentally obtained XRD spectra.

  2. On Crosslinguistic Variations in Imperfective Aspect: The Case of L2 Korean

    ERIC Educational Resources Information Center

    Lee, EunHee; Kim, Hae-Young

    2007-01-01

    This article examines the acquisition of Korean imperfective markers, the progressive "-ko iss-" and the resultative "-a iss-," with a view to understanding how tense/aspect morphology expands beyond prototype associations with inherent aspects of the verbs. We hypothesized that "-a iss-" will develop later than "-ko iss-," but that the…

  3. A circular inclusion with inhomogeneous non-slip imperfect interface in harmonic materials.

    PubMed

    McArthur, D R; Sudak, L J

    2016-06-01

    In this work, a rigorous study is presented for the problem associated with a circular inclusion embedded in an infinite matrix in finite plane elastostatics where both the inclusion and matrix are comprised a harmonic material. The inclusion/matrix boundary is treated as a circumferentially inhomogeneous imperfect interface that is described by a linear spring-type imperfect interface model where in the tangential direction, the interface parameter is infinite in magnitude and in the normal direction, the interface parameter is finite in magnitude (the so-called non-slip interface condition). Through the repeated use of the technique of analytic continuation, the boundary value problem for four analytic functions is reduced to solve a single first-order linear ordinary differential equation with variable coefficients for a single analytic function defined within the inclusion. The unknown coefficients of said function are then found via various analyticity requirements. The method is illustrated, using a specific example of a particular class of inhomogeneous non-slip imperfect interface. The results from these calculations are then contrasted with the results from the homogeneous imperfect interface. These comparisons indicate that the circumferential variation of interface damage has a pronounced effect on the average boundary stress.

  4. Security analysis on some experimental quantum key distribution systems with imperfect optical and electrical devices

    NASA Astrophysics Data System (ADS)

    Liang, Lin-Mei; Sun, Shi-Hai; Jiang, Mu-Sheng; Li, Chun-Yan

    2014-10-01

    In general, quantum key distribution (QKD) has been proved unconditionally secure for perfect devices due to quantum uncertainty principle, quantum noncloning theorem and quantum nondividing principle which means that a quantum cannot be divided further. However, the practical optical and electrical devices used in the system are imperfect, which can be exploited by the eavesdropper to partially or totally spy the secret key between the legitimate parties. In this article, we first briefly review the recent work on quantum hacking on some experimental QKD systems with respect to imperfect devices carried out internationally, then we will present our recent hacking works in details, including passive faraday mirror attack, partially random phase attack, wavelength-selected photon-number-splitting attack, frequency shift attack, and single-photon-detector attack. Those quantum attack reminds people to improve the security existed in practical QKD systems due to imperfect devices by simply adding countermeasure or adopting a totally different protocol such as measurement-device independent protocol to avoid quantum hacking on the imperfection of measurement devices [Lo, et al., Phys. Rev. Lett., 2012, 108: 130503].

  5. Improving Prediction Skill of Imperfect Turbulent Models Through Statistical Response and Information Theory

    NASA Astrophysics Data System (ADS)

    Majda, Andrew J.; Qi, Di

    2016-02-01

    Turbulent dynamical systems with a large phase space and a high degree of instabilities are ubiquitous in climate science and engineering applications. Statistical uncertainty quantification (UQ) to the response to the change in forcing or uncertain initial data in such complex turbulent systems requires the use of imperfect models due to the lack of both physical understanding and the overwhelming computational demands of Monte Carlo simulation with a large-dimensional phase space. Thus, the systematic development of reduced low-order imperfect statistical models for UQ in turbulent dynamical systems is a grand challenge. This paper applies a recent mathematical strategy for calibrating imperfect models in a training phase and accurately predicting the response by combining information theory and linear statistical response theory in a systematic fashion. A systematic hierarchy of simple statistical imperfect closure schemes for UQ for these problems is designed and tested which are built through new local and global statistical energy conservation principles combined with statistical equilibrium fidelity. The forty mode Lorenz 96 (L-96) model which mimics forced baroclinic turbulence is utilized as a test bed for the calibration and predicting phases for the hierarchy of computationally cheap imperfect closure models both in the full phase space and in a reduced three-dimensional subspace containing the most energetic modes. In all of phase spaces, the nonlinear response of the true model is captured accurately for the mean and variance by the systematic closure model, while alternative methods based on the fluctuation-dissipation theorem alone are much less accurate. For reduced-order model for UQ in the three-dimensional subspace for L-96, the systematic low-order imperfect closure models coupled with the training strategy provide the highest predictive skill over other existing methods for general forced response yet have simple design principles based on a

  6. Thermodynamics of the Relationship between Lattice Energy and Lattice Enthalpy

    NASA Astrophysics Data System (ADS)

    Jenkins, H. Donald B.

