Sample records for including soils sediments

  1. 75 FR 4106 - Notice of Lodging of Consent Decree Under the Comprehensive Environmental Response, Compensation...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-01-26

    ..., the remedy chosen for the soils and sediments was failing to clean the soils and sediments up to the required performance standards. EPA issued an Amended Record of Decision for the soils and sediments... then became necessary to amend the 1998 Decree to include the revised soils and sediment cleanup under...

  2. 23 CFR 650.205 - Definitions.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ..., STRUCTURES, AND HYDRAULICS Erosion and Sediment Control on Highway Construction Projects § 650.205... transporting of soil particles by water or wind, including actions that limit the area of exposed soil and... completion of the project. Pollutants are substances, including sediment, which cause deterioration of water...

  3. 23 CFR 650.205 - Definitions.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ..., STRUCTURES, AND HYDRAULICS Erosion and Sediment Control on Highway Construction Projects § 650.205... transporting of soil particles by water or wind, including actions that limit the area of exposed soil and... completion of the project. Pollutants are substances, including sediment, which cause deterioration of water...

  4. 23 CFR 650.205 - Definitions.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ..., STRUCTURES, AND HYDRAULICS Erosion and Sediment Control on Highway Construction Projects § 650.205... transporting of soil particles by water or wind, including actions that limit the area of exposed soil and... completion of the project. Pollutants are substances, including sediment, which cause deterioration of water...

  5. 23 CFR 650.205 - Definitions.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ..., STRUCTURES, AND HYDRAULICS Erosion and Sediment Control on Highway Construction Projects § 650.205... transporting of soil particles by water or wind, including actions that limit the area of exposed soil and... completion of the project. Pollutants are substances, including sediment, which cause deterioration of water...

  6. 23 CFR 650.205 - Definitions.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ..., STRUCTURES, AND HYDRAULICS Erosion and Sediment Control on Highway Construction Projects § 650.205... transporting of soil particles by water or wind, including actions that limit the area of exposed soil and... completion of the project. Pollutants are substances, including sediment, which cause deterioration of water...

  7. Comparative phosphorus sorption by marine sediments and agricultural soils in a tropical environment.

    PubMed

    Fox, Robert L; Fares, Ali; Wan, Y; Evensen, Carl I

    2006-01-01

    The influence of soil phosphorus (P) sources on P sorption characteristics of marine sediments was investigated for Pearl Harbor and off shore Molokai in Hawaii. Estuary sediments were sampled in seven locations; these represented different soils and on-shore activities. The soil samples included nine major soils that contributed sediment to the Harbor and coastal sediments near the island of Molokai. Sediment and soil samples were equilibrated for 6 days in 0.01 M CaCl(2) solution and synthetic seawater containing differing amounts of P. Phosphorus sorption curves were constructed. The equilibrated solution P, with no P added, ranged from 0.01 to 0.2 mg L(-1); P sorption by sediments at standard solution concentration 0.2 mg L(-1), ranged from 0 to 230 mg kg(-1). Sediment P sorption corresponded closely with soil sorption characteristics. Soils contributing sediments to the west reach of Pearl Harbor are highly weathered Oxisols with high standard P sorption values while those in the southeast of the Harbor were Vertisols and Mollisols which sorb little P. The influence of source materials on sediment P sorption was also observed for off-shore sediments near Molokai. Sediments serve as both source and sink for P in Pearl Harbor and in this role can be a stabilizing influence on P concentration in the water column. Phosphorus sorption curves in conjunction with water quality data can help to understand P dynamics between sediments and the water column and help evaluate concerns about P loading to a water body. For Pearl Harbor, solution P in equilibrium with sediments from the Lochs was 0.021 mg L(-1); a value unlikely to produce an algal bloom. (Measured total P in the water columns (mean) was 0.060.).

  8. Analysis of suspended-sediment concentrations and radioisotope levels in the Wild Rice River basin, northwestern Minnesota, 1973-98

    USGS Publications Warehouse

    Brigham, Mark E.; McCullough, Carolyn J.; Wilkinson, Philip M.

    2001-01-01

    We examined historical suspended-sediment data and activities of fallout radioisotopes (lead-210 [210Pb], cesium-137 [137Cs], and beryllium-7 [7Be]) associated with suspended sediments and source-area sediments (cultivated soils, bank material, and reference soils) in the Wild Rice River Basin, a tributary to the Red River of the North, to better understand sources of suspended sediment to streams in the region. Multiple linear regression analysis of suspended-sediment concentrations from the Wild Rice River at Twin Valley, Minnesota indicated significant relations between suspended-sediment concentrations and streamflow. Flow-adjusted sediment concentrations tended to be slightly higher in spring than summer-autumn. No temporal trends in concentration were observed during 1973-98. The fallout radioisotopes were nearly always detectable in suspended sediments during spring-summer 1998. Mean 210Pb and 7Be activities in suspended sediment and surficial, cultivated soils were similar, perhaps indicating little dilution of suspended sediment from low-isotopic-activity bank sediments. In contrast, mean 137Cs activities in suspended sediment indicated a mixture of sediment originating from eroded soils and from eroded bank material, with bank material being a somewhat more important source upstream of Twin Valley, Minnesota; and approximately equal fractions of bank material and surficial soils contributing to the suspended load downstream at Hendrum, Minnesota. This study indicates that, to be effective, efforts to reduce sediment loading to the Wild Rice River should include measures to control soil erosion from cultivated fields.

  9. Assessment of herbicide sorption by biochars and organic matter associated with soil and sediment

    USDA-ARS?s Scientific Manuscript database

    Sorption of two herbicides, fluridone (FLUN) and norflurazon (NORO), by whole sediment, two types of biochars and various soil/sediment organic matter (OM) fractions including nonhydrolyzable carbon (NHC), black carbon (BC) and humic acid (HA) was examined. The single-point organic carbon (OC)-norma...

  10. Process recognition in multi-element soil and stream-sediment geochemical data

    USGS Publications Warehouse

    Grunsky, E.C.; Drew, L.J.; Sutphin, D.M.

    2009-01-01

    Stream-sediment and soil geochemical data from the Upper and Lower Coastal Plains of South Carolina (USA) were studied to determine relationships between soils and stream sediments. From multi-element associations, characteristic compositions were determined for both media. Primary associations of elements reflect mineralogy, including heavy minerals, carbonates and clays, and the effects of groundwater. The effects of groundwater on element concentrations are more evident in soils than stream sediments. A "winnowing index" was created using ratios of Th to Al that revealed differing erosional and depositional environments. Both soils and stream sediments from the Upper and Lower Coastal Plains show derivation from similar materials and subsequent similar multi-element relationships, but have some distinct differences. In the Lower Coastal Plain, soils have high values of elements concentrated in heavy minerals (Ce, Y, Th) that grade into high values of elements concentrated into finer-grain-size, lower-density materials, primarily comprised of carbonates and feldspar minerals (Mg, Ca, Na, K, Al). These gradational trends in mineralogy and geochemistry are inferred to reflect reworking of materials during marine transgressions and regressions. Upper Coastal Plain stream-sediment geochemistry shows a higher winnowing index relative to soil geochemistry. A comparison of the 4 media (Upper Coastal Plain soils and stream sediments and Lower Coastal Plain soils and stream sediments) shows that Upper Coastal Plain stream sediments have a higher winnowing index and a higher concentration of elements contained within heavy minerals, whereas Lower Coastal Plain stream sediments show a strong correlation between elements typically contained within clays. It is not possible to calculate a functional relationship between stream sediment-soil compositions for all elements due to the complex history of weathering, deposition, reworking and re-deposition. However, depending on the spatial separation of the stream-sediment and soil samples, some elements are more highly correlated than others. Crown Copyright ?? 2009.

  11. Towards Soil and Sediment Inventories of Black Carbon

    NASA Astrophysics Data System (ADS)

    Masiello, C. A.

    2008-12-01

    A body of literature on black carbon (BC) concentrations in soils and sediments is rapidly accumulating, but as of yet, there are no global or regional inventories of BC in either reservoir. Soil and sediment BC inventories are badly needed for a range of fields. For example, in oceanography a global sediment BC inventory is crucial in understanding the role of biomass burning in the development of stable marine carbon reservoirs, including dissolved organic carbon and sedimentary organic carbon. Again in the marine environment, BC likely strongly impacts the fate and transport of anthropogenic pollutants: regional inventories of BC in sediments will help develop better environmental remediation strategies. In terrestrial systems well-constrained natural BC soil inventories would help refine ecological, agricultural, and soil biogeochemical studies. BC is highly sorptive of nutrients including nitrogen and phosphorous. The presence of BC in ecosystems almost certainly alters N and P cycling; however, without soil BC inventories, we cannot know where BC has a significant impact. BC's nutrient sorptivity and water-holding capacity make it an important component of agricultural soils, and some researchers have proposed artificially increasing soil BC inventories to improve soil fertility. Natural soil BC concentrations in some regions are quite high, but without a baseline inventory, it is challenging to predict when agricultural amendment will significantly exceed natural conditions. And finally, because BC is one of the most stable fractions of organic carbon in soils, understanding its concentration and regional distribution will help us track the dynamics of soil organic matter response to changing environmental conditions. Developing effective regional and global BC inventories is challenging both because of data sparsity and methodological intercomparison issues. In this presentation I will describe a roadmap to generating these valuable inventories.

  12. Predicting the particle size distribution of eroded sediment using artificial neural networks.

    PubMed

    Lagos-Avid, María Paz; Bonilla, Carlos A

    2017-03-01

    Water erosion causes soil degradation and nonpoint pollution. Pollutants are primarily transported on the surfaces of fine soil and sediment particles. Several soil loss models and empirical equations have been developed for the size distribution estimation of the sediment leaving the field, including the physically-based models and empirical equations. Usually, physically-based models require a large amount of data, sometimes exceeding the amount of available data in the modeled area. Conversely, empirical equations do not always predict the sediment composition associated with individual events and may require data that are not always available. Therefore, the objective of this study was to develop a model to predict the particle size distribution (PSD) of eroded soil. A total of 41 erosion events from 21 soils were used. These data were compiled from previous studies. Correlation and multiple regression analyses were used to identify the main variables controlling sediment PSD. These variables were the particle size distribution in the soil matrix, the antecedent soil moisture condition, soil erodibility, and hillslope geometry. With these variables, an artificial neural network was calibrated using data from 29 events (r 2 =0.98, 0.97, and 0.86; for sand, silt, and clay in the sediment, respectively) and then validated and tested on 12 events (r 2 =0.74, 0.85, and 0.75; for sand, silt, and clay in the sediment, respectively). The artificial neural network was compared with three empirical models. The network presented better performance in predicting sediment PSD and differentiating rain-runoff events in the same soil. In addition to the quality of the particle distribution estimates, this model requires a small number of easily obtained variables, providing a convenient routine for predicting PSD in eroded sediment in other pollutant transport models. Copyright © 2017 Elsevier B.V. All rights reserved.

  13. Development of a Distributed Source Containment Transport, Transformation, and Fate (CTT&F) Sub-Model for Military Installations

    DTIC Science & Technology

    2007-08-01

    includes soil erodibility terms from the Universal Soil Lass Equation ( USLE ) for estimating the overland sediment transport capacity (for both the x and y...q = unit flow rate of water = va h [L2/T] vc = critical velocity for erosion overland [L/T] K = USLE soil erodibility factor C = USLE soil ...cover factor P = USLE soil management practice factor Be = width of eroding surface in flow direction [L]. In channels, sediment particles can be

  14. Soil conservation through sediment trapping: A review

    NASA Astrophysics Data System (ADS)

    Mekonnen, Mulatie; Keesstra, Saskia; Baartman, Jantiene; Maroulis, Jerry; Stroosnijder, Leo

    2014-05-01

    Preventing the off-site effects of soil erosion is an essential part of good catchment management. Most efforts are in the form of on-site soil and water conservation measures. However, sediment trapping (ST) can be an alternative (or additional) measure to prevent the negative off-site effects of soil erosion. Therefore, not all efforts should focus solely on on-site soil conservation, but also on the safe routing of sediment-laden flows and on creating sites and conditions where sediment can be trapped, preferably in a cost effective or even profitable way. ST can be applied on-site (in-field) and off-site and involves both vegetative and structural measures. The main vegetative measures include grass strips, tree or bush buffers, grassed waterways and restoration of the waterways and their riparian zone; while structural measures include terraces, ponds and check dams. This paper provides a review of studies that have assessed the sediment trapping efficacy (STE) of such vegetative and structural measures. Vegetation type and integration of two or more measures (vegetative as well as structural) are important factors influencing STE. In this review, the STE of most measures was evaluated either individually or in such combinations. In real landscape situations, it is not only important to select the most efficient erosion control measures, but also to determine their optimum location in the catchment. Hence, there is a need for research that shows a more integrated determination of STE at the catchment scale. If integrated measures are implemented at the most appropriate spatial locations within a catchment where they can disconnect landscape units from each other, they will decrease runoff velocity and sediment transport and, subsequently, reduce downstream flooding and sedimentation problems. KEY WORDS: Integrated sediment trapping, sediment trapping efficacy, vegetative, structural, on-site and off-site measures.

  15. Soil, environmental, and watershed measurements in support of carbon cycling studies in northwestern Mississippi

    USGS Publications Warehouse

    Huntington, T.G.; Harden, J.W.; Dabney, S.M.; Marion, D.A.; Alonso, C.; Sharpe, J.M.; Fries, T.L.

    1998-01-01

    Measurements including soil respiration, soil moisture, soil temperature, and carbon export in suspended sediments from small watersheds were recorded at several field sites in northwestern Mississippi in support of hillslope process studies associated with the U.S. Geological Survey's Mississippi Basin Carbon Project (MBCP). These measurements were made to provide information about carbon cycling in agricultural and forest ecosystems to understand the potential role of erosion and deposition in the sequestration of soil organic carbon in upland soils. The question of whether soil erosion and burial constitutes an important net sink of atmospheric carbon dioxide is one hypothesis that the MBCP is evaluating to better understand carbon cycling and climate change. This report contains discussion of methods used and presents data for the period December 1996 through March 1998. Included in the report are ancillary data provided by the U.S. Department of Agriculture (USDA) ARS National Sedimentation Laboratory and U.S. Forest Service (USFS) Center for Bottomland Hardwoods Research on rainfall, runoff, sediment yield, forest biomass and grain yield. Together with the data collected by the USGS these data permit the construction of carbon budgets and the calibration of models of soil organic matter dynamics and sediment transport and deposition. The U.S. Geological Survey (USGS) has established cooperative agreements with the USDA and USFS to facilitate collaborative research at research sites in northwestern Mississippi.

  16. Targeting sediment management strategies using sediment quantification and fingerprinting methods

    NASA Astrophysics Data System (ADS)

    Sherriff, Sophie; Rowan, John; Fenton, Owen; Jordan, Phil; hUallacháin, Daire Ó.

    2016-04-01

    Cost-effective sediment management is required to reduce excessive delivery of fine sediment due to intensive land uses such as agriculture, resulting in the degradation of aquatic ecosystems. Prioritising measures to mitigate dominant sediment sources is, however, challenging, as sediment loss risk is spatially and temporally variable between and within catchments. Fluctuations in sediment supply from potential sources result from variations in land uses resulting in increased erodibility where ground cover is low (e.g., cultivated, poached and compacted soils), and physical catchment characteristics controlling hydrological connectivity and transport pathways (surface and/or sub-surface). Sediment fingerprinting is an evidence-based management tool to identify sources of in-stream sediments at the catchment scale. Potential sediment sources are related to a river sediment sample, comprising a mixture of source sediments, using natural physico-chemical characteristics (or 'tracers'), and contributions are statistically un-mixed. Suspended sediment data were collected over two years at the outlet of three intensive agricultural catchments (approximately 10 km2) in Ireland. Dominant catchment characteristics were grassland on poorly-drained soils, arable on well-drained soils and arable on moderately-drained soils. High-resolution (10-min) calibrated turbidity-based suspended sediment and discharge data were combined to quantify yield. In-stream sediment samples (for fingerprinting analysis) were collected at six to twelve week intervals, using time-integrated sediment samplers. Potential sources, including stream channel banks, ditches, arable and grassland field topsoils, damaged road verges and tracks were sampled, oven-dried (<40oC) and sieved (125 microns). Soil and sediment samples were analysed for mineral magnetics, geochemistry and radionuclide tracers, particle size distribution and soil organic carbon. Tracer data were corrected to account for particle size and organic matter selectivity processes. Contributions from potential sources type groups (channel - ditches and stream banks, roads - road verges and tracks, fields - grassland and arable topsoils) were statistically un-mixed using FR2000, an uncertainty-inclusive algorithm, and combined with sediment yield data. Results showed sediment contributions from channel, field and road groups were 70%, 25% and 5% in the poorly-drained catchment, 59%, 22% and 19% in the well-drained catchment, and 17%, 74% and 9% in the moderately-drained catchment. Higher channel contributions in the poorly-drained catchment were attributed to bank erosion accelerated by the rapid diversion of surface runoff into channels, facilitated by surface and sub-surface artificial drainage networks, and bank seepage from lateral pressure gradients due to confined groundwater. Despite the greatest proportion of arable soils in the well-drained catchment, this source was frequently hydrologically disconnected as well-drained soils largely infiltrated rainfall and prevented surface soil erosion. Periods of high and intense rainfall were associated with greater proportions of field losses in the well-drained catchment likely due to infiltration exceeding the saturated hydraulic conductivity of soils and establishment of surface hydrological connectivity. Losses from field topsoils dominated in the moderately-drained catchment as antecedent soil wetness maintained surface flow pathways and coincided with low groundcover on arable soils. For cost-effective management of sediment pressures to aquatic ecosystems, catchment specific variations in sediment sources must be considered.

  17. Modeled and monitored variation in space and time of PCB-153 concentrations in air, sediment, soil and aquatic biota on a European scale.

    PubMed

    Hauck, Mara; Huijbregts, Mark A J; Hollander, Anne; Hendriks, A Jan; van de Meent, Dik

    2010-08-15

    We evaluated various modeling options for estimating concentrations of PCB-153 in the environment and in biota across Europe, using a nested multimedia fate model coupled with a bioaccumulation model. The most detailed model set up estimates concentrations in air, soil, fresh water sediment and fresh water biota with spatially explicit environmental characteristics and spatially explicit emissions to air and water in the period 1930-2005. Model performance was evaluated with the root mean square error (RMSE(log)), based on the difference between estimated and measured concentrations. The RMSE(log) was 5.4 for air, 5.6-6.3 for sediment and biota, and 5.5 for soil in the most detailed model scenario. Generally, model estimations tended to underestimate observed values for all compartments, except air. The decline in observed concentrations was also slightly underestimated by the model for the period where measurements were available (1989-2002). Applying a generic model setup with averaged emissions and averaged environmental characteristics, the RMSE(log) increased to 21 for air and 49 for sediment. For soil the RMSE(log) decreased to 3.5. We found that including spatial variation in emissions was most relevant for all compartments, except soil, while including spatial variation in environmental characteristics was less influential. For improving predictions of concentrations in sediment and aquatic biota, including emissions to water was found to be relevant as well. Copyright 2009 Elsevier B.V. All rights reserved.

  18. Evaluation methods for assessing effectiveness of in situ remediation of soil and sediment contaminated with organic pollutants and heavy metals.

    PubMed

    Song, Biao; Zeng, Guangming; Gong, Jilai; Liang, Jie; Xu, Piao; Liu, Zhifeng; Zhang, Yi; Zhang, Chen; Cheng, Min; Liu, Yang; Ye, Shujing; Yi, Huan; Ren, Xiaoya

    2017-08-01

    Soil and sediment contamination has become a critical issue worldwide due to its great harm to the ecological environment and public health. In recent years, many remediation technologies including physical, chemical, biological, and combined methods have been proposed and adopted for the purpose of solving the problems of soil and sediment contamination. However, current research on evaluation methods for assessing these remediation technologies is scattered and lacks valid and integrated evaluation methods for assessing the remediation effectiveness. This paper provides a comprehensive review with an environmental perspective on the evaluation methods for assessing the effectiveness of in situ remediation of soil and sediment contaminated with organic pollutants and heavy metals. The review systematically summarizes recent exploration and attempts of the remediation effectiveness assessment based on the content of pollutants, soil and sediment characteristics, and ecological risks. Moreover, limitations and future research needs of the practical assessment are discussed. These limitations are not conducive to the implementation of the abatement and control programs for soil and sediment contamination. Therefore, more attention should be paid to the evaluation methods for assessing the remediation effectiveness while developing new in situ remediation technologies in future research. Copyright © 2017 Elsevier Ltd. All rights reserved.

  19. Retention and Migration of Chlorpyrifos in Aquatic Sediments and Soils

    NASA Astrophysics Data System (ADS)

    Gebremariam, S. Y.; Beutel, M.; Yonge, D.; Flury, M.; Harsh, J. B.

    2010-12-01

    The accurate description of the fate and transport of potentially toxic agricultural pesticides in sediments and soils is of great interest to environmental scientists and regulators. Of particular concern is the widely documented detection of agricultural pesticides and their byproducts in drinking water wells. This presentation discusses results of a study of the fate and transport of chlorpyrifos, a strongly hydrophobic organophosphate-pesticide, in sediments and soils collected from a range of aquatic environments. Using radio-labeled chlorpyrifos, this study is unique in its comprehensive nature and focus on aquatic sediments, for which studies involving pesticide fate and transport are limited. Study components include: (1) batch equilibrium experiments to evaluate sorption/desorption parameters; (2) kinetic and non-equilibrium sorption experiments using miniaturized flow-cells; (3) column experiments to understand patterns of pesticide break through; and (4) numerical modeling of chlorpyrifos transport through aquatic sediments and soils. Initial results show that chlorpyrifos sorption, when corrected for reversible sorption to container walls, exhibited two component sorption, a large irreversible fraction and a smaller reversible fraction that can act as a secondary source. In addition, of a wide range of soil parameters measured, organic carbon content exhibited the highest correlation with chlorpyrifos retention in cranberry field soils. Simulation models developed in this study, which account for hysteretic and nonlinear sorption, will help to better predict the fate of chlorpyrifos and other hydrophobic chemicals in sediments and soils.

  20. Relationship of pyrogenic polycyclic aromatic hydrocarbons contamination among environmental solid media.

    PubMed

    Kim, Dong Won; Kim, Seung Kyu; Lee, Dong Soo

    2009-06-01

    This study compared the contamination levels and compositional characteristics of PAHs in soil, SS and sediment to understand the cross media characteristics among the three solid media and ecological risk implications for the purpose to help manage in a more integrated manner the environmental quality objectives or the ecological risk in the media. The study area included urban (metropolis and industrial zone), suburban and rural sites. Seasonal samples were concurrently collected in surface soils, surface waters (dissolved and suspended solid (SS) phases separately) and sediments. The emission estimate and source characterizing PAH indices consistently indicated that PAHs were from pyrogenic sources. The level of total PAHs in soil declined along the wind direction from the urban areas to the rural areas. The sorption power of soil appeared distinctly different between the urban and rural areas. The contamination levels and PAH profiles in soil and sediment were closely related to each other while no such correlation was observed between SS and sediment or SS and soil. Comparisons of the observed partitioning coefficients with three different partitioning equilibrium models strongly suggested that PAHs in water appeared to undergo partitioning among the dissolved phase in water, dissolved organic matter, and organic and soot carbons in SS, which might account for the level and profile of PAHs in SS that were not correlated with those in soil or sediment. The observed results suggested that PAHs of pyrogenic origins entered into soil, sediment, and water by the atmospheric deposition and subsequent other cross-media transfers of PAHs. The results also evidenced that sediments were principally contaminated with PAHs delivered via surface run-off from soil although in the urban areas the run-off influence appeared less immediate than in the rural areas. Environmental quality objectives for PAHs in soil and sediment should be set in a coherent manner and the protection efforts for the sediment quality should be made with the consideration of the soil quality particularly where the river bottom sediment is renewed periodically with eroded soil due to heavy rain and/or large river regime coefficient. In spite of the difference in PAH profiles among the three solid media, BaP commonly appeared to present the greatest TEQ, suggesting that strict regulation of BaP is necessary to efficiently and substantially minimize the total risk of the environmental PAHs.

  1. Analytical results from an environmental investigation of six sites on Kirtland Air Force Base, New Mexico, 1993-94

    USGS Publications Warehouse

    Wilcox, Ralph

    1995-01-01

    The six sites investigated include silver recovery units; a buried caustic drain line; a neutralization pit; an evaporation/infiltration pond; the Manzano fire training area; and a waste oil underground storage tank. Environmental samples of soil, pond sediment, soil gas, and water and gas in floor drains were collected and analyzed. Field quality-control samples were also collected and analyzed in association with the environmental samples. The six sites were investigated because past or current activities could have resulted in contamination of soil, pond sediment, or water and sediment in drains.

  2. Modeling of Soil Erosion by IntErO model: The Case Study of the Novsicki Potok Watershed, of the Prokletije high mountains of Montenegro

    NASA Astrophysics Data System (ADS)

    Spalevic, Velibor; Al-Turki, Ali M.; Barovic, Goran; Leandro Naves Silva, Marx; Djurovic, Nevenka; Soares Souza, Walisson; Veloso Gomes Batista, Pedro; Curovic, Milic

    2016-04-01

    The application of soil conservation programs to combat erosion and sedimentation are significantly contributing to the protection of the natural resources. Watershed management practices include the assessment of Physical-Geographical, Climate, Geological, Pedological characteristics, including the analysis of Land Use of the regions concerned. The policy makers are increasingly looking for the different land uses and climatic scenarios that can be used for valuable projections for watershed management. To increase knowledge about those processes, use of hydrological and soil erosion models is needed and that is allowing quantification of soil redistribution and sediment productions. We focused on soil erosion processes in one of Northern Montenegrin mountain watersheds, the Novsicki Potok Watershed of the Polimlje River Basin, using modeling techniques: the IntErO model for calculation of runoff and soil loss. The model outcomes were validated through measurements of lake sediment deposition at the Potpec hydropower plant dam. Our findings indicate a medium potential of soil erosion risk. With 464 m³ yr-1 of annual sediment yield, corresponding to an area-specific sediment yield of 270 m³km-2 yr-1, the Novsicki Potok drainage basin belongs to the Montenegrin basins with the medium sediment discharge; according to the erosion type, it is surface erosion. The value of the Z coefficient was calculated on 0.403, what indicates that the river basin belongs to 3rd destruction category (of five). Our results suggest that the calculated peak discharge from the river basin was 82 m3s-1 for the incidence of 100 years. According to our analysis there is a possibility for large flood waves to appear in the studied river basin. With this research we, to some extent, improved the knowledge on the status of sediment yield and runoff of the river basins of Montenegro, where the map of Soil erosion is still not prepared. The IntErO model we used in this study is relatively novel concept and is highly recommended for soil erosion modelling in other river basins similar to the studied watershed, because of its simple identification of critical areas affected by the soil loss caused by soil erosion.

  3. Regional Geochemical Results from Analyses of Stream-Water, Stream-Sediment, Soil, Soil-Water, Bedrock, and Vegetation Samples, Tangle Lakes District, Alaska

    USGS Publications Warehouse

    Wang, Bronwen; Gough, L.P.; Wanty, R.B.; Lee, G.K.; Vohden, James; O'Neill, J. M.; Kerin, L.J.

    2008-01-01

    We report chemical analyses of stream-water, stream-sediment, soil, soil-water, bedrock, and vegetation samples collected from the headwaters of the Delta River (Tangle Lakes District, Mount Hayes 1:250,000-scale quadrangle) in east-central Alaska for the period June 20-25, 2006. Additionally, we present mineralogic analyses of stream sediment, concentrated by panning. The study area includes the southwestward extent of the Bureau of Land Management (BLM) Delta River Mining District (Bittenbender and others, 2007), including parts of the Delta River Archeological District, and encompasses an area of about 500 km2(approximately bordered by the Denali Highway to the south, near Round Tangle Lake, northward to the foothills of the Alaska Range (fig. 1). The primary focus of this study was the chemical characterization of native materials, especially surface-water and sediment samples, of first-order streams from the headwaters of the Delta River. The impetus for this work was the need, expressed by the Alaska Department of Natural Resources (ADNR), for an inventory of geochemical and hydrogeochemical baseline information about the Delta River Mining District. This information is needed because of a major upturn in exploration, drilling, and general mineral-resources assessments in the region since the late 1990s. Currently, the study area, called the 'MAN Project' area is being explored by Pure Nickel, Inc. (http://www.purenickel.com/s/MAN_Alaska.asp), and includes both Cu-Au-Ag and Ni-Cu-PGE (Pt-Pd-Au-Ag) mining claims. Geochemical data on surface-water, stream-sediment, soil, soil-water, grayleaf willow (Salix glauca L.), and limited bedrock samples are provided along with the analytical methodologies used and panned-concentrate mineralogy. We are releasing the data at this time with only minimal interpretation.

  4. Hydraulic-based empirical model for sediment and soil organic carbon loss on steep slopes for extreme rainstorms on the Chinese loess Plateau

    NASA Astrophysics Data System (ADS)

    Liu, L.; Li, Z. W.; Nie, X. D.; He, J. J.; Huang, B.; Chang, X. F.; Liu, C.; Xiao, H. B.; Wang, D. Y.

    2017-11-01

    Building a hydraulic-based empirical model for sediment and soil organic carbon (SOC) loss is significant because of the complex erosion process that includes gravitational erosion, ephemeral gully, and gully erosion for loess soils. To address this issue, a simulation of rainfall experiments was conducted in a 1 m × 5 m box on slope gradients of 15°, 20°, and 25° for four typical loess soils with different textures, namely, Ansai, Changwu, Suide, and Yangling. The simulated rainfall of 120 mm h-1 lasted for 45 min. Among the five hydraulic factors (i.e., flow velocity, runoff depth, shear stress, stream power, and unit stream power), flow velocity and stream power showed close relationships with SOC concentration, especially the average flow velocity at 2 m from the outlet where the runoff attained the maximum sediment load. Flow velocity controlled SOC enrichment by affecting the suspension-saltation transport associated with the clay and silt contents in sediments. In consideration of runoff rate, average flow velocity at 2 m location from the outlet, and slope steepness as input variables, a hydraulic-based sediment and SOC loss model was built on the basis of the relationships of hydraulic factors to sediment and SOC loss. Nonlinear regression models were built to calculate the parameters of the model. The difference between the effective and dispersed median diameter (δD50) or the SOC content of the original soil served as the independent variable. The hydraulic-based sediment and SOC loss model exhibited good performance for the Suide and Changwu soils, that is, these soils contained lower amounts of aggregates than those of Ansai and Yangling soils. The hydraulic-based empirical model for sediment and SOC loss can serve as an important reference for physical-based sediment models and can bring new insights into SOC loss prediction when serious erosion occurs on steep slopes.

  5. Quantifying the main sediment sources in agricultural landscapes of Southern Brazil cultivated with conventional and conservation practices

    NASA Astrophysics Data System (ADS)

    Evrard, Olivier; Le Gall, Marion; Tiecher, Tales; Gomes Minella, Jean Paolo; Laceby, J. Patrick; Ayrault, Sophie

    2017-04-01

    Agricultural expansion that occurred in the 1960s in Southern Brazil significantly increased soil erosion and sediment supply to the river networks. To limit the deleterious impacts of soil erosion, conservation practices were progressively implemented in the 1990s, including the direct sowing of crops on a soil densely covered with plant residues, contour farming, the installation of ponds to trap sediment in the landscape and the use of crop rotations. However, there remains a lack of observational data to investigate the impact of these conservation practices on soil erosion and sediment supply. This data is crucial to protect soil resources and maintain the sustainability of food production systems in this region of the world characterized by a rapidly increasing population. Accordingly, sediment sources were investigated in the Guaporé catchment (2,032 km2) representative of the cultivated environments found in this part of the world. In the upper catchment, the landscape is characterized by gentle slopes and deep soils (Ferralsols, Nitisols) corresponding to the edge of the basaltic plateau. Soybean, corn and wheat under direct sowing are the main crops in this area. In contrast, steep and shallow soils (Luvisols, Acrisols, Leptosols) highly connected to the rivers are found in the lower catchment, where tobacco and corn fields are cultivated with conventional ploughing. These soil types were characterized by elemental geochemistry and 87Sr/86Sr ratios. Sediment sources were then modelled using the optimal suite of properties (87Sr/86Sr ratios, K, Ti, Co, As, Ba, and Pb). The results demonstrate that sediment collected at the catchment outlet during two hydrological years (2012-2014) mainly originated from downstream soils (Luvisols, Acrisols, Leptosols; 92±3%), with this proportion remaining stable throughout the monitoring period. This research indicates that conservation practices implemented in the upper catchment are effective and that similar methods should be applied to downstream soils in order to conserve soil resources and limit the degradation of freshwater environments.

  6. Phytoremediation management of selenium-laden drainage sediments in the San Luis Drain: a greenhouse feasibility study.

    PubMed

    Bañuelos, G S; Lin, Z-Q

    2005-11-01

    An estimated 100,000m(3) selenium (Se)-laden drainage sediment resides in the San Luis Drain (SLD) of Central California. This greenhouse study was undertaken to evaluate the feasibility of growing salt- and boron-tolerant plant species in sediment for reduction of Se content by plant extraction. Drainage sediment was collected from the SLD and mixed with control soil (i.e., uncontaminated soil) to the following ratios (sediment:control soil) by volume: 0:3 (i.e., control soil only), 1:2 (i.e., 1/3 sediment and 2/3 control soil), 2:1 (i.e., 2/3 sediment and 1/3 control soil), and 3:0 (i.e., sediment only). Salt-tolerant plant species consisted of canola (Brassica napus var. Hyola 420), tall fescue (Festuca arundinacea var. Au Triumph), salado grass (Sporobulus airoides), and cordgrass (Spartina patens var. Flageo). Increased ratios of sediment:soil resulted in decreased dry matter production for all tested plant species; especially at ratios of sediment:soil greater than 1:2. Plant Se concentrations (mgkg(-1) DM) ranged as follows for plant species at all ratios of sediment:soil: canola (51-72), tall fescue (16-36), and cordgrass and salado grass (9-14). Total Se concentrations in the soil were at least 20% lower at postharvest compared to preplant concentrations for all plant species at each ratio of sediment:soil. In contrast, water-extractable Se concentrations in the soil were at least three times higher at postharvest than at preplant for all plant species, irrespective of the ratio of sediment:soil. Leaching of Se occurred in irrigated bare pots from each respective ratio of sediment:soil over a duration of 60 days. Based upon the downward movement of Se in bare pots of sediment:soil, it may be more prudent to leave the drainage sediment in the SLD, incorporate clean soil, and then grow low maintenance salt-tolerant plants (e.g., cordgrass, salado grass) in the concrete-lined canal. By this means, possible contamination of groundwater with soluble Se will be eliminated, while phytoremediation slowly reduces Se content in the drainage sediment.

  7. Soil erosion and sediment connectivity modelling in Burgundy vineyards: case study of Mercurey, France

    NASA Astrophysics Data System (ADS)

    Fressard, Mathieu; Cossart, Étienne; Lejot, Jêrome; Michel, Kristell; Perret, Franck; Christol, Aurélien; Mathian, Hélène; Navratil, Oldrich

    2017-04-01

    This research aims at assessing the impact of agricultural landscape structure on soil erosion and sediment connectivity at the catchment scale. The investigations were conducted the vineyards of Mercurey (Burgundy, France), characterized by important issues related to soil loss, flash floods and associated management infrastructures maintenance. The methodology is based on two main steps that include (1) field investigations and (2) modelling. The field investigations consists in DEM acquisition by LiDAR imaging from a drone, soil mapping and human infrastructures impacting runoff classification and mapping (such as crop rows, storm water-basins, drainage network, roads, etc.). These data aims at supplying the models with field observations. The modelling strategy is based on two main steps: First, the modelling of soil sensitivity to erosion, using the spatial application of the RUSLE equation. Secondly, to assess the sediment connectivity in this area, a model based on graph theory developed by Cossart and Fressard (2017) is tested. The results allow defining the influence of different anthropogenic structures on the sediment connectivity and soil erosion at the basin scale. A set of sub-basins influenced by various anthropogenic infrastructures have been identified and show contrasted sensitivities to erosion. The modelling of sediment connectivity show that the runoff pattern is strongly influenced by the vine rows orientation and the drainage network. I has also permitted to identify non collected (by storm water-basins) areas that strongly contribute to the turbid floods sediment supply and to soil loss during high intensity precipitations events.

  8. Calculating sediment discharge from a highway construction site in central Pennsylvania

    USGS Publications Warehouse

    Reed, L.A.; Ward, J.R.; Wetzel, K.L.

    1985-01-01

    The Pennsylvania Department of Transportation, the Federal Highway Administration, and the U.S. Geological Survey have cooperated in a study to evaluate two methods of predicting sediment yields during highway construction. Sediment yields were calculated using the Universal Soil Loss and the Younkin Sediment Prediction Equations. Results were compared to the actual measured values, and standard errors and coefficients of correlation were calculated. Sediment discharge from the construction area was determined for storms that occurred during construction of Interstate 81 in a 0.38-square mile basin near Harrisburg, Pennsylvania. Precipitation data tabulated included total rainfall, maximum 30-minute rainfall, kinetic energy, and the erosive index of the precipitation. Highway construction data tabulated included the area disturbed by clearing and grubbing, the area in cuts and fills, the average depths of cuts and fills, the area seeded and mulched, and the area paved. Using the Universal Soil Loss Equation, sediment discharge from the construction area was calculated for storms. The standard error of estimate was 0.40 (about 105 percent), and the coefficient of correlation was 0.79. Sediment discharge from the construction area was also calculated using the Younkin Equation. The standard error of estimate of 0.42 (about 110 percent), and the coefficient of correlation of 0.77 are comparable to those from the Universal Soil Loss Equation.

  9. Wind erodibility of soils at Fort Irwin, California (Mojave Desert), USA, before and after trampling disturbance: Implications for land management

    USGS Publications Warehouse

    Belnap, J.; Phillips, S.L.; Herrick, J.E.; Johansen, J.R.

    2007-01-01

    Recently disturbed and 'control' (i.e. less recently disturbed) soils in the Mojave Desert were compared for their vulnerability to wind erosion, using a wind tunnel, before and after being experimentally trampled. Before trampling, control sites had greater cyanobacterial biomass, soil surface stability, threshold friction velocities (TFV, i.e. the wind speed required to move soil particles), and sediment yield than sites that had been more recently disturbed by military manoeuvres. After trampling, all sites showed a large drop in TFVs and a concomitant increase in sediment yield. Simple correlation analyses showed that the decline in TFVs and the rise in sediment yield were significantly related to cyanobacterial biomass (as indicated by soil chlorophyll a). However, chlorophyll a amounts were very low compared to chlorophyll a amounts found at cooler desert sites, where chlorophyll a is often the most important factor in determining TFV and sediment yield. Multiple regression analyses showed that other factors at Fort Irwin were more important than cyanobacterial biomass in determining the overall site susceptibility to wind erosion. These factors included soil texture (especially the fine, medium and coarse sand fractions), rock cover, and the inherent stability of the soil (as indicated by subsurface soil stability tests). Thus, our results indicate that there is a threshold of biomass below which cyanobacterial crusts are not the dominant factor in soil vulnerability to wind erosion. Most undisturbed soil surfaces in the Mojave Desert region produce very little sediment, but even moderate disturbance increases soil loss from these sites. Because current weathering rates and dust inputs are very low, soil formation rates are low as well. Therefore, soil loss in this region is likely to have long-term effects.

  10. Effects of rainfall intensity and slope gradient on runoff and sediment yield characteristics of bare loess soil.

    PubMed

    Wu, Lei; Peng, Mengling; Qiao, Shanshan; Ma, Xiao-Yi

    2018-02-01

    Soil erosion is a universal phenomenon on the Loess Plateau but it exhibits complex and typical mechanism which makes it difficult to understand soil loss laws on slopes. We design artificial simulated rainfall experiments including six rainfall intensities (45, 60, 75, 90, 105, 120 mm/h) and five slopes (5°, 10°, 15°, 20°, 25°) to reveal the fundamental changing trends of runoff and sediment yield on bare loess soil. Here, we show that the runoff yield within the initial 15 min increased rapidly and its trend gradually became stable. Trends of sediment yield under different rainfall intensities are various. The linear correlation between runoff and rainfall intensity is obvious for different slopes, but the correlations between sediment yield and rainfall intensity are weak. Runoff and sediment yield on the slope surface both presents an increasing trend when the rainfall intensity increases from 45 mm/h to 120 mm/h, but the increasing trend of runoff yield is higher than that of sediment yield. The sediment yield also has an overall increasing trend when the slope changes from 5° to 25°, but the trend of runoff yield is not obvious. Our results may provide data support and underlying insights needed to guide the management of soil conservation planning on the Loess Plateau.

  11. Estimation of Sediment Sources Using Selected Chemical Tracers in the Perry Lake and Lake Wabaunsee Basins, Northeast Kansas

    USGS Publications Warehouse

    Juracek, Kyle E.; Ziegler, Andrew C.

    2007-01-01

    In Kansas and nationally, stream and lake sediment is a primary concern as related to several important issues including water quality and reservoir water-storage capacity. The ability to achieve meaningful decreases in sediment loads to reservoirs requires a determination of the relative importance of sediment sources within the contributing basins. To investigate sources of sediment within the Perry Lake and Lake Wabaunsee Basins of northeast Kansas, representative samples of channel-bank sources, surface-soil sources (cropland and grassland), and reservoir bottom sediment were collected, analyzed, and compared. Subbasins sampled within the Perry Lake Basin included Atchison County Lake, Banner Creek Reservoir, Gregg Creek, Mission Lake, and Walnut Creek. The samples were sieved to isolate the less than 63-micron fraction (that is, the silt and clay) and analyzed for selected nutrients (total nitrogen and total phosphorus), organic and total carbon, 25 trace elements, and the radionuclide cesium-137 (137Cs). To determine which of the 30 constituents provided the best ability to discriminate between channel-bank and surface-soil sources in the two basins, four selection criteria were used. To be selected, it was required that the candidate constituent (1) was detectable, (2) had concentrations or activities that varied substantially and consistently between the sources, (3) had concentration or activity ranges that did not overlap between the sources, and (4) had concentration or activity differences between the sources that were statistically significant. On the basis of the four selection criteria, total nitrogen (TN), total phosphorus (TP), total organic carbon (TOC), and 137Cs were selected. Of the four selected constituents, 137Cs likely is the most reliable indicator of sediment source because it is known to be conservative in the environment. Trace elements were not selected because concentrations in the channel-bank and surface-soil sources generally were similar or did not vary in a consistent manner. To further account for differences in particle-size composition between the sources and the reservoir bottom sediment prior to the sediment-source estimations, constituent ratio and clay-normalization techniques were used. Computed ratios included the ratio of TOC to TN, TOC to TP, and TN to TP. Constituent concentrations (TN, TP, TOC) and activities (137Cs) were normalized by dividing by the percentage of clay. Thus, the sediment-source estimations involved the use of seven sediment-source indicators (that is, three constituent ratios and the clay-normalized concentration or activity for four constituents). Sediment-source estimation for each reservoir was based on a comparison between the reservoir bottom sediment and the end member channel-bank and surface-soil sources. Within the Perry Lake Basin, the seven-indicator consensus indicated that both channel-bank and surface-soil sources were important contributors of the sediment deposited in Atchison County Lake and Banner Creek Reservoir, whereas channel-bank sources were the dominant source of sediment for Mission Lake. On the sole basis of 137Cs activity, surface-soil sources contributed the most sediment to Atchison County Lake, and channel-bank sources contributed the most sediment to Banner Creek Reservoir and Mission Lake. For Perry Lake, both the seven-indicator consensus and 137Cs indicated that channel-bank sources were dominant and that channel-bank sources increased in importance with distance downstream in the Perry Lake Basin. For Lake Wabaunsee, the seven-indicator consensus and 137Cs indicated that both channel-bank and surface-soil sources were important. Given that the relative contribution of sediment from channel-bank and surface-soil sources can vary within and between basins and over time, basin-specific strategies for sediment management and monitoring are appropriate.

  12. SSMILES.

    ERIC Educational Resources Information Center

    Sunal, Dennis W.; Tracy, Dyanne M., Eds.

    1991-01-01

    A learning cycle activity which allows students to practice process skills by sieving different size fractions of sediments is described. Science topics include weathering, erosion, streams, sedimentation, sedimentary rocks, soils, beaches, dunes, or glacial deposits. Mathematics topics include number lines, ordinal numbers, greater than/less…

  13. Sediment and Particular Organic Carbon (POC) fluxes changes over the past decades in the Yellow River system

    NASA Astrophysics Data System (ADS)

    Lu, Xixi; Ran, Lishan

    2015-04-01

    The Yellow River system used to have very high sediment export to ocean (around 1.5 Gt/yr in the 1950s) because of severe soil erosion on the Loess Plateau. However, its sediment export has declined to <0.25 Gt/yr in recent years (in the 2000s), mainly due to human activities like construction of reservoirs and check dams and other soil and water conservations such as construction of terraces and vegetation restoration. Such drastic reduction in soil erosion and sediment flux and subsequently in associated Particular Organic Carbon (POC) transport can potentially play a significant role in carbon cycling. Through the sediment flux budget we examined POC budget and carbon sequestration through vegetation restoration and various soil and water conservations including reservoirs construction over the past decades in the Yellow River system. Landsat imageries were used to delineate the reservoirs and check dams for estimating the sediment trapping. The reservoirs and check dams trapped a total amount of sediment 0.94 Gt/yr, equivalent to 6.5 Mt C. Soil erosion controls through vegetation restoration and terrace construction reduced soil erosion 1.82 Gt/yr, equivalent to 12 Mt C. The annual NPP increased from 0.150 Gt C in 2000 to 0.1889 Gt C in 2010 with an average increment rate of 3.4 Mt C per year over the recent decade (from 2000 to 2010) through vegetation restoration. The total carbon stabilized on slope systems through soil erosion controls (12 Mt C per year) was much higher than the direct carbon sequestration via vegetation restoration (3.4 Mt C per year), indicating the importance of horizontal carbon mobilization in carbon cycling, albeit a high estimate uncertainty.

  14. Using sediment particle size distribution to evaluate sediment sources in the Tobacco Creek Watershed

    NASA Astrophysics Data System (ADS)

    Liu, Cenwei; Lobb, David; Li, Sheng; Owens, Philip; Kuzyk, ZouZou

    2014-05-01

    Lake Winnipeg has recently brought attention to the deteriorated water quality due to in part to nutrient and sediment input from agricultural land. Improving water quality in Lake Winnipeg requires the knowledge of the sediment sources within this ecosystem. There are a variety of environmental fingerprinting techniques have been successfully used in the assessment of sediment sources. In this study, we used particle size distribution to evaluate spatial and temporal variations of suspended sediment and potential sediment sources collected in the Tobacco Creek Watershed in Manitoba, Canada. The particle size distribution of suspended sediment can reflect the origin of sediment and processes during sediment transport, deposition and remobilization within the watershed. The objectives of this study were to quantify visually observed spatial and temporal changes in sediment particles, and to assess the sediment source using a rapid and cost-effective fingerprinting technique based on particle size distribution. The suspended sediment was collected by sediment traps twice a year during rainfall and snowmelt periods from 2009 to 2012. The potential sediment sources included the top soil of cultivated field, riparian area and entire profile from stream banks. Suspended sediment and soil samples were pre-wet with RO water and sieved through 600 μm sieve before analyzing. Particle size distribution of all samples was determined using a Malvern Mastersizer 2000S laser diffraction with the measurement range up to 600μm. Comparison of the results for different fractions of sediment showed significant difference in particle size distribution of suspended sediment between snowmelt and rainfall events. An important difference of particle size distribution also found between the cultivated soil and forest soil. This difference can be explained by different land uses which provided a distinct fingerprint of sediment. An overall improvement in water quality can be achieved by managing sediment according to the identified sediment sources in the watershed.

  15. Suspended sediment export in five intensive agricultural river catchments with contrasting land use and soil drainage characteristics

    NASA Astrophysics Data System (ADS)

    Sherriff, Sophie; Rowan, John; Melland, Alice; Jordan, Phil; Fenton, Owen; hUallacháin, Daire Ó.

    2015-04-01

    Soil erosion and sediment loss from land can have a negative impact on the chemical and ecological quality of freshwater resources. In catchments dominated by agriculture, prediction of soil erosion risk is complex due to the interaction of physical characteristics such as topography, soil erodibility, hydrological connectivity and climate. Robust measurement approaches facilitate the assessment of sediment loss magnitudes in relation to a range of agricultural settings. These approaches improve our understanding of critical sediment transfer periods and inform development of evidence-based and cost-effective management strategies. The aim of this study was to i) assess the efficacy of out-of-channel (ex-situ) suspended sediment measurement approaches, ii) to quantify the variability of sediment exported from five river catchments with varying hydrology and agricultural land uses over multiple years and iii) to investigate trends in relation to physical and land use characteristics when sediment data were compared between catchments. Sediment data were collected in five intensive agricultural river catchments in Ireland (3-11 km2) which featured contrasting land uses (predominantly intensive grassland or arable) and soil drainage classes (well, moderate and poor). High-resolution suspended sediment concentration data (SSC - using a calibrated turbidity proxy) were collected ex-situ and combined with in-stream discharge data measured at each catchment outlet to estimate suspended sediment yield (SSY - t km-2 yr-1). In two catchments additional in-stream turbidity monitoring equipment replicated ex-situ measurements including site specific calibration of individual in-stream and ex-situ turbidity probes. Depth-integrated samples were collected to assess the accuracy of both approaches. Method comparison results showed that true SSC values (from depth-integrated sampling) were predominantly within the 95% confidence interval of ex-situ predicted SSC consequently confirming the robust cross-validation of these results. Average annual SSCs and SSYs were higher in poorly drained catchments (17-27 t km-2 yr-1) than those with well drained soils (8-10 t km-2 yr-1). Catchments with both poorly-drained soils and land use dominated by tillage were most susceptible to field-scale soil erosion due to rapid establishment of overland flow pathways and periods of bare soils during cropping cycles. However results suggest that relatively high SSY may also occur in grassland catchments, particularly on poorly drained soils and with higher stocking densities and greater likelihood of channel bank erosion. Whilst the mean SSY rates are low by international standards, inter-annual variability was significant highlighting the spatial and temporal fluctuations in runoff and soil erosion risk. Such issues are of particular concern as Ireland pursues an agricultural policy of sustainable intensification. Effective soil erosion and sediment management should address catchment specific characteristics.

  16. Minor soil erosion contribution to denudation in Central Nepal Himalaya.

    NASA Astrophysics Data System (ADS)

    Morin, Guillaume; France-Lanord, Christian; Gallo, Florian; Lupker, Maarten; Lavé, Jérôme; Gajurel, Ananta

    2013-04-01

    In order to decipher river sediments provenance in terms of erosion processes, we characterized geochemical compositions of hillslope material coming from soils, glaciers and landslide, and compared them to rivers sediments. We focused our study on two South flank Himalayan catchments: (1) Khudi khola, as an example of small High Himalayan catchment (150 km2), undergoing severe precipitation, and rapid erosion ≈ 3.5 mm/yr [A] and (2) the Narayani-Gandak Transhimalayan basin (52000 km2) that drains the whole central Nepal. To assess the question, systematic samplings were conducted on hillslope material from different erosion processes in the basins. River sediment include daily sampling during the 2010 monsoon at two stations, and banks samples in different parts of the basins. Source rocks, soil and landslide samples, are compared to river sediment mobile to immobile element ratios, completed by hydration degree H2O+ analysis[2]. Data show that soils are clearly depleted in mobile elements Na, K, Ca, and highly hydrated compared to source rocks and other erosion products. In the Khudi basin, the contrast between soil and river sediment signatures allow to estimate that soil erosion represents less than 5% of the total sediment exported by the river. Most of the river sediment therefore derives from landslides inputs and to a lesser extent by barren high elevation sub-basins. This is further consistent with direct observation that, during monsoon, significant tributaries of the Khudi river do not export sediments. Considering that active landslide zones represent less than 0.5% of the total watershed area, it implies that erosion distribution is highly heterogeneous. Landslide erosion rate could reach more than 50 cm/yr in the landslide area. Sediments of the Narayani river are not significantly different from those of the Khudi in spite of more diverse geomorphology and larger area of the basin. Only H2O+ and Total Organic Carbon concentrations normalised to Al/Si ratios show distinctly higher values. This suggests that contribution of soil erosion is higher than in the Khudi basin. Nevertheless, soil erosion remains a minor source of sediments implying that more physical processes such as landslide and glaciers dominate the erosional flux. In spite of high deforestation and agricultural land-use [B], soil erosion does not represent an important source of sediments in Nepal Himalaya. [A] Gabet et al. (2008) Earth and Planetary Science Letters 267, 482-494. [B] Gardner et al. (2003) Applied Geography 23, 23-45.

  17. METHODS FOR THE DETERMINATION OF TOTAL ORGANIC ...

    EPA Pesticide Factsheets

    Organic matter in soils and sediments is widely distributed over the earth's surface occurring in almost all terrestrial and aquatic environments (Schnitzer, 1978). Soils and sediments contain a large variety of organic materials ranging from simple sugars and carbohydrates to the more complex proteins, fats, waxes, and organic acids. Important characteristics of the organic matter include their ability to: form water-soluble and water- insoluble complexes with metal ions and hydrous oxides; interact with clay minerals and bind particles together; sorb and desorb both naturally-occurring and anthropogenically-introduced organic compounds; absorb and release plant nutrients; and hold water in the soil environment. As a result of these characteristics, the determination of total organic carbon (a measure of one of the chemical components of organic matter that is often used as an indicator of its presence in a soil or sediment) is an essential part of any site characterization since its presence or absence can markedly influence how chemicals will react in the soil or sediment. Soil and sediment total organic carbon (TOC) determinations are typically requested with contaminant analyses as part of an ecological risk assessment data package. TOC contents may be used qualitatively to assess the nature of the sampling location (e.g., was it a depositional area) or may be used to normalize portions of the analytical chemistry data set (e.g., equilibrium partitioning).

  18. The early warning system of landslides and sediment runoffs using meteorological condition including rainfall-soil moisture index (Invited)

    NASA Astrophysics Data System (ADS)

    Kubota, T.; Silva, I. C.; Hasnawir, H.

    2009-12-01

    The research including observation of rain, soil moisture content and sediment discharge is conducted on a torrent in northern Kyushu whose geology consists of Paleozoic metamorphic rocks (mainly schist) and whose vegetation consists of mainly Japanese cypress and cedar. Soil depth is approximately 50cm in average and permeability k is 0.1~0.01 order. With data obtained by the observation for more than 4 years, standard rainfalls of warning and evacuation against the sudden sediment runoffs are analyzed. Then, the result was compared with the ones in Nuevo Leon Mexico (geology of schist, slate, k=0.01~0.001 order) and in southern Sulawesi Island Indonesia (volcanic geology, k=0.001~0.0001 order). Hitherto, various methods were proposed to analyze the warning critical standard for landslide disaster or large sediment discharge. In this study, we employed Hirano's element slope runoff theory, the Self Organized Criticality Assumption (SOC), and the Elementary Catastrophe Theory (ETC) to analyze the data, although the soil moisture fluctuation, meteorological condition such as upper air wind and dew point depression, the rainfall-soil moisture index provided by Japan Meteorological Agency was considered. The last one is a cutting edge technology based on the tank model calculation of soil moisture content combined with short term rainfall prediction which is a product of numerical simulation using radar image advection analysis compensated with surface rain data and with orographic rain effect. In Hirano's theory, we can describe the critical rain Rc and rain intensity Ric as following equation. Q/A/M/ cosθ = Ri ∫(r*cosθ)dt = Ri*R (1) ∴ Ric*Rc = C (2) Here, Q: sediment runoff or debris flow discharge, A: watershed area, M: function concerning with sediment deposit features on the upstream torrents or slopes (porosity, torrent bed slope gradient, sediment accumulation length and depth, cohesion), t: time, θ: torrent bed or hillside slope gradient, r: instant precipitation. C: constant, given as 8000 in Fukuoka (Kyushu, Japan), as 3750 in Sierra Madere Oriental (Nuevo Leon, Mexico), as 9000 in southern Sulawesi(Indonesia). Consequently, the forecast-warning system which has enough accuracy of 80% against sediment runoffs or debris flows for both wide range region with meteorological conditions and narrow region with the critical rain standard are established. However, in the region with lower soil permeability we may revise the standard rain by the compensation with the soil moisture content response such as increasing rate.

  19. Effects of Desert Dust on Nutrient Cycling in the San Juan Mountains, Colorado

    NASA Astrophysics Data System (ADS)

    Neff, J. C.; Farmer, L.; Painter, T. H.; Landry, C.; Reynolds, R.

    2005-12-01

    The San Juan Mountains of southwestern Colorado lie downwind from several major deserts and experience several dust-deposition events each year. These events appear related to storms that erode soils in the deserts of the western US and then deposit atmospheric dust from these soils during or after snowfall during large late winter and spring deposition events. To evaluate the biogeochemical implications of eolian deposition, we collected dust from distinct layers deposited into the seasonal snowpack. We also sampled soils and lake sediments in a high-elevation catchment in the San Juan Mountains. Atmospheric dust was characterized by measurements of chemical composition, Sr isotopic content and analysis of the organic and inorganic constituents of deposited eolian material. The origins of snowpack dust in the San Juans were analyzed using atmospheric tracer transport modeling. These analyses suggest that many dust events originate in southern Utah and northern Arizona, areas that have undergone substantial land use change through the 20th century and that experience severe wind erosion of soils during periodic severe droughts. Analyses of 87Sr/86Sr isotope ratios dust, soils, bedrock, and sediments suggest that eolian dust may compose as much as 90% of the near-surface soil (top 5 cm). In alpine lake sediments, Sr isotopes suggest a relatively recent (20th century) increase in the fraction of sediments derived from dust (relative to bedrock) and a similarly large contribution of dust to surface sediments. Sediment chemistry in two small alpine tarns show changes in Ca, Mg, Al, and Fe concentrations that imply increasing dust (vs. bedrock) contributions to lake sediments over the past 100-200 years. Increasing loading of Ca, Mg and P to alpine basins may have implications for alpine and sub-alpine biogeochemical cycling including water quality and plant nutrient use.

  20. Pyrosequencing reveals bacteria carried in different wind-eroded sediments.

    PubMed

    Gardner, Terrence; Acosta-Martinez, Veronica; Calderón, Francisco J; Zobeck, Ted M; Baddock, Matthew; Van Pelt, R Scott; Senwo, Zachary; Dowd, Scot; Cox, Stephen

    2012-01-01

    Little is known about the microbial communities carried in wind-eroded sediments from various soil types and land management systems. The novel technique of pyrosequencing promises to expand our understanding of the microbial diversity of soils and eroded sediments because it can sequence 10 to 100 times more DNA fragments than previous techniques, providing enhanced exploration into what microbes are being lost from soil due to wind erosion. Our study evaluated the bacterial diversity of two types of wind-eroded sediments collected from three different organic-rich soils in Michigan using a portable field wind tunnel. The wind-eroded sediments evaluated were a coarse sized fraction with 66% of particles >106 μm (coarse eroded sediment) and a finer eroded sediment with 72% of particles <106 μm. Our findings suggested that (i) bacteria carried in the coarser sediment and fine dust were effective fingerprints of the source soil, although their distribution may vary depending on the soil characteristics because certain bacteria may be more protected in soil surfaces than others; (ii) coarser wind-eroded sediment showed higher bacterial diversity than fine dust in two of the three soils evaluated; and (iii) certain bacteria were more predominant in fine dust (, , and ) than coarse sediment ( and ), revealing different locations and niches of bacteria in soil, which, depending on wind erosion processes, can have important implications on the soil sustainability and functioning. Infrared spectroscopy showed that wind erosion preferentially removes particular kinds of C from the soil that are lost via fine dust. Our study shows that eroded sediments remove the active labile organic soil particulates containing key microorganisms involved in soil biogeochemical processes, which can have a negative impact on the quality and functioning of the source soil. Copyright © by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, Inc.

  1. Sediment exchange to mitigate pollutant exposure in urban soil.

    PubMed

    Walsh, Daniel; Glass, Katherine; Morris, Samantha; Zhang, Horace; McRae, Isabel; Anderson, Noel; Alfieri, Alysha; Egendorf, Sara Perl; Holberton, Shana; Owrang, Shahandeh; Cheng, Zhongqi

    2018-05-15

    Urban soil is an ongoing source for lead (Pb) and other pollutant exposure. Sources of clean soil that are locally-available, abundant and inexpensive are needed to place a protective cover layer over degraded urban soil to eliminate direct and indirect pollutant exposures. This study evaluates a novel sediment exchange program recently established in New York City (NYC Clean Soil Bank, CSB) and found that direct exchange of surplus sediment extracted from urban construction projects satisfies these criteria. The CSB has high total yield with 4.2 × 10 5  t of sediment exchanged in five years. Average annual yield (8.5 × 10 4  t yr -1 ) would be sufficient to place a 15-cm (6-in.) sediment cover layer over 3.2 × 10 5  m 2 (80 acres) of impacted urban soil or 1380 community gardens. In a case study of sediment exchange to mitigate community garden soil contamination, Pb content in sediment ranged from 2 to 5 mg kg -1 . This sediment would reduce surface Pb concentrations more than 98% if it was used to encapsulate soil with Pb content exceeding USEPA residential soil standards (400 mg kg -1 ). The maximum observed sediment Pb content is a factor of 42 and 71 lower than median surface soil and garden soil in NYC, respectively. All costs (transportation, chemical testing, etc.) in the CSB are paid by the donor indicating that urban sediment exchange could be an ultra-low-cost source for urban soil mitigation. Urban-scale sediment exchange has advantages over existing national- or provincial-scale sediment exchanges because it can retain and upcycle local sediment resources to attain their highest and best use (e.g. lowering pollutant exposure), achieve circular urban materials metabolism, improve livability and maximize urban sustainability. Published by Elsevier Ltd.

  2. Effects of gamma-sterilization on the physico-chemical properties of natural sediments

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Bank, Tracy L.; Kukkadapu, Ravi K.; Madden, Andrew S.

    2008-06-30

    A series of experiments were completed to determine the effects of soil sterilization on various soil chemical properties including U(VI) sorption, soil pH, natural organic matter (NOM), cation exchange capacity (CEC), and iron oxidation state. Soils under investigation were a saprolitic sequence of interbedded weathered shale and limestone collected from the Oak Ridge Reservation (ORR). Sediments were sterilized by either steam sterilization at 121oC or by γ-irradiation using a cobalt-60 source. Subsamples of sediments were pretreated with dithionate-citrate-bicarbonate (DCB) and/or H2O2 to remove reducible Fe(III) oxides and NOM. Results from aerobic U(VI) sorption experiments indicated that γ-sterilized sediments sorbed moremore » U(VI) compared to non-sterile sediments. Results from sorption experiments completed using DCB and H2O2-treated samples indicated that the iron oxide and NOM fractions of the sediment accounted for the majority of U(VI) sorption and that γ-irradiation of these phases resulted in increased sorption of U(VI). Mössbauer spectra of γ-sterilized sedimentsdisplayed a decrease in the amount of ferric iron associated with goethite and a small increase in the amount of reduced iron in silicate minerals compared to spectra from non-sterile samples. Our results suggest that sterilization by γ-irradiation induced iron reduction that may have increased sorption of U(VI) on these sediments.« less

  3. Biogeochemistry of mercury in soils and sediments in a mining-impacted watershed, California

    NASA Astrophysics Data System (ADS)

    Holloway, J. M.; Goldhaber, M. B.

    2004-12-01

    The East Davis Creek watershed, located in the California Coast Ranges, is host to historic mines that provided mercury for recovery of gold in the Sierra Nevada goldfields in the mid-to-late 1800s. Bedrock in this watershed includes marine sedimentary rock, serpentinite, and hydrothermally altered serpentinite. Cinnabar (HgS) found in the altered serpentinite is the primary ore mineral for mercury. We evaluated the hypothesis that mercury is sequestered in soil organic matter downstream from source areas, releasing a fraction as water-soluble methylmercury. Microbial biomass and the presence of sulfur-reducing bacteria implicated in mercury methylation were quantified using phospholipid fatty acid (PLFA) data. Methylation incubations were performed on soil and sediment inoculated with water from Davis Creek Reservoir and sealed in glass containers under an anoxic headspace for 21 days. Methylmercury was measured on extracts of the soils at the start and at the end of the incubation period. Two sources of mercury to stream sediments, a soil with an altered serpentinite parent and mine tailings, were incubated. Stream sediment, an overbank deposit soil and a wetland soil forming from these sediments were also incubated. The overbank deposit soil is periodically flooded. The wetland soil around the edge of Davis Creek Reservoir is perennially saturated with water. The altered serpentinite soil and mine tailings had the highest total mercury concentrations (170 and 150 ng Hg /g, respectively). Total mercury concentrations in stream sediments are low (¡Ü1 ng Hg/g), with higher mercury concentrations in the overbank (3 ng/g) and wetland soils (18 ng Hg/g). Mercury leached from altered serpentinite soils and mine tailings may be transported downstream and sequestered through sorption to organic matter in the overbank and wetland soils. PLFA biomarkers for Desulfobacter (10Me16:0) and Desulfovibrio (i17:1) were present in all incubated materials, with lower concentrations in mine tailings and stream sediment relative to the three soils examined. Methylmercury was initially present in greater concentrations in the overbank deposit (23 ng HgMe/g) soils. The elevated methyl mercury in the overbank deposit soil may be due to the greater biomass of sulfur reducing bacteria indicated by the 10Me16:0 and i17:1 biomarkers. During the 21-day incubation, methylmercury increased from 0.6 to 15 ng HgMe/g in the wetland soil concomitantly with sulfate decreasing from 130 to 7.0 mg SO4=/g. Methylmercury concentrations did not change appreciably in the other soils, although sulfate decreased from 19 to 2.0 mg SO4=/g in the overbank deposit soil. These data suggest that overbank deposits and wetland soils sequester mercury leached from upstream sources, with a fraction of this mercury released through microbial methylation.

  4. Transfer of fallout radionuclides derived from Fukushima NPP accident: 1 year study on transfer of radionuclides through hydrological processes

    NASA Astrophysics Data System (ADS)

    Onda, Yuichi; Kato, Hiroaki; Patin, Jeremy; Yoshimura, Kazuya; Tsujimura, Maki; Wakahara, Taeko; Fukushima, Takehiko

    2013-04-01

    Previous experiences such as Chernobyl Nuclear Power Plant accident have confirmed that fallout radionuclides on the ground surface migrate through natural environment including soils and rivers. Therefore, in order to estimate future changes in radionuclide deposition, migration process of radionuclides in forests, soils, ground water, rivers should be monitored. However, such comprehensive studies on migration through forests, soils, ground water and rivers have not been conducted so far. Here, we present the following comprehensive investigation was conducted to confirm migration of radionuclides through natural environment including soils and rivers. 1)Study on depth distribution of radiocaesium in soils within forests, fields, and grassland 2)Confirmation of radionuclide distribution and investigation on migration in forests 3)Study on radionuclide migration due to soil erosion under different land use 4)Measurement of radionuclides entrained from natural environment including forests and soils 5)Investigation on radionuclide migration through soil water, ground water, stream water, spring water under different land use 6)Study on paddy-to-river transfer of radionuclides through suspended sediments 7)Study on river-to-ocean transfer of radionuclides via suspended sediments 8)Confirmation of radionuclide deposition in ponds and reservoirs

  5. Geomechanical Modeling of Gas Hydrate Bearing Sediments

    NASA Astrophysics Data System (ADS)

    Sanchez, M. J.; Gai, X., Sr.

    2015-12-01

    This contribution focuses on an advance geomechanical model for methane hydrate-bearing soils based on concepts of elasto-plasticity for strain hardening/softening soils and incorporates bonding and damage effects. The core of the proposed model includes: a hierarchical single surface critical state framework, sub-loading concepts for modeling the plastic strains generally observed inside the yield surface and a hydrate enhancement factor to account for the cementing effects provided by the presence of hydrates in sediments. The proposed framework has been validated against recently published experiments involving both, synthetic and natural hydrate soils, as well as different sediments types (i.e., different hydrate saturations, and different hydrates morphologies) and confinement conditions. The performance of the model in these different case studies was very satisfactory.

  6. An Innovative Method for Estimating Soil Retention at a ...

    EPA Pesticide Factsheets

    Planning for a sustainable future should include an accounting of services currently provided by ecosystems such as erosion control. Retention of soil improves fertility, increases water retention, and decreases sedimentation in streams and rivers. Landscapes patterns that facilitate these services could help reduce costs for flood control, dredging of reservoirs and waterways, while maintaining habitat for fish and other species important to recreational and tourism industries. Landscape scale geospatial data available for the continental United States was leveraged to estimate sediment erosion (RUSLE-based, Renard, et al. 1997) employing recent geospatial techniques of sediment delivery ratio (SDR) estimation (Cavalli, et al. 2013). The approach was designed to derive a quantitative approximation of the ecological services provided by vegetative cover, management practices, and other surface features with respect to protecting soils from the erosion processes of detachment, transport, and deposition. Quantities of soil retained on the landscape and potential erosion for multiple land cover scenarios relative to current (NLCD 2011) conditions were calculated for each calendar month, and summed to yield annual estimations at a 30-meter grid cell. Continental-scale data used included MODIS NDVI data (2000-2014) to estimate monthly USLE C-factors, gridded soil survey geographic (gSSURGO) soils data (annual USLE K factor), PRISM rainfall data (monthly USLE

  7. Soil erosion and sediment control laws. A review of state laws and their natural resource data requirements

    NASA Technical Reports Server (NTRS)

    Klein, S. B.

    1980-01-01

    Twenty states, the District of Columbia, and the Virgin Islands enacted erosion and sediment control legislation during the past decade to provide for the implementation or the strengthening of statewide erosion and sediment control plans for rural and/or urban lands. That legislation and the state programs developed to implement these laws are quoted and reviewed. The natural resource data requirements of each program are also extracted. The legislation includes amendments to conservation district laws, water quality laws, and erosion and sediment control laws. Laws which provides for legislative review of administrative regulations and LANDSAT applications and/or information systems that were involved in implementing or gathering data for a specific soil erosion and sediment control program are summarized as well as principal concerns affecting erosion and sediment control laws.

  8. (210)Pb as a tracer of soil erosion, sediment source area identification and particle transport in the terrestrial environment.

    PubMed

    Matisoff, Gerald

    2014-12-01

    Although (137)Cs has been used extensively to study soil erosion and particle transport in the terrestrial environment, there has been much less work using excess or unsupported (210)Pb ((210)Pbxs) to study the same processes. Furthermore, since (137)Cs activities in soils are decreasing because of radioactive decay, some locations have an added complication due to the addition of Chernobyl-derived (137)Cs, and the activities of (137)Cs in the southern hemisphere are low, there is a need to develop techniques that use (210)Pbxs to provide estimates of rates of soil erosion and particle transport. This paper reviews the current status of (210)Pbxs methods to quantify soil erosion rates, to identify and partition suspended sediment source areas, and to determine the transport rates of particles in the terrestrial landscape. Soil erosion rates determined using (210)Pbxs are based on the unsupported (210)Pb ((210)Pbxs) inventory in the soil, the depth distribution of (210)Pbxs, and a mass balance calibration ('conversion model') that relates the soil inventory to the erosion rate using a 'reference site' at which neither soil erosion nor soil deposition has occurred. In this paper several different models are presented to illustrate the effects of different model assumptions such as the timing, depth and rates of the surface soil mixing on the calculated erosion rates. The suitability of model assumptions, including estimates of the depositional flux of (210)Pbxs to the soil surface and the post-depositional mobility of (210)Pb are also discussed. (210)Pb can be used as one tracer to permit sediment source area identification. This sediment 'fingerprinting' has been extended far beyond using (210)Pb as a single radioisotope to include numerous radioactive and stable tracers and has been applied to identifying the source areas of suspended sediment based on underlying rock type, land use (roads, stream banks, channel beds, cultivated or uncultivated lands, pasture lands, forested lands, construction sites, undisturbed lands) or style of erosion (sheet wash, rills, bank). The transport time of particles in the terrestrial system can be estimated using (7)Be/(210)Pbxs radionuclide ratios and from mass balance models of (210)Pbxs and/or (7)Be in streams. Watershed residence times can be calculated from the radionuclide inventory and the erosional loss rate. Copyright © 2014 Elsevier Ltd. All rights reserved.

  9. Community and functional shifts in ammonia oxidizers across terrestrial and marine (soil/sediment) boundaries in two coastal Bay ecosystems.

    PubMed

    Zhang, Li-Mei; Duff, Aoife M; Smith, Cindy J

    2018-04-24

    Terrestrial-marine boundaries are significant sites of biogeochemical activity with delineated gradients from land to sea. While niche differentiation of ammonia-oxidizing archaea (AOA) and bacteria (AOB) driven by pH and nitrogen is well known, the patterns and environmental drivers of AOA and AOB community structure and activity across soil-sediment boundaries have not yet been determined. In this study, nitrification potential rate, community composition and transcriptional activity of AOA and AOB in soil, soil/sediment interface and sediments of two coastal Bays were characterized using a combination of field investigations and microcosm incubations. At DNA level, amoA gene abundances of AOA were significantly greater than AOB in soil, while in sediments AOB were significantly more abundant than AOA, but at the soil/sediment interface there were equal numbers of AOA and AOB amoA genes. Microcosm incubations provided further evidence, through qPCR and DGGE-sequencing analysis of amoA transcripts, that AOA were active in soil, AOB in sediment and both AOA and AOB were active at the soil/sediment interface. The AOA and AOB community composition shifted across the coastal soil-interface-sediment gradient with salinity and pH identified as major environmental drivers. © 2018 Society for Applied Microbiology and John Wiley & Sons Ltd.

  10. Amending soils with sediment material from constructed wetlands increases phosphorus sorption

    NASA Astrophysics Data System (ADS)

    Laakso, Johanna; Uusitalo, Risto; Leppänen, Janette; Yli-Halla, Markku

    2017-04-01

    Sediment of agricultural constructed wetlands (CWs) is comprised of matter eroded from surrounding fields. This material is rich in aluminium (Al) and iron (Fe) (hydr)oxides that have a high affinity for phosphorus (P). Sediment material returned to fields could therefore affect soil P retention characteristics. We incubated a clay soil with a high soil test P (STP, 24 mg PAc l-1; extracted with pH 4.65 ammonium acetate buffer) and a sandy loam with excessive STP (210 mg PAc l-1) for three weeks with increasing amounts of CW sediment: 0, 2, 5, 10 and 50% of the sample volume. After incubation, the soil-sediment mixtures were studied with the quantity/intensity (Q/I) technique, using chemical extractions and by exposing the mixtures to simulated rainfall. Sorption affinity for P regularly increased with increasing the sediment share of the mixtures, the 0% sediment content having the lowest and 50% sediment content the highest P sorption. With 0% sediment application, the value of equilibrium P concentration (EPC0) determined by Q/I technique, was 0.69 and 44.3 mg l-1 for clay soil and sandy loam, respectively. With 2-5% sediment amendment, the EPC0 decreased 13-36% for clay soil and 13-54% for sandy loam. The 50% sediment mixtures had EPC0 of 0.05 mg l-1 for both soils. At a practically feasible sediment addition rate of 5%, dissolved reactive P (DRP) in percolating water from simulated rainfall decreased by 55% in the clay soil and 54% in sandy loam (p<0.001 in both cases). Particulate-P (PP) also showed a decreasing trend with increasing sediment addition rate. Upon prolonged simulated rainfall, the decreasing effect of sediment on DRP and PP declined somewhat. The effects of sediment addition can be attributed partly to increased salt concentrations in the sediment, which have a short-term effect on P mobilisation, but mostly to increased concentrations of Al and Fe (hydr)oxides, increasing long-term P sorption capacity. Amending the soils with sediment material would decrease P solubility and might at large application rates hamper P uptake by plants or, on the other hand, the sediment amendment in the soil might reduce P losses by runoff.

  11. Beryllium-7 in vegetation, soil, sediment and runoff on the northern Loess Plateau.

    PubMed

    Zhang, Fengbao; Yang, Mingyi; Zhang, Jiaqiong

    2018-06-01

    Beryllium-7 ( 7 Be), as a potentially powerful tracer, was widely used to document soil redistribution and identify sediment sources in recent decades, but the quantity and distribution of 7 Be in vegetation, soil, sediment and runoff on the Loess Plateau have not been fully described. In this study, we measured 7 Be in vegetation, soil, sediment and runoff on the northern Loess Plateau of China and analyzed its variations during the rainy season to assess the potential of the 7 Be method for documenting soil redistribution and identifying sediment sources in a wide range of environments. The results indicated that vegetation, soil, and sediment samples showed higher levels and larger variations of 7 Be activities during the rainy season. The drying plants showed 7 Be mass activity that was more than three times higher than that of living and semi-decomposed plants. 7 Be mass activity in plants and sediment was much higher than in the soil. 7 Be activity in runoff water with a few submicron suspended particles varied slightly and was far lower than in plant, soil and sediment samples. The cumulative precipitation generally determined 7 Be inventory held by plants and soil. An inverse relationship was found between the 7 Be mass activity in sediment and the sediment amount. Globally, approximate 30% of the total 7 Be was held by plants in both the herbaceous and subshrub plots. Approximate 10% of the total 7 Be was lost with sediment from the bare plot. A very small proportion of 7 Be (1.18%-3.20%) was lost with runoff, and the vast majority of 7 Be was retained in the slope soil at the end of rainy season. Vegetation cover and soil erosion significantly affected the spatial distribution and variations of the 7 Be inventory in soil, providing a necessary condition for the development of a 7 Be method to document soil erosion on slopes with vegetation. Copyright © 2018 Elsevier B.V. All rights reserved.

  12. Preliminary study on detection sediment contamination in soil affected by the Indian Ocean giant tsunami 2004 in Aceh, Indonesia using laser-induced breakdown spectroscopy (LIBS)

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Idris, Nasrullah, E-mail: nasrullah.idris@unsyiah.ac.id; Ramli, Muliadi; Hedwig, Rinda

    This work is intended to asses the capability of LIBS for the detection of the tsunami sediment contamination in soil. LIBS apparatus used in this work consist of a laser system and an optical multichannel analyzer (OMA) system. The soil sample was collected from in Banda Aceh City, Aceh, Indonesia, the most affected region by the giant Indian Ocean tsunami 2004. The laser beam was focused onto surface of the soil pellet using a focusing lens to produce luminous plasma. The experiment was conducted under air as surrounding gas at 1 atmosphere. The emission spectral lines from the plasma weremore » detected by the OMA system. It was found that metal including heavy metals can surely be detected, thus implying the potent of LIBS technique as a fast screening tools of tsunami sediment contamination.« less

  13. Soil characteristics of sediment-amended baldcypress (Taxodium distichum) swamps of coastal Louisiana

    USGS Publications Warehouse

    Jiang, Ming; Middleton, Beth A.

    2011-01-01

    Amendments of sediment from dredging activities have played an important role in raising the elevation of sinking coastal wetlands. This study compared the soil characteristics of sediment- amended coastal swamps in the Barataria Preserve unit of Jean Lafitte National Historical Park and Preserve with natural swamps along Bayou des Familles. The sandy sediment amendments used in the coastal forests had different soil texture and characteristics than the more organic soils of the natural swamps. Three years after the application of these sediments on the sediment-amended swamps, dewatering and compaction of the sediment had occurred but the sediment still had high salinity and bulk density, and low organic matter content. The two sediment-amended swamps differed from each other in that Site 1 had a higher elevation (mean = 25 cm higher) and drier soil than Site 2. The effects of sediment in coastal forested wetlands require separate consideration from studies of salt marshes, e.g., the weight of the sediment might damage tree roots, or the amendments might influence soil stability during storms in a different way. Generally, this study suggests that shallower depths of sediment are more likely to yield environments beneficial to these sinking baldcypress swamps in coastal Louisiana.

  14. Selected pioneering works on humus in soils and sediments during the 20th century: A retrospective look from the International Humic Substances Society view

    NASA Astrophysics Data System (ADS)

    Feller, Christian; Brossard, Michel; Chen, Yona; Landa, Edward R.; Trichet, Jean

    Organic matter in general, and humic substances (HS) in particular, are involved in many processes in soils, sediments, rocks and natural waters. These include rock weathering, plant nutrition, pH buffering, trace metal mobility and toxicity, bioavailability, degradation and transport of hydrophobic organic chemicals, formation of disinfection by-products during water treatment, heterotrophic production in blackwater ecosystems and, more generally, the global carbon cycle. Before the 1970s, natural organic matter of different ecosystem pools ( i.e., soils, sediments, and natural waters) was often studied in isolation, although many similarities exist between them. This is particularly so for HS. In this historical context, a need appeared at the international level for bringing together environmental chemists, soil scientists, hydrologists, and geologists who were interested in HS to provide a forum for the exchange of ideas, to standardize analytical procedures and agree on definitions of HS. The International Humic Substances Society (IHSS) was founded in Denver, Colorado (USA) in 1981 with several objectives among them “to bring together scientists in the coal, soil, and water sciences with interests in humic substances” (home page of the IHSS web site: http://ihss.gatech.edu/ihss2/index.html). This paper presents selected pioneering works on humus in soils and sediments during the 20th century with a special focus on the links between the studies of soil HS and the formation, during early diagenesis, of the precursors of kerogens. Temporal coverage includes key contributions preceding the founding of the IHSS, and a brief history of the organization is presented.

  15. Nitrate retention capacity of milldam-impacted legacy sediments and relict A horizon soils

    NASA Astrophysics Data System (ADS)

    Weitzman, Julie N.; Kaye, Jason P.

    2017-05-01

    While eutrophication is often attributed to contemporary nutrient pollution, there is growing evidence that past practices, like the accumulation of legacy sediment behind historic milldams, are also important. Given their prevalence, there is a critical need to understand how N flows through, and is retained in, legacy sediments to improve predictions and management of N transport from uplands to streams in the context of climatic variability and land-use change. Our goal was to determine how nitrate (NO3-) is cycled through the soil of a legacy-sediment-strewn stream before and after soil drying. We extracted 10.16 cm radius intact soil columns that extended 30 cm into each of the three significant soil horizons at Big Spring Run (BSR) in Lancaster, Pennsylvania: surface legacy sediment characterized by a newly developing mineral A horizon soil, mid-layer legacy sediment consisting of mineral B horizon soil and a dark, organic-rich, buried relict A horizon soil. Columns were first preincubated at field capacity and then isotopically labeled nitrate (15NO3-) was added and allowed to drain to estimate retention. The columns were then air-dried and subsequently rewet with N-free water and allowed to drain to quantify the drought-induced loss of 15NO3- from the different horizons. We found the highest initial 15N retention in the mid-layer legacy sediment (17 ± 4 %) and buried relict A soil (14 ± 3 %) horizons, with significantly lower retention in the surface legacy sediment (6 ± 1 %) horizon. As expected, rewetting dry soil resulted in 15N losses in all horizons, with the greatest losses in the buried relict A horizon soil, followed by the mid-layer legacy sediment and surface legacy sediment horizons. The 15N remaining in the soil following the post-drought leaching was highest in the mid-layer legacy sediment, intermediate in the surface legacy sediment, and lowest in the buried relict A horizon soil. Fluctuations in the water table at BSR which affect saturation of the buried relict A horizon soil could lead to great loses of NO3- from the soil, while vertical flow through the legacy-sediment-rich soil profile that originates in the surface has the potential to retain more NO3-. Restoration that seeks to reconnect the groundwater and surface water, which will decrease the number of drying-rewetting events imposed on the relict A horizon soils, could initially lead to increased losses of NO3- to nearby stream waters.

  16. Fine Increment Soil Collector (FISC): A new device to support high resolution soil and sediment sampling for agri-environmental assessments

    NASA Astrophysics Data System (ADS)

    Mabit, Lionel; Meusburger, Katrin; Iurian, Andra-Rada; Owens, Philip N.; Toloza, Arsenio; Alewell, Christine

    2014-05-01

    Soil and sediment related research for terrestrial agri-environmental assessments requires accurate depth incremental sampling of soil and exposed sediment profiles. Existing coring equipment does not allow collecting soil/sediment increments at millimetre resolution. Therefore, the authors have designed an economic, portable, hand-operated surface soil/sediment sampler - the Fine Increment Soil Collector (FISC) - which allows extensive control of soil/sediment sampling process and easy recovery of the material collected by using a simple screw-thread extraction system. In comparison with existing sampling tools, the FISC has the following advantages and benefits: (i) it permits sampling of soil/sediment samples at the top of the profile; (ii) it is easy to adjust so as to collect soil/sediment at mm resolution; (iii) it is simple to operate by one single person; (iv) incremental samples can be performed in the field or at the laboratory; (v) it permits precise evaluation of bulk density at millimetre vertical resolution; and (vi) sample size can be tailored to analytical requirements. To illustrate the usefulness of the FISC in sampling soil and sediments for 7Be - a well-known cosmogenic soil tracer and fingerprinting tool - measurements, the sampler was tested in a forested soil located 45 km southeast of Vienna in Austria. The fine resolution increments of 7Be (i.e. 2.5 mm) affects directly the measurement of the 7Be total inventory but above all impacts the shape of the 7Be exponential profile which is needed to assess soil movement rates. The FISC can improve the determination of the depth distributions of other Fallout Radionuclides (FRN) - such as 137Cs, 210Pbexand239+240Pu - which are frequently used for soil erosion and sediment transport studies and/or sediment fingerprinting. Such a device also offers great potential to investigate FRN depth distributions associated with fallout events such as that associated with nuclear emergencies. Furthermore, prior to remediation activities - such as topsoil removal - in contaminated soils and sediments (e.g. by heavy metals, pesticides or nuclear power plant accident releases), basic environmental assessment often requires the determination of the extent and the depth penetration of the different contaminants, precision that can be provided by using the FISC.

  17. Soil/sediment characterization for 216-A-29 ditch

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Mitchell, R.M.

    1997-03-01

    This document provides a detailed description of the environmental samples collected from the 216-A-29 Ditch in 1988. Tables summarizing the laboratory data for radionuclides, metals, and soil chemistry are included.

  18. Contamination of water and soil by the Erdenet copper-molybdenum mine in Mongolia

    NASA Astrophysics Data System (ADS)

    Battogtokh, B.; Lee, J.; Woo, N. C.; Nyamjav, A.

    2013-12-01

    As one of the largest copper-molybdenum (Cu-Mo) mines in the world, the Erdenet Mine in Mongolia has been active since 1978, and is expected to continue operations for at least another 30 years. In this study, the potential impacts of mining activities on the soil and water environments have been evaluated. Water samples showed high concentrations of sulfate, calcium, magnesium, Mo, and arsenic, and high pH values in the order of high to low as follows: tailing water > Khangal River > groundwater. Statistical analysis and the δ2H and δ18O values of water samples indicate that the tailing water directly affects the stream water and indirectly affects groundwater through recharge processes. Soil and stream sediments are highly contaminated with Cu and Mo, which are major elements of ore minerals. Based on the contamination factor (CF), the pollution load index (PLI), and the degree of contamination (Cd), soil appears to be less contaminated than stream sediments. The soil particle size is similar to that of tailing materials, but stream sediments have much coarser particles, implying that the materials have different origins. Contamination levels in stream sediments display a tendency to decrease with distance from the mine, but no such changes are found in soil. Consequently, soil contamination by metals is attributable to wind-blown dusts from the tailing materials, and stream sediment contamination is caused by discharges from uncontained subgrade ore stock materials. Considering the evident impact on the soil and water environment, and the human health risk from the Erdenet Mine, measures to mitigate its environmental impact should be taken immediately including source control, the establishment of a systematic and continuous monitoring system, and a comprehensive risk assessment. Sampling locations around the Erdenet Mine

  19. Determination of Martian soil mineralogy and water content using the Thermal Analyzer for Planetary Soils (TAPS)

    NASA Technical Reports Server (NTRS)

    Gooding, James L.; Ming, Douglas W.; Allton, Judith H.; Byers, Terry B.; Dunn, Robert P.; Gibbons, Frank L.; Pate, Daniel B.; Polette, Thomas M.

    1992-01-01

    Physical and chemical interactions between the surface and atmosphere of Mars can be expected to embody a strong cause-and-effect relationship with the minerals comprising the martian regolith. Many of the minerals in soils and sediments are probably products of chemical weathering (involving surface/atmosphere or surface/hydrosphere reactions) that could be expected to subsequently influence the sorption of atmospheric gases and water vapor. Therefore, identification of the minerals in martian surface soils and sediments is essential for understanding both past and present interactions between the Mars surface and atmosphere. Clearly, the most definitive mineral analyses would be achieved with well-preserved samples returned to Earth-based laboratories. In advance of a Mars sample return mission, however, significant progress could be made with in situ experiments that fill current voids in knowledge about the presence or abundance of key soil minerals such as clays (layered-structured silicates), zeolites, and various salts, including carbonates. TAPS is intended to answer that challenge by providing first-order identification of soil and sediment minerals.

  20. Misrepresentation of hydro-erosional processes in rainfall simulations using disturbed soil samples

    NASA Astrophysics Data System (ADS)

    Thomaz, Edivaldo L.; Pereira, Adalberto A.

    2017-06-01

    Interrill erosion is a primary soil erosion process which consists of soil detachment by raindrop impact and particle transport by shallow flow. Interill erosion affects other soil erosion sub-processes, e.g., water infiltration, sealing, crusting, and rill initiation. Interrill erosion has been widely studied in laboratories, and the use of a sieved soil, i.e., disturbed soil, has become a standard method in laboratory experiments. The aims of our study are to evaluate the hydro-erosional response of undisturbed and disturbed soils in a laboratory experiment, and to quantify the extent to which hydraulic variables change during a rainstorm. We used a splash pan of 0.3 m width, 0.45 m length, and 0.1 m depth. A rainfall simulation of 58 mm h- 1 lasting for 30 min was conducted on seven replicates of undisturbed and disturbed soils. During the experiment, several hydro-physical parameters were measured, including splashed sediment, mean particle size, runoff, water infiltration, and soil moisture. We conclude that use of disturbed soil samples results in overestimation of interrill processes. Of the nine assessed parameters, four displayed greater responses in the undisturbed soil: infiltration, topsoil shear strength, mean particle size of eroded particles, and soil moisture. In the disturbed soil, five assessed parameters displayed greater responses: wash sediment, final runoff coefficient, runoff, splash, and sediment yield. Therefore, contextual soil properties are most suitable for understanding soil erosion, as well as for defining soil erodibility.

  1. Results of soil, ground-water, surface-water, and streambed-sediment sampling at Air Force Plane 85, Columbus, Ohio, 1996

    USGS Publications Warehouse

    Parnell, J.M.

    1997-01-01

    The U.S. Geological Survey (USGS), in cooperation with Aeronautical Systems Center, Environmental Management Directorate, Restoration Division, prepared the Surface- and Ground- Water Monitoring Work Plan for Air Force Plant 85 (AFP 85 or Plant), Columbus, Ohio, under the Air Force Installation Restoration Program to characterize any ground-water, surface-water, and soil contamination that may exist at AFP 85. The USGS began the study in November 1996. The Plant was divided into nine sampling areas, which included some previously investi gated study sites. The investigation activities included the collection and presentation of data taken during drilling and water-quality sampling. Data collection focused on the saturated and unsatur ated zones and surface water. Twenty-three soil borings were completed. Ten monitoring wells (six existing wells and four newly constructed monitoring wells) were selected for water-quality sam pling. Surface-water and streambed-sediment sampling locations were chosen to monitor flow onto and off of the Plant. Seven sites were sampled for both surface-water and streambed-sediment quality. This report presents data on the selected inorganic and organic constituents in soil, ground water, surface water, and streambed sediments at AFP 85. The methods of data collection and anal ysis also are included. Knowledge of the geologic and hydrologic setting could aid Aeronautical Systems Center, Environmental Management Directorate, Restoration Division, and its governing regulatory agencies in future remediation studies.

  2. Soil, Groundwater, Surface Water, and Sediments of Kennedy Space Center, Florida: Background Chemical and Physical Characteristics

    NASA Technical Reports Server (NTRS)

    Shmalzer, Paul A.; Hensley, Melissa A.; Mota, Mario; Hall, Carlton R.; Dunlevy, Colleen A.

    2000-01-01

    This study documented background chemical composition of soils, groundwater, surface; water, and sediments of Kennedy Space Center. Two hundred soil samples were collected, 20 each in 10 soil classes. Fifty-one groundwater wells were installed in 4 subaquifers of the Surficial Aquifer and sampled; there were 24 shallow, 16 intermediate, and 11 deep wells. Forty surface water and sediment samples were collected in major watershed basins. All samples were away from sites of known contamination. Samples were analyzed for organochlorine pesticides, aroclors, chlorinated herbicides, polycyclic aromatic hydrocarbons (PAH), total metals, and other parameters. All aroclors (6) were below detection in all media. Some organochlorine pesticides were detected at very low frequencies in soil, sediment, and surface water. Chlorinated herbicides were detected at very low frequencies in soil and sediments. PAH occurred in low frequencies in soiL, shallow groundwater, surface water, and sediments. Concentrations of some metals differed among soil classes, with subaquifers and depths, and among watershed basins for surface water but not sediments. Most of the variation in metal concentrations was natural, but agriculture had increased Cr, Cu, Mn, and Zn.

  3. Spatially resolved data on sediment transport: 1) field application examining fluorescent soil particle movement from tillage

    NASA Astrophysics Data System (ADS)

    Quinton, John; Hardy, Robert; Pates, Jacqueline; James, Michael

    2017-04-01

    Understanding where sediment originates from and where it travels to, in what quantities and at which rate is at the heart of many questions surrounding sediment transport. Progress towards unravelling these questions and deepening our understanding has come from a wide range of approaches, including laboratory and field experiments conducted at a variety of scales. In seeking to understand the connectivity of sources and sinks of sediment scientists have spent considerable energy in developing tracing technologies. These have included numerous studies that have relied on the chemical properties of the soil and sediment to establish source-sink connectivity, and the use of 137Ceasium, from radioactive fall-out, to map sediment redistribution. More recently there has been an upsurge in interest in the use of artificially applied soil tracers, including rare earth element oxides and magnetic minerals. However all these tracing methods have a significant drawback: they rely on the collection of samples to assess their concentration. This means that their spatial distribution cannot easily be established in situ and that the environment that is being studied is damaged by the sampling process; nor can data be collected in real time which allows a dynamic understanding of erosion and transport processes to be developed. Here we report on the field application of a fluorescent sand sized tracer at the hillslope scale during a tillage erosion experiment. Here we trialled both intensity based and particle counting methodologies for tracer enumeration. After simulating seven years of tillage on a hillslope we were able to precisely determine the distribution of the fluorescent tracer and also its incorporation and distribution within the soil profile. Single grains of tracer could be found over 35 m from the insertion point. In a second abstract we report on an application that combines novel fluorescent videography techniques with custom image processing to trace the motion of the fluorescent soil particles under rainfall. We demonstrate the tracking of multiple sub-millimetre particles simultaneously, establishing their position 50 times a second with submillimetre precision. From this we are able to visualise and quantify parameters such as distance and direction of travel.

  4. Ascribing soil erosion of hillslope components to river sediment yield.

    PubMed

    Nosrati, Kazem

    2017-06-01

    In recent decades, soil erosion has increased in catchments of Iran. It is, therefore, necessary to understand soil erosion processes and sources in order to mitigate this problem. Geomorphic landforms play an important role in influencing water erosion. Therefore, ascribing hillslope components soil erosion to river sediment yield could be useful for soil and sediment management in order to decrease the off-site effects related to downstream sedimentation areas. The main objectives of this study were to apply radionuclide tracers and soil organic carbon to determine relative contributions of hillslope component sediment sources in two land use types (forest and crop field) by using a Bayesian-mixing model, as well as to estimate the uncertainty in sediment fingerprinting in a mountainous catchment of western Iran. In this analysis, 137 Cs, 40 K, 238 U, 226 Ra, 232 Th and soil organic carbon tracers were measured in 32 different sampling sites from four hillslope component sediment sources (summit, shoulder, backslope, and toeslope) in forested and crop fields along with six bed sediment samples at the downstream reach of the catchment. To quantify the sediment source proportions, the Bayesian mixing model was based on (1) primary sediment sources and (2) combined primary and secondary sediment sources. The results of both approaches indicated that erosion from crop field shoulder dominated the sources of river sediments. The estimated contribution of crop field shoulder for all river samples was 63.7% (32.4-79.8%) for primary sediment sources approach, and 67% (15.3%-81.7%) for the combined primary and secondary sources approach. The Bayesian mixing model, based on an optimum set of tracers, estimated that the highest contribution of soil erosion in crop field land use and shoulder-component landforms constituted the most important land-use factor. This technique could, therefore, be a useful tool for soil and sediment control management strategies. Copyright © 2016 Elsevier Ltd. All rights reserved.

  5. Geomorphic controls on mercury accumulation in soils from a historically mined watershed, Central California Coast Range, USA

    USGS Publications Warehouse

    Holloway, J.M.; Goldhaber, M.B.; Morrison, J.M.

    2009-01-01

    Historic Hg mining in the Cache Creek watershed in the Central California Coast Range has contributed to the downstream transport of Hg to the San Francisco Bay-Delta. Different aspects of Hg mobilization in soils, including pedogenesis, fluvial redistribution of sediment, volatilization and eolian transport were considered. The greatest soil concentrations (>30 mg Hg kg-1) in Cache Creek are associated with mineralized serpentinite, the host rock for Hg deposits. Upland soils with non-mineralized serpentine and sedimentary parent material also had elevated concentrations (0.9-3.7 mg Hg kg-1) relative to the average concentration in the region and throughout the conterminous United States (0.06 mg kg-1). Erosion of soil and destabilized rock and mobilization of tailings and calcines into surrounding streams have contributed to Hg-rich alluvial soil forming in wetlands and floodplains. The concentration of Hg in floodplain sediment shows sediment dispersion from low-order catchments (5.6-9.6 mg Hg kg-1 in Sulphur Creek; 0.5-61 mg Hg kg-1 in Davis Creek) to Cache Creek (0.1-0.4 mg Hg kg-1). These sediments, deposited onto the floodplain during high-flow storm events, yield elevated Hg concentrations (0.2-55 mg Hg kg-1) in alluvial soils in upland watersheds. Alluvial soils within the Cache Creek watershed accumulate Hg from upstream mining areas, with concentrations between 0.06 and 0.22 mg Hg kg-1 measured in soils ~90 km downstream from Hg mining areas. Alluvial soils have accumulated Hg released through historic mining activities, remobilizing this Hg to streams as the soils erode.

  6. Vertical distribution of radiocesium in soils of the area affected by the Fukushima Dai-ichi nuclear power plant accident

    NASA Astrophysics Data System (ADS)

    Konoplev, A. V.; Golosov, V. N.; Yoschenko, V. I.; Nanba, K.; Onda, Y.; Takase, T.; Wakiyama, Y.

    2016-05-01

    Presented are results of the study of radiocesium vertical distribution in the soils of the irrigation pond catchments in the near field 0.25 to 8 km from the Fukushima Dai-ichi NPP, on sections of the Niida River floodplain, and in a forest ecosystem typical of the territory contaminated after the accident. It is shown that the vertical migration of radiocesium in undisturbed forest and grassland soils in the zone affected by the Fukushima accident is faster than it was in the soils of the 30-km zone of the Chernobyl NPP for a similar time interval after the accident. The effective dispersion coefficients in the Fukushima soils are several times higher than those for the Chernobyl soils. This may be associated with higher annual precipitation (by about 2.5 times) in Fukushima as compared to the Chernobyl zone. In the forest soils the radiocesium dispersion is faster as compared to grassland soils, both in the Fukushima and Chernobyl zones. The study and analysis of the vertical distribution of the Fukushima origin radiocesium in the Niida gawa floodplain soils has made it possible to identify areas of contaminated sediment accumulation on the floodplain. The average accumulation rate for sediments at the study locations on the Niida gawa floodplain varied from 0.3 to 3.3 cm/year. Taking into account the sediments accumulation leading to an increase in the radiocesium inventory in alluvial soils is key for predicting redistribution of radioactive contamination after the Fukushima accident on the river catchments, as well as for decision-making on contaminated territories remediation and clean-up. Clean-up of alluvial soils does not seem to be worthwhile because of the following accumulation of contaminated sediments originating from more contaminated areas, including the exclusion zone.

  7. Fingerprinting selection for agroenvironmental catchment studies: EDXRF analysis for solving complex artificial mixtures

    NASA Astrophysics Data System (ADS)

    Torres Astorga, Romina; Velasco, Hugo; Dercon, Gerd; Mabit, Lionel

    2017-04-01

    Soil erosion and associated sediment transportation and deposition processes are key environmental problems in Central Argentinian watersheds. Several land use practices - such as intensive grazing and crop cultivation - are considered likely to increase significantly land degradation and soil/sediment erosion processes. Characterized by highly erodible soils, the sub catchment Estancia Grande (12.3 km2) located 23 km north east of San Luis has been investigated by using sediment source fingerprinting techniques to identify critical hot spots of land degradation. The authors created 4 artificial mixtures using known quantities of the most representative sediment sources of the studied catchment. The first mixture was made using four rotation crop soil sources. The second and the third mixture were created using different proportions of 4 different soil sources including soils from a feedlot, a rotation crop, a walnut forest and a grazing soil. The last tested mixture contained the same sources as the third mixture but with the addition of a fifth soil source (i.e. a native bank soil). The Energy Dispersive X Ray Fluorescence (EDXRF) analytical technique has been used to reconstruct the source sediment proportion of the original mixtures. Besides using a traditional method of fingerprint selection such as Kruskal-Wallis H-test and Discriminant Function Analysis (DFA), the authors used the actual source proportions in the mixtures and selected from the subset of tracers that passed the statistical tests specific elemental tracers that were in agreement with the expected mixture contents. The selection process ended with testing in a mixing model all possible combinations of the reduced number of tracers obtained. Alkaline earth metals especially Strontium (Sr) and Barium (Ba) were identified as the most effective fingerprints and provided a reduced Mean Absolute Error (MAE) of approximately 2% when reconstructing the 4 artificial mixtures. This study demonstrates that the EDXRF fingerprinting approach performed very well in reconstructing our original mixtures especially in identifying and quantifying the contribution of the 4 rotation crop soil sources in the first mixture.

  8. Potential Impacts of Climate Change on Vegetative Ecosystem Services of Soil Retention [US-IALE 04/08/18

    EPA Science Inventory

    Planning for a sustainable future should include an accounting of services currently provided by ecosystems such as erosion control. Retention of soil not only maintains but improves soil fertility, improves water retention, and decreases sedimentation in streams and rivers ther...

  9. 40 CFR 264.552 - Corrective Action Management Units (CAMU).

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... (FML), and the lower component must consist of at least a two-foot layer of compacted soil with a... hazardous wastes, and all media (including ground water, surface water, soils, and sediments) and debris... with the compacted soil component; (ii) Alternate requirements. The Regional Administrator may approve...

  10. 40 CFR 264.552 - Corrective Action Management Units (CAMU).

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... (FML), and the lower component must consist of at least a two-foot layer of compacted soil with a... hazardous wastes, and all media (including ground water, surface water, soils, and sediments) and debris... with the compacted soil component; (ii) Alternate requirements. The Regional Administrator may approve...

  11. 40 CFR 264.552 - Corrective Action Management Units (CAMU).

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... (FML), and the lower component must consist of at least a two-foot layer of compacted soil with a... hazardous wastes, and all media (including ground water, surface water, soils, and sediments) and debris... with the compacted soil component; (ii) Alternate requirements. The Regional Administrator may approve...

  12. 40 CFR 264.552 - Corrective Action Management Units (CAMU).

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... (FML), and the lower component must consist of at least a two-foot layer of compacted soil with a... hazardous wastes, and all media (including ground water, surface water, soils, and sediments) and debris... with the compacted soil component; (ii) Alternate requirements. The Regional Administrator may approve...

  13. Comment of "Event-based soil loss models for construction sites" by Trenouth and Gharabaghi, J. Hydrol. doi: 10.1016/jhydrol.2015.03.010

    NASA Astrophysics Data System (ADS)

    Kinnell, P. I. A.

    2015-09-01

    Trenouth and Gharabaghi (2015) present two models which replace the EI30 index used as the event erosivity index in the USLE/RUSLE with ones that include runoff and values of EI30 to powers that differ for 1.0 as the event erosivity factor in modelling soil loss for construction sites. Their analysis on the application of these models focused on data from 5 locations as a whole but did not show how the models worked at each location. Practically, the ability to predict sediment yields at a specific location is more relevant than the capacity of a model to predict sediment yields globally. Also, the mathematical structure of their proposed models shows little regard to the physical processes involved in causing erosion and sediment yield. There is still the need to develop event-based empirical models for construction sites that are robust because they give proper consideration to the erosion process involved, and take account of the fact that sediment yield is usually determined from measurements of suspended load whereas soil loss at the scale for which the USLE/RUSLE model was developed includes both suspended load and bed load.

  14. Relationship between the parent material and the soil, in plain and mountainous areas

    NASA Astrophysics Data System (ADS)

    Kerek, Barbara; Kuti, Laszlo; Dobos, Timea; Vatai, Jozsef; Szentpetery, Ildiko

    2013-04-01

    One of the most important tasks of the soil is the nutrition of plants. This function is determinated by those parts of the geological media on what is the soil situated and from what the soil was formed (those two can be different). Soil can be formed definitely just from sediment, so it is more proper to speak about parent material than parent rock. Soil forming sediment is defined as the loose sediment on the surface, which is the upper layer of near-surface rocks in flat and hilly regions, and it is the upper layer of the sediment-ensemble situated on the undisturbed bedrock in mountainous areas. Considering its origin, these sediments could be autochthon or allochton. Soil forming is determinated, besides other factors (climate, elevation, vegetation, etc.), by the parent material, which has a crucial influence on the type, quality and fertility of soils through its mineral composition, physical and chemical characteristics. Agrogeological processes happen in the superficial loose sediments in mountainous areas, but the underlying solid rock (where on the surface or close to it, there is solid rock), has an effect on them. The plain and hilly regions covered by thick loose sediment and the areas build up by solid rock and covered with thinner loose sediment in mountainous areas should be searched separately. In plain areas the near-surface formations have to be studied as a whole down to the saturated zone, but at least to 10 m. In regions of mountain and mountain fronts, the thickness, the composition and genetics of the young unconsolidated sediments situated above the older solid rocks have a vital importance, and also the relations among the soils, soil forming sediments and the base rocks have to be understood.

  15. Consequences of the river valley bottom transformation after extreme flood (on the example of the Niida River, Japan)

    NASA Astrophysics Data System (ADS)

    Botavin, D.; Golosov, V.; Konoplev, A.; Wakiyama, Y.

    2018-01-01

    Detailed study of different sections of floodplain was undertaken in the Niida River basin (Fukushima Prefecture) after an extreme flood event which occurred in the middle of September 2015. The upstream part of the basin is located in the area with very high level of radionuclide contamination after the accident at Fukushima Dai-ichi NPP. Field and GIS methods were used, including direct measurement of the depth of fresh sediment and its area, with soil descriptions for the typical floodplain sections, measurement of dose rates, interpretation of space images for a few time intervals (before and after flood event) with the following evaluation of spatial changes in deposition for different floodplain sections. In addition, results of quantitative assessment of sedimentation rates and soil radionuclide contamination were applied for understanding the effect of extreme flood on alluvial soils of the different sections. It was established that the maximum sedimentation rates (20-50 cm/event) occurred in the middle part of the lower reach of the Niida River and in some locations of the upper reaches. Dose rates had reduced considerably for all the areas with high sedimentation because the top soil layers with high radionuclide contamination were buried under fresh sediments produced mostly due to bank erosion and mass movements.

  16. Fluoroquinolones and qnr genes in sediment, water, soil, and human fecal flora in an environment polluted by manufacturing discharges.

    PubMed

    Rutgersson, Carolin; Fick, Jerker; Marathe, Nachiket; Kristiansson, Erik; Janzon, Anders; Angelin, Martin; Johansson, Anders; Shouche, Yogesh; Flach, Carl-Fredrik; Larsson, D G Joakim

    2014-07-15

    There is increasing concern that environmental antibiotic pollution promotes transfer of resistance genes to the human microbiota. Here, fluoroquinolone-polluted river sediment, well water, irrigated farmland, and human fecal flora of local villagers within a pharmaceutical industrial region in India were analyzed for quinolone resistance (qnr) genes by quantitative PCR. Similar samples from Indian villages farther away from industrial areas, as well as fecal samples from Swedish study participants and river sediment from Sweden, were included for comparison. Fluoroquinolones were detected by MS/MS in well water and soil from all villages located within three km from industrially polluted waterways. Quinolone resistance genes were detected in 42% of well water, 7% of soil samples and in 100% and 18% of Indian and Swedish river sediments, respectively. High antibiotic concentrations in Indian sediment coincided with high abundances of qnr, whereas lower fluoroquinolone levels in well water and soil did not. We could not find support for an enrichment of qnr in fecal samples from people living in the fluoroquinolone-contaminated villages. However, as qnr was detected in 91% of all Indian fecal samples (24% of the Swedish) it suggests that the spread of qnr between people is currently a dominating transmission route.

  17. Quantification of soil erosion and transport processes in the in the Myjava Hill Land

    NASA Astrophysics Data System (ADS)

    Hlavcová, Kamila; Kohnová, Silvia; Velisková, Yvetta; Studvová, Zuzana; Socuvka, Valentin; Németová, Zuzana; Duregová, Maria

    2017-04-01

    The aim of the study is a complex analysis of soil erosion processes and proposals for erosion control in the region of the Myjava Hill Land located in western Slovakia. The Myjava Hill Land is characteristic of quick runoff response, intensive soil erosion by water and related muddy floods, which are determined by both natural and socio-economic conditions. In this paper a case study in the Svacenický Creek catchment, with a focus on the quantification of soil loss from the agriculturally arable lands and sediment transport to the dry water reservoir (polder) of the Svacenický Creek is presented. Erosion, sediment transport, and the deposition of sediments in the water reservoir represent a significant impact on its operation, mainly with regard to reducing its accumulation volume. For the analysis of the soil loss and sediment transport from the Svacenický Creek catchment, the Universal Soil Loss Equation, the USLE 2D, and the Sediment Delivery Ratio (SDR) models were applied. Because the resulting values of the soil loss exceeded the values of the tolerated soil loss, erosion control measures by strip cropping were designed. Strip cropping is based on altering crop strips with protective (infiltration) strips. The effectiveness of the protective (infiltration) strips for reducing runoff from the basin by the SCS-CN method was estimated. Monitoring the morphological parameters of bottom sediments and their changes over time is crucial information in the field of water reservoir operations. In September 2015, the AUV EcoMapper was used to gather the data information on the Svacenický Creek reservoir. The data includes information about the sediment depths and parameters of the water quality. The results of the surveying are GIS datasets and maps, which provide a higher resolution of the bathymetric data and contours of the bottom reservoir. To display the relief of the bottom, the ArcMap 10.1. software was used. Based on the current status of the bottom bathymetry, the current status of the clogging of the reservoir was evaluated. After an evaluation of all the analyses, we can conclude that within five years of the acceptance run, 10,515 m3 of bottom sediments accumulated in the Svacenický Creek reservoir.

  18. Towards real time spatially resolved data on sediment transport: 1) tracing the motion of the fluorescent soil particles under rainfall

    NASA Astrophysics Data System (ADS)

    Quinton, John; Hardy, Rob; Pates, Jackie; James, Mike

    2017-04-01

    Understanding where sediment originates from and where it travels to, in what quantities and at which rate is at the heart of many questions surrounding sediment transport, including the connectivity problem. Progress towards unravelling these questions and deepening our understanding has come from a wide range of approaches, including laboratory and field experiments conducted at a variety of scales. In seeking to understand the connectivity of sources and sinks of sediment scientists have spent considerable energy in developing tracing technologies. These have included numerous studies that have relied on the chemical properties of the soil and sediment to establish source-sink connectivity, and the use of 137Ceasium, from radioactive fall-out, to map sediment redistribution. More recently there has been an upsurge in interest in the use of artificially applied soil tracers, including rare earth element oxides and magnetic minerals. However all these tracing methods have a significant drawback: they rely on the collection of samples to assess their concentration. This means that their spatial distribution cannot easily be established in situ and that the environment that is being studied is damaged by the sampling process; nor can data be collected in real time which allows a dynamic understanding of erosion and transport processes to be developed. In this paper we present a methodology for use with a commercially available fluorescent tracer. The tracer is produced in a range of sizes and fluorescent signatures and can be applied to the soil surface. Here we report on an application that combines novel fluorescent videography techniques with custom image processing to trace the motion of the fluorescent soil particles under rainfall. Here we demonstrate the tracking of multiple sub-millimetre particles simultaneously, establishing their position 50 times a second with submillimetre precision. From this we are able to visualise and quantify parameters such as distance and direction of travel. In a second abstract we report on the field application of the tracer at the hillslope scale during a tillage erosion experiment. Here we trialled both intensity based and particle counting methodologies for tracer enumeration. After simulating seven years of tillage on a hillslope we were able to precisely determine the distribution of the fluorescent tracer and also its incorporation and distribution within the soil profile. Single grains of tracer could be found over 35 m from the insertion point.

  19. Suspended sediment source areas and future climate impact on soil erosion and sediment yield in a New York City water supply watershed, USA

    NASA Astrophysics Data System (ADS)

    Mukundan, Rajith; Pradhanang, Soni M.; Schneiderman, Elliot M.; Pierson, Donald C.; Anandhi, Aavudai; Zion, Mark S.; Matonse, Adão H.; Lounsbury, David G.; Steenhuis, Tammo S.

    2013-02-01

    High suspended sediment loads and the resulting turbidity can impact the use of surface waters for water supply and other designated uses. Changes in fluvial sediment loads influence material fluxes, aquatic geochemistry, water quality, channel morphology, and aquatic habitats. Therefore, quantifying spatial and temporal patterns in sediment loads is important both for understanding and predicting soil erosion and sediment transport processes as well as watershed-scale management of sediment and associated pollutants. A case study from the 891 km2 Cannonsville watershed, one of the major watersheds in the New York City water supply system is presented. The objective of this study was to apply Soil and Water Assessment Tool-Water Balance (SWAT-WB), a physically based semi-distributed model to identify suspended sediment generating source areas under current conditions and to simulate potential climate change impacts on soil erosion and suspended sediment yield in the study watershed for a set of future climate scenarios representative of the period 2081-2100. Future scenarios developed using nine global climate model (GCM) simulations indicate a sharp increase in the annual rates of soil erosion although a similar result in sediment yield at the watershed outlet was not evident. Future climate related changes in soil erosion and sediment yield appeared more significant in the winter due to a shift in the timing of snowmelt and also due to a decrease in the proportion of precipitation received as snow. Although an increase in future summer precipitation was predicted, soil erosion and sediment yield appeared to decrease owing to an increase in soil moisture deficit and a decrease in water yield due to increased evapotranspiration.

  20. Potential fate of SOC eroded from natural crusted soil surface under simulated wind driven storm

    NASA Astrophysics Data System (ADS)

    Xiao, Liangang; Fister, Wolfgang; Greenwood, Philip; Hu, Yaxian; Kuhn, Nikolaus J.

    2016-04-01

    Improving the assessment of the impact of soil erosion on carbon (C) cycling requires a better understanding of the redistribution of eroded sediment and associated soil organic carbon (SOC) across agricultural landscapes. Recent studies conducted on dry-sieved aggregates in the laboratory demonstrated that aggregation can profoundly skew SOC redistribution and its subsequent fate by accelerating settling velocities of aggregated sediment compared to mineral grains, which in turn can increase SOC mineralization into greenhouse gases. However, the erodibility of the soil in the field is more variable than in the laboratory due to tillage, crus formation, drying-wetting and freeze-thaw cycles, and biological effects. This study aimed to investigate the potential fate of the SOC eroded from naturally developed soil surface and to compare the observations with those made in the laboratory. Simulated, short, high intensity wind driven storms were conducted on a crusted loam in the field. The sediments were fractionated with a settling tube according to their potential transport distances. The soil mass, SOC concentration and cumulative 80-day CO2 emission of each fraction were identified. The results show: 1) 53% of eroded sediment and 62% of eroded SOC from the natural surface in the field would be deposited across landscapes, which is six times and three times higher compared to that implied by mineral grains, respectively; 2) the preferential deposition of SOC-rich fast-settling sediment potentially releases approximately 50% more CO2 than the same layer of the non-eroded soil; 3) the respiration of the slow-settling fraction that is potentially transported to the aquatic systems was much more active compared to the other fractions and the bulk soil. Our results confirm in general the conclusions drawn from laboratory and thus demonstrate that aggregation can affect the redistribution of sediment associated SOC under field conditions, including an increase in emissions compared to bulk soil. Overall, this confirms that terrestrial SOC redistribution and the mineralization play an important role in erosion induced C cycling, with major uncertainties to be addressed.

  1. Environmental distribution of PAHs in pine needles, soils, and sediments.

    PubMed

    Navarro-Ortega, Alícia; Ratola, Nuno; Hildebrandt, Alain; Alves, Arminda; Lacorte, Sílvia; Barceló, Damià

    2012-03-01

    The content of 16 polycyclic aromatic hydrocarbons (PAHs) was determined in 60 samples from three environmental matrices (soils, sediments, and pine needles) in an effort to assess their distribution on a river basin scale. A sampling campaign was carried out in 2006, selecting urban, industrial, and agricultural sampling sites along the northeast of Spain. Techniques used included pressurized liquid extraction and solid-liquid ultrasonic extraction followed by gas chromatography-electron impact ionization mass spectrometry. The mean total PAHs concentrations were 290 < 613 < 1,628 ng/g (dry weight) in pine needles, soil, and sediments, respectively. There is a good correspondence between the total concentration of soils and pine needles, as opposed to the levels between sediments and pine needles. The high concentrations found in some Pinus halepensis samples may reflect a superior uptake potential of this species in comparison to the others studied. The three matrices present a very different PAH distribution pattern, with pine needles showing a predominance of the lighter (2-, 3-, and 4-ring) PAHs, whereas 5- and 6-ring PAHs are the most abundant in soils. Sediments display a more heterogeneous pattern, with contributions of all the PAHs but different distribution depending on the site, suggesting a wider range of input sources. Established PAH molecular ratios and principal component analysis were used to identify the origins and profiles of PAHs. While sediments showed a wide range attributed to historical inputs, soils and pine needles confirmed the compartmentalization of the PAHs, with lighter airborne PAHs accumulated in pine needles and heavier ones in soils. It can be suggested that the monitoring of several matrices is a strong tool to elucidate the contamination sources and accumulation patterns of PAHs. However, given the influence of the matrix type on this assessment, the information should be considered complementary, yet allowing a more comprehensive depiction of the area in question.

  2. Soil erosion and sediment production on watershed landscapes: Processes and control

    Treesearch

    Peter F. Ffolliott; Kenneth N. Brooks; Daniel G. Neary; Roberto Pizarro Tapia; Pablo Garcia-Chevesich

    2013-01-01

    Losses of the soil resources from otherwise productive and well functioning watersheds is often a recurring problem confronting hydrologists and watershed managers. These losses of soil have both on-site and off-site effects on the watershed impacted. In addition to the loss of inherent soil resources through erosion processes, on-site effects can include the breakdown...

  3. Sediment composition for the assessment of water erosion and nonpoint source pollution in natural and fire-affected landscapes.

    PubMed

    Carkovic, Athena B; Pastén, Pablo A; Bonilla, Carlos A

    2015-04-15

    Water erosion is a leading cause of soil degradation and a major nonpoint source pollution problem. Many efforts have been undertaken to estimate the amount and size distribution of the sediment leaving the field. Multi-size class water erosion models subdivide eroded soil into different sizes and estimate the aggregate's composition based on empirical equations derived from agricultural soils. The objective of this study was to evaluate these equations on soil samples collected from natural landscapes (uncultivated) and fire-affected soils. Chemical, physical, and soil fractions and aggregate composition analyses were performed on samples collected in the Chilean Patagonia and later compared with the equations' estimates. The results showed that the empirical equations were not suitable for predicting the sediment fractions. Fine particles, including primary clay, primary silt, and small aggregates (<53 μm) were over-estimated, and large aggregates (>53 μm) and primary sand were under-estimated. The uncultivated and fire-affected soils showed a reduced fraction of fine particles in the sediment, as clay and silt were mostly in the form of large aggregates. Thus, a new set of equations was developed for these soils, where small aggregates were defined as particles with sizes between 53 μm and 250 μm and large aggregates as particles>250 μm. With r(2) values between 0.47 and 0.98, the new equations provided better estimates for primary sand and large aggregates. The aggregate's composition was also well predicted, especially the silt and clay fractions in the large aggregates from uncultivated soils (r(2)=0.63 and 0.83, respectively) and the fractions of silt in the small aggregates (r(2)=0.84) and clay in the large aggregates (r(2)=0.78) from fire-affected soils. Overall, these new equations proved to be better predictors for the sediment and aggregate's composition in uncultivated and fire-affected soils, and they reduce the error when estimating soil loss in natural landscapes. Copyright © 2015 Elsevier B.V. All rights reserved.

  4. Biotransformation of tetrabromobisphenol A (TBBPA) in anaerobic digester sludge, soils, and freshwater sediments.

    PubMed

    McAvoy, Drew C; Pittinger, Charles A; Willis, Alison M

    2016-09-01

    The biotransformation of tetrabromobisphenol A (TBBPA) was evaluated in anaerobic digester sludge, soils, and freshwater sediments. In anaerobic digester sludge, TBBPA biotransformed rapidly with a 50% disappearance time (DT50) of 19 days, though little mineralization (1.1%) was observed. In aerobic soils, mineralization of TBBPA ranged from 17.5% to 21.6% with 55.3-83.6% of the TBBPA incorporated into the soils as a non-extractable bound residue. The DT50 for TBBPA in aerobic soils ranged from 5.3 to 7.7 days. In anaerobic soils, 48.3-100% of the TBBPA was incorporated into the soils as non-extractable bound residue with <4% mineralized. The soil fate studies demonstrated extensive incorporation of TBBPA into the solid matrix and this association was related to the amount of organic carbon in the soils (i.e., greater association of TBBPA with soil at higher organic carbon content). In anaerobic sediments the DT50 for TBBPA ranged from 28 to 42 days, whereas in aerobic sediments the DT50 for TBBPA ranged from 48 to 84 days and depended on the initial dose concentration. Most of the TBBPA in the sediment studies was incorporated as a non-extractable bound residue with little mineralization observed. Sediment extracts revealed three unknown biotransformation products and bisphenol A (BPA). These results were consistent with previously published studies where TBBPA biotransformed in anaerobic environments (digester sludge and sediments) by debromination and slowly mineralized in the test environments (anaerobic digester sludge, soils, and freshwater sediments). Copyright © 2015 The Authors. Published by Elsevier Inc. All rights reserved.

  5. Soil fertility in deserts: a review on the influence of biological soil crusts and the effect of soil surface disturbance on nutrient inputs and losses

    USGS Publications Warehouse

    Reynolds, R.; Phillips, S.; Duniway, M.; Belnap, J.

    2003-01-01

    Sources of desert soil fertility include parent material weathering, aeolian deposition, and on-site C and N biotic fixation. While parent materials provide many soil nutrients, aeolian deposition can provide up to 75% of plant-essential nutrients including N, P, K, Mg, Na, Mn, Cu, and Fe. Soil surface biota are often sticky, and help retain wind-deposited nutrients, as well as providing much of the N inputs. Carbon inputs are from both plants and soil surface biota. Most desert soils are protected by cyanobacterial-lichen-moss soil crusts, chemical crusts and/or desert pavement. Experimental disturbances applied in US deserts show disruption of soil surfaces result in decreased N and C inputs from soil biota by up to 100%. The ability to glue aeolian deposits in place is compromised, and underlying soils are exposed to erosion. The ability to withstand wind increases with biological and physical soil crust development. While most undisturbed sites show little sediment production, disturbance by vehicles or livestock produce up to 36 times more sediment production, with soil movement initiated at wind velocities well below commonly-occurring wind speeds. Soil fines and flora are often concentrated in the top 3 mm of the soil surface. Winds across disturbed areas can quickly remove this material from the soil surface, thereby potentially removing much of current and future soil fertility. Thus, disturbances of desert soil surfaces can both reduce fertility inputs and accelerate fertility losses.

  6. Factors Affecting the Distribution of Perfluorinated Compounds in Sediments from Lake Shihwa, Korea

    EPA Science Inventory

    Perfluorinated compounds (PFCs) are ubiquitously distributed in various environmental media including water, soil, sediment, and biota. PFCs have also been shown to biomagnify in both aquatic and terrestrial environments. Lake Shihwa is an artificial saltwater lake, located on ...

  7. Sediment quality in the north coastal basin of Massachusetts, 2003

    USGS Publications Warehouse

    Breault, Robert F.; Ashman, Mary S.; Heath, Douglas

    2004-01-01

    The U.S. Geological Survey, in cooperation with the Massachusetts Department of Environmental Protection, completed a reconnaissance-level study of bottom-sediment quality in selected lakes, rivers, and estuaries in the North Coastal Basin of Massachusetts. Bottom-sediment grab samples were collected from 20 sites in the North River, Lake Quannapowitt, Saugus River, Mill River, Shute Brook, Sea Plane Basin, Pines River, and Bear Creek. The samples were tested for various types of potentially harmful contaminants? including 33 elements, 17 polyaromatic hydrocarbons (PAHs), 22 organochlorine pesticides, and 7 polychlorinated biphenyl (PCB) mixtures (Aroclors)?to benthic organisms (bottom-dwelling) and humans. The results were compared among sampling sites, to background concentrations, and to concen-trations measured in other urban rivers, and sediment-quality guidelines were used to predict toxicity at the sampling sites to benthic organisms and humans. Because there are no standards for human toxicity for aquatic sediment, standards for contaminated upland soil were used. Contaminant concentrations measured in sediment collected from the North Coastal Basin generally were equal to or greater than concentrations in sediment from uncontaminated rivers throughout New England. Contaminants in North Coastal Basin sediment with elevated concentrations (above back-ground levels) included arsenic, chromium, copper, lead, nickel, and zinc, some of the PAHs, dichlorodiphenyltrichloro-ethane (DDT) and its metabolites, and dieldrin. No PCBs were measured above the detection limits. Measured concentrations of arsenic, chromium, and lead were also generally greater than those measured in other urban rivers throughout the conter-minous United States. With one exception (arsenic), local con-centrations measured in sediment samples collected from the North Coastal Basin were lower than concentrations measured in sediment collected from two of three urban rivers draining to Boston Harbor. The probable toxicity to benthic organisms ranged from about 33 to 91 percent across the study area. Of the elements analyzed, antimony, arsenic, beryllium, and lead exceeded the soil standards for risk to human health. Of the PAHs analyzed, four also exceeded soil standards. Organochlorine pesticide concentrations, however, were not high enough relative to the soil standards to pose a risk to human health. Some trace element and some organic compound concentrations in bottom sediment may be toxic to aquatic organisms and may pose a risk to human health.

  8. Quantifying and modeling soil erosion and sediment export from construction sites in southern California

    NASA Astrophysics Data System (ADS)

    Wernet, A. K.; Beighley, R. E.

    2006-12-01

    Soil erosion is a power process that continuously alters the Earth's landscape. Human activities, such as construction and agricultural practices, and natural events, such as forest fires and landslides, disturb the landscape and intensify erosion processes leading to sudden increases in runoff sediment concentrations and degraded stream water quality. Understanding soil erosion and sediment transport processes is of great importance to researchers and practicing engineers, who routinely use models to predict soil erosion and sediment movement for varied land use and climate change scenarios. However, existing erosion models are limited in their applicability to constructions sites which have highly variable soil conditions (density, moisture, surface roughness, and best management practices) that change often in both space and time. The goal of this research is to improve the understanding, predictive capabilities and integration of treatment methodologies for controlling soil erosion and sediment export from construction sites. This research combines modeling with field monitoring and laboratory experiments to quantify: (a) spatial and temporal distribution of soil conditions on construction sites, (b) soil erosion due to event rainfall, and (c) potential offsite discharge of sediment with and without treatment practices. Field sites in southern California were selected to monitor the effects of common construction activities (ex., cut/fill, grading, foundations, roads) on soil conditions and sediment discharge. Laboratory experiments were performed in the Soil Erosion Research Laboratory (SERL), part of the Civil and Environmental Engineering department at San Diego State University, to quantify the impact of individual factors leading to sediment export. SERL experiments utilize a 3-m by 10-m tilting soil bed with soil depths up to 1 m, slopes ranging from 0 to 50 percent, and rainfall rates up to 150 mm/hr (6 in/hr). Preliminary modeling, field and laboratory results are presented.

  9. Predicting improved optical water quality in rivers resulting from soil conservation actions on land.

    PubMed

    Dymond, J R; Davies-Colley, R J; Hughes, A O; Matthaei, C D

    2017-12-15

    Deforestation in New Zealand has led to increased soil erosion and sediment loads in rivers. Increased suspended fine sediment in water reduces visual clarity for humans and aquatic animals and reduces penetration of photosynthetically available radiation to aquatic plants. To mitigate fine-sediment impacts in rivers, catchment-wide approaches to reducing soil erosion are required. Targeting soil conservation for reducing sediment loads in rivers is possible through existing models; however, relationships between sediment loads and sediment-related attributes of water that affect both ecology and human uses of water are poorly understood. We present methods for relating sediment loads to sediment concentration, visual clarity, and euphotic depth. The methods require upwards of twenty concurrent samples of sediment concentration, visual clarity, and euphotic depth at a river site where discharge is measured continuously. The sediment-related attributes are related to sediment concentration through regressions. When sediment loads are reduced by soil conservation action, percentiles of sediment concentration are necessarily reduced, and the corresponding percentiles of visual clarity and euphotic depth are increased. The approach is demonstrated on the Wairua River in the Northland region of New Zealand. For this river we show that visual clarity would increase relatively by approximately 1.4 times the relative reduction of sediment load. Median visual clarity would increase from 0.75m to 1.25m (making the river more often suitable for swimming) after a sediment load reduction of 50% associated with widespread soil conservation on pastoral land. Likewise euphotic depth would increase relatively by approximately 0.7 times the relative reduction of sediment load, and the median euphotic depth would increase from 1.5m to 2.0m with a 50% sediment load reduction. Copyright © 2017 Elsevier B.V. All rights reserved.

  10. Spatial and seasonal variations in mercury methylation and microbial community structure in a historic mercury mining area, Yolo County, California

    USGS Publications Warehouse

    Holloway, J.M.; Goldhaber, M.B.; Scow, K.M.; Drenovsky, R.E.

    2009-01-01

    The relationships between soil parent lithology, nutrient concentrations, microbial biomass and community structure were evaluated in soils from a small watershed impacted by historic Hg mining. Upland and wetland soils, stream sediments and tailings were collected and analyzed for nutrients (DOC, SO4=, NO3-), Hg, MeHg, and phospholipid fatty acids (PLFA). Stream sediment was derived from serpentinite, siltstone, volcanic rocks and mineralized serpentine with cinnabar, metacinnabar and other Hg phases. Soils from different parent materials had distinct PLFA biomass and community structures that are related to nutrient concentrations and toxicity effects of trace metals including Hg. The formation of MeHg appears to be most strongly linked to soil moisture, which in turn has a correlative relationship with PLFA biomass in wetland soils. The greatest concentrations of MeHg (> 0.5??ng g- 1 MeHg) were measured in wetland soils and soil with a volcanic parent (9.5-37????g g- 1 Hg). Mercury methylation was associated with sulfate-reducing bacteria, including Desulfobacter sp. and Desulfovibrio sp., although these organisms are not exclusively responsible for Hg methylation. Statistical models of the data demonstrated that soil microbial communities varied more with soil type than with season.

  11. Nitrogen enrichment in runoff sediments as affected by soil texture in Beijing mountain area.

    PubMed

    Yang, Yang; Ye, Zhihan; Liu, Baoyuan; Zeng, Xianqin; Fu, Suhua; Lu, Bingjun

    2014-02-01

    Enrichment ratio (ER) is widely used in nonpoint source pollution models to estimate the nutrient loss associated with soil erosion. The objective of this study was to determine the ER of total nitrogen (ERN) in the sediments eroded from the typical soils with varying soil textures in Beijing mountain area. Each of the four soils was packed into a 40 by 30 by 15 cm soil pan and received 40-min simulated rainfalls at the intensity of 90 mm h(-1) on five slopes. ERN for most sediments were above unity, indicating the common occurrence of nitrogen enrichment accompanied with soil erosion in Beijing mountain area. Soil texture was not the only factor that influenced N enrichment in this experiment since the ERN for the two fine-textured soils were not always lower. Soil properties such as soil structure might exert a more important influence in some circumstances. The selective erosion of clay particles was the main reason for N enrichment, as implied by the significant positive correlation between the ER of total nitrogen and clay fraction in eroded sediments. Significant regression equations between ERN and sediment yield were obtained for two pairs of soils, which were artificially categorized by soil texture. The one for fine-textured soils had greater intercept and more negative slope. Thus, the initially higher ERN would be lower than that for the other two soils with coarser texture once the sediment yield exceeded 629 kg ha(-1).

  12. Mining-Related Sediment and Soil Contamination in a Large Superfund Site: Characterization, Habitat Implications, and Remediation.

    PubMed

    Juracek, K E; Drake, K D

    2016-10-01

    Historical mining activity (1850-1970) in the now inactive Tri-State Mining District provided an ongoing source of lead and zinc to the environment including the US Environmental Protection Agency Superfund site located in Cherokee County, southeast Kansas, USA. The resultant contamination adversely affected biota and caused human health problems and risks. Remediation in the Superfund site requires an understanding of the magnitude and extent of contamination. To provide some of the required information, a series of sediment and soil investigations were conducted in and near the Superfund site to characterize lead and zinc contamination in the aquatic and floodplain environments along the main-stem Spring River and its major tributaries. In the Superfund site, the most pronounced lead and zinc contamination, with concentrations that far exceed sediment quality guidelines associated with potential adverse biological effects, was measured for streambed sediments and floodplain soils located within or downstream from the most intensive mining-affected areas. Tributary streambeds and floodplains in affected areas are heavily contaminated with some sites having lead and zinc concentrations that are an order of magnitude (or more) greater than the sediment quality guidelines. For the main-stem Spring River, the streambed is contaminated but the floodplain is mostly uncontaminated. Measured lead and zinc concentrations in streambed sediments, lakebed sediments, and floodplain soils documented a persistence of the post-mining contamination on a decadal timescale. These results provide a basis for the prioritization, development, and implementation of plans to remediate contamination in the affected aquatic and floodplain environments within the Superfund site.

  13. Mining-Related Sediment and Soil Contamination in a Large Superfund Site: Characterization, Habitat Implications, and Remediation

    NASA Astrophysics Data System (ADS)

    Juracek, K. E.; Drake, K. D.

    2016-10-01

    Historical mining activity (1850-1970) in the now inactive Tri-State Mining District provided an ongoing source of lead and zinc to the environment including the US Environmental Protection Agency Superfund site located in Cherokee County, southeast Kansas, USA. The resultant contamination adversely affected biota and caused human health problems and risks. Remediation in the Superfund site requires an understanding of the magnitude and extent of contamination. To provide some of the required information, a series of sediment and soil investigations were conducted in and near the Superfund site to characterize lead and zinc contamination in the aquatic and floodplain environments along the main-stem Spring River and its major tributaries. In the Superfund site, the most pronounced lead and zinc contamination, with concentrations that far exceed sediment quality guidelines associated with potential adverse biological effects, was measured for streambed sediments and floodplain soils located within or downstream from the most intensive mining-affected areas. Tributary streambeds and floodplains in affected areas are heavily contaminated with some sites having lead and zinc concentrations that are an order of magnitude (or more) greater than the sediment quality guidelines. For the main-stem Spring River, the streambed is contaminated but the floodplain is mostly uncontaminated. Measured lead and zinc concentrations in streambed sediments, lakebed sediments, and floodplain soils documented a persistence of the post-mining contamination on a decadal timescale. These results provide a basis for the prioritization, development, and implementation of plans to remediate contamination in the affected aquatic and floodplain environments within the Superfund site.

  14. Mining-related sediment and soil contamination in a large Superfund site: Characterization, habitat implications, and remediation

    USGS Publications Warehouse

    Juracek, Kyle E.; Drake, K. D.

    2016-01-01

    Historical mining activity (1850–1970) in the now inactive Tri-State Mining District provided an ongoing source of lead and zinc to the environment including the US Environmental Protection Agency Superfund site located in Cherokee County, southeast Kansas, USA. The resultant contamination adversely affected biota and caused human health problems and risks. Remediation in the Superfund site requires an understanding of the magnitude and extent of contamination. To provide some of the required information, a series of sediment and soil investigations were conducted in and near the Superfund site to characterize lead and zinc contamination in the aquatic and floodplain environments along the main-stem Spring River and its major tributaries. In the Superfund site, the most pronounced lead and zinc contamination, with concentrations that far exceed sediment quality guidelines associated with potential adverse biological effects, was measured for streambed sediments and floodplain soils located within or downstream from the most intensive mining-affected areas. Tributary streambeds and floodplains in affected areas are heavily contaminated with some sites having lead and zinc concentrations that are an order of magnitude (or more) greater than the sediment quality guidelines. For the main-stem Spring River, the streambed is contaminated but the floodplain is mostly uncontaminated. Measured lead and zinc concentrations in streambed sediments, lakebed sediments, and floodplain soils documented a persistence of the post-mining contamination on a decadal timescale. These results provide a basis for the prioritization, development, and implementation of plans to remediate contamination in the affected aquatic and floodplain environments within the Superfund site.

  15. Soil Microbial Community Contribution to Small Headwater Stream Metabolism.

    NASA Astrophysics Data System (ADS)

    Clapcott, J. E.; Gooderham, J. P.; Barmuta, L. A.; Davies, P. E.

    2005-05-01

    The temporal dynamics of sediment respiration were examined in seven small headwater streams in forested catchments in 2004. A strong seasonal response was observed with higher respiration rates in depositional zones than in gravel runs. The data were also examined in the context of proportional habitat distributions that highlighted the importance of high flow events in shaping whole stream metabolic budgets. This study specifically examines the question of terrestrial soil respiration contribution to whole stream metabolism by the controlled inundation of terrestrial soils. The experiment included six experimentally inundated terrestrial zones, six terrestrial controls, and six in-stream depositional zones. Sediment bacterial respiration was measured using 14C leucine incorporation and cotton strip bioassays were also employed to provide an indicative measure of sediment microbial activity. Despite high variability and exhibiting significantly lower bacterial activity than in-stream sediments, modelling using flow data and habitat mapping illustrated the important contribution of terrestrial soil respiration to the whole stream metabolic budgets of small headwater streams. In addition, microbial community composition examined using phospholipid fatty acid analysis clearly differentiated between terrestrial and aquatic communities. Freshly inundated terrestrial communities remained similar to un-inundated controls after 28 days.

  16. Soil property effects on wind erosion of organic soils

    NASA Astrophysics Data System (ADS)

    Zobeck, Ted M.; Baddock, Matthew; Scott Van Pelt, R.; Tatarko, John; Acosta-Martinez, Veronica

    2013-09-01

    Histosols (also known as organic soils, mucks, or peats) are soils that are dominated by organic matter (OM > 20%) in half or more of the upper 80 cm. Forty two states have a total of 21 million ha of Histosols in the United States. These soils, when intensively cropped, are subject to wind erosion resulting in loss of crop productivity and degradation of soil, air, and water quality. Estimating wind erosion on Histosols has been determined by USDA-Natural Resources Conservation Service (NRCS) as a critical need for the Wind Erosion Prediction System (WEPS) model. WEPS has been developed to simulate wind erosion on agricultural land in the US, including soils with organic soil material surfaces. However, additional field measurements are needed to understand how soil properties vary among organic soils and to calibrate and validate estimates of wind erosion of organic soils using WEPS. Soil properties and sediment flux were measured in six soils with high organic contents located in Michigan and Florida, USA. Soil properties observed included organic matter content, particle density, dry mechanical stability, dry clod stability, wind erodible material, and geometric mean diameter of the surface aggregate distribution. A field portable wind tunnel was used to generate suspended sediment and dust from agricultural surfaces for soils ranging from 17% to 67% organic matter. The soils were tilled and rolled to provide a consolidated, friable surface. Dust emissions and saltation were measured using an isokinetic vertical slot sampler aspirated by a regulated suction source. Suspended dust was sampled using a Grimm optical particle size analyzer. Particle density of the saltation-sized material (>106 μm) was inversely related to OM content and varied from 2.41 g cm-3 for the soil with the lowest OM content to 1.61 g cm-3 for the soil with highest OM content. Wind erodible material and the geometric mean diameter of the surface soil were inversely related to dry clod stability. The effect of soil properties on sediment flux varied among flux types. Saltation flux was adequately predicted with simple linear regression models. Dry mechanical stability was the best single soil property linearly related to saltation flux. Simple linear models with soil properties as independent variables were not well correlated with PM10E values (mass flux). A second order polynomial equation with OM as the independent variable was found to be most highly correlated with PM10E values. These results demonstrate that variations in sediment and dust emissions can be linked to soil properties using simple models based on one or more soil properties to estimate saltation mass flux and PM10E values from organic and organic-rich soils.

  17. Geomorphic considerations for erosion prediction

    USGS Publications Warehouse

    Osterkamp, W.R.; Toy, T.J.

    1997-01-01

    Current soil-erosion prediction technology addresses processes of rainsplash, overland-flow sediment transport, and rill erosion in small watersheds. The effects of factors determining sediment yield from larger-scale drainage basins, in which sediment movement is controlled by the combined small-scale processes and a complex set of channel and other basin-scale sediment-delivery processes, such as soil creep, bioturbation, and accelerated erosion due to denudation of vegetation, have been poorly evaluated. General suggestions are provided for the development of erosion-prediction technology at the geomorphic or drainage-basin scale based on the separation of sediment-yield data for channel and geomorphic processes from those of field-scale soil loss. An emerging technology must consider: (1) the effects on sediment yield of climate, geology and soils, topography, biotic interactions with other soil processes, and land-use practices; (2) all processes of sediment delivery to a channel system; and (3) the general tendency in most drainage basins for progressively greater sediment storage in the downstream direction.

  18. Wetland biogeochemistry and ecological risk assessment

    NASA Astrophysics Data System (ADS)

    Bai, Junhong; Huang, Laibin; Gao, Haifeng; Zhang, Guangliang

    2017-02-01

    Wetlands are an important ecotone between terrestrial and aquatic ecosystems and can provide great ecological service functions. Soils/sediments are one of the important components of wetland ecosystems, which support wetland plants and microorganisms and influence wetland productivity. Moreover, wetland soils/sediments serve as sources, sinks and transfers of carbon, nitrogen, phosphorus and chemical contaminants such as heavy metals. In natural wetland ecosystems, wetland soils/sediments play a great role in improving water quality as these chemical elements can be retained in wetland soils/sediments for a long time. Moreover, the biogeochemical processes of the abovementioned elements in wetland soils/sediments can drive wetland evolution and development, and their changes will considerably affect wetland ecosystem health. Therefore, a better understanding of wetland soil biogeochemistry will contribute to improving wetland ecological service functions.

  19. Global Soil and Sediment transfer during the Anthropocene

    NASA Astrophysics Data System (ADS)

    Hoffmann, Thomas; Vanacker, Veerle; Stinchcombe, Gary; Penny, Dan; Xixi, Lu

    2016-04-01

    The vulnerability of soils to human-induced erosion and its downstream effects on fluvial and deltaic ecosystems is highly variable in space and time; dependent on climate, geology, the nature and duration of land use, and topography. Despite our knowledge of the mechanistic relationships between erosion, sediment storage, land-use and climate change, the global patterns of soil erosion, fluvial sediment flux and storage throughout the Holocene remain poorly understood. The newly launched PAGES working group GloSS aims to determine the sensitivity of soil resources and sediment routing systems to varying land use types during the period of agriculture, under contrasting climate regimes and socio-ecological settings. Successfully addressing these questions in relation to the sustainable use of soils, sediments and river systems requires an understanding of past human-landscape interactions. GloSS, therefore, aims to: Develop proxies for, or indices of, human impact on rates of soil erosion and fluvial sediment transfer that are applicable on a global scale and throughout the Holocene; Create a global database of long-term (102-104 years) human-accelerated soil erosion and sediment flux records; Identify hot spots of soil erosion and sediment deposition during the Anthropocene, and Locate data-poor regions where particular socio-ecological systems are not well understood, as strategic foci for future work. This paper will present the latest progress of the PAGES GloSS working group.

  20. A regional soil and sediment geochemical study in northern California

    USGS Publications Warehouse

    Goldhaber, M.B.; Morrison, J.M.; Holloway, J.M.; Wanty, R.B.; Helsel, D.R.; Smith, D.B.

    2009-01-01

    Regional-scale variations in soil geochemistry were investigated in a 20,000-km2 study area in northern California that includes the western slope of the Sierra Nevada, the southern Sacramento Valley and the northern Coast Ranges. Over 1300 archival soil samples collected from the late 1970s to 1980 in El Dorado, Placer, Sutter, Sacramento, Yolo and Solano counties were analyzed for 42 elements by inductively coupled plasma-atomic emission spectrometry and inductively coupled plasma-mass spectrometry following a near-total dissolution. These data were supplemented by analysis of more than 500 stream-sediment samples from higher elevations in the Sierra Nevada from the same study site. The relatively high-density data (1 sample per 15 km2 for much of the study area) allows the delineation of regional geochemical patterns and the identification of processes that produced these patterns. The geochemical results segregate broadly into distinct element groupings whose distribution reflects the interplay of geologic, hydrologic, geomorphic and anthropogenic factors. One such group includes elements associated with mafic and ultramafic rocks including Cr, Ni, V, Co, Cu and Mg. Using Cr as an example, elevated concentrations occur in soils overlying ultramafic rocks in the foothills of the Sierra Nevada (median Cr = 160 mg/kg) as well as in the northern Coast Ranges. Low concentrations of these elements occur in soils located further upslope in the Sierra Nevada overlying Tertiary volcanic, metasedimentary and plutonic rocks (granodiorite and diorite). Eastern Sacramento Valley soil samples, defined as those located east of the Sacramento River, are lower in Cr (median Cr = 84 mg/kg), and are systematically lower in this suite compared to soils from the west side of the Sacramento Valley (median Cr = 130 mg/kg). A second group of elements showing a coherent pattern, including Ca, K, Sr and REE, is derived from relatively silicic rocks types. This group occurs at elevated concentrations in soils overlying volcanic and plutonic rocks at higher elevations in the Sierras (e.g. median La = 28 mg/kg) and the east side of the Sacramento Valley (median 20 mg/kg) compared to soils overlying ultramafic rocks in the Sierra Nevada foothills (median 15 mg/kg) and the western Sacramento Valley (median 14 mg/kg). The segregation of soil geochemistry into distinctive groupings across the Sacramento River arises from the former presence of a natural levee (now replaced by an artificial one) along the banks of the river. This levee has been a barrier to sediment transport. Sediment transport to the Valley by glacial outwash from higher elevations in the Sierra Nevada and, more recently, debris from placer Au mining has dominated sediment transport to the eastern Valley. High content of mafic elements (and low content of silicic elements) in surface soil in the west side of the valley is due to a combination of lack of silicic source rocks, transport of ultramafic rock material from the Coast Ranges, and input of sediment from the late Mesozoic Great Valley Group, which is itself enriched in mafic elements. A third group of elements (Zn, Cd, As and Cu) reflect the impact of mining activity. Soil with elevated content of these elements occurs along the Sacramento River in both levee and adjacent flood basin settings. It is interpreted that transport of sediment down the Sacramento River from massive sulfide mines in the Klamath Mountains to the north has caused this pattern. The Pb, and to some extent Zn, distribution patterns are strongly impacted by anthropogenic inputs. Elevated Pb content is localized in major cites and along major highways due to inputs from leaded gasoline. Zinc has a similar distribution pattern but the source is tire wear.

  1. Mobilization and attenuation of metals downstream from a base-metal mining site in the Matra Mountains, northeastern Hungary

    USGS Publications Warehouse

    Odor, L.; Wanty, R.B.; Horvath, I.; Fugedi, U.; ,

    1999-01-01

    Regional geochemical baseline values have been established for Hungary by the use of low-density stream-sediment surveys of flood-plain deposits of large drainage basins and of the fine fraction of stream sediments. The baseline values and anomaly thresholds thus produced helped to evaluate the importance of high toxic element concentrations found in soils in a valley downstream of a polymetallic vein-type base-metal mine. Erosion of the mine dumps and flotation dump, losses of metals during filtering, storage and transportation, human neglects, and operational breakdowns, have all contributed to the contamination of a small catchment basin in a procession of releases of solid waste. The sulfide-rich waste material weathers to a yellow color; this layer of 'yellow sand' blankets a narrow strip of the floodplain of Toka Creek in the valley near the town of Gyongyosoroszi. Contamination was spread out in the valley by floods. Metals present in the yellow sand include Pb, As, Cd, Cu, Zn, and Sb. Exposure of the local population to these metals may occur through inhalation of airborne particulates or by ingestion of these metals that are taken up by crops grown in the valley. To evaluate the areal extent and depth of the contamination, active stream sediment, flood-plain deposits, lake or reservoir sediments, soils, and surface water were sampled along the erosion pathways downstream of the mine and dumps. The flood-plain profile was sampled in detail to see the vertical distribution of elements and to relate the metal concentrations to the sedimentation and contamination histories of the flood plain. Downward migration of mobile Zn and Cd from the contaminated upper layers under supergene conditions is observed, while vertical migration of Pb, As, Hg and Sb appears to be insignificant. Soil profiles of 137Cs which originated from above-ground atomic bomb tests and the Chernobyl accident, provide good evidence that the upper 30-40 cm of the flood-plain sections, which includes the yellow sand contamination, were deposited in the last 30-40 years.The regional geochemical baseline values are established for Hungary using low-density stream-sediment surveys of flood-plain deposits of large drainage basins and of the fine fraction of stream sediments. The baseline values and anomaly thresholds allowed the evaluation of the importance of high toxic element concentrations in soils in a valley, downstream of a polymetallic vein-type base-metal mine. The metals present in the yellow sand include Pb, As, Cd, Cu, Zn and Sb. To evaluate the areal extent and depth of the contamination, active stream sediment, flood-plain deposits, lake or reservoir sediments, the soils and surface water were sampled along the erosion pathways downstream of the mine and dumps.

  2. DEMONSTRATION BULLETIN: SOIL/SEDIMENT WASHING SYSTEM BERGMANN USA

    EPA Science Inventory

    The Bergmann USA Soil/Sediment Washing System is a waste minimization technique designed to separate or "partition" soils and sediments by grain size and density. In this water-based volume reduction process, hazardous contaminants are concentrated into a small residual portion...

  3. An Innovative Method for Estimating Soil Retention at a Continental Scale

    EPA Science Inventory

    Planning for a sustainable future should include an accounting of services currently provided by ecosystems such as erosion control. Retention of soil improves fertility, increases water retention, and decreases sedimentation in streams and rivers. Landscapes patterns that fac...

  4. Scale, thresholds and connectivity: sediment pathways and delivery from the patch to the catchment scale

    NASA Astrophysics Data System (ADS)

    Cammeraat, L. H.

    2009-04-01

    Geomorphological processes including soil erosion are active in specific spatio-temporal domains and lead eventually to various emerging soil properties and landscape structures which are evidently also scale dependent. In this study the scale and threshold dependency of landscapes will be compared involving three different landscapes from the temperate, Mediterranean and semi-arid Sahelian geo-ecosystems, especially with regard to the connectivity of water and sediment redistribution. The dominant processes and feed-backs interwoven with soil erosion processes will be discussed from a hierarchical theory type of approach. However, current processes are almost always affected by the presence of inherited soil and landscape properties that might be formed under very different climatological conditions than those that are dominant today. Another important factor in these processes is the role of animals and plants. It will be shown that in all discussed geo-ecosystems plants and animals can be seen as geo-ecosystem engineers and are also important at broader scales with respect to runoff generation and sediment transport. For the temperate zone a case study from the cuesta landscape of the Paris Basin will be discussed, showing that fine scale, soil physico-chemical processes, soil animal and vegetation related processes lead to the emergence of partial areas and also play an important role in the formation of the cuestas itself. For the Mediterranean a case study is discussed where vegetation pattern heterogeneity determines water and sediment distribution from the patch to the sub-catchment scale leading to the emergence of either sheetwash generated slopes (pediments) or concentrated flow generated slopes (gullies), but where inherited landscape elements such as pediments with calcretes strongly affect runoff generation and the availability of sediments and hence have a strong impact on the sediment redistribution and measured erosion rates that strongly vary with the scale at which they are measured. Finally a case study from a semi-arid Sahelian ecosystem is discussed where runoff generation and sediment sources are strongly related to the semi-natural upper landscape zones with a strong interplay between vegetation and surface conditions, and where land use in the lower landscape units is an important sink area for both sediment and water. Landscape heterogeneity and the distribution of source and sinks of water and sediment is often strongly disconnected and shows clear physical thresholds that can be either of natural origin (e.g. vegetation clumps and patterns) or man-made (e.g. terraces). These physical thresholds are also important as temporary sediment sinks, that may convert to sediment sources during high magnitude events. The connectivity of sediment flow and hence sediment delivery to lower landscape units or larger channels is therefore highly variable and strongly dependent on both finer scale landscape elements and their specific position in the landscape, and the frequency-magnitude relationships of rainfall. It can be concluded that aspects of hydrological connectivity, temporary sinks of water and sediment in combination with biophysical and anthropogenic thresholds as well as storm characteristics should be included when scaling landscape processes to understand erosion and sediment yields. Furthermore the role and importance of biotic components in erosion studies is still underrated, despite the fact that vegetation is more and more applied to reduce erosion.

  5. Validation of an updated fractionation and indirect speciation procedure for inorganic arsenic in oxic and suboxic soils and sediments.

    PubMed

    Lock, Alan; Wallschläger, Dirk; McMurdo, Colin; Tyler, Laura; Belzile, Nelson; Spiers, Graeme

    2016-12-01

    A sequential extraction procedure (SEP) for the speciation analysis of As(III) and As(V) in oxic and suboxic soils and sediments was validated using a natural lake sediment and three certified reference materials, as well as spike recoveries of As(III) and As(V). Many of the extraction steps have been previously validated making the procedure useful for comparisons to similar previous SEP studies. The novel aspect of this research is the validation for the SEP to maintain As(III) and As(V) species. The proposed five step extraction procedure includes the extraction agents (NH 4 ) 2 SO 4 , NH 4 H 2 PO 4 , H 3 PO 4  + NH 2 OH·HCl, oxalate + ascorbic acid (heated), and HNO 3  + HCl + HF, targeting operationally defined easily exchangeable, strongly sorbed, amorphous Fe oxide bound, crystalline Fe oxide bound, and residual As fractions, respectively. The third extraction step, H 3 PO 4  + NH 2 OH·HCl, has not been previously validated for fraction selectivity. We present evidence for this extraction step to target As complexed with amorphous Fe oxides when used in the SEP proposed here. All solutions were analyzed on ICP-MS. The greatest concentrations of As were extracted from the amorphous Fe oxide fraction and the dominant species was As(V). Lake sediment materials were found to have higher As(III) concentrations than the soil materials. Because different soils/sediments have different chemical characteristics, maintenance of As species during extractions must be validated for specific soil/sediment types using spiking experiments. Copyright © 2016 Elsevier Ltd. All rights reserved.

  6. Radionuclides deposition and fine sediment transport in a forested watershed, central Japan

    NASA Astrophysics Data System (ADS)

    Nam, S.; Gomi, T.; Kato, H.; Tesfaye, T.; Onda, Y.

    2011-12-01

    We investigated radionuclides deposition and fine sediment transport in a 13 ha headwater watershed, Tochigi prefecture, located in 98.94 km north of Tokyo. The study site was within Karasawa experimental forest, Tokyo University of Agriculture and Technology. We conducted fingerprinting approach, based on the activities of fallout radionuclides, including caesium-134 (Cs-134) caesium-137 (Cs-137) and excess lead-210 (Pb-210ex). For indentifying specific sources of fine sediment, we sampled tree, soil on forested floor, soil on logging road surface, stream bed and stream banks. We investigated the radionuclides (i.e., as Cs-134, Cs-137 and Pb-210ex) deposition on tree after accident of nuclear power plants on March 11, 2011. We sampled fruits, leaves, branches, stems, barks on Japanese cedar (Sugi) and Japanese cypress (Hinoki). To analyze the samples, gammaray spectrometry was performed at a laboratory at the University of Tsukuba (Tsukuba City, Japan) using n-type coaxial low-energy HPGe gamma detectors (EGC-200-R and EGC25-195-R of EURYSIS Co., Lingolsheim, France) coupled with a multichannel analyzer. We also collected soil samples under the forest canopy in various soil depths from 2, 5, 10, 20, 30 cm along transect of hillslopes. Samples at forest road were collected road segments crossing on the middle section of monitoring watersheds. Fine sediment transport in the streams were collected at the outlet of 13 ha watersheds using integrated suspended sediment samplers. This study indicates the some portion of radio nuclide potentially remained on the tree surface. Part of the deposited radionuclides attached to soil particles and transported to the streams. Most of the fine sediment can be transported on road surface and/or near stream side (riparian zones).

  7. Searsville Sediment Experiment: What is the ideal agricultural soil?

    NASA Astrophysics Data System (ADS)

    Leal, J.; Lo, D.; Patel, N.; Gu, S.

    2014-12-01

    The purpose of this experiment is to decide whether or not the sediment located within Searsville Dam at the Jasper Ridge Biological Preserve is well suited for agricultural soil. By utilizing various combinations of sediment, farm soil, compost, and horse manure to grow basil plants, we underwent an exploratory study in order to better understand what type of materials and nutrients plants can best thrive within. Our general experiment protocol includes watering the crops with irrigation every day while young, and then limiting that water exposure to only Mondays, Wednesdays, and Fridays as they become more established. The basil is growing in pots filled with the different amounts of material, and are arranged randomly to prevent certain plants from getting more sunlight than others. The whole experiment plot is covered with a thin white fabric and secured with bricks and wood to keep out pests in the garden. In order to observe trends in the basil development, plant height and leaf number is recorded once every week. During the third week of the study we performed soil texture tests, and within the fourth week we calculated pH data. We discovered that the sediment our project focuses upon is 10-18% clay and 50% sand which categorizes it as loam, and the Stanford farm soil that serves as our control group contains 20-26% clay and 30% sand so it is a silt loam material. The pH tests also showed an average of 7.45 for sediment, 7.3 for farm soil, 7.85 for compost, and 7.65 for horse manure. By looking at all of the data recorded over the five-week time period, we have so far noticed that the 50% sediment and 50% horse manure combination consistently has the best height increase as well as leaf size and content. The 50% sediment and 50% compost mixture has also performed well in those terms, and is therefore a possibility for the best agricultural soil. However, future lab work conducted by Stanford students to examine the nutrient content of the basil tissue, along with the study of other types of plants in each agricultural medium, will be the determining factors when deciding whether or not the sediment from Searsville Dam is the ideal substance for growing crops, especially when mixed with other fertile substances.

  8. Soils as Sediment database: closing a gap between soil science and geomorphology

    NASA Astrophysics Data System (ADS)

    Kuhn, Nikolaus J.

    2016-04-01

    Soils are an interface between the Earth's spheres and shaped by the nature of the interaction between them. The relevance of soil properties for the nature of the interaction between atmosphere, hydrosphere and biosphere is well-studied and accepted, on point- or ecotone-scale. However, this understanding of the largely vertical connections between spheres is not matched by a similar recognition of soil properties affecting processes acting largely in a lateral way across the land surface, such as erosion, transport and deposition of soil. Key areas where such an understanding is essential are all issues related to the lateral movement of soil-bound substances that affect the nature of soils itself, as well as water or vegetation downslope from the source area. The redistribution of eroded soil falls several disciplines, most notably soil science, agronomy, hydrology and geomorphology. Accordingly, the way sediment is described differs: in soil science, aggregation and structure are essential properties, while most process-based soil erosion models treat soil as a mixture of individual mineral grains, based on concepts derived in fluvial geomorphology or civil engineering. The actual behavior of aggregated sediment is not reflected by either approach and difficult to capture due to the dynamic nature of aggregation, especially in an environment such as running water. Still, a proxy to assess the uncertainties introduced by aggregation on the behavior of soil as sediment would represent a step forward. To develop such a proxy, a database collating relevant soil and sediment properties could serve as an initial step to identify which soil types and erosion scenarios are prone to generate a high uncertainty compared to the use of soil texture in erosion models. Furthermore, it could serve to develop standardized analytical procedures for appropriate description of soil as sediment.

  9. Partition characteristics of polycyclic aromatic hydrocarbons on soils and sediments

    USGS Publications Warehouse

    Chiou, C.T.; Mcgroddy, S.E.; Kile, D.E.

    1998-01-01

    The partition behavior was determined for three polycyclic aromatic hydrocarbons (PAHs), i.e., naphthalene, phenanthrene, and pyrene, from water to a range of soil and sediment samples. The measured partition coefficients of the individual PAHs between soil/sediment organic matter (SOM) and water (i.e., K(oc) values) are relatively invariant either for the 'clean' (uncontaminated) soils or for the clean sediments; however, the mean K(oc) values on the sediments are about twice the values on the soils. This disparity is similar to the earlier observation for other nonpolar solutes and reflects the compositional differences between soil and sediment organic matters. No significant differences in K(oc) are observed between a clean coastal marine sediment and freshwater sediments. The coastal sediments that are significantly impacted by organic contaminants exhibit higher K(oc) values. At given K(ow) values (octanol-water), the PAHs exhibit much higher K(oc) values than other relatively nonpolar solutes (e.g., chlorinated hydrocarbons). This effect is shown to result from the enhanced partition of PAHs to SOM rather than from lower K(ow) values of PAHs at given supercooled liquid solute solubilities in water. The enhanced partition of PAHs over other nonpolar solutes in SOM provides an account of the markedly different correlations between log K(oc) and log K(ow) for PAHs and for other nonpolar solutes. The improved partition of PAHs in SOM stems apparently from the enhanced compatibility of their cohesive energy densities with those of the aromatic components in SOM. The approximate aromatic fraction in soil/sediment organic matter has been assessed by solid-state 13C-NMR spectroscopy.The partition behavior was determined for three polycyclic aromatic hydrocarbons (PAHs), i.e., naphthalene, phenanthrene, and pyrene, from water to a range of soil and sediment samples. The measured partition coefficients of the individual PAHs between soil/sediment organic matter (SOM) and water (i.e., Koc values) are relatively invariant either for the `clean' (uncontaminated) soils or for the clean sediments; however, the mean Koc values on the sediments are about twice the values on the soils. This disparity is similar to the earlier observation for other nonpolar solutes and reflects the compositional differences between soil and sediment organic matters. No significant differences in Koc are observed between a clean coastal marine sediment and freshwater sediments. The coastal sediments that are significantly impacted by organic contaminants exhibit higher Koc values. At given Kow values (octanol-water), the PAHs exhibit much higher Koc values than other relatively nonpolar solutes (e.g., chlorinated hydrocarbons). This effect is shown to result from the enhanced partition of PAHs to SOM rather than from lower Kow values of PAHs at given supercooled liquid solute solubilities in water. The enhanced partition of PAHs over other nonpolar solutes in SOM provides an account of the markedly different correlations between log Koc and log Kow for PAHs and for other nonpolar solutes. The improved partition of PAHs in SOM stems apparently from the enhanced compatibility of their cohesive energy densities with those of the aromatic components in SOM. The approximate aromatic fraction in soil/sediment organic matter has been assessed by solid-state 13C-NMR spectroscopy.

  10. Soil erosion and sediment yield and their relationships with vegetation cover in upper stream of the Yellow River.

    PubMed

    Ouyang, Wei; Hao, Fanghua; Skidmore, Andrew K; Toxopeus, A G

    2010-12-15

    Soil erosion is a significant concern when considering regional environmental protection, especially in the Yellow River Basin in China. This study evaluated the temporal-spatial interaction of land cover status with soil erosion characteristics in the Longliu Catchment of China, using the Soil and Water Assessment Tool (SWAT) model. SWAT is a physical hydrological model which uses the RUSLE equation as a sediment algorithm. Considering the spatial and temporal scale of the relationship between soil erosion and sediment yield, simulations were undertaken at monthly and annual temporal scales and basin and sub-basin spatial scales. The corresponding temporal and spatial Normalized Difference Vegetation Index (NDVI) information was summarized from MODIS data, which can integrate regional land cover and climatic features. The SWAT simulation revealed that the annual soil erosion and sediment yield showed similar spatial distribution patterns, but the monthly variation fluctuated significantly. The monthly basin soil erosion varied from almost no erosion load to 3.92 t/ha and the maximum monthly sediment yield was 47,540 tones. The inter-annual simulation focused on the spatial difference and relationship with the corresponding vegetation NDVI value for every sub-basin. It is concluded that, for this continental monsoon climate basin, the higher NDVI vegetation zones prevented sediment transport, but at the same time they also contributed considerable soil erosion. The monthly basin soil erosion and sediment yield both correlated with NDVI, and the determination coefficients of their exponential correlation model were 0.446 and 0.426, respectively. The relationships between soil erosion and sediment yield with vegetation NDVI indicated that the vegetation status has a significant impact on sediment formation and transport. The findings can be used to develop soil erosion conservation programs for the study area. Copyright © 2010 Elsevier B.V. All rights reserved.

  11. Assessment of contemporary erosion/sedimentation rates trend within a small well-cultivated catchments using caesium-137 as a chronomarker (on the example of the Republic of Tatarstan, Russia)

    NASA Astrophysics Data System (ADS)

    Sharifullin, Aidar; Gusarov, Artem; Gafurov, Artur; Golosov, Valentin

    2017-04-01

    An analysis of sedimentation at a first order valley bottoms allows us to receive a sufficiently reliable quantitative evaluation of soil losses from the catchment area for two time intervals: 1963-1986 and 1987-2015 and its temporal variability. The studied catchment "Temeva River" with total area 1.13 km2 is located in the northwestern part of the Republic of Tatarstan (the Myósha river basin). Combination methods and approaches were used for evaluation of sediment redistribution for the both time intervals, including detail geodetic survey of the main morphological units of the valley, large scale geomorphological mapping, cesium-137 technique for the sediment dating in the typical locations of the valley bottom, calculation of soil losses using modified version of USLE and State Hydrological Institute models. In addition available information was collected from the local meteorological stations about some climate characteristics dynamics for the period 1950-2015. Landsat images were applied for evaluation of possible changes of land use. Crop management coefficients were calculated separately for the rainfall season and snow-melt using available data about crop-rotation dynamics for the last 55 years. In the results it was found the significant decrease of average annual soil losses from the cultivated part of the "Temeva River" catchment for the period 1987-2015 if it is compare with period 1963-1986. Such conclusion is mainly based on the different sedimentation rates in the valley bottom: for the period of 1963-1986 the average sedimentation rates were 0.92-1.81 cm per year, while the period of 1987-2015 the rates were 0.17-0.50 cm per year. The main reason for this significant decrease sediment redistribution within the catchment is the reduction of surface runoff caused by climate warming in the region. It is led to the reduction of soils freezing depth and water reserves in a snow cover before the snow-melt, and to the sharp decline in the frequency of extreme (storm) precipitation (>50 mm per a day). The influence of agricultural activity on the erosion and sedimentation changeability was insignificant, although some regional variation of crop rotation including an increase in the proportion of perennial grasses obviously caused the decline in soil losses during warm period of year. The similar trend of erosion/sedimentation rates due to mostly climate changes was identified for south-western sector of the East European Plain, but the more serious reduction of erosion rates is established for the Middle Volga region. Keywords: erosion, sedimentation, sediment, caesium-137, dry valley, small catchment, cultivated lands, Republic of Tatarstan, East European Plain.

  12. Response of microbial community and catabolic genes to simulated petroleum hydrocarbon spills in soils/sediments from different geographic locations.

    PubMed

    Liu, Q; Tang, J; Liu, X; Song, B; Zhen, M; Ashbolt, N J

    2017-10-01

    Study the response of microbial communities and selected petroleum hydrocarbon (PH)-degrading genes on simulated PH spills in soils/sediments from different geographic locations. A microcosm experiment was conducted by spiking mixtures of petroleum hydrocarbons (PHs) to soils/sediments collected from four different regions of China, including the Dagang Oilfield (DG), Sand of Bohai Sea (SS), Northeast China (NE) and Xiamen (XM). Changes in bacterial community and the abundance of PH-degrading genes (alkB, nah and phe) were analysed by denaturing gradient electrophoresis (DGGE) and qPCR, respectively. Degradation of alkanes and PAHs in SS and NE materials were greater (P < 0·05) than those in DG and XM. Clay content was negatively correlated with the degradation of total alkanes by 112 days and PAHs by 56 days, while total organic carbon content was negatively correlated with initial degradation of total alkanes as well as PAHs. Abundances of alkB, nah and phe genes increased 10- to 100-fold and varied by soil type over the incubation period. DGGE fingerprints identified the dominance of α-, β- and γ-Proteobacteria (Gram -ve) and Actinobacteria (Gram +ve) bacteria associated with degradation of PHs in the materials studied. The geographic divergence resulting from the heterogeneity of physicochemical properties of soils/sediments appeared to influence the abundance of metabolic genes and community structure of microbes capable of degrading PHs. When developing practical in-situ bioremediation approaches for PHs contamination of soils/sediment, appropriate microbial community structures and the abundance of PH-degrading genes appear to be influenced by geographic location. © 2017 The Society for Applied Microbiology.

  13. Quantifying Construction Site Sediment Discharge Risk and Treatment Potential

    NASA Astrophysics Data System (ADS)

    Ferrell, L.; Beighley, R. E.

    2006-12-01

    Dealing with soil erosion and sediment transport can be a significant challenge during the construction process due to the potentially large spatial and temporal extent and conditions of bare soils. Best Management Practices (BMP) are commonly used to eliminate or reduce offsite discharge of sediment. However, few efforts have investigated the time varying risk of sediment discharge from construction sites, which often have dynamic soil conditions and the potential for less than optimal BMP installations. The goal of this research is to improve the design, implementation and effectiveness of sediment and erosion control at construction sites using site specific, temporal distributions of sediment discharge risk. Sediment risk is determined from individual factors leading to sediment expert, such as rainfall frequency, the adequacy of BMP installations, and the extent and duration of bare soil conditions. This research specifically focuses on quantifying: (a) the effectiveness of temporary sediment and control erosion control BMPs in preventing, containing, and/or treating construction site sediment discharge at varying levels of "proper" installation, and (b) sediment discharge potential from construction sites during different phases of construction, (ex., disturbed earth operations). BMPs are evaluated at selected construction sites in southern California and at the Soil Erosion Research Laboratory (SERL) in the Civil and Environmental Engineering department at San Diego State University. SERL experiments are performed on a 3-m by 10-m tilting soil bed with soil depths up to 1 meter, slopes ranging from 0 to 50 percent, and rainfall rates up to 150 mm/hr (6 in/hr). BMP performance is assessed based on experiments where BMPs are installed per manufacture specifications, potential less than optimal installations, and no treatment conditions. Soil conditions are also varied to represent site conditions during different phases of construction (i.e., loose lifts, stock piles, temporary roads, finished grade, others). Preliminary site monitoring, experimental results, and a conceptual model for estimating the time depend risk of sediment discharge over the duration of a construction project are presented.

  14. Ecoenzymatic Stoichiometry of Stream Sediments with Comparison to Terrestrial Soils

    EPA Science Inventory

    In this study, we extend the development of ecoenzymatic stoichiometry to the surface sediments of stream ecosystems using data collected in a nationwide survey. The data set is larger and more comprehensive than those used in our previous studies. The data include the first broa...

  15. Superfund Record of Decision (EPA Region 5): Summit National Liquid Disposal Service, Deerfield, OH. (First remedial action), (Amendment), November 1990. Final report

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Not Available

    The 11.5-acre Summit National Liquid Disposal Service site is a former liquid waste disposal facility in rural Deerfield Township, Ohio. The site contains two ponds, an inactive incinerator, and several vacant buildings. Surrounding the site are several residences, two landfills, light industries, and farmland. From 1973 to 1978, Summit National operated a solvent recycling and waste disposal facility onsite. The Record of Decision (ROD) amends a 1988 ROD that provided for remediation of contaminated soil, sediment, debris, ground water, and surface water. In both the 1990 proposed remedy for the ROD amendment and the 1988 ROD, the remedy for themore » most highly contaminated soil and sediment is excavation and treatment. The amended remedial action for the site includes expanding site boundaries to include contaminated areas along the site perimeters; excavating and incinerating onsite 24,000 cubic yards of soil excavated to a depth of 2 feet, 4,000 cubic yards of sediment from the site perimeter, drainage ditches and offsite ponds, and 900 to 1,600 buried drums.« less

  16. A procedure for estimating Bacillus cereus spores in soil and stream-sediment samples - A potential exploration technique

    USGS Publications Warehouse

    Watterson, J.R.

    1985-01-01

    The presence of bacterial spores of the Bacillus cereus group in soils and stream sediments appears to be a sensitive indicator of several types of concealed mineral deposits, including vein-type gold deposits. The B. cereus assay is rapid, inexpensive, and inherently reproducible. The test, currently under investigation for its potential in mineral exploration, is recommended for use on a research basis. Among the aerobic spore-forming bacilli, only B. cereus and closely related strains produce an opaque zone in egg-yolk emulsion agar. This characteristic, also known as the Nagler of lecitho-vitellin reaction, has long been used to rapidly indentify and estimate presumptive B. cereus. The test is here adapted to permit rapid estimation of B. cereus spores in soil and stream-sediment samples. Relative standard deviation was 10.3% on counts obtained from two 40-replicate pour-plate determinations. As many as 40 samples per day can be processed. Enough procedural detail is included to permit investigation of the test in conventional geochemical laboratories using standard microbiological safety precautions. ?? 1985.

  17. Particle size analysis of sediments, soils and related particulate materials for forensic purposes using laser granulometry.

    PubMed

    Pye, Kenneth; Blott, Simon J

    2004-08-11

    Particle size is a fundamental property of any sediment, soil or dust deposit which can provide important clues to nature and provenance. For forensic work, the particle size distribution of sometimes very small samples requires precise determination using a rapid and reliable method with a high resolution. The Coulter trade mark LS230 laser granulometer offers rapid and accurate sizing of particles in the range 0.04-2000 microm for a variety of sample types, including soils, unconsolidated sediments, dusts, powders and other particulate materials. Reliable results are possible for sample weights of just 50 mg. Discrimination between samples is performed on the basis of the shape of the particle size curves and statistical measures of the size distributions. In routine forensic work laser granulometry data can rarely be used in isolation and should be considered in combination with results from other techniques to reach an overall conclusion.

  18. Reducing sedimentation of depressional wetlands in agricultural landscapes

    USGS Publications Warehouse

    Skagen, S.K.; Melcher, Cynthia; Haukos, D.A.

    2008-01-01

    Depressional wetlands in agricultural landscapes are easily degraded by sediments and contaminants accumulated from their watersheds. Several best management practices can reduce transport of sediments into wetlands, including the establishment of vegetative buffers. We summarize the sources, transport dynamics, and effect of sediments, nutrients, and contaminants that threaten wetlands and the current knowledge of design and usefulness of grass buffers for protecting isolated wetlands. Buffer effectiveness is dependent on several factors, including vegetation structure, buffer width, attributes of the surrounding watershed (i.e., area, vegetative cover, slope and topography, soil type and structure, soil moisture, amount of herbicides and pesticides applied), and intensity and duration of rain events. To reduce dissolved contaminants from runoff, the water must infiltrate the soil where microbes or other processes can break down or sequester contaminants. But increasing infiltration also diminishes total water volume entering a wetland, which presents threats to wetland hydrology in semi-arid regions. Buffer effectiveness may be enhanced significantly by implementing other best management practices (e.g., conservation tillage, balancing input with nutrient requirements for livestock and crops, precision application of chemicals) in the surrounding watershed to diminish soil erosion and associated contaminant runoff. Buffers require regular maintenance to remove sediment build-up and replace damaged or over-mature vegetation. Further research is needed to establish guidelines for effective buffer width and structure, and such efforts should entail a coordinated, regional, multi-scale, multidisciplinary approach to evaluate buffer effectiveness and impacts. Direct measures in "real-world" systems and field validations of buffer-effectiveness models are crucial next steps in evaluating how grass buffers will impact the abiotic and biotic variables attributes that characterize small, isolated wetlands. ?? 2008 The Society of Wetland Scientists.

  19. BERGMANN USA SOIL SEDIMENT WASHING TECHNOLOGY - APPLICATIONS ANALYSIS REPORT

    EPA Science Inventory

    This document provides an evaluation of the performance of the Bergmann USA Soil/Sediment Washing System and its applicability for the treatment of soils or sediments contaminated with organic and/or inorganic compounds. Both the technical and economic aspects of the technology w...

  20. Occurrence and source apportionment of polycyclic aromatic hydrocarbons in soils and sediment from Hanfeng Lake, Three Gorges, China.

    PubMed

    Cai, Jing; Gao, Shutao; Zhu, Like; Jia, Xuwei; Zeng, Xiangying; Yu, Zhiqiang

    2017-11-10

    This study was conducted to investigate the pollutant status and the retention mechanism of polycyclic aromatic hydrocarbons (PAHs) in soils and sediment from bank-water-level-fluctuating zone (WLFZ)-water systems in Hanfeng Lake, Three Gorges, China. The concentrations of the 16 PAHs ranged from 21.8 to 1324 ng g -1 dry wt for all 20 soil and sediment samples. These concentration levels were remarkably lower than those in soils and sediment collected domestically and worldwide. PAHs with two and three rings were found to be dominant in all the samples, with phenanthrene being most abundant. The spatial distribution of PAHs in bank soil, WLFZ soil, and sediment implied that the transfer and fate of PAHs in the bank soil-WLFZ soil-sediment systems were influenced by both water dynamic factors and physicochemical properties of PAHs. Diagnostic ratio analysis and principal component analysis suggested that the PAHs in the areas of Hanfeng Lake were primarily (>75%) derived from coal combustion and vehicle emissions . Use of natural gas, improving gasoline/diesel quality and phasing out old and nonstandard vehicles and ships are proposed to control PAH contamination and protect drinking water safety in the region.

  1. Correlation of soil and sediment organic matter polarity to aqueous sorption of nonionic compounds

    USGS Publications Warehouse

    Kile, D.E.; Wershaw, R. L.; Chiou, C.T.

    1999-01-01

    Polarities of the soiL/sediment organic matter (SOM) in 19 soil and 9 freshwater sediment sam pies were determined from solid-state 13C-CP/MAS NMR spectra and compared with published partition coefficients (K(oc)) of carbon tetrachloride (CT) from aqueous solution. Nondestructive analysis of whole samples by solid-state NMR permits a direct assessment of the polarity of SOM that is not possible by elemental analysis. The percent of organic carbon associated with polar functional groups was estimated from the combined fraction of carbohydrate and carboxylamide-ester carbons. A plot of the measured partition coefficients (K(oc)) of carbon tetrachloride (CT) vs. percent polar organic carbon (POC) shows distinctly different populations of soils and sediments as well as a roughly inverse trend among the soil/sediment populations. Plots of K(oc) values for CT against other structural group carbon fractions did not yield distinct populations. The results indicate that the polarity of SOM is a significant factor in accounting for differences in K(oc) between the organic matter in soils and sediments. The alternate direct correlation of the sum of aliphatic and aromatic structural carbons with K(oc) illustrates the influence of nonpolar hydrocarbon on solute partition interaction. Additional elemental analysis data of selected samples further substantiate the effect of the organic matter polarity on the partition efficiency of nonpolar solutes. The separation between soil and sediment samples based on percent POC reflects definite differences of the properties of soil and sediment organic matters that are attributable to diagenesis.Polarities of the soil/sediment organic matter (SOM) in 19 soil and 9 freshwater sediment samples were determined from solid-state 13C-CP/MAS NMR spectra and compared with published partition coefficients (Koc) of carbon tetrachloride (CT) from aqueous solution. Nondestructive analysis of whole samples by solid-state NMR permits a direct assessment of the polarity of SOM that is not possible by elemental analysis. The percent of organic carbon associated with polar functional groups was estimated from the combined fraction of carbohydrate and carboxyl-amide-ester carbons. A plot of the measured partition coefficients (Koc) of carbon tetrachloride (CT) vs. percent polar organic carbon (POC) shows distinctly different populations of soils and sediments as well as a roughly inverse trend among the soil/sediment populations. Plots of Koc values for CT against other structural group carbon fractions did not yield distinct populations. The results indicate that the polarity of SOM is a significant factor in accounting for differences in Koc between the organic matter in soils and sediments. The alternate direct correlation of the sum of aliphatic and aromatic structural carbons with Koc illustrates the influence of nonpolar hydrocarbon on solute partition interaction. Additional elemental analysis data of selected samples further substantiate the effect of the organic matter polarity on the partition efficiency of nonpolar solutes. The separation between soil and sediment samples based on percent POC reflects definite differences of the properties of soil and sediment organic matters that are attributable to diagenesis.

  2. Erodibility of calcareous soils as influenced by land use and intrinsic soil properties in a semiarid region of central Iran.

    PubMed

    Ayoubi, Shamsollah; Mokhtari, Javad; Mosaddeghi, Mohammad Reza; Zeraatpisheh, Mojtaba

    2018-03-06

    The most important properties affecting the soil loss and runoff were investigated, and the effects of land use on the soil properties, together with the erodibility indices in a semiarid zone, central Iran, were evaluated. The locations of 100 positions were acquired by cLHS and 0-5-cm surface soil layer samples were used for laboratory analyses from the Borujen Region, Chaharmahal-Va-Bakhtiari Province, central Iran. To measure in situ runoff and soil erodibility of three different land uses comprising dryland, irrigated farming, and rangeland, a portable rainfall simulator was used. The results showed that the high variations (coefficient of variation, CV) were obtained for electrical conductivity (EC), mean weight diameter (MWD), soil organic carbon (SOC), and soil erodibility indices including runoff volume, soil loss, and sediment concentration (CV ~ 43.6-77.4%). Soil erodibility indices showed positive and significant correlations with bulk density and negative correlations with SOC, MWD, clay content, and soil shear strength in the area under investigation. The values of runoff in the dryland, irrigated farming, and rangeland were found 1.5, 28.9, and 58.7 cm 3 ; soil loss in the dryland, irrigated farming, and rangeland were observed 0.25, 2.96, and 76.8 g; and the amount of sediment concentration in the dryland, irrigated farming, and rangeland were found 0.01, 0.11, and 0.15 g cm -3 . It is suggested that further investigations should be carried out on soil erodibility and the potential of sediment yield in various land uses with varying topography and soil properties in semiarid regions of Iran facing the high risk of soil loss.

  3. METHODS FOR THE DETERMINATION OF TOTAL ORGANIC CARBON (TOC) IN SOILS AND SEDIMENTS

    EPA Science Inventory

    Organic matter in soils and sediments is widely distributed over the earth's surface occurring in almost all terrestrial and aquatic environments (Schnitzer, 1978). Soils and sediments contain a large variety of organic materials ranging from simple sugars and carbohydrates to th...