    2005-06-01

    Incorporation of lattice potential energy, U POT , within a Born Fajans Haber thermochemical cycle based on enthalpy changes necessitates correction of the energy of the lattice to an enthalpy term, Δ H L . For a lattice containing p i ions of type i in the formula unit, the lattice enthalpy is given by Δ H L = U POT + ∑ s i [( c i /2) - 2] RT where R is the gas constant (= 8.314 J K -1 mol -1 ), T is the absolute temperature, and c i is defined according as to whether the ion i is monatomic ( c i = 3), linear polyatomic ( c i = 5), or polyatomic ( c i = 6), respectively.

  7. Lattice QCD for nuclei

    NASA Astrophysics Data System (ADS)

    Beane, Silas

    2016-09-01

    Over the last several decades, theoretical nuclear physics has been evolving from a very-successful phenomenology of the properties of nuclei, to a first-principles derivation of the properties of visible matter in the Universe from the known underlying theories of Quantum Chromodynamics (QCD) and Electrodynamics. Many nuclear properties have now been calculated using lattice QCD, a method for treating QCD numerically with large computers. In this talk, some of the most recent results in this frontier area of nuclear theory will be reviewed.

  8. Magnetic-film atom chip with 10 μm period lattices of microtraps for quantum information science with Rydberg atoms.

    PubMed

    Leung, V Y F; Pijn, D R M; Schlatter, H; Torralbo-Campo, L; La Rooij, A L; Mulder, G B; Naber, J; Soudijn, M L; Tauschinsky, A; Abarbanel, C; Hadad, B; Golan, E; Folman, R; Spreeuw, R J C

    2014-05-01

    We describe the fabrication and construction of a setup for creating lattices of magnetic microtraps for ultracold atoms on an atom chip. The lattice is defined by lithographic patterning of a permanent magnetic film. Patterned magnetic-film atom chips enable a large variety of trapping geometries over a wide range of length scales. We demonstrate an atom chip with a lattice constant of 10 μm, suitable for experiments in quantum information science employing the interaction between atoms in highly excited Rydberg energy levels. The active trapping region contains lattice regions with square and hexagonal symmetry, with the two regions joined at an interface. A structure of macroscopic wires, cutout of a silver foil, was mounted under the atom chip in order to load ultracold (87)Rb atoms into the microtraps. We demonstrate loading of atoms into the square and hexagonal lattice sections simultaneously and show resolved imaging of individual lattice sites. Magnetic-film lattices on atom chips provide a versatile platform for experiments with ultracold atoms, in particular for quantum information science and quantum simulation.

  9. Magnetic-film atom chip with 10 μm period lattices of microtraps for quantum information science with Rydberg atoms

    NASA Astrophysics Data System (ADS)

    Leung, V. Y. F.; Pijn, D. R. M.; Schlatter, H.; Torralbo-Campo, L.; La Rooij, A. L.; Mulder, G. B.; Naber, J.; Soudijn, M. L.; Tauschinsky, A.; Abarbanel, C.; Hadad, B.; Golan, E.; Folman, R.; Spreeuw, R. J. C.

    2014-05-01

    We describe the fabrication and construction of a setup for creating lattices of magnetic microtraps for ultracold atoms on an atom chip. The lattice is defined by lithographic patterning of a permanent magnetic film. Patterned magnetic-film atom chips enable a large variety of trapping geometries over a wide range of length scales. We demonstrate an atom chip with a lattice constant of 10 μm, suitable for experiments in quantum information science employing the interaction between atoms in highly excited Rydberg energy levels. The active trapping region contains lattice regions with square and hexagonal symmetry, with the two regions joined at an interface. A structure of macroscopic wires, cutout of a silver foil, was mounted under the atom chip in order to load ultracold 87Rb atoms into the microtraps. We demonstrate loading of atoms into the square and hexagonal lattice sections simultaneously and show resolved imaging of individual lattice sites. Magnetic-film lattices on atom chips provide a versatile platform for experiments with ultracold atoms, in particular for quantum information science and quantum simulation.