  4. Effects of soil surface roughness on interrill erosion processes and sediment particle size distribution

    USDA-ARS?s Scientific Manuscript database

    Soil surface roughness significantly impacts runoff and erosion under rainfall. Few previous studies on runoff generation focused on the effects of soil surface roughness on the sediment particle size distribution (PSD), which greatly affects interrill erosion and sedimentation processes. To address...

  5. Effect of aggregation on SOC transport: linking soil properties to sediment organic matter

    NASA Astrophysics Data System (ADS)

    Kuhn, Nikolaus J.

    2016-04-01

    Soils are an interface between the Earth's spheres and shaped by the nature of the interaction between them. The relevance of soil properties for the nature of the interaction between atmosphere, hydrosphere and biosphere is well-studied and accepted, on point- or ecotone-scale. However, this understanding of the largely vertical connections between spheres is not matched by a similar recognition of soil properties affecting processes acting largely in a lateral way across the land surface, such as erosion, transport and deposition of soil and the associated organic matter. Understanding the redistribution of eroded soil organic matter falls into several disciplines, most notably soil science, agronomy, hydrology and geomorphology, and recently into biogeochemistry. Accordingly, the way soil and sediment are described differs: in soil science, aggregation and structure are essential properties, while most process-based soil erosion models treat soil as a mixture of individual mineral grains, based on concepts derived in fluvial geomorphology or civil engineering. The actual behavior of aggregated sediment and the associated organic matter is not reflected by either approach and difficult to capture due to the dynamic nature of aggregation, especially in an environment such as running water. Still, a proxy to assess the uncertainties introduced by aggregation on the behavior of soil/sediment organic while moving in water across landscapes and into the aquatic system would represent a major step forward. To develop such a proxy, a database collating relevant soil, organic matter and sediment properties could serve as an initial step to identify which soil types and erosion scenarios are prone to generate a high uncertainty compared to the use of soil texture in erosion models. Furthermore, it could serve to develop standardized analytical procedures for appropriate description of soil and organic matter as sediment.

  6. A step towards a holistic assessment of soil degradation in Europe: Coupling on-site erosion with sediment transfer and carbon fluxes.

    PubMed

    Borrelli, P; Van Oost, K; Meusburger, K; Alewell, C; Lugato, E; Panagos, P

    2018-02-01

    Soil degradation due to erosion is connected to two serious environmental impacts: (i) on-site soil loss and (ii) off-site effects of sediment transfer through the landscape. The potential impact of soil erosion processes on biogeochemical cycles has received increasing attention in the last two decades. Properly designed modelling assumptions on effective soil loss are a key pre-requisite to improve our understanding of the magnitude of nutrients that are mobilized through soil erosion and the resultant effects. The aim of this study is to quantify the potential spatial displacement and transport of soil sediments due to water erosion at European scale. We computed long-term averages of annual soil loss and deposition rates by means of the extensively tested spatially distributed WaTEM/SEDEM model. Our findings indicate that soil loss from Europe in the riverine systems is about 15% of the estimated gross on-site erosion. The estimated sediment yield totals 0.164 ± 0.013Pgyr -1 (which corresponds to 4.62 ± 0.37Mgha -1 yr -1 in the erosion area). The greatest amount of gross on-site erosion as well as soil loss to rivers occurs in the agricultural land (93.5%). By contrast, forestland and other semi-natural vegetation areas experience an overall surplus of sediments which is driven by a re-deposition of sediments eroded from agricultural land. Combining the predicted soil loss rates with the European soil organic carbon (SOC) stock, we estimate a SOC displacement by water erosion of 14.5Tg yr -1 . The SOC potentially transferred to the riverine system equals to 2.2Tgyr -1 (~15%). Integrated sediment delivery-biogeochemical models need to answer the question on how carbon mineralization during detachment and transport might be balanced or even off-set by carbon sequestration due to dynamic replacement and sediment burial. Copyright © 2017 The Authors. Published by Elsevier Inc. All rights reserved.

  7. The influence of particles recycling on the geochemistry of sediments in a large tropical dam lake in the Amazonian region, Brazil

    NASA Astrophysics Data System (ADS)

    Fonseca, Rita; Pinho, Catarina; Oliveira, Manuela

    2016-12-01

    As a result of over-erosion of soils, the fine particles, which contain the majority of nutrients, are easily washed away from soils, which become deficient in a host of components, accumulating in lakes. On one hand, the accumulation of nutrients-rich sediments are a problem, as they affect the quality of the overlying water and decrease the water storage capacity of the system; on the other hand, sediments may constitute an important resource, as they are often extremely rich in organic and inorganic nutrients in readily available forms. In the framework of an extensive work on the use of rock related materials to enhance the fertility of impoverish soils, this study aimed to evaluate the role on the nutrients cycle, of particles recycling processes from the watershed to the bottom of a large dam reservoir, at a wet tropical region under high weathering conditions. The study focus on the mineralogical transformations that clay particles undergo from the soils of the drainage basin to their final deposition within the reservoir and their influence in terms of the geochemical characteristics of sediments. We studied the bottom sediments that accumulate in two distinct seasonal periods in Tucuruí reservoir, located in the Amazonian Basin, Brazil, and soils from its drainage basin. The surface layers of sediments in twenty sampling points with variable depths, are representative of the different morphological sections of the reservoir. Nineteen soil samples, representing the main soil classes, were collected near the margins of the reservoir. Sediments and soils were subjected to the same array of physical, mineralogical and geochemical analyses: (1) texture, (2) characterization and semi-quantification of the clay fraction mineralogy and (3) geochemical analysis of the total concentration of major elements, organic compounds (organic C and nitrogen), soluble fractions of nutrients (P and K), exchangeable fractions (cation exchange capacity, exchangeable bases and acidity) and pH(H2O). There is a remarkable homogeneity in the sedimentary distribution along the reservoir in terms of the texture and mineralogy of the clay fraction and of the chemistry of the total, soluble and exchangeable phases. These observations contrast with the physical, morphological and chemical heterogeneity of the soils and the setting lithology. Most of the sediments has a higher contribution of fine-grained material and the mineralogy of the clay fraction is dominated by kaolinite in soils and kaolinite and illite in sediments, followed by lesser amounts of gibbsite, goethite, and metahaloisite and by small/vestigial contents of chlorite and smectite. The sediments are mainly inherited from the watershed but there exist marked differences between the accumulated sediments and their parent materials. These differences mainly come from the selective erosion of fine-grained particles and the extreme climatic conditions which enhance complex transformations of mineralogical and chemical nature. Compared with the parental soils, the reservoir sediments show the following differences: (1) enrichment in fine-grained and less dense inorganic particles, (2) aggradative mineralogical transformations, including enrichment in clay minerals with higher cationic adsorption and exchange capacity, (3) degradation of the crystalline structure of Fe- and Al-oxides (goethite, gibbsite), (4) increase in easily leached elements (Mg, Ca, P, K, Na) and decrease in chemically less mobile elements (Si, Fe) and (5) higher contents of organic carbon, nitrogen, and soluble forms of P and K, mainly concentrated in the clay fraction. These transformations are extremely important in the nutrients cycle, denoting that sediments represent an efficient sink for nutrients from the over-erosion of soils. Mineral and organic compounds can permanently or temporarily sequester these nutrients, recycling them and enhancing their availability through the slow release of components from relatively loose crystal structures. These processes can easily explain the enrichment in soluble and exchangeable forms of elements such as P, K, Ca or Mg. This study conclude that the particles recycling in a large tropical dam reservoir which receives high fluxes of allochthonous nutrients, has an important role in the good quality of sediments for agricultural use and in the profitable use of this technology to recover depleted soils in remediation projects in regions near large hydroelectric plants.

  8. Chemical and biological assessment of Cd-polluted sediment for land use: The effect of stabilization using chitosan-coated zeolite.

    PubMed

    Wen, Jia; Zeng, Guangming

    2018-04-15

    Disposal of dredged sediment contaminated with heavy metals on site or in landfills inevitably causes leaching of metals that generate new environmental problems. In this study, we investigated the effectiveness of stabilizing heavy metal Cd in sediment taken from Dongting Lake, China, using a chitosan-coated zeolite, and assessed the feasibility of reusing the stabilized sediment in river bank soil based on chemical and biological analyses. Results showed that the addition of chitosan-coated zeolite significantly reduced acid-exchangeable Cd by 8% in the dredged sediment and 7% in a sediment-soil mixture. Cadmium leachability was greatly reduced in the amended sediment or sediment-soil mixture. Toxicity bioassay using Eisenia fetida showed the mortality rate of worms reduced by 16% in sediment-soil mixture with a Cd concentration of 550 mg/kg and by 17% under a Cd concentration of 250 mg/kg, both with the addition of modified zeolite. Moreover, assimilation of Cd in the earthworms was decreased by a maximum of 36 mg/kg in the sediment-soil mixture with zeolite amendment. These results indicate that the reuse of Cd-contaminated sediment following chitosan-coated zeolite modification is a feasible option for treating the dredged sediment, and could thus benefit both aquatic and terrestrial systems. Copyright © 2018 Elsevier Ltd. All rights reserved.

  9. Use of the soil and water assessment tool to scale sediment delivery from field to watershed in an agricultural landscape with topographic depressions.

    PubMed

    Almendinger, James E; Murphy, Marylee S; Ulrich, Jason S

    2014-01-01

    For two watersheds in the northern Midwest United States, we show that landscape depressions have a significant impact on watershed hydrology and sediment yields and that the Soil and Water Assessment Tool (SWAT) has appropriate features to simulate these depressions. In our SWAT models of the Willow River in Wisconsin and the Sunrise River in Minnesota, we used Pond and Wetland features to capture runoff from about 40% of the area in each watershed. These depressions trapped considerable sediment, yet further reductions in sediment yield were required for calibration and achieved by reducing the Universal Soil Loss Equation (USLE) cropping-practice (P) factor to 0.40 to 0.45. We suggest terminology to describe annual sediment yields at different conceptual spatial scales and show how SWAT output can be partitioned to extract data at each of these scales. These scales range from plot-scale yields calculated with the USLE to watershed-scale yields measured at the outlet. Intermediate scales include field, upland, pre-riverine, and riverine scales, in descending order along the conceptual flow path from plot to outlet. Sediment delivery ratios, when defined as watershed-scale yields as a percentage of plot-scale yields, ranged from 1% for the Willow watershed (717 km) to 7% for the Sunrise watershed (991 km). Sediment delivery ratios calculated from published relations based on watershed area alone were about 5 to 6%, closer to pre-riverine-scale yields in our watersheds. Copyright © by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, Inc.

  10. Managing salinity in Upper Colorado River Basin streams: Selecting catchments for sediment control efforts using watershed characteristics and random forests models

    USGS Publications Warehouse

    Tillman, Fred; Anning, David W.; Heilman, Julian A.; Buto, Susan G.; Miller, Matthew P.

    2018-01-01

    Elevated concentrations of dissolved-solids (salinity) including calcium, sodium, sulfate, and chloride, among others, in the Colorado River cause substantial problems for its water users. Previous efforts to reduce dissolved solids in upper Colorado River basin (UCRB) streams often focused on reducing suspended-sediment transport to streams, but few studies have investigated the relationship between suspended sediment and salinity, or evaluated which watershed characteristics might be associated with this relationship. Are there catchment properties that may help in identifying areas where control of suspended sediment will also reduce salinity transport to streams? A random forests classification analysis was performed on topographic, climate, land cover, geology, rock chemistry, soil, and hydrologic information in 163 UCRB catchments. Two random forests models were developed in this study: one for exploring stream and catchment characteristics associated with stream sites where dissolved solids increase with increasing suspended-sediment concentration, and the other for predicting where these sites are located in unmonitored reaches. Results of variable importance from the exploratory random forests models indicate that no simple source, geochemical process, or transport mechanism can easily explain the relationship between dissolved solids and suspended sediment concentrations at UCRB monitoring sites. Among the most important watershed characteristics in both models were measures of soil hydraulic conductivity, soil erodibility, minimum catchment elevation, catchment area, and the silt component of soil in the catchment. Predictions at key locations in the basin were combined with observations from selected monitoring sites, and presented in map-form to give a complete understanding of where catchment sediment control practices would also benefit control of dissolved solids in streams.

  11. Coupling a basin erosion and river sediment transport model into a large scale hydrological model: an application in the Amazon basin

    NASA Astrophysics Data System (ADS)

    Buarque, D. C.; Collischonn, W.; Paiva, R. C. D.

    2012-04-01

    This study presents the first application and preliminary results of the large scale hydrodynamic/hydrological model MGB-IPH with a new module to predict the spatial distribution of the basin erosion and river sediment transport in a daily time step. The MGB-IPH is a large-scale, distributed and process based hydrological model that uses a catchment based discretization and the Hydrological Response Units (HRU) approach. It uses physical based equations to simulate the hydrological processes, such as the Penman Monteith model for evapotranspiration, and uses the Muskingum Cunge approach and a full 1D hydrodynamic model for river routing; including backwater effects and seasonal flooding. The sediment module of the MGB-IPH model is divided into two components: 1) prediction of erosion over the basin and sediment yield to river network; 2) sediment transport along the river channels. Both MGB-IPH and the sediment module use GIS tools to display relevant maps and to extract parameters from SRTM DEM (a 15" resolution was adopted). Using the catchment discretization the sediment module applies the Modified Universal Soil Loss Equation to predict soil loss from each HRU considering three sediment classes defined according to the soil texture: sand, silt and clay. The effects of topography on soil erosion are estimated by a two-dimensional slope length (LS) factor which using the contributing area approach and a local slope steepness (S), both estimated for each DEM pixel using GIS algorithms. The amount of sediment releasing to the catchment river reach in each day is calculated using a linear reservoir. Once the sediment reaches the river they are transported into the river channel using an advection equation for silt and clay and a sediment continuity equation for sand. A sediment balance based on the Yang sediment transport capacity, allowing to compute the amount of erosion and deposition along the rivers, is performed for sand particles as bed load, whilst no erosion or deposition is allowed for silt and clay. The model was first applied on the Madeira River basin, one of the major tributaries of the Amazon River (~1.4*106 km2) accounting for 35% of the suspended sediment amount annually transported for the Amazon river to the ocean. Model results agree with observed data, mainly for monthly and annual time scales. The spatial distribution of soil erosion within the basin showed a large amount of sediment being delivered from the Andean regions of Bolivia and Peru. Spatial distribution of mean annual sediment along the river showed that Madre de Dios, Mamoré and Beni rivers transport the major amount of sediment. Simulated daily suspended solid discharge agree with observed data. The model is able to provide temporaly and spatialy distributed estimates of soil loss source over the basin, locations with tendency for erosion or deposition along the rivers, and to reproduce long term sediment yield at several locations. Despite model results are encouraging, further effort is needed to validate the model considering the scarcity of data at large scale.

  12. Major and trace element distribution in soil and sediments from the Egyptian central Nile Valley

    NASA Astrophysics Data System (ADS)

    Badawy, W. M.; Ghanim, E. H.; Duliu, O. G.; El Samman, H.; Frontasyeva, M. V.

    2017-07-01

    The distributions of 32 major and trace elements in 72 surface soil and sediment samples collected from the Asyut to Cairo Nile river section were determined by epithermal neutron activation analysis and compared with corresponding data for the Upper Continental Crust, North American Shale Composite, Average Soil and Average Sediment as well as suspended sediments from Congo and Upper Niger Rivers, in order to establish to which extent the Nile sedimentary material can be related to similar material all over the world as well as to local geology. Their relative distributions indicate the presence of detrital material of igneous origin, most probably resulting from weathering of the Ethiopian Highlands and transported by the Blue Nile, the Nile main tributary. The distributions of nickel, zinc, and arsenic contents suggest that the lower part of the Nile and its surroundings including the Nile Delta is not seriously polluted with heavy metals, so that, in spite of a human activity, which lasted four millennia, the Nile River continues to be less affected by any anthropogenic contamination.

  13. Sediment budget for a polluted Hawaiian reef using hillslope monitoring and process mapping (Invited)

    NASA Astrophysics Data System (ADS)

    Stock, J. D.; Rosener, M.; Schmidt, K. M.; Hanshaw, M. N.; Brooks, B. A.; Tribble, G.; Jacobi, J.

    2010-12-01

    Pollution from coastal watersheds threatens the ecology of the nearshore, including tropical reefs. Suspended sediment concentrations off the reefs of Molokai, Hawaii, chronically exceed a toxic 10 mg/L, threatening reef ecosystems. We hypothesize that historic conversion of hillslope processes from soil creep to overland flow increased both magnitude and frequency of erosion. To create a process sediment budget, we used surficial and ecological mapping, hillslope and stream gages, and novel sensors to locate, quantify and model the generation of fine sediments polluting the reef. Ecological and geomorphic mapping from LiDAR and multi-spectral imagery located overland flow areas with vegetation cover below a threshold preventing erosion. Here, feral goat grazing exposed volcanic soils whose low matrix hydraulic conductivities (1-25 mm/hour) promote Horton overland flow. We instrumented steep, barren hillslopes with soil moisture sensors, overland flow meters, Parshal flumes, ISCO sediment samplers, and a rain gage and conducted repeat Tripod LiDAR and infiltration tests. To characterize soil resistance to overland flow erosion, we used a Cohesive Strength Meter (CSM) to simulate water stress. At the 13.5 km 2 watershed mouth we used a USGS stream gage with an ISCO sediment sampler to estimate total load. Over 3 years, storms triggered overland flow during rainfall intensities above 10-15 mm/hr. Overland flow meters indicate such flows can be up to 3 cm deep, with a tendency to deepen downslope. CSM tests indicate that these depths are insufficient to erode soils where vegetation is dense, but far above threshold values of 2-3 mm for bare soils. Sediment ratings curves for both hillslope and downstream catchment gages show clock-wise hysteresis during the first intense storms in the fall, becoming linear later in the season. During fall storms, sediment concentration is often 10X higher at a given stage. Revised annual lowering rates from experimental hillslopes are 1.5 cm/a (erosion pins), 1.4 cm/a (suspended sediment) and 1.6 cm/a (repeat Tripod LiDAR). These rates are at least 100-fold greater than the long-term river lowering rate of 0.13 mm/a. A sediment budget constructed by extrapolating hillslope lowering rates to the portions of the catchments mapped as unvegetated overland flow predicts a total yearly flux of ~ 6500 t, in agreement with the measured total of ~6200 t. Decadal records illustrate that rainfall intensities sufficient to generate overland flow occur for at least 8-10 hours every year, coincident with 1-3 large storm events. We hypothesize that high lowering rates reflect a combination of long-duration overland flow events, and availability of weathered soils that can be entrained by thin flow. It appears that generation of loose, seasonally weathered silt is a 1st order control on the amount of sediment exported to the reef. If climate change increases storm frequency or duration, or decreases vegetation cover, sediment loading to reefs could increase dramatically.

  14. Demonstration of an In-Situ Friction-Sound Probe for Mapping Particle Size at Contaminated Sediment Sites

    DTIC Science & Technology

    2013-09-01

    management practices resulting in the release of contaminants to soil , sediment, and groundwater in coastal environments. At contaminated sediment sites it...the release of contaminants to soil , sediment, and groundwater in coastal environments. Areas of potential concern at these sites are identified by...study will acquire additional soil and groundwater data necessary to satisfactorily evaluate remedial technologies and develop cleanup goals supporting

  15. Cancer Risk Assessment of Polycyclic Aromatic Hydrocarbons in the Soils and Sediments of India: A Meta-Analysis.

    PubMed

    Tarafdar, Abhrajyoti; Sinha, Alok

    2017-10-01

    A carcinogenic risk assessment of polycyclic aromatic hydrocarbons in soils and sediments was conducted using the probabilistic approach from a national perspective. Published monitoring data of polycyclic aromatic hydrocarbons present in soils and sediments at different study points across India were collected and converted to their corresponding BaP equivalent concentrations. These BaP equivalent concentrations were used to evaluate comprehensive cancer risk for two different age groups. Monte Carlo simulation and sensitivity analysis were applied to quantify uncertainties of risk estimation. The analysis denotes 90% cancer risk value of 1.770E-5 for children and 3.156E-5 for adults at heavily polluted site soils. Overall carcinogenic risks of polycyclic aromatic hydrocarbons in soils of India were mostly in acceptance limits. However, the food ingestion exposure route for sediments leads them to a highly risked zone. The 90% risk values from sediments are 7.863E-05 for children and 3.999E-04 for adults. Sensitivity analysis reveals exposure duration and relative skin adherence factor for soil as the most influential parameter of the assessment, followed by BaP equivalent concentration of polycyclic aromatic hydrocarbons. For sediments, biota to sediment accumulation factor of fish in terms of BaP is most sensitive on the total outcome, followed by BaP equivalent and exposure duration. Individual exposure route analysis showed dermal contact for soils and food ingestion for sediments as the main exposure pathway. Some specific locations such as surrounding areas of Bhavnagar, Raniganj, Sunderban, Raipur, and Delhi demand potential strategies of carcinogenic risk management and reduction. The current study is probably the first attempt to provide information on the carcinogenic risk of polycyclic aromatic hydrocarbons in soil and sediments across India.

  16. Cancer Risk Assessment of Polycyclic Aromatic Hydrocarbons in the Soils and Sediments of India: A Meta-Analysis

    NASA Astrophysics Data System (ADS)

    Tarafdar, Abhrajyoti; Sinha, Alok

    2017-10-01

    A carcinogenic risk assessment of polycyclic aromatic hydrocarbons in soils and sediments was conducted using the probabilistic approach from a national perspective. Published monitoring data of polycyclic aromatic hydrocarbons present in soils and sediments at different study points across India were collected and converted to their corresponding BaP equivalent concentrations. These BaP equivalent concentrations were used to evaluate comprehensive cancer risk for two different age groups. Monte Carlo simulation and sensitivity analysis were applied to quantify uncertainties of risk estimation. The analysis denotes 90% cancer risk value of 1.770E-5 for children and 3.156E-5 for adults at heavily polluted site soils. Overall carcinogenic risks of polycyclic aromatic hydrocarbons in soils of India were mostly in acceptance limits. However, the food ingestion exposure route for sediments leads them to a highly risked zone. The 90% risk values from sediments are 7.863E-05 for children and 3.999E-04 for adults. Sensitivity analysis reveals exposure duration and relative skin adherence factor for soil as the most influential parameter of the assessment, followed by BaP equivalent concentration of polycyclic aromatic hydrocarbons. For sediments, biota to sediment accumulation factor of fish in terms of BaP is most sensitive on the total outcome, followed by BaP equivalent and exposure duration. Individual exposure route analysis showed dermal contact for soils and food ingestion for sediments as the main exposure pathway. Some specific locations such as surrounding areas of Bhavnagar, Raniganj, Sunderban, Raipur, and Delhi demand potential strategies of carcinogenic risk management and reduction. The current study is probably the first attempt to provide information on the carcinogenic risk of polycyclic aromatic hydrocarbons in soil and sediments across India.

  17. Analyses and descriptions of geochemical samples from the Rich Mountain Roadless Area, Fannin and Gilmer counties, Georgia

    USGS Publications Warehouse

    Sears, C.M.; Foose, M.P.; Day, G.W.; Ericksen, M.S.

    1983-01-01

    Semi-quantitative spectrographic analyses for 31 elements on rock, soil, fine-grained stream sediment, bulk stream sediment, and panned stream sediment samples collected in the Rich Mountain Roadless Area, Fannin and Gilmer Counties, Georgia, are reported here. Atomic absorption analyses for gold and fluorometric analyses for uranium are also reported. Brief descriptions of all rock samples analyzed are included.

  18. [Using ultraviolet-visible ( UV-Vis) absorption spectrum to estimate the dissolved organic matter (DOM) concentration in water, soils and sediments of typical water-level fluctuation zones of the Three Gorges Reservoir areas].

    PubMed

    Li, Lu-lu; Jiang, Tao; Lu, Song; Yan, Jin-long; Gao, Jie; Wei, Shi-qiang; Wang, Ding-yong; Guo, Nian; Zhao, Zhena

    2014-09-01

    Dissolved organic matter (DOM) is a very important component in terrestrial ecosystem. Chromophoric dissolved organic matter (CDOM) is a significant constituent of DOM, which can be measured by ultraviolet-visible (UV-Vis) absorption spectrum. Thus the relationship between CDOM and DOM was investigated and established by several types of models including single-wavelength model, double-wavelength model, absorption spectrum slope (S value) model and three-wavelength model, based on the UV-Vis absorption coefficients of soil and sediment samples (sampled in July of 2012) and water samples (sampled in November of 2012) respectively. The results suggested that the three-wavelength model was the best for fitting, and the determination coefficients of water, soil and sediment data were 0. 788, 0. 933 and 0. 856, respectively. Meanwhile, the nominal best model was validated with the UV-Vis data of 32 soil samples and 36 water samples randomly collected in 2013, showing the RRMSE and MRE were 16. 5% and 16. 9% respectively for soil DOM samples, 10. 32% and 9. 06% respectively for water DOM samples, which further suggested the prediction accuracy was higher in water DOM samples as compared with that in soil DOM samples.

  19. Workshop on sediment budgets and routing in forested drainage basins: proceedings.

    Treesearch

    Frederick J. Swanson; Richard J. Janda; Thomas Dunne; Douglas N. Swanston

    1982-01-01

    Sediment budgets quantify the transport and storage of soil and sediment in drainage basins or smaller landscape units. Studies of sediment routing deal with the overall movement of soil and sediment through a series of landscape units. The 14 papers and 5 summaries from discussion groups in this volume report results of sediment budget and routing studies conducted...

  20. Establishing a tracer-based sediment budget to preserve wetlands in Mediterranean mountain agroecosystems (NE Spain).

    PubMed

    Navas, Ana; López-Vicente, Manuel; Gaspar, Leticia; Palazón, Leticia; Quijano, Laura

    2014-10-15

    Mountain wetlands in Mediterranean regions are particularly threatened in agricultural environments due to anthropogenic activity. An integrated study of source-to-sink sediment fluxes was carried out in an agricultural catchment that holds a small permanent lake included in the European NATURA 2000 Network. More than 1000 yrs of human intervention and the variety of land uses pose a substantial challenge when attempting to estimate sediment fluxes which is the first requirement to protect fragile wetlands. To date, there have been few similar studies and those that have been carried out have not addressed such complex terrain. Geostatistical interpolation and GIS tools were used to derive the soil spatial redistribution from point (137)Cs inventories, and to establish the sediment budget in a catchment located in the Southern Pyrenees. The soil redistribution was intense and soil erosion predominated over soil deposition. On the areas that maintained natural vegetation the median soil erosion and deposition rates were moderate, ranging from 2.6 to 6 Mg ha yr(-1) and 1.5 to 2.1 Mg ha yr(-1), respectively. However, in cultivated fields both erosion and deposition were significantly higher (ca. 20 Mg ha yr(-1)), and the maximum rates were always associated with tillage practices. Farming activities in the last part of the 20th century intensified soil erosion, as evidenced by the 1963 (137)Cs peaks in the lake cores and estimates from the sediment budget indicated a net deposition of 671 Mg yr(-1). Results confirm a siltation risk for the lake and provide a foundation for designing management plans to preserve this threatened wetland. This comprehensive approach provides information useful for understanding processes that influence the patterns and rates of soil transfer and deposition within fragile Mediterranean mountain wetlands subjected to climate and anthropogenic stresses. Copyright © 2014 Elsevier B.V. All rights reserved.

  1. Adsorption of tetracycline on soil and sediment: effects of pH and the presence of Cu(II).

    PubMed

    Zhang, Zheyun; Sun, Ke; Gao, Bo; Zhang, Guixiang; Liu, Xitao; Zhao, Ye

    2011-06-15

    Tetracycline (TC) is frequently detected in the environment, however, knowledge on the environmental fate and transport of TC is still limited. Batch adsorption experiments of TC by soil and sediment samples were conducted. The distribution of charge and electrostatic potential of individual atoms of various TC species in the aqueous solution were determined using MOPAC version 0.034 W program in ChemBio3D Ultra software. Most of the adsorption isotherms on the soil, river and marine sediments were well fitted with the Freundlich and Polanyi-Manes (PMM) models. The single point organic carbon (OC)-normalized adsorption distribution coefficients (K(OC)) and PMM saturated adsorption capacity (Q(OC)(0)) values of TC were associated with the mesopore volume and clay content to a greater extent, indicating the mesopore volume of the soil and sediments and their clay content possibly influenced the fate and transport of TC in the natural environment. The adsorption of TC on soil and sediments strongly depended on the pH and presence of Cu(II). The presence of Cu(II) facilitated TC adsorption on soil and sediments at low pH (pH<5), possibly due to the metallic complexation and surface-bridging mechanism by Cu(II) adsorption on soil and sediments. The cation exchange interaction, metallic complexation and Coulombic interaction of mechanisms for adsorption of TC to soils and sediments were further supported by quantum chemical calculation of various TC species in different pH. Copyright © 2011 Elsevier B.V. All rights reserved.

  2. Modeling of soil erosion and sediment transport in the East River Basin in southern China

    USGS Publications Warehouse

    Wu, Yping; Chen, Ji

    2012-01-01

    Soil erosion is a major global environmental problem that has caused many issues involving land degradation, sedimentation of waterways, ecological degradation, and nonpoint source pollution. Therefore, it is significant to understand the processes of soil erosion and sediment transport along rivers, and this can help identify the erosion prone areas and find potential measures to alleviate the environmental effects. In this study, we investigated soil erosion and identified the most seriously eroded areas in the East River Basin in southern China using a physically-based model, Soil and Water Assessment Tool (SWAT). We also introduced a classical sediment transport method (Zhang) into SWAT and compared it with the built-in Bagnold method in simulating sediment transport process along the river. The derived spatial soil erosion map and land use based erosion levels can explicitly illustrate the identification and prioritization of the critical soil erosion areas in this basin. Our results also indicate that erosion is quite sensitive to soil properties and slope. Comparison of Bagnold and Zhang methods shows that the latter can give an overall better performance especially in tracking the peak and low sediment concentrations along the river. We also found that the East River is mainly characterized by sediment deposition in most of the segments and at most times of a year. Overall, the results presented in this paper can provide decision support for watershed managers about where the best management practices (conservation measures) can be implemented effectively and at low cost. The methods we used in this study can also be of interest in sediment modeling for other basins worldwide.

  3. The concentration and chemical speciation of arsenic in the Nanpan River, the upstream of the Pearl River, China.

    PubMed

    Yang, Silin; Zhao, Ning; Zhou, Dequn; Wei, Rong; Yang, Bin; Pan, Bo

    2016-04-01

    The concentration and chemical speciation of arsenic (As) in different environmental matrixes (water, sediment, agricultural soils, and non-agricultural soils) were investigated in the Nanpan River area, the upstream of Pearl River, China. The results did not show any obvious transport of As along the flow direction of the river (from upstream to downstream). Total As concentrations in sediment were significantly different from those in agricultural soil. According to the comparison to quality standards, the As in sediments of the studied area have potential ecological risks and a minority of the sampling sites of agricultural soils in the studied area were polluted with As. As speciations were analyzed using sequential extraction and the percentage of non-residual fraction in sediment predominated over residual fraction. We thus believe that As in the studied area was with low mobility and bioavailability in sediment, agricultural soils, and non-agricultural soils. However, the bioavailability and mobility of As in sediment were higher than in both agricultural and non-agricultural soils, and thus, special attention should be paid for the risk assessment of As in the river in future studies.

  4. DEMONSTRATION BULLETIN: COGNIS TERRAMET LEAD EXTRACTION PROCESS - TWIN CITIES ARMY AMMUNITION PLANT - COGNIS, INC.

    EPA Science Inventory

    The TERRAMET® soil remediation system leaches and recovers lead (including metallic lead, and lead salts and oxides), and other metals from contaminated soil, sludge, or sediment. The system uses a proprietary aqueous leachant that is optimized through treatability tests for the ...

  5. Distributions of polycyclic aromatic hydrocarbons in surface waters, sediments and soils of Hangzhou City, China.

    PubMed

    Chen, Baoliang; Xuan, Xiaodong; Zhu, Lizhong; Wang, Jing; Gao, Yanzheng; Yang, Kun; Shen, Xueyou; Lou, Baofeng

    2004-09-01

    Ten polycyclic aromatic hydrocarbons (PAHs) were simultaneously measured in 17 surface water samples and 11 sediments of four water bodies, and 3 soils near the water-body bank in Hangzhou, China in December 2002. It was observed that the sum of PAHs concentrations ranged from 0.989 to 9.663 microg/L in surface waters, from 132.7 to 7343 ng/g dry weight in sediments, and from 59.71 to 615.8 ng/g dry weight in soils. The composition pattern of PAHs by ring size in water, sediment and soil were surveyed. Three-ring PAHs were dominated in surface waters and soils, meanwhile sediments were mostly dominated by four-ring PAHs. Furthermore, PAHs apparent distribution coefficients (K(d)) and solid f(oc)-normalized K(d) (e.g. K(oc)= K(d) / f(oc)) were calculated. The relationship between logK(oc) and logK(ow) of PAHs for field data on sediments and predicted values were compared. The sources of PAHs in different water bodies were evaluated by comparison of K (oc) values in sediments of the river downstream with that in soils. Hangzhou section of the Great Canal was heavily polluted by PAHs released from industrial wastewater in the past and now PAHs in sediment may serve as sources of PAHs in surface water. PAHs in Qiantang River were contributed from soil runoff. Municipal road runoff was mostly contributed to West Lake PAHs.

  6. Anthropogenic Increase Of Soil Erosion In The Gangetic Plain Revealed By Geochemical Budget Of Erosion

    NASA Astrophysics Data System (ADS)

    Galy, V.; France-Lanord, C.; Galy, A.; Gaillardet, J.

    2007-12-01

    Tectonic and climatic factors are the key natural variables controlling the erosion through complex interactions. Nonetheless, over the last few hundred years, human activity also exerts a dominant control in response to extensive land use. The geochemical budget of erosion allows the balance between the different erosion processes to be quantified. The chemical composition of river sediment results from the chemical composition of the source rock modified by (1) weathering reactions occurring during erosion and (2) physical segregation during transport. If erosion is at steady state, the difference between the chemical composition of source rocks and that of river sediments must therefore be counterbalanced by the dissolved flux. However, climatic variations or anthropic impact can induce changes in the erosion distribution in a given basin resulting in non steady state erosion. Using a mass balance approach, the comparison of detailed geochemical data on river sediments with the current flux of dissolved elements allows the steady state hypothesis to be tested. In this study, we present a geochemical budget of weathering for the Ganga basin, one of the most densely populated basin in the world, based on detailed sampling of Himalayan rivers and of the Ganga in the delta. Sampling includes depth profile in the river, to assess the variability generated by transport processes. Himalayan river sediments are described by the dilution of an aluminous component (micas + clays + feldspars) by quartz. Ganga sediments on the other hand correspond to the mixing of bedload, similar to coarse Himalayan sediments, with an aluminous component highly depleted in alkaline elements. Compared with the dissolved flux, the depletion of alkaline elements in Ganga sediments shows that the alkaline weathering budget is imbalanced. This imbalance results from an overabundance of fine soil material in the Ganga sediment relative to other less weathered material directly derived from Himalaya. Based on the average composition of the suspended load and of floodplain soils, we estimate that 250x106 t/yr i.e. 5 t/ha/yr is eroded from soil surfaces of the Ganga floodplain. This enhanced soil erosion is likely triggered by intense deforestation and change in land use due to increasing human activity in the basin.

  7. Effects of nutrient loading on the carbon balance of coastal wetland sediments

    USGS Publications Warehouse

    Morris, J.T.; Bradley, P.M.

    1999-01-01

    Results of a 12-yr study in an oligotrophic South Carolina salt marsh demonstrate that soil respiration increased by 795 g C m-2 yr-1 and that carbon inventories decreased in sediments fertilized with nitrogen and phosphorus. Fertilized plots became net sources of carbon to the atmosphere, and sediment respiration continues in these plots at an accelerated pace. After 12 yr of treatment, soil macroorganic matter in the top 5 cm of sediment was 475 g C m-2 lower in fertilized plots than in controls, which is equivalent to a constant loss rate of 40 g C m-2 yr-1. It is not known whether soil carbon in fertilized plots has reached a new equilibrium or continues to decline. The increase in soil respiration in the fertilized plots was far greater than the loss of sediment organic matter, which indicates that the increase in soil respiration was largely due to an increase in primary production. Sediment respiration in laboratory incubations also demonstrated positive effects of nutrients. Thus, the results indicate that increased nutrient loading of oligotrophic wetlands can lead to an increased rate of sediment carbon turnover and a net loss of carbon from sediments.

  8. Controls on sediment production in two U.S. deserts

    NASA Astrophysics Data System (ADS)

    Belnap, Jayne; Walker, Beau J.; Munson, Seth M.; Gill, Richard A.

    2014-09-01

    Much of the world’s airborne sediment originates from dryland regions. Soil surface disturbances in these regions are ever-increasing due to human activities such as energy and mineral exploration and development, recreation, suburbanization, livestock grazing and cropping. Sediment production can have significant impacts to human health with particles potentially carrying viruses such as Valley Fever or causing asthma or other respiratory diseases. Dust storms can cause decreased visibility at the ground level, resulting in highway accidents, and reduced visual quality in park and wildland airsheds. Sediment production and deposition is also detrimental to ecosystem health, as production reduces soil fertility at its source and can bury plants and other organisms where it is deposited. Therefore, it is important to understand how we can predict what areas are prone to producing sediment emissions both before and after soil surface disturbance. We visited 87 sites in two deserts of the western U.S. that represented a range of soil texture and surface cover types. We used a portable wind tunnel to estimate the threshold friction velocity (TFV) required to initiate sediment transport and the amount of sediment produced by the tunnel at a set wind speed. Wind tunnel runs were done before and after soil surface disturbance with a four-wheel drive vehicle. Results show that most undisturbed desert soils are very stable, especially if covered by rocks or well-developed biological soil crusts, which make them virtually wind-erosion proof. Particles at disturbed sites, in contrast, moved at relatively low wind speeds and produced high amounts of sediment. Silt was an important predictor of TFV and sediment production across all sites, whereas the influence of rock cover and biological soil crusts was site-dependent. Understanding the vulnerability of a site after disturbance is important information for land managers as they plan land use activities and attempt to mitigate the harmful effects that sediment production can have on both human and ecosystem health.

  9. Controls on sediment production in two U.S. deserts

    USGS Publications Warehouse

    Belnap, Jayne; Walker, Beau J.; Munson, Seth M.; Gill, Richard A.

    2014-01-01

    Much of the world’s airborne sediment originates from dryland regions. Soil surface disturbances in these regions are ever-increasing due to human activities such as energy and mineral exploration and development, recreation, suburbanization, livestock grazing and cropping. Sediment production can have significant impacts to human health with particles potentially carrying viruses such as Valley Fever or causing asthma or other respiratory diseases. Dust storms can cause decreased visibility at the ground level, resulting in highway accidents, and reduced visual quality in park and wildland airsheds. Sediment production and deposition is also detrimental to ecosystem health, as production reduces soil fertility at its source and can bury plants and other organisms where it is deposited. Therefore, it is important to understand how we can predict what areas are prone to producing sediment emissions both before and after soil surface disturbance. We visited 87 sites in two deserts of the western U.S. that represented a range of soil texture and surface cover types. We used a portable wind tunnel to estimate the threshold friction velocity (TFV) required to initiate sediment transport and the amount of sediment produced by the tunnel at a set wind speed. Wind tunnel runs were done before and after soil surface disturbance with a four-wheel drive vehicle. Results show that most undisturbed desert soils are very stable, especially if covered by rocks or well-developed biological soil crusts, which make them virtually wind-erosion proof. Particles at disturbed sites, in contrast, moved at relatively low wind speeds and produced high amounts of sediment. Silt was an important predictor of TFV and sediment production across all sites, whereas the influence of rock cover and biological soil crusts was site-dependent. Understanding the vulnerability of a site after disturbance is important information for land managers as they plan land use activities and attempt to mitigate the harmful effects that sediment production can have on both human and ecosystem health.

  10. Transfer of fallout radionuclides derived from Fukushima NPP accident: 1 year study on transfer of radionuclides through geomorphic processes

    NASA Astrophysics Data System (ADS)

    Onda, Y.; Kato, H.; Fukushima, T.; Wakahara, T.; Kita, K.; Takahashi, Y.; Sakaguchi, A.; Tanaka, K.; Yamashiki, Y.; Yoshida, N.

    2012-12-01

    After the Fukushima Daiichi Nuclear Power Plant acciden, fallout radionuclides on the ground surface will transfer through geomorphic processes. Therefore, in order to estimate future changes in radionuclide deposition, migration process of radionuclides in forests, soils, ground water, rivers, and entrainment from trees and soils should be confirmed. We (FMWSE group) was funded by MEXT, Japanese government, and 1 year following monitoring has been conducted about 1 year. 1 Migration study of radionuclides in natural environment including forests and rivers 1) Study on depth distribution of radiocaesium in soils within forests, fields, and grassland. 2) Confirmation of radionuclide distribution and investigation on migration in forests. 3) Study on radionuclide migration due to soil erosion under different land use. 4) Measurement of radionuclides entrained from natural environment including forests and soils. 2 Migration study of radionuclides through hydrological cycle such as soil water, rivers, lakes and ponds, ground water. 1) Investigation on radionuclide migration through soil water, ground water, stream water, spring water under different land use. 2) Study on paddy-to-river transfer of radionuclides through suspended sediment. 3) Study on river-to-ocean transfer of radionuclides via suspended sediment. 4) Confirmation of radionuclide deposition in ponds and reservoirs. We will present how and where the fallout radionulides transfter through geomorphic processes.

  11. Evaluation of erosion and sedimentation associated with tracked vehicle training

    Treesearch

    Jackie F. Crim; Jon E. Schoonover; Karl W.J. Williard; John W. Groninger; James J. Zaczek; Charles M. Ruffner

    2011-01-01

    A project was designed to assess erosion and sedimentation associated with tracked vehicle training in the Ft. Knox Military Reservation in Kentucky. The project provided an extensive physical and biotic characterization of the training area, including hydrology, water quality, soils, and vegetation. To determine any changes in channel morphology, cross sections were...

  12. Hydroxyatrazine in soils and sediments

    USGS Publications Warehouse

    Lerch, R.N.; Thurman, E.M.; Blanchard, P.E.

    1999-01-01

    Hydroxyatrazine (HA) is the major metabolite of atrazine in most surface soils. Knowledge of HA sorption to soils, and its pattern of stream water contamination suggest that it is persistent in the environment. Soils with different atrazine use histories were collected from four sites, and sediments were collected from an agricultural watershed. Samples were exhaustively extracted with a mixed-mode extractant, and HA was quantitated using high performance liquid chromatography with UV detection. Atrazine, deethylatrazine (DEA), and deisopropylatrazine (DIA) were also measured in all samples. Concentrations of HA were considerably greater than concentrations of atrazine, DEA, and DIA in all soils and sediments studied. Soil concentrations of HA ranged from 14 to 640 ??g/kg with a median concentration of 84 ??g/kg. Sediment concentrations of HA ranged from 11 to 96 ??g/kg, with a median concentration of 14 ??g/kg. Correlations of HA and atrazine concentrations to soil properties indicated that HA levels in soils were controlled by sorption of atrazine. Because atrazine hydrolysis is known to be enhanced by sorption and pH extremes, soils with high organic matter (OM) and clay content and low pH will result in greater atrazine sorption and subsequent hydrolysis. Significant correlation of HA concentrations to OM, pH, and cation exchange capacity of sediments indicated that mixed-mode sorption (i.e., binding by cation exchange and hydrophobic interactions) was the mechanism controlling HA levels in sediment. The presence of HA in soils and stream sediments at the levels observed support existing hypotheses regarding its transport in surface runoff. These results also indicated that persistence of HA in terrestrial and aquatic ecosystems is an additional risk factor associated with atrazine usage.

  13. Transport mechanisms of Silver Nanoparticles by runoff - A Flume Experiment

    NASA Astrophysics Data System (ADS)

    Mahdi Mahdi, Karrar NM; Commelin, Meindert; Peters, Ruud J. B.; Baartman, Jantiene E. M.; Ritsema, Coen; Geissen, Violette

    2017-04-01

    Silver Nanoparticles (AgNPs) are being used in many products as it has unique antimicrobial-biocidal properties. Through leaching, these particles will reach the soil environment which may affect soil organisms and disrupt plants. This work aims to study the potential transport of AgNPs with water and sediment over the soil surface due to soil erosion by water. This was done in a laboratory setting, using a rainfall simulator and flume. Low AgNPs concentration (50 μg.kg-1) was applied to two soil-flumes with slopes of 20% and 10%. The rainfall was applied in four events of 15 min each with the total amount of rainfall was 15mm in each event. After applying the rainfall, different samples were collected; soil clusters, background (BS) and surface sediments (Sf), from the flume surface, and, Runoff sediments (RS) and water (RW) was collected from the outlet. The results showed that AgNPs were detected in all samples collected, however, AgNPs concentration varied according samples type (soil or water), time of collection (for runoff water and sediment) and the slope of the soil flume. Further, the higher AgNPs concentrations were detected in the background soil (BS); as the BS samples have more finer parts (silt and clay). The AgNPs concentration in the runoff sediments increased with subsequent applied rain events. In addition to that, increasing the slope of the flume from 10% to 20% increased the total AgNPs transported with the runoff sediments by a factor 1.5. The study confirms that AgNPs can be transported over the soil surface by both runoff water and sediments due to erosion.

  14. Superfund Record of Decision (EPA Region 7): Mid-America Tanning site, Sergeant bBluff, IA. (First remedial action), September 1991

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Not Available

    1991-09-24

    The 98.7-acre Mid-America Tanning site is a former leather tannery in Sergeant Bluff, Woodbury County, Iowa. Surrounding land use is mixed industrial and agricultural. A portion of the site is bordered by Oxbow Lake and lies within the 100-year floodplain. The Missouri River is approximately 1.5 miles to the southwest of the site and receives discharges from Oxbow Lake. The facility began onsite processing of animal hides in 1970. In 1980, the State confirmed the onsite burial of chromium-containing sludge in trenches, and the company was cited for permit violations. A 1985 EPA investigation identified excessive chromium contamination in onsitemore » soil, sediment, and ground water. In 1990, EPA conducted a removal action that included excavating and consolidating onsite 1,290 cubic yards of sludge from the trench disposal area. The Record of Decision (ROD) addresses the contaminated soil, impoundment sediment and water, and the excavated trench material. A future ROD will address onsite ground water contamination. The primary contaminant of concern affecting the soil, sediment, debris, sludge, and surface water are metals including chromium and lead. The selected remedial action for the site is included.« less

  15. 43 CFR 11.73 - Quantification phase-resource recoverability analysis.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... or sediment properties and adsorption-desorption rates between soil or sediment components and water...) Chemical, physical, and biological removal rates of the oil or hazardous substance from the media involved..., sediments, water, or geologic materials; (B) Transport rates in air, soil, water, and sediments; (C...

  16. Modeling sediment accumulation in North American playa wetlands in response to climate change, 1940-2100

    USGS Publications Warehouse

    Burris, Lucy; Skagen, Susan K.

    2013-01-01

    Playa wetlands on the west-central Great Plains of North America are vulnerable to sediment infilling from upland agriculture, putting at risk several important ecosystem services as well as essential habitats and food resources of diverse wetland-dependent biota. Climate predictions for this semi-arid area indicate reduced precipitation which may alter rates of erosion, runoff, and sedimentation of playas. We forecasted erosion rates, sediment depths, and resultant playa wetland depths across the west-central Great Plains and examined the relative roles of land use context and projected changes in precipitation in the sedimentation process. We estimated erosion with the Revised Universal Soil Loss Equation (RUSLE) using historic values and downscaled precipitation predictions from three general circulation models and three emissions scenarios. We calibrated RUSLE results using field sediment measurements. RUSLE is appealing for regional scale modeling because it uses climate forecasts with monthly resolution and other widely available values including soil texture, slope and land use. Sediment accumulation rates will continue near historic levels through 2070 and will be sufficient to cause most playas (if not already filled) to fill with sediment within the next 100 years in the absence of mitigation. Land use surrounding the playa, whether grassland or tilled cropland, is more influential in sediment accumulation than climate-driven precipitation change.

  17. Heavy metals in soils and sediments from Dongting Lake in China: occurrence, sources, and spatial distribution by multivariate statistical analysis.

    PubMed

    Zhang, Yaxin; Tian, Ye; Shen, Maocai; Zeng, Guangming

    2018-05-01

    Heavy metal contamination in soils/sediments and its impact on human health and ecological environment have aroused wide concerns. Our study investigated 30 samples of soils and sediments around Dongting Lake to analyze the concentration of As, Cd, Cr, Cu, Fe, Mn, Ni, Pb, and Zn in the samples and to distinguish the natural and anthropogenic sources. Also, the relationship between heavy metals and the physicochemical properties of samples was studied by multivariate statistical analysis. Concentration of Cd at most sampling sites were more than five times that of national environmental quality standard for soil in China (GB 15618-1995), and Pb and Zn levels exceeded one to two times. Moreover, Cr in the soil was higher than the national environmental quality standards for one to two times while in sediment was lower than the national standard. The investigation revealed that the accumulations of As, Cd, Mn, and Pb in the soils, and sediments were affected apparently by anthropogenic activities; however, Cr, Fe, and Ni levels were impacted by parent materials. Human activities around Dongting Lake mainly consisted of industrial activities, mining and smelting, sewage discharges, fossil fuel combustion, and agricultural chemicals. The spatial distribution of heavy metal in soil followed the rule of geographical gradient, whereas in sediments, it was significantly affected by the river basins and human activities. The result of principal component analysis (PCA) demonstrated that heavy metals in soils were associated with pH and total phosphorus (TP), while in sediments, As, Cr, Fe, and Ni were closely associated with cation exchange capacity (CEC) and pH, where Pb, Zn, and Cd were associated with total nitrogen (TN), TP, total carbon (TC), moisture content (MC), soil organic matter (SOM), and ignition lost (IL). Our research provides comprehensive approaches to better understand the potential sources and the fate of contaminants in lakeshore soils and sediments.

  18. Microbiology of Wind-eroded Sediments: Current Knowledge and Future Research Directions

    USDA-ARS?s Scientific Manuscript database

    Wind erosion is a threat to the sustainability and productivity of soils that takes place at local, regional, and global scales. Current estimates of cost of wind erosion have not included the costs associated with the loss of soil biodiversity and reduced ecosystem functions. Microorganisms carrie...

  19. HIGHLY SENSITIVE DIOXIN IMMUNOASSAY AND ITS APPLICATIONS TO SOIL AND BIOTA SAMPLES. (R825433)

    EPA Science Inventory

    Tetrachlorodibenzo-p-dioxin (TCDD) is a well-known highly toxic compound that is present in nearly all components of the global ecosystem, including air, soil, sediment, fish and humans. Dioxin analysis is equipment intensive and expensive requiring low ppt or even ppq ...

  20. USING CONONICAL CORRELATION TO DETECT ASSOCIATION OF LANDSCAPE METRICS WITH WATER BIOLOGICAL AND CHEMICAL PROPERTIES IN SAVANNAH RIVER BASIN

    EPA Science Inventory

    Surface water quality is related to conditions in the surrounding geophysical environment, including soils, landcover, and anthropogenic activities. For example, clearing vegetation exposes soil to increased water/wind erosion, resulting in increased sediment loads to surface wat...

  1. Determining soil erosion from roads in coastal plain of Alabama

    Treesearch

    McFero Grace; W.J. Elliot

    2008-01-01

    This paper reports soil losses and observed sediment deposition for 16 randomly selected forest road sections in the National Forests of Alabama. Visible sediment deposition zones were tracked along the stormwater flow path to the most remote location as a means of quantifying soil loss from road sections. Volumes of sediment in deposition zones were determined by...

  2. Keeping agricultural soil out of rivers: evidence of sediment and nutrient accumulation within field wetlands in the UK.

    PubMed

    Ockenden, Mary C; Deasy, Clare; Quinton, John N; Surridge, Ben; Stoate, Chris

    2014-03-15

    Intensification of agriculture has resulted in increased soil degradation and erosion, with associated pollution of surface waters. Small field wetlands, constructed along runoff pathways, offer one option for slowing down and storing runoff in order to allow more time for sedimentation and for nutrients to be taken up by plants or micro-organisms. This paper describes research to provide quantitative evidence for the effectiveness of small field wetlands in the UK landscape. Ten wetlands were built on four farms in Cumbria and Leicestershire, UK. Annual surveys of sediment and nutrient accumulation in 2010, 2011 and 2012 indicated that most sediment was trapped at a sandy site (70 tonnes over 3 years), compared to a silty site (40 tonnes over 3 years) and a clay site (2 tonnes over 3 years). The timing of rainfall was more important than total annual rainfall for sediment accumulation, with most sediment transported in a few intense rainfall events, especially when these coincided with bare soil or poor crop cover. Nutrient concentration within sediments was inversely related to median particle size, but the total mass of nutrients trapped was dependent on the total mass of sediment trapped. Ratios of nutrient elements in the wetland sediments were consistent between sites, despite different catchment characteristics across the individual wetlands. The nutrient value of sediment collected from the wetlands was similar to that of soil in the surrounding fields; dredged sediment was considered to have value as soil replacement but not as fertiliser. Overall, small field wetlands can make a valuable contribution to keeping soil out of rivers. Copyright © 2014 The Authors. Published by Elsevier Ltd.. All rights reserved.

  3. Development and application of screening tools for biodegradation in water-sediment systems and soil.

    PubMed

    Junker, Thomas; Coors, Anja; Schüürmann, Gerrit

    2016-02-15

    Two new screening-test systems for biodegradation in water-sediment systems (WSST; Water-Sediment Screening Tool) and soil (SST; Soil Screening Tool) were developed in analogy with the water-only test system OECD 301C (MITI-test). The test systems could be applied successfully to determine reproducible experimental mineralization rates and kinetics on the screening-test level for fifteen organic chemicals in water (MITI), water-sediment (WSST) and soil (SST). Substance-specific differences were observed for mineralization compared among the three test systems. Based on mineralization rate and mineralization half-life, the fifteen compounds could be grouped into four biodegradation categories: substances with high mineralization and a half-life <28 days in (1) all three test systems, (2) only in the MITI test and in the WSST, (3) only in the SST, and (4) none of the test systems. The observed differences between the MITI results and the WSST and SST biodegradation rates of the compounds do not reflect their (reversible) sorption into organic matter in terms of experimental K(oc) values and log D values for the relevant pH range. Regarding mineralization kinetics we recommend to determine the lag-phase, mineralization half-life and mineralization rate using a 5-parameter logistic regression for degradation curves with and without lag-phase. Experimental data obtained with the WSST and the SST could be verified by showing good agreement with biodegradation data from databases and literature for the majority of compounds tested. Thus, these new screening-tools for water-sediment and soil are considered suitable to determine sound and reliable quantitative mineralization data including mineralization kinetics in addition to the water-only ready biodegradability tests according to OECD 301. Copyright © 2015 Elsevier B.V. All rights reserved.

  4. Modeling of soil erosion and sediment transport in the East River Basin in southern China.

    PubMed

    Wu, Yiping; Chen, Ji

    2012-12-15

    Soil erosion is a major global environmental problem that has caused many issues involving land degradation, sedimentation of waterways, ecological degradation, and nonpoint source pollution. Therefore, it is significant to understand the processes of soil erosion and sediment transport along rivers, and this can help identify the erosion prone areas and find potential measures to alleviate the environmental effects. In this study, we investigated soil erosion and identified the most seriously eroded areas in the East River Basin in southern China using a physically-based model, Soil and Water Assessment Tool (SWAT). We also introduced a classical sediment transport method (Zhang) into SWAT and compared it with the built-in Bagnold method in simulating sediment transport process along the river. The derived spatial soil erosion map and land use based erosion levels can explicitly illustrate the identification and prioritization of the critical soil erosion areas in this basin. Our results also indicate that erosion is quite sensitive to soil properties and slope. Comparison of Bagnold and Zhang methods shows that the latter can give an overall better performance especially in tracking the peak and low sediment concentrations along the river. We also found that the East River is mainly characterized by sediment deposition in most of the segments and at most times of a year. Overall, the results presented in this paper can provide decision support for watershed managers about where the best management practices (conservation measures) can be implemented effectively and at low cost. The methods we used in this study can also be of interest in sediment modeling for other basins worldwide. Published by Elsevier B.V.

  5. Enrichment and geochemical mobility of heavy metals in bottom sediment of the Hoedong reservoir, Korea and their source apportionment.

    PubMed

    Lee, Pyeong-Koo; Kang, Min-Ju; Yu, Soonyoung; Ko, Kyung-Seok; Ha, Kyoochul; Shin, Seong-Cheon; Park, Jung Han

    2017-10-01

    Physicochemical characteristics of bottom sediment in the Hoedong reservoir were studied to evaluate the effectiveness of the reservoir as traps for trace metals. Roadside soil, stream sediment and background soil were also studied for comparison. Sequential extractions were carried out, and lead isotopic compositions of each extraction were determined to apportion Pb sources. Besides, particle size distribution of roadside soil, and metal concentrations and Pb isotopes of each size group were determined to characterize metal contamination. In result, Zn and Cu were enriched in sediment through roadside soil. The data on metal partitioning implied that Zn posed potential hazards for water quality. Meanwhile, the noticeable reduction of the 206 Pb/ 207 Pb isotopic ratio in the acid-soluble fraction in the size group 200 μm - 2 mm of national roadside soil indicated that this size group was highly contaminated by automotive emission with precipitation of acid-soluble secondary minerals during evaporation. Based on the Pb isotopic ratios, the dry deposition of Asian dust (AD) and non-Asian dust (NAD) affected roadside soil, while the effects of AD and NAD on bottom sediment appeared to be low given the low metal concentrations in sediment. Metal concentrations and Pb isotopic compositions indicated that sediments were a mixture of background and roadside soil. Source apportionment calculations showed that the average proportion of traffic Pb in bottom and stream sediments was respectively 34 and 31% in non-residual fractions, and 26 and 28% in residual fraction. The residual fraction of sediments appeared to be as contaminated as the non-residual fractions. Copyright © 2017 Elsevier Ltd. All rights reserved.

  6. Part V--Sorption of pharmaceuticals and personal care products.

    PubMed

    Pan, Bo; Ning, Ping; Xing, Baoshan

    2009-01-01

    Pharmaceuticals and personal care products (PPCPs) including antibiotics, endocrine-disrupting chemicals, and veterinary pharmaceuticals are emerging pollutants, and their environmental risk was not emphasized until a decade ago. These compounds have been reported to cause adverse impacts on wildlife and human. However, compared to the studies on hydrophobic organic contaminants (HOCs) whose sorption characteristics is reviewed in Part IV of this review series, information on PPCPs is very limited. Thus, a summary of recent research progress on PPCP sorption in soils or sediments is necessary to clarify research requirements and directions. We reviewed the research progress on PPCP sorption in soils or sediments highlighting PPCP sorption different from that of HOCs. Special function of humic substances (HSs) on PPCP behavior is summarized according to several features of PPCP-soil or sediment interaction. In addition, we discussed the behavior of xenobiotic chemicals in a three-phase system (dissolved organic matter (DOM)-mineral-water). The complexity of three-phase systems was also discussed. Nonideal sorption of PPCPs in soils or sediments is generally reported, and PPCP sorption behavior is relatively a more complicated process compared to HOC sorption, such as the contribution of inorganic fractions, fast degradation and metabolite sorption, and species-specific sorption mechanism. Thus, mechanistic studies are urgently needed for a better understanding of their environmental risk and for pollution control. Recent research progress on nonideal sorption has not been incorporated into fate modeling of xenobiotic chemicals. A major reason is the complexity of the three-phase system. First of all, lack of knowledge in describing DOM fractionation after adsorption by mineral particles is one of the major restrictions for an accurate prediction of xenobiotic chemical behavior in the presence of DOM. Secondly, no explicit mathematical relationship between HS chemical-physical properties, and their sorption characteristics has been proposed. Last but not least, nonlinear interactions could exponentially increase the complexity and uncertainties of environmental fate models for xenobiotics. Discussion on proper simplification of fate modeling in the framework of nonlinear interactions is still unavailable. Although the methodologies and concepts for studying HOC environmental fate could be adopted for PPCP study, their differences should be highly understood. Prediction of PPCP environmental behavior needs to combine contributions from various fractions of soils or sediments and the sorption of their metabolites and different species. More detailed studies on PPCP sorption in separated soil or sediment fractions are needed in order to propose a model predicting PPCP sorption in soils or sediments based on soil or sediment properties. The information on sorption of PPCP metabolites and species and the competition between them is still not enough to be incorporated into any predictive models.

  7. Simulation of soil loss processes based on rainfall runoff and the time factor of governance in the Jialing River Watershed, China.

    PubMed

    Wu, Lei; Long, Tian-Yu; Liu, Xia; Mmereki, Daniel

    2012-06-01

    Jialing River is the largest tributary in the catchment area of Three Gorges Reservoir, and it is also one of the important areas of sediment yield in the upper reaches of the Yangtze River. In recent years, significant changes of water and sediment characteristics have taken place. The "Long Control" Project implemented since 1989 had greatly changed the surface appearance of the Jialing River Watershed (JRW), and it had made the environments of the watershed sediment yield and sediment transport change significantly. In this research, the Revised Universal Soil Loss Equation was selected and used to predict the annual average amount of soil erosion for the special water and sediment environments in the JRW after the implementation of the "Long Control" Project, and then the rainfall-runoff modulus and the time factor of governance were both considered as dynamic factors, the dynamic sediment transport model was built for soil erosion monitoring and forecasting based on the average sediment yield model. According to the dynamic model, the spatial and temporal distribution of soil erosion amount and sediment transport amount of the JRW from 1990 to 2007 was simulated using geographic information system (GIS) technology and space-grid algorithm. Simulation results showed that the average relative error of sediment transport was less than 10% except for the extreme hydrological year. The relationship between water and sediment from 1990 to 2007 showed that sediment interception effects of the soil and water conservation projects were obvious: the annual average sediment discharge reduced from 145.3 to 35 million tons, the decrement of sediment amount was about 111 million tons, and decreasing amplitude was 76%; the sediment concentration was also decreased from 2.01 to 0.578 kg/m(3). These data are of great significance for the prediction and estimation of the future changing trends of sediment storage in the Three Gorges Reservoir and the particulate non-point source pollution load carried by sediment transport from watershed surface.

  8. Interrill sediment enrichment of P and C from organically and conventionally farmed silty loams

    NASA Astrophysics Data System (ADS)

    Kuhn, N. J.

    2012-04-01

    Globally, between 0.57 and 1.33 Pg of soil organic carbon (SOC) may be affected by interrill processes. Also, a significant amount of phosphorus (P) is contained in the surface soil layer transformed by raindrop impact, runoff and crust formation. In the EU, the P content of a crusted (2 mm) surface layer corresponds to 4 to 40 kg ha-1 of P on arable land (1.094 mil km2). Therefore, the role of interrill processes for nutrient cycling and the global carbon cycle requires close attention. Interrill erosion is a complex phenomen on involving the detachment, transport and deposition of soil particles by raindrop impacted flow. Resistance to interrill erosion varies between soils depending on their physical, chemical and mineralogical properties. In addition, significant changes in soil resistance to interrill erosion occur during storms as a result of changes in surface roughness, cohesion and particle size. As a consequence, erosion on interrill areas is selective, moving the most easily detached small and/or light soil particles. This leads to the enrichment of clay, phosphorous (P)and carbon (C). Such enrichment in interrill sediment is well documented, however, the role of interrill erosion processes on the enrichment remains unclear. Enrichment of P and C in interrill sediment is attributed to the preferential erosion of the smaller, lighter soil particles. In this study, the P and organic C content of sediment generated from two Devon silts under conventional (CS) and organic (OS) soil management were examined. Artificial rainfall was applied to the soils using two rainfall scenarios of differing intensity and kinetic energy to determine the effects on the P and C enrichment in interrill sediment. Interrill soil erodibility was lower on the OS, irrespective of rainfall intensity. Sediment from both soils showed a significant enrichment in P and C compared to the bulk soil. However, sediment from the OS displayed a much greater degree of P enrichment. This shows that the net P export from organically farmed soils is not reduced by a similar degree than soil erosion compared to conventional soil management. The enrichment of P and C in the interrill sediment was not directly related to SOC, P content of the soil and soil interrill erodibility. A comparison of soil and sediment properties indicates that crusting, P and C content as well as density and size of eroded aggregate fragments control P and C enrichment. Due to complex and dynamic interactions between P, SOC and interrill erosional processes, the nutrient and C status of sediments cannot be predicted based on soil P content, SOC or interrill erodibility alone. Clearly, further research on crust formation and the composition of fragments generated by aggregate breakdown and their transport in raindrop impacted flow under different rainfall conditions is required. Attaining this critical missing knowledge would enable a comprehensive assessment of the benefits of organic farming on nutrient budgets, off-site effects of interrill erosion and its role in the global C cycle.

  9. Process based modelling of soil organic carbon redistribution on landscape scale

    NASA Astrophysics Data System (ADS)

    Schindewolf, Marcus; Seher, Wiebke; Amorim, Amorim S. S.; Maeso, Daniel L.; Jürgen, Schmidt

    2014-05-01

    Recent studies have pointed out the great importance of erosion processes in global carbon cycling. Continuous erosion leads to a massive loss of top soils including the loss of organic carbon accumulated over long time in the soil humus fraction. Lal (2003) estimates that 20% of the organic carbon eroded with top soils is emitted into atmosphere, due to aggregate breakdown and carbon mineralization during transport by surface runoff. Furthermore soil erosion causes a progressive decrease of natural soil fertility, since cation exchange capacity is associated with organic colloids. As a consequence the ability of soils to accumulate organic carbon is reduced proportionately to the drop in soil productivity. The colluvial organic carbon might be protected from further degradation depending on the depth of the colluvial cover and local decomposing conditions. Some colluvial sites can act as long-term sinks for organic carbon. The erosional transport of organic carbon may have an effect on the global carbon budget, however, it is uncertain, whether erosion is a sink or a source for carbon in the atmosphere. Another part of eroded soils and organic carbon will enter surface water bodies and might be transported over long distances. These sediments might be deposited in the riparian zones of river networks. Erosional losses of organic carbon will not pass over into atmosphere for the most part. But soil erosion limits substantially the potential of soils to sequester atmospheric CO2 by generating humus. The present study refers to lateral carbon flux modelling on landscape scale using the process based EROSION 3D soil loss simulation model, using existing parameter values. The selective nature of soil erosion results in a preferentially transport of fine particles while less carbonic larger particles remain on site. Consequently organic carbon is enriched in the eroded sediment compared to the origin soil. For this reason it is essential that EROSION 3D provides the grain size distribution (clay, silt and sand) of the transported sediment. A test slope is modeled covering certain land use and soil management scenarios referring to different rainfall events. Results allow first insights on carbon loss and depletion on sediment delivery areas as well as carbon gains and enrichments on deposition areas on landscape scale. Lal, R. (2003). Soil erosion and the global carbon budget. Environment International vol. 29: 437-450.

  10. Chemical quality of depositional sediments and associated soils in New Orleans and the Louisiana peninsula following Hurricane Katrina

    USGS Publications Warehouse

    Adams, C.; Witt, E.C.; Wang, Jingyuan; Shaver, D.K.; Summers, D.; Filali-Meknassi, Y.; Shi, H.; Luna, R.; Anderson, N.

    2007-01-01

    Hurricane Katrina made landfall on the Louisiana peninsula south of New Orleans on Aug 29, 2005. The resulting storm surge caused numerous levy breaches in the parishes of New Orleans as well as on the Louisiana peninsula. This study was conducted to determine the concentrations of inorganic and organic constituents in sediments and associated soils in New Orleans parishes and the Louisiana peninsula after the floodwaters had been removed and/or receded following Hurricane Katrina. A total of 46 sediment and soil samples were analyzed that were collected throughout New Orleans and the Louisiana peninsula. Approximately 20% of the sediment samples were analyzed, including shallow sediment samples from locations that included the top and beneath automobiles, in residential and commercial areas, and near refineries. Gasoline constituents, pesticides, and leachable heavy metals were analyzed using headspace gas chromatography/mass spectrometry (GC/MS), organic extraction GC/MS, and inductively coupled plasma/mass spectrometry, respectively. A significant number of samples had leachable As and Pb concentrations in excess of drinking water standards. The remaining metals analyzed (i.e., Cd, Cr, Cu, Hg, and V) generally had much lower leachable levels. Of the gasoline constituents, only benzene was observed above the limit of detection (of 5 ??g/kg), with no samples observed as being above the method detection limits of 10 ??g/kg. For the 18 pesticides analyzed, most were in the nondetectable range and all were in trace amounts that were orders of magnitude below regulatory guidelines. ?? 2007 American Chemical Society.

  11. Tracing the source of sedimentary organic carbon in the Loess Plateau of China: An integrated elemental ratio, stable carbon signatures, and radioactive isotopes approach.

    PubMed

    Liu, Chun; Dong, Yuting; Li, Zhongwu; Chang, Xiaofeng; Nie, Xiaodong; Liu, Lin; Xiao, Haibing; Bashir, Hassan

    2017-02-01

    Soil erosion, which will induce the redistribution of soil and associated soil organic carbon (SOC) on the Earth's surface, is of critically importance for biogeochemical cycling of essential elements and terrestrial carbon sequestration. Despite the importance of soil erosion, surprisingly few studies have evaluated the sources of eroded carbon (C). This study used natural abundance levels of the stable isotope signature ( 13 C) and radioactive isotopes ( 137 Cs and 210 Pb ex ), along with elements ratio (C/N) based on a two end member mixing model to qualitatively and quantitatively identify the sources of sedimentary OC retained by check dam in the Qiaozigou small watershed in the Loess Plateau, China. Sediment profiles (0-200 cm) captured at natural depositional area of the basin was compared to possible source materials, which included: superficial Loess mineral soils (0-20 cm) from three land use types [i.e., grassland (Medicago sativa), forestland (Robinia pseudoacacia.), shrubland (Prunus sibirica), and gully land (Loess parent material.)]. The results demonstrated that SOC in sediments showed significantly negative correlation with pH (P < 0.01), and positive correlation with soil water content (SWC) (P < 0.05). The sedimentary OC was not derived from grasslands or gullies. Forestland and shrubland were two main sources of eroded organic carbon within the surface sediment (0-60 cm deep), except for that in the 20-40 cm soil layer. Radionuclides analyses also implied that the surface sediments retained by check-dams mainly originated from soils of forestland and shrubland. Results of the two end-member mixing model demonstrated that more than 50% SOC (mean probability estimate (MPE) 50.13% via 13 C and 60.53% via C/N) in surface sediment (0-20 cm deep) derived from forestland, whereas subsurface sedimentary SOC (20-200 cm) mainly resulted from shrubland (MPE > 50%). Although uncertainties on the sources of SOC in deep soils exist, the soil organic δ 13 C and C/N is still an effective indicator for sources of sedimentary organic carbon in the deposition zone in the short term (<10 years). Copyright © 2016 Elsevier Ltd. All rights reserved.

  12. State of the Science Review: Potential for Beneficial Use of Waste By-Products for In-situ Remediation of Metal-Contaminated Soil and Sediment

    EPA Science Inventory

    Metal and metalloid contamination of soil and sediment is a widespread problem both in urban and rural areas throughout the United States (U.S. EPA, 2014). Beneficial use of waste by-products as amendments to remediate metal-contaminated soils and sediments can provide major eco...

  13. Toxic assessment of the leachates of paddy soils and river sediments from e-waste dismantling sites to microalga, Pseudokirchneriella subcapitata.

    PubMed

    Nie, Xiangping; Fan, Canpeng; Wang, Zhaohui; Su, Tian; Liu, Xinyu; An, Taicheng

    2015-01-01

    The potential adverse effects of e-waste recycling activity on environment are getting increasing concern. In this work, a model alga, Pseudokirchneriella subcapitata, was employed to assess the toxic effects of the leachates of paddy soils and river sediments collected from e-waste dismantling sites. Chemical analysis of the paddy soils and river sediments and their leachates were carried out and the growth rate, chlorophyll a fluorescence and anti-oxidative systems of the alga were measured. Results showed that two leachates decreased the amount of PSII active reaction centers and affected photosynthesis performance, interfered with chlorophyll synthesis and inhibited algal growth. Some chemical pollutants in the sediments and soils such as polybrominated diphenyl ethers (PBDEs) and metals derived from e-waste recycling activity may impose oxidative stress on algae and affect the activity of anti-oxidative enzymes such as GST, SOD, CAT and APX. The leachates of both river sediments and paddy soils are potentially toxic to the primary producers, P. subcapitata and the leachate from sediments was more deleterious than that from soils. Copyright © 2014 Elsevier Inc. All rights reserved.

  14. Determination of Soil Erosion Risk in the Mustafakemalpasa River Basin, Turkey, Using the Revised Universal Soil Loss Equation, Geographic Information System, and Remote Sensing

    NASA Astrophysics Data System (ADS)

    Ozsoy, Gokhan; Aksoy, Ertugrul; Dirim, M. Sabri; Tumsavas, Zeynal

    2012-10-01

    Sediment transport from steep slopes and agricultural lands into the Uluabat Lake (a RAMSAR site) by the Mustafakemalpasa (MKP) River is a serious problem within the river basin. Predictive erosion models are useful tools for evaluating soil erosion and establishing soil erosion management plans. The Revised Universal Soil Loss Equation (RUSLE) function is a commonly used erosion model for this purpose in Turkey and the rest of the world. This research integrates the RUSLE within a geographic information system environment to investigate the spatial distribution of annual soil loss potential in the MKP River Basin. The rainfall erosivity factor was developed from local annual precipitation data using a modified Fournier index: The topographic factor was developed from a digital elevation model; the K factor was determined from a combination of the soil map and the geological map; and the land cover factor was generated from Landsat-7 Enhanced Thematic Mapper (ETM) images. According to the model, the total soil loss potential of the MKP River Basin from erosion by water was 11,296,063 Mg year-1 with an average soil loss of 11.2 Mg year-1. The RUSLE produces only local erosion values and cannot be used to estimate the sediment yield for a watershed. To estimate the sediment yield, sediment-delivery ratio equations were used and compared with the sediment-monitoring reports of the Dolluk stream gauging station on the MKP River, which collected data for >41 years (1964-2005). This station observes the overall efficiency of the sediment yield coming from the Orhaneli and Emet Rivers. The measured sediment in the Emet and Orhaneli sub-basins is 1,082,010 Mg year-1 and was estimated to be 1,640,947 Mg year-1 for the same two sub-basins. The measured sediment yield of the gauge station is 127.6 Mg km-2 year-1 but was estimated to be 170.2 Mg km-2 year-1. The close match between the sediment amounts estimated using the RUSLE-geographic information system (GIS) combination and the measured values from the Dolluk sediment gauge station shows that the potential soil erosion risk of the MKP River Basin can be estimated correctly and reliably using the RUSLE function generated in a GIS environment.

  15. Organochlorine pesticides and polychlorinated biphenyls in surface soils of Novi Sad and bank sediment of the Danube River.

    PubMed

    Skrbic, Biljana; Cvejanov, Jelena; Durisic-Mladenovic, Natasa

    2007-01-01

    The contents of 16 organochlorine pesticides (OCPs) and six so-called indicator polychlorinated biphenyls (PCBs) were determined in the surface zone (0-5 cm) of soil and sediment samples, taken from different locations in the city of Novi Sad, capitol of Vojvodina Province (North of the Serbia) covering residential and commercial area, recreational and arable zone. The total organochlorine pesticides concentration in soil varied from 2.63 to 31.78 ng g(-1) dry weight, while the level in sediment was 10.35 ng g(-1) dry weight. Maximum content of identified individual organochlorine pesticide in soil samples was 10.40 ng g(-1) dry weight for p, p-DDE in the market garden and 6.31 ng g(-1) dry weight for p, p'-DDT in sediment of the Danube River, although their application is restricted in Serbia. Some of investigated PCBs were identified only in the soil samples from a park-school backyard in the city downtown (0.32 ng g(-1) dry weight) and market garden (0.22 ng g(-1) dry weight), and also in sediment sample from left bank of the Danube River (0.41 ng g(-1) dry weight). Data of the OCPs and PCBs present in this study were compared with the ones found for soils and river sediments throughout the world, and with limit values set by soil and sediment quality guidelines. Also, correlation between the levels of certain pesticides and soil characteristics (organic matter, pH and clay content) was investigated.

  16. Prediction of sedimentation using integration of RS, RUSLE model and GIS in Cameron Highlands, Pahang, Malaysia

    NASA Astrophysics Data System (ADS)

    Ghani, A. H. A.; Lihan, T.; Rahim, S. A.; Musthapha, M. A.; Idris, W. M. R.; Rahman, Z. A.

    2013-11-01

    Soil erosion and sediment yield are strongly affected by land use change. Spatially distributed erosion models are of great interest to predict soil erosion loss and sediment yield. Hence, the objective of this study was to determine sediment yield using Revised Universal Soil Loss Equation (RUSLE) model in Geographical Information System (GIS) environment at Cameron Highlands, Pahang, Malaysia. Sediment yield at the study area was determined using RUSLE model in GIS environment The RUSLE factors were computed by utilizing information on rainfall erosivity (R) using interpolation of rainfall data, soil erodibility (K) using soil map and field measurement, vegetation cover (C) using satellite images, length and steepness (LS) using contour map and conservation practices using satellite images based on land use/land cover. Field observations were also done to verify the predicted sediment yield. The results indicated that the rate of sediment yield in the study area ranged from very low to extremely high. The higher SY value can be found at middle and lower catchments of Cameron Highland. Meanwhile, the lower SY value can be found at the north part of the study area. Sediment yield value turned out to be higher close to the river due to the topographic characteristic, vegetation type and density, climate and land use within the drainage basin.

  17. Effects of sedimentation on soil physical and chemical properties and vegetation characteristics in sand dunes at the Southern Dongting Lake region, China

    PubMed Central

    Pan, Ying; Zhang, Hao; Li, Xu; Xie, Yonghong

    2016-01-01

    Sedimentation is recognized as a major factor determining the ecosystem processes of lake beaches; however, the underlying mechanisms, especially in freshwater sand dunes, have been insufficiently studied. To this end, nine belt transects from nine freshwater sand dunes, classified into low (<23.7 m), medium (25.4–26.0 m), and high-elevation groups (>28.1 m) based on their elevations in 1972, were sampled to investigate differences in sedimentation rate and soil and vegetation characteristics in Southern Dongting Lake, China. Sedimentation rate, soil sand content, and soil pH increased, whereas soil clay, fine silt, moisture (MC), organic matter (OM), total N, and total K content, in addition to the growth and biodiversity of sand dune plants generally decreased with decreasing belt transect elevation. Regression analyses revealed that the negative effects of sedimentation on the ecosystem functions of sand dunes could be attributed to higher fine sand content in deposited sediments and stronger inhibition of plant growth. These results are consistent with previous studies performed in coastal sand dunes, which highlights the importance of sedimentation in determining ecological processes. PMID:27808154

  18. Effects of sedimentation on soil physical and chemical properties and vegetation characteristics in sand dunes at the Southern Dongting Lake region, China

    NASA Astrophysics Data System (ADS)

    Pan, Ying; Zhang, Hao; Li, Xu; Xie, Yonghong

    2016-11-01

    Sedimentation is recognized as a major factor determining the ecosystem processes of lake beaches; however, the underlying mechanisms, especially in freshwater sand dunes, have been insufficiently studied. To this end, nine belt transects from nine freshwater sand dunes, classified into low (<23.7 m), medium (25.4-26.0 m), and high-elevation groups (>28.1 m) based on their elevations in 1972, were sampled to investigate differences in sedimentation rate and soil and vegetation characteristics in Southern Dongting Lake, China. Sedimentation rate, soil sand content, and soil pH increased, whereas soil clay, fine silt, moisture (MC), organic matter (OM), total N, and total K content, in addition to the growth and biodiversity of sand dune plants generally decreased with decreasing belt transect elevation. Regression analyses revealed that the negative effects of sedimentation on the ecosystem functions of sand dunes could be attributed to higher fine sand content in deposited sediments and stronger inhibition of plant growth. These results are consistent with previous studies performed in coastal sand dunes, which highlights the importance of sedimentation in determining ecological processes.

  19. Quadrant III RFI draft report: Volume 1

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Not Available

    1992-12-01

    The purpose of the RCRA Facility Investigation (RFI) at The Portsmouth Gaseous Diffusion Plant (PORTS) is to acquire, analyze and interpret data that will: characterize the environmental setting, including ground water, surface water and sediment, soil and air; define and characterize sources of contamination; characterize the vertical and horizontal extent and degree of contamination of the environment; assess the risk to human health and the environment resulting from possible exposure to contaminants; and support the Corrective Measures Study (CMS), which will follow the RFI, if required. A total of 18 Solid Waste Management Units (SWMU's) were investigated. All surficial soilmore » samples (0--2 ft), sediment samples and surface-water samples proposed in the approved Quadrant III RFI Work Plan were collected as specified in the approved work plan and RFI Sampling Plan. All soil, sediment and surface-water samples were analyzed for parameters specified from the Target Compound List and Target Analyte List (TCL/TAL) as listed in the US EPA Statement of Work for Inorganic (7/88a) and Organic (2/88b) analyses for Soil and Sediment, and analyses for fluoride, Freon-113 and radiological parameters (total uranium, gross alpha, gross beta and technetium).« less

  20. Quadrant III RFI draft report: Volume 1

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Not Available

    1992-12-01

    The purpose of the RCRA Facility Investigation (RFI) at The Portsmouth Gaseous Diffusion Plant (PORTS) is to acquire, analyze and interpret data that will: characterize the environmental setting, including ground water, surface water and sediment, soil and air; define and characterize sources of contamination; characterize the vertical and horizontal extent and degree of contamination of the environment; assess the risk to human health and the environment resulting from possible exposure to contaminants; and support the Corrective Measures Study (CMS), which will follow the RFI, if required. A total of 18 Solid Waste Management Units (SWMU`s) were investigated. All surficial soilmore » samples (0--2 ft), sediment samples and surface-water samples proposed in the approved Quadrant III RFI Work Plan were collected as specified in the approved work plan and RFI Sampling Plan. All soil, sediment and surface-water samples were analyzed for parameters specified from the Target Compound List and Target Analyte List (TCL/TAL) as listed in the US EPA Statement of Work for Inorganic (7/88a) and Organic (2/88b) analyses for Soil and Sediment, and analyses for fluoride, Freon-113 and radiological parameters (total uranium, gross alpha, gross beta and technetium).« less

  1. Agrogeology today

    NASA Astrophysics Data System (ADS)

    Kerek, Barbara; Kuti, Laszlo; Vatai, Jozsef

    2010-05-01

    Agrogeology is one of the research sectors of applied geology. It addresses all geological characteristics of the superficial deposits and the related geological processes taking place therein which are of crucial importance regarding agricultural production and sylviculture, influence the plantation of crops and woods and provide information on a number of factors including the sequences constituting the soil, soil forming sediments and parent rocks, the position and quality of groundwater, the salt regime governed by groundwater movement as well as the natural and manmade changes in the regions below the soil horizon affecting the surface as well. Accordingly, it investigates not only the sediment appearing on the surface and affected by soil development (=soil) but all near-surface sequences taken together as well as the relationship between soil-parent material-groundwater in lowlands and soil-soil forming sediment and parent rock in mountain and hilly areas. Furthermore, it examines also the changes of these systems as a result of human intervention and makes predictions concerning the advantageous or disadvantageous effects of these changes. Consequently, the most important tasks of agrogeology can be defined as follows: 1. Detailed agrogeological description and specification of farmlands and land units aimed at optimal land use as well as supporting the rational selection of crops and the production system. 2. Investigation of the geological factors of different soil degradation processes (erosion, deflation, salinisation, acidification, desiccation, etc.), prediction of the occurrence of these processes together with the geological chances of their prevention and minimisation. 3. Examination of the agrogeological and water regime properties of the soil-(soil forming sediment)-parent rock-groundwater system characteristic for the given land unit. 4. Research, survey, simulation and prediction of the impacts of soil use as well as agri- and sylviculture on the soil-(soil forming sediment)-parent rock-groundwater or "soil-parent rock-bedrock" system aimed at the prevention and elimination of harmful effects. 5. Investigation of the geological aspects of water regulation and irrigation as well as their impact on the environment. 6. Definition, examination and characterisation of the real soil forming geological sequence. In Hungary the actual agrogeological investigations were launched by the agricultural reambulation of geological mapping data. During the early 1980s the so-called BFK-method was elaborated to the agrogeological investigation of these areas still used today. The main aspect of this method is that apart from the common geological sampling of the boreholes samples are also taken from the top- and subsoil (horizon 1), the soil forming sediment or parent material (horizon 2), the fluctuation zone of the groundwater (horizon 3) as well as from the zone permanently below the groundwater level (horizon 4) and the groundwater itself (Figure 2). These samples undergo detailed laboratory analyses. The comparative evaluation of the derived results allows making different agrogeological conclusions. During the period elapsed from the early 1980s the survey of the pilot areas allowed us investigating among others the agrogeological relationships of salinisation, acidification, excess water risk, erosion, and trace element regime as well as vine chlorosis.

  2. An evaluation of technologies for the heavy metal remediation of dredged sediments.

    PubMed

    Mulligan, C N; Yong, R N; Gibbs, B F

    2001-07-30

    Sediments dewatering is frequently necessary after dredging to remediate and treat contaminants. Methods include draining of the water in lagoons with or without coagulants and flocculants, or using presses or centrifuges. Treatment methods are similar to those used for soil and include pretreatment, physical separation, thermal processes, biological decontamination, stabilization/solidification and washing. However, compared to soil treatment, few remediation techniques have been commercially used for sediments. In this paper, a review of the methods that have been used and an evaluation of developed and developing technologies is made. Sequential extraction technique can be a useful tool for determining metal speciation before and after washing. Solidification/stabilization techniques are successful but significant monitoring is required, since the solidification process can be reversible. In addition, the presence of organics can reduce treatment efficiency. Vitrification is applicable for sediments but expensive. Only if a useful glass product can be sold will this process be economically viable. Thermal processes are only applicable for removal of volatile metals, such as mercury and costs are high. Biological processes are under development and have the potential to be low cost. Since few low cost metal treatment processes for sediments are available, there exists significant demand for further development. Pretreatment may be one of the methods that can reduce costs by reducing the volumes of sediments that need to be treated.

  3. Rapid residue analysis of oxathiapiprolin and its metabolites in typical Chinese soil, water, and sediments by a modified quick, easy, cheap, effective, rugged, and safe method with ultra high performance liquid chromatography and tandem mass spectrometry.

    PubMed

    Ju, Chao; Dong, Fengshou; Liu, Xingang; Wu, Xiaohu; Zhao, Huanhuan; Zheng, Yongquan; Xu, Jun

    2015-03-01

    A sensitive and effective method for the simultaneous determination of residues from a new fungicide, oxathiapiprolin, and its metabolites (IN-E8S72 and IN-WR791) in soil, water, and sediment, was developed using ultra high performance liquid chromatography with tandem mass spectrometry. Three compounds were extracted from water, soil, and sediment by using acetonitrile and different proportions of formic acid aqueous solution (1% v/v for water; 2% v/v for soil; and sediment), and were cleaned with octadecylsilane. The target compounds were determined within 5 min using an electrospray ionization source in the positive mode for oxathiapiprolin and in the negative mode for the two metabolites. The limits of quantification for all the three compounds were 0.1 μg/kg in water and 1 μg/kg in soil and sediment. Recovery studies were performed using three spiked levels (0.1, 1, and 10 μg/kg for water; 1, 10, and 50 μg/kg for soil and sediment). The overall average recoveries ranged from 64.8 to 112.7% with all intra- and interday relative standard deviation values below 19.4 and 19.1%, respectively. The method validation confirmed that the proposed method was convenient and reliable for determining residual oxathiapiprolin and its metabolites in soil, water, and sediments. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  4. [Assessment of the impacts of soil erosion on water environment based on the integration of soil erosion process and landscape pattern].

    PubMed

    Liu, Yu; Wu, Bing-Fang; Zeng, Yuan; Zhang, Lei

    2013-09-01

    The integration of the effects of landscape pattern to the assessment of the impacts of soil erosion on eco-environmental is of practical significance in methodological prospect, being able to provide an approach for identifying water body's sediment source area, assessing the potential risks of sediment export of on-site soil erosion to the target water body, and evaluating the capacity of regional landscape pattern in preventing soil loss. In this paper, the RUSLE model was applied to simulate the on-site soil erosion rate. With the consideration of the soil retention potential of vegetation cover and topography, a quantitative assessment was conducted on the impacts of soil erosion in the water source region of the middle route for South-to-North Water Transfer Project on rivers and reservoirs by delineating landscape pattern at point (or cell) scale and sub-watershed level. At point (or grid cell) scale, the index of soil erosion impact intensity (I) was developed as an indicator of the potential risk of sediment export to the water bodies. At sub-watershed level, the landscape leakiness index (LI) was employed to indicate the sediment retention capacity of a given landscape pattern. The results revealed that integrating the information of landscape pattern and the indices of soil erosion process could spatially effectively reflect the impact intensity of in situ soil erosion on water bodies. The LI was significantly exponentially correlated to the mean sediment retention capacity of landscape and the mean vegetation coverage of watershed, and the sediment yield at sub-watershed scale was significantly correlated to the LI in an exponential regression. It could be concluded that the approach of delineating landscape pattern based on soil erosion process and the integration of the information of landscape pattern with its soil retention potential could provide a new approach for the risk evaluation of soil erosion.

  5. Determining Relative Contributions of Eroded Landscape Sediment and Bank Sediment to the Suspended Load of Streams and Wetlands Using 7Be and 210Pbxs

    NASA Astrophysics Data System (ADS)

    Wilson, C.; Matisoff, G.; Whiting, P.; Kuhnle, R.

    2005-12-01

    The naturally occurring radionuclides, 7Be and 210Pbxs, have been used individually as tracers of sediment particles throughout watersheds. However, use of the two radionuclides together enables eliciting information regarding the major contributors of fine sediment to the suspended load of a stream or wetland. We report on a study that uses these radionuclides to quantify the relative proportion of eroded surface soils, bank material and resuspended bed sediment in the fine suspended sediment load of the Goodwin Creek, MS, and Old Woman Creek, OH watersheds. The eroded surface soil has a unique radionuclide signature relative to the bed sediments in Old Woman Creek and the bank material along Goodwin Creek that allows for the quantification of the relative proportions of the different sediments in the sediment load. In Old Woman Creek, the different signatures are controlled by the differential decay of the two radionuclides. In Goodwin Creek, the different signatures are due to different erosion processes controlling the sediment delivery to streams, namely sheet erosion and bank collapse. The eroded surface soils will have higher activities of the 7Be and 210Pbxs than bed/bank sediments. The fine suspended sediment, which is a mixture of eroded surface soils and resuspended bed sediment or collapsed bank sediment, will have an intermediate radionuclide signature quantified in terms of the relative proportion from both sediments. A simple two-end member mixing model is used to determine the relative proportions of both sediments to the total fine sediment load.