  10. Magnetic-film atom chip with 10 μm period lattices of microtraps for quantum information science with Rydberg atoms

    SciTech Connect

    Leung, V. Y. F.; Pijn, D. R. M.; Schlatter, H.; Torralbo-Campo, L.; La Rooij, A. L.; Mulder, G. B.; Naber, J.; Soudijn, M. L.; Tauschinsky, A.; Spreeuw, R. J. C.; Abarbanel, C.; Hadad, B.; Golan, E.; Folman, R.

    2014-05-15

    We describe the fabrication and construction of a setup for creating lattices of magnetic microtraps for ultracold atoms on an atom chip. The lattice is defined by lithographic patterning of a permanent magnetic film. Patterned magnetic-film atom chips enable a large variety of trapping geometries over a wide range of length scales. We demonstrate an atom chip with a lattice constant of 10 μm, suitable for experiments in quantum information science employing the interaction between atoms in highly excited Rydberg energy levels. The active trapping region contains lattice regions with square and hexagonal symmetry, with the two regions joined at an interface. A structure of macroscopic wires, cutout of a silver foil, was mounted under the atom chip in order to load ultracold {sup 87}Rb atoms into the microtraps. We demonstrate loading of atoms into the square and hexagonal lattice sections simultaneously and show resolved imaging of individual lattice sites. Magnetic-film lattices on atom chips provide a versatile platform for experiments with ultracold atoms, in particular for quantum information science and quantum simulation.

  11. Investigation on the Geometric Imperfections driven Local Buckling Onset in Composite Conical Shells

    NASA Astrophysics Data System (ADS)

    Di Pasqua, Maria Francesca; Khakimova, Regina; Castro, Saullo G. P.; Arbelo, Mariano A.; Riccio, Aniello; Raimondo, Antonio; Degenhardt, Richard

    2016-08-01

    Buckling is a critical failure phenomenon for structures, and represents a threat for thin shells subjected to compressive forces. The global buckling load, for a conical structure, depends on the geometry and material properties of the shell, on the stacking sequence, on the type of applied load and on the initial geometric imperfections. Geometric imperfections, occurring inevitably during manufacturing and assembly of thin-walled composite structures, produce a reduction in the carrying load capability with respect to the design value. This is the reason why investigating these defects is of major concern in order to avoid over-conservative design structures. In this paper, the buckling behavior a conical structure with 45° semi-vertical angle is numerically investigated. The initial imperfections are taken into account by using different strategies. At first, the Single Perturbation Load Approach (SPLA), which accounts for defects in the form of a lateral load, normal to the surface, has been adopted. Then, the actual measured defects have been applied to the structure by using the Real Measured Mid-Surface Imperfections (MSI) approach. Investigations on cylindrical shells using the first strategy have already shown the occurrence of a particular phenomenon called "local snap-through", which represents a preliminary loss of stiffness. In order to better understand this phenomenon for conical shells, both the aforementioned techniques have been used to provide an exhaustive overview of the imperfections sensitiveness in conical composite shells. This study is related to part of the work performed in the frame of the European Union (EU) project DESICOS.

  12. Structural elucidation and magnetic behavior evaluation of rare earth (La, Nd, Gd, Tb, Dy) doped BaCoNi-X hexagonal nano-sized ferrites

    NASA Astrophysics Data System (ADS)

    Majeed, Abdul; Khan, Muhammad Azhar; Raheem, Faseeh ur; Hussain, Altaf; Iqbal, F.; Murtaza, Ghulam; Akhtar, Majid Niaz; Shakir, Imran; Warsi, Muhammad Farooq

    2016-06-01

    Rare-earth (RE=La3+, Nd3+, Gd3+, Tb3+, Dy3+) doped Ba2NiCoRExFe28-xO46 (x=0.25) hexagonal ferrites were synthesized for the first time via micro-emulsion route, which is a fast chemistry route for obtaining nano-sized ferrite powders. These nanomaterials were investigated by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), as well as vibrating sample magnetometer (VSM). The XRD analysis exhibited that all the samples crystallized into single X-type hexagonal phase. The crystalline size calculated by Scherrer's formula was found in the range 7-19 nm. The variations in lattice parameters elucidated the incorporation of rare-earth cations in these nanomaterials. FTIR absorption spectra of these X-type ferrites were investigated in the wave number range 500-2400 cm-1. Each spectrum exhibited absorption bands in the low wave number range, thereby confirming the X-type hexagonal structure. The enhancement in the coercivity was observed with the doping of rare-earth cations. The saturation magnetization was lowered owing to the redistribution of rare-earth cations on the octahedral site (3bVI). The higher values of coercivity (664-926 Oe) of these nanomaterials suggest their use in longitudinal recording media.