  6. Soils on raised marine terraces in the Metaponto area, S Italy: not a simple chronosequence

    NASA Astrophysics Data System (ADS)

    Sauer, Daniela; Al-Sharif, Riyad; Wagner, Stephen; Scarciglia, Fabio; Deffontaines, Benoît; Benvenuti, Marco; Carnicelli, Stefano; Brückner, Helmut

    2015-04-01

    A sequence of Middle and Late Pleistocene raised marine terraces stretches along the Gulf of Taranto, S Italy, for more than 65 km from Rocca Imperiale, Calabria, in the SW to Taranto, Apulia, in the NE, in an approximately 25 km wide belt. The terraces formed as a result of the interplay between sea-level fluctuations and regional tectonic uplift over a time-span of ca. 780 ka. They were selected for establishing a soil chronosequence, in order to analyse rates of soil-forming processes in the central Mediterranean region. Indeed, several general trends of soil formation with terrace age were identified. For example, soil thickness and Fed/Fet ratios increase, while the weathering ratio (Ca+Mg+K+Na)/Al decreases with assumed terrace age. These changes could be best described by power functions (R2 = 0.88 for soil thickness, R2 = 0.87 for Fed/Fet, and R2 = 0.96 for (Ca+Mg+K+Na)/Al). However, closer examination revealed that the soils did not simply form in the marine gravel bodies but in various kinds of sediments. The development of the landscape along the Gulf of Taranto turned out to be much more complex than previously expected. Sediment-soil successions exposed in several gravel quarries reveal that each terrace, after its original formation, was exposed to changing conditions in terms of climate, vegetation, level of erosion base (related to sea-level oscillations and/or tectonics), and other environmental factors during the Pleistocene and Holocene periods. As a result, it was subject to (i) further geomorphological and sedimentological evolution, including incision, denudation, deposition of alluvial sediments, and accumulation of colluvial deposits, in parts due to natural processes and in parts due to human activity; (ii) various directions and rates of soil development, corresponding to changing environmental conditions during glacial and interglacial periods. In some cases, there is evidence for a period of soil formation in the marine deposits prior to the deposition of the alluvial sediments. For example, a several metres thick marine gravel body, overlain by a layer of alluvial sandy-loamy sediments, is exposed in a gravel quarry on terrace T2 (assumed to have accumulated during MIS 5c). The boundary between the two sediment packages is very sharp and wavy, indicating a period of incision into the gravel body prior to the deposition of the alluvial sediments. Based on these observations, the following chronological sequence of events is assumed for this site: 1) accumulation of the gravel body in a delta environment during MIS 5c; 2) period of soil formation during late MIS 5c, after the surface of the gravel body had fallen dry; 3) incision of creeks, cutting channels into the gravel body as sea level dropped during MIS 5b; 4) sea-level rise during MIS 5a, not reaching the same level as during MIS 5c due to progressing regional uplift in the meantime; wave action of the MIS 5a sea removed part of the MIS 5c gravel body and cut a cliff into it, thus shaping the seaward edge of terrace T2; 5) accumulation of alluvial deposits in the previously incised channels and on top of the erosional gravel-body surface during MIS 5a because of the raised erosion base level; 6) incorporation of sandy sediments from the near-by MIS 5a beach, possibly with some contribution from temporarily dry beds of the nearby torrential rivers, into the alluvial deposits. Similarly complex sediment successions can be observed in several exposures. In addition, in some locations up to several metres of loess-like sediments are exposed. They probably accumulated during glacial periods, being blown out from the wide, temporarily dry river beds and from the exposed shelf. These observations led to a more differentiated reconstruction of the evolution of the landscape and soils in the Metaponto area.

  7. Data and statistical summaries of background concentrations of metals in soils and streambed sediments in part of Big Soos Creek drainage basin, King County, Washington

    USGS Publications Warehouse

    Prych, E.A.; Kresch, D.L.; Ebbert, J.C.; Turney, G.L.

    1995-01-01

    Twenty-nine soil samples from 14 holes at 9 sites in part of the Big Soos Creek drainage basin in southwest King County, Washington, were collected and analyzed to obtain data on the magnitude and variability of background concentrations of metals in soils. Seven streambed-sediment samples and three streamwater samples from three sites also were collected and analyzed. These data are needed by regulating government agencies to determine if soils at sites of suspected contamination have elevated concentrations of metals, and to evaluate the effectiveness of remediation at sites with known contamination. Concentrations of 43 metals were determined by a total method, and concentrations of 17 metals were determined by a total-recoverable method and two different leaching methods. Metals analyzed for by all methods included most of those on the U.S. Environmental Protection agency list of priority pollutants, plus alluminum, iron, and manganese. Ranges of concentrations of metals determined by the total method are within ranges found by others for the conterminous United States. Concentrations of mercury, manganese, phosphorus, lead, selenium, antimony, and zinc as determined by the total method, and of some of these plus other metals as determined by the other methods were larger in shallow soil (less than 12 inches deep) than in deep soil (greater than 12 inches). Concentrations of metals in streambed sediments were more typical of shallow than deep soils.

  8. Final Environmental Assessment for a Solar Power System at Davis-Monthan Air Force Tucson, Arizona

    DTIC Science & Technology

    2009-09-01

    construction would occur in previously disturbed area, soil condition would not be substantially altered. Best Management Practices (BMP), to include...installation of silt fencing and sediment traps, water spray application, disturbed area revegatation, would be used to limit soil movement, stabilize...implementation of BMPs and adherence to the Arizona Pollutant Discharge Elimination System Permit would minimize the potential for exposed soils or other

  9. Soil Organic Matter Erosion by Interrill Processes from Organically and Conventionally farmed Devon Soil

    NASA Astrophysics Data System (ADS)

    Armstrong, E.; Ling, A.; Kuhn, N. J.

    2012-04-01

    Globally, between 0.57 and 1.33 Pg of soil organic carbon (SOC) may be affected by interrill processes. Also, a significant amount of phosphorus (P) is contained in the surface soil layer transformed by raindrop impact, runoff and crust formation. In the EU, the P content of a crusted (2 mm) surface layer corresponds to 4 to 40 kg ha-1 of P on arable land (1.094 mil km2). Therefore, the role of interrill processes for nutrient cycling and the global carbon cycle requires close attention. Interrill erosion is a complex phenomenon involving the detachment, transport and deposition of soil particles by raindrop impacted flow. Resistance to interrill erosion varies between soils depending on their physical, chemical and mineralogical properties. In addition, significant changes in soil resistance to interrill erosion occur during storms as a result of changes in surface roughness, cohesion and particle size. As a consequence, erosion on interrill areas is selective, moving the most easily detached small and/or light soil particles. This leads to the enrichment of clay, phosphorous (P) and carbon (C). Such enrichment in interrill sediment is well documented, however, the role of interrill erosion processes on the enrichment remains unclear. Enrichment of P and C in interrill sediment is attributed to the preferential erosion of the smaller, lighter soil particles. In this study, the P and organic C content of sediment generated from two Devon silts under conventional (CS) and organic (OS) soil management were examined. Artificial rainfall was applied to the soils using two rainfall scenarios of differing intensity and kinetic energy to determine the effects on the P and C enrichment in interrill sediment. Interrill soil erodibility was lower on the OS, irrespective of rainfall intensity. Sediment from both soils showed a significant enrichment in P and C compared to the bulk soil. However, sediment from the OS displayed a much greater degree of P enrichment. This shows that the net P export from organically farmed soils is not reduced by a similar degree than soil erosion compared to conventional soil management. The enrichment of P and C in the interrill sediment was not directly related to SOC, P content of the soil and soil interrill erodibility. A comparison of soil and sediment properties indicates that crusting, P and C content as well as density and size of eroded aggregate fragments control P and C enrichment. Due to complex and dynamic interactions between P, SOC and interrill erosional processes, the nutrient and C status of sediments cannot be predicted based on soil P content, SOC or interrill erodibility alone. Clearly, further research on crust formation and the composition of fragments generated by aggregate breakdown and their transport in raindrop impacted flow under different rainfall conditions is required. Attaining this critical missing knowledge would enable a comprehensive assessment of the benefits of organic farming on nutrient budgets, off-site effects of interrill erosion and its role in the global C cycle.

  10. Evaluation of available data on the geohydrology, soil chemistry, and ground-water chemistry of Gas Works Park and surrounding region, Seattle, Washington

    USGS Publications Warehouse

    Sabol, M.A.; Turney, G.L.; Ryals, G.N.

    1988-01-01

    Gas Works Park, in Seattle, Washington, is located at the site of an abandon gasification plant on Lake Union. Wastes deposited during 50 years of plant operations (1906-1956) have extended the shore line 100 ft and left the park soil contaminated with a number of hazardous material. Soil contaminants include polynuclear aromatic hydrocarbons (PAHs), polychlorinated biphenyls, pesticides, volatile organic compounds, cyanide, and metals. PAHs and metals have been detected in Lake Union sediments. Maximum total PAH concentrations exceeded 100 million micrograms/kilogram in some places in the soils of the park at 6-inch depths and in some lake sediments. Other contaminants present are much lower in concentrations. The park is on glacial drift overlain by gasification waste materials and clean fill. Waste materials include sand and gravels, mixed with lampblack, oil, bricks, and other industrial wastes. Groundwater flows through the soils and waste toward Lake Union. Vertical groundwater movement is uncertain, but is assumed to be upward near Lake Union. Concentrations of most soil contaminants are probably low in the groundwater and in Lake Union due to the low solubilities and high sorptive characteristics of these contaminants. However, no water quality data are available to confirm this premise. (USGS)

  11. Status and trends in suspended-sediment discharges, soil erosion, and conservation tillage in the Maumee River basin--Ohio, Michigan, and Indiana

    USGS Publications Warehouse

    Myers, Donna N.; Metzker, Kevin D.; Davis, Steven

    2000-01-01

    The relation of suspended-sediment discharges to conservation-tillage practices and soil loss were analyzed for the Maumee River Basin in Ohio, Michigan, and Indiana as part of the U.S. Geological Survey?s National Water-Quality Assessment Program. Cropland in the basin is the largest contributor to soil erosion and suspended-sediment discharge to the Maumee River and the river is the largest source of suspended sediments to Lake Erie. Retrospective and recently-collected data from 1970-98 were used to demonstrate that increases in conservation tillage and decreases in soil loss can be related to decreases in suspended-sediment discharge from streams. Average annual water and suspended-sediment budgets computed for the Maumee River Basin and its principal tributaries indicate that soil drainage and runoff potential, stream slope, and agricultural land use are the major human and natural factors related to suspended-sediment discharge. The Tiffin and St. Joseph Rivers drain areas of moderately to somewhat poorly drained soils with moderate runoff potential. Expressed as a percentage of the total for the Maumee River Basin, the St. Joseph and Tiffin Rivers represent 29.0 percent of the basin area, 30.7 percent of the average-annual streamflow, and 9.31 percent of the average annual suspended-sediment discharge. The Auglaize and St. Marys Rivers drain areas of poorly to very poorly drained soils with high runoff potential. Expressed as a percentage of the total for the Maumee River Basin, the Auglaize and St. Marys Rivers represent 48.7 percent of the total basin area, 53.5 percent of the average annual streamflow, and 46.5 percent of the average annual suspended-sediment discharge. Areas of poorly drained soils with high runoff potential appear to be the major source areas of suspended sediment discharge in the Maumee River Basin. Although conservation tillage differed in the degree of use throughout the basin, on aver-age, it was used on 55.4 percent of all crop fields in the Maumee River Basin from 1993-98. Conservation tillage was used at relatively higher rates in areas draining to the lower main stem from Defiance to Waterville, Ohio and at relatively lower rates in the St. Marys and Auglaize River Basins, and in areas draining to the main stem between New Haven, Ind. and Defiance, Ohio. The areas that were identified as the most important sediment-source areas in the basin were characterized by some of the lowest rates of conservation tillage. The increased use of conservation tillage was found to correspond to decreases in suspended-sediment discharge over time at two locations in the Maumee River Basin. A 49.8 percent decrease in suspended-sediment discharge was detected when data from 1970-74 were compared to data from 1996-98 for the Auglaize River near Ft. Jennings, Ohio. A decrease in suspended-sediment discharge of 11.2 percent was detected from 1970?98 for the Maumee River at Waterville, Ohio. No trends in streamflow at either site were detected over the period 1970-98. The lower rate of decline in suspended-sediment discharge for the Maumee River at Waterville, Ohio compared to the Auglaize River near Ft. Jennings, may be due to resuspension and export of stored sediments from drainage ditches, stream channels, and flood plains in the large drainage basin upstream from Waterville. Similar findings by other investigators about the capacity of drainage networks to store sediment are supported by this investigation. These findings go undetected when soil loss estimates are used alone to evaluate the effectiveness of conservation tillage. Water-quality data in combination with soil-loss estimates were needed to draw these conclusions. These findings provide information to farmers and soil conservation agents about the ability of conservation tillage to reduce soil erosion and suspended-sediment discharge from the Maumee River Basin.

  12. Sediment pathways in a tropical forest: effects of logging roads and skid trails

    NASA Astrophysics Data System (ADS)

    Sidle, Roy C.; Sasaki, Shozo; Otsuki, Mieko; Noguchi, Shoji; Rahim Nik, Abdul

    2004-03-01

    Significant erosion occurred from recently constructed forest logging roads and skid trails in a small headwater catchment in Peninsular Malaysia. Soil loss was estimated by measuring dimensions of all significant rills and gullies along the road, as well as by measuring height of preserved soil pedestals in sidecast and fill material and on skid trails. Estimates of surface erosion from logging roads and skid trails were 272 +/- 20 t ha-1 year-1 and 275 +/- 20 t ha-1 year-1 respectively. However, owing to lack of connectivity of skid trails to the stream, much of the sediment mobilized on skid trails was stored either on adjacent hillslopes or the trails themselves, rather than being transported to the stream system, as was the case for the road. Steeper skid trails (>20% gradient) had slightly higher erosion rates (320 +/- 24 t ha-1 year-1) than trails with gentler gradients (245-264 t ha-1 year-1). Some 60% of the soil loss on logging roads comes from erosion of the running surface. Disturbed cut and fill material along the road supplied the remaining 40% of the soil loss from roads. Roads and skid trails had no designed drainage systems; runoff discharged onto the hillslope at 25 major discharge nodes from the logging road (690 m total length) and at 34 nodes from skid trails (2300 m). Sediment pathways were either fully or moderately connected to headwater channels at 64% of the logging road nodes, but at only 26% of the nodes emanating from skid trails. A detailed sediment budget revealed that 78% of the soil loss from the road system (including log landings) was delivered to the stream in the first 16 months after logging began. Most (90%) of the deposition from skid trails occurred below just three discharge nodes. Runoff from and onto skid trails often exacerbated the sediment connectivity to channels. Clearly, sediment discharge from logging roads was more highly connected to the stream than discharge from skid trails. Once in the channel, much of this sediment was temporarily stored in the floodplain and behind woody debris.

  13. Spatial analysis of soil erosion and sediment fluxes: a paired watershed study of two Rappahannock River tributaries, Stafford County, Virginia.

    PubMed

    Ricker, Matthew C; Odhiambo, Ben K; Church, Joseph M

    2008-05-01

    Soil erosion is a serious problem in areas with expanding construction, agricultural production, and improper storm water management. It is important to understand the major processes affecting sediment delivery to surficial water bodies in order to tailor effective mitigation and outreach activities. This study analyzes how naturally occurring and anthropogenic influences, such as urbanization and soil disturbance on steep slopes, are reflected in the amount of soil erosion and sediment delivery within sub-watershed-sized areas. In this study, two sub-watersheds of the Rappahannock River, Horsepen Run and Little Falls Run, were analyzed using the Revised Universal Soil Loss Equation (RUSLE) and a sediment delivery ratio (SDR) to estimate annual sediment flux rates. The RUSLE/SDR analyses for Horsepen Run and Little Falls Run predicted 298 Mg/y and 234 Mg/y, respectively, but nearly identical per-unit-area sediment flux rates of 0.15 Mg/ha/y and 0.18 Mg/ha/y. Suspended sediment sampling indicated greater amounts of sediment in Little Falls Run, which is most likely due to anthropogenic influences. Field analyses also suggest that all-terrain vehicle crossings represent the majority of sediment flux derived from forested areas of Horsepen Run. The combined RUSLE/SDR and field sampling data indicate that small-scale anthropogenic disturbances (ATV trails and construction sites) play a major role in overall sediment flux rates for both basins and that these sites must be properly accounted for when evaluating sediment flux rates at a sub-watershed scale.

  14. Modeling and analysis of Soil Erosion processes by the River Basins model: The Case Study of the Krivacki Potok Watershed, Montenegro

    NASA Astrophysics Data System (ADS)

    Vujacic, Dusko; Barovic, Goran; Mijanovic, Dragica; Spalevic, Velibor; Curovic, Milic; Tanaskovic, Vjekoslav; Djurovic, Nevenka

    2016-04-01

    The objective of this research was to study soil erosion processes in one of Northern Montenegrin watersheds, the Krivacki Potok Watershed of the Polimlje River Basin, using modeling techniques: the River Basins computer-graphic model, based on the analytical Erosion Potential Method (EPM) of Gavrilovic for calculation of runoff and soil loss. Our findings indicate a low potential of soil erosion risk, with 554 m³ yr-1 of annual sediment yield; an area-specific sediment yield of 180 m³km-2 yr-1. The calculation outcomes were validated for the entire 57 River Basins of Polimlje, through measurements of lake sediment deposition at the Potpec hydropower plant dam. According to our analysis, the Krivacki Potok drainage basin is with the relatively low sediment discharge; according to the erosion type, it is mixed erosion. The value of the Z coefficient was calculated on 0.297, what indicates that the river basin belongs to 4th destruction category (of five). The calculated peak discharge from the river basin was 73 m3s-1 for the incidence of 100 years and there is a possibility for large flood waves to appear in the studied river basin. Using the adequate computer-graphic and analytical modeling tools, we improved the knowledge on the soil erosion processes of the river basins of this part of Montenegro. The computer-graphic River Basins model of Spalevic, which is based on the EPM analytical method of Gavrilovic, is highly recommended for soil erosion modelling in other river basins of the Southeastern Europe. This is because of its reliable detection and appropriate classification of the areas affected by the soil loss caused by soil erosion, at the same time taking into consideration interactions between the various environmental elements such as Physical-Geographical Features, Climate, Geological, Pedological characteristics, including the analysis of Land Use, all calculated at the catchment scale.

  15. Effects of soil type and rainfall intensity on sheet erosion processes and sediment characteristics along the climatic gradient in central-south China.

    PubMed

    Wu, Xinliang; Wei, Yujie; Wang, Junguang; Xia, Jinwen; Cai, Chongfa; Wei, Zhiyuan

    2018-04-15

    Soil erosion poses a major threat to the sustainability of natural ecosystems. The main objective of this study was to investigate the effects of soil type and rainfall intensity on sheet erosion processes (hydrological, erosional processes and sediment characteristics) from temperate to tropical climate. Field plot experiments were conducted under pre-wetted bare fallow condition for five soil types (two Luvisols, an Alisol, an Acrisol and a Ferralsol) with heavy textures (silty clay loam, silty clay and clay) derived separately from loess deposits, quaternary red clays and basalt in central-south China. Rainfall simulations were performed at two rainfall intensities (45 and 90mmh -1 ) and lasted one hour after runoff generation. Runoff coefficient, sediment concentration, sediment yield rate and sediment effective size distribution were determined at 3-min intervals. Runoff temporal variations were similar at the high rainfall intensity, but exhibited a remarkable difference at the low rainfall intensity among soil types except for tropical Ferralsol. Illite was positively correlated with runoff coefficient (p<0.05). Rainfall intensity significantly contributed to the erosional process (p<0.001). Sediment concentration and yield rate were the smallest for the tropical Ferralsol and sediment concentration was the largest for the temperate Luvisol. The regimes (transport and detachment) limiting erosion varied under the interaction of rainfall characteristics (intensity and duration) and soil types, with amorphous iron oxides and bulk density jointly enhancing soil resistance to erosive forces (Adj-R 2 >88%, p<0.001). Sediment size was dominated by <0.1mm size fraction for the Luvisols and bimodally distributed with the peaks at <0.1mm and 1-0.5mm size for the other soil types. Exchangeable sodium decreased sediment size while rainfall intensity and clay content increased it (Adj-R 2 =96%, p<0.01). These results allow to better understand the climate effect on erosion processes at the spatial-temporal scale from the perspective of soil properties. Copyright © 2017 Elsevier B.V. All rights reserved.

  16. An Asia-specific source of dechlorane plus: concentration, isomer profiles, and other related compounds.

    PubMed

    Wang, De-Gao; Yang, Meng; Qi, Hong; Sverko, Ed; Ma, Wan-Li; Li, Yi-Fan; Alaee, Mehran; Reiner, Eric J; Shen, Li

    2010-09-01

    The distribution of dechloranes, a group of chlorinated flame retardants, were investigated in air, soil, and sediment around a newly discovered Dechlorane Plus (DP) production facility in China (Anpon). To date, the only known DP manufacturing plant is located in Niagara Falls, NY (OxyChem). Dechloranes including DP, Dechlorane (Mirex), and the recently discovered Dechlorane 602 (Dec 602) were detected in air, soil, and sediment, while Dechlorane 603 and Dechlorane 604 were below detection limit in all matrices. DP air concentrations near the facility ranged from 7737 to 26 734 pg m(-3), the greatest reported thus far. Soil concentrations in the same area for DP, Dechlorane, and Dec 602 were 1490+/-3580 ng g(-1), 81.6+/-96.5 ng g(-1), and 7.24+/-13.2 ng g(-1) dry weight, respectively. Interestingly, lower concentrations of DP (4.93+/-4.34 ng g(-1)), Dechlorane (30.2+/-19.9 ng g(-1)), and Dec 602 (2.14+/-2.23 ng g(-1)) were found in sediment from a nearby canal. Spatial trends of Dechlorane and Dec 602 in soil were similar to DP, implying that the DP manufacturing plant may also be a source of these other flame retardants. DP soil concentrations surrounding the facility decreased by an order of magnitude within 7.5 km. The syn-DP fractional abundance (fsyn) value (0.40) for the commercial DP product manufactured at Anpon was slightly higher than that (0.20-0.36) produced by OxyChem. The fsyn value in most air samples was largely similar to the Chinese commercial DP mixture, while most soil and sediment abundances were lower, suggesting a stereoselective depletion of syn-DP.

  17. Soil erosion and sediment yield, a double barrel problem in South Africa's only large river network without a dam

    NASA Astrophysics Data System (ADS)

    Le Roux, Jay

    2016-04-01

    Soil erosion not only involves the loss of fertile topsoil but is also coupled with sedimentation of dams, a double barrel problem in semi-arid regions where water scarcity is frequent. Due to increasing water requirements in South Africa, the Department of Water and Sanitation is planning water resource development in the Mzimvubu River Catchment, which is the only large river network in the country without a dam. Two dams are planned including a large irrigation dam and a hydropower dam. However, previous soil erosion studies indicate that large parts of the catchment is severely eroded. Previous studies, nonetheless, used mapping and modelling techniques that represent only a selection of erosion processes and provide insufficient information about the sediment yield. This study maps and models the sediment yield comprehensively by means of two approaches over a five-year timeframe between 2007 and 2012. Sediment yield contribution from sheet-rill erosion was modelled with ArcSWAT (a graphical user interface for SWAT in a GIS), whereas gully erosion contributions were estimated using time-series mapping with SPOT 5 imagery followed by gully-derived sediment yield modelling in a GIS. Integration of the sheet-rill and gully results produced a total sediment yield map, with an average of 5 300 t km-2 y-1. Importantly, the annual average sediment yield of the areas where the irrigation dam and hydropower dam will be built is around 20 000 t km-2 y-1. Without catchment rehabilitation, the life expectancy of the irrigation dam and hydropower dam could be 50 and 40 years respectively.

  18. Foliar concentrations of volunteer willows growing on polluted sediment-derived sites versus sites with baseline contamination levels.

    PubMed

    Vandecasteele, Bart; Quataert, Paul; De Vos, Bruno; Tack, Filip M G; Muys, Bart

    2004-04-01

    Many alluvial soils along navigable waterways are affected by disposal of dredged sediments or overbank sedimentation and contain metal concentrations that are elevated compared to baseline levels. Uptake patterns for metals and other elements by several volunteer Salix species growing on these sites were determined during a growing season in field plots and compared with the same species growing on soils with baseline contamination levels. For Cd and Zn, foliar concentrations were clearly higher on dredged sediment landfills. Uptake patterns differed significantly between species. A high uptake of Mn and low uptake of Cu, K and S in S. cinerea was attributed to wetland soil chemistry. Site effects on metal uptake were evaluated in more detail for Salix cinerea and S. alba growing on different sediment-derived sites under field conditions. Foliar Cd concentrations were higher in S. cinerea than in S. alba. This appeared to be a genetic feature not influenced by soil chemical properties, as it was observed both on clean sites and polluted sediment-derived sites. For S. cinerea, soil chemistry was reflected in foliar concentrations, while foliar Cd concentrations and bioavailability were found to be independent of the thickness of the polluted horizon. Dredged sediment landfills and freshwater tidal marshes with comparable Cd soil pollution had significantly different foliar Cd concentrations.

  19. Sediment pollution impacts sensory ability and performance of settling coral-reef fish.

    PubMed

    O'Connor, J Jack; Lecchini, David; Beck, Hayden J; Cadiou, Gwenael; Lecellier, Gael; Booth, David J; Nakamura, Yohei

    2016-01-01

    Marine organisms are under threat globally from a suite of anthropogenic sources, but the current emphasis on global climate change has deflected the focus from local impacts. While the effect of increased sedimentation on the settlement of coral species is well studied, little is known about the impact on larval fish. Here, the effect of a laterite "red soil" sediment pollutant on settlement behaviour and post-settlement performance of reef fish was tested. In aquarium tests that isolated sensory cues, we found significant olfaction-based avoidance behaviour and disruption of visual cue use in settlement-stage larval fish at 50 mg L(-1), a concentration regularly exceeded in situ during rain events. In situ light trap catches showed lower abundance and species richness in the presence of red soil, but were not significantly different due to high variance in the data. Prolonged exposure to red soil produced altered olfactory cue responses, whereby fish in red soil made a likely maladaptive choice for dead coral compared to controls where fish chose live coral. Other significant effects of prolonged exposure included decreased feeding rates and body condition. These effects on fish larvae reared over 5 days occurred in the presence of a minor drop in pH and may be due to the chemical influence of the sediment. Our results show that sediment pollution of coral reefs may have more complex effects on the ability of larval fish to successfully locate suitable habitat than previously thought, as well as impacting on their post-settlement performance and, ultimately, recruitment success.

  20. Comparisons of Unconsolidated Sediments Analyzed by APXS (MSL-Curiosity) within Gale Crater, Mars: Soils, Sands of the Barchan and Linear Dunes of the Active Bagnold Dune Field, and Ripple-field Sands.

    NASA Astrophysics Data System (ADS)

    Thompson, L. M.; O'Connell-Cooper, C.; Spray, J. G.; Gellert, R.; Boyd, N. I.; Desouza, E.

    2017-12-01

    The MSL-APXS has analyzed a variety of unconsolidated sediments within the Gale impact crater, including soils, sands from barchan [High, Namib dunes], and linear dunes [Nathan Bridges, Mount Desert dunes], within the active Bagnold dune field, and sands from two smaller ripple fields ("mega-ripples"). The Gale "soils" (unsorted, unconsolidated sediments, ranging from fine-grained particles (including dust) to coarser "pebbly" material [>2 mm]), are, to a large degree, similar to Martian basaltic soils quantified by APXS, at Gusev crater (MER-A_Spirit) and Meridiani Planum (MER-B_Opportunity). Some local contributions are indicated by, for example, the enriched K levels (relative to a martian average basaltic soil [ABS]) within coarser Gale soil samples, and a Cr, Mn, Fe enrichment within finer-grained samples. Sands (grain size 62 µm to 2 mm) of the Bagnold dunes, generally, exhibit elevated Mg and Ni, indicating enrichment from olivine and pyroxene, but depleted S, Cl and Zn, indicating high activity levels and low dust. Compositional differences, related both to position within a dune (i.e., crest versus off-crest sand), and type of dune (linear versus barchan), are identified. Off-crest sands have Na, Al, Si, K, P contents similar to (or slightly depleted, relative to) the ABS, enrichment in Mg, and low dust content, whilst crest sands contain very high Mg and Ni (relative to the ABS), low felsic elemental concentrations and very low dust content. Cr is significantly enriched (and, to a lesser degree, Mn, Fe, Ti) in the off-crest sands of the linear dunes. In contrast, barchan dunes off-crest sands have Cr, Mn, Fe, and Ti abundances similar to those in the Gale soils. Additionally, Ni concentrations in barchan dunes off-crest sands are enriched relative to the linear dunes. Analyses from a small, isolated "mega-ripple" reveal a composition similar to that of the Gale soils, including a high dust content. The second mega-ripple, within a larger ripple field, is broadly similar in composition to the active dune sands, with low dust, and elevated Mg and Ni. The compositional differences between sand bodies indicate the influence of ongoing eolian sorting processes. Further, the Cr enrichment (found in most Gale sediments, most notably the linear dunes off-crest sands) reinforces evidence of local contributions.

  1. MODELING UNCERTAINTY OF RUNOFF AND SEDIMENT YIELD IN TWO EXPERIMENTAL WATERSHEDS

    EPA Science Inventory

    Sediment loading from agriculture is adversely impacting surface water quality and ecological conditions. In this regard, the use of distributed hydrologic models has gained acceptance in management of soil erosion and sediment yield from agricultural watersheds. Soil infiltrati...

  2. Predicting Monsoonal-Driven Stream Discharge and Sediment Yield in Himalaya Mountain Basins with Changing Climate and Deforestation

    NASA Astrophysics Data System (ADS)

    Neupane, R. P.; White, J. D.

    2014-12-01

    Short and long term effects of site water availability impacts the spectrum of management outcomes including landslide risk, hydropower generation, and sustainable agriculture in mountain systems heavily influenced by climate and land use changes. Climate change and land use may predominantly affect the hydrologic cycle of mountain basins as soil precipitation interception is affected by land cover. Using the Soil and Water Assessment Tool, we estimated stream discharge and sediment yield associated with climate and land use changes for two Himalaya basins located at eastern and western margins of Nepal that included drainages of the Tamor and Seti Rivers. Future climate change was modeled using average output of temperature and precipitation changes derived from Special Report on Emission Scenarios (B1, A1B & A2) of 16 global circulation models for 2080 as meteorological inputs into SWAT. Land use change was modeled spatially and included 1) deforestation, 2) expansion of agricultural land, and 3) increased human settlement that were produced by considering current land use with projected changes associated with viability of elevation and slope characteristics of the basins capable of supporting different land use types. We found higher annual stream discharge in all GCM-derived scenarios compared to the baseline with maximum increases of 13 and 8% in SRES-A2 and SRES-A1B for the Tamor and Seti basins, respectively. With 7% of original forest land removed, sediment yield for Tamor basin was estimated to be 65% higher, but increased to 124% for the SRES-B1 scenario. For the Seti basin, 4% deforestation yielded 33% more sediment for the SRES-A1B scenario. Our results indicated that combined effects of future, intensified monsoon rainfall with deforestation lead to dramatic potential for increased stream discharge and sediment yield as rainfall on steep slopes with thin exposed soils increases surface runoff and soil erosion in the Himalayas. This effect appears to be geographically important with higher influence in the eastern Tamor basin potentially due to longer and stronger monsoonal period of that area. Future slope stability and sediment deposition in downstream reservoirs are important future potential vulnerabilities for these basins of which land management plays an important mediating role.

  3. Interpreting stream sediment fingerprints against primary and secondary source signatures in agricultural catchments

    NASA Astrophysics Data System (ADS)

    Blake, Will H.; Haley, Steve; Smith, Hugh G.; Taylor, Alex; Goddard, Rupert; Lewin, Sean; Fraser, David

    2013-04-01

    Many sediment fingerprinting studies adopt a black box approach to source apportionment whereby the properties of downstream sediment are compared quantitatively to the geochemical fingerprints of potential catchment sources without consideration of potential signature development or modification during transit. Working within a source-pathway-receptor framework, this study aimed to undertake sediment source apportionment within 6 subcatchments of an agricultural river basin with specific attention to the potential role of contaminants (vehicle emissions and mine waste) in development of stream sediment signatures. Fallout radionuclide (FRN) and geochemical fingerprinting methods were adopted independently to establish source signatures for primary sediment sources of surface and subsurface soil materials under various land uses plus reworked mine and 'secondary' soil material deposited, in transit, along road networks. FRN data demonstrated expected variability between surface soil (137Cs = 14 ± 3 Bq kg-1; 210Pbxs = 40 ± 7 Bq kg-1) and channel bank materials (137Cs = 3 ± 1 Bq kg-1; 210Pbxs = 24 ± 5 Bq kg-1) but road transported soil material was considerably elevated in 210Pbxs (up to 673 ± 51 Bq kg-1) due to sediment interaction with pluvial surface water within the road network. Geochemical discrimination between surface and subsurface soil materials was dominated by alkaline earth and alkali metals e.g. Ba, Rb, Ca, K, Mg which are sensitive to weathering processes in soil. Magnetic susceptibility and heavy metals were important discriminators of road transported material which demonstrated transformation of the signatures of material transported via the road network. Numerical unmixing of stream sediment indicated that alongside channel bank erosion, road transported material was an important component in some systems in accord with FRN evidence. While mining spoil also ranked as a significant source in an affected catchment, perhaps related to legacy sediment, the potential role of dissolved metal leaching and subsequent sediment-water interaction within the channel on signature modification remained unclear. Consideration of sediment signature modification en route from primary source to stream elucidated important information regarding sediment transfer pathways and dynamics relevant to sediment management decisions. Further work on sediment-water interactions and potential for signature transformation in the channel environment is required.

  4. Assessment of grass root effects on soil piping in sandy soils using the pinhole test

    NASA Astrophysics Data System (ADS)

    Bernatek-Jakiel, Anita; Vannoppen, Wouter; Poesen, Jean

    2017-10-01

    Soil piping is an important land degradation process that occurs in a wide range of environments. Despite an increasing number of studies on this type of subsurface erosion, the impact of vegetation on piping erosion is still unclear. It can be hypothesized that vegetation, and in particular plant roots, may reduce piping susceptibility of soils because roots of vegetation also control concentrated flow erosion rates or shallow mass movements. Therefore, this paper aims to assess the impact of grass roots on piping erosion susceptibility of a sandy soil. The pinhole test was used as it provides quantitative data on pipeflow discharge, sediment concentration and sediment discharge. Tests were conducted at different hydraulic heads (i.e., 50 mm, 180 mm, 380 mm and 1020 mm). Results showed that the hydraulic head was positively correlated with pipeflow discharge, sediment concentration and sediment discharge, while the presence of grass roots (expressed as root density) was negatively correlated with these pipeflow characteristics. Smaller sediment concentrations and sediment discharges were observed in root-permeated samples compared to root-free samples. When root density exceeds 0.5 kg m- 3, piping erosion rates decreased by 50% compared to root-free soil samples. Moreover, if grass roots are present, the positive correlation between hydraulic head and both sediment discharge and sediment concentration is less pronounced, demonstrating that grass roots become more effective in reducing piping erosion rates at larger hydraulic heads. Overall, this study demonstrates that grass roots are quite efficient in reducing piping erosion rates in sandy soils, even at high hydraulic head (> 1 m). As such, grass roots may therefore be used to efficiently control piping erosion rates in topsoils.

  5. Contamination and risk of heavy metals in soils and sediments from a typical plastic waste recycling area in North China.

    PubMed

    Tang, Zhenwu; Zhang, Lianzhen; Huang, Qifei; Yang, Yufei; Nie, Zhiqiang; Cheng, Jiali; Yang, Jun; Wang, Yuwen; Chai, Miao

    2015-12-01

    Plastic wastes are increasingly being recycled in many countries. However, available information on the metals released into the environment during recycling processes is rare. In this study, the contamination features and risks of eight heavy metals in soils and sediments were investigated in Wen'an, a typical plastic recycling area in North China. The surface soils and sediments have suffered from moderate to high metal pollution and in particular, high Cd and Hg pollution. The mean concentrations of Cd and Hg were 0.355 and 0.408 mg kg(-1), respectively, in the soils and 1.53 and 2.10 mg kg(-1), respectively, in the sediments. The findings suggested that there is considerable to high potential ecological risks in more than half of the soils and high potential ecological risk in almost all sediments. Although the health risk levels from exposure to soil metals were acceptable for adults, the non-carcinogenic risks to local children exceeded the acceptable level. Source assessment indicated that heavy metals in soils and sediments were mainly derived from inputs from poorly controlled plastic waste recycling operations in this area. The results suggested that the risks associated with heavy metal pollution from plastic waste recycling should be of great concern. Copyright © 2015 Elsevier Inc. All rights reserved.

  6. Differentiating the sources of fine sediment, organic matter and nitrogen in a subtropical Australian catchment.

    PubMed

    Garzon-Garcia, Alexandra; Laceby, J Patrick; Olley, Jon M; Bunn, Stuart E

    2017-01-01

    Understanding the sources of sediment, organic matter and nitrogen (N) transferred from terrestrial to aquatic environments is important for managing the deleterious off-site impacts of soil erosion. In particular, investigating the sources of organic matter associated with fine sediment may also provide insight into carbon (C) and N budgets. Accordingly, the main sources of fine sediment, organic matter (indicated by total organic carbon), and N are determined for three nested catchments (2.5km 2 , 75km 2 , and 3076km 2 ) in subtropical Australia. Source samples included subsoil and surface soil, along with C 3 and C 4 vegetation. All samples were analysed for stable isotopes (δ 13 C, δ 15 N) and elemental composition (TOC, TN). A stable isotope mixing model (SIAR) was used to determine relative source contributions for different spatial scales (nested catchments), climatic conditions and flow stages. Subsoil was the main source of fine sediment for all catchments (82%, SD=1.15) and the main N source at smaller scales (55-76%, SD=4.6-10.5), with an exception for the wet year and at the larger catchment, where surface soil was the dominant N source (55-61%, SD=3.6-9.9), though contributions were dependent on flow (59-680m 3 /s). C 3 litter was the main source of organic C export for the two larger catchments (53%, SD=3.8) even though C 4 grasses dominate the vegetation cover in these catchments. The sources of fine sediment, organic matter and N differ in subtropical catchments impacted by erosion, with the majority of C derived from C 3 leaf litter and the majority of N derived from either subsoil or surface soil. Understanding these differences will assist management in reducing sediment, organic matter and N transfers in similar subtropical catchments while providing a quantitative foundation for testing C and N budgets. Copyright © 2016 Elsevier B.V. All rights reserved.

  7. SUPERFUND TREATABILITY CLEARINGHOUSE: COMPOSITING EXPLOSIVES/ORGANICS CONTAMINATED SOILS

    EPA Science Inventory

    Laboratory scale and pilot scale studies were conducted to evaluate composting to treat sediments and soils containing explosive and organic compounds. Sediment and soil from lagoons at Army ammunition plants, located in Louisiana, Wisconsin and Pennsylvania contained high...

  8. Sorption and speciation of iodine in groundwater system: The roles of organic matter and organic-mineral complexes.

    PubMed

    Li, Junxia; Zhou, Hailing; Wang, Yanxin; Xie, Xianjun; Qian, Kun

    2017-06-01

    Characterizing the properties of main host of iodine in soil/sediment and the geochemical behaviors of iodine species are critical to understand the mechanisms of iodine mobilization in groundwater systems. Four surface soil and six subsurface sediment samples were collected from the iodine-affected area of Datong basin in northern China to conduct batch experiments and to evaluate the effects of NOM and/or organic-mineral complexes on iodide/iodate geochemical behaviors. The results showed that both iodine contents and k f -iodate values had positive correlations with solid TOC contents, implying the potential host of NOM for iodine in soil/sediment samples. The results of chemical removal of easily extracted NOM indicated that the NOM of surface soils is mainly composed of surface embedded organic matter, while sediment NOM mainly occurs in the form of organic-mineral complexes. After the removal of surface sorbed NOM, the decrease in k f -iodate value of treated surface soils indicates that surface sorbed NOM enhances iodate adsorption onto surface soil. By contrast, k f -iodate value increases in several H 2 O 2 -treated sediment samples, which was considered to result from exposed rod-like minerals rich in Fe/Al oxyhydroxide/oxides. After chemical removal of organic-mineral complexes, the lowest k f -iodate value for both treated surface soils and sediments suggests the dominant role of organic-mineral complexes on controlling the iodate geochemical behavior. In comparison with iodate, iodide exhibited lower affinities on all (un)treated soil/sediment samples. The understanding of different geochemical behaviors of iodine species helps to explain the occurrence of high iodine groundwater with iodate and iodide as the main species in shallow (oxidizing conditions) and deep (reducing conditions) groundwater. Copyright © 2017 Elsevier B.V. All rights reserved.

  9. Dioxin-like chemicals in soil and sediment from residential and industrial areas in central South Africa.

    PubMed

    Nieuwoudt, Claudine; Quinn, Laura P; Pieters, Rialet; Jordaan, Ilse; Visser, Maret; Kylin, Henrik; Borgen, Anders R; Giesy, John P; Bouwman, Henk

    2009-08-01

    Persistent organic pollutants (POPs) are a global concern due to their ubiquitous presence and toxicity. Currently, there is a lack of information regarding POPs from South Africa. Here we report and interpret concentrations of polychlorinated dibenzo-p-dioxins (PCDDs), -dibenzofurans (PCDFs) and co-planar-biphenyls (PCBs) in soils and sediments collected from central South Africa. High resolution gas chromatography-high resolution mass spectrometry (HRGC/HRMS) and the H4IIE-luc bio-assay were used to identify and quantify individual PCDD/F congeners and to report the total concentration of 2,3,7,8-tetrachloro dibenzo-p-dioxin equivalents (TCDD-EQ), respectively. TCDD-EQs determined by use of the bio-assay, and concentrations of WHO(2005)-TEQ (toxic equivalents) determined by chemical analysis, were similar. The limit of detection (LOD) for the bio-assay was 0.82 and 2.8 ng TCDD-EQ kg(-1), dw for sediment and soil, respectively. EQ20 concentrations determined by use of the bio-assay ranged from

  10. Sorption and speciation of iodine in groundwater system: The roles of organic matter and organic-mineral complexes

    NASA Astrophysics Data System (ADS)

    Li, Junxia; Zhou, Hailing; Wang, Yanxin; Xie, Xianjun; Qian, Kun

    2017-06-01

    Characterizing the properties of main host of iodine in soil/sediment and the geochemical behaviors of iodine species are critical to understand the mechanisms of iodine mobilization in groundwater systems. Four surface soil and six subsurface sediment samples were collected from the iodine-affected area of Datong basin in northern China to conduct batch experiments and to evaluate the effects of NOM and/or organic-mineral complexes on iodide/iodate geochemical behaviors. The results showed that both iodine contents and kf-iodate values had positive correlations with solid TOC contents, implying the potential host of NOM for iodine in soil/sediment samples. The results of chemical removal of easily extracted NOM indicated that the NOM of surface soils is mainly composed of surface embedded organic matter, while sediment NOM mainly occurs in the form of organic-mineral complexes. After the removal of surface sorbed NOM, the decrease in kf-iodate value of treated surface soils indicates that surface sorbed NOM enhances iodate adsorption onto surface soil. By contrast, kf-iodate value increases in several H2O2-treated sediment samples, which was considered to result from exposed rod-like minerals rich in Fe/Al oxyhydroxide/oxides. After chemical removal of organic-mineral complexes, the lowest kf-iodate value for both treated surface soils and sediments suggests the dominant role of organic-mineral complexes on controlling the iodate geochemical behavior. In comparison with iodate, iodide exhibited lower affinities on all (un)treated soil/sediment samples. The understanding of different geochemical behaviors of iodine species helps to explain the occurrence of high iodine groundwater with iodate and iodide as the main species in shallow (oxidizing conditions) and deep (reducing conditions) groundwater.

  11. Fine sediment sources in conservation effects assessment project watersheds

    USDA-ARS?s Scientific Manuscript database

    Two naturally occurring radionuclides, 7Be and 210Pbxs , were used as tracers to discriminate eroded surface soils from channel-derived sediments in the fine suspended sediment loads of eight Conservation Effects Assessment Project (CEAP) benchmark watersheds. Precipitation, source soils, and suspe...

  12. DETERMINATION OF THE ENVIRONMENTAL IMPACT OF SEVERAL SUBSTITUTE CHEMICALS IN AGRICULTURALLY AFFECTED WETLANDS

    EPA Science Inventory

    Procedures have been developed for processing of anaerobic wetland sediments for pesticide recovery along with formulation of simulation models of anaerobic/aerobic soil and sediment environments to study pesticide degradation. Redox conditions of soils and sediment-water systems...

  13. ISSUES IN ASSESSING LOW LEVEL IONIZABLE CONTAMINANT PARTITIONING IN SOILS AND SEDIMENTS

    EPA Science Inventory

    Solubilization has profound implications for such diverse risk assessment activities as assessing sediment contaminant porewater exposures to benthic fauna, determining half lives of refractory toxicants in natural soils and sediments, and assessing the fate and transport of th...

  14. Methane Emission in a Specific Riparian-Zone Sediment Decreased with Bioelectrochemical Manipulation and Corresponded to the Microbial Community Dynamics

    PubMed Central

    Friedman, Elliot S.; McPhillips, Lauren E.; Werner, Jeffrey J.; Poole, Angela C.; Ley, Ruth E.; Walter, M. Todd; Angenent, Largus T.

    2016-01-01

    Dissimilatory metal-reducing bacteria are widespread in terrestrial ecosystems, especially in anaerobic soils and sediments. Thermodynamically, dissimilatory metal reduction is more favorable than sulfate reduction and methanogenesis but less favorable than denitrification and aerobic respiration. It is critical to understand the complex relationships, including the absence or presence of terminal electron acceptors, that govern microbial competition and coexistence in anaerobic soils and sediments, because subsurface microbial processes can effect greenhouse gas emissions from soils, possibly resulting in impacts at the global scale. Here, we elucidated the effect of an inexhaustible, ferrous-iron and humic-substance mimicking terminal electron acceptor by deploying potentiostatically poised electrodes in the sediment of a very specific stream riparian zone in Upstate New York state. At two sites within the same stream riparian zone during the course of 6 weeks in the spring of 2013, we measured CH4 and N2/N2O emissions from soil chambers containing either poised or unpoised electrodes, and we harvested biofilms from the electrodes to quantify microbial community dynamics. At the upstream site, which had a lower vegetation cover and highest soil temperatures, the poised electrodes inhibited CH4 emissions by ∼45% (when normalized to remove temporal effects). CH4 emissions were not significantly impacted at the downstream site. N2/N2O emissions were generally low at both sites and were not impacted by poised electrodes. We did not find a direct link between bioelectrochemical treatment and microbial community membership; however, we did find a correspondence between environment/function and microbial community dynamics. PMID:26793170

  15. Online interactive U.S. Reservoir Sedimentation Survey Database

    USGS Publications Warehouse

    Gray, J.B.; Bernard, J.M.; Schwarz, G.E.; Stewart, D.W.; Ray, K.T.

    2009-01-01

    In April 2009, the U.S. Geological Survey and the Natural Resources Conservation Service (prior to 1994, the Soil Conservation Service) created the Reservoir Sedimentation Survey Database (RESSED) and Web site, the most comprehensive compilation of data from reservoir bathymetric and dry basin surveys in the United States. RESSED data can be useful for a number of purposes, including calculating changes in reservoir storage characteristics, quantifying rates of sediment delivery to reservoirs, and estimating erosion rates in a reservoir's watershed.

  16. Membrane inlet laser spectroscopy to measure H and O stable isotope compositions of soil and sediment pore water with high sample throughput

    DOE PAGES

    Oerter, Erik J.; Perelet, Alexei; Pardyjak, Eric; ...

    2016-10-20

    Here, the fast and accurate measurement of H and O stable isotope compositions (δ 2H and δ 18O values) of soil and sediment pore water remains an impediment to scaling-up the application of these isotopes in soil and vadose hydrology. Here we describe a method and its calibration to measuring soil and sediment pore water δ 2H and δ 18O values using a water vapor-permeable probe coupled to an isotope ratio infrared spectroscopy analyzer.

  17. Modeling runoff and sediment yield from a terraced watershed using WEPP

    Treesearch

    Mary Carla McCullough; Dean E. Eisenhauer; Michael G. Dosskey

    2008-01-01

    The watershed version of WEPP (Water Erosion Prediction Project) was used to estimate 50-year runoff and sediment yields for a 291 ha watershed in eastern Nebraska that is 90% terraced and which has no historical gage data. The watershed has a complex matrix of elements, including terraced and non-terraced subwatersheds, multiple combinations of soils and land...

  18. Sedimentation and Its Impacts/Effects on River System and Reservoir Water Quality: case Study of Mazowe Catchment, Zimbabwe

    NASA Astrophysics Data System (ADS)

    Tundu, Colleta; Tumbare, Michael James; Kileshye Onema, Jean-Marie

    2018-04-01

    Sediment delivery into water sources and bodies results in the reduction of water quantity and quality, increasing costs of water purification whilst reducing the available water for various other uses. The paper gives an analysis of sedimentation in one of Zimbabwe's seven rivers, the Mazowe Catchment, and its impact on water quality. The Revised Universal Soil Loss Equation (RUSLE) model was used to compute soil lost from the catchment as a result of soil erosion. The model was used in conjunction with GIS remotely sensed data and limited ground observations. The estimated annual soil loss in the catchment indicates soil loss ranging from 0 to 65 t ha yr-1. Bathymetric survey at Chimhanda Dam showed that the capacity of the dam had reduced by 39 % as a result of sedimentation and the annual sediment deposition into Chimhanda Dam was estimated to be 330 t with a specific yield of 226 t km-2 yr-1. Relationship between selected water quality parameters, TSS, DO, NO3, pH, TDS, turbidity and sediment yield for selected water sampling points and Chimhanda Dam was analyzed. It was established that there is a strong positive relationship between the sediment yield and the water quality parameters. Sediment yield showed high positive correlation with turbidity (0.63) and TDS (0.64). Water quality data from Chimhanda treatment plant water works revealed that the quality of water is deteriorating as a result of increase in sediment accumulation in the dam. The study concluded that sedimentation can affect the water quality of water sources.

  19. Lutz's spontaneous sedimentation technique and the paleoparasitological analysis of sambaqui (shell mound) sediments

    PubMed Central

    Camacho, Morgana; Pessanha, Thaíla; Leles, Daniela; Dutra, Juliana MF; Silva, Rosângela; de Souza, Sheila Mendonça; Araujo, Adauto

    2013-01-01

    Parasite findings in sambaquis (shell mounds) are scarce. Although the 121 shell mound samples were previously analysed in our laboratory, we only recently obtained the first positive results. In the sambaqui of Guapi, Rio de Janeiro, Brazil, paleoparasitological analysis was performed on sediment samples collected from various archaeological layers, including the superficial layer as a control. Eggs of Acanthocephala, Ascaridoidea and Heterakoidea were found in the archaeological layers. We applied various techniques and concluded that Lutz's spontaneous sedimentation technique is effective for concentrating parasite eggs in sambaqui soil for microscopic analysis. PMID:23579793

  20. Lutz's spontaneous sedimentation technique and the paleoparasitological analysis of sambaqui (shell mound) sediments.

    PubMed

    Camacho, Morgana; Pessanha, Thaíla; Leles, Daniela; Dutra, Juliana M F; Silva, Rosângela; Souza, Sheila Mendonça de; Araujo, Adauto

    2013-04-01

    Parasite findings in sambaquis (shell mounds) are scarce. Although the 121 shell mound samples were previously analysed in our laboratory, we only recently obtained the first positive results. In the sambaqui of Guapi, Rio de Janeiro, Brazil, paleoparasitological analysis was performed on sediment samples collected from various archaeological layers, including the superficial layer as a control. Eggs of Acanthocephala, Ascaridoidea and Heterakoidea were found in the archaeological layers. We applied various techniques and concluded that Lutz's spontaneous sedimentation technique is effective for concentrating parasite eggs in sambaqui soil for microscopic analysis.

  1. Arsenic and mercury concentrations in major landscape components of an intensively cultivated watershed.

    PubMed

    Cooper, C M; Gillespie, W B

    2001-01-01

    To provide an understanding of arsenic (As) and mercury (Hg) concentrations in soil, sediment, water, and fish tissues, samples were collected from a Mississippi River alluvial floodplain located in northwest Mississippi. As concentrations increased approximately an order of magnitude from water (5.12 micrograms/l) to fish tissues (36.99 micrograms/kg) and an additional two orders of magnitude in soils, lake sediments, and wetland sediments (5728, 5614, and 6746 micrograms/kg), respectively. Average Hg concentrations in water, soils, lake sediments, and fish were 2.16 micrograms/l, 55.1, 14.5 and 125 micrograms/kg, respectively. As and Hg concentrations were within published ranges for uncontaminated soil, water, and sediments. As concentrations represented a low risk. Hg concentrations were also low but showed a greater tendency to concentrate in fish tissue. The dominant mode of entry of these materials into aquatic systems is through storm-generated runoff. Since both metals accompany sediments, agricultural conservation practices such as reduced tillage, buffer riparian strips, and bordering sediment ponds or drainage wetlands will minimize watershed input to aquatic systems.

  2. Estimation of sediment sources using selected chemical tracers in the Perry lake basin, Kansas, USA

    USGS Publications Warehouse

    Juracek, K.E.; Ziegler, A.C.

    2009-01-01

    The ability to achieve meaningful decreases in sediment loads to reservoirs requires a determination of the relative importance of sediment sources within the contributing basins. In an investigation of sources of fine-grained sediment (clay and silt) within the Perry Lake Basin in northeast Kansas, representative samples of channel-bank sources, surface-soil sources (cropland and grassland), and reservoir bottom sediment were collected, chemically analyzed, and compared. The samples were sieved to isolate the <63 ?? m fraction and analyzed for selected nutrients (total nitrogen and total phosphorus), organic and total carbon, 25 trace elements, and the radionuclide cesium-137 (137Cs). On the basis of substantial and consistent compositional differences among the source types, total nitrogen (TN), total phosphorus (TP), total organic carbon (TOC), and 137Cs were selected for use in the estimation of sediment sources. To further account for differences in particle-size composition between the sources and the reservoir bottom sediment, constituent ratio and clay-normalization techniques were used. Computed ratios included TOC to TN, TOC to TP, and TN to TP. Constituent concentrations (TN, TP, TOC) and activities (137Cs) were normalized by dividing by the percentage of clay. Thus, the sediment-source estimations involved the use of seven sediment-source indicators. Within the Perry Lake Basin, the consensus of the seven indicators was that both channel-bank and surface-soil sources were important in the Atchison County Lake and Banner Creek Reservoir subbasins, whereas channel-bank sources were dominant in the Mission Lake subbasin. On the sole basis of 137Cs activity, surface-soil sources contributed the most fine-grained sediment to Atchison County Lake, and channel-bank sources contributed the most fine-grained sediment to Banner Creek Reservoir and Mission Lake. Both the seven-indicator consensus and 137Cs indicated that channel-bank sources were dominant for Perry Lake and that channel-bank sources increased in importance with distance downstream in the basin. ?? 2009 International Research and Training Centre on Erosion and Sedimentation and the World Association for Sedimentation and Erosion Research.

  3. Rainfall kinetic energy controlling erosion processes and sediment sorting on steep hillslopes: A case study of clay loam soil from the Loess Plateau, China

    NASA Astrophysics Data System (ADS)

    Wang, L.; Shi, Z. H.; Wang, J.; Fang, N. F.; Wu, G. L.; Zhang, H. Y.

    2014-05-01

    Rainfall kinetic energy (KE) can break down aggregates in the soil surface. A better understanding of sediment sorting associated with various KEs is essential for the development and verification of soil erosion models. A clay loam soil was used in the experiments. Six KEs were obtained (76, 90, 105, 160, 270, and 518 J m-2 h-1) by covering wire screens located above the soil surface with different apertures to change the size of raindrops falling on the soil surface, while maintaining the same rainfall intensity (90 ± 3.5 mm h-1). For each rainfall simulation, runoff and sediment were collected at 3-min intervals to investigate the temporal variation of the sediment particle size distribution (PSD). Comparison of the sediment effective PSD (undispersed) and ultimate PSD (dispersed) was used to investigate the detachment and transport mechanisms involved in sediment mobilization. The effective-ultimate ratios of clay-sized particles were less than 1, whereas that of sand-sized particles were greater than 1, suggesting that these particles were transported as aggregates. Under higher KE, the effective-ultimate ratios were much closer to 1, indicating that sediments were more likely transported as primary particles at higher KE owing to an increased severity of aggregate disaggregation for the clay loam soil. The percentage of clay-sized particles and the relative importance of suspension-saltation increased with increasing KE when KE was greater than 105 J m-2 h-1, while decreased with increasing KE when KE was less than 105 J m-2 h-1. A KE of 105 J m-2 h-1 appeared to be a threshold level beyond which the disintegration of aggregates was severe and the influence of KE on erosion processes and sediment sorting may change. Results of this study demonstrate the need for considering KE-influenced sediment transport when predicting erosion.

  4. Determination of soil erosion risk in the Mustafakemalpasa River Basin, Turkey, using the revised universal soil loss equation, geographic information system, and remote sensing.

    PubMed

    Ozsoy, Gokhan; Aksoy, Ertugrul; Dirim, M Sabri; Tumsavas, Zeynal

    2012-10-01

    Sediment transport from steep slopes and agricultural lands into the Uluabat Lake (a RAMSAR site) by the Mustafakemalpasa (MKP) River is a serious problem within the river basin. Predictive erosion models are useful tools for evaluating soil erosion and establishing soil erosion management plans. The Revised Universal Soil Loss Equation (RUSLE) function is a commonly used erosion model for this purpose in Turkey and the rest of the world. This research integrates the RUSLE within a geographic information system environment to investigate the spatial distribution of annual soil loss potential in the MKP River Basin. The rainfall erosivity factor was developed from local annual precipitation data using a modified Fournier index: The topographic factor was developed from a digital elevation model; the K factor was determined from a combination of the soil map and the geological map; and the land cover factor was generated from Landsat-7 Enhanced Thematic Mapper (ETM) images. According to the model, the total soil loss potential of the MKP River Basin from erosion by water was 11,296,063 Mg year(-1) with an average soil loss of 11.2 Mg year(-1). The RUSLE produces only local erosion values and cannot be used to estimate the sediment yield for a watershed. To estimate the sediment yield, sediment-delivery ratio equations were used and compared with the sediment-monitoring reports of the Dolluk stream gauging station on the MKP River, which collected data for >41 years (1964-2005). This station observes the overall efficiency of the sediment yield coming from the Orhaneli and Emet Rivers. The measured sediment in the Emet and Orhaneli sub-basins is 1,082,010 Mg year(-1) and was estimated to be 1,640,947 Mg year(-1) for the same two sub-basins. The measured sediment yield of the gauge station is 127.6 Mg km(-2) year(-1) but was estimated to be 170.2 Mg km(-2) year(-1). The close match between the sediment amounts estimated using the RUSLE-geographic information system (GIS) combination and the measured values from the Dolluk sediment gauge station shows that the potential soil erosion risk of the MKP River Basin can be estimated correctly and reliably using the RUSLE function generated in a GIS environment.

  5. How To Live with Phosphorus Scarcity in Soil and Sediment: Lessons from Bacteria

    PubMed Central

    Tapia-Torres, Yunuen; Rodríguez-Torres, Maria Dolores; Islas, Africa; Souza, Valeria; García-Oliva, Felipe

    2016-01-01

    ABSTRACT Phosphorus (P) plays a fundamental role in the physiology and biochemistry of all living things. Recent evidence indicates that organisms in the oceans can break down and use P forms in different oxidation states (e.g., +5, +3, +1, and −3); however, information is lacking for organisms from soil and sediment. The Cuatro Ciénegas Basin (CCB), Mexico, is an oligotrophic ecosystem with acute P limitation, providing a great opportunity to assess the various strategies that bacteria from soil and sediment use to obtain P. We measured the activities in sediment and soil of different exoenzymes involved in P recycling and evaluated 1,163 bacterial isolates (mainly Bacillus spp.) for their ability to use six different P substrates. DNA turned out to be a preferred substrate, comparable to a more bioavailable P source, potassium phosphate. Phosphodiesterase activity, required for DNA degradation, was observed consistently in the sampled-soil and sediment communities. A capability to use phosphite (PO33−) and calcium phosphate was observed mainly in sediment isolates. Phosphonates were used at a lower frequency by both soil and sediment isolates, and phosphonatase activity was detected only in soil communities. Our results revealed that soil and sediment bacteria are able to break down and use P forms in different oxidation states and contribute to ecosystem P cycling. Different strategies for P utilization were distributed between and within the different taxonomic lineages analyzed, suggesting a dynamic movement of P utilization traits among bacteria in microbial communities. IMPORTANCE Phosphorus (P) is an essential element for life found in molecules, such as DNA, cell walls, and in molecules for energy transfer, such as ATP. The Valley of Cuatro Ciénegas, Coahuila (Mexico), is a unique desert characterized by an extreme limitation of P and a great diversity of microbial life. How do bacteria in this valley manage to obtain P? We measured the availability of P and the enzymatic activity associated with P release in soil and sediment. Our results revealed that soil and sediment bacteria can break down and use P forms in different oxidation states and contribute to ecosystem P cycling. Even genetically related bacterial isolates exhibited different preferences for molecules, such as DNA, calcium phosphate, phosphite, and phosphonates, as substrates to obtain P, evidencing a distribution of roles for P utilization and suggesting a dynamic movement of P utilization traits among bacteria in microbial communities. PMID:27235437

  6. How To Live with Phosphorus Scarcity in Soil and Sediment: Lessons from Bacteria.

    PubMed

    Tapia-Torres, Yunuen; Rodríguez-Torres, Maria Dolores; Elser, James J; Islas, Africa; Souza, Valeria; García-Oliva, Felipe; Olmedo-Álvarez, Gabriela

    2016-08-01

    Phosphorus (P) plays a fundamental role in the physiology and biochemistry of all living things. Recent evidence indicates that organisms in the oceans can break down and use P forms in different oxidation states (e.g., +5, +3, +1, and -3); however, information is lacking for organisms from soil and sediment. The Cuatro Ciénegas Basin (CCB), Mexico, is an oligotrophic ecosystem with acute P limitation, providing a great opportunity to assess the various strategies that bacteria from soil and sediment use to obtain P. We measured the activities in sediment and soil of different exoenzymes involved in P recycling and evaluated 1,163 bacterial isolates (mainly Bacillus spp.) for their ability to use six different P substrates. DNA turned out to be a preferred substrate, comparable to a more bioavailable P source, potassium phosphate. Phosphodiesterase activity, required for DNA degradation, was observed consistently in the sampled-soil and sediment communities. A capability to use phosphite (PO3 (3-)) and calcium phosphate was observed mainly in sediment isolates. Phosphonates were used at a lower frequency by both soil and sediment isolates, and phosphonatase activity was detected only in soil communities. Our results revealed that soil and sediment bacteria are able to break down and use P forms in different oxidation states and contribute to ecosystem P cycling. Different strategies for P utilization were distributed between and within the different taxonomic lineages analyzed, suggesting a dynamic movement of P utilization traits among bacteria in microbial communities. Phosphorus (P) is an essential element for life found in molecules, such as DNA, cell walls, and in molecules for energy transfer, such as ATP. The Valley of Cuatro Ciénegas, Coahuila (Mexico), is a unique desert characterized by an extreme limitation of P and a great diversity of microbial life. How do bacteria in this valley manage to obtain P? We measured the availability of P and the enzymatic activity associated with P release in soil and sediment. Our results revealed that soil and sediment bacteria can break down and use P forms in different oxidation states and contribute to ecosystem P cycling. Even genetically related bacterial isolates exhibited different preferences for molecules, such as DNA, calcium phosphate, phosphite, and phosphonates, as substrates to obtain P, evidencing a distribution of roles for P utilization and suggesting a dynamic movement of P utilization traits among bacteria in microbial communities. Copyright © 2016, American Society for Microbiology. All Rights Reserved.

  7. Superfund record of decision (EPA Region 4): Alabama Army Ammunition Plant, Area B soils operable unit, Childersburg, AL, November 14, 1995

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    NONE

    1996-03-01

    This decision document presents the selected remedial action for the contaminated soils and sediments in Study Areas, 6, 7, and 21, and the Industrial Sewer System (ISS) in Study Areas 6, 7, and 10 within Area B at the Alabama Army Ammunition Plant (ALAAP), Childersburg, Alabama. The Area B Soils Operable Unit addresses the principal threats from soils and sediments in Study Areas 6, 7, and 21, and underground industrial sewer lines in Study Areas 6, 7, and 10. The soils and sediments and the industrial sewer lines are contaminated with explosives and lead.

  8. Multivariate analysis of heavy metal contents in soils, sediments and water in the region of Meknes (central Morocco).

    PubMed

    Tahri, M; Benyaïch, F; Bounakhla, M; Bilal, E; Gruffat, J J; Moutte, J; Garcia, D

    2005-03-01

    Concentrations of Al, Fe, Cr, Cu, Ni, Pb and Zn in soils, sediments and water samples collected along the Oued Boufekrane river (Meknes, central Morocco) were determined. In soils, a homogeneous distribution of metal concentrations was observed throughout the study area except for Pb, which presents high enrichment at sites located at the vicinity of a main highway. In sediments, high enrichment, with respect to upstream sites, were observed downstream of the city of Meknes for Al, Cr, Fe and Ni and inside the city for Cu, Zn and Pb. In water samples, the metal contents showed to correlate with their homologues in sediments suggesting that the metal contents in water and sediments have identical origins. Descriptive statistics and multivariate analysis (principal factor method, PFM) were used to assist the interpretation of elemental data. This allowed the determination of the correlations between the metals and the identification of three main factor loadings controlling the metal variability in soils and sediments.

  9. Runoff and sediment variation in the areas with high and coarse sediment yield of the middle Yellow River

    NASA Astrophysics Data System (ADS)

    Zhang, Pan; Yao, Wenyi; Xiao, Peiqing; Sun, Weiying

    2018-02-01

    Massive water and soil conservation works (WSCW) have been conducted in the areas with high and coarse sediment yield of the middle Yellow River since 1982. With the impending effects of climate change, it is necessary to reconsider the effects of WSCW on runoff and sediment variation at decadal and regional scales. Using long-term official and synthesized data, the WSCW impacts on reducing water and soil loss were studied in Sanchuanhe River watershed. Results showed that the sediment and runoff generated from this area showed a decreasing trend in the past 50 years. A great progress has been achieved in erosion control since the 1970s. After the 4 soil and water conservation harnessing stages during the period from 1970 to 2006, the sediment and runoff yield showed decreases with the extension of harnessing. The results revealed that human activities exerted the largest effects on the sediment reduction and explained 66.6% of the variation in the specific sediment yield. The contribution of rainfall variation to runoff reduction was as large as human activities. A great benefit have been obtained in water and soil loss control in this area.

  10. 16S rRNA Gene Survey of Microbial Communities in Winogradsky Columns

    PubMed Central

    Rundell, Ethan A.; Banta, Lois M.; Ward, Doyle V.; Watts, Corey D.; Birren, Bruce; Esteban, David J.

    2014-01-01

    A Winogradsky column is a clear glass or plastic column filled with enriched sediment. Over time, microbial communities in the sediment grow in a stratified ecosystem with an oxic top layer and anoxic sub-surface layers. Winogradsky columns have been used extensively to demonstrate microbial nutrient cycling and metabolic diversity in undergraduate microbiology labs. In this study, we used high-throughput 16s rRNA gene sequencing to investigate the microbial diversity of Winogradsky columns. Specifically, we tested the impact of sediment source, supplemental cellulose source, and depth within the column, on microbial community structure. We found that the Winogradsky columns were highly diverse communities but are dominated by three phyla: Proteobacteria, Bacteroidetes, and Firmicutes. The community is structured by a founding population dependent on the source of sediment used to prepare the columns and is differentiated by depth within the column. Numerous biomarkers were identified distinguishing sample depth, including Cyanobacteria, Alphaproteobacteria, and Betaproteobacteria as biomarkers of the soil-water interface, and Clostridia as a biomarker of the deepest depth. Supplemental cellulose source impacted community structure but less strongly than depth and sediment source. In columns dominated by Firmicutes, the family Peptococcaceae was the most abundant sulfate reducer, while in columns abundant in Proteobacteria, several Deltaproteobacteria families, including Desulfobacteraceae, were found, showing that different taxonomic groups carry out sulfur cycling in different columns. This study brings this historical method for enrichment culture of chemolithotrophs and other soil bacteria into the modern era of microbiology and demonstrates the potential of the Winogradsky column as a model system for investigating the effect of environmental variables on soil microbial communities. PMID:25101630

  11. Review of chemical and electrokinetic remediation of PCBs contaminated soils and sediments.

    PubMed

    Fan, Guangping; Wang, Yu; Fang, Guodong; Zhu, Xiangdong; Zhou, Dongmei

    2016-09-14

    Polychlorinated biphenyls (PCBs) are manmade organic compounds, and pollution due to PCBs has been a global environmental problem because of their persistence, long-range atmospheric transport and bioaccumulation. Many physical, chemical and biological technologies have been utilized to remediate PCBs contaminated soils and sediments, and there are some emerging new technologies and combined methods that may provide cost-effective alternatives to the existing remediation practice. This review provides a general overview on the recent developments in chemical treatment and electrokinetic remediation (EK) technologies related to PCBs remediation. In particular, four technologies including photocatalytic degradation of PCBs combined with soil washing, Fe-based reductive dechlorination, advanced oxidation process, and EK/integrated EK technology (e.g., EK coupled with chemical oxidation, nanotechnology and bioremediation) are reviewed in detail. We focus on the fundamental principles and governing factors of chemical technologies, and EK/integrated EK technologies. Comparative analysis of these technologies including their major advantages and disadvantages is summarized. The existing problems and future prospects of these technologies regarding PCBs remediation are further highlighted.

  12. Facing the scaling problem: A multi-methodical approach to simulate soil erosion at hillslope and catchment scale

    NASA Astrophysics Data System (ADS)

    Schmengler, A. C.; Vlek, P. L. G.

    2012-04-01

    Modelling soil erosion requires a holistic understanding of the sediment dynamics in a complex environment. As most erosion models are scale-dependent and their parameterization is spatially limited, their application often requires special care, particularly in data-scarce environments. This study presents a hierarchical approach to overcome the limitations of a single model by using various quantitative methods and soil erosion models to cope with the issues of scale. At hillslope scale, the physically-based Water Erosion Prediction Project (WEPP)-model is used to simulate soil loss and deposition processes. Model simulations of soil loss vary between 5 to 50 t ha-1 yr-1 dependent on the spatial location on the hillslope and have only limited correspondence with the results of the 137Cs technique. These differences in absolute soil loss values could be either due to internal shortcomings of each approach or to external scale-related uncertainties. Pedo-geomorphological soil investigations along a catena confirm that estimations by the 137Cs technique are more appropriate in reflecting both the spatial extent and magnitude of soil erosion at hillslope scale. In order to account for sediment dynamics at a larger scale, the spatially-distributed WaTEM/SEDEM model is used to simulate soil erosion at catchment scale and to predict sediment delivery rates into a small water reservoir. Predicted sediment yield rates are compared with results gained from a bathymetric survey and sediment core analysis. Results show that specific sediment rates of 0.6 t ha-1 yr-1 by the model are in close agreement with observed sediment yield calculated from stratigraphical changes and downcore variations in 137Cs concentrations. Sediment erosion rates averaged over the entire catchment of 1 to 2 t ha-1 yr-1 are significantly lower than results obtained at hillslope scale confirming an inverse correlation between the magnitude of erosion rates and the spatial scale of the model. The study has shown that the use of multiple methods facilitates the calibration and validation of models and might provide a more accurate measure for soil erosion rates in ungauged catchments. Moreover, the approach could be used to identify the most appropriate working and operational scales for soil erosion modelling.

  13. 77 FR 14717 - National Oil and Hazardous Substances Pollution Contingency Plan; National Priorities List...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-03-13

    ... preclude future actions under Superfund. This partial deletion pertains to the surface soil, unsaturated subsurface soil, surface water and sediments of Operable Unit (OU) 1, the Gateway Lake Ash Study Area, and.... Surface soil, unsaturated subsurface soil, surface water, and sediments at OU-2, OU-3, OU-4, OU-5, OU-6...

  14. Sediment Fingerprinting Using Carbon and Nitrogen Stable Isotopes in the Upper Palouse Watershed, Northwestern Idaho

    NASA Astrophysics Data System (ADS)

    Fox, J. F.; Papanicolaou, A. T.

    2003-12-01

    Unwarranted soil erosion creates detrimental problems for watershed users and for habitats and human infrastructure that experience increased suspended sediment in surface water. Identification and mitigation of erosion prone uplands relies on the realization that land uses (i.e. agriculture, forest, industrial, pasture, etc.) "produce sediment differently" at the watershed scale. Quantification of sediment production from various land uses is deemed feasible by using sediment-particle fingerprinting. This technique utilizes vegetative derived carbon (C) and nitrogen (N) stable isotopes and the carbon/nitrogen (C/N) atomic ratio of sediments to identify sediment producing land uses. Past research has established differences between C and N isotopic signatures and C/N ratios for soils under forest vs. agriculture (i.e. grasses and wheat) land cover. The current research rigorously examines these distinct signatures through isotopic analysis of field soils from the Palouse River Watershed of Northwestern Idaho preceded with statistical analyses to establish soil uniqueness. In addition, stream sediments are preliminarily analyzed to identify their origin with the goal of establishing a blueprint methodology for estimating sediment source and erosion rates within the watershed. Prior to field sampling of source soils, a statistical-experimental design was established with the intent to capture spatial and temporal variations and random errors of C and N isotopic signatures and C/N ratios within the forest and agriculture land uses. Factors including, elevation, slope topography, and season, were assessed by excavating over 300 samples during 4 seasons (i.e. May 2002, August 2002, November 2002, and March 2003) and at numerous locations throughout the watershed. Atomic analyses was performed at the University of Idaho Natural Resources Stable Isotope Laboratory using a Costech 4010 Elemental Combustion System connected with a continuous flow inlet system to the Finnigan MAT Delta Plus isotope ratio mass spectrometer. The statistical analysis of variance (ANOVA) with C and N isotopic signatures and C/N ratios as three independent response variables was administered to identify the agriculture and forested uniqueness, and discriminant analysis was used to create an organic fingerprint parameter which weights the contribution of C and N isotopic signatures and C/N ratios to the land cover separation. Results indicate uniqueness of the N isotope C/N ratio for the forest and agriculture sediment sources and little distinction possible for the C isotope signature. The organic fingerprint parameter was then calculated and coupled with in-stream sediment isotopic data using a simple end-member model. Preliminary results indicate that C and N isotopic signatures and C/N ratios will serve as a useful technique in quantifying erosive source rates and understanding upland erosion processes.

  15. Transport of Hexabromocyclododecane (HBCD) into the soil, water and sediment from a large producer in China.

    PubMed

    Zhang, Yueqing; Lu, Yonglong; Wang, Pei; Li, Qifeng; Zhang, Meng; Johnson, Andrew C

    2018-01-01

    Hexabromocyclododecane (HBCD) is used as a flame retardant with extensive industrial applications, which is mainly produced at facilities on the coast of China. Radially distributed soil samples and equidistant paired water and sediment samples were taken around one of the biggest HBCD production enterprises to reflect its environmental behavior via air deposition and wastewater discharge of HBCD diastereoisomers (α-, β- and γ-HBCD). Worldwide high concentrations of HBCD (11,700ng/g in the soil, 5080ng/L in the water and 6740ng/g in the sediment) were detected in these environmental samples. Concentrations dropped by two orders of magnitude over several kilometers distance from the plant. The diastereoisomer pattern varied in the three environmental compartments examined, such that γ-HBCD was the predominant diastereoisomer in the soil and sediment whilst α- and γ-HBCD shared the predominance in the water. The mass inventories of HBCD in the local soil and sediment were estimated to be 5006kg and 30kg respectively, suggesting that soil was the major sink of HBCD in the production area. As for the soil, the environmental burdens in the areas with radiuses of 2, 4 and 6km were 3210, 3770 and 4590kg respectively. Copyright © 2017 Elsevier B.V. All rights reserved.

  16. Laboratory measurements of upwelled radiance and reflectance spectra of Calvert, Ball, Jordan, and Feldspar soil sediments

    NASA Technical Reports Server (NTRS)

    Whitlock, C. H.; Usry, J. W.; Witte, W. G.; Gurganus, E. A.

    1977-01-01

    An effort to investigate the potential of remote sensing for monitoring nonpoint source pollution was conducted. Spectral reflectance characteristics for four types of soil sediments were measured for mixture concentrations between 4 and 173 ppm. For measurements at a spectral resolution of 32 mm, the spectral reflectances of Calvert, Ball, Jordan, and Feldspar soil sediments were distinctly different over the wavelength range from 400 to 980 nm at each concentration tested. At high concentrations, spectral differences between the various sediments could be detected by measurements with a spectral resolution of 160 nm. At a low concentration, only small differences were observed between the various sediments when measurements were made with 160 nm spectral resolution. Radiance levels generally varied in a nonlinear manner with sediment concentration; linearity occurred in special cases, depending on sediment type, concentration range, and wavelength.

  17. Quantitative enzyme-linked immunosorbent assay for determination of polychlorinated biphenyls in environmental soil and sediment samples.

    PubMed

    Johnson, J C; Van Emon, J M

    1996-01-01

    An enzyme-linked immunosorbent assay (ELISA) for the quantitative determination of Aroclors 1242, 1248, 1254, and 1260 in soil and sediments was developed and its performance compared with that of gas chromatography (GC). The detection limits for Aroclors 1242 and 1248 in soil are 10.5 and 9 ng/g, respectively. The assay linear dynamic range is 50-1333 ng/g. Cross-reactivity of the assay with 37 structurally related potential cocontaminants in environmental soil samples was examined; none of the chlorinated anisoles, benzenes, or phenols exhibited >3% cross-reactivity, with <0.1% cross-reactivity being the norm. Soil spike recoveries of 107% and 104% were obtained for Aroclors 1242 and 1248, respectively, for a spike level of 5 mg/kg, with corresponding relative standard deviations of 14% and 17%. One hundred forty-eight environmental soil, sediment, and paper pulp samples, obtained from two EPA listed Superfund sites, were analyzed by ELISA and standard GC methods. Samples were extracted for ELISA analysis by shaking with methanol. Additional extractions of the same samples were performed either with supercritical carbon dioxide or by Soxhlet extraction with methanol. ELISA results for both the supercritical fluid and the Soxhlet extracts were in close agreement with the GC results, while the ELISA results for the methanol shake extracts were not. The data for the environmental samples demonstrated the capability of the ELISA to provide accurate results and reinforced the dependence of any detection method, including ELISA, on appropriate extraction procedures.

  18. [Spatial Distribution and Potential Ecological Risk Assessment of Heavy Metals in Soils and Sediments in Shunde Waterway, Southern China].

    PubMed

    Cai, Yi-min; Chen, Wei-ping; Peng, Chi; Wang, Tie-yu; Xiao, Rong-bo

    2016-05-15

    Environmental quality of soils and sediments around water source area can influence the safety of potable water of rivers. In order to study the pollution characteristics, the sources and ecological risks of heavy metals Zn, Cr, Pb, Cu, Ni and Cd in water source area, surface soils around the waterway and sediments in the estuary of main tributaries were collected in Shunde, and ecological risks of heavy metals were assessed by two methods of potential ecological risk assessment. The mean contents of Zn, Cr, Pb, Cu, Ni and Cd in the surface soils were 186.80, 65.88, 54.56, 32.47, 22.65 and 0.86 mg · kg⁻¹ respectively, and they were higher than their soil background values except those of Cu and Ni. The mean concentrations of Zn, Cr, Pb, Cu, Ni and Cd in the sediments were 312.11, 111.41, 97.87, 92.32, 29.89 and 1.72 mg · kg⁻¹ respectively, and they were higher than their soil background values except that of Ni. The results of principal component analysis illustrated that the main source of Cr and Ni in soils was soil parent materials, and Zn, Pb, Cu and Cd in soils mainly came from wastewater discharge of local manufacturing industry. The six heavy metals in sediments mainly originated from industry emissions around the Shunde waterway. The results of potential ecological risk assessment integrating environmental bioavailability of heavy metals showed that Zn, Cu, Pb and Ni had a slight potential ecological risk. Cd had a slight potential ecological risk in surface soils, but a moderate potential ecological risk in surfaces sediments. Because the potential ecological risk assessment integrating environmental bioavailability of heavy metals took the soil properties and heavy metal forms into account, its results of risks were lower than those of Hakanson methods, and it could avoid overestimating the potential risks of heavy metals.

  19. The potential of carbon and nitrogen isotopes to conservatively discriminate between subsoil sediment sources

    NASA Astrophysics Data System (ADS)

    Laceby, J. Patrick; Olley, Jon

    2013-04-01

    Moreton Bay, in South East Queensland, Australia, is a Ramsar wetland of international significance. A decline of the bay's ecosystem health has been primarily attributed to sediments and nutrients from catchment sources. Sediment budgets for three catchments indicated gully erosion dominates the supply of sediment in Knapp Creek and the Upper Bremer River whereas erosion from cultivated soils is the primary sediment source in Blackfellow Creek. Sediment tracing with fallout-radionuclides confirmed subsoil erosion processes dominate the supply of sediment in Knapp Creek and the Upper Bremer River whereas in Blackfellow Creek cultivated and subsoil sources contribute >90% of sediments. Other sediment properties are required to determine the relative sediment contributions of channel bank, gully and cultivated sources in these catchments. The potential of total organic carbon (TOC), total nitrogen (TN), and carbon and nitrogen stable isotopes (δ13C, δ15N) to conservatively discriminate between subsoil sediment sources is presented. The conservativeness of these sediment properties was examined through evaluating particle size variations in depth core soil samples and investigating whether they remain constant in source soils over two sampling occasions. Varying conservative behavior and source discrimination was observed. TN in the

  20. Identification of Critical Erosion Prone Areas and Computation of Sediment Yield Using Remote Sensing and GIS: A Case Study on Sarada River Basin

    NASA Astrophysics Data System (ADS)

    Sundara Kumar, P.; Venkata Praveen, T.; Anjanaya Prasad, M.; Santha Rao, P.

    2018-06-01

    The two most important resources blessed by nature to the mankind are land and water. Undoubtedly, these gifts have to be conserved and maintained with unflinching efforts from every one of us for an effective environmental and ecological balance. The efforts and energy of water resources engineers and conservationists are going in this direction to conserve these precious resources of nature. The present study is an attempt to develop suitable methodology to facilitate decision makers to conserve the resources and also reflects the cause mentioned above has been presented here. The main focus of this study is to identify the critical prone areas for soil erosion and computation of sediment yield in a small basin using Universal Soil Loss Equation and Modified Universal Soil Loss Equation (MUSLE) respectively. The developed model has been applied on Sarada river basin which has a drainage area of 1252.99 km2. This river is located in Andhra Pradesh State (AP), India. The basin has been divided into micro basins for effective estimation and also for precise identification of the areas that are prone to soil erosion. Remote Sensing and Geographic Information Systems tools were used to generate and spatially organize the data that is required for soil erosion modeling. It was found that the micro basins with very severe soil erosion are consisting of hilly areas with high topographic factor and 38.01% of the study area has the rate erosion more than 20 t/ha/year and hence requires an immediate attention from the soil conservation point of view. In this study region, though there is one discharge measuring gauge station available at Anakapalli but there is no sediment yield gauging means available to compute the sediment yield. Therefore, to arrive at the suspended-sediment concentration was a challenge task. In the present study the sediment measurement has been carried out with an instrument (DH-48), sediment sampling equipment as per IS: 4890-1968, has been used. Suspended-sediment samples were collected and sediment yield was arrived at the site by using this instrument. The sediment yield was also computed using MUSLE. Data for this model study has been generated from the samples collected from 28 storm events spread over a time span of 1 year, at the outlet of the basin at Anakapalli for computation of sediment yield. The sediment yield as estimated by MUSLE model has been successfully compared with the sediment yield measured at the outlet of the basin by sediment yield measuring unit and found fairly good correlation between them. Hence the developed methodology will be useful to estimate the sediment yield in the hydrologically similar basins that are not gauged for sediment yield.

  1. Superfund Record of Decision (EPA Region 3): Metal Banks, Philadelphia, PA, December 31, 1997

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    NONE

    1998-09-01

    This Record of Decision (ROD) presents the final remedial action selected for the Metal Bank Superfund Site (Site), located in northeastern Philadelphia, Pennsylvania. The remedy addresses contaminated soil, sediment, surface water, and groundwater at the Site and includes: installation of an oil collection system consisting of a sheet pile wall around the southern and western perimeter of the property; installation of temporary cofferdams prior to soil/sediment excavation to minimize transport of contamination into the Delaware River; excavation of contaminated soil within the Courtyard Area within two feet of the surface where polychlorinated biphenyl (PCB) concentrations exceed 10 ppm; disposal ofmore » contaminated soils and sediments that are hazardous; removal and disposal of the underground storage tank and its contents from the Southern Portion of the property; backfilling of excavated areas; posting signs prohibiting consumption of fish caught in the Delaware River in the vicinity of the Site; restrictions on the deed to the property to prevent future residential or agricultural use of the Site, use of the groundwater, and intrusive activities into the subsurface soils below the water table in the Southern Portion of the property; additional investigation to determine whether dense non-aqueous phase liquids (DNAPLs) are present at the Site and whether the storm sewer system in the vicinity of the Site is contaminated; and monitoring of groundwater, the Delaware River, and the Baxter Water intake.« less

  2. NNSS Soils Monitoring: Plutonium Valley (CAU 366) FY2013 and FY2014

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Miller, Julianne J.; Nikolich, George; Mizell, Steve

    The Desert Research Institute (DRI) is conducting a field assessment of the potential for contaminated soil transport from the Plutonium Valley Contamination Area (CA) as a result of wind transport and storm runoff in support of Nevada Nuclear Security Administration (NNSA) efforts to complete regulatory closure of the contamination areas. The DRI work is intended to confirm the likely mechanism(s) of transport and determine the meteorological conditions that might cause movement of contaminated soils. Emphasis is given to collecting sediment transported by channelized storm runoff at the Plutonium Valley investigation sites. These data will inform closure plans that are beingmore » developed, which will facilitate appropriate closure design and postclosure monitoring. Desert Research Institute installed two meteorological monitoring stations south (station number 1) and north (station number 2) of the Plutonium Valley CA and a runoff sediment sampling station within the CA in 2011. Temperature, wind speed, wind direction, relative humidity, precipitation, solar radiation, barometric pressure, soil temperature, and airborne particulate concentration are collected at both meteorological stations. The maximum, minimum, and average or total (as appropriate) for each of these parameters is recorded for each 10-minute interval. The sediment sampling station includes an automatically activated ISCO sampling pump with collection bottles for suspended sediment, which is activated when sufficient flow is present in the channel, and passive traps for bedload material that is transported down the channel during runoff events. This report presents data collected from these stations during FY2013 and FY2014.« less

  3. NNSS Soils Monitoring: Plutonium Valley (CAU 366) FY2015

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Nikolich, George; Mizell, Steve; McCurdy, Greg

    Desert Research Institute (DRI) is conducting a field assessment of the potential for contaminated soil transport from the Plutonium Valley Contamination Area (CA) as a result of wind transport and storm runoff in support of National Nuclear Security Administration (NNSA) efforts to complete regulatory closure of the contamination areas. The DRI work is intended to confirm the likely mechanism(s) of transport and determine the meteorological conditions that might cause movement of contaminated soils. The emphasis of the work is on collecting sediment transported by channelized storm runoff at the Plutonium Valley investigation sites. These data will inform closure plans thatmore » are being developed, which will facilitate the appropriate closure design and post-closure monitoring. In 2011, DRI installed two meteorological monitoring stations south (station #1) and north (station #2) of the Plutonium Valley CA and a runoff sediment sampling station within the CA. Temperature, wind speed, wind direction, relative humidity, precipitation, solar radiation, barometric pressure, soil temperature, and airborne particulate concentration are collected at both meteorological stations. The maximum, minimum, and average or total (as appropriate) for each of these parameters are recorded for each 10-minute interval. The sediment sampling station includes an automatically activated ISCO sampling pump with collection bottles for suspended sediment, which is activated when sufficient flow is present in the channel, and passive traps for bedload material that is transported down the channel during runoff events. This report presents data collected from these stations during fiscal year (FY) 2015.« less

  4. Results of analyses performed on soil adjacent to penetrators emplaced into sediments at McCook, Nebraska, January 1976. [simulated penetration into wind-deposited sediments on Martian plains

    NASA Technical Reports Server (NTRS)

    Blanchard, M.; Bunch, T.; Davis, A.; Kyte, F.; Shade, H.; Erlichman, J.; Polkowski, G.

    1977-01-01

    During 1976 several penetrators (full and 0.58 scale) were dropped into a test site McCook, Nebraska. The McCook site was selected because it simulated penetration into wind-deposited sediments (silts and sands) on Martian plains. The physical and chemical modifications found in the sediment after the penetrators' impact are described. Laboratory analyses have shown mineralogical and elemental changes are produced in the sediment next to the penetrator. Optical microscopy studies of material next to the skin of the penetrator revealed a layer of glassy material about 75 microns thick. Elemental analysis of a 0-1-mm layer of sediment next to the penetrator revealed increased concentrations for Cr, Fe, Ni, Mo, and reduced concentrations for Mg, Al Si, P, K, and Ca. The Cr, Fe, Ni, and Mo were in fragments abraded from the penetrator. Mineralogical changes occurring in the sediment next to the penetrator included the introduction of micron-size grains of alpha iron and several hydrated iron oxide minerals. The newly formed silicate minerals include metastable phases of silica (cristobalite, lechatelierite, and opal). The glassy material was mostly opal which formed when the host minerals (mica, calcite, and clay) decomposed. In summary, contaminants introduced by the penetrator occur up to 2 mm away from the penetrator's skin. Although volatile elements do migrate and new minerals are formed during the destruction of host minerals in the sediment, no changes were observed beyond the 2-mm distance. The analyses indicate 0.58-scale penetrators do effectively simulate full-scale testing for soil modification effects.

  5. Compositon of sediments transported by the wind at different heights

    NASA Astrophysics Data System (ADS)

    Iturri, Antonela; Funk, Roger; Leue, Martin; Sommer, Michael; Buschiazzo, Daniel

    2017-04-01

    Wind erosion (WE) is one of the most important degradation process of soils in arid- and semiarid environments in the world, affecting soil properties and adjacent ecosystems, including human health. Estimations about the amount of eroded soil are available in Argentina and in the world, but the quality of the eroded sediments, particularly the sorting effects in agricultural soils, has been scarcely studied. The trend of the different mineral and organic soil compounds, which enrich in different size classes, can define height distribution profiles. Therefore, the uppermost 2.5 cm of four agricultural loess soils that differ in granulometric composition were used for WE simulations in a wind tunnel. Particles with a diameter smaller than 10 µm (PM10) were collected with a laboratory dust generator. The bulk soil and all the sediment samples were characterized by the granulometric composition, the soil organic carbon (SOC) content and the mineral and organic functional groups. Despite different texture, the soils were subjected to similar sorting processes in height, but differed depending on their granulometry. There was a separation between coarser and finer soil particles in coarser textured soils, while finer textured soils were more homogeneous in all heights. This correlated with the preferential transport of Si-O from quartz and C-H, C=O and C-C from soil organic matter (SOM), which were transported in larger and/or denser particles at lower heights. O-H from clay minerals and C-O-C and C-O from polysaccharides, carbohydrates and derivatives from SOM were transported in higher heights. Despite similar SOC content in the bulk soils, both the amount and composition in the PM10 fractions was different. The SOC transported at higher heights was mostly composed of polysaccharides, carbohydrates and derivatives associated with clay minerals. The SOC in PM10 fractions of coarser-textured soils was dominated by labile C-H groups. According to the determined height distribution profiles, it can be deduced that WE may affect both soil quality and the soil C balance due to the sorting effects during transport.

  6. Trace metal occurrence and distribution in sediments and mangroves, Pumicestone region, southeast Queensland, Australia.

    PubMed

    Preda, Micaela; Cox, Malcolm E

    2002-11-01

    The Pumicestone region is a unique catchment in northern Moreton Bay, southeast Queensland. The region supports a wide range of land-use activities as well as attractions such as nature conservation areas. One environmental aspect that has not previously been addressed in this area is the occurrence of minor and trace metals in estuarine sediments associated with the main estuaries of the region. The trace metals included in this investigation are: vanadium, chromium, molybdenum, cobalt, nickel, copper, zinc, cadmium, lead and arsenic. To determine and evaluate the occurrence and distribution of metals in the area, several components have been analysed: bedrock material, pre-industrial settings, recent estuarine sediments, soils of estuarine origin and mangrove pneumatophores. The 40 sites chosen for sediment and soil samples cover a variety of estuarine settings and represent a range of natural conditions in terms of channel and bank morphology, tidal energy, vegetation cover, relationship to bedrock, water salinity and land disturbance. The chemical, mineralogical and statistical analyses employed in this study enabled (a) establishment of background values for the area, (b) determination of relationships between metals and (c) identification of sites with anomalous metal concentrations. All the metals found in the sediments of the area are sourced from the geological bedrock. The dominant trace elements identified in sediments are Zn, V and Cr. The remaining metals are highly variable spatially. All trace metals are controlled by the presence of Fe and Mn oxides, and by the grainsize of the sediment. Typically, fine-grained Fe-rich materials tend to adsorb more trace metals than sandy sediments. In soils that have developed from estuarine muds, some metals such as Cr, Mo, Pb and As tend to be in larger quantities than in the estuarine counterparts. Some of the elements, which occur in significant amounts in the sediment, have been detected in mangrove tissue (Avicenniamarina) such as V, Cr, Zn, Fe and Mn. Of particular note is Cu, which is present in mangrove tissue in quantities many times exceeding the sediment concentration. The comparative analysis of pre-industrial settings and recent sediments and soils highlighted some areas of metal enrichment such as acid-affected sites where oxidation of pyrite has mobilised metals from sediments; these metals are then redistributed in Fe-rich surficial layers. Disturbed banks within the estuaries are also likely to have low levels of metal enrichment due to boating activities.

  7. Biological soil crusts in deserts: A short review of their role in soil fertility, stabilization, and water relations

    USGS Publications Warehouse

    Belnap, Jayne

    2003-01-01

    Cyanobacteria and cyanolichens dominate most desert soil surfaces as the major component of biological soil crusts (BSC). BSCs contribute to soil fertility in many ways. BSC can increase weathering of parent materials by up to 100 times. Soil surface biota are often sticky, and help retain dust falling on the soil surface; this dust provides many plant-essential nutrients including N, P, K, Mg, Na, Mn, Cu, and Fe. BSCs also provide roughened soil surfaces that slow water runoff and aid in retaining seeds and organic matter. They provide inputs of newly-fixed carbon and nitrogen to soils. They are essential in stabilizing soil surfaces by linking soil particles together with filamentous sheaths, enabling soils to resist both water and wind erosion. These same sheaths are important in keeping soil nutrients from becoming bound into plant-unavailable forms. Experimental disturbances applied in US deserts show soil surface impacts decrease N and C inputs from soil biota by up to 100%. The ability to hold aeolian deposits in place is compromised, and underlying soils are exposed to erosion. While most undisturbed sites show little sediment production, disturbance by vehicles or livestock produces up to 36 times more sediment production, with soil movement initiated at wind velocities well below commonly-occurring wind speeds. Winds across disturbed areas can quickly remove this material from the soil surface, thereby potentially removing much of current and future soil fertility. Thus, reduction in the cover of cyanophytes in desert soils can both reduce fertility inputs and accelerate fertility losses.

  8. Riparian soil development linked to forest succession above and below dams along the Elwha River, Washington, USA

    USGS Publications Warehouse

    Perry, Laura G; Shafroth, Patrick B.; Perakis, Steven

    2017-01-01

    Riparian forest soils can be highly dynamic, due to frequent fluvial disturbance, erosion, and sediment deposition, but effects of dams on riparian soils are poorly understood. We examined soils along toposequences within three river segments located upstream, between, and downstream of two dams on the Elwha River to evaluate relationships between riparian soil development and forest age, succession, and channel proximity, explore dam effects on riparian soils, and provide a baseline for the largest dam removal in history. We found that older, later-successional forests and geomorphic surfaces contained soils with finer texture and greater depth to cobble, supporting greater forest floor mass, mineral soil nutrient levels, and cation exchange. Forest stand age was a better predictor than channel proximity for many soil characteristics, though elevation and distance from the channel were often also important, highlighting how complex interactions between fluvial disturbance, sediment deposition, and biotic retention regulate soil development in this ecosystem. Soils between the dams, and to a lesser extent below the lower dam, had finer textures and higher mineral soil carbon, nitrogen, and cation exchange than above the dams. These results suggested that decreased fluvial disturbance below the dams, due to reduced sediment supply and channel stabilization, accelerated soil development. In addition, reduced sediment supply below the dams may have decreased soil phosphorus. Soil δ15N suggested that salmon exclusion by the dams had no discernable effect on nitrogen inputs to upstream soils. Recent dam removal may alter riparian soils further, with ongoing implications for riparian ecosystems.

  9. Ecological site-based assessments of wind and water erosion: informing accelerated soil erosion management in rangelands

    USGS Publications Warehouse

    Webb, Nicholas P.; Herrick, Jeffrey E.; Duniway, Michael C.

    2014-01-01

    Accelerated soil erosion occurs when anthropogenic processes modify soil, vegetation or climatic conditions causing erosion rates at a location to exceed their natural variability. Identifying where and when accelerated erosion occurs is a critical first step toward its effective management. Here we explore how erosion assessments structured in the context of ecological sites (a land classification based on soils, landscape setting and ecological potential) and their vegetation states (plant assemblages that may change due to management) can inform systems for reducing accelerated soil erosion in rangelands. We evaluated aeolian horizontal sediment flux and fluvial sediment erosion rates for five ecological sites in southern New Mexico, USA, using monitoring data and rangeland-specific wind and water erosion models. Across the ecological sites, plots in shrub-encroached and shrub-dominated vegetation states were consistently susceptible to aeolian sediment flux and fluvial sediment erosion. Both processes were found to be highly variable for grassland and grass-succulent states across the ecological sites at the plot scale (0.25 Ha). We identify vegetation thresholds that define cover levels below which rapid (exponential) increases in aeolian sediment flux and fluvial sediment erosion occur across the ecological sites and vegetation states. Aeolian sediment flux and fluvial erosion in the study area can be effectively controlled when bare ground cover is 100 cm in length is less than ~35%. Land use and management activities that alter cover levels such that they cross thresholds, and/or drive vegetation state changes, may increase the susceptibility of areas to erosion. Land use impacts that are constrained within the range of natural variability should not result in accelerated soil erosion. Evaluating land condition against the erosion thresholds identified here will enable identification of areas susceptible to accelerated soil erosion and the development of practical management solutions.

  10. Natural attenuation of Fukushima-derived radiocesium in soils due to its vertical and lateral migration.

    PubMed

    Konoplev, A; Golosov, V; Wakiyama, Y; Takase, T; Yoschenko, V; Yoshihara, T; Parenyuk, O; Cresswell, A; Ivanov, M; Carradine, M; Nanba, K; Onda, Y

    2018-06-01

    Processes of vertical and lateral migration lead to gradual reduction in contamination of catchment soil, particularly its top layer. The reduction can be considered as natural attenuation. This, in turn, results in a gradual decrease of radiocesium activity concentrations in the surface runoff and river water, in both dissolved and particulate forms. The purpose of this research is to study the dynamics of Fukushima-derived radiocesium in undisturbed soils and floodplain deposits exposed to erosion and sedimentation during floods. Combined observations of radiocesium vertical distribution in soil and sediment deposition on artificial lawn-grass mats on the Niida River floodplain allowed us to estimate both annual mean sediment accumulation rates and maximum sedimentation rates corresponding to an extreme flood event during Tropical Storm Etau, 6-11 September 2015. Dose rates were reduced considerably for floodplain sections with high sedimentation because the top soil layer with high radionuclide contamination was eroded and/or buried under cleaner fresh sediments produced mostly due to bank erosion and sediments movements. Rate constants of natural attenuation on the sites of the Takase River and floodplain of Niida River was found to be in range 0.2-0.4 year -1 . For the site in the lower reach of the Niida River, collimated shield dose readings from soil surfaces slightly increased during the period of observation from February to July 2016. Generally, due to more precipitation, steeper slopes, higher temperatures and increased biological activities in soils, self-purification of radioactive contamination in Fukushima associated with vertical and lateral radionuclide migration is faster than in Chernobyl. In many cases, monitored natural attenuation along with appropriate restrictions seems to be optimal option for water remediation in Fukushima contaminated areas. Copyright © 2017. Published by Elsevier Ltd.

  11. Sediment and solute transport in a mountainous watershed in Valle del Cauca, Colombia

    NASA Astrophysics Data System (ADS)

    Guzman, C. D.; Castro, A.; Morales, A.; Hoyos, F.; Moreno, P.; Steenhuis, T. S.

    2014-12-01

    A main goal of this study was to improve prediction of sediment and solute transport using soil surface and soil nutrient changes, based on field measurements, within small watersheds receiving conservation measures. Sediment samples and solute concentrations were measured from two streams in the southwestern region of the Colombian Andes. Two modeling approaches for stream discharge and sediment transport predicted were used with one of these being used for nutrient transport prediction. These streams are a part of a recent initiative from a water fund established by Asobolo, Asocaña, and Cenicaña in collaboration with the Natural Capital Project to improve conservation efforts and monitor their effects. On-site soil depth changes, groundwater depth measurements, and soil nutrient concentrations were also monitored to provide more information about changes within this mountainous watershed during one part of the yearly rainy season. This information is being coupled closely with the outlet sediment concentration and solute concentration patterns to discern correlations. Lateral transects in the upper, middle, and lower part of the hillsides in the Aguaclara watershed of the Rio Bolo watershed network showed differences in soil nutrient status and soil surface depth changes. The model based on semi-distributed hydrology was able to reproduce discharge and sediment transport rates as well as the initially used model indicating available options for comparison of conservation changes in the future.

  12. Development of a Coupled Hydrological/Sediment Yield Model for a Watershed at Regional Level

    NASA Technical Reports Server (NTRS)

    Rajbhandaril, Narayan; Crosson, William; Tsegaye, Teferi; Coleman, Tommy; Liu, Yaping; Soman, Vishwas

    1998-01-01

    Development of a hydrologic model for the study of environmental conservation requires a comprehensive understanding of individual-storm affecting hydrologic and sedimentologic processes. The hydrologic models that we are currently coupling are the Simulator for Hydrology and Energy Exchange at the Land Surface (SHEELS) and the Distributed Runoff Model (DRUM). SHEELS runs continuously to estimate surface energy fluxes and sub-surface soil water fluxes, while DRUM operates during and following precipitation events to predict surface runoff and peak flow through channel routing. The lateral re-distribution of surface water determined by DRUM is passed to SHEELS, which then adjusts soil water contents throughout the profile. The model SHEELS is well documented in Smith et al. (1993) and Laymen and Crosson (1995). The model DRUM is well documented in Vieux et al. (1990) and Vieux and Gauer (1994). The coupled hydrologic model, SHEELS/DRUM, does not simulate sedimentologic processes. The simulation of the sedimentologic process is important for environmental conservation planning and management. Therefore, we attempted to develop a conceptual frame work for coupling a sediment yield model with SHEELS/DRUM to estimate individual-storm sediment yield from a watershed at a regional level. The sediment yield model that will be used for this study is the Universal Soil Loss Equation (USLE) with some modifications to enable the model to predict individual-storm sediment yield. The predicted sediment yield does not include wind erosion and erosion caused by irrigation and snow melt. Units used for this study are those given by Foster et al. (1981) for SI units.

  13. Contaminated Sediments at Navy Facilities: Cleanup Alternatives

    DTIC Science & Technology

    2002-12-01

    a factor of 300 to 500. Major sediment contaminants include: mercury , PCBs, dioxins, DDT, PAHs, and metals. These contaminants remain in the...destruction) • Phytoremediation (destruction/separation) Beneficial Use • Manufactured soil/fill (separation) • Cement (destruction... phytoremediation , $20 to $270 Disposal 3 • Commercial landfill, $30 to $300 • On-site landfill, $3 to $20 • CDF, $15 to $50 • CAD, more than $50 1

  14. Landscape planning for agricultural nonpoint source pollution reduction III: Assessing phosphorus and sediment reduction potential

    USGS Publications Warehouse

    Diebel, M.W.; Maxted, J.T.; Robertson, Dale M.; Han, S.; Vander Zanden, M. J.

    2009-01-01

    Riparian buffers have the potential to improve stream water quality in agricultural landscapes. This potential may vary in response to landscape characteristics such as soils, topography, land use, and human activities, including legacies of historical land management. We built a predictive model to estimate the sediment and phosphorus load reduction that should be achievable following the implementation of riparian buffers; then we estimated load reduction potential for a set of 1598 watersheds (average 54 km2) in Wisconsin. Our results indicate that land cover is generally the most important driver of constituent loads in Wisconsin streams, but its influence varies among pollutants and according to the scale at which it is measured. Physiographic (drainage density) variation also influenced sediment and phosphorus loads. The effect of historical land use on present-day channel erosion and variation in soil texture are the most important sources of phosphorus and sediment that riparian buffers cannot attenuate. However, in most watersheds, a large proportion (approximately 70%) of these pollutants can be eliminated from streams with buffers. Cumulative frequency distributions of load reduction potential indicate that targeting pollution reduction in the highest 10% of Wisconsin watersheds would reduce total phosphorus and sediment loads in the entire state by approximately 20%. These results support our approach of geographically targeting nonpoint source pollution reduction at multiple scales, including the watershed scale. ?? 2008 Springer Science+Business Media, LLC.

  15. Estimating the GIS-based soil loss and sediment delivery ratio to the sea for four major basins in South Korea.

    PubMed

    Lee, S E; Kang, S H

    2013-01-01

    This paper describes a sediment delivery ratio (SDR) using the Geographic Information System (GIS)-based Revised Universal Soil Loss Equation (RUSLE), to calculate the soil loss and sediment rating curve (SRC) basis of measured data in the six basins of Four Rivers, South Korea. The data set for calculating SDR was prepared during 3 years from 2008 to 2010. Mean soil loss in the six basins of Four Rivers was 515-869 t km(-2) yr(-1) and mean specific sediment yield (SSY) was 20-208 t km(-2) yr(-1) with basin size. The SDR ranged from 0.03 to 0.33 in the six rivers. Most sediment flows in the monsoon period from June to September (mean Max.: >97%; mean Min.: >84%), but SDR is lower than those of similar continental river basins. This is due to environmental factors, for example rainfall characteristics and associated run-off, soil characteristics and cultivated patterns with increasing basin size. This research provides the first application of SDR based on the observed field data in South Korea.

  16. Human induced prehistoric and historical soil erosion and landscape development in Southwestern USA

    NASA Astrophysics Data System (ADS)

    Dotterweich, Markus; Ivester, Andrew H.; Hanson, Paul R.; Daniel, Larsen; Dye, David H.; Foster, Thomas H., II

    2015-04-01

    The significance of soil erosion due to pre-historic land use and possible feedback mechanisms had been hardly recognized in the Southeastern USA. Here, the agricultural practices only began in the second half of the Holocene. Sedentary hunters and gatherers started to domesticate squash and sunflowers. Associated with the expansion of maize cultivation in the Mississippian period between AD 800 and 1100, significant forest clearings took place on the river floodplains. During this time, central settlements with up to 30,000 residences existed and the surrounding ridge and furrow fields extended to up to 30 ha. It is still open to question why these groups already declined in the 14/15th centuries already before the arrival of the Europeans. However, around AD 1540 the conquistador de Soto still reports extended fields with intensive cultivation of maize in the uplands of Northern Mississippi. Despite of this intensive land use by Native Americans, current research gives no indication that these activities had any significant impact on river channel form. Also, no clear evidence exists for distinct channel change occurring in response to any sort of middle Holocene Hypsithermal, Medieval warm period, or the Little Ice Age. We will present results of a project which aims to explore erosion forms, colluvial sediments and buried soils in selected 0-order and 1st-order watersheds in the southeastern USA in order to gain, solidify, and evaluate general data on soil erosion during the Native American land use period and its respective long-term effects on the environment. This will be achieved by 1) recording the stratigraphy of colluvial and alluvial sediments and buried soils, 2) mapping the extent of erosional and colluvial forms, 3) analyzing chemical and physical soil and sediment properties, 4) establishing chronological control using various dating techniques including radiocarbon and OSL dating, and 5) quantifying soil erosion using hillslope sediments. The gathered data will be used to i) compare the spatial extent of prehistoric and historic erosion and the short-term and long-term pedological and geomorphological effects of subtle soil erosion against extreme events, ii) assess the feedback-mechanisms of soil erosion on soil fertility and measurable land use changes in prehistorical and historical times, and (iii) estimate the long term effects of soil erosion and sediment deposition on archaeological features. The outcome will provide a decisive step forward to gather new qualitative and quantitative information on soil erosion during the Native American land use period to be able to achieve a better understanding of the long-term human induced landscape evolution in the uplands of the Southeastern USA and deliver data for a better predicting of landscape evolution to future climatic shifts in precipitation regimes.

  17. Verification and completion of a soil data base for process based erosion model applications in Mato Grosso/Brazil

    NASA Astrophysics Data System (ADS)

    Schindewolf, Marcus; Schultze, Nico; Schönke, Daniela; Amorim, Ricardo S. S.; Schmidt, Jürgen

    2014-05-01

    The study area of central Mato Grosso is subjected to severe soil erosion. Continuous erosion leads to massive losses of top soil and related organic carbon. Consequently agricultural soil soils suffer a drop in soil fertility which only can be balanced by mineral fertilization. In order to control soil degradation and organic carbon losses of Mato Grosso cropland soils a process based soil loss and deposition model is used. Applying the model it will be possible to: - identify the main areas affected by soil erosion or deposition in different scales under present and future climate and socio-economic conditions - estimate the related nutrient and organic carbon losses/yields - figure out site-related causes of soil mobilization/deposition - locate sediment and sediment related nutrient and organic matter pass over points into surface water bodies - estimate the impacts of climate and land use changes on the losses of top soil, sediment bound nutrients and organic carbon. Model input parameters include digital elevation data, precipitation characteristics and standard soil properties as particle size distribution, total organic carbon (TOC) and bulk density. The effects of different types of land use and agricultural management practices are accounted for by varying site-specific parameters predominantly related to soil surface properties such as erosional resistance, hydraulic roughness and percentage ground cover. In this context the existing EROSION 3D soil parameter data base deducted from large scale rainfall simulations in Germany is verified for application in the study area, using small scale disc type rainfall simulator with an additional runoff reflux approach. Thus it's possible to enlarge virtual plot length up to at least 10 m. Experimental plots are located in Cuiabá region of central Mato Grosso in order to cover the most relevant land use variants and tillage practices in the region. Results show that derived model parameters are highly influenced by soil management. This indicates a high importance of tillage impact on resistance to erosion, mulch cover and TOC. The measured parameter ranges can generally be confirmed by the existing data base, which only need to be completed due to changed phenological stages in Mato Grosso compared to German conditions.

  18. Novel sorbents for environmental remediation

    NASA Astrophysics Data System (ADS)

    Manariotis, Ioannis D.; Karapanagioti, Hrissi K.; Werner, David

    2014-05-01

    Nowadays, one of the major environmental problems is the pollution of aquatic systems and soil by persistent pollutants. Persistent pollutants have been found widespread in sediments, surface waters, and drinking water supplies. The removal of pollutants can be accomplished prior to their discharge to receiving bodies or by immobilizing them onto soil. Sorption is the most commonly applied process, and activated carbons have been widely used. Rapid progress in nanotechnology and a new focus on biomass-based instead of non-renewable starting materials have produced a wide range of novel engineered sorbents including biosorbents, biochars, carbon-based nanoparticles, bio-nano hybrid materials, and iron-impregnated activated carbons. Sorbent materials have been used in environmental remediation processes and especially in agricultural soil, sediments and contaminated soil, water treatment, and industrial wastewater treatment. Furthermore, sorbents may enhance the synergistic action of other processes, such as volatilization and biodegradation. Novel sorbents have been employed for the removal or immobilization of persistent pollutants such as and include heavy metals (As, Cr, Cu, Pb, Cd, and Hg), halogenated organic compounds, endocrine disrupting chemicals, metalloids and non-metallic elements, and other organic pollutants. The development and evaluation of novel sorbents requires a multidisciplinary approach encompassing environmental, nanotechnology, physical, analytical, and surface chemistry. The necessary evaluations encompass not only the efficiency of these materials to remove pollutants from surface waters and groundwater, industrial wastewater, polluted soils and sediments, etc., but also the potential side-effects of their environmental applications. The aim of this work is to present the results of the use of biochar and impregnated carbon sorbents for the removal of organic pollutants and metals. Furthermore, the new findings from the forthcoming session on Novel sorbents for environmental remediation, will also be evaluated and presented.

  19. The contribution of sediment from forested areas of the Chesapeake Bay Watershed

    NASA Astrophysics Data System (ADS)

    Gellis, A.; Brakebill, J.

    2012-12-01

    Fine-grained sediment is a major pollutant in the Chesapeake Bay and its receiving waters. Sediment budget studies have been conducted in small basins draining to the Bay over the last decade to understand the important sources of fine-grained sediment, quantify erosion rates, and determine sediment yields. Sediment budget approaches include modeling (SPARROW), sediment fingerprinting, and quantifying upland rates of erosion (Cesium-137). SPARROW model results indicate that forests deliver between 2 to 8% of the total sediment to the Bay. Sediment-fingerprinting results from small watershed studies indicate that forests contribute between 13 to 29 % of the sediment. The Cesium-137 technique was used to quantify soil redistribution (erosion and deposition) rates for forested areas in the Linganore Creek (146 km2) watershed which drains the Piedmont Physiographic Province. Average forest erosion rates measured in 2009 for Linganore Creek using Cesium-137 were 2.6 t/ha/yr. With 27% of the Linganore Creek watershed in forest, over 10,300 may be eroded off of forested lands which is more than the average annual suspended-sediment load (8,050 Mg/yr) in Linganore Creek, indicating that much of the eroded forest sediment goes in storage. Most of the forested areas in the Chesapeake Bay watershed were cut down for agriculture between the time of European colonization and the early 20th Century. In the late 20th century forested lands show an increase in areal extent. Although studies have not been conducted to understand why these secondary growth forests are eroding, it may involve that these forests have not fully recovered from deforestation. Soil profiles are thin, and runoff and sediment relations may have been altered, leading to high rates of erosion.

  20. Diploptene: an indicator of terrigenous organic carbon in Washington coastal sediments

    NASA Technical Reports Server (NTRS)

    Prahl, F. G.; Hayes, J. M.

    1992-01-01

    The pentacyclic triterpene 17 beta(H),21 beta(H)-hop-22(29)-ene (diploptene) occurs in sediments throughout the Columbia River drainage basin and off the southern coast of Washington state in concentrations comparable to long-chain plantwax n-alkanes. The same relationship is evident for diploptene and long-chain n-alkanes in soils from the Willamette Valley. Microorganisms indigenous to soils and soil erosion are indicated as the biological source and physical process, respectively, for diploptene in coastal sediments. Similarity between the stable carbon isotopic composition (delta 13CPDB) of diploptene isolated from soil in the Willamette Valley (-31.2 +/- 0.3%) and from sediments deposited throughout the Washington coastal environment (-31.2 +/- 0.5%) supports this argument. Values of delta for diploptene in river sediments are variable and 8-17% lighter, indicating that an additional biological source such as methane-oxidizing bacteria makes a significant contribution to the diploptene record in river sediments. Selective biodegradation resulting from a difference in the physicochemical association within eroded particles can explain the absence of the more-13C-depleted form of diploptene in Washington coastal sediments, but this mechanism remains unproven.

  1. Possible Exposure Pathways During Emergencies

    EPA Pesticide Factsheets

    There are three basic ways a person may be exposed to a hazardous substance: inhalation, ingestion, or direct contact. Points of contact include groundwater or surface water; soil, sediment, or dust; air; or food.

  2. Effects of climate change and wildfire on soil loss in the Southern Rockies Ecoregion

    Treesearch

    S. E. Litschert; D. M. Theobald; T. C. Brown

    2014-01-01

    Forests in the Southern Rockies Ecoregion surround the headwaters of several major rivers in the western and central US. Future climatic changes will increase the incidence of wildfire in those forests, and will likely lead to changes in downstream water quality, including sediment loads.We estimated soil loss under the historic climate and two IPCC climate change...

  3. 78 FR 42730 - Safety Zone; Old Mormon Slough, Stockton, CA

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-07-17

    ... Environmental Protection Agency to decontaminate soil, groundwater, and sediment in Old Mormon Slough and the... efforts of the EPA to rehabilitate soil, sediment, and ground water from contaminates of the McCormick... waste ponds were closed in 1981. Sampling has shown that soils throughout the site and groundwater in...

  4. What are the contemporary sources of sediment in the Mississippi River?

    NASA Astrophysics Data System (ADS)

    Hassan, M. A.; Roberge, L.; Church, M.; More, M.; Donner, S. D.; Leach, J.; Ali, K. F.

    2017-09-01

    Within the last two centuries, the Mississippi River basin has been transformed by changes in land use practices, dam construction, and training of the rivers for navigation. Here we analyze the contemporary patterns of fluvial sediment yield in the Mississippi River basin using all available data in order to assess the influence of regional land condition on the variation of sediment yield within the basin. We develop regional-scale relations between specific sediment yield (yield per unit area) and drainage area to reveal contemporary regional sediment yield patterns and source areas of riverine sediments. Extensive upland erosion before the development of soil conservation practices exported large amounts of sediment to the valleys and floodplains. We show that sediment today is sourced primarily along the river valleys from arable land, and from stream bank and channel erosion, with sediment yields from areas dominated by arable land 2 orders of magnitude greater than that of grassland dominated areas. Comparison with the "T factor," a commonly quoted measure of agricultural soil resilience suggests that the latter may not reflect contemporary soil loss from the landscape.

  5. Scale and processes dominating soil erosion and sediment transport: case studies from Indonesia and Australia

    NASA Astrophysics Data System (ADS)

    van Dijk, A. I. J. M.; Bruijnzeel, L. A.

    2009-04-01

    Soil erosion and sediment transport at different scales of space and time are dominated by a variable set of landscape properties and processes. Research results from West Java (Indonesia) and southeast Australia are presented, taking a natural resources management perspective. The dominant role of vegetation and soil health, rainfall infiltration, and connectivity between hillslope and stream are elaborated on. In humid volcanic upland West Java, vegetative cover and associated infiltration capacity are the dominant control on surface runoff and sediment generation, with additional variation attributed to slope and soil surface structure. Use of process models to replicate and upscale field measurements highlighted that a predictive theory to link vegetative cover and infiltration capacity is lacking, and that full knowledge of the covariance between terrain attributes that promote sediment generation is needed for process based modelling. At the hillslope to catchment scale, slope gradient and a less erodible substrate became additional constraints on sediment yield. A conceptual framework relating processes, scale and sediment delivery ratio was developed. In water-limited southeast Australia, measures to reduce erosion and sediment production generally aim to intercept surface runoff, allowing runoff to infiltrate and sediment to settle on vegetated buffer strips or roadsides or in leaky dams. It is illustrated how remote sensing can help to assess the sources of sediment and hydrological connectivity at different scales and to identify opportunities for mitigation.

  6. Distribution of Escherichia coli and Enterococci in water, sediments, and bank soils along North Shore Channel between Bridge Street and Wilson Avenue, Metropolitan Water Reclamation District of Greater Chicago

    USGS Publications Warehouse

    Byappanahalli, Muruleedhara; Whitman, Richard L.; Shively, Dawn; Przybyla-Kelly, Katarzyna; Lukasik, Ashley M.

    2010-01-01

    The Metropolitan Water Reclamation District of Greater Chicago (MWRDGC) wished to know the distribution and potential sources of fecal indicator bacteria, E. coli and enterococci, in water, sediments, and upland soils along an upstream and downstream portion of the North Shore Channel (NSC) that is the receiving stream for the District’s North Side Water Reclamation Plant (NSWRP) outfall. Biweekly water and sediment samples were collected between August and October 2008 and included the following locations upstream of the outfall: Bridge Street (UPS-1), Oakton Street (UPS-2), the NSWRP outfall (OF), and downstream: Foster Avenue (DNS-1), and Wilson Avenue (DNS-2). E. coli and enterococci were consistently found in water and sediments at all sampling locations, with bacterial densities in water increasing below the NSWRP outfall; bacterial densities in sediment were more variable. On a relative measurement basis (i.e., 100 ml=100 g), both E. coli and enterococci densities were significantly higher in sediments than water. E. coli and enterococci were consistently recovered from bank soil along wooded, grassy, erosional, and depositional areas at two recreational parks, as well as other riparian areas along the river. Thus, soils along the river basin are likely sources of these bacteria to the NSC channel, introduced through runoff or other physical processes. Tributaries, such as the North Branch of the Chicago River (NBCR) that flow into NSC near Albany Ave, may provide a constant source of E. coli and enterococci to the NSC. Additionally, storm sewer outfalls may increase E. coli loadings to NSC during wet weather conditions. Our findings suggest that the abundance of nonpoint sources contributing to the overall fecal indicator bacteria (FIB) load in the NSC channel may complicate bacteria source determination and remediation efforts to protect the stream water quality.

  7. A theoretical assessment of microplastic transport in river catchments and their retention by soils and river sediments.

    PubMed

    Nizzetto, Luca; Bussi, Gianbattista; Futter, Martyn N; Butterfield, Dan; Whitehead, Paul G

    2016-08-10

    The presence of microplastics (MPs) in the environment is a problem of growing concern. While research has focused on MP occurrence and impacts in the marine environment, very little is known about their release on land, storage in soils and sediments and transport by run-off and rivers. This study describes a first theoretical assessment of these processes. A mathematical model of catchment hydrology, soil erosion and sediment budgets was upgraded to enable description of MP fate. The Thames River in the UK was used as a case study. A general lack of data on MP emissions to soils and rivers and the mass of MPs in agricultural soils, limits the present work to serve as a purely theoretical, nevertheless rigorous, assessment that can be used to guide future monitoring and impact evaluations. The fundamental assumption on which modelling is based is that the same physical controls on soil erosion and natural sediment transport (for which model calibration and validation are possible), also control MP transport and storage. Depending on sub-catchment soil characteristics and precipitation patterns, approximately 16-38% of the heavier-than-water MPs hypothetically added to soils (e.g. through routine applications of sewage sludge) are predicted to be stored locally. In the stream, MPs < 0.2 mm are generally not retained, regardless of their density. Larger MPs with densities marginally higher than water can instead be retained in the sediment. It is, however, anticipated that high flow periods can remobilize this pool. Sediments of river sections experiencing low stream power are likely hotspots for deposition of MPs. Exposure and impact assessments should prioritize these environments.

  8. Assessment of environmentally persistent free radicals in soils and sediments from three Superfund sites.

    PubMed

    dela Cruz, Albert Leo N; Cook, Robert L; Dellinger, Barry; Lomnicki, Slawomir M; Donnelly, Kirby C; Kelley, Matthew A; Cosgriff, David

    2014-01-01

    We previously reported the presence of environmentally persistent free radicals (EPFRs) in pentachlorophenol (PCP) contaminated soils at a closed wood treatment facility site in Georgia. The reported EPFRs were pentachlorophenoxyl radicals formed on soils under ambient conditions via electron transfer from PCP to electron acceptors in the soil. In this study, we present results for soil and sediment samples from additional Superfund sites in Montana and Washington. Paramagnetic centers associated with different chemical environments were characterized by distinct g-factors and line widths (ΔHp-p). EPFR concentrations in contaminated samples were ~30×, ~12×, and ~2× higher than background samples at the Georgia, Montana, and Washington sites, respectively. EPR signals in the Montana contaminated soils were very similar to those previously observed for pentachlorophenol contaminated soils at the Georgia site, i.e., g = 2.00300 and ΔHp-p = 6.0 G, whereas signals in the Washington sediment samples were similar to those previously observed for other PAH contaminated soils, i.e., g = 2.00270 and ΔHp-p = 9.0 G. Total carbon content measurements exhibited direct correlation with EPFR concentration. The presence of radicals in sites contaminated a decade to a century ago suggests continuous formation of EPFRs from molecular contaminants in the soil and sediment.

  9. Assessment of Environmentally Persistent Free Radicals in Soils and Sediments from Three Superfund Sites

    PubMed Central

    dela Cruz, Albert Leo N.; Cook, Robert L.; Dellinger, Barry; Lomnicki, Slawomir M.; Donnelly, Kirby C.; Kelley, Matthew A.; Cosgriff, David

    2014-01-01

    We previously reported the presence of environmentally persistent free radicals (EPFRs) in pentachlorophenol (PCP) contaminated soils at a closed wood treatment facility site in Georgia. The reported EPFRs were pentachlorophenoxyl radicals formed on soils under ambient conditions via electron transfer from PCP to electron acceptors in the soil. In this study, we present results for soil and sediment samples from additional Superfund sites in Montana and Washington. Paramagnetic centers associated with different chemical environments were characterized by distinct g-factors and line widths (ΔHp-p). EPFR concentrations in contaminated samples were ~30x, ~12x, and ~2x higher than background samples at the Georgia, Montana, and Washington sites, respectively. EPR signals in the Montana contaminated soils were very similar to those previously observed for pentachlorophenol contaminated soils at the Georgia site, i.e., g = 2.00300 and ΔHp-p = 6.0 G, whereas signals in the Washington sediment samples were similar to those previously observed for other PAH contaminated soils, i.e., g = 2.00270 and ΔHp-p = 9.0G. Total carbon content measurements exhibited direct correlation with EPFR concentration. The presence of radicals in sites contaminated a decade to a century ago suggests continuous formation of EPFRs from molecular contaminants in the soil and sediment. PMID:24244947

  10. Sediment production from forest roads in western Oregon

    Treesearch

    Charlie Luce; Thomas A. Black

    1999-01-01

    Prevention and estimation of soil erosion from forest roads requires an understanding of how road design and maintenance affect sediment production. Seventy-four plots were installed on forest roads in the Oregon Coast Range to examine the relationship between sediment production and road attributes such as distance between culverts, road slope, soil texture,...

  11. Ideas and perspectives: why Holocene thermokarst sediments of the Yedoma region do not increase the northern peatland carbon pool

    NASA Astrophysics Data System (ADS)

    Hugelius, G.; Kuhry, P.; Tarnocai, C.

    2015-11-01

    Permafrost deposits in the Beringian Yedoma region store large amounts of organic carbon (OC). Walter Anthony et al. (2014) describe a previously unrecognized pool of 159 Pg OC accumulated in Holocene thermokarst sediments deposited in Yedoma region alases (thermokarst depressions). They claim that these alas sediments increase the previously recognized circumpolar permafrost peat OC pool by 50 %. It is stated that previous integrated studies of the permafrost OC pool have failed to account for these deposits because the Northern Circumpolar Soil Carbon Database (NCSCD) is biased towards non-alas field sites and that the soil maps used in the NCSCD underestimate coverage of organic permafrost soils. Here we evaluate these statements against a brief literature review, existing datasets on Yedoma region soil OC storage and independent field-based and geospatial datasets of peat soil distribution in the Siberian Yedoma region. Our findings are summarised in three main points. Firstly, the sediments described by Walter Anthony et al. are primarily mineral lake sediments and do not match widely used international scientific definitions of peat or organic soils. They can therefore not be considered an addition to the circumpolar peat carbon pool. Secondly, independent field data and geospatial analyses show that the Siberian Yedoma regions is dominated by mineral soils, not peatlands. Thus, there is no evidence to suggest any systematic bias in the NCSCD field data or maps. Thirdly, there is spatial overlap between these Holocene thermokarst sediments and previous estimates of permafrost soil and sediment OC stocks. These carbon stocks were already accounted for by previous studies and cannot be added to the permafrost OC count. We suggest that statements made in Walter Anthony et al. (2014) resulted from misunderstandings caused by conflicting definitions and terminologies across different geoscientific disciplines. A careful cross-disciplinary review of terminologies would help future studies to appropriately harmonize definitions between different fields.

  12. Iron oxides in eroded sediments from two representative catchments form South Spain: an example of its environmental implications

    NASA Astrophysics Data System (ADS)

    Diaz, I.; del Campillo, M. C.; Barrón, V.; Delgado, A.

    2012-04-01

    Iron (Fe) oxides accounts for one of the most important sorbent compounds in soil and sediments. Nutrients such as P and organic and inorganic pollutants can be retained in soils through its adsorption on these compounds. Particles of Fe oxides can act as a source of sorbed pollutants when these particles are eroded and transported into the bottom of lakes or water as a result of desorption of sorbed compounds or after reduction of Fe oxides under anaerobic conditions. The main target of this work was to study Fe oxides in sediments eroded from two representative catchments from South Spain and how the content and type of oxides in sediments can be affected by the soil properties. One catchment had an extension of 60 ha and soils were mainly classified as Vertisols, with 44-50 % clay in the upper horizon and pH ranging from 7.4 to 7.9. Soils in the other catchment, with an extension of 25 ha, were mainly Alfisols, with 6-33 % clay in the upper horizon and pH between 7.4 and 8.0. Phosphorus and Fe fractions in soil (18 and 10 sampling points in the Vertisol and Alfisols catchment, respectively) and sediments in runoff samples (taken during two consecutive agricultural years, 2000-2002) were studied by means of a sequential fractionation method involving extraction with: NaOH, citrate-bicarbonate (CB), citrate (C), citrate-ascorbate (CA), citrate-bicarbonate-dithionite (CBD), acetate, and HCl. Iron extraction involved sequential extraction with of CB, C, CA and CBD. The two formers step in the Fe fractionation dissolve the poorly crystalline and crystalline Fe oxides, respectively. The concentrations of all the Fe and P fractions were similar in sediments (sum of fractions were 11.5 g Fe/kg and 509 mg P/kg) and soil (sum of fractions were 10.5 g Fe/kg and 586 mg P/kg) from the Vertisol catchment. In this highly calcareous soil, the relevance of Fe oxides in the dynamics of applied P fertilizer was secondary when compared with the precipitation of poorly soluble Ca phosphates, as revealed by the significance of citrate extractable P. In the Alfisols catchment, however, the total free Fe (sum of fractions) was much higher in the sediments (19 g/kg) than in the soil (7.9 g/kg) which explains the increased amounts of P fractions related to oxides (NaOH, CB, CA, and CBD) in sediments (425 mg/kg) when compared with soils (183 mg/kg). Also, the ratio of CA to CBD extractable Fe was higher in sediments (0.22) than in soils (0.15). It can be concluded that in the Alfisol catchment, the content of sorbent surfaces sensitive to reductant conditions are increased in the sediments eroded when compared with soils, and thus, the potential release of pollutants (in this case P) adsorbed or occluded in them. In contrast, in the Vertisol catchment, where P dynamics is dominated by precipitation of Ca phosphates, these forms accounts for the dominant one in soils and sediments, without an increase in the proportion of sorbent surfaces or P forms sensitive to redox conditions.

  13. Autecological Study of the Chemoautotroph Nitrobacter by Immunofluorescence

    PubMed Central

    Fliermans, C. B.; Bohlool, B. B.; Schmidt, E. L.

    1974-01-01

    Fluorescent antibodies (FA) prepared for Nitrobacter agilis and N. winogradskyi were highly reactive in homologous staining. Low-level cross-reactions between the two species were removed by adsorption. All 15 pure-culture isolates of Nitrobacter tested reacted strongly with either N. agilis FA or N. winogradskyi FA. All pure-culture isolates from soils were determined to be N. winogradskyi; those from Mammoth Cave sediments and a cattle waste oxidation ditch were N. agilis. No cross-reaction was found in extensive tests that included five isolates of Nitrosomonas europaea and 668 heterotrophic aerobic and anaerobic bacteria isolated from soil, sewage, and cave sites. The FA preparations were used to detect Nitrobacter species in Mammoth Cave sediments, in a cattle waste oxidation ditch, and in surface waters and sediments of a river and to observe that N. winogradskyi can outgrow N. agilis in enrichment culture. Images PMID:4589121

  14. The impact of Best Management Practices on simulated streamflow and sediment load in a Central Brazilian catchment.

    PubMed

    Strauch, Michael; Lima, Jorge E F W; Volk, Martin; Lorz, Carsten; Makeschin, Franz

    2013-09-01

    The intense use of water for both public supply and agricultural production causes societal conflicts and environmental problems in the Brazilian Federal District. A serious consequence of this is nonpoint source pollution which leads to increasing water treatment costs. Hence, this study investigates in how far agricultural Best Management Practices (BMPs) might contribute to sustainable water resources management and soil protection in the region. The Soil and Water Assessment Tool (SWAT) was used to study the impact of those practices on streamflow and sediment load in the intensively cropped catchment of the Pipiripau River. The model was calibrated and validated against measured streamflow and turbidity-derived sediment loads. By means of scenario simulations, it was found that structural BMPs such as parallel terraces and small sediment basins ('Barraginhas') can lead to sediment load reductions of up to 40%. The implementation of these measures did not adversely affect the water yield. In contrast, multi-diverse crop rotations including irrigated dry season crops were found to be disadvantageous in terms of water availability by significantly reducing streamflow during low flow periods. The study considers rainfall uncertainty by using a precipitation data ensemble, but nevertheless highlights the importance of well established monitoring systems due to related shortcomings in model calibration. Despite the existing uncertainties, the model results are useful for water resource managers to develop water and soil protection strategies for the Pipiripau River Basin and for watersheds with similar characteristics. Copyright © 2013 Elsevier Ltd. All rights reserved.

  15. Investigating the Influence of Clay Mineralogy on Stream Bank Erodibility

    NASA Astrophysics Data System (ADS)

    Ambers, R. K.; Stine, M. B.

    2005-12-01

    Soil scientists concerned with erosion of agricultural fields and geotechnical engineers concerned with the mechanical behavior of soils under different conditions have both examined the role of clay mineralogy in controlling soil/sediment properties. Fluvial geomorphologists studying stream channel erosion and stability have focused more on the effects of particle-size distribution, vegetation and rooting. The clay mineralogy of bed and bank sediment has the potential to influence cohesiveness and erodibility, however. The goal of this study is to determine the influence of clay mineralogy on the erodibility of natural stream bank sediment, utilizing techniques drawn from pedology and soil mechanics. Bank samples were collected from eleven sites in small watersheds in central and western Virginia. To obtain sediment containing a range of different clay minerals, watersheds with different types of bedrock were chosen for sampling. Rock types included mafic to felsic metamorphic and igneous rocks, shale, sandstone, and limestone. Where stream bank materials were clearly stratified, different layers were sampled separately. X-ray diffraction of the clay-fraction of the sediment indicates the presence of kaolinite, illite, vermiculite, and mixed-layer clay minerals in various abundances in the different samples. Clay content is 9-46%, as determined by the hydrometer method, and textures range from silty clay and silt loam to clay loam and sandy loam. Organic mater contents range from 1-5% by the loss-on-ignition method. Bulk density of intact sediment samples averages 1.5 g/cc. Liquid limits range from 23-41 with one sample having a value of 65; plasticity indices range from 15-22. While these tests predict that the samples would show a range of mechanical behaviors, the channel morphology at the sampling sites was not strikingly different, all having steep cut banks eroded primarily by scour with no evidence of mass movement and most having a width/depth ratio around 4.5. The ASTM pinhole test for identifying dispersive clay soils is being adapted to measure erodibility of intact and remolded sediment samples in the laboratory to look for more subtle differences in behavior under erosive conditions. Factors such as the extent and method of sample compaction are being taken into account in order to standardize the method.

  16. Identifying synergies between water resource protection and farm business objectives: the role of soil management

    NASA Astrophysics Data System (ADS)

    Stoate, Chris

    2017-04-01

    We use a 3,000 ha BACI experiment on clay soils in central England as a focus for exploring synergies between Water Framework Directive targets for water quality (sediment, nutrients and pesticides) and crop production objectives of farm businesses. Based on base of catchment annual sediment loads, we estimate annual soil loss from farmland to be in the order of 0.3 - 0.6 tonnes per hectare. This has impacts on aquatic ecology, reservoir storage capacity and downstream flood risk through sedimentation of drainage channels. Soil loss is relatively low in a European context but reflects poorly functioning soils with high runoff risk, and poor crop performance due to compaction, low organic matter, waterlogging, and competition from the grass weed, blackgrass (Alopecuris alopoides). We use a range of mechanisms to increase farmers' awareness, understanding and motivation for improving soil management to meet multiple public and private benefits of soil function and present results for soil organic matter testing, earthworm surveying, and horizontal and vertical soil compaction mapping.

  17. Forecasting the remaining reservoir capacity in the Laurentian Great Lakes watershed

    NASA Astrophysics Data System (ADS)

    Alighalehbabakhani, Fatemeh; Miller, Carol J.; Baskaran, Mark; Selegean, James P.; Barkach, John H.; Dahl, Travis; Abkenar, Seyed Mohsen Sadatiyan

    2017-12-01

    Sediment accumulation behind a dam is a significant factor in reservoir operation and watershed management. There are many dams located within the Laurentian Great Lakes watershed whose operations have been adversely affected by excessive reservoir sedimentation. Reservoir sedimentation effects include reduction of flood control capability and limitations to both water supply withdrawals and power generation due to reduced reservoir storage. In this research, the sediment accumulation rates of twelve reservoirs within the Great Lakes watershed were evaluated using the Soil and Water Assessment Tool (SWAT). The estimated sediment accumulation rates by SWAT were compared to estimates relying on radionuclide dating of sediment cores and bathymetric survey methods. Based on the sediment accumulation rate, the remaining reservoir capacity for each study site was estimated. Evaluation of the anthropogenic impacts including land use change and dam construction on the sediment yield were assessed in this research. The regression analysis was done on the current and pre-European settlement sediment yield for the modeled watersheds to predict the current and natural sediment yield in un-modeled watersheds. These eleven watersheds are in the state of Indiana, Michigan, Ohio, New York, and Wisconsin.

  18. Impact of sedimentation on wetland carbon sequestration in an agricultural watershed.

    PubMed

    McCarty, Gregory; Pachepsky, Yakov; Ritchie, Jerry

    2009-01-01

    Landscape redistribution of soil C is common within agricultural ecosystems. Little is known about the effects of upland sediment deposition on C dynamics within riparian wetlands. To assess sedimentation impact, we obtained profile samples of wetland soil and used the combination of (137)Cs, (210)Pb, and (14)C chronological markers to determine rates of C sequestration and mineral deposition over the history of a wetland within a first-order catchment under agricultural management in the coastal plains of the United States. Substantial post settlement deposition in the wetland soil was evidenced in places by a 20- to 40-cm layer of mineral soil that buried the original histosol. Soil profiles contained a minimum in C content within the top 35 cm of the profile which originated from a rapid deposition from low C upland soils. Radiocarbon and radioisotope dating showed that increases in C above this minimum were the result of C sequestered in the past approximately 50 yr. Modeling the kinetics of modern C dynamics using the (137)Cs and (210)Pb markers within these surface profiles provides strong evidence for accelerated C sequestration associated with mineral sediment deposition in the ecosystem. These findings indicate that at the landscape scale, dilution of ecosystem C by import of low C upland sediment into wetlands stimulates C sequestration by pulling soil C content below some pedogenic equilibrium value for the ecosystem. They also indicate that over the history of the wetland, rates of C accretion may be linked to mineral soil deposition.

  19. Methodological issues concerning the application of reliable laser particle sizing in soils

    NASA Astrophysics Data System (ADS)

    de Mascellis, R.; Impagliazzo, A.; Basile, A.; Minieri, L.; Orefice, N.; Terribile, F.

    2009-04-01

    During the past decade, the evolution of technologies has enabled laser diffraction (LD) to become a much widespread means of particle size distribution (PSD), replacing sedimentation and sieve analysis in many scientific fields mainly due to its advantages of versatility, fast measurement and high reproducibility. Despite such developments of the last decade, the soil scientist community has been quite reluctant to replace the good old sedimentation techniques (ST); possibly because of (i) the large complexity of the soil matrix inducing different types of artefacts (aggregates, deflocculating dynamics, etc.), (ii) the difficulties in relating LD results with results obtained through sedimentation techniques and (iii) the limited size range of most LD equipments. More recently LD granulometry is slowly gaining appreciation in soil science also because of some innovations including an enlarged size dynamic range (0,01-2000 m) and the ability to implement more powerful algorithms (e.g. Mie theory). Furthermore, LD PSD can be successfully used in the application of physically based pedo-transfer functions (i.e., Arya and Paris model) for investigations of soil hydraulic properties, due to the direct determination of PSD in terms of volume percentage rather than in terms of mass percentage, thus eliminating the need to adopt the rough approximation of a single value for soil particle density in the prediction process. Most of the recent LD work performed in soil science deals with the comparison with sedimentation techniques and show the general overestimation of the silt fraction following a general underestimation of the clay fraction; these well known results must be related with the different physical principles behind the two techniques. Despite these efforts, it is indeed surprising that little if any work is devoted to more basic methodological issues related to the high sensitivity of LD to the quantity and the quality of the soil samples. Our work aims to both analyse and to suggest technical solutions to address the following key methodological problems: (i) sample representativeness due to the very small amount of soil sample required by LD (e.g. 0,2 g) as compared to ST (e.g. 40 g for densimetry); (ii) PSD reading variability caused by the large number of instantaneous reading on a very small volume of the solution, (iii) the varying soil mineralogy that in turn produce varying refractive indexes affecting PSD results, (iv) the determination of the mass density of the soil samples to compare results with those obtained from ST. Our results, referring to many different soil types (Vertisols, Regosols, Andosols, Calcisols, Luvisols) show that the listed major technical problems can be successfully addressed by the following set of solutions: (i) adequate subsampling in both solid and liquid phases (including a setup of a dilution system); (ii) preliminary study of the PSD variability to reasonably increase the number of readings per each sample; (iii, iv) preliminary sensitivity analysis of both refractive indexes and mass density in accordance to the specific soil mineralogy.

  20. Sedimentation Time Measurements of Soil Particles by Light Scattering and Determination of Chromium, Lead, and Iron in Soil Samples via ICP

    ERIC Educational Resources Information Center

    Todebush, Patricia Metthe; Geiger, Franz M.

    2005-01-01

    The study of soil samples, using light scattering and Inductively Coupled Plasma spectrometry (ICP) to determine colloid sedimentation rates and the quantity of chromium, lead, and iron in the sample is described. It shows the physical and chemical behavior of solid components in soil, and how such pollutant binding colloid surfaces directly…

  1. On the non-uniqueness of sediment yield

    NASA Astrophysics Data System (ADS)

    Kim, J.; Ivanov, V. Y.; Katopodes, N.

    2012-12-01

    Estimation of sediment yield at the catchment scale plays an important role for optimal design of hydraulic structures, such as bridges, culverts, reservoirs, and detention basins, as well as making informed decisions in environmental management. Many experimental studies focused on obtaining flow and sediment data in search of unique relationships between runoff (specifically, volume and peak) and sediment characteristics. These relationships were employed to predict sediment yield from flow information. However, despite the same flow volume, the actual sediment yield produced by river basins can vary significantly depending on several conditions: (i) the catchment size, (ii) land use, topography, and soil type, (iii) climatic variations or characteristics , and (iv) initial conditions of soil moisture and soil surface . Additionally, shield formation by relatively larger particles can be one of the possible controllers of erosion and net sediment transport. Smaller particles have low settling velocities and tend to move far from their original position of detachment. Conversely, larger particles can settle quickly near their original locations. Eventually, such particles can form a shield on soil bed and protect underlying soil from rainfall detachment and runoff entrainment. The shield formation and temporal development can be influenced by rainfall intensity, frequency, and volume. Rainfall influences the generation of runoff leading to different conditions of flow depth and velocity that can perturb intact soil into a loose condition. In this study, we numerically investigate the effects of precipitation patterns on the generation of sediment yield. In particular, we address reasons of non-uniqueness of basin sediment yield for the same runoff volume as well as causes of unsteady phenomena in erosion processes under steady state flow conditions. For numerical simulations, the two-dimensional Hairsine-Rose model coupled with a fully distributed hydrology and hydraulics model (tRIBS-OFM: Triangulated irregular network - based Real time Integrated Basin Simulator-Overland Flow Model) is used.

  2. Tracing the source of soil organic matter eroded from temperate forest catchments using carbon and nitrogen isotopes

    DOE PAGES

    McCorkle, Emma P.; Berhe, Asmeret Asefaw; Hunsaker, Carolyn T.; ...

    2016-04-29

    Here, soil erosion continuously redistributes soil and associated soil organic matter (SOM) on the Earth's surface, with important implications for biogeochemical cycling of essential elements and terrestrial carbon sequestration. Despite the importance of soil erosion, surprisingly few studies have evaluated the sources of eroded carbon (C). We used natural abundance levels of the stable and radioactive isotopes of C ( 13C and 14C) and stable isotope of nitrogen ( 15N) to elucidate the origins of SOM eroded from low-order catchments along the western slopes of the Sierra Nevada of California, USA. Our work was conducted in two relatively undisturbed catchmentsmore » (low elevation = 1800 m, and high elevation = 2300 m) of the Kings River Experimental Watersheds (KREW) in the Sierra National Forest. Sediment captured in basins at the outlet of each gauged watershed were compared to possible source materials, which included: upland surficial organic horizons (i.e., forest floor) and mineral soils (0–0.6 m) from three landform positions (i.e., crest, backslope, and toeslope), stream bank soils (0–0.6 m), and stream-bed materials (0–0.05 m). We found that most of the organic matter (OM) in the captured sediments was composed of O-horizon material that had high C concentrations. Radiocarbon analyses also showed that the captured OM is composed of modern (post-1950) C, with fraction modern values at or above 1.0. Our results suggest that surface (sheet) erosion, as opposed to channeling through established streams and episodic mass wasting events, is likely the largest source of sediment exported out of these minimally disturbed, headwater catchments. The erosional export of sediment with a high concentration of C, especially in the form of relatively undecomposed litter from the O horizon, suggests that a large fraction of the exported C is likely to be decomposed during or after erosion; hence, it is unlikely that soil erosion acts as a significant net sink for atmospheric CO 2 in these low-order, temperate forest catchments.« less

  3. Tracing the source of soil organic matter eroded from temperate forest catchments using carbon and nitrogen isotopes

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    McCorkle, Emma P.; Berhe, Asmeret Asefaw; Hunsaker, Carolyn T.

    Here, soil erosion continuously redistributes soil and associated soil organic matter (SOM) on the Earth's surface, with important implications for biogeochemical cycling of essential elements and terrestrial carbon sequestration. Despite the importance of soil erosion, surprisingly few studies have evaluated the sources of eroded carbon (C). We used natural abundance levels of the stable and radioactive isotopes of C ( 13C and 14C) and stable isotope of nitrogen ( 15N) to elucidate the origins of SOM eroded from low-order catchments along the western slopes of the Sierra Nevada of California, USA. Our work was conducted in two relatively undisturbed catchmentsmore » (low elevation = 1800 m, and high elevation = 2300 m) of the Kings River Experimental Watersheds (KREW) in the Sierra National Forest. Sediment captured in basins at the outlet of each gauged watershed were compared to possible source materials, which included: upland surficial organic horizons (i.e., forest floor) and mineral soils (0–0.6 m) from three landform positions (i.e., crest, backslope, and toeslope), stream bank soils (0–0.6 m), and stream-bed materials (0–0.05 m). We found that most of the organic matter (OM) in the captured sediments was composed of O-horizon material that had high C concentrations. Radiocarbon analyses also showed that the captured OM is composed of modern (post-1950) C, with fraction modern values at or above 1.0. Our results suggest that surface (sheet) erosion, as opposed to channeling through established streams and episodic mass wasting events, is likely the largest source of sediment exported out of these minimally disturbed, headwater catchments. The erosional export of sediment with a high concentration of C, especially in the form of relatively undecomposed litter from the O horizon, suggests that a large fraction of the exported C is likely to be decomposed during or after erosion; hence, it is unlikely that soil erosion acts as a significant net sink for atmospheric CO 2 in these low-order, temperate forest catchments.« less

  4. Evaluating soil contamination

    USGS Publications Warehouse

    Beyer, W.N.

    1990-01-01

    This compilation was designed to help U.S. Fish and Wildlife Service contaminant specialists evaluate the degree of contamination of a soil, based on chemical analyses. Included are regulatory criteria, opinions, brief descriptions of scientific articles, and miscellaneous information that might be useful in making risk assessments. The intent was to make hard-to-obtain material readily available to contaminant specialists, but not to critique the material or develop new criteria. The compilation is to be used with its index, which includes about 200 contaminants. There are several entries for a few of the most thoroughly studied contaminants, but for most of them the information available is meager. Entries include soil contaminant criteria from other countries, contaminant guidelines for applying sewage sludge to soil, guidelines for evaluating sediments, background soil concentrations for various elements, citations to scientific articles that may help estimate the potential movement of soil contaminants into wildlife food chains, and a few odds and ends. Articles on earthworms were emphasized because they are a natural bridge between soil and many species of wildlife.

  5. Streambeds Merit Recognition as a Scientific Discipline

    NASA Astrophysics Data System (ADS)

    Constantz, J. E.

    2016-12-01

    Streambeds are generally viewed as simply sediments beneath streams, sediments topping alluvial aquifers, or sediments housing aquatic life, rather than as distinct geographic features comparable to soils and surficial geologic formations within watersheds. Streambeds should be viewed as distinct elements within watersheds, e.g., as akin to soils. In this presentation, streambeds are described as central features in watersheds, cycling water between the surface and underlying portions of the watershed. Regarding their kinship to soils, soils are often described as surficial sediments largely created by atmospheric weathering of underlying geologic parent material, and similarly, streambeds should be described as submerged sediments largely created by streamflow modification of underlying geologic parent material. Thus, streambeds are clearly overdue for recognition as their own scientific discipline along side other well-recognized disciplines within watersheds; however, slowing progress in this direction, the point is often made that hyporheic zones should be considered comparable to streambeds, but this is as misguided as equating unsaturated zones to soils. Streambeds and soils are physical geographic features of relatively constant volume, while hyporheic and unsaturated zones are hydrologic features of varying volume. Expanded upon in this presentation, 'Streambed Science' is proposed for this discipline, which will require both a well-designed protocol to physically characterize streambeds as well as development of streambed taxonomy, for suitable recognition as an independent discipline within watersheds.

  6. Soil erosion and sediment fluxes analysis: a watershed study of the Ni Reservoir, Spotsylvania County, VA, USA.

    PubMed

    Pope, Ian C; Odhiambo, Ben K

    2014-03-01

    Anthropogenic forces that alter the physical landscape are known to cause significant soil erosion, which has negative impact on surface water bodies, such as rivers, lakes/reservoirs, and coastal zones, and thus sediment control has become one of the central aspects of catchment management planning. The revised universal soil loss equation empirical model, erosion pins, and isotopic sediment core analyses were used to evaluate watershed erosion, stream bank erosion, and reservoir sediment accumulation rates for Ni Reservoir, in central Virginia. Land-use and land cover seems to be dominant control in watershed soil erosion, with barren land and human-disturbed areas contributing the most sediment, and forest and herbaceous areas contributing the least. Results show a 7 % increase in human development from 2001 (14 %) to 2009 (21.6 %), corresponding to an increase in soil loss of 0.82 Mg ha(-1) year(-1) in the same time period. (210)Pb-based sediment accumulation rates at three locations in Ni Reservoir were 1.020, 0.364, and 0.543 g cm(-2) year(-1) respectively, indicating that sediment accumulation and distribution in the reservoir is influenced by reservoir configuration and significant contributions from bedload. All three locations indicate an increase in modern sediment accumulation rates. Erosion pin results show variability in stream bank erosion with values ranging from 4.7 to 11.3 cm year(-1). These results indicate that urban growth and the decline in vegetative cover has increased sediment fluxes from the watershed and poses a significant threat to the long-term sustainability of the Ni Reservoir as urbanization continues to increase.

  7. Heavy metal contamination from historic mining in upland soil and estuarine sediments of Egypt Bay, Maine, USA

    NASA Astrophysics Data System (ADS)

    Osher, L. J.; Leclerc, L.; Wiersma, G. B.; Hess, C. T.; Guiseppe, V. E.

    2006-10-01

    Concentrations of Cd, Cu, Pb and Zn in sediments of Egypt Bay in Hancock County, Maine, are elevated above background levels. The source of the contamination is Cu mining that occurred in the uplands adjacent to Egypt Stream between 1877 and 1885. Egypt Stream is a tributary to Egypt Bay. Egypt Bay is part of the Taunton Bay estuary system. The Hagan Mine was one of the mines extracting metals from the sulfide deposits in Downeast Maine north of Penobscot Bay. Metal concentrations were determined using ICP-AES after sample digestion with nitric acid. Soil collected from the coarse textured mine tailings pile contained elevated concentrations of Cd, Cu, Pb and Zn, but the majority of the surface soils at the Hagan Mine site were not contaminated. Estuary sediments from the surface to 100 cm depth were collected in four locations within Egypt Bay. Below 40 cm, metal concentrations in sediments were similar to those in uncontaminated upland soils. Metal concentrations in the estuary sediments between the surface and 26 cm were above background levels. According to 210Pb dating, the sediment at 26-34 cm depth was likely to have been deposited at the time the historic mines were in operation. Concentrations of Cd, Cu, Pb, and Zn in sediment from the 32-34 cm depth interval are similar to concentrations in the upland soil sample from the mine tailings pile. Elevated Pb concentrations in sediments from the surface to 24 cm are from atmospheric Pb deposition from anthropogenic sources. Sediment in the top 10 cm of the estuary has been mixed both by the polychaete worm Nereis virens and by those harvesting the worms for sale as fish bait.

  8. Heavy metals in sediments, soils, and aquatic plants from a secondary anabranch of the three gorges reservoir region, China.

    PubMed

    Gao, Jun-Min; Sun, Xiu-Qian; Jiang, Wen-Chao; Wei, Yun-Mei; Guo, Jin-Song; Liu, Yuan-Yuan; Zhang, Ke

    2016-06-01

    We investigated the occurrence of cadmium (Cd), copper (Cu), chromium (Cr), nickel (Ni), lead (Pb), Znic (Zn), iron (Fe), manganese (Mn), and magnesium (Mg) in sediments, as well as in related soils and aquatic plants in the Liangtan River, a typical secondary anabranch of the Yangtze River in the Three Gorges Reservoir Region (TGRR) of China. We found that sediments accumulated more metals than soils and aquatic plants. Concentrations of the nine metals in sediments and soils followed the same sequence, while their concentrations in aquatic plants followed a different sequence. Potential adverse effects of contaminated sediments on benthic fauna were evaluated, and the results showed that the toxic effect on benthic organisms followed the sequence Zn > Ni > Cr > Cu > Cd > Pb. The potential ecological risk index analysis indicated that Cd in sediments had considerable ecological risk, whereas Cr, Cu, Zn, Ni, and Pb had low ecological risk. The potential ecological risk index (RI) of the heavy metals in sediments of the Liangtan River was 174.9, indicating moderate ecological risk. The transfer factor trend of metals for aquatic plants showed that Cd and Ni had the most and least accumulation, respectively. For Cu, Cd, Mg, Pb, and Cr, a significant positive correlation of the metal concentrations was observed between sediments and soils, but no correlations (excluding Cr) were detected between sediments and aquatic plants. Our study indicated that anthropogenic input may be the primary source of metal contamination in the Liangtan River, and that Zn and Cd pollution in the Liangtan River should be further explored.

  9. Herbicide monitoring in soil, runoff waters and sediments in an olive orchard.

    PubMed

    Calderon, Maria Jesus; De Luna, Elena; Gomez, Jose Alfonso; Hermosin, M Carmen

    2016-11-01

    Occurrences of surface water contamination by herbicides in areas where olive orchards are established reveal a need to understand soil processes affecting herbicide fate at field scale for this popular Mediterranean crop. A monitoring study with two herbicides (terbuthylazine and oxyfluorfen) in the first 2cm of soil, runoff waters, and sediments, was carried out after under natural rainfall conditions following winter herbicide application. At the end of the 107day field experiment, no residues of the soil applied terbuthylazine were recovered, whereas 42% of the oxyfluorfen applied remained in the top soil. Very low levels of both herbicides were measured in runoff waters; however, concentrations were slightly higher for terbuthylazine (0.53% of applied) than for oxyfluorfen (0.03% of applied), relating to their respective water solubilities. Congruent with soil residue data, 38.15% of the applied oxyfluorfen was found in runoff-sediment, compared to only 0.46% for terbuthylazine. Accordingly, the herbicide soil distribution coefficients measured within runoff field tanks was much greater for oxyfluorfen (Kd=3098) than for terbuthylazine (Kd=1.57). The herbicide oxyfluorfen is co-transported with sediment in runoff, remaining trapped and/or adsorbed to soil particle aggregates, due in part to its low water solubility. In contrast, terbuthylazine soil dissipation may be associated more so with leaching processes, favored by its high water solubility, low sorption, and slow degradation. By comparing these two herbicides, our results reaffirm the importance of herbicide physico-chemical properties in dictating their behavior in soil and also suggest that herbicides with low solubility, as seen in the case oxyfluorfen, remain susceptible to offsite transport associated with sediments. Copyright © 2016 Elsevier B.V. All rights reserved.

  10. Risk factors for faecal sand excretion in Icelandic horses.

    PubMed

    Husted, L; Andersen, M S; Borggaard, O K; Houe, H; Olsen, S N

    2005-07-01

    Sandy soil is often mentioned as a risk factor in the development of sand-related gastrointestinal disease (SGID) in the horse. There are other variables, but few studies confirm any of these. To investigate soil type, pasture quality, feeding practice in the paddock, age, sex and body condition score as risk factors for sand intake in the horse. Faeces were collected from 211 Icelandic horses on 19 different studs in Denmark together with soil samples and other potential risk factors. Sand content in faeces determined by a sand sedimentation test was interpreted as evidence of sand intake. Soil types were identified by soil analysis and significance of the data was tested using logistic analysis. Of horses included in the study, 56.4% showed sand in the faeces and 5.7% had more than 5 mm sand as quantified by the rectal sleeve sedimentation test. Soil type had no significant effect when tested as main effect, but there was interaction between soil type and pasture quality. Significant interactions were also found between paddock feeding practice and pasture quality. To evaluate the risk of sand intake it is important to consider 3 variables: soil type, pasture quality and feeding practice. Pasture quality was identified as a risk factor of both short and long grass in combination with sandy soil, while clay soil had the lowest risk in these combinations. Feeding practice in the paddock revealed feeding directly on the ground to be a risk factor when there was short (1-5 cm) or no grass. Also, no feeding outdoors increased the risk on pastures with short grass, while this had no effect in paddocks with no grass. More than 50% of all horses investigated in this study had sand in the faeces. The identification of risk factors is an important step towards prevention of SGID. Further research is necessary to determine why some horses exhibit more than 5 mm sand in the sedimentation test and whether this is correlated with geophagic behaviour.

  11. Comparative effects of oil palm and selective logging on erosion, river channels and water chemistry in Malaysian steeplands

    NASA Astrophysics Data System (ADS)

    Walsh, Rory; Nainar, Anand; Nurhidayu, Siti; Higton, Sam; Annammala, Kogilavani; Wall, Katy; Bidin, Kawi; Blake, William; Darling, Isabella

    2017-04-01

    Oil palm land-use has expanded greatly in recent decades in SE Asia and other parts of the wet tropics, including to steepland areas, where bench-terraced landscaping is involved. Retaining (and sometimes restoring) riparian forest strips and rainforest fragments on the steepest slopes have been adopted as elements of strategies designed to reduce adverse effects on runoff generation, erosion, downstream sedimentation, flooding and pollutional problems - as well as biodiversity and emissions. Results of catchment monitoring, soil erosion and sediment fingerprinting research in oil palm and selectively logged steeplands of eastern Sabah and Peninsular Malaysia are presented. The evidence indicates the greater scale and temporal persistence of effects that oil palm land-use (compared with selective logging) has had on suspended sediment dynamics, soil erosion, downstream sedimentation, channel geometry and dynamics and river pollution. The importance of (1) high densities of roads and tracks and (2) relatively impermeable bench-terraced terrain in enhancing runoff, sediment and nutrient outputs in storm events is stressed. Influences of oil palm management practices including riparian forest strips in increasing or reducing these effects are critically reviewed and ways of increasing the effectiveness of riparian forest strips are proposed. The design and rationale of current projects exploring and testing consequences of existing and proposed improved land management practices are briefly described. The key importance of involvement of people from the oil palm industry (including multinational companies, smallholders and their organizations) and Government bodies that are responsible for land-use policies and land management practices is stressed.

  12. Soil erosion and sediment delivery in a mountain catchment under scenarios of land use change using a spatially distributed numerical model

    NASA Astrophysics Data System (ADS)

    Alatorre, L. C.; Beguería, S.; Lana-Renault, N.; Navas, A.; García-Ruiz, J. M.

    2012-05-01

    Soil erosion and sediment yield are strongly affected by land use/land cover (LULC). Spatially distributed erosion models are of great interest to assess the expected effect of LULC changes on soil erosion and sediment yield. However, they can only be applied if spatially distributed data is available for their calibration. In this study the soil erosion and sediment delivery model WATEM/SEDEM was applied to a small (2.84 km2) experimental catchment in the Central Spanish Pyrenees. Model calibration was performed based on a dataset of soil redistribution rates derived from point 137Cs inventories, allowing capture differences per land use in the main model parameters. Model calibration showed a good convergence to a global optimum in the parameter space, which was not possible to attain if only external (not spatially distributed) sediment yield data were available. Validation of the model results against seven years of recorded sediment yield at the catchment outlet was satisfactory. Two LULC scenarios were then modeled to reproduce land use at the beginning of the twentieth century and a hypothetic future scenario, and to compare the simulation results to the current LULC situation. The results show a reduction of about one order of magnitude in gross erosion (3180 to 350 Mg yr-1) and sediment delivery (11.2 to 1.2 Mg yr-1 ha-1) during the last decades as a result of the abandonment of traditional land uses (mostly agriculture) and subsequent vegetation recolonization. The simulation also allowed assessing differences in the sediment sources and sinks within the catchment.

  13. 78 FR 60218 - Safety Zone; Old Mormon Slough, Stockton, CA

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-10-01

    ... decontaminate soil, groundwater, and sediment in Old Mormon Slough and the surrounding basin. This safety zone... safety zone in Old Mormon Slough to further the efforts of the EPA to rehabilitate soil, sediment, and... water collection ponds. The unlined oily waste ponds were closed in 1981. Sampling has shown that soils...

  14. Quaternary Glacial Mapping in Western Wisconsin Using Soil Survey Information

    ERIC Educational Resources Information Center

    Oehlke, Betsy M.; Dolliver, Holly A. S.

    2011-01-01

    The majority of soils in the western Wisconsin have developed from glacial sediments deposited during the Quaternary Period (2.6 million years before present). In many regions, multiple advances and retreats have left a complex landscape of diverse glacial sediments and landforms. The soils that have developed on these deposits reflect the nature…

  15. QUANTITATIVE ENZYME-LINKED IMMUNOSORBENT ASSAY FOR DETERMINATION OF POLYCHLORINATED BIPHENYLS IN ENVIRONMENTAL SOIL AND SEDIMENT SAMPLES

    EPA Science Inventory

    An enzyme-linked immunosorbent assay (ELISA) for the quantitative determination of Aroclors 1242, 1248, 1254, and 1260 in soil and sediments was developed and its performance compared with that of gas chromatography (GC). The detection limits for Aroclors 1242 and 1248 in soil ar...

  16. SIMPLE METHOD FOR ESTIMATING POLYCHLORINATED BIPHENYL CONCENTRATIONS ON SOILS AND SEDIMENTS USING SUBCRITICAL WATER EXTRACTION COUPLED WITH SOLID-PHASE MICROEXTRACTION. (R825368)

    EPA Science Inventory

    A rapid method for estimating polychlorinated biphenyl (PCB) concentrations in contaminated soils and sediments has been developed by coupling static subcritical water extraction with solid-phase microextraction (SPME). Soil, water, and internal standards are placed in a seale...

  17. Herbicides--Protecting Long-Term Sustainability and Water Quality in Forest Ecosystems

    Treesearch

    Daniel G. Neary; Jerry L. Michael

    1996-01-01

    World-wide, sediment is the major water quality problem. The use of herbicides for controllingcompeting vegetation during stand establishment can be benciicial to forest ecosystem sustainability and water quality by minimising off-site soil loss, reducing onsite soil and organic matter displacement, and preventing deterioration of soil physical properties. Sediment...

  18. Results of rainfall simulation to estimate sediment-bound carbon and nitrogen loss from an Atlantic Coastal Plain (USDA) ultisol

    USDA-ARS?s Scientific Manuscript database

    The impact of erosion on soil and carbon loss and redistribution within landscapes is an important component for developing estimates of carbon sequestration potential, management plans to maintain soil quality, and transport of sediment bound agrochemicals. Soils of the Southeastern U.S. Coastal Pl...

  19. Engineering geologic conditions at the sinkhole entrance to Logan Cave, Benton County, Arkansas

    USGS Publications Warehouse

    Schulz, William H.; McKenna, Jonathan P.

    2004-01-01

    Logan Cave, located in Benton County, Arkansas, is inhabited by several endangered and threatened species. The cave and surrounding area was designated a National Wildlife Refuge under the control of the U.S. Fish and Wildlife Service (USFWS) in 1989. Cave researchers access the cave through a steep-sided sinkhole entrance, which also is one of the two access points used by endangered bats. There is evidence of instability of one of the entrance slopes that has raised concerns that the entrance could close if slope failure was to occur. At the request of USFWS, we performed an engineering geologic investigation of the sinkhole to evaluate stability of this slope, which is comprised of soil, and other mechanisms of sediment transport into the cave entrance. The investigation included engineering geologic mapping, sampling and laboratory testing of subsurface geologic materials, and slope-stability analysis. We found that the sinkhole slope that extends into the entrance of the cave is comprised of sandy and gravelly soil to the depths explored (6.4 meters). This soil likely was deposited as alluvium within a previous, larger sinkhole. Based on properties of the alluvium, geometry of the slope, and results of finite-element slope-stability analyses, we conclude that the slope is marginally stable. Future failures of the slope probably would be relatively thin and small, thus several would be required to completely close the cave entrance. However, sediment is accumulating within the cave entrance due to foot traffic of those accessing the cave, surface-water erosion and transport, and shallow slope failures from the other sinkhole slopes. We conclude that the entrance will be closed by sediment in the future, similar to another entrance that we identified that completely closed in the past. Several measures could be taken to reduce the potential for closure of the cave entrance, including periodic sediment removal, installation of materials that reduce erosion by foot traffic and surface water, construction of a sediment-retention wall, and excavation of the soil slope. Any measures taken must be carefully planned and executed so that they have no impact on organisms within the cave.

  20. Fingerprinting Persistent Turbidity in Sheep Creek Reservoir, Owhyee, Nevada

    NASA Astrophysics Data System (ADS)

    Ransom, R. N.; Hooper, R. L.; Kerner, D.; Nicols, S.

    2007-12-01

    Sheep Creek Reservoir near Owyhee, NV is historically a quality rainbow trout fishery. Persistent high-turbidity has been an issue since a major storm event in 2005 resulted in surface water runoff into the Reservoir. The high turbidity is adversely impacting the quality of the fishery. Initial turbidity measurements in 2005 were upwards of 80NTU and these numbers have only decreased to 30NTU over the past two summers. Field parameters indicate the turbidity is associated with high total suspended solids (TSS) and not algae. Five water samples collected from around the reservoir during June, 2007 indicated uniform TSS values in the range of 5 to 12mg/L and oriented powder x-ray diffraction(XRD) and transmission electron microscopy(TEM) analyses of suspended sediment shows very uniform suspended particulate mineralogy including smectite, mixed layer illite/smectite (I/S), discrete illite, lesser amounts of kaolin, sub-micron quartz and feldspar. Diatoms represent a ubiquitous but minor component of the suspended solids. Six soil samples collected from possible source areas around the reservoir were analyzed using both XRD and TEM to see if a source area for the suspended solids could be unambiguously identified. Soils on the east side of the reservoir contain smectite and mixed layer I/S but very little of the other clays. The less than 2 micron size fraction from soils collected from a playa on the topographic bench immediately to the west of the reservoir show a mineralogic finger-print essentially identical to the current suspended sediment. The suspended sediment probably originates on the bench to the west of the reservoir and cascades into the reservoir over the topographic break during extreme storm events. The topographic relief, short travel distance and lack of a suitable vegetated buffer zone to the west are all consistent with a primary persistent suspended sediment source from the west. Identification of the sediment source allows for design of a cost effective remediation plan that includes minimizing future loading of the reservoir with soils capable of producing extended turbidity.

  1. The role of livestock-poached pasture as a sediment source

    NASA Astrophysics Data System (ADS)

    Greenwood, Philip; Walling, Desmond; Quine, Timothy

    2015-04-01

    Historically, the occurrence of sediment-laden runoff has almost exclusively been associated with cultivated hillslopes and particularly with arable land. This association was commonly accompanied by the presumption that, in comparison with cultivated slopes, erosion from intensively-managed lowland pasture was relatively low. Recent developments in sediment source tracing and fingerprinting techniques have, however, challenged these assumptions by demonstrating that soil loss from grasslands may be greater than previously assumed. In attempting to identify potential source areas within grassland environments, attention has frequently focused on areas of livestock poaching where herd animals tend to congregate. However, the role of poached grassland as a sediment-source remains uncertain. Reasons include the difficulties associated with accurately documenting the movement or redistribution of small quantities of fine sediment over relevant spatial and temporal scales. Motivated by an urgent need for such information, this communication presents preliminary results from a tracing study aimed at measuring sediment redistribution within areas of poached pasture over short (i.e. event-based) timescales using the artificial radionuclides, caesium-134 (134Cs) and cobalt-60 (60Co). The approach involved labelling six small areas (0.2 * 0.2 m) of poached soil, each with a contrasting gradient, with either 134Cs or 60Co, and then measuring changes in the radiometric inventory at predetermined points before and after periods of rainfall. Each labelled area of poached pasture was measured on three separate occasions over a 65 day period. At the end of the monitoring phase, the mean net soil redistribution depth (mm) was negative for all plots, with values ranging from -6.8 mm to -15.2 mm. This is interpreted as evidence of the removal, or erosion, of surface material. The findings indicate that areas of livestock-poached pasture can act as significant sediment sources. These findings are discussed with regard to the potential contribution of poaching to the off-site transfer of fine-sediment from affected grasslands, and to the implications for the water quality of receiving streams.

  2. Spatio-temporal patterns of soil erosion and suspended sediment dynamics in the Mekong River Basin.

    PubMed

    Suif, Zuliziana; Fleifle, Amr; Yoshimura, Chihiro; Saavedra, Oliver

    2016-10-15

    Understanding of the distribution patterns of sediment erosion, concentration and transport in river basins is critically important as sediment plays a major role in river basin hydrophysical and ecological processes. In this study, we proposed an integrated framework for the assessment of sediment dynamics, including soil erosion (SE), suspended sediment load (SSL) and suspended sediment concentration (SSC), and applied this framework to the Mekong River Basin. The Revised Universal Soil Loss Equation (RUSLE) model was adopted with a geographic information system to assess SE and was coupled with a sediment accumulation and a routing scheme to simulate SSL. This framework also analyzed Landsat imagery captured between 1987 and 2000 together with ground observations to interpolate spatio-temporal patterns of SSC. The simulated SSL results from 1987 to 2000 showed the relative root mean square error of 41% and coefficient of determination (R(2)) of 0.89. The polynomial relationship of the near infrared exoatmospheric reflectance and the band 4 wavelength (760-900nm) to the observed SSC at 9 sites demonstrated the good agreement (overall relative RMSE=5.2%, R(2)=0.87). The result found that the severe SE occurs in the upper (China and Lao PDR) and lower (western part of Vietnam) regions. The SSC in the rainy season (June-November) showed increasing and decreasing trends longitudinally in the upper (China and Lao PDR) and lower regions (Cambodia), respectively, while the longitudinal profile of SSL showed a fluctuating trend along the river in the early rainy season. Overall, the results described the unique spatio-temporal patterns of SE, SSL and SSC in the Mekong River Basin. Thus, the proposed integrated framework is useful for elucidating complex process of sediment generation and transport in the land and river systems of large river basins. Copyright © 2016 Elsevier B.V. All rights reserved.

  3. Ideas and perspectives: Holocene thermokarst sediments of the Yedoma permafrost region do not increase the northern peatland carbon pool

    NASA Astrophysics Data System (ADS)

    Hugelius, Gustaf; Kuhry, Peter; Tarnocai, Charles

    2016-04-01

    Permafrost deposits in the Beringian Yedoma region store large amounts of organic carbon (OC). Walter Anthony et al. (2014) describe a previously unrecognized pool of 159 Pg OC accumulated in Holocene thermokarst sediments deposited in Yedoma region alases (thermokarst depressions). They claim that these alas sediments increase the previously recognized circumpolar permafrost peat OC pool by 50 %. It is stated that previous integrated studies of the permafrost OC pool have failed to account for these deposits because the Northern Circumpolar Soil Carbon Database (NCSCD) is biased towards non-alas field sites and that the soil maps used in the NCSCD underestimate coverage of organic permafrost soils. Here we evaluate these statements against a brief literature review, existing data sets on Yedoma region soil OC storage and independent field-based and geospatial data sets of peat soil distribution in the Siberian Yedoma region. Our findings are summarized in three main points. Firstly, the sediments described by Walter Anthony et al. (2014) are primarily mineral lake sediments and do not match widely used international scientific definitions of peat or organic soils. They can therefore not be considered an addition to the circumpolar peat carbon pool. We also emphasize that a clear distinction between mineral and organic soil types is important since they show very different vulnerability trajectories under climate change. Secondly, independent field data and geospatial analyses show that the Siberian Yedoma region is dominated by mineral soils, not peatlands. Thus, there is no evidence to suggest any systematic bias in the NCSCD field data or maps. Thirdly, there is spatial overlap between these Holocene thermokarst sediments and previous estimates of permafrost soil and sediment OC stocks. These carbon stocks were already accounted for by previous studies and they do not significantly increase the known circumpolar OC pool. We suggest that these inaccurate statements made in Walter Anthony et al. (2014) mainly resulted from misunderstandings caused by conflicting definitions and terminologies across different geoscientific disciplines. A careful cross-disciplinary review of terminologies would help future studies to appropriately harmonize definitions between different fields.

  4. Field scale modeling to estimate phosphorus and sediment load reductions using a newly developed graphical user interface for soil and water assessment tool

    USDA-ARS?s Scientific Manuscript database

    Streams throughout the North Canadian River watershed in northwest Oklahoma, USA have elevated levels of nutrients and sediment. SWAT (Soil and Water Assessment Tool) was used to identify areas that likely contributed disproportionate amounts of phosphorus (P) and sediment to Lake Overholser, the re...

  5. Sediment-bound total organic carbon and total organic nitrogen losses from conventional and strip tillage cropping systems

    USDA-ARS?s Scientific Manuscript database

    Soil erosion and sediment loss with runoff are closely linked to global carbon and nitrogen cycles. Reducing tillage has been shown to reduce erosion and runoff sediment-bound carbon (C) and nitrogen (N) losses. However, published studies represent only a few soil types and regions and rarely direct...

  6. The dirt on sediments

    USGS Publications Warehouse

    Smith, Loren M.; Euliss, Ned H. "Chip"

    2010-01-01

    In the wetland science field, sediment deposition is often thought of as being beneficial especially when one thinks of coastal estuarine systems. For example, sediments deposited from streams and rivers are necessary to naturally build and maintain tidal marshes. These sediments come from eroded upland soils in the interior of the continent. When these sediments are diverted from natural coastal deposition areas, such as occurs from river channelization, we lose marshes through subsidence as is happening throughout coastal Louisiana. However, the value of eroded soils is all a matter of hydrogeomorphic perspective.

  7. Atmospheric dust in modern soil on aeolian sandstone, Colorado Plateau (USA): Variation with landscape position and contribution to potential plant nutrients

    USGS Publications Warehouse

    Reynolds, R.; Neff, J.; Reheis, M.; Lamothe, P.

    2006-01-01

    Rock-derived nutrients in soils originate from both local bedrock and atmospheric dust, including dust from far-distant sources. Distinction between fine particles derived from local bedrock and from dust provides better understanding of the landscape-scale distribution and abundance of soil nutrients. Sandy surficial deposits over dominantly sandstone substrates, covering vast upland areas of the central Colorado Plateau, typically contain 5-40% silt plus clay, depending on geomorphic setting and slope (excluding drainages and depressions). Aeolian dust in these deposits is indicated by the presence of titanium-bearing magnetite grains that are absent in the sedimentary rocks of the region. Thus, contents of far-traveled aeolian dust can be estimated from magnetic properties that primarily reflect magnetite content, such as isothermal remanent magnetization (IRM). Isothermal remanent magnetization was measured on bulk sediment samples taken along two transects in surficial sediment down gentle slopes away from sandstone headwalls. One transect was in undisturbed surficial sediment, the other in a setting that was grazed by domestic livestock until 1974. Calculation of far-traveled dust contents of the surficial deposits is based on measurements of the magnetic properties of rock, surficial deposits, and modern dust using a binary mixing model. At the undisturbed site, IRM-based calculations show a systematic down-slope increase in aeolian dust (ranging from 2% to 18% of the surface soil mass), similar to the down-slope increase in total fines (18-39% of surface soil mass). A combination of winnowing by wind during the past and down-slope movement of sediment likely accounts for the modern distribution of aeolian dust and associated nutrients. At the previously grazed site, dust also increases down slope (5-11%) in sediment with corresponding abundances of 13-25% fines. Estimates of the contributions of aeolian dust to the total soil nutrients range widely, depending on assumptions about grain-size partitioning of potential nutrients in weathered bedrock. Nevertheless, aeolian dust is important for this setting, contributing roughly 40-80% of the rock-derived nutrient stocks (P, K, Na, Mn, Zn, and Fe) in uppermost soil over most of the sampled slope at the undisturbed site, which shows no evidence of recent wind erosion. ?? 2005 Elsevier B.V. All rights reserved.

  8. Sedimentation and associated trace metal enrichment in the riparian zone of the Three Gorges Reservoir, China.

    PubMed

    Tang, Qiang; Bao, Yuhai; He, Xiubin; Zhou, Huaidong; Cao, Zhijing; Gao, Peng; Zhong, Ronghua; Hu, Yunhua; Zhang, Xinbao

    2014-05-01

    Impoundment of the Three Gorges Reservoir has created an artificial riparian zone with a vertical height of 30 m and a total area of 349 km(2), which has been subjected to seasonal inundation and exposure due to regular reservoir impoundment and the occurrence of natural floods. The significant alteration of hydrologic regime has caused numerous environmental changes. The present study investigated the magnitude and spatial pattern of sedimentation and metal enrichment in a typical section of the riparian zone, composed of bench terraces with previous agricultural land uses, and explored their links to the changed hydrologic regime. In particular, we measured the total sediment depths and collected surface riparian sediments and down-profile sectioned riparian soils (at 5 cm intervals) for trace metal determination. Our analysis showed that the annual average sedimentation rates varied from 0.5 to 10 cm·yr(-1) and they decreased significantly with increasing elevation. This lateral distribution was principally attributed to seasonal variations in water levels and suspended sediment concentrations. Enriched concentrations of trace metals were found both in the riparian sediments and soils, but they were generally higher in the riparian sediments than in riparian soils and followed a similar lateral decreasing trend. Metal contamination assessment showed that the riparian sediments were slightly contaminated by Ni, Zn, and Pb, moderately contaminated by Cu, and moderately to strongly contaminated by Cd; while riparian soils were slightly contaminated by As, and moderately contaminated by Cd. Trace metal enrichment in the riparian sediments may be attributed to external input of contaminated sediments produced from upstream anthropogenic sources and chemical adsorption from dissolved fractions during pure sediment mobilization and after sink for a prolonged flooding period due to reservoir impoundment. Copyright © 2014 Elsevier B.V. All rights reserved.

  9. Fate and movement of selenium from drainage sediments disposed onto soil with and without vegetation.

    PubMed

    Bañuelos, G S; Bitterli, C; Schulin, R

    2013-09-01

    Disposal options for salty and selenium-laden agricultural drainage sediments are needed to protect the agricultural ecosystem in Central California. Thus, a 7-year pilot-scale field study evaluated the effects of disposing Se-laden drainage sediment onto soil that was planted with either salado grass (Sporobolus airoides 'salado') or cordgrass (Spartina patens 'Flageo'), or on soil left bare with and without irrigation. Significant decreases in salinity and water-extractable and total soil Se concentrations were observed in all treatments to a depth 30 cm, while water extractable Se and salinity increased most significantly between 30 and 60 cm. Total yields increased over time for both species, while plant Se concentrations were ≈10 and 12 mg kg(-1) DM for salado and cordgrass, respectively. The results show that Se and soluble salts disposed of as Se-laden drainage sediment onto light textured soils will significantly migrate to lower depths with or without vegetation. Published by Elsevier Ltd.

  10. Hysteretic sediment fluxes in rainfall-driven soil erosion

    NASA Astrophysics Data System (ADS)

    Cheraghi, Mohsen; Jomaa, Seifeddine; Sander, Graham C.; Barry, D. Andrew

    2017-04-01

    Hysteresis patterns of different sediment particle sizes were studied via a detailed laboratory study and modelling. Seven continuous rainfall events with stepwise- varying rainfall intensities (30, 37.5, 45, 60, 45, 37.5 and 30 mm h-1, each 20 min duration) were conducted using a 5-m × 2-m erosion flume. Flow rates and sediment concentration data were measured using flume discharge samples, and interpreted using the Hairsine and Rose (HR) soil erosion model. The total sediment concentration and concentrations of seven particle size classes (< 2, 2-20, 20-50, 50-100, 100-315, 315-1000 and > 1000 μm) were measured. For the total eroded soil and the finer particle sizes (< 2, 2-20 and 20-50 μm), there was a clockwise pattern in the sediment concentration versus discharge curves. However, as the particle size increased, concentrations tended to vary linearly with discharge. The HR model predictions for the total eroded soil and the finer particle size classes (up to 100 μm) were in good agreement with the experimental results. For the larger particles, the model provided qualitative agreement with the measurements but concentration values were different. In agreement with previous investigations using the HR model, these differences were attributed to the HR model's assumption of suspended sediment flow, which does not account for saltation and rolling motions. Keywords: Hysteresis effects, Sediment transport, Flume experiment, Splash soil erosion, Hairsine and Rose model, Particle Swarm Optimization.

  11. Effects of soil management techniques on soil water erosion in apricot orchards.

    PubMed

    Keesstra, Saskia; Pereira, Paulo; Novara, Agata; Brevik, Eric C; Azorin-Molina, Cesar; Parras-Alcántara, Luis; Jordán, Antonio; Cerdà, Artemi

    2016-05-01

    Soil erosion is extreme in Mediterranean orchards due to management impact, high rainfall intensities, steep slopes and erodible parent material. Vall d'Albaida is a traditional fruit production area which, due to the Mediterranean climate and marly soils, produces sweet fruits. However, these highly productive soils are left bare under the prevailing land management and marly soils are vulnerable to soil water erosion when left bare. In this paper we study the impact of different agricultural land management strategies on soil properties (bulk density, soil organic matter, soil moisture), soil water erosion and runoff, by means of simulated rainfall experiments and soil analyses. Three representative land managements (tillage/herbicide/covered with vegetation) were selected, where 20 paired plots (60 plots) were established to determine soil losses and runoff. The simulated rainfall was carried out at 55mmh(-1) in the summer of 2013 (<8% soil moisture) for one hour on 0.25m(2) circular plots. The results showed that vegetation cover, soil moisture and organic matter were significantly higher in covered plots than in tilled and herbicide treated plots. However, runoff coefficient, total runoff, sediment yield and soil erosion were significantly higher in herbicide treated plots compared to the others. Runoff sediment concentration was significantly higher in tilled plots. The lowest values were identified in covered plots. Overall, tillage, but especially herbicide treatment, decreased vegetation cover, soil moisture, soil organic matter, and increased bulk density, runoff coefficient, total runoff, sediment yield and soil erosion. Soil erosion was extremely high in herbicide plots with 0.91Mgha(-1)h(-1) of soil lost; in the tilled fields erosion rates were lower with 0.51Mgha(-1)h(-1). Covered soil showed an erosion rate of 0.02Mgha(-1)h(-1). These results showed that agricultural management influenced water and sediment dynamics and that tillage and herbicide treatment should be avoided. Copyright © 2016 Elsevier B.V. All rights reserved.