  13. Gauge symmetry and non-Abelian topological sectors in a geometrically constrained model on the honeycomb lattice.

    PubMed

    Fendley, Paul; Moore, Joel E; Xu, Cenke

    2007-05-01

    We study a constrained statistical-mechanical model in two dimensions that has three useful descriptions. They are (i) the Ising model on the honeycomb lattice, constrained to have three up spins and three down spins on every hexagon, (ii) the three-color and fully packed loop model on the links of the honeycomb lattice, with loops around a single hexagon forbidden, and (iii) three Ising models on interleaved triangular lattices, with domain walls of the different Ising models not allowed to cross. Unlike the three-color model, the configuration space on the sphere or plane is connected under local moves. On higher-genus surfaces there are infinitely many dynamical sectors, labeled by a noncontractible set of nonintersecting loops. We demonstrate that at infinite temperature the transfer matrix admits an unusual structure related to a gauge symmetry for the same model on an anisotropic lattice. This enables us to diagonalize the original transfer matrix for up to 36 sites, finding an entropy per plaquette S/k{B} approximately 0.3661 ... centered and substantial evidence that the model is not critical. We also find the striking property that the eigenvalues of the transfer matrix on an anisotropic lattice are given in terms of Fibonacci numbers. We comment on the possibility of a topological phase, with infinite topological degeneracy, in an associated two-dimensional quantum model.

  14. Ambiguities in Powder Indexing: Conjunction of a Ternary and Binary Lattice Metric Singularity in the Cubic System.

    PubMed

    Mighell, Alan D

    2004-01-01

    A lattice metric singularity occurs when unit cells defining two (or more) lattices yield the identical set of unique calculated d-spacings. The existence of such singularities, therefore, has a practical and theoretical impact on the indexing of powder patterns. For example, in experimental practice an indexing program may find only the lower symmetry member of a singularity. Obviously, it is important to recognize such cases and know how to proceed. Recently, we described: a binary singularity involving a monoclinic and a rhombohedral lattice in a subcell-supercell relationship anda second type of singularity-a ternary singularity-in which two of the three lattices are in a derivative composite relationship. In this work, we describe a ternary lattice metric singularity involving a cubic P, a tetragonal P, and an orthorhombic C lattice. Furthermore, there is a binary singularity, involving a hexagonal P and orthorhombic P lattice, which is characterized by a set of unique d-spacings very close to that of the ternary singularity. The existence of such singularities is more common than once thought and requires a paradigm shift in experimental practice. In addition singularities provide opportunities in material design as they point to highly specialized lattices that may be associated with unusual physical properties.

  15. Lattice harmonics expansion revisited

    NASA Astrophysics Data System (ADS)

    Kontrym-Sznajd, G.; Holas, A.

    2017-04-01

    The main subject of the work is to provide the most effective way of determining the expansion of some quantities into orthogonal polynomials, when these quantities are known only along some limited number of sampling directions. By comparing the commonly used Houston method with the method based on the orthogonality relation, some relationships, which define the applicability and correctness of these methods, are demonstrated. They are verified for various sets of sampling directions applicable for expanding quantities having the full symmetry of the Brillouin zone of cubic and non-cubic lattices. All results clearly show that the Houston method is always better than the orthogonality-relation one. For the cubic symmetry we present a few sets of special directions (SDs) showing how their construction and, next, a proper application depend on the choice of various sets of lattice harmonics. SDs are important mainly for experimentalists who want to reconstruct anisotropic quantities from their measurements, performed at a limited number of sampling directions.

  16. Orthocomplemented complete lattices and graphs

    NASA Astrophysics Data System (ADS)

    Ollech, Astrid

    1995-08-01

    The problem I consider originates from Dörfler, who found a construction to assign an Orthocomplemented lattice H(G) to a graph G. By Dörfler it is known that for every finite Orthocomplemented lattice L there exists a graph G such that H(G)=L. Unfortunately, we can find more than one graph G with this property, i.e., orthocomplemented lattices which belong to different graphs can be isomorphic. I show some conditions under which two graphs have the same orthocomplemented lattice.

  17. Two Nucleons on a Lattice

    SciTech Connect

    S.R. Beane; P.F.Bedaque; A. Parreno; M.J. Savage

    2004-04-01

    The two-nucleon sector is near an infrared fixed point of QCD and as a result the S-wave scattering lengths are unnaturally large compared to the effective ranges and shape parameters. It is usually assumed that a lattice QCD simulation of the two-nucleon sector will require a lattice that is much larger than the scattering lengths in order to extract quantitative information. In this paper we point out that this does not have to be the case: lattice QCD simulations on much smaller lattices will produce rigorous results for nuclear physics.

  18. Lattice Dynamics of the Rhenium and Technetium Dichalcogenides

    NASA Astrophysics Data System (ADS)

    Wolverson, Daniel; Hart, Lewis S.

    2016-05-01

    The rhenium and technetium dichalcogenides are layered van der Waals semiconductors which show a large number of Raman-active zone-centre phonon modes as a result of their unusually large unit cells and deviation from hexagonal symmetry. They thus offer the possibility of introducing in-plane anisotropy into composite heterostructures based on van der Waals materials, and Raman spectroscopy is generally used to determine their in-plane orientation. We show that first-principles calculations give a good description of the lattice dynamics of this family of materials and thus predict the zone-centre phonon frequencies and Raman activities of TcS2. We consider the distribution of the phonon modes in frequency and their atomic displacements and give a unified understanding of the phonon frequencies and Raman spectra of ReS2, TcS2 and ReSe2 in terms of the scaling of Raman frequency with the chalcogen mass.

  19. Elimination of spurious lattice fermion solutions and noncompact lattice QCD

    SciTech Connect

    Lee, T.D.

    1997-09-22

    It is well known that the Dirac equation on a discrete hyper-cubic lattice in D dimension has 2{sup D} degenerate solutions. The usual method of removing these spurious solutions encounters difficulties with chiral symmetry when the lattice spacing l {ne} 0, as exemplified by the persistent problem of the pion mass. On the other hand, we recall that in any crystal in nature, all the electrons do move in a lattice and satisfy the Dirac equation; yet there is not a single physical result that has ever been entangled with a spurious fermion solution. Therefore it should not be difficult to eliminate these unphysical elements. On a discrete lattice, particle hop from point to point, whereas in a real crystal the lattice structure in embedded in a continuum and electrons move continuously from lattice cell to lattice cell. In a discrete system, the lattice functions are defined only on individual points (or links as in the case of gauge fields). However, in a crystal the electron state vector is represented by the Bloch wave functions which are continuous functions in {rvec {gamma}}, and herein lies one of the essential differences.

  20. Hexagon functions and the three-loop remainder function

    SciTech Connect

    Dixon, Lance J.; Drummond, James M.; von Hippel, Matt; Pennington, Jeffrey

    2013-12-01

    We present the three-loop remainder function, which describes the scattering of six gluons in the maximally-helicity-violating configuration in planar NN = 4 super-Yang-Mills theory, as a function of the three dual conformal cross ratios. The result can be expressed in terms of multiple Goncharov polylogarithms. We also employ a more restricted class of hexagon functions which have the correct branch cuts and certain other restrictions on their symbols. We classify all the hexagon functions through transcendental weight five, using the coproduct for their Hopf algebra iteratively, which amounts to a set of first-order differential equations. The three-loop remainder function is a particular weight-six hexagon function, whose symbol was determined previously. The differential equations can be integrated numerically for generic values of the cross ratios, or analytically in certain kinematic limits, including the near-collinear and multi-Regge limits. These limits allow us to impose constraints from the operator product expansion and multi-Regge factorization directly at the function level, and thereby to fix uniquely a set of Riemann ζ valued constants that could not be fixed at the level of the symbol. The near-collinear limits agree precisely with recent predictions by Basso, Sever and Vieira based on integrability. The multi-Regge limits agree with the factorization formula of Fadin and Lipatov, and determine three constants entering the impact factor at this order. We plot the three-loop remainder function for various slices of the Euclidean region of positive cross ratios, and compare it to the two-loop one. For large ranges of the cross ratios, the ratio of the three-loop to the two-loop remainder function is relatively constant, and close to -7.