  12. Impacts of heterogeneous organic matter on phenanthrene sorption--Different soil and sediment samples

    USGS Publications Warehouse

    Karapanagioti, Hrissi K.; Childs, Jeffrey; Sabatini, David A.

    2001-01-01

    Organic petrography has been proposed as a tool for characterizing the heterogeneous organic matter present in soil and sediment samples. A new simplified method is proposed as a quantitative means of interpreting observed sorption behavior for phenanthrene and different soils and sediments based on their organic petrographical characterization. This method is tested under singe solute conditions and at phenanthrene concentration of 1 μg/L. Since the opaque organic matter fraction dominates the sorption process, we propose that by quantifying this fraction one can interpret organic content normalized sorption distribution coefficient (Koc) values for a sample. While this method was developed and tested for various samples within the same aquifer, in the current study the method is validated for soil and sediment samples from different sites that cover a wide range of organic matter origin, age, and organic content. All 10 soil and sediment samples studied had log Koc values for the opaque particles between 5.6 and 6.8. This range of Koc values illustrates the heterogeneity of opaque particles between sites and geological formations and thus the need to characterize the opaque fraction of materials on a site-by-site basis.

  13. The assumption of heterogeneous or homogeneous radioactive contamination in soil/sediment: does it matter in terms of the external exposure of fauna?

    PubMed

    Beaugelin-Seiller, K

    2014-12-01

    The classical approach to environmental radioprotection is based on the assumption of homogeneously contaminated media. However, in soils and sediments there may be a significant variation of radioactivity with depth. The effect of this heterogeneity was investigated by examining the external exposure of various sediment and soil organisms, and determining the resulting dose rates, assuming a realistic combination of locations and radionuclides. The results were dependent on the exposure situation, i.e., the organism, its location, and the quality and quantity of radionuclides. The dose rates ranged over three orders of magnitude. The assumption of homogeneous contamination was not consistently conservative (if associated with a level of radioactivity averaged over the full thickness of soil or sediment that was sampled). Dose assessment for screening purposes requires consideration of the highest activity concentration measured in a soil/sediment that is considered to be homogeneously contaminated. A more refined assessment (e.g., higher tier of a graded approach) should take into consideration a more realistic contamination profile, and apply different dosimetric approaches. Copyright © 2014 Elsevier Ltd. All rights reserved.

  14. Using rare earth elements to trace wind-driven dispersion of sediments from a point source

    NASA Astrophysics Data System (ADS)

    Van Pelt, R. Scott; Barnes, Melanie C. W.; Strack, John E.

    2018-06-01

    The entrainment and movement of aeolian sediments is determined by the direction and intensity of erosive winds. Although erosive winds may blow from all directions, in most regions there is a predominant direction. Dust emission causes the removal preferentially of soil nutrients and contaminants which may be transported tens to even thousands of kilometers from the source and deposited into other ecosystems. It would be beneficial to understand spatially and temporally how the soil source may be degraded and depositional zones enriched. A stable chemical tracer not found in the soil but applied to the surface of all particles in the surface soil would facilitate this endeavor. This study examined whether solution-applied rare earth elements (REEs) could be used to trace aeolian sediment movement from a point source through space and time at the field scale. We applied erbium nitrate solution to a 5 m2 area in the center of a 100 m diameter field 7854 m2 on the Southern High Plains of Texas. The solution application resulted in a soil-borne concentration three orders of magnitude greater than natively found in the field soil. We installed BSNE sampler masts in circular configurations and collected the trapped sediment weekly. We found that REE-tagged sediment was blown into every sampler mast during the course of the study but that there was a predominant direction of transport during the spring. This preliminary investigation suggests that the REEs provide a viable and incisive technique to study spatial and temporal variation of aeolian sediment movement from specific sources to identifiable locations of deposition or locations through which the sediments were transported as horizontal mass flux and the relative contribution of the specific source to the total mass flux.

  15. Spatial and temporal variability of trace element concentrations in an urban subtropical watershed, Honolulu, Hawaii

    USGS Publications Warehouse

    Heinen, De Carlo E.; Anthony, S.S.

    2002-01-01

    Trace metal concentrations in soils and in stream and estuarine sediments from a subtropical urban watershed in Hawaii are presented. The results are placed in the context of historical studies of environmental quality (water, soils, and sediment) in Hawaii to elucidate sources of trace elements and the processes responsible for their distribution. This work builds on earlier studies on sediments of Ala Wai Canal of urban Honolulu by examining spatial and temporal variations in the trace elements throughout the watershed. Natural processes and anthropogenic activity in urban Honolulu contribute to spatial and temporal variations of trace element concentrations throughout the watershed. Enrichment of trace elements in watershed soils result, in some cases, from contributions attributed to the weathering of volcanic rocks, as well as to a more variable anthropogenic input that reflects changes in land use in Honolulu. Varying concentrations of As, Cd, Cu, Pb and Zn in sediments reflect about 60 a of anthropogenic activity in Honolulu. Land use has a strong impact on the spatial distribution and abundance of selected trace elements in soils and stream sediments. As noted in continental US settings, the phasing out of Pb-alkyl fuel additives has decreased Pb inputs to recently deposited estuarine sediments. Yet, a substantial historical anthropogenic Pb inventory remains in soils of the watershed and erosion of surface soils continues to contribute to its enrichment in estuarine sediments. Concentrations of other elements (e.g., Cu, Zn, Cd), however, have not decreased with time, suggesting continued active inputs. Concentrations of Ba, Co, Cr, Ni, V and U, although elevated in some cases, typically reflect greater proportions attributed to natural sources rather than anthropogenic input. ?? 2002 Elsevier Science Ltd. All rights reserved.

  16. Seismic displacement of gently-sloping coastal and marine sediment under multidirectional earthquake loading

    USGS Publications Warehouse

    Kayen, Robert E.

    2017-01-01

    Gentle sediment-laden slopes are typical of the onshore coastal zone and offshore continental shelf and slope. Coastal sediment are commonly young weakly consolidated materials that are well stratified, have low strength, and can mobilize shear displacements at low levels of stress. Seismically-driven plastic displacements of these sediment pose a hazard to coastal cities, buried onshore utilities, and offshore infrastructure like harbor protection and outfalls. One-dimensional rigid downslope-directed Newmark sliding block analyses have been used to predict earthquake deformations generally on steeper slopes that are modeled as frictional materials. This study probes the effect of multidirectional earthquake motions on inertial displacements of gently sloping ground of the coastal and offshore condition where soft-compliant soil is expected. Toward that objective, this investigation seeks to understand the effect on Newmark-type displacements of [1] multidirectional earthquake shaking and [2] soil compliance. In order to model multidirectional effects, the earthquake motions are rotated into the local slope strike- and dip-components. On gently sloping ground, including the strike component of motion always results in a larger and more accurate shear stress vector. Strike motions are found to contribute to downslope deformations on any declivity. Compliant response of the soil mass also influences the plastic displacements. The magnitude of seismic displacements can be estimated with a simplified model using only the estimated soil yield-acceleration (ky) and the peak ground velocity (Vmax) of the earthquake motions. Compliance effects can be effectively mapped using the concept of Plastic Displacement Response Spectra (PDRS).

  17. Floodplain trapping and cycling compared to streambank erosion of sediment and nutrients in an agricultural watershed

    USGS Publications Warehouse

    Gillespie, Jaimie; Noe, Gregory; Hupp, Cliff R.; Gellis, Allen; Schenk, Edward R.

    2018-01-01

    Floodplains and streambanks can positively and negatively influence downstream water quality through interacting geomorphic and biogeochemical processes. Few studies have measured those processes in agricultural watersheds. We measured inputs (floodplain sedimentation and dissolved inorganic loading), cycling (floodplain soil nitrogen [N] and phosphorus [P] mineralization), and losses (bank erosion) of sediment, N, and P longitudinally in stream reaches of Smith Creek, an agricultural watershed in the Valley and Ridge physiographic province. All study reaches were net depositional (floodplain deposition > bank erosion), had high N and P sedimentation and loading rates to the floodplain, high soil concentrations of N and P, and high rates of floodplain soil N and P mineralization. High sediment, N, and P inputs to floodplains are attributed to agricultural activity in the region. Rates of P mineralization were much greater than those measured in other studies of nontidal floodplains that used the same method. Floodplain connectivity and sediment deposition decreased longitudinally, contrary to patterns in most watersheds. The net trapping function of Smith Creek floodplains indicates a benefit to water quality. Further research is needed to determine if future decreases in floodplain deposition, continued bank erosion, and the potential for nitrate leaching from nutrient-enriched floodplain soils could pose a long-term source of sediment and nutrients to downstream rivers.

  18. Developing a Dynamic SPARROW Water Quality Decision Support System Using NASA Remotely-Sensed Products

    NASA Astrophysics Data System (ADS)

    Al-Hamdan, M. Z.; Smith, R. A.; Hoos, A.; Schwarz, G. E.; Alexander, R. B.; Crosson, W. L.; Srikishen, J.; Estes, M., Jr.; Cruise, J.; Al-Hamdan, A.; Ellenburg, W. L., II; Flores, A.; Sanford, W. E.; Zell, W.; Reitz, M.; Miller, M. P.; Journey, C. A.; Befus, K. M.; Swann, R.; Herder, T.; Sherwood, E.; Leverone, J.; Shelton, M.; Smith, E. T.; Anastasiou, C. J.; Seachrist, J.; Hughes, A.; Graves, D.

    2017-12-01

    The USGS Spatially Referenced Regression on Watershed Attributes (SPARROW) surface water quality modeling system has been widely used for long term, steady state water quality analysis. However, users have increasingly requested a dynamic version of SPARROW that can provide seasonal estimates of nutrients and suspended sediment to receiving waters. The goal of this NASA-funded project is to develop a dynamic decision support system to enhance the southeast SPARROW water quality model and finer-scale dynamic models for selected coastal watersheds through the use of remotely-sensed data and other NASA Land Information System (LIS) products. The spatial and temporal scale of satellite remote sensing products and LIS modeling data make these sources ideal for the purposes of development and operation of the dynamic SPARROW model. Remote sensing products including MODIS vegetation indices, SMAP surface soil moisture, and OMI atmospheric chemistry along with LIS-derived evapotranspiration (ET) and soil temperature and moisture products will be included in model development and operation. MODIS data will also be used to map annual land cover/land use in the study areas and in conjunction with Landsat and Sentinel to identify disturbed areas that might be sources of sediment and increased phosphorus loading through exposure of the bare soil. These data and others constitute the independent variables in a regression analysis whose dependent variables are the water quality constituents total nitrogen, total phosphorus, and suspended sediment. Remotely-sensed variables such as vegetation indices and ET can be proxies for nutrient uptake by vegetation; MODIS Leaf Area Index can indicate sources of phosphorus from vegetation; soil moisture and temperature are known to control rates of denitrification; and bare soil areas serve as sources of enhanced nutrient and sediment production. The enhanced SPARROW dynamic models will provide improved tools for end users to manage water quality in near real time and for the formulation of future scenarios to inform strategic planning. Time-varying SPARROW outputs will aid water managers in decision making regarding allocation of resources in protecting aquatic habitats, planning for harmful algal blooms, and restoration of degraded habitats, stream segments, or lakes.

  19. Organic-Carbon Sequestration in Soil/Sediment of the Mississippi River Deltaic Plain - Data; Landscape Distribution, Storage, and Inventory; Accumulation Rates; and Recent Loss, Including a Post-Katrina Preliminary Analysis (Chapter B)

    USGS Publications Warehouse

    Markewich, Helaine W.; Buell, Gary R.; Britsch, Louis D.; McGeehin, John P.; Robbins, John A.; Wrenn, John H.; Dillon, Douglas L.; Fries, Terry L.; Morehead, Nancy R.

    2007-01-01

    Soil/sediment of the Mississippi River deltaic plain (MRDP) in southeastern Louisiana is rich in organic carbon (OC). The MRDP contains about 2 percent of all OC in the surface meter of soil/sediment in the Mississippi River Basin (MRB). Environments within the MRDP differ in soil/sediment organic carbon (SOC) accumulation rate, storage, and inventory. The focus of this study was twofold: (1) develop a database for OC and bulk density for MRDP soil/sediment; and (2) estimate SOC storage, inventory, and accumulation rates for the dominant environments (brackish, intermediate, and fresh marsh; natural levee; distributary; backswamp; and swamp) in the MRDP. Comparative studies were conducted to determine which field and laboratory methods result in the most accurate and reproducible bulk-density values for each marsh environment. Sampling methods included push-core, vibracore, peat borer, and Hargis1 sampler. Bulk-density data for cores taken by the 'short push-core method' proved to be more internally consistent than data for samples collected by other methods. Laboratory methods to estimate OC concentration and inorganic-constituent concentration included mass spectrometry, coulometry, and loss-on-ignition. For the sampled MRDP environments, these methods were comparable. SOC storage was calculated for each core with adequate OC and bulk-density data. SOC inventory was calculated using core-specific data from this study and available published and unpublished pedon data linked to SSURGO2 map units. Sample age was estimated using isotopic cesium (137Cs), lead (210Pb), and carbon (14C), elemental Pb, palynomorphs, other stratigraphic markers, and written history. SOC accumulation rates were estimated for each core with adequate age data. Cesium-137 profiles for marsh soil/sediment are the least ambiguous. Levee and distributary 137Cs profiles show the effects of intermittent allochthonous input and/or sediment resuspension. Cesium-137 and 210Pb data gave the most consistent and interpretable information for age estimations of soil/sediment deposited during the 1900s. For several cores, isotopic 14C and 137Cs data allowed the 1963-64 nuclear weapons testing (NWT) peak-activity datum to be placed within a few-centimeter depth interval. In some cores, a too old 14C age (when compared to 137Cs and microstratigraphic-marker data) is the probable result of old carbon bound to clay minerals incorporated into the organic soil/sediment. Elemental Pb coupled with Pb source-function data allowed age estimation for soil/sediment that accumulated during the late 1920s through the 1980s. Exotic pollen (for example, Vigna unguiculata and Alternanthera philoxeroides) and other microstratigraphic indicators (for example, carbon spherules) allowed age estimations for marsh soil/sediment deposited during the settlement of New Orleans (1717-20) through the early 1900s. For this study, MRDP distributary and swamp environments were each represented by only one core, backswamp environment by two cores, all other environments by three or more cores. MRDP core data for the surface meter soil/sediment indicate that (1) coastal marshes, abandoned distributaries, and swamps have regional SOC-storage values >16 kg m-2; (2) swamps and abandoned distributaries have the highest SOC storage values (swamp, 44.8 kg m-2; abandoned distributary, 50.9 kg m-2); (3) fresh-to-brackish marsh environments have the second highest site-specific SOC-storage values; and (4) site-specific marsh SOC storage values decrease as the salinity of the environment increases (fresh-marsh, 36.2 kg m-2; intermediate marsh, 26.2 kg m-2; brackish marsh, 21.5 kg m-2). This inverse relation between salinity and SOC storage is opposite the regional systematic increase in SOC storage with increasing salinity that is evident when SOC storage is mapped by linking pedon data to SSURGO map units (fresh marsh, 47 kg m-2; intermediate marsh, 67 kg m-2; brackish marsh, 75 kg m-2; and salt marsh, 80 kg m-2). MRDP core data for this study also indicate that levees and backswamp have regional SOC-storage values <16 kg m-2. Group-mean SOC storage for cores from these environments are natural levee (17.0 kg m-2) and backswamp (14.1 kg m-2). An estimate for the SOC inventory in the surface meter of soil/sediment in the MRDP can be made using the SSURGO mapped portion of the coastal-marsh vegetative-type map (13,236 km2, land-only area) published by the Louisiana Department of Wildlife and Fisheries and U.S. Geological Survey (1997). This area has a SOC inventory (surface meter) of 677 Tg (slightly more than 2 percent of the 30,289 Tg SOC inventory for the MRB). The MRDP (6,180 km2, land-only area) has an estimated SOC inventory of 397 Tg. Most of the MRDP is located within the SSURGO mapped coastal marshlands. The entire MRDP, including water, has an area of about 10,800 km2. Using the ratio of total MRDP area to SSURGO mapped MRDP area as an adjustment, the MRDP SOC inventory is estimated at 694 Tg. This larger estimate of 694 Tg for the SOC inventory is probably more realistic, because it is reasonable to assume that the marsh sediments overlain by shallow water have comparable SOC storage to that of the adjacent land areas. MRDP core data for this study indicate that there is some variability in long-term SOC mass-accumulation rates for centuries and millennia and that this variability may indicate important geologic changes or changes in land use. However, the consistency of the range in rates of SOC accumulation through time suggests a remarkable degree of marsh sustainability throughout the Holocene, including the recent period of significant marsh modification/channelization for human use. One example of marsh sustainability is its present ability to function as a SOC sink even with Louisiana's large-scale coastal land loss during the last several decades. With coastal-marsh restoration efforts, this sink potential will increase. Looking to the future, a total of 1,101 g m-2 yr-1 SOC is projected to be lost from all of coastal Louisiana (U.S. Army Corps of Engineers, Louisiana Coastal Area (LCA) subprovinces 1-4; not just the MRDP) through coastal erosion from year 2000 to 2050. This translates to a projected SOC-loss rate of about 0.20 percent per year. The recent Hurricanes Katrina and Rita, which devastated the Louisiana coast during late August and late September 2005, transformed about 259 km2 (100 mi2) of marsh to open water (U.S. Geological Survey, 2005). To the extent that some or all of this land loss is permanent, this result equates to a SOC loss of about 15 Tg. This estimate is based on the year-2000 15,153-km2 land area for the LCA study area that includes LCA subprovince 4. Using the year-2000 land area, the LCA study area had an estimated SOC inventory of 858 Tg. The estimated 15 Tg SOC loss attributable to Hurricanes Katrina and Rita is 1.7 percent of the year-2000 LCA inventory and 2.3 percent of the year-2000 MRDP inventory. If this SOC loss is included in the projection for the year 2050, then the MRDP would either remain a source with a net SOC loss of 3 Tg or become a weak sink with a net SOC gain of 4 Tg. These estimates are lower bounds for potential SOC flux because they are only for the surface meter of landmass.

  20. Spies and Bloggers: New Synthetic Biology Tools to Understand Microbial Processes in Soils and Sediments

    NASA Astrophysics Data System (ADS)

    Masiello, C. A.; Silberg, J. J.; Cheng, H. Y.; Del Valle, I.; Fulk, E. M.; Gao, X.; Bennett, G. N.

    2017-12-01

    Microbes can be programmed through synthetic biology to report on their behavior, informing researchers when their environment has triggered changes in their gene expression (e.g. in response to shifts in O2 or H2O), or when they have participated in a specific step of an elemental cycle (e.g. denitrification). This use of synthetic biology has the potential to significantly improve our understanding of microbes' roles in elemental and water cycling, because it allows reporting on the environment from the perspective of a microbe, matching the measurement scale exactly to the scale that a microbe experiences. However, synthetic microbes have not yet seen wide use in soil and sediment laboratory experiments because synthetic organisms typically report by fluorescing, making their signals difficult to detect outside the petri dish. We are developing a new suite of microbial programs that report instead by releasing easily-detected gases, allowing the real-time, noninvasive monitoring of behaviors in sediments and soils. Microbial biosensors can, in theory, be programmed to detect dynamic processes that contribute to a wide range of geobiological processes, including C cycling (biofilm production, methanogenesis, and synthesis of extracellular enzymes that degrade organic matter), N cycling (expression of enzymes that underlie different steps of the N cycle) and potentially S cycling. We will provide an overview of the potential uses of gas-reporting biosensors in soil and sediment lab experiments, and will report the development of the systematics of these sensors. Successful development of gas biosensors for laboratory use will require addressing issues including: engineering the intensity and selectivity of microbial gas production to maximize the signal to noise ratio; normalizing the gas reporter signal to cell population size, managing gas diffusion effects on signal shape; and developing multiple gases that can be used in parallel.

  1. Phytoremediation as a management option for contaminated sediments in tidal marshes, flood control areas and dredged sediment landfill sites.

    PubMed

    Bert, Valérie; Seuntjens, Piet; Dejonghe, Winnie; Lacherez, Sophie; Thuy, Hoang Thi Thanh; Vandecasteele, Bart

    2009-11-01

    Polluted sediments in rivers may be transported by the river to the sea, spread over river banks and tidal marshes or managed, i.e. actively dredged and disposed of on land. Once sedimented on tidal marshes, alluvial areas or control flood areas, the polluted sediments enter semi-terrestrial ecosystems or agro-ecosystems and may pose a risk. Disposal of polluted dredged sediments on land may also lead to certain risks. Up to a few years ago, contaminated dredged sediments were placed in confined disposal facilities. The European policy encourages sediment valorisation and this will be a technological challenge for the near future. Currently, contaminated dredged sediments are often not valorisable due to their high content of contaminants and their consequent hazardous properties. In addition, it is generally admitted that treatment and re-use of heavily contaminated dredged sediments is not a cost-effective alternative to confined disposal. For contaminated sediments and associated disposal facilities used in the past, a realistic, low cost, safe, ecologically sound and sustainable management option is required. In this context, phytoremediation is proposed in the literature as a management option. The aim of this paper is to review the current knowledge on management, (phyto)remediation and associated risks in the particular case of sediments contaminated with organic and inorganic pollutants. This paper deals with the following features: (1) management and remediation of contaminated sediments and associated risk assessment; (2) management options for ecosystems on polluted sediments, based on phytoremediation of contaminated sediments with focus on phytoextraction, phytostabilisation and phytoremediation of organic pollutants and (3) microbial and mycorrhizal processes occurring in contaminated sediments during phytoremediation. In this review, an overview is given of phytoremediation as a management option for semi-terrestrial and terrestrial ecosystems affected by polluted sediments, and the processes affecting pollutant bioavailability in the sediments. Studies that combine contaminated sediment and phytoremediation are relatively recent and are increasing in number since few years. Several papers suggest including phytoremediation in a management scheme for contaminated dredged sediments and state that phytoremediation can contribute to the revaluation of land-disposed contaminated sediments. The status of sediments, i.e. reduced or oxidised, highly influences contaminant mobility, its (eco)toxicity and the success of phytoremediation. Studies are performed either on near-fresh sediment or on sediment-derived soil. Field studies show temporal negative effects on plant growth due to oxidation and subsequent ageing of contaminated sediments disposed on land. The review shows that a large variety of plants and trees are able to colonise or develop on contaminated dredged sediment in particular conditions or events (e.g. high level of organic matter, clay and moisture content, flooding, seasonal hydrological variations). Depending on the studies, trees, high-biomass crop species and graminaceous species could be used to degrade organic pollutants, to extract or to stabilise inorganic pollutants. Water content of sediment is a limiting factor for mycorrhizal development. In sediment, specific bacteria may enhance the mobilisation of inorganic contaminants whereas others may participate in their immobilisation. Bacteria are also able to degrade organic pollutants. Their actions may be increased in the presence of plants. Choice of plants is particularly crucial for phytoremediation success on contaminated sediments. Extremely few studies are long-term field-based studies. Short-term effects and resilience of ecosystems is observed in long-term studies, i.e. due to degradation and stabilisation of pollutants. Terrestrial ecosystems affected by polluted sediments range from riverine tidal marshes with several interacting processes and vegetation development mainly determined by hydrology, over alluvial soils affected by overbank sedimentation (including flood control areas), to dredged sediment disposal facilities where hydrology and vegetation might be affected or managed by human intervention. This gradient is also a gradient of systems with highly variable soil and hydrological conditions in a temporal scale (tidal marshes) versus systems with a distinct soil development over time (dredged sediment landfill sites). In some circumstances (e.g. to avoid flooding or to ensure navigation) dredging operations are necessary. Management and remediation of contaminated sediments are necessary to reduce the ecological risks and risks associated with food chain contamination and leaching. Besides disposal, classical remediation technologies for contaminated sediment also extract or destroy contaminants. These techniques imply the sediment structure deterioration and prohibitive costs. On the contrary, phytoremediation could be a low-cost option, particularly suited to in situ remediation of large sites and environmentally friendly. However, phytoremediation is rarely included in the management scheme of contaminated sediment and accepted as a viable option. Phytoremediation is still an emerging technology that has to prove its sustainability at field scale. Research needs to focus on optimisations to enhance applicability and to address the economic feasibility of phytoremediation.

  2. Analyzing ecological restoration strategies for water and soil conservation

    PubMed Central

    Mota da Silva, Jonathan; Silva, Marx Leandro Naves; Guimarães, João Luis Bittencourt; Sousa Júnior, Wilson Cabral; Figueiredo, Ricardo de Oliveira; da Rocha, Humberto Ribeiro

    2018-01-01

    The choice of areas for nature conservation involves the attempt to maximize the benefits, whether by carrying out an economic activity or by the provision of Ecosystem Services. Studies are needed to improve the understanding of the effect of the extent and position along the watershed of restored areas on soil and water conservation. This study aimed to understand how different restoration strategies might reflect in soil conservation and sediment retention. Using InVEST tool, sediment transport was simulated in a small 12 km2 watershed (Posses River, in Southeast Brazil), where one of first Brazilian Payment for Ecosystem Services (PES) projects is being carried out, comparing different hypothetical restoration strategies. With 25% of restoration, sediment export decreased by 78% for riparian restoration, and 27% for the steepest slopes restoration. On the other hand, the decrease in soil loss was lower for riparian restoration, with a 16% decrease, while the steepest slopes restoration reduced it by 21%. This mismatch between the reduction of sediment export and soil loss was explained by the fact that forest not only reduces soil loss locally but also traps sediment arriving from the upper parts of the watershed. While the first mechanism is important to provide soil stability, decreasing the risk of landslip, and to maintain agricultural productivity, the second can improve water quality and decrease the risk of silting, with positive effects on the water reservoirs at the outlet of the watershed. This suggests that Riparian and the Steepest Slopes restoration strategies are complementary in the sense of preventing sediments from reaching the water bodies as well as protecting them at their origin (with the reduction of erosion), so it will be advisable to consider the two types of restoration. PMID:29425214

  3. Analyzing ecological restoration strategies for water and soil conservation.

    PubMed

    Saad, Sandra Isay; Mota da Silva, Jonathan; Silva, Marx Leandro Naves; Guimarães, João Luis Bittencourt; Sousa Júnior, Wilson Cabral; Figueiredo, Ricardo de Oliveira; Rocha, Humberto Ribeiro da

    2018-01-01

    The choice of areas for nature conservation involves the attempt to maximize the benefits, whether by carrying out an economic activity or by the provision of Ecosystem Services. Studies are needed to improve the understanding of the effect of the extent and position along the watershed of restored areas on soil and water conservation. This study aimed to understand how different restoration strategies might reflect in soil conservation and sediment retention. Using InVEST tool, sediment transport was simulated in a small 12 km2 watershed (Posses River, in Southeast Brazil), where one of first Brazilian Payment for Ecosystem Services (PES) projects is being carried out, comparing different hypothetical restoration strategies. With 25% of restoration, sediment export decreased by 78% for riparian restoration, and 27% for the steepest slopes restoration. On the other hand, the decrease in soil loss was lower for riparian restoration, with a 16% decrease, while the steepest slopes restoration reduced it by 21%. This mismatch between the reduction of sediment export and soil loss was explained by the fact that forest not only reduces soil loss locally but also traps sediment arriving from the upper parts of the watershed. While the first mechanism is important to provide soil stability, decreasing the risk of landslip, and to maintain agricultural productivity, the second can improve water quality and decrease the risk of silting, with positive effects on the water reservoirs at the outlet of the watershed. This suggests that Riparian and the Steepest Slopes restoration strategies are complementary in the sense of preventing sediments from reaching the water bodies as well as protecting them at their origin (with the reduction of erosion), so it will be advisable to consider the two types of restoration.

  4. [Effects of sub-watershed landscape patterns at the upper reaches of Minjiang River on soil erosion].

    PubMed

    Yang, Meng; Li, Xiu-zhen; Yang, Zhao-ping; Hu, Yuan-man; Wen, Qing-chun

    2007-11-01

    Based on GIS, the spatial distribution of soil loss and sediment yield in Heishui and Zhenjiangguan sub-watersheds at the upper reaches of Minjiang River was simulated by using sediment delivery-distribution (SEDD) model, and the effects of land use/cover types on soil erosion and sediment yield were discussed, based on the simulated results and related land use maps. A landscape index named location-weighted landscape contrast index (LCI) was calculated to evaluate the effects of landscape components' spatial distribution, weight, and structure of land use/cover on soil erosion. The results showed the soil erosion modulus varied with land use pattern, and decreased in the order of bare rock > urban/village > rangeland > farmland > shrub > forest. There were no significant differences in sediment yield modules among different land use/covers. In the two sub-watersheds, the spatial distribution of land use/covers on slope tended to decrease the final sediment load at watershed outlet, hut as related to relative elevation, relative distance, and flow length, the spatial distribution tended to increase sediment yield. The two sub-watersheds had different advantages as related to landscape components' spatial distribution, but, when the land use/cover weight was considered, the advantages of Zhenjiangguan sub-watershed increased. If the land use/cover structure was considered in addition, the landscape pattern of Zhenjiangguan subwatershed was better. Therefore, only the three elements, i.e., landscape components' spatial distribution, land use/cover weight, and land use/cover structure, were considered comprehensively, can we get an overall evaluation on the effects of landscape pattern on soil erosion. The calculation of LCI related to slope suggested that this index couldn' t accurately reflect the effects of land use/cover weight and structure on soil erosion, and thus, needed to be modified.

  5. Hydrologic connectivity to streams increases nitrogen and phosphorus inputs and cycling in soils of created and natural floodplain wetlands

    USGS Publications Warehouse

    Wolf, Kristin L.; Noe, Gregory B.; Ahn, Changwoo

    2013-01-01

    Greater connectivity to stream surface water may result in greater inputs of allochthonous nutrients that could stimulate internal nitrogen (N) and phosphorus (P) cycling in natural, restored, and created riparian wetlands. This study investigated the effects of hydrologic connectivity to stream water on soil nutrient fluxes in plots (n = 20) located among four created and two natural freshwater wetlands of varying hydrology in the Piedmont physiographic province of Virginia. Surface water was slightly deeper; hydrologic inputs of sediment, sediment-N, and ammonium were greater; and soil net ammonification, N mineralization, and N turnover were greater in plots with stream water classified as their primary water source compared with plots with precipitation or groundwater as their primary water source. Soil water-filled pore space, inputs of nitrate, and soil net nitrification, P mineralization, and denitrification enzyme activity (DEA) were similar among plots. Soil ammonification, N mineralization, and N turnover rates increased with the loading rate of ammonium to the soil surface. Phosphorus mineralization and ammonification also increased with sedimentation and sediment-N loading rate. Nitrification flux and DEA were positively associated in these wetlands. In conclusion, hydrologic connectivity to stream water increased allochthonous inputs that stimulated soil N and P cycling and that likely led to greater retention of sediment and nutrients in created and natural wetlands. Our findings suggest that wetland creation and restoration projects should be designed to allow connectivity with stream water if the goal is to optimize the function of water quality improvement in a watershed.

  6. Monitoring aggregate disintegration with laser diffraction: A tool for studying soils as sediments

    NASA Astrophysics Data System (ADS)

    Mason, Joseph; Kasmerchak, Chase; Liang, Mengyu

    2016-04-01

    One of the more important characteristics of soil that becomes hillslope, fluvial, or aeolian sediment is the presences of aggregates, which disintegrate at varying rates and to varying degrees during transport. Laser diffraction particle size analyzers allow monitoring of aggregate disintegration as a sample of soil or sediment suspended in water is circulated continuously through the measurement cell (Bieganowski et al., 2010, Clay Minerals 45-23-34; Mason et al., Catena 87:107-118). Mason et al. (2011) applied this approach to aeolian sedimentary aggregates (e.g. clay pellets eroded from dry lakebeds), immersing dry samples in DI water and circulating them through a Malvern Mastersizer 2000 particle size analyzer for three hours while repeated size distribution (SD) measurements were made. A final measurement was made after sonication and treatment with Na-metaphosphate. In that study, most samples approached a steady SD within three hours, which included both primary mineral grains and persistent aggregates. The disintegration process could be modeled with a first-order rate law representing the disintegration of a single population of aggregates. A wide range of model parameters were observed among the samples studied, and it was suggested that they could be useful in predicting the behavior of these aggregates, under rainfall impact and during slopewash or fluvial transport. Addition of Ca++ to the suspension altered aggregate behavior in some but not all cases. We applied the same method to dry, unground material from upper horizons of soils sampled along a bioclimatic gradient in northern Minnesota, USA, all formed in lithologically similar glacigenic sediment. These ranged from Alfisols (Luvisols) formed under forest since the last deglaciation, to Alfisols under forest that more recently replaced grassland, and Mollisols (Chernozems) that formed entirely under grassland vegetation. Few of these soil samples approached a steady SD within three hours, and modeling aggregate disintegration required the assumption of at least two aggregate populations. Upper horizons of soils formed under grassland displayed relatively slow disintegration throughout the procedure, with a large proportion of aggregates remaining after three hours. E horizons from forest soils, with low organic matter (OM) and clay content, displayed rapid early distintegration of a large portion of the aggregates, followed by much slower breakdown of the remainder (i.e. the two populations modeled had very different rate constants). OM content is clearly the overriding control on aggregate behavior, but we are also exploring effects of clay content and mineralogy, cation chemistry, and other factors. The differences in aggregate behavior are likely to be relevant to transport and deposition of sediment eroded from these soils, and possibly to the transport of OM or nutrients with eroded soil. We hope to incorporate this method into ongoing field studies of soil erosion with colleagues at UW-Madison.

  7. Screening of polymers on selected Hawaii soils for erosion reduction and particle settling

    NASA Astrophysics Data System (ADS)

    Teo, James A.; Ray, Chittaranjan; El-Swaify, Samir A.

    2006-01-01

    In recent years, high-molecular-weight anionic polyacrylamides (PAMs) have been tested on a variety of soils, primarily in temperate climates. However, little information is available regarding the effectiveness of PAM for preventing soil loss through runoff in tropical settings. Screening tests were performed using three negatively charged PAMs and one positively charged PAM on five Hawaii soils (two Oxisols, one Vertisol, and two Aridisols) to determine erosion loss, sediment settling, and aggregate stability. A laboratory-scale rainfall simulator was used to apply erosive rainfall at intensities from 5 to 8.5 cm h-1 at various PAM doses applied in both dry and solution forms. Soil detachment due to splash and runoff, as well as the runoff and percolate water volumes, were measured for initial and successive storms. The impact of PAM on particle settling and aggregate stability was also evaluated for selected soil-treatment combinations. Among the PAMs, Superfloc A-836 was most effective, and significantly reduced runoff and splash sediment loss for the Wahiawa Oxisol and Pakini Andisol at rates varying between 10 and 50 kg ha-1. Reduced runoff and splash sediment loss were also noted for PAM Aerotil-D when applied in solution form to the Wahiawa Oxisol. Significant reductions in soil loss were not noted for either the Lualualei Vertisol or the Holomua Oxisol. It is believed that the high montmorillonite content of the Lualualei Vertisol and the low cation-exchange capacity of the Holomua Oxisol diminished the effectiveness of the various PAMs tested. The polymers were also found to enhance sediment settling of all soils and helped improve their aggregate stability. This screening study shows the potential use of PAM for tropical soils for applications such as infiltration enhancement, runoff reduction, and enhanced sedimentation of detention ponds.

  8. Mineralogical Controls on Carbon Cycling in a Floodplain Environment

    NASA Astrophysics Data System (ADS)

    Arora, B.; Dwivedi, D.; Steefel, C. I.; Spycher, N.; Fox, P. M.; Nico, P. S.

    2016-12-01

    With the overarching goal of understanding mineral-organic-microbe interactions on carbon and nutrient cycles, we are developing a reactive transport model that includes carbon (C) pools and transformations, a realistic treatment of protected C pools, multiple decomposition pathways, and radiocarbon (14C) dynamics. The objective of the modeling is to understand the impact of mineralogy on carbon turnover and residence times in a floodplain site in Rifle, CO. Previous studies have identified naturally reduced zones (NRZs) in the saturated zone of the Rifle site to be C hotspots and regions characterized by diffusion-limited transport and high rates of microbially-mediated biogeochemical reactions. Detailed characterization of the soil organic matter in both the NRZ and non-NRZ sediments at the Rifle site including radiocarbon dating, and extraction and chemical characterization of mineral-bound pool of organic matter, is used to inform the modeling. In this study, we describe the development of a coupled unsaturated-saturated flow and biogeochemical reactive transport model of the Rifle site along a two-dimensional cross-section (parallel to groundwater flow). The biogeochemical reaction network includes representations of bacterial and fungal activity, archetypal polymer and monomer carbon substrate groups, kinetic and equilibrium mineral precipitation and dissolution reactions, and aqueous and surface complexation. We use this model to explore fungal and bacterial community emergence at the site and compare organo-mineral interactions across NRZ and non-NRZ regions. Observed 14C profiles suggest that sediment-associated carbon in NRZ locations is much older than both the depositional age of the floodplain sediments and dissolved organic carbon in the groundwater. Model simulations were able to capture the observed soil organic matter (SOM) and Δ14C profiles across the Rifle site. Modeling results show higher lignin content in the NRZ sediments and greater Fe-associated organic carbon as compared to non-NRZ locations. Results therefore suggest that soil mineralogy constitutes a dominant control over organic carbon stocks and residence times. A mechanistic representation of soil mineral-organic-microbe interactions is necessary to reproduce SOM profiles at the site.

  9. A Layered Past: the Transformation and Development of Legacy Sediments as Alluvial Soils

    NASA Astrophysics Data System (ADS)

    Wade, A.; Richter, D. D., Jr.

    2017-12-01

    Legacy sediments are a widespread consequence of post-colonial upland erosion in the United States. Although these deposits are ubiquitous in valley bottoms of the southeastern Piedmont, mature hardwood forests and collapsed stream banks mask their occurrence. While these deposits have been studied for their fluvial dynamics and water quality impacts, they have received less attention in regards to soil structure and formation. In this study, we characterized legacy sediment mineraology, composition and structure to understand how pedogenic processes are overprinting sediment layering in a 40-hectare Piedmont floodplain. To constrain the timing of deposition, we used Pb-210 and C-14 dating on buried charcoal and tree stumps. Our results show that in 100 years of forest regeneration, vegetation and oscillating floodplain conditions have driven these eroded sediment deposits to evolve as soil profiles both in structure and composition. These textural and nutrient gradients have ramifications for the subsurface flow of nutrients through the floodplain. Given the estimated millennia it will take to erode legacy sediment from Piedmont floodplains, it is important to think of these deposits as new stable environments on their own trajectory of soil evolution.

  10. Soil Black Carbon Loss and Sediment Black Carbon Accumulation in a Central Texas Woodland

    NASA Astrophysics Data System (ADS)

    Schieve, E. A.; Hockaday, W. C.; White, J. D.

    2016-12-01

    The Balcones Canyonlands National Wildlife Refuge is located along the eastern edge of the Edwards Plateau in Texas, and was established in 1992 for the purpose of conserving habitat for two endangered bird species. The landscape is composed of hilly, mesa-valley terrain, which is mostly covered by grasslands and woodlands dominated by juniper with intermingling of various oak species. Based on historical photo analysis and tree fire scar dendrochronology, the area has experienced major land use changes over the last century due to wildfire, logging, and drought affecting soil stability and woodland species composition. A previous study on soil black carbon showed that site-specific soil erosion potential and time since last fire may act as controls on soil black carbon concentrations. However, the black carbon transport flux, depositional fate, or the magnitude of soil erosion effects upon the black carbon budget are unconstrained at the watershed scale. To address this, we sampled the sediments accumulating in small ponds constructed during the 1950's for livestock watering. We are quantifying black carbon in sediments using solid-state 13C nuclear magnetic resonance spectroscopy. Preliminary data suggest that the pond sediments are a black carbon sink. Black carbon comprises 15 % - 25 %, of the sedimentary organic carbon, as substantial enrichment relative to soils within the watershed. We will present an early assessment of the black carbon erosion and sediment accumulation rates in first- and second-order watersheds.

  11. Review on utilization of biochar for metal-contaminated soil and sediment remediation.

    PubMed

    Wang, Mingming; Zhu, Yi; Cheng, Lirong; Andserson, Bruce; Zhao, Xiaohui; Wang, Dayang; Ding, Aizhong

    2018-01-01

    Biochar is a carbon-neutral or even carbon-negative material produced through thermal decomposition of plant- and animal-based biomass under oxygen-limited conditions. Recently, there has been an increasing interest in the application of biochar as an adsorbent, soil ameliorant and climate mitigation approach in many types of applications. Metal-contaminated soil remediation using biochar has been intensively investigated in small-scale and pilot-scale trials with obtained beneficial results and multifaceted effects. But so far, the study and application of biochar in contaminated sediment management has been very limited, and this is also a worldwide problem. Nonetheless, there is reason to believe that the same multiple benefits can also be realized with these sediments due to similar mechanisms for stabilizing contaminants. This paper provides a review on current biochar properties and its use as a sorbent/amendment for metal-contaminated soil/sediment remediation and its effect on plant growth, fauna habits as well as microorganism communities. In addition, the use of biochar as a potential strategy for contaminated sediment management is also discussed, especially as regards in-situ planning. Finally, we highlight the possibility of biochar application as an effective amendment and propose further research directions to ensure the safe and sustainable use of biochar as an amendment for remediation of contaminated soil and sediment. Copyright © 2017. Published by Elsevier B.V.

  12. Grain size associations of branched tetraether lipids in soils and riverbank sediments: influence of hydrodynamic sorting processes

    NASA Astrophysics Data System (ADS)

    Peterse, Francien; Eglinton, Timothy I.

    2017-06-01

    We analyzed the abundance and distribution of branched glycerol dialkyl glycerol tetraethers (brGDGTs) in grain size fractions of 7 globally distributed river flank sediments and catchment soils in order to determine if and how the initial soil-brGDGT signature is influenced by hydrodynamic sorting upon entering a river and during subsequent transport from land to sea. BrGDGTs are hypothesized to form associations with high-surface-area fine-grained minerals in soils. Such associations, if maintained during transport, may impart resistance to degradation and promote downstream transport, reducing potential interferences by aquatic brGDGTs. We find that brGDGTs are indeed primarily associated with organic carbon (OC) bound to the clay-silt fraction (<63μm) in both soils and river sediments, and that these associations appear to be maintained during river transport. However, the relative distribution of individual brGDGTs among size fractions is relatively uniform, suggesting that brGDGTs are well mixed in river sediments and that OC-mineral associations are continuously renewed. Consequently, the brGDGT signature finally stored in continental margin sediments appears insensitive to differential particle transport processes. Nevertheless, the lower (upstream) temperature signal generally reflected by brGDGTs in river sediments may also be explained by a contribution of in situ produced brGDGTs leading to an underestimation of reconstructed air temperatures.

  13. RECOVERY OF DNA FROM SOILS AND SEDIMENTS

    EPA Science Inventory

    Experiments were performed to evaluate the effectiveness of different methodological approaches for recovering DNA from soil and sediment bacterial communities; cell extraction followed by lysis and DNA recovery (cell extraction method) versus direct cell lysis and alkaline extra...

  14. Improved Flotation Technique for Microscopy of In Situ Soil and Sediment Microorganisms

    PubMed Central

    Bone, T. L.; Balkwill, D. L.

    1986-01-01

    An improved flotation method for microscopy of in situ soil and sediment microorganisms was developed. Microbial cells were released into gellike flotation films that were stripped from soil and sediment aggregates as these aggregates were submerged in 0.5% solutions of polyvinylpyrrolidone. The use of polyvinylpyrrolidone solutions instead of water facilitated the release of films from saturated samples such as aquifer sediments as well as from typical surface soils. In situ microbial morphological characteristics could then be surveyed rapidly by light microscopy of films stained with acridine orange. This method effectively determined the ranges of morphological diversity in a variety of sample types. It also detected microcolonies and other spatial relationships among microbial cells. Only a small fraction (3.4 to 10.1%) of the microflora was released into the flotation films, but plating and direct evaluations by microscopy showed that this fraction was representative of the total population. Images PMID:16347005

  15. Investigation of Pb species in soils, celery and duckweed by synchrotron radiation X-ray absorption near-edge structure spectrometry

    NASA Astrophysics Data System (ADS)

    Luo, Liqiang; Shen, Yating; Liu, Jian; Zeng, Yuan

    2016-08-01

    The Pb species play a key role in its translocation in biogeochemical cycles. Soils, sediments and plants were collected from farmlands around Pb mines, and the Pb species in them was identified by X-ray absorption near-edge structure spectrometry. In soils, Pb5(PO4)3Cl and Pb3(PO4)2 were detected, and in sediments, Pb-fulvic acids (FAs) complex was identified. A Pb complex with FA fragments was also detected in celery samples. We found that (1) different Pb species were present in soils and sediments; (2) the Pb species in celery, which was grown in sediments, was different from the species present in duckweed, which grew in water; and (3) a Pb-FA-like compound was present in celery roots. The newly identified Pb species, the Pb-FA-like compound, may play a key role in Pb tolerance and translocation within plants.

  16. Driving forces and their contribution to the recent decrease in sediment flux to ocean of major rivers in China.

    PubMed

    Li, Tong; Wang, Shuai; Liu, Yanxu; Fu, Bojie; Zhao, Wenwu

    2018-09-01

    Understanding the mechanisms behind land-ocean sediment transport processes is crucial, due to the resulting impacts on the sustainable management of water and soil resources. This study investigated temporal trends and historical phases of sediment flux delivered to the sea by nine major rivers in China, while also quantifying the contribution of key anthropogenic and natural driving forces. During the past six decades, sediment flux from these nine major rivers exhibited a statistically significant negative trend, decreasing from 1.92Gtyr -1 during 1954-1968 to 1.39Gtyr -1 , 0.861Gtyr -1 and 0.335Gtyr -1 during 1969-1985, 1986-1999 and 2000-2016, respectively. We used a recently developed Sediment Identity approach and found that the sharp decrease in sediment load observed across China was mainly (~95%) caused by a reduction in sediment concentration. Reservoir construction exerted the strongest influence on land-ocean sediment fluxes, while soil conservation measures represented a secondary driver. Before 1999, soil erosion was not controlled effectively in China and reservoirs, especially large ones, played a dominant role in reducing riverine sediments. After 1999, soil erosion has gradually been brought under control across China, so that conservation measures directly accounted for ~40% of the observed decrease in riverine sediments. With intensifying human activities, it is predicted that the total sediment flux delivered to the sea by the nine major rivers will continue to decrease in the coming decades, although at a slower rate, resulting in severe challenges for the sustainable management of drainage basins and river deltas. Copyright © 2018 Elsevier B.V. All rights reserved.

  17. A mathematical model of reservoir sediment quality prediction based on land-use and erosion processes in watershed

    NASA Astrophysics Data System (ADS)

    Junakova, N.; Balintova, M.; Junak, J.

    2017-10-01

    The aim of this paper is to propose a mathematical model for determining of total nitrogen (N) and phosphorus (P) content in eroded soil particles with emphasis on prediction of bottom sediment quality in reservoirs. The adsorbed nutrient concentrations are calculated using the Universal Soil Loss Equation (USLE) extended by the determination of the average soil nutrient concentration in top soils. The average annual vegetation and management factor is divided into five periods of the cropping cycle. For selected plants, the average plant nutrient uptake divided into five cropping periods is also proposed. The average nutrient concentrations in eroded soil particles in adsorbed form are modified by sediment enrichment ratio to obtain the total nutrient content in transported soil particles. The model was designed for the conditions of north-eastern Slovakia. The study was carried out in the agricultural basin of the small water reservoir Klusov.

  18. Soil erosion transport through multiple rainfall events in the presence of stone cover: Laboratory flume experiments and analysis with the Hairsine-Rose model

    NASA Astrophysics Data System (ADS)

    Jomaa, S.; Barry, D. A.; Brovelli, A.; Heng, B. P.; Sander, G. C.; Parlange, J.

    2011-12-01

    Soil erosion is a major environmental problem that can lead to loss of fertility and degradation of agricultural fields. In order to develop efficient strategies to mitigate the impact of precipitation and reduce the erosion rate, a process-based understanding of the mechanisms that govern sediment transport and delivery is necessary. Soil state and physical properties prior to a precipitation event can affect significantly the erosion rate. Among the most important soil variables are moisture content, compaction and infiltration capacity. Additionally, the presence of stones on the topsoil surface retards the overland flow discharge, reduces runoff generation as well as the sediment delivery and prevents the development of a surface seal, which in turn maintains the infiltration rate. The aim of this study was to examine in detail the effect of surface stones, soil compaction and sealing for a sequence of rainfall events on soil erosion. Experiments were conducted using the EPFL erosion flume, which was divided into two identical flumes (one with stone and one without). The experiment involved four rainfall events with the precipitation rates: 28, 74, 74 and 28 mm h-1. After each 2-h event, the soil was allowed to air dry for 22 h. The total sediment concentration, the concentration of seven sediment size classes and the flow discharge were measured during each event at the outlet of each flume. Experimental results were analyzed using the Hairsine and Rose (H-R) soil erosion model. Results showed that (i) within each precipitation event, the proportion of each size class for the bare/stone-covered flume pairs at steady state were similar, whereas the initial response differed significantly; (ii) in all cases the effluent was enriched in finer particles relative to the original soil; and (iii) the effluent sediment composition was different from that of the original soil, and there was no clear trend towards the parent soil sediment size composition with time. The H-R model was able to reproduce well the events with high precipitation rate (events 2 and 3) with the same parameter set, while the match was less satisfactory for the low precipitation events. A possible explanation for this is that the initial soil compaction/sealing/development of the deposited layer combined to yield a surface that eroded similarly for identical rainfall conditions. Changes in the precipitation rate modifies the soil surface (the deposited layer in particular) and thus the erosion rates. Model application further suggested that over the course of the rainfall events, the contribution of the original soil to the eroded sediment decreased gradually, while that of the deposited layer increased.

  19. Polychlorinated biphenyls (PCBs) in sediments/soils of different wetlands along 100-year coastal reclamation chronosequence in the Pearl River Estuary, China.

    PubMed

    Zhao, Qingqing; Bai, Junhong; Lu, Qiongqiong; Gao, Zhaoqin; Jia, Jia; Cui, Baoshan; Liu, Xinhui

    2016-06-01

    PCBs (polychlorinated biphenyls) were determined in sediment/soil profiles to a depth of 30 cm from three different wetlands (i.e., ditch wetlands, riparian wetlands and reclaimed wetlands) of the Pearl River Estuary to elucidate their levels, distribution and toxic risks along a 100-year chronosequence of reclamation. All detected PCB congeners and the total 15 PCBs (∑15 PCBs) decreased with depth along sediment/soil profiles in these three wetlands. The ∑15 PCBs concentrations ranged from 17.68 to 169.26 ng/g in surface sediments/soils. Generally, old wetlands tended to have higher PCB concentrations than younger ones. The dominant PCB congeners at all sampling sites were light PCB homologues (i.e., tetra-CBs and tri-CBs). According to the sediment quality guideline, the average PCB concentrations exceeded the threshold effects level (TEL, 21.6 ng/g) at most of the sampling sites, exhibiting possible adverse biological effects, which were dominantly caused by light PCB congeners. The total toxic equivalent (TEQ) concentrations of 10 dioxin-like PCBs (DL-PCBs) detected at all sampling sites ranged from 0.04 to 852.7 (10(-3) ng/g), mainly affected by PCB126. Only DL-PCB concentrations in ditch and riparian wetland sediments with 40-year reclamation histories (i.e., D40 and Ri40) exhibited moderate adverse biological effects according to SQGQ values. Principal component analysis indicated that PCBs in three wetland sediments/soils mainly originated from Aroclor 1016, 1242, and 1248. Correlation analysis showed that sediment/soil organic carbon content had a significant correlation with the concentrations of several PCB congeners (P < 0.05), whereas no significant correlations were observed between any PCBs congeners and grain size or aggregate content (P > 0.05). Copyright © 2016 Elsevier Ltd. All rights reserved.

  20. A tree from waste: Decontaminated dredged sediments for growing forest tree seedlings.

    PubMed

    Ugolini, Francesca; Mariotti, Barbara; Maltoni, Alberto; Tani, Andrea; Salbitano, Fabio; Izquierdo, Carlos García; Macci, Cristina; Masciandaro, Graziana; Tognetti, Roberto

    2018-04-01

    The sediments dredged from a waterway and decontaminated through a phytoremediation process have been used as substrates alternatively to the traditional forest nursery substrate for pot productions of holm oak (Quercus ilex L.) planting stocks. The substrates, made by mixing decontaminated sediments to agricultural soil at different degrees, were tested in order to evaluate their suitability as growth substrates. The experiment was carried out at the nursery of the Department of Agricultural, Food and Forestry Systems of the University of Florence (Italy). The experimental design consisted of four randomized blocks with six pots as replicates for each of the following treatments: 100% sediments, 66% sediments, 33% sediments, 100% agronomic soil and 100% traditional peat based substrate. In each pot, one holm oak acorn was seeded. Germination and both physiological and morphological traits of the seedlings were analysed during and at the end of the first growing season. Holm oak grown in phytoremediated sediments at higher concentrations showed germination levels comparable to those in the traditional substrate, and survival capacity (especially in 66% sediments) slightly higher than in 100% soil. Physiological performance of seedlings resembled that on the traditional substrate which required the addition of fertilizer, at least for the first growing season. Seedlings grown in mixed substrates with higher sediment concentrations occasionally showed better photosynthetic capacity with improved connectivity between the units of the photosystem II. At the end of the first growing season, height as well as the number of growth flushes of the seedlings grown in sole sediment or soil-sediment substrates were similar to what generally is observed for forest nursery stock of Quercus spp.. Regarding the root-system articulation and growth in depth, results in the mixed substrates were comparable to those for seedlings grown in the traditional forest nursery media, and higher than seedlings grown in 100% agronomic soil. According to our results, the reclamation of dredged sediments can provide appropriate nursery substrate for germination beds for forestry species. Copyright © 2018 Elsevier Ltd. All rights reserved.

  1. Soil erosion under multiple time-varying rainfall events

    NASA Astrophysics Data System (ADS)

    Heng, B. C. Peter; Barry, D. Andrew; Jomaa, Seifeddine; Sander, Graham C.

    2010-05-01

    Soil erosion is a function of many factors and process interactions. An erosion event produces changes in surface soil properties such as texture and hydraulic conductivity. These changes in turn alter the erosion response to subsequent events. Laboratory-scale soil erosion studies have typically focused on single independent rainfall events with constant rainfall intensities. This study investigates the effect of multiple time-varying rainfall events on soil erosion using the EPFL erosion flume. The rainfall simulator comprises ten Veejet nozzles mounted on oscillating bars 3 m above a 6 m × 2 m flume. Spray from the nozzles is applied onto the soil surface in sweeps; rainfall intensity is thus controlled by varying the sweeping frequency. Freshly-prepared soil with a uniform slope was subjected to five rainfall events at daily intervals. In each 3-h event, rainfall intensity was ramped up linearly to a maximum of 60 mm/h and then stepped down to zero. Runoff samples were collected and analysed for particle size distribution (PSD) as well as total sediment concentration. We investigate whether there is a hysteretic relationship between sediment concentration and discharge within each event and how this relationship changes from event to event. Trends in the PSD of the eroded sediment are discussed and correlated with changes in sediment concentration. Close-up imagery of the soil surface following each event highlight changes in surface soil structure with time. This study enhances our understanding of erosion processes in the field, with corresponding implications for soil erosion modelling.

  2. Geochemical markers of soil anthropogenic contaminants in polar scientific stations nearby (Antarctica, King George Island).

    PubMed

    Prus, Wojciech; Fabiańska, Monika J; Łabno, Radosław

    2015-06-15

    The organic contamination of Antarctic soils and terrestrial sediments from nearby of five polar scientific stations on King George Island (Antarctica) was investigated. Gas chromatography-mass spectrometry (GC-MS) was applied to find composition of dichloromethane extracts of soil and terrestrial sediments. The presence of geochemical markers, such as n-alkanes, steranes, pentacyclic triterpenoids, and alkyl PAHs, their distribution types, and values of their ratios indicates the predominating source of organic fossil fuels and products of their refining rather than from the natural Antarctic environment. Fossil fuel-originated compounds well survived in conditions of Antarctic climate over long times thus enabling to characterize geochemical features of source fossil fuel identified as petroleum expelled from kerogen II of algal/bacterial origins deposited in sub-oxic conditions and being in the middle of catagenesis. Both microbial activity and water leaching play an important role in degradation of terrestrial oil spills in the Antarctica climate, and petroleum alteration occurs lowly over long periods of time. Synthetic anthropogenic compounds found in terrestrial Antarctica sediments included diisopropylnaphthalenes, products of their sulfonates degradation in paper combustion, and organophosporus compounds used as retardants and plasticizers. Copyright © 2015 Elsevier B.V. All rights reserved.

  3. A simple distributed sediment delivery approach for rural catchments

    NASA Astrophysics Data System (ADS)

    Reid, Lucas; Scherer, Ulrike

    2014-05-01

    The transfer of sediments from source areas to surface waters is a complex process. In process based erosion models sediment input is thus quantified by representing all relevant sub processes such as detachment, transport and deposition of sediment particles along the flow path to the river. A successful application of these models requires, however, a large amount of spatially highly resolved data on physical catchment characteristics, which is only available for a few, well examined small catchments. For the lack of appropriate models, the empirical Universal Soil Loss Equation (USLE) is widely applied to quantify the sediment production in meso to large scale basins. As the USLE provides long-term mean soil loss rates, it is often combined with spatially lumped models to estimate the sediment delivery ratio (SDR). In these models, the SDR is related to data on morphological characteristics of the catchment such as average local relief, drainage density, proportion of depressions or soil texture. Some approaches include the relative distance between sediment source areas and the river channels. However, several studies showed that spatially lumped parameters describing the morphological characteristics are only of limited value to represent the factors of influence on sediment transport at the catchment scale. Sediment delivery is controlled by the location of the sediment source areas in the catchment and the morphology along the flow path to the surface water bodies. This complex interaction of spatially varied physiographic characteristics cannot be adequately represented by lumped morphological parameters. The objective of this study is to develop a simple but spatially distributed approach to quantify the sediment delivery ratio by considering the characteristics of the flow paths in a catchment. We selected a small catchment located in in an intensively cultivated loess region in Southwest Germany as study area for the development of the SDR approach. The flow pathways were extracted in a geographic information system. Then the sediment delivery ratio for each source area was determined using an empirical approach considering the slope, morphology and land use properties along the flow path. As a benchmark for the calibration of the model parameters we used results of a detailed process based erosion model available for the study area. Afterwards the approach was tested in larger catchments located in the same loess region.

  4. Transport mechanisms of soil-bound mercury in the erosion process during rainfall-runoff events.

    PubMed

    Zheng, Yi; Luo, Xiaolin; Zhang, Wei; Wu, Xin; Zhang, Juan; Han, Feng

    2016-08-01

    Soil contamination by mercury (Hg) is a global environmental issue. In watersheds with a significant soil Hg storage, soil erosion during rainfall-runoff events can result in nonpoint source (NPS) Hg pollution and therefore, can extend its environmental risk from soils to aquatic ecosystems. Nonetheless, transport mechanisms of soil-bound Hg in the erosion process have not been explored directly, and how different fractions of soil organic matter (SOM) impact transport is not fully understood. This study investigated transport mechanisms based on rainfall-runoff simulation experiments. The experiments simulated high-intensity and long-duration rainfall conditions, which can produce significant soil erosion and NPS pollution. The enrichment ratio (ER) of total mercury (THg) was the key variable in exploring the mechanisms. The main study findings include the following: First, the ER-sediment flux relationship for Hg depends on soil composition, and no uniform ER-sediment flux function exists for different soils. Second, depending on soil composition, significantly more Hg could be released from a less polluted soil in the early stage of large rainfall events. Third, the heavy fraction of SOM (i.e., the remnant organic matter coating on mineral particles) has a dominant influence on the enrichment behavior and transport mechanisms of Hg, while clay mineral content exhibits a significant, but indirect, influence. The study results imply that it is critical to quantify the SOM composition in addition to total organic carbon (TOC) for different soils in the watershed to adequately model the NPS pollution of Hg and spatially prioritize management actions in a heterogeneous watershed. Copyright © 2016 Elsevier Ltd. All rights reserved.

  5. 75 FR 4803 - Notice of Availability of the Final Environmental Impact Statement for Decommissioning and/or...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-01-29

    ...). The Proposed Action includes the decontamination and decommissioning of the waste storage tanks and... site facilities identified in the Final EIS would be removed; contaminated soil, sediment, and...

  6. DEMONSTRATION BULLETIN: GRACE DEARBORN INC. DARAMEND™ BIOREMEDIATION TECHNOLOGY

    EPA Science Inventory

    The DARAMEND™ Bioremediation Technology may be applied to the remediation of soils and sediments contaminated by a wide variety of organic contaminants including chlorinated phenols, polynuclear aromatic hydrocarbons (PAHs), and petroleum hydrocarbons. The technology may be ap...

  7. Water quality, sediment, and soil characteristics near Fargo-Moorhead urban areas as affected by major flooding of the Red River of the North.

    PubMed

    Guy, A C; Desutter, T M; Casey, F X M; Kolka, R; Hakk, H

    2012-01-01

    Spring flooding of the Red River of the North (RR) is common, but little information exits on how these flood events affect water and overbank sediment quality within an urban area. With the threat of the spring 2009 flood in the RR predicted to be the largest in recorded history and the concerns about the flooding of farmsteads, outbuildings, garages, and basements, the objectives of this study, which focused on Fargo, ND, and Moorhead, MN, were to assess floodwater quality and to determine the quantity and quality of overbank sediment deposited after floodwaters recede and the quality of soil underlying sediment deposits. 17β-Estradiol was detected in 9 of 24 water samples, with an average concentration of 0.61 ng L. Diesel-range organics were detected in 8 of 24 samples, with an average concentration of 80.0 μg L. The deposition of sediment across locations and transects ranged from 2 to 10 kg m, and the greatest mass deposition of chemicals was closest to the river channel. No gasoline-range organics were detected, but diesel-range organics were detected in 26 of the 27 overbank sediment samples (maximum concentration, 49.2 mg kg). All trace elements detected in the overbank sediments were within ranges for noncontaminated sites. Although flooding has economic, social, and environmental impacts, based on the results of this study, it does not appear that flooding in the RR in F-M led to decreased quality of water, sediment, or soil compared with normal river flows or resident soil. Copyright © by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, Inc.

  8. Characteristics of Soil and Organic Carbon Loss Induced by Water Erosion on the Loess Plateau in China

    PubMed Central

    Li, Zhongwu; Nie, Xiaodong; Chang, Xiaofeng; Liu, Lin; Sun, Liying

    2016-01-01

    Soil erosion has been a common environmental problem in the Loess Plateau in China. This study aims to better understand the losses of soil organic carbon (SOC) induced by water erosion. Laboratory-simulated rainfall experiments were conducted to investigate the characteristics of SOC loss induced by water erosion. The applied treatments included two rainfall intensities (90 and 120 mm h-1), four slope gradients (10°, 15°, 20°, and 25°), and two typical soil types- silty clay loam and silty loam. Results showed that the sediment OC enrichment ratios (ERoc) in all the events were relative stable with values ranged from 0.85 to1.21 and 0.64 to 1.52 and mean values of 0.98 and 1.01 for silty clay loam and silty loam, respectively. Similar to the ERoc, the proportions of different sized particles in sediment showed tiny variations during erosion processes. No significant correlation was observed between ERoc values and the proportions of sediment particles. Slope, rainfall intensity and soil type almost had no impact on ERoc. These results indicate that the transportation of SOC during erosion processes was nonselective. While the mean SOC loss rates for the events of silty clay loam and silty loam were 0.30 and 0.08 g m-2 min-1, respectively. Greater differences in SOC loss rates were found in events among different soil types. Meanwhile, significant correlations between SOC loss and soil loss for all the events were observed. These results indicated that the amount of SOC loss was influenced primarily by soil loss and the SOC content of the original soil. Erosion pattern and original SOC content are two main factors by which different soils can influence SOC loss. It seems that soil type has a greater impact on SOC loss than rainfall characteristics on the Loess Plateau of China. However, more kinds of soils should be further studied due to the special formation processes in the Loess Plateau. PMID:27124482

  9. Characteristics of Soil and Organic Carbon Loss Induced by Water Erosion on the Loess Plateau in China.

    PubMed

    Li, Zhongwu; Nie, Xiaodong; Chang, Xiaofeng; Liu, Lin; Sun, Liying

    2016-01-01

    Soil erosion has been a common environmental problem in the Loess Plateau in China. This study aims to better understand the losses of soil organic carbon (SOC) induced by water erosion. Laboratory-simulated rainfall experiments were conducted to investigate the characteristics of SOC loss induced by water erosion. The applied treatments included two rainfall intensities (90 and 120 mm h-1), four slope gradients (10°, 15°, 20°, and 25°), and two typical soil types- silty clay loam and silty loam. Results showed that the sediment OC enrichment ratios (ERoc) in all the events were relative stable with values ranged from 0.85 to1.21 and 0.64 to 1.52 and mean values of 0.98 and 1.01 for silty clay loam and silty loam, respectively. Similar to the ERoc, the proportions of different sized particles in sediment showed tiny variations during erosion processes. No significant correlation was observed between ERoc values and the proportions of sediment particles. Slope, rainfall intensity and soil type almost had no impact on ERoc. These results indicate that the transportation of SOC during erosion processes was nonselective. While the mean SOC loss rates for the events of silty clay loam and silty loam were 0.30 and 0.08 g m-2 min-1, respectively. Greater differences in SOC loss rates were found in events among different soil types. Meanwhile, significant correlations between SOC loss and soil loss for all the events were observed. These results indicated that the amount of SOC loss was influenced primarily by soil loss and the SOC content of the original soil. Erosion pattern and original SOC content are two main factors by which different soils can influence SOC loss. It seems that soil type has a greater impact on SOC loss than rainfall characteristics on the Loess Plateau of China. However, more kinds of soils should be further studied due to the special formation processes in the Loess Plateau.

  10. 76 FR 32081 - National Oil and Hazardous Substances Pollution Contingency Plan; National Priorities List...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-06-03

    ... County. Groundwater near the Site is used for domestic purposes, including drinking water. Landfill No. 1... synthetic liner. The permit also required leachate collection, installation of groundwater monitoring wells... investigation during the RI/FS included waste, leachate, groundwater, surface water and sediment, soil, and air...

  11. Factors Controlling Sediment Load in The Central Anatolia Region of Turkey: Ankara River Basin.

    PubMed

    Duru, Umit; Wohl, Ellen; Ahmadi, Mehdi

    2017-05-01

    Better understanding of the factors controlling sediment load at a catchment scale can facilitate estimation of soil erosion and sediment transport rates. The research summarized here enhances understanding of correlations between potential control variables on suspended sediment loads. The Soil and Water Assessment Tool was used to simulate flow and sediment at the Ankara River basin. Multivariable regression analysis and principal component analysis were then performed between sediment load and controlling variables. The physical variables were either directly derived from a Digital Elevation Model or from field maps or computed using established equations. Mean observed sediment rate is 6697 ton/year and mean sediment yield is 21 ton/y/km² from the gage. Soil and Water Assessment Tool satisfactorily simulated observed sediment load with Nash-Sutcliffe efficiency, relative error, and coefficient of determination (R²) values of 0.81, -1.55, and 0.93, respectively in the catchment. Therefore, parameter values from the physically based model were applied to the multivariable regression analysis as well as principal component analysis. The results indicate that stream flow, drainage area, and channel width explain most of the variability in sediment load among the catchments. The implications of the results, efficient siltation management practices in the catchment should be performed to stream flow, drainage area, and channel width.

  12. Factors Controlling Sediment Load in The Central Anatolia Region of Turkey: Ankara River Basin

    NASA Astrophysics Data System (ADS)

    Duru, Umit; Wohl, Ellen; Ahmadi, Mehdi

    2017-05-01

    Better understanding of the factors controlling sediment load at a catchment scale can facilitate estimation of soil erosion and sediment transport rates. The research summarized here enhances understanding of correlations between potential control variables on suspended sediment loads. The Soil and Water Assessment Tool was used to simulate flow and sediment at the Ankara River basin. Multivariable regression analysis and principal component analysis were then performed between sediment load and controlling variables. The physical variables were either directly derived from a Digital Elevation Model or from field maps or computed using established equations. Mean observed sediment rate is 6697 ton/year and mean sediment yield is 21 ton/y/km² from the gage. Soil and Water Assessment Tool satisfactorily simulated observed sediment load with Nash-Sutcliffe efficiency, relative error, and coefficient of determination ( R²) values of 0.81, -1.55, and 0.93, respectively in the catchment. Therefore, parameter values from the physically based model were applied to the multivariable regression analysis as well as principal component analysis. The results indicate that stream flow, drainage area, and channel width explain most of the variability in sediment load among the catchments. The implications of the results, efficient siltation management practices in the catchment should be performed to stream flow, drainage area, and channel width.

  13. Evaluating grass strips trapping efficiency of sediments and herbicides

    NASA Astrophysics Data System (ADS)

    Burguet, Maria; Guzmán, Gema; de Luna, Elena; Taguas, Encarnación V.; Gómez, José Alfonso

    2016-04-01

    Water erosion and associated offsite contamination are major environmental risks in many Mediterranean crops such as olives or vineyards (Beaufoy, 2001; Gómez et al., 2011). The use of cover crops has been prescribed as a mitigation measure for both problems because permanent cover crops have demonstrated to reduce sediment and agrochemical loads (e.g. Gómez, 2009a, b). However, large uncertainty remains about its effectiveness degree to reduce sediment and agrochemical contribution to streams due to the limited number of available studies, and the large variability observed under field conditions (Taguas et al., 2012). Furthermore, the determination of sediment and herbicide sources using suitable sediment tracing/fingerprinting properties has been noted as one tool to evaluate the effectiveness and functioning of vegetated filters at the catchment scale (Koiter et al., 2013). The objectives of the present study were twofold: [1] to explore the combined use of natural and simulated rainfall and magnetic iron oxide in understanding the performance of vegetation strips on runoff and soil and herbicide losses at plot scale and, [2] to evaluate the effectiveness degree of vegetation strips in buffering sediment and herbicide from bare soil areas under different conditions compared to a control situation with no strips. This study encompasses six rainfall simulations under four different soil managements combining the use of a magnetic iron oxide as a sediment tracer to obtain a better understanding of the vegetation strips trapping efficiency. Three runoff plots of 6 m × 14 m were established in a 20% hillslope under a Fluvisol alluvial terrace. Each of the plots contained three bare strips tagged with magnetic iron oxide and three strips with Lolium multiflorum L. The soil management simulated scenarios were: immediately after sowing the vegetation cover (June 2011cover crop), with settled vegetation cover (June 2012cover crop), after 5 cm of deep ploughing (October 2013freshly tilled) and after ploughing and mechanically compacting the soil with a sheet metal (November 2013 consolidated surface). Our results indicate that by using cover crop strips, runoff and sediment losses were approximately 50 % and 12 % respectively lower than the measured values in bare consolidated and freshly tilled soil. The formation of microrelief steps after the first simulation also helped to reduce soil losses and runoff. Ploughed and compacted soil management showed the highest cumulative runoff and soil losses values (28 mm and 15 kg). Evident tracer selectivity from small particle size soil textures (clays) was observed as there was an enrichment of these particles in the collected sediment. These features contribute to explain the effects of the management and the vegetation on the sediment distribution in the hillslopes and must be taken into account when performing tracing studies as well as when using cover crop strips to mitigate offsite contamination by agrochemicals. Acknowledgements: The authors would like to thank Clemente Trujillo, Manuel Redondo and Azahara Ramos for their full help and support during the fieldwork. This study was supported by the Project P08-AGR-03925 (Andalusian Government), AGL2009-12936-C03-01 (Ministry of Science and Innovation), RESEL (Ministry of Agriculture, Food and Environment) and FEDER fund. The program JAE of the National Spanish Research Centre which provided grant support for the PhD project of the corresponding author is also thanked. References: Beaufoy, G. 2001. EU policies for olive farming. Unsustainable on all counts. BirdLife Internacional-WWF, Brussels. Gómez, J.A., Sobrinho, T.A, Giráldez, J.V., Fereres, E. 2009a. Soil management effects on runoff, erosion and soil properties in an olive grove of Southern Spain. Soil & Tillage Research 102: 5-13. Gómez, J.A., Guzmán, M.G., Giráldez, J.V., Fereres, E. 2009b. The influence of cover crops and tillage on water and sediment yield, and on nutrient, and organic matter losses in an olive orchard on a sandy loam soil. Soil Till Res 106: 137-144. Gómez, J.A., Llewellyn, C., Basch, G., Sutton, P. B., Dyson, J. S., Jones, C. A. 2011. The effects of cover crops and conventional tillage on soil and runoff loss in vineyards and olive groves in several Mediterranean countries. Soil Use and Management 27: 502 - 514. Koiter, A.J., Owens, P.N., Petticrew, E.L., Lobb, D.A. 2013. The behavioural characteristics of sediment properties and their implications for sediment fingerprinting as an approach for identifying sediment sources in river basins. Earth-Science Reviews 125: 24-42. Taguas, E.V., Burguet, M., Pérez, R., Ayuso, J.L., Gómez, J.A., 2012. Interpretation of the impact of different managements and the rainfall variability on the soil erosion in a Mediterranean olive orchard microcatchment. Geophysical Research Abstracts 14, EGU2012-10966.

  14. Sediment reallocations due to erosive rainfall events in the Three Gorges Reservoir Area, Central China

    NASA Astrophysics Data System (ADS)

    Stumpf, Felix; Goebes, Philipp; Schmidt, Karsten; Schindewolf, Marcus; Schönbrodt-Stitt, Sarah; Wadoux, Alexandre; Xiang, Wei; Scholten, Thomas

    2017-04-01

    Soil erosion by water outlines a major threat to the Three Gorges Reservoir Area in China. A detailed assessment of soil conservation measures requires a tool that spatially identifies sediment reallocations due to rainfall-runoff events in catchments. We applied EROSION 3D as a physically based soil erosion and deposition model in a small mountainous catchment. Generally, we aim to provide a methodological frame that facilitates the model parametrization in a data scarce environment and to identify sediment sources and deposits. We used digital soil mapping techniques to generate spatially distributed soil property information for parametrization. For model calibration and validation, we continuously monitored the catchment on rainfall, runoff and sediment yield for a period of 12 months. The model performed well for large events (sediment yield>1 Mg) with an averaged individual model error of 7.5%, while small events showed an average error of 36.2%. We focused on the large events to evaluate reallocation patterns. Erosion occurred in 11.1% of the study area with an average erosion rate of 49.9Mgha 1. Erosion mainly occurred on crop rotation areas with a spatial proportion of 69.2% for 'corn-rapeseed' and 69.1% for 'potato-cabbage'. Deposition occurred on 11.0%. Forested areas (9.7%), infrastructure (41.0%), cropland (corn-rapeseed: 13.6%, potatocabbage: 11.3%) and grassland (18.4%) were affected by deposition. Because the vast majority of annual sediment yields (80.3%) were associated to a few large erosive events, the modelling approach provides a useful tool to spatially assess soil erosion control and conservation measures.

  15. [Impact of wind-water alternate erosion on the characteristics of sediment particles].

    PubMed

    Tuo, Deng-Feng; Xu, Ming-Xiang; Ma, Xin-Xin; Zheng, Shi-Qing

    2014-02-01

    Wind and water are the two dominant erosion agents that caused soil and water losses in the wind-water alternate erosion region on the Loess Plateau. It is meaningful to study the impact of wind-water alternate erosion on the characteristics of soil particles for understanding the response of soil quality and environment to erosion. Through wind tunnel combined rainfall simulation, this paper studied the characteristics of the erosive sediment particles under the effect of wind-water alternate erosion. The results showed that the particles of 0-1 cm soil were coarsened by wind erosion at the wind speeds of 11 and 14 m x s(-1) compared with no wind erosion. Soil fine particles (< 0.01 mm) decreased by 9.8%-10.8%, and coarse particles (> 0.05 mm) increased by 16.8%-20.8%. The physical property of surface soil was changed by the wind erosion, which, in turn, caused an increase in finer particles content in the sediment. Compared with no wind erosion, fine particles (< 0.01 mm) in sediment under the water-wind alternate erosion increased by 2.7%-18.9% , and coarse particles (> 0.05 mm) decreased by 3.7%-9.3%. However, the changing trend of erosive sediment particles after the wind erosion at wind speeds of 11 and 14 m x s(-1) was different along with the rainfall intensity and duration. The erosive sediment particles at the rainfall intensities of 60, 80, 100 mm x h(-1) changed to greater extents than at the 150 mm x h(-1) rainfall intensity with longer than 15 min runoff flowing.

  16. Aggregation Rates of Sediments (Montmorillonite, Kaolinite, Illite and Goethite) with the Enveloped Φ6 Bacteriophage

    NASA Astrophysics Data System (ADS)

    Katz, A.; Block, K. A.; Peña, S.; Alimova, A.; Gottlieb, P.

    2015-12-01

    The interaction between sediments and viruses has been studied extensively from the prospective of virus survivability and infectivity. However, the role of soil organisms, including viruses in C and N sequestration in soil has not been studied as extensively. Φ6, a member of the cystoviridae family, is a bacteriophage that infects Pseudomonas syringae, a common plant pathogen known to readily form biofilms.The small mineral fraction (< 0.2 μm) of soil and Φ6 are colloidal particles, therefore aggregation can be explained by DLVO (Derjaguin & Landau, Verwey & Overbeek) theory. Time-resolved visible-light turbidity measurements were used to calculate the heteroaggregation rates of Φ6 with the sediments. Samples were suspended in a low-concentration cation buffer so that the kinetics were in the reaction limited cluster aggregation (RLCA) regime in where the probability of two particles adhering after collision is determined by the interaction forces between the particles.At neutral pH to slightly acidic pH, Φ6 is slightly negatively charged; montmorillonite and illite are negatively charged; and kaolinite and goethite are positively charged. In isolation, neither Φ6 nor the sediments aggregated in the modified buffer. However, in mixtures, Φ6 and montmorillonite, and Φ6 and illite, exhibited increases in turbidity, indicating heteroaggregation. Neither Φ6 and kaolinite, nor Φ6 and goethite, exhibited increased turbidity upon mixing indicating little or no aggregation. These results suggest that the interaction of the virus with the sediments is governed by hydrophobic rather than electrostatic forces. Heteroaggregation rates were calculated from the time rate of change of the turbidity.

  17. Mississippi Basin Carbon Project science plan

    USGS Publications Warehouse

    Sundquist, E.T.; Stallard, R.F.; Bliss, N.B.; Markewich, H.W.; Harden, J.W.; Pavich, M.J.; Dean, M.D.

    1998-01-01

    Understanding the carbon cycle is one of the most difficult challenges facing scientists who study the global environment. Lack of understanding of global carbon cycling is perhaps best illustrated by our inability to balance the present-day global CO2 budget. The amount of CO2 produced by burning fossil fuels and by deforestation appears to exceed the amount accumulating in the atmosphere and oceans. The carbon needed to balance the CO2 budget (the so-called "missing" carbon) is probably absorbed by land plants and ultimately deposited in soils and sediments. Increasing evidence points toward the importance of these terrestrial processes in northern temperate latitudes. Thus, efforts to balance the global CO2 budget focus particular attention on terrestrial carbon uptake in our own North American "backyard."The USGS Mississippi Basin Carbon Project conducts research on the carbon budget in soils and sediments of the Mississippi River basin. The project focuses on the effects of land-use change on carbon storage and transport, nutrient cycles, and erosion and sedimentation throughout the Mississippi River Basin. Particular emphasis is placed on understanding the interactions among changes in erosion, sedimentation, and soil dynamics. The project includes spatial analysis of a wide variety of geographic data sets, estimation of whole-basin and sub-basin carbon and sediment budgets, development and implementation of terrestrial carbon-cycle models, and site-specific field studies of relevant processes. The USGS views this project as a "flagship" effort to demonstrate its capabilities to address the importance of the land surface to biogeochemical problems such as the global carbon budget.

  18. Growth of plants on TBT-contaminated harbour sludge and effect on TBT removal.

    PubMed

    Novak, Jana; Trapp, Stefan

    2005-11-01

    Worldwide, large amounts of sediments have to be dredged annually from waterways and harbours. These sediments are sometimes polluted with a variety of toxic compounds. In some countries, including Belgium, the load with the biocide tributyltin (TBT) from ship coatings prohibits the dumping of harbour sludge into the sea. Land-based dumping is a commonly used alternative. This research investigated the feasibility to use land-deposited harbour sludge for plant production. In a field trial, the growth of 38 more or less salt-tolerant plant species on low and high TBT-contaminated sediments was studied. The elimination of TBT from sludge with and without vegetation was compared. The uptake of TBT and its degradation products di- and monobutyltin (DBT and MBT) into harvest products under field conditions was determined. EXPERIMENTAL SET-UP: Sediments dredged in May 2003 from the brackish waters of the port of Antwerp were analysed in the laboratory for soil texture, pH, electroconductivity, sodium, magnesium, potassium, calcium, ammonium, nitrate, total nitrogen, chloride, sulphur and the organotins TBT, DBT and MBT. The sediments were lagooned for one year to dewater, desalinate and improve their structure. Salt-tolerant domestic and wild plants were selected and sown in May 2004. In August 2004, plants were harvested and the produced biomass was determined. Samples were taken from vegetated and non-vegetated top and bottom sediments and from plants growing above soil and analysed for TBT, DBT and MBT. The fresh sediments showed a good supply with nutrients and a neutral pH, but were rather saline (EC 14 mS cm(-1) of the saturated paste extract). The salinity decreased to 3.7 mS cm(-1) during lagoonation. The high and the low contaminated sediment had initially 43 and 1.6 mg TBT kg(-1) dry weight, respectively. Besides TBT, several other contaminants were present in the sediments at critical levels. The biomass production of the plant species from the field trial ranged from 0.2 to 13 tons dry mass per hectare. Plants performing excellently were barley, sorghum, rape seed, a clover/grass mix and reed. If at all, a positive influence of TBT on plant growth was seen. TBT was degraded significantly faster (>40%) below barley. The uptake of TBT, DBT and MBT into stem and leaves of reed, grass and clover was very low, but measurable and not related to concentrations in soil. No uptake of TBT or its metabolites into corn of barley was found. This study confirmed former results: the toxicity of TBT to higher plants is low, and even high levels in soils would not be a hindrance for crop production. The removal of TBT seemed to be increased by both lagooning and plant growth, although the target values for sea dumping in use in certain European countries were not reached. A plausible explanation for the faster degradation of TBT under vegetation is that oxygen is a limiting factor, and plants dewater the soil, thus aerating it. The uptake of the organotins TBT, DBT and MBT into harvest products is probably due to attached soil particles. To summarize, barley was the optimal species: it grew very well despite the salinity of the dredged sediments, it had a significantly positive effect on TBT removal; it showed no measurable uptake of TBT or the other butyltins into the harvested product; and it is a cash crop well established in European agriculture. The amounts of dredged sediments are high, and good soils are becoming increasingly rare. The feasibility of using dredged sediments for non-food production, such as energy crops, should be investigated by a critical risk assessment.

  19. A review of physically based models for soil erosion by water

    NASA Astrophysics Data System (ADS)

    Le, Minh-Hoang; Cerdan, Olivier; Sochala, Pierre; Cheviron, Bruno; Brivois, Olivier; Cordier, Stéphane

    2010-05-01

    Physically-based models rely on fundamental physical equations describing stream flow and sediment and associated nutrient generation in a catchment. This paper reviews several existing erosion and sediment transport approaches. The process of erosion include soil detachment, transport and deposition, we present various forms of equations and empirical formulas used when modelling and quantifying each of these processes. In particular, we detail models describing rainfall and infiltration effects and the system of equations to describe the overland flow and the evolution of the topography. We also present the formulas for the flow transport capacity and the erodibility functions. Finally, we present some recent numerical schemes to approach the shallow water equations and it's coupling with infiltration and erosion source terms.

  20. Soil aggregate stability and rainfall-induced sediment transport on field plots as affected by amendment with organic matter inputs

    NASA Astrophysics Data System (ADS)

    Shi, Pu; Arter, Christian; Liu, Xingyu; Keller, Martin; Schulin, Rainer

    2017-04-01

    Aggregate stability is an important factor in soil resistance against erosion, and, by influencing the extent of sediment transport associated with surface runoff, it is thus also one of the key factors which determine on- and off-site effects of water erosion. As it strongly depends on soil organic matter, many studies have explored how aggregate stability can be improved by organic matter inputs into the soil. However, the focus of these studies has been on the relationship between aggregate stability and soil organic matter dynamics. How the effects of organic matter inputs on aggregate stability translate into soil erodibility under rainfall impacts has received much less attention. In this study, we performed field plot experiments to examine how organic matter inputs affect aggregate breakdown and surface sediment transport under field conditions in artificial rainfall events. Three pairs of plots were prepared by adding a mixture of grass and wheat straw to one of plots in each pair but not to the other, while all plots were treated in the same way otherwise. The rainfall events were applied some weeks later so that the applied organic residues had sufficient time for decomposition and incorporation into the soil. Surface runoff rate and sediment concentration showed substantial differences between the treatments with and without organic matter inputs. The plots with organic inputs had coarser and more stable aggregates and a rougher surface than the control plots without organic inputs, resulting in a higher infiltration rate and lower transport capacity of the surface runoff. Consequently, sediments exported from the amended plots were less concentrated but more enriched in suspended particles (<20 µm) than from the un-amended plots, indicating a more size-selective sediment transport. In contrast to the amended plots, there was an increase in the coarse particle fraction (> 250 µm) in the runoff from the plots with no organic matter inputs towards the end of the rainfall events due to emerging bed-load transport. The results show that a single application of organic matter can already cause a large difference in aggregate breakdown, surface sealing, and lateral sediment-associated matter transfer under rainfall impact. Furthermore, we will present terrestrial laser scanning data showing the treatment effects on soil surface structure, as well as data on carbon, phosphorus and heavy metal export associated with the translocation of the sediments.

  1. Superfund Record of Decision (EPA Region 1): Baird and McGuire, Holbrook, Massachusetts (Third remedial action), September 1989

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Not Available

    1989-09-14

    The Baird McGuire site is a former chemical manufacturing facility in northwest Holbrook, Massachusetts, approximately 14 miles south of Boston. From 1912 to 1983 the company operated a chemical manufacturing and batching facility on the property. Manufactured products included herbicides, pesticides, disinfectants, soaps, floor waxes and solvents. Waste disposal methods at the site included direct discharge into the soil, nearby brook and wetlands, and a former gravel pit (now covered) in the eastern portion of the site. Underground disposal systems were also used. EPA also conducted an Initial Remedial Measure at the site from 1985 through 1987 which involved constructingmore » a new water main to direct water away from the site, removing building structures, and installing a temporary cap. In 1986 a Record of Decision (ROD) was signed to address onsite ground water treatment and incineration of contaminated soil. This ROD addresses the Cochato River sediment contamination. The primary contaminants of concern affecting the sediment are organics including PAHs and pesticides, and metals including arsenic. The selected remedial action for the site are included.« less

  2. Distribution of metals and brominated flame retardants (BFRs) in sediments, soils and plants from an informal e-waste dismantling site, South China.

    PubMed

    Wang, Junxia; Liu, Lili; Wang, Jinfu; Pan, Bishu; Fu, Xiaoxu; Zhang, Gang; Zhang, Long; Lin, Kuangfei

    2015-01-01

    Brominated flame retardants (BFRs, including polybrominated diphenyl ethers (PBDEs) and tetrabromobisphenol-A (TBBPA)) and metals (Cu, Zn, Pb, Cd, Ni, Hg and As) in sediments, soils and herb plants from unregulated e-waste disposal sites were examined. The metal concentrations, ∑PBDE and TBBPA concentrations in all samples from the examined e-waste dismantling sites were relatively high in comparison with those of rural and urban areas around the world. The PBDE and TBBPA levels in soils significantly decreased with increasing distance from the e-waste dismantling sites, indicating that PBDEs and TBBPA had similar transport potential from the e-waste dismantling process as a point source to the surrounding region. BDE-209 and TBBPA predominated in all samples, which is consistent with the evidence that the deca-BDE and TBBPA commercial mixtures were extensively used in electronic products. Metals, PBDEs and TBBPA displayed significant positive correlations with TOC, whereas the correlations with pH were insignificant, indicating that TOC was a major factor governing the spatial distribution, transportation and fate in sediments and soils. A significant relationship between log-transformed metals and BFR concentrations indicated common pollution sources. Moreover, cluster analysis and principal component analysis further confirmed that the metals and BFRs had a common source, and penta- and deca-BDE commercial products may be two sources of PBDEs in this region.

  3. Model analysis of check dam impacts on long-term sediment and water budgets in southeast Arizona, USA

    USGS Publications Warehouse

    Norman, Laura M.; Niraula, Rewati

    2016-01-01

    The objective of this study was to evaluate the effect of check dam infrastructure on soil and water conservation at the catchment scale using the Soil and Water Assessment Tool (SWAT). This paired watershed study includes a watershed treated with over 2000 check dams and a Control watershed which has none, in the West Turkey Creek watershed, Southeast Arizona, USA. SWAT was calibrated for streamflow using discharge documented during the summer of 2013 at the Control site. Model results depict the necessity to eliminate lateral flow from SWAT models of aridland environments, the urgency to standardize geospatial soils data, and the care for which modelers must document altering parameters when presenting findings. Performance was assessed using the percent bias (PBIAS), with values of ±2.34%. The calibrated model was then used to examine the impacts of check dams at the Treated watershed. Approximately 630 tons of sediment is estimated to be stored behind check dams in the Treated watershed over the 3-year simulation, increasing water quality for fish habitat. A minimum precipitation event of 15 mm was necessary to instigate the detachment of soil, sediments, or rock from the study area, which occurred 2% of the time. The resulting watershed model is useful as a predictive framework and decision-support tool to consider long-term impacts of restoration and potential for future restoration.

  4. Hydrology of area 4, Eastern Coal Province, Pennsylvania, Ohio, and West Virginia

    USGS Publications Warehouse

    Roth, Donald K.; Engelke, Morris J.; ,

    1981-01-01

    Area 4 (one of the 24 hydrologic areas defining the Eastern Coal Province) is located at the northern end of the Eastern Coal Province in eastern Ohio, northern West Virginia, and western Pennsylvania. It is part of the upper Ohio River basin, which includes the Beaver, Mahoning, and Shenango Rivers. The area is underlain by rocks of the Pottsville, Allegheny, Conemaugh, Monongahela Groups (or Formations) and Dunkard Group. Area 4 has a temperate climate with an annual average rainfall of 38 to 42 inches, most of its area is covered by forest. The soils have a high erosion potential where the vegetation cover is removed. In response to Public Law 95-87, 132 sites were added to the existing surface-water data-collection network in area 4. At these added sites, collected data includes discharge, water quality, sediment, and biology. The data are available from computer storage through the National Water Data Exchange (NAWDEX) or the published annual Water Resources Data reports for Ohio, Pennsylvania, and West Virginia. Hydrologic problems related to mining are: (1) Erosion and increased sedimentation, and (2) degradation of water quality. Erosion and sedimentation are associated chiefly with surface mining. Sediment yields increase drastically when vegetation is removed from the highly erosive soils. Degradation of water quality can be caused by acid-mine drainage from underground and surface mining. More than half the acid-mine drainage effluent in area 4 comes from underground mines. The rest seeps from abandoned surface mines. Usually in reclaimed surface mines the overburden is replaced in such a short time after the coal is taken out that oxidation of acid-forming minerals, commonly pyrite or marcasite, is not complete or is neutralized by the buffering action of calcareous minerals in the soils. (USGS)

  5. Study of soil aggregate breakdown dynamics under low dispersive ultrasonic energies with sedimentation and X-ray attenuation**

    PubMed Central

    Schomakers, Jasmin; Zehetner, Franz; Mentler, Axel; Ottner, Franz; Mayer, Herwig

    2016-01-01

    It has been increasingly recognized that soil organic matter stabilization is strongly controlled by physical binding within soil aggregates. It is therefore essential to measure soil aggregate stability reliably over a wide range of disruptive energies and different aggregate sizes. To this end, we tested high-accuracy ultrasonic dispersion in combination with subsequent sedimentation and X-ray attenuation. Three arable topsoils (notillage) from Central Europe were subjected to ultrasound at four different specific energy levels: 0.5, 6.7, 100 and 500 J cm−3, and the resulting suspensions were analyzed for aggregate size distribution by wet sieving (2 000-63 μm) and sedimentation/X-ray attenuation (63-2 μm). The combination of wet sieving and sedimentation technique allowed for a continuous analysis, at high resolution, of soil aggregate breakdown dynamics after defined energy inputs. Our results show that aggregate size distribution strongly varied with sonication energy input and soil type. The strongest effects were observed in the range of low specific energies (< 10 J cm−3), which previous studies have largely neglected. This shows that low ultrasonic energies are required to capture the full range of aggregate stability and release of soil organic matter upon aggregate breakdown. PMID:27099408

  6. Study of soil aggregate breakdown dynamics under low dispersive ultrasonic energies with sedimentation and X-ray attenuation

    NASA Astrophysics Data System (ADS)

    Schomakers, Jasmin; Zehetner, Franz; Mentler, Axel; Ottner, Franz; Mayer, Herwig

    2015-10-01

    It has been increasingly recognized that soil organic matter stabilization is strongly controlled by physical binding within soil aggregates. It is therefore essential to measure soil aggregate stability reliably over a wide range of disruptive energies and different aggregate sizes. To this end, we tested highaccuracy ultrasonic dispersion in combination with subsequent sedimentation and X-ray attenuation. Three arable topsoils (notillage) from Central Europe were subjected to ultrasound at four different specific energy levels: 0.5, 6.7, 100 and 500 J cm-3, and the resulting suspensions were analyzed for aggregate size distribution by wet sieving (2 000-63 μm) and sedimentation/X-ray attenuation (63-2 μm). The combination of wet sieving and sedimentation technique allowed for a continuous analysis, at high resolution, of soil aggregate breakdown dynamics after defined energy inputs. Our results show that aggregate size distribution strongly varied with sonication energy input and soil type. The strongest effects were observed in the range of low specific energies (< 10 J cm-3), which previous studies have largely neglected. This shows that low ultrasonic energies are required to capture the full range of aggregate stability and release of soil organic matter upon aggregate breakdown.

  7. Infiltration and interrill erosion rates after a wildfire in western Montana, USA

    Treesearch

    Pete Robichaud; Joseph W. Wagenbrenner; Fredrick B. Pierson; Kenneth E. Spaeth; Louise E. Ashmun; Corey A. Moffet

    2016-01-01

    The 2000 Valley Complex wildfire burned in steep montane forests with ash cap soils in western Montana, USA. The effects of high soil burn severity on forest soil hydrologic function were examined using rainfall simulations (100mmh-1 for 1 h) on 0.5-m2 plots. Infiltration rates, sediment yields and sediment concentrations were compared among three treatments:...

  8. Annotated bibliography on soil erosion and erosion control in subarctic and high-latitude regions of North America.

    Treesearch

    C.W. Slaughter; J.W. Aldrich

    1989-01-01

    This annotated bibliography emphasizes the physical processes of upland soil erosion, prediction of soil erosion and sediment yield, and erosion control. The bibliography is divided into two sections: (1) references specific to Alaska, the Arctic and subarctic, and similar high-latitude settings; and (2) references relevant to understanding erosion, sediment production...

  9. Response of two semiarid grasslands to a second fire application

    Treesearch

    Carleton S. White; Rosemary L. Pendleton; Burton K. Pendleton

    2006-01-01

    Prescribed fire was used in two semiarid grasslands to reduce shrub cover, promote grass production, and reduce erosional loss that represents a potential non­point-source of sediment to degrade water quality. This study measured transported soil sediment, dynamics in soil surface microtopography, cover of the woody shrub, grass, and bare ground cover classes, and soil...

  10. Effects of gully erosion on sediment connectivity in a small agrarian catchment: basis of an experimental proposal

    NASA Astrophysics Data System (ADS)

    Zubieta, Elena; Casalí, Javier; Masselink, Rens J. H.; Giménez, Rafael; Keesstra, Saskia D.

    2017-04-01

    Connectivity aims to explain the transit of substances in a certain (natural) area. Thereby, the connectivity of sediments from soil erosion involves complex factors determining the subsequent movement of detached matter across the land (for instance, a hydrographic catchment). Agricultural soil erosion in Navarre has been studied mainly by recording sediments at the outlets of experimental catchments. These studies have revealed a complex dynamics in the sediments. For example, a clear seasonality was noticed, with the highest records in winter and the beginning of spring, coinciding, however, with rainfall events of a relatively low erosion capacity. In fact, this dynamics was not only conditioned by the intensity and duration of precipitations, but also, for instance, by the soil's previous humidity, use and management, and by plant cover. Further, it was suspected that a key factor in sediment connectivity would be erosion due to concentrated flows (i.e. ephemeral gullies), which would act as a source and transport of sediments. The aim of this research is to monitor, long-term, the movement of sediments generated by erosion from ephemeral gullies within a typical agrarian catchment in Navarra, in order to clarify the role played by those gullies in sediment connectivity. The experiments will be performed in the experimental catchment of "La Tejería" (169 ha) located in the Central Area of Navarre, and which is frequently affected by concentrated flow erosion and with long-term records of sediments at its outlet. The climate is humid submediterranean, with an average annual precipitation of approximately 725 mm. The prevailing soil class is Vertic Haploxerept and cereal crops usually cover over 90% of the total area. Our previous experience in the study area would permit the prediction, with a high degree of certainty, of the appearance of ephemeral gullies at least in 4-5 watercourses selected. A specific tracer (a rare-earth oxide) will be sprinkled over each watercourse following the methodology proposed by Masselink et al.(under review). This will also be done throughout the principal channel of the catchment in an area next to its outlet. These tracers do not affect either the soil properties - or therefore their erodibility - or the natural process of sediment transport by runoff either. With the formation of each gully, after the occurrence of rain events, significant for their intensity or duration, the surface layer of the soil will be sampled. This will be carried out throughout the natural drainage network of the catchment (determined from a high resolution DEM), starting from the gully upper limit to the main channel of the catchment. The soil samples will be analysed in our laboratory. A very much higher rare-earth oxide concentration than those found naturally in the soil would indicate that this element comes from the experimentation and, therefore, from a certain gully. The spatial-temporal monitoring of the sediments from different gullies associated with rainfall records, soil conditions, degree of plant cover, and sediment records at the catchment outlet, would contribute to a better understanding of sediment movement and the factors conditioning its dynamics. References Masselink, R. J.H., A. Temme, R. Giménez, J. Casalí, S. Keesstra. Determining hillslope-channel connectivity in an agricultural catchment using rare-earth oxide tracers and random forests. Cuadernos de Investigación Geográfica. (Under review).

  11. Study of sediment movement in an irrigated maize-cotton system combining rainfall simulations, sediment tracers and soil erosion models

    NASA Astrophysics Data System (ADS)

    Guzmán, Gema; Laguna, Ana; Cañasveras, Juan Carlos; Boulal, Hakim; Barrón, Vidal; Gómez-Macpherson, Helena; Giráldez, Juan Vicente; Gómez, José Alfonso

    2015-05-01

    Although soil erosion is one of the main threats to agriculture sustainability in many areas of the world, its processes are difficult to measure and still need a better characterization. The use of iron oxides as sediment tracers, combined with erosion and mixing models opens up a pathway for improving the knowledge of the erosion and redistribution of soil, determining sediment sources and sinks. In this study, magnetite and a multivariate mixing model were used in rainfall simulations at the micro-plot scale to determine the source of the sediment at different stages of a furrow-ridge system both with (+T) and without (-T) wheel tracks. At a plot scale, magnetite, hematite and goethite combined with two soil erosion models based on the kinematic wave approach were used in a sprinkler irrigation test to study trends in sediment transport and tracer dynamics along furrow lengths under a wide range of scenarios. In the absence of any stubble cover, sediment contribution from the ridges was larger than the furrow bed one, almost 90%, while an opposite trend was observed with stubble, with a smaller contribution from the ridge (32%) than that of the bed, at the micro-plot trials. Furthermore, at a plot scale, the tracer concentration analysis showed an exponentially decreasing trend with the downstream distance both for sediment detachment along furrows and soil source contribution from tagged segments. The parameters of the distributed model KINEROS2 have been estimated using the PEST Model to obtain a more accurate evaluation. Afterwards, this model was used to simulate a broad range of common scenarios of topography and rainfall from commercial farms in southern Spain. Higher slopes had a significant influence on sediment yields while long furrow distances allowed a more efficient water use. For the control of runoff, and therefore soil loss, an equilibrium between irrigation design (intensity, duration, water pattern) and hydric needs of the crops should be defined in order to establish a sustainable management strategy.

  12. Assessing bioturbation using micromorphology and biosilicate evidence: A case study of the early-Holocene Brady Soil, central Great Plains, USA

    NASA Astrophysics Data System (ADS)

    Woodburn, T. L.; Hasiotis, S. T.; Johnson, W. C.

    2012-12-01

    The Old Wauneta Roadcut site in southwestern Nebraska exhibits a 1.2 meter-thick exposure of the Brady Soil, a buried paleosol which formed within loess during the Pleistocene-Holocene transition. Excavation of the loess-paleosol sequence has revealed considerable bioturbation by plant roots, invertebrates, and small vertebrates. Bioturbation was not restricted to a single time period, but occurred continually throughout soil development, as evidenced by differing sediment fills and crosscutting relationships. The Brady Soil is an accretionary soil within the uppermost part of the Last Glacial Maximum Peoria Loess. At the base of the solum, the Bkb horizon exhibits an increased illuvial clay and carbonate content, and contains extensive, small (~2cm width), backfilled burrows typically produced by cicada nymphs (Cicadidae) or beetle larvae. The most stable period of the Brady Soil is expressed by the dark (9.8 YR 4/1), thick Ab horizon. This is overlain by an ACb horizon, where soil formation was being extinguished by the onset of Holocene-age Bignell Loess deposition. Within the upper solum and Bignell Loess, a shift in biota activity occurs as indicated by the large burrow (6-12 cm width) and chamber (30-40 cm width) systems observed. Trace sizes suggest that a burrowing rodent, such as the prairie dog (Cynomys sp.) or ground squirrel (Spermophilus sp.), was responsible for their creation. Soil micromorphology was used to distinguish sediment-size classes, mineralogy, and clay morphology of specific loess deposits and soil horizons in order to track displacement of sediment through the profile due to bioturbation. Five block samples were taken in undisturbed sediment and soil horizons for thin-section analysis. Twelve additional samples of burrow cross-sections or bioturbated sediment were analyzed for comparison. Soil features produced by faunal and floral activity were differentiated from features produced by pedologic processes through the identification and classification of granular and spongy microstructures indicative of excrement, calcitic biospheroids, infilling, meniscate backfilling, channel microstructures, and well-oriented clay coatings. Sediment morphology, mineralogy of the infill and backfill material, and biosilicate assemblages were used to trace the material to the source sediment location providing a timeline for events of bioturbation. Defining localized versus deep-mixing events provides an assessment of the disturbance to paleoclimate proxies and age data and will allow for a more accurate paleoclimate reconstruction in this heavily bioturbated paleosol.

  13. The effect of water harvesting techniques on runoff, sedimentation, and soil properties.

    PubMed

    Al-Seekh, Saleh H; Mohammad, Ayed G

    2009-07-01

    This study addressed the hydrological processes of runoff and sedimentation, soil moisture content, and properties under the effect of different water harvesting techniques (treatments). The study was conducted at three sites, representing environmental condition gradients, located in the southern part of the West Bank. For each treatment, the study evaluated soil chemical and physical properties, soil moisture at 30 cm depth, surface runoff and sedimentation at each site. Results showed that runoff is reduced by 65-85% and sedimentation by 58-69% in stone terraces and semi-circle bunds compared to the control at the semi-humid site. In addition, stone terraces and contour ridges significantly reduced the amount of total runoff by 80% and 73%, respectively, at the arid site. Soil moisture content was significantly increased by water harvesting techniques compared to the control in all treatments at the three study sites. In addition, the difference between the control and the water harvesting structures were higher in the arid and semi-arid areas than in the semi-humid area. Soil and water conservation, via utilization of water harvesting structures, is an effective principle for reducing the negative impact of high runoff intensity and subsequently increasing soil moisture storage from rainfall. Jessour systems in the valley and stone terraces were effective in increasing soil moisture storage, prolonging the growing season for natural vegetation, and decreasing the amount of supplemental irrigation required for growing fruit trees.

  14. The Effect of Water Harvesting Techniques on Runoff, Sedimentation, and Soil Properties

    NASA Astrophysics Data System (ADS)

    Al-Seekh, Saleh H.; Mohammad, Ayed G.

    2009-07-01

    This study addressed the hydrological processes of runoff and sedimentation, soil moisture content, and properties under the effect of different water harvesting techniques (treatments). The study was conducted at three sites, representing environmental condition gradients, located in the southern part of the West Bank. For each treatment, the study evaluated soil chemical and physical properties, soil moisture at 30 cm depth, surface runoff and sedimentation at each site. Results showed that runoff is reduced by 65-85% and sedimentation by 58-69% in stone terraces and semi-circle bunds compared to the control at the semi-humid site. In addition, stone terraces and contour ridges significantly reduced the amount of total runoff by 80% and 73%, respectively, at the arid site. Soil moisture content was significantly increased by water harvesting techniques compared to the control in all treatments at the three study sites. In addition, the difference between the control and the water harvesting structures were higher in the arid and semi-arid areas than in the semi-humid area. Soil and water conservation, via utilization of water harvesting structures, is an effective principle for reducing the negative impact of high runoff intensity and subsequently increasing soil moisture storage from rainfall. Jessour systems in the valley and stone terraces were effective in increasing soil moisture storage, prolonging the growing season for natural vegetation, and decreasing the amount of supplemental irrigation required for growing fruit trees.

  15. Significant or negligible sediment and nutrient losses after fire? Pre- and post-fire comparisons

    NASA Astrophysics Data System (ADS)

    Shakesby, R. A.; Ferreira, A. J. D.; Ferreira, C. S. S.; Stoof, C. R.; Urbanek, E.; Walsh, R. P. D.

    2009-04-01

    Prescribed fire (or a controlled burn) is a management tool used in wildfire-prone areas to reduce the fuel load of living and dead biomass, while attempting to keep disturbance of the ground surface and soil to a minimum. We know that wildfire, particularly of moderate or extreme severity, can cause important changes to the chemical and physical properties of soil, typically leading to a reduction in aggregate stability, surface roughness and water storage capacity, and an increase in overland flow. It has also been shown that wildfire disturbance can cause major loss of soil, particularly at plot and hillslope scales. There is less information on soil losses at catchment scales, but it is known that losses particularly of organic-rich fine sediment and nutrients can undergo hillslope to channel transfer, where they can affect water quality. Far less research has been carried out into the effects of prescribed fire on soil and nutrient losses at all scales, but particularly at catchment scales. This paper considers the impact of an experimental fire (equivalent to a severe prescribed fire) on soil and nutrient losses. These losses have been monitored at a range of scales (small rainfall simulation plots, long-term erosion plot, erosion plot, hillslope sediment traps (sediment fences) and catchment) before and after the fire in a 10-ha catchment near Góis, central Portugal, which forms part of the 5-year DESIRE research programme concerning desertification and its mitigation at a range of study sites worldwide. The catchment has steep slopes covered mainly with scrub vegetation ranging from c. 0.15 to 2m in height. The soil is thin, stony and highly water repellent. Long-term pre-burn erosion rates are known from a c. 10-year record of soil losses from a small erosion plot (8 x 2m in size) and sediment accumulation in the weir pool of a subcatchment gauging station. Rainfall simulations carried out under dry and wet antecedent conditions before and after the fire, eroded soil collected in sediment fences installed in strategic locations on the catchment slopes and suspended sediment and bedload determinations at the catchment gauging station provide the evidence for pre- and post-fire erosional losses. Comparison with wildfire effects is provided by instrumented scrub-covered hillslopes burnt in early summer 2008 in the same area. In addition to monitoring soil losses in the small catchment, losses of selected nutrients in eroded soil and runoff together with determinations of pre- and post-fire vegetation cover, fuel loads and soil water repellency have been determined. The soil degradational implications are discussed and placed in the context of the literature on prescribed fire and wildfire impacts from elsewhere in the Mediterranean and from further afield.

  16. Human activity and climate variability impacts on sediment discharge and runoff in the Yellow River of China

    NASA Astrophysics Data System (ADS)

    He, Yi; Wang, Fei; Mu, Xingmin; Guo, Lanqin; Gao, Peng; Zhao, Guangju

    2017-07-01

    We analyze the variability of sediment discharge and runoff in the Hekou-Longmen segment in the middle reaches of the Yellow River, China. Our analysis is based on Normalized Difference Vegetation Index (NDVI), sediment discharge, runoff, and monthly meteorological data (1961-2010). The climate conditions are controlled via monthly regional average precipitation and potential evapotranspiration (ET0) that are calculated with the Penman-Monteith method. Data regarding water and soil conservation infrastructure and their effects were investigated as causal factors of runoff and sediment discharge changes. The results indicated the following conclusions: (1) The sediment concentration, sediment discharge, and annual runoff, varied considerably during the study period and all of these factors exhibited larger coefficients of variation than ET0 and precipitation. (2) Sediment discharge, annual runoff, and sediment concentration significantly declined over the study period in a linear fashion. This was accompanied by an increase in ET0 and decline in precipitation that were not significant. (3) Within paired years with similar precipitation and potential evapotranspiration conditions (SPEC), all pairs showed a decline in runoff, sediment discharge, and sediment concentration. (4) Human impacts in this region were markedly high as indicated by NDVI, and soil and water measurements, and especially the soil and water conservation infrastructure resulting in an approximately 312 Mt year-1 of sediment deposition during 1960-1999.

  17. Between and within-field variation in physico-chemical soil properties of vineyards: implications for terroir zoning and management in Heuvelland, Belgium

    NASA Astrophysics Data System (ADS)

    Tavernier, Emma; Verdoodt, Ann; Cornelis, Wim; Delbecque, Nele; Tiebergijn, Lynn; Seynnaeve, Marleen; Gabriels, Donald

    2015-04-01

    The 'Heuvelland' region with a surface area of 94 km² is situated in the Province of West Flanders, Belgium, bordering with France. The region comprises a number of hills ("heuvel") on which a fast growing 'wine culture' is developing. Both professional as well as non-professional wine makers together cultivate about 19 ha of vineyards, and are still expanding. Grapes cultivated include Chardonnay, Pinot gris and Pinot noir among others. The small-scale, strongly dispersed vineyards are located in different landscape positions of variable aspect. The objective of our preliminary study was to assess the between-field and within-field variation in physico-chemical soil properties of these vineyards with the aim to better characterise the terroir(s) in Heuvelland and provide guidelines for soil management. Fourteen vineyards from five different wineries were selected for detailed soil sampling. Twenty-five sampling sites were chosen according to the topography, soil map units and observed variability in grape growth. The soil was sampled using 15 cm depth increments up to a depth of 60 cm or a shallower lithic contact. Composite samples of 5 sampling locations along the contour lines were taken per within-field zone. Besides the texture, pH, organic carbon, total nitrogen, available phosphorous and exchangeable base cations (Ca, Mg, K), also some micronutrients (Fe, B, Cu, Mn) were determined using standard laboratory procedures. The soils developed on Quaternary niveo-eolian sandy loam and loamy sediments of variable thickness covering marine sandy and clayey sediments of the Tertiary. Where the Tertiary clayey sediments occur at shallow depth, they can strongly influence the internal drainage. At higher positions in the landscape, iron-rich sandstone layers are found at shallow depth. Fragments of this iron-rich sandstone can also be found at lower positions (colluvial material). This iron sandstone is claimed to contribute to the unique character of this wine growing region. According to the soil map of Belgium (scale 1:20,000), the soils are characterized by variable depth, texture, internal drainage and profile development. As such, the 23 vineyards in Heuvelland are found on 21 different soil types; of which 12 different soil types are included within our sampling strategy. Our sampling furthermore revealed an even greater variability in physico-chemical soil properties than reflected by the soil map. This leads to a 'tentative' conclusion that Heuvelland cannot be considered as one natural terroir as such and that the wine growers can potentially improve their production by adapting their management to local soil properties using the improved knowledge on the vineyard soils.

  18. In-filled reservoirs serving as sediment archives to analyse soil organic carbon erosion - Taking a closer look at the Karoo rangelands

    NASA Astrophysics Data System (ADS)

    Krenz, Juliane; Greenwood, Philip; Kuhn, Brigitte; Heckrath, Goswin; Foster, Ian; Boardman, John; Meadows, Michael; Kuhn, Nikolaus

    2016-04-01

    The semi-arid rangelands of the Great Karoo region in South Africa, which are nowadays characterized by badlands on the foot slopes of upland areas and complex gully systems in valley bottoms, have experienced a number of environmental changes. With the settlement of European farmers in the late 18th century agricultural activities increased, leading to overgrazing which probably acted as a trigger to land degradation. As a consequence of higher water demands and shifting rainfall patterns, many dams and small reservoirs have been constructed to provide drinking water for cattle or to facilitate irrigation during dry periods. Most of these dams are now filled with sediment and many have become breached, revealing sediment archives that can be used to analyse land use changes as well as carbon erosion and deposition during the last ca. 100 years. In this ongoing project, a combination of analytical methods that include drone imagery, landscape mapping, erosion modelling and sediment analysis have been employed to trace back the sediment origin and redistribution within the catchment, setting a special focus on the carbon history. Sediment deposits from a silted-up reservoir were analysed for varying physicochemical parameters, in order to analyse erosional and depositional patterns. A sharp decrease in total carbon content with decreasing depth suggests that land degradation during and after the post-European settlement most likely triggered erosion of the relatively fertile surface soils which presumably in-filled the reservoirs. It is assumed that the carbon-rich bottom layers of the dam deposits originate from these eroded surface soils. A combination of erosion modelling and sediment analysis will be used to determine the source areas of the depositional material and might clarify the question if land degradation in the Karoo has resulted in its return from being a net sink of carbon into a net source of carbon.

  19. Tracing metal sources in core sediments of the artificial lake An-Dong, Korea: Concentration and metal association.

    PubMed

    Choi, Mansik; Park, Jongkyu; Cho, Dongjin; Jang, Dongjun; Kim, Miseon; Choi, Jongwoo

    2015-09-15

    The concentration and source of trace metals in the artificial lake An-Dong, which has widespread abandoned mines and a Zn smelter upstream of the drainage basin, were investigated. Soils (18ea), stream waters (15ea) and sediments (15ea) in the main channel and five tributaries downstream of the Zn smelter towards the lake (~ 50 km downstream) were collected. And two core sediments were also taken from the middle of the lake. All samples were analyzed for trace metals in bulk and in a 1N HCl-leached fraction. Although the soil and stream sediments consisted mostly of sand-sized grains, concentrations of metals (Cu, Zn, Cd and Pb) were very high in all samples, including soils, stream waters and sediments at sites near the Zn smelter. However the metal concentrations decreased rapidly downstream, suggesting that the area of impact of the smelter lies within 5 km. Highly enriched metal concentrations were also found in dated core sediments from the lake; while the highest concentrations of Co, Ni, As, Cu, Zn, Cd and Pb were detected in the bottom of the sediment core (dated 1980) they decreased towards 2000, and only Cu, Zn and Cd concentrations increased again in present-day samples. Since the temporal variation in metal concentrations appeared consistent with historical variation in ore mining and Zn smelter production rates, a model combining the production rates of each was developed, which estimated 3%, 12% and 7% contributions from Zn smelter compared to ore mining production rate to levels of Cu, Cd and Zn, respectively, suggesting the different pathways by different sources. In addition, analysis of Cd/Zn and Cu/Zn ratios showed that contamination from ore mining decreased from 1980 to 2000, and smelting processes were most likely responsible for metal enrichment (Cu, Cd and Zn) from 2000 to the present. Copyright © 2015 Elsevier B.V. All rights reserved.

  20. Interactions between fauna and environment in recent alluvial soils (Dunajec River, SE Poland)

    NASA Astrophysics Data System (ADS)

    Mikuś, Paweł; Uchman, Alfred

    2017-04-01

    Recent riverine system is a particular place for interactions between fauna and the deposited sediments containing young and old alluvial soils. It is characterized by large energy gradients in relatively short time, which forces special adaptations of burrowing animals recorded in bioturbation structures. Predators produce mainly shelter burrows (interpreted as domichnia), and saprofags, especially earthworms, produce locomotion and feeding structures (pascichnia). Such structures have been studied in non- or poorly vegetated, sandy or muddy Holocene alluvia in the lower reach of the Dunajec River flowing through the Carpathian Foredeep in SE Poland. The observed burrows are mostly produced by a variety of organisms, including the European mole (Talpa europaea), common earthworm (Lumbricus terrestris), ground beetles (Carabidae), solitary bees (Ammophila), red fox (Vulpes vulpes), European beaver (Castor fiber), shrews (Soricidae), European otter (Lutra lutra), several species of mice (Muridae), voles (Myodae, Microtae), and the swallow sand martin (Riparia riparia). Burrows of a few species of ground beetles have been subjected to more detailed studies. Fertile deposits of older (early to middle Holocene) terraces, formed with many long-term interruptions in sedimentation processes, have a well-developed soil levels, more vulnerable to burrowing than recently deposited sediments. The terraces contain layers of sands and muds, which primary sedimentary structures and layer boundaries are completely or partly disturbed by bioturbation. Organic-rich muds have been moved up and down and mixed with sand. Moreover, sediments have been leached into open burrows during floods or rainfalls. In the natural levee sediments, mostly fine to medium sands, are horizontally burrowed, foremost by earthworms (Lumbricidae). Vertical, long (over 2 m deep) burrows of larger earthworms cross cut the natural levee sediments and enter buried soils. They were formed during a long period between flooding events reaching into the soil profile. Not rarely, the vertical burrows follow living or dead roots. As the European mole feed on earthworms, their burrows commonly co-occur. Diversity and abundance of burrowing animals in the riverine environment are mainly controlled by water-level fluctuations, foremost these which cause floods or droughts. The highest biodiversity of infauna occurs under moderate level of river disturbances. With low level of disturbances, larger, long-living species dominate, whereas with high-level disturbances small, short-living forms prevail.

  1. Estimation of sediment deposits in the Ghézala reservoir in northern Tunisia

    NASA Astrophysics Data System (ADS)

    Mathlouthi, Majid; Lebdi, Fethi

    2018-04-01

    The control of sedimentation in a reservoir provides a global evaluation of the process of erosion and transportation of sediment. Knowledge of sedimentation is useful for reservoir management. Bathymetric surveys can be used to assess the silting volume of dams. The results of two surveys of the Ghézala dam reservoir in northern Tunisia are available. The measurements provide initial information about the quantity and variability of silting and the mechanism of sediment deposition. According to the results of measurements, the average annual specific sediment yield of the Ghézala dam watershed is estimated at 1851 t km-2 yr-1. The annual average sediment volume trapped varies from 23 000 m3 in 1993 to 66 692 m3 in 2011. The sedimentation rates increases from 0.20 to 0.57 % overtime. The results indicate interdependence between the specific erosion rates and the occurrence of soils on steep slopes. The pressure exerted on the soil by plowing as well as overgrazing to meet the needs of the population of this area has exposed the soil to continued deterioration manifested by increased erosion endangering the only source of revenue for the area.

  2. Modelling suspended-sediment propagation and related heavy metal contamination in floodplains: a parameter sensitivity analysis

    NASA Astrophysics Data System (ADS)

    Hostache, R.; Hissler, C.; Matgen, P.; Guignard, C.; Bates, P.

    2014-09-01

    Fine sediments represent an important vector of pollutant diffusion in rivers. When deposited in floodplains and riverbeds, they can be responsible for soil pollution. In this context, this paper proposes a modelling exercise aimed at predicting transport and diffusion of fine sediments and dissolved pollutants. The model is based upon the Telemac hydro-informatic system (dynamical coupling Telemac-2D-Sysiphe). As empirical and semiempirical parameters need to be calibrated for such a modelling exercise, a sensitivity analysis is proposed. An innovative point in this study is the assessment of the usefulness of dissolved trace metal contamination information for model calibration. Moreover, for supporting the modelling exercise, an extensive database was set up during two flood events. It includes water surface elevation records, discharge measurements and geochemistry data such as time series of dissolved/particulate contaminants and suspended-sediment concentrations. The most sensitive parameters were found to be the hydraulic friction coefficients and the sediment particle settling velocity in water. It was also found that model calibration did not benefit from dissolved trace metal contamination information. Using the two monitored hydrological events as calibration and validation, it was found that the model is able to satisfyingly predict suspended sediment and dissolve pollutant transport in the river channel. In addition, a qualitative comparison between simulated sediment deposition in the floodplain and a soil contamination map shows that the preferential zones for deposition identified by the model are realistic.

  3. NEW GIS WATERSHED ANALYSIS TOOLS FOR SOIL CHARACTERIZATION AND EROSION AND SEDIMENTATION MODELING

    EPA Science Inventory

    A comprehensive procedure for computing soil erosion and sediment delivery metrics has been developed which utilizes a suite of automated scripts and a pair of processing-intensive executable programs operating on a personal computer platform.

  4. Ecoenzymatic Stoichiometry of Microbial Organic Nutrient Acquisition in Soil and Sediment

    EPA Science Inventory

    Terrestrial soils and freshwater sediments contain reserves of organic carbon estimated at 1500 Pg and 0.2 Pg, respectively. Mineralization of this organic matter by heterotrophic microorganisms drives global carbon and nutrient cycles, controlling plant production and atmospher...

  5. Residue determination and levels of glyphosate in surface waters, sediments and soils associated with oil palm plantation in Tasik Chini, Pahang, Malaysia

    NASA Astrophysics Data System (ADS)

    Mardiana-Jansar, K.; Ismail, B. S.

    2014-09-01

    Levels of glyphosate and its main metabolite were determined in surface water, soil and sediment samples from an oil palm plantation area located at Tasik Chini, Pahang, Malaysia. The optimization analytical method has been developed for the determination of glyphosate herbicide and its metabolite amino-methyl-phosphonic acid (AMPA) in surface waters to a level of 0.1μg/L, while in sediments and soils to a level of 0.5μg/g with a good linearity in the calibration range of 1-100μg/L. The procedure involves a pre-columnderivatization step with 9-fluorenyl-methyl-chloroformate (FMOC-Cl) yielding highly fluorescent derivatives of the analytes which can be determined by HPLC with fluorescence detection. In the field, levels of glyphosate in surface waters ranges from not detected to 1.0mg/L, while in soils and sediments were from not detected to 6.0mg/kg. For AMPA, the residues in surface waters were between not detected to 2.0mg/L, while in soil and sediment samples were from not detected to 5mg/kg. This variation of glyphosate and AMPA levels depended directly on time of pesticide application and the season.

  6. Role of freeze-thaw cycles and chlorpyrifos insecticide use on diffuse Cd loss and sediment accumulation

    NASA Astrophysics Data System (ADS)

    Wang, Fangli; Ouyang, Wei; Hao, Fanghua; Jiao, Wei; Shan, Yushu; Lin, Chunye

    2016-06-01

    Freeze-thaw cycles are predicted to increase in cold temperate regions. The potential influence of the interactions of freeze-thaw cycles and agrochemicals on the release of Cd into river water is unknown. In this study, the interactions of freeze-thaw cycles and chlorpyrifos (FC) on Cd mobility in soils were analysed. The spatial variability of soil Cd under long-term intensive tillage in a freeze-thaw agro-system was also identified. The temporal variation of sediment Cd was detected based on analysis of the sediment geochemistry. The results showed that FC increased soil Cd mobility, with an increase of approximately 10% in CaCl2-extractable Cd. The increased mobile fractions of water-soluble and exchangeable Cd originated from the decreased fraction of Fe-Mn-oxide-associated Cd and organic matter-bound Cd. The total Cd content in the surface soil followed the zonally decreasing trend of dry land > paddy land > natural land. The Cd concentrations and sedimentation rates of the sediment core generally increased from 1943 to 2013 due to agricultural exploration and farmland irrigation system construction, indicating an increase of the Cd input flux into water. The results provide valuable information about the soil Cd transport response to the influence of climatic and anthropogenic factors in cold intensive agro-systems.

  7. PHYTOTECHNOLOGIES IN THE UNITED STATES: GROWING SOLUTIONS TO ENVIRONMENTAL CHALLENGES

    EPA Science Inventory

    Phytotechnology may be defined as the use of plants to contain, sequester, remove, or degrade organic and inorganic contaminants in soils, sediments, surface water, and groundwater. Mechanisms employed by the plant community may include transpiration (phytovolatilization), plant...

  8. Retention and mitigation of metals in sediment, soil, water, and plant of a newly constructed root-channel wetland (China) from slightly polluted source water.

    PubMed

    Wang, Baoling; Wang, Yu; Wang, Weidong

    2014-01-01

    Constructed root-channel wetland (CRCW) is a term for pre-pond/wetland/post-pond complexes, where the wetland includes plant-bed/ditch landscape and root-channel structure. Source water out of pre-ponds flows through alternate small ditches and plant beds with root-channels via a big ditch under hydraulic regulation. Then source water flows into post-ponds to finish final polishing. This article aims to explore the potential of components of a pilot CRCW in China on mitigating metals in micro-polluted source water during its initial operation stage. We investigated six heavy metals (Cd, Cr, Cu, Ni, Zn, and Pb) in surface sediment, plant-bed subsurface soil, water, and aquatic plants during 2012-2013. Monitoring results showed that pond/ditch sediments and plant-bed soil retained a significant amount of Cr, Ni, and Zn with 93.1%, 72.4%, and 57.5% samples showing contamination factor above limit 1 respectively. Remarkably the high values of metal enrichment factor (EF) occurred in root-channel zones. Water monitoring results indicated that Ni, Zn, and Pb were removed by 78.5% (66.7%), 57.6% (59.6%), and 26.0% (7.5%) in east (west) wetland respectively. Mass balance estimation revealed that heavy metal mass in the pond/ditch sediments accounted for 63.30% and that in plant-bed soil 36.67%, while plant uptake occupied only 0.03%. The heavy metal accretion flux in sediments was 0.41 - 211.08 μg · cm(-2) · a(-1), less than that in plant-bed soil (0.73 - 543.94 μg · cm(-2) · a(-1)). The 1.83 ha wetland has retained about 86.18 kg total heavy metals within 494 days after operation. This pilot case study proves that constructed root-channel wetland can reduce the potential ecological risk of purified raw water and provide a new and effective method for the removal of heavy metals from drinking water sources.

  9. Spatial and temporal distributions of hexabromocyclododecanes in the vicinity of an expanded polystyrene material manufacturing plant in Tianjin, China.

    PubMed

    Zhu, Hongkai; Zhang, Kai; Sun, Hongwen; Wang, Fei; Yao, Yiming

    2017-03-01

    To investigate the environmental fate of 3 main hexabromocyclododecane diastereoisomers (α-, β-, and γ-HBCDs), samples from various environmental media, including outdoor settled dust, soil, sediment, plant tissues (holly, cypress and pine) and marine species (shrimp, crab and fish) were obtained around an expanded polystyrene material manufacturing plant in Tianjin, China. The 3 main HBCD diastereoisomers were detected with the total concentrations ranging from 328 to 31,752 ng/g dry weight (dw), 2.91-1730 ng/g dw, 23.5-716 ng/g dw, 3.45-2494 ng/g dw, and 0.878-44.8 ng/g dw in the dust, soil, sediment, plant tissues, and marine species, respectively. This indicated that a point source of HBCDs could bring wide impact on its vicinal environment. A significant increasing trend of HBCDs concentrations was noted, as indicated by 12.9-41.6% of increasing rates in total concentrations of HBCDs at four sediment sites in the past five years. The diastereoisomer profiles were sorted into 3 groups: dust, soil and sediment, which had no statistical difference from commercial EPS-products (p > 0.05); plant tissues, which showed a moderate increase of α-isomer (22.9 ± 3.3%); and marine species, which were dominated by α-isomer (62.6 ± 2.8%). For α- and β-isomers, the results of enantiomeric analysis showed a preferential accumulation of the (+)-enantiomer in part of plant tissues and all marine organisms (p < 0.05). However, there was no enantioselectivity of the 3 isomers in dust, soil, and sediment samples (p > 0.05). Besides, marine food web magnification is observed for HBCDs, with trophic magnification factors close to 2. The daily intakes of HBCDs were estimated to be 0.058-5.84 ng/kg-bw/day for local residents through dust and soil ingestion and 0.048-8.43 ng/kg-bw/day for Tianjin citizens through seafood consumption. Copyright © 2016 Elsevier Ltd. All rights reserved.

  10. New ways of using an old isotopic system - meteoric 10-Be is back and ready to do geomorphology

    NASA Astrophysics Data System (ADS)

    Bierman, P.; Reusser, L.; Pavich, M.

    2009-04-01

    Meteoric 10-Be, produced in the atmosphere and delivered in precipitation, is an important tracer of sediment and geomorphic processes. This talk will review several decades of work measuring 10-Be adhered to soil and sediment collected from varied terrains around the world. We will then present new data and modeling approaches demonstrating the rich potential but complex, dynamic nature of this isotope system. Considering all of these data, we will examine the utility of meteoric10-Be, produced in the atmosphere and delivered in precipitation, as a tracer of watershed and hillslope sediment transport processes at a variety of spatial scales. We will finish the talk by examining uncertainties that require additional research to resolve. After a brief hay-day in the 1980s, tracing sediment down rivers, dating a few terraces, and following sediment through subduction zones, meteoric or garden variety 10-Be was largely forgotten. It's been lurking somewhere in the dark corners of isotope geoscience while its more famous but difficult-to-measure twin, the 10-Be produced in quartz, got all the attention. Recently, several research groups have again begun to build upon the excellent foundation constructed by those working in the 1980s and early 1990s. New data from a series of soil pits on hillslopes from around the world suggest that meteoric 10-Be is mobile in the soil column moving from the more acidic, organic-rich A-horizon to the B-horizon. Meteoric 10-Be concentrations are well correlated with both soil pH and extractable Al suggesting that Be is retained in Al-rich grain coatings that we know, from numerous attempts to purify riverine quartz, survive fluvial transport all too well. The important take-away message is that meteoric 10-Be is mobile in soil fluids while in situ 10-Be only moves with the quartz grains in which it resides. Depth profiles of in situ and meteoric 10-Be can be quite different, helping us to learn about rates of soil stirring and 10-Be translocation. Both new (New Zealand and central Appalachians) and existing data (Potomac, Europe, South America) suggest that the concentration of 10-Be adhered to sediment can be used to estimate basin-scale rates of denudation as well as to trace, through mixing models, the source of sediment in a watershed. The approach is founded on the work of Brown et al. (1988) and employs similar thinking to the approach taken when in situ 10-Be is used to estimate basin scale rates of erosion (Bierman and Steig, 1996; Granger et al., 1996; Brown et al., 1995) and mixing at tributary junctions. Comparison of in situ and meteoric 10-Be concentrations measured in the same sediment samples can suggest the depth and style of erosion when the depth dependence of meteoric 10-Be has been constrained by soil pit profiles and a bit of guesswork. Lingering uncertainties (and significant opportunities for research) include poorly constrained delivery rates of 10-Be from the atmosphere over both time and space as well the effect of sediment grain size and mean annual precipitation on meteoric 10-Be concentration.

  11. Microbial community and nitrogen cycling shift with snowmelt in high-elevation barren soils of Mount Rainier National Park

    NASA Astrophysics Data System (ADS)

    Simpson, A.; Zabowski, D.

    2015-12-01

    Climate change and nutrient deposition have the potential to accelerate soil formation in high-elevation sediments recently exposed by glacier or snow melt. This process has implications not only for ecosystem formation on Earth but for the formation of Earth-like ecosystems on other planets and icy moons. Research into microbial communities shifting from subnival to mesotrophic conditions has mainly focused on changes on respiration and biomass, and is generally limited to one or two well-studied geographical locations. In particular, more information is needed on microbial shifts in snow-covered volcanic sediments, which may prove the closest analog to the most 'habitable' non-terrestrial environments for Earth microorganisms. We sampled in volcanic soil and sediment along gradients of elevation and snowmelt - dry soil, moist soil next to snowpack, and soil underneath snowpack - at the Muir Snowfields at Mount Rainier National Park, in order to investigate changes in carbon and nitrogen compounds, microbial diversity and gene expression. Initial results show a decrease in available ammonium and increase in microbial biomass carbon in exposed sediment with increasing soil moisture, and a sharp decrease in microbial C:N ratios after snowmelt and drying. Available/labile organic carbon and organic nitrogen decrease strongly with elevation, while microbial biomass carbon and nitrogen and mineral nitrogen compounds show no change with elevation. Though gene expression data is needed for confirmation, we hypothesize that these snowfields receive strong wind-borne deposits of carbon and nitrogen but that chemoautotrophic communities under semi-permanent snowpack do not shift to more mesotrophic communities until after exposed sediment has already begun to desiccate, limiting soil formation.

  12. Forest soil erosion prediction as influenced by wildfire and roads

    NASA Astrophysics Data System (ADS)

    Cao, L.; Brooks, E. S.; Elliot, W.

    2017-12-01

    Following a wildfire, the risk of erosion is greatly increased. Forest road networks may change the underlying topography and alter natural flow paths. Flow accumulation and energy can be redistributed by roads and alter soil erosion processes. A LiDAR (Light Detection and Ranging) DEM makes it possible to quantify road topography, and estimate how roads influence surface runoff and sediment transport in a fire-disturbed watershed. With GIS technology and a soil erosion model, this study was carried out to evaluate the effect of roads on erosion and sediment yield following the Emerald Fire southwest of Lake Tahoe. The GeoWEPP model was used to estimate onsite erosion and offsite sediment delivery from each hillslope polygon and channel segment before and after fire disturbance in part of the burned area. The GeoWEPP flow path method was used to estimate the post-fire erosion rate of each GIS pixel. A 2-m resolution LiDAR DEM was used as the terrain layer. The Emerald Fire greatly increased onsite soil loss and sediment yields within the fire boundary. Following the fire, 78.71% of the burned area had predicted sediment yields greater than 4 Mg/ha/yr, compared to the preburn condition when 65.3% of the study area was estimated to generate a sediment yield less than 0.25 Mg/ha/yr. Roads had a remarkable influence on the flow path simulation and sub-catchments delineation, affecting sediment transport process spatially. Road segments acted as barriers that intercepted overland runoff and reduced downslope flow energy accumulation, therefore reducing onsite soil loss downslope of the road. Roads also changed the boundary of sub-catchment and defined new hydrological units. Road segments can transport sediment from one sub-catchment to another. This in turn leads to the redistribution of sediment and alters sediment yield for some sub-catchments. Culverts and road drain systems are of vital importance in rerouting runoff and sediment. Conservation structures can be installed to avoid sediment deposition or debris accumulation on the road surface. On the other hand, the outlets of culverts might be at a high risk of increasing downstream channel erosion due to the large amount of runoff. This implies that conservation measurements should be considered to control the runoff and sediment output from culverts.

  13. Integrating remotely sensed hydrologic parameters into an index of sediment connectivity

    NASA Astrophysics Data System (ADS)

    Ahlmer, Anna-Klara; Kalantari, Zhara; Cavalli, Marco; Crema, Stefano

    2017-04-01

    As a consequence of a changing climate the occurrence of unexpected events, like flooding and erosion, that affects urban areas will most likely increase. The infrastructure is especially vulnerable to heavy rainfall events due to high costs and long term investments. Accumulation of water and sediments thus has a large impact on the consequences of such events, and it is therefore essential to identify factors that influence the catchment and the occurrence of flooding. Both spatial and temporal characteristics of the patterns of sediment connectivity is important for estimating the sediment contribution and transfer paths in a catchment. In recent years several approaches have been developed to assess sediment connectivity, as for example the geomorphometric indices of sediment connectivity which mainly picture a static frame of the system. With the development of remote sensing technology and the growing availability of satellite images the opportunity to consider also temporal variability and hydrological parameters as soil moisture within this kind of indices is increasing (e.g., Foerster et al., 2014; Gay et al., 2015). However, there is still a knowledge gap in considering the potential of soil moisture satellite imagery in assessing sediment connectivity at the catchment scale. This study aims to integrate spatial and temporal soil moisture properties in the index of sediment connectivity by Cavalli et al. (2013), which can be used to predict where flood events will have the strongest impact. The results will provide decision makers with a prediction tool to identify road-intersections that are prone to flood risk at the catchment scale. The method developed in this study would increase awareness and be a basis for decision makers and stakeholders to promote action towards enabling sustainable water and land management. References Cavalli, M., Trevisani, S., Comiti, F., Marchi, L. , (2013) Geomorphometric assessment of spatial sediment connectivity in small Alpine catchments. Geomorphology 188: 31-41, doi:10.1016/j.geomorph.2012.05.007. Foerster, S., Wilczok,.C., Brosinsky, A., Segl, K., (2014) Assessment of sediment connectivity from vegetation cover and topography using remotely sensed data in a dryland catchment in the Spanish Pyrenees. J Soils Sediments 14:1982-2000 Gay, A., Cerdan, O., Mardhel, V., Desmet, M. (2015) Application of an index of sediment connectivity in a lowland area. J. Soils Sediments 16(1), 280-293, doi:10.1007/s11368-015-1235-y,.

  14. Mapping Erosion Risk in California's Rangelands Using the Universal Soil Loss Equation (USLE)

    NASA Astrophysics Data System (ADS)

    Salls, W. B.; O'Geen, T. T.

    2015-12-01

    Soil loss constitutes a multi-faceted problem for agriculture: in addition to reducing soil fertility and crop yield, it compromises downstream water quality. Sediment itself is a major issue for aquatic ecosystems, but also serves as a vector for transporting nutrients, pesticides, and pathogens. Rangelands are thought to be a contributor to water quality degradation in California, particularly in the northern Coast Range. Though total maximum daily loads (TMDLs) have been imposed in some watersheds, and countless rangeland water quality outreach activities have been conducted, the connection between grazing intensity recommendations and changes in water quality is poorly understood at the state level. This disconnect gives rise to poorly informed regulations and discourages adoption of best management practices by ranchers. By applying the Universal Soil Loss Equation (USLE) at a statewide scale, we highlighted areas most prone to erosion. We also investigated how two different grazing intensity scenarios affect modeled soil loss. Geospatial data layers representing the USLE parameters—rainfall erosivity, soil erodibility, slope length and steepness, and cover—were overlaid to model annual soil loss. Monitored suspended sediment data from a small North Coast watershed with grazing as the predominant land use was used to validate the model. Modeled soil loss values were nearly one order of magnitude higher than monitored values; average soil loss feeding the downstream-most site was modeled at 0.329 t ha-1 yr-1, whereas storm-derived sediment passing the site over two years was calculated to be 0.037 t ha-1 yr-1. This discrepancy may stem from the fact that the USLE models detached sediment, whereas stream monitoring reflects sediment detached and subsequently transported to the waterway. Preliminary findings from the statewide map support the concern that the North Coast is particularly at risk given its combination of intense rain, erodible soils, and relatively steep terrain, though there is a fair degree of variability statewide.

  15. Organochlorine pesticides in residential soils and sediments within two main agricultural areas of northwest Mexico: Concentrations, enantiomer compositions and potential sources.

    PubMed

    Sánchez-Osorio, José Luis; Macías-Zamora, José Vinicio; Ramírez-Álvarez, Nancy; Bidleman, Terry F

    2017-04-01

    The agricultural Mexicali and Yaqui valleys (MV, YV) in northwest Mexico were heavily treated with organochlorine pesticides in the past. Residential soils and agricultural drain sediments were sampled in 2008-2009 and analyzed for DDTs (o,p'- and p,p'- isomers of DDE, DDD and DDT); hexachlorocyclohexanes (α-, β-, γ- and δ-HCH) and chlordanes (trans-chlordane, cis-chlordane, heptachlor and heptachlor exo-epoxide). Geometric means (GMs) (ng g -1 dry weight) were: MV soils (n = 27) ΣDDT 22, ΣHCH 0.80, ΣCHL 0.88; YV soils (n = 25) ΣDDT 5.0, ΣHCH 0.23, ΣCHL 0.67; MV sediments (n = 3) ΣDDT 5.0, ΣHCH 0.23, ΣCHL 0.53; YV sediments (n = 8) ΣDDT 2.6, ΣHCH 0.12, ΣCHL 0.090. GMs were significantly higher (p < 0.05) in MV than YV soils for ΣDDT and ΣHCH, but not for ΣCHL. Comparison to worldwide regulatory guideline values (RGVs) for residential soils showed all compounds below mean or GM RGVs, but above the lowest RGV in some cases. Low p,p'-DDT/(p,p'-DDT + p,p'-DDE) in most soils indicated aged residues. Lack of p,p'-DDT metabolism might account for its dominance in a few soils. HCH isomer profiles suggested aged technical HCH in the YV, and technical HCH + lindane in the MV. Heptachlor dominated the ΣCHL, probably from application of technical heptachlor as well as chlordane. Chiral compounds were nonracemic in soils and sediments and indicated enantioselective microbial degradation of (+)α-HCH, (-)trans-chlordane, (-)cis-chlordane and (+)o,p'-DDT. Depletion of (+)o,p'-DDT in soils may account for similar enantiomer signatures previously reported in air of northwest Mexico. Copyright © 2017 Elsevier Ltd. All rights reserved.

  16. Sebkhet Karkura: an example of a semi-arid Mediterranean wetland rich in biotic sediments

    NASA Astrophysics Data System (ADS)

    Abdulsamad, Esam O.; Elbabour, Mansour M.

    2014-05-01

    Habitat wetlands in Libya may be grouped into several distinct varieties, according to climate, water supply, soils, and biotic diversity. They include coastal Sebkhas (salt marshes), karst lakes, Wadi estuaries, below sea-level desert lakes, and balat flats (playas) where the soil is saturated part of some rainy seasons forming a kind of ephemeral, shallow lakes in pre-desert areas. The most prominent, however, are the extensive coastal salt marshes. These have either organic or inorganic soils, or both, depending on their location and climate conditions. Soils common to most coastal wetlands are composed largely of inorganic material in the form of sand, silt, or clay; in addition to organic material formed by decayed plants and various biotic sediments. For the purpose of the present poster, however, Sebkhet Karkura, an extensive stretch of about 50 km square (20 km long by an average width of 2.5 km) of Sebkha/wetland formation, located about 80 km southwest of Benghazi, will serve as an example of coastal Sebkhas. Here, the sediments are consisting mostly of dark earth brown sandy silt with salt and gypsum. Pure-salt deposits are normally extracted for salt processing in the area. Loams, silt, gravel, and calcareous sand are also present. At the surface of the wetland, calcarenites are fairly common but sand-beach and sand-dunes are representing the major sediments along the coastal wetland area. The recent biotal components of these sediments are described and a number of recent small-sized benthic seashells, belonging to phylum mollusca, have been investigated along the seaside of Sabkhet Karkura and several species have been identified. It is worth noting that Sebkhet Karkura, as well as other similar coastal wetlands, currently face serious threats due to human action, especially over exploitation of their resources, urban encroachments, dredging, and solid waste dumping. Increased awareness on the part of the general public of wetland ecological values and functions is essential as a preventive measure against such threats.

  17. Historic brownfields and industrial activity in Kingston, Ontario: assessing potential contributions to mercury contamination in sediment of the Cataraqui River.

    PubMed

    Manion, N C; Campbell, L; Rutter, A

    2010-04-01

    The waterfront of historic Kingston, Ontario (pop: 113,000) has been used for industrial activities for over a century. More than 40 industries have existed within the inner harbour, and while many of these industries are no longer present, the properties that they operated on remain as potential sources of persistent contamination to the present day, including mercury. To assess the extent and distribution of total mercury (THg) contamination, 21 sediment cores as well as pore water samples were collected within the inner harbour of Kingston. The spatial distribution of THg in the surface sediment is not homogenous; with concentrations in the surface sediment along the southwestern shoreline, adjacent to the former industrial properties, are significantly greater (p<0.01) than the rest of the inner harbour, and were above the Federal severe effect limit (>2000 microg/kg;) guideline for sediment. MeHg was detected in some sediment cores, and was found to have a significant, positive correlation with [THg] in the surface sediment (0-5 cm). THg was not found in storm sewer discharges, but was detected in terrestrial soil near the Kingston Rowing Club at a concentration of more than 4000 microg/kg. Significant [THg] was detected in runoff draining from contaminated shoreline soils, indicating that erosion from terrestrial sources may be an ongoing source of Hg to the sediment. It can be concluded that there is an increased risk over time to surrounding ecosystems where properties with historical contamination are not remediated until they are developed. (c) 2010 Elsevier B.V. All rights reserved.

  18. Environmental and Anthropogenic Factors Influencing Mercury Dynamics During the Past Century in Floodplain Lakes of the Tapajós River, Brazilian Amazon.

    PubMed

    Oestreicher, Jordan Sky; Lucotte, Marc; Moingt, Matthieu; Bélanger, Émilie; Rozon, Christine; Davidson, Robert; Mertens, Frédéric; Romaña, Christina A

    2017-01-01

    In the Tapajós River region of the Brazilian Amazon, mercury (Hg) is a prevalent contaminant in the aquatic ecosystem. Few studies have used comprehensive chronological analyses to examine the combined effects of environmental and anthropogenic factors on Hg accumulation in sediments. Total mercury (THg) content was measured in sediments from eight floodplain lakes and Pb 210 isotope analysis was used to develop a timeline of THg accumulation. Secondary data representing environmental and anthropogenic factors were analyzed using geo-spatial analyses. These include land-cover change, hydrometeorological time-series data, lake morphology, and watershed biophysical characteristics. The results indicate that THg accumulation and sedimentation rates have increased significantly at the surface of most sediment cores, sometimes doubling since the 1970s. Human-driven land-cover changes in the watershed correspond closely to these shifts. Tropical deforestation enhances erosion, thereby mobilizing the heavy metal that naturally occurs in soils. Environmental factors also contribute to increased THg content in lacustrine sediments. Climate shifts since the 1980s are further compounding erosion and THg accumulation in surface sediments. Furthermore, variations in topography, soil types, and the level of hydrological connectivity between lakes and the river explain observed variations in THg fluxes and sedimentation. Although connectivity naturally varies among sampled lakes, deforestation of sensitive floodplain vegetation has changed lake-river hydrology in several sites. In conclusion, the results point to a combination of anthropogenic and environmental factors as determinants of increased THg accumulation in tropical floodplain sediments in the Tapajós region.

  19. Central Colorado Assessment Project (CCAP)-Geochemical data for rock, sediment, soil, and concentrate sample media

    USGS Publications Warehouse

    Granitto, Matthew; DeWitt, Ed H.; Klein, Terry L.

    2010-01-01

    This database was initiated, designed, and populated to collect and integrate geochemical data from central Colorado in order to facilitate geologic mapping, petrologic studies, mineral resource assessment, definition of geochemical baseline values and statistics, environmental impact assessment, and medical geology. The Microsoft Access database serves as a geochemical data warehouse in support of the Central Colorado Assessment Project (CCAP) and contains data tables describing historical and new quantitative and qualitative geochemical analyses determined by 70 analytical laboratory and field methods for 47,478 rock, sediment, soil, and heavy-mineral concentrate samples. Most samples were collected by U.S. Geological Survey (USGS) personnel and analyzed either in the analytical laboratories of the USGS or by contract with commercial analytical laboratories. These data represent analyses of samples collected as part of various USGS programs and projects. In addition, geochemical data from 7,470 sediment and soil samples collected and analyzed under the Atomic Energy Commission National Uranium Resource Evaluation (NURE) Hydrogeochemical and Stream Sediment Reconnaissance (HSSR) program (henceforth called NURE) have been included in this database. In addition to data from 2,377 samples collected and analyzed under CCAP, this dataset includes archived geochemical data originally entered into the in-house Rock Analysis Storage System (RASS) database (used by the USGS from the mid-1960s through the late 1980s) and the in-house PLUTO database (used by the USGS from the mid-1970s through the mid-1990s). All of these data are maintained in the Oracle-based National Geochemical Database (NGDB). Retrievals from the NGDB and from the NURE database were used to generate most of this dataset. In addition, USGS data that have been excluded previously from the NGDB because the data predate earliest USGS geochemical databases, or were once excluded for programmatic reasons, have been included in the CCAP Geochemical Database and are planned to be added to the NGDB.

  20. Assessing temporal variations in connectivity through suspended sediment hysteresis analysis

    NASA Astrophysics Data System (ADS)

    Sherriff, Sophie; Rowan, John; Fenton, Owen; Jordan, Phil; Melland, Alice; Mellander, Per-Erik; hUallacháin, Daire Ó.

    2016-04-01

    Connectivity provides a valuable concept for understanding catchment-scale sediment dynamics. In intensive agricultural catchments, land management through tillage, high livestock densities and extensive land drainage practices significantly change hydromorphological behaviour and alter sediment supply and downstream delivery. Analysis of suspended sediment-discharge hysteresis has offered insights into sediment dynamics but typically on a limited selection of events. Greater availability of continuous high-resolution discharge and turbidity data and qualitative hysteresis metrics enables assessment of sediment dynamics during more events and over time. This paper assesses the utility of this approach to explore seasonal variations in connectivity. Data were collected from three small (c. 10 km2) intensive agricultural catchments in Ireland with contrasting morphologies, soil types, land use patterns and management practices, and are broadly defined as low-permeability supporting grassland, moderate-permeability supporting arable and high-permeability supporting arable. Suspended sediment concentration (using calibrated turbidity measurements) and discharge data were collected at 10-min resolution from each catchment outlet and precipitation data were collected from a weather station within each catchment. Event databases (67-90 events per catchment) collated information on sediment export metrics, hysteresis category (e.g., clockwise, anti-clockwise, no hysteresis), numeric hysteresis index, and potential hydro-meteorological controls on sediment transport including precipitation amount, duration, intensity, stream flow and antecedent soil moisture and rainfall. Statistical analysis of potential controls on sediment export was undertaken using Pearson's correlation coefficient on separate hysteresis categories in each catchment. Sediment hysteresis fluctuations through time were subsequently assessed using the hysteresis index. Results showed the numeric hysteresis index varied over time in all three catchments. The exact response was catchment specific reflecting changing sediment availability and connectivity through time as indicated by dominant controls. In the low-permeability grassland catchment, proximal sources dominated which was consistent with observations of active channel bank erosion. Seasonal increases in rainfall increased the erosion potential but continuous grassland cover mitigated against hillslope sediment contributions despite high hydrological connectivity and surface pathways. The moderate-permeability arable catchment was dominated by events with a distal source component but those with both proximal and distal sediment sources yielded the highest sediment quantities. These events were driven by rainfall parameters suggesting sediment were surface derived and the hillslope was hydrologically connected during most events. Through time, a sustained period of rainfall increased the magnitude of negative hysteresis, likely demonstrating increasing surface hydrological connectivity due to increased groundwater saturation. Where increased hydrological connectivity coincided with low groundcover, the largest sediment exports were recorded. Events in the high permeability catchment indicated predominantly proximal sediments despite abundant distal sources from tilled fields. The infiltration dominated high permeability soils hydrologically disconnected these field sources and limited sediment supply. However, the greatest sediment export occurred in this catchment suggesting thresholds existed, which when exceeded during higher magnitude events, resulted in efficient conveyance of sediments. Hysteresis analysis offers wider utility as a tool to understand sediment pathways and connectivity issues with applications to catchment management strategies.

  1. Mapping soil erosion hotspots and assessing the potential impacts of land management practices in the highlands of Ethiopia

    NASA Astrophysics Data System (ADS)

    Tamene, Lulseged; Adimassu, Zenebe; Ellison, James; Yaekob, Tesfaye; Woldearegay, Kifle; Mekonnen, Kindu; Thorne, Peter; Le, Quang Bao

    2017-09-01

    An enormous effort is underway in Ethiopia to address soil erosion and restore overall land productivity. Modelling and participatory approaches can be used to delineate erosion hotspots, plan site- and context-specific interventions and assess their impacts. In this study, we employed a modelling interface developed based on the Revised Universal Soil Loss Equation adjusted by the sediment delivery ratio to map the spatial distribution of net soil loss and identify priority areas of intervention. Using the modelling interface, we also simulated the potential impacts of different soil and water conservation measures in reducing net soil loss. Model predictions showed that net soil loss in the study area ranges between 0.4 and 88 t ha- 1 yr- 1 with an average of 12 t ha- 1 yr- 1. The dominant soil erosion hotspots were associated with steep slopes, gullies, communal grazing and cultivated areas. The average soil loss observed in this study is higher than the tolerable soil loss rate estimated for the highland of Ethiopia. The scenario analysis results showed that targeting hotspot areas where soil loss exceeds 10 t ha- 1 yr- 1 could reduce net soil loss to the tolerable limit (< 2 t ha- 1 yr- 1). The spatial distribution of soil loss and the sediment yield reduction potential of different options provided essential information to guide prioritization and targeting. In addition, the results can help promoting awareness within the local community of the severity of the soil erosion problem and the potential of management interventions. Future work should include cost-benefit and tradeoff analyses of the various management options for achieving a given level of erosion reduction.

  2. Initial sediment transport model of the mining-affected Aries River Basin, Romania

    USGS Publications Warehouse

    Friedel, Michael J.; Linard, Joshua I.

    2008-01-01

    The Romanian government is interested in understanding the effects of existing and future mining activities on long-term dispersal, storage, and remobilization of sediment-associated metals. An initial Soil and Water Assessment Tool (SWAT) model was prepared using available data to evaluate hypothetical failure of the Valea Sesei tailings dam at the Rosia Poieni mine in the Aries River basin. Using the available data, the initial Aries River Basin SWAT model could not be manually calibrated to accurately reproduce monthly streamflow values observed at the Turda gage station. The poor simulation of the monthly streamflow is attributed to spatially limited soil and precipitation data, limited constraint information due to spatially and temporally limited streamflow measurements, and in ability to obtain optimal parameter values when using a manual calibration process. Suggestions to improve the Aries River basin sediment transport model include accounting for heterogeneity in model input, a two-tier nonlinear calibration strategy, and analysis of uncertainty in predictions.

  3. Contribution of inorganic and organic components to sorption of neutral and ionizable pharmaceuticals by sediment/soil.

    PubMed

    Yamamoto, Hiroshi; Takemoto, Kohei; Tamura, Ikumi; Shin-Oka, Norihiro; Nakano, Takahiro; Nishida, Masayo; Honda, Yuta; Moriguchi, Shigemi; Nakamura, Yudai

    2018-03-01

    Our previous study showed that the sorption coefficient of certain polar pharmaceuticals to river sediment, especially particular amines, was unexpectedly high. Thus, we conducted sorption experiments of selected polar pharmaceuticals and pyrene derivatives, including amines, carboxylic acids, and neutral compounds, to model clay minerals, i.e., montmorillonite and kaolin, in addition to silica sands and humic substances. The contribution of each component was roughly estimated by simple fractionation of the individual sorption coefficients. Relatively high sorption coefficients (K d values) were found, especially for amines on clay minerals, which suggest that electrochemical affinity may play an important role. The estimated contribution percentage suggests a relatively large contribution from inorganic constituents, such as clay minerals, for silt loam soil; in contrast, organic components predominantly contribute for sandy river sediments. These findings could be the key to understanding not only the fate and transport but also bioavailability and environmental risks of pharmaceuticals, which are mostly polar and/or ionizable.

  4. Glomalin accumulated in seagrass sediments reveals past alterations in soil quality due to land-use change

    NASA Astrophysics Data System (ADS)

    López-Merino, Lourdes; Serrano, Oscar; Adame, María Fernanda; Mateo, Miguel Ángel; Martínez Cortizas, Antonio

    2015-10-01

    Arbuscular mycorrhizal fungi (AMF), symbionts with most terrestrial plants, produce glomalin-related soil protein (GRSP), which plays a major role in soil structure and quality. Both fungi hyphae and protein production in soils are affected by perturbations related to land-use changes, implying that GRSP is a sensitive indicator of soil quality. Unfortunately, GRSP degrades within years to decades in oxic environments, preventing its use as palaeoecological proxy. However, GRSP is transported to marine, near-shore anoxic sediments, where it accumulates and remains non-degraded, enabling the assessment of its potential as a palaeoecological proxy for soil ecosystem's health. Exploiting this fact, we have obtained for the first time a long-term record (c. 1250 years) of GRSP content using a Posidonia oceanica seagrass mat sediment core from the Western Mediterranean (Portlligat Bay, Spain). The trends in GRSP content matched well with land-use changes related to agrarian activities reconstructed by pollen analysis. In periods of cultivation, GRSP accumulation in the mat decreased. Given the role played by GRSP, the results suggest that agrarian intensification may have resulted in perturbations to soil quality. Thus, GRSP in seagrass mat sediments can be used to assess long-term trends in continental soil quality induced by human activities. These findings open new possibilities in long-term ecology research, as other anoxic environments could be potentially valid too. Testing them would open the possibility to identify long-term patterns in soil quality and other environmental stressors that could also affect AMF and GRSP production in soils.

  5. High contamination in the areas surrounding abandoned mines and mining activities: An impact assessment of the Dilala, Luilu and Mpingiri Rivers, Democratic Republic of the Congo.

    PubMed

    Atibu, Emmanuel K; Lacroix, Pierre; Sivalingam, Periyasamy; Ray, Nicolas; Giuliani, Gregory; Mulaji, Crispin K; Otamonga, Jean-Paul; Mpiana, Pius T; Slaveykova, Vera I; Poté, John

    2018-01-01

    Abandoned mines and mining activities constitute important sources of toxic metals and Rare Earth Elements (REEs) affecting surrounding environmental compartments and biota. This study investigates the contamination degree and distribution of toxic metals and REEs in contrasting sediment, soil and plant samples surrounding rivers in the African copperbelt area characterized by the presence of numerous abandoned mines, artisanal and industrial mining activities. ICP-MS results highlighted the highest concentration of Cu, Co and Pb in sediments reaching values of 146,801, 18,434 and 899 mg kg -1 , respectively. In soil, the values of 175,859, 21,134 and 1164 mg kg -1 were found for Cu, Co and Pb, respectively. These values are much higher than the sediment guidelines for the protection of aquatic life and international soil clean-up standards. Enrichment factor and geoaccumulation index results indicated important contribution of mining activities to the study sites pollution in addition to natural background. Highest metal accumulation in leaves of Phalaris arundinacea L., was observed, reaching values of 34,061, 5050 and 230 mg kg -1 for Cu, Co, and Pb, respectively. The ∑REE concentration reached values of 2306, 733, 2796 mg kg -1 in sediment, soil and plant samples, respectively. The above results were combined with geographical information including satellite imagery, hydrography and mining concessions. Maps were produced to present the results in a comprehensive and compelling visual format. The results will be disseminated through an innovative mapping online platform to simplify access to data and to facilitate dialogue between stakeholders. Copyright © 2017 Elsevier Ltd. All rights reserved.

  6. METAL SPECIATION IN SOIL, SEDIMENT, AND WATER SYSTEMS VIA SYNCHROTRON RADIATION RESEARCH

    EPA Science Inventory

    Metal contaminated environmental systems (soils, sediments, and water) have challenged researchers for many years. Traditional methods of analysis have employed extraction methods to determine total metal content and define risk based on the premise that as metal concentration in...

  7. DYNAMICS OF MINERAL STRUCTURES AND THE FATE OF METALS IN SOILS AND SEDIMENTS

    EPA Science Inventory

    Significant progress has been made in elucidating sorption reactions that control the partitioning of metals from solution to mineral surfaces in contaminated soil/sediment systems. Surface complexation models have been developed to quantify the forward reaction with reasonable ...

  8. Development and Application of Immunoaffinity Chromatography for Coplanar PCBs in Soil and Sediment

    EPA Science Inventory

    An immunoaffinity chromatography (IAC) column was developed as a simple cleanup procedure for preparing environmental samples for analysis of polychlorinated biphenyls (PCBs). Soil and sediment samples were prepared using pressurized liquid extraction (PLE), followed by the IAC c...

  9. Sediment transport in forested head water catchments - Calibration and validation of a soil erosion and landscape evolution model

    NASA Astrophysics Data System (ADS)

    Hancock, G. R.; Webb, A. A.; Turner, L.

    2017-11-01

    Sediment transport and soil erosion can be determined by a variety of field and modelling approaches. Computer based soil erosion and landscape evolution models (LEMs) offer the potential to be reliable assessment and prediction tools. An advantage of such models is that they provide both erosion and deposition patterns as well as total catchment sediment output. However, before use, like all models they require calibration and validation. In recent years LEMs have been used for a variety of both natural and disturbed landscape assessment. However, these models have not been evaluated for their reliability in steep forested catchments. Here, the SIBERIA LEM is calibrated and evaluated for its reliability for two steep forested catchments in south-eastern Australia. The model is independently calibrated using two methods. Firstly, hydrology and sediment transport parameters are inferred from catchment geomorphology and soil properties and secondly from catchment sediment transport and discharge data. The results demonstrate that both calibration methods provide similar parameters and reliable modelled sediment transport output. A sensitivity study of the input parameters demonstrates the model's sensitivity to correct parameterisation and also how the model could be used to assess potential timber harvesting as well as the removal of vegetation by fire.

  10. Watershed Sediment Losses to Lakes Accelerating Despite Agricultural Soil Conservation Efforts

    PubMed Central

    Heathcote, Adam J.; Filstrup, Christopher T.; Downing, John A.

    2013-01-01

    Agricultural soil loss and deposition in aquatic ecosystems is a problem that impairs water quality worldwide and is costly to agriculture and food supplies. In the US, for example, billions of dollars have subsidized soil and water conservation practices in agricultural landscapes over the past decades. We used paleolimnological methods to reconstruct trends in sedimentation related to human-induced landscape change in 32 lakes in the intensively agricultural region of the Midwestern United States. Despite erosion control efforts, we found accelerating increases in sediment deposition from erosion; median erosion loss since 1800 has been 15.4 tons ha−1. Sediment deposition from erosion increased >6-fold, from 149 g m−2 yr−1 in 1850 to 986 g m−2 yr−1 by 2010. Average time to accumulate one mm of sediment decreased from 631 days before European settlement (ca. 1850) to 59 days mm−1 at present. Most of this sediment was deposited in the last 50 years and is related to agricultural intensification rather than land clearance or predominance of agricultural lands. In the face of these intensive agricultural practices, traditional soil conservation programs have not decelerated downstream losses. Despite large erosion control subsidies, erosion and declining water quality continue, thus new approaches are needed to mitigate erosion and water degradation. PMID:23326454

  11. Watershed sediment losses to lakes accelerating despite agricultural soil conservation efforts.

    PubMed

    Heathcote, Adam J; Filstrup, Christopher T; Downing, John A

    2013-01-01

    Agricultural soil loss and deposition in aquatic ecosystems is a problem that impairs water quality worldwide and is costly to agriculture and food supplies. In the US, for example, billions of dollars have subsidized soil and water conservation practices in agricultural landscapes over the past decades. We used paleolimnological methods to reconstruct trends in sedimentation related to human-induced landscape change in 32 lakes in the intensively agricultural region of the Midwestern United States. Despite erosion control efforts, we found accelerating increases in sediment deposition from erosion; median erosion loss since 1800 has been 15.4 tons ha(-1). Sediment deposition from erosion increased >6-fold, from 149 g m(-2) yr(-1) in 1850 to 986 g m(-2) yr(-1) by 2010. Average time to accumulate one mm of sediment decreased from 631 days before European settlement (ca. 1850) to 59 days mm(-1) at present. Most of this sediment was deposited in the last 50 years and is related to agricultural intensification rather than land clearance or predominance of agricultural lands. In the face of these intensive agricultural practices, traditional soil conservation programs have not decelerated downstream losses. Despite large erosion control subsidies, erosion and declining water quality continue, thus new approaches are needed to mitigate erosion and water degradation.

  12. Constraints on the sources of branched GDGTs in open ocean sediments: dust transport or in situ production?

    NASA Astrophysics Data System (ADS)

    Weijers, J.; Schefuss, E.; Kim, J.; Sinninghe Damsté, J. S.; Schouten, S.

    2012-12-01

    Branched glycerol dialkyl glycerol tetraethers (brGDGTs) are membrane lipids synthesized by soil bacteria that, upon soil erosion, are transported by rivers to the ocean where they accumulate in the near shore sedimentary archive. The degrees of cyclisation (CBT) and methylation (MBT) of these compounds have been shown to relate to soil pH and annual mean air temperature [1]. Therefore, brGDGTs in near shore sedimentary archives can be used to estimate past continental air temperatures and enable a direct comparison of these to marine sea surface temperature estimates obtained from the same samples. In addition, brGDGT abundance relative to crenarchaeol, an isoprenoid GDGT synthesized by marine pelagic Thaumarchaeota, quantified in the branched vs. isoprenoid tetraether (BIT) index, is an indicator of the relative input of soil organic matter in near shore sediments [2]. High BIT values near river outflows testify of relative strong soil organic matter input and generally the BIT index will decrease off shore to values near 0, the marine end-member value. Even in remote open ocean sediments, however, the BIT index will rarely reach 0 as small amounts of brGDGTs are often present. The occurrence of these brGDGTs in open marine settings might be a result of i) dust input, ii) sediment dispersion from near coastal areas, or iii) in situ production in marine sediments. In order to constrain the origin of branched GDGTs in open marine sediments we analyzed i) atmospheric dust samples taken along an equatorial African coastal transect, ii) marine surface waters near and away of the Congo river outflow, iii) a series of surface sediments at and around the Congo deep sea fan, and iv) a series of open marine surface sediments from different oceans with BIT values < 0.08. Our results show that brGDGTs are present, though in relative low amounts, in dust. Their distribution resembles that of soil input as also found in the Congo deep sea fan, with MBT and CBT values that could be representative of tropical African soils. Strikingly, BIT indices are much lower than expected for soils (0.15-0.42), likely as a result of sea spray on the dust filters. Open ocean sediments, on the contrary, are typically characterized by relative high amounts of cyclopentane containing brGDGTs resulting in low CBT values ranging from -0.4 - 0.8. These values are similarly low as reported earlier in marine sediments near Svalbard [3] and in the East China Sea [4], for which in situ production was invoked. Thus, brGDGT transport by dust does seem possible, though quantities are low. Since open ocean brGDGT distributions are markedly different from those in soils and dust, the latter is most likely not a significant source. Our results indicate that production of brGDGTs in ocean sediments, though in relative low amounts, is much more widespread than previously thought. This emphasizes that the MBT-CBT proxy for continental air temperature should only be used at locations where soil organic matter input is significant as evidenced by high BIT indices. References: [1] Weijers J.W.H. et al. (2007) Geochmim. Cosmochim. Acta 71, 703-713. [2] Hopmans E.C. et al. (2004) Earth Planet. Sci. Lett. 224, 107-116. [3] Peterse F. et al. (2009) Org. Geochem. 40, 692-699. [4] Zhu C. Et al. (2011) Org. Geochem. 42, 376-386.

  13. Steady as a rock: Biogeomorphic influence of nurse rocks and slope processes on kūpaoa (Dubautia menziesii) shrubs in Haleakalā Crater (Maui, Hawai'i)

    NASA Astrophysics Data System (ADS)

    Pérez, Francisco L.

    2017-10-01

    This study examines biogeomorphic interactions between nurse rocks, slope processes, and 300 kūpaoa (Dubautia menziesii) shrubs in Haleakalā Crater (Maui, Hawai'i). Research objectives were to: assess the association of kūpaoa with substrates upslope and downslope of plants, and proximity to the closest rock uphill; contrast shrub/substrate relationships with site frequency of sediment types; measure surface soil shear-strength and compressibility on 50 paired locations near boulders; and investigate the aggregation characteristics and spatial patterns of kūpaoa in relation to rock and substrate variation. Data analyzed came from three 100-plant surveys at 3 sites: a plant census at 2720-2975 m altitude, and wandering-quarter transects (WQTs) across two areas (2610-2710 m); ground sediment cover was estimated along four phototransects on these sites. Data for the three 100-plant surveys included substrate type-outcrops, blocks, cobbles, pebbles, exposed soil, organic litter-upslope from each plant, and distance to the largest rock upslope. The two surveys examined along WQTs included substrate type found downslope from kūpaoa, plant height, plant diameters across and along the slope, and distance between successively censused plants. Most plants grew downslope of nurse rocks; > 74% were adjacent to blocks or outcrops, and > 17% near cobbles. Plants showed avoidance for finer substrates; only 5.3% and 2.7% grew on/near bare soils and pebbles, respectively. About 92% of kūpaoa were ≤ 10 cm downslope of rocks; > 89% grew ≤ 2 cm away, and 83% in direct contact with a rock. Some seedlings also grew on pukiawe (Leptecophylla tameiameiae) nurse plants. Several stable rock microsites protected plants from disturbance by slope processes causing debris shift. Site sediments were significantly finer than substrates near plants; shrubs grew preferentially adjacent to boulders > 20 cm wide, which were more common near plants than across sites. Soils downslope of 50 boulders-mean 41.3 cm-showed higher shear strength and compressibility than soils along rock sides. These boulder dams stop descending debris, steadily deflecting them toward rock sides, whereas protected soils downslope of blocks are infrequently disturbed and develop into downslope elongated, clast-free fine-earth flags. Kūpaoa were uniformly dispersed across slopes, showing a single-phase mosaic arrangement, without apparent aggregation. Slopes where kūpaoa grows had a relatively uniform distribution of surface sediments; observed kūpaoa patterns may have resulted from the array of microsites generated by surface rocks and sediments, as shrubs simply responded to such spatial structure.

  14. A Tool for Assessing Future Capacity Loss Due to Sedimentation in the United States' Reservoirs

    NASA Astrophysics Data System (ADS)

    Pinson, A. O.; Baker, B.; White, K. D.

    2017-12-01

    Federal reservoirs are critical components of the United States' water supply, flood risk management, hydropower and navigation infrastructure. These reservoirs included capacity for storage loss due to the deposition of sediment by inflowing streams in their original design. However, the actual rate of capacity loss experienced is controlled in part by climate, topography, soils, and land use/land cover, and may vary from the design. To assess the current and future vulnerability of its reservoirs to sedimentation. USACE has developed an online planning tool to identify USACE reservoirs where sedimentation is currently a problem (e.g., sedimentation rate exceeds design sedimentation rate, or zone losses disproportionately affect authorized purposes), and reservoirs where rates are expected to increase significantly in the future. The goal is to be able to prioritize operation and maintenance actions to minimize the effects of reservoir capacity loss on authorized purposes and help maximize reservoir use life.

  15. Quantitative characterization of short- and long-chain perfluorinated acids in solid matrices in Shanghai, China.

    PubMed

    Li, Fei; Zhang, Chaojie; Qu, Yan; Chen, Jing; Chen, Ling; Liu, Ying; Zhou, Qi

    2010-01-01

    Perfluorinated acids (PFAs) have been recognized as emerging environmental pollutants because of their widespread occurrences, persistence, and bioaccumulative and toxicological effects. PFAs have been detected in aquatic environment and biota in China, but the occurrences of these chemicals have not been reported in solid matrices in China. In the present study, short- and long-chain PFAs (C2-C14) have been quantitatively determined in solid matrices including sediments, soils and sludge collected in Shanghai, China. The results indicate that sludge contains more PFAs than sediments and soils, and the total PFAs concentrations in sediments, soil and sludge are 62.5-276 ng g(-1), 141-237 ng g(-1) and 413-755 ng g(-1), respectively. In most cases, trifluoroacetic acid was the major PFA and accounted for 22-90% of the total PFAs. Although the levels of perfluorooctanoate (PFOA) and perfluorooctanesulfonate (PFOS) were not only lower than trifluoroacetic acid, but also lower than some short-chain PFCAs (

  16. Modelling soil erosion and associated sediment yield for small headwater catchments of the Daugava spillway valley, Latvia

    NASA Astrophysics Data System (ADS)

    Soms, Juris

    2015-04-01

    The accelerated soil erosion by water and associated fine sediment transfer in river catchments has various negative environmental as well as economic implications in many EU countries. Hence, the scientific community had recognized and ranked soil erosion among other environmental problems. Moreover, these matters might worsen in the near future in the countries of the Baltic Region, e.g. Latvia considering the predicted climate changes - more precisely, the increase in precipitation and shortening of return periods of extreme rainfall events, which in their turn will enable formation of surface runoff, erosion and increase of sediment delivery to receiving streams. Thereby it is essential to carry out studies focused on these issues in order to obtain reliable data in terms of both scientific and applied aims, e.g. environmental protection and sustainable management of soils as well as water resources. During the past decades, many of such studies of soil erosion had focused on the application of modelling techniques implemented in a GIS environment, allowing indirectly to estimate the potential soil losses and to quantify related sediment yield. According to research results published in the scientific literature, this approach currently is widely used all over the world, and most of these studies are based on the USLE model and its revised and modified versions. Considering that, the aim of this research was to estimate soil erosion rates and sediment transport under different hydro-climatic conditions in south-eastern Latvia by application of GIS-based modelling. For research purposes, empirical RUSLE model and ArcGIS software were applied, and five headwater catchments were chosen as model territories. The selected catchments with different land use are located in the Daugava spillway valley, which belongs to the upper Daugava River drainage basin. Considering lithological diversity of Quaternary deposits, a variety of soils can be identified, i.e., Stagnic Albeluvisols, Albic Rubic Arenosols and Albic Stagnic Podzols with stony loamy - clayey diamicton to coarse sand textures prevail in the selected catchments. The results of modelling were validated through obtaining data on suspended sediment load directly during episodic runoff events caused by different scenarios of runoff formation. In order to get comparable values of suspended sediment load from gully catchments that differ in size, an area-specific daily suspended sediment yield was derived. The obtained results indicate that modelled area-specific sediment yield from the catchments to river greatly varies from 0.001 to 97.2 t ha-1 yr-1; the average soil loss predicted by RUSLE for the each of five catchments calculated for a 1 × 1 m cell grid totals 0.81; 1.36; 0.96; 1.05 and 1.55 t ha-1 yr-1 respectively. Notably, despite the presence of forest vegetation that cover more than 40% of area of three of these catchments, sizable plots of soils are potentially prone to erosion rates above the tolerable threshold, i.e. 0.3 t ha-1 yr-1. Comparison of modelled vs. measured values indicates that the applied RUSLE model underestimates real sediment delivery, which shortly can reach values 213.75 kg ha-1 day-1 during intense snow melting in spring. Nevertheless, results of GIS modelling can be reasonably used to estimate the spatial distribution of soil erosion risk and to identify potential erosion hotspots.

  17. Integrated monitoring and assessment of soil restoration treatments in the Lake Tahoe Basin.

    PubMed

    Grismer, M E; Schnurrenberger, C; Arst, R; Hogan, M P

    2009-03-01

    Revegetation and soil restoration efforts, often associated with erosion control measures on disturbed soils, are rarely monitored or otherwise evaluated in terms of improved hydrologic, much less, ecologic function and longer term sustainability. As in many watersheds, sediment is a key parameter of concern in the Tahoe Basin, particularly fine sediments less than about ten microns. Numerous erosion control measures deployed in the Basin during the past several decades have under-performed, or simply failed after a few years and new soil restoration methods of erosion control are under investigation. We outline a comprehensive, integrated field-based evaluation and assessment of the hydrologic function associated with these soil restoration methods with the hypothesis that restoration of sustainable function will result in longer term erosion control benefits than that currently achieved with more commonly used surface treatment methods (e.g. straw/mulch covers and hydroseeding). The monitoring includes cover-point and ocular assessments of plant cover, species type and diversity; soil sampling for nutrient status; rainfall simulation measurement of infiltration and runoff rates; cone penetrometer measurements of soil compaction and thickness of mulch layer depths. Through multi-year hydrologic and vegetation monitoring at ten sites and 120 plots, we illustrate the results obtained from the integrated monitoring program and describe how it might guide future restoration efforts and monitoring assessments.

  18. The integrated project AquaTerra of the EU sixth framework lays foundations for better understanding of river-sediment-soil-groundwater systems.

    PubMed

    Gerzabek, M H; Barceló, D; Bellin, A; Rijnaarts, H H M; Slob, A; Darmendrail, D; Fowler, H J; Négrel, Ph; Frank, E; Grathwohl, P; Kuntz, D; Barth, J A C

    2007-07-01

    The integrated project "AquaTerra" with the full title "integrated modeling of the river-sediment-soil-groundwater system; advanced tools for the management of catchment areas and river basins in the context of global change" is among the first environmental projects within the sixth Framework Program of the European Union. Commencing in June 2004, it brought together a multidisciplinary team of 45 partner organizations from 12 EU countries, Romania, Switzerland, Serbia and Montenegro. AquaTerra is an ambitious project with the primary objective of laying the foundations for a better understanding of the behavior of environmental pollutants and their fluxes in the soil-sediment-water system with respect to climate and land use changes. The project performs research as well as modeling on river-sediment-soil-groundwater systems through quantification of deposition, sorption and turnover rates and the development of numerical models to reveal fluxes and trends in soil and sediment functioning. Scales ranging from the laboratory to river basins are addressed with the potential to provide improved river basin management, enhanced soil and groundwater monitoring as well as the early identification and forecasting of impacts on water quantity and quality. Study areas are the catchments of the Ebro, Meuse, Elbe and Danube Rivers and the Brévilles Spring. Here we outline the general structure of the project and the activities conducted within eleven existing sub-projects of AquaTerra.

  19. Development of a New Zealand SedNet model for assessment of catchment-wide soil-conservation works

    NASA Astrophysics Data System (ADS)

    Dymond, John R.; Herzig, Alexander; Basher, Les; Betts, Harley D.; Marden, Mike; Phillips, Chris J.; Ausseil, Anne-Gaelle E.; Palmer, David J.; Clark, Maree; Roygard, Jon

    2016-03-01

    Much hill country in New Zealand has been converted from indigenous forest to pastoral agriculture, resulting in increased soil erosion. Following a severe storm that hit the Manawatu-Wanaganui region in 2004 and caused 62,000 landslides, the Horizons Regional Council have implemented the Sustainable Land Use Initiative (SLUI), a programme of widespread soil conservation. We have developed a New Zealand version (SedNetNZ) of the Australian SedNet model to evaluate the impact of the SLUI programme in the 5850 km2 Manawatu catchment. SedNetNZ spatially distributes budgets of fine sediment in the landscape. It incorporates landslide, gully, earthflow erosion, surficial erosion, bank erosion, and flood-plain deposition, the important forms of soil erosion in New Zealand. Modelled suspended sediment loads compared well with measured suspended sediment loads with an R2 value of 0.85 after log transformation. A sensitivity analysis gave the uncertainty of estimated suspended sediment loads to be approximately plus or minus 50% (at the 95% confidence level). It is expected that by 2040, suspended sediment loads in targeted water management zones will decrease by about 40%. The expected decrease for the whole catchment is 34%. The expected reduction is due to maturity of tree planting on land at risk to soil erosion. The 34% reduction represents an annual rate of return of 20% on 20 million NZ of investment on soil conservation works through avoided damage to property and infrastructure and avoided clean-up costs.

  20. Sediment and solute transport in a mountainous watershed in Valle del Cauca, Colombia

    NASA Astrophysics Data System (ADS)

    Guzman, Christian; Hoyos Villada, Fanny; Morales Vargas, Amalia; Rivera, Baudelino; Da Silva, Mayesse; Moreno Padilla, Pedro; Steenhuis, Tammo

    2015-04-01

    Sediment samples and solute concentrations were measured from the La Vega micro watershed in the southwestern region of the Colombian Andes. A main goal of this study was to improve prediction of soil surface and soil nutrient changes, based on field measurements, within small basin of the Aguaclara watershed network receiving different types of conservation measures. Two modeling approaches for stream discharge and sediment transport predictions were used with one of these based on infiltration-excess and the other on saturation-excess runoff. These streams are a part of a recent initiative from a water fund established by Asobolo, Asocaña, and Cenicaña in collaboration with the Natural Capital Project to improve conservation efforts and monitor their effects. On-site soil depth changes, groundwater depth measurements, and soil nutrient concentrations were also monitored to provide more information about changes within this mountainous watershed during one part of the yearly rainy season. This information is being coupled closely with the outlet sediment concentration and solute concentration patterns to discern correlations between scales. Lateral transects in the upper, middle, and lower part of the hillsides in the La Vega micro watershed showed differences in soil nutrient status and soil surface depth changes. The model based on saturation-excess, semi-distributed hydrology was able to reproduce discharge and sediment transport rates as well as the initially used infiltration excess model indicating available options for comparison of conservation changes in the future.

  1. Downstream mixing of sediment and tracers in agricultural catchments: Evidence of changing sediment sources and fluvial processes?

    NASA Astrophysics Data System (ADS)

    Ralph, Timothy; Wethered, Adam; Smith, Hugh; Heijnis, Henk

    2014-05-01

    Land clearance, soil tillage and grazing in agricultural catchments have liberated sediment and altered hydrological connectivity between hillslopes and channels, leading to increased sediment availability, mobilisation and delivery to rivers. The type and amount of sediment supplied to rivers is critical for fluvial geomorphology and aquatic ecosystem health. Contemporary sediment dynamics are routinely investigated using environmental radionuclides such as caesium-137 (Cs-137) and excess lead-210 (Pb-210ex), which can provide information regarding sediment source types and fluvial processes if sediment sources can be distinguished from one another and mixing models applied to representative samples. However, downstream transport, mixing and dilution of radionuclide-labelled sediment (especially from sources with low initial concentrations) can obliterate the tracer signal; sometimes before anything of geomorphological importance happens in the catchment. Can these findings be used as evidence of sediment source variations and fluvial processes when the limits of detection (of Cs-137 in particular) are being exceeded so rapidly downstream? Sediment sources and downstream sediment dynamics were investigated in Coolbaggie Creek, a major supplier of sediment to the Macquarie River in an agricultural catchment with temperate to semi-arid climate in Australia. Radionuclides were used to discriminate between the <63 micron fraction of sediment sources including forested topsoils (Cs-137 11.28 +/- 0.75 Bq/kg; Pb-210ex 181.87 +/- 20.00 Bq/kg), agricultural topsoils (Cs-137 3.21 +/- 0.26 Bq/kg; Pb-210ex 29.59 +/- 10.94 Bq/kg) and sub-soils from channel banks and gullies (Cs-137 1.45 +/- 0.47 Bq/kg; Pb-210ex 4.67 +/- 1.93 Bq/kg). Within the trunk stream, suspended sediment, organic matter and Cs-137 and Pb-210ex concentrations declined downstream. Results from a mixing model suggest that agricultural topsoils account for 95% of fine sediment entering the channel in the upper reach (<10 km long), while sub-soils account for 90 to 100% of sediment entering and being transported in the remaining ~50 km of the system. This shift in dominant sediment source material coincided with a large increase in channel cross sectional area (~20 to >200 m2) downstream, with channel expansion and gullies contributing fine sediment to the system. A lack of topsoil being supplied to the channel suggests minimal lateral connectivity between the catchment and the trunk stream in all areas apart from the upper catchment. The enlargement and entrenchment of the channel downstream has also resulted in lateral disconnection between the channel and floodplain. In this case, a rapid reduction in radionuclide concentrations downstream does coincide with hydrogeomorphic changes, supporting their use for studying short-term sediment dynamics. These findings highlight the importance of understanding hydrogeomorphic processes and connectivity when interpreting sediment source and tracer data.

  2. PFAS methods and guidance for sampling and analyzing water and other environmental media (Technical Brief)

    EPA Pesticide Factsheets

    EPA's methods for analyzing PFAS in environmental media are in various stages of development. This fact sheet summarizes EPA's analytical methods development for groundwater, surface water, wastewater, and solids, including soils, sediments, and biosolids

  3. Preface

    Treesearch

    Robert R. Ziemer

    1998-01-01

    Abstract - These proceedings report on 36 years of research at the Caspar Creek Experimental Watershed, Jackson Demonstration State Forest in northwestern California. The 16 papers include discussions of streamflow, sediment production and routing, stream channel condition, soil moisture and subsurface water, nutrient cycling, aquatic and riparian habitat, streamside...

  4. Superfund Record of Decision (EPA Region 5): Midco I, Gary, IN. (First remedial action), (amendment), April 1992

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Not Available

    The 4-acre Midco I site is an abandoned, industrial waste recycling, storage, and disposal facility in Gary, Indiana. The surrounding land use is mixed industrial, commercial, and residential. The Calumet Aquifer underlies the site and provides drinking water to wells within 1 mile of the site. The primary contaminants are VOCs, including TCE, toluene, and xylenes; metals, including chromium and lead; and inorganics. The amended remedial action for the ROD includes a reduction in the amount of soil to be treated to a minimum of 5,200 cubic yards because of the amendment to soil CALs and the determination that arsenicmore » may not be present above background levels at the site; and treating the contaminated soil onsite using with soil vapor extraction, followed by in-situ solidification/stabilization; and excavating and treating contaminated sediment from the surrounding wetlands.« less

  5. Chapter 4. Predicting post-fire erosion and sedimentation risk on a landscape scale

    USGS Publications Warehouse

    MacDonald, L.H.; Sampson, R.; Brady, D.; Juarros, L.; Martin, Deborah

    2000-01-01

    Historic fire suppression efforts have increased the likelihood of large wildfires in much of the western U.S. Post-fire soil erosion and sedimentation risks are important concerns to resource managers. In this paper we develop and apply procedures to predict post-fire erosion and sedimentation risks on a pixel-, catchment-, and landscape-scale in central and western Colorado.Our model for predicting post-fire surface erosion risk is conceptually similar to the Revised Universal Soil Loss Equation (RUSLE). One key addition is the incorporation of a hydrophobicity risk index (HY-RISK) based on vegetation type, predicted fire severity, and soil texture. Post-fire surface erosion risk was assessed for each 90-m pixel by combining HYRISK, slope, soil erodibility, and a factor representing the likely increase in soil wetness due to removal of the vegetation. Sedimentation risk was a simple function of stream gradient. Composite surface erosion and sedimentation risk indices were calculated and compared across the 72 catchments in the study area.When evaluated on a catchment scale, two-thirds of the catchments had relatively little post-fire erosion risk. Steeper catchments with higher fuel loadings typically had the highest post-fire surface erosion risk. These were generally located along the major north-south mountain chains and, to a lesser extent, in west-central Colorado. Sedimentation risks were usually highest in the eastern part of the study area where a higher proportion of streams had lower gradients. While data to validate the predicted erosion and sedimentation risks are lacking, the results appear reasonable and are consistent with our limited field observations. The models and analytic procedures can be readily adapted to other locations and should provide useful tools for planning and management at both the catchment and landscape scale.

  6. Water and soil loss from landslide deposits as a function of gravel content in the Wenchuan earthquake area, China, revealed by artificial rainfall simulations.

    PubMed

    Gan, Fengling; He, Binghui; Wang, Tao

    2018-01-01

    A large number of landslides were triggered by the Mw7.9 Wenchuan earthquake which occurred on 12th May 2008. Landslides impacted extensive areas along the Mingjiang River and its tributaries. In the landslide deposits, soil and gravel fragments generally co-exist and their proportions may influence the hydrological and erosion processes on the steep slopes of the deposit surface. Understanding the effects of the mixtures of soil and gravels in landslide deposits on erosion processes is relevant for ecological reconstruction and water and soil conservation in Wenchuan earthquake area. Based on field surveys, indoor artificial rainfall simulation experiments with three rainfall intensities (1.0, 1.5 and 2.0 mm·min-1) and three proportions of gravel (50%, 66.7% and 80%) were conducted to measure how the proportion of gravel affected soil erosion and sediment yield in landslide sediments and deposits. Where the proportion of gravel was 80%, no surface runoff was produced during the 90 minute experiment under all rainfall intensities. For the 66.7% proportion, no runoff was generated at the lowest rainfall intensity (1.0 mm·min-1). As a result of these interactions, the average sediment yield ranked as 50> 66.6> 80% with different proportions of gravel. In addition, there was a positive correlation between runoff generation and sediment yield, and the sediment yield lagging the runoff generation. Together, the results demonstrate an important role of gravel in moderating the mobilization of landslide sediment produced by large earthquakes, and could lay the foundation for erosion models which provide scientific guidance for the control of landslide sediment in the Wenchuan earthquake zone, China.

  7. Quantifying Sediment Transport in a Premontane Transitional Cloud Forest

    NASA Astrophysics Data System (ADS)

    Waring, E. R.; Brumbelow, J. K.

    2013-12-01

    Quantifying sediment transport is a difficult task in any watershed, and relatively little direct measurement has occurred in tropical, mountainous watersheds. The Howler Monkey Watershed (2.2 hectares) is located in a premontane transitional cloud forest in San Isidro de Peñas Blancas, Costa Rica. In June 2012, a V-notch stream-gaging weir was built in the catchment with a 8 ft by 6 ft by 4 ft concrete stilling basin. Sediment captured by the weir was left untouched for an 11 month time period. To collect the contents of the weir, the stream was rerouted and the weir was drained. The stilling basin contents were systematically sampled, and samples were taken to a lab and characterized using sieve and hydrometer tests. The wet volume of the remaining sediment was obtained, and dry mass was estimated. Particle size distribution of samples were obtained from lab tests, with 96% of sediment trapped by the weir being sand or coarser. The efficiency of the weir as a sediment collector was evaluated by comparing particle fall velocities to residence time of water in the weir under baseflow conditions. Under these assumptions, only two to three percent of the total mass of soil transported in the stream is thought to have been suspended in the water and lost over the V-notch. Data were compared to the Universal Soil Loss Equation (USLE), a widely accepted method for predicting soil loss in agricultural watersheds. As expected, application of the USLE to a tropical rainforest was problematic with uncertainty in parameters yielding a soil loss estimate varying by a factor of 50. Continued monitoring of sediment transport should yield data for improved methods of soil loss estimation applicable to tropical mountainous forests.

  8. Water and soil loss from landslide deposits as a function of gravel content in the Wenchuan earthquake area, China, revealed by artificial rainfall simulations

    PubMed Central

    Gan, Fengling; Wang, Tao

    2018-01-01

    A large number of landslides were triggered by the Mw7.9 Wenchuan earthquake which occurred on 12th May 2008. Landslides impacted extensive areas along the Mingjiang River and its tributaries. In the landslide deposits, soil and gravel fragments generally co-exist and their proportions may influence the hydrological and erosion processes on the steep slopes of the deposit surface. Understanding the effects of the mixtures of soil and gravels in landslide deposits on erosion processes is relevant for ecological reconstruction and water and soil conservation in Wenchuan earthquake area. Based on field surveys, indoor artificial rainfall simulation experiments with three rainfall intensities (1.0, 1.5 and 2.0 mm·min-1) and three proportions of gravel (50%, 66.7% and 80%) were conducted to measure how the proportion of gravel affected soil erosion and sediment yield in landslide sediments and deposits. Where the proportion of gravel was 80%, no surface runoff was produced during the 90 minute experiment under all rainfall intensities. For the 66.7% proportion, no runoff was generated at the lowest rainfall intensity (1.0 mm·min-1). As a result of these interactions, the average sediment yield ranked as 50> 66.6> 80% with different proportions of gravel. In addition, there was a positive correlation between runoff generation and sediment yield, and the sediment yield lagging the runoff generation. Together, the results demonstrate an important role of gravel in moderating the mobilization of landslide sediment produced by large earthquakes, and could lay the foundation for erosion models which provide scientific guidance for the control of landslide sediment in the Wenchuan earthquake zone, China. PMID:29723279

  9. ENGINEERING ISSUE: TECHNOLOGY ALTERNATIVES FOR THE REMEDIATION OF PCB-CONTAMINATED SOIL AND SEDIMENT

    EPA Science Inventory

    Because of the increased need for Superfund decision-makers to have a working knowledge of the remedial capabilities available to treat soil and sediment contaminated with polychlorinated biphenyls (PCBs), the Superfund Engineering Forum has identified remediation of PCB-contamin...

  10. Impacts of climate and land use change on reservoir sedimentation

    USDA-ARS?s Scientific Manuscript database

    Impacts of evolving climate and implementation of upstream soil conservation measures on sedimentation of the Fort Cobb Reservoir in West-Central Oklahoma are investigated. Conservation practices before the 1950s were few. Between 1950 and 2008, extensive soil conservation measures were implemented...

  11. THE INFLUENCE OF MINERAL REACTIONS ON THE ENVIRONMENTAL FATE OF METALS IN SOILS AND SEDIMENTS

    EPA Science Inventory

    Significant progress has been made in elucidating sorption reactions that control the partitioning of metals from solution to mineral surfaces in contaminated soil/sediment systems. Surface complexation models have been developed to quantify the forward reaction, however, these ...

  12. Elements patterns of soil and river sediments as a tracer of sediment migration

    NASA Astrophysics Data System (ADS)

    Dordevic, Dragana; Pétursdóttir, Þórunn; Halldórsson, Guðmundur; Sakan, Sanja; Škrivalj, Sandra; Finger, David Christian

    2017-04-01

    Iceland is the small island on the mid Atlantic ridge, with strong natural catastrophes, such as floods, droughts, landslides, storms and volcanic eruptions that can have devastating impacts on natural and build environment. Rangárvellir area next to Mt Hekla and the glacier Tindfjallajökul has impacted by severe erosion processes but also rich of surface water that play a crucial role in sediment transport processes in the watersheds of the two rivers Eystri-Rangá and Ytri-Rangá. Their sediments consist of various materials originating from volcanoes ash and lava. Difference of contents of various chemical components in sediments and surrounding soil could be bases for identification of erosion processes and watersheds connectivity. River sediment is accumulator of chemical constituents from water in water-sediment interaction, making it as an important material for investigation their migration routes. In order to develop of methods for investigating of sediment migration using their chemical patterns the STSM of Connecteur COST Action ES1306-34336 have been approved. Samples of river sediments and surrounding soils of the Eystri-Rangá and Ytri-Rangá rivers in watersheds of Rangárvellir area as well as primarily volcanic ash from Eyafjallajökull were taken. Sequential extraction of heavy metals and trace elements from collected samples has been applied using the optimized procedure proposed by European Community Bureau of reference (BCR) in the next fractions: 1) soluble in acid - metals that are exchangeable or associated with carbonates; 2) reducible fraction - metals associated with oxides of Fe and Mn; 3) oxidizable fraction - metals associated with organic matter and sulfides and 4) residual fraction - metals strongly associated with the crystalline structure of minerals. Extracted solutions have analyzed by ICP/OES on next elements: Al, As, B, Ba, Be, Bi, Ca, Cd, Co, Cr, Cu, Fe, Hg, K, Li, Mg, Mn, Na, Ni, P, Pb, S, Sb, Si, Sr, V, Zn. Distributions of Si is the same in all investigated samples of soils, river sediments and volcanic ash pointing to the same their geochemical basis. Some elements like Li and partly B exist in the first phase of volcanic ash and river sediments but no in the first phases of soils as if they were already washed from them and adsorbed on the river sediments surfaces. In the first phase of volcanic ash P was found but no exists in the first phase of soil and river sediments. Total content of Bi is found only in silicate matrix while total contents of As is found only in organic/sulphide form in all investigated samples.

  13. [Physicochemical properties of Guanting Reservoir sediment and its land application].

    PubMed

    Su, De-Chun; Hu, Yu-Feng; Song, Chong-Wei; Wu, Fei-Long; Liu, Pei-Bin

    2007-06-01

    Surface sediment of Guanting Reservoir was dredged up and dewatered in field, and pollutant and physicochemical characterizations were mensurated. The stabilization and agricultural land use of the sediment was also studied in the field. Results showed that the sediments have a higher clay content, bulk density (1.89 g x cm(-3)) and lower porosity (23.8%), higher deoxidize material and available nitrogen, phosphorus concentration. Heavy metal and organochlorinated pesticides concentration was lower than the class II of national standard for soil. Stabilized the sediment with sand soil and straw could improve the physical property and decrease the concentration of deoxidize material and available nitrogen, phosphorus. Stabilized sediment could be a suitable medium for alfalfa, tree and corn growth and used for agricultural land.

  14. Erodibility of selected soils and estimates of sediment yields in the San Juan Basin, New Mexico

    USGS Publications Warehouse

    Summer, Rebecca M.

    1981-01-01

    Onsite rainfall-simulation experiments were conducted to derive field-erodibility indexes for rangeland soils and soils disturbed by mining in coal fields of northwestern New Mexico. Mean indexes on rangeland soils range from 0 grams (of detached soil) on dune soil to 121 grams on wash-transport zones. Mean field-erodibility-index values of soils disturbed by mining range from 16 to 32 grams; they can be extrapolted to nearby coal fields where future mining is expected. Because field-erodibility-index data allow differentiation of erodibilities across a variable landscape, these indexes were used to adjust values of K, the erodibility factor of the Universal Soil Loss Equation. Estimates of soil loss and sediment yield were then calculated for a small basin following mining. (USGS)

  15. Pre-aged plant waxes in tropical lake sediments and their influence on the chronology of molecular paleoclimate proxy records

    NASA Astrophysics Data System (ADS)

    Douglas, Peter M. J.; Pagani, Mark; Eglinton, Timothy I.; Brenner, Mark; Hodell, David A.; Curtis, Jason H.; Ma, Keith F.; Breckenridge, Andy

    2014-09-01

    Sedimentary records of plant-wax hydrogen (δDwax) and carbon (δ13Cwax) stable isotopes are increasingly applied to infer past climate change. Compound-specific radiocarbon analyses, however, indicate that long time lags can occur between the synthesis of plant waxes and their subsequent deposition in marginal marine sediments. The influence of these time lags on interpretations of plant-wax stable isotope records is presently unconstrained, and it is unclear whether such time lags also affect lacustrine sediments. We present compound-specific radiocarbon (14Cwax) data for n-alkanoic acid plant waxes (n-C26 to n-C32) from: (1) a sediment core from Lake Chichancanab, Yucatan Peninsula, Mexico, (2) soils in the Lake Chichancanab catchment, and (3) surface sediments from three other lakes in southeastern Mexico and northern Guatemala. 14Cwax ages in the surface sediments are consistently older than modern, and may be negatively correlated with mean annual precipitation and positively correlated with lake catchment area. 14Cwax ages in soils surrounding Lake Chichancanab increase with soil depth, consistent with deep, subsoil horizons being the primary source of lacustrine aged plant waxes, which are likely delivered to lake sediments through subsurface transport. Plant waxes in the Lake Chichancanab core are 350-1200 years older than corresponding ages of bulk sediment deposition, determined by 14C dates on terrestrial plant macrofossils in the core. A δDwax time series is in closer agreement with other regional proxy hydroclimate records when a plant-wax 14C age model is applied, as opposed to the macrofossil-based core chronology. Inverse modeling of plant-wax age distribution parameters suggests that plant waxes in the Lake Chichancanab sediment core derive predominantly from millennial-age soil carbon pools that exhibit relatively little age variance (<200 years). Our findings demonstrate that high-temporal-resolution climate records inferred from stable isotope measures on plant waxes in lacustrine sediments may suffer from possible chronologic distortions as a consequence of long residence times of plant waxes in soils. They also underscore the importance of direct radiocarbon dating of these organic molecules.

  16. Copper and cadmium in bottom sediments dredged from Wyścigi Pond, Warsaw, Poland--contamination and bioaccumulation study.

    PubMed

    Wojtkowska, Małgorzata; Karwowska, Ewa; Chmielewska, Iwona; Bekenova, Kundyz; Wanot, Ewa

    2015-12-01

    This research covered an evaluation of the copper and cadmium concentrations in bottom sediments dredged from one of the ponds in Warsaw. The samples of sediments, soil, and plants were analyzed in terms of Cu and Cd content. The research concerned the heap of dredged bottom sediments from Wyścigi Pond, Warsaw, Poland. Two boreholes were made to obtain sediment cores with depths of A 162.5 cm and B 190.0 cm. The cores were divided into 10 sub-samples with a thickness of about 15-20 cm. A control sample of soil was taken from the horse racecourse several hundred meters away from the heap. The vegetation was sampled directly from the heap. The predominating plants were tested: Urtica dioica, Glechoma hederacea, Euonymus verrucosus, and Drepanocladus aduncus. A control sample of U. dioica taken outside of the heap was also tested. The commercial PHYTOTOXKIT microbiotest was applied to evaluate the influence of heavy metal-contaminated sediments (used as soil) on germination and growth of the chosen test plants. The analyses of cadmium and copper concentrations revealed that the metal concentration in sediments was diverse at different depths of sampling, probably reflecting their concentration in stored layers of sediments. Moreover, the metal content in core A was four to five times lower than that in core B, which reveals heterogeneity of the sediments in the tested heap. In core A, the copper concentration ranged from 4.7 to 13.4 mg/kg d.w. (average 8.06 ± 0.71 mg/kg d.w.), while in core B, it ranged from 9.2 to 82.1 mg/kg d.w. (average 38.56 ± 2.6 mg/kg d.w.). One of the results of the heavy metal presence in soils is their bioaccumulation in plants. Comparing plant growth, more intensive growth of roots was observed in the case of plants growing on the control (reference) soil than those growing on sediments. The intensive development of both primary and lateral roots was noticed. During this early growth, metal accumulation in plants occurred.

  17. Preliminary use of compound-specific stable isotope (CSSI) technique to identify and apportion sediment origin in a small Austrian catchment

    NASA Astrophysics Data System (ADS)

    Mabit, Lionel; Gibbs, Max; Chen, Xu; Meusburger, Katrin; Toloza, Arsenio; Resch, Christian; Klik, Andreas; Eder, Alexander; Strauss, Peter; Alewell, Christine

    2015-04-01

    The overall impacts of climate change on agriculture are expected to be negative, threatening global food security. In the agricultural areas of the European Union, water erosion risk is expected to increase by about 80% by the year 2050. Reducing soil erosion and sedimentation-related environmental problems represent a key requirement for mitigating the impact of climate change. A new forensic stable isotope technique, using the compound specific stable isotope (CSSI) signatures of inherent soil organic biomarkers, can discriminate and apportion the source soil contribution from different land uses. Plant communities label the soil where they grow by exuding organic biomarkers. Although all plants produce the same biomarkers, the stable isotopic signature of those biomarkers is different for each plant species. For agri-environmental investigation, the CSSI technique is based on the measurement of carbon-13 (13-C) natural abundance signatures of specific organic compounds such as natural fatty acids (FAs) in the soil. By linking fingerprints of land use to the sediment in deposition zones, this approach has been shown to be a useful technique for determining the source of eroded soil and thereby identifying areas prone to soil degradation. The authors have tested this innovative stable isotopic approach in a small Austrian agricultural catchment located 60 km north of Vienna. A previous fallout radionuclide (i.e. 137-Cs) based investigation established a sedimentation rate of 4 mm/yr in the lowest part of the study site. To gain knowledge about the origin of these sediments, the CSSI technique was then tested using representative samples from the different land-uses of the catchment as source material. Values of 13-C signatures of specific FAs (i.e. C22:0 = Behenic Acid ; C24:0 = Lignoceric Acid) and the bulk 13-C of the sediment mixture and potential landscape sources were analyzed with the mixing models IsoSource and CSSIAR v1.00. Using both mixing models, preliminary results highlighted that about 50-55% of the sediment located in the deposition area originated from the main grassed waterway of the catchment.

  18. Microbial diversity on sedimentated rice fields due to coal mining activities in Tenggarong Seberang subdistrict of Kutai Kartanegara

    NASA Astrophysics Data System (ADS)

    Rosfiansyah; Sopialena

    2018-04-01

    The results showed that on upland rice fields with sediment found five genus of fungus with number of colonies 4.0 x 103 cfu/g to 9.3 x 104 cfu/g; three bacterial families with number of colonies 7,1 x 104 cfu/g to 2,8 x 105 cfu/g; and five genera of nematodes with the amount of 2.6 x 102/kg of soil to 1.1 x103/kg of soil. In unpolished upland rice fields were found four genus of fungus with colonies of 2.4 x 103 cfu/g to 8.4 x 104 cfu/g, three bacterial families with number of colonies 1.2 x 105 cfu/g to 2.7 x 105 cfu/g and four genera of nematodes with the amount of 9.6 x 102/kg of soil to 1.1 x103/kg of soil. The most common microbes are Aspergillus, Cladosporium, Penicillium, Phytium and Trichoderma (fungi), Achromobacteraceae, Brevibacteriaceae, Micrococcaceae (Bacteria), as well as Dorylaimus, Hemicycliophora, Mononchus, Meloidogyne, Paratrichodorus, Radopholus, Rotylenchulus, Rhabditis, Seinura and Trichodorus (Nematodes). Fungi, bacteria and nematodes have a good role in the process of soil decomposition. The results of soil chemical analysis showed that soil fertility is lower in upland rice fields with sediments compare to those without sediment.

  19. Overland flow generation mechanisms affected by topsoil treatment: Application to soil conservation

    NASA Astrophysics Data System (ADS)

    González Paloma, Hueso; Juan Francisco, Martinez-Murillo; Damian, Ruiz-Sinoga Jose; Hanoch, Lavee

    2015-04-01

    Hortonian overland-flow is responsible for significant amounts of soil loss in Mediterranean geomorphological systems. Restoring the native vegetation is the most effective way to control runoff and sediment yield. During the seeding and plant establishment, vegetation cover may be better sustained if soil is amended with an external source. Four amendments were applied in an experimental set of plots: straw mulching (SM); mulch with chipped branches of Aleppo Pine (Pinus halepensis L.) (PM); TerraCotten hydroabsobent polymers (HP); sewage sludge (RU); and control (C). Plots were afforested following the same spatial pattern, and amendments were mixed with the soil at the rate 10 Mg ha-1. This research demonstrates the role played by the treatments in overland flow generation mechanism (runoff, overland flow and soil moisture along the soil profile). The general overland flow characteristics showed that in the C plots the average overland flow was 8.0 ± 22.0 l per event, and the HP plots produced a similar mean value (8.1 ± 20.1 l). The average overland flow per event was significantly less for soil amended with SM, PM or RU (2.7 ± 8.3 l; 1.3 ± 3.5 l and 2.2 ± 5.9 l, respectively). There was a similar trend with respect to the maximum overland flow. The mean sediment yield per event was relatively high in the C and HP plots (8.6 ± 27.8 kg and 14.8 ± 43.4 kg, respectively), while significantly lower values were registered in the SM, PM and RU plots (0.4 ± 1.0 kg; 0.2 ± 0.3 kg and 0.2 ± 0.3 kg, respectively). Very similar trends were found for the maximum sediment yield. Regarding to the soil moisture values, there was a difference in the trends between the C and HP plots and the SM, PM and RU plots. In the C and HP plots the general trend was for a decrease in soil moisture downward through the soil profile, while in the SM, PM and RU plots the soil moisture remained relatively constant or increased, except for the RU treatment in which the soil moisture decreased from 5 to 10 cm depth. According to the results, the hydrological and erosive response in the five treatments showed dissimilarities, despite having similar rainfall exposure and the same original soil properties. This means that the differences between the treatments play a key role in the soil moisture, overland flow and sediment yield values. The study has demonstrated the effects of various treatments on the generation of overland flow, and hence the sediment yield. In the C and HP plots, relatively large amounts of overland flow rapidly developed. This cannot be explained by saturation conditions, as the soil moisture content was highest near the surface and decreased with depth in the profile. This, together with the relatively low macro-porosity, proved that the mechanism of overland flow generation was of the Hortonian type. On the other hand, in the SM and PM plots, the high level of macro-porosity, together with the increase in soil moisture content with depth, explained the small quantities of overland flow and sediment yield. In the rare case that overland flow developed in these plots, it was minor in amount, and yielded little sediment because of saturation conditions. The processes in the RU plots were more complicated; from 10 cm depth the soil moisture content always increased with further depth, usually rapidly. Thus, water infiltrated continuously and there was no rainfall excess. Therefore, in terms of overland flow and sediment yield, the RU plots behaved in a similar way to the SM and PM plots. The fact that the soil moisture content was low at depths of 10 cm is because of the uptake of water at these depths by the roots of Carlina hispanica Lam. From a land management standpoint, the SM, PM and RU treatments were the most effective in reducing overland flow and sediment yield following afforestation. In addition, the soil profile became more wettable, which provided more water to support plant survival. However, when afforestation was combined with RU treatment, the vegetation cover resulting from the amendment treatment was the main factor controlling the hydrological processes. Application of the HP treatment caused a decrease in soil moisture content with depth in the soil profile, and overland flow and sediment yield were maximum in this treatment.

  20. Risk assessment of watershed erosion at Naesung Stream, South Korea.

    PubMed

    Ji, Un; Velleux, Mark; Julien, Pierre Y; Hwang, Manha

    2014-04-01

    A three-tiered approach was used to assess erosion risks within the Nakdong River Basin in South Korea and included: (1) a screening based on topography and land use; (2) a lumped parameter analysis using RUSLE; and (3) a detailed analysis using TREX, a fully distributed watershed model. These tiers span a range of spatial and temporal scales, with each tier providing increasing detail and resolution. The first two tiers were applied to the entire Nakdong River Basin and the Naesung Stream watershed was identified as having the highest soil erosion risk and potential for sedimentation problems. For the third tier, the TREX watershed model simulated runoff, channel flow, soil erosion, and stream sediment transport in the Naesung Stream watershed at very high resolution. TREX was calibrated for surface flows and sediment transport, and was used to simulate conditions for a large design storm. Highly erosive areas were identified along ridgelines in several headwater areas, with the northeast area of Songriwon having a particularly high erosion potential. Design storm simulations also indicated that sediment deposition of up to 55 cm could occur. Copyright © 2014 Elsevier Ltd. All rights reserved.

  1. Sediment Sources Change for the Past 42 Years in a Small Watershed Located in the Black Soil Region of Northeastern China Based on Fingerprinting Method

    NASA Astrophysics Data System (ADS)

    Du, P.; Huang, D.; Ning, D.

    2017-12-01

    The temporal change of sediment source in watershed is very helpful for evaluating the adopted soil conservation measures and the implemented land management practices. For this purpose, a sediment profile from Hebei watershed outlet and 59 samples from the three potential sediment sources were collected. The rediounuclide Pb-210 was then measured to obtain sedimentation rate for the past 42 years. Generally, the sedimentation rate was gradually decreased from 10.83 cm yr-1 in the 1970's to 1.50 cm yr-1in the 2010's. Taken the radiounulide Cs-137 as a fingerprinting identifying tracer, the mean contribution of sediment from cultivated lands, woodlands, and channel banks were 50.60%, 22.26%, and 26.74%, while the ranges varying from 20.16% to 84.02%, from 2.22% to 36.85%, and from 11.61% to 53.28%, respectively. The percentage of sediment sources from cultivated lands was decreased, whereas the percentages from woodlands and channel banks were both increased in the past 42 years. The results indicate that soil conservation measures adopted in the cultivated lands have been played a very important role in reducing erosion, however, more attention on land management practices implementation should be paid to maintain current woodland and to control serious gully erosion in the black soil region. (This paper is a contribution to the project of National Natural Science Foundation of China (No. 41501299), and the non-profit project of Ministry of Water Resources of China (No. 201501045).)

  2. A field method for measurement of infiltration

    USGS Publications Warehouse

    Johnson, A.I.

    1963-01-01

    The determination of infiltration--the downward entry of water into a soil (or sediment)--is receiving increasing attention in hydrologic studies because of the need for more quantitative data on all phases of the hydrologic cycle. A measure of infiltration, the infiltration rate, is usually determined in the field by flooding basins or furrows, sprinkling, or measuring water entry from cylinders (infiltrometer rings). Rates determined by ponding in large areas are considered most reliable, but the high cost usually dictates that infiltrometer rings, preferably 2 feet in diameter or larger, be used. The hydrology of subsurface materials is critical in the study of infiltration. The zone controlling the rate of infiltration is usually the least permeable zone. Many other factors affect infiltration rate--the sediment (soil) structure, the condition of the sediment surface, the distribution of soil moisture or soil- moisture tension, the chemical and physical nature of the sediments, the head of applied water, the depth to ground water, the chemical quality and the turbidity of the applied water, the temperature of the water and the sediments, the percentage of entrapped air in the sediments, the atmospheric pressure, the length of time of application of water, the biological activity in the sediments, and the type of equipment or method used. It is concluded that specific values of the infiltration rate for a particular type of sediment are probably nonexistent and that measured rates are primarily for comparative use. A standard field-test method for determining infiltration rates by means of single- or double-ring infiltrometers is described and the construction, installation, and operation of the infiltrometers are discussed in detail.

  3. Selenium volatilization in vegetated agricultural drainage sediment from the San Luis Drain, Central California.

    PubMed

    Bañuelos, G S; Lin, Z-Q; Arroyo, I; Terry, N

    2005-09-01

    The presence of large amounts of Se-laden agricultural drainage sediment in the San Luis Drain, Central California, poses a serious toxic threat to wildlife in the surrounding environment. Effective management of the drainage sediment becomes a practical challenge because the sediment is polluted with high levels of Se, B, and salts. This two-year field study was conducted to identify the best plant species that are salt and B tolerant and that have a superior ability of volatilizing Se from drainage sediment. The drainage sediment was mixed with clean soil, and vegetated with salado alfalfa (Medicago sativa 'salado'), salado grass (Sporobulus airoides 'salado'), saltgrass-turf (Distichlis spp. 'NYPA Turf'), saltgrass-forage (Distichlis spicata (L.) Greene), cordgrass (Spartina patens 'Flageo'), Leucaenia (Leucaena leucocephola), elephant grass (Pennistum purpureum), or wild type-Brassica (Brassica spp.). Results show that elephant grass produced the greatest amount of biomass and accumulated highest concentrations of B. Highest concentrations of Se, S, and Cl were observed in wild-type Brassica. Biogenic volatilization of Se by plants and soil microbes was greater in summer. Among the treatments, the mean daily rates of Se volatilization (microg Se m(-2)d(-1)) were wild-type Brassica (39) > saltgrass-turf (31) > cordgrass (27) > saltgrass forage (24) > elephant grass (22) > salado grass (21) > leucaenia (19) > salado alfalfa (14) > irrigated bare soil (11) > non-irrigated bare soil (6). Overall, rates of Se volatilization in drainage sediment were relatively low due to high levels of sulfate. To manage Se in drainage sediment by phytoremediation, the biological volatilization process needs to be enhanced substantially under field conditions.

  4. Effects of post-fire salvage logging and a skid trail treatment on ground cover, soils, and sediment production in the interior western United States

    Treesearch

    Joseph W. Wagenbrenner; Lee H. MacDonald; Robert N. Coats; Peter R. Robichaud; Robert E. Brown

    2015-01-01

    Post-fire salvage logging adds another set of environmental effects to recently burned areas, and previous studies have reported varying impacts on vegetation, soil disturbance, and sediment production with limited data on the underlying processes. Our objectives were to determine how: (1) ground-based post-fire logging affects surface cover, soil water repellency,...

  5. U.S. Geological Survey programs and investigations related to soil and water conservation

    USGS Publications Warehouse

    Osterkamp, W.R.; Gray, J.R.

    2001-01-01

    The U.S. Geological Survey has a rich tradition of collecting hydrologic data, especially for fluxes of water and suspended sediment, that provide a foundation for studies of soil and water conservation. Applied and basic research has included investigations of the effects of land use on rangelands, croplands, and forests; hazards mapping; derivation of flood and drought frequency, and other statistics related to streamflow and reservoir storage; development and application of models of rainfall-runoff relations, chemical quality, and sediment movement; and studies of the interactive processes of overland and channel flow with vegetation. Networks of streamgaging stations and (or) sampling sites within numerous drainage basins are yielding information that extends databases and enhances the ability to use those data for interpretive studies.

  6. The evolution of concepts for soil erosion modelling

    NASA Astrophysics Data System (ADS)

    Kirkby, Mike

    2013-04-01

    From the earliest models for soil erosion, based on power laws relating sediment discharge or yield to slope length and gradient, the development of the Universal Soil Loss Equation was a natural step, although one that has long continued to hinder the development of better perceptual models for erosion processes. Key stumbling blocks have been: 1. The failure to go through runoff generation as a key intermediary 2. The failure to separate hydrological and strength parameters of the soil 3. The failure to treat sediment transport along a slope as a routing problem 4. The failure to analyse the nature of the dependence on vegetation Key advances have been in these directions (among others) 1. Improved understanding of the hydrological processes (e.g. infiltration and runoff, sediment entrainment) leading to KINEROS, LISEM,WEPP, PESERA 2. Recognition of selective sediment transport (e.g. transport- or supply-limited removal, grain travel distances) leading e.g. to MAHLERAN 3. Development of models adapted to particular time/space scales Some major remaining problems 1. Failure to integrate geomorphological and agronomic approaches 2. Tillage erosion - Is erosion loss of sediment or lowering of centre of mass? 3. Dynamic change during an event, as rills etc form.

  7. Effect of well construction on the mechanical state of unconsolidated methane hydrate-bearing sediment

    NASA Astrophysics Data System (ADS)

    Sasaki, T.; Soga, K.; Yamamoto, K.

    2016-12-01

    World's first offshore production of gas from methane hydrate-bearing sediment was accomplished in Nankai Trough off the coast of Japan. The achievement signals the beginning of exploitation of methane hydrate as a new source of energy, as an estimated amount of the new gas resource significantly exceeds that of the existing conventional oil and gas resources. Conventional gas reservoirs exist in consolidated sediment (i.e. rocks) thousands of metres below seafloor, and such sediment is hard enough to resist deformation. Methane hydrate reservoirs, on the other hand, lies only a couple of hundreds of metres down the seafloor, which means the sediment is unconsolidated (i.e. soils) and is readily deformed. In addition, the hydrate melts away in the pore space when it releases gas, giving rise to a significant rearrangement of stresses in the sediment. Well construction in methane hydrate reservoir might affect the mechanical state of the sediment to the point where the interpretation of the fracture pressure test becomes difficult and sand production could be enhanced. Existing numerical simulations tend to overlook soil mechanics, which is more appropriate than rock mechanics to model unconsolidated sediment, and the effect of methane hydrate on soil's mechanical behaviour is missed. In the present research, the construction of well in unconsolidated hydrate-bearing sediment was modelled with finite element analysis incorporating the critical state soil mechanics. Results showed that cement shrinkage in the well annulus would have a significant effect on the principal stresses and directions of the sediment even if the magnitude of the shrinkage was 0.1%. Cement shrinkage would also promote the generation of plastic strains, potentially enhancing sand production. Results also showed that the direction of fracture inferred from a fracture pressure test at Nankai Trough might have been vertical, indicating it was developed at the cement-sediment interface.

  8. The impact of military activities on the concentration of mercury in soils of military training grounds and marine sediments.

    PubMed

    Gębka, Karolina; Bełdowski, Jacek; Bełdowska, Magdalena

    2016-11-01

    Military activities have been conducted on land and at sea. Both during conflicts and in peace time, some regions served as a military training ground which included firing positions and bunkers. Mercury fulminate has been used in ammunition primers and detonators. Certain amount of ammunition was dumped into the Baltic Sea after the Second World War. Because of corroded containers, mercury can be released into the marine environment. The soil and sediment samples were taken from military training grounds, southern Baltic in 2014 and 2015. The concentration of mercury was determined by AMA-254 analyzer. Hg concentration was higher in the places of military activities, as compared to other areas. Ten times increased concentration of Hg was determined in soil sample collected in area of active gun range compared to the reference station. The significant higher concentration of mercury was detected in stations where chemical warfare agents were found.

  9. Permafrost Mobilization from the Watershed to the Colville River Delta: Evidence from Biomarkers and 14C Ramped Pyrolysis

    NASA Astrophysics Data System (ADS)

    Zhang, X.; Bianchi, T. S.; Cui, X.; Rosenheim, B. E.; Ping, C. L.; Kanevskiy, M. Z.; Hanna, A. M.; Allison, M. A.

    2016-12-01

    As temperatures in the Arctic rise abnormally fast, permafrost in the region is vulnerable to extensive thawing. This could release previously frozen organic carbon (OC) into the contemporary carbon cycle, giving a positive feedback on global warming. Recent research has found the presence of particulate permafrost in rivers, deltas, and continental shelves in the Arctic, but little direct evidence exists on the mechanism of transportation of previously frozen soils from watershed to the coast. The Colville River in northern Alaska is the largest North American Arctic River with a continuous permafrost within its watershed. Previous work has found evidence for the deposition of previously frozen soils in the Colville River delta (Schreiner et al., 2014). Here, we compared the bulk organic carbon thermal properties, ages of soils and river and delta sediments from the Colville River drainage system using 14C Ramped Pyrolysis and chemical biomarkers. Our data show that deep permafrost soils as well as river and delta sediments had similar pyrograms and biomarker signatures, reflecting transport of soils from watershed to the delta. Surface soil had pyrograms indicative of less stable (more biodegradable) OC than deeper soil horizons. Similarity in pyrograms of deep soils and river sediment indicated the limited contribution of surface soils to riverine particulate OC inputs. Sediments in the delta showed inputs of yedoma (ice-rich syngenetic permafrost with large ice wedges) from the watershed sources (e.g., river bank erosion) in addition to peat inputs, that were largely from coastal erosion.

  10. Soil surface lowering due to soil erosion in villages near Lake Victoria, Uganda

    NASA Astrophysics Data System (ADS)

    de Meyer, A.; Deckers, J.; Poesen, J.; Isabirye, M.

    2009-04-01

    In the effort to pinpoint the sources of sediment pollution in Lake Victoria, the contribution of sedi-ment from compounds, landing sites, main roads and footpaths is determined in the catchment of Na-bera Bay and Kafunda Bay at the northern shore of Lake Victoria in southern Uganda. The amount of soil loss in compounds and landing sites is determined by the reconstruction of the original and current soil surface according to botanical and man-made datable objects. The soil erosion rate is then deter-mined by dividing the eroded soil volume (corrected for compaction) by the age of the oldest datable object. In the study area, the average soil erosion rate in compounds amounts to 107 Mg ha-1 year-1 (per unit compound) and in landing sites to 207 Mg ha-1 year-1 (per unit landing site). Although com-pounds and landing sites occupy a small area of the study area (1.1 %), they are a major source of sediment to Lake Victoria (63 %). The soil loss on footpaths and main roads is calculated by multip-lying the total length of footpaths and main roads with the average width and depth (measured towards a reference surface). After the correction for compaction is carried out, the soil erosion rate on foot-paths amounts to 34 Mg ha-1 year-1 and on main roads to 35 Mg ha-1 year-1. Also footpaths and main roads occupy a small area of the study area (1.1 %), but contribute disproportionately to the total soil loss in the catchment (22 %). In this research, the information about the village/compound given by the villager/owner is indispensable. In accordance to an adaptation of the model of McHugh et al. (2002), 32 % of the sediment that is generated in the catchment, is deposited in Lake Victoria (i.e. 2 209 Mg year-1 or 0.7 Mg ha-1 year-1). The main buffer in the study area is papyrus at the shore of Lake Victoria. Also sugarcane can be a major buffer. However, the sugarcane-area is intersected by com-pounds, landing sites, footpaths and main roads that generate large amounts of sediment and function as main bypass mechanisms (high CR) facilitating and enhancing sediment delivery to Lake Victoria.

  11. Data Gap Analysis and Database Expansion of Parameters for Munitions Constitutents

    DTIC Science & Technology

    2005-12-01

    BIOWIN documentation (Boethling et al. 1994). Sediment is briefly considered to be anaerobic soil, with overall conversion factors, and water is aerobic...degradation of a chemical in water, soil, and sediment is determined using the ultimate biodegradation expert survey module of the BIOWIN estimation

  12. Determination of Polychlorinated Biphenyls in Soil and Sediment by Selective Pressurized Liquid Extraction with Immunochemical Detection

    EPA Science Inventory

    A selective liquid pressurized extraction (SPLE) method was developed as a streamlined sample preparation/cleanup procedure for determining Aroclors and coplanar polychlorinated biphenyls (PCBs) in soil and sediment matrices. The SPLE method was coupled with an enzyme-linked imm...

  13. ATTENUATION/STABILIZATION OF ARSENIC BY IRON (HYDR)OXIDES IN SOILS/SEDIMENTS: LABORATORY STUDY.

    EPA Science Inventory

    Laboratory studies will be performed to assess the role of naturally occurring soil/sediment iron (hydr)oxides on the attenuation/stabilization of arsenic. Changes in the reversibility of arsenic partitioning will be assessed as a function of aging time using model experimental ...

  14. IMMUNOASSAY METHOD FOR THE DETERMINATION OF PENTACHLOROPHENOL IN SOIL AND SEDIMENT

    EPA Science Inventory

    The journal article describes the use of a prototype immunoassay method for the determination of pentacholorphenol (PCP) in soil and sediment. PCP was used as a pesticide and wood preservative and is not currently available to the general public. The paper stresses the importan...

  15. Erosion and Sediment Transport Modelling in Shallow Waters: A Review on Approaches, Models and Applications.

    PubMed

    Hajigholizadeh, Mohammad; Melesse, Assefa M; Fuentes, Hector R

    2018-03-14

    The erosion and sediment transport processes in shallow waters, which are discussed in this paper, begin when water droplets hit the soil surface. The transport mechanism caused by the consequent rainfall-runoff process determines the amount of generated sediment that can be transferred downslope. Many significant studies and models are performed to investigate these processes, which differ in terms of their effecting factors, approaches, inputs and outputs, model structure and the manner that these processes represent. This paper attempts to review the related literature concerning sediment transport modelling in shallow waters. A classification based on the representational processes of the soil erosion and sediment transport models (empirical, conceptual, physical and hybrid) is adopted, and the commonly-used models and their characteristics are listed. This review is expected to be of interest to researchers and soil and water conservation managers who are working on erosion and sediment transport phenomena in shallow waters. The paper format should be helpful for practitioners to identify and generally characterize the types of available models, their strengths and their basic scope of applicability.

  16. Assessment of Available Phosphorus in the Lake Sediments Using an Innovative Composite Membrane

    NASA Astrophysics Data System (ADS)

    Huang, Qinghui; Wang, Zijian; Wang, Donghong

    2010-11-01

    An innovative iron oxide embedded cellulose acetate membrane (FeO/CAM) was synthesized and used to study available phosphorus in Chinese lake sediments. The kinetics of available P release was investigated by FeO/CAM for different types of sediments ranging in Olsen-P from 19.1 to 170.6 mg/kg. The results showed that the average kd values (0.094 h-1) of the Taihu sediments were comparable to those of the soils with similar texture estimated by iron oxide impregnated filter paper (FeO paper) though they were generally lower than those of sandy soils. It is indicated that the FeO/CAM can be used as an infinite P sink to estimate available P (FeO-P). The concentrations of FeO-P were significantly correlated with those of extractable P forms, e.g. Olsen-P (R2 = 0.962, p<0.01) in lake sediments. This synthetic membrane excelled FeO paper in the endurance and the stain resistance to soil particles. Therefore, the FeO/CAM is useful to assess phosphorus bioavailability of the sediments.

  17. Erosion and Sediment Transport Modelling in Shallow Waters: A Review on Approaches, Models and Applications

    PubMed Central

    Fuentes, Hector R.

    2018-01-01

    The erosion and sediment transport processes in shallow waters, which are discussed in this paper, begin when water droplets hit the soil surface. The transport mechanism caused by the consequent rainfall-runoff process determines the amount of generated sediment that can be transferred downslope. Many significant studies and models are performed to investigate these processes, which differ in terms of their effecting factors, approaches, inputs and outputs, model structure and the manner that these processes represent. This paper attempts to review the related literature concerning sediment transport modelling in shallow waters. A classification based on the representational processes of the soil erosion and sediment transport models (empirical, conceptual, physical and hybrid) is adopted, and the commonly-used models and their characteristics are listed. This review is expected to be of interest to researchers and soil and water conservation managers who are working on erosion and sediment transport phenomena in shallow waters. The paper format should be helpful for practitioners to identify and generally characterize the types of available models, their strengths and their basic scope of applicability. PMID:29538335

  18. State of the Science Review: Potential for Beneficial Use of ...

    EPA Pesticide Factsheets

    Metal and metalloid contamination of soil and sediment is a widespread problem both in urban and rural areas throughout the United States (U.S. EPA, 2014). Beneficial use of waste by-products as amendments to remediate metal-contaminated soils and sediments can provide major economic and environmental advantages on both a site-specific and national scale. These waste by-products can also reduce our need to mine virgin materials or produce synthetic materials for amendments. Waste by-products must not be hazardous or pose unacceptable risk to human health and the environment, and should be a suitable replacement for virgin and synthetic materials. This review serves to present the state of science on in-situ remediation of metal-contaminated soil and sediment and the potential for beneficial usage of waste by-product materials. Not all unintended consequences can be fully understood or predicted prior to implementing a treatment option, however some realized, and potentially unrealized, benefits and unintended consequences are explored. The objectives of this review article are to: (1) summarize the current state of the science on in-situ treatment of metal-contaminated soils and sediments; (2) review the more recent use of non-municipal and non-hazardous waste by-products for use as soil and sediment amendments; and (3) identify physical and chemical properties that are indicative of the success or effectiveness of using a specific amendment to treat metal

  19. Polybrominated diphenyl ethers in soils, sediments, and human hair in a plastic waste recycling area: a neglected heavily polluted area.

    PubMed

    Tang, Zhenwu; Huang, Qifei; Cheng, Jiali; Yang, Yufei; Yang, Jun; Guo, Wei; Nie, Zhiqiang; Zeng, Ning; Jin, Lu

    2014-01-01

    The release of pollutants during the recycling of contaminated plastics is a problem which has drawn worldwide attention; however, little information on the transfer of polybrominated diphenyl ethers (PBDEs) in these processes is available. We conducted a survey of PBDEs in soils, sediments, and human hair in a typical plastic waste recycling area in northern China. The total concentrations (ng/g) of 21 PBDEs were 1.25-5504 (average 600), 18.2-9889 (average 1619), and 1.50-861 (average 112) in soils, sediments, and hair, respectively. The PBDE concentrations were comparable to concentrations observed in e-waste recycling areas; however, the concentrations in soils and sediments were 1-3 orders of magnitude higher than in other areas, and the concentrations in hair were much higher than in other areas. This indicates that this area is highly polluted with PBDEs. BDE-209 was the dominant congener (representing 91.23%, 92.3%, and 91.5% of the total PBDEs observed in soils, sediments, and hair, respectively), indicating that the commercial deca-BDE product was dominant. The commercial penta- and octa-BDE products made small contributions to the total PBDE concentrations, unlike what has been found in some e-waste recycling areas. Our results show that crude plastic waste processing is a major contributor of PBDEs to the environment and humans, which should be of great concern.

  20. Missing evidence for the LGM-asynchronity in the Central Spanish Pyrenees in geomorphological, sedimentological and pedological archives

    NASA Astrophysics Data System (ADS)

    Hirsch, Florian; Raab, Thomas

    2016-04-01

    According to the state of knowledge, the glacial advances in the Eastern Pyrenees were synchronous with the global LGM during the Late Pleistocene (MIS 2), but the glacial advances in the Central Spanish Pyrenees at MIS 3 were asynchron with the global LGM. Whereas in the Eastern Pyrenees the glacial advances are dated in several well agreeing studies by surface exposure dating of boulders from lateral or terminal moraines, the asynchronity of the Central Spanish Pyrenees was postulated mainly by OSL dating on glacial and fluvial sediments and on radiocarbon dating of pollen from lacustrine deposits. The time difference of about 15 ka raises the question if this is a result of (local) climate factors or owed to failures caused by using several dating techniques on different archives. Anyway, if this time lag is correct, post-LGM formation of soils and sediments from the Late Pleistocene should be different between the Eastern Pyrenees and the Central Spanish Pyrenees. We therefore applied a combined approach of geomorphological, sedimentological and pedological investigations to reconstruct the Late Quaternary landscape development in the Aragon- and Gallego Valley of the Central Spanish Pyrenees. Our study reveals that in both valleys the Pre-Holocene geomorphodynamics on the lateglacial deposits show clear analogies with findings from Pleistocene periglacial landscapes in Central Europe. For MIS 4 and early MIS 3 periglacial processes are proven by loess deposition and formation of solifluction sediments. The glacial sediments, which were dated in earlier studies into mid MIS 3 and counted so far as prove for the asynchronous LGM of the Central Spanish Pyrenees, are covered by periglacial deposits of lateglacial age (14 ka to 11 ka). Surprisingly neither the glacial sediments have pedogenic features that indicate lateglacial soil development, nor do the periglacial deposits show indications for lateglacial soil erosion. Therefore we conclude that soil formation began after the sedimentation of the periglacial deposits, either implying a striking timeframe of more than 15 ka with a stable landscape without any pedogenesis, or the untenability of the MIS 3 age of the glacial sediments. Because we can clearly differentiate further phases of geomorphodynamics during the Holocene with truncated soil profiles and the correlate sediments of soil erosion next to undisturbed soils in periglacial sediments with a lateglacial age, we challenge the thesis of an asynchronous LGM in the Central Spanish Pyrenees and advocate a synchronous LGM in the Gallego- and Aragon valley analog to the Eastern Pyrenees.

  1. Hanford Environmental Analytical Methods (methods as of March 1990). Volume 2, Appendix A1-O and appendix A1-I

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Goheen, S.C.; McCulloch, M.; Daniel, J.L.

    1993-05-01

    Techniques in use at the Hanford Reservation as of March, 1990 for the analysis of liquids, organic wastes, soils, and sediments, are described. Limitations and applications of the techniques are included.

  2. Sediment budget for five millennia of tillage in the Rockenberg catchment (Wetterau loess basin, Germany)

    NASA Astrophysics Data System (ADS)

    Houben, Peter

    2012-10-01

    The long-cultivated loess landscapes of central Europe provide the opportunity to explore the long-term perspective on the evolution human-natural sediment systems that are driven by human-caused soil erosion processes. A balance of spatially non-uniform sediment production, sedimentation and delivery was developed to highlight the quantitative dimensions and functioning of anthropogenic sediment redistribution in an undulating loess catchment of temperate Europe. The presented long-term perspective relies on analysing pedostratigraphic and lithostratigraphic field data from 728 corings across ˜10-km2, GIS-based data processing, and the analysis of data uncertainty. For a period of 5000 years of tillage, anthropogenic sediment production equals ˜9425 t ha-1, of which 62% still reside as colluvial sediment on the catchment's hillsides. The valley floors fulfil a sediment-conveyor function through transporting 77% of the sediment received from the hillsides. Whole-catchment yield to the contiguous higher-order valley is 29% of the amount of anthropogenic sediment production. The average catchment-scale depth of soil truncation is 0.64 m while the remaining anthropogenic sediment cover has an average thickness of 0.46 m (effective surface denudation: ˜0.18 m). The long-term integral net erosion rate is ˜0.5 t ha-1 a-1 because of extensive sediment retention on hillsides. The inherited human imprint on the soilscape, eventually, can be judged as beneficial rather than detrimental: the ubiquitous cover of humic colluvia generally is more suitable for intense cultivation than pristine pedostratigraphies. The sediment budget, although build from a historic perspective, also provides a plausible reference for realistic objectives of managing the soil erosion problem in human-natural sediment systems.

  3. A new perspective on soil erosion: exploring a thermodynamic approach in a small area of the River Inn catchment

    NASA Astrophysics Data System (ADS)

    Reid, Lucas; Scherer, Ulrike; Zehe, Erwin

    2016-04-01

    Soil erosion modeling has always struggled with compensating for the difference in time and spatial scale between model, data and the actual processes involved. This is especially the case with non-event based long-term models based on the Universal Soil Loss Equation (USLE), yet USLE based soil erosion models are among the most common and widely used for they have rather low data requirements and can be applied to large areas. But the majority of mass from soil erosion is eroded within short periods of times during heavy rain events, often within minutes or hours. Advancements of the USLE (eg. the Modified Universal Soil Loss Equation, MUSLE) allow for a daily time step, but still apply the same empirical methods derived from the USLE. And to improve the actual quantification of sediment input into rivers soil erosion models are often combined with a Sediment Delivery Ratio (SDR) to get results within the range of measurements. This is still a viable approach for many applications, yet it leaves much to be desired in terms of understanding and reproducing the processes behind soil erosion and sediment input into rivers. That's why, instead of refining and retuning the existing methods, we explore a more comprehensive, physically consistent description on soil erosion. The idea is to describe soil erosion as a dissipative process (Kleidon et al., 2013) and test it in a small sub-basin of the River Inn catchment area in the pre-Alpine foothills. We then compare the results to sediment load measurements from the sub-basin and discuss the advantages and issues with the application of such an approach.

  4. Characteristics of pulsed runoff-erosion events under typical rainstorms in a small watershed on the Loess Plateau of China.

    PubMed

    Wu, Lei; Jiang, Jun; Li, Gou-Xia; Ma, Xiao-Yi

    2018-02-27

    The pulsed events of rainstorm erosion on the Loess Plateau are well-known, but little information is available concerning the characteristics of superficial soil erosion processes caused by heavy rainstorms at the watershed scale. This study statistically evaluated characteristics of pulsed runoff-erosion events based on 17 observed rainstorms from 1997-2010 in a small loess watershed on the Loess Plateau of China. Results show that: 1) Rainfall is the fundamental driving force of soil erosion on hillslopes, but the correlations of rainfall-runoff and rainfall-sediment in different rainstorms are often scattered due to infiltration-excess runoff and soil conservation measures. 2) Relationships between runoff and sediment for each rainstorm event can be regressed by linear, power, logarithmic and exponential functions. Cluster Analysis is helpful in classifying runoff-erosion events and formulating soil conservation strategies for rainstorm erosion. 3) Response characteristics of sediment yield are different in different levels of pulsed runoff-erosion events. Affected by rainfall intensity and duration, large changes may occur in the interactions between flow and sediment for different flood events. Results provide new insights into runoff-erosion processes and will assist soil conservation planning in the loess hilly region.

  5. Depth and areal extent of sheet and rill erosion based on radionuclides in soils and suspended sediment

    NASA Astrophysics Data System (ADS)

    Whiting, Peter J.; Bonniwell, E. Chris; Matisoff, Gerald

    2001-12-01

    Sheetwash and rilling are two important mechanisms of soil erosion by runoff. The relative contribution of each mechanism has been a vexing question because measuring thin sheet erosion is difficult. Fortuitously, various fallout radionuclides have distinct distributions in the soil column; thus, different depths of erosion produce suspended sediment with unique radionuclide signatures. Those signatures can be used to estimate the depth and areal extent of sheet and rill erosion. We developed a model to execute multiple mass balances on soil and radionuclides to quantify these erosion mechanisms. Radionuclide activities (7Be, 137Cs, 210Pb) in the soil of a 6.03 ha agricultural field near Treynor, Iowa, and in suspended sediment washed off the field during thunderstorm runoff were determined by gamma spectroscopy. Using the model, we examined 15.5 million possible combinations of the depth and areal extent of rill and sheet erosion. The best solution to the mass balances corresponded to rills eroding 0.38% of the basin to a depth of 35 mm and sheetwash eroding 37% of the basin to a depth of 0.012 mm. Rill erosion produced 29 times more sediment than sheet erosion.

  6. Experimental and ecosystem model approach to assessing the sensitivity of High arctic deep permafrost to changes in surface temperature and precipitation

    NASA Astrophysics Data System (ADS)

    Rasmussen, L. H.; Zhang, W.; Elberling, B.; Cable, S.

    2016-12-01

    Permafrost affected areas in Greenland are expected to experience large temperature increases within the 21st century. Most previous studies on permafrost consider near-surface soil, where changes will happen first. However, how sensitive the deep permafrost temperature is to near-surface conditions through changes in soil thermal properties, snow depth and soil moisture, is not known. In this study, we measured the sensitivity of thermal conductivity (TC) to gravimetric water content (GWC) in frozen and thawed deep permafrost sediments from deltaic, alluvial and fluvial depositional environments in the Zackenberg valley, NE Greenland. We also calibrated a coupled heat and water transfer model, the "CoupModel", for the two closely situated deltaic sites, one with average snow depth and the other with topographic snow accumulation. With the calibrated model, we simulated deep permafrost thermal dynamics in four scenarios with changes in surface forcing: a. 3 °C warming and 20 % increase in precipitation; b. 3 °C warming and 100 % increase in precipitation; c. 6 °C warming and 20 % increase in precipitation; d. 6 °C warming and 100 % increase in precipitation.Our results indicated that frozen sediments had higher TC than thawed sediments. All sediments showed a positive linear relation between TC and soil moisture when frozen, and a logarithmic one when thawed. Fluvial sediments had high sensitivity, but never reached above 12 % GWC, indicating a field effect of water retention capacity. Alluvial sediments were less sensitive to soil moisture than deltaic and fluvial sediments, indicating the importance of unfrozen water in frozen sediment. The deltaic site with snow accumulation had 1 °C higher annual mean ground temperature than the average snow site. The soil temperature at the depth of 18 m increased with 1.5 °C and 3.5 °C in the scenarios with 3 °C and 6 °C warming, respectively. Precipitation had no significant additional effect to warming. We conclude that below-ground sediment properties affect the sensitivity of TC to GWC, that surface temperature changes can significantly affect the deep permafrost within a short period, and that differences in snow depth affect surface temperatures. Geology, pedology and precipitation should thus be considered if estimating future High arctic deep permafrost sensitivity.

  7. Identifying sources of acidity and spatial distribution of acid sulfate soils in the Anglesea River catchment, southern Australia

    NASA Astrophysics Data System (ADS)

    Wong, Vanessa; Yau, Chin; Kennedy, David

    2015-04-01

    Globally, coastal and estuarine floodplains are frequently underlain by sulfidic sediments. When exposed to oxygen, sulfidic sediments oxidise to form acid sulfate soils, adversely impacting on floodplain health and adjacent aquatic ecoystems. In eastern Australia, our understanding of the formation of these coastal and estuarine floodplains, and hence, spatial distribution of acid sulfate soils, is relatively well established. These soils have largely formed as a result of sedimentation of coastal river valleys approximately 6000 years BP when sea levels were one to two metres higher. However, our understanding of the evolution of estuarine systems and acid sulfate soil formation, and hence, distribution, in southern Australia remains limited. The Anglesea River, in southern Australia, is subjected to frequent episodes of poor water quality and low pH resulting in closure of the river and, in extreme cases, large fish kill events. This region is heavily reliant on tourism and host to a number of iconic features, including the Great Ocean Road and Twelve Apostles. Poor water quality has been linked to acid leakage from mining activities and Tertiary-aged coal seams, peat swamps and acid sulfate soils in the region. However, our understanding of the sources of acidity and distribution of acid sulfate soils in this region remains poor. In this study, four sites on the Anglesea River floodplain were sampled, representative of the main vegetation communities. Peat swamps and intertidal marshes were both significant sources of acidity on the floodplain in the lower catchment. However, acid neutralising capacity provided by carbonate sands suggests that there are additional sources of acidity higher in the catchment. This pilot study has highlighted the complexity in the links between the floodplain, upper catchment and waterways with further research required to understand these links for targeted acid management strategies.

  8. Modelling soil carbon fate under erosion process in vineyard

    NASA Astrophysics Data System (ADS)

    Novara, Agata; Scalenghe, Riccardo; Minacapilli, Mario; Maltese, Antonino; Capodici, Fulvio; Borgogno Mondino, Enrico; Gristina, Luciano

    2017-04-01

    Soil erosion processes in vineyards beyond water runoff and sediment transport have a strong effect on soil organic carbon loss (SOC) and redistribution along the slope. The variation of SOC across the landscape determines a difference in soil fertility and vine productivity. The aim of this research was to study erosion of a Mediterranean vineyard, develop an approach to estimate the SOC loss, correlate the vines vigor with sediment and carbon erosion. The study was carried out in a Sicilian (Italy) vineyard, planted in 2011. Along the slope, six pedons were studied by digging 6 pits up to 60cm depth. Soil was sampled in each pedon every 10cm and SOC was analyzed. Soil erosion, detachment and deposition areas were measured by pole height method. The vigor of vegetation was expressed in term of NDVI (Normalized difference Vegetation Index) derived from a satellite image (RapidEye) acquired at berry pre-veraison stage (July) and characterized by 5 spectral bands in the shortwave region, including a band in the red wavelength (R, 630-685 nm) and in the near infrared (NIR, 760-850 nm) . Results showed that soil erosion, sediments redistribution and SOC across the hill was strongly affected by topographic features, slope and curvature. The erosion rate was 46Mg ha-1 y-1 during the first 6 years since planting. The SOC redistribution was strongly correlated with the detachment or deposition area as highlighted by pole height measurements. The approach developed to estimate the SOC loss showed that during the whole study period the off-farm SOC amounts to 1.6Mg C ha-1. As highlighted by NDVI results, the plant vigor is strong correlated with SOC content and therefore, developing an accurate NDVI approach could be useful to detect the vineyard areas characterized by low fertility due to erosion process.

  9. SERDP and ESTCP Expert Panel Workshop on Research and Development Needs for Understanding and Assessing the Bioavailability of Contaminants in Soils and Sediments

    DTIC Science & Technology

    2008-11-01

    Risk Assess. 2(4): 841-873. Maskall, J.E., and I. Thornton. 1998. Chemical partitioning of heavy metals in soils , clays and rocks at historical...assay system correlated with risk of heavy metals in soil or sediments. Two projects were selected under this SON: ER-1165 and ER-1166 (Sections A.3...chemical environment of the stabilized metals . The project is ongoing. ER-1352 (Facilitated Immobilization of Heavy Metals in Soil by Manipulation

  10. Crevasse Splays Versus Avulsions: A Recipe for Land Building With Levee Breaches

    NASA Astrophysics Data System (ADS)

    Nienhuis, Jaap H.; Törnqvist, Torbjörn E.; Esposito, Christopher R.

    2018-05-01

    Natural-levee breaches can not only initiate an avulsion but also, under the right circumstances, lead to crevasse splay formation and overbank sedimentation. The formative conditions for crevasse splays are not well understood, yet such river sediment diversions form an integral part of billion-dollar coastal restoration projects. Here we use Delft3D to investigate the influence of vegetation and soil consolidation on the evolution of a natural-levee breach. Model simulations show that crevasse splays heal because floodplain aggradation reduces the water surface slope, decreasing water discharge into the flood basin. Easily erodible and unvegetated floodplains increase the likelihood for channel avulsions. Denser vegetation and less potential for soil consolidation result in small crevasse splays that are not only efficient sediment traps but also short-lived. Successful crevasse splays that generate the largest land area gain for the imported sediment require a delicate balance between water and sediment discharge, vegetation root strength, and soil consolidation.

  11. Data Gap Analysis and Database Expansion of Parameters for Munitions Constituents

    DTIC Science & Technology

    2005-12-01

    the BIOWIN documentation (Boethling et al. 1994). Sediment is briefly considered to be anaerobic soil, with overall conversion factors, and water is...life for degradation of a chemical in water, soil, and sediment is determined using the ultimate biodegradation expert survey module of the BIOWIN

  12. MANAGING ARSENIC CONTAMINATED SOIL, SEDIMENT, AND INDUSTRIAL WASTE WITH SOLIDIFICATION/STABILIZATION TREATMENT

    EPA Science Inventory

    Arsenic contamination of soil, sediment and groundwater is a widespread problem in certain areas and has caused great public concern due to increased awareness of the health risks. Often the contamination is naturally occurring, but it can also be a result of waste generated from...

  13. TECHNOLOGIES FOR MONITORING AND MEASUREMENT OF DIOXIN AND DIOXIN-LIKE COMPOUNDS IN SOIL AND SEDIMENT. HYBRIZYME CORPORATION AHRC PCR KIT

    EPA Science Inventory

    A demonstration of technologies for determining the presence of dioxin and dioxin-like compounds in soil and sediment was conducted under EPA's Superfund Innovative Technology Evaluation Program in Saginaw, Michigan in April 2004. This report describes the performance evaluation ...

  14. AUTOMATED GIS WATERSHED ANALYSIS TOOLS FOR RUSLE/SEDMOD SOIL EROSION AND SEDIMENTATION MODELING

    EPA Science Inventory

    A comprehensive procedure for computing soil erosion and sediment delivery metrics has been developed using a suite of automated Arc Macro Language (AML ) scripts and a pair of processing- intensive ANSI C++ executable programs operating on an ESRI ArcGIS 8.x Workstation platform...

  15. TOWARDS A STANDARD METHOD FOR THE MEASUREMENT OF ORGANIC CARBON IN SEDIMENTS

    EPA Science Inventory

    The precisions achieved by two different methods for analysis of organic carbon in soils and sediments were determined and compared. The first method is a rapid dichromate oxidation technique (Walkley-Black) that has long been a standard in soil chemistry. The second is an automa...

  16. AN OVERVIEW OF PARTITIONING AND BIOAVAILABILITY OF PAHS IN SEDIMENTS AND SOILS

    EPA Science Inventory

    Understanding and predicting any adverse effects of PAHs depends on generating a reliable measure or estimate of how much PAH is available for uptake. Simply knowing the total amount of PAH in soil, water or sediment is insufficient for determining whether or not these compounds ...

  17. IN-SITU REDUCTION OF CHROMIUM-CONTAMINATED GROUNDWATER, SOILS, AND SEDIMENTS BY SODIUM DITHIONITE

    EPA Science Inventory

    Laboratory studies were conducted to characterize the extent of chromium contamination in the groundwater and underlying soils and sediments of a chrome-plating shop at the USCG Support Center near Elizabeth City, NC. Most of the mobile Cr(VI) is present in the capillary zone ...

  18. EXPERIMENTAL DESIGN CONSIDERATIONS WHEN VERIFYING THE PERFORMANCE OF MONITORING TECHNOLOGIES FOR DIOXIN AND DIOXIN-LIKE COMPOUNDS IN SOILS AND SEDIMENTS

    EPA Science Inventory

    A performance verification demonstration of technologies capable of detecting dioxin and dioxin-like compounds in soil and sediment samples was conducted in April 2004 under the U.S. Environmental Protection Agency's Superfund Innovative Technology Evaluation (SITE) Monitoring an...

  19. EFFECTS OF MOUNTAINTOP MINING/VALLEY FILL (MTM/VF) ON FUNCTIONAL INDICATORS IN APPALACHIAN HEADWATER STREAMS

    EPA Science Inventory

    The objectives of this poster were 1)to evaluate the impact of MTM/VF on the functional attributes SOD, soil/sediment respiration rate, soil/sediment DEA and dissolved trace gas concentrations across gradients of mining disturbance and hydrolgy and 2)compare these functional attr...

  20. PERFORMANCE OF THE CAPE TECHNOLOGIES DF1 DIOXIN/FURAN IMMUNOASSAY KIT FOR SOIL AND SEDIMENT SAMPLES

    EPA Science Inventory

    A demonstration of screening technologies for determining the presence of dioxin and dioxin-like compounds in soil and sediment was conducted under the U.S. Environmental Protection Agency’s (EPA’s) Superfund Innovative Technology Evaluation Program in Saginaw, Michigan in 2004. ...

  1. IN-SITU REMEDIATION OF CHROMIUM-CONTAMINATED SOILS AND SEDIMENTS

    EPA Science Inventory

    The objectives of this study were to characterize the extent of total chromium and Cr(VI)contamination in the underlying soils and sediments of a chrome-plating shop at the USCG Support Center near Elizabeth City, NC and to evaluate the use of liquid reductants for in situ treatm...

  2. ELECTROLYTIC DECHLORINATION OF 2-CHLOROBIPHENYL AT A PALLADIUM MODIFIED GRANULAR-GRAPHITE-PACKED ELECTRODE

    EPA Science Inventory

    Polychlorinated biphenyls (PCBs) and other chlorinated aromatic compounds are distributed in soils and sediments at over 400 sites in the USA. A national need exists for both in situ and ex situ methods to destroy these persistent organic pollutants in soils and sediments at ambi...

  3. A Pyoverdin Siderophore Produced By Pseudomonas aeruginosa CHL-004 Binds Lead And Other Heavy Metals

    EPA Science Inventory

    Heavy metal pollution in soils, sediments and wastewater poses a significant environmental and public health threat due to toxicity and the potential for bioaccumulation in both plant and animal tissues. Remediation of heavy metals in soils and sediments using solely physical or...

  4. A Pyoverdin Siderophore Produced By Pseudomonas aeruginosa CHL-004 Binds Lead And Other Heavy Metals - (Poster)

    EPA Science Inventory

    Heavy metal pollution in soils, sediments and wastewater poses a significant environmental and public health threat due to toxicity and the potential for bioaccumulation in both plant and animal tissues. Remediation of heavy metals in soils and sediments using solely physical or...

  5. 75 FR 8402 - Notice of Lodging of Consent Decree Under the Comprehensive Environmental Response, Compensation...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-02-24

    ... facility at the Site, where soil, sediment, and water have been contaminated with hazardous substances such as volatile organic compounds and heavy metals. The proposed Consent Decree requires ITT Corporation... response costs. The remedial action consists of disposal of contaminated soil and sediment, bioremediation...

  6. DEMONSTRATION AND QUALITY ASSURANCE PROJECT PLAN: XRF TECHNOLOGIES OF MEASURING TRACE ELEMENTS IN SOIL AND SEDIMENT

    EPA Science Inventory

    A demonstration of field portable/mobile technologies for measuring trace elements in soil and sediments was conducted under the U.S. Environmental Protection Agency Superfund Innovative Technology Evaluation (SITE) Program. The demonstration took place from January 24 to 28, 200...

  7. Subsoil erosion dominates the supply of fine sediment to rivers draining into Princess Charlotte Bay, Australia.

    PubMed

    Olley, Jon; Brooks, Andrew; Spencer, John; Pietsch, Timothy; Borombovits, Daniel

    2013-10-01

    The Laura-Normanby River (catchment area: 24,350 km(2)), which drains into Princess Charlotte Bay, has been identified in previous studies as the third largest contributor of sediment to the Great Barrier Reef World Heritage Area. These catchment scale modelling studies also identified surface soil erosion as supplying >80% of the sediment. Here we use activity concentrations of the fallout radionuclides (137)Cs and (210)Pbex to test the hypothesis that surface soil erosion dominates the supply of fine (<10 μm) sediment in the river systems draining into Princess Charlotte Bay. Our results contradict these previous studies, and are consistent with channel and gully erosion being the dominant source of fine sediment in this catchment. The hypothesis that surface soil erosion dominates the supply of fine sediment to Princess Charlotte Bay is rejected. River sediment samples were collected using both time-integrated samplers and sediment drape deposits. We show that there is no detectable difference in (137)Cs and (210)Pbex activity concentrations between samples collected using these two methods. Two methods were also used to collect samples to characterise (137)Cs and (210)Pbex concentrations in sediment derived from surface soil erosion; sampling of surface-wash deposits and deployment of surface runoff traps that collected samples during rain events. While there was no difference in the (137)Cs activity concentrations for samples collected using these two methods, (210)Pbex activity concentrations were significantly higher in the samples collected using the runoff traps. The higher (210)Pbex concentrations are shown to be correlated with loss-on-ignition (r(2) = 0.79) and therefore are likely to be related to higher organic concentrations in the runoff trap samples. As a result of these differences we use a three end member mixing model (channel/gully, hillslope surface-wash and hillslope runoff traps) to determine the relative contribution from surface soil erosion. Probability distributions for (137)Cs and (210)Pbex concentrations were determined for each of the end members, with these distributions then used to estimate the surface soil contribution to each of the collected river sediment samples. The mean estimate of contribution of surface derived sediment for all river samples (n = 70) is 16 ± 2%. This study reinforces the importance of testing model predictions before they are used to target investment in remedial action and adds to the body of evidence that the primary source of sediment delivered to tropical river systems is derived from subsoil erosion. Copyright © 2013 Elsevier Ltd. All rights reserved.

  8. Physicochemical Characterization of Potential Mobile Organic Matter In Five Typical German Agricultural Soils

    NASA Astrophysics Data System (ADS)

    Séquaris, J.-M.; Lewandowski, H.; Vereecken, H.

    Organic matter (OM) in soils plays an important role, i.e., in maintaining soil structure or as source of nutrients. OM is mainly adsorbed at the surface of clay minerals and oxides and remains mostly immobile. However, mobile OM in dissolved form (DOM) or associated with water dispersible colloids (WDC) in soil water may influence trans- port of pollutants. The goal of this study is to compare 5 typical German agricultural soils in terms of distribution and quality of OM in the top soil (0-15 cm). The present report focuses on the physicochemical characterization of potential mobile OM so- lutions obtained after physical fractionation of soil materials based on sedimentation after a prolonged shaking in water or electrolyte solutions. Three soil fractions dif- fering in particle size were separated in function of sedimentation time: a colloidal fraction: < 2 ţm; a microaggregate fraction: 2-20 ţm and a sediment fraction: > 20 ţm. The soil electrolyte phase containing the DOM fraction was obtained by a high-speed centrifugation of the colloidal phase. After a water or low electrolyte concentration (« 1 mM Ca2+) extraction, it can be shown that the mobile fraction of OM or OC (organic carbon) is distributed between the colloidal and the electrolyte phases in a concentration ratio range of 10-40 to 1. A less mobile OC fraction is associated with the microaggregate fraction while immobile OC remains adsorbed in the sediment fraction. An increasing OC and total-N content with diminishing particle-size of soil (colloidal and microaggregate fractions) has been confirmed. A higher OC input due to special soil management is sensitively detected in fractions with a greater particle size (sediment fraction). Increasing the Ca2+ concentration up to 10 mM during the water extraction diminishes the DOC concentration by an average factor of 3 while the OC associated with the dispersed colloids (OCWDC) vanished almost completely. Thus, a critical coagulation concentration of about 1-2 mM Ca2+ can be estimated which increases the stability of soil aggregates in water. Different titration, electrokinetic and spectroscopic methods were applied to characterize the colloidal and electrolyte phases. These techniques provide information on the physicochemical heterogeneity of mobile OM from various agricultural soils.

  9. Soil fauna and leaf species, but not species diversity, affect initial soil erosion in a subtropical forest plantation

    NASA Astrophysics Data System (ADS)

    Seitz, Steffen; Goebes, Philipp; Assmann, Thorsten; Schuldt, Andreas; Scholten, Thomas

    2017-04-01

    In subtropical parts of China, high rainfall intensities cause continuous soil losses and thereby provoke severe harms to ecosystems. In woodlands, it is not the tree canopy, but mostly an intact forest floor that provides protection from soil erosion. Although the protective role of leaf litter covers against soil losses is known for a long time, little research has been conducted on the processes involved. For instance, the role of different leaf species and leaf species diversity has been widely disregarded. Furthermore, the impact of soil meso- and macrofauna within the litter layer on soil losses remains unclear. To investigate how leaf litter species and diversity as well as soil meso- and macrofauna affect sediment discharge in a subtropical forest ecosystem, a field experiment was carried out in Xingangshan, Jiangxi Province, PR China (BEF China). A full-factorial random design with 96 micro-scale runoff plots and seven domestic leaf species in three diversity levels and a bare ground feature were established. Erosion was initiated with a rainfall simulator. This study confirms that leaf litter cover generally protects forest soils from water erosion (-82 % sediment discharge on leaf covered plots compared to bare plots) and this protection is gradually removed as the litter layer decomposes. Different leaf species showed variable impacts on sediment discharge and thus erosion control. This effect can be related to different leaf habitus, leaf decomposition rates and food preferences of litter decomposing meso- and macrofauna. In our experiment, runoff plots with leaf litter from Machilus thunbergii in monoculture showed the highest sediment discharge (68.0 g m-2), whereas plots with Cyclobalanopsis glauca in monoculture showed the smallest rates (7.9 g m-2). At the same time, neither leaf species diversity, nor functional diversity showed any significant influence, only a negative trend could be observed. Nevertheless, the protective effect of the leaf litter layer was influenced by the presence (or absence) of soil meso- and macrofauna. Fauna presence increased soil erosion rates significantly by 58 %. It was assumed that this faunal effect arose from arthropods loosening and processing the soil surface as well as fragmenting and decomposing the protecting leaf litter covers. Thus, effects of this fauna group on sediment discharge have to be considered in soil erosion experiments.

  10. Environmental Assessment: Zebra Mussel Eradication from the Base Lake at Offutt Air Force Base

    DTIC Science & Technology

    2008-09-11

    water flow even in large diameter piping, increase sedimentation rates , and promote surface corrosion. Natural populations of 5,000 to 30,000...Body Weight (kg) Foraging Territory (ha) Food Ingestion Rate (kg dw/day) Food Ingestion Rate (kg ww/day) Water (L/day) Sediment / Soil Ingestion...Composition - based on diets for Missouri; Korschgen (1958) in USEPA (1993) Soil/ Sediment Ingestion Rate – Assumed 1% of dw ingestion rate ; USEPA (2000

  11. Environmental behaviors and potential ecological risks of heavy metals (Cd, Cr, Cu, Pb, and Zn) in multimedia in an oilfield in China.

    PubMed

    Hu, Yan; Wang, Dazhou; Li, Yu

    2016-07-01

    The environmental behaviors of five heavy metals (Cd, Cr, Cu, Pb, and Zn) in a Chinese oilfield were investigated using a steady-state multimedia aquivalence (SMA) model. The modeling results showed good agreement with the actual measured values, with average residual errors of 0.69, 0.83, 0.35, 0.16, and 0.54 logarithmic units for air, water, soil, sediment, and vegetation compartments, respectively. Model results indicated that most heavy metals were buried in sediment, and that transfers between adjacent compartments were mainly deposition from the water to the sediment compartment (48.59 %) and from the air to the soil compartment (47.74 %) via atmospheric dry/wet deposition. Sediment and soil were the dominant sinks, accounting for 68.80 and 25.26 % of all the heavy metals in the multimedia system, respectively. The potential ecological risks from the five heavy metals in the sediment and soil compartments were assessed by the potential ecological risk index (PERI). The assessment results demonstrate that the heavy metals presented low levels of ecological risk in the sediment compartment, and that Cd was the most significant contributor to the integrated potential ecological risk in the oilfield. The SMA model provided useful simulations of the transport and fate of heavy metals and is a useful tool for ecological risk assessment and contaminated site management.

  12. Investigation of the Impact of Stone Bunds on Erosion and Deposition Processes combining Conventional and Tracer Methodology in the Gumara Maksegnit Watershed, Northern Highlands of Ethiopia

    NASA Astrophysics Data System (ADS)

    Obereder, Eva Maria; Wakolbinger, Stefanie; Guzmán, Gema; Strohmeier, Stefan; Demelash, Nigus; Gomez, José Alfonso; Klik, Andreas

    2016-04-01

    Ethiopia is one of the poorest countries of the word, with over 85 % of total population dependent from agriculture. Massive deforestation in the past and missing soil and water conservation (SWC) measures cause severe soil erosion problems in the northern highlands of Ethiopia. Different SWC methods are supposed to prevent ongoing land degradation, which is triggered by rainfall driven soil erosion in the Ethiopian agricultural lands. Common technologies for soil and water conservation are stone bunds, which reduce surface runoff and sediment loss. In June 2015 two field experiments were set up in the Gumara-Maksegnit watershed in Northern Ethiopia. The objective of this study was to evaluate the impact of graded stone bunds on surface runoff and sediment yield by using conventional and tracing approaches. Three consecutive runoff plots of 20 x 4 m length and width, respectively were established along the maximum slope direction. Each one was separated to the downstream one by a stone bund. The experimental setup allowed the measurement of surface runoff along each stone bund and the measurement of overflow over the lowest stone bund. To assess the pathway and the spatial distribution of the sediments a different tracer (Magnetite, Hematite and Goethite) was applied in a 40 cm wide strip at the top of each one of the plots. The second tracer experiment was conducted on the same hillslope. It consisted of a 20 m long hillslope without borders in which a 4 m long and 40 cm wide Magnetite strip was placed at the top. At the end of August 2015 soil samples of 0-2 cm depth were taken in a 1.5 x 1.5 m grid within the area of the hillslope. Soil samples parallel to the stone bund (above and underneath) were taken along 16 m to assess the soil movement/deposition. Tracer concentrations of soil and sediment samples in both trials were analysed. Runoff and sediment were collected in weekly intervals from July to September. Runoff and erosion data, as well as the evaluation of the tracer experiments are presented. Preliminary results give an insight of the spatial pattern of sediment flow paths and accumulation areas to understand sediment dynamics within these systems. Gained knowledge on erosion processes provides information about the efficiency of the stone bunds as a SWC measure, very useful to optimize their design which affect indirectly to soil fertility and therefore to crop yield.

  13. Mars Pathfinder Wheel Abrasion Experiment Ground Test

    NASA Technical Reports Server (NTRS)

    Keith, Theo G., Jr.; Siebert, Mark W.

    1998-01-01

    The National Aeronautics and Space Administration (NASA) sent a mission to the martian surface, called Mars Pathfinder. The mission payload consisted of a lander and a rover. The primary purpose of the mission was demonstrating a novel entry, descent, and landing method that included a heat shield, a parachute, rockets, and a cocoon of giant air bags. Once on the surface, the spacecraft returned temperature measurements near the Martian surface, atmosphere pressure, wind speed measurements, and images from the lander and rover. The rover obtained 16 elemental measurements of rocks and soils, performed soil-mechanics, atmospheric sedimentation measurements, and soil abrasiveness measurements.

  14. Watershed sediment measurement and sediment transport modeling techniques: Case study to quantify the impact of converting cropland to forested stream buffers on soil loss and water quality at the watershed scale

    USDA-ARS?s Scientific Manuscript database

    Watershed models such as the Soil and Water Assessment Tool (SWAT) have been widely used to simulate watershed hydrologic processes and the effect of management, such as agroforestry, on soil and water resources. In order to use model outputs for tasks ranging from aiding policy decision making to r...

  15. Complete Genome Sequence of the Diesel-Degrading Acinetobacter sp. Strain DR1 ▿

    PubMed Central

    Jung, Jaejoon; Baek, Jeong-Hun; Park, Woojun

    2010-01-01

    The genus Acinetobacter is ubiquitous in soil, aquatic, and sediment environments and includes pathogenic strains, such as A. baumannii. Many Acinetobacter species isolated from various environments have biotechnological potential since they are capable of degrading a variety of pollutants. Acinetobacter sp. strain DR1 has been identified as a diesel degrader. Here we report the complete genome sequence of Acinetobacter sp. DR1 isolated from the soil of a rice paddy. PMID:20639327

  16. Chemical composition of windblown dust emitted from agricultural soils amended with biosolids

    NASA Astrophysics Data System (ADS)

    Pi, Huawei; Sharratt, Brenton; Schillinger, William F.; Bary, Andrew; Cogger, Craig

    2018-06-01

    Biosolids are frequently applied to agricultural lands in dry regions, but wind erosion of these lands might transport biosolids particulates offsite and impact environmental quality. Our objective was to measure concentrations of EPA-regulated metals as well as macronutrients and micronutrients in soil and windblown sediment from a biosolids field experiment. A wind tunnel was used to generate windblown sediment from experimental plots subject to traditional (disk) or conservation (undercutter) tillage and application of biosolids or synthetic fertilizer on two measurement dates during the summer fallow phase of a winter wheat-summer fallow (WW-SF) rotation at Lind, WA in 2015 and 2016. Application of biosolids or use of undercutter tillage resulted in higher concentrations of heavy metals in the soil. For example, zinc (Zn) concentration in soil was 14% higher for undercutter than disk tillage and 21% higher for biosolids than synthetic fertilizer on the first measurement date in 2015. Differences in metal concentrations between treatments, however, were not as evident in windblown sediment. Similar results were found for nutrient concentrations in soil, but concentrations in windblown sediment were at least 10% lower for biosolids than synthetic fertilizer and undercutter than disk tillage on at least one measurement date. Little difference was found in loss of heavy metals and nutrients in windblown sediment between biosolids and synthetic fertilizer treatments. Our results suggest similar loss of metals and other elements from agriculture land after application of biosolids and synthetic fertilizer. Biosolids, however, are beneficial for increasing C and N content in soil.

  17. Evaluation of organic compounds and trace elements in Amazon Creek Basin, Oregon, September 1990

    USGS Publications Warehouse

    Rinella, F.A.

    1993-01-01

    Water and bottom sediment were collected from Amazon Creek, Oregon during a summer low-flow condition and analyzed for different classes of organic compounds, including many from the U.S. Environmental Protection Agency's priority pollutant list. Bottom sediment also was analyzed for trace elements typically associated with urban runoff. Trace-element concentrations in the less than 63 micrometer fraction of Amazon Creek bottom-sediment samples were compared with baseline concentrations (expected 95 percent confidence range) for soils from the Western United States and with concen- trations found in bottom sediment from the Willamette River Basin. Total-digestion concentrations of antimony, arsenic, cadmium, chromium, cobalt, copper, lead, manganese, mercury, nickel, silver, titanium, and zinc were enriched at some or all sites sampled. Whole-water samples from some sites contained concentrations of several chlorophenoxy-acid herbicides, the organophosphorus insecticide diazinon, and several semivolatile priority pollutants. Classes of compounds not detected in whole-water samples included carbamate insecticides, triazine and other nitrogen-containing herbicides, and purgeable organic compounds. Bottom-sediment samples contained many organochlorine compounds, including chlordane, DDT plus metabolites, dieldrin, endrin, heptachlor epoxide (a metabolite of heptachlor), and PCBs at some or all sites sampled. Twenty-four of 54 semivolatile compounds were detected in bottom- sediment samples at some or all sites sampled.

  18. Distribution and biogeochemical controls on net methylmercury production in Penobscot River marshes and sediment.

    PubMed

    Gilmour, Cynthia; Bell, James Tyler; Soren, Ally Bullock; Riedel, Georgia; Riedel, Gerhardt; Kopec, A Dianne; Bodaly, R A

    2018-06-01

    The distribution of mercury and methylmercury (MeHg) in sediment, mudflats, and marsh soils of the Hg-contaminated tidal Penobscot River was investigated, along with biogeochemical controls on production. Average total Hg in surface samples (0-3 cm) ranged from 100 to 1200 ng/g; average MeHg ranged from 5 to 50 ng/g. MeHg was usually highest at or near the surface except in highly mobile mudflats. Although total Hg concentrations in the Penobscot are elevated, it is the accumulation of MeHg that stands out in comparison to other ecosystems. Surface soils in the large Mendall Marsh, about 17 km downstream from the contamination source, contained particularly high %MeHg (averaging 8%). In Mendall marsh soil porewaters, MeHg often accounted for more than half of total Hg. Salt marshes are areas of particular concern in the Penobscot River, for they are depositional environments for a Hg-contaminated mobile pool of river sediment, hot spots for net MeHg production, and sources of risk to marsh animals. We hypothesized that exceptionally low mercury partitioning between the solid and aqueous phases (with log K d averaging ~4.5) drives high MeHg in Penobscot marshes. The co-occurrence of iron and sulfide in filtered soil porewaters, sometimes both above 100 μM, suggests the presence of nanoparticulate and/or colloidal metal sulfides. These colloids may be stabilized by high concentrations of aromatic and potentially sulfurized dissolved organic matter (DOM) in marsh soils. Thus, Hg in Penobscot marsh soils appears to be in a highly available for microbial methylation through the formation of DOM-associated HgS complexes. Additionally, low partitioning of MeHg to marsh soils suggests high MeHg bioavailability to animals. Overall, drivers of high MeHg in Penobscot marshes include elevated Hg in soils, low partitioning of Hg to solids, high Hg bioavailability for methylation, rapidly shifting redox conditions in surface marsh soils, and high rates of microbial activity. Copyright © 2018 Elsevier B.V. All rights reserved.

  19. Prediction of Mass Wasting, Erosion, and Sediment Transport With the Distributed Hydrology-Soil-Vegetation Model

    NASA Astrophysics Data System (ADS)

    Doten, C. O.; Lanini, J. S.; Bowling, L. C.; Lettenmaier, D. P.

    2004-12-01

    Erosion and sediment transport in a temperate forested watershed are predicted with a new sediment module linked to the Distributed Hydrology-Soil-Vegetation Model (DHSVM). The DHSVM sediment module represents the main sources of sediment generation in forested environments: mass wasting, hillslope erosion and road surface erosion. It produces failures based on a factor-of-safety analysis with the infinite slope model through use of stochastically generated soil and vegetation parameters. Failed material is routed downslope with a rule-based scheme that determines sediment delivery to streams. Sediment from hillslopes and road surfaces is also transported to the channel network. Basin sediment yield is predicted with a simple channel sediment routing scheme. The model was applied to the Rainy Creek catchment, a tributary of the Wenatchee River which drains the east slopes of the Cascade Mountains, and Hard and Ware Creeks on the west slopes of the Cascades. In these initial applications, the model produced plausible sediment yield and ratios of landsliding and surface erosion , when compared to published rates for similar catchments in the Pacific Northwest. We have also used the model to examine the implications of fires and logging road removal on sediment generation in the Rainy Creek catchment. Generally, in absolute value, the predicted changes (increased sediment generation) following fires, which are primarily associated with increased slope failures, are much larger than the modest changes (reductions in sediment yield) associated with road obliteration, although the small sensitivity to forest road obliteration may be due in part to the relatively low road density in the Rainy Creek catchment, and to mechanisms, such as culvert failure, that are not represented in the model.

  20. Changes in soil erosion and sediment transport based on the RUSLE model in Zhifanggou watershed, China

    NASA Astrophysics Data System (ADS)

    Wang, Lei; Qian, Ju; Qi, Wen-Yan; Li, Sheng-Shuang; Chen, Jian-Long

    2018-04-01

    In this paper, changes of sediment yield and sediment transport were assessed using the Revised Universal Soil Loss Equation (RUSLE) and Geographical Information Systems (GIS). This model was based on the integrated use of precipitation data, Landsat images in 2000, 2005 and 2010, terrain parameters (slope gradient and slope length) and soil composition in Zhifanggou watershed, Gansu Province, Northwestern China. The obtained results were basically consistent with the measured values. The results showed that the mean modulus of soil erosion is 1224, 1118 and 875 t km-2 yr-1 and annual soil loss is 23 130, 21 130 and 16 536 in 2000, 2005 and 2010 respectively. The measured mean erosion modulus were 1581 and 1377 t km-2 yr-1, and the measured annual soil loss were 29 872 and 26 022 t in 2000 and 2005. From 2000 to 2010, the amount of soil erosion was reduced yearly. Very low erosion and low erosion dominated the soil loss status in the three periods, and moderate erosion followed. The zones classified as very low erosion were increasing, whereas the zones with low or moderate erosion were decreasing. In 2010, no zones were classified as high or very high soil erosion.

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